Envisage Environmental Incorporated 

September I. 1999 

Ms. Jane Bell 

Agency Representative 

Cleveland Department of Environment 

Department of Health and Welfare 

City or Cleveland 

1925 51. Clair Ave. 

Cleveland, Ohio 44114 

~c 0 9 1999 

f -, ,I; . u, •• ,,;,''; c ',- I\l;~ POLLUTjj~I\J COi:i,. 

Rc: Submission Ohio E PA Int cnt to Test Not ifi cation Pilch! 

Oi:lIllolld Ha rd Chl"o mc Inc. 

611 0 Grand Avenue 

Clevela nd, O hio 44 104 

Dear Ms. Bel!: 

Enclosed for your review is a completed Ohi u EPA In tent To Test Notilication 

Packet for Din lllond I-lard Chrome J nc. 

The purpose of this notification is the desire to demonstrate compliance \0 an Ohio 

EPA PTI for an increase in plating power for Plating Tank No.7. Plating Tank No. 

7 has been modified to now being able 10 apply 9000 amps of electrical power to 

the plaling operation from a preexisting power capacity of 5000 amps. 

Additionally, the air pollution mcsh pad collector system for Plating Tank No.7 has 

been replaced with a larger more ef'ficient system. 

The proposed testi ng program will follow the current MACT standards for Chrome 

plating system by employing USEPA Method 306 sampli ng procedures, as 

stipulated in the I1T packet. Two exceptions to the standard sampling procedures 

are proposed. Both of these modifications wcre incorporated into the last testing 

program conducted on this system. June 18. 1997, and were acceptable to local, 

state and federal agencies. Because orthe spatiallimiialions of the exhaust 

ductwork exiling the 1.0. fan system. Method I and Method 2 specifications were 

not mel and modifications were incorporated to compensate for these method 

deficiencies. These modification were; I) Mcthod I distances were not available 

and straightening vanes were added to tbe ductwork. 2) For Method 2, thc 

innermost sample point for each sample pan could not be physically reached with 

the sampling probe assembl y. Therefore the second point on each sample port was 

sampled for twice the time to compensate for this physica l constraint. We are 

proposing 10 sample in the same fashion for this proposed sampling program. 

P.O. 80ll 152 Richheld. Ohio 44286 Phon~ (440) 526·0990 Fall (440) 526·8555 
Ms. Bell 

9/1199 

page 2 of2 

Please review the attached ITT packet and feel free to call me with your comments 

and suggestions. 

I have not called for a pre-test meeting however we certainly are available if it is 

decided to have one. 

Sincerely, 

Envisage Envirorunental Inc. 

iZ:~ (1.""4<- )(;;;'~t/s. Anderson 

. President 

Attachment: 

cc: 

Ohio ITT Packet, Diamond Hard Chrome Inc. Method 306 

Mr. Robert Tankovich, Diamond Hard Chrome Inc. 

Envisage 

Environmental 

Incorporated 

P.o. Box 152 AJchh&.d. OhIO 44286 

Pno"" (440) 526.()9<J() 
INTENT TO TEST NOTIFICATION 

(One Emissions Unit Per Sheet) 

Agency Use Only Proposed Test Date: To be determined 

Date Received: ------------------------------------- Pre-Test Meeting Desired YesD NoD 

No. Assigned: SCC Code: 

Facility Premise Number: 

Company Name: DIAMOND HARD CHROME INC. Address: 6110 Grand Ave., Cleveland, Ohio 44104 

Contact Name: Mr. Robert Tankovich Telephone Number: 216-391-3618 

B. Testing Firm Information 

Name: Envisage Environmental Inc. Address: P.O. Box 152, Richfield, Ohio 44286 

Contact Name: Mr. Bryon Marusek, EIT Telephone Number: 440-526-0990 

----~----~--~--~-------------------- C. Test Plans and Emission Units Information Table: List the applicable information under each respective column heading. 

Emissions Control Monitoring Pollutant(s) to EPA Test Filter Box Number of Total Time for Number of 

Unit Equipment Equipment Be Tested Method(s) Temperature Sampling points Test Run Sampling Runs 

Chrome Plating Scrubber #3 Velocity Pressure Total Chrome 1,2,4,306 Ambient 25 120 3 

Tank #7 Gauges 

Source is testing to comply with (check all 

that apply) State PTI ~ State PTO D Title V D NSPS D MACT D BIF D Title IV D Other D 

D. What is the Maximum rated 

capacity? 

9000 amps plating power 

Will Emissions Unit be 0llerated at the maximum capacity given in its Permit·to·Iustall or Pennit.to-Opcratc? Yes ~No [ I If no, attach explanation 

Spcci~~w~~ratiqra~wm~.moo~~~~riq~~rS~n~~I~Md300~p~ p~ro~d=u~c~ti~o~n~r~e~c~o~r~d~s~ ______________________________________________________________ _ 

Any modifications to USEr'A Reference Mcthod(s) proposed? Y es ~ NOD If"no" is checked. then no modification. however minor, will ~ accepted 

If yes, explain proposed modificalion(s): due to physical restraints Method 1 and 2 will be modified as per testing of 6/18/97 

Snrnpling Location(s): Inlet D Outlet ~ SimullMcous D Will cyclonic now check(s) ~ conducled? Yes D No ~ Fuel Sampling: Coal - Proximate D Ultimate D If olher. specify: D 

Emission mles to be calculated using: F·Factor Proximate D Ultimale Coal At13lysis D Other ~ If other. specify: Test Results compared to regulations 

Arc concurrent Method 9 readings to be perfonned Yes No [0 

Does this test method require audit samples? Yes D No ~ 

E. Sample Train Calibration: All affected measuring and monitoring equipment should be calibrated within 60 days of the scheduled testing. Ohio EPA Form revised 3/98 
Intent To Test Notification 

General Notes on Chromium Sampling and Analysis 

The field emission sampling procedures used by Envisage Environmental, Incorporated, are presented in 

USEPA Reference Method 306, Determination of Chromium Emissions From Decorative and Hard Chromium 

Electroplating and Anodizing Operations. 

The chromium sampling train assembly may be found in the sampling train diagram. A brief description of its 

operation is presented below. 

Gas flow measurements will be conducted simultaneously with the chromium sampling so isokinetic rates can 

be maintained. The pitot system is zeroed and each leg is leak checked at greater than 3" H20 gage pressure 

for at least fifteen seconds. The average velocity pressure and temperature between the two runs will be used to 

calculate a chromium emission rate. The entire sampling train is vacuum leak checked from the nozzle opening 

at about (-)15" Hg gage pressure. The sample probe is positioned at the first sample point within the stack and 

sampling begins when the source reaches stability. 

Post-test run leak checks are performed as above with the sample train leak check conducted at the highest 

vacuum attained during the run and is held for one minute. 

Also incorporated into the field sampling and data analysis are those considerations and calculations contained 

in the following: 

1) Construction Details of Isokinetic Source Sampling Equipment, USEPA Doc. APTD - 0581, April 1971. 

2) Maintenance, Calibration, and Operations of Isokinetic Source Sampling Equipment, USEPA Doc. 

APTO - 0576, March 1972. 

3) "A Method of Interpreting Stack Sampling Data," by W.S. Smith et ai, June 14 - 19,1970. 

