# Minnesota Pollution Control Agency

520 Lafayette Road North 

### I St. Paul, Minnesota 55155-4194 

### I 651-296-6300

800-657-3864 

### I 651-282-5332 TTY 

### I wwwpc.a.,late.mn.Ll, 

### I**Equ~1** Opportun,ry Employer

May 23,2011

Ms. Susan Hedman Regional Administrator U.S. Environmental Protection Agency Region 5 77 West Jackson Boulevard Chicago, IL 60604

RE: State of Minnesota Designation Recommendation for Primary National Ambient Air Quality Standard for Sulfur Dioxide

Dear Ms. Hedman:

Pursuant to Section 107(d) of the Clean Air Act, and following the revision of the sulfur dioxide (S02) National Ambient Air Quality Standard (NAAQS) on June 3, 2010, (75 FR 35520), the Minnesota Pollution Control Agency (MPCA) hereby submits the following designation recommendation for the new onehour NAAQS for S02.

This recommendation does not include areas in the state that are under tribal jurisdiction. Those tribal governments which have met eligibility determination and have submitted a Tribal Implementation Plan to the U.S. Environmental Protection Agency (EPA) may submit designation requests to EPA under the Tribal Authority Rule of 1998 (63 FR 7254).

This designation recommendation is based on a combination of air monitoring data collected from 2008 through 2010 and emission inventory information.

Monitoring Data Minnesota currently has seven monitoring sites, in four locations for S02' Locations are shown in the enclosed map. Quality assured S02 monitoring data for Minnesota has been submitted to the Air Quality System through 2010. The design values for all of these monitors clearly demonstrate attainment with the new one-hour standard.

Monitored S02 Design Values
Monitor Name Monitor County 2008-2010 S02 Design Value
FHR 420 Dakota 20 FHR 423 Dakota 11 FHR 442 Dakota 3 FHR 443 Dakota 2 Minneapolis (954) Hennepin 35 Duluth* (2010 data only) St. Louis 9

Saint Paul !-'ark Washington 

## 16S. Hedman May 

### 23,2011 Page Two

The MPCA believes that this data could be used to support an attainment designation, particularly in Dakota County. Although four of the monitors are sited very close to Flint Hills Resources, a major
source with average S02 emissions over 

### 1000 tons per year (tpy), they showed concentrations that are about one quarter of the standard.

However, on March 

### 24, 2011, EPA issued a memorandum on Area Designations for the 2010 Revised Primary Sulfur Dioxide National Ambient Air Quality Standards. This guidance indicates that an area that has no monitored violations and lacks an appropriate modeling analysis or other supporting information will be designated as unclassifiable. Therefore, the MPCA is not making any designation recommendations based solely on the monitoring data.

Emissions Inventory Information The above-mentioned designation guidance, along with discussion in the preamble of the Final Rule concerning the Primary National Ambient Air Quality Standard for Sulfur Dioxide (75 FR 

### 35520), indicate
a focus on sources with allowable emissions greater than 

### 100 tpy as those that could cause or contribute to a violation of the new NAAQS.

Based on this guidance, and taking into account the fact that there are no monitored violations in Minnesota, the MPCA recommends an attainment designation for all counties in Minnesota that contain only sources with a potential to emit less than 

### 100 tpy.

These counties include:

Recommendation: Attainment; Counties with No Sources of S02 PTE > 

### 100 tpy Aitkin Anoka Becker Beltrami Big Stone Cass Chippewa Chisago Clearwater Cottonwood Dodge Douglas Fillmore Freeborn Grant Houston Isanti Jackson Kanabec Kittson Lake of the Woods Le Sueur Lincoln Mahnomen Marshall Meeker Mille Lacs Morrison Murray Nicollet Norman Pennington Pine Pipestone Pope Red Lake Redwood Rice Rock Roseau Sibley Steele Stevens Todd Traverse Wabasha Wadena Waseca Watonwan Wilkin Wright Yellow Medicine

Promulgating an attainment designation for all counties without a large S02 source (PTE> 

### 100 tpy) and
an unclassifiable designation for counties with such a source and no monitored attainment will allow the MPCA to focus resources in developing a maintenance state implementation plan (air quality control) on

### S. Hedman May 23,2011 Page Three

the counties where the evidence shows there is most likely to be sources that could cause or contribute to an exceedance of the standard. This represents the MPCA's preferred set of designations for Minnesota.

