BIWEEKL Y UNIT #4 (CMS Tas k IC4032) PAG E 1 O F 3 

WAST E FEE D CUT ; OFF _ PAS S FAIL 

1- TSHH-30 5 KILN HIGH HIGH S 

2 TSHH-31 7 SC C HIGH HIGH ^ 

3 PAHH-30 0 KILN HIGH PRESSUR E / 

\C 

4 PAHH-32 4 SC C HIGH PRESSUR E ^ 

6 TAHH-404 TEMPERIN G CHAMBE R HIGH TEM P f 

7 VIOLATION OPACIT Y HIGH INSTANTATEOU S 

8 PROCES S MONITOR FAILED ./ ^ 

9 WAST E FEE D MONITOR FAILE D y/ ^ 

12 VIOLATION STAC K FLO W HIGH 1 MIN S 

13 VIOLATION ZAC-31 6 (TRV) OPE N S 

14 VIOLATION ZAC-02 6 SURG E VEN T OPE N ^ 

15 UA-557 ANALYZE R FAIL HC L X ^ 

- o UA-558 ANALYZE R FAIL C O , 

17 UA-560 ANALYZE R FAIL 0 2 S 

18 UA-562 ANALYZE R FAIL H C ^ 

19 PDAL-56 3 LO W DELTA P. (ID FA N FAILURE) ^/ ^ 

2 0 WFD-OF F CARBO N INJECTION SYSTE M FAILED ^/ ^ 

21 PSL-10O/PSL-20 0 SC C COMB . AI R FA N FAILED

 s f 

2 3 PSL-20 9 X-1 4 PRIMAR Y FUE L LO W PRES S (ONLY APPLICABL E FO R #2 FUE L OIL) \ f 

2 5 STAC K FLO W HIGH INSTANTANEOU S ^ 

35 " VIOLATIO N SC C TEMP . LO W 1 MIN AVERAG E / 

36 VIOLATION KILN TEMP . LO W 1 MIN AVERAG E ^ 

3 7 WFD-OF F HC L HIGH 1 MIN AVERAG E ^ 

38 WFD-OF F OPACIT Y HIGH 1 MIN AVERAG E ^ 

39 WFD-OF F C O HIGH 1 MIN AVERAG E 

WFD-OF F H C (THC) HIGH 1 MIN AVERAG E f j S 

41 WFD-OF F BAGHOUS E DELT A P HIGH 1 MIN AVERAG E . c ; 

VES018999 
BIWEEKL Y UNIT #4 (CM S Tas k IC4032) PAG E 2 O F 3 

' ST E FEE D CUT-OF F PAS S FAIL 

y 

y _ 

42 WFD-OF F SD A OUTLE T HIGH TEMP . 1 MIN AVERAG E 

4 3 WFD-OF F OXYGE N (02) LO W 1 MIN AVERAG E 

44 VIOLATION HC L HIGH 1 HOU R AVERAG E 

45 VIOLATION C O HIGH 1 HOU R AVERAG E 

4 6 VIOLATION SC C TEMP . LO W 1 HOU R AVERAG E 

4 7 WFD-OF F KILN TEMP . LO W 1 BHFF AVERAG E y 

4 8 VIOLATION OPACIT Y HIGH 480 SEC/HOU R S 

4 9 WFD-OF F BAGHOUS E DELT A P LO W 1 MIN AVERAG E y ^ 

5 2 Ba g Leak Detection System (Tribo) y ^ 

6 5 Pumpable 1 Hour Rolling Total OP L 

66 Non-Pumpable 1 Hour Rolling Total OP L 

°q Total Waste 1 Hour Rolling Total OP L 

68 BT U 1 Hour.Totai OP L y 

6 9 C L 12 Hour Rolling Total OP L y ^ 

7 0 Low Violatile 12 Hour Rolling Total OP L y ^ 

71 Sem i Violatile 12 Hour Rolling Total OP L 

7 2 Mercury 12 Hour Rolling Total OP L 

7 3 As h 12 Hour Rolling Total OP L 

74 PC C Temperature 1 Hour Rolling Average Low OP L 

7 5 SC C Temperature 1 Hour Rolling Average Low OP L 

76 SD A Outlet Temperature 1 Hour Rolling Average High OP L 

7 7 Baghouse Differential Pressure 1 Minute Average Low OP L 

78 Baghouse Differential Pressure 1 Minute Average High OP L 

79 Stack HC L Corrected 1 Hour Rolling Average High OP L 

80 Stack C O Corrected 1 Hour Rolling Average High OP L 

M Stack Flow 1 Hour Rolling Average High OP L 

82 Hrt Cl/Hra Lime Flow 1 Minute Average OP L 

VESO19000 
PAG E 3 O F 3 

5 0 WAST E FEE D CUT-OF F TES T BY OPERATO R 

UNIT #4 OPERATO R T O CLOS E MANUAL HAN D VALV E A T LIQUID INJECTO R BEFOR E FLE X LIME & AIR LINE T O 

SCREENE D FEEDE R XV-01 3 SLIDE GATE . 

UNIT M OPERATO R T O VERIF Y CUT-OF F BY PRESSIN G EAC H STAR T BUTTON . 

(THEN INITIAL & SIGN SHEET ) 

SHREDDE D SCREENE D MAIN CONVEYO R AU X CONVEYO R 

X -11 _3_ _ 

x-12 CT? " x-22 "yy 2

^ 

VERIFY ATOMIZING AIR ALARM BY MANUALLY SHUTTING AIR TO PRESSURE SWITCH. 

(NOZZEL MUST BE OPEN FOR ALARM TO FUNCTION) 

x

"

1 0

 X-11 77 ^ X-12 ^jy - X-22 VT ^ 

83 Lime Slurry Density Low 1 Hour Rolling Average Shoutdown 

4 LOG CHECKS IN OPERATIONS BOOK 

85 ROD OUT KILN PRESSURE LINE (PT-300) 

COMMENTS: 

CHECKE D BY : Date: j/./T-Q ^ Time: 2 ' SO AM 

APPROVE D BY : Place: Control Room 

BIWEEKLY_4 

9/10/07 HK 

VES019001 
" BivVEEKLY UNIT #4 (CMS Tas k IC4032) PAG E 1 O F 3 

' "AST E FEE D CUT-OF F [ PAS S _.fAI L 

1 TSHH-305 KILN HIGH HIGH ^ 

2 TSHH-317 SC C HIGH HIGH X 

3 PAHH-300 KILN HIGH PRESSUR E X * 

4 PAHH-324 SC C HIGH PRESSUR E / 

6 TAHH-404 TEMPERIN G CHAMBE R HIGH TEM P X 

7 VIOLATION OPACITY HIGH INSTANTATEOU S S~ 

8 PROCES S MONITOR FAILED ^ 

9 WAST E FEE D MONITOR FAILED ^ 

12 VIOLATION STAC K FLO W HIGH 1 MIN 

13 VIOLATION ZAC-31 6 (TRV) OPE N X 

14 VIOLATION ZAC-02 6 SURG E VEN T OPE N S 

15 UA-557 ANALYZE R FAIL HC L X 

16 UA-558 ANALYZE R FAIL C O , X 

17 UA-560 ANALYZE R FAIL 0 2 

18 UA-562 ANALYZE R FAIL H C 

19 PDAL-563 LO W DELTA P. (ID FA N FAILURE) / " 

- 2 0 WFD-OF F CARBO N INJECTION SYSTE M FAILE D 

21 PSL-1O0/PSL-200 SC C COMB . AIR FA N FAILE D * S 

2 3 PSL-209 X-1 4 PRIMAR Y FUE L LO W PRESS . (ONLY APPLICABL E FO R #2 FUE L OIL) ^ 

2 5 STAC K FLO W HIGH INSTANTANEOU S ^ 

3 5 VIOLATION SC C TEMP. LO W 1 MIN AVERAG E X ^ 

X " 

3 6 VIOLATION KILN TEMP . LO W 1 MIN AVERAG E 

37 WFD-OF F HC L HIGH 1 MIN AVERAG E ^ 

38 WFDOF F OPACITY HIGH 1 MIN AVERAG E ^ 

39 WFD-OF F C O HIGH 1 MIN AVERAG E ^ 

.'40 WFD-OF F H C (THC) HIGH 1 MIN AVERAG E X ^ 

41 WFD-OF F BAGHOUS E DELTA P HIGH 1 MIN AVERAG E S 

VES019002 
BIWEEKL Y UNIT #4 (CMS Tas k IC4032) PAG E 2 O F 3 

• ' ' ^ST E FEEDCUT-OF F PAS S FAI_L_ 

4 2 WFD-OF F SD A OUTLET HIGH TEMP . 1 MIN AVERAG E 

4 3 WFD-OF F OXYGE N (02) LO W 1 MIN AVERAG E 

4 8 VIOLATION OPACIT Y HIGH 480 SEC/HOU R 

4 9 WFD-OF F BAGHOUS E DELTA P LO W 1 MIN AVERAG E 

5 2 Ba g Leak Detection System (Tribo) 

6 5 Pumpable 1 Hour Rolling Total OP L 

6 6 Non-Pumpable 1 Hour Rolling Total OP L 

6 7 Total Wast e 1 Hour Rolling Total OP L 

6 8 BT U 1 Hour Total OP L 

6 9 C L 12 Hour Rolling Total OP L 

7 0 Low VTolatile 12 Hour Rolling Total OP L 

71 Sem i Violatile 12 Hour Rolling Total OP L 

7 2 Mercury 12 Hour Rolling Total OP L 

7 3 As h 12 Hour Rolling Total OP L 

7 4 PC C Temperature 1 Hour Rolling Average Lo w OP L 

75 SC C Temperature 1 Hour Rolling Average Lo w OP L 

4 4 VIOLATION HC L HIGH 1 HOUR AVERAG E X 

7 

4 5 VIOLATION C O HIG H 1 HOU R AVERAG E / ~ 

4 6 VIOLATION SC C TEMP . LO W 1 HOU R AVERAG E / ~ 

k\0<A1L X 

4 7 WFD-OF F KILN TEMP . LO W HMtt* AVERAG E ' 

X 

r 

7 6 SD A Outlet Temperature 1 Hour Rolling Average High OP L f 

77 Baghouse Differential Pressure 1 Minute Average Low OP L 

78 Baghouse Differential Pressure 1 Minute Average High OP L 

7 9 Stack HC L Corrected 1 Hour Rolling Averag e High OP L 

80 Stack C O Corrected 1 Hour Rolling Average High OP L 

31 Stack Flow 1 Hour Rolling Average High OP L 

82 Hrt Cl/Hra Lime Flow 1 Minute Average OP L 

VES019003 
BIWEEKLY UNIT #4 

\ST E FEE D CUT-OF F 

CHECKSHEE T PAG E 3 O F 3 

50 WAST E FEE D CUT-OF F TES T B Y OPERATO R 

UNIT #4 OPERATO R TO CLOS E MANUA L HAN D VALV E A T LIQUID INJECTOR BEFOR E FLE X LIME & AIR LINE T O 

SCREENE D FEEDE R XV-013 SLIDE GATE . 

UNIT m OPERATO R TO VERIFY CUT-OF F B Y PRESSIN G EAC H STAR T BUTTON . 

(THEN INITIAL & SIGN SHEET) 

SHREDDED _ 

X-1 0 

_SCREENED _ 

X-11 

MAIN CONVEYO R 

X-1 2 

A U X CONVEYO R 

X-22 

VERIFY ATOMIZING AIR ALARM BY MANUALLY SHUTTING AIR TO PRESSURE SWITCH. 

(NOZZEL MUST BE OPEN FOR ALARM TO FUNCTION) 

X-1 0 X-11 X-12 X-22 

ALS O CHEC K OPEI 

CHECKE D BY : 

OF RA M COOLIN G WATE R LOWiFLO W ALAR M (MSG * >278) 

83 Lime Slurry Density Low 1 Hour Rolling Average 

, JA LOG CHECKS IN OPERATIONS BOOK. 

85 ROD OUT KILN PRESSURE LINE (PT-300) 

Shoutdown 

COMMENTS: 

CHECKE D BY : 

APPROVED BY: 

Date:lo^-VD° l Time: I < (a^Vm -

Place: Control Room 

BIWEEKLY_4 

9/10/07 HK 

VES019004 
ABSOLUT E CALIBRATIO N AUDI T (ACA ) DAT A SHEE T 

Uni t # 4 Seria l # 

Paramete r NIS T Traceabl e Calibratio n Standard s 

> 0 2 25 % G a s Concentratio n 

«* CO-lo w rang e 200pp m Low (Zero) 0 + 0.5 

r CO-hig h rang e 3000pp m Mid 8.93 ± 0.5 

r HC I 1000pp m High 15 + 0.5 

Run Number Concentration Difference 

Reference Analyzer Low Mid High 

1-Low 0 0.1 -0.1 — — 

2-Mid 8.93 8.98 — -0.05 — 

3-High 15 15.3 — ' — -0.3 

4-Low 0 0.1 -0.1 — — 

5-Mid 8.93 9 — . -0.07 _ 

6-High 15 15.2 x — — -0.2 

7rL0W 0. 0.1 -0.1 . . — . — . 

8-Mid 8.93 8.9 — 0.03 — 

9-High 15 15.2 — — -0.2 

Mean Difference = -0.10 -0.03 -0.23 

Calibration Error = -0.40% -0.12% -0.93% 

Calibration Error = Mean Difference/Span Value * 100 

E/ITec h 

Title 

9/22/200 9 

Date 

VES019005 
ABSOLUT E CALIBRATIO N AUDI T (ACA ) DAT A SHEE T 

Unit #

 4 Seria l # 

Paramete r NIS T Traceabl e Calibratio n Standard s 

r 0 2 25 % G a s Concentratio n 

CO-lo w rang e 200pp m Low (Zero) 0 ± 10 

r CO-hig h rang e 3000pp m Mid 68.9 ± 10 

r HC I 1000pp m High 154 ± 10 

Run Number Concentration Difference 

Reference Analyzer Low Mid High 

1-Low 0 -0.2 0.2 — — 

2^Mid 68.9 66.7 — 2.2 — 

3-High 154 152.6 — — . 1.4 

4-Low 0 -0.4 0.4 — — 

5-Mid 68.9 66.8 — 2.1 _ 

6-High 154 154.5 — — -0.5 

7-Low. 0 -0.1 0.1 — — 

8-Mid 68.9 67 — 1.9 — 

9-High 154 153.4 — — 0.6 

Mean Difference = 0.23 2.07 0.50 

Calibration Error = 0.12% 1.03% 0.25% 

Calibration Error = Mean Difference / Span Value * 100 

E / l Tec h 

Title 

9/22/200 9 

Date 

VES019006 
ABSOLUT E CALIBRATIO N AUDI T (ACA ) DAT A SHEE T 

Unit #

 4 Seria l # 

Paramete r NIS T Traceabl e Calibratio n Standard s 

r 0 2 25 % G a s Concentratio n 

r CO-lo w rang e 200pp m Low (Zero) 0 ± 150 

CO-hig h rang e 3000pp m Mid 1079.1 ± 150 

r HC I 1000pp m High 2289 ± 150 

Run Number Concentration Difference 

Reference Analyzer Low Mid High 

1-Low. 0 -0.2 0.2 — — 

2-Mid . 1079.1 1086.5 — -7.4 — 

3-High 2289 2287 — — 2 

4-Low 0 -0.4 0.4 — — 

5-Mid 1079.1 1077.6 — 1.5 — 

6-High 2289 2317.4. — — -28.4 

7-Low 0 -0.1 0.1 — — 

8-Mid 1079.1 1077.7 — 1.4 — 

9-High 2289 2301.9 — — -12.9 

Mean Difference= 0.23 -1.50' -13.10 

Calibration Error = 0.01% -0.05% -0.44% 

Calibration Error = Mean Difference / Span Value * 100 

E / l Tec h 

Title 

9/22/200 9 

Date 

VES019007 
ABSOLUT E CALIBRATIO N AUDI T (ACA ) DAT A SHEE T 

Uni t # 4 Seria l # 

Paramete r 

r 0 2 25 % 

r CO-lo w rang e 200pp m 

r CO-hig h rang e 3000pp m 

ff HC I 1000pp m 

Paramete r NIS T Traceabl e Calibratio n Standard s 

r 0 2 25 % 

r CO-lo w rang e 200pp m 

r CO-hig h rang e 3000pp m 

ff HC I 1000pp m 

G a s Concentratio n 

Paramete r 

r 0 2 25 % 

r CO-lo w rang e 200pp m 

r CO-hig h rang e 3000pp m 

ff HC I 1000pp m 

Low (Zero) 0 ± 50 

Paramete r 

r 0 2 25 % 

r CO-lo w rang e 200pp m 

r CO-hig h rang e 3000pp m 

ff HC I 1000pp m 

Mid 318 + 50 

Paramete r 

r 0 2 25 % 

r CO-lo w rang e 200pp m 

r CO-hig h rang e 3000pp m 

ff HC I 1000pp m High 707 + 50 

Run Number Concentration Difference 

Reference Analyzer Low Mid • High 

1-Low 0 -0.3 0.3 — — 

2-Mid 318 284.9 — 33.1 — 

3-High 707 713.1 — — -6.1 

4-Low 0 0 0 — — 

5-Mid 318 306.2 — 11.8 _ 

6-High 707 707.1 ' — — -0.1 

7-Low 0 0.6 -0.6 — — 

8-Mid 318 314.2 — 3.8 — 

9-High 707. 708.6 — — -1.6 

Mean Difference = 

Calibration Error = 

Mean Difference = -0.10 16.23 -2.60 

Calibration Error = -0.01% 1.62% -0.26% 

Calibration Error = Mean Difference / Span Value * 100 

E/ITec h 

Title 

9/22/200 9 

Date 

VES019008 
Table 1 

Summary of Relative Accuracy Test Audit Results 

Veolia ES Technical Solutions 

Sauget, Illinois 

June 22,23 and 24,2009 

CEM S Parameter Units Measured R A Criteria Pass/Fail 

Unit 2 CO ppm @ 7% 02 0.004 ppma 5

a

'

b Uni Pass t 2 

02, dry %o2 0.09%a 1.0

 a

-

c Pass 

Unit 2 

02, wet %o2 0.13%a 1.0

 a'° Pass 

Unit 3 CO ppm @ 7% 02 0.063 ppma Uni Pass t 3 

02, dry %o2 0.02%a 1.0

 a

'

c Pass 

Unit 3 

02, wet %02 0.31%a 1.0a,c Pass 

Unit 4 CO ppm @ 7% 02 1.146 ppm" 5a.b Pass t 4 

02, dry %o2 0.15%a 1.0a

'

c Pass 

Unit 4 

02, wet %o2 , 0.46%a 1.0

 a'c Pass 

a

 Percent of emission standard or absolute average difference (ppm or %). 

bPS4B. 

C PS3. 

INCINERATOR CEMS RATA 5 JULY 7,2009 

VEOLIA ES CEC Project 090-861 

VES019009 
Incinerato r 

Data Point 

Carbon Injection Flow 

Lime Slurry Density 

Stack Opacity 

Stack C O RCR A 

S D A Outlet Temp 

Baghouse Diff Pres s Lo w 

Baghouse Diff Pres s High 

Stack TH C 

X11 Weight 

X 2 2 Weight 

X 1 2 Weight 

X 1 0 Weight 

Stack HC L RCR A 

Veolia 

Environmental Services 

Sauget Illinois 

Created 

Period Start 

Period En 

1/1/2010 6:00 A M 

1/1/2010 6:00 A M 

1/1/2010 6:00 A M 

Page 5 of7 

4 

IMin IMin IMin I Hr Roll 1 Hr Roll 1 Hr Roll I Hr Roll 1 Hr Roll I Hr Roll 12 Hr 12 Hr 12 Hr 1 Hr Tot 1 H r Tot 1 Hr Tot 

A V G AV G AV G Warn Shut OPL Tot Tot Shut Tot OPL Roll Tot Roll Tot Roll Tot Warn 

Warn Shut OPL Warn Warn Shut 

Shut OPL 

OPL 

65.00000 

8.000000 10.00000 

450.0000 500.0000 

440.0000 500.0000 

3.000000 2.000000 

9.000000 10.00000 

8.000000 10.00000 

. 6.600000 6.300000 6.200000 

65.50000 65.40000 65.20000 

30.00000 40.00000 100.0000 

429.0000 431.0000 434.0000 

. 900.0000 950.0000 1008.000 

400.0000 500.0000 15.00000 32.00000 35.00000 

. 1550.000 1650.000 1700.000 

. 850.0000 950.0000 1 000.000 

. 1000.000 1050.000 1100.000 

. 1600.000 1650.000 1700.000 

VES019010 
Veolia 

Environmental Services 

Sauget Illinois 

4.000000 3.000000 

30.00000 33.50000 37.20000 

Stac k 0 2 RCR A 

HCLtoLime 

Shredded Weight 

Tempering Chambe r Temp soo.oooo 1200.000 

P C C Temp 1300.000 1240.000 

S C C Temp 1850.000 1825.000 

Stack C O Corrected 

Stack HC L Corrected 

Stack 0 2 Corrected 

Stack Flow 

L o w BT U Liquid Weight 

High BT U Liquid Weight 

Liquid Weight 

Containerized Weight 

Solids Weight 

Weight 

450.0000 500.0000 

100.0000 150.0000 

4.000000 

38000.00 

1570.000 1515.000 1507.000 

1905.000 1890.000 1886.000 

30.00000 75.00000 100.0000 

25.00000 32.00000 

37000.00 37600.00 38086.00 

. 2800.000 3050.000 3256.000 

. 1500.000 

. 10000.00 

. 12500.00 13000.00 13796.00 

Created 

Period Start 

Period En 

1/1/2010 6:00 A M 

1/1/2010 6:00 A M 

1/1/2010 6:00 A M 

Page 6 of7 

13000.00 145O0.00 15000.00 

1600.000 165O.000 1700.000 

1000.000 1050.000 1100.000 

2500.000 2750.000 3000.000 

13000.00 140O0.00 15000.00 

VES019011 
I 

B T U 

Chlorine 

Mercury 

Ash 

L o w Volatile 

Sem i Volatile 

Veolia 

Environmental Services 

Sauget Illinois 

. 235.0000 252.0000 

. 0.021000 0.026000 

. 8000.000 8777.000 

. 43.00000 47.00000 

. 60.00000 64.00000 

Created 

Period Start 

Period En 

1/1/2010 6:00 A M 

1/1/2010 6:00 A M 

1/1/2010 6:00 A M 

Page 7 of7 

. 48000000 490OD000 50000000 

. 2800.000 2900.000 3024.000 400.0000 450.0000 500.0000 

. 0.250000 0.275000 0.312000 

. 90000.00 100000.0 105324.0 

. 500.0000 540.0000 564.0000 

. 700.0000 740.0000 768.0000 

VES019012 
Facilit y Oxyge n Dat a 

VES019013 
December, 2009 Average Oxygen Concentrations for Units 2, 3, and 4 

Unit 4 

Date 

Method 5/26 

Wet 02 Dry 02 

(%) (%) 

Method 0023A 

Wet 02 Dry 02 

(%) (%) 

12/8/2009 5.6 10.3 4.8 9.1 

12/9/2009 5.8 10.4 5.1 9.3 

12/10/2009 5.1 9.3 4.3 8.2 

Date 

Method 

Wet 02 

(%) 

5/26 

Dry 02 

(%) 

Method 0023A 

Wet 02 Dry 02 

(%) (%) 

12/1/2009 5.7 9.5 4.0 7.3 

12/2/2009 4.5 7.8 4.1 7.3 

12/3/2009 6.2 10.4 5.6 9.5 

Date 

Method 5/26 

Wet 02 Dry 02 

(%) (%) 

Method 0023A 

Wet 02 Dry 02 

(%) (%) 

12/16/2009 8.6 12.7 7.7 12.6 

12/17/2009 7.9 12.5 8.0 12.4 

12/18/2009 7.3 12.6 6.9 12.3 
CD 

VES019015 
AECOM 

Appendi x B J 

Referenc e Metho d Fiel d Dat a an d Calculation s j 

VES019016 
Metho d 5/26 A 

VES019017 
Particulate Results Summary 

Unit 4 

Veolia ES Technical Solutions 

Sauget, IL 

Average 

0.0016B 

0.00282 

0.00120 

Test Results : Run 1 Run 2 Run 3 

Particulate Emission Concentration: 

grains/dscf 

grains/dscf @ 7% 02 

grains/dscf® 15% 02 

0.00138 

0.00234 

0.00099 

0.00118 

0.0019S 

0.00083 

0.00246 

0.00415 

0.00176 

Where; 

pj^s$^^ ^ 

VES019018 
Result s Summar y 

Unit 4 

Veoli a E S Technica l Solution s 

Sauget , IL 

Run 1 Run 2 Run 3 Average 

Parameter: Molecular (Total mg)'mg/dscm', (ppm@ (Ib/hr) (Total mgymg/dscm; (ppm% (Ib/hr) (Total mgy.mg/dsom) (ppm@ (IM") (mg/dscm; (ppm® (Ib/hr) 

Weight 7%02) 7%02) 7%02) 7%02) 

HCI | 36.46 | I 34.6 I 26.0 29.1 1.83 I 43.1 [ 33.1 36.2 2.32 I 3.6 I 3.0 3.3 0.20 20.7 22.8 1.45 

CL2 | 70.9 I | 0.48 I 0.45 0.16 0.00B I 0.47 I 0.44 0.15 O.01 I 0.48 I 0.43 0.15 0.01 0.44 0.15 0.01 

Total 29.2 36.3 3.6 23.0 

Where: 

m6«?a*= rMBqcWatf HWWtiwrdr)! sfwaarsf cubic melsi-= (msftscf^S! (3S St4-^icfe«/eu|*ns<star) 

UlJrnKS @ 7%02- OSrts pSrrtifcn « 7%6xtfgej^(<mfl/(l5cm'2,4 04 litsra/mQl!/ftKil>»*n*((ZO,9-7)/(20.9.a?%)) 

VES019019 
Calculations Summary 

Unit 4 

Veolia ES Technical Solutions 

Sauget, IL 

Vw(std), scf = 

Vm(std), dscf = 

Bws= 

Md= 

Ms= 

Vs, ft/sec = 

Qs, acfm = 

Qs(std), dscfrn = 

Isokinetic Sampling Rate, % 

Run 1 

26.124 

47.004 

0.357 

29.42 

25.34 

61.8 

46,603 

18,845 

101.7 

Run 2 

26.081 

45.921 

0.362 

29.44 

25.30 

62.1 

46,847 

18,646 

100.4 

Run 3 

23.916 

43.016 

0.357 

29.38 

25.32 

59.2 

44,653 

17,704 

99.0 

Averaqe 

25.374 

45.314 

0.359 

29.41 

25.32 

61.1 

46,034 

18,398 

100.4 

Where: 

Vw£std> volume of water vapor in gas, standard conditions * 0M7G7V\c 

Vm(sld) *Vol. of ^as sampled, Standard cOridrttoris = 17 647 xVm x gamma xTPb + (dH/136)j/Tm<R) 

B\fe!!i^aiir&^ 

Md molecular weight Of stack gas, dry basfe => (0.44 x%C02) + (0.32 x%02) + [02B X (%N2+ %CQ)] 

Ms =• molecular weight of stack gas, wet basis * [Md x (1-Bws)] +• (18>Q x Bws) 

V s * stacis gas velocity = 85.49 X Cp x (avg. Sq Ri dP) x]5q,Rt (Ts(R»/(Ms x PS)J 

Qs(std) *> stack gas flqwrater standard conditions = Qs x (1-Bws) x <528/(Ts<R)>x (Ps/29 92) 

VES019020 
Test Data Summary 

Unit 4 

Veolia ES Technical Solutions 

Sauget, IL 

12/16/09 

11:38 

12:41 

60 

0.307 

0.84 

0.991 

1.801 

Parameter Run 1 

Run Date 

Start Time 

Stop Time 

Duration of Run, Minutes 

A>ve. Nozzle Diameter, inches 

Pitot Calibration Factor, CF 

Meter Gamma 

Meter Delta H, inches of H20 

Stack Diameter, inches 

Rectangular Width, inches 

Rectangular Length, inches 

Stack Area, sq.ft. 

