Federa l Registe r / Vol

. 58 , No
. 3 5 /

Wednesday , Februar y 24 , 199 3 / Propose dRule s 1120 1 amende dguidance. ' Th e SI P cal l letter s interprete dtha t

guidanc e an dindicate d correction s necessar y fo

r specific , nonattainmen t

areas . Th e nonattainmen t are aencompassin g Clar

k Count y Indian ai s classifie da s moderat e an di s therefore , subjec t

t o th e RACT fix-up requirement

. Indiana' s SIP revisio n reques t whic h i t submitte di n respons e t o th e SI P cal l letter , als o respond s to par t o f th e RAC T fix-up requirement

. O n Apri l 10,1989 , th e IDE M submitte dane w rule , 32 6 IA C 8-2-13 , Marin e Vesse l Surfac e Coating

. Thi s ne w rul e applies.t o onl y on e source , Jeffboat , locate di n Clar

k Count y Indian a whic h i s designate dnonattainmen t fo r ozone . Rul e 32 6 IA

C 8-2-1 3 wa s develope di n respons e t o th e Act' s requiremen t

tha t al l State s adop t

RACT fo r major VO C source s i n countie s unabl e t o attai n th e ozon e standar db y Decembe r 31,1982 , an dwhich,wer e grante da n extensio n o

f th e ozon e attainmen t

dote unti l Decembe r

31 , 1987

. Th e followin g provide s a summar y ofth e State' s requirements.fo r marin e vesse l coatin g a s containe di n th e submittal : 1

. Inorgani c zin c preconstructio n prime r shal l b e applie dusin g an automati c airles s syste mwit h automati c electroni c sensor s designe dt o minimiz e overspra y an d(o limi t

prime r thicknes s to n o greate r

tha n 0.00 1 inche s (0.002 5 millimeters) on plate s an d0.00125 ' inche s (0.003 2 millimeters ) o n othe r structura l elements ; a s determine db y AST M procedur e D-1186-8 1 (incorporate db y referenc e i n Indiana' s rules) , fo r al l prime r

coatin g operations

. 2

. A s on alternative , th e inorgani c zin c preconstructio n prime r shal l contai n n o VO

C a s delivere dt o applicator

. I

f Jeffboa t elect s t o appl y suc h acoating , i t

shal l notif

y th e Stat e thirty (30 ) day s prio r

t o th o chango

. 3

. Jeffboa t shal l maintai n doil y record s o f th e (a ) tons an dsquar e fee

t o f stee l coated , an d(b ) gallon s an dVO C

. conten t o f preconstructio n prime r

use d i n th e automati c airlos s systems
. 4

. Jeffboa t shal l submi t

an annua l

. report containin g th e dail y record s require dt o th o Stat e thirt y (30 ) day s afte r th o en do

f eac h calenda r

year.Th e annua l repor t

shal l documen t

th o metho do f applicatio n o

f oi l preconstructio n prime r

coating s an dan y operationa l change s whic h affect VO C

. 'Amon g othe r things , th o pro-amondmon t guidanc e consist s o f th o VO C RAC T portion s o f th o l*nsl-B 7 policy , 5 2 F R 4504 4 (Nov . 24,1997) ; th o Hlunhook . "Issuo s Relatin g t o VO C Rngtilatio n Culpnints , Deficiencie s find Deviations , Clarificatio n t o Appondi x D o f Novombe r 24 , 190 7 Firdero l Rftgisle r Notice " (o f whic h nottc o o f . availabilit y wa s publi.sho d i n th o Federa l RnginlR r * o n Ma y 25 , 191)0) , an d th o oxistin g CTGs. . .'. ' emission s fro mth o automati c blas t

an d primin g lines

. I

f a n Inorgani c zin c prime r containin g n o VOC wa s no t I n use , th e report

shal l documen t

th e curren t availabilit y o

f suc h primer s fo

r th e preconslructio n primin g operatio n a t Jeffboat

. III
. USEPA' s Analysi s o f

th e Propose d Rul e IDE M assert s that

i t i s no t reasonable forjeffboa t to us e awaterborn e zin c primer , a s recommende di n th e "Developmen t

o f Contro l Guidelin e Documen t

fo r Selecte dNon-CT G Source s i n Indiana". 3 Th e Stat e provide dth e followin g justificatio n fo r thi s position : 1

. Ther e are n o waterborn e primer s available.t o mee t

th e requiremen t

fo r a 3-minut e dryin g tim e necessary fo r Jeffboa t t o continu e usin g th e equipmen t currentl y a

t th e plant

. 2

. In orde r

t o us o awaterborn e prime r wit h alonge r

dryin g time , Jeffboa

t woul dhav e t o mak e significan t change s t o it s paintin g lines

. 3

. Given Jeffboat' s financial conditio n an dth o curren t

stat e ofth e market , th e cost s o f conversio n canno t

b e justified

. However , Indian aha s no t adequatel y demonstrate dtha t

th e requirement s i n Rul e 32 5 IAC 8-2-1 3 represen t RACT forjeffboat

. Specifically , th e USEP A maintain s that : 1

. Jeffboa t ha s no t provide da

n adequat e explanatio n o

f it s basi s fo

r th o cos t estimat e fo

r change s t o th e paintin g line s t o accommodat e th e us e o f a waterborn e primer

. Th e cos t analysi s submitte db y Jeffboa

t provide dalis t

o f equipment , capital , an doperatin g cost s fo r bot h ne w an drelocate dequipment , bu t th e submitta l di dno t

includ e an explanatio n o

f wh y thi s equipmen t

wa s neede do r ho w th e cost s wore determined

. 2

. Jeffboa t ha s no t provide da complet e evaluatio n ofth e feasibility of add-o n contro l equipment

. Fo r example , Jeffboa t doe s no t appea r t o hav e evaluate dth o feasibility o f controllin g th e omission s fro

monl y th e spray booth s o r onl y th e oven s throug h th e us e o f add-o n contro l devices

. 3

. Even i f Jeffboa t can provid e th e documentatio n discusse dabove , thor o i s n o justificatio n provide dfo r specifyin g onl y amaximu mallowabl e film thicknes s a s RACT , an dplacin g n o constrain t on th o amoun t

o f VO C pe r uni t o f applie dcoating

. In addition , i t shoul dbo note dtha t

th e specifie dfilm thicknes s unit s ar e no t

internall y

* I n ordo r t o assis t Indian a i n determinin g RAC T fo r thi s source , th e abovo-namo d repor t wa s proparo d b y Engineering—Scionc o fo r USEPA , Kogio n V , an d wa s provide d t o th e State . consistent

. A thicknes s o f 0.00 1 inc h i s 0.02 5 millimeters , no t

0.002 5 millimeter s a s specifie di n th e propose d rule

. I n additio n t o th o RACT deficiencie s state dabove , USEP

A als o note s tha t

32 6 IA C 8-2-13(b ) fail s t o defin e th e phras e "minimiz e overspray, " an dfail s t o describ e ho w th e electroni c sensor s wil l b e use dt o mee t

thi s requirement

. Th e rul e als o need s t o specif

y th e tes t protoco l whic h wil l b e use dt o vorif v th e allowabl e limits

. IV
. Summar y o f

USEPA' s Action ; Reques t fo r Publi c Commen t USEP A i s proposin g t o disapprov e thi s rule , Marin e Vesse l Surfac e Coatin g (32 6 IAC 8-2-13) , becaus e th e Stat e ha s no t adequatel y demonstrate dtha t th e rul e represent s RAC

T fo r Joffboat

. Therefore , th e rul e doe s no t mee t th e requiremen t

unde r sectio n 182(o)(2)(A) o f th e amende dAc t

tha t Indian acorrec t tha t rul e s o tha t

i t applie s RACT a s require db y pre-amende dsectio n 172

. Publi c comment s ar e solicite do n th e requeste dSIP revisio n an do n USEPA' s propose drulemakin g action

. Publi c comment s receivedb y Apri l 26,1993 , wil l b e considere di n th o developmen t o f USEPA' s final rulemakin g action

. Unde r 5 U.S.C

. 605(b) , I certif

y tha t disapprovin g thi s rul e wil l no t hav e a significan t

economi c impac t

o n a substantia l numbe r

o f smal l entitio s becaus e i t affect s onl y on e source , Joffboat

. (Se e 4 6 F

R8709. ) Unde r Executiv o Ordo r

12291 , today' s actio n i s no t

"Major"

. It

ha s bee n submitte dto th e Offic e o f Managemen t an dBudge t

(OMB ) fo

r review

. Lis t o f Subject s i n 4 0 CF

RPar t 5 2 Ai r pollutio n control , Environmenta l protection , Intergovernmenta l relations , Ozone

. Authority : 4

2 U.S.C . 740l-7G71q . Dated : Februar

y 10,1993

. Davi dA

. Ullrich , Acting Regional

Administrator. |F RDoc
. 93-429 0 Filed2-23-93 ; 8:4 5 am i BILLIN G COD E 6SW-S0- M
4 0 CF R Part 6 3 IAD-FRL-4560-3 ] Nationa l Emissio n Standard s fo r Hazardou s Ai r Pollutant s fo r Sourc e Categories : Organi c Hazardou s Ai r Pollutant s Fro m th e Syntheti c Organi c Chemica l Manufacturin g Industr y an d Seve n Othe r Processe s AGENCY : Environmenta l Protectio n Agenc y (EPA)

.P.1 4



### lft0 2 Federa

l Registe r /Vol

. 50 , No
. 3 5 /

Wednesday , Februar

y 24 , 199 3 /

ProposedRule s ACTION : Notic e o f

publi c hearin g an d extensio n o f

publi c commen t

period

. SUMMARY

: O n Decembe r

31,199 2 (5 7 F R 62608) , EP A propose dstandard s t o regulat e th e emission s o f certai n organi c hazardou s ai r

pollutant s fro msyntheti c organi c chemica l manufacturin g industr y (SOCMI ) productio n processe s whic h ar e par t

o f majo r source s unde r Sectio n 11 2 o f

th e Clea n Ai r

Ac t a s amende di n 199 0 (th e Act)

. Thi s notic e announce s tha t

EP A wil l hol dapubli c hearin g i n Bato n Rouge , Louisian at o hoa r comment s o n th e propose drule

. Th o publi c hearin g wil l b e hel do n Marc h 18,1993

. Th e perio dfo r receivin g writte n publi c comment s o n th e propose drul e i s bein g extended

. DATES : Comments. Comment s mus t b e receive do n o r

befor e Apri l 19,1993

. Public Hearing. Th e publi c hearin g wil l b o hel do n Marc h 18,199 3 i n Bato n Rouge , Louisiana

. Th e hearin g wil l star t a t 6 p.m . an den da t

1 0 p.m . Bequest to Speak

at Hearing. Person s wishin g t o presen t

ora l testimon y mus t contac t EP A b y Marc h 12,1993

. Eac h speake r wil l b e allowe du p t o 1 0 minutes , an deac h organizatio n wil l b o allowe damaximu mo f 2 0 minutes

. ADDRESSES : Comments. Comment s shoul db e submitte d(i n duplicat e i f possible ) t o th e EPA' s Ai r Docke t (LE

131) , ATTN : Docke t

Numbe r (se e lis t followin g address ) roo mM1500 , U.S

. Environmenta l Protectio n Agency , 40 1 M Street , SW „ Washington , D C 20460

. Comment s tha t

addres s area s pertinen t t o th e propose drul e a s awhol e o r tha t ar e applicabl e t o mor e tha n on e kin do f emissio n point , suc h a s genera l polic y o r lega l comments , comment s o n th e overal l impact s ofth e standards , an d comment s o n tes t

method s shoul db e marke dATTN : Docke t Numbe r A-90

- 19

. Technica l comment s specifi c t o proces s vent s shoul db e marke dATTN : Docke t Numbe r A-90-19 ; technica l
' comment s abou t

equipmen t

leak s an d an y othe r

comment s abou t

th e negotiate dregulatio n fo r equipmen t leak s shoul db e marke dATTN : Docke t Numbe r A-90-20 ; technica l comment s abou t storag e vessel s shoul db e marke d ATTN : Docke t

Numbe r A-90-21 ; technica l comment s abou t transfe r operation s shoul db o marke dATTN : Docke t Numbe r A-90-22 ; an d' comment s specifi c t o wastewate r operation s shoul db e marke dATTN : Docke t Numbo r

A-90-23

. Public Hearing. Th e publi c hearin g wil l b e hel da t

th e Conservatio n Hearin g Roo ma t th o Louisian aDepartmen t o f Natura l Rosources
. Person s intereste di n attondin g th o hearin g o r wishin g t o presen t ora l testimon y shoul dnotif y Ms
. Ki mTeal , Standard s Developmen t Branch , Emissio n Standard s Division , U.S

. Environmenta l Protectio n Agency , Offic e b f Ai r Qualit y Plannin g an d Standard s (MD-13) , Researc h Triangl e Park , Nort h Carolin a27711 , (919 ) 541

- 5580

. Background

Information Docket. Th e backgroun dinformatio n documen t (BID ) fo r thi s rulemakin g ma y b e obtaine d fro mth e U.S

. EP A Librar y (MD-35) , Researc h Triangl e Park , Nort h Carolin a 27711 , (919 ) 541-2777

. Refe r t o EPA

453/D-92-016a , b , an dc . Th e HO N BI D comprise s thro e volumos

. Person s requestin g copie s o f

th e BI D shoul d specif y th e volume(s ) required , Fo r informatio n o n th e methodolog y an d result s of

th e analysi s o f

nationa l impacts , reques t

BI D Volum e IA

. Fo r informatio n o n emissio n contro l technologie s an dcos t

procedures , reques t BI D Volum e IB
. Fo r

informatio n o n th e developmen t

o f model s fo r

th e . fiv e kind s o f

emissio n points , reques t BI D Volum e IC

. Dockets. Th e docket s liste dabov e unde r ADDRESSE

S contai n supportin g informatio n use di n developin g th e propose drule

. Supportin g informatio n use di n developin g th e negotiate d standar dfo r

equipmen t

leak s i s availabl e i n Docke t

Numbe r A-89-10

. Thes e docket s ar e availabl e fo r publi c inspectio n an dcopyin g betwee n 8:3 0

, a.m. an d3:3 0 p.m. , Monda y throug h Friday , a t

th e EPA' s Ai r

Docke t Section , Watersid e Mall , roo mM1500 , U.S

. Environmenta l Protectio n Agency , 40 1 M Street , SW „ Washington , D C 20460

. A reosonabl e fe e ma y b o charge dfo r copying

. FO RFURTHE

RINFORMATIO

N CONTACT

: Dr
. Jane t S

. Meyer , Standard s Developmen t

Branch , Emissio n Standard s Divisio n (MD-13) , U.S

.

. Environmenta l Protectio n Agency , Offic e of Ai r Qualit y Plannin g an d Standards/Researc h Triangl e Park , Nort h Carolin a27711 , telephon e numbe r (919 ) 541-5299

. SUPPLEMENTAR

Y INFORMATION

: O n Decembe r

31,199 2 (5 7 F R62608) , EP A propose dstandard s t o regulat e th e emission s o f

certai n organi c hazardou s ai r pollutant s fro msyntheti c organi c chemica l manufacturin g industr y (SOCMI ) productio n processe s whic h ar e par t o f majo r source s unde r

Sectio n 11 2 o f th e Clea n Ai r

Ac t a s amende di n 199 0 (th e Act)

. Th e propose dnotic e announce dthat , i f

requested , a publi c hearin g woul db e hel di n EP A office s locate di n Researc h Triangl e Par k (RTP) , Nort h Carolina

. Th e EP A receive d severa l requests tha t

th e hearin g b e hel d i n Bato n Rouge , Louisian at o allo w th e affecte dcommunit y a n opportunit y t o presen t ora l testimon y o n th e propose d rule

. Th o Marc h 18 , 199 3 hoarin g i n Bato n Roug e wa s schedule di n respons e t o thos e requests
. Th e hearin g schedule d fo r Februar y 25,199 3 wil l stil l b e hel d a t EP A office s i n RT P becaus e request s t o spea k a t tha t hearin g hav e alread y bee n receive dfro msevera l individuals

. Dated : February 17,1993

. Michae l H
. Shapiro , Acting Assistant

Administrator, Office of

Air and Radiation^ [F RDoc
. 93-429 1 File d2-23-93 ; 8:45 am ] BILLIN G COD E 6SSO-CO- M
4 0 CF R Par

t 8 6 [FRL-4599-7 ] Contro l of Ai r Pollutio n Fro m New Moto r Vehicle s an d Ne wMoto r Vehicl e Engines ; Federa l Tes t Procedur e Revie w AGENCY: Environmenta l Protectio n Agency

. ACTION : Notic e o f

publi c workshop

. SUMMARY

: O n Marc h 9 an d10,1993 , th e Environmenta l Protectio n Agenc y (EPA ) wil l hol dapubli c worksho p t o infor m intereste dpartie s o f

EPA' s curren t

an d planne dactivitie s regardin g th e Agency' s revie w o f

th e Federa l Tes t Procedur e (FTP ) fo r

measuremen t

o f moto r vehicl e emissions

. Sectio n 206(h ) o f th e Clea n Ai r

Ac t (CAA ) require s EP A t o "revie w an drevis e a s necessary " th e regulation s governin g th e FT P t o "insur e tha t

vehicle s ar e teste dunde r circumstance s whic h reflec t th e actua l curren t drivin g condition s unde r which , moto r vehicle s ar e used"

. DATES : Th e worksho p wil l b e convene d a t 8:3 0 a.m . o n Marc h 9,1993

. Person s intereste di n makin g presentation s a t th e worksho p ar e requeste dt o notif y th e Agenc y contac t

liste dbelo w a t

leas t tw o week s prio r

t o th e worksho p s o tha t a fina l agend ama y b e prepared

. Writte n commen t

ma y b e submitte dt o th e Ai r Docke t (se e ADDRESSE

S below ) o r

th e Agenc y contac t

unti l Apri l 9,1993

. ADDRESSES : Th e worksho p wil l b e hel d a t th e Sherato n Inn , 320 0 Boardwal k Street , An n Arbor , M I 48104

. Telephone : (313 ) 996-0600

. Material s relevan t t o th e worksho p ar e containe d i n Docke t

No
. A-92-64

. Th e docke t i s locate da t

th e Ai r Docke t Room , roo m M-1500 , Watersid e Mall , 40 1 M Street , SW. , Washington , DC , 20460

. Th e docke t ma y b o Inspecte dbetwee n th e hour s o f 8:3 0 a.m . t o 1 2 noo n an dfro m 1:3 0 t o 3:3 0 p.m . Monda y throug h Friday

. A reasonabl e fe e ma y b e charge d b y EP A fo r

copyin g docke t

materials

. FO RFURTHE

RINFORMATIO

N CONTACT

: Joh n German , Certificatio n Division , U.S

.p. 1



# OAR Box 1252 Prepped by Candice Davis



## Document

Number: 

# 38 ) FE D RE G VOL

. 58 , NO

. 3 7 2/26/9 3 Docket Number: 

# A-90-2 2

Printed 5/21/20083:16:06

PM Sheet 38of 184P. 2 

# A-40-23- Gosredtll©! ^ Federa l Sogists r .

. Vol . 58 , No. 3

7 Friday , Februar y 28 , 199 3
Thi s sectio n o tth e FEDERA L REGISTER

ZZY. ^ contain s editoria l correction

s b J prevkntsl

y publishe d Presidential

, Rule , Propose d Rule , an d Notic e documents

. Thes e correction

s ar e prepare d b y fre Offic e o S fre Federa

l Register . Agenc y prepare d correction

s ar e issue d a s signe d document

s an d appea r I n th e appropriat

e documen tcategorie s elsewher e i n th e issue .
ENVIRONMENTA

L PROTECTIO

N • • ••• ' AGENCV-^ " ; 4 0 CF R Part S 3 [AD-fRM53M J ...'"-.•Z\...:- Nationa l Emissio n Standard s tor-; ; 7 Hazardou s Ai

r Pollutant s to? Sourc e Categories ; Organi c WaaanrdousAJ r Pollutant s fron

tth ® Syntheti c Organi c Chemical Manufacturin g Industr y an d Seve n ©thei

r Processe s ••.;':•/.••

. Correction . . ''_-.. , . , • .".'..- . '.; YI n propose d rul e documen t92-2829 2 beginnin g o n pag e 6260 8 i n th e issu e o f . Thursday , Decembe r 31,1992 , portion s of §§63.128,63.131,63.143,63.144,.. . 63.145 , an d 63.15 0 wer e illegible . Fo r th e convenienc e of

th e reader , th e section s liste d abov e ar

e reprinte d in.••' • thei r entirety.' ' r

~ 7^,r-

r ::-.•; ; y ; '§63.12 8 -Trsnote

r operation

s provision©

— tes tmethods ' an

d procedures.' ' - (a ) A performance tes ti s required fo r determinin g complianc e wit h th e reductio n o f

organi c HA

Pemission s i n § 63.126(b ) fo

r al l control device s othe r than : Vapor balancin g systems ; flares ; an d certai n boiler s an d proces s heater s liste d i n paragrap

h (c ) o f thi s section . Performanc

e tes tprocedure s ar

e a s • follows: , y 7 . - . . :-\y- ' .. . •.•.-.• : (1 ) A perfonnanc e tes tshal l consis tof thre e runs . (2 ) Al l testin g equipmen tshal l b e prepared an d installe d a s specifie d i n th e appropriat

e tes tmethods . 7 (3 ) For contro l device s capabl e o f continuou s vapo r processing , eac h run shal l representa tleas ton e complet e fillin g period , durin g whid i liqui d organi c HAP' a are loaded . r.... : y (4 ) Fo ? intermitten tvapo r processin g systems , eacT

h ran shall represen ta

t= , leas ton e complet e contro l defie s cycl a ' - (5)Methbd.l£H'l A o f par t60.-----V,.7:7......

. appendi x A , a s appropriate , shall b e . use d fo r selectio n o f

samplin g sites . (i ) For a n owne r o r operato r complyin g wit h th e 98-percen8 organi c HA P reductio n requirement

s i n § 63.126(b)(1) , samplin g site s shal l b e locate d a s specifie d i n paragrap h (a)(5)(i)(A)or(a)(5)(i)(B) . (A ) Samplin g site s shal l b e locate d a t th e inle tan

d outle to f th e contro l device , excep ta

s provide d i n paragrap

h (a)(5)(i)(B) . (B ) I f a ven tstrea

m i s introduce d with th e combustio n ai r o

r as a secondary fuel into a boile r o

rproces s heate r wit h a desig n capacit

y las s tha n 4 4 megawatts , selectio n p

f th e locatio n o f th e inle tsamplin g site s shal l ensur e th e measurementof

tota l organi c HA

Por . TO C (minu s methane and ethane) , - concentration s i n al l ven tstreams an d primar y and secondar

y fuel s introduce d int o th e boile r orproces s heater . A . samplin g sit e shal l als o b e locate d a tth e outle to f the boile r o

rproces s heater . (ii ) For a n owne r o

r operator ; : complyin g with th e 2 0 part s pe r millio n b y volum e limi ti n § 63.126(b)(1) , th e samplin g sit e shal l b e locate d a tth e outle tof th e control device . Y'- (6 ) Th e volum e exhauste d shal l b e ..-.' , determine d usin g Method 2 , 2A , 2C , o r 2 D of par t60 , appendi x A , a s appropriate . (7 ) Forth e purpos e of

determinin g complianc e with th e 2 0 part s pe r millio n b y volum e limi ti n § 63.126(b)(1) , Method 1 8 o rMetho d 2 5 A of par t60 , appendi x A shal l b e use d t o measur e eithe r organic compoun d concentratio n o r organi c HA Pconcentration , excep ta s provide d i n paragrap

h (a)(9) of thi s section . (i ) I f Method 25

A i s used , th e followin g procedure s shal l b e use d t o calculate th e concentratio n of organi c compound s (Cr) : 7 (A ) Th e principa

l organic HA

Pi n th e ven tstrea m shal l b e use d a s th e calibratio n gas . (B ) Th e span valu e fo

r Metho d 25 A shal l b e twic e th e concentratio n bein g measured..•-..., . ,.-.. - ( Q Us e o f Metho d 2 5 A i s acceptabl e i f th e respons e from th e high-leve l - calibratio n ga s i s a

tleas t2 0 time s th e standar d deviatio n of

th e respons e from th e zer o calibratio n ga s whe n th e instrumenti s zeroe d o n th e mos t sensitiv e scale . ...-••• ; -j > •: . -,- i •.-.-. • (D) The concentratio n of

TO C shal l b e corrected t o 3 percen toxyge n usin g th e procedure s an d equatio n i n paragrap h (a)(7)(v) o f

thi s section . (ii ) I f Method 1 8 i s use d t o measure th e concentratio n o f

organi c compounds , th e organi c compoun d :

concentratio n (Cr

) i s th e su m o f

the : individua l component s an d shal l b e compute d fo

r eac h run usin g th e followin g equation :

• C T = L.C J

where : Ct=Tota l concentratio n of

organi c compound s (minu s methan e an d ethane) ; dr

y basis , part

s pe r millio n b y volume . : y y Q=Concentratio n of

sampl e component s "j" , dr y basis , part

s pe r millio n b y volume . '•

' n=Numbe r o f

component s i n th e sample:-;• /

,

. (iii ) I f a n owne r or operato r use s Metho d 1 8 t o comput e total organi c HAP concentratio n rather tha n organi c compound s concentration , th e equatio n i n paragrap

h (a)(7)(H ) of thi s sectio n shal l b e use d excep ttha

tonl y organi c HAP specie s shal l b e summed . Th e lis t o f organi c HAP' s i s provide d i n § 63.10 4 of subpar tF o f thi s Part . (iv ) Th e emissio n rat

e correctio n factor or exces s ai r integrate d samplin g an d analysi s procedure s o f Metho d 3

B o f par t60 , appendi x A shal l b e use d t o detennin e th e oxyge n concentration . Th e samplin g sit e shall b e th e sam e a s tha tof th e organi c HA

P or organi c compoun d samples , an d th e sample s shall b e take

n durin g th e sam e tim e tha t th e organi c HA

Po r organi c compoun d sample s ar

e taken ; (v ) Th e organi c compoun d concentratio n correcte d t o 3 percen t oxyge n (C J shal l b e calculate d usin g th e followin g equation : C^=G r 17. 9

20. 9 -ftO * where : Cc=C6ncentration o f

organi c compound s correcte d t o 3 percen toxygen , dr y basis , part

s pe r milho n b y volume . Cr=Tota l concentratio n o f

organi c compounds , dr

y basis , part

s pe r millio n b y volume . %02d=Concentratlo

n o f oxygen , dr y basis , percen tb y volume .



## nam

### 1166 8 - Federa l Registe r / Vol

. 58 , No
. 37. /

Friday , Februaryv26 , 1993: / Correction s P. 3

(8 ) Forth e purpos e of

determinin g complianc e wit h th e 98-percent reduction requirementi n § 63.126(b)(1) , Metho d 1 8 orMetho d 25 A o f 4 0 CF R par t60 , appendi x A shal l b e used , . excep ta s provide d i n paragrap h (a)(9) of thi s section . ;r,

> '- ; (i ) Fo rth e purpos e o f

determinin g complianc e wit h th e reductio n efficiency requirement, organi c compoun d concentratio n ma y b e measure d i n lie u o f

organi c HA

P concentration . (ii ) I f Metho d 25A i s use d t o measur e th e concentratio n o f

organi c compound s (Cr) . th e principal organi c HA P i n th e ven tstrea m shal l b e use d a s th e calibratio n gas . (A ) A h emissio n testin g interva l shal l consis to f each 5-minut

e perio d during , th e performanc

e test . Fo reach interval , a readin g from each measurementshal l b e recorded. (B ) Th e average organi c compoun d concentratio n and th e volum e measuremen tshai i correspon d t o th e same emission s testin g interval . (C ) Th e mas s a

tth e inle tan d outle tof

. th e contro l devic e durin g each testin g interva l shal l b e calculate d a s follows : M^FKV.C r where : Mj=Mas s o f organi c compound s emitte d ' durin g testin g interval) , kilograms . V,=Volum e o

f air-vapo r mixture exhauste d a

tstandar d conditions , 2 0 ° C and 76 0 millimeter s mercury , standar d cubi c meters . Cr=Tofa l concentrationo f

organi c compound s (as measured ) a tth e exhaus tvent , part

s pe rmillio n b y volume , dr

y basis . K=Density , (kilograms pe rstandar d cubi c mete rorgani c HAP) . FsiO^^Cqnversio n factor, (cubi c ••••• ' meters orgamc HA

P pe rcubi c meter s air

) (part s pe rmillio n b y volume) -1
. (D ) Th e organi c compoun d mas s emissio n rates a

tth e inle tand outle tof th e contro l devic e shal l b e calculate d a s follows : E i = -



### E„ = - n 

### L M ° J

whiBre: Ei , Eo=Mas s flo w rat e o f organi c compound s a

tth e inle t(i ) and outle t(o ) ofth e combustio n or recover y device , kilograms pe r hour. " My , Moj=Mas

s o f organi c compound s a

t th e inle t(i ) o

routle t(o ) durin g testin g interva

l j , kilograms . T=Tota l tim e o f all testin g intervals , hours . n=Numberof

testin g intervals . (iii ) I f Metho d 1 8 i s use d t o measure organi c compounds , th e mas s rates of organi c compound s (Ei

, Eo ) shal l he... . compute d usin g the. followin g equations:" '



### E, = ^(^CijMWijJQ i



### E 0 

### = K 2 

### (LC ()j 

### MW o j 

### \Q o \J= I •

• . • : >••• •
where : dj , (^Concentratio n of

sampl e componen t"j " o

f th e ga s strea

m a t th e inle tand outle to

f th e contro l device , respectively , dr

y basis ; part

s pe r millio n by volume . , ; ; ; - > MWy , MWoj=Molecula

r weigh tof

7 sampl e componen t"j " of th e gas strea m a tth e inletan d outle tof

th e contro l device , respectively, gram / gram-mole . Oj,Qo=Flo w rat

e of gas strea m a tth e inle tand outle tofth e contro l device , respectively , dr

y standar d cubi c mete rpe rminute . K 2=Constant

, 2;494xl0~ 6 (part

s pe r million).~ ' (gram-molepe r standar d cubi c meter) (kilogram

/

. gram ) (minute/hour) , wher e standar d temperatur

e fo r(grammol e pe rstandar d cubi c meter

) i s 2 0 ° C (iv ) Wher e Metho d 1 8 or25 A i s use d t o measure th e percentreductio n i n organi c compounds , th e percen t reductio n acros s th e contro l devic e shal l b e calculate d a s follows :

E.-E Q * E , (100 )
where : R=Contro l efficiency of

contro l device , percent . 7 Ei=Mass emitte d o rmas s flo w rate "o f organi c compound s a

tth e inle tt o th e combustio n o rrecover y devic e a s calculate d unde rparagrap h (a)(8 ) (ii)(D ) o r(a)(8)(iii ) o f

thi s section , kilogra m pe rhour . Eo=Mas s emitte d o

rmas s flo w rat

e o f organi c compound s a

tth e outle to

f th e combustio n o

rrecovery device , a s calculated.unde r paragrap h (a)(8)(ii)(D);o r (a)(8)(iii ) of thi s section , kilogra

m pe rhour . (9 ) Th e owne ro roperato rmay us e aii y method s o

rdat a othe rthan Metho d 1 8 o rMetho d 25A , i f

th e metho d ordat

a ha s bee n validated'accordin g t o Metho d 30 1 o f 4 0 CF Rpar t6 3 of appendi x A . (b) Whe n a flar e i s use d t o compl y wit h § 63.126(b)(2) , th e owne ror operato rshal l compl y with th e flar e provision s i n §63.1 1 o

f subpar tA o f thi s part. " :-,••• . (1 ) Th e complianc e determinatio n required b y § 63.6(g ) of

subpar tA of thi s part , ashal l b e conductin g usin g Metho d 2 2 o f

4 0 CF Rpar t60 , appendi x A , t o determin e visibl e emissions . Th e observatio n perio d shal l b e a tleas t2 hour s and shal l b e conducte d accordin g t o Metho d 22 . : r ' : (i ) Th e complianc e determinatio n shal l b e conducte d durin g a tleas tthre e complet e loadin g cycle s with a separat e tes trun fo

reac h loadin g cycle . Th e observatio n perio d fo

rdetectin g visibl e emission s shal l encompas s each loadin g cycle . (ii ) Integrated samplin g t o measur e > ven tstrea m flo w rat

e shal l b e performed continuousl y durin g eac h loadin g cycle . (2) A n owne ro

roperato ri s no t required t o conduc ta performance tes t t o determin e th e percen temissio n reductio n or outle tHA

P o r TO C concentratio n whe n a flar e i s used . (c ) A n owne roroperato rIs no t require d t o conduc ta performance tes t whe n any devic e specifie d i n paragraphs (c)(1) . (c)(2) , (c)(3) ; or (c)(4 ) o f thi s sectio n i s used . "Th e EP A wil l propos e tubpar

tA I n th e future. "Se e Footnot

e 11 .P. 4

Federa l Registe r

/ Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 /Correction s 1166 9 (1 ) A boile r

o r proces s heate r

wit h a desig n hea t

inpu t capacit y o f

4 4 megawatt s o r

greater
. (2 ) A boile r

o r proces s heate r

burnin g hazardou s wast e fo

r whic h th e owne r

o r operator : (i ) Ha s bee n issue dafinal permi t unde r 4 0 CF Rpar t 27 0 an dcomplie s - wit h th e requirements of

4 0 CF Rpar t 26 6 subpar t

H , o r (ii ) Ha s certifie dcomplianc e wit h th e interi mstatu s requirement s of 4 0 CF R par t 26 8 subpar t

H
. (3 ) A boile r

o r proces s heate r

int o whic h th e ven t

strea mi s introduce d

. wit h th e primar y fuel

. (4 ) A vapo r

balancin g system , (d ) A n owne r

o r operato r usin g a combustio n devic e followe db y a scrubbe r t o contro l ahalogenate d transfe r ven t strea mi n complianc e with §63.126(d ) shal l conduc t aperformanc e tes t t o determin e complianc e Wit h th e contro l efficienc y o r

emissio n limit s fo

r hydroge n halide s an dhalogens

. (1 ) Fo r a n owne r

o r operato r determinin g complianc e wit h th e 9 9 percen t reductio n o

f tota l hydroge n halide s an dhalogens , samplin g site s - shal l b e locate da t

th e inle t an doutle t ofth e scrubber

. Fo r

a n owne r o r operato r complyin g wit h th e 0. 5 milligra mpe r

dr y standar dcubi c mete r outle t emission : limi t

fo r eac h hydroge n halid e an dhalogen , th e samplin g sit e shal l b e locate dat

th e outle t

of th e scrubber

. (2 ) Excep t a s provide di n paragrap h (d)(5 ) of thi s section , Metho d2 6 o r 26A

, - of par t 60

. appendi x A , shal l b e use dt o determin e th e concentratio n i n milligram s pe r

dr y standar dcubi c meter , correcte dt o a3 percen t oxyge n oasis , of th e hydroge n halide s an d halogen s tha t

may b e presen t

i n th e stream
. (3 ) T o determin e complianc e with th e 9 9 percen t

emission s reductio n limit , th e emission s fo

r an y hydroge n halide s an dhalogen s presen t

at th e scrubber inle t

shal l b e summe dtogether

. Th e mas s emission s of

th e compound s presen t a t th e scrubber

outle t shal l b e summe dtogether

. Percen t reductio n shal l b e determine db y compariso n of

. th e summe dinle t

an doutle t measurements
. . - . (4 ) T o demonstrat e complianc e wit h th e 0. 5 milligrampe r

dr y standar dcubi c mete r emissio n limit , th e tes t

result s mus t sho w tha t

th e concentratio n of eac h individua l compoun dmeasure dat th e scrubbe r

outlet , correcte dt o 3 y percen t oxygen , i s belo w 0. 5 milligra m pe r dry standar dcubi c mete r o r i s belo w detectabl e levels

. (5 ) Th e owne r

o r operato r ma y us e an y othe r metho do r

dat at o demonstrat e complianc e i

f th e metho do r

dat aha s bee n validate daccordin g t o th e protoco l o f Metho d30 1 o

f 4 0 CF Rpar t 63 , appendi x A

. le ) Th e owne r

o r operato r shal l inspec t th e vapo r

collectio n syste man d vapo r balancin g syste mfo

r detectabl e emission s greate r

tha n 50 0 part s pe r million

. (1 ) Metho d2 1 of

4 0 CF Rpart 60 , appendi x A an dvisua l inspection s shal l b e used

. ^ y (2) Inspection s shal l b e performed,

. onl y whil e atank

truc k o r railca r i s .•• _ bein g loaded

. '- (3 ) Inspection s shal l b e performe dat th e followin g times : (i ) B y th e complianc e dat e an d annuall y thereafte r

t o demonstrat e complianc e with § 63.126(a)(3 ) an d(4) , o r (b)(3) ; an d.,..- . 7
. (ii j Befor e eac h performanc e tes t require dt o demonstrat e complianc e with §63.126(b)(1). 'ZZ'YY
. .Y'YY... .YY

YY ( 0 For th e purpose s o f

demonstratin g vapo r tightnes s t o determin e complianc e wit h § 63.126(e)(2) , th e followin g procedure s an dequipmen t
. shal l b e used : (1 ) Th e pressur e tes t

procedure s .specifie di n Metho d2 7 o f par t 60 , . appendi x A ; an d (2 ) A pressur e measuremen t devic e whic h ha s aprecisio n of

±2. 5 millimeter s o f

mercur y an dwhic h is

. capabl e o f

measurin g abov e th e pressur e a t whic h th e tan k

truc k o r raiica r i s t o b e teste dfo

r vapo r tightness

. §63.13 1 Proces s wastewater provisions — flo w diagram s an dtables

. . -.. , (a ) Th e flow diagram s i n thi s section , ar e provide da s guidanc e fo r understandin g th e basi c interrelationship s of

th e wastewate r provisions ' fo

r proces s units ' at

ne w an d existin g sources . Paragraph s (a)(1 ) throug h (a)(8 ) of

thi s sectio n briefl y outlin e th e flow diagram s provided

. (1 ) Figur e 1 provide s a n overvie w of th e HO N wastewate r

provisions , (2 ) Figur e 2 outline s th e proces s fo r determinin g whethe r

astrea mmeet s th e HON definitio n of

aproces s wastewate r stream , . .'.'.'.'•...'' " •"'

. " '-

. • (3 ) Figur e 3 summarize s Grou p 1 an d Grou p 2 determination s fo r wastewate r stream s containin g Tabl e 8 HAP's , (4 ) Figur e 4 summarize s Grou p 1 an d Grou p 2 determination s fo r wastewate r stream s containin g Tabl e 9 HAP's , (5 ) Figur e 5 summarize s complianc e option s fo

r contro l o f

wastewate r stream s containin g Tabl e 8 HAP's , (6 ) Figur e 6 summarize s complianc e option s fo

r contro l of

wastewate r stream s containin g Tabl e 9 HAP!s , (7 ) Figur e 7 present s th e proces s uni t alternativ e complianc e optio n fo r contro l of wastewate r

stream s a t

existin g source s containin g Tabl e 9 HAP's , an d (8 ) Figur e 8 outline s complianc e option s fo

r contro l of

residuals

. (b ) Becaus e th e flow diagram s ar e intricatel y relate dt o Tabl e 8 an dTabl e 9 an dfo r eas y reference , thes e tw o table s ar e als o include di n thi s section

. BIUTJN O COD E 7IS<*-OI- O '.'•.'•'•." •P. 5

• *

. . 

