# U.S. EPA Data Request

Emissions Test Report

Prepared for:



# Johns Manville

Defiance Complex

925 Carpenter Road (Plant 8)

Defiance, Ohio 43512

Project No. 11-4191.01

February 22, 2012

BT Environmental Consulting, Inc.

4949 Fernlee Avenue

Royal Oak, Michigan 48073

(248) 548-8070

## Johns ManvilleDefiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 i 

## Executive Summary

For the purpose of assisting in the developmen t of any emission standa rd under Section 7412 of

the Clean Air Act (CAA), Section 114 of the CAA gives the United States Environmental

Protection Agency (U.S. EPA) authority to requi re that persons who operate any emission source

“sample such emissions (in accordance with such procedures or methods, at such locations, at

such intervals, during such periods and in such manner as the Administrator shall prescribe)”

. Consistent with this authority, U.S. EPA has re quired that Johns Manville (JM) sample emissions

for the purpose of providing resi dual risk-related data for the National Emission Standards for

Hazardous Air Pollutants (NESHAP) for Wool Fiberglass Manufacturing 1



## .

To assist in collecting the ag reed upon data, BT Environmental Consulting, Inc. (BTEC) was

retained by JM to evaluate emission rates of the following pollutants from one exhaust stack

associated with the Line 89 Melter Dust Colle ctor located at the Johns Manville Complex in

Defiance, Ohio:

• Filterable particulate matter (PM) using U.S. EPA Methods 5/29

• Filterable chromium (FCr) using U.S. EPA Method 29

• Vaporous chromium (VCr) using U.S. EPA Method 29

• Total chromium (TCr) using U.S. EPA Method 29

• Hexavalent chromium (Cr +6 

## ) using SW-846 Method 0061

• TCr using SW-846 Method 0061

Table I on the following page summarizes the over all results of the emi ssions test program.

1 

## Codified at 40 CFR 63, Subpart NNN

## Johns ManvilleDefiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 ii 

## Table I

Overall Emissions Test Results Summary

Line 89 Melter Dust Collector

Test Dates: December 7 and 8, 2011

Test Methods Pollutant MDL

used Emission

Rate

(lbs/hour) Emission

Rate

(lbs/ton) Emission

Rate

(mg/dscm)

USEPA

Method 5/29 Filterable PM < 3.6 x 10 -2 

## 4.2 x 10 -1



## Filterable Chromium

(FCr) 6.9 x 10 -5 

## 8.2 x 10 -4



## Vaporous Chromium

(VCr) 6.6 x 10 -6 

## 7.8 x 10 -5 

## USEPA

Method 29

Total Chromium (TCr) 7.6 x 10 -5 

## 9.0 x 10 -4



## Hexavalent Chromium

(Cr +6 

## ) < 4.4 x 10 -6 

## 5.3 x 10 -5 

## USEPA

Method 0061 Total Chromium (TCr) < 9.3 x 10 -5 

## 1.1 x 10 -3



## Notes: (1) Pollutant emission rates in terms of mg/dscm were not corrected to 7% O 2 

## because exhaust from the

process is essentially ambient (i.e., approximately 20.9% O 2 

## ).

(2) The “less than” symbol (<) included in the table indicates that the emission rate was calculated using the method

detection limit (MDL) value instead of zero because the an alytical result was below the MDL for one or more of the

sample fractions.

## Johns ManvilleDefiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 iii 

## TABLE OF CONTENTS

1.0 INTRODUCTION............................................................................................................... 1

2.0 PROCESS DESCRIPTION ............................................................................................... 2

2.1 P ROCESS 

## M ONITORING 

## ....................................................................................................... 2

3.0 SAMPLING AND ANALYTICAL METHODOLOGIES.............................................. 2

3.1 E XHAUST 

## G AS 

## V ELOCITY



## , M OLECULAR 

## W EIGHT



## , AND 

## M OISTURE 

## C ONTENT 

## .................... 2

3.2 PM, FC R



## , VC R



## , AND 

## TC R 

## C ONCENTRATIONS AND 

## E MISSION 

## R ATES 

## ................................. 3

3.3 C R +6 

### AND 

## TC R 

## C ONCENTRATIONS AND 

## E MISSION 

## R ATES 

## ................................................... 4

4.0 TEST RESULTS ................................................................................................................. 4

TABLES

Table 1 – Test Personnel

Table 2 – Overall Emission Test Results Summary

Table 3 – Line 89 Melter Dust Collector Method 5/29 Emission Rate Results Summary

Table 3 – Line 89 Melter Dust Collector Method 0061 Emission Rate Results Summary

FIGURES

Figure 1 – Line 89 Melter Dust Collector (Stack 8901) Exhaust Stack Tr averse Point Diagram

Figure 2 – Method 3A Sampli ng Train Schematic Drawing

Figure 3 – Method 5/29 Sampli ng Train Schematic Drawing

Figure 4 – Method 0061 Sampli ng Train Schematic Drawing

APPENDICES

Appendix A – Field and Co mputer Generated Raw Data and Field Notes

Appendix B – Process Data

Appendix C – Equipment Calibration Documents

Appendix D – Laboratory Analytical Reports

## Johns Manville Defiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 1 

## 1.0 Introduction

For the purpose of assisting in the developmen t of any emission standa rd under Section 7412 of

the Clean Air Act (CAA), Section 114 of the CAA gives the United States Environmental

Protection Agency (U.S. EPA) authority to requi re that persons who operate any emission source

“sample such emissions (in accordance with such procedures or methods, at such locations, at

such intervals, during such periods and in such manner as the Administrator shall prescribe)”

. Consistent with this authority, U.S. EPA has re quired that Johns Manville (JM) sample emissions

for the purpose of providing resi dual risk-related data for the National Emission Standards for

Hazardous Air Pollutants (NESHAP) for Wool Fiberglass Manufacturing 2



## .

To assist in collecting the ag reed upon data, BT Environmental Consulting, Inc. (BTEC) was

retained by JM to evaluate emission rates of the following pollutants from one exhaust stack

associated with the Line 89 Melter Dust Collect or located at the Johns Manville (Johns Manville)

Complex in Defiance, Ohio:

• Filterable particulate matter (PM) using U.S. EPA Methods 5/29

• Filterable chromium (FCr) using U.S. EPA Method 29

• Vaporous chromium (VCr) using U.S. EPA Method 29

• Total chromium (TCr) using U.S. EPA Method 29

• Hexavalent chromium (Cr +6 

## ) using SW-846 Method 0061

• TCr using SW-846 Method 0061

The emissions test program was conducted on December 7 and 8, 2011. The test program

consisted of triplicate 240-minute emission tests for each parameter. The field sampling portion

of the emissions test program included the personnel summarized by Table 1.

Table 1

Emissions Test Program Personnel

Personnel Affiliation

Barry Boulianne BTEC

James Sharp BTEC

Matthew Young BTEC

Paul Draper BTEC

Paul Molenda BTEC

Jim Smargiassi

Adam Vega Johns Manville

Johns Manville

2 

## Codified at 40 CFR 63, Subpart NNN

## Johns Manville Defiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 2 

## 2.0 Process Description

The Line 89 electric melter charges batch and cu llet and feeds to a natural forehearth which

distributes the glass to a series of fiberizing rotary discs wh ich attenuate the fibers onto a

collection mat. The collected mat enters a curing oven to thermally set the binder and then enters

a cooling table prior to being cut and packaged.

A schematic drawing showing traverse point loca tions for the stack eval uated is available as

Figure 1.

2.1 Process Monitoring

Process and control equipment data collected duri ng the emissions test program, as well as the

frequency of data collect ion, includes the following:

(1) Glass Pull Rate (tons/hr), 15-min

(2) Baghouse Pressure Drop, 15-min

Process production data is availabl e in Appendix B. Control equipm ent data will be available to

U.S. EPA on request.

3.0 Sampling and Analytical Methodologies

Sampling and analytical methodologies for the em issions test program can be separated into

three categories as follows:

(1) Measurement of exhaust gas velocity, mo lecular weight, and moisture content;

(2) Measurement of exhaust gas PM, FCr, VCr, and TCr concentrations and emission rates

using Methods 5/29; and

(3) Measurement of exhaust gas CR +6 

## and TCr concentrations and emission rates using

Method 0061.

Descriptions of sampling and analytical methodologies by cate gory are summarized by Sections

3.1 through 3.3, respectively.

3.1 Exhaust Gas Velocity, Molecular Weight, and Moisture Content

Measurement of exhaust gas velocity, molecula r weight, and moisture content were conducted

using the following reference test methods codifi ed at Title 40, Part 60, Appendix A of the Code

of Federal Regulations (40 CFR 60, Appendix A):

• Method 1 - “Location of the Sampling Site and Sampling Points”

• Method 2 - “Determination of Stack Gas Velo city and Volumetric Flowrate”

• Method 3A - “Determination of Molecula r Weight of Dry Stack

Gas”(Integrated tedlar bags)

• Method 4 - “Determination of Moisture Content in Stack Gases”

## Johns Manville Defiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 3 

## These test methods were used to evaluate e xhaust gas flowrates in conjunction with the

isokinetic sampling methodologies.

Stack gas velocity traverses we re conducted in accordance with the procedures outlined in

Method 1 and Method 2 (see Figure 1 for a traverse location drawing). An S-type pitot tube with

a thermocouple assembly, calibrated in accordance with Method 2, Section 4.1.1, was used to

measure exhaust gas velocity pressures (using a manometer) and temperatures at each location

during testing. The S-type pito t tube dimensions was within specified limits, therefore, a

baseline pitot tube coefficient of 0.84 (dimensionless) was assigned.

Molecular weight was determined according to USEPA Method 3A, “Determination of Oxygen

and Carbon Dioxide Concentrations in Emi ssions from Stationary Sources”. The O 2 

## content of

the exhaust gas was measured us ing an M&C Products PMA 100-L O 2 

## gas analyzer and the CO 2 

## content of the exhaust gas was measured usi ng a California Analytical Instruments (CAI) 600

Series CO 2 

## gas analyzer. A sample of the gas streamwas drawn through an insulated stainlesssteel probe into an integrated tedlar bag by th e use of a vacuum sample lung. The sample was

then connected to sample conditioner to remove the moisture from the sample before it entered

the analyzers. Data was recorded at 4-second intervals on a PC equipped with data acquisition

software.

For O 2 

## and CO 2 

## analyzer calibrations, calibration gases were mixed to desi red concentrations

using an Environics Series 4040 Computerized Gas Dilution System . The Series 4040 consists

of a single chassis with four mass flow controll ers. The mass flow controllers are factorycalibrated using a primary flow standard traceable to the United State's National Institute of

Standards and Technology (NIST). Each flow c ontroller utilizes an 11 -point calibration table

with linear interpolation, to increase accuracy and reduce flow controller nonlinearity.

Exhaust gas moisture content was evaluated usin g Method 4. Exhaust gas moisture content was

determined gravimetrically.

3.2 

## PM, FCr, VCr, and TCr Concen trations and Emission Rates

PM, FCr, VCr, and TCr concentrations and emi ssion rates were measured using the procedures

of 40 CFR 60, Appendix A, Methods 5 and 29. Se lected metals concentrations and emission

rates were measured using BTEC’s Nutech ® Model 2010 modular isokinetic stack sampling

system. This system consisted of (1) a borosi licate glass or quartz no zzle, (2) a steel probe

w/glass liner, (3) a heated quartz fiber filter assembly, (4) a set of four GS impingers, (5) a

length of sample line, and (6) a Nutech ® control case equipped with a pump, dry gas meter, and

calibrated orifice. Prior to each test, the first two impingers were filled with 100 ml of a 5%

nitric acid (HNO 3 

## )/10% hydrogen peroxide solution, the third impinger was empty, and the

fourth contained approximately 300 g of silica gel desiccant. A schematic drawing of the

PM/metals sampling train is provided as Figure 3.

## Johns Manville Defiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 4 

## 3.3 Cr +6 

## and TCr Concentrations and Emission Rates

Measurement of Cr +6 

## and TCr concentrations and emissi on rates were measured using the

procedures Method 0061. Cr +6 

## and TCr concentrations and emission rates were measured using

BTEC’s Nutech ® Model 2010 modular isokinetic stack samp ling system. This system consisted

of (1) a glass nozzle, (2) a heated steel probe with a glass probe liner, (4) a Teflon tee with a

recirculating pump, (5) five GS impingers, (6 ) a length of sample line, and (7) a Nutech ® control

case equipped with a pump, dry gas meter, and calibrated orifice. Prior to each test, the first

impinger was filled with 150 mL of 0.1N KOH, the next two were fille d with 75 mL of 0.1 N

KOH, the fourth was empty, and the last impinge r contained approximately 300 g of silica gel

desiccant. A schematic drawing of the Me thod 0061 sampling train is provided as Figure 4.