Laboratory analyses which are fol/owed by Envisage Environmental are those procedures stated in USEPA 

Reference Method 306A, Determination of Chromium Emissions From Decorative and Hard Chromium 

Electroplating and Anodizing Operations, with associated calculations presented therein. Envisage 

Environmental Inc. also uses the on-site sampling procedures and sample analysis quality control and quality 

assurance requirements as published in USEPA Document 600/4-77/027b June 1987, Volume III, Part A and 8; 

Quality Assurance Handbook for Pollution Measurement Systems: Volume III. Stationary Source Specific 

Methods. 

t ,1.,11 ..... .. ;""I'_J-·,; 

" 1"':'-" ,}·'C,i,;_,I_i.,',· . .. ,,"':. I - - - - -' ' .' ' .. :! \. 

Envisage 

Environmental 

Incorporated 

p.o. Box 152 Richfield, Ohio 44286 

Phone (440) 526-0990 
Intent To Test Notification 

Chromium 

I F. Sampling Train Information 

Please refer to Sampling Train Diagram for schematic of proposed chromium sampling train. (Attachments No. 

1) 

Sampling for chromium emissions will be performed using the USEPA Method 5 sample train (excluding filter) 

in place of the Mason Jar method. The sampling train is assembled as follows: Method 5 probe and impingers. 

The four impingers contain in order· 100 ml. of 0.1 N NaOH, 100 ml. of 0.1 N NaOH, empty, and 200 g. of silica 

gel. Glass probe liners will be used. The probe will be modified by installing a calibrated "type K" therniocouple 

for probe exit temperature measurement. This modification will not alter the heater construction design as 

specified in APTD-0581. 

The on-site sample recovery is carried out as follows: 

After the post test sample train leak checks have been performed, the probe assembly is disconnected from the 

sample train and rinsed and recovered with the absorbing solution. The probe is considered clean and may be 

reused for the next sampling run. 

After the leak check operations the impingers are removed from the sample train, wiped clean from sealing 

grease, and stored in their labeled and recorded sample case. 

Envisage 

Environmental 

Incorporated 

p.o. eo. 152 RlChlteid. Ohio 44286 

Phone (4401 526-0990 
Sampling Train Diagram 

I 

~ ~ -1'1111'1 ~&'~~~ ;;x n < < :. ..... 0-.-- :?~ .... en ~ 'DOl» 

:1: 0 ~ca 

~ &;3 tD 

.. tD tD~ Q. .. 

DI 

-

PERAnJRE SENSOR IMPINGER TRAIN 

;d .j.PR08E 

~E S PITOTlVBE 

GLASS 

NOZZLE 

TEMPERATURE 

SENSOR 

FILTER OMlllED 

\,~~ " IjdJ 

n 

PITOT MANOMETER 

100 mIO.1N 100mlO.1N empty 

NaOH Naot-I (modl1lod 1 

(modll\ed 1110 Up) (standard Up) no lip) 

ORIFICE 

-I 

DRY GAS METER 

U.S.EPA Method 306 - Isokinetic Sampling Train 

TEMPERATURE 

SENSOR 

1 

a111ca gel 

200·3OOg. 

(modlllod 1110 lip) 
Attachment #3 

Centrol Unit (Molor Boxl 

~E~.,saqo Envltonmenl3t Inc 

_Ar.aotsen SampietS 

RcmanufadUfod RAC 

=O~Pcnt ConSlanI Flow Pumps 

Con Slant Motlitcnng Syslems 

VIG Flame le",,!8tlon OelOCIot 

Thermo EnY~Cnm8ntal Chamllumltleseence NO, NO:, NO, 

Sam~le Box 

A.-EEI 

_Rsmanufactutod RAC 

_EEl Spoclal Oesign 

Tentative Equipment Specifications 

Impln~ets • pet sample Ita", (each S81 changod ler each test tUnl 

.lLEEt 

..LEEt 

Samele Ptobe LitletS 

Tem~etatutO Sen SOtS 

_Omega Englnoellng 

L Type K Thermocouples 

.lLFlukO 51 

F.shet SCientific 

=Fosn8t SCIOntlfic 

Ptessuro Gaugos 

L Inclone Manomolet 

_ Ma<;nholoc 

_ Ma<;nhehc 

"U- Tube Manomet8t 

·tt" Tube Monemote, 

MICI'019dOt 

E:ectromanomoler 

Chemicals & Roagents 

.lLWator 

~ AcoloftIJ 

A.-Solica Gel 

..L Vacuum G,ea50 

_N.tncAc,d 

_S~lluticACId 

_Isopropyl Alecno. 

_Hydrogen POfOXlc19 

__ SOdium HydroXiCe 

length 

2 loot 

31cet 

51001 

7 fOOl 

10 loot 

12 loot 

16 loot 

24 loot 

ACS Gtade 

I.IB09·13 

MB IA. 2A 

MB 03·07 

SB01,02,&05·07 

SB 03 & 04 

SB 08 ·11 

J MOllified Smith Gteenburg 

t Smlll\ GreenbU'g 

Matenal 

SS~x. Quartz. Teflon 

SS te. :-Quartz. Teflon 

SS. . Quartz. Tallon 

SS. Pyrex. Quanz. Teflon 

SS. ext91r. Qualtt. Teflon 

SS. Pyrex. Quanz. Teflon 

SS. Pytex, Qualtt. Teflon 

SS. Pytex, Quanz. Taflon 

PYOI & 02 

PY09·14 

Metcury .n Glass 

Bimetlllhc 

001, O· 10 "H,O 

MagnetlClMechanlCaJ 0 • 1 "H:O 

MagnetlClMechanlCaJ 0 • 10 "H:O 

Metcury :!SWatet 72-

Watet O· 10 "H,O 

ElecttlC 001 .. 100 "H20 

O.,onlZod & OislJlled 

ACS Grade 

6· 16M9.n 

Acetone Insotuble & Heat ReSIstant 

ACS Gtado 

ACS Grade 

30'4 SOlution 

Envisage 

Environmental 

Incorporated 

PO 50x 152 R,cr-.l,e'rj ,::,0-.') ·~~i ":,,' 

Phone 1·1JC~ 526·0q()~j 
Intent To Test Notification 

Chromium 

G. Laboratory Analysis 

The protocol used for the laboratory analysis of the collected samples is as presented in US EPA Reference 

Method 306. The impinger liquid catch is measured volumetrically. The liquid contents are combined. The 

I solutions are combined with the probe rinse and sent to an independent laboratory for analysis by Method 306. 

The silica gel is measured gravimetrically and its weight difference from its tare is determined and recorded as 

I water vapor collected. The appropriate blanks from the test program are treated and recorded along with the 

above samples. 

Envisage 

Environmental 

Incorporated 

p.o. Box 152 Ricltfield. O~IO 44286 

Phone (440) 526-0990 
Intent To Test Notification 

H. Description of Operation 

Three chrome tanks use chromic acid to provide a finished product with a smooth working surface. The 

emiSsions from this source go through a mist eliminator at the outlet of each tank and then go through a chrome 

scrubber before exiting into the atmosphere. 

I. Stack and Vent Diagram 

See Attachment #2 diagram. 

J. Safety 

All standard safety procedures and precautions shall be followed. The following personal protection is 

recommended: 

I ~ I~ ~ X 1-

I~ 

I~ 

safety glasses with side shields 

chemical resistant goggles 

ear protection 

hard hat 

steel toed safety shoes 

long sleeved shirts 

flame retardant clothing 

respirator 

dusUparticle 

acid gas 

organic vapor 

SCBA 

Envisage 

Environmental 

Incorporated 

p.o. Bo. 152 Richfield. O~IO 44286 

Phone (440) 526·0990 
Process Diagram 

Chrome 

Tanle7 

Mezzanine 

Composite 

Mesh Pad 

Mist Ellminalrn 

~-----,~------~ 

Composite 

Mesh Pad 

Mist Enminator 

Straightening 

Vanes \ 

WaU 

I 

Sample Port 

Location 

Envisage 

Environmental 

Incorporated 

PO So. '~2 n ,.,;,~I'"j Or- -, ':.1;';;'-' 

Pt"1one I':'':C~ 526·0g.),) . 
Traverse Point I Port Location Diagram 

i 

00000 

-----r 

13.750' 

Q.534 Equivalent 

Diametl!l1l Upstream 

tram Disturbance 

(5) 3" 1.0. 

