## Source **No. Runs**  **% A DL**  **% BDL** Floor tile roller kilns 

## 15 100 0 Floor tile press dryers 

## 12 58 42 Floor tile spray dryers 

## 15 73 27 Wall tile roller kilns 

## 6 50 50 Wall tile press dryers 

## 3 0 100 Wall tile spray dryers 

## 3 100 0 First-fire sanitaryware tunnel kilns [8 stacks, 5 kilns] 

## 24 75 25 Sanitaryware ware dryers [5 stacks, 3 dryers] 

## 15 0 100



# Summary-by Source

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 2320 0.62ADL 2320 1630 2.5ADL 1630 1760 2.4ADL 1760ADL 1,2,3,7,8 PeCDD 5780 75ADL 5780 4180 66ADL 4180 4040 10ADL 4040ADL 1,2,3,4,7,8 HxCDD 2500 100ADL 250 1810 79ADL 181 1620 120ADL 162ADL 1,2,3,6,7,8 HxCDD 3700 87ADL 370 2660 66ADL 266 2710 97ADL 271 ADL 1,2,3,7,8,9 HxCDD 12300 91 ADL 1230 8790 68ADL 879 5110 100ADL 511 ADL 1,2,3,4,6,7,8 HpCDD 36000 230ADL 360 24900 180ADL 249 26400 94ADL 264ADL OCDD 359000 3ADL 107.7 322000 4ADL 96.6 340000 9.7ADL 102ADL 2,3,7,8 TCDF 52.3 3.9ADL 5.23 64.9 2.3ADL 6.49 55 2.1 ADL 5.5ADL 1,2,3,7,8 PeCDF 46.1 2.5ADL 1.383 32.7 2.6ADL 0.981 32.9 2.1 ADL 0.987ADL 2,3,4,7,8 PeCDF 63.7 2.3ADL 19.11 50.6 2.5ADL 15.18 46.4 2ADL 13.92ADL 1,2,3,4,7,8 HxCDF 40.7 4.8ADL 4.07 21.9 2.8ADL 2.19 18 BDL J, R 0BDL 1,2,3,6,7,8 HxCDF 52.2 4.3ADL 5.22 33.1 2.5ADL 3.31 35.9 1.3ADL 3.59ADL 2,3,4,6,7,8 HxCDF 33.4 4.6ADL 3.34 26 2.7ADL 2.6 23.1 1.4ADL 2.31 ADL 1,2,3,7,8,9 HxCDF 20.3 5.5ADL 2.03 18.6 3.1 ADL J 1.86 17.8 1.7ADL J 1.78ADL 1,2,3,4,6,7,8 HpCDF 53.9 3.8ADL 0.539 29 2.6ADL 0.29 30.2 3.8ADL 0.302ADL 1,2,3,4,7,8,9 HpCDF 51.2 5.2ADL 0.512 43.6 3.5ADL 0.436 40.2 5.2ADL 0.402ADL OCDF 86.2 7.9ADL 0.02586 69 BDL R 0 69 BDL R 0BDL Total TEQ, pg 10459.16 7514.937 7138.791 Total TEQ, ng 10.45916 7.514937 7.138791 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Indicated the Estimated Detection Limit, based on the measured background noise for this target in this sample.Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 768 1.2ADL 768 744 3.5ADL 744 1090 1.3ADL 1090ADL 1,2,3,7,8 PeCDD 705 2.3ADL 705 780 3.2ADL 780 941 18ADL 941 ADL 1,2,3,4,7,8 HxCDD 345 1.5ADL 34.5 271 2.3ADL 27.1 350 1.5ADL 35ADL 1,2,3,6,7,8 HxCDD 414 1.3ADL 41.4 377 1.9ADL 37.7 473 1.3ADL 47.3ADL 1,2,3,7,8,9 HxCDD 908 1.3ADL 90.8 834 2ADL 83.4 1050 1.3ADL 105ADL 1,2,3,4,6,7,8 HpCDD 4150 1.5ADL 41.5 3360 2.7ADL 33.6 5870 1.7ADL 58.7ADL OCDD 39300 1.3ADL 11.79 32400 3ADL 9.72 43400 1.2ADL 13.02ADL 2,3,7,8 TCDF 13.8 0.19ADL 1.38 7.6 BDL R 0 12.3 0.87ADL 1.23BDL 1,2,3,7,8 PeCDF 4.7 BDL R 0 7.52 1.8ADL 0.2256 4.6 BDL R 0BDL 2,3,4,7,8 PeCDF 5.1 BDL R 0 7.26 1.7ADL 2.178 8.42 0.8ADL 2.526BDL 1,2,3,4,7,8 HxCDF 2.7 BDL R 0 2.5 BDL R 0 1.7 BDL R 0BDL 1,2,3,6,7,8 HxCDF 4.6 BDL R 0 5.5 BDL R 0 4.1 BDL R 0BDL 2,3,4,6,7,8 HxCDF 2 BDL R 0 2.67 0.95ADL 0.267 2.1 BDL R 0BDL 1,2,3,7,8,9 HxCDF 1.4 BDL 0 2.27 1.1 ADL 0.227 0.99 BDL 0BDL 1,2,3,4,6,7,8 HpCDF 5.7 BDL R 0 5.9 BDL R 0 4.5 BDL R 0BDL 1,2,3,4,7,8,9 HpCDF 1.9 BDL R 0 2 BDL R 0 0.66 BDL 0BDL OCDF 7.8 BDL R 0 3.8 BDL R 0 6.1 BDL R 0BDL Total TEQ, pg 1694.37 1718.418 2293.776 Total TEQ, ng 1.69437 1.718418 2.293776 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % * EDL - Estimated Detection Limit Run 3 100 0 0 **Dal Italia: Muskogee, OK - Kilns 61/62 Run 1**  **Run 2 Run 3**  **Monarch: Florence, A L - Kiln 77**  **Run 1 Run 2**  **Run 3 Status** 

ADL BDL

ADL BDL**Status**



### CC-Tile Kilns 1

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 1060 38ADL 1060 1250 4.6ADL 1250 1240 8.2ADL 1240ADL 1,2,3,7,8 PeCDD 1440 24ADL M 1440 1500 27ADL M 1500 1410 26ADL M 1410ADL 1,2,3,4,7,8 HxCDD 401 55ADL M 40.1 507 15ADL M 50.7 448 43ADL M 44.8ADL 1,2,3,6,7,8 HxCDD 935 58ADL M 93.5 1010 16ADL M 101 885 45ADL M 88.5ADL 1,2,3,7,8,9 HxCDD 1640 56ADL M 164 1780 15ADL M 178 1610 43ADL M 161 ADL 1,2,3,4,6,7,8 HpCDD 7910 110ADL 79.1 6730 71 ADL 67.3 6680 65ADL 66.8ADL OCDD 68400 8.9ADL 20.52 71200 9ADL 21.36 63500 24ADL 19.05ADL 2,3,7,8 TCDF 8.48 4.9ADL M 0.848 8.34 5ADL M 0.834 9.65 6.6ADL M 0.965ADL 1,2,3,7,8 PeCDF 7.71 3.4ADL J 0.2313 5.8 BDL M, J, R 0 7.2 BDL M, J, R 0BDL 2,3,4,7,8 PeCDF 6.9 BDL M, J, R 0 9.34 2.2ADL M, J 2.802 9.2 BDL M, J, R 0BDL 1,2,3,4,7,8 HxCDF 3.92 3.2ADL M, J 0.392 4.8 BDL M, U 0 4.95 3.1 ADL J 0.495BDL 1,2,3,6,7,8 HxCDF 6.3 BDL M, J, R 0 7.17 4.4ADL M, J 0.717 6.54 2.9ADL J 0.654 BDL 2,3,4,6,7,8 HxCDF 4.2 BDL M, J, R 0 4.6 BDL U 0 4.53 3ADL J 0.453BDL 1,2,3,7,8,9 HxCDF 3.3 BDL M, U 0 5 BDL U 0 4.87 3.3ADL J 0.487BDL 1,2,3,4,6,7,8 HpCDF 9.65 2.5ADL M, J 0.0965 19 2.6ADL M, J 0.19 8.9 BDL J, R 0BDL 1,2,3,4,7,8,9 HpCDF 3.6 BDL M, J, R 0 4.4 BDL M, J, R 0 6.8 BDL M, J, R 0BDL OCDF 11 BDL J, R 0 48 8ADL 0.0144 20.7 18ADL J 0.00621 BDL Total TEQ, pg 2898.788 3172.917 3033.21 Total TEQ, ng 2.898788 3.172917 3.03321 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % * EDL - Estimated Detection Limit Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 1160 1.72ADL 1160 1220 1.39ADL 1220 1340 5.29ADL 1340ADL 1,2,3,7,8 PeCDD 1630 1.57ADL 1630 1730 1.72ADL 1730 2110 1.09ADL 2110ADL 1,2,3,4,7,8 HxCDD 555 1.52ADL 55.5 616 1.87ADL 61.6 780 4.1 ADL 78ADL 1,2,3,6,7,8 HxCDD 805 1.54ADL 80.5 839 2.01 ADL 83.9 1140 4.14ADL 114ADL 1,2,3,7,8,9 HxCDD 1680 1.77ADL 168 1870 2.14ADL 187 2530 4.52ADL 253ADL 1,2,3,4,6,7,8 HpCDD 5780 9.09ADL 57.8 5930 9.74ADL 59.3 10100 10.9ADL 101 ADL OCDD 43200 4.76ADL 12.96 41800 3.71 ADL 12.54 90300 5.13ADL 27.09ADL 2,3,7,8 TCDF 13.9 1.54ADL 1.39 13.4 1.39ADL 1.34 13.5 3.88ADL 1.35ADL 1,2,3,7,8 PeCDF 6.39 1.11 ADL J 0.1917 6.43 1.31 ADL J 0.1929 6.92 3.16ADL J 0.2076ADL 2,3,4,7,8 PeCDF 8.01 1.18ADL J 2.403 7.05 1.3ADL J 2.115 2.77 BDL 0BDL 1,2,3,4,7,8 HxCDF 5.32 1.16ADL J 0.532 4.84 0.985ADL J 0.484 8.62 2.68ADL J 0.862ADL 1,2,3,6,7,8 HxCDF 4.96 1.13ADL J 0.496 5.28 0.915ADL J 0.528 5.78 2.38ADL J 0.578ADL 2,3,4,6,7,8 HxCDF 4.16 BDL J 0 4.36 1.03ADL J 0.436 5.94 2.45ADL J 0.594 BDL 1,2,3,7,8,9 HxCDF 1.48 BDL 0 1.31 BDL 0 3.27 BDL 0BDL 1,2,3,4,6,7,8 HpCDF 8.12 1.53ADL J 0.0812 6.31 1.24ADL J 0.0631 8 2.5ADL J 0.08ADL 1,2,3,4,7,8,9 HpCDF 4.44 2.33ADL J 0.0444 4.99 1.86ADL J 0.0499 7.36 3.16ADL J 0.0736ADL OCDF 14.7 6.41 ADL J 0.00441 12.7 5.19ADL J 0.00381 22.6 9.1 ADL J 0.00678ADL Total TEQ, pg 3169.903 3359.553 4026.842 Total TEQ, ng 3.169903 3.359553 4.026842 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *DL - detection limit Run 3 100 0 0 **Florim: Clarksville, TN May Testing - Kiln 41**

