### p. 1



# OAR Box 

# 1168
Prepped by Ollie Stewart



# Document

Number: 

# 66 ) lll-B- 1

Docket Number: 

# A-89-1 0

Printed 4/29/2008 11:23:18 AM Sheet 66 of 131

### P. 2



# * I

. 

# RADIA N

MEMORANDU M

DATE : Ma

y18 , 198 9



# TO : Docke t No . A-79-27 , Benzen e Equipment Leak s
FROM : Jennife r Buzun , Radia nCorporatio n ^1>J ** • T"

. 

# A-89-1 0

II-B- 1



# ' j FE B 14199 1 i

EP AAIR1)OCK:"- T

SUBJECT : Update dInformatio nObtaine do nPercen t Leaker s fo r Equipmen t i nBenzen e Servic e

1. 0 INTRODUCTIO N
Th e purpos e o f thi s memorandum i s t o documen t th e informatio nobtaine d

onpercen t leaker s fro m complianc e reports . Thi s informatio nwa s obtaine da s par t o f th e respons e t o th e point s o f severa l commenter s tha t th e EPA' s estimate s o f emission s prepare dfo r th e propose drul e o nequipmen t leak s (5 3 FR28496 , Jul y

28 , 1988 ) wer e overstate db y two order s o f magnitud e o r
more . Th e commenter s cite dreason s why the y thought tha t th e emission s had bee noverestimated , includin g th e point s tha t refiner y dat a hadbee nuse dt o estimat e emission s from chemica l plants , tha t equipmen t lea kemission s had decrease dsinc e 198 4 (the dat e o f calculatio no f th e EPA' s mos t curren t emission s estimate ) becaus e o f increase dregulator y pressure s t o reduc e emission s (OSHA , SIP , an dNESHAP) , an

dtha t th e characteristic s o f th e equipmen t populatio nha dchange dtowar dusin g mor e "leakless " pump s tha n previousl y

estimated . 2. 0 DAT A GATHERING

Mor e curren t percentag e leaker s dat a fo r equipmen t inbenzen e servic e
wer e availabl e from : (1 ) self-monitorin g report s requiredb y th e equipmen t leak s NESHA P an

dsubmitte dt o th e State s b y th e individua l facilitie s regulated , an

d(2 ) a repor t o

nphotochemicall y

reactiv e organi c compound s prepare dfo r th e Californi a Ai r Resource s Boar d(CARB ) whic hcontaine d
percen t leake r value s fo r Californi a refineries . Thes e source s o f dat a ar e discusse dbelow . A numbe r o f State s tha t hav e facilitie s subjec t t o th e benzen e fugitive s NESHA P wer e contacte dregardin g th e availabilit y o f th e Subpart Jself
monitorin g records . Two States , Texa s an dLouisiana , wer e the nselecte d

## P. 3

o •?• fi



# becaus e o f accessibilit y o f record s an

dth e larg e numbe r o f facilitie s subjec t t o th e NESHA P locate dthere . A listin g o f al l facilitie s filin g Subpar t Jmonitorin g report s inTexa s
wa s obtained . Becaus e o f time an dresourc e constraints , a subse t o f thes e facilitie s wa s chosen ; th e selectio nwa s random . Next , th e mos t recen t year' s wort ho f self-monitorin g record s wer e obtaine dfo r a s many facilitie s i nth e subse t a s time woul dallow . Record s fo r th e followin g facilitie s wer e obtained :

o ARCO , Channelview , Texa s
o Cai nChemical , Alvin , Texa s
o Phillip s 66 , Sweeny , Texa s
o Shel l Oil , Dee r Park , Texa s
o Exxo nChemicals , Baytow nOlefins , Baytown , Texa s
o Unio nCarbide , Texa s City , Texa s
o Amoco Chemica l Co. , Chocolat e Bayou , Texa s

o Cai nChemical , Corpu s Christi , Texa s

o Do w Chemical , Freeport , Texa s
o Exxo nCo. , Baytow nRefining , Baytown , Texa s

o Maratho nPetroleum , Texa s City , Texa s
o Petr o Unite dTerminals , Seabrook , Texa s
o Intercontinenta l Terminals , Dee r Park , Texa s
o Sterlin g Chemicals , Texa s City , Texa s
o Texa s Eastma nKodak , Longview , Texa s
o Monsant o Chemicals , Alvin , Texa s (Se e Docke t No . A-79-27 , Ite m IX-J-6) . Almos t al l o f th e dat a obtaine dar e fo r 198 7 an d198 8 an

dar e presume d t o accuratel y

reflec t th e curren t statu s o f equipmen t lea kemissio ncontrol . Becaus e th e equipmen t leak s NESHA P onl y require s report s onpump s an dvalves , an ddoe s no t requir e facilitie s t o differentiat e inthei r report s betwee n ligh t liqui dandga s valves , mos t o f th e dat a availabl e throug hth e self
monitorin g report s wer e fo r pump s an dvalves . Ver y

few facilitie s reporte d

onflanges , compressors , o r othe r piece s o f equipment , an dmos t dat a fo r