Barometric Pressure, inches of Hg 

Static Pressure, inches of H20 

Dry Gas Meter Sample Volume. (VM)ft3 

Initial 

Final 

Difference 43.842 

48 

12.57 

30.2 

-0.47 

580.378 

624.22 

Run 2 

12/17/09 

9:46 

10:48 

60 

0.307 

0.84 

0.991 

1.801 

48 

12.57 

30 

-0.51 

755.414 

799.164 

43.75 

Run 3 

12/18/09 

9:50 

10:52 

60 

0.307 

0.84 

0.991 

1.801 

48 

12.57 

29.65 

-0.34 

930.625 

972.957 

42.332 

Avve. Stack Temperature, Ts(F) 

A>ve. Meter Temperature, Tm(F) 

A,ve. Run Delta H, inches of H20 

/\ve. Square Root of Delta P 

386.2 

34.8 

1.85 

0.8181 

387.3 

42.1 

1.83 

0.8184 

387.4 

52.4 

1.65 

0.7758 

Moisture Data 

Volume of water collected, mis 

Silica Gel, grams 

Total Collected, mis 

546 

555 

544 

10.1 

554.1 

499 

9.1 

508.1 

ORSAT Data 

%02 

%C02 

%CO 

12.7 

5.7 

12.5 

5.9 

12.6 

5.5 

VES019021 
Field Data Summary 

Unit 4 

Veolia ES Technical Solutions 

Sauget, IL 

Travense 

Paint 

Start 

Temp(F) 

Delta 

P 

Delta 

W 

TmtF) SQRT 

Delta P 

Stack 

TempfF) 

Delta 

P 

Delta 

H 

TmlF) SQRT 

Delta P 

StacH 

TempfF) 

Delta 

P 

Delta 

W 

TmlF) sour 

Delta P 

Start 

Temp(F) 

Delta 

P 

Delta 

W In out 

SQRT 

Delta P 

Stack 

TempfF) 

Delta 

P 

Delta 

H In out 

SQRT 

Delta P 

StacH 

TempfF) 

Delta 

P 

Delta 

W in out 

sour 

Delta P 

382 072 2.00 27 28 0.8485 387 0.70 1.90 33 36 0.B367 \- 383 0.72 2.00 39 39 0.84B5 

386 0.68 1.90 26 34 0.8246 387 0.70 1.90 34 40 0.8367 ;l |: 3B0 0.66 1.90 39 45 0.8248 

388 0.67 1.8S 29 36 0.8185 391 0.74 2.00 35 43 0.8602 ;! 389 0.65 1.60 40 49 0.8062 

387 0.70 1.90 29 37 0.8367 384 0.74 2.00 36 45 0.B602 I: 388 0.63 1.70 42 , 53 0.7937 

386 0.66 1.80 30 39 0.B246 3B4 0.64 1.75 36 46 0.8000 :• i 388 0.60 1.65 44 56 0.7746 

384 0.57 1.60 31 40 0.7550 384 0.53 1.45 37 47 0.7280 :•• 385 0.49 1.35 46 59 0.7000 

384 0.73 2.00 31 39 0.8644 385 0.64 1.75 38 47 o.sooo :•• 386 0.63 1.70 49 60 0.7937 

385 0.66 1.90 32 40 0.8246 386 0.72 2.00 36 48 0.B4B5 :i 38B 0.63 1.70 51 62 0.7937 

390 0.73 2.00 33 42 0.8544 388 0.74 2.00 40 51 0.8602 ;i 387 0.60 1.65 52 64 0.7746 

390 073 2.00 34 42 0.8544 392 0.74 2.00 40 51 0.8602 i: 369 0.60 1.65 54 66 0.7746 

389 0.64 1.60 34 42 0.8000 390 0.70 1.90 41 53 0.8367 :i 388 0.57 1.55 55 67 0.7550 

383 0.S2 1.40 35 44 0.7211 369 0.43 1.30 42 53 0.6928 \\ ii 368 0.45 1.20 57 69 0.6708 

-

366.2 0.67 1.85 31 39 0.8181 387.3 0.67 1.83 38 47 0.8184 387.4 0.60 1.65 47 57 0.7758 

M 

2 

3 

4 

5 

6 

81 

2 

3 

4 

5 

6 

Average 

Laboratory Results 

FuelF-factor.dscf/MMBtu 

Filer ID 

Front Half Residues: 

Filter wt, g 

Acetone rinse volume, ml 

Acetone wt,g 

F H Total, g 

Back Half Residues: 

BH. Total.g 

Acetone Blank Residues: 

Acetone blank volume, ml 

Acetone Blank weight g 

Acetone weight gain.g 

AsetonB Blank concentration 

.001% of Acetone Blank Weight 

Weioht of Residue in Acetone Wash, g 

Corrected Acetone Blank Value, g 

(F.H. Total+B.H. Total-Blank): 

Run 1 

1 

I T1615 I fj 

I 0.0015 I I 0.0015 ~l 

3 C 3 

0.Q026 I I 0,0021 1 

Run 3 

T1818 I 

0.0042 I 

~-iT~l 

0.0028 I 

1 

155.4696 I I 155.4696 ' 

I 0.0001 

0.0003 

I 198 I 

I 155.46961 

I 0.0003 I 

0.0001 I I 0.0001 

0.000074 I 

Ca = MalVaPa 

Wa = CaVawPa 

Total, g 

VES019022 
Dry Gas Meter Calibration Data Summary 

Unit 4 

Veolia ES Technical Solutions 

Sauget, IL 

Parameter 

Run ID 

Run Date 

Meter Box ID 

Duration of Run, Minutes 

Meter Gamma 

Delta H@, inches of H20 

Barometric Pressure, inches of Hg 

Sample Volume, dcf (Vm) 

Ave. Meter Temperature, F (Tin) 

Dry Molecular Weight (Md) 

Ave. Delta H, inches of H20 

Ave. SQRT Delta H, inches of H20 

Yqa (calculated calibration factor) 

% Difference 

12/16/2009 

002 

60 

0.991 

1.801 

30.2 

43.842 

34.83 

29.42 

1.85 

1.36 

0.9S3 

0.2 

12/17/2009 

002 

60 

0.991 

1.801 

30 

43.750 

42.08 

29.28 

1.83 

1.35 

1.001 

1.0 

12/18/2009 

002 

60 

0.991 

1.801 

29.65 

42.332 

52.38 

29.38 

1.65 

1.28 

0.998 

0.7 

Average 

0.6 

Yqa = (test durationA/m) x (SQRT(0.0319*TmR)/(Delta H@ x (Pbar + Ave. Delta H/13.6)) x (SQRT(29/Md)) x Ave.(SQRT Delta 

% Difference = (Yqa - Meter Gamma)/Meter Gamma 

Three run Average % Difference must be <= 5% 

VES019023 
EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Sampling Train M 5 

Run Number 

Client ± Veolia ES Technical Solutions 

Facility Location 

Source 

Date 

Operator 

Stack Dia, - in. 

Start Time 

Stop Time 

Sauget, IL 

~3£T~ 

Jt&. 

J O S 

Barometric Pressure 

Static Pressure (+/-) 

Probe/Pitot Number 

Pitot Coefficient _^ 

Filter Boi No. _ 

Meter Box No. 

Orifice Coefficient (Y) 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple ID: 

tap Outlet TC ID: 

3a. 2, LEAK CHECKS in "Hg 

INITIAL VAC. /JiFINAL VAC. 

CFM€?,0O>-jp 

CFM 

CFM 

- y +. '7 

* / FINAL PITOT */ *H 

FILTER DATA 

iv p 

INT 

ri K 

r \ 

no I 

sffillliLiI 

HUr 

*-T_ -27 -

SsiMiiiBBfiS r\nr . 

2.7$-

G4 M H 

A k 

TEMPERATUR E READINGS , °F 

IdX) 

.FINAL* 

3 d ? 

/ 00 

PR Bt-il IMI IM I It IN I '"I 

| VACI'l'W 

. '-n Hp 

OYsat 

CQ2 ' 02 

f.7 /?.? 

Final Purge tUte fi j fig 

Final PH « — 

COMMENTS 

SE j . O ~35T •2D_ 221 2& 5 = 

157 

lif t 

I S C M : 276 , 

_2L 

3 / F 

-22=-

_K1 fi 3 ^ - 3 o 

fro.? 26 / 

-2* 7 2 ^ 1 3 3 

24x1 

2 - Q £03 i -XL 2 3 . 5 3 2 L 

•3C W 0.1* 6 bar 2 3 -

3 ? 

i t 

w 3 ^ ^TP.7 3 3?0 n6 2 e 

X-0 3?o 21 y 2^7 

241 

1 £ 

5 5 

t 383 2kQ- 3 S ~ 

VES019024 
AECOM EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Sampling Train 

Run Number 

Client 

Barometric Pressure $DJB> 

Veolia ES Technical Solutions 

Facility Location 

Source 

Date 

Operator 

Stack Dia. - in. 

Start Time 

Stop Time 

Sauget, IL 

Prone/Pilot Number _Sf*iS~- V. 

Pitot Coefficient . Q .ff 

Filter Box No. Q^>e\ 

Meter Box No. 

LEAK CHECKS in "Hg 

INITIAL VAC. /QL. 

MID VAC. --~ -

FINAL VAC. /O 

CFM O 

CFM 

CFM O .<sa 

INIT. PITOT 

JBL 

Orifice Coefficient (Y) <Q f 

Delta H@ / ~ /HO I 

Nozzle Size/No. Q.SOl 

FINAL PITOT 

FILTER DATA 

iQ. t/f /O ¥8 *AD Thermocouple ID: M<7Td~2 

Mill 

IMPlNGIlt V01 >, I 

JNH V 

"30" 

1W 

. Toe 

160 

(Co. 

? * 3 

RINSE 

V7 

ur 

1 Orsat 1 

| C02. . , 02 

V'1 

Final Purge Rate fl/ AIP c 

PO N 

h, I T 

mfflMrlW 

o in r 

H 

\ iv FK 

• ft i1 

TEMPERATUR E READINGS , °F PUMP 

\ ACI ii M 

ill. Hp 

COMMENTS 

IP c 

PO N 

h, I T 

mfflMrlW 

o in r 

H 

\ iv FK 

• ft i1 

i \ i i H in O WN 

(UK \<ll 

Mlllll 1 1 1 MPINGERI 

1 \SMI IIII 

PUMP 

\ ACI ii M 

ill. Hp 

COMMENTS 

IP c 

PO N 

h, I T 

mfflMrlW 

o in r 

H 

\ iv FK 

• ft i1 

i \ i i H in O WN 

(UK \<ll 

Mlllll 1 1 1 MPINGERI oi I 

PUMP 

\ ACI ii M 

ill. Hp 

COMMENTS 

A * 0.70 /.?o W -3.-! We 1? 

2. C <0 O.io t.qo 7 ft 7 to 3 

3 (0 t<f &nf 1ST? V S 

is io 0.7 ¥ HS& 06,3- 36 & 

z> vr a.M •24.5- XfiO 36- 3d> Fb 

f jr Jo 0>5i> 3&<f 3 7 -7 SWf<2. — /<£Vt& 

So i<r M r i&r 7 Ce-MprlrQ. -/Of fl 

o. 5 f to 0.73-. 16/ * n te? 

3 uo W i . G XSf 37 sr/ q 

M vr SD 5..Q nm.— -2,35- jo £7 

<T clo f.9r> 390 2-S-g- £ 73 fl 23 

1.3 •2-0? o 7 GAJOG* toia 

s

r 

VES019025 
AECOM EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

IMI IM.I l< Mil 1 1 Orsat 

Sampling Train /' V //TO / Barometric Pressure oi 7. j f ©—' LEAK CHECKS in "Hg IMI IIN\I ,RINSEs ;coi?'-

Run Number Z ' Static Pressure <+/-) -~0 ,'3T INITIAL V 

VI1D VAC. 

FINAL W 

INIT. PITO 

n. CFM V 

n. CFM 

n. CFM 

S O 

Client Veolia ES Technical Solutions Probe/Pitot Number .£jftt£Vtffc f.r 

INITIAL V 

VI1D VAC. 

FINAL W 

INIT. PITO 

n. CFM V 

n. CFM 

n. CFM 

m f.r 

Facility Locution Sauget, IL Pitot Coctficient 

Filter Box No. 

Meter Box No. 

INITIAL V 

VI1D VAC. 

FINAL W 

INIT. PITO 

^C. 

n. CFM V 

n. CFM 

n. CFM ff,00 2- /Od 

Source /Mf/T *t V 

Pitot Coctficient 

Filter Box No. 

Meter Box No. 

INITIAL V 

VI1D VAC. 

FINAL W 

INIT. PITO T FINAL PITOT 

DATA 

+

/> &fTf 

Da,e /3-/*-7d<l« y 

Pitot Coctficient 

Filter Box No. 

Meter Box No. 

INITIAL V 

VI1D VAC. 

FINAL W 

INIT. PITO T FINAL PITOT 

DATA 

+

/> /CO 

Operator 

Stack Dta. - in 

Start Time 

Stop Time 

tiUUtobLf -t- tv>*«oL&f Orifice Coefficient 0 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple 

Imp Outlet TC ID; 

0 £> <& / 

INITIAL V 

VI1D VAC. 

FINAL W 

INIT. PITO 

FILTER 

FINAL PITOT 

Operator DATA pa 

Stack Dta. - in 

Start Time 

Stop Time 

Orifice Coefficient 0 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple 

Imp Outlet TC ID; 

MiMlim | IXKI . &JfC* 

Operator 

Stack Dta. - in 

Start Time 

Stop Time 

Orifice Coefficient 0 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple 

Imp Outlet TC ID; 

0***1 

Operator 

Stack Dta. - in 

Start Time 

Stop Time 

Orifice Coefficient 0 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple 

Imp Outlet TC ID; 

I ' m SHK'At.IL Final Purg eRate 

Operator 

Stack Dta. - in 

Start Time 

Stop Time 

Orifice Coefficient 0 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple 

Imp Outlet TC ID; 3P1J 1 Final PH 

h. LA M IB || TEMPERATUR E READINGS F | 1 1 % 

> n COMMENTS 

h. 

01 TN 

R VM 

% Ol L Iti f 

II 

1 1 % 

> n COMMENTS 

h. 

01 TN 

R VM 

% Ol L Iti f i> ! 0 

1 1 % 

> n COMMENTS 

T l ? on a J S 7 .** to 

r

-k n .t>3 /,<? 260 0-3 ^ 7 

3 o.65 /A *tZ8.t7 27 ( • 7 

H 1.1 •2^7 3 7 7 

5 i.(>s- as? F t 

L x<r so 0.49 I.Z5 si 

X 

SO 5C l

l . If f 2S¥ 38 (8'juA-/iy sou 

"2- 3<r €o I'l '263- 2&>.i 7 7 "7 

US' 2£?7 ;?£ 7 

^ £ •Z$8 7 

so <JT 2 0 / H O &

7 7 

<c to O-HS 263 2 6 7 S7 

-

VES019026 
AECO M 

UNIT f SAMPLE TRAIN MOISTURE RECOVERY DATA SHEET 

Reference Method / Sampling Train : 

Recovered by : NJ \fo (Ho^fi-iS Recovered by : .^J7/V\ AVUrtCtfJ ' Recovered by : <dii * t^lWlJ " 

RunNo . U'-f'rU Date: |>-lltl<>f Run No. U 4 — It X - Date : Run No. U«f-jV 3 Date: 

l . • " '—" T 

X A D Module No. : M | 

X A D Module No. : |0 1 ft X A D Module No. : P. 

Filter No. : <^\%& 0'tH>3>3 Filter No. : *T7 f f / ? <9,^flf Filter No. : "T/ rf 0 - W 

Im pinger No. and Volum e Im pinger No . an d Volum e Im pinger No . an d Volum e 

N o. 

Initial 

(mL) 

Final 

(mL) 

Rinse 

(mL) No. 

Initial 

(mL) 

Final 

(mL) 

Rinse 

(mL) No. 

Initial 

(mL) 

Final 

(mL) 

Rinse 

(mL) 

1 1 f 1 Sv 

2 / o o 

2 

| o o 

2 jOTJ 

3 /ot > 3 | 0 0 \ \ 0 |T>0 1 

4 0 i g o 

4 0 4 

0 

5 /OT ) 100 

I 

5 I O O J O © 5 /oe> /tro 

6 1 0 0 6 l o o r 6 

t o o 4 3 

7 7 7 

DIFF : DIFF : 

7 

DIFF : 

Total s M S o Totals *f£o Totals 

initial 

. (9) 

Final 

'(B) 

Initial 

(g) 

Final 

(g) 

Initial 

(g) 

Final 

(g) 

initial 

. (9) 

Final 

'(B) DIFF : 

Initial 

(g) 

Final 

(g) Dl F 

Initial 

(g) 

Final 

(g) DIFF : 

Silica 

G el 

Silica 

Gel /«. / 

Silica 

Gel 9.7 

Final Net Moisture Gain : 55 5 Final Net Moistur e Gain : Final Net Moisture Gain : 

CADocuments and Seitings\mllos\Desktop\(MoistiJre Recovery.xls]A 

VES019027 
Metho d 0023 A 

VES019028 
PCDD 

Veolii 

! PCDF Emij 

Method ( 

Run No. 

i ES Technical £ 

ssion Results -1 

)023A Sampling 

1 

(Olutions 

"EQ Basis - Front 

Parameters 

2 

Half 

3 

Date 

Start Time 

Stop Time 

16-Dec-09 

13:54 

16:59 

17-Dec-09 

12:30 

15:35 

18-Dec-09 

11:45 

14:50 

Units 

Sample Volume dscf 137.455 131.667 131.717 

Sample Volume m

3 3.89 3.73 3.73 

Moisture Content % v/v 35.6 36.4 36.0 

0 2 Concentration % v/v (dry) 12.60 12.40 12.30 

C 0 2 Concentration % v/v (dry) 5.66 4.87 5.54 

Isokinetics % 100 101 99 

Stack Flowrate dscfm 18,601 17,665 18,002 

PCDD/PCDF 

Parameters T E F (a) 

pg ng/m3 

TEQ 

P9 ng/m3 

TEQ 

pg ng/m3 

T EQ 

2,3,7,8-TCDD 1.00 0.33 8.3E-05 0.57 1.5E-04 0.38 1.0E-04 

1,2,3,7,8-PeCDD 0.50 14.1 1.8E-03 12.9 1.7E-03 17.7 2.4E-03 

1,2,3,4,7,8-HxCDD 0.10 22.3 5.7E-04 20.5 5.5E-04 27.0 7.2E-04 

1,2,3,6,7,8-HxCDD 0.10 64.5 1.7E-03 62.5 1.7E-03 84.3 2.3E-03 

1,2,3,7,8,9-HxCDD 0.10 37.2 9.6E-04 28.6 7.7E-04 41.3 1.1E-03 

1,2,3,4,6,7,8-HpCDD 0.01 364 9.4E-04 352 , 9.4E-04 515 1.4E-03 

OCDD 0.001 .263 6.8E-05 276 7.4E-05 377 1.0E-04 

2,3,7,8-TCDF 0.10 3.66 9.4E-05 3.66 9.8E-05 4.85 1.3E-04 

1,2,3,7,8-PeCDF 0.05 6.47 8.3E-05 6.57 8.8E-05 9.78 1.3E-04 

2,3,4,7,8-PeCDF 0.50 30.1 3.9E-03 26.4 3.5E-03 45.3 6.1E-03 

1,2,3,4,7,8-HxCDF 0.10 17.8 4.6E-04 17.9 4.8E-04 28.4 7.6E-04 

1,2,3,6,7,8-HxCDF 0.10 24.4 6.3E-04 24.0 I 6.4E-04 36,3 9.7E-04 

2,3,4,6,7,8-HxCDF 0.10 64.4 1.7E-03 61.0 1.6E-03 99.1 2.7E-03 

1,2,3,7,8,9-HxCDF 0.10 10.9 2.8E-04 10.4 2.8E-04 15.8 4.2E-04 

1,2,3,4,6,7,8-HpCDF 0.01 90.0 2.3E-04 91.6 2.5E-04 137 3.7E-04 

1,2,3,4,7,8,9-HpCDF 0.01 20.9 5.4E-05 21.4 5.7E-05 33.5 9.0E-O5 

OCDF 0.001 44.7 1.1 E-05 

i o r n o 

47.0 1.3E-05 68.1 1.8E-05 

o n c no 

X \J l^Lu JLJCfV£S ^Ug/Ul ) — 

TOTA L TEQ s (ng/m 3 @ 7 % 02 ) 

1 .oc-uz 

2.2E-02 2.1E-02 3.2E-02 

TOTA L TEQ s (g/s) 1.2E-10 1.1E-10 1.7E-10 

(a) U.S.EP A (1989) Toxic Equivalency Factor 

S:\_JOB\2009WeoliaVrest DataUJnit 4\[unit4_M0023A_0.4 slandard.xlslTEQS-FH 

VES019029 
Veolia 

PCDD / PCDF Emis 

Method 0 

ES Technical S 

.sion Results -1 

023A Sampling 

olutions 

EQ Basis - Back Half 

Parameters 

Run No. 1 2 3 

Date 16-Dec-09 17-Dec-09 18-Dec-09 

Start Time 13:54 12:30 11:45 

Stop Time 

1 Initc 

16:59 15:35 14:50 

Sample Volume 

units 

dscf 137.455 131.667 131.717 

Sample Volume m

5 3.89 3.73 3.73 

Moisture Content % v/v 35.6 36.4 36.0 

0 2 Concentration % v/v (dry) 12.60 12.40 12.30 

C 0 2 Concentration % v/v (dry) 5.66 4.87 5.54 

Isokinetics % 100 101 99 

Stack Flowrate dscfm 18,601 17,665 18,002 

PCDD/PCDF 

Parameters TEF (a) 

pg 'rig/m3 

TEQ 

pg ng/m3 

TEQ 

pg ng/m3 

T EQ 

2,3,7,8-TCDD 1.00 18.5 4.8E-03 24.0 6.4E-03 I 20.3 5.4E-03 

1,2,3,7,8-PeCDD 0.50 275 3.5E-02 327 4.4E-02 293 3.9E-02 

1,2,3,4,7,8-HxCDD 6.10 298 7.7E-03 266 7.1E-03 259 6.9E-03 

1,2,3,6,7,8-HxCDD 6.10 859 2.2E-02 791 2.1E-02 817 2.2E-02 

1,2,3,7,8,9-HxCDD 0.10 341 [ 8.8E-03 256 6.9E-03 347 9.3E-03 

1,2,3,4,6,7,8-HpCDD 0.01 2,580 6.6E-03 2,090 5.6E-03 2,380 6.4E-03 

OCDD 0.001 985 2.5E-04 711 1.9E-04 812 2.2E-04 

2,3,7,8-TCDF 0.10 86.5 2.2E-03 83.8 2.2E-03 85.5 2.3E-03 

1,2,3,7,8-PeCDF 0.05 126 1.6E-03 112 1.5E-03 141 1.9E-03 

2,3,4,7,8-PeCDF 0.50 578 7.4E-02 484 6.5E-02 647 8.7E-02 

1,2,3,4,7,8-HxCDF 0.10 264 6.8E-03 224 6.0E-03 263 7.1E-03 

1,2,3,6,7,8-HxCDF 0.10 343 8.8E-03 268 7.2E-03 343 9.2E-03 

2,3,4,6,7,8-HxCDF 0.10 796 2.0E-02 554 1.5E-02 749 2.0E-02 

1,2,3,7,8,9-HxCDF 0.10 86 2.2E-03 45.9 1.2E-03 70.8 1.9B03 

1,2,3,4,6,7,8-HpCDF 0.01 867 2.2E-03 638 1.7E-03 870 2.3E-03 

1,2,3,4,7,8,9-HpCDF 0.01 111 2.9E-04 57.5 1.5E-04 96.6 2.6E-04 

OCDF 0.001 165 4.2E-05 85.9 2.3E-05 135 3.6E-05 

TOTAL TEQs (ng/m3) = 

T O T A T TI H O C Cna/m3 fil 1 0/. n 1 = 

0.204 

0 3d1 

0.191 

O ^11 

0.221 

0 356 

TOTAL TEQs (g/s) 1.8E-09 

Uat) 1 1 

1.6E-09 1.9E-09 

(a) U.S.EPA (1989) Toxic Equivalency Factor 

S:t_JOBE009Weolia\Tesl DataUJnit 4\[uniM_M0023A_O..<! standard.xIsJTEQS-FH 

VES019030 
Veolia ES Technical Solutions 

Rotary Kiln Incinerator #4 

Method 0023A Sampling Parameters 

Run No. 1 

16-Dec-09 

13:54 

16:59 

2 

17-Dec-09 

12:30 

15:35 

3 

18-Dec-09 

11:45 

14:50 AVGS 

Date 

1 

16-Dec-09 

13:54 

16:59 

2 

17-Dec-09 

12:30 

15:35 

3 

18-Dec-09 

11:45 

14:50 AVGS 

Start Time j Units 

1 

16-Dec-09 

13:54 

16:59 

2 

17-Dec-09 

12:30 

15:35 

3 

18-Dec-09 

11:45 

Stop Time 14:50 AVGS 

1 

16-Dec-09 

13:54 

16:59 

2 

17-Dec-09 

12:30 

15:35 

3 

18-Dec-09 

11:45 

14:50 AVGS 

Nozzle Diameter inches 0.307 

30.20 

180.0 

130.657 

0.307 

30.00 

180.0 

128.873 

0.307 

29.65 

180.0 

131.253 

0.307 

Barometric Pressure in. Hg 

0.307 

30.20 

180.0 

130.657 

0.307 

30.00 

180.0 

128.873 

0.307 

29.65 

180.0 

131.253 

29.95 

Net Sampling Time min. 

0.307 

30.20 

180.0 

130.657 

0.307 

30.00 

180.0 

128.873 

0.307 

29.65 

180.0 

131.253 

180.0 

Volume Metered dcf 

0.307 

30.20 

180.0 

130.657 

0.307 

30.00 

180.0 

128.873 

0.307 

29.65 

180.0 

131.253 130.261 

Avg. DGM Temp. °F 44.2 55.6 58.9 52.9 

Avg Delta H in H2 0 1.80 1.69 1.75 1.75 

Avg Delta H in. Hg 0.1325 0.1245 0.1285 0.1285 

DGM Calibration Factor — 0.9910 0.9910 0.9910 0.9910 

Gas Sample Volume dscf 137.455 131.667 131.717 133.613 

Total Water Collected ml" 1613.0 1595.1 1569.5 1592.5 

Volume of Water Vapor scf 76.053 75.209 74.002 75.088 

Moisture (measured) % v/v 35.6 36.4 36.0 36.0 

Moisture (@ saturation) %v/v 99.2 99.9 101.0 loo.o 

Dry Mole Fraction, 100-%M -0.6438 0.6365 0.6403 0.6402 

C O z at Stack %dry 5.66 

12.60 

4.87 

12.40 

5.54 

12.30 

5.36 

0 2 at Stack %dry 

5.66 

12.60 

4.87 

12.40 

5.54 

12.30 12.43 

CO + N2 %dry 81.74 i 82.73 82.16 82.21 

Dry Molecular Weight lb/fb-mole 29.41 ' 29.28 f

 29.38 29.35 

Wet Molecular Weight Ib/lb-mole 25.35 25.18 I 25.29 .25.27 

Excess Air at Stack % 140.3 131.3 131.0 134.2 

Stack Diameter inches 48.0 48.0 48.0 48.0 

i Stack Area sq. in. 1809.6 1809.6 1809.6 1809.6 

Static Pressure in H2 0 -0.48 -0.50 -0.46 -0.48 

Stack Pressure in. Hg 30.16 29.96 29.62 29.91 

i Avg. Stack Temp. °F 389.4 389.2 391.8 390.1 

r Avg. Sqroot of Delta P — 0.8077 0.7759 0.7934 0.7923 

I SDE Average — 23.540 22.609 23.156 23.102 

Pitot Coefficient -

0.84 0.84 6.84 0.84 

Stack Gas Velocity afpm 3,669 3,547 3,646 j 3,621 

Stack Flowrate wet acfm 46,101 44,576 45,822 45,500 

Stack Flowrate wet scfm 28,892 27,756 28,117 28,255 

Stack Flowrate dscfm j i"8V6"6"l 17,665 18,002 18,089 

Isokinetics %

 1 100 101 99 100 

Meter Box No. — 2 

1.8010 

2 

1.8010 

2 

1.8010 

— 

Delta H @ 1 in. Hg 

2 

1.8010 

2 

1.8010 

2 

1.8010 ~ 

Field QA Ygc — 0.997 0.996 1.001 0.998 

[Deviation] Pre-Y % 0.6% 0.5% 1.0% 0.7% 

S:\_JO8\2009Weolia\Test DataUJnit 4\[unit4_MQ023A_0.4 slandard.xls]DATA 

VES019031 
Method 0023A Sampling Parameters 

PT 

R U N 1AVGS - - PCDDs / PCDFs R U N 2 AVG S - PCDDs/PCDF s R U N 3 AVG S - PCDDs/PCDF s 

PT DP SQRT 

DP 

DGM 

IN 

DGM 

OUT 

DH STACK 

TEMP 

DP SQRT 

DP 

DGM 

IN 

DGM 

OUT 

DH STACK 

TEMP 

DP SQRT 

DP 

DGM 

IN 

DGM 

OUT 

DH STACK 

TEMP 

a1 0.70 0.8367 40 42 1.90 392 0.64 0.8000 49 52 1.75 389 0.63 0.7937 67 67 1.75 392 

1 0.6S 0.8246 40 45 1.90 388 0.64 0.8000 50 56 1.75 387 0.60 0.7746 66 69 1.65 392 

a2 0.65 0.8062 41 47 1.80 388 0.66 0.8124 51 57 1.80 389 0.63 0.7937 65 68 1.75 395 

2 0.68 0.8246 41 47 1.90 390 0.66 0.8124 51 57 1.80 390 0.63 0.7937 64 66 1.75 393 

a3 0.72 0.8485 41 47 2.00 390 0.64 0.800D 51 57 1.75 . 392 0.65 0.8062 62 65 1.80 393 

3 0.68 0.8246 41 47 1.90 389 0.62 0.7874 51 57 1.70 391 0.68 0.6246 61 63 1.90 394 

a4 0.73 0.8544 42 47 2.00 389 0.64 0.8000 51 57 1.75 391 0.65 0.8062 59 63 1.80 393 

4 0.70 0.8367 42 47 1.90 390 0.70 0.8367 52 57 1.90 391 0.65 0.8062 58 62 1.80 393 

aS 0.67 0.8185 43 48 1.85 391 0.60 0.7746 52 57 1.65 389 0.60 0.7746 57 61 1.65 392 

5 0.65 0.8062 43 48 1.80 390 0.65 0.8062 52 58 1.80 389 0.65 0.8062 56 59 1.80 391 

a6 0.57 0.7550 42 48 1.55 387 0.50 0.7071 53 58 1.40 385 0.45 0.6708 55 59 1.25 390 

6 0.55 0.7416 42 48 1.50 387 0.50 0.7071 53 59 1.40 383 0.45 0.6708 54 58 1.25 390 

b1 0.70 0.8367 42 47 1.90 386 0.62 0.7874 54 57 1.70 390 0.65 0.8062 53 57 1.80 390 

1 0.70 0.8367 42 47 1.90 391 0.68 0.8246 53 58 1,90 390 0.68 0.8246 53 59 1.90 388 

b2 0.68 0.8246 42 48 1.90 389 0.65 0.8062 53 59 1.80 387 0.68 0.8246 53 59 1.90 389 

2 0.72 0.8485 42 48 2.00 387 0.68 0.8246 54 59 1.90 390 0.74 0.8602 53 59 2.00 392 

b3 0.68 0.8246 42 47 1.90 391 0.68 0.8246 53 59 1.90 387 0.72 0.8485 53 59 2.00 392 

3 0.67 0.8185 42 47 1.85 390 0.65 0.8062 54 60 1.80 391 0.70 0.8367 52 59 1.90 393 

b4 0.65 0.8062 42 47 1.80 390 0.65 0.8062 54 60 1.80 391 0.68 0.8246 52 59 1.90 392 

4 0.65 0.8062 41 47 1.80 392 0.68 0.8246 54 61 1.90 392 0.68 0.8246 53 60 1.90 392 

bS 0.60 0.7746 41 46 1.65 392 0.60 0.7746 54 62 1.65 390 0.63 0.7937 53 60 1.75 392 

5 0.60 0.7746 41 47 1.65 390 0.40 0.6325 55 63 1.65 390 0.63 0.7937 53 60 1.75 392 

b6 0.53 0.7280 41 47 1.45 388 0.40 0.6325 55 63 1.10 389 0.55 0.7416 53 59 1.50 392 

6 0.53 0.7280 41 47 1.45 388 0.40 0.6325 56 63 1.10 388 0.55 0.7416 54 60 1.50 390 

A V G 0.65 0.8077 44.2 1.80 389 0.61 0.7759 55.6 1.69 389 0.63 0.7934 58.9 1.75 392 

VES019032 
AECOM 

Sampling Train fY[ 

EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Run Number 

Client Veolia ES Technical Solutions 

Facility Location 

Source 

U>te 

Operator 

Stack Dia. - in. 