**Run 2 Run 3**  **Status Run 1**  **Run 1 Run 2** 

ADL BDL**Status Run 3** 

**Florim: Clarksville, TN October Testing - Kiln 41**

BDL ADL



### CC-Tile Kilns 2

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 160 1.8ADL 160 208 1.5ADL 208 199 1.8ADL 199ADL 1,2,3,7,8 PeCDD 258 8.2ADL M 258 332 17ADL M 332 348 10ADL M 348ADL 1,2,3,4,7,8 HxCDD 119 9.9ADL 11.9 144 21 ADL 14.4 141 27ADL 14.1 ADL 1,2,3,6,7,8 HxCDD 220 8.9ADL 22 267 19ADL 26.7 236 25ADL 23.6ADL 1,2,3,7,8,9 HxCDD 478 9.4ADL M 47.8 639 20ADL M 63.9 561 26ADL 56.1 ADL 1,2,3,4,6,7,8 HpCDD 2780 33ADL 27.8 3940 60ADL 39.4 3280 48ADL 32.8ADL OCDD 40500 1.1 ADL 12.15 57600 2.3ADL 17.28 53100 2.4ADL 15.93ADL 2,3,7,8 TCDF 45.8 1.3ADL 4.58 67.9 0.96ADL M 6.79 61.2 1.4ADL 6.12ADL 1,2,3,7,8 PeCDF 8.88 1.2ADL M, J 0.2664 12.5 1.5ADL M, J 0.375 12.2 1.1 ADL J 0.366ADL 2,3,4,7,8 PeCDF 38.4 1.2ADL M 11.52 44.9 1.5ADL M 13.47 41.7 1 ADL M 12.51 ADL 1,2,3,4,7,8 HxCDF 9.03 0.93ADL J 0.903 10.9 1.2ADL M, J 1.09 12 0.88ADL J 1.2ADL 1,2,3,6,7,8 HxCDF 4.8 BDL J, R 0 5.3 BDL M, J, R 0 5.93 0.79ADL J 0.593BDL 2,3,4,6,7,8 HxCDF 7.3 BDL J, R 0 8.66 1.1 ADL M, J 0.866 9.75 0.83ADL J 0.975BDL 1,2,3,7,8,9 HxCDF 1 BDL U 0 1.7 BDL M, J, R 0 2.11 0.95ADL J 0.211 BDL 1,2,3,4,6,7,8 HpCDF 5.6 BDL J, R 0 8 BDL M, J, R 0 6.64 0.93ADL M, J 0.0664 BDL 1,2,3,4,7,8,9 HpCDF 1.2 BDL M, J, R 0 1.7 BDL M, J, R 0 2.2 BDL M, J, R 0BDL OCDF 10.2 2.5ADL M, J 0.00306 13.1 3.9ADL M, J 0.00393 15.9 3.1 ADL J 0.00477ADL Total TEQ, pg 556.9225 724.2749 711.5762 Total TEQ, ng 0.556922 0.724275 0.711576 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 38 BDL M, R 0 29 BDL M, R 0 33 BDL M, R 0BDL 1,2,3,7,8 PeCDD 80.6 4.7ADL M 80.6 64.8 1.7ADL M 64.8 61 3.9ADL M, R 61 ADL 1,2,3,4,7,8 HxCDD 57.1 14ADL 5.71 46.3 9.2ADL 4.63 41.2 11 ADL 4.12ADL 1,2,3,6,7,8 HxCDD 73.5 12ADL 7.35 58.3 8.3ADL 5.83 58.8 9.8ADL 5.88ADL 1,2,3,7,8,9 HxCDD 100 13ADL 10 86.8 8.7ADL 8.68 76.1 10ADL 7.61 ADL 1,2,3,4,6,7,8 HpCDD 822 20ADL 8.22 729 24ADL 7.29 665 23ADL 6.65ADL OCDD 7540 5.2ADL 2.262 6560 7.4ADL 1.968 6450 12ADL 1.935ADL 2,3,7,8 TCDF 7 BDL M, R 0 2.91 1.6ADL M, J 0.291 6.52 2.2ADL M 0.652 BDL 1,2,3,7,8 PeCDF 3.87 2.2ADL M, J 0.1161 2.5 BDL M, J, R 0 3.74 2.3ADL J 0.1122 BDL 2,3,4,7,8 PeCDF 6.76 2.2ADL M, J 2.028 3.7 BDL M, J, R 0 5.86 2.3ADL M, J 1.758BDL 1,2,3,4,7,8 HxCDF 2.88 1.5ADL M, J 0.288 2.8 BDL M, J, R 0 2.2 BDL M, J, R 0BDL 1,2,3,6,7,8 HxCDF 2.9 BDL M, J, R 0 3.06 1.4ADL M, J 0.306 2.6 BDL M, J, R 0BDL 2,3,4,6,7,8 HxCDF 2.82 1.4ADL M, J 0.282 2.5 1.5ADL M, J 0.25 2.9 BDL M, J, R 0BDL 1,2,3,7,8,9 HxCDF 1.84 1.6ADL J 0.184 1.7 BDL M, U 0 2.1 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 5.28 1.8ADL M, J 0.0528 4.5 BDL M, J, R 0 7.42 2.7ADL M, J 0.0742 BDL 1,2,3,4,7,8,9 HpCDF 2.2 BDL M, U 0 2.6 BDL U 0 4.3 BDL M, J, R 0BDL OCDF 5.8 BDL M, U 0 6.8 BDL U 0 8.1 BDL M, J, R 0BDL Total TEQ, pg 117.0929 94.045 89.7914 Total TEQ, ng 0.117093 0.094045 0.089791 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit Run 3 100 0 0 **Run 2 Run 3** 

**Dal Tile: El Paso, TX - Kilns 64/65/68/69 Bisque Status** 

**Status Run 3**  **Run 1 Run 2**  **American Marazzi: Sunnyvale, TX - Kiln 84 Run 1** 

ADL BDL

ADL BDL



### CC-Tile Kilns 3

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 3.2 BDL U 0 1.9 BDL U 0 2.1 BDL U 0BDL 1,2,3,7,8 PeCDD 3.21 1.8ADL M, J 3.21 3.14 1.8ADL M, J 3.14 3.71 2.1 ADL M, J 3.71 ADL 1,2,3,4,7,8 HxCDD 2.58 1.9ADL M, J 0.258 3.2 BDL M, U 0 2.3 BDL M, U 0BDL 1,2,3,6,7,8 HxCDD 1.8 BDL M, J, R 0 3.18 2.9ADL M, J 0.318 2.8 BDL M, J, R 0BDL 1,2,3,7,8,9 HxCDD 5.4 BDL M, J, R 0 3.5 BDL M, J, R 0 4.84 2.2ADL M, J 0.484 BDL 1,2,3,4,6,7,8 HpCDD 32.6 6.3ADL M, J, R 0.326 33.6 4.4ADL M 0.336 29.4 3.8ADL M 0.294ADL OCDD 267 12ADL 0.0801 306 9.7ADL 0.0918 202 9.3ADL M 0.0606ADL 2,3,7,8 TCDF 3.7 BDL U 0 2.2 BDL U 0 5.8 BDL U 0BDL 1,2,3,7,8 PeCDF 1.9 BDL M, U 0 2.5 BDL U 0 1.6 BDL U 0BDL 2,3,4,7,8 PeCDF 3.3 BDL J, R 0 3.5 2.4ADL M, J 1.05 2.6 BDL J, R 0BDL 1,2,3,4,7,8 HxCDF 2.89 1.5ADL M, J 0.289 1.3 BDL U 0 1.4 BDL M, J, R 0BDL 1,2,3,6,7,8 HxCDF 2.2 BDL M, J, R 0 1.1 BDL U 0 2 BDL M, J, R 0BDL 2,3,4,6,7,8 HxCDF 2.73 1.4ADL M, J 0.273 2.48 1.2ADL M, J 0.248 2.7 BDL M, J, R 0BDL 1,2,3,7,8,9 HxCDF 1.6 BDL U 0 1.4 BDL U 0 1.3 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 4.8 BDL J, R 0 2.8 BDL M, J, R 0 5.81 1.1 ADL M, J 0.0581 BDL 1,2,3,4,7,8,9 HpCDF 2.7 BDL U 0 2.3 BDL U 0 1.4 BDL M, U 0BDL OCDF 6.8 BDL U 0 7.3 BDL U 0 5.3 BDL U 0BDL Total TEQ, pg 4.4361 5.1838 4.6067 Total TEQ, ng 0.004436 0.005184 0.004607 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL - Estimated detection limit Run 0 0 3 100

**Overall for Clay Ceramics Tile -- WA LL: 2 Kilns** 

Count % Count % Run 3 50 3 50

**Overall for Clay Ceramics Tile -- FLOOR: 5 Kilns**

Count % Count % Run 15 100 0 0 **Run 2 Run 3** 

ADL BDL

ADL BDL ADL BDL**Status Dal Tile: El Paso, TX - Kilns 70/71/74/75 Glost**  **Run 1**