## P. 4



# valve s di dno t differentiat e betwee nvalve s inligh t liqui dan dga s service , bu t lumpe dbot htogether . Some o f th e facilitie s provide dpercentag e leaker s number s inthei r reports , som e provide dth e ra

w numbe r o f leaker s an

dthe tota l numbe r o f equipmen t piece s teste dwhic henable dth e calculatio no f percentag e leakers . However , some facilitie s gav e onl y th e numbe r o f leakers ; percentag e leaker s fo r thes e facilitie s coul dno t b e calculate d becaus e thei r initia l report s (file din1984-85) , whic hcontaine dtota l equipmen t counts , coul dno t be obtaine dwithi nth e time availabl e fo r dat a gathering . Self-monitorin greport s fro m Louisian a wer e provide db y Stat e Offic e o f Ai r Qualit y

officials , an

dwer e selecte da t random fro m readil y availabl e file s o f facilitie s require dt o repor t emission s o f hazardou s ai r pollutants . Record s fo r th e followin gplant s wer e obtained :

o Vist a Chemical , Lak e Charle s LA B Plant , Louisian a
o Exxo nCo. , Bato nRoug e Refinery , Louisian a
o Unio nCarbide , Hahnville , Louisian a
o Exxo nChemica l Americas , Bato nRoug e Resi nFinishin gPlant , Louisian a
o Unio nTexa s Petroleum , Geismar , Louisian a
o Chevro nChemical , St . James , Louisian a
o Rubicon , Geismar , Louisian a
o Atla s Processing , Shreveport , Louisian a
o CITG OPetroleum , Lak e Charles , Louisian a
o Exxo nChemica l Americas , Bato nRoug e Chemica l Plant , Louisian a
o Dow Chemical , Plaquemine , Louisian a (Se e Docke t No . A-79-27 , Ite m IX-J-7) . Th e report s fo r Rubicon , Atla s Processing , an

dCITG Ower e no t use dbecaus e they di dno t provid e informatio n b y componen t type . Al l o f th e dat a obtaine dwer e 1987-8 8 data . Monthl y numbe r o f leaker s o r percentag e leaker s value s fo r eac hequipmen t typ e reported , fo r eac hproces s uni t reported , wer e entere dint o a LOTU S spreadshee t fo r al l o f th e Texa s an dLouisian a facilities . Averag e percentag e leake r value s fo r pump s an dvalve s ineac hfacilit y wer e compute db

y th e

__u_U__ l

# spreadshee t program wher e sufficien t dat a wer e availabl e t o mak e suc ha calculatio nmeaningful . Th e spreadshee t dat a an dresult s ar e give nin Appendi xA

o f thi s memorandum . Th e othe r sourc e o f dat a examine dwa s "Assessmen t o f Fugitiv e Emission s
o f PRO C (Photochemicall y Reactiv e Organi c Compounds ) fro m Petroleu

m Refinin g Operations" , prepare dfo r th e Californi a Ai r Resource s Board , Ma y 27 , 198 7 (Docke t No . A-79-27 , Items VIII-I- 1 an d2) . Thi s repor t give s percentag e leaker s fo r Californi a refinery equipmen t i nPRO C servic e (se e Tabl e 2-13 , pag e 2-2 4 o f th e CAR 8 report , show ninAppendi xB o f thi s memorandum) . Althoug hpercentag e leake r informatio nfo r flanges , compressors , an dpressur e relie f valve s wa s availabl e inth e report , onl y th e valv e an

dpum pdat a wer e
usedi norde r t o b e consisten t wit hth e availabl e dat a fro m Texa s an

