# Envisage Environmental Incorporated

Sept ember I. 1999 Ms. Jane Bell Agency Repre se ntative 

### C leve land Department of Environment Department of Health and Welfare 

### City or C leve land 1925 5 1. Clair Ave. C leveland , Ohio 44114**~c** 

## 0 9 1999
f -, ,I;
. u, •• ,,;,''; 

# c ',-**I\l;~ POLLUTjj~I\J**  

## COi:i,.
Rc : S ub miss ion Oh io E PA Int cn t t o Tes t Not ifi cat ion Pilch ! 

### Oi :lIll o lld H a rd C hl"o mc In c . 

### 6 11 0 Gra nd Ave n ue C levela nd , O hi o 44 104 

### Dear Ms. Bel!: Enclosed for yo ur review is a completed O hi u E PA In tent To Test Not ili cation Packet f or Din lllond I

- lard Chrome J

### nc. The purpose of thi s notification is the desire to demonstrate compliance \0 

### an Ohio EPA PTI 

### for an increase in plating power for Plating Tank No.7. Plating Tank No. 

### 7 has been modified to now being ab le 10 

### apply 9000 amps o f electrical power to the plaling operation from a preex isti ng power capac ity o f 5000 amps. Additionally, the air pollution mcsh pad collector system for Plating Tank No.7 has been replaced with a larger more ef'ficient system. The proposed tes ti ng program will fo ll ow the current MACT standards for Ch r ome plating system by 

### emp l oying USEPA Method 306 sampli ng procedures, as st ipulated in the 

### I1T packet. Two exceptions to 

### the standard sampling procedures are proposed. Both of these modifications wcre incorporated into the last testing program conducted on this system. June 18. 1997 , and were acceptable to local , state and federal agencies. Beca use orthe spatia llimi ialion s of the exhaust ductwork exiling the 1.0
. fan sys t em. Method I and Method 2 specifi cation s were no t mel and modification s were inc orporated to compensate for the se method deficiencie s . These modification were; I ) Mcthod I di stances were not available and strai ghtening vanes were added to tbe ductwork. 2) For Method 2, thc innermost sample point for each sample pan could not be physically reached with the sampling probe assembl y. Therefore the second point on each sa mple port was samp led for twice the time to co mpensate for thi s physica l con straint. We are propos ing 10 samp le in the same f as hi on for th is propo sed sampling program.

P.O. 80ll 152 Richh eld. Oh io 44286**Phon~** (4 40) 526·0990 Fall (440) 526·8555

### Ms. Bell 

### 9/1199 page 2 of2
Please review the attached ITT packet and feel free to call me with your comments and suggestions. I have not called for a pre-test meeting however we certainly are available if it is decided to have one. Sincerely, Envisage Envirorunental Inc.

# iZ:~ (1.""4<-**)(;;;'~t/s.** Anderson

. President



### Attachment:
cc: Ohio ITT Packet, Diamond Hard Chrome Inc. Method 306 

### Mr. Robert Tankovich, Diamond Hard Chrome Inc.

Envisage Environmental Incorporated P.o. Box 152 AJchh&.d. OhIO 44286 Pno"" (440) 526.()9<J()

### INTENT TO TEST NOTIFICATION (One Emissions Unit Per Sheet) Proposed Test Date: To be determined Agency Use Only Date Received: 

# ------------------------------------- Pre-Test Meeting Desired 

### YesD 

# NoD No. Assigned: SCC Code: Facility Premise Number: Company Name: DIAMOND 

### HARD CHROME INC. Address: 6110 Grand Ave., Cleveland, Ohio 44104 Contact Name: Mr. Robert Tankovich Telephone Number: 216-391-3618 

### B. Testing Firm Information Name: Envisage Environmental Inc. Address: P.O. Box 152, Richfield, Ohio 44286 Contact Name: Mr. Bryon Marusek, EIT Telephone Number: 440-526-0990**----~----~--~--~--------------------** 

### C. Test Plans and Emission Units Information Table: List the applicable information under each respective column heading. Emissions Control Monitoring Pollutant(s) to 

### EPA Test Filter Box Number of Total Time for Number of Unit Equipment Equipment Be Tested Method(s) Temperature Sampling points Test Run Sampling Runs Chrome Plating Scrubber #3 Velocity Pressure Total Chrome 1,2,4,306 Ambient 25 120 3 Tank #7 Gauges

Source is testing to comply with (check all that apply) 

### State PTI

### ~ State PTO 

# D Title V 

# D NSPS 

# D MACT 

# D BIF 

# D Title IV 

# D Other 

# D D. What is the Maximum rated capacity? 9000 amps plating power

Will Emissions Unit be 0llerated at the maximum capacity given in its Permit·to·Iustall or Pennit.to-Opcratc? Yes

### ~No 

# [ I If no, attach explanation**Spcci~~w~~ratiqra~wm~.moo~~~~riq~~rS~n~~I~Md300~p~ p~ro~d=u~c~ti~o~n~r~e~c~o~r~d~s~** 

### _______________________________________________________________ Any modifications to USEr'A Reference Mcthod(s) proposed? 