SUrt Time 

Slop Time 

Sauget, IL. 

( I N r t # 4 : 

ZOOS . _ 

Barometric Pressure 

Static Pressure (+/-) 

Probe/Pilot Number 

Pilot Coefficient 

Filter Box No. 

Meter Box No. 

Orifice Coefficient (Y) 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple IP; 

Imp Outlet TC ID: 

-Q. T8 

» 5 -</Z> 

LEAK CHECKS in "Hg 

INITIAL VAC. /(g 

MID VAC. 

FINAL VAC. 

CFM g-^ ^ 

CFM 

CFM G.GO—\ 

INIT. PITOT FINAL PITOT 

FILTER DATA 

ifSBMSifii ! 

IMflNCfRVniS I 

IMI I FINAL', *: ,/| H 

Final Purge Bute /(\-

1 Orsat 

IPScri:-;, ^sOii:-

VES019033 
\ 

AECO M EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Sampling Train 

Run Number 

Client' Veolia ES Technical Solutions 

Facility Location 

Source ___ 

Date 

Operator 

Stack Dia. - in. 

Siart Time 

Stop Time 

Sauget, IL 

Barometric Pressure 

Static Pressure (+/-) "_Q'5P 

fVobe/P.tol Number 

Pitot Coemclent Q. 

Filter Box No. 

Meter Box No. 

Orifice Coefficient (Y) 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple ID: 

Imp Outlet TC ID: 

LEAK CHECKS in "Hg 

INITIAL VAC. 

MID VAC. 

FINAL VAC. 

CFM Qj00, 

CFM 

CFM 

<G>,o&5 

FINAL PITOT 

+ 

y 

FILTER DATA 

XAD-<f 

?4NUMBf,KJg 

MPIF 

IO NT 

3D 

C CK 

TTM 

R r E 

lOwaHSlnlwi 

T7T 

A % FK 

rag: 

'It 

TEMPERATUR E READINGS, "F 

2 2 £ 

SILICA-GEL: 

S F 

OVFN 

K( M 

It (II I L 

'•V'Ml I HI | V\< IHJMg 

S X 

RINSgl 

Orsat 

..0 2 

<•/.? 

Final Purge Rate 

Final PH 

&jr^$P?:J§ 

COMMENTS : 

^ 5 " 

SD 

7 r > 2 £X 43 

a i r 2< <0-t>L> t. 6(1.11 

2 2 

£ X si Sizee io -vs- OM l t LIS ' 

h i 

g^3 y/ *3?3 - r 

.ML 2-Sf 2 5 

vs- sitre.Ly- ^ 2 131 

me tQ 

IPS 

_______ _ P T 

ft- /t>7,<_ ft.feO3.1E~ 

-IS 

2±L 

X1L 

_ _ 

2ML ~ X 

1 £ 

_ 

5X. 

_5rt».5jL . 

2$. Id I 2k fa')- 53 X _ 

x X 5 ssn 

1 3 r 

e3&£> 

2 7 / S 3 

i3o too £r>Jr rf bX- Ml 39c9 26& 

53 & 6 

/as- /S bC 

0A8-

3i57 O 

I S 

4 « i Z 1 Z 

39 / 26& 

2 £ 

^ 1 

x ^ 

TITf7 

Uga /S?sr 

3 1 ( 

/•t 5 

2ML 

JSLQ. 

Z(fQ> 

-iXfp 

i t 

5± JeO 

lO 

6. 5 : 

3 : 

X X €WLA\ ,6 

<?2.t>.06 

xsx 5 T 

X I 

- X 

VES019034 
AECO M E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Client 

Barometric Pressure 

Static Pressure (+/-) 

Veolia ES Technical Solutions 

Facility Location 

Source 

Date 

Operator ____ 

Stack Dia. - in. 

Start Time 

Stop Time 

Sauget, IL 

Probc/Pifot Number ^S/MS"~V£>~ 

Pitot Coefficient ^ ~W$l$Sit 

Fitter Box No. _>B>ff_'' ' 

Meter Box No. 

Orifice Coefficient (Y) 

Delta H @ 

Nozzle Size/No. 

LEAK CHECKS in "Hg 

INITIAL VAC. /<£ : 

MID VAC. 

FINAL VAC. ± 

0-60/ 

C FM ty.gtf g 

C FM e.eof 

FINAL PITOT 

XAD Thermocouple ID; \cA-£>~"G 

FILTER RATA 

^,'IMP1NGER,VQI'S )} | 

, FINAL 

ICQ 

Silica. 

a,:.:..,-:../Stt.tc.AC.KL. 

RINSE 

Orsat 

: .Cb2. . 02 .: 

r . r n.j 

Final Purge Rate 

VMPII 

IODsl 

• fit k 

TIM* 

MLficirv 

Hi Alt 

Dcllal n"i>c 

HAS MEIER . .11 TEMPERATUR E READINGS , ° F | it 

in. He 

COMMENTS 

VMPII 

IODsl 

• fit k 

TIM* 

MLficirv 

Hi Alt 

Dcllal n"i>c m PROBE .; mm/A 

^S^A'SiMffTEita^isi 

it 

in. He 

COMMENTS 

VMPII 

IODsl 

• fit k 

TIM* 

MLficirv 

Hi Alt 

Dcllal n"i>c m PROBE .; mm/A 

it 

in. He 

COMMENTS 

~trr- r9 7. . * ?<r <f?3,2X7- Ml 5 3 ze> 6 7 to 

a r /S " G&O i ? _ 

• z o 1 2 5 6 0 7 S 

/.<T /.75 ~ 5 _ & 

e?.ts •2-4 / s V &f _ " or 

Q4<f- <?f Cf 

s i r D.L& /.f o IOOV 55 2^t_) (pf 6 _ 4 

<o.« - o/* r (Jo ,000.2.— (,$ <-\ 

< a r c o i t o 1 OHM s y - S3 °L 

• o-oo lon.t-o % Vr 2r> 3 * r f i %/ 

67.C IS O-0>5 i.fit) - 5 ? 7 

A C 6 MS I.IS~ tRO 5 3 ~ ? 7 

1033.OB 2?6 2Ce( 7 SWe. IZ IS~ 

><^** : Ote^ k 

fc?l ?/> <m /oJ7 . 7&P - /yro <_ o 5 V -

~ 7 

r?s~ tog • & (p8 1 96 his. 2 G / Sf 

a r /ru " 0 -6 8 'l/l O 3 8 9 2 - 7 J>-> / o 

'OS f&> i < o '/OSi-lfe i s ~ " 7 SO tO 

110 " £>.73- 39" - " 7 31-

^ 1 

iO 

QiS iv: " e<io i . i 2 5 -

^ 7 

5 7 LO 

/ 2 T /«fi -

\-°, • - ^ 6 10 

/ Y J A 10-16.— • 5 3 to 

S T /5D /_7< - f>>&S .-75 - •^b C 5 5 3 c 

(Si r A< • Dr_> 3 39- - 6 

ffc_~ ills C55 I.St) • _ x 

f J r — fh€ ISO ao 

U014SY] 

1 

7 

VES019035 
AECOM 

SAMPLE TRAIN MOISTURE RECOVERY DATA SHEET 

Heference Method / Sampling Train : Ih 2 $ J s 

Recovered by : of f to /Hdjt^li Recovered by : ^fiftv 'fH'tffli- / Recovered by : (ftAv 0 

Run No. Utf - " ( Da t e : |^/|fc(»f Run No. U^'P " Date.: (>//?/ a

f Run No. Date: ^^/" ? 

XA.D Module No. : iMtA^A'Oll 1 X A D Module No . : 6 « y i # kO^HI^ X A D Module No. : A"0 9 / / {<T 

Filter No. : rVv~cjW«( <sf Filter No. : Filter No. : tVe -C l eewwJL fi- F 

Im pinger No. an d Volum e Im pinge r No. am i Volum e Im pinger No. and Volum e 

N o . 

Initial 

(mL) 

Final 

(mL) 

Rinse 

(mL) No. 

Initial 

(mL) 

Final 

(mL) 

Rinse 

(mL) No. 

Initial 

(mL) 

Final 

(mL) 

Rinse 

(mL) 

1 1 

) ^ 

1 0 

m 

2 2 gjSO 

If to 

*) 

2 2-00 

3 3 /(T O 3 I T O 

4 0 4 0 / 

4 

0 

5 5 5 

6 6 6 

7 7 7 

DIFF : DIFF : 

7 

DIFF : 

Totals Totals Totals 

Initial 

(g) 

Final 

(g) ' NInitial (g) 

Final 

(g) 

lliillillPll s Initial. 

(g) 

Final 

(g) 

Initial I 

(g) 

Final 

(g) DIFF : ' NInitial (g) 

Final 

(g) DIFF 

lliillillPll s Initial. 

(g) 

Final 

(g) DIFF : 

a 

G e l 

Silica 

G el 

Silica 

Gel 3 f U ? 

Final Net Moisture Gain : Final Net Moisture Gain : Final Net Moisture Gain : 

C:\Documents and Seltings\milos\Desktop\[Moisture Recovery.xls]A 

• US C Do^bl t col l t*>nk**i *Jrf 

falls' 'l^ktsp+fify 

~ fvUrWH* - 01* 3 S"S 7 

-{^vr X 

VES019036 
Method 25A 

VES019037 
AVERAGE D CE M DATA Jo b Number: 60133216 Start Time : 14:07:00 

R u n ID: R1B Start Date: 12/16/09 

Date Tim e ~ TH C 

12/16/2009 14:09:00 0.56 

12/16/2009 14:11:00 0.5 

12/16/2009 14:13:00 0.56 

12/16/2009 14:15:00 0.47 

12/16/2009 14:17:00 0.48 

12/16/2009 14:19:00 0.42 

12/16/2009 14:21:00 0.39 

12/16/2009 14:23:00 0.42 

12/16/2009 14:25:00 0.46 

12/16/2009 14:27:00 0.44 

12/16/2009 14:29:00 0.4 

12/16/2009 14:31:00 0.31 

12/16/2009 14:33:00 0.42 

12/16/2009 14:35:00 0.32 

12/16/2009 14:37:00. 0.37 

12/16/2009 14:39:00 0.24 

12/16/2009 14:41:00 0.19 

12/16/2009 14:43:00 0.24 

12/16/2009 14:45:00 0.24 

12/16/2009 14:47:00 0.29 

12/16/2009 14:49:00 0.28 

12/16/2009 14:51:00 0.31 

12/16/2009. 14:53:00 0.29 

12/16/2009 14:55:00 0.34 

12/16/2009 14:57:00 0.43 

12/16/2009 14:59:00 0.6 

12/16/2009 15:01:00 0.63 

12/16/2009 15:03:00 0.73 

12/16/2009 15:05:00 0.75 

12/16/2009 15:07:00 0.72 

Averag e Value : 0.43 

Correcte d Average : .52 

VES019038 
AVERAGE D CE M DATA Jo b

 Number: 60133216 Start Time : 12:51:00 

R u n ID: R2B Start Date : 12/17/09 

Date Tim e T H C 

12/17/2009 12:53:00 0.35 

12/17/2009 12:55:00 0.43 

12/17/2009 12:57:00 0.49 

12/17/2009 12:59:00 0.45 

12/17/2009 13:01:00 0.45 

12/17/2009 13:03:00 0.52 

12/17/2009 13:05:00 0.54 

12/17/2009 13:07:00 0.57 

12/17/2009 13:09:00 0.6 

12/17/2009 13:11:00 0.57 

12/17/2009 13:13:00 0.52 

12/17/2009 13:15:00 0.43 

12/17/2009 13:17:00 0.52 

12/17/2009 13:19:00 ! 0.52 

12/17/2009 13:21:00 j 0.51 

12/17/2009 13:23:00 ' 0.53 

12/17/2009 13:25:00 0.47 

12/17/2009 13:27:00 0.51 

12/17/2009 13:29:00 0.52 

12/17/2009 13:31:00 0.51 

12/17/2009 13:33:00 0.45 

12/17/2009 13:35:00 0.51 

12/17/2009 13:37:00 0.57 

12/17/2009 13:39:00 0.51 

12/17/2009 13:41:00 0.51 

12/17/2009 13:43:00 0.51 

12/17/2009 13:45:00 0.53 

12/17/2009 13:47:00 0.49 

12/17/2009 13:49:00 0.49 

12/17/2009 13:51:00 0.5 

Averag e Value : 0.5 

Correcte d Average : .55 

VES019039 
j 

/ 

AVERAGE D CE M DATA

 Jo b Number :

 60133216 Start Time : 11:45:00 

R u n ID: R3B Start Date : 12/18/09 

Date Tim e T H C 

12/18/2009 11:47:00 0.14 

12/18/2009 11:49:00 0.06 

12/18/2009 11:51:00 0.12 

12/18/2009 11:53:00 0.13 

12/18/2009 11:55:00 0.16 

12/18/2009 11:57:00 0.15 

12/18/2009 11:59:00 0.13 

12/18/2009 12:01:00 0.16 

12/18/2009 12:03:00 0.18 

12/18/2009 12:05:00 0.17 

12/18/2009 12:07:00 0.17 

12/18/2009 12:09:00 0.15 

12/18/2009 12:11:00 0.15 

12/18/2009 12:13:00 0.12 

12/18/2009 12:15:00 0.15 

12/18/2009 12:17:00 j 0.14 

12/18/2009 12:19:00 0.11 

12/18/2009 12:21:00 0.04 

12/18/2009 12:23:00 0.15 

12/18/2009 12:25:00 0.17 

12/18/2009 12:27:00 0.19 

12/18/2009 12:29:00 0.21 

12/18/2009 12:31:00 0.18 

12/18/2009 12:33:00 0.12 

12/18/2009 12:35:00 0.19 

12/18/2009 12:37:00 0.09 

12/18/2009 12:39:00 0.14 

12/18/2009 12:41.00 0.12 

12/18/2009 12:43:00 0.14 

12/18/2009 12:45:00 0.18 

Averag e Value : 0.14 

Correcte d Average : . .24 

VES019040 
o 

VES019041 
AECOM 

AppendixC 

Reference Method Calibrations, Verifications, and Certifications ^ 

(...) 

VES019042 
AECOM 

Calibrator: MikeO'toole Reference Thermometer: SYR-CAL-1 

| Filter Bo x Calibration 

Hot Box #5 Hot Box #8D 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/olaced in servic Pre 1995 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/placed in servio Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 8-Jan-09 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

67 250 Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Reference 69 250 Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

66 249 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 249 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 1 1 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 0 1 

Hot B< JX#6 Hot Box #9 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/placed in servic Pre 1995 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/placed in servio Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 8-Jan-09 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 250 Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Reference 68 251 Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 250 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

68 250 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 0 0 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 0 1 

Hot Box #7 Hot Box #10 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/placed in servic Pre 1995 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/placed in servio Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 8-Jan-09 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

68 250 Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Reference

71 250 Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 249 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

71 250 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) -1 1 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 0 0 

Hot Be )X#7A Hot Box #11 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

DatR rHCBived/Dlaced in servic Pre 1995 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/placed in servio Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 7-Jan-09 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 250 Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Referenc 70 251 e Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 249 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 250 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 0 1 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 1 1 

Hot E ox #8 

Manufacturer: Anderson NUTEC H 

Serial No.: N/A 

Date received/oiaced in servic Pre 1995 

Calibration Date: 8-Jan-09 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Reference Temperatures 69 250 

Actual Temperatures 

Temp Difference (tol. = +-2) 

69 248 

Reference Temperatures 

Actual Temperatures 

Temp Difference (tol. = +-2) 0 2 

Checked amph connector, t-couple and plugs 

QC checked by S Milo 2/9/09 

VES019043 
AICO M 

DRY GAS METER CALIBRATION 

Meter Box No.: 

Check one: 

Annual Calibration Recalibration 

Date: 7/10/2009 

Operator: S. Milo 

Barometric Pressure: 29.61 (in Hg) 

Theoretical Critical Vacuum: 14.06 (in Hg) 

Manufacturer: Environmental Supply 

Date Received/Placed in service: 2002 

Serial No.; 2 

Pretest Leak Checks 

Allowable Actual 

Positive 0 i 0.00 

(at 5-7ln.H:0) In. HjO per min. 

Negative 0 0.000 

Cat 3 In. Hg) cfm cfm 

DRY GAS METER DATA CRITICAL ORIFICE DATA 

Volume* Tern P Critical K'Orifice Actual Ambient Temperature 

Time Initial Final Total Initial Final Orifice Callbratior Vacuum Initial Final Averaqe 

(in H20) (min) <ftJ

) (tei (ft1

) °F *F Serial # Coefficient fln-Hg) "F •F "F 

0.29 20 0.05O 6.378 6.328 71 73 40 0.240 24 70 71 71 

0.64 15 6.402 13.325 6.923 72 76 48 0.350 22.5 72 72 72 

1.15 15 13.396 22.533 9.137 75 77 55 0.460 21 73 72 ' 73 

1.90 10 22.577 30.451 7.874 77 79 63 0.594 19 73 72 73 

3.70 10 30.507 41.271 10.764 78 32 73 0.809 16 73 74 74 

CORRECTED VOLUME 

Dry Gas 

Meter 

Vm (std ft3) 

Critical 

Orifice 

Ver (std ft") 

DRY GAS METER 

CALIBRATION 

FACTOR Y 

DRY GAS METER 

CALIBRATION 

FACTOR AH@ 

6.259 . 6.212 0.993 0.001 1.691 -0.111 

6.331 6.779 0.992 0.00 1.762 -0.039 

8.989 8.919 0.992 0.00 1.830 0.028 

7.732 7.668 0.992 0.00 1.818 0.02 

10.582 10.446 0.987 0.00 1.907 0.11 

1) For valid test rasults, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above. 

2) The Critical Orifice Coefficient, K, must be entered in English units, (ft)A3*(deg R)A0.5/(fln.Hgnrr.iri)). 

3) The minimum number of sample volume required per orifice is 5 cubic feet 

4) For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of individual values from the average is ±0.02 

5) For Orifice Calibration Factor AH@, the orifice differential pressure in inches of H20 lhat equates to 0.75 cfm of air at 63 F and 29.92 inches of Hg, 

acceptable tolerance of individual values from the average fs ± 0.2. 

Dry Gas Meter Thennocouple calibration 

Ref. TC ID# REF -SYR -TC2 Inlet ID*: 002-IN OutletlD* 002-OUT 

Rer. Source Ref, T •F °F A 

Amb. Air 65 66 -1 66 1 

Hot Water 118 118 0 117 -1 

Notes: 1) Hot Water to be in the ra igeof1Q4- 22 °F. 

2) Tolerance allowed for all thermocouple individual readings: ± 5.4 °F 

3) Tolerance allowed for all potentiometer individual readings: ± 2 °F 

Potentiometer Calibration 

Low 100 "F 99 

Mid 400 "F 400 

High 900 °F 899 

k„t,*i=>? -

s , K)— — 

^+46 0 tl(llJ) 

VES019044 
AZCOM 

Calibrator: 

Date: 

Steven Milo 

12/16/2008 

Reference Thremometer ID: CL-1000 

Last Imolrmer Thermocouple Calibration 2007 

Thermocouple Reference Difference (+/-2°) Thermocouple Reference Difference (+/-2°) 

LI-1 Hot 210 212 -2 LI-18 Hot 210 212 -2 LI-1 

Cold 32 33 -1 

LI-18 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/placed in service: Pre 1990 

, 

LI-3 Hot 211 213 -2 LI-20 Hot 211 212 -1 LI-3 

Cold 32 32 0 

LI-20 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-4 Hot 212 213 -1 LI-22 Hot 213 212 1 LI-4 

Cold 32 32 0 

LI-22 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/placed in service: Pre 1990 

LI-8 Hot 212 213 -1 LI-22A Hot 210 212 -2 LI-8 

Cold 32. 32 0 

LI-22A 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial Mo.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

Hot 0 LI-24 Hot 210 212 -2 

Cold 0 

LI-24 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: ' Pre 1990 Date received/placed in service: Pre 1990 

Hot 0 Lt-25 Hot 212 212 0 

Cold 0 

Lt-25 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-13 Hot 210 212 -2 LI-28 Hot 213 212 1 LI-13 

Cold 33 32 1 

LI-28 

Cold 32 32 0 

Manufacturer: Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/Dlaced in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-15 Hot 210 212 -2 LI-15 

Cold 32 32 0 

Manufacturer: Anderson NUTECH 

Serial No.: 

Date received/placed in service: Pre 1990 

After calibration shower heads were cleaned and leak checked 

QC check S. Milo 

VES019045 
Calibrator: 

Date: 

Bill Hardy Reference Thremometer ID: CL-1000 

1/18/2010 

Last ImDinaer Thermocouple Calibration 2007 

Thermocouple Reference I Difference (+/- 2°) Thermocouple Reference Difference (+/- 2°) 

LI-1 Hot 210 212 -2 LI-20 Hot 211 212 -1 LI-1 

Cold 32 32 0 

LI-20 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/olaced in service: Pre 1990 

LI-3 Hot 212 212 0 LI-22 Hot 211 212 -1 LI-3 

Cold 32 32 0 

LI-22 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: 

Serial No.: Serial No.: 

Date received/placed In service: Pre 1990 Date received/placed in service: Pre 1990 

LI-4 Hot 210 212 -2 L1-22A Hot 211 212 -1 LI-4 

Cold 32 32 0 

L1-22A 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couole 2006 Date received/placed in service: Pre 1990 

LI-13 Hot 212 212 0 LI-24 Hot 211 212 -1 LI-13 

Cold 33 32 1 

LI-24 

Cold 33 32 1 

Manufacturer: Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed In service: Pre 1990 

LI-15 Hot 211 212 -1 LI-25 Hot 210 212 -2 LI-15 

Cold 33 32 1 

LI-25 

Cold 33 32 1 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date rsceived/olaced in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-18 Hot 210 212 -2 LI-28 Hot 211 212 -1 LI-18 

Cold 33 32 1 

LI-28 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

After calibration shower heads were cleaned and leak checked 

QC check S. Milo 

VES019046 
AECOM 

SAMPLE PROBE CALIBRATION DATA FORM 

TYPE "S" PITOT TUBE ASSEMBLY AND NOZZLE 

Thermocouple Calibration 

PROBE 10: 

S-NMD 

Rtltnncs 

ThamudiiWr 10 

PROBE ENSR RTD #2131035 Omesa CI1000,006022200 Omega CI1000. #08022200 10: 

S-NMD 

Rtltnncs 

ThamudiiWr 10 

Bcglng WalW Tub*Flumes [M'. SOO" •) 

PROBE 10: 

S-NMD 

. •'.J^,\^1.:

 F IO.K. P.ill, .*iV.-.^£««.»,-t.'i? 

'?l*«>m»./:- . L>.-R«toTM\,-^;**TM-;*.-JiiSriTC... .w . .. .• .Jw;,^ 

=V?-'.^'';:r'^.^ . fc» .;p*Hi>*i": 

.LV^.t'>^.^^KW^i'!i*.=e:. ... •* - ' . .•;•.•» Data: 1/26/2009 34 274 34 274 0 212 373 212 373 Q.O 451 608 4 5 0 505 -0.1 

Am Mini TtfflMihn Q 

S-MS-4D 34 274 34 274 0 212 373 212 373 0.0 451 506 450 505 -0.1 

Am Mini TtfflMihn Q 

S-MS-4D 

34 274 34 274 0 212 373 212 373 0.0 451 506 4 5 0 505 -0.1 

(MHM: 34 274 34 274 0 212 373 212 373 0.0 451 506 450 505 -0.1 

"Pitot Tube Calibration: ^ 

••8M« Indlcaiuna lav«l pMltton for 

otatsmtnlneT th*n ealeulet* Z. 

Level and perpendicular 

Obstruction 

Damaged 

a, (-10"S a,s+10") 

o2 (-10° £ aj £ +10') 

R, (-5° s ft, s + 5") 

z = ATany(±s 0.125") 

W « ATan9(±£ 0.O3125") 

D, (3/16 < D,s 3/6") 

A 

A/2D, (1.05 s P A /D,£ 1.5) 

0.000 

•Pito t Tube t o NtibjMHion : 

|Pi TUX a 

1) Plot to nozzlt wpa rattan X 1*? 

2) Thermocouple to pitot separation Z >3f4" 075 

3) Pitot end ID probe union distance Y »3.0" 3.37S 

iv_ >V •*.#{? j -" * .•*a? ^grob e Ipfprjjtion' 

Manufacturer: 

Data Received and placed In Service: 

[Condition of Probe vrfien placed In service: NEW 

p-e-1595 

QA/QC Check 

Completeness . Legibility 

certify that the TypnS pitot tube/probe fD# SM5-4D 

I criteria and/or applicable design features and Is hereby asalflned a pitot tube calibration factor C„of Q.B4 

RECONDITIONED (circle one) 

Accuracy _X _ 

„ meets or exceeds all Specifications, 

Specifications _X _ Reasonableness „ X, 

Certified bv: Slevn Milo 1J2B/09 

Perwnnei (Signature/Date) 

Steven Milo 2/18/09 

Team Leader (Signature/Date) 

construction oritetii for an isolated "S" type pitot are within given tolerances prescribed in 

iQuality Assurance Handbook for Air Pollution Measurement Systems: Volume [II, Stationary Source-Spedfio Methods. 

isweOO/R-M/OMc. September 1994 

VES019047 
AECOM 

A/15 Thermocouple Calibrations - 2009 

Date: 12/16/08 

BP: 30.08 

Reference Thermometer ID#: 

Manufacture: 

Date placed in Service: 

Calibrator: Steven Milo 

Ambient Temp (F): 65 

CL-1000 Fluke Digital RTD 2131035 

Fluke 

Pre 1980 

Ice Bath Boiling Water 

Thermocouple 

ID# 

Reference 

Temp 

X A D 

Temp 

Temp 

Difference 

Tol = +- 2 F 

Reference 

Temp 

X A D 

Temp 

Temp 

Difference 

Tol = +-2 F 

M5-TC1 212 212 0 32 33 1 

M5-TC2 212 211 -1 32 33 1 

XAD-6 32 32 0 213 212 -1 

XAD- 7 32 32 0 213 212 -1 

Q C check S. Milo 

VES019048 
AECOM 

MS Thermocouple Calibrations - 2010 

Date: 1/17/2010 

BP: 30.08 

Reference Thermometer ID#: 

Manufacture: 

Date placed in Service: 

Calibrator: Bill Hardy 

Ambient Temp (F): 65 

CL-1000 Fluke Digital RTD 2131035 

Fluke 

Pre 1980 

Ice Bath Boiling Water 

Thermocouple 

ID# 

Reference 

Temp 

X A D 

Temp 

Temp 

Difference 

Tol = +-2 F 

Reference 

Temp 

X A D 

Temp 

Temp 

Difference 

Tol'=+-2 F 

M5-TC1 32 33 1 212 212 0 

M5-TC2 32 33 1 212 211 -1 

XAD- 6 32 32 0 213 212 -1 

XAD-7 32 32 0 212 212 0 

Q C check S. Milo 

VES019049 
DAILY CALIBRATION REPORT 

Date: 12/16/2009 

Span 

Param Value 

C02 11 

THC 9 

Calibration Error = 

System Bias = 

Mid-Gas 

Standard 

S.02 

5.13 

Analyzer 

Zero Response 

0.01 

N/A 

Start Time: 08:49:14 

End Time: 10:09:30 

Analyzer 

Mid Response 

5.01 

N/A 

Zero 

Cal Error 

0.1% 

0.0% 

Methods: 3A, 6C, 7E and 10 

Job Number: 121609 

Mid 

Cal Error 

-0.1% 

0.0% 

System 

Zero Response 

0.03 

0. 