d Louisiana . Also , separat e percentag e leaker s value s wer e availabl e inth e CAR B repor t fo r ga s an dligh t liqui dvalves . Again , however , inorde r t o compar e th e CAR B value s dat a t o tha t fo r Texa s an dLouisiana , on e combine d valv e percentag e leaker s valu e wa s compute dfo r eac hfacility . Thi s valu e
wa s compute dfo r eac hfacilit y using weighte daverage s o f th e percen t leaker s fo r ligh t liqui dvalve s an dga s valve s weighte daccordin g t o th e numbe r o f valve s o f eac htype . Thes e calculation s ar e show ninAppendi xC o f thi s memorandum . Th e dat a inthi s repor t wer e somewha t olde r tha nth e Texa s an dLouisian a self-monitorin g dat a (1985-198 6 vs . 1987-1988 ; i.e. , 1- 2 year s afte r th e promulgatio no f th e NESHA P vs . 3- 4 years) , an dwer e collecte dusing a variet y
o f differen t detectio ninstruments , calibratio ngases , an dscreenin g distances . T o compar e results , th e repor t author s converte dal l screenin g value s t o a commo nbasis . Th e author s als o use dextrapolatio ncurve s t o fil l indat a bas e gaps . Becaus e o f thes e adjustment s an dth e ag e o f th e data , i t
wa s questione dwhethe r th e CAR B dat a wer e indeedcomparabl e t o tha t fro m Texa s an dLouisiana . Thi s wa s investigate ddurin g analysi s o f th e dat a describe dinSectio n3.0 . Altogether , useabl e dat a o npercentag e leaker s wer e obtaine dfo r 1 6 refinerie s inCalifornia , 1 2 SOCM I (Syntheti c Organi c Chemica l Manufacturin g Industries ) plant s inTexa s an dLouisiana , 2 refinerie s in

J | kJHUl l M** i JI" i -tk

iltt l

## P. 6



# Texa s an dLouisiana , 4 storag e facilitie s inTexas , an d2 combinatio n refiner y an dSOCM I plant s inTexas . Th e facilit y typ e (SOCMI , refinery , storage ) fo r th e Texa s an dLouisian a plant s wa s determine dfro m th e type s o f proces s unit s show

ni nthe self-monitorin g reports . 3. 0 DAT A

ANALYSI S
Befor e developin g estimate s o f percen t leakin g component s fo r th e benzen e equipmen t leak s sourc e category , decision s hadt o be mad e abou t whic h dat a t o us e andabou t whethe r differen t factor s wer e appropriat e fo r differen t type s o f plant s (chemica l versu s refinery) . I norde r t o mak e thes e decisions , two hypothese s abou t th e dat a wer e tested : (1 ) tha t ther e wa s a differenc e inthe percentag e leake r rate s betwee nrefinerie s an dSOCM I plants , an

d(2 ) tha t th e Californi a dat a wer e significantl y differen t fro

m th e Texa s an

dLouisian a data . Th e analyse s don e t o tes t thes e hypothese s ar e describe dbelow . First , th e Californi a refinery , Texa s an dLouisian a refiner y

an dTexa s
an dLouisian a SOCM I population s wer e statisticall y teste dt o determin e whethe r ther e wer e difference s betwee nth e mea npercentag e leaker s fo r valve s
an dpump s a t refinerie s versu s chemica l plants . Becaus e th e dat a bein g teste dwer e percentages , th e dat a wer e normalize dusin g a transformation :

arcsin e (squar e roo t (percen t leaker s divide db y 100)) .

Then , th e thre e group s wer e teste dusin g a three-wa y analyse s o f varianc e on th e transforme dpercentage s o f leakin g valve s an dpercentage s o f leaking pumps . Thi s test , performe dwit hth e SYSTA T compute r program , showe dtha t th e percentag e leakin g valve s wer e significantl y greate r fo r th e Californi a refinerie s tha nfo r th e Texa s an dLouisian a refinerie s an dth e Texa s an

d Louisian a SOCM I plants . However , ther e wer e no significan t difference s betwee nthes e thre e group s fo r the percentag e leakin g pumps . Thes e results , along wit hth e ra

w dat a usedinth e analysi s ar e show ninAppendi xD . I

n ligh t o f concern s abou t the olde r ag e o f th e Californi a dat a an dth e adjustment s fo r differen t lea kdetectio ninstrument s an dextrapolation s fo r

## P. 7



# missin gdat a performe db y CARB , an

dth e finding s o f th e statistica l analysis , i t wa s decide dtha t th e Californi a refiner y dat a wer e to o differen t fro m th e Texa s an dLouisian a data . Th e Californi a dat a wer e omitte dfro m th e calculatio no f averag e emissio nfactor s i nth e res t o f th e analyses . I norde r t o furthe r tes t th e hypothesi s tha t refiner y an dSOCM I plant s hav e differen t percen t leakers , a two-wa y analysi s o f varianc e wa s performe d

onjus t th e Texa s an

dLouisian a refiner y

an dTexa s an

dLouisian a SOCM I groups . Th e result s o f thi s analysi s showe dtha t ther e wa s no significan t differenc e i nthes e two group s fo r th e percentag e leakin g valves , bu t tha t SOCM I plant s hadsignificantl y highe r pum