### Y

### es**~** 

# NOD If"no" is checked. then no modification. however minor, will**~** accepted If yes, explain proposed modificalion(s): 

### due to physical restraints Method 1 and 2 

### will be modified as per testing of 6/18/97
Snrnpling Location(s): Inlet 

# D Outlet

# ~ SimullMcous 

# D Will cyclonic now check(s)**~** conducled? Yes 

# D No

# ~ Fuel Sampling: Coal

- Proximate 

# D Ultimate 

# D If olher. specify: 

# D
Emission mles to be calculated using: F·Factor Proximate 

# D Ultimale Coal At13lysis 

# D Other**~** If other. specify: 

### Test Results compared to regulations Arc concurrent Method 9 readings to be perfonned Yes No 

# [0 Does this test method require audit samples? Yes 

# D No

### ~ 

### E. Sample Train Calibration: All affected measuring and monitoring equipment should be calibrated within 60 days ofthe scheduled testing. Ohio EPA Form revised 3/98Intent To Test Notification General Notes on Chromium Sampling and Analysis The field emission sampling procedures used by Envisage Environmental, Incorporated, are presented in USEPA Reference Method 

### 306, Determination of Chromium Emissions From Decorative and Hard Chromium Electroplating and Anodizing Operations. The chromium sampling train assembly may be found in the sampling train diagram. A brief description of its operation is presented below. Gas flow measurements will be conducted simultaneously with the chromium sampling so isokinetic rates can be maintained. The pitot system is zeroed and each leg is leak checked at greater than 3" H20 gage pressure for at least fifteen seconds. The average velocity pressure and temperature between the two runs will be used to calculate a chromium emission rate. The entire sampling train is vacuum leak checked from the nozzle opening at about 

### (-)15" Hg gage pressure. The sample probe is positioned at the 

### first sample point within the stack and sampling begins when the source reaches stability. Post-test run leak checks are performed as above with the sample train leak check conducted at the highest vacuum attained during the run and is held for one minute. Also incorporated into the field sampling and data analysis are those considerations and calculations contained in the following: 

### 1) Construction Details of Isokinetic Source Sampling Equipment, USEPA Doc. APTD - 

### 0581, April 

### 1971. 2) Maintenance, Calibration, and Operations of Isokinetic Source Sampling Equipment, USEPA Doc. APTO - 

### 0576, March 

### 1972. 3) "A Method of Interpreting Stack Sampling Data," by W.S. Smith et ai, June 

### 14

- 19,1970. Laboratory analyses which are fol/owed by Envisage Environmental are those procedures stated in USEPA Reference Method 

### 306A, Determination of Chromium Emissions From Decorative and Hard Chromium Electroplating and Anodizing Operations, with associated calculations presented therein. Envisage Environmental Inc. also uses the on-site sampling procedures and sample analysis quality control and quality assurance requirements as published in USEPA Document 

### 600/4-77/027b June 

### 1987, Volume III, Part A and 8; Quality Assurance Handbook for Pollution Measurement Systems: Volume III. Stationary Source Specific Methods.

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### Envisage Environmental Incorporated p.o. Box 152 Richfield, Ohio 44286 Phone (440) 526-0990Intent To Test Notification Chromium

I F. Sampling Train Information

Please refer to Sampling Train Diagram for schematic of proposed chromium sampling train. (Attachments No. 1) Sampling for chromium emissions 

### will be performed using the USEPA Method 5 sample train (excluding filter) in place of the Mason Jar method. The sampling train is assembled as follows: Method 5 probe and impingers. The four impingers contain in order· 100 ml. of 0.1 N NaOH, 100 ml. of 0.1 N NaOH, empty, and 200 g. of silica gel. Glass probe liners will be used. The probe 

### will be modified by installing a calibrated "type K" therniocouple for probe exit temperature measurement. This modification 

### will not alter the heater construction design as specified in APTD-0581. The on-site sample recovery is carried out as follows: After the post test sample train leak checks have been performed, the probe assembly is disconnected from the sample train and rinsed and recovered with the absorbing solution. The probe is considered clean and may be reused for the next sampling run. After the leak check operations the impingers are removed from the sample train, wiped clean from sealing grease, and stored in their labeled and recorded sample case.



