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1 EPI Suite Results For Oleylamine HCL CAS 41130 - 29 - 4

H3 C NH Cl

SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : Oleylamine HCL MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

------------------------------ EPI SUMMARY (v4.11) -------------------------- Physical Property Inputs: Log Kow (octanol - water): ------ Boiling Point (deg C) : ------ Melting Point (deg C) : ------ Vapor Pressure (mm Hg) : ------ Water Solubility (mg/L): ------ Henry LC (atm- m3/mole) : ------ KOWWIN Program (v1.68) Results:
=============================== Log Kow(version 1.68 estimate): 7.41 SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

------- + ----- + -------------------------------------------- + --------- + -------- TYPE | NUM | LOGKOW FRAGMENT DESCRIPTION | COEFF | VALUE

------- + ----- + -------------------------------------------- + --------- + -------- Frag | 1 | - CH3 [aliphatic carbon] | 0.5473 | 0.5473 Frag | 15 | - CH2 - [aliphatic carbon] | 0.4 911 | 7.3665 Frag | 2 | =CH - or =C< [olefinc carbon] | 0.3836 | 0.7672 Frag | 1 | - NH - [aliphatic attach] | - 1.4962 | - 1.4962 Frag | 1 | Halogen { - CL, - Br, - F, - I} [Nitrogen attach] | 0.0001 | 0.0001 Const | | Equation Constant | | 0.2290

------- + ----- + -------------------------------------------- + --------- + -------- Log Kow = 7.4139

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MPBPVP (v1.43) Program Results:
=============================== Experimental Database S tructure Match: no data SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

------------------------ SUMMARY MPBVP v1.43 -------------------- Boiling Point: 353.88 deg C (Adapted Stein and Brown Method) Melting Point: 96.96 deg C (Adapted Joback Method) Melting Point: 92.97 deg C (Gold and Ogle Method) Mean Melt Pt : 94.96 deg C (Joback; Gold,Ogle Methods) Selected MP: 94.96 deg C (Mean Value) Vapor Pressure Estimations (25 deg C): (Using BP: 353.88 deg C (estimated)) (Using MP: 94.96 deg C (estimated)) VP: 9.95E - 006 mm Hg (Antoine Method) : 0.00133 Pa (Antoine Method) VP: 2.24E - 005 mm Hg (Modified Grain Method) : 0.00299 Pa (Modified Grain Method) VP: 4.31E - 005 mm Hg (Mackay Method) : 0.00575 Pa (Mackay Method) Selected VP: 2.24E - 005 mm Hg (Modified Grain Method) : 0.00299 Pa (Modified Grain Method) Subcooled liquid VP: 0.000107 mm Hg (25 deg C, Mod - Grain method) : 0.0142 Pa (25 deg C, Mod - Grain method)

------- + ----- + -------------------- + ---------- + --------- TYPE | NUM | BOIL DESCRIPTION | COEFF | VALUE

------- + ----- + -------------------- + ---------- + --------- Group | 1 | - CH3 | 21.98 | 21.98 Group | 15 | - CH2 - | 24.22 | 363.30 Group | 2 | =CH - | 27.95 | 55.90 Group | 1 | - Cl | 34.08 | 34.08 Group | 1 | >NH (nonring) | 45.28 | 45.28 * | | Equation Constant | | 198.18 =============+====================+==========+========= RESULT - uncorr| BOILING POINT in deg Kelvin | 718.72 RESULT - corr | BOILING POINT in deg Kelvin | 627.04 | BOILING POINT in deg C | 353.88

-------------------------------------------------------

------- + ----- + -------------------- + ---------- + --------- TYPE | NUM | MELT DESCRIPTION | COEFF | VALUE

------- + ----- + -------------------- + ---------- + --------- Group | 1 | - CH3 | - 5.10 | - 5.10 Group | 15 | - CH2 - | 11.27 | 169.05 Group | 2 | =CH - | 8.73 | 17.46 Group | 1 | - Cl | 13.55 | 13.55 Group | 1 | >NH (nonring) | 52.66 | 52.66 * | | Equation Constant | | 122.50

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=============+====================+==========+========= RESULT | MELTING POINT in deg Kelvin | 370.12 | MELTING POINT in deg C | 96.96

------------------------------------------------------- Water Sol from Kow (WSKOW v1.42) Results:
======================================== Water Sol: 0.005575 mg/L SMILES : CCCCCCCCC=CCCC CCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

