# www.dep.state.fl.us 

# F LORIDA 

# D EPARTMENT OF



# E NVIRONMENTAL 

# P ROTECTION

NORTHEAST DISTRICT

8800 BAYMEADOWS WAY WEST, SUITE 100

JACKSONVILLE, FLORIDA 32256 RICK SCOTT

GOVERNOR

HERSCHEL T. VINYARD JR.

SECRETARY



# March 18, 2013

In the Matter of an

Application for Permit by:

Mr. Terry Baker, General Manage r File Number FL0000655-006-IW1S

PCS Phosphate - White Springs Hamilton County

Post Office Box 300 PCS Phosphate - White Springs

White Springs, Florida 32096

NOTICE OF PERMIT REVISION

Enclosed is a permit revision for Permit Number FL0000655, issued under Chapter 403, Florida Statutes.

The revision includes a modification of groundwater sections III.B.2.(b) and III.B.5 of the permit in

accordance with requirements of Consent Order 10-1878. All other conditions of the permit remain in

effect. Monitoring requirements unde r this revision is effective in July 2013. Until such time, the

permittee shall continue to monitor and report in accordance with previously effective permit

requirements, if any.

The Department's proposed agency action shall become final unless a timely petition for an administrative

hearing is filed under Sections 120. 569 and 120.57, Florida Statutes, with in fourteen days of receipt of

notice. The procedures for petitioning for a hearing are set forth below.

A person whose substantial interests are affected by the Department's proposed permitting decision may

petition for an administrative proceeding (hearing) u nder Sections 120.569 and 120. 57, Florida Statutes.

The petition must contain the information set forth below and must be filed (received by the Clerk) in the

Office of General Counsel of the Department at 3900 Commonwealth Boulevard, Mail Station 35,

Tallahassee, Florida 32399-3000.

Under Rule 62-110.106(4), Florida Administrative Code , a person may request an extension of the time

for filing a petition for an administrative hearing. The request must be filed (received by the Clerk) in the

Office of General Counsel before the end of the time period for filing a petition for an administrative

hearing.

Petitions by the applicant or any of the persons listed be low must be filed within fourteen days of receipt

of this written notice. Petitions filed by any pe rsons other than those entitled to written notice under

Section 120.60(3), Florida Statutes, must be filed with in fourteen days of publication of the notice or

within fourteen days of receipt of the written notice, whichever occurs first. Section 120.60(3), Florida

Statutes, however, also allows that any person who h as asked the Department for notice of agency action

may file a petition within fourteen days of receipt of such notice, regardless of the date of publication.

The petitioner shall mail a copy of the petition to the applicant at the address indicated above at the time

of filing. The failure of any pers on to file a petition or request for an extension of time within fourteen

days of receipt of notice shall constitute a waiver of that person's right to request an administrative

# PCS Phosphate – White Springs

FL0000655-006

Page 2 of 3

determination (hearing) under Sections 120.569 an d 120.57, Florida Statutes. Any subsequent

intervention (in a proceeding initiated by another part y) will be only at the discretion of the presiding

officer upon the filing of a motion in compliance with Rule 28-106.205, Florida Administrative Code.

A petition that disputes the material facts on which th e Department's action is based must contain the

following information, as indicated in Rule 28-106.201, Florida Administrative Code:

(a) The name and address of each agency affected and ea ch agency's file or identification number, if

known;

(b) The name, address, and telephone number of the petitioner; the name, address, and telephone

number of the petitioner's representative, if any, which shall be the address for service purposes

during the course of the proceeding; and an e xplanation of how the petitioner's substantial

interests will be affected by the determination;

(c) A statement of when and how the petitioner r eceived notice of the Department's decision;

(d) A statement of all disputed issues of material f act. If there are none, the petition must so indicate;

(e) A concise statement of the ultimate facts alleged, including the specific facts the petitioner

contends warrant reversal or modificati on of the Department's proposed action;

(f) A statement of the specific rules or statutes the petitioner contends require reversal or

modification of the Department's proposed action; and

(g) A statement of the relief sought by the petitioner, stating precisely the action petitioner wishes the

Department to take with respect to the Department's proposed action.

Because the administrative hearing process is designed to formulate final agency action, the filing of a

petition means that the Department's final action may be different from the position taken by it in this

notice. Persons whose substantial interests will be af fected by any such final decision of the Department

have the right to petition to become a party to th e proceeding, in accordance with the requirements set

forth above.

In addition to requesting an administrative hearing, any petitioner may elect to pursue mediation. The

election may be accomplished by filing with the Departme nt a mediation agreement with all parties to the

proceeding (i.e., the applicant, the Department, a nd any person who has filed a timely and sufficient

petition for a hearing). The agreement must contai n all the information required by Rule 28-106.404,

Florida Administrative Code. The agreement must be received by the Clerk in the Office of General

Counsel of the Department at 3900 Commonwealth Boulevard, Mail Station 35, Tallahassee, Florida

32399-3000, within ten days after the deadline fo r filing a petition, as set forth above. Choosing

mediation will not adversely affect the right to a hearing if mediation does not result in a settlement.

As provided in Section 120.573, Florida Statutes, the timely agreement of all parties to mediate will toll

the time limitations imposed by Sections 120.569 and 120.57, Florida Statutes, for holding an

administrative hearing and issuing a final order. Un less otherwise agreed by the parties, the mediation

must be concluded within sixty days of the execution of the agreement. If mediation results in settlement

of the administrative dispute, the Department must en ter a final order incorporating the agreement of the

parties. Persons seeking to protect their substantial in terests that would be affected by such a modified

final decision must file their petitions within fourteen days of receipt of this notice, or they shall be

deemed to have waived their right to a proceeding under Sections 120.569 and 120.57, Florida Statutes.

If mediation terminates without settlement of the disput e, the Department shall notify all parties in writing

that the administrative hearing processes under Sections 120.569 and 120.57, Florida Statutes, remain

available for disposition of the dispute, and the noti ce will specify the deadlines that then will apply for

challenging the agency action and electing remedies under those two statutes.

# PCS Phosphate – White Springs

FL0000655-006

Page 3 of 3

This permit action is final and eff ective on the date filed with the Clerk of the Department unless a petition

(or request for an extension of time) is filed in accordance with the above. Upon the timely filing of a

petition (or request for an extension of time), this pe rmit will not be effective until further order of the

Department.

Any party to this permit has the right to seek judi cial review of the permit action under Section 120.68,

Florida Statutes, by the filing of a notice of appeal under Rules 9.110 and 9.190, Florida Rules of Appellate

Procedure, with the Clerk of the Department in the Office of General Counsel, 3900 Commonwealth

Boulevard, Mail Station 35, Tallahassee, Florida, 32399- 3000, and by filing a copy of the notice of appeal

accompanied by the applicable filing fees with the appropria te district court of appeal. The notice of appeal

must be filed within 30 days from the date when this permit action is filed with the Clerk of the

Department.

Executed in Jacksonville, Florida.

STATE OF FLORIDA DEPARTMENT

OF ENVIRONMENTAL PROTECTION

Melissa M. Long, P.E.

Program Administrator

Water and Environmental Resource Permitting

FILING AND ACKNOWLEDGMENT

FILED, on this March 18, 2013, under Section 120.52 , Florida Statutes, with the designated Deputy

Clerk, receipt of which is hereby acknowledged.

March 18, 2013

[ Clerk] [Date]

CERTIFICATE OF SERVICE

The undersigned hereby certifies that this NOTIC E OF PERMIT REVISION and all copies were mailed

before the close of business on March 18, 2013 to the listed persons.

March 18, 2013

Name Date

Enclosure

Copies furnished to:

Bill White, PCS Phosphate

Elsa Potts, P.E., FDEP

# www.dep.state.fl.us 

# F LORIDA 

# D EPARTMENT OF



# E NVIRONMENTAL 

# P ROTECTION

NORTHEAST DISTRICT

8800 BAYMEADOWS WAY WEST, SUITE 100

JACKSONVILLE, FLORIDA 32256 RICK SCOTT

GOVERNOR

HERSCHEL T. VINYARD JR.

SECRETARY



# STATE OF FLORIDA

INDUSTRIAL WASTEWATER FACILITY PERMIT

PERMITTEE: PERMIT NUMBER: FL0000655 (Major)

PA FILE NUMBER: FL0000655 – 006 – IW1S

PCS Phosphate - White Springs ISSUANCE DATE: January 8, 2010 (004/NR)

Post Office Box 300 EXPIRATION DATE: January 7, 2015

White Springs, Florida 32096 1 st 

# REVISION DATE: March 31, 2011 (005/MM)

2 nd 

# REVISION DATE: March 18, 2013 (006/RM)

RESPONSIBLE AUTHORITY:

Mr. Terry Baker

General Manager

FACILITY:

PCS Phosphate - White Springs

County Road 137

North of White Springs

White Springs, Florida 32096

Hamilton County

Latitude: 30° 24’ 40” N Longitude: 82° 46’ 57” W

This permit is issued under the provisions of Chapter 403, Florida Statutes (F.S.) and applicable rules of

the Florida Administrative Code (F.A.C.), and constitutes authorization to discharge to waters of the state

under the National Pollutant Discharge Elimination System (NPDES). The above named permittee is

hereby authorized to operate the facilities in acco rdance with the document s attached hereto and

specifically described as follows:

Operation renewal is authorized for an existi ng 27.8 MGD (Suwannee River Facility) and 26.9 MGD

(Swift Creek Facility) discharge consisting of treated process wastewater, contaminated non-process

wastewater (CNPW), sanitary wastewater, storm water, clay settling areas, and the phosphogypsum stack

systems. These permits (FL0000655 and FL0036226) are being combined.

Wastewater is generated from open- pit mining of phosphate rock, beneficiation of the rock in the mining

areas, manufacture of sulfuric acid and phosphoric aci d, production of fertilizer components and animalfeed supplements, storm water runoff, clay se ttling areas, and the phosphogypsum stack systems.

WASTEWATER TREATMENT:

Treatment consists of pH adjustme nt and chemical precipitation when required using lime and other water

treatment aids such as flocculants and shading agen ts (as approved by DEP), settling/sedimentation, and

adsorption/absorption on mining waste clay particles in clay settling areas.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

2 

# Final discharge to surface waters of the state o ccurs at outfalls D-001 (Swift Creek), D-002 (Hunter

Creek), D-003 (Roaring Creek) and D-004(Camp Branch ) class III fresh surface waters of the state.

Discharge of the above described wastewater to gr ound waters of the state occurs within clay settling

areas and on-site retention/treatment ponds.

Approximately 8 MGD of contaminated non-pro cess wastewater (CNPW) from Suwannee River

Chemical is diverted via internal outfall I-S03 to th e Swift Creek Mine clay settling areas and the Altman

Bay retention pond as part of the Nutrient Removal Sy stem (NRS), which then ultimately discharges via

outfall D-001.

Hamilton County landfill leachate is sent to the To wn of White Springs WWTF. The Town of White

Springs WWTF effluent is discharged to the clay settling area. This permit combines the previous

NPDES permits FL000655 (PCS Suwannee) and FL0036226 (PCS Swift Creek).

Permit Revision 006/RM

Groundwater section 

# III.B.2.(b) and III.B.5 has been revised and added to the permit in accordance with

requirements of Consent Order 10-1878. This secti on describes new monitoring well locations that the

facility will begin monitoring in the third quarter of 2013. The zone of discharge for the facility has also

been more clearly defined.

EFFLUENT DISPOSAL:

Surface Water Discharge:

An existing 20.6 MGD average daily flow (ADF) discharge to Swift Creek (Class III Fresh waters –

WBID 3375 Upper Suwannee Swift Creek), D-001. Th e point of discharge is located approximately

at latitude 30  22' 35" N, longitude 82  47' 57" W.

An existing 7.2 MGD average flow to Hunter Creek (Class III Fresh waters – WBID 3364 Upper

Suwannee Hunter Creek), D-002. The point of di scharge is located approximately at latitude 30  29'

08" N, longitude 82  42' 43" W.

A new discharge to Roaring Creek (Class III Fr esh waters – WBID 3392 Upper Suwannee Roaring

Creek), D-003. The point of discharge is located approximately at latitude 30  26' 32" N, longitude

82  40' 15" W.

An existing discharge to Camp Branch (Class III Fresh waters - WBID 3423 Upper Suwannee Camp

Branch), D-004. The point of discharge is located approximately at latitude 30  23' 11" N, longitude

82  52' 08" W.

Land Application:

Continued ground water monitoring is required for the discharge to ground waters of the state that

occurs from the land application of wastewater in the clay settling areas, retention/treatment ponds,

mining and reclamation areas, spray irrigation and wetlands system project, and phosphogypsum

stack systems including the cooling ponds and process wastewater management systems.

Operation and maintenance of these systems will be in compliance with the appl icable provisions of FAC

62-672 and 62-673.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

3 

# Internal Outfalls (see attachment A – PCS Water Circulation Diagram):

This permit authorizes discharge from the following existing internal outfalls :

a. I-S02 to Swift Creek through I-S04 via D-001,

b. I-S03 to clay settling areas and the Altman Bay retention pond,

c. I-S04 to Swift Creek via D-001,

d. I-S06 to Swift Creek through I-S04 via D-001,

e. I-S07 to Swift Creek through I-S04 via D-001,

f. I-S22 to Eagle Lake,

g. I-S28 to retention pond at Swift Creek Chemical Complex,

h. I-C41 to Camp Branch through D-004,

i. I-S08 to spray field irrigation system, flow of treated process water from large pond

normally to SRM SA 9 or to SCM SA 11 (if dredging/pumping)

j. I-S09 to Swift Creek through I-S04 via D-001, and

k. I-S18 to Swift Creek via D-001.

Permit Revision 005/MM

Corrects and revised Table I.A.12 to indicate that the pH monitoring for internal outfall locations

OUI-8, OUI-11, OUI-12 and OUI-13 should be grab samples and report only.

IN ACCORDANCE WITH: The limitations, monitoring requirements and other conditions as set forth

in Part I through Part VIII on pa ges 3 through 46 of this permit.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

4 

# I. Effluent Limitations and Monitoring Requirements

A. Surface Water Discharges

1. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge fro m Outfall D-001. Such discharge shall be limited

and monitored by the permittee as specified below and reported in accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Daily Calculated EFF-1

Oxygen,

Dissolved (DO)

(MG/L) Report -- 5.0 Weekly In-situ, midstream and

mid-depth EFF-1

Solids, Total

Suspended

(MG/L) Report Report -- Weekly 24-hr. time

proportional

composite EFF-1

Fluoride, Total

(as F) (MG/L) Report 10.0 -- Weekly 24-hr. time

proportional

composite EFF-1

Specific

Conductance

(UMHO/CM) Report 1275 -- Weekly 24-hr. time

proportional

composite EFF-1

Temperature

(oC), Water Report Report -- Weekly Grab or Insitu EFF-1

pH (SU) -- 8.5 6.0 Weekly Grab or Insitu EFF-1

Turbidity (NTU) Report 31.0

See Permit

Condition

I.A.32 -- Weekly Grab EFF-1

Nitrogen,

Ammonia, Total

(as N) (MG/L) Report Report -- Weekly 24-hr. time

proportional

composite EFF-1

Ammonia,

Unionized (as

NH3) (MG/L) Report 0.02 -- Weekly Calculated EFF-1

Nitrogen,

Kjeldahl, Total

(as N) (MG/L) Report Report -- Weekly 24-hr. time

proportional

composite EFF-1

Nitrogen, Total

(MG/L) Report Report -- Weekly 24-hr. time

proportional

composite EFF-1

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

5 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Nitrogen, Total

(LBS/DAY) Report -- -- Weekly Calculated EFF-1

Phosphorus,

Total

(as P) (MG/L) Report Report -- Weekly 24-hr. time

proportional

composite EFF-1

Phosphorus,

Total

(as P)

(LBS/DAY) Report -- -- Weekly Calculated EFF-1

Radium 226 +

Radium 228,

Total (PCI/L) -- 5.0 -- Quarterly 24-hr. time

proportional

composite EFF-1

Alpha, Gross

Particle Activity

(PCI/L) 1 

# -- 15.0 -- Quarterly 24-hr. time

proportional

composite EFF-1

Chronic Whole

Effluent Toxicity,

7-Day IC25

(Ceriodaphnia

dubia) 100

See Permit

Condition

I.A.3 Quarterly 24-hr. time

proportional

composite EFF-1

Chronic Whole

Effluent Toxicity,

7-Day IC25

(Pimephales

promelas) 100

See Permit

Condition

I.A.3 Quarterly 24-hr. time

proportional

composite EFF-1

Biological

Integrity See Permit Condition I.A.31 Quarterly -- EFF-1

2. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.1 and as

described below:

Sample Point Description of Monitoring Location

EFF-1 Swift Creek Surface Water Location

3. The permittee shall comply with th e following requirements to evaluate chronic whole effluent

toxicity of the discharge from outfall D-001.

1 

# The Permittee shall firs t analyze for gross alpha particle including radium 226 but excluding radon and uranium. If the gross alpha particle

activity exceeds 5 pCi/L, the Permittee will be required to analyz e an aliquot of the same sample for the Radium 226 and 228, a nd shall be

reported on the subsequent month's Discharg e Monitoring Report (DMR). If the gross alpha particle activity does not exceed 5 p Ci/L,

compliance with the combined radium 226 and 228 limit will be deemed to have been achieved.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

6 

# a. Effluent Limitation

(1) In any routine or additional follow-up test for chronic whole effluent toxicity, the 25 percent

inhibition concentration (IC 25 

# ) shall not be less than 100% effluent. [Rules 62-302.530(61)

and 62-4.241(1)(b), F.A.C.]

(2) For acute whole effluent toxicity, the 96-hour LC50 shall not be less than 100% effluent in

any test. [Rule 62-302.500(1)(a)4 . and 62-4.241(1)(a), F.A.C.]

b. Monitoring Frequency

(1) Routine toxicity tests shall be conducted once every three months, the first starting three

months from previous test and lasting for the duration of this permit.

(2) Upon completion of four consecutive, valid routine tests that demonstrate compliance with

the effluent limitation in 3.a.(1) above, the permittee may submit a written request to the

Department for a reduction in monitoring freque ncy to once every six months. The request

shall include a summary of the data and the comp lete bioassay laboratory reports for each test

used to demonstrate compliance. The Department shall act on the request within 45 days of

receipt. Reductions in monitoring shall only b ecome effective upon the Department’s written

confirmation that the facility has completed four consecutive valid routine tests that

demonstrate compliance with the effl uent limitation in 3.a.(1) above.

(3) If a test within the sequence of the four is deemed invalid based on the acceptance criteria in

EPA-821-R-02-013, but is replaced by a repeat valid test initiated within 21 days after the last

day of the invalid test, the invalid test will not be counted against the requirement for four

consecutive valid tests for the purpose of eval uating the reduction of monitoring frequency.

c. Sampling Requirements

(1) For each routine test or additional follow-up test conducted, a total of three 24-hour composite

or grab samples of final effluent shall be co llected and used in accordance with the sampling

protocol discussed in EPA-821-R-02-013, Section 8.

(2) The first sample shall be used to initiate the test. The remaining two samples shall be

collected according to the protocol and used as renewal solutions on Day 3 (48 hours) and

Day 5 (96 hours) of the test.

(3) Samples for routine and additional follow-up tests shall not be collected on the same day.

d. Test Requirements

(1) Routine Tests: All routine tests shall be conducted using a control (0% effluent) and a

minimum of five test dilutions: 100%

, 50%

, 25%

, 12.5%, and 6.25% final effluent.

(2) The permittee shall conduct a daphnid, Ceriodaphnia dubia , Survival and Reproduction Test

and a fathead minnow, Pimephales promelas , Larval Survival and Growth Test,

concurrently.

