5420 Mainway Drive, Burlington ON, Canada, L7L 6A4

Client Project Information

Project ID: 050352.0031 Eramet

Contact: Tom Gerstle

ALSE Project Information

Project ID: EQM100

Contact: Ron McLeod

Submission ID(s): L1535265

Final Package Review by:

Date Reviewed: 5-Dec-14

SVOC DATA PACKAGE
5420 Mainway Drive, Burlington ON, Canada, L7L 6A4

ALSE Project Information Client Project Information

Project ID: EQM100 Project ID: 050352.0031 Eramet

Contact: Ron McLeod Contact: Tom Gerstle

Submission ID(s): L1535265

Analyical Method: PAH via modified CARB 429

Date Date Date Date

ALS Sample ID Client Sample Descriptions Matrix Sampled Received Extracted Analyzed

L1535265-1 MAIN BAGHOUSE RUN#1 Stack 15-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-2 MAIN BAGHOUSE RUN#2 Stack 15-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-3 FIELD BLANK Stack 14-Oct-14 20-Oct-14 28-Oct-14 15-Nov-14

L1535265-4 ACETONE/HEXANE/METH. BLANK Stack 14-Oct-14 20-Oct-14 28-Oct-14 15-Nov-14

L1535265-5 MAIN BAGHOUSE RUN#3 Stack 15-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-6 MAIN BAGHOUSE RUN#4 Stack 15-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-7 FURNACE 12 RUN#1 Stack 16-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-8 FURNACE 12 RUN#2 Stack 16-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-9 FURNACE 12 RUN#3 Stack 16-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-10 FURNACE 12 RUN#4 Stack 16-Oct-14 20-Oct-14 28-Oct-14 16-Nov-14

L1535265-11 BLANK XAD Trap 22-Oct-14 23-Oct-14 28-Oct-14 15-Nov-14

WG1980014-1 Method Blank QC n/a n/a 28-Oct-14 15-Nov-14

WG1980014-2 Laboratory Control Sample QC n/a n/a 28-Oct-14 15-Nov-14

Comments and Notes:

a) Sample Integrity:

The samples were received in good condition at 8.2 degrees C, which is marginally above the method recommended temperature (7 degrees C).

No negative impact to data quality is expected.

b) Instrumental Analysis:

The method blank was lost during laboratory processing and has not been reported. The field blank serves as an indication that the sample data

are not impacted by significant laboratory background.

Selected targets from selected samples have been reported from the analysis of diluted extracts that have been re-spiked with quantification

standard. As a result, these data are not calculated by isotope dilution and are not inherently recovery-corrected. Reported extraction standard

recoveries for these targets are not indicative of extraction efficiency as they have been spiked after extraction.

This includes all Main Baghouse results where the dilution factor is noted to be 10 or 100.

An additional high level calibration standard has been analyzed and included in the mean RRF for selected targets.

Field spike standards were added to the XAD2 in the traps before sampling. Extraction standards were added as internal standards to the XAD2 and 

filters just prior to extraction. The recovery standards (or injection standards) were added to the extracts just prior to instrumental analysis. For higher 

dilutions and where the extraction standards would otherwise be diluted below the levels of significant instrument response, the extracts were fortified 

with extraction standards before injection.

SVOC DATA PACKAGE

SECTION 1: PROJECT NARRATIVE

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 1 of 84
5420 Mainway Drive, Burlington ON, Canada, L7L 6A4

ALSE Project Information Client Project Information

Project ID: EQM100 Project ID: 050352.0031 Eramet

Contact: Ron McLeod Contact: Tom Gerstle

Submission ID(s): L1535265

Analyical Method: PAH via modified CARB 429

b) Instrumental Analysis:

Field Spike Recovery Data:

Fluorene-d10 p-Terphenyl-d14

L1535265-11 BLANK 76% 48%

L1535265-3 FIELD BLANK 96% 106%

L1535265-1 MAIN BAGHOUSE RUN#1 111% 73%

L1535265-2 MAIN BAGHOUSE RUN#2 145% 65%

L1535265-5 MAIN BAGHOUSE RUN#3 104% 87%

L1535265-6 MAIN BAGHOUSE RUN#4 125% 85%

L1535265-7 FURNACE 12 RUN#1 118% 115%

L1535265-8 FURNACE 12 RUN#2 109% 85%

L1535265-9 FURNACE 12 RUN#3 114% 113%

L1535265-10 FURNACE 12 RUN#4 104% 85%

Calibration Range and the amount of isotope dilution spike used:

Estimated Project Lower 

Range

Isotope Dilution 

Upper Range

Split Factor 10 10 Pre-extraction dilution postDilution Factor 1 50 spiking spike amount

Final Extract Volume 1 1 amount added to 1mL

Target Analytes ug ug Extraction Standards ng ng

Naphthalene 0.77 1000 d8-naphthalene 1000 100

2-Me-Naphthalene 0.1 1000 d10-2-methylnaphthalene 1000 100

1-Me-Naphthalene 0.06 1000 d8-acenaphthylene 1000 100

Acenaphthylene 0.03 1000 d10-phenanthrene 1000 100

Acenaphthene 0.02 1000 d10-fluoranthene 1000 100

Fluorene 0.29 1000 d12-benz[a]anthracene 1000 100

Phenanthrene 0.25 1000 d12-chrysene 1000 100

Anthracene 0.04 1000 d12-benzo[b]fluoranthene 1000 100

Fluoranthene 0.25 1000 d12-benzo[k]fluoranthene 1000 100

Pyrene 0.19 1000 d12-benzo[a]pyrene 1000 100

Benz[a]anthracene 0.06 1000 d12-perylene 1000 100

Chrysene/Triphenylene 0.21 1000 d12-indeno[123-cd]pyrene 1000 100

Benzo[b]fluoranthene 0.07 1000 d14-dibenzo[ah]anthracene 1000 100

Benzo[k]fluoranthene 0.03 1000 d12-benzo[ghi]perylene 1000 100

Benzo[e]pyrene 0.06 1000 d10-Anthracene 1000 100

Benzo[a]pyrene 0.02 1000 d8-Carbazole 1000 100

Perylene 0.02 1000 1000 100

Indeno[1,2,3-cd]pyrene 0.02 1000

Dibenzo[a,h]anthracene 0.02 1000

Benzo[g,h,i]perylene 0.02 1000

Total PAH 2.5 ~4000

I certify that this data package is in compliance with the terms and condition of the contract, both technically and for completeness, for other than the conditions 

detailed above. Release of the data contained in this data package (hardcopy and/or electronic version) has been authorized by the Laboratory Manager

 or his designee, as verified by the following signature.

5-Dec-14

Steve Kennedy Date

ALS Project Design 2014

Sample ID

SVOC DATA PACKAGE

SECTION 1: PROJECT NARRATIVE

Extraction Standard Spiking

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 2 of 84
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

SVOC DATA PACKAGE

SECTION 2: DATA SUMMARY REPORT

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 3 of 84
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

 Phone: 905-331-3111, FAX: 905-331-4567

ALS Project Contact: Ron McLeod Client Name: Environmental Quality Management Inc

ALS Project ID: EQM100 Client Address: 1800 Carillon Boulevard

ALS WO#: L1535265 Cincinnati, OH 45240

Date of Report: 18-Nov-14

Date of Sample Receipt: 20-Oct-14 Client Contact: Tom Gerstle

Client Project ID: 050352.0031 Eramet

COMMENTS: PAH via modified CARB 429

The method blank was lost during laboratory processing and has not been reported. The field blank serves as an indication that the sample data

are not impacted by significant laboratory background.

Selected targets from selected samples have been reported from the analysis of diluted extracts that have been re-spiked with quantification

standard. As a result, these data are not calculated by isotope dilution and are not inherently recovery-corrected. Reported extraction standard

recoveries for these targets are not indicative of extraction efficiency as they have been spiked after extraction.

S.Kennedy 18-Nov-14

Certified by:

Whitney Davis

Account Manager 

Results in this certificate relate only to the samples as submitted to the laboratory.

This report shall not be reproduced, except in full, without the written permission of ALS Canada Ltd.

Certificate of Analysis

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 4 of 84
Sample Name BLANK ACETONE/HEXANE

/METH. BLANK

FIELD BLANK MAIN BAGHOUSE

RUN#1

MAIN BAGHOUSE

RUN#2

ALS Sample ID L1535265-11 L1535265-4 L1535265-3 L1535265-1 L1535265-2

Sample Size 11111

Sample units sample train train train train

Moisture Content n/a n/a n/a n/a n/a

Matrix XAD Trap Stack Stack Stack Stack

Sampling Date 22-Oct-14 14-Oct-14 14-Oct-14 15-Oct-14 15-Oct-14

Extraction Date 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14

Target Analytes ng ng ng ng ng

Naphthalene 103 2260 9270 471000 458000

2-Me-Naphthalene 12.3 4860 17900 74800 103000

1-Me-Naphthalene 10.2 3910 13600 55200 74800

Acenaphthylene 1.55 157 395 153000 188000

Acenaphthene 1.42 450 1180 32000 43400

Fluorene 6.27 648 1620 70200 121000

Phenanthrene 13.5 3380 12200 2020000 1590000

Anthracene 3.04 140 556 343000 203000

Fluoranthene 1.92 118 554 3620000 4790000

Pyrene 2.97 69.2 522 2600000 3550000

Benz[a]anthracene 4.46 7.33 96.8 268000 570000

Chrysene/Triphenylene 3.33 29.9 225 473000 1250000

Benzo[b]fluoranthene 4.90 614 187 141000 419000

Benzo[k]fluoranthene 2.88 524 51.7 41100 112000

Benzo[e]pyrene 1.74 4.47 109 51900 149000

Benzo[a]pyrene 2.59 <1.8 45.3 22600 60300

Perylene 1.55 <1.3 5.05 4080 8800

Indeno[1,2,3-cd]pyrene 7.92 4.63 30.0 8370 22900

Dibenzo[a,h]anthracene 7.65 1.66 12.4 1190 4120

Benzo[g,h,i]perylene 6.20 3.17 57.1 7330 17700

Field Spike Standards % Rec % Rec % Rec % Rec % Rec

Fluorene-d10 76 n/s 96 111 145

p-Terphenyl-d14 48 n/s 106 73 65

Extraction Standards % Rec % Rec % Rec % Rec % Rec

Naphthalene-d8 72 83 80 100 83

2-Me-Naphthalene-d10 63 84 78 99 67

Acenaphthylene-d8 49 85 81 113 60

Phenanthrene-d10 38 83 85 73 94

Anthracene-d10 40 71 71 78 95

Fluoranthene-d10 45 90 87 81 95

Benz[a]anthracene-d12 20 101 122 66 78

Chrysene-d12 22 75 93 71 79

Benzo[b]fluoranthene-d12 36 103 98 70 94

Benzo[k]fluoranthene-d12 34 77 71 74 99

Benzo[a]pyrene-d12 36 74 66 71 90

Perylene-d12 36 75 69 74 92

Indeno[1,2,3-cd]pyrene-d12 27 88 97 66 92

Dibenzo[a,h]anthracene-d14 25 89 100 64 91

Benzo[g,h,i]perylene-d12 30 86 89 73 101

ALS Environmental

Sample Analysis Summary Report

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 5 of 84
Sample Name MAIN BAGHOUSE

RUN#3

MAIN BAGHOUSE

RUN#4

FURNACE 12

RUN#1

FURNACE 12

RUN#2

FURNACE 12

RUN#3

FURNACE 12

RUN#4

ALS Sample ID L1535265-5 L1535265-6 L1535265-7 L1535265-8 L1535265-9 L1535265-10

Sample Size 111111

Sample units train train train train train train

Moisture Content n/a n/a n/a n/a n/a n/a

Matrix Stack Stack Stack Stack Stack Stack

Sampling Date 15-Oct-14 15-Oct-14 16-Oct-14 16-Oct-14 16-Oct-14 16-Oct-14

Extraction Date 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14

Target Analytes ng ng ng ng ng ng

Naphthalene 326000 347000 41700 20200 44100 43900

2-Me-Naphthalene 53700 71100 14100 13900 18300 16400

1-Me-Naphthalene 41000 49900 9600 10400 13200 11700

Acenaphthylene 75000 129000 14800 3670 15000 19100

Acenaphthene 19400 20900 1780 1620 2330 2050

Fluorene 41500 70100 2740 2370 3500 3080

Phenanthrene 1590000 1370000 36400 22200 74000 43500

Anthracene 208000 167000 8620 3610 13200 10500

Fluoranthene 4100000 2070000 36800 11800 64500 30400

Pyrene 2990000 1430000 26800 7950 46900 23100

Benz[a]anthracene 707000 177000 3530 3350 3510 3290

Chrysene/Triphenylene 1480000 461000 13800 9990 10600 5200

Benzo[b]fluoranthene 614000 178000 5170 5290 5060 3160

Benzo[k]fluoranthene 207000 59300 1950 2630 1880 1250

Benzo[e]pyrene 233000 75000 2540 2770 2150 1660

Benzo[a]pyrene 121000 30000 831 457 510 681

Perylene 20600 6220 107 87.8 60.4 133

Indeno[1,2,3-cd]pyrene 40300 11200 1060 1170 651 980

Dibenzo[a,h]anthracene 5890 1980 207 324 129 204

Benzo[g,h,i]perylene 27600 8400 821 751 528 807

Field Spike Standards % Rec % Rec % Rec % Rec % Rec % Rec

Fluorene-d10 104 125 118 109 114 104

p-Terphenyl-d14 87 85 115 85 113 85

Extraction Standards % Rec % Rec % Rec % Rec % Rec % Rec

Naphthalene-d8 97 103 68 90 105 95

2-Me-Naphthalene-d10 116 90 71 91 70 71

Acenaphthylene-d8 104 92 75 88 72 68

Phenanthrene-d10 81 81 108 81 105 77

Anthracene-d10 84 86 103 99 109 81

Fluoranthene-d10 84 87 120 103 102 87

Benz[a]anthracene-d12 71 73 108 64 103 44

Chrysene-d12 73 78 71 48 74 35

Benzo[b]fluoranthene-d12 79 80 96 87 95 67

Benzo[k]fluoranthene-d12 86 81 72 57 94 54

Benzo[a]pyrene-d12 82 78 73 78 72 56

Perylene-d12 81 80 76 81 74 57

Indeno[1,2,3-cd]pyrene-d12 70 76 92 90 97 58

Dibenzo[a,h]anthracene-d14 72 73 95 91 101 56

Benzo[g,h,i]perylene-d12 80 85 92 91 95 55

ALS Environmental

Sample Analysis Summary Report

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 6 of 84
Sample Name Laboratory Control

Sample

ALS Sample ID WG1980014-2

Sample Size 1

Sample units n/a

Moisture Content n/a

Matrix QC

Sampling Date n/a

Extraction Date 28-Oct-14

Target Analytes % Rec

Naphthalene 123

2-Me-Naphthalene n/s

1-Me-Naphthalene n/s

Acenaphthylene 98

Acenaphthene 103

Fluorene 105

Phenanthrene 99

Anthracene 101

Fluoranthene 102

Pyrene 92

Benz[a]anthracene 103

Chrysene/Triphenylene 97

Benzo[b]fluoranthene 109

Benzo[k]fluoranthene 103

Benzo[e]pyrene n/s

Benzo[a]pyrene 89

Perylene n/s

Indeno[1,2,3-cd]pyrene 111

Dibenzo[a,h]anthracene 104

Benzo[g,h,i]perylene 104

Field Spike Standards % Rec

Fluorene-d10 n/s

p-Terphenyl-d14 n/s

Extraction Standards % Rec

Naphthalene-d8 85

2-Me-Naphthalene-d10 81

Acenaphthylene-d8 84

Phenanthrene-d10 80

Anthracene-d10 74

Fluoranthene-d10 91

Benz[a]anthracene-d12 56

Chrysene-d12 50

Benzo[b]fluoranthene-d12 85

Benzo[k]fluoranthene-d12 79

Benzo[a]pyrene-d12 75

Perylene-d12 79

Indeno[1,2,3-cd]pyrene-d12 79

Dibenzo[a,h]anthracene-d14 80

Benzo[g,h,i]perylene-d12 81

ALS Environmental

Quality Control Sample Analysis Summary Report

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 7 of 84
Sample Name CCV CCV CCV

ALS Sample ID H4-14-CCV-0452 H4-14-CCV-0453 H4-14-CCV-0454

Sample Size 111

Sample units n/a n/a n/a

Moisture Content n/a n/a n/a

Matrix QC QC QC

Sampling Date n/a n/a n/a

Extraction Date n/a n/a n/a

Target Analytes % Rec % Rec % Rec

Naphthalene 88 87 77

2-Me-Naphthalene 98 95 88

1-Me-Naphthalene 100 98 88

Acenaphthylene 93 92 84

Acenaphthene 99 100 97

Fluorene 96 101 132

Phenanthrene 87 86 85

Anthracene 88 93 88

Fluoranthene 89 92 81

Pyrene 88 91 81

Benz[a]anthracene 84 90 76

Chrysene/Triphenylene 96 88 82

Benzo[b]fluoranthene 90 100 89

Benzo[k]fluoranthene 101 97 96

Benzo[e]pyrene 88 90 85

Benzo[a]pyrene 91 91 85

Perylene 94 95 92

Indeno[1,2,3-cd]pyrene 91 92 77

Dibenzo[a,h]anthracene 103 104 90

Benzo[g,h,i]perylene 96 94 84

Field Spike Standards % Rec % Rec % Rec

Fluorene-d10 100 101 141

p-Terphenyl-d14 113 115 120

Extraction Standards % Rec % Rec % Rec

Naphthalene-d8 103 95 81

2-Me-Naphthalene-d10 101 95 97

Acenaphthylene-d8 97 91 87

Phenanthrene-d10 100 91 76

Anthracene-d10 106 91 84

Fluoranthene-d10 101 96 101

Benz[a]anthracene-d12 102 93 66

Chrysene-d12 101 100 83

Benzo[b]fluoranthene-d12 102 91 80

Benzo[k]fluoranthene-d12 96 93 90

Benzo[a]pyrene-d12 95 96 99

Perylene-d12 103 102 107

Indeno[1,2,3-cd]pyrene-d12 109 117 139

Dibenzo[a,h]anthracene-d14 122 130 167

Benzo[g,h,i]perylene-d12 111 117 143

ALS Environmental

Continuing Calibration Verification Summary Report

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 8 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-11 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A15

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units ng

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL

Target Analytes Time ng ng

Naphthalene 7:33 103 1.3 M

2-Me-Naphthalene 8:44 12.3 0.25 M J

1-Me-Naphthalene 8:54 10.2 0.26 M J

Acenaphthylene 10:10 1.55 0.072 M J

Acenaphthene 10:27 1.42 0.22 J

Fluorene 11:18 6.27 0.48 M J

Phenanthrene 12:51 13.5 0.40 M J

Anthracene 12:56 3.04 0.52 M J

Fluoranthene 14:47 1.92 0.38 M J

Pyrene 15:09 2.97 0.36 M J

Benz[a]anthracene 17:32 4.46 0.22 M J

Chrysene/Triphenylene 17:37 3.33 0.22 M J

Benzo[b]fluoranthene 19:44 4.90 0.64 M J

Benzo[k]fluoranthene 19:47 2.88 0.69 M J

Benzo[e]pyrene 20:14 1.74 0.75 M J

Benzo[a]pyrene 20:21 2.59 0.78 M J

Perylene 20:30 1.55 0.60 M J

Indeno[1,2,3-cd]pyrene 22:22 7.92 1.4 M J

Dibenzo[a,h]anthracene 22:26 7.65 1.3 M J

Benzo[g,h,i]perylene 22:46 6.20 0.74 M J

Field Spike Standards % Rec Limits

Fluorene-d10 11:15 76 50-150

p-Terphenyl-d14 15:34 48 50-150

Extraction Standards % Rec Limits

Naphthalene-d8 7:31 72 20-150

2-Me-Naphthalene-d10 8:40 63 20-150

Acenaphthylene-d8 10:08 49 20-150

Phenanthrene-d10 12:48 38 30-150

Anthracene-d10 12:53 40 30-150

Fluoranthene-d10 14:45 45 30-150

Benz[a]anthracene-d12 17:29 20 30-150

Chrysene-d12 17:33 22 30-150

Benzo[b]fluoranthene-d12 19:41 36 30-150

Benzo[k]fluoranthene-d12 19:44 34 30-150

Benzo[a]pyrene-d12 20:17 36 30-150

Perylene-d12 20:27 36 30-150

Indeno[1,2,3-cd]pyrene-d12 22:20 27 30-150

Dibenzo[a,h]anthracene-d14 22:23 25 30-150

Benzo[g,h,i]perylene-d12 22:44 30 30-150

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

BLANK 22-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 sample Ella Gdyczynski

n/a --e-signature--

XAD Trap 10 17-Nov-2014

15-Nov-14 20:44

Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 9 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-4 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A16

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units ng

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL

Target Analytes Time ng ng

Naphthalene 7:33 2260 16 M

2-Me-Naphthalene 8:42 4860 7.2

1-Me-Naphthalene 8:52 3910 7.6

Acenaphthylene 10:09 157 1.4 M

Acenaphthene 10:26 450 3.4 M

Fluorene 11:17 648 1.6 M

Phenanthrene 12:50 3380 2.2 M

Anthracene 12:55 140 2.6 M

Fluoranthene 14:46 118 0.92 M

Pyrene 15:09 69.2 0.86 M J

Benz[a]anthracene 17:32 7.33 0.40 M J

Chrysene/Triphenylene 17:35 29.9 0.43 M J

Benzo[b]fluoranthene 19:45 614 1.3 M

Benzo[k]fluoranthene 19:47 524 1.6 M

Benzo[e]pyrene 20:15 4.47 1.7 M J

Benzo[a]pyrene NotFnd <1.8 1.8 M U

Perylene NotFnd <1.3 1.3 M U

Indeno[1,2,3-cd]pyrene 22:22 4.63 0.90 M J

Dibenzo[a,h]anthracene 22:26 1.66 0.45 M J

Benzo[g,h,i]perylene 22:46 3.17 0.55 M J

Field Spike Standards % Rec Limits

Fluorene-d10 11:14 n/s

p-Terphenyl-d14 15:34 n/s

Extraction Standards % Rec Limits

Naphthalene-d8 7:31 83 20-150

2-Me-Naphthalene-d10 8:39 84 20-150

Acenaphthylene-d8 10:08 85 20-150

Phenanthrene-d10 12:47 83 30-150

Anthracene-d10 12:52 71 30-150

Fluoranthene-d10 14:44 90 30-150

Benz[a]anthracene-d12 17:29 101 30-150

Chrysene-d12 17:32 75 30-150

Benzo[b]fluoranthene-d12 19:40 103 30-150

Benzo[k]fluoranthene-d12 19:44 77 30-150

Benzo[a]pyrene-d12 20:17 74 30-150

Perylene-d12 20:27 75 30-150

Indeno[1,2,3-cd]pyrene-d12 22:19 88 30-150

Dibenzo[a,h]anthracene-d14 22:22 89 30-150

Benzo[g,h,i]perylene-d12 22:44 86 30-150

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

U Indicates that this compound was not detected above the MDL.

n/s Indicates that this standard has not been spiked.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

ACETONE/HEXANE/METH. BLANK 14-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 10 17-Nov-2014

15-Nov-14 21:18

Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 10 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-3 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A17

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units ng

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL

Target Analytes Time ng ng

Naphthalene 7:35 9270 39 M

2-Me-Naphthalene 8:43 17900 2.5

1-Me-Naphthalene 8:53 13600 2.6

Acenaphthylene 10:10 395 1.4 M

Acenaphthene 10:27 1180 6.5 M

Fluorene 11:17 1620 2.9 M

Phenanthrene 12:50 12200 8.3 M

Anthracene 12:55 556 10 M

Fluoranthene 14:47 554 1.8 M

Pyrene 15:09 522 1.7 M

Benz[a]anthracene 17:32 96.8 1.2 M J

Chrysene/Triphenylene 17:36 225 1.3 M

Benzo[b]fluoranthene 19:43 187 0.61 M

Benzo[k]fluoranthene 19:46 51.7 0.70 M J

Benzo[e]pyrene 20:14 109 0.85 M

Benzo[a]pyrene 20:20 45.3 0.89 M J

Perylene 20:30 5.05 0.61 M J

Indeno[1,2,3-cd]pyrene 22:22 30.0 2.1 M J

Dibenzo[a,h]anthracene 22:26 12.4 0.98 M J

Benzo[g,h,i]perylene 22:47 57.1 1.4 M J

Field Spike Standards % Rec Limits

Fluorene-d10 11:14 96 50-150

p-Terphenyl-d14 15:34 106 50-150

Extraction Standards % Rec Limits

Naphthalene-d8 7:33 80 20-150

2-Me-Naphthalene-d10 8:40 78 20-150

Acenaphthylene-d8 10:08 81 20-150

Phenanthrene-d10 12:48 85 30-150

Anthracene-d10 12:53 71 30-150

Fluoranthene-d10 14:45 87 30-150

Benz[a]anthracene-d12 17:29 122 30-150

Chrysene-d12 17:32 93 30-150

Benzo[b]fluoranthene-d12 19:40 98 30-150

Benzo[k]fluoranthene-d12 19:44 71 30-150

Benzo[a]pyrene-d12 20:17 66 30-150

Perylene-d12 20:27 69 30-150

Indeno[1,2,3-cd]pyrene-d12 22:19 97 30-150

Dibenzo[a,h]anthracene-d14 22:22 100 30-150

Benzo[g,h,i]perylene-d12 22:43 89 30-150

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

FIELD BLANK 14-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 10 17-Nov-2014

15-Nov-14 21:52

Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 11 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-1 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2 Run 3

Filename 4-141115B17 4-141115B04 4-141115A19

Run Date

Final Volume 1000 uL 1000 uL 1000 uL

Dilution Factor 1 10 100

Analysis Units ng ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng Time. ng ng

Naphthalene 7:33 471000 390 7:34 604000 1400 7:34 686000 5800 M

2-Me-Naphthalene 8:43 74800 58 M 8:43 117000 170 8:43 141000 4100 J

1-Me-Naphthalene 8:52 55200 60 M 8:52 94800 180 8:52 126000 4300 J

Acenaphthylene 10:10 153000 19 M 10:10 255000 360 M 10:09 238000 1800 M J

Acenaphthene 10:27 32000 130 M 10:27 53700 530 M 10:27 44400 2500 M J

Fluorene 11:18 70200 110 M 11:19 102000 450 M 11:18 104000 2400 M J

Phenanthrene 12:50 1130000 93 M E 12:50 2020000 130 M 12:50 1970000 2600 M

Anthracene 12:55 129000 96 M 12:55 343000 150 M 12:55 385000 3300 M J

Fluoranthene 14:47 2000000 260 M E 14:47 3620000 1600 M 14:46 3810000 3600 M

Pyrene 15:10 1670000 250 M E 15:09 2600000 1500 M 15:09 2780000 3300 M

Benz[a]anthracene 17:33 153000 99 M 17:32 268000 1200 M 17:32 220000 3700 M J

Chrysene/Triphenylene 17:36 314000 100 M 17:36 473000 1100 M 17:36 470000 3200 M J

Benzo[b]fluoranthene 19:44 79700 90 M 19:44 141000 340 M 19:44 116000 1100 M J

Benzo[k]fluoranthene 19:47 36200 92 M 19:46 41100 380 M J 19:46 51100 1100 M J

Benzo[e]pyrene 20:15 10800 26 M 20:14 51900 390 M 20:14 53600 1200 M J

Benzo[a]pyrene 20:21 5150 28 M 20:21 22600 410 M J 20:21 23300 1200 M J

Perylene 20:31 2500 48 M J 20:30 4080 300 M J 20:31 6630 710 M J

Indeno[1,2,3-cd]pyrene NotFnd <34000 34000 M U 22:22 8370 380 M J 22:22 8760 3000 M J

Dibenzo[a,h]anthracene 22:27 885 220 M J 22:26 1190 250 M J 22:28 3790 2300 M J

Benzo[g,h,i]perylene 22:48 4620 120 M J 22:46 7330 190 M J 22:47 7050 1500 M J

Field Spike Standards % Rec Limits % Rec % Rec

Fluorene-d10 11:15 111 50-150 11:15 141 11:15 222

p-Terphenyl-d14 15:34 73 50-150 15:34 158 15:34 59

Extraction Standards % Rec Limits % Rec % Rec

Naphthalene-d8 7:32 100 20-150 7:32 77 7:32 80

2-Me-Naphthalene-d10 8:40 99 20-150 8:40 70 8:40 68

Acenaphthylene-d8 10:08 113 20-150 10:08 75 10:08 80

Phenanthrene-d10 12:48 119 30-150 12:48 73 12:48 64

Anthracene-d10 12:53 128 30-150 12:53 78 12:53 63

Fluoranthene-d10 14:45 131 30-150 14:45 81 14:45 67

Benz[a]anthracene-d12 17:30 66 30-150 17:29 66 17:29 52

Chrysene-d12 17:33 57 30-150 17:32 71 17:33 73

Benzo[b]fluoranthene-d12 19:41 121 30-150 19:41 70 19:40 67

Benzo[k]fluoranthene-d12 19:44 100 30-150 19:44 74 19:44 67

Benzo[a]pyrene-d12 20:18 316 30-150 20:17 71 20:18 73

Perylene-d12 20:28 147 30-150 20:27 74 20:27 70

Indeno[1,2,3-cd]pyrene-d12 22:15 76 30-150 22:20 66 22:20 65

Dibenzo[a,h]anthracene-d14 22:25 37 M 30-150 22:23 64 22:24 61

Benzo[g,h,i]perylene-d12 22:45 105 30-150 22:44 73 22:44 83

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

U Indicates that this compound was not detected above the MDL.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN#1 15-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 500 17-Nov-2014

16-Nov-14 11:01 16-Nov-14 03:35 15-Nov-14 23:01

Flags Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 12 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-2 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2 Run 3

Filename 4-141115B18 4-141115B05 4-141115A20

Run Date

Final Volume 1000 uL 1000 uL 1000 uL

Dilution Factor 1 10 100

Analysis Units ng ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng Time. ng ng

Naphthalene 7:34 458000 240 M 7:34 437000 700 7:35 570000 4400 M

2-Me-Naphthalene 8:43 103000 36 8:43 79900 180 8:44 107000 2800 J

1-Me-Naphthalene 8:52 74800 38 8:53 65500 190 8:53 83800 2900 J

Acenaphthylene 10:10 188000 110 M 10:10 156000 500 M 10:09 147000 830 M J

Acenaphthene 10:27 43400 52 M 10:27 32900 120 J 10:28 32700 1100 M J

Fluorene 11:19 121000 140 M 11:19 57300 120 M 11:18 71300 1900 M J

Phenanthrene 12:50 2480000 220 M E 12:50 1590000 790 M 12:51 1600000 2300 M

Anthracene 12:55 205000 250 M 12:55 203000 970 M 12:55 261000 3300 M J

Fluoranthene 14:47 5300000 450 M E 14:47 4790000 1900 M 14:47 4050000 570 M

Pyrene 15:10 4720000 420 M E 15:10 3550000 1700 M 15:09 3210000 530 M

Benz[a]anthracene 17:32 1120000 670 M E 17:32 570000 370 M 17:32 466000 2500 M J

Chrysene/Triphenylene 17:36 2400000 600 M E 17:36 1250000 350 M 17:32 536000 2800 M

Benzo[b]fluoranthene 19:44 776000 180 M E 19:44 419000 440 M 19:44 400000 3700 M J

Benzo[k]fluoranthene 19:47 152000 120 M 19:47 112000 480 M 19:47 126000 4300 M J

Benzo[e]pyrene 20:15 88000 41 M 20:14 149000 540 M 20:15 142000 4000 M J

Benzo[a]pyrene 20:21 38700 43 M 20:20 60300 560 M 20:21 71400 4200 M J

Perylene 20:31 16200 95 M 20:30 8800 440 M J 20:30 5550 3100 M J

Indeno[1,2,3-cd]pyrene 22:23 46800 150 M 22:22 22900 620 M J 22:22 26600 3600 M J

Dibenzo[a,h]anthracene 22:27 8480 210 M 22:27 4120 200 M J 22:27 5290 2200 M J

Benzo[g,h,i]perylene 22:48 29100 140 M 22:46 17700 320 M J 22:46 18000 1600 M J

Field Spike Standards % Rec Limits % Rec % Rec

Fluorene-d10 11:15 175 50-150 11:15 145 11:16 60 

p-Terphenyl-d14 15:35 173 50-150 15:35 65 15:36 186 

Extraction Standards % Rec Limits % Rec % Rec

Naphthalene-d8 7:32 83 20-150 7:32 94 7:32 97 

2-Me-Naphthalene-d10 8:40 67 20-150 8:40 98 8:40 87 

Acenaphthylene-d8 10:08 60 20-150 10:08 88 10:08 93 

Phenanthrene-d10 12:48 54 30-150 12:48 94 12:48 78 

Anthracene-d10 12:53 52 30-150 12:53 95 12:53 84 

Fluoranthene-d10 14:45 52 30-150 14:45 95 14:45 102 

Benz[a]anthracene-d12 17:29 27 30-150 17:29 78 17:30 80

Chrysene-d12 17:33 28 30-150 17:32 79 17:30 48

Benzo[b]fluoranthene-d12 19:41 47 M 30-150 19:40 94 19:41 79

Benzo[k]fluoranthene-d12 19:44 68 M 30-150 19:44 99 19:44 85

Benzo[a]pyrene-d12 20:18 136 M 30-150 20:17 90 20:18 86

Perylene-d12 20:28 50 M 30-150 20:27 92 20:27 88

Indeno[1,2,3-cd]pyrene-d12 22:21 33 M 30-150 22:19 92 22:20 87

Dibenzo[a,h]anthracene-d14 22:25 33 M 30-150 22:23 91 22:23 81

Benzo[g,h,i]perylene-d12 22:45 39 M 30-150 22:44 101 22:44 111

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN#2 15-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 500 17-Nov-2014

16-Nov-14 11:36 16-Nov-14 04:10 15-Nov-14 23:35

Flags Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 13 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-5 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2 Run 3

Filename 4-141115B19 4-141115B06 4-141115A21

Run Date

Final Volume 1000 uL 1000 uL 1000 uL

Dilution Factor 1 10 100

Analysis Units ng ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng Time. ng ng

