## EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -002 UNIT 2
PARTICULATE MATTER, SULFUR DIOXIDE, and VISIBLE EMISSIONS April 2, 2008

Prepared For: Tampa Electric Company Big Bend Station

P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Environmental Services Air Services Group

Environmental Services Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Jorge A. Varino Environmental Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE NO.
1.0 SUMMARY OF RESULTS 1
2.0 DISCUSSION OF RESULTS 2
3.0 SOURCE DESCRIPTION / TEST PROCEDURES 3
4.0 TABULATED RESULTS
SOOT BLOWING PARTICULATE TEST SUMMARY 6
NON SOOT BLOWING PARTICULATE TEST SUMMARY 7
SULFUR DIOXIDE INFORMATION SUMMARY 8
SOOT BLOWING OPACITY DATA SUMMARY 9
NON SOOT BLOWING OPACITY DATA SUMMARY 10
HEAT INPUT CALCULATIONS 11
4.0 FIGURES
FIGURE 1 SAMPLING LOCATION DIAGRAM 13
APPENDICES
A. PARTICULATE MATTER CALCULATIONS
B. PARTICULATE MATTER LABORATORY ANALYTICAL DATA
C. BOILER/PRECIPITATOR OPERATIONAL DATA
D. PLANT CEMS DAHS PRINTOUTS
E. FUEL ANALYSIS
F. FIELD DATA SHEETS
G. SAMPLING EQUIPMENT CALIBRATIONS
H. CHAIN OF CUSTODY
I. TEST PARTICIPANTS

## 1.0 INTRODUCTION
On April 2, 2008, Tampa Electric Company’s Environmental, Health, & Safety Air Services Group, performed source emission tests at the Big Bend Station Boiler No. 2, emissions unit I.D. # -002. Testi ng was conducted in accordance with the Title V Permit #0570039-028-AV, C onditions A.12 through A.14.

1

## 2.0 DISCUSSION OF RESULTS

The particulate matter emission rate under both soot blowing, and non-soot blowing conditions were derived from three United States Environmental Protection Agency (USEPA) Re ference Method 5B test runs. Under soot blowing conditions the average of the three test runs was 0.03 lb/mmBtu. Under nonsoot blowing conditions t he average of the three test runs was 0.03 lb/mmBtu.
The USEPA Consent Decree allowable emi ssion rate under either condition is
0.03 lb/mmBtu.

The Sulfur Dioxide (SO 2 

### ) emission rate was determined using data provided by the Continuous Emissions Monitoring S ystem’s (CEMS) Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was determined to be 0.1 lb/mmBtu, and 298 lb s/hr. The FDEP a llowable emission
rate is 6.5 lbs/mmBtu based on a two hour average, and 3277 lbs/hr based on scenario 3 as listed in condition A.9 of the permit.

Visible emissions were evaluated using a United Sciences In corporated, Model 500C transmissometer (S/N 5001689), duri ng both soot blowing and non-soot blowing testing. The 1-hour average opac ity under soot blowin g conditions was 9%. The 1-hour average opacity under non- soot blowing conditions was 8%. The FDEP allowable emission rate is 20 percent opacity.

During the test performed on April 2, 200 8, Boiler No. 2 was operated at an average heat input rate of 3929 mmBtu/hr. The average quant ity of fuel burned was 166.4 tons per hour. Based on the pe rmitted maximum heat input rate of 3996 mmBtu/hr, the capacity factor for this test was determined to be 98%.

2

## 3.0 SOURCE DESCRIPT ION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The Boiler No. 2 particulate matter sampling location consists of a shared circ ular stack 29.83 feet in diameter with four sample ports located 90 degrees apart on the stack circumference. These ports are located downstr eam of the electrostatic precipitator and the FGD scrubber. The sampling ports were determined to be 8.74 diameters
downstream of the transition ductwork and 2.42 diameters upstream of the stack exit. Using these criteria, a total of 12 sampling points were chosen for particulate sampling as stipulated in t he USEPA Method 1 test procedure. During this test, Boiler No. 1 was not operating, and was isolated from the FGD module. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site.

Boiler No. 2 is serviced by an electrostati c precipitator for the control of flyash emissions, and a flue gas desulfurization (FGD) system for control of sulfur
dioxide emissions. Generat or and precipitator operations data is included in Appendix C of this report.

Particulate sampling was perform ed according to USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources".
Individual test run calcul ations are included as A ppendix A of this report. Particulate matter laboratory analysis may be found in Appendix B of this report.

Diluent gas sampling and anal ysis was performed according to USEPA Method 3B "Gas Analysis for Determination of Emission Rate Correction Factor or Excess Air”. Gas analysis was perform ed on-site using an Orsat analyzer.

Sulfur Dioxide (SO 2 

### ) and Carbon Dioxide (CO 2 

### ) data were provided by the Continuous Emissions Monitoring System (CEMS) Data Acquisition and Handling

3

### System (DAHS). Averages were derived from the time frame of 7:40 through 16:22 on April 2, 2008. This data is in cluded as Appendix D of this report.

Visible emissions were a ssessed using the installed Continuous Opacity Monitor (COM), and the CEMS DAHS.

4

## 4.0 TABULATED RESULTS

5

## BIG BEND STATION PARTICULATE MATTER DATA SUMMARY

Run 1s Run 2s Run 3s V m(std) 

### , scf 37.542 36.185 35.040

B ws 

### , ratio 0.151 0.151 0.151

O 2 

### , % volume 9.00 9.00 9.00

M

d 

### , lb/lb - mole 29.96 29.96 29.96

M

s 

### , lb/lb - mole 28.16 28.16 28.16

Q s 

### , acf/min 1331539.3 1292618.4 1243964.2

Q s(std) 

### , dscf/min 1009297.4 977836.2 940788.7

I, % 102.6 102.1 102.8

C, lbs/dscf 1.894E-06 1.590E-06 1.762E-06

E r 

### , lb/mmBtu 0.03 0.03 0.03

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) 

### 102.50

1.7485E-06

0.03 29.960

28.160

1289373.96

975974.12 

### T est Summary 36.256

0.1505

9.00 

### Boiler #2 WET-BOTTOM UTILITY BOILE R April 2, 2008 SOOT BLOWING



### 6

## BIG BEND STATION PARTICULATE MATTER DATA SUMMARY

Run 1 Run 2 Run 3 V m(std) 

### , scf 37.772 36.577 34.856

B ws 

### , ratio 0.146 0.148 0.140

O 2 

### , % volume 9.00 9.00 9.00

M

d 

### , lb/lb - mole 29.96 29.96 29.96

M

s 

### , lb/lb - mole 28.21 28.19 28.29

Q s 

### , acf/min 1340362.9 1304689.2 1238294.7

Q s(std) 

### , dscf/min 1024958.5 991479.7 949244.0

I, % 101.7 101.8 101.3

C, lbs/dscf 1.605E-06 1.775E-06 2.046E-06

E r 

### , lb/mmBtu 0.03 0.03 0.04

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) 

### 1.8087E-06

0.03 

### NON - SOOT BLOWING

28.229

1294448.95

988560.74

101.60 36.402

0.1447

9.00

29.960 

### Boiler #2 WET-BOTTOM UTILITY BOILE R April 2, 2008

T est Summary



### 7

## BIG BEND STATION SULFUR DIOXIDE DATA FROM CEMs

T est Period Information Start Time 7:40:00 Eastern Standard Time (EST) Stop Time 16:22:00 Eastern Standard Time (EST) T otal Time 8:42:00 Correspondin g to the time frame for the PM test.

