TS-K784YD00TestReportMeasurementofthemolecularweightsICBICBIAttachment1PagelI17S50788300TS-K784YD.[Summary]Attachment1Page2I178507883Themeasurementsoftheaveragemolecularweightsandthecontentsofcomponentshavingmolecularweightoflessthan1000andlessthan500ofthetestsamplejCBIIwerecarriedoutusingGPC.TheresultsareshowninTableA.TableAAveragemolecularweightsandContentsofcomponentslessthanMW1000andlessthanMW500*Numberaveragemolecularweight(M11)Weightaveragemolecularweight(Mw)Zaveragemolecularweight(M2)Polydispersity(MwiMn)Polydispersity(M2IMw)Contentofcomponent<MW1000Contentofcomponent<MW500*relativevaluesofpolystyrenestandards-1-0TS-K784YD1.SponsorNameAddress2.TestLaboratoryAttachment1Page3I17S507883NameAddress3.ObjectiveTheobjectiveoftllismeasurementistoobtaintheaveragemolecularweightsandcontentsofcomponentshavingmolecularweightoflessthan1000andlessthan500of...IC_BI__.....;__.4.SampleCBI5.Experimental5.1PrincipleGelpermeationchromatography(GPC)isafamilyoftheliquidchromatographythatseparatesmoleculesofthepolymersamplebythedifferenceintheirmolecularsize.Thepolymermoleculesareseparatedinthecolumnpackedwiththegelsthathavetheporeofthesamesizeasthepolymersizeindilutesolution(hydrodynanlicvolume).Thehighmolecularweight·componentiselutedfasterthanthelowmolecularweightcomponentbecausethehighmolecularweightcomponentisslightlypermeableintotheporeofthegel.ThereforeGPCprovidesthemolecularweightdistributioncurveandtheaveragemolecularweightsofthepolymer.5.2MeasurementParametersApparatusGelPermeationChromatograph(GPC-19)DetectorDifferentialrefractiveindexdetectorRI-8020(TOSOH)DataProcessingsystemGPCDataProcessingSystem(TorayresearchCenter)ColumnsetColumnsetofthreeTSKgelMultiporeHXL-M(TOSOH)MobilePhaseTetrahydrofuran-2-0 0 TS-K784YD Flow rate Temperature Sample Concentration Solubility Filtration Injection volume the calibration curve of the standar ds 6. Results 6.1 GPC Curve

1.0 rnUmin 23±2'C 0.20% (w / v) Soluble 0.45 **~-tm-Millex-LH** (Millipore)

. 0.200 rnL

. Polystyrene (PS) standar ds (TOSOH) Attachment

1 Page4

I 1.7 S50 7883 The GPC curve of the samp le is shown in Fig.1 and Fig.2. The signal of the .e luted sample was detected from about 18 min. to 33 min. The peaks detected after about 33 min. of t he elution time were the solvent-composition-change

, so lvent-impurity and/or the sys tem peak (It was confirmed by the GPC measurement

of th e solvent. See Fig.3). 6.2 Calibration curve of molecular weight The calibration curve of polystyrene

( PS) standards

is shown in Fig.4. The calibration curve was obtained from the r e lation

s hip between the mole c ula r weight and el ution time under the same GPC conditions. In this report the calcu

l ated molecular weights were relative

v alues of PS standards. log M where,

M

: Molecular weight : Elut ion time Ai

: Coefficients

(1) 6.3 Ca l culation of molecular weight distribution (MWD) and average molecular weights The MWD was originated by the RI curves of the sample (Fig.

I and Fig.2) and the calibration curve (Fig.4) using GPC data processing system. The MWD curve and the average molecular weigh