4.0 Test Results

The overall results of the emissions te st program are summarized by Table 2.

Table 2

Overall Emissions Test Results Summary

Line 89 Melter Dust Collector

Test Methods Pollutant MDL

used Emission

Rate

(lbs/hour) Emission

Rate

(lbs/ton) Emission

Rate

(mg/dscm)

USEPA

Method 5/29 Filterable PM < 3.6 x 10 -2 

## 4.2 x 10 -1



## Filterable Chromium

(FCr) 6.9 x 10 -5 

## 8.2 x 10 -4



## Vaporous Chromium

(VCr) 6.6 x 10 -6 

## 7.8 x 10 -5 

## USEPA

Method 29

Total Chromium (TCr) 7.6 x 10 -5 

## 9.0 x 10 -4



## Hexavalent Chromium

(Cr +6 

## ) < 4.4 x 10 -6 

## 5.3 x 10 -5 

## USEPA

Method 0061 Total Chromium (TCr) < 9.3 x 10 -5 

## 1.1 x 10 -3



## Notes: (1) Pollutant emission rates in terms of mg/dscm were not corrected to 7% O 2 

## because exhaust from the

process is essentially ambient (i.e., approximately 20.9% O 2 

## ).

(2) The “less than” symbol (<) included in the table indicates that the emission rate was calculated using the method

detection limit (MDL) value instead of zero because the an alytical result was below the MDL for one or more of the

sample fractions.



## Detailed results for individual emission test r uns are summarized in Table 3. Field and

computer-generated data sheets are included in Appendix A. Process data associated with the

emissions test program is provided in Appe ndix B. Equipment calibration documents are

provided in Appendix C. Labor atory analytical results are available in Appendix D.

## Johns Manville Defiance BTEC Project No. 11-4191.01

U.S. EPA Emissions Test Report February 22, 2012 5 

## Limitations

The information and opinions rendered in this re port are exclusively for use by Johns Manville.

BTEC will not distribute or pub lish this report without Johns Manville’s consent except as

required by law or court order. BTEC accepts re sponsibility for the competent performance of

its duties in executing the assignment and prep aring reports in accordance with the normal

standards of the profession, but disclaims a ny responsibility for consequential damages.

This report was prepared by:

Brandon Chase

Staff Environmental Engineer

This report was reviewed by:

Randal J. Tysar

Senior Environmental Engineer

# TablesTable 3

Line 89 Melter Dust Collector Method 5/29 Emission Rate Results Summary

Company JM Defiance

Source Designation 89 melter dust collector

Test Date 12/7/2011 12/8/2011 12/8/2011

Meter/Nozzle Information P-1 P-2 P-3 Average

Meter Temperature Tm (F) 69.5 69.2 73.3 70.7

Meter Pressure - Pm (in. Hg) 30.2 30.4 30.4 30.3

Measured Sample Volume (Vm) 204.1 200.4 203.7 202.7

Sample Volume (Vm-Std ft3) 205.8 203.2 205.0 204.7

Sample Volume (Vm-Std m3) 5.83 5.75 5.80 5.80

Condensate Volume (Vw-std) 1.900 2.117 2.282 2.100

Gas Density (Ps(std) lbs/ft3) (wet) 0.0744 0.0743 0.0743 0.0743

Gas Density (Ps(std) lbs/ft3) (dry) 0.0746 0.0746 0.0746 0.0746

Total weight of sampled gas (m g lbs) (wet) 15.44 15.25 15.40 15.36

Total weight of sampled gas (m g lbs) (dry) 15.36 15.15 15.30 15.27

Nozzle Size - An (sq. ft.) 0.000392 0.000392 0.000392 0.000392

Isokinetic Variation - I 92.6 93.0 93.4 93.0

Production Data

Production Data (lb/hr)

Stack Data

Average Stack Temperature - Ts (F) 108.3 110.8 109.8 109.6

Molecular Weight Stack Gas- dry (Md) 28.9 28.8 28.9 28.9

Molecular Weight Stack Gas-wet (Ms) 28.8 28.7 28.8 28.8

Stack Gas Specific Gravity (Gs) 0.994 0.992 0.993 0.993

Percent Moisture (Bws) 0.91 1.03 1.10 1.02

Water Vapor Volume (fraction) 0.0091 0.0103 0.0110 0.0102

Pressure - Ps ("Hg) 30.0 30.2 30.2 30.1

Average Stack Velocity -Vs (ft/sec) 42.7 42.0 42.1 42.2

Area of Stack (ft2) 9.6 9.6 9.6 9.6

Exhaust Gas Flowrate

Flowrate f t 3 ( Actual ) 24,60 8 24,213 24,289 24,37 0

Flowrate f t 3 ( Standard Wet ) 22,927 22,57 8 22,687 22,73 1

Flowrate f t 3 ( Standard Dr y) 22,717 22,34 5 22,43 8 22,50 0

Flowrate m 3 ( standard dr y) 643 633 63 5 637

Total Particulate Weights (mg)

Acetone Rinse 3.6 1.5 1.3 2.1

Filter < 0.3 < 0.3 < 0.3 0.3

Total < 3.9 < 1.8 < 1.6 2.4

Total Particulate Concentration

lb/1000 lb (wet) < 5.6E-04 < 2.6E-04 < 2.3E-04 3.5E-04

lb/1000 lb (dry) < 5.6E-04 < 2.6E-04 < 2.3E-04 3.5E-04

mg/dscm (dry) < 6.7E-01 < 3.1E-01 < 2.8E-01 4.2E-01

gr/dscf < 2.9E-04 < 1.4E-04 < 1.2E-04 1.8E-04

Total Particulate Emission Rate

lb/ hr < 5.7E-02 < 2.6E-02 < 2.3E-02 3.6E-02

lb/ ton product

Filterable Chromium Weights (ug)

Front Half Chromium (Filterable) 6.22 4.62 3.42 4.75

Filterable Chromium Concentrations

lb/1000 lb (wet) 8.9E-07 6.7E-07 4.9E-07 6.8E-07

lb/1000 lb (dry) 8.9E-07 6.7E-07 4.9E-07 6.9E-07

mg/dscm (dry) 1.1E-03 8.0E-04 5.9E-04 8.2E-04

gr/dscf 4.7E-07 3.5E-07 2.6E-07 3.6E-07

Filterable Chromium Emission Rate

lb/ hr 9.1E-05 6.7E-05 5.0E-05 6.9E-05

lb/ ton product

Vaporous Chromium Weights (ug)

Back Half Chromium (Vaporous) 0.40 0.68 0.27 0.45

Vaporous Chromium Concentrations

lb/1000 lb (wet) 5.7E-08 9.8E-08 3.9E-08 6.5E-08

lb/1000 lb (dry) 5.7E-08 9.9E-08 3.9E-08 6.5E-08

mg/dscm (dry) 6.9E-05 1.2E-04 4.7E-05 7.8E-05

gr/dscf 3.0E-08 5.2E-08 2.0E-08 3.4E-08

Vaporous Chromium Emission Rate

lb/ hr 5.9E-06 9.9E-06 3.9E-06 6.6E-06

lb/ ton product

Total Chromium Weights (ug)

Total Chromium 6.62 5.30 3.69 5.20

Total Chromium Concentrations

lb/1000 lb (wet) 9.4E-07 7.7E-07 5.3E-07 7.5E-07

lb/1000 lb (dry) 9.5E-07 7.7E-07 5.3E-07 7.5E-07

mg/dscm (dry) 1.1E-03 9.2E-04 6.4E-04 9.0E-04

gr/dscf 5.0E-07 4.0E-07 2.8E-07 3.9E-07

Total Chromium Emission Rate

lb/ hr 9.7E-05 7.7E-05 5.4E-05 7.6E-05

lb/ ton productTable 4

Line 89 Melter Dust Collector Method 0061 Emission Rate Results Summary

Company JM Defiance

Source Designation 89 melter dust collector

Test Date 12/7/2011 12/8/2011 12/8/2011

Meter/Nozzle Information P-1 P-2 P-3 Average

Meter Temperature Tm (F) 73.3 72.3 77.2 74.3

Meter Pressure - Pm (in. Hg) 30.2 30.3 30.3 30.3

Measured Sample Volume (Vm) 209.2 195.3 196.6 200.4

Sample Volume (Vm-Std ft3) 209.8 197.0 196.5 201.1

Sample Volume (Vm-Std m3) 5.94 5.58 5.56 5.69

Condensate Volume (Vw-std) 1.919 2.122 2.037 2.026

Gas Density (Ps(std) lbs/ft3) (wet) 0.0744 0.0743 0.0743 0.0743

Gas Density (Ps(std) lbs/ft3) (dry) 0.0746 0.0746 0.0746 0.0746

Total weight of sampled gas (m g lbs) (wet) 15.74 14.79 14.76 15.10

Total weight of sampled gas (m g lbs) (dry) 15.65 14.69 14.66 15.00

Nozzle Size - An (sq. ft.) 0.000366 0.000366 0.000366 0.000366

Isokinetic Variation - I 99.0 100.0 100.0 99.7

Production Data

Production Data (lb/hr)

Stack Data

Average Stack Temperature - Ts (F) 109.1 111.0 110.4 110.2

Oxygen Concentration (%) 20.6 21.1 21.0

Molecular Weight Stack Gas- dry (Md) 28.9 28.8 28.9 28.9

Molecular Weight Stack Gas-wet (Ms) 28.8 28.7 28.8 28.8

Stack Gas Specific Gravity (Gs) 0.994 0.992 0.993 0.993

Percent Moisture (Bws) 0.91 1.07 1.03 1.00

Water Vapor Volume (fraction) 0.0091 0.0107 0.0103 0.0100

Pressure - Ps ("Hg) 30.0 30.2 30.2 30.1

Average Stack Velocity -Vs (ft/sec) 43.6 40.5 40.4 41.5

Area of Stack (ft2) 9.6 9.6 9.6 9.6

Exhaust Gas Flowrate

Flowrate ft 3 (Actual) 25,17 1 23,39 4 23,29 0 23,95 2

Flowrate ft 3 (Standard Wet) 23,41 6 21,808 21,73 2 22,31 9

Flowrate ft 3 (Standard Dry) 23,20 4 21,57 6 21,50 9 22,09 6

Flowrate m 3 (standard dry) 657 61 1 60 9 62 6

Total Hexavalent Chromium Weight (ug)

Hexavalent Chromium < 0.30 < 0.30 < 0.30 0.30

Total Hexavalent Chromium Concentration

lb/1000 lb (wet) < 4.2E-08 < 4.5E-08 < 4.5E-08 4.4E-08

lb/1000 lb (dry) < 4.2E-08 < 4.5E-08 < 4.5E-08 4.4E-08

mg/dscm (dry) < 5.1E-05 < 5.4E-05 < 5.4E-05 5.3E-05

Total Hexavalent Chromium Emission Rate

lb/ hr < 4.4E-06 < 4.4E-06 < 4.4E-06 4.4E-06

lb/ ton product

Total Chromium Weight (ug)

Back Half Chromiu m < 4.00 < 4.00 < 4.00 4.00

Front Half Chromium 0.50 < 0.30 < 0.30 0.37

Rinse Chromium < 2.00 < 2.00 < 2.00

Total Chromium < 6.50 < 6.30 < 6.30 6.37

Total Chromium Concentration

lb/1000 lb (wet) < 9.1E-07 < 9.4E-07 < 9.4E-07 9.3E-07

lb/1000 lb (dry) < 9.2E-07 < 9.5E-07 < 9.5E-07 9.4E-07

mg/dscm (dry) < 1.1E-03 < 1.1E-03 < 1.1E-03 1.1E-03

Total Chromium Emission Rate

lb/ hr < 9.5E-05 < 9.2E-05 < 9.2E-05 9.3E-05

lb/ ton product

# Figures

### diameter = 42"

Points Distance "

12 0.9

11 2.8

10 5.0

9 7.4

8 10.5

7 15.0

6 27.0

5 31.5

4 34.6

3 37.0

2 39.2

1 41.1



## Figure 1

Site: Sampling Dates:

Johns Manv ille December 7-8, 2011

Defiance, Ohio

Line 89 Melter BT Environmental Consulting,

Inc.

