## REACTIVITY ESTIMATES FOR SELECTED CONSUMER PRODUCT COMPOUNDS

Final Report to the

California Air Resources Board Contract No. 06-408

By

William P. L. Carter

February 19, 2008

Center for Environmental Research and Technology College of Engineering University of California Riverside, California 92521ii 

### ABSTRACT

An experimental and modeling study was c onducted to assess the ground-level atmospheric ozone impacts of several types of consumer pr oduct compounds Environmenta l chamber experiments were carried out for the representative amines 2- amino-2-methyl-1-propanol (AMP), ethanolamine, isopropyl amine and t -butyl amine and also for d -limonene. AMP and t -butyl amine were found to inhibit ozone formation, but the others e nhanced ozone, and most were found to significantly enhance formation of secondary particle matter (PM). Methods to esti mate mechanisms for amines that were qualitatively consistent with the chamber data we re developed. However, the amine chamber data were not useful for quantitative valuation because the amount of amine available for gas-phase reaction could not be measured, and appeared to be signi ficantly less than the amount injected . Estimates of atmospheric ozone impacts for the amines are also ve ry uncertain because the amount of amines removed by reaction with HNO 3 in the atmosphere cannot be predic ted. The chamber data obtained for d -limonene were well simulated by the existing d -limonene mechanism.

Representations of the atmospheric reactions of for 15 amines and 30 other types of consumer product VOCs were added to the SAPRC-07 mechan ism and its MIR and other reactivity scale tabulations, which are included with this report.iii 

### ACKNOWLEDGEMENTS AND DISCLAIMERS

This work was funded by the California Air R esources Board (CARB) through contract number 06-408. The compounds studied for this project were dete rmined in discussions with Dr. Dongmin Luo, the CARB project officer, and other members of the CARB Research Division and Consumer Products Regulation staff, and th eir helpful input is gr atefully acknowledged.

The environmental chamber experiments were carried out at the College of Engineering Center for Environmental Research and Technology (CE-CERT) primarily by Bethany Warren, with assistance from Kurt Bumiller, Lindsay D. Yee, Dylan Switzer, and Nicolette A. Ramirez. Mr. Dennis Fitz provided assistance in administration of this project. Helpful discussions with Dr. Roger Atkinson and Dr. David Cocker are also acknowledged.

Although this project was funded by the CARB, the contents of this report reflect only the opinions and conclusions of the author. Menti on of trade names and commercial products does not constitute endorsement or recommendation for use.iv 

### TABLE OF CONTENTS

EXECUTIVE SUMMARY .............................................................................................................. ............ 1

INTRODUCTION ................................................................................................................... ..................... 6 Background ..................................................................................................................... ....................... 6 Objectives..................................................................................................................... .......................... 7 Overall Approach ............................................................................................................... .................... 7

EXPERIMENTAL METHODS........................................................................................................... ....... 10 Chamber Description............................................................................................................ ................ 10 Analytical Instrumentation ..................................................................................................... .............. 11 Sampling Methods............................................................................................................... ................. 14 Characterization Methods....................................................................................................... .............. 14 Experimental Procedures........................................................................................................ .............. 15 Materials...................................................................................................................... ......................... 16

MODELING METHODS............................................................................................................... ............ 17 Base Mechanism................................................................................................................. .................. 17 Representation of Chamber Conditions........................................................................................... ..... 17 Mechanisms for Amines.......................................................................................................... ............. 18 Reaction with OH radicals ...................................................................................................... ....... 18 Reaction with NO 3 Radicals .......................................................................................................... 25 Reactions with Ozone ........................................................................................................... ......... 25 Reactions with HNO 3 ..................................................................................................................... 27 Mechanism for d -Limonene ................................................................................................................. 28 Mechanisms for Other VOCs. ..................................................................................................... ......... 28 Atmospheric Reactivity Simulations............................................................................................. ....... 28

RESULTS AND DISCUSSION ......................................................................................................... ........ 33 Summary of Experiments and Characterization Results ...................................................................... 33 Blacklight Characterization .................................................................................................... ....... 33 Chamber Effects Characterization ............................................................................................... .. 34 Background PM Characterization................................................................................................. . 35 Gas-Phase Mechanism Evaluation Results ......................................................................................... . 36 Amines ......................................................................................................................... .................. 38 d -Limonene...................................................................................................................... .............. 43 PM Impact Results .............................................................................................................. ................. 44 Atmospheric Reactivity Calculations ............................................................................................ ....... 47

DISCUSSION AND CONCLUSIONS ..................................................................................................... . 54

REFERENCES ..................................................................................................................... ...................... 56

APPENDIX A. MECHANISM LISTING .................................................................................................. 60

APPENDIX B. CHAMBER EXPERIMENT LISTING............................................................................. 68

APPENDIX C. UPDATED VOC AND ATMO SPHERIC REACTIVITY LISTING............................... 72v 

### LIST OF TABLES

Table E-1. Compounds in consumer products inventor ies for which ozone impact estimates were added for this project, and r ecommended MIR values for regulatory applications. .................................................................................................................. ........... 4

Table 1. List of analytical and characterization in strumentation for the UCR EPA chamber............... 12

Table 2. Experimental and estimated rate constants for the reactions of amines included in mechanisms were derived for this project.............................................................................. 19

Table 3. Group additivity parameters used for esti mating rate constants for abstraction reactions by OH and NO 3 radicals and by Cl atoms. ............................................................. 21

Table 4. Assignments made for alkoxy radical intermed iates predicted to be formed in the photooxidation mechanisms of the amines. ........................................................................... 24

Table 5. List of compounds whose reactivities have been added to the SAPRC-07 reactivity tabulation or whose reactivities have been requested by the CARB...................................... 29

Table 6. Summary of initial concentrations and select ed gas-phase results of the incremental reactivity experiments. ........................................................................................................ ... 37

Table 7. Summary of conditions and selected results of the d -limonene NO x experiments.................. 45

Table 8. Selected results of PM number a nd volume measurements made during the incremental reactivity experiments carried out for this project.............................................. 48

Table 9. Summary of average 5-hour PM volume incr emental reactivities of VOCs studied in incremental reactivity experiments in the UCR EPA chamber.............................................. 50

Table 10. Calculated atmospheric reactivity values for amines and other compounds added to the atmospheric reactivity tabulations.................................................................................... 51

Table 11. Change in MIR values assigned to amines as a result of this work......................................... 53

Table A-1. Reactions and rate constants used for amines, d -limonene, and the new compounds added to the mechanism for this project. ............................................................................... 60

Table A-2. New lumped molecule representations used for atmospheric reactivity estimates of compounds added to the reactivity tabulations for this project.............................................. 67

Table B-1. Summary chamber experiments relevant to this project. ....................................................... 68

Table C-1. Listing of VOCs for which atmospheric ozone impact estimates are available, their representation in the model, and their cal culated atmospheric reactivity values in various reactivity scales. This tabulation is current as of December 20, 2007. ..................... 72vi 

### LIST OF FIGURES

Figure 1. Schematic of the UCR EPA environmental chamber reactors and enclosure......................... 11 Figure 2. Plots of logs of the rate constants for the reactions of the methylamines and DMAE with O 3 against the logs of the rate constants for reaction of OH radicals at the group next to the amino group and also agai nst the total OH rate constant. .................................... 26 Figure 3. Plots of light intensity data used to assign NO 2 photolysis rates for the blacklight light source................................................................................................................... .......... 34 Figure 4. Plots of best fit HONO offgasing parameters against UCR EPA run number. ....................... 35 Figure 5. Plots of 5-hour PM volume measurements in pure air experiments the EPA chamber against EPA run number. ....................................................................................................... 3 6 Figure 6. Plots of selected experimental and calculated incremental reactivity results for AMP........... 39 Figure 7. Plots of selected experimental and calculated incremental reactivity results for aminoethanol, isopropyl amine, and t-butyl amine. ............................................................... 40 Figure 8. Plots of experimental and selected calculat ed data for formaldehyde when measured in AMP experiments. ............................................................................................................ . 41 Figure 9. Plots of experimental and selected calc ulated data for formaldehyde in the ethanolamine experiment with u seable formaldehyde data. .................................................. 41 Figure 10. Plots of initial amine concentrations that gave best fits to results of model simulations to concentrations calculated fro m the amount of liquid amine injected. ............ 42 Figure 11. Plots of selected experimental and calculated incremental reactivity results for d -limonene. ..................................................................................................................... ....... 44 Figure 12. Plots of selected experimental and calcula ted data for the d-limonene experiments carried out for this program (EPA r uns) and previously (ETC runs)..................................... 46 Figure 13. Plot of experimental and calcul ated formaldehyde data for the d -limonene - NO x experiments where formaldehyde data are available. ............................................................ 47 Figure 14. Plots of PM volume data from all of th e incremental reactivity experiments carried out for this project. .......................................................................................................... ....... 49 Figure 15. Plots of incremental reactivities of amines for the various types of atmospheric reactivity scenarios calculated assuming rapid and irreversible loss by reaction with HNO 3 against incremental reactivities calculated assuming no reaction with HNO 3 . ........... 521 

### EXECUTIVE SUMMARY

Background

Emissions from consumer products are a non-negl igible component of the total emissions of volatile organic compounds (VOCs) into the atmos phere. VOCs emitted into the atmosphere react in sunlight in the presence of oxides of nitrogen (NO x ) emitted from other sources to contribute to the formation of ground-level ozone (O 3 ), an important air pollution problem in California. Because controls from other VOC sources may not be sufficient to ac hieve air-quality standards for ozone, the California Air Resources Board (CARB) has been implemen ting additional controls for VOC emissions from consumer products. In order to achieve the most co st-effective results, the CA RB has proposed to utilize controls that take into account differences in ozon e impacts, or "reactivity", of the many types of consumer product VOCs that are in use.

Reactivity-based VOC controls have already been implemented in regulations for mobile source (CARB, 1993) and aerosol coatings (CARB, 2000) emissi ons in California. These are based on use of the Maximum Incremental Reactivity (MIR) scale, which is designed to reflect differences in impacts of VOCs on O 3 formation in environments where O 3 is most sensitive to VOC emissions. However, consumer product emissions include many VOCs fo r which reactivity values are unknown or highly uncertain, for which the CARB has had to use "uppe r limit" estimates of ozone impacts of these compounds, based on worst-case considerations of their unknown atmospheric chemistry. This has lead to relatively small amounts of some compounds dominating ozone impact estimates of some product categories. This is problematical because the actual ozone impacts of these product categories may be significantly less, and regulations based on upper limit reactivity estimates may lead inappropriate control strategies.

Objectives

The overall objective of this project is to reduce uncertainties of ozone impact quantifications of selected consumer products compounds of interest to the CARB. The project focused primarily on amines, since use of upper limit reactivity esti mates for these compounds is problematic for some categories. The amines 2-amino-2-methyl-1-propa nol (AMP) and ethanolamine were chosen for experimental study because of their importance in the consumer product inventories, but atmospheric reaction mechanisms and MIR values were also derive d for other amines based in part on the results obtained for those representative compounds. Amines we re not the only types of compounds in consumer product inventories where reactivity values are needed, so an additional objective of this project was to estimate reactivity values for other compounds for which such values were not previously available. Experiments were also needed to verify exis ting atmospheric reaction mechanisms and reactivity estimates for d -limonene, an important consumer product VOC for which mechanism evaluation data were inadequate.2 Methods and Results

Environmental Chamber Experiments

The major effort in this project was to conduc t environmental chamber experiments to test estimated mechanisms for the repr esentative amines AMP and ethanolamine, and to test the existing mechanism for d -limonene. Experiments using t -butyl isopropyl amine were also carried out to further test the general amine mechanisms developed for this project. The chamber experiments were carried out in the UCR EPA environmental chamber that was de veloped for mechanism evaluation at lower and more atmospherically representative pollutant levels than previously possible, and that was utilized in recent studies of VOCs used in architectural coatings and pesticides. The type of experiments carried out were “incremental reactivity” experiments, which involved de termining the effect of adding the solvent to standard reactive organic gas (ROG) surrogate - NO x experiments designed to simulate the chemical conditions of polluted urban atmospheres. Experiments at two different ROG and NO x levels were employed to represent different conditions of NO x availability, to provide a more comprehensive test of the mechanisms that affect r eactivity under differing chemical conditions. The total NO x levels employed were in the 25-30 ppb range, which is designed to be representative of urban areas in California and which are lower than employed in pr evious reactivity chamber studies.

The chamber experiments were useful for quantitative mechanism evaluation for d -limonene and for qualitative evaluation of the mechanisms fo r the amines. The results indicated that d -limonene, ethanolamine and isopropyl amine had relatively high and positive im pacts on ozone formation, but also indicated (somewhat unexpectedly) that AMP and t -butyl amine were ozone inhibitors. Unfortunately, the data obtained for the amines were not useful for quantitative mechanism evaluation because of uncertainties in the amounts of injected amines that were available for reaction in the gas phase. The amount of amine in the gas-phase could not be measure d because of lack of suitable analytical methods for these compounds, and the chamber results could only be fit by assuming that the amount of amine reacting in the gas phase was only 5-60% of the injected amine, with the ratio varying significantly from run to run. On the other hand, the results of the limonene experiments were useful for obtaining high quality data for mechanism evaluation for this compound.

Chemical Mechanism Development and Evaluation

The SAPRC-07 mechanism (Carter, 2007a), whic h was recently developed under CARB funding and utilized to derive an updated MIR scale for use in California reactivity-based regulations was used as the starting point. New methods were developed to estimate mechanisms for am ines, based on available laboratory information and also the results of th e experiments for this project. The new estimation methods predicted that amines that lack reactive hy drogen atoms vicinal to the amino groups would be ozone inhibitors, as indicated by the results of the AM P and t-butyl amine experiments carried out for this project. On the other hand, amines such as ethanolamin e are predicted and confirmed to have positive and relatively high ozone impacts, though not as high as the upper limit estimates that would otherwise be used in CARB regulations. Estimated mechanisms were developed for 11 other amines besides the 4 that were studied, using an approach that was consistent with the chamber data that were obtained. Estimated mechanisms, or methods for estimating atmospheric ozone impacts, were developed for 30 other types of VOCs found in consumer products emission inventories. The existing SAPRC-07 mechanism for d

limonene was found to give good simulations of the results of the experiments for this project and was not modified.3 An additional consideration in the mechanisms for amines is the fact that they are basic compounds that can react with atmospheric nitric acid (HNO 3 ) to form amine nitrate salts, which partition into the aerosol phase. The chamber experiments are not sensitive to this reac tion because the injected amine was in large excess over the HNO 3 formed in the experiments, but this could be important under atmospheric conditions. However, modeling this under atmospheric conditions is difficult because it requires knowledge of unknown equilibr ium constants and also requir es better knowledge of sources and sinks of HNO 3, ammonia, and other amines in the atmos phere, which are unknown and probably highly variable. Model simulations were carried out based on using two extreme assumptions in this regard – one assuming that the amine + HNO 3 reaction had a negligible effect on removing amines from ozone formation reactions, as would occur if the salt equilibri um favored dissociation in the atmosphere, or if there were other significant sinks for HNO 3 in the atmosphere, such as reaction with ammonia or other amines; and the other assuming that the amine + HNO 3 reaction was rapid and irreversible.

Atmospheric Reactivity Calculations

Compounds in consumer products inventories for which ozone impact esti mates were added for this project, and their recommended MIR values for regul atory applications, are listed in Table E-1. The values in the "Previous" column were the values given for a few of the amines in previous MIR tabulations provided to the CARB for regulatory a pplications using the SAPRC-99 (Carter, 2003), and those in the "Upper Limit" column were derive d using the upper limit method (Appendix D of Carter, 2000a) that would be the probable default values for regulatory MIR's if better estimates were not available. The values in parentheses are percent chan ges in the new values relative to the tabulated values shown. It can be seen that in most cases the new values are lower than the previous SAPRC-99 estimates for the few cases were they were available, and in all cases the new values were significantly lower than the upper limit MIR estimates. Uncerta inty codes for the current estimated mechanisms are given in the full updated reactivity tabulations incl uded as Appendix C to this report. The uncertainty codes are based on those used in previous versions of the mech anism (Carter, 2000a, 2003, 2007a) and are given in footnote [b] to Table C-1.

It should be noted that the MIR values given for the amines on Table E-1 and Appendix C were calculated assuming that the removal of the amines by reaction with HNO 3 is negligible under atmospheric conditions. If the upper limit estimate fo r removal by this reaction is assumed, the magnitudes of the ozone impacts are lower by an or der of magnitude or more . However, for regulatory purposes, we recommend that values used in the Ma ximum Incremental Reactivity (MIR) be based on conditions where they would have the maximum oz one impact, and those are the conditions where removal by reaction with HNO 3 is negligible. This is consistent with the general concept of maximum incremental reactivity (Carter, 1994a).

PM Impact Results

Although the primary focus of this project was reducing uncertainties in ozone impact estimates, data were also obtained concerning the relative PM formation potentials for AMP, ethanolamine, and d

limonene. All three of these compounds were found to ha ve very high PM formation potentials compared to most of the coatings (Carter et al, 2005b) a nd pesticide (Carter and Malkina, 2007) VOCs studied previously.4 Table E-1. Compounds in consumer products invent ories for which ozone impact estimates were added for this project, and recommended MIR values for regulatory applications.

MIR (gm O 3 / gm VOC) Compound This Work Previous Upper Limit Methylamine 7.25 10.8 (-33%) Dimethyl amine 2.65 9.4 (-72%) 14.9 (-82%) Ethyl amine 5.45 7.8 (-30%) 14.9 (-63%) Trimethyl amine 5.27 7.1 (-25%) 17.1 (-69%) Triethyl amine 3.07 16.6 (-81%) Triethylene diamine 2.77 15.0 (-81%) Ethanolamine 6.59 6.0 (+11%) 11.0 (-40%) Dimethylaminoethanol 5.15 4.8 (8%) 15.1 (-66%) 2-Amino-1-butanol 4.79 15.1 (-68%) 2-Amino-2-methyl-1-propanol -2.68 4.8 (negative) 15.1 (negative) Diethanol amine 2.22 4.0 (-45%) 12.8 (-83%) Triethanolamine 3.25 2. 8 (+18%) 11.3 (-71%) Triisopropanolamine 1.99 8.8 (-77%) Terpinolene 6.14 12.3 (-50%) Tripropylene glycol 2.07 3.0 (-32%) Diethylene glycol mono(2-ethylhexyl) ether 1.45 2.7 (-46%) Tripropylene glycol n-butyl ether 1.55 2.4 (-34%) Triethyl citrate 0.66 2.9 (-77%) 2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 0.33 2.8 (-88%) Citronellol (3,7-dimethyl-6-oct en-1-ol) 5.80 3.8 (53%) Linalool 5.44 10.8 (-49%) Geraniol 5.10 9.8 (-48%) Hexyl cinnamal 2.93 7.8 (-62%) Hydroxycitronellal 2.54 10.9 (-77%) Cinnamic aldehyde 4.79 12.7 (-62%) Amyl cinnamal 3.13 8.3 (-62%) 4-Vinylphenol 1.44 14.0 (-90%) Methylparaben (4-hydroxy benzoic acid, methyl ester) 1.70 11.0 (-85%) Propylparaben 1.44 9.3 (-85%) 2,6-Di- tert -butyl- p -cresol 1.18 7.6 (-85%) Beta-phenethyl alcohol 4.49 13.8 (-67%) Cinnamic alcohol 0.83 12.5 (-93%) Anethol 0.75 11.3 (-93%) 2-Ethylhexyl benzoate 0.92 7.2 (-87%) 1-Nitropropane 0.20 11.3 (-98%) Ethyl methyl ketone oxime 1.55 15.4 (-90%) Lauryl pyrrolidone 0.89 6.6 (-87%)

o -Dichlorobenzene 0.17 11.4 (-99%) 2-Chlorotoluene 2.86 13.3 (-78%) Methyl nonafluorobutyl ether 0.05 7.2 (-99%) Methyl nonafluoroisobutyl ether 0.05 7.2 (-99%) Ethyl nonafluorobutyl ether 0.19 6.4 (-97%) Ethyl nonafluoroisobutyl ether 0.19 6.4 (-97%)5 Discussion and Recommendations

This project made significant progress towards achieving its objectives of decreasing uncertainties and improving estimates of ozone impacts of c onsumer product compounds of interest to the CARB. Ozone impact estimates and MIR values were derived for a total of 7 amines and 30 other compounds present in consumer products inventories fo r which estimates were not previously available, ozone impact estimates and MIR valu es were significantly improved for 8 amines, and data were obtained to support the predictive capabilities of the previously derived mechanism for d -limonene. The major contribution of this project concerned the devel opment of improved methods for estimating mechanisms for calculating ozone impact estimates for amines , which were previously represented using highly approximate "placeholder" mechanisms, or for whic h only upper limit ozone impact estimates were available. As a result of this project, the estimated ozone impacts of amines appropriate for regulatory applications were found to be much lower than the upper limit values would indicate.

However, significant uncertainties still remain concerning the atmospheric reaction mechanisms of the amines. The most important concerns the removal of the amines by reaction with HNO 3 , which requires improved values for the equilibrium constants for these reactions, as we ll as more information about sources and sinks of HNO 3 , amines, and ammonia in the atmosphere. However, there are other uncertainties in the amine mechanisms and the available chamber data could not be used to quantitatively evaluate mechanism predictions because of the la ck of suitable analytical methods for quantitative analysis of amines in the gas phase. Methods need to be developed to quantitatively inject and monitor these compounds in the gas phase before quantitative da ta can be obtained to comprehensively evaluate the mechanisms for these compounds.

Mechanisms and reactivity estimates were also derived for a number of other compounds found in consumer product inventories for which estimates we re not previously available. However, the CARB staff had also requested reactivity estimates for a total of 63 other compounds for which reactivity estimates are still needed. Of these, 4 are probably of negligible reactivity and 20 are probably nonvolatile, leaving 39 compounds for which reactivity estim ates are actually needed. In some of these cases the chemical structures could not be determined, but in others the mechanisms are too uncertain to estimate; while for others, estimates could be made if more time and resources were available. Additional work in this area may be appropriate if the missing estimates remain problematic for the CARB.

Although the primary focus of this project was reducing uncertainties in ozone impact estimates, data were also obtained concerning the relative PM formation potentials for the compounds studied. Developing mechanisms for PM impacts was beyond the scope of this project, and it should be emphasized that the results are applicable only for the conditions of these experiments, and relative PM impacts in the atmosphere may be different. Howeve r, the data obtained should be useful for testing mechanisms for PM formation of these compounds , and work in this area is needed.6 

### INTRODUCTION

Background

Many different types of volatile organic com pounds (VOCs) are emitted into the atmosphere, where they can affect photochemical ozone formati on and other measures of air quality. Because VOCs can react in the atmospheres at different rates and with different mechanisms, the different types of VOCs can differ significantly in their effects on air quality. Therefore, VOC control strategies that take these “reactivity” differences into acc ount can potentially achieve ozone reductions and other air quality benefits in a more cost-effective manner than st rategies that treat all non-exempt VOCs equally. Reactivity-based control strategies have already been implemented in the California Air Resources Board (CARB) Clean Fuel/Low Emissions Vehicle (CF/LEV ) regulations (CARB, 1993), aerosol coatings regulations (CARB, 2000), and are be ing considered for architectural coatings (CARB 2007) and other stationary source applications. Since California has been successful in implementing reactivity-based regulations as a cost-effective way to reduce ozone, it is reasonable to expect that this approach will be adopted in other jurisdictions as well. For example, the U.S. EPA recently proposed a national rule on aerosol sprays based on reactivity (EPA, 2007).

Implementation of reactivity-based controls requires some means to measure and quantify relative ozone impacts of different VOCs. This is not a simple probl em, because the ozone impact of a VOC depends on the environment where the VOC is emitted as well as the nature of the VOC (e.g., see Carter and Atkinson, 1989). The effect of a VOC on oz one formation in a particular environment can be determined from its “incremental reac tivity”, which is defined as the amount of additional ozone formed when a small amount of the VOC is added to the e nvironment, divided by the amount added. Although this can be measured in environmental chamber expe riments, such experiment cannot be assumed to be the same as incremental reactivities in the atmosphere (Carter and Atki nson, 1989; Carter et al., 1995a). This is because it is not currently prac tical to duplicate in an experiment all the environmental factors that affect relative reactivities; and, even if it were, the results would only be applicable to a single type of environment. The only practical means to assess atmos pheric reactivity, and how it varies among different environments, is to estimate its atmospheric ozone impacts using airshed models. However, such model calculations are no more reliable than the chemical mechanisms upon which they are based. While the initial atmospheric reaction rates for most VOCs are reasonably well known or at least can be estimated, for most VOCs the subsequent reactions of the radicals formed are complex and have uncertainties that can significantly affect predictions of atmos pheric impacts. Laboratory studies can reduce these uncertainties, but for most VOCs they will not provide the needed information in the time frame required for current regulatory applications. For this reas on, environmental chambe r experiments and other experimental measurements of reactiv ity are necessary to test and veri fy the predictive capabilities of the chemical mechanisms used to calculate atmospheric reactivities.

The SAPRC-99 chemical mechanism (Carter, 2000a) has been the most widely used mechanism in the United States for calculating relative impacts (r eactivities) of VOCs on ozone formation, and is the basis of the MIR ozone reactivity scale used in the current CARB reactivity-based regulations. This mechanism, and its corresponding r eactivity scales, have recently been updated to the SAPRC-07 mechanism (Carter, 2007a), and it is expected that the current CARB regulatory reactivity scale will be updated to the SAPRC-07 version in the next update. The SAPRC-99 and SAPRC-07 mechanisms are based on the wide body of available laboratory data , kinetic and mechanistic evaluations, atmospheric chemical theories and estimation methods, and envir onmental chamber data for the many types of7 compounds involved (Carter, 2000a, 20 07a and references therein). The most recent SAPRC-07 reactivity tabulation has ozone impact estimates for over 1000 types of compounds. However, the number of compounds that have been experimentally studied is much more limited, and some of these ozone impacts are based on highly uncertain estimated or approxi mated mechanisms. In add ition, there are still many compounds in emissions inventories for which mechanis ms have not been derived, and therefore ozone impact estimates are not available.

Consumer products are an important component of the total emissions of VOCs into the atmosphere, which might make a non-negligible contribut ion to ozone formation. Because of this, the CARB has been implementing additional controls fo r VOC emissions from consumer products, and is considering use of reactivity-based controls for th ese source categories. However, the uncertainties in quantification of ozone impacts (reactivity) of many compounds contained in consumer products are a concern. For example, reactivity estimates for sever al constituents in hairsp ray and nail care products, particularly amines such as 2-amino-2-methyl-1-pr opanol (AMP) and ethanolamine, are highly uncertain. Improved reactivity estimates for these and others ar e needed. For many such compounds the CARB has had to use "upper limit" estimates of ozone im pacts of these compounds, based on worst-case considerations of reaction rates and mechanisms (see Appendix D of Carter, 2000a). This has led to relatively small amounts of some compounds dominating ozone impact estimates of some product categories. This is problematical because the actual ozone impacts of these product categories may be significantly less, and regulations based on upper-limit reactivity estimates may lead inappropriate control strategies.

Objectives

The overall objective of this project is to reduce uncertainties of ozone impact quantifications of selected consumer products compounds of interest to the CARB. Specific objectives included carrying out environmental chamber experiments needed to deve lop or evaluate mechanisms for a few selected representative compounds, derive mechanisms for these and related compounds and other compounds of interest based on the data obtained and other available information and estimates, and use the results to update or enhance the SAPRC-07 mechanism to incl ude representations and ozone impacts for these compounds.

Based on discussions with the CARB staff, it was decided that this project would focus primarily on reducing uncertainties in reactivity estimates for amines, with environmental chamber experiments being carried out using the represen tative amines AMP and aminoethanol. It was also determined that experiments were needed to reduce uncertainties in ozone impacts for d -limonene, an important consumer product VOC for which mechanism evaluation data were inadequate. The CARB staff also requested that the reactivity estimates be made for a number of co mpounds for which mechanisms reactivity estimates were not available, and to accomplish this it w as necessary to derive estimated mechanisms or approximate representations for the atmospheric reactions of these compounds for the purpose of calculating reactivity values.

Overall Approach

This work was carried out at the College of E ngineering Center for Environmental Research and Technology (CE-CERT) at the University of Califor nia at Riverside. The chamber experiments were carried out in the UCR EPA chamber, which w as developed under EPA funding for more precise mechanism evaluation at lower and more atmospherically representative pollutant levels than previously possible (Carter et al, 1999; Carter, 2002; Carter et al 2005a). Results of earlier experiments carried out in8 this chamber, including characterization results that ar e applicable to this study, are given in previous reports or publications (Carter, 2004; Carter and Malk ina, 2005; Carter et al, 2005a,b). The approach employed followed that used in our previous studi es of architectural coating (Carter and Malkina, 2005; Carter et al, 2005b) and pesticide (Carter a nd Malkina, 2007; Carter, 2007b) VOC reactivity.

The primary objective of these experiments with r espect to ozone formation is not to directly measure atmospheric ozone reactivity, but to provide data to test the ability of chemical mechanisms used in models to predict their ozone impacts in the at mosphere. If the mechanism can be shown to adequately simulate the relevant impacts of the VOC in well-characterized environmental chamber experiments with a range of chemical conditions representative of the atmosphere, one has increased confidence in the predictive capabilities of the model when applie d to atmospheric scenarios. If the mechanism performance in simulating the experiments is less than satisfactory, then the need to improve the mechanism is indicated, and one has decreased confiden ce in its predictions of atmospheric reactivity.

The most realistic chemical environment in th is regard is one where the test compounds or mixtures react in the presence of the other pollutants present in the atmosphere. Therefore, most of the environmental chamber experiments for this and th e coatings VOC reactivity programs consisted of measurements of “incremental reac tivity” of the subject compounds or solvents under various conditions. These involve two types of irradiations of model photochemical smog mixtures. The first is a “base case” experiment where a mixture of reactive organic gases (ROGs) representing those present in polluted atmospheres (the “ROG surrogate”) is irradiated in the presence of oxides of nitrogen (NO x ) in air. The second is the “test” experiment that consists of dupli cating the base case irradia tion, except that the VOC whose reactivity is being assessed is added. The di fferences between the results of these experiments provide a measure of the atmospheric impact of the test compound. These results can be used to test the ability of a chemical mechanism to predict the compound's atmospheric impacts under the chemical conditions of the experiment.

Base case experiments to simulate ambient chemical environments require choice of an appropriate reactive organic gas (ROG) surrogate mi xture to represent the reactive organics that are important in affecting ozone forma tion in the urban atmospheres. For this and the coatings reactivity projects, we continued to use a modified version of the 8-component “full surrogate” that was employed in our previous reactivity studies for this project. This is because, as discussed previously (Carter et al, 1995a), use of this surrogate gives a reasonably good representation of ambient anthropogenic VOC emissions as represented in current models, a nd use of more detailed mixtures would not give significantly different reactivity results. However, beca use of experimental problems, for this and many of the experiments in the coatings project, the formal dehyde was removed from the surrogate and the initial concentrations of the other ROG components were increased by 10% to make up for this reactivity change. Model calculations indicate th at this surrogate modification shoul d not have significant effects on experimental incremental reactivity results (Carte r and Malkina, 2005). Target and average measured compositions of the ROG surrogates for the reactivit y experiments for coatings projects are given by Carter and Malkina (2005). The target concentrations used in the expe riments for this program were the

same.
In order to provide data to test mechanism im pacts of the test compounds or mixtures under differing atmospheric conditions, the incremental reac tivity experiments are generally carried out using two different standard conditions of NO x availability relevant to VOC reactivity assessment. Probably the most relevant for California regulatory applica tions is “maximum incremental reactivity” (MIR) conditions, which are relatively high NO x conditions where ozone forma tion is most sensitive to VOC emissions. However, it is also necessary to provide data to test mechanism predictions under lower NO x9 conditions, since different aspects of the mechanisms are important when NO x is limited. The NO x levels that define the boundary line between VOC-sensitive, MIR-like conditions and NO x -limited (and therefore NO x -sensitive) conditions is that which yields th e maximum ozone concentrations for the given level of ROGs, or the conditions of the “maxim um ozone incremental reactivity” (MOIR) scale. Therefore, experiments with NO x levels that are approximately ha lf that for MOIR conditions might provide an appropriate test of the mechanism under NO x -limited conditions. This is referred to as “MOIR/2” conditions in the subsequent discussion. If NO x levels are reduced significantly below this, the experiment becomes less sensitive to VOC levels and thus less relevant to VOC reactivity assessment.

The conditions of NO x availability are determined by the ROG/NO x ratios in the base case incremental reactivity experiments. In order to comp letely fix the conditions of these experiments, it is also necessary to specify a desired absolute NO x level. We sought input from the CARB staff concerning the NO x levels they would consider to be appropriate to use for reactivity studies in the new chamber (Carter and Malkina, 2005). Based on their input, and model simulations of reactivity characteristics in our chamber, it was determined that the nominal in itial concentrations of the MIR base case experiment would consist of ~30 ppb NO x and ~0.5 ppmC ROG surrogate, and th e MOIR/2 experiment would consist of ~25 ppb NO x and ~1 ppmC ROG surrogate (Carter and Ma lkina, 2005). These were therefore the two standard base cases for all the incremental r eactivity experiments discussed in this report.

A number of other control and characterization e xperiments were also carried out in order to adequately characterize the conditions of the chamber for mechanism evaluation and background particulate matter (PM). These experiments are discu ssed where applicable in the results and modeling methods sections.

The SAPRC-07 mechanism, as documented by Cart er (2007a), was used as the starting point for the mechanism development aspect of the project. The mechanisms for the VOCs studied for this project were added to this mechanism, and these VOCs were added to the list of compounds for which reactivity values are tabulated. The SAPRC-07 documentation and tabulations (Carte r, 2007a, available at http://www.cert.ucr.edu/~carter/SAPRC) were update d to include the mechanisms and reactivity assignments developed or updated for this project.10 

### EXPERIMENTAL METHODS

Chamber Description

All of the environmental chamber experiments fo r this project were carried out using the UCR EPA environmental chamber. This chamber was cons tructed under EPA funding to address the needs for an improved environmental chamber database for mechanism evaluation (Carter et al, 1999, Carter, 2002). The objectives, design, construction, and results of the initial evaluation of this chamber facility are described in more detail elsewhere (Carter et al, 1999, Carter, 2002; Carter, 2004, Carter et al, 2005a). A description of the chamber is also given below.

The UCR EPA chamber consists of two ~85,000-lit er Teflon® reactors located inside a 16,000 cubic ft temperature-controlled “clean room” that is continuously flushed with purified air. The clean room design is employed in order to minimize background contaminants into the reactor due to permeation or leaks. Two alternative light sources can be used. The first consists of a 200 KW argon arc lamp with specially designed UV filters that give a UV and visible spectrum similar to sunlight. This light source could not be used for this project because it was not operational duri ng this period. Banks of blacklights are also present to serve as a backup light source for experiments where blacklight irradiation is sufficient, and this was used fo r the experiments for this project because of availability and because use of blacklights was judged to be sufficient to satisfy th e project objectives. The interior of the enclosure is covered with reflective aluminum pane ls in order to maximize the availa ble light intensity and to attain sufficient light uniformity, which is estimated to be ± 10% or better in the portion of the enclosure where the reactors are located (Carter, 2002) . A diagram of the enclosure and r eactors is shown in Figure 1. The spectrum of the blacklight light source is given by Carter et al (1995b).

The dual reactors are constructed of flexible 2 mil Teflon® film, which is the same material used in the other UCR Teflon chambers used for mechan ism evaluation (e.g., Carter et al, 1995b; Carter, 2000a, 2007a, and references therein). A semi-flexible framework design was developed to minimize leakage and simplify the management of large volume reactors. The Te flon film is heat-sealed into separate sheets for the top, bottom, and sides (the latter sealed into a cylindrical shape) that are held together and in place using bottom frames attached to the floor and moveable top frames. The moveable top frame is held to the ceiling by cables that are c ontrolled by motors that raise the top to allow the reactors to expand when filled or lower the top to allow the volume to contract when the reactors are being emptied or flushed. These motors in turn are c ontrolled by pressure sensors that raise or lower the reactors as needed to maintain slight positive pr essure. During experiments the top frames are slowly lowered to maintain continuous positive pressure as the reactor volumes decrease due to sampling or leaks. The experiment is terminated if the volume of one of the reactor reaches about 1/3 the maximum value, where the time this took varied depending on th e amount of leaks in the reactor, but was greater than the duration of most of the experiments discu ssed in this report. Since at least some leaks are unavoidable in large Teflon film reactors, the cons tant positive pressure is important to minimize the introduction of enclosure air into the reactor that may otherwise result.

As indicated in Figure 1, the floor of the reac tors has openings for a high volume mixing system for mixing reactants within a reactor and also for ex changing reactants between the reactors to achieve equal concentrations in each. This utilizes four 10” Teflon pipes with Teflon-coated blowers and flanges to either blow air from one side of a reactor to the other, or to move air between each of the two reactors11 20 ft. 20 ft. 20 ft. This volume kept clear to maintain light uniformity

Temperature controlled room flushed with purified air and with reflective material on all inner surfaces Dual Teflon Reactors

Two air Handlers are located in the corners on each side of the light

(not shown).

Gas sample lines to laboratory below Access Door 200 KW Arc Light 2 Banks of Blacklights

SEMS (PM) Instrument Floor Frame Movable top frame allows

reactors to

collapse

under
pressure control

Mixing System

Under floor of reactors

Figure 1. Schematic of the UCR EPA environmental chamber reactors and enclosure.

Teflon-coated air-driven metal valves ar e used to close off the openings to the mixing system when not in use, and during the irradiation experiments.

An AADCO air purification system that provides dry purified air at flow rates up to 1500 liters min -1 is used to supply the air to flush the enclos ure and to flush and f ill the reactors between experiments. The air is further purified by passing it through cartridges filled with Purafil® and heated Carulite 300® which is a Hopcalite® type catalyst, and also through a filter to remove particulate matter. The measured NO x , CO, and non-methane organic concentrations in the purified air were found to be less than the detection limits of the instrumentation employed (see Analytical Equipment, below).

The chamber enclosure is located on the second floo r of a two-floor laboratory building that was designed and constructed specifically to house this f acility (Carter et al, 2002). Most of the analytical instrumentation is located on the ground floor beneat h the chamber, with sampling lines leading down as indicated in Figure 1.

Analytical Instrumentation

Table 1 gives a listing of the analytical and ch aracterization instrumentation whose data were utilized for this project. Other instrumentation was av ailable and used for some of these experiments, as discussed by Carter 2002a and Carter et al, 2005a, but the data obtained were not characterized for modeling and thus not used in the mechanism evalua tions for this project. The table includes a brief description of the equipment, species monitored, a nd their approximate sensitivities, where applicable. These are discussed further in the following sections.12 Table 1. List of analytical and characterization instrumentation for the UCR EPA chamber.

Type Model or Description Species Sensitivity Comments

Ozone Analyzer Dasibi Model 1003-AH. UV absorption analysis. Also, a Monitor Labs Chemiluminescence Ozone Analyzer Model 8410 was used as a backup. O 3 2 ppb Standard monitoring instrument.

NO 1 ppb NO - NO y Analyzer TECO Model 42 C with external converter. Chemiluminescent analysis for NO, NO y by catalytic conversion. NO y 1 ppb Useful for NO and initial NO 2 monitoring. Converter close-coupled to the reactors so the “NO y ” channel should include HNO 3 as well as NO 2 , PANs, organic nitrates, and other species converted to NO by the catalyst. CO Analyzer Thermo Environmental Instruments Inc. Model 48 C CO 50 ppb Standard monitoring instrument

GC-FID Instruments Dual HP 6890 Series II GC with dual columns, loop injectors and FID detectors. Controlled by computer interfaced to network. VOCs ~10 ppbC 30 m x 0.53 mm GS-Alumina column used for the analysis of light hydrocarbons such as ethylene, propylene, n -butane and trans-2-butene and 30 m x 0.53 mm DB-5 column used for the analysis of C 5+ alkanes and aromatics, such as toluene and m -xylene. Loop injection is suitable for low to medium volatility VOCs that are not too “sticky” to pass through valves. Two 30 m x 0.32 mm DB-5 column measure C 5+ alkanes and aromatics, such as toluene and m -xylene. PTR-MS Ionicon Analytik high sensitivity proton transfer reaction mass spectrometer equipped with a quadruple MS. Controlled by computer interface. VOCs ~5ppt Used to measure light VOCs such as formaldehyde and some other compounds. Used primarily for formaldehyde for this project.

Gas Calibrator Model 146C Thermo Environmental Dynamic Gas Calibrator N/A N/A Used for calibration of NO x and other analyzers. Instrument acquired early in project and under continuous use.

Data Acquisition Sytem Windows PC with custom LabView software, 16 analoginput, 40 I/O, 16 thermocouple, and 8 RS-232 channels. N/A N/A Used to collect data from most monitoring instruments and control sampling solenoids. In-house LabView software was develo ped using software developed by Sonoma Technology for ARB for the Central California Air Quality Study as the starting point.Table 1 (continued)

13 Type Model or Description Species Sensitivity Comments

Temperature

sensors Various thermocouples, radiation shielded thermocouple housing Tempera -ture ~0.1 o C Primary measurement is thermocouples inside reactor. However, comparison with temperature measurements in the sample line suggests that irradiative heating may bias these data high by ~2.5 o C. See text. Humidity Monitor General Eastern HYGRO-M1 Dew Point Monitor Humidity Dew point range: -40 - 50 o C Instrument performs as expected, but dew point below the performance range for most of the experiments discussed in this report, except for those with added humidity.
QSL Spherical Irradiance Sensor Biospherical QSL-2100 PAR Irradiance Sensor. Responds to 400-700 nm light. SphericalBroadband Light Intensity Adequate Provides a measure of absolute intensity and light uniformity that is more directly related to photolysis rates than light intensity on surface. Gives more precise measurement of light intensity trends than NO 2 actinometry, but is relatively sensitive to small changes in position. Scanning Mobility Particle Spectrometer (SMPS) TSI 3080L column, TSI 3077
85 Kr neutralizer, and TSI 3760A CPC. Instrument design, control, and operation Similar to that described in Cocker et al. (2001) Aerosol number and sizedistributions Adequate Provides information on size distribution of aerosols in the 28 -730 nm size range, which accounts for most of the aerosol mass formed in our experiments. Data can be used to assess effects of VOCs on secondary PM formation.

