Competence Center Analytics

Final Report

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Characterization of "EFKA·3600N without DOA"

Study No. 11L00371 (confidential)

Test item

Chemical identity

Chemical structure

Batch identification

Date of production (test item)

Origin of test item

PSN

CAS no.

Sponsor

Date of receipt of order

Date of receipt of test item

Testing facility

Study director

Storage condo test item

Test period

Storage of records

Storage of sample of test item

Page 1 of 32

"EFKA-3600N without DOA"

Polyacrylat -Copolymer

GK3365-099 without DOA

Jun 07. 2011

Ms. Merz. GKD/A, B001

Efka-P-236

1334163-54-0

Dr. Engelbrecht, GKD/A - B001

Aug 29, 2011

Aug 29, 2011

Competence Center Analytics, BASF SE,

D-67056 Ludwigshafen

Mr. Beringer, GKC/C - E210

Ambient temperature

Sep 09 - Oct 19, 2011

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Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 2 of 32

Summary of results

The IR spectrum shows mainly the expected bands for the given chemical identity, but there are

additional bands which originate from anhydride.

The molecular weight distribution was investigated by gel permeation chromatography.

The THF soluble mass of the polymer amounts to

Mn = 2320 g/mol

Mw = 5470 g/mol

0= Mw/Mn = 2.4

fraction < 1000 and> 150 g/mol: 8.7 area-%

fraction < 500 and> 150 g/mol: 2.2 area-%

Quantitative determinations yielded:

< 100 mg/kg by GC

1 Appearance and Homogeneity

Method Visual inspection

Result At ambient temperature, the test item was a clear, colourless, viscous

liquid. It was seemingly homogeneous.

Date of test Sep 13, 2011

Head of laboratory Dr. Euler, GKC/C - E 210

2 Identity

Method IR Spectroscopy

Apparatus

Sample preparation

Nicolet 6700

Test item was measured as film on a KBr-disc.

Result

Resolution: 4.000 em"

Number of scans: 32

Temperature: ambient

The IR spectrum (page 11) shows mainly the expected bands for the

given chemical identity, but there are additional bands which originate

from anhydride.

Test parameters

Date of test

Head of laboratory

Oct 04,2011

Dr. Meyer, GKC/S - E 210
Competence Center Analytics a·BASF

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Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 3 of 32

3 Molecular mass distribution, fractions < 500 and < 1000 Dalton

Method Gel Permeation Chromatography

Apparatus Modular GPC system with a combination of columns and refractive

index detector

Reagents THF (BASF)

Mixture of polystyrene standards with known molecular mass distribution (Polymer Laboratories)

Heptylbenzene (Fluka)

Sample preparation About 95 -101 mg of the test item were weighed into a 10 ml

volumetric flask dissolved and filled up to the mark with THF.

Test parameters Columns: combination of 3 columns;

manufactured by Polymer Laboratories.

1) and 2) Mini-Mix C, 250mm x 4.6 mm i.d., dp = 5 IJm

3) Mini-Mix E, 250mm x 4.6 mm Ld.,dp = 3 IJm

Mobile phase: THF

Flow: 0.3 ml/min

Injection volume: 20 1-11

Temperature: 35°C

Detection: refractive index

Results Mn = 2320 g/mol

Mw = 5470 g/mol

D = Mw/Mn = 2.4 (mean value out of unrounded molecular weights)

fraction < 1000 and> 150 g/mol: 8.7 area-%

fraction < 500 and> 150 g/mol: 2.2 area-%

1. det 2. det mean

Mn (g/mol) 2315 2321 2320

Mw (g/mol) 5448 5485 5470

D 2.35 2.36 2.4

Fraction

<1000 >150 g/mol 8.68 8.65 8.7

(area-%)

Fraction

<500 >150 g/mol 2.23 2.25 2.2

(area-%)

Calibration curve see page 12

Because the results of the two determinations are similar only the

graphs of the first determination are depicted.
Competence Center Analytics a·BASF

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Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 4 of 32

GPC - diagram of test item correlated with molecular weight

distribution see page 12

GPC - diagrams of the test item and blank see page 13

Slice file report see pages 14 - 28

Note:

All GPC-values are referring to polystyrene resp. heptylbenzene used

as calibration standards.

Date of test Sep 14, 2011

Head of laboratory Dr. Euler, GKC/C - E 210

4 Content of residual monomer of n-butyl acrylate

Method Headspace gas chromatography, standard addition method

Apparatus Capillary gas chromatograph equipped with autosampler,

split injection system and flame ionisation detector (FlO)

adapted to a chromatography data system

Reagents -Dimethyl acetamide minimum 99.5 % (DMAA, Promochem)

-n-butyl acrylate (reference material, BASF)

-Drinking water

Sample preparation For the standard addition solution approx. 28 mg (solution 1)

and approx. 26 mg (solution 2) n-butyl acrylate exactly

weighed to 0.1 mg were dissolved in 5 or 10 ml DMAA.

Method of standard addition:

Approx. 231 - 255 mg of the test item exactly weighed to

0.1 mg were dissolved in 2 ml OMAA and 0.5 ml drinking

water. Approx. 256 - 271 mg of the test item exactly

weighed to 0.1 mg were mixed with 5 IJIstandard addition

solution 1 or 2. The mixtures were dissolved in 2 ml OMAA

and 0.5 ml drinking water.

Headspace conditions: Equilibration temp.:

Preliminary heating time:

Transfer line temp.:

Pressure bild-up time:

Normal pressure:

High pressure;

Injection time:

Dwell time:

Cycle time:

Analysis time:

90°C

60 min

150°C

1.0 min

115 kPa

180 kPa

6 sec

0.2 min

65 min

55 min
Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

a·BASF

The Chemical Company

Page 5 of 32

GC conditions Column:

Length:

Internal diameter:

Film thickness:

Carrier gas:

Head pressure:

Split:

Oven temperature:

Injector temperature:

Detector temperature:

CP-WAX 52 CB

50 m

0.32 mm

1.2 IJm

helium

70 kPa

10 mllmin

50°C, 5 min isothermal

SO "C - 200°C, 5°C/min

200°C, 15 min isothermal

150 °C

250°C

Result w (n-butyl acrylate) < 100 mg/ kg

Two determinations with and two determinations without

added standard were carried out.

Representative chromatograms see page 29.

Date of test Oct 18 -19,2011

Head of laboratory: Dr. Guntner, GKC/C, E210

5 Content of residual monomer of iso-butyl methacrylate

Method Headspace gas chromatography, standard addition method

Apparatus Capillary gas chromatograph equipped with autosampler,

split injection system and flame ionisation detector (FlO)

adapted to a chromatography data system

Reagents -Dimethyl acetamide minimum 99.5 % (DMAA, Promochem)

-Iso-butyl methacrylate (reference material, BASF)

-Drinking water

Sample preparation For the standard addition solution approx. 27 mg (solution 3)

and 26 mg (solution 4) of iso-butyl methacrylate exactly

weighed to 0.1 mg were dissolved in 5 or 10 ml DMAA.

Method of standard addition:

Approx. 260 - 285 mg of the test item exactly weighed to 0.1

mg were dissolved in 2 ml DMAA and 0.5 ml drinking water.

Approx. 240 - 273 mg of the test item exactly weighed to 0.1

mg were mixed with 5 IJI standard addition solution 3 or 4.

The mixtures were dissolved in 2 ml DMAA and O.S ml

drinking water.
competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

a·BASF

The Chemical Company

Page 6 of 32

Headspace conditions: Equilibration temp.:

Preliminary heating time:

Transfer line temp.:

Pressure bild-up time:

Normal pressure:

High pressure;

Injection time:

Dwell time:

Cycle time:

Analysis time:

GC conditions Column:

Length:

Internal diameter:

Film thickness:

Carrier gas:

Head pressure:

Split:

Oven temperature:

Injector temperature:

Detector temperature:

90°C

60 min

150°C

1.0 min

0.88 bar (turbomatrix)

1.4 bar

6 sec

0.2 min

75 min

57 min

DB-1

30 m

0.25 mm

1.0 IJm

helium

0.7 bar

5 ml/min

50°C, 5 min isothermal

50 -c - 260°C, 5°C/min

260°C, 10 min isothermal

150 °C

300°C

Result w (iso-butyl methacrylate) < 100 mgt kg

Two determinations with and two determinations without

added standard were carried out.

Representative chromatograms see page 30.

Date ottest Oct18,2011

Head of laboratory: Dr. GOntner, GKC/C, E210

6 Content of residual monomer of perfluorohexylethyl methacrylate

Apparatus

Method Headspace gas chromatography, standard addition method

Capillary gas chromatograph equipped with autosampler,

split injection system and flame ionisation detector (FlO)

adapted to a chromatography data system

Reagents -Dimethyl acetamide minimum 99.5 % (DMAA, Promochem)

-Perfluorohexylethyl methacrylate (reference material, BASF)

-Drinking water
Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

a·BASF

The Chemical Company

Page 7 of 32

Sample preparation For the standard addition solution approx. 24 mg (solution 3

and solution 4) of perfluorohexylethyl methacrylate exactly

weighed to 0.1 mg were dissolved in 5 or 10 ml DMAA.

Method of standard addition:

Approx. 260 - 285 mg of the test item exactly weighed to 0.1

mg were dissolved in 2 ml DMAA and 0.5 ml drinking water.

Approx. 240 - 273 mg of the test item exactly weighed to 0.1

mg were mixed with 5 jJl standard addition solution 3 or 4.

The mixtures were dissolved in 2 ml DMAA and 0.5 ml

drinking water.

Headspace conditions: Equilibration temp.:

Preliminary heating time:

Transfer line temp.:

Pressure bild-up time:

Normal pressure:

High pressure;

injection time:

Dwell time:

Cycle time:

Analysis time:

GC conditions Column:

Length:

Internal diameter:

Film thickness:

Carrier gas:

Head pressure:

Split:

Oven temperature:

Injector temperature:

Detector temperature:

Result

90°C

60 min

150°C

1.0 min

0.88 bar (turbomatrix)

1.4 bar

6 sec

0.2 min

75 min

57 min

D8-1

30 m

0.25 mm

1.0 IJm

helium

0.7 bar

5 mllmin

50°C, 5 min isothermal

50 °C - 260°C, 5 °C/min

260°C, 10 min isothermal

150°C

300 °C

w (perfluorohexylethyl methacrylate) < 100 mgl kg

Two determinations with and two determinations without

added standard were carried out.