4949 Fernlee Avenue

Royal Oak, Michigan Not to Scale <0.5 diameters

<2 diameters

### Bags Samples

to analyzers



## Figure 2

Site: Sampling Dates:

USEPA Method 3 A December 7-8, 2011

Johns Manville

Defiance, Ohio BT Environmental Consulting, Inc.

4949 Fernlee Avenue

Royal Oak, Michigan Data Acquisition System



### Calibration Gases

(Fed to Probe Tip) Environics Gas

Dilution System M&C Model 100-L

O

2 

### Analyzer CAI Series 600

CO

2 

### Analyzer pump tedlar

bagFigure 3Site: Sampling Dates:USEPA Methods 5/29December 7-8, 0211Johns ManvilleDefiance, OhioBT Environmental Consulting Inc.4949 Fernlee AvenueRoyal Oak, Michigan 48073PumpSilica gel100 mL 5% HNO3 / 10% H2O2 solutionHeated Filter BoxS-Type Pitot w/ ThermocoupleHeated Probe w/ Glass Liner & NozzleMeter RigTemp.ProbeFilterOnOff-+00:001 2 3 4 5Figure 4Site: Sampling Dates:USEPA Method 0061 December 7-8, 2011Johns ManvilleDefiance, OhioBT Environmental Consulting, Inc.4949 Fernlee AvenueRoyal Oak, MichiganPumpMeter RigTemp.ProbeFilterOnOff-+00:001 2 3 4 5150 mL 0.1 N KOHEmptySilica GelPerastaltic pumpTeflon tee75 mL 0.1 N KOH