### CC-Tile Kilns 4

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 10 BDL R 0 1 BDL U 0 2.1 BDL U 0BDL 1,2,3,7,8 PeCDD 40.1 2.4ADL 40.1 61 3.9ADL 61 51.3 2.6ADL 51.3ADL 1,2,3,4,7,8 HxCDD 40.6 6.4ADL 4.06 45.1 16ADL 4.51 24.5 9.4ADL 2.45ADL 1,2,3,6,7,8 HxCDD 50.6 5.3ADL 5.06 36 BDL R 0 52.5 7.8ADL 5.25BDL 1,2,3,7,8,9 HxCDD 126 5.5ADL 12.6 158 14ADL 15.8 107 8.1 ADL 10.7ADL 1,2,3,4,6,7,8 HpCDD 1010 15ADL 10.1 1000 17ADL 10 858 9.7ADL 8.58ADL OCDD 31900 1.6ADL 9.57 29300 3.8ADL 8.79 24900 5.3ADL 7.47ADL 2,3,7,8 TCDF 1.3 BDL U 0 1 BDL U 0 1.2 BDL U 0BDL 1,2,3,7,8 PeCDF 1.4 BDL U 0 0.97 BDL U 0 1.1 BDL U 0BDL 2,3,4,7,8 PeCDF 1.4 BDL U 0 0.92 BDL U 0 1.1 BDL U 0BDL 1,2,3,4,7,8 HxCDF 1.2 BDL U 0 0.9 BDL U 0 1.1 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.1 BDL U 0 0.81 BDL U 0 0.98 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.1 BDL U 0 0.87 BDL U 0 1 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.3 BDL U 0 1 BDL U 0 1.2 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1.4 BDL U 0 1.3 BDL U 0 1 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.9 BDL U 0 1.7 BDL U 0 1.4 BDL U 0BDL OCDF 7.53 1.5ADL J, B 0.002259 1.8 BDL U 0 6.1 BDL J, R 0BDL Total TEQ, pg 81.49226 100.1 85.75 Total TEQ, ng 0.081492 0.1001 0.08575 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % * EDL - Estimated Detection Limit Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 28 BDL R 0 26 BDL R 0 69.9 1.7ADL 69.9BDL 1,2,3,7,8 PeCDD 11.7 1.4ADL 11.7 9.14 2ADL 9.14 21.1 0.94ADL 21.1 ADL 1,2,3,4,7,8 HxCDD 5.56 2ADL 0.556 1 BDL R 0 5.1 BDL R 0BDL 1,2,3,6,7,8 HxCDD 5.22 1.7ADL 0.522 2 BDL R 0 3 BDL R 0BDL 1,2,3,7,8,9 HxCDD 18.5 1.7ADL 1.85 6.9 BDL R 0 12 BDL R 0BDL 1,2,3,4,6,7,8 HpCDD 100 7.7ADL 1 39.9 4.3ADL 0.399 59.4 5.7ADL 0.594ADL OCDD 1750 1.2ADL 0.525 842 0.9ADL 0.2526 899 3.6ADL 0.2697ADL 2,3,7,8 TCDF 0.79 BDL 0 0.83 BDL 0 1 BDL 0BDL 1,2,3,7,8 PeCDF 4.1 BDL R 0 0.74 BDL 0 1.3 BDL 0BDL 2,3,4,7,8 PeCDF 1.8 BDL R 0 1.9 BDL R 0 2 BDL R 0BDL 1,2,3,4,7,8 HxCDF 6.8 BDL R 0 0.62 BDL 0 0.69 BDL 0BDL 1,2,3,6,7,8 HxCDF 2.5 BDL R 0 0.56 BDL 0 0.62 BDL 0BDL 2,3,4,6,7,8 HxCDF 0.82 BDL R 0 0.6 BDL 0 0.66 BDL 0BDL 1,2,3,7,8,9 HxCDF 0.42 BDL 0 0.71 BDL 0 0.78 BDL 0BDL 1,2,3,4,6,7,8 HpCDF 16 BDL R 0 1.6 BDL R 0 1.2 BDL 0BDL 1,2,3,4,7,8,9 HpCDF 2.6 BDL R 0 0.92 BDL 0 1.6 BDL 0BDL OCDF 41.6 1.5ADL 0.01248 1.34 0.65ADL 0.000402 2.8 BDL 0BDL Total TEQ, pg 16.16548 9.792002 91.8637 Total TEQ, ng 0.016165 0.009792 0.091864 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL ADL

Count % Count % * EDL - Estimated Detection Limit Run 1 33.333333 2 66.66667 **Monarch: Florence, A L - Press Dryer D-1** 

**Status**

**Run 1 Run 2**  **Run 3 Status** 

BDL **Run 1 Run 2**  **Run 3**

ADL BDL

ADL **Dal Italia: Muskogee, OK - Press Dryer VD#9**



### CC-Tile Press Dryers 1

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 30.5 2.39ADL 30.5 12.7 1.31 ADL 12.7 22.2 1.17ADL 22.2ADL 1,2,3,7,8 PeCDD 28.5 2.34ADL J 28.5 13.5 1.58ADL J 13.5 19.5 1.34ADL J 19.5ADL 1,2,3,4,7,8 HxCDD 17.7 2.68ADL J 1.77 8.58 1.64ADL J 0.858 10.5 1.39ADL J 1.05ADL 1,2,3,6,7,8 HxCDD 29.6 2.77ADL J 2.96 13.8 1.63ADL J 1.38 18.2 1.44ADL J 1.82ADL 1,2,3,7,8,9 HxCDD 69.5 2.85ADL 6.95 38 1.67ADL J 3.8 48.9 1.51 ADL J 4.89ADL 1,2,3,4,6,7,8 HpCDD 710 6.78ADL 7.1 291 3.19ADL 2.91 359 3.77ADL 3.59ADL OCDD 13200 5.76ADL 3.96 8050 3.25ADL 2.415 11700 2.99ADL 3.51 ADL 2,3,7,8 TCDF 2.17 BDL 0 1.07 BDL 0 1.17 BDL 0BDL 1,2,3,7,8 PeCDF 1.92 BDL 0 1.02 BDL 0 0.897 BDL 0BDL 2,3,4,7,8 PeCDF 1.92 BDL 0 1.03 BDL 0 0.886 BDL 0BDL 1,2,3,4,7,8 HxCDF 3.56 1.29ADL J 0.356 3.83 0.806ADL J 0.383 1.91 0.626ADL J 0.191 ADL 1,2,3,6,7,8 HxCDF 1.16 BDL 0 0.779 BDL 0 0.573 BDL 0BDL 2,3,4,6,7,8 HxCDF 1.23 BDL 0 0.869 BDL 0 0.639 BDL 0BDL 1,2,3,7,8,9 HxCDF 1.82 BDL 0 1.16 BDL 0 0.82 BDL 0BDL 1,2,3,4,6,7,8 HpCDF 2.05 BDL 0 1.82 BDL J 0 1.24 BDL J 0BDL 1,2,3,4,7,8,9 HpCDF 4.3 BDL 0 2.25 BDL 0 1.76 BDL 0BDL OCDF 34.9 BDL 0 31.3 BDL 0 4.91 BDL 0BDL Total TEQ, pg 82.096 37.946 56.751 Total TEQ, ng 0.082096 0.037946 0.056751 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *DL - detection lilmit Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 2.5 BDL J, R 0 2.2 BDL M, J, R 0 1.5 BDL U 0BDL 1,2,3,7,8 PeCDD 1.6 BDL M, J, R 0 1.63 1.3ADL M, J 1.63 1.5 BDL M, J, R 0BDL 1,2,3,4,7,8 HxCDD 1.8 BDL U 0 1.7 BDL U 0 1.3 BDL U 0BDL 1,2,3,6,7,8 HxCDD 1.6 BDL M, U 0 1.5 BDL U 0 1.2 BDL U 0BDL 1,2,3,7,8,9 HxCDD 1.7 BDL M, U 0 2.2 BDL M, J, R 0 2 BDL J, R 0BDL 1,2,3,4,6,7,8 HpCDD 8.3 BDL M, J, R 0 10.4 2.9ADL M, J 0.104 10.1 2.1 ADL M, J 0.101 BDL OCDD 215 6.4ADL 0.0645 233 3.9ADL 0.0699 210 2.7ADL M 0.063ADL 2,3,7,8 TCDF 1.2 BDL U 0 1.6 BDL U 0 1.8 BDL U 0BDL 1,2,3,7,8 PeCDF 0.84 BDL M, U 0 0.92 BDL U 0 0.74 BDL U 0BDL 2,3,4,7,8 PeCDF 0.82 BDL M, U 0 0.9 BDL U 0 1 BDL M, J, R 0BDL 1,2,3,4,7,8 HxCDF 0.81 BDL U 0 0.81 BDL U 0 0.56 BDL U 0BDL 1,2,3,6,7,8 HxCDF 0.72 BDL U 0 0.73 BDL U 0 0.5 BDL U 0BDL 2,3,4,6,7,8 HxCDF 0.76 BDL U 0 0.77 BDL U 0 0.53 BDL U 0BDL 1,2,3,7,8,9 HxCDF 0.88 BDL U 0 0.88 BDL U 0 0.61 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1.42 1.4ADL M, J 0.0142 0.6 BDL U 0 1.4 0.5ADL M, J 0.014 BDL 1,2,3,4,7,8,9 HpCDF 1.7 BDL U 0 0.74 BDL U 0 0.61 BDL U 0BDL OCDF 3.3 BDL M, U 0 1.3 BDL U 0 1.3 1.3BDL U 0BDL Total TEQ, pg 0.0787 1.8039 0.178 Total TEQ, ng 7.87E-05 0.001804 0.000178 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL - Estimated detection limit. Run 0 0 3 100 **Status Run 1**  **Run 2** ADL