Ozone, CO, NO, and NO y were monitored using commercially available instruments as indicated in Table 1. The instruments were spanned for NO, NO 2 , and CO and zeroed prior to most experiments using the gas calibration system indicated in Table 1, and a prepared calibration gas cylinder with known amounts of NO and CO. O 3 and NO 2 spans were conducted by gas phase titration using the calibrator during this period. Span and zero corrections were made to the NO, NO 2 , and CO data as appropriate based on the results of these span measurements, and the O 3 spans indicated that the UV absorption instrument was performing within its specifications.

Organic reactants other than the amines were measured by gas chromatography with FID detection as described elsewhere (Carter et al, 1995b); see also Table 1. The surrogate gaseous compounds ethylene, propylene, n -butane and trans-2-butene were monitored by using 30 m megabore GS-Alumina column and the loop sampling system. The second signal of the same GC outfitted with FID, loop sampling system and 30 m megabore DB-5 column was used to analyze surrogate liquid components toluene, n -octane, and m -xylene. The sampling methods employed fo r injecting the sample with the test compounds on the GC column depended on the volatility or “stickiness” of the compounds.

Both the GC instruments were controlled and thei r data were analyzed using HPChem software installed on a dedicated PC. The GC's were spanne d using the prepared calibration cylinder with known amounts of ethylene, propane, propylene, n -butane, n -hexane, toluene, n -octane and m -xylene in ultrapure nitrogen. Analyses of the span mixture were conducte d approximately every day an experiment was run, and the results were tracked for consistency.14 The surrogate components analyzed by the above syst em were calibrated by repeated analysis of a standard mixture containing these compounds, and verified by injecting and sampling known amounts of the compound in calibration chamber of known vo lume. The amounts of gaseous compounds injected were determined by vacuum methods, using an MK S Baratron precision pressure gauge, and bulbs of known volume, determined by weighing when fill ed with water. The amounts of liquid compounds injected were determined by measuring amounts inject ed using microliter syringes. The volumes of the calibration chambers were determin ed by injecting and analyzing compounds whose analyses have been calibrated previously.

d -Limonene was monitored by the GC with the 30 m megabore DB-5 column. The GC was calibrated using the known volume of the reactor and the amount injected for these and previous experimental runs with this compound.

Unfortunately, we were not able to develop a GC or other method to quantitatively analyze the amines in the gas phase. Although they give a r esponse on the GC when sampled using the Tenax cartridge sampling, this was not found to be quan titative or reproducible in practice. Insufficient resources, personnel, or time were available to availa ble to develop a suitable method for this project, and a suitable analytical method we could use was not found in the literature. Therefore, most amine compound concentrations were dete rmined using the amount injected and the chamber reactors known volume.

Most of the instruments, other than the GCs a nd aerosol instrument, were interfaced to a PCbased computer data acquisition system under the co ntrol of a LabView program written for this purpose. These data, and the GC data from the HP ChemSta tion computer, were collected over the CE-CERT computer network and merged into Excel files that were used for applying span, zero, and other corrections, and preparation of the data for modeling.

Sampling Methods

Samples for analysis by the continuous monito ring instrument were withdrawn alternately from the two reactors and zero air, under the control of sole noid valves that were in turn controlled by the data acquisition system discussed above. For most expe riments the sampling cycle was 5 minutes for each reactor, the zero air, or (for control purpose) the chamber enclosure. The program controlling the sampling sent data to the data acquisition program to indicate which state was being sampled, so the data could be appropriately apportioned when being processed. Data take n less than 3-4 minutes after the sample switched were not used for subsequent data processing. The sampling system employed is described in more detail by Carter (2002).

Samples for GC analysis of surrogate compounds were taken at approximately every 20-minute directly from each of the reactors through the separate sample lines attached to th e bottom of the reactors. The GC sample loops were flushed for a desired time with the air from reactors using a pump.

Samples from the PTR-MS were conducted from sel ected reactors for some of the experiments. The reactors sampled were selected manually, typically sampling for at least an hour before switching sides. The PTR-MS data were used primarily for mon itoring formaldehyde in a few of the experiments.

Characterization Methods

Use of chamber data for mechanism evaluation requ ires that the conditions of the experiments be adequately characterized. This includes measurements of temperature, humidity, and light, and wall15 effects characterization. Wall effects characterization is discussed in detail by Carter (2004) and updated by Carter and Malkina (2005) and Carter (2007a), a nd most of that discussion is applicable to the experiments for this project. The instrumentation u sed for the other characterization measurements is summarized in Table 1, above, and these me asurements are discussed further below.

Temperature was monitored during chamber experi ments using calibrated thermocouples attached to thermocouple boards on our computer data acquisition system. The temperature in each of the reactors was continuously measured using relatively fine gauge thermocouples that were located ~1’ above the floor of the reactors. These thermocoupl es were not shielded from the light, though it was expected that irradiative heating would be minimized because of their small size. Experiments where the thermocouple for one of the reactors was relocated to inside the sample line indicated that radiative heating is probably non-negligible, and that a corr ection needs to be made for this by subtracting ~2.5 o C from the readings of the ther mocouples in the reactors. This is discussed by Carter (2004).

Light Spectrum and Intensity . The spectrum of the light source in the 300-850 nm region has been measured using a LiCor LI-1800 spectroradiometer , which is periodically calibrated at the factory (e.g., see Carter et al, 2005b). Based on previous ex tensive measurements the spectrum of the blacklight light was assumed to be constant, and was not me asured during the time period of this project. The method used to derive the light intensity using the blacklight light source was based on that discussed by Carter et al (2005b), updated as described by Cart er and Malkina (2007). Briefly, the absolute light intensity is measured by carrying out NO 2 actinometry experiments periodically using the quartz tube method of Zafonte et al (1977) modified as discussed by Carter et al (1995b). In most cases the quartz tube was located in front of the reactors. Since this lo cation is closer to the light than the centers of the reactors, the measurement at this location is expected to be biased high, so the primary utility of these data are to assess potential variation of intensity over time. However, several special actinometry experiments were previously conducted where the quartz tube was located inside the reactors, to provide a direct measurement of the NO 2 photolysis rates inside the reactor s. The results of these measurements were used to derive a correction factor of 0.698 to derive NO 2 photolysis rates in the reactor from those measured in front of the reactor (Carter et al, 2005b ). The trend of in-reactor and corrected in-front-ofreactor actinometry results over blacklight run number (the number of runs cond ucted using blacklights) were then used to derive an assigned NO 2 photolysis rate as a function of blacklight run number. Results of actinometry measurements carried during the course of this project are given in the "Characterization results" section, below.

Experimental Procedures

The reaction bags were collapsed to the minimu m volume by lowering the top frames, and then emptied and refilled at least six times after each experi ment, and then were filled with dry purified air on the nights before experiments. Span measurements we re generally made on the continuous instruments prior to injecting the reactants for the experiments. The reactants were then injected through Teflon injection lines (that are separate from the sampli ng lines) leading from the laboratory below to the reactors. The common reactants were injected in bot h reactors simultaneously, and were mixed by using the reactor-to-reactor exchange blowers and pipes fo r 10 minutes. The valves to the exchange system were then closed and the other reactants were inject ed to their respective sides and mixed using the inreactor mixing blowers and pipes for 1 minute. The c ontents of the chamber were then monitored for at least 30 minutes prior to irradiation, and samples were taken from each reactor for GC analysis.

Once the initial reactants are in jected, stabilized, and sampled, the blacklights are turned on to begin the irradiation. During the irradiation the cont ents of the reactors are kept at a constant positive pressure by lowering the top frames as needed, unde r positive pressure control. The reactor volumes therefore decrease during the course of the experiments, in part due to sample withdrawal and in part due16 to small leaks in the reactor. A typical irradiation e xperiment ended after about 6 hours, by which time the reactors are typically down to about half their fully filled volume. Larger leaks are manifested by more rapid decline of reactor volumes, and the run is a borted early if the volume declines to about 1/3 the maximum. This was not the case for most of the experi ments discussed in this report. After the irradiation the reactors were emptied and filled six times as indicated above.

The procedures for injecting th e various types of reactants were as follows. The NO, and NO 2 were prepared for injection using a vacuum rack. Known pressures of NO, measured with MKS Baratron capacitance manometers, were expanded into Pyrex bulbs with known volumes, which were then filled with nitrogen (for NO) or purified air (for NO 2 ). In order to maintain constant NO/NO 2 ratios the same two bulbs of specified volume were utilized in most of experiments. The contents of the bulbs were then flushed into the reactor(s) with nitrogen. For experi ments with added CO, the CO was purified by passing it through an in-line activated charco al trap and flushing it into the reactor at a known rate for the amount of time required to obtain the desired concentrati on. Measured volumes of volatile liquid reactants were injected, using a micro syringe, into a 2 ft long Pyrex injection tube surrounded with heat tape and equipped with one port for the injection of the liquid and other ports to attach bulbs with gas reactants. For injections into bo th reactors (e.g, the NO x and base ROG surrogate components in incremental reactivity experiments), one end of the injection tube was attached to the “Y”-shape glass tube (equipped with stopcocks) that was connected to reactors and th e other end of injection tube was connected to a nitrogen source. The injections into a single reactor (e .g., for an amine in the r eactivity experiments) was similar except the “Y” tube was not used.

The procedures for injection of the hydrocar bon surrogate components were as follows. A cylinder containing n -butane, trans-2-butene, propylene and ethylene in nitrogen, was used for injecting the gaseous components of the surrogate. The cylinder was attached to the injection system and a gas stream was introduced into reactors at controlled flow for certain time to obtain desired concentrations. A prepared mixture with the appropriate ratios of toluene, n -octane and m -xylene was utilized for injection of these surrogate components, using the procedures as discussed above for pure liquid reactants. All the gas and liquid reactants intended to be the same in both reactors were injected at the same time. The injection consisted of opening the st opcocks and flushing the contents of the bulbs and the liquid reactants with nitrogen, with the liquid reactants being heated slightly using heat that surrounded the injection tube. The flushing continued for approximately 10 minutes.

The amines and d -limonene were injected, using a microsyringe, into a glass injection tube leading into the reactor to be employed for the comp ound. The procedure was simila r to that used for the liquid hydrocarbon surrogate components. The compoun ds were flushed into the chamber at least 30 minutes or longer, until there was no material visible in the injection tube. The amines and sample lines leading into the chamber were heated to ~90-100 o C.

Materials

The sources of the NO, CO and the various b ase case surrogate compounds came from various commercial vendors as employed in previous projects at our laboratory. The AMP was obtained from Fluka, the ethanolamine was from Sigma, and the d -limonene was from MP Biochemicals. In all cases the stated purities were at least 99%, and no further purification was carried out.17 

### MODELING METHODS

Base Mechanism

The starting point for the chemical mechanis m evaluated in this work is the SAPRC-07 mechanism as documented and listed by Carter (2007a). Files and software implementing this chemical mechanism are being prepared and will be ava ilable at the SAPRC mechanism web site at http://www.cert.ucr.edu/~carter/SAPRC. The changes a nd additions made to the mechanism as a result of work for this project are di scussed later in this section.

As discussed previously (Carter, 2000a,b, 20 07a), the SAPRC mechanisms consist of a “base mechanism” that represents the reactions of the in organic species and common organic products and lumped organic radical model species and “operator s”, and separate mechanisms for the initial reactions of the many types other organic compounds that are not in the base mechanism. The compounds, or groups of compounds, that are not included in the base mechanism but for whic h mechanism assignments have been made, are referred to as detailed model species. These include all the base ROG surrogate constituents and the compounds whose reactions were modeled in this work. These compounds can either be represented explicitly, with separate model speci es with individual reactions or sets of reactions for each, or using lumped model species similar to those employed in the “fixed parameter” version of SAPRC (Carter, 2000b, 2007a). The latter approach is useful when modeling complex mixtures in ambient simulations or simulations of experiments with complex mi xtures, but the other approach, representing each compound explicitly, is more appropr iate when evaluating mech anisms for individual compounds or simple mixtures. This is because the purpose of mechanism evaluations against chamber data is to assess the performance of the mechanis m itself, not to assess the performance lumping approaches. The latter is most appropriately assessed by comparing simulations of explicit and condensed versions of the same mechanism in ambient simulations.

In view of this, all of the organic constituen ts of the base ROG surrogate were represented explicitly using separate model species for each co mpound. In addition, the individual test compounds were also represented explicitly when simulating expe riments with those compounds. This gives the least approximate representation of the atmospheric reacti ons of these compounds within the framework of the SAPRC-07 mechanism. The mechanisms for the individu al test compounds are discussed later in this section.

Representation of Chamber Conditions

The procedures used in the model simulations of the environmental chamber experiments for this project were based on those discussed in detail by Carter (2004) and were employed in more recent studies (Carter and Malkina, 2007, and references th erein), except as indicated below. Carter (2004) should be consulted for details of the characterizat ion model and chamber effects parameters employed. The temperatures used when modeling were the averag es of the temperatures measured in the reactors, corrected as discussed by Carter (2004). The light intensity for the black light experiments varied with time, and the NO 2 photolysis rate for those experiments was derived as discussed in the Characterization Results section, below. The blacklight spectral distribu tion given by Carter et al (1995b) was found to be appropriate for the blacklights in this chamber and w as therefore used when modeling the blacklight runs discussed in this report.18 The chamber effects parameters used when modeli ng the experiments in this chamber were the same as those given by Carter (2004) except for th e HONO offgasing parameters, which were derived based on results of characterization runs carried out in conjunction with th ese experiments. As discussed by Carter (2004), the chamber effects model currently used for this chamber represents both the chamber radical source and background NO x offgasing by HONO offgasing, whose magnitude is determined by the chamber effects parameter RN-I, which is the ratio of the HONO offgasing rate to the NO 2 photolysis rate. The RN-I parameter that best fits the characterization data tends to vary over time depending on the conditions of the chamber, and the results of the ch aracterization experiments a pplicable to modeling the experiments discussed in this report, and the assign ment of the RN-I values used, are given in the Characterization Results section, below.

The initial reactant concentrations used in the model simulations were based on the measured values except for the amines, for which no quantita tive analytical method could be found during the course of this project. In those cases, an upper limit to the initial concentration can be derived from the volume of liquid injected and the volume of the reactor s, which were determined in separate experiments where known amounts of materials were injected and an alyzed in the gas-phase. Although the reactors are flexible, their initial volumes were ve ry consistent from run to run b ecause of the use of the pressure control system when filling the reactor to its maxi mum volume prior to the reactant injections (see Chamber Description section, above, and Carter, 2004). However, in the case of the amines, the results of the reactivity experiments indicate that it is probable that not all of the liquid injected was successfully introduced into the gas phase. Therefore, it was n ecessary to use the initial amine concentrations as an adjustable parameter in the model simulations of th e added amine experiments. This is discussed in the Mechanism Evaluation Results section, below.

Mechanisms for Amines

Amines might react in the atmosphere with OH radicals, O 3 , NO 3 radicals, and all these possibilities need to be considered when estimati ng their mechanisms for reactivity assessment. In addition, unlike most other VOCs currently represente d in the SAPRC mechanisms, amines are basic and might also be lost to some extent by reaction with HNO 3 , forming non-volatile amine salts, potentially reducing their availability for ozone formation. Photolysis is not e xpected to be important based on available absorption cross-section da ta for representative amines.

The amines for which mechanisms have been derive d for the current project are listed on Table 2, along with rate constants used for their reactions in the model. The mechanisms in terms of SAPRC-07 model species are given in Table A-1 in Appendix A. The derivations of these rate constants and mechanisms are discussed below.

Reaction with OH radicals

Available kinetic information concerning the rate constant for the reactions of amines relevant to those modeled in this study with OH radicals is summarized on Table 2. It is assumed that the reaction proceeds from H-atom abstraction, since there does not appear to be a chemically reasonable alternative mechanism. The rate constants are relatively high co mpared to H-atom abstractions from alkyl groups. This is also the case for tertiary amines, where abstraction from NH ca nnot occur, which indicates that the amino group enhances reaction at adjacent groups wh en abstracting the alpha-hydrogens. On the other hand, the rate constants are also high for reaction of OH with amines, such as AMP, which do not have reactive adjacent groups, which indicates that the reaction at the amino group itself is also relatively rapid. Therefore, both types of reaction need to be take n into account when deriving group additivity estimates.19 Table 2. Experimental and estimated rate cons tants for the reactions of amines included in mechanisms were derived for this project.

Rate Constant Compound Measured values [a] Avg. [b] Est'd [c] Diff [d]

Reaction with OH (10 -11 cm 3 molec -1 s -1 ) Methyl amine 1.73 1 2.20 2 1.97 3.08 36% Dimethyl amine 6.49 1 6.54 3 6.52 6.51 0% Ethyl amine 2.38 1 2.77 3 2.58 3.59 28% Trimethyl amine 3.58 1 6.09 3 4.84 5.01 4% Isopropylamine 3.78 t-Butyl amine 1.18 6 1.18 1.79 34% Triethyl amine 5.57 Ethanolamine 4.41 N,N-Dimethylethanolamine (DMAE) 9.00 4 4.70 5 6.85 6.02 -14% 2-Amino-1-butanol 5.32 2-Amino-2-methyl-1-propanol (AMP) 2.80 5 2.80 2.19 -28% Diethanol amine 10.1 Triethanol amine 8.04 Triisopropanol amine 9.37

Reaction with NO 3 (10 -13 cm 3 molec -1 s -1 ) Methyl amine 0.96 Dimethyl amine 2.03 Ethyl amine 1.16 Trimethyl amine 1.56 Isopropylamine 1.21 t-Butyl amine 0.59 Triethyl amine 1.71 Ethanolamine 1.35 N,N-Dimethylethanolamine (DMAE) 1.80 2-Amino-1-butanol 1.70 2-Amino-2-methyl-1-propanol (AMP) 0.59 Diethanol amine 3.30 Triethanol amine 2.29 Triisopropanol amine 2.29

Reaction with O 3 (10 -18 cm 3 molec -1 s -1 ) Methyl amine 0.007 7 0.007 0.011 52% Dimethyl amine 1.67 7 1.67 0.64 -61% Ethyl amine 0.020 Trimethyl amine 7.84 7 7.84 6.87 -12% Isopropylamine 0.033 t-Butyl amine 0 Triethyl amine 12.10 Ethanolamine 0.066 N,N-Dimethylethanolamine (DMAE) 6.76 7 6.76 13.2 95% 2-Amino-1-butanol 0.36 2-Amino-2-methyl-1-propanol (AMP) 0 Diethanol amine 3.77Table 2 (continued)

20 Rate Constant Compound Measured values [a] Avg. [b] Est'd [c] Diff [d]

Triethanol amine 40.2 Triisopropanol amine 40.2

Reaction with HNO 3 (10 -11 cm 3 molec -1 s -1 ) All amines – Lower limit assumption 0 All amines – Upper limit assumption 4 [a] References for measured rate constants: 1 Carl and Crowley (1998) 2 Atkinson et al. (1977) 3 Atkinson et al. (1978) 4 Anderson and Stephens (1988) 5 Harris and Pitts (1983) 6 Koch et al (1996) 7 Tuazon et al (1994) [b] Average of measured values. Used for deriving best-fit structure-reactivity parameters, and for environmental chamber and/or at mospheric reactivity modeling. [c] Estimated rate constant derived from structure-r eactivity estimates as discussed in the text. Used for environmental chamber and/or atmospheric reactivit y modeling if the entry in the "Used" column is blank [d] Difference between average experimental and estimated rate constant, where applicable.

The kinetic data in Table 2 were used to deri ve parameters for group additivity estimates for the rate constants for reactions of OH with amines, using the parameters in the SAPRC-99 and -07 mechanism generation systems (Carter, 2000a, 2007a) for reactions at the other positions in the molecules. Table 3 gives the H-abstraction gro up-additivity parameters used in the SAPRC-07 mechanism generation system, to which reactions at the amino groups have been added. For completeness, the table shows all the H-atom abstra ction parameters used in the system, including those for compounds other than amines. Footnotes to the table indicate how these parameters were derived. Table 2 indicates that the group-additivity methods can estimate the rate constants for the amines to within ± 26% on the average. Table 2 also gives the estimat ed OH radical rate constants for the amines represented in the mechanism for which no measured rate constant data are available, which were used in the mechanisms derived for these compounds.

The subsequent reactions of the carbon-centered radi cals formed in these reactions can be derived using the mechanism generation system as employed for other compounds, except that estimates need to be made for reactions of α -amino alkoxy radicals, e.g., RCH[O·]- NHR'. Although this is uncertain, to simplify the mechanism generation we assume that d ecompositions forming N-centered radicals, e.g., RCH[O·]-NHR' → RCHO + R'NH·, are not important, and estimate the relative rates of reactions for the competing routes based on estimates for other radicals considered to be similar. The applicable radicals and reactions assumed to dominate when generating mech anisms for amines in the current version of the mechanism are indicated on Table 4. These assumptions are uncertain, though alternative assumptions probably do not yield mechanisms with significantly different reactivities.

The subsequent reactions of the nitrogen-cente red radicals formed after H-abstraction from NH 2 or NH groups depends on whether there is an abstractable hydrogen in the α -position to the amine. If there is, then it is assumed that the dominant r eaction is abstraction of this hydrogen by O 2 , forming HO 2 and the corresponding C=N compound, e.g.,21 Table 3. Group additivity parameters used for est imating rate constants for abstraction reactions by OH and NO 3 radicals and by Cl atoms.

Table 3a. Abstraction rate constants assigned to groups
OH [a] NO 3 Cl Group k(300) A B D Notes [b] k(300) Notes k(300) Notes

CH 3 1.39e-13 4.49e-18 2 320 1,2 7.00e-19 9 3.43e-11 13 CH 2 9.41e-13 4.50e-18 2 -253 1, 2 1.50e-17 9 6.77e-11 13 CH 1.94e-12 2.12e-18 2 -696 1, 2 8.20e-17 9 4.46e-11 13 OH 1.42e-13 2.10e-18 2 85 1,2 0 10 0 10 CHO 1.56e-11 5.55e-12 0 -311 1,3 2.84e-15 [c] 11 6.64e-11 13 HCO(O) 0 1,4 0 10 0 12 OH(O) 9.99e-13 1.47e-17 2 85 5 0 10 0 10 CH 3 (Bz) [d] 4.92e-13 6 7.00e-19 12 3.43e-11 12 CH 2 (Bz) [d] 1.88e-12 7 1.50e-17 12 6.77e-11 12 CH(Bz) [d] 1.33e-12 8 8.20e-17 12 4.46e-11 12 CH 3 (NH x ) [e] 1.67e-11 22 ~6.2e-14 24 [f] CH 2 (NH x ) [e] 1.84e-11 22 ~4.4e-14 24 [f] CH(NH x ) [e] 2.01e-11 23 ~9.9e-14 24 [f] NH 2 1.41e-11 22 ~5.2e-14 24 [f] NH 3.17e-11 22 ~5.7e-14 24 [f] [a] Temperature dependences for OH rate constants given by k(T) = A B T exp(-D/T), where T is in o K. [b] Notes for derivations of the group rate constants and substituent correction factors are given below (Note [a] with Table 3b). [c] The temperature dependence of this group rate constant is given by 1.40e-12 x exp(-1860/T). [d] "Bz" refers to any aromatic carbon. [e] Applicable for x=0,1,2. [f] Group rate constants for reactions of chlorine with amines were not derived.

Table 3b. Group correction factors for abstraction reactions

Substitutent Correction Factor
OH NO 3 Cl Group Factor Note [a] Factor Note Factor Note

CH 3 1 1,2,14 1 17 0 14 CH x (x<3) 1.23 1,2 1.34 11 0.95 13 CH x (CO) 3.90 1,2 1.34 17 0.95 17 CH x (CO-O) 1.23 1,2 1.34 17 0.95 17 CH x (Cl) 0.36 1,2 1.34 17 0.19 19 CH x (Br) 0.46 1,2 1.34 17 0.95 17 CH x (F) 0.61 1,2 1.34 17 0.95 17 OH 3.50 1,2 0 18 1.07 13 CHO 0.75 1,2 0.18 11 0.40 13 CO 0.75 1,2 0.89 11 0.04 13 CO(O) 0.31 15 0 12 0.04 17 CO(OH) 0.74 1,2 0 12 0.04 17Table 3b (continued)

22 Substitutent Correction Factor
OH NO 3 Cl Group Factor Note [a] Factor Note Factor Note
O 8.40 1,2 0 18 1.07 20 O(CO) 1.60 1,2 0 18 1.07 17 O(HCO) 0.90 1,15 0 18 1.07 17 O(NO2) 0.04 1,2 0 18 1.07 17 O(OH) 3.90 5 1 18 1.07 17 NO2 0.00 1,2 0 12 n/a F 0.09 1,2 0 12 0.01 21 Cl 0.38 1,2 0 12 0.01 13 Br 0.28 1,2 0 12 n/a I 0.53 1,2 0 12 n/a C=C 1.00 1,2 1 17 0.95 13 ONO 2 0.04 1,2 0 12 0.12 Bz 1 14 1 17 2.03 13 NH 2 , NH, N 1 14 1 14 [b] [a] Notes for derivations of the group rate constant s and group correction factors are as follows. (Note that the cited references are given by Carter (2007a ) and are not in the reference list for this report unless they are relevant for the amines). 1 Same as used in SAPRC-99 2 Kwok and Atkinson (1995) 3 Based on IUPAC (1997) recommendations for acetaldehyde and propionaldehyde 4 Reaction at formate group assumed to be negligib le based on tabulated formate rate constants. 5 Derived to fit IUPAC (2006) recommended rate c onstant and branching ratio for reaction of OH with methyl hydroperoxide. 6 Average of estimated rate constants per methy l group for the alkylbenzenes for which aromatic aldehyde yields have been derived. Reaction at the methyl group is estimated based on the aromatic aldehyde yield and the total rate constant. 7 Derived from the difference for the total rate constants for ethylbenzene and toluene, assuming the same rate constant for addition to the aroma tic ring and the estimated rate constant at the methyl group in ethylbenene. 8 Derived from the difference for the total rate constants for isopropylbenzene and toluene, and p

cymene and p -xylene, assuming the same rate constant fo r addition to the aromatic ring and the estimated rate constants for reactions at the methyl groups in isopropylbenzene and p -cymene. 9 From Atkinson (1991). Derived from the correlation between NO 3 and OH radical rate constants. 10 Assumed to be negligible. 11 Derived from the IUPAC (1997) recomme nded rate constant for acetaldehyde. 12 No explicit assignment made. By default, the system uses the same assignment as for standard CH 3 , CH 2 , or CH groups. 13 Derived by Carter (2007a) from measure d chlorine + VOC rate constants. 14 Assigned. 15 From Kwok et al (1996). 16 Adjusted to fit OH + ethyl and propyl formate rate constants (Wallington et al, 1988)Table 3b (continued)

23 17 No assignment made. This is the default valu e used by the mechanism generation system, and may not be appropriate. 18 This is the assignment incorpor ated into the current system. It may not be appropriate. It is not used as the basis for estimating NO 3 rate constants for any detailed model species. 19 Based on chloroacetaldehyde only 20 Estimated to be approximately the same as the factor for OH. 21 Estimated to be approximately the same as the factor for Cl. 22 Derived to give the best fits to the available kinetic data for simple am ines and alcohol amines for which kinetic data are available, as indicated in Table 2. In order to fit the data for tertiary amines, it is necessary to assume that OH reacts w ith an enhanced rate at groups next to the amino group, and in order to fit the data for am ines, such as AMP and t-butyl amine, that do not have abstractable hydrogens next to the ami no group it is necessary to assume that reaction also occurs at a significant rate at the NH or NH 2 groups. 23 No data are available for which to derive gr oup-additivity estimates for this type of group. The group rate constant is estimated by lin ear interpolation from those used for CH 3 (NH x ) and CH 2 (NH x ). 24 The only kinetic data concerning the reactions of NO 3 radicals with amines is for N-methyl-2- pyrrolidinone (NMP), where a relativel y high rate constant of 1.26 x 10 -13 cm 3 molec -1 s -1 is measured (Aschmann and Atkinson, 19 99). This suggests that this reaction is also rapid for other amines. We assume that this is an H-atom abstraction reaction, forming HNO 3 . For lack of other data, use the rate constant for NMP as the basi s for estimating the group rate constants for reaction at the -CH 2 (N) or CH 3 (N) groups. The group rate constant s for reactions at other amine groups, including NH and NH 2 , are estimated assuming that the ratios of rate constants for reactions at the various groups are the same for the NO 3 reaction as derived for the OH reaction. This is highly uncertain. [b] Group rate constants for reactions of chlorine with amines were not derived

RCH 2 NH· + O 2 → HO 2 + RCH=NH This is based on kinetic data obtained by Lindley et al (1979) for reactions of (CH 3 ) 2 N· with O 2 , NO, and NO 2 , where the reaction with O 2 , forming HO 2 + CH 3 -N=CH 2 , is calculated to dominate under atmospheric conditions.

The subsequent reactions of the C=N produc ts formed in these reactions are unknown and therefore this is an additional source of uncerta inty in the mechanism. Th ese are expected to be reasonably reactive compounds. For the current mechan ism, they are approximately represented by the generic reactive non-aldehyde oxygenated species PROD2 . The appropriateness of this representation is highly uncertain.

The above type of reaction cannot occur if the nitrogen-centered radical lacks an abstractable hydrogen in the α -position, as is the case in radicals predicted to be formed in the reactions of t-butyl amine and 2-Amino-2-Methyl-1-Propanol (AMP). In these cases, the only expected reactions of the nitrogen-centered radical is reaction with NO, NO 2 , or HO 2 , e.g., (CH 3 ) 3 CNH· + NO → (CH 3 ) 3 CNHNO (a) (CH 3 ) 3 CNH· + NO 2 → (CH 3 ) 3 CNHNO 2 (b) (CH 3 ) 3 CNH· + HO 2 → O 2 + (CH 3 ) 3 CNH 2 (c)24 Table 4. Assignments made for alkoxy radical in termediates predicted to be formed in the photooxidation mechanisms of the amines.

Radical Reaction Assumed to Dominate
·OCH 2 -NH 2 + O 2 HCO-NH 2 + HO 2 · CH 3 -NH-CH 2 O· + O 2 CH 3 -NH-CHO + HO 2 · .OCH 2 CH 2 -NH 2 HCHO + .CH 2 -NH 2 CH 3 CH(O·)NH 2 + O 2 CH 3 C(O)NH 2 + HO 2 · CH 3 -N(CH 3 )CH 2 O· + O 2 CH 3 -N(CH 3 )CHO + HO 2 · NH 2 CH(O·)CH 2 OH HCO-NH 2 + .CH 2 OH CH 3 C(O·)(CH 3 )NH 2 CH 3 C(O)NH 2 + CH 3 · CH 3 C(CH 3 )(CH 2 O·)NH 2 HCHO + CH 3 C(·)(CH 3 )NH 2 CH 3 -N(CH 2 O·)CH 2 CH 2 OH CH 3 -N(CH 2 OH)CH 2 CH(·)OH CH 3 C(CH 2 O·)(NH 2 )CH 2 OH + O 2 CH 3 C(CHO)(NH 2 )CH 2 OH + HO 2 · .OCH 2 CH 2 CH(NH 2 )CH 2 OH NH 2 CH(CH 2 CH 2 OH)CH(·)OH CH 3 -N(CH 3 )CH(O·)CH 2 OH CH 3 -N(CH 3 )CHO + .CH 2 OH CH 3 CH(O·)CH(NH 2 )CH 2 OH CH 3 CHO + NH 2 CH(·)CH 2 OH CH 3 CH 2 C(O·)(NH 2 )CH 2 OH CH 3 CH 2 C(O)NH 2 + .CH 2 OH HOCH 2 CH 2 -NH-CH(O·)CH 2 OH HCO-NH-CH 2 CH 2 OH + .CH 2 OH CH 3 CH 2 -N(CH 2 CH 3 )CH 2 CH 2 O· CH 3 CH 2 -N(CH 2 CH 2 OH)CH(·)CH 3 CH 3 CH 2 -N(CH 2 CH 3 )CH(O·)CH 3 CH 3 CH 2 -N(CH 2 CH 2 ·)CH(CH 3 )OH CH 3 CH 2 -N(CH 2 CH 2 O·)CH(CH 3 )OH CH 3 CH(·)N(CH 2 CH 2 OH)CH(CH 3 )OH CH 3 CH 2 -N(CH 2 CH 2 OH)CH(O·)CH 3 CH 3 CH 2 -N(CH 2 CH(·)OH)CH(CH 3 )OH CH 3 CH(O·)N(CH 2 CH 2 OH)CH(CH 3 )OH CH 3 CH(OH)N(CH 2 CH(·)OH)CH(CH 3 )OH HOCH 2 CH 2 -N(CH 2 CH 2 OH)CH(O·)CH 2 OH HCO-N(CH 2 CH 2 OH)CH 2 CH 2 OH + .CH 2 OH CH 3 CH(OH)CH 2 -N(CH 2 CH(CH 3 )OH)CH 2 - CH(CH 2 O·)OH HCHO + CH 3 CH(OH)CH 2 -N(CH 2 CH(·)OH)CH 2 CH- (CH 3 )OH CH 3 CH(OH)CH 2 -N(CH 2 CH(CH 3 )OH)- CH(O·)CH(CH 3 )OH CH 3 CH(OH)CH 2 -N(CHO)CH 2 CH(CH 3 )OH + CH 3 CH(·)OH

If NO x is present, the major reaction is expected to be process (b), forming the nitramine, since the nitrosoamines formed in process (a) are expected to undergo rapid photolysis back to NO and the radical, resulting in no net reaction. Since nitramine formati on is a radical terminating process, this mechanism predicts that t-butyl amine and AMP would be radical inhibitors, since reaction forming the N-centered radical is estimated to be the major initial reaction. This is consistent with the fact that these compounds are indeed found to be strong ozone and radical inhi bitors in environmental chamber experiments, as discussed in the Mechanism Evalua tion Results section, below.

For implementation in the mechanism, the m odel species "NRAD" is used to represent the reactions of the N-centered radicals that lack abstractable hydrogens in the α position. This species is representing as reacting with NO 2 to form a nitramine, with a rate constant estimated by assuming that it is the same as for the reaction of NO 2 with the generic higher acyl peroxy radical species RCO 3 . The nitramine is approximately represented by PROD2 in the current mechanism, though the appropriateness of this representation is also highly uncertain. Th e reaction with NO, forming the nitrosoamine, is neglected because of the expected rapid photolysis of the nitrosoamine to reverse the reaction. In the absence of NO x , the NRAD is represented as reacting with HO 2 to re-form the amine, with a rate constant25 assumed to be the same as u sed for the reaction of RCO 3 with HO 2 . Because of the way the mechanism is implemented it is not practical to represent the amine formed in the reaction as the amine itself, so its subsequent reactions are therefore neglected. This is because the two amines represented to form NRAD are inhibitors, so representing them with reactive pr oduct model species such as PROD2 is inappropriate.

Table A-1 in Appendix A gives the mechanisms that were derived for the reactions of the OH radicals with amines based on these assumptions and representations.

Reaction with NO 3 Radicals

The only kinetic data concerning the reactions of NO 3 radicals with amines is for N-methyl-2- pyrrolidinone (NMP), where a relativel y high rate constant of 1.26 x 10 -13 cm 3 molec -1 s -1 was measured (Aschmann and Atkinson, 1999). This suggests that this reaction is also rapid for other amines. We assume that this is an H-atom abstraction reaction, forming HNO 3 . For lack of other data, we use the rate constant for NMP as the basis for estimating th e group rate constants for reaction at the -CH 2 (N) or CH 3 (N) groups. The group rate constants for reac tions at other amine groups, including NH and NH 2 , are estimated assuming that the ratios of rate constants fo r reactions at the various groups are the same for the NO 3 reaction as derived for the OH react ion. This is highly uncertain.

These assumptions were used as the basis for deriving group-additivity estimates for H-atom abstraction reactions of NO 3 radicals with amines, as indicated on Table 3, above. For completeness, that table also gives group-additivity parameters for other H-atom abstractions by NO 3 from other groups as implemented in the current mechanism generation syst em. These were used for deriving rate constants and initial branching ratios for the reactions of NO 3 with all the amines used in the current study. These estimated rate constants are included in Table 2, above.

The radicals formed in the H-atom abstraction r eactions that are assumed to be formed in the initial NO 3 + amine reactions are the same as those for med in the OH system. The representations of those reactions, and of the products formed, have been already discussed above. The mechanisms so derived are given in Table A-1 in Appendix A.

Reactions with Ozone

The limited available kinetic da ta concerning the reaction of O 3 with amines are given in Table 2, above. The rate constant for methylamine is too low to be important under atmospheric conditions, but the rate constants for the other compounds are sufficiently high that O 3 reaction may be non-negligible, though probably not dominant, under atmospheric c onditions. Therefore, the possible reactions of O 3 with amines need to be taken into account when deriving atmospheric mechanisms for these compounds.

Although some product data were obtained in the st udy of Tuazon et al (1994), the mechanism is uncertain, though the products they observed were sim ilar to those observed or expected from the OH reaction. Murphy et al (2007) studied aerosol-phase products of the reactions of trimethyl amine with O 3 and observed similar aerosol phase products in the O 3 reaction as formed in the NO x -air photooxidations of the amine, which are expected to be dominated by the OH reaction. If O-addition reactions occur, the adduct formed must eventually decompose to form pr oducts similar to those formed in H-abstraction reactions, otherwise different types of products would be observed in O 3 reactions as formed in OH reactions or photooxidations. The relatively high rate constants for the reaction of O 3 with trimethyl amine and DMAE, and the low rate constant for me thylamine, suggests that abstraction from N-H bonds is probably not the major process.26 Based on these considerations, for rate constant and mechanism estimation purposes we assume that the initial reaction of O 3 with amines is at the group next to the amino group, ultimately resulting in abstraction from α C-H bonds, forming OH radicals and the same types of radicals as formed in the OH reaction, e.g.,

CH 3 NH 2 + O 3 → [adduct?] → O 2 + OH + ·CH 2 NH 2 This is consistent with the fact that simi lar products appear to be formed in the O 3 as the OH reaction, and is also reasonably consistent with the fact that the O 3 + amine rate constant data are well correlated with the estimated rate constant for reaction of OH radica ls at the group next to the amino group, with the correlation being better than the correlation of the O 3 rate constant to the total rate constant. This is shown on Figure 2, where it can be seen that the O 3 rate constants are better correla ted to the rate constant for OH abstraction from the adjacent group than to the total OH radical rate constant.

The correlation between the estimated rate constant s for reaction of OH with the group next to the amino groups and the total O 3 rate constants were used as the basis for estimating the rate constants for reactions of O 3 at these groups, forming OH, O 2 , and the corresponding H-abstraction radical. The data for the methylamines and DMAE were fit by

K(group,O 3 ) = 10 -42.97 - {5.84 k(group,OH)}

, where k(group) refers to net H-atom abstraction at a group adjacent to the amino group and the rate constants are in cm 3 molec -1 s -1 . This was used as the basis for estimating both total O 3 rate constants and relative rates of reaction at differe nt positions (secondary or tertiary amines) that have non-equivalent substituents. The O 3 rate constants so derived are given in Ta ble 2, above, where it can be seen that the measured values are predicted within a factor better than 2.

The radicals formed in these O 3 reactions are assumed to be the same as formed when OH abstracts from the C-H bond in the group adjacent to the amino group, and the representations of their

16.5 17.5 18.5 19.5 20.5

10.0 10.2 10.4 10.6 10.8 11.0

- Log10 k(OH) (cm 3 molec -1 s- 1 )- Log 10 k(O3) Relative to total OH rate constant
Relative to OH reaction at alpha position
Best fit line to above

Figure 2. Plots of logs of the rate constants for the reactions of the methylamines and DMAE with O 3 against the logs of the rate constants for reaction of OH radicals at the group next to the amino group and also against the total OH rate constant.27 subsequent reactions, and of the products formed, ar e the same as used for the OH radical reactions, discussed above. The mechanisms so derived are given in Table A-1 in Appendix A.

Reactions with HNO 3
Amines are basic compounds th at can react with HNO 3 to form amine salts, which are nonvolatile and partition into the aerosol phase, making the amine unavailable for reaction in the gas phase. However, this reaction is reversible and an equilibriu m exists between the salt, and the amine and HNO 3 . This means that under sufficiently low amine or HNO 3 concentrations, or if other basic species such as NH 3 are present to compete with the HNO 3 , or there are other important loss processes for the amine or HNO 3 , then the salt formation may be less important in affec ting the availability of the amine to react in the gas phase. The equilibrium constants for amine salt formation are too uncertain to be useful for estimating availability based on theoretical equilibrium consid erations (Murphy et al, 2007). Aerosol amine salt formation from reactions of amines with HNO 3 in environmental chamber experiments under simulated atmospheric conditions has been st udied by Murphy et al (2007), who found that aerosol amine salt formation occurs rapidly when the gas-phase amine and HNO 3 are present at concentrations of ~100 ppb. However, they also found that the amine salt aeros ol formation eventually declined relatively under conditions where the amine can undergo gas-phase reactions, such as when O 3 is added or photooxidation in the presence of NO x . This suggests that revolatilization may be important under atmospheric conditions, and because of the relatively high gas phase reactivity of the amines, the amine salt formation may not be a permanent sink for the amine under conditions where O 3 formation can occur. In addition, if excess NH 3 is present in the environment, it may compet e with the amine for nitrate salt formation, making loss of the amine to salt formation less important.

