## 5420 Mainway Drive, Burlington ON, Canada, L7L 6A4



# Client Project Information Project ID: 050352.0031 Eramet

Contact: Tom Gerstle


# ALSE Project Information Project ID: EQM100

Contact: Ron McLeod Submission ID(s): L1535265

Final Package Review by:

Date Reviewed: 5-Dec-14 

# SVOC DATA PACKAGE

### 5420 Mainway Drive, Burlington ON, Canada, L7L 6A4



## ALSE Project Information Client Project Information Project ID: EQM100 Project ID: 050352.0031 Eramet

Contact: Ron McLeod Contact: Tom Gerstle Submission ID(s): L1535265

Analyical Method: PAH via modified CARB 429

Date Date Date Date ALS Sample ID Client Sample Descriptions Matrix Sampled Received Extracted Analyzed

L1535265-1 MAIN BAGHOUSE RUN#1 Stack 15-Oc t-14 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-2 MAIN BAGHOUSE RUN#2 Stack 15-Oc t-14 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-3 FIELD BLANK Stack 14-Oct-14 20-Oct-14 28-Oct-14 15-Nov-14 L1535265-4 ACETONE/HEXANE/METH. BLANK Stack 14-Oct-14 20-Oct-14 28-Oct-14 15-Nov-14 L1535265-5 MAIN BAGHOUSE RUN#3 Stack 15-Oc t-14 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-6 MAIN BAGHOUSE RUN#4 Stack 15-Oc t-14 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-7 FURNACE 12 RUN#1 Stack 16-Oct-1 4 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-8 FURNACE 12 RUN#2 Stack 16-Oct-1 4 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-9 FURNACE 12 RUN#3 Stack 16-Oct-1 4 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-10 FURNACE 12 RUN#4 Stack 16-Oc t-14 20-Oct-14 28-Oct-14 16-Nov-14 L1535265-11 BLANK XAD Trap 22-Oct-14 23-Oct-14 28-Oct-14 15-Nov-14

WG1980014-1 Method Blank QC n/a n/a 28-Oct-14 15-Nov-14 WG1980014-2 Laboratory Control Sample QC n/a n/a 28-Oct-14 15-Nov-14

Comments and Notes: a) Sample Integrity:

The samples were received in good condition at 8.2 degrees C, which is marginally above the method recommended temperature (7 d egrees C). No negative impact to data quality is expected.

b) Instrumental Analysis:

The method blank was lost during laboratory processing and has not been reported. The field blank serves as an indication that the sample data are not impacted by significant laboratory background.

Selected targets from selected samples have been reported from the analysis of diluted extracts that have been re-spiked with q uantification standard. As a result, these data are not calculated by isotope dilution and are not inherently recovery-corrected. Reported ex traction standard recoveries for these targets are not indicative of extraction efficiency as they have been spiked after extraction. This includes all Main Baghouse results where the dilution factor is noted to be 10 or 100.

An additional high level calibration standard has been analyzed and included in the mean RRF for selected targets.

Field spike standards were added to the XAD2 in the traps befor e sampling. Extraction standards were added as internal standard s to the XAD2 and filters just prior to extraction. The recovery standards (or in jection standards) were added to the extracts just prior to inst rumental analysis. For higher dilutions and where the extraction standards would otherwise be dilu ted below the levels of significant instrument response, th e extracts were fortified with extraction standards before injection. 

# SVOC DATA PACKAGE
SECTION 1: PROJECT NARRATIVE

### 5420 Mainway Drive, Burlington ON, Canada, L7L 6A4



## ALSE Project Information Client Project Information Project ID: EQM100 Project ID: 050352.0031 Eramet

Contact: Ron McLeod Contact: Tom Gerstle Submission ID(s): L1535265

Analyical Method: PAH via modified CARB 429

b) Instrumental Analysis:

Field Spike Recovery Data: Fluorene-d10 p-Terphenyl-d14 L1535265-11 BLANK 76% 48% L1535265-3 FIELD BLANK 96% 106% L1535265-1 MAIN BAGHOUSE RUN#1 

### 111% 73% L1535265-2 MAIN BAGHOUSE RUN#2 

### 145% 65% L1535265-5 MAIN BAGHOUSE RUN#3 

### 104% 87% L1535265-6 MAIN BAGHOUSE RUN#4 

### 125% 85% L1535265-7 FURNACE 12 RUN#1 

### 118% 115% L1535265-8 FURNACE 12 RUN#2 

### 109% 85% L1535265-9 FURNACE 12 RUN#3 

### 114% 113% L1535265-10 FURNACE 12 RUN#4 

### 104% 85%

Calibration Range and the amount of isotope dilution spike used:

Estimated Project Lower Range Isotope Dilution Upper Range Split Factor 10 10 Pre-extraction dilution postDilution Factor 1 50 spiking spike amount Final Extract Volume 1 1 amount added to 1mL Target Analytes ug ug Extraction Standards ng ng Naphthalene 0.77 1000 d8-naphthalene 1000 100 2-Me-Naphthalene 0.1 1000 d10-2-methylnaphthalene 1000 100 1-Me-Naphthalene 0.06 1000 d8-acenaphthylene 1000 100

Acenaphthylene 0.03 1000 d10-phenanthrene 1000 100

Acenaphthene 0.02 1000 d10-fluoranthene 1000 100 Fluorene 0.29 1000 d12-benz[a]anthracene 1000 100 Phenanthrene 0.25 1000 d12-chrysene 1000 100

Anthracene 0.04 1000 d12-benzo[b]fluoranthene 1000 100 Fluoranthene 0.25 1000 d12-benzo[k]fluoranthene 1000 100 Pyrene 0.19 1000 d12-benzo[a]pyrene 1000 100 Benz[a]anthracene 0.06 1000 d12-perylene 1000 100 Chrysene/Triphenylene 0.21 1000 d12-indeno[123-cd]pyrene 1000 100

Benzo[b]fluoranthene 0.07 1000 d14-dibenzo[ah]anthracene 1000 100 Benzo[k]fluoranthene 0.03 1000 d12-benzo[ghi]perylene 1000 100 Benzo[e]pyrene 0.06 1000 d10-Anthracene 1000 100 Benzo[a]pyrene 0.02 1000 d8-Carbazole 1000 100 Perylene 0.02 1000 1000 100 Indeno[1,2,3-cd]pyrene 0.02 1000 Dibenzo[a,h]anthracene 0.02 1000

Benzo[g,h,i]perylene 0.02 1000

Total PAH 2.5 ~4000

I certify that this data package is in compliance with the terms and condition of the contract, both technically and for comple teness, for other than the conditions detailed above. Release of the data contained in this data package (hardcopy and/or electronic version) has been authorized by the Laboratory Manager or his designee, as verified by the following signature.

5-Dec-14 Steve Kennedy Date ALS Project Design 2014 Sample ID 

# SVOC DATA PACKAGE
SECTION 1: PROJECT NARRATIVE

Extraction Standard Spiking

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4



# SVOC DATA PACKAGE

SECTION 2: DATA SUMMARY REPORT

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4 Phone: 905-331-3111, FAX: 905-331-4567

ALS Project Contact: 

## Ron McLeod Client Name: 

## Environmental Quality Management Inc ALS Project ID: 

## EQM100 Client Address: 

## 1800 Carillon Boulevard ALS WO#: 

## L1535265 Cincinnati, OH 45240 Date of Report: 

## 18-Nov-14 Date of Sample Receipt: 

## 20-Oct-14 Client Contact: 

## Tom Gerstle Client Project ID: 

## 050352.0031 Eramet

COMMENTS: PAH via modified CARB 429

The method blank was lost during laboratory processing and has not been reported. The field blank serves as an indication that the sample data are not impacted by significant laboratory background.

Selected targets from selected samples have been reported from the analysis of diluted extracts that have been re-spiked with q uantification standard. As a result, these data are not calculated by isotope dilution and are not inherently recovery-corrected. Reported ex traction standard recoveries for these targets are not indicative of extraction efficiency as they have been spiked after extraction. S.Kennedy 18-Nov-14

Certified by: Whitney Davis A ccount Manager
Results in this certificate relate only to the samples as submitted to the laboratory. This report shall not be reproduced, except in full, without the written permission of ALS Canada Ltd. 

# Certificate of AnalysisSample Name BLANK ACETONE/HEXANE /METH. BLANK FIELD BLANK MAIN BAGHOUSE RUN#1 MAIN BAGHOUSE RUN#2

ALS Sample ID L1535265-11 L1535265-4 L1535265-3 L1535265-1 L1535265-2 Sample Size 11111 Sample units sample train train train train
Moisture Content n/a n/a n/a n/a n/a
Matrix XAD Trap Stack Stack Stack Stack Sampling Date 22-Oct-14 14-Oct-14 14-Oct-14 15-Oct-14 15-Oct-14
Extraction Date 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14

Target Analytes ng ng ng ng ng
Naphthalene 103 2260 9270 471000 458000 2-Me-Naphthalene 12.3 4860 17900 74800 103000 1-Me-Naphthalene 10.2 3910 13600 55200 74800

Acenaphthylene 1.55 157 395 153000 188000

Acenaphthene 1.42 450 1180 32000 43400
Fluorene 6.27 648 1620 70200 121000
Phenanthrene 13.5 3380 12200 2020000 1590000

Anthracene 3.04 140 556 343000 203000
Fluoranthene 1.92 118 554 3620000 4790000 Pyrene 2.97 69.2 522 2600000 3550000 Benz[a]anthracene 4.46 7.33 96.8 268000 570000 Chrysene/Triphenylene 3.33 29.9 225 473000 1250000 Benzo[b]fluoranthene 4.90 614 187 141000 419000 Benzo[k]fluoranthene 2.88 524 51.7 41100 112000 Benzo[e]pyrene 1.74 4.47 109 51900 149000 Benzo[a]pyrene 2.59 <1.8 45.3 22600 60300 Perylene 1.55 <1.3 5.05 4080 8800 Indeno[1,2,3-cd]pyrene 7.92 4.63 30.0 8370 22900 Dibenzo[a,h]anthracene 7.65 1.66 12.4 1190 4120

Benzo[g,h,i]perylene 6.20 3.17 57.1 7330 17700

Field Spike Standards % Rec % Rec % Rec % Rec % Rec

Fluorene-d10 76 n/s 96 111 145 p-Terphenyl-d14 48 n/s 106 73 65

Extraction Standards % Rec % Rec % Rec % Rec % Rec

Naphthalene-d8 72 83 80 100 83 2-Me-Naphthalene-d10 63 84 78 99 67 Acenaphthylene-d8 49 85 81 113 60
Phenanthrene-d10 38 83 85 73 94

Anthracene-d10 40 71 71 78 95
Fluoranthene-d10 45 90 87 81 95 Benz[a]anthracene-d12 20 101 122 66 78 Chrysene-d12 22 75 93 71 79 Benzo[b]fluoranthene-d12 36 103 98 70 94 Benzo[k]fluoranthene-d12 34 77 71 74 99 Benzo[a]pyrene-d12 36 74 66 71 90 Perylene-d12 36 75 69 74 92 Indeno[1,2,3-cd]pyrene-d12 27 88 97 66 92 Dibenzo[a,h]anthracene-d14 25 89 100 64 91

Benzo[g,h,i]perylene-d12 30 86 89 73 101 

# ALS Environmental

Sample Analysis Summary ReportSample Name MAIN BAGHOUSE RUN#3 MAIN BAGHOUSE RUN#4 FURNACE 12 RUN#1 FURNACE 12 RUN#2 FURNACE 12 RUN#3 FURNACE 12 RUN#4

ALS Sample ID L1535265-5 L1535265-6 L1535265-7 L1535265-8 L1535265-9 L1535265-10 Sample Size 111111 Sample units train train train train train train
Moisture Content n/a n/a n/a n/a n/a n/a
Matrix Stack Stack Stack Stack Stack Stack Sampling Date 15-Oct-14 15-Oct-14 16-Oct-14 16-Oct-14 16-Oct-14 16-Oct-14
Extraction Date 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14 28-Oct-14

Target Analytes ng ng ng ng ng ng
Naphthalene 326000 347000 41700 20200 44100 43900 2-Me-Naphthalene 53700 71100 14100 13900 18300 16400 1-Me-Naphthalene 41000 49900 9600 10400 13200 11700

Acenaphthylene 75000 129000 14800 3670 15000 19100

Acenaphthene 19400 20900 1780 1620 2330 2050
Fluorene 41500 70100 2740 2370 3500 3080
Phenanthrene 1590000 1370000 36400 22200 74000 43500

Anthracene 208000 167000 8620 3610 13200 10500
Fluoranthene 4100000 2070000 36800 11800 64500 30400 Pyrene 2990000 1430000 26800 7950 46900 23100 Benz[a]anthracene 707000 177000 3530 3350 3510 3290 Chrysene/Triphenylene 1480000 461000 13800 9990 10600 5200 Benzo[b]fluoranthene 614000 178000 5170 5290 5060 3160 Benzo[k]fluoranthene 207000 59300 1950 2630 1880 1250 Benzo[e]pyrene 233000 75000 2540 2770 2150 1660 Benzo[a]pyrene 121000 30000 831 457 510 681 Perylene 20600 6220 107 87.8 60.4 133 Indeno[1,2,3-cd]pyrene 40300 11200 1060 1170 651 980 Dibenzo[a,h]anthracene 5890 1980 207 324 129 204

Benzo[g,h,i]perylene 27600 8400 821 751 528 807

Field Spike Standards % Rec % Rec % Rec % Rec % Rec % Rec

Fluorene-d10 104 125 118 109 114 104 p-Terphenyl-d14 87 85 115 85 113 85

Extraction Standards % Rec % Rec % Rec % Rec % Rec % Rec

Naphthalene-d8 97 103 68 90 105 95 2-Me-Naphthalene-d10 116 90 71 91 70 71 Acenaphthylene-d8 104 92 75 88 72 68
Phenanthrene-d10 81 81 108 81 105 77

Anthracene-d10 84 86 103 99 109 81
Fluoranthene-d10 84 87 120 103 102 87 Benz[a]anthracene-d12 71 73 108 64 103 44 Chrysene-d12 73 78 71 48 74 35 Benzo[b]fluoranthene-d12 79 80 96 87 95 67 Benzo[k]fluoranthene-d12 86 81 72 57 94 54 Benzo[a]pyrene-d12 82 78 73 78 72 56 Perylene-d12 81 80 76 81 74 57 Indeno[1,2,3-cd]pyrene-d12 70 76 92 90 97 58 Dibenzo[a,h]anthracene-d14 72 73 95 91 101 56

Benzo[g,h,i]perylene-d12 80 85 92 91 95 55 

# ALS Environmental

Sample Analysis Summary ReportSample Name Laborator y Control Sample

ALS Sample ID WG1980014-2 Sample Size 1 Sample units n/a
Moisture Content n/a
Matrix QC Sampling Date n/a
Extraction Date 28-Oct-14

Target Analytes % Rec

Naphthalene 123 2-Me-Naphthalene n/s 1-Me-Naphthalene n/s

Acenaphthylene 98

Acenaphthene 103
Fluorene 105
Phenanthrene 99

Anthracene 101
Fluoranthene 102 Pyrene 92 Benz[a]anthracene 103 Chrysene/Triphenylene 97 Benzo[b]fluoranthene 109 Benzo[k]fluoranthene 103 Benzo[e]pyrene n/s Benzo[a]pyrene 89 Perylene n/s Indeno[1,2,3-cd]pyrene 111 Dibenzo[a,h]anthracene 104

Benzo[g,h,i]perylene 104

Field Spike Standards % Rec

Fluorene-d10 n/s p-Terphenyl-d14 n/s

Extraction Standards % Rec

Naphthalene-d8 85 2-Me-Naphthalene-d10 81 Acenaphthylene-d8 84
Phenanthrene-d10 80

Anthracene-d10 74
Fluoranthene-d10 91 Benz[a]anthracene-d12 56 Chrysene-d12 50 Benzo[b]fluoranthene-d12 85 Benzo[k]fluoranthene-d12 79 Benzo[a]pyrene-d12 75 Perylene-d12 79 Indeno[1,2,3-cd]pyrene-d12 79 Dibenzo[a,h]anthracene-d14 80

Benzo[g,h,i]perylene-d12 81 

# ALS Environmental

Quality Control Sample Analysis Summary ReportSample Name CCV CCV CCV

ALS Sample ID H4-14-CCV-0452 H4-14-CCV-0453 H4-14-CCV-0454 Sample Size 111 Sample units n/a n/a n/a
Moisture Content n/a n/a n/a
Matrix QC QC QC Sampling Date n/a n/a n/a
Extraction Date n/a n/a n/a

Target Analytes % Rec % Rec % Rec

Naphthalene 88 87 77 2-Me-Naphthalene 98 95 88 1-Me-Naphthalene 100 98 88

Acenaphthylene 93 92 84

Acenaphthene 99 100 97
Fluorene 96 101 132
Phenanthrene 87 86 85

Anthracene 88 93 88
Fluoranthene 89 92 81 Pyrene 88 91 81 Benz[a]anthracene 84 90 76 Chrysene/Triphenylene 96 88 82 Benzo[b]fluoranthene 90 100 89 Benzo[k]fluoranthene 101 97 96 Benzo[e]pyrene 88 90 85 Benzo[a]pyrene 91 91 85 Perylene 94 95 92 Indeno[1,2,3-cd]pyrene 91 92 77 Dibenzo[a,h]anthracene 103 104 90

Benzo[g,h,i]perylene 96 94 84

Field Spike Standards % Rec % Rec % Rec

Fluorene-d10 100 101 141 p-Terphenyl-d14 113 115 120

Extraction Standards % Rec % Rec % Rec

Naphthalene-d8 103 95 81 2-Me-Naphthalene-d10 101 95 97 Acenaphthylene-d8 97 91 87
Phenanthrene-d10 100 91 76

Anthracene-d10 106 91 84
Fluoranthene-d10 101 96 101 Benz[a]anthracene-d12 102 93 66 Chrysene-d12 101 100 83 Benzo[b]fluoranthene-d12 102 91 80 Benzo[k]fluoranthene-d12 96 93 90 Benzo[a]pyrene-d12 95 96 99 Perylene-d12 103 102 107 Indeno[1,2,3-cd]pyrene-d12 109 117 139 Dibenzo[a,h]anthracene-d14 122 130 167

Benzo[g,h,i]perylene-d12 111 117 143 

# ALS Environmental

Continuing Calibration Verification Summary ReportSam p le Name Sam p lin g Date ALS Sam p le ID L1535265-11 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A1 5 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units n g Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Tar g et Anal y tes Time n g n g
Naphthalene 7:33 103 1.3 M 2-Me-Naphthalene 8:44 12.3 0.25 M J 1-Me-Naphthalene 8:54 10.2 0.26 M J

Acenaphthylene 10:10 1.55 0.072 M J

Acenaphthene 10:27 1.42 0.22 J
Fluorene 11:18 6.27 0.48 M J
Phenanthrene 12:51 13.5 0.40 M J

Anthracene 12:56 3.04 0.52 M J
Fluoranthene 14:47 1.92 0.38 M J Pyrene 15:09 2.97 0.36 M J Benz[a]anthracene 17:32 4.46 0.22 M J Chrysene/Triphenylene 17:37 3.33 0.22 M J

Benzo[b]fluoranthene 19:44 4.90 0.64 M J Benzo[k]fluoranthene 19:47 2.88 0.69 M J Benzo[e]pyrene 20:14 1.74 0.75 M J Benzo[a]pyrene 20:21 2.59 0.78 M J Perylene 20:30 1.55 0.60 M J Indeno[1,2,3-cd]pyrene 22:22 7.92 1.4 M J Dibenzo[a,h]anthracene 22:26 7.65 1.3 M J

Benzo[g,h,i]perylene 22:46 6.20 0.74 M J

Field Spike Standards % Rec Limits

Fluorene-d10 11:15 76 50-150 p-Terphenyl-d14 15:34 48 50-150

Extraction Standards % Rec Limits

Naphthalene-d8 7:31 72 20-150 2-Me-Naphthalene-d10 8:40 63 20-150 Acenaphthylene-d8 10:08 49 20-150
Phenanthrene-d10 12:48 38 30-150

Anthracene-d10 12:53 40 30-150
Fluoranthene-d10 14:45 45 30-150 Benz[a]anthracene-d12 17:29 20 30-150 Chrysene-d12 17:33 22 30-150 Benzo[b]fluoranthene-d12 19:41 36 30-150 Benzo[k]fluoranthene-d12 19:44 34 30-150 Benzo[a]pyrene-d12 20:17 36 30-150 Perylene-d12 20:27 36 30-150 Indeno[1,2,3-cd]pyrene-d12 22:20 27 30-150 Dibenzo[a,h]anthracene-d14 22:23 25 30-150

Benzo[g,h,i]perylene-d12 22:44 30 30-150

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

BLAN K 22-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 sam p le Ella Gd y cz y nski n/a --e-si g nature-- XAD Trap 10 17-Nov-2014

15-Nov-14 20:44

FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 4 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A1 6 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units n g Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Tar g et Anal y tes Time n g n g
Naphthalene 7:33 2260 16 M 2-Me-Naphthalene 8:42 4860 7.2 1-Me-Naphthalene 8:52 3910 7.6

Acenaphthylene 10:09 157 1.4 M

Acenaphthene 10:26 450 3.4 M
Fluorene 11:17 648 1.6 M
Phenanthrene 12:50 3380 2.2 M

Anthracene 12:55 140 2.6 M
Fluoranthene 14:46 118 0.92 M Pyrene 15:09 69.2 0.86 M J Benz[a]anthracene 17:32 7.33 0.40 M J Chrysene/Triphenylene 17:35 29.9 0.43 M J

Benzo[b]fluoranthene 19:45 614 1.3 M Benzo[k]fluoranthene 19:47 524 1.6 M Benzo[e]pyrene 20:15 4.47 1.7 M J Benzo[a]pyrene NotFnd <1.8 1.8 M U Perylene NotFnd <1.3 1.3 M U Indeno[1,2,3-cd]pyrene 22:22 4.63 0.90 M J Dibenzo[a,h]anthracene 22:26 1.66 0.45 M J

Benzo[g,h,i]perylene 22:46 3.17 0.55 M J

Field Spike Standards % Rec Limits

Fluorene-d10 11:14 n/s p-Terphenyl-d14 15:34 n/s

Extraction Standards % Rec Limits

Naphthalene-d8 7:31 83 20-150 2-Me-Naphthalene-d10 8:39 84 20-150 Acenaphthylene-d8 10:08 85 20-150
Phenanthrene-d10 12:47 83 30-150

Anthracene-d10 12:52 71 30-150
Fluoranthene-d10 14:44 90 30-150 Benz[a]anthracene-d12 17:29 101 30-150 Chrysene-d12 17:32 75 30-150 Benzo[b]fluoranthene-d12 19:40 103 30-150 Benzo[k]fluoranthene-d12 19:44 77 30-150 Benzo[a]pyrene-d12 20:17 74 30-150 Perylene-d12 20:27 75 30-150 Indeno[1,2,3-cd]pyrene-d12 22:19 88 30-150 Dibenzo[a,h]anthracene-d14 22:22 89 30-150

Benzo[g,h,i]perylene-d12 22:44 86 30-150

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated. U Indicates that this com p ound was not detected above the MDL. n/s Indicates that this standard has not been s p iked. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

ACETONE/HEXANE/METH. BLANK 14-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 10 17-Nov-2014

15-Nov-14 21:18

FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 3 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A1 7 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units n g Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Tar g et Anal y tes Time n g n g
Naphthalene 7:35 9270 39 M 2-Me-Naphthalene 8:43 17900 2.5 1-Me-Naphthalene 8:53 13600 2.6

Acenaphthylene 10:10 395 1.4 M

Acenaphthene 10:27 1180 6.5 M
Fluorene 11:17 1620 2.9 M
Phenanthrene 12:50 12200 8.3 M

Anthracene 12:55 556 10 M
Fluoranthene 14:47 554 1.8 M Pyrene 15:09 522 1.7 M Benz[a]anthracene 17:32 96.8 1.2 M J Chrysene/Triphenylene 17:36 225 1.3 M

Benzo[b]fluoranthene 19:43 187 0.61 M Benzo[k]fluoranthene 19:46 51.7 0.70 M J Benzo[e]pyrene 20:14 109 0.85 M Benzo[a]pyrene 20:20 45.3 0.89 M J Perylene 20:30 5.05 0.61 M J Indeno[1,2,3-cd]pyrene 22:22 30.0 2.1 M J Dibenzo[a,h]anthracene 22:26 12.4 0.98 M J

Benzo[g,h,i]perylene 22:47 57.1 1.4 M J

Field Spike Standards % Rec Limits

Fluorene-d10 11:14 96 50-150 p-Terphenyl-d14 15:34 106 50-150

Extraction Standards % Rec Limits

Naphthalene-d8 7:33 80 20-150 2-Me-Naphthalene-d10 8:40 78 20-150 Acenaphthylene-d8 10:08 81 20-150
Phenanthrene-d10 12:48 85 30-150

Anthracene-d10 12:53 71 30-150
Fluoranthene-d10 14:45 87 30-150 Benz[a]anthracene-d12 17:29 122 30-150 Chrysene-d12 17:32 93 30-150 Benzo[b]fluoranthene-d12 19:40 98 30-150 Benzo[k]fluoranthene-d12 19:44 71 30-150 Benzo[a]pyrene-d12 20:17 66 30-150 Perylene-d12 20:27 69 30-150 Indeno[1,2,3-cd]pyrene-d12 22:19 97 30-150 Dibenzo[a,h]anthracene-d14 22:22 100 30-150

Benzo[g,h,i]perylene-d12 22:43 89 30-150

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

FIELD BLAN K 14-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 10 17-Nov-2014

15-Nov-14 21:52

FlagsSample Name Samplin g Date ALS Sample ID L1535265-1 Extraction Date Analysis Method Sample Size Ana l ysis Type Samp l e Moisture Conten t Sample Matrix Split Ratio

Run Information Run 1 Run 2 Run 3

Filename 4-141115B17 4-141115B04 4-141115A19 Run Date Final Volume 1000 u L 1000 u L 1000 u L Dilution Facto r 1 10 100 Analysis Units n g n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Ret. Conc. EDL Tar g et Analytes Time n g n g Time. n g n g Time. n g n g
Naphthalene 7:33 471000 390 7:34 604000 1400 7:34 686000 5800 M 2-Me-Naphthalene 8:43 74800 58 M 8:43 117000 170 8:43 141000 4100 J 1-Me-Naphthalene 8:52 55200 60 M 8:52 94800 180 8:52 126000 4300 J

Acenaphthylene 10:10 153000 19 M 10:10 255000 360 M 10:09 238000 1800 M J

Acenaphthene 10:27 32000 130 M 10:27 53700 530 M 10:27 44400 2500 M J
Fluorene 11:18 70200 110 M 11:19 102000 450 M 11:18 104000 2400 M J
Phenanthrene 12:50 1130000 93 M E 12:50 2020000 130 M 12:50 1970000 2600 M

Anthracene 12:55 129000 96 M 12:55 343000 150 M 12:55 385000 3300 M J
Fluoranthene 14:47 2000000 260 M E 14:47 3620000 1600 M 14:46 3810000 3600 M Pyrene 15:10 1670000 250 M E 15:09 2600000 1500 M 15:09 2780000 3300 M Benz[a]anthracene 17:33 153000 99 M 17:32 268000 1200 M 17:32 220000 3700 M J Chrysene/Triphenylene 17:36 314000 100 M 17:36 473000 1100 M 17:36 470000 3200 M J

Benzo[b]fluoranthene 19:44 79700 90 M 19:44 141000 340 M 19:44 116000 1100 M J Benzo[k]fluoranthene 19:47 36200 92 M 19:46 41100 380 M J 19:46 51100 1100 M J Benzo[e]pyrene 20:15 10800 26 M 20:14 51900 390 M 20:14 53600 1200 M J Benzo[a]pyrene 20:21 5150 28 M 20:21 22600 410 M J 20:21 23300 1200 M J Perylene 20:31 2500 48 M J 20:30 4080 300 M J 20:31 6630 710 M J Indeno[1,2,3-cd]pyrene NotFnd <34000 34000 M U 22:22 8370 380 M J 22:22 8760 3000 M J Dibenzo[a,h]anthracene 22:27 885 220 M J 22:26 1190 250 M J 22:28 3790 2300 M J

Benzo[g,h,i]perylene 22:48 4620 120 M J 22:46 7330 190 M J 22:47 7050 1500 M J

Field Spike Standards % Rec Limits % Rec % Rec

Fluorene-d10 11:15 111 50-150 11:15 141 11:15 222 p-Terphenyl-d14 15:34 73 50-150 15:34 158 15:34 59

Extraction Standards % Rec Limits % Rec % Rec

Naphthalene-d8 7:32 100 20-150 7:32 77 7:32 80 2-Me-Naphthalene-d10 8:40 99 20-150 8:40 70 8:40 68 Acenaphthylene-d8 10:08 113 20-150 10:08 75 10:08 80
Phenanthrene-d10 12:48 119 30-150 12:48 73 12:48 64

Anthracene-d10 12:53 128 30-150 12:53 78 12:53 63
Fluoranthene-d10 14:45 131 30-150 14:45 81 14:45 67 Benz[a]anthracene-d12 17:30 66 30-150 17:29 66 17:29 52 Chrysene-d12 17:33 57 30-150 17:32 71 17:33 73 Benzo[b]fluoranthene-d12 19:41 121 30-150 19:41 70 19:40 67 Benzo[k]fluoranthene-d12 19:44 100 30-150 19:44 74 19:44 67 Benzo[a]pyrene-d12 20:18 316 30-150 20:17 71 20:18 73 Perylene-d12 20:28 147 30-150 20:27 74 20:27 70 Indeno[1,2,3-cd]pyrene-d12 22:15 76 30-150 22:20 66 22:20 65 Dibenzo[a,h]anthracene-d14 22:25 37 M 30-150 22:23 64 22:24 61

Benzo[g,h,i]perylene-d12 22:45 105 30-150 22:44 73 22:44 83

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sample. M Indicates that a peak has been manually inte g rated. U Indicates that this compound was not detected above the MDL. E Indicates that this compound was detected above the calibrated ran g e. J indicates that a tar g et analyte was detected below the LQL

. 