plea krate s tha ndi drefineries . Thes e result s ar e show ninAppendi xD . Du e t o missin gdata , ther e wer e onl y fou r valv e lea kan

dthre e pum

plea kdat a point s fo r refineries . Becaus e o f th e very smal l refiner y

sampl e siz e an

dth e fac t tha t th e Agenc y i s no t awar e
o f any technologica l reaso nwhy pump s inSOCM I unit s shoul dlea kmor e tha n thos e inrefineries , th e Agenc y feel s tha t n o fir

m conclusio nca nb e drawn fro m thi s dat a se t abou t th e difference s inequipmen t lea krate s betwee n refinerie s an

dSOCM I plants . Therefore , fo r th e purpose s o f calculatin g averag e emission s factor s t o estimat e curren t equipmen t lea kemissions , th e Agenc y considere drefiner y

an dSOCM I dat a together . Afte r havin gdetermine dtha t th e Californi a dat a wer e t o be exclude d fro m furthe r analysi s an

dtha t refiner y

an dSOCM I dat a wer e t o be analyze d together , new

percentag e leaker s fo r valve s an dpump s wer e calculated . A s discusse dabove , becaus e th e Californi a refiner y dat a wer e to o differen t fro m th e Texa s an

dLouisian a dat a an

dma y be les s representativ e o f curren t conditions , thes e dat a wer e omitte dan daverag e percentag e lea krate s fo r valve s an

dpump s wer e compute dbase donth e Texa s an dLouisian a SOCMI , refinery , an

dstorag e facilities . Th e averag e percen t lea krate s compute d

wer e 0.2 7 percen t fo r valves , an d2.2 7 percen t fo r pumps . (Se e Appendi xA. ) Th e range s onthes e lea krate s wer e 0.002 4 t o 1. 3 percen t fo r valves , an d 0.8 4 t o 12. 5 percen t fo r pumps . Becaus e few facilitie s gav e dat a fo r compressor s o r flanges , percentag e leaker s fo r thes e wer e no t calculated . Also , sinc e no facilitie s brok e thei r valv e dat a dow nint o ligh t liqui d

versu s ga s valves , al l valv e type s wer e considere dtogethe r incomputin g on e averag e percen t lea krat e fo r valves .

L_r

-

## P. 8



# APPENDI XA

Texa s an dLouisian a Facilitie s Equipmen t Leak s NESHA P Self-Monitorin gDat a Spreadshee t wit hPercen t Leaker s Calculation sFacilit yName/Locatio n Facili t Typ e

SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCM I SOCH I SOCH I SOCH I SOCH I SOCH I

SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I

Ref

. Ref

. Rel

. Ref

. Ref

. Ref

. Ref

. Ref

. Ref

. Ref

. Ref

. Ref

. SOCH I SOCH I V Uni t

EB S EB S EB S EB S EB S EB S EB S EB S EB S EB S EB S EB S Dat e

Mont h

1 0 1 1 1 2 rea r
B B B 8 B S B B B B B B 8 7 B 7 8 7 8 7 8 7 8 7 Averag e Percen t Lea k H C H C H C N C H C H C H C H C H C H C H C H C O H 0 1 f 0 1 f 0 1 f 0 1 f O H OH 0 1 f OH OH O H O H Averag e Hexls o Hexls o H e d s o Rex[s o Hexls o Hexls a Hetls a Hexls a Hexls o He xI s o Heils o Hexls o SalvE x SalvE x 1 0

1 1 1 2



## t o 1 1 1 2

Percen t

1 0 1 1 1 2 8 8 8 8 8 8 8 8

. 8 8 8 8 8 7 8 7 B 7 8 8 8 8 8 8 8 8 8 8 8 8 8 8 B 8 S B 8 7 8 7 8 7 8 8 8 8 8 8 Lea k 8 8 8 8 6 8 8 8 8 8 8 8 8 7 8 7 8 8 8 8 8 8 

## s a 8 8 8 8 Val ve

s lot. l 1 Lea k

Z Lea k

133 2 133 2 133 2 133 2 133 2 133 2 133 2 133 2 133 2 133 2 133 2 133 2

306 1 306 1 30_ 1 306 1 306 1 306 1 306 1 306 1 306 1 306 1 306 1 306 1

202 2

197 7

68 6 68 6 68 6 68 6 68 6 68 6 68 6 68 6 68 6 68 6 68 6 68 6 64 1 641 6 0.450 4

9 0.675 6 3 0.225 2 5 0.375 3 6 0.450 4 0 0 3 0.225 2 7 0.525 5 3 0.225 2

1 0.075 0 3 0.225 2 0.313 ? 0 0 0 0 2 0.065 3 0 0 0 0 5 0.163 3 1 0.032 6 2 0.065 3 8 0.261 3 0 0 0 0 2 0.065 3