Naphthalene 7:34 326000 97 7:33 445000 860 7:34 530000 11000

2-Me-Naphthalene 8:44 53700 19 8:43 88100 440 8:44 106000 2900 J

1-Me-Naphthalene 8:53 41000 20 8:52 65400 460 8:53 93800 3100 J

Acenaphthylene 10:11 75000 59 10:09 125000 270 M 10:10 120000 1900 M J

Acenaphthene 10:27 19400 19 M 10:26 26600 340 M J 10:27 25900 2000 M J

Fluorene 11:18 41500 65 M 11:18 58100 310 M 11:19 60300 2200 M J

Phenanthrene 12:50 1090000 97 M E 12:49 1590000 130 M 12:51 1570000 7600 M

Anthracene 12:55 95500 110 M 12:54 208000 160 M 12:55 358000 12000 M J

Fluoranthene 14:47 2300000 140 M E 14:46 4100000 620 M 14:47 3340000 7500 M

Pyrene 15:10 1940000 130 M E 15:09 2990000 580 M 15:10 2600000 7000 M

Benz[a]anthracene 17:32 584000 51 M 17:31 707000 200 M 17:33 640000 2000 M

Chrysene/Triphenylene 17:37 1290000 47 M E 17:35 1480000 190 M 17:36 1640000 1800 M

Benzo[b]fluoranthene 19:44 481000 89 M E 19:44 614000 320 M 19:44 634000 4400 M

Benzo[k]fluoranthene 19:47 164000 86 M 19:45 207000 320 M 19:47 206000 5000 M J

Benzo[e]pyrene 20:15 72900 35 M 20:14 233000 380 M 20:15 245000 5600 M J

Benzo[a]pyrene 20:21 38500 36 M 20:20 121000 390 M 20:21 126000 5800 M J

Perylene 20:31 16800 82 20:30 20600 290 M J 20:31 23900 3900 M J

Indeno[1,2,3-cd]pyrene 22:23 27200 310 M 22:21 40300 490 M J 22:23 30300 4500 M J

Dibenzo[a,h]anthracene 22:27 5510 200 M 22:26 5890 260 M J 22:28 7220 3400 M J

Benzo[g,h,i]perylene 22:48 16000 200 M 22:46 27600 250 M J 22:47 25500 2000 M J

Field Spike Standards % Rec Limits % Rec % Rec

Fluorene-d10 11:15 104 50-150 11:14 131 11:15 142 

p-Terphenyl-d14 15:35 87 50-150 15:34 176 15:37 67 

Extraction Standards % Rec Limits % Rec % Rec

Naphthalene-d8 7:32 97 20-150 7:31 85 7:32 94 

2-Me-Naphthalene-d10 8:40 116 20-150 8:40 86 8:40 78 

Acenaphthylene-d8 10:09 104 20-150 10:08 81 10:09 84 

Phenanthrene-d10 12:48 119 30-150 12:47 81 12:48 75 

Anthracene-d10 12:53 105 30-150 12:53 84 12:54 69 

Fluoranthene-d10 14:45 109 30-150 14:44 84 14:45 93 

Benz[a]anthracene-d12 17:29 80 30-150 17:28 71 17:30 69

Chrysene-d12 17:33 71 30-150 17:32 73 17:33 81

Benzo[b]fluoranthene-d12 19:41 105 M 30-150 19:40 79 19:41 73

Benzo[k]fluoranthene-d12 19:44 99 M 30-150 19:44 86 19:45 80

Benzo[a]pyrene-d12 20:17 233 M 30-150 20:17 82 20:18 80 

Perylene-d12 20:23 90 M 30-150 20:27 81 20:28 83 

Indeno[1,2,3-cd]pyrene-d12 22:21 87 30-150 22:19 70 22:20 76 

Dibenzo[a,h]anthracene-d14 22:25 70 30-150 22:22 72 22:24 70 

Benzo[g,h,i]perylene-d12 22:45 121 30-150 22:43 80 22:44 85 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN#3 15-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 500 17-Nov-2014

16-Nov-14 12:10 16-Nov-14 04:44 16-Nov-14 00:09

Flags Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 14 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-6 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B20 4-141115B07

Run Date

Final Volume 1000 uL 1000 uL

Dilution Factor 1 10

Analysis Units ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng

Naphthalene 7:33 347000 200 7:34 487000 820

2-Me-Naphthalene 8:43 71100 31 8:44 88700 190

1-Me-Naphthalene 8:52 49900 33 8:52 67900 190

Acenaphthylene 10:09 129000 28 M 10:09 188000 360 M

Acenaphthene 10:27 20900 120 M 10:27 29500 170 M J

Fluorene 11:18 70100 39 M 11:19 83400 230 M

Phenanthrene 12:50 1320000 100 M E 12:51 1370000 260 M

Anthracene 12:54 104000 120 M 12:55 167000 330 M

Fluoranthene 14:47 1820000 74 M E 14:47 2070000 810 M

Pyrene 15:09 1460000 69 M E 15:09 1430000 750 M

Benz[a]anthracene 17:32 176000 92 M 17:32 177000 230 M

Chrysene/Triphenylene 17:36 394000 79 M 17:36 461000 220 M

Benzo[b]fluoranthene 19:44 158000 440 M 19:44 178000 240 M

Benzo[k]fluoranthene 19:46 59100 510 M 19:46 59300 250 M

Benzo[e]pyrene 20:14 35200 240 M 20:15 75000 270 M

Benzo[a]pyrene 20:21 14500 240 M 20:21 30000 280 M J

Perylene 20:30 3510 340 M J 20:30 6220 220 M J

Indeno[1,2,3-cd]pyrene 22:23 12800 120 M 22:22 11200 280 M J

Dibenzo[a,h]anthracene 22:28 1900 97 M J 22:26 1980 240 J

Benzo[g,h,i]perylene 22:48 9830 68 M 22:47 8400 140 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 125 50-150 11:16 159

p-Terphenyl-d14 15:34 85 50-150 15:34 34

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:31 103 20-150 7:32 86

2-Me-Naphthalene-d10 8:40 90 20-150 8:40 84

Acenaphthylene-d8 10:08 92 20-150 10:08 81

Phenanthrene-d10 12:48 92 30-150 12:48 81

Anthracene-d10 12:53 92 30-150 12:53 86

Fluoranthene-d10 14:44 95 30-150 14:45 87

Benz[a]anthracene-d12 17:29 52 30-150 17:29 73

Chrysene-d12 17:32 53 30-150 17:33 78

Benzo[b]fluoranthene-d12 19:41 81 M 30-150 19:41 80

Benzo[k]fluoranthene-d12 19:44 74 M 30-150 19:44 81

Benzo[a]pyrene-d12 20:20 142 M 30-150 20:17 78

Perylene-d12 20:27 104 M 30-150 20:27 80

Indeno[1,2,3-cd]pyrene-d12 22:21 52 30-150 22:19 76

Dibenzo[a,h]anthracene-d14 22:24 51 30-150 22:23 73

Benzo[g,h,i]perylene-d12 22:45 57 30-150 22:44 85

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN#4 15-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 500 17-Nov-2014

16-Nov-14 12:44 16-Nov-14 05:18

Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 15 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-7 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B12 4-141115B08

Run Date

Final Volume 1000 uL 1000 uL

Dilution Factor 1 50

Analysis Units ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng

Naphthalene 7:34 41700 41 M 7:33 37700 61 M

2-Me-Naphthalene 8:43 14100 17 8:43 14500 11

1-Me-Naphthalene 8:53 9600 18 8:52 12700 11

Acenaphthylene 10:10 14800 2.9 M 10:10 12100 26 M

Acenaphthene 10:27 1780 1.5 M 10:27 1950 34 M J

Fluorene 11:18 2740 15 M 11:19 2540 49 M J

Phenanthrene 12:50 30000 6.6 M E 12:51 36400 15 M

Anthracene 12:55 4750 7.3 M 12:56 8620 21 M

Fluoranthene 14:47 38100 7.9 M E 14:47 36800 26 M

Pyrene 15:10 31400 7.4 M E 15:09 26800 24 M

Benz[a]anthracene 17:32 3530 3.7 M 17:33 2190 53 M J

Chrysene/Triphenylene 17:36 13800 4.0 M 17:33 2520 61 M J

Benzo[b]fluoranthene 19:44 5170 1.4 M 19:45 4060 18 M J

Benzo[k]fluoranthene 19:47 1950 1.5 M 19:47 2940 24 M J

Benzo[e]pyrene 20:15 2540 1.8 M 20:15 842 5.5 M J

Benzo[a]pyrene 20:21 831 1.8 M 20:22 108 5.7 M J

Perylene 20:31 107 1.4 M 20:30 85.2 12 M J

Indeno[1,2,3-cd]pyrene 22:22 1060 0.62 M 22:25 1040 26 M J

Dibenzo[a,h]anthracene 22:26 207 0.83 M 22:27 216 28 M J

Benzo[g,h,i]perylene 22:47 821 0.36 M 22:48 579 14 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 118 50-150 11:15 94 

p-Terphenyl-d14 15:34 115 50-150 15:35 78 

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 68 20-150 7:31 119 

2-Me-Naphthalene-d10 8:41 71 20-150 8:40 100 

Acenaphthylene-d8 10:09 75 20-150 10:08 108 

Phenanthrene-d10 12:48 79 30-150 12:48 108 

Anthracene-d10 12:53 69 30-150 12:53 103 

Fluoranthene-d10 14:45 82 30-150 14:45 120 

Benz[a]anthracene-d12 17:29 108 30-150 17:30 67 

Chrysene-d12 17:33 71 30-150 17:30 41 

Benzo[b]fluoranthene-d12 19:41 96 30-150 19:42 103 M 

Benzo[k]fluoranthene-d12 19:44 72 30-150 19:46 74 M 

Benzo[a]pyrene-d12 20:17 73 30-150 20:17 354 M 

Perylene-d12 20:27 76 30-150 20:28 101 M 

Indeno[1,2,3-cd]pyrene-d12 22:20 92 30-150 22:21 67 M 

Dibenzo[a,h]anthracene-d14 22:23 95 30-150 22:24 26 

Benzo[g,h,i]perylene-d12 22:44 92 30-150 22:45 113 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#1 16-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 10 17-Nov-2014

16-Nov-14 08:10 16-Nov-14 05:52

Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 16 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-8 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B13 4-141115B09

Run Date

Final Volume 1000 uL 1000 uL

Dilution Factor 1 50

Analysis Units ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng

Naphthalene 7:34 26400 63 E 7:33 20200 200

2-Me-Naphthalene 8:44 13900 3.4 8:43 13200 18

1-Me-Naphthalene 8:53 10400 3.5 8:52 12600 19

Acenaphthylene 10:10 3670 3.2 M 10:09 3480 18 M J

Acenaphthene 10:28 1620 1.9 10:26 1630 16 M J

Fluorene 11:18 2370 5.3 M 11:17 2860 34 M J

Phenanthrene 12:51 22700 7.8 M E 12:51 22200 63 M

Anthracene 12:55 1820 9.8 M 12:54 3610 76 M J

Fluoranthene 14:47 11800 4.1 M 14:47 10700 4.5

Pyrene 15:10 7950 3.8 M 15:10 8380 4.2 M

Benz[a]anthracene 17:32 3350 4.7 M 17:34 3330 11 M J

Chrysene/Triphenylene 17:37 9990 5.0 M 17:37 9600 8.7 M

Benzo[b]fluoranthene 19:44 5460 3.2 M E 19:44 5290 34 M

Benzo[k]fluoranthene 19:47 1600 3.6 M 19:48 2630 39 M J

Benzo[e]pyrene 20:15 2770 4.9 M 20:14 1560 8.0 M J

Benzo[a]pyrene 20:21 457 5.1 M 20:21 132 8.3 M J

Perylene 20:31 87.8 3.6 M J 20:30 163 17 M J

Indeno[1,2,3-cd]pyrene 22:23 1170 3.8 M 22:24 816 52 M J

Dibenzo[a,h]anthracene 22:26 324 1.3 M 22:26 95.0 54 J

Benzo[g,h,i]perylene 22:48 751 2.2 M 22:48 856 37 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 109 50-150 11:14 117

p-Terphenyl-d14 15:34 85 50-150 15:34 93

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 84 20-150 7:31 90

2-Me-Naphthalene-d10 8:41 91 20-150 8:40 83

Acenaphthylene-d8 10:09 88 20-150 10:08 91

Phenanthrene-d10 12:48 91 30-150 12:48 81

Anthracene-d10 12:53 76 30-150 12:53 99

Fluoranthene-d10 14:45 103 30-150 14:45 100

Benz[a]anthracene-d12 17:29 64 30-150 17:30 40

Chrysene-d12 17:33 48 30-150 17:33 56

Benzo[b]fluoranthene-d12 19:41 104 30-150 19:42 87

Benzo[k]fluoranthene-d12 19:44 93 30-150 19:42 57

Benzo[a]pyrene-d12 20:18 78 30-150 20:18 158 M 

Perylene-d12 20:27 81 30-150 20:27 46 M 

Indeno[1,2,3-cd]pyrene-d12 22:20 90 30-150 22:21 53 M 

Dibenzo[a,h]anthracene-d14 22:23 91 30-150 22:27 49 M 

Benzo[g,h,i]perylene-d12 22:44 91 30-150 22:45 60 M 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#2 16-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 10 17-Nov-2014

16-Nov-14 08:44 16-Nov-14 06:27

Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 17 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-9 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B15 4-141115B14

Run Date

Final Volume 1000 uL 1000 uL

Dilution Factor 1 50

Analysis Units ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng

Naphthalene 7:35 42000 51 E 7:33 44100 190 M

2-Me-Naphthalene 8:43 18300 2.9 8:43 16000 19

1-Me-Naphthalene 8:53 13200 3.0 8:52 13700 19

Acenaphthylene 10:10 15000 3.8 M 10:09 12700 10 M

Acenaphthene 10:27 2330 1.4 M 10:27 2570 31 M J

Fluorene 11:18 3500 8.0 M 11:18 4220 32 M J

Phenanthrene 12:50 36200 4.3 M E 12:50 74000 25 M

Anthracene 12:55 5970 4.6 M 12:56 13200 31 M

Fluoranthene 14:47 43800 12 M E 14:47 64500 58 M

Pyrene 15:10 37700 11 M E 15:09 46900 54 M

Benz[a]anthracene 17:33 3510 1.3 M 17:33 2180 20 M J

Chrysene/Triphenylene 17:36 10600 1.5 M 17:36 9520 18 M

Benzo[b]fluoranthene 19:44 5080 1.2 M E 19:45 5060 60 M

Benzo[k]fluoranthene 19:47 1310 1.3 M 19:47 1880 50 M J

Benzo[e]pyrene 20:15 2150 1.5 M 20:14 959 59 M J

Benzo[a]pyrene 20:21 510 1.5 M 20:22 189 62 M J

Perylene 20:31 60.4 1.1 M J 20:31 <220 220 M U

Indeno[1,2,3-cd]pyrene 22:22 651 0.74 M 22:23 597 44 M J

Dibenzo[a,h]anthracene 22:26 129 1.2 M 22:28 198 57 M J

Benzo[g,h,i]perylene 22:47 528 0.45 M 22:48 505 22 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 114 50-150 11:15 135

p-Terphenyl-d14 15:34 113 50-150 15:34 103

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 65 20-150 7:31 105

2-Me-Naphthalene-d10 8:40 70 20-150 8:40 110

Acenaphthylene-d8 10:09 72 20-150 10:08 104

Phenanthrene-d10 12:48 77 30-150 12:48 105

Anthracene-d10 12:54 69 30-150 12:53 109

Fluoranthene-d10 14:45 80 30-150 14:45 102

Benz[a]anthracene-d12 17:29 103 30-150 17:29 72

Chrysene-d12 17:33 74 30-150 17:33 81

Benzo[b]fluoranthene-d12 19:41 85 30-150 19:41 95 M 

Benzo[k]fluoranthene-d12 19:45 69 30-150 19:45 94 M 

Benzo[a]pyrene-d12 20:18 72 30-150 20:16 268 M 

Perylene-d12 20:27 74 30-150 20:27 115 M 

Indeno[1,2,3-cd]pyrene-d12 22:20 97 30-150 22:21 91 M 

Dibenzo[a,h]anthracene-d14 22:23 101 30-150 22:25 56

Benzo[g,h,i]perylene-d12 22:44 95 30-150 22:44 116 M 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

U Indicates that this compound was not detected above the MDL.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#3 16-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 10 17-Nov-2014

16-Nov-14 09:53 16-Nov-14 09:18

Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 18 of 84
Sample Name Sampling Date

ALS Sample ID L1535265-10 Extraction Date

Analysis Method Sample Size

Analysis Type Sample Moisture Content

Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B16 4-141115B11

Run Date

Final Volume 1000 uL 1000 uL

Dilution Factor 1 50

Analysis Units ng ng

Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL

Target Analytes Time ng ng Time. ng ng

Naphthalene 7:34 43100 43 E 7:33 43900 93 M

2-Me-Naphthalene 8:44 16400 3.9 M 8:42 15100 38 M

1-Me-Naphthalene 8:54 11700 4.0 M 8:52 13500 40 M

Acenaphthylene 10:10 19100 2.9 M 10:09 14900 28 M

Acenaphthene 10:27 2050 5.8 M 10:27 2350 30 M J

Fluorene 11:18 3080 2.0 M 11:17 3650 15 M J

Phenanthrene 12:50 34100 11 M E 12:50 43500 56 M

Anthracene 12:55 6300 11 M 12:55 10500 71 M

Fluoranthene 14:47 38400 14 M E 14:46 30400 78 M

Pyrene 15:10 25600 13 M E 15:09 23100 72 M

Benz[a]anthracene 17:32 3290 1.1 M 17:35 4350 86 M J

Chrysene/Triphenylene 17:36 5200 1.1 M 17:35 5000 99 M

Benzo[b]fluoranthene 19:44 3160 2.8 M 19:45 3470 160 M J

Benzo[k]fluoranthene 19:47 1250 3.2 M 19:47 1470 170 M J

Benzo[e]pyrene 20:15 1660 3.7 M 20:14 1140 42 M J

Benzo[a]pyrene 20:21 681 3.8 M 20:23 160 43 M J

Perylene 20:31 133 2.9 M 20:31 <40 40 M U

Indeno[1,2,3-cd]pyrene 22:22 980 1.7 M 22:24 707 81 M J

Dibenzo[a,h]anthracene 22:27 204 2.7 M 22:29 <140 140 M U

Benzo[g,h,i]perylene 22:47 807 1.0 M 22:48 868 48 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 104 50-150 11:14 113 

p-Terphenyl-d14 15:34 85 50-150 15:34 85 

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 69 20-150 7:31 95 

2-Me-Naphthalene-d10 8:40 71 20-150 8:40 87 

Acenaphthylene-d8 10:09 68 20-150 10:08 87 

Phenanthrene-d10 12:48 66 30-150 12:48 77 

Anthracene-d10 12:54 59 30-150 12:53 81 

Fluoranthene-d10 14:45 69 30-150 14:44 87 

Benz[a]anthracene-d12 17:29 44 30-150 17:30 36 

Chrysene-d12 17:33 35 30-150 17:30 22 

Benzo[b]fluoranthene-d12 19:41 67 30-150 19:41 56 

Benzo[k]fluoranthene-d12 19:45 54 30-150 19:45 43 

Benzo[a]pyrene-d12 20:18 56 30-150 20:21 111 

Perylene-d12 20:28 57 30-150 20:27 151 

Indeno[1,2,3-cd]pyrene-d12 22:20 58 30-150 22:22 37 M 

Dibenzo[a,h]anthracene-d14 22:23 56 30-150 22:27 25 M 

Benzo[g,h,i]perylene-d12 22:44 55 30-150 22:45 42 M 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

M Indicates that a peak has been manually integrated.

U Indicates that this compound was not detected above the MDL.

E Indicates that this compound was detected above the calibrated range.

J indicates that a target analyte was detected below the LQL.

ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#4 16-Oct-14

28-Oct-14 Approved:

CARB 429 Modified 1 train Ella Gdyczynski

n/a --e-signature--

Stack 10 17-Nov-2014

16-Nov-14 10:27 16-Nov-14 07:35

Flags Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 19 of 84
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including:

- Individual Quantitation Reports

SVOC DATA PACKAGE

SECTION 3: SAMPLE DATA

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 20 of 84
Quantification Report OPUS v3.6

 Sample ID L1535265-11

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115A15

 Acquired 15-Nov-2014 20:44

 Processed 16-Nov-2014 10:02

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 2867700 - n 7:33 103.472 0 1.26094 - y n 1433800 273630 2794 98 - - - 

 2-Me-Naphthalene 1 128580 - n 8:44 12.2772 0 0.246899 - Y y n EG141116MB 64289 8689.7 227 38.2 - - -  1-Me-Naphthalene 1 101950 - n 8:54 10.1601 0 0.25768 - Y y n EG141116MB 50977 7870.2 227 34.6 - - - 

 Acenaphthylene 1 28425 - n 10:10 1.54687 0 0.07154 - y n 14213 2496.1 117 21.4 - - - 

 Acenaphthene 1 12791 - n 10:27 1.41544 0 0.224041 - n n 6395.3 1396.3 180 7.8 - - - 

 Fluorene 1 37975 - n 11:18 6.26772 0 0.480116 - y n 18988 3210.5 209 15.3 - - - 

 Phenanthrene 1 230850 - n 12:51 13.4766 0 0.402253 - Y y n EG141116MB 115420 17901 496 36.1 - - - 

 Anthracene 1 59732 - n 12:56 3.04073 0 0.519225 - Y y n EG141116MB 29866 3261.5 496 6.6 - - - 

 Fluoranthene 1 23162 - n 14:47 1.91501 0 0.381187 - y n 11581 2428.6 309 7.9 - - - 

 Pyrene 1 38512 - n 15:09 2.96842 0 0.355362 - y n 19256 2879.5 309 9.3 - - - 

 Benz[a]anthracene 1 20920 - n 17:32 4.46445 0 0.218094 - y y n eg141116MB 10460 1142 70 16.4 - - - 

 Chrysene/Triphenylene 1 24597 - n 17:37 3.33305 0 0.215044 - y y n EG141116MB 12298 1344 70 19.3 - - - 

 Benzo[b]fluoranthene 1 14591 - n 19:44 4.89794 0 0.637456 - Y y n EG141116MB 7295.3 1066.2 129 8.3 - - - 

 Benzo[k]fluoranthene 1 11331 - n 19:47 2.87912 0 0.690809 - Y y n EG141116MB 5665.5 1115.2 129 8.6 - - - 

 Benzo[e]pyrene 1 6597.8 - n 20:14 1.73894 0 0.751464 - Y y n EG141116MB 3298.9 700.59 129 5.4 - - -  Benzo[a]pyrene 1 9438.7 - n 20:21 2.58745 0 0.781597 - Y y n EG141116MB 4719.4 793.09 129 6.1 - - - 

 Perylene 1 7273.9 - n 20:30 1.54813 0 0.599241 - Y y n EG141116MB 3637 714.52 129 5.5 - - - 

 Indeno[1,2,3-cd]pyrene 1 11586 - n 22:22 7.91667 0 1.42914 - Y y n EG141116MB 5793.2 636.19 80 8 - - - 

 Dibenzo[a,h]anthracene 1 11871 - n 22:26 7.65176 0 1.28625 - Y y n EG141116MB 5935.3 768.67 80 9.6 - - - 

 Benzo[g,h,i]perylene 1 14000 - n 22:46 6.20143 0 0.739959 - Y y n EG141116MB 7000 740.99 80 9.3 - - - 

 Fluorene-d10 1 3229600 - n 11:15 761.691 0 0 76.2 n n 1614800 296770 0 Div0 - - - 

 p-Terphenyl-d14 1 2292400 - n 15:34 479.67 0 0 48 n n 1146200 173290 0 Div0 - - - 

 Naphthalene-d8 1 21686000 - n 7:31 723.303 0 0.306478 72.3 n n 10843000 2167000 884 2451.3 - - - 

 2-Me-Naphthalene-d10 1 6876000 - n 8:40 627.724 0 0 62.8 n n 3438000 755180 0 Div0 - - - 

 Acenaphthylene-d8 1 12675000 - n 10:08 492.029 0 0 49.2 n n 6337400 1408600 0 Div0 - - - 

 Phenanthrene-d10 1 15662000 - n 12:48 377.866 0 0 37.8 n n 7831100 1409700 0 Div0 - - - 

 Anthracene-d10 1 17338000 - n 12:53 400.651 0 0 40.1 n n 8668800 1054200 0 Div0 - - - 

 Fluoranthene-d10 1 8105100 - n 14:45 447.89 0 0 44.8 n n 4052600 678040 0 Div0 - - - 

 Benz[a]anthracene-d12 1 3640300 - n 17:29 201.114 0 0 20.1 n n 1820100 309770 0 Div0 - - - 

 Chrysene-d12 1 6597300 - n 17:33 219.886 0 0 22 n n 3298600 361520 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 2556600 - n 19:41 357.392 0 0 35.7 n n 1278300 217150 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 3787700 - n 19:44 344.219 0 0 34.4 n n 1893900 224700 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 3009400 - n 20:17 362.987 0 0 36.3 n n 1504700 170240 0 Div0 - - - 

 Perylene-d12 1 2979600 - n 20:27 363.711 0 0 36.4 n n 1489800 170690 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 1469200 - n 22:20 265.296 0 0 26.5 n n 734600 70242 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 985350 - n 22:23 254.634 0 0 25.5 n n 492670 49380 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 1844600 - n 22:44 301.864 0 0 30.2 n n 922320 110430 0 Div0 - - - 

 Acenaphthene-d10 1 16958000 - n 10:24 151.316 0 - - n n 8479000 2039300 0 Div0 - - - 

 Pyrene-d10 1 20522000 - n 15:07 124.22 0 - - n n 10261000 1872900 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 10393000 - n 20:11 52.4379 0 - - n n 5196400 870910 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-4

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115A16

 Acquired 15-Nov-2014 21:18

 Processed 16-Nov-2014 10:02

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 91081000 - n 7:33 2257.46 0 15.6301 - y n 45541000 9741500 51858 187.8 - - - 

 2-Me-Naphthalene 1 87295000 - n 8:42 4857.22 0 7.23546 - n n 43647000 11047000 12424 889.2 - - -  1-Me-Naphthalene 1 67308000 - n 8:52 3908.66 0 7.55142 - n n 33654000 8414600 12424 677.3 - - - 

 Acenaphthylene 1 6341000 - n 10:09 157.487 0 1.36863 - y n 3170500 642880 5073 126.7 - - - 

 Acenaphthene 1 8917600 - n 10:26 450.382 0 3.35387 - y n 4458800 1084500 6114 177.4 - - - 

 Fluorene 1 10991000 - n 11:17 648.376 0 1.58614 - y n 5495600 1122700 2400 467.8 - - - 

 Phenanthrene 1 162100000 - n 12:50 3382.35 0 2.15475 - y n 81051000 18563000 9217 2014.1 - - - 

 Anthracene 1 6169200 - n 12:55 139.79 0 2.55191 - Y y n EG141116MB 3084600 469810 9217 51 - - - 

 Fluoranthene 1 3309000 - n 14:46 118.211 0 0.919694 - y n 1654500 325310 2027 160.5 - - - 

 Pyrene 1 2077300 - n 15:09 69.1832 0 0.857386 - y n 1038700 192670 2027 95 - - - 

 Benz[a]anthracene 1 199260 - n 17:32 7.32595 0 0.403395 - y n 99632 18149 787 23.1 - - - 

 Chrysene/Triphenylene 1 870910 - n 17:35 29.9084 0 0.431006 - y n 435450 49969 787 63.5 - - - 

 Benzo[b]fluoranthene 1 15899000 - n 19:45 613.865 0 1.32422 - Y y n EG141116MB 7949300 815030 2609 312.4 - - - 

 Benzo[k]fluoranthene 1 13942000 - n 19:47 523.585 0 1.60469 - Y y n EG141116MB 6970800 811960 2609 311.2 - - - 

 Benzo[e]pyrene 1 104000 - n 20:15 4.47311 0 1.73248 - Y y n EG141116MB /// 52000 10456 2609 4 - - -  Benzo[a]pyrene 0 * - n NotFnd * * 1.80195 - y n * * 2609 * - - - 

 Perylene 0 * - n NotFnd * * 1.31831 - y n * * 2609 * - - - 

 Indeno[1,2,3-cd]pyrene 1 67306 - n 22:22 4.63154 0 0.900991 - Y y n EG141116MB 33653 3614 580 6.2 - - - 

 Dibenzo[a,h]anthracene 1 27081 - n 22:26 1.66468 0 0.448027 - Y y n EG141116MB 13540 2350.9 383 6.1 - - - 

 Benzo[g,h,i]perylene 1 61254 - n 22:46 3.16959 0 0.545877 - Y y n EG111416MB 30627 4454.7 580 7.7 - - - 

 Fluorene-d10 1 13781 - n 11:14 1.16166 0 0 0.1 n n 6890.3 1617.1 0 Div0 - - - 

 p-Terphenyl-d14 1 8735.7 - n 15:34 0.789804 0 0 0.1 n n 4367.8 854.49 0 Div0 - - - 

 Naphthalene-d8 1 31571000 - n 7:31 825.462 0 0.256989 82.5 n n 15786000 3245200 940 3452.4 - - - 

 2-Me-Naphthalene-d10 1 11800000 - n 8:39 844.451 0 0 84.4 n n 5899900 1409200 0 Div0 - - - 

 Acenaphthylene-d8 1 27772000 - n 10:08 845.135 0 0 84.5 n n 13886000 3196000 0 Div0 - - - 

 Phenanthrene-d10 1 43820000 - n 12:47 828.77 0 0 82.9 n n 21910000 4888800 0 Div0 - - - 

 Anthracene-d10 1 38950000 - n 12:52 705.6 0 0 70.6 n n 19475000 3984600 0 Div0 - - - 

 Fluoranthene-d10 1 18758000 - n 14:44 901.027 0 0 90.1 n n 9379200 1846200 0 Div0 - - - 

 Benz[a]anthracene-d12 1 21131000 - n 17:29 1014.74 0 0 101.5 n n 10565000 1895200 0 Div0 - - - 

 Chrysene-d12 1 26032000 - n 17:32 754.168 0 0 75.4 n n 13016000 2041200 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 22228000 - n 19:40 1033.1 0 0 103.3 n n 11114000 2113500 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 25627000 - n 19:44 774.325 0 0 77.4 n n 12813000 1955800 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 18441000 - n 20:17 739.555 0 0 74 n n 9220600 1493000 0 Div0 - - - 

 Perylene-d12 1 18426000 - n 20:27 747.801 0 0 74.8 n n 9212800 1568700 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 14588000 - n 22:19 875.851 0 0 87.6 n n 7294100 808050 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 10333000 - n 22:22 887.782 0 0 88.8 n n 5166300 679460 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 15791000 - n 22:44 859.18 0 0 85.9 n n 7895500 1085600 0 Div0 - - - 

 Acenaphthene-d10 1 21632000 - n 10:24 193.025 0 - - n n 10816000 2586000 0 Div0 - - - 

 Pyrene-d10 1 23609000 - n 15:07 142.909 0 - - n n 11805000 2253100 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 31258000 - n 20:11 157.714 0 - - n n 15629000 2719700 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-3

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115A17

 Acquired 15-Nov-2014 21:52

 Processed 16-Nov-2014 10:03

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 300820000 - n 7:35 9270.62 0 38.6475 - y n 150410000 38799000 116367 333.4 - - - 

 2-Me-Naphthalene 1 249500000 - n 8:43 17945.5 0 2.4586 - n n 124750000 34168000 3476 9829.6 - - - 

 1-Me-Naphthalene 1 181580000 - n 8:53 13630.8 0 2.56596 - n n 90792000 24796000 3476 7133.3 - - - 

 Acenaphthylene 1 12651000 - n 10:10 394.754 0 1.41069 - y n 6325700 1231100 4352 282.8 - - - 

 Acenaphthene 1 18581000 - n 10:27 1178.96 0 6.49866 - y n 9290500 2274000 9860 230.6 - - - 

 Fluorene 1 23522000 - n 11:17 1617.54 0 2.86211 - y n 11761000 2368800 3690 641.9 - - - 

 Phenanthrene 1 500830000 - n 12:50 12182.1 0 8.30653 - y n 250410000 59578000 30278 1967.7 - - - 

 Anthracene 1 20463000 - n 12:55 555.592 0 10.3315 - y n 10231000 1523200 30278 50.3 - - - 

 Fluoranthene 1 16804000 - n 14:47 553.982 0 1.82356 - y n 8402000 1682600 4587 366.8 - - - 

 Pyrene 1 16973000 - n 15:09 521.644 0 1.70002 - y n 8486500 1647100 4587 359.1 - - - 

 Benz[a]anthracene 1 3553300 - n 17:32 96.8355 0 1.24924 - Y y n EG141116MB 1776700 346430 3615 95.8 - - - 

 Chrysene/Triphenylene 1 9072800 - n 17:36 224.907 0 1.34176 - Y y n EG141116MB 4536400 586540 3615 162.3 - - - 

 Benzo[b]fluoranthene 1 7515900 - n 19:43 187.099 0 0.6135 - Y y n EG141116MB 3758000 538640 1930 279.1 - - - 

 Benzo[k]fluoranthene 1 2062900 - n 19:46 51.7058 0 0.698783 - Y y n EG141116MB 1031500 160560 1930 83.2 - - - 

 Benzo[e]pyrene 1 3692600 - n 20:14 109.395 0 0.851396 - Y y n EG141116MB 1846300 345630 1930 179.1 - - -  Benzo[a]pyrene 1 1471300 - n 20:20 45.3365 0 0.885536 - Y y n EG141116MB 735660 119850 1930 62.1 - - - 

 Perylene 1 221730 - n 20:30 5.04567 0 0.609893 - Y y n EG141116MB 110860 21109 1930 10.9 - - - 

 Indeno[1,2,3-cd]pyrene 1 791090 - n 22:22 29.9744 0 2.06232 - Y y n EG141116MB 395550 58125 2642 22 - - - 

 Dibenzo[a,h]anthracene 1 372670 - n 22:26 12.4284 0 0.976966 - Y y n EG141116MB 186340 25564 1776 14.4 - - - 

 Benzo[g,h,i]perylene 1 1857300 - n 22:47 57.1327 0 1.35604 - Y y n EG141116MB 928660 136540 2642 51.7 - - - 

 Fluorene-d10 1 9732800 - n 11:14 956.427 0 0 95.6 n n 4866400 1108500 0 Div0 - - - 

 p-Terphenyl-d14 1 12722000 - n 15:34 1061.44 0 0 106.1 n n 6361000 1307700 0 Div0 - - - 