Model simulations of the environmental chamber experiments carried out for this project were found not to be sensitive to assumptions made concerni ng the loss of amines by reaction with gas-phase HNO 3 . Model calculations assuming rapid (and irreversib le) loss of the amine due to reaction with HNO 3 gave essentially the same results in terms of calculations of O 3 and other measured gas-phase species as those assuming no reaction between the amine and HNO 3 . This is because the amount of HNO 3 calculated to be formed in the gas-phase reactions of NO x is small compared to the amount of amine injected. Therefore, the chamber experiments are not useful for assessing whether loss of amines due to this reaction may be important under atmospheric conditions.

On the other hand, as discussed in the Atmosphe ric Reactivity Results section, below, in the model simulations of the ozone impacts of the amines in the box model, atmospheric scenarios used for calculation of the ozone reactivity scales (C arter, 1994a, 2000a, 2007a) are highly sensitive to assumptions made concerning the loss of the amine due to reaction with HNO 3. The impact in the real atmosphere depends on the magnitudes of HNO 3 sources and sinks, the amounts of other amines or ammonia present to compete with the HNO 3 , and the amine salt equilibrium constants, which are unknown. At present, there is insufficient informati on available to quantify these impacts, or even to assess which of these extremes is most likely to be representative of ozone exceedances in California.

Because of these uncertainties, atmospheric reactivity assessment calculations are carried out assuming either no amine + HNO 3 reaction, or assuming that the reaction is rapid and irreversible. The latter simulations use an amine + HNO 3 rate constant of 4 x 10 -11 cm 3 molec -1 s -1 , which is a high rate constant representative of radical + radical reactions. The product formed is assu med to be unreactive in these upper limit calculations. The actual rate constants are unknown but probably less than this value, which is considered appropriate for upper limit analyses only.

As indicated above, the environmental chambe r simulations are not sensitive to assumptions concerning the rate or reversibility of the amine + HNO 3 reaction. However, because the results of the28 model simulations of the added amine experiments indicat e that not all the injected amine is available for reaction in the gas phase, most of the chamber simu lations are based on the assumption that the amine + HNO 3 reaction is rapid and irreversible.

Mechanism for d -Limonene

The mechanism used for d -limonene in this work is the sa me as that given with the SAPRC-07 mechanism as documented by Carter (2007a). This was derived using the SAPRC-07 mechanism estimation and generation system, incorporating the mea sured rate constants for its various atmospheric reactions. The reactions and rate constants are given in Table A-1 in Appendix A, with footnotes to the table indicating the sources of the rate constants used. Because the SAPRC-07 limonene mechanism performed reasonably well in simulating the new limonene experiments carried out for this project, this mechanism was not changed as a result of this work.

Mechanisms for Other VOCs.

The consumer products compounds for which mechan isms and/or ozone reactivity estimates have been added as part of this project are summarized on Table 5. In addition to the amines, discussed above, these include a number of other compounds found in consumer products speciation surveys for which reactivity estimates are needed by the CARB staff. The table indicates how the mechanisms were derived or, for compounds represented using the "lumped mol ecule approach", the compound or model species assumed to have the same ozone impact on a per-molecule basis. The reactions and rate constants for the compounds that were represented explicitly are given in Table A-1 in Appendix A, and footnotes to the table give more information how the mechanisms and/or rate constants were estimated. Table A-2 summarizes the lumped molecule representations used, for compounds where this is applicable.

The CARB staff also requested ozone impacts fo r other compounds found in consumer product speciation surveys for which ozone impacts have not ye t been derived. These are also listed in Table 5, along with the reasons why we were unable to de rive mechanisms or assignments for those compounds.

Atmospheric Reactivity Simulations

Atmospheric reactivity model simulations were ca rried out to derive MIR and other atmospheric reactivity values for the selected compounds whose oz one impacts were evaluated for this project. The scenarios and methods used were the same as those u sed when calculating the MIR and other atmospheric ozone reactivity scales, and were described previously (Carter, 1994a,b 2000a, 2007). The base ROG constituents were represented using the lumping proce dures incorporated in the condensed version of the SAPRC-07 mechanism (Carter, 2007a), and individua l compounds whose reactivities were being assessed were represented explicitly. The mech anisms used for the compounds studi ed in this project are discussed above and also given in Table A-1 in Appendix A.

Note that the impact of the reactions of amines with HNO 3 under atmospheric conditions is very uncertain, and for that reason the atmospheric reacti vity calculations were carried out using only upper and lower limit assumptions in this regard. The eff ects of assumptions regarding the importance of amine removal are shown in the Atmospheric Reactivity Calc ulation Results section, below. For the purpose of deriving reactivity scales for regulatory applicatio ns, it is probably appropriate to use upper limit estimates of the ozone impacts of these compounds u nder conditions where they will have their highest impacts. For that reason, the tabulated atmospheric reactivity values given in the Atmospheric Reactivity Calculation Results section were derived based on ca lculations assuming that loss by reaction with HNO 3 is negligible.29 Table 5. List of compounds whose reactivities have been added to the SAPRC-07 reactivity tabulation or whose reactivities have been requested by the CARB.

Compound CAS No. Mechanism Derivation Method or Representation

Amines for which mechanisms were derived Methylamine 74-89-5 Dimethyl amine 124-40-3 Ethyl amine 75-04-7 Trimethyl amine 75-50-3 Isopropylamine 75-31-0 t-Butyl amine 75-64-9 Triethyl amine 121-44-8 Ethanolamine 141-43-5 Dimethylaminoethanol 108-01-0 2-Amino-1-butanol 96-20-8 2-Amino-2-methyl-1-propanol 124-68-5 Diethanol amine 111-42-2 Triethanolamine 102-71-6 Triisopropanolamine 122-20-3 The mechanisms were derived based on work for this project as discussed in this report. Reactions and rate constants as implemented in the SAPRC-07 mechanism are given in Table A-1 in Appendix A. The atmospheric ozone impacts of these compounds depend on the extent to which they are removed by reaction with HNO 3 , which is highly uncertain. In order to provide an upper limit estimate of the ozone impacts of these compounds under conditions where they will have their highest impacts, the tabulated atmospheric reactivity values were derived based on calculations assuming that loss by reaction with HNO 3 is negligible. If loss by this process is important, the magnitude of the ozone impact may be more than an order of magnitude lower. Other Compounds whose mechanisms were added Tripropylene glycol 24800-44-0 Diethylene glycol mono(2- ethylhexyl) ether 1559-36-0

Tripropylene glycol n-butyl ether 55934-93-5

Triethyl citrate 77-93-0 2,2,4-Trimethyl-1,3- pentanediol diisobutyrate 6846-50-0

Citronellol (3,7-dimethy-6- octen-1-ol) 106-22-9

Linalool 78-70-6 Geraniol 106-24-1 Hydroxycitronellal 107-75-5 The mechanisms were derived using the SAPRC-07 mechanism generation system without modifications or new explicit assignments. The reactions and rate constants as implemented in SAPRC-07 are listed in Table A-1 in Appendix A.

Terpinolene 586-62-9 1-Nitropropane 108-03-2 Methyl nonafluorobutyl ether 163702-07-6 Ethyl nonafluorobutyl ether 163702-05-4 The mechanisms were derived using the SAPRC-07 mechanism generation system without modifications except that the dominant re action pathways for some radicals had to be assigned based on mechanism generation estimates for similar radicals. The reactions and rate constants as implemented in SAPRC-07 are listed in Table A-1 in Appendix A. 2-Ethylhexyl benzoate 5444-75-7 Ethyl methyl ketone oxime 96-29-7 Mechanism estimated. The r eactions and rate constants as implemented in SAPRC-07 are listed in Table A-1 in Appendix A. Footnotes to the table indicate the estimation methods used.Table 5 (continued)

30 Compound CAS No. Mechanism Derivation Method or Representation Methyl iodide 74-88-4 Mechanism of Ca rter (2007b) used. The reactions and rate constants as implemented in SAPRC-07 are also listed in Table A-1 in Appendix A. Footnotes to the table give the sources of the rate constants and estimates. Compounds represented using the "Lumped Molecule" approach (assumed to have the same ozone impact per mol ecule emitted as another compound or model species) Hexyl cinnamal 101-86-0 Cinnamic aldehyde 104-55-2 Amyl cinnamal 122-40-7 Assumed to have the same per-molecule reactivity as the lumped c5+ unsaturated carbonyl model species (ISOPROD) used to represent these products in the isoprene mechanism. 4-Vinylphenol 2628-17-3 Assumed to have the same per-molecule reactivity as styrene Methylparaben (4-Hydroxy benzoic acid, methyl ester) 99-76-3

Propylparaben 94-13-3 2,6-Di-tert-butyl- p -cresol 128-37-0 Assumed to have the same per-molecule reactivity as

o -cresol

Beta-phenethyl alcohol 98-85-1 Assumed to have the same per-molecule reactivity as benzyl alcohol
Cinnamic alcohol 104-54-1 Anethol 104-46-1 Assumed to have the same per-molecule reactivity as ß-methyl styrene Triethylene diamine 280-57-9 Assumed to have the same per-molecule reactivity as triethyl amine Lauryl pyrrolidone 2687-96-9 Assumed to ha ve the same per-molecule reactivity as

n -methyl-2-pyrrolidone.

o -Dichlorobenzene 95-50-1 Assumed to have the same per-molecule reactivity as p-dichlorobenzene
2-Chlorotoluene 95-49-8 Assumed to have the same per-molecule reactivity as toluene Methyl nonafluoroisobutyl ether 163702-08-7

Ethyl nonafluoroisobutyl ether 163702-06-5 Assumed to have the same per-molecule reactivity as the corresponding nonafluorobutyl ether.

Compounds requested by the CARB st aff for which mechanisms were not derived because the compounds are estimated to have very low ozone impacts.
HCFC-225ca 422-56-0 HCFC-225cb 507-55-1 HFC 43-10mee 138495-42-8 HFC-245fa 460-73-1Table 5 (continued)

31 Compound CAS No. Mechanism Derivation Method or Representation

Compounds requested by the CARB staff for which mechanisms were not derived because there was insufficient time and resources available in the project to derive estimated mechanisms. (It may be possible to develop estimated mechanisms for these compounds, but reactivity estimates would be highly uncertain) Acetamide MEA (N-acetyl monoethanolamine) 142-26-7

Benzyl benzoate 120-51-4 Benzyl salicylate 118-58-1 Butylphenyl methylpropional (Lillac-synthetic fragrance) 80-54-6

Compounds requested by the CARB staff for which mechanisms were not derived because their mechanisms are too uncertain to estimate Acetic acid benzyl ester 140-11-4 Benzophenone-3 131-57-7 Benzophenone-4 4065-45-6 Benzyl nicotinate 94-44-0 Beta-myrcene 123-35-3 Biotin (Vitamin H or B7) 58-85-5 Butetamate (Buteth-3) 14007-64-8 Butylparaben 94-26-8 Coumarin 91-64-5 Ethylparaben 120-47-8 Eugenol 97-53-0 Isobutylparaben 4247-02-3 Isoeugenol 97-54-1L-Cysteine (2-amino-3-sulfanylpropanoic acid) 52-90-4

Musk ketone 81-14-1 Musk xylene 81-15-2 Niacinamide (Vitamin B3) 98-92-0

Pantothenic acid (Vitamin B5) 79-83-4 Phenyl trimethicone (Methyl phenyl polysiloxane) 2116-84-9

Vanillin 121-33-5 Compounds requested by the CARB staff that are probably sufficiently low in volatility that they may not have significant ozone impacts. They probably should not be included in VOC emissions inventories. Adenosine triphosphate 56-65-5 Alpha Olefin sulfonate 68439-57-6 Ammonium benzoate 1863-63-4 Ascorbic acid (Vitamin C) 50-81-7 Di-2-ethylhexyl sebacate 122-62-3 Di- n -butyltin dilaurate 77-58-7Table 5 (continued)

32 Compound CAS No. Mechanism Derivation Method or Representation Dioctyl Sodium Sulfosuccinate 577-11-7 Ethylene diamine tetraacetic acid 60-00-4 Ethylhexyl salicylate (octyl salicylate) 118-60-5

Lauramide DEA 120-40-1 Mixed fatty acid methyl esters, C16 - C18 67762-38-3

Myristic acid (C14 fatty acid) 544-63-8 Octyl methoxycinnamate 5466-77-3 Oleic acid 112-80-1 Palmitic acid (C16 fatty acid) 57-10-3 Pyridoxine hydrochloride (Vitamin B6) 58-56-0

Sodium benzoate (Benzoic acid, sodium salt) 532-32-1

Sodium lauroyl sarcosinate (sodium salt (8CI)) 137-16-6

Sodium PCA (monosodium salt) 28874-51-3 Stearic acid 57-11-4 Compounds or mixtures requested by the CARB staff for which we were unable to determine the chemical composition or structure. Cedarwood (Cedrus Atlantica) Oil 68990-83-0

Chlorinated paraffin solvent 63449-39-8 4,4-(Oxydi-2,1-ethanediyl) bismorpholine 6425-39-4

Cocamide DEA 68603-42-9 Diethyltoluenediamine (DETDA) 68479-98-1

Dimethyl lauramine isostearate 70729-87-2 HFC-365mfc 406-58-6 Lauryl lactate 6283-92-7 MEA borate; monoethanolamine borate 68130-12-1

MIPA borate; monoisopropanolamine borate 68003-13-4

Panthenyl ethyl ether (N-(3-Ethoxypropyl)-2,4-dihydroxy3,3-dimethylbutyramide) 667-83-4

Soy methyl esters Trimethylolpropane trioleate 68002-79-9 Trimethylolpropane trioleate polyol ester 57675-44-233 

### RESULTS AND DISCUSSION

Summary of Experiments and Characterization Results

A chronological listing of the environmental chambe r experiments carried out for this project is given in Table B-1 in Appendix B. These included expe riments with the test compounds of interest for this study and appropriate characteri zation and control experiments needed for the data to be useful for mechanism evaluation. The results of the mechanis m evaluation experiments are discussed in the Mechanism Evaluation Results section, below. The ch aracterization results are discussed in the remainder of this section.

The results of the individual characterization expe riments that are relevant to the experiments for this project are summarized in the “Results” colu mn of Table B-1. The initial characterization experiments relevant this chamber are described in detail by Carter (2004) or by Carter and Malkina (2005) or Carter et al (2005b), and thus need not be discussed further here. Characterization results specific to this project are discussed below.

Blacklight Characterization

Because of problems with the arc light source during the period of this project, all of the experiments for this project were carried out using the blacklight light source. Methods for characterizing the intensity of the blacklight light source were di scussed by Carter et al (2005b), though some revisions were made as a result of subsequent measurements. As with the arc light source, NO 2 actinometry measurements were made using the quartz tube method of Zafonte et al (1977), modified as discussed by Carter et al (1995b), with the quartz tube both inside the reactors and also in front of the reactors. As discussed by Carter et al (2005b), the results of these measurements, and other measures of light intensity, indicated a steady decline in light intensity with ti me, with the results being best correlated with the “blacklight run count”, which is the number of e xperiments carried out in the chamber using theblacklights, and is thus an indicator of the ageing of the lights due to use. A plot of the results of the inand out-of-reactor actinometry measurements agains t run count for UCR EPA experiments carried out using the blacklight light source is shown on Figure 3.

The actinometry measurements made in front of the reactor as shown on Figure 3 are corrected by a factor of 0.698 to give an estimate of the corres ponding light intensity inside the reactor. As discussed by Carter et al (2005b), this was derived from near -simultaneous actinometry measurements made both inside and in front of the reactor. Both measurements show similar declines in intensity with time, though the measurements in front of the reactor are more comprehensive because of the larger number of measurements and the larger period of time for which measurements were made.

The actinometry measurements using the blacklight lights source are reasonably well fit by the following empirical expression, where k 1 is the NO 2 photolysis rate in min -1 :
k 1 = 0.0958 x [1 + exp(-Blacklight Run Count x 0.003914)] (I) The parameters in Equation (I) were derived to minimi ze sum-of-squares errors in predictions of both the in-reactor actinometry measurements and the in-front-of-reactor measure ments corrected by a factor of 0.698. This equation was used to derive the NO 2 photolysis rates used when modeling the blacklight experiments modeled for this project. Figure 3 indi cates the range of blacklight run counts that is applicable to the experiments for this project.34 0.10 0.12 0.14 0.16 0.18 0.20

0 100 200 300 400 Blacklight Run CountNO2 Photolysis Rate (min-1) In Reactor Measurements Enclosure Measurements (corrected)
Best fit to data Runs for this project

Figure 3. Plots of light intensity data used to assign NO 2 photolysis rates for the blacklight light

source.

The spectrum of the blacklights in this chamber has been measured periodically and continues to be essentially the same as the spectrum recommended by Carter et al (1995b) for modeling blacklight chamber runs.

Chamber Effects Characterization

Except as discussed below, the characterization resu lts for the more recent experiments for this project are consistent with those discussed by Cart er et al (2005b) and Carter and Malkina (2005, 2007), and the same characterization parameters were used for modeling. The most important chamber effect, and the only chamber effect parameter that was chan ged when modeling the experiments for this project, concerns the apparent HONO offgasing, which is believ ed to be responsible for both the chamber radical source and NO x offgasing effects (Carter, 2004). This is repr esented in the chamber effects model by the parameter RN-I, which is the HONO o ffgasing rate used in the simulations divided by the light intensity as measured by the NO 2 photolysis rate. Figure 4 shows the HONO offgasing parameters that best fit the radical or NO x - sensitive characterization experiments carried out in the UCR EPA during the period of the last three sets of reactors. Note that the experime nts carried out for this project start at run EPA777, so the applicable characterization data for this project is for the last set of reactors shown on the figure.

For the runs carried out for this project, which were all in the newest set of reactors installed after run 683, the RN-I value used for both reactors was 15 ppt, the average of the measured values for the applicable characterization runs. The values assigned for modeling the runs in the last three sets of reactors are indicated on Figure 4.

Side equivalency test experiments, in which the same mixture is irradiated in both reactors, are carried out periodically as controls for the incr emental reactivity experiments. Generally good side equivalency is observed for the gas-phase results, t hough sometimes one reactor is more favorable for particle formation than the othe r (Carter et al, 2005b). The results of the side equivalency test35 0 5 10 15 20 25

350 400 450 500 550 600 650 700 750 800

EPA Run NumberHONO Input Parameter (RN-I) (ppt) Radical sensitive (Side A)

Radical sensitive (Side B)

NOx sensitive (Side A)

NOx sensitive (Side B)

Used in Model (Side A)

Used in Model (Side B)

Replaced Reactors

Figure 4. Plots of best fit HONO offgasing parameters against UCR EPA run number.

experiment carried out during this project were simi lar, and are discussed below in conjunction with the incremental reactivity experiments with the added test compounds.

Background PM Characterization

Although the primary objective of this project was to obtain data on ozone impacts, particulate matter (PM) volume number measurements were made in conjunction with the experiments that were carried out. The results of the initial PM characteri zation experiments in this chamber were discussed by Carter et al (2005a,b). The most useful PM b ackground characterization experiments are pure air irradiations, where small but measurable PM formation is generally observed. This is apparently due to reaction of OH radicals with some PM precursor, since no PM formation is observed in CO - air or NO x - air irradiations, where the presence of the added CO or NO x tend to suppress the OH radical levels. Because of this, pure air irradiations continue to be carried out for the purpose of characterizing background PM levels, including experiments around th e time of the mechanism evaluation experiments for this project.

Plots of the 5-hour PM volume levels measured in this chamber since the time that routine PM measurements began are shown on Figure 5. (Data from runs with 5-hour PM volume of greater than 1.5 μg/m 3 , which includes some early runs in the first set of reactors; and run EPA796 carried out during this program, which appears to be anomalously contaminat ed, are not shown.) As discussed by Carter et al (2005a,b), for the first two sets of reactors the backgr ound PM level was consistently higher in Side A than in Side B, with the background in Side B being qu ite low. However, for the third set of reactors, the PM levels were essentially the same on both sides, at about the low range of the level of Side A in the previous sets of reactors. For the fourth set of react ors, those used for the runs for this project, the background PM levels were lower, being comparable to those found on Side B in the first two reactors, though the PM levels were somewhat lower on Side B than on Side A. This background PM level is small compared to that formed in the incremental experi ments with the added test compounds, and thus should not significantly alter conclusions of this study co ncerning relative PM impacts of the various compounds that were studied.365-Hour PM volume (ug/m3)

0.0 0.5 1.0 1.5

150 250 350 450 550 650 750 850
Run Number Side A Reactors Changed
Side B Runs for this project

Figure 5. Plots of 5-hour PM volume measuremen ts in pure air experiments the EPA chamber against EPA run number.

Gas-Phase Mechanism Evaluation Results

Table 6 lists the initial concentrations and selected gas-phase results for th e incremental reactivity experiments carried out for this project. For comp arison, the results of the side equivalency test experiment, which had no added reactants, are also shown. The measures of gas-phase reactivity used to evaluate the mechanisms in the incremental reactivity experiments ar e the effects of the test compound or solvent on ∆ ([O 3 ]-[NO]), or ([O 3 ] t -[NO] t )-([O 3 ] 0 -[NO] 0 ), and IntOH, the integrated OH radical levels. As discussed elsewhere (e.g., Johnson, 1983; Carter and Atkinson, 1987; Carter and Lurmann, 1991, Carter et al, 1993), ∆ ([O 3 ]-[NO]) gives a direct measure of the amount of conversion of NO to NO 2 by peroxy radicals formed in the photooxidation reactions, which is the process that is directly responsible for ozone formation in the atmosphere. This gives a useful measure of factors affecting O 3 reactivity even early in the experiments where O 3 formation is suppressed by the unreacted NO. Although this is the primary measure of the effect of the VOC on O 3 formation, the effect on radical levels is also a useful measure for mechanism evaluation, because radical levels affect how rapidly all VOCs present, including the base ROG components, react to form ozone.

The integrated OH radical levels are not measured directly, but can be derived from the amounts of consumption of reactive VOCs that react onl y with OH radical levels. In particular,

tracer t 0 t kOH Dt ) ] tracer [ ] tracer [ ln( IntOH −

= (II)

where [tracer] 0 and [tracer] t are the initial and time t concentra tions of the compound used as the OH tracer, kOH tracer is its OH rate constant, and D is the dilution rate in the expe riments. The latter is small in our chamber and is neglected in our analysis. For these experiments, the base ROG surrogate component

m -xylene is the most reactive compound in the experi ment that reacts only with OH radicals, and was therefore used as the OH tracer to derive the IntOH data. The m -xylene OH radical rate constant used in this analysis was 2.36x10 -11 cm 3 molec -1 s -1 (Atkinson, 1989).37 Table 6. Summary of initial concentrations and selected gas-phase results of the incremental reactivity experiments.

Test VOC Added (ppb) [b] Base Run Initial Concentrations Final O 3 (ppb) D([O 3 ]-[NO]) Change (ppb) IntOH Change Run Test Side Type [a] Calc Adj NO x (ppb) ROG (ppmC) Hours Light

[c] Test Base 2 Hr Final (ppt-min)

Side Equivalency Test 785 A MIR - 29 0.55 6 81 79 -2 2 2 AMP (calculated and adjusted amounts addded) 799 A MIR 64 20 28 0.56 5 32 64 -19 -35 -17 782 A MIR 525 30 29 0.60 5 16 61 -21 -51 -24 781 A MIR 536 25 29 0.50 5 14 48 -18 -42 -23 792 A MOIR/2 52 10 16 1.05 5 64 69 -31 -5 -6 789 B MOIR/2 53 25 25 1.15 5 72 104 -47 -32 -15 783 A MOIR/2 105 35 25 1.21 5 67 100 -53 -33 -12 784 A MOIR/2 105 40 25 1.08 5 59 100 -57 -40 -15 Ethanolamine (calculated and adjusted amounts added) 780 A MIR 100 70 33 0.50 3 71 24 42 50 1 790 A MIR 101 5 30 0.58 6 81 81 -1 -1 0 791 A MOIR/2 53 15 25 1.16 5 90 100 1 -11 -5 798 A MOIR/2 101 20 29 1.34 5 92 96 4 -7 -1 805 A MOIR/2 250 50 24 1.09 5 81 95 9 -16 -10 Isopropyl amine (calculated and adjusted amounts added) 807 A MOIR/2 252 100 22 1.18 6 106 97 34 9 -10

t -Butyl amine (calculated and adjusted amounts added) 806 A MOIR/2 251 140 22 1.09 5 13 95 -62 -86 -21

d -Limonene (measured amounts added) 797 A MIR 26 25 0.60 5 77 65 22 11 -10 793 A MIR 35 29 0.58 5 99 62 46 36 -5 804 A MOIR/2 23 19 1.08 6 83 89 10 -6 -4 [a] Codes for types of base case experiments for th e incremental reactivity experiments are as follows: “MIR”: ~30 ppb NO x and ~0.55 ppmC ROG surrogate; “MOIR/2”: ~25 ppb NO x and ~1.1 ppmC ROG surrogate. [b] For the amines, the initial concentrations calculate d from the amount of liquid injected are given in the "Calc" column, and the initial concentrations that gave the best fit of model simulations to the data are given in the "Adj" column. For d -limonene, the measured initial concentrations, which are consistent with the calculated amounts injected, are given. [c] Hours of irradiation for which O 3 and ∆ ([O 3 ]-[NO]) data are available.38 A series of d -limonene - NO x experiments were also carried out for the purpose of providing additional mechanism evaluation data for that compound . The results of those experiments are discussed in conjunction of the mechanism evaluation results for those compounds.

Amines

The amines whose ozone impacts were experi mentally studied for this project consisted primarily of 2-amino-2-methyl-1-propanol (AMP) and aminoethanol, though one experiment each was carried out for t -butyl amine and isopropyl amine. The first two were studied because they are important in consumer products inventories, wh ile the latter two were studied to pr ovide additional data to evaluate the general mechanism estimation approach. Conditions and selected gas-phase results of the incremental reactivity experiments are shown on Table 6 and expe rimental and calculated concentration-time plots for selected species are shown on Figure 6 and Figure 8 fo r AMP and on Figure 7 and Figure 9 for the other amines.

It was immediately apparent that AMP is a str ong inhibitor of the gas-phase reactions, since its addition caused a significant slowing of O 3 formation, NO oxidation and integrated OH radical levels in all experiments. This was also observed with t -butyl amine, but not for aminoethanol and isopropyl amine, both of which tended to e nhance rates of NO oxidation and O 3 formation (at least initially) in most experiments. The strong inhibition characteristics of AMP was not expected based on the initially estimated mechanisms that assumed that reactions at the amino group were unimportant, but is consistent with the mechanism derived in this work, as describ ed above. The inhibiting characteristics of AMP and
t -butyl amine are attributed to the fact that these compounds lack abstractable hydrogens in the position next to the amino group, which means that they have no significant radical propagation pathways available following the reactions of OH radicals with the amino group.

The estimated amine mechanisms developed in this work were qualitatively consistent with the results of the reactivity experiments, in that they predicted that AMP and t -butyl amine were strong inhibitors; while the other two had a generally positive effect on initial O 3 formation and NO oxidation rates, and relatively small effects on integrated OH levels.

However, quantitative mechanism evaluation usin g the amine experiments was complicated by the fact that we were unable to develop a useful quantitative gas-phase analysis method for amines for this project, so the amounts of amines injected in to the gas phase in these experiments could not be determined experimentally, and was therefore uncerta in. The amount of compound in the gas phase can be estimated from the measured amount of liquid injected, assuming complete injection of all the material, and loss of the materials on the wall. Th is approach has been su ccessfully employed in experiments with complex hydrocarbon mixtures such as petroleum distillates used in coatings (Carter and Malkina, 2005) and kerosene (Carter and Malkina, 2007). But if this is assumed in the case of the amines, then, as shown on Figure 6 and Figure 7, the model significantly overpredicts the effects of the amines on NO oxidation and O 3 formation in essentially all the amine experiments, both in a negative sense for AMP and t -butyl amine, and in a positive sense for aminoethanol and isopropyl amine. Although the possibility that this is due to mechanism problems cannot be completely ruled out, the much more likely explanation is that only a fraction of th e injected amine is making it to the gas phase in the experiments, the remainder being lost either to the walls of the reactors or to the injection lines. PM formation during injection is probably not playing an important role, since as discussed below no significant PM formation occurred in the added amine experiments until the irradiation began.

In order to obtain at least appr oximately satisfactory fits of model simulations to the chamber data, it is necessary to adjust the initial gas-phase amine concentration for each added amine experiment. The best fit concentrations are summarized on Table 6, and the results of the model calculations using39 EPA781A EPA782A EPA799A MIR MIR MIR
∆ (O 3 -NO) (ppm) vs Hour

IR ∆ (O 3 -NO) (mole basis) vs Hour

IR IntOH ( ppt-min/ppm ) vs Hour

EPA783A EPA784A EPA789B EPA792A MOIR/2 MOIR/2 MOIR/2 MOIR/2
∆ (O 3 -NO) (ppm) vs Hour

IR ∆ (O 3 -NO) (mole basis) vs Hour

IR IntOH ( ppt-min/ppm ) vs Hour 0.00 0.02 0.04 0.06 0.08

0123456

-0.16 -0.12 -0.08 -0.04 0.00 0.04

0123456

-50 -40 -30 -20 -10

0
0123456 0.00 0.02 0.04 0.06 0.08 0.10

0123456

-0.20 -0.15 -0.10 -0.05 0.00 0.05

0123456

-60 -40 -20

0 20

0123456 0.00 0.02 0.04 0.06 0.08 0.10

0123456

-1.2 -0.8 -0.4 0.0 0.4

0123456

-500 -400 -300 -200 -100

0
0123456

0.00 0.04 0.08 0.12

0123456

-1.0 -0.8 -0.6 -0.4 -0.2 0.0
0123456

-160 -120 -80 -40

0 40

0123456 0.00 0.04 0.08 0.12

0123456

-1.2 -0.8 -0.4 0.0 0.4

0123456

-200 -150 -100 -50

0 50

0123456 0.00 0.04 0.08 0.12

0123456

-1.6 -1.2 -0.8 -0.4 0.0 0.4

0123456

-400 -300 -200 -100

0 100

0123456 0.00 0.02 0.04 0.06 0.08 0.10

0123456

-2.0 -1.5 -1.0 -0.5 0.0 0.5

0123456

-400 -300 -200 -100

0 100

0123456 Base Experiment

Test Experiment

Base Calc

Test Calc (Adj. Amine Inj.)

Test Calc (All Amine Inj.)

Figure 6. Plots of selected experimental and cal culated incremental reactivity results for AMP.40 EPA791A EPA798A EPA805A EtOH-NH2 (MOIR/2) EtOH-NH2 (MOIR/2) EtOH-NH2 (MOIR/2)
∆ (O 3 -NO) (ppm) vs Hour

IR ∆ (O 3 -NO) (mole basis) vs Hour

IR IntOH ( ppt-min/ppm ) vs Hour 0.00 0.04 0.08 0.12

0123456

-0.4 -0.2 0.0 0.2 0.4 0.6

0123456

-200 -150 -100 -50

0 50

0123456 0.00 0.04 0.08 0.12

0123456

-0.2 0.0 0.2 0.4

0123456

-80 -40

0 40

0123456 0.00 0.04 0.08 0.12

0123456

-0.2 -0.1 0.0 0.1 0.2 0.3

0123456

-60 -40 -20

0 20

0123456 Base Experiment

Test Experiment

Base Calc

Test Calc (Adj. Amine Inj.)

Test Calc (All Amine Inj.)

EPA780A EPA790A EPA807A EPA806A EtOH-NH2 (MIR) EtOH-NH2 (MIR) IPR-NH2 (MOIR/2) TBU-NH2 (MOIR/2)
∆ (O 3 -NO) (ppm) vs Hour

IR ∆ (O 3 -NO) (mole basis) vs Hour

IR IntOH ( ppt-min/ppm ) vs Hour 0.00 0.04 0.08 0.12

01234

-0.4 0.0 0.4 0.8 1.2

01234

-20

0 20 40

01234 0.00 0.04 0.08 0.12

0123456

-0.4 0.0 0.4 0.8 1.2

0123456

-60 -40 -20

0 20 40

0123456 0.00 0.04 0.08 0.12

0123456

-0.2 -0.1 0.0 0.1 0.2 0.3

0123456

-120 -80 -40

0 40

0123456 0.00 0.04 0.08 0.12

0123456

-0.4 -0.3 -0.2 -0.1 0.0 0.1

0123456

-100 -80 -60 -40 -20

0
0123456

Figure 7. Plots of selected experimental and calculated incremental reactivity results for aminoethanol, isopropyl amine, and t-butyl amine.41 EPA799 (MIR) EPA792 (MOIR/2) Formaldehyde (ppm) vs Hour

0.000 0.002 0.004 0.006

0123456 0.000 0.004 0.008 0.012

012345 Base Experiment

Test Experiment

Base Calc

Test Calc (Adj. Amine Inj.)

Figure 8. Plots of experimental and selected calc ulated data for formaldehyde when measured in AMP experiments.

EPA791 (MOIR/2) Formaldehyde (ppm) vs Hour

0.000 0.005 0.010 0.015 0.020

012345 Test Experiment

Test Calc (Adj. Amine Inj.)

Figure 9. Plots of experimental and selected calcu lated data for formaldehyde in the ethanolamine experiment with useable formaldehyde data.

these adjusted initial concentrations are shown on Figur e 6 through Figure 9. Plots of the best fit initial concentrations against the initial concentrations cal culated from the amount of liquid injected are shown on Figure 10. The apparent amount of amine in th e gas phase ranged from 5% to ~60% of the amount injected, with the least squares fit ratio being 26%. Th e fact that there is no systematic trend for this fraction based on the compound, amount injected, or t ype of experiment suggests that this apparent incomplete injection is due to experimental variab ility, and not due to systematic problems with the mechanisms used in the model simulations. Th e higher apparent fractions injected for t -butyl and isopropyl amine compared to AMP and aminoethanol can be attributed to the expectation that the latter two compounds would be more "sticky" because they have hydroxyl as well as amino groups, which the former two compounds lack.

In any case, the fact that the initial reactant conc entrations had to be treated as an adjustable parameter in the model simulations in order to obtai n even approximately satisfactory fits of the model simulations to the data indicates that these data ar e not very good quantitative tests of the mechanism. The only conclusion that can be drawn is that the experiments are qualitatively consistent, or at least not inconsistent, with model predictions.42 0.00 0.05 0.10 0.15

0.0 0.2 0.4 0.6 Calculated based on volume liqued injected (ppm)"Best fit" initial concentration (ppm) AMP
Ethanolamine t-Butyl amine Isopropyl amine
5% line
26% line
60% line

Figure 10. Plots of initial amine concentrations that ga ve best fits to results of model simulations to concentrations calculated from the amount of liquid amine injected.

Figure 6 shows that if the initial AMP concentrati ons are adjusted, then the model simulates the ∆ ([O 3 ]-[NO]) and IntOH incremental reactivity r esults reasonably well. The good fits to the ∆ ([O3]-[NO]) at the initial states of the experiments can be attributed to the adjustment, but the ∆ ([O 3 ]-[NO]) data at the later stages of the experiments, and the IntOH data are also fit reasonably well. Similarly good simulations are also obtained for the t -butyl amine experiments as well, as shown on Figure 7.

For ethanolamine, Figure 7 shows that when the in itial amine concentration is adjusted so the model simulates the initial ∆ ([O 3 ]-[NO]) levels, the simulations of the ∆ ([O 3 ]-[NO]) later in the experiment and of the IntOH data are reasonably satis factory in the MIR experiments, but the simulations are not quite as good in the more NO x -limited MOIR/2 runs. In those runs, the added amine causes a slight reduction in O 3 yields at the end of the experiment, while the model predicts the impact is positive, and also the model tends to underpredict the IntO H reactivity. A similar result is observed for the ∆ ([O3]-[NO]) data for the isopropyl amine experiment, though in that case the IntOH reactivity data are reasonably well simulated. The tendenc y for these amines to reduce peak O 3 in NO x -limited experiments suggests that their reactions, or more likely the reactions of their oxid ation products, have NO x sinks that are not adequately represented in the current mechan ism. This may be due to the highly approximate representation of C=N products predicted to be formed from the reactions of amines with α C-H bonds.

This discrepancy in the predicti ons of the effects of ethanolamine and isopropyl amine on peak O 3 levels suggests that the current mechanism may underpredict the O 3 impacts of these compounds, and other non-inhibiting amines, under NO x -limited conditions. However, this should not necessarily result in biases in predictions of O 3 impacts in the MIR scale, whic h are based on conditions when NO x is in excess and are therefore generally insensitive to NO x sinks in the mechanisms for the compounds.

Figure 8 and Figure 9 show experimental and cal culated formaldehyde results for the few added amine experiments where formaldehyde measurement data were available. Note that the PTR-MS has not yet been quantitatively calibrate d for formaldehyde and the r esponse is based on theoretical considerations which have some uncertainties. Generally the results are consistent with model predictions43 that the impacts of AMP and aminoethanol on formalde hyde formation are relatively small. However, the formaldehyde data in run EPA799 suggests that the m odel may be somewhat overpredicting the effect of AMP on formaldehyde formation. In that experimen t, the formaldehyde levels observed in the added amine reactor was slightly lower than that in the base case reactor, while the model predicted a slight positive effect of AMP on the amine formation. Ho wever, the AMP mechanism (shown in Table A-1 in Appendix A) does not have formaldehyde as a direct product in any AMP reaction, so the slight formaldehyde overprediction is probably due to th e approximate representation used for the reactive products.

As discussed above, an uncertainty exists concer ning the importance of amine salt formation from the amine + HNO 3 reaction in removing the amines from availa bility for gas-phase reaction. To check its importance in the environmental chamber simulati ons, the added amine runs were modeled both by assuming that this reaction is negligible, and by usi ng the upper limit rate constant for the reaction and assuming it is irreversible. The only significant change caused by using the upper limit rate constant and irreversible removal is that the resulting calculation predicted that all the HNO 3 forms the salt. The changes in final calculated ∆ ([O 3 ]-[NO]) and IntOH caused by making alternative assumptions concerning amine salt formation were less than 3% for all the added amine experiments. This is because the amine present was in large exces s over the calculated amount of HNO 3 formed in the experiments, and the model assumes that, other than possi ble amine salt formation, the gas-phase HNO 3 is unreactive.

d -Limonene

The conditions and selected results of the incremental reactivity experiments with d -limonene are shown on Table 6, and plots of selected experimenta l and calculated data are shown on Figure 11. The model gives reasonabl y good simulations of ∆ ([O 3 ]-[NO]), IntOH, and d -limonene results of runs EPA793 and EPA804. The simulation of EPA797 is not quite as good, with the model predicting the approximate impact on ∆ ([O 3 ]-[NO]) but at a later time in the experiment, predicting a later time for most of the limonene consumption, a nd a somewhat lower magnitude of ∆ ([O 3 ]-[NO]) impact. However, these discrepancies can be attributed to the mechanism’s underpredictions of the rate of ∆ ([O 3 ]-[NO]) formation, as tends to be the case for the simulations of surrogate experiments at lower ROG/NO x levels (Carter, 2007a). If this is taken into acc ount, the simulation of the effects of the d -limonene addition can be considered to be reasonably satisfactory.

In addition to incremental reactivity experiments, several d -limonene - NO x experiments, without other added reactants, were also carried out for mechanism evaluation as part of this project. Limonene - NO x experiments were also carried out previously at higher concentrations in a smaller chamber (Carter et al, 1995b), and these results are also used for mechan ism evaluation in this work. The conditions and selected results of these and the previous experime nts are summarized on Table 7, and experimental and calculated results for selected gas-phase sp ecies are shown on Figur e 12 and Figure 13.

Figure 12 shows that the model gave very good simulations of the results of the d -limonene - NO x experiments carried out for this program, and genera lly good simulations of the experiments carried out previously, except perhaps for ETC451. The model predictions of the formaldehyde levels were reasonably consistent with the PTR-MS data in th e one new experiment with such data, especially considering the uncertainty in the calibration of this instrument. The model consistently underpredicted the formaldehyde in the earlier d -limonene - NO x experiments, though as discussed by Carter et al (1995b), the formaldehyde instrument used at the time tended to be unreliable and subject to biases. Despite the uncertainty in the calibration, the more recent PTR-MS formaldehyde data probably should be given the greater weight.44 EPA793A EPA797A EPA804A MIR MIR MOIR/2
∆ (O 3 -NO) (ppm) vs Hour

IR ∆ (O 3 -NO) (mole basis) vs Hour

IR IntOH ( ppt-min/ppm ) vs Hour

d-Limonene ( ppm ) vs Hour 0.00 0.04 0.08 0.12 0.16

0123456

-0.5 0.0 0.5 1.0 1.5 2.0

0123456

-200 -100

0 100

0123456 0.00 0.04 0.08 0.12

0123456

-0.4 0.0 0.4 0.8 1.2 1.6

0123456

-600 -400 -200

0 200

0123456 0.00 0.04 0.08 0.12

0123456

-0.8 -0.4 0.0 0.4 0.8

0123456

-400 -200

0 200

0123456 Base Experiment
Test Experiment

Base Calc

Test Calc

0.00 0.01 0.02 0.03 0.04

0123456 0.00 0.01 0.02 0.03

0123456 0.000 0.005 0.010 0.015 0.020 0.025

0123456

Figure 11. Plots of selected experimental and calculated incremental reactivity results for d -limonene.

In view of the generally satisfa ctory performance of the existing d -limonene mechanism in simulating the current and previous chamber data, no modifications were made to the mechanism for that compound as part of this project.