---------------------------------- WSKOW v1.42 Results ------------------------ Log Kow (estimated) : 7.41 Log Kow (experimental): not available from database Log Kow used by Water solubility estimates: 7.41 Equation Used to Make Water Sol estimate: Log S (mol/L) = 0.796 - 0.854 log Kow - 0.00728 MW + Correction (used when Melting Point NOT available) Correction(s): Value

-------------------- ----- No Applicable Correction Factors Log Water Solubility (in moles/L) : - 7.734 Water Solubility at 25 deg C (mg/L): 0.005575 WATERNT Program (v1.01) Results:
=============================== Water Sol (v1.01 est): 0.057424 mg/L SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

------- + ----- + -------------------------------------------- + ---------- + --------- TYPE | NUM | WATER SOLUBILITY FRAGMENT DESCRIPTION | COEFF | VALUE

------- + ----- + -------------------------------------------- + ---------- + -- ------- Frag | 1 | - CH3 [aliphatic carbon] | - 0.3213 | - 0.3213 Frag | 15 | - CH2 - [aliphatic carbon] | - 0.5370 | - 8.0553 Frag | 2 | =CH - or =C< [olefinc carbon] | - 0.3646 | - 0.7292 Frag | 1 | - NH - [aliphatic attach] | 2.1357 | 2.1357 Frag | 1 | Halogen { - CL, - Br, - F, - I} [Nitrogen attach] | 0.0000 | 0.0000 Const | | Equation Constant | | 0.2492

------- + ----- + ---------------------- ---------------------- + ---------- + --------- Log Water Sol (moles/L) at 25 dec C = - 6.7208 Water Solubility (mg/L) at 25 dec C = 0.057424

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ECOSAR Program (v1.11) Results:
=============================== ECOSAR Version 1.11 Results Page SMILES : CCCCC CCCC=CCCCCCCCCN(CL) CHEM : CAS Num: ChemID1: MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95 Log Kow: 7.414 (EPISuite Kowwin v1.68 Estimate) Log Kow: (User Entered) Log Kow: (PhysProp DB exp value - for comparison only) Melt Pt: (User Entered for Wat Sol estimate) Melt Pt: (deg C, PhysProp DB exp value for Wat Sol estimate) Wat Sol: 0.005575 (mg/L, EPISuite WSKowwin v1.43 Estimate) Wat Sol: (User Entered) Wat Sol: (PhysProp DB exp value)

- ------------------------------------- Values used to Generate ECOSAR Profile

-------------------------------------- Log Kow: 7.414 (EPISuite Kowwin v1.68 Estimate) Wat Sol: 0.005575 (mg/L, EPISuite WSKowwin v1.43 Estimate)

----------------------- --------------- ECOSAR v1.11 Class - specific Estimations

-------------------------------------- ****************************************************************************** | Not Related to an Existing ECOSAR Class Definition | | | | Estimates provided below use the Neutral Organics QSAR equations which | | represent baseline toxicity potential (minimum toxicity) assuming a simple | | non - polar narcosis model. Without empirical data on structurally similar | | chemicals, it is uncertain if this substance will present significantly | | higher toxicity above baseline estimates. | **************************************** ************************************** Predicted ECOSAR Class Organism Duration End Pt mg/L (ppm) =========================== ================== ======== ====== ========== Neutral Organics : Fish 96 - hr LC50 0.003 Neutral Organics : Daphnid 48 - hr LC50 0.003 Neutral Organics : Green Algae 96 - hr EC50 0.019 * Neutral Organics : Fish ChV 0 .0006 Neutral Organics : Daphnid ChV 0.00125 Neutral Organics : Green Algae ChV 0.015 * Neutral Organics : Fish (SW) 96 - hr LC50 0.004 Neutral Organics : Mysid 96 - hr LC50 8.41e - 005 Neutral Organics : Fish (SW) ChV 0.013 * Neutral Organics : Mysid (SW) ChV 1.46e - 006 Neutral Organics : Earthworm 14 - day LC50 144.115 *

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Note: * = asterisk designates: Chemical may not be soluble enough to measure this predicted effect. If the effect level exceeds the water solubility by 10X, typically no effects at saturation (NES) are reported.