# Appendix A

Field and Computer Generate d Raw Data and Field NotesCompanyJM DefianceSource Designation89 melter dust collectorTest Date12/7/2011Assumed Moisture (Bws)2Test NumberM29-R1Condensate Volume (Vlc)10.7OperatorPM/BB/PDSilica Gel Weight Gain (Vlc)29.6Filter Number11081884Nozzle Diameter (in.)0.268Barometric Pressure (Pb)30.02Leak Rate Initial.001@15"Stack Static Pressure (Pg)-0.26Leak Rate Final.000@8"Stack Dimensions 1 (in.)42Traverse points24*Stack Dimensions 2 (in.) Pitot Corr. Factor (Cp)0.84Pitot Tube Number5'FMeter Corr. Factor (Y)1.002Meter NumberMB 4Orsat Results (%)Meter Isokinetic Factor (Kiso)-CO20.3Delta∆H@1.7O220.6Traverse Sampling Time Sampling Stack Temp.Velocity Pres.Desired Orifice Actual Orifice Sample VolumeDry Gas Meter Temp. Last Impinger Probe Filter Box Expected IsokineticPoint (Minutes) Clock Time Train Vac. (F) ("H2O) Differential Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature DGM VariationNumber ø (24 hour) ("Hg) Ts∆Ps ("H2O)∆H ("H2O)∆H Vm (F) Tm (F) Tm (F) (F) (F) (cubic feet) %10 16:15 5 110 0.42 1.97 1.83 854.86 71 64 62 250 251 858.87 95.325 5 111 0.42 1.97 1.83 858.68 63 64 49 247 250 862.65 94.1310 5 111 0.43 2.02 1.87 862.42 66 64 47 249 250 866.45 94.5415 5 111 0.43 2.02 1.86 866.23 67 65 48 250 250 870.27 93.8520 5 110 0.41 1.92 1.78 870.02 68 67 50 249 250 873.98 94.2625 4 110 0.41 1.92 1.78 873.75 69 65 52 250 250 877.70 93.5730 4 110 0.44 2.07 1.91 877.45 70 65 53 251 250 881.55 92.6835 4 110 0.44 2.07 1.91 881.25 71 66 54 252 250 885.36 93.2940 5 109 0.58 2.72 2.52 885.08 72 66 54 250 250 889.80 94.11045 5 109 0.58 2.72 2.52 889.52 72 66 54 249 250 894.24 93.21150 5 109 0.59 2.77 2.57 893.92 73 67 55 251 250 898.69 92.71255 5 110 0.59 2.77 2.57 898.34 73 67 55 251 250 903.11 93.21360 6 110 0.59 2.77 2.57 902.78 73 67 56 250 250 907.55 93.61465 6 110 0.59 2.77 2.57 907.24 74 67 56 248 250 912.01 93.91570 6 109 0.57 2.68 2.49 911.72 74 68 56 250 250 916.42 93.31675 6 109 0.57 2.68 2.49 916.10 73 68 56 252 250 920.80 92.91780 6 109 0.53 2.49 2.32 920.46 73 68 56 250 250 924.99 92.81885 6 109 0.53 2.49 2.32 924.66 73 68 56 249 250 929.19 94.11990 6 109 0.51 2.39 2.23 928.92 74 68 56 249 250 933.37 93.82095 6 109 0.51 2.39 2.23 933.09 74 68 56 250 250 937.54 94.021100 5 108 0.51 2.39 2.23 937.27 74 68 55 250 250 941.72 92.822105 5 109 0.51 2.39 2.23 941.40 73 68 55 250 250 945.84 94.123110 5 109 0.51 2.39 2.23 945.58 74 68 55 250 250 950.03 92.724115 18:15 5 108 0.51 2.39 2.23 949.70 74 68 55 249 250 954.15 93.0120 18:34953.841120 7 107 0.65 3.05 2.85 954.52 68 67 55 247 250 959.52 93.82125 7 108 0.65 3.05 2.85 959.20 70 68 51 250 250 964.21 94.53130 7 107 0.65 3.05 2.86 963.92 72 67 51 250 250 968.93 93.94135 7 107 0.65 3.05 2.86 968.62 72 68 52 250 250 973.64 93.45140 7 107 0.63 2.96 2.76 973.30 72 68 52 250 250 978.24 93.26145 7 107 0.63 2.96 2.76 977.90 73 68 53 250 250 982.85 92.97150 7 107 0.63 2.96 2.76 982.49 73 68 53 250 250 987.44 92.58155 7 107 0.63 2.96 2.76 987.06 73 68 53 253 250 992.01 95.09160 7 107 0.63 2.96 2.76 991.75 73 68 53 251 250 996.70 94.010165 7 107 0.63 2.96 2.76 996.39 73 68 54 251 250 1001.34 94.011170 7 107 0.61 2.86 2.67 1001.03 72 68 54 248 250 1005.89 94.112175 7 107 0.61 2.86 2.67 1005.60 72 68 54 250 250 1010.46 93.913180 6 107 0.53 2.49 2.32 1010.16 72 68 54 251 250 1014.69 93.114185 6 107 0.53 2.49 2.32 1014.380 72 68 54 251 250 1018.91 92.915190 5 107 0.5 2.35 2.2 1018.590 72 68 54 250 250 1022.99 94.116195 5 107 0.5 2.36 2.2 1022.730 72 68 54 250 250 1027.13 93.817200 5 107 0.48 2.26 2.12 1026.860 72 68 53 249 250 1031.17 93.218205 5 107 0.48 2.27 2.12 1030.880 72 68 53 250 250 1035.19 93.019210 5 107 0.48 2.27 2.12 1034.890 72 68 53 250 250 1039.20 93.020215 5 107 0.48 2.27 2.12 1038.900 72 68 53 250 250 1043.21 93.421220 5 107 0.52 2.46 2.3 1042.930 72 68 53 250 250 1047.42 93.622225 5 106 0.52 2.47 2.3 1047.130 72 67 53 250 250 1051.62 92.923230 5 107 0.52 2.47 2.3 1051.300 72 67 53 249 250 1055.79 93.224235 5 107 0.52 2.47 2.3 1055.480 72 67 53 250 250 1059.97 92.3240 20:341059.620Average 240 108.3 0.54 2.53 2.36 204.080 71.8 67.2 53.7 249.9 250.0 958.4 93.569.50CompanyJM DefianceSource Designation89 melter dust collectorTest Date12/8/2011Assumed Moisture (Bws)2Test NumberM29-R2Condensate Volume (Vlc)16.3OperatorPM/PDSilica Gel Weight Gain (Vlc)28.6Filter Number11081883Nozzle Diameter (in.)0.268Barometric Pressure (Pb)30.18Leak Rate Initial.001@15"Stack Static Pressure (Ps)-0.26Leak Rate Final.001@10"Stack Dimensions 1 (in.)42Traverse points24*Stack Dimensions 2 (in.) Pitot Corr. Factor (Cp)0.84Pitot Tube Number5ft FMeter Corr. Factor (Y)1.002Meter NumberMB 5Orsat Results (%)Meter Isokinetic Factor (Kiso) CO20Delta∆H@1.7O221.1Traverse Sampling Time Sampling Stack Temp.Velocity Pres.Desired Orifice Orifice Sample VolumeDry Gas Meter Temp. Last Impinger Probe Filter Box Expected IsokineticPoint (Minutes) Clock Time Train Vac. (F) ("H2O) Differential Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature DGM VariationNumber ø (24 hour) ("Hg) Ts∆Ps ("H2O)∆H ("H2O)∆H Vm (F) Tm (F) Tm (F) (F) (F) (cubic feet) %10 8:00 2 110 0.53 2.48 2.28 60.21 60 60 57 256 258 64.64 92.925 2 110 0.53 2.48 2.28 64.32 61 60 48 249 250 68.75 92.6310 2 110 0.53 2.48 2.28 68.42 61 60 48 248 250 72.85 93.0415 2 110 0.53 2.48 2.28 72.54 64 61 42 249 250 76.99 93.4520 2 110 0.55 2.58 2.38 76.69 66 61 43 250 250 81.23 93.5625 2 110 0.55 2.58 2.38 80.93 68 61 43 251 250 85.48 93.7730 2 111 0.54 2.54 2.34 85.19 69 32 44 250 250 89.57 94.1835 2 111 0.54 2.54 2.34 89.31 70 63 44 251 250 93.83 93.9940 2 111 0.54 2.55 2.34 93.55 70 63 44 251 250 98.07 93.01045 2 111 0.54 2.55 2.35 97.75 70 63 44 250 250 102.27 93.01150 2 111 0.52 2.46 2.27 101.95 71 64 45 250 250 106.39 93.01255 2 111 0.52 2.46 2.27 106.08 72 65 45 251 250 110.53 92.61360 2 111 0.48 2.27 1.97 110.20 72 65 45 249 249 114.48 93.31465 2 111 0.48 2.28 2.11 114.19 72 66 45 251 250 118.47 93.91570 2 110 0.45 2.14 1.98 118.21 72 66 45 251 250 122.36 94.01675 2 111 0.45 2.14 1.98 122.11 72 66 45 250 250 126.26 93.81780 2 111 0.45 2.14 1.98 126.00 73 67 45 250 250 130.15 93.91885 2 111 0.45 2.14 1.98 129.90 73 67 45 250 250 134.05 93.91990 2 111 0.44 2.10 1.95 133.80 73 67 45 250 250 137.91 93.22095 2 111 0.44 2.10 1.95 137.63 73 67 45 250 250 141.74 93.221100 2 111 0.42 2.01 1.87 141.46 73 68 46 250 250 145.48 93.822105 2 111 0.42 2.01 1.87 145.23 73 67 45 250 250 149.24 93.723110 2 110 0.42 2.01 1.87 148.99 73 67 45 250 250 153.01 93.824115 2 109 0.42 2.02 1.91 152.76 73 68 46 250 250 156.78 94.4120 10:00156.561120 10:09 2 110 0.53 2.55 2.41 156.83 70 68 48 249 250 161.33 93.32125 2 110 0.53 2.55 2.41 161.03 71 68 46 250 250 165.54 93.93130 2 109 0.53 2.55 2.41 165.26 73 68 44 249 250 169.78 93.94135 3 109 0.53 2.56 2.42 169.50 73 68 44 250 250 174.02 93.95140 3 109 0.55 2.66 2.52 173.74 74 68 45 250 250 178.35 94.16145 3 110 0.55 2.66 2.52 178.07 74 68 46 249 249 182.67 94.17150 4 110 0.54 2.61 2.48 182.40 74 68 46 250 249 186.96 93.98155 4 110 0.54 2.62 2.48 186.68 74 68 46 250 250 191.24 93.99160 4 111 0.57 2.77 2.62 190.96 74 69 47 250 250 195.65 94.610165 4 111 0.57 2.77 2.63 195.390 74 69 47 251 250 200.08 94.211170 4 111 0.58 2.82 2.68 199.800 74 69 47 250 250 204.53 94.212175 4 111 0.58 2.82 2.68 204.250 75 69 47 249 250 208.98 94.613180 3 111 0.55 2.68 2.54 208.720 76 70 47 250 250 213.34 94.714185 3 112 0.55 2.68 2.54 213.090 76 70 47 250 250 217.70 94.415190 3 112 0.54 2.64 2.5 217.440 76 70 47 250 250 222.01 94.416195 3 112 0.54 2.64 2.5 221.750 76 70 47 250 250 226.32 94.417200 3 112 0.54 2.64 2.51 226.060 76 70 47 250 250 230.63 93.918205 3 112 0.54 2.65 2.51 230.350 76 70 47 250 250 234.92 93.919210 3 112 0.55 2.70 2.56 234.640 76 70 47 251 250 239.25 94.020215 3 112 0.55 2.70 2.56 238.970 76 70 47 250 251 243.58 94.021220 3 112 0.56 2.75 2.6 243.300 76 71 47 249 250 247.96 93.922225 3 112 0.56 2.76 2.62 247.670 76 71 48 250 250 252.33 93.923230 3 112 0.56 2.76 2.62 252.040 76 71 48 250 250 256.70 94.324235 3 112 0.56 2.76 2.63 256.430 76 72 48 250 250 261.09 94.7240 12:09260.840Average 240 110.8 0.52 2.50 2.34 200.360 72 66 46 250 250 161 9469.22CompanyJM DefianceSource Designation89 melter dust collectorTest Date12/8/2011Assumed Moisture (Bws)2Test NumberM29-R3Condensate Volume (Vlc)16.5OperatorPM/PDSilica Gel Weight Gain (Vlc)31.9Filter Number11081882Nozzle Diameter (in.)0.268Barometric Pressure (Pb)30.18Leak Rate Initial.001@15"Stack Static Pressure (Ps)-0.26Leak Rate Final.000@6"Stack Dimensions 1 (in.)42Traverse points24*Stack Dimensions 2 (in.) Pitot Corr. Factor (Cp)0.84Pitot Tube Number5ft FMeter Corr. Factor (Y)1.002Meter NumberMB 5Orsat Results (%)Meter Isokinetic Factor (Kiso) CO20.2Delta∆H@1.7O221Traverse Sampling Time Sampling Stack Temp.Velocity Pres.Desired Orifice Orifice Sample VolumeDry Gas Meter Temp. Last Impinger Probe Filter Box Expected IsokineticPoint (Minutes) Clock Time Train Vac. (F) ("H2O) Differential Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature DGM VariationNumber ø (24 hour) ("Hg) Ts∆Ps ("H2O)∆H ("H2O)∆H Vm (F) Tm (F) Tm (F) (F) (F) (cubic feet) %10 12:45 4 110 0.51 2.40 2.26 261.16 68 69 58 251 252 265.57 93.725 4 110 0.51 2.40 2.26 265.29 68 68 54 252 251 269.70 94.2310 4 110 0.51 2.40 2.26 269.44 68 68 49 249 250 273.85 94.0415 4 109 0.51 2.40 2.26 273.58 71 68 47 250 251 278.00 95.0520 4 109 0.54 2.55 2.41 277.78 74 68 48 249 250 282.34 94.7625 4 109 0.54 2.55 2.40 282.10 74 68 48 249 250 286.66 94.3730 4 109 0.55 2.59 2.45 286.40 75 69 48 250 250 291.01 93.9835 4 109 0.55 2.59 2.45 290.73 75 69 48 252 250 295.34 94.3940 4 109 0.56 2.64 2.50 295.08 75 69 48 250 250 299.74 94.41045 4 109 0.56 2.64 2.49 299.47 76 70 48 250 250 304.14 94.01150 4 109 0.54 2.55 2.41 303.85 76 70 48 250 250 308.43 93.91255 4 110 0.54 2.55 2.41 308.15 76 70 48 251 250 312.73 94.01360 4 110 0.55 2.59 2.46 312.45 76 70 48 250 250 317.07 93.81465 4 110 0.55 2.59 2.45 316.78 76 70 48 250 250 321.40 94.01570 4 110 0.54 2.55 2.41 321.12 77 71 48 250 250 325.71 94.31675 4 110 0.54 2.55 2.41 325.44 77 71 48 250 250 330.03 94.31780 4 110 0.55 2.59 2.46 329.76 77 71 49 250 250 334.39 94.31885 4 110 0.55 2.59 2.46 334.12 77 71 49 250 250 338.75 94.31990 4 110 0.54 2.55 2.41 338.48 77 71 49 250 250 343.07 94.32095 4 110 0.54 2.55 2.41 342.80 77 71 49 250 250 347.39 94.721100 4 110 0.53 2.50 2.37 347.14 77 71 49 250 250 351.68 94.322105 4 110 0.53 2.50 2.37 351.42 76 71 49 250 250 355.96 93.923110 4 110 0.53 2.50 2.37 355.68 76 72 48 250 250 360.22 94.124115 4 110 0.53 2.50 2.37 359.95 76 71 49 250 250 364.49 93.9120 14:45 364.211120 14:52 4 110 0.56 2.64 2.51 364.32 73 71 52 250 250 368.97 94.52125 3 110 0.56 2.64 2.50 368.71 74 71 51 250 250 373.37 93.93130 3 110 0.56 2.64 2.50 373.08 75 71 48 250 250 377.74 93.84135 3 110 0.56 2.64 2.50 377.45 76 71 49 250 250 382.12 94.25140 3 110 0.58 2.74 2.60 381.84 77 71 49 250 250 386.59 94.46145 3 110 0.58 2.74 2.59 386.32 77 71 50 250 250 391.07 94.87150 3 110 0.56 2.64 2.51 390.82 77 72 50 250 250 395.49 94.78155 3 110 0.56 2.64 2.50 395.24 77 72 51 250 250 399.91 94.79160 3 110 0.55 2.59 2.46 399.66 77 72 51 250 250 404.29 94.610165 3 110 0.55 2.59 2.46 404.040 77 72 51 250 250 408.67 94.211170 3 110 0.54 2.55 2.42 408.400 77 72 51 250 250 412.99 94.012175 3 110 0.54 2.55 2.42 412.710 77 72 51 250 250 417.30 94.013180 3 110 0.48 2.26 2.15 417.020 78 72 51 250 250 421.35 93.514185 3 110 0.48 2.27 2.15 421.070 78 72 51 250 250 425.40 93.515190 3 110 0.46 2.17 2.07 425.120 77 72 51 250 250 429.36 93.916195 3 110 0.46 2.18 2.07 429.100 77 72 51 250 250 433.34 94.417200 3 110 0.46 2.18 2.07 433.100 77 72 52 251 250 437.34 93.718205 3 110 0.46 2.18 2.12 437.070 77 72 52 250 250 441.31 94.019210 3 110 0.47 2.23 2.12 441.050 77 72 52 251 250 445.33 94.120215 3 110 0.47 2.23 2.12 445.080 77 72 52 250 250 449.36 94.621220 3 110 0.45 2.14 2.04 449.130 78 72 52 250 250 453.32 94.622225 3 110 0.45 2.14 2.03 453.100 78 73 52 249 250 457.30 94.823230 3 110 0.45 2.15 2.04 457.080 78 73 52 250 250 461.28 93.824235 3 110 0.45 2.15 2.04 461.020 78 73 52 250 250 465.22 94.3240 16:52464.980Average 240 109.8 0.52 2.47 2.34 203.710 75.8 70.9 50.0 250.1 250.1 366.6 94.273.34CompanyJM DefianceSource Designation89 melter dust collectorTest Date12/7/2011Assumed Moisture (Bws)2Test