Sulfur Dioxide Data:

SO 2 

### CO 2 

### SO 2 

### SO 2 

### ppmvw %, wet lb/mmBtu lbs/hr

24.88 9.83 0.1 298

Calculation Details SO 2 

### , lb/mmBtu = SO 2 

### , ppmvw x C f 

### x F c 

### x (100 / CO2 %, wet)
where: C

f 

### = 1.6635E-07 (lb/scf)/ppm SO 2 

### F c



### = 1800 scf/mmBtu SO 2 

### , lbs/hr = SO 2 

### , lb/mmBtu x Heat Input, mmBtu/hr
where: Heat Input = 3929 mmBtu/hr, from Heat Input Calculation 

### Unit #2 WET-BOTTOM UTILITY BOILER April 2, 2008

CEM DATA RM - 19

8Facility: Big Bend Station Unit: Unit 2 Operating Conditions: Sootblowing

Record# DATE T IME OPA62 Record# DATE T IME OPA62 1 4/2/08 9:07 9.4 31 4/2/08 9:37 9.1 2 4/2/08 9:08 9.7 32 4/2/08 9:38 8.6 3 4/2/08 9:09 9.8 33 4/2/08 9:39 8.4 4 4/2/08 9:10 9.8 34 4/2/08 9:40 8.4 5 4/2/08 9:11 9.8 35 4/2/08 9:41 8.4 6 4/2/08 9:12 9.8 36 4/2/08 9:42 8.4 7 4/2/08 9:13 9.8 37 4/2/08 9:43 8.4 8 4/2/08 9:14 9.4 38 4/2/08 9:44 8.7 9 4/2/08 9:15 9.2 39 4/2/08 9:45 9.0 10 4/2/08 9:16 9.2 40 4/2/08 9:46 9.0 11 4/2/08 9:17 9.2 41 4/2/08 9:47 9.0 12 4/2/08 9:18 9.2 42 4/2/08 9:48 9.0 13 4/2/08 9:19 9.2 43 4/2/08 9:49 9.0 14 4/2/08 9:20 9.2 44 4/2/08 9:50 8.8 15 4/2/08 9:21 9.3 45 4/2/08 9:51 8.5 16 4/2/08 9:22 9.4 46 4/2/08 9:52 8.5 17 4/2/08 9:23 9.4 47 4/2/08 9:53 8.5 18 4/2/08 9:24 9.4 48 4/2/08 9:54 8.5 19 4/2/08 9:25 9.4 49 4/2/08 9:55 8.5 20 4/2/08 9:26 9.3 50 4/2/08 9:56 8.8 21 4/2/08 9:27 9.3 51 4/2/08 9:57 9.0 22 4/2/08 9:28 9.3 52 4/2/08 9:58 9.0 23 4/2/08 9:29 9.3 53 4/2/08 9:59 9.0 24 4/2/08 9:30 9.3 54 4/2/08 10:00 9.0 25 4/2/08 9:31 9.3 55 4/2/08 10:01 9.0 26 4/2/08 9:32 9.2 56 4/2/08 10:02 9.2 27 4/2/08 9:33 9.1 57 4/2/08 10:03 9.5 28 4/2/08 9:34 9.1 58 4/2/08 10:04 9.5 29 4/2/08 9:35 9.1 59 4/2/08 10:05 9.5 30 4/2/08 9:36 9.1 60 4/2/08 10:06 9.5

T est Average: 9.12 % Minimum One Minute Average: 8.40 % Maximum One Minute Average: 9.80 %

Maximum Six Minute Average: 9.78 % V isible Emissions Determination from Opacity Monitor



### 9Facility: Big Bend Station Unit: Unit 2 Operating Conditions: Non-sootblowing

Record# DATE T IME OPA62 Record# DATE T IME OPA62 1 4/2/08 10:53 8.5 31 4/2/08 11:23 8.0 2 4/2/08 10:54 8.5 32 4/2/08 11:24 8.0 3 4/2/08 10:55 8.5 33 4/2/08 11:25 8.0 4 4/2/08 10:56 8.4 34 4/2/08 11:26 8.1 5 4/2/08 10:57 8.4 35 4/2/08 11:27 8.3 6 4/2/08 10:58 8.4 36 4/2/08 11:28 8.3 7 4/2/08 10:59 8.4 37 4/2/08 11:29 8.3 8 4/2/08 11:00 8.4 38 4/2/08 11:30 8.3 9 4/2/08 11:01 8.4 39 4/2/08 11:31 8.3 10 4/2/08 11:02 8.3 40 4/2/08 11:32 8.2 11 4/2/08 11:03 8.3 41 4/2/08 11:33 8.0 12 4/2/08 11:04 8.3 42 4/2/08 11:34 8.0 13 4/2/08 11:05 8.3 43 4/2/08 11:35 8.0 14 4/2/08 11:06 8.3 44 4/2/08 11:36 8.0 15 4/2/08 11:07 8.3 45 4/2/08 11:37 8.0 16 4/2/08 11:08 8.6 46 4/2/08 11:38 8.1 17 4/2/08 11:09 8.8 47 4/2/08 11:39 8.2 18 4/2/08 11:10 8.8 48 4/2/08 11:40 8.2 19 4/2/08 11:11 8.8 49 4/2/08 11:41 8.2 20 4/2/08 11:12 8.8 50 4/2/08 11:42 8.2 21 4/2/08 11:13 8.8 51 4/2/08 11:43 8.2 22 4/2/08 11:14 8.3 52 4/2/08 11:44 8.0 23 4/2/08 11:15 7.8 53 4/2/08 11:45 7.8 24 4/2/08 11:16 7.8 54 4/2/08 11:46 7.8 25 4/2/08 11:17 7.8 55 4/2/08 11:47 7.8 26 4/2/08 11:18 7.8 56 4/2/08 11:48 7.8 27 4/2/08 11:19 7.8 57 4/2/08 11:49 7.8 28 4/2/08 11:20 7.9 58 4/2/08 11:50 7.9 29 4/2/08 11:21 8.0 59 4/2/08 11:51 7.9 30 4/2/08 11:22 8.0 60 4/2/08 11:52 7.9

