## Competence Center Analytics



# Final Report { 

# I 

# /

Characterization of "EFKA·3600Nwithout DOA" Study No. 11L00371 (confidential)

Test item

Chemical identity

Chemical structure

Batch identification

Date of production (test item)

Origin oftest item

PSN

CAS no.

Sponsor

Date of receipt oforder

Date of receipt oftest item

Testing facility

Study director

Storage condotest item

Test period

Storage of records

Storage ofsample oftest item Page 1 of32

"EFKA-3600N without DOA"

Polyacrylat -Copolymer

GK3365-099 without DOA

Jun 07. 2011

Ms. Merz. GKD/A, B001

Efka-P-236

1334163-54-0

Dr. Engelbrecht, GKD/A

- B001

Aug 29, 2011

Aug 29, 2011

Competence Center Analytics, BASF SE, D-67056 Ludwigshafen

Mr. Beringer, 

# GKC/C

-E210

Ambient temperature

Sep 09

- Oct 19, 2011

GLP archives. Competence Center Analytics

Archives, Competence Center Analytics

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 2of32

Summary of results

The IRspectrum shows mainly the expected bands forthe given chemical identity, butthere are additional bands which originate from anhydride.

The molecular weight distribution was investigated bygel permeation chromatography. The THF soluble mass ofthe polymer amounts to

Mn

# =2320 g/mol Mw

# =5470 g/mol 0= Mw/Mn =

# 2.4 fraction < 

# 1000 and> 

# 150g/mol: 8.7 area-% fraction < 

# 500 and> 

# 150g/mol: 

# 2.2 area-%

Quantitative determinations yielded:

< 

# 100 mg/kg byGC

1 Appearance and Homogeneity

Method Visual inspection

Result At ambient temperature, the test item was aclear, colourless, viscous liquid. Itwas seemingly homogeneous.

Date oftest Sep 

# 13,2011

Head of laboratory Dr. Euler, 

# GKC/C

- E

# 210

2 Identity

Method IRSpectroscopy Apparatus Sample preparation Nicolet 

# 6700

Test item was measured asfilm on a KBr-disc.

Result Resolution: 

# 4.000 

# em" Number ofscans: 

# 32 Temperature: ambient

The IRspectrum (page 

# 11)shows mainly the expected bands forthe given chemical identity, butthere are additional bands which originate from anhydride. Test parameters

Date oftest
Head of laboratory Oct

# 04,2011

Dr. Meyer, GKC/S

- E

# 210

## Competence Center Analytics 

# a·BASF

The 

### Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 3of32



# 3 Molecular mass distribution, fractions <500 and < 1000 Dalton

Method Gel Permeation Chromatography

Apparatus Modular GPC system with acombination ofcolumns and refractive indexdetector

Reagents THF (BASF) Mixture ofpolystyrene standards with known molecular mass distribution (Polymer Laboratories) Heptylbenzene (Fluka)

Sample preparation About 95 -101 mg ofthe test item were weighed into a 10ml volumetric flask dissolved and filled uptothe markwith THF.

Test parameters Columns: combination of 3columns; manufactured by Polymer Laboratories. 1) and 2) Mini-Mix C,250mm x4.6 mm i.d., dp =5 IJm 3) Mini-Mix E,250mm x4.6 mm Ld.,dp

# = 3 IJm Mobile phase: THF Flow: 0.3 ml/min Injection volume: 20 1-11 

## Temperature: 35°C Detection: refractive index

Results Mn 

# =2320 

# g/mol Mw

# =5470 

# g/mol D

# = Mw/Mn 

# =2.4 (mean value out of unrounded molecular weights) fraction < 1000 and> 150

# g/mol: 8.7 area-% fraction < 500 and> 150

# g/mol: 2.2 area-%

1. det 2. det mean Mn (g/mol) 2315 2321 2320 Mw (g/mol) 5448 5485 5470 D 2.35 2.36 2.4 Fraction <1000 >150 g/mol 8.68 8.65 8.7 (area-%) Fraction <500 >150 g/mol 2.23 2.25 2.2 (area-%)

Calibration curve see page 12

Because the results ofthe two determinations are similar only the graphs ofthe first determination are depicted.

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 4

# of32

GPC

- diagram oftest item correlated with molecular weight distribution see page 12 GPC

- diagrams ofthe test item and blank see page 13 Slice file report see pages 14

-28

Note: All GPC-values are referring to polystyrene resp. heptylbenzene used

as calibration standards.

Date oftest Sep 14, 2011

Head of laboratory Dr. Euler, GKC/C

- E210

4 Content of residual monomer of n-butyl acrylate

Method Headspace gas chromatography, standard addition method

Apparatus Capillary gas chromatograph equipped with autosampler, split injection system and flame ionisation detector (FlO) adapted toachromatography data system

Reagents -Dimethyl acetamide minimum 99.5 

# % (DMAA, Promochem) -n-butyl acrylate (reference material, BASF) -Drinking water

Sample preparation Forthe standard addition solution approx. 28 mg (solution 1) and approx. 26 mg (solution 2) n-butyl acrylate exactly weighed to 0.1 mg were dissolved in5or 10ml DMAA.

Method of standard addition: Approx. 231

- 255 mg ofthe test item exactly weighed to 0.1 mgwere dissolved in2 ml OMAA and 0.5 ml drinking water. Approx. 256

- 271 mg ofthe test item exactly weighed to 0.1 mg were mixed with 5 IJIstandard addition solution 1 or2.The mixtures were dissolved in2 ml OMAA and 0.5 ml drinking water.

Headspace conditions: Equilibration temp.: Preliminary heating time: Transfer linetemp.: Pressure bild-up time: Normal pressure: High pressure; Injection time: Dwell time: Cycle time: Analysis time: 90°C 60 min 150°C 1.0 min 115 kPa 180 kPa 6sec 0.2 min 65 min 55 min

## Competence Center Analytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company


## Page 5of32

GC conditions Column: Length: Internal diameter: Film thickness: Carrier gas: Head pressure: Split: Oven temperature:

Injector temperature: Detector temperature: CP-WAX 52 CB 50

# m 0.32 

# mm 1.2 

# IJm helium 70 kPa 10 mllmin 50°C, 5min isothermal SO "C

- 200°C, 5°C/min 200°C, 15min isothermal 150 °C 250°C

Result w (n-butyl acrylate) < 100 mg/ kg

Two determinations with and two determinations without added standard were carried out.

Representative chromatograms see page 29.

Date oftest Oct 18-19,2011

Head of laboratory: Dr. Guntner, GKC/C, E210

5 Content of residual monomer of iso-butyl methacrylate

Method Headspace gas chromatography, standard addition method

Apparatus Capillary gas chromatograph equipped with autosampler, split injection system and flame ionisation detector (FlO) adapted to achromatography data system

Reagents -Dimethyl acetamide minimum 99.5 

# % (DMAA, Promochem) -Iso-butyl methacrylate (reference material, BASF) -Drinking water

Sample preparation Forthe standard addition solution approx. 27 mg (solution 3) and 26 mg (solution 4) of iso-butyl methacrylate exactly weighed to 0.1 mgwere dissolved in 5or 10 ml DMAA.

Method ofstandard addition: Approx. 260

-285 mg ofthe test item exactly weighed to 0.1 mgwere dissolved in2 ml DMAA and 0.5 ml drinking water. Approx. 240

-273 mg ofthe test item exactly weighed to0.1 mgwere mixed with 5

# IJIstandard addition solution 3or4. The mixtures were dissolved in2 ml DMAA and O.S ml drinking water.

## competence Center Analytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company


## Page 6of32

Headspace conditions: Equilibration temp.: Preliminary heating time: Transfer linetemp.: Pressure bild-up time: Normal pressure: High pressure; Injection time: Dwell time: Cycle time: Analysis time:

GC conditions Column: Length: Internal diameter: Film thickness: Carrier gas: Head pressure: Split: Oven temperature:

Injector temperature: Detector temperature: 90°C 60 min 150°C 1.0 min 0.88 bar(turbomatrix) 1.4 bar 6sec 0.2 min 75 min 57 min

DB-1 30 m 0.25 mm 1.0 IJm helium 0.7 bar 5ml/min 50°C, 5 min isothermal 50

# -c
- 260°C, 5°C/min 260°C, 10min isothermal 150 °C 300°C

Result w (iso-butyl methacrylate) < 100 mgt kg

Two determinations with and two determinations without added standard were carried out.

Representative chromatograms see page 30.

Date ottest Oct18,2011

Head of laboratory: Dr. GOntner, GKC/C, E210

6 Content of residual monomer of perfluorohexylethyl methacrylate

Apparatus Method Headspace gas chromatography, standard addition method

Capillary gas chromatograph equipped with autosampler, split injection system and flame ionisation detector (FlO) adapted to achromatography data system

Reagents -Dimethyl acetamide minimum 99.5 

# % (DMAA, Promochem) -Perfluorohexylethyl methacrylate (reference material, BASF) -Drinking water

## Competence Center Analytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company



## Page 7of32

Sample preparation Forthe standard addition solution approx. 24 mg (solution 3 and solution 4) ofperfluorohexylethyl methacrylate exactly weighed to 0.1 mg were dissolved in5or 10ml DMAA. Method of standard addition: Approx. 260

-285 mg ofthe test item exactly weighed to0.1 mgwere dissolved in2 ml DMAA and 0.5 ml drinking water. Approx. 240

-273 mg ofthe test item exactly weighed to0.1 mgwere mixed with 5jJlstandard addition solution 3or4. The mixtures were dissolved in2 ml DMAA and 0.5 ml drinking water.

Headspace conditions: Equilibration temp.: Preliminary heating time: Transfer line temp.: Pressure bild-up time: Normal pressure: High pressure; injection time: Dwell time: Cycle time: Analysis time:

GC conditions Column: Length: Internal diameter: Film thickness: Carrier gas: Head pressure: Split: Oven temperature:

Injector temperature: Detector temperature:

Result 90°C 60 min 150°C 1.0 min 0.88 bar (turbomatrix) 1.4 bar 6sec 0.2 min 75 min 57 min

D8-1 30 m 0.25 mm 1.0 IJm helium 0.7 bar 

# 5mllmin 50°C, 5min isothermal 50 °C

- 260°C, 

# 5°C/min 260°C, 10min isothermal 150°C 300 °C

w(perfluorohexylethyl methacrylate) < 

## 100 mgl kg

Two determinations with and two determinations without added standard were carried out.

Date oftest Oct 18,2011 Representative chromatograms see page 30.

Head of laboratory: Dr. Guntner, GKC/C, E210

## Competence Center Analytics 

# a·BASF

The Chemical Company



# FinalReport Characterizationof "EFKA-3600Nwithout DOA" StudyNo.11L00371(confidential) Page8of32

7 Residualcontentofacrylicacid

Method RP-HPLG with UV-detection and evaluation bythe external standard method.

Apparatus Automated HPLC System with autosampler, pump, column oven, column switching and UVNIS-detector.