Date of test Oct 18,2011

Representative chromatograms see page 30.

Head of laboratory: Dr. Guntner, GKC/C, E210
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600Nwithout DOA"

Study No. 11L00371 (confidential)

Page8 of 32

7 Residual content of acrylic acid

Method RP-HPLG with UV-detection and evaluation by the external standard

method.

Apparatus Automated HPLC System with autosampler, pump, column oven,

column switching and UVNIS-detector.

Reagents -Water (demineralized water from MiIliQ-system)

-Methanol (Merck)

-Phosphoric acid, 85 - 88 %, (Sigma-Aldrich)

Sample preparation Approx. 1 9 of the test item exactly weighed to 0.1 mg were transferred

into a 100 ml erlenmeyer flask, dissolved with 5 ml methanol and

precipitationed with 44 ml phosphoric acid, 0.1 %. The resultant

volume of the solution was 50 rnl, The supernantant solution was

filtrated

(0.2 prn) and injected.

For calibration approx. 35 - 53 mg of the acrylic acid were exactly

weighed to 0.01 mg into 50 ml volumetric flasks, dissolved, filled up to

the mark and diluted with water.

Measuring Parameters Column: Zorbax SB aq, 4.6 x 150 mm, 5 IJm (Agilent)

Mobile phase:

900 ml phosphoric acid 0.1 % + 100 ml methanol

Flow rate: 0.8 ml/min

Injection volume: 20 IJI

Detection: A = 205 nm

Note: 15 min after the injection the columns were back flushed for 12

min by using a column switching system. The next injection was

started 30 min after the previous injection.

Result w(acrylic acid) < 10 mg/kg

The result was the mean out of two determinations.

Representative chromatograms see page 31.

Date of test Sep 15, 2011

Head of laboratory Mr. Krempel, GKC/C - E 210

8 Residual content of methacrylic acid

Method RP-HPLC with UV-detection and evaluation by the external standard

method.
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 9 of 32

Apparatus

Reagents

Sample preparation

Measuring Parameters

Result

Date of test

Head of laboratory

Study director

(Mr. Beringer)

Automated HPLC System with autosampler, pump, column oven,

column switching and UVNIS-detector.

-Water (demineralized water from MilliQ-system)

-Methanol (Merck)

-Phosphoric acid, 85 - 88 %, (Sigma-Aldrich)

Approx. 1 g of the test item exactly weighed to 0.1 mg were transferred

into a 100 ml erlenmeyer flask, dissolved with 5 ml methanol and

precipitationed with 44 ml phosphoric acid, 0.1 %. The resultant

volume of the solution was 50 ml. The supernantant solution was

filtrated

(0.2 urn) and injected.

For calibration approx. 25 - 57 mg of the acrylic acid were exactly

weighed to 0.01 mg into 50 ml volumetric flasks, dissolved, filled up to

the mark and diluted with water.

Column: Zorbax SB aq, 4.6 x 150 mm, 5 urn (Agilent)

Mobile phase:

900 ml phosphoric acid 0.1 % + 100 ml methanol

Flow rate: 0.80 mllmin

Injection volume: 20 IJI

Detection: A = 205 nm

Note: 15 min after the injection the columns were back washed for 12

min by using a column switching system. The next injection start

30 min after the previous injection.

w(methacrylic acid) < 10 mg/kg

The result was the mean out of two determinations.

Representative chromatograms see page 31

Sep 15, 2011

Mr. Krempel, GKC/C - E 210

Date
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 10 of 32

GLP Compliance Statement

This study was conducted in accordance with the OECD Principles of Good Laboratory Practice

and the GLP Principles of the German "Chemikaliengesetz" (Chemicals Act).

Study director

(Mr. Beringer)

Date
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Scans: 32

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Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 12 of 32

GPC calibration curve

5.0 6.0 7.5

ElutIon~~um.n

GPC - diagram of the test item correlated with molecular weight distribution

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Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

Page 13 of 32

GPC diagrams

Test item

AS; og. ,A1

~----------------.----------------.------~ se:

11100371

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Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

a·BASF

The Chemical Company

Page 14 of 32

GPC slice file

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4

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10

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12

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16

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18

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20

21

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24

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29

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31

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34

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50

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71

72

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74

75

76

Molmasse RI ERe 75H Integral [%]

1.50000E+2 8.26172E·1 5.33071E·3

1.51604E"'2 1.16626E+O 1.22104E·2

1.53226E+2 1.08548E+0 1.87222E·2

1.54865E+2 7.59461E·1 2.37491E·2

1.56521E+2 1.07625E+0 3.02188E·2

1.58196E+2 1.10110E+O 3.8B017E·2

1.59888E+2 1.10508E+0 4.34027E·2

1.61598E+2 1.18468E+0 5.03663E·2

1.63326E+2 1.05653E+0 5.67462E·2.

1.65073E+2 1.10717E+0 6.33568E·2

1.66B39E+2 1.12600E+0 7.00532E·2

1.68624E+2 9.98079E·1 7.61669E·2

1.70427E+2 1.22584E+0 B.33179E-2

1.72250E+2 1.24715E+0 9.05661E-2

1.74093E+2 1.29067E+0 9.B0124E-2

1.75955E+2 1.37937E+0 1.05863E-1

1.77837E+2 1.35492E+0 1.13602E-1

1.79739E+2 1.27649E+0 1.20984E·1

1.81662E+2 1.25124E+O 1.2B250E-1

1.B3605E+2 1.4675BE+O 1.36503E-1

1.85569E+2 1.557B2E+0 1.45166E·1

1.87553E+2 1.52729E+0 1.53690E·1

1.89560E+2 1.53535E+0 1.62251E-1

1.91587E+2 1.58920E+0 1.71057E·1

1.93636E+2 1.B11B1E+O 1.B0877E-1

1.9570BE+2 1.9000BE+0 1.91099E-1

1.97801E+2 1.86240E+0 2.01149E-1

1.99917E+2 1.99205E+O 2.11790E-1

2.02055E+2 2.12761E"·O 2.23049E-1

2.04216E+2 2.10728E+0 2.34215E-1

2.06401E+2 2.16288E+0 2.45634E-1

2.0B608E+2 2.26227E+O 2.57505E·1

2.10840E+2 2.18552E+O 2.69028E·1

2.13095E+2 2.33064E+O 2.B1211E-1

2.15374£::+2 2.39029E+O 2.93666£::-1

2.17678E+2 2.36603E+0 3.06010E-1

2.20006E+2 2.35039E+0 3.18283E-1

2.22359E+2 2.47355E+O 3.31117E-1

2.24736E+2 2.5649SE+0 3.44368E·1

2.27142E+2 2.54143E+0 3.57511E-1

2.29571E+2 2.57811E+0 3.70821E-1

2.32027E+2 2.57972E+0 3.84139E-1

2.34509E+2 2.73363E+0 3.98158E-1

2.37017E+2 2.77541E+0 4.12367E·1

2.39552E+2 2.80106E+0 4.26692E-1

2.42115E+2 3.01526E"'0 4.41994E-1

2.44704E+2 3.10946E+0 4.57724E-1

2.47322E...2 3.17839E+0 4.73769E-1

2.49967E+2 3.26037E+0 4.90187E-1

2.52641E+2 3.43133E+O 5.07383E·1

2.55343E+2 3.42430E+0 5.24548E-1

2.58074E+2 3.60782E+0 5.42548E·1

2.60635E+2 3.74167E+0 5.61156E-1

2.63625E+2 3.82341E+0 5.80140E·1

2.66445E+2 4.09517E+0 6.00361 E-1

2.69295E+2 4.26522E+O 6.21355E·1

2.72175E+2 4.28751E+O 6.42452E-1

2.75086E+2 4.53235E+O 6.M663E·1

2.78029E+2 4.71792E+O 6.87720E-1

2.81002E+2 4.B7723E+0 7.11S02E·1

2.84008E+2 4.91990E+0 7.35478E·1

2.87046E+2 4.94735E+0 7.59580E·1

2.90116E+2 5.13961E+O 7.84557E·1

2.93219E+2 5.14687E+0 8.09568E·'

2.96356E+2 5.09740E+0 8.34353E·1

2.99526E+2 4.95805E+0 8.58503E·1

3.02729E+2 4.907S2E+0 8.82423E-1

3.05968E+2 4.B2563E+0 9.05970E·1

3.09240E+2 4.66196E+0 9.28772E-1

3.12548E"'2 4.53826E+0 9.51011E-'

3.15891E+2 4.32278E+0 9.72267E-1

3.19270E+2 4.22638E+O 9.93085E-1

3.22685E+2 3.96632E+O 1.01272E+O

3.26136E+2 3.74300E+O 1.03133E+O

3.29625E+2 3.53468E+0 1.04900E+0

3.33151E+2 3.31055E+O 1.06565E+0

i'iL0037'1

~W/1

A~ . .09. ./!'7
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 15 of 32

Molmasse RI ERe 75H Integral [%J 11LOO371

77 3.36714E+2 3. 17767E+0 1.08169E+0

78 3.40316E+2 3.01397E+0 1.09698E+0 EJ,J /l

79 3.43956E+2 2.83564E+0 1.11147E+0

80 3.47635E+2 2.83954E+0 1.12597E+0

81 3.51353E+2 2.89075E+0 1.14070E+0 /16, 09. .,/J'?