Number1Condensate Volume (Vlc)10.7OperatorMYSilica Gel Weight Gain (Vlc)30Filter NumberNozzle Diameter (in.)0.259Barometric Pressure (Pb)30.02Leak Rate Initial.0@15"Stack Static Pressure (Pg)-0.26Leak Rate Final0.000 @ 7"Stack Dimensions 1 (in.)42Traverse points24*Stack Dimensions 2 (in.) Pitot Corr. Factor (Cp)0.84Pitot Tube Number4'AMeter Corr. Factor (Y)1.003Meter NumberMB 5Orsat Results (%)Meter Isokinetic Factor (Kiso)CO20.3Delta∆H@1.82O220.6Traverse Sampling Time Sampling Stack Temp.Velocity Pres.Desired Orifice Actual Orifice Sample VolumeDry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit Expected IsokineticPoint (Minutes) Clock Time Train Vac. (F) ("H2O) Differential Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature DGM VariationNumber ø (24 hour) ("Hg) Ts∆Ps ("H2O)∆H ("H2O)∆H Vm (F) Tm (F) Tm (F) (F) (F) (F) (cubic feet) %10 16:15 3 111 0.45 1.98 1.93 487.17 61 61 47 na na na 490.99 97.725 3 111 0.45 1.98 1.93 490.90 66 63 54 na na na 494.74 99.9310 3 112 0.51 2.25 2.20 494.74 69 64 52 na na na 498.84 100.2415 3 111 0.51 2.25 2.20 498.85 72 65 52 na na na 502.97 100.5520 3 111 0.44 1.94 1.91 502.99 73 66 55 na na na 506.83 100.0625 3 111 0.45 1.98 1.95 506.83 74 66 56 na na na 510.71 99.1730 3 111 0.43 1.90 1.87 510.68 75 67 57 na na na 514.48 98.8835 3 111 0.43 1.90 1.87 514.44 75 68 58 na na na 518.25 99.8940 4 110 0.54 2.38 2.35 518.24 75 68 59 na na na 522.51 100.31045 4 110 0.54 2.38 2.35 522.52 76 69 60 na na na 526.80 100.81150 4 110 0.59 2.60 2.57 526.83 77 69 60 na na na 531.30 99.31255 4 111 0.63 2.78 2.75 531.27 77 70 62 na na na 535.89 99.81360 5 111 0.64 2.82 2.80 535.88 78 70 62 na na na 540.54 100.51465 5 110 0.64 2.82 2.80 540.56 78 71 63 na na na 545.23 100.71570 5 110 0.61 2.69 2.67 545.26 78 71 63 na na na 549.82 98.71675 5 110 0.61 2.69 2.67 549.76 78 71 63 na na na 554.32 101.21780 5 110 0.63 2.78 2.76 554.37 78 71 63 na na na 559.01 99.81885 5 109 0.63 2.78 2.76 558.99 78 71 62 na na na 563.63 99.91990 5 109 0.63 2.78 2.76 563.62 79 72 63 na na na 568.27 99.92095 5 109 0.61 2.69 2.68 568.26 79 72 62 na na na 572.83 99.821100 5 110 0.61 2.69 2.68 572.82 79 72 63 na na na 577.39 99.722105 5 110 0.64 2.82 2.81 577.37 79 72 63 na na na 582.05 99.523110 5 108 0.54 2.38 2.37 582.02 79 72 64 na na na 586.33 100.124115 5 109 0.60 2.64 2.64 586.33 78 72 63 na na na 590.86 99.2120 18:15590.82 na na na1120 18:34 4 110 0.60 2.64 2.64 590.82 70 71 48 na na na 595.31 100.72125 4 109 0.60 2.64 2.64 595.34 74 71 58 na na na 599.85 100.73130 4 109 0.62 2.73 2.73 599.88 77 71 58 na na na 604.48 99.74135 4 109 0.62 2.73 2.73 604.46 78 71 58 na na na 609.06 100.05140 4 108 0.59 2.60 2.60 609.06 78 71 59 na na na 613.55 99.16145 4 108 0.59 2.60 2.60 613.51 78 71 58 na na na 618.00 99.37150 4 108 0.59 2.60 2.60 617.97 78 71 58 na na na 622.46 99.88155 4 108 0.59 2.60 2.60 622.45 78 71 59 na na na 626.94 100.29160 4 108 0.59 2.60 2.60 626.95 78 71 60 na na na 631.44 100.210165 4 108 0.63 2.78 2.77 631.45 78 71 60 na na na 636.09 99.611170 4 108 0.61 2.69 2.69 636.07 79 72 60 na na na 640.65 98.812175 4 108 0.62 2.73 2.73 640.59 78 72 60 na na na 645.20 100.113180 4 108 0.60 2.64 2.64 645.20 78 72 60 na na na 649.74 99.714185 4 108 0.57 2.52 2.52 649.72 78 72 58 na na na 654.14 100.515190 4 108 0.57 2.52 2.52 654.16 78 72 59 na na na 658.58 100.016195 4 108 0.52 2.30 2.3 658.58 78 72 60 na na na 662.80 100.417200 4 108 0.5 2.21 2.22 662.82 78 72 60 na na na 666.96 100.718205 4 107 0.5 2.22 2.22 666.99 78 72 59 na na na 671.14 100.819210 4 108 0.5 2.22 2.22 671.17 78 72 59 na na na 675.31 100.020215 4 108 0.49 2.18 2.18 675.31 77 71 60 na na na 679.40 99.921220 4 107 0.53 2.36 2.36 679.40 77 71 60 na na na 683.66 100.322225 4 107 0.53 2.36 2.36 683.67 77 71 61 na na na 687.93 100.023230 4 107 0.52 2.32 2.32 687.93 77 71 62 na na na 692.15 101.224235 4 107 0.52 2.32 2.33 692.20 77 71 62 na na na 696.42 99.8240 20:34696.41Average 240 109.1 0.56 2.48 2.47 209.240 76.4 70.1 59.2 #DIV/0! #DIV/0! #DIV/0! 99.973.25CompanyJM DefianceSource Designation89 melter dust collectorTest Date12/8/2011Assumed Moisture (Bws)1Test Number2Condensate Volume (Vlc)9.7OperatorMYSilica Gel Weight Gain (Vlc)35.3Filter NumberNozzle Diameter (in.)0.259Barometric Pressure (Pb)30.18Leak Rate Initial.0@15"Stack Static Pressure (Ps)-0.26Leak Rate Final.0@7"Stack Dimensions 1 (in.)42Traverse points24*Stack Dimensions 2 (in.) Pitot Corr. Factor (Cp)0.84Pitot Tube Number4'AMeter Corr. Factor (Y)1.003Meter NumberMB 5Orsat Results (%)Meter Isokinetic Factor (Kiso) CO20Delta∆H@1.82O221.1Traverse Sampling Time Sampling Stack Temp.Velocity Pres.Desired Orifice Orifice Sample VolumeDry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit Expected IsokineticPoint (Minutes) Clock Time Train Vac. (F) ("H2O) Differential Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature DGM VariationNumber ø (24 hour) ("Hg) Ts∆Ps ("H2O)∆H ("H2O)∆H Vm (F) Tm (F) Tm (F) (F) (F) (F) (cubic feet) %10 8:00 4 110 0.51 2.28 2.19 696.75 60 60 56 na na na 700.84 97.725 4 111 0.51 2.28 2.19 700.74 61 60 51 na na na 704.83 100.1310 4 111 0.50 2.24 2.15 704.83 63 61 47 na na na 708.89 98.6415 4 111 0.50 2.24 2.15 708.83 65 61 46 na na na 712.90 98.4520 4 111 0.50 2.24 2.16 712.83 67 62 47 na na na 716.91 98.2625 4 111 0.52 2.33 2.25 716.83 69 62 47 na na na 721.00 95.6730 4 111 0.50 2.25 2.17 720.81 70 63 48 na na na 724.90 98.5835 4 111 0.50 2.25 2.18 724.84 71 64 49 na na na 728.94 99.3940 4 111 0.49 2.21 2.14 728.91 72 65 49 na na na 732.98 99.41045 4 111 0.49 2.21 2.14 732.95 73 65 49 na na na 737.02 99.31150 4 111 0.52 2.35 2.28 736.99 74 66 50 na na na 741.19 99.81255 4 111 0.52 2.35 2.28 741.18 75 67 50 na na na 745.39 99.41360 4 111 0.49 2.22 2.16 745.36 75 67 50 na na na 749.45 100.41465 4 111 0.47 2.13 2.07 749.46 75 68 50 na na na 753.47 98.91570 4 111 0.43 1.95 1.90 753.42 76 68 51 na na na 757.26 99.11675 4 111 0.42 1.91 1.86 757.22 76 69 51 na na na 761.01 99.11780 4 111 0.40 1.82 1.79 760.98 76 69 50 na na na 764.68 100.21885 4 111 0.40 1.82 1.78 764.69 76 69 51 na na na 768.39 98.81990 4 111 0.39 1.78 1.74 768.35 76 69 51 na na na 772.01 99.82095 4 111 0.39 1.78 1.74 772.00 76 70 51 na na na 775.66 100.221100 4 111 0.38 1.74 1.70 775.67 76 70 51 na na na 779.28 99.622105 4 109 0.42 1.92 1.88 779.27 76 70 51 na na na 783.07 99.923110 4 109 0.42 1.92 1.88 783.07 77 70 51 na na na 786.88 100.024115 4 109 0.41 1.88 1.87 786.88 77 71 51 na na na 790.65 100.9120 10:00790.68 na na na1120 10:09 5 110 0.52 2.39 2.38 790.68 72 70 51 na na na 794.89 101.02125 5 110 0.52 2.39 2.38 794.93 75 70 52 na na na 799.16 100.93130 4 110 0.50 2.30 2.29 799.19 77 71 49 na na na 803.34 100.74135 4 110 0.50 2.30 2.29 803.37 77 71 49 na na na 807.52 100.95140 4 110 0.50 2.31 2.30 807.56 78 71 50 na na na 811.72 100.66145 4 111 0.49 2.26 2.26 811.74 78 71 50 na na na 815.85 101.97150 4 111 0.50 2.31 2.30 815.93 78 71 51 na na na 820.08 100.48155 4 111 0.50 2.31 2.30 820.10 78 72 51 na na na 824.26 101.19160 4 111 0.51 2.36 2.36 824.30 78 72 51 na na na 828.50 101.310165 5 112 0.53 2.46 2.45 828.550 79 72 51 na na na 832.83 100.111170 5 112 0.51 2.37 2.37 832.830 79 72 51 na na na 837.03 101.512175 5 112 0.55 2.56 2.55 837.090 79 72 51 na na na 841.45 100.613180 5 112 0.53 2.47 2.46 841.470 80 73 51 na na na 845.76 101.114185 5 113 0.53 2.47 2.47 845.800 80 73 51 na na na 850.09 100.215190 5 113 0.55 2.57 2.56 850.090 80 73 52 na na na 854.46 101.416195 5 113 0.55 2.57 2.57 854.510 80 73 52 na na na 858.88 100.917200 5 112 0.55 2.57 2.57 858.910 80 73 52 na na na 863.28 101.118205 5 112 0.55 2.58 2.57 863.320 80 73 53 na na na 867.69 100.619210 5 111 0.5 2.34 2.34 867.710 81 74 53 na na na 871.89 99.420215 5 111 0.5 2.35 2.34 871.860 80 74 53 na na na 876.03 99.021220 4 111 0.45 2.11 2.11 875.990 80 74 53 na na na 879.95 101.522225 4 110 0.45 2.12 2.12 880.010 80 74 53 na na na 883.97 100.523230 4 110 0.46 2.17 2.17 883.990 80 74 53 na na na 888.00 100.624235 4 111 0.45 2.12 2.12 888.020 80 74 53 na na na 891.98 101.0240 12:09892.020Average 240 111.0 0.49 2.23 2.19 195.270 75 69 51 #DIV/0! #DIV/0! #DIV/0! 100.072.33CompanyJM DefianceSource Designation89 melter dust collectorTest Date12/8/2011Assumed Moisture (Bws)1Test Number3Condensate Volume (Vlc)4OperatorMYSilica Gel Weight Gain (Vlc)39.2Filter NumberNozzle Diameter (in.)0.259Barometric Pressure (Pb)30.18Leak Rate Initial.001@15"Stack Static Pressure (Ps)-0.26Leak Rate Final.0@7"Stack Dimensions 1 (in.)42Traverse points24*Stack Dimensions 2 (in.) Pitot Corr. Factor (Cp)0.84Pitot Tube Number4'AMeter Corr. Factor (Y)1.003Meter NumberMB 5Orsat Results (%)Meter Isokinetic Factor (Kiso) CO20.2Delta∆H@1.82O221Traverse Sampling Time Sampling Stack Temp.Velocity Pres.Desired Orifice Orifice Sample VolumeDry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit Expected IsokineticPoint (Minutes) Clock Time Train Vac. (F) ("H2O) Differential Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature DGM VariationNumber ø (24 hour) ("Hg) Ts∆Ps ("H2O)∆H ("H2O)∆H Vm (F) Tm (F) Tm (F) (F) (F) (F) (cubic feet) %10 12:45 4 111 0.50 2.25 2.23 892.25 72 72 59 na na na 896.38 100.225 4 111 0.50 2.25 2.23 896.39 73 72 55 na na na 900.53 98.9310 4 110 0.49 2.21 2.19 900.48 75 72 53 na na na 904.59 100.4415 4 110 0.49 2.21 2.19 904.60 77 72 54 na na na 908.72 99.7520 4 110 0.48 2.16 2.15 908.70 78 72 55 na na na 912.78 100.1625 4 110 0.48 2.16 2.15 912.78 78 72 57 na na na 916.86 99.6730 4 110 0.48 2.16 2.15 916.84 79 72 58 na na na 920.92 100.0835 4 110 0.46 2.07 2.06 920.92 79 72 58 na na na 924.91 99.4940 4 110 0.48 2.16 2.15 924.89 79 73 59 na na na 928.97 99.71045 4 110 0.48 2.16 2.15 928.96 80 73 60 na na na 933.05 99.41150 4 110 0.50 2.25 2.25 933.02 80 73 61 na na na 937.19 100.01255 4 110 0.50 2.25 2.25 937.19 80 73 61 na na na 941.36 99.51360 4 111 0.54 2.43 2.43 941.34 80 74 62 na na na 945.68 99.31465 4 111 0.54 2.43 2.43 945.64 81 74 62 na na na 949.98 99.71570 4 111 0.52 2.34 2.34 949.96 81 74 62 na na na 954.22 99.91675 4 111 0.53 2.39 2.38 954.21 81 74 63 na na na 958.51 100.11780 4 110 0.54 2.43 2.43 958.51 81 74 63 na na na 962.85 100.31885 4 110 0.54 2.43 2.43 962.86 81 74 64 na na na 967.20 100.31990 4 110 0.54 2.43 2.43 967.21 81 74 64 na na na 971.55 100.72095 4 110 0.54 2.43 2.43 971.58 81 74 64 na na na 975.92 100.521100 4 110 0.49 2.21 2.21 975.94 81 74 64 na na na 980.08 99.622105 4 110 0.49 2.21 2.21 980.06 81 74 64 na na na 984.20 98.923110 4 109 0.47 2.12 2.12 984.15 81 75 64 na na na 988.21 100.824115 4 110 0.47 2.12 2.12 988.24 81 75 65 na na na 992.30 101.1120 14:45992.34 na na na1120 14:52 4 111 0.52 2.34 2.34 992.34 77 74 64 na na na 996.58 99.32125 4 111 0.52 2.34 2.34 996.55 78 74 64 na na na 1000.80 100.23130 4 111 0.51 2.30 2.30 1000.80 80 74 63 na na na 1005.01 100.74135 4 111 0.50 2.25 2.25 1005.04 81 74 64 na na na 1009.22 100.25140 4 111 0.49 2.21 2.21 1009.22 81 75 65 na na na 1013.36 99.96145 4 111 0.49 2.21 2.21 1013.35 81 75 65 na na na 1017.49 100.17150 4 111 0.50 2.25 2.25 1017.49 82 75 66 na na na 1021.67 100.98155 4 111 0.50 2.25 2.25 1021.71 82 75 65 na na na 1025.89 101.29160 4 111 0.52 2.34 2.34 1025.94 82 75 61 na na na 1030.21 99.910165 4 111 0.52 2.34 2.34 1030.200 82 75 57 na na na 1034.47 100.211170 4 111 0.54 2.43 2.43 1034.470 82 75 55 na na na 1038.82 99.712175 4 111 0.54 2.43 2.43 1038.800 82 75 53 na na na 1043.15 99.213180 4 111 0.47 2.12 2.12 1043.110 82 75 52 na na na 1047.17 100.114185 4 111 0.47 2.12 2.12 1047.170 82 75 52 na na na 1051.23 101.915190 4 111 0.45 2.03 2.03 1051.300 82 76 51 na na na 1055.27 98.216195 4 110 0.45 2.04 2.04 1055.200 82 76 51 na na na 1059.18 98.117200 4 110 0.42 1.90 1.9 1059.100 82 76 51 na na na 1062.94 100.218205 4 110 0.42 1.90 1.9 1062.950 82 76 51 na na na 1066.79 99.219210 4 110 0.4 1.82 1.82 1066.760 82 76 51 na na na 1070.51 101.920215 4 110 0.35 1.59 1.59 1070.580 81 70 51 na na na 1074.06 104.421220 4 110 0.37 1.68 1.68 1074.220 81 76 51 na na na 1077.82 101.522225 4 110 0.37 1.69 1.69 1077.880 81 76 51 na na na 1081.48 100.723230 4 110 0.38 1.73 1.73 1081.510 81 76 51 na na na 1085.16 99.924235 4 110 0.38 1.73 1.74 1085.160 81 76 51 na na na 1088.81 99.7240 16:521088.800Average 240 110.4 0.48 2.17 2.17 196.550 80.2 74.1 58.5 #DIV/0! #DIV/0! #DIV/0! 100.177.17

