DEPARTMENTOF PUBLIC BEALTB Donald F. Schwarz,MD, MPH Depllfl' MororjiJrHeaith & Oppo/'llilli!," Heallh Cnmmissioner 

# CITY OF PHILADELPHIA Nan Feyler,JD,MPH Chie/o/Sh!fl Air Management Services Thomas Huynh Direc'lor SourceRegistration 321 University Avenue, 2nd Floor Philadelphia, PA 19104 Telephone (215) 685-7572 Fax (215) 685-7593
February 19,2014 Mr. Charles Barksdale PhiladelphiaEnergy SolutionsRefiningandMarketingLLC (PES) 3144 Passyunk Avenue Philadelphia, P A 19145 PUD: 01501 

### RE: Plan Approval Application No. 12195 and RAeT 

### Plan Approval Amendment for the Modification ofSeven (7) Heaters

Dear Mr. Barksdale, The comment period has ended for Plan Approval Application No. 12195 and the RACT Plan Approval Amendment for the modificationofseven (7)heaters. Enclosed are the final issued plan approval, amendedRACTplan approval. andcommentresponse document. Ifyouhave any questions,please contactme at (215) 685-9426 oredward.wienerrmphila.gov

. Sincerely,

# c;:u~**t~** Edward Wiener Environmental EngineerCITY OF PHILADELPHIA DEPARTMENT OF PUBLIC HEALTH AIR MANAGEMENT SERVICES Plan Approval Approval No: 12195 Source: Philadelphia Energy Solutions Refining and Marketing LLC (PES) Plant ID: 01501 Owner: Philadelphia Energy Solutions Refining and Marketing LLC (PES) Location: 3144 PassyunkAvenue Address: 3144 Passyunk Avenue Philadelphia, PA 19145 Philadelphia, PA 19145 Attention: Mr. Charles Barksdale Manager, Environmental Department (215) 339-2074
In accordancewith provisions ofTitle 3 ofthe Philadelphia Code, the Air Management Code of February 17. 1995. as amended, and after due consideration ofan application received underthe rules and regulations of Philadelphia Air Pollution Control Board and the Pennsylvania Department of Environmental Protection (PADEP), the City of Philadelphia, Department of Public Health, Air Management Services (AMS) on February 19, 2014, approved plans forthe modification and temporary operation ofthe air contamination device(s) described below:
• Replace the MMBTU per hourfiring rate limits with MMBTU per rolling 365-day period limits forthe following seven (7) process heaters: o Unit 231 B101 Heater (rated capacity 104.5 MMBTUlhr) o Unit 865 11H1 Heater (rated capacity 87.3 MMBTU/hr) o Unit 865 11H2 Heater (rated capacity 64.2 MMBTU/hr) o Unit 210 H101 Heater (rated capacity 192.0 MMBTUlhr) o Unit 210 H201NB Heater (rated capacity 254.0 MMBTU/hr) o Unit 86612H1 Heater (rated capacity 61.2 MMBTU/hr) o Unit 868 8H101 Heater (rated capacity 60.0 MMBTU/hr)
• Install Ultra Low-NOx Burners (ULNBs) on the following process heaters: o Unit 231 B101 Heater o Unit 86511H1 Heater
This plan approval expires August 19, 2015. This plan approval is subjectto conditions prescribed in the attachment.

( , 

# I EdwardWiener Chief, Source Registration. 

# IPLANAPPROVALCONDITIONS PLAN APPROVALNO. 12195 COMPANY: PhiladelphiaEnergySolutions
1. The heaters and crude units listed on the cover shall be operated in accordancewith the specifications in the application (as approved herein). 2. Emissions from the heaters shall not exceed the following limits in tons per rolling 12-month period, calculated monthly: [Application] NOx S02 TPM/PM10/PM2.5 CO VOC GHG 231 B101 Heater 12.8 0.8 3.1 34.4 2.3 49,243 865 11H 1 Heater 10.5 0.7 2.6 28.5 1.9 40,777 865 11H2 Heater 28.3 0.5 1.8 20.4 1.3 29,168 210 H101 Heater 73.1 2.7 6.1 66.9 4.4 95,847 2 10 H201 Heater 32.6 3.2 8.0 88.5 5.8 126,707 866 12H1 Heater 25.8 0.5 1.7 18.6 1.2 26,601 8688H101 Heater 27.1 0.6 1.7 18.9 1.2 27,054 Total Particulate Matter (TPM), PM10, and PM2.5 emissions include both filterable (Method 