PM Impact Results

The PM volume measurement data taken during the incremental re activity experiments for this program are shown on Figure 14, and selected PM r esults from these experiments, and also the side equivalency test experiment, are summarized on Table 8. In addition, the maximum PM volume levels in the d -limonene - NO x experiments carried out for this project are included in Table 7, above.

These results show that, with the possible exception of t -butyl amine, all the compounds studied for this project have large, positive impacts on PM formation under simulate d atmospheric conditions.45 Table 7. Summary of conditions and selected results of the d -limonene NO x experiments.

Initial Conc (ppm) Ozone (ppb) Run Limonene NO x 2 Hr. 5 Hr Max PM ( μ g/m 3 )
Previous Experiments [a] ETC425 0.30 0.25 279 387 ETC450 0.27 0.24 295 410 ETC451 0.26 0.57 22 117 ETC452 0.27 0.16 317 374 Experiments for this project EPA794B 0.15 0.096 140 168 289 EPA795A 0.32 0.139 144 176 681 EPA795B 0.15 0.107 131 167 227 [a] See Carter et al (1995b) for a discussion of the conditions and modeling methods for these experiments, which were carried out in the ETC ch amber, which consists of a ~4000-liter collapsible Teflon bag with a blacklight light source with a light intensity corresponding to an NO 2 photolysis rate of 0.35 min -1 . These runs were modeled using the chamber effects model for the ETC runs as given by Carter et al (1995b) except with a HONO input parameter, RN-I of 40 ppt. No PM data were taken during these experiments.

Note that for the amines, the PM levels at the be ginning of the experiments are relatively low (see Figure 14), indicating that the amine itself is not significan tly partitioning into the aerosol phase, and aerosol formation does not contribute significantly to the discr epancy between the amount of amines injected and the apparent amount of amine reacting in the gas phase. The PM formation must be due to either amine salt formation from reaction with the HNO 3 formed in the gas-phase reactions, or condensation or heterogeneous reactions of oxidation products, or (most likely) both.

For the purpose of comparing PM impacts of diffe rent compounds, it is useful to derive a "PM Incremental Reactivity", which is defined as the mass of PM formed (derived from the PM volume assuming the PM has the density of water) divi ded by the mass of VOC initially present in the experiments. This normalizes for differences in amounts of VOC injected in the different experiments. In the case of the amines, the "initially present" amount in this context was taken as the calculated amount injected, since even if all the amount injected did not participate in the gas phase reaction it may possibly have contributed somehow to PM formation. These PM incremental reactivity values derived from the 5- hour PM volume values measured for the various experi ments are given in Table 8, and the averages of these values for the different compounds are summarized on Table 9.

For comparison with other VOCs, Table 9 also gives the average 5-hour PM incremental reactivities obtained from studies of other compounds and mixtures in this chamber in these types of incremental reactivity experiments. These include coa tings VOCs studied by Carter et al (2005b) and pesticide VOCs studied by Carter and Malkina (2007) . The compounds are listed in order of increasing PM incremental reactivity.

Table 9 shows that except for t -butyl amine, which had a moderately low relative PM impact in the one experiment with this compound, the compounds studied for this project are among the highest in46 EPA794B EPA795A EPA795B Ozone (ppm) vs time (minutes)

NO(ppm) vs time (minutes)

d-Limonene (ppm) vs time (minutes) 0.00 0.05 0.10 0.15 0.20

0 120 240 360 0.00 0.05 0.10 0.15 0.20

0 120 240 360 0.00 0.05 0.10 0.15 0.20

0 120 240 360

0.00 0.02 0.04 0.06 0.08

0 120 240 360 0.00 0.04 0.08 0.12 0.16

0 120 240 360 0.00 0.02 0.04 0.06 0.08 0.10

0 120 240 360

0.00 0.04 0.08 0.12 0.16

0 120 240 360 0.0 0.1 0.2 0.3 0.4

0 120 240 360 0.00 0.04 0.08 0.12 0.16

0 120 240 360 Experimental

Calculation

ETC425 ETC450 ETC451 ETC452 Ozone (ppm) vs time (minutes)

NO(ppm) vs time (minutes)

d-Limonene (ppm) vs time (minutes) O3

0.0 0.1 0.2 0.3 0.4

0 120 240 360 O3

0.0 0.1 0.2 0.3 0.4

0 120 240 360 O3

0.0 0.1 0.2 0.3 0.4

0 120 240 360

NO

0.00 0.05 0.10 0.15 0.20 0.25

0 120 240 360 NO

0.00 0.05 0.10 0.15 0.20

0 120 240 360 NO

0.0 0.1 0.2 0.3 0.4 0.5

0 120 240 360 NO

0.00 0.04 0.08 0.12 0.16

0 120 240 360 O3

0.00 0.04 0.08 0.12 0.16

0 120 240 360

D-LIMONE

0.0 0.1 0.2 0.3 0.4

0 120 240 360 D-LIMONE

0.0 0.1 0.2 0.3

0 120 240 360 D-LIMONE

0.0 0.1 0.2 0.3

0 120 240 360 D-LIMONE

0.0 0.1 0.2 0.3

0 120 240 360

Figure 12. Plots of selected experimental and calcula ted data for the d-limonene experiments carried out for this program (EPA runs) and previously (ETC runs).47 EPA795A Formaldehyde (ppm) vs time (minutes)

FORMALD

0.00 0.02 0.04 0.06

0 120 240 360 Experimental

Calculation

ETC425 ETC450 ETC451 ETC452 Formaldehyde (ppm) vs time (minutes)

FORMALD

0.00 0.04 0.08 0.12 0.16

0 120 240 360 FORMALD

0.00 0.04 0.08 0.12 0.16

0 120 240 360 FORMALD

0.00 0.04 0.08 0.12 0.16

0 120 240 360 FORMALD

0.00 0.04 0.08 0.12 0.16

0 120 240 360

Figure 13. Plot of experimental and calculated formaldehyde data for the d -limonene - NO x experiments where formaldehyde data are available.

terms of PM formation potential of the compounds studied. The highest PM formation was from d

limonene and ethanolamine, which were essentially the same to within the experimental variability. The inhibiting amines (AMP and t -butyl amine) were the least reactive of the amines studied, presumably in part because they inhibited the overall photooxidation pr ocesses, including the rate at which they reacted, and were calculated not to react to completion in these experiments. These may have higher relative PM formation potentials under more phot ochemically reactive conditions.

It should be noted that the relative PM formati on potentials summarized in Table 9 are applicable only for the conditions of these experiments, and the magnitudes, and even the ordering, of the incremental reactivities may be different in atmosphe ric conditions. The ultimate utility of these data will be to provide tests for model predictions of PM formation from these compounds, once mechanisms for this purpose have been developed. However, de veloping mechanisms for predicting quantitative PM impacts of these compounds was beyond the scope of this program.

Atmospheric Reactivity Calculations

The atmospheric incremental reac tivities calculated for the amines and other compounds added to the SAPRC-07 mechanism for this project are give n on Table 10. Table C-1 in Appendix C gives the complete tabulation of VOCs and reactivity values fo r the SAPRC-07 mechanism, with values for these compounds studied for this project added or updated. Table C-1 also gives codes indicating generally how these VOCs are represented in the mech anism, the availability of rate c onstant and experimental data for the compounds or mixtures, and uncertainty codes for the mechanisms and atmospheric reactivity estimates. The reactivity values and codes Table C-1 replace those given in the initial SAPRC-07 documentation, dated August 31, 2007 for the compounds st udied in this project. [The values for the other compounds are unchanged, except that methyl iodide, st udied by Carter (2007b), has also been added.]48 Table 8. Selected results of PM number and volume measurements made during the incremental reactivity experiments carried out for this project.

5-Hour PM Number (10 3 /m 3 ) 5-Hour PM Vol. ( μ g/m 3 ) Run Test Side Type [a] Test Cmpd added (ppb) [b] Test Base Test Base 5 Hr. PM Vol. Incr'l Rct'y [c]
Side Equivalency Test
785 A MIR - 2 2 3.1 0.0 -

AMP
799 A MIR 64 6 3 12.9 0.1 55 782 A MIR 525 16 4 1.3 0.1 1 781 A MIR 536 17 0 1.6 0.0 1 792 A MOIR/2 52 13 11 20.0 0.7 103 789 B MOIR/2 53 6 14 26.4 0.7 133 783 A MOIR/2 105 12 3 26.5 2.6 63 784 A MOIR/2 105 9 13 23.3 0.7 59

Ethanolamine 780 A MIR 100 No 5 hour data - short run 790 A MIR 101 7 2 38.4 0.1 153 791 A MOIR/2 53 15 11 47.5 0.6 356 798 A MOIR/2 101 12 8 62.9 0.6 248 805 A MOIR/2 250 23 4 95.7 0.3 154 Isopropyl amine 807 A MOIR/2 252 8 9 47.6 0.4 78

t -Butyl amine 806 A MOIR/2 251 5 9 5.6 0.6 7

d -Limonene
797 A MIR 26 9 7 36.8 0.5 256 793 A MIR 35 12 1 34.5 0.1 177 804 A MOIR/2 23 14 6 28.8 0.2 225 [a] See footnotes to Table 6. [b] For amines this is the calculated initial concentr ation based on the volume of liquid amine injected. Note that if the amount injected that gave the best fits of the model simulations to the ozone reactivity data were used then the PM volume in cremental reactivity would be higher. [c] PM volume incremental reactivity is in units of μg PM formed per milligram of VOC added. Calculated as the 5-hour PM volume on the test side minus the PM volume in the base case experiments, divided by the amount of mg/m 3 test compound added.49 EPA781A EPA782A EPA799A AMP (MIR) AMP (MIR) AMP (MIR) PM Volume ( μ g/m 3 ) vs Hour

EPA783A EPA784A EPA789B EPA792A AMP (MOIR/2) AMP (MOIR/2) AMP (MOIR/2) AMP (MOIR/2) 0.0 0.5 1.0 1.5 2.0

0123456 0 1 2 3

0123456 0 5 10 15 20 25

0123456

0 10 20 30

0123456 0 10 20 30

0123456 0 10 20 30

0123456 0 5 10 15 20 25

0123456 Base Experiment

Test Experiment

EPA791A EPA798A EPA805A EtOH-NH2 (MOIR/2) EtOH-NH2 (MOIR/2) EtOH-NH2 (MOIR/2)

0 20 40 60

0123456 0 20 40 60 80

0123456 0 40 80 120

0123456 EPA780A EPA790A EPA807A EPA806A EtOH-NH2 (MIR) EtOH-NH2 (MIR) IPR-NH2 (MOIR/2) TBU-NH2 (MOIR/2)

0 20 40 60 80

01234 0 10 20 30 40 50

0123456 0 20 40 60

0123456 0 2 4 6 8 10

0123456

EPA793A EPA797A EPA804A Limonene (MIR) Limonene (MIR) Limonene (MOIR/2)

0 10 20 30 40 50

0123456 0 10 20 30 40 50

0123456 0 10 20 30 40

0123456

Figure 14. Plots of PM volume data from all of th e incremental reactivity experiments carried out for this project.50 Table 9. Summary of average 5-hour PM volu me incremental reactivities of VOCs studied in incremental reactivity experiments in the UCR EPA chamber.

Compound or Mixture Average 5-Hour PM IR [a] Project [b]

1,2-Dichloropropenes Low Pesticide Propylene glycol Low Coatings Ethylene glycol Low Coatings Texanol isomers Low Coatings Synthetic isoparaffinic mixture (ASTM-3C1) Low Coatings Carbon disulfide 6±1 Pesticide

t -Butyl amine ~7 This work Petroleum distillates (coatings study) 8±3 Coatings S-ethyl dipropylthiocarbamate (EPTC) 11±3 Pesticide Methyl isothiocyanate 11±5 Pesticide 2-(2-Butoxyethoxy)-ethanol 34±11 Coatings Kerosene 41±9 Pesticide 2-Amino-2-methyl-1-propanol 59±49 This work Isopropyl amine ~78 This work Benzyl alcohol 92±7 Coatings d -Limonene 219±40 This work Ethanolamine 228±97 This work [a] PM volume incremental reactivity is in units of μg PM formed per milligram of VOC added. Calculated as the 5-hour PM volume on the test side minus the PM volume in the base case experiments, divided by the amount of mg/m 3 test compound added. "Low" means the PM volume in the added test compound experiment was either lower or not significantly different than in the base case experiment. If no standard deviation is given th en useful data are available for only a single experiment, and the value must be considered to be uncertain by at least ± 50%. [b] Project for which this compound was studied; cons ult the project report for details: "Coatings": data from Carter et al (2005b); "Pesticide": data from Carter and Malkina (2007); "This work": see Table 8.

The online SAPRC-07 mechanism docu mentation and reactivity scales available at http://www.cert.ucr .edu/~carter/SAPRC have been updated accordingly.

As discussed above, there is a significant uncertain ty as to how to represent the possible loss of amines due to reaction with HNO 3 to form the amine salts in the atmospheric ozone impact simulations. Figure 15 shows plots of amine reactivities calculated assu ming that this reaction is fast and irreversible, against those calculated assuming that the reaction is unimportant. It can be seen that, unlike the simulations of the chamber experime nt, alternative assumptions in this regard have a significant impact on the O 3 reactivity results, with the magnitudes of the ozone impacts of the amines generally being at least an order of magnitude lower if the reaction is assumed to be fast and irreversible. For some of the lower reactivity amines, the low NO x reactivities (reactivities in some base case and EBIR scenarios) go from positive to negative, which is pr obably due to the removal of NO x sources in the mechanism due to the reactions of HNO 3 . The difference between these and the ch amber simulations comes from the fact that in the chamber simulations, the amine is in large excess, while in these atmospheric reactivity51 Table 10. Calculated atmospheric reactivity va lues for amines and other compounds added to the atmospheric reactivity tabulations.

Reactivity (gm O 3 / gm VOC) Compound CAS No. MIR MOIR EBIR Avg Base

` Amines [a] Methylamine 74-89-5 7.25 4.04 2.60 3.57±1.09 Dimethyl amine 124-40-3 2.65 1.84 1.33 1.61±0.56 Ethyl amine 75-04-7 5.45 2.97 1.91 2.63±0.80 Trimethyl amine 75-50-3 5.27 2.75 1.81 2.48±0.74 Isopropylamine 75-31-0 6.97 3.26 2.06 2.97±0.96
t -Butyl amine 75-64-9 -3.26 -1.06 -0.44 -0.99±0.70 Triethyl amine 121-44-8 3.07 1.48 0.91 1.31±0.44 Triethylene diamine 280-57-9 2.77 1.33 0.82 1.18±0.40 Ethanolamine 141-43-5 6.59 2.99 1.85 2.72±0.92 Dimethylaminoethanol 108-01-0 5.15 2.21 1.40 2.05±0.69 2-Amino-1-butanol 96-20-8 4.79 2.14 1.31 1.95±0.67 2-Amino-2-methyl-1-propanol 124-68-5 -2.68 -0.80 -0.30 -0.76±0.62 Diethanol amine 111-42-2 2.22 1.08 0.70 0.98±0.32 Triethanolamine 102-71-6 3.25 1.37 0.81 1.25±0.46 Triisopropanolamine 122-20-3 1.99 0.96 0.60 0.86±0.29 Other Compounds Terpinolene 586-62-9 6.14 2.21 1.17 2.09±1.08 Tripropylene glycol 24800- 44-0 2.07 1.04 0.64 0.92±0.31 Diethylene glycol mono(2-ethylhexyl ) ether 1559-36-0 1.45 0.75 0.42 0.64±0.24 Tripropylene glycol n -butyl ether 55934-93-5 1.55 0.75 0.43 0.65±0.24 Triethyl citrate 77-93-0 0.66 0.31 0.16 0.26±0.11 2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 0.33 0.20 0.06 0.14±0.09

Citronellol (3,7-dimethy-6-octen-1-ol) 106-22-9 5.80 2.05 1.12 1.94±0.96 Linalool 78-70-6 5.44 1.96 1.09 1.85±0.90 Geraniol 106-24-1 5.10 1.88 1.06 1.78±0.85 Hexyl cinnamal 101-86-0 2.93 1.08 0.64 1.03±0.41 Hydroxycitronellal 107-75-5 2.54 1.02 0.61 0.94±0.34 Cinnamic aldehyde 104-55-2 4.79 1.77 1.05 1.68±0.68 Amyl cinnamal 122-40-7 3.13 1.16 0.69 1.10±0.44 4-Vinylphenol 2628-17-3 1.44 0.16 -0.41 -0.01±0.45 Methylparaben (4-hydroxy-benzoic acid, methyl ester) 99-76-3 1.70 0.10 -0.55 -0.04±0.54

Propylparaben 94-13-3 1.44 0.08 -0.47 -0.03±0.45 2,6-Di- tert -butyl- p -cresol 128-37-0 1.18 0.07 -0.38 -0.02±0.37 Beta-phenethyl alcohol 98- 85-1 4.49 1.57 0.76 1.44±0.72 Cinnamic alcohol 104-54-1 0.83 0.10 -0.29 -0.03±0.27 Anethol 104-46-1 0.75 0.09 -0.26 -0.03±0.24 2-Ethylhexyl benzoate 5444- 75-7 0.92 0.42 0.18 0.34±0.17 1-Nitropropane 108-03-2 0.20 0.15 0.11 0.13±0.03 Ethyl methyl ketone oxime 96-29-7 1.55 1.32 1.45 1.40±0.30 Lauryl pyrrolidone 2687-96-9 0.89 0.45 0.27 0.40±0.14Table 10 (continued)

52 Reactivity (gm O 3 / gm VOC) Compound CAS No. MIR MOIR EBIR Avg Base

` o -Dichlorobenzene 95-50-1 0.17 0.02 -0.04 0.01±0.05 2-Chlorotoluene 95-49-8 2.86 1.00 0.40 0.88±0.50 Methyl nonafluorobutyl ether 163702-07-6 0.05 0.04 0.03 0.04±0.01 Methyl nonafluoroisobutyl ether 163702-08-7 0.05 0.04 0.03 0.04±0.01 Ethyl nonafluorobutyl ether 163702-05-4 0.19 0.12 0.08 0.11±0.03 Ethyl nonafluoroisobutyl ether 163702-06-5 0.19 0.12 0.08 0.11±0.03 [a] Reactivities calculated assuming no loss of amine by reaction with HNO 3 . See Figure 15 for results of calculations assuming rapid and irreversible loss of amines by reaction with HNO 3 .

-0.2 0.0 0.2 0.4 0.6

-4 -2 0 2 4 6 8 Reactivity if no HNO 3 Reaction (gm O 3 / gm amine)Reactivity if fast HNO3 reaction Base
MIR MOIR
EBIR Slope = 0.064

Figure 15. Plots of incremental reactivities of amin es for the various types of atmospheric reactivity scenarios calculated assuming rapid and irreversible loss by reaction with HNO 3 against incremental reactivities calculated assuming no reaction with HNO 3 .

scenarios, where the incremental effects of sm all VOC additions are being calculated, the HNO 3 is in excess and consumes most of the amine if the amine sa lt reaction is assumed to be fast and irreversible.

For regulatory purposes, we recommend that the amine reactivities in the maximum incremental reactivity (MIR) scale be calculated based on assuming no significant loss of amines by reaction with HNO 3 , as may occur in environments where there are significant other sinks for HNO 3 , such as reaction with ammonia, other amines, or heterogeneous loss pr ocesses, or if the equilibrium favors dissociation of the amine salt in the environment under consideration. This would represent the impact of the amines under conditions where they would have the maximum oz one impact, which is cons istent with the general concept of maximum incremental re activity (Carter, 1994a). Therefore, the amine reactivity values given in Table 10 and Table C-1 are based on assuming no loss of the amine by reaction with HNO 3 . Footnotes53 for the amines in Table C-1 indicate that the tabu lated values should be considered upper limits in magnitude.

Table 11 gives the previous estimates of MIR or upper limit MIR values for th e amines as a result of this work. The values in the middle column were from the most recent update of the SAPRC-99 tabulation given by Carter (2003) and are based on calculations using highly a pproximate "placeholder" mechanisms as discussed by Carter (2000a). For most amines for which reactivity values were available in the previous tabulations the new MIR's are somew hat lower, and in the case of AMP the previous estimate was positive, while the current mechanism (and chamber data) indicate it is an ozone inhibitor. For most amines, the reactivity va lues used for regulatory purposes were the upper limit values derived using the method given in Appendix D of the SAPR C-99 documentation, which are also shown on Table 11. It can be seen that these upper limit values are signifi cantly higher than the current estimates, in most cases by more than a factor of two. Therefore, ozone impacts estimates for most amines have declined as a result of this work.

Table 11. Change in MIR values assigned to amines as a result of this work.

Compound MIR (gm O 3 / gm VOC) [a] This work SAPRC-99 [b] Upper Limit [c] Methylamine 7.25 10.8 (-33%) Dimethyl amine 2.65 9.4 (-72%) 14.9 (-82%) Ethyl amine 5.45 7.8 (-30%) 14.9 (-63%) Trimethyl amine 5.27 7.1 (-25%) 17.1 (-69%) Isopropylamine 6.97 17.1 (-59%)
t -Butyl amine -3.26 18.4 (negative) Triethyl amine 3.07 16.6 (-81%) Triethylene diamine 2.77 15.0 (-81%) Ethanolamine 6.59 6.0 (+11%) 11.0 (-40%) Dimethylaminoethanol 5.15 4.8 (8%) 15.1 (-66%) 2-Amino-1-butanol 4.79 15.1 (-68%) 2-Amino-2-methyl-1-propanol (AMP) -2.68 4.8 (negative) 15.1 (negative) Diethanol amine 2.22 4.0 (-45%) 12.8 (-83%) Triethanolamine 3.25 2.8 (+18%) 11.3 (-71%) Triisopropanolamine 1.99 8.8 (-77%) [a] Value in parentheses is change relative to the tabulated value as a result of this work. [b] From tabulation of Carter (2003) [b] Upper limit MIR calculated using the procedure of Appendix D in the SAPRC-99 documentation (Carter, 2000a).54 

### DISCUSSION AND CONCLUSIONS

This project made significant progress towards achieving its objectives of decreasing uncertainties and improving estimates of ozone impacts of c onsumer product compounds of interest to the CARB. Ozone impact estimates and MIR values were derived for a total of 7 amines and 30 other compounds present in consumer products inventories fo r which estimates were not previously available, ozone impact estimates and MIR values for 8 amines we re significantly improved, and data were obtained to support the predictive capabilities of the previously derived mechanism for d -limonene. The major contribution of this project concerned the devel opment of improved methods for estimating mechanisms for calculating ozone impact estimates for amines , which were previously represented using highly approximate "placeholder" mechanisms, or for whic h only upper limit ozone impact estimates were available. As a result of this project, the estimated ozone impacts of amines appropriate for regulatory applications are much lower than th e upper limit values used previously.

One unexpected result of this project is that certain types of amines, those that lack abstractable hydrogens adjacent to the amino groups, were f ound to have negative impacts on ozone formation, contrary to previous estimates. The most important exam ple of this is AMP, which was one of the priority consumer product compounds chosen for study in this project. This inhibition is explainable by the current estimated mechanisms, and supported by the environmental chamber experiments with AMP and
t -butyl amine, another example compound of this type . The chamber experiments with aminoethanol and isopropyl amine support the predictions of the cu rrent mechanisms that these compounds have positive impacts on ozone formation, though their impact s are lower than previous upper limit estimates.

On the other hand, this project was not totally successful in reducing uncertainties in mechanisms and ozone impact estimates of amines to the level ob tained for other compounds that have been studied previously. Although the experiments carried out for th is project were useful in testing mechanisms in a qualitative sense, particularly for determining wh en compounds are inhibitors as opposed to having positive impacts of ozone formation, they were not particularly useful for quantitative mechanism evaluation. This is because amines ar e extremely "sticky" compounds that are difficult to reliably inject or monitor in the gas phase, and attempts to develo p methods to quantitatively monitor these compounds in the gas phase were unsuccessful. The results of the experiments could not be satisfactorily simulated using reasonable mechanisms unless it is assumed that onl y a fraction of the injected amines are available for reaction in the gas phase, and the amount of amin e reacting in the gas phase had to be treated as an adjustable parameter. Because this adjustment coul d mask errors in the mechanism, this means that the data obtained cannot fully test the mechanism. Methods need to be developed to quantitatively inject and monitor these compounds in the gas phase before quan titative data can be obtain ed to comprehensively evaluate the mechanisms for these compounds.

On the other hand, the data obtained were suffici ent to evaluate the predictive capabilities of the mechanisms concerning general reactivity trends, a nd for the most part the data did not indicate systematic problems with the estimated mechanisms. Th e one exception is that the estimated mechanisms did not correctly predict the tendency of the positiv ely reactive amines (aminoethanol and isopropyl amine) to cause a slight decrease in O 3 formation under NO x -limited conditions. This is attributable to uncertainties and approximations in the mechanism concerning the representation of reactive products, such as compounds with C=N bonds, in the model. Th is aspect of the amine mechanisms needs to be improved, though how to improve model performance in th is respect is presently unclear. However, this ozone overprediction bias under NO x -limited conditions should not signifi cantly affect predictions of MIR values, which reflect ozone impacts under conditions when NO x is in excess.55 An even more significant problem concerning qua ntitative predictions of ozone impacts of amines concerns its possible removal by reaction with HNO 3 , forming non-volatile amine salts. HNO 3 is an important NO x sink species formed under conditions where O 3 formation occurs, so its reactions need to be taken into account. Amines are basic compounds a nd are known to rapidly form amine nitrate salts, which partition into the aerosol phase, when injected into environmental chambers in the presence of HNO 3 under atmospheric conditions (Murphy et al, 2007). Ho wever, these will also dissociate back to the amines and HNO 3 , and evidence for this dissociation is also observed, though the equilibrium constants are highly uncertain (Murphy et al, 2007). If this pr ocess is not important in affecting results of the chamber experiments carried out for this work b ecause the injected amine is in large excess over the HNO 3 formed in the photooxidation reactions, it is calculated to be extremely important under atmospheric conditions. In particular, if the reactions of HNO 3 with amines are rapid and irreversible, then the magnitudes of the incremental reactivity va lues for these compounds are calculated to be an order of magnitude or more less than is the case if the reaction is assumed to be negligible.

It is extremely uncertain how to represent the amine + HNO 3 reaction in the atmospheric reactivity scenarios because its importance is highl y sensitive to atmospheric sources and sinks for ammonia, other amines and HNO 3 , which have highly variable levels that are in most cases unknown. For regulatory purposes, we recommend that values u sed for Maximum Incremental Reactivity (MIR) be based on conditions where they would have the maxi mum ozone impact, which is consistent with the general concept of maximum incre mental reactivity (Carter, 1994a). For this reason, the tabulated MIR and other reactivity values are based on assuming that the reaction with HNO 3 is negligible. However, the magnitudes of their actual impacts will probably be l ess than these under real atmospheric conditions. If it is desired to derive reactivity valu es for amines that are more representa tive to their atmospheric impacts, then appropriate methods to represent sources and sinks for basic pollutants (HNO 3 , ammonia, amines, etc.), need to be derived for use in atmospheric react ivity scenarios. This requires a major research effort that is beyond the scope of this project.

In addition to amines, data were also obtained to better evaluate ozone impact mechanisms for d

limonene, an important compound in consu mer products emissions. In the case of d -limonene, mechanism evaluation experiments were limited to limonene - NO x experiments carried out with relatively high reactant concentrations, and the predictive capabilities of th e mechanism had not been tested under conditions more representative of the atmo sphere. The new experiments carried out for this project addressed the need for better data to eval uate the mechanism for this important compound, but since the mechanism performed well in simulating these data, no need to change the mechanism was indicated.

Mechanisms and reactivity estimates were also derived for 30 other compounds found in consumer product inventories for which estimates were not previously available. However the CARB staff had also requested reactivity estimates for a total of 63 other compounds for which reactivity estimates are still needed. Of these, 4 are probably of negligible reactivity and 20 are probably nonvolatile, leaving 39 compounds for which reactivity estim ates are actually needed. In some of these cases the chemical structures could not be determined bu t in others the mechanisms are too uncertain to estimate, while for other estimates could be made if more time and resources were available. Additional work in this area may be appropriate if the missing estimates remain problematic for the CARB.

Although the primary focus of this project was reducing uncertainties in ozone impact estimates, data were also obtained concerning the relative PM formation potentials for AMP, ethanolamine, and d

limonene. All three of these compounds were found to ha ve very high PM formation potentials compared to most of the coatings VOCs (Carter et al, 2005 b) and pesticide VOCs (Carter and Malkina, 2007) studied previously. The data obtained should be usef ul for testing mechanisms for PM formation of these compounds, and work in this area is needed.56 

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### APPENDIX A. MECHANISM LISTING

Table A-1. Reactions and rate constants used for amines, d -limonene, and the new compounds added to the mechanism for this project.

Reaction Rate [a] Compound Expression Ref Reactions

Methylamine 1.97e-11 1 ME-AMINE + OH = #.458 HO2 + #.542 RO2C + #.458 PROD2 + #.542 xHO2 + #.542 xPROD2 + #.542 yROOH + XN + #-5 XC 7.40e-21 2 ME-AMINE + O3 = OH + RO2C + xHO2 + xPROD2 + yROOH + #-5 XC + XN 9.60e-14 e1 ME-AMINE + NO3 = HNO3 + #.458 HO2 + #.542 RO2C + #.458 PROD2 + #.542 xHO2 + #.542 xPROD2 + #.542 yROOH + #-5 XC + XN 4.00e-11 e2 ME-AMINE + HNO3 = XC + XN Dimethyl Amine 6.52e-11 1 DM-AMINE + OH = #.243 HO2 + #.514 RO2C + #.243 PROD2 + #.514 xHO2 + #.514 xPROD2 + #.514 yROOH + XN + #-2.542 XC 1.67e-18 2 DM-AMINE + O3 = OH + RO2C + xHO2 + xPROD2 + yROOH + #-4 XC + XN 2.03e-13 e1 DM-AMINE + NO3 = HNO3 + #.244 HO2 + #.512 RO2C + #.244 PROD2 + #.512 xHO2 + #.512 xPROD2 + #.512 yROOH + #-2.537 XC + XN 4.00e-11 e2 DM-AMINE + HNO3 = #2 XC + XN Ethyl Amine 2.58e-11 1 ET-AMINE + OH = #.485 HO2 + #.515 RO2C + #.485 PROD2 + #.515 xHO2 + #.515 xPROD2 + #.515 yROOH + XN + #-4 XC 1.98e-20 e3 ET-AMINE + O3 = OH + RO2C + xHO2 + xPROD2 + yROOH + #-4 XC + XN 1.16e-13 e1 ET-AMINE + NO3 = HNO3 + #.508 HO2 + #.492 RO2C + #.508 PROD2 + #.492 xHO2 + #.492 xPROD2 + #.492 yROOH + #-4 XC + XN 4.00e-11 e2 ET-AMINE + HNO3 = #2 XC + XN Trimethyl Amine 4.84e-11 1 TM-AMINE + OH = RO2C + xHO2 + xPROD2 + yROOH + XN + #-3 XC 7.84e-18 2 TM-AMINE + O3 = OH + RO2C + xHO2 + xPROD2 + yROOH + #-3 XC + XN 1.56e-13 e1 TM-AMINE + NO3 = HNO3 + RO2C + xHO2 + xPROD2 + yROOH + #-3 XC + XN 4.00e-11 e2 TM-AMINE + HNO3 = #3 XC + XN isopropylamine 3.78e-11 e4 IPR-AMIN + OH = #.463 HO2 + #.537 RO2C + #.463 PROD2 + #.537 xMEO2 + #.537 xPROD2 + #.537 yROOH + XN + #-3.537 XC 3.32e-20 e3 IPR-AMIN + O3 = OH + RO2C + xMEO2 + xPROD2 + yROOH + #-4 XC + XN 1.21e-13 e1 IPR-AMIN + NO3 = HNO3 + #.487 HO2 + #.513 RO2C + #.487 PROD2 + #.513 xMEO2 + #.513 xPROD2 + #.513 yROOH + #- 3.513 XC + XN 4.00e-11 e2 IPR-AMIN + HNO3 = #3 XC + XNTable A-1 (continued)

61 Reaction Rate [a] Compound Expression Ref Reactions

t -butyl amine 1.18e-11 3 TBU-AMIN + OH = #.971 NRAD + #.055 RO2C + #.001 RO2XC + #.001 zRNO3 + #.028 xMEO2 + #.028 xHCHO + #.028 xPROD2 + #.029 yROOH + #.029 XN + #-.113 XC 5.88e-14 e1 TBU-AMIN + NO3 = HNO3 + NRAD Same as rxn BR28 e5 NRAD + NO2 = PROD2 + #2 XN + #-2 XC (Neglected) e6 NRAD + NO = nitrosoamine Same as rxn BR31 e7 NRAD + HO2 = #4 XC + XN 4.00e-11 e2 TBU-AMIN + HNO3 = #4 XC + XN Triethyl Amine 5.57e-11 e4 TE-AMINE + OH = #2.297 RO2C + #.311 RO2XC + #.311 zRNO3 + #.689 xHO2 + #.689 xRCHO + yR6OOH + XN + #2.066 XC 1.21e-17 e3 TE-AMINE + O3 = OH + #2.297 RO2C + #.311 RO2XC + #.311 zRNO3 + #.689 xHO2 + #.689 xRCHO + yROOH + #2.066 XC + XN 1.71e-13 e1 TE-AMINE + NO3 = HNO3 + #2.297 RO2C + #.311 RO2XC + #.311 zRNO3 + #.689 xHO2 + #.689 xRCHO + yR6OOH + #2.066 XC + XN 4.00e-11 e2 TE-AMINE + HNO3 = #6 XC + XN Ethanolamine 4.41e-11 e4 ETOH-NH2 + OH = #.486 HO2 + #.514 RO2C + #.091 RCHO + #.394 PROD2 + #.514 xHO2 + #.514 xHCHO + #.514 xPROD2 + #.514 yROOH + XN + #-4.24 XC 6.58e-20 e3 ETOH-NH2 + O3 = OH + RO2C + xHO2 + xHCHO + xPROD2 + yROOH + #-5 XC + XN 1.35e-13 e1 ETOH-NH2 + NO3 = HNO3 + #.436 HO2 + #.564 RO2C + #.436 PROD2 + #.564 xHO2 + #.564 xHCHO + #.564 xPROD2 + #.564 yROOH + #-4.564 XC + XN 4.00e-11 e2 ETOH-NH2 + HNO3 = #2 XC + XN Dimethylaminoethanol 6.85e-11 4 DMAE + OH = #.067 HO2 + #.896 RO2C + #.037 RO2XC + #.037 zRNO3 + #.067 RCHO + #.896 xHO2 + #.362 xHCHO + #.535 xRCHO + #.362 xPROD2 + #.93 3 yROOH + XN + #-.557 XC 6.76e-18 2 DMAE + O3 = OH + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + #.961 xHO2 + #.384 xHCHO + #.576 xRCHO + #.384 xPROD2 + yROOH + #-0.655 XC + XN 1.80e-13 e1 DMAE + NO3 = HNO3 + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + #.961 xHO2 + #.406 xHCHO + #.554 xRCHO + #.406 xPROD2 + yROOH + #-.743 XC + XN 4.00e-11 e2 DMAE + HNO3 = #4 XC + XN 2-amino-1-butanol 5.32e-11 e4 2A1C4OH + OH = #.404 HO2 + #.594 RO2C + #.024 RO2XC + #.024 zRNO3 + #.076 RCHO + #.328 PROD2 + #.573 xHO2 + #.573 xHCHO + #.021 xCCHO + #.573 xPROD2 + #.596 yROOH + XN + #-2.387 XC 3.65e-19 e3 2A1C4OH + O3 = OH + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + #.961 xHO2 + #.961 xHCHO + #.961 xPROD2 + yROOH + #-2.961 XC + XN 1.70e-13 e1 2A1C4OH + NO3 = HNO3 + #.347 HO2 + #.628 RO2C + #.026 RO2XC + #.026 zRNO3 + #.347 PROD2 + #.628 xHO2 + #.628 xHCHO + #.628 xPROD2 + #.653 yROOH + #-2.628 XC + XN 4.00e-11 e2 2A1C4OH + HNO3 = #4 XC + XNTable A-1 (continued)

62 Reaction Rate [a] Compound Expression Ref Reactions

2-Amino-2-Methyl-1- Propanol 2.80e-11 5 AMP + OH = #.185 HO2 + #.799 NRAD + #.015 RO2C + #.001 RO2XC + #.001 zRNO3 + #.185 RCHO + #.015 xHO2 + #.015 xRCHO + #.016 yROOH + #.201 XN + #.199 XC 5.88e-14 e1 AMP + NO3 = HNO3 + NRAD Same as rxn BR28 e5 NRAD + NO2 = PROD2 + #2 XN + #-2 XC (Neglected) e6 NRAD + NO = nitrosoamine Same as rxn BR31 NRAD + HO2 = #4 XC + XN 4.00e-11 e2 AMP + HNO3 = #4 XC + XN Diethanol Amine 1.01e-10 e4 ETOH2-NH + OH = #.316 HO2 + #.43 RO2C + #.018 RO2XC + #.018 zRNO3 + #.08 RCHO + #.236 PROD2 + #.43 xHO2 + #.43 xHCHO + #.43 xPROD2 + #.44 8 yROOH + XN + #-.774 XC 3.77e-18 e3 ETOH2-NH + O3 = OH + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + #.961 xHO2 + #.961 xHCHO + #.961 xPROD2 + yROOH + #-2.961 XC + XN 3.30e-13 e1 ETOH2-NH + NO3 = HNO3 + #.269 HO2 + #.444 RO2C + #.018 RO2XC + #.018 zRNO3 + #.269 PROD2 + #.444 xHO2 + #.444 xHCHO + #.444 xPROD2 + #.463 yROOH + #-.832 XC + XN 4.00e-11 e2 ETOH2-NH + HNO3 = #4 XC + XN Triethanolamine 8.04e-11 e4 ETOH3-N + OH = #.151 HO2 + #.766 RO2C + #.083 RO2XC + #.083 zRNO3 + #.151 RCHO + #.766 xHO2 + #.766 xHCHO + #.766 xPROD2 + #.849 yR6OOH + XN + #-.314 XC 4.02e-17 e3 ETOH3-N + O3 = OH + #.902 RO2C + #.098 RO2XC + #.098 zRNO3 + #.902 xHO2 + #.902 xHCHO + #.902 xPROD2 + yROOH + #-0.902 XC + XN 2.29e-13 e1 ETOH3-N + NO3 = HNO3 + #.902 RO2C + #.098 RO2XC + #.098 zRNO3 + #.902 xHO2 + #.902 xHCHO + #.902 xPROD2 + yR6OOH + #-.902 XC + XN 4.00e-11 e2 ETOH3-N + HNO3 = #6 XC + XN triisopropanol amine 9.37e-11 e4 IC3OH3-N + OH = #.268 HO2 + #.581 RO2C + #.151 RO2XC + #.151 zRNO3 + #.268 PROD2 + #.581 xHO2 + #.581 xCCHO + #.581 xPROD2 + #.732 yR6OOH + XN + #1.838 XC 4.02e-17 e3 IC3OH3-N + O3 = OH + #.794 RO2C + #.206 RO2XC + #.206 zRNO3 + #.794 xHO2 + #.794 xCCHO + #.794 xPROD2 + yROOH + #1.413 XC + XN 2.29e-13 e1 IC3OH3- N + NO3 = HNO3 + #.794 RO2C + #.206 RO2XC + #.206 zRNO3 + #.794 xHO2 + #.794 xCCHO + #.794 xPROD2 + yR6OOH + #1.413 XC + XN 4.00e-11 e2 IC3OH3-N + HNO3 = #9 XC + XNTable A-1 (continued)

63 Reaction Rate [a] Compound Expression Ref Reactions

d -Limonene 4.28e-11 x exp(-0.797)/RT 6 D-LIMONE + OH = #.972 RO2C + #.17 RO2XC + #.17 zRNO3 + #.827 xHO2 + #.003 xRCO3 + #.288 xHCHO + #.539 xRCHO + #.053 xMEK + #.287 xPROD2 + #.019 xMVK + #.012 xIPRD + yR6OOH + #5.001 XC 2.95e-15 x exp(1.556)/RT 6 D-LIMONE + O3 = #.729 OH + #.009 HO2 + #.619 RO2C + #.177 RO2XC + #.177 zRNO3 + #.029 CO + #.017 CO2 + #.263 PROD2 + #.021 xHO2 + #.482 xMECO3 + #.058 xRCO3 + #.089 xHCHO + #.5 xRCHO + #.015 xMACR + #.007 xIPRD + #.738 yR6OOH + #4.497 XC 1.22e-11 6 D-LIMONE + NO3 = #1.11 RO2C + #.296 RO2XC + #.296 zRNO3 + #.626 xNO2 + #.076 xHO2 + #.002 xRCO3 + #.078 xHCHO + #.009 xCCHO + #.641 xRCHO + #.039 xMACR + #.009 xMVK + #.028 xIPRD + #.069 xRNO3 + yR6OOH + #5.452 XC + #.304 XN 7.20e-11 7 D-LIMONE + O3P = PROD2 + #4 XC