T est Average: 8.18 % Minimum One Minute Average: 7.80 % Maximum One Minute Average: 8.80 %

Maximum Six Minute Average: 8.77 % V isible Emissions Determination from Opacity Monitor



### 10

## BIG BEND GENERATING STATION HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (March): 10353 KMBtu/MWh 1.0353E+07 MMBtu/MWh

Me g aWatt Hour Inte g rator Information Initial Inte g rator Readin g : 898026 MWh

Final Inte g rator Readin g : 901358 MWh T otal: 3332 MWh

T est Time Information T estin g Start Time: 7:40

T estin g End Time: 16:27

T otal Test Time: 8.78 hours

Calculated Heat Input Avera g e Unit Load, MW = MWh / hours: 379.5 MW Heat Input, MMBtu/h = MMBtu/MWh x MW: 3929 mmBtu/hr

Fuel Consumption Calculation

Laboratory Sample ID: AA93807 Btu as received: 11803 Btu/lb T ons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 166.4 T ons/hour Unit #2
April 2, 2008 WET-BOTTOM UTILTIY BOILER

11

## 5.0 FIGURES

12FIGURE 1 EXHAUST STACK 426.5 ’ EL. BIG BEND GENERATING STATION

PARTICULATE TRAVERSE POINTS

OUTLET 

# N

PORT LOCATION PLAN

REVISED: 10-Jan-06 CS0W1 (BOILERS 1 & 2) TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 8.74

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 2.42

STACK DIAMETER = 29.917 FT. ID. STACK AREA = 702.952 SQ. FT.

PORT LENGTH = 62 IN. TRAVERSE

POINT

1

2

3 % OF STACK DIAMETER IN. FROM STACK WALL

4.4%

14.6%

29.6% 15.80 IN.

52.41 IN.

106.27 IN.

. 499 ’ EL.

165 ’ EL. 261.5 ’

FGD

PRESSURIZED

ANNULUS 72.5 ’



## A

B C D

9 ’ EL.



### 13

## APPENDIX A

PARTICULATE MATTER CALCULATIONS

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 1s Date: April 2, 2008

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.279 inches Barometric Pressure, P b : 29.72 "Hg Nozzle Area, A n : 0.000425 ft 2 Stack Pressure, P s : 29.71 "Hg Average Orifice Meter, Δ H: 1.334 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 39.563 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 93.4 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 127.6 o F 9.0 % O 2 Average √ Δ p: 0.525 "H 2 O 0.0 % CO Condensate Volume, V lc : 141.1 ml 81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V lc 6.651 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 37.542 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.151 % FDA = 1.0 - B w s 0.849 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole M s = (M d x FDA) + (18.0 x B w s ) 28.16 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 31.57 ft/second Q s = v s x A s x 60 1331539.3 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1009297.4 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 102.6 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.03225 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.013 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.010 grains/acf C = c s / 7000 1.894E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.033 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 2s Date: April 2, 2008

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.279 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000425 ft 2 Stack Pressure, P s : 29.74 "Hg Average Orifice Meter, Δ H: 1.273 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 38.794 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 103.5 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 129.3 o F 9.0 % O 2 Average √ Δ p: 0.509 "H 2 O 0.0 % CO Condensate Volume, V lc : 136.0 ml 81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V lc 6.411 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.185 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.151 % FDA = 1.0 - B w s 0.849 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole M s = (M d x FDA) + (18.0 x B w s ) 28.16 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 30.65 ft/second Q s = v s x A s x 60 1292618.4 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 977836.2 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 102.1 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02610 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.011 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.008 grains/acf C = c s / 7000 1.590E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.027 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 3s Date: April 2, 2008

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.279 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000425 ft 2 Stack Pressure, P s : 29.74 "Hg Average Orifice Meter, Δ H: 1.196 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 38.144 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 111.8 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 129.4 o F 9.0 % O 2 Average √ Δ p: 0.490 "H 2 O 0.0 % CO Condensate Volume, V l c : 131.8 ml 81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.213 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 35.040 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.151 % FDA = 1.0 - B ws 0.849 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.16 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.49 ft/second Q s = v s x A s x 60 1243964.2 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 940788.7 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 102.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02800 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.012 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.009 grains/acf C = c s / 7000 1.762E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.030 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 1 Date: April 2, 2008

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.279 inches Barometric Pressure, P b : 29.72 "Hg Nozzle Area, A n : 0.000425 ft 2 Stack Pressure, P s : 29.71 "Hg Average Orifice Meter, Δ H: 1.349 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 39.390 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 87.7 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 125.5 o F 9.0 % O 2 Average √ Δ p: 0.529 "H 2 O 0.0 % CO Condensate Volume, V l c : 137.0 ml 81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.458 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 37.772 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.146 % FDA = 1.0 - B ws 0.854 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.21 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 31.78 ft/second Q s = v s x A s x 60 1340362.9 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1024958.5 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.7 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02750 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.011 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.009 grains/acf C = c s / 7000 1.605E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.028 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 2 Date: April 2, 2008

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.279 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000425 ft 2 Stack Pressure, P s : 29.74 "Hg Average Orifice Meter, Δ H: 1.295 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 38.952 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 99.8 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 128.3 o F 9.0 % O 2 Average √ Δ p: 0.514 "H 2 O 0.0 % CO Condensate Volume, V l c : 135.0 ml 81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.364 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.577 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.148 % FDA = 1.0 - B ws 0.852 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.19 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 30.93 ft/second Q s = v s x A s x 60 1304689.2 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 991479.7 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02945 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.012 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.009 grains/acf C = c s / 7000 1.775E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.030 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 3 Date: April 2, 2008

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.279 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000425 ft 2 Stack Pressure, P s : 29.74 "Hg Average Orifice Meter, Δ H: 1.185 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 37.693 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 108.3 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 128.8 o F 9.0 % O 2 Average √ Δ p: 0.489 "H 2 O 0.0 % CO Condensate Volume, V l c : 120.4 ml 81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 5.676 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 34.856 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.140 % FDA = 1.0 - B ws 0.860 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.29 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.36 ft/second Q s = v s x A s x 60 1238294.7 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 949244.0 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.03235 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0143 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0110 grains/acf C = c s / 7000 2.046E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.035 lbs/MMBtu