100% x (Analyzer Response - Cylinder Gas Standard Value) / (Span Value) 

100% x (System Response - Analyzer Response) / (Span Value) 

For THC Measurements: 

Calibration Error = 100% x (System Response - Cylinder Gas Standard Value) / (Cylinder Gas Standard Value) 

System Bias = 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Mid Response 

5.08 

5.13 

System 

Zero Bias 

0.1% 

0.0% 

System 

Mid Bias 

0.6% 

0.0% 

VES019050 
CALIBRATION CHEC K REPORT 

Run ID: R1A Date: 12/16/2009 

Start Time: 09:44:39 

E nd Time: 12:55:32 

E P A Methods: 3A, 6C, 7E and 10 

J ob Number: 121609 

Analyzer Analyzer System System System System System System System System 

Zero Mid Pre-Zero Pre-Mid Pre-Zero Pre-Mid Post-Zero Post-Mid Post-Zero Post-Mid 

Param Response Response Response Response Bias Bias Response Response Bias Bias Zero Drift Mid Drift 

C02 0.01 5.01 0.03 5.08 0.1% 0.6% 0.05 5.11 0.3% 0.9% 0.2% 0.3% 

THC WA N/A 0. 5.13 0.0% 0.0% -0.1 5.13 -1.1% 0.0% -1.1% 0.0% 

System Bias= 100% x (System Response - Analyzer Response) / (Span Value) 

System Drift= 100% x (System Post Response - System Pre Response) / (Span Value) 

For THC Measurements: 

System Bias= 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Avg-Zero 

Response 

0.04 

-0.05 

System 

Avg-Mid 

Response 

5.1 

5.13 

VES019051 
DAILY CALIBRATION REPORT Start Time: 0B:54:24 Methods: 3A, 6C, 7E and 10 

Date: 12/17/2009 En d Time : 09:3°:38 Job Number: 121709 

Span 

Param Value 

C02 11 

THC 9 

Calibration Error = 

System Bias = 

Mid-Gas 

Standard 

5.02 

5.13 

Analyzer 

Zero Response 

0 

N/A 

Analyzer 

Mid Response 

5.1 

N/A 

Zero 

Cal Error 

0.1% 

-0.3% 

Mid 

Cal Error 

0.8% 

-0.7% 

System 

Zero Response 

-0.02 

-0.03 

System 

Mid Response 

5.08 

5.09 

System 

Zero Bias 

-0.2% 

-0.3% 

System 

Mid Bias 

-0.2% 

-0.4% 

100% x (Analyzer Response - CylinderGas Standard Value) / (Span Value) 

100% x (System Response - Analyzer Response) / (Span Value) 

For THC Measurements: 

Calibration Error = 100% x (System Response - Cylinder Gas Standard Value) / (CylinderGas Standard Value) 

System Bias = ' 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

VES019052 
CALIBRATION CHEC K REPOR T Start Time: 11:02:50 EPA Methods: 3A, 6C, 7E and 10 

Run ID: R2B Date: 12/17/2009 End Time: 15:59:08 Job Number: 121709 

Analyzer Analyzer 

Zero Mid 

Param Response Response 

C02 0 5.1 

THC N/A N/A 

System Bias' 

System Drift' 

System System System System System System System System 

Pre-Zero Pre-Mid Pre-Zero Pre-Mid Post-Zero Post-Mid Post-Zero Post-Mid 

Response Response Bias Bias Response Response Bias Bias 

0.02 5.1 0.2% 0.0% 0.01 5.08 0.0% -0.2% 

-0.07 5.06 -0.8% -0.8% -0.01 5.03 -0.1% -1.1% 

100% x (System Response - Analyzer Response) / (Span Value) 

100% x (System Post Response - System P.re Response) / (Span Value) 

For THC Measurements: 

System Bias= 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

Zero Drift 

-0.1% 

0.7% 

Mid Drift 

-0.2% 

-0.3% 

System 

Avg-Zero 

Response 

0.02 

-0.04 

System 

Avg-MId 

Response 

5.09 

5.05 

VES019053 
DAILY CALIBRATION REPORT Start Time: 08:50:13 Methods: 3A, 6C, 7E and 10 

Date: 12118/200S Ent l Time: 09:30:35 Job Number: 121809 

Param 

C02 

THC 

Span 

Value 

11 

9 

Mid-Gas 

Standard 

5.02 

5.13 

Analyzer 

Zero Response 

0.01 

N/A 

Analyzer 

Mid Response 

5.01 

N/A 

Zero 

Cal Error 

0.2% 

0.0% 

Mid 

Cal Error 

-0.1% 

0.7% 

System 

Zero Response 

-0. 

0. 

Calibration Error = 100% x (Analyzer Response - Cylinder Sas Standard Value) / (Span Value) 

System Bias = 100% x (System Response - Analyzer Response) / (Span Value) 

For THC Measurements: 

Calibration Error = 100% x (System Response - Cylinder Gas Standard Value) / (Cylinder Gas Standard Value) 

System Bias = 100% x (System Response - Cylinder Gas Standard Value) / (Span Value] 

System 

Mid Response 

4.99 

5.17 

System 

Zero Bias 

-0.2% 

0.0% 

System 

Mid Bias 

-0.2% 

0.4% 

VES019054 
CALIBRATION CHECK REPORT start Time: 11:12:36 EPA Methods: 3A, 6C, 7E and 10 

Run ID: R3B Date: 12/18/2009 End Time: 15:02:38 Job Number: 121809 

Analyzer Analyzer System System System System System System System System 

Zero Mid Pre-Zero Pre-Mid Pre-Zero Pre-Mid Post-Zero Post-Mid Post-Zero Post-Mid 

Param Response Response Response Response Bias Bias Response Response Bias Bias Zero Drift Mid Drift 

C02 0.01 5.01 -0.04 4.94 -0.5% -0.7% 0.02 4.92 0.0% -0.9% 0.5% -0.2% 

THC N/A N/A -0.06 5.1 -0.7% -0.3% -0.14 5.11 -1.5% -0.2% -0.9% 0.1% 

System Bias= 100% x (System Response - Analyzer Response) / (Span Value) 

System Drift= 100% x (System Post Response - System Pre Response)/(Span Value) 

For THC Measurements: 

System Bias= 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Avg-Zero 

Response 

-0.01 

-0.1 

System 

Avg-Mid 

Response 

4.93 

5.1 

VES019055 
A2CQM 

Comments: 

Initial THC Monitor Calibrations 

Plant I.D.V'goLiA SftU6e~^ |Ll.NiofS Project No. 

Source I.D. 

Pollutant _ 

Date 

r H c 

Analyzer Serial No. O IOO i 7 <? Hr 

Operator T . .SRoez: YK&Ki 

Analyzer I.D. Vi 6 Hotel Q.O 

Span Value 

1 e» 6 

Initial Calibration (Time \Q:oc

l ) 

Zero Gas 

Cylinder Value 

(ppm) 

0>OOQ 

System 

Response 

(ppm) 

d O 

Predicted 

Value 

(ppm) 

System 

Response 

(ppm) 

Calibration 

Error 

(% of Span) 

Low Level Gas 

Mid Level Gas 5. I 3 "3 

£ M 9 

£ . ' 3 

Cylinder I.D. 

Zero Gas ULTR A Zt.Ro f^/Mb e 

Low Level Ga s 4 . 7 0 

Mid Level Ga s 

High Level Ga s 

Calibration Error (Svstem Response - Predicted Value) X 100 

Calibration Gas 

Predicted Value f (High Response - Zero Respon X Mid or Low Level Gas ] + Zero Response 

High Level Gas 

VES019056 
Initial Monitor Calibrations 

Plant I.D. AugeTj \U\mS Project No. (£^i 3 3e31k 

Source I.D. UM i T 4 Operator g jga CZYAJS^1 

Pollutant ^ Oa, Analyzer LD^ERV^Mfjf > 4 <? ^ 

Date I /' $.00 °j Span Value _ 

Analyzer Serial No. / V/j^C /,27<9 ^ " 

Initial Calibration (Time \0:<^H ) 

Cylinder Value 

(ppm or %) 

Analyzer 

Response 

(ppm or %) 

Calibration 

Error 

(% of Span) 

System 

Response 

(ppm or %) 

System 

Bias 

(% of Span) 

Zero Gas

 x 

0, Oo 

Low Level Gas — 

— - — 

Mid Level Gas 

m 

£06 % 

High Level Gas il,0 O + 0**+ )l.ol 0, f 

AECOM 

Comments: 

Cylinder I.D. 

Zero Gas if PrtmHi0 funny 

Low Level Gas 

Mid Level Gas 

High Level Gas 

Calibration Error (Analyzer Response - Cylinder Value) X 100 

Span Value 

System Bias = (Svstem Response - Analyzer Response) X 100 

Span Value 

VES019057 
Initial Monitor Calibrations 

Plant i.D.Vfe>l/A SnW6*T \LU)JO\S Project No. l"3 3 £ { 

Source I.D. i T ^ Operator T"« £ Roc^-Y^ K i 

Pollutant £ Analyzer l.D.5^t < ^ 0 5 

Date j. g II I /ZOO <? Span Value 

AnalyzerSerial No. ±W5c/£7o£ _ ^ °

 % 

Initial Calibration (Time 0tf>3c?) 

Cylinder Value 

(ppm or %) 

Analyzer 

Response 

(ppm or %) 

Calibration 

Error 

(% of Span) 

System 

Response 

(ppm or %) 

System 

Bias 

(% of Span) 

Zero Gas OA 

Low Level Gas < — , — — 

Mid Level Gas SAo S*e>8 -o. a 

High Level Gas 1 0 , 1 7 - O a | 

AECO M 

Comments: 

Cylinder I.D. 

Zero Gas C C Q.30Ft&4> 

Low Level Gas 

Mid Level Gas < 

High Level Gas 

Calibration Error (Analvzer Response - Cylinder Value) X 100 

Span Value 

System Bias = (Svstem Response - Analvzer Response) X 100 

Span Value 

VES019058 
AECOM 

Comments: 

Initial THC Monitor Calibrations 

Plant \BSJUoU.fi SbOCfTj luwoiS Project No. &> 1 33 Q 1 & 

Source I.D. U ^ f T *f OperatorT- SEar-g^S'IC ( 

Pollutant ' ' " 

Date \ 1 17 o o <? 

Analyzer Serial No. NI OO f ~7 9 9 

Analvzer I.D.Vf 6 2 o 

Span Value 

Initial Calibration (Time^.^Q) 

Cylinder Value 

(ppm) 

System 

Response 

(ppm) 

Predicted 

Value 

(ppm) 

System 

Response 

(ppm) 

Calibration 

Error 

(% of Span) 

Zero Gas 0 'OOO 

Low Level Gas 

Mid Level Gas 

^^^^^^^^^^^^^ 

High Level Gas 

Cylinder I.D. 

Zero Gas A \ R 

Low Level Gas CC 9.\^<

I'70 

Mid Level Gas 

High Level Gas 3 

Calibration Error (Svstem Response - Predicted Value) X 100 

Calibration Gas 

Predicted Value f (High Response - Zero Respon X Mid or Low Level Gas ] + Zero Response 

High Level Gas 

VES019059 
AZCOM Initial Monitor Calibrations 

Comments: 

Plant I.D. \j£<yL 'if\ 5vfl uCrf. \LL IWS Project No. £0/33g.i£> 

Source I.D. U fo i ~ <f Operator:Ti Xfotz ; i 

Pollutant C 0* Analvzer I.D. R\fQ*ex lLi°0 

Date \ 3. / j 3 9 Span Value 

Analyzer Serial No. 

Initial Calibration (Time <7?

 :3p) 

Cylinder Value 

(ppm or %) 

Analyzer 

Response ' 

(ppm or %) 

Calibration 

Error 

(% of Span) 

System 

Response 

(ppm or %) 

System 

Bias 

(% of Span) 

Zero Gas 0, CO 0>0 \ 

Low Level Gas • — ~ 

Mid Level Gas f. 

- 6, Q 

High Level Gas 10.7* +0.2. > 

Cylinder I.D. 

Zero Gas M a 

Low Level Gas 

Mid Level Gas 

High Level Gas 

Calibration Error (Analvzer Response - Cylinder Value) X 100 

Span Value 

System Bias = (Svstem Response - Analvzer Response) X 100 

Span Value 

VES019060 
Comments: 

Plant I 

Source I.D. 

Pollutant _ 

Date 

Initial THC Monitor Calibrations 

D. V&Ofl Sf\u6eX lu <7w.- g Project No. <£>Q (33SL\G 

Operator \ > € Rotz. </vSK t 

Analvzer I.D. V< & Mabe'L 2.0 

id /ZOO •? span Value <R 

Analyzer Serial No. O ~?0O i l ^ tyInitial Calibration (Time &\'>Z>0) 

Cylinder Value 

(ppm) 

System 

Response 

(ppm) 

Predicted 

Value 

(ppm) 

System 

Response 

(ppm) 

Calibration 

Error 

(% of Span) 

Zero Gas 0 u 

Low Level Gas 

Mid Level Gas 13 3 5 , 3 

High Level Gas 

Zero Gas A' cx 

Low Level Gas 

Mid Level Ga s 

High Level Ga s 

Cylinder I.D. 

S6 otoWWA 

v z G 

Calibration Error (Svstem Response - Predicted Value) X 100 

Calibration Gas 

Predicted Value f (High Response - Zero Respon X Mid or Low Level Gas ] + Zero Response 

High Level Gas 

VES019061 
I 

o 

r i 

VES019062 
AECOM 

Appendix D 

Laboratory Data 

VES019063 
Method 5/26A 

VES019064 
AECOM Report Environment 

Case Narrative 

Re.: Gravimetric Analysis of Filter and Front Half Probe Rinse Samples - Veolia ES Tech 

Sauget, IL 

Project #: 60133216 

LAB ID * 09-064,09-067,09-069 

ANALYTICAL PROCEDURE: 

Eleven (11) Teflon® type filters and 12 front half acetone rinse samples were 

analyzed via EPA Method 5 Gravimetric Analysis as governed by AECOM' s SOP 

2629-300. 

Consecutive gravimetric weights of filters and beaker residues were taken with an 

annually calibrated Mettler balance', and weighed within specified limits as outlined 

in EPA Method 5 and AECOM' s SO P 2629-300. 

1. For two of three shipments received, 09-067 and 09-069, one field blank of 

both filter and acetone were analyzed as specified by EPA Method 5 

Gravimetric Analysis and AECOM' s SOP 2629-300. The first set of samples, 

09-064, contained one acetone blank, but no filter blank was received. 

2. Laboratory blanks of both filter and acetone were analyzed for each of the 

three sets of samples per the same Method and SOP as listed above. 

1. For the first set of samples received, Lab ID: 09-064, two of the acetone 

sample bottles, M5-Acetone-RB and M5-U3-AR-R3, did not have the level of 

acetone marked on the bottle. Additionally, following evaporation of the first 

of these two samples, i.e. the field blank, a moist, oily-appearing residue was 

observed in the sample beaker. The gravimetric result for that sample 

indicated a net gain of 1.9 mg. 

2. For the third set of samples, Lab ID: 09-069, one of the acetone rinse sample 

bottles, M5-U4-FHR-R2, was found to contain a piece of aluminum foil, which 

was removed during the acetone rinse procedure and prior to weighing. 

.QUALITY CONTROL: 

DISCUSSION: 

Date Samples Received by the Laboratory: 12/04,12/11 & 12/21/09 

Date Analysis Started: 12/07/09 

R:\AirDBaseMVl5DB\Metriod 5 DatabaseWlETHOD 5 CLIENT FILESWeolia\09-064_067_069_CaseNarrative.doc 

Page 2 of 14 

VES019065 
AECOM 

Method 5 Exposed Filter Data Sheet 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Jeff Gorman \'M f * -•;Project Manager: T5afe Time R.H(A.t " R T CF) Analyst 

Project Name: 

Project Number: 

Analysis Method: 

Veolia Start Monday 12/21/2009 10:30 34 69 WV 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

60133216 Wt1 Tuesday 12/29/2009 8:40 36 68 WV 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: Oven Dried Wt2 Wednesday 12/30/2009 16:10 33 68 MW 

Wt3 

Wt.4 

QAShriet 

i PatioS.. 

Initial Woig'K S " i .'Sample ' 

* SprrtpflolD 

, Filter" 

Tyi

 e 

1st V.l 

. Gran 

2nd Wt-" 

Grains _ 

A*&2Wt 

"Crams 

•>rdWt I Ai&3WfJ- 4th Wt ' 

Grams 

.. 

Gram6 , 

FmmWt 

Grims 

4 FiV \\\ 

Tot il Groins 

QAShriet 

i PatioS.. . . .Date. J, r-Gram's. .filter* Rim Date * SprrtpflolD 

, Filter" 

Tyi

 e 

1st V.l 

. Gran 

2nd Wt-" 

Grains _ 

A*&2Wt 

"Crams Grams Gram 

4th Wt ' 

Grams 

.. 

Gram6 , 

FmmWt 

Grims 

4 FiV \\\ 

Tot il Groins 

90 12/22/09 0.3942 T1829 Lab Filter Blank 86.2mm 0.3942 0.3942 0.0000 okbvWt. 0.3942 0.0003 

88 11/25/09 0.4008 T1823 12/15/09 Mf>CPT-PF-FB-U4 86.2mm 0.4006 0.4006 0.0000 okbvWt. 0.4006 0.0003 

87 11/25/09 0.4033 T1815 12/16/09 M5-U4-F-R1 86.2mm 0.4048 0.4047 0.0001 okbvWt. 0.4048 0.0015 

88 11/25/09 0.4115 T1819 12/17/09 M5-U4-F-R2 88.2mm 0.4130 0.4130 0.0000 ok byWt. 0.4130 0.0015 

87 11/25/09 0.4124 T1816 12/18/09 M5-U4-F-R3 86.2mm 0.4167 0.4164 0.0003 okbvWt. 0.4166 0.0042 

fD 

O 

-h 

FHterTyoe: G=GIass Q=Quartz 

1. Delta Weight tolerance +/- O.OOOSg of total weight less tare weight between two consecutive weightings or average weight 

2. Filters must be weighed with me proper conditions (RH - 25 - 50 % and RT * 59-78 deg f) 

3. Fillets must be properly conditioned (24 hour desiccation; Further Conditioning > 6 hours). 

4. Conditioning for oven method; Oven dried et 10S deg c fo 2-3 hours; Further conditioning > 6 hours. 

5. Total grams below or equal to .0005 (LDL) Is presented as .0003. 

Veolia_09-069_60l33216 emalLxls 

VES019066 
AECOM 

Method 5 Front Half Acetone Probe Rinse Data Sheet 

Balance Used: Mettler 3 

Project Manager: Jeff Gorman s u m - Date • Time R.T.TFV 

Project Name: Veolia Start Wednesday 12/30/2009 18:00 33 68 MW 

Project Number: 60133216 Wt. 1 Monday 1/4/2010 16:10 34 68 WV 

Analysis Method: M M M Heat Application Wt.2 Tuesday 1/5/2010 8:30 34 68 WV 

Wt3 

Wt.4 

QA.sho»; i-< InltlalWI «*a 

BeakoY* Run bate 

, 1st Wt 

' Grams, 

2nd Wt 

finms^, 

&l&:Wt

 n 

J jr_i 

•>-d WI, 

'• Grams 

4th Wt 

V . »,.g«...s <• 

&4W 

Grans 

Flml Wt 

r 

A FW IW 

i.w±f^ unguis 

QA.sho»; 

Dat? «... .. " M!-,M BeakoY* Run bate 

, 1st Wt 

' Grams, 

2nd Wt 

finms^, 

&l&:Wt

 n 

J jr_i 

•>-d WI, 

'• Grams 

4th Wt 

V . »,.g«...s <• 

&4W 

Grans 

Flml Wt 

r 

A FW IW 

i.w±f^ unguis 

485 12/16/09 91.5106 372 — Lab Acetone Blank — 50 91.5106 91.5108 0.0002 okbyWt. 91.5107 0.0003 

485 12/16/09 109.6951 2284 12/15/09 M5-Acetone-RB-U4 198 50 109.6956 109.6956 0.0000 okbyWt. 109.6956 0.0003 

485 12/16/09 106.7010 2278 12/16/09 M5-U4-FHR-R1 59 50 106.7035 106.7040 0.0005 okbyWt. 106.7038 0.0028 

485 12/16/09 104.2682 117 12/17/09 M5-U4-FHR-R2 49 50 104.2700 104.2705 0.0005 ok byWt. 104.2703 0.0021 

485 12/16/09 109.7162 2266 12/18/09 M5-U4-FHR-R3 61 50 109.7191 109.7188 0.0003 okbyWt. 109.7190 0.0028 

Acetone Manufacturer/Lot No.: Fisher/092950 

Acetone Rinse = 25 mis twice - (50 mis total) 

1. Delta Weight tolerance +/- O.OOOSg of total weight (ess tare weight between wo consecutrve weightings or average weight. 

2. Beakers must be weighed with the proper condiiions (RH = 25 - 60 % and RT = 59-78 deg f) 

3. Beakers must be property conditioned (24 hour desiccation; Further Conditioning > 6 hours). 

4. Natural Evaporation Method « Evaporate to dryness at room temperature under a hood / watch glass cover 

5. Heat Application = Under a hood and watch glass over sample, apply heat below the boiling point of sample until evaporated lo 25 mis; then fallow step 4 (above) for remaining portion.. 

6. Total grams below or equal to .0005 (LOL) Is presented as .0003. 

VES019067 
Sample Traceability List 

Site of Program: Veolia ES Tech Sample Date: U,l / £ - & l//Oc

r Project Location: Sauget, iL P.O. #: 

Type of Program: CPT Date Shipped: \2.\ lff/0" ¥ Laboratory AECOM EnviranmorK 

Project*: 80133216 Harvard, MA f . f-v )*«•£ r* 

Program Office: Syracuse NY 

Shipper / Steven Milo 

Recovery: Jim Morris 

Laboratory AECOM EnviranmorK 

Harvard, MA f . f-v )*«•£ r* 

Program Contact: Jeff Gorman FedEx Air Bill #: 

Item Sample ID Code Sample Matrix Sample Description Analitical Parameters Special instructions 

1 M5-U4-F-R 1 Filter IWS, Filler, Run 1 Particulate Matter ©9-069-3. . 

2 M8-U4-FHR-R 1 . Acetone MB, FH Acetone Rinse, Run 1 Particulate Matter 

3 

4 M5-U4-F-R 2 Filter MS, Filter, Run 2 Particulate Matter 

5 M5-U4-FHR-R 2 Acetone WI5, FH /Acetone Rinse, Run 2 Particulate Matter C'V -069- 7 

6 

7 M5-U4-F-R 3 Filter M5, Filter, Run 3 Particulate Matter 

8 MS4J4-FHR-R 3 Aceton e M5, FK Acetone Rinse, Run 3 Particulate Matter (\<?« c c i> •• 1? 

9 

10 

11 

12 

13 

14 

15 

16 

17 -

18 

19 fur-, fi I f-^- & Ul.4C ol-os?--/ 

20 MIS-Acetor»e-RB-U4 Acetone IMS-Acetone Blank Particulate Matter 

Field N( >tes/ Comments 

Page \ of 1 

Relinquished By (print): Date: 

Signature: Time: 

1700 

Relinquished By (print): Date: 

Signature: Time: 

(Relinquished By (print): Date: 

Signature: Time: 

[Received by Lab (print): Date: 

Signature: Time: 

Received By (print): _ Date: 

Signature: Time: 

^Mu, U, U 

Received By (print): Date: 

Signature: Time: 

iReceived By (print): Date: 

Signature: Time: 

Analytical Laboratory Destination: 

lAECOM Environment 

325 Ayer Road 

Harvard, MA 01451 

lAttn: Mr. Paul Taverna (978) 772-2345 Ext 32 

VES019068 
nient/Proj#_ 

Project Mgr:_ 

SAMPLE LOG-IN & RECEIPT CHECKLIST 

Lab Pool#: 09-061 

Inspected & Logged in by:. Date & Time: 

l^nvbeffof 

stJfraPj ^ WBSoSSSSs 

fib*- HT:#/Vo<? 

Due://W/O 

H 

HT: It-fa/oX 

Due: //v A 

HT: 

Due: 

Circle the appropriate response: 

1) S^fpp^d / Hand delivered 

i COC p^Serft / not present on receipt 

3) Samples broken / leaking / (n{§p$ on receipt 

4) Samples ^nbj|M / chilled on receipt 

5) Samples preserved correctly / incorrectly_|^noj3e recommended 

6) Received ^Rjjp/ outside holding time 

7) COC tapes present / r^SDaesent on samples /NA 

9) Discrepancies /^^discrepancies noted between COCs and samples 

Additional Comments: • 

6 3 8/26/2008 

Page 14 of 14 

VES019069 
1 

TestAmerica 

THE LEADER IN ENVIRONMENTAL TESTING 

TestAmerica Laboratories , Inc 

ANALYTICAL REPORT 

PROJECT HO. 6013321S 

Veolia - ES Tech 

Lot #: H9L210403 

Jeff Gorman 

AECOM, Inc 

5105 Canrpuswood Drive 

Suite 104 

East Syracuse, NY 130S7 

TESTftMERICft. LABORATORIES, INC. 

Kevin S. Woodcock 

Project Manager 

December 30, 2009 

5815 Middlebrook Pike Knoxville, TN 37921 tel 865.291.3000 fax 865.584.4315 www.testamericainc.com 

VES019070 
2 

ANALYTICAL METHODS SUMMARY 

H9L210403 

ANALYTICAL 

PARAMETER METHOD 

Chlorine Emissions KNOX 0050/26A Mod 

Hydrogen Chloride Emissions KHOX 0050/26A Mod 

References: 

KNOX TestAmerica Laboratories Inc., Knoxville Laboratory Standard 

Operating Procedure 

VES019071 
3 

SAMPLE SUMMARY 

H9L210403 

WO # SAMPLEft CLIENT SAMPLE ID 

SAMPLED SAMP 

DATE TIME 

LRE20 

LRE22 

LRE23 

LRE24 

LRE25 

LRE26 

LRE28 

LEE29 

LRE3S 

001 

002 

003 

004 

005 

006 

007 

008 

009 

CPT-HCL-FB-U4 

CPT-CL2-FB-U4 

CPT-U4-HCL-IMP1-4-RIA 

CPT-174 - CL2 - IMP5 - 6 -Rl 

CPT-U4-HCL-IMP1-4-R2A 

CPT-U4-CL2-IMP5-6-R2 

CPT-04-HCL-IMP1-4-R3A 

CPT-U4-CL2-IMP5-6-R3 

CPT-H20-FB-U4 

12/16/09 

12/16/09 

12/17/09 

12/17/09 

12/18/09 

12/18/09 

12/15/09 

12/15/09 

12/15/09 

MOTE (S) : 

- The anaiyiicai results or ihe samples listed above are presented on ihe following pages. 

• All calculations are performed before rounding io avoid round-off errors in calculated results. 

- Results noted as "ND" were not detected at or above liffi staled limit. 

- This report musl noi be reproduced, esccpt in full, without the written approval of the laboratory. 

- Results Tor the following parameters are never reported on a dry weight basis: color, corrosiviiy, density, flashpoint, ignitability. layers, odor, 

paint filler tusr. pH, porosity pressure, reaciiviiy, redox potential, specific gravity, spoiiests, solids, solubility, temperature, viscosity, and weight. 

VES019072 
4 

PROJECT NARRATIVE 

H9L210403 

The results reported herein are applicable to the samples submitted for analysis only. 

This report shall not be reproduced except in full, without the written approval of the 

laboratory. 

The original chain of custody documentation is included with this report. 

Sample Receipt 

Custody seals were not present. 

Quality Control and Data Interpretation 

Unless otiierwise noted, all holding times and QC criteria were met and the test results 

shown in this report meet all applicable NELAC requirements. 

Samples were analyzed for chloride by ion chromatography using SOP number KNOXWC-005 (based on EPA methods 9056,9057 and 26A). All sample results were reported 

as total n g hydrogen chloride (HCI) and total u.g chlorine (Cl2). Results were calculated 

using the following equations: 

HCI, ug = (Chloride,ug/mL)*(Sample Volume,mL)*[ ^'^"'^WeightHCA„ Q 

\ Molecular Weight C! , 

Cl 2,ug = (Chloride,ug/ mL)* (Sample Volume, mL)* Bench Dilution 

NaOH impinger samples were treated with sodium thiosulfate (NazS^Os) prior to the final 

analysis in order to convert residual hypochlorite (OC1") to chloride ion. 