### 1167 0 Federa

l Registe r 7 Vol

. 58 , No
. 3 7 /'Friday , Februar y 26 , 199 3 /Correction s

• Ye s
Contro l (Figure ; »5.&8 ) . • .



## Figur e 1 .Overvie wo

f HO N Wastewate r Provision sP. 6


### Federa l Registe r / Vol . 58, , No . 3 7 /Friday , Februar y 26 , 1993 /

Correction

s 1167 1

Figure 2 . HO N Wastewate r Determinatio nP. 7


### 1167 2 Fed;^/Reg^f;/^:yol.h5Q;'..Np X 37. / Friday , Februar y 26 , 199 3 / . Correction

s
D o fb r eac h wastewate r strea m generate d fro m a process uni t a t a ne wsourc e

Determin e Concentratio n an d Flo wRat e

Flowrat e &0.0 2 fp m ^s ^ N o an d Concentratio n o

f any Tabl e 8 HA P alOppmw ?

Grou p 1 Wastewate r Stream : Require s Treatmen t fo r Tabl e 8 HAP's G o t o Figur

e 5



## Figur e 3 . Grou p 1 an d Grou p 2 Determination s fo r Wastewate r Stream s

Tabl e 8 HAP' s (Refe r t o §63.132(c) )P. 8 

### Federa l Registe r /Vol . 58 , No . 37,/;,Friday ; Februar y 26 , 199 3 /Correction s 1167 3
D o fo r eac h wastewate r strea m

Determin e Concentratio n an d Flo wRat e (§63.132(1)

)

Tota l VOHA P Concentration ; 2100 0 ppm

wan d Flo

wRat e alOjepm ? ••(§63.132(0(1)0) -

Grou p 2 (Wastewater

) Strea m Yes Ye s

Grou p 2 (Wastewater

) Strea m



## 4 . Grou p 1 an d Grou p 2 Determination s fo r Wastewate r Stream s Tabl e 9>IAP' s (Refe r t o §§63.132(f) an d 63.138(c) ) g

### 1167 4 i * • YU

7I^e^7Rjegistei^/5Volv;58;sNo/3 7 ^Friday;:Fe ^ P. 9

Contro l Ai r Emission s Befor e an d Durin g Treatment/Recycl e

Fo r On e Grou p 1 '','"•' ; Wastewate r Strea m Only : '•'- • On e o r N o ^''"Mor e Grou p 1 and/or\ ^ Ye s J3rou p 2 Wastewate r Streams ^

Combined ?

1 > Recycl e t o Process . : 7 . . • : o r 2 . Us e Desig n Stea m Strippe r

o r • 3 . Reduc e VOHA P Mas s by.99 %

o r . ; : - ; " 7 • 4 . : Reduc e Concentratio n of Eac h HAPt o <10ppmw ' 7 : , n, ... Y y.;-~-.;h'vC i -•?• •

Fo r On e o r Mor e GroiTi p 1 / Grou p 7 2 Wastewate r Streams : 7 . 1 . Recycl e t o Process.^; : 7 ^ ; ;>v : ~ y v

.. ' ..-.'-o r -Y.YY'ZYY

'..'..,'.'.'••..••''•. ' 2 . Us e Design.Steam.Stripper.' ; ••."or""':-.; ' -

" • ' ""',': : y 3 . Reduc e VOHA P Mass 7 b y 99 % y •or ' , ;•• • . '"'y<,.y " 7 4 . ..Trea t t o Achiev e Require d

. Mas s Remova l : r y

Trea t Residual s (Figured ) {Determin e i

f Grou p 1 1 fb r Tabl e 9 HAP' s (Figur e 4 )



## Figure5 . ComplianceQptibnsforControliofTable;8 • HAP's 

# tfr§63 ? U-iYS.

s'A. vVi - -M-w

V '"'•'• • '••;;•.••: !

### Federal Registe r /Vol . 58 , No . 3 7 / Friday , Februar

y 26 , 199 3 /Correction s P.1 0



### 1167 5

Contro l Ai rEmissionsBefor e an d Durin g Treatment/Recycl e

Fo rOn e o rMor e Individua l Grou p 1 Wastewate rStreams : 1 Recycl e t o Proces s

o r 2

. Us e Desig n Stea m Strippe r

o r 3

. Reduc e VOHA P Mas s by Percentage s Specifie d fo r Strippabiirty Group s i n Tabl e 9 o r 4

. Reduc e Tota l VOHA P Concentratio n to<50ppm w o r 5

. Reduc e VOHA P Mas s b y 99 % Fo rOn e o rMor e Grou p 1 / Grou p 2 Wastewate rStreams : 1

. Recycl e t o Proces s . o r 2

. Us e Desig n Stea m Strippe r

o r 3

. Reduc e VOHA P Mas s by Percentage s Specifie d fo r Strippabiirty Group s i n Tabl e 9

o r 4

. Treat t o Achiev e Require d Mas s Remova l

o r 5.

. Reduc e VOHA P Mas s by 99 %



### Figur e 6 , Complianc e Option s fo r Contro l o f Tabl e 9 HAP' s

•.'."• • (Refe r t o §63.138(c) )p.1 1


### 1167 6 Federal s Registe r ./.Vol i 58; . N o 37- 7 Friday , February : 26;- : 1993 /Correction s

Fo r contro l of Tabl e 9 HAP' s ont y Non-proces s wastewate r stream s an d wastewate r stream s fro m othe r proces s unit s cahno » b e combine d whe n usin g thi s optio n

Contro l Ai r Emission s Befor e an d Durin g Treatment/Recycl e

Ai l Proces s Wastewate r Stream s fro m a Proces s Uni t Mus t Compl y wit h thes e Provision s i f thi s Optio n i s Selecte d

Fo r Al l Wastewate r Streams ; Recycl e t o th e Proces s

o r Reduc e Tota l VOHA P Concentratio n t o < 1 0 ppm wbefor e Bein g Discharge d o r Combine d wit h Wastewate r Stream s fro m Othe r Proces s Unit s



## Figur e 7 , Proces s Uni t Alternativ e Complianc e Optio n (Refe r to§63.138(d) ) :P.1 2


### Federal Registe r /

Vol. , 58 , No . 3 7 /

Friday , Februar

y 26 , 199 3 /

Correction s 1167 7

Contro l Ai rEmission s Befor e an d Durin g Treatment/Recycl e

Fo rAl l Residuals : 1

. Recycl e t o Proces s (include s sal e a s feedstock )

o r 2

. Retur n t o Treamen t Proces s

o r 3

. Destor

y Tota l HA P Mas s b

y 99 % (include s sal e fo renerg y recovery)



## Figur e 8 . Complianc e Option s fo r Contro l o f Residual s (Refe r t o §63.138(g) ) s s

BtUIN O COD E IMS-Ot- TP.1 3
1167 8 Registe r /Vol . 58 , No . 3 7 / Friday , Februar y 26 , 19,9 3 /Correction s \

TABL E 8.—ORGANI C HA P COMPOUND S SUBJEC T T O REQUIREMENT

S FO R PROC
ES S UNIT S A

T NE W SOURCE S Chemica l name Ally ) chlorid e Benzen e 1,3-Butadlen e Carbo n disulfid e Carbo n tetrachlorid e ....- Cumen e (isopropy l benzene ) Ethylbenzen e Ethy l chlorid e (Chloroethane) Ethyliden e dichlorid e (1.1 - Dichkxoethane) - Hexachlorobutadien e Hexachloroethan e Hexane Methy l bromid e (Bromomelhane) .. . Methy l chlorid e (Chtoromethane) .. . Methy l chlorofor m (1,1,1 - Trichloroethane) Phosgen e Tetrachloroethylen e (Perchloroethylene) T oluen e T richloroethylene ... 7 2.2.4-Trimethylpentan

e Viny l chlorid e ; Vinyliden e chlorid e (1,1 - Dichlorosthytene

) . . nvXylen e 7 p-Xylen e : '. : CA S numbe* 0
10705 1 7143 2 10698 0 7515 0 5623 5 9882 8 10041 4 7500 3 7534 3 8768 3 6772 1 11054 3 7483 9 7487 3 7155 6 7544 5 12718 4 10888 3 7901 6 54084 1 7501 4 7535 4 10838 3 10642 3 "CA S number

s refe r t o th e Chemica l Abstract s Servic e registr

y numbe r assigne d to specifi c compounds , isomers , o r mixtures o f compounds . TABL E 9.—ORGANI C HA P STRIPPABILIT Y GROUP S AN D TARGE T REMOVA L EFFI CIENCIE S Strippabilit

y grou p
A B C Compoun d nam e

Se e attache d lis

t o f compounds . Se e attache d Us

t o f compounds . Se e attache d list o f compounds . Targe t re mova l effi cienc y (percent) 9 9 9 5 7 0 Strippabilit

y grou p A Compoun d nam e

Acetaldehyd e ..7... . Ally l chlorid e Benzen e -.;.. . Benzy l chlorid e ... . 1,3-Butadien e Carbo n disulfid e . . Carbo n tetra -

. chloride . Chlorobenzen e ... . Chlorofor m Chloropren e (2 - Chk>ro-1,3-Butadiene) . CA S num ber " 7507 0 10705 1 7143 2 10044 7 9252 4 75252 10699 0 7515 0 5623 5 10890 7 6766 3 12699 8 Strippabilit

y grou p Compoun d nam e

Cumen e (iso propy l benzene) . 1.4-Dichtorobenzene(p) . 1,3-Dichtoropropene . Ethvlbenzen e Ethy l chlorid e (Chloro - ethane) . Ethylen e dibromide . Ethylen e dichloride (1,2 - Dichloro-eth - . ane) . Ethylen e oxid e Ethyliden e di chlorid e (1,1 - Dtchloro - eth ane) . Hexachloro - ben zene . Hexachloro - buta diene . Hexachloro - eth ane . Hexan e Methy l bromid e (Bromo-meth ane) . Methy l chlorid e (Chloro- meth - • ane) . Methy l chlorofor m (1.1.1-Tri chloro- ethane) . Methy l ethy l ke ton e (2 - Butanone) . Methy l isobuty l ke ton e (Hexone) . Methy l terl-buty l ether . Methylen e chlorid e (Dichloromethane) . Naphthalen e : 2-Nitropropan e Phosgen e Propylen e dichloride (1.2 - Dtchloro - pro pane) . Propylen e oxide.. . Styren e 1.1.2.2 - Tetrachloroe thane . Tetrachloro-ethyl en e (Perchloroethylene) . Toluen e 1.2.4-Trichtorobenzene . 1.1,2-Trichloroethane . Trichloro- ethylen e Triethylamin e 2,2.4-Trimethyl pentane . Viny l acetate Viny l chlorid e CA S num ber 0 9882 8 10646 7 54275 6 10041 4 7500 3 10893 4 10706 2

7521 8 7534 3

11874 1 8768 3 6772 1 11054 3 7483 9

7487 3

7155 6

7893 3
10810 1 163404 4 7509 2

9120 3 7946 9 7544 5 7887 5

7556 9 10042 5 7934 5

12718 4

10888 3 12082 1 7900 5 7901 6 12144 8 54084 1 10805 4 7501 4 Strippabilit

y grou p

B

C Compoun d nam e

Vinyliden e chlo ride. (1.1-DfcNoro ethylene) . m-Xyteh e .... . o-Xylen e Acetonltril e - Acetopherioh e Acrolei n Acrylonitril e 2-ChSoroace

tophenone . Dichtoroethy l ethe r N,NrOimethy»-anl line . 2,4-Dlnitro-phencJ Ethylen e glyco l di methy l ether . Ethylen e glyco l mono-buty l ethe r acetate . Isophoron e Methy l methacry

late . Propionalde-hyd e 2,4,5-Trichloro phenol . Anilin e o-Creso l Diethy l sulfate 3,3'-Dimethyl-ben zidihe . 1,1-Dim e thyl-hy drazine . Dimethy l sulfate .. . 2,4-Dinitro-toluen e 1,4-Dioxan e (1,4 - Di - ethylene oxide) . Epichloro-hydrin . (1-Chloro-2.3 - epoxy- propane) . Ethylen e glyco l mono-methy l ethe r acetate . Diethylen e glyco l diethy l ether . Diethylen e glyco l dimethy l ether . Ethylen e glyco l mono-ethy l ethe r acetate . Methano l o-ToiuJdin e CA S num ber "

7535 4 10838 3 9547 6 10642 3 7505 8 98862 10702 8 10713 1 53227 4 11144 4 12169 7 5128 5 14088 5 11071 4 11207 2
7859 1 8062 6 9895 3 12338 6 9595 4 6253 3 9548 7 6467 5 11993 7 5714 7 7778 1 12114 2 12391 1

10689 8 11049 6
11236 7 11196 6 11115 9
6756 1 9553 4

. "CA S numbers refe r t o th e Chemica l Abstracts Servic e registi y numbe r assigne d to specifi c compounds , isomers , o r mixtures , o f compounds . ' § 63.14 3 Proces s wastewate r jwovlolcno — bispocilcn o ond monitorin g o t operation a (a ) Fo reac h wastewate r tank , surfac e impoundment , container , individua l drai n system , an d oil-wate r separato r tha treceives , manages , o rtreat s a Grou p 1 wastewate r strea m o rresidua l remove d fro m a Grou p 1 wastewate r stream , th e owne r o roperato r shal lP. M


### Federa l Registe r

/ Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 / Correction s 1167 9 compl y wit h th e inspectionrequirement s specifiedi n Table 1 0 o f thi s subpart

.

to . compl y wit h Tanks : 63.133(bKD(H ) ~ . 63.133(c ) 63.133(d )
63.133(e ) _. . Surfac e impoundments : 63.134(bM1)(U ) '... 63.134(c ) „ Containers : 63.135(b)(2 ) ; 63.135(d)(2 ) 63.135(e ) - „ Individua l drai n systems.* : 63.136(b)(1)(H ) 63.136(b)(3 ) „ 63.136(c)(1 ) ............_„
63.136(c)(4)(l ) - , 63.136(c)(4)(H ) 63.l36(c)(4)(Hi ) '. Oil-wate r separators : 63.137(b)(1)(H ) •

• —.. . 63.137(c)....„

_

j . « 63.137(d ) TABL E 10.—MONITORIN G REQUIREMENT S FO R WAST E MANAGEMEN T UNIT S Inspectio n o r monitorin g requiremen t Inspec t fixe d roo

f an d al l opening s tor leaks 0

.... . Inspec t floatin g roo

f in . accordance wit h §§63.120(a)(2 ) an d (a)(3) . Measure floatin g roo

f sea l gap s I n accordance wit h §§63.120(b)(2)(i ) throug h (b)(6)(H) . —Secondar

y sea l gap s - Inspec t wastewate r tan k

fo r failures an d Im prope r wor k

practices . Inspec t cove r an d al l opening s fo r leaks 0 Inspec t surface impoundment fo r failures an d imprope r wor k

practices . Inspec t enclosur

e an d al l opening s fo r leaks"... . Inspec t containe r fo r failures an d imprope r wor k practices . Inspec t cove r an d a

O opening s fo r leaks 0 , . Inspec t individua l drai n syste m to r failures an d i imprope r wor k

practices . Verif y flo wo f wate r suppl y to al l drain s usin g :wate r seal s t o ensur

e appropriat

e wate r level s .an d t o preven t othe r condition s tha t reduce wate r sea l contro l effectiveness . Inspec t al l drain s usin g tightly-seale d cap s o r plug s t o ensur e cap s an d plug s ar e I n plac e an d properl y installed . Inspec t al l junctio n boxe s to ensur e cover s ar e i n plac e an d hav

e tigh t seal s aroun d edges . Inspec t unburied portio n o

f al l sewe r lines fo r crack s an d gaps . Inspec t fixe d roo

f an d a H opening s fo r leaks " .... . Measure floatin g roo

f sea t gaps b t accordance wit h 4 0 CF R 60.696(d)(1) . ; -Primar y sea l gap s ; —Secondar

y sea l gap s Inspec t oil-wate r separato r fo r failures an d im prope r wor k

practices . Frequenc y

-AftftUfilt V MMM * M..M.M . M M .... . .. . Se e §63.120('al('27a ^ (a)(3 )

Onc e ever

y 5 years . Annually . Semi-annuall y
Annuall y Semi-annuall y
Annuall y

Annuall y Semi-annuall y „ Semi-annually :

Semi-annuall y Semi-annuall y

Once ever

y 5 years . Annually . . Semi-annuall y ; - Metho d
Metho d 21 b

. Visual . Se e § 63.120(b)(2)(H ) throug h (b)(6)(H )
Visual . Matho d 2 1 •» . Visual . Metho d 21 b

. Metho d 21" . Visual . Metho d 21" . Visual . Visual .

Visual . Visual . Metho d 21 b See40CFR60.686(dX1) .
Visual .

" Leak s ar e detectabl e emission s o f 50 0 parts pe r millio n b y volum e abov

e background . •"Method 2 1 o

f 4 0 CF R Part 60 , Appendi x A . c A s specifie d I n §63.136(a) , th e owne r o r operato r shal l comply wit h th e requirements o f eithe r §363.13 6 (b ) o r (c) . 

### (b ) Fo r each waste managemen

t uni t o r treatmen t proces s use dto compl

y wit h § 63.138(b)(1) , (c)(1) , o

r (d ) o f thi s subpart , th e owne

r or operator shal l compl

y wit h th e monitoring requirement s specifiedi n Tabl e 1 1 o f thi s subpart

.

. T o compl y wtt h 1 . Effluen t totaJ VOHA P aver ag e concentration : 63.138 - (c)(1)(H)(C ) 63.138(d)(2)(i) . TABL E 11.—MONITORIN G REQUIREMENT S FO R TREATMEN T PROCESSE S Parameters to be monitore d A . Measure effluen t tota l V O concentratio n a s a surrogat e fo r VOHA P concentration , o r B . Measure effluen t tota l VOHA P concentraSo n Frequenc y

Monthl y „:.„.i..„.„.i„...„„. 4 Method s Metho d 25 D Propose d Matho d 305 , o r an y othe r appiicabi e meth o d whic h ha s bee n vali date d usin g sectio n 5. 1 o r 5. 3 o f Metho d 30 1 °1168 0 Federal ; Register . / Vol . 58 , No ; 3 7 /

Friday * Februar y 26 , 199 3 / Correction s TABL E 11.—MONITORIN G REQUIREMENT S FO R TREATMEN T PROCESSES—Continue d T o compl y wit h 2 . Effluen t VOHA P concentra tio n o f eac h HAP : 63.138 - (b)(1)(H)(A): ; ; 3 . Percentag e reductio n o f tota l VOHA P mas s f}o w rate : 63.138(c)(1)(ii)(B) ; 63.138(c)(1)fiH)(B) .

4 . Percen t reduction : d f VOHA P mas s flo wrat e fo r eac h strippability grou p ' of HAP's : 63.138(b)(1)(H)(C ) 63.138(b)(1)(Hi)(A ) 63.138(c)(1)(H)(D ) 63.138 - (c)(1)(iii)(C) .

5 . VOHA P mas s remova l of : HAP' s I n a treatmen t proc es s othe r tha n a properl y operate d biologica l treat men t uni t 63.138(b)(1)(Hi)(C) :

6 . VOHAP . mas s remova l o f total HAP' s I n a treatmen t proces s othe r tha n a prop erty operate d biologica l treatmen t uni t

. 63.138(c)(1p)(D) . ; ' 7 . VOHA P mas s remova l o f eac h o r total HAP s i h a properl y operate d biologica l treatmen t uni t 63.138(b)(1) - f.ii)(C ) 63.138(c)(1)(ifl)(D) , . : 8 . Altemativ e t o item s 1 throug h 7 above . 9 . Desig n stea m strippe r 63.138(f)(3) , (4) . (5) . an d (6) . Parameter s to b e monitore d Measur e VOHA P concentratio n of eac h HA P

A . Measur e total V O concentratio n a s a surro gat e fo r VOHA P concentratio n I n influen t an d 7 effluent , o r ; - ' B . Measur e total VOHA P concentratio n I n Influ en t an d effluen t

A . Measure : VOHA P concentratio n of eac h strippability grou p of HAP' s I n influen t an d ef fluent o r •

B . Measur e concentration s o f speciate d HAP' s I n Influen t an d effluen t
A . Measur e VOHA P concentratio n of eac h HA P i n influen t an d effluen t of treatmen t proces s o r treatmen t proces s train , o r B . Measur e concentration s of speciate d HAP s i n influen t an d effluen t of treatmen t proces s o r treatmen t proces s trai n Measur e tota l VOHA P concentratio n I n Influen t an d effluen t o

f treatmen t proces s o r treatmen t proces s trai n v ;
Appropriat e parameter s ma y b e monitore d upo n approva l fro m th e Administrato r i n accordanc e wit h ih e requirement s specifie d i n §63.143(c )
Othe r parameter s ma y b e monitore d upo n ap prova l fro m th e Administrato r i n accordanc e wit h th e requirement s specifie d I h § 63.143(d ) Stea m flowrat e ......:.............:..... . .....Y......... Wastewate r fee d mas s flowrat e ........ .
Wastewate r fee d temperatur e

> Condense r vapo r outle t temperatur e ................. . Frequenc y Monthl y „ ; ... .

Monthl y . : ;.... .
Monthl y ..;........ . ,..„...., „

Monthly ; •i;.:..i..:.±.L.^.^..:.;

Monthly : .......;......... . Mdntt5ly ; .;..:....:..;„....;,:..„... L

Monthly......v..:.......;.;..;;.:.„..;; /

. MonthVC.„....-7;.:...:.......:.... :

Monthl y ..........;.....;.„;J..;..v.;.. .

Continuousl y ...........7..;.. ' Continuousl y ...........7„.,.. „
Continuousl y ..;.....i.,......U..;; .

Continuousl y ..;.....:.,;.;...-..:;:„ .

•I f method(s ) ar e use d t o measur e organi c HA P concentration s bi'' a wast e o r wastewate r stream ; ra l concentration s I n a n ai r strea m purge d fro m a wast e o r wastewate r stream , the . correctio n factor s liste d I n Tabl e result s t o provid e a measur e of th e volalfl e portio n Oe. . th e VOHA P concentratlbn ) o f th e organi c HAP's . Method s Propose d Metho d 305 , o r an y othe r applicabl e meth o d whic h ha s bee n vali date d usin g sectio n 5. 1 o r 5. 3 of Metho d 301 » Metho d 25 D
Proposed - Metho d 305 , o r : an y other , applicabl e meth - ; o d whic h ha s bee n vali date d usin g sectio n 5. 1 o r • 5. 3 of Metho d 30 1 • - Propose d Metho d 305 , o r an y othe r applicable'meth o d whic h ha s bee n vali date d usin g sectio n 5. 1 o r 5. 3 o f Metho d 30 1 \
An y applicabl e metho d whic h ha s • bee n validate d usin g : sectio n 5. 1 o r 5. 3 of Meth o d 301 ' • • ..";- : y Proposed . Metho d 305 , o r an y othe r applicabl e meth -

. o d whic h ha s bee n vall - • date d usin g sectio n 5. 1 b r 5. 3 of Metho d 30 1 • An y appiicabi e metho d whic h ha s bee n validate d usin g sectio n 5. 1 o r 5. 3 of Meth - .' • ,od.30ir ; :.•'

• Proposed ' Metho d 305 , o r an y othe r applicabl e meth - • , ' bd ; whic h jia s bee n vall- ; i date d usin g Sectio n 5. 1 o r 5. 3 of Metho d 30 1 \ Metho d 304 , o r an y othe r metho d whic h ha s bee n approve d by EP A durin g compliance : ,:

•demonstra -

- tion s ; , Integratin g stea m flowmon - • •itorin g 'devic e •

•equippe d wit h a continuou s recorde r Uqul d flo wmete r installe d a t stripper: . - influent ' and ;
, equippe d wit h a-contlnu - " ' ; bu s recorder* Y

'• Y Y" ."• • Lkjuid ; .temperatur e -monitor l ; ..in g .devic e J Installe d a t 7 strippe r Influen t an d ; equippe d wit h a i continu ou s recorde r ;-. Temperatur e monitorin g de vic e Installe d a t condense r vapo r outle t an d equippe d wit h a continuou s recorde r he r tha n measurin g VOHA P 1 3 ma y b e use d to adjus t th e P.1 5



### >P.1 6

Federa l Registe r/

Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s 1168 1 (c ) I f th e owne ro

roperatorelect s t o compl y with Ite

m 7 i n Tabl e 1 1 of

thi s subpart , th e owne ro

roperatorshal l requestapprova

l t o monito rappropriat

e parameter

s tha tdemonstrat

e prope r operation ofth e biologica l treatmen t unit . Th e reques tshal l b e submitte d accordin g t o th e procedure s specifie d i n § 63.146(a)(3 ) and i n eithe r§ 63.151(f ) o r § 63.152(e ) o

f thi s subpart. (d ) I f th e owne ro

roperatorelect s t

o compl y with Ite

m 8 i n Table 1 1 o

f thi s subpart , th e owne ro

roperatorshal l requestapprova

l t o monito rparameter

s othertha n thos e liste d i n Item s 1 throug h 7 o f Tabl e 11 . Th e reques tshal l b e submitte d accordin g t

o th e procedure s specifie d i n § 63.146(a)(3 ) an d i n eithe r§ 63.151(f

) o r§ 63.152(e ) of thi s subpart

, and shal l includ e a descriptio n o f

planne d reporting and recordkeeping procedures . Th e Administrato rwil l specif y appropriat

e reporting and recordkeeping requirement

s as par tofth e revie w o

f th e Implementatio n Pla

n o rpermi t application . fe ) Excepta s provide d i n paragraph

s (e)(4 ) an d (e)(5 ) o f thi s section , fo

reach close d ventsystem an

d control devic e use d t o compl y wit h th e requirement s of §§63.13 3 throug

h 63.13 9 of

thi s subpart , th e owne roroperato rshal l compl y with th e requirements i n § 63.139(e) , (f) , and (h) of thi s subpart, and with th e requirements specifie d ix. paragrap h (e)(1) , (e)(2) , o r(e)(3 ) o f thi s section . (1 ) Th e owne ror operato rshal l compl y with th e monitorin g requirement

s specifie d i n Tabl e 1 2 of thi s subpart ; or

Contro l devic e Al l contro l device s :. .

Therma l incinerato r

Boile r o r proces s heate r <4 4 megawatts an d ven t strea m i s no t mixe d wit h th e pri mar y fuel .
Carbo n adsorbe r (regenera tive) .

Carbo n adsorbe r (non-regen erative) . TABL E 12.—MONITORIN G REQUIREMENT S FO R CONTRO L DEVICE S Monitorin g equipmen t require d 1 . Flo windicato r Installed at al l bypass lines to th e atmospher

e an d equipped wit h continuou s recorder 6 or. 2. Valve s seale d ciosed wit h car : sea l o r lockand-ke y configuration . Temperatur

e monitorin g devic

e installed i n fire bo x o r i n ductwor k

Immediatel y downstrea m o f firebo x * an d equipped wit h a continuou s re ^ corder 6

. Temperature monitorin g device installed i n ga s strea m immediatel y befor e an d afte r catalys

t be d an d equippe d wit h a continuou s re corder 6

. Hea t sensin g device installed at th e pilo t light an d equippe d wit h a continuou s recorder b

. Temperature monitorin g devic e installed i n fire box * an d equipped wit h continuou s recorder6

. Temperatur

e monitorin g devic

e Installed a

t con dense r exi t an d equipped wit h continuou s re corder b

. Integratin g regeneratio n strea m flowmonitorin g devic e havin g a n accurac y o f ±1 0 percen t an d equippe d wit h a continuou s recorder6 , and. Carbo n be d temperatur e monitorin g device equippe d wit h a continuou s recorder 6

.

Organi c compoun d concentratio n monitorin g de vice 0

. Parameters to b e monitored 1 . Presence o

f flowdiverte d fro m th e contro l devic e t b th e atmospher

e or. 2. Monthl y inspection s o f seale d valves .

• ; Temperatur

e upstrea m an d downstrea m o

f catalys

t bed. . Presenc e o

f a flam e at th e pilo t Ught . Combustio n temperatur e

Condense r exi t (produc t side ) temperature . Total . regeneratio n strea m mass flowdurin g carbo n be d regeneratio n cyde(s). : Temperatur

e o f carbo n be d afte r regeneratio n (an d withi n 1 5 minute

s o f com pletin g an y coolin g cycle(s) ] an d duratio n o f th e carbo n be d steamin g cycle . Organi c compoun d con centratio n o

f adsorbe r ex haus t . Frequenc y Continuou s
Monthl y Continuou s

Continuou s

Continuou s Continuou s

- Continuou s
Continuou s

3 ••

• ••

- Continuou s . .

, , DaU y o r a t interval s n o great e r tha n 2 0 percen t o

f th e desig n carbo n replacemen t interval , whicheve r I s greate r * Monito r ma y b e installe

d i n th e firebo x o ri n th e ductwor k Immediatel

y downstrea

m o f th e firebo x befor e an y substantia

l hea texchang e i s encountered

. 6 "Continuou

s recorder " i s define d i n §63.11 1 o

f thi s Subpar t cA s a n altemativ

e to conductin

g thi s monitoring

, a n owne r o r operato r ma y replac e th e carbo n i n th e carbo n adsorptio

n syste m wit h fres h carbo n a ta regula rpredetermine

d time interva

l tha tis les s tha

n th e carbo n replacemen

tinterva l tha ti s determine

d b y th e maximu m desig n flo w rat e an d organi c concentratio

n i n th e gas strea m vente d t o th e carbo n adsorptio n system . (2) Th e owne r o

roperatorshal l us e a

n organi c monitorin g devic e installe d at . th e outle tof

th e contro l devic e and equippe d with a continuou s recorder . Continuou s recorderi s define d i n § 63.11 1 of

thi s subpart ; o r (3 ) Th e owne ro roperatorshal l reques tapprova

l t o monito rparameter

s othe rtha n thos e specifie d ir

i paragraph

s ' " (e)(1 ) and (e)(2) of

thi s sectiori . Th e requestshal l b e submitted accordin g t o th e procedure s specifie d i n § 63.146(a)(3 ) and i n eithe r § 63.151(f ) o r § 63.152(e ) o

f thi s subpart, and shal l includ e a descriptio n o f

planne d ; reporting and recordkeepin g procedures . Th e Administrato rwil l specif y appropriat

e reportin g and recordkeepin g requirements a s par tofP.1 7


### 1168 2 Federa l Register, / Vol

. 58 , No
. 3 7 /

Friday , Februar

y 26 , 199 3 /

Correction s th e revie w o f th e Implementatio

n Pla n o rpermitapplication . (4 ) Fo ra boile rorproces s heate ri n whic h al l ven tstream s ar e introduce d with primar

y fuel,'th e owne roroperato r shal l compl y wit h th e requirement s i n § 63.13 9 (e) , (f) . an d (h) , bu tth e owne r oroperatori s exemp tfro

m th e monitorin g requirements specifie d i n paragraph

s (e)(1 ) throug

h (e)(3 ) of thi s section . (5 ) Fo ra boile rorproces s heate rwith a desig n heatinpu tcapacit y of 4 4 megawatt s or greater , th e owne ro

r operator shal l compl y with th e requirement

s i n § 63.13 9 (e) , (f) , an

d (h) , butth e owne roroperato ri s exemp t fro m the.monitorin g requirement s specifie d i n paragraphs.(e)(1 ) throug h (e)(3 ) of thi s section . (f ) Fo reach paramete

rmonitore d i n accordance with paragrap h (c) , (d) , o

r(e) of Uiis section , th e owne ro roperator shal l establis h a rang

e tha tindicate s properoperatio n of

th e treatmen

t proces s o rclose d ven tsyste m and control device . I

n ordert o establis h th e range, th e informatio n required i n § 63.152(b)(2 ) of

thi s subpar

tshal l b e submitte d i n th e Notificatio n o f Complianc e Statu s orth e operatin g permi tapplicatio n i n accordance wit h th e requirementspecifie d i n § § 63.14 6 (b)(6)(ii)(A ) and (b)(7)(iii) . (g ) Monitorin g equipmen tshal l b e installed , calibrated , and maintaine d accordin g t

o th e manufacturer' s specifications . § 63.14 4 Proces s wastewate

rprovisions tes tmethod

s en d procedure

o t o determin

e applicability. (a ) An owne roroperato rshal l determin e th e annual wastewate r quantit y fo ra wastewate rstrea

m b y on e o f th e followin g methods : (1 ) Selectin g th e highes tannua l quantit y o f wastewate rmanaged fro m historical record s representin g th e mos t recent5 year s o f

operatio n or , i f

th e proces s uni ta

tth e sourc e ha s bee n i n servic e fo rles s tha n 5 years buta

tleas t 1 year , fro

m historica l record s representin g th e total operatin g lif e o f th e source ; (2 ) Usin g th e maximum desig n capacit y Ofthe waste managemen tunit ; (3 ) Usin g th e maximu m wastewate r generatio n rat

e base d o n th e maximu

m desig n productio n capacit y ofth e proces s uni tgeneratin g th e wastewate r stream ; o r (4 ) Measurement

s tha tar e representative of

maximu m wastewate r generatio n rates . (b ) A n owne ro

roperatorshal l determin e th e tota

l VOHA P averag e concentratio n o

raverag e VOHAP . concentratio n of

each HA P fo rth e poin t o f generatio n of

each wastewate rstrea

m b y on e of th e followin g methods : (1 ) Knowledg e ofth e wastewater . Tfie owne roroperatorshal l provid e sufficien tinfonnatio n t

o documentth e total VOHA

P averag e concentratio n o

r average VOHA

P concentratio n of

each HA P o f each wastewate r stream . Example s of

information tha

tcoul d constitut e knowledg e includ e materia l balances , record s of

chemical s purchases , proces s stoichiometry , o r previou s tes tresults provided th e result s ar e stil l representative o

f curren t operatin g practice s a

tth e proces s unit(s) . I f tes tdat a ar e used , the n th e owne roroperator shal l provid e documentatio n describin g th e testin g protoco l and th e means b y whic h samplin g variabilit

y an d analytical variabilit y were accounted fo

rin th e determinatio n ofth e tota

l VOHA P averag e concentratio n o

raverag e VOHA P concentratio n o

f eac h HA P fo r th e wastewate rstream . (2) Bench-scal e o

rpilot-scal e testdata . Th e owne ro

roperator shal l provid e sufficien tinformation t o demonstrat e tha tth e bench-scal e o

rpilot-scal e tes t concentratio n dat

a ar e representative of th e actual tota

l VOHA P averag e concentratio n o

raverag e VOHA P concentratio n of

each HAP

. Th e owne r oroperatorshal l als o provid e documentatio n describin g th e testin g protocol , and th e means b y whic h samplin g variabilit

y and analytica

l variabilit y were accounte d fo

ri n th e determinatio n of

tota l VOHA P averag e concentratio n o

raverag e VOHA P concentratio n o

f eac h HA P fo rth e wastewate rstream . (3 ) Measurement

s mad e a tth e poin tof generatio n or, whe n notfeasible , measurement

s made a ta downstrea

m locatio n tha

tar e corrected t o poin to f generatio n value s o f th e total VOHA

P average concentratio n o raverage VOHA P concentratio n of

eac h HA P i n th e wastewate rstrea

m i n accordanc e with th e followin g procedures : - (i ) Collec ta minimu m o f

thre e sample s fro

m each wastewate rstrea

m whic h ar e representativ e o f

nonna l flo w and concentratio n conditions . Where feasible , sample s shal l b e taken from a n enclose d pip e prio r t o th e wastewate r bein g expose d t o th e atmosphere . Wastewatersample s shal l b e collecte d u&jn g th e samplin g procedure s specifie d i n 4 0 CF Rpar t60 , appendi x A , Metho d 25D . (ii ) Whe n samplin g from a

n enclose d pip e i s no tfeasible , a minimu m of thre e representativ e sample s shal l b e collecte d i n a manne rt o minimiz e exposur e o

f th e sampl e t o th e atmosphere and los s of

HA P compound s prio rt o sampling . (iii ) Eac h wastewate rsampl e shal l b e analyze d usin g on e o f

th e followin g tes t method s fo

rdeterminin g th e tota

l VOHA P averag e concentratio n o

r average VOHA

P concentratio n o f

eac h HA P i n e wastewate rstream : \ (A ) Fo rtota l VOHA P average concentratio n oraverage VOHA P concentratio n o

f each HAP, propose d Metho d 30 5 shal l b e used . TTi e targe t component s shal l b e strippe d from th e wastewate rsample s usin g th e procedure s specifie d i n propose d Metho d 30 5 (i.e. , suspende d i n a polyethylen e glycol/wate r matrix , heate d t o 75 °C , purged wit h 6 liter s pe r minute p f gaseou s nitrogen , sample d fo r 3 0 minutes , etc.) . Th e exitin g purge strea m containin g th e targe

tcomponent s shal l b e collecte d and analyze d usin g th e appropriat

e technique s describe d i n propose d Metho d 305 . Th e precisio n and accurac

y requirement

s of propose d Metho d 30 5 mus tb e meta s par tof th e complianc e requirement

s o f thi s rule . Performanc

e audi tsamples , i

f available , shal l b e analyze d usin g th e procedure s specifie d i n propose d Metho d 305 . Th e followin g equatio n shal l b e use d t o calculate th e VOHA

P concentratio n ofa n individually-speciate d compoun d i n th e wastewate rfrom th e propose d Metho d 30 5 result :



### 24.05 5 76 0 x xtxLxlO 3 

### )/M sP.1 8

e r/ Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s where : Cw=VOHA

P concentratio n ofth e individually-speciate d HA P compoun d i n th e wastewater , part s pe r millio n b y weight . Cc=Concentration of

compoun d i n th e gas stream , a s measured b y propose d Metho d 305 , part s pe r millio n b y volum e o n a dr y basis . Ms=Mas s o f

sample , from propose d Metho d 305 , milligrams . MW=Molecula

rweigh to

f th e HA P compound , gram

s pe rgram-mole . 24.055=Ideal gas molarvolum e a t29 3 "Kelvi n and 76 0 millimeter s of mercury , liter s pe rgram-mole . Pi=Barometri

c pressure a

tth e tim e o

f sampl e analysis , millimeter s mercur y absolute . 760=Reference o

r standar d pressure , millimeter s mercur

y absolute . 293=Reference o

rstandar d temperature , "Kelvin . T;=Sampl e gas temperatur

e a tth e tim e of sampl e analysis , "Kelvin . t=Actua l purge time , fro

m propose d Metho d 305 , minutes . L=Actua l purge rate , from propose d

. Metho d 305 , liter s pe rminute . 103 =Conversio n factor, milligram s pe r gram. Tota l VOHA P averag e concentratio n ca

n b e determine d b y summin g th e VOHA P concentration s o

f all HA P compound s i n th e wastewater . (B ) Metho d 25D o

f par t60 , appendi x A ma y b e use d instea d o

f propose d Metho d 30 5 t o measur

e tota l V O averag e concentratio n a s a surrogat e fo rtota l VOHA P averag e concentration ; (C ) A tes tmetho d o

rresults from a tes tmetho d thatmeasure s organi c HA P concentration s i n th e wastewater , an d tha tha s bee n validate d accordin g t o sectio n 5. 1 or 5. 3 of

Metho d 30 1 of appendi x A of

thi s par tma y b e used . Th e specifi c requiremento f propose d Metho d 30 5 t o collec tth e sampl e into polyethylen e glyco l woul d notb e applicable . Th e concentration s ofth e individua l organi c HA

P compound s measured i n Ui

e wate rma

y b e corrected t o thei rconcentration s had the y bee n measure d b y propose d Metho d 305 , b y multiplyin g each concentratio n by th e compound-specifi c fraction measured factori n Tabl e 1 3 of

thi s subpart. TABL E 13.—FRACTIO N MEASURE D (F,» ) AN D FRACTIO N EMITTE D (F e ) FO R HA P COMPOUND S I N WASTEWATE R STREAM S Chemica l Warn s Acetaldehyd e
Acrolei n F m 0.72 4 0.73 9 0.80 7 0.85 0 0.87 5 F .