### 51 201A) and condensable particulate (Method 202) forthis condition. Greenhouse Gas (GHG) emissions are expressed in terms ofCarbon Dioxide Equivalent (C02e), based upon a global warming potential ofCH4

# = 21 and N20

# = 310. 3. Nitrogen Oxides (NOx) emissions shall notexceed the following: [Application]
a. 0.03Ibs/MMBTU for Unit 231 B101 Heater. b. 0.03 Ibs/MMBTU for Unit 865 11 H 1 Heater. c. 0.113 Ibs/MMBTU for Unit 865 11H2 Heater. d. 0.089Ibs/MMBTU for Unit210 H101 Heater. [Case-by-case RACT Plan Approval dated August 1, 2000] e. 0.030 Ibs/MMBTU for Unit 210 H201A1B Heater. [AMS Plan Approval No. 10180, dated 2/3/11] f. 0.113Ibs/MMBTU for Unit 86612H1 Heater. g. 0.113 Ibs/MMBTU for Unit 868 8H101 Heater. h. Compliance determination shall be based on a 365-day rolling average and NOx Continuous Emission Monitoring System (CEMS) data for Unit210 H201A1B Heater. Compliance determination shall be based on three 60-minute test runs during an AMSapproved stacktestfor the other heaters. 4. Particulate Matter (PM) emissions shall not exceed thefollowing:
a. 0.20 Ibs/MMBTU for Unit 231 B101 Heater. [AMR II, Section V.1
- assures compliance with 25 Pa. Code §123.11] b. 0.10 Ibs/MMBTU for Unit 865 11H1 Heater. [AMR II. Section V.2
- assures compliance with 25 Pa. Code §123.11] c. 0.10 Ibs/MMBTU for Unit 865 11H2 Heater. [AMR II, Section V.2
- assures compliance 2 2119/14PLAN APPROVALCO.NDITIONS PLAN APPROVALNO. 12195 COMPANY: PhiladelphiaEnergy Solutions with 25 Pa. Code §123.11

### J d. 0.19 Ibs/MMBTU for Unit 210 H101 Heater. [25 Pa. Code §123.11
- assures compliance with AMR II, Section V.1J e. 0.10 Ibs/MMBTU for Unit210 H201A1B Heater. [AMR II, Section V.2
- assures compliance with 25 Pa. Code §123.11] f. 0.10 Ibs/MMBTU for Unit 866 12H1 Heater. [AMR II, Section V.2
- assures compliance with 25 Pa. Code §123.11] g. 0.10 Ibs/MMBTU for Unit 868 8H101 Heater. [AMR II. Section V.2
- assures compliance with 25 Pa. Code §123.11] PM emissions include only filterable particulate (EPA Method 5) forthis condition. 5. Carbon Monoxide (CO) emissions from each heatershall notexceed thefollowing on an hourly basis. Application
- Ensures compliance with AMR VIII, Section 11.6 for each heater and AMS Installation Permit. 03054 dated July 29,2003for Unit 868 8H101 Heater]
a. 8.6 Ibs/hourfor Unit231 B101 Heater. b. 7.2 Ibs/hourfor Unit 865 11H1 Heater. c. 5.3 Ibs/hourfor Unit865 11H2 Heater. d. 15.7lbs/hourfor Unit 210 H101 Heater. e. 20.8 Ibs/hourfor Unit 210 H201A1B. f. 5.0 Ibs/hourfor Unit 866 12H1 Heater. g. 4.9 Ibs/hourfor Unit 868 8H101 Heater. h. Compliance determination shall be based on three 60-minute test runs during an AMSapproved stack test. 6. Sulfur Dioxide (S02) emissions from each heater shall not exceed 500 ppmvd. [25 Pa. Code §123.21(b)] 7. Each heatershall only burn refinery fuel gas. a. Each heatershall not burn any fuel gas that contains hydrogen sulfide (H2S) in excess of230 