# ALS Environmental

Sam p le Anal y sis Re p or t

MAIN BAGHOUSE RUN#1 15-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gdyczynski n/a --e-si g nature--
Stack 500 17-Nov-2014

16-Nov-14 11:01 16-Nov-14 03:35 15-Nov-14 23:01

Flags Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 2 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2 Run 3

Filename 4-141115B1 8 4-141115B0 5 4-141115A2 0 Run Date Final Volume 1000 u L 1000 u L 1000 u L Dilution Factor 1 10 100 Anal y sis Units n g n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g Time. n g n g
Naphthalene 7:34 458000 240 M 7:34 437000 700 7:35 570000 4400 M 2-Me-Naphthalene 8:43 103000 36 8:43 79900 180 8:44 107000 2800 J 1-Me-Naphthalene 8:52 74800 38 8:53 65500 190 8:53 83800 2900 J

Acenaphthylene 10:10 188000 110 M 10:10 156000 500 M 10:09 147000 830 M J

Acenaphthene 10:27 43400 52 M 10:27 32900 120 J 10:28 32700 1100 M J
Fluorene 11:19 121000 140 M 11:19 57300 120 M 11:18 71300 1900 M J
Phenanthrene 12:50 2480000 220 M E 12:50 1590000 790 M 12:51 1600000 2300 M

Anthracene 12:55 205000 250 M 12:55 203000 970 M 12:55 261000 3300 M J
Fluoranthene 14:47 5300000 450 M E 14:47 4790000 1900 M 14:47 4050000 570 M Pyrene 15:10 4720000 420 M E 15:10 3550000 1700 M 15:09 3210000 530 M Benz[a]anthracene 17:32 1120000 670 M E 17:32 570000 370 M 17:32 466000 2500 M J Chrysene/Triphenylene 17:36 2400000 600 M E 17:36 1250000 350 M 17:32 536000 2800 M

Benzo[b]fluoranthene 19:44 776000 180 M E 19:44 419000 440 M 19:44 400000 3700 M J Benzo[k]fluoranthene 19:47 152000 120 M 19:47 112000 480 M 19:47 126000 4300 M J Benzo[e]pyrene 20:15 88000 41 M 20:14 149000 540 M 20:15 142000 4000 M J Benzo[a]pyrene 20:21 38700 43 M 20:20 60300 560 M 20:21 71400 4200 M J Perylene 20:31 16200 95 M 20:30 8800 440 M J 20:30 5550 3100 M J Indeno[1,2,3-cd]pyrene 22:23 46800 150 M 22:22 22900 620 M J 22:22 26600 3600 M J Dibenzo[a,h]anthracene 22:27 8480 210 M 22:27 4120 200 M J 22:27 5290 2200 M J

Benzo[g,h,i]perylene 22:48 29100 140 M 22:46 17700 320 M J 22:46 18000 1600 M J

Field Spike Standards % Rec Limits % Rec % Rec

Fluorene-d10 11:15 175 50-150 11:15 145 11:16 60 p-Terphenyl-d14 15:35 173 50-150 15:35 65 15:36 186

Extraction Standards % Rec Limits % Rec % Rec

Naphthalene-d8 7:32 83 20-150 7:32 94 7:32 97 2-Me-Naphthalene-d10 8:40 67 20-150 8:40 98 8:40 87 Acenaphthylene-d8 10:08 60 20-150 10:08 88 10:08 93
Phenanthrene-d10 12:48 54 30-150 12:48 94 12:48 78

Anthracene-d10 12:53 52 30-150 12:53 95 12:53 84
Fluoranthene-d10 14:45 52 30-150 14:45 95 14:45 102 Benz[a]anthracene-d12 17:29 27 30-150 17:29 78 17:30 80 Chrysene-d12 17:33 28 30-150 17:32 79 17:30 48 Benzo[b]fluoranthene-d12 19:41 47 M 30-150 19:40 94 19:41 79 Benzo[k]fluoranthene-d12 19:44 68 M 30-150 19:44 99 19:44 85 Benzo[a]pyrene-d12 20:18 136 M 30-150 20:17 90 20:18 86 Perylene-d12 20:28 50 M 30-150 20:27 92 20:27 88 Indeno[1,2,3-cd]pyrene-d12 22:21 33 M 30-150 22:19 92 22:20 87 Dibenzo[a,h]anthracene-d14 22:25 33 M 30-150 22:23 91 22:23 81

Benzo[g,h,i]perylene-d12 22:45 39 M 30-150 22:44 101 22:44 111

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN#2 15-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 500 17-Nov-2014

16-Nov-14 11:36 16-Nov-14 04:10 15-Nov-14 23:35

Flags Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 5 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2 Run 3

Filename 4-141115B1 9 4-141115B0 6 4-141115A21 Run Date Final Volume 1000 u L 1000 u L 1000 u L Dilution Factor 1 10 100 Anal y sis Units n g n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g Time. n g n g
Naphthalene 7:34 326000 97 7:33 445000 860 7:34 530000 11000 2-Me-Naphthalene 8:44 53700 19 8:43 88100 440 8:44 106000 2900 J 1-Me-Naphthalene 8:53 41000 20 8:52 65400 460 8:53 93800 3100 J

Acenaphthylene 10:11 75000 59 10:09 125000 270 M 10:10 120000 1900 M J

Acenaphthene 10:27 19400 19 M 10:26 26600 340 M J 10:27 25900 2000 M J
Fluorene 11:18 41500 65 M 11:18 58100 310 M 11:19 60300 2200 M J
Phenanthrene 12:50 1090000 97 M E 12:49 1590000 130 M 12:51 1570000 7600 M

Anthracene 12:55 95500 110 M 12:54 208000 160 M 12:55 358000 12000 M J
Fluoranthene 14:47 2300000 140 M E 14:46 4100000 620 M 14:47 3340000 7500 M Pyrene 15:10 1940000 130 M E 15:09 2990000 580 M 15:10 2600000 7000 M Benz[a]anthracene 17:32 584000 51 M 17:31 707000 200 M 17:33 640000 2000 M Chrysene/Triphenylene 17:37 1290000 47 M E 17:35 1480000 190 M 17:36 1640000 1800 M

Benzo[b]fluoranthene 19:44 481000 89 M E 19:44 614000 320 M 19:44 634000 4400 M Benzo[k]fluoranthene 19:47 164000 86 M 19:45 207000 320 M 19:47 206000 5000 M J Benzo[e]pyrene 20:15 72900 35 M 20:14 233000 380 M 20:15 245000 5600 M J Benzo[a]pyrene 20:21 38500 36 M 20:20 121000 390 M 20:21 126000 5800 M J Perylene 20:31 16800 82 20:30 20600 290 M J 20:31 23900 3900 M J Indeno[1,2,3-cd]pyrene 22:23 27200 310 M 22:21 40300 490 M J 22:23 30300 4500 M J Dibenzo[a,h]anthracene 22:27 5510 200 M 22:26 5890 260 M J 22:28 7220 3400 M J

Benzo[g,h,i]perylene 22:48 16000 200 M 22:46 27600 250 M J 22:47 25500 2000 M J

Field Spike Standards % Rec Limits % Rec % Rec

Fluorene-d10 11:15 104 50-150 11:14 131 11:15 142 p-Terphenyl-d14 15:35 87 50-150 15:34 176 15:37 67

Extraction Standards % Rec Limits % Rec % Rec

Naphthalene-d8 7:32 97 20-150 7:31 85 7:32 94 2-Me-Naphthalene-d10 8:40 116 20-150 8:40 86 8:40 78 Acenaphthylene-d8 10:09 104 20-150 10:08 81 10:09 84
Phenanthrene-d10 12:48 119 30-150 12:47 81 12:48 75

Anthracene-d10 12:53 105 30-150 12:53 84 12:54 69
Fluoranthene-d10 14:45 109 30-150 14:44 84 14:45 93 Benz[a]anthracene-d12 17:29 80 30-150 17:28 71 17:30 69 Chrysene-d12 17:33 71 30-150 17:32 73 17:33 81 Benzo[b]fluoranthene-d12 19:41 105 M 30-150 19:40 79 19:41 73 Benzo[k]fluoranthene-d12 19:44 99 M 30-150 19:44 86 19:45 80 Benzo[a]pyrene-d12 20:17 233 M 30-150 20:17 82 20:18 80 Perylene-d12 20:23 90 M 30-150 20:27 81 20:28 83 Indeno[1,2,3-cd]pyrene-d12 22:21 87 30-150 22:19 70 22:20 76 Dibenzo[a,h]anthracene-d14 22:25 70 30-150 22:22 72 22:24 70

Benzo[g,h,i]perylene-d12 22:45 121 30-150 22:43 80 22:44 85

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN#3 15-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 500 17-Nov-2014

16-Nov-14 12:10 16-Nov-14 04:44 16-Nov-14 00:09

Flags Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 6 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B2 0 4-141115B0 7 Run Date Final Volume 1000 u L 1000 u L Dilution Factor 1 10 Anal y sis Units n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g
Naphthalene 7:33 347000 200 7:34 487000 820 2-Me-Naphthalene 8:43 71100 31 8:44 88700 190 1-Me-Naphthalene 8:52 49900 33 8:52 67900 190

Acenaphthylene 10:09 129000 28 M 10:09 188000 360 M

Acenaphthene 10:27 20900 120 M 10:27 29500 170 M J
Fluorene 11:18 70100 39 M 11:19 83400 230 M
Phenanthrene 12:50 1320000 100 M E 12:51 1370000 260 M

Anthracene 12:54 104000 120 M 12:55 167000 330 M
Fluoranthene 14:47 1820000 74 M E 14:47 2070000 810 M Pyrene 15:09 1460000 69 M E 15:09 1430000 750 M Benz[a]anthracene 17:32 176000 92 M 17:32 177000 230 M Chrysene/Triphenylene 17:36 394000 79 M 17:36 461000 220 M

Benzo[b]fluoranthene 19:44 158000 440 M 19:44 178000 240 M Benzo[k]fluoranthene 19:46 59100 510 M 19:46 59300 250 M Benzo[e]pyrene 20:14 35200 240 M 20:15 75000 270 M Benzo[a]pyrene 20:21 14500 240 M 20:21 30000 280 M J Perylene 20:30 3510 340 M J 20:30 6220 220 M J Indeno[1,2,3-cd]pyrene 22:23 12800 120 M 22:22 11200 280 M J Dibenzo[a,h]anthracene 22:28 1900 97 M J 22:26 1980 240 J

Benzo[g,h,i]perylene 22:48 9830 68 M 22:47 8400 140 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 125 50-150 11:16 159 p-Terphenyl-d14 15:34 85 50-150 15:34 34

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:31 103 20-150 7:32 86 2-Me-Naphthalene-d10 8:40 90 20-150 8:40 84 Acenaphthylene-d8 10:08 92 20-150 10:08 81
Phenanthrene-d10 12:48 92 30-150 12:48 81

Anthracene-d10 12:53 92 30-150 12:53 86
Fluoranthene-d10 14:44 95 30-150 14:45 87 Benz[a]anthracene-d12 17:29 52 30-150 17:29 73 Chrysene-d12 17:32 53 30-150 17:33 78 Benzo[b]fluoranthene-d12 19:41 81 M 30-150 19:41 80 Benzo[k]fluoranthene-d12 19:44 74 M 30-150 19:44 81 Benzo[a]pyrene-d12 20:20 142 M 30-150 20:17 78 Perylene-d12 20:27 104 M 30-150 20:27 80 Indeno[1,2,3-cd]pyrene-d12 22:21 52 30-150 22:19 76 Dibenzo[a,h]anthracene-d14 22:24 51 30-150 22:23 73

Benzo[g,h,i]perylene-d12 22:45 57 30-150 22:44 85

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

MAIN BAGHOUSE RUN# 4 15-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 500 17-Nov-2014

16-Nov-14 12:44 16-Nov-14 05:18

Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 7 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B1 2 4-141115B0 8 Run Date Final Volume 1000 u L 1000 u L Dilution Factor 1 50 Anal y sis Units n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g
Naphthalene 7:34 41700 41 M 7:33 37700 61 M 2-Me-Naphthalene 8:43 14100 17 8:43 14500 11 1-Me-Naphthalene 8:53 9600 18 8:52 12700 11

Acenaphthylene 10:10 14800 2.9 M 10:10 12100 26 M

Acenaphthene 10:27 1780 1.5 M 10:27 1950 34 M J
Fluorene 11:18 2740 15 M 11:19 2540 49 M J
Phenanthrene 12:50 30000 6.6 M E 12:51 36400 15 M

Anthracene 12:55 4750 7.3 M 12:56 8620 21 M
Fluoranthene 14:47 38100 7.9 M E 14:47 36800 26 M Pyrene 15:10 31400 7.4 M E 15:09 26800 24 M Benz[a]anthracene 17:32 3530 3.7 M 17:33 2190 53 M J Chrysene/Triphenylene 17:36 13800 4.0 M 17:33 2520 61 M J

Benzo[b]fluoranthene 19:44 5170 1.4 M 19:45 4060 18 M J Benzo[k]fluoranthene 19:47 1950 1.5 M 19:47 2940 24 M J Benzo[e]pyrene 20:15 2540 1.8 M 20:15 842 5.5 M J Benzo[a]pyrene 20:21 831 1.8 M 20:22 108 5.7 M J Perylene 20:31 107 1.4 M 20:30 85.2 12 M J Indeno[1,2,3-cd]pyrene 22:22 1060 0.62 M 22:25 1040 26 M J Dibenzo[a,h]anthracene 22:26 207 0.83 M 22:27 216 28 M J

Benzo[g,h,i]perylene 22:47 821 0.36 M 22:48 579 14 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 118 50-150 11:15 94 p-Terphenyl-d14 15:34 115 50-150 15:35 78

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 68 20-150 7:31 119 2-Me-Naphthalene-d10 8:41 71 20-150 8:40 100 Acenaphthylene-d8 10:09 75 20-150 10:08 108
Phenanthrene-d10 12:48 79 30-150 12:48 108

Anthracene-d10 12:53 69 30-150 12:53 103
Fluoranthene-d10 14:45 82 30-150 14:45 120 Benz[a]anthracene-d12 17:29 108 30-150 17:30 67 Chrysene-d12 17:33 71 30-150 17:30 41 Benzo[b]fluoranthene-d12 19:41 96 30-150 19:42 103 M Benzo[k]fluoranthene-d12 19:44 72 30-150 19:46 74 M Benzo[a]pyrene-d12 20:17 73 30-150 20:17 354 M Perylene-d12 20:27 76 30-150 20:28 101 M Indeno[1,2,3-cd]pyrene-d12 22:20 92 30-150 22:21 67 M Dibenzo[a,h]anthracene-d14 22:23 95 30-150 22:24 26

Benzo[g,h,i]perylene-d12 22:44 92 30-150 22:45 113

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#1 16-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 10 17-Nov-2014

16-Nov-14 08:10 16-Nov-14 05:52

Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 8 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B1 3 4-141115B0 9 Run Date Final Volume 1000 u L 1000 u L Dilution Factor 1 50 Anal y sis Units n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g
Naphthalene 7:34 26400 63 E 7:33 20200 200 2-Me-Naphthalene 8:44 13900 3.4 8:43 13200 18 1-Me-Naphthalene 8:53 10400 3.5 8:52 12600 19

Acenaphthylene 10:10 3670 3.2 M 10:09 3480 18 M J

Acenaphthene 10:28 1620 1.9 10:26 1630 16 M J
Fluorene 11:18 2370 5.3 M 11:17 2860 34 M J
Phenanthrene 12:51 22700 7.8 M E 12:51 22200 63 M

Anthracene 12:55 1820 9.8 M 12:54 3610 76 M J
Fluoranthene 14:47 11800 4.1 M 14:47 10700 4.5 Pyrene 15:10 7950 3.8 M 15:10 8380 4.2 M Benz[a]anthracene 17:32 3350 4.7 M 17:34 3330 11 M J Chrysene/Triphenylene 17:37 9990 5.0 M 17:37 9600 8.7 M

Benzo[b]fluoranthene 19:44 5460 3.2 M E 19:44 5290 34 M Benzo[k]fluoranthene 19:47 1600 3.6 M 19:48 2630 39 M J Benzo[e]pyrene 20:15 2770 4.9 M 20:14 1560 8.0 M J Benzo[a]pyrene 20:21 457 5.1 M 20:21 132 8.3 M J Perylene 20:31 87.8 3.6 M J 20:30 163 17 M J Indeno[1,2,3-cd]pyrene 22:23 1170 3.8 M 22:24 816 52 M J Dibenzo[a,h]anthracene 22:26 324 1.3 M 22:26 95.0 54 J

Benzo[g,h,i]perylene 22:48 751 2.2 M 22:48 856 37 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 109 50-150 11:14 117 p-Terphenyl-d14 15:34 85 50-150 15:34 93

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 84 20-150 7:31 90 2-Me-Naphthalene-d10 8:41 91 20-150 8:40 83 Acenaphthylene-d8 10:09 88 20-150 10:08 91
Phenanthrene-d10 12:48 91 30-150 12:48 81

Anthracene-d10 12:53 76 30-150 12:53 99
Fluoranthene-d10 14:45 103 30-150 14:45 100 Benz[a]anthracene-d12 17:29 64 30-150 17:30 40 Chrysene-d12 17:33 48 30-150 17:33 56 Benzo[b]fluoranthene-d12 19:41 104 30-150 19:42 87 Benzo[k]fluoranthene-d12 19:44 93 30-150 19:42 57 Benzo[a]pyrene-d12 20:18 78 30-150 20:18 158 M Perylene-d12 20:27 81 30-150 20:27 46 M Indeno[1,2,3-cd]pyrene-d12 22:20 90 30-150 22:21 53 M Dibenzo[a,h]anthracene-d14 22:23 91 30-150 22:27 49 M

Benzo[g,h,i]perylene-d12 22:44 91 30-150 22:45 60 M

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated.

E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#2 16-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 10 17-Nov-2014

16-Nov-14 08:44 16-Nov-14 06:27

Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265- 9 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B1 5 4-141115B1 4 Run Date Final Volume 1000 u L 1000 u L Dilution Factor 1 50 Anal y sis Units n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g
Naphthalene 7:35 42000 51 E 7:33 44100 190 M 2-Me-Naphthalene 8:43 18300 2.9 8:43 16000 19 1-Me-Naphthalene 8:53 13200 3.0 8:52 13700 19

Acenaphthylene 10:10 15000 3.8 M 10:09 12700 10 M

Acenaphthene 10:27 2330 1.4 M 10:27 2570 31 M J
Fluorene 11:18 3500 8.0 M 11:18 4220 32 M J
Phenanthrene 12:50 36200 4.3 M E 12:50 74000 25 M

Anthracene 12:55 5970 4.6 M 12:56 13200 31 M
Fluoranthene 14:47 43800 12 M E 14:47 64500 58 M Pyrene 15:10 37700 11 M E 15:09 46900 54 M Benz[a]anthracene 17:33 3510 1.3 M 17:33 2180 20 M J Chrysene/Triphenylene 17:36 10600 1.5 M 17:36 9520 18 M

Benzo[b]fluoranthene 19:44 5080 1.2 M E 19:45 5060 60 M Benzo[k]fluoranthene 19:47 1310 1.3 M 19:47 1880 50 M J Benzo[e]pyrene 20:15 2150 1.5 M 20:14 959 59 M J Benzo[a]pyrene 20:21 510 1.5 M 20:22 189 62 M J Perylene 20:31 60.4 1.1 M J 20:31 <220 220 M U Indeno[1,2,3-cd]pyrene 22:22 651 0.74 M 22:23 597 44 M J Dibenzo[a,h]anthracene 22:26 129 1.2 M 22:28 198 57 M J

Benzo[g,h,i]perylene 22:47 528 0.45 M 22:48 505 22 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 114 50-150 11:15 135 p-Terphenyl-d14 15:34 113 50-150 15:34 103

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 65 20-150 7:31 105 2-Me-Naphthalene-d10 8:40 70 20-150 8:40 110 Acenaphthylene-d8 10:09 72 20-150 10:08 104
Phenanthrene-d10 12:48 77 30-150 12:48 105

Anthracene-d10 12:54 69 30-150 12:53 109
Fluoranthene-d10 14:45 80 30-150 14:45 102 Benz[a]anthracene-d12 17:29 103 30-150 17:29 72 Chrysene-d12 17:33 74 30-150 17:33 81 Benzo[b]fluoranthene-d12 19:41 85 30-150 19:41 95 M Benzo[k]fluoranthene-d12 19:45 69 30-150 19:45 94 M Benzo[a]pyrene-d12 20:18 72 30-150 20:16 268 M Perylene-d12 20:27 74 30-150 20:27 115 M Indeno[1,2,3-cd]pyrene-d12 22:20 97 30-150 22:21 91 M Dibenzo[a,h]anthracene-d14 22:23 101 30-150 22:25 56

Benzo[g,h,i]perylene-d12 22:44 95 30-150 22:44 116 M

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated. U Indicates that this com p ound was not detected above the MDL. E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

FURNACE 12 RUN#3 16-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 10 17-Nov-2014

16-Nov-14 09:53 16-Nov-14 09:18

Flags FlagsSam p le Name Sam p lin g Date ALS Sam p le ID L1535265-1 0 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e Sam pl e Moisture Content Sample Matrix Split Ratio

Run Information Run 1 Run 2

Filename 4-141115B1 6 4-141115B11 Run Date Final Volume 1000 u L 1000 u L Dilution Factor 1 50 Anal y sis Units n g n g Instrument - Column HRMS-4 Rxi5Sil1117926 HRMS-4 Rxi5Sil1117926

Ret. Conc. EDL Ret. Conc. EDL Tar g et Anal y tes Time n g n g Time. n g n g
Naphthalene 7:34 43100 43 E 7:33 43900 93 M 2-Me-Naphthalene 8:44 16400 3.9 M 8:42 15100 38 M 1-Me-Naphthalene 8:54 11700 4.0 M 8:52 13500 40 M

Acenaphthylene 10:10 19100 2.9 M 10:09 14900 28 M

Acenaphthene 10:27 2050 5.8 M 10:27 2350 30 M J
Fluorene 11:18 3080 2.0 M 11:17 3650 15 M J
Phenanthrene 12:50 34100 11 M E 12:50 43500 56 M

Anthracene 12:55 6300 11 M 12:55 10500 71 M
Fluoranthene 14:47 38400 14 M E 14:46 30400 78 M Pyrene 15:10 25600 13 M E 15:09 23100 72 M Benz[a]anthracene 17:32 3290 1.1 M 17:35 4350 86 M J Chrysene/Triphenylene 17:36 5200 1.1 M 17:35 5000 99 M

Benzo[b]fluoranthene 19:44 3160 2.8 M 19:45 3470 160 M J Benzo[k]fluoranthene 19:47 1250 3.2 M 19:47 1470 170 M J Benzo[e]pyrene 20:15 1660 3.7 M 20:14 1140 42 M J Benzo[a]pyrene 20:21 681 3.8 M 20:23 160 43 M J Perylene 20:31 133 2.9 M 20:31 <40 40 M U Indeno[1,2,3-cd]pyrene 22:22 980 1.7 M 22:24 707 81 M J Dibenzo[a,h]anthracene 22:27 204 2.7 M 22:29 <140 140 M U

Benzo[g,h,i]perylene 22:47 807 1.0 M 22:48 868 48 M J

Field Spike Standards % Rec Limits % Rec

Fluorene-d10 11:15 104 50-150 11:14 113 p-Terphenyl-d14 15:34 85 50-150 15:34 85

Extraction Standards % Rec Limits % Rec

Naphthalene-d8 7:32 69 20-150 7:31 95 2-Me-Naphthalene-d10 8:40 71 20-150 8:40 87 Acenaphthylene-d8 10:09 68 20-150 10:08 87
Phenanthrene-d10 12:48 66 30-150 12:48 77

Anthracene-d10 12:54 59 30-150 12:53 81
Fluoranthene-d10 14:45 69 30-150 14:44 87 Benz[a]anthracene-d12 17:29 44 30-150 17:30 36 Chrysene-d12 17:33 35 30-150 17:30 22 Benzo[b]fluoranthene-d12 19:41 67 30-150 19:41 56 Benzo[k]fluoranthene-d12 19:45 54 30-150 19:45 43 Benzo[a]pyrene-d12 20:18 56 30-150 20:21 111 Perylene-d12 20:28 57 30-150 20:27 151 Indeno[1,2,3-cd]pyrene-d12 22:20 58 30-150 22:22 37 M Dibenzo[a,h]anthracene-d14 22:23 56 30-150 22:27 25 M

Benzo[g,h,i]perylene-d12 22:44 55 30-150 22:45 42 M

ED L Indicates the Estimated Detection Limit, based on the measured back g round noise for this tar g et in this sam p le. M Indicates that a p eak has been manuall y inte g rated. U Indicates that this com p ound was not detected above the MDL. E Indicates that this com p ound was detected above the calibrated ran g e. J indicates that a tar g et anal y te was detected below the LQL. 