0.46 9 0.35 4 0.30 2 0.44 5 0.45 7 TABL E 13.—FRACTIO N MEASURE D (Fm )

AN D FRACTIO N EMITTE D (F e ) FO R HA P COMPOUND S I N WASTEWATE R STREAMS—Continue d Chemica l Nam e Ally l chlorid e . .. . „ . AnBin ® . ;~ . Benzy l chlorid e . . ........ . 1,3-Butadien a Carbo n disulfid e 2-Chleroacetopherton e .... . Chlorofor m Chloropren e (2-Chloro 1,3-6utadiene) Cumen e (isopropy l ben zene ) 1,4-Dich(oroben2ene(p)... . 1,3-Dlchloropropen e Diethy l sulfat

e
_ S.S'-Dimethylbenzldln e .... . 1,1-Dimethylhydrazin e 2,4-DJnitropheno l 2,4-Dtnitrotoiuen e 1,4-Dioxan e (1,4 - Diethyleneoxlde

) Epichlorohydrin(1-Chloro2,3-epox y propane

) Ethylbenzen e Ethy l chlorid e (Chloroethane

) Ethylen e dichlorid e (1,2 - Dtchlorosthane

) Ethylen e oxid e Ethyliden e dichlorid e (1,1 - Dichloroethane

) Diethylen e glyco l diethy l ethe r Ethylen e glyco l monobuty l ethe r acetate Ethylen e glyco l dimethy l ethe r Ethylen e glyco l monoethyl . othe r acetate .. . Diethylen e glyco l dimethy l ethe r Ethylen e glyco l monomethy l ethe r ace tate „ Hexachlorobenzen e Hexachlorosthan e Hexan e Methano l Methy l bromid e (Bromomsthans) „ Methy l chtorid s (ChJoromethane

) .......... . Methy l chlorofor m (1,1,1 - TrtehJoroathane

) Methy l ethy l keton e (2 - Butamms

) .... . 

### F

„ 1.00 0 0.24 5 1.00 0 1.00 0 1.00 0 0.48 1 1.00 0 1.00 0 1.00 0 0.84 1 1.00 0 1.00 0 1.00 0 0.11 9 1.00 0 1.00 0 0.93 9 1.00 0 1.00 0 0.01 4 0.11 0 0.48 6 0.07 7 0.01 4 0.00 4 0.68 1 0.85 9 0.78 8 1.00 0 1.00 0 1.00 0 1.00 0 0.71 2 1.00 0 0.77 0 0.10 0 0.68 0 0.36 0 0.37 0
0.37 0 1.00 0 1.00 0 1.00 0 1.00 0 0.99 7 0.32 1 0.53 9 1.00 0 1.00 0 0.88 1 F 0

0.75 5 0.19 4 0.72 1 0.53 4 0.55 0 0.56 8 0.88 8 0.80 2 0.83 2 0.37 5 0.69 8 0.69 9 0.60 4 0.18 9 0.77 7 0.68 4 0.35 8 0.69 2 0.32 9 0.27 5 0.23 3 0.18 9 0.24 7 0.29 7 0.23 1 056 8 0.29 3 0.45 9 0.74 4 0.77 2 0.58 1 0.61 9 0.51 5 0.72 2 050 6 0.32 8 0.38 9 0.19 4 0.18 4
050 8 0.63 7 0.76 1 0.74 8 1.00 0 0.39 7 0.27 8 0.73 5 0.75 1 0.79 6 0.47 5 TABL E 13.—FRACTIO N MEASURE D (Fm )

AN D FRACTIO N EMITTE D (F e ) FO R HA P COMPOUND S I N WASTEWATE R STREAMS—Continue d Chemica) Nam

® Msffiy l isobuty l keton e Methy l tart-buty l ethe r Methylen e chlorid e
2-Nitropropan e Phosgen e Propylen e dichtortd e (15 - Dichloropropane

) 1,15.2-Tetrachloroethan e Tetrachloroethylen e Toluen e o-ToMdin e 1,2,4-Trlchlorobenzen e ... . Trichloroethylen e 2,4,5-Trichloropheno l 2,2,4rTrimethy!pentan e ... . Viny l chlorid e Vinyliden e chlorid e (1,1 - Dichloroethytene

) • C J

0.95 4 0.80 2 0.91 1 1.00 0 1.00 0 0.57 5 0.53 7 0.86 8 0.81 3 1.00 0 0.84 1 1.00 0 1.00 0 1.00 0 1.00 0 0:26 7 1.00 0 0.96 6 1.00 0 058 6 0.93 0 1.00 0 0.74 8 1.00 0 1.00 0 1.00 0 1.00 0 1.00 0 F

o
0.54 7 0.44 7 0.57 0 0.68 0 0.56 1 0.36 5 0.46 9 0.94 5 0.42 4 0.67 8 0.54 1 0.67 1 0.51 8 0.79 7 0.73 1 0.19 8 0.65 2 0.59 6 0.76 1 059 8 0.47 3 1.00 0 0.56 4 0.82 3 0.82 2 0.74 0 0.71 2 0.74 0 (iv ) Th e total VOHA

P average concentratio n o

r average VOHA

P concentratio n of

each HA P shal l b e calculate d b y averagin g th e result s o f th e sampl e analyse s a s follows :

_l. n . 

### C = —x l (Q0(Ci ) Q

. ,= 1 where : C=Tota l VOHA P average concentratio n oraverage VOHA

P concentratio n o f each HA P forwastewate rstream , part s pe rmillio n b y weight . Q,=Tota l annual wastewate r quantif y for wastewate rstream , kilogram s pe r year . n=Numbe rof

wastewate rsample s (a

t leas t3) . Q=Annua l wastewate r quantif y fo r wastewate rstrea

m represente d b y Q , kilogram s pe ryear . Q=Measure d average concentratio n (i.e. , tota l VOHA P average concentratio n o r average VOHA

P concentratio n o f each HAP

) i n wastewate rsampl e i , part s pe rmillio n b y weight .



## ii um\.mmmimmmm.mmmP.1 9 

### 1168 4 Federal Registe r / Vol . 58 , No . 3 7 /Friday , Februar y 26 , 199 3 /

Correction s (c ) T o demonstrat

e tha tth e tota l VOHA P mas s flo w rat

e from Grou

p 1 wastewate rstream s i n ne w an d existin g SOCM I unit s i s les s tha

n 1 megagra

m pe ryea ra s specifie d i n § 63.138(c)(5 ) of thi s subpart, a

n owne roroperato rshal l determin e fo

rthe'sourc e th e total VOHA P mas s flo w rat

e from al l Grou

p 1 wastewate rstream s identifie d i n § 63.132(f)(1 ) o f

thi s subpar

tatthei r point s o f generatio n b y th e followin g procedure : (1 ) Determin e th e annua

l wastewate r quantit y fo reac h wastewate rstrea

m usin g th e procedure s specifie d i n paragrap h (a) o f thi s section . (2 ) Determin e th e total VOHA P average concentratio n fo

reach wastewate rstrea

m usin g th e procedure s specifie d i n paragrap

h (b) o f thi s section . (3 ) Calculat

e th e annua

l tota l VOHA P mas s flo w rat

e i n eac h wastewate r strea m b y multiplyin g th e annua l average flow rat

e 7o f th e wastewate r strea m time s th e total VOHA

P averag e concentration . (4 ) Calculat

e th e tota l sourc e VOHA

P mas s flo w rat

e from al l Crou

p 1 wastewate r stream s b y addin g togethe r th e annua

l tota l VOHA P mas s flo w rat

e from each Grou

p 1 wastewate rstream . (d) A n owne ro roperatorelectin g t o " reduce th e total sourc e VOHA P mas s flow rat e t b les s tha n 1 megagra

m pe r yeari n accordanc e wit

h § 63.136(c)(6 ) of thi s subpar

tshall determin e th e total sourc e VOHA

P mas s flow rat

e fro m Grou p 1 wastewate rstreams identifie d i n § 63.138(f)(1 ) o f

thi s subpar

tby th e followin g procedures : (1 ) Th e annual tota

l VOHA P mas s flow rat e o f eac h Grou

p 1 ; wastewate r strea m treate d t o th e leve l of

th e provision s o f

63.138(c ) of

thi s subpar

t shal l no tb e include d i n th e tota l sourc e VOHA P mas s flo w rat

e calculation . (2 ) Foreac h untreated Grou p 1 wastewate rstream , annua l tota l VOHA P mas s flo w rat

e shal l b e determine d by th e procedure s ir

i paragrap h (c) o f thi s section . (3 ) Fo r eac h Grou

p 1 wastewate r strea m treate d t o level s les s tha n required b y th e provision s of § 63.138(c ) o f thi s subpart, Ui

e annual tota

l VOHA P mas s flo w rate shal l b e determine d a s follows : (i ) Measurementp

r samplin g shal l occur, a tth e poin to f

discharg e o

f th e treatmen tproces s orserie s o f

treatmen t processes . Th e poin to f

discharg e is define d a s th e point-wher e th e treated wastewate rexit s th e treatmentprbces s butbefor e i ti s m^xe

d with other . wastewate rstreaiBs . and prio rt o exposur e t o th e athiosphere . (ii ) Determin e th e annua

l wastewate r quantit y foreac h wastewate rstrea m a t th e poin to

f discharge of

th e treatment proces s orserie s of

treatmen tprocesse s usin g th e procedure s specifie d i n paragrap h (a ) of thi s section . (iii ) Determin e th e total VOHA P average concentratio n fb

r eac h wastewate rstrea

m a tth e poin to f discharg e usin g th e procedure s specifie d i n paragrap

h (b ) of thi s section. " (iv ) Calculat

e th e annual total VOHA

P quantit y i n each wastewate rstrea m b y multiplyin g th e annua

l wastewate r quantit y ofth e wastewate rstrea

m time s th e tota l VOHA P averag e concentration . (4 ) Th e tota

l source VOHA

P mas s flow rat e shal l b e calculate d b y summin g th e annua

l tota l VOHA P 

# J uantit y from al l wastewate r streams a s etermine d i n paragraph

s (d)(2 ) and (d)(3 ) o f thi s section . (e) T d determin e th e annua

l averag e wastewate rflo w rat

e fo ra wastewate r stream , on e ofth e followin g method s shal l b e used : (1 ) Us e th e maximu

m productio n capacit y ofth e proces s unit , knowledg e of th e process , and mas s balanc e information t o either : estimate directl y th e average wastewate rflo w rate ; o r estimate th e tota

l annua l wastewater , volum e and the n divid e total volum e b y 525,60 0 minute s i n a year , (2 ) Selec tth e highes taverage flow rat e of wastewate rfro

m historical record s ":

" representin g th e mos trecen t5 years of operatio n or , if

th e proces s uni tha s bee n i n servic e fo

rless tha n 5 years but a tleas t1 year , from historical record s representin g th e tota

l operating lif

e o f th e proces s unit ; (3 ) Measur

e th e flow rat

e of th e wastewate rfo

rth e poin tof

generatio n durin g condition s matar e representativ e of

averag e wastewate r generatio n rates. §63.14 5 Proces s wastewate r provision* — test method s an d procedure s t o determin e compliance

. ~(a ) Thi s paragrap

h applie s t o th e us e of al l performanc

e test s t o demonstrat

e complianc e of

a treatmen

tproces s or waste managemen

tunit . (1 ) Th e tes tshal l b e conducte d whe n th e treatmen

tproces s orwaste managemen

tuni ti s operatin g d

ta representativ e inle twastewate rstrea m flow rate an d VOHA

P concentratio n unde r whic h i twoul d b e mos tdifficul t t o demonstrat

e compliance . — - (2 ) Operations durin g period s o f startup , shutdown , o rmalfunctio n shal l no tconstitut e representative conditions ' fo rth e purpos e of

a tes t (3 ) Al l testin g equipmentshal l b e prepare d an d installe d a s specifie d i n th e appropriat

e tes tmethods . - •

: (4 ) Th e owne roroperatorshal l recor d al l proces s information a s i s necessary t o documentoperatin g condition s durin g th e tes t (b ) Thi s paragrap

h applie s t o th e us e of performanc

e test s t o demonstrat

e complianc e of

a treatmentproces s with th e part s pe rmillio n b y weigh t wastewate rstrea

m concentratio n limit s a tth e outle tof

th e treatmentprocess . (1 ) Th e tota

l VOHA P average concentratio n shal l b e measure d for complianc e wit h th e concentratio n alternative s specifie d i n § 63.138(c)(l)(ii)(C ) an d (d)(l)(i ) o f thi s subpart ; o rth e average concentratio n o f each VOHA

P shal l b e measure d fo

r complianc e wit h th e concentratio n alternative s specifie d i n § 63.138(b)(l)(ii)(A ) of

thi s subpar t (2) A minimum of

thre e representativ e sample s o f

th e wastewate rstrea

m exitin g th e treatmen

tproces s shal l b e collecte d and analyze d usin g th e procedure s i n § 63.144(b)(3 ) o f thi s subpart . (c) Thi s paragrap

h applie s t o th e us e o f performanc

e test s t o demonstrat

e complianc e o f

a noncombustio n treatmen tproces s with th e percen t reductio n limit s fo

rtotal VOHA

P mas s flow rat e o r VOHA

P mas s flo w rote for strippabilit

y group s of

HAP's . '•' - (1 ) Th e percen treductio n o f tota l VOHAPmas s flowrate shal l b e . measured fo

rcomplianc e wit h . § 63.i38(c)(l)(ii)(B ) or (c)(l)(iii)(B ) o f thi s subpart ; o rd

f VOHA P mas s flow rat e fo rstrippabilit

y group s o f

HAP' s fo r complianc e with §63.138(b)(l)(ii)(C) , (b)(l)(iii)(A) . (c)(l)(ii)(D) , o r(c)(l)(tii)( Q of thi s subpar t (2) Th e sam e tes tmetho d shal l b e use d t o analyz e th e wastewate r sample s from bot h th e inle tan d outle tof

th e treatmen tprocess . . -..-•.. (3 ) Th e mas s flo w rat

e of tota l VOHA

P o ro f VOHA P fo r a strippabilit

y group o f HAP' s enterin g th e treatmentprocess . (E h ) and exitin g th e treatmentproces s (E J shal l b e determine d b y computin g th e producto f

th e flo w rat

e o f th e wastewate r strea

m enterin g orexitin g th e treatmen

tprocess , ari

d th e total VOHA P o r strippabilitygrou p VOHA P averag e concentratio n o f

th e enterin g or exitin g wastewate rstreams , respectively ! ',•>" " (1 ) th e flo w rat

e o f th e enterin g an d exitin g wasteWate

r stream s shal l b e detennine d usin g th e inle tan d outle t flow meters , respectively . •..•; • (ii ) Th e total VOHA

P orstrippabilit

y grou p VOHA P average concentration s o f th e enterin g and exitin g wastewate r stream s shal l b e determine d usin g th e metho d specifie d i n § 63.144(b)(3)(iii ) o f thi s subpait

l V (iii ) Three gra

b sample s ofth e -.-

. • enterin g wastewate rstrea m shal l b e take n a tequall y space d tim e interval sP.2 0

Federa l Registe r /

Vol . 58 , N a 3 7 /

Friday , Februar y 26 , 199 3 / Correction s

ove ra 1-hour period . Eac h 1-hour perio d constitute s a mn , ari d th e performance tes tshal l consis to f a minimu m o f

3 runs . (iv ) Thre e gra

b sample s o f

di e exitin g wastewate rstream shal l b e take n a t equall y space d tim e interval s ove ? a S hou r period . Eac

b 1-hour perio d constitute s a run , an d di e perfonnanc e tes tshal l consis tof

a minimu m o f

3 run s conducte d ove rth e sam e 3-hou r perio d a twhic h th e mes s flow rate of tota l VOHA P o r strippabilit

y group VOHA P enterin g th e treatmentproces s i s determined . (v ) The . mas s flow rates o f tota l VOHA P o rstrippabilit

y grou p VOHA

P enterin g an d exitin g th e treatmen t proces s ar

e calculate d a s follows:


### K E b = - nxlO 6 

# (l^c. )

K -(LVaAi ) 

## nxlO 6
where : Eb=Mas s flow rat e o f total VOHA

P or strippabilit

y grou p VOHA

P enterin g th e treatmen

tprocess , kilogram s pe r hour . Ee=Mas s flow rate of

tota l VOHA P or strippabilit

y group VOHA

P exitin g th e treatmentprocess , kilogram s per hour . K=Densit y of th e wastewate r stream , kilogram s pe rcubi c meter . Vbi=Averag

e volumetri c flow rat

e o f wastewate renterin g th e treatmen t proces s durin g esc h ran i , cubi c meter s pe rhour . V^Averag e volumetri c flow rate o f wastewate r exitin g tb e treatmen t proces s durin g eac h ru

n i, cubi c meters ps rhour . CM=Averag

e concentratio n o f

total VOHA P cs- strippabilit

y group VOHA P i n th e wastewate rstrea m enterin g th e treatmentproces s durin g eac h ru

n i , part s pe rmillio n b y weigh tThi s shal l b e th e sum o f th e average VOHA

P concentration s o f al l HAP' s i n th e stream , orof al l HAP' s i n th e targe

tstrippabilit

y grou p thatar

e i n th e stream . Ccj=Averag

e concentratio n of

tota l VOHA P orstrippabilit

y grou p VOHA P i n th e wastewate rstrea m exitin g th e treatmentproces s durin g eac h ru n i , part s pe rmillio n b y weish tThi s sha

U b e th e su

m of th e averag

e VOHA P concentration s o f al l HAP' s I

n th e strea

m o ro f al l HAP' s i n th e targe

tstrippabilit

y grou p tha tar e i n th e stream . n=Number o f

runs . 

## K
(4 ) Tb e treatmen t follows : reductio n acros s the .

shal l b e calculate d a s

R = K10 0
where : R=Contro l efficiency of

th e treatment process , percen t Eb=Mas s flow rat e of tota l VOHA P mstrippabilit

y grou p VOHA

P enterin g th s treatmen

tprocess , kilogram s pe r hour . E„=Mas s flow rate of

tota l VOHA P o r strippabilit

y group VOHA

P exitin g tb e treatmen

tprocess , kilogram s pe r hour . (d ) Thi s paragrap

h applie s t o di e us e ofa performanc

e test to demonstrat

e complianc e o f

a combustio n treatmen

t7 

# E roces s with th e percentreductio n mit e fo rtotal VOHA

P mas s flow rat

e orVOHA P mas s flow rate fo

r strippabilit

y group s o f

HAP's . Tb e percen treductio n o f

total VOHA

P mas s flow rat e shal l b e measured for complianc e with §63.138{c)(lKiiKB ) o r (c)(l)(iii)(B ) of

thi s subpart ; or o f VOHA P mas s flow rat

e for strippabilit

y group s of HAP' s for complianc e with § 63.138|bKlMii)( a foHlHiiiXA), (c)(l)(iiMD) . o r (c)(l)(iiiHC ) o f thi s subpar t (1 ) Th e mas s flow rat

e o f total VOHA

P o ro f VOHA P for a strippabilit

y group o f HAP' s enterin g th e combustio n uni t shal l b e detennine d b y computin g tb e produc to f the averag

e flow rat e ofth e wastewate rstrea

m enterin g th e combustio n uni ta s determine d b y tb © inle tflow mete? , an d tb e tota l VOHA P orgrou p VOHA P average concentratio n o f th e waste stream , a s determine d usin g th e samplin g procedure s i n § 63.144(b)(3 ) o f

thi s subpart

. (2) Eac h 1-hou r perio d constitute s a run , and th e performanc

e tes tshal l consis tof a minimum o f

3 run s conducte d ove ra

tleas ta 3-hou r period . (3 ) I f gra b samplin g technique s ar e used , then thes e gra

b sample s shal l b e take n a ta minimum o f

three equall y space d time interval s durin g th e run . (4 ) Tb e mas s flow rat

e o f tota l VOHA P orstrippabilit

y group VOHA

P int o th e . combustio n uni ti s calculate d a s follows : E b = - 

### nxlO 6 

# (5, w 

# )

where : Eb=Mas s flow sate o f

total VOHA

P o r strippabilit

y grou p VOHA

P int o tb e combustio n uni tkilogram s pe r hour . K=Densit y of th e wast e stream , kilogram s pe r cubi c meter . V<=Averag

e volumetri c flow rat

e o f wast e enterin g th e combustio n uni t durin g eac b ru n i , cubi c meter s pe r hour . Q=Averag e concentratio n o f total VOHA P or strippabilit

y group VOHA P i n th e wast e strea

m enterin g th e combustio n uni tdurin g eac h ?u n i,parts-pe r millio n b y weight . Thi s "shaf

tb a th e sum of

th e average VOHA

P concentration s of al l HAP' s i n th e stream , o rof al l HAP' s i n th e targe

tstrippabilit

y group thatare i n th e stream . n=Numbe r o

f runs . (5 ) Th e mas s flow rate o f tota l VOHA P o rstrippabilit

y grou p VOHA

P exitin g th e combustio n uni texhaus tstack shal l b e determine d BSMIOWB : (i ) Th e tim e perio d for

. th e testshal l no tb e les s than ' 3 hour s durin g whic h a tleas tthre e 1-hou r run s ar e conducte d an d ba th e sam e time perio d a twhic h th e mas s flow rate o f

VOHA P enterin g th e treatmentproces s i s determined . Eacf e ru n shall represen ta time integrate d composit e sampl e correspondin g to tb e period s whe n th e wast e feed i s sampled . (ii ) A ru n shal l consis tof

a 1-hour perio d durin g th e tes tFo reac h run : (A ) Th e volum e exhauste d shal l b e determine d usin g Metho d 2,2A , 2C , p r 2 D from appendi x A of

4 0 CF Rpar t60 , a s appropriate . '.••-• - (B ) Tb e total VOHA

P o rstrippabilit

y group VOHA

P averag e concentratio n i n th e exhaus tdownstrea m o f tb s combustio n uni tshall b s determine d usin g Metho d i s o f

appendi x A o f

4 0 CFR par tSO . Alternatively , an y othe r tes tmetho d validate d accordin g t o th e procedure s i n Metho d 30 1 o f appendi x A o f thi s par t (iii ) Th e mas s o f

total VOHA

P q r strippabilit

y grou p VOHA

P emitte d duririg eac h ru

n shal l b e calculate d a s follows :

Mi = —I 0.041 6 MWj Q

1 0 6j= l

IMjaUMi i lAiP.2 1
1168 6 Federa l Registe r/ Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s where : Mi=Mas s of tota l VOHA P o r strippabilit

y group VOHA

P emitte d durin g run i , kilograms . V=Volume of

air-vapo rmixture exhauste d a

tstandar d conditions , cubi c meters . 6Q=VOHAP concentratio n o f compoun d j measure d i n theexhaust , part s pe rmillio n b y volume . MWj=Molecula

r weigh to

f compoun d j i n exhaus tstream , kilograms pe r kilogram-mole . m=NumDe

ro f HA P compound s i n tota

l o ri n strippabilit

y group . 0.0416=Conversio n factorfo rmolar volume , kilogram-mol e pe rcubi c mete ra t29 3 "Kelvi

n and 76 0 millimeter s mercur

y absolute . . (iv ) Th e tota

l VOHA P orstrippabilit

y group.VOHA

P mas s emissio n rat

e i n th e exhaus tshal l b e calculate d as follows :



## (|M,)/ T

where : E a =Mass flowrat e o

f tota l o r strippabilit

y group VOHA

P emitted , kilogram s pe rhour. . - Mj=Mas s of tota l o rstrippability group VOHA P emitte d durin g ru

n i ,

. kilograms . . T=Tota l time.of-al l runs , hours . n=Numbero

f runs . (6) Th e tota

l VOHA P o rstrippabilit

y grou p VOHA P destructio n efficiency fo r th e combustio n uni tshal l b e calculate d as follows : Eb—E o R = —X10 0 E„ ' where : R= Total orstrippabilit

y group VOHA

P destructio n efficienc y fo

rth e combustio n unit , percent . E b = Mas s flo w rate of

total or strippabilit

y grou p VOHA

P enterin g th e combustio n unit , kilogram s pe r hour . E 0 = Mas s flow rat e of tota l or strippabilit

y group VOHA

P exitin g th e combustio n unit , kilogram s pe r hour . (e) A n owne r o

roperatorshal l tes t equipmentfo

remission s of

50 0 part s pe rmillio n b y volum e or greate r required i n §§63.13 3 through 63:13 7 and 63.13 9 o

f thi s subpar

ti n accordance with th e followin g requirements : (1 ) Monitoring shal l compl y with Metho d 2 1 from Appendi x A o f 4 0 CF R par t60 . (2) Th e detectio n instrumentshal l meetth e performanc

e criteri a o

f Metho d 21 . (3 ) Th e instrumentshal l b e calibrated befor e us e o n each da y o f it s us e b y th e procedure s specifie d i n Metho d 21 . (4 ) Calibration gase s shal l be : (i ) Zer o air(les s tha

n 1 0 part s pe r millio n b y volum e o

f hydrocarbon i n air) ; and (ii ) A mixture o

f methan e and ai ra

t a concentratio n o

f approximately , but less than , 50 0 part

s pe rmillio n b

y volum e methane . (iii ) The instrumentma

y b e calibrate d a ta highe rmethane concentratio n u p t o 2,00 0 part

s pe rmillio n by volum e highe rtha

n th e lea k definitio n concentratio n fo

ra specifi c piec e o

f equipmentfo

rmonitorin g thatpiec e of equipment . Th e instrumentma y no tb e calibrated a

ta methane concentratio n lowe rtha n th e lea k definitio n concentratio n fo

r a specifi c piec e o

f equipment . • :-\ (5) Th e backgroun

d leve l shal l b e determine d as setfort

h ir i Metho d 21 . (6 ) Th e instrumentprob e shal l b e traversed aroun

d al l potential lea

k interface s as clos e as possibl e t o th e interface a s describe d i n Metho d 21 . (7 ) Th e instrumentresponse factor s shal l b e considere d accordin g t o paragraph

s (e)(7)(i ) and (e)(7)(ii ) o

f thi s section . (i ) Th e response factor

s use d shal l b e th e instrumentrespons e factor detennine d fo

rth e predominantHA

P (i.e. , th e HA

P presenta

tth e highes t percentage ) a

t50 0 part s pe rmillio n b y volume . Th e response factor s ma y b e obtained from th e availabl e literature , th e instrumentmanufacturer , o r detennine d fo

rth e specifi c instrument and HAP . (ii ) Chemica

l compositio n of individua l proces s stream s ma y b e determine d b y sampling , engineerin g calculations , orproces s knowledge . A separat e detenninatio n foreac h strea m i s no tnecessary if

al l o rportion s of

th e proces s uni tcan b e show n t o exhibi t simila rcomposition . Th e basi s fo ral l proces s strea

m compositio n determination s shal l be . documente d as required i n § 63.144(b ) of thi s subpart. (8 ) Th e arithmeti c difference betwee n th e maximum concentratio n indicate d b y th e instrumentand th e background leve l i s compared t o 50 0 part s pe r millio n b y volum e fo

rdeterminin g compliance . (f ) A performanc

e tes tt o demonstrat

e complianc e o

f a ven tstrea

m contro l devic e with th e organi c compoun d reduction efficienc y requirement specifie d unde r§ 63.139(b ) o f thi s subpar tshal l us e th e followin g procedures : (1 ) Samplin g site s shal l b e selecte d usin g Metho d 1 orI A from appendi x A of 4 0 CF Rpar t60 , a s appropriate . (2 ) Th e mas s flo w rat

e of organic s enterin g and exitin g th e contro l devic e shal l b e determine d a s follows : (i ) Th e tim e perio d fo

rth e tes tshal l no tb e less tha

n 3 hour s durin g whic h a tleas tthre e run s ar

e conducted . (ii ) A ru n shal l consis to

f a 1-hour perio d durin g th e test . For eac h run : (A ) Th e volum e exhauste d shal l b e determine d usin g Metho d 2 , 2A , 2C , or 2 D from appendi x A o

f 4 0 CF Rpar t60 , a s appropriate ; (B ) Th e organi c concentratio n i n th e ven tstrea m enterin g an d exitin g th e contro l devic e shal l b e determine d usin g Metho d 1 8 from appendi x A o f 4 0 CF Rpar t60 . Alternatively , any othe r tes tmetho d validate d accordin g t o th e procedure s i n Metho d 30 1 o f appendi x A o f thi s par tma y b e used . (iii ) Th e mas s flow rat

e o f organic s enterin g an d exitin g th e contro l devic e durin g each ru

n shal l b e calculate d a s follows :

### Federa l Registe r / Vol

. 58 , No
. 3 7 /Friday , Februar y 26 , 199 3 /Correction s 1168 7

0.041 6 - K3 

### = —- U Va

j ICai^MW , 10 6 

### x mlj=1



### - \ l = 1 / J



### 0.041 6 f m

### . „ E b 

### = [ L_y hi

### (^CwjMWi ) J 10 6 

### x m
where : E.=Mas s flo w rate o f

organic s exitin g th e control ; device , kilogram s pe r hour

. Eb=Mas s flow rat e o f

organic s enterin g th e contro l device , kilogram s pe r hour

. V^=Averag e volumetri c flow rat e o f ven t strea mexitin g th e contro l devic e durin g ru n j a t standard s conditions , cubi c meter s pe r

hour

. Vbj =Averag e volumetri c flow rat e of ven t strea menterin g th e contro l devic e durin g ru n j at standard s conditions , cubi c meter s pe r

hour

. m=Numbe r

o f runs . Cuij=Organic concentratib n o f .compoun di measure di n th e ven t strea mexitin g th e contro l devic e durin g ru n j a s determine db y Metho d18

. part s pe r millio n b y vbluiri e O

n adr y basis

. Chij=Organic concentratio n o f compoun di measure di n th e ven t strea menterin g th e contro l devic e durin g ru n j a s determine db y Metho d18 , part s pe r millio n b y volum e o n adr y basis

. MVVi=Molecula

r weigh t o f organi c compoun di i n th e ven t stream , kilogram s pe r

kilogram-mole

. n=Numbe r

o f organi c compound s i n th e ven t stream
. 0.0416=Conversio n facto r fo r mola r volume , kilograms-mol e pe r cubi c meter'a t

29 3 "Kelvi n an d760 millimeter s mercur y absolute

. (4 ) Th e organi c reductio n efficienc y fo r th e contro l devic e shal l b e calculate d e s follows : E„-E
. R = X10 0 E b where : R=Tota l organi c reductio n efficienc y for th e contro l device , percen t Eb=Mas s flo w rat e of

organic s enterin g th e contro l device , kilogram s pe r hour

. E a=Mas s flow rate o f

organic s exitin g th e contro l device , kilogram s pe r hour

. (g) A perfonnanc e tes t

t o demonstrat e complianc e wit h th e mas s remova l provisio n for

ne w SOCMI proces s unit s i n §63.138(b)(l)(iii)(C ) o f thi s subpar t shal l consis t

of adeterminatio n o f

mas s removal require dt o b e achieved , an da detenninatio n o f

mas s remova l actuall y achieved

. Actua l mas s remova l an d complianc e shal l b e determine db y th e procedur e i n paragrap h (i ) o f thi s section

. Th e require dmas s remova l for eac h Grou p 1 wastewate r strea mprio r

t o combinatio n o f

th e stream s fo

r treatmen t shal l b e detennine dusin g th e followin g equation : RM R K I O 6 n 

## V 

# E 3 = 1 0.9 9

where : RMR=Require dmas s remova l o f VOHA P fromTabl e 8 HAP compound s i n aGrou p 1 wastewate r

stream , i n kilogram s pe r year . KcDensit y o

f th e Grou p 1 wastewate r stream , kilogram s pe r

cubi c meter
. V=Annua l wastewate r

quantit y ofth e Grou p 1 wastewate r

stream , cubi c meter s pe r

year . n=Numbe r

o f Tabl e 8 HAP compound s i n stream
. £j=Averag e VOHA

P concentratio n o f eac b Tabl e 8 organi c HAP compoun d"j " i n th e Grou p 1 wastewate r

strea ma t th e poin t o f generation , part s pe r

millio n b y weigh t 0.99sRequire dremova l fractio n o f VOHAP fromTabl e 8 Compounds