# Appendix B

Process Data

# Appendix C

Equipment Calibration DocumentsOxygen and Carbon Dioxide Concentration Results SummaryJohns Manville - Defiance, OhioBTEC Project No. 11-4191.01Sampling Dates: December 7 & 8, 2011Parameter Run 1 Run 2 Run 3 AverageTest Run Date12/7/2011 12/8/2011 12/8/2011Test Time21:11 15:07 17:57Oxygen concentration (%) 20.86 20.95 20.79 20.87Oxygen concentration (%) (corrected as per USEPA 3A) 20.57 21.11 20.95 20.88Carbon Dioxide concentration (%) 0.36 -0.03 0.12 0.15Carbon Dioxide concentration (%) (corrected as per USEPA 3A) 0.34 0.01 0.16 0.17CO2CorrectionO2Correction1 2 3 12 3Co0.03 -0.04 -0.04Co0.00 0.25 0.25Cma10.10 10.10 10.10Cma10.00 10.00 10.00Cm9.95 10.07 10.07Cm10.14 10.06 10.06Co= Average of initial and final zero gasesCma=Actual concentration of the calibration gasCm= Average of initial and final calibration gasesMETHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of timenecessary to achieve a minimum total volume of 5 cubic feet.4) Record data and information in theGREENcells, YELLOW cells are calculated.INITIAL FINAL AVG (Pbar)DATE:10/26/2011METER SERIAL #: C-5000BAROMETRIC PRESSURE (in Hg): 29.78 29.81 29.795 IF Y VARIATION EXCEEDS 2.00%,METER PART #: MB3 CRITICAL ORIFICE SET SERIAL #: 1447ORIFICE SHOULD BE RECALIBRATEDK' TESTEDTEMPERATURES °F ELAPSEDFACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGMΔH(1)(2)(3)YORIFICE # RUN # (AVG) (in Hg) INITIAL FINALNET (Vm)INITIAL FINAL INITIAL FINAL AVGθ(in H2O) Vm(STD) Vcr(STD)YVARIATION (%)ΔH@1 0.8778 16 913.70 920.465 6.765 66 68 67 68 67 67.5 6.00 4.4 6.81766.84421.0041.922 0.8778 16 920.465 927.282 6.817 66 67 69 67 67 67.5 6.00 4.4 6.8706.84420.9961.923 0.8778 16 927.282 934.090 6.808 66 69 71 67 67 68.5 6.00 4.4 6.84806.84420.9991.91AVG = 1.000-0.291 0.5057 16 934.090 939.924 5.834 66 71 71 67 68 69.25 9.00 1.35 5.81635.91441.0171.752 0.5057 16 939.924 945.752 5.828 66 71 72 68 68 69.75 9.00 1.35 5.80485.91441.0191.753 0.5057 16 945.752 953.578 7.826 66 72 72 68 68 70 12.00 1.35 7.79127.88591.0121.75AVG = 1.0161.311 0.3367 16 953.578 958.890 5.312 66 72 70 68 68 69.5 12.00 0.61 5.28375.25050.9941.782 0.3367 16 958.890 964.644 5.754 66 70 70 68 68 69 13.00 0.61 5.72885.68810.9931.783 0.3367 16 964.644 969.964 5.320 66 70 70 68 68 69 12.00 0.61 5.29675.25050.9911.78AVG = 0.993-1.02AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =1.003AVERAGEΔH@=1.82(1) =Net volume of gas sample passed through DGM, corrected to standard conditionsK1=17.64oR/in. Hg (English), 0.3858oK/mm Hg (Metric)Tm=Absolute DGM avg. temperature (oR - English,oK - Metric)ΔH@=0.75θΔH Vm(std)Vcr(std)Vm(2) =Volume of gas sample passed through the critical orifice, corrected to standard conditionsTamb=Absolute ambient temperature (oR - English,oK - Metric)K' = Average K' factor from Critical Orifice Calibration(3) =DGM calibration factor321812ENVIRONMENTAL SUPPLY COMPANYUSING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm(std), and the criticalorifice, Vcr(std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.()2()TmHPbarVmKVmstd)6.13/(1)(Δ+∗∗=TambPbarKVcrstdΘ∗∗=')()()(stdstdVmVcrY=Meter box 3 calsMETHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of timenecessary to achieve a minimum total volume of 5 cubic feet.4) Record data and information in theGREENcells, YELLOW cells are calculated.INITIAL FINAL AVG (Pbar)DATE: 1/13/2012 METER SERIAL #: C-5000BAROMETRIC PRESSURE (in Hg): 29.54 29.54 29.54 IF Y VARIATION EXCEEDS 2.00%,METER PART #: MB3 CRITICAL ORIFICE SET SERIAL #: 1447ORIFICE SHOULD BE RECALIBRATEDK' TESTEDTEMPERATURES °F ELAPSEDFACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGMΔH(1)(2)(3)YORIFICE # RUN # (AVG) (in Hg) INITIAL FINALNET (Vm)INITIAL FINAL INITIAL FINAL AVGθ(in H2O) Vm(STD) Vcr(STD)YVARIATION (%)ΔH@1 0.8778 16 602.70 609.330 6.630 67 52 54 50 52 52 6.00 4.1 6.82066.77920.9941.862 0.8778 16 609.330 615.980 6.650 66 54 57 52 53 54 6.00 4.1 6.81466.78570.9961.853 0.8778 16 615.980 622.670 6.690 66 57 61 53 55 56.5 6.00 4.1 6.82246.78570.9951.84AVG = 0.995-0.281 0.5057 16 623.0 628.760 5.760 65 60 63 56 58 59.25 9.00 1.3 5.80255.86941.0121.732 0.5057 16 628.760 634.550 5.790 66 63 66 58 60 61.75 9.00 1.3 5.80485.86381.0101.733 0.5057 16 634.550 640.340 5.790 67 66 68 60 62 64 9.00 1.3 5.77985.85831.0141.72AVG = 1.0121.421 0.3367 16 640.50 645.810 5.310 66 66 68 62 64 65 12.00 0.58 5.28115.20560.9861.722 0.3367 16 645.810 651.120 5.310 67 68 70 64 65 66.75 12.00 0.58 5.26365.20060.9881.723 0.3367 16 651.120 656.460 5.340 67 70 70 65 67 68 12.00 0.58 5.28085.20060.9851.72AVG = 0.986-1.14AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =0.998AVERAGEΔH@=1.77(1) =Net volume of gas sample passed through DGM, corrected to standard conditionsK1=17.64oR/in. Hg (English), 0.3858oK/mm Hg (Metric)Tm=Absolute DGM avg. temperature (oR - English,oK - Metric)ΔH@=0.75θΔH Vm(std)Vcr(std)Vm(2) =Volume of gas sample passed through the critical orifice, corrected to standard conditionsTamb=Absolute ambient temperature (oR - English,oK - Metric)K' = Average K' factor from Critical Orifice Calibration(3) =DGM calibration factor321812ENVIRONMENTAL SUPPLY COMPANYUSING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm(std), and the criticalorifice, Vcr(std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.()2()TmHPbarVmKVmstd)6.13/(1)(Δ+∗∗=TambPbarKVcrstdΘ∗∗=')()()(stdstdVmVcrY=Meter box 3 calsMETHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of timenecessary to achieve a minimum total volume of 5 cubic feet.4) Record data and information in theGREENcells, YELLOW cells are calculated.INITIAL FINAL AVG (Pbar)DATE: 10/24/2011 METER SERIAL #: CA 4BAROMETRIC PRESSURE (in Hg): 29.93 29.96 29.945 IF Y VARIATION EXCEEDS 2.00%,METER PART #: MB4 CRITICAL ORIFICE SET SERIAL #: 1447ORIFICE SHOULD BE RECALIBRATEDK' TESTEDTEMPERATURES °F ELAPSEDFACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGMΔH(1)(2)(3)YORIFICE # RUN # (AVG) (in Hg) INITIAL FINALNET (Vm)INITIAL FINAL INITIAL FINAL AVGθ(in H2O) Vm(STD) Vcr(STD)YVARIATION (%)ΔH@1 0.6665 15 804.80 809.970 5.170 68 65 67 65 66 65.75 6.00 2.3 5.22685.21300.9971.732 0.6665 15 809.970 815.20 5.230 67 67 66 66 67 66.5 6.00 2.3 5.27995.21790.9881.733 0.6665 15 815.20 820.40 5.20 65 66 69 67 66 67 6.00 2.3 5.24475.22790.9971.72AVG = 0.994-0.791 0.5057 15 820.50 826.330 5.830 67 66 70 67 67 67.5 9.00 1.25 5.85945.93861.0141.622 0.5057 15 826.330 832.150 5.820 67 70 71 67 67 68.75 9.00 1.25 5.83555.93861.0181.623 0.5057 15 832.150 837.960 5.810 67 71 72 67 68 69.5 9.00 1.25 5.81735.93861.0211.62AVG = 1.0171.521 0.3367 15 838.10 843.420 5.320 67 72 71 69 69 70.25 12.00 0.6 5.31065.27190.9931.752 0.3367 15 843.420 848.710 5.290 67 72 72 69 69 70.5 12.00 0.6 5.27825.27190.9991.743 0.3367 15 848.710 854.040 5.330 67 72 73 70 70 71.25 12.00 0.6 5.31065.27190.9931.74AVG = 0.995-0.73AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =1.002AVERAGEΔH@=1.70(1) =Net volume of gas sample passed through DGM, corrected to standard conditionsK1=17.64oR/in. Hg (English), 0.3858oK/mm Hg (Metric)Tm=Absolute DGM avg. temperature (oR - English,oK - Metric)ΔH@=0.75θΔH Vm(std)Vcr(std)Vm(2) =Volume of gas sample passed through the critical orifice, corrected to standard conditionsTamb=Absolute ambient temperature (oR - English,oK - Metric)K' = Average K' factor from Critical Orifice Calibration(3) =DGM calibration factor241812ENVIRONMENTAL SUPPLY COMPANYUSING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm(std), and the criticalorifice, Vcr(std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.()2()TmHPbarVmKVmstd)6.13/(1)(Δ+∗∗=TambPbarKVcrstdΘ∗∗=')()()(stdstdVmVcrY=Meter box 4 calsMETHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of timenecessary to achieve a minimum total volume of 5 cubic feet.4) Record data and information in theGREENcells, YELLOW cells are calculated.INITIAL FINAL AVG (Pbar)DATE: 12/16/2011 METER SERIAL #: CA 4BAROMETRIC PRESSURE (in Hg): 30.29 30.26 30.275 IF Y VARIATION EXCEEDS 2.00%,METER PART #: MB4 CRITICAL ORIFICE SET SERIAL #: 1447ORIFICE SHOULD BE RECALIBRATEDK' TESTEDTEMPERATURES °F ELAPSEDFACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGMΔH(1)(2)(3)YORIFICE # RUN # (AVG) (in Hg) INITIAL FINALNET (Vm)INITIAL FINAL INITIAL FINAL AVGθ(in H2O) Vm(STD) Vcr(STD)YVARIATION (%)ΔH@1 0.6665 15 466.570 471.750 5.180 63 63 63 63 62 62.75 6.00 2.3 5.32475.29560.9951.712 0.6665 15 471.750 476.960 5.210 62 63 63 62 62 62.5 6.00 2.3 5.35815.30070.9891.703 0.6665 15 476.960 482.160 5.20 61 63 64 62 63 63 6.00 2.3 5.34275.30570.9931.70AVG = 0.992-1.231 0.5057 15 482.50 488.260 5.760 65 65 65 63 63 64 9.00 1.3 5.89256.01551.0211.672 0.5057 15 488.260 494.030 5.770 62 65 66 63 63 64.25 9.00 1.3 5.89996.03271.0231.663 0.5057 15 494.030 499.80 5.770 63 66 67 63 64 65 9.00 1.3 5.89156.02691.0231.66AVG = 1.0221.741 0.3367 15 500.0 505.250 5.250 64 66 66 64 64 65 12.00 0.6 5.35155.34530.9991.732 0.3367 15 505.250 510.510 5.260 62 66 67 64 65 65.5 12.00 0.6 5.35655.35551.0001.733 0.3367 15 510.510 516.650 6.140 63 67 68 65 65 66.25 14.00 0.6 6.24386.24211.0001.73AVG = 0.999-0.51AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =1.005AVERAGEΔH@=1.70(1) =Net volume of gas sample passed through DGM, corrected to standard conditionsK1=17.64oR/in. Hg (English), 0.3858oK/mm Hg (Metric)Tm=Absolute DGM avg. temperature (oR - English,oK - Metric)ΔH@=0.75θΔH Vm(std)Vcr(std)Vm(2) =Volume of gas sample passed through the critical orifice, corrected to standard conditionsTamb=Absolute ambient temperature (oR - English,oK - Metric)K' = Average K' factor from Critical Orifice Calibration(3) =DGM calibration factor241812ENVIRONMENTAL SUPPLY COMPANYUSING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm(std), and the criticalorifice, Vcr(std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.()2()TmHPbarVmKVmstd)6.13/(1)(Δ+∗∗=TambPbarKVcrstdΘ∗∗=')()()(stdstdVmVcrY=Meter box 4 cals