## APPENDIX B

PARTICULATE MATTER LABORATORY ANALYTICAL DATACustomerAIR SERVICESPlantBIG BENDUnit2/CS01WMethod5-BStack Test Completion Date04/02/2008AnalystSSSample NumberAA93807ACETONE BEAKER1st weighingDate04/09/2008Time11:05% RH51.0%2nd weighingDate04/10/2008Time11:35% RH50.0%3rd weighingDateTime% RH4th weighingDateTime% RH***Blank***Run 1Run 2Run 3Run 1SRun 2SRun 3SAcetone Container IDAIR IKAIR ICAIR IAAIR IEAIR IFAIR IBAIR IDAcetone Rinse Vol.(Va), mls150.00001501501501501501501st Gross Wt., grams97.4541105.1420103.9537106.2446111.5206105.8612101.41122nd Gross Wt., grams97.4540105.1419103.9535106.2449111.5206105.8612101.41133rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams97.45405105.14195103.95360106.24475111.52060105.86120101.41125Tare Wt., grams97.45445105.13630103.94875106.23520111.51325105.85775101.40515Acetone Blank Wt.,mg-0.40-0.40-0.40-0.40-0.40-0.40-0.40Acetone Particulate Wt.,mg6.055.259.957.753.856.50Acetone Residue, mg/g-0.0034Acetone Blank CriteriaOK to subtract acetone blankFILTER1st weighingDate04/09/2008Time11:25% RH51.0%Date04/10/2008Time11:55% RH50.0%3rd weighingDateTime% RH4th weighingDateTime% RHFilter/Thimble ID203073203079203078203.0742030772030762030751st Gross Wt., grams0.25270.27300.27670.27440.27520.27380.27462nd Gross Wt., grams0.25270.27330.27640.27430.27520.27410.27433rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams0.252700.273150.276550.274350.275200.273950.27445Tare Wt., grams0.252700.251700.252350.251950.250700.251700.25295Filter Particulate Wt.,mg21.4524.2022.4024.5022.2521.50Difference, milligrams0Total Sample Particulate Wt.,mg27.5029.4532.3532.2526.1028.000.02750.029450.032350.032250.02610.028Start Here

## APPENDIX C

BOILER/PRECIPITATOR OPERATIONAL DATA

## APPENDIX D

PLANT CEMS DAHS PRINTOUTS

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

04/02/2008 7:40 20.8 9.6 04/02/2008 7:41 18.8 9.5 04/02/2008 7:42 18.8 9.5 04/02/2008 7:43 19.4 9.5 04/02/2008 7:44 19.7 9.5 04/02/2008 7:45 21.1 9.5 04/02/2008 7:46 20.8 9.4 04/02/2008 7:47 19.9 9.4 04/02/2008 7:48 19.4 9.4 04/02/2008 7:49 20.4 9.5 04/02/2008 7:50 19.9 9.6 04/02/2008 7:51 20.9 9.6 04/02/2008 7:52 19.8 9.4 04/02/2008 7:53 19.9 9.4 04/02/2008 7:54 19.6 9.4 04/02/2008 7:55 20.5 9.4 04/02/2008 7:56 20.7 9.4 04/02/2008 7:57 20.7 9.4 04/02/2008 7:58 20.6 9.4 04/02/2008 7:59 22.1 9.4 04/02/2008 8:00 22.1 9.6 04/02/2008 8:01 22.4 9.7 04/02/2008 8:02 21.3 9.6 04/02/2008 8:03 20.3 9.4 04/02/2008 8:04 19.3 9.3 04/02/2008 8:05 18.8 9.4 04/02/2008 8:06 18.8 9.6 04/02/2008 8:07 18.6 9.6 04/02/2008 8:08 18 9.6 04/02/2008 8:09 18.5 9.5 04/02/2008 8:10 18.1 9.5 04/02/2008 8:11 18.5 9.4 04/02/2008 8:12 18.4 9.4 04/02/2008 8:13 18.9 9.4 04/02/2008 8:14 18.8 9.4

Page 1 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

04/02/2008 8:15 18.8 9.3 04/02/2008 8:16 19.1 9.4 04/02/2008 8:17 04/02/2008 8:18 04/02/2008 8:19 04/02/2008 8:20 04/02/2008 8:21 04/02/2008 8:22 04/02/2008 8:23 04/02/2008 8:24 04/02/2008 8:25 04/02/2008 8:26 04/02/2008 8:27 04/02/2008 8:28 04/02/2008 8:29 04/02/2008 8:30 04/02/2008 8:31 04/02/2008 8:32 04/02/2008 8:33 04/02/2008 8:34 04/02/2008 8:35 04/02/2008 8:36 04/02/2008 8:37 04/02/2008 8:38 04/02/2008 8:39 04/02/2008 8:40 04/02/2008 8:41 04/02/2008 8:42 04/02/2008 8:43 04/02/2008 8:44 04/02/2008 8:45 04/02/2008 8:46 04/02/2008 8:47 04/02/2008 8:48 04/02/2008 8:49 31.8 4.4 04/02/2008 8:50 38.2 8.7 04/02/2008 8:51 34.9 9.2 Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress Calibration in Progress

Page 2 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

04/02/2008 8:52 30.1 9.2 04/02/2008 8:53 27.7 9.3 04/02/2008 8:54 26.6 9.3 04/02/2008 8:55 26.1 9.3 04/02/2008 8:56 25.6 9.3 04/02/2008 8:57 24.6 9.3 04/02/2008 8:58 24.4 9.4 04/02/2008 8:59 24.1 9.4 04/02/2008 9:00 24.2 9.3 04/02/2008 9:01 24 9.3 04/02/2008 9:02 23.6 9.3 04/02/2008 9:03 23.8 9.4 04/02/2008 9:04 24.2 9.5 04/02/2008 9:05 24.3 9.5 04/02/2008 9:06 24.4 9.5 04/02/2008 9:07 24 9.5 04/02/2008 9:08 24.1 9.5 04/02/2008 9:09 24.3 9.5 04/02/2008 9:10 25.8 9.4 04/02/2008 9:11 26.2 9.4 04/02/2008 9:12 26.1 9.4 04/02/2008 9:13 28.2 9.6 04/02/2008 9:14 30.2 9.8 04/02/2008 9:15 29 9.8 04/02/2008 9:16 26.2 9.7 04/02/2008 9:17 24.1 9.7 04/02/2008 9:18 24.4 9.5 04/02/2008 9:19 23.4 9.5 04/02/2008 9:20 21.8 9.4 04/02/2008 9:21 22.6 9.6 04/02/2008 9:22 22.9 9.6 04/02/2008 9:23 23.3 9.7 04/02/2008 9:24 22.9 9.7 04/02/2008 9:25 23.1 9.7 04/02/2008 9:26 23.4 9.7 04/02/2008 9:27 23.7 9.6 04/02/2008 9:28 24.2 9.5