. (1 ) Th e annua l wastewate r quantit y fb r eac h Grou p 1 wastewate r strea mt o b e combine dfo

r treatmen t

(V) , shal l b e determine dusin g th e procedure s specifie di n paragrap h (a ) o f thi s section

. (2 ) Th e VOHAP averag e concentratio n of eac h Tabl e 8 HA P compoun d(Cj ) i n eac h Grou p 1 wastewate r strea mt o b e combine dfo

r treatmen t

shal l b e determine dusin g th e procedure s specifie di n § 63.144(b)(3 ) o f thi s subpart

. (3 ) Th e tota l require dmas s remova l i s calculate db y addin g togethe r th e requiredmas s remova l for each " individua l Grou p 1 strea mt o b e combine dfo

r treatmen t (h ) A performanc e tes t

t o demonstrat e complianc e wit h th e mas s remova l provision s for

ne w an dexistin g SOCM I proces s unit s i n § 63.138(c)(l)(iii)(D ) o f thi s subpar t

shal l consis t

o f a determinatio n o f

mas s remova l require d t o b e achieved , an dadeterminatio n O f mas s removal actuall y achieved

. Actua l mas s removal an dcomplianc e shal l b e determine db y th e procedur e i n paragrap h (i ) o f

thi s section

. Th e require dmas s remova l for eac h Grou p 1 wastewate r

strea mprio r

t o combinatio n o f th e stream s for

treatmen t

shal l b e determine dusin g th e followin g equation :P.2 3


### 1168 8 Federa l Registe r / Vol

. 58 , No
. 3 7 /

Friday , Februar

y 26 , 199 3 /

Correction s

RMR 

## -T^ v 

## ^ 1 

## h ••• ! 0 0
where : * RMR=Require

d mas s remova

l o f total VOHA P average concentratio n i n th e Grou p 1 wastewate rstream , prio rt o combinatio n wit h othe r Grou p 1 wastewate rstreams , kilogram s pe ryear . K=Densit y of th e Grou p 1 wastewate r stream , kilogram s pe rcubi c meter . V=Average wastewate rflo w rat e fo rth e Grou p 1 wastewate rstream , cubi c meters pe ryear . n=Numbe ro f

organi c HA

P compound s i n stream . CJ=Averag

e VOHA P concentratio n of compoun d "j " i n th e Grou p 1 wastewate rstrea

m a tth e poin to

f generation , part

s pe rmillio n b

y weight . F=Require

d percen tremoval, of

each compoun d "j " (targe

tremova l '* » : efficiency fro

m Tabl e 9) . (1 ) Th e average wastewate rflow rat e fo reac h Grou

p 1 wastewate rstrea

m t o b e combine d fo

rtreatmen

t(V) , shal l b e determine d usin g th e procedure s specifie d i n § 63.144(e ) o f thi s subpart

. (2) Th e average of

each VOHA

P concentratio n (Cj ) i n each Grou p 1 wastewate rstrea

m t o b e combine d fo

r treatmen tshal l b e determine d usin g th e procedure s specifie d i n § 63.144(b)(3 ) of thi s subpart

. (3 ) Th e tota

l required mas s removal i s calculate d by addin g togethe rth e required mas s remova

l fo reach . • : . . individua l Grou

p 1 wastewate rstrea

m t o b e combine d fo

rtreatment . (i ) Fora performance tes tt o demonstrat

e complianc e o f

a treatmen

t proces s with th e mas s removal . standards , th e actual mas s removal of total VOHA

P (fo r complianc e with , §63.138(c)(l)(iii)(D ) of

thi s subpart

) o r o f VOHA P from tabl e 8 compound s (fo r complianc o wit h §63.138(b)(l)(iii)(C ) o f thi s subpart

] i n th e wastewate rstrea

m shal l b e determine d b y th e followin g procedure : (1 ) Th e actua

l mas s remova

l of a treatmen tprocess , o rserie s o f

treatmen t 

# E rocesse s othe rthan a properly operated iologica l treatmentuni tshal l b e determine d usin g th e followin g equation : MR^b-E J where : ' . MR=Actua

l mas s remova

l b y th e treatmentproces s orserie s of treatmen tprocesse s of

tota l VOHA P forTabl e 9 HA

P compound s o

r VOHA

P from Table 8 HA

P compounds , kilograms pe rhour . Eb=Mas s flow rat e of tota l VOHA P fo r Tabl e 9 HA

P compound s orVOHA

P from Table 8 HA

P compound s enterin g th e treatmen

tproces s or serie s o f treatmen tprocesses , kilograms perhour . E n =Mass flow rat

e of tota l VOHA P fo r Table 9 HA

P compound s o

rVOHA P from Table 8 HA

P compound s exitin g th e treatmen

tproces s o

r serie s o f treatmen tprocesses , kilograms pe rhour . (i ) Th e mas s flow rat

e o f tota l VOHA P fo rTabl e 9 HA

P compound s o

rVOHA P from Table 8 HA

P compound s enterin g th e treatmen

tproces s (Eb

) shal l b e determine d usin g th e procedure s specifie d i n paragrap

h (c)(3 ) of thi s section . (ii ) Th e mas s flow rat

e o f tota l VOHA P fo rTable 9 HA

P compound s o

r VOHA P from Table 8 HA

P compound s exitin g th e treatmen

tproces s (E

J shal l b e determine d usin g th e procedure s specifie d i n paragrap

h (c)(3 ) of thi s section. ' (2 ) Th e actua

l mas s removal (MR

) o f a treatmen

tproces s whic h i s a properly operated biological treatmen tuni ti s ' equa l t o th e mas s removed du e t o biologica l destruction . Th e mas s remova l moul d b e determine d usin g th e followin g equation : MR=(E b -E«)*F bi o where : MR=Actua

l mas s removal b y th e treatmen tproces s o

r serie s o f treatmen tprocesse s o

f tota l VOHA P fo rTabl e 9 HA

P compound s o

r VOHA P from Tabl e 8 HA

P compounds , kilograms perhour . Eb=Mas s flo w rat e of tota l VOHA P fo r Table 9 HA

P coiripound s o

rVOHA P from Table 8 HA

P compound s enterin g th e treatmen

tproces s o

r serie s o f treatmen tprocesses , kilograms perhour . . E a =Mass flow rat

e o f tota l VOHA P fo r Tabl e 9 HA

P compound s o

rVOHA P fro m Table 8 HA

P compound s exitin g th e treatmen

tproces s or serie s o f treatmen tprocesses , kilograms perhour . F bi „=The fraction o

f VOHA P from Table 8 HA P compounds , o

r tota l VOHA P fo rTabl e 9 HA

P compounds, , biodegraded in a properly operated biological treatmen

tunit . Thi s fraction shal l b e determine d usin g WATER7 . Th e sit e specifi c biorat

e constants use d a s input s t o WATER 7 shal l b e deterrriine

d usin g Method 30 4 o

f appendi x A of

thi s part . ' (3 ) Compliance wit

h th e riiass removal provision s i n §63.138(b)(l)(iii)(C ) o r §63.138(c)(l)(iii)(D ) of thi s subpar

ti s achieve d whe n th e actua l mas s remova

l o f tb e treatmentproces s (MR ) i s demonstrate d t o mee to

r excee d th e tota

l required mas s removal (RMR) , determine d usin g th e procedure s specifie d i n paragraphs (g ) or (h ) of thi s section , respectively. §63.15 0 . Emlaolon

o averagin

g provlolons . (a ) Thi s sectio n applie s t o owner s o r operators wh o see k t o compl y wit h emissio n limit s b y usin g emission s averaging accordin g t o § 62.112(c)(2 ) o f thi s subpar

trathe rtha n followin g th e provision s o

f § § 63.11 3 through 63.14 9 o f thi s subpar

tfo ral l emissio n points . (b) Unles s a

n operatin g permit , applicatio n ha s bee n submitted , th e owne r oroperato r shal l develop , and submi tfo rapproval , a

n Implementatio n Pla n containin g all b

f th e informatio n required i n § 63.151(d ) of thi s subpar

t fo ral l point s t o b e include d i n a n emissio n average . Th e Implementatio n Plan o roperatin g permi tapplicatio n shal l identif

y al l emissio n point s t o b e include d i n th e emission s averaging . Thi s mus tinclud e any Grou p 1 ' emissio n point s t o whic h th e reference contro l technolog y (define d i n § 63.11 1 of thi s subpart

) i s no tapplie d and all othe remissio n point s bein g controlle d a s par tofth e average . - (c ) Th e followin g emissio n point s ca n b e credite d i n a

n emission s average to ' offse tus e of control s les s stringenttha n th e reference technolog y o n Grou p 1 emissio n points , if

sufficien t informatio n i s availabl e t o determin e : th e appropriat

e valu e o f credit s fo

rth e point : (1 ) A Grou

p 2 emissio n point-to whic h a ne w contro l ha s bee n applie d afte rNovembe r15,1990 . (2 ) A Grou

p 1 emissio n poin ttha

ti s * controlle d by a technolog y tha tth e Directo ro

f th e EP A Office of

Ai r Qualit

y Plannin g and Standard s or th e operatin g permitauthorit

y agree s ha s a highe r nominal contro l efficienc y tha n th e . reference technolog y i f

th e emissio n poin tWa s no tcontrolle d t o thi s leve l o n orbefor e Novembe r15,1990. ' •

; Information o n th e nomina l contro l efficiencie s forsuc h technologie s mus t b e submitte d an d approve d a s provide d i n paragraph (h) of

thi s section . - ; • (3 ) Emissio n point s from whic h : emission s are reduced h y pollutio n , . preventio n project

s initiated : afte

r1987 . ForGroup , 1 emissio n points , i n ordert b b e credited , th e pollutio n preventio n 

# 1 >roject s mus tresulti n emissio n level s , owe rthan wha twoul d hav e occurre d if th e reference technolog y ha d bee n applie d t o th e emissio n point s a tthei r emissio n level s prio rt o pollutio nprevention . Pollutio n preventio n i s

define d i n paragrap

h (i ) of thi s section . (4 ) An y Grou

p 2 emissio n poin tt o whic h control s wer e applie d a s par tof th e early reductio n progra m establishe d b y th e EP A unde rsectio n 112(i)(5 ) o f th e Clea n Ai rActa s amende d i n 199 0 (5 6 F R27338) . (5 ) A Grou

p 1 emissio n poin t controlle d b y a technolog y EP A agree s ha s a highe rnominal contro l efficienc y tha n th e reference technolog y if thi s contro l wa s applie d a s par tof th e earl y reduction progra

m establishe d by th e EP A unde rsectio n 112(i)(5 ) o f th e Clea n Ai rActa s amende d i n 199 0 (5 6 F R 27338) . (6 ) Any Grou

p 2 emission s poin tt

o whic h control s wer e applie d a s par tof a commitmen tunde rth e Agency' s 33/5 0 progra m describe d i n EP

A Publicatio n NumberEPA-741-K-92-OQ1 . (7 ) Any Grou

p 1 emission s poin t controlle d b y a technolog y EPA'agrees has a highe rnominal contro l efficienc y tha n th e reference contro l technolog y if th e contro l wa s applie d a s par to f a commitmen tunde rth e Agency' s 33/5 0 progra m describe d i n EP

A Publicatio n NumberBPA-741-K-92-i0pi . (d)Th e followin g emissio n point s canno tb e iise d t

o generat e credit s i n emissio n averaging : . > (1 ) Emissio n point s already controlle d o n orbefor

e Novembe r15,1990 , excep t thos e tha twere controlle d a s par

tofth e Sectio n 112(i)(5 ) early reductio n program, th e 33/5 0 prograrii, ora pollutio n preventio n progra m a S describe d i n paragrap

h (c ) o f thi s section . • y (2 ) Emissio n point s achievin g contro l level s highe rthan ; th e nomina l efficiency o f

a reference technolog y whe n usin g a reference contro l technology , unles s th e requirements of § 63.150(h)(6 ) o f

thi s subpar

thav e bee n satisfie d fo

rproces s vents , o

rth e requirerrierit

s i n §63.S50(g)(3)(ii)(C ) or (g)(3)(iii)(D ) hav e bee n satisfie d for storage vessels . For example , i f i s no t allowabl e t o clai m tha

ta n internal Abatin g roo f meetin g th e specifications " of § 63.119(b ) o f

thi s Subpar

tapplie d t

o a storage vesse l i s achievin g greatertha n 9 5 percentcontrol . '. ' . ,

. (3 ) Productio n cutback s an d shutdowns . Th e .emissio n credit s ar e calculate d a

tth e actual monthl y productio n leve l an d d o no tinclud e an y proces s unit s thatar

e shu tdown , (e) Foral l point s include d > n a n emissio n average , th e owne roroperato r shall:-' - :'•:-• = ••• : ••:•>-••• • > "' ; : (1 ) Calculat e and recor

d monthl y debits fo rall Grou p 1 emissio n point s tha tar e controlle d t o a leve l les s stringenttha

n th e reference technolog y leve l fo rthos e emissio n points . Equations i n paragrap

h (f ) of thi s sectio n shal l b e use d t o calculate debits . (2) Calculat

e and recor

d monthl y credits fb ral l Grou p 1 o rGrou p 2 emissio n point s tha

tar e overcontrolle d t o compensate fo

r th e debits usin g equation s i n paragrap

h (g ) of thi s section . Emissio n point s tha tmeetth e criteri a o f paragrap h (c) of thi s sectio n ma y b e include d i n th e credi t calculation , whereas thos e describe d i n paragrap h (d ) o f thi s sectio n shal l notb e included . ..'.'; . (3 ) Demonstrat

e tha tannua l credit s calculate d accordin g t

o paragrap

h (g ) o f thi s sectior

i ar e greate rthan orequa

l t o debits calculate d fo

rth e sam e annua

l complianc e perio d accordin g t o paragrap h (f ) o f thi s section . I

f th e credit s ar e no tgreaterthan o r equa l t o th e debits fo

rth e same annua) compliarice period , and th e owne ror operato rhas metth e requirement s i h paragraph

s (e)(3)(i ) throug

h (e)(3)(iv ) of thi s section , th e owne ro

roperatorma

y us e banked credits ari

d credits from th e relevan tcomplianc e perio d t o offsetth e debits . I f banke d credits ar

e availabl e and necessary , complianc e shal l b e judged based o n th e sum of banke d credits an d credits from th e relevant complianc e period , averaged wit h debits from th e relevantcomplianc e period . (i ) I f th e credits 'calculated accordin g t o paragrap

h (g ) of thi s sectio n ar

e greate rtha n th e debits calculate d fo rth e sam e annua

l complianc e perio d accordin g t o paragrap

h (f ) o f thi s section , th e owne ror operatorma y ban k th e extr a credits fo

rus e i n futur

e compliarice periods . (A ) I n Orde

r t o ban k credits forus e i n futur e complianc e periods , th e owne ror operato r mus trepor

tth e dat a use d f o calculat e tha

tth e extr a credits were generated an d certif

y th e accurac

y o f tha tdat a i n th e Periodi c Report

s a s specifie d i n § 63.152(c ) of thi s Subpart

. Thes e record s mus tb e readily accessibl e for5 year

s afte rth e perio d ir

i Whic h th e credi ti s availabl e fo

rus e a s specifie d ir

i paragrap h (e)(3)(iy ) o

f thi s section., . (B ) Th e owne ro r operato rma y choos e t o includ e mor

e than, th e required numberof

credi tgenerating emissio n point s i n a

n averag e i n order t o increas e th e likelihoo d of

creating bankabl e credits . However , thes e additional point s ar e notrequired t o creat

e .. . bankabl e credits . (ii ) Banked credit s can onl y b e use d t c compl y with th e annua l requirement specifie d i n paragrap

h (e)(3 ) of thi s section . Banked credit s canno tb e use d fo rth e quarterly requirementspecifie d i n paragrap

h (e)(4 ) of thi s section. (iii ) I n th e Implementatio n Plan fo r emission s averagin g a s specifie d i n § 63.151(c ) and (d ) o f

tbi s subpar

torth e operatin g permi tapplicatio n a s specifie d i n § 63.152(e ) of thi s subpart, th e credi tgeneratin g emissio n point s mus tb e capabl e o f

generatin g sufficien t credits t o offsetth e debit s fro m th e debit generatin g emissio n point s unde r representativ e operatin g conditions . Th e owne ro r operato rshal l no tdevelo p a n Implementatio n Plan oroperatin g permitapplicatio n fo

remission s averagin g tha

trelie s o n banke d credits t o ensur e tha

tcredit s wil l excee d debits . I f suc h ia n averagin g pla

n i s submitted , i twil l no tb e approved . . , (iv ) Th e length o f

tim e tha tbanke d credit s shal l b e availabl e fo rus e afte r th e yea ri n whic h th e extr a credi twa s generate d i s (

a rang e of 2 t o 5 year s i s bein g proposed ; a singl e numbe rwil l b e selecte d a tpromulgation) . I

f a banke d credi ti s ho tuse d withi n ( 2 t b 5 ) years ofth e yea ri n whic h i

f wa s generated , i ti s n o longe ravailabl e fo ruse . (4 ) Demonstrate tha

tdebit s calculate d fo ra quarterl

y (3-month ) perio d accordin g t o paragraph (f ) o f thi s sectio n ar e no tmor e than ( a range of 1.2 5 t o 1.3 5 i s bein g proposed ; a singl e numbe r willb e selecte d a

tpromulgation ) times th e credit s fo

rth e sam e perio d calculate d accordin g t o paragrap h (g ) of thi s section . Complianc e fo rth e quarte

r shal l b e determine d base d o n th e ratio o f credits an d debit s from tha tquarter, ivith (2 5 t o 35 ) percen tmor e debit s tha

n credit s allowe d o n a quarterly basis . (5 ) Calculatio n o f

monthl y credit s and debit s shal l no tinclud e period s of startup , shutdown , an d malfunctio n a s describe d i n th e source' s startup , shutdown , an d malfunctio n pla n required b y § 63.6(e)(3 ) o f subpar tA of thi s part. 16 ' . (6 ) The.quarterl y an d annual credit s an d debit s shal l b e recorde d an d reported i n th e Periodi c Report s a s specifie d i n § 63.152(c ) o f thi s subpart . Th e Periodi c Report

s shal l includ e a certificatio n o f

complianc e wit h th e emission s averagin g provisions . (f ) Debit s shal l b a calculate d a s follows: (1 ) Th e overal l equatio n for : , calculatin g source-wid e debits is :

"Th e EP A Kil l propos e subpar

tA i n th e future.

I —" — -P.2 5


### 1169 0 Federa l Registe r / Vol . 58 , No . 3 7 /

Friday , Februar

y 26 , 199 3 /

Correction s

Debit s = I (EPViAc- , UAI.

- (0:0 2 )EPV 1 U )+.!.(ES.ACI IMI . - (0.05)ES iu )

+ I-(CTRiACTUAL-(0.02)ETR lu ) + 1 (E\VW IAC TVAI.-EWW 1 C ) I=I

. • ' I= I

where ; Debit s an d al l terms o f

th e equatio n ar

e i n unit s o f

megagrams pe rmonth , and EPViAcruAL=Emission

8 from eac h Grou

p 1 proces s ven t(i ) tha

ti s no t controlle d t o th e leve l o f

th e reference technology . Thi s i s calculate d accordin g t o paragraph , (f)(2) of thi s section. . - : (0.02 ) EPVu,=Emission

s from each . Grou p 1 ven t(i ) i f

th e reference contro l technolog y ha d been , applie d t o th e uncontrolle d emissions , calculate d accordin g t o paragrap h (f)(2) o f thi s section . ESiAcruAL=Emission

s from eac h Grou

p ' 1 storage vesse l (i ) thati s no t controlle d t o th e leve l o f

th e reference technology . Thi s i s calculate d accordin g tb paragrap h (f)(3) o f thi s section . (0.05 ) EStu=Emission

s from eac h Grou

p 1 storage vesse l (i ) i f

th e reference contro l technolog y ha d bee n 

### applie dto tb e uncontrolle d emissions , calculate d accordin g t o paragrap h (f)(3 ) o f thi s section . ETRiAcruAL=Emission

s fro m each Grou

p 1 transferrack (i ) tha

ti s no t controlle d t o th e leve l of

th e reference technology . Thi s i s calculate d accordin g t o paragrap h (f)(4) o f thi s section . (0.02 ) ETRja=Emission

s from each : " Grou p 1 transfe

rrack (i ) i f

th e ; . reference control technolog y had . bee n applie d t o th e uncontrolle d emissions , calculate d accordin g t o paragrap h (f)(4) of thi s section . EWW(AcruAi.=Emission

s from each Grou p 1 wastewate rstrea

m (i ) that i s no tcontrolle d t o th e leve l o f th e reference technology . Thi s i s calculate d accordin g t o paragrap h (f)(5 ) of thi s sectiori . EWWic~Emission

s from each Grou

p 1 wastewate rstrea

m (i ) i f th e reference control technolog y ha d bee n applie d t o th e uncontrolle d emissions . Thi s i s calculate d accordin g t o paragraph (f)(5 ) o f thi s section . n=Th e numbe ro f

emissio n point s bein g include d i n th e emission s average . Th e valu e of

n i s no tnecessaril y th e sam e for proces s vents , storage vessels , transfer racks , an d wastewater . (2 ) Emission s from proces s vent s shal l b e calculate d a s follows : (i ) Forpurpose s o f

determinin g . proces s ven tstrea

m flow rate , organi c HA P concentrations , an d temperature , th e samplin g sit e shal l b e afte rth e final productrecovery device , i f an y recover

y device s ar

e present , before an y combustio n device , an d before discharg e t o th e atmosphere . Metho d 1 o r1 A shal l b e use d fo

rselectio n of

th e samplin g site . (ii ) Th e followin g equatio n shal l b e use d for eac h proces s ven t(i ) t o calculate EPVh, :



### EPV 1 U 

### = - "(7.31xlO-'')Qh(LC J 

### M J 

### ' )

v J= i ; 

### T • + 27 3

where : EPVia=Uncontrolied proces s ven t emissio n rate from proces s ven t(i j i n megagrams pe rmonth . Q=Ven tstrea m flow rat

e (dr y standar d cubi c meter s pe rminute ) measure d usin g Metho d 2,2A , 2C , or2 D o f par t60 , appendi x A , a s appropriate . h=Monthl y hour s o f

operatio n durin g whic h positiv e flo w i s presen ti n th e ven t Cj=Concentration (part

s pe rmillio n b y volume , dr

y basis ) o f

organi c HA

P compoun d j a s measured b y Metho d

18 . Mj=Molecula

r weigh to f

organi c HA

P compoun d j (gram/gram-mole) . T=Ven tstrea m discharge temperature , in°C . .. . n=Number o f

organi c HA

P compounds ; (A ) TTi e value s of

OjQ,Mj , and f

^ ' shal l b e determine d during ' a n initia l performance tes tconducte d unde r representative operating conditions . Monthl y testin g i s no trequired . (B ) I f there i s a chang e i n capacity utilizatio n othe rthan a chang e i n . monthl y operatin g hours ; o ri f an y othe r chang e i s mad e t o th e proces s o r productrecovery equipmen to r operatio n suc h tha tth e previousl y measure d value s o f

Q , Q , Mj , o rTar e . n o longe rrepresentative , a ne w perfonnanc e tes tshal l b e coridu c (iii ) th e following procedure s an d equation s shal l b e use d t o calculat e EPVIACTUAL :P.2 6

(A ) I f th e ven ti s no tcontrolle d b y a contro l devic e orpollutio n preventio n measure EPVtAcruAL=EPV to , wher e EPVh , i s calculate d accordin g t o th e procedure s i n paragraph s (f)(2)(i) an d (f)(2)(ii ) o f thi s section , (B ) I f th e venti s controlle d usin g a contro l devic e o r a pollutio n preventio n measure achievin g les s than th e 98 - percen treductio n leve l associate d wit h th e reference contro l technology ,



## EPViAcruAL=EPV iu 

## x

U ) Percentreductio n shal l b e initiall y measured accordin g t o th e procedure s i n §63.11 6 o f

thi s subpar

ti f a combustio n devic e i s used . I f a non combustio n contro l devic e i s used , percentreductio n shal l b a demonstrate d by a n initia l performance tes ta tth e inle tand outle tofth e contro l devic e or. i f testin g i s no tfeasible , b y a control desig n evaluatio n ari

d documente d engineerin g calculations . [2) Forproces s vents , product recover y device s shal l no tb e considere d contro l device s an d canno tb e assigne d a percentreductio n i n calculatin g EPViAcruAL

. Th e samplin g sit e fo

r measuremento f

uncontrolle d emission s i s afte rth e final productrecover y device . However , a s provide d i n § 63.113(a)(3 ) o f

thi s subpart, a Grou

p 1 proces s ven tma

y ad d sufficien tproduc

t 

### ( * . 

## Percen t reduction 100% )

recovery t

o rais e th e TR

E inde x valu e abov e 1.0 , thereb y becomin g a Grou p 2 proces s ven t (3 ) Procedures fo

rcalculatin g th e percen treductio n o

f pollutio n preventio n measure s ar

e specifie d i n paragrap h (i ) o f thi s section . (3 ) Emission s fro

m storage vessel s shal l b e calculate d a s follows : (i ) Th e followin g equation shall b e use d fo reach storage vesse l (i ) t

o calculate ESh, :

C-bi U L B 

## + L

w 1 2 ES lu =Uncontrolle d emission s from a

fixed roof vesse l havin g identica l dimension s an d vesse l colo ra s vesse l i , i n megagrams pe rmonth . Ln=Breathing los s emission s i n megagrams pe ryea rcalculate d accordin g t o paragrap

h (f)(3)(i)(A ) of thi s section . Lw=Workln

g los s emission s i n megagrams pe ryea rcalculate d accordin g t o paragrap

h (f)(3)(i)(B ) of thi s section . (A ) Breathin g los s emission s shal l b e calculate d usin g th e followin g equation :

where :

L B 1.0 2 x 10 _!> M ,

where : Lti=Breathin

g los s emission s (megagram

s pe ryear) . M v =Molecula r weigh tof

vapo r i n storage vesse l (pound/poun d mole) . P A =Average atmospneri c pressure (pound s pe rsquar

e inc h absolute) . P=Tru e vapo rpressur e o f

th e HA P a t liqui d storage temperatur e (pound s pe rsquare inc h absolute) . Se e Table 2 0 o f thi s subpart. D=Tan k diamete r (feet) . H=Average vapo rspac e heigh t(feet) . Us e vessel-specifi c value s ora n assume d valu e o f

one-hal f th e heigh t AT=Averag

e ambien tdiurnal temperature chang e (°F) . A typica l valu e of 2 0 ° F ma y b e used . Fp=Pain tfacto r(dimensionless ) from Tabl e 21 . (^Adjustmen tfacto r fo

r smal l diamete r tanks 1 (dimensionless) ; us e C= l for diamete r 23 0 feet ; us e C=0.0771D-0.0013D?-0.133 4 fo r diamete r<3 0 feet . - P 

# )° - 6 8 D 1 7 3 H 0.51 A T 0.50 F p C K c

Kc=Produc

tfactor(dimensionless) . Us e 1. 0 fo r volatil e organi c HAP's . (B) Workin

g losse s shal l b e calculate d usin g th e followin g equation : L w =1.089xl0- 8 M V (P ) (V ) (N ) (KN ) (KC ) where : V=Tan k capacit y (gallon) . N=Numbero

f turnover s pe r year . KN=Turnove

r factor(dimensionless) . 180+ N K N = fo

r turnovers >3 6 6 N KM= 1 fo rturnovers £36 . ' M „ P , and K

c a s define d i n paragrap

h (A ) above . (ii ) Th e followin g equation s shal l b e use d fo reach fixed roof

storag e vesse l (i ) t o calculate i n ESJACTUAL . i n ...., , megagram

s permonth : (A ) I f th e vesse l i s no tcontrolle d wit h a n intema i floating roof, a

n externa l floating roof, a close d ven tsysto m an d contro l device , o r anothe rcontro l technique , ESiAcruAL=ES fa , wher e ESt

o i s calculate d accordin g t o th e procedure s i n paragrap

h (f)(3)(i ) of

thi s section. (B ) I f th e vesse l i s controlle d usin g a contro l devic e o rpollutio n preventio n measure achievin g les s than th e 9 5 percentreductio n leve l associate d wit h th e reference contro l technology ,
ESiAcnj ,

AO-ES* ) 1-Percen treductio n 10 0 (C ) I f th e vesse l i s controlle d wit h a n intema i orexternal floatin g roof tha t dos s ne tmee tth e specification s o f § 83. 1 S 9 (b) , (c) , o r (d ) o f thi s subpart , ESIACTOA L shall ba calculate d a s specifie d i n paragraph (fK3Kiii ) or (f)(3)(iv) of

thi s section. (iii ) Tii e foliowin g equatio n shal l b e use d fo reac h internal floating roof vesse l (i ) tha tdoe s no tmee tth e



### B BP.2 7

1169 2 Federa l Registe r/ Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s specification s of

§ 63.119(b ) o

r(d) of thi s Subpar

tt o calculate ESIACTTJA L i n megagram

s pe rmonth : ESiACTUAL LW+LR+LP+L D 1 2
where : Lw=Withdrawa

l los s emission s i n megagram s pe ryear calculate d accordin g t o paragrap h (f)(3)(iii)(A ) of

thi s section . L R =Ri m seal los s emission s i n megagram s pe ryearcalculate d accordin g t o paragrap h (f)(3)(iii)(B ) o f

thi s section. L,F=Fittin g los s emission s i n megagram s pe ryea rcalculate d accordin g t o paragrap h (f)(3)(iii)(C ) of

thi s section. Lo=Dec k sea m los s emission s i n megagram s pe ryearcalculate d accordin g t o paragrap h (f)(3)(iii)(D ) o f

thi s section . (A ) Withdrawa

l los s emission s shal l b e calculate d usin g th e followin g equation :

L\ v = - 

### 1.01 8 xlO" 5 

### QCW L 

## D where : Q=Throughpu

t(gallo n pe ryear) ; (gallon/turnover) * (turnover s pe ryear) . C=Shel l clingag e factor(barrel/1,00 0 feet 2 ) , se e Tabl e 22 of

thi s Subpart

. W L=Averag e liqui d density (pound/gallon) . D=Tan k diamete r(feet) . N<~Numbe

r o f column s (dimensionless) , se e Table 2 3 o f thi s subpart

. F c=Effective colum n diamete r(feet ) (colum n perimete r(feet ) 3.1416] , se e Table 2 4 of thi s subpart. (B ) Ri m seal los s emission s shal l b e calculate d usin g th e followin g equation :

K S V" P xDMvK . L R= - 2204. 6

where : Mv =Molecular weigh to

f vapo r i n storag e vesse l (pound/poun d mole) . P A =Average atmospheri c pressur e (pound s pe rsquar

e inc h absolute) . P=Tru e vapo rpressure a

tliqui d storage temperatur

e (pound s persquar

e inc h absolute) . D=Tan k diamete r(feet) . Kc=Produc

tfactor(dimensionless) ; us e 1. 0 fo rorgani c HAP's . K,=Sea l factor . [pound-mole/(fee t(mile s pe rhour) " year)] , se e Table 2 5 of thi s subpart. V=Averag e win d spee d a

tth e sourc e (mile s perhour) . A valu e o f 1 0 mile s pe rhourma y b e assume d i

f source-specifi c dat

a ar e no t available . n=Seal related win d spee d exponen t (dimensionless) , se e Table 25 o f thi s subpart . P*=Vapor pressur

e functio n (dimensionless) , (C ) Fittin g los s emission s shal l b e calculate d usin g th e followin g equation :



### P = _P

_ P A 

# M'-^ H Fittin g Los s (Mg/yr ) = • FfP-xMvK c 

### 220 5 wher e F r Th e tota

l deck fitting los s factor (poun d mol e pe ryear) , and

n F f " . £ ("F i K F i ) " !< N F ! K Fj. ) * ( N F 2 Kp 2 ) * • < % n * F n »
where : N n =Numbe r of

fittings of

a particulartyp e (dimensionless) . N H i s detennine d fo rth e specifi c tan

k o restimate d fro

m Table s 2 3 an d 2 6 of

thi s subpart. Kn=Dec k fitting los s factorfo

ra particulartyp e fitting (poun d mol e pe ryear) . K n i s determine d fo

reac h fittin g typ e fro m Tabl e 2 6 of

thi s subpart. n=Numberof

differenttype s of

fittings (dimensionless) . 2205=Constant(pound/megagram) . P° , M v , Kc=a

s define d above . (D ) Dec k sea m los s emission s shal l b e calculate d usin g th e followin g equation :P.2 8



### Federa l Registe r / Vo L 58 . N a 3

7 / Friday , Februar y 26 , 199 3 / Correction

s 1169 3

Dec k Sea mLos s (Mg/yr ) = - KDSDD 2 PXMVK C



### 220 4 6
where : Kf>=Dec k sea mlos s facto r

(pound-mole/fee t

year)

. =0.3 4 fo r non-welde ddecks

. = 0 fo r welde ddecks

. So=Dec k sea mlengt h facto r

(feet/feet 2 ) , see Tabl e 2 7 o f thi s subpart

. D , P* , Mv , Kc=a s define dabove

. (iv ) Th e followin g equatio n shal l b e use dfo r eac h externa l floating roo f vessel (i ) doe s no t

mee t th e specification s of

§ 63.119(c ) of

thi s Subpar t t o calculat e ES^CTUA L i n megagram s pe r

month :
ESiA c LW+LR+L P

1 2 where : Lw=Withdrawa l los s emission s In megagram s pe r

yea r calculate d accordin g t o paragrap h (f)(3)(iv)(A) of thi s section

. Lp=Ri msea l los s emission s i n megagram s pe r

year calculate d accordin g t o paragrap h (f)(3)(iv)(B ) o f thi s section

. Lp=Fittin g los s emission s i n megagram s pe r year calculate daccordin g t o paragrap h (f)(3)(iv)(C ) of thi s section

. (A ) Withdrawa l los s emission s shal l b e calculate dusin g th e followin g equation : Lw=4.28*10- » QCWJ D where : Q=Throughpu t

(gallon s pe r

year)

. C=Shel l clingag e factor

(barre l pe r

1,00 0 feet 2 ) , se e Tabl e 2 2 of

thi s subpart

. Wi.=Averag e liqui ddensit y (pound / gallon)

. D=Vesse l diamete r

(feet)

. (B ) Seal los s emission s shai i b e calculate dusin g th e following equation ; LSE=K,V N P*DM,K C /220 5 where : K,=Seal factor , see Tabl e 2 8 o f thi s subpart

. V=Averag o win dspee d(mile s pe r hour ) a t th e source . A valu e of

1 0 mile s pe r

hou r ma y b e assume di f

source specifi c dat aar e no t

available

. N=Sea l win dspee dexponent , se e Tabl e 2 8 o f thi s subpar t P*=Dimensionles s vapo r pressur e functio n e s define di n paragrap h (f)(3)(iii)(B ) o f

thi s section

. D=Vesse l diamete r

i n feet

. Mv=Molecular

weigh t ofth e HA P fai pound/po u nd-mole

. 5Q=Dimensionles s produc t facto r (us e 1. 0 for volatil e organi c HAP's)

. 2205=Constan t

(pound/megagram)

. (C) Fittin g los s emission s shal l b e calculate dusin g th e foliowin g equation : LKP=FFP*M,KC/220 5 where : FF=The tota l dec k

fitting los s facto r (poun dmol e pe r

year)

.