(3) All test species, procedures and quality assuran ce criteria used shall be in accordance with

Short-term Methods for Estimating the Chronic Toxicity of Effluents and Receiving Waters

to Freshwater Organisms , 4th ed., EPA-821-R-02-013. Any deviation of the bioassay

procedures outlined herein shall be submitted in writing to the Department for review and

approval prior to use. In the event the above method is revised, the permittee shall conduct

chronic toxicity testing in accordance with the revised method.

(4) The control water and dilution water shall be moderately hard water as described in EPA821-R-02-013, Section 7.

e. Quality Assurance Requirements

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

7 

# (1) A standard reference toxicant (SRT) quality assurance (QA) chronic toxicity test shall be

conducted with each species used in the required to xicity tests either concurrently or initiated

no more than 30 days before the date of each r outine or additional follow-up test conducted.

Additionally, the SRT test must be conducted c oncurrently if the test organisms are obtained

from outside the test laboratory unless the test organism supplier provides control chart data

from at least the last five monthly chronic toxi city tests using the same reference toxicant and

test conditions. If the organism supplier pr ovides the required SRT data, the organism

supplier’s SRT data and the test laboratory’s monthly SRT-QA data shall be included in the

reports for each companion routine or additional follow- up test required.

(2) If the mortality in the control (0% effluent) exceeds 20% for either species in any test or does

not meet test acceptability criteria, the test fo r that species (including the control) shall be

invalidated and the test repeated. Test acceptab ility criteria for each species are defined in

EPA-821-R-02-013, Section 13.12 ( Ceriodaphnia dubia ) and Section 11.11 ( Pimephales

promelas ). The repeat test shall begin within 21 da ys after the last day of the invalid test.

(3) If 100% mortality occurs in all effluent concen trations prior to the end of any test and the

control mortality is less than 20% at that ti me, the test (including the control) shall be

terminated with the conclusion that the test fails and constitutes non-compliance.

(4) Routine and additional follow-up tests sha ll be evaluated for acceptability based on the

observed dose-response relationship as required by EPA-821-R-02-013, Section 10.2.6., and

the evaluation shall be included with the bioassay laboratory reports.

f. Reporting Requirements

(1) Results from all required Routine and Add itional Follow-up tests shall be reported on the

Discharge Monitoring Report (DMR) as the calculated IC 25 

# for each test species.

(2) A bioassay laboratory report for each routine test shall be prepared according to EPA-821-R02-013, Section 10, Report Preparation and Test Review, and e-mailed or mailed to the

Department at the address below within 30 days after the last day of the test.

(3) For additional follow-up tests, a single bioassay laboratory report shall be prepared according

to EPA-821-R-02-013, Section 10, and e -mailed or mailed within 30 days after the last day of

the second valid additional follow-up test.

(4) Data for invalid tests shall be included in the bioassay laboratory report for the repeat test.

(5) The same bioassay data shall not be repo rted as the results of more than one test.

(6) All bioassay laboratory reports shall be e-mailed or mailed to Jacksonville :

Florida Department of Environmental Protection

Northeast District - Wastewater Section

8800 Baymeadows Way West, Suite 100

Jacksonville, Florida 32256

g. Test Failures

(1) A test fails when the test results do not meet the limits in 3.a.(1).

(2) Additional Follow-up Tests:

(a) If a routine test does not meet the chr onic toxicity limitation in 3.a.(1) above, the

permittee shall notify the Department at the a ddress above within 21 days after the last

day of the failed routine test and conduct tw o additional follow-up tests on each species

that failed the test in accordance with 3.d.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

8 

# (b) The first test shall be initiated within 28 days after the last day of the failed routine test.

The remaining additional follow-up tests sh all be conducted weekly thereafter until a

total of two valid additional follow-up tests are completed.

(c) The additional follow-up tests shall be c onducted using a control and a minimum of five

dilutions: 100%, 50%, 25%, 12.5%, and 6.25% effluent, OR the permittee may modify

the dilution series in the add itional follow-up tests to more accurately bracket the toxicity

such that at least two dilutions above and two dilutions below the target concentration

and a control are run. All test results sha ll be statistically analyzed according to the

Appendices in EPA-821-R-02-013.

(3) In the event of three valid test failures (whether routine or additional follow-up tests) at a

single sampling location within a 12-month period, the permittee shall notify the Department

within 21 days after the last day of the third test failure.

(a) The permittee shall consult with the Department and submit a plan for correction of the

effluent toxicity within 60 days after the last day of the third test failure.

(b) The Department shall review and approve the plan before initiation.

(c) The plan shall be initiated within 30 days following the Department’s written approval of

the plan.

(d) Progress reports shall be submitted quarterly to the Department at the address above.

(e) During the implementation of the plan, th e permittee shall conduct quarterly routine

whole effluent toxicity tests in accordance w ith 3.d. Additional follow-up tests are not

required while the plan is in progress. Follo wing completion or termination of the plan,

the frequency of monitoring for routine and a dditional follow-up tests shall return to the

schedule established in 3.b.(1). If a routine test is invalid according to the acceptance

criteria in EPA-821-R-02-013, a repeat test shall be initiated within 21 days after the last

day of the invalid routine test.

(f) Upon completion of four consecutive, valid routine tests that demonstrate compliance

with the effluent limitation in 3.a.(1) above , the permittee may submit a written request to

the Department to terminate the plan. The plan shall be terminated upon written

verification by the Department that the fac ility has passed at least four consecutive valid

routine whole effluent toxicity tests.

(g) If a test within the sequence of the four is deemed invalid, but is replaced by a repeat

valid test initiated within 21 days after the last day of the invalid test, the invalid test will

not be counted against the requirement for f our consecutive valid tests for the purpose of

terminating the plan.

(4) If chronic toxicity test results indicate gr eater than 50% mortality within 96 hours in an

effluent concentration equal to or less than th e effluent concentration specified as the acute

toxicity limit in 3.a.(2), the Department may revise this permit to require acute definitive

whole effluent toxicity testing.

(5) The additional follow-up testing and the pl an do not preclude the Department taking

enforcement action for acute or chronic whol e effluent toxicity test failures.

4. During the period beginning on the issuance date and lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S02 (previously known as 001-

2) to Swift Creek through I-S04 via D-001and from Internal Outfall I-S03 (previously known as 001-

2a) to clay settling areas and the Altman Bay reten tion pond. Such discharge shall be limited and

monitored by the permittee as specified below a nd reported in accordance with condition I.E.3.:

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

9 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Continuous Meter OUI02,

OUI-03

Fluoride, Total

(as F) (MG/L) 25.0 75.0 -- 2 days/week 24-hour time

proportioned

composite OUI02,

OUI-03

Phosphorus,

Total

(as P) (MG/L) 35.0 105.0 -- 2 days/week 24-hour time

proportioned

composite OUI02,

OUI-03

pH (SU) -- 9.5 6.0 2 days/week Grab OUI02,

OUI-03

Nitrogen, Total

(MG/L) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI02,

OUI-03

Nitrogen, Total

(LBS/DAY) Report -- 2 days/week Calculated OUI02,

OUI-03

5. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.4 and as

described below:

Sample Point Description of Monitoring Location

OUI-02 Altman Bay Canal to Swift Creek

OUI-03 Discharge from the pumps to the Swift Creek mine clay settling areas

and Altman Bay retention pond.

6. During the period beginning on the issuance date and lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S04 (Previously known as

001-4) to Swift Creek via D-001. Such discharge sh all be limited and monitored by the permittee as

specified below and reported in accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Weekly Calculate OUI-04

Nitrogen,

Ammonia, Total

(as N) (MG/L) 4.0 -- -- Weekly Grab OUI-04

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

10 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Ammonia,

Unionized (as

NH3) (MG/L) Report 0.02 -- Weekly Calculated OUI-04

Oxygen,

Dissolved (DO)

(MG/L) Report -- 5.0 Weekly Grab or

In-situ OUI-04

Temperature

(oC), Water

(DEG.C) Report Report -- Weekly Grab or

In-situ OUI-04

pH (SU) -- 8.5 6.0 Weekly Grab or

In-situ OUI-04

7. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.8 and as

described below:

Sample Point Description of Monitoring Location

OUI-04 Sampling location downstream of va rious Lake discharge but prior to

mixing with OUI-18 (Eagle Lake Outfall)

8. During the period beginning on the issuance date and lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S06 (previously known as 001-

6) to Swift Creek through I-S04 to D-001. Such discharge shall be limited and monitored by the

permittee as specified below and reporte d in accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Continuous Meter OUI-06

Solids, Total

Suspended

(MG/L) 50.0 150.0 -- 2 days/week 24-hour time

proportioned

composite OUI-06

Phosphorus,

Total

(as P) (MG/L) 35.0 105.0 -- 2 days/week 24-hour time

proportioned

composite OUI-06

pH (SU) -- 9.5 6.0 2 days/week Grab or Insitu OUI-06

Turbidity (NTU) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI-06

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

11 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Fluoride, Total

(as F) (MG/L) 25.0 75.0 -- 2 days/week 24-hour time

proportioned

composite OUI-06

9. Effluent samples shall be taken at the monitoring s ite locations listed in permit condition I.A.10 and

as described below:

Sample Point Description of Monitoring Location

OUI-06 Discharge from Altman Bay Lake Retention Pond

10. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S07 and I-S09 (previously

known as 001-7 and 001-9 respectively) to Swift Creek through I-S04 via D-001. Such discharge

shall be limited and monitored by the permittee as specified below and reported in accordance with

condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sampl

e Point

Flow (MGD) Report Report -- 4 days/week Calculated OUI07,

OUI-09

Total NonVolatile NonFilterable

Residue (MG/L) 12 25 -- 2 days/week 24-hour time

proportioned

composite OUI07,

OUI-09

Solids, Total

Suspended

(MG/L) 30.0 60.0 -- 2 days/week 24-hour time

proportioned

composite OUI07,

OUI-09

Phosphorus,

Total

(as P) (MG/L) 3.0 5.0 -- 2 days/week 24-hour time

proportioned

composite OUI07,

OUI-09

Turbidity (NTU) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI07,

OUI-09

pH (SU) -- 9.0 6.0 2 days/week Grab or Insitu OUI07,

OUI-09

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

12 

# 11. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.12 and

as described below:

Sample Point Description of Monitoring Location

OUI-07 Discharge from South Altman Bay Lake

OUI-09 Discharge from Purvis Lake that does not go through South Altman

Bay Lake and discharge from Clay Settling Areas

12. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S08 (previously known as

001-8F) to the spray irrigation and wetlands land ap plication project, clay settling areas, mining and

reclamation areas. Such discharge shall be limited and monitored by the permittee as specified

below and reported in accord ance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

See Note a below

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Continuous

or Calculated Meter OUI-8,

OUI-11,

OUI-12*,

OUI-13*

Solids, Total

Suspended

(MG/L) Report Report -- 2 days/week Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Turbidity (NTU) Report Report -- 2 days/week Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Phosphorus,

Total

(as P) (MG/L) Report Report -- 2 days/week Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Phosphorus,

Total

(as P)

(LBS/DAY) Report

(Annual

Average) -- -- 2 days/week Calculated OUI-8,

OUI-11,

OUI-12,

OUI-13

Nitrogen,

Ammonia, Total

(as N) (MG/L) Report Report -- Weekly Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

13 

# Discharge Limitations Monitoring Requirements

See Note a below

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Nitrogen, Total

(MG/L) Report Report -- Weekly Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Nitrogen, Total

(LBS/DAY) Report

(Annual

Average) -- -- Weekly Calculated OUI-8,

OUI-11,

OUI-12,

OUI-13

pH (SU) -- Report Report Weekly Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Fluoride, Total

(as F) (MG/L) Report Report -- Weekly Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Specific

Conductance

(UMHO/CM) Report Report -- Weekly Grab OUI-8,

OUI-11,

OUI-12,

OUI-13

Note a: Sampling will not be required during maintena nce periods when the lime slurry is pumped to the

clay settling areas for recovery of retention volume . Total Nitrogen and tota l Phosphorous loading in

lbs/day is a calculated value based on the w eekly grab sample and the corresponding flow.

Note *: Flows for OUI-12 and OUI-13 are calcula ted from open channel ditch two times per week.

13. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.14 and

as described below:

Sample Point Description of Monitoring Location

OUI-8 Discharges associated with the spray irrigation and wetlands land

application project, clay settling ar eas, mining and reclamation areas;

treated process wastewater sent to storage areas.

OUI-11 Discharges associated with outflow from the spray irrigation and

wetlands land application project, clay settling areas, mining and

reclamation areas; water delivered to the spray irrigation system.

OUI-12 Discharges associated with outflow from the spray irrigation and

wetlands land application project, clay settling areas, mining and

reclamation areas; flow from the spray irrigation system at the

connection between CSA 4 and CSA 8.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

14 

# Sample Point Description of Monitoring Location

OUI-13 Discharges associated with outflow from the spray irrigation and

wetlands land application project, clay settling areas, mining and

reclamation areas; flow from the spray irrigation system at the

connection between CSA 8 and CSA 11.

14. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S18 (previously known as

001-18) to Swift Creek via D-001. Such discharge shall be limited and monitored by the permittee

as specified below and reported in accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Continuous Meter OUI-18

Total NonVolatile NonFilterable

Residue (MG/L) 12 25 -- 2 days/week Grab OUI-18

Solids, Total

Suspended

(MG/L) 30 60 -- 2 days/week Grab OUI-18

Nitrogen,

Ammonia, Total

(as N) (MG/L) Report 4.0 -- 2 days/week Grab OUI-18

Ammonia,

Unionized (as

NH3) (MG/L) Report 0.02 -- 2 days/week Calculated OUI-18

Oxygen,

Dissolved (DO)

(MG/L) -- -- 5.0 2 days/week Grab or Insitu OUI-18

Temperature

(oC), Water

(DEG.C) Report Report -- 2 days/week Grab or Insitu OUI-18

Phosphorus,

Total

(as P) (MG/L) 3.0 5.0 -- 2 days/week Grab OUI-18

Nitrogen, Total

(MG/L) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI-18

Nitrogen, Total

(LBS/DAY) Report -- -- 2 days/week Calculated OUI-18

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

15 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

pH (SU) -- 9.0 6.0 2 days/week Grab or Insitu OUI-18

Radium 226 +

Radium 228,

Total (PCI/L) -- 5.0 -- Quarterly 24-hour time

proportioned

composite OUI-18

Alpha, Gross

Particle Activity

(PCI/L) 2 

# -- 15.0 -- Quarterly 24-hour time

proportioned

composite OUI-18

15. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.16 and

as described below:

Sample Point Description of Monitoring Location

OUI-18 Eagle Lake Outfall

16. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall I-S22 (previously known as

001-22) to Eagle Lake. Such discharge shall be li mited and monitored by the permittee as specified

below through the Swift Creek mine clay settling ar ea and then relocate Swift Creek to Eagle Lake

and reported in accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Continuous Meter OUI-22

Phosphorus,

Total

(as P) (MG/L) 35.0 105.0 -- 2 days/week 24-hour time

proportioned

composite OUI-22

pH (SU) -- 9.5 6.0 2 days/week Grab or Insitu OUI-22

Nitrogen, Total

(MG/L) Report Report -- 2 days/week Grab OUI-22

Fluoride, Total

(as F) (MG/L) 25.0 75.0 -- 2 days/week 24-hour time

proportioned

composite OUI-22

2 

# The Permittee shall firs t analyze for gross alpha particle including radium 226 but excluding radon and uranium. If the gross alpha particle

activity exceeds 5 pCi/L, the Permittee will be required to analyz e an aliquot of the same sample for the Radium 226 and 228, a nd shall be

reported on the subsequent month's Discharg e Monitoring Report (DMR). If the gross alpha particle activity does not exceed 5 p Ci/L,

compliance with the combined radium 226 and 228 limit will be deemed to have been achieved.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

16 

# 17. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.18 and

as described below:

Sample Point Description of Monitoring Location

OUI-22 Discharge from Retention pond

18. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge from a calcium sulfate storage pile runoff facility

operated separately or in combination with a wate r recirculation system designed, constructed and

operated to maintain a surge capacity equal to th e runoff from the 25-year, 24-hour rainfall event

may be discharged from Internal Outfall I-S28 (p reviously known as 001-28) to retention pond at

Swift Creek Chemical Complex, after treatment, and whenever chronic or catastrophic precipitation

events cause the water level to rise into the surg e capacity. Process wastewater must be treated and

discharged whenever the water level equals or ex ceeds the mid-point of the surge capacity. Such

discharge shall be limited and monitored by th e permittee as specified below and reported in

accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- 2 days/week Calculated OUI-28

Solids, Total

Suspended

(MG/L) 50.0 150.0 -- 2 days/week 24-hour time

proportioned

composite OUI-28

Phosphorus,

Total

(as P) (MG/L) 35.0 105.0 -- 2 days/week 24-hour time

proportioned

composite OUI-28

Turbidity (NTU) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI-28

Fluoride, Total

(as F) (MG/L) 25.0 75.0 -- 2 days/week 24-hour time

proportioned

composite OUI-28

Specific

Conductance

(UMHO/CM) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI-28

Nitrogen, Total

(MG/L) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI-28

Radium 226 +

Radium 228,

Total (PCI/L) -- 5.0 -- Quarterly 24-hour time

proportioned

composite OUI-28

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

17 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Alpha, Gross

Particle Activity

(PCI/L) 3 

# -- 15.0 -- Quarterly 24-hour time

proportioned

composite OUI-28

19. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.20 and

as described below:

Sample Point Description of Monitoring Location

OUI-28 After Liming Pond on Swift Creek Chemical Complex

20. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge fro m Outfall D-002. Such discharge shall be limited

and monitored by the permittee as specified below and reported in accordance with condition I.E.3.:

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- 4 days/week Calculated EFF-2

Total NonVolatile NonFilterable

Residue (MG/L) 12 25 -- 2 days/week 24-hour time

proportioned

composite EFF-2

Solids, Total

Suspended

(MG/L) 30 60 -- 2 days/week 24-hour time

proportioned

composite EFF-2

Oxygen,

Dissolved (DO)

(MG/L) Report -- 5.0 Weekly In-situ EFF-2

Specific

Conductance

(UMHO/CM) 1275 Weekly Grab EFF-2

Fluoride, Total

(as F) (MG/L) Report 10.0 -- Weekly 24-hour time

proportioned

composite EFF-2

Ammonia,

Unionized (as

NH3) (MG/L) Report 0.02 -- Weekly Calculated EFF-2

3 

# The Permittee, when treating and discharg ing process water, shall first analyze fo r gross alpha particle including radium 226 but excluding

radon and uranium. If the gross alpha particle activity exceeds 5 pCi/L, the Permittee will be required to analyze an aliquot of the same sample

for the Radium 226 and 228, and shall be re ported on the subsequent month's Discharge Monitoring Report (DMR). If the gross al pha particle

activity does not exceed 5 pCi/L, compliance w ith the combined radium 226 and 228 limit will be deemed to have been achieved.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

18 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Nitrogen,

Ammonia, Total

(as N) (MG/L) Report Report -- Weekly Grab EFF-2

Temperature

(oC), Water

(DEG.C) Report Report -- Weekly Grab or Insitu EFF-2

Turbidity (NTU) Report 31.0

See Permit

Condition

I.A.32 -- Weekly Grab EFF-2

pH (SU) -- 8.5 6.0 Weekly Grab or Insitu EFF-2

Phosphorus,

Total

(as P) (MG/L) 3.0 5.0 -- Weekly 24-hour time

proportioned

composite EFF-2

Phosphorus,

Total

(as P)

(LBS/DAY) Report -- -- Weekly Calculated EFF-2

Nitrogen,

Kjeldahl, Total

(as N) (MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-2

Nitrogen, Total

(MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-2

Nitrogen, Total

(LBS/DAY) Report -- -- Weekly Calculated EFF-2

Radium 226 +

Radium 228,

Total (PCI/L) -- 5.0 -- Quarterly 24-hour time

proportioned

composite EFF-2

Alpha, Gross

Particle Activity

(PCI/L) 4 

# -- 15.0 -- Quarterly 24-hour time

proportioned

composite EFF-2

4 

# The Permittee shall firs t analyze for gross alpha particle including radium 226 but excluding radon and uranium. If the gross alpha particle

activity exceeds 5 pCi/L, the Permittee will be required to analyz e an aliquot of the same sample for the Radium 226 and 228, a nd shall be

reported on the subsequent month's Discharg e Monitoring Report (DMR). If the gross alpha particle activity does not exceed 5 p Ci/L,

compliance with the combined radium 226 and 228 limit will be deemed to have been achieved.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

19 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Acute Whole

Effluent Toxicity

(Ceriodaphnia

dubia) 100

See Permit

Condition

I.A.28 Quarterly Grab EFF-2

Acute Whole

Effluent Toxicity

(Cyprinella leedsi) 100

See Permit

Condition

I.A.28 Quarterly Grab EFF-2

Biological

Integrity See Permit Condition I.A.31 Quarterly -- SWD-2

21. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.22 and

as described below:

Sample Point Description of Monitoring Location

EFF-2 Canal to Hunter Creek

SWD-2 Hunter’s Creek at CR 135

22. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge fro m Outfall D-003. Such discharge shall be limited

and monitored by the permittee as specified below and reported in accordance with condition I.E.3.