t s are shown in Fig.5, Fig.6 and Table A, respectively

. The average molecular weights were calculated accord ing to Eqs. (2), (3) and

( 4) . / M ="L-(N·

• M·)I<£N· n

z z

z

(2) - 3-00TS-K784YDM.=2:(N-•M.2)12:(N·•M.·)WllIIM;=2:(Ni•Mi3)12:(Ni•Mi2)where,MnMw:Numberaveragemolecularweight:WeightaveragemolecularweightMz:ZaveragemolecularweightNi:molarfractionatelutiontimetiMi:molecularweightatelutiontimetiAttachment1PageSI17(3)(4)S507883Thepolydispersity(MwIMn,MzIMw),indicatingtheindexofthedispersionofMWD,isshowninTableAwhere,MwIMn:Polydispersity(theindexofthedispersioninthelowmolecularweightregion)MzIMw:Polydispersity(theindexofthedispersioninthehighmolecularweightregion)6.4Contentofthecomponentslessthanmolecularweight1000and500TherawdataofMWDcalculatedaccordingtothesection6.3areshowninTable1andTable2.Thecontentofthecomponents havingmolecularweightoflessthan1000andlessthan500wereICBII7.ConclusionThemeasurementsoftheaveragemolecularweightsandthecontentsofcomponentsmolecularweightoflessthan1000andlessthan500ofiCBIIwerecarriedoutusingGPC.ThenumberaveragemolecularweightandtheweightayeragemolecularweightofthesamplewereICBIIrespectively.Thecontentofthecomponentshavingmolecularweightoflessthan1000andlessthan500were....IC_BI______,-4-.___rs•______.l-0 0 TS-K784YD

Attac h ment

1 Page6

/ 17 ssoi883 Thls work was carried out by Chemist Chihiro Hamashlge, Research Associate Kazutomo Akasaka and Manager Tsuneyuki Yamane at ... lc_B.;.. Jt _;..__ .....;. .;.._ _ _;......;._..;._.;.._ _ _.:;. ___ ....... ICBI

I Manager

: Tsuneyuki Yamane Signature: Tsunevy k.; 'to mane / Date:

Se .D . / / 20/3 r

. Study Director

: Kazutomo Akasaka Signature:

Date: -5-

# 0 Table 1 Molecular Weight Data



# ,_,, I :' 

# - · ''"'I . " 

# l , 1**Flf~** 

### . ADS . Ql() llw . ..: .• : -**Ar~a** : 278. 00 1V • sec liz :**.~-' ~**  -:. O!lerator: Hamuhise llv : 

# .J: :: · .**Oat~** : 2013/9/4 llw/lln:**~-~'i·** 

### - .. · llz!l.lw: · -.: .. Retention llolecular Intens i ty 

### d!!ei&btl

Tile leisht 

### IIIVl d LogOftl J.i 

### nl 18. 23 441128 Q. 000 0 . 000 18. 32 422401 0. 000 D. 000 18. 40 404469 . 0. 002 . 0. 002 18.48 387298 0. 003 0. 003 18 . 57 370856 0. 003 0. 003 18. 65 355113 0. 006 0. 006 18.73 340038 D. 006 D. 006 18.82 325602 0. 007 D. 007 18.90 311780 0. 009 0. 008 18.98 298544 0. 011 0. 011 19.07 285870 ' 0. 014 0. 013 19. 15 273734 0. 015 0. 014 19 . 23 262114 0. 018 0. 017 19 . 32 250986 0. 022 0. 021 19 . 40 240331 0. 025 0.024 19 . 48 230129 0. 027 0. 026 19 . 57 220359 0. 031 0. 029 19.65 211005 0. 035 0. 033 19 . 

### 73 202047 0. 040 0 . 039 19 . 82 193470 0. 046 0. 044 19.90 185256 0. 050 D. 048 19.98 177392 0. 056 0. 054 20. 07 169861 0. 063 0. 060 20. 15 162650 0. 069 0 . 066 20. 23 155745 0.077 D. 073 20. 32 149134 0. 085 D. 081 20 . 40 142803 0. 092 0. 088 20 . 48 136740 0. 101 D. 096 20 . 57 130935 0 . 111 0 . 106 20 . 65 125377 0 . 120 0. 115 20.73 120054 0.131 0. 125 20.82 114958 0. 1 42 0. 136 20.90 110078 0. 154 0. 147 20 . 98 105405 0. 168 0. 160 21.07 100930 0. 181 0. 173 21. 15 96645 0 . 195 0. 187 21 . 23 92542 0. 211 0. 201 21. 32 88614 0. 227 0. 217 

### 21. 40 84852 0. 243 0. 232 21 . 48 81250 0. 260 0. 248 21 . 57 77800 0. 278 0. 266 21 . 65 W98 0. 297 0. 283

- File : AOS . Iml SSD7883

Weight X

100. 00 100.00 100. 00 99.99 99 . 99 99.98 99 . 97 99 . 95 99.94 ' 99 . 92 I 99. 90 99.87 99 . 84 99 . 80 99.76 99 . 71 99 . 66 99.60 99 . 53 99 . 45 99 . 37 99 . 27 99 . 16 99 . 04 98 . 91 98 . 76 98 . 60 98. 43 98 . 24 98 . 03 97.80 97.55 97.28 96 . 99 96 . 67 96 . 33 95 . 96 95 . 57 95.14 94. 69 94 . 20 93.68 Table 1 Page

