November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: US

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 60

Houston

3 Greenway Plaza, Suite 1150

Shintech, Inc.

(979) 233-7861, ext. 398

tandersen@shin-tech.com

Plant 1

5618 Hwy 332 East

Freeport

Thomas Andersen
ers (PVC) Production Process Wastewater

State: Texas Zip Code: 77046

hes, and related establishments owned): 575

State: Texas Zip Code: 77541
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: PL-1

Process Equipment ID: PL1WWSTRIP

Wastewater Feed Rate (lb/hr): 26,300

Feed Temperature (°F): 212.45

Feed Inlet Pressure (psia): 25.2

Liquid Loading Rate (liters/m2): 10,320

Steam Feed Rate (lb/hr): 1,530

Steam to Feed Ratio (kg steam/liter of wastewater): 0.06

Operating Temperature (°F): 215.88

Operating Pressure (psig): 0.44

Total Number of Stages: 11

Overall Calculated Tray Efficiency: 0.998

Stripping Factor: -

Flow configuration (countercurrent, cocurrent): Countercurrent

Number of Actual Trays: 11

Column Height (meters): 10.2

Year Equipment Installed: 1984

Equipment Currently Regulated Under (cite regulations): 30 TAC 115.352,30 TAC 115.357, 40 CFR 61

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

,30 TAC 115.357, 40 CFR 61

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: 12,100 liters/hour

 liters

m design rate or capacity, please provide those values:

 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production fa

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wa

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for e

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3

PL-1 LV-5

PL-1 CF-401D

PL-1 CF-401E

PL-1 CF-401F

PL-1 CF-401G

PL-1 CF-402D

PL-1 CF-402E

PL-1 CF-402F

PL-1 CF-402G

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

Centrifuge water - See Section 2.5 of the report

Centrifuge water - See Section 2.5 of the report

PVC Process 

Wastewater 

Stream ID

Centrifuge water - See Section 2.5 of the report

Centrifuge water - See Section 2.5 of the report

Centrifuge water - See Section 2.5 of the report

Centrifuge water - See Section 2.5 of the report

2

Centrifuge water - See Section 2.5 of the report

Incinerator quench water

Centrifuge water - See Section 2.5 of the report
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6

Min

PL-1 PL1WWSTRIP Steam Stripping Continuous PL1WWSTRIP 43,200

Table 3. PVC Process Wastewater Destination Codes Table

Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment S

2 3

Min Max

Type of Process 

Wastewater 

Treatment System

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

1

N/A

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

PVC Process Wastewate

VC) Production Process Wastewater

hin the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process waste

VC production process wastewater treatment system.

ter treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC prod

tment System

4 5 6 7 8

Min Max Average

6,900 9,700 8,300 Estimated 365

64,000 99,000 79,000 Estimated 365

64,000 99,000 79,000 Estimated 365

64,000 113,000 93,000 Estimated 365

64,000 113,000 93,000 Estimated 365

61,000 100,000 87,000 Estimated 365

61,000 100,000 87,000 Estimated 365

66,000 113,000 95,000 Estimated 365

66,000 113,000 95,000 Estimated 365

Operating Days Per 

Year

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day)
7 8 9 10 11

Max Average

89,280 76,752 Measured 365 WWT

Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

Wastewater Treatment System

4 5 6 7

Average

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Operating Days 

Per Year

Process Wastewater Destination D

water Stream Flow Rate 

ons per day)

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

VC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

eated by a PVC production process wastewater treatment system.

hat does not originate from the PVC production facility.

9 10

LV-5 Incinerator

CF-401D PVC Slurry Centrifuge

CF-401E PVC Slurry Centrifuge

CF-401F PVC Slurry Centrifuge

CF-401G PVC Slurry Centrifuge

CF-402D PVC Slurry Centrifuge

CF-402E PVC Slurry Centrifuge

CF-402F PVC Slurry Centrifuge

CF-402G PVC Slurry Centrifuge

Originating PVC Process 

Equipment Description

Originating PVC Process 

Equipment ID
12 13

Plant 1 Wastewater Treatment Yes

e of the wastewater treatment system

ere in the process the stream is recycled

Associated Destination 

Information

(Refer to Table 3 below)

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

11 12

WWT Plant 1 Wastewater Treatment

WWT Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

RECYC Plant 1 Wastewater Treatment

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

The Min, Max and Average are calculated from the 31 day campaign.

able 1 and Column 11 of Table 2

13

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?
de a description of the process wastewaetr 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

107211 Ethylene glycol SW-846-8015C 4 Non-detect 4 Non-detect

67561 Methanol SW-846-8015C 47 51

75070 Acetaldehyde SW-846-8315A 4.59 J 4.62

50000 Formaldehyde SW-846-8315A 0.075 Non-detect R 0.15 Non-detect

51285 2,4-dinitrophenol SW-846-8270D 0.175 Non-detect UJ 0.175 Non-detect UJ

98862 Acetophenone SW-846-8270D 2.52 J 4.11

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.125 Non-detect 0.125 Non-detect