### n

- E <%!%! > = ((N F l 

### K F l 

### ) + (Np 2 

### K F2 

### ) 1 = 1 

### ( N F n 

### K F n 

### ) ]

whore : Nn=Numbe r

o f fittings of

aparticula r

typ e (dimensionless)

. N H i s determine dfo r th e specifi c tan k

o r estimate dfrom Table s 2 9 throug h 3 1 o f

thi s subpart

. K R =Dec k fitting los s facto r

fo r aparticula r

typ e fitting (poun dmol e pe r year)

. sKFaJ+Kp w V" 5 ' , see Tabl e 2 9 o f thi s subpar t

fo r th e appropriat e value s o f Kf» , KR H an dmfor

eac h fitting type
. P*

. M v , K « = a s define dabove

. (4 ) Emission s fromtransfe r rack s shal l b e calculate da s follows : (i ) Th e following equatio n shal l b e use dfor eac h transfe r

rack (i ) t o calculat e ETRj„ :
ETRi^fl^OxlO- 7 ) SPM G

where : ETRt e n Uncontrolle dtransfe r emissio n rate , megagram s pe r

month

. S s Saturatio n factor (se e Tabl e 3 2 of thi s subpart)

. P » Weighte daverag e rack vapo r pressur e of

organi c HAP' s transferre dat

th e rac k durin g th e month , kilopascals

. M = Weighte daverag e molecula r weigh t of organi c HAP' s transferre da t th e rac k durin g di e month , gram/gram

mole

. G s Monthl y volum e of

organi c HAP transfened , liter s pe r

month

. T » Temperatur e of

bul k liqui dloaded

. "Kelvi n ("0273)

. (ii ) Th e followin g equatio n shal l b e use dfor eac h transfe r

rac k (i ) t o calculat e th e weighte daverag e rack vapo r pressur e (P) : 

### J = n E < P 

### 3><Qj>

where :1169 4 Federa l Registe r/ Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s P=Weighted average rac

k vapo rpressure o f organi c HAP' s transferre d a tth e rac k durin g th e month , kilopascals . Pj=Vapo r pressure o f

individua l organi c

. HA P transferre

d a tth e rack, kilopascals . G=Monthly volum e o f

organi c HA

P transferred , liter s permonth . Gj=Monthl

y volum e of

individua l organi c HA

P transferre

d a tth e rack, liters . n=Numberof

organi c HAP' s transferre d a tth e rack. (iii ) Th e followin g equatio n shal l b e use d fo reach transfe

rrack (i ) t

o calculat e th e weighte d averag e rack molecula rweigh t(M) : M = 1
where : M=Weighted averag

e molecula rweigh t o f organi c HA

P transferre

d a tth e rac k during a month , gram/gram mole . Mj=Molecula

r weigh to

f individua l - • organi c HA

P transferre

d a tth e rack, gram/gram-mole . GpMontht

y volume , o

f individua l organi c HA

P transferre

d a tth e rack, liter s pe rmonth . n=Numberof organi c HAP' s transferre d a tth e rack. (iv ) Th e followin g procedure s and equation s shal l b e use d t o calculate ETRIACTUAL : (A ) I f th e transferrack i s no t controlled , ETRJACTUAL=ETRIU , wher e ETR m i s calculate d usin g th e equation s unde rparagraphs (f)(4)(i) , (f)(4)(ii) , and (f)(4)(iii ) of

thi s section . . (B ) I f th e transferrack i s controlle d usin g a contro l devic e ora pollutio n preventio n measur

e achievin g les s tha

» 9 8 percentreduction leve l associate d with th e reference contro l technolog y level ,

ETRjACTUAi . - ETR

j . . ( 1 - Percen treductio n



### 100 % )
(1 ) Th e percen treductio n fo ra combustio n o

rrecover y devic e shal l b e initiall y measured accordin g t o th e aquation s and method s specifie d i n § 63.128(a ) of thi s Subpart

. A s othe rcontro l technique s ar e used , percen treduction shal l b e demonstrate d b y a

n initia l performanc

e tes to rby a control desig n analysi s and documente d engineerin g calculations . (2) Procedure s fo

rcalculatin g th e percen treductio n fo r pollutio n preventio n measure s ar e specifie d i n paragrap h (i ) o f thi s section . (5 ) Emission s from wastewate rshal l b e calculate d as follows : I n paragrap

h (f)(5) o f thi s section , th e terms wastewate r an d wastewate rstrea

m ar e use d t o mea n wastewater . (i ) Th e followin g equatio n shal l b e use d fo reach wastewate rstrea

m (i ) t o calculate EWWic

:


### EWW 1 C 

### = (6. 0 xlO" 8 

### )Q,H , 1(1

- Fr m 

### )Fe m 

### HAP i m

### + (0.05)(6. 0 x 1 0 i- K 

### )Q,H , I (Fr m 

### HAP im 

### )

m= l where : EWWic=Monthl

y wastewate rstrea

m emissio n rate if

wastewate r strea

m (i ) i s controlle d by th e reference contro l technology , i n megagrams pe rmonth . Qi=Averag

e flow rate fo

rwastewate rstrea

m (i) , as detennine d b y th e procedure i n § 63.144(e)(3 ) o f thi s subpart, i n liter s pe rminute . Hi=Numbe

r of hour s durin g th e mont

h tha twastewate r strea

m (i j wa s discharged , i n hour s pe r month . Fr ro =Strippabilit

y factorof

HA P compoun d (m

) i n wastewater , from Tabl e 3 3 o f tid s subpart, dimensionless . Fe m=Fraction emitte d o f

HA P compoun d (m

) i n wastewate r from Tabl e 3 3 of thi s subpart, dimensionless . ,. . s=Tota l numbe rof

organi c HA

P compound s ir

i wastewate rstrea

m (i) . HAP im=Average organi c HA

P concentratio n of

compoun d (m

) i n wastewate rstrea

m (i) , i n part

s pe rmillio n b y weight , a s determine d fo

rth e poin tof

generatio n usin g th e samplin g procedure i n §63.144(b)(3)(i ) an d (b)(3)(ii ) of thi s subpart : T o analyz e th e sample s collected , (1 ) a tes tmetho d o r results from a tes tmetho d thatmeasure s organi c HA P concentration s i n th e wastewater , and tha tha s bee n validate d pursuantf o section . 5. 1 or 5. 3 o f Metho d 30 1 of appendi x A of

thi s Par tma y b e used ; or(2) th e procedure s i n § 63.144(b)(3)(iii)(A ) o f thi s Subpar

t ma y b e use d t o determin e th e term . Q m describe d below , and the n HAPi m ma y ba calculate d from i tusin g th e followin g equation : HAPi m=Ciro /Fm ro , wher e Fm m forcompoun d m i s obtaine d from Tabl e 1 3 o f thi s Subpart

. C im=Average VOHA

P concentratio n o

f HA P compoim d (m

) i n wastewate r strea

m (i) , a s determine d fo rth e poin tof generatio n accordin g t o th e procedure s i n § 63.144(b)(3 ) of thi s Subpart

, i n part s pe rmillio n b y weigh t (A ) Value s fo

rQj , Gm . an d HAPi

m ma y b a determine d durin g e n initia l perfonnanc e tes tconducte d unde rrepresentativ e conditions . Th e average valu e obtaine d fro m three tes trun s shal l b e used . Monthl y testin g i s no trequired . (B ) I f there i s a chang e t

o th e proces s o

roperatio n suc h tha

tth e previousl y measure d value s p f Q , Cim , and HAPi m ar e n o longe rrepresentative , a ne w perfonnanc e tes tshal l b e conducted . (C ) A s a n alternativ e f

o th e perfonnanc e testin g specifie d i n paragraph s (f)(5)(i ) (A ) an d (B ) of thi s section , Q

j ma y b e detennine d fro

m record s orproces s knowledg e a s specifie d i n § 63.144(a) . an d Q m an d HAPh , ma y b e determine d throug h proces s knowledg e a s specifie d i n § 63.144(b ) o f thi s Subpart

.P.3 0

.Federa l Registe r

I Vol

. 58 , Np f

.37; : / jFriday , Februar y 26 , 199 3 / Correction s 1169 5 (ii ) Th e followin g equatio n shal l b e use dt o calculat e EWWIACTUAL for eac h wastewate r

strea m(i ) whic h i s -nanage d i n an y wastewate r

tank , surfac e impoundment , container , individua l drai n system , o r oil-wate r

separato r

no t meetin g th e requirements o f

§§63.13 3 throug h 63.13 7 of thi s Subpart , respectively, o r an y othe r

wast e managemen t

uni t o r treatmen t proces s no t

meetin g th e requirements of § 63.138(h ) of

thi s subpart :


### (6.0x1 0 •'" . m=l - where : XEWWiAcruAL=Monthl

y wastewate r

strea memissio n rat e i f wastewate r

strea m(i ) i s no t

controlle dt o 7 th e leve l o f th e reference contro l technology, i n megagram s pe r month , Oj , Hi , s , Fem

, an dHAP

mar e a s define dan ddetermine daccordin g t o paragrap h (f)(5)(i ) of thi s section

. (iii ) Th e followin g equatio n shal l b e use dt o calculat e EWWIACTUAL for eac h wastewate r

strea m(i ) fo

r whic h al l wastewate r

tanks , surfac e impoundments , containers , individua l drai n systems , an doil-wate r separator s use dt o manag e th e wastewate r

strea mmee t

th e requirements of.§§63.13 3 throug h 63:13 7 o f thi s subpar t

an dan y othe r

wast e managemen t uni t o r treatmen t

process , meet s th e requirement s of §63.138(h ) of

thi s subpart , an dwastewate r strea m(i ) i s no t

controlle d t o th e leve l of

th e reference contro l technology :



### EWWiACT

### UAL = (6.0xlO- 8 

### )QiH i I [FemHAP^ l -PR i m 

### ) l ''.•.'. • m= l

where : EWWiACTUAL=Morithl

y wastewate r strea memissio n rat e i f

wastewate r strea m(i ) i s no t

controlle dt o th e leve l O f th e reference contro l technology , i n megagram s pe r month ; PR4 m =Th e efficienc y of

th e treatmen t process , o r

serie s o f treatmen t processes , whic h trea t

wastewate r : strea m(i) , i n reducin g th e emissio n potentia l o

f organi c HAP compoun d (m ) i n wastewater , dimensionless , : a s Calculate dby : 

### HAP; , HAP , "PRi m— • im-ou t 

### HAP , im- m

where : ' .7 ' HAPin^brAyerag e concentrationo f HAP

. compoun d(m) , define dan ddetennine daccordin g t o paragrap h (f)(5)(i ) o f thi s section , i n th e wastewate r enterin g th e first

treatmen t

proces s i n th e series

. HAPinw,w=Average concentratio n o f HAP compoun d(iri) , define dan ddetermine daccordin g t o paragrap h (f)(5)(i ) of thi s section , i n th e wastewate r exitin g m e las t

treatmen t

proces s i n th e series

. R,=Organi c reduction efficienc y o f th e devic e use dt o contro l an y vapo r stream s emitte dan dcollecte dfromwastewate r strea m(i ) durin g treatirient,a s deteririine daccordin g t o th e procedure s i n § 63.145(f ) o f thi s subpart

. Qi ; HI , s , Fem

, an dHAPiri , ar e a s define dan ddetermine daccordin g t o paragrap h (f)(5)(i ) o f thi s section

. Value s o f CaAni. Gnww, , Gu,, , an dHAPi mma y b e measure ddurin g an , initia l tes t o r determine dbase do n knowledg e ai s provide d i n paragrap h (f)(5)(i)(A) , (B) , an d(C) of thi s section

. . ; (g ) Credit s shal l b e calculate da s follows: |

. (1 ) Th e overal l equatio n fo r calculatin g source-wid e credit s is :P.3 1


### 1169 6 Federa

l Registe r /Vol . 58 , No . 3

7 / Friday , Februar y 26 , 199 3 / Correction

s

Credits ^ D I ((0.02)EPVl lu 

### -EPVl iACT 

### UAL )

1= 1

i n 

### + D Z (EPV2JBASE - 

### EPV 2 iACTUA U i= l



### + D I ((0.05)ESliu-ESliACTUAL ) i = l

+ D I (ES2 1 BASE-ES2 I A CTUAL ) I= I



### + D I ((0.02)ETR1 1U 

### -ETR I .ACTUAL ) 1= 1

+ D I (ETR2,„ASE-ETR2 IAC TUAL ) i = l .



### + D I ( EWW-

1 i c

### - EW\ V 1 iA 

### CTUA L ) i = l

+ D E (EWW2iBASE-EWW2 iA cTUAL ) i = l
where : Credit s an d al l terms of

th e equatio n ar e i n unit s o f

megagrams pe r month , an d th e baselin e dat

e i s Novembe r 15 , 1990 , excep ttha

tfo r a pollutio n preventio n measure initiate d afte r 198 7 o r a contro l applie d a s par tofth e early reduction progra

m o r th e 33/5 0 program , th e baselin e dat e i s prio r t o initiatio n ofth e pollutio n preventio n measure o r th e early reductio n or 33/5 0 progra m contro l strategy , an d D=Discoun tfactor=(

A rang e o f 0. 8 t o 1. 0 i s proposed . A singl e number wil l b e selecte d a

tpromulgation) . EPVliAcnjAL=Emission

s fo r each Grou

p 1 proces s ven t(i ) tha

ti s controlle d t o a leve l mor

e stringenttha

n th e reference contro l technology , calculate d accordin g t o paragrap h (g)(2 ) of thi s section . (0.02 ) EPVl| U =Emission s from each Grou p 1 proces s ven t(i ) if

th e reference contro l technolog y had bee n applie d t o th e uncontrolle d emissions . EPVli u i s calculate d accordin g t o paragrap

h (g)(2) o f thi s section . EPV2iAcnjAL=Emission

s from eac h Grou p 2 proces s ven t(i ) tha

ti s controlled , calculate d accordin g t o paragrap h (g)(2 ) of thi s section . EPV2 IB ASE=Emission

s froiri each Grou

p 2 proces s ven t(i ) a

tth e baselin e date , a s calculate d i n paragrap h (g)(2) o f thi s section . ESliACTUAL=Emission

s froir i each Grou

p 1 storage vesse l (i ) tha

ti s controlle d t o a leve l mor

e stringenttha

n th e reference control technology , calculate d accordin g t o paragrap h (g)(3 ) o f thi s section . (0.05 ) ES I j„=Emission

s from each Grou

p 1 storage vesse l (i ) if

th e reference control technolog y ha

d been applie d t o th e uncontrolle d emissions . ESl i u i s calculate d accordin g t

o paragrap

h (g)(3) o f thi s sectiori . ES2iAcruAL=Emission

s from each Grou

p 2 storag e vesse l (i ) tha

ti s controlled , calculate d accordin g t o paragrap h (g)(3 ) of thi s section . ES2iRASE=Emission s from eac h Grou

p 2 storage vesse l (i ) a

tth e baselin e date , a s calculate d i n paragraph (g)(3 ) of thi s section . ETRliACTUAL=Emission

s from eac h Grou p 1 transfer rac

k (i ) tha ti s controlle d f

o a leve l more stringent tha n th e referenc e contro l technology , calculate d accordin g t o paragrap h (g)(4 ) o f

thi s section. (0.02 ) ETRli U =Emission s from eac h Grou p 1 transfer rac

k (i ) i f th e reference contro l technolog y ha d . bee n applie d t o th e uncontrolle d emissions . ETR

I i u i s calculate d accordin g t o paragrap

h (g)(4 ) o f

thi s section . ETR2 iA cTUAL=Emission

s from eac h Grou p 2 transfer rac

k (i ) tha tar e controlled , calculate d accordin g t o paragrap h (g)(4 ) o f

thi s section . ETR2iBASE=Emission

s from each Grou

p 2 transfer rack (i ) a

tth e baselin e date , a s calculate d i n paragrap h (g)(4 ) o f thi s section. EWWliACTUAL=Emission s from eac h Grou p 1 wastewate r strea

m (i ) tha tP.3 2

Federa l Registe r

/Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 /Correction s 1169 7 i s controlle dt o aleve l mor e stringen t tha n th e reference contro l technology , calculate daccordin g t o paragrap h (g)(5 ) of

thi s section

. EWWlit—Emission s fromeac h Grou p 1 wastewate r

strea m(i ) i f

th e referenc e contro l technolog y ha d bee n applie dt o tb e uncontrolle d emissions , calculate daccordin g t o paragrap h (g)(5 ) of

thi s section

. E\VW2iACTUAL=Emission s fromeac h Grou p 2 wastewate r

strea m(i ) tha t i s controlled , calculate daccordin g t o paragrap h (g)(5 ) of

thi s section

. EWW2

iB ASE=Emission s fromeac h Grou p 2 wastewate r

strea m(i ) at

th e baseUn e date , calculate daccordin g

t o paragrap h (g)(5 ) of

thi s section

. n=Numbe r

o f Grou p 1 emissio n point s include di n th e emission s average . Th e valu e of

n i s no t necessaril y th e sam e fo r proces s vents , storag e vessels , transfe r

racks, an d wastewater ; m=Numbe r

o f Grou p 2 emissio n point s include di n th e emission s average . Th e valu e of

mi s no t necessaril y th e sam e fo

r proces s vents , storag e vessels , transfe r

racks, an d wastewater
. (2 ) Emission s fromproces s vent s shal l b e determine da s follows : (i ) Uncontrolle demission s from Grou p 1 proces s vents , EPVl tu , shal l b e calculate daccordin g t o tb e procedure s an dequation s i n paragraph s (f)(2)(i ) an d (f)(2)(h) of

thi s section

. (ii ) Th e followin g procedure s an d equations : shal l b e use dt o calculate , actua l emission s fromGrou p 1 proces s vents , EPVliAcnjAL , (A ) IfaGrou p 1 proces s ven t i s controlle dusin g atechnolog y wit h a n approve dnomina l efficienc y greate r tha n 9 8 percen t

o r apollutio n preventio n measur e achievin g greate r tha n 9 8 percen t

emissio n reduction.

EPV 1 .ACTUA

L = EPVl j ( ' - Nomina l efficienc y % 100 % )

(B ) Th e nomina l efficienc y shal l b e determine da s describe di n paragrap h (h ) o f thi s sectio n fo

r acontro l devic e an dparagrap h (i ) of

thi s sectio n fo

r a pollutio n preventio n measure . (C) Combustio n device s shal l no t b e attribute danomina l efficienc y greate r tha n 9 8 percent , unles s the y hav e bee n assigne dahighe r nomina l efficienc y accordin g t o th e procedure s i n paragrap h (h ) o

f thi s section

. (iii ) Th e followin g procedure s shal l b e use dt o calculat e actua l emission s from Grou p 2 proces s vents , EPV2IACTUAL : (A) I f aGrou p 2 proces s ven t

i s controlle db y acontro l device , a recover y devic e applie dafter 198 7 a s a pollutio n preventio n project , o r a pollutio n preventio n measur e achievin g apercen t reductio n les s tha n o r

equa l t o 9 8 percen t

reductio n leve l associate d wit h th e referenc e contro l technology ,



### EPV2 , ACTUAL
- 

### EPV2 m 

### x 1

- ( 

### Percent

reductio n 100 % )

(J ) EPV2 i

u shal l b e calculate daccordin g t o th e equation s an dprocedure s i n paragrap h (f)(2)(i ) ari d(f)(2)(ii ) o f thi s section , excep t

a s provide di n paragrap h (g)(2)(iii)(A)(3 ) below

. 12) Th e percen t

reductio n shal l b e calculate daccordin g t o th e procedure s i n paragrap h (f)(2)(iii)(B)(J) , (2) , an d(3 ) of thi s section , excep t

a s provide di n paragrap h (g)(2)(iii)(A)(4 ) below

. . (3 ) I f arecover y devic e wa s adde da s par t o f apollutio n preventio n projec t initiate dafte r

1987 , EPV2io shal l b e calculate dprio r

t o th e recovery device..

. Th e equatio n i n paragrap h (f)(2)(ii ) o f thi s sectio n shal l b e use dt o calculat e EPV2i„ ; however , th e samplin g sit e fo r measuremen t

o f ven t strea mflow rate , organi c HAP concentration , an dtemperatur e shal l b e at

th e inle t o f th e recovery device

. (4 ) If arecover y devic e wa s adde da s par t of apollutio n preventio n projec t initiate dafter

1987 , th e percen t

reduction shal l b e demonstrate db y conductin g aperformanc e tes t a t th e inle t an doutlet

o f th e recover y device

. (B ) I f aGrou p 2 proces s ven t i s controlle dusin g atechnolog y wit h a n approve dnomina l efficienc y greate r tha n 9 8 percen t

o r apollutio n preventio n measur e achievin g greate r tha n 9 8 percen t

reduction,

EPV2 IACT UAL = 

### EPV2 ; 

# 0 - Nomina l efficienc y %

•<"-•• 100 % ) (1 ) Th e nomina l efficienc y shal l b e detennine da s describe di n paragrap h (h ) o f thi s sectio n fo r

acontro l devic e o r i n paragrap h (i ) of

thi s sectio n fo

r apollutio n preventio n measure .P.3 3

1169 8 Federa l Registe r /Vol

. 58 , No
. 3 7 / Friday , Februar y 26 , 199 3 /Correction s (2 ) Combustio n device s shal l no t b e attribute danomina l efficienc y greate r tha n 9 8 percent , unles s the y hav e bee n assigne dahighe r

nomina l efficienc y accordin g t o th e procedure s i n paragrap h (h ) of thi s section

. 7 (iv ) Emission s fromGrou p 2 proces s vent s at baseline , EPV2i iBA sE , shal l b e calculate da s follows : (A ) I f th e proces s Ven

t wa s uncontrolle do n Novembe r 15 , 1990 , EPV^BAi

E = EPV2 iu an dshal l b e calculate daccordin g t o th e procedure s an dequation s i n paragraph s (f)(2)(i ) an d(f)(2)(H) i of this.section

. (B ) I f th e prbces s ven t

wa s controlle do n Novembe r 15 , 1990 , an dthi s contro l wa s no t applie dunde r

eithe r th e 33/5 0 o r th e earl y reductio n progra man dwa s no t th e resul t

o f apollutio n preventio n measure . 

### Percent reductio n % EPV2iBAS C = 

### EPV2 i u 

# ( Percent reductio n % v. , ; 100 % : . )
Wher e EPV2i „ i s calculate daccordin g t o th e equation s i n paragraph s (f)(2)(i ) an d(f)(2)(ii ) o f thi s section

. Th e percen t reduction shal l b e calculate daccordin g t o th e procedure s specifie di n paragraph s (f)(2)(iii)(B ) (1)

. (2)

. and.(3 ) o f thi s section

. (C) I f arecover y device : wa s adde dt o aproces s ven t a s par t of apollutio n preventio n projec t initiate dafter

1987

. EPV2IBAS E = EPV2| U , wher e rtPV2 i u i s calculate daccordin g t o paragrap h (g)(2)(iii)(A)(3 ) o f thi s section

. (3 ) Emission s fromstorag e vessel s shal l b e determine da s follows : (i ) Uncontrolle demission s fromGroup : 1 storag e vessels , ESli„ , 6hal l b e calculate daccordin g t o th e equatio n i n paragrap h (f)(3)(i ) of

thi s section

. (ii ) Th e followin g procedure s an dequation s shal l b e use dt o calculat e actua l emission s fromGrou p 1 storag e vessels , ESliAcniAL . (A ) I f aGrou p 1 storag e vesse l i s controlle dusin g atechnolog y wit h a n approve dnomina l efficienc y greate r tha n 9 5 percen t

o r apollutio n preventio n measur e achievin g greate r tha n 9 5 percen t

emissio n reduction ; 

### Nomina l efficiency

. % ESl i ACTUAL

- 

### E S l i



# uJi- 100 % (B ) Excep t

e s provide di n paragrap h (g)(3)(ii)(c ) o f thi s section , th e nomina l efficienc y shal l b e determine da s describe d i n paragrap h (h ) of

thi s sectio n fo

r acontro l devic e an dparagrap h (i ) of thi s sectio n fo

r apollutio n preventio n measure . (C ) i f aGrou p 1 Storag e Vesse l i s controlle dusin g aclose dven t syste man dcontro l devic e tha t i s demonstrate d t o achiev e e t

leas t 9 8 percen t

emissior ) reduction , the n th e 8 8 percen t ca n b e use da s th e nomina l efficiency , i n th e equatio n i n paragrap h (g)(3)(ii)(A ) o f thi s section , an dth e bwne r o r operato r i s no t require dt o appl y fo

r anomina l efficienc y accordin g t o paragrap h (h ) o f thi s section

. (1 ) T o demonstrat e tha t

9 8 percen t

emissio n reduction i s achieved , th e owne r o r operato r shal l conduc t

aperformanc e tes t accordin g t o th e procedure s i n §63.11 6 o f thi s Subpar t

o r us e adesig n analysis

. I f aperformanc e tes t

i s used , samplin g site s shal l b e locate da t th e inle t an doutle t

o f th e contro l device

.

. [2) Thi s owne r

o r operato r shal l repor t

the.result s of

th e perfonnance : tes t

an destablis h th e rang e for th e monitore d parameters ) i n th e Notificatio n ;o f Complianc e Statu s requiredb y § 63.152(b ) of thi s subpart

. : (iii ) Th e followin g procedure s shal l b e use dt o calculat e actua l emission s fromGrou p 2 storag e vessels , ES2IACIVAL : (A) I f aCrou p 2 storag e vessel i s controlle dusin g aclose dven t syste man dcontro l devic e o r apollutio n preventio n measur e achievin g apercen t reduction les s tha n o r

equa l t o th e 9 5 percen t reduction leve l associate dwidi

. the;referenc e i contro l technology

. 

### Percent reductio n 

# ( t n \ 1

- —. —

) 100 % /

wher e £Si u i s calculate daccordin g t o th e equation s an dprocedure s i n paragrap h (f)(3)(i ) of thi s section

. (B ) I f aGrou p 2 storag e vesse l i s controlle dwit h a n interna l o r externa l floating roof

, ES2iAcniA

L shal l b e calculate d a s specifie di n paragrap h (f)(3)(iii ) o r (f)(3)(iv ) b f

thi s section

.

. (C) If

. aGrou p 2 storag e vessel i s controlle d.usin g atechnolog y wit h a n approve dnomina l efficienc y greate r tha n 9 5 percen t

o r apollutio n preventio n measur e achievin g greate r tha n 9 5 percen t

reduction.P.3 4

:e r / VbJ

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 /Correction s

ES2 , ACTUA L = ES2 1U : l ( ' Nomina l efficienc y %

100 % :
(J) Th e nomina l efficienc y fo r a contro l devic e shal l b e determine d as describe d i n paragrap

h (h ) of thi s section , excep ta s provide d i n paragrap h (g)(3)(iii)(D ) o

f thi s section . (2) Th e nominal efficiency fo ra pollutio n preventio n measure shal l b e determine d as describe d i n paragrap h (i ) o f thi s section . (D) I f aGrou p 2 Storage Vesse l i s controlle d usin g aclose d ven tsystem and contro l devic e tha

ti s demonstrated t o achiev e a

tleas t9 8 percentemissio n reduction, the n th e 9 8 percentca n b e use d as th e nominal efficiency i n th e equatio n i n paragrap

h (g)(3)(iii)(C ) o

f thi s section , and th e owne roroperator i s no trequired t o appl y fo ranominal efficienc y accordin g t

b paragrap

h (h ) of thi s section . .•-•• - (1 ) T o demonstrat

e tha t9 8 percent emissio n reductio n i s achieved , th e owne r oroperator shal l conduc ta performanc

e tes taccordin g t o th e procedure s i n § 63.11 6 of thi s Subpar

tor us e adesig n analysis . I

f aperformanc

e tes ti s used , samplin g site s shal l b e locate d a tth e inle tan

d outle tofth e contro l device . (2) Th e owne ro

roperatorshal l repor

t th e results of

th e performanc

e tes tand establis h th e rang

e fo rth e monitore d parameter(s) i n th e Notificatio n o f Complianc e Status required by §63.152(b ) o

f thi s Subpart

. (iv ) Emission s from Grou p 2 storag e vessel s a tbaseline , ES2

iB ASE > shal l b e calculate d a s follows : (A ) I f th e vesse l wa s notcontrolle d with a n interna l floating roof

, a n externa l floatin g roof

, aclose d ven t syste m ari

d control device , oranothe r control techniqu e o n Novembe r15 , 1990 , ES2JBA.S

E = ES2| H and shall b e calculate d accordin g t o th e procedure s and equation s i n paragrap h (f)(3)(i ) of thi s section . (B ) I f th e storage vesse l wa s controlle d o n Novembe r15,1990 , an d thi s contro l wa s no tapplie d unde reithe r th e 33/5 0 o rth e early reduction progra m an d wa s no tth e resultof

a pollutio n preventio n measure , (J) Th e equation s i n paragrap h (f)(3)(iii ) o

f thi s sectio n shal l b e use d t o calculate ES2 (B AS E fo

rvessel s controlle d with a n interna l floatin g roof

. (2 ) Th e equation s i n paragrap h (f)(3)(iy ) o f thi s sectio n shal l b e use d t o calculat e ES2JBAS E fo

rvessel s controlle d with a n externa l floating roof

. (73 ) Th e followin g equation s shal l b e use d t o calculat e ES2 1B AS E forvessel s controlle d with a close d ven tsyste m and control device ,

ES2JBASE = 

### ES2j , (>-. Percen t reductio n % 100 %

wher e ESt o is calculate

d accordin g t o th e equation s i n paragrap h (f)(3)(i ) o f thi s section. , (4 ) Emission s fro

m transferracks shal l b e determine d as follows : (i ) Uncontrolle d emission s from Grou p 1 transfe

r racks , ETRlio , shal l b e calculate d a s describe d i n paragraphs (f)(4)(i) , (f)(4)(ii) , ari

d (f)(4)(iii ) o f

tbi s section. (ii ) Tb e foliowin g procedure s and equation s shal l b e use d t o calculat e actua l emission s from Grou

p i transfer racks , ETRIIACTUAL : • • .'.••"• ' . (A ) I f a Grou p 1 transferrac

k i s controlle d usin g a technology , othe rtha n th e reference contro ) technology , wit h a n approve d nomina l efficienc y greaterthan 9 8 percento ra pollutio n preventio n measure 7 achievin g greaterthan 9 8 percentemissio n reduction ,

ETRliAcruAL = ETRli u 1 Nomina l efficienc y 100 % (B ) Th e nomina l efficienc y shal l b e detennine da s describe di n paragrap h (h ) o f thi s sectio n for acoatro l devic e otbe r tha n th e referenc e technolog y an dparagrap h (i ) o f thi s sectio n for apollutio n preventio n measure . (C ) Combustio n .devices , carbo n adsorbers , absorbers , ian dcondensers-shal l no t

-'b e attribute da-nomina l efficienc y greate r tha n 9 8 percen t

•,-•••. . • • •.'-,•.-.•
. ';

. (iii ) Th e followin g procedure s anal ! b e use dt o calculat e actua l emission s iro mGrou p 2 .transfe r racks,' ETOaucruAL : I (A ) I

f aQroup^ S ts^s^t e ^^.ist-contfwlle db y & >cont ^ GcWovin g a percen t reductions les s the

moe equa l t o th e 98)

. percent ; leve l assodate dwit b th e reference contro l technology, ' "P.3 5

1170 0 Federa l Registe r / Vol

. 58 , No
. 3 7 /

Friday

. Februar y 26

. 199 3 /

. Correction s

ETR2 IAC TUAL = 

### ETR2i 

## (• - Percen t reductio n \ 100 % (1 ) ETR^ u shal l b e calculate daccordin g t o th e equation s an dprocedure s i n paragraph s (f)(4)(i)

. (f)(4)(ii)

. an d(f)(4)(iii ) o f thi s section

. (2 ) Th e percen t

reduction shal l b e calculate daccordin g t o th e procedure s i n paragrap h (f)(4)(iv){B ) (1 ) an d(2 ) o f thi s section

. (B ) I f e Crou p 2 transfe r

rack i s controlle dusin g atechnology , othe r tha n th e reference contro l technology , wit h a n approve dnomina l efficienc y greate r the n 8 8 percen t

o r apollutio n preventio n measur e achievin g greate r tha n 9 8 percen t reduction.



### ETR2 , ACT U AL 

### = ETR2, U 

### I 

# iJi Nomina

l efficienc y 7 100 %
(? ) Th e nomina l efficienc y shal l b e determine da s describe di n paragrap h (h ) o f thi s sectio n fo

r acontro l devic e o r i n paragrap h (i ) o f

thi s sectio n fo

r apollutio n preventio n measure . (2 ) Combustio n devices , carbo n adsorbers , absorbers , an dcondenser s shal l no t b e attribute danomina l efficienc y greate r tha n 9 8 percen t (iv ) Emission s fromGrou p 2 transfe r rack s a t baseline , fclK2 m ASE. shal l b e calculate da s follows : (A ) I f th e transfe r

rac k wa s uncontrolle do n Novembe r 15

. 1990 , ETR2JBAS E = ETR2 i u an dshal l b e calculate daccordin g t o th e procedure s an dequation s i n paragraph s (f)(4)(i)

. (f)(4)(H) , an d(fl(4)(iii ) o f thi s sectiori

. (B ) I f th e transfe r

rac k wa s controlled'o n Novembe r 15 , 1990 , an dthi s contro l wa s no t applie d7 unde r

eithe r th e 33/5 0 o r th e earl y reductio n programan dwa s no t th e resul t

of apollutio n prevention measure .



### ETR2 iaAS 

### E = ETR2 1 U 

### l

- Percent reductio n 100 %

wher e ETR2, „ i s calculatedaccordin

g t o th a equation s i

n paragraph s (f)(4j(i) , (fi(4)(ii)

. en d (0(4!(<ii ) o f thi s section

. Percen

t reduction shall b e calculate daccordin

g t o the procedure s i n paragraph s (f)(4)(iv)(B) ( 1 ) and (2 ) o f thi s section

. • (5 ) Emission s fro

mwastewate r

shal l b e determine da s follows

. I n paragrap h (g)(5 ) o f thi s section , th e term s wastewate r

an dwastewate r

strea mar e use dt o mea n proces s wastewater
. (i ) EWW1 « shal l b e calculate d accordin g t o th e equatio n fo r EWW * i n paragrap h (f)(5)(i ) of

thi s section.

