# Patent

## Title
Disposable wipers and towels containing 100% recycled fibers

## Abstract

A high utility (strong in both dry and wet states, highly absorbent, abrasion resistant, thick, and soft) disposable wiper or towel that contains 85% or more recycled fibers and, in one construction, 100% recycled fibers. The recycled fibers are from post-consumer waste and/or post-industrial waste. The base sheet is produced in a wet-pressed, creped process and is post-treated using a DRC process. The final wiper or towel is a double re-creped, non-woven sheet having a first side and a second side. The non-woven sheet includes about 85% to about 90% by weight of cellulose fibers. The non-woven sheet includes at least about 10% to about 15% by weight of binder.

## Background
BACKGROUND
The present invention relates to non-woven towels or wipers. More particularly, embodiments of the invention relate to a disposable wiper or towel (and methods of making the same) that is made from 100% recycled fibers. More particularly, embodiments of the invention relate to such items that are made from 100% recycled fibers obtained from post-consumer waste (“PCW”) and/or post-industrial waste (“PIW”).
Paper towels, wipers, and similar items made from non-woven materials or fabrics can be manufactured in a variety of ways. In the past, many such items were made entirely from virgin materials. In other words, the products were made from fibers (e.g., cellulose) derived directly from the fiber source (e.g., trees) and not with fibers that had been previously used in a product. More recently, at least some paper towels and similar items have been made with some recycled fibers. Today, there is a drive to utilize recycled fiber in more demanding applications, and at a greater percentage from PCW. The use of recycled fibers is believed to both reduce energy consumption and preserve the source (e.g., forests) of the fibers used in such products.
SUMMARY
A variety of efforts, including efforts by the inventors and the assignee, have been made to produce high-utility disposable wipers that are made from recycled fibers, including efforts to produce products with as much as about 80% recycled fibers. Generally, efforts were made to maximize the amount of recycled fibers. Yet despite these efforts, the inventors found that, in many instances, the products produced with more than 80% recycled fibers and certainly with 100% recycled fibers either could not be produced or were significantly inferior, in one or more ways, to products made with significant amounts of virgin fibers. In fact, a high utility wiping product made from 100% PCW and/or PIW that exhibits desirable characteristics and meet the requirements (e.g., performance and cost) for commercial success has been viewed as unachievable. As a consequence, there remains a need to create products with all or nearly all recycled fibers that exhibit performance that is, at least, comparable to products that are made from virgin fibers.
Although indications pointed to the impossibility of creating a product with 100% recycled fibers, the inventors surprisingly found that it is nonetheless possible to create such a product using a double recreping (“DRC”) process by using the techniques describe herein.
In one embodiment of the invention, a high-utility, high-performance (at least in relative terms) disposable wiper or towel (towels are usually lighter weight, low-strength wipers) is made with recycled fibers derived from PCW and/or PIW. The product exhibits performance characteristics that are similar to currently-available, high-utility wipers and disposable towels made with 100% virgin fibers, including wipers and towels that are made with a double-recreping process, such as the process disclosed in U.S. Pat. No. 3,879,257.