### Envisage Environmental Incorporated p.o. eo. 152 RlChlteid. Ohio 44286 Phone (4401 526-0990

## Sampling Train Diagram



# I**~ ~**  

### -1'1111'1**~&'~~~** ;;x 

## n < < 

# :. ..... 0-.--**:?~** .... 

### en**~** 'DOl» :1: 0**~ca**

### ~ 

## &;3 tD

.. tD**tD~** Q. .. DI 

# - PERAnJRE SENSOR IMPINGER TRAIN 

# ;d .j.PR08E

# ~E S PITOTlVBE

GLASS NOZZLE TEMPERATURE SENSOR FILTER OMlllED

# \,~~ 

# " IjdJ 

# n

PITOT MANOMETER 100 mIO.1N 100mlO.1N empty NaOH Naot-I (modl1lod 1 (modll\ed 1110 Up) (standard Up) no lip)

ORIFICE 

## -I

DRY GAS METER 

### U.S.EPA Method 306

- Isokinetic Sampling Train TEMPERATURE SENSOR 

# 1

a111ca gel 200·3OOg. (modlllod 1110 lip)Attachment #3

Centrol Unit (Molor Boxl**~E~.,saqo** Envltonmenl3t Inc _Ar.aotsen SampietS

RcmanufadUfod RAC**=O~Pcnt** ConSlanI Flow Pumps ConSlant Motlitcnng Syslems VIG Flame le",,!8tlon OelOCIot Thermo**EnY~Cnm8ntal** Chamllumltleseence NO, NO:, NO,**Sam~le** Box A.-EEI _Rsmanufactutod RAC _EEl Spoclal Oesign Tentative Equipment Specifications**Impln~ets** • pet sample Ita", (each S81 changod ler each test tUnl .lLEEt ..LEEt Samele Ptobe LitletS**Tem~etatutO** Sen SOtS _Omega Englnoellng L Type K Thermocouples .lLFlukO 51

F.shet SCientific =Fosn8t SCIOntlfic Ptessuro Gaugos L Inclone Manomolet

_ Ma<;nholoc

_ Ma<;nhehc "U- Tube Manomet8t ·tt" Tube Monemote, MICI'019dOt E:ectromanomoler Chemicals & Roagents .lLWator**~** AcoloftIJ A.-Solica Gel ..L

Vacuum G,ea50 _N.tncAc,d**_S~lluticACId** _Isopropyl Alecno. _Hydrogen POfOXlc19

__SOdium HydroXiCe length 2 loot 31cet 51001 7 fOOl 10 loot 12 loot 16 loot 24 loot

ACS Gtade I.IB09·13 MB IA. 2A MB 03·07

SB01,02,&05·07 SB 03 & 04 SB 08 ·11

J MOllified Smith Gteenburg t Smlll\ GreenbU'g Matenal**SS~x.** Quartz. Teflon SS te. :-Quartz. Teflon SS.
. Quartz. Tallon SS. Pyrex. Quanz. Teflon SS. ext91r. Qualtt. Teflon SS. Pyrex. Quanz. Teflon SS. Pytex, Qualtt. Teflon SS. Pytex, Quanz. Taflon

PYOI & 02 PY09·14 Metcury .n Glass Bimetlllhc

001, O· 10 "H,O MagnetlClMechanlCaJ 0 • 1 "H:O MagnetlClMechanlCaJ 0 • 10 "H:O Metcury :!SWatet 72- Watet O· 10 "H,O ElecttlC 001
.. 100 "H20
O.,onlZod & OislJlled ACS Grade 6· 16M9.n Acetone Insotuble & Heat ReSIstant ACS Gtado ACS Grade 30'4 SOlution



### Envisage Environmental Incorporated PO 50x 152 R,cr-.l,e'rj ,::,0-.')**·~~i** ":,,' Phone**1·1JC~ 526·0q()~j** Intent To Test Notification 

### Chromium G. Laboratory Analysis The protocol used for the laboratory analysis of the collected samples is as presented in US EPA Reference Method 

### 306. The impinger liquid catch is measured volumetrically. The liquid contents are combined. The
I solutions are combined with the probe rinse and sent to an independent laboratory for analysis by Method 

### 306.

The silica gel is measured gravimetrically and its weight difference from its tare is determined and recorded as I water vapor collected. The appropriate blanks from the test program are treated and recorded along with the

above samples.



### Envisage Environmental Incorporated p.o. Box 152 Ricltfield.**O~IO** 44286 Phone (440) 526-0990Intent To Test Notification H. Description of Operation Three chrome tanks use chromic acid to provide a finished product with a smooth working surface. The emiSsions from this source go through a mist eliminator at the outlet of each tank and then go through a chrome scrubber before exiting into the atmosphere. I. Stack and Vent Diagram See Attachment 

### #2 diagram. 

### J. Safety All standard safety procedures and precautions shall be followed. The following personal protection is recommended: 

# I

# ~**I~ ~**  X 1-

### I~**I~** safety glasses with side shields chemical resistant goggles ear protection hard hat steel toed safety shoes long sleeved shirts flame retardant clothing respirator dusUparticle acid gas organic vapor SCBA



### Envisage Environmental Incorporated p.o. Bo. 152 Richfield.**O~IO** 44286 Phone (440) 526·0990

### Process Diagram

Chrome Tanle7 Mezzanine

Composite Mesh Pad Mist Ellminalrn

### ~-----,~------~ Composite Mesh Pad Mist Enminator Straightening Vanes \ WaU

I Sample Port

Location



### Envisage Environmental Incorporated PO So.**'~2** n**,.,;,~I'"j** Or- -, ':.1;';;'-' Pt"1one**I':'':C~** 526·0g.),)
.