**American Marazzi: Sunnyvale, TX - Press Dryer DC-10 Run 2** 

BDL **Run 3 Florim: Clarksville, TN - Press Dryer VD-1** 

**Status Run 1** 

**Run 3**

ADL BDL



### CC-Tile Press Dryers 2

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 2.4 BDL U 0 1.2 BDL U 0 0.98 BDL U 0BDL 1,2,3,7,8 PeCDD 1.8 BDL M, U 0 2.7 1.3ADL M, J 2.7 1.24 0.85ADL M, J 1.24BDL 1,2,3,4,7,8 HxCDD 3.9 BDL U 0 3 BDL U 0 1.7 BDL U 0BDL 1,2,3,6,7,8 HxCDD 3.5 BDL U 0 2.7 BDL U 0 1.5 BDL M, U 0BDL 1,2,3,7,8,9 HxCDD 4.3 BDL M, J, U 0 6.8 BDL M, J, R 0 3.92 1.6ADL M, J 0.392 BDL 1,2,3,4,6,7,8 HpCDD 56.3 4.8ADL M 0.563 55.2 4ADL M 0.552 42.1 3.7ADL M 0.421 ADL OCDD 856 11 ADL 0.2568 1020 6ADL 0.306 751 9.3ADL M 0.2253ADL 2,3,7,8 TCDF 1.7 BDL U 0 1.2 BDL U 0 1.3 BDL U 0BDL 1,2,3,7,8 PeCDF 1.5 BDL U 0 1.1 BDL U 0 1.2 BDL U 0BDL 2,3,4,7,8 PeCDF 1.5 BDL U 0 1.1 BDL M, U 0 1.2 BDL U 0BDL 1,2,3,4,7,8 HxCDF 1.3 BDL U 0 1.1 BDL U 0 0.85 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.1 BDL U 0 0.98 BDL U 0 0.76 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.2 BDL M, U 0 1 BDL U 0 0.81 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.4 BDL U 0 1.2 BDL U 0 0.93 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 2.7 BDL M, J, R 0 1.3 BDL U 0 1.3 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 2.2 BDL U 0 1.6 BDL U 0 1.6 BDL U 0BDL OCDF 4.9 BDL U 0 4.7 BDL U 0 4.2 BDL U 0BDL Total TEQ, pg 0.8198 3.558 2.2783 Total TEQ, ng 0.00082 0.003558 0.002278 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL - Estimated detection limit. Run 0 0 3 100

**Overall for Clay Ceramics Tile -- WA LL: 1 Press Dryer** 

Count % Count % Run 0 0 3 100

**Overall for Clay Ceramics Tile -- FLOOR: 4 Press Dryers**

Count % Count % Run 7 58 5 42 **Run 2 Run 3**  **Status Dal Tile: El Paso, TX - Press Dryer DC-5**  **Run 1**

ADL BDL

ADL BDL ADL BDL



### CC-Tile Press Dryers 3

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Spray Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 82.4 1.4ADL 82.4 82 2.4ADL 82 73.4 0.2ADL 73.4ADL 1,2,3,7,8 PeCDD 212 5.5ADL 212 236 6.9ADL 236 198 11 ADL 198ADL 1,2,3,4,7,8 HxCDD 107 20ADL 10.7 136 14ADL 13.6 95.6 21 ADL 9.56ADL 1,2,3,6,7,8 HxCDD 205 17ADL 20.5 183 12ADL 18.3 127 18ADL 12.7ADL 1,2,3,7,8,9 HxCDD 480 17ADL 48 515 13ADL 51.5 351 18ADL 35.1 ADL 1,2,3,4,6,7,8 HpCDD 3490 41 ADL 34.9 3090 42ADL 30.9 2350 49ADL 23.5ADL OCDD 105000 4.7ADL 31.5 104000 6.6ADL 31.2 84000 4ADL 25.2ADL 2,3,7,8 TCDF 1.4 BDL U 0 1.8 BDL U 0 1.3 BDL U 0BDL 1,2,3,7,8 PeCDF 1.6 BDL U 0 2 BDL U 0 1.6 BDL U 0BDL 2,3,4,7,8 PeCDF 1.5 BDL U 0 3.2 BDL J, R 0 1.6 BDL U 0BDL 1,2,3,4,7,8 HxCDF 1.5 BDL U 0 1.4 BDL U 0 0.8 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.3 BDL U 0 1.3 BDL U 0 0.72 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.4 BDL U 0 1.4 BDL U 0 0.77 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.7 BDL U 0 1.6 BDL U 0 0.91 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1.7 BDL U 0 1.4 BDL U 0 1.1 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 2.3 BDL U 0 1.9 BDL U 0 1.5 BDL U 0BDL OCDF 20.3 1.2ADL J 0.00609 12 BDL J, R 0 14 BDL J, R 0BDL Total TEQ, pg 440.0061 463.5 377.46 Total TEQ, ng 0.440006 0.4635 0.37746 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % * EDL - Estimated Detection Limit Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 13 BDL R 0 14 BDL R 0 20 1 ADL 20 BDL 1,2,3,7,8 PeCDD 8.5 BDL J, R 0 37.1 2.3ADL 37.1 26.8 3.1 ADL 26.8BDL 1,2,3,4,7,8 HxCDD 15 1.8ADL J 1.5 5.1 BDL J, R 0 16 BDL J, R 0BDL 1,2,3,6,7,8 HxCDD 8.6 BDL J, R 0 12 BDL J, R 0 8.5 BDL J, R 0BDL 1,2,3,7,8,9 HxCDD 32.2 1.6ADL 3.22 19 BDL J, R 0 29.8 1.7ADL 2.98BDL 1,2,3,4,6,7,8 HpCDD 231 9.8ADL 2.31 228 5ADL 2.28 225 7.1 ADL 2.25ADL OCDD 4250 4ADL 1.275 4320 3.3ADL 1.296 4910 4.1 ADL 1.473ADL 2,3,7,8 TCDF 1.3 BDL U 0 1.6 BDL U 0 1.7 BDL U 0BDL 1,2,3,7,8 PeCDF 1.3 BDL U 0 1.5 BDL U 0 1.4 BDL U 0BDL 2,3,4,7,8 PeCDF 1.2 BDL U 0 1.5 BDL U 0 1.3 BDL U 0BDL 1,2,3,4,7,8 HxCDF 0.81 BDL U 0 1.1 BDL U 0 1.2 BDL U 0BDL 1,2,3,6,7,8 HxCDF 0.73 BDL U 0 1 BDL U 0 1.1 BDL U 0BDL 2,3,4,6,7,8 HxCDF 0.77 BDL U 0 1.1 BDL U 0 1.2 BDL U 0BDL 1,2,3,7,8,9 HxCDF 0.91 BDL U 0 1.3 BDL U 0 1.4 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1 BDL J, R 0 20 BDL J, R 0 1.6 BDL J, R 0BDL 1,2,3,4,7,8,9 HpCDF 1.3 BDL U 0 2.3 BDL U 0 1.7 BDL U 0BDL OCDF 2.73 1.8ADL J, B 0.000819 22 BDL J, R 0 5.6 BDL J, R 0BDL Total TEQ, pg 8.305819 40.676 53.503 Total TEQ, ng 0.008306 0.040676 0.053503 Compare to Utilities TEQ EDL (0.018 ng) BDL ADL ADL

Count % Count % * EDL - Estimated Detection Limit Run 2 66.666667 1 33.33333 **Monarch: Florence, A L - Spray Dryer SD-1**  **Run 3 Status** 

**Run 1 Monarch: Florence, A** **L - Spray Dryer SD-2 Run 2**  **Run 1**

ADL BDL

**Run 2 Run 3**  **Status**

ADL BDL



### CC-Tile Spray Dryers 1

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Spray Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 59.3 0.97ADL 59.3 72.9 2ADL 72.9 51 1.6ADL 51 ADL 1,2,3,7,8 PeCDD 38.4 1.9ADL 38.4 52.9 2.4ADL 52.9 37 2.4ADL 37ADL 1,2,3,4,7,8 HxCDD 8.9 BDL R 0 9.1 BDL R 0 12 2.5ADL 1.2 BDL 1,2,3,6,7,8 HxCDD 15 BDL R 0 25.4 3ADL 2.54 13 BDL R 0BDL 1,2,3,7,8,9 HxCDD 76.9 2.4ADL 7.69 84.5 3.1 ADL 8.45 65.3 2.2ADL 6.53ADL 1,2,3,4,6,7,8 HpCDD 285 2.4ADL 2.85 261 2.2ADL 2.61 299 2.4ADL 2.99ADL OCDD 7260 0.82ADL 2.178 6540 0.7ADL 1.962 9910 1.2ADL 2.973ADL 2,3,7,8 TCDF 2.4 BDL 0 1.9 BDL 0 1.4 BDL 0BDL 1,2,3,7,8 PeCDF 1.3 BDL 0 0.99 BDL 0 0.56 BDL 0BDL 2,3,4,7,8 PeCDF 1.5 BDL R 0 0.94 BDL 0 0.54 BDL 0BDL 1,2,3,4,7,8 HxCDF 0.95 BDL 0 0.88 BDL 0 0.7 BDL R 0BDL 1,2,3,6,7,8 HxCDF 0.86 BDL 0 0.79 BDL 0 0.41 BDL 0BDL 2,3,4,6,7,8 HxCDF 0.92 BDL 0 2.3 BDL R 0 0.44 BDL 0BDL 1,2,3,7,8,9 HxCDF 1.1 BDL 0 1 BDL 0 0.52 BDL 0BDL 1,2,3,4,6,7,8 HpCDF 2.1 BDL R 0 1.3 BDL 0 0.76 BDL 0BDL 1,2,3,4,7,8,9 HpCDF 1.8 BDL 0 1.7 BDL 0 1 BDL 0BDL OCDF 4 BDL R 0 2.3 BDL R 0 2.6 BDL R 0BDL Total TEQ, pg 110.418 141.362 101.693 Total TEQ, ng 0.110418 0.141362 0.101693 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % * EDL - Estimated Detection Limit. Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 1290 1.93ADL 1290 919 3.97ADL 919 603 1.35ADL 603ADL 1,2,3,7,8 PeCDD 1520 2.07ADL 1520 1160 4.02ADL 1160 793 1.45ADL 793ADL 1,2,3,4,7,8 HxCDD 605 2.53ADL 60.5 461 5.95ADL 46.1 387 2.25ADL 38.7ADL 1,2,3,6,7,8 HxCDD 981 2.63ADL 98.1 719 5.76ADL 71.9 628 2.29ADL 62.8ADL 1,2,3,7,8,9 HxCDD 2400 2.82ADL 240 1790 7.05ADL 179 1650 2.62ADL 165ADL 1,2,3,4,6,7,8 HpCDD 14800 9.87ADL 148 10900 14ADL 109 12300 10.9ADL 123ADL OCDD 467000 4.54ADL 140.1 301000 8.01 ADL 90.3 380000 4.03ADL 114ADL 2,3,7,8 TCDF 1.59 BDL 0 3.27 BDL 0 4.32 1.47ADL J 0.432 BDL 1,2,3,7,8 PeCDF 1.43 BDL 0 2.1 BDL 0 1.3 BDL 0BDL 2,3,4,7,8 PeCDF 1.38 BDL 0 2.03 BDL 0 1.26 BDL 0BDL 1,2,3,4,7,8 HxCDF 1.41 BDL 0 2.59 2.59ADL 0.259 4.73 1.24ADL J 0.473BDL 1,2,3,6,7,8 HxCDF 1.39 BDL 0 2.41 BDL 0 1.17 BDL 0BDL 2,3,4,6,7,8 HxCDF 1.38 BDL 0 2.59 BDL 0 1.27 BDL 0BDL 1,2,3,7,8,9 HxCDF 1.97 BDL 0 3.48 BDL 0 1.75 BDL 0BDL 1,2,3,4,6,7,8 HpCDF 3.62 BDL J 0 3.55 BDL 0 3.96 1.93ADL J 0.0396BDL 1,2,3,4,7,8,9 HpCDF 3.67 BDL 0 5.77 BDL 0 2.85 BDL 0BDL OCDF 68.1 9.37ADL J 0.02043 36.8 13.3ADL J 0.01104 53.2 7.98ADL J 0.01596ADL Total TEQ, pg 3496.72 2575.57 1900.461 Total TEQ, ng 3.49672 2.57557 1.900461 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *DL - detection limit Run 3 100 0 0 **Run 2 Status**  **Run 2 Run 3** 