 Naphthalene-d8 1 25391000 - n 7:33 797.217 0 0.433667 79.7 n n 12696000 2945100 1372 2146.6 - - - 

 2-Me-Naphthalene-d10 1 9128300 - n 8:40 784.469 0 0.003461 78.4 n n 4564200 1160300 4 290077.5 - - - 

 Acenaphthylene-d8 1 22106000 - n 10:08 807.815 0 0 80.8 n n 11053000 2660100 0 Div0 - - - 

 Phenanthrene-d10 1 37590000 - n 12:48 853.717 0 0 85.4 n n 18795000 4166100 0 Div0 - - - 

 Anthracene-d10 1 32506000 - n 12:53 707.134 0 0 70.7 n n 16253000 3233200 0 Div0 - - - 

 Fluoranthene-d10 1 20327000 - n 14:45 872.159 0 0 87.2 n n 10164000 2107000 0 Div0 - - - 

 Benz[a]anthracene-d12 1 28507000 - n 17:29 1222.82 0 0 122.3 n n 14253000 2809900 0 Div0 - - - 

 Chrysene-d12 1 36063000 - n 17:32 933.265 0 0 93.3 n n 18032000 3010500 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 34476000 - n 19:40 981.599 0 0 98.2 n n 17238000 3375000 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 38398000 - n 19:44 710.736 0 0 71.1 n n 19199000 3322700 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 26773000 - n 20:17 657.73 0 0 65.8 n n 13387000 2247500 0 Div0 - - - 

 Perylene-d12 1 27868000 - n 20:27 692.838 0 0 69.3 n n 13934000 2508500 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 26494000 - n 22:19 974.412 0 0 97.4 n n 13247000 1607600 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 19045000 - n 22:22 1002.43 0 0 100.2 n n 9522700 1442900 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 26563000 - n 22:43 885.353 0 0 88.5 n n 13282000 1990100 0 Div0 - - - 

 Acenaphthene-d10 1 18014000 - n 10:24 160.742 0 - - n n 9007200 2236800 0 Div0 - - - 

 Pyrene-d10 1 26430000 - n 15:07 159.986 0 - - n n 13215000 2669400 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 51026000 - n 20:11 257.458 0 - - n n 25513000 4898700 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-1

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B17

 Acquired 16-Nov-2014 11:01

 Processed 16-Nov-2014 14:25

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 241030000 - n 7:33 470788 0 390.575 - n n 120510000 25232000 14760 1709.5 - - - 

 2-Me-Naphthalene 1 16395000 - n 8:43 74835.4 0 57.6982 - y n 8197700 1796500 1182 1519.2 - - -  1-Me-Naphthalene 1 11596000 - n 8:52 55241.4 0 60.2178 - y n 5798100 1261300 1182 1066.7 - - - 

 Acenaphthylene 1 86316000 - n 10:10 153342 0 19.2405 - y n 43158000 10339000 1012 10211.4 - - - 

 Acenaphthene 1 8850300 - n 10:27 31972.4 0 132.454 - y n 4425200 1035800 3428 302.2 - - - 

 Fluorene 1 17819000 - n 11:18 70162 0 114.542 - y n 8909500 1681300 2639 637.2 - - - 

 Phenanthrene 1 811940000 - n 12:50 1130820 0 92.5761 - y n 405970000 78843000 6030 13076 - - - 

 Anthracene 1 107840000 - n 12:55 128686 0 95.8821 - y n 53921000 8249800 6030 1368.2 - - - 

 Fluoranthene 1 836580000 - n 14:47 1998740 0 264.18 - y n 418290000 82154000 9808 8375.9 - - - 

 Pyrene 1 748680000 - n 15:10 1667560 0 246.282 - y n 374340000 77982000 9808 7950.5 - - - 

 Benz[a]anthracene 1 28038000 - n 17:33 153416 0 98.5634 - Y y n EG141116MB 14019000 2636500 1379 1911.6 - - - 

 Chrysene/Triphenylene 1 71340000 - n 17:36 313986 0 102.46 - Y y n EG141116MB 35670000 4427700 1379 3210.3 - - - 

 Benzo[b]fluoranthene 1 8584900 - n 19:44 79652.6 0 89.8164 - Y y n EG141116MB 4292500 659200 633 1041.4 - - - 

 Benzo[k]fluoranthene 1 4403500 - n 19:47 36198.7 0 92.2285 - Y y n EG141116MB 2201800 310400 633 490.4 - - - 

 Benzo[e]pyrene 1 3805500 - n 20:15 10835.5 0 26.4702 - y n 1902700 302080 633 477.2 - - -  Benzo[a]pyrene 1 1737800 - n 20:21 5146.52 0 27.5317 - y n 868900 89719 633 141.7 - - - 

 Perylene 1 506150 - n 20:31 2500.37 0 47.9521 - y n 253080 22383 633 35.4 - - - 

 Indeno[1,2,3-cd]pyrene 0 * - n NotFnd * * 33677.4 - Y y n EG141116MB * * 483 * - - - 

 Dibenzo[a,h]anthracene 1 21464 - n 22:27 884.553 0 216.13 - Y y n EG141116MB 10732 1951.3 433 4.5 - - - 

 Benzo[g,h,i]perylene 1 385480 - n 22:48 4620.15 0 118.534 - Y y n EG141116MB 192740 17578 483 36.4 - - - 

 Fluorene-d10 1 197180 - n 11:15 1109.47 0 0 110.9 n n 98592 19960 0 Div0 - - - 

 p-Terphenyl-d14 1 121140 - n 15:34 732.492 0 0 73.2 n n 60571 9224.7 0 Div0 - - - 

 Naphthalene-d8 1 400610 - n 7:32 20.0783 0 0 2 n n 200310 36963 0 Div0 - - - 

 2-Me-Naphthalene-d10 1 143840 - n 8:40 19.7326 0 0 2 n n 71921 16820 0 Div0 - - - 

 Acenaphthylene-d8 1 388260 - n 10:08 22.6485 0 0 2.3 n n 194130 45370 0 Div0 - - - 

 Phenanthrene-d10 1 656510 - n 12:48 23.801 0 0 2.4 n n 328260 74441 0 Div0 - - - 

 Anthracene-d10 1 739630 - n 12:53 25.6837 0 0 2.6 n n 369810 69378 0 Div0 - - - 

 Fluoranthene-d10 1 280490 - n 14:45 26.2702 0 0 2.6 n n 140240 31101 0 Div0 - - - 

 Benz[a]anthracene-d12 1 141980 - n 17:30 13.2946 0 0 1.3 n n 70989 13589 0 Div0 - - - 

 Chrysene-d12 1 203120 - n 17:33 11.4743 0 0 1.1 n n 101560 15042 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 92502 - n 19:41 24.2933 0 0 2.4 n n 46251 7560.5 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 117080 - n 19:44 19.9893 0 0 2 n n 58539 8256.5 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 278570 - n 20:18 63.1245 0 0 6.3 n n 139280 23709 0 Div0 - - - 

 Perylene-d12 1 128370 - n 20:28 29.4397 0 0 2.9 n n 64187 10464 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 251.2 - n 22:15 0.085219 0 0 0 n n 125.6 18 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 15412 - n 22:25 7.48273 0 0 0.7 y n 7706.2 1589.5 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 68175 - n 22:45 20.9598 0 0 2.1 n n 34087 4162.7 0 Div0 - - - 

 Acenaphthene-d10 1 11285000 - n 10:24 100.697 0 - - n n 5642600 1358800 0 Div0 - - - 

 Pyrene-d10 1 12108000 - n 15:08 73.2907 0 - - n n 6054000 1257200 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 5531800 - n 20:11 27.9114 0 - - n n 2765900 437240 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-1

 Comments SAMPLE X50 DILX10 R»

 Sample size 1

 Filename 4-141115B04

 Acquired 16-Nov-2014 03:35

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 28423000 - n 7:34 603688 0 1410.82 - n n 14212000 2433300 4752 512.1 - - - 

 2-Me-Naphthalene 1 2176500 - n 8:43 116646 0 172.516 - n n 1088200 218580 260 840.7 - - -  1-Me-Naphthalene 1 1694200 - n 8:52 94762.8 0 180.05 - n n 847080 166740 260 641.3 - - - 

 Acenaphthylene 1 11353000 - n 10:10 254957 0 363.186 - y n 5676400 1199900 1382 868.5 - - - 

 Acenaphthene 1 1177000 - n 10:27 53749.5 0 526.471 - y n 588480 130620 985 132.6 - - - 

 Fluorene 1 1919000 - n 11:19 102406 0 449.294 - y n 959510 147880 639 231.4 - - - 

 Phenanthrene 1 107200000 - n 12:50 2023480 0 126.904 - y n 53601000 10740000 510 21048.1 - - - 

 Anthracene 1 20836000 - n 12:55 343225 0 148.565 - y n 10418000 1008000 510 1975.4 - - - 

 Fluoranthene 1 155640000 - n 14:47 3621450 0 1570.92 - y n 77821000 16396000 5164 3175.2 - - - 

 Pyrene 1 120020000 - n 15:09 2603310 0 1464.5 - y n 60008000 12360000 5164 2393.7 - - - 

 Benz[a]anthracene 1 8074200 - n 17:32 267563 0 1188.1 - Y y n EG141117MB 4037100 718390 2598 276.6 - - - 

 Chrysene/Triphenylene 1 22014000 - n 17:36 472879 0 1102.27 - Y y n EG141116MB 11007000 1201600 2598 462.6 - - - 

 Benzo[b]fluoranthene 1 3128000 - n 19:44 140590 0 336.577 - Y y n EG141116MB 1564000 226080 577 391.8 - - - 

 Benzo[k]fluoranthene 1 1318600 - n 19:46 41097 0 379.966 - Y y n EG141116MB 659310 101850 577 176.5 - - - 

 Benzo[e]pyrene 1 1457700 - n 20:14 51923.6 0 393.081 - Y y n EG141116MB 728870 115680 577 200.5 - - -  Benzo[a]pyrene 1 609970 - n 20:21 22598 0 408.844 - Y y n EG141116MB 304990 34812 577 60.3 - - - 

 Perylene 1 149340 - n 20:30 4080.58 0 297.379 - Y y n EG141116MB 74668 8526.5 577 14.8 - - - 

 Indeno[1,2,3-cd]pyrene 1 116540 - n 22:22 8368.55 0 375.81 - Y y n EG141116MB 58270 5421.8 200 27.1 - - - 

 Dibenzo[a,h]anthracene 1 17485 - n 22:26 1186.42 0 245.802 - Y y n EG141116MB 8742.5 1343.8 149 9 - - - 

 Benzo[g,h,i]perylene 1 151760 - n 22:46 7328.21 0 193.692 - Y y n EG141116MB 75878 8356 200 41.8 - - - 

 Fluorene-d10 1 18475 - n 11:15 1408.8 0 0 0.3 n n 9237.3 1625.3 0 Div0 - - - 

 p-Terphenyl-d14 1 26783 - n 15:34 1577.17 0 0 0.3 n n 13392 2028.7 0 Div0 - - - 

 Naphthalene-d8 1 18458000 - n 7:32 393627 0 328.039 78.6 n n 9228800 1650600 1436 1149.4 - - - 

 2-Me-Naphthalene-d10 1 6137500 - n 8:40 358256 0 0 71.5 n n 3068700 619670 0 Div0 - - - 

 Acenaphthylene-d8 1 15387000 - n 10:08 381931 0 0 76.2 n n 7693600 1643200 0 Div0 - - - 

 Phenanthrene-d10 1 24269000 - n 12:48 374375 0 0 74.7 n n 12134000 2302300 0 Div0 - - - 

 Anthracene-d10 1 26843000 - n 12:53 396628 0 0 79.2 n n 13422000 1898300 0 Div0 - - - 

 Fluoranthene-d10 1 14429000 - n 14:45 413756 0 0 82.6 n n 7214600 1379500 0 Div0 - - - 

 Benz[a]anthracene-d12 1 11745000 - n 17:29 336710 0 0 67.2 n n 5872500 1063700 0 Div0 - - - 

 Chrysene-d12 1 20850000 - n 17:32 360605 0 0 72 n n 10425000 1319400 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 9566800 - n 19:41 357788 0 0 71.4 n n 4783400 921340 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 15471000 - n 19:44 376151 0 0 75.1 n n 7735500 915200 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 11156000 - n 20:17 360012 0 0 71.9 n n 5578200 729090 0 Div0 - - - 

 Perylene-d12 1 11627000 - n 20:27 379718 0 0 75.8 n n 5813700 770530 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 7003800 - n 22:20 338356 0 0 67.5 n n 3501900 334570 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 4689700 - n 22:23 324232 0 0 64.7 n n 2344800 240740 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 8477400 - n 22:44 371151 0 0 74.1 n n 4238700 528380 0 Div0 - - - 

 Acenaphthene-d10 1 13287000 - n 10:24 118.563 0 - - n n 6643700 1550600 0 Div0 - - - 

 Pyrene-d10 1 19814000 - n 15:07 119.933 0 - - n n 9906800 1892900 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 19462000 - n 20:11 98.1964 0 - - n n 9730900 1603100 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-1

 Comments DILUTIONX50000

 Sample size 1

 Filename 4-141115A19

 Acquired 15-Nov-2014 23:01

 Processed 16-Nov-2014 10:04

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 3475900 - n 7:34 685825 0 5841.28 - y n 1738000 283550 2067 137.2 - - - 

 2-Me-Naphthalene 1 263140 - n 8:43 140535 0 4138.66 - n n 131570 23333 624 37.4 - - -  1-Me-Naphthalene 1 226510 - n 8:52 126250 0 4319.39 - n n 113250 20230 624 32.4 - - - 

 Acenaphthylene 1 1184400 - n 10:09 237743 0 1844.32 - y n 592190 120300 782 153.8 - - - 

 Acenaphthene 1 108790 - n 10:27 44405.2 0 2510.32 - Y y n EG141116MB 54393 12437 524 23.8 - - - 

 Fluorene 1 179330 - n 11:18 104478 0 2379.29 - Y y n EG141116MB 89666 14155 280 50.6 - - - 

 Phenanthrene 1 9577800 - n 12:50 1973710 0 2627.63 - y y n EG1411116MB 4788900 805630 874 921.5 - - - 

 Anthracene 1 1976300 - n 12:55 384530 0 3328.45 - y y n EG141116MB 988150 111050 874 127 - - - 

 Fluoranthene 1 12873000 - n 14:46 3806320 0 3570.36 - y n 6436700 1082700 847 1278 - - - 

 Pyrene 1 10094000 - n 15:09 2782410 0 3328.47 - y n 5047200 887470 847 1047.6 - - - 

 Benz[a]anthracene 1 497480 - n 17:32 220194 0 3672.66 - Y y n EG141116MB 248740 51890 567 91.6 - - - 

 Chrysene/Triphenylene 1 2136500 - n 17:36 470070 0 3194.98 - Y y n EG141116MB 1068300 93213 567 164.5 - - - 

 Benzo[b]fluoranthene 1 277950 - n 19:44 116352 0 1074.63 - Y y n EG141116MB 138970 19839 155 128.3 - - - 

 Benzo[k]fluoranthene 1 169520 - n 19:46 51109.8 0 1133.33 - Y y n EG141116MB 84762 12119 155 78.4 - - - 

 Benzo[e]pyrene 1 176360 - n 20:14 53620.7 0 1156.41 - Y y n EG141116MB 88181 13887 155 89.8 - - -  Benzo[a]pyrene 1 73655 - n 20:21 23292.1 0 1202.78 - Y y n EG141116MB 36828 4506.5 155 29.1 - - - 

 Perylene 1 25611 - n 20:31 6631.79 0 714.034 - Y y n EG141116MB 12806 1312.8 155 8.5 - - - 

 Indeno[1,2,3-cd]pyrene 1 13579 - n 22:22 8764.85 0 3031.59 - Y y n EG141116MB 6789.3 1208.7 177 6.8 - - - 

 Dibenzo[a,h]anthracene 1 6030.9 - n 22:28 3786.18 0 2267.58 - Y y n EG141116MB 3015.4 473.11 148 3.2 - - - 

 Benzo[g,h,i]perylene 1 18915 - n 22:47 7052.23 0 1491.86 - Y y n EG141116MB 9457.4 975.66 177 5.5 - - - 

 Fluorene-d10 1 2668.7 - n 11:15 2221.74 0 0 0.4 n n 1334.3 372.25 0 Div0 - - - 

 p-Terphenyl-d14 1 794.79 - n 15:34 594.728 0 0 0.1 n n 397.39 124.73 0 Div0 - - - 

 Naphthalene-d8 1 1986900 - n 7:32 406089 0 647.197 81.1 n n 993450 173370 292 593.7 - - - 

 2-Me-Naphthalene-d10 1 615910 - n 8:40 344557 0 0 68.8 n n 307960 61993 0 Div0 - - - 

 Acenaphthylene-d8 1 1721500 - n 10:08 409521 0 0 81.7 n n 860770 183230 0 Div0 - - - 

 Phenanthrene-d10 1 2222900 - n 12:48 328643 0 0 65.6 n n 1111500 190510 0 Div0 - - - 

 Anthracene-d10 1 2272600 - n 12:53 321818 0 0 64.2 n n 1136300 145180 0 Div0 - - - 

 Fluoranthene-d10 1 1135500 - n 14:45 343039 0 0 68.5 n n 567750 99579 0 Div0 - - - 

 Benz[a]anthracene-d12 1 879340 - n 17:29 265590 0 0 53 n n 439670 75070 0 Div0 - - - 

 Chrysene-d12 1 2035700 - n 17:33 370929 0 0 74 n n 1017900 99303 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 1027200 - n 19:40 339989 0 0 67.9 n n 513580 77333 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 1599300 - n 19:44 344144 0 0 68.7 n n 799650 82229 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 1307000 - n 20:18 373280 0 0 74.5 n n 653500 66416 0 Div0 - - - 

 Perylene-d12 1 1227000 - n 20:27 354640 0 0 70.8 n n 613500 86000 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 779150 - n 22:20 333139 0 0 66.5 n n 389580 36668 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 506860 - n 22:24 310149 0 0 61.9 n n 253430 25954 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 1098000 - n 22:44 425445 0 0 84.9 n n 548990 60650 0 Div0 - - - 

 Acenaphthene-d10 1 1386400 - n 10:24 12.3712 0 - - n n 693220 159810 0 Div0 - - - 

 Pyrene-d10 1 1880600 - n 15:07 11.3837 0 - - n n 940320 167130 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 2199000 - n 20:11 11.0951 0 - - n n 1099500 166510 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-2

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B18

 Acquired 16-Nov-2014 11:36

 Processed 16-Nov-2014 14:25

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 185020000 - n 7:34 457687 0 243.728 - y n 92512000 19452000 7885 2467 - - - 

 2-Me-Naphthalene 1 14639000 - n 8:43 103276 0 36.1662 - n n 7319700 1497000 444 3371.6 - - -  1-Me-Naphthalene 1 10162000 - n 8:52 74821.3 0 37.7455 - n n 5081100 1089500 444 2453.8 - - - 

 Acenaphthylene 1 53441000 - n 10:10 188241 0 108.876 - y n 26720000 6124500 2903 2109.9 - - - 

 Acenaphthene 1 6061700 - n 10:27 43419.7 0 51.6032 - y n 3030900 702830 677 1038.8 - - - 

 Fluorene 1 13187000 - n 11:19 120985 0 142.027 - y n 6593300 1221200 1336 913.8 - - - 

 Phenanthrene 1 764610000 - n 12:50 2481340 0 219.66 - y n 382300000 78905000 5844 13502.5 - - - 

 Anthracene 1 65902000 - n 12:55 205346 0 252.314 - y n 32951000 3613800 5844 618.4 - - - 

 Fluoranthene 1 937260000 - n 14:47 5302530 0 446.758 - y n 468630000 82398000 7530 10942.2 - - - 

 Pyrene 1 894520000 - n 15:10 4717850 0 416.491 - y n 447260000 81243000 7530 10788.8 - - - 

 Benz[a]anthracene 1 88697000 - n 17:32 1117230 0 673.459 - y n 44348000 9484400 4431 2140.6 - - - 

 Chrysene/Triphenylene 1 285810000 - n 17:36 2396630 0 599.432 - y n 142900000 23191000 4431 5234 - - - 

 Benzo[b]fluoranthene 1 34977000 - n 19:44 776305 0 184.57 - Y y n EG141118MB 17488000 2652200 637 4160.8 - - - 

 Benzo[k]fluoranthene 1 13745000 - n 19:47 152389 0 122.488 - Y y n EG141118MB 6872300 1119700 637 1756.7 - - - 

 Benzo[e]pyrene 1 14514000 - n 20:15 88004.3 0 40.9908 - Y y n EG141116MB 7256800 1208800 637 1896.5 - - -  Benzo[a]pyrene 1 6143600 - n 20:21 38746.2 0 42.6345 - Y y n EG141116MB 3071800 352260 637 552.6 - - - 

 Perylene 1 1205900 - n 20:31 16170.7 0 95.0835 - Y y n EG141116MB 602930 64701 637 101.5 - - - 

 Indeno[1,2,3-cd]pyrene 1 974620 - n 22:23 46785.9 0 149.528 - Y y n EG141118MB 487310 41378 263 157.5 - - - 

 Dibenzo[a,h]anthracene 1 196070 - n 22:27 8480.61 0 206.42 - Y y n EG141118MB 98035 6885.4 263 26.2 - - - 

 Benzo[g,h,i]perylene 1 979160 - n 22:48 29087.8 0 141.27 - Y y n EG141118MB 489580 54509 263 207.5 - - - 

 Fluorene-d10 1 133350 - n 11:15 1748.35 0 0 174.8 n n 66676 13419 0 Div0 - - - 

 p-Terphenyl-d14 1 120990 - n 15:35 1732.35 0 0 173.2 n n 60496 8970.1 0 Div0 - - - 

 Naphthalene-d8 1 316330 - n 7:32 16.678 0 0 1.7 n n 158170 31644 0 Div0 - - - 

 2-Me-Naphthalene-d10 1 93067 - n 8:40 13.4305 0 0 1.3 n n 46534 10075 0 Div0 - - - 

 Acenaphthylene-d8 1 195820 - n 10:08 12.0161 0 0 1.2 n n 97908 22987 0 Div0 - - - 

 Phenanthrene-d10 1 281750 - n 12:48 10.7451 0 0 1.1 n n 140870 30406 0 Div0 - - - 

 Anthracene-d10 1 283250 - n 12:53 10.347 0 0 1 n n 141630 25552 0 Div0 - - - 

 Fluoranthene-d10 1 118450 - n 14:45 10.3771 0 0 1 n n 59225 14119 0 Div0 - - - 

 Benz[a]anthracene-d12 1 61675 - n 17:29 5.40194 0 0 0.5 n n 30838 6388.9 0 Div0 - - - 

 Chrysene-d12 1 106610 - n 17:33 5.63323 0 0 0.6 n n 53305 8260 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 38669 - n 19:41 9.33999 0 0 0.9 y n 19334 3704.9 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 86806 - n 19:44 13.6308 0 0 1.4 y n 43403 6260.4 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 130810 - n 20:18 27.262 0 0 2.7 y n 65404 15417 0 Div0 - - - 

 Perylene-d12 1 47290 - n 20:28 9.97422 0 0 1 y n 23645 5314.1 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 20912 - n 22:21 6.52473 0 0 0.7 Y y n EG141116MB 10456 2204.4 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 14684 - n 22:25 6.55689 0 0 0.7 Y y n EG141116MB 7342.2 1010.3 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 27506 - n 22:45 7.77741 0 0 0.8 Y y n EG141116MB 13753 1899.2 0 Div0 - - - 

 Acenaphthene-d10 1 10728000 - n 10:24 95.7236 0 - - n n 5363900 1280000 0 Div0 - - - 

 Pyrene-d10 1 12944000 - n 15:08 78.354 0 - - n n 6472200 1319700 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 6014700 - n 20:12 30.348 0 - - Y y n EG141116MB 3007400 509440 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-2

 Comments SAMPLE X50 DILX10 R»

 Sample size 1

 Filename 4-141115B05

 Acquired 16-Nov-2014 04:10

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 22938000 - n 7:34 437329 0 697.426 - n n 11469000 1982900 2532 783.1 - - - 

 2-Me-Naphthalene 1 1903000 - n 8:43 79889.8 0 183.788 - n n 951490 184810 340 543.5 - - -  1-Me-Naphthalene 1 1495500 - n 8:53 65525.1 0 191.814 - n n 747750 137920 340 405.6 - - - 

 Acenaphthylene 1 7529800 - n 10:10 155858 0 498.881 - y n 3764900 804380 2016 399 - - - 

 Acenaphthene 1 781960 - n 10:27 32913.8 0 118.766 - n n 390980 87244 236 369.7 - - - 

 Fluorene 1 1264400 - n 11:19 57266.9 0 120.881 - y n 632210 111050 200 555.2 - - - 

 Phenanthrene 1 99178000 - n 12:50 1588830 0 789.782 - y n 49589000 9856900 3694 2668.1 - - - 

 Anthracene 1 13826000 - n 12:55 202806 0 970.044 - y n 6913200 665530 3694 180.2 - - - 

 Fluoranthene 1 239760000 - n 14:47 4793270 0 1857.36 - y n 119880000 26021000 7140 3644.5 - - - 

 Pyrene 1 190720000 - n 15:10 3554430 0 1731.52 - y n 95359000 20301000 7140 2843.4 - - - 

 Benz[a]anthracene 1 20157000 - n 17:32 570378 0 366.007 - y n 10079000 1840500 984 1870.7 - - - 

 Chrysene/Triphenylene 1 64270000 - n 17:36 1248830 0 350.209 - y n 32135000 4060800 984 4127.3 - - - 

 Benzo[b]fluoranthene 1 10441000 - n 19:44 419362 0 440.699 - Y y n EG141116MB 5220700 792400 862 919.4 - - - 

 Benzo[k]fluoranthene 1 4003300 - n 19:47 111590 0 477.451 - Y y n EG141116MB 2001600 328790 862 381.5 - - - 

 Benzo[e]pyrene 1 4438200 - n 20:14 149241 0 541.904 - Y y n EG141116MB 2219100 383530 862 445 - - -  Benzo[a]pyrene 1 1723100 - n 20:20 60264.6 0 563.634 - Y y n EG141116MB 861540 110950 862 128.7 - - - 

 Perylene 1 333660 - n 20:30 8802.68 0 438.402 - Y y n EG141116MB 166830 19617 862 22.8 - - - 

 Indeno[1,2,3-cd]pyrene 1 368790 - n 22:22 22914 0 617.548 - y n 184400 18392 387 47.5 - - - 

 Dibenzo[a,h]anthracene 1 72453 - n 22:27 4122.35 0 203.742 - y n 36227 2969.3 152 19.5 - - - 

 Benzo[g,h,i]perylene 1 424400 - n 22:46 17731.1 0 319.714 - y n 212200 25053 387 64.7 - - - 

 Fluorene-d10 1 22379 - n 11:15 1448.35 0 0 0.3 n n 11189 2512.9 0 Div0 - - - 

 p-Terphenyl-d14 1 12896 - n 15:35 652.477 0 0 0.1 n n 6448.1 1076.2 0 Div0 - - - 

 Naphthalene-d8 1 20562000 - n 7:32 477464 0 454.496 95.3 n n 10281000 1779100 1756 1013.1 - - - 

 2-Me-Naphthalene-d10 1 7835200 - n 8:40 497995 0 0 99.4 n n 3917600 760640 0 Div0 - - - 

 Acenaphthylene-d8 1 16695000 - n 10:08 451207 0 0 90.1 n n 8347400 1745500 0 Div0 - - - 

 Phenanthrene-d10 1 28595000 - n 12:48 480299 0 0 95.9 n n 14297000 2678400 0 Div0 - - - 

 Anthracene-d10 1 30146000 - n 12:53 485001 0 0 96.8 n n 15073000 2105000 0 Div0 - - - 

 Fluoranthene-d10 1 16794000 - n 14:45 485265 0 0 96.9 n n 8396900 1613200 0 Div0 - - - 

 Benz[a]anthracene-d12 1 13755000 - n 17:29 397356 0 0 79.3 n n 6877400 1307800 0 Div0 - - - 

 Chrysene-d12 1 23050000 - n 17:32 401713 0 0 80.2 n n 11525000 1572900 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 10706000 - n 19:40 479788 0 0 95.8 n n 5352900 1051100 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 17298000 - n 19:44 503972 0 0 100.6 n n 8648900 1088000 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 11817000 - n 20:17 456968 0 0 91.2 n n 5908700 790020 0 Div0 - - - 

 Perylene-d12 1 12043000 - n 20:27 471275 0 0 94.1 n n 6021400 780770 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 8094600 - n 22:19 468599 0 0 93.5 n n 4047300 393910 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 5592700 - n 22:23 463348 0 0 92.5 n n 2796400 297590 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 9798400 - n 22:44 514053 0 0 102.6 n n 4899200 619310 0 Div0 - - - 

 Acenaphthene-d10 1 12203000 - n 10:24 108.888 0 - - n n 6101600 1368500 0 Div0 - - - 

 Pyrene-d10 1 19662000 - n 15:08 119.018 0 - - n n 9831200 1888100 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 16241000 - n 20:11 81.9461 0 - - n n 8120500 1387000 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-2

 Comments DILUTIONX50000

 Sample size 1

 Filename 4-141115A20

 Acquired 15-Nov-2014 23:35

 Processed 16-Nov-2014 10:04

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 3248100 - n 7:35 570203 0 4411.04 - y n 1624000 253880 1704 149 - - - 

 2-Me-Naphthalene 1 237990 - n 8:44 107388 0 2754.58 - n n 119000 20337 424 48 - - -  1-Me-Naphthalene 1 178030 - n 8:53 83841.4 0 2874.87 - n n 89016 15719 424 37.1 - - - 

 Acenaphthylene 1 781680 - n 10:09 147131 0 826.502 - y n 390840 83161 376 221 - - - 

 Acenaphthene 1 85507 - n 10:28 32728.2 0 1089.74 - y n 42753 9078.7 244 37.2 - - - 

 Fluorene 1 135730 - n 11:18 71339.9 0 1935.67 - y n 67865 10074 271 37.1 - - - 

 Phenanthrene 1 8585800 - n 12:51 1596200 0 2322.67 - Y y n EG141116MB 4292900 716350 920 778.5 - - - 

 Anthracene 1 1649400 - n 12:55 261143 0 3288.96 - Y y n EG141116MB 824710 78717 920 85.5 - - - 

 Fluoranthene 1 16958000 - n 14:47 4052550 0 567.806 - y n 8479100 1431500 164 8729.8 - - - 

 Pyrene 1 14408000 - n 15:09 3209770 0 529.338 - y n 7203800 1249300 164 7618.5 - - - 

 Benz[a]anthracene 1 1320600 - n 17:32 465603 0 2455.38 - y n 660310 134510 487 276.1 - - - 

 Chrysene/Triphenylene 1 1320600 - n 17:32 535792 0 2825.53 - y n 660310 134510 487 276.1 - - - 

 Benzo[b]fluoranthene 1 924260 - n 19:44 400015 0 3669.25 - Y y n EG141116MB 462130 65523 597 109.7 - - - 

 Benzo[k]fluoranthene 1 428190 - n 19:47 125947 0 4267.55 - Y y n EG141116MB 214100 32531 597 54.4 - - - 

 Benzo[e]pyrene 1 447730 - n 20:15 142320 0 4025.39 - Y y n EG141116MB 223860 36645 597 61.3 - - -  Benzo[a]pyrene 1 215880 - n 20:21 71373.6 0 4186.8 - Y y n EG141116MB 107940 12024 597 20.1 - - - 

 Perylene 1 22072 - n 20:30 5546.05 0 3067.95 - Y y n EG141116MB 11036 2320.2 597 3.9 - - - 

 Indeno[1,2,3-cd]pyrene 1 44835 - n 22:22 26576.8 0 3634.28 - Y y n EG141116MB 22417 1881.3 202 9.3 - - - 

 Dibenzo[a,h]anthracene 1 9146.6 - n 22:27 5290.9 0 2215.81 - Y y n EG141116MB 4573.3 668.67 135 4.9 - - - 

 Benzo[g,h,i]perylene 1 52774 - n 22:46 18023.3 0 1574.12 - Y y n EG141116MB 26387 2791.3 202 13.8 - - - 

 Fluorene-d10 1 804.58 - n 11:16 604.303 0 0 0.1 n n 402.29 69.753 0 Div0 - - - 

 p-Terphenyl-d14 1 3073.8 - n 15:36 1859.03 0 0 0.4 n n 1536.9 294.25 0 Div0 - - - 

 Naphthalene-d8 1 2233100 - n 7:32 496694 0 626.489 99.1 n n 1116600 189330 260 728.2 - - - 

 2-Me-Naphthalene-d10 1 728970 - n 8:40 443794 0 0 88.6 n n 364490 63289 0 Div0 - - - 

 Acenaphthylene-d8 1 1835900 - n 10:08 475274 0 0 94.9 n n 917960 196680 0 Div0 - - - 

 Phenanthrene-d10 1 2464000 - n 12:48 396430 0 0 79.1 n n 1232000 226860 0 Div0 - - - 

 Anthracene-d10 1 2792900 - n 12:53 430393 0 0 85.9 n n 1396400 154650 0 Div0 - - - 

 Fluoranthene-d10 1 1404900 - n 14:45 520974 0 0 104 n n 702460 121200 0 Div0 - - - 

 Benz[a]anthracene-d12 1 1104000 - n 17:30 409274 0 0 81.7 n n 551980 96535 0 Div0 - - - 

 Chrysene-d12 1 1104000 - n 17:30 246908 0 0 49.3 n n 551980 96535 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 993500 - n 19:41 402529 0 0 80.3 n n 496750 87520 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 1639300 - n 19:44 431788 0 0 86.2 n n 819640 84384 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 1250100 - n 20:18 437034 0 0 87.2 n n 625060 73728 0 Div0 - - - 

 Perylene-d12 1 1264400 - n 20:27 447342 0 0 89.3 n n 632210 77344 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 848440 - n 22:20 444050 0 0 88.6 n n 424220 34910 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 550100 - n 22:23 412026 0 0 82.2 n n 275050 24288 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 1198700 - n 22:44 568537 0 0 113.5 n n 599340 65604 0 Div0 - - - 

 Acenaphthene-d10 1 1274000 - n 10:24 11.368 0 - - n n 637010 147000 0 Div0 - - - 

 Pyrene-d10 1 1532100 - n 15:07 9.27414 0 - - n n 766070 138270 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 1796400 - n 20:11 9.06413 0 - - n n 898220 133250 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-5