Page 3 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

04/02/2008 9:29 23.5 9.5 04/02/2008 9:30 25 9.6 04/02/2008 9:31 24.4 9.7 04/02/2008 9:32 24.5 9.7 04/02/2008 9:33 25.3 9.7 04/02/2008 9:34 25.2 9.8 04/02/2008 9:35 25.4 9.7 04/02/2008 9:36 25.7 9.7 04/02/2008 9:37 26.6 9.6 04/02/2008 9:38 27.1 9.6 04/02/2008 9:39 25.9 9.7 04/02/2008 9:40 26.1 9.7 04/02/2008 9:41 23.7 9.9 04/02/2008 9:42 21.4 9.9 04/02/2008 9:43 22.7 9.9 04/02/2008 9:44 23.4 9.8 04/02/2008 9:45 22.9 9.7 04/02/2008 9:46 23.7 9.7 04/02/2008 9:47 24 9.6 04/02/2008 9:48 23.7 9.7 04/02/2008 9:49 23.5 9.7 04/02/2008 9:50 22.1 9.8 04/02/2008 9:51 23 9.8 04/02/2008 9:52 22.7 9.8 04/02/2008 9:53 23.1 9.8 04/02/2008 9:54 23 9.7 04/02/2008 9:55 22.9 9.6 04/02/2008 9:56 23.7 9.7 04/02/2008 9:57 25 9.7 04/02/2008 9:58 24.9 9.7 04/02/2008 9:59 24.6 9.7 04/02/2008 10:00 24.7 9.7 04/02/2008 10:01 25.8 9.8 04/02/2008 10:02 25.5 9.8 04/02/2008 10:03 25.6 9.8 04/02/2008 10:04 24.5 9.8 04/02/2008 10:05 23.5 9.7

Page 4 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 10:06 22.3 9.7 04/02/2008 10:07 22.4 9.7 04/02/2008 10:08 22.4 9.8 04/02/2008 10:09 22.2 9.7 04/02/2008 10:10 23.6 9.7 04/02/2008 10:11 24.2 9.7 04/02/2008 10:12 25 9.7 04/02/2008 10:13 25.6 9.6 04/02/2008 10:14 24.9 9.7 04/02/2008 10:15 26.4 9.8 04/02/2008 10:16 25.5 9.7 04/02/2008 10:17 24.2 9.6 04/02/2008 10:18 25.1 9.6 04/02/2008 10:19 25.9 9.6 04/02/2008 10:20 25.5 9.7 04/02/2008 10:21 26.2 9.7 04/02/2008 10:22 25.9 9.6 04/02/2008 10:23 26.1 9.6 04/02/2008 10:24 26.9 9.7 04/02/2008 10:25 28.4 9.7 04/02/2008 10:26 27.6 9.8 04/02/2008 10:27 27.1 9.8 04/02/2008 10:28 27.7 9.8 04/02/2008 10:29 24.6 9.6 04/02/2008 10:30 23.5 9.6 04/02/2008 10:31 23.2 9.6 04/02/2008 10:32 22.9 9.6 04/02/2008 10:33 23.2 9.5 04/02/2008 10:34 22.4 9.5 04/02/2008 10:35 24.4 9.7 04/02/2008 10:36 25.2 9.8 04/02/2008 10:37 26.3 9.8 04/02/2008 10:38 24.5 9.6 04/02/2008 10:39 24.6 9.7 04/02/2008 10:40 25.8 9.7 04/02/2008 10:41 26.5 9.7 04/02/2008 10:42 25.3 9.6

Page 5 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 10:43 26.7 9.6 04/02/2008 10:44 25.4 9.7 04/02/2008 10:45 25.1 9.8 04/02/2008 10:46 28.9 9.8 04/02/2008 10:47 28.7 9.6 04/02/2008 10:48 28.6 9.6 04/02/2008 10:49 29.5 9.8 04/02/2008 10:50 28 9.8 04/02/2008 10:51 26.5 9.8 04/02/2008 10:52 24.9 9.8 04/02/2008 10:53 23.1 9.7 04/02/2008 10:54 23.7 9.6 04/02/2008 10:55 24.8 9.7 04/02/2008 10:56 23.3 9.9 04/02/2008 10:57 23.1 9.9 04/02/2008 10:58 22.8 9.7 04/02/2008 10:59 22.7 9.7 04/02/2008 11:00 22.8 9.6 04/02/2008 11:01 23.6 9.7 04/02/2008 11:02 22.9 9.6 04/02/2008 11:03 23.6 9.7 04/02/2008 11:04 23.3 9.7 04/02/2008 11:05 23.4 9.6 04/02/2008 11:06 24.1 9.7 04/02/2008 11:07 24.8 9.8 04/02/2008 11:08 25.2 9.9 04/02/2008 11:09 25.2 9.7 04/02/2008 11:10 25.2 9.6 04/02/2008 11:11 25.4 9.6 04/02/2008 11:12 25.4 9.7 04/02/2008 11:13 25.4 9.7 04/02/2008 11:14 25.4 9.8 04/02/2008 11:15 25.1 9.9 04/02/2008 11:16 24.6 9.9 04/02/2008 11:17 23.4 10 04/02/2008 11:18 22.7 10 04/02/2008 11:19 21.9 9.9

Page 6 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 11:20 20.8 9.8 04/02/2008 11:21 21.1 9.7 04/02/2008 11:22 21 9.8 04/02/2008 11:23 21.2 9.9 04/02/2008 11:24 21.3 9.9 04/02/2008 11:25 21.9 9.9 04/02/2008 11:26 21.9 9.9 04/02/2008 11:27 22.2 9.9 04/02/2008 11:28 23 9.9 04/02/2008 11:29 22.7 9.9 04/02/2008 11:30 22.6 9.8 04/02/2008 11:31 23.1 9.8 04/02/2008 11:32 23.4 9.8 04/02/2008 11:33 24.2 9.8 04/02/2008 11:34 24.5 9.8 04/02/2008 11:35 24.8 9.8 04/02/2008 11:36 25.4 9.9 04/02/2008 11:37 25.2 10 04/02/2008 11:38 24.8 9.9 04/02/2008 11:39 24.2 9.9 04/02/2008 11:40 23.5 10 04/02/2008 11:41 22.5 10.1 04/02/2008 11:42 21.2 9.9 04/02/2008 11:43 20.9 9.8 04/02/2008 11:44 21.4 9.8 04/02/2008 11:45 22 9.9 04/02/2008 11:46 22.6 10 04/02/2008 11:47 21.3 10 04/02/2008 11:48 20.9 9.9 04/02/2008 11:49 22 9.8 04/02/2008 11:50 22.6 9.7 04/02/2008 11:51 23.7 9.9 04/02/2008 11:52 23.5 9.9 04/02/2008 11:53 23.5 9.8 04/02/2008 11:54 23.8 9.9 04/02/2008 11:55 24.5 10 04/02/2008 11:56 24.8 10.1