Sampling Porta 

6.750' 

2. 12 Equivalent 

Diameter. Downstream 

from Oisturoance 

J 

Pat 1 

Pat 2 

Pat 3 

Pat 4 

Pat 5 

~5"11 6.75" 

-.l 

22.5" 

~--- 30.125" ----I 

Point 

1 

2 

3 

4 

5 

~Fram 

" of Duct Dllpiltl Iftakie W-'IIIft.1 

10 

30 

50 

70 

90 

3.00' 

9.082" 

15.082" 

21.082" 

27.125" 

Envisage 

Environmental 

Incorporated 

po. Box 152 Richfield. Ohio .\.128~ 

Phone (440) 526·0990 
SOURCE 

EVALUATION 

RESULTS 

PREPARED BY 

Envisage 

,... Environmental 

Incorporated 

P.O. Box 152 Richfield, Ohio 44286 

Phone (440) 526-0990 
Envisage ICnvironmental Incorporated 

Novem ber 19, 1999 

Mr. Robert Tankovich 

Diamond Hard Chrome Inc. 

6110 Grand Avenue 

Cleveland, Ohio 44104 

Dear Mr. Tankovich 

The following report is the result of the emission evaluations performed on November 10, 

1999 at Diamond Hard Chrome Inc, Cleveland, Ohio. Testing was performed on the 

exhaust stack of the #3 Scrubber serving Chrome Plating Tank #7. The mass emission of 

total chromium was determined on the outlet gas stream to verify compliance with 

applicable Federal and State regulations in force at the time of testing. 

The results are true and accurate to the degree specified in the pertinent sections of the 

Code of Federal Regulations, in force at the time of testing. 

I look forward to answering any questions you may have and assisting you in the future. 

Respectfully submitted, 

U;7~NTALINC. 

Air 

DavidR. 

Quality 

Salem 

Services 

~ 

P.O. Box 152 Richfield, Ohio 44286 Phone (440) 526·0990 Fax (440) 526·8555 
TABLE OF CONTENTS 

INTRODUCTION 

DESCRIPTION OF PROGRAM 

TEST RESUL TS SUMMARY 

TEST RESULTS DETAILED 

OPERATIONAL PARAMETERS 

SAMPLE POINT LOCATION DIAGRAM 

SAMPLING TRAIN DIAGRAM 

LABORATORY SECTION 

FIELD DATA SHEETS 

CALIBRATION SECTION 

EMISSION SAMPLING NOMENCLATURE 

EMISSION SAMPLING CALCULATIONS 

PAGE NUMBER 

3 

5-6 

8 

10 

12 - 13 

15 

17 

19 - 21 

23 - 27 

29 - 30 

32 - 34 

36 

Envisage 

Environmenta I 

rC:C:777i7TF",,", Incorporated 
2 

INTRODUCTION 

Envisage , ".".~.. Environmental 

Incorporated 

p.o, BOl( 152 R'<;tlf~e:d. OhlO.4.42e6 

Pr~ooe {440} 516·0?J0 
3 

INTRODUCTION 

Envisage Environmental Incorporated conducted emission sampling at Diamond Hard Chrome Inc. Cleveland, 

Ohio on November 10, 1999. The objective of the test program was to measure the mass emission rates of total 

chrome emitted into the atmosphere from the exhaust of the #3 Scrubber. Emission sampling was conducted in 

triplicate on the source exhaust, with each of the test runs conducted over two (2) hour periods. 

Mr. Robert Tankovich (Diamond Hard Chrome) coordinated the test program and operational procedures. The 

Envisage testing team consisted of: Mr. David Salem, Mr. Andrew Brown and Mr. Chris Mcintosh. 

Ms. Jane Bell (The Cleveland Division of Air Pollution Control) was on site to witness the testing event. 

Envisage 

Environmental 

Incorporated 

P.O 80x 152 Richfield. Ohl!) 44286 

Ptlone (440) 526..0990 
DESCRIPTION OF PROGRAM 

4 

Envisage 

Environmental 

Incorporated 

P.O.ll<>x152 Riohfiold.Oh\o44286 

Ph"". (440) 52600990 
5 

SAMPLING AND ANALYTICAL PROCEDURES 

The sample collection and analysis techniques utilized for this test program were performed in accordance with 

the following USEPA Reference test methods: 

USEPA Method 1 

USEPA Method 2 

USEPA Method 4 

USEPA Method 306 

METHODS 1 

Sample and Velocity Traverses for Stationary Sources. 

Determination of Stack Gas Velocity and Volumetric Flow Rate. 

Determination of Moisture Content in Stack Gases. 

Determination of Particulate Emissions from Stationary Sources. 

The exhaust stack serving the #3 Scrubber has dimensions of 22.5 inches by 30.125 inches (an equivalent 

diameter of 25.76 inches). Five (5) sample test ports are located on the 22.5 inch plane, and have an upstream 

distance of 13.75 inches (.534 equivalent diameters). Because of the spatial limitations the downstream distance 

does not meet Method 1 requirements and straightening vanes were added to the ductwork. A total of twenty five 

(25) sample traverse points were used, five (5) per sample port. 

METHOD 2 

A three (3) foot "s" type pitot tube, and a Type K thermocouple were used for measuring the gas stream velocity 

and temperature. The pressure drops, temperatures and samples were measured by traversing across the 

internal diameter (30.13 inches) of the stack through the five sample ports. 

METHOD 4 

The moisture content of the gas stream was determined by USEPA Method 4, impinger procedure. The impinger 

procedure consists of an integrated gas stream sample which is drawn through a series of chilled impingers, filled 

in this instance, with Method 306 reagents and tarred dry silica gel, by means of calibrated dry gas meter. The 

net weight of liquid and water absorbed by the silica gel were recorded for the calculation of water content per 

sample volume. 

METHOD 306 

The chromium emissions exiting the exhaust stack were measured by following the procedures outlined in 

USEPA Method 306, "Determination of Chromium Emissions From Decorative and Hard Chromium 

Electroplating and Anodizing Operations". The sampling train consists of a pyrex nozzle connected to an 

unheated Pyrex liner. The liner was connected to a series of impingers (Method 4) which contained; 100ml of 0.1 

N NaOH in the first two, followed by an empty, and the final impinger containing the 200 grams of dry silica gel. 

Samples were taken from the gas stream isokinetically through the nozzle and sample train. Exit gas temperature 

of the impingers was maintained below 68°F. with an ice bath. At the conclusion of each test run the sample train 

Envisage 

Environmental 

Incorporated 

P.o, Box 152 R,ch1'eld', Ohio 44286 

Phone {440J 52&0990 
6 

was allowed to cool and a leak check of the train and pitot tube was performed. After the leak check the probe 

and nozzle cleaning was performed in the field using a carrier liquid of sodium hydroxide. The field cleaning of 

the sampling probe and nozzle follows this procedure; At the conclusion of the test run the nozzle is removed. 

the inside surface is rinsed until visually clean of particulate matter. The rinse is collected in a glass sample 

bottle and capped with a teflon lined lid. The sample probe is rinsed into the same container by tilting the probe 

assembly and rotating so that the rinse liquid empties into the collection bottle. Visual inspection is then made 

and the process repeated until the rinse liquid is visually clean. A final rinse is then rotated down the inclined 

probe liner into the sample bottle. The sample bottle is then capped and secured in the appropriate test run 

container. 