Terpinolene 1.96e-10 e8 TRPNOLEN + OH = #.77 RO2C + #.23 RO2XC + #.23 zRNO3 + #.77 xHO2 + #.348 xRCHO + #.422 xACET + #.422 xPROD2 + yROOH + #3.78 XC 1.02e-15 e8 TRPNOLEN + O3 = #.908 OH + #.003 HO2 + #.872 RO2C + #.113 RO2XC + #.113 zRNO3 + #.01 CO + #.006 CO2 + #.33 ACET + #.419 PROD2 + #.056 xHO2 + #.501 xMECO3 + #.241 xRCO3 + #.35 xHCHO + #.171 xRCHO + #.055 xAFG3 + #.001 xIPRD + #.911 yROOH + #2.825 XC 6.66e-11 e8 TRPNOLEN + NO3 = #1.22 RO2C + #.343 RO2XC + #.343 zRNO3 + #.486 xNO2 + #.17 xHO2 + #.007 xHCHO + #.091 xRCHO + #.394 xACET + #.394 xPROD2 + #.123 xMVK + #.046 xIPRD + #.171 xRNO3 + yROOH + #2.368 XC + #.343 XN 1.63e-10 e8 TRPNOLEN + O3P = PROD2 + #4 XC tripropylene glycol 6.59e-11 e8 TPR-GLCL + OH = #.255 HO2 + #.938 RO2C + #.165 RO2XC + #.165 zRNO3 + #.255 PROD2 + #.519 xHO2 + #.061 xMEO2 + #.023 xHCHO + #.264 xCCHO + #.92 xPROD2 + #.745 yR6OOH + #.347 XC diethylene glycol mono(2-ethylhexyl) ether 5.16e-11 e8 DG2EHE + OH = #.079 HO2 + #1.357 RO2C + #.36 RO2XC + #.36 zRNO3 + #.079 RCHO + #.562 xHO2 + #.155 xHCHO + #.03 xCCHO + #.092 xRCHO + #.003 xMEK + #.941 xPROD2 + #.921 yR6OOH + #3.457 XC tripropylene glycol n

butyl ether 9.54e-11 e8 TGLBE + OH = #.042 HO2 + #1.441 RO2C + #.336 RO2XC + #.336 zRNO3 + #.042 RCHO + #.492 xHO2 + #.13 xMEO2 + #.172 xHCHO + #.031 xCCHO + #.091 xRCHO + #.327 xMEK + #.834 xPROD2 + #.013 xHCOOH + #.958 yR6OOH + #3.895 XC triethyl citrate 5.91e-12 e8 TETCITRA + OH = #.026 RCO3 + #.727 RO2C + #.248 RO2XC + #.248 zRNO3 + #.026 MEK + #.001 BACL + #.182 xHO2 + #.544 xMECO3 + #.065 xRCHO + #.027 xMEK + #.183 xPROD2 + #.09 xMGLY + #.09 xBACL + #.361 xRCOOH + #.974 yROOH + #6.125 XC 2,2,4-trimethyl-1,3- pentanediol diisobutyrate 1.15e-11 e8 TXIB + OH = #1.976 RO2C + #.53 RO2XC + #.53 zRNO3 + #.443 xHO2 + #.006 xMEO2 + #.022 xRCO3 + #.186 xCO + #.071 xHCHO + #.011 xCCHO + #.026 xRCHO + #.659 xACET + #.842 xMEK + #.004 xPROD2 + #.001 xBACL + #.199 xRCOOH + yROOH + #6.427 XCTable A-1 (continued)

64 Reaction Rate [a] Compound Expression Ref Reactions

Citronellol (3,7- dimethy-6-octen-1-ol) 9.87e-11 e8 CITRNLOL + OH = #.041 HO2 + #.792 RO2C + #.226 RO2XC + #.226 zRNO3 + #.041 RCHO + #.727 xHO2 + #.006 xMEO2 + #.043 xHCHO + #.004 xCCHO + #.7 xRCHO + #.687 xACET + #.027 xPROD2 + #.005 xMACR + #.006 xMVK + #.009 xIPRD + #.959 yR6OOH + #4.05 XC 3.48e-16 e8 CITRNLOL + O3 = #.728 OH + #.009 HO2 + #.765 RO2C + #.007 RO2XC + #.007 zRNO3 + #.029 CO + #.017 CO2 + #.7 RCHO + #.3 ACET + #.263 PROD2 + #.031 xHO2 + #.7 xMECO3 + #.703 xHCHO + #.001 xCCHO + #.03 xRCHO + #.737 yR6OOH + #3.141 XC 9.37e-12 e8 CITRNLOL + NO3 = #1.337 RO2C + #.389 RO2XC + #.389 zRNO3 + #.084 xNO2 + #.527 xHO2 + #.018 xHCHO + #.013 xCCHO + #.084 xRCHO + #.084 xACET + #.016 xPROD2 + #.528 xRNO3 + yR6OOH + #3.854 XC + #.388 XN 3.71e-11 e8 CITRNLOL + O3P = PROD2 + #4 XC Linalool 1.22e-10 e8 LINALOOL + OH = #.775 RO2C + #.232 RO2XC + #.232 zRNO3 + #.768 xHO2 + #.064 xHCHO + #.131 xCCHO + #.637 xRCHO + #.558 xACET + #.137 xPROD2 + #.009 xMVK + yR6OOH + #3.841 XC 3.58e-16 e8 LINALOOL + O3 = #.712 OH + #.013 HO2 + #.737 RO2C + #.006 RO2XC + #.006 zRNO3 + #.036 CO + #.019 CO2 + #.014 HCHO + #.694 RCHO + #.292 ACET + #.269 PROD2 + #.005 HCOOH + #.03 xHO2 + #.68 xMECO3 + #.704 xHCHO + #.006 xRCHO + #.024 xMVK + #.717 yR6OOH + #3.136 XC 9.38e-12 e8 LINALOOL + NO3 = #1.298 RO2C + #.388 RO2XC + #.388 zRNO3 + #.084 xNO2 + #.528 xHO2 + #.084 xRCHO + #.084 xACET + #.528 xMVK + #.528 xRNO3 + yR6OOH + #1.887 XC + #.388 XN 6.60e-11 e8 LINALOOL + O3P = PROD2 + #4 XC Geraniol 1.80e-10 e8 GERANIOL + OH = #.003 HO2 + #.791 RO2C + #.231 RO2XC + #.231 zRNO3 + #.761 xHO2 + #.005 xMEO2 + #.014 xHCHO + #.378 xCCHO + #.378 xRCHO + #.378 xACET + #.378 xPROD2 + #.003 xMACR + #.005 xMVK + #.013 xIPRD + #.997 yR6OOH + #3.205 XC 6.96e-16 e8 GERANIOL + O3 = #.728 OH + #.028 HO2 + #.672 RO2C + #.064 RO2XC + #.064 zRNO3 + #.029 CO + #.017 CO2 + #.019 HCHO + #.35 CCHO + #.35 RCHO + #.15 ACET + #.004 MEK + #.281 PROD2 + #.128 RCOOH + #.015 xHO2 + #.608 xMECO3 + #.031 xRCO3 + #.413 xHCHO + #.258 xRCHO + #.014 xMACR + #.001 xIPRD + #.719 yR6OOH + #2.708 XC 1.87e-11 e8 GERANIOL + NO3 = #1.096 RO2C + #.319 RO2XC + #.319 zRNO3 + #.419 xNO2 + #.254 xHO2 + #.008 xMEO2 + #.242 xHCHO + #.37 xCCHO + #.055 xRCHO + #.055 xACET + #.364 xPROD2 + #.006 xMACR + #.008 xMVK + #.018 xIPRD + #.266 xRNO3 + yR6OOH + #2.841 XC + #.315 XN 1.35e-10 e8 GERANIOL + O3P = PROD2 + #4 XCTable A-1 (continued)

65 Reaction Rate [a] Compound Expression Ref Reactions

Hydroxycitronellal 2.80e-11 e8 HYCITRLL + OH = #.696 RCO3 + #.366 RO2C + #.103 RO2XC + #.103 zRNO3 + #.181 xHO2 + #.02 xRCO3 + #.012 xCO + #.02 xHCHO + #.005 xCCHO + #.183 xRCHO + #.098 xACET + #.002 xPROD2 + #.015 xMGLY + #.304 yR6OOH + #6.294 XC Phot set= C2CHO e9 HYCITRLL + HV = HO2 + #1.43 RO2C + #.372 RO2XC + #.372 zRNO3 + CO + #.628 xHO2 + #.006 xHCHO + #.622 xRCHO + #.006 xPROD2 + yR6OOH + #4.86 XC 2-ethylhexyl benzoate 1.37e-11 e10 2EHXBOAT + OH = #.067 OH + #.039 HO2 + #1.286 RO2C + #.352 RO2XC + #.352 zRNO3 + #.039 CRES + #.067 AFG3 + #.539 xHO2 + #.045 xGLY + #.029 MGLY + #.382 xPROD2 + #.003 xRCO3 + #.101 xRCHO + #.037 xAFG1 + #.037 xAFG2 + #.801 yR6OOH + #.094 yRAOOH + #8.998 XC 1-nitropropane 1.33e-12 e8 C3-NO2 + OH = #.955 RO2C + #.045 RO2XC + #.045 zRNO3 + #.955 xHO2 + #.129 xRCHO + yROOH + XN + #2.346 XC ethyl methyl ketone oxime 1.25e-12 e11 EMKO + OH = #.04 {RO2XC + zRNO3} + #.96 {RO2C + xHO2 + xPROD2} + #-2 XC + XN 3.89e-12 e12 EMKO + OH = HO2 + EMKO-NO methyl nonafluoro butyl ether 1.15e-12 e8 MEONC4F9 + OH = #.935 RO2C + #.065 RO2XC + #.065 zRNO3 + #.935 xHO2 + #.935 NROG + yROOH + #3.675 XC ethyl nonafluoro butyl ether 7.97e-12 e8 ETONC4F9 + OH = #.902 RO2C + #.098 RO2XC + #.098 zRNO3 + #.902 xHO2 + #.019 xRCHO + #.883 NROG + yROOH + #4.473 XC [a] Rate constants are in units of cm 3 molec -1 s -1 . If a temperature dependence is used, it is given by k(T) = A exp(-Ea/RT), where T is the temperature in degrees k and R = 0.0019872. For photolysis reactions, the "Phot set" is the set of absorpti on cross sections and wavelength-dependent quantum yields (if any) given in Table A-3 of the SAPRC- 07 documentation report (Carte r, 2007a), and "qy" is the wavelength-independent quantum yield, if applicable. "Same k as Rxn xxx" indicates that the rate constant is the same as a reaction in the base mechanism as listed in Table A-2 of the SAPRC-07 documentation report, where "xxx" is the reaction la bel. References for measured rate constants or photolysis data are as follows: 1 Average of values tabulated by Carl and Crowley (1998). 2 Rate constant from Tuazon et al (1994) 3 Koch et al (1996) 4 Average of values of Harris and Pitts (1983) a nd Anderson and Stephens (1988), as tabulated by Atkinson (1989). 5 Harris and Pitts (1983) 6 As recommended or tabulated by Atkinson and Arey (2003) 7 As recommended or tabulated by Calvert et al (2002) Methods used to estimate rate constant s or photolysis rates are as follows: e1 Estimated based on the NO 3 + NMP rate constant and assuming ratios of rate constants for reactions of NO 3 at various types of amine groups is th e same as those estimated for the reactions of OH with those groups. Reaction assumed to occur only from NH or NH2 or from C-H bonds on carbons bonded to the amino group. e2 This represents the removal of amines ava ilable for gas-phase reaction by reacting with HNO 3 to form the amine salt that is removed from the system. The rate constant shown is an estimated upper limit. The upper limit rate constant is arbitr arily estimated based on typical rate constants for radical + NO x reactions, which is sufficiently large that this would dominate over other gasphase reactions if gas-phase HNO 3 were available. Because of the uncertainty and variability ofTable A-1 (continued)

66 availability of HNO 3 in atmospheric scenarios, the atmos pheric reactivity calculations are carried out both with these amine + HNO 3 reactions with the upper limit rate constant, and assuming that this reaction is negligible (or rapidly reversed ). However, it is recommended that the reactivity values used for amines for regulatory applications be based on the assumption that net loss of the amine by this reaction is negligible. This w ill provide a reasonable upper limit on the magnitude of the amines' impacts on O 3 under conditions where they will have their maximum impact. e3 Estimated from the estimated rate of reac tion of OH at the alpha position, and correlations between this and the measured O3 rate constant s of Tuazon et al (1994) for the methylamines and DMAE. e4 Derived from structure-reactivity methods, where group rate constants for reactions at HN, NH 2 , at groups adjacent to the amino group were derived based on rate constants for the simple amines for which rate constant data are available. e5 This represents the reactions of N-centere d radicals that lack alpha hydrogens with NO 2 to form nitramines. Rate constant assumed to be the same as used for lumped higher acylperoxy (RCO3) + NO 2 . The nitramines are very approximately re presented by PROD2. The appropriateness of this representation is uncertain. e6 The formation of nitrosoamines is neglected because these products are rapidly decomposed by photolysis under conditions wher e ozone formation occurs. e7 This represents the reactions of N-centere d radicals that lack alpha hydrogens with HO 2 to form O 2 and re-form the amine. The rate constant assu med to be the same as used for lumped higher acylperoxy (RCO3) + HO 2 . The amines that form these radicals are generally inhibitors, so representing them with reactive model species is ina ppropriate. Therefore, they are represented as being inert. e8 Estimated using the group-additivity estimation assignments implemented in the current mechanism generation system. See Carter (2000a) and the discussion of the mechanism generation system in this report. e9 Assumed to have the same photolysis ra te as propionaldehyde (model species RCHO). e10 Rate constant for reaction at the aromatic ring estimated to be the same as the total rate constant for acetophenone (Atkinson, 1989), assuming that ri ng addition is the major reaction for that compound. The rate constant for reaction at groups off the aromatic ring based on those estimated for 2-ethyl hexyl acetate, since reaction at the acet ate group is estimated to be negligible for that compound. e11 The rate constant for addition of OH to the C=N double bond is estimated by the rate constant for OH + isobutene x the average of the ratio of the rate constants for CH 2 =NOH / Ethene and CH 3 CH=NOH / Propene, with abstractions from the methyl group subtracted off. The CH 2 =NOH and CH3CH=NOH rate constants are from the tabulation of Atkinson (1989). e12 The rate constants for addition to the methyl gr oups were estimated using the structure-reactivity methods incorporated in the mechanism generation system.67 Table A-2. New lumped molecule representations used for atmospheric reactivity estimates of compounds added to the reactivity tabulations for this project.

Compound Represented by (on molar basis)

Hexyl cinnamal lumped c5+ unsaturated carbonyl species (isoprene product) Cinnamic aldehyde lumped c5+ unsaturated carbonyl species Amyl cinnamal lumped c5+ unsaturated carbonyl species 4-vinylphenol styrene methylparaben (4-Hydroxybenzoic acid, methyl ester) o -cresol propylparaben o -cresol 2,6-di-tert-butyl- p -cresol o -cresol beta-phenethyl alcohol benzyl alcohol Cinnamic alcohol β -methyl styrene anethol β -methyl styrene triethylene diamine triethyl amine lauryl pyrrolidone n -methyl-2-pyrrolidone

o -dichlorobenzene p -dichlorobenzene 2-chlorotoluene toluene methyl nonafluoroisobutyl ether methyl nonafluorobutyl ether ethyl nonafluoroisobutyl ether ethyl nonafluorobutyl ether68 

### APPENDIX B. CHAMBER EXPERIMENT LISTING

Table B-1. Summary chamber experiments relevant to this project.

Run Date Type [b] Purpose and Conditions Results

777 6/26 CO - NO x Irradiation Characterize chamber radical source. ~25 ppb NO x and 50 ppm CO injected into both sides. Data indicated that chamber radical source in the normal range. Somewhat higher radical source in Side A. See Figure 4. 778 6/27 Pure Air Irradiation Background characterization. No injections. 4 ppb O 3 formed after 5 hours on both sides. PM levels low on both sides but somewhat higher on Side A 779 6/28 MIR surrogate + ethanolamine (both sides) Intended to be incremental reactivity experiment to evaluate ethanolamine mechanism, but ~100 ppb ethanolamine injected into both sides, so no base case experiment was carried out. Results were similar to subsequent MIR surrogate experiments with similar levels of ethanolamine. Run not used for mechanism evaluation because of lack of base case data. 780 6/29 MIR surrogate + ethanolamine Incremental reactivity experiment to evaluate ethanolamine mechanism. ~100 ppb ethanolamine injected into Side A. Run ended early because of experimental problems. Results shown on Table 6 and Figure 7.

781 7/3 MIR surrogate + AMP Incremental reactivity experiment to evaluate AMP mechanism. 0.5 ppm AMP injected into Side A. Essentially no ozone formed on added AMP side. Measurement data are uncertain because of sampling problem, but data looked reasonable after an estimated correction was made. Results shown on Table 6, Table 8, and Figure 6. 782 7/5 MIR surrogate + AMP Repeat previous experiment because results were not as expected. Results similar to previous experiment. Measurement data are uncertain because of sampling problem, but data looked reasonable after an estimated correction was made Results shown on Table 6, Table 8 and Figure 6. 783 7/6 MOIR/2 surrogate + AMP Incremental reactivity experiment to evaluate AMP mechanism. ~100 ppb AMP injected into Side A. Results shown on Table 6, Table 8 and Figure 6.

784 7/9 MOIR/2 surrogate + AMP Repeat previous experiment Results shown on Table 6, Table 8 and Figure 6.Table B-1 (continued)

69 Run Date Type [b] Purpose and Conditions Results 785 7/10 MIR surrogate side equivalency
test Test for side equivalency in reactivity experiments. Standard base case MIR surrogate - NO x run on both sides. Reasonably good side equivalenc y seen. Results summarized on Table 6 and Table 8.

786 7/11 CO - air irradiation Characterize background NO x offgasing. 50 ppm CO injected into both sides Data indicated that the NO x offgasing rates were in the normal range Somewhat higher NO x offgasing in Side A. See Figure 4. 787 7/12 Pure Air Irradiation Background characterization. No injections. 3 ppb O 3 formed after 5 hours on both sides. PM levels low on both sides but somewhat higher on Side A 788 7/13 Pure Air Irradiation Background characterization. No injections. Results similar to previous run. 4 ppb O 3 formed after 5 hours on both sides. PM levels low on both sides but somewhat higher on Side A 789 7/16 MOIR/2 surrogate + AMP Incremental reactivity experiment to evaluate AMP mechanism. ~50 ppb AMP injected into Side B. Results shown on Table 6, Table 8 and Figure 6.

790 7/17 MIR surrogate + ethanolamine Incremental reactivity experiment to evaluate ethanolamine mechanism. ~100 ppb ethanolamine injected into Side A. Effect of ethanolamine on gasphase results was unexpectedly small, but effect on PM was large. Results shown on Table 6, Table 8 and Figure 7. 791 7/18 MOIR/2 surrogate + ethanolamine Incremental reactivity experiment to evaluate ethanolamine mechanism. ~50 ppb ethanolamine injected into Side A. Effect of ethanolamine on gasphase results was unexpectedly small, but effect on PM was large. Results shown on Table 6, Table 8 and Figure 7. 792 7/19 MOIR/2 surrogate + AMP Incremental reactivity experiment to evaluate AMP mechanism. ~50 ppb AMP injected into Side A. Results shown on Table 6, Table 8 and Figure 6.

793 7/24 MIR surrogate + d -Limonene Incremental reactivity experiment to evaluate d -limonene mechanism. 35 ppb d -limonene injected into Side A. Results shown on Table 6, Table 8 and Figure 11.

794 7/25 d -Limonene - NO x Irradiation Evaluate d -limonene mechanism in the absence of other reactants. See Table 7. Data on Side A not useable because of instrument and sampling problem. Results for Side B shown on Table 7 and Figure 12 795 7/26 d -Limonene - NO x Irradiation Evaluate d -limonene mechanism in the absence of other reactants. See Table 7. Results shown on Table 7 and Figure 12Table B-1 (continued)

70 Run Date Type [b] Purpose and Conditions Results

796 7/27 Pure Air Irradiation Background characterization. No injections. Unusually high O 3 and PM formation on both sides, with higher levels on Side A. Chamber apparently contaminated, though reason is unknown. 5-Hour O 3 was 20 and 11 ppb on Sides A and B, respectively. 797 7/30 MIR surrogate + d-Limonene Incremental reactivity experiment to evaluate d-limonene mechanism. 26 ppb d-limonene injected into Side A. Results shown on Table 6, Table 8 and Figure 11.

798 8/1 MOIR/2 surrogate + ethanolamine Incremental reactivity experiment to evaluate ethanolamine mechanism. ~100 ppb ethanolamine injected into Side A. Effect on O 3 formation was relatively small. Results shown on Table 6, Table 8 and Figure 11.

799 8/3 MIR surrogate + AMP Evaluate AMP mechanism with lower added AMP levels. ~60 ppb AMP injected into Side A. Results shown on Table 6, Table 8 and Figure 6.

801 8/7 Pure Air Irradiation Background characterization. No injections. 5-Hour O 3 was 7 and 3 ppb on Sides A and B, respectively. PM levels low on both sides but somewhat higher on Side A. 802 8/8 Pure Air Irradiation Background characterization. No injections. Results similar to previous run. 5- Hour O3 was 5 and 2 ppb on Sides A and B, respectively. PM levels low on both sides but somewhat higher on Side A. 804 8/13 MOIR/2 surrogate + d -limonene Incremental reactivity experiment to evaluate d -limonene mechanism. 25 ppb d -limonene injected into Side A. Results shown on Table 6, Table 8 and Figure 11.

805 8/14 MOIR/2 surrogate + ethanolamine Incremental reactivity experiment to evaluate ethanolamine mechanism. ~250 ppb ethanolamine injected into Side A. Results shown on Table 6, Table 8 and Figure 7.

806 8/15 MOIR/2 surrogate + t

butyl amine Incremental reactivity experiment to evaluate t -butyl amine mechanism. ~250 ppb t -butyl amine injected into Side A. t -Butyl amine caused significant inhibition of gas-phase reactivity. Results shown on Table 6, Table 8 and Figure 7. 807 8/16 MOIR/2 surrogate + isopropyl amine Incremental reactivity experiment to evaluate isopropyl amine mechanism. ~250 ppb isopropyl amine injected into Side A. Isopropyl amine enhanced rate of O 3 formation. Results shown on Table 6, Table 8 and Figure 7.Table B-1 (continued)

71 Run Date Type [b] Purpose and Conditions Results

808 8/17 CO - NO x Irradiation Characterize chamber radical source. ~25 ppb NO x and 60 ppm CO injected into both sides. Data indicated that radical source rate was in normal range for Side A. No useable data for Side B because of sampling problems. See Figure 4. 809 8/18 Pure Air Irradiation Background characterization. No injections. 5-Hour O 3 was 6 and 2 ppb on Sides A and B, respectively. PM levels low on both sides but somewhat higher on Side A. [a] “Surrogate” refers to the 8-component “Full Su rrogate” as used in previous environmental chamber incremental reactivity studies in our laboratories, except that formaldehyde was removed and the other ROG components were increased by 10% to yield approximately the same reactivity as discussed by Carter and Malkina (2005). The designati on “MIR Surrogate” refers to experiments with 0.55 ppmC base case surrogate and 30 ppb NO x , The designation “MOIR/2 Surrogate” refers to experiments with 1.1 ppmC base case surrogate and 25 ppb NO x .72 

### APPENDIX C. UPDATED VOC AND AT MOSPHERIC REACTIVITY LISTING

Table C-1. Listing of VOCs for which atmospheric ozone impact estimates are available, their representation in the model, and their calculate d atmospheric reactivity values in various reactivity scales. This tabulation is current as of December 20, 2007.

Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
carbon monoxide 630-08-0 28.01 Exp 1 2 0 1 0.052 0.038 0.029 0.035±0.007 methane 74-82-8 16.04 Exp 1 0 6 0.014 0.008 0.006 0.008±0.002 ethane 74-84-0 30.07 Exp 1 3 0 1 0.26 0.183 0.132 0.163±0.043 propane 74-98-6 44.10 Exp 1 3 0 1 0.46 0.32 0.23 0.28±0.07 n-butane 106-97-8 58.12 Exp 1 2 0 1 1.08 0.71 0.48 0.62±0.17 n-pentane 109-66-0 72.15 Exp 1 0 6 1.22 0.80 0.51 0.69±0.21 n-hexane 110-54-3 86.18 Exp 1 3 0 2 1.14 0.76 0.44 0.63±0.21 n-heptane 142-82-5 100.20 Exp 1 0 6 0.97 0.64 0.33 0.51±0.20 n-octane 111-65-9 114.23 Exp 1 1 0 2 0.80 0.53 0.23 0.40±0.19 n-nonane 111-84-2 128.26 Exp 1 0,+ 6 b 0.68 0.45 0.171 0.32±0.18 n-decane 124-18-5 142.28 Exp 1 0,+ 6 b 0.59 0.39 0.129 0.27±0.17 n-undecane 1120-21-4 156.31 Exp 1 0,+ 6 b 0.52 0.35 0.104 0.23±0.15 n-dodecane 112-40-3 170.33 Exp 1 2 0,+ 3 b 0.47 0.32 0.088 0.21±0.15 n-tridecane 629-50-5 184.36 Exp 1 0,+ 6 b 0.45 0.30 0.083 0.198±0.140 n-tetradecane 629-59-4 198.39 Exp 1 2 0,+ 3 b 0.43 0.29 0.084 0.194±0.136 n-pentadecane 629-62-9 212.41 Exp 1 4 0,+ 3 b 0.42 0.28 0.085 0.189±0.130 n-c16 544-76-3 226.44 AdjP 1 3 0,+ 3 b 0.36 0.25 0.051 0.156±0.136 n-c17 629-78-7 240.47 LM 0,+ 7 b 0.34 0.24 0.048 0.147±0.128 n-c18 593-45-3 254.49 LM 0,+ 7 b 0.32 0.23 0.045 0.138±0.121 n-c19 629-92-5 268.52 LM 0,+ 7 b 0.31 0.21 0.043 0.131±0.115 n-c20 112-95-8 282.55 LM 0,+ 7 b 0.29 0.20 0.041 0.125±0.109 n-c21 629-94-7 296.57 LM 0,+ 7 b 0.28 0.194 0.039 0.119±0.104 n-c22 629-97-0 310.60 LM 0,+ 7 b 0.27 0.186 0.037 0.113±0.099 isobutane 75-28-5 58.12 Exp 1 3 0 2 1.18 0.70 0.48 0.63±0.16 branched c5 alkanes 72.15 LM 0 8 1.36 0.88 0.61 0.78±0.20 neopentane 463-82-1 72.15 Exp 1 0 6 0.65 0.38 0.26 0.34±0.09 iso-pentane 78-78-4 72.15 Exp 1 0 6 1.36 0.88 0.61 0.78±0.20 branched c6 alkanes 86.18 LM 0 8 1.22 0.77 0.51 0.67±0.19 2,2-dimethyl butane 75-83-2 86.18 Exp 1 0 6 1.11 0.67 0.43 0.59±0.17 2,3-dimethyl butane 79-29-8 86.18 Exp 1 0 6 0.90 0.61 0.41 0.53±0.13 2-methyl pentane 107-83-5 86.18 Exp 1 0 6 1.40 0.84 0.52 0.72±0.23 3-methylpentane 96-14-0 86.18 Exp 1 0 6 1.69 1.04 0.68 0.91±0.26 branched c7 alkanes 100.20 LM 0 8 1.38 0.81 0.47 0.68±0.23 2,2,3-trimethyl butane 464-06-2 100.20 Exp 1 0 6 1.05 0.62 0.39 0.54±0.15 2,2-dimethyl pentane 590-35-2 100.20 Exp 1 0 6 1.04 0.63 0.38 0.53±0.17 2,3-dimethyl pentane 565-59-3 100.20 Exp 0 7 1.25 0.77 0.48 0.66±0.20 2,4-dimethyl pentane 108-08-7 100.20 Exp 1 0 6 1.46 0.84 0.51 0.72±0.23 2-methyl hexane 591-76-4 100.20 AdjP 0 7 1.09 0.68 0.37 0.55±0.20 3,3-dimethyl pentane 562-49-2 100.20 Exp 0 7 1.12 0.70 0.45 0.61±0.18 3-methyl hexane 589-34-4 100.20 Exp 0 7 1.50 0.88 0.51 0.74±0.26 3-ethylpentane 617-78-7 100.20 Exp 0 7 1.78 1.03 0.64 0.89±0.28Table C-1 (continued)

73 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

branched c8 alkanes 114.23 LM 0 8 1.33 0.77 0.40 0.63±0.25 2,2,3,3-tetramethyl butane 594-82-1 114.23 Exp 1 0 6 0.30 0.183 0.101 0.151±0.053 2,2,4-trimethyl pentane 540-84-1 114.23 Exp 1 3 0 2 1.20 0.67 0.41 0.58±0.18 2,2-dimethyl hexane 590-73-8 114.23 Exp 1 0 6 0.94 0.55 0.29 0.45±0.17 2,3,4-trimethyl pentane 565-75-3 114.23 Exp 1 0 6 0.95 0.60 0.35 0.50±0.16 2,3-dimethyl hexane 584-94-1 114.23 Exp 0 7 1.09 0.67 0.37 0.55±0.20 2,4-dimethyl hexane 589-43-5 114.23 Exp 0 7 1.61 0.90 0.48 0.74±0.28 2,5-dimethyl hexane 592-13-2 114.23 Exp 0 7 1.35 0.78 0.42 0.64±0.24 2-methyl heptane 592-27-8 114.23 Exp 0 7 0.97 0.61 0.29 0.48±0.20 3-methyl heptane 589-81-1 114.23 Exp 0 7 1.12 0.70 0.35 0.55±0.22 4-methyl heptane 589-53-7 114.23 Exp 0 7 1.14 0.68 0.34 0.54±0.22 2,3,3-trimethylpentane 560-21-4 114.23 Exp 0 7 0.95 0.60 0.37 0.51±0.15 3,3-dimethylhexane 563-16-6 114.23 Exp 0 7 1.15 0.68 0.38 0.57±0.20 2,2,3-trimethyl-pentane 564-02-3 114.23 Exp 0 7 1.15 0.66 0.39 0.56±0.18 3,4-dimethylhexane 583-48-2 114.23 Exp 0 7 1.40 0.83 0.48 0.70±0.24 3-ethyl 2-methyl pentane 609-26-7 114.23 Exp 0 7 1.24 0.72 0.41 0.61±0.21 branched c9 alkanes 128.26 LM 0 8 b 1.03 0.61 0.27 0.47±0.22 2,2,5-trimethyl hexane 3522-94-9 128.26 Exp 0 7 b 1.05 0.59 0.31 0.49±0.19 2,3,5-trimethyl hexane 1069-53-0 128.26 AdjP 1 0 6 b 1.12 0.66 0.34 0.54±0.21 2,4-dimethyl heptane 2213-23-2 128.26 Exp 0 7 b 1.27 0.71 0.33 0.56±0.25 2-methyl octane 3221-61-2 128.26 Exp 1 0,+ 6 b 0.73 0.47 0.183 0.34±0.18 3,3-diethyl pentane 1067-20-5 128.26 Exp 1 0,+ 6 b 1.13 0.68 0.39 0.57±0.20 3,5-dimethyl heptane 926-82-9 128.26 Exp 0 7 b 1.42 0.83 0.41 0.66±0.28 4-ethyl heptane 2216-32-2 128.26 Exp 0 7 b 1.11 0.65 0.31 0.51±0.23 4-methyl octane 2216-34-4 128.26 Exp 1 0,+ 6 b 0.85 0.53 0.23 0.40±0.20 2,4,4-trimethylhexane 16747-30-1 128.26 Exp 0 7 b 1.25 0.70 0.37 0.58±0.22 3,3-dimethylheptane 4032-86-4 128.26 Exp 0 7 b 1.04 0.62 0.32 0.50±0.20 4,4-dimethylheptane 1068-19-5 128.26 Exp 0 7 b 1.18 0.65 0.33 0.53±0.22 2,2-dimethylheptane 1071-26-7 128.26 Exp 0 7 b 0.92 0.53 0.26 0.42±0.18 2,2,4-trimethylhexane 16747-26-5 128.26 Exp 0 7 b 1.17 0.64 0.31 0.52±0.21 2,6-dimethylheptane 1072-05-5 128.26 Exp 0 7 b 0.94 0.55 0.25 0.43±0.20 2,3-dimethylheptane 3074-71-3 128.26 Exp 0 7 b 0.98 0.61 0.30 0.48±0.20 2,5-dimethylheptane 2216-30-0 128.26 Exp 0 7 b 1.23 0.73 0.36 0.58±0.24 3-methyloctane 2216-33-3 128.26 Exp 0 7 b 0.88 0.55 0.24 0.42±0.20 3,4-dimethylheptane 922-28-1 128.26 Exp 0 7 b 1.13 0.69 0.35 0.55±0.22 3-ethylheptane 15869-80-4 128.26 Exp 0 7 b 0.99 0.60 0.27 0.46±0.21 branched c10 alkanes 142.28 LM 0 8 b 0.83 0.50 0.20 0.37±0.19 2,4,6-trimethyl heptane 2613-61-8 142.28 Exp 0 7 b 1.18 0.64 0.28 0.50±0.24 2,4-dimethyl octane 4032-94-4 142.28 Exp 0 7 b 0.92 0.54 0.22 0.41±0.21 2,6-dimethyl octane 2051-30-1 142.28 Exp 1 2 0,+ 2 b 0.98 0.56 0.25 0.43±0.21 2-methyl nonane 871-83-0 142.28 Exp 1 2 0,+ 2 b 0.63 0.41 0.135 0.28±0.18 3,4-diethyl hexane 19398-77-7 142.28 Exp 1 2 0,+ 2 b 0.81 0.49 0.24 0.38±0.16 3-methyl nonane 5911-04-6 142.28 Exp 0 7 b 0.66 0.42 0.145 0.30±0.18 4-methyl nonane 17301-94-9 142.28 Exp 0 7 b 0.76 0.47 0.181 0.34±0.19 4-propyl heptane 3178-29-8 142.28 Exp 0 7 b 0.91 0.54 0.23 0.41±0.20 2,4,4-trimethylheptane 142.28 Exp 0 7 b 1.22 0.65 0.31 0.53±0.23 2,5,5-trimethylheptane 142.28 Exp 0 7 b 1.15 0.65 0.33 0.53±0.21 3,3-dimethyloctane 4110-44-5 142.28 Exp 0 7 b 1.00 0.58 0.28 0.46±0.20 4,4-dimethyloctane 15869-95-1 142.28 Exp 0 7 b 1.04 0.59 0.28 0.47±0.21Table C-1 (continued)

74 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
2,2-dimethyloctane 15869-87-1 142.28 Exp 0 7 b 0.76 0.44 0.185 0.33±0.16 2,2,4-trimethylheptane 14720-74-2 142.28 Exp 0 7 b 1.08 0.58 0.26 0.46±0.21 2,2,5-trimethylheptane 142.28 Exp 0 7 b 1.17 0.65 0.34 0.54±0.21 2,3,6-trimethylheptane 4032-93-3 142.28 AdjP 0 7 b 0.80 0.50 0.21 0.37±0.18 2,3-dimethyloctane 7146-60-3 142.28 Exp 0 7 b 0.76 0.48 0.20 0.36±0.18 2,5-dimethyloctane 142.28 Exp 0 7 b 0.92 0.55 0.22 0.41±0.21 2-methyl-3-ethylheptane 14676-29-0 142.28 Exp 0 7 b 0.89 0.54 0.24 0.41±0.20 4-ethyloctane 15869-86-0 142.28 AdjP 0 7 b 0.68 0.44 0.131 0.30±0.20 branched c11 alkanes 156.31 LM 0 8 b 0.63 0.40 0.130 0.28±0.17 2,3,4,6-tetramethyl heptane 61868-54-0 156.31 Exp 0 7 b 1.00 0.59 0.27 0.46±0.21 2,6-dimethyl nonane 17302-28-2 156.31 Exp 0 7 b 0.69 0.42 0.149 0.30±0.17 3,5-diethyl heptane 61869-02-1 156.31 Exp 0 7 b 0.99 0.58 0.23 0.43±0.23 3-methyl decane 13151-34 -3 156.31 Exp 0 7 b 0.55 0.36 0.10 6 0.24±0.16 4-methyl decane 2847-72-5 156.31 Exp 0 7 b 0.59 0.38 0.118 0.26±0.17 branched c12 alkanes 170.33 LM 0 8 b 0.54 0.35 0.077 0.22±0.17 2,3,5,7-tetramethyl octane 62199-32-0 170.33 Exp 0 7 b 0.81 0.47 0.174 0.34±0.19 2,6-diethyl octane 62183-94-2 170.33 Exp 0 7 b 0.86 0.51 0.22 0.39±0.19 3,6-dimethyl decane 17312- 53-7 170.33 AdjP 0 7 b 0.59 0.38 0.08 9 0.24±0.18 3-methyl undecane 1002-43-3 170.33 Exp 0 7 b 0.50 0.33 0.091 0.22±0.15 5-methyl undecane 1632-70-8 170.33 AdjP 0 7 b 0.46 0.31 0.040 0.179±0.169 branched c13 alkanes 184.36 LM 0 8 b 0.51 0.33 0.084 0.21±0.16 2,3,6-trimethyl 4-isopropyl heptane 184.36 Exp 0 7 b 0.83 0.48 0.20 0.36±0.19

2,4,6,8-tetramethyl nonane 14638-54-1 184.36 AdjP 0 7 b 0.66 0.38 0.105 0.26±0.18 3,6-dimethyl undecane 17301-28-9 184.36 Exp 0 7 b 0.60 0.37 0.119 0.26±0.16 3,7-diethyl nonane 184.36 Exp 0 7 b 0.79 0.45 0.176 0.34±0.18 3-methyl dodecane 17312-57-1 184.36 Exp 0 7 b 0.46 0.31 0.082 0.20±0.14 5-methyl dodecane 17453-93-9 184.36 AdjP 0 7 b 0.38 0.26 0.017 0.143±0.157 branched c14 alkanes 198.39 LM 0 8 b 0.47 0.30 0.077 0.197±0.146 2,4,5,6,8-pentamethyl

nonane 198.39 Exp 0 7 b 0.84 0.51 0.20 0.37±0.20

2-methyl 3,5-diisopropyl heptane 198.39 AdjP 0 7 b 0.47 0.30 0.066 0.189±0.150

3,7-dimethyl dodecane 82144-67-0 198.39 Exp 0 7 b 0.54 0.34 0.107 0.23±0.15 3,8-diethyl decane 6224-52-8 198.39 AdjP 0 7 b 0.50 0.33 0.076 0.21±0.16 3-methyl tridecane 6418-41-3 198.39 Exp 0 7 b 0.43 0.29 0.07 7 0.188±0.137 6-methyl tridecane 13287-21 -3 198.39 AdjP 0 7 b 0.37 0.25 0.01 9 0.139±0.152 branched c15 alkanes 212.41 LM 0 8 b 0.42 0.28 0.067 0.179±0.138 2,6,8-trimethyl 4-isopropyl

nonane 212.41 Exp 0 7 b 0.54 0.33 0.099 0.23±0.15

3,7-dimethyl tridecane 212.41 Exp 0 7 b 0. 47 0.30 0.091 0.20±0.14 3,9-diethyl undecane 13286-72 -1 212.41 Exp 0 7 b 0.43 0.29 0.07 8 0.188±0.138 3-methyl tetradecane 18435-22-8 212.41 Exp 0 7 b 0.40 0.27 0. 074 0.178±0.130 6-methyl tetradecane 26730-16-5 212.41 AdjP 0 7 b 0.34 0.24 0. 015 0.127±0.144 branched c16 alkanes 226.44 LM 0 8 b 0.40 0.26 0.074 0.174±0.127 2,7-dimethyl 3,5- diisopropyl heptane 226.44 AdjP 0 7 b 0.44 0.28 0.057 0.176±0.148

3-methyl pentadecane 2882-96-4 226.44 Ex p 0 7 b 0.38 0. 26 0.072 0.170±0.124 4,8-dimethyl tetradecane 175032-36-7 226.44 Exp 0 7 b 0.41 0.27 0.076 0.180±0.130Table C-1 (continued)

75 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
7-methyl pentadecane 6165-40-8 226.44 Ex p 0 7 b 0.38 0. 26 0.071 0.168±0.124 branched c17 alkanes 240.47 LM 0 8 b 0.37 0.25 0.069 0.164±0.120 branched c18 alkanes 254.49 LM 0 8 b 0.35 0.24 0.066 0.155±0.113 branched c19 alkanes 268.52 LM 0 8 b 0.33 0.22 0.062 0.147±0.107 branched c20 alkanes 282.55 LM 0 8 b 0.32 0.21 0.059 0.140±0.102 branched c21 alkanes 296.57 LM 0 8 b 0.30 0.20 0.056 0.133±0.097 branched c22 alkanes 310.60 LM 0 8 b 0.29 0.193 0.054 0.127±0.093 cyclopropane 75-19-4 42.08 Exp 1 0 6 0.081 0.056 0.039 0.049±0.014 cyclobutane 287-23-0 56.11 Exp 1 0 6 1.11 0.72 0.48 0.63±0.21 cyclopentane 287-92-3 70.13 AdjP 1 0 6 2.24 1.31 0.82 1.14±0.35 c6 cycloalkanes 84.16 LM 0 8 1.14 0.73 0.41 0.60±0.21 cyclohexane 110-82-7 84.16 AdjP 1 2 0 2 1.14 0.73 0.41 0.60±0.21 isopropyl cyclopropane 3638-35-5 84.16 Exp 1 0 6 1.14 0.74 0.49 0.65±0.18 methylcyclopentane 96-37-7 84.16 AdjP 0 7 2.05 1.14 0.66 0.97±0.34 1,1-dimethylcyclopentane 1638-26-2 98.19 AdjP 0 7 0.99 0.58 0.29 0.47±0.19 1,2-dimethylcyclopentane 2452-99-5 98.19 AdjP 0 7 1.86 1.00 0.54 0.84±0.32 c7 cycloalkanes 98.19 LM 0 7 1.56 0.90 0.46 0.72±0.29 1,3-dimethyl cyclopentane 2453-00-1 98.19 AdjP 0 7 1.81 0.97 0.51 0.80±0.31 cycloheptane 291-64-5 98.19 AdjP 1 0 6 1.80 1.00 0.53 0.82±0.33 ethyl cyclopentane 1640-89-7 98.19 AdjP 0 7 1.87 1.03 0.55 0.85±0.33 methylcyclohexane 108-87-2 98.19 AdjP 1 0 6 1.56 0.90 0.46 0.72±0.29 c8 bicycloalkanes 110.20 LM 0 8 1.39 0.80 0.41 0.65±0.26 1,1,2- trimethylcyclopentane 4259-00-1 112.21 Exp 0 7 1.02 0.58 0.27 0.46±0.20