Reagents -Water (demineralized water from MiIliQ-system) -Methanol (Merck) -Phosphoric acid, 85

- 88 %, (Sigma-Aldrich)

Sample preparation Approx. 1 9ofthe test item exactly weighed to0.1 mgwere transferred into a 100 ml erlenmeyer flask, dissolved with 5 ml methanol and precipitationed with 44 ml phosphoric acid, 0.1 %. The resultant volume ofthe solution was 50 

# rnl, The supernantant solution was filtrated (0.2 prn) and injected.

Forcalibration approx. 35

-53 mg ofthe acrylic acid were exactly weighed to 0.01 mg into 50 mlvolumetric flasks, dissolved, filled upto the mark and diluted with water.

Measuring Parameters Column: Zorbax SB aq, 4.6 x 150 mm, 5 IJm(Agilent) Mobile phase: 900 ml phosphoric acid 0.1 % + 100 ml methanol Flow rate: 0.8 ml/min Injection volume: 20 IJI Detection: A

# =205 nm Note: 15min after the injection the columns were back flushed for 12 min by using acolumn switching system. The next injection was started 30 min after the previous injection.

Result w(acrylic acid) < 10

# mg/kg The result was the mean out oftwo determinations.

Representative chromatograms see page 31.

Date oftest Sep 15, 2011

Head of laboratory Mr. Krempel, GKC/C

- E210



# 8 Residualcontentofmethacrylicacid

Method RP-HPLC with UV-detection and evaluation bythe external standard method.

## Competence Center Analytics 

# a·BASF

The Chemical Company



# Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page9of32

Apparatus

Reagents

Sample preparation

Measuring Parameters

Result

Date oftest

Head of laboratory

Study director (Mr. Beringer) Automated HPLC System with autosampler, pump, column oven, column switching and UVNIS-detector.

-Water (demineralized water from MilliQ-system) -Methanol (Merck) -Phosphoric acid, 85

- 88

# %, (Sigma-Aldrich)

Approx. 1g ofthe test item exactly weighed to 0.1 mgwere transferred into a 100 ml erlenmeyer flask, dissolved with 5ml methanol and precipitationed with 44 ml phosphoric acid, 0.1 %.The resultant volume ofthe solution was 50 ml. The supernantant solution was filtrated (0.2 urn) and injected. Forcalibration approx. 25

-57 mg ofthe acrylic acid were exactly weighed to 0.01 mg into 50 mlvolumetric flasks, dissolved, filled upto the mark and diluted with water.

Column: Zorbax SB aq, 4.6 x 150 mm, 5urn (Agilent) Mobile phase: 900 ml phosphoric acid 0.1 %+ 100 ml methanol Flow rate: 0.80 mllmin Injection volume: 20 IJI Detection: 

# A

# =205 nm Note: 15min after the injection the columns were back washed for 12 min by using acolumn switching system. The next injection start 30 min after the previous injection.

w(methacrylic acid) < 10mg/kg The result was the mean out oftwo determinations.

Representative chromatograms see page 31

Sep 15, 2011

Mr. Krempel, GKC/C

- E210

Date

# Competence Center Analytics 

# a·BASF

The 

### Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 10of32



# GLP Compliance Statement

This studywas conducted inaccordance with the OECD Principles ofGood Laboratory Practice andtheGLP Principles ofthe German "Chemikaliengesetz" (Chemicals Act).

Study director (Mr. Beringer) 

# Date105] 

### BASFSE

-GKC/sAnalytlkE210Dr.BaderlDr.Meyer tAat 6700Inv.Nr.:08508794 

# •

100 

### TueOct0411:55:.22011 (GMT+02:00)

95

90

86

80

75

70

55



# - 

# r:JI I}

.~382

# \ 

# I 110116 

# § 80

III := 55 

# ~t~,1r E



# .. t:: 50 

### f!! t- 

# II

~ II- 45
2875 

## C~,~ 40..:1 II

35 

# :J 

# r- II ) 1240 

# p/ ( 2961 

## I 

# -l- 

# II 1187

15~ 

# ('1,

# C1

-c.- O-c10
The IR-tpOdrun_onainytho

~

_ '" the~ chemlCII



# ~ '1735ttJ(

1dontIIy, butIhn

..

__ wIichcrigiIal8

### mn enh)ldride. 

# '"'II,A

4000 3500 SOOO 2500 2000 1800 1800 1400 1200 1000 800 800 

### Wavenumbers (cm-1)

Date:TueOct0411:55:422011 (GMT+02:00)

Scans: 32 

### EFKA-3600N

## withoutDCA

-Ch.:GJ<3365.099

## withoutDOA

-PSN:keine,wirdnachgereicht

-Dr.Engelbrecht, Lothar 

# J:

# Pr./I~-* 11l00371.1.001

-FilmaufKBrgernessen b.RT

-DIEP

8508794 

# Wa. 0'1, ,.10.)1,1 Resolution: 4.000 

## ;:u cnO"TI 

# o -::::T- (/) C II) 

# :s 0 "0 

## Q.~!2. 

# 3 CD '<11);:0 "0 

# n. ZaCD CD



# ...... 

# .... OCD-c CD 

## c: 

# 3 • ~ 0 ::::l



# .....N'::I- o

..... 11) 

### CD rl:!: 

# o 00 

### CD 

## o:s ::::l 

### (.,,)0



## ...... 

# ~- CD



# .... 

# - : 

# » nm ::::l 

### 0"," II)



# ~~ ~ Q., ('5' 

## CDw (/) 

## :sen I:!: 0 11)0 

## .::::Z $£ ;:;: ::::T 

### 0 C 

# - C



# ~



# iD

"tI 

## o 

# • zr II) (I) 

### CC

# jE CD



# ....

.... 0



# ... w 

# ~-n N

## Competence Center Analytics 

# a·BASF

TheChemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 12 of32

GPC calibration curve

5.0 6.0 7.5 ElutIon~~um.n



## GPC

- diagram ofthe test item correlated with molecular weight distribution

100 100



## 80

60 60 10



# -- i

~ 01


# ~ 0



# ~ 40 40 

# I g

0 

### c:


# ~ 20 20



# ~

~ 0 0


# ~ 

# • 5"104



## Molare Masse [Oa]

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 13

# of32

GPC diagrams

Test item



# AS; og. ,A1



# ~----------------.----------------.------~ 

# se:

11100371



# • Elutions Volumen [mil



## Blank

0.0300

0.0275

0.0250



# ::c < 0.0225



## o.n



# .... o.n



# ..... 0.0200



# ~ W

0.0150 

# 11L00371AS-, 0.1.4-1

~.



# • Elutions Volumen [ml]

## Competence Center Analytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

TheChemicalCompany



## Page 14of32

GPC slice file

1 2 3 4 

### 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 

# O~~

27 28 29 30 31 32 33 34 35 

### 36 37 38 39 40 41 42 43 44 45 46 47 

# 0::

50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 

### 66 67 68 69 70 71 72 73 74 75 76 Molmasse RI ERe 75H Integral [%]
1.50000E+2 8.26172E·1 5.33071E·3 1.51604E"'2 1.16626E+O 1.22104E·2 1.53226E+2 1.08548E+0 1.87222E·2 1.54865E+2 7.59461E·1 2.37491E·2 1.56521E+2 1.07625E+0 3.02188E·2 1.58196E+2 1.10110E+O 3.8B017E·2 1.59888E+2 1.10508E+0 4.34027E·2 1.61598E+2 1.18468E+0 5.03663E·2 1.63326E+2 1.05653E+0 5.67462E·2. 1.65073E+2 1.10717E+0 6.33568E·2 1.66B39E+2 1.12600E+0 7.00532E·2 1.68624E+2 9.98079E·1 7.61669E·2 1.70427E+2 1.22584E+0 B.33179E-2 1.72250E+2 1.24715E+0 9.05661E-2 1.74093E+2 1.29067E+0 9.B0124E-2 1.75955E+2 1.37937E+0 1.05863E-1 1.77837E+2 1.35492E+0 1.13602E-1 1.79739E+2 1.27649E+0 1.20984E·1 1.81662E+2 1.25124E+O 1.2B250E-1 1.B3605E+2 1.4675BE+O 1.36503E-1 1.85569E+2 1.557B2E+0 1.45166E·1 1.87553E+2 1.52729E+0 1.53690E·1 1.89560E+2 1.53535E+0 1.62251E-1 1.91587E+2 1.58920E+0 1.71057E·1 1.93636E+2 1.B11B1E+O 1.B0877E-1 1.9570BE+2 1.9000BE+0 1.91099E-1 1.97801E+2 1.86240E+0 2.01149E-1 1.99917E+2 1.99205E+O 2.11790E-1 2.02055E+2 2.12761E"·O 2.23049E-1 2.04216E+2 2.10728E+0 2.34215E-1 2.06401E+2 2.16288E+0 2.45634E-1 2.0B608E+2 2.26227E+O 2.57505E·1 2.10840E+2 2.18552E+O 2.69028E·1 2.13095E+2 2.33064E+O 2.B1211E-1 2.15374£::+2 2.39029E+O 2.93666£::-1 2.17678E+2 2.36603E+0 3.06010E-1 2.20006E+2 2.35039E+0 3.18283E-1 2.22359E+2 2.47355E+O 3.31117E-1 2.24736E+2 2.5649SE+0 3.44368E·1 2.27142E+2 2.54143E+0 3.57511E-1 2.29571E+2 2.57811E+0 3.70821E-1 2.32027E+2 2.57972E+0 3.84139E-1 2.34509E+2 2.73363E+0 3.98158E-1 2.37017E+2 2.77541E+0 4.12367E·1 2.39552E+2 2.80106E+0 4.26692E-1 2.42115E+2 3.01526E"'0 4.41994E-1 2.44704E+2 3.10946E+0 4.57724E-1 2.47322E

...