**Run 3 Run 1**  **Florim: Clarksville, TN - Spray Dryer SD-2 Run 1** 

ADL **Dal Italia: Muskogee, OK - Spray Dryer SD-1**

BDL

ADL BDL**Status**



### CC-Tile Spray Dryers 2

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Spray Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 4.1 BDL M, R 0 4.7 BDL M, R 0 3 BDL J, R 0BDL 1,2,3,7,8 PeCDD 1.2 BDL M,U 0 1.5 BDL M, U 0 1.2 BDL U 0BDL 1,2,3,4,7,8 HxCDD 1.9 BDL U 0 1.4 BDL U 0 1.3 BDL U 0BDL 1,2,3,6,7,8 HxCDD 1.7 BDL U 0 1.2 BDL U 0 1.2 BDL U 0BDL 1,2,3,7,8,9 HxCDD 1.8 BDL U 0 1.3 BDL U 0 1.3 BDL U 0BDL 1,2,3,4,6,7,8 HpCDD 5.48 1.3ADL J 0.0548 3.9 1.2ADL M, J 0.039 3 BDL M, J, R 0BDL OCDD 58.6 1.8ADL M 0.01758 70.9 1.7ADL 0.02127 43.8 1.6ADL M 0.01314ADL 2,3,7,8 TCDF 1.4 BDL U 0 1.8 BDL U 0 2 BDL U 0BDL 1,2,3,7,8 PeCDF 0.84 BDL U 0 1.1 BDL U 0 0.92 BDL U 0BDL 2,3,4,7,8 PeCDF 0.87 BDL M, J, R 0 1.1 BDL U 0 0.9 BDL U 0BDL 1,2,3,4,7,8 HxCDF 0.74 BDL U 0 0.97 BDL U 0 0.57 BDL U 0BDL 1,2,3,6,7,8 HxCDF 0.66 BDL U 0 0.87 BDL U 0 0.51 BDL U 0BDL 2,3,4,6,7,8 HxCDF 0.7 BDL U 0 0.92 BDL U 0 0.54 BDL U 0BDL 1,2,3,7,8,9 HxCDF 0.81 BDL U 0 1.1 BDL U 0 0.62 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 0.85 BDL U 0 0.94 BDL M, J, R 0 1.1 BDL M, J, R 0BDL 1,2,3,4,7,8,9 HpCDF 1 BDL U 0 0.81 BDL U 0 0.86 BDL U 0BDL OCDF 1.6 BDL M, U 0 2.12 1.3ADL M, J 0.000636 0.93 BDL U 0BDL Total TEQ, pg 0.07238 0.060906 0.01314 Total TEQ, ng 7.24E-05 6.09E-05 1.31E-05 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % * EDL - Estimated Detection Limit Run 0 0 3 100

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 4 BDL M, R 0 4.8 BDL M, R 0 3.3 BDL M, J, R 0BDL 1,2,3,7,8 PeCDD 18.7 1.9ADL M, J 18.7 22.8 2.1 ADL M 22.8 14.9 0.65ADL M, J 14.9ADL 1,2,3,4,7,8 HxCDD 21.3 6.5ADL 2.13 27.1 8ADL M 2.71 17.7 5ADL J 1.77ADL 1,2,3,6,7,8 HxCDD 30.2 5.5ADL 3.02 34.3 6.8ADL M 3.43 23.6 4.3ADL 2.36ADL 1,2,3,7,8,9 HxCDD 67.8 5.8ADL 6.78 76.6 7.1 ADL M 7.66 52.4 4.5ADL 5.24ADL 1,2,3,4,6,7,8 HpCDD 739 27ADL 7.39 873 25ADL M 8.73 593 14ADL 5.93ADL OCDD 28800 50ADL 8.64 33200 130ADL 9.96 24200 92ADL 7.26ADL 2,3,7,8 TCDF 0.94 BDL U 0 0.65 BDL U 0 0.808 0.54ADL M, J 0.0808BDL 1,2,3,7,8 PeCDF 1.2 BDL U 0 0.95 BDL U 0 0.82 BDL U 0BDL 2,3,4,7,8 PeCDF 1.2 BDL U 0 0.96 BDL U 0 0.83 BDL U 0BDL 1,2,3,4,7,8 HxCDF 0.91 BDL U 0 0.62 BDL U 0 0.72 BDL U 0BDL 1,2,3,6,7,8 HxCDF 0.8 BDL U 0 0.54 BDL U 0 0.63 BDL U 0BDL 2,3,4,6,7,8 HxCDF 0.87 BDL U 0 0.58 BDL U 0 0.69 BDL U 0BDL 1,2,3,7,8,9 HxCDF 0.99 BDL U 0 0.66 BDL U 0 0.78 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1.2 BDL U 0 1.1 BDL M, J, R 0 0.84 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.5 BDL U 0 1.2 BDL U 0 1.1 BDL U 0BDL OCDF 4.87 3.1 ADL M, J 0.001461 3.2 BDL M, U 0 4.5 BDL M, J, R 0BDL Total TEQ, pg 46.66146 55.29 37.5408 Total TEQ, ng 0.046661 0.05529 0.037541 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % * EDL - Estimated Detection Limit Run 3 100 0 0

**Overall for Clay Ceramics Tile -- WA LL: 1 Spray Dryer**  **American Marazzi: Sunnyvale, TX - Spray Dryer SD-3**

ADL BDL

ADL BDL **Dal Tile: El Paso, TX - Spray Dryer SD-1**

**Status Run 3**  **Run 1 Run 2**  **Run 1 Run 2**  **Run 3 Status** 



### CC-Tile Spray Dryers 3

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Tile Spray Dryers

Count % Count % Run 3 100 0 0

**Overall for Clay Ceramics Tile -- FLOOR: 5 Spray Dryers**

Count % Count % Run 11 73 4 27 ADL BDL ADL BDL



### CC-Tile Spray Dryers 4

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 103 1 ADL 103 89.2 2.2ADL 89.2 89.4 0.99ADL 89.4ADL 1,2,3,7,8 PeCDD 372 3.8ADL 372 346 12ADL 346 471 4.1 ADL 471 ADL 1,2,3,4,7,8 HxCDD 234 2.8ADL 23.4 231 15ADL 23.1 170 3.1 ADL 17ADL 1,2,3,6,7,8 HxCDD 481 3.1 ADL 48.1 435 17ADL 43.5 479 3.4ADL 47.9ADL 1,2,3,7,8,9 HxCDD 783 2.9ADL 78.3 743 16ADL 74.3 755 3.2ADL 75.5ADL 1,2,3,4,6,7,8 HpCDD 4850 2.2ADL 48.5 4520 4.2ADL 45.2 4980 8.3ADL 49.8ADL OCDD 40200 1.1 ADL 12.06 37400 4.3ADL 11.22 42100 3ADL 12.63ADL 2,3,7,8 TCDF 36 BDL R 0 38.1 1.4ADL 3.81 40.8 3.2ADL 4.08BDL 1,2,3,7,8 PeCDF 14 2.3ADL J 0.42 12.3 4ADL J 0.369 13.9 3.2ADL J 0.417ADL 2,3,4,7,8 PeCDF 22 BDL R 0 23 3.8ADL 6.9 22.8 3.1 ADL 6.84BDL 1,2,3,4,7,8 HxCDF 3 BDL J, R 0 7.46 1.5ADL J 0.746 8.2 BDL U 0BDL 1,2,3,6,7,8 HxCDF 6.1 BDL J, R 0 4.2 BDL J, R 0 7.5 BDL U 0BDL 2,3,4,6,7,8 HxCDF 3.5 BDL J, R 0 2.6 BDL J, R 0 7.9 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.6 BDL U 0 1.7 BDL U 0 9 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 6 BDL J, R 0 4.94 1.4ADL J 0.0494 7.78 7.4ADL J 0.0778BDL 1,2,3,4,7,8,9 HpCDF 0.91 BDL U 0 1.8 BDL U 0 9.4 BDL U 0BDL OCDF 8.2 BDL J, R 0 12.7 1.1 ADL J 0.00381 10.2 2.2ADL J 0.00306BDL Total TEQ, pg 685.78 644.3982 774.6479 Total TEQ, ng 0.68578 0.644398 0.774648 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 4.1 BDL U 0 2.5 BDL U 0 3.2 BDL U 0BDL 1,2,3,7,8 PeCDD 4.2 BDL U 0 4.15 2ADL J 4.15 3 BDL U 0BDL 1,2,3,4,7,8 HxCDD 2.9 BDL U 0 2.7 BDL J, R 0 2.4 BDL U 0BDL 1,2,3,6,7,8 HxCDD 3.2 BDL U 0 2.7 BDL J, R 0 2.9 BDL J, R 0BDL 1,2,3,7,8,9 HxCDD 4.1 BDL J, R 0 10 2.1 ADL J 1 2.9 BDL J, R 0BDL 1,2,3,4,6,7,8 HpCDD 34.5 2.8ADL 0.345 55.3 3.6ADL 0.553 21.1 2.3ADL 0.211 ADL OCDD 349 4.6ADL 0.1047 578 5.1 ADL 0.1734 128 4ADL 0.0384ADL 2,3,7,8 TCDF 7.1 BDL U 0 3.2 BDL J, R 0 7.81 2.3ADL 0.781 BDL 1,2,3,7,8 PeCDF 2.4 BDL U 0 2.6 BDL U 0 3.3 BDL U 0BDL 2,3,4,7,8 PeCDF 2.3 BDL U 0 2.5 BDL U 0 4.36 3.2ADL J 1.308BDL 1,2,3,4,7,8 HxCDF 1.6 BDL J, R 0 4.9 BDL U 0 3 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.3 BDL U 0 4.4 BDL U 0 2.8 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.3 BDL U 0 4.7 BDL U 0 2.9 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.5 BDL U 0 5.3 BDL U 0 3.3 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1.1 BDL U 0 0.83 BDL J, R 0 1.1 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.4 BDL U 0 0.95 BDL U 0 1.4 BDL U 0BDL OCDF 2.1 BDL U 0 1.6 BDL U 0 2 BDL U 0BDL Total TEQ, pg 0.4497 5.8764 2.3384 Total TEQ, ng 0.00045 0.005876 0.002338 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL - Estimated detection limit. Run 0 0 3 100 **Run 1 Run 2**  **Run 3**