82 3.65111E+2 2.80432E+O 1.15504E+0 ~

83 3.58910E+2 2.82574E+O 1.16948E+0

84 3.62749E+2 2.96438E+0 1.18455E+0

85 3.66629E+2 2.95761E+0 1.19959E+0

86 3.70550E+2 3.03331E+0 1.21497E+0

87 3.74514E+2 3.22320E+0 1.23122E+0

88 3.78520E+2 3.58199E+0 1.24911E+0

89 3.82568E+2 3.692271:+0 1.26749E+0

90 3.86661E+2 3.96841E+0 1.28713E+0

91 3.90796E+2 4.24617E+0 1.30804E+0

92 3.94976E+2 4.62794E+0 1.33069E+0

93 3.99201E+2 5.02884E+0 1.35516E+0

94 4.03471E+2 5.40195E+0 1.38133E+0

95 4.07787E+2 5.84494E+0 1.40952E+0

96 4.12149E+2 6.31041E+0 1.43983E+0

97 4.16557E+2 6.63081E+0 1.47160E+0

98 4.21013E+2 7.06696E+0 1.50536E+0

99 4.25516E+2 7.61360E+0 1.54160E+0

100 4.30067E+2 8.16969E+0 1.58038E+0

0

101 4.34667E+2 8.48354E+0 1.62059E+0

102 4.39317E+2 9.02559E+0 1.66327E+0

103 4.44016E+2 9.32204E+0 1.70730E+0

104 4.48765E+2 9.79214E+0 1.75346E+0

105 4.53565E+2 9.90484E+0 1.80015E+0

106 4.58417E"'2 1.03503E+1 1.84886E+0

107 4.63320E+2 1.03668E+1 1.89764E+0

108 4.68276E+2 1.04795E+1 1.94694E+0

109 4.73285E+2 1.06502E+1 1.99702E+0

110 4.78347E+2 1.06289E"1 2.04700E+0

111 4.83463E+2 1.05259E+1 2.09651E+0

112 4.88635E+2 1.06568E+1 2.14661E+0

113 4.93861E+2 1.05518E+1 2.19624E+0

114 4.99144E+2 1.04267E+1 2.24530E+0

115 5.04483E+2 1.04097E+1 2.29428E+0

116 5.09879E+2 1.04206E+1 2.34331E+0

117 5.15333E+2 1.05827E+1 2.39308E+0

118 5.20845E+2 1.06856E+1 2.44332E+0

119 5.26416E+2 1.08684E+1 2.49439E+0

120 5.32046E+2 1.11578E+1 2.54678E+0

121 5.37737E+2 1.14948E+1 2.60070E+0

122 5.43489E ...2 1.17791E+1 2.65592E+0

123 5.49302E+2 1.21881E+1 2.71300E+0

0

1245.55178E+2 1.26473E+1 2.77218E+0

125 5.61116E+2 1.32098E+1 2.83391E+0

126 5.67118E+2 1.35667E+1 2.89727E+0

127 5.73184E+2 1.39611E+1 2.96243E+0

128 5.79315E"2 1.45797E+1 3.03040E+0

129 5.85512E+2 1.51725E+1 3.10108E+0

130 5.91774E+2 1.55222E+1 3.17334E+0

131 5.98104E+2 1.58928E+1 3.24730E+0

132 6,04502E+2 1.63615E+1 3.32339E+0

133 6.10967E+2 1.65878E+1 3.40051E+0

134 6. 17503E+2 1.70538E+1 3.47975E+0

135 6.2410BE+2 1.70B471:+1 3.55914E+0

136 6.30783E+2 1.74611E+1 3.64024E+0

137 6.37530E+2 1.76706E+1 3.72229E+0

138 6.44349E"2 1.79378E+1 3.80556E+0

139 6.51241E+2 1.80755E+1 3.88946E+0

140 6.58207E+2 1.83334E+1 3.97453E+0

141 6.65248E ....·2 1.84845E+1 4.06029E+O

142 6.72363E+2 1.87781E+1 4.14739E+0

143 6.79555E+2 1.91358E+1 4.23611E+O

144 6.86824E+2 1.95529E+1 4.32674E+0

145 6.94170E+2 1.98488E+1 4.41871E+0

146 7.01595E+2 2.02260E+1 4.51240E+0

147 7.09100E+2 2.07113E+1 4.60B31E+0

148 7. 16684E+2 2.11968E+1 4.70642E+0

149 7.24350E+2 2.16857E+1 4.80676E+O

150 7.32098E+2 2.21161E+1 4.90906E+0

151 7.39929E+2 2.25679E+1 5.01342E+0

152 7.47843E+2 2.29886E+1 5.11970E+0
competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 16 of 32

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0

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~oo

\...1'.201

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MoimaSS8

7.SS842E+2

7.63927E+2

7.72098E+2

7.80357E+2

7.88704E+2

7.97140E+2

8.0S666E+2

8.14264E+2

8.22994E+2

8.31797E+2

8.40694E+2

8.49686E+2

8.58774E+2

8.67960E+2

8.77244E+2

8.86627E+2

8.96111E+2

9.05696E+2

9.15383E+2

9.25175E+2

9.35071E+2

9.45072E+2

9.55181E+2

9.65398E+2

9.75724E+2

9.86161E+2

9.96709E+2

1.00737E+3

1.01815E+3

1.02904E+3

1.04004E+3

1.05117E+3

1.06241E+3

1.07377E+3

1.08526E+3

1.09687E+3

1.10860E+3

1.12046E+3

1.13244E+3

1.14456E..3

1.15680E+3

1.16917E+3

1.18168E+3

1.19432E+3

1.20709E+3

1.22000E+3

1.23305E+3

1.24624E+3

1.25957E+3

1.27304E+3

1.28666E+3

1.30042E+3

1.31433E+3

1.32839E+3

1.34260E+3

1.35696E+3

1.37148E+3

1.38615E+3

1.40097E+3

1.41596E+3

1.43110E+3

1.44641E+3

1.46188E+3

1.47752E+3

1.49332E"'3

1.50929E+3

1.S2544E+3

1.5417SE+3

1.SS82SE+3

1.57491E+3

1.59176E+3

1.60878E+3

1.62599E+3

1.64338E+3

1.66096E+3

1.67873E+3

RI ERe 75H Integral ["!o]