- 1 

# 0

Retention llolecular Intensity

Ti1e Weiaht (mV) IIi n) 21. 73 71335 0. 316 21 . 82 68307 . 0 . 336 21. 90**65~07** 0. 358 21. 98 62630 

## o. 380 

### 22. 07 59971 0 . 402 

### 22. 15 57426 0 . 426 22. 23 54988 0. 449 22. 32 52653 

## o . .m 2Z. 40 50418 0.**~98** 22.48 48278 0. 523 22. 57**~6228** 0. 548 22. 65**~4266** 0 . 575 22.73**~2387** 0 . 602 22. 82 40587 0 . 628 22. 90 38864 0. 656 22. 98 37214 0. 683 23 . 07 35634 0 . 710 2l. 15 34122 D. 737 23. 23 32673 

## o. 765 23 . 32 31286 0. 792 23 . 40 29958 0 . 819 2l48 28686 0. 845 23 . 57 27468 6.371 2l65 26302 0. 896 23 . 73 25186 0. 919 2l. 82 24116 

## o. 943 2l. 90 23093 0 . 964 

### 2198 22112 0. 984 24. 07 21174 1. 003 24 . 15 20275 1 . 018 24 . 23 19414 1 . 032 24 . 32 18590 1 . 043 24 . 40 17801 1. 051 24 . 48 17045 1 . 056 24 . 57 16321 1 . 058 24 . 65 15629 1 . 057 24 . 73 14965 1 . 054 24.82 W30 1. 046 24 . 90 13721 1. 035 2.(. 98 13139 1 . 021 25 . 07 12581 1. 005 25. 15 12047 0. 985 25.23 11536 D . 965 25 . 32 11046 D. 941 25 . 40 10577 Q. 915 25.48 10128 0. 888 25 . 57 9698 

## o. 859 25.65 9286 0. 830 25.73 8892 0. 799 f il e : AOS . ItiD 

### d !rci&bll d Los Mil D . 302 0. 321 0 . 341 D. 363 D. 384 0. 406 D. 429 0. 452 0 475 0. 499 0. 524 0 . 549 D. 575 D. 600 0. 626 D. 652 

### 0.677 D. 704 D. 731 0 . 756 0 . 782 0 . 807 0. 831 0 . 855 D. 878 D. 900 0 . 920 0 . 940 D. 957 0 . 972 D. 985 0 . 996 1. 004 1. 008 1. 010 1. 009 1 . 006 0. 999 0 . 988 0 . 974 D. 959 0 . 941 D. 921 0. 898 0 . 874 D. 848 

## o . 820 0 . 792 

## o . 763 S507883 leiaht X

93 . 13 92 . 54 91.91 91.24 90. 53 39.79 88 . 99 88. 16 87 . 28 86 . 36 85 . 39 84 . 38 83.32 82 . 20 81.04 79 . 83 78 . 58 

### 77. 27 75.92**1~-** 51 73. 06 71.56 70. 01 68 . 41 66.78 65. 10 63. 38 61. 62 59 . 83 58.01 

### 56.17 54.30 5Z. 41 50 . 52 48 . 62 46.71 44 . 82 42 . 93 41.06 39 . 21 37 . 39 ' 35. 51 33.86 32. 15 30 . 48 28 . 86 27 . 30 25.78 24.33 -; (/) I ::><; 

## ..., 

# "' .... -< 0

)> 

### -u:+ 

# .. ..

... (l

.. ::r ...,3 -..... <> -;:l.**...,~** Table 1 Page

- 2

# 0 $507883 Retention Molecular lntensi ty 

### dllei&btl Weight f

Ti11e Weisht 

### !IIVJ d Logllfl 

### Ill in! 25.82 8515 

## o. 768 0 . 733 22.92 25. 90 8153 0. 738 0. 704 2 1 .57 25 . 98 7807 0. 707 0 . 675 20. 28 26.07 7476 0. 675 0. 645 19.04 