### mg/dscm (0.10 gr/dscf) [40 CFR 60.104(a)(1), Consent Decree Order 05-CV2866] 8. Each heatershall be limited tothefollowing rolling 365-day heat input limits: [Application]
a. Unit 231 B101 Heatershall not exceed 856,000 MMBTU on a rolling 365-day basis. b. Unit 865 11H1 Heatershall not exceed 699,000 MMBTU on a rolling 365-day basis. c. Unit 865 11 H2 Heatershall not exceed 500,000 MMBTU on a rolling 365-day basis. d. Unit 210 H101 Heatershall not exceed 1,643,000 MMBTU on a rolling 365-day basis. e. Unit 210 H201A1B Heatershall notexceed 2,172,000 MMBTU on a rolling 365-day basis. 3 2/19/14PLAN APPROVALCONDITIONS PLANAPPROVALNO. 12195 COMPANY: PhiladelphiaEnergySolutions f. Unit 866 12H1 Heatershall not exceed 456,000 MMBTU on a rolling 365-day basis. g. Unit 868 8H101 Heatershall not exceed 480,000 MMBTU on a rolling 365-day basis. 9. The Permittee shall Install Ultra Low-NOx Burners (ULNBs) on the Unit 231 B101 Heaterand the Unit 865 11H1 Heaterwithin 18 months ofthe issuance ofthis plan approval. Each heater mustcomplywith its existing MMBTU/hrfiring rate limit until it has ULNBs installed and has demonstrated compliance with the 0.03 Ibs/MMBTU NOx emission limitthrough an AMS-approved stacktest. The NOx emission limits in Conditions 2 and 3forthese heaters are not applicable until the ULNBs have been installed. [Application] 10. The Permittee shall operate the facility consistent and within the projected future actual emissions basis contained in the plan approval application. [Application] 11.The Permittee shall perform an annual adjustment ortuneup on each heater. This adjustment shall include, at a minimum, the following: [Case-by-case RACT, 25 Pa. Code §§129.91-95, Section 2E; 25 Pa. Code §129.93(b)(2) and (5)]
a. Inspection, adjustment, cleaning or replacement offuel-burning equipment, including the burners and moving parts necessary for proper operation as specified by the manufacturer. b. Inspection ofthe flame pattern or characteristics and adjustments necessaryto minimize total emissions of NOx, and to the extent practicable minimize emissions ofCO. c. Inspection ofthe air-to-fuel ratio control system and adjustments necessaryto ensure proper calibration and operation as specified by the manufacturer. d. For gas fired units requiring an annual adjustment ortuneup on the combustion process, the Permittee shall make the annual adjustment in accordance with the EPA document "Combustion Efficiency Optimization Manual for Operators ofOil and Gas-fired BOilers," September 1983 (EPA-340/1-83-023) orequivalent procedures approved in writing by the AMS. 12. Each heater shall comply with 40 CFR 63 Subpart 

### 00000 by no laterthan January 31, 2016. [40 CFR 63.7495(b)] 13.Within 180 days ofthe installation of ULNBs for the Unit 231 B101 Heaterand the Unit 865 11 H1 Heaterand within 180 days ofthe issuance ofthis plan approval for the other heaters, the Permittee shall conduct thefollowing performance tests:
a. NOxfor each heater besidesthe Unit 210 H201A1B Heater, to determine compliance with NOx emission limits in Condition 2 ofthis plan approval and to usefor determining compliance with the rolling 12-month NOx emission limit in Condition 3.

4 2'19114PLAN APPROVALCONDITIONS PLANAPPROVALNO. 12195 COMPANY: PhiladelphiaEnergy Solutions b. CO for each heaterto determine compliance with the CO emission limits in Condition 5 and to use for demonstrating compliance with the rolling 12-month CO emission limit in Condition 3. c. The NOx and CO tests must be conducted simultaneously. d. Testing shall be conducted in accordancewith 25 Pa. Code Chapter 139. The Permittee shall submit a test protocol to AMS for approval at least 30 days priorto the first test and shall submit a test report with the results no laterthan 60 days after completion ofthe last test. Ifat anytime AMS has cause to believe that air contaminant emissions from the heaters for any pollutant may be in excess ofthe limitations specified in this plan approval, or established pursuantto, any applicable rule or regulation contained in 25 Pa. Code Article III, the Permittee shall be required to conductwhatevertest are deemed necessary byAMS to determine the actual emission rate(s). 14. The Unit210 Heater 201A1B shall be equipped with continuous monitors and recorders for NOx and 02. The continuous monitors and recorders shall meetthe requirements of25 Pa. Code Chapter 139. [Consent Decree Order05-CV-2866, 25 Pa. Code §123.51] 15.Compliance with the NOx limits in Condition 3 shall be based on a rolling 365-day average and NOx CEMS data for heaters with certified NOx CEMS and AMS-approved stacktest data for the other heaters. 16.Compliance with the rolling 12-month limits in Condition 2 shall be monitored and recorded on a monthly basis for each heaterand shall be based on heat input and the following:
a. NOx CEMS data for heaters with certified NOx CEMS and the most recent AMSapproved stack test data forthe other heaters. An AMS-approved method may be used forthe period priorto the completion ofthe stack tests. b. CO limits shall be based on the most recent AMS-approved stacktest datafor each heater. An AMS-approved method may be used for the period priorto the completion of the stack tests. c. For the other pollutants, AMS-approved stack test data if a stacktest is ever required. Otherwise, AP-42 or other or otherAMS-approved emission factors shall be used. 17.Compliance with the NOx Ibs/MMBTU emission limits forthe heaters listed in Condition 3 shall be monitored by quarterly stack sampling with a portable NOx analyzerfor any heaterwithout a certified NOx CEMS. After one year ofsampling, the Permittee may petition AMS for semiannual monitoring. AMS may, at anytime, require three one-hour stacktests. 18.The Permittee shall utilize an instrumentfor continuously monitoring and recording the concentration (dry basis) of H2 S in fuel gases before being burned in any ofthe heaters that meets the requirements of25 Pa. Code Chapter 139. [40 CFR 60.105(a)(4)]