- ----------------------------- Class Specific LogKow Cut - Offs

------------------------------ If the log Kow of the chemical is greater than the endpoint specific cut - offs presented below, then no effects at saturation are expected for those endpoints. Neut ral Organics:

---------------- Maximum LogKow: 5.0 (Fish 96 - hr LC50; Daphnid LC50, Mysid LC50) Maximum LogKow: 6.0 (Earthworm LC50) Maximum LogKow: 6.4 (Green Algae EC50) Maximum LogKow: 8.0 (ChV)
HENRYWIN (v3.20) Program Results:
==================== ========= Bond Est : 1.58E - 002 atm- m3/mole (1.60E+003 Pa - m3/mole) Group Est: Incomplete SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

--------------------------- HENRYWIN v3.20 Results --------------------------

-- -------- + --------------------------------------------- + --------- + ---------- CLASS | BOND CONTRIBUTION DESCRIPTION | COMMENT | VALUE

---------- + --------------------------------------------- + --------- + ---------- HYDROGEN | 33 Hydrogen to Ca rbon (aliphatic) Bonds | | - 3.9493 HYDROGEN | 2 Hydrogen to Carbon (olefinic) Bonds | | - 0.2010 HYDROGEN | 1 Hydrogen to Nitrogen Bonds | | 1.2835 FRAGMENT | 14 C - C | | 1.6283 FRAGMENT | 2 C - Cd | | 0.1269 FRAGMENT | 1 C - N | | 1.3010 FRAGMENT | 1 Cd=Cd | | 0.0000 FRAGMENT | 1 N - CL | ESTIMATE| 0.0000

---------- + --------------------------------------------- + --------- + ---------- RESULT | BOND ESTIMATION METHOD for LWAPC VALUE | TOTAL | 0.189

---------- + ----------------------------------- ---------- + --------- + ---------- HENRYs LAW CONSTANT at 25 deg C = 1.58E - 002 atm- m3/mole = 6.47E - 001 unitless = 1.60E+003 Pa - m3/mole

-------- + ----------------------------------------------- + ------------ + -------- | GROUP CONTRIBUTION DESCRIPTION | COMMENT | VALUE

-------- + ----------------------------------------------- + ------------ + -------- | 1 CH3 (X) | | - 0.62

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| 12 CH2 (C)(C) | | - 1.80 | 2 CH2 (C)(Cd) | | - 0.46 | 1 CH2 (C)(N) | | - 0.08 | 2 CdH (C) | | 0.44 | MISSING Value for: NH (CL)(C)

-------- + ------- ---------------------------------------- + ------------ + -------- RESULT | GROUP ESTIMATION METHOD for LOG GAMMA VALUE | INCOMPLETE | - 2.52

-------- + ----------------------------------------------- + ------------ + -------- For Henry LC Comparison Purposes: Exper Database: none available User - Entered Henry LC: not entered Henrys LC [via VP/WSol estimate using User - Entered or Estimated values]: HLC: 1.596E - 003 atm- m3/mole (1.617E+002 Pa - m3/mole) VP: 2.24E - 005 mm Hg (source: MPBPVP) WS: 0.00558 mg/L (sour ce: WSKOWWIN) Log Octanol -Air (KOAWIN v1.10) Results:
====================================== Log Koa: 7.600 SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

--------------------------- KOAWIN v1.10 Results ----------- --------------- Log Koa (octanol/air) estimate: 7.600 Koa (octanol/air) estimate: 3.979e+007 Using: Log Kow: 7.41 (KowWin est) HenryLC: 0.0158 atm - m3/mole (HenryWin est) Log Kaw: - 0.190 (air/water part.coef.) LogKow : ---- (exp database) LogKow : 7.41 (KowWin estimate) Henry LC: --- atm- m3/mole(exp database) Henry LC: 0.0158 atm - m3/mole (HenryWin bond estimate) Log Koa (octanol/air) estimate: 7.600 (from KowWin/HenryWin) BIOWIN (v4.10) Program Results:
============================== SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

--------------------------- BIOWIN v4.10 Results ---------------------------- Biowin1 (Linear Model Prediction) : Biodegrades Fast Biowin2 (Non - Linear Model Prediction): Bio degrades Fast

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Biowin3 (Ultimate Biodegradation Timeframe): Weeks Biowin4 (Primary Biodegradation Timeframe): Days - Weeks Biowin5 (MITI Linear Model Prediction) : Biodegrades Fast Biowin6 (MITI Non - Linear Model Prediction): Biodegrades Fast Biowin7 ( Anaerobic Model Prediction): Biodegrades Fast Ready Biodegradability Prediction: YES