As Commissioner of the Minnesota Pollution Control Agency, I am duly authorized by the Governor of the State of Minnesota to submit this letter on his behalf. If you have questions or comments on this submission, please contact Catherine l\Jeuschler of my staff at 651-757-2607. 

# ?a1

Paul W. Aasen Commissioner

PA/CN:jab

Enclosure1



## Technical Support Monitored Values

More information on SO2 

### monitoring in Minnesota can be foundation in the MPCA’s Annual Air Monitoring Network Plan. 1 

### Figure 1: SO2 

### Monitoring Sites in Minnesota

Figure 2: Monitored SO2 

### Design Values

1

### Gavin, K., McMahon, C. and Palmer, K. (2011) Annual air monitoring network plan for Minnesota

. http://www.pca.state.mn.us/index.php/view-document.html?gid=13400 20 11 3 2 35
9 16

0 10 20 30 40 50 60 70 80Concentration (ppb) 

## 1-hr SO2 

## NAAQS Design Values, 2010 3-year average of the 99th percentile 1-hour SO2 concentration (ppb)



### 2008-2010
Standard2



### Emissions Inventory
In determining which counties should be modeled during the implementation phase, the MPCA looked at average actual SO2 

### emissions from 2002 – 2009, and selectedall facilities with average actual emissions over 10 tpy. Of these sources, all those with a PTE greater than 100 tpy are listed in the table below, sorted by county. The MPCA recommends that all counties without a source greater with a PTE greater than 100 tpy should be given an attainment designation. Any county with a source with a PTE greater than 100 tpy should be given an unclassifiable designation, and the MPCA will conduct modeling of those counties for the maintenance SIP due in June 2013.

Table 1: SO2 

### Emission Sources

Facility ID County Facility Name Avg 2002 - 2009 Actual Emissions (tpy) PTE (tpy) 00900011 Benton Verso Paper Corp - Sartell Mill 849 2,624 01300007 Blue Earth CHS Oilseed Processing - Mankato 188 3,090 01300006 Blue Earth ADM - Mankato 143 1,847 01300015 Blue Earth Xcel Energy - Key City/Wilmarth 36 519 01500007 Brown Acme-Ochs Plant 25 240 01700002 Carlton Sappi Cloquet LLC 261 2,975 01900001 Carver Bongards' Creameries 44 1,409 02700022 Clay Busch Agricultural Resources - Moorhead 383 2,805 02700001 Clay American Crystal Sugar - Moorhead 491 2,293 03100001 Cook Minnesota Power - Tac Harbor Energy Ctr 4,769 5,873 03500002 Crow Wing Wausau Paper Mills LLC 462 4,198 03700003 Dakota Xcel Energy - Black Dog 3,376 17,480 03700015 Dakota Xcel Energy - Inver Hills 4 12,300 03700011 Dakota Flint Hills Resour ces Pine Bend LLC 1,386 3,169 03700016 Dakota Gopher Resource LLC 1,536 2,414 03700043 Dakota Seneca Wastewater Treatment Plant 98 589 03700070 Dakota Sanimax USA Inc 103 240 04300041 Faribault Corn Plus 53 125 04900007 Goodhue USG Interiors Inc - Red Wing 1,109 1,709 04900001 Goodhue ADM - Red Wing 100 807 04900005 Goodhue Xcel Energy - Red Wing Generating Plant 79 110 05300011 Hennepin NRG Energy Center Minneapolis LLC 347 646 05301050 Hennepin University of MN - Twin Cities 10 277 05300127 Hennepin Owens Corning Roofing & Asphalt LLC Mpls 72 183 05700006 Hubbard Lamb Weston/RDO Frozen 41 244 06100004 Itasca Minnesota Power Inc - Boswell Energy Ctr 19,724 52,240 06100001 Itasca Blandin Paper/Rapids Energy Center 89 2,606 06100067 Itasca Essar Steel Minnesota (MSI) N/A 417 06700005 Kandiyohi Willmar Municipal Utilities 615 1,9363