# ALS Environmental

Sample Analysis Report

FURNACE 12 RUN# 4 16-Oct-14 28-Oct-14 Approved: CARB 429 Modified 1 train Ella Gd y cz y nski n/a --e-si g nature--
Stack 10 17-Nov-2014

16-Nov-14 10:27 16-Nov-14 07:35

Flags Flags

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including: - Individual Quantitation Reports 

# SVOC DATA PACKAGE

SECTION 3: SAMPLE DATAQuantification Report OPUS v3.6Sample ID L1535265-11Comments SAMPLE X10Sample size 1Filename 4-141115A15Acquired 15-Nov-2014 20:44Processed 16-Nov-2014 10:02Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 2867700 - n 7:33 103.472 0 1.26094 - y n 1433800 273630 2794 98 - - - - 1.0046 7:31 7:352-Me-Naphthalene1 128580 - n 8:44 12.2772 0 0.246899 - Y y n EG141116MB 64289 8689.7 227 38.2 - - - - 1.0075 8:41 8:451-Me-Naphthalene1 101950 - n 8:54 10.1601 0 0.25768 - Y y n EG141116MB 50977 7870.2 227 34.6 - - - - 1.0267 8:50 8:54Acenaphthylene1 28425 - n 10:10 1.54687 0 0.07154 - y n 14213 2496.1 117 21.4 - - - - 1.0027 10:07 10:11Acenaphthene1 12791 - n 10:27 1.41544 0 0.224041 - n n 6395.3 1396.3 180 7.8 - - - - 1.0313 10:25 10:29Fluorene1 37975 - n 11:18 6.26772 0 0.480116 - y n 18988 3210.5 209 15.3 - - - - 0.8832 11:15 11:19Phenanthrene1 230850 - n 12:51 13.4766 0 0.402253 - Y y n EG141116MB 115420 17901 496 36.1 - - - - 1.0045 12:48 12:52Anthracene1 59732 - n 12:56 3.04073 0 0.519225 - Y y n EG141116MB 29866 3261.5 496 6.6 - - - - 1.0035 12:53 12:57Fluoranthene1 23162 - n 14:47 1.91501 0 0.381187 - y n 11581 2428.6 309 7.9 - - - - 1.0022 14:45 14:49Pyrene1 38512 - n 15:09 2.96842 0 0.355362 - y n 19256 2879.5 309 9.3 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 20920 - n 17:32 4.46445 0 0.218094 - y y n eg141116MB 10460 1142 70 16.4 - - - - 1.0026 17:30 17:34Chrysene/Triphenylene1 24597 - n 17:37 3.33305 0 0.215044 - y y n EG141116MB 12298 1344 70 19.3 - - - - 1.0041 17:34 17:38Benzo[b]fluoranthene1 14591 - n 19:44 4.89794 0 0.637456 - Y y n EG141116MB 7295.3 1066.2 129 8.3 - - - - 1.0028 19:42 19:46Benzo[k]fluoranthene1 11331 - n 19:47 2.87912 0 0.690809 - Y y n EG141116MB 5665.5 1115.2 129 8.6 - - - - 1.0024 19:45 19:49Benzo[e]pyrene1 6597.8 - n 20:14 1.73894 0 0.751464 - Y y n EG141116MB 3298.9 700.59 129 5.4 - - - - 1.0026 20:12 20:16Benzo[a]pyrene1 9438.7 - n 20:21 2.58745 0 0.781597 - Y y n EG141116MB 4719.4 793.09 129 6.1 - - - - 1.003 20:18 20:22Perylene1 7273.9 - n 20:30 1.54813 0 0.599241 - Y y n EG141116MB 3637 714.52 129 5.5 - - - - 1.0026 20:27 20:31Indeno[1,2,3-cd]pyrene1 11586 - n 22:22 7.91667 0 1.42914 - Y y n EG141116MB 5793.2 636.19 80 8 - - - - 1.0017 22:21 22:25Dibenzo[a,h]anthracene1 11871 - n 22:26 7.65176 0 1.28625 - Y y n EG141116MB 5935.3 768.67 80 9.6 - - - - 1.0021 22:24 22:28Benzo[g,h,i]perylene1 14000 - n 22:46 6.20143 0 0.739959 - Y y n EG141116MB 7000 740.99 80 9.3 - - - - 1.0014 22:45 22:49Fluorene-d101 3229600 - n 11:15 761.691 0 0 76.2 n n 1614800 296770 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 2292400 - n 15:34 479.67 0 0 48 n n 1146200 173290 0 Div0 - - - - 1.0559 15:29 15:39Naphthalene-d81 21686000 - n 7:31 723.303 0 0.306478 72.3 n n 10843000 2167000 884 2451.3 - - - - 0.7234 7:27 7:372-Me-Naphthalene-d101 6876000 - n 8:40 627.724 0 0 62.8 n n 3438000 755180 0 Div0 - - - - 0.8339 8:35 8:45Acenaphthylene-d81 12675000 - n 10:08 492.029 0 0 49.2 n n 6337400 1408600 0 Div0 - - - - 0.9748 10:03 10:13Phenanthrene-d101 15662000 - n 12:48 377.866 0 0 37.8 n n 7831100 1409700 0 Div0 - - - - 1.2307 12:43 12:53Anthracene-d101 17338000 - n 12:53 400.651 0 0 40.1 n n 8668800 1054200 0 Div0 - - - - 1.2399 12:48 12:58Fluoranthene-d101 8105100 - n 14:45 447.89 0 0 44.8 n n 4052600 678040 0 Div0 - - - - 0.9748 14:39 14:49Benz[a]anthracene-d121 3640300 - n 17:29 201.114 0 0 20.1 n n 1820100 309770 0 Div0 - - - - 1.1563 17:23 17:33Chrysene-d121 6597300 - n 17:33 219.886 0 0 22 n n 3298600 361520 0 Div0 - - - -1.16 17:26 17:36Benzo[b]fluoranthene-d121 2556600 - n 19:41 357.392 0 0 35.7 n n 1278300 217150 0 Div0 - - - - 0.975 19:35 19:45Benzo[k]fluoranthene-d121 3787700 - n 19:44 344.219 0 0 34.4 n n 1893900 224700 0 Div0 - - - - 0.9779 19:38 19:48Benzo[a]pyrene-d121 3009400 - n 20:17 362.987 0 0 36.3 n n 1504700 170240 0 Div0 - - - - 1.0053 20:12 20:22Perylene-d121 2979600 - n 20:27 363.711 0 0 36.4 n n 1489800 170690 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 1469200 - n 22:20 265.296 0 0 26.5 n n 734600 70242 0 Div0 - - - - 1.1063 22:13 22:23Dibenzo[a,h]anthracene-d141 985350 - n 22:23 254.634 0 0 25.5 n n 492670 49380 0 Div0 - - - - 1.1092 22:17 22:27Benzo[g,h,i]perylene-d121 1844600 - n 22:44 301.864 0 0 30.2 n n 922320 110430 0 Div0 - - - - 1.1265 22:38 22:48Acenaphthene-d101 16958000 - n 10:24 151.316 0 - - n n 8479000 2039300 0 Div0 - - - - 0.6873 10:13 10:33Pyrene-d101 20522000 - n 15:07 124.22 0 - - n n 10261000 1872900 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 10393000 - n 20:11 52.4379 0 - - n n 5196400 870910 0 Div0 - - - - 1.3344 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F5 Lock Mass0 * NotFnd * * - - n **0 Div0 * 25:08 25:280 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0Quantification Report OPUS v3.6Sample ID L1535265-4Comments SAMPLE X10Sample size 1Filename 4-141115A16Acquired 15-Nov-2014 21:18Processed 16-Nov-2014 10:02Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 91081000 - n 7:33 2257.46 0 15.6301 - y n 45541000 9741500 51858 187.8 - - - - 1.0046 7:31 7:352-Me-Naphthalene 1 87295000 - n 8:42 4857.22 0 7.23546 - n n 43647000 11047000 12424 889.2 - - - - 1.006 8:40 8:441-Me-Naphthalene 1 67308000 - n 8:52 3908.66 0 7.55142 - n n 33654000 8414600 12424 677.3 - - - - 1.0242 8:49 8:53Acenaphthylene 1 6341000 - n 10:09 157.487 0 1.36863 - y n 3170500 642880 5073 126.7 - - - - 1.002 10:07 10:11Acenaphthene 1 8917600 - n 10:26 450.382 0 3.35387 - y n 4458800 1084500 6114 177.4 - - - - 1.0306 10:25 10:29Fluorene 1 10991000 - n 11:17 648.376 0 1.58614 - y n 5495600 1122700 2400 467.8 - - - - 0.8824 11:14 11:18Phenanthrene 1 162100000 - n 12:50 3382.35 0 2.15475 - y n 81051000 18563000 9217 2014.1 - - - - 1.0037 12:47 12:51Anthracene 1 6169200 - n 12:55 139.79 0 2.55191 - Y y n EG141116MB 3084600 469810 9217 51 - - - - 1.0033 12:52 12:56Fluoranthene1 3309000 - n 14:46 118.211 0 0.919694 - y n 1654500 325310 2027 160.5 - - - - 1.0023 14:44 14:48Pyrene1 2077300 - n 15:09 69.1832 0 0.857386 - y n 1038700 192670 2027 95 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 199260 - n 17:32 7.32595 0 0.403395 - y n 99632 18149 787 23.1 - - - - 1.0033 17:30 17:34Chrysene/Triphenylene1 870910 - n 17:35 29.9084 0 0.431006 - y n 435450 49969 787 63.5 - - - - 1.0029 17:33 17:37Benzo[b]fluoranthene1 15899000 - n 19:45 613.865 0 1.32422 - Y y n EG141116MB 7949300 815030 2609 312.4 - - - - 1.0041 19:41 19:45Benzo[k]fluoranthene1 13942000 - n 19:47 523.585 0 1.60469 - Y y n EG141116MB 6970800 811960 2609 311.2 - - - - 1.0029 19:45 19:49Benzo[e]pyrene1 104000 - n 20:15 4.47311 0 1.73248 - Y y n EG141116MB /// 52000 10456 2609 4 - - - - 1.0031 20:12 20:16Benzo[a]pyrene0 * - n NotFnd * * 1.80195 - y n * * 2609 * - - - - * 20:18 20:22Perylene0 * - n NotFnd * * 1.31831 - y n * * 2609 * - - - - * 20:27 20:31Indeno[1,2,3-cd]pyrene1 67306 - n 22:22 4.63154 0 0.900991 - Y y n EG141116MB 33653 3614 580 6.2 - - - - 1.0024 22:20 22:24Dibenzo[a,h]anthracene1 27081 - n 22:26 1.66468 0 0.448027 - Y y n EG141116MB 13540 2350.9 383 6.1 - - - - 1.0028 22:23 22:27Benzo[g,h,i]perylene1 61254 - n 22:46 3.16959 0 0.545877 - Y y n EG111416MB 30627 4454.7 580 7.7 - - - - 1.0017 22:45 22:49Fluorene-d101 13781 - n 11:14 1.16166 0 0 0.1 n n 6890.3 1617.1 0 Div0 - - - - 0.8791 11:08 11:18p-Terphenyl-d141 8735.7 - n 15:34 0.789804 0 0 0.1 n n 4367.8 854.49 0 Div0 - - - - 1.0564 15:28 15:38Naphthalene-d81 31571000 - n 7:31 825.462 0 0.256989 82.5 n n 15786000 3245200 940 3452.4 - - - - 0.7234 7:27 7:372-Me-Naphthalene-d101 11800000 - n 8:39 844.451 0 0 84.4 n n 5899900 1409200 0 Div0 - - - - 0.8329 8:35 8:45Acenaphthylene-d81 27772000 - n 10:08 845.135 0 0 84.5 n n 13886000 3196000 0 Div0 - - - - 0.9748 10:03 10:13Phenanthrene-d101 43820000 - n 12:47 828.77 0 0 82.9 n n 21910000 4888800 0 Div0 - - - - 1.2303 12:43 12:53Anthracene-d101 38950000 - n 12:52 705.6 0 0 70.6 n n 19475000 3984600 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 18758000 - n 14:44 901.027 0 0 90.1 n n 9379200 1846200 0 Div0 - - - - 0.9748 14:39 14:49Benz[a]anthracene-d121 21131000 - n 17:29 1014.74 0 0 101.5 n n 10565000 1895200 0 Div0 - - - - 1.1559 17:23 17:33Chrysene-d121 26032000 - n 17:32 754.168 0 0 75.4 n n 13016000 2041200 0 Div0 - - - - 1.1597 17:26 17:36Benzo[b]fluoranthene-d121 22228000 - n 19:40 1033.1 0 0 103.3 n n 11114000 2113500 0 Div0 - - - - 0.9743 19:35 19:45Benzo[k]fluoranthene-d121 25627000 - n 19:44 774.325 0 0 77.4 n n 12813000 1955800 0 Div0 - - - - 0.9772 19:38 19:48Benzo[a]pyrene-d121 18441000 - n 20:17 739.555 0 0 74 n n 9220600 1493000 0 Div0 - - - - 1.005 20:12 20:22Perylene-d121 18426000 - n 20:27 747.801 0 0 74.8 n n 9212800 1568700 0 Div0 - - - - 1.0128 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 14588000 - n 22:19 875.851 0 0 87.6 n n 7294100 808050 0 Div0 - - - - 1.1053 22:13 22:23Dibenzo[a,h]anthracene-d141 10333000 - n 22:22 887.782 0 0 88.8 n n 5166300 679460 0 Div0 - - - - 1.1082 22:17 22:27Benzo[g,h,i]perylene-d121 15791000 - n 22:44 859.18 0 0 85.9 n n 7895500 1085600 0 Div0 - - - - 1.1259 22:38 22:48Acenaphthene-d101 21632000 - n 10:24 193.025 0 - - n n 10816000 2586000 0 Div0 - - - - 0.6874 10:13 10:33Pyrene-d101 23609000 - n 15:07 142.909 0 - - n n 11805000 2253100 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 31258000 - n 20:11 157.714 0 - - n n 15629000 2719700 0 Div0 - - - - 1.3353 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0Quantification Report OPUS v3.6Sample ID L1535265-3Comments SAMPLE X10Sample size 1Filename 4-141115A17Acquired 15-Nov-2014 21:52Processed 16-Nov-2014 10:03Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 300820000 - n 7:35 9270.62 0 38.6475 - y n 150410000 38799000 116367 333.4 - - - - 1.0046 7:33 7:372-Me-Naphthalene1 249500000 - n 8:43 17945.5 0 2.4586 - n n 124750000 34168000 3476 9829.6 - - - -1.006 8:41 8:451-Me-Naphthalene1 181580000 - n 8:53 13630.8 0 2.56596 - n n 90792000 24796000 3476 7133.3 - - - - 1.0241 8:50 8:54Acenaphthylene1 12651000 - n 10:10 394.754 0 1.41069 - y n 6325700 1231100 4352 282.8 - - - - 1.0027 10:07 10:11Acenaphthene1 18581000 - n 10:27 1178.96 0 6.49866 - y n 9290500 2274000 9860 230.6 - - - - 1.0306 10:25 10:29Fluorene1 23522000 - n 11:17 1617.54 0 2.86211 - y n 11761000 2368800 3690 641.9 - - - - 0.8825 11:15 11:19Phenanthrene1 500830000 - n 12:50 12182.1 0 8.30653 - y n 250410000 59578000 30278 1967.7 - - - - 1.0031 12:48 12:52Anthracene1 20463000 - n 12:55 555.592 0 10.3315 - y n 10231000 1523200 30278 50.3 - - - - 1.0026 12:53 12:57Fluoranthene1 16804000 - n 14:47 553.982 0 1.82356 - y n 8402000 1682600 4587 366.8 - - - - 1.0022 14:45 14:49Pyrene1 16973000 - n 15:09 521.644 0 1.70002 - y n 8486500 1647100 4587 359.1 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 3553300 - n 17:32 96.8355 0 1.24924 - Y y n EG141116MB 1776700 346430 3615 95.8 - - - - 1.0033 17:30 17:34Chrysene/Triphenylene1 9072800 - n 17:36 224.907 0 1.34176 - Y y n EG141116MB 4536400 586540 3615 162.3 - - - - 1.0034 17:33 17:37Benzo[b]fluoranthene1 7515900 - n 19:43 187.099 0 0.6135 - Y y n EG141116MB 3758000 538640 1930 279.1 - - - - 1.0025 19:41 19:45Benzo[k]fluoranthene1 2062900 - n 19:46 51.7058 0 0.698783 - Y y n EG141116MB 1031500 160560 1930 83.2 - - - - 1.0018 19:45 19:49Benzo[e]pyrene1 3692600 - n 20:14 109.395 0 0.851396 - Y y n EG141116MB 1846300 345630 1930 179.1 - - - - 1.0024 20:12 20:16Benzo[a]pyrene1 1471300 - n 20:20 45.3365 0 0.885536 - Y y n EG141116MB 735660 119850 1930 62.1 - - - - 1.0024 20:18 20:22Perylene1 221730 - n 20:30 5.04567 0 0.609893 - Y y n EG141116MB 110860 21109 1930 10.9 - - - - 1.0028 20:27 20:31Indeno[1,2,3-cd]pyrene1 791090 - n 22:22 29.9744 0 2.06232 - Y y n EG141116MB 395550 58125 2642 22 - - - - 1.0022 22:20 22:24Dibenzo[a,h]anthracene1 372670 - n 22:26 12.4284 0 0.976966 - Y y n EG141116MB 186340 25564 1776 14.4 - - - - 1.0029 22:23 22:27Benzo[g,h,i]perylene1 1857300 - n 22:47 57.1327 0 1.35604 - Y y n EG141116MB 928660 136540 2642 51.7 - - - - 1.0026 22:44 22:48Fluorene-d101 9732800 - n 11:14 956.427 0 0 95.6 n n 4866400 1108500 0 Div0 - - - - 0.8787 11:09 11:19p-Terphenyl-d141 12722000 - n 15:34 1061.44 0 0 106.1 n n 6361000 1307700 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 25391000 - n 7:33 797.217 0 0.433667 79.7 n n 12696000 2945100 1372 2146.6 - - - - 0.7262 7:27 7:372-Me-Naphthalene-d101 9128300 - n 8:40 784.469 0 0.003461 78.4 n n 4564200 1160300 4 290077.5 - - - -0.834 8:35 8:45Acenaphthylene-d81 22106000 - n 10:08 807.815 0 0 80.8 n n 11053000 2660100 0 Div0 - - - - 0.9748 10:03 10:13Phenanthrene-d101 37590000 - n 12:48 853.717 0 0 85.4 n n 18795000 4166100 0 Div0 - - - - 1.2301 12:43 12:53Anthracene-d101 32506000 - n 12:53 707.134 0 0 70.7 n n 16253000 3233200 0 Div0 - - - - 1.2386 12:48 12:58Fluoranthene-d101 20327000 - n 14:45 872.159 0 0 87.2 n n 10164000 2107000 0 Div0 - - - - 0.9749 14:39 14:49Benz[a]anthracene-d121 28507000 - n 17:29 1222.82 0 0 122.3 n n 14253000 2809900 0 Div0 - - - - 1.1555 17:23 17:33Chrysene-d121 36063000 - n 17:32 933.265 0 0 93.3 n n 18032000 3010500 0 Div0 - - - - 1.1598 17:26 17:36Benzo[b]fluoranthene-d121 34476000 - n 19:40 981.599 0 0 98.2 n n 17238000 3375000 0 Div0 - - - - 0.9743 19:35 19:45Benzo[k]fluoranthene-d121 38398000 - n 19:44 710.736 0 0 71.1 n n 19199000 3322700 0 Div0 - - - - 0.9775 19:38 19:48Benzo[a]pyrene-d121 26773000 - n 20:17 657.73 0 0 65.8 n n 13387000 2247500 0 Div0 - - - -1.005 20:12 20:22Perylene-d121 27868000 - n 20:27 692.838 0 0 69.3 n n 13934000 2508500 0 Div0 - - - - 1.0128 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 26494000 - n 22:19 974.412 0 0 97.4 n n 13247000 1607600 0 Div0 - - - - 1.1056 22:13 22:23Dibenzo[a,h]anthracene-d141 19045000 - n 22:22 1002.43 0 0 100.2 n n 9522700 1442900 0 Div0 - - - - 1.1081 22:17 22:27Benzo[g,h,i]perylene-d121 26563000 - n 22:43 885.353 0 0 88.5 n n 13282000 1990100 0 Div0 - - - - 1.1258 22:38 22:48Acenaphthene-d101 18014000 - n 10:24 160.742 0 - - n n 9007200 2236800 0 Div0 - - - - 0.6876 10:13 10:33Pyrene-d101 26430000 - n 15:07 159.986 0 - - n n 13215000 2669400 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 51026000 - n 20:11 257.458 0 - - n n 25513000 4898700 0 Div0 - - - - 1.3347 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280000F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280000F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280000F4 Lock Mass0* NotFnd * * - - n * *0 Div0 * 25:08 25:280000F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280000F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280000DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280000Quantification Report OPUS v3.6Sample ID L1535265-1Comments SAMPLE X50Sample size 1Filename 4-141115B17Acquired 16-Nov-2014 11:01Processed 16-Nov-2014 14:25Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 241030000 - n 7:33 470788 0 390.575 - n n 120510000 25232000 14760 1709.5 - - - - 1.0022 7:32 7:362-Me-Naphthalene1 16395000 - n 8:43 74835.4 0 57.6982 - y n 8197700 1796500 1182 1519.2 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 11596000 - n 8:52 55241.4 0 60.2178 - y n 5798100 1261300 1182 1066.7 - - - - 1.0231 8:50 8:54Acenaphthylene1 86316000 - n 10:10 153342 0 19.2405 - y n 43158000 10339000 1012 10211.4 - - - - 1.0033 10:07 10:11Acenaphthene1 8850300 - n 10:27 31972.4 0 132.454 - y n 4425200 1035800 3428 302.2 - - - - 1.0313 10:25 10:29Fluorene1 17819000 - n 11:18 70162 0 114.542 - y n 8909500 1681300 2639 637.2 - - - - 0.8828 11:15 11:19Phenanthrene1 811940000 - n 12:50 1130820 0 92.5761 - y n 405970000 78843000 6030 13076 - - - - 1.0026 12:48 12:52Anthracene1 107840000 - n 12:55 128686 0 95.8821 - y n 53921000 8249800 6030 1368.2 - - - - 1.0026 12:53 12:57Fluoranthene1 836580000 - n 14:47 1998740 0 264.18 - y n 418290000 82154000 9808 8375.9 - - - - 1.0023 14:45 14:49Pyrene1 748680000 - n 15:10 1667560 0 246.282 - y n 374340000 77982000 9808 7950.5 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 28038000 - n 17:33 153416 0 98.5634 - Y y n EG141116MB 14019000 2636500 1379 1911.6 - - - - 1.0029 17:31 17:35Chrysene/Triphenylene1 71340000 - n 17:36 313986 0 102.46 - Y y n EG141116MB 35670000 4427700 1379 3210.3 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 8584900 - n 19:44 79652.6 0 89.8164 - Y y n EG141116MB 4292500 659200 633 1041.4 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 4403500 - n 19:47 36198.7 0 92.2285 - Y y n EG141116MB 2201800 310400 633 490.4 - - - - 1.0025 19:45 19:49Benzo[e]pyrene1 3805500 - n 20:15 10835.5 0 26.4702 - y n 1902700 302080 633 477.2 - - - - 1.0033 20:12 20:16Benzo[a]pyrene1 1737800 - n 20:21 5146.52 0 27.5317 - y n 868900 89719 633 141.7 - - - - 1.0025 20:19 20:23Perylene1 506150 - n 20:31 2500.37 0 47.9521 - y n 253080 22383 633 35.4 - - - - 1.0024 20:28 20:32Indeno[1,2,3-cd]pyrene0 * - n NotFnd * * 33677.4 - Y y n EG141116MB * *483 * - - - - * 22:16 22:20Dibenzo[a,h]anthracene1 21464 - n 22:27 884.553 0 216.13 - Y y n EG141116MB 10732 1951.3 433 4.5 - - - - 1.0015 22:26 22:30Benzo[g,h,i]perylene1 385480 - n 22:48 4620.15 0 118.534 - Y y n EG141116MB 192740 17578 483 36.4 - - - - 1.0022 22:46 22:50Fluorene-d101 197180 - n 11:15 1109.47 0 0 110.9 n n 98592 19960 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 121140 - n 15:34 732.492 0 0 73.2 n n 60571 9224.7 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 400610 - n 7:32 20.0783 0 0 2 n n 200310 36963 0 Div0 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 143840 - n 8:40 19.7326 0 0 2 n n 71921 16820 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 388260 - n 10:08 22.6485 0 0 2.3 n n 194130 45370 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 656510 - n 12:48 23.801 0 0 2.4 n n 328260 74441 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 739630 - n 12:53 25.6837 0 0 2.6 n n 369810 69378 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 280490 - n 14:45 26.2702 0 0 2.6 n n 140240 31101 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 141980 - n 17:30 13.2946 0 0 1.3 n n 70989 13589 0 Div0 - - - - 1.1564 17:24 17:34Chrysene-d121 203120 - n 17:33 11.4743 0 0 1.1 n n 101560 15042 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 92502 - n 19:41 24.2933 0 0 2.4 n n 46251 7560.5 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 117080 - n 19:44 19.9893 0 0 2 n n 58539 8256.5 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 278570 - n 20:18 63.1245 0 0 6.3 n n 139280 23709 0 Div0 - - - - 1.0058 20:12 20:22Perylene-d121 128370 - n 20:28 29.4397 0 0 2.9 n n 64187 10464 0 Div0 - - - -1.014 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 251.2 - n 22:15 0.085219 0 0 0 n n 125.618 0 Div0 - - - - 1.1024 22:13 22:23Dibenzo[a,h]anthracene-d141 15412 - n 22:25 7.48273 0 0 0.7 y n 7706.2 1589.5 0 Div0 - - - - 1.1107 22:17 22:27Benzo[g,h,i]perylene-d121 68175 - n 22:45 20.9598 0 0 2.1 n n 34087 4162.7 0 Div0 - - - - 1.1272 22:38 22:48Acenaphthene-d101 11285000 - n 10:24 100.697 0 - - n n 5642600 1358800 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 12108000 - n 15:08 73.2907 0 - - n n 6054000 1257200 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 5531800 - n 20:11 27.9114 0 - - n n 2765900 437240 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n**0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-1Comments SAMPLE X50 DILX10 R»Sample size 1Filename 4-141115B04Acquired 16-Nov-2014 03:35Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 28423000 - n 7:34 603688 0 1410.82 - n n 14212000 2433300 4752 512.1 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 2176500 - n 8:43 116646 0 172.516 - n n 1088200 218580 260 840.7 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 1694200 - n 8:52 94762.8 0 180.05 - n n 847080 166740 260 641.3 - - - - 1.0231 8:50 8:54Acenaphthylene1 11353000 - n 10:10 254957 0 363.186 - y n 5676400 1199900 1382 868.5 - - - - 1.0033 10:07 10:11Acenaphthene1 1177000 - n 10:27 53749.5 0 526.471 - y n 588480 130620 985 132.6 - - - - 1.0313 10:25 10:29Fluorene1 1919000 - n 11:19 102406 0 449.294 - y n 959510 147880 639 231.4 - - - - 0.8841 11:17 11:21Phenanthrene1 107200000 - n 12:50 2023480 0 126.904 - y n 53601000 10740000 510 21048.1 - - - - 1.0026 12:48 12:52Anthracene1 20836000 - n 12:55 343225 0 148.565 - y n 10418000 1008000 510 1975.4 - - - - 1.0026 12:53 12:57Fluoranthene1 155640000 - n 14:47 3621450 0 1570.92 - y n 77821000 16396000 5164 3175.2 - - - - 1.0023 14:45 14:49Pyrene1 120020000 - n 15:09 2603310 0 1464.5 - y n 60008000 12360000 5164 2393.7 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 8074200 - n 17:32 267563 0 1188.1 - Y y n EG141117MB 4037100 718390 2598 276.6 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 22014000 - n 17:36 472879 0 1102.27 - Y y n EG141116MB 11007000 1201600 2598 462.6 - - - - 1.0038 17:33 17:37Benzo[b]fluoranthene1 3128000 - n 19:44 140590 0 336.577 - Y y n EG141116MB 1564000 226080 577 391.8 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 1318600 - n 19:46 41097 0 379.966 - Y y n EG141116MB 659310 101850 577 176.5 - - - - 1.0017 19:45 19:49Benzo[e]pyrene1 1457700 - n 20:14 51923.6 0 393.081 - Y y n EG141116MB 728870 115680 577 200.5 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 609970 - n 20:21 22598 0 408.844 - Y y n EG141116MB 304990 34812 577 60.3 - - - - 1.0033 20:18 20:22Perylene1 149340 - n 20:30 4080.58 0 297.379 - Y y n EG141116MB 74668 8526.5 577 14.8 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 116540 - n 22:22 8368.55 0 375.81 - Y y n EG141116MB 58270 5421.8 200 27.1 - - - - 1.0015 22:21 22:25Dibenzo[a,h]anthracene1 17485 - n 22:26 1186.42 0 245.802 - Y y n EG141116MB 8742.5 1343.8 149 9 - - - - 1.0022 22:24 22:28Benzo[g,h,i]perylene1 151760 - n 22:46 7328.21 0 193.692 - Y y n EG141116MB 75878 8356 200 41.8 - - - - 1.0015 22:45 22:49Fluorene-d101 18475 - n 11:15 1408.8 0 0 0.3 n n 9237.3 1625.3 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 26783 - n 15:34 1577.17 0 0 0.3 n n 13392 2028.7 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 18458000 - n 7:32 393627 0 328.039 78.6 n n 9228800 1650600 1436 1149.4 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 6137500 - n 8:40 358256 0 0 71.5 n n 3068700 619670 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 15387000 - n 10:08 381931 0 0 76.2 n n 7693600 1643200 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 24269000 - n 12:48 374375 0 0 74.7 n n 12134000 2302300 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 26843000 - n 12:53 396628 0 0 79.2 n n 13422000 1898300 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 14429000 - n 14:45 413756 0 0 82.6 n n 7214600 1379500 0 Div0 - - - - 0.9757 14:39 14:49Benz[a]anthracene-d121 11745000 - n 17:29 336710 0 0 67.2 n n 5872500 1063700 0 Div0 - - - - 1.1566 17:23 17:33Chrysene-d121 20850000 - n 17:32 360605 0 0 72 n n 10425000 1319400 0 Div0 - - - - 1.1599 17:26 17:36Benzo[b]fluoranthene-d121 9566800 - n 19:41 357788 0 0 71.4 n n 4783400 921340 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 15471000 - n 19:44 376151 0 0 75.1 n n 7735500 915200 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 11156000 - n 20:17 360012 0 0 71.9 n n 5578200 729090 0 Div0 - - - - 1.005 20:12 20:22Perylene-d121 11627000 - n 20:27 379718 0 0 75.8 n n 5813700 770530 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 7003800 - n 22:20 338356 0 0 67.5 n n 3501900 334570 0 Div0 - - - - 1.1065 22:13 22:23Dibenzo[a,h]anthracene-d141 4689700 - n 22:23 324232 0 0 64.7 n n 2344800 240740 0 Div0 - - - - 1.109 22:17 22:27Benzo[g,h,i]perylene-d121 8477400 - n 22:44 371151 0 0 74.1 n n 4238700 528380 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 13287000 - n 10:24 118.563 0 - - n n 6643700 1550600 0 Div0 - - - - 0.688 10:13 10:33Pyrene-d101 19814000 - n 15:07 119.933 0 - - n n 9906800 1892900 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 19462000 - n 20:11 98.1964 0 - - n n 9730900 1603100 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n **0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-1Comments DILUTIONX50000Sample size 1Filename 4-141115A19Acquired 15-Nov-2014 23:01Processed 16-Nov-2014 10:04Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 3475900 - n 7:34 685825 0 5841.28 - y n 1738000 283550 2067 137.2 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 263140 - n 8:43 140535 0 4138.66 - n n 131570 23333 624 37.4 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 226510 - n 8:52 126250 0 4319.39 - n n 113250 20230 624 32.4 - - - - 1.0231 8:50 8:54Acenaphthylene 1 1184400 - n 10:09 237743 0 1844.32 - y n 592190 120300 782 153.8 - - - - 1.0016 10:07 10:11Acenaphthene 1 108790 - n 10:27 44405.2 0 2510.32 - Y y n EG141116MB 54393 12437 524 23.8 - - - - 1.0313 10:25 10:29Fluorene 1 179330 - n 11:18 104478 0 2379.29 - Y y n EG141116MB 89666 14155 280 50.6 - - - - 0.8828 11:15 11:19Phenanthrene 1 9577800 - n 12:50 1973710 0 2627.63 - y y n EG1411116MB 4788900 805630 874 921.5 - - - - 1.0026 12:48 12:52Anthracene 1 1976300 - n 12:55 384530 0 3328.45 - y y n EG141116MB 988150 111050 874 127 - - - - 1.0026 12:53 12:57Fluoranthene 1 12873000 - n 14:46 3806320 0 3570.36 - y n 6436700 1082700 847 1278 - - - - 1.0011 14:45 