P.1 

RCRA Box 1883 

Prepped by Ollie Stewart 

Document Number: 

71) ll-B-233 

Docket Number: 

A-90-19 

Printed 12/3/200810:42:14 AM Sheet 71 of 171 
P.2 

* i A-90-19 

ll-B-233 

MEMORANDU M 

TO: Process Vents Docket A-90-19 

FROM: Wanda Floyd 

DATE: January 1992 

SUBJECT: HON NESHAP: Industry Characteristics/ Ethylene Glycol Monoethyl 

Ether Acetate 

Attached is a product-process summary (PPS) for the production of Ethylene Dimethyl 

Ether via hydrogenation of ethylene glycol monomethyl ether and acetaldehyde. This 

PPS was developed as part of the Industrial Profile project in support of the Hazardous 

Organic NESHAP (HON) regulatory effort. Information in this PPS is used as a basis 

for emissions and cost impact estimates for the HON program. 

he Corresponding Quality Assurance 

Y'Y>.. X 

A-90-19 

ll-B-252 
P.3 

Preparer: 

Date: 7/9/9 J ~ 

Reviewer: 

ADMINISTRATIVE NOTES 

Prodact-Precm Cod* Hi \S°. ^ 

Hours spentton this PPS /«fl 

P-P Name ^JJMO, J*<^C\ yMfH^ALdL etkur cuc&i-ede, in*. e.sttrt'Cic+hirhsr ui> 

Incomplete Items (parts of " 

form you cannot complete) 

nine # and description) Pate Cleared Initials 

l,/-,.7^7^flc./p^ j lhf

ef0 ty 

1.0 ~(£*J~u<er) 

1*0 - (G-f-c. 0-f f>n>Ju.c€rs) .'"*"* " 

f 6 - (7>r*c-t4*T, Jiscrtpf-in AJ^U**£-J ) 

S.o - (.TYore^s £lrur AIAJI . ) 

Chemicals missino CAS numbers "hrv»iv iSoprBpi^ A-ceby/e ^cn'p^r ^ , 

Plant with Citv but no County (plant name, dty , state) 

' SOL, pUfcfe I'lS^^l %X — 
P.4 

Preparer: / JScJoJU^ 

Date: 

Reviewer: 

Chemical Name 

AltemattVi Cl^iwl Raaw 

CAS I lilt51 

Karen 

CHEMICAL SPECIFIC INFORMATION 

1.0 U.S. Production 

PROOUCT-PROCESS SUMMARY (PPS) 

327 

Ref I 

.. Pg ' ., Ref Year 

1.1 

UZ 

1.3 

M 

l,sr 

l.B 

1.7 

I X I 

ur.e 

1.7:3 

(Indicate the same reference Information for any answers below from a 

different reference) 

IM^&jrfmq&m {cTrclft out) millions of ko or millions of paeons 

A * Ak. 

** ^f^ 

*u <U*-

hu. <M\, 

i/Ka or i/oallon 

1.8 Comments 
P.5 

2.0 Chealcal End-Use Ref # , Pg # , Ref Year 

Usfi . Percent 
3.0 U.S. Producers Ref # _1__ , Pg # ., Ref Year WO 

millions of Kg ut will Ions of gallons ^ 4<^~ 

3.2 Naae, Location, and Capacity 

Process Used 

(use P-P I) !Its fro A»=k~ 

0 cot J ^4j^l Vdroclp^irCeJl Beuuerfd, ffya^ 

P^PjL (tes<+*»4*() *-e 4eM~^ 

\f 

Total Capacity *o JgJ-^, 
P.7 

i^r,^*1 ^ 'zZk>^ 

PRODUCJ-PROCESS SPECIFIC INFORMATION 

4.0 Potential Product-Processes (P-P) Ref # IO Pg I /4^ 

Commercially % Nat'l 

. Mams Viable (y/n) Capacity 

P-P 3 

P-P 4 

P-P 5 

P-P 6 

4.1 Documentation of P-Ps Excluded 

P-P not 

Commercially Viable Reason? . 

C 2 T Process described 

ty^SI^—^jrujAA. &*~r*4r 
P.8 

Air Oxidation Reaction 

Oxidation Reaction 

Alkylation Reaction 

CarbonylatIon Reaction 

Halogenation Reaction 

Condensation Reaction 

Dehydrogenation Reaction 

Dehydrohalogenation React1on 

Esterification React 1b7T*^ 

Hydrogenation Reaction 

Hydrohalogenation Reaction 

Hydroformylation Reaction 

Hydrolysis Reaction 

Nitration Reaction 

OxyacetylatIon Reaction 

Oxyhalogenatlon Reaction 

Sulfonation Reaction 

Catalytic Reformation 

Hydrodlmerizatlon Reaction 

Ref # 10 Pg I K S 

Generic Reaction 

4.4 Explain how you selected the reaction type In Un e 4.3. 

%Jf. descnpfin^ of. Oc^ \*u)*^4u^ *~Pr**^ *"» £•+ 

de*f. of e^ferrf\cJtirh r%^-k^pn.. 
P.9 

0.,cnpt1.n Sff*"_i£4i_,P

t*-^^) 4.5 lArltten 

In the 7«ft aargln, Indicate references and page numbers throughout written 

description. 