------ + ----- + -------------------------------------------- + --------- + --------- TYPE | NUM | Biowin1 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -- ------------------------------------------ + --------- + --------- Frag | 1 | Linear C4 terminal chain [CCC - CH3] | 0.1084 | 0.1084 MolWt| * | Molecular Weight Parameter | | - 0.1437 Const| * | Equation Constant | | 0.7475 ============+============================================+=========+========= RESULT | Biowin1 (Linear Biodeg Probability) | | 0.7122 ============+============================================+=========+= ========

------ + ----- + -------------------------------------------- + --------- + --------- TYPE | NUM | Biowin2 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -------------------------------------------- + --------- + --------- Frag | 1 | L inear C4 terminal chain [CCC - CH3] | 1.8437 | 1.8437 MolWt| * | Molecular Weight Parameter | | - 4.2877 ============+============================================+=========+========= RESULT | Biowin2 (Non - Linear Biodeg Pr obability) | | 0.6375 ============+============================================+=========+========= A Probability Greater Than or Equal to 0.5 indicates -- > Biodegrades Fast A Probability Less Than 0.5 indicates -- > Does NOT Biodegrade Fast

-- ---- + ----- + -------------------------------------------- + --------- + --------- TYPE | NUM | Biowin3 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -------------------------------------------- + --------- + --------- Frag | 1 | Linear C4 terminal chain [CCC - CH3] | 0.2983 | 0.2983 MolWt| * | Molecular Weight Parameter | | - 0.6673 Const| * | Equation Constant | | 3.1992 ============+========================================== ==+=========+========= RESULT | Biowin3 (Survey Model - Ultimate Biodeg) | | 2.8302 ============+============================================+=========+=========

------ + ----- + -------------------------------------------- + --------- + --------- TY PE | NUM | Biowin4 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -------------------------------------------- + --------- + --------- Frag | 1 | Linear C4 terminal chain [CCC - CH3] | 0.2691 | 0.2691 MolWt| * | Molecular Weigh t Parameter | | - 0.4356 Const| * | Equation Constant | | 3.8477 ============+============================================+=========+========= RESULT | Biowin4 (Survey Model - Primary Biodeg) | | 3.6812 ============+============================================+=========+========= Result Classification: 5.00 - > hours 4.00 - > days 3.00 - > weeks (Primary & Ultimate) 2.00 - > months 1.00 - > longer

------ + ----- + -------------- ------------------------------ + --------- + --------- TYPE | NUM | Biowin5 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -------------------------------------------- + --------- + --------- Frag | 1 | Methyl [ - CH3] | 0.0004 | 0.0004 Frag | 15 | - CH2 - [linear] | 0.0494 | 0.7412

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Frag | 2 | - C=CH [alkenyl hydrogen] | 0.0062 | 0.0124 MolWt| * | Molecular Weight Parameter | | - 0.8983 Cons t| * | Equation Constant | | 0.7121 ============+============================================+=========+========= RESULT | Biowin5 (MITI Linear Biodeg Probability) | | 0.5679 ============+=================== =========================+=========+=========

------ + ----- + -------------------------------------------- + --------- + --------- TYPE | NUM | Biowin6 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + ------------------------------------------- - + --------- + --------- Frag | 1 | Methyl [ - CH3] | 0.0194 | 0.0194 Frag | 15 | - CH2 - [linear] | 0.4295 | 6.4424 Frag | 2 | - C=CH [alkenyl hydrogen] | 0.0285 | 0.0570 MolWt| * | Molecular Weight Parameter | | - 8.7168 ============+============================================+=========+========= RESULT |Biowin6 (MITI Non - Linear Biodeg Probability)| | 0.5812 ============+===================== =======================+=========+========= A Probability Greater Than or Equal to 0.5 indicates -- > Readily Degradable A Probability Less Than 0.5 indicates -- > NOT Readily Degradable