2.33830E+1 5.22777E+O

2.37009E+1 5.33729E+O

2.41509E+1 5.44885E+o

2.43969E+1 5.56154E+O

2.48537E+1 5.87631 E+O

2.52565E"1 5.79292E+O

2.57386E+1 S.91172E+O

2.60453E"'1 6.03192E+O

2.65240E+1 6.15429E+O

2.69349E"1 6.27854E+0

2.740S0E+1 6.40493E+O

2.78197E+1 6.53321E+O

2.8174BE+1 6.66311E+O

2.84947E+1 6.79446E+O

2.92S36E+1 6.92927E+O

2.96893E+1 7.06607E+O

3.01344E+1 7.20489E+O

3.05756E+1 7.34572E+O

3.10154E"'1 7.48856E+O

3.14678E+1 7.63345E+O

3.20196E+1 7.78086E+O

3.25406E+1 7.93064E+O

3.29600E+1 8.0B234E+O

3.35032E+1 8.23650E"'O

3.39316E"'1 8.39262E+O

3.44086E+1 8.55091 E+O

3.50760E"'1 8.71224E+0

3.53949E+1 8.87502E+0

3.59772E+1 9.04046E+O

3.65560E+1 9.20853E+0

3.71012E+1 9.37908E+0

3.7B541E+1 9.55307E+O

3.81217E+1 9.72827E+O

3.86420E+1 9.90584E+O

3.91961 E+1 1.00859E+1

3.97975E+1 1.02688E+1

4.04129E+1 1.04544E+1

4.09428E+1 1.06425E+1

4.15277E+1 1.08332E+1

4.19113E+1 1.10256E"1

4.25027E+1 1.12208E+1

4.30270E+1 1.14183E+1

4.36947E+1 1.16189E+1

4.44042E+1 1.18227E+1

4.47769E+1 1.20283E+1

4.52367E+1 1.22359E+1

4.60709E+1 1.24473E+1

4.65879E+1 1.26610E+1

4.72545E+1 1.28778E+1

4.76841E+1 1.30966E+1

4.84223E+1 1.33187E+1

4.89111E+1 1.35431E+1

4.94445E+1 1.37698E+1

5.01015E+1 1.39996E+1

5.06875E+1 1.42320E+1

5.12733E+l 1.44671E+1

5.19799E+1 1.47055E+1

5.26266E+1 1.49467E+1

5.32181E+1 1.51907E+1

5.37780E+l 1.54372E+1

5.42868E+1 1.56860E+1

5.49319E+l 1.59378E+1

5.56813E+l 1.61930E+1

5.63130E+l 1.64510E+l

5.69705E+1 1.67121E+1

5.76506E+1 1.69763E+1

5.80678E+1 1.72423E+1

5.88249E+1 1.75118E+1

5.93194E+1 1.77836E+1

6.00072E+1 1.80584E+1

6.07526E+1 1.83367E+1

6.1351BE+1 1.86177E+1

6.20290E+l 1.89018E+1

6.26757E+l 1.918B9E+1

6.32876E+1 1.94787E+1

6.38920E+1 1.97713E+1

.j 'i L 00371

ew'1

-es: t!)9. /f'1 7e
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

Page 17 of 32

229

230

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233

234

235

236

237

238

239

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246

247

248

249

250

251

252

r-,253

V254

255

256

257

258

259

260

261

262

263

264

265

266

267

268

269

270

271

272

273

274

275

0

276

277

278

279

280

281

282

283

284

285

286

287

288

289

290

291

292

293

294

295

296

297

298

299

300

301

302

303

304

Molmasse

1.69668E+3

1.71483E+3

1.73318E+3

1.75171E+3

1.77045E+3

1.78939E+3

1.80853E+3

1.82787E+3

1.84742E+3

1.86718E+3

1.88716E+3

1.90734E+3

1.92774E+3

1.94836E+3

1.96920E+3

1.99027E+3

2.0115SE+3

2.03307E+3

2.054B2E+3

2.07680E+3

2.09901E+3

2.12146E+3

2.14415E+3

2.16709E+3

2.19027E+3

2.21369E+3

2.23737E+3

2.26130E+3

2.28549E+3

2.30994E+3

2.3346SE+3

2.35962E+3

2.38486E+3

2.41037E+3

2.43615E+3

2.46220E+3

2.48854E+3

2.51516E+3

2.54206E+3

2.56925E+3

2.59673E+3

2.62451E+3

2.65258E+3

2.68095E+3

2.70963E+3

2.73861E+3

2.76791E+3

2.79751E+3

2.82744E+3

2.85768E+3

2.88824E+3

2.91914E+3

2.95036E+3

2.98192E+3

3.01382E+3

3.04605E+3

3.07863E+3

3.11156E+3

3.14485E+3

3.17848E+3

3.21248E+3

3.24684E+3

3.28157E+3

3.31667E+3

3.35215E+3

3.38800E+3

3.42424E+3

3.46087E+3

3.49789E+3

3.53530E+3

3.57312E+3

3.61134E+3

3.64996E+3

3.68900E+3

3.72846E+3

3.76834E+3

RI ERe 75H Integral ["101

6.44147E+1 2.00662E+1

6.S0364E+1 2.03640E+1

6.57096E+1 2.06649E+1

6.62756E+1 2.09683E+1

6.68149E+1 2.12742E+1

6.74558E+1 2.15830E+1

6.80614E+1 2.18946E+l

6.85646E+1 2.22085E+1

6.9l202E+1 2.25248E+l

6.98543E+1 2.28446E+1

7.04503E+1 2.31670E+1

7.09334E+1 2.34917E+1

7.14169E+1 2.38185E+1

7.21639E+1 2.41488E+1

7.26504E+1 2.44813E+1

7.32371E+1 2.4Bl64E+l

7.39011E+1 2.51546E+l

7.45200E+l 2.54956E+1

7.50219E+1 2.58388E+1

7.54937E+1 2.61843E+1

7.59982E+l 2.65320E+l

7.664S0E+1 2.68826E+1

7.72008E+1 2.72358E+1

7.77602E+1 2.75916E+1

7.82963E+1 2.79498E+1

7.88424E+1 2.83104E+1

7.93722E+1 2.86735E+1

7.99350E+1 2.90392E+1

8.04273E+1 2.94071E+1

8.08224E+l 2.97768E+1

8.15075E+1 3.01496E+1

8.19308E+1 3.05243E+1

B.25584E+1 3.09019E+1

8.26674E+1 3.12800E+1

8.34106E+1 3.16615E+l

8.39464E+1 3.20454E+l

8.42623E+l 3.24308E+1

8.49007E+1 3.28l91E+l

8.54180E+l 3.32097E+1

8.58288E+1 3.36022E+1

8.63566E+1 3.39971E+1

8.67834E+1 3.43939E+1

8.72156E+1 3.47927E+1

8.76926E+1 3.51937E+1

8.81393E+1 3.55967E+1

8.86439E+1 3.60021 E+1

8.90002E+1 3.64090E+1

8.94794E+1 3.68181 E+1

8.99506E+1 3.72294E+1

9.04922E+1 3.78431 E+1

9.10049E+1 3.80592E+1

9.12532E+1 3.84764E+1

9.14902E+1 3.88947E+1

9.20525E+1 3.93155E+1

9.26128E+1 3.97389E+1

9.29071E+1 4.01637E+1

9.33363E+1 4.05904E+1

9.37879E+1 4.10191 E+1

9.40496E+1 4.14490E+1

9.44899E+1 4.18810E+1

9.48518E+1 4.23146E+1

9.52499E+1 4.27500E+1

9.53901 E+1 4.31860E+1

9.5B907E+1 4.36244E+1

9.62153E+l 4.40642E+1

9.64425E+1 4.45050E+1

9.66302E+1 4.49467E+1

9.69134E+1 4.53897E+1

9.72245E+1 4.58341E+1

9.74387E+1 4.62794E+1

9.77124E+1 4.67261E+1

9.81079E+1 4.71745E+1

9.82660E+1 4.76236E+1

9.84748E+1 4.80737E+1

9.87052E+1 4.85249E+1

9.88740E+1 4.89768E+1

.j 1 L 00371

EW/I

/I.{". OS. ~
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 18 of 32

Molmasse RI ERe 75H Integral [%] 11LOO371

305

306

3.80865E+3

3.84939E+3

9.90654E+1

9.91594E+1

4.94296E+1

4.98828E+1 eWA

307 3.89056E+3 9.92771E+1 5.03365E+1

309

308

3.97424E+3

3.93218E+3

9.96474E+1

9.94279E+1

5.

5.07910E+1

12464E+1

/(J": .99_ /1'1 K 310 4.01675E+3 9.94755E+1 5.17011E+1

311 4.05971E+3 9.96639E+1 5.21566E+1

312 4.10313E+3 9.96994E+1 5.26123E+1

313 4.14702E+3 9.98174E+1 5.30685E+1

314 4.19138E+3 9.98064E+1 5.35246E+l

315 4.23621E+3 9.98507E+1 5.39810E+1

316 4.28152E+3 9.99902E+1 5.44380E+1

317 4.32732E+3 9.97946E+1 5.48941E+1

318 4.37361E+3 9.97480E+1 5.53500E+1

319 4.42039E+3 9.97077E+1 5.58057E+1

320 4.46767E+3 9.95750E+1 5.62608E+1

321 4.51546E+3 9.94522E+1 5.67154E+1

322 4.56375E+3 9.94117E+1 5.71697E+1

323 4.61257E+3 9.93530E+1 5.76238E+1

324 4.66191E+3 9.91320E+1 5.80769E+1

325 4.71177E+3 9.89234E+1 5.85290E+l

326 4.76217E+3 9.87902E+l 5.89806E+1

327 4.81311E+3 9.86773E+l 5.94316E+1

328 4.86459E+3 9.85796E+l 5.98822E+1

a

Z9 4.91662E+3 9.82853E+1 6.03314E+1

30 4.96921E+3 9.80373E+1 6.07795E+1

331 5.02236E+3 9.77719E+1 6.12264E+1

332 5.07608E+3 9.76149E+1 6.16726E+1

333 5.13038E+3 9.73620E+1 6.21176E+1

334 5.18526E+3 9.71064E+l 6.25615E+l

335 5.24072E+3 9.69744E+1 6.30047E+1

336 5.29677E+3 9.67449E+1 6.34469E+1

337 5.35343E+3 9.64067E+1 6.38876E+1

338 5.41069E+3 9.61153E+1 6.43270E+1

339 5.46857E+3 9.57469E+l 6.47646E+1

340 5.52706E+3 9.53592E+1 6.52005E+1

341 5.58618E+3 9.49026E+1 6.56344E+l

342 5.64593E+3 9.46182E+1 6.60669E+1

343 5.70632E+3 9.44056E+1 6.64984E+l

344 5.76736E+3 9.40931E+1 6.69286E+1

345 5.82904E+3 9.36947E+1 6.73569E+1

34e 5.89139E+3 9.32893E+1 6.77834E+1

347 5.95441E+3 9.29323E+1 6.82082E"'1

34e 6.01810E+3 9.25300E+1 6.86313E+1

349 6.08247E+3 9.22653E+l 6.90531E+1

350 6.14753E+3 9.18498E+1 6.94730E+1

351 6.21329E+3 9.14214E+1 6.98910E+l

0!52 6.27974E+3 9.10538E+1 7.03072E+1

53 6.34691E+3 9.05164E+1 7.07211E+l

354 6.41480E+3 9.01362E+1 7.11332E+1

355 6.48342E+3 8.97643E+1 7.15436E+l

356 6.55277E+3 8.92772E+l 7.19518E+1

357 6.62286E+3 B.B7883E+1 7.2357BE+1

358 6.69370E+3 8.82509E+1 7.27613E+l

359 6.76529E+3 6.77262E+1 7.31625E+1

360 6.B3766E+3 8.71914E+l 7.35612E+l

361 6.91079E+3 8.68288E+1 7.39582E+1

362 6.98471E+3 8.63446E+1 7.43531E+l

363 7.05942E+3 8.56841E+1 7.47449E+l

364 7.13493E+3 8.51829E+l 7.51345E+1

365 7.21125E+3 8,46305E+1 7.55215E+1

366 7.28838E+3 6.41839E+1 7.59065E+l

367 7.36634E+3 6.37213E+1 7.62894E+1

368 7.44513E+3 8.30492E+1 7.66692E+1

369 7.52477E+3 8.24097E+1 7.70462E+1

370 7.60526E+3 8.18429E+1 7.74205E+1

371 7.68660E+3 8.12759E+l 7.77923E+1

372 7.76882E+3 8.07106E+l 7.81615E+1

373 7.85192E+3 8.01452E+1 7.852B1E+1

374 7.93590E+3 7.94313E+1 7.B8914E+1

375 8.02079E+3 7.87582E+1 7.92517E+1

376 8.10658E+3 7.81460E+1 7.96092E+1

377 8.19329E+3 7.75458E+l 7.99640E+l

378 8.28093E+3 7.68420E+1 8.03155E+l

379 8.369SOE+3 7.62139E+1 8.06842E+1

380 8.45903E+3 7.S5534E+l 8.10099E+l
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

Page 19 of 32

11LOO371 Molmasse RI ERe 751~ Integral rID]

381 8.54951E+3 7.48754E+1 8.13525E+1 eW/?