123319 Hydroquinone SW-846-8270D 0.25 Non-detect 0.25 Non-detect

108952 Phenol SW-846-8270D 0.025 Non-detect 0.025 Non-detect

79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect

106990 1,3-butadiene SW-846-8260B 0.002 Non-detect 0.002 Non-detect

540841 2,2,4-trimethylpentane SW-846-8260B 0.001 J 0.001 Non-detect

71432 Benzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect

108907 Chlorobenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect

67663 Chloroform SW-846-8260B 0.001 Non-detect 0.001 Non-detect

126998 Chloroprene SW-846-8260B 0.002 Non-detect 0.002 Non-detect

98828 Cumene SW-846-8260B 0.001 Non-detect 0.001 Non-detect

75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.002 J 0.002 J

100414 Ethylbenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.054 0.056

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect

74873 Methyl chloride (Chloromethane) SW-846-8260B 0.011 J 0.012

75092 Methylene chloride SW-846-8260B 0.001 Non-detect 0.001 Non-detect

110543 n-Hexane SW-846-8260B 0.001 Non-detect UJ 0.001 Non-detect

108883 Toluene SW-846-8260B 0.001 Non-detect 0.001 Non-detect

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect

79005 1,1,2-Trichloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect

108054 Vinyl acetate SW-846-8260B 0.001 Non-detect 0.001 Non-detect

593602 Vinyl bromide SW-846-8260B 0.001 Non-detect 0.001 Non-detect

75014 Vinyl chloride EPA Method 107 0.006 Non-detect 0.006 Non-detect

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.001 Non-detect 0.001 Non-detect

1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.002 Non-detect 0.002 Non-detect

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B 0.098 0.093

Sample Date -->

Suspension Suspension

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Refer to Lab Reports

SF-PL-1-2

1

215.6

54

01/03/13

2

210.4

53

SF-PL-1-1

130030-1

Refer to Lab Reports

01/04/13

130030-4

Flow Rate Determination Method --> Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

on, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

4 Non-detect UJ 4 Non-detect UJ

48 44

5.03 4.67

0.15 Non-detect 0.152 J

0.175 Non-detect 0.175 Non-detect

3.79 3.07

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.046 0.058

0.001 Non-detect 0.001 Non-detect

0.01 0.012

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect UJ

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.095 0.086

Suspension Suspension

Refer to Lab Reports

SF-PL-1-3 SF-PL-1-4

3 4

215.2 210.2

58 59.8

01/05/13 01/06/13

Refer to Lab Reports

130030-5 130030-6

Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect UJ 4 Non-detect UJ

22 41

4.36 4.79

0.186 J 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

3.67 4.43

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 J 0.003 J

0.001 Non-detect 0.001 Non-detect

0.044 0.06

0.001 Non-detect 0.001 Non-detect

0.009 0.015

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect UJ 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.063 0.097

Suspension Suspension

214.3

56

SF-PL-1-5 SF-PL-1-6

5

216

54

6

01/07/13 01/08/13

Refer to Lab Reports Refer to Lab Reports

130030-7 130030-8

Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect UJ

56 56

3.68 4.77

0.075 Non-detect 0.15 Non-detect

0.175 Non-detect UJ 0.175 Non-detect UJ

3.28 4.07

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.003 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.036 0.05

0.001 Non-detect 0.001 Non-detect

0.014 0.01

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect UJ 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.041 0.059

Suspension Suspension

30 62

SF-PL-1-7

01/09/13 01/10/13

7 8

214 215.4

Refer to Lab Reports Refer to Lab Reports

130030-9 130030-10

SF-PL-1-8

Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect UJ 10 Non-detect UJ

57 59

4.92 4.43

0.15 Non-detect 0.15 Non-detect

0.35 Non-detect UJ 0.175 Non-detect UJ

5.08 2.63

0.25 Non-detect 0.125 Non-detect

0.5 Non-detect 0.25 Non-detect

0.05 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.002 J

0.001 Non-detect 0.001 Non-detect

0.034 0.048

0.001 Non-detect 0.001 Non-detect

0.005 J 0.012

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect UJ

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.052 0.051

Suspension Suspension

Measured Measured

59.9 53.7

01/11/13 01/12/13

9 10

211.6 212.2

Refer to Lab Reports Refer to Lab Reports

130030-11 130030-12

SF-PL-1-9 SF-PL-1-10
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

41 44

4.85 4.53

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect UJ 0.175 Non-detect UJ

2.8 3.47

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.003 J 0.005 J

0.001 Non-detect 0.001 Non-detect

0.041 0.048

0.001 Non-detect 0.001 Non-detect

0.013 0.013

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect UJ 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.021