14:49Pyrene1 10094000 - n 15:09 2782410 0 3328.47 - y n 5047200 887470 847 1047.6 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 497480 - n 17:32 220194 0 3672.66 - Y y n EG141116MB 248740 51890 567 91.6 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 2136500 - n 17:36 470070 0 3194.98 - Y y n EG141116MB 1068300 93213 567 164.5 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 277950 - n 19:44 116352 0 1074.63 - Y y n EG141116MB 138970 19839 155 128.3 - - - - 1.0034 19:41 19:45Benzo[k]fluoranthene1 169520 - n 19:46 51109.8 0 1133.33 - Y y n EG141116MB 84762 12119 155 78.4 - - - - 1.0017 19:45 19:49Benzo[e]pyrene1 176360 - n 20:14 53620.7 0 1156.41 - Y y n EG141116MB 88181 13887 155 89.8 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 73655 - n 20:21 23292.1 0 1202.78 - Y y n EG141116MB 36828 4506.5 155 29.1 - - - - 1.0025 20:19 20:23Perylene1 25611 - n 20:31 6631.79 0 714.034 - Y y n EG141116MB 12806 1312.8 155 8.5 - - - - 1.0033 20:29 20:33Indeno[1,2,3-cd]pyrene1 13579 - n 22:22 8764.85 0 3031.59 - Y y n EG141116MB 6789.3 1208.7 177 6.8 - - - - 1.0015 22:21 22:25Dibenzo[a,h]anthracene1 6030.9 - n 22:28 3786.18 0 2267.58 - Y y n EG141116MB 3015.4 473.11 148 3.2 - - - - 1.003 22:25 22:29Benzo[g,h,i]perylene1 18915 - n 22:47 7052.23 0 1491.86 - Y y n EG141116MB 9457.4 975.66 177 5.5 - - - - 1.0022 22:45 22:49Fluorene-d101 2668.7 - n 11:15 2221.74 0 0 0.4 n n 1334.3 372.25 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 794.79 - n 15:34 594.728 0 0 0.1 n n 397.39 124.73 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 1986900 - n 7:32 406089 0 647.197 81.1 n n 993450 173370 292 593.7 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 615910 - n 8:40 344557 0 0 68.8 n n 307960 61993 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 1721500 - n 10:08 409521 0 0 81.7 n n 860770 183230 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 2222900 - n 12:48 328643 0 0 65.6 n n 1111500 190510 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 2272600 - n 12:53 321818 0 0 64.2 n n 1136300 145180 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 1135500 - n 14:45 343039 0 0 68.5 n n 567750 99579 0 Div0 - - - - 0.9757 14:39 14:49Benz[a]anthracene-d121 879340 - n 17:29 265590 0 0 53 n n 439670 75070 0 Div0 - - - - 1.1566 17:23 17:33Chrysene-d121 2035700 - n 17:33 370929 0 0 74 n n 1017900 99303 0 Div0 - - - - 1.161 17:26 17:36Benzo[b]fluoranthene-d121 1027200 - n 19:40 339989 0 0 67.9 n n 513580 77333 0 Div0 - - - - 0.9744 19:35 19:45Benzo[k]fluoranthene-d121 1599300 - n 19:44 344144 0 0 68.7 n n 799650 82229 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 1307000 - n 20:18 373280 0 0 74.5 n n 653500 66416 0 Div0 - - - - 1.0058 20:12 20:22Perylene-d121 1227000 - n 20:27 354640 0 0 70.8 n n 613500 86000 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 779150 - n 22:20 333139 0 0 66.5 n n 389580 36668 0 Div0 - - - - 1.1065 22:13 22:23Dibenzo[a,h]anthracene-d141 506860 - n 22:24 310149 0 0 61.9 n n 253430 25954 0 Div0 - - - - 1.1098 22:17 22:27Benzo[g,h,i]perylene-d121 1098000 - n 22:44 425445 0 0 84.9 n n 548990 60650 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 1386400 - n 10:24 12.3712 0 - - n n 693220 159810 0 Div0 - - - - 0.688 10:13 10:33Pyrene-d101 1880600 - n 15:07 11.3837 0 - - n n 940320 167130 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 2199000 - n 20:11 11.0951 0 - - n n 1099500 166510 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-2Comments SAMPLE X50Sample size 1Filename 4-141115B18Acquired 16-Nov-2014 11:36Processed 16-Nov-2014 14:25Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 185020000 - n 7:34 457687 0 243.728 - y n 92512000 19452000 7885 2467 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 14639000 - n 8:43 103276 0 36.1662 - n n 7319700 1497000 444 3371.6 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 10162000 - n 8:52 74821.3 0 37.7455 - n n 5081100 1089500 444 2453.8 - - - - 1.0231 8:50 8:54Acenaphthylene1 53441000 - n 10:10 188241 0 108.876 - y n 26720000 6124500 2903 2109.9 - - - - 1.0033 10:07 10:11Acenaphthene1 6061700 - n 10:27 43419.7 0 51.6032 - y n 3030900 702830 677 1038.8 - - - - 1.0313 10:25 10:29Fluorene1 13187000 - n 11:19 120985 0 142.027 - y n 6593300 1221200 1336 913.8 - - - - 0.8841 11:17 11:21Phenanthrene1 764610000 - n 12:50 2481340 0 219.66 - y n 382300000 78905000 5844 13502.5 - - - - 1.0026 12:48 12:52Anthracene1 65902000 - n 12:55 205346 0 252.314 - y n 32951000 3613800 5844 618.4 - - - - 1.0026 12:53 12:57Fluoranthene1 937260000 - n 14:47 5302530 0 446.758 - y n 468630000 82398000 7530 10942.2 - - - - 1.0023 14:45 14:49Pyrene1 894520000 - n 15:10 4717850 0 416.491 - y n 447260000 81243000 7530 10788.8 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 88697000 - n 17:32 1117230 0 673.459 - y n 44348000 9484400 4431 2140.6 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 285810000 - n 17:36 2396630 0 599.432 - y n 142900000 23191000 4431 5234 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 34977000 - n 19:44 776305 0 184.57 - Y y n EG141118MB 17488000 2652200 637 4160.8 - - - - 1.0025 19:41 19:45Benzo[k]fluoranthene1 13745000 - n 19:47 152389 0 122.488 - Y y n EG141118MB 6872300 1119700 637 1756.7 - - - - 1.0025 19:44 19:48Benzo[e]pyrene1 14514000 - n 20:15 88004.3 0 40.9908 - Y y n EG141116MB 7256800 1208800 637 1896.5 - - - - 1.0025 20:11 20:15Benzo[a]pyrene1 6143600 - n 20:21 38746.2 0 42.6345 - Y y n EG141116MB 3071800 352260 637 552.6 - - - - 1.0025 20:20 20:24Perylene1 1205900 - n 20:31 16170.7 0 95.0835 - Y y n EG141116MB 602930 64701 637 101.5 - - - - 1.0024 20:30 20:34Indeno[1,2,3-cd]pyrene1 974620 - n 22:23 46785.9 0 149.528 - Y y n EG141118MB 487310 41378 263 157.5 - - - - 1.0015 22:19 22:23Dibenzo[a,h]anthracene1 196070 - n 22:27 8480.61 0 206.42 - Y y n EG141118MB 98035 6885.4 263 26.2 - - - - 1.0015 22:26 22:30Benzo[g,h,i]perylene1 979160 - n 22:48 29087.8 0 141.27 - Y y n EG141118MB 489580 54509 263 207.5 - - - - 1.0022 22:44 22:48Fluorene-d101 133350 - n 11:15 1748.35 0 0 174.8 n n 66676 13419 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 120990 - n 15:35 1732.35 0 0 173.2 n n 60496 8970.1 0 Div0 - - - - 1.0565 15:29 15:39Naphthalene-d81 316330 - n 7:32 16.678 0 0 1.7 n n 158170 31644 0 Div0 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 93067 - n 8:40 13.4305 0 0 1.3 n n 46534 10075 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 195820 - n 10:08 12.0161 0 0 1.2 n n 97908 22987 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 281750 - n 12:48 10.7451 0 0 1.1 n n 140870 30406 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 283250 - n 12:53 10.347 0 0 1 n n 141630 25552 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 118450 - n 14:45 10.3771 0 0 1 n n 59225 14119 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 61675 - n 17:29 5.40194 0 0 0.5 n n 30838 6388.9 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 106610 - n 17:33 5.63323 0 0 0.6 n n 53305 8260 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 38669 - n 19:41 9.33999 0 0 0.9 y n 19334 3704.9 0 Div0 - - - - 0.9744 19:34 19:44Benzo[k]fluoranthene-d121 86806 - n 19:44 13.6308 0 0 1.4 y n 43403 6260.4 0 Div0 - - - - 0.9769 19:38 19:48Benzo[a]pyrene-d121 130810 - n 20:18 27.262 0 0 2.7 y n 65404 15417 0 Div0 - - - -1.005 20:10 20:20Perylene-d121 47290 - n 20:28 9.97422 0 0 1 y n 23645 5314.1 0 Div0 - - - - 1.0132 20:20 20:30Indeno[1,2,3-cd]pyrene-d121 20912 - n 22:21 6.52473 0 0 0.7 Y y n EG141116MB 10456 2204.4 0 Div0 - - - - 1.1064 22:14 22:24Dibenzo[a,h]anthracene-d141 14684 - n 22:25 6.55689 0 0 0.7 Y y n EG141116MB 7342.2 1010.3 0 Div0 - - - - 1.1097 22:15 22:25Benzo[g,h,i]perylene-d121 27506 - n 22:45 7.77741 0 0 0.8 Y y n EG141116MB 13753 1899.2 0 Div0 - - - - 1.1262 22:38 22:48Acenaphthene-d101 10728000 - n 10:24 95.7236 0 - - n n 5363900 1280000 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 12944000 - n 15:08 78.354 0 - - n n 6472200 1319700 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 6014700 - n 20:12 30.348 0 - - Y y n EG141116MB 3007400 509440 0 Div0 - - - - 1.3348 20:04 20:24F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n**0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-2Comments SAMPLE X50 DILX10 R»Sample size 1Filename 4-141115B05Acquired 16-Nov-2014 04:10Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 22938000 - n 7:34 437329 0 697.426 - n n 11469000 1982900 2532 783.1 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 1903000 - n 8:43 79889.8 0 183.788 - n n 951490 184810 340 543.5 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 1495500 - n 8:53 65525.1 0 191.814 - n n 747750 137920 340 405.6 - - - -1.025 8:50 8:54Acenaphthylene1 7529800 - n 10:10 155858 0 498.881 - y n 3764900 804380 2016 399 - - - - 1.0033 10:07 10:11Acenaphthene1 781960 - n 10:27 32913.8 0 118.766 - n n 390980 87244 236 369.7 - - - - 1.0313 10:25 10:29Fluorene1 1264400 - n 11:19 57266.9 0 120.881 - y n 632210 111050 200 555.2 - - - - 0.8841 11:15 11:19Phenanthrene1 99178000 - n 12:50 1588830 0 789.782 - y n 49589000 9856900 3694 2668.1 - - - - 1.0026 12:48 12:52Anthracene1 13826000 - n 12:55 202806 0 970.044 - y n 6913200 665530 3694 180.2 - - - - 1.0026 12:53 12:57Fluoranthene1 239760000 - n 14:47 4793270 0 1857.36 - y n 119880000 26021000 7140 3644.5 - - - - 1.0023 14:45 14:49Pyrene1 190720000 - n 15:10 3554430 0 1731.52 - y n 95359000 20301000 7140 2843.4 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 20157000 - n 17:32 570378 0 366.007 - y n 10079000 1840500 984 1870.7 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 64270000 - n 17:36 1248830 0 350.209 - y n 32135000 4060800 984 4127.3 - - - - 1.0038 17:33 17:37Benzo[b]fluoranthene1 10441000 - n 19:44 419362 0 440.699 - Y y n EG141116MB 5220700 792400 862 919.4 - - - - 1.0034 19:41 19:45Benzo[k]fluoranthene1 4003300 - n 19:47 111590 0 477.451 - Y y n EG141116MB 2001600 328790 862 381.5 - - - - 1.0025 19:45 19:49Benzo[e]pyrene1 4438200 - n 20:14 149241 0 541.904 - Y y n EG141116MB 2219100 383530 862 445 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 1723100 - n 20:20 60264.6 0 563.634 - Y y n EG141116MB 861540 110950 862 128.7 - - - - 1.0025 20:18 20:22Perylene1 333660 - n 20:30 8802.68 0 438.402 - Y y n EG141116MB 166830 19617 862 22.8 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 368790 - n 22:22 22914 0 617.548 - y n 184400 18392 387 47.5 - - - - 1.0022 22:20 22:24Dibenzo[a,h]anthracene1 72453 - n 22:27 4122.35 0 203.742 - y n 36227 2969.3 152 19.5 - - - -1.003 22:24 22:28Benzo[g,h,i]perylene1 424400 - n 22:46 17731.1 0 319.714 - y n 212200 25053 387 64.7 - - - - 1.0015 22:45 22:49Fluorene-d101 22379 - n 11:15 1448.35 0 0 0.3 n n 11189 2512.9 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 12896 - n 15:35 652.477 0 0 0.1 n n 6448.1 1076.2 0 Div0 - - - - 1.0565 15:29 15:39Naphthalene-d81 20562000 - n 7:32 477464 0 454.496 95.3 n n 10281000 1779100 1756 1013.1 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 7835200 - n 8:40 497995 0 0 99.4 n n 3917600 760640 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 16695000 - n 10:08 451207 0 0 90.1 n n 8347400 1745500 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 28595000 - n 12:48 480299 0 0 95.9 n n 14297000 2678400 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 30146000 - n 12:53 485001 0 0 96.8 n n 15073000 2105000 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 16794000 - n 14:45 485265 0 0 96.9 n n 8396900 1613200 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 13755000 - n 17:29 397356 0 0 79.3 n n 6877400 1307800 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 23050000 - n 17:32 401713 0 0 80.2 n n 11525000 1572900 0 Div0 - - - - 1.1586 17:27 17:37Benzo[b]fluoranthene-d121 10706000 - n 19:40 479788 0 0 95.8 n n 5352900 1051100 0 Div0 - - - - 0.9744 19:35 19:45Benzo[k]fluoranthene-d121 17298000 - n 19:44 503972 0 0 100.6 n n 8648900 1088000 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 11817000 - n 20:17 456968 0 0 91.2 n n 5908700 790020 0 Div0 - - - -1.005 20:12 20:22Perylene-d121 12043000 - n 20:27 471275 0 0 94.1 n n 6021400 780770 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 8094600 - n 22:19 468599 0 0 93.5 n n 4047300 393910 0 Div0 - - - - 1.1057 22:13 22:23Dibenzo[a,h]anthracene-d141 5592700 - n 22:23 463348 0 0 92.5 n n 2796400 297590 0 Div0 - - - -1.109 22:17 22:27Benzo[g,h,i]perylene-d121 9798400 - n 22:44 514053 0 0 102.6 n n 4899200 619310 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 12203000 - n 10:24 108.888 0 - - n n 6101600 1368500 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 19662000 - n 15:08 119.018 0 - - n n 9831200 1888100 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 16241000 - n 20:11 81.9461 0 - - n n 8120500 1387000 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n**0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-2Comments DILUTIONX50000Sample size 1Filename 4-141115A20Acquired 15-Nov-2014 23:35Processed 16-Nov-2014 10:04Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 3248100 - n 7:35 570203 0 4411.04 - y n 1624000 253880 1704 149 - - - - 1.0066 7:32 7:362-Me-Naphthalene 1 237990 - n 8:44 107388 0 2754.58 - n n 119000 20337 424 48 - - - - 1.0077 8:41 8:451-Me-Naphthalene 1 178030 - n 8:53 83841.4 0 2874.87 - n n 89016 15719 424 37.1 - - - - 1.025 8:50 8:54Acenaphthylene1 781680 - n 10:09 147131 0 826.502 - y n 390840 83161 376 221 - - - - 1.0016 10:07 10:11Acenaphthene1 85507 - n 10:28 32728.2 0 1089.74 - y n 42753 9078.7 244 37.2 - - - - 1.0329 10:25 10:29Fluorene1 135730 - n 11:18 71339.9 0 1935.67 - y n 67865 10074 271 37.1 - - - - 0.8828 11:15 11:19Phenanthrene1 8585800 - n 12:51 1596200 0 2322.67 - Y y n EG141116MB 4292900 716350 920 778.5 - - - - 1.0039 12:48 12:52Anthracene1 1649400 - n 12:55 261143 0 3288.96 - Y y n EG141116MB 824710 78717 920 85.5 - - - - 1.0026 12:53 12:57Fluoranthene1 16958000 - n 14:47 4052550 0 567.806 - y n 8479100 1431500 164 8729.8 - - - - 1.0023 14:45 14:49Pyrene1 14408000 - n 15:09 3209770 0 529.338 - y n 7203800 1249300 164 7618.5 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 1320600 - n 17:32 465603 0 2455.38 - y n 660310 134510 487 276.1 - - - - 1.0019 17:31 17:35Chrysene/Triphenylene1 1320600 - n 17:32 535792 0 2825.53 - y n 660310 134510 487 276.1 - - - - 1.0019 17:31 17:35Benzo[b]fluoranthene1 924260 - n 19:44 400015 0 3669.25 - Y y n EG141116MB 462130 65523 597 109.7 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 428190 - n 19:47 125947 0 4267.55 - Y y n EG141116MB 214100 32531 597 54.4 - - - - 1.0025 19:45 19:49Benzo[e]pyrene1 447730 - n 20:15 142320 0 4025.39 - Y y n EG141116MB 223860 36645 597 61.3 - - - - 1.0033 20:12 20:16Benzo[a]pyrene1 215880 - n 20:21 71373.6 0 4186.8 - Y y n EG141116MB 107940 12024 597 20.1 - - - - 1.0025 20:19 20:23Perylene1 22072 - n 20:30 5546.05 0 3067.95 - Y y n EG141116MB 11036 2320.2 597 3.9 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 44835 - n 22:22 26576.8 0 3634.28 - Y y n EG141116MB 22417 1881.3 202 9.3 - - - - 1.0015 22:21 22:25Dibenzo[a,h]anthracene1 9146.6 - n 22:27 5290.9 0 2215.81 - Y y n EG141116MB 4573.3 668.67 135 4.9 - - - - 1.003 22:24 22:28Benzo[g,h,i]perylene1 52774 - n 22:46 18023.3 0 1574.12 - Y y n EG141116MB 26387 2791.3 202 13.8 - - - - 1.0015 22:45 22:49Fluorene-d101 804.58 - n 11:16 604.303 0 0 0.1 n n 402.29 69.753 0 Div0 - - - - 0.8802 11:09 11:19p-Terphenyl-d141 3073.8 - n 15:36 1859.03 0 0 0.4 n n 1536.9 294.25 0 Div0 - - - - 1.0576 15:29 15:39Naphthalene-d81 2233100 - n 7:32 496694 0 626.489 99.1 n n 1116600 189330 260 728.2 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 728970 - n 8:40 443794 0 0 88.6 n n 364490 63289 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 1835900 - n 10:08 475274 0 0 94.9 n n 917960 196680 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 2464000 - n 12:48 396430 0 0 79.1 n n 1232000 226860 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 2792900 - n 12:53 430393 0 0 85.9 n n 1396400 154650 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 1404900 - n 14:45 520974 0 0 104 n n 702460 121200 0 Div0 - - - - 0.9757 14:39 14:49Benz[a]anthracene-d121 1104000 - n 17:30 409274 0 0 81.7 n n 551980 96535 0 Div0 - - - - 1.1577 17:23 17:33Chrysene-d121 1104000 - n 17:30 246908 0 0 49.3 n n 551980 96535 0 Div0 - - - - 1.1577 17:26 17:36Benzo[b]fluoranthene-d121 993500 - n 19:41 402529 0 0 80.3 n n 496750 87520 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 1639300 - n 19:44 431788 0 0 86.2 n n 819640 84384 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 1250100 - n 20:18 437034 0 0 87.2 n n 625060 73728 0 Div0 - - - - 1.0058 20:12 20:22Perylene-d121 1264400 - n 20:27 447342 0 0 89.3 n n 632210 77344 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 848440 - n 22:20 444050 0 0 88.6 n n 424220 34910 0 Div0 - - - - 1.1065 22:13 22:23Dibenzo[a,h]anthracene-d141 550100 - n 22:23 412026 0 0 82.2 n n 275050 24288 0 Div0 - - - - 1.109 22:17 22:27Benzo[g,h,i]perylene-d121 1198700 - n 22:44 568537 0 0 113.5 n n 599340 65604 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 1274000 - n 10:24 11.368 0 - - n n 637010 147000 0 Div0 - - - - 0.688 10:13 10:33Pyrene-d101 1532100 - n 15:07 9.27414 0 - - n n 766070 138270 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 1796400 - n 20:11 9.06413 0 - - n n 898220 133250 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-5Comments SAMPLE X50Sample size 1Filename 4-141115B19Acquired 16-Nov-2014 12:10Processed 16-Nov-2014 14:25Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 157350000 - n 7:34 325520 0 96.5931 - n n 78676000 16228000 3972 4085.6 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 13422000 - n 8:44 53705 0 18.8628 - n n 6711200 1406300 416 3380.5 - - - - 1.0077 8:41 8:451-Me-Naphthalene1 9818100 - n 8:53 40999.2 0 19.6865 - n n 4909100 1081300 416 2599.2 - - - -1.025 8:50 8:54Acenaphthylene1 37580000 - n 10:11 74995.5 0 59.476 - n n 18790000 4121500 2500 1648.6 - - - - 1.0033 10:08 10:12Acenaphthene1 4780200 - n 10:27 19398.8 0 19.239 - y n 2390100 554310 398 1393.8 - - - - 1.0296 10:26 10:30Fluorene1 10296000 - n 11:18 41516.6 0 64.6936 - y n 5148200 904310 1373 658.7 - - - - 0.8828 11:15 11:19Phenanthrene1 765350000 - n 12:50 1091570 0 97.1714 - y n 382680000 78067000 5830 13391.4 - - - - 1.0026 12:48 12:52Anthracene1 63706000 - n 12:55 95491.1 0 111.593 - y n 31853000 3225900 5830 553.4 - - - - 1.0026 12:53 12:57Fluoranthene1 942080000 - n 14:47 2299730 0 143.859 - y n 471040000 83928000 4940 16988.1 - - - - 1.0023 14:45 14:49Pyrene1 850490000 - n 15:10 1935490 0 134.113 - y n 425240000 82326000 4940 16663.9 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 151730000 - n 17:32 583714 0 51.431 - y y n EG141117MB 75863000 15297000 1066 14354.9 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 422960000 - n 17:37 1287730 0 47.0413 - y y n EG141117MB 211480000 34921000 1066 32771.6 - - - - 1.0038 17:34 17:38Benzo[b]fluoranthene1 66477000 - n 19:44 480908 0 89.1941 - y n 33239000 5732400 1020 5619.6 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 29297000 - n 19:47 163660 0 86.1508 - y n 14649000 2143200 1020 2101.1 - - - - 1.0025 19:45 19:49Benzo[e]pyrene1 28034000 - n 20:15 72933.2 0 35.0823 - y n 14017000 2401300 1020 2354.1 - - - - 1.0025 20:13 20:17Benzo[a]pyrene1 14220000 - n 20:21 38477.8 0 36.4891 - y n 7110000 879350 1020 862.1 - - - - 1.0033 20:18 20:22Perylene1 3062400 - n 20:31 16779.1 0 82.045 - n n 1531200 150390 1020 147.4 - - - - 1.0065 20:29 20:33Indeno[1,2,3-cd]pyrene1 2065800 - n 22:23 27208.1 0 310.615 - y n 1032900 96566 1350 71.6 - - - - 1.0015 22:22 22:26Dibenzo[a,h]anthracene1 372740 - n 22:27 5509.92 0 200.601 - Y y n EG141116MB 186370 17718 621 28.5 - - - - 1.0015 22:26 22:30Benzo[g,h,i]perylene1 2283300 - n 22:48 16017.5 0 203.889 - y n 1141600 115140 1350 85.3 - - - - 1.0022 22:46 22:50Fluorene-d101 180720 - n 11:15 1041.29 0 0 104.1 n n 90360 17102 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 140660 - n 15:35 869.023 0 0 86.9 n n 70332 12876 0 Div0 - - - - 1.0565 15:29 15:39Naphthalene-d81 378240 - n 7:32 19.4844 0 0 1.9 n n 189120 40221 0 Div0 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 164090 - n 8:40 23.1364 0 0 2.3 n n 82046 18100 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 345630 - n 10:09 20.7223 0 0 2.1 n n 172810 36241 0 Div0 - - - -0.976 10:03 10:13Phenanthrene-d101 641090 - n 12:48 23.8882 0 0 2.4 n n 320550 68568 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 588820 - n 12:53 21.0152 0 0 2.1 n n 294410 57634 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 274520 - n 14:45 21.8575 0 0 2.2 n n 137260 28767 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 201930 - n 17:29 16.0745 0 0 1.6 n n 100970 20120 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 293630 - n 17:33 14.101 0 0 1.4 n n 146820 25314 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 118640 - n 19:41 21.0402 0 0 2.1 y n 59319 12269 0 Div0 - - - - 0.9744 19:36 19:46Benzo[k]fluoranthene-d121 172290 - n 19:44 19.8637 0 0 2 y n 86143 14244 0 Div0 - - - - 0.9769 19:39 19:49Benzo[a]pyrene-d121 304880 - n 20:17 46.6543 0 0 4.7 y n 152440 28828 0 Div0 - - - - 1.0041 20:13 20:23Perylene-d121 115750 - n 20:23 17.9246 0 0 1.8 Y y n EG141116MB 57873 9855.7 0 Div0 - - - - 1.0091 20:19 20:29Indeno[1,2,3-cd]pyrene-d121 76220 - n 22:21 17.4612 0 0 1.7 n n 38110 5451.9 0 Div0 - - - - 1.1064 22:14 22:24Dibenzo[a,h]anthracene-d141 42967 - n 22:25 14.0869 0 0 1.4 n n 21484 2458.3 0 Div0 - - - - 1.1097 22:18 22:28Benzo[g,h,i]perylene-d121 116480 - n 22:45 24.182 0 0 2.4 n n 58238 6760.6 0 Div0 - - - - 1.1262 22:39 22:49Acenaphthene-d101 10980000 - n 10:24 97.9729 0 - - n n 5489900 1250100 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 14243000 - n 15:08 86.2129 0 - - n n 7121400 1445500 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 8191800 - n 20:12 41.3325 0 - - y n 4095900 728560 0 Div0 - - - - 1.3348 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n**0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-5Comments SAMPLE X50 DILX10 R»Sample size 1Filename 4-141115B06Acquired 16-Nov-2014 04:44Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 24065000 - n 7:33 444889 0 855.474 - n n 12033000 2080000 3220 646 - - - - 1.0044 7:31 7:352-Me-Naphthalene 1 2079600 - n 8:43 88076.4 0 442.352 - n n 1039800 202950 812 249.9 - - - - 1.0058 8:41 8:451-Me-Naphthalene 1 1480100 - n 8:52 65421.2 0 461.669 - n n 740030 140910 812 173.5 - - - - 1.0231 8:50 8:54Acenaphthylene 1 6244000 - n 10:09 125384 0 271.884 - y n 3122000 652660 1151 567 - - - - 1.0016 10:07 10:11Acenaphthene1 650350 - n 10:26 26556.8 0 340.716 - y n 325180 69400 709 97.8 - - - - 1.0296 10:25 10:29Fluorene1 1241300 - n 11:18 58077.1 0 309.113 - Y y n EG141116MB 620670 84584 500 169.1 - - - - 0.884 11:14 11:18Phenanthrene 1 95814000 - n 12:49 1585600 0 125.673 - y n 47907000 9371400 575 16301.2 - - - - 1.0026 12:47 12:51Anthracene 1 14142000 - n 12:54 208188 0 157.12 - y n 7071000 646940 575 1125.3 - - - - 1.0013 12:53 12:57Fluoranthene 1 197790000 - n 14:46 4096920 0 623.269 - y n 98895000 21082000 2240 9412.4 - - - - 1.0023 14:44 14:48Pyrene 1 154840000 - n 15:09 2989900 0 581.044 - y n 77418000 16094000 2240 7185.5 - - - - 1.0022 15:06 15:10Benz[a]anthracene 1 24629000 - n 17:31 706892 0 204.07 - y n 12315000 2327300 555 4194.8 - - - - 1.0029 17:29 17:33Chrysene/Triphenylene 1 76670000 - n 17:35 1479100 0 190.833 - y n 38335000 4930500 555 8886.7 - - - - 1.0029 17:33 17:37Benzo[b]fluoranthene 1 14650000 - n 19:44 614180 0 320.484 - Y y n EG141116MB 7325100 1183700 606 1954.3 - - - - 1.0034 19:41 19:45Benzo[k]fluoranthene 1 7399300 - n 19:45 207476 0 324.692 - Y y n EG141116MB 3699700 568320 606 938.3 - - - - 1.0008 19:45 19:49Benzo[e]pyrene 1 7260400 - n 20:14 232672 0 377.776 - y n 3630200 616410 606 1017.7 - - - - 1.0025 20:12 20:16Benzo[a]pyrene 1 3636400 - n 20:20 121208 0 392.924 - y n 1818200 215320 606 355.5 - - - - 1.0025 20:18 20:22Perylene 1 788550 - n 20:30 20629.4 0 292.284 - y n 394280 40764 606 67.3 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 563750 - n 22:21 40284.3 0 486.976 - y n 281880 28131 272 103.6 - - - - 1.0015 22:20 22:24Dibenzo[a,h]anthracene1 93363 - n 22:26 5893.33 0 258.261 - Y y n EG141116MB 46681 5336.4 163 32.7 - - - - 1.003 22:23 22:27Benzo[g,h,i]perylene1 601480 - n 22:46 27627.7 0 254.728 - y n 300740 32792 272 120.7 - - - - 1.0022 22:44 22:48Fluorene-d101 19625 - n 11:14 1312.05 0 0 0.3 n n 9812.5 2022.3 0 Div0 - - - - 0.8787 11:08 11:18p-Terphenyl-d141 33644 - n 15:34 1763.7 0 0 0.4 n n 16822 2044.2 0 Div0 - - - - 1.0566 15:28 15:38Naphthalene-d81 21206000 - n 7:31 435796 0 81.1482 87 n n 10603000 1844500 364 5067.3 - - - - 0.7239 7:26 7:362-Me-Naphthalene-d101 7766600 - n 8:40 436869 0 0 87.2 n n 3883300 754760 0 Div0 - - - - 0.8347 8:34 8:44Acenaphthylene-d81 17209000 - n 10:08 411614 0 0 82.2 n n 8604400 1828700 0 Div0 - - - - 0.9759 10:02 10:12Phenanthrene-d101 27681000 - n 12:47 411492 0 0 82.1 n n 13841000 2619400 0 Div0 - - - - 1.2311 12:42 12:52Anthracene-d101 30037000 - n 12:53 427682 0 0 85.4 n n 15018000 2022400 0 Div0 - - - - 1.2408 12:47 12:57Fluoranthene-d101 16209000 - n 14:44 430946 0 0 86 n n 8104300 1508200 0 Div0 - - - - 0.9746 14:39 14:49Benz[a]anthracene-d121 13561000 - n 17:28 360462 0 0 71.9 n n 6780400 1322700 0 Div0 - - - - 1.1555 17:23 17:33Chrysene-d121 23216000 - n 17:32 372301 0 0 74.3 n n 11608000 1627700 0 Div0 - - - - 1.1599 17:26 