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B19

 Acquired 16-Nov-2014 12:10

 Processed 16-Nov-2014 14:25

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 157350000 - n 7:34 325520 0 96.5931 - n n 78676000 16228000 3972 4085.6 - - - 

 2-Me-Naphthalene 1 13422000 - n 8:44 53705 0 18.8628 - n n 6711200 1406300 416 3380.5 - - -  1-Me-Naphthalene 1 9818100 - n 8:53 40999.2 0 19.6865 - n n 4909100 1081300 416 2599.2 - - - 

 Acenaphthylene 1 37580000 - n 10:11 74995.5 0 59.476 - n n 18790000 4121500 2500 1648.6 - - - 

 Acenaphthene 1 4780200 - n 10:27 19398.8 0 19.239 - y n 2390100 554310 398 1393.8 - - - 

 Fluorene 1 10296000 - n 11:18 41516.6 0 64.6936 - y n 5148200 904310 1373 658.7 - - - 

 Phenanthrene 1 765350000 - n 12:50 1091570 0 97.1714 - y n 382680000 78067000 5830 13391.4 - - - 

 Anthracene 1 63706000 - n 12:55 95491.1 0 111.593 - y n 31853000 3225900 5830 553.4 - - - 

 Fluoranthene 1 942080000 - n 14:47 2299730 0 143.859 - y n 471040000 83928000 4940 16988.1 - - - 

 Pyrene 1 850490000 - n 15:10 1935490 0 134.113 - y n 425240000 82326000 4940 16663.9 - - - 

 Benz[a]anthracene 1 151730000 - n 17:32 583714 0 51.431 - y y n EG141117MB 75863000 15297000 1066 14354.9 - - - 

 Chrysene/Triphenylene 1 422960000 - n 17:37 1287730 0 47.0413 - y y n EG141117MB 211480000 34921000 1066 32771.6 - - - 

 Benzo[b]fluoranthene 1 66477000 - n 19:44 480908 0 89.1941 - y n 33239000 5732400 1020 5619.6 - - - 

 Benzo[k]fluoranthene 1 29297000 - n 19:47 163660 0 86.1508 - y n 14649000 2143200 1020 2101.1 - - - 

 Benzo[e]pyrene 1 28034000 - n 20:15 72933.2 0 35.0823 - y n 14017000 2401300 1020 2354.1 - - -  Benzo[a]pyrene 1 14220000 - n 20:21 38477.8 0 36.4891 - y n 7110000 879350 1020 862.1 - - - 

 Perylene 1 3062400 - n 20:31 16779.1 0 82.045 - n n 1531200 150390 1020 147.4 - - - 

 Indeno[1,2,3-cd]pyrene 1 2065800 - n 22:23 27208.1 0 310.615 - y n 1032900 96566 1350 71.6 - - - 

 Dibenzo[a,h]anthracene 1 372740 - n 22:27 5509.92 0 200.601 - Y y n EG141116MB 186370 17718 621 28.5 - - - 

 Benzo[g,h,i]perylene 1 2283300 - n 22:48 16017.5 0 203.889 - y n 1141600 115140 1350 85.3 - - - 

 Fluorene-d10 1 180720 - n 11:15 1041.29 0 0 104.1 n n 90360 17102 0 Div0 - - - 

 p-Terphenyl-d14 1 140660 - n 15:35 869.023 0 0 86.9 n n 70332 12876 0 Div0 - - - 

 Naphthalene-d8 1 378240 - n 7:32 19.4844 0 0 1.9 n n 189120 40221 0 Div0 - - - 

 2-Me-Naphthalene-d10 1 164090 - n 8:40 23.1364 0 0 2.3 n n 82046 18100 0 Div0 - - - 

 Acenaphthylene-d8 1 345630 - n 10:09 20.7223 0 0 2.1 n n 172810 36241 0 Div0 - - - 

 Phenanthrene-d10 1 641090 - n 12:48 23.8882 0 0 2.4 n n 320550 68568 0 Div0 - - - 

 Anthracene-d10 1 588820 - n 12:53 21.0152 0 0 2.1 n n 294410 57634 0 Div0 - - - 

 Fluoranthene-d10 1 274520 - n 14:45 21.8575 0 0 2.2 n n 137260 28767 0 Div0 - - - 

 Benz[a]anthracene-d12 1 201930 - n 17:29 16.0745 0 0 1.6 n n 100970 20120 0 Div0 - - - 

 Chrysene-d12 1 293630 - n 17:33 14.101 0 0 1.4 n n 146820 25314 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 118640 - n 19:41 21.0402 0 0 2.1 y n 59319 12269 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 172290 - n 19:44 19.8637 0 0 2 y n 86143 14244 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 304880 - n 20:17 46.6543 0 0 4.7 y n 152440 28828 0 Div0 - - - 

 Perylene-d12 1 115750 - n 20:23 17.9246 0 0 1.8 Y y n EG141116MB 57873 9855.7 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 76220 - n 22:21 17.4612 0 0 1.7 n n 38110 5451.9 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 42967 - n 22:25 14.0869 0 0 1.4 n n 21484 2458.3 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 116480 - n 22:45 24.182 0 0 2.4 n n 58238 6760.6 0 Div0 - - - 

 Acenaphthene-d10 1 10980000 - n 10:24 97.9729 0 - - n n 5489900 1250100 0 Div0 - - - 

 Pyrene-d10 1 14243000 - n 15:08 86.2129 0 - - n n 7121400 1445500 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 8191800 - n 20:12 41.3325 0 - - y n 4095900 728560 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-5

 Comments SAMPLE X50 DILX10 R»

 Sample size 1

 Filename 4-141115B06

 Acquired 16-Nov-2014 04:44

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 N

 Naphthalene 1 24065000 - n 7:33 444889 0 855.474 - n n 12033000 2080000 3220 646 - - 

 2-Me-Naphthalene 1 2079600 - n 8:43 88076.4 0 442.352 - n n 1039800 202950 812 249.9 - -  1-Me-Naphthalene 1 1480100 - n 8:52 65421.2 0 461.669 - n n 740030 140910 812 173.5 - - 

 Acenaphthylene 1 6244000 - n 10:09 125384 0 271.884 - y n 3122000 652660 1151 567 - - 

 Acenaphthene 1 650350 - n 10:26 26556.8 0 340.716 - y n 325180 69400 709 97.8 - - 

 Fluorene 1 1241300 - n 11:18 58077.1 0 309.113 - Y y n EG141116MB 620670 84584 500 169.1 - - 

 Phenanthrene 1 95814000 - n 12:49 1585600 0 125.673 - y n 47907000 9371400 575 16301.2 - - 

 Anthracene 1 14142000 - n 12:54 208188 0 157.12 - y n 7071000 646940 575 1125.3 - - 

 Fluoranthene 1 197790000 - n 14:46 4096920 0 623.269 - y n 98895000 21082000 2240 9412.4 - - 

 Pyrene 1 154840000 - n 15:09 2989900 0 581.044 - y n 77418000 16094000 2240 7185.5 - - 

 Benz[a]anthracene 1 24629000 - n 17:31 706892 0 204.07 - y n 12315000 2327300 555 4194.8 - - 

 Chrysene/Triphenylene 1 76670000 - n 17:35 1479100 0 190.833 - y n 38335000 4930500 555 8886.7 - - 

 Benzo[b]fluoranthene 1 14650000 - n 19:44 614180 0 320.484 - Y y n EG141116MB 7325100 1183700 606 1954.3 - - 

 Benzo[k]fluoranthene 1 7399300 - n 19:45 207476 0 324.692 - Y y n EG141116MB 3699700 568320 606 938.3 - - 

 Benzo[e]pyrene 1 7260400 - n 20:14 232672 0 377.776 - y n 3630200 616410 606 1017.7 - -  Benzo[a]pyrene 1 3636400 - n 20:20 121208 0 392.924 - y n 1818200 215320 606 355.5 - - 

 Perylene 1 788550 - n 20:30 20629.4 0 292.284 - y n 394280 40764 606 67.3 - - 

 Indeno[1,2,3-cd]pyrene 1 563750 - n 22:21 40284.3 0 486.976 - y n 281880 28131 272 103.6 - - 

 Dibenzo[a,h]anthracene 1 93363 - n 22:26 5893.33 0 258.261 - Y y n EG141116MB 46681 5336.4 163 32.7 - - 

 Benzo[g,h,i]perylene 1 601480 - n 22:46 27627.7 0 254.728 - y n 300740 32792 272 120.7 - - 

 Fluorene-d10 1 19625 - n 11:14 1312.05 0 0 0.3 n n 9812.5 2022.3 0 Div0 - - 

 p-Terphenyl-d14 1 33644 - n 15:34 1763.7 0 0 0.4 n n 16822 2044.2 0 Div0 - - 

 Naphthalene-d8 1 21206000 - n 7:31 435796 0 81.1482 87 n n 10603000 1844500 364 5067.3 - - 

 2-Me-Naphthalene-d10 1 7766600 - n 8:40 436869 0 0 87.2 n n 3883300 754760 0 Div0 - - 

 Acenaphthylene-d8 1 17209000 - n 10:08 411614 0 0 82.2 n n 8604400 1828700 0 Div0 - - 

 Phenanthrene-d10 1 27681000 - n 12:47 411492 0 0 82.1 n n 13841000 2619400 0 Div0 - - 

 Anthracene-d10 1 30037000 - n 12:53 427682 0 0 85.4 n n 15018000 2022400 0 Div0 - - 

 Fluoranthene-d10 1 16209000 - n 14:44 430946 0 0 86 n n 8104300 1508200 0 Div0 - - 

 Benz[a]anthracene-d12 1 13561000 - n 17:28 360462 0 0 71.9 n n 6780400 1322700 0 Div0 - - 

 Chrysene-d12 1 23216000 - n 17:32 372301 0 0 74.3 n n 11608000 1627700 0 Div0 - - 

 Benzo[b]fluoranthene-d12 1 10256000 - n 19:40 401822 0 0 80.2 n n 5128200 1015800 0 Div0 - - 

 Benzo[k]fluoranthene-d12 1 17196000 - n 19:44 437977 0 0 87.4 n n 8598100 1124400 0 Div0 - - 

 Benzo[a]pyrene-d12 1 12400000 - n 20:17 419169 0 0 83.7 n n 6200000 796420 0 Div0 - - 

 Perylene-d12 1 12145000 - n 20:27 415470 0 0 82.9 n n 6072300 823010 0 Div0 - - 

 Indeno[1,2,3-cd]pyrene-d12 1 7038200 - n 22:19 356186 0 0 71.1 n n 3519100 350650 0 Div0 - - 

 Dibenzo[a,h]anthracene-d14 1 5041100 - n 22:22 365102 0 0 72.9 n n 2520600 251450 0 Div0 - - 

 Benzo[g,h,i]perylene-d12 1 8912300 - n 22:43 408745 0 0 81.6 n n 4456200 545650 0 Div0 - - 

 Acenaphthene-d10 1 13789000 - n 10:23 123.036 0 - - n n 6894300 1588900 0 Div0 - - 

 Pyrene-d10 1 21369000 - n 15:07 129.348 0 - - n n 10685000 2081100 0 Div0 - - 

 Benzo[e]pyrene-d12 1 18578000 - n 20:11 93.7392 0 - - n n 9289200 1597400 0 Div0 - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-5

 Comments DILUTIONX50000

 Sample size 1

 Filename 4-141115A21

 Acquired 16-Nov-2014 00:09

 Processed 16-Nov-2014 10:04

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 N

 Naphthalene 1 2878300 - n 7:34 529681 0 10639.5 - n n 1439100 228950 3996 57.3 - - 

 2-Me-Naphthalene 1 207310 - n 8:44 105631 0 2933.33 - n n 103660 17192 428 40.2 - -  1-Me-Naphthalene 1 176470 - n 8:53 93841.9 0 3061.42 - n n 88234 15289 428 35.7 - - 

 Acenaphthylene 1 568360 - n 10:10 119720 0 1925.67 - y n 284180 58541 766 76.5 - - 

 Acenaphthene 1 60419 - n 10:27 25879.6 0 2034.65 - y n 30209 6841.4 398 17.2 - - 

 Fluorene 1 109020 - n 11:19 60328.6 0 2189.75 - Y y n EG141116MB 54511 9328.1 276 33.8 - - 

 Phenanthrene 1 8012400 - n 12:51 1568270 0 7575.64 - y n 4006200 679830 2697 252.1 - - 

 Anthracene 1 1835200 - n 12:55 357579 0 11741.4 - y n 917580 93845 2697 34.8 - - 

 Fluoranthene 1 13772000 - n 14:47 3338490 0 7538.56 - y n 6886000 1178300 2121 555.6 - - 

 Pyrene 1 11525000 - n 15:10 2604430 0 7027.83 - y n 5762300 1015800 2121 479 - - 

 Benz[a]anthracene 1 1684600 - n 17:33 639765 0 1954.37 - y n 842300 162050 350 463.5 - - 

 Chrysene/Triphenylene 1 7409400 - n 17:36 1643570 0 1848.52 - y n 3704700 337490 350 965.2 - - 

 Benzo[b]fluoranthene 1 1430000 - n 19:44 634284 0 4401.84 - Y y n EG141116MB 714980 96037 699 137.4 - - 

 Benzo[k]fluoranthene 1 702150 - n 19:47 206218 0 5013.24 - Y y n EG141116MB 351070 49749 699 71.2 - - 

 Benzo[e]pyrene 1 767260 - n 20:15 244718 0 5598.64 - Y y n EG141116MB 383630 57018 699 81.6 - -  Benzo[a]pyrene 1 379670 - n 20:21 125953 0 5823.15 - Y y n EG141116MB 189840 21010 699 30.1 - - 

 Perylene 1 96156 - n 20:31 23949.3 0 3893.58 - Y y n EG141116MB 48078 5537.2 699 7.9 - - 

 Indeno[1,2,3-cd]pyrene 1 47115 - n 22:23 30267.1 0 4474.77 - Y y n EG141116MB 23557 2694.5 231 11.7 - - 

 Dibenzo[a,h]anthracene 1 11406 - n 22:28 7216.87 0 3423.5 - Y y n EG141116MB 5702.8 864.87 180 4.8 - - 

 Benzo[g,h,i]perylene 1 60500 - n 22:47 25454.9 0 1997.53 - Y y n EG141116MB 30250 3680.2 231 15.9 - - 

 Fluorene-d10 1 1795 - n 11:15 1419.4 0 0 0.3 n n 897.51 224.79 0 Div0 - - 

 p-Terphenyl-d14 1 1087 - n 15:37 666.886 0 0 0.1 n n 543.52 152 0 Div0 - - 

 Naphthalene-d8 1 2130300 - n 7:32 478147 0 359.054 95.4 n n 1065100 184050 140 1314.6 - - 

 2-Me-Naphthalene-d10 1 645570 - n 8:40 396609 0 0 79.2 n n 322780 59993 0 Div0 - - 

 Acenaphthylene-d8 1 1640600 - n 10:09 428579 0 0 85.5 n n 820280 171760 0 Div0 - - 

 Phenanthrene-d10 1 2340400 - n 12:48 379986 0 0 75.8 n n 1170200 203870 0 Div0 - - 

 Anthracene-d10 1 2269300 - n 12:54 352913 0 0 70.4 n n 1134700 126970 0 Div0 - - 

 Fluoranthene-d10 1 1385000 - n 14:45 472676 0 0 94.3 n n 692500 118060 0 Div0 - - 

 Benz[a]anthracene-d12 1 1024900 - n 17:30 349686 0 0 69.8 n n 512430 87041 0 Div0 - - 

 Chrysene-d12 1 2019100 - n 17:33 415622 0 0 83 n n 1009600 105900 0 Div0 - - 

 Benzo[b]fluoranthene-d12 1 969380 - n 19:41 369942 0 0 73.8 n n 484690 85332 0 Div0 - - 

 Benzo[k]fluoranthene-d12 1 1641800 - n 19:45 407318 0 0 81.3 n n 820880 84020 0 Div0 - - 

 Benzo[a]pyrene-d12 1 1245900 - n 20:18 410256 0 0 81.9 n n 622950 62004 0 Div0 - - 

 Perylene-d12 1 1275600 - n 20:28 425092 0 0 84.8 n n 637820 71283 0 Div0 - - 

 Indeno[1,2,3-cd]pyrene-d12 1 782880 - n 22:20 385937 0 0 77 n n 391440 32441 0 Div0 - - 

 Dibenzo[a,h]anthracene-d14 1 502900 - n 22:24 354791 0 0 70.8 n n 251450 20913 0 Div0 - - 

 Benzo[g,h,i]perylene-d12 1 972970 - n 22:44 434676 0 0 86.8 n n 486490 59153 0 Div0 - - 

 Acenaphthene-d10 1 1262500 - n 10:24 11.265 0 - - n n 631240 138110 0 Div0 - - 

 Pyrene-d10 1 1664700 - n 15:08 10.0768 0 - - n n 832370 144880 0 Div0 - - 

 Benzo[e]pyrene-d12 1 1907200 - n 20:11 9.62313 0 - - n n 953610 142580 0 Div0 - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 2



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-6

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B20

 Acquired 16-Nov-2014 12:44

 Processed 16-Nov-2014 14:25

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois

 Naphthalene 1 175590000 - n 7:33 347093 0 201.199 - n n 87797000 18355000 7644 2401.2 - - - 

 2-Me-Naphthalene 1 13612000 - n 8:43 71100.9 0 31.1527 - n n 6806000 1420800 544 2611.8 - - -  1-Me-Naphthalene 1 9161500 - n 8:52 49943.9 0 32.513 - n n 4580800 980010 544 1801.5 - - - 

 Acenaphthylene 1 56995000 - n 10:09 129060 0 28.0264 - y n 28498000 6496800 1118 5812.5 - - - 

 Acenaphthene 1 4543200 - n 10:27 20919.9 0 123.006 - y n 2271600 524190 2412 217.3 - - - 

 Fluorene 1 13275000 - n 11:18 70112.4 0 39.1367 - y n 6637300 1163800 669 1738.9 - - - 

 Phenanthrene 1 707340000 - n 12:50 1321460 0 104.596 - y n 353670000 76948000 5057 15216.5 - - - 

 Anthracene 1 60108000 - n 12:54 103511 0 120.023 - y n 30054000 2926900 5057 578.8 - - - 

 Fluoranthene 1 806640000 - n 14:47 1822780 0 73.8716 - y n 403320000 80467000 2660 30254.2 - - - 

 Pyrene 1 695220000 - n 15:09 1464570 0 68.8669 - y n 347610000 74177000 2660 27889.1 - - - 

 Benz[a]anthracene 1 37075000 - n 17:32 175881 0 91.5555 - y n 18537000 3435200 1516 2265.9 - - - 

 Chrysene/Triphenylene 1 121140000 - n 17:36 393697 0 79.0896 - y n 60572000 8327300 1516 5492.8 - - - 

 Benzo[b]fluoranthene 1 17907000 - n 19:44 158306 0 441.188 - y n 8953500 1373700 4649 295.5 - - - 

 Benzo[k]fluoranthene 1 8422800 - n 19:46 59124.3 0 509.526 - y n 4211400 642050 4649 138.1 - - - 

 Benzo[e]pyrene 1 8768700 - n 20:14 35162.3 0 235.526 - y n 4384400 679680 4649 146.2 - - -  Benzo[a]pyrene 1 3469400 - n 20:21 14470.2 0 244.97 - y n 1734700 188030 4649 40.4 - - - 

 Perylene 1 792550 - n 20:30 3509.97 0 335.47 - y n 396280 43140 4649 9.3 - - - 

 Indeno[1,2,3-cd]pyrene 1 611460 - n 22:23 12801.5 0 124.375 - y n 305730 22599 289 78.2 - - - 

 Dibenzo[a,h]anthracene 1 98481 - n 22:28 1903.21 0 96.8278 - y n 49240 4301.7 250 17.2 - - - 

 Benzo[g,h,i]perylene 1 699150 - n 22:48 9825.59 0 68.1559 - y n 349570 31187 289 107.9 - - - 

 Fluorene-d10 1 165290 - n 11:15 1247.52 0 0 124.8 n n 82645 15655 0 Div0 - - - 

 p-Terphenyl-d14 1 148540 - n 15:34 849.458 0 0 84.9 n n 74268 13088 0 Div0 - - - 

 Naphthalene-d8 1 395860 - n 7:31 20.6118 0 0 2.1 n n 197930 37161 0 Div0 - - - 

 2-Me-Naphthalene-d10 1 125700 - n 8:40 17.9136 0 0 1.8 n n 62848 14331 0 Div0 - - - 

 Acenaphthylene-d8 1 304610 - n 10:08 18.4596 0 0 1.8 n n 152300 34386 0 Div0 - - - 

 Phenanthrene-d10 1 489420 - n 12:48 18.4334 0 0 1.8 n n 244710 55257 0 Div0 - - - 

 Anthracene-d10 1 512510 - n 12:53 18.4891 0 0 1.8 n n 256260 46482 0 Div0 - - - 

 Fluoranthene-d10 1 296560 - n 14:44 18.9543 0 0 1.9 n n 148280 30160 0 Div0 - - - 

 Benz[a]anthracene-d12 1 163760 - n 17:29 10.4641 0 0 1 n n 81879 16080 0 Div0 - - - 

 Chrysene-d12 1 275090 - n 17:32 10.6045 0 0 1.1 n n 137540 21421 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 97082 - n 19:41 16.2091 0 0 1.6 Y y n EG141116MB 48541 11304 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 137110 - n 19:44 14.882 0 0 1.5 Y y n EG141116MB 68553 10976 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 197800 - n 20:20 28.4959 0 0 2.8 Y y n EG141116MB 98900 19569 0 Div0 - - - 

 Perylene-d12 1 143200 - n 20:27 20.877 0 0 2.1 Y y n EG141116MB 71598 10985 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 47949 - n 22:21 10.3414 0 0 1 n n 23975 2916.8 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 32865 - n 22:24 10.1441 0 0 1 n n 16433 2049.9 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 58142 - n 22:45 11.3641 0 0 1.1 n n 29071 4332.6 0 Div0 - - - 

 Acenaphthene-d10 1 10863000 - n 10:24 96.9284 0 - - n n 5431400 1277100 0 Div0 - - - 

 Pyrene-d10 1 17743000 - n 15:08 107.399 0 - - n n 8871500 1795200 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 8701300 - n 20:11 43.9034 0 - - y n 4350700 665810 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:2



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-6

 Comments SAMPLE X50 DILX10 R»

 Sample size 1

 Filename 4-141115B07

 Acquired 16-Nov-2014 05:18

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 5010

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 25110000 - n 7:34 487151 0 823.229 - n n 12555000 2151900 2960 727 - - - 

 2-Me-Naphthalene 1 1939300 - n 8:44 88738.5 0 186.421 - n n 969670 187700 308 609.4 - - -  1-Me-Naphthalene 1 1422500 - n 8:52 67933.7 0 194.562 - n n 711270 139620 308 453.3 - - - 

 Acenaphthylene 1 8888500 - n 10:09 187885 0 357.459 - y n 4444200 922970 1441 640.6 - - - 

 Acenaphthene 1 685720 - n 10:27 29475.4 0 172.052 - y n 342860 73462 341 215.4 - - - 

 Fluorene 1 1697000 - n 11:19 83376.9 0 234.687 - Y y n EG141116MB 848490 119470 361 331.1 - - - 

 Phenanthrene 1 79017000 - n 12:51 1373210 0 262.273 - Y y n EG141117MB 39508000 7581700 1140 6650.8 - - - 

 Anthracene 1 11120000 - n 12:55 167244 0 326.688 - Y y n EG141117MB 5560100 556120 1140 487.8 - - - 

 Fluoranthene 1 95783000 - n 14:47 2066100 0 809.109 - y n 47892000 9311700 2837 3282.8 - - - 

 Pyrene 1 71057000 - n 15:09 1428910 0 754.293 - y n 35529000 6745500 2837 2378.1 - - - 

 Benz[a]anthracene 1 5926300 - n 17:32 176968 0 234.868 - y n 2963200 604970 576 1049.9 - - - 

 Chrysene/Triphenylene 1 23975000 - n 17:36 460610 0 221.449 - y n 11987000 1248200 576 2166.3 - - - 

 Benzo[b]fluoranthene 1 4205200 - n 19:44 178283 0 237.84 - Y y n EG141116MB 2102600 332290 419 793.2 - - - 

 Benzo[k]fluoranthene 1 1935500 - n 19:46 59283.2 0 253.677 - Y y n EG141116MB 967740 148290 419 354 - - - 

 Benzo[e]pyrene 1 2173100 - n 20:15 75041.4 0 269.511 - y n 1086600 175100 419 418 - - -  Benzo[a]pyrene 1 834840 - n 20:21 29984.6 0 280.318 - y n 417420 49888 419 119.1 - - - 

 Perylene 1 226620 - n 20:30 6219.37 0 215.207 - y n 113310 10818 419 25.8 - - - 

 Indeno[1,2,3-cd]pyrene 1 166630 - n 22:22 11245.7 0 279.51 - Y y n EG141116MB 83313 8234.3 150 54.9 - - - 

 Dibenzo[a,h]anthracene 1 31484 - n 22:26 1984.82 0 237.114 - Y n n EG141116MB 15742 1845.2 150 12.3 - - - 

 Benzo[g,h,i]perylene 1 189750 - n 22:47 8401.4 0 139.837 - Y y n EG141116MB 94876 10776 150 71.8 - - - 

 Fluorene-d10 1 22695 - n 11:16 1593.42 0 0 0.3 n n 11348 1952 0 Div0 - - - 

 p-Terphenyl-d14 1 6183.8 - n 15:34 337.579 0 0 0.1 n n 3091.9 787.4 0 Div0 - - - 

 Naphthalene-d8 1 20207000 - n 7:32 437599 0 343.467 87.3 n n 10103000 1762000 1448 1216.8 - - - 

 2-Me-Naphthalene-d10 1 7188700 - n 8:40 426115 0 0 85.1 n n 3594400 679320 0 Div0 - - - 

 Acenaphthylene-d8 1 16348000 - n 10:08 412061 0 0 82.2 n n 8174000 1741000 0 Div0 - - - 

 Phenanthrene-d10 1 26359000 - n 12:48 412915 0 0 82.4 n n 13180000 2488800 0 Div0 - - - 

 Anthracene-d10 1 29401000 - n 12:53 441148 0 0 88.1 n n 14701000 1928700 0 Div0 - - - 

 Fluoranthene-d10 1 15565000 - n 14:45 443129 0 0 88.4 n n 7782300 1471200 0 Div0 - - - 

 Benz[a]anthracene-d12 1 13034000 - n 17:29 370996 0 0 74.1 n n 6517000 1193600 0 Div0 - - - 

 Chrysene-d12 1 23312000 - n 17:33 400311 0 0 79.9 n n 11656000 1456700 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 10142000 - n 19:41 407086 0 0 81.3 n n 5071100 946690 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 15742000 - n 19:44 410775 0 0 82 n n 7871100 995330 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 11508000 - n 20:17 398542 0 0 79.5 n n 5753800 772100 0 Div0 - - - 

 Perylene-d12 1 11577000 - n 20:27 405754 0 0 81 n n 5788400 773080 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 7451900 - n 22:19 386369 0 0 77.1 n n 3726000 337380 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 5047500 - n 22:23 374532 0 0 74.8 n n 2523800 251630 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 9245900 - n 22:44 434440 0 0 86.7 n n 4622900 548900 0 Div0 - - - 

 Acenaphthene-d10 1 13085000 - n 10:24 116.755 0 - - n n 6542400 1493300 0 Div0 - - - 

 Pyrene-d10 1 19956000 - n 15:08 120.794 0 - - n n 9977900 1808800 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 18134000 - n 20:11 91.4958 0 - - n n 9066900 1537500 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-7

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115B12

 Acquired 16-Nov-2014 08:10

 Processed 16-Nov-2014 14:20

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments

 Naphthalene 1 906690000 - n 7:34 41667.5 0 40.6088 - y n 

 2-Me-Naphthalene 1 138960000 - n 8:43 14067.2 0 16.8199 - n n  1-Me-Naphthalene 1 90895000 - n 8:53 9603.61 0 17.5544 - n n 

 Acenaphthylene 1 348120000 - n 10:10 14770 0 2.87459 - y n 

 Acenaphthene 1 20635000 - n 10:27 1780.34 0 1.54584 - y n 

 Fluorene 1 28903000 - n 11:18 2735.18 0 15.498 - y n 

 Phenanthrene 1 895430000 - n 12:50 29972.4 0 6.56526 - y n 

 Anthracene 1 135170000 - n 12:55 4748.06 0 7.33878 - y n 

 Fluoranthene 1 795690000 - n 14:47 38069.1 0 7.93399 - y n 

 Pyrene 1 703070000 - n 15:10 31358.6 0 7.39647 - y n 

 Benz[a]anthracene 1 83645000 - n 17:32 3533.39 0 3.68618 - y n 

 Chrysene/Triphenylene 1 310130000 - n 17:36 13791.1 0 4.00467 - y n 

 Benzo[b]fluoranthene 1 100820000 - n 19:44 5171.03 0 1.36164 - Y y n EG141116MB 

 Benzo[k]fluoranthene 1 39405000 - n 19:47 1951.64 0 1.4991 - Y y n EG141116MB 

 Benzo[e]pyrene 1 47667000 - n 20:15 2544.98 0 1.7698 - Y y n EG141116MB  Benzo[a]pyrene 1 14957000 - n 20:21 830.591 0 1.84076 - Y y n EG141116MB 

 Perylene 1 2573500 - n 20:31 107.218 0 1.37971 - Y y n EG141116MB 

 Indeno[1,2,3-cd]pyrene 1 13176000 - n 22:22 1063.38 0 0.616077 - y n 

 Dibenzo[a,h]anthracene 1 2949700 - n 22:26 207.464 0 0.826039 - y n 

 Benzo[g,h,i]perylene 1 13731000 - n 22:47 820.664 0 0.357547 - y n 

 Fluorene-d10 1 8757400 - n 11:15 1184.25 0 0 118.4 n n 

 p-Terphenyl-d14 1 9470600 - n 15:34 1146.73 0 0 114.7 n n 

 Naphthalene-d8 1 17027000 - n 7:32 678.722 0 0.508622 67.9 n n 

 2-Me-Naphthalene-d10 1 6485500 - n 8:41 707.596 0 0 70.8 n n 

 Acenaphthylene-d8 1 16257000 - n 10:09 754.223 0 0 75.4 n n 

 Phenanthrene-d10 1 27316000 - n 12:48 787.622 0 0 78.8 n n 

 Anthracene-d10 1 25125000 - n 12:53 693.91 0 0 69.4 n n 

 Fluoranthene-d10 1 14007000 - n 14:45 821.099 0 0 82.1 n n 

 Benz[a]anthracene-d12 1 18391000 - n 17:29 1077.84 0 0 107.8 n n 

 Chrysene-d12 1 20103000 - n 17:33 710.804 0 0 71.1 n n 

 Benzo[b]fluoranthene-d12 1 16734000 - n 19:41 957.201 0 0 95.7 n n 

 Benzo[k]fluoranthene-d12 1 19432000 - n 19:44 722.635 0 0 72.3 n n 

 Benzo[a]pyrene-d12 1 14856000 - n 20:17 733.242 0 0 73.3 n n 

 Perylene-d12 1 15222000 - n 20:27 760.322 0 0 76 n n 

 Indeno[1,2,3-cd]pyrene-d12 1 12439000 - n 22:20 919.129 0 0 91.9 n n 

 Dibenzo[a,h]anthracene-d14 1 9030600 - n 22:23 954.955 0 0 95.5 n n 

 Benzo[g,h,i]perylene-d12 1 13671000 - n 22:44 915.469 0 0 91.5 n n 

 Acenaphthene-d10 1 14189000 - n 10:24 126.611 0 - - n n 

 Pyrene-d10 1 19345000 - n 15:08 117.096 0 - - n n 

 Benzo[e]pyrene-d12 1 25397000 - n 20:11 128.146 0 - - n n 

 F1 Lock Mass 0 * NotFnd * * - - n  F2 Lock Mass 0 * NotFnd * * - - n  F3 Lock Mass 0 * NotFnd * * - - n  F4 Lock Mass 0 * NotFnd * * - - n  F5 Lock Mass 0 * NotFnd * * - - n  F6 Lock Mass 0 * NotFnd * * - - n 

 DUMMY LINE 0 * NotFnd * * - - n 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-7

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B08

 Acquired 16-Nov-2014 05:52

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 27562000 - n 7:33 37665.1 0 61.4328 - y n 13781000 2512600 3325 755.7 - - - 

 2-Me-Naphthalene 1 3899900 - n 8:43 14511.8 0 10.8988 - n n 1949900 396540 252 1573.6 - - -  1-Me-Naphthalene 1 3260200 - n 8:52 12661.4 0 11.3747 - n n 1630100 340900 252 1352.8 - - - 

 Acenaphthylene 1 7865300 - n 10:10 12099.7 0 26.0988 - y n 3932700 821630 1400 586.8 - - - 

 Acenaphthene 1 622150 - n 10:27 1946.27 0 34.1405 - y n 311080 70271 901 78 - - - 

 Fluorene 1 707830 - n 11:19 2542.84 0 48.6024 - y n 353910 61226 1000 61.2 - - - 

 Phenanthrene 1 28658000 - n 12:51 36415.9 0 14.9229 - Y y n EG141116MB 14329000 2532000 868 2916.9 - - - 

 Anthracene 1 7021300 - n 12:56 8622.98 0 21.335 - Y y n EG141116MB 3510700 316800 868 365 - - - 

 Fluoranthene 1 21833000 - n 14:47 36805.9 0 25.7255 - y n 10916000 1836200 1099 1671.1 - - - 

 Pyrene 1 17028000 - n 15:09 26761.7 0 23.9827 - y n 8514100 1533000 1099 1395.2 - - - 

 Benz[a]anthracene 1 626550 - n 17:33 2187.34 0 53.4124 - y n 313280 85285 985 86.5 - - - 

 Chrysene/Triphenylene 1 626550 - n 17:33 2517.08 0 61.4643 - y n 313280 85285 985 86.5 - - - 

 Benzo[b]fluoranthene 1 725830 - n 19:45 4063.8 0 18.46 - Y y n EG141116MB 362920 60880 254 239.5 - - - 

 Benzo[k]fluoranthene 1 518250 - n 19:47 2935.2 0 23.8613 - Y y n EG141116MB 259120 39840 254 156.7 - - - 