**Run 3 Kohler SC - Kiln 2 POC Stack**  **Kohler WI - Kiln 19**

**Status**

**Run 1 Run 2**  **Status** ADL BDL

ADL BDL



### CC-Sanitaryware Kilns 1

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 180 7.7ADL 180 43.9 9.6ADL 43.9 19 BDL R 0BDL 1,2,3,7,8 PeCDD 1540 29ADL 1540 180 26ADL 180 75.1 9.6ADL 75.1 ADL 1,2,3,4,7,8 HxCDD 2500 140ADL 250 238 23ADL 23.8 57.8 7.2ADL 5.78ADL 1,2,3,6,7,8 HxCDD 3300 150ADL 330 261 25ADL 26.1 63 7.9ADL 6.3ADL 1,2,3,7,8,9 HxCDD 6350 140ADL 635 565 24ADL 56.5 188 7.4ADL 18.8ADL 1,2,3,4,6,7,8 HpCDD 50700 1300ADL 507 4250 190ADL 42.5 949 45ADL 9.49ADL OCDD 484000 22ADL 145.2 39900 11 ADL 11.97 8380 5.3ADL 2.514ADL 2,3,7,8 TCDF 43 BDL R 0 27 BDL U 0 8 BDL U 0BDL 1,2,3,7,8 PeCDF 29 9.8ADL 0.87 9.9 BDL U 0 6 BDL U 0BDL 2,3,4,7,8 PeCDF 92 BDL R 0 15.2 9.5ADL J 4.56 5.8 BDL U 0BDL 1,2,3,4,7,8 HxCDF 46 BDL U 0 7.7 BDL U 0 2.6 BDL U 0BDL 1,2,3,6,7,8 HxCDF 42 BDL U 0 7 BDL U 0 2.4 BDL U 0BDL 2,3,4,6,7,8 HxCDF 44 BDL U 0 7.4 BDL U 0 2.6 BDL U 0BDL 1,2,3,7,8,9 HxCDF 50 BDL U 0 8.4 BDL U 0 2.9 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 49.6 12ADL 0.496 8.5 BDL U 0 3.2 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 16 BDL U 0 11 BDL U 0 4.1 BDL U 0BDL OCDF 190 18ADL 0.057 12 BDL U 0 3.1 BDL U 0BDL Total TEQ, pg 3588.623 389.33 117.984 Total TEQ, ng 3.588623 0.38933 0.117984 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit. Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 55.2 3.4ADL 55.2 48 BDL R 0 41.5 3.5ADL 41.5BDL 1,2,3,7,8 PeCDD 226 11 ADL 226 270 14ADL 270 197 2.6ADL 197ADL 1,2,3,4,7,8 HxCDD 199 22ADL 19.9 246 24ADL 24.6 194 12ADL 19.4ADL 1,2,3,6,7,8 HxCDD 262 24ADL 26.2 378 26ADL 37.8 246 13ADL 24.6ADL 1,2,3,7,8,9 HxCDD 574 23ADL 57.4 874 24ADL 87.4 506 13ADL 50.6ADL 1,2,3,4,6,7,8 HpCDD 3590 98ADL 35.9 5480 170ADL 54.8 3070 8.4ADL 30.7ADL OCDD 31700 20ADL 9.51 54000 11 ADL 16.2 25300 8.7ADL 7.59ADL 2,3,7,8 TCDF 21 BDL U 0 19 BDL U 0 99 BDL U 0BDL 1,2,3,7,8 PeCDF 5.5 BDL U 0 8.6 BDL U 0 11 BDL U 0BDL 2,3,4,7,8 PeCDF 12 BDL J, R 0 8.3 BDL U 0 11 BDL U 0BDL 1,2,3,4,7,8 HxCDF 3 BDL U 0 18 BDL U 0 13 BDL U 0BDL 1,2,3,6,7,8 HxCDF 2.8 BDL U 0 17 BDL U 0 13 BDL U 0BDL 2,3,4,6,7,8 HxCDF 2.9 BDL U 0 18 BDL U 0 13 BDL U 0BDL 1,2,3,7,8,9 HxCDF 3.3 BDL U 0 20 BDL U 0 14 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 4.7 BDL U 0 2.5 BDL J, R 0 5.6 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 6 BDL U 0 3.2 BDL U 0 7.1 BDL U 0BDL OCDF 8.6 BDL U 0 21.7 4.6ADL J 0.00651 7.8 BDL U 0BDL Total TEQ, pg 430.11 490.8065 371.39 Total TEQ, ng 0.43011 0.490807 0.37139 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit. Run 3 100 0 0 ADL BDL **Run 1 Run 2**  **Run 3 Run 1**  **Run 2**

**Status Run 3**  **Status**

**Kohler SC - Kiln 2 FE Stack** ADL BDL **Kohler SC - Kiln 2 EE Stack**



### CC-Sanitaryware Kilns 2

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 121 12ADL 121 120 BDL R 0 112 8.8ADL 112 BDL 1,2,3,7,8 PeCDD 494 21 ADL 494 539 15ADL 539 507 11 ADL 507ADL 1,2,3,4,7,8 HxCDD 350 BDL R 0 438 28ADL 43.8 422 23ADL 42.2 BDL 1,2,3,6,7,8 HxCDD 350 BDL R 0 483 30ADL 48.3 566 25ADL 56.6BDL 1,2,3,7,8,9 HxCDD 933 41 ADL 93.3 1200 29ADL 120 1550 23ADL 155ADL 1,2,3,4,6,7,8 HpCDD 6650 90ADL 66.5 7260 44ADL 72.6 7070 81 ADL 70.7ADL OCDD 44000 41 ADL 13.2 45300 31 ADL 13.59 46000 48ADL 13.8ADL 2,3,7,8 TCDF 9.1 BDL U 0 10 BDL U 0 9.9 BDL U 0BDL 1,2,3,7,8 PeCDF 14.1 9.9ADL J 0.423 9.5 BDL J, R 0 10 BDL U 0BDL 2,3,4,7,8 PeCDF 9.6 BDL U 0 8.1 BDL U 0 9.7 BDL U 0BDL 1,2,3,4,7,8 HxCDF 12 BDL U 0 4 BDL U 0 3.2 BDL U 0BDL 1,2,3,6,7,8 HxCDF 11 BDL U 0 3.7 BDL U 0 2.9 BDL U 0BDL 2,3,4,6,7,8 HxCDF 11 BDL U 0 3.9 BDL U 0 3.1 BDL U 0BDL 1,2,3,7,8,9 HxCDF 13 BDL U 0 4.4 BDL U 0 3.5 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 17.4 8.8ADL J 0.174 9.8 BDL U 0 16 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 11 BDL U 0 12 BDL U 0 20 BDL U 0BDL OCDF 21 BDL J, R 0 17 BDL U 0 22 BDL U 0BDL Total TEQ, pg 788.597 837.29 957.3 Total TEQ, ng 0.788597 0.83729 0.9573 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit. Run 3 100 0 0

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 16 BDL R 0 2.7 BDL U 0 15 BDL R 0BDL 1,2,3,7,8 PeCDD 59.5 7.5ADL 59.5 53.1 2.8ADL 53.1 47.3 3.6ADL 47.3ADL 1,2,3,4,7,8 HxCDD 43.6 10ADL 4.36 42 BDL R 0 31.5 5.6ADL 3.15BDL 1,2,3,6,7,8 HxCDD 49 BDL R 0 42 BDL R 0 50.1 6.2ADL 5.01 BDL 1,2,3,7,8,9 HxCDD 138 11 ADL 13.8 128 9.4ADL 12.8 95.4 5.8ADL 9.54ADL 1,2,3,4,6,7,8 HpCDD 850 36ADL 8.5 666 34ADL 6.66 600 24ADL 6ADL OCDD 7490 7.6ADL 2.247 6020 9.8ADL 1.806 4960 2.8ADL 1.488ADL 2,3,7,8 TCDF 11 BDL U 0 6.5 BDL U 0 6.2 BDL U 0BDL 1,2,3,7,8 PeCDF 4.2 BDL U 0 2 BDL U 0 1.7 BDL U 0BDL 2,3,4,7,8 PeCDF 4.1 BDL U 0 2 BDL J, R 0 2.1 BDL J, R 0BDL 1,2,3,4,7,8 HxCDF 3.5 BDL U 0 2.2 BDL U 0 0.8 BDL U 0BDL 1,2,3,6,7,8 HxCDF 3.2 BDL U 0 2 BDL U 0 1.58 0.73ADL J 0.158BDL 2,3,4,6,7,8 HxCDF 3.4 BDL U 0 2.1 BDL U 0 0.77 BDL U 0BDL 1,2,3,7,8,9 HxCDF 3.9 BDL U 0 2.4 BDL U 0 0.87 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 2.2 BDL U 0 2.3 BDL U 0 2 BDL J, R 0BDL 1,2,3,4,7,8,9 HpCDF 2.9 BDL U 0 3 BDL U 0 1.3 BDL U 0BDL OCDF 1.8 BDL J, R 0 2.3 BDL U 0 1.4 BDL J, R 0BDL Total TEQ, pg 88.407 74.366 72.646 Total TEQ, ng 0.088407 0.074366 0.072646 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit. Run 3 100 0 0 **Kohler SC - Kiln 10 POC Stack Kohler SC - Kiln 8 POC Stack** 