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- 4 days/week Calculated EFF-3

Total NonVolatile NonFilterable

Residue (MG/L) 12 25 -- 2 days/week 24-hour time

proportioned

composite EFF-3

Solids, Total

Suspended

(MG/L) 30 60 -- 2 days/week 24-hour time

proportioned

composite EFF-3

Oxygen,

Dissolved (DO)

(MG/L) Report -- 5.0 Weekly In-situ EFF-3

Specific

Conductance

(UMHO/CM) 1275 Weekly Grab EFF-3

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

20 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Fluoride, Total

(as F) (MG/L) Report 10.0 -- Weekly 24-hour time

proportioned

composite EFF-3

Ammonia,

Unionized (as

NH3) (MG/L) Report 0.02 -- Weekly Calculated EFF-3

Nitrogen,

Ammonia, Total

(as N) (MG/L) Report Report -- Weekly Grab EFF-3

Temperature

(oC), Water

(DEG.C) Report Report -- Weekly Grab or Insitu EFF-3

Turbidity (NTU) Report 31.0

See Permit

Condition

I.A.32 -- Weekly Grab EFF-3

pH (SU) -- 8.5 6.0 Weekly Grab or Insitu EFF-3

Phosphorus,

Total

(as P) (MG/L) 3.0 5.0 -- Weekly 24-hour time

proportioned

composite EFF-3

Phosphorus,

Total

(as P)

(LBS/DAY) Report -- -- Weekly Calculated EFF-3

Nitrogen,

Kjeldahl, Total

(as N) (MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-3

Nitrogen, Total

(MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-3

Nitrogen, Total

(LBS/DAY) Report -- -- Weekly Calculated EFF-3

Radium 226 +

Radium 228,

Total (PCI/L) -- 5.0 -- Quarterly 24-hour time

proportioned

composite EFF-3

Alpha, Gross

Particle Activity

(PCI/L) 5 

# -- 15.0 -- Quarterly 24-hour time

proportioned

composite EFF-3

5 

# The Permittee shall firs t analyze for gross alpha particle including radium 226 but excluding radon and uranium. If the gross alpha particle

activity exceeds 5 pCi/L, the Permittee will be required to analyz e an aliquot of the same sample for the Radium 226 and 228, a nd shall be

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

21 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Acute Whole

Effluent Toxicity

(Ceriodaphnia

dubia) 100

See Permit

Condition

I.A.28 Quarterly Grab EFF-3

Acute Whole

Effluent Toxicity

(Cyprinella leedsi) 100

See Permit

Condition

I.A.28 Quarterly Grab EFF-3

Biological

Integrity See Permit Condition I.A.31 Quarterly -- SWD-3

23. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.24 and

as described below:

Sample Point Description of Monitoring Location

EFF-3 Roaring Creek at CR 135

SWD-3 Downstream from D-003 within Roaring Creek prior to Suwannee

River

24. During the period beginning upon placing the system into operation and lasting through the

expiration date of this permit, the permittee is authorized to discharge from Outfall D-004. Such

discharge shall be limited and monitored by th e permittee as specified below and reported in

accordance with condition I.E.3.

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- 2 days/week Calculated EFF-4

pH (SU) -- 8.5 6.0 2 days/week Grab or Insitu EFF-4

Solids, Total

Suspended

(MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-4

Oxygen,

Dissolved (DO)

(MG/L) Report -- 5.0 Weekly In-situ EFF-4

reported on the subsequent month's Discharg e Monitoring Report (DMR). If the gross alpha particle activity does not exceed 5 p Ci/L,

compliance with the combined radium 226 and 228 limit will be deemed to have been achieved.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

22 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Fluoride, Total

(as F) (MG/L) Report 10.0 -- Weekly 24-hour time

proportioned

composite EFF-4

Specific

Conductance

(UMHO/CM) -- 1275 -- Weekly Grab EFF-4

Turbidity (NTU) Report 31.0

See Permit

Condition

I.A.32 -- Weekly Grab EFF-4

Phosphorus,

Total

(as P) (MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-4

Phosphorus,

Total

(as P)

(LBS/DAY) Report -- -- Weekly Calculated EFF-4

Nitrogen, Total

(MG/L) Report Report -- Weekly 24-hour time

proportioned

composite EFF-4

Nitrogen, Total

(LBS/DAY) Report -- -- Weekly Calculated EFF-4

Biological

Integrity See Permit Condition I.A.31 Quarterly -- SWD-4

25. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.26 and

as described below:

Sample Point Description of Monitoring Location

EFF-4 Camp Branch

SWD-4 Downstream of D-004 within Camp Branch prior to discharge

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

23 

# 26. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge from Internal Outfall OUI-41 (previously known as

004-1) to Camp Branch through D-004. Such di scharge shall be limited and monitored by the

permittee as specified below and reporte d in accordance with condition I.E.3.

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Flow (MGD) Report Report -- Continuous Meter OUI-41

Total NonVolatile NonFilterable

Residue (MG/L) 12 25 -- 2 days/week 24-hour time

proportioned

composite OUI-41

Solids, Total

Suspended

(MG/L) 30.0 60.0 -- 2 days/week 24-hour time

proportioned

composite OUI-41

Phosphorus,

Total

(as P) (MG/L) 3.0 5.0 -- 2 days/week 24-hour time

proportioned

composite OUI-41

Phosphorus,

Total

(as P)

(LBS/DAY) Report -- -- 2 days/week Calculated OUI-41

pH (SU) -- 8.5 6.0 2 days/week Grab OUI-41

Nitrogen, Total

(MG/L) Report Report -- 2 days/week 24-hour time

proportioned

composite OUI-41

Nitrogen, Total

(LBS/DAY) Report -- -- 2 days/week Calculated OUI-41

Turbidity (NTU) -- Report -- Weekly 24-hour time

proportioned

composite OUI-41

Temperature (C),

Water (DEG.C) Report Report -- Weekly Grab or Insitu OUI-41

Oxygen,

Dissolved (DO)

(MG/L) Report -- 5.0 Weekly In-situ OUI-41

Ammonia,

Unionized (as

NH3) (MG/L) Report 0.02 -- Weekly Calculated OUI-41

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

24 

# Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Nitrogen,

Ammonia, Total

(as N) (MG/L) Report Report -- Weekly 24-hour time

proportioned

composite OUI-41

Radium 226 +

Radium 228,

Total (PCI/L) -- 5.0 -- Quarterly 24-hour time

proportioned

composite OUI-41

Alpha, Gross

Particle Activity

(PCI/L) 6 

# -- 15.0 -- Quarterly 24-hour time

proportioned

composite OUI-41

Acute Whole

Effluent Toxicity

(Ceriodaphnia

dubia) 100

See

Permit

Condition

I.A.28 Quarterly Grab OUI-41

Acute Whole

Effluent Toxicity

(Cyprinella leedsi) 100

See

Permit

Condition

I.A.28 Quarterly Grab OUI-41

27. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.28 and

as described below:

Sample Point Description of Monitoring Location

OUI-41 Lang Lake Outfall

28. The permittee shall comply with the following requirements to evaluate acute whole effluent

toxicity of the discharge from outfall D-002, D-003, and OUI-41.

a. Effluent Limitation

(1) Whole effluent acute toxicity testing shall not result an LC 50 

# of less than 100% effluent in any

routine or additional follow-up test. [Rules 62-302.200(1), 62-302.500(1)(a)4., 62-

4.244(3)(a), and 62-4.241(1)(a) or 2(a), F.A.C.]

b. Monitoring Frequency

(1) Routine toxicity tests shall be conducted ev ery three months, the first starting three months

from previous test and lasting for the duration of this permit.

(2) Upon completion of four consecutive, valid routine tests that demonstrate compliance with

the effluent limitation in 28.a.(1) above, th e permittee may submit a written request to the

Department for a reduction in monitoring freque ncy to once every six months. The request

shall include a summary of the data and the comp lete bioassay laboratory reports for each test

6 

# The Permittee shall firs t analyze for gross alpha particle including radium 226 but excluding radon and uranium. If the gross alpha particle

activity exceeds 5 pCi/L, the Permittee will be required to analyz e an aliquot of the same sample for the Radium 226 and 228, a nd shall be

reported on the subsequent month's Discharg e Monitoring Report (DMR). If the gross alpha particle activity does not exceed 5 p Ci/L,

compliance with the combined radium 226 and 228 limit will be deemed to have been achieved.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

25 

# used to demonstrate compliance. The Department shall act on the request within 45 days of

receipt. Reductions in monitoring shall only b ecome effective upon the Department’s written

confirmation that the facility has completed four consecutive valid routine tests that

demonstrate compliance with the effluent limitation in 28.a.(1) above.

(3) If a test within the sequence of the four is deemed invalid based on the acceptance criteria in

EPA-821-R-02-012, but is replaced by a repeat valid test initiated within 14 days after the last

day of the invalid test, the invalid test will not be counted against the requirement for four

consecutive valid tests for the purpose of evalua ting the reduction of monitoring frequency.

c. Sampling Requirements

(1) All tests shall be conducted on a single grab sample of final effluent.

(2) Results for each additional test shall incl ude the determination of LC50 values with 95%

confidence limits.

d. Test Requirements

(1) Routine Tests: All routine tests shall be conducted using a control (0% effluent) and a

minimum of five dilutions: 100%, 75%, 50%

, 25% , and 12.5% effluent.

(2) The permittee shall conduct 96-hour acute static renewal multi-concentration toxicity tests

using the daphnid, Ceriodaphnia dubia , and the bannerfin shiner, Cyprinella leedsi

, concurrently.

(3) All test species, procedures and quality assura nce criteria used shall be in accordance with

Methods for Measuring Acute Toxicity of Effluents and Receiving Waters to Freshwater and

Marine Organisms , EPA-821-R-02-012. Any deviation of the bioassay procedures outlined

herein shall be submitted in writing to the Depart ment for review and approval prior to use. In

the event the above method is revised, the perm ittee shall conduct acute toxicity testing in

accordance with the revised method.

(4) The control water and dilution water shall be moderately hard water as described in EPA821-R-02-012, Table 7.

e. Quality Assurance Requirements

(1) A standard reference toxicant (SRT) quality assurance (QA) acute toxicity test shall be

conducted with each species used in the required to xicity tests either concurrently or initiated

no more than 30 days before the date of each routine or additional follow-up test conducted.

Additionally, the SRT test must be conducted c oncurrently if the test organisms are obtained

from outside the test laboratory unless the test organism supplier provides control chart data

from at least the last five monthly acute toxici ty tests using the same reference toxicant and

test conditions. If the organism supplier pr ovides the required SRT data, the organism

supplier’s SRT data and the test laboratory’s monthly SRT-QA data shall be included in the

reports for each companion routine or additional follow- up test required.

(2) If the mortality in the control (0% effluent) ex ceeds 10% for either species in any test, the test

for that species (including the control) shall be invalidated and the test repeated. The repeat

test shall begin within 14 days afte r the last day of the invalid test.

(3) If 100% mortality occurs in all effluent concen trations prior to the end of any test and the

control mortality is less than 10% at that ti me, the test (including the control) shall be

terminated with the conclusion that the test fails and constitutes non-compliance.

(4) Additional follow-up tests shall be evalua ted for acceptability based on the concentrationresponse relationship, as required by EPA-821- R-02-012, Section 12.2.6.2., and included

with the bioassay laboratory reports.

f. Reporting Requirements

(1) Results from all required tests shall be reporte d on the toxicity page of the DMR as follows:

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

26 

# (a) If 50% or more survival occurs in all t est concentrations, then the calculated LC50 is

greater than 100% effluent and “ > 100%” should be entered for that test species.

(b) If less than 50% survival o ccurs for either test species, then report the calculated LC50

value for that test species and the 95%confidence limits.

(c) When no discharge occurs during any repor ting period, NODI=C shall be reported on

the toxicity page of the DMR.

(2) A bioassay laboratory report for the routine test shall be prepared according to EPA-821-R02-012, Section 12, Report Preparation and Test Review, and e-mailed or mailed to the

Department at the address below within 30 days after the last day of the test.

(3) For additional follow-up tests, a single bioassay laboratory report shall be prepared

according to EPA-821-R-02-012, Section 12, and e-mailed or mailed within 30 days after

the last day of the second valid additional follow-up test.

(4) Data for invalid tests shall be included in the bioassay laboratory report for the repeat test.

(5) The same bioassay data shall not be repo rted as the results of more than one test.

(6) All bioassay laboratory reports shall be e-mailed or mailed to Jacksonville :

Florida Department of Environmental Protection

Northeast District Office – Wastewater Section

8800 Baymeadows Way West, Suite 100

Jacksonville, Florida 32256

g. Test Failures

(1) A test fails when the test results do not meet the limits in 28.a.(1).

(2) Additional Follow-up Tests:

(a) If a routine test does not meet the acute t oxicity limitation in 28.a.(1) above, the permittee

shall notify the Department at the address above within 21 days after the last day of the

failed routine test and conduct two additiona l follow-up tests on each species that failed

the test in accordance with 28.d.

(b) The first test shall be initiated within 28 days after the last day of the failed routine test.

The remaining additional follow-up tests sh all be conducted weekly thereafter until a

total of two valid additional follow-up tests are completed.

(c) The additional follow-up tests shall be c onducted using a control (0% effluent) and a

minimum of five dilutions: 100%, 75%, 50%, 25%, a nd 12.5% effluent, OR the permittee

may modify the dilution series in the add itional follow-up tests to more accurately

bracket the toxicity such that at least two dilutions above and two dilutions below the

target concentration and a control are run. All test results shall be statistically analyzed

according to the Appendices in EPA-821-R-02-012.

(3) In the event of three valid test failures (whether routine or additional follow-up tests) at a

single sampling location within a 12-month period, the permittee shall notify the Department

within 21 days after the last day of the third test failure.

(a) The permittee shall consult with the Department and submit a plan for correction of the

effluent toxicity within 60 days after the last day of the third test failure.

(b) The Department shall review and approve the plan before initiation.

(c) The plan shall be initiated within 30 days following the Department’s written approval of

the plan.

(d) Progress reports shall be submitted quarterly to the Department at the address above.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

27 

# (e) During the implementation of the plan, th e permittee shall conduct quarterly routine

whole effluent toxicity tests in accordance with 28.d. Additional follow-up tests are not

required while the plan is in progress. Follo wing completion or termination of the plan,

the frequency of monitoring for routine and a dditional follow-up tests shall return to the

schedule established in 28.b.(1). If a routine test is invalid according to the acceptance

criteria in EPA-821-R-02-012, a repeat test shall be initiated within 14 days after the last

day of the invalid routine test.

(f) Upon completion of four consecutive, valid routine tests that demonstrate compliance

with the effluent limitation in 28.a.(1) above , the permittee may submit a written request

to the Department to terminate the plan . The plan shall be terminated upon written

verification by the Department that the fac ility has passed at least four consecutive valid

routine whole effluent toxicity tests.

(g) If a test within the sequence of the four is deemed invalid, but is replaced by a repeat

valid test initiated within 14 days after the last day of the invalid test, the invalid test will

not be counted against the requirement for f our consecutive valid tests for the purpose of

terminating the plan.

(4) The additional follow-up testing and the pl an do not preclude the Department taking

enforcement action for whole effluent toxicity test failures.

29. During the period beginning on the issuance date a nd lasting through the expiration date of this

permit, the permittee is authorized to discharge combination of all discharges from D-001, D-002,

and D-003 and D-004 (OUI-41) from Outfall D-SUM. Such discharge shall be limited and

monitored by the permittee as specified below a nd reported in accordance with condition I.E.3.

Discharge Limitations Monitoring Requirements

Parameters

(units) Monthly

Average Daily

Maximum Daily

Minimum Monitoring

Frequency Sample

Type Sample

Point

Phosphorus,

Total

(as P)

(LBS/DAY) 5901 -- -- Weekly Calculated OTHSUM

Nitrogen, Total

(LBS/DAY) 4013 -- -- Weekly Calculated OTHSUM

a. The total loading at outfalls D-001, D-00 2, D-003 and D-004 (OUI-41) shall be summed

monthly. PCS Phosphate (permittee) is subject to the effluent limitation for annual average mass

load of total phosphorous and total nitrogen (i.e ., the monthly mass loading of total phosphorous

and total nitrogen for each month starting from th e first day of the second month following permit

issuance through the last day of the 12 th 

# month period (rolling 12 month period) discharged from

PCS Phosphate to the Upper Suwannee River basin through Outfalls D-001, D-002, D-003 and

D-004 (OUI-41). The annual mass-based effluent limitation for total phosphate shall not exceed

5901 lb/day monthly average and total nitrogen (as N) shall not exceed 4013 lb/day monthly

average discharged from Outfalls D-001, D-002, D-003 and D-004 (OUI-41). The total sum is

calculated from individual concentration and indivi dual flow of each designed outfall. The total

nitrogen and total phosphorous mass load limit is ca lculated monthly, and is a rolling 12-month

annual average. Monthly loadings shall be cal culated from the monthly average flows and the

monthly average total nitrogen and total phosphor us concentrations at the respective outfalls.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

28 

# 30. Effluent samples shall be taken at the monitoring site locations listed in permit condition I.A.29 and

as described below:

Sample Point Description of Monitoring Location

OTH-SUM combined numbers from D-001, D-002, D-003 and OUI-41

31. Biological Integrity – The biological integrity of Swift Creek at outfall D-001, Hunter’s Creek at

SWD-2, Roaring Creek at SWD-3, and Camp Branch at SWD-4 shall be in compliance with FAC

Rule 62-302.530(10). Sampling to demonstrat e compliance with the biological integrity

requirement shall be done on a quarterly basis. Co mpliance will be demonstrated if the quarterly

Shannon-Weaver index measures at each location are not less than 75% of the background value.

The background values are as follows:

Stream Associated

Outfall Background

Index

Swift Creek D-001 3.62

Hunter Creek D-002 (SWD2) 4.11

Roaring Creek D-003 (SWD3) 4.11

Camp Branch D-004(SWD-4) 4.00

32. Turbidity shall not exceed 31.0 NTU, except wh ere the Permittee can demonstrate that the

exceedance is not related to the facility’s operations . The Permittee shall make this demonstration by

sampling from its other outfalls as well as any offsite tributaries not affected by its operations. In

accordance with rule 62-302.530(69) FAC, turbidity for Class III fresh waters, the value shall be less

than or equal to 29 NTU above natural background conditions. 62- 302.530(69) FAC.

33. There shall be no discharge of floating solids or visible foam in other than trace amounts.

34. The discharge shall not cause a visible sheen on the receiving water.

B. Underground Injection Control Systems

1. This section is not applicable to this facility.

C. Land Application Systems

1. The permittee is authorized to land apply pro cess generated wastewater, contaminated non-process

water (CNPW), stormwater, and treated sanitary wast ewater to the spray irrigation and wetlands land

application project, clay settling areas, mining and reclamation areas as reference in Part I.A.12

above.