382 B.64095E+3 7.42296E+l B.16922E+l

383 8.73338E+3 7.34574E+l 8.20284E+1

384 8.82679E+3 7.27746E+l 8.23614E+l A.>. 09, /1'17:e_

385 8.92121E+3 7.22l98E+l 8.26919E+1

386 9.0l663E+3 7.l54l7E+l 8.30l93E+l

387 9.11308E+3 7.08124E+1 8.33434E+1

388 9.2l055E+3 7.0l376E+l B.36645E+l

389 9.30907E+3 6.93790E+l 8.39820E+l

390 9.40864E+3 6.B6459E+1 8.42963E"'1

391 9.50928E+3 6.79783E+l 8.46074E+l

392 9.61099E+3 6.72274E+1 8.49152E+1

393 9.7l380E+3 6.63955E+1 8.52192E+1

394 9.8l770E+3 6.55737E+l 8.55194E+1

395 9.92271E+3 6.48600E+l 8.58164E+1

396 1.00288E+4 8.4l476E+1 8.61102E+1

397 1.0l361E+4 6.34110E+1 8.64006E+1

398 1.02445E+4 6.26160E+1 8.66873E+1

399 1.03S41E+4 6.l80l7E+l B.69704E+1

400 1.04649E+4 6.09885E+1 8.72497E+l

401 1.05768E+4 6.03492E+l 8.7S262E+l

402 1.06899E+4 5.96283E+l 8.77993E+l

403 1.08043E+4 5.88402E+l 8.80689E+l

404 1.09l98E+4 5.80655E+l 8.83350E+l

O:g~1.l0366E+4 5.73359E+l 8.85977E+l

1.11S47E+4 5.63BB3E+l 8.88561E+1

407 1.12740E+4 5.54437E+1 B.91102E+l

408 1.13946E+4 5.45B9BE+1 8.93604E+l

409 1.15165E+4 5.38939E+1 8.96074E+1

410 1.16397E+4 5.31162E+1 B.98S09E+l

411 1.17642E+4 S.21815E+1 9.00902E+1

412 1.18900E+4 5.15566E+1 9.03266E+1

413 1.20172E+4 5.07972E+l 9.05595E+1

414 1.2l457E+4 4.97351E+l 9.07876E+1

415 1.22756E+4 4.89879E+1 9.10123E+1

416 1.24069E+4 4.82343E+1 9.12336E+1

417 1.25396E+4 4.74673E+1 9.14513E+l

418 1.26738E+4 4.67639E+l 9.16659E+1

419 1.28093E+4 4.S967SE+l 9.18768E+1

420 1.29463E+4 4.51802E+l 9.20842E+l

421 1.30848E+4 4.43662E+l 9.22878E+l

422 1.3224BE+4 4.36243E+1 9.24881E+1

423 1.33662E+4 4.28S80E+1 9.26849E+l

424 1.35092E+4 4.20220E+l 9.28778E+l

425 1.36537E+4 4.12277E+1 9.30672E+l

426 1.37997E+4 4.04406E+l 9.32529E+1

427 1.39473E+4 3.97067E+1 9.34354E+l

0!28 1.40965E+4 3.89733E+l 9.36144E+1

429 1.42473E+4 3.BOBB1E+l 9.37B9SE+l

430 1.43997E+4 3.74001E+1 9.39614E+1

431 1.45S37E+4 3.66360E+1 9.41298E+l

432 1.47094E+4 3.58413E+1 9.42947E+l

433 1.48667E+4 3.51801E+1 9.44565E+l

434 1.50257E+4 3.4Sl32E+l 9.46l52E+l

435 1.5l865E+4 3.37855E+l 9.47707E+1

436 1.53489E+4 3.32042E+l 9.49235E+l

437 1.5Sl31E+4 3.24738E+l 9.50730E+l

438 1.56790E+4 3.17397E+1 9.52191E+1

439 1.58467E+4 3.09353E+l 9.53616E+l

440 1.60l62E+4 3.03262E+1 9.55013E+l

441 1.6l875E+4 2.97563E+l 9.56384E+l

442 1.63607E+4 2.90702E+1 9.57723E+l

443 1.6S357E+4 2.84522E+l 9.S9035E+1

444 1.67l25E+4 2.77865E+1 9.60315E+l

445 1.66913E+4 2.71536E+1 9.61569E+1

446 1.70720E+4 2.65901E+l 9.62796E+l

447 1.72546E+4 2.5883SE+l 9.63990E+l

448 1.74391E+4 2.5l951E+l 9.6S153E+l

449 1.76257E+4 2.47133E+1 9.66295E+1

450 1.7B142E+4 2.40762E+l 9.67407E+l

451 1.80047E+4 2.34566E+1 9.68491E+l

452 1.81973E+4 2.28970E+1 9.69550E+l

453 1.83920E+4 2.23425E+l 9.70SB3E+l

454 1.85887E+4 2.17893E+l 9.71591E+1

455 1.87875E+4 2.12374E+1 9.72574E+l

456 1.89885E+4 2.06868E+l 9.73532E+1
Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

a·BASF

The Chemical Company

Page 20 of 32

457

458

459

460

461

462

463

464

465

466

467

468

469

470

471

472

473

474

475

476

477

478

479

480

~481

"\L7482

483

484

485

486

487

488

489

490

491

492

493

494

495

498

497

498

499

500

501

502

503

.A":l.504

'-J505

506

507

508

509

510

511

512

513

514

515

516

517

518

519

520

521

522

523

524

525

526

527

528

529

530

531

532

Molmasse

1.91916E+4

1.93969E+4

1.96043E+4

1.98140E+4

2.00260E+4

2.02402E+4

2.04567E+4

2.06755E+4

2.08966E+4

2.11201 E+4

2.13461E+4

2.15744E+4

2.18051E+4

2.20384E+4

2.22741E+4

2.25124E+4

2.27531E+4

2.29965E+4

2.32425E+4

2.34911E+4

2.37424E+4

2.39963E+4

2.42530E+4

2.45124E+4

2.47746E+4

2.50396E+4

2.53074E+4

2.55781E+4

2.58517E+4

2.61282E+4

2.64077E+4

2.66902E+4

2.69757E+4

2.72642E+4

2.75558E+4

2.78506E+4

2.81485E+4

2.84495E+4

2.87538E+4

2.90614E"'4

2.93723E+4

2.96864E+4

3.00040E+4

3.03249E+4

3.06493E+4

3.09771E+4

3.13084E+4

3.16433E+4

3.19818E+4

3.23239E+4

3.26696E+4

3.30190E+4

3.33"122E+4

3.37292E+4

3.40900E+4

3.44546E+4

3.48231E+4

3.51956E+4

3.55721E+4

3.59526E+4

3.63371E+4

3.67258E+4

3.71186E+4

3.75156E+4

3.79169E+4

3.83225E+4

3.87324E+4

3.91467E+4

3.95654E+4

3.99886E+4

4.04163E+4

4.06486E"'4

4.12856E+4

4.17272E+4

4.21735E+4

4.26246E"'4

RI ERe 751 e Integral [%]

2.02032E+1 9.74468E+1

1.96675E+1 9.75379E+1

1.91796E+1 9.76269E+1

1.86547E+1 9.77134E+1

1.81085E+1 9.77974E+1

1.76082E+1 9.78792E+1

1.71039E+1 9.79587E+1

1.66238E+1 9.80360E+1

1.61862E+1 9.81113E+1

1.56669E"'1 9.81842E+1

1.51740E+1 9.82549E+1

1.46042E+1 9.83230E+1

1.43600E+1 9.83899E+1

1.38266E+1 9.84545E+1

1.35089E+1 9.85176E+1

1.30679E+1 9.85787E+1

1.24919E+1 9.86371 E+1

1.21051E+1 9.86938E+1

1.17537E+1 9.87489E+1

1.13741E+1 9.88023E+1

1.09974E+1 9.88540E+1

1.06513E+1 9.89040E+1

1.03046E+1 9.89525E+1

9.87036E+0 9.89991E+1

9.50846E+0 9.90439E+1

9.20902E+0 9.90875E+1

8.91035E+0 9.91296E+1

8.54195E+0 9.91701E+1

8.17046E+0 9.92089E+1

7.80322E+0 9.92460E+1

7.48470E+0 9.92816E+1

7.23258E+0 9.93161E+1

6.94109E+0 9.93493E+1

6.65944E+0 9.93812E+1

6.42670E+0 9.94121E+1

6.04612E"'0 9.94412E+1

5.88799E+0 9.94696E+1

5.59740E+Q 9.94966E+1

5.38022E+0 9.95227E+1

5.16407E+0 9.95478E+1

4.948461i+0 9.95719E+1

4.68344E+0 9.95948E+1

4.48094E+0 9.96168E+1

4.30485E+O 9.96379E+1

4.03768E+0 9.96579E+1

3.79362E+O 9.96768E+1

3.81002E+O 9.96957E+1

3.52272E+0 9.97133E+1

3.16770E+0 9.97293E+1

3.01497E+0 9.97446E+1

2.99093E+0 9.97598E+1

2.89268E+0 9.97745E+1

2.75468E+0 9.97886E+1

2.54830E+0 9.98018E+1

2.34553E+0 9.96141E+1

2.25882E+0 9.98259E+1

2.14040E+0 9.96372E+1

2.13890E+0 9.98485E+1

1.93240E+0 9.98589E+1

1.91130E+0 9.98692E+1

1.86159E+0 9.98792E+1

1.74868E+0 9.98888E+1

1.57534E+O 9.98975E+1

1.42695E+0 9.99056E+ 1

1.34269E+0 9.99133E+1

1.20556E+0 9.99203E+1

1.07352E+0 9.99268E+1

1.00603E+0 9.99329E+1

1.06197E+0 9.99393E+1

926384E-1 9.99451E+1

7.68514E-1 9.99502E+1

7.70967E-1 9.99553E+1

7.63850E-1 9.99603E+1

5.55966E-1 9.99644E+1

5.46591 E-1 9.99685E+1

4.16044E-1 9.99719E+1

11L0037'j

Ghl/f

/l b. 0.5'. /l".,::e
Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

a·BASF

The Chemical Company

Page 21 of 32

Molmasse RI ERe 75H Integral [%1

533 4.30805E+4 4.77056E-1 9.99757E+1

534 4.35413E+4 3.81490E-1 9.99790E+1

535 4.40070E+4 2.96279E-1 9.99819E+1

536 4.44778E+4 2.32763E-1 9.99845E+1

537 4.49535E+4 2.46774E-1 9.99872E+1

538 4.54343E+4 3.19242E-1 9.99902E+1

539 4.59203E+4 2.03857E-1 9.99927E+1

540 4.64115E+4 2.06516E-1 9.99952E+1

541 4.69079E+4 1.44759E-1 9.99975E+1

542 4.74097E+4 1.37809E-1 9.99997E+1

543 4.79168E+4 1.86201E-1 1.00000E+2

S44 4.84293E+4 1.87327E-1 1.00000E+2

545 4.89473E+4 1.00353E-1 1.00000E+2

546 4.94709E+4 5.87721E-4 1.00000E+2

o

o

'j 1 La 0371

EW/l

-r«. 05'. /1'1 rte
Competence Center Analytics a·BASF

The Chemical Company

Final Report Page 22 of 32

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

77

78

79

80

81

82

83

84

85

86

87

88

89

90

91

92

93

94

95

96

97

98

99

100

a0

1

02

103

104

105

106

107

108

109

110

111

112

113

114

115

116

117

118

119

120

121

122

123

Q

24

25

126

127

128

129

130

131

132

133

134

135

136

137

138

139

140

141

142

143

144

145

146

147

148

149

150

151

152

Molmasse

3.53886E+2

3.57601E+2

3.61356E+2

3.6515OE+2

3.68984E+2

3.72858E+2

3.76773E+2

3.80729E+2

3.84726E+2

3.88766E+2

3.92847E+2

3.96972E+2

4.0114OE+2

4.05352E+2

4.09608E+2

4.13909E+2

4.18254E+2

4.22646E+2

4.27083E+2

4.31568E+2

4.36099E+2

4.40678E+2

4.45304E+2

4.49980E+2

4.54704E+2

4.59479E+2

4.64303E+2

4.69178E+2

4.74104E+2

4.79082E+2

4.84112E+2

4.89195E+2

4.94331E+2

4.99521E+2

5.04766E+2

5.10066E+2

5.15421E+2

5.20833E+2

5.26301E+2

5.31827E+2

5.37411E+2

5.43054E+2

5.48755E+2

5.54517E+2

5.60339E+2

5.66222E+2

5.72168E+2

5.78175E+2

5.84246E+2

5.90380E+2

5.96578E+2

6.02842E+2

6.09172E+2

6.15568E+2

6.22031E+2

6.28562E+2

6.35161E+2

6.41830E+2

6.48569E+2

6.55379E+2

6.62260E+2

6.69213E+2

6.76240E+2

6.83340E+2

6.90515E+2

6.97765E+2

7.05091E+2

7.12494E+2

7.19975E+2

7.27534E+2

7.35173E+2

7.42892E+2

7.50692E+2

7.58573E+2

7.66538E+2

7.74586E ...2

RI ERe 75H Integral ['Yo]