. (ii ) EWW2iBA

S Eshal l b e calculate d accordin g i o th e equatio n fo r EWWtAcruA

L i n paragrap h (f)(5)(ii ) o f thi s sectio n fo

r eac h wastewate r

strea m (i) , which , o n th e baselin e dat e specifie d i n paragrap h (g)(1 ) o f

thi s section ; wa s ..- ; untreated , o r

whic h wa s manage deithe r i n awastewate r

tank , surface , impoundment , container , individua l drai n syste mo r

oil-wate r separato r

no t meetin g th e requirements of §63.13 3 throug h § 63.13 7 o f

thi s subpart

. . . respectively , o r

i n an y othe r

wast e . managemen t uni t o r treatmen t

proces s no t meetin g th e requirement s of § 63.138(h ) of

thi s subpart

. (iii ) EWVV2iaAS

E shal l b e calculate d accordin g t o th e equatio n fo r EVVWiAcruA

L i n paragrap h (f)(5)(iii ) o f thi s sectio n for

eac h wastewate r

strea m (i)

. fo r whic h al l tanks , surfac e impoundments , containers , individua l drai n system s an doil-wate r separator s use dt o manag e th e wastewate r strea m me t th e requirement s of

§63.13 3 throug h § 63.13 7 of

thi s subpart , respectively, an dfo

r whic h al l othe r wast e managemen t

unit s o r treatmen t processe s use dt o manag e th e wastewate r

strea mme t

th e requirement s o f § 63.138(h ) o f

thi s subpar t

o n th e baselin e dat e specifie din.paragrap h (g)(1 ) o f thi s section

. . . . . . , (iv)EVvlV2

iA cTUA L shal l b e calculate d a s follows: (A) EWW2iAovA

L shal l b e calculate d accordin g t o tb e equatio n fo r EWWIACHJA L ir

i paragrap h (f)(5)(iii ) of

. thi s sectio n fo

r eac h wastewate r

strea m (i ) whic h i s controlle dt o aleve l les s

stringen t than , o r equivalen t

to , th e referenc e contro l technolog y level

. Grou p 2 stream s ar e no t

considere dt o b e controlle di

f the y ar e no t

treate db y atreatmen t

process , o r

i f the y er e manage di n an y wastewate r tank , surfac e impoundment , container , individua l drai n system , o r oil-wate r separato r no t meetin g th e requirement s o f £63.13 3 throug h §63.13 7 o f thi s subpart , respectively, o r

i n an y othe r wast e managemen t

uni t p r treatmen t proces s no t

meetin g th e requirement s of § 63.138(h ) of

thi s subpart

. (B ) I f aGrou p 2 wastewate r

strea mi s controlle dt o aleve l mor e stringen t tha n th e leve l o f

th e referenc e contro l technology , th e procedure s for calculatin g EWWIIACIUA L in

. paragraph, , (g)(5)(v j of thi s sectio n shal l b e use dt o calculat e EWWiiAcruAL. : , (v ) Th e followin g equation s for EWWliACTUA

L shal l b e use dt o calculat e emission s fro

meac h Grou p 1 wastewate r

strea m(i ) tha t

i s controlle dP.3 6

Federa l Registe r

/ Vol

. 58 , No
. 3 7 /Friday , Februar y 26 , 199 3 / Correction s 1170 1
t o aleve l mor e stringen t

tha n th e referenc e contro l technology

. Grou p 1 stream s ar e no t

considere dt o b e controlle dt o o r

abov e th e leve l o

f th e referenc e contro l technolog y if the y ar e manage di n an y wastewate r tank , surfac e impoundment , container , individua l drai n system , o r oil-wate r separato r no t meetin g th e requirement s o f §63.13 3 throug h §63.13 7 o f thi s subpart , respectively , o r i n an y othe r wast e managemen t

uni t o r treatmen t proces s no t

meetin g th e requirements o f § 63.138(h ) o

f thi s subpart

. (A ) I f th e Grou p 1 wastewate r strea m (i ) i s controlle dusin g atreatmen t proces s o r

serie s o f treatmen t

processe s whic h achiev e an approve dnomina l reduction efficienc y i n th e tota l VOHA P concentratio n o

f stream(i ) greate r

tha n tha t

whic h woul db e achieve dusin g th e desig n steamstrippe r

specifie di n § 63.138(f ) of thi s Subpart , bu t

th e contro l devic e use dt o reduce HAP emission s fromth e vapo r strsam(s ) vente dfromth e treatmen t process(es ) achieve s s n efficienc y equa l t o th e 9 5 percen t o f th e reference contro l technology , th e followin g formul ashal l b e used :

EW\V1 IAC TUA I 

### = (6. 0 x 10- * )Q,H , I | Fe n! 

### H AP mi 

### ( 1 m = i 

### PR, m 

### ) ] +0.0 5 (6.0xlO- K 

### )Q,H , I [HAP im 

### PR im 

### ] m = l

wher e al l term s are a s define dan ddetennine di n paragrap h (f)(5 ) o f thi s section

. (B ) I f th e Grou p 1 wastewate r stream(i ) i s no t

controlle dusin g atreatmen t proces s o r

serie s o f treatmen t

processe s whic h achieve s atota l VOHA P concentratio n reductio n greate r tha n tha t

whic h woul db e achieve dusin g th e desig n stea mstrippe r

specifie di n § 63.138(f ) o f thi s Subpart , bu t

th e vapo r

stream(s ) vente dfromth e treatmen t process(es ) ar e controlle dusin g adevice , othe r tha n th e referenc e contro l technology , fp r whic h EP

A ha s approve danomina l efficienc y greate r

tha n 9 5 percent , th e followin g formul ashal l b e used : 

### EWWl, AC1UAl 

### y 7 6. 0 x 10~ s 

### )Q,H , I
. [ Fe m 

### l i AP l!71 

### (

. 1 - Fr m 

### ) ; niF l

Nomina ! efficienc v % s V 

### 10 0 (6.0xl()- K 

### )Q 1 

### H , I |HAP im 

### Fr m 

### | m = l
wher e al l term s othe r

tha n nomina l efficienc y ar e a s define dan d determine di n paragrap h (f)(5 ) o f thi s section

. (C ) I f th e Grou p 1 wastewate r stream (i ) i s controlle dusin g atreatmen t proces s o r serie s o f treatmen t

processe s whic h achieve s atota l VOHA P concentratio n reductio n greate r tha n tha t whic h woul db e achieve dusin g th e desig n steamstrippe r

specifie di n §63.138(f ) o f thi s Subpart , an dth e vapo r stream(s ) vente dfro

mth e treatmen t proces s ar e controlle dusin g a device , othe r

tha n th e referenc e contro l technology , wit h a n approve dnomina l efficienc y greate r

tha n 9 5 percent , th e followin g formul ashal l b e used :



### EWWI lACTlML 

### = (6.0xl()- K 

### )Q,H , I [Fe m 

### HAP, m 

### ( I -PR„,) J m= l

( - Nomina l efficienc y %

10 0 ) 

### (6:0xl()-»)Q,H I 

### I [HAP im 

### PR m 

### | m = l

wher e al l term s othe r

tha n nomina l efficienc y ar e a s define dan d determine di n paragrap h (f)(5 ) of thi s section

. (D ) Th e nomina l efficienc y fo r a treatmen t proces s o r

contro l devic e shal l b e determine da s describe di n paragrap h (h ) of thi s section

. (h ) Th e followin g procedure s shal l b e followe dt o establis h anomina l efficienc y fo

r an y contro l technolog y achievin g greate r

emissio n reduction tha n th e percentag e efficienc y assigne d t o th e reference contro l technolog y i n § 63.11 1 o

f thi s subpart

. Th e procedure s i n paragraph s (h)(1 ) throug h (h)(5 ) of

.. . thi s sectio n shal l b e followe dfo r contro l technologie s tha t

ar e differen t

i n us e o r desig n fromth e reference contro l technologies

. Th e procedure s i n paragrap h (h)(6 ) of

thi s sectio n shal l b e followe dfo

r proces s vent s controlle db y reference contro l technologie s tha t ca n b e demonstrate dt o consistentl y achiev eP.3 7

1170 2 Federa l Registe r/ Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s

a highe r contro l efficienc y tha n tha t whic h hs s bee n assigne d b y th e propose d rul e t o tha tparticula rtyp e o f device . (1 ) Th e owne ro roperato rseekin g permissio n t o tak e credi tfo rus e o f a ttxhnolog y tha ti s differen ti n us e o r desig n fro m th e reference contro l technolog y shal l submi tth e informatio n specifie d i n paragraph s (h)(l)(i ) throug h (h)(l)(iv ) o f

thi s sectio n i n writin g t o th e Directo r o f

th e EP A Offic e o f

Ai rQualit y Plannin g an d Standards : (i ) Emissio n strea m characteristic s o f eac h emissio n poin tt o whic h th e contro l technolog y i s o rwil l b e applie d includin g th e kin d o f

emissio n points , flow , organi c HA P concentration , an d al l othe r strea m characteristic s necessar y t o desig n th e contro l technolog y o rdetermin e it s performance , (ii ) Descriptio n o f

tiie contro l technolog y includin g desig n specifications . (iii ) Documentatio n demonstratin g t o th e Director' s satisfactio n th e contro l efficienc y o f

th e contro l technology . Thi s ma y includ e performanc e tes tdata collecte d usin g a n appropriat e EP A metho d o ran y othe rmetho d validate d accordin g t o Metho d 30 1 o f appendi x A o f thi s part , l f

i ti s infeasibl e t o obtai n tes tdata , documentatio n ma y includ e a desig n analysi s an d engineerin g calculations . Th e basi s ofth e calculationa l procedure s an d al l input s an d assumption s mad e i n th e calculation s shal l b e documented . (iv ) A descriptio n ofth e paramete ro r parameter s t o b e monitore d f o ensur e tha tth e contro l technolog y wil l be ' operate d i n conformanc e wit h it s desig n an d a n explanatio n o f

th e criteri a use d fo r selectio n o f

tha tparamete r(o r parameters) . (2 ) Th e Directo rshal l determin e withi n 12 0 day s whethe r a n applicatio n present s sufficien tinformatio n t o determin e nomina l efficiency . Th e Directo r reserve s th e righ tt o reques t specifi c dat a i n additio n t o th e item s liste d i n paragrap h (h)(1 ) o f tlii s section . (3 ) Th e Directo rshal l determin e withi n 12 0 day s ofth e submitta l o f sufficien tdat a whethe ra devic e shal l hav o a nomina l contro l efficienc y an d th e leve l o f

tha tnomina l efficiency . If , i n th o Director' s judgment , th e contro l technolog y achieve s a leve l o f emissio n reductio n greate rtha n th e referenc e contro l technolog y fo ra particula r kin d o f emissio n point , th e Directo rwil l publis h a Federa l Registe rnotic e establishin g a nomina l efficienc y fo rth e contro l technology . . (4 ) The-Directo r ma y conditio n permissio n t o tak e emissio n credit s fo r us o o f th e contro l technolog y o n requirements tha tma y b e necessar y t o ensur e operatio n an d maintenanc e t o achiev e th e specifie d nomina l efficiency . (5 ) I n i n os e case s wher e th e owne r o r operatori s seekin g permissio n t o tak e credi tfo r us e of a technolog y lha ti s - differen ti n us e o rdesig n fro m th e reference contro l technolog y an d th e differen ttechnolog y wil l b e use d i n n o mor e tha n thre e applications , th e informatio n liste d i n paragraph s (h)(l)(i ) throug h (h)(l)(iv ) ca n b e submitte d t o th e operatin g permi tauthorit y fo r th e sourc e instea d o f

th e Director . I n thes e instances , us e an d condition s fo rus e o f th e differen ttechnolog y ca n b e approve d a s parto f

a n operatin g permi t applicatio n o rmodification . In thes e instances , a Federa l Registe r notic e I s no trequire d t o establis h th e nomina l efficienc y fo r th e differen ttechnology . (i ) If , i n reviewing th e application , th e operatin g permi tauthorit y believe s th e technolog y ha s broa d applicabilit y fo r us e b y othe rsources , th e authorit y shal l submi tth e informatio n provide d i n th e applicatio n t o th e Directo r o f th e EP A Offic e o f Ai rQualit y Plannin g an d Standards . Th e Directo r shal l review th e technolog y fo r broa d applicabilit y an d ma y publis h a Federa l Registe r notice ; however , thi s EP

A review shal l no t affec tth e operatin g permi tauthority' s approva l o f

th e nomina l efficienc y o f th e technolog y for th e specifi c application . (ii ) If , i n reviewing a n applicatio n fo r a proces s ven tcontrol , th e operatin g permi tauthorit y determine s tha tthe . technolog y i s no tdifferen ti n us e an d desig n from th e reference contro l technology , th e authorit y shal l submi t th e applicatio n t o th e Directo rofth e EP A Offic e o f

Ai r Qualit y Plannin g an d Standards . Th e procedure s i n paragrap h (h)(6 ) o f thi s sectio n shal l b e followe d fo rsubmissio n o f

information , review, an d approva l o f

th e nomina l efficiency . If , i n reviewing a n applicatio n fo r a contro l fo r a n emissio n poin tothe rtha n a proces s vent , th e operatin g permi t authorit y determine s th e technolog y i s no tdifferen ti n us e o r desig n from th e reference contro l technolog y an d i s no t a close d ven tsyste m fbr a storag e vessel , th e authorit y shal l den y th e application ! (6 ) A n owne ro r operato r seekin g permissio n t o tak e credi tfo ra proces s ven tusin g reference contro l technolog y tha tachieve s a percen temissio n reduction efficienc y highe r tha n th e percen tassigne d t o th e referenc e contro l technolog y i n § 63.11 1 shal l submi tth e informatio n i n paragraph s (h)(8)(i ) throug h (h)(6)(iv ) o f

thi s sectio n t o th e Directo ro f

th e EP A Offic e o f

Air , Qualit y Plannin g an d Standards . Th e procedure s i n paragraph s (h)(2 ) throug h (h)(4 ) o f tbi s sectio n shal l b e followe d fo rrevie w an d approva l o f th e nomina l efficienc y o f

th e control-technolog y i n th e specifie d application . (i ) emission.strea m characteristic s o f eac h proces s ven tt o whic h th e contro l technolog y i s o r wil l b e applie d includin g th e flow , organi c HA P concentration , an d al l othe rven tstrea m characteristic s necessar y t o desig n th e contro l technolog y o rdetermiri e it s performance . (ii ) Descriptio n ofth e contro l technolog y includin g desig n specifications , (iii ) Documentatio n demonstratin g t o th e Director' s satisfactio n tha tth e technolog y i n th e intende d applicatio n achieve s 99. 9 percen to r greate r emissio n reduction . Thi s documentatio n shal l includ e performanc e tes tdat a collecte d usin g a n appropriat e EPA metho d o ran y othe rmetho d o r dat a validate d accordin g t o Metho d 30 1 o f appendi x A o f

thi s part . (iv ) A pla n fo r institutin g continuou s emission s monitorin g t o demonstrat e tha t99. 9 percen temissio n reductio n i s achieve d o n a continuou s basis . (i ) Th e followin g procedure s shal l b e use d fo rcalculatin g th e efficienc y (percen treduction) o f

pollutio n preventio n measures : (1 ) A pollutio n preventio n measur e i s an y practic e whic h meet s th e criteri a o f paragraph s (i)(l)(i ) an d (ii ) o f thi s section . (i ) A pollutio n preventio n measur e i s an y practic e whic h results i n a lesse r quantit y o f

organi c HA P emission s release d t o th e atmospher e prio r t o out of-proces s recycling , treatment , o r contro l o f

emissions , whil e th e sam e quantit y ofth e sam e produc ti s produced . (ii ) Pollutio n preventio n measure s ma y includ e substitutio n o f non-toxi c fo rtoxi c feedstock s i n makin g a product ; alteration s t o th e productio n proces s t o reduc e th e volum e o f material s released t o th e environment ; equipmen tmodifications ; housekeepin g measures ; an d in-proces s recyclin g tha t returns wast e material s directl y t o productio n a s ra w materials . (2 ) Th e emissio n reduction efficienc y o f pollutio n preventio n measure s implemente d afte r 198 7 ca n b e use d i n calculatin g th e actua l emission s from a n emissio n poin ti n th e debi tan d credi t equation s i n § 63.15 0 ( 0 an d (g ) o f thi s subpart . (i ) Fo r pollutio n preventio n measures , th e percen treductio n use d i n th e equation s i n paragraph s (f)(2) , (f)(3) , (f)(4) , an d (f)(5 ) o f

thi s section , an d paragraph s (g)(2) , (g)(3) . (g)(4) . an d (g)(5 ) o f thi s section , i s th e percen tdifferenc e betwee n th e monthl y organi c HA PFedera l Registe r / Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 /Conection s 1170 3 emission s fo

r eac h emissio n poin t

afte r th e pollutio n preventio n measur e fo r th e mos t recen t month versu s monthl y emission s fromth e sam e emissio n poin t befor e th e pollutio n preventio n measure , adjuste db y th e volum e o f produc t produce ddurin g th e tw o monthl y periods

. (ii ) Th e followin g equatio n shal l b e use dt o calculat e th e percen t reduction o f apollutio n preventio n measur e fo r eac h emissio n point

.



### E B 

### = Z [(6.0xlO- 8 

### )Q Bi 

### Hnii : Fe^HAPoin ,

i = l - m= l
where : Percen t reduction=Efficiency o

f pollutio n preventio n measur e (percen t organi c HA

P reduction). E B =Monthl y emission s before th e pollutio n preventio n measure , determine da s specifie di n paragrap h (i)(2)(ii ) (A) , (B) , an d(C) of

thi s section

. Epp=Monthl

y emission s afte

r th e pollutio n prevention measure , a s determine dfo r th e mos t

recen t month , detennine d a s specifie di n paragrap h (i)(2)(ii)(C ) o r (D ) o f thi s section

. P B =Monthl y productio n befor e th e pollutio n preventio n measure , durin g th e sam e perio dove r whic h EB i s calculated

. Ppp=Monthly productio n afte r th e pollutio n preventio n measure , a s determine dfo r th amos t recent month

. (A ) Th e monthl y emission s before th e pollutio n preventio n measure , E B , shal l b e determine di n amanne r consisten t with th e equation s an dprocedure s i n paragraph s (f)(2) , (f)(3) , an d(f)(4) o f thi s sectio n fo

r proces s vents , storag e vessels , an dtransfe r

operations

. (B ) Fo r wastewater , E B shal l b e calculate da s follows

. I n paragrap h (i)(2)(ii)(B ) o f thi s section , th e term s wastewate r an dwastewate r

strea mar e use dt o mea n proces s wastewater
. 

### (Ep P

### xPn )

Percent reductio n = • p p 

### •Bxl00 % where : n=Numbe r

of wastewate r

streams
. QHi=Average flow rat e fo r wastewate r

strea m(i ) befor

e th e pollutio n preventio n measure , a s determine db y th e procedur e i n § 63.144(e)(3 ) of

thi s Subpart , liter s pe r minute , befor

e implementatio n o

f th e pollutio n preventio n measure . HBi=Numbe

r o f hour s pe r

mont h tha t

wastewate r

stream(i ) wa s discharge dbefor e th e pollutio n preventio n measure , hour s pe r month

. s=Total numbe r

o f organi c HA

P compound s i n wastewate r stream(i)

. Fe m =Fractio n emitte dof

HAP compoun d(m

) i n wastewate r

fro mTabl e 3 3 o

f thi s Subpart , dimensionless

. HAPm

m=Averag e organi c HAP concentratio n o f compoun d(m

) i n wastewate r

strea m(i) , define dan ddetermine daccordin g t o paragrap h (f)(5)(i) o

f thi s section/befor e th e pollutio n preventio n measure , i n part s pe r millio n b y weight , a s measure dbefor e th e implementatio n ofth e pollutio n measure . (1 ) Value s fo

r Qa i an dHAP Bi mmay b e determine ddurin g an initia l performanc e tes t conducte dunde r

representativ e conditions , o r (2) Value s fo

r Q w ma y b e determine dfro

mrecord s a s specifie di n § 63.144(a ) o f thi s subpart , an dvalue s for HAP B i m ma y b e determine dthroug h proces s knowledg e a s specifie di n § 63.144(b ) o f thi s subpart

. (C) I f th e pollutio n preventio n measur e wa s implemente dprio r t o th e effectiv e dat e of th e reguletion , record s moy b e use dt o determin e E B . (D) Th e monthl y emission s afte r th e pollutio n prevention measure , Epp , ma y b e determine db y testin g o r b y desig n analysi s an ddocumente dengineerin g calculations

. Onc e an emission s t o productio n rati o ha s bee n established , thi s can b e use dt o estimat e monthl y emission s frommonthl y productio n records

. (E ) Fo r wastewater , Ep

p shal l b e calculate dusin g th e followin g equation

. I n paragrap h (i)(2)(ii)(E ) of thi s section , th e term s wastewate r

an dwastewate r

strea mar e use dt o mea

n proces s wastewater
.


### Ep P

### = I [ (6. 0 x IO" 8 

### )Q Ppi 

### Hpp i I FenJiAPpp, TM |

> = ' 1 m= l J 

# m

where : n , Qppj , Hppj , s , Fe m , an dHAP, ^ define dan ddetermine da s ar e describe dabov e unde r th e definitio n o

f E B . excep t

tha t Qppi

. Hppi , an dHAPppi

mshal l b e - determine dafter th e pollutio n preventio n measur e ha s bee n implemented

.1170 4 Federa l Registe r/ Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s P.3 9

(iii ) Al l equations , calculations , tes t procedures , tes tresults , an d othe r infonnatio n use d t o determin e th e percentreduction achieve d b y a pollutio n preventio n measure fo reach emissio n poin tshal l b e full y documented . (iv ) Th e sam e pollutio n preventio n measure ma

y reduc e emission s from multipl e emissio n points . I n suc h cases , th e percentreductio n i n emission s fo r each emissio n poin tmus tb e calculated . (v ) For th e purpose s o f

th e equation s i n paragraphs (g)(2) . (g)(3) , (g)(4) , and (g)(5 ) o f thi s section , use d t o calculate credits for emissio n point s controlle d mor e stringentl y tha

n th e reference technolog y i n paragraph

s (g)(2) , (g)(3) . (g)(4) , and (g)(5 ) of

thi s section , th e nomina l efficiency o

f a pollutio n preventio n measur

e i s equivalen tt

o th e percentreductio n ofth e pollutio n preventio n measure . Whe n a pollutio n preventio n measur

e i s used , th e owne r oroperatoro

f a source i s notrequire

d t o appl y t o th e Directorfo

ra nomina

l efficiency and i s notsubjectt o paragrap h (h ) o f thi s section . TABL E 20.—AVERAG E STORAG E TEMPERA TUR E (Ts ) A S A FUNCTIO N O F TAN K PAIN T COLO R Tan k colo r
Whit e ...... . Aluminum . Gra y Blac k Averag e Storag e Tempera tur e (Ts ) T A M > T A *2 ^ TA+3. 5 TA+5. 0 * T A i s th e averaa e annua l ambien t temperatur

e i n degree s Fahrenheit .
TABL E 21.—PAIN T FACTOR S FO R FIXE D ROO F TANK S Tan k colo r Roo f Shel l Pain t Factors (F p ) pain t conditio n Goo d Poo r White Aluminu m (specular

) White .... . Aluminu m (specular) White Aluminu m (diffuse).. . White Light gra y Mediu m gra

y White Whit e 7.. . Aluminu m (specular

) Aluminu m (specular

) Aluminu m (diffuse

) .. . Aluminu m (diffuse

) .. . Gra y Ugh t gra y — Mediu m gra

y 1.0 0 1.0 4 1.1 6 1.2 0 1.3 0 1.3 9 1.3 0 1.3 3 1.4 0 1.1 5

1.1 8 1.2 4 1.2 9 1.3 8 1.4 6 1.3 8 1.44 1.5 8

TABL E 22:—AVERAG E CLINGAG E FACTOR S (C) *
Liqui d Shel l conditio n Ligh t rust* Dens e rus t G unite line d Gasolin e Singl e componen t stock s Crud e oi l

_ 0.001 5 0.001 5 0.006 0 0.007 5

0.007 5 0.03 0 0.1 5

0.1 5 0.6 0 •Units fo r averag e dirigag e factor s are barrel s pe r 1.00 0 squar e fee L i f n o specifi c informatio n t s available , thes e value s ca n b e assumed to represen t th e mos t commo n conditio n o

f tank s currentl y I n use . TABL E 23.—TYPICA L NUMBE R O F COLUMN S A S A FUNCTIO N O F TAN KDIAMETE R FO R INTERNA L FLOATIN G ROO F TANK S WIT H COLUM N SUPPORTE D FIXE D ROOFS *

Tan k diamete r rang e ( D I n feet ) Typica l numbe r o f columns . (Nc ) 0<D585„ . 65<D 5 10 0 .. . 10 0 < D 5 12 0 .. . 12 0 < D S 13 5 .. . 13 5 < D 5 15 0 .. . 150<DS17 0 .. . 170<D 5 19 0 .. . 19 0 < D 5 22 0 .. . 22 0 < D 523 5 .. . 23 5 < D 5 27 0 ._ 27 0 < D 5 27 5 .. . 27 5 < D 5 29 0 .. . 290<D533 0 .. . 33 0 < D 536 0 .. . 36 0 < D 540 0 . - 1 6 7 8 9 1 6 1 9 2 2 3 1 3 7 4 3 4 9 6 1 7 1 8 1

* Oat a i n thi s tabl e shoul d no t supersed e informatio n o n actua l tanks .P.4 0

Federa l Registe r /

Vol . 58 , No . 3 7 /

Friday , Februar y 26 , 199 3 / Correction s 1170 5

TABL E 24.—EFFECTIV E COLUM N DIAMETE R (F c )

Colum n type F c (feet ) 9-inc h b y 7-Inc h built-u p column s 8-lnch-diameto rpip e column s N o constructio n detail s know n ... . 1. 1 0. 7 1. 0
TABL E 25.—SEA L RELATE D FACTOR S FO R INTERNA L FLOATIN G ROO F VESSEL S Sea l typ e K s Liqui d mounte d resilien t seal : Primar y sea l onl y :
_ Wit h rim-mounte d secondary sea l • :.... . « ;... . Vapo rmounte d resilien t seal : Primary sea l onl y 7 Wit h rim-mounted secondai y seal * 'i f vessel-specifi c infonnatio n i s no t availabl e abou t th e secondar y seal , assum e onl y a primary sea l i s presen t 3. 0 1. 6 6. 7 2. 5

TABL E 26.—SUMMAR Y O F INTERNA L FLOATIN G DEC KFITTIN G LOS S FACTOR S (K F ) an d Typica l Numbe ro f Fitting s (N F ) Dec k fittin g typ e Dec k fittin g loss facto r Typica l numbe ro f fit
ting s (Nr ) Acces s hatc h ; Bolte d cover , gaskete d Unbolte d cover , gaskete d Unbolte d cover , ungaskete d Automati c gaug e floa t wel l

. „ _ „ _ Bolte d cover , gaskete d Unbolte d cover , gaskete d Unbolte d cover , ungaskete d Colum n wel l Buittu p column-slidin

g cover , gaskete d Buittu p column-slidin g cover , ungaskete d Pip e column-flexibl e fabri c sleev e sea l Pip e column-slidin g cover , gaskete d Pip e column-slidin g cover , ungaskete d Ladde rwel l - Slidin g cover , gaskete d Slidin g cover , ungaskete d Roof le g o rhange rwel l Adjustabl e .. _:...... . Fixe d

.. . Sampl e pip e o rwel l Slotte d pipe-slidin g cover , gaskete d Slotte d pipe-slidin g cover , ungaskete d Sampl e well-sli t fabri c seal , 1 0 percen t ope n are a Stu b drain , 1-l n diameter".. ; Vacuu m breake r: „ Weighte d mechanica l actuation , gaskete d Weighte d mechanica l actuation , ungaskete d 1. 6 1 1 b 2 5 5. 1 1 5 »2 8 3 3 c 4 7 1 0 1 9 3 2 (' )

5 6 "7 6 "7. 9 0 «(5+D/10+D 2 /600 )

4 4 5 7 »1 2 1. 2 e (D 2 /125 ) 1 »0. 7 0. 9 •Unit s fo rK P ar e pound-mole s pe ryear . .. . "I f n o specifi c informatio n i s available , thi s valu e ca n b e assume d t o represen t th e mos t common/typica l dec k fitting s currentl y used . cD=Tan k diamete r(feet)

. d No t use d o n welde d contac t interna l floatin g decks

. "Se e Tabl e 23

. TABL E 27.—DEC KSEA M LENGT H FACTORS " (S D ) FO R INTERNA L FLOATIN G ROO F TANK S

Dec k constmctio n Typica l dec k sea m

Continuou s shee t construction ? 5-fee t wid e sheet s
_ . 6-fee t wid e sheets

. 7-fee t wid e sheet s _....__ . «0. 2 0.1 7 0.1 4P.4 1

1170 6 Federa l Registe r / Vol

. 58. : No
. 3 7 /

Friday , Februar y 26 , 199 3 / Correction s
TABL E 27.-T-DEC

X SEA M LENGT H FACTORS " (S D ) FO R INTERNA L FLOATIN G ROO F TANKS—Continue d

Dec k constructio n Typica l dec k sea m

Pane l construction " 5x7. 5 fee t rectangular . 5x1 2 fee t rectangular . 0.3 3 0.2 8 "Dec k 6eamlos s appUe

s to bolte d deck

s only.- Units tor

S u ar e feet pe r squar e fee t « , So=1/W . wher

e Wtshee t widt h (feet) . c l l n o specifi c Informatio n b avaiiabie , thes e factor s ca n b e assume d t o represen t th e mos t commo n bolte d deck s currentl y I n use . 0 So=:(L*W)/LW , where W=pane l widt h (feet) , an d L=pane l lengt h (feet) . TABL E 28.—SEA L RELATE D FACTOR S FO R EXTERNA L FLOATIN G ROO F VESSEL S

Sea ) typ e Welde d vas 7 sel s K s

71.2 ; 0.8 : 

### i 0


### - 2



### . ; 1. 1 0. 8 .0. 7 A 2

- 0. 9 70. 2 N

1. 5 17 2 1. 0 1. 0 0. 9 0 4 2. 3 22 2. 6 Rivete d ves sels

. K s

1. 3 1. 4 0. 2 •N A

. N A N A -NA
N A N A N

. 1 5 1. 2 1. 6 N A

. N A N A N A

. N A

. N A Metalli c sho e seal : Primar y sea l onl y ., . Wit h shoe-mounte d secondar y sea l Wit h rim-mounted secondar y seal. . Uqui d mounte d resilien t seal : Primar y sea l onl y Wit h weathe r shiel d Wit h rim-mounted secondar y sea l Vapo r mounte d resilien t seal : Primar y sea l onl y ;........ . Wit h weathe r shiel d Wit h rim-mounte d secondar y seal. . »NA=Not applicable .

TABL E 29.—ROO F FITTIN G LOS S FACTORS, " KF „ Kn, , AN D M . AN D TYPICA L NUMSE R O F ROO F FITTINGS . N T
Fittin g typ e an d constructio n detail s Los s factors 6 Kr . (tb-mole/yr

) :Krt(!bHnola/(ml

/ br)° > -y r ) m . (dimensionless ) Typica l numbe r o f fittings , '

. Nr
. Acces s hatc h (24-ln-diaroete r well ) .... . Bolte d cover , gaskete d Unbolte d cover , ungaskete d Unbolte d cover , gaskete d .....;... . Unslotte d guide-pol e wel l (8-in-diamete r unstotted pola , 21-ln-diamsle r well) . Ungaskete d slidin g cove r .... . Gaskete d slidin g coye r .......:..... . .. . Slotte d gukJa-pola/sampl e wel l (8-hvdiamete r unslotted pole . 21-Jn-dlamete r well) . Ungaskete d slidin g cover , withou t float Ungaskete d slidin g cover , wit h floa t : Gaskete d slidin g cover , withou t floa t 'Gaskete d slidin g cover , wit h float r . Gauge-float wel l (20-ihc h diameter) Unbolte d cover , ungaskete d Unbolte d cover , gaskete d Bolte d cover , gaskete d :... ; Gauge-hatch/sampl e wel l (8-inc h diameter ) ........ . , Weighte d mechanica l actuation , gaskete d Weighte d mechanica l actuation , ungaskete d Vacuu m breake r (10-inch-diamete r well ) Weighte d mechanica l actuation , gaskete d Weighte d mechanica l actuation , ungaskete d Roo f drai n (3-Inc h diameter) ... ; Ope n 9 0 percen t ciose d Roo f le g (3-inc h diameter) Adjustable , pontoo n are a Adjustable , cente r are a
_ _ 0 2. 7 2. 9

.5 025 0

7. 1 0.4 1 0 0

0 0 0 0 2. 3 2. 4 0 0.9 5 0.9 1 \2 \2
0 0.5 1 6. 7

3. 0

310 2 9 26 0 8. 5 5. 9 0.3 4 0 0.1 4 2. 4 0.1 7 3. 0
7. 0 0.8 1 0.2 0 0.0 6 ( c ) 0

1. 0 1. 0 0.9 8 ( c )
1.2 2. 0 \2 2 4 ( c )1 0 1. 0 0 ( c )i o 1. 0 ( c )i o 1. 0

i o 

# n

N « (Table-30)

.
Nr r (Table-30) . ( c )1 4 N m (Table-310 . «1. 0 «1. 0

### Federa l Registe r / Vol . 58 , No . 3 7 /

Friday , Februar

y 26 , 199 3 /

Correction s 1170 7
TABL E 29.—ROO F FITTIN G LOS S FACTORS,»:KF»I W AN D M * AN D TYPICA L NUMBE R O F ROO F FITTINGS , NT-rContJnue d

Rttin g typ e an d constructio n detail s

Fixe d

Fixe d „ Ri m ven t (6-Inc h diameter ) 7 Los s factors " KF

. (Ib-mole/yr )

. 0 1. 7 0.4 1 0.4 1 0
0.7 1 0.6 8 KFb(U>mole/Imi /

hr)»-yr ) 0.0 6

. 7 0 0 0 0
0.1 0 1. 8 m (dimensionless )

0 '-.;oooo

c 1. 0 1. 0 Typica l numbe ro f fittings ,

N r

N r a (TabkH310
-

'«1

.
•Th e roo f fittin g loss factors , KF. , Kn> , an d m , ma

y onl y b e use d fo r win d speed s fro m 2 t o 1 5 miles pe r hour .

- " Uni t abbreviation s ar e a s follows : to=pouRd; mi=miles ; hr=hour ; yrs=year . «l f n o specifi c informatio n i s avaiiabie , thi s valu e ca n be assume d t o represen t th e mos t commo n o r typica l roo f fitting s currentl y i n use . ' A slotted guide-pole/sampl e wel l i s a n optiona l fittin g an d i s no t typicall y used . • Roo f drain s tha

t drai n exces s rainwate r Into th e produc t ar e no t use d o n pontoo n floatin g roofs . The y are , however , use d o n double-dec k floating roof

s an d ar e typicall y lef

t open . 'Th e mos

t commo n roo

f le g diamete r i s 3 inches . Th e loss factor s fo r Vh Inc h cfiamete r roo

f leg s are provided fo r us e I f thi s smatle r siz

e roo f I s use d o n a particula r floating roof . . . t

. « Rimvent s ar e use d onl y with ; mechanical-shoe primar y seals .
; TABL E 30.—TYPICA L NUMBE R O F VACUU M BREAKERS , NF S AN D ROO F DRAINS, " N n Tan k diamete rD (feet)' *
5 0

10 0 15 0 20 0 250 300 35 0 40 0 No

. o f vacuu m breakers , N »

Pontoo n roo f 1

1 2 3 4 5 .6

. 7 Double-dec k roo f 1

1 2 2 3 3
' 4 4 No

. o f roo f drains , N n (double
dec k roof) c
1

1 2 3 5 7 d d •TThi s tabl e shoul d no

t supersed e Informatio n base d o n actua l tan k data . : "I f th e actua l diamete r i s betwee n th e diameters.Isted , th e closes t diamete r liste d shoul d b e used : I f th e actua l diamete r I s midwa y betwee n th e diameter

s listed , th e nex

t large r cfiamete r shoul d b e used . : c Roo f drain s that drai n exces s rainwate r int o th e produc t ar e ho t use d o n pontoo n floatin g roofs . They are , however , use d o n double-dec k floating roofs , an d ar e typicall y lef t open . "Fo r tank

s mor e tha n 30 0 feet I n diameter , actua l tan k dat a o r th e manufacturer' s recommendation s ma y b e neede d fo r th e numbe r o f roo f drains . . ; •. \

Tan k diamete rD (feet) *
3 0

4 0 5 0 1 6 0 7 0 8 0 , 9 0 10 0 11 0 i 12 0 : 13 0 • 14 0

. 15 0 7 16 0 17 0

, 18 0 7 19 0 20 0 7 21 0

- r22 0 23 0 TABL E 31;—TYPICA L NUMBE R O F ROO F LEGS, " N r a Pontoo n roo f No

. o f pontoo n leg s 4 4 6 9 1 3 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 3 2 6 2 7 -...2 8 2 9 30 ; 7 3 1 i 3 2 : . 3 3 N a o f cente rleg s 2 4 6 7 9 1 0 1 2 1 6 2 0 2 4 2 8 3 3 3 8 4 2 4 9 5 6 6 2 6 9 7 7 > 8 3 9 2 No

. o f leg s o n double-dec k roo f
6 7 8 1 0 1 3 1 6 2 0

- -...•• ' 2 5 2 9 3 4 4 0 4 6 • 6 2
• . /6 8 6 6 ..-,:,'..7 4 8 2 y 9 0

. 8 8 10 7 11 6

### 1170 8 FederalRegiste r / Vol

. 58 , No
. 3 7 /Friday , Februar y 26

. 199 3 /

Correction s

Tan k cfiamete rD (feet) *

24 0 25 0 26 0 27 0 28 0 290 30 0 310 32 0 33 0 34 0 35 0 36 0 37 0 380 39 0

. 40 0 TABL E 31.—TYPICA L NUMSE R O F ROO F LEGS, " N F «—Continued
Pontoo n roo f No

. o f pontoo n tegs 3 4
' 3 4 36

. 3 6 3 7 3 8 3 8 3 9
• 3 9 4 0 4 1 4 2 4 4 4 5 4 6 4 7 4 3 No

. o f cente rtegs 10 1 10 9 11 8 12 8 13 8 14 8 15 8 16 8 17 9 19 0 20 2 21 3 22 6 23 8 25 2 25 6 28 1 No

. o f leg s o n double-dec k roo t

12 7

. 13 8 14 9 16 2 17 3 18 6 200 21 3 22 6 24 0 25 5

. . 27 0 28 5 300 31 5 330 34 5

* Thi s tabl e shoul d mo t supersed e informatio n ba-sed'o n adaa ! lan k data

. * « th e actua l diamete rI s betwee n th e diameter s listed , ih a closes t diamete rliste d shoul d b a used

. I f m e actua l diamete rI s midwa y betwee n th e diameter s listed , tfw oext.large rdiamete rshoul d b a used

.
TABL E 32.—SATURATIO N FACTOR S Carg o car rier Tan k truck s : an d rail
' lank cars .

• ' Mod e o f operatio n

Submerge d loadin g o f a dea n carg o tank

. Submerge d loading : dedicate d noima l

. service

. Submerge d loading : dedicated , vapor

toal-

'"" ' arvce ' service

. Splas h loadin g o f a dear i carg o tank

. ' " Splas h loading : dedi
cate d nonria l serv : • - • fee'. Splas h loading : dedi
cate d vapo rbalanc e service

. S fac
to r 0.5 0

0.8 0

1.0 0

. L4 5 1;*»S

1.0 0 TABL E 33.—FRACTIO N REMOVE D (Fr ) FO A

HA P COMPOUND S I N WASTEWATE H STREAMS—Continue d TABL E 33.—FRACTION " REMOVE D (Fr ) FO A HA P COMPOUND S I N .WASTEWATE R STREAMS—Cont i nue d

TABL E 33.—FRACTIO N REMOVED' • (Fr ) FO R HA P COMPOUND S I N WASTEWATER " STREAM S Chemica l nam e Acetaldehyd a Acetonitril e -. Acstophenori e Acrolei n Acryksnitril a Ally ! chlorid e Anilin e Benzen e Benzy l chlorid e Bipheny l Bromofor m 1,3-Butadien e Carbo n disulfid e Carbo n tetrachlorid e ... . 2-Chloroacetophenon e Qtlorobenzen e Fr
1.00 0 0.93 4 0.92 0 0.95 7 0.96 0 1.00 0 0,46 8 1.00 0 1.00 0 1.00 0 1.00 0 1.00 0 1.00 0 1.00 0 0.93 9 1.00 0 Chenscalnam a

CWorofon n Chloroprene ' ( 2 -Chloro-1.3-8uta
diane )

. ' o-Oreso l Cumen e (isopropy l benzene ) 1,4-DicfrtiorobBnzene(p ) 7.....

. •Dichloroethy l ethe r 1.3-Dk£>k*r©propen e ..„ . N.N-Dimsttiyianilin e Oiethy t sulfate

. . ... . S.S'-DimsthylbenzJdin e Ll-Oimelhylhvdrazin s .-...:. 7 :.. '
• Dimethy l sulfat e 2,4-Dimirophsno l : 2.4^lnitroto!uen e : 1.4^Dioxaria.(L4-Oieihy1eneoxlde )

. Epichtorohydrin ( 1 -Chloro-2.3
- ' epoxypropane ) ; Ethy l acrylat e :•.. ; Ethylbenzen e .;..... . Ethy l chlorid e (Chloroethana ) Ethylen e dibromid e Ethylen e dichlorid e - . (1.2
- Dichloroelhane )

_ Ethylen e oxid e .........'.;.'.....

. 7..