### . . 26. 15 7158 0. 646 0. 6 1 6 l7. 86 26. 23 6&54 0. 615 0. 587 16. 73 26.32 6563 0. 585 0. 559 1 5 .6 6 26. 40 6285 0 . 556 0. 531 14.64 26. 48 6018 0. 527 0. 503 13. 67 26.57 5762 0. 499 0.477 12.75 26. 65 5518 0. 474 D . 452 11.88 26.73 5284 0. 448 0. 428 11.05 26. 82 5059 0.423 0. 404 10. 28 26. 90 4U5 0 . 399 0. 381 9. 54 26. 98 4639 0 . 376 D. 359 8 . 85 27 . 07**~442** 0. 355 0 . 338 8 . 19 27. 15 4253 0 . 334 0 . 319 7. 58 27 . 23**~073** 0. 312 0 . 298 7. 00 27 . 32 39 00 0. 294 0 . 280 6 . 46 27 . 4D 3734 0 . 274 D . 262 5. 95 27.48 3576 0 . 255 0. 244 5 . 48 27.57 3424 0 . 239 0. 228 5. 04 27 . 65 3279 0. 222 0 . 212 4. 63 27.73 3139 

## o. 206 0. 197 4. 25 27.82 3006 0 . 1

92 0. 183 3.89 27. 90 2879 0.177 0. 169 3 . 56 

### 27. 98 2756 0. 162 0. 155 3. 26 28. 07 2639 0. 151 0 . 144 2 . 98 28. 15 2527 

## o : 139 0 . 133 2. 72 28. 23 2420 0. 129 

## o . 123 2.49 28.32 2317 0.117 0. 112 2 . 27 28.40 2219 0 . 107 0. 102 2 . 07 28.48 2 1 25 0. 100 0. 095 1.88 28. 57 2035 0. 091 0. D87 1.71 28 . 65 1948 

## o . 083 0. 080 1 . 56 28 . 73 1865 0.077 0. 073 l. 42 23. 82 1786 0 . 069 0. 066 I . 29 28 . 90 1710 0. 063 0 . 060 l. 17 23. 98 1638 0. 058 0 . 055 l. 06 2 9

. 07 1568 

## o . 052 D. 050 

## o. 96 29 . 15 1502 0. 047 

## o. 045 D. 87 2 9. 23 1438 0. 043 0. 04 1 

## o. 79 29. 32 1377 

## o. 039 0. 037 

## o.n 29 . 40 1318 

## o . 035 0. 034 

## o. 65 29 .48 1262 D. 033 0. 031 0. 59 29 . 57 1209 

## o . 029 0. 028 0. 54 29 . 65 1158 0. 027 0. 025 

## o. 49 29 . 73 1108 D. 024 0. 023 

## o. 44 29. 82 1061 0. 02Z D. 02 1 0. 40 

### F i I 

### e : A O S.IIMl Table 1 Poage

- 3 

# 0

Relent ion lololecula r I ntens i IY

Tl•e Ieight 

### (•VJ fllin) 29. 90 

## --------ifgf:··- 1 0 16 

## --·-------- 973 ______ 0. 020 

## ---.- - --- ii"li18

- --- - 30. 07 932 0. 016 30 . 15 892 D. 016 30 . 23 854 D. 014 30. 32 8 18 0. 013 30.40 783 0. 014 30 . 48 750 0 . 013 30 . 57 718 0 . 013 30 . 65 688 0. 014 30.73 659 0. 013 30.82 631 0. 0 12 30.9 0 604 0 . 010 30 . 98 578 0 . 007 31. 07 554 0 . 006 31. 15 530 0. 004



### _______ JUL ... _______ ___ jjljl__

_ ___



### _ _________ O,_Q9L ... 31. 32 486 0 . 002 31. 40 465 0. 002 31. 48 446 0. 001 31.57 427 0. 001 31. 65 409 0. 000 31 . 73 391 0. 000 31. 82 375 0. 000 31. 9 0 359 0. 000 31.98 344 0 . 000 32. 07 329 0. 001 32. 15 315 0. 000 32. 23 302 0. 0 0 1 32. 32 289 0. 002 32. 40 

### 277 0. 001 32. 48 265 0. 001 32.57 254 0. 000 32.65 243 0 . 00 0 32.73 233 0. 000 32.82 223 0. 000 32.9 0 213 0. 000 32.98 204 0. 000