# Appendix D

Laboratory Analytical ResultsAcetoneRinseVolume(mL)ParticulateWeight inAcetoneRinse (mg)ParticulateWeight onFilter (mg)ParticulateWeight inAcetoneRinse (mg)CombinedParticulateWeight(mg)Run 1120 4.6 0.3 3.63.9Run 2110 2.5 0.3 1.51.8Run 3130 2.4 0.3 1.31.6Blank230 2.00 0.30Method 5 PM Lab ResultsCorrectedSampling Date: December 7-8, 2011BTEC job #11-4191.00Defiance, OhioJohns ManvilleCompound/FractionBlankFilterResult(μg)BlankFilterDetectionLimit(μg)Run 1Result(μg)Run 2Result(μg)Run 3Result(μg)Test RunDetectionLimit(μg)Run 1(μg)Run 2(μg)Run 3(μg)Back Half Chromium 1.45 0.15 1.85 2.13 1.72 0.150.40 0.68 0.27Front Half Chromium 1.30 0.30 7.52 5.92 4.72 0.606.22 4.62 3.42Johns ManvilleMethod 29 Lab ResultsCorrectedSampling Date: December 7-8, 2011BTEC job #11-4191.00Defiance, OhioCorrectedTotal Volume(ml)Impinger KOH(ml)HexavalentChromium,Cr6+ [μg] RDLHexavalentChromium,Cr6+ [μg]Run 18485880.16 0.300.30Run 29196290.29 0.300.30Run 39593000.13 0.300.30Blank KOH306 0.30 0.30Note: No blank correction applied. RDL used to calculate results.CorrectedTotal Volume(ml)Impinger KOH(ml)Back HalfChromium(μg)Back HalfRDLFront HalfChromium(μg)Front HalfRDLRinseChromium(μg)RinseRDLTotalChromium,Cr [μg]Run 18485882.004.000.500.30 1.00 2.006.50Run 29196292.004.000.300.30 1.00 2.006.30Run 39593002.004.000.300.30 1.00 2.006.30Blank KOH306 1.00 2.00 0.20 0.30 1.00 2.00Note: No blank correction applied. RDL used for all fractions except Run 1 Front Half Chromium, which was above RDL.Method 0061 Lab ResultsSampling Date: December 7-8, 2011BTEC job #11-4191.00Defiance, OhioJohns Manville

### Your Project #: 11-4190.00

Site Location: JM

DEFIANCE

Attention: Barry

Boulianne

BT Environmental Consulting

2615 Wolcott St.

Ferndale, MI

USA 48220

Report Date: 2011/12/23



## CERTIFICATE

OF ANALYSIS

MAXXAM JOB #: B1J5639

Received: 2011/12/12, 15:15

Sample Matrix: Stack

Sampling Train

# Samples Received: 4

Date Date Method

Analyses Quantity Extracted Analyzed Laboratory Method Reference

Metals B.H. in H2O2/HNO3 Imp.(6020) 4 2011/12/21 2011/12/22 BRL SOP-00103 / BRL EPA 6020 / M29

SOP-00102

Metals F.H. in Filter + Rinses (6020) 4 2011/12/20 2011/12/21 BRL SOP-00103/ BRL EPA 6020 / M29

SOP-00102

Particulates/Acetone Rinse (M5/315/M201) 4 2011/12/13 2011/12/19 BRL SOP-00109 EPA 5/315

Particulates/Filter (M5/315/NJATM1/M201) 4 N/A 2011/12/15 BRL SOP-00109 EPA 5/315/NJATM1

Final Volume of Acetone Probe Rinse 4 N/A 2011/12/14

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.



### Encryption

Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

CLAYTON JOHNSON, Project Manager

Email: CJohnson@maxxam.ca

Phone# (905) 817-5769

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section

5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 1

Page 1 of 7

### BT Environmental Consulting

Maxxam Job #: B1J5639 Client Project #: 11-4190.00

Report Date: 2011/12/23 Site Location: JM DEFIANCE



### EPA M29 METALS (FRONT & BACK)

Maxxam ID L Y 4 5 7 8 L

Y 4 5 7 9 L

Y 4 5 7 9 L

Y 4 5 8 0 L

Y 4 5 8 1

Sampling Date 2011/12/08 2011/12/07 2011/12/07 2011/12/08 2011/12/08

U n i t s BLANK-M5/29 RDL RUN RUN RUN RUN RDL QC Batch

1-M5/29 1-M5/29 2-M5/29 3-M5/29

Lab-Dup

Back Half Chromium (Cr) ug 1.45 0.15 1.85 1.95 2.13 1.72 0.15 2720392

Front Half Chromium (Cr) ug 1.30 0.30 7.52 7.50 5.92 4.72 0.60 2719130

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 2 of 7

### BT Environmental Consulting

Maxxam Job #: B1J5639 Client Project #: 11-4190.00

Report Date: 2011/12/23 Site Location: JM DEFIANCE



### EPA M5 PARTICULATE MATTER (PM)

Maxxam ID L Y 4 5 7 8 L

Y 4 5 7 9 L

Y 4 5 8 0 L

Y 4 5 8 1

Sampling Date 2011/12/08 2011/12/07 2011/12/08 2011/12/08

U n i t s BLANK-M5/29 RUN RUN RUN RDL QC Batch

1-M5/29 2-M5/29 3-M5/29

Acetone Rinse Particulate Weight in Acetone Rinse mg 2.0 4.6 2.5 2.4 0.5 2712098

Front Half Particulate Weight on Filter mg <0.30 <0.30 <0.30 <0.30 0.30 2712097

Acetone Rinse Volume ml 230 120 110 130 1 2712099

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 3 of 7

### BT Environmental Consulting

Maxxam Job #: B1J5639 Client Project #: 11-4190.00

Report Date: 2011/12/23 Site Location: JM DEFIANCE



### Test Summary

Maxxam ID LY4578 Collected 2011/12/08

Sample ID BLANK-M5/29 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Metals B.H. in H2O2/HNO3 Imp.(6020) ICP1 /MS 2720392 2011/12/21 2011/12/22 NAN RAYKHA

Metals F.H. in Filter + Rinses (6020) ICP1 /MS 2719130 2011/12/20 2011/12/21 NAN RAYKHA

Particulates/Acetone Rinse (M5/315/M201) BAL 2712098 2011/12/13 2011/12/19 FRANK MO

Particulates/Filter (M5/315/NJATM1/M201) BAL 2712097 N/A 2011/12/15 BRENDA MOORE

Final Volume of Acetone Probe Rinse 2712099 N/A 2011/12/14 FRANK MO

Maxxam ID LY4579 Collected 2011/12/07

Sample ID RUN 1-M5/29 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Metals B.H. in H2O2/HNO3 Imp.(6020) ICP1 /MS 2720392 2011/12/21 2011/12/22 NAN RAYKHA

Metals F.H. in Filter + Rinses (6020) ICP1 /MS 2719130 2011/12/20 2011/12/21 NAN RAYKHA

Particulates/Acetone Rinse (M5/315/M201) BAL 2712098 2011/12/13 2011/12/19 FRANK MO

Particulates/Filter (M5/315/NJATM1/M201) BAL 2712097 N/A 2011/12/15 BRENDA MOORE

Final Volume of Acetone Probe Rinse 2712099 N/A 2011/12/14 FRANK MO

Maxxam ID LY4579 D u p Collected 2011/12/07

Sample ID RUN 1-M5/29 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Metals B.H. in H2O2/HNO3 Imp.(6020) ICP1 /MS 2720392 2011/12/23 2011/12/22 NAN RAYKHA

Metals F.H. in Filter + Rinses (6020) ICP1 /MS 2719130 2011/12/22 2011/12/21 NAN RAYKHA

Maxxam ID LY4580 Collected 2011/12/08

Sample ID RUN 2-M5/29 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Metals B.H. in H2O2/HNO3 Imp.(6020) ICP1 /MS 2720392 2011/12/21 2011/12/22 NAN RAYKHA

Metals F.H. in Filter + Rinses (6020) ICP1 /MS 2719130 2011/12/20 2011/12/21 NAN RAYKHA

Particulates/Acetone Rinse (M5/315/M201) BAL 2712098 2011/12/13 2011/12/19 FRANK MO

Particulates/Filter (M5/315/NJATM1/M201) BAL 2712097 N/A 2011/12/15 BRENDA MOORE

Final Volume of Acetone Probe Rinse 2712099 N/A 2011/12/14 FRANK MO

Maxxam ID LY4581 Collected 2011/12/08

Sample ID RUN 3-M5/29 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Metals B.H. in H2O2/HNO3 Imp.(6020) ICP1 /MS 2720392 2011/12/21 2011/12/22 NAN RAYKHA

Metals F.H. in Filter + Rinses (6020) ICP1 /MS 2719130 2011/12/20 2011/12/21 NAN RAYKHA

Particulates/Acetone Rinse (M5/315/M201) BAL 2712098 2011/12/13 2011/12/19 FRANK MO

Particulates/Filter (M5/315/NJATM1/M201) BAL 2712097 N/A 2011/12/15 BRENDA MOORE

Final Volume of Acetone Probe Rinse 2712099 N/A 2011/12/14 FRANK MO

Page 4 of 7

### BT Environmental Consulting

Maxxam Job #: B1J5639 Client Project #: 11-4190.00

Report Date: 2011/12/23 Site Location: JM DEFIANCE

EPA M29 METALS (FRONT & BACK)

Metals B.H. in H2O2/HNO3 Imp.(6020): Post digestion duplicate and spike was done on sample LY4579.

Metals F.H. in Filter + Rinses (6020): Extra 2x dilution was required for all samples except LY4578, due to the matrix

Post digestion duplicate and spike was done on sample LY4579.

EPA M5 PARTICULATE MATTER (PM)

Particulates/Acetone Rinse (M5/315/M201): Reagent blank recieved contains residue after evaporation

Particulates/Filter (M5/315/NJATM1/M201): Negative weights observed.

Results relate only to the items tested.