1 0.04. 4

0 0

0.050 2 0 0 0 0 0 0 0 0 1 0.145 7 4 0.5B3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 LL Valve s

lot. l 1 Lea k

Z Lea k To t

263 7 263 7 263 7 263 7 263 7 263 7 263 7 263 7 263 7 263 7 263 7 263 7 185 2 3 185 2 3 185 2 3 1852 3 185 2 3 185 2 3 185 2 3 185 2 3 185 2 3 185 2 3 185 2 3 185 2 3 Ga s Valve s . 1 1 Lea k

I Lea k

A

4 8 4 8 4 8 4 6 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 Pump s lot. l 1 Lea k

Z Lea k

4 B 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8

2 8 2 8 2 B 2 B 2 8 2 8 2 8 2 8 2 8 2 8 2 B 2 8

0 0 2 4.166 6 5 10.41 6 1 2.083 3 1 2.083 3 2 4.166 6 0 0

. 2 4.166 6 3 6.2 5 1 2.083 3

0 0 0 0 3.219 6 2 4.545 4 3 6.818 1 0 0 1 2.272 7 0 0 0 0 3 6.818 1 5 11.36 3 4 9.090 9 1 2.272 7 2 4.545 4 1 2.272 7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2.083 3 0 0 1 0 0 0 0 0 0 0 0 0 0 0 Compressor s lot. l 1 Lea k

Z

6 0 6 0 6 0 6 0 6 0 6 0 6 0 6 0 6 0 6 0 6 0 6 0 Leak

0 0 0 0 0 0 0 0 0 0 0 0 0 Flange s Tot. l 1 Lea k Z Lea k CO M.fit s

Arco Che n ca l Arco Che n ca l Arco Chemica l Arc o Che n ca l Arco Chemica l Arc o Che n ca l Arco Che n ca l Arc o Che n ca l Arco Che n ca l Arc o Chemica l Are a Cheiica l Arc o Chemica l

Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chetica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l Cai n Chemica l
Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Phillip s 66 , Channelvie« , I x

Channelviea , T i Channe l view

. I x Channelvien , T

x Channelviea , T

x Channelviea , T

x Channelviea , T

x Channelviea , T

x Channelviea , T

x Channelviea , T

x Channelviea , T

x Channelviea , T

x

Alvi n Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvin , Alvi n Alvin , Alvi n Alvi n Alvi n Alvin , Alvi n Alvi n
Saeeny, Saeeny , Saeeny, Saeeny , Saeeny , Saeeny , Saeeny , Saeeny , Saeeny , Saeeny , Saeeny, Saeeny , Saeeny , Saeeny , T

x T x T x T t T x T x T x T x T x f x T x T x T x T x T x T x T x T x T x T x T x T x T x T x
T x T x T x T x T x T x T x T x T x T x T x T x I x T x 1299 Liqui d valves , 3 3 Ea s valves

. I Benten e i s al l eithe rI0Z , o r80,90 1

EB S Uni t Shutdoa n

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. Terminals , DeerPark , Intercont

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7 SOCHI LHC

7 SOCHI LHC

7 SOCHI LHC

7 SOCHI LHC

7 SOCHI LHC

7 SOCH I LHC

7 SOCHI LHC

7 SOCH I LHC

7 SOCH I LHC

7 SOCH I LHC

7 SOCHI LHC

6 SOCH I LHC

6 SOCHI LHC

6 SOCHI LHC

6 SOCHI LHC

6 SOCHI LHC

6 SOCH I LHC

6 SOCHI LHC

6 SOCHI LHC

6 SOCH I LHC

6 SOCH I LHC

6 SOCHI LHC

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percont.Facilit y Name/Locatio n Facilit yDate Valve s L L Valve s Ga s Valve s Pump s Compressor s Flange s Typ e Uni t Hont h Vea rTot. l I Lea k Z Lea l Tot. l I Lea k Z Lea k Tot. l I Lea k

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. Terminals , Dee r Intercont