2 3.17839E+0 4.73769E-1 2.49967E+2 3.26037E+0 4.90187E-1 2.52641E+2 3.43133E+O 5.07383E·1 2.55343E+2 3.42430E+0 5.24548E-1 2.58074E+2 3.60782E+0 5.42548E·1 2.60635E+2 3.74167E+0 5.61156E-1 2.63625E+2 3.82341E+0 5.80140E·1 2.66445E+2 4.09517E+0 6.00361 E-1 2.69295E+2 4.26522E+O 6.21355E·1 2.72175E+2 4.28751E+O 6.42452E-1 2.75086E+2 4.53235E+O 6.M663E·1 2.78029E+2 4.71792E+O 6.87720E-1 2.81002E+2 4.B7723E+0 7.11S02E·1 2.84008E+2 4.91990E+0 7.35478E·1 2.87046E+2 4.94735E+0 7.59580E·1 2.90116E+2 5.13961E+O 7.84557E·1 2.93219E+2 5.14687E+0 8.09568E·' 2.96356E+2 5.09740E+0 8.34353E·1 2.99526E+2 4.95805E+0 8.58503E·1 3.02729E+2 4.907S2E+0 8.82423E-1 3.05968E+2 4.B2563E+0 9.05970E·1 3.09240E+2 4.66196E+0 9.28772E-1 3.12548E"'2 4.53826E+0 9.51011E-' 3.15891E+2 4.32278E+0 9.72267E-1 3.19270E+2 4.22638E+O 9.93085E-1 3.22685E+2 3.96632E+O 1.01272E+O 3.26136E+2 3.74300E+O 1.03133E+O 3.29625E+2 3.53468E+0 1.04900E+0 3.33151E+2 3.31055E+O 1.06565E+0 

# i'iL0037'1 ~W/1


# A~

..09

. ./!'7

## Competence Center Analytics 

# a·BASF

The Chemical Company



# Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page15of32

Molmasse RI ERe 75H Integral [%J 

# 11LOO371

77 3.36714E+2 3.17767E+0 1.08169E+0 

# EJ,J /l 78 3.40316E+2 3.01397E+0 1.09698E+0 79 3.43956E+2 2.83564E+0 1.11147E+0 80 3.47635E+2 2.83954E+0 1.12597E+0 

# /16, 

# 09. 81 3.51353E+2 2.89075E+0 1.14070E+0 

## .,/J'?



# ~ 82 3.65111E+2 2.80432E+O 1.15504E+0 83 3.58910E+2 2.82574E+O 1.16948E+0 84 3.62749E+2 2.96438E+0 1.18455E+0 85 3.66629E+2 2.95761E+0 1.19959E+0 86 3.70550E+2 3.03331E+0 1.21497E+0 87 3.74514E+2 3.22320E+0 1.23122E+0 88 3.78520E+2 3.58199E+0 1.24911E+0 89 3.82568E+2 3.692271:+0 1.26749E+0 90 3.86661E+2 3.96841E+0 1.28713E+0 91 3.90796E+2 4.24617E+0 1.30804E+0 92 3.94976E+2 4.62794E+0 1.33069E+0 93 3.99201E+2 5.02884E+0 1.35516E+0 94 4.03471E+2 5.40195E+0 1.38133E+0 95 4.07787E+2 5.84494E+0 1.40952E+0 96 4.12149E+2 6.31041E+0 1.43983E+0 97 4.16557E+2 6.63081E+0 1.47160E+0 98 4.21013E+2 7.06696E+0 1.50536E+0 99 4.25516E+2 7.61360E+0 1.54160E+0
100 4.30067E+2 8.16969E+0 1.58038E+0 

# 0101 4.34667E+2 8.48354E+0 1.62059E+0
102 4.39317E+2 9.02559E+0 1.66327E+0 103 4.44016E+2 9.32204E+0 1.70730E+0 104 4.48765E+2 9.79214E+0 1.75346E+0 105 4.53565E+2 9.90484E+0 1.80015E+0
106 4.58417E"'2 1.03503E+1 1.84886E+0
107 4.63320E+2 1.03668E+1 1.89764E+0
108 4.68276E+2 1.04795E+1 1.94694E+0 109 4.73285E+2 1.06502E+1 1.99702E+0 110 4.78347E+2 1.06289E"1 2.04700E+0 111 4.83463E+2 1.05259E+1 2.09651E+0 112 4.88635E+2 1.06568E+1 2.14661E+0 113 4.93861E+2 1.05518E+1 2.19624E+0 114 4.99144E+2 1.04267E+1 2.24530E+0 115 5.04483E+2 1.04097E+1 2.29428E+0 116 5.09879E+2 1.04206E+1 2.34331E+0 117 5.15333E+2 1.05827E+1 2.39308E+0 118 5.20845E+2 1.06856E+1 2.44332E+0 119 5.26416E+2 1.08684E+1 2.49439E+0 120 5.32046E+2 1.11578E+1 2.54678E+0 121 5.37737E+2 1.14948E+1 2.60070E+0 122 5.43489E

...

2 1.17791E+1 2.65592E+0 123 5.49302E+2 1.21881E+1 2.71300E+0 

# 0 124

5.55178E+2 1.26473E+1 2.77218E+0 125 5.61116E+2 1.32098E+1 2.83391E+0 126 5.67118E+2 1.35667E+1 2.89727E+0 127 5.73184E+2 1.39611E+1 2.96243E+0 128 5.79315E"2 1.45797E+1 3.03040E+0 129 5.85512E+2 1.51725E+1 3.10108E+0 130 5.91774E+2 1.55222E+1 3.17334E+0
131 5.98104E+2 1.58928E+1 3.24730E+0 132 6,04502E+2 1.63615E+1 3.32339E+0 133 6.10967E+2 1.65878E+1 3.40051E+0 134 6.17503E+2 1.70538E+1 3.47975E+0 135 6.2410BE+2 1.70B471:+1 3.55914E+0 136 6.30783E+2 1.74611E+1 3.64024E+0 137 6.37530E+2 1.76706E+1 3.72229E+0 138 6.44349E"2 1.79378E+1 3.80556E+0 139 6.51241E+2 1.80755E+1 3.88946E+0 140 6.58207E+2 1.83334E+1 3.97453E+0
141 6.65248E

....

·2 1.84845E+1 4.06029E+O 142 6.72363E+2 1.87781E+1 4.14739E+0 143 6.79555E+2 1.91358E+1 4.23611E+O 144 6.86824E+2 1.95529E+1 4.32674E+0 145 6.94170E+2 1.98488E+1 4.41871E+0 146 7.01595E+2 2.02260E+1 4.51240E+0 147 7.09100E+2 2.07113E+1 4.60B31E+0 148 7.16684E+2 2.11968E+1 4.70642E+0 149 7.24350E+2 2.16857E+1 4.80676E+O 150 7.32098E+2 2.21161E+1 4.90906E+0 151 7.39929E+2 2.25679E+1 5.01342E+0 152 7.47843E+2 2.29886E+1 5.11970E+0

# a·BASF competence Center Analytics

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 16of32

153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 

# 0177 178 179 180 181 182 183 164 185 186 187 166 189 190 191 192 193 194 195 196 197 198 199 

## ~oo \...1'.201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 MoimaSS8
7.SS842E+2 7.63927E+2 7.72098E+2 7.80357E+2 7.88704E+2 7.97140E+2 8.0S666E+2 8.14264E+2 8.22994E+2 8.31797E+2 8.40694E+2 8.49686E+2 8.58774E+2 8.67960E+2 8.77244E+2 8.86627E+2 8.96111E+2 9.05696E+2 9.15383E+2 9.25175E+2 9.35071E+2 9.45072E+2 9.55181E+2 9.65398E+2 9.75724E+2 9.86161E+2 9.96709E+2 1.00737E+3 1.01815E+3 1.02904E+3 1.04004E+3 1.05117E+3 1.06241E+3 1.07377E+3 1.08526E+3 1.09687E+3 1.10860E+3 1.12046E+3 1.13244E+3 1.14456E

..3 1.15680E+3 1.16917E+3 1.18168E+3 1.19432E+3 1.20709E+3 1.22000E+3 1.23305E+3 1.24624E+3 1.25957E+3 1.27304E+3 1.28666E+3 1.30042E+3 1.31433E+3 1.32839E+3 1.34260E+3 1.35696E+3 1.37148E+3 1.38615E+3 1.40097E+3 1.41596E+3 1.43110E+3 1.44641E+3 1.46188E+3 1.47752E+3 1.49332E"'3 1.50929E+3 1.S2544E+3 1.5417SE+3 1.SS82SE+3 1.57491E+3 1.59176E+3 1.60878E+3 1.62599E+3 1.64338E+3 1.66096E+3 1.67873E+3 RI ERe 75H Integral ["!o]

2.33830E+1 5.22777E+O 2.37009E+1 5.33729E+O 2.41509E+1 5.44885E+o 2.43969E+1 5.56154E+O 2.48537E+1 5.87631 E+O 2.52565E"1 5.79292E+O 2.57386E+1 S.91172E+O 2.60453E"'1 6.03192E+O 2.65240E+1 6.15429E+O 2.69349E"1 6.27854E+0 2.740S0E+1 6.40493E+O 2.78197E+1 6.53321E+O 2.8174BE+1 6.66311E+O 2.84947E+1 6.79446E+O 2.92S36E+1 6.92927E+O 2.96893E+1 7.06607E+O 3.01344E+1 7.20489E+O 3.05756E+1 7.34572E+O 3.10154E"'1 7.48856E+O 3.14678E+1 7.63345E+O 3.20196E+1 7.78086E+O 3.25406E+1 7.93064E+O 3.29600E+1 8.0B234E+O 3.35032E+1 8.23650E"'O 3.39316E"'1 8.39262E+O 3.44086E+1 8.55091 E+O 3.50760E"'1 8.71224E+0 3.53949E+1 8.87502E+0 3.59772E+1 9.04046E+O 3.65560E+1 9.20853E+0 3.71012E+1 9.37908E+0 3.7B541E+1 9.55307E+O 3.81217E+1 9.72827E+O 3.86420E+1 9.90584E+O 3.91961 E+1 1.00859E+1 3.97975E+1 1.02688E+1 4.04129E+1 1.04544E+1 4.09428E+1 1.06425E+1 4.15277E+1 1.08332E+1 4.19113E+1 1.10256E"1 4.25027E+1 1.12208E+1 4.30270E+1 1.14183E+1 4.36947E+1 1.16189E+1 4.44042E+1 1.18227E+1 4.47769E+1 1.20283E+1 4.52367E+1 1.22359E+1 4.60709E+1 1.24473E+1 4.65879E+1 1.26610E+1 4.72545E+1 1.28778E+1 4.76841E+1 1.30966E+1 4.84223E+1 1.33187E+1 4.89111E+1 1.35431E+1 4.94445E+1 1.37698E+1 5.01015E+1 1.39996E+1 5.06875E+1 1.42320E+1 5.12733E+l 1.44671E+1 5.19799E+1 1.47055E+1 5.26266E+1 1.49467E+1 5.32181E+1 1.51907E+1 5.37780E+l 1.54372E+1 5.42868E+1 1.56860E+1 5.49319E+l 1.59378E+1 5.56813E+l 1.61930E+1 5.63130E+l 1.64510E+l 5.69705E+1 1.67121E+1 5.76506E+1 1.69763E+1 5.80678E+1 1.72423E+1 5.88249E+1 1.75118E+1 5.93194E+1 1.77836E+1 6.00072E+1 1.80584E+1 6.07526E+1 1.83367E+1 6.1351BE+1 1.86177E+1 6.20290E+l 1.89018E+1 6.26757E+l 1.918B9E+1 6.32876E+1 1.94787E+1 6.38920E+1 1.97713E+1 