 Benzo[e]pyrene 1 647220 - n 20:15 841.814 0 5.51761 - Y y n EG141116MB 323610 46154 254 181.6 - - -  Benzo[a]pyrene 1 79721 - n 20:22 107.848 0 5.73886 - Y y n EG141116MB 39861 8197.3 254 32.2 - - - 

 Perylene 1 23056 - n 20:30 85.1588 0 11.971 - Y y n EG141116MB 11528 2210 254 8.7 - - - 

 Indeno[1,2,3-cd]pyrene 1 80125 - n 22:25 1042.5 0 25.5784 - Y y n EG141116MB 40062 3505.9 90 38.8 - - - 

 Dibenzo[a,h]anthracene 1 7193.5 - n 22:27 215.703 0 28.0971 - Y y n EG141116MB 3596.8 803.29 90 8.9 - - - 

 Benzo[g,h,i]perylene 1 101630 - n 22:48 579.166 0 13.5 - Y y n EG141116MB 50815 5053.6 90 55.9 - - - 

 Fluorene-d10 1 182730 - n 11:15 938.041 0 0 93.8 n n 91363 16629 0 Div0 - - - 

 p-Terphenyl-d14 1 181940 - n 15:35 776.256 0 0 77.6 n n 90972 11578 0 Div0 - - - 

 Naphthalene-d8 1 572590 - n 7:31 23.7881 0 0.065043 2.4 n n 286300 52941 144 367.6 - - - 

 2-Me-Naphthalene-d10 1 176440 - n 8:40 20.0635 0 0 2 n n 88221 18976 0 Div0 - - - 

 Acenaphthylene-d8 1 448370 - n 10:08 21.68 0 0 2.2 n n 224180 46256 0 Div0 - - - 

 Phenanthrene-d10 1 719560 - n 12:48 21.6237 0 0 2.2 n n 359780 66483 0 Div0 - - - 

 Anthracene-d10 1 718660 - n 12:53 20.6859 0 0 2.1 n n 359330 44887 0 Div0 - - - 

 Fluoranthene-d10 1 397510 - n 14:45 24.0274 0 0 2.4 n n 198760 35779 0 Div0 - - - 

 Benz[a]anthracene-d12 1 222530 - n 17:30 13.4477 0 0 1.3 n n 111270 17917 0 Div0 - - - 

 Chrysene-d12 1 222530 - n 17:30 8.11275 0 0 0.8 n n 111270 17917 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 153290 - n 19:42 20.6538 0 0 2.1 y n 76645 14772 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 169930 - n 19:46 14.8845 0 0 1.5 y n 84964 12816 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 609820 - n 20:17 70.8959 0 0 7.1 y n 304910 45676 0 Div0 - - - 

 Perylene-d12 1 171690 - n 20:28 20.2002 0 0 2 y n 85847 16832 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 77155 - n 22:21 13.4284 0 0 1.3 y n 38577 4432.9 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 21182 - n 22:24 5.2759 0 0 0.5 n n 10591 2553.3 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 143380 - n 22:45 22.6153 0 0 2.3 n n 71691 6836.4 0 Div0 - - - 

 Acenaphthene-d10 1 13614000 - n 10:24 121.481 0 - - n n 6807200 1565300 0 Div0 - - - 

 Pyrene-d10 1 18761000 - n 15:07 113.564 0 - - n n 9380700 1678600 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 10783000 - n 20:11 54.4045 0 - - y n 5391300 833260 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-8

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115B13

 Acquired 16-Nov-2014 08:44

 Processed 16-Nov-2014 14:24

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 606030000 - n 7:34 26408.3 0 63.2898 - n n 303020000 67186000 115132 583.6 - - - 

 2-Me-Naphthalene 1 150370000 - n 8:44 13919.9 0 3.37125 - n n 75184000 18666000 3500 5333.2 - - -  1-Me-Naphthalene 1 107190000 - n 8:53 10356.5 0 3.51846 - n n 53597000 13952000 3500 3986.4 - - - 

 Acenaphthylene 1 85694000 - n 10:10 3665.15 0 3.22489 - y n 42847000 10151000 6922 1466.5 - - - 

 Acenaphthene 1 18659000 - n 10:28 1622.82 0 1.89486 - n n 9329400 2248600 2000 1124.3 - - - 

 Fluorene 1 24763000 - n 11:18 2367.31 0 5.29912 - y n 12381000 2600500 4924 528.2 - - - 

 Phenanthrene 1 672650000 - n 12:51 22745.5 0 7.76486 - y n 336330000 74012000 20397 3628.5 - - - 

 Anthracene 1 48660000 - n 12:55 1817.6 0 9.82978 - y n 24330000 3982400 20397 195.2 - - - 

 Fluoranthene 1 220750000 - n 14:47 11805.2 0 4.07893 - y n 110370000 25000000 6620 3776.2 - - - 

 Pyrene 1 159490000 - n 15:10 7951.32 0 3.80259 - y n 79744000 17070000 6620 2578.3 - - - 

 Benz[a]anthracene 1 33867000 - n 17:32 3346.58 0 4.72447 - Y y n EG141116MB 16934000 3120700 3775 826.7 - - - 

 Chrysene/Triphenylene 1 108410000 - n 17:37 9992.48 0 5.03945 - Y y n EG141116MB 54204000 8448600 3775 2238.1 - - - 

 Benzo[b]fluoranthene 1 33049000 - n 19:44 5464.09 0 3.18728 - Y y n EG141116MB 16524000 2619400 1547 1692.8 - - - 

 Benzo[k]fluoranthene 1 11783000 - n 19:47 1596.06 0 3.56191 - Y y n EG141116MB 5891600 1002500 1547 647.9 - - - 

 Benzo[e]pyrene 1 15737000 - n 20:15 2773.33 0 4.94459 - Y y n EG141116MB 7868300 1361400 1547 879.8 - - -  Benzo[a]pyrene 1 2492700 - n 20:21 456.911 0 5.14287 - Y y n EG141116MB 1246300 143100 1547 92.5 - - - 

 Perylene 1 640450 - n 20:31 87.7751 0 3.55186 - Y y n EG141116MB 320220 33637 1547 21.7 - - - 

 Indeno[1,2,3-cd]pyrene 1 4057200 - n 22:23 1169.03 0 3.83501 - Y y n EG141116MB 2028600 206370 522 395.6 - - - 

 Dibenzo[a,h]anthracene 1 1254100 - n 22:26 324.072 0 1.34808 - Y y n EG141116MB 627060 57623 244 235.9 - - - 

 Benzo[g,h,i]perylene 1 3561100 - n 22:48 751.189 0 2.17667 - y n 1780500 209210 522 401 - - - 

 Fluorene-d10 1 7960900 - n 11:15 1087.55 0 0 108.8 n n 3980500 899810 0 Div0 - - - 

 p-Terphenyl-d14 1 6303200 - n 15:34 853.091 0 0 85.3 n n 3151600 594250 0 Div0 - - - 

 Naphthalene-d8 1 17957000 - n 7:32 837.372 0 0.750771 83.7 n n 8978500 1779300 1560 1140.6 - - - 

 2-Me-Naphthalene-d10 1 7092400 - n 8:41 905.255 0 0.010538 90.5 n n 3546200 852040 8 106504.8 - - - 

 Acenaphthylene-d8 1 16127000 - n 10:09 875.282 0 0 87.5 n n 8063400 1850600 0 Div0 - - - 

 Phenanthrene-d10 1 27040000 - n 12:48 912.09 0 0 91.2 n n 13520000 3002400 0 Div0 - - - 

 Anthracene-d10 1 23629000 - n 12:53 763.418 0 0 76.3 n n 11814000 2289300 0 Div0 - - - 

 Fluoranthene-d10 1 12531000 - n 14:45 1027.51 0 0 102.8 n n 6265500 1359600 0 Div0 - - - 

 Benz[a]anthracene-d12 1 7861800 - n 17:29 644.501 0 0 64.5 n n 3930900 775900 0 Div0 - - - 

 Chrysene-d12 1 9698800 - n 17:33 479.667 0 0 48 n n 4849400 837060 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 5191000 - n 19:41 1041.89 0 0 104.2 n n 2595500 520830 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 7105300 - n 19:44 927.125 0 0 92.7 n n 3552700 522620 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 4500700 - n 20:18 779.436 0 0 77.9 n n 2250300 310270 0 Div0 - - - 

 Perylene-d12 1 4627200 - n 20:27 810.969 0 0 81.1 n n 2313600 345340 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 3483900 - n 22:20 903.273 0 0 90.3 n n 1742000 170690 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 2457900 - n 22:23 912 0 0 91.2 n n 1229000 143840 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 3873500 - n 22:44 910.13 0 0 91 n n 1936800 244790 0 Div0 - - - 

 Acenaphthene-d10 1 12129000 - n 10:24 108.227 0 - - n n 6064500 1469100 0 Div0 - - - 

 Pyrene-d10 1 13830000 - n 15:08 83.7144 0 - - n n 6915000 1393800 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 7238300 - n 20:12 36.5215 0 - - n n 3619100 649730 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-8

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B09

 Acquired 16-Nov-2014 06:27

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 11033000 - n 7:33 20235.4 0 197.775 - n n 5516500 987320 7876 125.4 - - - 

 2-Me-Naphthalene 1 2879900 - n 8:43 13181.3 0 18.0383 - n n 1440000 287710 332 866.6 - - -  1-Me-Naphthalene 1 2643100 - n 8:52 12625.7 0 18.826 - n n 1321600 273390 332 823.5 - - - 

 Acenaphthylene 1 1874100 - n 10:09 3482.1 0 17.6058 - y n 937040 185110 819 225.9 - - - 

 Acenaphthene 1 431330 - n 10:26 1629.69 0 15.5643 - y n 215660 48771 356 136.9 - - - 

 Fluorene 1 588940 - n 11:17 2855.01 0 33.7698 - y n 294470 48457 469 103.3 - - - 

 Phenanthrene 1 12923000 - n 12:51 22158.2 0 62.5476 - y n 6461300 1094400 2457 445.4 - - - 

 Anthracene 1 2782800 - n 12:54 3612.12 0 75.6079 - y n 1391400 138540 2457 56.4 - - - 

 Fluoranthene 1 5140200 - n 14:47 10701.6 0 4.46404 - n n 2570100 405430 150 2702.8 - - - 

 Pyrene 1 4318300 - n 15:10 8381.18 0 4.1616 - y n 2159100 352870 150 2352.5 - - - 

 Benz[a]anthracene 1 549370 - n 17:34 3328.43 0 10.7016 - Y y n EG141116MB 274680 58876 112 524.2 - - - 

 Chrysene/Triphenylene 1 3231400 - n 17:37 9603.36 0 8.67377 - Y y n EG141116MB 1615700 130450 112 1161.4 - - - 

 Benzo[b]fluoranthene 1 576710 - n 19:44 5290.32 0 34.458 - Y y n EG141116MB 288350 34656 218 159.3 - - - 

 Benzo[k]fluoranthene 1 256130 - n 19:48 2634.79 0 38.6407 - Y y n EG141116MB 128070 17784 218 81.7 - - - 

 Benzo[e]pyrene 1 387720 - n 20:14 1563.08 0 7.98646 - Y y n EG141116MB 193860 24759 218 113.8 - - -  Benzo[a]pyrene 1 31480 - n 20:21 132.003 0 8.30671 - Y y n EG141116MB 15740 3308.4 218 15.2 - - - 

 Perylene 1 14579 - n 20:30 163.327 0 17.0521 - Y y n EG141116MB 7289.4 1384.9 218 6.4 - - - 

 Indeno[1,2,3-cd]pyrene 1 35665 - n 22:24 815.991 0 52.3308 - y n 17833 1852.9 100 18.5 - - - 

 Dibenzo[a,h]anthracene 1 4268 - n 22:26 94.9548 0 53.7593 - n n 2134 430.09 100 4.3 - - - 

 Benzo[g,h,i]perylene 1 58170 - n 22:48 855.739 0 36.9972 - y n 29085 2548.7 100 25.5 - - - 

 Fluorene-d10 1 168710 - n 11:14 1168.72 0 0 116.9 n n 84356 13272 0 Div0 - - - 

 p-Terphenyl-d14 1 175770 - n 15:34 926.109 0 0 92.6 n n 87884 9278.2 0 Div0 - - - 

 Naphthalene-d8 1 426640 - n 7:31 17.9896 0 0.003621 1.8 n n 213320 38951 8 4868.9 - - - 

 2-Me-Naphthalene-d10 1 143450 - n 8:40 16.5559 0 0 1.7 n n 71724 15105 0 Div0 - - - 

 Acenaphthylene-d8 1 371230 - n 10:08 18.2187 0 0 1.8 n n 185610 40127 0 Div0 - - - 

 Phenanthrene-d10 1 533240 - n 12:48 16.2644 0 0 1.6 n n 266620 44904 0 Div0 - - - 

 Anthracene-d10 1 679970 - n 12:53 19.8651 0 0 2 n n 339980 35857 0 Div0 - - - 

 Fluoranthene-d10 1 321880 - n 14:45 20.0447 0 0 2 n n 160940 28147 0 Div0 - - - 

 Benz[a]anthracene-d12 1 128220 - n 17:30 7.98311 0 0 0.8 n n 64112 10192 0 Div0 - - - 

 Chrysene-d12 1 300810 - n 17:33 11.2984 0 0 1.1 n n 150410 14471 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 93559 - n 19:42 17.4009 0 0 1.7 n n 46780 6773.5 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 93559 - n 19:42 11.3124 0 0 1.1 n n 46780 6773.5 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 196740 - n 20:18 31.5732 0 0 3.2 Y y n EG141116MB 98372 27009 0 Div0 - - - 

 Perylene-d12 1 56606 - n 20:27 9.19326 0 0 0.9 Y y n EG141116MB 28303 10114 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 43877 - n 22:21 10.5414 0 0 1.1 y n 21938 2397.9 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 28548 - n 22:27 9.81571 0 0 1 y n 14274 1476.8 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 55543 - n 22:45 12.0933 0 0 1.2 y n 27772 2760.7 0 Div0 - - - 

 Acenaphthene-d10 1 13414000 - n 10:24 119.69 0 - - n n 6706800 1561900 0 Div0 - - - 

 Pyrene-d10 1 18211000 - n 15:07 110.23 0 - - n n 9105300 1564100 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 7811200 - n 20:11 39.4124 0 - - Y y n EG141116MB 3905600 577260 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-9

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115B15

 Acquired 16-Nov-2014 09:53

 Processed 16-Nov-2014 14:24

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 826870000 - n 7:35 42043.2 0 51.0537 - n n 413440000 78066000 84120 928 - - - 

 2-Me-Naphthalene 1 169760000 - n 8:43 18310 0 2.85431 - n n 84878000 21503000 2484 8656.7 - - -  1-Me-Naphthalene 1 117090000 - n 8:53 13180.8 0 2.97895 - n n 58544000 15278000 2484 6150.6 - - - 

 Acenaphthylene 1 318790000 - n 10:10 15005.6 0 3.82638 - y n 159400000 40921000 7771 5266.1 - - - 

 Acenaphthene 1 24327000 - n 10:27 2328.48 0 1.4186 - y n 12163000 2991200 1417 2111.4 - - - 

 Fluorene 1 34138000 - n 11:18 3498.93 0 8.01185 - y n 17069000 3493700 6874 508.3 - - - 

 Phenanthrene 1 997300000 - n 12:50 36155.1 0 4.2779 - y n 498650000 83777000 10376 8074 - - - 

 Anthracene 1 159650000 - n 12:55 5969.03 0 4.6203 - y n 79824000 14558000 10376 1403 - - - 

 Fluoranthene 1 961120000 - n 14:47 43785 0 11.5153 - y n 480560000 82429000 21626 3811.6 - - - 

 Pyrene 1 886920000 - n 15:10 37667.1 0 10.7351 - y n 443460000 81194000 21626 3754.5 - - - 

 Benz[a]anthracene 1 85725000 - n 17:33 3507.59 0 1.31956 - y n 42862000 8551900 2565 3334.3 - - - 

 Chrysene/Triphenylene 1 267830000 - n 17:36 10561.9 0 1.45361 - y n 133920000 19977000 2565 7789 - - - 

 Benzo[b]fluoranthene 1 107720000 - n 19:44 5081.22 0 1.20975 - y n 53859000 10136000 2103 4819.1 - - - 

 Benzo[k]fluoranthene 1 30966000 - n 19:47 1306.52 0 1.3357 - y n 15483000 2521900 2103 1199 - - - 

 Benzo[e]pyrene 1 48604000 - n 20:15 2153.35 0 1.47517 - y n 24302000 4687100 2103 2228.4 - - -  Benzo[a]pyrene 1 11066000 - n 20:21 509.922 0 1.53433 - y n 5532900 790660 2103 375.9 - - - 

 Perylene 1 1720100 - n 20:31 60.3603 0 1.12143 - y n 860040 133750 2103 63.6 - - - 

 Indeno[1,2,3-cd]pyrene 1 10459000 - n 22:22 651.184 0 0.737189 - y n 5229600 630320 553 1138.8 - - - 

 Dibenzo[a,h]anthracene 1 2375300 - n 22:26 128.855 0 1.23689 - y n 1187600 154530 1231 125.5 - - - 

 Benzo[g,h,i]perylene 1 11193000 - n 22:47 528.175 0 0.4457 - y n 5596700 735020 553 1328 - - - 

 Fluorene-d10 1 7814200 - n 11:15 1144.47 0 0 114.4 n n 3907100 855360 0 Div0 - - - 

 p-Terphenyl-d14 1 9793600 - n 15:34 1129.14 0 0 112.9 n n 4896800 1018600 0 Div0 - - - 

 Naphthalene-d8 1 15389000 - n 7:32 648.893 0 0.54712 64.9 n n 7694700 1611600 1268 1271 - - - 

 2-Me-Naphthalene-d10 1 6087000 - n 8:40 702.505 0 0 70.3 n n 3043500 714220 0 Div0 - - - 

 Acenaphthylene-d8 1 14654000 - n 10:09 719.136 0 0 71.9 n n 7326900 1750900 0 Div0 - - - 

 Phenanthrene-d10 1 25221000 - n 12:48 769.246 0 0 76.9 n n 12611000 2772200 0 Div0 - - - 

 Anthracene-d10 1 23606000 - n 12:54 689.617 0 0 69 n n 11803000 2477700 0 Div0 - - - 

 Fluoranthene-d10 1 14710000 - n 14:45 796.405 0 0 79.6 n n 7355000 1573100 0 Div0 - - - 

 Benz[a]anthracene-d12 1 18986000 - n 17:29 1027.69 0 0 102.8 n n 9493200 1887500 0 Div0 - - - 

 Chrysene-d12 1 22670000 - n 17:33 740.257 0 0 74 n n 11335000 1971700 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 18194000 - n 19:41 849.794 0 0 85 n n 9097100 1865200 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 22810000 - n 19:45 692.627 0 0 69.3 n n 11405000 1894400 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 17903000 - n 20:18 721.507 0 0 72.2 n n 8951500 1413600 0 Div0 - - - 

 Perylene-d12 1 18072000 - n 20:27 737.054 0 0 73.7 n n 9035900 1486800 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 16124000 - n 22:20 972.805 0 0 97.3 n n 8061900 942100 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 11708000 - n 22:23 1010.93 0 0 101.1 n n 5854100 790400 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 17317000 - n 22:44 946.824 0 0 94.7 n n 8658300 1268400 0 Div0 - - - 

 Acenaphthene-d10 1 13414000 - n 10:24 119.694 0 - - n n 6707100 1638500 0 Div0 - - - 

 Pyrene-d10 1 20946000 - n 15:08 126.789 0 - - n n 10473000 2167600 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 31105000 - n 20:11 156.941 0 - - n n 15552000 2921500 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-9

 Comments SAMPLE X50 REINJECT

 Sample size 1

 Filename 4-141115B14

 Acquired 16-Nov-2014 09:18

 Processed 16-Nov-2014 14:24

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 

 Naphthalene 1 25267000 - n 7:33 44081 0 193.419 - y n 12633000 2252900 8007 281.4 - - - 

 2-Me-Naphthalene 1 4193000 - n 8:43 15960.3 0 18.5169 - n n 2096500 432890 388 1115.7 - - -  1-Me-Naphthalene 1 3441900 - n 8:52 13673.2 0 19.3255 - n n 1720900 355630 388 916.6 - - - 

 Acenaphthylene 1 7049600 - n 10:09 12711 0 10.2938 - y n 3524800 754170 488 1546.2 - - - 

 Acenaphthene 1 701280 - n 10:27 2571.3 0 31.0222 - y n 350640 79736 723 110.3 - - - 

 Fluorene 1 1018300 - n 11:18 4223.48 0 31.6339 - Y y n EG141116MB 509140 76906 573 134.2 - - - 

 Phenanthrene 1 50446000 - n 12:50 74009.4 0 25.495 - y n 25223000 4647600 1306 3559.6 - - - 

 Anthracene 1 10098000 - n 12:56 13211.2 0 30.5543 - y n 5048800 430190 1306 329.5 - - - 

 Fluoranthene 1 33871000 - n 14:47 64547.2 0 58.0548 - y n 16936000 3009200 2040 1474.8 - - - 

 Pyrene 1 26394000 - n 15:09 46889.8 0 54.1217 - y n 13197000 2378200 2040 1165.6 - - - 

 Benz[a]anthracene 1 695770 - n 17:33 2179.37 0 20.2298 - Y y n EG141116MB 347880 97471 395 247 - - - 

 Chrysene/Triphenylene 1 4914300 - n 17:36 9523.91 0 17.7449 - Y y n EG141116MB 2457200 196370 395 497.6 - - - 

 Benzo[b]fluoranthene 1 1065900 - n 19:45 5057.73 0 60.0566 - Y y n EG141116MB 532940 73280 686 106.9 - - - 

 Benzo[k]fluoranthene 1 538520 - n 19:47 1882.08 0 49.5709 - Y y n EG141116MB 269260 32784 686 47.8 - - - 

 Benzo[e]pyrene 1 714580 - n 20:14 958.586 0 59.4299 - Y y n EG141116MB 357290 53063 3964 13.4 - - -  Benzo[a]pyrene 1 135790 - n 20:22 189.462 0 61.813 - Y y n EG141116MB 67895 7379.4 3964 1.9 - - - 

 Perylene 1 24002 - n 20:31 60.5625 0 223.997 - Y y n EG141116MB 12001 2470.3 3964 0.6 - - - 

 Indeno[1,2,3-cd]pyrene 1 79466 - n 22:23 596.847 0 44.0295 - Y y n EG141116MB 39733 3767.1 201 18.7 - - - 

 Dibenzo[a,h]anthracene 1 18020 - n 22:28 197.979 0 56.5105 - Y y n EG141116MB 9010.2 751.77 309 2.4 - - - 

 Benzo[g,h,i]perylene 1 116170 - n 22:48 505.172 0 21.5819 - Y y n EG141116MB 58084 5299.9 201 26.4 - - - 

 Fluorene-d10 1 227380 - n 11:15 1347.68 0 0 134.8 n n 113690 19232 0 Div0 - - - 

 p-Terphenyl-d14 1 212880 - n 15:34 1026.71 0 0 102.7 n n 106440 16080 0 Div0 - - - 

 Naphthalene-d8 1 448520 - n 7:31 20.9779 0 0 2.1 n n 224260 40490 0 Div0 - - - 

 2-Me-Naphthalene-d10 1 172490 - n 8:40 22.0819 0 0 2.2 n n 86244 17197 0 Div0 - - - 

 Acenaphthylene-d8 1 382540 - n 10:08 20.8246 0 0 2.1 n n 191270 40855 0 Div0 - - - 

 Phenanthrene-d10 1 623240 - n 12:48 21.0856 0 0 2.1 n n 311620 58532 0 Div0 - - - 

 Anthracene-d10 1 674580 - n 12:53 21.8604 0 0 2.2 n n 337290 47144 0 Div0 - - - 

 Fluoranthene-d10 1 351650 - n 14:45 20.3762 0 0 2 n n 175830 29441 0 Div0 - - - 

 Benz[a]anthracene-d12 1 248020 - n 17:29 14.3678 0 0 1.4 n n 124010 18943 0 Div0 - - - 

 Chrysene-d12 1 461290 - n 17:33 16.1215 0 0 1.6 Y n n EG141116MB 230650 24851 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 180870 - n 19:41 19.0149 0 0 1.9 Y y n EG141116MB 90436 12248 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 275380 - n 19:45 18.821 0 0 1.9 Y y n EG141116MB 137690 16640 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 591270 - n 20:16 53.6346 0 0 5.4 Y y n EG141116MB 295640 66135 0 Div0 - - - 

 Perylene-d12 1 251330 - n 20:27 23.0725 0 0 2.3 Y y n EG141116MB 125670 14029 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 133660 - n 22:21 18.1509 0 0 1.8 Y y n EG141116MB 66829 5731 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 57812 - n 22:25 11.2357 0 0 1.1 n n 28906 4341.7 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 187900 - n 22:44 23.1248 0 0 2.3 Y y n EG141116MB 93950 9516.7 0 Div0 - - - 

 Acenaphthene-d10 1 12093000 - n 10:23 107.904 0 - - n n 6046400 1378700 0 Div0 - - - 

 Pyrene-d10 1 19571000 - n 15:07 118.465 0 - - n n 9785500 1791000 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 13819000 - n 20:11 69.7258 0 - - y n 6909600 1120000 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-10

 Comments SAMPLE X10

 Sample size 1

 Filename 4-141115B16

 Acquired 16-Nov-2014 10:27

 Processed 16-Nov-2014 14:25

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois

 Naphthalene 1 971840000 - n 7:34 43099.6 0 43.0338 - n n 485920000 83399000 81944 1017.8 - - - 

 2-Me-Naphthalene 1 166190000 - n 8:44 16400.4 0 3.85211 - Y y n EG141116MB 83097000 21416000 3797 5640.3 - - -  1-Me-Naphthalene 1 113940000 - n 8:54 11734.7 0 4.02032 - Y y n EG141116MB 56969000 13923000 3797 3666.8 - - - 

 Acenaphthylene 1 413020000 - n 10:10 19063.7 0 2.9386 - y n 206510000 54815000 6124 8951.1 - - - 

 Acenaphthene 1 21829000 - n 10:27 2048.84 0 5.76557 - y n 10914000 2655300 5909 449.4 - - - 

 Fluorene 1 27909000 - n 11:18 3075.36 0 2.04726 - y n 13954000 2831600 1615 1752.9 - - - 

 Phenanthrene 1 874940000 - n 12:50 34102.5 0 10.5061 - y n 437470000 82870000 23436 3535.9 - - - 

 Anthracene 1 155680000 - n 12:55 6298.59 0 11.3271 - y n 77839000 15287000 23436 652.3 - - - 

 Fluoranthene 1 671540000 - n 14:47 38394.6 0 13.6445 - y n 335770000 75619000 20508 3687.3 - - - 

 Pyrene 1 481120000 - n 15:10 25644.2 0 12.7201 - y n 240560000 54695000 20508 2667 - - - 

 Benz[a]anthracene 1 31517000 - n 17:32 3287.84 0 1.06611 - y n 15759000 2989700 797 3751.6 - - - 

 Chrysene/Triphenylene 1 56773000 - n 17:36 5204.83 0 1.13111 - y n 28387000 3854100 797 4836.2 - - - 

 Benzo[b]fluoranthene 1 18450000 - n 19:44 3164.93 0 2.83701 - Y y n EG141116MB 9224800 1549300 1241 1248.2 - - - 

 Benzo[k]fluoranthene 1 8047200 - n 19:47 1246.82 0 3.17101 - Y y n EG141116MB 4023600 600580 1241 483.8 - - - 

 Benzo[e]pyrene 1 10193000 - n 20:15 1660.75 0 3.65433 - y n 5096500 866820 1241 698.3 - - -  Benzo[a]pyrene 1 4021100 - n 20:21 681.427 0 3.80086 - y n 2010500 252480 1241 203.4 - - - 

 Perylene 1 1025400 - n 20:31 132.977 0 2.91423 - y n 512690 54758 1241 44.1 - - - 

 Indeno[1,2,3-cd]pyrene 1 3283500 - n 22:22 980.136 0 1.74022 - Y y n EG141116MB 1641800 173220 223 776.1 - - - 

 Dibenzo[a,h]anthracene 1 728270 - n 22:27 203.765 0 2.7233 - Y y n EG141116MB 364130 41705 434 96 - - - 

 Benzo[g,h,i]perylene 1 3485200 - n 22:47 807.449 0 1.03337 - Y y n EG141116MB 1742600 209470 223 938.5 - - - 

 Fluorene-d10 1 6612700 - n 11:15 1041.27 0 0 104.1 n n 3306300 733140 0 Div0 - - - 

 p-Terphenyl-d14 1 5867600 - n 15:34 849.012 0 0 84.9 n n 2933800 565740 0 Div0 - - - 

 Naphthalene-d8 1 17644000 - n 7:32 689.401 0 0.540702 68.9 n n 8822000 1862500 1344 1385.8 - - - 

 2-Me-Naphthalene-d10 1 6653300 - n 8:40 711.541 0 0.004405 71.2 n n 3326600 808940 4 202235.8 - - - 

 Acenaphthylene-d8 1 14944000 - n 10:09 679.587 0 0 68 n n 7471900 1796700 0 Div0 - - - 

 Phenanthrene-d10 1 23459000 - n 12:48 663.015 0 0 66.3 n n 11729000 2549600 0 Div0 - - - 

 Anthracene-d10 1 21814000 - n 12:54 590.548 0 0 59.1 n n 10907000 2282700 0 Div0 - - - 

 Fluoranthene-d10 1 11721000 - n 14:45 694.503 0 0 69.5 n n 5860500 1259000 0 Div0 - - - 

 Benz[a]anthracene-d12 1 7447100 - n 17:29 441.161 0 0 44.1 n n 3723500 725890 0 Div0 - - - 

 Chrysene-d12 1 9751300 - n 17:33 348.496 0 0 34.8 n n 4875700 787310 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 5003100 - n 19:41 667.051 0 0 66.7 n n 2501500 469380 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 6211600 - n 19:45 538.41 0 0 53.8 n n 3105800 470910 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 4868200 - n 20:18 560.041 0 0 56 n n 2434100 336770 0 Div0 - - - 

 Perylene-d12 1 4890100 - n 20:28 569.317 0 0 56.9 n n 2445000 337640 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 3363000 - n 22:20 579.199 0 0 57.9 n n 1681500 160940 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 2270100 - n 22:23 559.515 0 0 56 n n 1135000 126630 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 3526900 - n 22:44 550.473 0 0 55 n n 1763400 220610 0 Div0 - - - 

 Acenaphthene-d10 1 14476000 - n 10:24 129.166 0 - - n n 7237900 1757400 0 Div0 - - - 

 Pyrene-d10 1 19139000 - n 15:08 115.848 0 - - n n 9569300 1916000 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 10896000 - n 20:12 54.979 0 - - n n 5448200 970240 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID L1535265-10

 Comments SAMPLE X50

 Sample size 1

 Filename 4-141115B11

 Acquired 16-Nov-2014 07:35

 Processed 16-Nov-2014 10:13

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area Hght1 Nois1 S/N 1 Area2 Hght2 N

 Naphthalene 1 24410000 - n 7:33 43863 0 93.1008 - y n 12205000 2221000 4030 551.1 - - 

 2-Me-Naphthalene 1 3364100 - n 8:42 15136.7 0 38.0919 - y n 1682000 320680 649 494.3 - -  1-Me-Naphthalene 1 2883800 - n 8:52 13542.3 0 39.7553 - y n 1441900 293720 649 452.7 - - 

 Acenaphthylene 1 7391100 - n 10:09 14908 0 27.9179 - y n 3695600 773380 1177 656.9 - - 

 Acenaphthene 1 572810 - n 10:27 2349.45 0 29.8722 - y n 286410 63747 619 102.9 - - 

 Fluorene 1 686030 - n 11:17 3647.15 0 14.6751 - y n 343010 53463 182 294.3 - - 

 Phenanthrene 1 23125000 - n 12:50 43486.4 0 55.7218 - Y y n EG141116MB 11563000 1942300 1950 996.1 - - 

 Anthracene 1 6398200 - n 12:55 10527.1 0 70.7458 - Y y n EG141116MB 3199100 273610 1950 140.3 - - 

 Fluoranthene 1 13716000 - n 14:46 30364.9 0 77.7516 - y n 6858200 1123900 2418 464.8 - - 

 Pyrene 1 11179000 - n 15:09 23070 0 72.4841 - y n 5589300 972080 2418 402 - - 

 Benz[a]anthracene 1 706790 - n 17:35 4347.79 0 86.0842 - Y y n EG141116MB 353400 49528 915 54.2 - - 

 Chrysene/Triphenylene 1 706790 - n 17:35 5003.22 0 99.0613 - Y y n EG141116MB 353400 49528 915 54.2 - - 

 Benzo[b]fluoranthene 1 263780 - n 19:45 3468.16 0 160.11 - Y y n EG141116MB 131890 17130 763 22.4 - - 

 Benzo[k]fluoranthene 1 117420 - n 19:47 1472.94 0 169.658 - Y y n EG141116MB 58708 9898 763 13 - - 

 Benzo[e]pyrene 1 217360 - n 20:14 1143.18 0 41.8169 - Y y n EG141116MB 108680 13108 763 17.2 - -  Benzo[a]pyrene 1 29160 - n 20:23 159.518 0 43.4937 - Y y n EG141116MB 14580 2627.4 763 3.4 - - 

 Perylene 1 10067 - n 20:31 31.5096 0 39.9405 - Y y n EG141116MB 5033.3 1292.3 763 1.7 - - 

 Indeno[1,2,3-cd]pyrene 1 23916 - n 22:24 706.507 0 81.2366 - y y n EG141116MB 11958 1534.2 149 10.3 - - 

 Dibenzo[a,h]anthracene 1 3051.7 - n 22:29 124.144 0 137.922 - Y y n EG141118MB 1525.9 368.83 203 1.8 - - 

 Benzo[g,h,i]perylene 1 44635 - n 22:48 868.149 0 48.1411 - y y n EG141116MB 22318 2491.3 149 16.8 - - 

 Fluorene-d10 1 148170 - n 11:14 1125.65 0 0 112.6 n n 74085 12546 0 Div0 - - 

 p-Terphenyl-d14 1 152160 - n 15:34 852.469 0 0 85.2 n n 76078 9237.4 0 Div0 - - 

 Naphthalene-d8 1 435450 - n 7:31 19.0256 0 0 1.9 n n 217730 42338 0 Div0 - - 

 2-Me-Naphthalene-d10 1 145920 - n 8:40 17.4499 0 0 1.7 n n 72958 13979 0 Div0 - - 