### Facility ID County Facility Name Avg 2002 - 2009 Actual Emissions (tpy) PTE (tpy) 07100002 Koochiching Boise White Paper LLC - Intl Falls 74 446 07300016 Lac Qui Parle Associated Milk Producers Inc - Dawson 44 554 07500003 Lake Northshore Mining - Silver Bay 2,499 9,095 08300038 Lyon ADM Corn Processing - Marshall 515 1,024 09100007 Martin Interstate Power & Light - Fox Lake 186 2,427 08500049 McLeod 3M - Hutchinson Tape Manufacturing Plant 190 1,124 09900001 Mower Austin Utilities - NE Power Station 1,562 4,840 09900002 Mower Hormel Foods Corp/QPP - Austin 142 236 10500001 Nobles Swift Pork Co - Worthington 29 240 10900011 Olmsted Rochester Public Utilities - Silver Lake 2,241 6,221 10900084 Olmsted Mayo Medical Center Rochester 77 3,868 10900010 Olmsted Associated Milk Producers Inc - Rochester 61 241 10900005 Olmsted Olmsted Waste-to-Energy Facility 20 101 11100002 Otter Tail Otter Tail Power Co - Hoot Lake Plant 2,987 19,360 11900002 Polk American Crystal Sugar - E Grand Forks 747 3,589 11900001 Polk American Crystal Sugar - Crookston 486 1,809 12300410 Ramsey Waldorf Corp - A Rock-Tenn Co 149 8,914 12300694 Ramsey 3M - Administrative Offices - Maplewood 453 4,336 12300063 Ramsey District Energy St Paul Inc-Hans O'Nyman 345 2,863 12300055 Ramsey Gerdau Ameristeel US Inc - St Paul Mill 35 707 12900014 Renville Southern Minnesota Beet Sugar Coop 1,039 3,716 13900005 Scott Anchor Glass Cont ainer Corp - Shakopee 380 540 13900013 Scott CertainTeed Corp 32 152 13900003 Scott Rahr Malting Co - Shakopee 101 127 14100004 Sherburne Xcel Energy - Sherburne Generating Plant 24,860 79,545 14100003 Sherburne Great River Energy - Energy Recovery Project 40 148 13700015 St Louis Minnesota Power Inc - Hibbard 297 7,464 13700005 St Louis US Steel Corp - Minntac 1,771 5,790 13700027 St Louis Hibbing Public Utilities Commission 520 4,733 13700113 St Louis United Taconite LLC - Fairlane Plant 2,894 3,914 13700028 St Louis Virginia Dept of Public Utilities 471 2,997 13700013 St Louis Minnesota Power - Laskin Energy Center 1,539 2,865 13700061 St Louis Hibbing Taconite Co 440 1,628 13700031 St Louis Georgia-Pacific - Duluth Hardboard 230 1,546 13700063 St Louis US Steel Corp - Keetac 642 1,480 13700022 St Louis Duluth Steam Cooperative Association 345 1,000 13700318 St Louis Mesabi Nugget, Phase I N/A 421 13700032 St Louis Northshore Mining Co - Babbitt 34 402 13700062 St Louis ArcelorMittal Minorca Mine Inc 128 3334



### Facility ID County Facility Name Avg 2002 - 2009 Actual Emissions (tpy) PTE (tpy) 14500003 Stearns Melrose Dairy Proteins LLC 41 317 14500026 Stearns St Cloud State University 57 248 14500032 Stearns Associated Milk Producers - Paynesville 31 239 14500008 Stearns Order of St Benedict/St John’s Abbey 91 225 15100038 Swift Fibrominn Biomass Power Plant 56 590 16300005 Washington Xcel Energy - Allen S King Generating 15,192 3,027 16300003 Washington Saint Paul Park Refining Co LLC (Marathon) 495 2,770 16900013 Winona Malteurop North America Inc - Winona 27 2405



## Map of Recommendation
Figure 3: Minnesota County Map; Pr oposed Unclassifiable Areas Shaded