6.79603E+0 1.49881 E+O

7.51969E+0 1.53219E+0

7.70551 E+O 1.56638E+0

8.15229E+0 1.60250E+0

8.41215E+0 1.63975E+0

9.45690E+0 1.68153E+0

1.01727E+1 1.72641 E+O

1.0794OE+1 1.77399E+0

1.2024OE+1 1.82689E+0

1.33666E+1 1.88562E+0

1.47866E+1 1.95050E+0

1.66207E+1 2.02333E+0

1.65481 E+1 2.10452E+0

2.09528E+1 2.19613E+0

2.33698E+1 2.29822E+0

2.64402E+1 2.41361E ...0

2.95437E+1 2.54246E+0

3.32745E+1 2.68748E+0

3.73129E+1 2.85001E+0

4.16024E+1 3.03113E+0

4.60755E+1 3.23164E+0

5.12844E+1 3.45473E+0

5.62655E+1 3.69941E+0

6. 18326E+ 1 3.96822E+0

6.71577E+1 4.26012E+0

7.28749E+1 4.57679E+O

7.83067E+1 4.91702E+0

8.31544E+1 5.27825E+0

8.79459E+1 5.66026E+0

9.207946+1 6.06018E+0

9.55620E+1 6.47520E+0

9.82025E+1 6.90167E+0

9.96311 E+1 7.33433E+0

9.99189E+1 7.76823E+0

9.949971:+1 8.20032E+0

9.81147E+l 8.62641E+0

9.55380E+1 9.04132E+O

9.21533E+1 9'44157E+0

8.77650E+1 9.82279E+0

8.24918E+l 1.01812E+1

7.69367E+1 1.05154E+1

7. 12255E+1 1.08250E+1

6.53419E+1 1.11090E+l

5.97427E+1 1.13687E+1

5.37766E+1 1.16026E+1

4.85133E+1 1.18137E+1

4.33967E+1 1.20026E+1

3.90536E+1 1.21727E+l

3.51788E+1 1.23260E+1

3.16684E+1 1.24640E+1

2.88847E+1 1.25900E+l

2.64999E+1 1.27057E+1

2.46415E+1 1.28133E+1

2.30282E+1 1.29139E+1

2.17309E+1 1.30089E+1

2.09758E+1 1.31006E+1

2.01027E+1 1.31885E+1

1.92469E+1 1.32727E+1

1.94168E+1 1.33577E+1

1.90126E+1 1.34409E+1

1.89349E+1 1.35237E+1

1.879906:+1 1.36060E+1

1.89455E+1 1.36889E+1

1.91152E"1 1.37725E+1

1.B4200E+1 1.38575E+1

1.96261 E+1 1.39434E+1

2.01261E+1 1.40314E+1

2.06093E+1 1.41215E+1

2.07937E+1 1.42124E"1

2.12627E+1 1.43054E+1

2.15469E+1 1.43996E+1

2.20202E+1 1.44958E+1

2.25693E+1 1.45944E+1

2.29518E+1 1.46947E+1

2.33843E+1 1.47969E+1

2.36171 E+1 1.49000E+1

&'17/4

11L00246

'2?-. o», A1 ~
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA·3600N without DOA"

Study No. 11L00371 (confidential)

Page 23 of 32

Molmasse RI ERe 751 e Integral [%] Gh//f

153 7.82719E+2 2.39439E+1 1.50046E+1

154 7.90937E+2 2.430S9E+1 1.S1107E+1

155 7.99242E+2 2.46183E+1 1.52182E+1

156 8.07633E+2 2.49362E+1 1.S3271E+1 '11LOO246

157 8.16113E+2 2.52557E+1 1.54374E+1

158 8.24682E+2 2.57216E+l 1.55497E+1

159 8.33340E+2 2.61855E+1 1.56639E+1 27. Oi-. A17?:_

160 8.42090E+2 2.65284E+1 1.57797E+1

161 8.50932E+2 2.70951E+1 1.58980E+1

162 8.S9866E+2 2.73120E+1 1.60171E+1

163 8.68894E+2 2.77868E+1 1.61384E+1

164 8.78017E+2 2.82S68E+1 1.62616E+1

165 8.87236E+2 2.87304E+1 1.63870E+1

166 8.965S1E+2 2.90273E+1 1.65136E+1

167 9.05965E+2 2.93664E+1 1.66417E+1

168 9.1S477E+2 2.9999SE+1 1.6772SE+1

169 9.2S089E+2 3.05538E+1 1.69057E+1

170 9.34802E+2 3.10015E+1 1.70409E+1

171 9.44617E+2 3.13161E+1 1.71774E+1

172 9.S4S35E+2 3.16341E+1 1.731S3E+1

173 9.64557E+2 3.20591E+1 1.74551E+l

174 9.74684E+2 3.25324E+1 1.75969E+1

175 9.84918E+2 3.27487E+1 1.77396E+1

176 9.95259E+2 3.33121E+1 1.78848E+1

a

77 1.00571E+3 3.37990E+1 1.80321E+1

78 1.01627E+3 3.47061E+1 1.81833E+1

179 1.02694E+3 3.47602E+1 1.83348E+1

180 1.03772E+3 3.54864E+1 1.84894E+1

181 1.04862E+3 3.58538E+1 1.86456E+1

182 1.05963E+3 3.65100E+1 1.86046E+1

183 1.07075E+3 3.72088E+1 1.89667E+1

184 1.08199E+3 3.75339E+1 1.91302E+1

185 1.09335E+3 3.77595E+1 1.92947E+1

186 1.10483E+3 3.83198E+1 1.94616E+1

187 1.11643E+3 3.89333E+1 1.96311E+1

188 1.12816E+3 3.95559E+1 1.98034E+1

189 1.14000E+3 4.00229E+1 1.99776E+1

190 1.15197E+3 4.05867E+1 2.01543E+1

191 1.16407E+3 4.10033E+1 2.03329E+1

192 1.17629E+3 4.16403E+1 2.05142E+1

193 1.18864E+3 4.21870E+1 2.06978E+1

194 1.20112E+3 4.26577E+1 2.08835E+1

195 1.21373E+3 4.32538E+1 2.10718E+1

196 1.22647E+3 4.37306E+1 2.12621E+1

197 1.239351::+3 4.434861::+1 2.145521::+1

198 1.25236E+3 4.45257E+1 2.16489E+1

199 1.26551E+3 4.51427E+1 2.18454E+1 GOO 1.27880E+3 4.57820E+1 2.20447E+1

01 1.29223E+3 4.65340E+1 2.22471E+1

202 1.30579E+3 4.70794E+1 2.24520E+1

203 1.31950E+3 4.75183E+1 2.26588E+1

204 1.33336E+3 4.81401E+1 2.26662E+1

205 1.34736E+3 4.86766E+1 2.30800E+1

206 1.36150E+3 4.94715E+1 2.32952E+1

207 1.375BOE+3 4.99462E+1 2.35125E+1

208 1.39024E+3 5.04128E+1 2.37319E+1

209 1.40464E+3 5.09379E+1 2.39534E+l

210 1.41959E+3 5.15885E+1 2.41779E+1

211 1.43450E+3 5.20540E+1 2.44043E+1

212 1.44956E+3 5.25768E+1 2.46330E+1

213 1.46478E+3 5.30735E+1 2.48638E+1

214 1.48016E+3 5.37741E+1 2.50977E+1

215 1.49570E+3 5.41563E+1 2.53332E+1

216 1.51140E+3 5.50040E+1 2.55724E+1

217 1.52727E+3 5.56360E+1 2.58144E+1

218 1.54331E+3 5.61013E+1 2.60584E+l

219 1.55951E+3 5.65623E+1 2.63043E+1

220 1.57588E+3 5.71298E+l 2.65528E+1

221 1.59243E+3. 5.74130E+1 2.68024E+1

222 1.60915E+3 5.83612E+1 2.70562E+1

223 1.62604E+3 5.88910E+1 2.73122E+1

224 1.64312E+3 5.96078E+l 2.75714E+1

225 1.86037E+3 6.01139E+1 2.78328E+1

226 1.67780E+3 6.05828E+1 2.80962E+1

227 1.69542E+3 6.12811E+1 2.83626E+1

228 1.71322E+3 6.18177E+1 2.86313E+1
competence Center Analytics a·BASF

The Chemical Company

Final Report Page 24 of 32

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

229

230

231

232

233

234

235

236

237

238

239

240

241

242

243

244

245

246

247

248

249

2150

251

2152

a~255

256

257

258

259

260

261

262

263

264

265

266

267

268

269

270

271

272

273

274

275

~76

~77

278

279

260

281

282

283

284

285

286

287

288

289

290

291

292

293

294

295

296

297

298

299

300

301

302

303

304

Molmass8

1.73121E+3

1.74938E+3

1.76775E+3

1.78631E+3

1.60507E+3

1.82402E+3

1.84317E+3

1.86252E+3

1.88208E+3

1.90l84E+3

1.92181E+3

1.94l98E+3

1.96237E+3

1.98298E+3

2.00380E+3

2.024B4E+3

2.04610E+3

2.06758E+3

2.08929E+3

2.11123E+3

2.1.3339E+3

2.15579E+3

2.17843E+3

2.20130E+3

2.22441E+3

2.24777E+3

2.27137E+3

2.29521E+3

2.31931E+3

2.34366E+3

2.36827E+3

2.39314E+3

2.41826E+3

2.44365E+3

2.46931E+3

2.49524E+3

2.52144E+3

2.54791E+3

2.57466E+3

2.60170E+3

2.62901E+3

2.65661E +3

2.68451E+3

2.71269E+3

2.74118E+3

2.76996E+3

2.79904E+3

2.82843E+3

2.85812E+3

2.88813E+3

2.91846E+3

2.94910E+3

2.98006E+3

3.01135E+3

3.04297E+3

3.07492E+3

3.10721E+3

3.13983E+3

3.17280E+3

3.206llE+3

3.23977E+3

327379E+3

3.30816E+3

3.34289E+3

3.37799E"3

3.4l346E+3

3.44930E+3

3.46551E+3

3.52211E+3

3.55S09E+3

3.59646E+3

3.63422E+3

3.67238E+3

3.7l094E+3

3.74990E+3

3.76927E+3

RI ERe 751f Integral flo]