 Acenaphthylene-d8 1 341970 - n 10:08 17.3897 0 0 1.7 n n 170980 36356 0 Div0 - - 

 Phenanthrene-d10 1 486230 - n 12:48 15.367 0 0 1.5 n n 243120 39997 0 Div0 - - 

 Anthracene-d10 1 536420 - n 12:53 16.2384 0 0 1.6 n n 268210 30409 0 Div0 - - 

 Fluoranthene-d10 1 302710 - n 14:44 17.4776 0 0 1.7 n n 151360 26053 0 Div0 - - 

 Benz[a]anthracene-d12 1 126290 - n 17:30 7.28991 0 0 0.7 n n 63145 10317 0 Div0 - - 

 Chrysene-d12 1 126290 - n 17:30 4.39788 0 0 0.4 n n 63145 10317 0 Div0 - - 

 Benzo[b]fluoranthene-d12 1 65277 - n 19:41 11.1477 0 0 1.1 n n 32638 5114 0 Div0 - - 

 Benzo[k]fluoranthene-d12 1 76720 - n 19:45 8.51768 0 0 0.9 n n 38360 5412 0 Div0 - - 

 Benzo[a]pyrene-d12 1 150810 - n 20:21 22.2221 0 0 2.2 n n 75404 18096 0 Div0 - - 

 Perylene-d12 1 202600 - n 20:27 30.2124 0 0 3 n n 101300 15148 0 Div0 - - 

 Indeno[1,2,3-cd]pyrene-d12 1 33982 - n 22:22 7.49645 0 0 0.7 y n 16991 2296.1 0 Div0 - - 

 Dibenzo[a,h]anthracene-d14 1 15613 - n 22:27 4.9292 0 0 0.5 y n 7806.6 1171.4 0 Div0 - - 

 Benzo[g,h,i]perylene-d12 1 42011 - n 22:45 8.39874 0 0 0.8 y n 21005 3153.8 0 Div0 - - 

 Acenaphthene-d10 1 12945000 - n 10:23 115.512 0 - - n n 6472700 1511700 0 Div0 - - 

 Pyrene-d10 1 19641000 - n 15:07 118.891 0 - - n n 9820700 1699800 0 Div0 - - 

 Benzo[e]pyrene-d12 1 8507000 - n 20:11 42.9231 0 - - n n 4253500 584700 0 Div0 - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 2



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including:

for Multi-Point Calibration(s)

- Multi-Point Calibration Tables

- Individual Quantitation Reports

for Continuing Calibration(s)

- Multi-Point Calibration Tables

- Individual Quantitation Reports

SVOC DATA PACKAGE

SECTION 4: CALIBRATION DATA

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 43 of 84
Cal Level Filename Run Date

CS1 4-141115A03

CS2 4-141115A04

CS3 4-141115A05

CS4 4-141115A06 Approved:

CS5 4-141115A07 --e-signature--

CS6 4-141115A08

Target Analytes CS1 CS2 CS3 CS4 CS5 CS6 Mean %RSD

 Naphthalene 1.44 1.20 1.14 1.24 1.21 1.43 1.28 10%

 2-Me-Naphthalene 1.57 1.52 1.45 1.43 1.44 1.73 1.52 7%

 1-Me-Naphthalene 1.52 1.42 1.39 1.42 1.36 1.65 1.46 7%

 Acenaphthylene 1.42 1.35 1.31 1.36 1.41 1.85 1.45 14%

 Acenaphthene 0.69 0.70 0.68 0.69 0.69 0.83 0.71 8%

 Fluorene 0.40 0.36 0.38 0.38 0.36 0.44 0.39 8%

 Phenanthrene 1.08 1.00 1.02 1.04 1.16 1.25 1.09 9%

 Anthracene 1.12 1.05 1.09 1.10 1.18 1.26 1.13 7%

 Fluoranthene 1.35 1.36 1.31 1.39 1.51 2.04 1.49 18%

 Pyrene 1.46 1.42 1.44 1.44 1.67 2.17 1.60 18%

 Benz[a]anthracene 1.07 1.10 1.17 1.16 1.29 1.93 1.29 25%

 Chrysene/Triphenylene 1.07 1.10 1.02 1.01 1.13 1.38 1.12 12%

 Benzo[b]fluoranthene 1.08 1.09 1.19 1.16 1.31 * 1.17 8%

 Benzo[k]fluoranthene 1.05 1.06 0.99 1.02 1.08 * 1.04 3%

 Benzo[e]pyrene 1.22 1.15 1.16 1.17 1.22 1.64 1.26 15%

 Benzo[a]pyrene 1.15 1.12 1.10 1.12 1.17 1.62 1.21 17%

 Perylene 1.34 1.43 1.41 1.60 1.61 2.08 1.58 17%

 Indeno[1,2,3-cd]pyrene 0.95 0.93 0.92 0.86 0.97 1.35 1.00 18%

 Dibenzo[a,h]anthracene 1.45 1.63 1.54 1.63 1.63 * 1.57 5%

 Benzo[g,h,i]perylene 1.14 1.13 1.14 1.12 1.21 1.61 1.22 16%

Labeled Field Spike Standards

 Fluorene-d10 0.29 0.24 0.28 0.28 0.27 0.26 0.27 6%

 p-Terphenyl-d14 0.60 0.53 0.58 0.61 0.61 0.61 0.59 5%

Labeled Extraction Standards

 Naphthalene-d8 1.70 1.82 1.77 1.72 1.78 1.82 1.76 3%

 2-Me-Naphthalene-d10 0.63 0.66 0.65 0.64 0.65 0.65 0.65 2%

 Acenaphthylene-d8 1.47 1.52 1.51 1.49 1.53 1.60 1.50 3%

 Phenanthrene-d10 2.24 2.53 2.33 2.46 2.49 2.61 2.41 6%

 Anthracene-d10 2.38 2.66 2.41 2.50 2.60 2.76 2.51 6%

 Fluoranthene-d10 0.89 0.90 0.87 0.90 0.85 0.88 0.88 2%

 Benz[a]anthracene-d12 0.86 0.92 0.79 0.81 0.90 1.00 0.86 9%

 Chrysene-d12 1.38 1.43 1.35 1.37 1.53 1.71 1.41 9%

 Benzo[b]fluoranthene-d12 0.69 0.71 0.66 0.71 0.67 0.69 0.69 3%

 Benzo[k]fluoranthene-d12 0.93 0.99 1.00 1.12 1.09 1.23 1.02 10%

 Benzo[a]pyrene-d12 0.73 0.77 0.78 0.76 0.84 0.92 0.77 9%

 Perylene-d12 0.75 0.77 0.76 0.79 0.82 0.85 0.78 5%

 Indeno[1,2,3-cd]pyrene-d12 0.53 0.56 0.38 0.35 0.63 0.75 0.49 28%

 Dibenzo[a,h]anthracene-d14 0.37 0.42 0.28 0.27 0.52 * 0.37 28%

 Benzo[g,h,i]perylene-d12 0.60 0.66 0.41 0.39 0.68 0.79 0.55 27%

ALS Environmental

Calibration Summary Report

15-Nov-2014 13:53

15-Nov-2014 14:27

15-Nov-2014 15:01

15-Nov-2014 15:35 Ella Gdyczynski

15-Nov-2014 16:10

15-Nov-2014 16:44 17-Nov-2014

Relative Response Factors

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 44 of 84
ALS Sample ID H4-14-CS#1-0112

Analysis Method CARB 429 Modified

Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski

Run Data 4-141115A03 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF

Native Target Analyte Time ng/mL

 Naphthalene 7:36 10 2.81E+06 1.44

 2-Me-Naphthalene 8:44 10 1.13E+06 1.57

 1-Me-Naphthalene 8:53 10 1.10E+06 1.52

 Acenaphthylene 10:10 10 2.39E+06 1.42

 Acenaphthene 10:28 10 1.16E+06 0.69

 Fluorene 11:19 10 1.02E+06 0.40

 Phenanthrene 12:51 10 2.79E+06 1.08

 Anthracene 12:56 10 3.05E+06 1.12

 Fluoranthene 14:48 10 1.96E+06 1.35

 Pyrene 15:11 10 2.11E+06 1.46

 Benz[a]anthracene 17:32 10 1.49E+06 1.07

 Chrysene/Triphenylene 17:37 10 2.40E+06 1.07

 Benzo[b]fluoranthene 19:44 10 1.55E+06 1.08

 Benzo[k]fluoranthene 19:47 10 2.02E+06 1.05

 Benzo[e]pyrene 20:15 10 1.85E+06 1.22

 Benzo[a]pyrene 20:21 10 1.74E+06 1.15

 Perylene 20:30 10 2.09E+06 1.34

 Indeno[1,2,3-cd]pyrene 22:23 10 1.04E+06 0.95

 Dibenzo[a,h]anthracene 22:27 10 1.13E+06 1.45

 Benzo[g,h,i]perylene 22:47 10 1.43E+06 1.14

Labeled Field Spike Standards

 Fluorene-d10 11:16 100 7.45E+06 0.29

 p-Terphenyl-d14 15:35 100 8.69E+06 0.60

Labeled Extraction Standards

 Naphthalene-d8 7:33 100 1.96E+07 1.70

 2-Me-Naphthalene-d10 8:41 100 7.22E+06 0.63

 Acenaphthylene-d8 10:09 100 1.69E+07 1.47

 Phenanthrene-d10 12:49 100 2.58E+07 2.24

 Anthracene-d10 12:54 100 2.74E+07 2.38

 Fluoranthene-d10 14:46 100 1.44E+07 0.89

 Benz[a]anthracene-d12 17:30 100 1.40E+07 0.86

 Chrysene-d12 17:33 100 2.23E+07 1.38

 Benzo[b]fluoranthene-d12 19:41 100 1.44E+07 0.69

 Benzo[k]fluoranthene-d12 19:45 100 1.93E+07 0.93

 Benzo[a]pyrene-d12 20:18 100 1.52E+07 0.73

 Perylene-d12 20:27 100 1.56E+07 0.75

 Indeno[1,2,3-cd]pyrene-d12 22:20 100 1.10E+07 0.53

 Dibenzo[a,h]anthracene-d14 22:23 100 7.81E+06 0.37

 Benzo[g,h,i]perylene-d12 22:44 100 1.25E+07 0.60

ALS Environmental

Calibration Analysis Report

15-Nov-2014 13:53

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 45 of 84
ALS Sample ID H4-14-CS#2-0112

Analysis Method CARB 429 Modified

Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski

Run Data 4-141115A04 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF

Native Target Analyte Time ng/mL

 Naphthalene 7:33 50 1.23E+07 1.20

 2-Me-Naphthalene 8:42 50 5.65E+06 1.52

 1-Me-Naphthalene 8:51 50 5.28E+06 1.42

 Acenaphthylene 10:08 50 1.15E+07 1.35

 Acenaphthene 10:26 50 5.99E+06 0.70

 Fluorene 11:16 50 5.09E+06 0.36

 Phenanthrene 12:49 50 1.42E+07 1.00

 Anthracene 12:54 50 1.56E+07 1.05

 Fluoranthene 14:46 50 1.02E+07 1.36

 Pyrene 15:09 50 1.06E+07 1.42

 Benz[a]anthracene 17:30 50 8.47E+06 1.10

 Chrysene/Triphenylene 17:35 50 1.31E+07 1.10

 Benzo[b]fluoranthene 19:42 50 8.30E+06 1.09

 Benzo[k]fluoranthene 19:45 50 1.12E+07 1.06

 Benzo[e]pyrene 20:13 50 9.46E+06 1.15

 Benzo[a]pyrene 20:19 50 9.21E+06 1.12

 Perylene 20:29 50 1.19E+07 1.43

 Indeno[1,2,3-cd]pyrene 22:21 50 5.57E+06 0.93

 Dibenzo[a,h]anthracene 22:25 50 7.43E+06 1.63

 Benzo[g,h,i]perylene 22:45 50 7.99E+06 1.13

Labeled Field Spike Standards

 Fluorene-d10 11:13 100 6.92E+06 0.24

 p-Terphenyl-d14 15:33 100 7.95E+06 0.53

Labeled Extraction Standards

 Naphthalene-d8 7:31 100 2.05E+07 1.82

 2-Me-Naphthalene-d10 8:39 100 7.44E+06 0.66

 Acenaphthylene-d8 10:07 100 1.70E+07 1.52

 Phenanthrene-d10 12:47 100 2.84E+07 2.53

 Anthracene-d10 12:52 100 2.98E+07 2.66

 Fluoranthene-d10 14:44 100 1.50E+07 0.90

 Benz[a]anthracene-d12 17:28 100 1.54E+07 0.92

 Chrysene-d12 17:31 100 2.39E+07 1.43

 Benzo[b]fluoranthene-d12 19:39 100 1.53E+07 0.71

 Benzo[k]fluoranthene-d12 19:43 100 2.13E+07 0.99

 Benzo[a]pyrene-d12 20:16 100 1.65E+07 0.77

 Perylene-d12 20:26 100 1.66E+07 0.77

 Indeno[1,2,3-cd]pyrene-d12 22:18 100 1.20E+07 0.56

 Dibenzo[a,h]anthracene-d14 22:22 100 9.12E+06 0.42

 Benzo[g,h,i]perylene-d12 22:43 100 1.41E+07 0.66

ALS Environmental

Calibration Analysis Report

15-Nov-2014 14:27

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 46 of 84
ALS Sample ID H4-14-CS#3-0112

Analysis Method CARB 429 Modified

Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski

Run Data 4-141115A05 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF

Native Target Analyte Time ng/mL

 Naphthalene 7:33 100 2.24E+07 1.14

 2-Me-Naphthalene 8:42 100 1.04E+07 1.45

 1-Me-Naphthalene 8:51 100 1.00E+07 1.39

 Acenaphthylene 10:08 100 2.19E+07 1.31

 Acenaphthene 10:26 100 1.13E+07 0.68

 Fluorene 11:17 100 9.85E+06 0.38

 Phenanthrene 12:49 100 2.64E+07 1.02

 Anthracene 12:54 100 2.91E+07 1.09

 Fluoranthene 14:46 100 1.87E+07 1.31

 Pyrene 15:09 100 2.07E+07 1.44

 Benz[a]anthracene 17:31 100 1.52E+07 1.17

 Chrysene/Triphenylene 17:35 100 2.27E+07 1.02

 Benzo[b]fluoranthene 19:42 100 1.49E+07 1.19

 Benzo[k]fluoranthene 19:45 100 1.88E+07 0.99

 Benzo[e]pyrene 20:13 100 1.70E+07 1.16

 Benzo[a]pyrene 20:19 100 1.62E+07 1.10

 Perylene 20:28 100 2.03E+07 1.41

 Indeno[1,2,3-cd]pyrene 22:21 100 6.61E+06 0.92

 Dibenzo[a,h]anthracene 22:25 100 8.10E+06 1.54

 Benzo[g,h,i]perylene 22:45 100 8.87E+06 1.14

Labeled Field Spike Standards

 Fluorene-d10 11:14 100 7.25E+06 0.28

 p-Terphenyl-d14 15:33 100 8.24E+06 0.58

Labeled Extraction Standards

 Naphthalene-d8 7:31 100 1.96E+07 1.77

 2-Me-Naphthalene-d10 8:39 100 7.18E+06 0.65

 Acenaphthylene-d8 10:07 100 1.67E+07 1.51

 Phenanthrene-d10 12:47 100 2.58E+07 2.33

 Anthracene-d10 12:52 100 2.67E+07 2.41

 Fluoranthene-d10 14:44 100 1.43E+07 0.87

 Benz[a]anthracene-d12 17:28 100 1.29E+07 0.79

 Chrysene-d12 17:32 100 2.22E+07 1.35

 Benzo[b]fluoranthene-d12 19:39 100 1.25E+07 0.66

 Benzo[k]fluoranthene-d12 19:43 100 1.90E+07 1.00

 Benzo[a]pyrene-d12 20:16 100 1.47E+07 0.78

 Perylene-d12 20:25 100 1.44E+07 0.76

 Indeno[1,2,3-cd]pyrene-d12 22:18 100 7.20E+06 0.38

 Dibenzo[a,h]anthracene-d14 22:22 100 5.27E+06 0.28

 Benzo[g,h,i]perylene-d12 22:43 100 7.81E+06 0.41

ALS Environmental

Calibration Analysis Report

15-Nov-2014 15:01

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 47 of 84
ALS Sample ID H4-14-CS#4-0112

Analysis Method CARB 429 Modified

Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski

Run Data 4-141115A06 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF

Native Target Analyte Time ng/mL

 Naphthalene 7:33 200 4.76E+07 1.24

 2-Me-Naphthalene 8:42 200 2.03E+07 1.43

 1-Me-Naphthalene 8:51 200 2.02E+07 1.42

 Acenaphthylene 10:08 200 4.50E+07 1.36

 Acenaphthene 10:25 200 2.29E+07 0.69

 Fluorene 11:16 200 2.08E+07 0.38

 Phenanthrene 12:48 200 5.73E+07 1.04

 Anthracene 12:53 200 6.17E+07 1.10

 Fluoranthene 14:46 200 3.94E+07 1.39

 Pyrene 15:08 200 4.09E+07 1.44

 Benz[a]anthracene 17:30 200 2.97E+07 1.16

 Chrysene/Triphenylene 17:35 200 4.34E+07 1.01

 Benzo[b]fluoranthene 19:42 200 1.89E+07 1.16

 Benzo[k]fluoranthene 19:45 200 2.60E+07 1.02

 Benzo[e]pyrene 20:12 200 2.02E+07 1.17

 Benzo[a]pyrene 20:18 200 1.92E+07 1.12

 Perylene 20:28 200 2.85E+07 1.60

 Indeno[1,2,3-cd]pyrene 22:20 200 6.91E+06 0.86

 Dibenzo[a,h]anthracene 22:25 200 9.95E+06 1.63

 Benzo[g,h,i]perylene 22:45 200 9.96E+06 1.12

Labeled Field Spike Standards

 Fluorene-d10 11:13 100 7.62E+06 0.28

 p-Terphenyl-d14 15:33 100 8.63E+06 0.61

Labeled Extraction Standards

 Naphthalene-d8 7:31 100 1.91E+07 1.72

 2-Me-Naphthalene-d10 8:39 100 7.10E+06 0.64

 Acenaphthylene-d8 10:07 100 1.66E+07 1.49

 Phenanthrene-d10 12:46 100 2.74E+07 2.46

 Anthracene-d10 12:52 100 2.79E+07 2.50

 Fluoranthene-d10 14:44 100 1.42E+07 0.90

 Benz[a]anthracene-d12 17:28 100 1.28E+07 0.81

 Chrysene-d12 17:31 100 2.16E+07 1.37

 Benzo[b]fluoranthene-d12 19:39 100 8.12E+06 0.71

 Benzo[k]fluoranthene-d12 19:43 100 1.27E+07 1.12

 Benzo[a]pyrene-d12 20:16 100 8.61E+06 0.76

 Perylene-d12 20:25 100 8.93E+06 0.79

 Indeno[1,2,3-cd]pyrene-d12 22:18 100 4.02E+06 0.35

 Dibenzo[a,h]anthracene-d14 22:21 100 3.04E+06 0.27

 Benzo[g,h,i]perylene-d12 22:43 100 4.45E+06 0.39

ALS Environmental

Calibration Analysis Report

15-Nov-2014 15:35

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 48 of 84
ALS Sample ID H4-14-CS#5-0112

Analysis Method CARB 429 Modified

Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski

Run Data 4-141115A07 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF

Native Target Analyte Time ng/mL

 Naphthalene 7:33 500 1.19E+08 1.21

 2-Me-Naphthalene 8:42 500 5.19E+07 1.44

 1-Me-Naphthalene 8:51 500 4.91E+07 1.36

 Acenaphthylene 10:08 500 1.19E+08 1.41

 Acenaphthene 10:26 500 5.85E+07 0.69

 Fluorene 11:17 500 5.01E+07 0.36

 Phenanthrene 12:49 500 1.60E+08 1.16

 Anthracene 12:54 500 1.70E+08 1.18

 Fluoranthene 14:46 500 1.09E+08 1.51

 Pyrene 15:08 500 1.21E+08 1.67

 Benz[a]anthracene 17:31 500 9.92E+07 1.29

 Chrysene/Triphenylene 17:35 500 1.48E+08 1.13

 Benzo[b]fluoranthene 19:42 500 1.02E+08 1.31

 Benzo[k]fluoranthene 19:45 500 1.37E+08 1.08

 Benzo[e]pyrene 20:13 500 1.20E+08 1.22

 Benzo[a]pyrene 20:19 500 1.15E+08 1.17

 Perylene 20:28 500 1.54E+08 1.61

 Indeno[1,2,3-cd]pyrene 22:20 500 7.15E+07 0.97

 Dibenzo[a,h]anthracene 22:24 500 9.84E+07 1.63

 Benzo[g,h,i]perylene 22:45 500 9.58E+07 1.21

Labeled Field Spike Standards

 Fluorene-d10 11:14 100 7.37E+06 0.27

 p-Terphenyl-d14 15:33 100 8.86E+06 0.61

Labeled Extraction Standards

 Naphthalene-d8 7:31 100 1.96E+07 1.78

 2-Me-Naphthalene-d10 8:39 100 7.21E+06 0.65

 Acenaphthylene-d8 10:07 100 1.69E+07 1.53

 Phenanthrene-d10 12:47 100 2.75E+07 2.49

 Anthracene-d10 12:52 100 2.87E+07 2.60

 Fluoranthene-d10 14:44 100 1.44E+07 0.85

 Benz[a]anthracene-d12 17:28 100 1.54E+07 0.90

 Chrysene-d12 17:32 100 2.61E+07 1.53

 Benzo[b]fluoranthene-d12 19:39 100 1.56E+07 0.67

 Benzo[k]fluoranthene-d12 19:43 100 2.54E+07 1.09

 Benzo[a]pyrene-d12 20:16 100 1.97E+07 0.84

 Perylene-d12 20:25 100 1.91E+07 0.82

 Indeno[1,2,3-cd]pyrene-d12 22:18 100 1.48E+07 0.63

 Dibenzo[a,h]anthracene-d14 22:21 100 1.21E+07 0.52

 Benzo[g,h,i]perylene-d12 22:42 100 1.59E+07 0.68

ALS Environmental

Calibration Analysis Report

15-Nov-2014 16:10

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 49 of 84
ALS Sample ID H4-14-CS#6-0112

Analysis Method CARB 429 Modified

Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski

Run Data 4-141115A08 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF

Native Target Analyte Time ng/mL

 Naphthalene 7:33 2000 5.85E+08 1.43

 2-Me-Naphthalene 8:42 2000 2.52E+08 1.73

 1-Me-Naphthalene 8:51 2000 2.40E+08 1.65

 Acenaphthylene 10:08 2000 6.67E+08 1.85

 Acenaphthene 10:26 2000 2.99E+08 0.83

 Fluorene 11:17 2000 2.59E+08 0.44

 Phenanthrene 12:49 2000 7.34E+08 1.25

 Anthracene 12:54 2000 7.83E+08 1.26

 Fluoranthene 14:46 2000 6.13E+08 2.04

 Pyrene 15:08 2000 6.52E+08 2.17

 Benz[a]anthracene 17:31 2000 6.61E+08 1.93

 Chrysene/Triphenylene 17:34 2000 8.02E+08 1.38

 Benzo[b]fluoranthene NotFnd 2000 * * 

 Benzo[k]fluoranthene NotFnd 2000 * * 

 Benzo[e]pyrene 20:13 2000 6.89E+08 1.64

 Benzo[a]pyrene 20:19 2000 6.78E+08 1.62

 Perylene 20:29 2000 8.03E+08 2.08

 Indeno[1,2,3-cd]pyrene 22:20 2000 4.62E+08 1.35

 Dibenzo[a,h]anthracene 22:24 2000 5.71E+08 * 

 Benzo[g,h,i]perylene 22:45 2000 5.81E+08 1.61

Labeled Field Spike Standards

 Fluorene-d10 11:14 100 7.79E+06 0.26

 p-Terphenyl-d14 15:33 100 9.13E+06 0.61

Labeled Extraction Standards

 Naphthalene-d8 7:31 100 2.05E+07 1.82

 2-Me-Naphthalene-d10 8:39 100 7.28E+06 0.65

 Acenaphthylene-d8 10:07 100 1.81E+07 1.60

 Phenanthrene-d10 12:47 100 2.94E+07 2.61

 Anthracene-d10 12:52 100 3.10E+07 2.76

 Fluoranthene-d10 14:44 100 1.50E+07 0.88

 Benz[a]anthracene-d12 17:28 100 1.71E+07 1.00

 Chrysene-d12 17:32 100 2.92E+07 1.71

 Benzo[b]fluoranthene-d12 19:40 100 1.57E+07 0.69

 Benzo[k]fluoranthene-d12 19:43 100 2.82E+07 1.23

 Benzo[a]pyrene-d12 20:16 100 2.10E+07 0.92

 Perylene-d12 20:26 100 1.93E+07 0.85

 Indeno[1,2,3-cd]pyrene-d12 22:18 100 1.71E+07 0.75

 Dibenzo[a,h]anthracene-d14 NotFnd 100 * * 

 Benzo[g,h,i]perylene-d12 22:43 100 1.81E+07 0.79

ALS Environmental

Calibration Analysis Report

15-Nov-2014 16:44

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 50 of 84
Calibration Report OPUS v3.6

 Sample ID H4-14-CS#1-0112 

 Comments C429ALS-CS#1-016

 Sample size 1

 Filename 4-141115A03

 Acquired 15-Nov-2014 13:53

 Processed 15-Nov-2014 21:07

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429ALSK

 Cal level 10

 Target Analyte Conc Resp RA RT RRF Mean RR M? P1? P2? Coding Comments

 Naphthalene 10 2810000 - n 7:36 1.4359 1.278 y y n 

 2-Me-Naphthalene 10 1132400 - n 8:44 1.5678 1.5231 n n n 

 1-Me-Naphthalene 10 1096400 - n 8:53 1.518 1.4594 n n n 

 Acenaphthylene 10 2394500 - n 10:10 1.4207 1.4498 n n n 

 Acenaphthene 10 1158000 - n 10:28 0.6871 0.713 n n n 

 Fluorene 10 1021500 - n 11:19 0.3966 0.3868 n n n 

 Phenanthrene 10 2789600 - n 12:51 1.0832 1.0937 n n n 

 Anthracene 10 3052000 - n 12:56 1.1155 1.133 n n n 

 Fluoranthene 10 1955000 - n 14:48 1.354 1.4922 n n n 

 Pyrene 10 2109600 - n 15:11 1.4611 1.6007 n n n 

 Benz[a]anthracene 10 1493000 - n 17:32 1.0688 1.2872 n n n 

 Chrysene/Triphenylene 10 2395500 - n 17:37 1.0726 1.1186 n n n 

 Benzo[b]fluoranthene 10 1553300 - n 19:44 1.0758 1.1652 n n n 

 Benzo[k]fluoranthene 10 2021900 - n 19:47 1.0452 1.039 n n n 

 Benzo[e]pyrene 10 1851800 - n 20:15 1.221 1.2608 n n n 

 Benzo[a]pyrene 10 1743400 - n 20:21 1.1495 1.2122 n n n 

 Perylene 10 2090800 - n 20:30 1.3408 1.5769 n n n 

 Indeno[1,2,3-cd]pyrene 10 1043600 - n 22:23 0.9476 0.9962 n n n 

 Dibenzo[a,h]anthracene 10 1128300 - n 22:27 1.4453 1.5744 n n n 

 Benzo[g,h,i]perylene 10 1426100 - n 22:47 1.142 1.2238 n n n 

 Fluorene-d10 100 7445400 - n 11:16 0.2891 0.2707 n n n 

 p-Terphenyl-d14 100 8685800 - n 15:35 0.6016 0.5896 n n n 

 Naphthalene-d8 100 19570000 - n 7:33 1.703 1.768 n n n 

 2-Me-Naphthalene-d10 100 7222600 - n 8:41 0.6285 0.6459 n n n 

 Acenaphthylene-d8 100 16854000 - n 10:09 1.4667 1.5191 n n n 

 Phenanthrene-d10 100 25755000 - n 12:49 2.2413 2.4442 n n n 

 Anthracene-d10 100 27360000 - n 12:54 2.381 2.5518 n n n 

 Fluoranthene-d10 100 14438000 - n 14:46 0.8919 0.8818 n n n 

 Benz[a]anthracene-d12 100 13969000 - n 17:30 0.8629 0.882 n n n 

 Chrysene-d12 100 22334000 - n 17:33 1.3797 1.462 n n n 

 Benzo[b]fluoranthene-d12 100 14439000 - n 19:41 0.6906 0.6883 n n n 

 Benzo[k]fluoranthene-d12 100 19344000 - n 19:45 0.9252 1.0588 n n n 

 Benzo[a]pyrene-d12 100 15167000 - n 20:18 0.7254 0.7977 n n n 

 Perylene-d12 100 15593000 - n 20:27 0.7458 0.7883 n n n 

 Indeno[1,2,3-cd]pyrene-d12 100 11013000 - n 22:20 0.5268 0.5329 n n n 

 Dibenzo[a,h]anthracene-d14 100 7807200 - n 22:23 0.3734 0.3723 n n n 

 Benzo[g,h,i]perylene-d12 100 12488000 - n 22:44 0.5973 0.588 n n n 

 Acenaphthene-d10 100 11491000 - n 10:25 - - n n n 

 Pyrene-d10 100 16188000 - n 15:09 - - n n n 

 Benzo[e]pyrene-d12 100 20908000 - n 20:12 - - n n n 

 F1 Lock Mass 0 * NotFnd - - n n 

 F2 Lock Mass 0 * NotFnd - - n n 

 F3 Lock Mass 0 * NotFnd - - n n 

 F4 Lock Mass 0 * NotFnd - - n n 

 F5 Lock Mass 0 * NotFnd - - n n 

 F6 Lock Mass 0 * NotFnd - - n n 

 DUMMY LINE 0 * NotFnd - - n n 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 51 of 84
Calibration Report OPUS v3.6

 Sample ID H4-14-CS#2-0112 

 Comments C429ALS-CS#2-016

 Sample size 1

 Filename 4-141115A04

 Acquired 15-Nov-2014 14:27

 Processed 15-Nov-2014 21:08

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429ALSK

 Cal level 50

 Target Analyte Conc Resp RA RT RRF Mean RR M? P1? P2? Coding Comments

 Naphthalene 50 12289000 - n 7:33 1.201 1.278 n n n 

 2-Me-Naphthalene 50 5646000 - n 8:42 1.5184 1.5231 n n n 

 1-Me-Naphthalene 50 5281900 - n 8:51 1.4205 1.4594 n n n 

 Acenaphthylene 50 11529000 - n 10:08 1.3547 1.4498 n n n 

 Acenaphthene 50 5990100 - n 10:26 0.7039 0.713 n n n 

 Fluorene 50 5088100 - n 11:16 0.3587 0.3868 n n n 

 Phenanthrene 50 14222000 - n 12:49 1.0025 1.0937 n n n 

 Anthracene 50 15619000 - n 12:54 1.0472 1.133 n n n 

 Fluoranthene 50 10175000 - n 14:46 1.3593 1.4922 n n n 

 Pyrene 50 10642000 - n 15:09 1.4217 1.6007 n n n 

 Benz[a]anthracene 50 8468300 - n 17:30 1.1027 1.2872 n n n 

 Chrysene/Triphenylene 50 13147000 - n 17:35 1.0996 1.1186 n n n 

 Benzo[b]fluoranthene 50 8303300 - n 19:42 1.0863 1.1652 n n n 

 Benzo[k]fluoranthene 50 11229000 - n 19:45 1.0565 1.039 n n n 

 Benzo[e]pyrene 50 9458300 - n 20:13 1.1475 1.2608 n n n 

 Benzo[a]pyrene 50 9207800 - n 20:19 1.1171 1.2122 n n n 

 Perylene 50 11861000 - n 20:29 1.4253 1.5769 n n n 

 Indeno[1,2,3-cd]pyrene 50 5567800 - n 22:21 0.9304 0.9962 n n n 

 Dibenzo[a,h]anthracene 50 7430300 - n 22:25 1.6291 1.5744 n n n 

 Benzo[g,h,i]perylene 50 7994100 - n 22:45 1.1338 1.2238 n n n 

 Fluorene-d10 100 6920500 - n 11:13 0.2439 0.2707 n n n 

 p-Terphenyl-d14 100 7953900 - n 15:33 0.5313 0.5896 n n n 

 Naphthalene-d8 100 20465000 - n 7:31 1.8244 1.768 n n n 

 2-Me-Naphthalene-d10 100 7436900 - n 8:39 0.663 0.6459 n n n 

 Acenaphthylene-d8 100 17020000 - n 10:07 1.5173 1.5191 n n n 

 Phenanthrene-d10 100 28373000 - n 12:47 2.5294 2.4442 n n n 

 Anthracene-d10 100 29830000 - n 12:52 2.6593 2.5518 n n n 

 Fluoranthene-d10 100 14971000 - n 14:44 0.8962 0.8818 n n n 

 Benz[a]anthracene-d12 100 15360000 - n 17:28 0.9195 0.882 n n n 

 Chrysene-d12 100 23914000 - n 17:31 1.4316 1.462 n n n 

 Benzo[b]fluoranthene-d12 100 15288000 - n 19:39 0.7107 0.6883 n n n 

 Benzo[k]fluoranthene-d12 100 21258000 - n 19:43 0.9882 1.0588 n n n 

 Benzo[a]pyrene-d12 100 16485000 - n 20:16 0.7664 0.7977 n n n 

 Perylene-d12 100 16644000 - n 20:26 0.7737 0.7883 n n n 

 Indeno[1,2,3-cd]pyrene-d12 100 11969000 - n 22:18 0.5564 0.5329 n n n 

 Dibenzo[a,h]anthracene-d14 100 9122200 - n 22:22 0.4241 0.3723 n n n 

 Benzo[g,h,i]perylene-d12 100 14102000 - n 22:43 0.6556 0.588 n n n 

 Acenaphthene-d10 100 11217000 - n 10:23 - - n n n 

 Pyrene-d10 100 16704000 - n 15:07 - - n n n 

 Benzo[e]pyrene-d12 100 21511000 - n 20:10 - - n n n 

 F1 Lock Mass 0 * NotFnd - - n n 

 F2 Lock Mass 0 * NotFnd - - n n 

 F3 Lock Mass 0 * NotFnd - - n n 

 F4 Lock Mass 0 * NotFnd - - n n 

 F5 Lock Mass 0 * NotFnd - - n n 

 F6 Lock Mass 0 * NotFnd - - n n 

 DUMMY LINE 0 * NotFnd - - n n 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 52 of 84
Calibration Report OPUS v3.6