The rinse samples including the impinger liquid are taken and analyzed in the laboratory. The impinger liquid is 

measured volumetrically and transferred to a storage bottle. The liquid is then transported to an independent 

laboratory for analysis of chromium using graphite furnace atomic absorption spectroscopy. 

All sampling and analytical procedures were performed in accordance with the methods specified in the Code of 

Federal Regulations, Title 40, Part 60, Volume 43. 

Example calculations to determine the emission rates can be found in the example calculation section of this 

report. 

Envisage 

Environmental 

Incorporated 

P.o. Box 152 Rlchfa)ld. OhIO ';~2ef, 

Phono 1':-40) 526-0990 
7 

TEST RESULTS SUMMARY 

Envisage ........... _-. Environmental 

Incorporated 

P.O.1lox 1$2 R'OI\f,cl~_ 01\0 ~~266 

Pnono (4401 $2\i.()9!)() 
TEST RESULTS SUMMARY 

Diamond Hard Chrome Inc. 

Cleveland, Ohio 

Chrome Plating Tank #7 - Scrubber #3 

Chromium Emission Evaluation 

DATE: November 10,1999 

PARAMETER 

Run 1 

Chromium Emissions 

Pounds/hour 7.53E-05 

Grainsldscf 4.24E-06 

mg/dscm 0.0097 

System Flow Rates 

FUSee 7.71 

ACFM 2,179 

DSCFM 2,072 

Moisture Content 

Volume percent 1.76 

Sample Location Temperature 

Degrees Fahrenheit 85 

Run 2 

4.77E-05 

2.81E-06 

0.0064 

7.40 

2,092 

1,983 

1.69 

88 

8 

Run 3 

2.76E-05 

1.61E-06 

0.0037 

7.49 

2,115 

2,003 

2.29 

85 

Envisage 

Environmental 

Incorporated 

PO 00. lSZ Ad',j,t!IO Oh'tJ .,t·$:?8t. 

Ph0l'\t) ~ ':':0 I S~t> OCtO{; 
9 

TEST RESULTS DETAILED 

Envisage 

,-.---....... Environmental 

; --.'-... '-." Incorporated 

p.O.ll<Ix 152 RIch! .. Id. Ohl' 44285 

I'too<» (440) 52'>-0990 
TEST RESULTS 

Diamond Hard Chrome Inc. 

Chrome Plating Tank #7 - Scrubber #3 

Chromium Emission Evaluation 

DATE: November 10, 1999 Symbol Units 

Time of Day 

1 Gas Volume-dry,std. Vmstd cu. ft. 

1a Gas Volume-dry,std. Vmstd meters 

2 Condensate Vapor Vol. Vwstd cu. ft. 

3 Gas Stream Moisture Bws voJ.dec 

4 Mol.Wt-fJue gas (dry) Msd Ib/lb mo. 

5 MoI.Wt-f1ue gas (wet) Ms Ib/lb mo. 

6 Flue Gas Velocity Vs ftlsec 

7 Flue Gas Volume-Actual Os ACFM 

8 Flue Gas Volume-Std. Os (Std) DSCFM 

9 Concentrations Cs 

- Chromium gr/dscf 

mg/dscm 

10 Emission Rate E 

- Chromium Ib/hr 

11 Iso kinetic Rate % 

Run 1 Run2 

08:00 10:25 

10:00 12:47 

72.09 72.56 

2.04 2.05 

1.29 1.25 

0.0176 0.0169 

28.84 28.84 

28.64 28.65 

7.71 7.40 

2,179 2,092 

2,072 1,983 

4.24E-06 2.B1E-06 

0.00970 0.00642 

7.53E-05 4.77E-05 

100.3 105.5 

10 

Run 3 

01:00 

03:00 

69.29 

1.96 

1.62 

0.0229 

28.84 

28.59 

7.49 

2,115 

2,003 

1.61E-06 

0.00368 

2.76E-05 

99.7 

Envisage 

Environmental 

Incorporated 

po Boll 1S2 R..::h!llJir1 o~.') 4428£, 

Phmo ~':40j S26{.1990 
r--

11 

OPERATIONAL PARAMETERS 

I 
11/11/1999 13:3~ 2153'31~:>.1.8 

_DIAMOND 

PAGe: 81 

12 

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to 11:05 rtf-! 

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i-.----------I.'·, -------------:, 

14 

SAMPLE POINT LOCATION DIAGRAM 

Envisage ,,, '-. '''-''. Environmental , .. ,,-~~-~,,:. Incorporated 

,." ., P.O. 00. 16Z Rodl!;cld. OM 442&6 

~~i:ill' ""_(440)525·0900 
15 

o 

SAMPLE POINT LOCATIONS 

Facility: Diamond Hard Chrome 

Location: Scrubber #3 

inches width 

Point # Distance From Inside Wall 

1.9 inches 

2 5.6 inches 

3 9.4 inches 

4 13.1 inches 

5 16.9 inches 

Width 

Length 

Area 

22.5 inches 

30.125 inches 

4.71 square feet 

Position Horizontal 

Stack Description: Rectangle 

Horizontal 

*** Downstream distance too shortl *** 

1.1 Feet, Upstream Disturbance Distance 

2.3 Feet, Downstream Disturbance Distance 

4.71 Square Feet, Cross Section Area 

4 Number of Traverses 

2.1 Feet, Equivalent Diameter 

0.5 Equivalent Upstream Diameters 

1.1 Equivalent Downstream Diameters 

24 Total Number of Sampling Points 

Envisage 

Environmental 

Incorporated 

po Be. '!.2 RdJIL"id OhIO 442bf 

PhOM (440\ S2t>,o;J90 
I 

I 

16 

SAMPLING TRAIN DIAGRAM 

Envisage 

f;::- ,',',,,1,1:.7, Environmental "'i,':~,,>,"i I d ' ___ ,,-:1 . ~"",:, ncorporate _ P.O. Box 152 Ajcllficl~.Ohio442ee ..~ ... .. .. ,... Pl>cno (440) 526-0090 
Sampling Train Diagram 

~ -mm ~ ~::s::s t n < < !? 0 ::;._. 

~ -a 0 = 

:g o::s u:a o .. 3 CD 

!LCD 

CD::S 

A, .... 

-'" 

----_ ... _--------------

lEMPERA~E6ENSOR IMPIUGER lRAIU 

r1l n- ¥i; PRooe 

~) ~U~, =, (~-~l ____ ~_ ~===== FILlER OMInEO 

• ~E 6 PI10TlUBE ~(I-'- --- TEMPERAlURE 

SENSOR 

1 

WEeK 

/ VAlVE 

~~< ...... ---...... ----...... ···11 ~:~ 

Co .In\, ,0, /0, 1'';-

,J) rlh.JJ til,,]) -?IIJ I IY~~~'. 