In one embodiment, the invention provides a wiper or towel that is made predominantly of cellulose fiber (85% to 90% of the wiper by weight). 100% of the cellulose fiber is derived from recycled fiber which is entirely or a blend of bleached, semi-bleached, or unbleached PCW and/or PIW. The fiber is formed into a web and a bonding material is applied to each side of the web (10% to 15% of the wiper by weight). The result is a disposable wiper that has high utility (strong in both dry and wet states, highly absorbent, abrasion resistant, thick, and soft) and that can meet or exceed EPA guidelines related to the level of PCW in wipers. In other embodiments, the wiper is made from less than 100% recycled fibers but more than 85% recycled fibers.
One difficulty at least partially overcome by embodiments of the invention relates to the use of recycled fiber derived from PCW. In general, fibers derived from PCW are highly variable, both in physical and in chemical properties, due to the varied sources, paper grades, and prior uses of the base material. To date, this variability has limited the use of PCW recycled fiber in high-utility, disposable wipers.
The inventors have discovered a method that enhances both a base-paper process (wet-pressed, creped paper making process) and a post-treatment process (a double recreping (“DRC”) process) which allows the highly-variable bleached, semi-bleached, and unbleached PCW and/or PIW fiber to be incorporated at levels of up to 100% of the cellulose content of the wiper. These improvements allow the manufacturing of an array of high-utility wipers and towels that meet EPA guidelines. In general, a wiper or towel produced by embodiments of the invention exhibits both wet and dry strength, has good instantaneous and total liquid (water, oil, solvent) absorbency, abrasion resistance when wiping surfaces, and tactile properties comparable to those of cloth and currently-existing, high-utility, cellulose-based wipers.
In one embodiment, the invention provides a method of making a disposable wiper or towel. The method includes creating a slurry of recycled cellulose fibers, including fibers from post-consumer waste. The slurry blend contains at least 85% recycled fibers and can contain up to 100% recycled cellulose fibers. A contaminant deactivator and a debonder are added to the mixture. The slurry is formed into a web and the web is dried and creped into a base sheet. The base sheet is fed to a first printer. A binder is applied to a first side of the base sheet with the first printer. The binder has a viscosity of about 10 to about 80 centipoise (cps). To achieve this viscosity, a thickener is added to the binder. The result is a binder that has at least about 31% to 35% binder solids. The binder is pressed into the base sheet. The base sheet is then re-creped, dried, and fed to a second printer. The method then includes applying a binder to a second side of the base sheet with the second printer, pressing the binder into the base sheet; re-creping the base sheet a second time; and drying the base sheet a second time. The now double re-creped sheet is heated in a curing oven to cure the binder. The base sheet is cooled and may be wound into rolls or converted to desirable sizes and configurations.
Other aspects of the invention will become apparent by consideration of the detailed description and accompanying drawings.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic illustration of a first part of a manufacturing line designed to produce a base sheet or paper that is made with 100% recycled fibers.
FIG. 2 is a schematic illustration of a second part of a manufacturing line designed to produce a base sheet that is made with 100% recycled fibers.
FIG. 3 is a schematic illustration of a manufacturing line in which the base sheet produced on the manufacturing line illustrated in FIGS. 1 and 2 is printed and re-creped and then wound on a roll.
FIG. 4 is a schematic illustration of the sheet structure of a double-recreped 100% recycled fiber content wiper.
FIG. 5 is an illustration of a towel made from the material produced as a result of the processes carried out in the manufacturing lines of FIGS. 1, 2, and 3.
FIG. 6 is an illustration of a quarter-folded product made from the material produced as a result of the processes carried out in the manufacturing lines of FIGS. 1, 2, and 3.
FIG. 7A is an illustration of a stack of quarter-folded products.
FIG. 7B is an illustration of the stack of quarter-folded products from a different point of view.