BDL

**Run 2 Run 3**  **Status** ADL **Run 1 Run 2**  **Run 3 Status** 

**Run 1**

ADL BDL



### CC-Sanitaryware Kilns 3

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Kilns

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 1.7 BDL U 0 2.8 BDL U 0 1.2 BDL U 0BDL 1,2,3,7,8 PeCDD 1.5 BDL U 0 2.1 BDL U 0 2.5 BDL U 0BDL 1,2,3,4,7,8 HxCDD 2.2 BDL J, R 0 2 BDL U 0 1.4 BDL U 0BDL 1,2,3,6,7,8 HxCDD 2.46 2ADL J 0.246 2.2 BDL U 0 1.5 BDL U 0BDL 1,2,3,7,8,9 HxCDD 7.3 BDL J, R 0 2 BDL U 0 1.6 BDL J, R 0BDL 1,2,3,4,6,7,8 HpCDD 61.1 5.2ADL 0.611 22.5 3.4ADL 0.225 13 BDL J, R 0BDL OCDD 548 3.7ADL 0.1644 209 3.7ADL 0.0627 130 BDL R 0BDL 2,3,7,8 TCDF 4.1 BDL U 0 2.8 BDL U 0 1.1 BDL U 0BDL 1,2,3,7,8 PeCDF 1.2 BDL U 0 3.5 BDL U 0 1.3 BDL U 0BDL 2,3,4,7,8 PeCDF 1.2 BDL U 0 3.4 BDL U 0 1.3 BDL U 0BDL 1,2,3,4,7,8 HxCDF 3.9 BDL U 0 3.5 BDL U 0 0.61 BDL U 0BDL 1,2,3,6,7,8 HxCDF 3.6 BDL U 0 3.2 BDL U 0 0.56 BDL U 0BDL 2,3,4,6,7,8 HxCDF 3.8 BDL U 0 3.4 BDL U 0 0.59 BDL U 0BDL 1,2,3,7,8,9 HxCDF 4.3 BDL U 0 3.8 BDL U 0 0.67 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 0.98 BDL U 0 0.9 BDL U 0 0.75 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.3 BDL U 0 1.1 BDL U 0 0.96 BDL U 0BDL OCDF 1.6 BDL U 0 2.2 BDL U 0 0.88 BDL U 0BDL Total TEQ, pg 1.0214 0.2877 0 Total TEQ, ng 0.001021 0.000288 0 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL - Estimated detection limit. Run 0 0 3 100

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 129 11 ADL 129 97 BDL R 0 127 5.9ADL 127BDL 1,2,3,7,8 PeCDD 674 28ADL 674 555 10ADL 555 640 19ADL 640ADL 1,2,3,4,7,8 HxCDD 574 57ADL 57.4 475 39ADL 47.5 551 55ADL 55.1 ADL 1,2,3,6,7,8 HxCDD 656 63ADL 65.6 694 43ADL 69.4 627 60ADL 62.7ADL 1,2,3,7,8,9 HxCDD 711 59ADL 71.1 1060 40ADL 106 1120 57ADL 112ADL 1,2,3,4,6,7,8 HpCDD 7470 94ADL 74.7 7310 56ADL 73.1 7580 41 ADL 75.8ADL OCDD 41500 66ADL 12.45 40600 20ADL 12.18 45900 18ADL 13.77ADL 2,3,7,8 TCDF 27 BDL U 0 52 BDL U 0 11 BDL U 0BDL 1,2,3,7,8 PeCDF 17 BDL U 0 13 BDL U 0 13 BDL U 0BDL 2,3,4,7,8 PeCDF 17 BDL U 0 13 BDL U 0 13 BDL U 0BDL 1,2,3,4,7,8 HxCDF 25 BDL U 0 11 BDL U 0 17 BDL U 0BDL 1,2,3,6,7,8 HxCDF 23 BDL U 0 10 BDL U 0 15 BDL U 0BDL 2,3,4,6,7,8 HxCDF 24 BDL U 0 11 BDL U 0 16 BDL U 0BDL 1,2,3,7,8,9 HxCDF 28 BDL U 0 12 BDL U 0 18 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 36 BDL U 0 11 BDL U 0 6.4 5.4ADL J 0.064 BDL 1,2,3,4,7,8,9 HpCDF 46 BDL U 0 14 BDL U 0 10 BDL J, R 0BDL OCDF 305 36ADL 0.0915 17 BDL U 0 23 BDL U 0BDL Total TEQ, pg 1084.342 863.18 1086.434 Total TEQ, ng 1.084342 0.86318 1.086434 Compare to Utilities TEQ EDL (0.018 ng) ADL ADL ADL

Count % Count % *EDL - Estimated detection limit. Run 3 100 0 0

**Overall for Clay Ceramics Sanitaryw are -- 8 Stacks of Kilns**  **Run 1 Run 2**  **Run 3 Status**  **Kohler TX - Kilns 6 & 12 Kohler SC - Kiln 10 RCE Stack**  **Run 1 Run 2**  **Run 3**

ADL BDL

ADL BDL**Status**



### CC-Sanitaryware Kilns 4

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Kilns

Count % Count % Run 18 75 6 25 ADL BDL



### CC-Sanitaryware Kilns 5

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 2.5 BDL U 0 4.8 BDL R 0 2.8 BDL U 0BDL 1,2,3,7,8 PeCDD 3.1 BDL U 0 5.7 BDL J, R 0 7.31 1.1 ADL J 7.31 BDL 1,2,3,4,7,8 HxCDD 3.5 BDL J, R 0 1.9 BDL U 0 6.95 1.8ADL J 0.695BDL 1,2,3,6,7,8 HxCDD 9.2 BDL J, R 0 8.4 BDL J, R 0 7.1 BDL J, R 0BDL 1,2,3,7,8,9 HxCDD 10 BDL J, R 0 9.7 BDL J, R 0 18 BDL J, R 0BDL 1,2,3,4,6,7,8 HpCDD 139 6.2ADL 1.39 76.9 3.5ADL 0.769 192 6.8ADL 1.92ADL OCDD 1350 1.9ADL 0.405 711 3.6ADL 0.2133 2170 3.2ADL 0.651 ADL 2,3,7,8 TCDF 1.1 BDL U 0 1.1 BDL U 0 1.6 BDL U 0BDL 1,2,3,7,8 PeCDF 1.2 BDL U 0 1.6 BDL U 0 2 BDL U 0BDL 2,3,4,7,8 PeCDF 1.1 BDL U 0 1.5 BDL U 0 2 BDL U 0BDL 1,2,3,4,7,8 HxCDF 0.86 BDL U 0 0.6 BDL U 0 1.68 0.94ADL J 0.168BDL 1,2,3,6,7,8 HxCDF 0.79 BDL U 0 0.55 BDL U 0 0.86 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.3 BDL J, R 0 0.58 BDL U 0 0.91 BDL U 0BDL 1,2,3,7,8,9 HxCDF 0.94 BDL U 0 0.65 BDL U 0 1 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 2.2 BDL J, R 0 1.7 BDL J, R 0 1.1 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 0.91 BDL U 0 0.86 BDL U 0 1.4 BDL U 0BDL OCDF 1.3 BDL J, R 0 1.3 BDL U 0 2.2 BDL J, R 0BDL Total TEQ, pg 1.795 0.9823 10.744 Total TEQ, ng 0.001795 0.000982 0.010744 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL -Estimated detection limit. Run 0 0 3 100

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 1.5 BDL U 0 2.1 BDL U 0 2.5 BDL U 0BDL 1,2,3,7,8 PeCDD 6.3 BDL J, R 0 5.8 2.1 ADL J 5.8 1.5 BDL J, R 0BDL 1,2,3,4,7,8 HxCDD 2.8 BDL U 0 4.04 1.6ADL J 0.404 2 BDL J, R 0BDL 1,2,3,6,7,8 HxCDD 5.7 BDL J, R 0 5.5 BDL J, R 0 2.6 BDL J, R 0BDL 1,2,3,7,8,9 HxCDD 7.1 BDL J, R 0 9.8 BDL J, R 0 2.68 1.8ADL J 0.268BDL 1,2,3,4,6,7,8 HpCDD 79.2 1.9ADL 0.792 87.9 3.2ADL 0.879 18.8 1.3ADL J 0.188ADL OCDD 656 5.5ADL 0.1968 764 5.8ADL 0.2292 174 4.7ADL 0.0522ADL 2,3,7,8 TCDF 7.2 BDL U 0 2.1 BDL U 0 1.5 BDL U 0BDL 1,2,3,7,8 PeCDF 1.4 BDL U 0 1.5 BDL U 0 1.3 BDL U 0BDL 2,3,4,7,8 PeCDF 1.4 BDL U 0 1.7 BDL J, R 0 1.4 BDL J, R 0BDL 1,2,3,4,7,8 HxCDF 1.8 BDL U 0 1.4 BDL U 0 0.98 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.6 BDL U 0 1.3 BDL U 0 0.9 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.7 BDL U 0 1.4 BDL U 0 1.32 0.95ADL J 0.132 BDL 1,2,3,7,8,9 HxCDF 1.9 BDL U 0 1.6 BDL U 0 1.1 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1.4 BDL U 0 1.2 BDL U 0 0.83 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.7 BDL U 0 1.5 BDL U 0 1.1 BDL U 0BDL OCDF 2.4 BDL U 0 2.9 BDL U 0 1.9 BDL U 0BDL Total TEQ, pg 0.9888 7.3122 0.6402 Total TEQ, ng 0.000989 0.007312 0.00064 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL -Estimated detection limit. Run 0 0 3 100 **Kohler WI - Ware Dryer 1**

ADL BDL

**Run 3 Status**  **Run 1 Run 2**  **Run 3**

ADL **Status**

**Run 1 Run 2**  **Kohler TX - Batch Dryer E117B**

BDL



### CC-Sanitaryware Dryers 1

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 3 BDL J, R 0 3 BDL J, R 0 5.2 BDL U 0BDL 1,2,3,7,8 PeCDD 8.1 BDL J, R 0 5.36 1.2ADL J 5.36 4.9 BDL J, R 0BDL 1,2,3,4,7,8 HxCDD 3.48 1.5ADL J 0.348 2.53 1.1 ADL J 0.253 1.8 BDL U 0BDL 1,2,3,6,7,8 HxCDD 6.17 1.7ADL J 0.617 2.7 BDL J, R 0 3.1 BDL J, R 0BDL 1,2,3,7,8,9 HxCDD 11.8 1.6ADL J 1.18 4.7 BDL J, R 0 3.7 BDL J, R 0BDL 1,2,3,4,6,7,8 HpCDD 64.7 2.5ADL 0.647 19.5 1.8ADL J 0.195 30 1.6ADL 0.3ADL OCDD 360 5.2ADL 0.108 133 3.7ADL 0.0399 369 9.1 ADL 0.1107ADL 2,3,7,8 TCDF 1.4 BDL U 0 1.2 BDL U 0 4 BDL U 0BDL 1,2,3,7,8 PeCDF 1.8 BDL U 0 0.82 BDL U 0 2 BDL U 0BDL 2,3,4,7,8 PeCDF 1.7 BDL U 0 0.99 BDL J, R 0 1.9 BDL U 0BDL 1,2,3,4,7,8 HxCDF 1.3 BDL U 0 0.74 BDL U 0 1.7 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.2 BDL U 0 0.68 BDL U 0 1.6 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.2 BDL U 0 0.72 BDL U 0 1.6 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.4 BDL U 0 0.82 BDL U 0 1.9 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 4.5 1.1 ADL J 0.045 1.55 1 ADL J 0.0155 1.1 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.5 BDL U 0 1.3 BDL U 0 1.4 BDL U 0BDL OCDF 3 BDL U 0 1.5 BDL U 0 3.7 BDL U 0BDL Total TEQ, pg 2.945 5.8634 0.4107 Total TEQ, ng 0.002945 0.005863 0.000411 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL -Estimated detection limit. Run 0 0 3 100