D. Other Methods of Disposal or Recycling

1. There shall be no discharge of industrial wastewater from this facility to ground or surface waters,

except as authorized by this permit.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

29 

# E. Other Limitations and Monito ring and Reporting Requirements

1. The sample collection, analytical test methods and method detection limits (MDLs) applicable to this

permit shall be in accordance with Rule 62-4.246, Chapters 62-160 and 62-601, F.A.C., and 40 CFR

136, as appropriate. The list of Department est ablished analytical methods, and corresponding MDLs

(method detection limits) and PQLs (practical qua ntification limits), which is titled “Florida

Department of Environmental Protection Table as Re quired By Rule 62-4.246(4) Testing Methods for

Discharges to Surface Water” is available at http://www.dep.state.fl.us/labs/guidance/index.htm. The

MDLs and PQLs as described in this list shall constitute the minimum a cceptable MDL/PQL values

and the Department shall not accept results for which the laboratory's MDLs or PQLs are greater than

those described above unless alternate MDLs and/or PQLs have been specifically approved by the

Department for this permit. Any method included in the list may be used for reporting as long as it

meets the following requirements:

a. The laboratory’s reported MDL and PQL values fo r the particular method must be equal or less

than the corresponding method values specified in the Department’s a pproved MDL and PQL list;

b. The laboratory reported MDL for the specific parame ter is less than or equal to the permit limit or

the applicable water quality criteria, if any, stated in Chapter 62-302, F.A.C. Parameters that are

listed as “report only” in the permit shall use met hods that provide a MDL, which is equal to or

less than the applicable water quality cr iteria stated in 62-302, F.A.C.; and

c. If the MDLs for all methods available in the a pproved list are above the stated permit limit or

applicable water quality criteria for that paramete r, then the method with the lowest stated MDL

shall be used.

When the analytical results are below method de tection or practical quantification limits, the

permittee shall report the actual laboratory MDL and/or PQL values for the analyses that were

performed following the instructions on the a pplicable discharge monitoring report.

Where necessary, the permittee may request approval of alternate methods or for alternative MDLs

or PQLs for any approved analytical method. Approval of alternate la boratory MDLs and PQLs

are not necessary if the laboratory reported MDLs and PQLs are less than or equal to the permit

limit or the applicable water quality criteria, if an y, stated in Chapter 62-302, F.A.C. Approval of

an analytical method not included in the above-refe renced list is not necessary if the analytical

method is in accordance with 40 CFR 136.

2. Parameters which must be monitored as a result of a surface water discharge shall be analyzed using a

sufficiently sensitive method to assure compliance with applicable water quality standards and

effluent limitations in accordance with 40 CFR Part 136. All monitoring shall be representative of the

monitored activity.

3. Monitoring requirements under this permit are effective on the first day of the second month

following permit issuance. Until such time, the pe rmittee shall continue to monitor and report in

accordance with previously effective permit require ments, if any. During the period of operation

authorized by this permit, the permittee shall comp lete and submit to the Northeast District Office

Discharge Monitoring Reports (D MRs) in accordance with the frequ encies specified by the REPORT

type (i.e., monthly, toxicity, quarterly, semiannual, annual, etc.) indicated on the DMR forms attached

to this permit. The permittee has the option to submit the DMRs through DEP electronic submittal

(eDMR). Monitoring results for each monitoring pe riod shall be submitted in accordance with the

associated DMR due dates below.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

30 

# REPORT TYPE shown on

DMR Monitoring Period DMR Due Date

Monthly first day of month – last day of

month 28 th 

# day of following month

Toxicity January 1 - March 31

April 1 – June 30

July 1 – September 30

October 1 – December 31 April 28

July 28

October 28

January 28

Quarterly January 1 - March 31

April 1 – June 30

July 1 – September 30

October 1 – December 31 April 28

July 28

October 28

January 28

Semi-annual January 1 – June 30

July 1 – December 31 July 28

January 28

Annual January 1 – December 31 January 28

DMRs shall be submitted for each required monitoring period including months of no discharge.

The permittee has the option to submit the DMRs through DEP electronic submittal (eDMR), or the

permittee shall make copies of the attached DM R form(s) and shall submit the completed DMR

form(s) to the Department at the address specified below:

Florida Department of Environmental Protection

Wastewater Compliance Evaluati on Section, Mail Station 3551

Bob Martinez Center

2600 Blair Stone Road

Tallahassee, Florida 32399-2400

4. Unless specified otherwise in this permit, all re ports and notifications required by this permit,

including twenty-four hour notifica tions, shall be submitted to or reported to the Northeast District

Office at the address specified below:

Florida Department of Environmental Protection

Attn.: Industrial Wastewater Section

8800 Baymeadows Way West, Suite 100

Jacksonville, FL 32256

Phone (904) 256-1700

FAX (904) 256-1589 (All FAX copies shall be followed by original copies.)

5. All reports and other information shall be signed in accordance with requirements of Rule 62-620.305,

F.A.C.

6. The permittee shall provide safe access points for obtaining representative samples which are required

by this permit.

7. If there is no discharge from the facility on a da y scheduled for sampling, the sample shall be

collected on the day of the next scheduled sa mpling day as per the schedule submitted with the

application.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

31 

# 8. Any bypass of the treatment facility which is not incl uded in the monitoring specified in sections I.A,

I.B, I.C, or I.D, is to be monitored for flow a nd all other required paramete rs. For parameters other

than flow, at least one grab sample per day shall be monitored. Daily flow shall be monitored or

estimated, as appropriate, to obtain reportable data . All monitoring results shall be reported on the

appropriate DMR.

II. Industrial Sludge Management Requirements

A. Basic Management Requirements

1. Solids from the lime treatment process are manage d in the clay settling areas at this facility.

2. Management of other sludge generated by the treatment of industrial wastew ater at this facility, if any,

would be disposed of at a Class I solid waste landfill or as otherwise required by applicable

Department rule.

3. The permittee shall be responsible for proper treatme nt, management, use or land application of its

sludges.

4. Disposal of sludge in a solid waste management facility permitted by the De partment shall be in

accordance with the requirements of Chapter 62-701, F.A. C. Storage, transportation, and disposal of

sludge/solids characterized as hazardous waste shall be in compliance with requirements of Chapter

62-730, F.A.C.

5. The permittee shall keep records of the amount of sludge disposed, transported, or incinerated in

Class I Landfill. If a person other than the permittee is responsible for sludge transporting, disposal,

or incineration, the permittee shall also keep the following records:

a. name, address and telephone number of any trans porter, and any manifests or bill of lading used;

b. name and location of the site of disposal, treatment or incineration;

c. name, address, and telephone number of the entity responsible for disposal, treatment, or

incineration site.

III. Ground Water Monitoring Requirements

A. Construction Requirements

1. Prior to construction of new ground water monitoring wells, a soil boring shall be made at each new

monitoring well location in order to properly de termine the well depth and screen interval.

2. The permittee shall give at least 72-hours notice to the Department, prior to the installation or

replacement of any monitoring wells detailed in this permit.

3. Within 30 days after installation of a new moni toring well, the permittee shall submit to the

Department's Northeast District Office detailed in formation on the well’s loca tion and construction on

DEP Form 62-522.900(3), Monitor Well Completion Report.

B. Operational Requirements

1. During the period of operation authorized by this permit, the permittee shall sample ground water at

the monitoring wells identified in item III.B.2 (a) an d (b) below, in accordance with this permit and

the approved ground water monitoring plan prepar ed in accordance with Rule 62-520.600, F.A.C.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

32 

# 2. (a) The following monitoring wells shall be sampled through 2 nd 

# Quarter 2013:

Monitoring

Well ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

MWB-SC/SRB 30o 28’ 01” N 82o 49’ 30” W 30 Surficial Existing

MWI-SC1S 30o 27’ 03” N 82o 53’ 09” W 36 Surficial Existing

MWI-SC2S 30o 27’ 03” N 82o 53’ 09” W 36 Surficial Existing

MWI-SC3S 30o 26’ 31” N 82o 52’ 37” W 52 Surficial Existing

MWI-SC4S 30o 26’ 32” N 82o 52’ 38” W 41 Surficial Existing

MWI-SC4D Adjacent to SC-4S 61 Surficial Existing

MWI-SC5S 30o 27’ 20” N 82o 53’ 20” W 30 Surficial Existing

MWI-SC5D Adjacent to SC-5S 61 Surficial Existing

MWC-SC6 30o 27’ 05” N 82o 55’ 40” W 28 Surficial Existing

MWC-SC7 30o 25’ 31” N 82o 54’ 16” W 28 Surficial Existing

MWC-SC9S 30°25’15”N 82°47’11”W 30 Surficial Existing

MWC-SC10 TBD TBD ≈ 35 Surficial Existing

MWC-SC11 TBD TBD ≈ 35 Surficial Existing

MWC-SCG1 30o 24’ 01” N 82o 50’ 04” W 33 Surficial Existing

MWI-SR3S 30o 25’ 47” N 82o 47’ 43” W 41 Surficial Existing

MWI-SR7S 30o 26’ 54” N 82o 48’ 05” W 35 Surficial Existing

MWI-SR7D Adjacent to SR-7S 50 Surficial Existing

MWI-SR8S 30o 26’ 21” N 82o 47’ 51” W 30 Surficial Existing

MWI-SR8D Adjacent to SR-8S 55 Surficial Existing

MWC-SR8F Adjacent to SR-8S 210 Floridan Existing

MWI-SR9S 30o 25’ 14” N 82o 47’ 10” W 30 Surficial Existing

MWC-SRA1 30o 24’ 04” N 82o 47’ 21” W 22 Surficial Existing

MWC-SRM1 30o 25’ 49” N 82o 45’ 43” W 41 Surficial Existing

MWC-SR10 TBD TBD ≈ 35 Surficial Existing

MWC-SR11 TBD TBD ≈ 35 Surficial Existing

MWC-SR12 TBD TBD ≈ 35 Surficial Existing



# MWB = Background; MWI = Intermediate; MW C = Compliance TBD = To be determined

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

33

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

34 

# (b) The following monitoring wells shall be sampled beginning with 3 rd 

# Quarter 2013:

SWIFT CREEK COMPLEX

Monitoring Well

ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

B MWB-SC/SRB 30o 28’ 01”N 82o 49’ 30”W 30 Surficial Existing

I MWI -EPA-11S 30° 26' 36”N 82° 53' 01”W 57 Surficial Existing

I MWI-EPA-15S 30° 27' 17”N 82° 51' 44”W 26.5 Surficial Existing

I MWI-EPA-15D Adjacent to EPA-15S 47 Surficial Existing

C MWC-EPA-16S 30° 27' 02”N 82° 51' 26”W 30 Surficial Existing

C MWC-EPA-16D Adjacent to EPA-16S 50 Surficial Existing

I MWI-EPA-18S 30° 26' 13”N 82° 52' 06”W 47 Surficial Existing

I MWI-SC5S 30o 27’20” N 82o 53’ 20”W 30 Surficial Existing

I MWI-SC5D Adjacent to SC-5S 61 Surficial Existing

C MWC-SC-12S  30°28’01”N  82° 52‘ 15”W  30 Surficial New

C MWC-SC-12D Adjacent to SC-12S  60 Surficial New

C MWC-SC-13S  30°27’59”N  82° 53’ 45”W  30 Surficial New

C MWC-SC-13D Adjacent to SC-13S  60 Surficial New

C MWC-SC-14D  30°26’50”N  82° 53’ 41”W  60 Surficial New

C MWC-SC-15D  30°26’08”N  82° 52’ 59”W  60 Surficial New

C MWC-SC-16S  30°26’05”N  82° 51’ 55”W  30 Surficial New

C MWC-SC-16D Adjacent to SC-16S  60 Surficial New

C MWC-SC-17S  30°27’30”N  82° 51’ 50”W  30 Surficial New

C MWC-SC-17D Adjacent to SC-17S  60 Surficial New

C MWC-SC-4F 30° 26' 32”N 82° 52' 37”W 240 Floridan Existing

C MWC-SC-5F 30° 27' 22”N 82° 53' 29”W 240 Floridan Existing

C MWC-MC-3FS 30° 27' 04”N 82° 51' 54”W 204 Floridan Existing

C MWC-C-CW (SC5) 30° 26' 45”N 82° 52' 01”W 216 Floridan Existing



# B = Background; I = Intermediate; C = Compliance

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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35 

# SUWANNEE RIVER COMPLEX

Monitoring Well

ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

B MWB-SC/SRB 30o 28’ 01” N 82o 49’ 30” W 30 Surficial Existing

C MWC-SR-1SR 30° 27' 12”N 82° 46' 05”W 39.5 Surficial Existing

C MWC-SRM1 30o 25’ 49” N 82o 45’ 43” W 41 Surficial Existing

I MWI-EPA-P1-C 30° 26' 38”N 82° 48' 03”W 58 Surficial Existing

I MWI-EPA-4D 30° 26' 39”N 82° 48' 02”W 67 Surficial Existing

C MWC-EPA-23D 30° 26' 12”N 82° 45' 48”W 45 Surficial Existing

C MWC-SR-1D  30°27’10”N  82°46’06”W  30 Surficial New

C MWC-SR9S 30°25’15”N 82°47’11”W 30 Surficial Existing

C MWC-SR9D  30°24’15”N  82°47’13”W  60 Surficial New

C MWC-SR-13S  30°27’25”N  82°48’26”W  30 Surficial New

C MWC-SR-13D Adjacent to SR-13S  60 Surficial New

C MWC-SR-14S  30°26’31”N  82°48’26”W  30 Surficial New

C MWC-SR-14D Adjacent to SR-14S  60 Surficial New

C MWC-SR-15D  30°25’24”N  82°48’24”W  60 Surficial New

C MWC-SR-16S  30°27’50”N  82°47’01”W  30 Surficial New

C MWC-SR-16D Adjacent to SR-16S  60 Surficial New

C MWC-SR-17S  30°27’51”N  82° 47’45”W  30 Surficial New

C MWC-SR-17D Adjacent to SR-17S  60 Surficial New

C MWC-SRC-CD5 30° 26' 40”N 82° 47' 04”W 316 Floridan Existing

C MWC-SR8F 30o 26’ 21”N 82o 47’ 51”W 210 Floridan Existing

C MWC-FAS-DORR 30° 26' 22”N 82° 46' 49”W 240 Floridan Existing

C MWC-Moretrench 30° 26' 50”N 82° 48' 00”W 220 Floridan Existing



# B = Background; I = Intermediate; C = Compliance



# Copyrighted map removed

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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36 

# 3. The monitor wells specified in Condition III.B.2(a) a nd (b) shall be sampled for the parameters listed

below:

Paramete r Name Compliance

Well Limit Units Sample

Type Monitoring

Frequency

Water Level Relative to NGVD Report FEET Measured Quarterly

Specific Conductance Report UMHOS/CM In-situ Quarterly

pH Repo rt SU In-situ Quarterly

Phosphate, Ortho (as PO4) Report MG/L Grab Quarterly

Solids, Total Dissolved (TDS) Repo rt M G /L Grab Quarterly

Fluoride, Total (as F) 4 MG/L Grab Quarterly

Sodium, Total Recoverable 160 MG/L Grab Quarterly

Sulfate, Total Report MG/L Grab Quarterly

Arsenic, Total Recoverable 10 UG/L Grab Semiannually

Turbidity R eport NTU Grab Semiannually

Alpha, Gross Particle Activity 15 PCI/L Grab Semiannually

Radium 226 + Radium 228, Total 5 PCI/L Grab See III.B.4



# 4. All monitoring wells identified as background or compliance wells shall be sampled for Radium

226+228 on a semiannual (twice per year) frequency. The remaining wells are individually su bject to

Radiu m 226+228 sampling within 14 days followi ng receipt of Gross Alpha result exceeding 15

pCi/L.

5. Separate zones of discharge (ZOD) are estab lishe d for the Swift Creek and Suwannee River

Co mplexes, extending horizontally along the gro und surface to the boundaries shown in the figure

below. These ZODs do not extend into or across an y state jurisdictional surface waters, or state,

federal, or county roadways except as previously designated for U.S. Highway 41 between latitude

30o27’06” N and 30o25’57” N, and County Road 137, between latitude 30o27’22” N and 30o25’ 16” N.

Vertically , the ZODs extend to the base of the first intermediate aquifer, or to the base of the Penny

Farm s Fm , if an intermediate aquifer is absent.

6. The perm ittee's discharge to ground water shall not cause a violation of any primary water quality

standard at the boundary of the established zones of discharge (ZOD), nor cause the violation of a 

# Copyrighted map removed

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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37 

# secondary standard at any potable well beyond the ZOD. The limited exemption from secondary

standards is subject to the terms set forth in Section 62-520.520, F.A.C.

7. The permittee's discharge to ground water shall no t cause a violation of the minimum criteria for

groun d water within the zone of discharge. [Rule 62-520.520, F.A.C.]

8. If the concentration for any groundwater monitoring parameter is greater in the natural background

than the stated maximum, or in the case of pH is also less than the minimum, the representative

background quality shall be the prevailing standard.

9. Water levels shall be recorded prior to evacuating the well for sample collection. Elevation references

shall include the top of t he well casing and land surface at each well site (NGVD allowable) at a

precision of plus or minus 0.01 feet.

10. Ground water monitoring wells shall be purged prio r to sampling to obtain a representative sample

.

11. Analy ses shall be conducted on un-filtered samples, unl ess filtered samples have been approved by the

Depart ment as being more represen tative of ground wa ter conditions.

12. If a monitoring well becomes damaged or cannot be sampled for some reason, the permittee shall

notif y the Department immediately and a written re port shall follow within seven days de tailing the

circu mstances and remedial measures taken or propo sed. Repair or replacement of monitoring well s

shall be approved in ad vance by the Departme nt.

13. All piezo meters and monitoring wells not part of th e approved ground water monitoring plan are to be

plugged and abandoned in accordance with Rule 62-532. 500(4), F.A.C., unless there is intent for their

future use.

14. The perm ittee shall provide verbal notice to the De partment as soon as practical after discovery of a

sinkhole with in an area for the management or app lication of wastes or wastewater. The perm ittee

shall i mmediately implement measures appropriate to control the entry of contaminants, and shall

detail these measures to the Department in a writte n report within 7 days of the sinkhole discovery

.

15. Ground water monitoring test results shall be s ubmitted on Part D of DEP Form 62-620.910(10) in

accordance w ith the following schedule.

SAMPLE P ERIOD REPORT DUE DATE

January - March April 28

April - June July 28

July - September October 28

October - December January 28

IV. Other Land Application Requirements

1. This sect ion is not applicable to this facility.

V. Operation and Maintenance Requirements

A. Treatment and Disposal Facilities

1. The permittee shall ensure that the operation of th is facility is as described in the application and

supportin g docum ents.

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# 2. The operation of the pollution control facilities descr ibed in this perm it shall be under the supervision

of a person who is qualified b y fo rmal training and/or practical experience in the field of water

polluti on control.

B. Record keeping Requirements:

1. The permittee shall maintain the following records on the site of the permitted facility and make them

available for inspection:

a. Records of all compliance monitoring inform ation, including all calibration and maintena nce

records and all original strip chart recordings for continuous monitoring instrume ntation,

including, if applicable, a copy of the laborator y certification show ing the certification number of

the laboratory, for at least three y ears from the date the sample or measurement was taken;

b. Copies of all reports, other than those required in items a. and f. of this section, required by the

per mit for at least three years from the date the report was prepared, unless otherwise specified by

Department rule;

c. Records of all data, including reports and docum ents used to complete the application for the

per mit for at least three years from the date the application was filed, unless otherwise specified by

Department rule;

d. A copy of the current permit;

e. A copy of any required record drawings;

f. Copies of the logs and schedules showing plant operations and equipment maintenance for three

y ears from the date on the logs or schedule.

