# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information**

Parent Company

Name:

Address:

City:

Country: US

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 60 Houston 3 Greenway

Plaza, Suite 1150 Shintech, Inc.

(979) 233-7861, ext. 398

tandersen@shin-tech.com Plant 1

5618 Hwy

332 East

Freeport

Thomas Andersen

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: Texas Zip Code: 77046

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 575

State: Texas Zip Code: 77541

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER**

Process Unit ID: PL-1

Process Equipment ID: PL1WWSTRIP Wastewater Feed Rate (lb/hr): 26,300 Feed Temperature (°F): 212.45 Feed Inlet Pressure (psia): 25.2 Liquid Loading Rate (liters/m2): 10,320 SteamFeed Rate (lb/hr): 1,530 Steamto Feed Ratio (kg steam/liter of wastewater): 0.06 Operating Temperature (°F): 215.88 Operating Pressure (psig): 0.44 Total Number of Stages: 11 Overall Calculated Tray Efficiency: 0.998 Stripping Factor:

- Flow configuration (countercurrent, cocurrent): Countercurrent Number of Actual Trays: 11 Colum n Height (meters): 10.2

Year Equipm ent Installed: 1984 Equipm ent Currently

Regulated Under (cite regulations): 30 TAC 115.352,30 TAC 115.357, 40 CFR 61 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions**

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

30 TAC 115.352,30 TAC 115.357, 40 CFR 61 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 12,100 liters/hour liters

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

PL-1 LV-5 PL-1 CF-401D PL-1 CF-401E PL-1 CF-401F PL-1 CF-401G PL-1 CF-402D PL-1 CF-402E PL-1 CF-402F PL-1 CF-402G **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream**

Centrifuge water - See Section 2.5 of the report Centrifuge water - See Section 2.5 of the report **PVC Process Wastewater**  **Stream ID**

Centrifuge water - See Section 2.5 of the report

Centrifuge water - See Section 2.5 of the report Centrifuge water - See Section 2.5 of the report Centrifuge water - See Section 2.5 of the report **2**

Centrifuge water - See Section 2.5 of the report Incinerator quench water Centrifuge water - See Section 2.5 of the report

# Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System **1 2**  **3 4**  **5 6** 

**Min** PL-1 PL1WWSTRIP SteamStripping Continuous PL1WWSTRIP 43,200

**Table 3. PVC Process Wastewater Destination Codes Table**

Wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System**
**2 3** 

**Min Ma** **x Ty** **pe of Process Wastewater**  **Treatment System**

**Destination Description PVC Process**  **Wastewater Treatment**  **System ID PVC Process**  **Unit ID PVC Process**  **Wastewater Stream ID**  **Is this**
**process wastewater**  **treatment system batch**  **or continuous operation?** 

**1**

N/A **Process Wastewater Stream Flow Rate (gallons per day)**  **Source of Process Wastewater Stream PVC Process Wastewater Stream Flow Rate** 

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage** 6,900 9,700 8,300 Estimated 365 64,000 99,000 79,000 Estimated 365 64,000 99,000 79,000 Estimated 365 64,000 113,000 93,000 Estimated 365 64,000 113,000 93,000 Estimated 365 61,000 100,000 87,000 Estimated 365 61,000 100,000 87,000 Estimated 365 66,000 113,000 95,000 Estimated 365 66,000 113,000 95,000 Estimated 365 **Operating Days Per Year**  **Flow Rate Determination**  **Me thod**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day)**

# 7 **8 9**  **10 11** 

**Ma x**  **Av erage**  89,280 76,752 Measured 365 WWT

**Code**
WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System**
**4 5**  **6 7** 

**Av erage**  **PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **Operating Days Per Year** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**Process Wastewater Stream Flow Rate**

**(gallons per day) Flow Rate**  **Determination Me** **thod PVC Process**  **Wastewater Treatment**  **System ID PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Flow Rate**  **Determination Me** **thod**

**Operating Days Per Year** 

# 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

LV-5 Incinerator CF-401D PVC Slurry Centrifuge CF-401E PVC Slurry Centrifuge CF-401F PVC Slurry Centrifuge CF-401G PVC Slurry Centrifuge CF-402D PVC Slurry Centrifuge CF-402E PVC Slurry Centrifuge CF-402F PVC Slurry Centrifuge CF-402G PVC Slurry Centrifuge **Originating PVC Process Equipment Description**  **Originating PVC Process Equipment ID** 

# 12 **13**

Plant 1 W astewater Treatment Yes

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recycled **As sociated Destination**  **Information**

(Refer to Table 3 below) **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

# 11 **12**

WWT Plant 1 W astewater Treatment WWT Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment RECYC Plant 1 W astewater Treatment **PVC Process Wastewater Stream Destination Code** 

(Refer to Table 3 below) **As sociated Destination Information** 

# 14

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

The Min, Max and Average are calculated from the 31 day campaign.