DETAILED DESCRIPTION
Before any embodiments of the invention are explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the following drawings. The invention is capable of other embodiments and of being practiced or of being carried out in various ways. The product produced can also be used for other purposes than towels and wipers—e.g., as construction medium for the production of wet wipes; absorbent bed sheets; filtration medium; sound and heat insulating medium; limited-reuse, low-cost clothing; and/or environmental protection garments.
As noted above, producing a towel or wiper of the present invention involves at least two major steps. First, a base sheet is produced. Second, the base sheet is printed, double re-creped, and wound on a roll. Of course, once a roll of double re-creped material is formed, further processes may be carried out (e.g., “converting”) in which the material is, for example, cut, slit, perforated, and wound on smaller rolls suitable for sale to consumers (such as in a form that resembles rolls of paper towels commercially available in retail stores), folded into packs (such as in a form that resembles packs of napkins), or combined with other substrates (scrim, particle board, etc.) to form even higher value products. It can also be sold in roll form to converters as a construction material for use in applications as listed above.
FIG. 1 illustrates part of a paper machine or base-sheet manufacturing line 10 in which a fibrous web containing 85% to 100% of bleached, semi-bleached, or unbleached PCW and/or PIW (having a basis weight of about 25 to about 55 pounds per ream of 3000 square feet) is formed from an aqueous slurry of fibers. The fibrous web is formed under conditions where inter-fiber bonding is reduced by 40% to 70% as compared to paper webs of similar weight produced in a conventional manner. A wet-pressed, creped, paper machine process is carried out in the paper machine line 10.
The paper machine line 10 (shown schematically) includes a blend chest 12. To create an embodiment of a wiper made completely from recycled fibers, a 100% recycled fiber slurry, or a 100% blend of recycled fiber slurries is added to the chest 12 from a fiber proportioning apparatus 13. Slightly less than 100% recycled fiber can be used, although the highest percentage of recycled fiber will generally be desired. In such cases, a slurry or blend of slurries of 85% or more recycled fiber is added to the blend chest 12 with the remainder of the fiber comprised of virgin fiber. The slurry in the blend chest is controlled so that the slurry contains approximately 3% fiber (i.e., the total fiber from the recycled fiber slurry or recycled-and-virgin fiber slurry) and 97% water. It also possible to provide dry fiber to the chest and mix it with water there. Regardless of the exact manner in which the ingredients are delivered to the blend chest 12, the ultimate goal is to create a slurry that contains a desired fiber-to-water ratio, such as the 3% fiber to 97% water ratio mentioned above. In at least some embodiments, bleached, semi-bleached, or unbleached recycled fiber with high levels of PCW content is blended with other recycled fibers, so that the fiber content of the slurry is 100% recycled fiber.
The slurry in the blend chest 12 is pumped by a pump 14 to a machine chest 16. Talc, or other commercially available contaminant control agent, at the addition rate of about 5 to about 25 pounds/tons of fiber, is added to the slurry as it exits the blend chest 12 (if needed, particularly for low-quality recycled fiber). The talc acts as a contaminant neutralizer or deactivator and helps to capture and deactivate contaminants that are present on or with the fibers of the PCW. The slurry is pumped from the machine chest 16 to a silo 18 by a pump 20. A refiner (or deflaker) 19 can be run or bypassed depending on the characteristics of the blended slurry and the desired end product. Debonder is added to the slurry as it exits the machine chest 16. The debonder may be one of a number of commercially available debonders available from a number of sources. It is added at rates of about 10 to about 30 pounds/ton of fiber (0.5% to 1.5%). This helps to reduce the level of hydrogen bonds formed as water is removed from the dilute slurry and the cellulose fibers come into intimate contact with one another in the paper making process. The silo receives recirculated water from downstream processes. The slurry in the silo includes about 0.2% fiber and about 99.8% water and is used to dilute the blended stock to the 0.5% fiber and 99.5% water desired for forming the sheet.