1,1,3- trimethylcyclopentane 4516-69-2 112.21 Exp 0 7 0.92 0.53 0.23 0.41±0.19

1,1-dimethyl cyclohexane 590-66-9 112.21 Exp 0 7 1.12 0.65 0.31 0.51±0.22 1,2,3- trimethylcyclopentane 112.21 Exp 0 7 1.50 0.83 0.42 0.67±0.28

1,2,4- trimethylcyclopentane 112.21 Exp 0 7 1.42 0.76 0.36 0.61±0.26

1-methyl-3- ethylcyclopentane 112.21 AdjP 0 7 1.51 0.82 0.39 0.66±0.29

1,2-dimethylcyclohexane 583-57-3 112.21 AdjP 0 7 1.27 0.77 0.35 0.59±0.27 1,4-dimethylcyclohexane 589-90-2 112.21 AdjP 0 7 1.48 0.81 0.37 0.64±0.29 c8 cycloalkanes 112.21 LM 0 8 1.35 0.78 0.38 0.62±0.26 1,3-dimethyl cyclohexane 591-21-9 112.21 AdjP 0 7 1.39 0.76 0.34 0.59±0.28 cyclooctane 292-64-8 112.21 AdjP 1 0 6 1.31 0.74 0.32 0.57±0.28 ethylcyclohexane 1678-91-7 112.21 Exp 0 7 1.35 0.78 0.38 0.62±0.26 propyl cyclopentane 2040-96-2 112.21 AdjP 0 7 1.55 0.84 0.40 0.67±0.30 cis-hydrindane; bicyclo[4.3.0]nonane 496-10-6 124.22 AdjP 0 7 b 1.16 0.64 0.23 0.47±0.27

c9 bicycloalkanes 124.22 LM 0 8 b 1.25 0.71 0.31 0.55±0.26 1,2,3-trimethylcyclohexane 1678-97-3 126.24 AdjP 0 7 b 1.08 0.65 0.26 0.48±0.25 1,3,5-trimethylcyclohexane 1839-63-0 126.24 Exp 0 7 b 1.03 0.57 0.21 0.42±0.23 c9 cycloalkanes 126.24 LM 0 8 b 1.23 0.69 0.31 0.54±0.26 1,1,3-trimethyl cyclohexane 3073-66-3 126.24 Exp 1 0 6 b 1.08 0.60 0.25 0.46±0.23Table C-1 (continued)

76 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
1-ethyl-4-methyl cyclohexane 3728-56-1 126.24 AdjP 0 7 b 1.30 0.72 0.30 0.55±0.27

propyl cyclohexane 1678-92-8 126.24 Exp 0 7 b 1.17 0.67 0.31 0.52±0.24 c10 bicycloalkanes 138.25 LM 0 8 b 0.97 0.57 0.24 0.43±0.22 isobutylclohexane; (2- methylpropyl) cyclohexane 1678-98-4 140.27 LM 0 8 b 0.88 0.53 0.22 0.40±0.20

sec-butylcyclohexane 7058-01-7 140.27 LM 0 8 b 0.88 0.53 0.22 0.40±0.20 c10 cycloalkanes 140.27 LM 0 8 b 0.96 0.56 0.23 0.42±0.21 1,3-diethyl-cyclohexane 1678-99-5 140.27 AdjP 0 7 b 1.13 0.64 0.26 0.48±0.25 1,4-diethyl-cyclohexane 1679-00-1 140.27 Exp 0 7 b 1.11 0.62 0.26 0.47±0.24 1-methyl-3-isopropyl cyclohexane 16580-24-8 140.27 Exp 0 7 b 0.90 0.54 0.22 0.40±0.20

butyl cyclohexane 1678-93-9 140.27 Exp 1 0 6 b 0.88 0.53 0.22 0.40±0.20 c11 bicycloalkanes 152.28 LM 0 8 b 0.80 0.48 0.172 0.34±0.20 c11 cycloalkanes 154.29 LM 0 8 b 0.79 0.47 0.169 0.34±0.20 1,3-diethyl-5-methyl cyclohexane 164259-42-1 154.29 Exp 0 7 b 0.93 0.52 0.20 0.38±0.21

1-ethyl-2-propyl cyclohexane 62238-33-9 154.29 AdjP 0 7 b 0.70 0.44 0.140 0.30±0.20

pentyl cyclohexane 4292-92-6 154.29 Exp 0 7 b 0.74 0.45 0.172 0.33±0.18 c12 tricycloalkanes 164.29 LM 0 8 b 0.71 0.42 0.130 0.29±0.19 c12 bicycloalkanes 166.30 LM 0 8 b 0.70 0.42 0.128 0.29±0.19 c12 cycloalkanes 168.32 LM 0 8 b 0.69 0.41 0.127 0.29±0.19 1,3,5-triethyl cyclohexane 164259-43-2 168.32 Exp 0 7 b 0.92 0.51 0.20 0.38±0.21 1-methyl-4-pentyl cyclohexane 75736-67-3 168.32 Exp 0 7 b 0.62 0.38 0.114 0.26±0.18

hexyl cyclohexane 4292-75-5 168.32 AdjP 1 2 0 2 b 0.54 0.34 0.065 0.21±0.18 c13 tricycloalkanes 178.31 LM 0 8 b 0.61 0.38 0.111 0.26±0.17 c13 bicycloalkanes 180.33 LM 0 8 b 0.61 0.37 0.110 0.25±0.17 c13 cycloalkanes 182.35 LM 0 8 b 0.60 0.37 0.109 0.25±0.17 1,3-diethyl-5-propyl cyclohexane 182.35 Exp 0 7 b 0.86 0.48 0.193 0.36±0.19

1-methyl-2-hexylcyclohexane 92031-93-1 182.35 Exp 0 7 b 0.49 0.32 0.086 0.21±0.16

heptyl cyclohexane 5617-41-4 182.35 AdjP 0 7 b 0.45 0.30 0.049 0.181±0.166 c14 tricycloalkanes 192.34 LM 0 8 b 0.57 0.35 0.101 0.24±0.17 c14 bicycloalkanes 194.36 LM 0 8 b 0.57 0.35 0.100 0.23±0.16 c14 cycloalkanes 196.37 LM 0 8 b 0.56 0.34 0.099 0.23±0.16 1,3-dipropyl-5-ethyl cyclohexane 196.37 Exp 0 7 b 0.82 0.46 0.186 0.34±0.18

trans 1-methyl-4-heptyl cyclohexane 205324-73-8 196.37 Exp 0 7 b 0.44 0.29 0.069 0.186±0.148

octyl cyclohexane 1795-15-9 196.37 AdjP 2 0 7 b 0.42 0.28 0.044 0.168±0.157 c15 tricycloalkanes 206.37 LM 0 8 b 0.54 0.33 0.097 0.22±0.16 c15 bicycloalkanes 208.38 LM 0 8 b 0.53 0.33 0.096 0.22±0.15 c15 cycloalkanes 210.40 LM 0 8 b 0.53 0.32 0.095 0.22±0.15 1,3,5-tripropyl cyclohexane 210.40 Exp 0 7 b 0.78 0.43 0.179 0.33±0.17 1-methyl-2-octyl cyclohexane 210.40 AdjP 0 7 b 0.42 0.28 0.075 0.182±0.139

nonyl cyclohexane 2883-02-5 210.40 AdjP 0 7 b 0.38 0.26 0.034 0.149±0.149Table C-1 (continued)

77 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
c16 tricycloalkanes 220.39 LM 0 8 b 0.50 0.31 0.091 0.21±0.15 c16 bicycloalkanes 222.41 LM 0 8 b 0.50 0.31 0.090 0.21±0.14 c16 cycloalkanes 224.43 LM 0 8 b 0.47 0.29 0.082 0.196±0.142 1,3-propyl-5-butyl cyclohexane 224.43 Exp 0 7 b 0.67 0.38 0.152 0.28±0.16

1-methyl-4-nonyl cyclohexane 39762-40-8 224.43 Exp 0 7 b 0.39 0.26 0.065 0.166±0.132

decyl cyclohexane 1795-16-0 224.43 AdjP 0 7 b 0.35 0.24 0.031 0.138±0.141 c17 tricycloalkanes 234.42 LM 0 8 b 0.47 0.29 0.086 0.197±0.137 c17 bicycloalkanes 236.44 LM 0 8 b 0.47 0.29 0.085 0.195±0.136 c17 cycloalkanes 238.45 LM 0 8 b 0.44 0.28 0.077 0.184±0.134 c18 tricycloalkanes 248.45 LM 0 8 b 0.45 0.27 0.081 0.186±0.129 c18 bicycloalkanes 250.46 LM 0 8 b 0.44 0.27 0.080 0.185±0.128 c18 cycloalkanes 252.48 LM 0 8 b 0.42 0.26 0.073 0.174±0.127 c19 tricycloalkanes 262.47 LM 0 8 b 0.42 0.26 0.076 0.176±0.122 c19 bicycloalkanes 264.49 LM 0 8 b 0.42 0.26 0.076 0.175±0.121 c19 cycloalkanes 266.51 LM 0 8 b 0.39 0.25 0.069 0.165±0.120 c20 tricycloalkanes 276.50 LM 0 8 b 0.40 0.25 0.073 0.167±0.116 c20 bicycloalkanes 278.52 LM 0 8 b 0.40 0.24 0.072 0.166±0.115 c20 cycloalkanes 280.53 LM 0 8 b 0.37 0.23 0.066 0.157±0.114 c21 tricycloalkanes 290.53 LM 0 8 b 0.38 0.23 0.069 0.159±0.110 c21 bicycloalkanes 292.54 LM 0 8 b 0.38 0.23 0.069 0.158±0.110 c21 cycloalkanes 294.56 LM 0 8 b 0.36 0.22 0.063 0.149±0.108 c22 tricycloalkanes 304.55 LM 0 8 b 0.36 0.22 0.066 0.152±0.105 c22 bicycloalkanes 306.57 LM 0 8 b 0.36 0.22 0.065 0.151±0.105 c22 cycloalkanes 308.58 LM 0 8 b 0.34 0.21 0.060 0.142±0.104 ethene 74-85-1 28.05 Exp 1 1 0 3 d 8.88 3.72 2.29 3.47±1.30 propene 115-07-1 42.08 Exp 1 1 0 3 d 11.57 4.53 2.79 4.29±1.66 1-butene 106-98-9 56.11 Exp 1 3 0 3 d 9.57 3.83 2.35 3.59±1.33 c4 terminal alkenes 56.11 LM 0 7 9.57 3.83 2.35 3.59±1.33 1-pentene 109-67-1 70.13 Exp 1 0 6 d 7.07 2.87 1.75 2.67±0.99 3-methyl-1-butene 563-45-1 70.13 Exp 1 0 6 d 6.86 2.80 1.72 2.61±0.95 c5 terminal alkenes 70.13 LM 0 7 7.07 2.87 1.75 2.67±0.99 1-hexene 592-41-6 84.16 Exp 1 4 0 4 d 5.35 2.29 1.41 2.11±0.74 3,3-dimethyl-1-butene 558-37-2 84.16 Exp 1 0 8 d 5.68 2.41 1.50 2.23±0.78 3-methyl-1-pentene 760-20-3 84.16 Exp 0 8 6.00 2.50 1.52 2.31±0.83 4-methyl-1-pentene 691-37-2 84.16 Exp 0 8 5.55 2.28 1.37 2.11±0.78 c6 terminal alkenes 84.16 LM 0 8 5.35 2.29 1.41 2.11±0.74 1-heptene 592-76-7 98.19 AdjP 1 0 8 d 4.29 1.86 1.09 1.68±0.61 3,4-dimethyl-1-pentene 7385-78-6 98.19 Exp 0 8 4.72 1.98 1.18 1.81±0.66 3-methyl-1-hexene 3404-61-3 98.19 Exp 0 8 4.27 1.86 1.10 1.69±0.61 1-octene 111-66-0 112.21 Exp 0 8 3.14 1.37 0.77 1.22±0.47 c8 terminal alkenes 112.21 LM 0 8 3.14 1.37 0.77 1.22±0.47 2,4,4-trimethyl-1-pentene 107-39-1 112.21 Exp 0 8 3.31 1.23 0.66 1.13±0.52 1-nonene 124-11-8 126.24 Exp 0 8 2.49 1.11 0.60 0.97±0.38 c9 terminal alkenes 126.24 LM 0 8 2.49 1.11 0.60 0.97±0.38 1-decene 872-05-9 140.27 Exp 0 8 2.07 0.93 0.49 0.80±0.33 c10 terminal alkenes 140.27 LM 0 8 2.07 0.93 0.49 0.80±0.33 1-undecene 821-95-4 154.29 Exp 0 8 1.77 0.80 0.41 0.68±0.29Table C-1 (continued)

78 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

c11 terminal alkenes 154.29 LM 0 8 1.77 0.80 0.41 0.68±0.29 c12 terminal alkenes 168.32 LM 0 8 1.56 0.71 0.36 0.60±0.26 1-dodecene 112-41-4 168.32 Exp 0 8 1.56 0.71 0.36 0.60±0.26 1-tridecene 2437-56-1 182.35 Exp 0 8 1.40 0.64 0. 32 0.54±0.23 c13 terminal alkenes 182.35 LM 0 8 1.40 0.64 0.32 0.54±0.23 1-tetradecene 1120-36-1 196.37 Exp 0 8 1.27 0.58 0.29 0.49±0.21 c14 terminal alkenes 196.37 LM 0 8 1.27 0.58 0.29 0.49±0.21 1-pentadecene 13360-61-7 210.40 LM 0 8 1.18 0.54 0.27 0.46±0.20 c15 terminal alkenes 210.40 LM 0 8 1.18 0.54 0.27 0.46±0.20 isobutene 115-11-7 56.11 Exp 1 3 0 3 6.31 2.23 1.23 2.10±1.00 2-methyl-1-butene 563-46-2 70.13 Exp 1 0 8 6.38 2.35 1.35 2.21±0.97 2,3-dimethyl-1-butene 563-78-0 84.16 Exp 0 8 4.71 1.78 1.01 1.65±0.71 2-ethyl-1-butene 760-21-4 84.16 Exp 0 8 5.04 1.89 1.06 1.76±0.77 2-methyl-1-pentene 763-29-1 84.16 Exp 1 0 8 5.25 1.94 1.09 1.82±0.80 2,4-dimethyl-1-pentene 2213-32-3 98.19 AdjP 0 8 5.91 2.40 1.42 2.21±0.86 2,3-dimethyl-1-pentene 3404-72-6 98.19 Exp 0 8 5.04 2.10 1.21 1.91±0.74 3,3-dimethyl-1-pentene 3404-73-7 98.19 Exp 0 8 4.75 2.13 1.35 1.96±0.64 2-methyl-1-hexene 6094-02-6 98.19 Exp 0 8 4.99 2.08 1.19 1.89±0.74 2,3,3-trimethyl-1-butene 594-56-9 98.19 Exp 0 8 4.42 1.79 1.06 1.65±0.64 c7 terminal alkenes 98.19 LM 0 8 4.29 1.86 1.09 1.68±0.61 3-methyl-2-isopropyl-1- butene 111823-35-9 112.21 AdjP 0 8 3.21 1.36 0.74 1.21±0.49

4,4-dimethyl-1-pentene 762-62-9 126.24 Exp 0 8 3.02 1.29 0.72 1.15±0.45 cis -2-butene 590-18-1 56.11 Exp 1 0 6 14.26 5.26 3.18 5.06±2.18

trans -2-butene 624-64-6 56.11 Exp 1 1 0 3 15.20 5.51 3.29 5.30±2.37 c4 internal alkenes 56.11 LM 0 7 14.73 5.39 3.23 5.17±2.27 2-methyl-2-butene 513-35-9 70.13 Exp 1 0 6 14.20 4.83 2.73 4.68±2.41 cis -2-pentene 627-20-3 70.13 Exp 1 0 6 10.28 3.99 2.46 3.79±1.47

trans -2-pentene 646-04-8 70.13 Exp 1 0 6 10.47 4.02 2.46 3.82±1.51 2-pentenes 70.13 LM 0 7 10.38 4.01 2.46 3.80±1.49 c5 internal alkenes 70.13 LM 0 7 10.38 4.01 2.46 3.80±1.49 3-methyl-trans-2-pentene 616-12-6 84.16 Exp 0 7 11.66 4.15 2.39 3.98±1.92 2,3-dimethyl-2-butene 563-79-1 84.16 Exp 1 0 8 12.58 4.03 2.14 3.94±2.30 2-methyl-2-pentene 625-27-4 84.16 Exp 1 0 8 11.03 3.88 2.22 3.73±1.79 cis 4-methyl-2-pentene 84.16 LM 0 8 8.04 3.14 1.91 2.96±1.16 cis-2-hexene 7688-21-3 84.16 Exp 0 8 8.22 3.22 1.98 3.04±1.17 cis-3-hexene 7642-09-3 84.16 Exp 0 8 7.44 3.03 1.89 2.84±1.02 cis-3-methyl-2-pentene 922-62-3 84.16 Exp 0 8 12.52 4.40 2.53 4.23±2.07 trans 3-methyl-2-pentene 20710-38-7 84.16 Exp 0 8 13.20 4.61 2.64 4.44±2.18 trans 4-methyl-2-pentene 674-76-0 84.16 Exp 1 0 8 8.04 3.14 1.91 2.96±1.16 trans-2-hexene 4050-45-7 84.16 Exp 0 8 8.55 3.29 1.99 3.11±1.24 trans-3-hexene 13269-52-8 84.16 Exp 0 8 7.42 3.01 1.87 2.82±1.02 2-hexenes 592-43-8 84.16 LM 0 8 8.38 3.25 1.98 3.08±1.21 c6 internal alkenes 84.16 LM 0 8 8.38 3.25 1.98 3.08±1.21 4,4-dimethyl-cis-2-pentene 762-63-0 98.19 Exp 0 8 6.59 2.56 1.53 2.41±0.98 2,4-dimethyl-2-pentene 625-65-0 98.19 Exp 0 8 9.31 3.27 1.84 3.13±1.53 2-methyl-2-hexene 2738-19-4 98.19 Exp 0 8 9.50 3.33 1.86 3.18±1.57 3-ethyl-2-pentene 816-79-5 98.19 Exp 0 8 9.76 3.54 2.05 3.38±1.60 3-methyl-trans-3-hexene 3899-36-3 98.19 Exp 0 8 9.70 3.54 2.05 3.37±1.54Table C-1 (continued)

79 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
cis-2-heptene 6443-92-1 98.19 Exp 0 8 7.08 2.79 1.69 2.62±1.03 2-methyl-trans-3-hexene 692-24-0 98.19 Exp 0 8 6.11 2.51 1.55 2.34±0.85 3-methyl-cis-3-hexene 4914-89-0 98.19 Exp 0 8 9.69 3.53 2.05 3.36±1.54 3,4-dimethyl-cis-2-pentene 4914-91-4 98.19 Exp 0 8 9.19 3.23 1.79 3.08±1.56 2,3-dimethyl-2-pentene 10574-37-5 98.19 Exp 1 0 8 9.79 3.27 1.75 3.15±1.74 cis-3-heptene 7642-10-6 98.19 Exp 0 8 6.18 2.54 1.56 2.36±0.86 trans 4,4-dimethyl-2- pentene 690-08-4 98.19 Exp 1 0 8 6.58 2.56 1.53 2.41±0.98

trans-2-heptene 14686-13-6 98.19 Exp 1 0 8 7.06 2.79 1.69 2.62±1.02 trans-3-heptene 14686-14-7 98.19 Exp 0 8 6.17 2.53 1.56 2.36±0.86 2-heptenes 98.19 LM 0 8 6.17 2.54 1.56 2.36±0.86 c7 internal alkenes 98.19 LM 0 8 6.17 2.53 1.56 2.36±0.86 trans-2-octene 13389-42-9 112.21 Exp 0 8 5.92 2.34 1.40 2.19±0.87 2-methyl-2-heptene 627-97-4 112.21 Exp 0 8 8.35 2.95 1.64 2.81±1.38 cis-4-octene 7642-15-1 112.21 AdjP 0 8 4.60 1.93 1.13 1.75±0.67 trans 2,2-dimethyl 3- hexene 690-93-7 112.21 Exp 0 8 4.86 2.05 1.26 1.89±0.68

trans 2,5-dimethyl 3- hexene 692-70-6 112.21 AdjP 0 8 4.68 1.99 1.24 1.84±0.65

trans-3-octene 14919-01-8 112.21 AdjP 0 8 5.20 2.18 1.31 2.00±0.74 trans-4-octene 14850-23-8 112.21 AdjP 1 0 8 4.69 1.94 1.13 1.77±0.69 3-octenes 112.21 LM 0 8 5.20 2.18 1.31 2.00±0.74 c8 internal alkenes 112.21 LM 0 8 4.69 1.94 1.13 1.77±0.69 2,4,4-trimethyl-2-pentene 107-40-4 112.21 Exp 0 8 6.30 2.28 1.26 2.14±1.02 4-nonene 2198-23-4 126.24 LM 0 8 4.42 1.86 1.10 1.69±0.64 3-nonenes 126.24 LM 0 8 4.42 1.86 1.10 1.69±0.64 c9 internal alkenes 126.24 LM 0 8 4.42 1.86 1.10 1.69±0.64 trans-4-nonene 10405-85-3 126.24 AdjP 0 8 4.42 1.86 1.10 1.69±0.64 3,4-diethyl-2-hexene 59643-70-8 140.27 Exp 0 8 3.26 1.44 0.79 1.28±0.51 cis-5-decene 7433-78-5 140.27 AdjP 0 8 3.56 1.52 0.85 1.36±0.55 trans-4-decene 19398-89-1 140.27 AdjP 0 8 3.76 1.59 0.92 1.44±0.56 c10 3-alkenes 140.27 LM 0 8 3.76 1.59 0.92 1.44±0.56 c10 internal alkenes 140.27 LM 0 8 3.76 1.59 0.92 1.44±0.56 trans-5-undecene 764-97-6 154.29 AdjP 0 8 3.49 1.49 0.87 1.35±0.52 c11 3-alkenes 154.29 LM 0 8 3.49 1.49 0.87 1.35±0.52 c11 internal alkenes 154.29 LM 0 8 3.49 1.49 0.87 1.35±0.52 c12 2-alkenes 168.32 LM 0 8 3.05 1.31 0.74 1.17±0.46 c12 3-alkenes 168.32 LM 0 8 3.05 1.31 0.74 1.17±0.46 c12 internal alkenes 168.32 LM 0 8 3.05 1.31 0.74 1.17±0.46 trans-5-dodecene 7206-16-8 168.32 AdjP 0 8 3.05 1.31 0.74 1.17±0.46 trans-5-tridecene 23051-84-5 182.35 Exp 0 8 2.51 1.09 0.62 0.97±0.39 c13 3-alkenes 182.35 LM 0 8 2.51 1.09 0.62 0.97±0.39 c13 internal alkenes 182.35 LM 0 8 2.51 1.09 0.62 0.97±0.39 trans-5-tetradecene 41446-66-6 196.37 Exp 0 8 2.28 0.99 0.57 0.88±0.36 c14 3-alkenes 196.37 LM 0 8 2.28 0.99 0.57 0.88±0.36 c14 internal alkenes 196.37 LM 0 8 2.28 0.99 0.57 0.88±0.36 trans-5-pentadecene 74392- 33-9 210.40 Exp 0 8 2.10 0.91 0.52 0.81±0.33 c15 3-alkenes 210.40 LM 0 8 2.10 0.91 0.52 0.81±0.33 c15 internal alkenes 210.40 LM 0 8 2.10 0.91 0.52 0.81±0.33Table C-1 (continued)

80 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

c4 alkenes 56.11 LM 0 8 12.15 4.61 2.79 4.38±1.79 c5 alkenes 70.13 LM 0 8 8.72 3.44 2.10 3.24±1.24 c6 alkenes 84.16 LM 0 8 6.69 2.71 1.63 2.52±0.96 c7 alkenes 98.19 LM 0 8 5.23 2.20 1.33 2.02±0.73 c8 alkenes 112.21 LM 0 8 3.91 1.65 0.95 1.50±0.58 c9 alkenes 126.24 LM 0 8 3.46 1.48 0.85 1.33±0.51 c10 alkenes 140.27 LM 0 8 2.92 1.26 0.71 1.12±0.44 c11 alkenes 154.29 LM 0 8 2.63 1.15 0.64 1.02±0.40 c12 alkenes 168.32 LM 0 8 2.30 1.01 0.55 0.89±0.36 c13 alkenes 182.35 LM 0 8 1.95 0.86 0.47 0.75±0.31 c14 alkenes 196.37 LM 0 8 1.78 0.79 0.43 0.69±0.29 c15 alkenes 210.40 LM 0 8 1.64 0.73 0.39 0.63±0.26 cyclopentene 142-29-0 68.12 Exp 1 0 8 6.69 2.55 1.53 2.41±0.96 3-methylcyclopentene 1120-62-3 82.14 Exp 0 8 5.00 2.03 1.25 1.90±0.70 1-methyl cyclopentene 693-89-0 82.14 AdjP 0 8 12.45 4.46 2.57 4.27±1.99 cyclohexene 110-83-8 82.14 Exp 1 4 0 4 4.89 2.02 1.25 1.88±0.68 1-methyl cyclohexene 591-49-1 96.17 Exp 1 0 8 6.58 2.48 1.42 2.33±1.04 4-methyl cyclohexene 591-47-9 96.17 Exp 0 8 4.08 1.68 1.03 1.56±0.58 1,2-dimethyl cyclohexene 1674-10-8 110.20 Exp 0 8 5.57 2.10 1.11 1.93±0.94 1,2-propadiene (allene) 463-49-0 40.06 Exp 1 0 11 8.15 3.90 2.48 3.55±1.14 1-buten-3-yne (vinyl acetylene) 689-97-4 52.07 LM 0 11 10.32 4.13 2.54 3.87±1.43

1,2-butadiene 590-19-2 54.09 Exp 1 0 11 9.09 3.98 2.50 3.67±1.25 1,3-butadiene 106-99-0 54.09 Exp 1 0 6 12.45 4.77 2.91 4.51±1.73 trans 1,3-pentadiene 2004-70-8 68.12 Exp 0 8 12.33 4.82 2.97 4.54±1.70 cis 1,3-pentadiene 1574-41-0 68.12 LM 0 8 12.33 4.82 2.97 4.54±1.70 1,4-pentadiene 591-93-5 68.12 Exp 1 0 8 9.05 3.73 2.39 3.51±1.20 1,2-pentadiene 591-95-7 68.12 Exp 1 0 11 7.68 3.21 1.99 2.98±1.05 3-methyl-1,2-butadiene 598-25-4 68.12 Exp 1 0 11 10.11 4.01 2.46 3.76±1.40 isoprene 78-79-5 68.12 Exp 1 2 0 1 10.48 3.97 2.36 3.74±1.49 trans,trans-2,4-hexadiene 5194-51-4 82.14 LM 0 8 8.76 3.37 2.04 3.19±1.27 trans 1,3-hexadiene 20237-34-7 82.14 LM 0 8 10.23 3.99 2.47 3.77±1.41 trans 1,4-hexadiene 7319-00-8 82.14 Exp 1 0 8 8.52 3.35 2.04 3.15±1.21 c6 cyclic or di-olefins 82.14 LM 0 8 8.59 3.33 2.03 3.16±1.24 c7 cyclic or di-olefins 96.17 LM 0 8 7.21 2.85 1.72 2.67±1.05 c8 cyclic or di-olefins 110.20 LM 0 8 4.78 1.98 1.16 1.80±0.70 c9 cyclic or di-olefins 124.22 LM 0 8 4.49 1.89 1.12 1.72±0.65 c10 cyclic or di-olefins 138.25 LM 0 8 3.82 1.61 0.94 1.46±0.57 c11 cyclic or di-olefins 152.28 LM 0 8 3.54 1.51 0.88 1.37±0.53 c12 cyclic or di-olefins 166.30 LM 0 8 3.08 1.32 0.75 1.18±0.47 c13 cyclic or di-olefins 180.33 LM 0 8 2.54 1.10 0.63 0.98±0.40 c14 cyclic or di-olefins 194.36 LM 0 8 2.31 1.00 0.57 0.89±0.36 c15 cyclic or di-olefins 208.38 LM 0 8 2.12 0.92 0.52 0.82±0.34 cyclopentadiene 542-92-7 66.10 LM 0 8 6.89 2.63 1.58 2.48±0.98 3-carene 13466-78-9 136.23 Exp 1 3 0 4 3.18 1.26 0.73 1.17±0.47 a-pinene 80-56-8 136.23 Exp 1 2 0 4 4.49 1.66 0.88 1.53±0.72 b-pinene 127-91-3 136.23 Exp 1 2 0 4 3.43 1.41 0.76 1.26±0.53 d-limonene 5989-27-5 136.23 Exp 1 2 0 4 4.50 1.71 0.96 1.60±0.72 sabinene 3387-41-5 136.23 Exp 1 3 0 4 4.08 1.67 0.93 1.51±0.62Table C-1 (continued)

81 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
terpene 136.23 LM 0 8 3.98 1.55 0.84 1.41±0.62 Terpinolene 586-62-9 136.23 Exp 0 8 6.14 2.21 1.17 2.09±1.09 styrene 100-42-5 104.15 Exp 1 2 0 2 1.66 0.186 -0.47 -.008±0.521 allylbenzene 300-57-2 118.18 LM 0 8 1.46 0.164 -0.41 -.007±0.460 a-methyl styrene 98-83-9 118.18 LM 0 8 1.46 0.164 -0.41 -.007±0.460 c9 styrenes 118.18 LM 0 8 1.46 0.164 -0.41 -.007±0.460 b-methyl styrene 637-50-3 118.18 Exp 1 0 8 0.94 0.113 -0.33 -.035±0.307 c10 styrenes 132.20 LM 0 8 1.31 0.147 -0.37 -.006±0.411 benzene 71-43-2 78.11 Exp 1 2 0? 4 0.69 0.104 -0.146 0.042±0.202 toluene 108-88-3 92.14 Exp 1 2 0 4 3.93 1.38 0.55 1.20±0.70 ethyl benzene 100-41-4 106.17 Exp 1 3 0 4 2.96 1.15 0.50 0.99±0.51 c9 monosubstituted benzenes 120.19 LM 0 8 1.96 0.80 0.35 0.68±0.34

n-propyl benzene 103-65-1 120.19 Exp 1 0 8 1.96 0.80 0.35 0.68±0.34 isopropyl benzene (cumene) 98-82-8 120.19 Exp 1 0 8 2.45 0.94 0.39 0.81±0.43

c10 monosubstituted benzenes 134.22 Exp 0 8 2.29 0.92 0.41 0.79±0.39

n-butyl benzene 104-51-8 134.22 LM 0 8 2.29 0.92 0.41 0.79±0.39 s-butyl benzene 135-98-8 134.22 LM 0 8 2.29 0.92 0.41 0.79±0.39 t-butyl benzene 98-06-6 134.22 Exp 1 0 8 1.91 0.70 0.27 0.60±0.35 n-pentylbenzene 538-68-1 148.24 LM 0 8 2.04 0.84 0.38 0.72±0.34 c11 monosubstituted benzenes 148.24 Exp 0 8 2.04 0.84 0.38 0.72±0.34

c12 monosubstituted benzenes 162.27 Exp 0 8 1.84 0.77 0.36 0.66±0.31

c13 monosubstituted benzenes 176.30 Exp 0 8 1.68 0.71 0.34 0.61±0.28

c14 monosubstituted benzenes 190.32 Exp 0 8 1.54 0.66 0.32 0.57±0.26

c15 monosubstituted benzenes 204.35 Exp 0 8 1.43 0.62 0.30 0.53±0.24

c16 monosubstituted benzenes 218.38 Exp 0 8 1.33 0.58 0.29 0.50±0.22

c17 monosubstituted benzenes 232.40 LM 0 8 1.25 0.55 0.27 0.47±0.20

c18 monosubstituted benzenes 246.43 LM 0 8 1.18 0.52 0.25 0.44±0.19

c19 monosubstituted benzenes 260.46 LM 0 8 1.11 0.49 0.24 0.42±0.18

c20 monosubstituted benzenes 274.48 LM 0 8 1.06 0.46 0.23 0.40±0.17

c21 monosubstituted benzenes 288.51 LM 0 8 1.01 0.44 0.22 0.38±0.16

c22 monosubstituted benzenes 302.54 LM 0 8 0.96 0.42 0.21 0.36±0.16

c8 disubstituted benzenes 1330-20-7 106.17 LM 0 8 7.72 2.59 1.21 2.37±1.26 m-xylene 108-38-3 106.17 Exp 1 1 0 4 9.73 3.20 1.55 2.97±1.57 o-xylene 95-47-6 106.17 Exp 1 2 0 4 7.58 2.58 1.20 2.34±1.24 p-xylene 106-42-3 106.17 Exp 1 3 0 4 5.78 1.98 0.86 1.77±0.97Table C-1 (continued)

82 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

c9 disubstituted benzenes 120.19 LM 0 8 5.78 2.01 0.94 1.82±0.94 m-ethyl toluene 620-14-4 120.19 Exp 1 0 8 7.39 2.49 1.20 2.29±1.19 o-ethyl toluene 611-14-3 120.19 Exp 1 0 8 5.54 1.96 0.91 1.76±0.91 p-ethyl toluene 622-96-8 120.19 Exp 1 0 8 4.39 1.59 0.72 1.41±0.73 o-cymene; 1-methyl-2-(1- methylethyl)benzene 527-84-4 134.22 LM 0 8 5.43 1.91 0.91 1.73±0.88

1-methyl-2-npropylbenzene 1074-17-5 134.22 LM 0 8 5.43 1.91 0.91 1.73±0.88

m-cymene; 1-methyl-3-(1- methylethyl)benzene 535-77-3 134.22 LM 0 8 7.08 2.39 1.17 2.21±1.13

1-methyl-3-npropylbenzene 1074-43-7 134.22 LM 0 8 7.08 2.39 1.17 2.21±1.13

1-methyl-4-npropylbenzene 1074-55-1 134.22 LM 0 8 4.39 1.58 0.73 1.41±0.71

c10 disubstituted benzenes 134.22 LM 0 8 5.64 1.96 0.94 1.78±0.91 m-c10 disubstituted benzenes 134.22 Exp 0 8 7.08 2.39 1.17 2.21±1.13

o-c10 disubstituted benzenes 134.22 Exp 0 8 5.43 1.91 0.91 1.73±0.88

p-c10 disubstituted benzenes 134.22 Exp 0 8 4.39 1.58 0.73 1.41±0.71

m-diethyl benzene 141-93-5 134.22 LM 0 8 7.08 2.39 1.17 2.21±1.13 o-diethyl benzene 135-01-3 134.22 LM 0 8 5.43 1.91 0.91 1.73±0.88 1-methyl-4-isopropylbenzene (pcymene) 99-87-6 134.22 Exp 1 0 8 4.41 1.57 0.71 1.40±0.72

p-diethyl benzene 105-05-5 134.22 LM 0 8 4.39 1.58 0.73 1.41±0.71 m-c11 disubstituted benzenes 148.24 Exp 0 8 6.12 2.08 1.03 1.92±0.98

o-c11 disubstituted benzenes 148.24 Exp 0 8 4.68 1.67 0.80 1.51±0.75

p-c11 disubstituted benzenes 148.24 Exp 0 8 3.82 1.40 0.66 1.25±0.62

1-butyl-2-methylbenzene 148.24 LM 0 8 4.68 1.67 0.80 1.51±0.75 1-ethyl-2-n-propylbenzene 148.24 LM 0 8 4.68 1.67 0.80 1.51±0.75 o-t-butyl toluene; 1-(1,1- dimethylethyl)-2- methylbenzene 1074-92-6 148.24 LM 0 8 4.68 1.67 0.80 1.51±0.75

1-methyl-3-n-butylbenzene 1595-04-6 148.24 LM 0 8 6.12 2.08 1.03 1.92±0.98

p-Isobutyl toluene; 1- methyl-4(2-methylpropyl) benzene 5161-04-6 148.24 LM 0 8 3.82 1.40 0.66 1.25±0.62

c11 disubstituted benzenes 148.24 LM 0 8 4.88 1.72 0.83 1.56±0.78 m-c12 disubstituted benzenes 162.27 Exp 0 8 5.48 1.87 0.92 1.73±0.87

o-c12 disubstituted benzenes 162.27 Exp 0 8 4.18 1.50 0.72 1.35±0.67

p-c12 disubstituted benzenes 162.27 Exp 0 8 3.43 1.26 0.60 1.13±0.55Table C-1 (continued)

83 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
1,3-di-n-propylbenzene 162.27 LM 0 8 4.18 1.50 0.72 1.35±0.67 1,4 diisopropyl benzene 162.27 LM 0 8 3.43 1.26 0.60 1.13±0.55 3-isopropyl cumene; 1,3- diisopropyl benzene 99-62-7 162.27 LM 0 8 5.48 1.87 0.92 1.73±0.87

c12 disubstituted benzenes 162.27 LM 0 8 4.36 1.54 0.75 1.40±0.70 m-c13 disubstituted benzenes 176.30 Exp 0 8 4.90 1.68 0.83 1.55±0.78

o-c13 disubstituted benzenes 176.30 Exp 0 8 3.73 1.35 0.66 1.22±0.60

p-c13 disubstituted benzenes 176.30 Exp 0 8 3.08 1.15 0.55 1.02±0.49

c13 disubstituted benzenes 176.30 LM 0 8 3.90 1.39 0.68 1.27±0.62 m-c14 disubstituted benzenes 190.32 Exp 0 8 4.42 1.53 0.76 1.41±0.70

o-c14 disubstituted benzenes 190.32 Exp 0 8 3.36 1.23 0.60 1.11±0.54

p-c14 disubstituted benzenes 190.32 Exp 0 8 2.79 1.05 0.51 0.93±0.44

c14 disubstituted benzenes 190.32 LM 0 8 3.52 1.27 0.62 1.15±0.56 c15 disubstituted benzenes 204.35 LM 0 8 3.20 1.16 0.58 1.06±0.51 m-c15 disubstituted benzenes 204.35 Exp 0 8 4.02 1.40 0.70 1.29±0.64

o-c15 disubstituted benzenes 204.35 Exp 0 8 3.05 1.12 0.55 1.01±0.49

p-c15 disubstituted benzenes 204.35 Exp 0 8 2.54 0.96 0.47 0.86±0.40

m-c16 disubstituted benzenes 218.38 Exp 0 8 3.68 1.29 0.65 1.19±0.58

o-c16 disubstituted benzenes 218.38 Exp 0 8 2.79 1.04 0.51 0.93±0.44

p-c16 disubstituted benzenes 218.38 Exp 0 8 2.33 0.89 0.44 0.80±0.37

c16 disubstituted benzenes 218.38 LM 0 8 2.93 1.07 0.53 0.97±0.46 c17 disubstituted benzenes 232.40 LM 0 8 2.76 1.01 0.50 0.91±0.44 c18 disubstituted benzenes 246.43 LM 0 8 2.60 0.95 0.47 0.86±0.41 c19 disubstituted benzenes 260.46 LM 0 8 2.46 0.90 0.45 0.82±0.39 c20 disubstituted benzenes 274.48 LM 0 8 2.33 0.85 0.42 0.77±0.37 c21 disubstituted benzenes 288.51 LM 0 8 2.22 0.81 0.40 0.74±0.35 c22 disubstituted benzenes 302.54 LM 0 8 2.12 0.77 0.39 0.70±0.33 isomers of ethylbenzene 106.17 LM 0 8 5.38 1.88 0.86 1.69±0.89 isomers of propylbenzene 120.19 LM 0 8 6.19 2.18 1.10 2.00±0.97 c9 trisubstituted benzenes 25551-13-7 120.19 LM 0 8 10.84 3.72 2.02 3.50±1.66 1,2,3-trimethyl benzene 526-73-8 120.19 Exp 1 2 0 4 11.94 4.07 2.19 3.83±1.83 1,2,4-trimethyl benzene 95-63-6 120.19 Exp 1 2 0 4 8.83 3.14 1.71 2.93±1.34 1,3,5-trimethyl benzene 108-67-8 120.19 Exp 1 2 0 4 11.75 3.96 2.15 3.76±1.81 1,2,3-c10 trisubstituted benzenes 134.22 Exp 0 8 10.16 3.50 1.90 3.29±1.55

1,2,4-c10 trisubstituted benzenes 134.22 Exp 0 8 7.54 2.71 1.48 2.53±1.14Table C-1 (continued)

84 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
1,3,5-c10 trisubstituted benzenes 134.22 Exp 0 8 10.10 3.43 1.87 3.25±1.55

1,2,3,4-tetramethylbenzene 488-23-3 134.22 LM 0 8 9.26 3.21 1.75 3.02±1.41 1,2,4,5-tetramethylbenzene 95-93-2 134.22 LM 0 8 9.26 3.21 1.75 3.02±1.41 1,2-dimethyl-3- ethylbenzene 933-98-2 134.22 LM 0 8 10.16 3.50 1.90 3.29±1.55