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 1.5 BDL U 0 2.5 BDL J, R 0 4 BDL J, R 0BDL 1,2,3,7,8 PeCDD 10.4 2.4ADL J 10.4 6.07 2.4ADL J 6.07 7.2 BDL J, R 0BDL 1,2,3,4,7,8 HxCDD 2.6 BDL J, R 0 2.4 BDL U 0 1.8 BDL U 0BDL 1,2,3,6,7,8 HxCDD 3.5 BDL J, R 0 4.6 BDL J, R 0 2.1 BDL J, R 0BDL 1,2,3,7,8,9 HxCDD 7.32 2.2ADL J 0.732 5.9 BDL J, R 0 5.33 1.9ADL J 0.533BDL 1,2,3,4,6,7,8 HpCDD 25.4 3ADL 0.254 15.5 2.9ADL J 0.155 12 BDL J, R 0BDL OCDD 109 4.5ADL 0.0327 75 BDL R 0 63.3 5.3ADL 0.01899BDL 2,3,7,8 TCDF 3 BDL U 0 3 BDL U 0 0.357 0.26ADL J 0.0357BDL 1,2,3,7,8 PeCDF 2 BDL U 0 2.4 BDL U 0 1.6 BDL U 0BDL 2,3,4,7,8 PeCDF 1.9 BDL U 0 2.3 BDL U 0 1.6 BDL U 0BDL 1,2,3,4,7,8 HxCDF 1.2 BDL U 0 1 BDL U 0 1.3 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.1 BDL U 0 0.92 BDL U 0 1.2 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.1 BDL U 0 0.97 BDL U 0 1.2 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.3 BDL U 0 1.1 BDL U 0 1.4 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 0.87 BDL U 0 0.87 BDL U 0 0.98 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.1 BDL U 0 1.1 BDL U 0 1.3 BDL U 0BDL OCDF 4.3 BDL U 0 2.8 BDL U 0 3 BDL U 0BDL Total TEQ, pg 11.4187 6.225 0.58769 Total TEQ, ng 0.011419 0.006225 0.000588 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL -Estimated detection limit. Run 0 0 3 100 ADL BDL

**Run 3 Status**  **Kohler TX - Tunnel Dryer E238-S2**

**Run 1 Run 2**  **Run 3 Run 2** 

ADL BDL

**Status Kohler TX - Tunnel Dryer E238-S3**  **Run 1**



### CC-Sanitaryware Dryers 2

### Run by Run Summary of Dioxin/Furan Raw Emissions Data for Ceramic Sanitaryware Dryers

**Congener Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  **Mass, pg Det Limit**  **Status Flag**  **TEQ, pg Mass, pg**  **Det Limit Status**  **Flag TEQ, pg**  2,3,7,8 TCDD 3.8 BDL U 0 5.3 BDL U 0 3.5 BDL U 0BDL 1,2,3,7,8 PeCDD 5.47 2.5ADL J 5.47 2 BDL U 0 3.1 BDL U 0BDL 1,2,3,4,7,8 HxCDD 5.4 BDL J, R 0 2.1 BDL U 0 3.2 BDL U 0BDL 1,2,3,6,7,8 HxCDD 8.83 3.3ADL J 0.883 2.3 BDL U 0 3.5 BDL U 0BDL 1,2,3,7,8,9 HxCDD 11 BDL J, R 0 2.8 BDL J, R 0 8.26 3.3ADL J 0.826BDL 1,2,3,4,6,7,8 HpCDD 81.2 3ADL 0.812 13 BDL J, R 0 26.8 2.7ADL 0.268BDL OCDD 322 5.3ADL 0.0966 126 5ADL 0.0378 202 6.5ADL 0.0606ADL 2,3,7,8 TCDF 3.7 BDL U 0 0.66 BDL U 0 3.9 BDL U 0BDL 1,2,3,7,8 PeCDF 1.9 BDL U 0 1.6 BDL U 0 2.1 BDL U 0BDL 2,3,4,7,8 PeCDF 1.8 BDL U 0 1.5 BDL U 0 2 BDL U 0BDL 1,2,3,4,7,8 HxCDF 1.6 BDL U 0 0.77 BDL U 0 1.3 BDL U 0BDL 1,2,3,6,7,8 HxCDF 1.5 BDL U 0 0.71 BDL U 0 1.2 BDL U 0BDL 2,3,4,6,7,8 HxCDF 1.6 BDL U 0 0.75 BDL U 0 1.3 BDL U 0BDL 1,2,3,7,8,9 HxCDF 1.8 BDL U 0 0.85 BDL U 0 1.4 BDL U 0BDL 1,2,3,4,6,7,8 HpCDF 1 BDL U 0 1 BDL U 0 1.2 BDL U 0BDL 1,2,3,4,7,8,9 HpCDF 1.3 BDL U 0 1.3 BDL U 0 1.5 BDL U 0BDL OCDF 3.4 BDL U 0 3.4 BDL U 0 3.2 BDL U 0BDL Total TEQ, pg 7.2616 0.0378 1.1546 Total TEQ, ng 0.007262 3.78E-05 0.001155 Compare to Utilities TEQ EDL (0.018 ng) BDL BDL BDL

Count % Count % *EDL -Estimated detection limit. Run 0 0 3 100

**Overall for Clay Ceramics Sanitaryw are -- 5 Stacks** 

Count % Count % Run 0 0 15 100 ADL BDL ADL BDL**Status Kohler TX - Tunnel Dryer E238-S5**  **Run 1 Run 2**  **Run 3**



### CC-Sanitaryware Dryers 3Notes:

B = Indicates that the compound mass was less than 10x higher than method blank level EMPC = Estimated Maximum Possible Concentration J = Indicates that a target analyte was detected below the LQL M = Indicates that a peak has been manually integrated R = Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion U = Indicates that compound was not detected above the MDL

EE = entrance exhaust FE = fume exhaust POC = products of combustion RCE = rapid cooling exhaust

ADL = above detection level BDL = below detection level DLL = detection level limited

TEQ = Toxic Equivalency TEF = Toxic Equivalency Factor

1 Indicates mass value is at least 3 times the detection level ADL Indicates the mass values for all three runs are at least 3 times the respective detection levels

Values used in calculating TEQ:

Congener TEF (Mammals) Congener TEF (Mammals) 2,3,7,8 TCDD 1 2,3,7,8-TCDD 1 1,2,3,7,8 PeCDD 1 1,2,3,7,8-PeCDD 1 1,2,3,4,7,8 HxCDD 0.1 1,2,3,4,7,8-HxCDD 0.1 1,2,3,6,7,8 HxCDD 0.1 1,2,3,6,7,8-HxCDD 0.1 1,2,3,7,8,9 HxCDD 0.1 1,2,3,7,8,9-HxCDD 0.1 1,2,3,4,6,7,8 HpCDD 0.01 1,2,3,4,6,7,8-HpCDD 0.01
Total OCDD 0.0003 OCDD 0.0003 2,3,7,8 TCDF 0.1 2,3,7,8-TCDF 0.1 1,2,3,7,8 PeCDF 0.03 1,2,3,7,8-PeCDF 0.03 2,3,4,7,8 PeCDF 0.3 2,3,4,7,8-PeCDF 0.3 1,2,3,4,7,8 HxCDF 0.1 1,2,3,4,7,8-HxCDF 0.1 1,2,3,6,7,8 HxCDF 0.1 1,2,3,6,7,8-HxCDF 0.1 2,3,4,6,7,8 HxCDF 0.1 1,2,3,7,8,9-HxCDF 0.1 1,2,3,7,8,9 HxCDF 0.1 2,3,4,6,7,8-HxCDF 0.1 1,2,3,4,6,7,8 HpCDF 0.01 1,2,3,4,6,7,8-HpCDF 0.01 1,2,3,4,7,8,9 HpCDF 0.01 1,2,3,4,7,8,9-HpCDF 0.01
Total OCDF 0.0003 OCDF 0.0003

WHO 2005 values http://www.epa.gov/raf/files/tefs-for-dioxin-epa-00-r-10-005-final.pdf Provided in "Framework for Application of the Toxicity Equivalence Methodology for Polychlorinated Dioxins, Furans, and Biphenyls in Ecological Risk The TEF values are based on the values for mammals from the World Health Organization 2006 tables located on page 13 of this report: http://www.epa.gov/raf/files/tefs-for-dioxin-epa-00-r-10-005-final.pdf Assessment," EPA 100/R-08/004, June 2008 which cites the source as:

Compare to Utilities TEQ (Method 23) sum (ng) value (1/2 of RDL provided in guidance document) Data and procedure for handling below detection level data in analyzing various pollutant emissions databases for MACT and RTR emissions limits. Peter Westlin, SPPD, MPG and Raymond Merrill, AQAD, MTG December 13, 2011 (revised April 5, 2012)

sum/EDL (ng) 3xRDL (ng) RDL (ng) Utilities TEQ (Method 23) 1.80E-02 1.10E-01 3.60E-02 Van den Berg, M; Birnbaum, LS; Denison, M, DeVito, M, Farland, W, Feeley, M; Fiedler, H; Hakansson, H; Hanberg, A; Haws, L; Rose, M; Safe, S; Schrenk, D; Tohyama, C; Tritscher, A; Tuomisto, J; Tysklind, M; Walker, N; Peterson, RE. (2006) The 2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-Like Compounds.Toxicol Sci93:223-241.