## .j

# 'iL00371 

# ew'1 

# -es: t!)

# 9. /f'1

# 7e

# a·BASF Competence Center Analytics

TheChemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 17of 32

229 

### 230 231 232 233 234 235 236 237 238 

### 239 240 241 242 243 244 245 246 247 248 249 250 251 252 

### r-,253 V254 

### 255 256 257 

### 258 259 

### 260 261 

### 262 263 264 265 

### 266 267 

### 268 269 

### 270 271 272 273 274 275 

# 0276 277 278 279 

### 280 281 282 283 

### 284 285 

### 286 287 288 289 

### 290 291 

### 292 293 294 295 

### 296 297 298 299 

### 300 301 

### 302 303 

### 304 Molmasse
1.69668E+3 1.71483E+3 1.73318E+3 1.75171E+3 1.77045E+3 1.78939E+3 1.80853E+3 1.82787E+3 1.84742E+3 1.86718E+3 1.88716E+3 1.90734E+3 1.92774E+3 1.94836E+3 1.96920E+3 1.99027E+3 2.0115SE+3 2.03307E+3 2.054B2E+3 2.07680E+3 2.09901E+3 2.12146E+3 2.14415E+3 2.16709E+3 2.19027E+3 2.21369E+3 2.23737E+3 2.26130E+3 2.28549E+3 2.30994E+3 2.3346SE+3 2.35962E+3 2.38486E+3 2.41037E+3 2.43615E+3 2.46220E+3 2.48854E+3 2.51516E+3 2.54206E+3 2.56925E+3 2.59673E+3 2.62451E+3 2.65258E+3 2.68095E+3 2.70963E+3 2.73861E+3 2.76791E+3 2.79751E+3 2.82744E+3 2.85768E+3 2.88824E+3 2.91914E+3 2.95036E+3 2.98192E+3 3.01382E+3 3.04605E+3 3.07863E+3 3.11156E+3 3.14485E+3 3.17848E+3 3.21248E+3 3.24684E+3 3.28157E+3 3.31667E+3 3.35215E+3 3.38800E+3 3.42424E+3 3.46087E+3 3.49789E+3 3.53530E+3 3.57312E+3 3.61134E+3 3.64996E+3 3.68900E+3 3.72846E+3 3.76834E+3 

### RI ERe 75H Integral 

### ["101

6.44147E+1 2.00662E+1 6.S0364E+1 2.03640E+1 6.57096E+1 2.06649E+1 6.62756E+1 2.09683E+1 6.68149E+1 2.12742E+1 6.74558E+1 2.15830E+1 6.80614E+1 2.18946E+l 6.85646E+1 2.22085E+1 6.9l202E+1 2.25248E+l 6.98543E+1 2.28446E+1 7.04503E+1 2.31670E+1 7.09334E+1 2.34917E+1 7.14169E+1 2.38185E+1 7.21639E+1 2.41488E+1 7.26504E+1 2.44813E+1 7.32371E+1 2.4Bl64E+l 7.39011E+1 2.51546E+l 7.45200E+l 2.54956E+1 7.50219E+1 2.58388E+1 7.54937E+1 2.61843E+1 7.59982E+l 2.65320E+l 7.664S0E+1 2.68826E+1 7.72008E+1 2.72358E+1 7.77602E+1 2.75916E+1 7.82963E+1 2.79498E+1 7.88424E+1 2.83104E+1 7.93722E+1 2.86735E+1 7.99350E+1 2.90392E+1 8.04273E+1 2.94071E+1 8.08224E+l 2.97768E+1 8.15075E+1 3.01496E+1 8.19308E+1 3.05243E+1 B.25584E+1 3.09019E+1 8.26674E+1 3.12800E+1 8.34106E+1 3.16615E+l 8.39464E+1 3.20454E+l 8.42623E+l 3.24308E+1 8.49007E+1 3.28l91E+l 8.54180E+l 3.32097E+1 8.58288E+1 3.36022E+1 8.63566E+1 3.39971E+1 8.67834E+1 3.43939E+1 8.72156E+1 3.47927E+1 8.76926E+1 3.51937E+1 8.81393E+1 3.55967E+1 8.86439E+1 3.60021 E+1 8.90002E+1 3.64090E+1 8.94794E+1 3.68181 E+1 8.99506E+1 3.72294E+1 9.04922E+1 3.78431 E+1 9.10049E+1 3.80592E+1 9.12532E+1 3.84764E+1 9.14902E+1 3.88947E+1 9.20525E+1 3.93155E+1 9.26128E+1 3.97389E+1 9.29071E+1 4.01637E+1 9.33363E+1 4.05904E+1 9.37879E+1 4.10191 E+1 9.40496E+1 4.14490E+1 9.44899E+1 4.18810E+1 9.48518E+1 4.23146E+1 9.52499E+1 4.27500E+1 9.53901 E+1 4.31860E+1 9.5B907E+1 4.36244E+1 9.62153E+l 4.40642E+1 9.64425E+1 4.45050E+1 9.66302E+1 4.49467E+1 9.69134E+1 4.53897E+1 9.72245E+1 4.58341E+1 9.74387E+1 4.62794E+1 9.77124E+1 4.67261E+1 9.81079E+1 4.71745E+1 9.82660E+1 4.76236E+1 9.84748E+1 4.80737E+1 9.87052E+1 4.85249E+1 9.88740E+1 4.89768E+1 

## .j

# 1L00371 

# EW/I /I.{". OS.

~

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 18of32

Molmasse RI ERe 75H Integral [%] 

# 11LOO371

305 3.80865E+3 9.90654E+1 4.94296E+1 

# eWA 306 3.84939E+3 9.91594E+1 4.98828E+1 307 3.89056E+3 9.92771E+1 5.03365E+1 308 3.93218E+3 9.94279E+1 5.07910E+1 

## /(J": 

# .99_ /1'1 

# K 309 3.97424E+3 9.96474E+1 5.12464E+1 310 4.01675E+3 9.94755E+1 5.17011E+1 311 4.05971E+3 9.96639E+1 5.21566E+1 312 4.10313E+3 9.96994E+1 5.26123E+1 313 4.14702E+3 9.98174E+1 5.30685E+1 314 4.19138E+3 9.98064E+1 5.35246E+l 315 4.23621E+3 9.98507E+1 5.39810E+1 316 4.28152E+3 9.99902E+1 5.44380E+1 317 4.32732E+3 9.97946E+1 5.48941E+1 318 4.37361E+3 9.97480E+1 5.53500E+1 319 4.42039E+3 9.97077E+1 5.58057E+1 320 4.46767E+3 9.95750E+1 5.62608E+1 321 4.51546E+3 9.94522E+1 5.67154E+1 322 4.56375E+3 9.94117E+1 5.71697E+1 323 4.61257E+3 9.93530E+1 5.76238E+1 324 4.66191E+3 9.91320E+1 5.80769E+1 325 4.71177E+3 9.89234E+1 5.85290E+l 326 4.76217E+3 9.87902E+l 5.89806E+1 327 4.81311E+3 9.86773E+l 5.94316E+1 328 4.86459E+3 9.85796E+l 5.98822E+1 

# aZ9 4.91662E+3 9.82853E+1 6.03314E+1 30 4.96921E+3 9.80373E+1 6.07795E+1 331 5.02236E+3 9.77719E+1 6.12264E+1 332 5.07608E+3 9.76149E+1 6.16726E+1 333 5.13038E+3 9.73620E+1 6.21176E+1 334 5.18526E+3 9.71064E+l 6.25615E+l 335 5.24072E+3 9.69744E+1 6.30047E+1 336 5.29677E+3 9.67449E+1 6.34469E+1 337 5.35343E+3 9.64067E+1 6.38876E+1 338 5.41069E+3 9.61153E+1 6.43270E+1 339 5.46857E+3 9.57469E+l 6.47646E+1 

### 340 5.52706E+3 9.53592E+1 6.52005E+1 341 5.58618E+3 9.49026E+1 6.56344E+l 342 5.64593E+3 9.46182E+1 6.60669E+1 343 5.70632E+3 9.44056E+1 6.64984E+l 344 5.76736E+3 9.40931E+1 6.69286E+1 345 5.82904E+3 9.36947E+1 6.73569E+1 34e 5.89139E+3 9.32893E+1 6.77834E+1 347 5.95441E+3 9.29323E+1 6.82082E"'1 34e 6.01810E+3 9.25300E+1 6.86313E+1 349 6.08247E+3 9.22653E+l 6.90531E+1 350 6.14753E+3 9.18498E+1 6.94730E+1 351 6.21329E+3 9.14214E+1 6.98910E+l
0!52 6.27974E+3 9.10538E+1 7.03072E+1 53 6.34691E+3 9.05164E+1 7.07211E+l 354 6.41480E+3 9.01362E+1 7.11332E+1 355 6.48342E+3 8.97643E+1 7.15436E+l 356 6.55277E+3 8.92772E+l 7.19518E+1 357 6.62286E+3 B.B7883E+1 7.2357BE+1 358 6.69370E+3 8.82509E+1 7.27613E+l 359 6.76529E+3 6.77262E+1 7.31625E+1 360 6.B3766E+3 8.71914E+l 7.35612E+l 361 6.91079E+3 8.68288E+1 7.39582E+1 362 6.98471E+3 8.63446E+1 7.43531E+l 363 7.05942E+3 8.56841E+1 7.47449E+l 364 7.13493E+3 8.51829E+l 7.51345E+1 365 7.21125E+3 8,46305E+1 7.55215E+1 366 7.28838E+3 6.41839E+1 7.59065E+l 367 7.36634E+3 6.37213E+1 7.62894E+1 368 7.44513E+3 8.30492E+1 7.66692E+1 369 7.52477E+3 8.24097E+1 7.70462E+1 370 7.60526E+3 8.18429E+1 7.74205E+1 371 7.68660E+3 8.12759E+l 7.77923E+1 372 7.76882E+3 8.07106E+l 7.81615E+1 373 7.85192E+3 8.01452E+1 7.852B1E+1 374 7.93590E+3 7.94313E+1 7.B8914E+1 375 8.02079E+3 7.87582E+1 7.92517E+1 376 8.10658E+3 7.81460E+1 7.96092E+1 377 8.19329E+3 7.75458E+l 7.99640E+l 378 8.28093E+3 7.68420E+1 8.03155E+l 379 8.369SOE+3 7.62139E+1 8.06842E+1 380 8.45903E+3 7.S5534E+l 8.10099E+l

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 19of32



# 11LOO371
Molmasse RI ERe 751~ Integral 

### rID]

381 8.54951E+3 7.48754E+1 8.13525E+1 

# eW/?

382 B.64095E+3 7.42296E+l B.16922E+l 383 8.73338E+3 7.34574E+l 8.20284E+1 

# A.>.09, 

# /1'17:e_ 384 8.82679E+3 7.27746E+l 8.23614E+l 385 8.92121E+3 7.22l98E+l 8.26919E+1 386 9.0l663E+3 7.l54l7E+l 8.30l93E+l 387 9.11308E+3 7.08124E+1 8.33434E+1 388 9.2l055E+3 7.0l376E+l B.36645E+l 389 9.30907E+3 6.93790E+l 8.39820E+l 390 9.40864E+3 6.B6459E+1 8.42963E"'1 391 9.50928E+3 6.79783E+l 8.46074E+l 392 9.61099E+3 6.72274E+1 8.49152E+1 393 9.7l380E+3 6.63955E+1 8.52192E+1 394 9.8l770E+3 6.55737E+l 8.55194E+1 395 9.92271E+3 6.48600E+l 8.58164E+1 396 1.00288E+4 8.4l476E+1 8.61102E+1 397 1.0l361E+4 6.34110E+1 8.64006E+1 398 1.02445E+4 6.26160E+1 8.66873E+1 399 1.03S41E+4 6.l80l7E+l B.69704E+1 400 1.04649E+4 6.09885E+1 8.72497E+l 401 1.05768E+4 6.03492E+l 8.7S262E+l 402 1.06899E+4 5.96283E+l 8.77993E+l 403 1.08043E+4 5.88402E+l 8.80689E+l 404 1.09l98E+4 5.80655E+l 8.83350E+l 