. Terminals , Dee r Park , T Park , T Intercont

. Terminals , Dee rPark , T Intercont

. Terminals , Oeer Intercont

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Maratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texa s Haratho n Petroleum , Texas Haratho n Petroleum , Texas 1 Haratho n Petroleum , Texa s Haratho n Petroleum , Texas 1 Haratho n Petroleum , Texas Haratho n Petroleum , Texa s 1 Haratho n Petroleum , Texas Haratho n Petroleum , Texa s Haratho n Petroleum , Texas Maratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas ( Haratho n Petroleum , Texas I Haratho n Petroleum , Texa s 1 Haratho n Petroleum , Texas Haratho n Petroleum , Texa s I Haratho n Petroleum , Texas Haratho n Petroleum , Texas I Haratho n Petroleum , Texas Haratho n Petroleum , Texa s 1 Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas ( Haratho n Petroleum , Texas Haratho n Petroleum , Texas I Haratho n Petroleum , Texas Haratho n Petroleum , Texa s Haratho n Petroleum , Texa s Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texas Haratho n Petroleum , Texa s Haratho n Petroleum , Texas Haratho n Petroleum , Texas "ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x ity , T x 'ity , T x ity , T x :ity , T x ity , T x :ity , T x :ity , T x .ity , T x :ity , T x .11y , T x :ity , T x City , T x ."ity , T x City , I x City , T i Storag e Storag e Storag e Storag e Storag e Storag e Storag e Storag e Storag e

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5 B 7 6 87 1 68 2 8B 3 8 8 4 B B S 8 8 6 88 'ercen t Lea k 1 0 8 7 I t 87 1 2 87 1 8 8 2 8 B 3 8 8 4 8 7 5 •87 6 8 7 7 87 8 87 9 87 4 B 7 5 8 7 6 87 7 8 7 8 87 9 87 1 0 87 1 1 87 1 2 8 7 1 88 2 8 8 3 88 4 87 5 87 6 8 7 7 8 7 8 87 9 8 7 1 0 B 7 1 1 8 7 1 2 8 7 1 88 2 B B 3 88 4 8 7 5 67 6 87 7 67 6 8 7 9 8 7 3

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## -. T lFacilit ) Facilit yName/Locatio n Typ e

Haratho n Petroleum , T e Haratho n Petroleum , T e Haratho n Petroleum , T e xa s City , la s City , xa s City , Haratho n Petroleum , Texa s City , Haratho n Petroleum , T e Haratho n Petroleum , T e

Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals , Petrounite d Terminals ,
Ster l Ster l Ster l Ster l Ster l Ster l Ster l Ster l Ster l Ster l Ster l xa s City , xa s City , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport , Bayport ,

n g Chems. , Texa s City , T x n g Chems. , Texa s
n g Chems. , Texa s n g Chems. , Texa s n g Chems. , Texa s n g Chems. , Texa s n g Chems. , Texa s n g Chems. , Texa s n g Chems. , Texa s
n g Chems. , Texa s n g Chems. , Texa s Sterlin g Chems. , Texa s

Kodak , LongvieB , T

x Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Koda k Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x

, Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x City , T

x City , T x City , T x City , T x City , T x City , T x City , T x City , I x City , T x City , T x City , T x T xStar

. I xStor

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SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I SOCH I
Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Uni t

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1 1 1 2

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8 7 8 7 8 7 B B 8 8 8 8 Lea k 8 8 8 8 8 8 8 8 8 8 8 8 8 7 B 8 8 8 6 8 8 8 8 8 Lea k 8 8 8 8 8 8 8 8 8 8 8 8 8 7 8 7 8 7 8 8 8 8 8 8 Percen t Lea k

1 0 1 1 1 2

1 0 1 1 1 2 8 7 8 7 8 7 8 7 6 7 8 8 .8 8 8 8 8 8 8 8 8 8 8 8 8 7 B 7 6 7 8 7 8 7 8 8 8 8 Tot. l

6 4 8 4 B 4 8 4 8 4 B 4 8 4 8 4 8 4 8 4 6 4 B 4

250 0 250 0 250 0 250 0 250 0 250 0 250 0 250 0 250 0 250 0 250 0 250 0 Valve s 1 Lea k

0 0 0 0 0 0

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T l h oFacilit y Name/Locatio n Facilit y Typ e Uni t Oat e Valve s

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Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , Kodak , kodak , Kodak , Kodak , Kodak , Kodak , LongvieB , T

x Longviea , T

x Longviea , T

x LangvieB , T

x Longviea , T

x LongvieB , T

x Longviea , T

x Longviea , T

x LongvieB , T

x LongvieB , T

x LongvieB , T

x LongvieB , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x LongvieB , Ti LongvieB , T

x LongvieB , T

x Longviea , T

x LongvieB , T

x LongvieB , T

i Longviea , Ti Longviea , Ti Longviea , Ti Longviea , T

x Longviea , T

x Longviea , T

x Longviea , Ti Longviea , Ti Longviea , Ti Longviea , T

x Longviea , T

x Longviea , I

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , T

x Longviea , Ti Longviea , T

x Longviea , T

x

Honsanto , Chocolat e Bayou , Alvin , T I Hansanto , Chocolat e Bayou , Alvin , T I Honsanto , Chocolat e Bayou , Alvin , T I Honsanto , Chocolat e Bayou , Alvin , I I