17:36Benzo[b]fluoranthene-d121 10256000 - n 19:40 401822 0 0 80.2 n n 5128200 1015800 0 Div0 - - - - 0.9744 19:35 19:45Benzo[k]fluoranthene-d121 17196000 - n 19:44 437977 0 0 87.4 n n 8598100 1124400 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 12400000 - n 20:17 419169 0 0 83.7 n n 6200000 796420 0 Div0 - - - - 1.005 20:12 20:22Perylene-d121 12145000 - n 20:27 415470 0 0 82.9 n n 6072300 823010 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 7038200 - n 22:19 356186 0 0 71.1 n n 3519100 350650 0 Div0 - - - - 1.1057 22:13 22:23Dibenzo[a,h]anthracene-d141 5041100 - n 22:22 365102 0 0 72.9 n n 2520600 251450 0 Div0 - - - - 1.1082 22:17 22:27Benzo[g,h,i]perylene-d121 8912300 - n 22:43 408745 0 0 81.6 n n 4456200 545650 0 Div0 - - - - 1.1255 22:38 22:48Acenaphthene-d101 13789000 - n 10:23 123.036 0 - - n n 6894300 1588900 0 Div0 - - - - 0.6869 10:13 10:33Pyrene-d101 21369000 - n 15:07 129.348 0 - - n n 10685000 2081100 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 18578000 - n 20:11 93.7392 0 - - n n 9289200 1597400 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-5Comments DILUTIONX50000Sample size 1Filename 4-141115A21Acquired 16-Nov-2014 00:09Processed 16-Nov-2014 10:04Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 2878300 - n 7:34 529681 0 10639.5 - n n 1439100 228950 3996 57.3 - - - - 1.0044 7:32 7:362-Me-Naphthalene 1 207310 - n 8:44 105631 0 2933.33 - n n 103660 17192 428 40.2 - - - - 1.0077 8:41 8:451-Me-Naphthalene 1 176470 - n 8:53 93841.9 0 3061.42 - n n 88234 15289 428 35.7 - - - - 1.025 8:50 8:54Acenaphthylene 1 568360 - n 10:10 119720 0 1925.67 - y n 284180 58541 766 76.5 - - - - 1.0016 10:08 10:12Acenaphthene 1 60419 - n 10:27 25879.6 0 2034.65 - y n 30209 6841.4 398 17.2 - - - - 1.0296 10:26 10:30Fluorene 1 109020 - n 11:19 60328.6 0 2189.75 - Y y n EG141116MB 54511 9328.1 276 33.8 - - - - 0.8841 11:17 11:21Phenanthrene 1 8012400 - n 12:51 1568270 0 7575.64 - y n 4006200 679830 2697 252.1 - - - - 1.0039 12:48 12:52Anthracene1 1835200 - n 12:55 357579 0 11741.4 - y n 917580 93845 2697 34.8 - - - - 1.0013 12:54 12:58Fluoranthene1 13772000 - n 14:47 3338490 0 7538.56 - y n 6886000 1178300 2121 555.6 - - - - 1.0023 14:45 14:49Pyrene1 11525000 - n 15:10 2604430 0 7027.83 - y n 5762300 1015800 2121 479 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 1684600 - n 17:33 639765 0 1954.37 - y n 842300 162050 350 463.5 - - - - 1.0029 17:31 17:35Chrysene/Triphenylene1 7409400 - n 17:36 1643570 0 1848.52 - y n 3704700 337490 350 965.2 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 1430000 - n 19:44 634284 0 4401.84 - Y y n EG141116MB 714980 96037 699 137.4 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 702150 - n 19:47 206218 0 5013.24 - Y y n EG141116MB 351070 49749 699 71.2 - - - - 1.0017 19:46 19:50Benzo[e]pyrene1 767260 - n 20:15 244718 0 5598.64 - Y y n EG141116MB 383630 57018 699 81.6 - - - - 1.0033 20:12 20:16Benzo[a]pyrene1 379670 - n 20:21 125953 0 5823.15 - Y y n EG141116MB 189840 21010 699 30.1 - - - - 1.0025 20:19 20:23Perylene1 96156 - n 20:31 23949.3 0 3893.58 - Y y n EG141116MB 48078 5537.2 699 7.9 - - - - 1.0024 20:28 20:32Indeno[1,2,3-cd]pyrene1 47115 - n 22:23 30267.1 0 4474.77 - Y y n EG141116MB 23557 2694.5 231 11.7 - - - - 1.0022 22:21 22:25Dibenzo[a,h]anthracene1 11406 - n 22:28 7216.87 0 3423.5 - Y y n EG141116MB 5702.8 864.87 180 4.8 - - - - 1.003 22:25 22:29Benzo[g,h,i]perylene1 60500 - n 22:47 25454.9 0 1997.53 - Y y n EG141116MB 30250 3680.2 231 15.9 - - - - 1.0022 22:45 22:49Fluorene-d101 1795 - n 11:15 1419.4 0 0 0.3 n n 897.51 224.79 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 1087 - n 15:37 666.886 0 0 0.1 n n 543.52 152 0 Div0 - - - - 1.0588 15:29 15:39Naphthalene-d81 2130300 - n 7:32 478147 0 359.054 95.4 n n 1065100 184050 140 1314.6 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 645570 - n 8:40 396609 0 0 79.2 n n 322780 59993 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 1640600 - n 10:09 428579 0 0 85.5 n n 820280 171760 0 Div0 - - - - 0.976 10:03 10:13Phenanthrene-d101 2340400 - n 12:48 379986 0 0 75.8 n n 1170200 203870 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 2269300 - n 12:54 352913 0 0 70.4 n n 1134700 126970 0 Div0 - - - - 1.2404 12:48 12:58Fluoranthene-d101 1385000 - n 14:45 472676 0 0 94.3 n n 692500 118060 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 1024900 - n 17:30 349686 0 0 69.8 n n 512430 87041 0 Div0 - - - - 1.1564 17:24 17:34Chrysene-d121 2019100 - n 17:33 415622 0 0 83 n n 1009600 105900 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 969380 - n 19:41 369942 0 0 73.8 n n 484690 85332 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 1641800 - n 19:45 407318 0 0 81.3 n n 820880 84020 0 Div0 - - - - 0.9785 19:38 19:48Benzo[a]pyrene-d121 1245900 - n 20:18 410256 0 0 81.9 n n 622950 62004 0 Div0 - - - - 1.0058 20:12 20:22Perylene-d121 1275600 - n 20:28 425092 0 0 84.8 n n 637820 71283 0 Div0 - - - - 1.014 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 782880 - n 22:20 385937 0 0 77 n n 391440 32441 0 Div0 - - - - 1.1065 22:13 22:23Dibenzo[a,h]anthracene-d141 502900 - n 22:24 354791 0 0 70.8 n n 251450 20913 0 Div0 - - - - 1.1098 22:17 22:27Benzo[g,h,i]perylene-d121 972970 - n 22:44 434676 0 0 86.8 n n 486490 59153 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 1262500 - n 10:24 11.265 0 - - n n 631240 138110 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 1664700 - n 15:08 10.0768 0 - - n n 832370 144880 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 1907200 - n 20:11 9.62313 0 - - n n 953610 142580 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-6Comments SAMPLE X50Sample size 1Filename 4-141115B20Acquired 16-Nov-2014 12:44Processed 16-Nov-2014 14:25Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 175590000 - n 7:33 347093 0 201.199 - n n 87797000 18355000 7644 2401.2 - - - - 1.0044 7:31 7:352-Me-Naphthalene1 13612000 - n 8:43 71100.9 0 31.1527 - n n 6806000 1420800 544 2611.8 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 9161500 - n 8:52 49943.9 0 32.513 - n n 4580800 980010 544 1801.5 - - - - 1.0231 8:50 8:54Acenaphthylene1 56995000 - n 10:09 129060 0 28.0264 - y n 28498000 6496800 1118 5812.5 - - - - 1.0016 10:07 10:11Acenaphthene1 4543200 - n 10:27 20919.9 0 123.006 - y n 2271600 524190 2412 217.3 - - - - 1.0313 10:25 10:29Fluorene1 13275000 - n 11:18 70112.4 0 39.1367 - y n 6637300 1163800 669 1738.9 - - - - 0.8828 11:15 11:19Phenanthrene1 707340000 - n 12:50 1321460 0 104.596 - y n 353670000 76948000 5057 15216.5 - - - - 1.0026 12:48 12:52Anthracene1 60108000 - n 12:54 103511 0 120.023 - y n 30054000 2926900 5057 578.8 - - - - 1.0013 12:53 12:57Fluoranthene1 806640000 - n 14:47 1822780 0 73.8716 - y n 403320000 80467000 2660 30254.2 - - - - 1.0034 14:44 14:48Pyrene1 695220000 - n 15:09 1464570 0 68.8669 - y n 347610000 74177000 2660 27889.1 - - - - 1.0011 15:07 15:11Benz[a]anthracene1 37075000 - n 17:32 175881 0 91.5555 - y n 18537000 3435200 1516 2265.9 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 121140000 - n 17:36 393697 0 79.0896 - y n 60572000 8327300 1516 5492.8 - - - - 1.0038 17:33 17:37Benzo[b]fluoranthene1 17907000 - n 19:44 158306 0 441.188 - y n 8953500 1373700 4649 295.5 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 8422800 - n 19:46 59124.3 0 509.526 - y n 4211400 642050 4649 138.1 - - - - 1.0017 19:45 19:49Benzo[e]pyrene1 8768700 - n 20:14 35162.3 0 235.526 - y n 4384400 679680 4649 146.2 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 3469400 - n 20:21 14470.2 0 244.97 - y n 1734700 188030 4649 40.4 - - - - 1.0008 20:19 20:23Perylene1 792550 - n 20:30 3509.97 0 335.47 - y n 396280 43140 4649 9.3 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 611460 - n 22:23 12801.5 0 124.375 - y n 305730 22599 289 78.2 - - - - 1.0015 22:22 22:26Dibenzo[a,h]anthracene1 98481 - n 22:28 1903.21 0 96.8278 - y n 49240 4301.7 250 17.2 - - - - 1.003 22:25 22:29Benzo[g,h,i]perylene1 699150 - n 22:48 9825.59 0 68.1559 - y n 349570 31187 289 107.9 - - - - 1.0022 22:46 22:50Fluorene-d101 165290 - n 11:15 1247.52 0 0 124.8 n n 82645 15655 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 148540 - n 15:34 849.458 0 0 84.9 n n 74268 13088 0 Div0 - - - - 1.0566 15:28 15:38Naphthalene-d81 395860 - n 7:31 20.6118 0 0 2.1 n n 197930 37161 0 Div0 - - - - 0.7228 7:27 7:372-Me-Naphthalene-d101 125700 - n 8:40 17.9136 0 0 1.8 n n 62848 14331 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 304610 - n 10:08 18.4596 0 0 1.8 n n 152300 34386 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 489420 - n 12:48 18.4334 0 0 1.8 n n 244710 55257 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 512510 - n 12:53 18.4891 0 0 1.8 n n 256260 46482 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 296560 - n 14:44 18.9543 0 0 1.9 n n 148280 30160 0 Div0 - - - - 0.9736 14:40 14:50Benz[a]anthracene-d121 163760 - n 17:29 10.4641 0 0 1 n n 81879 16080 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 275090 - n 17:32 10.6045 0 0 1.1 n n 137540 21421 0 Div0 - - - - 1.1586 17:27 17:37Benzo[b]fluoranthene-d121 97082 - n 19:41 16.2091 0 0 1.6 Y y n EG141116MB 48541 11304 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 137110 - n 19:44 14.882 0 0 1.5 Y y n EG141116MB 68553 10976 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 197800 - n 20:20 28.4959 0 0 2.8 Y y n EG141116MB 98900 19569 0 Div0 - - - - 1.0074 20:15 20:25Perylene-d121 143200 - n 20:27 20.877 0 0 2.1 Y y n EG141116MB 71598 10985 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 47949 - n 22:21 10.3414 0 0 1 n n 23975 2916.8 0 Div0 - - - - 1.1073 22:13 22:23Dibenzo[a,h]anthracene-d141 32865 - n 22:24 10.1441 0 0 1 n n 16433 2049.9 0 Div0 - - - - 1.1098 22:17 22:27Benzo[g,h,i]perylene-d121 58142 - n 22:45 11.3641 0 0 1.1 n n 29071 4332.6 0 Div0 - - - - 1.1272 22:38 22:48Acenaphthene-d101 10863000 - n 10:24 96.9284 0 - - n n 5431400 1277100 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 17743000 - n 15:08 107.399 0 - - n n 8871500 1795200 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 8701300 - n 20:11 43.9034 0 - - y n 4350700 665810 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n **0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-6Comments SAMPLE X50 DILX10 R»Sample size 1Filename 4-141115B07Acquired 16-Nov-2014 05:18Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 5010Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 25110000 - n 7:34 487151 0 823.229 - n n 12555000 2151900 2960 727 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 1939300 - n 8:44 88738.5 0 186.421 - n n 969670 187700 308 609.4 - - - - 1.0077 8:41 8:451-Me-Naphthalene1 1422500 - n 8:52 67933.7 0 194.562 - n n 711270 139620 308 453.3 - - - - 1.0231 8:50 8:54Acenaphthylene1 8888500 - n 10:09 187885 0 357.459 - y n 4444200 922970 1441 640.6 - - - - 1.0016 10:07 10:11Acenaphthene1 685720 - n 10:27 29475.4 0 172.052 - y n 342860 73462 341 215.4 - - - - 1.0313 10:25 10:29Fluorene1 1697000 - n 11:19 83376.9 0 234.687 - Y y n EG141116MB 848490 119470 361 331.1 - - - - 0.8841 11:17 11:21Phenanthrene1 79017000 - n 12:51 1373210 0 262.273 - Y y n EG141117MB 39508000 7581700 1140 6650.8 - - - - 1.0039 12:48 12:52Anthracene1 11120000 - n 12:55 167244 0 326.688 - Y y n EG141117MB 5560100 556120 1140 487.8 - - - - 1.0026 12:53 12:57Fluoranthene1 95783000 - n 14:47 2066100 0 809.109 - y n 47892000 9311700 2837 3282.8 - - - - 1.0023 14:45 14:49Pyrene1 71057000 - n 15:09 1428910 0 754.293 - y n 35529000 6745500 2837 2378.1 - - - - 1.0011 15:07 15:11Benz[a]anthracene1 5926300 - n 17:32 176968 0 234.868 - y n 2963200 604970 576 1049.9 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 23975000 - n 17:36 460610 0 221.449 - y n 11987000 1248200 576 2166.3 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 4205200 - n 19:44 178283 0 237.84 - Y y n EG141116MB 2102600 332290 419 793.2 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 1935500 - n 19:46 59283.2 0 253.677 - Y y n EG141116MB 967740 148290 419 354 - - - - 1.0017 19:45 19:49Benzo[e]pyrene1 2173100 - n 20:15 75041.4 0 269.511 - y n 1086600 175100 419 418 - - - - 1.0033 20:12 20:16Benzo[a]pyrene1 834840 - n 20:21 29984.6 0 280.318 - y n 417420 49888 419 119.1 - - - - 1.0033 20:18 20:22Perylene1 226620 - n 20:30 6219.37 0 215.207 - y n 113310 10818 419 25.8 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 166630 - n 22:22 11245.7 0 279.51 - Y y n EG141116MB 83313 8234.3 150 54.9 - - - - 1.0022 22:20 22:24Dibenzo[a,h]anthracene1 31484 - n 22:26 1984.82 0 237.114 - Y n n EG141116MB 15742 1845.2 150 12.3 - - - - 1.0022 22:24 22:28Benzo[g,h,i]perylene1 189750 - n 22:47 8401.4 0 139.837 - Y y n EG141116MB 94876 10776 150 71.8 - - - - 1.0022 22:45 22:49Fluorene-d101 22695 - n 11:16 1593.42 0 0 0.3 n n 11348 1952 0 Div0 - - - - 0.8802 11:09 11:19p-Terphenyl-d141 6183.8 - n 15:34 337.579 0 0 0.1 n n 3091.9 787.4 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 20207000 - n 7:32 437599 0 343.467 87.3 n n 10103000 1762000 1448 1216.8 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 7188700 - n 8:40 426115 0 0 85.1 n n 3594400 679320 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 16348000 - n 10:08 412061 0 0 82.2 n n 8174000 1741000 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 26359000 - n 12:48 412915 0 0 82.4 n n 13180000 2488800 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 29401000 - n 12:53 441148 0 0 88.1 n n 14701000 1928700 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 15565000 - n 14:45 443129 0 0 88.4 n n 7782300 1471200 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 13034000 - n 17:29 370996 0 0 74.1 n n 6517000 1193600 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 23312000 - n 17:33 400311 0 0 79.9 n n 11656000 1456700 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 10142000 - n 19:41 407086 0 0 81.3 n n 5071100 946690 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 15742000 - n 19:44 410775 0 0 82 n n 7871100 995330 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 11508000 - n 20:17 398542 0 0 79.5 n n 5753800 772100 0 Div0 - - - - 1.005 20:12 20:22Perylene-d121 11577000 - n 20:27 405754 0 0 81 n n 5788400 773080 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 7451900 - n 22:19 386369 0 0 77.1 n n 3726000 337380 0 Div0 - - - - 1.1057 22:13 22:23Dibenzo[a,h]anthracene-d141 5047500 - n 22:23 374532 0 0 74.8 n n 2523800 251630 0 Div0 - - - - 1.109 22:17 22:27Benzo[g,h,i]perylene-d121 9245900 - n 22:44 434440 0 0 86.7 n n 4622900 548900 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 13085000 - n 10:24 116.755 0 - - n n 6542400 1493300 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 19956000 - n 15:08 120.794 0 - - n n 9977900 1808800 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 18134000 - n 20:11 91.4958 0 - - n n 9066900 1537500 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample IDL1535265-7CommentsSAMPLE X10Sample size1Filename4-141115B12Acquired 16-Nov-2014 08:10Processed 16-Nov-2014 14:20InstrumentHRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level10Target Analyte#Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding CommentsNaphthalene1 906690000 - n 7:34 41667.5 0 40.6088 - y n2-Me-Naphthalene1 138960000 - n 8:43 14067.2 0 16.8199 - n n1-Me-Naphthalene1 90895000 - n 8:53 9603.61 0 17.5544 - n nAcenaphthylene1 348120000 - n 10:10 14770 0 2.87459 - y nAcenaphthene1 20635000 - n 10:27 1780.34 0 1.54584 - y nFluorene1 28903000 - n 11:18 2735.18 0 15.498 - y nPhenanthrene1 895430000 - n 12:50 29972.4 0 6.56526 - y nAnthracene1 135170000 - n 12:55 4748.06 0 7.33878 - y nFluoranthene1 795690000 - n 14:47 38069.1 0 7.93399 - y nPyrene1 703070000 - n 15:10 31358.6 0 7.39647 - y nBenz[a]anthracene1 83645000 - n 17:32 3533.39 0 3.68618 - y nChrysene/Triphenylene1 310130000 - n 17:36 13791.1 0 4.00467 - y nBenzo[b]fluoranthene1 100820000 - n 19:44 5171.03 0 1.36164 - Y y n EG141116MBBenzo[k]fluoranthene1 39405000 - n 19:47 1951.64 0 1.4991 - Y y n EG141116MBBenzo[e]pyrene1 47667000 - n 20:15 2544.98 0 1.7698 - Y y n EG141116MBBenzo[a]pyrene1 14957000 - n 20:21 830.591 0 1.84076 - Y y n EG141116MBPerylene1 2573500 - n 20:31 107.218 0 1.37971 - Y y n EG141116MBIndeno[1,2,3-cd]pyrene1 13176000 - n 22:22 1063.38 0 0.616077 - y nDibenzo[a,h]anthracene1 2949700 - n 22:26 207.464 0 0.826039 - y nBenzo[g,h,i]perylene1 13731000 - n 22:47 820.664 0 0.357547 - y nFluorene-d101 8757400 - n 11:15 1184.25 0 0 118.4 n np-Terphenyl-d141 9470600 - n 15:34 1146.73 0 0 114.7 n nNaphthalene-d81 17027000 - n 7:32 678.722 0 0.508622 67.9 n n2-Me-Naphthalene-d101 6485500 - n 8:41 707.596 0 0 70.8 n nAcenaphthylene-d81 16257000 - n 10:09 754.223 0 0 75.4 n nPhenanthrene-d101 27316000 - n 12:48 787.622 0 0 78.8 n nAnthracene-d101 25125000 - n 12:53 693.91 0 0 69.4 n nFluoranthene-d101 14007000 - n 14:45 821.099 0 0 82.1 n nBenz[a]anthracene-d121 18391000 - n 17:29 1077.84 0 0 107.8 n nChrysene-d121 20103000 - n 17:33 710.804 0 0 71.1 n nBenzo[b]fluoranthene-d121 16734000 - n 19:41 957.201 0 0 95.7 n nBenzo[k]fluoranthene-d121 19432000 - n 19:44 722.635 0 0 72.3 n nBenzo[a]pyrene-d121 14856000 - n 20:17 733.242 0 0 73.3 n nPerylene-d121 15222000 - n 20:27 760.322 0 0 76 n nIndeno[1,2,3-cd]pyrene-d121 12439000 - n 22:20 919.129 0 0 91.9 n nDibenzo[a,h]anthracene-d141 9030600 - n 22:23 954.955 0 0 95.5 n nBenzo[g,h,i]perylene-d121 13671000 - n 22:44 915.469 0 0 91.5 n nAcenaphthene-d101 14189000 - n 10:24 126.611 0 - - n nPyrene-d101 19345000 - n 15:08 117.096 0 - - n nBenzo[e]pyrene-d121 25397000 - n 20:11 128.146 0 - - n nF1 Lock Mass0 * NotFnd * * - - nF2 Lock Mass0 * NotFnd * * - - nF3 Lock Mass0 * NotFnd * * - - nF4 Lock Mass0 * NotFnd * * - - nF5 Lock Mass0 * NotFnd * * - - nF6 Lock Mass0 * NotFnd * * - - nDUMMY LINE0 * NotFnd * * - - nQuantification Report OPUS v3.6Sample ID L1535265-7Comments SAMPLE X50Sample size 1Filename 4-141115B08Acquired 16-Nov-2014 05:52Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 27562000 - n 7:33 37665.1 0 61.4328 - y n 13781000 2512600 3325 755.7 - - - - 1.0044 7:31 7:352-Me-Naphthalene1 3899900 - n 8:43 14511.8 0 10.8988 - n n 1949900 396540 252 1573.6 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 3260200 - n 8:52 12661.4 0 11.3747 - n n 1630100 340900 252 1352.8 - - - - 1.0231 8:50 8:54Acenaphthylene1 7865300 - n 10:10 12099.7 0 26.0988 - y n 3932700 821630 1400 586.8 - - - - 1.0033 10:07 10:11Acenaphthene1 622150 - n 10:27 1946.27 0 34.1405 - y n 311080 70271 901 78 - - - - 1.0313 10:25 10:29Fluorene1 707830 - n 11:19 2542.84 0 48.6024 - y n 353910 61226 1000 61.2 - - - - 0.8841 11:17 11:21Phenanthrene1 28658000 - n 12:51 36415.9 0 14.9229 - Y y n EG141116MB 14329000 2532000 868 2916.9 - - - - 1.0039 12:48 12:52Anthracene1 7021300 - n 12:56 8622.98 0 21.335 - Y y n EG141116MB 3510700 316800 868 365 - - - - 1.0039 12:53 12:57Fluoranthene1 21833000 - n 14:47 36805.9 0 25.7255 - y n 10916000 1836200 1099 1671.1 - - - - 1.0023 14:45 14:49Pyrene1 17028000 - n 15:09 26761.7 0 23.9827 - y n 8514100 1533000 1099 1395.2 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 626550 - n 17:33 2187.34 0 53.4124 - y n 313280 85285 985 86.5 - - - - 1.0029 17:31 17:35Chrysene/Triphenylene1 626550 - n 17:33 2517.08 0 61.4643 - y n 313280 85285 985 86.5 - - - - 1.0029 17:31 17:35Benzo[b]fluoranthene1 725830 - n 19:45 4063.8 0 18.46 - Y y n EG141116MB 362920 60880 254 239.5 - - - - 1.0025 19:43 19:47Benzo[k]fluoranthene1 518250 - n 19:47 2935.2 0 23.8613 - Y y n EG141116MB 259120 39840 254 156.7 - - - - 1.0008 19:47 19:51Benzo[e]pyrene1 647220 - n 20:15 841.814 0 5.51761 - Y y n EG141116MB 323610 46154 254 181.6 - - - - 1.0033 20:12 20:16Benzo[a]pyrene1 79721 - n 20:22 107.848 0 5.73886 - Y y n EG141116MB 39861 8197.3 254 32.2 - - - - 1.0041 20:18 20:22Perylene1 23056 - n 20:30 85.1588 0 11.971 - Y y n EG141116MB 11528 2210 254 8.7 - - - - 1.0016 20:28 20:32Indeno[1,2,3-cd]pyrene1 80125 - n 22:25 1042.5 0 25.5784 - Y y n EG141116MB 40062 3505.9 90 38.8 - - - - 1.003 22:23 22:27Dibenzo[a,h]anthracene1 7193.5 - n 22:27 215.703 0 28.0971 - Y y n EG141116MB 3596.8 803.29 90 8.9 - - - - 1.0022 22:23 22:27Benzo[g,h,i]perylene1 101630 - n 22:48 579.166 0 13.5 - Y y n EG141116MB 50815 5053.6 90 55.9 - - - - 1.0022 22:46 22:50Fluorene-d101 182730 - n 11:15 938.041 0 0 93.8 n n 91363 16629 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 181940 - n 15:35 776.256 0 0 77.6 n n 90972 11578 0 Div0 - - - - 1.0565 15:29 15:39Naphthalene-d81 572590 - n 7:31 23.7881 0 0.065043 2.4 n n 286300 52941 144 367.6 - - - - 0.7228 7:27 7:372-Me-Naphthalene-d101 176440 - n 8:40 20.0635 0 0 2 n n 88221 18976 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 448370 - n 10:08 21.68 0 0 2.2 n n 224180 46256 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 719560 - n 12:48 21.6237 0 0 2.2 n n 359780 66483 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 718660 - n 12:53 20.6859 0 0 2.1 n n 359330 44887 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 397510 - n 14:45 24.0274 0 0 2.4 n n 198760 35779 0 Div0 - - - - 0.9757 14:39 14:49Benz[a]anthracene-d121 222530 - n 17:30 13.4477 0 0 1.3 n n 111270 17917 0 Div0 - - - - 1.1577 17:23 17:33Chrysene-d121 222530 - n 17:30 8.11275 0 0 0.8 n n 111270 17917 0 Div0 - - - - 1.1577 17:26 17:36Benzo[b]fluoranthene-d121 153290 - n 19:42 20.6538 0 0 2.1 y n 76645 14772 0 Div0 - - - - 0.9761 19:34 19:44Benzo[k]fluoranthene-d121 169930 - n 19:46 14.8845 0 0 1.5 y n 84964 12816 0 Div0 - - - - 0.9794 19:39 19:49Benzo[a]pyrene-d121 609820 - n 20:17 70.8959 0 0 7.1 y n 304910 45676 0 Div0 - - - - 1.005 20:12 20:22Perylene-d121 171690 - n 20:28 20.2002 0 0 2 y n 85847 16832 0 Div0 - - - - 1.014 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 77155 - n 22:21 13.4284 0 0 1.3 y n 38577 4432.9 0 Div0 - - - - 1.1073 22:16 22:26Dibenzo[a,h]anthracene-d141 21182 - n 22:24 5.2759 0 0 0.5 n n 10591 2553.3 0 Div0 - - - - 1.1098 22:19 22:29Benzo[g,h,i]perylene-d121 143380 - n 22:45 22.6153 0 0 2.3 n n 71691 6836.4 0 Div0 - - - - 1.1272 22:38 22:48Acenaphthene-d101 13614000 - n 10:24 121.481 0 - - n n 6807200 1565300 0 Div0 - - - - 0.688 10:13 10:33Pyrene-d101 18761000 - n 15:07 113.564 0 - - n n 9380700 1678600 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 10783000 - n 20:11 54.4045 0 - - y n 5391300 833260 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-8Comments SAMPLE X10Sample size 1Filename 4-141115B13Acquired 16-Nov-2014 08:44Processed 16-Nov-2014 14:24Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 606030000 - n 7:34 26408.3 0 63.2898 - n n 303020000 67186000 115132 583.6 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 150370000 - n 8:44 13919.9 0 3.37125 - n n 75184000 18666000 3500 5333.2 - - - - 1.0058 8:42 8:461-Me-Naphthalene1 107190000 - n 8:53 10356.5 0 3.51846 - n n 53597000 13952000 3500 3986.4 - - - -1.023 8:51 8:55Acenaphthylene1 85694000 - n 10:10 3665.15 0 3.22489 - y n 42847000 10151000 6922 1466.5 - - - - 1.0016 10:08 10:12Acenaphthene1 18659000 - n 10:28 1622.82 0 1.89486 - n n 9329400 2248600 2000 1124.3 - - - - 1.0312 10:26 10:30Fluorene1 24763000 - n 11:18 2367.31 0 5.29912 - y n 12381000 2600500 4924 528.2 - - - - 0.8828 11:15 11:19Phenanthrene1 672650000 - n 12:51 22745.5 0 7.76486 - y n 336330000 74012000 20397 3628.5 - - - - 1.0039 12:48 12:52Anthracene1 48660000 - n 12:55 1817.6 0 9.82978 - y n 24330000 3982400 20397 195.2 - - - - 1.0026 12:53 12:57Fluoranthene1 220750000 - n 14:47 11805.2 0 4.07893 - y n 110370000 25000000 6620 3776.2 - - - - 1.0023 14:45 14:49Pyrene1 159490000 - n 15:10 7951.32 0 3.80259 - y n 79744000 17070000 6620 2578.3 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 33867000 - n 17:32 3346.58 0 4.72447 - Y y n EG141116MB 16934000 3120700 3775 826.7 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 108410000 - n 17:37 9992.48 0 5.03945 - Y y n EG141116MB 54204000 8448600 3775 2238.1 - - - - 1.0038 17:34 17:38Benzo[b]fluoranthene1 33049000 - n 19:44 5464.09 0 3.18728 - Y y n EG141116MB 16524000 2619400 1547 1692.8 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 11783000 - n 19:47 1596.06 0 3.56191 - Y y n EG141116MB 5891600 1002500 1547 647.9 - - - - 1.0025 19:45 19:49Benzo[e]pyrene1 15737000 - n 20:15 2773.33 0 4.94459 - Y y n EG141116MB 7868300 1361400 1547 879.8 - - - - 1.0025 20:13 20:17Benzo[a]pyrene1 2492700 - n 20:21 456.911 0 5.14287 - Y y n EG141116MB 1246300 143100 1547 92.5 - - - - 1.0025 20:19 20:23Perylene1 640450 - n 20:31 87.7751 0 3.55186 - Y y n EG141116MB 320220 33637 1547 21.7 - - - - 1.0033 20:27 20:31Indeno[1,2,3-cd]pyrene1 4057200 - n 22:23 1169.03 0 3.83501 - Y y n EG141116MB 2028600 206370 522 395.6 - - - - 1.0022 22:21 22:25Dibenzo[a,h]anthracene1 1254100 - n 22:26 324.072 0 1.34808 - Y y n EG141116MB 627060 57623 244 235.9 - - - - 1.0022 22:24 22:28Benzo[g,h,i]perylene1 3561100 - n 22:48 751.189 0 2.17667 - y n 1780500 209210 522 401 - - - - 1.0029 22:45 22:49Fluorene-d101 7960900 - n 11:15 1087.55 0 0 108.8 n n 3980500 899810 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 6303200 - n 15:34 853.091 0 0 85.3 n n 3151600 594250 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 17957000 - n 7:32 837.372 0 0.750771 83.7 n n 8978500 1779300 1560 1140.6 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 7092400 - n 8:41 905.255 0 0.010538 90.5 n n 3546200 852040 8 106504.8 - - - - 0.8349 8:35 8:45Acenaphthylene-d81 16127000 - n 10:09 875.282 0 0 87.5 n n 8063400 1850600 0 Div0 - - - -0.976 10:03 10:13Phenanthrene-d101 27040000 - n 12:48 