# O:g~1.l0366E+4 5.73359E+l 8.85977E+l

1.11S47E+4 5.63BB3E+l 8.88561E+1 407 1.12740E+4 5.54437E+1 B.91102E+l 408 1.13946E+4 5.45B9BE+1 8.93604E+l 409 1.15165E+4 5.38939E+1 8.96074E+1 410 1.16397E+4 5.31162E+1 B.98S09E+l 411 1.17642E+4 S.21815E+1 9.00902E+1 412 1.18900E+4 5.15566E+1 9.03266E+1 413 1.20172E+4 5.07972E+l 9.05595E+1 414 1.2l457E+4 4.97351E+l 9.07876E+1 415 1.22756E+4 4.89879E+1 9.10123E+1 416 1.24069E+4 4.82343E+1 9.12336E+1 417 1.25396E+4 4.74673E+1 9.14513E+l 418 1.26738E+4 4.67639E+l 9.16659E+1 419 1.28093E+4 4.S967SE+l 9.18768E+1 420 1.29463E+4 4.51802E+l 9.20842E+l 421 1.30848E+4 4.43662E+l 9.22878E+l 422 1.3224BE+4 4.36243E+1 9.24881E+1 423 1.33662E+4 4.28S80E+1 9.26849E+l 424 1.35092E+4 4.20220E+l 9.28778E+l 425 1.36537E+4 4.12277E+1 9.30672E+l 426 1.37997E+4 4.04406E+l 9.32529E+1 427 1.39473E+4 3.97067E+1 9.34354E+l
0!28 1.40965E+4 3.89733E+l 9.36144E+1 429 1.42473E+4 3.BOBB1E+l 9.37B9SE+l 430 1.43997E+4 3.74001E+1 9.39614E+1 431 1.45S37E+4 3.66360E+1 9.41298E+l 432 1.47094E+4 3.58413E+1 9.42947E+l 433 1.48667E+4 3.51801E+1 9.44565E+l 434 1.50257E+4 3.4Sl32E+l 9.46l52E+l 435 1.5l865E+4 3.37855E+l 9.47707E+1 436 1.53489E+4 3.32042E+l 9.49235E+l 437 1.5Sl31E+4 3.24738E+l 9.50730E+l 438 1.56790E+4 3.17397E+1 9.52191E+1 439 1.58467E+4 3.09353E+l 9.53616E+l 440 1.60l62E+4 3.03262E+1 9.55013E+l 441 1.6l875E+4 2.97563E+l 9.56384E+l 442 1.63607E+4 2.90702E+1 9.57723E+l 443 1.6S357E+4 2.84522E+l 9.S9035E+1 444 1.67l25E+4 2.77865E+1 9.60315E+l 445 1.66913E+4 2.71536E+1 9.61569E+1 446 1.70720E+4 2.65901E+l 9.62796E+l 447 1.72546E+4 2.5883SE+l 9.63990E+l 448 1.74391E+4 2.5l951E+l 9.6S153E+l 449 1.76257E+4 2.47133E+1 9.66295E+1 450 1.7B142E+4 2.40762E+l 9.67407E+l 451 1.80047E+4 2.34566E+1 9.68491E+l 452 1.81973E+4 2.28970E+1 9.69550E+l 453 1.83920E+4 2.23425E+l 9.70SB3E+l 454 1.85887E+4 2.17893E+l 9.71591E+1 455 1.87875E+4 2.12374E+1 9.72574E+l 456 1.89885E+4 2.06868E+l 9.73532E+1

# Competence CenterAnalytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company



## Page 20of32

457 458 459 460 461 462 463 464 465 466 467 468 469 470 471 

### 472 473 

### 474 475 476 477 478 

### 479 480 ~481 

### "\L7482 483 484 485 486 487 

### 488 489 490 491 492 493 494 495 498 

### 497 498 499 500 501 502 503 

### .A":l.504 '-J505 506 

### 507 508 509 

### 510 511 

### 512 513 

### 514 515 516 

### 517 518 519
520 521 522 

### 523 524 525 

### 526 527 528 

### 529 530 

### 531 532 Molmasse
1.91916E+4 1.93969E+4 1.96043E+4 1.98140E+4 2.00260E+4 2.02402E+4 2.04567E+4 2.06755E+4 2.08966E+4 2.11201 E+4 2.13461E+4 2.15744E+4 2.18051E+4 2.20384E+4 2.22741E+4 2.25124E+4 2.27531E+4 2.29965E+4 2.32425E+4 2.34911E+4 2.37424E+4 2.39963E+4 2.42530E+4 2.45124E+4 2.47746E+4 2.50396E+4 2.53074E+4 2.55781E+4 2.58517E+4 2.61282E+4 2.64077E+4 2.66902E+4 2.69757E+4 2.72642E+4 2.75558E+4 2.78506E+4 2.81485E+4 2.84495E+4 2.87538E+4 2.90614E"'4 2.93723E+4 2.96864E+4 3.00040E+4 3.03249E+4 3.06493E+4 3.09771E+4 3.13084E+4 3.16433E+4 3.19818E+4 3.23239E+4 3.26696E+4 3.30190E+4 3.33"122E+4 3.37292E+4 3.40900E+4 3.44546E+4 3.48231E+4 3.51956E+4 3.55721E+4 3.59526E+4 3.63371E+4 3.67258E+4 3.71186E+4 3.75156E+4 3.79169E+4 3.83225E+4 3.87324E+4 3.91467E+4 3.95654E+4 3.99886E+4 4.04163E+4 4.06486E"'4 4.12856E+4 4.17272E+4 4.21735E+4 4.26246E"'4 RI ERe 751eIntegral [%]

2.02032E+1 9.74468E+1 1.96675E+1 9.75379E+1 1.91796E+1 9.76269E+1 1.86547E+1 9.77134E+1 1.81085E+1 9.77974E+1 1.76082E+1 9.78792E+1 1.71039E+1 9.79587E+1 1.66238E+1 9.80360E+1 1.61862E+1 9.81113E+1 1.56669E"'1 9.81842E+1 1.51740E+1 9.82549E+1 1.46042E+1 9.83230E+1 1.43600E+1 9.83899E+1 1.38266E+1 9.84545E+1 1.35089E+1 9.85176E+1 1.30679E+1 9.85787E+1 1.24919E+1 9.86371 E+1 1.21051E+1 9.86938E+1 1.17537E+1 9.87489E+1 1.13741E+1 9.88023E+1 1.09974E+1 9.88540E+1 1.06513E+1 9.89040E+1 1.03046E+1 9.89525E+1 9.87036E+0 9.89991E+1 9.50846E+0 9.90439E+1 9.20902E+0 9.90875E+1 8.91035E+0 9.91296E+1 8.54195E+0 9.91701E+1 8.17046E+0 9.92089E+1 7.80322E+0 9.92460E+1 7.48470E+0 9.92816E+1 7.23258E+0 9.93161E+1 6.94109E+0 9.93493E+1 6.65944E+0 9.93812E+1 6.42670E+0 9.94121E+1 6.04612E"'0 9.94412E+1 5.88799E+0 9.94696E+1 5.59740E+Q 9.94966E+1 5.38022E+0 9.95227E+1 5.16407E+0 9.95478E+1 4.948461i+0 9.95719E+1 4.68344E+0 9.95948E+1 4.48094E+0 9.96168E+1 4.30485E+O 9.96379E+1 4.03768E+0 9.96579E+1 3.79362E+O 9.96768E+1 3.81002E+O 9.96957E+1 3.52272E+0 9.97133E+1 3.16770E+0 9.97293E+1 3.01497E+0 9.97446E+1 2.99093E+0 9.97598E+1 2.89268E+0 9.97745E+1 2.75468E+0 9.97886E+1 2.54830E+0 9.98018E+1 2.34553E+0 9.96141E+1 2.25882E+0 9.98259E+1 2.14040E+0 9.96372E+1 2.13890E+0 9.98485E+1 1.93240E+0 9.98589E+1 1.91130E+0 9.98692E+1 1.86159E+0 9.98792E+1 1.74868E+0 9.98888E+1 1.57534E+O 9.98975E+1 1.42695E+0 9.99056E+ 1 1.34269E+0 9.99133E+1 1.20556E+0 9.99203E+1 1.07352E+0 9.99268E+1 1.00603E+0 9.99329E+1 1.06197E+0 9.99393E+1 926384E-1 9.99451E+1 7.68514E-1 9.99502E+1 7.70967E-1 9.99553E+1 7.63850E-1 9.99603E+1 5.55966E-1 9.99644E+1 5.46591 E-1 9.99685E+1 4.16044E-1 9.99719E+1 

# 11L0037'j
Ghl/f
/lb. 0.5'.

# /l".,::e

## Competence Center Analytics



# Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company


# Page21 of32

Molmasse RI ERe75H Integral [%1
533 4.30805E+4 4.77056E-1 9.99757E+1 534 4.35413E+4 3.81490E-1 9.99790E+1 535 4.40070E+4 2.96279E-1 9.99819E+1 536 4.44778E+4 2.32763E-1 9.99845E+1 537 4.49535E+4 2.46774E-1 9.99872E+1 538 4.54343E+4 3.19242E-1 9.99902E+1 539 4.59203E+4 2.03857E-1 9.99927E+1 540 4.64115E+4 2.06516E-1 9.99952E+1 541 4.69079E+4 1.44759E-1 9.99975E+1 542 4.74097E+4 1.37809E-1 9.99997E+1 543 4.79168E+4 1.86201E-1 1.00000E+2 S44 4.84293E+4 1.87327E-1 1.00000E+2 545 4.89473E+4 1.00353E-1 1.00000E+2 546 4.94709E+4 5.87721E-4 1.00000E+2



# o



# o 'j 

# 1La0371 

# EW/l 

# -r«. 05'./1'1 

# rte

# a·BASF Competence Center Analytics

TheChemical Company


# Page22of32 Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential)

77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 

# a01 02 103 104 105 106 107 

### 108 109 

### 110 111 112 113 114 115 116 117 

### 118 119 

### 120 121 

### 122 123 

# Q24 25 

### 126 127 

### 128 129 

### 130
131 132 

### 133 134 135 

### 136 137 

### 138 139 

### 140
141 

### 142 143 144 

### 145 146 

### 147 148 149 

### 150 151 152 Molmasse
3.53886E+2 3.57601E+2 3.61356E+2 3.6515OE+2 3.68984E+2 3.72858E+2 3.76773E+2 3.80729E+2 3.84726E+2 3.88766E+2 3.92847E+2 3.96972E+2 4.0114OE+2 4.05352E+2 4.09608E+2 4.13909E+2 4.18254E+2 4.22646E+2 4.27083E+2 4.31568E+2 4.36099E+2 4.40678E+2 4.45304E+2 4.49980E+2 4.54704E+2 4.59479E+2 4.64303E+2 4.69178E+2 4.74104E+2 4.79082E+2 4.84112E+2 4.89195E+2 4.94331E+2 4.99521E+2 5.04766E+2 5.10066E+2 5.15421E+2 5.20833E+2 5.26301E+2 5.31827E+2 5.37411E+2 5.43054E+2 5.48755E+2 5.54517E+2 5.60339E+2 5.66222E+2 5.72168E+2 5.78175E+2 5.84246E+2 5.90380E+2 5.96578E+2 6.02842E+2 6.09172E+2 6.15568E+2 6.22031E+2 6.28562E+2 6.35161E+2 6.41830E+2 6.48569E+2 6.55379E+2 6.62260E+2 6.69213E+2 6.76240E+2 6.83340E+2 6.90515E+2 6.97765E+2 7.05091E+2 7.12494E+2 7.19975E+2 7.27534E+2 7.35173E+2 7.42892E+2 7.50692E+2 7.58573E+2 7.66538E+2 7.74586E

...