Note: A sample volume of 100 mL was used to convert the results to total for the 

method blanks, laboratory control samples, and client reagent blanks in order to 

standardize tlie analyte sample total. 

TesiAmerica Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Lab #88-

0688, California DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Lab #PH-0223, Florida DOH Lab 

#E87177. Georgia DNR Lab i/906, Hawaii DOH, Illinois EPA Lab S20D012, Indiana DOH Lab #C-TN-02, Iowa DNR 

Lab #375; Kansas DHE Cert. i'E-10349, Kentucky DEP Lab #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH, 

Maryland DOE Cert. #277, Michigan DEQ Lab #9933, Nevada DEP, New Jersey DEP Lab #TN001, New York DOH 

Lab"f, 10781, North Carolina DPH Lab #21.705, North Carolina DEHNR Cert. #64, Ohio EPA VAP Lab &CL0059, 

Oklahoma DEQ Lab #9415, Pennsylvania DEP Lab #68-00576, South Carolina DHEC Cert #84001001, Tennessee 

DOH Lab #02014, Texas CEQ, Utah DOH Lab # QUAN3, Virginia DGS Lab #00165, Washington DOE Lab #C1314, 

West Virginia DEP Cert. 2345, West Virginia DHHR Cert S9955C, Wisconsin DNR Lab #998044300, Naval Faciliiies 

Engineering Service Center and USDA Soil Permit #S-46424. This list of approvals is subject to change and does not 

imply lhat laboratory certification is available for all parameters reported in this environmental sample data report. 

VES019073 
5 

PROJECT NARRATIVE 

H9L210403 

For demonstration of analytical method performance on these samples, TestAmerica 

Knoxville analyzed matrix spikes (MS) and matrix spike duplicates (MSD). Acceptable 

recoveries of these spikes demonstrate that quantitation from this particular stack gas 

matrix is accurate and acceptable, Impinger samples containing 0.1N HiS04 and O.IN 

NaOH display matrix interference effects causing poor method performance and possibly 

giving unreliable data unless the interference is removed. Therefore, the samples were 

diluted in the lab to remove the interference for a more accurate chloride response. The 

samples may be analyzed at increasing dilutions along with matrix spikes until matrix 

spikes recover from the sample within laboratory control limits. The ion chromatograph 

calibration range used to quantitate the sample results permits a standard ten-fold sample 

dilution while supporting the reporting limit with the low calibration standard. 

The dilution factor reported on the sample result form does not represent the bench 

dilution factor. It is actually the combination of factors required by the method to convert 

the anion reporting limit and method detection limit from ug/mL to total ug. It may 

appear to be elevated because it includes the total sample volume in mL. 

VES019074 
6 

QC DATA ASSOCIATION SUMMARY 

H9L210403 

Sample Preparation and Analysis Control Numbers 

SAMPLEj 

001 

002 

003 

004 

005 

006 

007 

008 

009 

MATRIX 

AIR 

A I R 

AIS 

AIR 

AIR 

AIR 

AIR 

AIR 

AIR 

ANALYTICAL 

METHOD 

KNOX 0050/26A Mod 

KNOX O0S0/26A Mod 

KNOX 0050/26A Mod 

KNOX 0050/26A Mod 

KNOX 0050/26A Mod 

KNOX 0050/26A Mod 

KNOX 0050/26A Mod 

KNOX 0050/26A Mod 

KNOX 0050/26A Mod 

LEACH 

BATCH # 

PREP 

BATCH # 

9358195 

.9357355 

9358195 

9357355 

9358195 

935735 5 

9358195 

935B195 

9357355 

MS RUN# 

9358120 

9356072 

9358120 

9358072 

9358120 

9358072 

9358120 

935B120 

9358072 

I 

VES019075 
7 

Sample Data Summary 

VES019076 
8 

AECOM, Inc 

Client Sample ED: CPT-TJ4-HCL-IMP1-4-R1A 

General Chemistry. 

Lot-Sample #...: H9L-210403-001 Work Order #.'..: LRE20 Matrix : AIR 

Date Sampled...: 12/16/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen cOiloride 34600 4420. ug KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factors 44222.46 ' MDL. : 1900 

VES019077 
9 

AECOM. mc 

Client Sample ID: CPT-04-CL2-IMP5-6-R1 

General Chemistry 

Lot-Sample #...: H9L210403-002 Work Order LRE22 Matrix.... : AIR 

Date Sampled : 12/16/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER .RESULT RL UNITS METHOD ' ANALYSIS DATE BATCH # 

Chlorine ND 484 ug KNOX 0050/26A Mod 12/21/09 935735S 

Dilution Factor: 4840 HDI> 200 

VES019078 
1 0 

AECOM, Inc. 

Client Sample ID: CPT-04-HCL-IMP1-4-E2A 

General ChemistryLot -Sample #... : H9L210403-D03 Work Order : LRE23 Matrix : AIR 

Date Sampled.: 12/17/09 . Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride 43100 4420 ng KNOX 005Q/26A Mod 12/22/09 9358195 

Dilution Factor: 44222.46 MDI, :• 1900 

VES019079 
11 

AECOM, Inc 

Client Sample ID; CPT-U4-CL2-XME5-6-R2 

General Chemistry 

Lot-Sample #..-: H9L210403-004 Work Order -. L-RE24 Matrix.... t AIR 

Date Sampled...; 12/17/09 Date Received.. -. 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine 208 B 472 ug KNOX 0050/26A Mod X2/21/09 9357355 

Dilution Factor: 4720 MDL : 200 

NOTB(S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. 

VES019080 
1 2 

AECOM, Inc 

Client Sample ID: CPT-U4-HCL-IMP1-4-R3A 

General Chemistry 

Lot-Sample #.-.: H9L210403-0.05 Work Order #...: LRE25 Matrix : AIR 

Date Sampled : 12/18/09 Date Received..: 12/19/09 

.PREPARATION- PREP 

PARAMETER RESULT RL CHITS . METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride 3640 1590 ug KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 16866.24 MDL 710 

VES019081 
13 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

. AECOM, Inc 

Client Sample ID: CPT-U4-CL2-IMP5-6-R3 

General Chemistry 

.: H9L210403-005 Work Order #...: LRE26" 

.: 12/18/09 Date Received.-: 12/19/09 

Matrxx. AIR 

RESULT RL UNITS METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Chlorine 204 B 480 ug 

Dilution. Factor: 4800 

KNOX 0050/26A Mod 12/21/09 

MDL : 200 

9357355 

NOTE(S) : -

IU. Reporting Limit 

B Estimated result. Result is less than RL. 

VES019082 
14 

AECOM; Inc 

Client Sample ID: CPT-H2O-FB-04 

General Chemistry 

Lot-Sample #... : H9L2104.03-007 Work Order : LRE28 Matrix : AIR 

Date Sampled : 12/15/09 Date Received. .: 12/19/09 

PREPARATION- PREP 

PARAMETER ; RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride ND 103 ug KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 1028.43 MDL : 43 

VES019083 
1 5 

• AECOM, lac 

Client Sample ID: CPI-HCL-FB-tf4 

General Chemistry 

Lot-Sample if... : H9L210403-008 Work Order #...: LRE2S 

Date Sampled...: 12/15/09 Date Received..: 12/19/09 

Matrix. .: : AIR 

PARAMETER RESULT RL UNITS 

Hydiogen chloride ND 411 ug 

Dilution Factor.- 4113.72 MDL : 170 

PREPARATION- PREP 

METHOD ANALYSIS DATE BATCH # 

KNOX 0050/26A Mod 12/22/09 9358195 

VES019084 
16 

AECOM, Inc 

Client Sample ID: CPT~CL2-FB-U4 

General Chemistry 

Lot-Sample #...: H9L210403-009 Work Order : LRE3A Matrix : AIR 

Date Sampled-..: 12/15/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL . UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine ND .100 ug KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 1000 HDL : 42 

VES019085 
17 

METHOD BLANK REPORT 

General Chemistry 

Client Lot #. . .: H9L210403 Matrix. . : AI R 

PARAMETER 

REPORTING 

RESULT LIMIT UNITS 

Chlorine 

ND 

METHOD 

PREPARATION- PREP 

ANALYSIS DATE ,BATCH ft 

Work Order #: LRLHD1AA MB Lot-Sample #: H9L230000-355 

10.0 ug KNOX 0050/2SA. Mod 12/21/09 

Dilution Factor: 100 

9357355 

Hydrogen chloride . Work Order,#: LRL131AA MB Lot-Sample #: H9L240000-195 

ND 10.3 ug KNOX 0050/26A Mod 12/22/09 

Dilution Factor: 102.8 

9358195 

NOTE IS) ; 

Calculations arc performed before rounding to avoid roundoff errors in calculated results. 

VES019086 
18 

LABORATORY COHTROL SAMPLE EVALDATIOH REPORT 

General Chemistry 

Lot-Sample #...: H9L210403 Matrix. 

PARAMETER 

Chlorine 

PERCENT 

RECOVERY 

98 

103 

RECOVERY 

LIMITS RPD 

RPD . 

LIMITS METHOD 

PREPARATION-• 

ANALYSIS DATE 

: AIR 

PREP 

BATCH # 

. WO#:LRLHDIAC-LCS/LRLHDIAD-LCSD LCS Lot-Sample#: H9L230000-355 

(90 - 110) KNOX O05O/26A Mod 12/21/09 9357355 

(90 - 110) 5.0 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 100 

Hydrogen chloride 

100 

98 

WO#:LRL131AC-LCS/LRL131AD-LCSD LCS Lot-Sample#: H9L240000-195 

(90 - 110) KNOX 0050/26A Mod 12/22/09 9358195 

(90 - 110) 2.0 (0-20) KNOX 0050/2SA Mod 12/22/09 935B195 

Dilution Factor: 102.8 

NOTBCS) t 

Calculuions arc performed before roundinc lo avoid roundoff errors in calculaied results. 

VES019087 
1 9 

LABORATORY COHTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample tt... -. H9L210403 Matrix. AIR 

PARAMETER 

Chlorine 

SPIKE MEASURED 

AMOUNT AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

75.0 

75.0 

PREP 

BATCH # 

WO#:LRLHDIAC-LCS/LRLHDIAD-LCSD LCS Lot-Sample#: H9L230000-355 

.73.7 ug . 98 • ICNOX 0050/26A Mod 12/21/09 9357355 

77.5 ug 103 S.O KNOX 0 050/26A Mod 12/21/09 .9357355 

Dilution Factor: 100 

Hydrogen chloride 

77.1 

77.1 

WO#:LRL131AC-LCS/LRL131AD-LCSD LCS Lot-Sample#: H9L240000-195 

77.2 ug ' 100 KNOX 0050/26A Mod 12/22/09 9358195 

75.6 ug 98 2.0 KNOX 0 050/26A Mod 12/22/09 9358195 

Dilution Factor: 102.S 

NOTE(S): 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES019088 
20 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Chemistry 

Client Lot #„..: H9L210403 

Date Sampled^...: 12/17/09 Date Received..: 12/19/09 

Matrix. .: AIR 

• PARAMETER 

Chlorine 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

98 

78 

WO#: LRE24IAC-MS/.LRE24IAD-MSD. MS Lot-Sample #; H9L21O403-004 

(75 - 125) KNOX 0050/26A Mod 12/21/09 9357355 

(75 - 125) 18 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 4720 

Hydrogen chloride 

.107 (75 

118 ' (75 

W0#: LRE23IAC-MS/LRE23IAD-MSD MS Lot-Sample #: H9L210403-003 

125) KNOX 0050/26A Mod 12/22/09 9358195 

125) 1.8 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 44222 

NOTE(S): 

Calculaiions arc performed before rounding io avoid round-off errors in calculated results. 

VES019089 
21 

MATRIX SPIKE SAMPLE DATA REPORT 

General Chemistry 

Client Lot 

Date Sampled.. 

H9L210403 

12/17/09 Date Received..: 12/19/09 

Matrxx. A I R 

SAMPLE SPIKE MEASRD 

PARAMETER AMOUNT AMT 

Chlorine 

208 

208 

944 

944 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATION - PREP 

ANALYSIS DATE BATCH # 

WO#: LRE24IAC-MS/LRE24lAD-MSD MS Lot-Sample #: H9L21O403-004 

1130 ug 98 KNOX 0050/26A 12/21/09 9357355 

945 ug 78 18 KHOX 0050/26A 12/21/09 9357355 

Dilution Factor: 4720 

Hydrogen chloride 

43100 8840 

43100 8840 

WO#: LRE231AC-MS/LRE231AD-MSD MS Lot-Sample #: H9L21O403-003 

52600 ug 107 KNOX 0050/26A 12/22/09 9358195 

53500 ug- .118 1.8 ICNOX 0O50/26A 12/22/09 9358195 

Dilution Factor: '44222 

NOTE (S) 

Calculaiions arc performtil before rounding 10 avoid round-off errors in calculated results.. 

VES019090 
22 

Client Lot H9L210403 

Date Sampled...: 12/16/09 

SAMPLE DDPLICATE EVALUATION EEPORT 

General Chemistry 

Work Order #...: LRE20-SMP 

LRE20-DDP 

Date Received...- 12/19/09 

PARAM RESULT 

DUPLICATE 

RESULT 

Hydrogen chloride 

34600 35900 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix.. .• :-AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-001 

ug 3.7 (0-20) KNOX 0050/26A Mod 12/22/09 , 9358195 

Dilution Factor: 44222.46 

VES019091 
2 3 

Client Lot §. 

Date Sanrpled. 

PARAM RESULT 

Chlorine 

ND 

: H9L210403 

: 12/16/09 

DDPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LRE22-SMP 

LRE22-DUP 

Date Received.,: 12/19/09 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L2.10403-D02 

211 B ug 200 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 4840 

NOTE(S) : 

Calculations arc performed before rounding lo avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES019092 
24 

Client Lot #...: H9L210403 

Date Sampled...: 12/17/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LRE23-SMP 

LRE23-DUP 

Date Received..: 12/19/09 

PARAM RESULT 

DUPLICATE 

RESULT 

Hydrogen chloride 

43100 44000 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : AIR 

PREPARATION-_ PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample ft: H9L210403-0O3 

ug 2.1 (0-20) KNOX OO50/26A Mod 12/22/09 9358195 

Dilution Factor: 44222.46' 

VES019093 
25 

Client Lot #. 

Date Sampled. 

PARAM RESULT 

Chlairine 

208 B 

H9L210403 

12/17/09 

DUPLICATE 

RESULT ' 

SAMPLE DUPLICATE EVALDATIOH REPORT 

General Cnemistry 

Work Order LRE24-SMP 

LRE24-DUP 

Date Received..: 12/19/09 

ND 

UNITS RPD 

RPD 

LIMIT METHOD 

Matrix . -.: AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SO Lot-Sample #: H9L210403-004 

ug 200 (0-20) KNOX 0050/26A Mod 12/21/09 3357355 

Dilution Factor: 4720 

NOTE(S) : 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

B Estitnated result. Result is less titan RL. 

VES019094 
26 

Client Lot #.. 

Date Sampled.. 

PARAM RESULT 

H9L210403 

12/18/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #.„•.: LRE25-SMP 

LRE25-DUP 

Date Received..: 12/19/09 

Hydrogen chloride 

3640 3590 

UNITS 

• RPD 

RPD LIMIT METHOD 

Matrix : AIR 

PREPARATION-" PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-0O5 

ug 1.5 "(0-20) KNOX 0050/26A-Mod 12/22/09 9358195 

Dilution Factor: 16866.24 

VES019095 
27 

Client Lot #. 

Sate Sampled. 

PARAM RESULT 

. : H9L210403 

.: 12/18/09 

DUPLICATE 

• RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...s LRE26-SMP 

LRE26-DUP 

Date Received..: 12/19/09 

• Chlorine 

204 B ND 

Matrix. A I R 

UNITS 

RPD 

RPD . LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-006 

ua; 200 (0-20) KNOX 0050/26A'Mod 12/21/09 9357355 

Dilution Factor: 4800 

NOTE(S) : . 

Calculations arc performed before rounding lo avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES019096 
28 

Client Lot #.. 

Date Sampled.. 

PARAM RESULT 

.: H9L210403 

.: 12/15/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #.,.: LRE2 8 -SMP 

LRE28-DUP 

Date Received..: 12/19/09 

Hydrogen chloride 

ND ND 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD LOt-Sample #: H9L210403-007 

ng 0 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factors 1028.43 

VES019097 
29 

Client Lot H9L210403 

Date Sampled : 12/15/09 

SAMPLE DDPLICATE EVALUATION EEPORT 

General Chemistry 

Work Order #...: LRE29-SMP 

LRE29-DUP 

Date Received..: 12/19/09 

PARAM RESULT 

DUPLICATE 

RESULT 

Hydrogen chloride 

ND ND 

Matrix. A I R 

UNITS 

RPD 

RPD . LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-00S 

ug 0 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 4113.72 

VES019098 
3 0 

H9L210403 

12/15/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LRE3A-SMP 

LRE3A-DUP 

Date Received..: 12/19/09 

ND 

Matrix. AIR 

UNITS RPD 

RPD 

LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE • BATCH ft 

SD Lot-Sample #: H9L210403-009 

ug 0 (0-20) KNOX 0050/2SA Mod 12/21/09 9357355 

Dilution Factor: 1000 

VES019099 
31 

Sample Receipt Documentation 

VES019100 
Sample Traceability List AECOM 

Sits of Pronram: Veolia ES Tech Samplo Date: vz/11, -\tl iSf/eft Prolect Location: Sauget, IL LabPO#': 

Type of Proqram: CPT Date Shipped: ^JlSfot Laboratory: Test America, Inc, 

Project*: 60133216 

Program Office: Syracuse NY 

Shipper/ Steven. Milo 

Recovery: Jeff Gorman 

Laboratory: 

Knoxville, TN 

Program Contact: . Jeff Gorman FedEx Air Bill #: 

Hem Sample ID Code Sample Matrix Sample Description . Analytical Parameters Special Instructions 

1 CPT-U4-HCL-.MP1-4- R 1 A . 0.1N H2S04 Unit 4, Impingers H , Run 1 A HCL 

2 ' 

3 CPT-U4-CI2-IMP5 ^R't O. l N NaOH Unit 4, Impingers 5-6, Run 1 

A 

5 

a 

CPT-U4-HCL-IW1P1 -4-R 2 A 0.1N H2S04 Unit A, Impingers 1-4, Run 2 A HCL p\& 

O 

7 CPT-U4-CI2-IMP5-6-R 2 0.1 N NaOH Unit 4, Impingers 5-6, Run 2 c b ypS a -ST f 

0 O iA. L- X3CrX\J 

8 

g CPT-U4-HCL-IMP1-4- R 3 A 0.1NH2SO4 Unit 4, Impingers 1-4. Run 3 A HCL 

Hr*' . 

(0 

11 CPT-U4-CI2-IMP5-6-R 3 0.1 N NaOH Unit 4, Impingers 5-6, Run 3 CI2 

12 

13 

14 

15 

16 

17 CPT-H20-FB-U 4 DI-H20 DI-H20 Field Blank ' HCL and CL2 

1B CPT-HCL-FB-U 4 0.1N H2S04 0.1N H2S04 Field Blank HCL 

19 CPT-CI2-FB-U 4 O.INNaOH O.INNaOH Field Blank CI2 

20 

Field Notes/ Comments 

Page I of f_ 

Relinquished By (print): Date: 

Steven Milo \Z\\8l<P\ 

Signature: . Time: 

JSi w no o 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

Received by Lab (print): Date: 

Signature: Time: 

Received By (print): .Date: 

Signature: Time: 

. aovv9K ^ 

Received By (print): Date: 

Signature: Time: 

Received By (print); Date: 

Signature: Time: 

Analytical Laboratory Destination: 

TestAmerica Inc. 

5815 Middlebrook Pike 

Knoxville, TN 37921 

Attn: Mr. Kevin Woodcock 865-291-3000 

VES019101 
TESTAMERICA KNOXVILLE SAMPLE RECEIPT/CONDITION UPON RECEIPT ANOMALY CHECKLIST 

Lot Number: W'MAMn

 U 1X 

Review Items No NA If No, what was the problem? Comments/Actions Taken 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) 1 

• la Do not match COC 

• lb Incomplete information 

• lc Marking smeared 

• Id Label tom 

Die No label 

• lf COC not received 

D lg Other: 

2. Is the cooler temperature within limits? (> freezing 

temp, of water to 6°C; NC, 1668,1613B: 0-4"C; 

VOST: 10°C; MA: 2-6°C) 

J 

1 

2. Is the cooler temperature within limits? (> freezing D 2a Temp Blank = 

temp, of water to 6°C; NC, 1668,1613B: 0-4"C; 

VOST: 10°C; MA: 2-6°C) 

J 

1 

D 2b Cooler Temp = 

2. Is the cooler temperature within limits? (> freezing 

temp, of water to 6°C; NC, 1668,1613B: 0-4"C; 

VOST: 10°C; MA: 2-6°C) 

J 

1 

3. . Were samples received with correct chemical 

preservative (excluding Encore)? J D 3si Sample preservative = 

1 

3. . Were samples received with correct chemical 

preservative (excluding Encore)? J D 3si Sample preservative = 

1 

4. Were custody seals present/intact on cooler and/or 

containers? 1 Ui 4)i Not present 0 4b Not intact 

D 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? 1 Ui 4)i Not present 0 4b Not intact 

D 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? 1 Ui 4)i Not present 0 4b Not intact 

D 4c Other: 

5. Were all ofthe samples listed on the COC received? I • 5a Samples received-not on COC 

• 5b Samples notreceived-on COC • 

5. Were all ofthe samples listed on the COC received? I • 5a Samples received-not on COC 

• 5b Samples notreceived-on COC • 

S. Were all ofthe sample containers received intact? 1 / 

D 6a Leaking 

D 6 b Broken 

S. Were all ofthe sample containers received intact? 1 / 

D 6a Leaking 

D 6 b Broken 

7. Were VOA samples received without headspace? V D 7a Headspace (VOA only) 

8, Were samples received in appropriate containers? V

7 

—i- • 8a Improper container 

9. Did you check for residual chlorine, if necessary? 

I •• 

/ • 9a Could not be determined due 

to matrix interference 

9. Did you check for residual chlorine, if necessary? 

I •• 

/ • 9a Could not be determined due 

to matrix interference 

10. Were samples received within holding time? J O 10a Holding time expired 

11. For rad samples, was sample activity info, provided? • Incomplete infonnation 

12. For 16I3B water samples is pH<9? J If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

12 • . For 16I3B water samples is pH<9? J If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

13. Are the shipping containers intact? • 13a Leaking 

013b Other: 

13. Are the shipping containers intact? • 13a Leaking 

013b Other: 

14. Was COC relinquished? (Signed/Dated/Timed) hf 014n Not relinquished 

15. Are tests/parameters listed for each sample? 

V 

• 15a Incomplete information 

16. Is the matrix ofthe samples noted? 1/ • I5a Incomplete information 

17. Is tlie date/time of sample collection noted? 7 

D 15a Incomplete information 

18. Is the client and project name/# identified? // 0 15a Incomplete information 

19. Was the sampler identified on the COC? / 

Ouote#: . PM Instructions: 

. ( ^J\. ^ . r-r - = : 

Sample Receiving AssocWXW Iflhlffl Date:) 0 [ 2-i |0 <3 QA026R21 .doc, 090409 

w 

w 

VES019102 
34 
35 

Sample Summary 

VES019104 
36 

AECOM, Inc 

Client Sample ID; CPT-U4-HCL-IMP1-4-R1A 

General Chemistry 

Lot-Sample ft-..: H9L210403-001 Work Order #.. .: ' LRE20 Matrix .: AIR 

Date Sampled.-. 12/16/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride 34600 4420 ug KNOX 0050/2GA Mod 12/22/09 9358195 

Dilution Factor: 44222.46 HDL... s 1900 

VES019105 
3 7 

AECOM, inc 

Client Sample ID: CPTrD4-CL2-IMP5-S-Rl 

General Chemistry 

Lot-Sample tt...: H9L210403-002 

Date Sampled : 12/16/09 

PARAMETER RESULT 

Work Order #...: LRE22 

Date Received..: 12/19/09 

RL UNITS METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Chlorine ND 484 ug KNOX 0050/26A Mod 12/21/09 93573S5 

Dilution Factor: 4840 MDI. = 200 

VES019106 
3 8 

AECOM, Inc 

Client Sample ID: CPT-D4-HCL-IMP1-4-R2A 

General Chemistry 

Lot-Sample it...: H9L210403-003 Work Order #...-. LRE23 Matrix : AIR 

Date Sampled...: 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH tt 

Hydrogen chloride 43100 4420 ug KNOX 0050/26A Mod 12/22/09 93B8195 

Dilution Factor: 44222.46 MDL :1900 

VES019107 
3 9 

AECOM, Inc 

Clxent Saniple ID: CPT-04-CL2-IMP5-6-*R2 _ 

General Chemistry 

Lot-Sample : H9L210403-004 Work Order : LRE24 Matrix : AIR 

Date Sampled...: 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS, DATE BATCH g 

Chlorine 208 B 472 ug KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 4720. MDL : 200 

HOTS (S) : ] ' 

RL Reporting limit 

B Estimated result. Result is less than RL. 

VES019108 
40 

AECOM, Inc • 

Client Sample ID: CFT-04-HO.-IMP1-4-R3A 

General Chemistry 

Lot-Sample*...: H9L210403-0Q5 Work Order #...: LRE25 Matrix : AIR 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride 3640 1690 ug KNOX O05O/26A Mod 12/22/09 9358195 

Dilution Factor; 16866.24 MDL ..: 710 

VES019109 
41 

AECOM, Inc 

Client Sample ID: CPT-TJ4-CL2-IMP5-6-R3 

General Chemistry 

Lot-Sample #...: H9L210403-006 Work Order ft...: LRE26 Matrix.... : AIR 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine 204 B 480 ug KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor.- 4800 MDL : 200 

NOTE(S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. 

VES019110 
42 

AECOM, Inc 

Client Sample ID: CPT-H20-FB-U4 

General Chemistry 

Lot-Sample #...: H9L210403-007 Work Order #..-: LRE2B 

Date Sampled...: 12/15/09 Date Received..: 12/19/09 

PARAMETER RESULT RL UNITS METHOD 

Matrix. AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Hydrogen chloride ND 103 ug KNOX 0050/26A Mod 12/22/09 

Dilution Factor: 1026.43 MDL : 43 

9358195 

VES019111 
4 3 

AECOM, Inc 

Client Sample ID: CPT-HCL-FB-U4 

General Chemistry 

Lot-Sample ft...: H9L21O403-OO8 

Date Sampled...: 12/15/09 

Work Order #...: LRE29 

Date Received..: 12/19/09 

Matrix : AIR 

PARAMETER RESULT RL UNITS 

Hydrogen chloride ND 411 ug 

Dilution Factor: 4113.72 ' MDL : 1?0 

PREPARATION- PREP 

METHOD ANALYSIS DATE BATCH # 

ICNOX 0050/26A Mod 12/22/09 9358195 

VES019112 
44 

AECOM> Inc 

Client Sample ID: CPT-CL2-PB-D4 

General Chemistry 

Lot-Sample tt...: H9L210403-009 Work Order #...: LRE3A Matrix : AIR 

Date Sampled : 12/15/09 Date Received..: 12/19/09 

' PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine ND 100 ug KNOX 0050/26A Mod 12/21/09 9357355 

Dilution. Factor: 1000 MDL : 42 

VES019113 
45 

QC Summary 

VES019114 
46 

METHOD BLANK REPORT 

General Oientistxy 

Client Lot #...: H9L210403 Matrix .- AIR 

REPORTING PREPARATION- PREP 

PARAMETER RESULT LIMIT UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine Work Order #: LRLHD1AA MB Lot-Sample'#: H9L230000-355 

ND 10.0 ug ICNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 100 

Hydrogen chloride Work Order #: LRL131AA MB Lot-Sample #: H9L240000-195 

ND 10.3 ug KNOX 005O/26A Mod 12/22/09 

Dilution Factor: 102.8 

HOTECS) ; , • ; 

Calculations are performed before rounding io avoid round-ofT errors in calculaied results. 

9358195 

* 

VES019115 
4 7 

LABORATORY CONTROL, SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample tt . . .: H9L210403 Matrix : AIR 

PARAMETER 

Chlorine 

PERCENT 

RECOVERY 

98 

103 

RECOVERY 

LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

WO#:LRLHD1AC-LCS/LRLHD1AD-LCSD LCS Lot-Sample#: H9L230000-355 

(90 - 110) KNOX 0050/26A Mod 12/21/09 9357355 

(90 - 110) 5.0 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 100 

Hydrogen chloride 

100 

98 

WO#:LRL13.1AC-LCS/LRL131AD-LCSD LCS Lot-Sample#: H9L240000-19S 

(90 - 110) KNOX 0050/2SA Mod 12/22/09 9358195 

(90 - 110) 2.0 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 102.8 

HOTE(S) 

Calculaiions are performed before rounding io avoid round-off errors in calculated results. 