VI. Schedules

1. A Be st Management Practices (BMP) Plan shall be prepared and implemented in accordance with

Part VII of this perm it and the following schedule:

Action Item Scheduled Completion Date

1 Continue Implementing Existing BMP Plan Issuance Date of Permit

2 Installation of “new” monitoring wells identified in

section III.2(b). 2 nd 

# Quarter 2013

2. The perm ittee shall achieve compliance with the other conditions of this perm it as follows:

Operational level attained Issuance Date of permit

3. The Permittee shall submit on an annual basis, in March of each year, a Mining and Reclam ation

Report includ ing drawings for that y ear.

4. The Per mittee shall submit an annual report describin g the status of the spray irri gation and wetlands

land application pro j ect.

5. No later than 14 calendar days following a date iden tified in the above schedule(s) of comp liance, the

per mittee shall submit either a report of progress or, in the case of specific acti ons being required by

an identified date, a written notice of compliance or noncompliance. In the latter case, th e notice

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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39 

# shall include the cause of noncompliance, any remedi al actions taken, and the probability of meeting

the next scheduled requirement.

VII. Other Specific Conditions

A. Specific Conditions Applicable to All Permits

1. Drawings, plans, documents or specifications su bmitted by the perm ittee, not attached hereto, but

retained on file at the Northeast District Office, are made a part hereof.

2. Where required by Chapter 471 (P.E.) or Chapter 492 (P.G.) F.S., applicable portions of reports to be

subm itted under this permit, shall be signed and seal ed by the professional(s) who prepared them.

3. This permit satisfies Industrial Wastewater program permitting requirements only and does not

authorize operation of this facility prior to obtain ing any other permits required by lo cal, state or

federal agenc i es.

4. The permittee shall provide verbal notice to the Department as soon as practical after discovery of a

sinkhole within an area for the m anagement or appl ication of wastewater or sludge. The perm ittee

shall i mmediately implement measures appropriate to control the entry of contaminants, and shall

detail these measures to the Department in a writte n report within 7 days of the sinkhole discovery

.

B. Specific Conditions Related to Construction

1. T his section is not applicable to this facility

.

C. Duty to Reapply

1 The permittee shall apply for renewal of this permit at least 180 days before the expiration date of the

permit using the appropriate forms listed in Rule 62-620.910, F.A.C., including submittal of the

appropriate processing fee set forth in Rule 62-4.050, F.A.C. The existing permit shall not expire until

the Department has taken final action on the application renewal in accordance with the provisions of

62-620.335(3) and (4), F.A.C.

D. Specific Conditions Related to Best Management Practices

1. BMP Plan:

For purposes of this part, the ter ms "pollutant" or "pollutants" refer to any substance listed as toxic

under Section 307(a)(1) of the Clean Water Act (the "A ct"), oil, as defined in Section 311(a)(1 ) of the

Act, and any substance listed as hazardous under Section 311 of the Ac t. The permittee shall develop

and implement a Best Management Practices (BMP) plan which prevents, or minimize s, the potential

for the release of pollutants fro m an cillary activities, including material storage areas; plant si te runoff;

in-plant transfer, process and material handling ar eas; loading and unloading operations; and sludge

and waste disposal areas, to the waters of the State through plant site runoff; spillage or leaks; sludge

or waste disposal; or drainage fro m raw material storag e.

2. Imple mentation:

The BMP plan shall be developed and im plemented in accordance with the sche dule contained in Part

VI of this permit.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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40 

# 3. General Requirements:

The BMP plan shall:

a. Be documented in narrative form, and shall incl ude any necessary plot plans, drawings or ma ps.

b. Establish specific objectives for the control of polluta nts.

(1) Each facility component or system shall be ex amined for its potential for causing a release of

significant am ounts of pollutants to waters of the State due to equipment failure, improper

operation, natural phenomena such as rain or snowfall, etc.

(2) Where experience indicates a reasonable poten tial for equipment failure (e.g., a tank overflow

or leakage), natural conditions (e.g., precip itation), or other circumstances to result in

significant amounts of pollutants reaching surface waters, the plan should include a prediction

of the direction, rate of flow, and total quan tity of pollutants which could be discharged from

the facility as a result of each condition or circumstance.

c. Establish specific best management practices to meet the objectives identified under paragraph b.

of this subsec tion, addressing each component or system capable of causing a release of significant

amounts of pollutants to the waters of the State, and identifying sp ecific preventative or remedial

measures to be im plemented.

d. Be reviewed by plant engineering staff and plant ma nager.

4. Documentati on:

The perm ittee shall maintain the BMP plan at the f acility and shall make th e plan available to the

Department upon request.

5. BMP Plan Modification:

The perm ittee shall amend the BMP plan whenever there is a change in the facility or change in the

operation of t he facility which materially increases th e potential for the ancillary activities to result in a

discharge of significant amounts of pollu tants.

6. Modification for Ineffecti veness:

If the BMP pl an proves to be ineffective in achieving the general objective of preventing the release of

significant amounts of pollutants to surface waters and the specific objectives and requireme nts under

paragraphs b. and c. of item 3, the permit shall be subject to modification pursuant to rule 62-620.325

, F.A.C., to inc orporate revised BMP requireme nts.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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41 

# E. Specific Conditions Related to Existing Manuf acturing, Commercial, Mining, and Silviculture

Wastewater Facilities or Activities

1. Existing manufacturing, commercial, mining, and silvicultural wastewater facilities or activities that

discharge into surface waters shall notify the Department as soon as they know or have reason to

believe:

a. That any activity has occurred or will occur wh ich would result in the discharge, on a routine or

frequent basis, of any toxic pollutant which is not limited in the permit, if that discharge will

exceed the highest of the following leve ls

(1) One hundred micrograms per liter,

(2) Two hundred micrograms per liter for acrolein and acrylonitrile; five hundred micrograms per

liter for 2,4-dinitrophenol and for 2-methyl-4,6 -dinitrophenol; and one milligram per liter for

antimony, or

(3) Five times the maximum concentration value reported for that pollutant in the permit

application.

b. T hat any activity has occurred or will occur which would result in any discharge, on a non-routine

or infrequent basis, of a toxic pollutant which is not limited in the permit, if that discharge will

exceed the highest of the following leve ls

(1) Five hundred micrograms per liter,

(2) One milligram per liter for antimony, or

(3) Ten times the maximum concentration value reported for that pollutant in the permit

application.

F. Reopener Clause

1. The permit shall be revised, or alternatively, re voked and reissued in accordance with the pr ovisions

contained in Rules 62-620.325 and 62-620.345, F.A.C., if applicable, or to comply with any

applicable effluent standard or limitation issued or approved under Secti ons 301(b)(2)(C) and (D),

304(b)( 2) and 307(a)(2) of the Clean Water Act (the Act), as amended, if th e effluent standards,

lim itations, or water quality sta ndards so issued or approved:

a. Contains d ifferent conditions or is otherwise mo re stringent than any condition in the permit /or;

b. Controls any pollutant not addressed in the permit.

The permit as revised or reissued under this paragraph shall also contain any other requirements of

the Act then applicable.

2. The permit may be reopened to adjust effluent li mitations or monitoring requireme nts should future

Water Quality Based Effluent Limitation determinations, water quality studies, DEP approved

changes in water quality standard s, EPA established Total maximum Daily Loads (TMDL), or ot her

inform ation show a need for a different limitation or m onitoring requirement.

3. The Department may develop a Total Maximum Daily Load (TMDL) during the life of the permit.

Once a TMDL has been established and adopted by ru le, the Department shall revise this perm it to

incorporate the final findings of the TMDL.

VIII. Gene ral Conditions

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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# 1. The terms, conditions, requirements, limitations a nd restrictions set forth in this permit are binding

and enforceable pursuant to Chapter 403, F.S. Any permit noncompliance constitutes a violation of

Chapter 403, F.S., and is grounds for enforcement action, permit termination, permit revocation and

reissuance, or permit revision. [62-620.610(1), F.A.C.]

2. This permit is valid only for the specific processe s and operations applied fo r and indicated in the

approved drawings or exhibits. Any unauthorized deviation fro m the approved drawings, exhibits,

specifications or conditions of this permit cons titutes grounds for revocation and enforcem ent action

b y the Department. [62-620.610(2), F.A.C.]

3. As provided in subsection 403.087(7), F.S., the issuance of this permit does not convey any vested

rights or an y exclusive privileges. Neither does it authorize any injury to public or private property or

any invasion of personal rights, nor authorize any in fringements of federal, state, or local laws or

regulations. This permit is not a waiver of or approval of any othe r Department perm it or

authorization that may be required for other aspects of the total project which are not addressed in this

permit . [62-620.610(3), F.A.C.]

4. This permit conveys no title to land or water, does not constitute state recognition or acknowledgm ent

of title, and does not constitute authority for the use of submerged lands unless herein provided and

the necessary title or leasehold interests have been obt ained from the State. Only the Trustees of the

Internal I mprovement Trust Fund may express State opinion as to title. [62-620.610(4), F.A.C.]

5. This permit does not relieve the permittee from li ability and penalties for harm or injury to human

health or welfare, animal or plant life, or pr operty caused by the construction or operation of this

permitted source; nor does it allow the permittee to cause pollution in contravention of Florida

Statutes and Department rules, unless specifically authorized by an order from the Department. The

permittee shall take all reasonable steps to minimize or prevent any discharge, reuse of reclaimed

water, or residuals use or disposal in violation of this permit which has a reasonable likelihood of

adversely affecting human health or the environment. It shall not be a defense for a permitt ee in an

enforce ment action that it would have been necessary to halt or reduce the permitted activity in order

to m aintain compliance with the conditions of this permit. [62-620.610(5), F.A.C.]

6. If the permittee wishes to continue an activity regul ated by this permit after its expiration date, th e

perm ittee shall apply for and obtain a new permit. [62-620.610(6), F.A.C.]

7. The permittee shall at all times properly operate an d maintain the facility and systems of treat ment

and control, and related appurtenances, that are installed and used by the permittee to achieve

co mpliance with the conditions of this permit. This provision includes the operation of b ackup or

auxiliary facilities or si milar systems when necessar y to maintain or achieve comp liance with the

conditions of the permit. [62-620.610(7), F.A.C.]

8. This permit may be modified, revoked and reissued, or terminated for cause. The filing of a request

b y the permittee for a permit revision, revocation and reissuance, or termination, or a notific ation of

planned changes or anticipated noncom plia nce does not stay any permit condition. [62-620.610(8),

F.A.C.]

9. The permittee, by accepting this permit, specifi cally agrees to allow authorized Department

personnel, including an authorized representative of the Department and author ized EPA personnel,

when applicable, upon presentation of credentials or other documents as may be required by law, and

at reasonable times, depending upon the nature of the concern being investigated, to

a. Enter upon the permittee’s premises where a regulat ed facility, system, or activity is located or

conducted, or where records shall be ke pt under the conditions of this perm it;

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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43 

# b. Have access to and copy any records that shall be kept under the conditions of this perm it;

c. Inspect the facilities, equipment, practices, or operations regulated or required under this perm it;

and

d. Sample or monitor any substances or parame ters at any location necessary to assure compliance

with this permit or Department rules. [62-620.610(9), F.A.C.]

10. In accepting this permit, the permittee understands a nd agrees that all records, notes, m onitoring data,

and other i nformation relating to the construction or operation of this permitt ed source which are

subm itted to the Department may be used by th e Department as evidence in any enforcem ent case

involving t he permitted source arising under the Florida Statutes or Department rules, except as such

use is proscribed by Section 403.111, Florida Statutes, or Rule 62-620.302, F.A.C. Such evidence

shall only be used to the extent that it is consis tent with the Florida Rules of Civil Procedure and

applicable evidentiary rules. [62-620.610(10), F.A.C.]

11. When requested by the Department, the perm ittee shall within a reasonable time provi de any

inform ation required by law which is needed to determine whether there is cause for revising,

revoking and reissuing, or termina ting this permit, or to determin e compliance with the permit. The

perm ittee shall also provide to the Department upon re quest copies of records required by this permit

to be kept. If the permittee becomes aware of relevant facts that were not submitted or were in correct

in the perm it application or in any report to th e Department, such facts or information shall be

prom ptly submitted or corrections pr omptly reported to the Department. [62-620.610(11), F.A.C.]

12. Unless specifically stated otherwise in Departme nt rules, the permittee, in accepting this permit,

agrees to comply with changes in Department rules and Florida Statutes after a reasonable time for

co mpliance; provided however, the permittee does not waive any other rights granted by Florida

Statutes or Department rules. A reasonable time for compliance with a new or amended surface water

quality standard, other than those standards address ed in Rule 62-302.500, F. A.C., shall include a

reasonable time to obtain or be denied a mi xing zone for the new or amended standard. [62-

620.610(12), F.A.C.]

13. The permittee, in accepting this permit, agrees to pay the applicable regulatory program and

surveillance fee in accordance with Rule 62-4.052, F.A.C. [62-620.610(13), F.A.C.]

14. This permit is transferable only upon Department approval in accordance with Rule 62-620.340,

F.A.C. The permittee shall be liable for any noncompliance of the permitted activity until the

Depart ment approves the transfer. [62-620.610(14), F.A.C.]

15. The permittee shall give the Department written notice at least 60 days before inactivation or

abandonment of a wastewater facility and shall spec ify what steps will be taken to safeguard public

health and safety during and following inactivation or abandonment. [62-620.610(15), F.A.C.]

16. The permittee shall apply for a revision to th e Department permit in accordance with Rule 62-

620.300, F.A.C., and the Department of Environmen tal Protection Guide to Wastewater Permitting at

least 90 days before construction of any planned substantial modifications to the permitted facility is

to commence or with Rule 62-620. 325(2), F.A.C., for minor modifica tions to the permitted facility

. A revised permit shall be obtained befor e construction begins excep t as provided in Rule 62-620.300,

F.A.C. [62-620.610(16), F.A.C.]

17. The permittee shall give advance notice to the De partment of any planned changes in the permitted

facility or activity which may result in noncomplian ce with permit requirements. The perm ittee shall

be responsibl e for any and all damages which ma y result from the changes and may be s ubject to

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

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44 

# enforcement action by the Department for penalties or revocation of this permit. The notice shall

include the following information:

a. A description of the anticipated noncompliance;

b. The period of the anticipated noncompliance, including dates and times; and

c. Steps bein g taken to prevent fu ture occurrence of the noncompliance. [62-620.610( 17),

F.A.C. ]

18. Sampling and monitoring data shall be collected and analyzed in accordance with Rule 62-4.246,

Chapters 62-160 and 62-601, F.A.C., and 40 CFR 136, as approp riate.

a. Monit oring results shall be reported at the inte rvals specified elsewhere in this permit and shall be

reported on a Discharge Monitoring Report (DMR), DEP Form 62-620.910(10), or as specified

elsewhere in the perm it.

b. If the p ermittee monitors any contaminate mo re frequently than required by the permit, using

Department approved test procedures, the results of this monitoring shall be included in the

calculation and reporting of the data submitted in the DMR.

c. Cal culations for all limitations which require averaging of measurements shall use an arithmetic

mean unless otherwise specified in this permit.

d. Except as specifically provided in Rule 62-160.300, F.A.C., any laboratory test required by this

permit shall be performed by a laboratory that has been certified by the Departme nt of Health

Environm ental Laboratory Certification Program (DOH ELCP). Such certification shall be for the

matrix, test method and analyte(s) being measured to comply with this permit. For domestic

wastewater facilities, testing for parameters listed in Rule 62-160.300(4), F.A.C., shall be

conducted un der the direction of a certified operator.

e. Field activities including on-site tests and sample collection shall follow the applicable standard

operating procedures described in DEP-SOP-001/01 adopted by reference in Chapter 62-160,

F.A.C.

f. Alternate field procedures and laboratory methods may be used where they have been approved in

accordance with Rules 62-160.220 and 62-160.330, F.A.C. [62-620.610(18), F.A.C.]

19. Reports of compliance or noncompliance with, or any progress reports on, interim and final

requirem ents contained in any compliance schedul e detailed elsewhere in this permit shall be

submitted no later than 14 days following each schedule date. [62-620.610(19), F.A.C.]

20. The permittee shall report to the Department’s Northeast District Office any noncompliance which

may endanger health or the environment. Any in formation shall be provided orally within 24 hours

from the time the permittee becom es aware of the circumstances. A written submission shall also be

provided within five days of the time the permittee becomes aware of the circ umstances. The written

subm ission shall contain: a description of the noncompliance and its cause; the period of

noncom pliance including exact dates and time, and if the noncomplian ce has not been corrected, the

anticipated time it is expected to continue; and st eps taken or planned to reduce, elim inate, and

prevent recurrence of the noncom pliance.

a. The following shall be included as information wh ich must be reported within 24 hours under this

condition:

(1) Any unanticipated bypass which causes any reclaime d water or effluent to exceed any permit

limitation or results in an unpermitted discharge,

(2) Any upset which causes any reclaimed water or the effluent to exceed any limitation in the

permit,

(3) Violation of a maximum daily discharge limitati on for any of the pollutants specifically listed

in the permit for such notice, and

(4) Any unauthorized discharge to surface or ground waters.

b. Oral reports as required b y this subsection shall be provided as follows:

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

45 

# (1) For unauthorized releases or spills of untreated or treated wastewater reported pursuant to

subparagraph a.(4) that are in excess of 1, 000 gallons per incident, or where information

indicates that public health or the environment will be endangered, oral reports shall be

provided to the Department by calling the STATE WARNING POINT TOLL FREE

NUMBER (800) 320-0519, as soon as practical, but no later than 24 hours from the time the

permittee becomes aware of the discharge. The pe rmittee, to the extent known, shall provide

the following information to the State Warning Point:

(a) Name, address, and telephone number of person reporting;

(b) Name, address, and telephone number of permittee or responsible person for the

discharge;

(c) Date and time of the discharge and status of discharge (ongoing or ceased);

(d) Characteristics of the wastewater spilled or released (untreated or treated, industrial or

domestic wastewater);

(e) Estimated amount of the discharge;

(f) Location or address of the discharge;

(g) Source and cause of the discharge;

(h) Whether the discharge was contained on -site, and cleanup actions taken to date;

(i) Description of area affected by the discharge, including name of water body affected, if

any; and

(j) Other persons or agencies contacted.

(2) Oral reports, not otherwise required to be pr ovided pursuant to subparagraph b.(1) above,

shall be provided to Department’s Northeast District Office within 24 hours from the time the

permittee becomes aware of the circumstances.

c. If the oral report has been received within 24 h ours, the noncompliance has been corrected, and the

noncompliance did not endanger health or the envi ronment, the Department’s Northeast District

Office shall waive the written report. [62-620.610(20), F.A.C.]

21. The permittee shall report all instances of nonc ompliance not reported under Conditions VIII.17., 18.

and 19. of this permit at the time monitoring report s are submitted. This report shall contain the same

inform ation required by Conditi on VIII.20. of this permit. [62-620.610(21), F.A.C.]

22. Bypass Provisions.

a. By pass is prohibited, and the Department may take enforcement action against a permi ttee for

by pass, unless the permittee affirmatively demonstrates that:

(1) Bypass was unavoidable to prevent loss of life, personal injury, or severe property damage;

and

(2) There were no feasible alternatives to the by pass, such as the use of auxiliary treatment

facilities, retention of untreated wastes, or ma intenance during normal periods of equipment

downtime. This condition is not satisfied if adequate back-up equipment should have been

installed in the exercise of reasonable engi neering judgment to prevent a bypass which

occurred during normal periods of equipment downtime or preventative maintenance; and

(3) The permittee submitted notices as required under Condition VIII.22.b. of this permit.

b. If the permittee knows in advance of the need for a bypass, it shall submit prior notic e to the

Depart ment, if possible at least 10 days before th e date of the bypass. The permittee shall submit

notice of an unanticipated bypass within 24 ho urs of learning about the bypass as required in

Condition VIII.20. of this permit. A notice shall include a description of the bypass and its cause;

the period of the bypass, including exact dates a nd times; if the bypass has not been corrected, the

anticipated time it is expected to continue; and the steps taken or planned to reduce, eliminate, and

prevent recurrence of the bypass.

c. The Dep artment shall approve an anticipated bypass, after considering its adverse effe ct, if the

perm ittee demonstrates that it will meet the three conditions listed in Condition VIII.22 a.(1)

through (3) of this permit.