2 RI ERe 75H Integral ['Yo]
6.79603E+0 1.49881 E+O 7.51969E+0 1.53219E+0 7.70551 E+O 1.56638E+0 8.15229E+0 1.60250E+0 8.41215E+0 1.63975E+0 9.45690E+0 1.68153E+0 1.01727E+1 1.72641 E+O 1.0794OE+1 1.77399E+0 1.2024OE+1 1.82689E+0 1.33666E+1 1.88562E+0 1.47866E+1 1.95050E+0 1.66207E+1 2.02333E+0 1.65481 E+1 2.10452E+0 2.09528E+1 2.19613E+0 2.33698E+1 2.29822E+0 2.64402E+1 2.41361E

... 0 2.95437E+1 2.54246E+0 3.32745E+1 2.68748E+0 3.73129E+1 2.85001E+0 4.16024E+1 3.03113E+0 4.60755E+1 3.23164E+0 5.12844E+1 3.45473E+0 5.62655E+1 3.69941E+0 6.18326E+ 1 3.96822E+0 6.71577E+1 4.26012E+0 7.28749E+1 4.57679E+O 7.83067E+1 4.91702E+0 8.31544E+1 5.27825E+0 8.79459E+1 5.66026E+0 9.207946+1 6.06018E+0 9.55620E+1 6.47520E+0 9.82025E+1 6.90167E+0 9.96311 E+1 7.33433E+0 9.99189E+1 7.76823E+0 9.949971:+1 8.20032E+0 9.81147E+l 8.62641E+0 9.55380E+1 9.04132E+O 9.21533E+1 9'44157E+0 8.77650E+1 9.82279E+0 8.24918E+l 1.01812E+1 7.69367E+1 1.05154E+1 7.12255E+1 1.08250E+1 6.53419E+1 1.11090E+l 5.97427E+1 1.13687E+1 5.37766E+1 1.16026E+1 4.85133E+1 1.18137E+1 4.33967E+1 1.20026E+1 3.90536E+1 1.21727E+l 3.51788E+1 1.23260E+1 3.16684E+1 1.24640E+1 2.88847E+1 1.25900E+l 2.64999E+1 1.27057E+1 2.46415E+1 1.28133E+1 2.30282E+1 1.29139E+1 2.17309E+1 1.30089E+1 2.09758E+1 1.31006E+1 2.01027E+1 1.31885E+1 1.92469E+1 1.32727E+1 1.94168E+1 1.33577E+1 1.90126E+1 1.34409E+1 1.89349E+1 1.35237E+1 1.879906:+1 1.36060E+1 1.89455E+1 1.36889E+1 1.91152E"1 1.37725E+1 1.B4200E+1 1.38575E+1 1.96261 E+1 1.39434E+1 2.01261E+1 1.40314E+1 2.06093E+1 1.41215E+1 2.07937E+1 1.42124E"1 2.12627E+1 1.43054E+1 2.15469E+1 1.43996E+1 2.20202E+1 1.44958E+1 2.25693E+1 1.45944E+1 2.29518E+1 1.46947E+1 2.33843E+1 1.47969E+1 2.36171 E+1 1.49000E+1 

# &'17/4 11L00246 '2?-. 

# o», A1

~

## Competence Center Analytics 

# a·BASF

TheChemical Company



## Final Report Characterization of "EFKA·3600N without DOA" Study No. 11L00371 (confidential) Page 23of32

Molmasse RI ERe 751

# eIntegral [%] 

# Gh//f 153 7.82719E+2 2.39439E+1 1.50046E+1 154 7.90937E+2 2.430S9E+1 1.S1107E+1 155 7.99242E+2 2.46183E+1 1.52182E+1 

# '11LOO246 156 8.07633E+2 2.49362E+1 1.S3271E+1 157 8.16113E+2 2.52557E+1 1.54374E+1 158 8.24682E+2 2.57216E+l 1.55497E+1 

# 27. Oi-. A17?:_ 159 8.33340E+2 2.61855E+1 1.56639E+1 160 8.42090E+2 2.65284E+1 1.57797E+1 161 8.50932E+2 2.70951E+1 1.58980E+1 162 8.S9866E+2 2.73120E+1 1.60171E+1 163 8.68894E+2 2.77868E+1 1.61384E+1 164 8.78017E+2 2.82S68E+1 1.62616E+1 165 8.87236E+2 2.87304E+1 1.63870E+1 166 8.965S1E+2 2.90273E+1 1.65136E+1 167 9.05965E+2 2.93664E+1 1.66417E+1 168 9.1S477E+2 2.9999SE+1 1.6772SE+1 169 9.2S089E+2 3.05538E+1 1.69057E+1 170 9.34802E+2 3.10015E+1 1.70409E+1 171 9.44617E+2 3.13161E+1 1.71774E+1 172 9.S4S35E+2 3.16341E+1 1.731S3E+1 173 9.64557E+2 3.20591E+1 1.74551E+l 174 9.74684E+2 3.25324E+1 1.75969E+1 175 9.84918E+2 3.27487E+1 1.77396E+1 176 9.95259E+2 3.33121E+1 1.78848E+1 

# a77 1.00571E+3 3.37990E+1 1.80321E+1 78 1.01627E+3 3.47061E+1 1.81833E+1 179 1.02694E+3 3.47602E+1 1.83348E+1 180 1.03772E+3 3.54864E+1 1.84894E+1 181 1.04862E+3 3.58538E+1 1.86456E+1 182 1.05963E+3 3.65100E+1 1.86046E+1 183 1.07075E+3 3.72088E+1 1.89667E+1 184 1.08199E+3 3.75339E+1 1.91302E+1 185 1.09335E+3 3.77595E+1 1.92947E+1 186 1.10483E+3 3.83198E+1 1.94616E+1 187 1.11643E+3 3.89333E+1 1.96311E+1 188 1.12816E+3 3.95559E+1 1.98034E+1 189 1.14000E+3 4.00229E+1 1.99776E+1 190 1.15197E+3 4.05867E+1 2.01543E+1 191 1.16407E+3 4.10033E+1 2.03329E+1 192 1.17629E+3 4.16403E+1 2.05142E+1 193 1.18864E+3 4.21870E+1 2.06978E+1 194 1.20112E+3 4.26577E+1 2.08835E+1 195 1.21373E+3 4.32538E+1 2.10718E+1 196 1.22647E+3 4.37306E+1 2.12621E+1 197 1.239351::+3 4.434861::+1 2.145521::+1 198 1.25236E+3 4.45257E+1 2.16489E+1 199 1.26551E+3 4.51427E+1 2.18454E+1 

# GOO 1.27880E+3 4.57820E+1 2.20447E+1 01 1.29223E+3 4.65340E+1 2.22471E+1 202 1.30579E+3 4.70794E+1 2.24520E+1 203 1.31950E+3 4.75183E+1 2.26588E+1 204 1.33336E+3 4.81401E+1 2.26662E+1 205 1.34736E+3 4.86766E+1 2.30800E+1 206 1.36150E+3 4.94715E+1 2.32952E+1 207 1.375BOE+3 4.99462E+1 2.35125E+1 208 1.39024E+3 5.04128E+1 2.37319E+1 209 1.40464E+3 5.09379E+1 2.39534E+l 210 1.41959E+3 5.15885E+1 2.41779E+1 211 1.43450E+3 5.20540E+1 2.44043E+1 212 1.44956E+3 5.25768E+1 2.46330E+1 213 1.46478E+3 5.30735E+1 2.48638E+1 214 1.48016E+3 5.37741E+1 2.50977E+1 215 1.49570E+3 5.41563E+1 2.53332E+1 216 1.51140E+3 5.50040E+1 2.55724E+1 217 1.52727E+3 5.56360E+1 2.58144E+1 218 1.54331E+3 5.61013E+1 2.60584E+l 219 1.55951E+3 5.65623E+1 2.63043E+1 220 1.57588E+3 5.71298E+l 2.65528E+1 221 1.59243E+3. 5.74130E+1 2.68024E+1 

### 222 1.60915E+3 5.83612E+1 2.70562E+1 223 1.62604E+3 5.88910E+1 2.73122E+1 224 1.64312E+3 5.96078E+l 2.75714E+1 225 1.86037E+3 6.01139E+1 2.78328E+1 226 1.67780E+3 6.05828E+1 2.80962E+1 227 1.69542E+3 6.12811E+1 2.83626E+1 228 1.71322E+3 6.18177E+1 2.86313E+1

# a·BASF competence Center Analytics

The Chemical Company


## Page 24of32 Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential)

229 230 

### 231 232 233 

### 234 235 

### 236 237 238 

### 239 240 241 

### 242 243 244 

### 245 246 247 248 

### 249 2150 251 

### 2152 

# a~

255 256 257 258 

### 259 260 261 262 263 264 265 

### 266 267 268 

### 269 270 271 

### 272 273 274 

### 275 ~76 ~77

### 278 279 260 

### 281 282 283 284 

### 285 286 

### 287 288 289 

### 290 291 292 293 294 295 

### 296 297 298 299 300 301 

### 302 303 304 Molmass8
1.73121E+3 1.74938E+3 1.76775E+3 1.78631E+3 1.60507E+3 1.82402E+3 1.84317E+3 1.86252E+3 1.88208E+3 1.90l84E+3 1.92181E+3 1.94l98E+3 1.96237E+3 1.98298E+3 2.00380E+3 2.024B4E+3 2.04610E+3 2.06758E+3 2.08929E+3 2.11123E+3 2.1.3339E+3 2.15579E+3 2.17843E+3 2.20130E+3 2.22441E+3 2.24777E+3 2.27137E+3 2.29521E+3 2.31931E+3 2.34366E+3 2.36827E+3 2.39314E+3 2.41826E+3 2.44365E+3 2.46931E+3 2.49524E+3 2.52144E+3 2.54791E+3 2.57466E+3 2.60170E+3 2.62901E+3 2.65661E +3 2.68451E+3 2.71269E+3 2.74118E+3 2.76996E+3 2.79904E+3 2.82843E+3 2.85812E+3 2.88813E+3 2.91846E+3 2.94910E+3 2.98006E+3 3.01135E+3 3.04297E+3 3.07492E+3 3.10721E+3 3.13983E+3 3.17280E+3 3.206llE+3 3.23977E+3 327379E+3 3.30816E+3 3.34289E+3 3.37799E"3 3.4l346E+3 3.44930E+3 3.46551E+3 3.52211E+3 3.55S09E+3 3.59646E+3 3.63422E+3 3.67238E+3 3.7l094E+3 3.74990E+3 3.76927E+3 RI ERe 751f Integral flo]