### Traverse Point I 

### Port Location Diagram


# i 00000 

## -----r 13.750' Q.534 Equivalent Diametl!l1l Upstream

tram Disturbance (5) 3" 1.0. Sampling Porta

6.750' 2. 12 Equivalent Diameter. Downstream from Oisturoance 

# J Pat 1

Pat 2

Pat 3
Pat 4

Pat 5

# ~5"11 6.75" 

# -.l

22.5"**~---** 30.125" ----I

Point

1 2 3 4 5**~Fram** " of Duct Dllpiltl Iftakie W-'IIIft.1 10 30 50 70 90 3.00' 9.082" 15.082" 21.082" 27.125"



### Envisage Environmental Incorporated po. Box 152 Richfield. Ohio**.\.128~** Phone (440) 526·0990

# SOURCE EVALUATION RESULTS

PREPARED BY 

# Envisage
,... Environmental Incorporated P.O. Box 152 Richfield, Ohio 44286 Phone (440) 526-0990

# Envisage ICnvironmental Incorporated

Novem ber 19, 1999 Mr. Robert Tankovich Diamond Hard Chrome Inc. 6110 Grand Avenue Cleveland, Ohio 44104 Dear Mr. Tankovich The following report is the result of the emission evaluations performed on November 10, 1999 at Diamond Hard Chrome Inc, Cleveland, Ohio. Testing was performed on the exhaust stack of the #3 Scrubber serving Chrome Plating Tank #7. The mass emission of total chromium was determined on the outlet gas stream to verify compliance with applicable Federal and State regulations in force at the time of testing.
The results are true and accurate to the degree specified in the pertinent sections of the Code of Federal Regulations, in force at the time of testing.
I look forward to answering any questions you may have and assisting you in the future. Respectfully submitted,

# U;7~NTALINC. DavidR. Salem

# ~ Air Quality Services

P.O. Box 152 Richfield, Ohio 44286 Phone (440) 526·0990 Fax (440) 526·8555

# TABLE OF CONTENTS

INTRODUCTION DESCRIPTION OF PROGRAM TEST RESULTS SUMMARY TEST RESULTS DETAILED OPERATIONAL PARAMETERS SAMPLE POINT LOCATION DIAGRAM SAMPLING TRAIN DIAGRAM LABORATORY SECTION FIELD DATA SHEETS CALIBRATION SECTION EMISSION SAMPLING NOMENCLATURE EMISSION SAMPLING CALCULATIONS PAGE NUMBER 3 5-6 

## 8 10 12 - 13 15 17 19 - 21 23 - 27 29 - 30 32 - 34 36



### Envisage EnvironmentaI rC:C:777i7TF",,", 

### Incorporated

### 2



# INTRODUCTION

Envisage
,**".".~..** 

### Environmental Incorporated p.o, BOl( 152**R'<;tlf~e:d.** OhlO.4.42e6**Pr~ooe** {440} 516·0?J0

### 3 INTRODUCTION Envisage Environmental Incorporated conducted emission sampling at Diamond Hard Chrome Inc. Cleveland, Ohio on November 10, 1999. The objective of the test program was to measure the mass emission rates of total chrome emitted into the atmosphere from the exhaust of the #3 Scrubber. Emission sampling was conducted in triplicate on the source exhaust, with each of the test runs conducted over two (2) hour periods. Mr. Robert Tankovich (Diamond Hard Chrome) coordinated the test program and operational procedures. The Envisage testing team consisted of: Mr. David Salem, Mr. Andrew Brown and Mr. Chris Mcintosh. Ms. Jane Bell (The Cleveland Division of Air Pollution Control) was on site to witness the testing event.



### Envisage Environmental Incorporated P.O 80x 152 Richfield. Ohl!) 44286 Ptlone (440) 526..0990

# DESCRIPTION OF PROGRAM 4



### Envisage Environmental Incorporated P.O.ll<>x152 Riohfiold.Oh\o44286 Ph"". (440) 52600990

### 5 SAMPLING AND ANALYTICAL PROCEDURES The sample collection and analysis techniques utilized for this test program were performed in accordance with the following USEPA Reference test methods: USEPA Method 1 USEPA Method 2 USEPA Method 4 USEPA Method 306 METHODS 1 Sample and Velocity Traverses for Stationary Sources. Determination of Stack Gas Velocity and Volumetric Flow Rate. Determination of Moisture Content in Stack Gases. Determination of Particulate Emissions from Stationary Sources.