# PERMITTEE: PERMIT NUMBER : FL0000655 – 006

PCS Phosphate - White Springs EXPIRATION DATE: January 7, 2015

46 

# d. A perm ittee may allow any bypass to occur which does not cause re claimed water or effluent

limitations to be exceeded if it is for essential maintenance to assure efficient operation. These

bypasses are not subject to the provision of Condition VIII.22.a. through c. of this permit.

[62-620.610(22), F.A.C.]

23. Upset Provisions

a. A permittee who wishes to establish the affirm ative defense of upset shall demonstrat e, through

properl y signed contemporaneous operating lo gs, or other relevant evidence that:

(1) An upset occurred and that the permitt ee can identify the cause(s) of the upset;

(2) The permitted facility was at the time being properly operated;

(3) The permittee submitted notice of the upset as required in Condition VIII.20. of this permit;

and

(4) The permittee complied with any remedial meas ures required under Condition VIII.5. of this

permit.

b. In any enforcement proceeding, the burden of proof for establishing the occurrence of an upset

rests with the permittee.

c. Before an enforcement proceeding is ins tituted, no representation made during the Department

review of a claim that noncompliance was caused by an upset is final agency action subject to

judicial review.

[62-620.610(23), F.A.C.]

Executed in Jacksonville, Florida.

STATE OF FLORIDA DEPARTMENT OF

ENVIRONMENTAL PROTECTION

Melissa M. L ong, P.E.

Program Administrator

Water and Environmental Resource Permitting

DATE: March 18, 2013

# AMENDED FACT SHEET

FOR

FLORIDA DEPARTMENT OF ENVIRONMENTAL PROTECTION

INDUSTRIAL WASTEWATER FACILITY PERMIT



# PERMIT NUMBER: FL0000655-006-IW1S (Major)

FACILITY NAME: PCS Phosphate – White Springs

FACILITY LOCATION: County Road 137, north of White Springs

White Springs, Hamilton County, Florida 32096

NAME OF PERMITTEE: PCS Phosphate

PERMIT REVISION WRITER: Kath eryn Jarvis/ John Davis, P.G.

REVISION APPLICATION DATE: December 12, 2012

The groundwater monitoring plan is being revised in accordance with requirements of the current Consent

Order (10-1878). The current groun dwater monitoring is as follows:

Monitoring

Well ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

MWBSC/SRB 30o 28’ 01” N 82o 49’ 30” W 30 Surficial Existing

MWI-SC1S 30o 27’ 03” N 82o 53’ 09” W 36 Surficial Existing

MWI-SC2S 30o 27’ 03” N 82o 53’ 09” W 36 Surficial Existing

MWI-SC3S 30o 26’ 31” N 82o 52’ 37” W 52 Surficial Existing

MWI-SC4S 30o 26’ 32” N 82o 52’ 38” W 41 Surficial Existing

MWI-SC4D Adjacent to SC-4S 61 Surficial Existing

MWI-SC5S 30o 27’ 20” N 82o 53’ 20” W 30 Surficial Existing

MWI-SC5D Adjacent to SC-5S 61 Surficial Existing

MWC-SC6 30o 27’ 05” N 82o 55’ 40” W 28 Surficial Existing

MWC-SC7 30o 25’ 31” N 82o 54’ 16” W 28 Surficial Existing

MWC-SC9S 30°25’15”N 82°47’11”W 30 Surficial Existing

MWC-SC10 TBD TBD ≈ 35 Surficial Existing

MWC-SC11 TBD TBD ≈ 35 Surficial Existing

MWC-SCG1 30o 24’ 01” N 82o 50’ 04” W 33 Surficial Existing

MWI-SR3S 30o 25’ 47” N 82o 47’ 43” W 41 Surficial Existing

MWI-SR7S 30o 26’ 54” N 82o 48’ 05” W 35 Surficial Existing

MWI-SR7D Adjacent to SR-7S 50 Surficial Existing

MWI-SR8S 30o 26’ 21” N 82o 47’ 51” W 30 Surficial Existing

MWI-SR8D Adjacent to SR-8S 55 Surficial Existing

# PCS Phosphate – White Springs

FL0000655-006

Page 2 of 4

2 

# Monitoring

Well ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

MWC-SR8F Adjacent to SR-8S 210 Floridan Existing

MWI-SR9S 30o 25’ 14” N 82o 47’ 10” W 30 Surficial Existing

MWC-SRA1 30o 24’ 04” N 82o 47’ 21” W 22 Surficial Existing

MWC-SRM1 30o 25’ 49” N 82o 45’ 43” W 41 Surficial Existing

MWC-SR10 TBD TBD ≈ 35 Surficial Existing

MWC-SR11 TBD TBD ≈ 35 Surficial Existing

MWC-SR12 TBD TBD ≈ 35 Surficial Existing

MWB = Background; MWI = Intermediate; MW C = Compliance TBD = To be determined



# The facility will continue monito ring as required above through the 2 nd 

# quarter of 2013. Beginning in the

3 rd 

# quarter of 2013, the groundwater monito ring will change to the following:

SWIFT CREEK COMPLEX

Monitoring Well

ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

B MWB-SC/SRB 30o 28’ 01”N 82o 49’ 30”W 30 Surficial Existing

I MWI -EPA-11S 30° 26' 36”N 82° 53' 01”W 57 Surficial Existing

I MWI-EPA-15S 30° 27' 17”N 82° 51' 44”W 26.5 Surficial Existing

I MWI-EPA-15D Adjacent to EPA-15S 47 Surficial Existing

C MWC-EPA-16S 30° 27' 02”N 82° 51' 26”W 30 Surficial Existing

C MWC-EPA-16D Adjacent to EPA-16S 50 Surficial Existing

I MWI-EPA-18S 30° 26' 13”N 82° 52' 06”W 47 Surficial Existing

# PCS Phosphate – White Springs

FL0000655-006

Page 3 of 4

3 

# Monitoring Well

ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

I MWI-SC5S 30o 27’20” N 82o 53’ 20”W 30 Surficial Existing

I MWI-SC5D Adjacent to SC-5S 61 Surficial Existing

C MWC-SC-12S  30°28’01”N  82° 52‘ 15”W  30 Surficial New

C MWC-SC-12D Adjacent to SC-12S  60 Surficial New

C MWC-SC-13S  30°27’59”N  82° 53’ 45”W  30 Surficial New

C MWC-SC-13D Adjacent to SC-13S  60 Surficial New

C MWC-SC-14D  30°26’50”N  82° 53’ 41”W  60 Surficial New

C MWC-SC-15D  30°26’08”N  82° 52’ 59”W  60 Surficial New

C MWC-SC-16S  30°26’05”N  82° 51’ 55”W  30 Surficial New

C MWC-SC-16D Adjacent to SC-16S  60 Surficial New

C MWC-SC-17S  30°27’30”N  82° 51’ 50”W  30 Surficial New

C MWC-SC-17D Adjacent to SC-17S  60 Surficial New

C MWC-SC-4F 30° 26' 32”N 82° 52' 37”W 240 Floridan Existing

C MWC-SC-5F 30° 27' 22”N 82° 53' 29”W 240 Floridan Existing

C MWC-MC-3FS 30° 27' 04”N 82° 51' 54”W 204 Floridan Existing

C MWC-C-CW (SC5) 30° 26' 45”N 82° 52' 01”W 216 Floridan Existing

B = Background; I = Intermediate; C = Compliance



# Copyrighted map removed

# PCS Phosphate – White Springs

FL0000655-006

Page 4 of 4

4 

# SUWANNEE RIVER COMPLEX

Monitoring Well

ID Alternate Well Name and/or

Description of Monitoring Location Depth

(Feet) Aquifer

Monitored New or

Existing

B MWB-SC/SRB 30o 28’ 01” N 82o 49’ 30” W 30 Surficial Existing

C MWC-SR-1SR 30° 27' 12”N 82° 46' 05”W 39.5 Surficial Existing

C MWC-SRM1 30o 25’ 49” N 82o 45’ 43” W 41 Surficial Existing

I MWI-EPA-P1-C 30° 26' 38”N 82° 48' 03”W 58 Surficial Existing

I MWI-EPA-4D 30° 26' 39”N 82° 48' 02”W 67 Surficial Existing

C MWC-EPA-23D 30° 26' 12”N 82° 45' 48”W 45 Surficial Existing

C MWC-SR-1D  30°27’10”N  82°46’06”W  30 Surficial New

C MWC-SR9S 30°25’15”N 82°47’11”W 30 Surficial Existing

C MWC-SR9D  30°24’15”N  82°47’13”W  60 Surficial New

C MWC-SR-13S  30°27’25”N  82°48’26”W  30 Surficial New

C MWC-SR-13D Adjacent to SR-13S  60 Surficial New

C MWC-SR-14S  30°26’31”N  82°48’26”W  30 Surficial New

C MWC-SR-14D Adjacent to SR-14S  60 Surficial New

C MWC-SR-15D  30°25’24”N  82°48’24”W  60 Surficial New

C MWC-SR-16S  30°27’50”N  82°47’01”W  30 Surficial New

C MWC-SR-16D Adjacent to SR-16S  60 Surficial New

C MWC-SR-17S  30°27’51”N  82° 47’45”W  30 Surficial New

C MWC-SR-17D Adjacent to SR-17S  60 Surficial New

C MWC-SRC-CD5 30° 26' 40”N 82° 47' 04”W 316 Floridan Existing

C MWC-SR8F 30o 26’ 21”N 82o 47’ 51”W 210 Floridan Existing

C MWC-FAS-DORR 30° 26' 22”N 82° 46' 49”W 240 Floridan Existing

C MWC-Moretrench 30° 26' 50”N 82° 48' 00”W 220 Floridan Existing

B = Background; I = Intermediate; C = Compliance



# Copyrighted map removed

# www.dep.state.fl.us 

# F LORIDA 

# D EPARTMENT OF



# E NVIRONMENTAL 

# P ROTECTION

NORTHEAST DISTRICT

8800 BAYMEADOWS WAY WEST, SUITE 10 0

JACKSONVILLE, FLORIDA 32256 RICK SCOTT

GOVERNOR

HERSCHEL T. VINYARD JR.

SECRETARY



# MEMORANDUM

TO: WWTF PERMITTEE AND OPERATOR

FROM: FDEP – NORTHEAST DISTRICT

SUBJECT: ELECTRONIC DISCH ARGE MONITORING REPORT

DATE: MARCH 18, 2013

Attached is the hard copy Discharge Monitori ng Report (DMR) for your facility. However as

part of the Department’s ongoing efforts to impr ove business processes, we have been working

with members of the regulated community to provide new and more efficient paperless

alternatives for environmental reporting by util izing electronic submittal via the internet.

The Department’s web-enabled electronic DMR (e DMR) system offers the advantage of less

process for the regulated community. By offe ring several streamlined reporting options, the

system offers significant labor savings for both the Department and the regulated community.

Most importantly, while saving these costs, the system also increases timeliness.

All wastewater facilities should stro ngly consider participating in eDMR . Most wastewater

facilities are required to submit to the Departme nt a monthly DMR which typically summarizes

effluent quality or groundwater monitoring well results. eDMR simply provides an alternative

way for facilities to submit these wastewater re ports. Using an electronic process for submitting

reports can represent significant labor savings while greatly increas ing the data entry efficiency,

accuracy, and overall reliability of this information.

Some of the benefits of eDMRs and the eDMR System include:

 Save wastewater discharge facilities complia nce costs with a streamlined reporting method

and readily available computer tools,

 Save program costs by reducing resources required for managing paper-based DMRs,

 Improve accuracy of compliance data by eliminati ng potential errors that might otherwise be

introduced through manual data entry in the database, and

 Improve the DEP wastewater program's overall e ffectiveness with faster responses to data

analyses, compliance assessment, and decision-making.

To sign-up for eDMR, please contact the eDMR ad ministrator in Tallahassee by phone at (850)