6.23452E+l 2.89024E+l 6.29502E+l 2.91760E+l 6.34601E+1 2.94519E+1 6.39100E+l 2.97297E+1 6.43627E+1 3.00095E+1 6.48084E+l 3.02912E+1 6.53667E+1 3.05753E+1 6.60929E+1 3.08626E+l 6.65885E+1 3.11520E+1 6.72984E+l 3.14445E+1 6.79152E+1 3.17397E+1 6.83626E+1 3.20368E+1 6.86615E+1 3.23353E+1 6.9l210E+l 3.26357E+l 6.965l4E+l 3.29392E+1 7.04059E+l 3.32452E+l 7.07238E+1 3.35526E+l 7.12284E+1 3.38621E+1 7.18522E+l 3.41743E+1 7.22312E+l 3.44882E+l 7.28215E+~ 3.4B047E+1 7.33559E+l 3.51234E+1 7.38549E+l 3.54444E+l 7.43758E+l 3.57676E+1 7.48809E+l 3.60929E+1 7.52290E+l 3.6419BE+1 7.5616BE+1 3.67484E+1 7.60260E+1 3.707B7E+l 7.64002E+1 3.74107E+l 7.69286E+1 3.77449E+l 7.74077E+1 3.80812E+1 7.76189E+l 3.B41B5E+l 7.63250E+1 3.B7588E+1 7.B72B4E+l 3.91DOBE+l 7.91259E+l 3.94446E+1 7.955B4E+1 3.97902E+l B.02526E+1 4.01369E+1 6.04204E+1 4.04883E+l 8.11224E+1 4.0B407E+1 6.12622E+1 4.11936E+1 8.18078E+1 4.15492E+l 8.19711E+1 4.19053E+1 8.25303E+1 4.22638E+1 8.29706E+1 4.26242E+l 6.34667E+1 4.29668E+l 6.36486E+l 4.33502E+l 8.41336E+1 4.37157E+1 8,47327E+1 4.40838E+1 8.50474E+1 4.44532E+1 8.53722E+1 4,46241E+1 6.56442E+1 4.51961 E+1 6.60403E+l 4.55698E+1 8.63346E+l 4.59448E+l 8.68336E+l 4.63220E+1 8.711521::+1 4.67004E+1 B.7512BE+1 4.70806E+1 B.79230E+1 4.74625E+1 6.B1908E+1 4.78455E+1 8.851B3E+1 4.B2300E+1 8.68674E+1 4.86160E+1 B.90121E+1 4.90027E+1 8.92532E+1 4.93903E+l 8.96581E+1 4.97798E+1 8.976B1E+1 5.01697E+l 9.00368E+1 5.05607E+1 9.02347E+1 5.09527E+1 9.03450E+1 5.13451 E+1 9.06704E+1 5.17369E+1 9.09603E+1 5.21340E+l 9.11D05E+1 5.25296E+1 9.13282E+1 5.29263E+1 9.14617E+1 5.33235E+1 9.18181E+1 5.37223E+1 9.1965BE+1 5.41216E+1 9.19425E+l 5.45211E+1 9..20328E+1 5.49206E+l 

# eW4 '11 LOa 

# 246
2?-. t9). 4

Ayt:e_

# a·BASF Competence Center Analytics

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 25of32

305 306 307 308 309 310 311 312 

### 313 314 315 316 317 318 319 320 

### 321 322 323 324 325 326 327 328 r'\329 ~30

### 331 332 333 

### 334 335 336 337 

### 338 339 340 

### 341 342 343 344 345 

### 346 347 348 

### 349 350 351 £1\352 

### ~353 354 

### 355 356 357 358 

### 359 360 361 

### 362 363 364 365 366 

### 367 368 

### 369 370 

### 371 372 

### 373 374 

### 375 376 377 378 

### 379 380 Molmasse
3.82906E+3 3.86926E+3 3.90988E+3 3.95094E+3 3.99242E+3 4.03434E+3 4.07670E+3 4.11950E+3 4.16275E+3 4.20646E+3 4.25062E+3 4.29525E+3 4.34035E+3 4.38592E+3 4.43197E+3 4.47851E+3 4.52553E+3 4.57304E+3 4.62106E+3 4.66958E+3 4.71860E+3 4.76815E+3 4.81821E+3 4.86880E+3 4.91992E+3 4.97158E+3 5.02377E+3 5.07652E+3 5.12982E+3 5.18368E+3 S.23811E+3 S.29311E+3 S.34868E+3 5.40484E+3 5.46159E+3 5.S1893E+3 5.57688E+3 S.63543E+3 5.69460E+3 5.75439E+3 5.81481E+3 5.87586E+3 5.93755E+3 5.99990E+3 6.06289E+3 6.12655E+3 6.19087E+3 6.25587E+3 6.321S6E+3 6.38793E+3 6.45500E+3 6.52277E+3 6.59126E+3 6.66047E+3 6.73040E+3 6.80106E+3 6.87247E+3 6.94463E+3 7.01754E+3 7.09122E+3 7.16568E+3 7.24091E+3 7.31694E+3 7.39376E+3 7.47139E+3 7.54984E+3 7.62911E+3 7.70921E+3 7.79015E+3 7.87194E+3 7.95460E+3 8.03811E+3 8.12251E+3 8.20779E+3 8.29397E+3 8.3810SE+3 RI ERe 75H Integral rk]

9.21382E+1 5.53210E+1 9.23793E+l 5.57222E+1 9.23537E+l 5.61233E+l 9.23109E+l 5.65243E+1 9.22678E+1 5.69250E+l 9.25131E+1 5.73268E+1 9.26141E+1 5.77291E+1 9.25701E+1 5.81311E+1 9.25209E+1 5.85329E+1 9.23595E+l 5.89341E+1 9.25891 E+1 5.93362E+1 9.25441 E+' 5.97381 E+1 9.24765E+1 6.01398E+1 9.21739E+1 6.05401 E+1 9..21009E+1 6.09401 E+1 9.18485E+1 6.13391E+1 9..21799E"1 6.17394E+1 9.21170E"1 6.21395E+1 9.19160E+1 6.25387E"1 9.16266E+1 6.29367E+1 9.15797E+1 6.33344E+1 9.15743E+1 6.37322E+1 9.17082E+1 6.41305E+1 9.12380E+1 6.45288E+1 9.08346E+1 6.49213E+1 9.07192E"1 6.53153E"1 9.03188E+1 6.57076E+1 9.02015E+1 6.60994E+1 8.98031 E+1 6.64695E+1 8.97788E+1 6.68794E+1 8.97790E+1 6.72694E+1 8.93578E+1 6.76575E+1 8.91211E+1 6.80446E+1 8.87014E+1 6.84299E+1 8.84730E+1 6.88142E+1 8.80288E+1 6.91965E+1 8.77204E+1 6.95776E+1 8.75156E+1 6.99577E+1 8.71645E+1 7.03363E+1 8.67209E+1 7.07130E+1 8.64169E+1 7.10884E+1 8.62098E+1 7.14629E+1 8.58703E+1 7.18359E+1 8.54084E+1 7.22069E+1 8.49470E+1 7.25759E+1 8.44995E+1 7.29430E+1 8.41717E+1 7.33086E+1 8.3B624E+1 7.36729E+1 B.36546E+1 7.40363E+1 8.31957E+1 7.43977E+1 8.27307E"1 7.47571E+1 821543E+1 7.5114OE+1 8.20975E+1 7.54707E+1 8.13648E+1 7.58242E+1 8.07704E+1 7.61751E+1 8.05901 E+1 7.65252E+1 7.98697E+1 7.68722E+1 7.94061E+1 7.72172E+1 7.9075BE+1 7.75607E+1 7.8S111E+1 7.79018E+1 7.79222E+1 7.82404E+1 7.74566E+1 7.85769E+1 7.68855E+1 7.89110E+1 7.64160E+1 7.92430E"1 7.S9599E+1 7.95731 E+1 7.55097E+1 7.99012E+1 7.48511E+1 8.02264E"1 7.41332E+1 8.05486E+1 7.37206E+1 8.08689E+1 7.31147E+1 8.11866E+1 7.26840E+1 8.15025E+1 7.21917E+1 8.18162E+1 7.15245E+1 8.21270E+1 7.07319E+1 8.24344E+1 7.02060E+1 8.27395E+1 6.95169E"1 8.30416E+1 

# EI/4 '11La02.46 2::;,0"). A4

~

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 26 of32



# EW/f

Molmasse RI ERe 751

## eIntegral [%J
381 8.46905E+3 6.88330E+1 8.33408E+1 

# ·11L00246 382 8.55797E+3 6.83247E+1 8.36377E+1 383 8.64782E+3 6.78163E+1 8.39325E+1 

# 2-+

.. f)

# t-, ~ 

# -:;ze 384 8.73862E+3 6.72573E+1 8.42248E+1 385 8.83037E+3 6.64994E+1 8.45139E+1 386 8.92309E+3 6.58740E+1 8.48002E+1 387 9.01677E+3 6.53826E+1 8.50844E+1 388 9.11145E+3 6.45907E+1 8.53652E+1 389 9.20711E+3 6.38928E+1 8.56429E+1 390 9.30378E+3 6.31998E+1 8.59176E+1 391 9.40147E+3 6.25309E+1 8.61895E+1 392 9.50018E+3 6.19448E+1 8.64588E+1 393 9.59992E+3 6.12375E+1 8.67250E+1 394 9.70072E+3 6.04527E+1 8.69878E+1 395 9.80257E+3 5.99904E+1 8.72487E+1 396 9.90549E+3 5.90496E+1 8.75054E+1 397 1.00095E+4 5.83597E+1 8.77592E+1 398 1.01146E+4 5.76788E+1 8.80100E+1 399 1.02208E+4 5.73564E+1 8.82594E+1 400 1.03281E+4 5.61307E+1 8.85035E+1 401 1.04365E+4 5.57994E+1 8.87461E+1 402 1.05461E+4 5.50039E+1 8.89854E+1 