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

# 13

Yes Yes Yes Yes Yes Yes Yes Yes Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination?**

# If your response in Column 3 is "Other" then please provide a description of the process wastewaetr

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

107211 Ethylene glycol SW-846-8015C 4 Non-detect 4 Non-detect 67561 Methanol SW-846-8015C 47 51 75070 Acetaldehyde SW-846-8315A 4.59 J 4.62 50000 Formaldehyde SW-846-8315A 0.075 Non-detect R 0.15 Non-detect 51285 2,4-dinitrophenol SW-846-8270D 0.175 Non-detect UJ 0.175 Non-detect UJ 98862 Acetophenone SW-846-8270D 2.52 J 4.11 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.125 Non-detect 0.125 Non-detect 123319 Hydroquinone SW-846-8270D 0.25 Non-detect 0.25 Non-detect 108952 Phenol SW-846-8270D 0.025 Non-detect 0.025 Non-detect 79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 106990 1,3-butadiene SW-846-8260B 0.002 Non-detect 0.002 Non-detect 540841 2,2,4-trimethylpentane SW-846-8260B 0.001 J 0.001 Non-detect 71432 Benzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 108907 Chlorobenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 67663 Chloroform SW-846-8260B 0.001 Non-detect 0.001 Non-detect 126998 Chloroprene SW-846-8260B 0.002 Non-detect 0.002 Non-detect 98828 Cumene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.002 J 0.002 J 100414 Ethylbenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.054 0.056 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 74873 Methyl chloride (Chloromethane) SW-846-8260B 0.011 J 0.012 75092 Methylene chloride SW-846-8260B 0.001 Non-detect 0.001 Non-detect 110543 n-Hexane SW-846-8260B 0.001 Non-detect UJ 0.001 Non-detect 108883 Toluene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 79005 1,1,2-Trichloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 108054 Vinyl acetate SW-846-8260B 0.001 Non-detect 0.001 Non-detect 593602 Vinyl bromide SW-846-8260B 0.001 Non-detect 0.001 Non-detect 75014 Vinyl chloride EPA Method 107 0.006 Non-detect 0.006 Non-detect 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.002 Non-detect 0.002 Non-detect 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B 0.098 0.093 **Sample Date -->** Suspension Suspension

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

Refer to Lab Reports

SF-PL-1-2 **1**

215.6 54 01/03/13 **2**

210.4 53

SF-PL-1-1 130030-1 Refer to Lab Reports 01/04/13

130030-4 **Flow Rate Determination Method -->** Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->** 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

4 Non-detect UJ 4 Non-detect UJ 48 44 5.03 4.67 0.15 Non-detect 0.152 J 0.175 Non-detect 0.175 Non-detect 3.79 3.07 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.046 0.058 0.001 Non-detect 0.001 Non-detect 0.01 0.012 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.095 0.086 Suspension Suspension

Refer to Lab Reports

SF-PL-1-3 SF-PL-1-4 **3 4** 

215.2 210.2 58 59.8 01/06/13 01/05/13

Refer to Lab Reports 130030-5 130030-6 Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect UJ 4 Non-detect UJ 22 41 4.36 4.79 0.186 J 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 3.67 4.43 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J 0.003 J 0.001 Non-detect 0.001 Non-detect 0.044 0.06 0.001 Non-detect 0.001 Non-detect 0.009 0.015 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.063 0.097 Suspension Suspension

214.3 56

SF-PL-1-5 SF-PL-1-6 **5**

216 54 **6** 01/07/13 01/08/13

Refer to Lab Reports Refer to Lab Reports 130030-7 130030-8 Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect UJ 56 56 3.68 4.77 0.075 Non-detect 0.15 Non-detect 0.175 Non-detect UJ 0.175 Non-detect UJ 3.28 4.07 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.036 0.05 0.001 Non-detect 0.001 Non-detect 0.014 0.01 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.041 0.059 Suspension Suspension 30 62

SF-PL-1-7 01/09/13 01/10/13 **7 8** 

214 215.4 Refer to Lab Reports Refer to Lab Reports 130030-9 130030-10 SF-PL-1-8 Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect UJ 10 Non-detect UJ 57 59 4.92 4.43 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect UJ 0.175 Non-detect UJ 5.08 2.63 0.25 Non-detect 0.125 Non-detect 0.5 Non-detect 0.25 Non-detect 0.05 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J 0.001 Non-detect 0.001 Non-detect 0.034 0.048 0.001 Non-detect 0.001 Non-detect 0.005 J 0.012 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.052 0.051 Suspension Suspension

Measured Measured 59.9 53.7 01/11/13 01/12/13 **9 10** 

211.6 212.2 Refer to Lab Reports Refer to Lab Reports 130030-11 130030-12 SF-PL-1-9 SF-PL-1-10

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 41 44 4.85 4.53 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect UJ 0.175 Non-detect UJ 2.8 3.47 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 J 0.005 J 0.001 Non-detect 0.001 Non-detect 0.041 0.048 0.001 Non-detect 0.001 Non-detect 0.013 0.013 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.021 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.06 0.07 Suspension Suspension 53 52.5