Vist a Chemical , Lak e Charle s LAB , La . Vist a Chemical , Lak e Charle s LAB , La . Vist a Chemical , Lat e Charle s LAB , La . Vist a Chemical , Lak e Charle s LAB . La . Vist a Chemical , Lak e Charle s LAB , La . Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f

Stor . Star . SOCH I SOCH I

SOCH I SOCH I SOCH I SOCH I SOCH I HCC3 A

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## Buli l \Averag e Percen t Lea k DisT . Dist . SAB SAB Averag e Percen t Lea k LAB 7 8 8 LAB 8 8 8 LAD9 8 8 LAB 1 0 8 8 LAB 1 1 8 8 94 8 94 8 41 4 41 4 66 1 

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Vist a Vist a Vist a Vist a Vist a Vist a Vist a Vist a

Exxon , E xion , Euan , Exxon , Exxon , E xtan , Euan , Exxon , Exxon , Exxon , Euan , Exian ,

Unio n Unio n Unio n Unio n Unio n Unio n Unio n Unio n Unio n Unio n Unio n Unio n

Exxo n Exxo n Exxo n Exxon E xio n Exia n E xio n Exxo n Exia n Exia n Exxo n Exia n Chemical , Chemical , Chemical , Chemical , Chemical , Chemical , Chemical , Chemical , Lak

e Charle s LAB , L

, Lak e Charle s LAB , L

, Lak e Charle s LAB , L Lak e Charle s LAB , L

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Carbid e Carbid e Carbid e Carbid e Carbid e Carbid e Carbide , Carbid e Carbid e Carbid e Carbid e Carbid e Rouge , La

. Rouge , La

. Rouge , La

. Rouge, La

. Rouge , La

. Rouge , La

. Rouge , La

. Rouge , La

. Rouge , La

. Rouge , La

. Rouge , La

. Rouge , La

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Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant , Taf t Plant ,

Chemic a Chemic a Chemic a Chemic a Chemica ; Chemic a Chemica i Chemica l Chemic a Chemica ! Chemic a Chemic a Bato n Bato n Bato n Bato n Bato n Bato n Bato n Bato n Bato n Bato n Bato n Bato n Roug

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Unio n Texa

s Petrol. , Eeisaar , L a Unio n Teia s Petrol. , Geismar , L a Unio n Teia s Petrol. , Geismar , L a Unio n Texa

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# APPENDI XB

Percentag e Leake r Dat a fo r Californi a Refineries , fro m "Assessmen t o f Fugitiv e Emis i son s o f PRO C fro m Petroleu

m Refinin gOperations" , prepare dfo r th e Californi a Ai r Resource s Board , Ma y

198 7 (fro m Ite m No . VII-I- 1 o f thi s docket )IS J



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0 / 5 1/3 6

1/0 1

0/1 0
0/6 3
0/7 2 B

0.0 0 8.7 8

8.0 0

0.0 0
0.0 3
0.0 0 Liqui d

Froctlo n S

J

0 / 1 0.0 0

0 / 1 0.0 0

0 / 8 0.0 3
0/0 0 0.0 0
0/0 6 0.0 3 OC__ 3
i

0 

# 3

0 ! 3 > I 

# A ^

0 O
Btoocon OK , WomPor d Conoco , Sontt

o Oario Onnord , Onnord
Bloc

. Olotrlc t St__i_oto l 3/1,13 1 0/1 0 0/3 7 0.8 7

0.0 0 OI.O O 8/1,77 3

0/17 0 1/06 S O.O S . O/8,£0t 3

0.0 3 0.8 8 0/07 0 0.0 7 0/S 3 0.0 3 0/ 7 0.0 3 0/8 8 0.0 0 0/ 3 0.0 3 0/ 1 0.0 0 0/ 0 0.0 3

3/1,17 8 0.8 5 9/8,01 8 0.3 6 0/6,87 8 0.0 3 0/8 3 0.C 0

0.0 3 0/11 3 0.0 3 0/ 7 0.0 0 0/8 9 0.0 0 0/ 7 0.0 0

TOTA L ALL DISTRICT S 580/38,08 3 1.3 8 683/78,59 0 0.8 0 38/80,88 6 0.1 3 130/8,08 8 0.6 1 01/05 9 8.9 3 1/10 8 0.7 0 

## 0/5 0 0.0 0

Motes

. Footnote s or o «tef«ita d o n th o continuatio n o fthi e tabl e o n th o follcolnf l pofla

. 