------ + ----- + -------------------------------------------- + --------- + --------- TYPE | NUM | Biowin7 FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -------------------------------------------- + --------- + --------- Frag | 1 | Linear C4 terminal chain [CCC - CH3] | - 0.3177 | - 0.3177 Frag | 1 | Met hyl [ - CH3] | - 0.0796 | - 0.0796 Frag | 15 | - CH2 - [linear] | 0.0260 | 0.3898 Frag | 2 | - C=CH [alkenyl hydrogen] | - 0.0735 | - 0.1470 Const| * | Equation Constant | | 0.8361 ============+============================================+=========+========= RESULT | Biowin7 (Anaerobic Linear Biodeg Prob) | | 0.6816 ============+============================================+=========+===== ==== A Probability Greater Than or Equal to 0.5 indicates -- > Biodegrades Fast A Probability Less Than 0.5 indicates -- > Does NOT Biodegrade Fast Ready Biodegradability Prediction: (YES or NO)

---------------------------------------------- Criteria for t he YES or NO prediction: If the Biowin3 (ultimate survey model) result is "weeks" or faster (i.e. "days", "days to weeks", or "weeks" AND the Biowin5 (MITI linear model) probability is >= 0.5, then the prediction is YES (readily biodegradable). If this c ondition is not satisfied, the prediction is NO (not readily biodegradable). This method is based on application of Bayesian analysis to ready biodegradation data (see Help). Biowin5 and 6 also predict ready biodegradability, but for degradation in the OECD301C test only; using data from the Chemicals Evaluation and Research Institute Japan (CERIJ) database. BioHCwin (v1.01) Program Results:
============================== SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1

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MOL WT : 301. 95

-------------------------- BioHCwin v1.01 Results --------------------------- NO Estimate Possible ... Structure NOT a Hydrocarbon (Contains atoms other than C, H or S ( - S - )) AEROWIN Program (v1.00) Results:
=============================== Sorption to aerosols (25 Dec C)[AEROWIN v1.00]: Vapor pressure (liquid/subcooled): 0.0143 Pa (0.000107 mm Hg) Log Koa (Koawin est ): 7.600 Kp (particle/gas partition coef. (m3/ug)): Mackay model : 0.00021 Octanol/air (Koa) model: 9.77E - 006 Fraction so rbed to airborne particulates (phi): Junge - Pankow model : 0.00754 Mackay model : 0.0165 Octanol/air (Koa) model: 0.000781 AOP Program (v1.92) Results:
=========================== SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H3 6 CL1 N1 MOL WT : 301.95

------------------- SUMMARY (AOP v1.92): HYDROXYL RADICALS (25 deg C) -------- Hydrogen Abstraction = 29.8413 E - 12 cm3/molecule - sec Reaction with N, S and - OH = 0.0000 E - 12 cm3/molecule - sec Addition to Triple Bonds = 0 .0000 E - 12 cm3/molecule - sec Addition to Olefinic Bonds = 56.4000 E - 12 cm3/molecule - sec [Cis - isomer] Addition to Olefinic Bonds = 64.0000 E - 12 cm3/molecule - sec [Trans - isomer] Addition to Aromatic Rings = 0.0000 E - 12 cm3/molecule - sec Addition to Fused Ri ngs = 0.0000 E - 12 cm3/molecule - sec OVERALL OH Rate Constant = 86.2413 E - 12 cm3/molecule - sec [Cis - isomer] OVERALL OH Rate Constant = 93.8413 E - 12 cm3/molecule - sec [Trans - isomer] HALF - LIFE = 1.488 Hrs (12 - hr day; 1.5E6 OH/cm3) [Cis - isomer] HALF - LI FE = 1.368 Hrs (12 - hr day; 1.5E6 OH/cm3) [Trans - isomer]

------------------- SUMMARY (AOP v1.91): OZONE REACTION (25 deg C) ----------- OVERALL OZONE Rate Constant = 13.000000 E - 17 cm3/molecule - sec [Cis - ] OVERALL OZONE Rate Constant = 20.000000 E - 17 cm 3/molecule - sec [Trans - ] HALF - LIFE = 2.116 Hrs (at 7E11 mol/cm3) [Cis - isomer] HALF - LIFE = 1.375 Hrs (at 7E11 mol/cm3) [Trans - isomer] NOTE: Reaction with Nitrate Radicals May Be Important! Experimental Database: NO Structure Matches Fraction sorbed to a irborne particulates (phi): 0.012 (Junge - Pankow, Mackay avg) 0.000781 (Koa method) Note: the sorbed fraction may be resistant to atmospheric oxidation

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KOCWIN Program (v2.00) Results:
============================== SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

--------------------------- KOCWIN v2.00 Results --------------------------- Koc Estimate from MCI:

--------------------- First Order Molecular Connectivity Index ........... : 9.914 Non - Corrected Log Koc ( 0.5213 MCI + 0.60) .......... : 5.7681 Fragment Correction(s): 1 Nitrogen to Carbon (aliphatic) ( - N - C).. : - 0.2127 Corrected Log Koc .................................. : 5.5553 Estimated Koc: 3.592e+005 L/kg <=========== Koc Estimate from Log Kow:

------------------------- Log Kow (Kowwin estimate) ......................... : 7.41 Non - Corrected Log Koc (0.55313 logKow + 0.9251) .... : 5.0238 Fragment Correction(s): 1 Nitrogen to Carbon (aliphatic) ( - N - C).. : - 0.0218 Corrected Log Koc . ................................. : 5.0020 Estimated Koc: 1.005e+005 L/kg <=========== HYDROWIN Program (v2.00) Results:
================================ SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

--------- ------------------ HYDROWIN v2.00 Results --------------------------- Hydrolyzable Function detected: Haloamines N - halogen {F, Cl, Br, I} Halogen in N - haloamines is formally positive (oxidation state +1). These compounds hydrolyze in water yielding hypo halous acid (Kirk Othmer, 4th ed, 5:911 - 913 (1993)).
BCFBAF Program (v3.01) Results:
============================== SMILES : CCCCCCCCC=CCCCCCCCCN(CL) CHEM : MOL FOR: C18 H36 CL1 N1 MOL WT : 301.95

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--------------------------------- BCFBAF v3.01 ---- ---------------------------- Summary Results: Log BCF (regression - based estimate): 3.32 (BCF = 2.11e+003 L/kg wet - wt) Biotransformation Half - Life (days) : 6.41 (normalized to 10 g fish) Log BAF (Arnot - Gobas upper trophic): 4.06 (BAF = 1.15e+004 L/kg wet - wt) Log Kow (experimental): not available from database Log Kow used by BCF estimates: 7.41 Equation Used to Make BCF estimate: Log BCF = - 0.49 log Kow + 7.554 + Correction Correction(s): Value Alkyl chains (8+ - CH2 - groups) - 0 .596 Estimated Log BCF = 3.325 (BCF = 2112 L/kg wet - wt)

=========================================================== Whole Body Primary Biotransformation Rate Estimate for Fish:
===========================================================

------ + ----- + -- ------------------------------------------ + --------- + --------- TYPE | NUM | LOG BIOTRANSFORMATION FRAGMENT DESCRIPTION | COEFF | VALUE

------ + ----- + -------------------------------------------- + --------- + --------- Frag | 1 | Linear C4 terminal chain [CCC - CH3] | 0.0341 | 0.0341 Frag | 1 | Methyl [ - CH3] | 0.2451 | 0.2451 Frag | 15 | - CH2 - [linear] | 0.0242 | 0.3628 Frag | 2 | - C=CH [alkenyl hydrogen] | 0.0988 | 0.1977 Frag | 2 | - C=CH [alkenyl hydrogen] | 0.0000 | 0.0000 L Kow| * | Log Kow = 7.41 (KowWin estimate) | 0.3073 | 2.2786 MolWt| * | Molecular Weight Parameter | | - 0.7743 Const| * | Equati on Constant | | - 1.5371 ============+============================================+=========+========= RESULT | LOG Bio Half - Life (days) | | 0.8070 RESULT | Bio Half - Life (days) | | 6.412 NOTE | Bio Half - Life Normalized to 10 g fish at 15 deg C | ============+============================================+=========+========= Biotransformation Rate Constant: kM (Rate Constant): 0.1081 /day (10 gram fish) kM ( Rate Constant): 0.06079 /day (100 gram fish) kM (Rate Constant): 0.03419 /day (1 kg fish) kM (Rate Constant): 0.01922 /day (10 kg fish) Arnot - Gobas BCF & BAF Methods (including biotransformation rate estimates): Estimated Log BCF (upper trophic) = 2.5 97 (BCF = 395.3 L/kg wet - wt) Estimated Log BAF (upper trophic) = 4.060 (BAF = 1.147e+004 L/kg wet - wt) Estimated Log BCF (mid trophic) = 2.738 (BCF = 547.1 L/kg wet - wt) Estimated Log BAF (mid trophic) = 4.532 (BAF = 3.405e+004 L/kg wet - wt) Estima ted Log BCF (lower trophic) = 2.781 (BCF = 604.3 L/kg wet - wt) Estimated Log BAF (lower trophic) = 4.813 (BAF = 6.494e+004 L/kg wet - wt) Arnot - Gobas BCF & BAF Methods (assuming a biotransformation rate of zero): Estimated Log BCF (upper trophic) = 3.85 6 (BCF = 7176 L/kg wet - wt) Estimated Log BAF (upper trophic) = 7.157 (BAF = 1.435e+007 L/kg wet - wt)