211.5 Measured Measured 01/13/13 01/14/13 **12 11** 

213.4 Refer to Lab Reports Refer to Lab Reports

SF-PL-1-11 SF-PL-1-12 130030-13 130030-14

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 50 30 4.71 4.98 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 2.47 2.17 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J 0.004 J 0.001 Non-detect 0.001 Non-detect 0.045 0.066 0.001 Non-detect 0.001 Non-detect 0.014 0.018 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.068 0.109 Suspension Suspension 56.2 50

213.1 211.3 Measured Measured 01/15/13 **13 14**  01/16/13

Refer to Lab Reports Refer to Lab Reports

SF-PL-1-13 SF-PL-1-14 130030-16 130030-15

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 56 39 4.51 4.36 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 3.06 2.49 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.048 0.044 0.001 Non-detect 0.001 Non-detect 0.012 0.01 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.076 0.063 Suspension Suspension 60.8

211.46 Measured **15 16**  01/17/13 01/18/13

216 Measured

Refer to Lab Reports Refer to Lab Reports

SF-PL-1-15 130030-17 130030-18 SF-PL-1-16 47.4

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 42 42 5.1 5.04 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 2.35 3.87 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.004 J 0.003 J 0.001 Non-detect 0.001 Non-detect 0.043 0.039 0.001 Non-detect 0.001 Non-detect 0.014 0.012 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.007 0.006 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.064 0.053 Suspension Suspension **17 18**  01/19/13 01/20/13

Measured Measured 215.8 215.4

130030-19 130030-20 SF-PL-1-17 SF-PL-1-18 Refer to Lab Reports Refer to Lab Reports 54 51.8

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 44 60 5.49 7.12 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 3.95 3.8 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 J 0.001 Non-detect 0.004 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.039 J 0.061 0.001 Non-detect 0.001 Non-detect 0.013 0.012 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.055 0.082 Suspension Suspension **19 20**  01/21/13 01/22/13

52 Measured Measured 212.7 211.8 Refer to Lab Reports Refer to Lab Reports 130030-21 130030-24 SF-PL-1-19 SF-PL-1-20 55

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 51 55 5.02 6.24 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.175 Non-detect 3.97 4.28 0.25 Non-detect 0.125 Non-detect 0.5 Non-detect 0.25 Non-detect 0.05 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 J 0.003 J 0.001 Non-detect 0.001 Non-detect 0.055 0.05 0.001 Non-detect 0.001 Non-detect 0.013 0.012 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.056 0.053 Suspension Suspension **21** 01/23/13 01/24/13

215.8 Measured Measured 212

130209-1 Refer to Lab Reports Refer to Lab Reports 53 60

SF-PL-1-21 SF-PL-1-22 130209-2 **22**

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 39 34 6.11 5.13 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 4.66 2.88 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.048 0.045 0.001 Non-detect 0.001 Non-detect 0.009 0.009 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.063 0.056 Suspension Suspension

Measured 215.6 Refer to Lab Reports Refer to Lab Reports 130209-4 52.2

SF-PL-1-23 SF-PL-1-24 130209-3 48.8 01/26/13 01/25/13 **23 24** 

215.1 Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 40 38 4.78 4.5 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 2.3 3.29 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.045 0.041 0.001 Non-detect 0.001 Non-detect 0.006 0.008 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.053 0.048 Suspension Suspension

215.2 **26**

Refer to Lab Reports 130209-5 01/28/13

SF-PL-1-25 48.1 01/27/13 **25**

Measured 50.4

211.5

SF-PL-1-26 Refer to Lab Reports 130209-6 Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 44 40 4.69 4.54 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 4.79 2.43 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 J 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.045 0.043 0.001 Non-detect 0.001 Non-detect 0.007 0.007 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.009 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.052 0.056 Suspension Suspension **27 28**  01/29/13 01/30/13

53.9 51.2

211.8 214.9

SF-PL-1-27 SF-PL-1-28 Refer to Lab Reports Refer to Lab Reports 130209-7 130209-8 Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 40 37 4.76 4.76 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 3.14 3.49 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 J 0.002 J 0.001 Non-detect 0.001 Non-detect 0.044 0.051 0.001 Non-detect 0.001 Non-detect 0.006 0.01 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.006 Non-detect J 0.006 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.064 0.06 Suspension Suspension

Refer to Lab Reports 130209-9 130209-10 Measured

SF-PL-1-29 SF-PL-1-30 **29 30**  01/31/13 02/01/13

56.5 53.2

213.3 213.1 Refer to Lab Reports Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech, Inc. **Facility** Plant 1 **PVC Process Wastewater Treatment System ID** PL1WWSTRIP

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->** 

**Flow Rate Determination Method -->**

Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)** 

6.29 0.419 J **31** 02/02/13 Suspension 52 Measured 212

130209-11 SF-PL-1-31