6.23452E+l 2.89024E+l

6.29502E+l 2.91760E+l

6.34601E+1 2.94519E+1

6.39100E+l 2.97297E+1

6.43627E+1 3.00095E+1

6.48084E+l 3.02912E+1

6.53667E+1 3.05753E+1

6.60929E+1 3.08626E+l

6.65885E+1 3.11520E+1

6.72984E+l 3.14445E+1

6.79152E+1 3.17397E+1

6.83626E+1 3.20368E+1

6.86615E+1 3.23353E+1

6.9l210E+l 3.26357E+l

6.965l4E+l 3.29392E+1

7.04059E+l 3.32452E+l

7.07238E+1 3.35526E+l

7.12284E+1 3.38621E+1

7.18522E+l 3.41743E+1

7.22312E+l 3.44882E+l

7.28215E+~ 3.4B047E+1

7.33559E+l 3.51234E+1

7.38549E+l 3.54444E+l

7.43758E+l 3.57676E+1

7.48809E+l 3.60929E+1

7.52290E+l 3.6419BE+1

7.5616BE+1 3.67484E+1

7.60260E+1 3.707B7E+l

7.64002E+1 3.74107E+l

7.69286E+1 3.77449E+l

7.74077E+1 3.80812E+1

7.76189E+l 3.B41B5E+l

7.63250E+1 3.B7588E+1

7.B72B4E+l 3.91DOBE+l

7.91259E+l 3.94446E+1

7.955B4E+1 3.97902E+l

B.02526E+1 4.01369E+1

6.04204E+1 4.04883E+l

8.11224E+1 4.0B407E+1

6.12622E+1 4.11936E+1

8.18078E+1 4.15492E+l

8.19711E+1 4.19053E+1

8.25303E+1 4.22638E+1

8.29706E+1 4.26242E+l

6.34667E+1 4.29668E+l

6.36486E+l 4.33502E+l

8.41336E+1 4.37157E+1

8,47327E+1 4.40838E+1

8.50474E+1 4.44532E+1

8.53722E+1 4,46241E+1

6.56442E+1 4.51961 E+1

6.60403E+l 4.55698E+1

8.63346E+l 4.59448E+l

8.68336E+l 4.63220E+1

8.711521::+1 4.67004E+1

B.7512BE+1 4.70806E+1

B.79230E+1 4.74625E+1

6.B1908E+1 4.78455E+1

8.851B3E+1 4.B2300E+1

8.68674E+1 4.86160E+1

B.90121E+1 4.90027E+1

8.92532E+1 4.93903E+l

8.96581E+1 4.97798E+1

8.976B1E+1 5.01697E+l

9.00368E+1 5.05607E+1

9.02347E+1 5.09527E+1

9.03450E+1 5.13451 E+1

9.06704E+1 5.17369E+1

9.09603E+1 5.21340E+l

9.11D05E+1 5.25296E+1

9.13282E+1 5.29263E+1

9.14617E+1 5.33235E+1

9.18181E+1 5.37223E+1

9.1965BE+1 5.41216E+1

9.19425E+l 5.45211E+1

9..20328E+1 5.49206E+l

eW4

'11 LOa 24 6

2?-. t9). 4Ayt:e_
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 25 of 32

305

306

307

308

309

310

311

312

313

314

315

316

317

318

319

320

321

322

323

324

325

326

327

328

r'\329

~30

331

332

333

334

335

336

337

338

339

340

341

342

343

344

345

346

347

348

349

350

351

£1\352

~353

354

355

356

357

358

359

360

361

362

363

364

365

366

367

368

369

370

371

372

373

374

375

376

377

378

379

380

Molmasse

3.82906E+3

3.86926E+3

3.90988E+3

3.95094E+3

3.99242E+3

4.03434E+3

4.07670E+3

4.11950E+3

4. 16275E+3

4.20646E+3

4.25062E+3

4.29525E+3

4.34035E+3

4.38592E+3

4.43197E+3

4.47851E+3

4.52553E+3

4.57304E+3

4.62106E+3

4.66958E+3

4.71860E+3

4.76815E+3

4.81821E+3

4.86880E+3

4.91992E+3

4.97158E+3

5.02377E+3

5.07652E+3

5.12982E+3

5.18368E+3

S.23811E+3

S.29311E+3

S.34868E+3

5.40484E+3

5.46159E+3

5.S1893E+3

5.57688E+3

S.63543E+3

5.69460E+3

5.75439E+3

5.81481E+3

5.87586E+3

5.93755E+3

5.99990E+3

6.06289E+3

6.12655E+3

6.19087E+3

6.25587E+3

6.321S6E+3

6.38793E+3

6.45500E+3

6.52277E+3

6.59126E+3

6.66047E+3

6.73040E+3

6.80106E+3

6.87247E+3

6.94463E+3

7.01754E+3

7.09122E+3

7.16568E+3

7.24091E+3

7.31694E+3

7.39376E+3

7.47139E+3

7.54984E+3

7.62911E+3

7.70921E+3

7.79015E+3

7.87194E+3

7.95460E+3

8.03811E+3

8.12251E+3

8.20779E+3

8.29397E+3

8.3810SE+3

RI ERe 75H Integral rk]