Page 7 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 11:57 25.2 10.1 04/02/2008 11:58 25.5 10 04/02/2008 11:59 25.5 10 04/02/2008 12:00 25.7 10 04/02/2008 12:01 27.6 9.9 04/02/2008 12:02 29 9.9 04/02/2008 12:03 28 10 04/02/2008 12:04 27.7 10.2 04/02/2008 12:05 26.3 10.1 04/02/2008 12:06 25.4 10.1 04/02/2008 12:07 25.5 10 04/02/2008 12:08 26 9.9 04/02/2008 12:09 26.3 9.9 04/02/2008 12:10 26.9 9.9 04/02/2008 12:11 27.2 9.8 04/02/2008 12:12 27 9.8 04/02/2008 12:13 27.4 9.8 04/02/2008 12:14 27.8 10 04/02/2008 12:15 27.9 10.1 04/02/2008 12:16 27.5 10 04/02/2008 12:17 27.8 9.9 04/02/2008 12:18 28.7 9.9 04/02/2008 12:19 30 9.9 04/02/2008 12:20 31.1 10 04/02/2008 12:21 31.1 10 04/02/2008 12:22 31.2 10.1 04/02/2008 12:23 31.2 10.1 04/02/2008 12:24 31.4 10.2 04/02/2008 12:25 29.8 10.3 04/02/2008 12:26 28.5 10.2 04/02/2008 12:27 27.1 10.1 04/02/2008 12:28 26.2 10.1 04/02/2008 12:29 27 10.1 04/02/2008 12:30 26.7 10 04/02/2008 12:31 24.9 9.9 04/02/2008 12:32 24.8 10.1 04/02/2008 12:33 25 10.2

Page 8 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 12:34 25.8 10.2 04/02/2008 12:35 25.9 10.2 04/02/2008 12:36 25.6 10.2 04/02/2008 12:37 26.1 10.2 04/02/2008 12:38 25.5 10.1 04/02/2008 12:39 25.8 10 04/02/2008 12:40 25.7 9.9 04/02/2008 12:41 26.1 10 04/02/2008 12:42 26.6 10 04/02/2008 12:43 27 10.1 04/02/2008 12:44 27.6 10.2 04/02/2008 12:45 27.5 10.3 04/02/2008 12:46 27.8 10.2 04/02/2008 12:47 26.3 10.2 04/02/2008 12:48 25.2 10.2 04/02/2008 12:49 24.4 10.2 04/02/2008 12:50 22.6 10.1 04/02/2008 12:51 22.7 10.2 04/02/2008 12:52 24 10.2 04/02/2008 12:53 23.4 10.2 04/02/2008 12:54 23.7 10.1 04/02/2008 12:55 23.8 10.1 04/02/2008 12:56 24.3 10 04/02/2008 12:57 25.2 10.2 04/02/2008 12:58 25.8 10.1 04/02/2008 12:59 24.6 9.9 04/02/2008 13:00 24.4 9.8 04/02/2008 13:01 25.6 9.8 04/02/2008 13:02 25.6 9.9 04/02/2008 13:03 26.6 9.9 04/02/2008 13:04 26.4 9.8 04/02/2008 13:05 26.6 9.9 04/02/2008 13:06 27.9 10.1 04/02/2008 13:07 28.8 10.2 04/02/2008 13:08 27.7 10.3 04/02/2008 13:09 26.4 10.2 04/02/2008 13:10 25.4 10.1

Page 9 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 13:11 24.6 10.1 04/02/2008 13:12 23.7 10 04/02/2008 13:13 23.9 10.1 04/02/2008 13:14 24.3 10.1 04/02/2008 13:15 24.8 10.1 04/02/2008 13:16 24.5 10.2 04/02/2008 13:17 24.2 10.2 04/02/2008 13:18 24.5 10.1 04/02/2008 13:19 25.1 10 04/02/2008 13:20 24.2 9.9 04/02/2008 13:21 26.8 9.9 04/02/2008 13:22 27.7 9.9 04/02/2008 13:23 27.2 10 04/02/2008 13:24 29.9 10 04/02/2008 13:25 31.2 10.1 04/02/2008 13:26 30.6 10.1 04/02/2008 13:27 32.2 10.2 04/02/2008 13:28 32.5 10.2 04/02/2008 13:29 31.1 10.1 04/02/2008 13:30 31.3 10 04/02/2008 13:31 28.3 10 04/02/2008 13:32 27.4 10 04/02/2008 13:33 28.1 10.1 04/02/2008 13:34 28.1 10.1 04/02/2008 13:35 26.5 10.2 04/02/2008 13:36 25.6 10.1 04/02/2008 13:37 24.9 9.9 04/02/2008 13:38 24.7 9.9 04/02/2008 13:39 25.8 9.9 04/02/2008 13:40 26 9.9 04/02/2008 13:41 25.2 9.9 04/02/2008 13:42 26 9.9 04/02/2008 13:43 26.4 9.9 04/02/2008 13:44 26.9 9.9 04/02/2008 13:45 27.2 10 04/02/2008 13:46 28.1 10 04/02/2008 13:47 27 9.9

Page 10 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 13:48 26.9 9.8 04/02/2008 13:49 27.5 9.9 04/02/2008 13:50 27.8 9.8 04/02/2008 13:51 29.1 10 04/02/2008 13:52 29 10 04/02/2008 13:53 26 10 04/02/2008 13:54 25.5 10.1 04/02/2008 13:55 27.6 10.2 04/02/2008 13:56 26.6 10.2 04/02/2008 13:57 25.4 10.1 04/02/2008 13:58 24.6 10.1 04/02/2008 13:59 25.1 10.2 04/02/2008 14:00 24.7 10.2 04/02/2008 14:01 24.7 10.2 04/02/2008 14:02 24.5 10.1 04/02/2008 14:03 24.4 10 04/02/2008 14:04 24.8 9.9 04/02/2008 14:05 25.7 10 04/02/2008 14:06 27 10.1 04/02/2008 14:07 29 10.1 04/02/2008 14:08 27.7 10.1 04/02/2008 14:09 26.9 10 04/02/2008 14:10 26.9 9.9 04/02/2008 14:11 28.9 10 04/02/2008 14:12 29.2 10.1 04/02/2008 14:13 28.5 10.1 04/02/2008 14:14 28.3 10.1 04/02/2008 14:15 27.8 10 04/02/2008 14:16 27.8 10 04/02/2008 14:17 27.4 10.1 04/02/2008 14:18 26.5 10.1 04/02/2008 14:19 25 10.1 04/02/2008 14:20 23.7 10 04/02/2008 14:21 24 10.1 04/02/2008 14:22 24.2 10.2 04/02/2008 14:23 23.7 10.1 04/02/2008 14:24 24.1 10.1