912.09 0 0 91.2 n n 13520000 3002400 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 23629000 - n 12:53 763.418 0 0 76.3 n n 11814000 2289300 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 12531000 - n 14:45 1027.51 0 0 102.8 n n 6265500 1359600 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 7861800 - n 17:29 644.501 0 0 64.5 n n 3930900 775900 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 9698800 - n 17:33 479.667 0 0 48 n n 4849400 837060 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 5191000 - n 19:41 1041.89 0 0 104.2 n n 2595500 520830 0 Div0 - - - - 0.9744 19:36 19:46Benzo[k]fluoranthene-d121 7105300 - n 19:44 927.125 0 0 92.7 n n 3552700 522620 0 Div0 - - - - 0.9769 19:39 19:49Benzo[a]pyrene-d121 4500700 - n 20:18 779.436 0 0 77.9 n n 2250300 310270 0 Div0 - - - -1.005 20:13 20:23Perylene-d121 4627200 - n 20:27 810.969 0 0 81.1 n n 2313600 345340 0 Div0 - - - - 1.0124 20:23 20:33Indeno[1,2,3-cd]pyrene-d121 3483900 - n 22:20 903.273 0 0 90.3 n n 1742000 170690 0 Div0 - - - - 1.1056 22:14 22:24Dibenzo[a,h]anthracene-d141 2457900 - n 22:23 912 0 0 91.2 n n 1229000 143840 0 Div0 - - - - 1.1081 22:18 22:28Benzo[g,h,i]perylene-d121 3873500 - n 22:44 910.13 0 0 91 n n 1936800 244790 0 Div0 - - - - 1.1254 22:39 22:49Acenaphthene-d101 12129000 - n 10:24 108.227 0 - - n n 6064500 1469100 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 13830000 - n 15:08 83.7144 0 - - n n 6915000 1393800 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 7238300 - n 20:12 36.5215 0 - - n n 3619100 649730 0 Div0 - - - - 1.3348 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29F5 Lock Mass0 * NotFnd * * - - n**0 Div0 * 25:09 25:29F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:29Quantification Report OPUS v3.6Sample ID L1535265-8Comments SAMPLE X50Sample size 1Filename 4-141115B09Acquired 16-Nov-2014 06:27Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 11033000 - n 7:33 20235.4 0 197.775 - n n 5516500 987320 7876 125.4 - - - - 1.0044 7:31 7:352-Me-Naphthalene 1 2879900 - n 8:43 13181.3 0 18.0383 - n n 1440000 287710 332 866.6 - - - - 1.0058 8:41 8:451-Me-Naphthalene 1 2643100 - n 8:52 12625.7 0 18.826 - n n 1321600 273390 332 823.5 - - - - 1.0231 8:50 8:54Acenaphthylene 1 1874100 - n 10:09 3482.1 0 17.6058 - y n 937040 185110 819 225.9 - - - - 1.0016 10:07 10:11Acenaphthene 1 431330 - n 10:26 1629.69 0 15.5643 - y n 215660 48771 356 136.9 - - - - 1.0296 10:25 10:29Fluorene 1 588940 - n 11:17 2855.01 0 33.7698 - y n 294470 48457 469 103.3 - - - - 0.8815 11:15 11:19Phenanthrene 1 12923000 - n 12:51 22158.2 0 62.5476 - y n 6461300 1094400 2457 445.4 - - - - 1.0039 12:48 12:52Anthracene 1 2782800 - n 12:54 3612.12 0 75.6079 - y n 1391400 138540 2457 56.4 - - - - 1.0013 12:53 12:57Fluoranthene 1 5140200 - n 14:47 10701.6 0 4.46404 - n n 2570100 405430 150 2702.8 - - - - 1.0023 14:45 14:49Pyrene 1 4318300 - n 15:10 8381.18 0 4.1616 - y n 2159100 352870 150 2352.5 - - - - 1.0033 15:06 15:10Benz[a]anthracene 1 549370 - n 17:34 3328.43 0 10.7016 - Y y n EG141116MB 274680 58876 112 524.2 - - - - 1.0038 17:32 17:36Chrysene/Triphenylene1 3231400 - n 17:37 9603.36 0 8.67377 - Y y n EG141116MB 1615700 130450 112 1161.4 - - - - 1.0038 17:35 17:39Benzo[b]fluoranthene1 576710 - n 19:44 5290.32 0 34.458 - Y y n EG141116MB 288350 34656 218 159.3 - - - - 1.0017 19:43 19:47Benzo[k]fluoranthene1 256130 - n 19:48 2634.79 0 38.6407 - Y y n EG141116MB 128070 17784 218 81.7 - - - - 1.0051 19:45 19:49Benzo[e]pyrene 1 387720 - n 20:14 1563.08 0 7.98646 - Y y n EG141116MB 193860 24759 218 113.8 - - - - 1.0025 20:12 20:16Benzo[a]pyrene 1 31480 - n 20:21 132.003 0 8.30671 - Y y n EG141116MB 15740 3308.4 218 15.2 - - - - 1.0025 20:19 20:23Perylene 1 14579 - n 20:30 163.327 0 17.0521 - Y y n EG141116MB 7289.4 1384.9 218 6.4 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 35665 - n 22:24 815.991 0 52.3308 - y n 17833 1852.9 100 18.5 - - - - 1.0022 22:22 22:26Dibenzo[a,h]anthracene 1 4268 - n 22:26 94.9548 0 53.7593 - n n 2134 430.09 100 4.3 - - - - 0.9993 22:23 22:27Benzo[g,h,i]perylene 1 58170 - n 22:48 855.739 0 36.9972 - y n 29085 2548.7 100 25.5 - - - - 1.0022 22:48 22:52Fluorene-d101 168710 - n 11:14 1168.72 0 0 116.9 n n 84356 13272 0 Div0 - - - - 0.8776 11:09 11:19p-Terphenyl-d141 175770 - n 15:34 926.109 0 0 92.6 n n 87884 9278.2 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 426640 - n 7:31 17.9896 0 0.003621 1.8 n n 213320 38951 8 4868.9 - - - - 0.7228 7:27 7:372-Me-Naphthalene-d101 143450 - n 8:40 16.5559 0 0 1.7 n n 71724 15105 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 371230 - n 10:08 18.2187 0 0 1.8 n n 185610 40127 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 533240 - n 12:48 16.2644 0 0 1.6 n n 266620 44904 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 679970 - n 12:53 19.8651 0 0 2 n n 339980 35857 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 321880 - n 14:45 20.0447 0 0 2 n n 160940 28147 0 Div0 - - - - 0.9757 14:39 14:49Benz[a]anthracene-d121 128220 - n 17:30 7.98311 0 0 0.8 n n 64112 10192 0 Div0 - - - - 1.1577 17:24 17:34Chrysene-d121 300810 - n 17:33 11.2984 0 0 1.1 n n 150410 14471 0 Div0 - - - - 1.161 17:27 17:37Benzo[b]fluoranthene-d121 93559 - n 19:42 17.4009 0 0 1.7 n n 46780 6773.5 0 Div0 - - - - 0.9761 19:35 19:45Benzo[k]fluoranthene-d121 93559 - n 19:42 11.3124 0 0 1.1 n n 46780 6773.5 0 Div0 - - - - 0.9761 19:38 19:48Benzo[a]pyrene-d121 196740 - n 20:18 31.5732 0 0 3.2 Y y n EG141116MB 98372 27009 0 Div0 - - - - 1.0058 20:12 20:22Perylene-d121 56606 - n 20:27 9.19326 0 0 0.9 Y y n EG141116MB 28303 10114 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 43877 - n 22:21 10.5414 0 0 1.1 y n 21938 2397.9 0 Div0 - - - - 1.1073 22:16 22:26Dibenzo[a,h]anthracene-d141 28548 - n 22:27 9.81571 0 0 1 y n 14274 1476.8 0 Div0 - - - - 1.1123 22:22 22:32Benzo[g,h,i]perylene-d121 55543 - n 22:45 12.0933 0 0 1.2 y n 27772 2760.7 0 Div0 - - - - 1.1272 22:38 22:48Acenaphthene-d101 13414000 - n 10:24 119.69 0 - - n n 6706800 1561900 0 Div0 - - - - 0.688 10:13 10:33Pyrene-d101 18211000 - n 15:07 110.23 0 - - n n 9105300 1564100 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 7811200 - n 20:11 39.4124 0 - - Y y n EG141116MB 3905600 577260 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-9Comments SAMPLE X10Sample size 1Filename 4-141115B15Acquired 16-Nov-2014 09:53Processed 16-Nov-2014 14:24Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 826870000 - n 7:35 42043.2 0 51.0537 - n n 413440000 78066000 84120 928 - - - - 1.0057 7:32 7:362-Me-Naphthalene1 169760000 - n 8:43 18310 0 2.85431 - n n 84878000 21503000 2484 8656.7 - - - - 1.006 8:41 8:451-Me-Naphthalene1 117090000 - n 8:53 13180.8 0 2.97895 - n n 58544000 15278000 2484 6150.6 - - - - 1.0241 8:50 8:54Acenaphthylene1 318790000 - n 10:10 15005.6 0 3.82638 - y n 159400000 40921000 7771 5266.1 - - - - 1.002 10:08 10:12Acenaphthene1 24327000 - n 10:27 2328.48 0 1.4186 - y n 12163000 2991200 1417 2111.4 - - - - 1.0306 10:26 10:30Fluorene1 34138000 - n 11:18 3498.93 0 8.01185 - y n 17069000 3493700 6874 508.3 - - - - 0.8827 11:15 11:19Phenanthrene1 997300000 - n 12:50 36155.1 0 4.2779 - y n 498650000 83777000 10376 8074 - - - - 1.0026 12:48 12:52Anthracene1 159650000 - n 12:55 5969.03 0 4.6203 - y n 79824000 14558000 10376 1403 - - - - 1.002 12:54 12:58Fluoranthene1 961120000 - n 14:47 43785 0 11.5153 - y n 480560000 82429000 21626 3811.6 - - - - 1.0022 14:45 14:49Pyrene1 886920000 - n 15:10 37667.1 0 10.7351 - y n 443460000 81194000 21626 3754.5 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 85725000 - n 17:33 3507.59 0 1.31956 - y n 42862000 8551900 2565 3334.3 - - - - 1.0036 17:30 17:34Chrysene/Triphenylene1 267830000 - n 17:36 10561.9 0 1.45361 - y n 133920000 19977000 2565 7789 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 107720000 - n 19:44 5081.22 0 1.20975 - y n 53859000 10136000 2103 4819.1 - - - - 1.0029 19:42 19:46Benzo[k]fluoranthene1 30966000 - n 19:47 1306.52 0 1.3357 - y n 15483000 2521900 2103 1199 - - - - 1.0021 19:46 19:50Benzo[e]pyrene1 48604000 - n 20:15 2153.35 0 1.47517 - y n 24302000 4687100 2103 2228.4 - - - - 1.0031 20:12 20:16Benzo[a]pyrene1 11066000 - n 20:21 509.922 0 1.53433 - y n 5532900 790660 2103 375.9 - - - - 1.0027 20:19 20:23Perylene1 1720100 - n 20:31 60.3603 0 1.12143 - y n 860040 133750 2103 63.6 - - - - 1.0031 20:27 20:31Indeno[1,2,3-cd]pyrene1 10459000 - n 22:22 651.184 0 0.737189 - y n 5229600 630320 553 1138.8 - - - - 1.0016 22:21 22:25Dibenzo[a,h]anthracene1 2375300 - n 22:26 128.855 0 1.23689 - y n 1187600 154530 1231 125.5 - - - - 1.0025 22:24 22:28Benzo[g,h,i]perylene1 11193000 - n 22:47 528.175 0 0.4457 - y n 5596700 735020 553 1328 - - - - 1.0022 22:45 22:49Fluorene-d101 7814200 - n 11:15 1144.47 0 0 114.4 n n 3907100 855360 0 Div0 - - - - 0.8783 11:09 11:19p-Terphenyl-d141 9793600 - n 15:34 1129.14 0 0 112.9 n n 4896800 1018600 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 15389000 - n 7:32 648.893 0 0.54712 64.9 n n 7694700 1611600 1268 1271 - - - - 0.7238 7:27 7:372-Me-Naphthalene-d101 6087000 - n 8:40 702.505 0 0 70.3 n n 3043500 714220 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 14654000 - n 10:09 719.136 0 0 71.9 n n 7326900 1750900 0 Div0 - - - - 0.9748 10:03 10:13Phenanthrene-d101 25221000 - n 12:48 769.246 0 0 76.9 n n 12611000 2772200 0 Div0 - - - - 1.2306 12:43 12:53Anthracene-d101 23606000 - n 12:54 689.617 0 0 69 n n 11803000 2477700 0 Div0 - - - - 1.2391 12:48 12:58Fluoranthene-d101 14710000 - n 14:45 796.405 0 0 79.6 n n 7355000 1573100 0 Div0 - - - - 0.9749 14:40 14:50Benz[a]anthracene-d121 18986000 - n 17:29 1027.69 0 0 102.8 n n 9493200 1887500 0 Div0 - - - - 1.1552 17:24 17:34Chrysene-d121 22670000 - n 17:33 740.257 0 0 74 n n 11335000 1971700 0 Div0 - - - - 1.1594 17:27 17:37Benzo[b]fluoranthene-d121 18194000 - n 19:41 849.794 0 0 85 n n 9097100 1865200 0 Div0 - - - - 0.9747 19:35 19:45Benzo[k]fluoranthene-d121 22810000 - n 19:45 692.627 0 0 69.3 n n 11405000 1894400 0 Div0 - - - - 0.9779 19:38 19:48Benzo[a]pyrene-d121 17903000 - n 20:18 721.507 0 0 72.2 n n 8951500 1413600 0 Div0 - - - - 1.0053 20:12 20:22Perylene-d121 18072000 - n 20:27 737.054 0 0 73.7 n n 9035900 1486800 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 16124000 - n 22:20 972.805 0 0 97.3 n n 8061900 942100 0 Div0 - - - - 1.1061 22:13 22:23Dibenzo[a,h]anthracene-d141 11708000 - n 22:23 1010.93 0 0 101.1 n n 5854100 790400 0 Div0 - - - - 1.1086 22:17 22:27Benzo[g,h,i]perylene-d121 17317000 - n 22:44 946.824 0 0 94.7 n n 8658300 1268400 0 Div0 - - - - 1.1262 22:38 22:48Acenaphthene-d101 13414000 - n 10:24 119.694 0 - - n n 6707100 1638500 0 Div0 - - - - 0.6875 10:14 10:34Pyrene-d101 20946000 - n 15:08 126.789 0 - - n n 10473000 2167600 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 31105000 - n 20:11 156.941 0 - - n n 15552000 2921500 0 Div0 - - - - 1.3336 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F5 Lock Mass0 * NotFnd * * - - n **0 Div0 * 25:09 25:290 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0Quantification Report OPUS v3.6Sample ID L1535265-9Comments SAMPLE X50 REINJECTSample size 1Filename 4-141115B14Acquired 16-Nov-2014 09:18Processed 16-Nov-2014 14:24Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 25267000 - n 7:33 44081 0 193.419 - y n 12633000 2252900 8007 281.4 - - - - 1.0044 7:31 7:352-Me-Naphthalene 1 4193000 - n 8:43 15960.3 0 18.5169 - n n 2096500 432890 388 1115.7 - - - - 1.0058 8:41 8:451-Me-Naphthalene 1 3441900 - n 8:52 13673.2 0 19.3255 - n n 1720900 355630 388 916.6 - - - - 1.0231 8:50 8:54Acenaphthylene1 7049600 - n 10:09 12711 0 10.2938 - y n 3524800 754170 488 1546.2 - - - - 1.0016 10:07 10:11Acenaphthene1 701280 - n 10:27 2571.3 0 31.0222 - y n 350640 79736 723 110.3 - - - - 1.0313 10:25 10:29Fluorene1 1018300 - n 11:18 4223.48 0 31.6339 - Y y n EG141116MB 509140 76906 573 134.2 - - - - 0.8828 11:15 11:19Phenanthrene1 50446000 - n 12:50 74009.4 0 25.495 - y n 25223000 4647600 1306 3559.6 - - - - 1.0026 12:48 12:52Anthracene1 10098000 - n 12:56 13211.2 0 30.5543 - y n 5048800 430190 1306 329.5 - - - - 1.0039 12:53 12:57Fluoranthene1 33871000 - n 14:47 64547.2 0 58.0548 - y n 16936000 3009200 2040 1474.8 - - - - 1.0023 14:45 14:49Pyrene1 26394000 - n 15:09 46889.8 0 54.1217 - y n 13197000 2378200 2040 1165.6 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 695770 - n 17:33 2179.37 0 20.2298 - Y y n EG141116MB 347880 97471 395 247 - - - - 1.0038 17:30 17:34Chrysene/Triphenylene1 4914300 - n 17:36 9523.91 0 17.7449 - Y y n EG141116MB 2457200 196370 395 497.6 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 1065900 - n 19:45 5057.73 0 60.0566 - Y y n EG141116MB 532940 73280 686 106.9 - - - - 1.0034 19:43 19:47Benzo[k]fluoranthene1 538520 - n 19:47 1882.08 0 49.5709 - Y y n EG141116MB 269260 32784 686 47.8 - - - - 1.0017 19:45 19:49Benzo[e]pyrene1 714580 - n 20:14 958.586 0 59.4299 - Y y n EG141116MB 357290 53063 3964 13.4 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 135790 - n 20:22 189.462 0 61.813 - Y y n EG141116MB 67895 7379.4 3964 1.9 - - - - 1.0049 20:19 20:23Perylene1 24002 - n 20:31 60.5625 0 223.997 - Y y n EG141116MB 12001 2470.3 3964 0.6 - - - - 1.0033 20:29 20:33Indeno[1,2,3-cd]pyrene1 79466 - n 22:23 596.847 0 44.0295 - Y y n EG141116MB 39733 3767.1 201 18.7 - - - - 1.0015 22:19 22:23Dibenzo[a,h]anthracene1 18020 - n 22:28 197.979 0 56.5105 - Y y n EG141116MB 9010.2 751.77 309 2.4 - - - - 1.0022 22:26 22:30Benzo[g,h,i]perylene1 116170 - n 22:48 505.172 0 21.5819 - Y y n EG141116MB 58084 5299.9 201 26.4 - - - - 1.0029 22:45 22:49Fluorene-d101 227380 - n 11:15 1347.68 0 0 134.8 n n 113690 19232 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 212880 - n 15:34 1026.71 0 0 102.7 n n 106440 16080 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 448520 - n 7:31 20.9779 0 0 2.1 n n 224260 40490 0 Div0 - - - - 0.7239 7:26 7:362-Me-Naphthalene-d101 172490 - n 8:40 22.0819 0 0 2.2 n n 86244 17197 0 Div0 - - - - 0.8347 8:34 8:44Acenaphthylene-d81 382540 - n 10:08 20.8246 0 0 2.1 n n 191270 40855 0 Div0 - - - - 0.9759 10:02 10:12Phenanthrene-d101 623240 - n 12:48 21.0856 0 0 2.1 n n 311620 58532 0 Div0 - - - - 1.2327 12:42 12:52Anthracene-d101 674580 - n 12:53 21.8604 0 0 2.2 n n 337290 47144 0 Div0 - - - - 1.2408 12:47 12:57Fluoranthene-d101 351650 - n 14:45 20.3762 0 0 2 n n 175830 29441 0 Div0 - - - - 0.9757 14:39 14:49Benz[a]anthracene-d121 248020 - n 17:29 14.3678 0 0 1.4 n n 124010 18943 0 Div0 - - - - 1.1566 17:23 17:33Chrysene-d121 461290 - n 17:33 16.1215 0 0 1.6 Y n n EG141116MB 230650 24851 0 Div0 - - - - 1.161 17:26 17:36Benzo[b]fluoranthene-d121 180870 - n 19:41 19.0149 0 0 1.9 Y y n EG141116MB 90436 12248 0 Div0 - - - - 0.9752 19:36 19:46Benzo[k]fluoranthene-d121 275380 - n 19:45 18.821 0 0 1.9 Y y n EG141116MB 137690 16640 0 Div0 - - - - 0.9785 19:40 19:50Benzo[a]pyrene-d121 591270 - n 20:16 53.6346 0 0 5.4 Y y n EG141116MB 295640 66135 0 Div0 - - - - 1.0041 20:12 20:22Perylene-d121 251330 - n 20:27 23.0725 0 0 2.3 Y y n EG141116MB 125670 14029 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 133660 - n 22:21 18.1509 0 0 1.8 Y y n EG141116MB 66829 5731 0 Div0 - - - - 1.1073 22:16 22:26Dibenzo[a,h]anthracene-d141 57812 - n 22:25 11.2357 0 0 1.1 n n 28906 4341.7 0 Div0 - - - - 1.1107 22:17 22:27Benzo[g,h,i]perylene-d121 187900 - n 22:44 23.1248 0 0 2.3 Y y n EG141116MB 93950 9516.7 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 12093000 - n 10:23 107.904 0 - - n n 6046400 1378700 0 Div0 - - - - 0.6869 10:13 10:33Pyrene-d101 19571000 - n 15:07 118.465 0 - - n n 9785500 1791000 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 13819000 - n 20:11 69.7258 0 - - y n 6909600 1120000 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28Quantification Report OPUS v3.6Sample ID L1535265-10Comments SAMPLE X10Sample size 1Filename 4-141115B16Acquired 16-Nov-2014 10:27Processed 16-Nov-2014 14:25Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 971840000 - n 7:34 43099.6 0 43.0338 - n n 485920000 83399000 81944 1017.8 - - - - 1.0046 7:32 7:362-Me-Naphthalene1 166190000 - n 8:44 16400.4 0 3.85211 - Y y n EG141116MB 83097000 21416000 3797 5640.3 - - - - 1.0071 8:41 8:451-Me-Naphthalene1 113940000 - n 8:54 11734.7 0 4.02032 - Y y n EG141116MB 56969000 13923000 3797 3666.8 - - - - 1.0263 8:50 8:54Acenaphthylene 1 413020000 - n 10:10 19063.7 0 2.9386 - y n 206510000 54815000 6124 8951.1 - - - -1.002 10:08 10:12Acenaphthene1 21829000 - n 10:27 2048.84 0 5.76557 - y n 10914000 2655300 5909 449.4 - - - - 1.0306 10:26 10:30Fluorene1 27909000 - n 11:18 3075.36 0 2.04726 - y n 13954000 2831600 1615 1752.9 - - - - 0.8822 11:15 11:19Phenanthrene1 874940000 - n 12:50 34102.5 0 10.5061 - y n 437470000 82870000 23436 3535.9 - - - - 1.0026 12:48 12:52Anthracene1 155680000 - n 12:55 6298.59 0 11.3271 - y n 77839000 15287000 23436 652.3 - - - -1.002 12:54 12:58Fluoranthene1 671540000 - n 14:47 38394.6 0 13.6445 - y n 335770000 75619000 20508 3687.3 - - - - 1.0018 14:45 14:49Pyrene1 481120000 - n 15:10 25644.2 0 12.7201 - y n 240560000 54695000 20508 2667 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 31517000 - n 17:32 3287.84 0 1.06611 - y n 15759000 2989700 797 3751.6 - - - - 1.0028 17:30 17:34Chrysene/Triphenylene1 56773000 - n 17:36 5204.83 0 1.13111 - y n 28387000 3854100 797 4836.2 - - - - 1.0032 17:34 17:38Benzo[b]fluoranthene1 18450000 - n 19:44 3164.93 0 2.83701 - Y y n EG141116MB 9224800 1549300 1241 1248.2 - - - - 1.0025 19:42 19:46Benzo[k]fluoranthene1 8047200 - n 19:47 1246.82 0 3.17101 - Y y n EG141116MB 4023600 600580 1241 483.8 - - - - 1.0017 19:46 19:50Benzo[e]pyrene1 10193000 - n 20:15 1660.75 0 3.65433 - y n 5096500 866820 1241 698.3 - - - - 1.0025 20:13 20:17Benzo[a]pyrene1 4021100 - n 20:21 681.427 0 3.80086 - y n 2010500 252480 1241 203.4 - - - - 1.0025 20:19 20:23Perylene1 1025400 - n 20:31 132.977 0 2.91423 - y n 512690 54758 1241 44.1 - - - - 1.0024 20:28 20:32Indeno[1,2,3-cd]pyrene1 3283500 - n 22:22 980.136 0 1.74022 - Y y n EG141116MB 1641800 173220 223 776.1 - - - - 1.0016 22:21 22:25Dibenzo[a,h]anthracene1 728270 - n 22:27 203.765 0 2.7233 - Y y n EG141116MB 364130 41705 434 96 - - - -1.003 22:24 22:28Benzo[g,h,i]perylene1 3485200 - n 22:47 807.449 0 1.03337 - Y y n EG141116MB 1742600 209470 223 938.5 - - - - 1.0018 22:45 22:49Fluorene-d101 6612700 - n 11:15 1041.27 0 0 104.1 n n 3306300 733140 0 Div0 - - - - 0.8784 11:09 11:19p-Terphenyl-d141 5867600 - n 15:34 849.012 0 0 84.9 n n 2933800 565740 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 17644000 - n 7:32 689.401 0 0.540702 68.9 n n 8822000 1862500 1344 1385.8 - - - - 0.7239 7:27 7:372-Me-Naphthalene-d101 6653300 - n 8:40 711.541 0 0.004405 71.2 n n 3326600 808940 4 202235.8 - - - - 0.8334 8:35 8:45Acenaphthylene-d81 14944000 - n 10:09 679.587 0 0 68 n n 7471900 1796700 0 Div0 - - - - 0.9749 10:03 10:13Phenanthrene-d101 23459000 - n 12:48 663.015 0 0 66.3 n n 11729000 2549600 0 Div0 - - - - 1.2305 12:43 12:53Anthracene-d101 21814000 - n 12:54 590.548 0 0 59.1 n n 10907000 2282700 0 Div0 - - - - 1.2389 12:48 12:58Fluoranthene-d101 11721000 - n 14:45 694.503 0 0 69.5 n n 5860500 1259000 0 Div0 - - - - 0.9753 14:40 14:50Benz[a]anthracene-d121 7447100 - n 17:29 441.161 0 0 44.1 n n 3723500 725890 0 Div0 - - - - 1.1558 17:24 17:34Chrysene-d121 9751300 - n 17:33 348.496 0 0 34.8 n n 4875700 787310 0 Div0 - - - - 1.1596 17:27 17:37Benzo[b]fluoranthene-d121 5003100 - n 19:41 667.051 0 0 66.7 n n 2501500 469380 0 Div0 - - - - 0.9744 19:36 19:46Benzo[k]fluoranthene-d121 6211600 - n 19:45 538.41 0 0 53.8 n n 3105800 470910 0 Div0 - - - - 0.9777 19:39 19:49Benzo[a]pyrene-d121 4868200 - n 20:18 560.041 0 0 56 n n 2434100 336770 0 Div0 - - - -1.005 20:13 20:23Perylene-d121 4890100 - n 20:28 569.317 0 0 56.9 n n 2445000 337640 0 Div0 - - - - 1.0132 20:23 20:33Indeno[1,2,3-cd]pyrene-d121 3363000 - n 22:20 579.199 0 0 57.9 n n 1681500 160940 0 Div0 - - - - 1.1056 22:14 22:24Dibenzo[a,h]anthracene-d141 2270100 - n 22:23 559.515 0 0 56 n n 1135000 126630 0 Div0 - - - - 1.1081 22:18 22:28Benzo[g,h,i]perylene-d121 3526900 - n 22:44 550.473 0 0 55 n n 1763400 220610 0 Div0 - - - - 1.1258 22:39 22:49Acenaphthene-d101 14476000 - n 10:24 129.166 0 - - n n 7237900 1757400 0 Div0 - - - - 0.6878 10:14 10:34Pyrene-d101 19139000 - n 15:08 115.848 0 - - n n 9569300 1916000 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 10896000 - n 20:12 54.979 0 - - n n 5448200 970240 0 Div0 - - - - 1.3351 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290000F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290000F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290000F4 Lock Mass0* NotFnd * * - - n * *0 Div0 * 25:09 25:290000F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290000F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290000DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290000Quantification Report OPUS v3.6Sample ID L1535265-10Comments SAMPLE X50Sample size 1Filename 4-141115B11Acquired 16-Nov-2014 07:35Processed 16-Nov-2014 10:13Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments AreaHght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene 1 24410000 - n 7:33 43863 0 93.1008 - y n 12205000 2221000 4030 551.1 - - - - 1.0044 7:31 7:352-Me-Naphthalene1 3364100 - n 8:42 15136.7 0 38.0919 - y n 1682000 320680 649 494.3 - - - - 1.0038 8:41 8:451-Me-Naphthalene1 2883800 - n 8:52 13542.3 0 39.7553 - y n 1441900 293720 649 452.7 - - - - 1.0231 8:50 8:54Acenaphthylene 1 7391100 - n 10:09 14908 0 27.9179 - y n 3695600 773380 1177 656.9 - - - - 1.0016 10:07 10:11Acenaphthene 1 572810 - n 10:27 2349.45 0 29.8722 - y n 286410 63747 619 102.9 - - - - 1.0313 10:25 10:29Fluorene 1 686030 - n 11:17 3647.15 0 14.6751 - y n 343010 53463 182 294.3 - - - - 0.8815 11:15 11:19Phenanthrene 1 23125000 - n 12:50 43486.4 0 55.7218 - Y y n EG141116MB 11563000 1942300 1950 996.1 - - - - 1.0026 12:48 12:52Anthracene 1 6398200 - n 12:55 10527.1 0 70.7458 - Y y n EG141116MB 3199100 273610 1950 140.3 - - - - 1.0026 12:53 12:57Fluoranthene1 13716000 - n 14:46 30364.9 0 77.7516 - y n 6858200 1123900 2418 464.8 - - - - 1.0023 14:44 14:48Pyrene1 11179000 - n 15:09 23070 0 72.4841 - y n 5589300 972080 2418 402 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 706790 - n 17:35 4347.79 0 86.0842 - Y y n EG141116MB 353400 49528 915 54.2 - - - - 1.0048 17:31 17:35Chrysene/Triphenylene1 706790 - n 17:35 5003.22 0 99.0613 - Y y n EG141116MB 353400 49528 915 54.2 - - - - 1.0048 17:31 17:35Benzo[b]fluoranthene1 263780 - n 19:45 3468.16 0 160.11 - Y y n EG141116MB 131890 17130 763 22.4 - - - - 1.0034 19:42 19:46Benzo[k]fluoranthene1 117420 - n 19:47 1472.94 0 169.658 - Y y n EG141116MB 58708 9898 763 13 - - - - 1.0017 19:46 19:50Benzo[e]pyrene1 217360 - n 20:14 1143.18 0 41.8169 - Y y n EG141116MB 108680 13108 763 17.2 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 29160 - n 20:23 159.518 0 43.4937 - Y y n EG141116MB 14580 2627.4 763 3.4 - - - - 1.0016 20:22 20:26Perylene1 10067 - n 20:31 31.5096 0 39.9405 - Y y n EG141116MB 5033.3 1292.3 763 1.7 - - - - 1.0033 20:27 20:31Indeno[1,2,3-cd]pyrene1 23916 - n 22:24 706.507 0 81.2366 - y y n EG141116MB 11958 1534.2 149 10.3 - - - - 1.0015 22:23 22:27Dibenzo[a,h]anthracene1 3051.7 - n 22:29 124.144 0 137.922 - Y y n EG141118MB 1525.9 368.83 203 1.8 - - - - 1.0015 22:28 22:32Benzo[g,h,i]perylene1 44635 - n 22:48 868.149 0 48.1411 - y y n EG141116MB 22318 2491.3 149 16.8 - - - - 1.0022 22:46 22:50Fluorene-d101 148170 - n 11:14 1125.65 0 0 112.6 n n 74085 12546 0 Div0 - - - - 0.8776 11:09 11:19p-Terphenyl-d141 152160 - n 15:34 852.469 0 0 85.2 n n 76078 9237.4 0 Div0 - - - - 1.0566 15:28 15:38Naphthalene-d81 435450 - n 7:31 19.0256 0 0 1.9 n n 217730 42338 0 Div0 - - - - 0.7239 7:26 7:362-Me-Naphthalene-d101 145920 - n 8:40 17.4499 0 0 1.7 n n 72958 13979 0 Div0 - - - - 0.8347 8:34 8:44Acenaphthylene-d81 341970 - n 10:08 17.3897 0 0 1.7 n n 170980 36356 0 Div0 - - - - 0.9759 10:02 10:12Phenanthrene-d101 486230 - n 12:48 15.367 0 0 1.5 n n 243120 39997 0 Div0 - - - - 1.2327 12:42 12:52Anthracene-d101 536420 - n 12:53 16.2384 0 0 1.6 n n 268210 30409 0 Div0 - - - - 1.2408 12:47 12:57Fluoranthene-d101 302710 - n 14:44 17.4776 0 0 1.7 n n 151360 26053 0 Div0 - - - - 0.9746 14:39 14:49Benz[a]anthracene-d121 126290 - n 17:30 7.28991 0 0 0.7 n n 63145 10317 0 Div0 - - - - 1.1577 17:23 17:33Chrysene-d121 126290 - n 17:30 4.39788 0 0 0.4 n n 63145 10317 0 Div0 - - - - 1.1577 17:26 17:36Benzo[b]fluoranthene-d121 65277 - n 19:41 11.1477 0 0 1.1 n n 32638 5114 0 Div0 - - - - 0.9752 19:35 19:45Benzo[k]fluoranthene-d121 76720 - n 19:45 8.51768 0 0 0.9 n n 38360 5412 0 Div0 - - - - 0.9785 19:38 19:48Benzo[a]pyrene-d121 150810 - n 20:21 22.2221 0 0 2.2 n n 75404 18096 0 Div0 - - - - 1.0083 20:12 20:22Perylene-d121 202600 - n 20:27 30.2124 0 0 3 n n 101300 15148 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 33982 - n 22:22 7.49645 0 0 0.7 y n 16991 2296.1 0 Div0 - - - - 1.1082 22:13 22:23Dibenzo[a,h]anthracene-d141 15613 - n 22:27 4.9292 0 0 0.5 y n 7806.6 1171.4 0 Div0 - - - - 1.1123 22:22 22:32Benzo[g,h,i]perylene-d121 42011 - n 22:45 8.39874 0 0 0.8 y n 21005 3153.8 0 Div0 - - - - 1.1272 22:38 22:48Acenaphthene-d101 12945000 - n 10:23 115.512 0 - - n n 6472700 1511700 0 Div0 - - - - 0.6869 10:13 10:33Pyrene-d101 19641000 - n 15:07 118.891 0 - - n n 9820700 1699800 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 8507000 - n 20:11 42.9231 0 - - n n 4253500 584700 0 Div0 - - - - 1.3352 20:00 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:28