. Ethyliden e dichiorid a (1.1
- Dichloroeihane ) ...;..„.:. : Diethylen e glyco l dimethy l ethe r... . Ethylen e glyco l monomethy l ethe r acetat e ; Ethylen e glyco l dimethy l elhe r...... . Diethylen e glyco l diethy l ethe r Ethylen e glyco l monobuty l ethe r acetat e : Ethylen e glyco l monoethy l ethe r acetat e _..:: : HexachkHobehzen e Hexachlorobutadien e ......Y:Y Hexachloroethan s Hexan e ;.- . Isophoron e ...7.

. AY. F r 1.00 0 LOW ) 0.44 8 LOO O 1.00 0 0.93 5 LOO O 0.92 7 0.81 4 0.63 5 0.44 8 0.69 7 0.90 8 0.62 6 0.78 7 0.69 0 0.98 1 1.00 0 1.00 0 1.00 0 LOO O 1.00 0 1.00 0 0.42 5 0.52 9 0.94 3 0.52 3 0.92 7 0.47 0 1.00 0 LOO O 1.00 0 1.00 0 0.94 5 Chemica l nam e

Methano l

.... ; ;...- . Methy l bromid e (Bromomethahe)..

. Methy l chlorid e (Chtoromelhane )

.. . Methy l chlorofor m (1,1,1
- Trichloroelhane ) Methy l ethy l keton e (2-Butanone )

. . Methy l Isobuty l keton e (Hexone)...

. Methy l methacrylat e ........... : Methy l Jert-outy l ethe r.......... : Methylen e ' chlorid e

. (DichJoromalhane},:... . Naphthalen e ... . Nitrobenzen e 2-Nitropropan a Phosgen e .- . Propidnaldehyd a , . Propylen e dichlorid e (1,2-Dlchlo
ropropane ) Propylen e oxid e Styren e ........; . „... . 1.1.2.2-Tetrachtoroe1han e TetracMoroelhyien e (PerchloroeJhylerie ) Toluen e „:..;„'_.... ' ;.. : o-Toluidine;..~

. 1.2.4-Trichlorobenzen e 1.1.2-Trichlbroethan e Trichloroethylen e 2,4,5-Trichloropheno l Triethytamin e ..... . ; 2,2,4:Trimeihy1pentan e Viny l acetat e ..-.'.. ..........:,....... . Viny l chlorid e ....... : Vinyliden e . chlorid e (1,1
- Dichloroethylene )

.... : m-Xylen e :....... : o-Xylen e ........ 7 p-Xyten e ...:..+<......... F r 0.82 9 1.00 0 i.ooo LOO O LOO O 1.00 0 0.95 8 LOO O LOO O LOO O 0.93 6 LOO O 1.00 0 0.95 2 LOO O LOO O 1.00 0 LOO O LOO O 1.00 0 0.48 7 1.00 0 1.00 0 1.00 0 0.91 4 1.00 0 1.00 0 1.00 0 1.00 0 LOO O 1.00 0 i.oo o 1.00 0P. 1



# OAR Box 1252 Prepped by Candice Davis



## Document

Number: 

# 71 ) FE D RE G VOL . 58 , NO . 3 7 2/26/9 3 Docket Number: 

# A-90-2 2

Printed 5/21/2008 3:16:16

PM Sheet 71 of 184

## .y&r<j9W l Al e A'90'3d 

# H0tt Docfcer s A'^D'ZZ^ P. 2

Federa l Registe r

/ Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 / Correction s 

### 1170 9 ENVIRONMENTA

L PROTECTIO

N AGENC Y 40 CF R Par

t 6 0 [AD-FRL-4534-4

] Standard s o f Performanc e fo rNe w Stationar y Sources ; Appendi xA—Tesf l Methods ; Revision s t o Method s 1 8 an d 2 6 an d Additio n o f Metho d 26 A t o Appendi xA Correction I n propose drul e documen t 92-2829 3 beginnin g o n pag e 6279 8 i n th e issu e o f Thursday , Decembe r

31,1992 , variou s portion s o f

th e documen t

wer e illegibl e an dsevera l illustration s wer e incorrectl y publishe da t th e en do f

th e document

. Fo r

clarification , th e propose drul e i s reprinte dbelow

. Also , th e F RDocumen t

numbe r appearin g a t th e en do f

th e documen t

i s correctl y note dabove

. SUMMARY

: Th e purpos e o f

thi s actio n i s t o propos e revisions t o Metho d18 , "Measuremen t

o f Gaseou s Organi c Compoun dEmission s b y Ga s Chromatography " an dt o Metho d26 , "Determinatio n o f

Hydroge n Halid e an d Haloge n Emission s fromStationar y Sources—Midge t

Impinge r

Method, " an dt o propos e th e additio n o f Metho d 26A , "Determinatio n o f Hydroge n Halid e an dHaloge n Emission s fro m Stationar y Sources—Isokineti c Method, " t o appendi x A o f 4 0 CF Rpar t 60

. Propose dregulations publishe di n a separat e announcemen t unde r 4 0 CF R par t 6 3 entitle d"Nationa l Emissio n Standard s fo r

Organi c Hazardou s Ai r Pollutant s fro mSyntheti c Organi c Chemica l (SOCMI ) Industry, " includ e testin g requirement s fo r hydroge n halide s an dhalogen s afte r incineratio n contro l devices

. Metho d1 3 i s bein g revise dt o clarif

y th e phras e "engineerin g judgment " a s i t relates t o choosin g asamplin g methodology

. Metho d2 6 fo r

anisokineti c determinatio n o f

hydroge n chlorid e emission s i s bein g revisedt o ad d provision s fo r

determinin g emission s o f othe r hydroge n halide s an dhalogens

. Metho d26 A i s bein g propose da s a n isokineti c versio n o f

Metho d26

. A publi c hearin g wil l b e held , i f requested, t o provid e intereste dperson s a n opportunit y fo r

ora l presentatio n o f data , views , o r

argument s concernin g th e propose dtes t

methods

. DATES : Comments. Comment s mus t b e receive do n o r

befor e Marc h 31,1993

. Public Hearing. I f

anyon e contact s EP A requestin g t o spea k a t apubli c hearin g b y Januar y 21,1993 , apubli c hearin g wil l b e hel do n Februar y 10 , 199 3 beginnin g a t

1 0 a.m . Person s intereste di n attending-th e hearin g shoul dcal l th e contac t

mentione dunde r ADDRESSE

S t o verif y tha t ahearin g wil l b e held

. Bequest to Speak

at Hearing. Person s wishin g t o presen t

ora l testimon y mus t contac t EP A b y Januar y 21,1993

. ADDRESSES : Comments. Comment s shoul db e submitte d(i n duplicat e i f possible ) to : Ai r

Docke t Sectio n (LE

131) , Attention : Docke t Numbe r A-90

- 19 , U
. S

. Environmenta l Protectio n Agency , 40 1 M Street , SW. , Washington , D C 20460. ' Public Hearing. If

anyon e contact s EP A requesting apubli c hearing , i t wil l b e hel da t

EPA' s Emissio n Measuremen t Laborator y Building , Researc h Triangl e Park , Nort h Carolina

. Person s intereste d i n attendin g th e hearin g o r wishin g t o presen t ora l testimon y shoul dnotif y Robi n R
. Segall , Emissio n Measuremen t Branc h (MD-19) , Technica l Suppor t Division , U.S

. Environmenta l Protectio n Agency , Researc h Triangl e Park , Nort h Carolin a27711 , telephon e (919 ) 541

- 0893

. Docket. Docke t

No
. A-90-19 , containin g material s relevan t t o thi s rulemaking , i s availabl e fo r publi c inspectio n an dcopyin g betwee n 8 a.m . an d3:3 0 p.m. , Monda y throug h Friday , a t EPA' s Ai r

Docket , roo mM-1500,1s t Floor , Watersid e Mall , 40 1 M Street , SW.

. Washington , D C 20460

. A reasonabl e fe e ma y b e charge dfo r copying

. FO RFURTHE RINFORMATIO

N CONTACT

: Terr y Harriso n o r

Robi n R
. Segall , Emissio n Measuremen t Branc h (MD

19) , Technica l Suppor t

Division , U.S

. Environmenta l Protectio n Agency , Researc h Triangl e Park , Nort h Carolin a 27711 , telephon e numbe r (919 ) 541

- 5233

. SUPPLEMENTAR Y INFORMATION : I
. Th e Rulemakin g Metho d1 8 wa s develope dfo r an di s currentl y applicabl e t o th e speciatio n o f tota l gaseou s organic s i n asampl e t o determin e emission s o

f individua l organi c compounds

. I n response t o question s fro

mindustr y representatives seekin g t o us e th e metho dfo r complianc e demonstrations , th e EP A i s proposin g t o clarif

y th e phras e "engineerin g judgment " a s i t relates t o choosin g asampling an danalytica l methodology

. In th e propose drevision , a n owne r o r operato r wil l perfor

ma laboratory evaluatio n o

f th e methodolog y chose n t o sampl e an d analyz e th e compound s of interest

. Thi s evaluatio n woul db e use dt o characteriz e th e effectivenes s of th e methodolog y an dcorrec t

fo r an y inefficienc y i n th e chose n technique

. Unde r subpar t G of par t 63 , EP A i s proposin g standard s t o limi t emission s of halide s an dhalogen s from incineratio n o r

contro l o f

halogenate d organi c ven t

stream s a t

SOCM I facilities

. Metho d2 6 currentl y prescribe s onl y measuremen t

of hydroge n chlorid e emission s wit h samplin g a t aconstan t rate
. Th e revision s bein g propose dtoda y wil l expan dth e method' s applicabilit y t o othe r hydroge n halide s an dhalogens

. Th e additio n o

f Metho d26 A wil l provid e a n alternativ e t o th e revise d Metho d2 6 an dwil l allo w fo r isokineti c samplin g of

ga s stream s tha t

ar e saturate dwit h moisture

. Metho d2 6 wa s develope dfo r an di s currentl y applicabl e t o determinin g hydroge n chlorid e emission s fro m municipa l wast e combustors

. Method s simila r t o Metho d2 6 an dMetho d26A wer e develope dfo

r th e measuremen t

p f hydroge n chlorid e (HCl) an dchlorin e (CI2 ) i n emission s fromhazardou s wast e incinerator s and.boiler s an dindustria l furnace s burnin g hazardou s wast e (5 6 F R32728 , Jul y 17,1991)

. Applicatio n o f ametho dt o asourc e wit h emissio n characteristic s "similar " t o thos e unde r whic h i t wa s validate di s addresse di n sectio n 1 2 of

propose dMetho d301 , "Fiel dValidatio n o f

Emissio n Concentration s fro

mStationar y Sources " (5 6 F

R27370 , Jun e 13,1991)

. Th e Agenc y ha s compare dth e characteristic s of

incinerate dSOCMI proces s ven t

gase s t o emission s fro

m municipa l wast e combustor s an d hazardou s wast e incinerator s an dplan s t o waiv e th e Metho d30 1 validatio n requirement s fo

r applyin g th e : methodolog y develope dfo r wast e incinerator s t o th e incinerate dSOCMI ven t gases . Th e Agenc y believe s tha t th e sampl e ga s matrice s fromincinerate d SOCM I proces s ven t

gase s ar e simila r

t o thos e of wast e incinerator s an dd o no t contai n interference s tha t woul d warran t avalidatio n ofth e methodolog y fo r measuremen t

of HC l o r (CI2 ) emission s fromthi s source . Thi s initia l opinio n i s based , i n part , o n th e relativ e insensitivit y ofth e methodolog y t o interference s expecte di n th e SOCMI exhaus t ga s streams
. Th e revision s t o Metho d2 6 a s wel l a s Metho d26 A als o exten dth e applicabilit y ofth e methodolog y i n Metho d2 6 an dth e HCl/fCl J method s develope dfo

r hazardou s wast e incinerator s an dboiler s an dindustria l furnace s burnin g hazardou s wast e t o measuremen t

o f hydroge n bromid e (HBr) , hydroge n fluorid e (HF) , an d bromin e (Br2 )

. Th e applicabilit y extensio n i s base do n limite ddat aan d th e expecte dsimila r

behavio r o f thes e compound s t o HC l an d(Cl 2 ) i n regar dt o samplin g an danalytica l procedures

.Becaus e o

f it s extrem e reactivity, fluorine (F J shoul d no tb e presenti n th e sampl e matri

x and i s no taddresse d b y th e methods . Iodin e (I2

) and hydrogen iodid e (HI

) ar e als o no t covere d by th e method s becaus e few , if any , of tho orga n le s controlle d b y th e SOCM I proces s ven tincinerators wil l tcontai n th e iodin e io n and , additionally , ther e ar e n o know n dat

a t o suppor t measuremen

tof h and H I with thi s technique . Th e Agency intend s t

o asses s th e method s further, prio rt

o promulgation , throug h laborator

y and field evaluations . A stud y i s underwa y concernin g th e potential negativ e bia s i n Method 26A a

tHC l level s belo w 2 0 ppm ; specifically , th e stud y i s determinin g th o nee d forreplacin g certain glas s component s i n th e samplin g trai

n with Teflon

® t o reduce surfac e adsorptio n effects . Anothe r study i s planne d t o addres s sampl e stability , particularly i n regar d t o th e specie s created b y hydrolysi s o f th e halogen s i n th o alkalin e solutio n i n th e samplin g train . Finally , a laborator y and Hel d evaluatio n o

f Metho d 26A wil l b e conducte d t o asses s th e bia s and precisio n o f

th e metho d forth e targe

t analytes . T o assis ti n it s assessment , th e Agency solicit s comment s o n availabl e information o n th e propose d methodology . Specifically , th e Agency solicit s comment s with supportin g dat a t o betterdefin e th e compound s present i n th e ga s matrice s whic h may , fo rth e hydrogen halide s an d halogen s specifie d i n th e methods , (1 ) b e analytical interferences , (2) interfere with thei rquantitativ e collectio n i n th e impinge r solutions , or(3 ) affec tsampl e stability . Comment

s shoul d b e addresse d t o th e Ai rDocketliste d i n th e ADDRESSE

S section. II . Administrativ e Requirements A. Public Hearing . A publi c hearin g wil l b e held , if requested , t o discus s th e propose d rul e i n accordanc e wit h sectio n 307(d)(5 ) o f th e Clea n Ai rAct . Person s wishin g t o mak e ora l presentation s shoul d contact EP A a tth e addres s give n i n th e ADDRESSE

S sectio n o f

thi s preamble . Ora l presentation s wil l b e limite d t o 1 5 minute s each . An y memberofth e publi c ma

y fil e a writte n statementwith EP A before , during , o rwithi n 3 0 day s afte r th e hearing . Writte

n statements shoul d b e addresse d t o th e Ai rDocket addres s give n i n th e ADDRESSE S sectio n of thi s preamble . A verbatim transcrip tof

th e hearin g and writte n statements wil l b e availabl e fo r publi c inspectio n an d copyin g durin g norma

l workin g hour s a

tEPA' s Air Dccks tI

n Washington , D

C (se e ADDRESSE

S sectio n o

f thi s preamble) . B. Docket Th e docke

ti s a n organized and complet e fil e of

al l th e information submitte d t

o o rotherwis e considere d by EP A i n th e developmen to

f thi s propose d rulemaking . Th e principal purpose s ofth e docke

tare : (1 ) T o allo w intereste d parties t o identif y and locate documents s o tha

tthe y ca n effectivel y participat e i n th e rulemaking proces s and (2) t o serve a s th e recor

d i n cas e of judicial review (excep tfo rinteragenc

y revie w materials ) (sectio n 307(d)(7)(A)) . C . Office of

Management

and Budget Review 1 . Paperwor

k Reductio n Act . Thi s rul e doe s notcontai n an y information collectio n requirement s subjectt o OM B review underth e Paperwor k Reduction Ac

to f 1980,4 4 U.S.C . 350 1 et

seq. 2 . Executiv e Orde

r1229 1 Review . UnderExecutiv e Orde

r12291 , EP

A mus tjudge whethe ra regulation i s "major " and , therefore , subjec tt o th e requiremen

to f a regulator

y impac t analysis . Th e proposa

l o f thes e tes t method s i s notmajo

rbecaus e i twil l hot hav e a n annua l effec to n th e economy o f $10 0 millio n o

r more ; itwil l no t resul ti n a majo

rincreas e i n cost s o

r prices ; an d ther e wil l b e n o significant advers e effect

s o n competition , employment , investment , productivity , innovation , o

ro n th e abilit

y o f U.S. - base d enterprise s t o compete with foreign-based enterprise s i n domesti c o r exportmarkets . Thi s rulemaking wa s submitte d t

o th e Offic

e o f Managemen

t and Budge

t(OMB ) fo rrevie w as required b

y Executiv e Orde

r12291 . D. Begulatory Flexibility Act Compliance Pursuan tt o th e provision s o

f 5 U.S. C 605(b) , I hereby certif

y tha tthi s attache d rule , i f promulgated , wil l no thav e a n economi c impac

to n smal l entitie s becaus e n o aaditional cost s wil l b e incurred . Listo f Subject s i n 4 0 CF RPar t6 0 Ai rpollutio n control . Intergovernmenta

l relations, Reporting and recordkeepin g requirements , and Syntheti c organic chemical manufacturing . Dated : Octobe

r 29,1992 . Willia m K . Reilly.

. Administrator. Forth e reasons se tou ti n th e preamble , par

t60 , titl e 4 0 of

th e Code of

Federa l Regulation s i s propose d t o b e amende d a s follows : 1 . Th e authorit

y citatio n fo

rpar t6 0 continue s t o read as follows : Authority : Sees . 101 . Ill , 114.116 . 301 . Clea n Ai r Ac ta s amende d (4 2 U.S. C 7401 . 7411,7414,7416.7601) . Appendi x A (Amended ] 2 . I n appendi x A , Metho d 1 8 i s propose d t o b e amende d b y addin g paragrap h (c) t o sectio n 3 and b y revisin g section s 7.4.4. 1 an d 7.4.4. 5 and b y addin g sectio n 7. 6 t

o rea d as follows : Metho d 18—Measuremento f Gaseou s Organi c Compound Emission s b y Ga s Chromatography 3. Precision and

Accuracy * * * * * ' * (c) Recovery . Afte

rdevelopin g a

n appropriat

e samplin g and analytical syste m fo rth e pollutant s p

f interest , conduc tth e procedure i n sectio n 7.6 . Submitth e dat

a and result s of

th e recover y procedure with th e reporting o f result s unde rsectio n 7.5 . 7.4. 4 * * * 7.4.4. 1 Determin e th e recovery efficiency o f

th e pollutant s o

f interes t accordin g t o sectio n 7.6 . 7.4.4. 2 •»'*• * 7.4.4. 3 * • • • 7.4.4. 4 * * • 7.4.4. 5 Calculations . Al l calculation s ca n b e performed accordin g t o th e respectiv e NIOSH method . Correc tal l sampl e volume s t

o standar d conditions . I

f a sampl e dilutio n syste m ha s bee n used , multipl y th e results b y th e appropriat

e dilutio n ratio . Correc

tal l result s accordin g t

o th e procedure i n sectio n 7.6.3 .

7. 6 Recover

y Study . Afte rconductin g th e presurvey an d identifyin g al l of th e pollutant s o f

interest , assembl e (i n th e laborator

y oron-site ) th e samplin g and analytical syste m t o b e use d i n conductin g th e sourc e test . 7.6. 1 Obtain a certifie d gaseou s standar d (orprepar

e a gaseou s standar d a s describe d i n sectio n 6.2. 1 or6.2.2 ) containin g al l of th e pollutants o f

interes tpresen ti n th e sourc e ga s strea

m a tth e leve l o f

th e standar d (±1 0 percent) . I

f complyin g with a n efficienc y standard (determinin g th e percen tefficienc y o f a contro l device) , th e concentratio n o f each targe

tpollutan ti n th e standar d shal l b e a tth e leve l o f

th e outle tt o th e control devic e (±1 0 percent) .Federa l Registe r 7 Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 7 Correction s 1171 1 P. 4

7.6. 2 I f an integrate dba g sampling syste mi s t o b e use dat

th e sourc e (sectio n 7.1) , follo w th e procedur e specifie di n sectio n 7.6.2.1

. I f adirec t interfac e (sectio n 7.2 ) o r

adilutio n interfac e (sectio n 7.3 ) samplin g an d analysi s procedur e i s t o b e use da t th e source , follo w th e procedur e i n sectio n 7.6.2.2

. I

f a n adsorptio n tub e procedur e (sectio n 7.4 ) i s t o b e use d a t th e source , follo w th e procedur e i n sectio n 7.6.2.3

. 7.6.2. 1 Set

u p th e samplin g syste m includin g an y conditionin g syste m an don e of

thre e samplin g bag s exactl y a s i t

woul db e assemble da

t th e source . Attac h th e gaseou s standar dat

th e inle t t o th e samplin g syste m(i.e. , th e ti p ofth e samplin g probe)

. Sampl e th e gaseou s standar d exactl y a s yo u woul dextrac t asampl e fromth e source . Analyz e th e standar d sampl e a s th e sourc e sampl e woul db e analyzed

. Repea

t thi s procedur e thre e time s (sampl e an danalyz e thre e separat e ba g samples)

. 7.6.2. 2 Set

u p th e on-lin e GC , sampl e line , an dan y sampl e conditionin g system s exactl y a s the y woul db e a t th e sourc e (i

f usin g adilutio n interfac e samplin g system , se t u p th e hea t trac e an ddilutio n syste ma s the y woul db e at

th e source)

. Attac h th e gaseou s standar da

t th e inle t t o th e samplin g syste m(i.e. , th e ti p ofth e samplin g probe)

. Sampl e th e gaseou s standar dexactl y a s yo u woul dextrac t asampl e fromth e ga s streamo f th e source . Analyz e th e standar da s th e sourc e ga s woul db e analyzed

. Repea t thi s procedur e thre e time s (sampl e an danalyz e thre e standar dsamples)

. 7.6.2. 3 Assembl e th e samplin g syste m exactl y a s i t

woul db e se t

u p a t th e source , usin g th e sam e amount s an d numbe r o f adsorptio n tube s a s thos e t o b e use dat

th e source . Attac h th e gaseou s standar da

t th e inle t t o th e samplin g trai n (i.e. , th e ti p o f th e samplin g probe)

. Sampl e th e standar d at th e flo w rat e an dsamplin g time s t o b e use dat

th e source . Desor

b an d analyz e th e adsorben t

tube s i n th e laboratory usin g th e procedure s t o b e applie dt o th e sourc e samples

. Repea t thi s procedur e thre e times

. 7.6. 3 Calculations

. Th e relativ e standar ddeviatio n ofth e thre e result s fo r eac h pollutan t

o f interes t shal l b e £1 0 percent
. Calculat e th e theoretica l concentratio n fo

r eac h compoun d base do n standar dconcentration , tim e sampled(i

f usin g adsorben t

tube s o r bags) , an dflo w rat e ofth e gas . Calculat e th e measure dconcentratio n o f eac h compoun dbase do n th e analytica l results

. Calculat e fractio n recoveredb y dividin g measure d concentratio n b y theoretica l concentration

. Th e averag e fraction recovered(ofth e thre e runs ) shal l b e 20. 7 an d£1.3 0 fo

r eac h compoun dof interest

. I f averag e fractio n recovered <0. 7 o r >1.3 0 fo r aparticula r compound , th e samplin g an d analytica l technique s ar e no t acceptabl e fo

r tha t compound

. I

f th e averag e fractio n recovere di s 20. 7 an d £1.3 0 fo r acompound , correc t

al l of th e result s fromth e sourc e tes t before submittin g th e dat ab y dividin g sourc e concentratio n b y th e averag e fraction recovere dfo

r eac h compound

. ft « * o ft 3

. It i s propose dtha t

Metho d2 6 of

4 0 CF Rpar t 60 , appendi x A b e amende db y revising th e title ; b y revising section s 1.1 , 1.2,1.3,1.5,1.6 , 2.1.3 , th e first sentenc e o

f 2.1.4 , 2.1.5 , 2.2.2 , th e headin g o f sectio n 3.1.2 , section s 3.1.3 , 3.2.2 , 3.2.3 , 4.1.1 , 4.2 , 4.3 , 4.4.2 , 4.4.3 , 5.2 , 7.2 , 7.3 , 7.4 ; b y revising Figur e 26

- 1 ; an db y addin g references 4 an d5 t o sectio n 8 t o rea da s follows : Appendi x A—Tes t

Method s Metho d26—Determinatio n of Hydroge n Halid e an dHaloge n Emission s Fro m Stationar y Sources—Midge t Impinge r Metho d 4 ft ft ft 1. 1 Applicability

. Thi s metho di s applicabl e fo

r determinin g emission s o f hydroge n halide s (HX

) [hydroge n chlorid e (HCl) , hydroge n bromid e (HBr) , an dhydroge n fluorid e (HF) ) an dhalogen s (X

2 ) [chlorin e (Cl 2 ) an d bromin e (BrJ ] fromstationar y sources . Sources , suc h a s thos e controlle db y we t

scrubbers , tha t

emi t aci dparticulat e matte r

mus t b e sampledusin g Metho d26A

. [Note : Mentio n of

trad e names o r

specifi c product s doe s no t constitut e endorsemen t

b y th e Environmenta l Protectio n Agency. ) 1. 2 Principle

. A n integrate dsampl e i s extracte dfromth e sourc e an dpasse d throug h dilut e sulfuri c aci dan ddilut e sodiu mhydroxid e solution s whic h collec t th e gaseou s hydroge n halide s an dhalogens , respectively. Th e hydroge n halide s ar e solubilize di n th e acidi c solutio n an dfor mchlorid e (CI") , bromid e (Br~) , an dfluoride (F~ ) ions

. Th e halogen s hav e avery lo w solubilit y i n th e acidi c solutio n an dpas s throug h t o th e alkalin e solutio n wher e the y ar e hydrolyze dt o for maproto n (

H + ) , th e halid e ion , an dth e hydrohalou s aci d(HCIO o r HBrO)

. Th e halid e ion s i n th e separat e solution s ar e measure db y io n chromatograph y (IC)

. 1. 3 Interferences

. Volatil e materials , suc h a s chlorin e dioxid e (ClOj ) an d ammoniu mchlorid e (NH4CI) , whic h produc e halid aion s upo n dissolutio n durin g samplin g ar e potentia l interferents

. Interferent s fo r th e halid e measurement s ar e th e haloge n gase s whic h disproportionat e t o ahydroge n halid e an dahydrohalou s aci dupo n dissolutio n i n water
. Th e us e of acidi c rathe r tha n neutra l o r

basi c solution s fo r collectio n o

f th e hydroge n halide s greatl y reduces th e dissolutio n o f an y halogen s passin g throug h thi s solution

. High concentration s o f nitroge n oxide s (NO, ) ma y produc e sufficien t nitrat e (N03~ ) t o interfer e wit h measurement s of

ver y lo w Br ~ levels

. 1. 5 Sampl e Stability

. Th e collecte d C I ~ sample s ca n b e store dfo r u p t o 4 weeks

. 1. 6 Detectio n Limit

. Th e analytica l detectio n limi t

fo r Cl ~ i s 0. 1 ug/ml

. Detectio n limit s fo

r th e othe r analyte s

. shoul db e similar

.

900 0 2. 1 " * * BHJJM G CO0 2 1S03-01- O

## •Stac k Wal l S S Sheat h Purg e 3-Wa y Glas s Stopcoc k

/ 

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## Ma e Wes t Impinge ro rDryin g Tub e

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## Ga s N 

## Flo w L Filte rHolde r

Heate d Glas s Line r

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_ 

## Silic a Ge l Empt y 0. 1 N H2S0 4 0. 1 N NaO H

Rat e Mete r.'%_ ** ^
© Samplin g (Figur e 1C ) Ventin g (Figure , 1B )
e Purgin g (Figur e 1A ) JJ=C3 = 

## © 

# 7
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## \ Vacuu m Gaug e Pum p Dr y Ga s Mete r "Surg e Tan k


# Figur e 26-1

. Samplin g train

. BILUM O COO C 150*-01- C « 0 M



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### 3P®d©E*sJS

. BLBgiste r /Vol

. 58,

. No
. 37 : /

Friday , Februar y 26 , 199 3 I Correction s 13711 3 2.1. 3 Sampl e Impingers . Fou r30-ml midge timpinger s wit h leak-free glas s connectors . Silicon e greas e ma y b e used , if necessary , t o preventleakage . For samplin g a

thig h moisture source s orfo r samplin g time s greate

rtha n on e hour , a n additiona l midge timpinge r with a shortene d ste m (suc h tha tth e gas sampl e dos s no tbubbl e throug h th e collecte d condensate ) shoul d b e use d i n fron

tof th e firstimpinger . 2.1. 4 Dryin g Tub e o

rImpinger. Tub e o rimpinge r(Ma

e Wes tormidget design ) fille d with 6 - t o 16-mes h indicatin g typ e silic a gel , o r equivalent , t o dr

y th e ga s sampl e and t o protectth e dr

y ga s mete rand pump . ° ° ° 2.1. 5 Filter . A 25 - o r47-m m Teflon " mat , Pallflex RTX40H17 5 or equivalent . Locat

e i n a glass , quartz , o r Teflon 1 1 filte rholde rwith a Teflon * orothe rinertfilte rsuppor tinsid e a filterbo x heate d t

o 12 1 ° C (25 0 °F) . Whe n th e stack gas temperatur e exceed s 21 0 ° C (41 0 °F

) and th e HC

l concentratio n i s greate

rtha n 2 0 ppm , a quartz-fiberma

y b e used . « o o * » 2. 2 * * * 2.2. 2 Storage Bottles . 100 - o r250-ml . high-density polyethylen e bottle s wit h Teflon * scre w cap liner s t o store impinge r samples . « O O O ft r i ft ft ft 3 . 1 • « • » 3.1. 2 Acidi c Absorbin g Solution . 0. 1 N Sulfuri c Ad d (H12SO4). ° ° " 3.1. 3 Alkalin e Absorbin g Solution . 0. 1 N Sodiu m Hydroxid e (NaOH) . T o prepar e 10 0 ml of

th e alkalin e absorbing solutio n fo

rth e secon d impinge rpair , dissolv e 0.4 0 g of soli d NaO H i n about9 0 m

l of water and adjustth e fina

l volum e t o 10 0 ml usin g additional water . Shake wel l t o mix th e solution . 3. 2 " " ° 3.2. 2 Blan

k Solutions . Separat

e blan k solution s o f

th e absorbin g reagent

s shoul d b e prepare

d fo ranalysi s with th e fiel d samples . Dilut e 3 0 m l of each absorbing solutio n t

o 10 0 ml with wateri n separat

e volumetri c flasks . 3.2. 3 Halid e Sal tStock Standar d Solutions . Prepar

e concentrate d stock solution s fro

m reagen tgrade sodiu m chlorid e (Nad) , sodiu m bromid e (NaBr) , an d sodiu m fluorid e (NaF) . Eac h mus tb e drie d a t11 0 ° C fo rtw o o rmore hour s an d the n coole d t o roo m temperature i n a desiccato r Immediatel y befor

e weighing . Accuratel y weig h 2. 6 t o 2. 7 g ofth e dried NaCl to withi n 0. 2 mg , dissolv e i n water , an d dilut e t o 1 liter . Calculat e th e exac tQ " concentratio n usin g Equation 26-8 . ug Cl - /ml= g o f NaClxlO^S^SS/SB. ^

Eq.26- 1 I n a simila rmanner , accurately weig h and solubiliz e 1.

2 t o 1.3 g o f dried NaB rand 2. 2 t o 2. 3 g o f

Na F t o mak e 1-liter solutions . Us e Equations 26- 2 and 26- 3 t o calculate th e Br~ and F ~ concentrations . u g Br - /ml= g o f

NaBrxl0 2, x79.904/ 102.9 0 Eq . 26- 2 u g F"/ml= g of

NaFxl0M8.998/41.9 9

Eq . 26- 3 Alternately , solution s containin g a nominal certifie d concentratio n of 100 0 mg/ L NaC l ar e commerciall y availabl e a s convenien tstock solution s fro

m whic h standard s can b e made b

y appropriat

e volumetri c dilution . Refrigerat

e th e stoc k standar d solution s an

d store n o longe r tha n on e month . - ft a

* o o 4 . * ° ° 4 j o • o 4.1. 1 Preparatio

n of Collectio n Train . Prepar e th e samplin g trai

n a s follows : Pour1 5 m

l ofth e acidi c absorbing solutio n into each on e ofth e firstpai r o f impingers , and 1 5 m

l ofth e alkalin e absorbing solutio n int o each on e ofth e secon d pairo

f impingers . Connec tth e impingers i n serie s with th e knockou

timpinge rfirst, if

used , followe d by th e tw o impingers containin g th e acidi c absorbing solutio n and th e tw o impingers containin g th e alkalin e absorbing solution . Place a fres

h charg e o f silic a gel , o requivalent , i n th e dryin g tub e orimpinge ra

tth e en d ofth e impinge r train . « a « o o 4. 2 Sampl e Recovery . Disconnec tth e impingers afte

rsampling . Quantitativel y transfe

rth e content s of th e aci d impingers and th e knockou t impinger , if

used , t o a leak-free storage bottle . Ad d th e waterrinses of each o f thes e impingers and connectin g glassware t o th e storage bottle . Repea

tthi s procedur

e fo r th e alkalin e impingers an

d connectin g glassware usin g a separat e storag e bottle . Th e sampl e bottle s shoul d b e sealed , shaken t o mix . an d labeled . Mar k th e fluid level . 4. 3 Sampl e Preparatio

n fo rAnalysis . Note th e liqui d level s i n th e sampl e container s en d confir

m o n th e analysi s shee twhethe ro r no tleakag e occurred durin g transport. M a noticeabl e leakag

e ha s occurred , eithe r voi d th e sampl e o? us e methods , subjectt o th e approva l o f th e Administrator , t

o correc tth e final results . Quantitativel y transfe rth e sampl e solution s t o 200-ml volumetri c flasks, and dilut e t o 20 0 m l with water . 4. 4 ° ° ° 4.4. 2 Befor

e sampl e analysis , establis h a stabl e baseline . Next , injec ta sampl e o f water , and determin e if

an y Cl \ Br , o r P appears i n th e chromatogram . I f any o f thes e ion s ar

e present , repea

t th e load/injectio n procedur e unti l the y ar e n o longe rpresen tAnalysi s o f th e aci d and alkalin e absorbin g solutio n sample s require s separat e standar d calibratio n curves ; prepar e each accordin g t o sectio n 5.2 . Ensur e adequat e baselin e separatio n of

th e analytes . 4.4. 3 Betwee n injection s ofth e appropriat

e serie s o f

calibratio n standards , injecti n duplicat e th e reagentblanks , qualit

y contro l sample , an

d th e fiel d samples . Measur e th e areas orheight s of

th e CI" , Br , and F

" peaks . Us e th e average respons e t o determin e th e concentration s of

th e fiel d sample s and reagen

tblank s usin g th e linea r calibratio n curve . Th e value s fro m duplicate injection s shoul d agree withi n 5 percento f

thei r mea

n fo rth e analysi s t o b e valid . Dilute any sampl e an d th e blank wit h equal volume s o f

wate r i f th e concentratio n exceed s tha

to f th e highes tstandard . 0 ft ' O ft ft
5 ft o o 5. 2 Io n Chromatograph . T o prepar e th e calibratio n standards , dilut e give n amounts (1. 0 m

l orgreater

) of th e stock standar

d solution s t o convenien tvolumes , usin g 0. 1 N H2SO 4 o r0. 1 N NaOH, a s appropriate . Prepar e a tleas tfourcalibratio n standard s fo

reac h absorbing reagen

t containin g th e appropriat e stoc k solution s suc h tha

tthe y ar e withi n th e linea rrang

e o f th e fiel d samples . Usin g on e of

th e standard s i n eac h series , ensur e adequat

e baselin e separatio n fo

rth e peak s o f

interest . Injec tth e appropriat

e serie s of calibratio n standards , startin g wit h th e lowes tconcentratio n standar d firstbot h befor e an d afte r injectio n o f th e qualit y contro l chec k sample , reagen tblanks , an d field samples . Thi s allow s compensatio n fo ran y instrumentdrif

toccurrin g durin g sampl e analysis . Determin e th e peak areas , o rheights , fo rth e standard s an d plo tindividua l value s versu s halid e io n concentration s i n ug/ml . Dra

w a smoot h curv e through th e points . Us e linea r regressio n t o calculat e a formula describin g th e resultin g linea rcurve . -0000 0 y o o ft 7. 2 Total u g HCl , HBr

. o r H F Per Sample .P. 7

1171 4 Federa l Registe r/ Vol . 58 , No . 3 7 /Friday , Februar y 26 , 199 3 / Correction s

m HX =KV . (S x --r-B x - ) Eq . 26- 4 where : B x - = Analysi s of

reagen tblank , u g halid e io n (CI - , Br^ , F

_ )/ml . mKx=Mas

s o f HCl, HBr

, o rH F in sample , ug . S x - = Analysi s of

sample , u

g halid e io n (a-.Br-.F-J/ml . V,=Volum e o

f filtere d and dilute d sample , ml . K H o=1.02 8 (u

g HCl/ug-mole)/(u g CI - / ug-mole) . K H Br=1.013 (u

g HBr/ug-mole)/(u g Br - / Ug-mole) . K„ F =1.05 3 (u

g HF/ug-mole)/(u g F~/ug mole) . 7. 3 Tota l u g Cl 2 o rBr 2 Pe rSample . m XJ = 2 V . (S x - - B x - ) Eq . 26- 5 where : m X 2=Mass o f Cl 2 o rBr 2 i n sample , ug . 7. 4 Concentratio n of