The exhaust stack serving the #3 Scrubber has dimensions of 22.5 inches by 30.125 inches (an equivalent diameter of 25.76 inches). Five (5) sample test ports are located on the 22.5 inch plane, and have an upstream distance of 13.75 inches (.534 equivalent diameters). Because of the spatial limitations the downstream distance does not meet Method 1 requirements and straightening vanes were added to the ductwork. A total of twenty five (25) sample traverse points were used, five (5) per sample port. METHOD 2 A three (3) foot 

## "s" type pitot tube, and a Type K thermocouple were used for measuring the gas stream velocity and temperature. The pressure drops, temperatures and samples were measured by traversing across the internal diameter (30.13 inches) of the stack through the five sample ports. METHOD 

### 4 The moisture content of the gas stream was determined by USEPA Method 4, impinger procedure. The impinger procedure consists of an integrated gas stream sample which is drawn through a series of chilled impingers, filled in this instance, with Method 306 reagents and tarred dry silica gel, by means of calibrated dry gas meter. The net weight of liquid and water absorbed by the silica gel were recorded for the calculation of water content per sample volume. METHOD 306 The chromium emissions exiting the exhaust stack were measured by following the procedures outlined in USEPA Method 306, "Determination of Chromium Emissions From Decorative and Hard Chromium Electroplating and Anodizing Operations". The sampling train consists of a pyrex nozzle connected to an unheated Pyrex liner. The liner was connected to a series of impingers (Method 4) which contained; 100ml of 0.1 N NaOH in the first two, followed by an empty, and the final impinger containing the 200 grams of dry silica gel.
Samples were taken from the gas stream isokinetically through the nozzle and sample train. Exit gas temperature of the impingers was maintained below 68°F. with an ice bath. At the conclusion of each test run the sample train 

### Envisage Environmental Incorporated P.o, Box 152 R,ch1'eld', Ohio 44286 Phone {440J 52&0990

### 6 was allowed to cool and a leak check of the train and pitot tube was performed. After the leak check the probe and nozzle cleaning was performed in the field using a carrier liquid of sodium hydroxide. The field cleaning of the sampling probe and nozzle follows this procedure; At the conclusion of the test run the nozzle is removed. the inside surface is rinsed until visually clean of particulate matter. The rinse is collected in a glass sample bottle and capped with a teflon lined lid. The sample probe is rinsed into the same container by tilting the probe assembly and rotating so that the rinse liquid empties into the collection bottle. Visual inspection is then made and the process repeated until the rinse liquid is visually clean. A final rinse is then rotated down the inclined probe liner into the sample bottle. The sample bottle is then capped and secured in the appropriate test run container.
The rinse samples including the impinger liquid are taken and analyzed in the laboratory. The impinger liquid is measured volumetrically and transferred to a storage bottle. The liquid is then transported to an independent laboratory for analysis of chromium using graphite furnace atomic absorption spectroscopy. All sampling and analytical procedures were performed in accordance with the methods specified in the Code of Federal Regulations, Title 40, Part 60, Volume 43. Example calculations to determine the emission rates can be found in the example calculation section of this report.



### Envisage Environmental Incorporated P.o. Box 152 Rlchfa)ld. OhIO**';~2ef,** Phono 1':-40) 526-0990

### 7



# TEST RESULTS SUMMARY

Envisage

..........._-. Environmental Incorporated P.O.1lox 1$2**R'OI\f,cl~_** 01\0**~~266** Pnono (4401 $2\i.()9!)()TEST RESULTS SUMMARY Diamond Hard Chrome Inc. Cleveland, Ohio Chrome Plating Tank #7 - Scrubber #3 Chromium Emission Evaluation DATE: November 10,1999

PARAMETER Run 1 Chromium Emissions Pounds/hour 7.53E-05 Grainsldscf 4.24E-06 mg/dscm 0.0097 System Flow Rates FUSee 7.71 ACFM 2,179 DSCFM 2,072 Moisture Content Volume percent 1.76 Sample Location Temperature Degrees Fahrenheit 85 Run 2 4.77E-05 2.81E-06 0.0064

7.40 2,092 1,983

1.69

88 

### 8

Run 3 2.76E-05 1.61E-06

0.0037

7.49 2,115 2,003

2.29

85



### Envisage Environmental Incorporated PO 00. lSZ Ad',j,t!IO Oh'tJ .,t·$:?8t. Ph0l'\t)**~** ':':0 I**S~t>** OCtO{;

### 9



# TEST RESULTS DETAILED

Envisage ,-.---....... Environmental ; --.'-
...'-." Incorporated p.O.ll<Ix 152 RIch!
..Id. Ohl' 44285 I'too<» (440) 52'>-0990TEST RESULTS Diamond Hard Chrome Inc. Chrome Plating Tank #7 - Scrubber #3 Chromium Emission Evaluation
DATE: November 10, 1999 Symbol Units Time of Day
1 Gas Volume-dry,std. Vmstd cu. 