1,2-dimethyl-4- ethylbenzene 934-80-5 134.22 LM 0 8 7.54 2.71 1.48 2.53±1.14

1,3-dimethyl-2- ethylbenzene 2870-04-4 134.22 LM 0 8 10.16 3.50 1.90 3.29±1.55

1,3-dimethyl-4- ethylbenzene 874-41-9 134.22 LM 0 8 7.54 2.71 1.48 2.53±1.14

1,3-dimethyl-5- ethylbenzene 934-74-7 134.22 LM 0 8 10.10 3.43 1.87 3.25±1.55

1,4-dimethyl-2- ethylbenzene 1758-88-9 134.22 LM 0 8 7.54 2.71 1.48 2.53±1.14

1,2,3,5 tetramethyl benzene 527-53-7 134.22 LM 0 8 9.26 3.21 1.75 3.02±1.41 isomers of butylbenzene 134.22 LM 0 8 5.55 1.98 1.01 1.81±0.87 c10 trisubstituted benzenes 134.22 LM 0 8 9.26 3.21 1.75 3.02±1.41 c10 tetrasubstituted benzenes 134.22 LM 0 8 9.26 3.21 1.75 3.02±1.41

1,2,3-c11 trisubstituted benzenes 148.24 Exp 0 8 8.88 3.07 1.67 2.89±1.36

1,2,4-c11 trisubstituted benzenes 148.24 Exp 0 8 6.61 2.39 1.31 2.23±1.00

1,3,5-c11 trisubstituted benzenes 148.24 Exp 0 8 8.91 3.03 1.65 2.87±1.37

pentamethylbenzene 700-12-9 148.24 LM 0 8 8.13 2.83 1.54 2.66±1.24 1-methyl-3,5- diethylbenzene 2050-24-0 148.24 LM 0 8 8.91 3.03 1.65 2.87±1.37

isomers of pentylbenzene 148.24 LM 0 8 4.86 1.75 0.89 1.60±0.76 c11 trisubstituted benzenes 148.24 LM 0 8 8.13 2.83 1.54 2.66±1.24 c11 tetrasubstituted benzenes 148.24 LM 0 8 8.13 2.83 1.54 2.66±1.24

c11 pentasubstituted benzenes 148.24 LM 0 8 8.13 2.83 1.54 2.66±1.24

1,2,3-c12 trisubstituted benzenes 162.27 Exp 0 8 7.95 2.76 1.49 2.59±1.22

1,2,4-c12 trisubstituted benzenes 162.27 Exp 0 8 5.93 2.15 1.18 2.00±0.90

1,3,5-c12 trisubstituted benzenes 162.27 Exp 0 8 8.02 2.73 1.49 2.58±1.23

1-(1,1-dimethylethyl)-3,5- dimethylbenzene 98-19-1 162.27 LM 0 8 8.02 2.73 1.49 2.58±1.23

isomers of hexylbenzene 162.27 LM 0 8 4.37 1.57 0.80 1.44±0.68 c12 trisubstituted benzenes 162.27 LM 0 8 7.30 2.55 1.39 2.39±1.11 c12 tetrasubstituted benzenes 162.27 LM 0 8 7.30 2.55 1.39 2.39±1.11

c12 pentasubstituted benzenes 162.27 LM 0 8 7.30 2.55 1.39 2.39±1.11Table C-1 (continued)

85 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

c12 hexasubstituted benzenes 162.27 LM 0 8 7.30 2.55 1.39 2.39±1.11

1,2,3-c13 trisubstituted benzenes 176.30 Exp 0 8 7.11 2.48 1.34 2.33±1.09

1,2,4-c13 trisubstituted benzenes 176.30 Exp 0 8 5.33 1.94 1.06 1.80±0.80

1,3,5-c13 trisubstituted benzenes 176.30 Exp 0 8 7.23 2.47 1.35 2.34±1.11

c13 trisubstituted benzenes 176.30 LM 0 8 6.56 2.30 1.25 2.15±1.00 1,2,3-c14 trisubstituted benzenes 190.32 Exp 0 8 6.48 2.26 1.23 2.12±0.99

1,2,4-c14 trisubstituted benzenes 190.32 Exp 0 8 4.86 1.77 0.97 1.65±0.73

1,3,5-c14 trisubstituted benzenes 190.32 Exp 0 8 6.63 2.27 1.23 2.14±1.02

c14 trisubstituted benzenes 190.32 LM 0 8 5.98 2.10 1.15 1.97±0.91 c15 trisubstituted benzenes 204.35 LM 0 8 5.49 1.93 1.05 1.81±0.83 1,2,3-c15 trisubstituted benzenes 204.35 Exp 0 8 5.92 2.07 1.13 1.94±0.90

1,2,4-c15 trisubstituted benzenes 204.35 Exp 0 8 4.45 1.63 0.89 1.51±0.67

1,3,5-c15 trisubstituted benzenes 204.35 Exp 0 8 6.09 2.09 1.14 1.97±0.93

1,2,3-c16 trisubstituted benzenes 218.38 Exp 0 8 5.43 1.91 1.04 1.79±0.83

1,2,4-c16 trisubstituted benzenes 218.38 Exp 0 8 4.09 1.50 0.82 1.39±0.62

1,3,5-c16 trisubstituted benzenes 218.38 Exp 0 8 5.62 1.93 1.05 1.82±0.86

c16 trisubstituted benzenes 218.38 LM 0 8 5.04 1.78 0.97 1.67±0.77 c17 trisubstituted benzenes 232.40 LM 0 8 4.74 1.67 0.91 1.57±0.72 c18 trisubstituted benzenes 246.43 LM 0 8 4.47 1.58 0.86 1.48±0.68 c19 trisubstituted benzenes 260.46 LM 0 8 4.23 1.49 0.81 1.40±0.64 c20 trisubstituted benzenes 274.48 LM 0 8 4.01 1.42 0.77 1.33±0.61 c21 trisubstituted benzenes 288.51 LM 0 8 3.82 1.35 0.74 1.26±0.58 c22 trisubstituted benzenes 302.54 LM 0 8 3.64 1.29 0.70 1.20±0.55 indene 95-13-6 116.16 LM 0 10 1.49 0.167 -0.42 -.007±0.468 indan 496-11-7 118.18 LM 0 10 3.24 1.15 0.44 0.99±0.56 naphthalene 91-20-3 128.17 Exp 1 4 + 5 3.28 1.14 0.48 1.01±0.54 methyl indans 132.20 LM 0 10 2.89 1.03 0.39 0.89±0.50 tetralin 119-64-2 132.20 Exp 1 4 + 5 2.89 1.03 0.39 0.89±0.50 methyl naphthalenes 1321-94-4 142.20 Exp + 10 3.00 1.02 0.41 0.90±0.51 1-methyl naphthalene 90-12-0 142.20 LM + 10 3.00 1.02 0.41 0.90±0.51 2-methyl naphthalene 91-57-6 142.20 LM + 10 3.00 1.02 0.41 0.90±0.51 c11 tetralin or indan 146.23 LM + 10 2.61 0.93 0.35 0.80±0.45 1-ethylnaphthalene 1127-76-0 156.22 LM + 10 2.73 0.93 0.37 0.82±0.46 c12 naphthalenes 156.22 LM + 10 3.85 1.30 0.60 1.19±0.62 c12 monosubstituted naphthalene 156.22 LM + 10 2.73 0.93 0.37 0.82±0.46Table C-1 (continued)

86 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

c12 disubstituted naphthalenes 156.22 LM + 10 4.96 1.67 0.82 1.55±0.78

2,3-dimethyl naphthalene 581-40-8 156.22 Exp 1 4 + 5 4.96 1.67 0.82 1.55±0.78 dimethyl naphthalenes 156.22 LM + 10 4.96 1.67 0.82 1.55±0.78 c12 tetralin or indan 160.26 LM 0 10 2.39 0.85 0.32 0.73±0.41 c13 naphthalenes 170.25 LM 0 10 3.53 1.19 0.55 1.09±0.57 c13 monosubstituted naphthalene 170.25 LM 0 10 2.51 0.85 0.34 0.76±0.42

c13 disubstituted naphthalenes 170.25 LM 0 10 4.55 1.53 0.75 1.42±0.72

c13 trisubstituted naphthalenes 170.25 LM 0 10 4.55 1.53 0.75 1.42±0.72

c13 tetralin or indan 174.28 LM 0 10 2.19 0.78 0.30 0.67±0.38 c14 naphthalenes 184.28 LM 0 10 3.26 1.10 0.51 1.01±0.53 c14 tetralin or indan 188.31 LM 0 10 2.03 0.72 0.28 0.62±0.35 c15 naphthalenes 198.30 LM 0 10 3.03 1.02 0.47 0.93±0.49 c15 tetralin or indan 202.34 LM 0 10 1.89 0.67 0.26 0.58±0.33 c16 naphthalenes 212.33 LM 0 10 2.83 0.96 0.44 0.87±0.46 c16 tetralin or indan 216.36 LM 0 10 1.77 0.63 0.24 0.54±0.30 c17 naphthalenes 226.36 LM 0 10 2.65 0.90 0.41 0.82±0.43 c17 tetralin or indan 230.39 LM 0 10 1.66 0.59 0.22 0.51±0.29 c18 naphthalenes 240.38 LM 0 10 2.50 0.84 0.39 0.77±0.40 c18 tetralin or indan 244.41 LM 0 10 1.56 0.56 0.21 0.48±0.27 c19 naphthalenes 254.41 LM 0 10 2.36 0.80 0.37 0.73±0.38 c19 tetralin or indan 258.44 LM 0 10 1.48 0.53 0.20 0.45±0.25 c20 naphthalenes 268.44 LM 0 10 2.24 0.76 0.35 0.69±0.36 c20 tetralin or indan 272.47 LM 0 10 1.40 0.50 0.190 0.43±0.24 c21 naphthalenes 282.46 LM 0 10 2.13 0.72 0.33 0.66±0.34 c21 tetralin or indan 286.49 LM 0 10 1.33 0.47 0.181 0.41±0.23 c22 naphthalenes 296.49 LM 0 10 2.03 0.68 0.31 0.63±0.33 c22 tetralin or indan 300.52 LM 0 10 1.27 0.45 0.172 0.39±0.22 acetylene 74-86-2 26.04 Exp 1 2 - 3 0.95 0.38 0. 20 0.35±0.16 methyl acetylene 74-99-7 40.06 Exp 1 - 7 6.67 2.51 1.39 2.33±1.05 1,3-butadiyne 460-12-8 50.06 Exp 0 11 5.56 2.56 1.65 2.36±0.80 2-butyne 503-17-3 54.09 Exp 1 0 10 16.34 5.63 3.19 5.38±2.50 ethyl acetylene 107-00-6 54.09 Exp 1 - 7 6. 05 2.27 1.26 2.10±0.94 methanol 67-56-1 32.04 Exp 1 3 0 2 0.66 0.32 0.20 0.29±0.10 ethanol 64-17-5 46.07 Exp 1 3 0 2 1.45 0.84 0.57 0.75±0.23 isopropyl alcohol 67-63-0 60.10 Exp 1 2 0 2 0.59 0.35 0.26 0.32±0.07 n-propyl alcohol 71-23-8 60.10 Exp 1 0 6 2.39 1.23 0.79 1.10±0.37 isobutyl alcohol 78-83-1 74.12 Exp 1 0 6 2.42 1.16 0.72 1.04±0.35 n-butyl alcohol 71-36-3 74.12 Exp 1 0 6 2.77 1.38 0.88 1.24±0.41 s-butyl alcohol 78-92-2 74.12 Exp 1 0 6 1.29 0.73 0.50 0.66±0.18 t-butyl alcohol 75-65-0 74.12 Exp 1 2 + 2 0.39 0.22 0.141 0.195±0.056 cyclopentanol 96-41-3 86.13 Exp 1 0 6 1.65 0.87 0.57 0.78±0.23 2-pentanol 6032-29-7 88.15 Exp 1 0 6 1.53 0.83 0.55 0.74±0.22 3-pentanol 584-02-1 88.15 Exp 1 0 6 1.56 0.82 0.55 0.75±0.22 pentyl alcohol 71-41-0 88.15 Exp 1 0 6 2.72 1.33 0.84 1.20±0.40Table C-1 (continued)

87 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
isoamyl alcohol (3-methyl1-butanol) 123-51-3 88.15 Exp 1 0 6 3.06 1.42 0.90 1.30±0.43

2-methyl-1-butanol 137-32-6 88.15 Exp 0 7 2.31 1.14 0.72 1.03±0.33 cyclohexanol 108-93-0 100.16 AdjP 1 0 6 1.83 1.01 0.63 0.88±0.28 1-hexanol 111-27-3 102.17 AdjP 1 0 6 2.56 1.29 0.81 1.15±0.38 2-hexanol 626-93-7 102.17 AdjP 1 0 6 1.96 1.14 0.73 1.00±0.31 4-methyl-2-pentanol (methyl isobutyl carbinol) 108-11-2 102.17 AdjP 0 7 2.52 1.34 0.87 1.20±0.36

1-heptanol 111-70-6 116.20 Exp 1 0 6 1.74 0.91 0.55 0.80±0.27 dimethylpentanol (2,3- dimethyl-1-pentanol) 10143-23-4 116.20 Exp 0 7 2.13 1.05 0.64 0.94±0.31

1-octanol 111-87-5 130.23 Exp 1 2 + 2 1.33 0.73 0.40 0.61±0.23 2-ethyl-1-hexanol 104-76-7 130.23 Exp 0 7 1.90 0.94 0.54 0.82±0.29 2-octanol 4128-31-8 130.23 Exp 1 2 + 2 1.84 0.98 0.59 0.85±0.29 3-octanol 20296-29-1 130.23 Exp 1 2 + 2 2.15 1.10 0.67 0.96±0.33 4-octanol 589-62-8 130.23 AdjP 1 0 6 2.09 1.10 0.65 0.95±0.33 5-methyl-1-heptanol 7212-53-5 130.23 AdjP 0 7 1.69 0.85 0.47 0.73±0.27 trimethylcyclohexanol 1321-60-4 142.24 AdjP 0 7 1.73 0.92 0.50 0.77±0.30 dimethylheptanol (2,6- dimethyl-2-heptanol) 13254-34-7 144.25 Exp 0 7 0.87 0.48 0.24 0.39±0.16

2,6-dimethyl-4-heptanol 108-82-7 144.25 AdjP 0 7 1.96 0.99 0.56 0.85±0.32 menthol 89-78-1 156.27 Exp 0 7 1.34 0.70 0.40 0.60±0.22 8-methyl-1-nonanol (isodecyl alcohol) 25339-17-7 158.28 Exp 0 7 0.97 0.53 0.26 0.43±0.18

1-decanol 112-30-1 158.28 Exp 0 7 0.98 0.53 0.27 0.43±0.18 3,7-dimethyl-1-octanol 106-21-8 158.28 Exp 0 7 1.11 0.58 0.30 0.48±0.20 Trimethylnonanol, threo/erythro; 2,6,8- trimethyl-4-nonanol 123-17-1 186.33 AdjP 0 7 1.23 0.64 0.31 0.52±0.23

ethylene glycol 107-21-1 62.07 Exp 1 2 0 2 3.03 1.49 1.00 1.37±0.41 propylene glycol 57-55-6 76.09 AdjP 1 2 0 2 2.50 1.16 0.75 1.07±0.34 glycerol 56-81-5 92.09 AdjP 0 7 3.07 1.36 0.84 1.25±0.45 1,3-butanediol 107-88-0 90.12 Exp 1 0 6 3.22 1.58 1.02 1.43±0.45 1,2-butandiol 584-03-2 90.12 AdjP 1 0 6 2.45 1.11 0.72 1.03±0.33 1,4-butanediol 110-63-4 90.12 Exp 0 7 2.62 1.24 0.78 1.13±0.39 2,3-butanediol 90.12 AdjP 1 0 6 4.25 1.86 1.08 1.68±0.70 pentaerythritol 115-77-5 136.15 AdjP 0 7 2.10 0.98 0.62 0.89±0.30 1,2-dihydroxy hexane 6920-22-5 118.17 AdjP 0 7 2.45 1.18 0.73 1.06±0.36 2-methyl-2,4-pentanediol 107-41-5 118.17 Exp 1 0 6 1.40 0.68 0.44 0.62±0.19 2-ethyl-1,3-hexanediol 94-96-2 146.23 AdjP 0 7 1.94 0.98 0.60 0.87±0.30 dimethyl ether 115-10-6 46.07 Exp 1 3 0 2 0.76 0.54 0.43 0.50±0.09 trimethylene oxide 503-30-0 58.08 Exp 1 0 6 4.31 2.41 1.74 2.22±0.61 1,3-dioxolane 646-06-0 74.08 Exp 0 7 4.77 2.21 1.59 2.10±0.58 dimethoxy methane 109-87-5 76.09 AdjP 1 0 6 0.89 0.64 0.50 0.59±0.11 tetrahydrofuran 109-99-9 72.11 Exp 1 0 6 4.11 2.11 1.41 1.92±0.56 diethyl ether 60-29-7 74.12 Exp 1 2 0 2 3.65 1.73 1.12 1.59±0.49 1,4-dioxane 123-91-1 88.11 Exp 0 7 2.49 1.29 0.90 1.19±0.32alphamethyltetrahydrofuran 96-47-9 86.13 Exp 1 0 6 3.78 1.87 1.22 1.69±0.52Table C-1 (continued)

88 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
tetrahydropyran 142-68-7 86.13 Exp 1 0 6 3.04 1.65 1.07 1.47±0.43 ethyl isopropyl ether 625-54-7 88.15 Exp 0 7 3.65 1.62 1.04 1.50±0.49 methyl n-butyl ether 628-28-4 88.15 Exp 1 0 6 3.00 1.57 1.04 1.42±0.42 methyl t-butyl ether 1634-04-4 88.15 Exp 1 3 0 2 0.70 0.43 0.29 0.38±0.10 2,2-dimethoxy propane 77-76-9 104.15 Exp 0 7 0.46 0.29 0.20 0.26±0.06 di n-propyl ether 111-43-3 102.17 Exp 1 0 6 2.93 1.55 1.04 1.40±0.40 ethyl n-butyl ether 628-81-9 102.17 Exp 1 0 6 3.34 1.61 1.03 1.46±0.46 ethyl t-butyl ether 637-92-3 102.17 Exp 1 0 6 1.94 0.97 0.62 0.88±0.27 methyl t-amyl ether 994-05-8 102.17 Exp 1 0 6 1.61 0.90 0.59 0.80±0.23 diisopropyl ether 108-20-3 102.17 Exp 0 7 3.44 1.45 0.89 1.34±0.48 ethylene glycol diethyl ether; 1,2-diethoxyethane 629-14-1 118.17 Exp 0 7 2.82 1.40 0.90 1.26±0.38

acetal (1,1-diethoxyethane) 105-57-7 118.17 Exp 0 7 3.47 1.51 0.97 1.40±0.46 4,4-dimethyl-3-oxahexane 919-94-8 116.20 Exp 0 7 1.87 0.94 0.58 0.84±0.27 2-butyl tetrahydrofuran 1004-29-1 128.21 Exp 0 7 1.99 0.99 0.55 0.85±0.32 di-isobutyl ether 628-55-7 130.23 Exp 1 0 6 1.11 0.63 0.38 0.54±0.17 di-n-butyl ether 142-96-1 130.23 Exp 1 0 6 2.70 1.33 0.82 1.18±0.392-methoxy-1-(2-methoxy1-methylethoxy)-propane; dipropylene glycol dimethyl ether 89399-28-0 162.23 AdjP 0 7 1.92 0.95 0.62 0.86±0.26

di-n-pentyl ether 693-65-2 158.28 AdjP 1 0 6 2.00 1.07 0.64 0.92±0.32 2-methoxyethanol 109-86-4 76.09 Exp 1 0 6 2.86 1.29 0.84 1.20±0.39 1-methoxy-2-propanol 107-98-2 90.12 AdjP 1 2 0 2 2.34 1.22 0.85 1.12±0.31 2-ethoxyethanol 110-80-5 90.12 Exp 1 3 0 2 3.61 1.62 1.03 1.49±0.49 2-methoxy-1-propanol 1589-47-5 90.12 Exp 0 7 2.96 1.21 0.75 1.13±0.41 3-methoxy-1-propanol 1320-67-8 90.12 Exp 0 7 3.76 1.63 1.03 1.52±0.52 diethylene glycol 111-46-6 106.12 AdjP 0 7 3.27 1.43 0.90 1.32±0.45 tetrahydro-2-furanmethanol 97-99-4 102.13 Exp 0 7 3.22 1.40 0.87 1.29±0.44 1-ethoxy-2-propanol 1569-02-4 104.15 Exp 0 7 2.96 1.47 0.94 1.33±0.41 2-propoxyethanol 2807-30-9 104.15 AdjP 0 7 3.19 1.50 0.98 1.38±0.43 3-ethoxy-1-propanol 111-35-3 104.15 Exp 1 0 6 3.98 1.75 1.09 1.61±0.55 3-methoxy-1-butanol 2517-43-3 104.15 Exp 1 0 6 3.81 1.56 0.97 1.46±0.53 2-(2-methoxyethoxy) ethanol 111-77-3 120.15 AdjP 0 7 2.55 1.26 0.85 1.16±0.33

1-propoxy-2-propanol (propylene glycol n-propyl ether) 1569-01-3 118.17 AdjP 0 7 2.56 1.32 0.89 1.20±0.34

2-butoxyethanol 111-76-2 118.17 Exp 1 2 0 2 2.80 1.26 0.76 1.14±0.393 methoxy -3 methylbutanol 56539-66-3 118.17 Exp 0 7 1.46 0.77 0.49 0.69±0.22

n-propoxypropanol 30136-13-1 118.17 Exp 0 7 3.65 1.66 1.05 1.52±0.50 2-(2-ethoxyethoxy) ethanol 111-90-0 134.17 Exp 1 3 0 2 3.13 1.46 0.91 1.32±0.44 dipropylene glycol isomer (1-[2-hydroxypropyl]-2- propanol) 110-98-5 134.17 AdjP 0 7 2.20 1.14 0.76 1.04±0.30

triethylene glycol 112-27-6 150.17 Exp 0 7 3.13 1.46 0.91 1.32±0.44 1-tert-butoxy-2-propanol 57018-52-7 132.20 AdjP 0 7 1.53 0.81 0.51 0.72±0.22 2-tert-butoxy-1-propanol 94023-15-1 132.20 Exp 0 7 1.78 0.72 0.41 0.66±0.26Table C-1 (continued)

89 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
n-butoxy-2-propanol (propylene glycol n-butyl ether) 5131-66-8 132.20 Exp 0 7 2.59 1.28 0.81 1.15±0.37

2-(2-propoxyethoxy) ethanol 6881-94-3 148.20 Exp 0 7 2.72 1.32 0.83 1.18±0.38

dipropylene glycol methyl ether isomer (1-methoxy-2- [2-hydroxypropoxy]- propane) 148.20 AdjP 0 7 1.88 0.96 0.64 0.87±0.25

dipropylene glycol methyl ether isomer (2-[2- methoxypropoxy]-1- propanol) 13588-28-8 148.20 AdjP 0 7 2.48 1.13 0.72 1.04±0.34

2-[2-(2-methoxyethoxy) ethoxy] ethanol 112-35-6 164.20 Exp 0 7 2.44 1.22 0.77 1.09±0.35

2-hexyloxyethanol 112-25-4 146.23 AdjP 0 7 1.98 0.99 0.58 0.86±0.30 2,2,4-trimethyl-1,3- pentanediol 144-19-4 146.23 Exp 0 7 1.46 0.77 0.48 0.68±0.22

2-(2-butoxyethoxy)-ethanol 112-34-5 162.23 Exp 2 0 7 2.27 1.09 0.65 0.96±0.34 dipropylene glycol ethyl ether 15764-24-6 162.23 Exp 0 7 2.61 1.20 0.72 1.07±0.37

2-[2-(2-ethoxyethoxy) ethoxy] ethanol 112-50-5 178.23 Exp 0 7 2.33 1.15 0.71 1.02±0.34

tetraethylene glycol 112-60-7 194.23 Exp 0 7 2.39 1.15 0.71 1.03±0.35 1-(butoxyethoxy)-2- propanol 124-16-3 176.25 AdjP 0 7 1.81 0.95 0.59 0.83±0.26

2-[2-(2-propoxyethoxy) ethoxy] ethanol 23305-64-8 192.25 Exp 0 7 2.05 1.02 0.62 0.90±0.30

tripropylene glycol 24800-44-0 192.25 Exp 0 7 2.07 1.04 0.64 0.92±0.312,5,8,11-tetraoxatridecan13-ol 23783-42-8 208.25 Exp 0 7 1.85 0.94 0.57 0.83±0.28

2-(2-ethylhexyloxy) ethanol 1559-35-9 174.28 AdjP 0 7 1.44 0.76 0.38 0.62±0.26

2-(2-hexyloxyethoxy) ethanol 112-59-4 190.28 AdjP 0 7 1.72 0.90 0.52 0.77±0.27

glycol ether dpnb {1-(2- butoxy-1-methylethoxy)-2- propanol} 29911-28-2 190.28 AdjP 0 7 1.72 0.87 0.53 0.77±0.25

2-[2-(2-butoxyethoxy) ethoxy] ethanol 143-22-6 206.28 Exp 0 7 1.85 0.92 0.55 0.81±0.28

tripropylene glycol monomethyl ether 25498-49-1 206.28 Exp 0 7 1.81 0.91 0.55 0.80±0.27

diethylene glycol mono(2- ethylhexyl) ether 1559-36-0 218.33 Exp 0 7 1.45 0.75 0.42 0.64±0.24

3,6,9,12-tetraoxahexadecan-1-ol 1559-34-8 250.33 AdjP 0 7 1.61 0.82 0.49 0.71±0.25

tripropylene glycol n-butyl ether 55934-93-5 248.36 Exp 0 7 1.55 0.75 0.43 0.65±0.24

methyl formate 107-31-3 60.05 Exp 1 0 6 0.053 0.043 0.035 0.040±0.007 ethyl formate 109-94-4 74.08 Exp 1 0 6 0.45 0.27 0.193 0.25±0.07Table C-1 (continued)

90 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
methyl acetate 79-20-9 74.08 Exp 1 2 0 2 0.067 0.055 0.043 0.050±0.010 gamma-butyrolactone 96-48-0 86.09 Exp 0 7 0.90 0.56 0.38 0.50±0.14 ethyl acetate 141-78-6 88.11 Exp 1 2 0 3 0.59 0.35 0.23 0.31±0.09 methyl propionate 554-12-1 88.11 Exp 1 0 6 0.63 0.32 0.20 0.29±0.10 n-propyl formate 110-74-7 88.11 Exp 1 0 6 0.72 0.44 0.29 0.39±0.13 isopropyl formate 625-55-8 88.11 Exp 0 7 0.34 0.24 0.176 0.22±0.05 ethyl propionate 105-37-3 102.13 Exp 1 0 6 0.73 0.42 0.27 0.37±0.11 isopropyl acetate 108-21-4 102.13 Ex p 1 2 0 2 1.03 0.57 0.39 0.52±0.14 methyl butyrate 623-42-7 102.13 Exp 1 0 6 1.05 0.55 0.34 0.49±0.16 methyl isobutyrate 547-63-7 102.13 Exp 1 2 0 2 0.58 0.33 0.21 0.29±0.10 n-butyl formate 592-84-7 102.13 Exp 1 0 6 0.77 0.48 0.32 0.42±0.13 propyl acetate 109-60-4 102.13 Exp 1 0 6 0.72 0.45 0.30 0.40±0.12 ethyl butyrate 105-54-4 116.16 Exp 1 0 6 1.11 0.60 0.38 0.53±0.17 isobutyl acetate 110-19-0 116.16 Ex p 0 7 0.58 0.40 0.28 0.35±0.08 methyl pivalate 598-98-1 116.16 Exp 1 2 0 2 0.33 0.20 0.120 0.169±0.055 n-butyl acetate 123-86-4 116.16 Exp 1 2 0,+ 2 0.77 0.49 0.31 0.42±0.13 n-propyl propionate 106-36-5 116.16 Exp 1 0 6 0.78 0.47 0.30 0.41±0.14 s-butyl acetate 105-46-4 116.16 Exp 1 0 6 1. 24 0.75 0.51 0.67±0.18 t-butyl acetate 540-88-5 116.16 Exp 1 3 0 2 0.172 0.097 0.059 0.084±0.027 butyl propionate 590-01-2 130.18 Exp 0 7 0.78 0.48 0.29 0.40±0.14 amyl acetate 628-63-7 130.18 AdjP 0 7 0.77 0.49 0.28 0.41±0.14 n-propyl butyrate 105-66-8 130.18 Exp 1 0 6 0.98 0.56 0.34 0.49±0.16 isoamyl acetate (3- methylbutyl acetate) 123-92-2 130.18 Exp 0 7 1.01 0.60 0.36 0.51±0.17

2-methyl-1-butyl acetate 624-41-9 130. 18 Exp 0 7 1.01 0. 62 0.40 0.54±0.15 ethyl 3-ethoxy propionate 763-69-9 146.18 AdjP 0 7 3.50 1.44 0.84 1.32±0.51 hexyl acetates 144.21 LM 0 7 0.72 0.46 0. 24 0.37±0.14 2,3-dimethylbutyl acetate 144.21 Exp 0 7 0. 69 0.43 0.25 0.36±0.12 2-methylpentyl acetate 144.21 Exp 0 7 0. 90 0.53 0.29 0.44±0.17 3-methylpentyl acetate 144.21 AdjP 0 7 0. 99 0.59 0.33 0.49±0.17 4-methylpentyl acetate 144.21 Exp 0 7 0. 75 0.45 0.24 0.36±0.14 isobutyl isobutyrate 97-85-8 144.21 Exp 0 7 0.55 0.35 0.20 0.29±0.09 n-butyl butyrate 109-21-7 144.21 Exp 1 0 6 1.01 0.57 0.32 0.48±0.17 n-hexyl acetate 142-92-7 144.21 AdjP 0 7 0. 62 0.41 0.20 0.32±0.13 methyl amyl acetate (4- methyl-2-pentanol acetate) 108-84-9 144.21 Exp 0 7 1.27 0.67 0.37 0.56±0.21

n-pentyl propionate 624-54-4 144.21 AdjP 0 7 0.65 0.40 0.20 0.32±0.13 2,4-dimethylpentyl acetat e 158.24 Exp 0 7 0. 84 0.47 0.22 0.37±0.16 2-methylhexyl acetate 158.24 AdjP 0 7 0.62 0.39 0.162 0.29±0.14 3-ethylpentyl acetate 158.24 Exp 0 7 1.01 0.59 0.31 0.48±0.19 3-methylhexyl acetate 158.24 Exp 0 7 0.81 0.49 0.24 0.38±0.16 4-methylhexyl acetate 158.24 Exp 0 7 0.74 0.44 0.21 0.35±0.15 5-methylhexyl acetate 158.24 AdjP 0 7 0.52 0.33 0.123 0.24±0.13 isoamyl isobutyrate 2050-01-3 158.24 Exp 0 7 0.75 0.43 0.22 0.35±0.14 n-heptyl acetate 112-06-1 158.24 Ex p 0 7 0.57 0.38 0.161 0.28±0.14 2,4-dimethylhexyl acetate 172.26 AdjP 0 7 0. 68 0.41 0.162 0.30±0.16 2-ethyl-hexyl acetate 103-09-3 172.26 AdjP 0 7 0.58 0.36 0.125 0.26±0.15 3,4-dimethylhexyl acetate 172.26 AdjP 0 7 0. 79 0.48 0.23 0.38±0.16 3,5-dimethylhexyl acetate 172.26 Exp 0 7 0. 90 0.51 0.23 0.40±0.18Table C-1 (continued)

91 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
3-ethylhexyl acetate 172.26 Exp 0 7 0.82 0.49 0.23 0.38±0.17 3-methylheptyl acetate 172.26 Exp 0 7 0. 59 0.38 0.149 0.28±0.15 4,5-dimethylhexyl acetate 172.26 AdjP 0 7 0. 61 0.37 0.156 0.28±0.14 4-methylheptyl acetate 172.26 Exp 0 7 0. 58 0.36 0.142 0.26±0.14 5-methylheptyl acetate 172.26 AdjP 0 7 0. 53 0.34 0.113 0.24±0.15 n-octyl acetate 112-14-1 172.26 Exp 0 7 0.50 0.33 0.120 0.23±0.13 2,3,5-teimethylhexyl
acetate 186.29 AdjP 0 7 0.77 0.45 0.20 0.35±0.16

2,3-dimethylheptyl acetat e 186.29 Exp 0 7 0. 63 0.40 0.168 0.30±0.15 2,4-dimethylheptyl acetat e 186.29 AdjP 0 7 0. 60 0.36 0.111 0.25±0.16 2,5-dimethylheptyl acetat e 186.29 Exp 0 7 0. 70 0.43 0.179 0.32±0.16 2-methyloctyl acetate 186.29 AdjP 0 7 0.44 0.29 0.068 0.185±0.138 3,5-dimethylheptyl acetat e 186.29 AdjP 0 7 0. 72 0.42 0.158 0.31±0.17 3,6-dimethylheptyl acetat e 186.29 Exp 0 7 0. 69 0.42 0.163 0.31±0.16 3-ethylheptyl acetate 186.29 Exp 0 7 0.55 0.35 0.126 0.25±0.14 4,5-dimethylheptyl acetat e 186.29 AdjP 0 7 0. 61 0.38 0.149 0.28±0.14 4,6-dimethylheptyl acetat e 186.29 Exp 0 7 0. 70 0.40 0.160 0.30±0.16 4-methyloctyl acetate 186.29 Exp 0 7 0.54 0.34 0.122 0.24±0.14 5-methyloctyl acetate 186.29 AdjP 0 7 0.48 0.31 0.082 0.20±0.14 n-nonyl acetate 143-13-5 186.29 Exp 0 7 0. 45 0.30 0.096 0.20±0.13 3,6-dimethyloctyl acetate 200.32 Exp 0 7 0. 70 0.42 0.171 0.31±0.16 3-isopropylheptyl acetate 200.32 Ad jP 0 7 0.46 0.30 0.082 0.20±0.14 4,6-dimethyloctyl acetate 200.32 Exp 0 7 0. 68 0.40 0.153 0.29±0.16 3,5,7-trimethyloctyl acet ate 214.34 AdjP 0 7 0.57 0.34 0.10 4 0.24±0.15 3-ethyl-6-methyloctyl
acetate 214.34 AdjP 0 7 0.55 0.34 0.104 0.23±0.15

4,7-dimethylnonyl acetate 214.34 AdjP 0 7 0.43 0.27 0.057 0.171±0.136 methyl dodecanoate {methyl laurate} 111-82-0 214.34 Exp 0 7 0.40 0.26 0.074 0.175±0.118

2,3,5,7-tetramethyloctyl
acetate 228.37 Exp 0 7 0.54 0.33 0.113 0.23±0.14

3,5,7-trimethylnonyl
acetate 228.37 AdjP 0 7 0.54 0.32 0.099 0.22±0.14

3,6,8-trimethylnonyl
acetate 228.37 AdjP 0 7 0.51 0.31 0.077 0.20±0.15

2,4,6,8-tetramethylnonyl
acetate 242.40 AdjP 0 7 0.43 0.26 0.057 0.168±0.134

3-ethyl-6,7-dimethylnonyl
acetate 242.40 AdjP 0 7 0.53 0.33 0.104 0.23±0.15

4,7,9-trimethyldecyl
acetate 242.40 AdjP 0 7 0.35 0.22 0.022 0.126±0.128

methyl myristate {methyl tetradecanoate} 124-10-7 242.40 Exp 0 7 0.37 0.24 0.067 0.159±0.110

2,3,5,6,8- pentaamethylnonyl acetate 256.42 Exp 0 7 0.57 0.35 0.136 0.26±0.14

3,5,7,9-tetramethyldecyl
acetate 256.42 AdjP 0 7 0.40 0.25 0.046 0.155±0.136

5-ethyl-3,6,8- trimethylnonyl acetate 256.42 AdjP 0 7 0.69 0.40 0.154 0.30±0.16

dimethyl carbonate 616-38-6 90.08 Exp 1 2 0 2 0.055 0.045 0.035 0.041±0.008Table C-1 (continued)

92 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
propylene carbonate 108-32-7 102.09 Exp 1 2 + 2 0.26 0.184 0.137 0.166±0.037 methyl lactate 547-64-8 104.10 Exp 1 0 6 2.63 1.06 0.58 0.96±0.43 2-methoxyethyl acetate 110-49-6 118.13 Exp 0 7 1.08 0.65 0.47 0.59±0.14 ethyl lactate 97-64-3 118.13 Exp 1 0 6 2.42 1.04 0.60 0.94±0.38 methyl isopropyl carbonate 51729-83-0 118.13 Exp 1 2 0 2 0.59 0.34 0.23 0.31±0.08 1-methoxy-2-propyl acetate 108- 65-6 132.16 Exp 1 2 0,+ 2 1.63 0.83 0.56 0.76±0.21 2-ethoxyethyl acetate 111-15-9 132.16 Exp 0 7 1.76 0. 89 0.58 0.80±0.24 2-methyoxy-1-propyl
acetate 70657-70-4 132.16 Exp 0 7 1.06 0.59 0.41 0.54±0.13

methoxypropanol acetate 84540- 57-8 132.16 Exp 0 7 1.76 0.93 0.60 0.83±0.26 dimethyl succinate 106-65-0 146.14 Exp 1 2 0 2 0.21 0.131 0.081 0.113±0.034 ethylene glycol diacetate 111-55-7 146.14 Exp 0 7 0.62 0.37 0.24 0.32±0.11 diisopropyl carbonate 6482-34-4 146.18 Exp 0 7 0.94 0.49 0.30 0.43±0.14 1,2-propylene glycol diacetate 623-84-7 160.17 Exp 0 7 0.57 0.36 0.24 0.32±0.08

dimethyl glutarate 1119-40-0 160.17 AdjP 1 2 0 2 0.39 0.22 0.108 0.179±0.075 2-butoxyethyl acetate 112- 07-2 160.21 Exp 0 7 1.52 0.80 0.50 0.70±0.22 dimethyl adipate 627-93-0 174.19 AdjP 1 0 6 1.72 0.80 0.44 0.70±0.27 2-(2-ethoxyethoxy) ethyl
acetate 112-15-2 176.21 AdjP 0 7 1.39 0.74 0.47 0.65±0.20

dipropylene glycol npropyl ether isomer #1 176.25 AdjP 0 7 1.89 0.96 0.60 0.85±0.27

dipropylene glycol methyl ether acetate isomer #1 190.24 AdjP 0 7 1.30 0.68 0.42 0.59±0.19

dipropylene glycol methyl ether acetate isomer #2 190.24 AdjP 0 7 1.43 0.72 0.44 0.64±0.21

dipropylene glycol methyl ether acetate isomers 88917-22-0 190.24 LM 0 7 1.37 0.70 0.43 0.62±0.20

glyceryl triacetate 102- 76-1 218.20 Exp 0 7 0.50 0.31 0.17 8 0.26±0.09 2-(2-butoxyethoxy) ethyl
acetate 124-17-4 204.26 Exp 0 7 1.29 0.68 0.40 0.58±0.20

substituted c7 ester (c12) 216.32 LM 0 7 0.75 0.39 0.20 0.32±0.13 1-hydroxy-2,2,4- trimethylpentyl-3- isobutyrate 18491-15-1 216.32 Exp 0 7 0.84 0.40 0.21 0.34±0.14

3-hydroxy-2,2,4- trimethylpentyl-1- isobutyrate 77-68-9 216.32 AdjP 0 7 0.71 0.39 0.191 0.31±0.13

texanol isomers 25265-77-4 216.32 LM 1 2 0 2 0.75 0.39 0.20 0.32±0.13 substituted c9 ester (c12) 216.32 LM 0 7 0.75 0.39 0.20 0.32±0.13 dimethyl sebacate 106-79-6 230.30 Exp 0 7 0.38 0.23 0.070 0.161±0.102 diisopropyl adipate 6938-94-9 230.30 Exp 0 7 1.22 0.52 0.22 0.43±0.22 triethyl citrate 77-93-0 276.28 Exp 0 8 0.66 0.31 0.155 0.26±0.11 2,2,4-trimethyl-1,3- pentanediol diisobutyrate 6846-50-0 286.41 Exp 0 7 0.33 0.20 0.062 0.140±0.088

ethylene oxide 75-21-8 44.05 Exp 1 0 6 0.036 0.032 0.026 0.029±0.005 propylene oxide 75-56-9 58.08 Exp 1 0 6 0.28 0.21 0.159 0.188±0.037 1,2-epoxybutane 106-88-7 72.11 Exp 1 0 6 0.85 0.62 0.46 0.55±0.13 formic acid 64-18-6 46.03 Exp 1 0 6 0.062 0.045 0.035 0.041±0.008 acetic acid 64-19-7 60.05 Exp 1 0 6 0.67 0.32 0.20 0.29±0.10Table C-1 (continued)