VES019116 
48 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample #.'..: H9L210403 Matrix. AIR 

PARAMETER 

Chlorine 

SPIKE MEASURED 

AMOUNT AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATION- PREP 

. ANALYSIS DATE BATCH # 

WO#:LRLHD1AC-LCS/LRLHD1AD-LCSD LCS Lot-Sample#: H9L230000-355 

75.0 73.7 ug 98 KNOX 0050/26A Mod. 12/21/09 9357355 

75.0 77.5 ug 103 . 5.0 KNOX 0G5O/26A Mod 12/21/09 9357355 

Dilution Factor: 100 

Hydrogen chloride 

77.1 

77.1 

WO#;LRL131AC-LCS/LRL131AD-LCSD LCS Lot-Samplet: H9L240000-195 

77.2 ug 100. KNOX 0050/26A Mod 12/22/09 935B195 

75.S ug 98 2.0 KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 102.B 

NOTEtS) : 

Calculations are performed before rounding to avoid round-off errors in calculated results, 

VES019117 
49 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Chemistry 

Client Lot # -. . 

Date Sampled... 

: H9L210403 

: 12/17/09 

Matrix. AIR 

Date Received..: 12/19/09 

PARAMETER 

Chlorine 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

98 

78 

W0#: LRE24IAC-MS/LRE24lAD-MSD MS Lot-Sample #: H9L21O403-004 

(75 - 125) KNOX OO50/2SA Mod 12/21/09 9357355 

(75 - 125) 18 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 4720 

Hydrogen chloride 

107 (75 

118 (75 

W0#: LRE231AC-MS/LRE231AD-MSD MS Lot-Sample #: H9L210403-003 

125) KNOX 0050/26A Mod 12/22/09 9358195 

125) 1.8 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 44222 

NOTE(S); 

Calculaiions are performed before rounding to avoid round-off errors in calculaied results. 

VES019118 
50 

MATRIX SPIKE SAMPLE DATA EEPORT 

General Chemistry 

Clieat Lot #...: H9L210403 

Date Sampled....: 12/17/09 Date Received..: 12/19/09 

Matrix : AIR 

SAMPLE SPIKE MEASRD 

PARAMETER 

Chlorine 

AMODNT AMT 

20S 

208 

944 

944 

PERCNT 

RECVRY RPD METHOD 

PREPARATION- PREP 

AMOUNT UNITS . . . ANALYSIS DATE BATCH # 

WO#: LRE241AC-MS/LRE24lAD-MSD MS Lot-Sample #: H9L210403-004 

1130 ug 98 KNOX 0050/26A 12/21/09 9357355 

945 ug 78 18 KNOX 0050/26A 12/21/09 9357355 

Dilution Factor: 4720 

Hydrogen chloride 

.43100 8B40 

43100 8840 

WO#: LRE231AC-MS/LRE23lAD-MSD MS Lot-Sample #: H9L21O403-003 

52S00 ug 107 KNOX 0050/26A 12/22/09 9358195 

53500 ug 118 1.8 KNOX 0050/26A 12/22/09 9358195 

Dilution Factor: 44222 

NOTE(S) : 

Calculations arc pcribrmed before rounding lo avoid round-off errors in caioilnied results. 

VES019119 
51 

Client Lot ii...: H9L210403 

Date Sampled...: 12/16/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order ii...: LRE20-SMP 

LRE20-DUP 

Date Received..: 12/19/09 

DUPLICATE 

PARAM RESULT RESULT 

Hydrogen chloride 

34600 35900 

Matrxx. A IR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

~~ SD Lot-Sample #: H9L210403-OO1 

u g 3.7 {0-20} KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 44222.46 

VES019120 
52 

Client Lot #. 

Date Sampled. 

PARAM RESULT 

Chlorine 

ND 

. : H9L2104 03 

.: 12/16/09 

DDPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LRE22-SMP 

LRB22-DUP 

Date Received..: 12/19/09 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-0O2 

211 B ug 200 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 484 0 

NOTE(S)= 

Calculaiions arc pcrrornied berore roundins lo avoid round-orf errors in calculated rcsulis. 

B Estimated result. Result is less than RL. 

VES019121 
5 3 

Client Lot #...: H9L210403 

Date Sampled...: 12/17/09 

DUPLICATE 

PARAM RESULT RESULT 

Hydrogen chloride 

43100 44000 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LRE23-SMP 

LRE23-DUP 

Date Received..: 12/19/09 

Matrix. A IR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

' SD Lot-Sample #: H9L210403-0O3 

ug 2.1 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 44222.46 

VES019122 
54 

Client Lot #. 

Date Sampled. 

PARAM RESULT 

SAMPLE DUPLICATE EVALDATIOH REPORT 

General Chemistry 

.: H9L.210403 Work Order #...t LRE24-SMP 

LRE24-DUP 

.: 12/17/09 Date Received..: 12/19/09 

DUPLICATE 

RESULT UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Chlorine 

208 B ND 

SD Lot-Sample #: H9L210403-004 

ug 200 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Pacton 4720 

NOTE(S): 

Calculaiions are performed berore rounding to avoid round-ofT errors in calculated results. 

B Estimated result. Result is less than RL. 

VES019123 
55 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Client Lot ft...: H9L210403 Work Order #... 

Date Sampled...: 12/18/09 

LRE25-SMP 

LRE25-D0P 

Date Received..; 12/19/09 

Matrxx. . : AIR 

PARAW RESULT 

DUPLICATE 

RESULT UNITS RPD 

RPD 

LIMIT METHOD 

Hydrogen chloride 

3640 3590 

PREPARATION- PREP 

ANALYSIS DATE BATCH ft 

SD Lot-Sample #: H9L210403-005 

ug 1.5 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 1S8SS.24 

VES019124 
56 

Client Lot ft. 

Date Sampled. 

PARflM RESULT 

Chlorine 

204 B 

.: H9L2104O3 

.: 12/18/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order ft...: LRE26-SMP 

LRE26-DUP 

. Date Received..: 12/19/09 

ND 

Matrox. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH ft 

SD Lot-Sample ft: H9L210403-006 

ug 200 (0-20) KNOX 0O5O/26A Mod 12/21/09 93S7355 

Dilution Factor: 4800 

NOTE(S) : 

Calculiiions arc pcrrormcd before rounding io avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES019125 
57 

Client LOC #...:' H9L210403 

Date Sampled...: 12/15/09 

DDPLICATE 

PARAM RESULT RESULT 

Hydrogen chloride 

ND ND 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order LRE2B-SMP 

LRE2B-DUP 

Date Received..: 12/19/09 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-007 

ug 0 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 1028.43 

VES019126 
58 

Client Lot #. . . : H9L210403 

Date Sampled...: 12/15/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...r LRE29-SMP 

LRE29-DUP 

Date Received..: 12/19/0 9 

PARAM RESULT 

DUPLICATE 

RESULT 

Hydrogen chloride 

ND ND 

Matrxx. . : AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210403-008 

ug 0 (0-20) KNOX 0050/26A Mod 12/22/09 9358195 

Dilution Factor: 4113.72 

VES019127 
59 

Client Lot #=. 

Date Sampled. 

PARAM RESULT 

Chlorine 

ND 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

H9L210403 Work Order #.. 

12/15/09 

LRE3A-SMP 

LRE3A-DCP 

Date Received..: 12/19/09 

DUPLICATE 

RESULT UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

ND 

SD Lot-Sample #: H9L210403-009 

ug 0 (0-20) KNOX 0050/26A Mod 12/21/09 9357355 

Dilution Factor: 1000 

VES019128 
Method 0023A 

VES019129 
•Vista 

Analytical Laboratory 

January 12, 2010 

Vista Project LD.: 32313 

Mr. Jeffrey Gorman 

AJECOM Environment 

5015 Campuswood Drive 

Suite 104 

East.Syracuse, NY 13057-4232 

Dear Mr. Gorman, 

Enclosed are the results for the four MM5 samples received at Vista Analytical Laboratory on 

December 19, 2009 under your Project Name "60133216". These samples were extracted and 

analyzed using Method 0023A for tetra-through-octa chlorinated dioxins and furans. The front and 

back halves were extracted and analyzed separately for samples CPT-U4-M23-XAD-R1, -R2 and 

-R3. A standard turnaround time was provided for this work. 

The following report consists of a Sample Inventory (Section I), Analytical Results (Section II) 

and the Appendix, which contains the chain-of-custody, a list of data qualifiers and abbreviations, 

Vista's current certifications, and copies of the raw data (if requested). 

7ista Analytical Laboratory is committed to serving you effectively. If you require additional 

information, please contact me at 916-673-1520 or by email at mmaier@vista-analytical.com. 

Thank you for choosing Vista as part of your analytical support team. 

Sincerely, 

Martha M. Maier 

Laboratory Director 

Vtsta Anaiyiicai Laboratory certifies that the report herein meets all Ihe requirements set forth by NELAC for those applicable 

'fi, test methods. Results relate only to the samples as received by the laboratory. This report should not be reproduced except tnfull 

without the written approval of Visla Analytical Laboratory. 

Vista Analytical Laboratory I 1104Windfield Way | El Dorado Hills,CA 95762 I ph: 916-673-1520 [ fx: 916-673-0106 I wwww.vista-analytical.com 

Pro ject 32313 Page 1 of 18 

VES019130 
Wist a 

Section I: Sample Inventory Report 

Date Received: 12/19/2009 

Project No.: 32313 

Project Name: 60133216 

Lab. Sample ID Client Sample ID Component ID 

001 CPT-U4-M23A-XAD-R1 BHR 

XAD 

002 CPT-U4-M23A-PF-R1 FHR 

FILTER 

003 CPT-U4-M23A-XAD-R2 BHR 

XAD 

004 CPT-U4-M23A-PF-R2 FHR 

FILTER 

005 CPT-U4-M23A-XAD-R3 BHR 

XAD 

006 CPT-U4-M23A-PF-R3 FHR 

FILTER 

007 CPT-M23A-U4-FB ACE/MeC12/TOL 

FILTER 

XAD 

Smpinvgnmm5.rpi 

Project 32313 Page 2 of 18 

VES019131 
Vvista 

SECTION II 

Project 32313 

Page 3 of 18 

VES019132 
Method Blank Method 0023A 

Matrix: MM5 QC Batch No.: 2680 Lab Sample: 0-MB001 

Sample Size: Sample Date Extracted: 1-Jan-10 Date Analyzed DB-5: 9-Jan-10 Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) DL

 a EMPC b

 Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD ND IS 13C-2,3,7,8-TCDD 95.9 40 -135 

1,2,3,7,8-PeCDD ND 0.411 13C-1,2,3,7,8-PeCDD 88.5 40 - 135 

1,2,3,4,7,8-HxCDD ND 13C-1,2,3,6,7,8-HxCDD 93.6 40 -135 

1,2,3,6,7,8-HxCDD ND 0.533 13C-l,2,3,4,6,7,8-HpCDD 98.6 40 - 135 

1,2,3,7,8,9-HxCDD 13C-OCDD 94.9 40 -135 

1,2,3,4,6,7,8-HpCDD ND 0.667 l3C-2,3,7,8-TCDF 90.5 40-135 

OCDD ND • 1.37 ' 13C-l,2,3,7,8-PeCDF 82.9 40 - 135 

2,3,7,8-TCDF ND 0.294 13C-l,2,3,6,7,8-HxCDF 95.1 40-135 

1,2,3,7,8-PeCDF ND 13C-1,2,3,4,6,7,8-HpCDF 98.1 40 - 135 

2,3,4,7,8-PeCDF ND 0.319 13C-OCDF 94.4 40-135 

1,2,3,4,7,8-HxCDF ND 0.368 :.;^. V A^: f >-;U ' PS 37Cl-2,3,7,8-TCDD 92.9 70-130 

1,2,3,6,7,8-HxCDF ND 0.375 13C-2,3,4,7,8-PeCDF 84.4 70 - 130 

2,3,4,6,7,8-HxCDF ND 0.417 13C-l,2,3,4,7,8-HxCDD 97.9 70-130 

1,2,3,7,8,9-HxCDF ND 0.442 13C-l,2,3,4,7,8-HxCDF 95.4 70 - 130 

1,2,3,4,6,7,3-HpCDF ND ' -•'0.759:

'

:

V"•'•:^; v-":.'-- 13C-l,2,3,4,7,8,9-HpCDF 97.9 70 - 130 

1,2,3,4,7,8,9-HpCDF ND 0.896 AS 13C-l,2,3,7,8,9-HxCDF 98.1 40 - 135 

OCDF 0.915 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD ND 0.322 TEQ (Min-Max): 0-1.07 

Total PeCDD ND 

Total HxCDD ND 0.506 a. Sample specific estimated detection limit. 

Total HpCDD ND 0.667 b. Estimated maximum possible concentration. 

Total TCDF ND 0.294 c. Method detection limit. 

Total PeCDF ND 0 309 d. Lower control limit?, upper control Hmit.. • • '. 

Total HxCDF ND 0.400 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 0.828 -

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 4 of 18 

VES019133 
OPR Results Method 0023A 

Matrix: MM5 QC Batch No.: 2680 Lab Sample: 0-OPR001 

Sample Size: Sample Dale Extracted: l-Jan-10 Date Analyzed DB-5: 8-Jan-10 Date Analyzed DB-225: N A 

Analyte Spike Cone. Cone. (ng/mL) O PR Limits Labeled Standard % R LCL-UCL Qualifier 

2,3,7,8-TCDD 2.50 2.00 IS 13C-2,3,7,8-TCDD 88.7 40 - 135 

1,2,3,7,8-PeCDD 12.5 10.9 8.75 - 16.25 13C-l,2,3,7,8-PeCDD 85.3 40-135 

1,2,3,4,7,8-HxCDD 12.5 10.8 8.75 - 16.25 13C-l,2,3,6,7,8-HxCDD 90.8 40-135 

1,2,3,6,7,8-HxCDD 12.5 10.7 8.75 - 16.25 13C-l,2,3,4,6,7,8-HpCDD 90.5 40-135 

1,2,3,7,8,9-HxCDD 12.5 10.8 8.75 - 16.25 13C-OCDD 87.3 40-135 

1,2,3,4,6,7,8-HpCDD 12.5 10.7 8.75 - 16.25 13C-2,3,7,8-TCDF 86.4 40-135 

OCDD 25.0 20.8 17.5 - 32.5 13C-l,2,3,7,8-PeCDF 84.9 40 - 135 

2,3,7,8-TCDF 2.50 1.98 1.75-3.25 13C-l,2,3,6,7,8-HxCDF 90.4 40-135 

1,2,3,7,8-PeCDF 12.5 10.7 8.75 - 16 25 13C-l,2,3,4,6,7,8-HpCDF 88.7 40 - 135 

2,3,4,7,8-PeCDF 12.5 10.6 8.75 - 16.25 13C-OCDF 87.1 40-135 

1,2,3,4,7,8-HxCDF 12.5 10.9 8.75 - 16.25 AS 13C-l,2,3,7,8,9-HxCDF 90.5 40-135 

1,2,3,6,7,8-HxCDF 12.5 10.9 8.75 - 16.25 

2,3,4,6,7,8-HxCDF 12.5 10.9 8.75 - 16.25 

1,2,3,7,8,9-HxCDF 12.5 10.9 8.75 - 16.25 

1,2,3 4,6,7,8-HpCDF 12.5 10.6 8.75 - 16.25 

1,2,3,4,7,8,9-HpCDF 12.5 10.8 8.75 - 16.25 

OCDF 25.0 21.2 17.5-32.5 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 5 of 18 

VES019134 
Sample ID: CPT-U4-M23A-XAD-R1 Method 0O23A 

Client Data Sample Data Laboratory Data 

Name: AECOM Environment 

Project: 60133216 

Date Collected: 16-Dec-09 

Time Collected: N A 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32313-001 

QC Batch No.: 2680 

Date Analyzed DB-S: 9-Jan-10 

Date Received: 

Date Extracted: 

Dates Analyzed DB-225: 

19-Dec-09 

l-Jan-10 

10-Jan-10 

Analyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCLd Qualifiers 

2,3,7,8-TCDD 18.5 I§ 13C-2,3,7,8-TCDD 89.9 40 -135 

1,2,3,7,8-PeCDD 275 13C-l,2,3,7,8-PeCDD 87.4 40 - 135 

1,2,3,4,7,8-HxCDD 298 13C-l,2,3,6,7,8-HxCDD 92.9 40 - 135 

1,2,3,6,7,8-HxCDD 859 13C-1,2,3,4,6,7,8-HpCDD 93.3 40 - 135 

1,2,3,7,8,9-HxCDD 341 13C-OCDD 90.1 40-135 

1,2,3,4,6,7,8-HpCDD 2580 13C-2,3,7,8-TCDF 88.1 40 - 135 

OCDD 985 13C-l,2,3,7,8-PeCDF 87.7 40-135 

2,3,7,8-TCDF 86.5 13C-l,2,3,6.7,8-HxCDF 95.3 40-135 

1,2,3,7,8-PeCDF 126 13C-l,2,3,4,6,7,8-HpCDF 92.0 40 - 135 

2,3,4,7,8-PeCDF 578 13C-OCDF 88.4 40-135 

1,2,3,4,7,8-HxCDF 264 £S 37Cl-2,3,7,8-TCDD 86.5 70 - 130 

1,2,3,6,7,8-HxCDF 343 P 13C-2,3,4,7,8-PeCDF 85.5 70-130 

2,3,4,6,7,8-HxCDF 796 13C-l,2,3,4,7,8-HxCDD 95.2 70-130 

1,2,3,7,8,9-HxCDF 85.6 13C-1,2,3,4,7,8-HxCDF 97.5 70 - 130 

1,2,3,4,6,7,8-HpCDF 867 13C-l,2,3,4,7,8,9-HpCDF 93.0 70 - 130 

1,2,3,4,7,8,9-HpCDF 111 AS 13C-l,2,3,7,8,9-HxCDF 95.1 40 - 135 

OCDF 165 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 8450 8460 TEQ (Min-Max): 796-796 

Total PeCDD 16200 

Total HxCDD 16900 a. Sample specific estimated detection limit. 

Total HpCDD 5990 ' b. Estimated maximum possible concentration. . 

Total TCDF 12600 P c. Method detection limit. 

Total PeCDF 13200 P : d. Lower control limit - upper control limit. 

Total HxCDF 7880 P e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 2100 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 6 of 18 

VES019135 
V \ ' ta 

Sample ID: CPT-U4-M23A-PF-R1 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECOM Environment 

Project: 60133216 

Date Collected: 16-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32313-002 

QC Batch No.: 2680 

Date Analyzed DB-5: 9-Jan-10 

Date Received: 19-Dec-09 

Date Extracted: 1-Jan-10 

Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD ND IS 13C-2,3,7,8-TCDD 94.6 40-135 

1,2,3,7,8-PeCDD 14.1 J 13C-l,2,3,7,8-PeCDD 93.4 40 - 135 

1,2,3,4,7,8-HxCDD 13C-l,2,3,6,7,8-HxCDD 97.1 40 - 135 

1,2,3,6,7,8-HxCDD 64.5 13C-l,2,3,4,6,7,8-HpCDD 102 40-135 

1,2,3,7,8,9-HxCDD 37.2 13C-OCDD 96 4 40 - 135 

1,2,3,4,6,7,8-HpCDD 364 13C-2,3,7,8-TCDF 93.0 40 - 135 

OCDD 263 13C-l,2,3,7,8-PeCDF 92.1 40 - 135 

2,3,7,8-TCDF 3.66 J 13C-l,2,3,6,7,8-HxCDF 97.1 40-135 

1,2,3,7,8-PeCDF 6.47 13C-l,2,3,4,6,7,8-HpCDF 100 40 - 135 

2,3,4,7,8-PeCDF 30.1 J 13C-OCDF 95.0 40-135 

1,2,3,4,7,8-HxCDF 17.8 E§ 37Cl-2,3,7,8-TCDD NA 70 - 130 

1,2,3,6,7,8-HxCDF 24.4 J,P 13C-2,3,4,7,8-PeCDF NA 70- 130 

2,3,4,6,7,8-HxCDF 64.4 13C-l,2,3,4,7,8-HxCDD NA 70 - 130 

1,2,3,7,8,9-HxCDF 10.9 j 13C-l,2,3,4,7,8-HxCDF NA 70- 130 

1,2,3,4,6,7,8-HpCDF 90.0 13C-l,2,3,4,7,8,9-HpCDF NA 70-130 

1,2,3,4,7,8,9-HpCDF 20.9 J M 13C-l,2,3,7,8,9-HxCDF 99.7 40-135 

OCDF 44.7 j 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 184 TEQ (Min-Max): 51.9-52.3 

Total PeCDD 587 589 

Total HxCDD 1150 a. Sample specific estimated detection limit. 

Total HpCDD 745 ^b\Estiina^ 

Total TCDF 242 256 c. Method detection limit. 

Total PeCDF 423 -' P d. Lower control lirnit - upper control limit 

Total HxCDF 461 P e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 240 

Analyst: MAS Approved By. Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 7 of 18 

VES019136 
I i V \ ta 

Sample IB: CPT-U4-M23A-XAD-R2 Method 0O23A 

Client Data Sample Data Laboratory Data 

Name: AECOM Environment 

Project: 60133216 

Date Collected: 17-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32313-003 

QC Batch No.: 2680 

Date Analyzed DB-5: 9-Jan-10 

Date Received: 19-Dec-09 

Date Extracted: 1-Jan-10 

Dates Analyzed DB-225: - 10-Jan-10 

Analyte Cone. (pg/Sample) DL

 a EMPCb Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD 24.0 IS 13C-2,3,7,8-TCDD 94.8 40 - 135 

1,2,3,7,8-PeCDD 327 13C-l,2,3,7,8-PeCDD 85.8 40-135 

1,2,3,4,7,8-HxCDD 266 13C-l,2,3,6,7,8-HxCDD 93.6 40 - 135 

1,2,3,6,7,8-HxCDD 791 13C-l,2,3,4,6,7,8-HpCDD 93.0 40-135 

1,2,3,7,8,9-HxCDD 356 13C-OCDD 85.0 40 - 135 

1,2,3,4,6,7,8-HpCDD 2090 13C-2,3,7,8-TCDF 90.9 40-135 

OCDD 711 13C-1,2,3,7,8-PeCDF 88.0 40 - 135 

2,3,7,8-TCDF 83.8 13C- 1,2,3,6,7,8-HxCDF 97.7 40- 135 

1,2,3,7,8-PeCDF 13C-l,2,3,4,6,7,8-HpCDF 94.4 40-135 

2,3,4,7,8-PeCDF 484 13C-OCDF 84.0 40-135 

1,2,3,4,7,8-HxCDF F i 37Cl-2,3,7,8-TCDD 90.1 70 - 130 

1,2,3,6,7,8-HxCDF 268 P 13C-2,3,4,7,8-PeCDF 86.3 70- 130 

2,3,4,6,7,8-HxCDF 13C-l,2,3,4,7,8-HxCDD 93.3 70 - 130 

1,2,3,7,8,9-HxCDF 45.9 J 13C-l,2,3,4,7,8-HxCDF 103 70 - 130 

1,2,3,4,6,7,8-HpCDF 638 13C-l,2,3,4,7,8,9-HpCDF 88.5 70 - 130 

1,2,3,4,7,8,9-HpCDF 57.5 AS 13C-l,2,3,7,8,9-HxCDF 92.8 40-135 

OCDF 85.9 J 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 8040 TEQ (Min-Max): 723 - 723 

Total PeCDD 16300 

Total HxCDD 15500 a Sample specific estimated detection limit. 

Total HpCDD 4800 b. Estimated maximum possible concentration 

Total TCDF 13500 c. Method detection limit. 

Total PeCDF 13000 d: IJower.control limit- upper control limit. *• 

Total HxCDF 6230 p e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 1300 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 8 of 18 

VES019137 
\

V V ta 

Sample ID: CPT-U4-M23A-PF-R2 Method 0O23A 

Client Data Sample Data Laboratory Data 

Name: AECOM Environment 

Project: 60133216 

Date Collected: 17-Dec-09 

Time Collected: N A 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32313-004 

QC Batch No.: 2680 

Date Analyzed DB-5: 9-Jan-10 

Date Received: 19-Dec-09 

Date Extracted: l-Jan-10 

Date Analyzed DB-225: j\JA 

Analyte Cone. (pg/Sample) DL

 a EMPCb Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD ND ' 0.569 IS 13C-2,3,7,8-TCDD 87.4 40-135 

1,2,3,7,8-PeCDD 12.9 J 13C-l,2,3,7,8-PeCDD 79.7 40-135 

1,2,3,4,7,8-HxCDD 20.5 J 13C-1,2,3,6,7,8-HxCDD 89.3 40-135 

1,2,3,6,7,8-HxCDD 62.5 13C-1,2,3,4,6,7,8-HpCDD 85.3 40-135 

l,2,3;7,8,9-HxCDD 28.6 J 13C-OCDD 78.5 40 - 135 

1,2,3,4,6,7,8-HpCDD 352 13C-2,3,7,8-TCDF 84.2 40-135 

OCDD 276 13C-1,2,3,7,8-PeCDF 76.9 40 - 135 

2,3,7,8-TCDF 3.66 J 13C-1,2,3,6,7,8-HxCDF 90.6 40-135 

1,2,3,7,8-PeCDF 6.57 13C-l,2,3,4,6,7,8-HpCDF 86.0 40 - 135 

2,3,4,7,8-PeCDF 26.4 J 13C-OCDF 79.5 40 -135 

1,2,3,4,7,8-HxCDF 179 PS 37Cl-2,3,7,8-TCDD NA 70 -130 

1,2,3,6,7,8-HxCDF 24.0 J.P 13C-2,3,4,7,8-PeCDF NA 70 - 130 

2,3,4,6,7,8-HxCDF 61.0 13C-l,2,3,4,7,8-HxCDD : NA 70-130 

1,2,3,7,8,9-HxCDF 10.4 j 13C-l,2,3,4,7,8-HxCDF NA 70 - 130 

1,2,3,4,6,7,8-HpCDF 91.6 13C-1,2,3,4,7,8,9-HpCDF . NA 70-130 

1,2,3,4,7,8,9-HpCDF 21.4 j AS 13C-l,2,3,7,8,9-HxCDF 89.7 40-135 

OCDF 47.0 J 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 174 TEQ (Min-Max): 47.8 - 48.4 

Total PeCDD 524 

Total HxCDD 1090 a. Sample specific estimated detection limit. 

Total'HpCDD 721 b. Estimated maximum possible concentration. 

Total TCDF 218 230 c. Method detection limit. 

Total PeCDF 401 d. Lowercontiol limit - upper control limit.-::;; 

Total HxCDF 462 p e. TEQ based on (1989) International Toxic Equh alent Factors (ITEF). 

Total HpCDF A242f;

:.;: 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 9 of 18 

VES019138 
ta 

Sample ID: CPT-U4-M23A-XAD-R3 Method 0O23A 

Client Data 

Name: 

Project: 

Date Collected: 

Time Collected: 

AECOM Environment 

60133216 

18-Dec-09 

NA 

Sample Data 

Matrix: MM5 

Sample Size: Sample 

Laboratory Data 

Lab Sample: 

QC Batch No.: 

Date Analyzed DB-5: 

32313-005 Date Received: 19-Dec-09 

2680 Date Extracted: J - Jan-10 

9-Jan-10 Dates Analyzed DB-225: 10-Jan-10 

Analyte Cone. (pg/Sample) DL EMPCU

 Qualifiers Labeled Standard %R LCL-UCL" Qualifiers 

79.5 40 135 

85.5 40- 135 

96.8 40- 135 

97.2 40- 135 

94.5 40- 135 

71.4 40- 135 

82.1 40- 135 

105 40- 135 

98.7 40- 135 

92.2 40- 135 

70.0 70- 130 

69.4 70- 130 

81.4 70- 130 

82.5 70- 130 

52.6 70- 130 

96.1 40- 135 

2,3,7,8-TCDD 20 3 

1,2,3,7,8-PeCDD 293 

1,2,3,4,7,8-HxCDD 259 

1.2.3.6.7.8- HxCDD 817 

1.2.3.7.8.9- HxCDD 347 

1,2,3,4,6,7,8-HpCDD 2380 

OCDD 812 

2,3,7,8-TCDF 85.5 

1,2,3,7,8-PeCDF 141 

2,3,4,7,8-PeCDF 647 

1,2,3,4,7,8-HxCDF 263 

1,2,3,6,7,8-HxCDF 343 

2.3.4.6.7.8- HxCDF 749 

1.2.3.7.8.9- HxCDF 70.8 

1.2.3.4.6.7.8- HpCDF 870 

1.2.3.4.7.8.9- HpCDF 96.6 

OCDF 135 

IS 13C-2,3,7,8-TCDD 

13C-l,2,3,7,8-PeCDD 

13C-l,2,3,6,7,8-HxCDD 

13C-l,2,3,4,6,7,8-HpCDD 

13C-OCDD 

13C-2,3,7,8-TCDF 

13C-1,2,3,7,8-PeCDF ; M 

13C-l,2,3,6,7,8-HxCDF 

13C-1,2,3,4,6,7,8-HpCDF 

13C-OCDF 

?S 37Cl-2,3,7,8-TCDD 

13C-2,3,4,7,8-PeCDF . 