Hydroge n Halid e o r Halogen i n Flu e Gas . C= Km H x.x2/V„s<.

t d ) Eq

. 26- 6 where : C=Concentratio

n o f hydrogen halid e (HX ) o rhaloge n (X

2) , dr y basis , mg

/ dscm . Vm( S ui)'=Dr y gas volum e measured by th e dr y gas meter , corrected t

o standar d conditions , dscm . K-10" 3 mg/ug . 0 * * * 4 . Stern , D.A. , B.M. Myatt . J.F . Lachowski , and K.T . McGregor . Speciatio n of

Halogen and Hydroge

n Halid e Compound s i n Gaseou s Emissions . In : Incineratio n an d Treatmen to f Hazardous Waste : Proceeding s o

f th e 9t h Annua l Researc h Symposium , Cincinnati , Ohio , Ma y 2-4,1983 . Publicatio n No.600/9-84-015 . Jul

y 1984 . Availabl e fro

m National Technical Information Service , Springfield , V A 2216 1 as PB84-234525 . 5 . Holm , R.D . an

d S.A . Barksdale . Analysi s o

f Anion s i n Combustion Products . In : Io

n Chromatographic Analysi s o

f Environmenta

l Pollutants . E. Sawicki , J.D . Mulik , an d E. Wittgenstei n (eds.) . Ann Arbor , . Michigan , Ann Arbo

rScienc e Publishers . 1978 . pp . 99-110 . o ft o a o 4 . I ti s propose d tha

t4 0 CF Rpar t6 0 b e amende d b y addin g Metho d 26 A t o Appendi x A a s follows : Appendi x A—TestMethod s Method 26A—-Determinatio n o f Hydroge n Halid e and Haloge n Emission s Fro

m Stationary Sources— Isokineti c Metho d 1. Applicability, Principle, Interferences, Precision, Bias, and

Stability 1. 1 Applicability . Thi s metho d i s applicabl e fo

rdeterminin g emission s o f hydrogen halide s (HX

) [hydroge n chlorid e (HCl) , hydrogen bromid e (HBr) , an d hydrogen fluorid e (HF) ] and halogen s (X

2 ) [chlorin e (CI2

) an d bromine (Br

2 ) j from stationar

y sources . Thi s metho d collect s th e emissio n sampl e isokineticall y an d i s therefor e particularly suite d fo

r samplin g a

tsources , such a

s thos e controlle d by we tscrubbers , emittin g aci d particulat

e matte r(e.g. , hydrogen halide s dissolve d i n wate rdroplets) . [Note : Mention o

f trad e name s o r specifi c product

s doe s notconstitute endorsementb

y th e Environmenta

l Protectio n Agency. ) 1. 2 Principle . Gaseou s and particulat e pollutants ar

e withdrawn isokineticall y from th e source and collecte d i n a

n optional cyclone , o n a filter, an d i n absorbing solutions . Th e cyclon e collect s an

y liqui d droplets an d i s notnecessary if

th e source emission s d o notcontai n them ; however , iti s preferable t o includ e th e cyclon e i n th e samplin g trai n t o protec tthe filter from an

y moisture present. Th e filter collect s other particulat e matte rincludin g halid e salts . Acidi c and alkalin e absorbing solution s collec tth e gaseou s hydrogen halide s and halogens , respectively. Followin g samplin g o f emission s containin g liqui d droplets , an y halides/halogen s dissolve d in th e liqui d i n th e cyclon e and o n th e filter ar e vaporize d t

o gas an d collecte d i n th e impingers by pullin g conditione d ambientairthroug

h th e samplin g train . The hydrogen halide s ar e solubilize d i n th e acidi c solutio n and for m chlorid e (CI~) , bromid e (Br") , and fluoride (F~ ) ions . Th e halogen s hav e a ver

y lo w solubility i n th e acidi c solutio n and pas s throug h t o th e alkalin e solutio n wher e the y ar e hydrolyze d t o for

m a proton (H + ) , th e halid e ion , and th e hypohalou s aci d (HCI O o rHBrO) . Th e halid e ion s i n th e separat

e solution s ar

e measured by io n chromatograph

y (IC) . I f desired , th e particulat

e matter recovered fro

m th e filterand th e prob e i s analyze d followin g th e procedure s i n Metho d 5. 1.3 Interferences . Volatil e materials , suc h a s chlorin e dioxid e (C10 2 ) and ammoniu m chlorid e (NH4CI), whic h produce halid e ion s upo n dissolutio n during samplin g ar

e potential interferents . Interferent s fo rth e halid e measurement

s ar e th e haloge n gase s whic h disproportionat

e t o a hydrogen halid e and a

n hypohalou s aci d upo n dissolutio n i n water . Th e us e o f acidi c rathertha n neutra l o rbasi c solution s fo rcollectio n o f

th e hydroge n halide s greatly reduce s th e dissolutio n o f an y halogen s passin g through thi s solution . Hig

h concentration s of nitrogen oxide s (NO, ) ma y produc e sufficien tnitrat

e (NO a - ) t o interfer

e with measurements o f

very lo w Br~ levels . 1. 4 Precisio n an d Bias . Th e metho d ha s a measurabl e negativ e bia s belo w 2 0 ppm HCl. Simila rbia s fo r th e other hydrogen halide s i s possible . 1. 5 Sampl e Stability . Th e collecte d CI " sample s can b e store d fo ru p t o 4 week s fo

r analysi s fo

rHC l and Cl

3 . 1. 6 Detectio n Limit . Th e in-stack detectio n limi tfo

r HC l i s approximatel y 0.0 2 u

g pe rlite ro

f stac k gas ; th e analytical detectio n limi tfo rHC l i s 0. 1 ug/ml . Detectio n limit s fo rth e othe ranalyte s shoul d b e similar . 2. Apparatus 2. 1 Sampling . Th e samplin g trai n i s show n i n Figur

e 26A-1 ; th e apparatus i s simila rt o th e Metho d 5 train wher e note d as follows : ' 2.1. 1 Probe Nozzle . Borosilicate o r quart z glass ; constructe d and calibrated accordin g t

o Metho d 5 , section s 2.1. 1 and 5.1 , and couple d t o th e prob e line rusin g a Teflon ® union ; a stainles s stee l nu ti s recommende d fo rthi s union . Whe

n th e stac k temperatur

e exceed s 21 0 ° C (41 0 °F) , a onerpiec e glas s nozzle/line r assembl y mus tb e used . 2.1. 2 Probe Liner . Sam e a s Metho d 5 , sectio n 2.1.2 , excep tmeta l liner s shal l no tb e used . Water-coolin g of th e stainles s stee l sheath i s recommende d a ttemperature s exceedin g 50 0 "C 2.1. 3 PitotTube , Differentia l Pressure Gauge , Filte r Heatin g System , Metering System , Barometer , Ga s Density Determinatio n Equipment . Same a s Metho d 5 , section s 2.1.3 , 2.1.4 , 2.1.6 , 2.1.8 , 2.1.9 , an d 2.1.10 . 2.1. 4 Cyclon e (Optional) . Glass . Us e of th e cyclon e i s required only whe n th e sampl e gas strea

m i s saturated wit h moisture ; however , th e cyclon e i s recommende d t o protectth e filler fro m an y moistur e droplets present . 2.1. 5 Filte r Holder . Borosilicate glass , with a Teflon 0 filtersupportan d a sealin g gasket . Th e sealin g gasket shal l b e constructe d o f

Teflon 0 or equivalen tmaterials . Th e holde r desig n shal l provid e a positiv e sea l agains tleakag e a

tanypoin talon g th e filtercircumference . Th e holde rshal lP. 8

Federa l Registe r

/ Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 / Correction s 1171 5 b e attache dimmediatel y t o th e outle t ofth e cyclone

. 2.1. 6 Impinge r

Train

. Th e followin g syste mshal l b e use dt o determin e th e stac k ga s moistur e conten t

an dt o collec t th e hydroge n halide s an d halogens : fiv e o r

si x impinger s connecte di n serie s wit h leak-fre e groun dglas s fitting s o r

an y simila r leak-fre e noncontaminatin g fittings. Th e first impinge r show n i n Figur e 26A- 1 (knockou t

o r condensat e impinger ) i s optione l an di s recommendeda s awate r

knockou t tra p fo r us e unde r

hig h moistur e conditions

. I

f used , thi s impinge r shoul db e constructe da s describe d belo w fo r th e alkalin e impingers

. bu t with ashortene dstem , an dshoul d contai n 5 0 m

l of 0. 1 N H2SO4

. Th e followin g tw o impinger s (aci d Impinger s whic h eac h contai n 10 0 m l o f 0. 1 N H 2 S0 4 ) shal l b e o

f th e Greenburg-Smith desig n wit h th e standar dti p (Metho d5 , sectio n 2.1.7)

. Th e nex t tw o impinger s (alkalin e impinger s whic h eac h contai n 10 0 m l of 0. 1 N NaOH ) an dth e las t impinge r (containin g silic agel ) shal l b e of th e modifie dGreenburg-Smith desig n (Metho d5 , sectio n 2.1.7)

. Th e condensate , acid , an dalkaline ' impinger s shal l contai n know n quantitie s o

f th e appropriat e absorbin g reagents
. Th e las t impinge r shal l contai n aknow n weigh t o f silic a ge l o r equivalen t

desiccant

. 2.1. 7 Ambien t

Ai r Conditionin g Tub e (Optional)

. Tub e tightl y packe dwith approximatel y 15 0 g of

fres h 8 t o 2 0 mes h sodiu mhydroxide-coate dsilica , o r equivalent ; (Ascarit e D

® ha s bee n foun dsuitable ) t o dr y an dremove aci dgase s fro

mth e ambien t

ai r use d t o remov e moistur e fro

mth e filte r

an d cyclone , whe n th e cyclon e i s used

. Th e inle t an doutlet

end s ofth e tub e shoul db e packe dwit h a

t leas t 1-c m thicknes s o f

glas s woo l o r

filte r materia l suitabl e t o preven t escap e o f fines. Fi t on e en dwit h flexibl e tubing , etc
. t o allo w connectio n t o prob e nozzl e followin g th e tes t

run . 2. 2 Sampl e Recovery
. Th e followin g item s ar e needed : 2.2. 1 Probe-Line r

an dProbe-Nozzl e Brushes , Was h Bottles , Glas s Sampl e Storag e Containers , Petri Dishes , Graduate dCylinde r

o r Balance , an d Rubbe r Policeman

. Sam e a s Metho d5 , section s 2.2.1 , 2.2.2 , 2.2.3 , 2.2.4 , 2.2.5 , an d2.2.7

. 2.2. 2 Plasti c Storag e Containers

. Screw-cap polypropylen e o r polyethylen e container s t o stor e silic a gel

. High-densit y polyethylen e bottle s wit h Teflo n scre w ca p liner s t o stor e impinge r reagents , 1-liter

. 2.2. 3 Funnels

. Glas s o r high-densit y polyethylene , t o ai di n sampl e recovery . 2. 3 Analysis

. Fo r

analysis , th e followin g equipmen t

i s needed : 2.3. 1 Volumetri c Flasks

. Clas s A , variou s sizes

. 2.3. 2 Volumetri c Pipettes

. Clas s A

. assortment , t o dilut e sample s t o calibratio n rang e o

f th e io n chromatograp h (IC)

. 2.3. 3 Io n Chromatograph

. Suppresse d o r nonsuppres3ed , wit h a conductivit y detecto r

an delectroni c integrato r operatin g i n th e peak

are a mode

. Othe r

detectors , astri p chart recorder , an dpea

k height s ma

y b e used

. 3. Beagenis Unles s otherwis e indicated , al l reagents mus t confor mt o th e specification s of th e Committe e o n Analytica l Reagent s of th e America n Chemica l Society (AC S reagen t

grade)

. Whe n suc h specification s ar e no t

available , th e bes t availabl e grad e shal l b e used

. 3. 1 Sampling

. 3.1. 1 Water
. Deionized , distille dwate r tha t conform s t o America n Society o f Testin g an dMaterial s (ASTM) Specificatio n D1193-77 , Typ o 3

. 3.1. 2 Acidi c Absorbin g Solution , 0, 1 N Sulfuri c Aci d(H 2 Sb,i}

. T o prepar e 1 L , slowl y ad d2.8 0 ml of

concentrate d H 2 S0 4 t o abou t

90 0 ml of

wate r whil e stirring , an dadjus t

th e final volum e t o 1 L usin g additiona l water
. Shak e wel l t o mi x th e solution

. 3.1. 3 Alkalin e Absorbin g Solution

. 0. 1 N Sodiu mHydroxid e (NaOH)

. T o prepar e 1 L , dissolv e 4.0 0 g o f soli d NaO H i n abou t

90 0 m l of

wate r an d adjus t th e fina l volum e t o 1 L usin g additiona l water
. Shak e wel l t o mi x th e solution

. 3.1. 4 Filter

. Quartz-fibe r o r Teflon ® ma t (e.g. , Pallflex ® TX40HI45 ) filter

. 3.1. 5 Silic aGel , Crushe dIce , an d Stopcoc k Grease

. Sam e a s Metho d5 , section s 3.1.2 , 3.1.4 , an d3.1.5 , respectively. 3. 2 Sampl e Recovery
. 3.2. 1 Water
. Sam e a s Sectio n 3.1.1

. 3.2. 2 Acetone

. Sam e a s Metho d5 , Sectio n 3.2

. 3. 3 Sampl e Analysis

. 3.3. 1 Water
. Sam e a s sectio n 3.1.1

. 3.3. 2 Reagent

Blanks

. A separat e blan k solutio n of

eac h absorbin g reagent shoul db e prepare dfo

r analysi s wit h th e fieldsamples

. Dilut e 20 0 ml of eac h absorbin g solutio n (25 0 ml ofth e acidi c absorbin g solution , i f a condensat e impinge r

i s used ) t o th e sam e final volum e a s th e field sample s usin g th e blan k

sampl e of rins e water
. I

f aparticulat e determinatio n i s conducted , collec t a blan k sampl e of

acetone
. 3.3. 3 Halid e Sal t Stoc k Standar d Solutions

. Prepar e concentrate dstoc k solution s fro

mreagent

grad e sodiu m chlorid e (NaCl) , sodiu mbromid e (NaBr)

. an dsodiu mfluorid e (NaF)

. Eac h mus t

b e drie dat

11 0 ° C fo

r 2 o r mor e hour s an dthe n coole dt o roo m temperatur e i n adesiccato r immediatel y befor e weighing

. Accuratel y weig h 1. 6 t o 1. 7 g of th e drie dNaC l t o withi n 0. 1 mg , dissolv e i n water , an ddilut e t o 1 liter

. Calculat e th e exact

Cl ~ concentratio n usin g Equatio n 2 6 A-1

. u g Cl

_ /ml= g of

NaClxl0 3 x35.453/58.4 4

Eq
. 26A- 1 I n asimila r

manner , accuratel y weig h an dsolubiliz e 1. 2 t o 1. 3 g o f drie d NaB r an d2. 2 t o 2. 3 g of

Na Ft o mak e 1-liter solutions

. Us e Equation s 26A

2 an d26A- 3 t o calculat e th e Br ~ an d F ~ concentrations

. u g Br

_ /ml= g o

f NaBrxlO , x79.904 / 102.9 0 Eq
. 26A- 2 u g F-/ml= g olr1aFxWbilB.998hl.Q9 Eq
. 26A- 3 Alternately , solution s containin g a nomina l certifie dconcentratio n o f 100 0 mg/ L NaC l ar e commerciall y availabl e a s convenien t

stoc k solution s fro

mwhic h standard s ca n b e mad e b y appropriat e volumetri c dilution

. Refrigerate th e stoc k standar dsolution s an dstor e n o longe r tha n 1 month

. 3.3. 4 Chromatographi c Eluent

. Effectiv e eluent s fo

r nonsuppresse d io n chromatograph y usin g aresin

- o r silica-base dweak

io n exchang e colum n ar e a4 m

M potassiu m hydroge n phthalat e solution , adjuste d t o ap H of

4. 0 usin g asaturate d sodiu mborat e solution , an dam M 4

- hydrox y benzoat e solution , adjuste d t o ap H o f 8. 6 usin g 1 N sodiu m hydroxide

. A n effectiv e eluen t fo r suppresse dio n chromatograph y i s a solutio n containin g 3 mM sodiu m bicarbonat e an d2. 4 m

M sodiu m carbonate

. Othe r

dilut e solution s buffere dt o asimila r

p H tha t contai n n o ion s interferin g wit h th e chromatographi c analysi s ma y b e used

. If , whe n usin g suppresse dio n chromatography , th e "wate r dip " resultin g fro

msampl e injectio n i s interferin g wit h th e chlorin e peak , us e a2 m M sodiu mhydroxide/2. 4 m M sodiu mbicarbonat e eluent

. 4. Procedure Becaus e ofth e complexit y o f thi s method , tester s an danalyst s shoul d b e traine dan dexperience dwit h th e procedure s t o ensur e reliabl e results

4. 1 Sampling

. 4.1. 1 Pretes t

Preparation

. Follo w th e genera l procedur e give n i n Metho d5

.P. 9

1171 6 Federa l Registe r / Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 / Correction s sectio n 4,1.1 , excep t

th e filter nee d onl y b e desiccate dan dweighe di f a particulat e determinatio n wil l b e conducted

. 4.1. 2 Preliminar y Determinations

. Sam e a s Metho d5 , sectio n 4.1.2

. 4.1. 3 Preparatio n of

Samplin g Train ; Follo w th e genera l procedur e give n i n Metho d5 , sectio n 4.1.3 , excep t fo r th e followin g variations : Ad d5 0 m l of 0. 1 N H 2 S0 4 t o th e condensat e impinger , i

f used

. Plac e 10 0 m l of 0. 1 N H 2 S0 4 i n eac h of

th e nex t tw o impingers

. Plac e 10 0 ml o f 0. 1 N NaO H i n eac h o

f th e followin g tw o impingers

. Finally , transfe r approximatel y 200-30 0 g of preweighe dsilic age l fromit s containe r t o th e las t

impinger

. Se t

u p th e trai n a s i n Figur e 26A-1

. Whe n used , th e optiona l cyclon e i s inserte d betwee n th e prob e line r

an dfilter holde r an dlocate di n th e heate dfilter box

. . . 4.1. 4 Leak-Chec k

Procedures

. Follo w th e leak-chec k

procedure s give n i n Metho d5 , section s 4.4. 1 (Pretes t Leak

Chock) , 4.1.4. 2 (Leak-Check s Durin g th e Sampl e Run) , an d4.1.4. 3 (Post

Tes t Leak-Check) ; 4.1. 5 Trai n Operation

. Follo w th e genera l procedur e give n i n Metho d5 , sectio n 4.1.5

. Maintai n atemperatur e aroun dth e filter

an d(cyclone , if

used ) o f 120+1 4 ° C (24812 5 °F)

. Fo r eac h run , recor dth e dat arequire do n adat a shee t suc h a s th e on e show n i n Metho d5 , Figur e 5-2

. I

f th e condensat e impinge r

become s to o full , i t mayb e emptied , recharge d wit h 5 0 m

l of 0. 1 N H 2 S0 4 , an d replace ddurin g th e sampl e run . Th e condensat e emptie dmus t b e save d an dinclude di n th e measuremen t o f th e volum e o

f moistur e collecte dan d include di n th e sampl e fo r analysis

. Th e additiona l 5 0 ml o

f absorbin g reagent mus t als o b e considere di n calculatin g th e moisture

. After th e impinge r i s reinstalle di n th e train , conduc t aleak-chec k

a s describe di n Metho d5 , sectio n 4.1.4.2

. 4.1. 6 Post-Tes t

Moistur e Removal (Optional)

. Whe n acyclon e i s include di n th e samplin g train , perfor mth e followin g procedure

. Upo n completio n o

f th e tes t run , connec t th e ambien t

ai r conditionin g tub e a t th e prob e inle t

an doperat e th e trai n wit h th e filter

heatin g syste ma t 120±1 4 ° C (248±2 5 °F

) a t alo w flo w rat e (e.g. , AH= 1 in

. H 2 0 ) t o vaporiz e an y liqui dan dhydroge n halide s i n th e cyclon e o r

o n th e filte r

an dpul l the mthroug h th e trai n int o th e impingers

. After

3 0 minutes , tur n of

f th e flow , remove th e conditionin g tube , an dexamin e th e cyclon e an d filte r fo r an y visibl e moisture

. I

f moistur e i s visible , repeat thi s ste p fo

r 1 5 minutes

. 4. 2 Sampl e Recovery. : Allo w th e prob e t o cool

. Whe n th e prob e can b e handle dsafel y > wip e of

f al l th e external.surface s o

f th e ti p o f th e prob e nozzl e an dplac e acap loosel y ove r th e tip

. D o no t

ca p th e prob e ti p tightl y whil e th e sampling trai n i s coolin g dow n becaus e thi s will creat e avacuu mi n th e filter

holder , drawin g wate r fro mth e impinger s int o th e holder

. Befor

e movin g th e sampling trai n t o th e cleanu p site , remove th e probe , wip e of

f an y silicon e grease , an dca p th e ope n outle t

ofth e impinge r train , bein g carefu l no t

t o los e an y condensat e tha t

might b e present
. Wip e of

f an y silicon e greas e an dcap th e filter

o r cyclon e inlet

. Remov e th e umbilica l cor dfro mth e las t impinge r an dcap th e impinger

. I

f aflexibl e lin e i s use dbetwee n th e first impinge r an dth e filter

holder , disconnec t

i t a t th e filter holde r an d le t an y condense dwate r

drai n int o th e firs t impinger

. Wip e of

f an y silicon e greas e an dca p th e filter holde r outle t an dth e impinge r

inlet

. Groun dglas s stoppers , plasti c caps , seru mcaps , Teflon " tape , Parafilm" , o r aluminu mfoi

l ma y b e use dt o clos e thes e openings

. Transfer

th e prob e an dfilter/impinger

assombl y t o th e cleanu p area . Thi s are s shoul db e clea n an dprotecte dfromth e weathe r t o minimiz e sampl e contaminatio n o r loss

. Inspec t

th e trai n prio r

t o an d durin g disassembl y an dnot e an y abnormal-conditions

. Treat sample s a s follows : 4.2i l Containe r

No
. 1 (Optional ; Filte r Catc h fo r Particulat e Determination)

. Sam e a s Metho d5 , sectio n 4.2 , Containe r No
. 1

. 4.2. 2 Containe r

No
. 2 (Optional ; Front

Half Rins e fo r Particulat e Determination)

. Same a s Metho d5 , sectio n 4.2 , Containe r

No
. 2

. 4.2. 3 Containe r

No
. 3,(Knockou t

an d Aci dImpinge r

Catc h fo r Moistur e an d Hydroge n Halid e Determination)

. Disconnec t

th e impingers

. Measur e th e liqui di n th e aci dan dknockou t impinger s t o ± 1 m

l b y usin g a graduate dcylinde r

o r b y weighin g i t t o ±0. 5 g b y usin g abalance

. Recor d th e volum e o r

weigh t o f liqui d present
. Thi s informatio n i s require d t o calculat e th e moistur e conten t of th e effluent

gas . Quantitativel y transfe r thi s liqui dt o aleak-fre e sampl e storag e container

. Rins e thes e impinger s an dconnectin g glasswar e (an dtubing , i f

used ) wit h wate r

an d ad dthes e rinses t o th e storag e container

. Seal th e container , shak e t o mix , an dlabel

. Th e flui dleve l shoul d b e marke ds o tha t

i f an y sampl e i s los t durin g transport , acorrectio n

proportiona l t o th e los t

volum e ca n b e applied

. Retai n rinse wate r an dacidi c absorbin g solutio n blank s and

. analyz e wit h th e samples.

. 4.2. 4 Containe r

No
. 4 ; (Alkalin e Impinge r Catc h for Haloge n an d Moistur e Determination)

. Measur e an drecor dth e liqui di n th e alkalin e impinger s a s describe di n sectio n 4.2.3

. Quantitativel y transfe r thi s liqui dt o aleak-fre e sampl e storag e container

. Rins e thes e tw o impingers

. an dconnectin g glasswar e wit h wate r an dad dthes e rinse s t o th e container

. Seal th e container , shak e t o mix , an d label ; mar k th e flui dlevel

. Retain , alkalin e absorbin g solutio n blan k an d analyz e wit h th e samples

. 4.2. 5 Containe r

No
. 5 (Silic aGel fo

r Moistur e Determination)

. Sam e a s Metho d5 , sectio n 4.2 , Containe r No
. 3

. 4.2. 6 Containe r

Nos
. 6 throug h 9 (Reagent Blanks) : Sav e portion s o f th e absorbin g reagents (0. 1 N H 2 S0 4 an d 0. 1 N NaOH ) equivalen t

t o th e amoun t
• " use di n th e samplin g train ; dilut e t o th e approximat e volum e of th e correspondin g sample s usin g rinse wate r directl y fromth e was h bottl e bein g used

. Also , sav e aportio n o f th e rinse wate r

alon e an daportio n o

f th e aceton e equivalen t

t o th e amoun t use dt o rinse th e front

hal f o f th e samplin g train

. Plac e eac h i n a separate , prelabele dsampl e container

. 4.2. 7 Prio r

t o shipment , recheck

al l sampl e container s t o ensur e tha t th e cap s ar e well-secured

. Seal th e lid s o f al l container s aroun dth e circumferenc e wit h Teflon * tape
. Shi p al l liqui dsample s uprigh t an dal l particulat e filter s wit h th e particulat e catc h facin g upward

. 4. 3 Sampl e Preparatio n an dAnalysis

. Not e th e liqui dlevel s i n th e sampl e container s an dconfirmo n th e analysi s shee t

whethe r o r no t leakag e occurre ddurin g transport
. I f a noticeabl e leakag e ha s occurred , eithe r voi dth e sampl e o r

us e methods , subjec t

t o th e approva l of th e Administrator , t o correc t th e final results

. 4.3. 1 Containe r

Nos
. 1 an d2 an d Aceton e Blan k

(Optional ; Particulat e Determination)

. Sam e a s Metho d5 , sectio n 4.3

. 4.3. 2 Containe r

No
. 5

. Sam e a s Metho d 5 , sectio n 4. 3 fo

r silic agel

. . 4.3. 3 Containe r

Nos
. 3 an d4 an d Absorbin g Solutio n an dWate r Blanks

. Quantitativel y transfe r

eac h sampl e t o avolumetri c flask

o r graduate d cylinde r an ddilut e wit h wate r

t o a final volum e withi n 5 0 m l of th e larges t sample.

. ,P.1 0

Federa l Registe r

7 Vol

. 58 , No
. 3 7 /

Friday , Februar y 26 , 199 3 / Correction s 1171 7 4.3.3. 1 Th e I

C condition s wil l depen d upo n analytica l colum n typ e an d whethe r suppresse do r

nonsuppresse d I C i s used

. Prio r

t o calibratio n an d sampl e analysis , establis h astabl e baseline

. Next , injec t

asampl e o f water , an ddetermin e i f

an y Cl~

. Br~
. o r F ~ appear s i n th e chromatogram

. I f an y o f thes e ion s ar e present , repea t th e load/injectio n procedur e unti l the y ar e n o longe r

present
. Analysi s of th e aci dan dalkalin e absorbin g solutio n sample s require s separat e standar dcalibratio n curves ; prepar e eac h accordin g t o sectio n 5.2

. Ensur e adequat e baselin e separatio n o f th e analytes

. 4.3.3. 2 Betwee n injection s o f th e appropriat e serie s of

calibration standards , injec t

i n duplicat e th e reagen t blank s an dth e fiel dsamples

. Measur e th e area s o r

height s o f

th e CI" , Br~andF ~ peaks

. Us e th e averag e respons e t o determin e th e concentration s o f

th e fiel dsample s an dreagen t

blank s usin g th e linea r calibratio n curve . I

f th e value s fro

m duplicat e injection s ar e no t withi n 5 percen t o f thei r mean , th e duplicat e injectio n shal l b e repeate dan dal l fou r value s use dt o determin e th e averag e response. Dilut e an y sampl e an dth e blan k

with equa l volume s of ivate r i f th e concentratio n exceed s tha t of th e highes t

standard

. 4. 4 Audi t

Sampl e Analysis

. Audit sample s mus t

b e analyze dsubjec t

t o availability

. 5. Calibration Maintai n alaboratory lo g of ai l calibrations

. 5. 1 Prob e Nozzle , Pito t

Tube , Dr y Ga s Meterin g System , Prob e Heater , Temperatur e Gauges

. Leak-Chec k of Meterin g System , an dBarometer
. Sam e a s Metho d5

. section s 5.1

. 5.2

. 5.3

. 5.4

. 5 5 , 5.6

. an d5.7 , respectively. 5. 2 Io n Chromatograph

. T o prepar e th e calibratio n standards , dilut e give n amount s (1. 0 ml o r

greater ) ofth e stoc k standar dsolution s t o convenien t

volumes , usin g 0. 1 N H 2 S0 4 o r 0. 1 N NaOH , a s appropriate

. Prepar e a t

leas t fou r calibratio n standard s fo

r eac h absorbin g reagen t containin g th e thre e stoc k solution s suc h tha t the y ar e withi n th e linea r rang e ofth e fiel dsamples

. Usin g on e of th e standard s i n eac h series , ensur e adequat e baselin e separatio n fo r th e peak s o f interest

. Injec t

th e appropriat e serie s o f

calibratio n standards , startin g with th e lowes t concentratio n standar dfirs t both before ari dafter

injectio n ofth e qualit y contro l chec k

sample , reagen t blanks , an dfiel dsamples

. Thi s allow s compensatio n fo

r an y instrumen t

drif t occurrin g durin g sampl e analysis

. Determin e th e pea

k areas , o r height , o f th e standard s an dplo t

individua l value s versu s halid e io n concentration s i n Ug/ml

. Draw a smoot h curv e throug h th e points

. Us e linea r regressio n t o calculat e a formul adescribin g th e resultin g linea r curve . 6. Quality Control Sam e a s Metho d5

. Sectio n 4.4

. 7
. Quality Assurance 7. 1 Applicability

. Whe n th e metho di s use dt o demonstrat e complianc e wit h aregulation, ase t

of tw o audi t sample s shal l b e analyzed

. 7. 2 Audi t

Procedure

. Th e availabl e audi t sample s ar e chlorid e solutions

. Concurrentl y analyz e th e tw o audi t sample s an dase t

of complianc e sample s i n th e same manne r t o evaluat e th e techniqu e ofth e analys t an dth e standard s preparation

. Th e sam e analyst , analytica l reagents , an d analytica l syste mshal l b e use dboth fo r complianc e sample s an dth e Environmenta l Protectio n Agenc y (EPA) audi t

samples

. 7. 3 Audi t

Sampl e Availability

. Audi t sample s wil l b e supplie donl y t o enforcemen t

agencie s fo

r complianc e tests
. Audit

sample s ma

y b e obtaine d b y writin g th e Sourc s Tes t Audi t Coordinato r

(MD-77B) , Qualit y Assuranc e Division , Atmospheri c Researc h an dExposur e Assessmen t Laboratory , U.S

. Environmenta l Protectio n Laboratory , Researc h Triangl e Park , NC 2771 1 o r b y callin g th e Sourc e Tes t

Audit Coordinato r (STAC ) a t (919 ) 541-7834

. Th e request fo r th e audi t sample s shoul d b e mad e a t

leas t 3 0 day s prio r

t o th e schedule dcomplianc e sampl e analysis

. 7. 4 Audi t

Results

. Calculat e th e concentration s i n mg/dsc musin g th e specifie dsampl e volum e i n th e audi t instructions

. Includ e th e result s o f both audi t

samples , thei r identificatio n numbers , an dth e analyst' s nam e wit h th e result s o f th e complianc e determinatio n sample s i n appropriat e report s t o th e EP A regional offic e o r

th e appropriat e enforcemen t

agency . (NOTE : Acceptabilit y of

results ma

y b e obtaine dimmediatel y b y reporting th e audi t result s i n mg/dsc man d complianc e result s i n tota l u g HCl / sampl e t o th e responsibl e enforcemen t

agency. ) Th e concentration s of

th e audi t sample s , obtaine db y th e analys t

shal l agre e withi n 1 0 percen t

o f th e actua l concentrations

. I

f th e 1 0 percen t specificatio n i s no t

met
. reanalyz e th e complianc e sample s an daudi t

samples , an dinclud e initia l an d reanalysi s value s i n th e tes t report
. Failur e t o mee t

th e 1 0 percen t specificatio n ma y requir e retest s unti l th e audi t problem s ar e resolved

. 8. Calculations Retai n a t leas t on e extr adecima l figure beyon dthos e containe di n th e availabl e dat ai n intermediat e calculations , an droun dof f onl y th e fina l answe r appropriately

. 8. 1 Nomenclature

. Sem e a s Metho d5 , sectio n 6.1

. tn addition : B,-=Analysi s o f

reagen t blank , u g halid e ion0(Cl-.Br-.F-)/ml

. C=Concentratio n o f

hydroge n halid e (HX ) o r haloge n (X 2 ) , dr y basis , mg / dscm

. mnx=Mas s of

HCl

. HBr , o r

H Fi n sample , ug . m X2=Mas s of

C1 2 o r Br 2 i n sample , ug . Sx-=Analysi s o f

sample , u g halid e io n (Cl-,Br-.F-)/ml

. V s =Volume o f

filtere dan ddilute d sample , ml

. 8. 2 Averag e Dr

y Ga s Mete r Temperatur e an dAverag e Orific e Pressur e Drop , Se e dat ashee t (Figur e 5- 2 of Metho d5)

. 8. 3 Dr y Ga s Volume

. Calculat e Vm<uj ) an dadjus t

fo r leakage , i f necessary , usin g th e equatio n i n sectio n S. 3 of Metho d5

. 8. 4 Volum e o f

Water Vapo r an d Moistur e Content

. Calculat e th e volum e of

wate r vapo r y»( jU i ) an d moistur e conten t

B„ , fro mth e dat a obtaine di n thi s metho d(Figur e 5- 2 of Metho d5) ; us e Equation s 5- 2 an d5

- 3 of Metho d5

. 8. 5 Isokineti c Variatio n an d Acceptabl e Results

. Us e Metho d5

. section s 6.1 1 an d6.12

. 8. 6 Aceton e Blan

k Concentration

. Aceton e Was h Blank

Residu e Weight

. Particulat e Weight , an dParticulat e Concentration

. Fo r

particulat e determination

. 8. 7 Tota l u g HCl

. HBr , o r H F Pe r Sample

. m HX = K V , (S x ~ -B x - j Eq
. 26A- 4 where : KHC=1,02 8 (u g HCl/ug-mole)/(u g CI•" / ug-mole)

. KHB,=1.01 3 (u g HBr/ug-mole)/(u g Br - / ug-mole)

. K«F=1.0S 3 (u g HF/ug-mole)/(u g F~/ug

mole)

. 8. 8 Tota l u g Cl 2 o r

Br 2 Pe r Sample

. mx 2 =2V I (S x --Bx- ) Eq.26A- 5 8. 9 Concentratio n of

Hydroge n Halid e o r Haloge n i n Flu e Gas

. 4C=K mMxJCi/Vvnfstd

) Eq
. 26A- 6 where : K=10~ 3 mg/u gP.1 1



### 1171 8 Federa l Registe r7 Vol

. 58 , No
. 3 7 / Friday , Februar y 26 , 199 3 / Correction s 8.1 0 Stac k

Ga s Velocity an d Volumetri c Flo w Rat aCalculat e th e averag e stac k

ga s velocity an d volumetri c flo w rate , i f

needed , usin g dat aobtaine di n thi s metho dan dth e equation s i n section s 5. 2 an d5. 3 o f Metho d2

. 9. Bibliography 1

. Steinsberger , S. C an dJ.H
. Margeson
. Laboratory an dFiel dEvaluatio n of a Methodolog y fo

r Determinatio n of Hydroge n Chlorid e Emission s from Municipa l an dHazardou s Wast e Incinerators

. U.S

. Environmenta l Protectio n Agency , Offic e o f Researc h an dDevelopment

. Publicatio n No
. 600/3-89/064

. Apri l 1989

. Available ; fromNationa l Technica l Informatio n Service , Springfield , V

A 2216 1 a s PB89220586/AS

.

. Stat e of Californi aAi r

Resource s Board

. Metho d421—Determinatio n of Hydrochlori c Aci dEmission s fro m Stationar y Sources

. Marc h 18,1987

.

. Cheney , J.L
. an dCR

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. McGregor

. Spociatio n of

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. In : Incineratio n an d

. Treatmen t o f Hazardou s Waste : Proceeding s ofth e 9t h Annua l Researc h Symposium , Cincinnati , Ohio , Ma y 2-4,1983

. Publicatio n No
. 600/9-84-015

. Jul y 1984 . Availabl e fro mNationa l Technica l Informatio n Service , Springfield , V

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. an dS.A

. Barksdale

. Analysi s of

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. In : Io n Chromatographi c Analysi s of

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. Sawicki , J.D
. Mulik , an dE
. Wittgenstei n (eds.) J

. An n Arbor , Michigan ; An n Arbo r

Scienc e Publishers

. 1978

. pp . 99-110

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