{t !I-l-I(~o\' -\\/i I f'Ot l\'{\ 

\

1\; \\{\ I, n II 

)1 1\\ d' ',\ ~\ 

Tl:MPERARlIlE 

I

SEIISO!l 

- UlIIIEA1EO 

Gl ASS S rACK Gl ASS IltiEll •• 

""'\"'.,. ,:"~, -'~'''',JI')J' f:-·-----:-~·==·---i 

",:,~\' ,,~~--Il \ ~ J 

I ---\\ -- -. --- --I .. -- -.. ---------.-- --1 - --- -1 -.~- -: t --.- 1--" .. __ T--~~~I, 

PHOT MAtiOMEIER tIlOndO 1U 100",10 m e",1AV HnOl t 11001 t \modlnod , 

(modlll"" no IIp)t11elldotd Up) no Up) 

ORIFICE 

U.S.EPA Melhod )06 - Isokinetic Sampling Train 

IlIk:a gel 

200 JOOg 

I,nodlllod , 110 111'1 

c:>(~ -l~'l'l. VA 1M 

GAlIGE 

MAl ~VAI.VE 

... -- - AIR lIGIIr PUMP 

...... 

-...J 
• 0 

18 

LABORATORY SECTION 
Q 

19 

LABORATORY SUMMARY SHEET 

Diamond Hard Chrome Inc. 

Chrome Plating Tank #7 - Scrubber #3 

Chromium Emission Evaluation 

DATE: November 10, 1999 Symbol Units Run 1 Run 2 Run 3 

1 Sampling Time t minutes 120.0 120.0 120.0 

2 Barometric Pressure Pb in. Hg 29.92 29.92 29.92 

3 Static Pressure Pg in. H2O 0.03 0.03 0.03 

Stack Pressure Ps in. Hg 29.92 29.92 29.92 

4 Gas Meter Volume Vm cu. ft. 74.12 74.46 71.43 

5 Stack Area A sq. ft. 4.71 4.71 4.71 

6 Nozzle Diameter On dec. in. 0.50 0.50 0.50 

7 "Y" Factor 1.002 1.002 1.002 

8 Meter Temperature degrees F 85.7 84.6 87.1 

Tm degrees R 545.7 544.6 547.1 

9 Stack Temperature degrees F 85.5 87.5 84.8 

Ts degrees R 545.5 547.5 544.8 

10 Velocity Head (SQRT) "P in. H2O 0.134 0.129 0.130 

11 Orifice Pressure "H in. H2O 1.28 1.31 1.23 

12 Carbon dioxide CO2 % 0.0 0.0 0.0 

13 Oxygen 02 % 20.9 20.9 20.9 

14 Carbon monoxide CO % 0.0 0.0 0.0 

15 Nitrogen N2 % 79.1 79.1 79.1 

16 Pitot Coefficient Cp 0.84 0.84 0.84 

17 Water Collected Vic ml 27.5 26.5 34.5 

18 Sample Weight: Mn 

- Chromium ug 19.80 13.20 7.22 

mg 0.020 0.013 0.007 

9 1.98E-05 1. 32E-05 7.22E-06 

Envisage 

Environmental . ... . Incorporated \f&~F:~ffM~~.~~f·n ~)ropo;~:;: ~2').C.~,~r,~!~ Cr, a 4;~~~ 
Sample Date II {Icl q,\ 

Client Name D '¥,>C""'-' ~ '-\A.. (t 0 ~\:.I,,!'L C'" tr ,"-I <:... 

Facility Name 

Location 

USEPA Reference Method 4 

I RUn # 

I ~ I 1.. I Case # 

Moisture Collected 

Impinger #'s ,- 3 i- ') 

Rnal vol (.\$" -\ 'L\S"" .... ( • Initial vol I.... t,;>O - , 1.c;C)-- \ 

Net vol i~ -.\ l ~ --I 

Silica Gel 

Impinger # Y L.\. 

Final wt 

• Initial wt <-r7-.'~j <\"~:!> ,-~Q ~ LUO.$ 

Net wt I"Z.'::;-j It. ~ j 

.iiO·-lJal4 rorms;\lrtd04,iaO lUii("''''' 

(are Weights 

Sample Turnaround 

Final Weights 

3 I Field Blanks 

I 4th case 

l- 3 

l 20-' 

"Z uO~\ 

2.0-\ 

~ 

Z. I I..\.£"" ~ 

"1..<"'=>o~ 

\ ~I, S .s 
.: 1.q:,.", '1-' g '3 

D.J ~ ~o!:!!~lM!.! Analytlc.!1 L~bo,ato"es 

November 18. 1999 

Envlsage Env1ronmental Inc 

PO. Box 1~2 

Richfield. OH 4428h 

Dale Collected' N/A 

Date ReceIVed 11111/99 

ProJect~: 99-1.501 2111 118~ 

CUent ID fl' See Below 

Laboratory CD #. See Below 

Analysis' Total Chronuum (USl!PA Method 306) 

Detection Lmu t See Below 

Matnx. Liquid 

Date of Analysis: 11/ 18/99 

LIMtitorv ID Ii Client lD N VOlume {ml} 

QQ35SI-Ol EEll#l ev/I..J t 4.500 

<)o93S51-02 EEl1f2 ((VNt. ~ooo 

<)93551·03 EEl 1#3 Q.v 1\,)0 ~oo 0 

QQ3SS1-04 Blank 380.0 

Laboratory Manager Bassam Youl!lee;..m.~ - " 

,.., \"WI", 

III 

Detection Limit nua' Chromium 

(u2Lsgml2l~} 'l'I:l~~mRI~ 

o 4S 198 

0.4 lJ2 

04 7 ..... "'I 

0.38 .-: 038 

"Analyticallnt'grity" • A2LA Accreditation #0724.01 • ISO 90( 0 

5'15 East Tallmadge Avenue • Akron. Ohio 44310. Phone: 330-253-&211 • Fax: 130-253·4489 

Email se!3746@apk.net 

21 
~r----------~t~ __ ----------""" 

i 

FIELD DATA SHEETS 

22 

Envisage 

Environmental ~~.= Incorporated 

p.o. Bo. IS< RlOhl.Old. O~., 44286 

Phon. (440) 526-0990 
Field D:.1 t:.l Cover Sheet 

Cke t: Date: II 

lsource ID: 

i 

I Sc:uic P:-essure: 

i 

!Barometer ID: 

)Iere:- 3,):t ill: ,A-1 A - B 

/.00 <-

1--- . .=::. ..... -~:'w 'f' .' e:noe!'s: ~-------------- ) 

... r. :1. ... ~= ?~:r.:. .oc:t.Ucns I .' -4. 

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f I~. ~ urnoe:";)I --:'0("'05: 5 I 

j Port ~nside i)iamete: 3 I- I 

I 

E~vlSAGE E~"V1RON1-fEYrAL. ~c. 

23 
I. .. Ihli • 1,,1 (/+~~') ~~ t? .-v-)/2 i'~ '-:cl'::1 '::: ':} ..... , C IIH.uttall' .--_._p. ___ ~I2UJ1AcR, .... _#.3 ____ . ___ . ________ _ 

. .. 

\ 

1'01111 lime Vel/JIlly IIead Sill' k Siock 

Number olUIlY P",ssule lei"", illY 1011111. Wei 

'p "",0 5'111 'p 'F 'f 

( ",O'i tS0 

'- • () <.0 ~ 

1. 

-' I D~ &0 

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" .DS- 80 . 

~ 

(0 .D 'L 7'1 

') .0'2.. ',9 

6 , D"L /9 

f"-( .03 i9 

10 0,--\ 60 

/1 ,03 Jl_ _. . 