13C-l,2,3,4,7,8-ILxCDD 

13C- 1,2,3,4,7,8-HxCDF 

13C-l,2,3A7,8,9-HpCDF 

AS 13C-1,2,3,7,8,9-HxCDF 

Totals Toxic Equivalent Quotient (TEQ) Data 

Total TCDD 

Total PeCDD 

Total HxCDD 

Total HpCDD 

Total TCDF 

Total PeCDF 

Total HxCDF 

Total HpCDF 

7530 

15i00 

15600 

5680 

13900 

15200 

7860 

2000 

TEQ (Min-Max): 825-825 

a Sample specific estimated detection limit. 

b. Estimated maximum possible concentration. 

c. Method detection limit. 

d. Lower control limit - upper control limit 

e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 10 of 18 

VES019139 
V \ >ta 

Sample ID: CPT-U4-M23A-PF-R3 Method 00 23A 

Client Data Sample Data Laboratory Data 

Name: AECOM Environment 

Project: 60133216 

Date Collected: 18-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32313-006 

QC Batch No.: 2680 

Date Analyzed DB-5: 9-Jan-10 

Date Received: j 9^Dec-09 

Date Extracted: l-Jan-10 

Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) DL

 a EMPCb Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD ND 0.381 l§ 13C-2.3,7,8-TCDD 85.7 40 - 135 

1,2,3,7,8-PeCDD 17.7 J 13C-l,2,3,7,8-PeCDD 82.2 40-135 

1,2,3,4,7,8-HxCDD 27.0 13C-1,2,3,6,7,8-HxCDD 89 8 40-135 

1,2,3,6,7,8-HxCDD 84.3 13C-l,2,3,4,6,7,8-HpCDD 94.7 40 - 135 

1,2,3,7,8,9-HxCDD 41 3 13C-OCDD 91.7 40 - 135 

1,2,3,4,6,7,8-HpCDD 515 13C-2,3,7,8-TCDF 87.8 40 - 135 

OCDD 377 13C-l,2,3,7,8-PeCDF 82.1 40-135 

2,3,7,8-TCDF 4.85 J 13C-l,2,3,6,7,8-HxCDF 91.9 40-135 

1,2,3,7,8-PeCDF 9.78 J 13C-l,2,3,4,6,7,8-HpCDF 92.9 40 - 135 

2,3,4,7,8-PeCDF 45.3 J 13C-OCDF 92.2 40-135 

1,2,3,4,7,8-HxCDF 28.4 J PS 37Cl-2,3,7,8-TCDD .. '•' NA 70-130 

1,2,3,6,7,8-HxCDF 36.3 J,P 13C-2,3,4,7,8-PeCDF NA 70 - 130 

2,3,4,6,7,8-HxCDF 99.1 13C-l,2,3,4,7,8-HxCDD : • ;NA:

' 70 - 130 

1,2,3,7.8,9-HxCDF 15.8 J 13C-l,2,3,4,7,8-HxCDF NA 70-130 

1,2,3,4,6,7,8-HpCDF -;AB7:y.#;

i

;

-S;:'

:

 '".,./-v 13C-l,2,3,4,7,8,9-HpCDF •"::

;

:NA:- 70-130 

1,2,3,4,7,8,9-HpCDF 33.5 J M lSC-l^.SJ.S^-HxCDF 90.3 40 - 135 

OCDF 66.1 J 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 231 235 TEQ (Min-Max): 72.9 - 73.3 

Total PeCDD 739 

Total HxCDD 1510 a. Sample specific estimated detection limit. 

Total HpCDD 1120 b. Estimated maximum possible concentration. 

Total TCDF 368 c. Method detection limit. 

Total PeCDF 661 664 > :;p, ; d. Lower control limit - upper control'limit 

Total HxCDF 726 P e, TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 399 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 11 of 18 

VES019140 
W ;ta 

Sample DD: CPT-M23A-U4-FB Method 0O23A 

Client Date Sample Data Laboratory Data 

Name: AECOM Environment 

Project: 60133216 

Date Collected: 18-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32313-007 

QC Batch No.: 2680 

Date Analyzed DB-5: 9-Jan-10 

Date Received: 19-Dec-09 

Date Extracted: l-Jan-10 

Date Analyzed DB-225: NA 

Anaiyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD ND 0.329 IS 13C-2,3,7,8-TCDD 91.9 40 - 135 

1,2,3,7,8-PeCDD ND 0.457 13C-l,2,3,7,8-PeCDD 87.9 40 - 135 

1,2,3,4,7,8-HxCDD ND 0.674 13C-1,2,3,6,7,8-HxCDD 40 - 135 

1,2,3,6,7,8-HxCDD ND 0.709 13C-l,2,3,4,6,7,8-HpCDD 98.8 40 - 135 

1,2,3,7,8,9-HxCDD ND 0.634 13C-OCDD 95.6 40-135 

1,2,3,4,6,7,8-HpCDD ND 0.754 13C-2,3,7,8-TCDF 90.4 40 - 135 

OCDD 20.2 13C-l,2,3,7,8-PcCDF 86.6 40 - 135 

2,3,7,8-TCDF ND 0.410 13C-l,2,3,6,7,8-HxCDF 95.3 40-135 

1,2,3,7,8-PeCDF ND 0.434 13C-l,2,3,4,6,7,8-HpCDF 95.7 40 - 135 

2,3,4,7,8-PeCDF 1.33 J 13C-OCDF 95.6 40-135 

1,2,3,4,7,8-HxCDF ND 0.635 ES 37Cl-2,3,7,8-TCDD 89.0 70 - 130 

1,2,3,6,7,8-HxCDF ND 0.648 13C-2,3,4,7,8-PeCDF 87.0 70-130 

2,3,4,6,7,8-HxCDF "ND 0.720 13C-1,2,3,4,7,8-HxCDD 96.2 70-130 

. 1,2,3,7,8,9-HxCDF ND 0.763 13C-l,2,3,4,7,8-HxCDF 94.7 70-130 

1,2,3,4,6,7,8-HpCDF 6.25 J 13C-1,2,3,4,7,8,9-HpCDF , 97.2 70-130 

1,2,3,4,7,8,9-HpCDF ND 0.878 AS 13C-l,2,3,7,8,9-HxCDF 92.1 40 - 135 

OCDF ND 0.810 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 1.64 TEQ (Min-Max): 0.748-1.86 

Total PeCDD ND 0.457 

Total HxCDD ND 0.672 a. Sample specific estimated detection limit 

Total HpCDD ND 0.754 ib. Estimated maximum possible concentration: ' 

Total TCDF 4.49 c. Method detection limit. 

Total PeCDF 8.03 d. Lower control limit - upper conSol limit. 

Total HxCDF 4.71 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 6.25 

Analyst: MAS Approved By: Martha M. Maier 12-Jan-2010 13:41 

Project 32313 Page 12 of 18 

VES019141 
Wist a 

APPENDIX 

Page 13 of 18 

VES019142 
Wist a 

DATA QUALIFIERS & ABBREVIATIONS 

B This compound was also detected in the method blank. 

D Dilution 

E The amount detected is above the High Calibration Limit. 

P The amount reported is the maximum possible concentration due to possible 

chlorinated diphenylether interference. 

H Recovery was outside laboratory acceptance limits. 

I Chemical Interference 

J The amount detected is below the Low Calibration Limit. 

* See Cover Letter 

Cone. Concentration 

DL Sample-specific estimated detection limit 

MDL The minimum concentration of a substance that can be measured and 

reported with 99% confidence that the analyte concentration is greater 

than zero in the matrix tested. 

EMPC Estimated Maximum Possible Concentration 

NA Not applicable 

RL Reporting Limit - concentrations that correspond to low calibration point 

ND Not Detected 

TEQ Toxic Equivalency 

Unless otherwise noted, solid sample results are reported in dry weight. Tissue samples are reported 

in wet weight. 

Project 32313 Page 14 of 18 

VES019143 
Vvista 

CERTIFICATIONS 

Accrediting Authority Certificate Number 

State of Alaska, DEC CA413-2008 

State of Arizona AZ0639 

State of Arkansas, DEQ 08-043-0 

State of Arkansas, DOH Reciprocity through CA 

State of California - NELAP Primary AA 02102CA 

State of Colorado N/A 

State of Connecticut PH-0182 

State of Florida, DEP E87777 

State of Indiana Department of Health C-CA-02 

Commonwealth of Kentucky 90063 

State of Louisiana, Health and Hospitals LA08000 

State of Louisiana, DEQ 01977 

State of Maine 2008024 

State of Michigan 9932 

State of Mississippi Reciprocity through CA 

Naval Facilities Engineering Service Center NFESC413 

State of Nevada CA004132007A 

State of New Jersey CA003 

State of New Mexico Reciprocity through CA 

State of New York, DOH 11411 

State of North Carolina 06700 

State of North Dakota, DOH R-078 

State of Oklahoma D9919 

State of Oregon CA200001-006 

State of Pennsylvania 68-00490 

State of South Carolina 87002001 

State of Tennessee TN02996 

State of Texas T104704189-08-TX 

U.S. Army Corps of Engineers N/A 

State of Utah CA16400 

Commonwealth of Virginia 00013 

State of Washington C1285 

State of Wisconsin 998036160 

State of Wyoming 8TMS-Q 

Project 32313 Page 15 of 18 

VES019144 
I 

^2-3/3 , S-Vc, Anklet 

Sample Traceability List 

Site of Program: Veolia ES Tech Sample Date: tPJ/6- lAfiPJo** Project Location: Sauget, IL Lab PO 

Type of Program: CPT Date Shipped: * JZ/tfyoH Laboratory: Vista Analytical 

Pro]ect#: 60133216 El Dorado Hills, CA 

Program Office: Syracuse NY 

Shipper / Steven Milo 

Recovery: Jeff Gorman 

Laboratory: Vista Analytical 

El Dorado Hills, CA 

Program Contact: Jeff Gorman FedEx Air BUI #: 

Item Sample ID Code Sample Matrix Sample Description Analytical Parameters Special Instructions 

1 CPT-U4-M23A-XAD-R1 XAD2 RESIN M23 XAD Resin Trap, Run 1 PCDDs/PCDFs EPA 0023A 

2 CPT-U4-M23A-PF-R1 FILTER M23 PM Filter, Run 1 PCDDs/PCDFs EPA 0023A 

3 • 

4 CPT-U4-M23A-XAD-R2 XAD2 RESIN M23 XAD Resin Trap, Run 2 PCDDs/PCDFs EPA 0023A 

5 CPT-U4-M23A-PF-R2 FILTER M23 PM Filter, Run 2 PCDDs/PCDFs EPA 0023A 

6 

7 CPT-U4-M23A-XAD-R3 XAD2 RESIN M23 XAD Resin Trap, Run 3 PCDDs/PCDFs 

8 CPT-U4-M23A-PF-R3 FILTER M23 PM Filter, Run 3 PCDDs/PCDFs 

9 

10 CPT-M23A-PF-U4-FB FILTER Particulate Filter Field Blank PCDDs/PCDFs EPA 0023A 

11 C PT-M 23 A-XAD-U4-F B XAD2 RESIN Xad Resin Trap Field Blank PCDDs/PCDFs EPA 0023A 

12 CPT-M23A-U4-Field Blank Acetone/MeCI^Toiuene M23 Blank PCDDs/PCDFs EPA 0023A 

13 

14 CPT-U4-M23A-FHR-R1 Acetone/MeClaToluene M23A Front Half Rinse, Run 1 PCDDs/PCDFs EPA 0023A 

15 CPT-U4-M23A-FHR-R2 Acelone/MeCi^Toluene M23A Front Half Rinse, Run 2 PCDDs/PCDFs EPA 0023A 

16 CPT-U4-M23A-FHR-R3 Acetone/MeCl^Toluene M23A Front Half Rinse, Run 3 PCDDs/PCDFa EPA0023A 

17 

18 CPT-U4-M23A-BHR-R1 Acetone/MeClaTolUBne M23A Back Half Rinse, Run 1 PCDDs/PCDFs EPA 0023A 

19 CPT-U4-M23A-BHR-R2 Acetone/MeClaToluene M23A Back Half Rinse, Run 2 PCDDs/PCDFs EPA 0023A 

20 CPT-U4-M23A-BHR-R3 Acetone/MeCVToluene M23A Back Half Rinse, Run 3 PCDDs/PCDFs EPA 0023A 

Field N Dtes/ Comments 

Page 1 of 1 

Relinquished By (print): Date; 

Steven Milo M/t</70J 

Signature: ^ . Time: 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

iReceived by Lab (print): Date: 

Signature: Time: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Vista Analytical Laboratories, Inc. 

1104WindfieldWay 

El Dorado Hills, CA 95762 

| Attn: Ms. Martha Maier 916-673-1520 

Project 32313 Page 16 of 18 

VES019145 
SAMPLE LOG-JN CHECKLIST 

Vista Project*: \*h 

V>#Vista 

W Analytical Laboratory 

Samples Arrival: 

Date/Time Initials: Location: (jjv^- ^ 

Shelf/Rack: 

Logged In: 

Date/Time Initials: Location: ^ 

Shelf/Rack: fO/A 

Delivered By: (^FedS^) UPS Cal DHL n

 Hari d

 . Other Delivered 

Preservation: Ice (^Bkte Ice^) Dry Ice None 

Temp° C Time: Thermometer ID: IR-1 

Sfffllli^ ^ YES NO NA 

Adequate Sample Volume Received? 

Holding Time Acceptable? 

Shipping Container(s) Intact? 

Shipping Custody Seals Intact? 

Shipping Documentation Present? 

Airbill Trk# <£U % S U ? . ^TZJO 

Sample Container Intact? 

Sample Custody Seals Intact? > 

Chain of Custody / Sample Documentation Present? 

COC Anomaly/Sample Acceptance Form completed? 

If Chlorinated or Drinking Water Samples, Acceptable Preservation? 

Na2S2 03 Preservation Documented? 

Shipping Container ^^/ista ^ Client /•^RetairT^ Return Dispose 

pp - p £ 

Project 3231 3 

Sample Login 3/2007 rmh 

Page 17 of 18 

VES019146 
SAMPLE LOG-IN CHECKLIST 

Vista Project #: 

Vn/ista 

W Analytical Laboratory 

Samples Arrival: 

Date/Time initials: Location:^ 

Shelf/Rack: W 1 A " 

Logged In: 

Date/Time Initials: Location: ^ —/ 

Shelf/Rack: AV/ 1 

Delivered By: . ^FedEx5

^ I UPS Cal D H L

 Delivered ° ^ 

Preservation: ^ ^__^-4ce Blue Ice Dry Ice ('None ^ 

Temp°C I\YVA^V~ Time :

 [QZPl Thermometer ID: IR-1 

Adequate Sample Volume Received? 

Holding Time Acceptable? 

Shipping Container(s) Intact? 

Shipping Custody Seals Intact? 

Shipping Documentation Present? 

Airbill Trk#

<

g06?(p Sl\7 Vl^ 

Sample Container Intact? 

Sample Custody Seals Intact? 

Chain of Custody / Sample Documentation Present? 

COC Anomaly/Sample Acceptance Form completed? 

If Chlorinated or Drinking Water Samples, Acceptable Preservation? 

Na2S2 03 Preservation Documented? 

Shipping Container Vista 

COC 

Comments: 

rf' 

Sample 

Container 

Retain 

rf 

rf 

Return 

Project 3231 3 

Sample Login 3/2007 rmh 

Page 18 of 18 

VES019147 
Waste Feed 

i 

VES019148 
TestAmerica Laboratories, Inc. 

ANALYTICAL REPORT 

PROJECT NO. 60133216 

Veolia - ES Tech 

Lot #: H9L210404 

Jeff Gorman 

AECOM, Inc 

5105 Cairrpuswood Drive 

Suite 104 

East Syracuse, NY 13057 

TESTAMERICA LABORATORIES, INC. 

Kevin S. Woodcock 

Project Manager 

January 21, 2010 

5815 Middlebrook Pike Knoxville, TN 37921 tel 865.291.3000 fax 865.584.4315 www.tesiamericainc.com 

i 

VES019149 
ANALYTICAL METHODS SUMMARY 

H9L210404 

ANALYTICAL 

PARAMETER METHOD 

Ash Content ASTM D482-00a 

Heat of Combustion ASTM D240-02 

Heat of Combustion D5865 ASTM D5865-00 

Total Chlorine KNOX WC-001S 

References: 

ASTM Annual Book Of ASTM Standards. 

KNOX TestAmerica Laboratories Inc., Knoxville Laboratory Standard 

Operating Procedure 
3 

SAMPLE SUMMARY 

H9L210404 

SAMPLED SAMP 

WO # SAMPLE* CLIENT SAMPLE ID DATE 

LRE33 001 HBTU-U4-M23A-R1 12/16/09 

LRE34 002 HBTU-TJ4 -M23A-R2 12/17/09 

LRE3 5 003 HBTU-U4-M23A-R3 12/18/09 

LRE3 6 004 LBTU-U4-M23A-R1 12/16/09 

LRE3 7 005 LBTLT-U4-M23A-R2 12/17/09 

LRE3 8 006 LBTU-U4 -M2 3A-R3 12/18/09 

LRE4C 007 SF-U4-M23A-R1 12/16/09 

LRE4D 008 SF-U4-M23A-R2 12/17/09 

LRE4F 009 SF-U4-M23A-R3 12/18/09 

LRE4G 010 CS-U4-M23A-R1 12/16/09 

LRE4H O il CS-U4-M23A-R2 12/17/09 

LRE4J 012 CS-U4-M23A-R3 12/18/09 

LRE4K 013 BS-U4-M23A-R1 12/16/09 

LRE4L 014 BS-U4-M23A-R2 12/17/09 

LRE4M 015 BS-U4-M23A-R3 12/18/09 

LRE4N 015 HBTU-U4-M26A-R1 12/16/09 

LRE4P 017 HBTU-U4-M2SA-R2 12/17/09 

LRE4Q 018 HBTU-U4-M26A-R3 12/18/09 

LRE4R 019 LBTU-U4-M2 6A-R1 12/16/09 

;LRE4T 020 LBTU-TJ4-M2 6A-R2 12/17/09 

LRE4V 021 LBTU-U4-M26A-R3 12/18/09 

LRE4W 022 SF-U4-M26A-R1 12/16/09 

LRE4X 023 SF-U4-M26A-R2 12/17/09 

LRE40 024 SF-U4-M26A-R3 12/18/09 

LRE43 025 CS-U4-M26A-R1 12/16/09 

LRE44 026 CS-U4-M26A-R2 12/17/09 

LRE45 027 CS-U4-M26A-R3 12/1B/09 

LRE46 028 BS-U4-M26A-R1 12/16/09 

LRE47 029 BS-TJ4-M26A-R2 12/17/09 

LRE48 030 BS-U4-M26A-R3 12/18/09 

NQTE(S) : : 

- The analyfeal rcsulu of the samples Iisred above are presented on the following pages 

• All calculiicns are performed before rounding lo avoid round-off errors in calculated results. 

- Results noted as "ND" were not detected at or above the stated limit. 

- This repon must not be reproduced, except in full, without the written approval of the laboratory. 

- Results forthe following parameters are never reported on a dry weight basis: color, corrosiviiy, density, flashpoinL, ignitability, layers, odor, 

paint filietiest, pH. porosity pressure, reactivity, redox poiemial, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight. 

I 

VES019151 
4 

PROJECT NARRATIVE 

H9L210404 

The results reported herein are applicable to the samples submitted for analysis only. 

This report shall not be reproduced except in full, without the written approval of the 

laboratory. 

The original chain of custody documentation is included with this report. 

Sample Receipt 

Custody seals were not present. 

Quality Control and Data Interpretation 

Unless otherwise rioted, all holding times and QC criteria were met and the test results 

shown in this report meet all applicable NELAC requirements. 

Ash Content: 

The ash content of the samples was determined using SOP number KNOX-WC-0013 

(based on ASTM Methods A4422, D482, and E830). A ten gram aliquot of sample is 

fired in a pre-tared crucible at 750° ± 25° C in a forced-draft muffle furnace. The total 

weight of ash residue and the crucible is measured on a 4-place analytical balance, and 

the residue weight is determined by difference. The ratio of the residue weight (mg) and 

the initial sample weight (kg) is used to calculate the ash content ofthe sample. 

The duplicate RPD result for sample LBTU-U4-M26A-R3 is outside control limits. The 

laboratory control sample showed acceptable results indicating that the analysis was in 

control. The duplicate result is attributed to sample heterogeneity. 

Gross Calorific Value: 

The heat of combustion (gross calorific value) ofthe samples was determined using SOP 

number KNOX-WC-0010 (based on ASTM Method D5865 for solids and ASTM Method 

D240 for liquids). A waste feed sample is combusted in an oxygen bomb that has been 

placed in a bomb calorimeter. The energy released during this combustion process is 

TestAmerica Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Lab #88-

0688, California DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Lab #PH-0223, Florida DOH Lab 

#E87177, Georgia DNR Lab #906, Hawaii DOH, Illinois EPA Lab #200012, Indiana DOH Lab #C-TN-02, Iowa DNR 

Lab #375, Kansas DHE Cert. #E-I0349, Kentucky DEP Lab #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH, 

Maryland DOE Cert. #277, Michigan DEQ Lab #9933, Nevada DEP, New Jersey DEP Lab #TN00i, New York DOH 

Lab # 10781, North Carolina DPH Lab #21705, North Carolina DEHNR Cert. #64, Ohio EPA VAP Lab #CL0059, 

Oklahoma DEQ Lab #9415, Pennsylvania DEP Lab #68-00576, South Carolina DHEC Cert #84001001, Tennessee 

DOH Lab #02014, Texas CEQ, Utah DOH Lab # QUAN3, Virginia DGS Lab #00165, Washington DOE Lab #C1314, 

West Virginia DEP Cert. #345, West Virginia DHHR Cert #9955C, Wisconsin DNR Lab #998044300, Naval Facilities 

Engineering Service Center and USDA Soil Permit #S;46424. This list of approvals is subject to change and does not 

imply that laboratory certification is available for all parameters reported in this environmental sample data report. 

I 

VES019152 
PROJECT NARRATIVE 

H9L210404 

captured in the calorimeter, and the temperature rise of a water bath surrounding the 

bomb is measured. The temperature rise is proportional to the heat liberated during the 

combustion in calories. The gross calorific value is calculated from the temperature rise, 

the sample weight, and the calibration coefficient of the calorimeter. Certain extraneous 

sources of heat are assessed, and the effect of these heat sources is accounted for in the 

calculation, as well as the affect of various accelerants that are added to enhance 

combustion of the sample. The gross heat of combustion is calculated in units of cal/g 

using the following equation: 

Q(gross ) = [(AtEE)-(e 1 + e 2 + e 3+e4 ) ] 

m 

Where: 

Q (gross) = gross calorific value at constant volume as determined, cal/g. 

EE = the heat capacity of the calorimeter, cal/°C. 

At = corrected temperature rise as measured by the calorimeter, °C. 

ei = Correction for heat of formation of nitric acid in calories, calculated by 

the calorimeter based on the energy released by the sample. 

e2 = Correction for sulfur, which is usually 0. 

ej = Correction for fuse wire. 

e4 = Correction for spike addition that is calculated by the calorimeter using 

the spike weight benzoic acid equivalent (grams) times the benzoic 

acid heat of combustion (6318 cal/gram). 

m = mass of the sample, g. 

The results are converted to Btu/lb, as necessary using the following conversion factor: 

1 Btu/lb = 1.8 cal/gram 

The duplicate RPD results for samples LBTU-U4-M26A-R3 & BS-U4-M26A-R2 are 

outside control limits. The sample and/or duplicate results are below the reporting limit 

and are reported as estimated values. The laboratory control sample showed acceptable 

results indicating that the analysis was in control. The results are attributed to sample 

heterogeneity and increased method variability at levels below the reporting limit. 

Total Chlorine: 

The samples were prepared for total chlorine using SOP number KNOX-WC-0016 (based 

on ASTM Method E442 and SW-846 Method 5050). The sample is oxidized by 

combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen 

under pressure. The liberated halogen compounds are absorbed primarily as halides in a 

sodium carbonate/sodium bicarbonate buffer solution. The combustion products are 

collected by repeated rinsing of the combustion apparatus, and analyzed by ion 
PROJECT NARRATIVE 

H9L210404 

chromatography in accordance with SOP BCNOX-WC-0005 (based on SW-846 Method 

9056). The results are calculated using the following equation: 

Q = -com * com_ x lOOOff/fe 

W 

concentration of analyte in the sample, mg/kg. 

concentration of analyte inthe combustate, mg/L. 

total volume of combustate, L. 

weight of sample combusted, g. 

The duplicate RPD result for sample BS-U4-M26A-R3 is outside control limits. The 

laboratory control sample showed acceptable results indicating that the analysis was in 

control. The duplicate result is attiibuted to sample heterogeneity. 

Where: 

C 

c com 

Vco m 

W 
7 

QC DATA ASSOCIATION SUMMARY 

H9L210404 

Sample Preparation, and Analysis Control Numbers 

SAMPLE# 

001 

MATRIX 

WASTE 

WASTE 

WASTE 

ANALYTICAL 

METHOD 

ASTM D482-00a 

KNOX WC-0016 

ASTM D240-02 

LEACH 

BATCH # 

PREP 

BATCH # 

0011208 

0011044 

0012048 

MS RUN# 

002 

003 

004 

005 

WASTE ASTM D482-0 0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 . 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

'0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011108 

0011022 

0012019 

006 

007 

008 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02. 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE • ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

009 WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

010 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

011 SOLID ASTM D482-O0a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

(Continued on next page) 

VES019155 
8 

QC DATA ASSOCIATION SUMMARY 

H9L210404 

Sample Preparation and Analysis Control Numbers 

SAMPLE# 

012 

013 

MATRIX 

SOLID 

SOLID 

SOLID 

SOLID 

SOLID 

SOLID 

ANALYTICAL 

METHOD 

ASTM D482-O0a 

KNOX WC-0016 

ASTM D5865-00 

ASTM D482-O0a 

KNOX WC-0016 

ASTM D5865-00 

LEACH 

BATCH # 

PREP 

BATCH tt 

0005274 

0007036 

0013028 

0005274 

0007036 

0013028 

MS K0N# 

0005142 

0007016 

0013013 

014 

015 

016 

017 

SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

SOLID ASTM D4 82-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

WASTE ASTM D4 82-00a 

WASTE KNOX WC-0016 

WASTE ASTM D24 0-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0005274 

0007036 

0013028 

0005274 

0007036 

0013028 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011022 

018 WASTE ASTM D4 82-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

019 

020 

021 

WASTE ASTM D4 82-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-0 0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011208 

0011044 

0012048 

0011108 

0012019 

022 WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

(Continued on next page) 

VES019156 
9 

QC DATA ASSOCIATION SUMMARY 

H9L210404 

Sample Preparation and Analysis Control Numbers 

SAMPLE# MATRIX 

ANALYTICAL 

METHOD 

LEACH 

BATCH # 

PREP 

BATCH # MS RUN# 

023 WASTE ASTM D482-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

024 WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

0011208 

0011044 

0012048 

025 SOLID ASTM D482-O0a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

026 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

027 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

02 8 SOLID ASTM D482-00a 

SOLID KNOX WC-001S 

SOLID ASTM D5865-0.0 

0005274 

0007036 

0013028 

029 SOLID ASTM D482-O0a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

0005142 

0013013 

030 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

0005274 

0007036 

0013028 

0007017 

VES019157 
1 0 

Sample Data Summary 

i 

VES019158 
11 

AECOM, Inc 

Client Sample ID: HBTO-tr4-M23A-Rl 

General Chemistry 

Lot-Sample #...: H9L210404-001 Work Order #...: LRE33 

Date Sarcrpied. ..: 12/16/09 Date Received..: 12/19/09 

Matrxx. WASTE 

PARAMETER 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

RESULT RL UNITS 

6700 200 mg/kg 

Dilution Factor: 1 

8680 1800 BTU/lb 

Dilution Factor; 1 

6440 244 mg/kg 

Dilution Factor: 1.22 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KHOX WC-0016 

MDL : 73 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/15/10 0011044 

I 

VES019159 
12 

Lot-Sample #.. 

Date Sampled.. 

PARAMETER 

AECOM, ID.G 

Client Sample ID: HBTU-n4-M23A.-R2 

General Chemistry 

H9L210404-002 Work Order #...-. LRE34 Matrxx. WASTE 

12/17/09 

RESULT 

Date Received..: 12/19/09 

RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

3730 200 mg/kg 

Dilution Factor: 1 

8590 1800 BTU/lb 

Dilution Factor: 1 

2540 258 mg/kg 

Dilution Factor; 1.29 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 77 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/15/10 0011044 

VES019160 
1 3 

AECOM, Inc 

Client Sample ID: HBTU-U4-M23A-R3 

General Chemistry 

tot-Sample #...: H9L210404-003 Work Order #...; LRE35 

Da.te Sampled. .'.: 12/18/09 Date Received..: 12/19/09 

Matrix. WASTE 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

3080 200 nig/kg 

Dilution Factor: 1 

8510 1800 BTU/Ub 

Dilution Factor: 1 

2340 318 rrtg/kg 

Dilution Factor: 1.59 

_ METHOD ' 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 95 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/15/10 0011044 

I 

VES019161 
14 

AECOM, Inc 

Client Sample ID: LBTO-TJ4-M23 A-Rl 

General Cnemistry 

Lot-Sainple #. . . : H9L210404-004 Work Order #... : LRE36 Matrix : WASTE 

Date Sampled...: 12/15/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2560 200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c 226 B 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 1280 214 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.07 MDL : 64 

NOTE (S ) : 

RL Repotting Limit 

B Estimated result. Result is less than RL. 