### ft. 1a Gas Volume-dry,std. Vmstd meters 2 Condensate Vapor Vol. Vwstd cu. ft. 3 Gas Stream Moisture Bws voJ.dec 4 Mol.Wt-fJue gas (dry) Msd Ib/lb mo. 5 MoI.Wt-f1ue gas (wet) Ms Ib/lb mo. 6 Flue Gas Velocity Vs ftlsec 7 Flue Gas Volume-Actual Os ACFM 8 Flue Gas Volume-Std. Os (Std) DSCFM 

### 9 Concentrations Cs

- Chromium gr/dscf mg/dscm 10 Emission Rate E

- Chromium Ib/hr

11 Isokinetic Rate % Run 1 Run2 08:00 10:25 10:00 12:47 72.09 72.56

2.04 2.05 1.29 1.25 0.0176 0.0169

28.84 28.84 28.64 28.65

7.71 7.40 2,179 2,092 2,072 1,983

4.24E-06 2.B1E-06 0.00970 0.00642

7.53E-05 4.77E-05

100.3 105.5 

### 10

Run 3 01:00 03:00 69.29

1.96 1.62 0.0229

28.84 28.59

7.49 2,115 2,003

1.61E-06 0.00368

2.76E-05

99.7



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### 11



# OPERATIONAL PARAMETERS



# I11/11/1999**13:3~ 2153'31~:>.1.8**  

# _DIAMOND PAGe: 81 

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# SAMPLE POINT LOCATION DIAGRAM

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### Incorporated ,." ., P.O. 00. 16Z Rodl!;cld. OM 442&6**~~i:ill'** ""_(440)525·0900

### 15 

# o SAMPLE POINT LOCATIONS Facility: Diamond Hard Chrome Location: Scrubber 

### #3

inches width

Point 

### # Distance From Inside Wall
1.9 inches 

### 2 5.6 inches 

### 3 9.4 inches 

### 4 13.1 inches 

### 5 16.9 inches Width Length Area 22.5 inches 30.125 inches 4.71 square feet Position Horizontal

Stack Description: Rectangle Horizontal 

### *** Downstream distance too shortl 

### *** 1.1 Feet, Upstream Disturbance Distance 2.3 Feet, Downstream Disturbance Distance 4.71 Square Feet, Cross Section Area 4 Number of Traverses 2.1 Feet, Equivalent Diameter 0.5 Equivalent Upstream Diameters 1.1 Equivalent Downstream Diameters 24 Total Number of Sampling Points 

### Envisage Environmental Incorporated po Be. '!.2 RdJIL"id OhIO 442bf PhOM (440\ S2t>,o;J90

# I 

# I 16



# SAMPLING TRAIN DIAGRAM

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# LABORATORY SECTIONQ 

### 19 LABORATORY SUMMARY SHEET Diamond Hard Chrome Inc. Chrome Plating Tank #7 - Scrubber #3 Chromium Emission Evaluation
DATE: November 10, 1999 Symbol Units Run 1 Run 2 Run 3 1 Sampling Time t minutes 120.0 120.0 120.0 

### 2 Barometric Pressure Pb in. Hg 29.92 29.92 29.92 3 Static Pressure Pg in. H2O 0.03 0.03 0.03 Stack Pressure Ps in. Hg 29.92 29.92 29.92 4 Gas Meter Volume Vm cu. ft. 74.12 74.46 71.43 5 Stack Area A 

### sq. ft. 4.71 4.71 4.71 6 Nozzle Diameter On dec. in. 0.50 0.50 0.50 7 "Y" Factor 1.002 1.002 1.002 8 Meter Temperature degrees F 85.7 84.6 87.1 Tm degrees R 545.7 544.6 547.1 9 Stack Temperature degrees F 85.5 87.5 84.8 Ts degrees R 545.5 547.5 544.8 10 Velocity Head (SQRT) "P in. H2O 0.134 0.129 0.130 11 Orifice Pressure "H in. H2O 1.28 1.31 1.23 12 Carbon dioxide CO2 % 0.0 0.0 0.0 13 Oxygen 02 % 20.9 20.9 20.9 14 Carbon monoxide CO % 0.0 0.0 0.0 15 Nitrogen N2 % 79.1 79.1 79.1 16 Pitot Coefficient Cp 0.84 0.84 0.84 

### 17 Water Collected Vic ml 27.5 26.5 34.5 18 Sample Weight: Mn

- Chromium ug 19.80 13.20 7.22 mg 0.020 0.013 0.007 

### 9 1.98E-05 

### 1. 32E-05 7.22E-06 

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### Richfield. OH 4428h 

### Dale Collected' N/A Date ReceIVed 11111/99**ProJect~:** 

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# ..... 0.38 .-: 038



### "Analyticallnt'grity" • A2LA Accreditation #0724.01 • ISO 90( 0 5'15 East Tallmadge Avenue • Akron. Ohio 44310. Phone: 330-253-&211 • Fax: 130-253·4489 

### Email se!3746@apk.net 

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# CALIBRATION SECTION 28

Envisage Environmental Incorporated p.o. Box 152**Ri"I\fo.I~. o~;o**  44286 PM
... (440) 526·0990

# · :.. 

# EMTIC GUIDELINE DOCUMENT GD-026 Alternative Method 5 Post Test Calibration Company: Diamond Hard Chrome Inc. Cleveland, Ohio Meterbox 10: MB 17
Run 

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### 2 120.00

74.46 84.63 544.63

29.92

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## 29

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29.92

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### Envisage Environmental Incorporated po. Box 152 Richfield OhO 44286 Phone (440)520-0990.f 

## o C') METHOD 5 DRY GAS METER CAliBRATION USING CRITICAL ORIFICES 1) s.cten.CI1tcoI cd!Ic:ft III calbra
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# l