TW {u*- OM arV*opS of i^rrv*F»Jiax£ efW* Art f^rCJrtA U/^L 

Crxr-rcri^ltc^ UJJ* i esp/ fi^ceifrcr ^cu>{. IA*VKJ y>rAm\< -vS CAhdt^^-, 

f Tins fc«H&f d«S«-ri'pfiirK i* **l Ouuvu\*lrh . . ,) 

IVY*-

l^e^S - At- Is^rrpyf o-c*.*^ fy iShLf&c trf 'iop^afo^,/ ^/rXce^hc tee/ 

r**urU*^ HL0 • W prc*Lu.c7tr AS iH £****{-- ^ «*&/ KK U4t~J] 

distill r-jH*h- » 
P.10 

/ ' 

' f*. <i*xL+*jus «Wa -fus* Ifcu^j fencers a// i^p ^ )**4,C 

5.0 Process Flow Diagram (attach at end of package) H*ftg^ 

5.1 Flow Diagram Reference: Ref # , Pg # 

5.2 Comments on Flow Diagram 

gar-fF«wara 

Component Tvoes 

Distillation Columns 

Absorbers (A.0 f-wo-l os £or**uJ) 

Strippers 

Reactors 

Condensers 

Vaporizers 

Others 

Ref # '0; * • P9 * 143} UA / 

^ 

lewWTioni' 
P.11 

6.0 Chealcal Data i ^^^ 

6.1 Balanced Chemical Reactions Ref # »Q Pg # 143 

c i ^ TCA^-.I CotJr 

Jx>-5 / 

6.2 Chemical Tree Ref &S.'. 
P.12 

Ka 

6.4 Stolchloaetry p,ef # t pg # 

Show calculations and assumptions and then summarize 1n table on next 

<

 6*62 A. 

r*V* Co. to) 

^ A ^ ^4* 7.57 ^ksee^uhJ^yc '^L±±: x t060^_ 

*"<M£ K^ azotic 
P.13 

6.4 Stolchloaetry Conversion Factors 

a) aaaa^ifffyEflryrg^ '*0 

b) 

c) 

d) Conferst 

e) 

for Cd^Product 13 

f) Conversion Factor Comments 
P.14 

6.4.1 Product 

6.4.2 Raw Materialfsl 

#1 tAu^tA^Lr l9A>JLr afac*l yrtvKteHujt ^Ur 

#2 QL^XCJ OL^AJ 

#3 

#4 

#5 

6,4,3, CQ-Products 

#1 

#2 

#3 _ 

#4 

# 5 • 

6.4.4 Bv-Products 

#1 

#2 

#3 

#4 

#5 

d*.o 

$.4,5 Intermediates 

#i 

#2 

miff 

notoS 

64/97 

Q.H 
P.15 

7.0 Process Vent Emission Sources 

, Pg # 

7.3 Comments Ref # ., Pg # 

7.4 \\mumrm^^mmwa V (Y/N) 

H#& ;-fl,"r>-/ 

Ref # ^ 5 . Pg # /^3; ^ /tfS) 

7.5 Comments Ref # ., Pg# 
P.16 

(Y/N) Ref #N5 . Pg tfth^inS) 

7.9 Comments Ref I ., Pg # 
8.2.1 Product 

8.2.2 Co-Products 

P.17 

8.0 Transfer Emission Sources Ref # [0 Pg # ii i 

(Y/N) 

8.3 Comments Ref I ., Pg # 
P.18 

9.0 Storage Emission Sources Ref # (0 Pg # ^43 

971 ;:Ar^

 ;Bl^aiiM71torfld? V (Y/N) 

57? What lf$pgfp*;*r*' stored? 

Storage Service 

Kami ^ill l

 TyPe 

9.2.2 Co-Products 

9.2.3 R^w Materials //0fra5 

tirceM^ A^iA QAi°i1 ro*Ar ^Jr\' 

9.2.4 Intermediates 

9.4 Comments 
P.19 

10.0. Wastewater Eaission Sources 

i. 

10.2 Describe wastewater 

(Y/N) 

Ref # \0\ 5 pg t.m'^mti 

Stream Equipment Component 

Number Producing Wastewater 

#1 

*2 

#3 

Comments on flow 

final A T fv#o»45 d*«c^iprrv vt«f«.s- rt*v^v*U of R.J0 a^ 

<j.'sf.'(( /Crtg^ Col- (tusumtJ) 

2KJ «li*ti'tffo «f Uft4r" 

10.3 Stream Composition 

(provide only 1f readily available) 

Stream 11 

Ref I 

Steam #2 

.. P9 * 

Organics Organics 

HAPs HAPs 

Water 

Other 

Water 

Other 
Stream #3 

Organics . 

HAPs 

Water 

Other 

10.4 Comments Ref f , Pg # 

P.20