a. The span value for this instrument is 425 mg/dscm H2S.

5 2/191\4PLAN APPROVAL CONDITIONS PLANAPPROVALNO. 12195 COMPANY: Philadelphia Energy Solutions b. Fuel gas combustion devices having a common source offuel gas may be monitored at only one location, ifmonitoring at this location accurately represents the concentration of H2 S in the fuel gas being burned. c. The performance evaluations forthe H2S monitorshall use Performance Specification 7. Method 11 shall be used for conducting the relative accuracy evaluations. d. H2S shall be monitored atthe locations listed in theirTitle V operating permit. 19. The Permittee shall operate a parametric emissions monitoring system (PEMS) on the 868 8H 101 heater (CU-129) for Carbon Monoxide. The chosen parameters and software CEM shall accurately predictthe emissions. Accuracy ofthe system shall be demonstrated during a stacktest. The parameters and predicted emissions shall be monitored and recorded continuouslyto ensure compliance with the Carbon Monoxide emission limitation of400 ppmdv at 3% oxygen. [AMS Installation Permit. 03054 dated July 29, 2003] 20.The Permittee shall monitor and record the refinery fuel gas heating value and consumption daily, when each heater is in operation. 21.The Permittee shall monitor and record the MMBTU heat inputfor each heater hourly and on a rolling 365-day basis, calculated daily, toverify compliance with Condition 8.
a. Fuel gas BTU content shall be continuously monitored and recorded using the continuous heat input monitor at the 862 Unit ortested and recorded daily. The 862 Unit continuous heat input monitor shall meetthe requirements of25 Pa. Code Chapter 139. 22.The Permittee shall monitor and record compliance with the rolling 12-month limits in Condition 2 ona monthly basis.
a. Compliance with NOx limits for heaters with a certified NOx CEMS shall be based on CEM data. Missing or invalid data shall be handled using the missing data substitution procedures of40 CFR Part 75. b. Compliance with NOx limitsforthe other heaters and CO limitsfor all heaters shall be based on the most recent AMS-approved stack test and heat input or other AMSapproved method for periods prior to the AMS-approved stacktest. c. Compliance with other limits shall be based on AP-42 or otherAMS-approved emission factors and heat input. 23.The Permittee shall monitor and record the operating information and estimated emissionsfor all target heaters and ancillary units daily and on a rolling 12-month basis, calculated monthly, to demonstrate compliance with Condition 10. Calculations shall be based on AMS-approved stacktest or CEM data when available. Otherwise, calculations shall use the methods in the plan approval application unless approved by AMS. Records shall be kept in an AMSapproved format that includes the following for each unit:
a. The projected future actual emissions listed in the application. b. The emissions during the previous rolling 12-month period, calculated monthly. c. The calculation method. 6 2/19114PLANAPPROVALCONDITIONS PLANAPPROVALNO. 12195 COMPANY: PhiladelphiaEnergySolutions
24.The Permittee shall keep records ofall annual adjustments and tuneups required in Condition 11. 25.The Permittee shall submit quarterly reports to AMS forthe continuous monitors required in Conditions 14. 18, and 21.a in accordancewith 25 Pa. Code Chapter 139 and the Pennsylvania Continuous Source Monitoring Manual. 26. The Permittee shall report excess emission from the process heaters defined asfollows: [40 CFR 60.105(e)] a. All rolling 3-hour periods during which the average concentration of H2S as measured bythe H2 S continuous monitoring system 230 mg/dscm (0.10 gr/dscf), 27.The Permittee shall submit quarterly reports on the compliance with Condition 10 in an AMSapproved format.

7 2/19/14