# ~§ 5.1478 5.I7Z7 1.00f1 UfOl '.00 U 5.14113 5.1111 1.0031 1.13$0 IZ.OO U 1.75" 1.lU5 1.0011 1.1.51 Ava. 1.0011 0.1.

# ~§ salis 5.ZIM a .• _ 1.1101 5.00 ,. 531\1 5.lIM o.lUl 1.1101 5.00 U 5.1111 5.ZSSf O."!lI 1.1101 AVO_ O.ttZl .0." n.oo 0.•" 5.ZUl 5.'110 I._II 1.1113 11.00 UI5 5.22'0 S.'IBO uln 1IU, 13.00 0.
.. 5 S.nl. 5.Z_ 1.0112 urn Ave. 1.0101 0.10 Tho**~..,.-,.** ..-"10
_ tot -............ III p ....

d ItroI.9ItotDGU. V.(oId). nth e<tIcti ootIct. V.(IId).,mhOGU.
__ .y. T
...... ..- ..... _tlr_.dntot '1""
__ AVERAGE DRY GAS METER CALIBRATION FACTOR, Y 

## .1

- 1.0021 I" V. (.Id,.
(2, V
.. loldl· Il) y.
MBn
0.10 Callbral"': Dal.Ouo: K, V. p••+ .... HlI 3.11 T. • Natvolme elf gas so. passed**.~.,...** OGM. eorrec:led 10 sWldald**~~ons** K, • 17.84 'Mn IIg (EnglIsh). O.38S8 'KInrn Hg (MtIric) p e II' 

## -..IT::: T
.. ;s**~oU:.** OGM avg tttf11).atU'. ra .. EngI"'. eK· Metk)
• VeUTie elf gn**~** pasud Itroug, ""**at~tol** orIIke. corrected 10 standanI conctaons T
.... AbloU. atrbIOIt 1..,.....I
.. e (II. EngII
....oK·

# _.j

K'. ,, __**~** K' fad", &"", CrtUc" onto. Callnll"" V.(oId, • OGM caltnlan lactor V.lstdl
6.... 1.75

Yc. 1.002**,~** 1212418• AVERAGE Aile • U.5t
AHe • 

## (lI.lUJ I AN V,,(old

### Ci_~ 

# ......**~** CQ)ll**~** 

# ..**~ ~Emj**  _ .. 50 ""C 0 a:m 

## m 0 

## c.**~** fI)
.... '" .-.- 0**~6** 

## > > CJ**:~ CCC.g~**  

### 111111-**~Q.** 

# '1·' .'t**~.** 

### 31



# EMISSION SAMPLING NOMENCLATURE

Envisage

. Environmental

Incorporated P.o Box 152 R;el'li;eld. OI'uo 4428(. Phone (440) 526-0990

## A 

## An Bws C C

p 

### C

s 

### Cs02


## E Es02



## P

bar 

### =
=
=
=
=
=

=
=
= 

# =
=


## = SAMPLING NOMENCLATURE
Cross sectional area of stack or duct, ft.2. Cross sectional area of nozzle entry plane, ft.2. Water vapor in gas stream, proportion by volume. Nomograph correction factor, dimensionless. Pitot tube coefficent Concentration of particulate matter in gas stream, dry basis corrected to standard conditions, gr/dscf. Concentration of sulfur dioxide (Ib/dscf) Nominal diameter of probe nozzle entry plane, in. Emission Rate, Ib.lhr. Emission rate of sulfur dioxide, Ib./hr. Average pressure differential across orifice, in. of H2 

## 0. Orifice meter calibration factor, in. of H2 

## 0. 32



# = Percent of isokinetic sampling, 

## %.

= Pitot tube constant, 85.49 ft.lsec. 

# = Constant, 

### 0.002669 in. Hg-fe per ml - Rankin



### = Molecular weight of gas, dry basis, Ib.llb.-mole. 

# = Total amount of particulate matter collected, g.


### = Molecular weight of gas, wet basis, Ib.llb. -mole.



### = Molecular weight of water, 18 Ib.llb.-mole.



### = Barometric pressure, in. of Hg. 

### Envisage Environmental Incorporated po Box 152 RIchfIeld, OhoO 442B6 Phone- (440, 525·09!JO, 

# "

PCDD 

## = PCDF 

## =

=



## = P

std 

### = 

## = ppm 

## = AP avg 

# = Q 

### = Qstd 

### = 

## R 

## = t 

## =
=
=
Tstd 

### = 

# = Vic 

# = = Vm(std) 

### = VOC 

# = = Polychlorinated Dibenzo-p-Dioxins Polychlorinated Dibenzofurans Pressure differential from gas stream to atmosphere, (static pressure) in. of 

### H2

### 0. Absolute gas stream pressure, (P bar 

### + P

### gl13. 

### 6) in. of 

### Hg. Absolute pressure at standard conditions, 29.92 in. of 

## Hg. Density of water, 0.00221b.lml. Parts per Million 

### 33

Average of the square roots of the velocity head readings, in. of 

### H 2

### 0. Volumetric flow rate at gas stream conditions, AC.F.M. Dry volumetric gas flow rate corrected to standard conditions, Ideal gas constant, 21.85 in. of 

## Hg-fe, oR-lb.-mole. Total sampling time, minutes. Average dry gas meter temperature, oR. Average absolute gas stream temperature, 

## OR. Standard absolute temperature, 528° rankine. Volume of sample aliquot titrated Volume of water collected in impingers and silica gel, ml. Volume of gas sample measured at meter box (meter conditions), Volume of gas sample measured at meter box (corrected to standard conditions), ft.3. "Volatile Organic Compound" Average gas stream velocity, ft.lsec. 