Blended stock from the refiners is mixed in line with slurry from the silo 18 and pumped by a fan pump 21 to a headbox 22 (FIG. 2) of a twin wire former 24. In other embodiments of the invention, other commercially available formers can be used in lieu of the twin wire former 24. The former 24 produces a fibrous web or sheet 26. The sheet 26 is formed so that uniform distribution of the PCW within the sheet is achieved and so that both sheet surfaces are nearly equivalent. Additional steps—minimized chest retention, no or minimal refining, and controlled fines recapture and reuse—are taken to minimize hydration (a process that increases hydrogen bonding) of the fiber between the blending and paper forming steps.
The formed sheet 26 is transferred to a press section 27. A felt/pressure roll configuration is used in the embodiment shown and the sheet 26 is pressed against a Yankee dryer 28. In order to limit the creation of hydrogen bonds (some of which are created despite the addition of debonder) and to avoid bulk (thickness) reduction, pressure roll loading (in the felt/pressure roll configuration) is reduced to relatively low levels (about 300 to 350 pounds per linear inch (“PLI”)). The sheet 26 adheres to the surface of the Yankee dryer 28. As noted earlier, debonder is added to the slurry to reduce the formation of hydrogen bonds. The amount of debonder is greater than that used in at least several other paper making processes. The relatively high level of debonder makes it difficult to control the sheet 26 on the Yankee dryer 28 and to consistently crepe the sheet 26 with a creping blade or doctor 29. To help achieve positive control of the sheet 26, sheet moisture content is controlled and chemicals are sprayed on the Yankee dryer 28 to properly adhere the sheet 26 to the dryer and then crepe it with the creping doctor 29. Adhesives and release modifiers (chemicals) for Yankee dryers are known in the paper making industry and commercially available from a number of sources. In one embodiment, addition of an adhesion chemical or adhesive is controlled to 2.2 mg/m2 of Yankee dryer surface (+/−) 0.7 mg/m2 depending on sheet basis weight. Addition of the release modifier or release chemical helps ensure constant crepe generation and is controlled, in one embodiment, to 10.0 mg/m2 of Yankee dryer surface+/−2.0 mg/M2. Sheet dryness is controlled to less than about 80% to further inhibit inter-fiber bond formation due to drying. After the sheet 26 is creped, it is transferred to an after-dryer section 30 (or, more simply, an after dryer) having multiple steam-heated dryers 32.
As a result of the efforts to reduce inter-fiber bonding, the sheet 26 is relatively weak. In order to transport the sheet through the after-dryer section 30 without disrupting or damaging it, a double-felted, after-drying configuration is used. The sheet 26 is physically restrained in a sandwich between the two dryer fabrics (not shown) and transported through the after-drying section 30. This enables the process to operate with minimum sheet defects and sheet breaks. This, in turn, allows commercial paper machine efficiency to be achieved. Other modes of sheet after-drying providing positive sheet control can also be employed to remove water from the web.
Once dried to a level of about 96%+/−1%, the sheet 26 is fed to a reel 38 where the sheet is wound to form one or more rolls 40. At this stage in the process, the sheet is considered to be a base paper ready for post treatment and is labeled with reference numeral 42. Thus, the roll 40 can be referred to as a roll of base paper. In one embodiment, the reel 38 is configured so that the relative speed between the reel 38 and the after-dryer section 30 is +0.7%+/−0.1%. The loading between the reel and the base paper roll 40 is maintained at a low nip loading (0.5 to 2 PLI). When the reel is so operated, compaction and bulk reduction of the base paper 42 is reduced. As a result of the process described above with respect to the line 10, it is possible to create a cellulose web (i.e., the base paper 42) with 40% or more PCW and a total recycled fiber content of 85% to 100% in a basis weight range of 20 pounds to 50 pounds per ream and with the characteristics set forth in Table 1.