### 403 1.06568E+4 5.42639E+1 8.92214E+1 404 1.07687E+4 5.36778E+1 8.94548E+1 {l05 1.08818E+4 5.29566E+1 8.96852E+1 06 1.09961E"'4 5.22336E"'1 8.99124E"'1 407 1.11115E+4 5.14852E+1 9.01363E"'1 408 1.122B2E+4 5.08929E+1 9.03577E+1 409 1.13461E+4 5.01015E+1 9.05757E+1 410 1.14652E+4 4.93136E+1 9.07902E+1 411 1.15856E+4 4.87786E+1 9.10025E+1 412 1.17072E+4 4.79812E+1 9.12112E+1 413 1.18301E+4 4.74434E+1 9.14177E+1 414 1.19543E+4 4.68506E+1 9.16215E+1 415 1.20799E+4 4.60347E+1 9.18219E+1 416 1.22067E+4 4.51521E+1 9.20184E+1 417 1.23349E+4 4.44895E+1 9.22120E+1 418 1.24644E+4 4.38320E+1 9.24028E+1 419 1.25952E+4 4.29167E+1 9.25896E+1 420 1.27275E+4 4.23678E"'1 9.27740E"'1 421 1.28611E+4 4.15022E+1 9.29547E+1 422 1.29961E+4 4.08124E+1 9.31324E+1 423 1.31326E+4 3.99622E+1 9.33064E+1 424 1.32705E+4 3.93283E+1 9.34777E+1 425 1.34098E+4 3.85591E+1 9.36456E+1 426 1.35506E+4 3.81089E+1 9.38116E+1 427 1.36929E+4 3.75626E+1 9.39752E+1 Q28 1.38366E+4 3.68428E+1 9.41357E+1 29 1.39819E+4 3.62255E+1 9.42935E+1 430 1.41287E+4 3.54153E+1 9.44478E+1 431 1.42771E+4 3.46280E+1 9.45987E+1 432 1.44270E+4 3.40857E+1 9.47472E+1 433 1.457B5E+4 3.34460E+1 9.48930E+1 434 1.47315E+4 3.28053E+1 9.50360E+1 435 1.48862E+4 3.20429E+1 9.S1757E+1 436 1.S042SE+4 3.15295E+1 9.53131E+1 437 1.52004E+4 3.07959E+1 9.54474E+1 438 1.53600E+4 3.03561E+1 9.55798E+1 439 1.SS213E+4 2.95912E+1 9.S7088E+1 440 1.56843E+4 2.89768E+1 9.58352E+1 441 1.58489E+4 2.63150E+1 9.59588E+1 442 1.60153E+4 2.77005E+1 9.60796E+1 443 1.61835E+4 2.72001E+1 9.61983E+1
444 1.63534E+4 2.670 17E+1 9.63148E+1 445 1.65251E+4 2.60809E+1 9.64287E+1 446 1.66986E+4 2.53052E+1 9.65392E+1 447 1.68739E+4 2.48310E+1 9.66476E+1 

### 448 1.70511E+4 2.4397SE+1 9.67541E+1 449 1.72301E+4 2.34223E+1 9.68564E+1 450 1.74110E+4 2.30484E+1 9.69571 E+1 451 1.75939E+4 2.26754E+1 9.70562E+1 452 1.77786E

...

4 2.19040E

...1 9.71519E+1 453 1.79652E+4 2.13234E+1 9.72451E+1 454 1.81539E+4 2.10738E+1 9.73373E+1 455 1.8344SE+4 2.05266E+1 9.74270E+1 456 1.85371E+4 1.98542E+1 9.75139E+1

## Competence Center Analytics



# Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company


# Page27of32

457 458 459 460 461 462 463 46<l 

### 465 466 

### 467 468 469 470 471 472 473 474 

### 475 476 477 478 479 480 c,)I81 'Ull82 483 484 485 486 487 488 489 490 

### 491 492 493 

### 494 495 496 497 498 

### 499 500 501 502 503 

# (fo~

506 507 508 509 510 511 512 513 

### 514 515 516 517 

### 518 519 520 521 522 523 

### 524 525 526 527 528 529 530 

### 531 532 Molmsss8
1.87317E+4 1.89284E+4 1.91271E+4 1.93280E+4 1.95309E+4 1.97359E+4 1.99432E+4 2.01526E+4 2.03642E+4 2.05780E+4 2.07940E+4 2.10123E+4 2.12330E+4 2.14559E+4 2.16812E+4 2.19088E+4 2.21388E+4 2.23713E+4 2.26062E+4 2.28435E+4 2.30834E+4 2.33257E+4 2.35707E+4 2.38181E+4 2.40682E+4 2.43209E+4 2.45763E+4 2.48343E+4 2.50951E+4 2.53585E+4 2.56248E+4 2.58938E+4 2.61657E+4 2.64404E +4 2.67180E+4 2.69986E+4 2.72820E+4 2.75685E+4 2.78579E+4 2.81504E+4 2.84460E+4 2.87447E+4 2.90465E+4 2.93514E+4 2.96596E+4 2.99710E+4 3.02857E+4 3.06037E+4 3.09250E+4 3.12497E+4 3.15778E+4 3.19094E+4 3.224441:+4 3.25829E+4 3.29251E+4 3.32707E+4 3.36201E+4 3.39731E+4 3.43298E+4 3.46902E+4 3.50544E+4 3.54225E+4 3.57944E+4 3.61702E+4 3.65500E+4 3.69338E"'4 3.73215E+4 3.77134E+4 3.81094E+4 3.85095E+4 3.89138E+4 3.93224E+4 3.97353E+4 4.01525E"'4 4.05740E+4 4.10001E+4 RI ERe 7515Integral [%]

1.93210E+1 9.75984E+1 1.87572E+1 9.76805E+1 1.82988E+1 9.77606E+1 1.78717E+1 9.78389E+1 1.70709E+1 9.79137E+1 1.70593E+1 9.79884E+1 1.64902E+1 9.80607E+1 1_59932E+1 9.81308E+1 1.53400E+1 9.81981E+1 1.49373E+1 9.82636E+1 1.46947E+1 9.83281 E+1 1.43453E+1 9.83910E+1 1.40012E+ 1 9.84525E+1 1.36936E+1 9.85127E+1 1.29716E+1 9.85697E+1 1.27212E+1 9.86256E+1 1.23683E+1 9.86800E+1 1.19038E+1 9.87324E+1 1.15363E+1 9.87832E+1 1.10983E+1 9.88321E+1 1.05617E+1 9.88786E+1 1.02316E+1 9.89238E+1 1.00620E+1 9.89682E+1 9.75611 E+O 9.90113E+1 9.34239E+0 9.90525E+1 9.08357E+0 9.90927E+1 8.63073E+0 9.91309E+1 8.62149E+0 9.91691E+1 8.01776E+0 9.92046E+1 7.76954E+0 9.92391E+1 7.S7887E+0 9.92727E+1 7.11016E+0 9.93043E+1 6.76072E+O 9.93344E+1 6.73795E+0 9.93644E+1 6.39992E+O 9.9.3929E+1 6.07528E+O 9.94200E+1 5.95889E+0 9.94467E+1 5.63739E+0 9.94719E+1 S.39434E+0 9.94960E+1 5_16840E+0 9_95192E+1 5.00823E+0 9.95417E+1 4.85094E

...

0 9.95635E+1 4.66405E+0 9.95845E+1 4.53065E+0 9.96050E+1 4.31140E+0 9.96244E+1 4.08654E+O 9.96429E+1 3.86833E+0 9.9660SE+1 3.56277E+0 9.96767E+1 3.37791 E+O 9.96922E+1 3.44210E+0 9.97079E+ 1 3.40291E+O 9.97234E+1 2.99522E+O 9.97372E+1 2.737321:+0 9.974981:+1 2.95715E+O 9.97634E+1 2.85140E+O 9.97766E+1 2.74667E+0 9.97893E+1 2.71603E+O 9.98018E+1 2.47187E+0 9.98133E+1 2.26997E+O 9.98239E+1 2'34835E+O 9.98349E+1 2.31945E+0 9.98457E+1 2.10855E+0 9.98557E+1 1.89825E+0 9.98647E+1 1.n44BE+0 9.98732E+1 1.89257E+0 9.98822E+1 1_87SnE+0 9.98911 E+1 1.707351:+0 9.989931:+1 1.60029E+0 9.99070E+1 1.52397E+0 9.99144E+1 1.73877E+O 9.99227E+1 1.~572E+0 9.99298E+1 1.31033E+O 9.99363E+1 1.27405E+O 9.99426E+1 1.12659E+0 9.99482E+1 9.47351 E-1 9.99531 E+1 1.05441E+O 9.99585E+1 

# 'I1l 00246 

# z>. 07).. .,A1

# 7e.

# Competence Center Analytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company


## Page 28of32

Molmasse
533 4.14305E+4 534 4.18655E+4 535 4.23051E+4 536 4.27493E+4 537 4.31981E+4 538 4.36517E+4 539 4.41100E+4 540 4.45731E+4 541 4.50411E+4 542 4.55140E+4 543 4.59919E+4 544 4.64748E+4 545 4.69628E+4 546 4.74558E+4 547 4.79541E+4 548 4.84576E+4 549 4.89664E+4 

### 550 4.94805E+4



# o

o RI ERe 7515Integral [%]
1.16120E+0 9.99643E+1 9.51855E-1 9.99692E+1 9.23260E-1 9.99740E+1 8.55602E-1 9.99785E+1 7.013751:-1 9.99823E+1 6.04840E-1 9.99857E+l 6.73801E-1 9.99894E+1 5.l05S0E-1 9.99921E+1 4.7370SE-1 9.9995SE"'1 4.59540E-l 9.99983E+l 3.91197E-l 1.00000E+2 2.91929E-1 1.00000E+2 2.27932E-1 1.00000E+2 2.29551E-l 1.000ooE+2 2.31165E-1 1.000OOE+2 2.32773E-1 1.00000E"2 7.3793SE-2 1.00000E+2 1.94283E-1 1.00000E+2 

# Eiv4 '11 L

# 00246

2.)-

_

# D-;./I?~

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 29 of32

Content of residual monomer of n-butyl acrylate byGC

Test item

o 5 10 15 3J RIE*rialIiITB



# Test itemwith reference material

11

# I

o 5 10 15

## Competence Center Analytics

Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) 

# a·BASF

The Chemical Company


## Page 30of32

Content of residual monomer of iso-butyl methacrylate and perfluorohexylethyl methacrylate by 

# GC

Test item

., 1Q 

# .,

Test item with reference material 

# i I

....


# .5

o 5 10 15

RNulla Sum"""" for EFKA-3ISOONVlflflttwt OOA d fBmIIe B.

### 'nlfddlon 11 25



# I 

# t

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 31 of32

Acrylic acid or methacrylic acid by HPLC

Test item



# o 2 4

Reference materials



# o 2 4

## Competence Center Analytics 

# a·BASF

The Chemical Company



## Final Report Characterization of "EFKA-3600N without DOA" Study No. 11L00371 (confidential) Page 32

# of32