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.06 0.07

Suspension Suspension

53 52.5

211.5

Measured Measured

01/13/13 01/14/13

11 12

213.4

Refer to Lab Reports Refer to Lab Reports

SF-PL-1-11 SF-PL-1-12

130030-13 130030-14
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

50 30

4.71 4.98

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

2.47 2.17

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 J 0.004 J

0.001 Non-detect 0.001 Non-detect

0.045 0.066

0.001 Non-detect 0.001 Non-detect

0.014 0.018

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.068 0.109

Suspension Suspension

56.2 50

213.1 211.3

Measured Measured

01/15/13

13 14

01/16/13

Refer to Lab Reports Refer to Lab Reports

SF-PL-1-13 SF-PL-1-14

130030-15 130030-16
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

56 39

4.51 4.36

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

3.06 2.49

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.048 0.044

0.001 Non-detect 0.001 Non-detect

0.012 0.01

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect UJ 0.001 Non-detect UJ

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.076 0.063

Suspension Suspension

60.8

211.46

Measured

15 16

01/17/13 01/18/13

216

Measured

Refer to Lab Reports Refer to Lab Reports

SF-PL-1-15

130030-17 130030-18

SF-PL-1-16

47.4
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

42 42

5.1 5.04

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

2.35 3.87

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.004 J 0.003 J

0.001 Non-detect 0.001 Non-detect

0.043 0.039

0.001 Non-detect 0.001 Non-detect

0.014 0.012

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.007 0.006

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.064 0.053

Suspension Suspension

17 18

01/19/13 01/20/13

Measured Measured

215.8 215.4

130030-19 130030-20

SF-PL-1-17 SF-PL-1-18

Refer to Lab Reports Refer to Lab Reports

54 51.8
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

44 60

5.49 7.12

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

3.95 3.8

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.002 J 0.001 Non-detect

0.004 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.039 J 0.061

0.001 Non-detect 0.001 Non-detect

0.013 0.012

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect UJ 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.055 0.082

Suspension Suspension

19 20

01/21/13 01/22/13

52

Measured Measured

212.7 211.8

Refer to Lab Reports Refer to Lab Reports

130030-21 130030-24

SF-PL-1-19 SF-PL-1-20

55
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

51 55

5.02 6.24

0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.175 Non-detect

3.97 4.28

0.25 Non-detect 0.125 Non-detect

0.5 Non-detect 0.25 Non-detect

0.05 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.003 J 0.003 J

0.001 Non-detect 0.001 Non-detect

0.055 0.05

0.001 Non-detect 0.001 Non-detect

0.013 0.012

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect UJ 0.001 Non-detect UJ

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.056 0.053

Suspension Suspension

21

01/23/13 01/24/13

215.8

Measured Measured

212

130209-1

Refer to Lab Reports Refer to Lab Reports

53 60

SF-PL-1-21 SF-PL-1-22

130209-2

22
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

39 34

6.11 5.13

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

4.66 2.88

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.048 0.045

0.001 Non-detect 0.001 Non-detect

0.009 0.009

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.063 0.056

Suspension Suspension

Measured

215.6

Refer to Lab Reports Refer to Lab Reports

130209-4

52.2

SF-PL-1-23 SF-PL-1-24

130209-3

48.8

01/25/13 01/26/13

23 24

215.1

Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

40 38

4.78 4.5

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

2.3 3.29

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.003 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.045 0.041

0.001 Non-detect 0.001 Non-detect

0.006 0.008

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.053 0.048

Suspension Suspension

215.2

26

Refer to Lab Reports

130209-5

01/28/13

SF-PL-1-25

48.1

01/27/13

25

Measured

50.4

211.5

SF-PL-1-26

Refer to Lab Reports

130209-6

Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

44 40

4.69 4.54

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

4.79 2.43

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.003 J 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.045 0.043

0.001 Non-detect 0.001 Non-detect

0.007 0.007

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.009 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.052 0.056

Suspension Suspension

27 28

01/29/13 01/30/13

53.9 51.2

211.8 214.9

SF-PL-1-27 SF-PL-1-28

Refer to Lab Reports Refer to Lab Reports

130209-7 130209-8

Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect

40 37

4.76 4.76

0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect

3.14 3.49

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 J 0.002 J

0.001 Non-detect 0.001 Non-detect

0.044 0.051

0.001 Non-detect 0.001 Non-detect

0.006 0.01

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect UJ

0.001 Non-detect 0.001 Non-detect

0.006 Non-detect J 0.006 Non-detect

0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect

0.064 0.06

Suspension Suspension

Refer to Lab Reports

130209-9 130209-10

Measured

SF-PL-1-29 SF-PL-1-30

29 30

01/31/13 02/01/13

56.5 53.2

213.3 213.1

Refer to Lab Reports

Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech, Inc.

Facility Plant 1

PVC Process Wastewater Treatment System ID PL1WWSTRIP

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Refer to Lab Reports

Concentration 

(ppmw) Non-Detect? Note(s)

6.29

0.419 J

31

02/02/13

Suspension

52

Measured

212

130209-11

SF-PL-1-31