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including: for Multi-Point Calibration(s) - Multi-Point Calibration Tables - Individual Quantitation Reports

for Continuing Calibration(s) - Multi-Point Calibration Tables - Individual Quantitation Reports 

# SVOC DATA PACKAGE

SECTION 4: CALIBRATION DATACal Level Filename Run Date

CS1 4-141115A03
CS2 4-141115A04
CS3 4-141115A05
CS4 4-141115A06 Approved:
CS5 4-141115A07 --e-signature--
CS6 4-141115A08

Target Analytes CS1 CS2 CS3 CS4 CS5 CS6 Mean %RSD

Naphthalene 1.44 1.20 1.14 1.24 1.21 1.43 1.28 10% 2-Me-Naphthalene 1.57 1.52 1.45 1.43 1.44 1.73 1.52 7% 1-Me-Naphthalene 1.52 1.42 1.39 1.42 1.36 1.65 1.46 7% Acenaphthylene 1.42 1.35 1.31 1.36 1.41 1.85 1.45 14% Acenaphthene 0.69 0.70 0.68 0.69 0.69 0.83 0.71 8%

Fluorene 0.40 0.36 0.38 0.38 0.36 0.44 0.39 8%
Phenanthrene 1.08 1.00 1.02 1.04 1.16 1.25 1.09 9%
Anthracene 1.12 1.05 1.09 1.10 1.18 1.26 1.13 7%
Fluoranthene 1.35 1.36 1.31 1.39 1.51 2.04 1.49 18%

Pyrene 1.46 1.42 1.44 1.44 1.67 2.17 1.60 18% Benz[a]anthracene 1.07 1.10 1.17 1.16 1.29 1.93 1.29 25% Chrysene/Triphenylene 1.07 1.10 1.02 1.01 1.13 1.38 1.12 12% Benzo[b]fluoranthene 1.08 1.09 1.19 1.16 1.31 * 1.17 8% Benzo[k]fluoranthene 1.05 1.06 0.99 1.02 1.08 * 1.04 3%

Benzo[e]pyrene 1.22 1.15 1.16 1.17 1.22 1.64 1.26 15% Benzo[a]pyrene 1.15 1.12 1.10 1.12 1.17 1.62 1.21 17%

Perylene 1.34 1.43 1.41 1.60 1.61 2.08 1.58 17% Indeno[1,2,3-cd]pyrene 0.95 0.93 0.92 0.86 0.97 1.35 1.00 18% Dibenzo[a,h]anthracene 1.45 1.63 1.54 1.63 1.63 * 1.57 5%

Benzo[g,h,i]perylene 1.14 1.13 1.14 1.12 1.21 1.61 1.22 16%

Labeled Field Spike Standards

Fluorene-d10 0.29 0.24 0.28 0.28 0.27 0.26 0.27 6% p-Terphenyl-d14 0.60 0.53 0.58 0.61 0.61 0.61 0.59 5%

Labeled Extraction Standards

Naphthalene-d8 1.70 1.82 1.77 1.72 1.78 1.82 1.76 3% 2-Me-Naphthalene-d10 0.63 0.66 0.65 0.64 0.65 0.65 0.65 2%

Acenaphthylene-d8 1.47 1.52 1.51 1.49 1.53 1.60 1.50 3%
Phenanthrene-d10 2.24 2.53 2.33 2.46 2.49 2.61 2.41 6%
Anthracene-d10 2.38 2.66 2.41 2.50 2.60 2.76 2.51 6%
Fluoranthene-d10 0.89 0.90 0.87 0.90 0.85 0.88 0.88 2% Benz[a]anthracene-d12 0.86 0.92 0.79 0.81 0.90 1.00 0.86 9% Chrysene-d12 1.38 1.43 1.35 1.37 1.53 1.71 1.41 9% Benzo[b]fluoranthene-d12 0.69 0.71 0.66 0.71 0.67 0.69 0.69 3% Benzo[k]fluoranthene-d12 0.93 0.99 1.00 1.12 1.09 1.23 1.02 10%

Benzo[a]pyrene-d12 0.73 0.77 0.78 0.76 0.84 0.92 0.77 9%

Perylene-d12 0.75 0.77 0.76 0.79 0.82 0.85 0.78 5% Indeno[1,2,3-cd]pyrene-d12 0.53 0.56 0.38 0.35 0.63 0.75 0.49 28% Dibenzo[a,h]anthracene-d14 0.37 0.42 0.28 0.27 0.52 * 0.37 28%

Benzo[g,h,i]perylene-d12 0.60 0.66 0.41 0.39 0.68 0.79 0.55 27% 

# ALS Environmental
Calibration Summary Report

15-Nov-2014 13:53
15-Nov-2014 14:27
15-Nov-2014 15:01
15-Nov-2014 15:35 Ella Gdyczynski
15-Nov-2014 16:10
15-Nov-2014 16:44 17-Nov-2014

Relative Response Factors

### ALS Sample ID H4-14-CS#1-0112 Analysis Method CARB 429 Modified Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski
Run Data 4-141115A03 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF Native Target Analyte Time ng/mL

Naphthalene 7:36 10 2.81E+06 1.44 2-Me-Naphthalene 8:44 10 1.13E+06 1.57 1-Me-Naphthalene 8:53 10 1.10E+06 1.52

Acenaphthylene 10:10 10 2.39E+06 1.42 Acenaphthene 10:28 10 1.16E+06 0.69
Fluorene 11:19 10 1.02E+06 0.40
Phenanthrene 12:51 10 2.79E+06 1.08

Anthracene 12:56 10 3.05E+06 1.12
Fluoranthene 14:48 10 1.96E+06 1.35

Pyrene 15:11 10 2.11E+06 1.46 Benz[a]anthracene 17:32 10 1.49E+06 1.07 Chrysene/Triphenylene 17:37 10 2.40E+06 1.07 Benzo[b]fluoranthene 19:44 10 1.55E+06 1.08 Benzo[k]fluoranthene 19:47 10 2.02E+06 1.05

Benzo[e]pyrene 20:15 10 1.85E+06 1.22 Benzo[a]pyrene 20:21 10 1.74E+06 1.15 Perylene 20:30 10 2.09E+06 1.34 Indeno[1,2,3-cd]pyrene 22:23 10 1.04E+06 0.95 Dibenzo[a,h]anthracene 22:27 10 1.13E+06 1.45

Benzo[g,h,i]perylene 22:47 10 1.43E+06 1.14

Labeled Field Spike Standards

Fluorene-d10 11:16 100 7.45E+06 0.29 p-Terphenyl-d14 15:35 100 8.69E+06 0.60

Labeled Extraction Standards

Naphthalene-d8 7:33 100 1.96E+07 1.70 2-Me-Naphthalene-d10 8:41 100 7.22E+06 0.63

Acenaphthylene-d8 10:09 100 1.69E+07 1.47
Phenanthrene-d10 12:49 100 2.58E+07 2.24

Anthracene-d10 12:54 100 2.74E+07 2.38
Fluoranthene-d10 14:46 100 1.44E+07 0.89 Benz[a]anthracene-d12 17:30 100 1.40E+07 0.86 Chrysene-d12 17:33 100 2.23E+07 1.38 Benzo[b]fluoranthene-d12 19:41 100 1.44E+07 0.69 Benzo[k]fluoranthene-d12 19:45 100 1.93E+07 0.93

Benzo[a]pyrene-d12 20:18 100 1.52E+07 0.73 Perylene-d12 20:27 100 1.56E+07 0.75 Indeno[1,2,3-cd]pyrene-d12 22:20 100 1.10E+07 0.53 Dibenzo[a,h]anthracene-d14 22:23 100 7.81E+06 0.37

Benzo[g,h,i]perylene-d12 22:44 100 1.25E+07 0.60 

# ALS Environmental
Calibration Analysis Report

15-Nov-2014 13:53
17-Nov-2014

### ALS Sample ID H4-14-CS#2-0112 Analysis Method CARB 429 Modified Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski
Run Data 4-141115A04 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF Native Target Analyte Time ng/mL

Naphthalene 7:33 50 1.23E+07 1.20 2-Me-Naphthalene 8:42 50 5.65E+06 1.52 1-Me-Naphthalene 8:51 50 5.28E+06 1.42

Acenaphthylene 10:08 50 1.15E+07 1.35 Acenaphthene 10:26 50 5.99E+06 0.70
Fluorene 11:16 50 5.09E+06 0.36
Phenanthrene 12:49 50 1.42E+07 1.00

Anthracene 12:54 50 1.56E+07 1.05
Fluoranthene 14:46 50 1.02E+07 1.36

Pyrene 15:09 50 1.06E+07 1.42 Benz[a]anthracene 17:30 50 8.47E+06 1.10 Chrysene/Triphenylene 17:35 50 1.31E+07 1.10 Benzo[b]fluoranthene 19:42 50 8.30E+06 1.09 Benzo[k]fluoranthene 19:45 50 1.12E+07 1.06

Benzo[e]pyrene 20:13 50 9.46E+06 1.15 Benzo[a]pyrene 20:19 50 9.21E+06 1.12 Perylene 20:29 50 1.19E+07 1.43 Indeno[1,2,3-cd]pyrene 22:21 50 5.57E+06 0.93 Dibenzo[a,h]anthracene 22:25 50 7.43E+06 1.63

Benzo[g,h,i]perylene 22:45 50 7.99E+06 1.13

Labeled Field Spike Standards

Fluorene-d10 11:13 100 6.92E+06 0.24 p-Terphenyl-d14 15:33 100 7.95E+06 0.53

Labeled Extraction Standards

Naphthalene-d8 7:31 100 2.05E+07 1.82 2-Me-Naphthalene-d10 8:39 100 7.44E+06 0.66

Acenaphthylene-d8 10:07 100 1.70E+07 1.52
Phenanthrene-d10 12:47 100 2.84E+07 2.53

Anthracene-d10 12:52 100 2.98E+07 2.66
Fluoranthene-d10 14:44 100 1.50E+07 0.90 Benz[a]anthracene-d12 17:28 100 1.54E+07 0.92 Chrysene-d12 17:31 100 2.39E+07 1.43 Benzo[b]fluoranthene-d12 19:39 100 1.53E+07 0.71 Benzo[k]fluoranthene-d12 19:43 100 2.13E+07 0.99

Benzo[a]pyrene-d12 20:16 100 1.65E+07 0.77 Perylene-d12 20:26 100 1.66E+07 0.77 Indeno[1,2,3-cd]pyrene-d12 22:18 100 1.20E+07 0.56 Dibenzo[a,h]anthracene-d14 22:22 100 9.12E+06 0.42

Benzo[g,h,i]perylene-d12 22:43 100 1.41E+07 0.66 

# ALS Environmental
Calibration Analysis Report

15-Nov-2014 14:27
17-Nov-2014

### ALS Sample ID H4-14-CS#3-0112 Analysis Method CARB 429 Modified Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski
Run Data 4-141115A05 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF Native Target Analyte Time ng/mL

Naphthalene 7:33 100 2.24E+07 1.14 2-Me-Naphthalene 8:42 100 1.04E+07 1.45 1-Me-Naphthalene 8:51 100 1.00E+07 1.39

Acenaphthylene 10:08 100 2.19E+07 1.31 Acenaphthene 10:26 100 1.13E+07 0.68
Fluorene 11:17 100 9.85E+06 0.38
Phenanthrene 12:49 100 2.64E+07 1.02

Anthracene 12:54 100 2.91E+07 1.09
Fluoranthene 14:46 100 1.87E+07 1.31

Pyrene 15:09 100 2.07E+07 1.44 Benz[a]anthracene 17:31 100 1.52E+07 1.17 Chrysene/Triphenylene 17:35 100 2.27E+07 1.02 Benzo[b]fluoranthene 19:42 100 1.49E+07 1.19 Benzo[k]fluoranthene 19:45 100 1.88E+07 0.99

Benzo[e]pyrene 20:13 100 1.70E+07 1.16 Benzo[a]pyrene 20:19 100 1.62E+07 1.10 Perylene 20:28 100 2.03E+07 1.41 Indeno[1,2,3-cd]pyrene 22:21 100 6.61E+06 0.92 Dibenzo[a,h]anthracene 22:25 100 8.10E+06 1.54

Benzo[g,h,i]perylene 22:45 100 8.87E+06 1.14

Labeled Field Spike Standards

Fluorene-d10 11:14 100 7.25E+06 0.28 p-Terphenyl-d14 15:33 100 8.24E+06 0.58

Labeled Extraction Standards

Naphthalene-d8 7:31 100 1.96E+07 1.77 2-Me-Naphthalene-d10 8:39 100 7.18E+06 0.65

Acenaphthylene-d8 10:07 100 1.67E+07 1.51
Phenanthrene-d10 12:47 100 2.58E+07 2.33

Anthracene-d10 12:52 100 2.67E+07 2.41
Fluoranthene-d10 14:44 100 1.43E+07 0.87 Benz[a]anthracene-d12 17:28 100 1.29E+07 0.79 Chrysene-d12 17:32 100 2.22E+07 1.35 Benzo[b]fluoranthene-d12 19:39 100 1.25E+07 0.66 Benzo[k]fluoranthene-d12 19:43 100 1.90E+07 1.00

Benzo[a]pyrene-d12 20:16 100 1.47E+07 0.78 Perylene-d12 20:25 100 1.44E+07 0.76 Indeno[1,2,3-cd]pyrene-d12 22:18 100 7.20E+06 0.38 Dibenzo[a,h]anthracene-d14 22:22 100 5.27E+06 0.28

Benzo[g,h,i]perylene-d12 22:43 100 7.81E+06 0.41 

# ALS Environmental
Calibration Analysis Report

15-Nov-2014 15:01
17-Nov-2014

### ALS Sample ID H4-14-CS#4-0112 Analysis Method CARB 429 Modified Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski
Run Data 4-141115A06 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF Native Target Analyte Time ng/mL

Naphthalene 7:33 200 4.76E+07 1.24 2-Me-Naphthalene 8:42 200 2.03E+07 1.43 1-Me-Naphthalene 8:51 200 2.02E+07 1.42

Acenaphthylene 10:08 200 4.50E+07 1.36 Acenaphthene 10:25 200 2.29E+07 0.69
Fluorene 11:16 200 2.08E+07 0.38
Phenanthrene 12:48 200 5.73E+07 1.04

Anthracene 12:53 200 6.17E+07 1.10
Fluoranthene 14:46 200 3.94E+07 1.39

Pyrene 15:08 200 4.09E+07 1.44 Benz[a]anthracene 17:30 200 2.97E+07 1.16 Chrysene/Triphenylene 17:35 200 4.34E+07 1.01 Benzo[b]fluoranthene 19:42 200 1.89E+07 1.16 Benzo[k]fluoranthene 19:45 200 2.60E+07 1.02

Benzo[e]pyrene 20:12 200 2.02E+07 1.17 Benzo[a]pyrene 20:18 200 1.92E+07 1.12 Perylene 20:28 200 2.85E+07 1.60 Indeno[1,2,3-cd]pyrene 22:20 200 6.91E+06 0.86 Dibenzo[a,h]anthracene 22:25 200 9.95E+06 1.63

Benzo[g,h,i]perylene 22:45 200 9.96E+06 1.12

Labeled Field Spike Standards

Fluorene-d10 11:13 100 7.62E+06 0.28 p-Terphenyl-d14 15:33 100 8.63E+06 0.61

Labeled Extraction Standards

Naphthalene-d8 7:31 100 1.91E+07 1.72 2-Me-Naphthalene-d10 8:39 100 7.10E+06 0.64

Acenaphthylene-d8 10:07 100 1.66E+07 1.49
Phenanthrene-d10 12:46 100 2.74E+07 2.46

Anthracene-d10 12:52 100 2.79E+07 2.50
Fluoranthene-d10 14:44 100 1.42E+07 0.90 Benz[a]anthracene-d12 17:28 100 1.28E+07 0.81 Chrysene-d12 17:31 100 2.16E+07 1.37 Benzo[b]fluoranthene-d12 19:39 100 8.12E+06 0.71 Benzo[k]fluoranthene-d12 19:43 100 1.27E+07 1.12

Benzo[a]pyrene-d12 20:16 100 8.61E+06 0.76 Perylene-d12 20:25 100 8.93E+06 0.79 Indeno[1,2,3-cd]pyrene-d12 22:18 100 4.02E+06 0.35 Dibenzo[a,h]anthracene-d14 22:21 100 3.04E+06 0.27

Benzo[g,h,i]perylene-d12 22:43 100 4.45E+06 0.39 

# ALS Environmental
Calibration Analysis Report

15-Nov-2014 15:35
17-Nov-2014

### ALS Sample ID H4-14-CS#5-0112 Analysis Method CARB 429 Modified Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski
Run Data 4-141115A07 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF Native Target Analyte Time ng/mL

Naphthalene 7:33 500 1.19E+08 1.21 2-Me-Naphthalene 8:42 500 5.19E+07 1.44 1-Me-Naphthalene 8:51 500 4.91E+07 1.36

Acenaphthylene 10:08 500 1.19E+08 1.41 Acenaphthene 10:26 500 5.85E+07 0.69
Fluorene 11:17 500 5.01E+07 0.36
Phenanthrene 12:49 500 1.60E+08 1.16

Anthracene 12:54 500 1.70E+08 1.18
Fluoranthene 14:46 500 1.09E+08 1.51

Pyrene 15:08 500 1.21E+08 1.67 Benz[a]anthracene 17:31 500 9.92E+07 1.29 Chrysene/Triphenylene 17:35 500 1.48E+08 1.13 Benzo[b]fluoranthene 19:42 500 1.02E+08 1.31 Benzo[k]fluoranthene 19:45 500 1.37E+08 1.08

Benzo[e]pyrene 20:13 500 1.20E+08 1.22 Benzo[a]pyrene 20:19 500 1.15E+08 1.17 Perylene 20:28 500 1.54E+08 1.61 Indeno[1,2,3-cd]pyrene 22:20 500 7.15E+07 0.97 Dibenzo[a,h]anthracene 22:24 500 9.84E+07 1.63

Benzo[g,h,i]perylene 22:45 500 9.58E+07 1.21

Labeled Field Spike Standards

Fluorene-d10 11:14 100 7.37E+06 0.27 p-Terphenyl-d14 15:33 100 8.86E+06 0.61

Labeled Extraction Standards

Naphthalene-d8 7:31 100 1.96E+07 1.78 2-Me-Naphthalene-d10 8:39 100 7.21E+06 0.65

Acenaphthylene-d8 10:07 100 1.69E+07 1.53
Phenanthrene-d10 12:47 100 2.75E+07 2.49