I 

VES019162 
15 

AECOM, Inc 

Client Sample ID: _TU~U4-M23A-R2 

General Chemistry 

Lot-Sanrple #-. . : H9L210404-005 Work Order #... : LRE37 Matrix : WASTE 

Date Sampled. .. : 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2730 200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL •. : 51 

Gross Calorifi c 154 B 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor; 1 MDL : 130 

Total Chlorine 1370 216 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.08 MDL : 65 

NOTE(S) : 

RL Reporting Limil 

B Estimated result. Result is less than RL. 

I 

VES019163 
1 6 

AECOM, Inc 

Client Sample ID: LBTtT-Cf4-M23A-R3 

General Chemistry 

H9L210404-006 Work Order #...: LRE38 Matrix : WASTE 

12/18/09 Date Received..: 12/19/09 

Lot-Sample #...: 

Date Sampled...: 

PARAMETER ' RESULT EL UNITS 

Ash Content 3350 200 mg/kg 

Dilution Factor: 1 

PREPARATION- PREP 

_ METHOD ' ANALYSIS DATE BATCH # 

ASTM D482-00a 01/11-01/13/10 0011208 

MDL. : 51 

Gross Calorific 246 B 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 1670 216 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.08 MDL : 65 

NOTB (S) : 

RL Reporting limit 

B Estimated result. Result is less than RL. 

I 

VES019164 
1 7 

AECOM, Inc 

Client Sample ID: SF-U4-M23A-R1 

General Chemistry 

Lot-Saiople #...: H9L210404-007 Work Order : LRE4C 

Date Sampled...: 12/1S/09 Date Received..: 12/19/09 

Matrix : WASTE 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorific 

Value 

Total Chlorine 

1600 200 mg/kg 

Dilution Factor: 1 

4 *. 

9390 1800 BTU/lb 

Dilution Factor: 1 

1240 252 mg/kg 

Dilution Factor: 1.26 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0015 

MDL : 76 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/15/10 0011044 

VES019165 
18 

AECOM, _ c 

Client Sample ID: SF-U4-M23A-R2 

General Chemistry 

Lot-Sar_3>le #. . .: H9L210404-008 Work Order #... : LRE4D Matrix : WASTE 

Date Sampled.: 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2890 200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL. : 51 

Gross Calorifi c 9910 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

. Dilution Factor: 1 MDL, : 130 

Total Chlorine 2220 266 mg/kg KNOX WC-0016 01/11-01/15/10 0011D44 

Dilution Factor: 1.33 MDL : 80 

VES019166 
19 

AECOM, Inc 

Client Sample ID: SF-U4-M23A-R3 

General Chemistry 

Lot-Sample #... : H9L210404-009 Work Order #... : LRE4F Matrix : WASTE 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 1920 200 mg/kg ASTM D482-00a 0l/ll-0l/l3/10 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c 9770 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 1440 258 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.29 MDL : 77 

VES019167 
20 

AECOM, _C 

Client Sample ID: CS-U4-M23A.-R1 

General Chemistry 

Lot-Sample*...: H9L210404-010 Work Order : LRE4G Matrix : SOLID 

Date Sampled...: 12/16/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESOLT RL ONITS METHOD ANALYSIS DATE BATCH # 

Ash Content 699000 200 mg/kg ASTM D482-O0a 01/05-01/07/10 0005274 

Dilution Factor: • 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D5865-00- 01/13/10 • 0013028 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 224 204 rag/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1.02 MDL : 61 

I 

VES019168 
21 

AECOM, UlC 

Client Sample ID: CS-U4-M23A-R2 

General Chemistry 

tot-Sample #... : H9L210404-011 Work Order #... : LRE4H Matrix : SOLID 

Date Sampled—: 12/17/09 Date Received..: 12/19/09 

PARAMETER RESULT RL UNITS METHOD 

Ash Content 746000 200 mg/kg 

Dilution Factor: 1 

1800 BTU/lb 

Dilution Factor: 1 

2 08 mg/kg 

Dilution Factor: 1.04 

ASTM D482-00a 

MDL : El 

ASTM D5865-00 

MDL : 13 0 

KNOX WC-0016 

MDL : 62 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/OS-01/07/10 0005274 

01/13/10 0013028 

01/07-01/14/10 0007036 

Gross Calorifi c ND 

Value 

Total Chlorine ND 

VES019169 
22 

AECOM, Inc 

Client Sample ID: CS-U4-M23A-R3 

General ChemistryLot- Sample #... : H9L210404-012 Work Order #... : LRE4J Matrix : SOLID 

Date Sampled. ..: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 737000 200 mg/kg• ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL : 51 

Gross Calorific ND 1800 BTU/lb ASTM D58S5-00 01/13/10 0013028 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 146 B 200 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1 MDL : SO 

NOTE (S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. 

VES019170 
23 

AECOM, Xnc 

Client Sample ID: BS-U4-M23A-R1 

General Qiemistry 

Lot-Sample #...: H9L210404-013 Work Order #...: LRE4K Matrix : SOLID 

Date Sampled : 12/16/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DA.TE BATCH # 

Ash Content 725000 200 mg/kg ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c 215 B 1800 BTU/lb ASTM D5865-00 01/13/10 0013028 

Value 

Dilution Factor: 1 MDL : 13 0 

Total Chlorine 650 208 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1.04 MDL : 62 

NOTE(S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. • 

VES019171 
24 

AECOM, Inc 

Client Sample TD: BS-U4-M23A-R2 

General Chemistry 

Lot-Sample : H9L210404-014 Work Order #...: LRE4L Matrix : SOLID 

Date Sampled. ..: 12/17-/09 Date Received. .: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 776000 200 mg/kg ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL : 51 

Gross Calorific 198 B 1800 BTU/lb ASTM D58S5-00 01/13/10 0013028 

Value 

.Dilution Factor: 1 MDL : 130 

Total Chlorine 517 200 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1 MDL : 60 

HOTE(S) : : 

RL Reporting Limit 

B Estimaied result. ResuU is less than RL. 

VES019172 
2 5 

AECOM, Inc 

Client Saniple ID: BS-U4-M23A-R3 

General Chemistry 

Lot-Sample #...: H9L210404-015 Work Order #...: LRE4M Matrix : SOLID 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 794000 200 mg/kg ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL : 51 

Gross Calorific ND 1800 BTU/lb ASTM D5865-00 01/13/10 • 0013028 

Value 

Dilution Factor: 1 MDL. . . : 130 

Total C-ilorine 229 202 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1.01 MDL : €1 

VES019173 
26 

AECOM, Inc 

Client Sample ID: HBT0-U4-M26A-R1 

General Chemistry 

Lot-Sample #... 

Date Sampled... 

PARAMETER 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

H9L210404-016 Work Order #.. 

12/16/09 Date Received. 

RESULT RL UNITS 

13200 200 mg/kg 

Dilution Factor: 1 

9000 1800 BTU/lb 

Dilution Factor: 1 

12500 1190 mg/kg 

Dilution Factor: 5.94 

LRE4N 

12/19/09 

METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

ASTM. D482-O0a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 360 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/15/10 0011044 

I 

VES019174 
27 

AECOM, Inc 

Client Sample ID: HBTU-U4-M2SA-R2 

General Cnemistry 

Lot-Sample #...: H9L210404-017 Work Order #...: LRE4P 

Date Sampled...: 12/17/09 Date Received..: 12/19/09 

Matrix : WASTE 

PARAMETER RESULT RL UNITS 

Ash. Content 

Gross Calorific 

Value 

Total Chlorine 

3170 200 mg/kg 

Dilution Factor: 1 

8640 1800 BTU/lb 

Dilution Factor: 1 

2470 270 mg/kg 

Dilution Factor: 1.35 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 13 0 

KNOX WC-0016 

MDL. . . '. : 81 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/15/10 0011044 

VES019175 
28 

AECOM, Inc 

Client Sample ID: HBTU-U4-M26A-R3 

General Chemistry 

Lot-Sample*...: H9L210404-018 Work Order #. . . : LRE4Q Matrix : WASTE 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 3290 200 mg/kg ASTM D482-O0a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorific 8660 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 2310 240 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.2 MDL : 72 

VES019176 
29 

AECOM, Inc 

Client Sample ID: LBTU-U4-M26A-R1 

General Chemistry 

Lot-Sanrple #...: H9L210404-019 Work Order : LRE4R Matrix : WASTE 

Date Sampled...: 12/15/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD • ANALYSIS DATE BATCH # 

Ash Content 2660 200 mg/kg ASTM D482-00a 01/11-01/13/1O 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c 258 B 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 1250 212 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.06 MDL : 64 

NOTE(S) : ' 

RL Reporting Limit 

B Estimattd result. Result is less than RL. 

I 

VES019177 
30 

AECOM, Inc 

Client Sample ID: LBTU-U4-M26A-R2 

General Chemistry 

Lot - Sample #... : H9L210404-020 Work Order : LRE4T Matrix : WASTE 

Date Sampled...: 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2770 200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorific 251 B 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor; 1 MDL : 130 

Total Chlorine 1310 210 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.05 MDL .....: S3 

NOTE (S) : 

RL Reporting Limit 

B Estimaied result. Result is less than RL. 

VES019178 
31 

AECOM, Inc 

Client Sample ID: LBTU-U4-M26A-R3 

General Chemistry 

Lot-Sample #... : H9L210404-021 Work Order : LEE4V Matrix : WASTE 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 4150 200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorific 189 B 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL :; 13 0 

Total Chlorine 1620 208 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor; 1.04 ' ~MDL : 62 

NOTE(S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. 

VES019179 
32 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

Ash Content 

Gross Calorifi c 

Value 

Total Oxlorine 

AECOM, Inc 

Client Sample ID: SF-U4-M26A-R1 

General Chemistry 

H9L210404-022 

12/15/09 

RESULT 

Work Order #...;• LRE4W 

Date Received..: 12/19/09 

Matrxx. WASTE 

RL UNITS 

1480 200 mg/kg 

Dilution Factor: 1 

10100 1800 BTU/lb 

Dilution Factor: 1 

1120 260 mg/kg 

Dilution Factor: 1.3 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 7B 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/11-01/13/10 0011208 

01/12/10 0012048 

01/11-01/19/10 0011044 

VES019180 
3 3 

AECOM, Inc 

Client Sample ID: SF-U4-M26A-R2 

General Chemistry 

Lot-Saunple #.. .: H9L210404-023 Work Order #...: LRE4X Matrix : WASTE 

Date Sampled...: 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL; UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 4570 200 mg/kg ASTM D482-O0a 01/11-01/13/10 0011208 

Dilution Factor: 1 MDL : 51 

Gross Calorific 9430 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 3510 252 mg/kg KNOX WC-0016 01/11-01/19/10 0011044 

Dilution Factor: 1.26 MDL : 76 

VES019181 
34 

AECOM, Inc 

Client Sample 10: SF-TJ4-M26A-R3 

General Chemistry 

Lot-Sample #. .. : H9L210404-024 Work Order #... : LRE40 Matrix : WASTE 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH g 

Ash Content 1820 200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 HDL : 51 

Gross Calorific 9820 1800 BTU/lb ASTM D240-02 01/12/10 0012048 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 1400 252 mg/kg KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.26 MDL : 76 

VES019182 
35 

Lot-Sample #. 

Date Sampled. . 

PARAMETER 

AECOM, Inc 

Client Sample ID: CS-U4-M26A-R1 

General Chemistry 

B9L210404-025 Work Order #...: LRE43 

12/16/09 Date Received..: 12/19/09 

Matrix. SOLID 

RESULT RL UNITS 

Ash Content 

Gross Calorific 

Value 

Total Chlorine 

785000 200 mg/kg 

Dilution Factor: 1 

ND 18 00 BTU/lb 

Dilution Factor: 1 

ND 208 mg/kg 

Dilution Factor: 1.04 

_ METHOD 

ASTM D482-00a 

HDL : 51 

ASTM D5865-00 

MDL : 130 

KNOX WC-0015 

MDL : 62 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/05-01/07/10 0005274 

01/13/10 0013028 

01/07-01/14/10 0007036 

VES019183 
36 

AECOM, Inc 

Client Sample ID: CS-U4-M26A-R2 

General C_ttemistry 

Lot-Sample #...: H9L210404-026 Work Order #...: LRE44 Matrix : SOLID 

Date Sampled...: 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 857000 200 mg/kg ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL : 51 

Gross Calorific ND 1800 BTU/lb ASTM D5865-00 01/13/10 0013028 

Value 

Dilution Factor: 1 MDL : 13 0 

Total Chlorine ND 212 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1.06 MDL : 64 

VES019184 
37 

AECOM, Inc 

Client Sample ID: CS-U4-M26A-R3 

General Chemistry 

Lot-Sample #...: H9L210404-027 Work Order #... : LRE45 Matrix . : SOLID 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 744000 200 mg/kg ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL. : 51 

Gross Calorific ND 1800 BTU/lb ASTM D5865-00 01/13/10 0013028 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine ND 208 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1.04 MDL : 62 

VES019185 
38 

AECOM, Inc 

Client Sample ID: BS-U4-M26A-R1 

General Chemistry 

LK3t-Santple #...: H9L210404-028 Work Order #... 

Date Sampled...: 12/16/09 Date Received.. 

PARAMETER 

Ash Content 

Gross Calorific 

Value 

Total Chlorine 

RESULT RL UNITS 

808000 200 mg/kg 

Dilution Factor: 1 

200 B 1800 BTU/lb 

Dilution Factor: 1 

433 202 mg/kg 

. Dilution Factor: 1.01 

LRE4S 

12/19/09 

Matrix. SOLID 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM Dsses'-oo 

MDL : 130 

KNOX WC-0016 

MDL : SI 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

01/05-01/07/10 0005274 

01/13/10 0013028 

01/07-01/14/10 0007036 

NOTE(S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. 

VES019186 
3 9 

AECOM, Inc 

Client Sample ID: BS-U4-M26A-R2 

General Cnemistry 

Lot-Sample #...: H9L210404-D29 Work Order #...:- LRE4 7 • Matrix : SOLID 

Date Sampled... -. 12/17/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 801000 200 mg/kg ASTM D482-00a 01/05-01/07/10 0005274 

Dilutio n Factor: 1 MDL : 51 

Gross Calorific 196 B 1800 BTU/lb ASTM D5865-00 01/13/10 0013028 

Value 

Dilutio n Factor: 1 MDL : 130 

Total Chlorine 976 216 mg/kg KHOX WC-0016 01/07-01/14/10 0007036 

Dilutio n Factor: 1.08 MDL : 65 

NOTE(S) : 

RL Reporting Limit 

B Estimated result. Result is less than RL. 

VES019187 
40 

AECOM, Inc 

Client Sample ID: BS-U4-M26A-R3 

General Chemistry 

Lot-Saum?le #. ..: H9L210404-030 Work Order : LRE48 Matrix : SOLID 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 797000 200 mg/kg ASTM D482-O0a 01/05-01/07/10 0005274 

Dilution Factor: 1 MDL : SI 

Gross Calorific ND 1800 BTU/lb ASTM D5865-00 01/13/10 0013028 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine 610 200 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1 MDL : 60 

VES019188 
41 

Client Lot #. : H9L210404 

METHOD BLANK REPORT 

General Chemistry 

Matrix. SOLID 

PARAMETER 

Ash Content 

RESULT 

REPORTING 

LIMIT UNITS METHOD 

PREPARATIONANALYSIS DATE 

Work Order 

ND • 200 

Dilutio n Factor: 1 

PREP 

BATCH # 

If: LRVT31AA MB Lot-Sample #: HOA050000-274 

mg/kg ASTM D4S2-00a 01/05-01/07/10 0005274 

Total Chlorine Work Order #: LRW761AA MB. Lot-Sample #: HOA070000-036 

ND 200 mg/kg KNOX WC-0016 01/07-01/14/10 0007036 

Dilutio n Factor: 1 

NOTE(S) : 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES019189 
42 

Client Lat H9L210404 

METHOD BLANK REPORT 

General ChemistryMatrix : WASTE 

PARAMETER RESULT 

Ash Content 

ND 

REPORTING 

LIMIT UNITS METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Work Order #: LR2KQ1AA MB Lot-Sample #: H0A110000-208 

200 mg/kg ASTM D482-00a 01/11-01/13/10 0011208 

Dilutio n Factor: 1 

Total Chlorine Work Order #: LR2CJ1AA MB Lot-Sample #: HOA110000-044 

ND 200 mg/kg KNOX WC-001S 01/11-01/15/10 0011044 

Dilutio n Factor: 1 

NOTE(S) : 

Calculations are performed before rounding to avoid round-ofT errors tn calculated results. 

VES019190 
43 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample #...: H9L210404 Matrix : SOLID 

PARAMETER 

Ash Content 

PERCENT 

RECOVERY 

101 

101 

RECOVERY 

LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE PREP 

BATCH 

W0#:LRVT31AC-LCS/LRVT31AD-LCSD LCS Lot-Sample#: HOA050000-274 

(90 - 110) ASTM D482-00a 01/05-01/07/10 0005274 

(90 - 110) 0.12 (0-10) ASTM D482-00a 01/05-01/07/10 0005274 

Dilutio n Factor: 1 

Gross Calorific 

Value 

100 

100 

W0#:LR4DC1AA-LCS/LR4DC1AC-LCSD LCS Lot-Samples: HOA130000-028 

(98 - 102) 

(98 - 102) 0.05 (0-2.0) 

Dilutio n Factor: 1 

ASTM D5865-00 

ASTM D5865-00 

01/13/10 

01/13/10 

0013028 

0013028 

NOTE(S) : 

Calculaiions are performed before rounding io avoid round-off errors in calculated results. 

VES019191 
44 

LABORATORY COHTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample #...: H9L210404 Matrix : SOLID 

SPIKE MEASURED 

PARAMETER AMOUNT AMOUNT UNITS 

Ash Content 

4000 

4000 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

WO#:LRVT31AC-LCS/LRVT31AD-LCSD LCS Lot-Sample*: HOA050000-274 

4050 mg/kg 101 ASTM D482-00a 01/05-01/07/10 0005274 

4060 mg/kg 101 0.12 ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 

Gross Calorific 

Value 

11400 

11400 

W0#:LR4DC1AA-LCS/LR4DC1AC-LCSD LCS Lot-Satnple#: HOA130000-028 

114 00 BTU/lb '10 0 

11400 BTU/lb ' 100 

Dilution Factor: 1 

ASTM D5865-00 

0.06 ASTM D5865-00 

01/13/10 

01/13/10 

0013028 

0013028 

NOTE (S) : 

Calculaiions are performed before rounding io avoid round-off errors in calculated results. 

VES019192 
45 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Client Lot #...: H9L210404 Matrix : SOLID 

PERCENT RECOVERY PREPARATION- PREP 

PARAMETER RECOVERY LIMITS METHOD ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LRW761AC LCS Lot-Sample#: HOA070000-036 

101 (80 - 120) KNOX WC-0015 01/07-01/14/10 0007036 

Dilutio n Factor: 5 

NOTE(S) : . 

Calculations are performed before rounding io avoid round-off errors in calculated results. 

i 

VES019193 
46 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Client Lot #...: H9L210404 Matrix : SOLID 

SPIKE MEASURED PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMOUNT UNITS RECVRY METHOD ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LRW7S1AC LCS Lot-Sample#: HOA070000-036 

10000 10100 mg/kg 101 KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 5 

NOTE(S) : ' 

Calcufariom are perfomied before rounding to avoid round-off errors in calculated results. 

VES019194 
47 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample #., H9L210404 Matrix : WASTE 

PARAMETER 

Ash Content 

PERCENT 

RECOVERY 

98 

101 

RECOVERY 

LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

W0#:LR2KQ1AC-LCS/LR2KQ1AD-LCSD LCS Lot-Sample#: HOA110000-208 

(90 - 110) ASTM D482-00a 01/11-01/13/10 0011208 

(90 - 110) 2.4 (0-10) ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 

Gross Calorific 

Value 

100 

100 

WO#:LR2981AA-LCS/LR2981AC-LCSD LCS' Lot-Sample#: H0A120OOO-04 

(98 102) 

(98 - 102) 0.02 (0-2.0 

Dilution Factor: 1 

ASTM D240-02 

ASTM D240-02 

01/12/10 

01/12/10 

0012048 

0012048 

NOTE(S): 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES019195 
48 

LABORATORY COHTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample #...: H9L210404 Matrix : WASTE 

PARAMETER 

Ash Content 

SPIKE 

AMOUNT 

4000 

4000 

MEASURED 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

W0#:LR2KQ1AC-LCS/LR2KQ1AD-LCSD LCS Lot-Sample#: HOA110000-208 

3930 mg/kg 98 ASTM D482-00a 01/11-01/13/10 0011208 

4030 mg/kg 101 2.4 ASTM D482-00a 01/11-01/13/10 0011208 

Dilutio n Factor: 1 

Gross Calorific 

Value 

20600 

20GOO 

WO#:LR2981AA-LCS/LR2981AC-LCSD LCS Lot-Sample#: H0A120000-048 

20500 

20500 

BTU/lb 100 

BTU/lb 100 

Dilutio n Factor: 1 

ASTM D240-02 

0.02 ASTM D240-02 

01/12/10 

01/12/10 

0012048 

0012048 

NOTE(S) : 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES019196 
49 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Client Lot #...: H9L210404 Matrix : WASTE 

PERCENT RECOVERY PREPARATION- PREP 

PARAMETER RECOVERY LIMITS METHOD ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LR2CJ1AC LCS Lot-Sample#: HOA110000-044 

104 (80 - 120) KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 5 

NOTE(S) : 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES019197 
50 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Client Lot #. . . : H9L210404 Matrix : WASTE 

SPIKE MEASURED PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMOUNT UNITS RECVRY METHOD ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LR2CJ1AC LCS Lot-Sample#: HOA110000-044 

10000 10400 mg/kg 104 KNOX WC-0016 Ol/ll-Ol/15/lO 0011044 

Dilutio n Factor: 5 

NOTE(S) : 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES019198 
51 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

Client Lot #... 

Date Sampled... 

: H9L210404 

: 12/18/09 

General Chemistry 

Date Received..: 12/19/09 

Matrix : WASTE 

PARAMETER 

Total Chlorine 

107 

106 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE PREP 

BATCH # 

WO#: LRE351AG-MS/LRE351AH-MSD MS Lot-Sample #: H9L210404-003 

(80 - 120) KNOX WC-0016 01/11-01/15/10 0011044 

(80 - 120) 2.5 (0-10) KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factori 8.3 

NOTE(S): 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES019199 
5 2 

MATRIX SPIKE SAMPLE DATA REPORT 

General Chemistry 

Client Lot #...: H9L210404 Matrix : WASTE 

Date Sampled : 12/18/09 Date Received..: 12/19/09 

SAMPLE SPIKE MEASRD PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMT AMOUNT UNITS RECVRY RPD METHOD ANALYSIS DATE BATCH # 

Total Chlorine WO#: LRE351AG-MS/LRE351AH-MSD MS Lot-Sample #: H9L210404-003 

2340 16S00 20100 mg/kg 107 KNOX WC-001S 01/11-01/15/10 0011044 

2340 16200 19600 mg/kg 106 2.5 KNOX WC-0016 0l/ll-0l/l5/l 0 0011044 

Dilution Factor: 8. 3 

NOTE(S): 

Calculations are performed before rounding to avoid round-off enors in calculated results. 

i 

VES019200 
53 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Chemistry 

Client Lot #...: H9L210404 Matrix : SOLID 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

PERCENT RECOVERY RPD PREPARATION- PREP 

PARAMETER RECOVERY LIMITS RPD LIMITS METHOD ANALYSIS DATE BATCH # 

Total Chlorine WO#: LRE4J1AG-MS/LRE4J1AH-MSD MS Lot-Sample #: H9L210404-012 

97 (80 - 120) KNOX WC-0016 01/07-01/14/10 0007036 

100 (80 - 120) 3.4 (0-10) KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 4.96 

NOTE(S) : 

Calculations are performed before roundinc to avoid round-off errors in calculated results. 

1 

VES019201 
54 

MATRIX SPIKE SAMPLE DATA REPORT 

General Cnemistry 

Client Lot #.., 

Date Sampled.-. 

H9L210404 

12/18/09 

Matrix : SOLID 

Date Received. 12/19/09 

' SAMPLE SPIKE 

PARAMETER AMOUNT AMT 

Total Chlorine ' 

146 9920 

146 10000 

MEASRD 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

WO#: LRE4J1AG-MS/LRE4J1AH-MSD MS Lot-Sample #: H9L210404-012 

9820 mg/kg 97 KNOX WC-0016 01/07-01/14/10 0007036 

10200 mg/kg 100 3.4 KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: i.Se 

NOTE(S) : 

Calculaiions are performed before rounding to avoid round-off errors in calculated results. 

VES019202 
55 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Client Lot H9L210404 Work Order #. . . : LRE35-SMP Matrix : WASTE 

LRE35-DUP 

Date Sampled .- 12/18/09 Date Received.. : 12/19/09 

DUPLICATE RPD PREPARATION- PREP 

PARAM RESULT RESULT UNITS RPD LIMIT METHOD ANALYSIS DATE BATCH # 

Gross Calorific SD Lot-Sample #: H9L210404-OO3 

Value 

8510 8620 BTU/lb 1.3 (0-10) ASTM D240-02 01/12/10- 0012048 

Dilution Factor: 1 

Ash Content SD Lot-Sample #: H9L210404-003 

3080 3050 mg/kg 1.1 (0-10) ASTM D482-00a 01/11-01/13/10 0011208 

Dilution Factor: 1 

Total Chlorine SD Lot-Sample #: H9L210404-003 

2340 2350 mg/kg 0.13 (0-10) KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.59 

VES019203 
56 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Client Lot H9L210404 Work Order #...: LRE4J-SMP Matrix : SOLID 

LRE4J-DUP 

Date Sampled...: 12/18/09 Date Received..: 12/19/09 

DUPLICATE RPD PREPARATION- PREP 

PARAM RESULT RESULT UNITS RPD LIMIT METHOD ANALYSIS DATE BATCH # 

Gross Calorific SD Lot-Sample #: H9L210404-012 

Value 

ND ND BTU/lb 0 (0-10) ASTM D5865-00 01/13/10 0013028 

Dilutio n Factor: 1 

Ash Content SD Lot-Sample #: H9L210404-012 

737000 741000 mg/kg 0.5S (0-10) ASTM D482-00a 01/05-01/07/10 0005274 

Dilutio n Factor: 1 

Total Chlorine SD Lot-Sample #: H9L210404-012 

146 B 149 B mg/kg 1.9 (0-10) KNOX WC-0016 01/07-01/14/10 0007036 

Dilutio n Factor: 1 

NOTE(S) : 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES019204 
57 

Client Lot #...: H9L210404 

Date Sampled...: 12/17/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LRE4P-SMP 

LRE4P-DUP 

Date Received..: 12/19/09 

PARAM RESULT 

Total Chlorine 

2470 

DUPLICATE 

RESULT 

2530 

Matrix. WASTE 

UNITS RPD 

RPD 

LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210404-017 

mg/kg 2.5 (0-10) KNOX WC-0016 01/11-01/15/10 0011044 

Dilution Factor: 1.3S 

VES019205 
58 

Client Lot #. .. : 

Date Sampled...: 

PARAM RESULT 

H9L210404 

12/18/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General ChemistryWork Order #...: LRE4V-SMP 

LRE4V-DUP 

Date Received..: 12/19/09 

Gross Calorific 

Value 

18 9 B 

UNITS 

RPD 

RPD LIMIT 

229 B . BTU/lb 19 

Dilution Factor: l 

METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L210404-021 

(0-10) ASTM D240-02 01/12/10 0012048 

Ash Content 

4150 3 60 0 mg/kg 14 

Dilution Factor: 1 

SD Lot-Sample #: H9L210404-021 

(0-10) ASTM D482-00a 01/11-01/13/10 0011208 

NOTE(S) : 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

B Estimaied result. Result is less than RL. 

VES019206 
59 

Client Lot #...: H9L210404 

Date Sampled...: 12/17/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #... 

Date Received.. 

PARAM RESULT 

DUPLICATE 

RESULT 

Gross Calorific 

Value 

195 B 

Ash Content 

801000 

317 B 

797000 

LRE47-SMP 

LRE47-DUP 

12/19/09 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : SOLID 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

BTU/lb 47 

Dilution Factor: 1 

SD Lot-Sample #: H9L210404-029 

(0-10) ASTM D5B65-00 01/13/10 0013028 

SD Lot-Sample #: H9L210404-029 

mg/kg 0.41 (0-10) ASTM D482-00a 01/05-01/07/10 0005274 

Dilution Factor: 1 

NOTEIS) : 

Calculations are performer) before rouniitng to avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES019207 
60 

Client Lot #...: HSL210404 

Date Sampled...: 12/18/09 

SAMPLE DDPLICATE EVALDATIOH REPORT 

General Chemistry 

Work Order LRE48-SMP 

LRE48-DUP 

Date Received..: 12/19/09 

PARAM RESULT 

Total Chlorine 

610 

Matrix -. SOLID 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

DUPLICATE 

RESULT 

SD Lot-Sample #: H9L210404-030 

.245 mg/kg 85 (0-10) KNOX WC-0016 01/07-01/14/10 0007036 

Dilution Factor: 1 

VES019208