TABLE 1







Base Sheet








Property
Base Sheet/Base Paper





Basis Weight (pounds/3000 sq. ft.)
20 to 50


Thickness (mils/ply)
4 to 9


Machine Direction Tensile Strength (gm./in.)
 500 to 1200


Cross Direction Tensile Strength (gm./in.)
300 to 900


Web Dryness (%)
95% to 97%









When the base paper 42 is manufactured as outlined, tensile strength is reduced by 40% to 70%, and web thickness is increased by 20% to 40% (as compared to paper webs of similar weight produced in a conventional manner). The improved bulk creates a bulk-to-basis weight ratio of 1.5 to 1.8 (mils per 8 ply/pounds per ream). These properties and the methods in which they are achieved make the base paper 42 (with 40% or more PCW) and up to 100% total recycled fiber content suitable for post treatment in a DRC process.
FIG. 3 illustrates a manufacturing line 50 in which the base paper 42 is re-creped. A roll (such as the roll 40) of base paper is unwound so that the base paper 42 is fed to a printer 52 having two rollers or rolls: an impression roll 54 and a fine pattern engraved roll 56. A binder emulsion is applied or printed on a first side of the base paper 42 using the fine pattern engraved roll 56. The pattern covers 25% to 50% of the surface area of the first side of the base paper 42 with a binder that penetrates into 30% to 60% of the sheet thickness. This level of penetration range ensures sheet integrity so that the web does not split apart (referred to as delamination) when in finished-product form. However, proper printing of the binder emulsion on the base paper 42 is difficult (as compared to printing on a base sheet of virgin fiber) due to the presence of relatively short, compacted, and variable fibers having variable levels of water resistance or repellency present in the PCW used to make the base paper. To help achieve a desired range of binder penetration, the viscosity of the binder emulsion is adjusted to a level of about 10 to 80 cps. To achieve this viscosity level, a low-viscosity binder (such as styrene butadiene rubber, acrylic or vinyl acetate homopolymer, or ethylene vinyl acetate copolymer having an as received viscosity of 100 cps or less when measured by a Brookfield viscometer) is used. Solids in the binder emulsion are adjusted to a range of about 31% to 35% to achieve a final desired viscosity (i.e., the 10 to 80 cps mentioned above).
In addition to adjusting the viscosity of the binder emulsion, to further assist achieving proper binder penetration, the binder is pressed (using an automatically variable pressure control system) into the base paper 42 by the impression roll 54. The level of pressing is automatically adjusted over a range of about 30 to 65 PLI based on the thickness of the web as it is wound at the end of the process. If the measured thickness is above a target setting, the pressing is automatically increased. If the measured thickness is below the target setting, the pressing is automatically decreased.
After the first side of the base paper 42 is printed with binder by the printer 52, the base paper 42 is pressed onto a creping dryer 60 by a press roll 62. The sheet is dried to a 93% to 96% dryness level and re-creped by a crepe doctor 63. The loading of the crepe doctor is set in a range or about 15 to 40 PLI. The surface temperature of the creping dryer is controlled in a range of about 180° F. to about 230° F. The action of the creping blade on the base paper 42 as it is “creped” from the dryer loosens and breaks apart many of the weak hydrogen bonds in a central area 65 of the sheet 42 (see FIG. 4). However, fibers that are encapsulated with bonding material are not affected by the creping action. This causes many of the fibers in the central region 65 of the web to be oriented in the z direction. In addition, it creates voids 67 in the central area of the web. The resultant internal web structure enhances bulk (thickness), softness, and substantially increases liquid absorbing capacity.
After the first side of the base paper 42 is printed, dried, and creped the other side of the sheet is printed with a binder emulsion, dried, and creped in the same manner. Thus, the manufacturing line 50 includes a second printer 68 having two rollers or rolls: an impression roll 70 and a fine pattern engraved roll 72. The manufacturing line also includes a second creping dryer 74 with a crepe doctor 75. As with the first side of the base paper 42, binder emulsion is applied to the second side of the sheet to achieve a penetration range of about 20% to 50% of the sheet thickness. The effect of printing both sides of the base paper 42 with this range of binder penetration (30% to 60% on the first side and 20% to 50% on the second side) is akin to “stapling” of the two sides of the sheet at fiber intersections and achieves a desired internal bonding strength of the finished sheet (as measured by z-peel strength). At the same time, the double re-creping of the base paper creates the loose internal web structure. The result (as shown in FIG. 5) is a web with high bonded fiber concentration on the surface (top surface 76 and bottom surface 77) which provides good wiping and abrasive characteristics and looser fibers 78 and voids 67 in the central region of the web which creates enhanced bulk, softness, and absorbency characteristics. The “stapling” effect of the binder penetration ensures sufficient bonding in the center of the web to achieve the desired resistance to delamination (as measured by z-peel strength) to maintain sheet integrity in use.
Referring back to FIG. 3, after the second side of the base paper 42 is printed, dried, and re-creped, the base paper 42 is fed to a cure oven 80. The base paper 42 is heated to a temperature of about 300° F. to about 370° F. in the cure oven 80 to cure the binder to greater than 85% of its maximum potential. Curing causes the polymer chains of the binder to bond (crosslink), making the binder water resistant. Curing also ensures that desired levels of dry and wet strength of the base paper 42 are achieved. As the binder on the base paper is cured to greater that 85% of its maximum potential, the resultant ratio of wet strength to dry strength of 40% to 65% is achieved. This provides for superior strength when wet and high utility for wiping and cleaning tasks. After curing, the sheet is cooled to a temperature of less than about 95° F. at a cooling station 85 and wound with a reel 90 into a roll 94. The roll 94 of the base paper 42 may be moved or shipped to a converting line so that the sheet may be formed into end products of desired sizes and configurations, such as roll towels or wipers and folded towels or wipers.
FIG. 5 illustrates a towel or wiper 100 that is produced by converting the roll 94 of base paper 42 into a desired end product, which as shown in FIG. 5 is a roll 102 of towels with perforations between each towel. FIG. 6 illustrates another product that can be produced, namely a quarter-folded towel or wiper 102. A stack 104 of such wipers is shown in FIGS. 7A and 7B from two different perspectives. Using the processes described above, examples of wipers with the characteristics set forth in Table 2 were created.