## ^

-

### P.3 0



# APPENDI XC

Calculatio no f Percen t Leaker s fo r Ligh t Liqui dan d Ga s Valve s Aggregate dfo r Californi a Refinerie s

### P.3 1 

# RADIA N

SIGNATUR_________n____t__ £ft •.•>•__.__

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### P.3 2



# APPENDI XD

SYSTA T Statistica l Analysi s o f Valv e an dPum pPercen t Leaker s Dat a fo r Californi a refineries , Texa s an d Louisian a refineries , an dTexa s an

dLouisian a SOCM I Plant s

### P.3 3



## PLAI? $ TYPE ) VAL7I UPQHPl lVTHR A PTHRA TYP

E

CAS E CAS E CAS ! CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS E CAS I CAS E CAS E CAS E CAS E CAS I CAS I 

# 1 2 3 4 5 6 7 8 9 * 

# 1 0 1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 21 2 2 2 3 2 4 AtC O

Cie. 8 Edg a Glles t HacBi l levHa l Shel l Chev ! Exxo a Shell 2 Toa c Uiio o Coaa 

# [e m Texac o Beaf l Cono Oxnar d Pk.16 6 Aioco l Marat h DCar b AtCOT x Cai n CAle f

CAle f CAlef CAle f CAle f CAle f CASe f CAle f CAle f CAle f CAle f CAle f CAle f CAle f CAle f CAlef CAle f CAle f Tlie f Tlie f TUe f TLBe f TLSO C TLSO C 2.64 0 1.94 0 1.28 0 0.28 0 3.75 0 0.09 0

, 0.57 0 0.43 0 0.77 0 0.21 0 1.47 0 0.47 0 0.97 0 0.48 0 0.00 0 0.20 0 0.10 0 1.28 0 0.04 0 0.12 0 0.31 0 0.05 0 3.88 0

2.05 0 0.00 0 32.10 0 0.00 0 0.00 0 7.51 0 1.64 0 2.13 0 5.82 0 13.10 0 1.15 0 0.00 0 0.00 0 0.86 0 0.00 0

0.00 0

0.26 0 0.00 0 0.00 0 3.22 0 2.08 0 .

0.16 3 0.14 0 0.11 3 0.05 3 0.19 5 0.03 0

0.07 6 0.06 6 0.08 8 0.04 6 0.12 2 0.06 9 0.09 9 0.06 9 0.00 0 0.04 5 0.03 2 0.11 3 0.02 0 0.03 5 0.05 6 0.02 2 0.19 8

0.14 4 0.00 0 0.60 2 0.00 0 0.00 0 0.27 8 0.12 8 0.14 6 0.24 4 0.37 0 0.10 7 0.00 0 0.00 0 0.09 3 0.00 01

0.00 0

, ( 

## 0.05 1 ; 

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### P.3 4



# CAS E2 5 CAS E2 6 CAS I 2 7 CAS I 2 8 CAS E2 9 CAS E3 0 CAS E3 1 CAS E3 2 CAS E3 3 CAS E3 4 CAS E3 5 CAS E3 6 Phl66 S

ExxaBy Aioco S CainC C DouCh i Sterl g Hoaaa n Yist a l_x_\A 

# ExIes B ExChe i DORCL A 

# TLSO C

TLSO C TLSO C TLSO C TLSO C TLSO C TLSO C TLSO C TLSO C TLSO C TLSO C TLSO C

?A1IABL1 S i l STSTAT REC T FIL EA1E : PLAIT ) TYPE ) YALYEI i PTHITA TYP E >anovapthet a >category type= 3 >estiiat e 5 CASE S DELETE DDUET OHISS1I 6 DATA . 0.08 0 0.03 0 0.15 0 0.52 0 O.OO O 0.04 0 0.04 0 0.00 0 1.31 0 0.00 0 0.40 0 0.90 0

PUHP U 2.78 0 0.00 0 4.90 0 0.94 0 0.84 0 3.62 0 6.75 0 0.00 0 12.50 0 5.56 0 0.02 8

0.01 7 0.03 9 0.07 2 0.00 0 0.02 0 0.02 0 0.00 0 0.11 5 0.00 0 0.06 3 0.09 5

VTHIT A

YA! : PTHET A 

# I : 3 1 HDLTIPLIl : .38 2SQOASI D HDLTIPL It : .14 6

AIALYSI S O F VA1IAIC !

SOM A SOH-OF-S-QUAIE

S D E UM-SQUi lF-IATIO

TYP I0.05 720.02 9 2.39 3

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0.11 0 0.16 8

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2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0



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