93 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
glycolic acid 79-14-1 76.05 AdjP 0 8 2.35 0.92 0.49 0.84±0.39 peroxyacetic acid 79-21-0 76.05 LM 0 8 0.53 0.26 0.162 0.23±0.08 acrylic acid 79-10-7 72.06 AdjP 0 8 11.38 4.00 2.27 3.81±1.76 propionic acid 79-09-4 74.08 Exp 0 7 1.18 0.57 0.34 0.51±0.19 methacrylic acid 79-41-4 86.09 Exp 0 8 18.56 6.17 3.52 5.95±2.85 isobutyric acid 79-31-2 88.11 Exp 0 7 1.16 0.59 0.38 0.53±0.17 butanoic acid 107-92-6 88.11 AdjP 0 7 1.76 0.88 0.55 0.79±0.26 malic acid 6915-15-7 134.09 AdjP 0 8 6.92 2.44 1.33 2.29±1.08 3-methylbutanoic acid 503-74-2 102.13 AdjP 0 7 4.17 1.69 0.98 1.56±0.64 adipic acid 124-04-9 146.14 AdjP 0 8 2.95 1.41 0.88 1.27±0.43 2-ethyl hexanoic acid 149-57-5 144.21 Exp 0 7 3.21 1.39 0.75 1.23±0.50 methyl acrylate 96-33-3 86.09 Exp 0 8 11.50 3.90 2.19 3.73±1.77 vinyl acetate 108-05-4 86.09 Exp 0 8 3.16 1.21 0.72 1.14±0.46 2-methyl-3-butene-2-ol 115-18-4 86.13 Exp 1 0 8 4.81 2.00 1.29 1.88±0.64 ethyl acrylate 140-88-5 100.12 Exp 0 8 7.71 2.87 1.67 2.70±1.13 methyl methacrylate 80-62-6 100.12 Exp 0 8 15.67 5.20 2.95 5.02±2.41 ethyl methacrylate 97-63-2 114.14 Exp 0 8 12.50 4.21 2.38 4.04±1.92 hydroxypropyl acrylate 2918-23-2 130.14 Exp 0 8 4.82 1.94 1.16 1.80±0.68 n-butyl acrylate 141-32-2 128.17 Exp 0 8 4.95 1.91 1.08 1.76±0.73 isobutyl acrylate 106-63-8 128.17 AdjP 0 8 4.64 1.81 1.01 1.66±0.69 butyl methacrylate 97-88-1 142.20 Exp 0 8 8.71 2.96 1.64 2.82±1.34 isobutyl methacrylate 97-86-9 142.20 Exp 0 8 8.63 2.93 1.62 2.79±1.34

α -terpineol 98-55-5 154.25 Exp 0 8 4.62 1.67 0.90 1.57±0.78Citronellol (3,7-dimethyl6-octen-1-ol) 106-22-9 154.25 Exp 0 8 5.80 2.05 1.12 1.94±0.97

Linalool 78-70-6 156.27 Exp 0 8 5.44 1.96 1.09 1.85±0.91 Geraniol 106-24-1 172.26 Exp 0 8 5.10 1.88 1.06 1.78±0.86 2-ethyl-hexyl acrylate 103-11-7 184.28 Exp 0 8 2.46 0.96 0.47 0.85±0.39 Hexyl cinnamal 101-86-0 216.32 LM 0 10 2.93 1.08 0.64 1.03±0.42 furan 110-00-9 68.07 Exp 1 3 - 4 9.03 3.57 2.10 3.33±1.34 2-methyl furan 534-22-5 82.10 Exp 1 3 0 4 8.20 3.19 1.88 2.99±1.21 3-methyl furan 930-27-8 82.10 Exp 1 3 0 4 6.77 2.77 1.68 2.58±0.97 2-ethyl furan 3208-16-0 96.13 LM 0 8 7.01 2.72 1.61 2.55±1.03 2,5-dimethyl furan 625-86-5 96.13 Exp 1 3 0 4 7.78 2.96 1.75 2.79±1.15 formaldehyde 50-00-0 30.03 Exp 1 1 0 1 b 9.59 2.89 1.41 2.79±1.68 acetaldehyde 75-07-0 44.05 Exp 1 2 0 1 6.46 2.53 1. 62 2.42±0.86 propionaldehyde 123-38-6 58.08 Exp 1 0 6 6.96 2.72 1.72 2.58±0.93 2-methylpropanal 78-84-2 72.11 Exp 1 0 7 5.15 2.08 1.35 1.98±0.67 butanal 123-72-8 72.11 Exp 1 0 7 5.85 2.30 1.45 2.18±0.78 c4 aldehydes 72.11 LM 0 7 5.85 2.30 1.45 2.18±0.78 2,2-dimethylpropanal (pivaldehyde) 630-19-3 86.13 Exp 1 0 8 4.80 1.88 1.21 1.80±0.63

3-methylbutanal (isovaleraldehyde) 590-86-3 86.13 Exp 1 0 8 4.89 1.91 1.22 1.82±0.65

pentanal (valeraldehyde) 110-62-3 86.13 Exp 1 0 8 4.98 1.98 1.26 1.88±0.66 c5 aldehydes 86.13 LM 0 8 4.98 1.98 1.26 1.88±0.66 glutaraldehyde 111-30-8 100.12 Exp 0 8 4.21 1.70 1.13 1.62±0.54 hexanal 66-25-1 100.16 Exp 1 0 8 4.26 1.70 1.08 1.60±0.56 c6 aldehydes 100.16 LM 0 8 4.26 1.70 1.08 1.60±0.56Table C-1 (continued)

94 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
heptanal 111-71-7 114.19 Exp 1 0 8 3.60 1.43 0.90 1.35±0.48 c7 aldehydes 114.19 LM 0 8 3.60 1.43 0.90 1.35±0.48 2-methyl-hexanal 925-54-2 114.19 Exp 0 8 3.45 1.41 0.88 1.32±0.46 octanal 124-13-0 128.21 Exp 0 8 3.08 1.22 0.74 1.14±0.42 c8 aldehydes 128.21 LM 0 8 3.08 1.22 0.74 1.14±0.42 Hydroxycitronellal 107-75-5 154.25 Exp 0 8 2.54 1.02 0.61 0.94±0.35 glyoxal 107-22-2 58.04 Exp 1 0 6 12.59 3.95 2.02 3.81±2.18 methyl glyoxal 78-98-8 72.06 Exp 1 0 6 16.60 5.25 2.85 5.10±2.70 acrolein 107-02-8 56.06 Exp 1 3 0 2 7.37 2.69 1.62 2.56±1.02 crotonaldehyde 4170-30-3 70.09 Exp 1 0 8 9.34 3.35 1.98 3.20±1.34 methacrolein 78-85-3 70.09 Exp 1 2 0 2 5.96 2.19 1.34 2.09±0.81 hydroxy methacrolein 40364-84-9 86.09 Exp 0 8 6.16 2.36 1.42 2.22±0.85 lumped c5+ unsaturated carbonyl species 100.12 Exp 0 8 6.33 2.34 1.39 2.22±0.90

Cinnamic aldehyde 104-55-2 132.16 LM 0 10 4.79 1.77 1.05 1.68±0.68 Amyl cinnamal 122-40-7 202.29 LM 0 10 3.13 1.16 0.69 1.10±0.45 benzaldehyde 100-52-7 106.12 Exp 1 3 0 2 -0.71 -0.73 -1.05 -0.89±0.26 tolualdehyde 120.15 LM 0 7 -0.63 -0.65 -0.93 -0.78±0.23 acetone 67-64-1 58.08 Exp 1 1 0 2 0.35 0.146 0. 088 0.135±0.049 cyclobutanone 1191-95-3 70.09 Exp 1 0 8 0.58 0.34 0.23 0.30±0.09 methyl ethyl ketone 78-93-3 72.11 Exp 1 2 0 2 1.45 0.62 0.37 0.56±0.20 cyclopentanone 120-92-3 84.12 Exp 1 0 8 1.08 0.65 0.42 0.57±0.17 c5 cyclic ketones 84.12 LM 0 8 1.08 0.65 0.42 0.57±0.17 2-pentanone 107-87-9 86.13 Exp 1 2 0 2 2.72 1.33 0.85 1.21±0.38 3-pentanone 96-22-0 86.13 Exp 1 0 6 1.18 0.59 0.37 0.52±0.18 c5 ketones 86.13 LM 0 7 2.72 1.33 0.85 1.21±0.38 methyl isopropyl ketone 563-80-4 86.13 Exp 1 0 6 1.60 0.79 0.50 0.71±0.22 2,4-pentanedione 123-54-6 100.12 Exp 0 8 0.99 0.38 0.22 0.35±0.14 cyclohexanone 108-94-1 98.14 Exp 1 2 0 2 1.25 0.72 0.42 0.61±0.22 c6 cyclic ketones 98.14 LM 0 7 1.25 0.72 0.42 0.61±0.22 4-methyl-2-pentanone 108-10-1 100.16 Exp 1 2 0 3 3.78 1.67 1.07 1.55±0.51 methyl n-butyl ketone 591-78-6 100.16 Exp 1 0 8 3.02 1.49 0.94 1.34±0.43 methyl t-butyl ketone 75-97-8 100.16 Exp 1 0 8 0.62 0.32 0.20 0.29±0.09 c6 ketones 100.16 LM 0 8 3.02 1.49 0.94 1.34±0.43 c7 cyclic ketones 112.17 LM 0 8 1.09 0.63 0.37 0.53±0.19 2-heptanone 110-43-0 114.19 Exp 1 3 ? 4 2.23 1.16 0.69 1.01±0.34 2-methyl-3-hexanone 7379-12-6 114.19 Exp 0 8 1.44 0.77 0.47 0.67±0.23 di-isopropyl ketone 565-80-0 114.19 Exp 1 0 8 1.23 0.67 0.40 0.58±0.21 c7 ketones 114.19 LM 0 8 2.23 1.16 0.69 1.01±0.34 5-methyl-2-hexanone 110-12-3 114.19 AdjP 1 0 8 2.28 1.19 0.76 1.06±0.33 3-methyl-2-hexanone 2550-21-2 114.19 Exp 0 8 2.43 1.25 0.77 1.10±0.37 c8 cyclic ketones 126.20 LM 0 8 0.97 0.56 0.33 0.47±0.17 2-octanone 111-13-7 128.21 Exp 1 0 8 1.29 0.73 0.39 0.60±0.23 c8 ketones 128.21 LM 0 8 1.29 0.73 0.39 0.60±0.23 c9 cyclic ketones 140.22 LM 0 8 0.87 0.50 0.30 0.43±0.15 2-propyl cyclohexanone 94-65-5 140.22 AdjP 0 8 1.40 0.76 0.38 0.62±0.27 4-propyl cyclohexanone 40649-36-3 140.22 Exp 0 8 1.72 0.89 0.49 0.75±0.29 2-nonanone 821-55-6 142.24 Exp 1 0 8 0.98 0.57 0.27 0.44±0.19Table C-1 (continued)

95 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
di-isobutyl ketone (2,6- dimethyl-4-heptanone) 108-83-8 142.24 Exp 1 0 8 2.57 1.15 0.68 1.03±0.37

c9 ketones 142.24 LM 0 8 0.98 0.57 0.27 0.44±0.19 camphor 76-22-2 152.23 Exp 0 8 0.43 0.26 0.089 0.184±0.112 c10 cyclic ketones 154.25 LM 0 8 0.79 0.46 0.27 0.39±0.14 2-decanone 693-54-9 156.27 AdjP 1 0 8 0.80 0.48 0.187 0.35±0.19 c10 ketones 156.27 LM 0 8 0.80 0.48 0.187 0.35±0.19 2,6,8-trimethyl-4- nonanone; isobutyl heptyl ketone 123-18-2 184.32 Exp 0 8 1.56 0.75 0.39 0.63±0.26

biacetyl 431-03-8 86.09 Exp 1 0 6 20.10 6.46 3. 68 6.31±3.15 methylvinyl ketone 78-94-4 70.09 Exp 1 3 0 2 9.56 3.68 2.24 3.47±1.35 mesityl oxide (2-methyl-2- penten-4-one) 141-79-7 98.14 LM 0 8 6.46 2.39 1.41 2.26±0.92

isophorone {3,5,5- trimethyl-2- cyclohexenone} 78-59-1 138.21 LM 0 8 4.58 1.70 1.00 1.60±0.65

1-nonene-4-one 61168-10-3 140.22 Exp 0 8 3.00 1.24 0.71 1.12±0.43 hydroxy acetone 116- 09-6 74.08 Exp 1 0 8 3.21 1.20 0.66 1.11±0.49 dihydroxyacetone 96-26-4 90.08 Exp 0 8 3.72 1.43 0.80 1.32±0.57 methoxy acetone 5878-19-3 88.11 Exp 1 0 8 1.96 0.95 0.63 0.88±0.25 diacetone alcohol 123-42-2 116.16 Exp 0 8 0. 56 0.30 0.184 0.26±0.09 phenol 108-95-2 94.11 LM 0 8 2.75 0.163 -0.89 -.057±0.876 c7 alkyl phenols 1319-77-3 108.14 LM 0 5 2.40 0.142 -0.78 -.050±0.762

m -cresol 108-39-4 108.14 LM 4 -,0 5 2.40 0.142 -0.78 -.050±0.762
p -cresol 106-44-5 108.14 LM 4 0? 5 2.40 0.142 -0.78 -.050±0.762

o -cresol 95-48-7 108.14 Exp 1 4 ? 5 2.40 0.142 -0.78 -.050±0.762 4-vinylphenol 2628-17-3 120.15 LM 0 11 1.44 0.161 -0.41 -.007±0.452 2,4-dimethyl phenol 105-67-9 122.16 LM 0 8 2.12 0.125 -0.69 -.044±0.675 2,5-dimethyl phenol 122.16 LM 0 8 2.12 0.125 -0.69 -.044±0.675 3,4-dimethyl phenol 95-65-8 122.16 LM 0 8 2.12 0.125 -0.69 -.044±0.675 2,3-dimethyl phenol 526-75-0 122.16 LM 0 8 2.12 0.125 -0.69 -.044±0.675 2,6-dimethyl phenol 576-26-1 122.16 LM 0 8 2.12 0.125 -0.69 -.044±0.675 c8 alkyl phenols 122.16 LM 0 8 2.12 0.125 -0.69 -.044±0.675 methylparaben (4- hydroxybenzoic acid, methyl ester) 99-76-3 152.15 LM 0 11 1.70 0.101 -0.55 -.036±0.542

2,3,5-trimethyl phenol 697-82-5 136.19 LM 0 8 1.90 0.113 -0.62 -.039±0.606 2,3,6-trimethyl phenol 2416-94-6 136.19 LM 0 8 1.90 0.113 -0.62 -.039±0.606 c9 alkyl phenols 136.19 LM 0 8 1.90 0.113 -0.62 -.039±0.606 c10 alkyl phenols 150.22 LM 0 8 1.73 0.102 -0.56 -.036±0.549 propylparaben 94-13-3 180.20 LM 0 11 1.44 0.085 -0.47 -.030±0.458 c11 alkyl phenols 164.24 LM 0 8 1.58 0.094 -0.51 -.033±0.502 c12 alkyl phenols 178.27 LM 0 8 1.45 0.086 -0.47 -.030±0.463 2,6-di- tert -butyl- p -cresol 128-37-0 220.35 LM 0 10 1.18 0.070 -0.38 -.024±0.374 benzyl alcohol 100-51-6 108.14 Exp 1 2 0 4 5.08 1.77 0.85 1.62±0.82 methoxybenzene; anisole 100-66-3 108.14 Exp 1 0 8 6.61 2.25 1.04 2.05±1.09 beta-phenethyl alcohol 98-85-1 122.16 LM - 11 4.49 1.57 0.76 1.44±0.73Table C-1 (continued)

96 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

2- p henoxyethanol; ethylene glycol phenyl ether 122-99-6 138.16 Exp 0 8 4.43 1.64 0.85 1.50±0.69

phthalic anhydride 85-44-9 148.12 Exp 0 8 2.53 0.92 0.41 0.81±0.44 cinnamic alcohol 104-54-1 134.18 LM -1 10 0.83 0.099 -0.29 -.031±0.270 1-phenoxy-2-propanol 770-35-4 152.19 LM 0 8 1.55 0.63 0.28 0.54±0.27 anethol 104-46-1 148.20 LM 0 11 0.75 0.090 -0.26 -.028±0.245 1,2-diacetyl benzene 704- 00-7 162.19 Exp 1 0 8 2.20 0.80 0.34 0.70±0.39 diethyl phthalate 84-66-2 222.24 Exp 0 8 1.58 0.59 0.26 0.52±0.27 2-ethylhexyl benzoate 5444-75-7 234.33 Exp 0 10 0.92 0.42 0.176 0.34±0.17 Di n-butyl phthalate 84-74-2 278.34 Exp 0 8 1.21 0.48 0.22 0.42±0.20 nitrobenzene 98-95-3 123.11 Exp 1 0 8 0.054 0.007 -0.013 0.002±0.016 m-nitrotoluene 99-08-1 137.14 Exp 1 0 8 0.49 0.165 0.035 0.130±0.102 para toluene isocyanate 622-58-2 133.15 Exp 1 2 0 5 1.04 -0.077 -0.52 -.167±0.377 2,4-toluene diisocyanate 584-84-9 174.16 Exp 1 2 0 5 -0.084 -0.54 -0.82 -0.61±0.24 2,6-toluene diisocyanate 91-08-7 174.16 LM 4 0 5 -0.084 -0.54 -0.82 -0.61±0.24 toluene diisocyanate (mixed isomers) 26471-62-5 174.16 LM 0 5 -0.084 -0.54 -0.82 -0.61±0.24

methylene diphenylene diisocyanate 101-68-8 250.25 Exp 0 8 0.88 0.020 -0.31 -.044±0.273

methylamine 74-89-5 31.06 Exp 1 + 13 a,n 7.25 4.04 2.60 3.57±1.10 dimethyl amine 124-40-3 45.08 Exp 1 + 13 a,n 2.65 1.84 1.33 1.61±0.57 ethyl amine 75-04-7 45.08 Exp 1 + 13 a,n 5.45 2.97 1.91 2.63±0.81 trimethyl amine 75-50-3 59.11 Exp 1 + 13 a,n 5.27 2.75 1.81 2.48±0.75 isopropylamine 75-31-0 59.11 Exp 4a + 12 a,n 6.97 3.26 2.06 2.97±0.97 t-butyl amine 75-64-9 73.14 Exp 1 4a - 12 a -3.26 -1.06 -0.44 -0.99±0.70 triethyl amine 121-44-8 101.19 Exp + 13 a,n 3.07 1.48 0.91 1.31±0.45 triethylene diamine 280-57-9 112.17 LM + 13 a,n 2.77 1.33 0.82 1.18±0.40 ethanolamine 141-43-5 61.08 Exp 3a + 12 a,n 6.59 2.99 1.85 2.72±0.93 dimethylaminoethanol 108-01-0 89.14 Exp 1 + 13 a,n 5.15 2.21 1.40 2.05±0.70 2-amino-1-butanol 96-20-8 89.14 Exp + 13 a,n 4.79 2.14 1.31 1.95±0.67 2-amino-2-methyl-1- propanol 124-68-5 89.14 Exp 3a - 12 a -2.68 -0.80 -0.30 -0.76±0.62

diethanol amine 111-42-2 105.14 Exp + 13 a,n 2.22 1.08 0.70 0.98±0.32 triethanolamine 102-71-6 149.19 Exp + 13 a,n 3.25 1.37 0.81 1.25±0.46 triisopropanolamine 122-20-3 191.27 Exp + 13 a,n 1.99 0.96 0.60 0.86±0.29 methyl nitrite 624-91-9 61.04 Exp 1 0 6 10.94 4.76 4.20 5.05±1.35 acrylonitrile 107-13-1 53.06 Exp 1 0 10 2.18 1.09 0.73 1.01±0.29 1-nitropropane 108-03-2 89.09 Exp 0 8 0.20 0.147 0.108 0.131±0.029 ethyl methyl ketone oxime 96-29-7 87.12 Exp 0 10 1.55 1.32 1.45 1.40±0.30 n-methyl-2-pyrrolidone 872-50-4 99.13 Exp 1 2 0 2 2.28 1.16 0.68 1.01±0.35 lauryl pyrrolidone 2687-96-9 253.42 LM 0 11 0.89 0.45 0.27 0.40±0.14 methyl chloride 74-87-3 50.49 Exp 1 0 10 0.037 0.020 0.013 0.018±0.005 dichloromethane 75-09-2 84.93 Exp 1 0 10 0.038 0.026 0.018 0.023±0.006 methyl bromide 74-83-9 94.94 Exp 1 0 10 0.018 0.010 0.006 0.009±0.003 chloroform 67-66-3 119.38 Exp 1 0 10 0.020 0.014 0.010 0.012±0.003 carbon tetrachloride 56-23-5 153.82 LM 0 1 0 0 0 0 methylene bromide 74-95-3 173.83 LM 0 1 0 0 0 0 ethyl chloride 75-00-3 64.51 Exp 1 0 10 0.27 0.168 0.111 0.147±0.044 1,1-dichloroethane 75-34-3 98.96 Exp 1 0 10 0.065 0.043 0.030 0.038±0.009Table C-1 (continued)

97 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
1,2-dichloroethane 107-06-2 98.96 Exp 1 0 10 0.21 0.099 0.058 0.088±0.032 ethyl bromide 74-96-4 108.97 Exp 1 0 20 0.121 0.075 0.050 0.066±0.020 1,1,1-trichloroethane 71-55-6 133.40 Exp 1 0 10 0.005 0.003 0.002 0.003±0.001 1,1,2-trichloroethane 79-00-5 133.40 Exp 1 0 10 0.082 0.043 0.026 0.038±0.012 1,2-dibromoethane 106-93-4 187.86 Exp 1 0 20 0.098 0.047 0.028 0.042±0.015 1,2-dichloropropane 78-87-5 112.99 Exp 0 10 0.28 0.136 0.082 0.121±0.042 n-propyl bromide 106-94-5 122.99 Exp 1 2x -,+2 20 n 0.40 0.22 0.135 0.190±0.061 1-chlorobutane 109-69-3 92.57 Exp 0 10 1.04 0.59 0.37 0.52±0.16 n-butyl bromide 109-65-9 137.02 Exp 1 2x -,+2 20 n 0.78 0.44 0.28 0.38±0.12 3-(chloromethyl)-heptane 123-04-6 148.67 LM 0 10 0.86 0.53 0.27 0.42±0.17 vinyl chloride 75-01-4 62.50 Exp 1 0 10 2.71 1.42 0.95 1.29±0.37 1,1-dichloroethene 75-35-4 96.94 Exp 0 10 2.76 1.22 0.82 1.13±0.36 trans-1,2-dichloroethene 156-60-5 96.94 Exp 1 0 10 1.66 0.75 0.44 0.67±0.25 cis-1,2-dichloroethene 96.94 LM 0 10 1.66 0.75 0.44 0.67±0.25 trichloroethylene 79-01-6 131.39 Exp 1 2x +2 20 0.61 0.33 0.21 0.29±0.09 perchloroethylene 127-18-4 165.83 Exp 1 0 10 0.029 0.020 0.013 0.017±0.005 3-chloropropene 76.52 Exp 0 10 12.20 4.04 2.20 3.84±1.89 trans-1,3-dichloropropene 10061-02-6 110.97 Exp 1 2m 0 3 5.00 1.83 1.03 1.71±0.76 cis-1,3-dichloropropene 10061-01-5 110.97 Exp 1 2m 0 3 3.66 1.44 0.83 1.33±0.55 1,3-dichloropropene mixture 110.97 LM 1 2 0 2 4.25 1.61 0.92 1.49±0.64

2-(cl-methyl)-3-cl-propene 1871-57-4 125.00 Exp 1 4 - 20 6.75 2.30 1.30 2.18±1.01 monochlorobenzene 108-90-7 112.56 Exp 1 0 8 0.31 0.045 -0.068 0.017±0.091 p-dichlorobenzene 106-46-7 147.00 Exp 0 10 0.171 0.025 -0.039 0.009±0.051 o-dichlorobenzene 95-50-1 147.00 LM 0 8 0.171 0.025 -0.039 0.009±0.051 hexafluorobenzene 392-56-3 186.05 Exp 1 0 8 0.045 0.006 -0.011 0.002±0.014 2-chlorotoluene 95-49-8 126.58 LM 1 8 2.86 1.00 0.40 0.88±0.51 benzotrifluoride 98-08-8 146.11 Exp 1 0 8 0.29 0.109 0.042 0.092±0.053p-trifluoromethyl-clbenzene 98-56-6 180.55 Exp 1 0 8 0.122 0.047 0.018 0.039±0.023

methyl nonafluorobutyl ether 163702-07-6 234.06 Exp 0 8 0.051 0.041 0.030 0.036±0.008

methyl nonafluoroisobutyl ether 163702-08-7 234.06 LM 0 8 0.051 0.041 0.030 0.036±0.008

ethyl nonafluorobutyl ether 163702-05-4 264.09 Exp + 8 0.190 0.124 0.084 0.108±0.026 ethyl nonafluoroisobutyl ether 163702-06-5 264.09 LM + 8 0.190 0.124 0.084 0.108±0.026

chloroacetaldehyde 107-20-0 78.50 Exp 1 0 7 12.44 3. 72 1.85 3.58±2.05 chloropicrin 76-06-2 164.38 Exp 1 2 0 1 1.87 1.08 1.16 1.18±0.19 hexamethyldisiloxane 107-46-0 162.38 Exp 1 3 0 5 -0.030 0.020 0.032 0.020±0.020 hydroxymethyldisiloxane 164.35 Exp 1 3 0 5 -0.137 -0.019 0.015 -.015±0.043 d4 cyclosiloxane 556-67-2 296.62 Exp 1 3 0 5 -0.059 -0.014 0.001 -.011±0.016 d5 cyclosiloxane 541-02-6 370.77 Exp 1 4 0 5 -0.070 -0.016 0.001 -.014±0.019 carbon disulfide 75-15-0 76.14 Exp 1 2 0 2 0.23 0.159 0.125 0.147±0.026 methyl isothiocyanate 556-61-6 73.12 Exp 1 2 0 2 0.31 0.21 0.186 0.20±0.03 dimethyl sulfoxide 67-68-5 78.13 Exp 1 2 -2,0 4 6.63 2.47 1.54 2.37±0.97 molinate 187.30 Exp 0 7 1.43 0.70 0.43 0.62±0.21 eptc (s-ethyl dipropylthiocarbamate) 759-94-4 189.32 Exp 1 2 0 2 1.57 0.82 0.50 0.72±0.24Table C-1 (continued)

98 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base
pebulate 203.34 Exp 0 7 1.58 0.79 0.46 0.69±0.25 thiobencarb 257.78 Exp 0 8 0.64 0.27 0.100 0.21±0.12 methyl iodide 74-88-4 141.94 Exp 0 3 -0.52 -2.02 -2.65 -2.11±0.68

Base ROG Mixture 14.44 Mix 0 7 3.56 1.46 0.81 1.32±0.53 Final LEV -- RFA 14.03 Mix 0 7 3.48 1.43 0.77 1.28±0.54 TLEV Exhaust -- RFA 14.04 Mix 0 7 3.95 1.58 0.86 1.43±0.61 TLEV Exhaust -- Phase 2 14.12 Mix 0 7 3.91 1.58 0.87 1.43±0.60 Final LEV -- Phase 2 14.22 Mix 0 7 3.39 1.40 0.77 1.26±0.52 TLEV Exhaust -- LPG 14.86 Mix 0 7 2.02 0.89 0.55 0.82±0.28 TLEV Exhaust -- CNG 15.22 Mix 0 7 0.71 0.34 0.22 0.31±0.10 TLEV Exhaust -- E-85 20.74 Mix 0 7 2.48 1.18 0.75 1.08±0.35 TLEV Exhaust -- M-85 27.45 Mix 0 7 1.56 0.62 0.35 0.57±0.24 Composite mineral spirit (naphthas or lactol spirits) (CARB Profile ID 802) 14.06 Mix 0 7 1.75 0.80 0.36 0.66±0.31

Safety-Kleen Mineral Spirits "A" (Type I-B, 91% Alkanes) 14.08 Mix 2 0,+ 7 1.09 0.57 0.23 0.44±0.22

Safety-Kleen Mineral Spirits "B" (Type II-C) 14.10 Mix 2 0,+ 7 0.62 0.38 0.127 0.27±0.17

Safety-Kleen Mineral Spirits "C" (Type II-C) 14.11 Mix 2 0,+ 7 0.62 0.39 0.126 0.27±0.17

Exxon Exxol(r) D95 Fluid 14.11 Mix 2 0 7 0.53 0.33 0.104 0.23±0.15 Safety-Kleen Mineral Spirits "D" (Type II-C) 14.12 Mix 2 0,+ 7 0.62 0.39 0.127 0.27±0.17

Exxon Isopar(r) M Fluid 14.15 Mix 2 0 7 0.51 0.33 0.099 0.22±0.15 Thinning Solvent/Mineral Spirits (Cal Poly Slo. 1996) 14.40 Mix 0 7 1.79 0.85 0.41 0.71±0.30

Aromatic 100 13.36 Mix 2 0 7 7.55 2.62 1.34 2.43±1.19 Kerosene 13.94 Mix 2 0 7 1.45 0.67 0.29 0.54±0.26 Regular mineral spirits 13.97 Mix 2 0 7 1.73 0.78 0.34 0.64±0.30 Reduced Aromatics Mineral Spirits 14.05 Mix 2 0 7 1.06 0.56 0.22 0.43±0.22

Dearomatized Alkanes, mixed, predominately C10- C12 14.09 Mix 2 0 7 0.77 0.46 0.172 0.34±0.19

VMP Naphtha 14.16 Mix 2 0 7 1.10 0.64 0.29 0.50±0.23 Synthetic isoparaffinic alkane mixture, predominately C10-C12 14.20 Mix 2 0 7 0.66 0.41 0.139 0.29±0.17

ASTM-3C1 "Highly Branched" rep'n 14.20 Mix 0 7 1.00 0.59 0.26 0.45±0.21

Oxo-Tridecyl Acetate 16.19 Mix 0 7 0.52 0.31 0.106 0.22±0.14 Oxo-Dodecyl Acetate 16.30 Mix 0 7 0.56 0.33 0.114 0.24±0.14 Oxo-Decyl Acetate 16.71 Mix 2 0 7 0.64 0.39 0.151 0.29±0.15 Oxo-Nonyl Acetate 16.89 Mix 0 7 0.67 0.40 0.159 0.30±0.16 Oxo-Octyl Acetate 17.23 Mix 0 7 0.76 0.46 0.20 0.35±0.16 Oxo-Heptyl Acetate 17.58 Mix 0 7 0.79 0.47 0.23 0.37±0.16 Oxo-Hexyl Acetate 18.02 Mix 0 7 0.83 0.51 0.27 0.41±0.16Table C-1 (continued)

99 Codes [b] Reactivity (gm O 3 / gm VOC) Description CAS MWt [a] Rep k a Expt Bias Unc MIR MOIR EBIR Base

Unspeciated C6 Alkanes (n-, br-, and cyc-) 14.25 Mix 0 8 1.25 0.80 0.49 0.68±0.22

Unspeciated C7 Alkanes (n-, br-, and cyc-) 14.22 Mix 0 8 1.26 0.77 0.41 0.62±0.23

Unspeciated C8 Aromatics 13.27 Mix 0 8 7.56 2.56 1.20 2.34±1.23 Unspeciated C8 Alkanes (n-, br-, and cyc-) 14.19 Mix 0 8 1.16 0.70 0.34 0.55±0.23

Unspeciated C9 Aromatics 13.34 Mix 0 8 8.11 2.82 1.47 2.62±1.27 Unspeciated C9 Alkanes (n-, br-, and cyc-) 14.18 Mix 0 8 0.96 0.57 0.24 0.43±0.21

Unspeciated C10 Aromatics 13.39 Mix 0 8 7.21 2.52 1.31 2.34±1.12

Unspeciated C10 Alkanes (n-, br-, and cyc-) 14.16 Mix 0 8 0.79 0.48 0.186 0.35±0.19

Unspeciated C11 Aromatics 13.43 Mix 0 8 7.02 2.46 1.31 2.29±1.08

Unspeciated C11 Alkanes (n-, br-, and cyc-) 14.15 Mix 0 8 0.64 0.40 0.131 0.28±0.17

Unspeciated C12 Aromatics 13.32 Mix 0 8 5.70 1.98 1.03 1.84±0.88

Unspeciated C12 Alkanes (n-, br-, and cyc-) 14.14 Mix 0 8 0.59 0.37 0.118 0.26±0.16

Unspeciated C13 Aromatics 13.53 Mix 0 8 5.72 2.01 1.08 1.88±0.88

Unspeciated C13 Alkanes (n-, br-, and cyc-) 14.13 Mix 0 8 0.53 0.34 0.106 0.23±0.15

Unspeciated C14 Aromatics 13.56 Mix 0 8 5.22 1.84 0.98 1.72±0.80

Unspeciated C14 Alkanes (n-, br-, and cyc-) 14.12 Mix 0 8 0.50 0.32 0.100 0.22±0.15

Unspeciated C15 Aromatics 13.59 Mix 0 8 4.77 1.69 0.90 1.58±0.73

Unspeciated C15 Alkanes (n-, br-, and cyc-) 14.12 Mix 0 8 0.47 0.30 0.097 0.21±0.14

Unspeciated C16 Aromatics 13.62 Mix 0 8 4.39 1.56 0.83 1.45±0.67

Unspeciated C16 Alkanes (n-, br-, and cyc-) 14.11 Mix 0 8 0.43 0.28 0.087 0.190±0.131

[a] Molecular weights for complex mixtures (base ROG mixture and mixtures listed below it) are given on a per carbon basis. [b] Codes used in this tabulation are as follows: "Rep" ... Codes for method used to represent the VOC in the mechanism Exp An explicit mechanism assignment has been made for this compound or model species. See Carter (2007a) or Tabl e A-1 for the mechanism. AdjP An explicit mechanism assignment has been made for this compound and the adjusted product version of the mechanism has been used when calculating its atmospheric reactivity values. The adjusted product mechanism is given in Carter et al (2007a).Table C-1 (continued)

100 LM This compound is represented using the "Lumped Molecule" method. See Carter et al (2007a) or Table A-2. Mix This is represented by a complex mixture of detailed model species. The compositions of these mixtures are given in Carter et al (2007a).
"k a" ... Codes indicating of measurement data for the reaction rate constants 1 The OH radical rate constant has been measured. See Carter (2007a) or Table A-1 for the rate constant and reference citation. If the compound is consumed primarily by photolysis, this code means that absorption cross section and quantum yield are available and given by Carter (2007a). blank The OH radical rate constant or (if primarily photoreactive) the photolysis rate parameters had to be estimated. See Carter (2007a) for documentation of the estimation method used. "Expt" ... Environmental Chamber Data Availability Codes (if blank, no suitable evaluation data are available). 1 Extensive evaluation data for a variety of conditions. 2 Sufficient data available. At least 2 and often 3 types of evaluation experiments to test data under different conditions. 3 Limited evaluation data; usually representing one set of conditions, or some inconsistencies in evaluation results. 3a Evaluation data exist for 2 or more sets of conditions, but uncertainties exist concerning amount of compound available to react in th e gas phase. See Carter and Warren (2007). 4 Data from only a single experiment is available, results from different experiments gave inconsistent results, or problems exist with the data. 4a Data from only a single experiment is available, and uncertainties exist concerning the amount of compound available for reaction in the gas phase. See Carter and Warren (2007). m This compound was studied in a mixture with the other isomer. Since the reactivities of the two isomers are different, the uncertainty classification has been increased over that of the mixture that was studied. x No attempt was made to improve the mechanism performance to fit the available data. "Bias" ... Probable reactivity prediction bias codes (if blank, this compound has not been rated)
Chamber data available No chamber data available 0 No apparent bias Direction of bias is unknown + Some indication of positive bias Positive bias considered to be more likely than not - Some indication of negative bias Negative bias is considered to be more likely than
not

± 2 Bias found to be relatively large Bias may be relatively large x,x If two codes given, the first indicates observed or probable bias for predictions of rates of NO oxidation and O 3 formation, which is important in affecting MIR reactivity, and the second indicates observed or probable bias for low NO x conditions. E.g. "0,+" if chamber data available indicates that the model simulated rates of NO oxidation and O 3 formation but overpredicted final O 3 yields in NO x -limited experiments. ? There is some inconsistency in the data concerning this bias indication (or lack thereof), or the bias is unknown but may be large.Table C-1 (continued)

101 a The reactivity predictions and representation in the mechanism is based on the assumption that this compound is completely available for reaction in the gas phase. This is likely not to be the case for this compound. Thus the reactivity estimate may be high for compounds that have positive O 3 impacts and low for compounds that are calculated to be inhibitors.
"Unc" ... Uncertainty codes (if blank, this compound has not been rated) The following codes are used when experimental data are available to evaluate the reactivity predictions of the mechanism and the mechanism was (or would have been) adjusted to fit the data as appropriate to improve the fits. 1 The mechanism appears to be reasonably we ll established or at least its predictions appear to be are reasonably well evaluated. This does not rule out possible changes in reactivity values if the base mechanism, scenar io conditions, or r eactivity metrics are changed. Also used for compounds known or expected to be inert or to have upper limit reactivities much less than methane.
2 The mechanism has been evaluated at least to some extent, rate constant data are available for its major reactions, and is not c onsidered to have large uncertainties. If a likely bias is indicated it is probably not large.
3 The mechanism has been evaluated at least to some extent and rate constant data are available for its major reactions, but the mechanism has some uncertainties or apparent inconsistencies with available laboratory da ta, or there are some uncertainties in the evaluation data. If a likely bias is indicated it is probably not large.
4 The mechanism has been evaluated at least to some extent and rate constant data are available for its major reactions, but the mechanism has some uncertainties, apparent inconsistencies with available laboratory data exist that may be significant, or the available evaluation database is limited or has problems. If a likely bias of ± 1 is indicated it is probably not large. 5 A highly parameterized mechanism has been adjusted to simulate chamber data. The appropriateness of the parameterization, and its ability to extrapolate to ambient conditions, is uncertain. The following codes are used for compounds for which no experimental data exist to evaluate reactivity predictions of the mechanism, or where such data, if any, were not taken into account when developing the mechanism.
6 The mechanism has not been evaluated but at least the important reaction rate(s) have been measured and the methods used to estimate the mechanism have been found to generally perform reasonably well for compounds where evaluation data are available, or the mechanisms are not expected to be highly complex. If a likely bias is indicated it is based on evaluation results for similar compounds. 7 The mechanism has not been evaluated and the reaction rates had to be estimated, but the methods used to estimate the rate constant(s) and mechanism have been found to generally perform reasonably well for compounds where evaluation data are available. If a likely bias is indicated it is based on evaluation results for similar compounds. This code is also used for lumped molecule or mi xture representations that are considered to be reasonably appropriate. 8 The estimated mechanism and/or relevant rate constant(s) or photolysis rates have some uncertainties, but mechanisms based on similar assumptions have been found to perform satisfactorily for related compounds, or the mechanisms are not expected to be highly complex. The applicability of these assumptions to this compound, or the extrapolation of mechanisms for smaller compounds to one of this size, has some uncertainty. This code is also used for lumped molecule re presentations whose appropriateness has some uncertainty.Table C-1 (continued)

102 The uncertainty codes below mean that use of the reactivity values in regulatory applications is problematical.

10 The estimated mechanism is sufficiently uncertain that it needs to be evaluated. This code is also used for lumped molecule representations whose appropriateness is considered to be highly uncertain. However, the representation employed is the current best estimate, and the directio n of the bias is unknown.
11 The estimated mechanism is ex tremely uncertain that it needs to be evaluated. This code is also used for lumped molecule representations whose appropriateness is questionable, but no better alternative exists, and the bias of using the representation is unknown. However, the representation employed is the current best estimate, and the direction of the bias is unknown. 12 An estimated mechanism for the gas-phas e reactions for this compound has been developed and has been evaluated at least qualitatively against available chamber data, but its estimated atmospheric ozone impact is highly uncertain because the amount of emitted compound available for reaction in the gas-phase is unknown. One important issue is that this compound may be removed by gas-phase reaction with HNO 3 , whose presence depends on ambient conditions and may not be appropriately represented in the scenarios used for reactivity assessment. Fo r such compounds two reactivity values are given, and "upper limit magnitude" reactivity value based on assuming that all the emitted VOC is available for gas-phas e reaction and that reaction with HNO 3 is negligible (as may be applicable if the HNO 3 formed in gas-phase reactions is removed from the gas phase by other means) and one also assuming that all the emitted VOC is available for gas-phase reaction except that the reaction with gas-phase HNO 3 is fast and there is no other sink for HNO 3 formed in the gas-phase reactions. 13 Same as code 12 except that no chamber data are available to test the estimated gas-phase mechanism. 20 The representation or estimated mechanism us ed is considered to be biased, and the direction of the likely bias is indicted by th e bias code. Best estimate mechanisms have not been developed. Additional codes used where applicable
s Portions of the mechanism are unknown or highly uncertain and simplified or parameterized representation has been adjusted at lest in part to fit available data for this or relate compounds. This is used primarily for alkylbenzenes. d Portions of this mechanism appear to be inconsistent with available laboratory data. This is used primarily for the 1-alke nes, where radical yields in O 3 reactions have to be reduced to simulate chamber data. u The mechanism is unknown and a parameterized mechanism adjusted to fit the data for this or related compounds employed. m This uncertainty code is only applicable for mixtures whose composition has been analyzed using state-of-the-science methods. Rating of effects of compositional uncertainties is beyond the scope of the project (but see discussion in Carter and Malkina (2005) for hydrocarbon mixtures). b The reactivity predictions may be more sensitive than usual to changes in the base mechanism or scenario conditions. n Chamber data for this or related compounds suggest that the mechanism may overpredict ozone under conditions where NO x is limited. This should affect MIR values but will lead to too high reactivities in lower NO x scenarios.Table C-1 (continued)

103 a This compound may react with HNO 3 to form a non-volatile salt, which may reduce the availability for this compound to react in the gas phas e. The importance of this processunder atmospheric conditions is uncertain because (a) the salt may revolatilize to the gasphase species and the equilibrium constant is unknown, (b) the sources and other sinks for HNO 3 may vary significantly from scenario to scenario and have not been established for the reactivity assessment scenarios, and (c ) if ammonia or other amines are present they may compet e for the HNO 3 and reduce the importance of this process for this amine, and the importance of these processes have not been established for the reactivity scenarios. In order to derive an upper limit ozone impact estimate, the reactivities of these compounds have been calculated as suming that removal by reaction with HNO 3 is uncertain. If this process is important, the magnitude of the actual ozone impact may be an order of magnitude or more low. Therefor e, the tabulated reactivity values are upper limits for positively reactive compounds, and lower limits for ozone inhibitors. + This may appropriately be considered to be an upper limit estimate in the ozone impact of this compound. -- This may appropriately be considered to be an upper limit estimate in the amount of ozone inhibition caused by this compou nd. The upper limit r eactivity is zero.