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lip , 0\ ,,\ 

17 ,0 \ I S 

If!!. ,0 \ 80 

/1 1 0 \ 50 

LO ,0\ eo 

'2. ( ,,0, ~o 

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2-3- ,ot... 'BC) 

2'1 ( O~ 90 

"L-> ot...{ 50 

r.lol lube fiiil,TTim, - 1'cf'lnl~l U ~ 

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lillie 

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------

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I'.eulire 

"11,0 5'1" 'p 

Sla~k 

Telllp.Url' 

'F 

Slack 

1enlp. Wei 

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------1-----1-----1,-------;------11 

11------1-------1------1-------1------1------11 

r~ 

,.,6 __ --'''1110 

J' 
D\AM.(y-.)~ ,,~(2D J. J Facility Name: <::..H..(2. Oov.. ~- DATE: {I/Io I q C\ Runll I 

Slart Time: End Time: ( O· tX::::' 

Vdocity 

Ih:ad ~ KA 

Sample ~r MeIer Puml' I~ilter t'\ 1\ 

Time Gas MeIer I'U:SSUIC Pressure Pressure Stack Tell~' Temp Out Vacuum II er P~ hlll,illger 

Point N (Min.) Volume (Fll) I\p ("1l20) Sqrt. 1\ P ("1ll0) Temp (F) (F) (F) ("tlg) Teml F) TemP"'tR> TCIIIII (F) 

Velt)City 

Head Orifice 

6112 551rH -17 7 , :~D . 0 \ \ • (. '-\ COiP 6.:\ "u : I 

Tolal Average Average Average Averclge 

I -"]y, I L I Ij}1q(~ll,lB B~,,",~I 18~,(,Q11 

I Sample Train Leak Check PRE . 0 CFM @ 2. V "lIg Pilol Leak Check PRE (A) 0 @ ·1.~.·H20 (D) 0 @ C;. ""1120 J 

,OC:> "IUO (B) 

tJlS£CT·IIfORMI/.nOATASII XLS 
Facility Name: \)\t\. .. "c~D I-\ARV 

-(' \-\ Q.o "'" \£ 

Start Time: 10', L SVelocity 

Sample Head 

Time Gas Meter Pressure 

Point II (Mill.) Volume (Fe) "P ("1110) 

I 0 BIZ. '-10 Dl 

2 512.5 91~,u<,) lr) \ 

3 1015 8n,Ob ,O"L 

4 1517.5 1820. ~'1- ,0 '-

5 20/l0 Bl..'~. 5"L .OL 

6 25/12.5 ,~L\O or 3C1i .. 0, 

fin 30/15 8(.~, 1O 0\ 

11/8 35/17.S <O~)i,~1 0\ 

~/9 40/20 ~~~ .(,0) .0 , 

l-tllO 45/22.5 B~ I., .0L D2. 

,6/11 50/25 tL~9 ,Z- ,D \ 

~12 55/27.5 8'1 \/ L. ,0 \ 

,.~ ,1 60/lO'" 18i.J 3,70 ,c.) , 

I ~\ lHCJ?; 8L/~ ,03 ,0 I 

1. ~ )J J,>-,o IB~B''>7 ,0 \ 

Ii, ) lJ.8 7r Q.,<:(). (" I ,D , 

/1 -5~ 80 ICO) Z ,('.1 Z ,0 I 

ill .~ ~B~ 8S~,.30 .oL 

I <" :r :lS-' ciO ?~~. --Ie:, ,0,\ 

10 ~q.> I~( 1. C; .0:'> 

. 2.1 JJ ~/cO SliP ,10 0"-.0 

11 Id ~/V>- 3,"2... \ j 0(' 

. 1.~ 1X l,5Y" I ~ 817 , ,~ ,o~ 

~ '~t M 5.1o:'S II ~ RH'L ,('X..a '.Q'-\ 

-z.( 60 ('2...0 B81,() I 

Total 

/"_~ I 1*. c..f lJZ I 

I Sample Train Leak Check PRE .0 

,00 

U,ISEcr·IIfORM\l.tiUATASII.XI.S 

B lG .'" y'- '6 \ 1.. , '-\ D 

(i~_" 7 .. t 

DATE: II },..:.J ., <.\ lRunN"L Case#: e. c... L 'Location: :sc 1lv.16a2. ;it :3 IPage '-\ or 5' I 

End Time: \ 1 '. ~\., 

Velocity rJ-f\ 

~ Head Orifice 

~ Meter Pump • iller 

Pressure Pressure Stack Te In Temp Out Vacuum I der 

Sqrt. " P ("lllO) Temp (F) (F) (F) ("lIg) Tenip{F) 

( .G,'", to'l \ ce...,'l.. 1·0 \ , \ , L?'~ B~:> e,:~_ f,D 

. '''' \'-\, I. (~ 5<;. e/~ i.O 

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. \ L\ / '-\ I. <.'0 5<; 8 L \ f. ". 

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. ,~- .L to_'"\ e2'1 e/\ (.0 

, o to'-\ o " t:.> B~ /·0 

. \ . ~'-1 ~~ 6~ (.0 

• 1--\ ,,£ fS KP.J B L\ I, S-

, \ ( "'--\ P.JL ~~ 1,0 

I ,(0'" t)? 8~'( ,. (;> 

I , . (,' L/ P .--"1 ~y /,0 

o I ,(Q<{ S'c!J e~ 1 , (-:;:.J 

, \ , CoLJ 80 '0:::' /,V 

. \ .laL.\ ~~ B~ ,~ 0 

\ , (..,Y S2,', e..~ I d.::'> 

I '-\ I 1.~.1 p)X 9S- I,,~ \, '\ I \~ z.. ~e., e..S 3.0 

-1 ".~ I , C;'"'L RR ~L. 3,..& 

_ ''V''\ ~).0.{ B-' t:i.o ([,0 ) 

t z..z.... ~IZ.J ?I\ ~l /-"0 

,L1... '!" L , 81:\. .38 (., ·D 

,1.... "l,5.-~ e~ \ eb 1(P.o 

Average Average Ave~e Average 

I .\ 1..l:\.. I \, ~ \ 1 67.,;-'-1 I I ~'1k"" CFM@ 1.-- "lig Pitot Leai Check PRE (A) @ "H20 (B) ~ 

- "H20 (B) 

NA {{6 ~~ i )-

P~ Impinger ~, Tem F) Temp (f) .. "\ 

r.-, .. A 

( :;./ 1--., 

=. 

_)'3 ~/ 73 -r--

J\ 

(DC, 

'1 ~ ~ 1 ( ("""': . 10 ~~ 

(D 

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77 I(~ ?Jl\,\\-\ 

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,1, 

73 

7'"3> 

@ "1120 I 

~v N ) ()\)E-ra 

~\ C UI3~'\" LDLo.) 

SAM ('L-'" Pv Ll. 

{GA\£ 1-tE lGN' 

(€'#-IT) t.vAS "'j'( 

(.) \ 1=="1_ \ ~ v ... ;-- I. 