Page 11 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 14:25 25 10.1 04/02/2008 14:26 24.7 10 04/02/2008 14:27 24.8 10 04/02/2008 14:28 25.5 10 04/02/2008 14:29 25.5 10 04/02/2008 14:30 25.9 10 04/02/2008 14:31 25.9 9.9 04/02/2008 14:32 26.2 9.9 04/02/2008 14:33 26.3 9.9 04/02/2008 14:34 28.1 10 04/02/2008 14:35 30.1 10.1 04/02/2008 14:36 29.7 10 04/02/2008 14:37 29 10 04/02/2008 14:38 29.6 10 04/02/2008 14:39 30.3 10.1 04/02/2008 14:40 28.8 10.2 04/02/2008 14:41 27.1 10.1 04/02/2008 14:42 27.1 10 04/02/2008 14:43 25.8 10 04/02/2008 14:44 25.7 10 04/02/2008 14:45 25.7 10.1 04/02/2008 14:46 26.6 10 04/02/2008 14:47 26.1 10 04/02/2008 14:48 26.2 10 04/02/2008 14:49 26.5 10.1 04/02/2008 14:50 26.6 10.1 04/02/2008 14:51 25.5 10.1 04/02/2008 14:52 25.3 9.9 04/02/2008 14:53 23.5 9.9 04/02/2008 14:54 23 9.8 04/02/2008 14:55 24.6 9.8 04/02/2008 14:56 23.1 9.9 04/02/2008 14:57 23.9 9.9 04/02/2008 14:58 26.2 9.9 04/02/2008 14:59 25.2 10 04/02/2008 15:00 26.8 10.1 04/02/2008 15:01 28.4 10.2

Page 12 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 15:02 26.7 10.1 04/02/2008 15:03 24.8 9.9 04/02/2008 15:04 24.5 9.8 04/02/2008 15:05 22.4 9.8 04/02/2008 15:06 22 9.9 04/02/2008 15:07 21.8 9.8 04/02/2008 15:08 21.7 9.9 04/02/2008 15:09 22.8 10 04/02/2008 15:10 22.8 9.9 04/02/2008 15:11 22.3 9.9 04/02/2008 15:12 23.1 10 04/02/2008 15:13 23.5 10 04/02/2008 15:14 24.1 10 04/02/2008 15:15 24 10 04/02/2008 15:16 24.2 9.9 04/02/2008 15:17 26.9 10 04/02/2008 15:18 27.3 9.9 04/02/2008 15:19 26.1 9.8 04/02/2008 15:20 26.5 9.8 04/02/2008 15:21 25.9 10 04/02/2008 15:22 25.3 10 04/02/2008 15:23 25.2 9.9 04/02/2008 15:24 25.5 9.9 04/02/2008 15:25 25.7 9.9 04/02/2008 15:26 24.2 9.9 04/02/2008 15:27 22.9 9.8 04/02/2008 15:28 22.6 9.8 04/02/2008 15:29 22.6 10 04/02/2008 15:30 23.6 10.1 04/02/2008 15:31 24 10.1 04/02/2008 15:32 23.1 10.3 04/02/2008 15:33 24.9 10.4 04/02/2008 15:34 25.6 10.4 04/02/2008 15:35 25.3 10.3 04/02/2008 15:36 25.1 10.2 04/02/2008 15:37 25.6 10 04/02/2008 15:38 25.7 10.1

Page 13 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 15:39 25.9 10 04/02/2008 15:40 26.6 9.9 04/02/2008 15:41 25.3 9.8 04/02/2008 15:42 26.1 9.8 04/02/2008 15:43 26.8 9.9 04/02/2008 15:44 26 9.8 04/02/2008 15:45 24.8 9.7 04/02/2008 15:46 26 9.7 04/02/2008 15:47 27.6 9.7 04/02/2008 15:48 25.4 9.8 04/02/2008 15:49 24.2 9.8 04/02/2008 15:50 24 9.7 04/02/2008 15:51 23.2 9.7 04/02/2008 15:52 22.6 9.7 04/02/2008 15:53 21.8 9.7 04/02/2008 15:54 22.7 9.8 04/02/2008 15:55 23.8 9.9 04/02/2008 15:56 23 10 04/02/2008 15:57 22.8 9.8 04/02/2008 15:58 23.3 9.8 04/02/2008 15:59 21.1 9.8 04/02/2008 16:00 21.1 9.9 04/02/2008 16:01 23.2 9.8 04/02/2008 16:02 23.2 9.6 04/02/2008 16:03 23.7 9.6 04/02/2008 16:04 25.2 9.6 04/02/2008 16:05 24.1 9.7 04/02/2008 16:06 25.1 9.7 04/02/2008 16:07 26.6 9.7 04/02/2008 16:08 24.5 9.7 04/02/2008 16:09 25.9 9.8 04/02/2008 16:10 26.3 9.9 04/02/2008 16:11 25.7 9.9 04/02/2008 16:12 23.9 9.8 04/02/2008 16:13 22.7 9.7 04/02/2008 16:14 22.1 9.7 04/02/2008 16:15 21.9 9.8

Page 14 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 04/02/2008 16:16 21.7 9.7 04/02/2008 16:17 21.7 9.8 04/02/2008 16:18 22.7 9.9 04/02/2008 16:19 22.9 10 04/02/2008 16:20 23.1 9.9 04/02/2008 16:21 22.7 9.9 04/02/2008 16:22 22.9 9.8 A verages: 24.88 9.83

Page 15 of 15

## APPENDIX E

FUEL ANALYSIS

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 Ph (813) 630-7378 * Fax (813) 630-7360 * DOH #E54272

05/08/2008 Report For:

TE_BB_2_COMP_CO Location Code: Location Description: Sample Collector: Sample Collection Date: Lab Submittal Date: 

### Sample Information

Big Bend 2 Compliance 04/02/2008 04/03/2008

F. WADE Report Date: 

## Laboratory ID: AA93807

Laboratory Results

Coal Analysis - As Received Result Units Lower Limit Upper Limit Violation

% Ash, as Received 10.54
BTU/Lb BTU, as Received 11803
% Sulfur, as Received 1.62


### Coal Analysis - Dry Basis Result Units Lower Limit Upper Limit Violation

% Ash, Dry Basis 11.67
BTU/Lb. BTU, Dry Basis 13062
% Sulfur, Dry Basis 1.79


### Coal Analysis - Mi scellaneous Result Units Lower Limit Upper Limit Violation

BTU/Lb. BTU, Moisture-Ash Free 14788
Lbs. SO2/MMBTU Pounds SO2 / Million BTU 2.61
% Total Moisture 9.64


### Comments

Ray McDarby,

Manager, Laboratory Services For Peggy Penner,

Report Number: -050808- 08 AA93807 Page 1 of 1 "Coal Report"

## APPENDIX F

FIELD DATA SHEETS

## APPENDIX G

SAMPLING EQUIPMENT CALIBRATIONS

### Environmental Service s A ir Services Grou p



## SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS
CONSOLE (MB 06) INITIA L 02/01/2008 USEPA RM 5 0.998 POST TEST 04/03/2008 (ORIFICE) 0.994
NOZZLE (MN 19) INITIA L 02/01/2008 CALIPER 0.279 POST TEST 04/03/2008 CALIPER 0.280