 Sample ID H4-14-CS#3-0112 

 Comments C429ALS-CS#3-016

 Sample size 1

 Filename 4-141115A05

 Acquired 15-Nov-2014 15:01

 Processed 15-Nov-2014 21:08

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429ALSK

 Cal level 100

 Target Analyte Conc Resp RA RT RRF Mean RR M? P1? P2? Coding Comments

 Naphthalene 100 22449000 - n 7:33 1.1439 1.278 n n n 

 2-Me-Naphthalene 100 10432000 - n 8:42 1.4528 1.5231 n n n 

 1-Me-Naphthalene 100 9995300 - n 8:51 1.392 1.4594 n n n 

 Acenaphthylene 100 21854000 - n 10:08 1.3085 1.4498 n n n 

 Acenaphthene 100 11300000 - n 10:26 0.6766 0.713 n n n 

 Fluorene 100 9853500 - n 11:17 0.3812 0.3868 n n n 

 Phenanthrene 100 26438000 - n 12:49 1.0228 1.0937 n n n 

 Anthracene 100 29054000 - n 12:54 1.0869 1.133 n n n 

 Fluoranthene 100 18659000 - n 14:46 1.3053 1.4922 n n n 

 Pyrene 100 20652000 - n 15:09 1.4448 1.6007 n n n 

 Benz[a]anthracene 100 15195000 - n 17:31 1.1742 1.2872 n n n 

 Chrysene/Triphenylene 100 22652000 - n 17:35 1.0219 1.1186 n n n 

 Benzo[b]fluoranthene 100 14910000 - n 19:42 1.1931 1.1652 n n n 

 Benzo[k]fluoranthene 100 18803000 - n 19:45 0.9905 1.039 n n n 

 Benzo[e]pyrene 100 17022000 - n 20:13 1.1576 1.2608 n n n 

 Benzo[a]pyrene 100 16195000 - n 20:19 1.1014 1.2122 n n n 

 Perylene 100 20270000 - n 20:28 1.4106 1.5769 n n n 

 Indeno[1,2,3-cd]pyrene 100 6610000 - n 22:21 0.9182 0.9962 n n n 

 Dibenzo[a,h]anthracene 100 8103400 - n 22:25 1.5376 1.5744 n n n 

 Benzo[g,h,i]perylene 100 8869500 - n 22:45 1.1353 1.2238 n n n 

 Fluorene-d10 100 7248800 - n 11:14 0.2804 0.2707 n n n 

 p-Terphenyl-d14 100 8238500 - n 15:33 0.5764 0.5896 n n n 

 Naphthalene-d8 100 19625000 - n 7:31 1.7707 1.768 n n n 

 2-Me-Naphthalene-d10 100 7180600 - n 8:39 0.6479 0.6459 n n n 

 Acenaphthylene-d8 100 16702000 - n 10:07 1.5069 1.5191 n n n 

 Phenanthrene-d10 100 25849000 - n 12:47 2.3322 2.4442 n n n 

 Anthracene-d10 100 26731000 - n 12:52 2.4118 2.5518 n n n 

 Fluoranthene-d10 100 14294000 - n 14:44 0.8731 0.8818 n n n 

 Benz[a]anthracene-d12 100 12942000 - n 17:28 0.7905 0.882 n n n 

 Chrysene-d12 100 22166000 - n 17:32 1.3539 1.462 n n n 

 Benzo[b]fluoranthene-d12 100 12498000 - n 19:39 0.659 0.6883 n n n 

 Benzo[k]fluoranthene-d12 100 18983000 - n 19:43 1.001 1.0588 n n n 

 Benzo[a]pyrene-d12 100 14705000 - n 20:16 0.7754 0.7977 n n n 

 Perylene-d12 100 14370000 - n 20:25 0.7578 0.7883 n n n 

 Indeno[1,2,3-cd]pyrene-d12 100 7198700 - n 22:18 0.3796 0.5329 y y n 

 Dibenzo[a,h]anthracene-d14 100 5270100 - n 22:22 0.2779 0.3723 n n n 

 Benzo[g,h,i]perylene-d12 100 7812400 - n 22:43 0.412 0.588 n n n 

 Acenaphthene-d10 100 11084000 - n 10:23 - - n n n 

 Pyrene-d10 100 16372000 - n 15:07 - - n n n 

 Benzo[e]pyrene-d12 100 18964000 - n 20:10 - - n n n 

 F1 Lock Mass 0 * NotFnd - - n n 

 F2 Lock Mass 0 * NotFnd - - n n 

 F3 Lock Mass 0 * NotFnd - - n n 

 F4 Lock Mass 0 * NotFnd - - n n 

 F5 Lock Mass 0 * NotFnd - - n n 

 F6 Lock Mass 0 * NotFnd - - n n 

 DUMMY LINE 0 * NotFnd - - n n 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 53 of 84
Calibration Report OPUS v3.6

 Sample ID H4-14-CS#4-0112 

 Comments C429ALS-CS#4-016

 Sample size 1

 Filename 4-141115A06

 Acquired 15-Nov-2014 15:35

 Processed 15-Nov-2014 21:08

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429ALSK

 Cal level 200

 Target Analyte Conc Resp RA RT RRF Mean RR M? P1? P2? Coding Comments

 Naphthalene 200 47550000 - n 7:33 1.2427 1.278 n n n 

 2-Me-Naphthalene 200 20326000 - n 8:42 1.4313 1.5231 n n n 

 1-Me-Naphthalene 200 20151000 - n 8:51 1.419 1.4594 n n n 

 Acenaphthylene 200 45027000 - n 10:08 1.3592 1.4498 n n n 

 Acenaphthene 200 22921000 - n 10:25 0.6919 0.713 n n n 

 Fluorene 200 20796000 - n 11:16 0.3792 0.3868 n n n 

 Phenanthrene 200 57272000 - n 12:48 1.0444 1.0937 n n n 

 Anthracene 200 61653000 - n 12:53 1.1039 1.133 n n n 

 Fluoranthene 200 39414000 - n 14:46 1.3872 1.4922 n n n 

 Pyrene 200 40869000 - n 15:08 1.4384 1.6007 n n n 

 Benz[a]anthracene 200 29651000 - n 17:30 1.1557 1.2872 n n n 

 Chrysene/Triphenylene 200 43411000 - n 17:35 1.007 1.1186 n n n 

 Benzo[b]fluoranthene 200 18895000 - n 19:42 1.1631 1.1652 n n n 

 Benzo[k]fluoranthene 200 25996000 - n 19:45 1.0241 1.039 n n n 

 Benzo[e]pyrene 200 20193000 - n 20:12 1.1728 1.2608 n n n 

 Benzo[a]pyrene 200 19215000 - n 20:18 1.116 1.2122 n n n 

 Perylene 200 28501000 - n 20:28 1.5951 1.5769 n n n 

 Indeno[1,2,3-cd]pyrene 200 6906900 - n 22:20 0.8586 0.9962 n n n 

 Dibenzo[a,h]anthracene 200 9950600 - n 22:25 1.634 1.5744 n n n 

 Benzo[g,h,i]perylene 200 9955100 - n 22:45 1.1186 1.2238 n n n 

 Fluorene-d10 100 7622600 - n 11:13 0.278 0.2707 n n n 

 p-Terphenyl-d14 100 8626200 - n 15:33 0.6072 0.5896 n n n 

 Naphthalene-d8 100 19132000 - n 7:31 1.7155 1.768 n n n 

 2-Me-Naphthalene-d10 100 7100600 - n 8:39 0.6367 0.6459 n n n 

 Acenaphthylene-d8 100 16563000 - n 10:07 1.4852 1.5191 n n n 

 Phenanthrene-d10 100 27418000 - n 12:46 2.4585 2.4442 n n n 

 Anthracene-d10 100 27925000 - n 12:52 2.504 2.5518 n n n 

 Fluoranthene-d10 100 14207000 - n 14:44 0.9009 0.8818 n n n 

 Benz[a]anthracene-d12 100 12829000 - n 17:28 0.8135 0.882 n n n 

 Chrysene-d12 100 21556000 - n 17:31 1.367 1.462 n n n 

 Benzo[b]fluoranthene-d12 100 8122300 - n 19:39 0.714 0.6883 n n n 

 Benzo[k]fluoranthene-d12 100 12693000 - n 19:43 1.1157 1.0588 n n n 

 Benzo[a]pyrene-d12 100 8608600 - n 20:16 0.7567 0.7977 n n n 

 Perylene-d12 100 8934000 - n 20:25 0.7853 0.7883 n n n 

 Indeno[1,2,3-cd]pyrene-d12 100 4022400 - n 22:18 0.3536 0.5329 y y n 

 Dibenzo[a,h]anthracene-d14 100 3044900 - n 22:21 0.2677 0.3723 y y n 

 Benzo[g,h,i]perylene-d12 100 4449700 - n 22:43 0.3911 0.588 y y n 

 Acenaphthene-d10 100 11152000 - n 10:23 - - n n n 

 Pyrene-d10 100 15769000 - n 15:06 - - n n n 

 Benzo[e]pyrene-d12 100 11376000 - n 20:09 - - n n n 

 F1 Lock Mass 0 * NotFnd - - n n 

 F2 Lock Mass 0 * NotFnd - - n n 

 F3 Lock Mass 0 * NotFnd - - n n 

 F4 Lock Mass 0 * NotFnd - - n n 

 F5 Lock Mass 0 * NotFnd - - n n 

 F6 Lock Mass 0 * NotFnd - - n n 

 DUMMY LINE 0 * NotFnd - - n n 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 54 of 84
Calibration Report OPUS v3.6

 Sample ID H4-14-CS#5-0112 

 Comments C429ALS-CS#5-016

 Sample size 1

 Filename 4-141115A07

 Acquired 15-Nov-2014 16:10

 Processed 15-Nov-2014 21:08

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429ALSK

 Cal level 500

 Target Analyte Conc Resp RA RT RRF Mean RR M? P1? P2? Coding Comments

 Naphthalene 500 119130000 - n 7:33 1.2146 1.278 n n n 

 2-Me-Naphthalene 500 51894000 - n 8:42 1.4397 1.5231 n n n 

 1-Me-Naphthalene 500 49070000 - n 8:51 1.3613 1.4594 n n n 

 Acenaphthylene 500 119300000 - n 10:08 1.4091 1.4498 n n n 

 Acenaphthene 500 58480000 - n 10:26 0.6907 0.713 n n n 

 Fluorene 500 50117000 - n 11:17 0.3646 0.3868 n n n 

 Phenanthrene 500 159730000 - n 12:49 1.1621 1.0937 n n n 

 Anthracene 500 169750000 - n 12:54 1.184 1.133 n n n 

 Fluoranthene 500 108900000 - n 14:46 1.5105 1.4922 n n n 

 Pyrene 500 120590000 - n 15:08 1.6727 1.6007 n n n 

 Benz[a]anthracene 500 99229000 - n 17:31 1.2903 1.2872 n n n 

 Chrysene/Triphenylene 500 147880000 - n 17:35 1.1347 1.1186 n n n 

 Benzo[b]fluoranthene 500 101730000 - n 19:42 1.3075 1.1652 n n n 

 Benzo[k]fluoranthene 500 136980000 - n 19:45 1.079 1.039 n n n 

 Benzo[e]pyrene 500 120470000 - n 20:13 1.223 1.2608 n n n 

 Benzo[a]pyrene 500 115410000 - n 20:19 1.1716 1.2122 n n n 

 Perylene 500 154300000 - n 20:28 1.6131 1.5769 n n n 

 Indeno[1,2,3-cd]pyrene 500 71541000 - n 22:20 0.9694 0.9962 n n n 

 Dibenzo[a,h]anthracene 500 98421000 - n 22:24 1.6263 1.5744 n n n 

 Benzo[g,h,i]perylene 500 95779000 - n 22:45 1.2067 1.2238 n n n 

 Fluorene-d10 100 7372000 - n 11:14 0.2682 0.2707 n n n 

 p-Terphenyl-d14 100 8864300 - n 15:33 0.6147 0.5896 n n n 

 Naphthalene-d8 100 19617000 - n 7:31 1.7766 1.768 n n n 

 2-Me-Naphthalene-d10 100 7209300 - n 8:39 0.6529 0.6459 n n n 

 Acenaphthylene-d8 100 16933000 - n 10:07 1.5335 1.5191 n n n 

 Phenanthrene-d10 100 27488000 - n 12:47 2.4894 2.4442 n n n 

 Anthracene-d10 100 28673000 - n 12:52 2.5967 2.5518 n n n 

 Fluoranthene-d10 100 14419000 - n 14:44 0.845 0.8818 n n n 

 Benz[a]anthracene-d12 100 15380000 - n 17:28 0.9013 0.882 n n n 

 Chrysene-d12 100 26066000 - n 17:32 1.5275 1.462 n n n 

 Benzo[b]fluoranthene-d12 100 15561000 - n 19:39 0.6668 0.6883 n n n 

 Benzo[k]fluoranthene-d12 100 25391000 - n 19:43 1.0881 1.0588 n n n 

 Benzo[a]pyrene-d12 100 19700000 - n 20:16 0.8442 0.7977 n n n 

 Perylene-d12 100 19130000 - n 20:25 0.8198 0.7883 n n n 

 Indeno[1,2,3-cd]pyrene-d12 100 14760000 - n 22:18 0.6325 0.5329 n n n 

 Dibenzo[a,h]anthracene-d14 100 12104000 - n 22:21 0.5187 0.3723 n n n 

 Benzo[g,h,i]perylene-d12 100 15875000 - n 22:42 0.6803 0.588 n n n 

 Acenaphthene-d10 100 11042000 - n 10:23 - - n n n 

 Pyrene-d10 100 17064000 - n 15:07 - - n n n 

 Benzo[e]pyrene-d12 100 23336000 - n 20:10 - - n n n 

 F1 Lock Mass 0 * NotFnd - - n n 

 F2 Lock Mass 0 * NotFnd - - n n 

 F3 Lock Mass 0 * NotFnd - - n n 

 F4 Lock Mass 0 * NotFnd - - n n 

 F5 Lock Mass 0 * NotFnd - - n n 

 F6 Lock Mass 0 * NotFnd - - n n 

 DUMMY LINE 0 * NotFnd - - n n 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 55 of 84
Calibration Report OPUS v3.6

 Sample ID H4-14-CS#6-0112 CALIBRATION REPORT OPUS v3.6

 Comments C429ALS-CS#6-016

 Sample size 1

 Filename 4-141115A08

 Acquired 15-Nov-2014 16:44

 Processed 15-Nov-2014 21:08

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429ALSK

 Cal level 2000

 Target Analyte Conc Resp RA RT RRF Mean RR M? P1? P2?

 Naphthalene 2000 585180000 - n 7:33 1.4298 1.278 n n n 

 2-Me-Naphthalene 2000 251660000 - n 8:42 1.7287 1.5231 n n n 

 1-Me-Naphthalene 2000 239560000 - n 8:51 1.6455 1.4594 n n n 

 Acenaphthylene 2000 667080000 - n 10:08 1.8465 1.4498 n n n 

 Acenaphthene 2000 298970000 - n 10:26 0.8276 0.713 n n n 

 Fluorene 2000 259400000 - n 11:17 0.4407 0.3868 n n n 

 Phenanthrene 2000 733980000 - n 12:49 1.2471 1.0937 n n n 

 Anthracene 2000 782710000 - n 12:54 1.2606 1.133 n n n 

 Fluoranthene 2000 613000000 - n 14:46 2.0372 1.4922 n n n 

 Pyrene 2000 651600000 - n 15:08 2.1655 1.6007 n n n 

 Benz[a]anthracene 2000 660610000 - n 17:31 1.9317 1.2872 n n n 

 Chrysene/Triphenylene 2000 802280000 - n 17:34 1.3759 1.1186 n n n 

 Benzo[b]fluoranthene 2000 * - n NotFnd * 1.1652 y n n 

 Benzo[k]fluoranthene 2000 * - n NotFnd * 1.039 y n n 

 Benzo[e]pyrene 2000 688540000 - n 20:13 1.6427 1.2608 n n n 

 Benzo[a]pyrene 2000 677890000 - n 20:19 1.6173 1.2122 n n n 

 Perylene 2000 802910000 - n 20:29 2.0763 1.5769 n n n 

 Indeno[1,2,3-cd]pyrene 2000 462040000 - n 22:20 1.3528 0.9962 n n n 

 Dibenzo[a,h]anthracene 2000 571280000 - n 22:24 * 1.5744 n n n 

 Benzo[g,h,i]perylene 2000 580540000 - n 22:45 1.6066 1.2238 n n n 

 Fluorene-d10 100 7788600 - n 11:14 0.2647 0.2707 n n n 

 p-Terphenyl-d14 100 9127100 - n 15:33 0.6066 0.5896 n n n 

 Naphthalene-d8 100 20463000 - n 7:31 1.8179 1.768 n n n 

 2-Me-Naphthalene-d10 100 7279100 - n 8:39 0.6467 0.6459 n n n 

 Acenaphthylene-d8 100 18063000 - n 10:07 1.6047 1.5191 n n n 

 Phenanthrene-d10 100 29427000 - n 12:47 2.6143 2.4442 n n n 

 Anthracene-d10 100 31045000 - n 12:52 2.758 2.5518 n n n 

 Fluoranthene-d10 100 15045000 - n 14:44 0.8837 0.8818 n n n 

 Benz[a]anthracene-d12 100 17099000 - n 17:28 1.0043 0.882 n n n 

 Chrysene-d12 100 29156000 - n 17:32 1.7125 1.462 n n n 

 Benzo[b]fluoranthene-d12 100 15721000 - n 19:40 0.6889 0.6883 n n n 

 Benzo[k]fluoranthene-d12 100 28172000 - n 19:43 1.2345 1.0588 n n n 

 Benzo[a]pyrene-d12 100 20958000 - n 20:16 0.9184 0.7977 n n n 

 Perylene-d12 100 19335000 - n 20:26 0.8473 0.7883 n n n 

 Indeno[1,2,3-cd]pyrene-d12 100 17077000 - n 22:18 0.7483 0.5329 n n n 

 Dibenzo[a,h]anthracene-d14 100 * - n NotFnd * 0.3723 y n n 

 Benzo[g,h,i]perylene-d12 100 18067000 - n 22:43 0.7917 0.588 n n n 

 Acenaphthene-d10 100 11256000 - n 10:23 - - n n n 

 Pyrene-d10 100 17025000 - n 15:07 - - n n n 

 Benzo[e]pyrene-d12 100 22820000 - n 20:10 - - n n n 

 F1 Lock Mass 0 * NotFnd - - n n 

 F2 Lock Mass 0 * NotFnd - - n n 

 F3 Lock Mass 0 * NotFnd - - n n 

 F4 Lock Mass 0 * NotFnd - - n n 

 F5 Lock Mass 0 * NotFnd - - n n 

 F6 Lock Mass 0 * NotFnd - - n n 

 DUMMY LINE 0 * NotFnd - - n n 

0

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 56 of 84
Sample Name Sampling Date

ALS Sample ID H4-14-CCV-0452 Extraction Date

Analysis Method Sample Size

Analysis Type CCV Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A23

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units %

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret.

Target Analytes Time % Rec Limits

Naphthalene 7:35 88 70-130

2-Me-Naphthalene 8:44 98 70-130

1-Me-Naphthalene 8:53 100 70-130

Acenaphthylene 10:10 93 70-130

Acenaphthene 10:27 99 70-130

Fluorene 11:18 96 70-130

Phenanthrene 12:51 87 70-130

Anthracene 12:56 88 70-130

Fluoranthene 14:47 89 70-130

Pyrene 15:10 88 70-130

Benz[a]anthracene 17:32 84 70-130

Chrysene/Triphenylene 17:36 96 70-130

Benzo[b]fluoranthene 19:44 90 70-130

Benzo[k]fluoranthene 19:47 101 70-130

Benzo[e]pyrene 20:15 88 70-130

Benzo[a]pyrene 20:21 91 70-130

Perylene 20:30 94 70-130

Indeno[1,2,3-cd]pyrene 22:22 91 70-130

Dibenzo[a,h]anthracene 22:26 103 70-130

Benzo[g,h,i]perylene 22:47 96 70-130

Field Spike Standards % Rec Limits

Fluorene-d10 11:15 100 70-130

p-Terphenyl-d14 15:35 113 70-130

Extraction Standards % Rec Limits

Naphthalene-d8 7:33 103 70-130

2-Me-Naphthalene-d10 8:41 101 70-130

Acenaphthylene-d8 10:09 97 70-130

Phenanthrene-d10 12:48 100 70-130

Anthracene-d10 12:54 106 70-130

Fluoranthene-d10 14:45 101 70-130

Benz[a]anthracene-d12 17:30 102 70-130

Chrysene-d12 17:33 101 70-130

Benzo[b]fluoranthene-d12 19:41 102 70-130

Benzo[k]fluoranthene-d12 19:45 96 70-130

Benzo[a]pyrene-d12 20:18 95 70-130

Perylene-d12 20:27 103 70-130

Indeno[1,2,3-cd]pyrene-d12 22:20 109 70-130

Dibenzo[a,h]anthracene-d14 22:23 122 70-130

Benzo[g,h,i]perylene-d12 22:44 111 70-130

ALS Environmental

Continuing Calibration Report

CCV n/a

n/a Approved:

CARB 429 Modified 1 Ella Gdyczynski

n/a --e-signature--

QC 1 17-Nov-2014

16-Nov-14 01:18

Flags

ALS Canada Ltd L1535265 Data Package 141208a Page 58 of 73

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 57 of 84
Sample Name Sampling Date

ALS Sample ID H4-14-CCV-0453 Extraction Date

Analysis Method Sample Size

Analysis Type CCV Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115B01

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units %

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret.

Target Analytes Time % Rec Limits

Naphthalene 7:33 87 70-130

2-Me-Naphthalene 8:42 95 70-130

1-Me-Naphthalene 8:51 98 70-130

Acenaphthylene 10:08 92 70-130

Acenaphthene 10:26 100 70-130

Fluorene 11:16 101 70-130

Phenanthrene 12:49 86 70-130

Anthracene 12:54 93 70-130

Fluoranthene 14:46 92 70-130

Pyrene 15:08 91 70-130

Benz[a]anthracene 17:31 90 70-130

Chrysene/Triphenylene 17:35 88 70-130

Benzo[b]fluoranthene 19:42 100 70-130

Benzo[k]fluoranthene 19:45 97 70-130

Benzo[e]pyrene 20:13 90 70-130

Benzo[a]pyrene 20:19 91 70-130

Perylene 20:28 95 70-130

Indeno[1,2,3-cd]pyrene 22:20 92 70-130

Dibenzo[a,h]anthracene 22:25 104 70-130

Benzo[g,h,i]perylene 22:45 94 70-130

Field Spike Standards % Rec Limits

Fluorene-d10 11:14 101 70-130

p-Terphenyl-d14 15:33 115 70-130

Extraction Standards % Rec Limits

Naphthalene-d8 7:31 95 70-130

2-Me-Naphthalene-d10 8:39 95 70-130

Acenaphthylene-d8 10:07 91 70-130

Phenanthrene-d10 12:47 91 70-130

Anthracene-d10 12:52 91 70-130

Fluoranthene-d10 14:44 96 70-130

Benz[a]anthracene-d12 17:28 93 70-130

Chrysene-d12 17:32 100 70-130

Benzo[b]fluoranthene-d12 19:39 91 70-130

Benzo[k]fluoranthene-d12 19:43 93 70-130

Benzo[a]pyrene-d12 20:16 96 70-130

Perylene-d12 20:25 102 70-130

Indeno[1,2,3-cd]pyrene-d12 22:18 117 70-130

Dibenzo[a,h]anthracene-d14 22:21 130 70-130

Benzo[g,h,i]perylene-d12 22:42 117 70-130

ALS Environmental

Continuing Calibration Report

CCV n/a

n/a Approved:

CARB 429 Modified 1 Ella Gdyczynski

n/a --e-signature--

QC 1 17-Nov-2014

16-Nov-14 01:52

Flags

ALS Canada Ltd L1535265 Data Package 141208a Page 59 of 73

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 58 of 84
Sample Name Sampling Date

ALS Sample ID H4-14-CCV-0454 Extraction Date

Analysis Method Sample Size

Analysis Type CCV Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115B22

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units %

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret.

Target Analytes Time % Rec Limits

Naphthalene 7:35 77 70-130

2-Me-Naphthalene 8:45 88 70-130

1-Me-Naphthalene 8:53 88 70-130

Acenaphthylene 10:11 84 70-130

Acenaphthene 10:28 97 70-130

Fluorene 11:20 132 70-130

Phenanthrene 12:52 85 70-130

Anthracene 12:56 88 70-130

Fluoranthene 14:48 81 70-130

Pyrene 15:11 81 70-130

Benz[a]anthracene 17:33 76 70-130

Chrysene/Triphenylene 17:37 82 70-130

Benzo[b]fluoranthene 19:45 89 70-130

Benzo[k]fluoranthene 19:48 96 70-130

Benzo[e]pyrene 20:16 85 70-130

Benzo[a]pyrene 20:22 85 70-130

Perylene 20:31 92 70-130

Indeno[1,2,3-cd]pyrene 22:23 77 70-130

Dibenzo[a,h]anthracene 22:28 90 70-130

Benzo[g,h,i]perylene 22:48 84 70-130

Field Spike Standards % Rec Limits

Fluorene-d10 11:16 141 70-130

p-Terphenyl-d14 15:36 120 70-130

Extraction Standards % Rec Limits

Naphthalene-d8 7:33 81 70-130

2-Me-Naphthalene-d10 8:41 97 70-130

Acenaphthylene-d8 10:10 87 70-130

Phenanthrene-d10 12:49 76 70-130

Anthracene-d10 12:55 84 70-130

Fluoranthene-d10 14:46 101 70-130

Benz[a]anthracene-d12 17:31 66 70-130

Chrysene-d12 17:34 83 70-130

Benzo[b]fluoranthene-d12 19:42 80 70-130

Benzo[k]fluoranthene-d12 19:45 90 70-130

Benzo[a]pyrene-d12 20:19 99 70-130

Perylene-d12 20:28 107 70-130

Indeno[1,2,3-cd]pyrene-d12 22:21 139 M 70-130

Dibenzo[a,h]anthracene-d14 22:24 167 70-130

Benzo[g,h,i]perylene-d12 22:45 143 70-130

M Indicates that a peak has been manually integrated.

ALS Environmental

Continuing Calibration Report

CCV n/a

n/a Approved:

CARB 429 Modified 1 Ella Gdyczynski

n/a --e-signature--

QC 1 17-Nov-2014

16-Nov-14 13:53

Flags

ALS Canada Ltd L1535265 Data Package 141208a Page 60 of 73

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 59 of 84
Quantification Report OPUS v3.6

 Sample ID H4-14-CCV-0452

 Comments C429ALS-CS#3-016

 Sample size 1

 Filename 4-141115A23

 Acquired 16-Nov-2014 01:18

 Processed 16-Nov-2014 10:04

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 1

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/

 Naphthalene 1 19792000 - n 7:35 88.2231 0 0.130282 88.2 n n 9896000 2129900 2584 824.3 - - - 

 2-Me-Naphthalene 1 9366400 - n 8:44 97.8825 0 0.044234 97.9 n n 4683200 956800 344 2781.4 - - -  1-Me-Naphthalene 1 9147800 - n 8:53 99.7719 0 0.046166 99.8 n n 4573900 961990 344 2796.5 - - - 

 Acenaphthylene 1 19094000 - n 10:10 92.5437 0 0 92.5 n n 9547200 1811300 0 Div0 - - - 

 Acenaphthene 1 10004000 - n 10:27 98.5992 0 0.020847 98.6 n n 5002200 1008100 164 6146.8 - - - 

 Fluorene 1 8781800 - n 11:18 95.7884 0 0 95.8 n n 4390900 748500 0 Div0 - - - 

 Phenanthrene 1 22534000 - n 12:51 86.9387 0 0 86.9 n n 11267000 2056100 0 Div0 - - - 

 Anthracene 1 25940000 - n 12:56 87.5827 0 0 87.6 n n 12970000 1819600 0 Div0 - - - 

 Fluoranthene 1 17039000 - n 14:47 88.8859 0 0 88.9 n n 8519300 1506900 0 Div0 - - - 

 Pyrene 1 18098000 - n 15:10 88.0179 0 0 88 n n 9049200 1632800 0 Div0 - - - 

 Benz[a]anthracene 1 14071000 - n 17:32 84.2806 0 0 84.3 n n 7035300 1241300 0 Div0 - - - 

 Chrysene/Triphenylene 1 22747000 - n 17:36 95.9762 0 0 96 n n 11373000 1510700 0 Div0 - - - 

 Benzo[b]fluoranthene 1 14098000 - n 19:44 90.4604 0 0 90.5 n n 7048800 1379500 0 Div0 - - - 

 Benzo[k]fluoranthene 1 20194000 - n 19:47 100.647 0 0 100.6 n n 10097000 1299100 0 Div0 - - - 

 Benzo[e]pyrene 1 16018000 - n 20:15 87.6754 0 0 87.7 n n 8008800 1451200 0 Div0 - - -  Benzo[a]pyrene 1 15928000 - n 20:21 90.6828 0 0 90.7 n n 7964200 1127100 0 Div0 - - - 

 Perylene 1 22933000 - n 20:30 94.0631 0 0 94.1 n n 11467000 1794600 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene 1 9992700 - n 22:22 90.7071 0 0 90.7 n n 4996300 749040 0 Div0 - - - 

 Dibenzo[a,h]anthracene 1 14120000 - n 22:26 103.359 0 0 103.4 n n 7059800 879200 0 Div0 - - - 

 Benzo[g,h,i]perylene 1 14726000 - n 22:47 96.4862 0 0 96.5 n n 7363100 1001900 0 Div0 - - - 

 Fluorene-d10 1 6438800 - n 11:15 100.36 0 0 100.4 n n 3219400 559420 0 Div0 - - - 

 p-Terphenyl-d14 1 8564100 - n 15:35 113.068 0 0 113.1 n n 4282100 617550 0 Div0 - - - 

 Naphthalene-d8 1 17554000 - n 7:33 102.886 0 0.030483 102.9 n n 8777200 1940000 436 4449.5 - - - 

 2-Me-Naphthalene-d10 1 6282600 - n 8:41 100.787 0 0 100.8 n n 3141300 638230 0 Div0 - - - 

 Acenaphthylene-d8 1 14232000 - n 10:09 97.081 0 0 97.1 n n 7115800 1379300 0 Div0 - - - 

 Phenanthrene-d10 1 23699000 - n 12:48 100.473 0 0 100.5 n n 11850000 2151200 0 Div0 - - - 

 Anthracene-d10 1 26140000 - n 12:54 106.15 0 0 106.1 n n 13070000 1823200 0 Div0 - - - 

 Fluoranthene-d10 1 12846000 - n 14:45 101.042 0 0 101 n n 6422900 1147700 0 Div0 - - - 

 Benz[a]anthracene-d12 1 12970000 - n 17:30 101.992 0 0 102 n n 6484900 1228200 0 Div0 - - - 

 Chrysene-d12 1 21188000 - n 17:33 100.518 0 0 100.5 n n 10594000 1437100 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 13375000 - n 19:41 101.942 0 0 101.9 n n 6687600 1264600 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 19310000 - n 19:45 95.6813 0 0 95.7 n n 9655200 1388500 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 14491000 - n 20:18 95.296 0 0 95.3 n n 7245300 1089000 0 Div0 - - - 

 Perylene-d12 1 15462000 - n 20:27 102.902 0 0 102.9 n n 7730800 1107900 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 11059000 - n 22:20 108.879 0 0 108.9 n n 5529500 585930 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 8676600 - n 22:23 122.252 0 0 122.3 n n 4338300 500490 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 12471000 - n 22:44 111.27 0 0 111.3 n n 6235500 882440 0 Div0 - - - 

 Acenaphthene-d10 1 9650400 - n 10:24 86.1099 0 - - n n 4825200 1011200 0 Div0 - - - 

 Pyrene-d10 1 14417000 - n 15:08 87.2698 0 - - n n 7208700 1326200 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 19061000 - n 20:11 96.1759 0 - - n n 9530700 1740800 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29  F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

0

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID H4-14-CCV-0453

 Comments C429ALS-CS#3-016

 Sample size 1

 Filename 4-141115B01

 Acquired 16-Nov-2014 01:52

 Processed 16-Nov-2014 10:12

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 1

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/

 Naphthalene 1 20620000 - n 7:33 87.1469 0 0.14048 87.1 n n 10310000 2259100 2976 759.1 - - - 

 2-Me-Naphthalene 1 9716000 - n 8:42 94.5005 0 0.046586 94.5 n n 4858000 970360 392 2475.4 - - -  1-Me-Naphthalene 1 9613900 - n 8:51 97.5908 0 0.04862 97.6 n n 4806900 997200 392 2543.9 - - - 

 Acenaphthylene 1 20286000 - n 10:08 91.7103 0 0 91.7 n n 10143000 1920600 0 Div0 - - - 

 Acenaphthene 1 10875000 - n 10:26 99.9759 0 0.024888 100 n n 5437400 1096200 208 5270.2 - - - 

 Fluorene 1 9533100 - n 11:16 100.725 0 0 100.7 n n 4766500 820310 0 Div0 - - - 

 Phenanthrene 1 23110000 - n 12:49 86.3687 0 0 86.4 n n 11555000 2077000 0 Div0 - - - 

 Anthracene 1 26942000 - n 12:54 92.771 0 0 92.8 n n 13471000 1855800 0 Div0 - - - 

 Fluoranthene 1 17707000 - n 14:46 91.6884 0 0 91.7 n n 8853700 1581700 0 Div0 - - - 

 Pyrene 1 18942000 - n 15:08 91.4371 0 0 91.4 n n 9471100 1669600 0 Div0 - - - 

 Benz[a]anthracene 1 14458000 - n 17:31 89.5535 0 0 89.6 n n 7228900 1225000 0 Div0 - - - 

 Chrysene/Triphenylene 1 22154000 - n 17:35 88.4998 0 0 88.5 n n 11077000 1455600 0 Div0 - - - 

 Benzo[b]fluoranthene 1 15632000 - n 19:42 100.035 0 0 100 n n 7816200 1438000 0 Div0 - - - 