6 .zL.OW (frio 

p 

I\) 

0> 
FacilityNallle; a~flz;e 0-~w DATE; l( J IV/ 1'( Run" 3 Case"; 

Start Time: I ~ 00 End Time: 

Velocity IJA ;J f\ JJ-A 

Sample llead Orifice ~ter Meter Pump Filt~ %t 

Time Gas Meter PrC5Sure Pressure Pressure Stack T np III Temp Out Vacuum Hoi rP Impillger 

Point II (Min.) Volume (Ftl) "P ("1120) Sqrt." P ("1120) Temp (F) (F) (F) C'lIg) Tem f) Tel ) (F) Temp (F) 

Velocity 

Bead 

10 0B7.20 C£" '2-""'2. 3.2..1 BR , sCa S. () ? 0 

5 20/Ht -1 oCo I Z't . aq (L. 'Z . -; f f=) ex ~; p, "> ~ _~ J 

f8 351tT.5 C\. \lD I') () \ I \ 1((1'- 6'\ ee 1,0 .01 

19 40/20 I q I 6 '-I 1 . 0, I l I inCI f3 8 8 -:1 I , U ';:) -(.( 

kl/12 551'8:5 le,,- (P PH \) \ C' . (D '-l 88 8 1 , I D .\~, 

I~ 60/» (fz q ((p , 0 I I I (CoL 88 e 7 i·o ~<; 3 

I ~ 32.5 -:; Ie 31 • L\ '\ I 0 \ \' . ~ '"\ 8('\ B ( ( , (:) ~1..( 

?U "7.5){ Cil.lS" 32. . l) L I l'-f I, ltJ ~O ~"1 I. (;> Sy 

21 50 '-(:) Il('f8.1 I 10 I I \ I l oW ~~ ~ I I u \ \ . .:;-~ 

1.2. 0 52.5 'f~ ,q.,50, q 8 ,0 \ '\ I <'p'1 t1~ e', I. 0 \ <~S" 

1.) 155 ,fO O~).1.L .0\ • \ ,(PLt SO \ e7 1.0 ~-s-

"1'( 2 57.5 ~l i'-1 &"~,S"l ,0 L , \'-\ \ ,'1.."0 eC\.. p., '1 I. s SS 

Total Average Average Average Average 

}I. '-f~ I I. \ '\ () 11,23. I Ht,I~ I 18'Z081 

I Sample Train Leak Check PRE .0 CFM @ I L\ "lIg Pilot Leak Check PRE A) @ "H20 (B) @ "H2O I 

.O·z..... "H20 (8) 

U.ISEcr·IIFORMlMSUATASII.XLS 

J' 

\page S- of ~ \ 
CALIBRATION SECTION 

28 

Envisage 

Environmental 

Incorporated 

p.o. Box 152 Ri"I\fo.I~. o~;o 44286 

PM ... (440) 526·0990 
· :.. 

EMTIC GUIDELINE DOCUMENT GD-026 

Alternative Method 5 Post Test Calibration 

Company: Diamond Hard Chrome Inc. 

Cleveland, Ohio 

Meterbox 10: MB 17 

Run 1 

Time of Test min 120.00 

Volume of Meter dscf 74.12 

Temperature of Meter Deg F 85.67 

Deg R 545.67 

Barometric Pressure in. Hg 29.92 

Delta H H2O 1.28 

Delta H@ H2O 1.75 

% Oxygen 20.90 

% Carbon Dioxide 0.00 

% Carbon Monoxide 0.00 

% Nitrogen 79.10 

Dry Molecular Weight of Md 28.84 

Dry Gas Meter Calib. Ch Yqa 1.057 

Y Factor 1.00 

Difference 5.2% 

Average Difference MB 17 3.0% 

Run 2 

120.00 

74.46 

84.63 

544.63 

29.92 

1.31 

1.75 

20.90 

0.00 

0.00 

79.10 

28.84 

1.064 

1.00 

5.8% 

29 

Run 3 

120.00 

71.43 

87.08 

547.08 

29.92 

1.23 

1.75 

20.90 

0.00 

0.00 

79.10 

28.84 

0.981 

1.00 

-2.1% 

Envisage 

Environmental 

Incorporated 

po. Box 152 Richfield OhO 44286 

Phone (440)520-0990 
. f 

o 

C') 

METHOD 5 DRY GAS METER CAliBRATION USING CRITICAL ORIFICES 

1) s.ct en. CI1tcoI cd!Ic:ft III calbra ..... cty gallMlot oIKh braclcel ... e>epeded operaf"' .... 

21 R-.I....-1c ........ bef .... lIIII.ner cdbralanproce<b •. 

31 Ru'UllHllclwoun Ifrom onace C&IInlan R"I'OII~ lor • period (II time 

'*""'Y 10 Ictj_ • rrinnun IDlalvolme ~ 1\ c:dJIc leeL 

41 Reccrd rucfngs n GUIned boms beIGw, CIfler cd.Ims Ire eulamal!cllty c:aIcIJaled. 

DAII:IIIIIlS/llI METER 'EIlIAL.:~ 

.... ROMEIRIC PRESSURE In Hg): 

M"IR ,AIII.: M.\1 CRITICAL DRIFICE UI SERIAL.: I 

K' 

[J 0.5ON 15 158.20 8U .• U 5.285 113 1I n IU 

It 0.5ON 15 1111.210 In.es 5.115 BO 51 51 51.5 

It 0._ II IU..U I8O.Z1S 1.1'0 IZ 51 IZ eO.5 

[] ..ll!!!... ~ InOla 1.1.3n 5.SZ5 -.!!- ....!L I-~ n 

O.IZIt 15 Nun Inns 5.3410 12 M 85 M.S 

a.121' 15 ttl.U5 ttl.N 5.«5 IZ tIS 81 88 

[J O.3lOl 15 .U750 u .. no 5.310 41. 411 81 II 

1Z a.3lOl 15 1041.120 ISUSl Uill A ell 11 10 

n 0.3Z01 15 nUll .51 .• 10 5.1113 A 71 11 11 

U'''O TIlE CMICAL altl'lCIUI CAUllRAllON UAHDARDS: 

H11AL FINAL j'VG IP'_I Ui!L1 Ci!L1 211.11 

IF Y VARIATION EXCEEDS Z.ocn'o. 

DRlFlCE SHOIILD IE RECALII!IRATED 

l 

~§ 5.1478 5.I7Z7 1.00f1 UfOl 

'.00 U 5.14113 5.1111 1.0031 1.13$0 

IZ.OO U 1.75" 1.lU5 1.0011 1.1.51 

Ava. 1.0011 0.1. 

~§ salis 5.ZIM a .• _ 1.1101 

5.00 ,. 531\1 5.lIM o.lUl 1.1101 

5.00 U 5.1111 5.ZSSf O."!lI 1.1101 

AVO_ O.ttZl .0." 

n.oo 0 .• " 5.ZUl 5.'110 I._II 1.1113 

11.00 UI5 5.22'0 S.'IBO uln 1IU, 

13.00 0. .. 5 S.nl. 5.Z_ 1.0112 urn 

Ave. 1.0101 0.10 

Tho ~..,.-,. .. -"10 _ tot -.. .......... III p .... d ItroI.9ItotDGU. V.(oId). nth e<tIcti ootIct. 

V.(IId).,mhOGU. __ .y. T ...... ..-..... _tlr_.dntot '1"" __ AVERAGE DRY GAS METER CALIBRATION FACTOR, Y .1 -1.0021 

I" V. (.Id,. 

(2, V .. loldl· 

Il) y. 

MBn 

0.10 Callbral"': 

Dal.Ouo: 

K, V. p •• + .... HlI 3.11 

T. 

• Nat volme elf gas so. passed .~.,... OGM. eorrec:led 10 sWldald ~~ons 

K, • 17.84 'Mn IIg (EnglIsh). O.38S8 'KInrn Hg (MtIric) 

p e 

II' -..IT::: 

T .. ;s ~oU:. OGM avg tttf11).atU'. ra .. EngI"'. eK· Metk) 

• VeUTie elf gn ~ pasud Itroug, "" at~tol orIIke. corrected 10 standanI conctaons 

T .... AbloU. atrbIOIt 1..,.....I .. e (II. EngII .... oK· _.j K'. ,, __ ~ K' fad", &"", CrtUc" onto. Callnll"" 

V.(oId, • OGM caltnlan lactor 

V.lstdl 

6.... 1.75 

Yc. 1.002 

,~ 

1212418 • 

AVERAGE Aile • U.5t 

AHe • (lI.lUJ I AN 

V,,(old 

...... 