245-8567, by email at edmradmin@dep.state.fl.us or please visit our webpage at

http://www.dep.state.fl.us/water/wastewater/wce/edmr/

Thank you in advance for your participation.Version: March 18, 2013 – Effective: July 1, 2013 – Page1 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENTOF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER:FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT:FinalREPORT:MonthlyCLASS SIZE:MAPROGRAM:IndustrialFACILITY:PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-001LOCATION:CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: 001 DISCHARGE TO SWIFT CREEK15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300NO DISCHARGE FROM SITE:COUNTY:HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE:NortheastDistrictParameterQuantityorLoadingUnitsQuality or ConcentrationUnitsNo.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDDaily, whendischargingCalculatedOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 1Mon. Site No. EFF-1PermitRequirement5.0(Min.)Report(Mo.Avg.)mg/LWeeklyIn-situ, midstream andmid-depthSolids, Total SuspendedSampleMeasurementPARM Code 00530 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCFluoride, Total (as F)SampleMeasurementPARM Code 00951 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)10.0(Day.Max.)mg/LWeekly24-hr TPCSpecific ConductanceSampleMeasurementPARM Code 00095 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)1275(Day.Max.)umhos/cmWeekly24-hr TPCTemperature (C), WaterSampleMeasurementPARM Code 00010 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)Deg CWeeklyGrab or In-situI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page2 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:D-001 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypepHSampleMeasurementPARM Code 00400 1Mon. Site No. EFF-1PermitRequirement6.0(Day.Min.)8.5(Day.Max.)s.u.WeeklyGrab or In-situTurbiditySampleMeasurementPARM Code 00070 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)31.0(Day.Max.)NTUWeeklyGrabNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCAmmonia, Unionized (as NH3)SampleMeasurementPARM Code 00619 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)0.02(Day.Max.)mg/LWeeklyCalculatedNitrogen, Kjeldahl, Total (as N)SampleMeasurementPARM Code 00625 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 1Mon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. EFF-1PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedVersion: March 18, 2013 – Effective: July 1, 2013 – Page3 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: QuarterlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-001LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: 001 DISCHARGE TO SWIFT CREEK15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeRadium 226 + Radium 228, TotalSampleMeasurementPARM Code 11503 1Mon. Site No. EFF-1PermitRequirement5.0(Day.Max.)pCi/LQuarterly24-hr TPCAlpha, Gross Particle ActivitySampleMeasurementPARM Code 80045 1Mon. Site No. EFF-1PermitRequirement15.0(Day.Max.)pCi/LQuarterly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page4 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: Quarterly ToxicityCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-001LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: 001 DISCHARGE TO SWIFT CREEK15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY:OFFICE:HamiltonNortheast DistrictMONITORING PERIOD (check one)___ Jan 01to Mar 31, 20 _______ April 01 to June 30, 20 _______ Jul 01to Sept 30, 20 _______ Oct 01to Dec 31, 20 ____Parameter Quantity or LoadingUnits Quality or ConcentrationResults*Units No.Ex.Frequency ofAnalysisSample Type7-DAY STATRE CHRONICCeriodaphnia dubia(Routine)SampleMeasurementPARM Code TRP3B PMon. Site No. EFF-1PermitRequirement100(Min.)percentQuarterly24-hr TPC7-DAY STATRE CHRONICCeriodaphnia dubia(Additional) **SampleMeasurementPARM Code TRP3B QMon. Site No. EFF-1PermitRequirement100(Min.)percentAs neededAs required by thepermit7-DAY STATRE CHRONICCeriodaphnia dubia(Additional) **SampleMeasurementPARM Code TRP3B RMon. Site No. EFF-1PermitRequirement100(Min.)percentAs neededAs required by thepermit7-DAY STATRE CHRONICPimephales promelas(Routine)SampleMeasurementPARM Code TRP6C PMon. Site No. EFF-1PermitRequirement100(Min.)percentQuarterly24-hr TPC7-DAY STATRE CHRONICPimephales promelas(Additional) **SampleMeasurementPARM Code TRP6C QMon. Site No. EFF-1PermitRequirement100(Min.)percentAs neededAs required by thepermit7-DAY STATRE CHRONICPimephales promelas(Additional) **SampleMeasurementPARM Code TRP6C RMon. Site No. EFF-1PermitRequirement100(Min.)percentAs neededAs required by thepermit* ENTER “MNR” IN THE RESULTS BOX WHEN “MONITORING NOT REQUIRED” FOR ADDITIONAL TESTS IN THIS MONITORING PERIOD.** IF ADDITIONAL TESTS ARE REQUIRED, THEN ENTER THE RESULTS IN ROWS “Q” and “R”.I certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on my inquiryof the person or persons who manage thesystem, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page5 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-002LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: 002 STREAM FLOW OF HUNTER CREEK @ SR13615843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD4 Days/WeekCalculatedTotal Non-Volatile Non-FilterableResidueSampleMeasurementPARM Code 82287 1Mon. Site No. EFF-2PermitRequirement12(Mo.Avg.)25(Day.Max.)mg/L2 Days/Week24-hr TPCSolids, Total SuspendedSampleMeasurementPARM Code 00530 1Mon. Site No. EFF-2PermitRequirement30(Mo.Avg.)60(Day.Max.)mg/L2 Days/Week24-hr TPCOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 1Mon. Site No. EFF-2PermitRequirement5.0(Day.Min.)Report(Mo.Avg.)mg/LWeeklyIn-situSpecific ConductanceSampleMeasurementPARM Code 00095 1Mon. Site No. EFF-2PermitRequirement1275(Day.Max.)umhos/cmWeeklyGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)10.0(Day.Max.)mg/LWeekly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page6 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:D-002 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeAmmonia, Unionized (as NH3)SampleMeasurementPARM Code 00619 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)0.02(Day.Max.)mg/LWeeklyCalculatedNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabTemperature (C), WaterSampleMeasurementPARM Code 00010 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)Report(Day.Max.)Deg CWeeklyGrab or In-situTurbiditySampleMeasurementPARM Code 00070 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)31.0(Day.Max.)NTUWeeklyGrabpHSampleMeasurementPARM Code 00400 1Mon. Site No. EFF-2PermitRequirement6.0(Day.Min.)8.5(Day.Max.)s.u.WeeklyGrab or In-situPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 1Mon. Site No. EFF-2PermitRequirement3.0(Mo.Avg.)5.0(Day.Max.)mg/LWeekly24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedNitrogen, Kjeldahl, Total (as N)SampleMeasurementPARM Code 00625 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 1Mon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. EFF-2PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedVersion: March 18, 2013 – Effective: July 1, 2013 – Page7 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: QuarterlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-002LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: 002 STREAM FLOW OF HUNTER CREEK @ SR13615843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeRadium 226 + Radium 228, TotalSampleMeasurementPARM Code 11503 1Mon. Site No. EFF-2PermitRequirement5.0(Day.Max.)pCi/LQuarterly24-hr TPCAlpha, Gross Particle ActivitySampleMeasurementPARM Code 80045 1Mon. Site No. EFF-2PermitRequirement15.0(Day.Max.)pCi/LQuarterly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page8 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: Quarterly ToxicityCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-002LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: 002 STREAM FLOW OF HUNTER CREEK @ SR13615843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonOFFICE: Northeast District MONITORING PERIOD (check)___ Jan 01to March 31, 20 _______ April 01 to June 30, 20 ______ July 01to Sept 30, 20 _______ Oct 01to Dec 31, 20 ____Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Routine)SampleMeasurementPARM Code TAN3B PMon. Site No. EFF-2PermitRequirement100(Min.)percentQuarterlyGrabLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Additional)SampleMeasurementPARM Code TAN3B Q**Mon. Site No. EFF-2PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Additional)SampleMeasurementPARM Code TAN3B R**Mon. Site No. EFF-2PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECyprinella leedsi(Routine)SampleMeasurementPARM Code TAN6H PMon. Site No. EFF-2PermitRequirement100(Min.)percentQuarterlyGrabLC50 STATRE 96HOUR ACUTECyprinella leedsi(Additional)SampleMeasurementPARM Code TAN6H Q**Mon. Site No. EFF-2PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECyprinella leedsi(Additional)SampleMeasurementPARM Code TAN6H R**Mon. Site No. EFF-2PermitRequirement100(Min.)percentAs neededAs required by thepermit*ENTER “MNR IN THE RESULTS BOX WHEN “MONITORING NOT REQUIRED” FOR ADDITIONAL TESTS IN THIS MONITORING PERIOD.** IF ADDITIONAL TESTS ARE REQUIRED, THEN ENTER THE RESULTS IN ROWS “Q” AND “R”.I certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on my inquiryof the person or persons who manage thesystem, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page9 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-003LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Roaring Creek15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD4 Days/WeekCalculatedTotal Non-Volatile Non-FilterableResidueSampleMeasurementPARM Code 82287 1Mon. Site No. EFF-3PermitRequirement12(Mo.Avg.)25(Day.Max.)mg/L2 Days/Week24-hr TPCSolids, Total SuspendedSampleMeasurementPARM Code 00530 1Mon. Site No. EFF-3PermitRequirement30(Mo.Avg.)60(Day.Max.)mg/L2 Days/Week24-hr TPCOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 1Mon. Site No. EFF-3PermitRequirement5.0(Day.Min.)Report(Mo.Avg.)mg/LWeeklyIn-situSpecific ConductanceSampleMeasurementPARM Code 00095 1Mon. Site No. EFF-3PermitRequirement1275(Day.Max.)umhos/cmWeeklyGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)10.0(Day.Max.)mg/LWeekly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page10 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:D-003 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeAmmonia, Unionized (as NH3)SampleMeasurementPARM Code 00619 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)0.02(Day.Max.)mg/LWeeklyCalculatedNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabTemperature (C), WaterSampleMeasurementPARM Code 00010 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)Report(Day.Max.)Deg CWeeklyGrab or In-situTurbiditySampleMeasurementPARM Code 00070 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)31.0(Day.Max.)NTUWeeklyGrabpHSampleMeasurementPARM Code 00400 1Mon. Site No. EFF-3PermitRequirement6.0(Day.Min.)8.5(Day.Max.)s.u.WeeklyGrab or In-situPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 1Mon. Site No. EFF-3PermitRequirement3.0(Mo.Avg.)5.0(Day.Max.)mg/LWeekly24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedNitrogen, Kjeldahl, Total (as N)SampleMeasurementPARM Code 00625 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 1Mon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. EFF-3PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedVersion: March 18, 2013 – Effective: July 1, 2013 – Page11 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: QuarterlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-003LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Roaring Creek15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeRadium 226 + Radium 228, TotalSampleMeasurementPARM Code 11503 1Mon. Site No. EFF-3PermitRequirement5.0(Day.Max.)pCi/LQuarterly24-hr TPCAlpha, Gross Particle ActivitySampleMeasurementPARM Code 80045 1Mon. Site No. EFF-3PermitRequirement15.0(Day.Max.)pCi/LQuarterly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page12 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: Quarterly ToxicityCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-003LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Roaring Creek15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonOFFICE: Northeast District MONITORING PERIOD (check)___ Jan 01to March 31, 20 _______ April 01 to June 30, 20 ______ July 01to Sept 30, 20 _______ October 01to December 31, 20 ____Parameter Quantity or LoadingUnits Quality or ConcentrationResults*Units No.Ex.Frequency ofAnalysisSample TypeLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Routine)SampleMeasurementPARM Code TAN3B PMon. Site No. EFF-3PermitRequirement100(Min.)percentQuarterlyGrabLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Additional)SampleMeasurementPARM Code TAN3B Q**Mon. Site No. EFF-3PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Additional)SampleMeasurementPARM Code TAN3B R**Mon. Site No. EFF-3PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECyprinella leedsi(Routine)SampleMeasurementPARM Code TAN6H PMon. Site No. EFF-3PermitRequirement100(Min.)percentQuarterlyGrabLC50 STATRE 96HOUR ACUTECyprinella leedsi(Additional)SampleMeasurementPARM Code TAN6H Q**Mon. Site No. EFF-3PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECyprinella leedsi(Additional)SampleMeasurementPARM Code TAN6H R**Mon. Site No. EFF-3PermitRequirement100(Min.)percentAs neededAs required by thepermit*ENTER “MNR IN THE RESULTS BOX WHEN “MONITORING NOT REQUIRED” FOR ADDITIONAL TESTS IN THIS MONITORING PERIOD.** IF ADDITIONAL TESTS ARE REQUIRED, THEN ENTER THE RESULTS IN ROWS “Q”, “R”, AND “S”.I certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on my inquiryof the person or persons who manage thesystem, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page13 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-004LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Camp Branch15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 1Mon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD2 Days/WeekCalculatedpHSampleMeasurementPARM Code 00400 1Mon. Site No. EFF-4PermitRequirement6.0(Day.Min.)8.5(Day.Max.)s.u.2 Days/WeekGrab or In-situSolids, Total SuspendedSampleMeasurementPARM Code 00530 1Mon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 1Mon. Site No. EFF-4PermitRequirement5.0(Day.Min.)Report(Mo.Avg.)mg/LWeeklyIn-situFluoride, Total (as F)SampleMeasurementPARM Code 00951 1Mon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)10.0(Day.Max.)mg/LWeekly24-hr TPCSpecific ConductanceSampleMeasurementPARM Code 00095 1Mon. Site No. EFF-4PermitRequirement1275(Day.Max.)umhos/cmWeeklyGrabI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page14 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:D-004 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeTurbiditySampleMeasurementPARM Code 00070 1Mon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)31.0(Day.Max.)NTUWeeklyGrabPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 1Mon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedNitrogen, TotalSampleMeasurementPARM Code 00600 1Mon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. EFF-4PermitRequirementReport(Mo.Avg.)lb/dayWeeklyCalculatedVersion: March 18, 2013 – Effective: July 1, 2013 – Page15 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: Quarterly ToxicityCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-C41LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Camp Branch through D-00415843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonOFFICE: Northeast DistrictMONITORING PERIOD (check)___ Jan 01to March 31, 20 _______ April 01 to June 30, 20 ______ July 01to Sept 30, 20 _______ October 01to December 31, 20____Parameter Quantity or LoadingUnits Quality or ConcentrationResults*Units No.Ex.Frequency ofAnalysisSample TypeLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Routine)SampleMeasurementPARM Code TAN3B PMon. Site No. OUI-41PermitRequirement100(Min.)percentQuarterlyGrabLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Additional)SampleMeasurementPARM Code TAN3B Q**Mon. Site No. OUI-41PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECeriodaphnia dubia(Additional)SampleMeasurementPARM Code TAN3B R**Mon. Site No. OUI-41PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECyprinella leedsi(Routine)SampleMeasurementPARM Code TAN6H PMon. Site No. OUI-41PermitRequirement100(Min.)percentQuarterlyGrabLC50 STATRE 96HOUR ACUTECyprinella leedsi(Additional)SampleMeasurementPARM Code TAN6H Q**Mon. Site No. OUI-41PermitRequirement100(Min.)percentAs neededAs required by thepermitLC50 STATRE 96HOUR ACUTECyprinella leedsi(Additional)SampleMeasurementPARM Code TAN6H R**Mon. Site No. OUI-41PermitRequirement100(Min.)percentAs neededAs required by thepermit*ENTER “MNR IN THE RESULTS BOX WHEN “MONITORING NOT REQUIRED” FOR ADDITIONAL TESTS IN THIS MONITORING PERIOD.** IF ADDITIONAL TESTS ARE REQUIRED, THEN ENTER THE RESULTS IN ROWS “Q” AND “R”.I certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on my inquiryof the person or persons who manage thesystem, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page16 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: D-SUMLOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: SUM OF PHOSPHORUS AND NITROGEN D-001, D-002,D- 004(OUI-41)15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypePhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OTH-SUMPermitRequirement5901(Mo.Avg.)lb/dayWeeklyCalculatedNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OTH-SUMPermitRequirement4013(Mo.Avg.)lb/dayWeeklyCalculatedI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page17 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-C41LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Camp Branch through D-00415843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuousMeterTotal Non-Volatile Non-FilterableResidueSampleMeasurementPARM Code 82287 1Mon. Site No. OUI-41PermitRequirement12(Mo.Avg.)25(Day.Max.)mg/L2 Days/Week24-hr TPCSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-41PermitRequirement30.0(Mo.Avg.)60.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-41PermitRequirement3.0(Mo.Avg.)5.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 QMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)lb/day2 Days/WeekCalculatedpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-41PermitRequirement6.0(Day.Min.)8.5(Day.Max.)s.u.2 Days/WeekGrabI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page18 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-C41 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/Week24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 QMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)lb/day2 Days/WeekCalculatedTurbiditySampleMeasurementPARM Code 00070 PMon. Site No. OUI-41PermitRequirementReport(Day.Max.)NTUWeekly24-hr TPCTemperature (C), WaterSampleMeasurementPARM Code 00010 PMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)Report(Day.Max.)Deg CWeeklyGrab or In-situOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 PMon. Site No. OUI-41PermitRequirement5.0(Day.Min.)Report(Mo.Avg.)mg/LWeeklyIn-situAmmonia, Unionized (as NH3)SampleMeasurementPARM Code 00619 PMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)0.02(Day.Max.)mg/LWeeklyCalculatedNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 PMon. Site No. OUI-41PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeekly24-hr TPCVersion: March 18, 2013 – Effective: July 1, 2013 – Page19 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: QuarterlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-C41LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Camp Branch through D-00415843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeRadium 226 + Radium 228, TotalSampleMeasurementPARM Code 11503 PMon. Site No. OUI-41PermitRequirement5.0(Day.Max.)pCi/LQuarterly24-hr TPCAlpha, Gross Particle ActivitySampleMeasurementPARM Code 80045 PMon. Site No. OUI-41PermitRequirement15.0(Day.Max.)pCi/LQuarterly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page20 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S02LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Altman Bay Canal to Swift Creek15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-02PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuousMeterFluoride, Total (as F)SampleMeasurementPARM Code 00951 PMon. Site No. OUI-02PermitRequirement25.0(Mo.Avg.)75.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-02PermitRequirement35.0(Mo.Avg.)105.0(Day.Max.)mg/L2 Days/Week24-hr TPCpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-02PermitRequirement6.0(Day.Min.)9.5(Day.Max.)s.u.2 Days/WeekGrabNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-02PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/Week24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 QMon. Site No. OUI-02PermitRequirementReport(Mo.Avg.)lb/day2 Days/WeekCalculatedI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page21 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S03LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to clay settling areas and the Altman Bay retention pond15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-03PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuousMeterFluoride, Total (as F)SampleMeasurementPARM Code 00951 PMon. Site No. OUI-03PermitRequirement25.0(Mo.Avg.)75.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-03PermitRequirement35.0(Mo.Avg.)105.0(Day.Max.)mg/L2 Days/Week24-hr TPCpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-03PermitRequirement6.0(Day.Min.)9.5(Day.Max.)s.u.2 Days/WeekGrabNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-03PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/Week24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 QMon. Site No. OUI-03PermitRequirementReport(Mo.Avg.)lb/day2 Days/WeekCalculatedI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page22 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S04LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Swift Creek via D-00115843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-04PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDWeeklyCalculatedNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 PMon. Site No. OUI-04PermitRequirement4.0(Mo.Avg.)mg/LWeeklyGrabAmmonia, Unionized (as NH3)SampleMeasurementPARM Code 00619 PMon. Site No. OUI-04PermitRequirementReport(Mo.Avg.)0.02(Day.Max.)mg/LWeeklyCalculatedOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 PMon. Site No. OUI-04PermitRequirement5.0(Day.Min.)Report(Mo.Avg.)mg/LWeeklyGrab or In-situTemperature (C), WaterSampleMeasurementPARM Code 00010 PMon. Site No. OUI-04PermitRequirementReport(Mo.Avg.)Report(Day.Max.)Deg CWeeklyGrab or In-situpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-04PermitRequirement6.0(Day.Min.)8.5(Day.Max.)s.u.WeeklyGrab or In-situI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page23 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S06LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Swift Creek through I-S04 to D-00115843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-06PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuousMeterSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-06PermitRequirement50.0(Mo.Avg.)150.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-06PermitRequirement35.0(Mo.Avg.)105.0(Day.Max.)mg/L2 Days/Week24-hr TPCpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-06PermitRequirement6.0(Day.Min.)9.5(Day.Max.)s.u.2 Days/WeekGrab or In-situTurbiditySampleMeasurementPARM Code 00070 PMon. Site No. OUI-06PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/Week24-hr TPCFluoride, Total (as F)SampleMeasurementPARM Code 00951 PMon. Site No. OUI-06PermitRequirement25.0(Mo.Avg.)75.0(Day.Max.)mg/L2 Days/Week24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page24 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S07LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Swift Creek through I-S04 to D-00115843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-07PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD4 Days/WeekCalculatedTotal Non-Volatile Non-FilterableResidueSampleMeasurementPARM Code 82287 1Mon. Site No. OUI-07PermitRequirement12(Mo.Avg.)25(Day.Max.)mg/L2 Days/Week24-hr TPCSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-07PermitRequirement30.0(Mo.Avg.)60.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-07PermitRequirement3.0(Mo.Avg.)5.0(Day.Max.)mg/L2 Days/Week24-hr TPCTurbiditySampleMeasurementPARM Code 00070 PMon. Site No. OUI-07PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/Week24-hr TPCpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-07PermitRequirement6.0(Day.Min.)9.0(Day.Max.)s.u.2 Days/WeekGrab or In-situI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page25 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S08LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Spray Irrigation15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuous orCalculatedMeterSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabTurbiditySampleMeasurementPARM Code 00070 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/WeekGrabPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 YMon. Site No. OUI-08PermitRequirementReport(An.Avg.)lb/day2 Days/WeekCalculatedPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page26 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-S08 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeNitrogen, TotalSampleMeasurementPARM Code 00600 YMon. Site No. OUI-08PermitRequirementReport(An.Avg.)lb/dayWeeklyCalculatedNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-08PermitRequirementReport(Mo.Min.)Report(Mo.Max.)s.u.WeeklyGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabSpecific ConductanceSampleMeasurementPARM Code 00095 PMon. Site No. OUI-08PermitRequirementReport(Mo.Avg.)Report(Day.Max.)umhos/cmWeeklyGrabFlowSampleMeasurementPARM Code 50050 QMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuous orCalculatedMeterSolids, Total SuspendedSampleMeasurementPARM Code 00530 QMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabTurbiditySampleMeasurementPARM Code 00070 QMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/WeekGrabPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 QMon. Site No. OUI-11PermitRequirementReport(An.Avg.)lb/day2 Days/WeekCalculatedPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 RMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabVersion: March 18, 2013 – Effective: July 1, 2013 – Page27 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-S08 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 QMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabNitrogen, TotalSampleMeasurementPARM Code 00600 QMon. Site No. OUI-11PermitRequirementReport(An.Avg.)lb/dayWeeklyCalculatedNitrogen, TotalSampleMeasurementPARM Code 00600 RMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabpHSampleMeasurementPARM Code 00400 QMon. Site No. OUI-11PermitRequirementReport(Daily.Min.)Report(Daily.Max.)s.u.WeeklyGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 QMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabSpecific ConductanceSampleMeasurementPARM Code 00095 QMon. Site No. OUI-11PermitRequirementReport(Mo.Avg.)Report(Day.Max.)umhos/cmWeeklyGrabFlowSampleMeasurementPARM Code 50050 RMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD2 Days/WeekCalculatedSolids, Total SuspendedSampleMeasurementPARM Code 00530 RMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabTurbiditySampleMeasurementPARM Code 00070 RMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/WeekGrabPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 SMon. Site No. OUI-12PermitRequirementReport(An.Avg.)lb/day2 Days/WeekCalculatedVersion: March 18, 2013 – Effective: July 1, 2013 – Page28 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-S08 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypePhosphorus, Total (as P)SampleMeasurementPARM Code 00665 TMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 RMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabNitrogen, TotalSampleMeasurementPARM Code 00600 SMon. Site No. OUI-12PermitRequirementReport(An.Avg.)lb/dayWeeklyCalculatedNitrogen, TotalSampleMeasurementPARM Code 00600 TMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabpHSampleMeasurementPARM Code 00400 RMon. Site No. OUI-12PermitRequirementReport(Mo.Min.)Report(Mo.Max.)s.u.WeeklyGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 RMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabSpecific ConductanceSampleMeasurementPARM Code 00095 RMon. Site No. OUI-12PermitRequirementReport(Mo.Avg.)Report(Day.Max.)umhos/cmWeeklyGrabFlowSampleMeasurementPARM Code 50050 SMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD2 Days/WeekCalculatedSolids, Total SuspendedSampleMeasurementPARM Code 00530 SMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabTurbiditySampleMeasurementPARM Code 00070 SMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/WeekGrabVersion: March 18, 2013 – Effective: July 1, 2013 – Page29 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-S08 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypePhosphorus, Total (as P)SampleMeasurementPARM Code 00665 UMon. Site No. OUI-13PermitRequirementReport(An.Avg.)lb/day2 Days/WeekCalculatedPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 VMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 SMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabNitrogen, TotalSampleMeasurementPARM Code 00600 UMon. Site No. OUI-13PermitRequirementReport(An.Avg.)lb/dayWeeklyCalculatedNitrogen, TotalSampleMeasurementPARM Code 00600 VMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabpHSampleMeasurementPARM Code 00400 SMon. Site No. OUI-13PermitRequirementReport(Mo.Min.)Report(Mo.Max.)s.u.WeeklyGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 SMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/LWeeklyGrabSpecific ConductanceSampleMeasurementPARM Code 00095 SMon. Site No. OUI-13PermitRequirementReport(Mo.Avg.)Report(Day.Max.)umhos/cmWeeklyGrabVersion: March 18, 2013 – Effective: July 1, 2013 – Page30 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S09LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Swift Creek through I-S04 to D-00115843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-09PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD4 Days/WeekCalculatedTotal Non-Volatile Non-FilterableResidueSampleMeasurementPARM Code 82287 1Mon. Site No. OUI-09PermitRequirement12(Mo.Avg.)25(Day.Max.)mg/L2 Days/Week24-hr TPCSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-09PermitRequirement30.0(Mo.Avg.)60.