 Benzo[k]fluoranthene 1 21303000 - n 19:45 97.2897 0 0 97.3 n n 10652000 1414400 0 Div0 - - - 

 Benzo[e]pyrene 1 18651000 - n 20:13 89.5608 0 0 89.6 n n 9325500 1676600 0 Div0 - - -  Benzo[a]pyrene 1 18141000 - n 20:19 90.6035 0 0 90.6 n n 9070400 1343300 0 Div0 - - - 

 Perylene 1 25945000 - n 20:28 94.9837 0 0 95 n n 12973000 1959600 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene 1 12187000 - n 22:20 91.6029 0 0 91.6 n n 6093400 924670 0 Div0 - - - 

 Dibenzo[a,h]anthracene 1 16957000 - n 22:25 103.781 0 0 103.8 n n 8478500 1071600 0 Div0 - - - 

 Benzo[g,h,i]perylene 1 17114000 - n 22:45 94.4038 0 0 94.4 n n 8557000 1178800 0 Div0 - - - 

 Fluorene-d10 1 6715600 - n 11:14 101.395 0 0 101.4 n n 3357800 576320 0 Div0 - - - 

 p-Terphenyl-d14 1 8741100 - n 15:33 114.547 0 0 114.5 n n 4370600 651680 0 Div0 - - - 

 Naphthalene-d8 1 18515000 - n 7:31 95.184 0 0.023683 95.2 n n 9257400 2072100 376 5510.9 - - - 

 2-Me-Naphthalene-d10 1 6750300 - n 8:39 94.9862 0 0 95 n n 3375200 690580 0 Div0 - - - 

 Acenaphthylene-d8 1 15257000 - n 10:07 91.2896 0 0 91.3 n n 7628400 1465300 0 Div0 - - - 

 Phenanthrene-d10 1 24466000 - n 12:47 90.9806 0 0 91 n n 12233000 2199400 0 Div0 - - - 

 Anthracene-d10 1 25632000 - n 12:52 91.2984 0 0 91.3 n n 12816000 1773400 0 Div0 - - - 

 Fluoranthene-d10 1 12942000 - n 14:44 95.8753 0 0 95.9 n n 6471000 1157800 0 Div0 - - - 

 Benz[a]anthracene-d12 1 12542000 - n 17:28 92.8901 0 0 92.9 n n 6271000 1194600 0 Div0 - - - 

 Chrysene-d12 1 22379000 - n 17:32 99.9931 0 0 100 n n 11190000 1481800 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 13412000 - n 19:39 90.6741 0 0 90.7 n n 6705900 1305600 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 21074000 - n 19:43 92.6251 0 0 92.6 n n 10537000 1413600 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 16518000 - n 20:16 96.357 0 0 96.4 n n 8258900 1187300 0 Div0 - - - 

 Perylene-d12 1 17323000 - n 20:25 102.266 0 0 102.3 n n 8661300 1224700 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 13355000 - n 22:18 116.636 0 0 116.6 n n 6677700 717020 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 10378000 - n 22:21 129.705 0 0 129.7 n n 5188900 608320 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 14813000 - n 22:42 117.237 0 0 117.2 n n 7406500 1024500 0 Div0 - - - 

 Acenaphthene-d10 1 11002000 - n 10:23 98.17 0 - - n n 5501000 1122500 0 Div0 - - - 

 Pyrene-d10 1 15308000 - n 15:07 92.6608 0 - - n n 7654000 1402700 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 21489000 - n 20:10 108.423 0 - - n n 10744000 1897500 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28  F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:08 25:28 



ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
Quantification Report OPUS v3.6

 Sample ID H4-14-CCV-0454

 Comments C429ALS-CS#3-016

 Sample size 1

 Filename 4-141115B22

 Acquired 16-Nov-2014 13:53

 Processed 16-Nov-2014 17:17

 Instrument HRMS-4

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 1

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/

 Naphthalene 1 13878000 - n 7:35 76.5932 0 0.072653 76.6 n n 6939200 1442900 1112 1297.6 - - - 

 2-Me-Naphthalene 1 8312100 - n 8:45 87.6251 0 0.039194 87.6 n n 4156100 845830 308 2746.2 - - -  1-Me-Naphthalene 1 8036400 - n 8:53 88.4174 0 0.040905 88.4 n n 4018200 854940 308 2775.8 - - - 

 Acenaphthylene 1 16008000 - n 10:11 84.446 0 0 84.4 n n 8004000 1519900 0 Div0 - - - 

 Acenaphthene 1 9017400 - n 10:28 96.7318 0 0.01918 96.7 n n 4508700 917990 136 6749.9 - - - 

 Fluorene 1 9418100 - n 11:20 132.07 0 0 132.1 y n 4709100 741470 0 Div0 - - - 

 Phenanthrene 1 17169000 - n 12:52 85.1579 0 0 85.2 n n 8584300 1467400 0 Div0 - - - 

 Anthracene 1 21284000 - n 12:56 88.0895 0 0 88.1 n n 10642000 1285600 0 Div0 - - - 

 Fluoranthene 1 15242000 - n 14:48 81.1267 0 0 81.1 n n 7621000 1207100 0 Div0 - - - 

 Pyrene 1 16399000 - n 15:11 81.3708 0 0 81.4 n n 8199500 1345000 0 Div0 - - - 

 Benz[a]anthracene 1 8099600 - n 17:33 76.342 0 0 76.3 n n 4049800 705130 0 Div0 - - - 

 Chrysene/Triphenylene 1 15731000 - n 17:37 82.0723 0 0 82.1 n n 7865300 891710 0 Div0 - - - 

 Benzo[b]fluoranthene 1 8436800 - n 19:45 88.5596 0 0 88.6 n n 4218400 807900 0 Div0 - - - 

 Benzo[k]fluoranthene 1 14195000 - n 19:48 96.1173 0 0 96.1 n n 7097500 814550 0 Div0 - - - 

 Benzo[e]pyrene 1 12662000 - n 20:16 85.4746 0 0 85.5 n n 6331200 1105400 0 Div0 - - -  Benzo[a]pyrene 1 12142000 - n 20:22 85.2472 0 0 85.2 n n 6070900 825560 0 Div0 - - - 

 Perylene 1 18249000 - n 20:31 91.7441 0 0 91.7 n n 9124600 1267100 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene 1 8524400 - n 22:23 77.1777 0 0 77.2 n n 4262200 588210 0 Div0 - - - 

 Dibenzo[a,h]anthracene 1 13160000 - n 22:28 89.7926 0 0 89.8 n n 6580200 729100 0 Div0 - - - 

 Benzo[g,h,i]perylene 1 12944000 - n 22:48 83.9993 0 0 84 n n 6471800 833740 0 Div0 - - - 

 Fluorene-d10 1 7036900 - n 11:16 141.011 0 0 141 n n 3518500 565610 0 Div0 - - - 

 p-Terphenyl-d14 1 8872000 - n 15:36 119.508 0 0 119.5 n n 4436000 558330 0 Div0 - - - 

 Naphthalene-d8 1 14178000 - n 7:33 80.8986 0 0.025954 80.9 n n 7089200 1497100 368 4068.1 - - - 

 2-Me-Naphthalene-d10 1 6228100 - n 8:41 97.2665 0 0 97.3 n n 3114000 644930 0 Div0 - - - 

 Acenaphthylene-d8 1 13075000 - n 10:10 86.8312 0 0 86.8 n n 6537600 1243200 0 Div0 - - - 

 Phenanthrene-d10 1 18434000 - n 12:49 76.0821 0 0 76.1 n n 9217000 1606100 0 Div0 - - - 

 Anthracene-d10 1 21325000 - n 12:55 84.3024 0 0 84.3 n n 10662000 1258600 0 Div0 - - - 

 Fluoranthene-d10 1 12590000 - n 14:46 100.856 0 0 100.9 n n 6295200 1012500 0 Div0 - - - 

 Benz[a]anthracene-d12 1 8242300 - n 17:31 66.0091 0 0 66 n n 4121100 750820 0 Div0 - - - 

 Chrysene-d12 1 17135000 - n 17:34 82.7861 0 0 82.8 n n 8567400 1003000 0 Div0 - - - 

 Benzo[b]fluoranthene-d12 1 8176200 - n 19:42 79.5469 0 0 79.5 n n 4088100 795390 0 Div0 - - - 

 Benzo[k]fluoranthene-d12 1 14214000 - n 19:45 89.8992 0 0 89.9 n n 7106800 877060 0 Div0 - - - 

 Benzo[a]pyrene-d12 1 11750000 - n 20:19 98.6392 0 0 98.6 n n 5875100 767490 0 Div0 - - - 

 Perylene-d12 1 12615000 - n 20:28 107.166 0 0 107.2 n n 6307300 818900 0 Div0 - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 11088000 - n 22:21 139.346 0 0 139.3 y n 5543900 516060 0 Div0 - - - 

 Dibenzo[a,h]anthracene-d14 1 9309000 - n 22:24 167.428 0 0 167.4 n n 4654500 463450 0 Div0 - - - 

 Benzo[g,h,i]perylene-d12 1 12591000 - n 22:45 143.402 0 0 143.4 n n 6295500 819290 0 Div0 - - - 

 Acenaphthene-d10 1 9912800 - n 10:25 88.4519 0 - - n n 4956400 1002500 0 Div0 - - - 

 Pyrene-d10 1 14157000 - n 15:09 85.6925 0 - - n n 7078400 1173600 0 Div0 - - - 

 Benzo[e]pyrene-d12 1 14933000 - n 20:12 75.3441 0 - - n n 7466300 1254900 0 Div0 - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30 

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30  F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30  F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30  F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30  F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:10 25:30 

0

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including:

for Laboratory Method Blanks:

- Laboratory Method Blank Analysis Reports

- Individual Quantitation Reports

for LCS:

-Laboratory Control Sample Analysis Reports

- Individual Quantitation Reports

for MS:

- Matrix Spike Analysis Reports

- Individual Quantitation Reports

for Others (eg. Reference Data):

- QC Sample Analysis Reports

- Individual Quantitation Reports

SVOC DATA PACKAGE

SECTION 5: QC SAMPLE DATA

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 63 of 84
Sample Name Sampling Date

ALS Sample ID WG1980014-2 Extraction Date

Analysis Method Sample Size

Analysis Type LCS Moisture Content

Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A10

Run Date

Final Volume 1000 uL

Dilution Factor 1

Analysis Units %

Instrument - Column HRMS-4 Rxi5Sil1117926

Ret.

Target Analytes Time % Rec Limits

Naphthalene 7:34 123 50-150

2-Me-Naphthalene n/s

1-Me-Naphthalene n/s

Acenaphthylene 10:10 98 50-150

Acenaphthene 10:27 103 50-150

Fluorene 11:18 105 50-150

Phenanthrene 12:50 99 50-150

Anthracene 12:55 101 50-150

Fluoranthene 14:47 102 50-150

Pyrene 15:10 92 50-150

Benz[a]anthracene 17:32 103 50-150

Chrysene/Triphenylene 17:36 97 50-150

Benzo[b]fluoranthene 19:43 109 50-150

Benzo[k]fluoranthene 19:47 103 50-150

Benzo[e]pyrene n/s

Benzo[a]pyrene 20:20 89 50-150

Perylene n/s

Indeno[1,2,3-cd]pyrene 22:21 111 50-150

Dibenzo[a,h]anthracene 22:26 104 50-150

Benzo[g,h,i]perylene 22:46 104 50-150

Field Spike Standards % Rec Limits

Fluorene-d10 11:15 n/s

p-Terphenyl-d14 15:34 n/s

Extraction Standards % Rec Limits

Naphthalene-d8 7:32 85 20-150

2-Me-Naphthalene-d10 8:40 81 20-150

Acenaphthylene-d8 10:08 84 20-150

Phenanthrene-d10 12:48 80 30-150

Anthracene-d10 12:53 74 30-150

Fluoranthene-d10 14:45 91 30-150

Benz[a]anthracene-d12 17:29 56 30-150

Chrysene-d12 17:33 50 30-150

Benzo[b]fluoranthene-d12 19:40 85 30-150

Benzo[k]fluoranthene-d12 19:44 79 30-150

Benzo[a]pyrene-d12 20:17 75 30-150

Perylene-d12 20:27 79 30-150

Indeno[1,2,3-cd]pyrene-d12 22:19 79 30-150

Dibenzo[a,h]anthracene-d14 22:22 80 30-150

Benzo[g,h,i]perylene-d12 22:44 81 30-150

n/s Indicates that this standard has not been spiked.

ALS Environmental

Laboratory Control Sample Analysis Report

Laboratory Control Sample n/a

28-Oct-14 Approved:

CARB 429 Modified 1 Ella Gdyczynski

n/a --e-signature--

QC 1 17-Nov-2014

15-Nov-14 17:53

Flags

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 64 of 84
 Sample ID WG1980014-2

 Comments LCS

 Sample size 1

 Filename 4-141115A10

 Acquired 41958.74515

 Processed 41958.89339

 Instrument 0

 Column RXI5SILMS1117926

 Calibration 4-141115A-CAL6-C429»

 ES level 10

 Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 

 Naphthalene 1 58117000 - n 7:34 123.263 0 0.857043 123.3 n n 29059000 5849100 31796 184 - - - - 

 2-Me-Naphthalene 1 171590 - n 8:43 0.879253 0 0.047379 0.9 n n 85795 15303 868 17.6 - - - -  1-Me-Naphthalene 1 194070 - n 8:52 1.03789 0 0.049448 1 n n 97037 17301 868 19.9 - - - - 

 Acenaphthylene 1 44062000 - n 10:10 97.7306 0 0 97.7 n n 22031000 5179200 0 Div0 - - - - 

 Acenaphthene 1 22847000 - n 10:27 103.049 0 0.012917 103 n n 11424000 2778900 264 10526.1 - - - - 

 Fluorene 1 19565000 - n 11:18 105.128 0 0 105.1 n n 9782700 2088300 0 Div0 - - - - 

 Phenanthrene 1 52176000 - n 12:50 99.1634 0 0 99.2 n n 26088000 5323600 0 Div0 - - - - 

 Anthracene 1 52660000 - n 12:55 100.996 0 0 101 n n 26330000 4671000 0 Div0 - - - - 

 Fluoranthene 1 33618000 - n 14:47 101.926 0 0 101.9 n n 16809000 3303300 0 Div0 - - - - 

 Pyrene 1 32381000 - n 15:10 91.5262 0 0 91.5 n n 16191000 3096000 0 Div0 - - - - 

 Benz[a]anthracene 1 17865000 - n 17:32 103.075 0 0 103.1 n n 8932700 1632900 0 Div0 - - - - 

 Chrysene/Triphenylene 1 21876000 - n 17:36 97.3937 0 0 97.4 n n 10938000 1580200 0 Div0 - - - - 

 Benzo[b]fluoranthene 1 13833000 - n 19:43 108.765 0 0 108.8 n n 6916500 1331000 0 Div0 - - - - 

 Benzo[k]fluoranthene 1 16626000 - n 19:47 103.093 0 0 103.1 n n 8312900 1206100 0 Div0 - - - - 

 Benzo[e]pyrene 1 103780 - n 20:14 0.735918 0 0 0.7 n n 51888 7513.4 0 Div0 - - - -  Benzo[a]pyrene 1 12009000 - n 20:20 88.578 0 0 88.6 n n 6004600 903740 0 Div0 - - - - 

 Perylene 1 406360 - n 20:30 2.21514 0 0 2.2 n n 203180 19124 0 Div0 - - - - 

 Indeno[1,2,3-cd]pyrene 1 8641000 - n 22:21 110.598 0 0 110.6 n n 4320500 669620 0 Div0 - - - - 

 Dibenzo[a,h]anthracene 1 9003400 - n 22:26 103.512 0 0 103.5 n n 4501700 582350 0 Div0 - - - - 

 Benzo[g,h,i]perylene 1 11279000 - n 22:46 104.376 0 0 104.4 n n 5639300 789390 0 Div0 - - - - 

 Fluorene-d10 1 6347.2 - n 11:15 0.048735 0 0 0 n n 3173.6 597.43 0 Div0 - - - - 

 p-Terphenyl-d14 1 996.71 - n 15:34 0.007648 0 0 0 n n 498.35 113.12 0 Div0 - - - - 

 Naphthalene-d8 1 36894000 - n 7:32 85.2368 0 0.026887 85.2 n n 18447000 3628800 1128 3217 - - - - 

 2-Me-Naphthalene-d10 1 12813000 - n 8:40 81.025 0 0 81 n n 6406500 1503500 0 Div0 - - - - 

 Acenaphthylene-d8 1 31097000 - n 10:08 83.6206 0 0 83.6 n n 15549000 3583300 0 Div0 - - - - 

 Phenanthrene-d10 1 48110000 - n 12:48 80.4001 0 0 80.4 n n 24055000 5015300 0 Div0 - - - - 

 Anthracene-d10 1 46019000 - n 12:53 73.6642 0 0 73.7 n n 23010000 4141500 0 Div0 - - - - 

 Fluoranthene-d10 1 22103000 - n 14:45 91.4809 0 0 91.5 n n 11051000 2187900 0 Div0 - - - - 

 Benz[a]anthracene-d12 1 13465000 - n 17:29 55.7172 0 0 55.7 n n 6732500 1303300 0 Div0 - - - - 

 Chrysene-d12 1 20080000 - n 17:33 50.1279 0 0 50.1 n n 10040000 1472100 0 Div0 - - - - 

 Benzo[b]fluoranthene-d12 1 10916000 - n 19:40 85.3653 0 0 85.4 n n 5457800 1121800 0 Div0 - - - - 

 Benzo[k]fluoranthene-d12 1 15521000 - n 19:44 78.9125 0 0 78.9 n n 7760600 1151500 0 Div0 - - - - 

 Benzo[a]pyrene-d12 1 11185000 - n 20:17 75.4749 0 0 75.5 n n 5592500 831740 0 Div0 - - - - 

 Perylene-d12 1 11634000 - n 20:27 79.4459 0 0 79.4 n n 5816800 828630 0 Div0 - - - - 

 Indeno[1,2,3-cd]pyrene-d12 1 7843100 - n 22:19 79.2331 0 0 79.2 n n 3921600 438970 0 Div0 - - - - 

 Dibenzo[a,h]anthracene-d14 1 5524500 - n 22:22 79.8696 0 0 79.9 n n 2762200 372210 0 Div0 - - - - 

 Benzo[g,h,i]perylene-d12 1 8829400 - n 22:44 80.8343 0 0 80.8 n n 4414700 638190 0 Div0 - - - - 

 Acenaphthene-d10 1 24481000 - n 10:24 218.447 0 - - n n 12241000 2966200 0 Div0 - - - - 

 Pyrene-d10 1 27399000 - n 15:08 165.85 0 - - n n 13700000 2694700 0 Div0 - - - - 

 Benzo[e]pyrene-d12 1 18577000 - n 20:11 93.7305 0 - - n n 9288300 1643000 0 Div0 - - - - 

 F1 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F2 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F3 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F4 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F5 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 F6 Lock Mass 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 DUMMY LINE 0 * NotFnd * * - - n * * 0 Div0 * 25:09 25:29 

 0 0 0 0 0 0 0 0 0 0 0 0 0

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including:

- Prep Logs

- Run Logs

- Quantification tables

- Independent calculation checks

- Others as listed below:

SVOC DATA PACKAGE

SECTION 6: INTERNAL RECORDS

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 66 of 84
ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 67 of 84
ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 68 of 84
ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 69 of 84
ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 70 of 84
ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 71 of 84
 Date: 15-NOV-14

 Operator: EG

 Instrument: HRMS-4

 MS Method: C429-DB5MS-3

 GC Method: C429-DB5MS-3

 Column: RXI5SILMS1117926

 # Data_file S Vial Sample_text Comments Acquisition Time

1 4-141115A01 1 1 xxxxxx xxxxxx 15-Nov-2014 12:49

2 4-141115A02 1 1 xxxxxx xxxxxx 15-Nov-2014 13:19

3 4-141115A03 1 1 H4-14-CS#1-0112 C429ALS-CS#1-016 15-Nov-2014 13:53

4 4-141115A04 1 1 H4-14-CS#2-0112 C429ALS-CS#2-016 15-Nov-2014 14:27

5 4-141115A05 1 1 H4-14-CS#3-0112 C429ALS-CS#3-016 15-Nov-2014 15:01

6 4-141115A06 1 1 H4-14-CS#4-0112 C429ALS-CS#4-016 15-Nov-2014 15:35

7 4-141115A07 1 1 H4-14-CS#5-0112 C429ALS-CS#5-016 15-Nov-2014 16:10

8 4-141115A08 1 1 H4-14-CS#6-0112 C429ALS-CS#6-016 15-Nov-2014 16:44

9 4-141115A09 1 1 H4-14-RS#4-0112 C429ALS-RS#4-016 15-Nov-2014 17:18

10 4-141115A10 1 1 WG1980014-2 LCS 15-Nov-2014 17:53

11 4-141115A11 1 1 WG1980014-3A ENI 15-Nov-2014 18:27

12 4-141115A12 1 1 DCM INST BLANK 15-Nov-2014 19:01

13 4-141115A13 1 1 DCM INST BLANK 15-Nov-2014 19:35

14 4-141115A14 1 1 WG1980014-1 METHOD BLANK 15-Nov-2014 20:10

15 4-141115A15 1 1 L1535265-11 SAMPLE X10 15-Nov-2014 20:44

16 4-141115A16 1 1 L1535265-4 SAMPLE X10 15-Nov-2014 21:18

17 4-141115A17 1 1 L1535265-3 SAMPLE X10 15-Nov-2014 21:52

18 4-141115A18 1 1 L1535265-3 SAMPLE X50 15-Nov-2014 22:27

19 4-141115A19 1 1 L1535265-1 DILUTIONX50000 15-Nov-2014 23:01

20 4-141115A20 1 1 L1535265-2 DILUTIONX50000 15-Nov-2014 23:35

21 4-141115A21 1 1 L1535265-5 DILUTIONX50000 16-Nov-2014 00:09

22 4-141115A22 1 1 xxxxxx xxxxxx 16-Nov-2014 00:44

23 4-141115A23 1 1 H4-14-CCV-0452 C429ALS-CS#3-016 16-Nov-2014 01:18

Instrument Runlog

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 72 of 84
 Quantification Tabl

 c/q Data File S I AnalyteTable CAL level ES level Size Sample ID Comments

1 c 4-141115A03 1 1 C29ALS-DB5MS-HRMS4-C 10 1 1 H4-14-CS#1-0112 C429ALS-CS#1-016

2 c 4-141115A04 1 1 C29ALS-DB5MS-HRMS4-C 50 1 1 H4-14-CS#2-0112 C429ALS-CS#2-016

3 c 4-141115A05 1 1 C29ALS-DB5MS-HRMS4-C 100 1 1 H4-14-CS#3-0112 C429ALS-CS#3-016

4 c 4-141115A06 1 1 C29ALS-DB5MS-HRMS4-C 200 1 1 H4-14-CS#4-0112 C429ALS-CS#4-016

5 c 4-141115A07 1 1 C29ALS-DB5MS-HRMS4-C 500 1 1 H4-14-CS#5-0112 C429ALS-CS#5-016

6 c 4-141115A08 1 1 C29ALS-DB5MS-HRMS4-C 2000 1 1 H4-14-CS#6-0112 C429ALS-CS#6-016

7 q 4-141115A09 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-RS#4-0112 C429ALS-RS#4-016

8 q 4-141115A10 1 1 C429ALS-DB5MS-HRMS4-CCV 100 10 1 WG1980014-2 LCS

9 q 4-141115A11 1 1 C429ALS-DB5MS-HRMS4-CCV 100 10 1 WG1980014-3A ENI

10 q 4-141115A14 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 WG1980014-1 METHOD BLANK

11 q 4-141115A15 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-11 SAMPLE X10

12 q 4-141115A16 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-4 SAMPLE X10

13 q 4-141115A17 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-3 SAMPLE X10

14 q 4-141115A18 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-3 SAMPLE X50

15 q 4-141115A19 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-1 DILUTIONX50000

16 q 4-141115A20 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-2 DILUTIONX50000

17 q 4-141115A21 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-5 DILUTIONX50000

18 q 4-141115A23 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-CCV-0452 C429ALS-CS#3-016

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 73 of 84
 Page 1 of 1

 Date: 15-NOV-14

 Operator: EG

 Instrument: HRMS-4

 MS Method: C429-DB5MS-3

 GC Method: C429-DB5MS-3

 Column: RXI5SILMS1117926

 # Data_file S Vial Sample_text Comments Acquisition Time

1 4-141115B01 1 1 H4-14-CCV-0453 C429ALS-CS#3-016 16-Nov-2014 01:52

2 4-141115B02 1 1 DCM INST BLANK 16-Nov-2014 02:27

3 4-141115B03 1 1 DCM INST BLANK 16-Nov-2014 03:01

4 4-141115B04 1 1 L1535265-1 SAMPLE X50 DILX10 Rサ 16-Nov-2014 03:35

5 4-141115B05 1 1 L1535265-2 SAMPLE X50 DILX10 Rサ 16-Nov-2014 04:10

6 4-141115B06 1 1 L1535265-5 SAMPLE X50 DILX10 Rサ 16-Nov-2014 04:44

7 4-141115B07 1 1 L1535265-6 SAMPLE X50 DILX10 Rサ 16-Nov-2014 05:18

8 4-141115B08 1 1 L1535265-7 SAMPLE X50 16-Nov-2014 05:52

9 4-141115B09 1 1 L1535265-8 SAMPLE X50 16-Nov-2014 06:27

10 4-141115B10 1 1 L1535265-9 SAMPLE X50 16-Nov-2014 07:01

11 4-141115B11 1 1 L1535265-10 SAMPLE X50 16-Nov-2014 07:35

12 4-141115B12 1 1 L1535265-7 SAMPLE X10 16-Nov-2014 08:10

13 4-141115B13 1 1 L1535265-8 SAMPLE X10 16-Nov-2014 08:44

14 4-141115B14 1 1 L1535265-9 SAMPLE X50 REINJECT 16-Nov-2014 09:18

15 4-141115B15 1 1 L1535265-9 SAMPLE X10 16-Nov-2014 09:53

16 4-141115B16 1 1 L1535265-10 SAMPLE X10 16-Nov-2014 10:27

17 4-141115B17 1 1 L1535265-1 SAMPLE X50 16-Nov-2014 11:01

18 4-141115B18 1 1 L1535265-2 SAMPLE X50 16-Nov-2014 11:36

19 4-141115B19 1 1 L1535265-5 SAMPLE X50 16-Nov-2014 12:10

20 4-141115B20 1 1 L1535265-6 SAMPLE X50 16-Nov-2014 12:44

21 4-141115B21 1 1 DCM INST BLANK 16-Nov-2014 13:19

22 4-141115B22 1 1 H4-14-CCV-0454 C429ALS-CS#3-016 16-Nov-2014 13:53

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 74 of 84
 Quantification Table

 c/q Data File S I AnalyteTable CAL level ES level Size Sample ID Comments

1 c 4-141115A03 1 1 C429ALS-DB5MS-HRMS4-C 10 1 1 H4-14-CS#1-0112 C429ALS-CS#1-016

2 c 4-141115A04 1 1 C429ALS-DB5MS-HRMS4-C 50 1 1 H4-14-CS#2-0112 C429ALS-CS#2-016

3 c 4-141115A05 1 1 C429ALS-DB5MS-HRMS4-C 100 1 1 H4-14-CS#3-0112 C429ALS-CS#3-016

4 c 4-141115A06 1 1 C429ALS-DB5MS-HRMS4-C 200 1 1 H4-14-CS#4-0112 C429ALS-CS#4-016

5 c 4-141115A07 1 1 C429ALS-DB5MS-HRMS4-C 500 1 1 H4-14-CS#5-0112 C429ALS-CS#5-016

6 c 4-141115A08 1 1 C429ALS-DB5MS-HRMS4-C 2000 1 1 H4-14-CS#6-0112 C429ALS-CS#6-016

7 q 4-141115B01 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-CCV-0453 C429ALS-CS#3-016

8 q 4-141115B04 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-1 SAMPLE X50 DILX10 RES

9 q 4-141115B05 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-2 SAMPLE X50 DILX10 RES

10 q 4-141115B06 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-5 SAMPLE X50 DILX10 RES

11 q 4-141115B07 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-6 SAMPLE X50 DILX10 RES

12 q 4-141115B08 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-7 SAMPLE X50

13 q 4-141115B09 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-8 SAMPLE X50

14 q 4-141115B10 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-9 SAMPLE X50

15 q 4-141115B11 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-10 SAMPLE X50

16 q 4-141115B12 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-7 SAMPLE X10

17 q 4-141115B13 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-8 SAMPLE X10

18 q 4-141115B14 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-9 SAMPLE X50 REINJECT

19 q 4-141115B15 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-9 SAMPLE X10

20 q 4-141115B16 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-10 SAMPLE X10

21 q 4-141115B17 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-1 SAMPLE X50

22 q 4-141115B18 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-2 SAMPLE X50

23 q 4-141115B19 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-5 SAMPLE X50

24 q 4-141115B20 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-6 SAMPLE X50

25 q 4-141115B22 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-CCV-0454 C429ALS-CS#3-016

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 75 of 84
Approved: Ella Gdyczynski

--e-signature--

Calculation of RRF for Naphthalene in H4-14-CS#3-0112

Response of Naphthalene Concentration of d8-Naphthalene

RRF = ______________________ x _____________________________

Response of d8-Naphthalene Concentration of Naphthalene

2.24E+07 100

RRF = ______________________ x _____________________________ = 1.14

1.96E+07 100

Calculation of Naphthalene amount in

L1535265-11

Response of Naphthalene ng of d8-Naphthalene spiked dilution

ng = ______________________ x ____________________________________________

Response of d8-Naphthalene Mean RRF of Naphthalene * Sample Size

1433850 100 # 10.00

ng = ______________________ x _________________________________________ = 103.472

10843000 1.28 * 1.00

Calculation of d8-Naphthalene recovery in

L1535265-11

Response of d8-Naphthalene ng of d10-Acenaphthene spiked * 100%

% Recovery = ______________________ x ____________________________________________

Response of d10-Acenaphthene Mean RRF d8-Naphthalene * ng of d8-Naphthalene spiked

10843000 100 * 100

% Recovery = ______________________ x _________________________________________ = 72 %

8479000 1.77 * 100

ALS Environmental

Sample Calculation Report

17-Nov-2014

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 76 of 84
 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including:

- Airbills

- Chain-of-Custody Records

- Sample Log-in Sheet(s) - where applicable

- Others as listed below:

SVOC DATA PACKAGE

SECTION 7: SHIPPING/RECEIVING 

DOCUMENTS

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 77 of 84
-.- - ~ __ _ _ - ------- -- - - 

Envil.onmenrul Qualify Management, Inc. 

"Q 

C~lvIro~~rne~rtal Quallly 

Management, Inc. ANALYSIS REQUEST AND 

CI-FAXN OF CUSTODY RJXC0R.D 

Reference Documenl No. . \ 

Lab Contacl/Phone 

r Lab Purchase Order No. 

. CarrlerlWaybiLl No. 

ONE COKrAlNER PER LINE 

Method/(Paramelers) 

2 

I 'I'III'II~~UIIIII~ 'I1 111e IZec~ulred: 

Nurrllnl [l Rush U Resulls Required by 

Po~slble Jhznrd Idet~llflcnllo~~: 

No11-11w~nrd u fia~n~nmblc Skin lrrjlal~l fl Otllcr I$ I 

Sa~nple Dlsposal: 

Relurn lo Cllenl a ~lsposal by Lab fl Arclllvc (mos.) I 

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 78 of 84
~ ~ 

. .-....'.~.....=A. NALusrs - - ; - -mrrmentat Quatity EWT AND 

- . A -- - Nla n ageemZiiInc. CHAIN OF CUSTODY RECORD (cont.) 

Reference Document No. 

Page - 7 of sy 

Project ~arne Project NO. 0T03~2.cO3 1 Sample Shipment Date I~/Z;~Y 

ONE CONTAINER PER LINE 

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 79 of 84
- 

OF CUSTODY RECORD (cont.) 

Reference 

3 of 

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Number 

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ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 80 of 84
ANALYSS REQUEST AND -- - . 

GHAlFTUF CUSTODY RE-C-ORD (cont.) 

Reference Document No. 

Page Y of 4 

Project Name &W Project No. 0ya-3~ 2.043 1 Sample Shipment Date 

ONE CONTAINER PER LINE 

Datenlme 

Collected 

lo/ / j-j/&r' 

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ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 81 of 84
TDG MANIFEST 

(ROAD) 

ALS Environmental 

Street Address: 5420 Mainway Dr. Unit 5 Street Address: 

City/Province: Burlington, ON City/Province: Crown Point, 1b ~ 

Postal Code: L7L 6A4 

-- 

Acetone / Class 3 / UNI 090 / PG II 2 L 

Postal Code: 46307 

No. of Units & 

Container 

Type 

X Hexane / Class 3 / UN1208, PGll 

DG 

Dichloromethane / Class 6.1 / UN1593 / PGlll 

Description Total pac:kdge 

Proper Shipping NamelHazard Class/UN NumberlPacking Group Quantity 

Package Gross 

Cooler 2 

lL 

Carbonate Buffer Solution (not regulated) 

Shipper: 

I hereby declare that the contents of this consignment are fully and 

accurately described above by the proper shipping name and are 

classified, packaged, marked and labeled, and are in all respects in 

proper condition for transport according to the Canadian 

Regulations for the transportation of dangerous goods by road. 

1,Z 

-- Signature: / 

lL 

IN CASE OF TRANSPORTATI N 

EMERGENCY CALL (24 HR) 4 

/,z 

(61 3) 996-6666 (call colle 

or *666 from a cell 

Released By: (Shipper) Received By: (Carrier or Consignee) 

Date: 20-Oct- 14 

Signature: 

Date: do -0~7- /cf I 

1 

I 

Signature: 

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 82 of 84
Management, Inc. CHAIN Of- GUS 1 ULJY HECUHU (cont.) 

Reference Document No. 

Page / of f 

Project Name &GX Project No. 0ra3f 2 - om I Sample Shipment Date [J/

ONE CONTAINER PER LINE 

/ 

4 

/ 

Sample 

Number 

/ 

2 - 

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9z'i 

Reu;"d +,: 

AprRcrv &P-T~ 

23-OGt-ZO!Lj 

l0:YO 

20.6-C 

Condltlon on 

Receipt (Lab) 

ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208 Data Package Page 83 of 84
ALS Environmental - Burlington, ON L1535265 PAH DPKG 141208