Ci_~ ~ 

CQ)ll 

~ .. ~ 

~Emj _ .. 50 

""C 0 a:m 

m 0 c. ~ fI) .... '" .-.- 0 ~6 

> > CJ :~ CCC.g~ 

111111- ~Q. 

'1·' .' 
t ~. 

31 

EMISSION SAMPLING NOMENCLATURE 

Envisage 

. Environmental 

Incorporated 

P.o Box 152 R;el'li;eld. OI'uo 4428(. 

Phone (440) 526-0990 
A 

An 

Bws 

C 

Cp 

Cs 

Cs02 

E 

Es02 

Pbar 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

SAMPLING NOMENCLATURE 

Cross sectional area of stack or duct, ft.2. 

Cross sectional area of nozzle entry plane, ft.2. 

Water vapor in gas stream, proportion by volume. 

Nomograph correction factor, dimensionless. 

Pitot tube coefficent 

Concentration of particulate matter in gas stream, dry basis 

corrected to standard conditions, gr/dscf. 

Concentration of sulfur dioxide (Ib/dscf) 

Nominal diameter of probe nozzle entry plane, in. 

Emission Rate, Ib.lhr. 

Emission rate of sulfur dioxide, Ib./hr. 

Average pressure differential across orifice, in. of H20. 

Orifice meter calibration factor, in. of H20. 

32 

= Percent of isokinetic sampling, %. 

= Pitot tube constant, 85.49 ft.lsec. 

= Constant, 0.002669 in. Hg-fe per ml - Rankin 

= Molecular weight of gas, dry basis, Ib.llb.-mole. 

= Total amount of particulate matter collected, g. 

= Molecular weight of gas, wet basis, Ib.llb. -mole. 

= Molecular weight of water, 18 Ib.llb.-mole. 

= Barometric pressure, in. of Hg. 

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Phone- (440, 525·09!JO 
, " 

PCDD = 

PCDF = 

= 

= 

Pstd = 

= 

ppm = 

APavg = 

Q = 

Qstd = 

R = 

t = 

= 

= 

Tstd = 

= 

Vic = 

= 

Vm(std) = 

VOC = 

= 

Polychlorinated Dibenzo-p-Dioxins 

Polychlorinated Dibenzofurans 

Pressure differential from gas stream to atmosphere, 

(static pressure) in. of H20. 

Absolute gas stream pressure, (Pbar + P gl13. 6) in. of Hg. 

Absolute pressure at standard conditions, 29.92 in. of Hg. 

Density of water, 0.00221b.lml. 

Parts per Million 

33 

Average of the square roots of the velocity head readings, in. of H20. 

Volumetric flow rate at gas stream conditions, AC.F.M. 

Dry volumetric gas flow rate corrected to standard conditions, 

Ideal gas constant, 21.85 in. of Hg-fe, oR-lb.-mole. 

Total sampling time, minutes. 

Average dry gas meter temperature, oR. 

Average absolute gas stream temperature, OR. 

Standard absolute temperature, 528° rankine. 

Volume of sample aliquot titrated 

Volume of water collected in impingers and silica gel, ml. 

Volume of gas sample measured at meter box (meter conditions), 

Volume of gas sample measured at meter box (corrected to 

standard conditions), ft.3. 

"Volatile Organic Compound" 

Average gas stream velocity, ft.lsec. 

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PhOne {440J ~26-0990 
· ,. 

Vso1n = 

Vt = 

Vtb = 

Vw(sto) = 

y = 

13.6 = 

12%C02 = 

%C02 = 

%02 = 

%CO = 

%N2 = 

34 

Total volume of solution in which sample is contained 

Volume of barium perchlorate used for the sample 

Volume of barium perchlorate used for the blank 

Volume of water vapor in gas sample (standard conditions), ft.3. 

Dry gas meter claibration factor 

Specific gravity of mercury (Hg). 

Particulate concentration corrected to 12% Carbon Dioxide (dry 

Percent by volume of Carbon Dioxide in gas stream (dry basis). 

Percent by volume of Oxygen in gas stream (dry basis). 

Percent by volume of Carbon Monoxide in gas stream (dry basis). 

Percent by volume of Nitrogen in gas stream (dry basis). 

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• p. 

35 

EMISSION SAMPLING CALCULATIONS 

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Environmental . -, .. Incorporated 

P,o. Sox. 152 Roehfleld, 01110 4.42ao 

Phor·e (440) S26-09'~O 
• C> 

EXAMPLE CALCULATIONS 

Diamond Hard Chrome Inc. 

Chrome Plating Tank #7 - Scrubber #3 

Run # 

Start Time 08:00 

Finish Time 10:00 

Sample Time (t) = 120.00 

Barometric Pressure ( = 29.92 

Stack Pressure (Ps) = 29.92 

Stack Area (As) = 4.71 

Stack Temp. (Ts) = 8S.46 

Nozzle Diameter (On) = O.SO 

Velocity Head ("P) = 0.13 

Orifice Pressure (I\H) = 1.28 

Meter Y Factor (Y) = 1.002 

Volume of H20 Colle = 27.S0 

minutes 

in. Hg 

in. Hg 

sq. ft. 

Degrees F. 

dec. in. 

in. H2O 

in. H2O 

ml 

Pitot Factor (Cp) 

Gas Analysis 

Sample Weights (Mn) 

Chromium 

Vm std. = Vm x [Tstd/(Tm + 460)] x [Pb + ("H 113.6) 1 Pstd))) x Y 

VmCmstd. = Vm std x .02832 

Vw(std) = 0.04707 x Vic 

Bws = Vw(std) 1 [Vm(std) + Vw(std}] 

Md = (.44 x %C02) + (.32 x %02) + [.28 x (%N2 + %CO) 

Ms = (Md x (1 - 8ws)) + (18.0 x 8ws) 

Vs = 85.49 x Cp x SQRT[dP» x [SQRT{{Ts + 460) I (Ms x Ps}] 

Qs = Vs x As x 60 

Qs(std) = Qs x (1 - Bws) x [Tstd I (Ts + 460») x (Pb + Ps/13.6) 129.92 

Cs = 15.43 x (Mn I Vm (std» 

Cs = mg/ Vmcmstd 

E = Qstd x Cs x (1 Ib I 7000 grains) x (60 minutes 11 hour) 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

= 

1= {[100 x Ts x «K3 x Vic) + (Vm I Tm» x (Pbar + ("H 113.6»] 160 x An x Vs x Ps x tU x = 

36 

0.84 

0.00 % C02 

20.90 %02 

0.00 %CO 

79.10 %N2 

7.S3E-05 Ib/hr 

9.70E-03 mgldsem 

4.24E-06 gr/dscf 

72.09 Ft3 

2.04 M3 

1.29 Ft3 

0.0176 vol.decimal 

28.84 Ibllb mo. 

28.64 Ib/lb mo. 

7.71 fUsee 

2,179 acfm 

2,072 dsefm 

4.24E-06 grains/dscf 

0.0097 mg/dsem 

7.53E-OS Ibs/hr 

100.34 isokinetic 

;,' . 

~ 

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Phono (440) 525·0990