9.21382E+1 5.53210E+1

9.23793E+l 5.57222E+1

9.23537E+l 5.61233E+l

9.23109E+l 5.65243E+1

9.22678E+1 5.69250E+l

9.25131E+1 5.73268E+1

9.26141E+1 5.77291E+1

9.25701E+1 5.81311E+1

9.25209E+1 5.85329E+1

9.23595E+l 5.89341E+1

9.25891 E+1 5.93362E+1

9.25441 E+' 5.97381 E+1

9.24765E+1 6.01398E+1

9.21739E+1 6.05401 E+1

9..21009E+1 6.09401 E+1

9.18485E+1 6.13391E+1

9..21799E"1 6.17394E+1

9.21170E"1 6.21395E+1

9.19160E+1 6.25387E"1

9.16266E+1 6.29367E+1

9.15797E+1 6.33344E+1

9.15743E+1 6.37322E+1

9. 17082E+1 6.41305E+1

9.12380E+1 6.45288E+1

9.08346E+1 6.49213E+1

9.07192E"1 6.53153E"1

9.03188E+1 6.57076E+1

9.02015E+1 6.60994E+1

8.98031 E+1 6.64695E+1

8.97788E+1 6.68794E+1

8.97790E+1 6.72694E+1

8.93578E+1 6.76575E+1

8.91211E+1 6.80446E+1

8.87014E+1 6.84299E+1

8.84730E+1 6.88142E+1

8.80288E+1 6.91965E+1

8.77204E+1 6.95776E+1

8.75156E+1 6.99577E+1

8.71645E+1 7.03363E+1

8.67209E+1 7.07130E+1

8.64169E+1 7.10884E+1

8.62098E+1 7.14629E+1

8.58703E+1 7.18359E+1

8.54084E+1 7.22069E+1

8.49470E+1 7.25759E+1

8.44995E+1 7.29430E+1

8.41717E+1 7.33086E+1

8.3B624E+1 7.36729E+1

B.36546E+1 7.40363E+1

8.31957E+1 7.43977E+1

8.27307E"1 7.47571E+1

821543E+1 7.5114OE+1

8.20975E+1 7.54707E+1

8.13648E+1 7.58242E+1

8.07704E+1 7.61751E+1

8.05901 E+1 7.65252E+1

7.98697E+1 7.68722E+1

7.94061E+1 7.72172E+1

7.9075BE+1 7.75607E+1

7.8S111E+1 7.79018E+1

7.79222E+1 7.82404E+1

7.74566E+1 7.85769E+1

7.68855E+1 7.89110E+1

7.64160E+1 7.92430E"1

7.S9599E+1 7.95731 E+1

7.55097E+1 7.99012E+1

7.48511E+1 8.02264E"1

7.41332E+1 8.05486E+1

7.37206E+1 8.08689E+1

7.31147E+1 8.11866E+1

7.26840E+1 8.15025E+1

7.21917E+1 8.18162E+1

7.15245E+1 8.21270E+1

7.07319E+1 8.24344E+1

7.02060E+1 8.27395E+1

6.95169E"1 8.30416E+1

EI/4

'11 La 02.4 6

2::;,0"). A4 ~
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 26 of 32

EW/f

Molmasse RI ERe 751 e Integral [%J

381 8.46905E+3 6.88330E+1 8.33408E+1

382 8.55797E+3 6.83247E+1 8.36377E+1 ·11L 00246

383 8.64782E+3 6.78163E+1 8.39325E+1

384 8.73862E+3 6.72573E+1 8.42248E+1 2-+.. f) t-, ~ -:;ze

385 8.83037E+3 6.64994E+1 8.45139E+1

386 8.92309E+3 6.58740E+1 8.48002E+1

387 9.01677E+3 6.53826E+1 8.50844E+1

388 9.11145E+3 6.45907E+1 8.53652E+1

389 9.20711E+3 6.38928E+1 8.56429E+1

390 9.30378E+3 6.31998E+1 8.59176E+1

391 9.40147E+3 6.25309E+1 8.61895E+1

392 9.50018E+3 6. 19448E+1 8.64588E+1

393 9.59992E+3 6.12375E+1 8.67250E+1

394 9.70072E+3 6.04527E+1 8.69878E+1

395 9.80257E+3 5.99904E+1 8.72487E+1

396 9.90549E+3 5.90496E+1 8.75054E+1

397 1.00095E+4 5.83597E+1 8.77592E+1

398 1.01146E+4 5.76788E+1 8.80100E+1

399 1.02208E+4 5.73564E+1 8.82594E+1

400 1.03281E+4 5.61307E+1 8.85035E+1

401 1.04365E+4 5.57994E+1 8.87461E+1

402 1.05461E+4 5.50039E+1 8.89854E+1

403 1.06568E+4 5.42639E+1 8.92214E+1

404 1.07687E+4 5.36778E+1 8.94548E+1

{l05 1.08818E+4 5.29566E+1 8.96852E+1

06 1.09961E"'4 5.22336E"'1 8.99124E"'1

407 1.11115E+4 5.14852E+1 9.01363E"'1

408 1.122B2E+4 5.08929E+1 9.03577E+1

409 1.13461E+4 5.01015E+1 9.05757E+1

410 1.14652E+4 4.93136E+1 9.07902E+1

411 1.15856E+4 4.87786E+1 9.10025E+1

412 1.17072E+4 4.79812E+1 9.12112E+1

413 1.18301E+4 4.74434E+1 9.14177E+1

414 1.19543E+4 4.68506E+1 9.16215E+1

415 1.20799E+4 4.60347E+1 9.18219E+1

416 1.22067E+4 4.51521E+1 9.20184E+1

417 1.23349E+4 4.44895E+1 9.22120E+1

418 1.24644E+4 4.38320E+1 9.24028E+1

419 1.25952E+4 4.29167E+1 9.25896E+1

420 1.27275E+4 4.23678E"'1 9.27740E"'1

421 1.28611E+4 4.15022E+1 9.29547E+1

422 1.29961E+4 4.08124E+1 9.31324E+1

423 1.31326E+4 3.99622E+1 9.33064E+1

424 1.32705E+4 3.93283E+1 9.34777E+1

425 1.34098E+4 3.85591E+1 9.36456E+1

426 1.35506E+4 3.81089E+1 9.38116E+1

427 1.36929E+4 3.75626E+1 9.39752E+1

Q28 1.38366E+4 3.68428E+1 9.41357E+1

29 1.39819E+4 3.62255E+1 9.42935E+1

430 1.41287E+4 3.54153E+1 9.44478E+1

431 1.42771E+4 3.46280E+1 9.45987E+1

432 1.44270E+4 3.40857E+1 9.47472E+1

433 1.457B5E+4 3.34460E+1 9.48930E+1

434 1.47315E+4 3.28053E+1 9.50360E+1

435 1.48862E+4 3.20429E+1 9.S1757E+1

436 1.S042SE+4 3.15295E+1 9.53131E+1

437 1.52004E+4 3.07959E+1 9.54474E+1

438 1.53600E+4 3.03561E+1 9.55798E+1

439 1.SS213E+4 2.95912E+1 9.S7088E+1

440 1.56843E+4 2.89768E+1 9.58352E+1

441 1.58489E+4 2.63150E+1 9.59588E+1

442 1.60153E+4 2.77005E+1 9.60796E+1

443 1.61835E+4 2.72001E+1 9.61983E+1

444 1.63534E+4 2.670 17E+ 1 9.63148E+1

445 1.65251E+4 2.60809E+1 9.64287E+1

446 1.66986E+4 2.53052E+1 9.65392E+1

447 1.68739E+4 2.48310E+1 9.66476E+1

448 1.70511E+4 2.4397SE+1 9.67541E+1

449 1.72301E+4 2.34223E+1 9.68564E+1

450 1.74110E+4 2.30484E+1 9.69571 E+1

451 1.75939E+4 2.26754E+1 9.70562E+1

452 1.77786E ...4 2.19040E ...1 9.71519E+1

453 1.79652E+4 2.13234E+1 9.72451E+1

454 1.81539E+4 2.10738E+1 9.73373E+1

455 1.8344SE+4 2.05266E+1 9.74270E+1

456 1.85371E+4 1.98542E+1 9.75139E+1
Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

a·BASF

The Chemical Company

Page 27 of 32

457

458

459

460

461

462

463

46<l

465

466

467

468

469

470

471

472

473

474

475

476

477

478

479

480

c,)I81

'Ull82

483

484

485

486

487

488

489

490

491

492

493

494

495

496

497

498

499

500

501

502

503

(fo~

506

507

508

509

510

511

512

513

514

515

516

517

518

519

520

521

522

523

524

525

526

527

528

529

530

531

532

Molmsss8

1.87317E+4

1.89284E+4

1.91271E+4

1.93280E+4

1.95309E+4

1.97359E+4

1.99432E+4

2.01526E+4

2.03642E+4

2.05780E+4

2.07940E+4

2.10123E+4

2.12330E+4

2.14559E+4

2.16812E+4

2.19088E+4

2.21388E+4

2.23713E+4

2.26062E+4

2.28435E+4

2.30834E+4

2.33257E+4

2.35707E+4

2.38181E+4

2.40682E+4

2.43209E+4

2.45763E+4

2.48343E+4

2.50951E+4

2.53585E+4

2.56248E+4

2.58938E+4

2.61657E+4

2.64404E +4

2.67180E+4

2.69986E+4

2.72820E+4

2.75685E+4

2.78579E+4

2.81504E+4

2.84460E+4

2.87447E+4

2.90465E+4

2.93514E+4

2.96596E+4

2.99710E+4

3.02857E+4

3.06037E+4

3.09250E+4

3.12497E+4

3.15778E+4

3.19094E+4

3.224441:+4

3.25829E+4

3.29251E+4

3.32707E+4

3.36201E+4

3.39731E+4

3.43298E+4

3.46902E+4

3.50544E+4

3.54225E+4

3.57944E+4

3.61702E+4

3.65500E+4

3.69338E"'4

3.73215E+4

3.77134E+4

3.81094E+4

3.85095E+4

3.89138E+4

3.93224E+4

3.97353E+4

4.01525E"'4

4.05740E+4

4.10001E+4

RI ERe 7515 Integral [%]

1.93210E+1 9.75984E+1

1.87572E+1 9.76805E+1

1.82988E+1 9.77606E+1

1.78717E+1 9.78389E+1

1.70709E+1 9.79137E+1

1.70593E+1 9.79884E+1

1.64902E+1 9.80607E+1

1_59932E+1 9.81308E+1

1.53400E+1 9.81981E+1

1.49373E+1 9.82636E+1

1.46947E+1 9.83281 E+1

1.43453E+1 9.83910E+1

1.40012E+ 1 9.84525E+1

1.36936E+1 9.85127E+1

1.29716E+1 9.85697E+1

1.27212E+1 9.86256E+1

1.23683E+1 9.86800E+1

1.19038E+1 9.87324E+1

1.15363E+1 9.87832E+1

1.10983E+1 9.88321E+1

1.05617E+1 9.88786E+1

1.02316E+1 9.89238E+1

1.00620E+1 9.89682E+1

9.75611 E+O 9.90113E+1

9.34239E+0 9.90525E+1

9.08357E+0 9.90927E+1

8.63073E+0 9.91309E+1

8.62149E+0 9.91691E+1

8.01776E+0 9.92046E+1

7.76954E+0 9.92391E+1

7.S7887E+0 9.92727E+1

7.11016E+0 9.93043E+1

6.76072E+O 9.93344E+1

6.73795E+0 9.93644E+1

6.39992E+O 9.9.3929E+1

6.07528E+O 9.94200E+1

5.95889E+0 9.94467E+1

5.63739E+0 9.94719E+1

S.39434E+0 9.94960E+1

5_16840E+0 9_95192E+1

5.00823E+0 9.95417E+1

4.85094E ...0 9.95635E+1

4.66405E+0 9.95845E+1

4.53065E+0 9.96050E+1

4.31140E+0 9.96244E+1

4.08654E+O 9.96429E+1

3.86833E+0 9.9660SE+1

3.56277E+0 9.96767E+1

3.37791 E+O 9.96922E+1

3.44210E+0 9.97079E+ 1

3.40291E+O 9.97234E+1

2.99522E+O 9.97372E+1

2.737321:+0 9.974981:+1

2.95715E+O 9.97634E+1

2.85140E+O 9.97766E+1

2.74667E+0 9.97893E+1

2.71603E+O 9.98018E+1

2.47187E+0 9.98133E+1

2.26997E+O 9.98239E+1

2'34835E+O 9.98349E+1

2.31945E+0 9.98457E+1

2.10855E+0 9.98557E+1

1.89825E+0 9.98647E+1

1.n44BE+0 9.98732E+1

1.89257E+0 9.98822E+1

1_87SnE+0 9.98911 E+1

1.707351:+0 9.989931:+1

1.60029E+0 9.99070E+1

1.52397E+0 9.99144E+1

1.73877E+O 9.99227E+1

1.~572E+0 9.99298E+1

1.31033E+O 9.99363E+1

1.27405E+O 9.99426E+1

1.12659E+0 9.99482E+1

9.47351 E-1 9.99531 E+1

1.05441E+O 9.99585E+1

'I 1l 00246

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Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

a·BASF

The Chemical Company

Page 28 of 32

Molmasse

533 4.14305E+4

534 4.18655E+4

535 4.23051E+4

536 4.27493E +4

537 4.31981E+4

538 4.36517E+4

539 4.41100E+4

540 4.45731 E+4

541 4.50411E+4

542 4.55140E+4

543 4.59919E+4

544 4.64748E+4

545 4.69628E+4

546 4.74558E+4

547 4.79541E+4

548 4.84576E+4

549 4.89664E+4

550 4.94805E+4

o

o

RI ERe 7515 Integral [%]

1.16120E+0 9.99643E+1

9.51855E-1 9.99692E+1

9.23260E-1 9.99740E+1

8.55602E-1 9.99785E+1

7.013751:-1 9.99823E+1

6.04840E-1 9.99857E+l

6.73801E-1 9.99894E+1

5.l05S0E-1 9.99921E+1

4.7370SE-1 9.9995SE"'1

4.59540E-l 9.99983E+l

3.91197E-l 1.00000E+2

2.91929E-1 1.00000E+2

2.27932E-1 1.00000E+2

2.29551E-l 1.000ooE+2

2.31165E-1 1.000OOE+2

2.32773E-1 1.00000E"2

7.3793SE-2 1.00000E+2

1.94283E-1 1.00000E+2

Eiv4

'11 L 00246

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Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11 L00371 (confidential)

Page 29 of 32

Content of residual monomer of n-butyl acrylate by GC

Test item

o 5 10 15 3J

RIE*rialIiITB

Test item with reference material

11

I

o 5 10 15
Competence Center Analytics

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

a·BASF

The Chemical Company

Page 30 of 32

Content of residual monomer of iso-butyl methacrylate and perfluorohexylethyl methacrylate by

GC

Test item

., 1Q

.,

Test item with reference material

i

I....

.5

o 5 10 15

RNulla Sum"""" for EFKA-3ISOON Vlflflttwt OOA d fBmIIe B. 'nlfddlon 11

25

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Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 31 of 32

Acrylic acid or methacrylic acid by HPLC

Test item

o 2 4

Reference materials

o 2 4
Competence Center Analytics a·BASF

The Chemical Company

Final Report

Characterization of "EFKA-3600N without DOA"

Study No. 11L00371 (confidential)

Page 32 of 32