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-09PermitRequirement3.0(Mo.Avg.)5.0(Day.Max.)mg/L2 Days/Week24-hr TPCTurbiditySampleMeasurementPARM Code 00070 PMon. Site No. OUI-09PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/Week24-hr TPCpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-09PermitRequirement6.0(Day.Min.)9.0(Day.Max.)s.u.2 Days/WeekGrab or In-situI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page31 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S18LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Swift Creek via D-00115843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-18PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuousMeterTotal Non-Volatile Non-FilterableResidueSampleMeasurementPARM Code 82287 1Mon. Site No. OUI-18PermitRequirement12(Mo.Avg.)25(Day.Max.)mg/L2 Days/WeekGrabSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-18PermitRequirement30(Mo.Avg.)60(Day.Max.)mg/L2 Days/WeekGrabNitrogen, Ammonia, Total (as N)SampleMeasurementPARM Code 00610 PMon. Site No. OUI-18PermitRequirementReport(Mo.Avg.)4.0(Day.Max.)mg/L2 Days/WeekGrabAmmonia, Unionized (as NH3)SampleMeasurementPARM Code 00619 PMon. Site No. OUI-18PermitRequirementReport(Mo.Avg.)0.02(Day.Max.)mg/L2 Days/WeekCalculatedOxygen, Dissolved (DO)SampleMeasurementPARM Code 00300 PMon. Site No. OUI-18PermitRequirement5.0(Day.Min.)mg/L2 Days/WeekGrab or In-situI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page32 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-S18 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeTemperature (C), WaterSampleMeasurementPARM Code 00010 PMon. Site No. OUI-18PermitRequirementReport(Mo.Avg.)Report(Day.Max.)Deg C2 Days/WeekGrab or In-situPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-18PermitRequirement3.0(Mo.Avg.)5.0(Day.Max.)mg/L2 Days/WeekGrabNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-18PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/Week24-hr TPCNitrogen, TotalSampleMeasurementPARM Code 00600 QMon. Site No. OUI-18PermitRequirementReport(Mo.Avg.)lb/day2 Days/WeekCalculatedpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-18PermitRequirement6.0(Day.Min.)9.0(Day.Max.)s.u.2 Days/WeekGrab or In-situVersion: March 18, 2013 – Effective: July 1, 2013 – Page33 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: QuarterlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S18LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Swift Creek via D-00115843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeRadium 226 + Radium 228, TotalSampleMeasurementPARM Code 11503 PMon. Site No. OUI-18PermitRequirement5.0(Day.Max.)pCi/LQuarterly24-hr TPCAlpha, Gross Particle ActivitySampleMeasurementPARM Code 80045 PMon. Site No. OUI-18PermitRequirement15.0(Day.Max.)pCi/LQuarterly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page34 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S22LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to Eagle Lake15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-22PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGDContinuousMeterPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-22PermitRequirement35.0(Mo.Avg.)105.0(Day.Max.)mg/L2 Days/Week24-hr TPCpHSampleMeasurementPARM Code 00400 PMon. Site No. OUI-22PermitRequirement6.0(Day.Min.)9.5(Day.Max.)s.u.2 Days/WeekGrab or In-situNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-22PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/WeekGrabFluoride, Total (as F)SampleMeasurementPARM Code 00951 PMon. Site No. OUI-22PermitRequirement25.0(Mo.Avg.)75.0(Day.Max.)mg/L2 Days/Week24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page35 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: MonthlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S28LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to retention pond at Swift Creek15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeFlowSampleMeasurementPARM Code 50050 PMon. Site No. OUI-28PermitRequirementReport(Mo.Avg.)Report(Day.Max.)MGD2 Days/WeekCalculatedSolids, Total SuspendedSampleMeasurementPARM Code 00530 PMon. Site No. OUI-28PermitRequirement50.0(Mo.Avg.)150.0(Day.Max.)mg/L2 Days/Week24-hr TPCPhosphorus, Total (as P)SampleMeasurementPARM Code 00665 PMon. Site No. OUI-28PermitRequirement35.0(Mo.Avg.)105.0(Day.Max.)mg/L2 Days/Week24-hr FPCTurbiditySampleMeasurementPARM Code 00070 PMon. Site No. OUI-28PermitRequirementReport(Mo.Avg.)Report(Day.Max.)NTU2 Days/Week24-hr TPCFluoride, Total (as F)SampleMeasurementPARM Code 00951 PMon. Site No. OUI-28PermitRequirement25.0(Mo.Avg.)75.0(Day.Max.)mg/L2 Days/Week24-hr TPCSpecific ConductanceSampleMeasurementPARM Code 00095 PMon. Site No. OUI-28PermitRequirementReport(Mo.Avg.)Report(Day.Max.)umhos/cm2 Days/Week24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page36 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DISCHARGE MONITORING REPORT - PART A (Continued)FACILITY:PCS Phosphate - White SpringsMONITORING GROUPNUMBER:I-S28 PERMIT NUMBER: FL0000655MONITORING PERIOD From: _____________________ To: ________________Parameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeNitrogen, TotalSampleMeasurementPARM Code 00600 PMon. Site No. OUI-28PermitRequirementReport(Mo.Avg.)Report(Day.Max.)mg/L2 Days/Week24-hr TPCVersion: March 18, 2013 – Effective: July 1, 2013 – Page37 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994DEPARTMENT OF ENVIRONMENTAL PROTECTIONDISCHARGE MONITORING REPORT - PART AWhen Completed mail this report to:Department of Environmental Protection,Wastewater Compliance Evaluation Section,MS 3551, 2600 Blair Stone Road, Tallahassee,FL 32399-2400PERMITTEE NAME:PCS Phosphate - White SpringsPERMIT NUMBER: FL0000655MAILING ADDRESS: Post Office Box 300White Springs, Florida 32096LIMIT: FinalREPORT: QuarterlyCLASS SIZE: MAPROGRAM: IndustrialFACILITY: PCS Phosphate - White SpringsMONITORING GROUP NUMBER: I-S28LOCATION: CR-137, North of White SpringsMONITORING GROUP DESCRIPTION: Discharge to retention pond at Swift Creek15843 SE 78th StreetRE-SUBMITTED DMR:White Springs, Florida 32096-0300 NO DISCHARGE FROM SITE:COUNTY: HamiltonMONITORING PERIOD From: ____________________ To: ____________________OFFICE: Northeast DistrictParameter Quantity or Loading UnitsQuality or Concentration Units No.Ex.Frequency ofAnalysisSample TypeRadium 226 + Radium 228, TotalSampleMeasurementPARM Code 11503 PMon. Site No. OUI-28PermitRequirement5.0(Day.Max.)pCi/LQuarterly24-hr TPCAlpha, Gross Particle ActivitySampleMeasurementPARM Code 80045 PMon. Site No. OUI-28PermitRequirement15.0(Day.Max.)pCi/LQuarterly24-hr TPCI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluatethe information submitted. Based on my inquiry of the person orpersons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best of myknowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENT AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page38 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWB-SC/SRBCounty: Hamilton Well Type: BackgroundMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab SemiannuallyDescription: NW 1/4 of Sec 28, Twn 1N, Rng 15E,30o 28’ 01”N 82o 49’ 30”WI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on my inquiryof the person or persons who manage thesystem, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page39 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-EPA-11SCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30° 26' 36”N 82° 53' 01”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page40 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-EPA-15SCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30° 27' 17”N 82° 51' 44”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page41 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-EPA-15DCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description:Adjacent to EPA-15SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page42 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-EPA-18SCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description: 30° 26' 13”N 82° 52' 06”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page43 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-SC5SCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description: 30o 27’20” N 82o 53’ 20”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page44 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-SC5DCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description: Adjacent to SC-5SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page45 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-EPA-16SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 27' 02”N 82° 51' 26”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page46 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-EPA-16DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: Adjacent to EPA-16SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page47 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-12SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription:30°28’01”N82° 52‘ 15”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page48 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-12DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: Adjacent to SC-12SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page49 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-13SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription:30°27’59”N82° 53’ 45”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page50 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-13DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: Adjacent to SC-13SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page51 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-14DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°27’09”N82° 53’ 59”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page52 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-15DCounty: Hamilton Well Type: IComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°26’26”N82° 53’ 16”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page53 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-16SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°26’05”N82° 51’ 55”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page54 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-16DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description: Adjacent to SC-16SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page55 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-17SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°27’30”N82° 51’ 50”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page56 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-17DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: Adjacent to SC-17SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page57 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-4FCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description: 30° 26' 32”N 82° 52' 37”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page58 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SC-5FCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 27' 22”N 82° 53' 29”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page59 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-MC-3FSCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 27' 04”N 82° 51' 54”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page60 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-C-CW(SC5)County: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 26' 45”N 82° 52' 01”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page61 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWB-SC/SRBCounty: Hamilton Well Type: BackgroundMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab SemiannuallyDescription: NW 1/4 of Sec 28, Twn 1N, Rng 15E,30o 28’ 01”N 82o 49’ 30”WI certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on my inquiryof the person or persons who manage thesystem, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.NAME/TITLE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT SIGNATURE OF PRINCIPAL EXECUTIVE OFFICER OR AUTHORIZED AGENT TELEPHONE NO DATE (yy/mm/dd)COMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page62 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-EPA-P1-CCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description: 30° 26' 38”N 82° 48' 03”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page63 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWI-EPA-4DCounty: Hamilton Well Type: IntermediateMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Swift Creek ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 Report MG/L Grab QuarterlySodium, Total Recoverable 00923 Report MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 Report UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 80045 Report PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 Report PCI/L Grab Semiannually** See Permit Condition III.B.4Description: 30° 26' 39”N 82° 48' 02”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page64 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-1SRCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 27' 12”N 82° 46' 05”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page65 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SRM1County: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30o 25’ 49” N 82o 45’ 43” WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page66 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-EPA-23DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 26' 12”N 82° 45' 48”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page67 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-1DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription:30°27’10”N82°46’06”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page68 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR9SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30°25’15”N 82°47’11”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page69 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR9DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription:30°24’15”N82°47’13”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page70 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-13SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°24’15”N82°47’13”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page71 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-13DCounty: Hamilton Well Type: IComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4DescriptionAdjacent to SR-13SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page72 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-14SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°26’31”N82°48’26”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page73 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-14DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description: Adjacent to SC-14SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page74 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-15DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description:30°25’24”N82°48’24”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page75 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-16SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription:30°27’50”N82°47’01”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page76 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-16DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab Semiannually** See Permit Condition III.B.4Description: Adjacent to SR-16SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page77 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-17SCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription:30°27’51”N82° 47’45”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page78 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR-17DCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: Adjacent to SR-17SCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page79 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SRC-CD5County: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 26' 40”N 82° 47' 04”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page80 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-SR8FCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30o 26’ 21”N 82o 47’ 51”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page81 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-FAS-DORRCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 26' 22”N 82° 46' 49”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page82 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994GROUNDWATER MONITORING REPORT - PART DFacility Name: PCS Phosphate - White Springs Date Sample Obtained: ________________Permit Number: FL0000655Monitoring Location Site Number:MWC-MoretrenchCounty: Hamilton Well Type: ComplianceMonitoring Period From: _______________________ To: _______________________ Ground Water Class: G-IIWas the well pumped before sampling? ___ Yes ___ NoSite: Suwannee River ComplexParameter PARM Code SampleMeasurementPermitRequirementUnits Sample Type Monitoring Frequency Detection Limits Analysis Method SamplingEquipment UsedSamplesFiltered(L/F/N)Water Level Relative to NGVD 82545 Report FEET Measured QuarterlySpecific Conductance 00095 Report UMHOS/CM In-situ QuarterlypH 00400 Report SU In-situ QuarterlyPhosphate, Ortho (as PO4) 00660 Report MG/L Grab QuarterlySolids, Total Dissolved (TDS) 70295Report MG/L Grab QuarterlyFluoride, Total (as F) 00951 4 MG/L Grab QuarterlySodium, Total Recoverable 00923 160 MG/L Grab QuarterlySulfate, Total 00945 Report MG/L Grab QuarterlyArsenic, Total Recoverable 00978 10 UG/L Grab SemiannuallyTurbidity 00070 Report NTU Grab SemiannuallyAlpha, Gross Particle Activity 8004515 PCI/L Grab SemiannuallyRadium 226 + Radium 228, Total 11503 5 PCI/L Grab SemiannuallyDescription: 30° 26' 50”N 82° 48' 00”WCOMMENTS AND EXPLANATION (Reference all attachments here):Version: March 18, 2013 – Effective: July 1, 2013 – Page83 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994INSTRUCTIONS FOR COMPLETING THE WASTEWATER DISCHARGE MONITORING REPORTRead these instructions as well as the SUPPLEMENTAL INSTRUCTIONS FOR COMPLETING THE WASTEWATER DISCHARGE MONITORING REPORT before completing the DMR. Hard copies and/or electroniccopies of the required parts of the DMR were provided with thepermit. All required informationshall be completed in full andtyped or printed in ink. A signed, original DMR shall be mailed to the address printed on the DMRby the 28thof the month following the monitoring period. The DMR shallnot be submitted before the end of the monitoring period.The DMR consists of three parts--A, B, and D--all of which mayor may not be applicable toevery facility. Facilities may haveone or more Part A's for reportingeffluent or reclaimed water data. All domestic wastewater facilitieswill have a Part B for reporting daily sample results. PartD is used for reporting ground water monitoring well data.When results are not available,the following codes should be used on parts A and D of the DMR and an explanation provided where appropriate. Note: Codes used onPart B for raw data are different.CODE DESCRIPTION/INSTRUCTIONSCODE DESCRIPTION/INSTRUCTIONSANC Analysis not conducted. NOD No discharge from/to site.DRY Dry Well OPS Operations were shutdown so no samplecould be taken.FLD Flood disaster. OTH Other. Please enter an explanation of why monitoring data were not available.IFS Insufficient flow for sampling.SEF Sampling equipment failure.LS Lost sample.MNR Monitoring not required this period.When reporting analytical results that fall below a laboratory's reported method detection limits or practical quantification limits, the following instructions should be used:1. Results greater than or equal to the PQL shall be reported as the measured quantity.2. Results less than the PQL and greater thanor equal to the MDL shall be reported asthe laboratory's MDL value. These values shall be deemed equal to the MDL when necessaryto calculate an average for that parameter andwhen determining compliance with permit limits.3. Results less than the MDL shall be reported by entering a less than sign ("<") followed by the laboratory's MDL value, e.g.< 0.001. A value of one-half the MDL or one-half the effluent limit, whichever is lower, shall beused for that sample when necessary to calculate an average for that parameter. Values less than the MDL are considered to demonstrate compliance with an effluent limitation.PART A -DISCHARGE MONITORING REPORT (DMR)Part A of the DMR is comprised of one or more sections, each having its own header information.Facility information is preprinted in the header as well as the monitoring group number, whether the limits and monitoringrequirements are interim or final, and the required submittal frequency (e.g. monthly, annually,quarterly, etc.). Submit PartA based on the required reporting frequency in the header and the instructions shown in the permit. Thefollowing should be completed by the permittee or authorized representative:No Discharge From Site:Check this box if no discharge occurs and, as a result, there areno data or codes to be entered for all of the parameters on the DMR for the entire monitoring group number; however, if the monitoringgroup includes other monitoring locations (e.g., influent sampling), the "NOD" code should be used to individually denote thoseparameters for which there was no discharge.Monitoring Period:Enter the month, day, and year for the first and last day ofthe monitoring period (i.e. the month, the quarter, the year, etc.) during which the data on this report were collected and analyzed.Sample Measurement:Before filling in sample measurements inthe table, check to see that the datacollected correspond to the limit indicated onthe DMR (i.e. interim or final) and that the data correspond to the monitoringgroup number in the header. Enter the data or calculated resultsfor each parameter on this rowin the non-shaded area above the limit. Be sure the result being entered correspondsto the appropriate statistical base code (e.g.annual average, monthly average, single sample maximum, etc.) and units.No. Ex.:Enter the number of sample measurements during the monitoring period that exceeded the permitlimit for each parameter in thenon-shaded area. If none, enter zero.Frequency of Analysis:The shaded areas in this column contain the minimum number oftimes the measurement is required to be made according to the permit. Enter the actual number of times the measurement was made in thespace above the shaded area.Sample Type:The shaded areas in this column contain the type of sample(e.g. grab, composite, continuous) required by the permit. Enter the actual sample type that was takenin the space abovethe shaded area.Signature:This report must be signed in accordancewith Rule 62-620.305,F.A.C. Type or print the nameand title of the signing official. Include the telephone number where the official may be reached in the event there arequestions concerning this report. Enter the date when the report is signed.Comment and Explanation of Any Violations:Use this area to explain any exceedances, any upset or by-pass events, or other items which require explanation. If more space is needed, reference allattachments in this area.Version: March 18, 2013 – Effective: July 1, 2013 – Page84 of 84 DEP Form 62-620.910(10), Effective Nov. 29, 1994PART B - DAILY SAMPLE RESULTSMonitoring Period:Enter the month, day, and year for the first and last day ofthe monitoring period (i.e. the month, the quarter, the year, etc.) during which the data on this report were collected and analyzed.Daily Monitoring Results:Transfer all analytical datafrom your facility's laboratory or a contract laboratory's datasheets for all day(s) that samples were collected. Record the data inthe units indicated. Table 1 in Chapter 62-160, F.A.C., contains a complete list of all the data qualifier codes that your laboratory may use when reporting analytical results. However, when transferring numerical resultsonto Part B of the DMR, only the following dataqualifier codes should be used and anexplanation provided where appropriate.CODE DESCRIPTION/INSTRUCTIONS< The compound was analyzed for but not detected.A Value reported is the mean (average) of two or more determinations.J Estimated value, value not accurate.Q Sample held beyond the actual holding time.Y Laboratory analysis was from an unpreserved or improperly preserved sample.Add the results to get the Total and divide by the numberof days in the month to get the Monthly Average.Plant Staffing:List the name, certificate number, and class of all state certified operators operating the facility during the monitoring period. Use additional sheets as necessary.PART D - GROUND WATER MONITORING REPORTMonitoring Period:Enter the month, day, and year for the first and last day ofthe monitoring period (i.e. the month, the quarter, the year, etc.) during which the data on this report were collected and analyzed.Date Sample Obtained:Enter the date the sample was taken. Also, check whether or not the well was purged before sampling.Time Sample Obtained:Enter the time the sample was taken.Sample Measurement:Record the results of the analysis. If the result was below the minimum detection limit, indicate that.Detection Limits:Record the detection limits ofthe analytical methods used.Analysis Method:Indicate the analytical method used. Record the method numberfrom Chapter 62-160 or Chapter 62-601, F.A.C., or from other sources.Sampling Equipment Used:Indicate the procedure used to collect the sample(e.g. airlift, bucket/bailer, centrifugal pump, etc.)Samples Filtered:Indicate whether the sample obtained was filtered by laboratory (L), filtered in field (F), or unfiltered (N).Signature:This report must be signed in accordancewith Rule 62-620.305,F.A.C. Type or print the nameand title of the signing official. Include the telephone number where the official may be reached in the event there arequestions concerning this report. Enter the date when the report is signed.Comments and Explanation:Use this space to make any comments on or explanations of results that are unexpected. If morespace is needed, reference allattachments in this area.SPECIAL INSTRUCTIONS FOR LIMITED WET WEATHER DISCHARGESFlow (Limited Wet Weather Discharge):Enter the measured average flow rate during the period of discharge or divide gallons dischargedby duration of discharge (converted into days). Record in million gallons per day(MGD).Flow (Upstream):Enter the average flow rate in the receiving stream upstream fromthe point of discharge for the period of discharge. The average flow rate can be calculated based ontwo measurements; one made at the startand one made at the end of the discharge period. Measurements are to be made atthe upstream gauging station described in thepermit.Actual Stream Dilution Ratio:To calculate the Actual Stream DilutionRatio, divide the average upstream flow rateby the average discharge flowrate.Enter the Actual Stream Dilution Ratio accurate to the nearest 0.1.No. of Days the SDF > Stream Dilution Ratio:For each day of discharge, compare the minimum Stream DilutionFactor (SDF) from the permit to the calculated Stream Dilution Ratio. On Part B of theDMR, enter an asterisk(*) if the SDF is greater than the Stream Dilution Ratio on any day of discharge. On Part A of the DMR, add up the days with an "*" and record the total numberof days the Stream Dilution Factor was greater than the StreamDilution Ratio.CBOD5:Enter the average CBOD5of the reclaimed water discharged during the period shown in duration of discharge.TKN:Enter the average TKN of the reclaimed water discharged during the period shown in duration of discharge.Actual Rainfall:Enter the actual rainfall for each day on Part B. Enterthe actual cumulative rainfall to date for this calendar yearand the actual total monthly rainfall on Part A. The cumulativerainfall to date for this calendaryear is the total amount of rain, in inches, that has been recorded since January 1 of the current year through the month for which this DMR contains data.Rainfall During Average Rainfall Year:On Part A, enter the total monthly rainfall during the average rainfall year and the cumulative rainfall for the average rainfall year. The cumulative rainfall for the average rainfall year isthe amount of rain, in inches, which fellduring the average rainfall year from January through the month for which this DMR contains data.No. of Days LWWD Activated During Calendar Year:Enter the cumulative number of days that the limited wet weather discharge wasactivated since January 1 of the current year.Reason for Discharge:Attach to the DMR a brief explanation of the factors contributing to the need to activate thelimited wet weather discharge.