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Volatilization From Water
========================= Chemical Name: Molecular Weight : 301.95 g/mole Water Solubility : ----- Vapor Pressur e : ----- Henry's Law Constant: 0.0158 atm - m3/mole (estimated by Bond SAR Method) RIVER LAKE

--------- --------- Water Depth (meters): 1 1 Wind Velocity (m/sec): 5 0.5 Current Velocity (m/sec): 1 0.05 HALF - LIFE (hours) : 1.838 165.8 HALF - LIFE (days ) : 0.07657 6.906 STP Fugacity Model: Predicted Fate in a Wastewater Treatment Facility
======================================================= =============== (using 10000 hr Bio P,A,S) PROPERTIES OF:

------------- Molecular weight (g/mol) 301.95 Aqueous solubility (mg/l) 0 Vapour pressure (Pa) 0 (atm) 0 (mm Hg) 0 Henry 's law constant (Atm - m3/mol) 0.0158 Air - water partition coefficient 0.646173 Octanol - water partition coefficient (Kow) 2 .57039E+007 Log Kow 7.41 Biomass to water partition coefficient 5.14079E+006 Temperature [deg C] 25 Biodeg rate constants (h^ - 1),half life in biomass (h) and in 2000 mg/L MLSS (h):

- Primary tank 0.00 9999.03 10000.00

-Aeration tank 0.00 9999.03 10000.00

- Settling tank 0.00 9999.03 10000.00 STP Overall Chemical Mass Balance:

--------------------------------- g /h mol/h percent Influent 1.00E+001 3.3E - 002 100.00 Primary sludge 5.98E+000 2.0E - 002 59.84 Waste sludge 3.30E+000 1.1E - 002 32.97 Primary v olatilization 1.27E - 004 4.2E - 007 0.00 Settling volatilization 2.79E - 004 9.2E - 007 0.00 Aeration off gas 4.50E - 002 1.5E - 004 0.45 Primary biodegradation 1.75E - 002 5.8E - 005 0.18 Settling biodegradation 4.21E - 003 1.4E - 005 0.04

### oleylamine hydrochloride 20150623 egg.doc

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Aeration biodegradation 5.54E - 002 1.8E - 004 0.55 Final water effluent 5.97E - 001 2.0E - 003 5.97 Total removal 9.40E+000 3.1E - 002 94.03 Total biodegradation 7.71E - 002 2.6E - 004 0.77 Level III Fugacity Model (Full - Output): ======================================= Chem Name : Molecular Wt: 301.95 Henry's LC : 0.0158 atm - m3/mole (Henrywin pr ogram) Vapor Press : 2.24e - 005 mm Hg (Mpbpwin program) Liquid VP : 0.00011 mm Hg (super - cooled) Melting Pt : 95 deg C (Mpbpwin program) Log Kow : 7.41 (Kowwin program) Soil Koc : 3.59e+005 (KOCWIN MCI method) Mass Amount Half - Life Emis sions (percent) (hr) (kg/hr) Air 0.102 1.24 1000 Water 10.4 360 1000 Soil 50.3 720 1000 Sediment 39.2 3.24e+003 0 Fugacity Reaction Advection Reac tion Advection (atm) (kg/hr) (kg/hr) (percent) (percent) Air 1.68e - 012 1.17e+003 20.9 39.1 0.697 Water 1.98e - 008 412 214 13.7 7.13 Soil 3.48e - 010 993 0 33.1 0 Sediment 1.22e - 008 172 16.1 5.73 0.536 Persistence Time: 684 hr Reaction Time: 746 hr Advection Time: 8.18e+003 hr Percent Reacted: 91.6 Percent Advected: 8.36 Half - Lives (hr), (based upon Biowin (Ultimate) and Ao pwin): Air: 1.237 Water: 360 Soil: 720 Sediment: 3240 Biowin estimate: 2.830 (weeks ) Advection Times (hr): Air: 100 Water: 1000 Sediment: 5e+004



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