### Envisage Environmental Incorporated p.o. Box 152**R~td:o!e,** Oho 4-42&; PhOne {440J**~26-0990**

# · ,.

V so1n 

### = 

## V

t 

### = 

## V

tb 

### = 

## Vw(sto) = y 

### = 13.6 

### = 12%C02 

### = %C02 

### = %0 2 

### = %CO 

### = %N 2 

### = 34 

### Total volume of solution in which sample is contained Volume of barium perchlorate used for the sample Volume of barium perchlorate used for the blank Volume of water vapor in gas sample (standard conditions), 

### ft.3. Dry gas meter claibration factor Specific gravity of mercury (H g ). 

### Particulate concentration corrected to 12% Carbon Dioxide (dry Percent by volume of Carbon Dioxide in gas stream (dry basis). Percent by volume of Oxygen in gas stream (dry basis). Percent by volume of Carbon Monoxide in gas stream (dry basis). Percent by volume of Nitrogen in gas stream (dry basis).



### Envisage Environmental Incorporated po. Box 152 q,chfle!d_ Oh 044286 Phone (JJO) 526-0990• p. 

### 35



# EMISSION SAMPLING CALCULATIONS

Envisage Environmental

.-, .. Incorporated P,o. Sox. 152 Roehfleld, 01110 4.42ao Phor·e (440)**S26-09'~O**• C>

EXAMPLE CALCULATIONS Diamond Hard Chrome Inc. Chrome Plating Tank #7 - Scrubber #3 Run # Start Time 08:00 Finish Time 10:00 Sample Time (t) 

# = 120.00 Barometric Pressure ( 

# = 29.92 Stack Pressure (Ps) 

# = 29.92 Stack Area (As) 

# = 4.71 Stack Temp. (Ts) 

# = 8S.46 Nozzle Diameter (On) 

# = O.SO Velocity Head ("P) 

# = 0.13 Orifice Pressure (I\H) 

# = 1.28 Meter Y Factor (Y) 

# = 1.002 Volume of H20 Colle 

# = 27.S0 minutes in. Hg in. Hg sq. ft. Degrees F. dec. in. in. H2O in. H2O ml Pitot Factor (Cp) Gas Analysis
Sample Weights (Mn) Chromium

Vm std. 

## = Vm 

### x [Tstd/(Tm + 460)] 

### x [Pb + ("H 113.6) 1 Pstd))) 

### x Y VmCmstd. 

## = Vm std 

### x .02832 Vw(std) = 0.04707 

### x Vic Bws 

# = Vw(std) 1 [Vm(std) + Vw(std}] Md 

## =(.44 

### x %C02) + (.32 

### x %02) + [.28 

### x (%N2 + %CO) Ms 

### = (Md 

### x (1 - 8ws)) + (18.0 

### x 8ws) Vs 

# = 85.49 

### x Cp 

### x SQRT[dP» 

### x [SQRT{{Ts + 460) I (Ms 

### x Ps}] Qs 

# = Vs 

### x As 

### x 60 Qs(std) 

## = Qs 

### x (1 - Bws) 

### x [Tstd I (Ts + 460») 

### x (Pb + Ps/13.6) 129.92 Cs 

### = 15.43 

### x (Mn I Vm (std» Cs 

### = mg/ Vmcmstd E = Qstd x Cs x (1 Ib I 7000 grains) x (60 minutes 11 hour) 

# = =

=

= = = 

# = =
= 

# = = = 

# = = = 1= {[100 x Ts 

### x «K3 

### x Vic) + (Vm I Tm» 

### x (Pbar + ("H 113.6»] 160 

### x An 

### x Vs 

### x Ps x tU x 

# = 36

0.84 0.00 % C02 20.90 %02

0.00 %CO 79.10 %N2 7.S3E-05 Ib/hr 9.70E-03 mgldsem 4.24E-06 gr/dscf

72.09 Ft3 

### 2.04 

### M3
1.29 Ft3 0.0176 vol.decimal

28.84 Ibllb mo. 28.64 Ib/lb mo.

7.71 fUsee 2,179 acfm 2,072 dsefm 4.24E-06 grains/dscf

0.0097 mg/dsem 7.53E-OS Ibs/hr

100.34 isokinetic

;,' .

# ~ Envisage Environmental Incorporated p,O Box 152 RIchfield, QtllO 4.4286 Phono (440) 525·0990