### TS-F444LK Attachment 6 Page 1 of 4

#:- 

# (CBI) 

# Material Safety Data Sheet

Issued Dec-2-2011
Revised

Printed Dec-2-2011 1. Product/Company identification
1.1. Identification of the substance or preparation

Trade name CBI Purpose R&D use only Common name Fluoroalkyl acrylate copolymer emulsion. Major application CBI

1.2. Company/undertaking identification

Manufacturer CBI Supplier in US CBI

Phone: CBI

1.3. Emergency telephone Company CBI



### 2. Composition/information on ingredients

name CAS Number Mass%



### CBI CBI CBI

CBI CBI CBI

CBI CBI

CBI CBI CBI



### 3. Hazards identification
Emergency Overview

Non-flammable material.

Potential Health Effects

Skin contact may cause skin irri tation with discomfort or rash. Eye contact may cause eye irritation with discomfort, tearing, or blurring of vision. Inhalation may cause irritation to the respir atory and impairment of the nervous system. Ingestion may cause gastrointestinal tract irritation. Carcinogenicity Information None of the components present in this mate rial at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen.



### 4. First-aid measures

Inhalation If inhaled, remove to fresh ai r. If not breathin g, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing before

reuse. Eyes Contact In case of contact, immedi ately flush eyes with plenty of water for at least 15 minutes. Call a physician. Ingestion Rinse mouth. Get medical attention.



### 5. Fire-fighting measures

General Information Non-flammable.

Flash Point: none.TS-F444LK Attachment 6 Page 2 of 4

Flammable Limits: LEL: no data UEL: no data

Hazardous decomposition produc ts including carbon dioxide, carbon monoxide, hydrogen fluori de, toxic gases or particles may be formed during combustion. These products may cause severe eye, nose, throat, and lung irritation or toxic effects Extinguishing Media Water, Powder, alcohol- resistant foam, water in large amounts,

carbon dioxide. Fire fighting instructions Wear self-contained breathing apparatus (SCBA) and full protective gear. Use water spray to cool fire exposed containers.



### 6. Accidental release measures
General Information Use proper personal prot ective equipment as indicated in section

8.

Spills/Leaks Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer.



### 7. Handling and storage Handling Wear suitable protective clothing (see section 8)

Use in well ventilated areas.

Make available in the work ar ea emergency shower and eyes

wash. As there is a possibility for inhaling poisonous decomposition gas form smoking a cigarette to wh ich compound may be adhered, “no smoking” practice should be maintained in a work place and after handling materials, wish face and hands thoroughly.

Storage Store in a cool, dry area at –5 deg C to 40 deg C. Keep away from direct heat or sunlight. Keep containers tightly closed when not in use.



### 8. Exposure controls/personal protection
Engineering Controls: Use only with adequate ventilation. Vent heated extruder or dryer fumes outs ide work area. Do not aerosolize. In spray applications, use airless type and exhaust ducts, drip pans, or other design features to minimize worker exposure to mists and overspray.

Personal Protective Equipment Eyes Wear safety glasse s with side shields. Hand Wear appropriate protective gloves to prevent exposure. Skin and body Wear protecti ve clothing and boots to minimize contact with skin. Respirators Use a NIOSH or European St andard EN 149 approved respirator when necessary. If thermal decomposition occurs, mask for acidic gases must be used to av oid inhalation of the product.

Exposure Limits HF TLV(as F): 3ppm; (ceiling values)(ACGIH 1999) MAK: 3ppm; 2.5mg/m3, BA T 7mg/g creatinine (1999) MAK as STEL: 6ppm, 5mg/m3 (1999) COF2 TLV: 2ppm; 5.4mg/m3 (as TWA); 5ppm, 13mg/m3(as STEL) (ACGIH 1997) PFIB TLV: 0.01ppm; 0.082mg/m3 (ceiling values)(ACGIH 1993-1994)



### 9. Physical and chemical properties
Physical State CBI

Color CBITS-F444LK Attachment 6 Page 3 of 4

Odor CBI pH CBI Boiling point CBI Freezing point CBI Vapor pressure CBI Vapor density CBI Specific gravity CBI Solubility in water CBI Flash point CBI Auto-ignition Temp. CBI Explosion limits CBI



### 10. Stability and reactivity
Chemical Stability Normally stable. Conditions to Avoid Exposure to op en flame or higher temperatures . Incompatibility None reasonably foreseeable

Materials to avoid None reasonably foreseeable. Polymerization Polymerization will not occur. Decomposition Carbon monoxide, carb on dioxide, HF, COF2, PFIB etc.



### 11. Toxicological information

This material no data

Data of individual components: Fluoroalkyl acrylate no data copolymer Dipropylene glycol, monomethyl ether

RETCS No. JM1575000 eye-hmn 8 mg MLD skn-rbt 500 mg open MLD eye-rbt 500 mg/24H MLD orl-dog LD50: 7500 mg/kg skn-rbt TDLo: 650 mL/kg/13W-I F01;general anesthetic Z01;death



### 12. Ecological information
Ecotoxicological Information

CBI

Chemical Fate Information

CBI



### 13. Disposal considerations
Dispose of in compliance with local government regulations. Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HF. Dispose of waste product in a sanitary landfill. Product may be recycled.



### 14. Transport information

Hazard Class CBI

UN Number CBI

DOT Classifi cation CBI



### 15. Regulatory information
TSCA:Not Registered.

NFPA Ratings: Health: not determine Flammability not determineTS-F444LK Attachment 6 Page 4 of 4 Reactivity not determine



### 16. Other information

The data in this Material Safety Data Sheet relate s only to the specific material designated herein

and does not relate to use in combination wi th any other material or in any process.
NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY,
OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIE D, IS MADE CONCERNI NG THE INFORMATION

PROVIDED HEREIN.