### Fi I 

### e : AOS . 

### t.1JD d !lei sbtl d Los 

# om 0. 019



## ------ ----ii"oi 

## 1"------ 0. 016 0. 015 0. 013 0 . 013 0. 013 0. 012 0. 013 0. 013 0 . 013 0.011 0 . 009 0. 007 

### 0. 005 

### 0. 004



### _ __ _______ !l., _QOL • •. • • • 0. 002 0. 002 0. 001 0. 001 0. 000 0. 000 0. 000 0. 000 0. 000 0. 001 0. 000 D.n01 0. 002 0. 0

0 1 0. 001 0. 0

0 0 

## o . 000 0. ODO 0. 000 0. 000 0. 0 0 0 S507883 Weight f



## ---.**·---~c~L** 

## .. ---- 0 . 33 

## o . 30 0 . 27 0. 25 0. 22 

## o . 20 0.18 0.15 0. 13 0. 10 0. 08 

## o. 06 0. 05 0 . 04 0. 03

________ Qj)_2. _______ 

# o . 02 0. 02 

## o. 01 0. 01 0 . 01 

# o. 01 0 . 0 1 

## o. 01 0. 0 1 0. 01 0. 01 D. 0 1 0 . 00 

## o. 00 0. 0 0 0. 00 0. 0 0 

## o . 00 

# o. 0 0 0 . 00 0. 00

Table 

### 1 Page

- 4 -i Cll I 

# "'

..... 00

### ~ 0

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## "' "'

.. 0

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### 003 

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### ..... 

# _

# 0 Table 2 Molecular Weight Dar:t:=a"""""":"'"""=

Sa•ple 

# : I _,· - lXI 

# nl lin . ; 7**-~-;** 

# &l File 

### XUS: 1110 llw ,,.., - Areo 289.85 

### •V ·sec liz**-·~::.,..h~** Operator Hamshi &e 

### llv 

# ·.::"£-_:**~-** 

# .. Date 2013/9/4 

### llw / lhl : --•···· · · llz /llw: ·. ·•.- •.· · Relent ion llol ecular IntensIty 

### d !t:cisbll

Ti•e Ieicht linin) (•Vl 

### d log 

### OM 18. 23 441128 0. ODD 0. 000 18. 32 422401 0. 001 0. 001 18. 40 404469 0 . 002 0. 002 18. 48 387Z98 0 . 003 0. 0 0 3 18.57 370356 0. 005 0 . 004 18. 65 355113 0. 005 0. OD5 18.73 340038 0. 007 0. 007

. 18. 82 325602 0. 009 0. OD8

18. 9D 311780 0 . 010 0. 009 1 8.98 298544 0 . 014 D . 013 1 9

. 07 285870 0. 016 D . 015 19. 

### IS 273734 0 . 019 0. 017 19. 23 262114 0 . 021 D . 019 1 9

. 32 250986 0. 024 D . 022 19.40 240331 0 . 028 0. 025 1 9

.48 230129 

### o . 032 0 . 029 1 9

.- 57 220359 0. 035 

### 0 032 19 . 65 2 1 1005 0. 039 0 . 036 1 9.73 202047 0 . 043 0. 040 19 . 82 193470 

## o . 049 0. 045 1 9

. 90 185256 0. 053 0. 049 1 9. 98 177392 

## o . 060 0. 055 20 . 07 169861 0. 067 0. 061 20. 15 162650 

## o . 074 0. 068 20. 23 15514 5 0 . 082 0 . 075 20 . 32 149134 0 . 090 0. 083 20 . 40 142803 -. 0 . 098 0. 089 20.48 136740 0. 107 0 . 098 20. 57 1 30935 0.117 0. 108 20. 65 t253n 0. 127 0. 116 20 . 73 120054 D . 137 0. 126 20 . 82 11 4958 0. 150 0. 137 20. 90 110078 0. 161 

## a. 14 8 20 . 98 105405 0 . 175 

## a. 160 21 . 07 100930 0 . 189 

### Q.173 21. 15 96645 

## o . 203 0. 186 21 . 23 92542 0. 219 0. 200 21.32 88614 0. 235 

## o . 215 21.40 84852 0. 252 0. 230 21.48 81250 0. 271 

## a. 248 21.57 77800 0 . 288 0. 264 21. 65 74498 0. 309 

## o . 283 Fi l e : A06.1ltll S5D7883

Weight X 

# I

10D . 00 100.00 10D . 00 99.99 99. 98 99.98 99 . 96 99 . 95 99. 93 99 . 91 99.89 99 . 86 99. 82 99.78 99.74 99 . 69 99 . 63 99. 56 99 . 49 99.41 99. 32 99 . 23 99 . 11 98 . 99 98.86 98 . 71 98.54 98. 36 98 . 1 7 97 . 96 97 . 73 97.48 97. 21 96. 92 96.60 96 . 26 95 . 89 95 . 50 95 . 07 94 . 62 94 . 13 93 . 6 2 Table 2 Page