TABLE 2







Sample 100% Recycled Fiber Content Wiper










Property
34.5# Wiper














Basis Weight (pounds/ream)
34.5



Bulk (mils)
14-16



MD Tensile (grams/inch)
 700-1000



MD Stretch (%)
20%-30%



CD Tensile (grams/inch)
500-700



CD Wet Tensile (grams/inch)
300-400



Wet Tensile/Dry Tensile
60%



LAC (Liquid Absorptive Capacity %)
450



Z-peel (delamination grams/inch))
>35



Cellulose Content:



Recycled (PIW)
60%



Recycled (PCW)
40%










Note that the example set forth in Table 2 has an amount of recycled fibers of 100% (40% PCW and 60% PIW).

Table 3 sets out characteristics of high-performance or high-utility wipers or towels made from a base sheet composed of virgin or nearly all virgin fibers.







TABLE 3







Sample High-Utility Towels with Little or No PCW and/or PIW










Property
KC L-30














Basis Weight (pounds/ream)
35.1



Bulk (mils)
19.5



MD Tensile (grams/inch)
1050



MD Stretch (%)
23.0



CD Tensile (grams/inch)
775



CD Wet Tensile (grams/inch)
460



Wet Tensile/Dry Tensile
59%



LAC (Liquid Absorptive Capacity %)
620



Z-peel (delamination grams/inch))
85










As can be seen by a comparison of Tables 2 and 3, embodiments of the invention provide, among other things, a towel or wiper containing 100% recycled fibers with characteristics that are comparable to wipers that do not include significant levels of PCW and/or PIW. Various features and advantages of the invention are set forth in the following claims.

## Claims

1. A disposable wiper or towel comprising:
a wet-pressed, creped and double re-creped non-woven sheet having a first surface and a second surface opposite of the first surface, the non-woven sheet including about 85% to about 90% by weight of cellulose fibers, the cellulose fibers including 85% or more recycled cellulose fibers, the non-woven sheet including at least about 10% to about 15% by weight of binder.

2. The disposable wiper or towel as in claim 1, where the sheet has a thickness and wherein the binder penetrates into about 30% to about 60% of the sheet thickness from the first surface and penetrates into about 20% to about 50% of the sheet thickness from the second surface.

3. The disposable wiper or towel as in claim 1, wherein the wiper has a basis weight in a range of about 30 to about 50 pounds/ream.

4. The disposable wiper or towel as in claim 1, wherein the wiper has a liquid absorptive capacity of about 400% to about 600%.

5. The disposable wiper or towel as in claim 1, wherein the wiper has a bulk in the range of about 14 to about 24 (mils/ply).

6. The disposable wiper or towel as in claim 1, wherein the wiper has a ratio of wet tensile to dry tensile strength of about 40% to about 65%.

7. The disposable wiper or towel as in claim 1, wherein the binder is selected from the group of styrene butadiene rubber, acrylic or vinyl acetate homopolymer, and copolymer latex.

8. The disposable wiper or towel comprising:
a wet-pressed, creped and double re-creped non-woven sheet having a first surface and a second surface, the non-woven sheet including about 85% to about 90% by weight of cellulose fibers, the cellulose fibers including about 100% recycled cellulose fibers, the non-woven sheet including at least about 10% to about 15% by weight of binder.

9. The disposable wiper or towel as in claim 8, where the sheet has a thickness and wherein the binder penetrates into about 40% to about 50% of the sheet thickness from the first surface and penetrates into about 40% to about 50% of the sheet thickness from the second surface.

10. The disposable wiper or towel as in claim 8, wherein the wiper has a basis weight in a range of about 30 to about 50 pounds/ream.

11. The disposable wiper or towel as in claim 8, wherein the wiper has a liquid absorptive capacity of about 400% to about 600%.

12. The disposable wiper or towel as in claim 8, wherein the wiper has a bulk in the range of about 13 to about 24 (mils/ply).

13. The disposable wiper or towel as in claim 8, wherein the wiper has a ratio of wet tensile to dry tensile strength of about 40% to about 65%.

14. The disposable wiper or towel as in claim 8, wherein the binder is selected from the group of styrene butadiene rubber, acrylic or vinyl acetate homopolymer, or ethylene vinyl acetate copolymer.