Page 5 of 7

### BT Environmental Consulting

Attention: Barry Boulianne

Client Project #: 11-4190.00

P.O. #:

Site Location: JM DEFIANCE



### Quality Assurance Report

Maxxam Job Number: GB1J5639

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2712098 RSU Method Blank Acetone Rinse Particulate Weight in Acetone 2011/12/19 <0.5 mg

2719130 N_R Matrix Spike

(LY4579) Front Half Chromium (Cr) 2011/12/21 102 % 70

- 130

Matrix Spike DUP

(LY4579) Front Half Chromium (Cr) 2011/12/21 103 % 70

- 130

MS/MSD RPD Front Half Chromium (Cr) 2011/12/21 1 % 20

Spiked Blank Front Half Chromium (Cr) 2011/12/21 99 % 85

- 115

Spiked Blank DUP Front Half Chromium (Cr) 2011/12/21 101 % 85

- 115

RPD Front Half Chromium (Cr) 2011/12/21 2.4 % 20

Method Blank Front Half Chromium (Cr) 2011/12/21 <0.30 ug

Method Blank DUP Front Half Chromium (Cr) 2011/12/21 <0.30 ug

RPD Front Half Chromium (Cr) 2011/12/21 NC % 20

RPD

- Sample/Sample

Dup Front Half Chromium (Cr) 2011/12/21 0.2 % 20

2720392 N_R Matrix Spike

(LY4579) Back Half Chromium (Cr) 2011/12/22 98 % 70

- 130

Matrix Spike DUP

(LY4579) Back Half Chromium (Cr) 2011/12/22 100 % 70

- 130

MS/MSD RPD Back Half Chromium (Cr) 2011/12/22 2.0 % 20

Spiked Blank Back Half Chromium (Cr) 2011/12/22 101 % 85

- 115

Spiked Blank DUP Back Half Chromium (Cr) 2011/12/22 105 % 85

- 115

RPD Back Half Chromium (Cr) 2011/12/22 3.4 % 20

Method Blank Back Half Chromium (Cr) 2011/12/22 <0.15 ug

Method Blank DUP Back Half Chromium (Cr) 2011/12/22 <0.15 ug

RPD Back Half Chromium (Cr) 2011/12/22 NC % 20

RPD

- Sample/Sample

Dup Back Half Chromium (Cr) 2011/12/22 5.0 % 20

Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.

Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.

Spiked Blank: A blank matrix to which a known amount of the analyte has been added. Used to evaluate analyte recovery.

Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.

NC (RPD): The RPD was not calculated. The level of analyte detected in the parent sample and its duplicate was not sufficiently significant to permit a

reliable calculation.

Page 6 of 7

## Validation Signature Page

Maxxam Job #: B1J5639

The analytical data

and all QC contained

in this report

were reviewed

and validated by the following individual(s).

FRANK MO, B.Sc., Inorganic Lab. Manager

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of

ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Page 7 of 7

### Your Project #: 11-4190.00

Site Location: JM

DEFIANCE

Attention: James K. Sharp

BT Environmental Consulting

2615 Wolcott St.

Ferndale, MI

USA 48220

Report Date: 2011/12/22



## CERTIFICATE

OF ANALYSIS

MAXXAM JOB #: B1J5560

Received: 2011/12/12, 15:15

Sample Matrix: Stack

Sampling Train

# Samples Received: 4

Date Date Method

Analyses Quantity Extracted Analyzed Laboratory Method Reference

Hexavalent Chromium (M0061) 4 2011/12/16 2011/12/16 BRL SOP-00106 EPA 7199 (M0061)

Chromium on Filter by ICP 4 2011/12/15 2011/12/17 CAM SOP-00408 / BRL EPA M0061

SOP-00102

Chromium in Impinger by ICP 4 2011/12/15 2011/12/17 CAM SOP-00408 / BRL EPA M0061

SOP-00102

Chromium in Train Rinse by ICP 4 2011/12/15 2011/12/17 CAM SOP-00408 / BRL EPA M0061

SOP-00102

Final Volume of KOH Impinger 4 N/A 2011/12/15

Final Volume of Train Rinse 4 N/A 2011/12/15

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.

U = Undetected at the limit of quantitation.

J = Estimated concentration between the EDL & RDL.

B = Blank Contamination.

Q = One or more quality control criteria failed.



### Encryption

Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

CLAYTON JOHNSON, Project Manager

Email: CJohnson@maxxam.ca

Phone# (905) 817-5769

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section

5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 1

Page 1 of 8

### BT Environmental Consulting

Maxxam Job #: B1J5560 Client Project #: 11-4190.00

Report Date: 2011/12/22 Site Location: JM DEFIANCE



### RESULTS OF ANALYSES OF STACK SAMPLING TRAIN

Maxxam ID L Y 4 1 1 3 L

Y 4 1 4 2 L

Y 4 1 4 3 L

Y 4 1 4 3 L

Y 4 1 4 4

Sampling Date 2011/12/08 2011/12/07 2011/12/08 2011/12/08 2011/12/08

U n i t s BLANK--M0061 RDL RUN RUN RUN RUN RDL QC Batch

1-M0061 2-M0061 2-M0061 3-M0061

Lab-Dup

Acetone Rinse Volume ml 300 1 260 290 340 1 2714839

Potassium Hydroxide Volume ml 306 1 588 629 619 1 2714826

Hexavalent Chromium (Cr 6+) ug 0.3 0.2 0.16 J 0.29 J 0.29 J 0.13 J 0.3 2715660

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 2 of 8

### BT Environmental Consulting

Maxxam Job #: B1J5560 Client Project #: 11-4190.00

Report Date: 2011/12/22 Site Location: JM DEFIANCE



### ELEMENTS BY ICP-AES (STACK SAMPLING TRAIN)

Maxxam ID L Y 4 1 1 3 L

Y 4 1 4 2 L

Y 4 1 4 2 L

Y 4 1 4 3 L

Y 4 1 4 4

Sampling Date 2011/12/08 2011/12/07 2011/12/07 2011/12/08 2011/12/08

U n i t s BLANK--M0061 RDL RUN RUN RUN RUN RDL QC Batch

1-M0061 1-M0061 2-M0061 3-M0061

Lab-Dup

Back Half Chromium (Cr) ug 1 U 2 2 U 2 U 2 U 2 U 4 2714109

Front Half Chromium (Cr) ug 0.2 U 0.3 0.5 0.3 0.2 U 0.2 U 0.3 2714113

Rinse Chromium (Cr) ug 1 U 2 1 U 1 U 1 U 1 U 2 2714115

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 3 of 8

### BT Environmental Consulting

Maxxam Job #: B1J5560 Client Project #: 11-4190.00

Report Date: 2011/12/22 Site Location: JM DEFIANCE



### Test Summary

Maxxam ID LY4113 Collected 2011/12/08

Sample ID BLANK--M0061 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Hexavalent Chromium (M0061) IC /SPEC 2715660 2011/12/16 2011/12/16 LANG LE

Chromium on Filter by ICP ICP 2714113 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Impinger by ICP ICP 2714109 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Train Rinse by ICP ICP 2714115 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Final Volume of KOH Impinger 2714826 N/A 2011/12/15 FRANK MO

Final Volume of Train Rinse 2714839 N/A 2011/12/15 FRANK MO

Maxxam ID LY4142 Collected 2011/12/07

Sample ID RUN 1-M0061 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Hexavalent Chromium (M0061) IC /SPEC 2715660 2011/12/16 2011/12/16 LANG LE

Chromium on Filter by ICP ICP 2714113 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Impinger by ICP ICP 2714109 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Train Rinse by ICP ICP 2714115 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Final Volume of KOH Impinger 2714826 N/A 2011/12/15 FRANK MO

Final Volume of Train Rinse 2714839 N/A 2011/12/15 FRANK MO

Maxxam ID LY4142 D u p Collected 2011/12/07

Sample ID RUN 1-M0061 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Chromium on Filter by ICP ICP 2714113 2011/12/16 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Impinger by ICP ICP 2714109 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Train Rinse by ICP ICP 2714115 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Maxxam ID LY4143 Collected 2011/12/08

Sample ID RUN 2-M0061 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Hexavalent Chromium (M0061) IC /SPEC 2715660 2011/12/16 2011/12/16 LANG LE

Chromium on Filter by ICP ICP 2714113 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Impinger by ICP ICP 2714109 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Train Rinse by ICP ICP 2714115 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Final Volume of KOH Impinger 2714826 N/A 2011/12/15 FRANK MO

Final Volume of Train Rinse 2714839 N/A 2011/12/15 FRANK MO

Maxxam ID LY4143 D u p Collected 2011/12/08

Sample ID RUN 2-M0061 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Hexavalent Chromium (M0061) IC /SPEC 2715660 2011/12/16 2011/12/16 LANG LE

Page 4 of 8

### BT Environmental Consulting

Maxxam Job #: B1J5560 Client Project #: 11-4190.00

Report Date: 2011/12/22 Site Location: JM DEFIANCE



### Test Summary

Maxxam ID LY4144 Collected 2011/12/08

Sample ID RUN 3-M0061 Shipped

Matrix Stack Sampling Train Received 2011/12/12

Test Description Instrumentation Batch Extracted Analyzed Analyst

Hexavalent Chromium (M0061) IC /SPEC 2715660 2011/12/16 2011/12/16 LANG LE

Chromium on Filter by ICP ICP 2714113 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Impinger by ICP ICP 2714109 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Chromium in Train Rinse by ICP ICP 2714115 2011/12/15 2011/12/17 SUBAN KANAPATHIPPLLAI

Final Volume of KOH Impinger 2714826 N/A 2011/12/15 FRANK MO

Final Volume of Train Rinse 2714839 N/A 2011/12/15 FRANK MO

Page 5 of 8

### BT Environmental Consulting

Maxxam Job #: B1J5560 Client Project #: 11-4190.00

Report Date: 2011/12/22 Site Location: JM DEFIANCE

GENERAL COMMENTS

Results relate only to the items tested.

Page 6 of 8

### BT Environmental Consulting

Attention: James K. Sharp

Client Project #: 11-4190.00

P.O. #:

Site Location: JM DEFIANCE



### Quality Assurance Report

Maxxam Job Number: GB1J5560

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2714109 SUK Matrix Spike

(LY4142) Back Half Chromium (Cr) 2011/12/17 95 % 80

- 120

Matrix Spike DUP

(LY4142) Back Half Chromium (Cr) 2011/12/17 97 % 80

- 120

MS/MSD RPD Back Half Chromium (Cr) 2011/12/17 1.9 % 20

Spiked Blank Back Half Chromium (Cr) 2011/12/17 99 % 90

- 110

Spiked Blank DUP Back Half Chromium (Cr) 2011/12/17 100 % 90

- 110

RPD Back Half Chromium (Cr) 2011/12/17 1 % 20

Method Blank Back Half Chromium (Cr) 2011/12/17 0.3 U, MDL=0.3 ug

RPD

- Sample/Sample

Dup Back Half Chromium (Cr) 2011/12/17 NC % 20

2714113 SUK Matrix Spike

(LY4142) Front Half Chromium (Cr) 2011/12/17 106 % 80

- 120

Spiked Blank Front Half Chromium (Cr) 2011/12/17 106 % 90

- 110

Spiked Blank DUP Front Half Chromium (Cr) 2011/12/17 107 % 90

- 110

RPD Front Half Chromium (Cr) 2011/12/17 0.7 % 20

Method Blank Front Half Chromium (Cr) 2011/12/17 0.3 U, MDL=0.3 ug

RPD

- Sample/Sample

Dup Front Half Chromium (Cr) 2011/12/17 NC % 20

2714115 SUK Matrix Spike

(LY4142) Rinse Chromium (Cr) 2011/12/17 99 % 80

- 120

Matrix Spike DUP

(LY4142) Rinse Chromium (Cr) 2011/12/17 100 % 80

- 120

MS/MSD RPD Rinse Chromium (Cr) 2011/12/17 0.4 % 20

Spiked Blank Rinse Chromium (Cr) 2011/12/17 102 % 90

- 110

Spiked Blank DUP Rinse Chromium (Cr) 2011/12/17 103 % 90

- 110

RPD Rinse Chromium (Cr) 2011/12/17 0.6 % 20

Method Blank Rinse Chromium (Cr) 2011/12/17 0.3 U, MDL=0.3 ug

RPD

- Sample/Sample

Dup Rinse Chromium (Cr) 2011/12/17 NC % 20

2715660 LLE Matrix Spike

(LY4143) Hexavalent Chromium (Cr 6+) 2011/12/16 106 % 80

- 120

Spiked Blank Hexavalent Chromium (Cr 6+) 2011/12/16 100 % 90

- 110

Method Blank Hexavalent Chromium (Cr 6+) 2011/12/16 0.03 U, MDL=0.03 ug

RPD

- Sample/Sample

Dup Hexavalent Chromium (Cr 6+) 2011/12/16 NC % 20

Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.

Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.

Spiked Blank: A blank matrix to which a known amount of the analyte has been added. Used to evaluate analyte recovery.

Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.

NC (RPD): The RPD was not calculated. The level of analyte detected in the parent sample and its duplicate was not sufficiently significant to permit a

reliable calculation.

Page 7 of 8

## Validation Signature Page

Maxxam Job #: B1J5560

The analytical data

and all QC contained

in this report

were reviewed

and validated by the following individual(s).

FRANK MO, B.Sc., Inorganic Lab. Manager

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of

ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Page 8 of 8