- 1 

# 0

Retention llo lec ular lntensi tY

Ti •e Wcl&ht t.Vl t.inl 21. 73 71335 0. 328 21.82 68307 0. 350 21.90 65407 0. 371 21. 98 62630 0. 394 22. 07 59971 0.417 22 . 15 57426 0.441 22. 23 54988 0. 465 22. 32 52653 0. 489 22.40 50418 0. 516 22.48 48278 0. 542 22. 57 46228 0. 568 22. 65 44266 0. 596 

### 22.73 42387 0. 623 22.82 40587 0. 650 22. 90 38864 0. 678 22.98 37214 0. 706 23 . 07 35634 0. 7 35 23 . 15 34122 0. 763 23 . 23 32673 0. 792 23 . 32 31286 0. 820 23.40 29958 0. 846 2U8 28686 0. 874 

### 23. 57 27468 0. 902 23 . 65 26302 0. 929 2173 25186 0. 954 23.82 24116 0. 979 219D 23093 1 . 002 2 3.98 22112 1. 022 24.07 21174 1. 042 24. 15 20275 1. 059 24. 23 19414 1. 075 24. 32 18590 1. 087 24. 4D i7801 1. 095 24.48 17045 1. 101 24.57 1632 1 1. 102 24. 65 15629 1. 102 24.73 14965 1. 098 24.82 14330 1. 089 24.

- 90 1372 1 I. 079 24. 98 13139 I. 065 25. 07 1258 1 1. 04 8 25. 15 12047 I. 028 25. 23 11536 1. 005 25.32 110<46 0. 980 25.40 10577 0. 953 25.48 10128 0. 926 25. 57 9698 0. 895 25 . 65 9286 

## a. 865 25.73 8892 

## a. 832 File : A06 . 1ltll 

### dllcisbll d Locom 0. 301 0. 320 0. 340 0. 3 6 1 0. 382 0.404 

## o.m 0. 448 0. 472 0. 496 0 . 52D 0 . 546 0. 571 0 . 595 0. 621 0. 647 0 . 673 0 . 699 0.725 0. 751 0. 775 0. 80D 0. 826 0.850 0. 874 0. 896 0. 917 0. 936 0. 954 0. 970 0.934 0. 995 1. 003 1. 008 1. 009 1. OD9 I. 005 0. 998 0. 988 0. 975 0. 959 0. 941

. 0. 921 0. 897 0. 873 0. 848 0. 820 0. 792 0. 762

- S 507883 Ieight %

93 . 06 92 . 47 91.85 91. 18 90.44 89 . 74 88 . 95 88 . 13 87.25 86. 34 85 . 34 84 . 37 8131 82.21 81.06 79 . 86 78 . 61 77. 31 75 .97 74 . 57 73. 13 71.64 70. 11 68. 52 66. 89 65. 22 63 . 51 61.76 59.98 58 . 16 56 . 32 54.45 52.57 50 . 67 48 . 77 46 . 87 44.97 43 . 09 41.22 39.37 37.55 35 . 76 34. 01 32. 31 30.64 29 . 03 27 . 46 25 . 95 24 . 49 -t (/) I ;>;;

...... 00 

# ... -< 0

)> 

### -u:+ 

# .. 

# ..

.. 0

.. :r "'3 

## ...... .. -;:?.

...... Table 2 Page - 2

# 0 S507883 Retent i on Uol ecula r Intens i ty 

### d rfci tbll Weicht s

Ti•e lei !ht (mV) d 

### locaftl f.inl 25.82 8515 

## o . 800 0. 733 23. 09 25.90 8153 0. 767 0. 702 21.74 25. 98 7807 0. 73. 0.672 20.

**~5** 26.07 7476 

## o . 702 0. 642 19 . 22 26. 15 7158 0. 670 0..613 18.04 26.23

**685~** 0. 638 0. 585 16.92 26. 32 6563 0. 6D7 0. 556 15 . 85 26. 40 6285 0. 577 0. 529 14 . 8.4 26.48 6018 0. 548 0. 5 01 13.87 26. 5 7 5762 0. 518 0 . 474 12.96 26. 65 . 5518 0. 490