PYROMETER (PY 10) 02/01/2008 ASTM THERMOMETER + 2 o 

### F

PITOT TUBE (PT 09) 02/01/2008 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 07) 03/03/2008 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Red Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30.14 "Hg Instrument Code Number: ^MB06 Theoretical Critical Vacuum: 14.22 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.60 15 535.666 542.550 6.884 77 81 80 82 1.15 15 509.900 518.920 9.020 77 79 78 81 1.95 15 524.000 535.666 11.666 78 81 77 82 3.70 15 542.463 558.450 15.987 80 82 74 81

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3455 23.0 72 72 72.0 55 0.4592 21.5 72 72 72.0 63 0.5877 19.7 72 72 72.0 73 0.8022 16.9 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC
Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.788 6.772 6.776 0.998 0.000 1.631 -0.146 8.926 9.001 9.006 1.008 0.010 1.774 -0.003 11.551 11.520 11.527 0.997 -0.001 1.834 0.057 15.905 15.724 15.734 0.989 -0.009 1.868 0.092 Averages: 0.998 1.777

Review/Approval:

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2.



### 4-Feb-08 Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures 02/01/2008

GDB

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

### Environmental Services Air Services Group

Manufacturer: thermo Calibration Date: Model Number:mst Barometric Pressure: 30.15 "Hg Instrument Code Number: mb06 Theoretical Critical Vacuum: 14.22 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: RED

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF

1.2 10 119.000 125.020 6.020 68 74 69 75 1.2 10 125.020 131.040 6.020 69 75 69 76 1.2 10 131.040 137.075 6.035 69 76 70 77

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4593 23.0 72 72 72.0 55 0.4593 23.0 72 72 72.0 55 0.4593 23.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC
Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.042 6.004 6.006 0.994 -0.001 1.875 0.003 6.033 6.004 6.006 0.995 0.001 1.872 0.000 6.040 6.004 6.006 0.994 0.000 1.869 -0.003 Averages: 0.994 1.872 Prior Y: 0.998 % Difference: 0.37% + 5%

Review/Approval: Date: 4-Apr-08 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

rjn 04/03/2008 

### POST - TEST CALIBRATION CHECK

Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings

BIG BEND UNIT 2-04-02-08 IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.

### Environmental Service s A ir Services Grou p

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET Calibration Date: 02/01/2008 Responsible Party: RJN

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average
I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.292 0.286 0.293 0.003 0.114 ^SN04 0.322 0.323 0.323 0.000 0.127 ^SN05 0.379 0.380 0.378 0.001 0.149 ^SN06 0.494 0.496 0.499 0.002 0.195 ^SN09 0.686 0.689 0.686 0.001 0.270 ^SN10 0.754 0.750 0.750 0.002 0.296 ^SN12 0.985 0.979 0.982 0.002 0.387 ^SN15 0.419 0.416 0.414 0.002 0.164 ^SN16 0.501 0.501 0.499 0.001 0.197 ^SN19 0.711 0.706 0.712 0.002 0.279 ^SN22 0.934 0.935 0.932 0.001 0.368 ^SN30 0.792 0.792 0.794 0.001 0.312 ^SN36 0.467 0.474 0.473 0.003 0.186 ^SN37 0.527 0.530 0.533 0.002 0.209 ^SN38 0.628 0.632 0.633 0.002 0.248 ^SN46 0.479 0.479 0.478 0.000 0.188 ^SN47 0.514 0.511 0.508 0.002 0.201 ^SN48 0.636 0.638 0.634 0.002 0.250 ^SN50 0.788 0.784 0.784 0.002 0.309 ^SN58 0.610 0.616 0.618 0.003 0.242 ^SN68 0.622 0.625 0.625 0.001 0.246 ^SN69 0.950 0.950 0.951 0.000 0.374 ^SN70 1.561 1.558 1.553 0.003 0.613 ^SN71 1.554 1.557 1.555 0.001 0.612 ^SN72 0.953 0.954 0.950 0.002 0.375 ^SN73 1.280 1.280 1.280 0.000 0.504 ^SN74 1.230 1.231 1.230 0.000 0.484 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by:

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 04/03/2008 

### Calibration Personnel: rjn 

### Test Designation: big bend unit 2 04-02-08



### Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
sn19 0.710 0.708 0.712 0.002 0.280

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID sn19 was 0.279

Difference (Pre-test/Post-test) is: -0.001

4-Apr-08 QA/QC Review by:

### Environmental Services A ir Services Group Pyrometer Calibration Red Team Pyrometer Under Tes t Pyrometer Number: ^PY10 Labworks Sample # 0 Calibration Date: 02/01/200 8

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 04/17/200 7 Calibration Personnel (Typed and Si g nature): SEG-RJN

Calibration Data

Calibration Reference Pyromete r Point Temperature Indication Difference

1 

### 400 401 -1 2 

### 212 214 -2 3 

### 32 34 -2

Reference temperatures must encompass the expected range of measurement. These three point s should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit

. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: 

### 4-Feb-08Environmental Services Air Services Group

_ _

s PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT09 Calibration Date 02/01/2008 Operating Quarter/Year: 1/08 Shared Resource Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 1.9 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 1.1 degrees Pass α < 10 degrees β 1 1.6 degrees Pass ( α 1 measured across top impact openings) β 2 1.8 degrees Pass ( α 2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α
, Ζ
, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.1 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.28 cm W < 0.08 cm (Asin ο )
Ζ 0.004 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.3 degrees ψ angle between tips W 0.012 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by: RJN - SEG

Q uality Assurance Review / Approval:

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR07 Calibration Date: 03/03/2008 Calibration Personnel: SEG Labworks #: Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 9:00 29.98 29.99 -0.01 10:00 29.99 30.00 -0.01 11:00 30.01 30.01 0

Avera g e Difference: -0.00667

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: Date: 5-Mar-08

## APPENDIX H

CHAIN OF CUSTODY

## APPENDIX I

TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL SERVICES AIR SERVICES GROUP Test Team Jorge Varino Environmental Technician, Test Team Lead Gary Barber Associate Technician
Scott Given Associate Technician Ryan Newell Associate Technician
Process Data
Karen Zwolak Senior Environmental Consultant, Big Bend Station Raymond A. McDarby Senior Environmental Technician Fuel Analysis
Patrice Jackson Envi ronmental Technician Sample Analysis
Sam Soth Environmental Technician Project Quality Objectives & Reporting Raymond A. McDarby Senior Environmental Technician
Test Coordination
Karen Zwolak Senior Environmental Consultant, Big Bend Station David A. Smith Coordinator, Air Services Group