**0.~9** 12 . 09 26. 73 528. 0. 465 0. 426 11.21 26. 82 5059 0 . 439 0. 402 10. 50 . 26.90 4845 0. 415 0. 380 9 . 76 26. 98 4639 0. 39 1 0 . 358 9 . 07 27.07 4442 0. 369 0. 337 3.42 27. 15 4253 0. 345 0. 316 7. 81 27.23 4073 0. 324 0. 297 7. 24 27. 32 3900 0. 304 0. 278 6.70 27.40 3734 0. 285 0. 261 6. 19 27.48 3576 0. 267 0. 244 5 . 72 27 . 57 3424 0. 249 0. 228 5 . 28 27.65 3279 0. 232 0. 213 4. 87 27. 73 3 1 39 0. 216 0. 198 4. 49 27. 82 3006 0. 20 1 0.184 4 . 13 27.90 2879 0. 186 0. 170 3. 80 27.98 2756 0.172 0.158 3. 49 28.07 2639 0 . 158 0. 14 5 3. 21 28. 15 2527 D . 147 0. 134 2 . 95 28. 23 2420 0. 136 0. 125 2. 71 28.32 2317 

## o. 126 0. 11 5 2. 4 8 28. 4 0 2219 D. 116 0. 1 D 6 2 . 28 28.48 2 1 25 0. 108 0. 098 2 . 08 28.57 2035 0 . 099 0. 09 1 1.91 28.65 1948 0. 09 1 0. 084 1.75 28.73 1865 0. 083 0. 076 1 . 6D 28.82 1786 0. 076 0. 070 1. 46 2&. 90 1710 0 . 070 0. 064 1.34 2&. 98 1638 0. 065 0. 059 1. 22 29.07 1568 0. 058 0. 053 1.12 29. 15 1502 0. 053 0. 048 1. 02 29. 23 1438 0. 048 0.044 0. 93 29.32 13n 0. 045 0. 041 0. 85 29. 4 0 1318 0. 040 0. 037 

## o . 78 29.48 m2 0. 036 0. 033 0. 72 29.57 1209 0. 034 0. 031 

## o . 66 29.65 1158 0. 030 0. 028 

## o . 60 29.73 1108 0. D28 0. 025 0 . 55 29.82 1061 0.

**02~** 0. 022 0 . 51 Fi l e : A06.1Ml Table 2 Page - 3 

# 0

Re t ention llol ecular I ntensity

Tl•e lelaht (mV) C.inl 29. 90



## - - - -

---if9f ____ 1 0 1 6 

## - -- - -- - --- 973 ______ 0. 022 

## -------· -o:-o22 _____ 30.07 932 0. 019

. 30. 15 892 0. 0 1 8 30. 23 854 0. 0 1 7 30. 32 8 1 8 O.D17 30.40 783 0. DIS 30.48 750 0. 0 1 6 30. 57 7 1 8 0. 017 30.65 688 0. 016 30.73 659 0. D17 30.82 631 0. DIS 30. 9D 6D4 0. D13 30. 98 

### SIS 0. D11 31. D7 554 0. D09 31. 15 530 0.008



### --- **-- ---~U.L**  

## .. __________ jp_s_

_ __ ___ ___ __ JLQP

_ 6

____ _ 31.32 486 0.004 31.40 465 0. 005 3 1. 48 446 0. 003 3 1. 57 427 0. DD3 3 1. 65 409 0. DD2 3 1. 7 3 39 1 0. 002 31 . 82 375 0. 001 31.90 359 0. DO D 31 . 98 344 0. ODI 32. 07 329 0. 0 0 1 32. 15 315 0. 001 32. 23 302 0. OD1 32. 32 289 0. 001 32.40 

### 277 0. D 0 1 32. 48 265 0. D 0 1 32. 57 254 0. DOD 32.65 243 0. DOD 32. 73 233 0. DOD 32. 82 223 0. DOO 32. 90 213 0. DOD 32. 98 204 0. DOD

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### d [lcitb!l d loc 111'111 0. 021



## ---- - ----o: -oiil

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