Anthracene-d10 12:52 100 2.87E+07 2.60
Fluoranthene-d10 14:44 100 1.44E+07 0.85 Benz[a]anthracene-d12 17:28 100 1.54E+07 0.90 Chrysene-d12 17:32 100 2.61E+07 1.53 Benzo[b]fluoranthene-d12 19:39 100 1.56E+07 0.67 Benzo[k]fluoranthene-d12 19:43 100 2.54E+07 1.09

Benzo[a]pyrene-d12 20:16 100 1.97E+07 0.84 Perylene-d12 20:25 100 1.91E+07 0.82 Indeno[1,2,3-cd]pyrene-d12 22:18 100 1.48E+07 0.63 Dibenzo[a,h]anthracene-d14 22:21 100 1.21E+07 0.52

Benzo[g,h,i]perylene-d12 22:42 100 1.59E+07 0.68 

# ALS Environmental
Calibration Analysis Report

15-Nov-2014 16:10
17-Nov-2014

### ALS Sample ID H4-14-CS#6-0112 Analysis Method CARB 429 Modified Sample type Calibration

Filename Inst # Column Run Date Approved: Ella Gdyczynski
Run Data 4-141115A08 HRMS-4 Rxi5SilMS1117926 --e-signature--

Ret. Concentration Response RRF Native Target Analyte Time ng/mL

Naphthalene 7:33 2000 5.85E+08 1.43 2-Me-Naphthalene 8:42 2000 2.52E+08 1.73 1-Me-Naphthalene 8:51 2000 2.40E+08 1.65

Acenaphthylene 10:08 2000 6.67E+08 1.85 Acenaphthene 10:26 2000 2.99E+08 0.83
Fluorene 11:17 2000 2.59E+08 0.44
Phenanthrene 12:49 2000 7.34E+08 1.25

Anthracene 12:54 2000 7.83E+08 1.26
Fluoranthene 14:46 2000 6.13E+08 2.04

Pyrene 15:08 2000 6.52E+08 2.17 Benz[a]anthracene 17:31 2000 6.61E+08 1.93 Chrysene/Triphenylene 17:34 2000 8.02E+08 1.38 Benzo[b]fluoranthene NotFnd 2000 * * Benzo[k]fluoranthene NotFnd 2000 * *

Benzo[e]pyrene 20:13 2000 6.89E+08 1.64 Benzo[a]pyrene 20:19 2000 6.78E+08 1.62 Perylene 20:29 2000 8.03E+08 2.08 Indeno[1,2,3-cd]pyrene 22:20 2000 4.62E+08 1.35 Dibenzo[a,h]anthracene 22:24 2000 5.71E+08 *

Benzo[g,h,i]perylene 22:45 2000 5.81E+08 1.61

Labeled Field Spike Standards

Fluorene-d10 11:14 100 7.79E+06 0.26 p-Terphenyl-d14 15:33 100 9.13E+06 0.61

Labeled Extraction Standards

Naphthalene-d8 7:31 100 2.05E+07 1.82 2-Me-Naphthalene-d10 8:39 100 7.28E+06 0.65

Acenaphthylene-d8 10:07 100 1.81E+07 1.60
Phenanthrene-d10 12:47 100 2.94E+07 2.61

Anthracene-d10 12:52 100 3.10E+07 2.76
Fluoranthene-d10 14:44 100 1.50E+07 0.88 Benz[a]anthracene-d12 17:28 100 1.71E+07 1.00 Chrysene-d12 17:32 100 2.92E+07 1.71 Benzo[b]fluoranthene-d12 19:40 100 1.57E+07 0.69 Benzo[k]fluoranthene-d12 19:43 100 2.82E+07 1.23

Benzo[a]pyrene-d12 20:16 100 2.10E+07 0.92 Perylene-d12 20:26 100 1.93E+07 0.85 Indeno[1,2,3-cd]pyrene-d12 22:18 100 1.71E+07 0.75 Dibenzo[a,h]anthracene-d14 NotFnd 100 * *

Benzo[g,h,i]perylene-d12 22:43 100 1.81E+07 0.79 

# ALS Environmental
Calibration Analysis Report

15-Nov-2014 16:44
17-Nov-2014

### Calibration Report OPUS v3.6

Sample ID H4-14-CS#1-0112

Comments C429ALS-CS#1-016 Sample size 1 Filename 4-141115A03 Acquired 15-Nov-2014 13:53 Processed 15-Nov-2014 21:07 Instrument HRMS-4 Column RXI5SILMS1117926 Calibration 4-141115A-CAL6-C429ALSK Cal level 10

Target Analyte Conc Resp RA RT RRF Mean R R M? P1? P2? Coding Comments

Naphthalene 10 2810000 - n 7:36 1.4359 1.278 y y n 2-Me-Naphthalene 10 1132400 - n 8:44 1.5678 1.5231 n n n 1-Me-Naphthalene 10 1096400 - n 8:53 1.518 1.4594 n n n Acenaphthylene 10 2394500 - n 10:10 1.4207 1.4498 n n n Acenaphthene 10 1158000 - n 10:28 0.6871 0.713 n n n

Fluorene 10 1021500 - n 11:19 0.3966 0.3868 n n n Phenanthrene 10 2789600 - n 12:51 1.0832 1.0937 n n n Anthracene 10 3052000 - n 12:56 1.1155 1.133 n n n Fluoranthene 10 1955000 - n 14:48 1.354 1.4922 n n n

Pyrene 10 2109600 - n 15:11 1.4611 1.6007 n n n Benz[a]anthracene 10 1493000 - n 17:32 1.0688 1.2872 n n n Chrysene/Triphenylene 10 2395500 - n 17:37 1.0726 1.1186 n n n Benzo[b]fluoranthene 10 1553300 - n 19:44 1.0758 1.1652 n n n Benzo[k]fluoranthene 10 2021900 - n 19:47 1.0452 1.039 n n n

Benzo[e]pyrene 10 1851800 - n 20:15 1.221 1.2608 n n n Benzo[a]pyrene 10 1743400 - n 20:21 1.1495 1.2122 n n n

Perylene 10 2090800 - n 20:30 1.3408 1.5769 n n n Indeno[1,2,3-cd]pyrene 10 1043600 - n 22:23 0.9476 0.9962 n n n Dibenzo[a,h]anthracene 10 1128300 - n 22:27 1.4453 1.5744 n n n

Benzo[g,h,i]perylene 10 1426100 - n 22:47 1.142 1.2238 n n n

Fluorene-d10 100 7445400 - n 11:16 0.2891 0.2707 n n n p-Terphenyl-d14 100 8685800 - n 15:35 0.6016 0.5896 n n n Naphthalene-d8 100 19570000 - n 7:33 1.703 1.768 n n n 2-Me-Naphthalene-d10 100 7222600 - n 8:41 0.6285 0.6459 n n n

Acenaphthylene-d8 100 16854000 - n 10:09 1.4667 1.5191 n n n Phenanthrene-d10 100 25755000 - n 12:49 2.2413 2.4442 n n n Anthracene-d10 100 27360000 - n 12:54 2.381 2.5518 n n n Fluoranthene-d10 100 14438000 - n 14:46 0.8919 0.8818 n n n Benz[a]anthracene-d12 100 13969000 - n 17:30 0.8629 0.882 n n n Chrysene-d12 100 22334000 - n 17:33 1.3797 1.462 n n n Benzo[b]fluoranthene-d12 100 14439000 - n 19:41 0.6906 0.6883 n n n Benzo[k]fluoranthene-d12 100 19344000 - n 19:45 0.9252 1.0588 n n n

Benzo[a]pyrene-d12 100 15167000 - n 20:18 0.7254 0.7977 n n n

Perylene-d12 100 15593000 - n 20:27 0.7458 0.7883 n n n Indeno[1,2,3-cd]pyrene-d12 100 11013000 - n 22:20 0.5268 0.5329 n n n Dibenzo[a,h]anthracene-d14 100 7807200 - n 22:23 0.3734 0.3723 n n n

Benzo[g,h,i]perylene-d12 100 12488000 - n 22:44 0.5973 0.588 n n n Acenaphthene-d10 100 11491000 - n 10:25 - - n n n Pyrene-d10 100 16188000 - n 15:09 - - n n n Benzo[e]pyrene-d12 100 20908000 - n 20:12 - - n n n

F1 Lock Mass 0 * NotFnd - - n n F2 Lock Mass 0 * NotFnd - - n n F3 Lock Mass 0 * NotFnd - - n n F4 Lock Mass 0 * NotFnd - - n n F5 Lock Mass 0 * NotFnd - - n n F6 Lock Mass 0 * NotFnd - - n n DUMMY LINE 0 * NotFnd - - n n


### Calibration Report OPUS v3.6

Sample ID H4-14-CS#2-0112

Comments C429ALS-CS#2-016 Sample size 1 Filename 4-141115A04 Acquired 15-Nov-2014 14:27 Processed 15-Nov-2014 21:08 Instrument HRMS-4 Column RXI5SILMS1117926 Calibration 4-141115A-CAL6-C429ALSK Cal level 50

Target Analyte Conc Resp RA RT RRF Mean R R M? P1? P2? Coding Comments

Naphthalene 50 12289000 - n 7:33 1.201 1.278 n n n 2-Me-Naphthalene 50 5646000 - n 8:42 1.5184 1.5231 n n n 1-Me-Naphthalene 50 5281900 - n 8:51 1.4205 1.4594 n n n Acenaphthylene 50 11529000 - n 10:08 1.3547 1.4498 n n n Acenaphthene 50 5990100 - n 10:26 0.7039 0.713 n n n

Fluorene 50 5088100 - n 11:16 0.3587 0.3868 n n n Phenanthrene 50 14222000 - n 12:49 1.0025 1.0937 n n n Anthracene 50 15619000 - n 12:54 1.0472 1.133 n n n Fluoranthene 50 10175000 - n 14:46 1.3593 1.4922 n n n

Pyrene 50 10642000 - n 15:09 1.4217 1.6007 n n n Benz[a]anthracene 50 8468300 - n 17:30 1.1027 1.2872 n n n Chrysene/Triphenylene 50 13147000 - n 17:35 1.0996 1.1186 n n n Benzo[b]fluoranthene 50 8303300 - n 19:42 1.0863 1.1652 n n n Benzo[k]fluoranthene 50 11229000 - n 19:45 1.0565 1.039 n n n

Benzo[e]pyrene 50 9458300 - n 20:13 1.1475 1.2608 n n n Benzo[a]pyrene 50 9207800 - n 20:19 1.1171 1.2122 n n n

Perylene 50 11861000 - n 20:29 1.4253 1.5769 n n n Indeno[1,2,3-cd]pyrene 50 5567800 - n 22:21 0.9304 0.9962 n n n Dibenzo[a,h]anthracene 50 7430300 - n 22:25 1.6291 1.5744 n n n

Benzo[g,h,i]perylene 50 7994100 - n 22:45 1.1338 1.2238 n n n

Fluorene-d10 100 6920500 - n 11:13 0.2439 0.2707 n n n p-Terphenyl-d14 100 7953900 - n 15:33 0.5313 0.5896 n n n Naphthalene-d8 100 20465000 - n 7:31 1.8244 1.768 n n n 2-Me-Naphthalene-d10 100 7436900 - n 8:39 0.663 0.6459 n n n

Acenaphthylene-d8 100 17020000 - n 10:07 1.5173 1.5191 n n n Phenanthrene-d10 100 28373000 - n 12:47 2.5294 2.4442 n n n Anthracene-d10 100 29830000 - n 12:52 2.6593 2.5518 n n n Fluoranthene-d10 100 14971000 - n 14:44 0.8962 0.8818 n n n Benz[a]anthracene-d12 100 15360000 - n 17:28 0.9195 0.882 n n n Chrysene-d12 100 23914000 - n 17:31 1.4316 1.462 n n n Benzo[b]fluoranthene-d12 100 15288000 - n 19:39 0.7107 0.6883 n n n Benzo[k]fluoranthene-d12 100 21258000 - n 19:43 0.9882 1.0588 n n n

Benzo[a]pyrene-d12 100 16485000 - n 20:16 0.7664 0.7977 n n n

Perylene-d12 100 16644000 - n 20:26 0.7737 0.7883 n n n Indeno[1,2,3-cd]pyrene-d12 100 11969000 - n 22:18 0.5564 0.5329 n n n Dibenzo[a,h]anthracene-d14 100 9122200 - n 22:22 0.4241 0.3723 n n n

Benzo[g,h,i]perylene-d12 100 14102000 - n 22:43 0.6556 0.588 n n n Acenaphthene-d10 100 11217000 - n 10:23 - - n n n Pyrene-d10 100 16704000 - n 15:07 - - n n n Benzo[e]pyrene-d12 100 21511000 - n 20:10 - - n n n

F1 Lock Mass 0 * NotFnd - - n n F2 Lock Mass 0 * NotFnd - - n n F3 Lock Mass 0 * NotFnd - - n n F4 Lock Mass 0 * NotFnd - - n n F5 Lock Mass 0 * NotFnd - - n n F6 Lock Mass 0 * NotFnd - - n n DUMMY LINE 0 * NotFnd - - n n


### Calibration Report OPUS v3.6

Sample ID H4-14-CS#3-0112

Comments C429ALS-CS#3-016 Sample size 1 Filename 4-141115A05 Acquired 15-Nov-2014 15:01 Processed 15-Nov-2014 21:08 Instrument HRMS-4 Column RXI5SILMS1117926 Calibration 4-141115A-CAL6-C429ALSK Cal level 100

Target Analyte Conc Resp RA RT RRF Mean R R M? P1? P2? Coding Comments

Naphthalene 100 22449000 - n 7:33 1.1439 1.278 n n n 2-Me-Naphthalene 100 10432000 - n 8:42 1.4528 1.5231 n n n 1-Me-Naphthalene 100 9995300 - n 8:51 1.392 1.4594 n n n Acenaphthylene 100 21854000 - n 10:08 1.3085 1.4498 n n n Acenaphthene 100 11300000 - n 10:26 0.6766 0.713 n n n

Fluorene 100 9853500 - n 11:17 0.3812 0.3868 n n n Phenanthrene 100 26438000 - n 12:49 1.0228 1.0937 n n n Anthracene 100 29054000 - n 12:54 1.0869 1.133 n n n Fluoranthene 100 18659000 - n 14:46 1.3053 1.4922 n n n

Pyrene 100 20652000 - n 15:09 1.4448 1.6007 n n n Benz[a]anthracene 100 15195000 - n 17:31 1.1742 1.2872 n n n Chrysene/Triphenylene 100 22652000 - n 17:35 1.0219 1.1186 n n n Benzo[b]fluoranthene 100 14910000 - n 19:42 1.1931 1.1652 n n n Benzo[k]fluoranthene 100 18803000 - n 19:45 0.9905 1.039 n n n

Benzo[e]pyrene 100 17022000 - n 20:13 1.1576 1.2608 n n n Benzo[a]pyrene 100 16195000 - n 20:19 1.1014 1.2122 n n n

Perylene 100 20270000 - n 20:28 1.4106 1.5769 n n n Indeno[1,2,3-cd]pyrene 100 6610000 - n 22:21 0.9182 0.9962 n n n Dibenzo[a,h]anthracene 100 8103400 - n 22:25 1.5376 1.5744 n n n

Benzo[g,h,i]perylene 100 8869500 - n 22:45 1.1353 1.2238 n n n

Fluorene-d10 100 7248800 - n 11:14 0.2804 0.2707 n n n p-Terphenyl-d14 100 8238500 - n 15:33 0.5764 0.5896 n n n Naphthalene-d8 100 19625000 - n 7:31 1.7707 1.768 n n n 2-Me-Naphthalene-d10 100 7180600 - n 8:39 0.6479 0.6459 n n n

Acenaphthylene-d8 100 16702000 - n 10:07 1.5069 1.5191 n n n Phenanthrene-d10 100 25849000 - n 12:47 2.3322 2.4442 n n n Anthracene-d10 100 26731000 - n 12:52 2.4118 2.5518 n n n Fluoranthene-d10 100 14294000 - n 14:44 0.8731 0.8818 n n n Benz[a]anthracene-d12 100 12942000 - n 17:28 0.7905 0.882 n n n Chrysene-d12 100 22166000 - n 17:32 1.3539 1.462 n n n Benzo[b]fluoranthene-d12 100 12498000 - n 19:39 0.659 0.6883 n n n Benzo[k]fluoranthene-d12 100 18983000 - n 19:43 1.001 1.0588 n n n

Benzo[a]pyrene-d12 100 14705000 - n 20:16 0.7754 0.7977 n n n

Perylene-d12 100 14370000 - n 20:25 0.7578 0.7883 n n n Indeno[1,2,3-cd]pyrene-d12 100 7198700 - n 22:18 0.3796 0.5329 y y n Dibenzo[a,h]anthracene-d14 100 5270100 - n 22:22 0.2779 0.3723 n n n

Benzo[g,h,i]perylene-d12 100 7812400 - n 22:43 0.412 0.588 n n n Acenaphthene-d10 100 11084000 - n 10:23 - - n n n Pyrene-d10 100 16372000 - n 15:07 - - n n n Benzo[e]pyrene-d12 100 18964000 - n 20:10 - - n n n

F1 Lock Mass 0 * NotFnd - - n n F2 Lock Mass 0 * NotFnd - - n n F3 Lock Mass 0 * NotFnd - - n n F4 Lock Mass 0 * NotFnd - - n n F5 Lock Mass 0 * NotFnd - - n n F6 Lock Mass 0 * NotFnd - - n n DUMMY LINE 0 * NotFnd - - n n


### Calibration Report OPUS v3.6

Sample ID H4-14-CS#4-0112

Comments C429ALS-CS#4-016 Sample size 1 Filename 4-141115A06 Acquired 15-Nov-2014 15:35 Processed 15-Nov-2014 21:08 Instrument HRMS-4 Column RXI5SILMS1117926 Calibration 4-141115A-CAL6-C429ALSK Cal level 200

Target Analyte Conc Resp RA RT RRF Mean R R M? P1? P2? Coding Comments

Naphthalene 200 47550000 - n 7:33 1.2427 1.278 n n n 2-Me-Naphthalene 200 20326000 - n 8:42 1.4313 1.5231 n n n 1-Me-Naphthalene 200 20151000 - n 8:51 1.419 1.4594 n n n Acenaphthylene 200 45027000 - n 10:08 1.3592 1.4498 n n n Acenaphthene 200 22921000 - n 10:25 0.6919 0.713 n n n

Fluorene 200 20796000 - n 11:16 0.3792 0.3868 n n n Phenanthrene 200 57272000 - n 12:48 1.0444 1.0937 n n n Anthracene 200 61653000 - n 12:53 1.1039 1.133 n n n Fluoranthene 200 39414000 - n 14:46 1.3872 1.4922 n n n

Pyrene 200 40869000 - n 15:08 1.4384 1.6007 n n n Benz[a]anthracene 200 29651000 - n 17:30 1.1557 1.2872 n n n Chrysene/Triphenylene 200 43411000 - n 17:35 1.007 1.1186 n n n Benzo[b]fluoranthene 200 18895000 - n 19:42 1.1631 1.1652 n n n Benzo[k]fluoranthene 200 25996000 - n 19:45 1.0241 1.039 n n n

Benzo[e]pyrene 200 20193000 - n 20:12 1.1728 1.2608 n n n Benzo[a]pyrene 200 19215000 - n 20:18 1.116 1.2122 n n n

Perylene 200 28501000 - n 20:28 1.5951 1.5769 n n n Indeno[1,2,3-cd]pyrene 200 6906900 - n 22:20 0.8586 0.9962 n n n Dibenzo[a,h]anthracene 200 9950600 - n 22:25 1.634 1.5744 n n n

Benzo[g,h,i]perylene 200 9955100 - n 22:45 1.1186 1.2238 n n n

Fluorene-d10 100 7622600 - n 11:13 0.278 0.2707 n n n p-Terphenyl-d14 100 8626200 - n 15:33 0.6072 0.5896 n n n Naphthalene-d8 100 19132000 - n 7:31 1.7155 1.768 n n n 2-Me-Naphthalene-d10 100 7100600 - n 8:39 0.6367 0.6459 n n n

Acenaphthylene-d8 100 16563000 - n 10:07 1.4852 1.5191 n n n Phenanthrene-d10 100 27418000 - n 12:46 2.4585 2.4442 n n n Anthracene-d10 100 27925000 - n 12:52 2.504 2.5518 n n n Fluoranthene-d10 100 14207000 - n 14:44 0.9009 0.8818 n n n Benz[a]anthracene-d12 100 12829000 - n 17:28 0.8135 0.882 n n n Chrysene-d12 100 21556000 - n 17:31 1.367 1.462 n n n Benzo[b]fluoranthene-d12 100 8122300 - n 19:39 0.714 0.6883 n n n Benzo[k]fluoranthene-d12 100 12693000 - n 19:43 1.1157 1.0588 n n n

Benzo[a]pyrene-d12 100 8608600 - n 20:16 0.7567 0.7977 n n n

Perylene-d12 100 8934000 - n 20:25 0.7853 0.7883 n n n Indeno[1,2,3-cd]pyrene-d12 100 4022400 - n 22:18 0.3536 0.5329 y y n Dibenzo[a,h]anthracene-d14 100 3044900 - n 22:21 0.2677 0.3723 y y n

Benzo[g,h,i]perylene-d12 100 4449700 - n 22:43 0.3911 0.588 y y n Acenaphthene-d10 100 11152000 - n 10:23 - - n n n Pyrene-d10 100 15769000 - n 15:06 - - n n n Benzo[e]pyrene-d12 100 11376000 - n 20:09 - - n n n

F1 Lock Mass 0 * NotFnd - - n n F2 Lock Mass 0 * NotFnd - - n n F3 Lock Mass 0 * NotFnd - - n n F4 Lock Mass 0 * NotFnd - - n n F5 Lock Mass 0 * NotFnd - - n n F6 Lock Mass 0 * NotFnd - - n n DUMMY LINE 0 * NotFnd - - n n


### Calibration Report OPUS v3.6

Sample ID H4-14-CS#5-0112

Comments C429ALS-CS#5-016 Sample size 1 Filename 4-141115A07 Acquired 15-Nov-2014 16:10 Processed 15-Nov-2014 21:08 Instrument HRMS-4 Column RXI5SILMS1117926 Calibration 4-141115A-CAL6-C429ALSK Cal level 500

Target Analyte Conc Resp RA RT RRF Mean R R M? P1? P2? Coding Comments

Naphthalene 500 119130000 - n 7:33 1.2146 1.278 n n n 2-Me-Naphthalene 500 51894000 - n 8:42 1.4397 1.5231 n n n 1-Me-Naphthalene 500 49070000 - n 8:51 1.3613 1.4594 n n n Acenaphthylene 500 119300000 - n 10:08 1.4091 1.4498 n n n Acenaphthene 500 58480000 - n 10:26 0.6907 0.713 n n n

Fluorene 500 50117000 - n 11:17 0.3646 0.3868 n n n Phenanthrene 500 159730000 - n 12:49 1.1621 1.0937 n n n Anthracene 500 169750000 - n 12:54 1.184 1.133 n n n Fluoranthene 500 108900000 - n 14:46 1.5105 1.4922 n n n

Pyrene 500 120590000 - n 15:08 1.6727 1.6007 n n n Benz[a]anthracene 500 99229000 - n 17:31 1.2903 1.2872 n n n Chrysene/Triphenylene 500 147880000 - n 17:35 1.1347 1.1186 n n n Benzo[b]fluoranthene 500 101730000 - n 19:42 1.3075 1.1652 n n n Benzo[k]fluoranthene 500 136980000 - n 19:45 1.079 1.039 n n n

Benzo[e]pyrene 500 120470000 - n 20:13 1.223 1.2608 n n n Benzo[a]pyrene 500 115410000 - n 20:19 1.1716 1.2122 n n n

Perylene 500 154300000 - n 20:28 1.6131 1.5769 n n n Indeno[1,2,3-cd]pyrene 500 71541000 - n 22:20 0.9694 0.9962 n n n Dibenzo[a,h]anthracene 500 98421000 - n 22:24 1.6263 1.5744 n n n

Benzo[g,h,i]perylene 500 95779000 - n 22:45 1.2067 1.2238 n n n

Fluorene-d10 100 7372000 - n 11:14 0.2682 0.2707 n n n p-Terphenyl-d14 100 8864300 - n 15:33 0.6147 0.5896 n n n Naphthalene-d8 100 19617000 - n 7:31 1.7766 1.768 n n n 2-Me-Naphthalene-d10 100 7209300 - n 8:39 0.6529 0.6459 n n n

Acenaphthylene-d8 100 16933000 - n 10:07 1.5335 1.5191 n n n Phenanthrene-d10 100 27488000 - n 12:47 2.4894 2.4442 n n n Anthracene-d10 100 28673000 - n 12:52 2.5967 2.5518 n n n Fluoranthene-d10 100 14419000 - n 14:44 0.845 0.8818 n n n Benz[a]anthracene-d12 100 15380000 - n 17:28 0.9013 0.882 n n n Chrysene-d12 100 26066000 - n 17:32 1.5275 1.462 n n n Benzo[b]fluoranthene-d12 100 15561000 - n 19:39 0.6668 0.6883 n n n Benzo[k]fluoranthene-d12 100 25391000 - n 19:43 1.0881 1.0588 n n n

Benzo[a]pyrene-d12 100 19700000 - n 20:16 0.8442 0.7977 n n n

Perylene-d12 100 19130000 - n 20:25 0.8198 0.7883 n n n Indeno[1,2,3-cd]pyrene-d12 100 14760000 - n 22:18 0.6325 0.5329 n n n Dibenzo[a,h]anthracene-d14 100 12104000 - n 22:21 0.5187 0.3723 n n n

Benzo[g,h,i]perylene-d12 100 15875000 - n 22:42 0.6803 0.588 n n n Acenaphthene-d10 100 11042000 - n 10:23 - - n n n Pyrene-d10 100 17064000 - n 15:07 - - n n n Benzo[e]pyrene-d12 100 23336000 - n 20:10 - - n n n

F1 Lock Mass 0 * NotFnd - - n n F2 Lock Mass 0 * NotFnd - - n n F3 Lock Mass 0 * NotFnd - - n n F4 Lock Mass 0 * NotFnd - - n n F5 Lock Mass 0 * NotFnd - - n n F6 Lock Mass 0 * NotFnd - - n n DUMMY LINE 0 * NotFnd - - n n


### Calibration Report OPUS v3.6

Sample ID H4-14-CS#6-0112 CALIBRATION REPORT OPUS v3.6

Comments C429ALS-CS#6-016 Sample size 1 Filename 4-141115A08 Acquired 15-Nov-2014 16:44 Processed 15-Nov-2014 21:08 Instrument HRMS-4 Column RXI5SILMS1117926 Calibration 4-141115A-CAL6-C429ALSK Cal level 2000

Target Analyte Conc Resp RA RT RRF Mean R R M? P1? P2?

Naphthalene 2000 585180000 - n 7:33 1.4298 1.278 n n n 2-Me-Naphthalene 2000 251660000 - n 8:42 1.7287 1.5231 n n n 1-Me-Naphthalene 2000 239560000 - n 8:51 1.6455 1.4594 n n n

Acenaphthylene 2000 667080000 - n 10:08 1.8465 1.4498 n n n Acenaphthene 2000 298970000 - n 10:26 0.8276 0.713 n n n Fluorene 2000 259400000 - n 11:17 0.4407 0.3868 n n n Phenanthrene 2000 733980000 - n 12:49 1.2471 1.0937 n n n

Anthracene 2000 782710000 - n 12:54 1.2606 1.133 n n n Fluoranthene 2000 613000000 - n 14:46 2.0372 1.4922 n n n

Pyrene 2000 651600000 - n 15:08 2.1655 1.6007 n n n Benz[a]anthracene 2000 660610000 - n 17:31 1.9317 1.2872 n n n Chrysene/Triphenylene 2000 802280000 - n 17:34 1.3759 1.1186 n n n Benzo[b]fluoranthene 2000 * - n NotFnd * 1.1652 y n n Benzo[k]fluoranthene 2000 * - n NotFnd * 1.039 y n n

Benzo[e]pyrene 2000 688540000 - n 20:13 1.6427 1.2608 n n n Benzo[a]pyrene 2000 677890000 - n 20:19 1.6173 1.2122 n n n Perylene 2000 802910000 - n 20:29 2.0763 1.5769 n n n Indeno[1,2,3-cd]pyrene 2000 462040000 - n 22:20 1.3528 0.9962 n n n Dibenzo[a,h]anthracene 2000 571280000 - n 22:24 * 1.5744 n n n

Benzo[g,h,i]perylene 2000 580540000 - n 22:45 1.6066 1.2238 n n n

Fluorene-d10 100 7788600 - n 11:14 0.2647 0.2707 n n n p-Terphenyl-d14 100 9127100 - n 15:33 0.6066 0.5896 n n n Naphthalene-d8 100 20463000 - n 7:31 1.8179 1.768 n n n 2-Me-Naphthalene-d10 100 7279100 - n 8:39 0.6467 0.6459 n n n

Acenaphthylene-d8 100 18063000 - n 10:07 1.6047 1.5191 n n n Phenanthrene-d10 100 29427000 - n 12:47 2.6143 2.4442 n n n

Anthracene-d10 100 31045000 - n 12:52 2.758 2.5518 n n n Fluoranthene-d10 100 15045000 - n 14:44 0.8837 0.8818 n n n Benz[a]anthracene-d12 100 17099000 - n 17:28 1.0043 0.882 n n n Chrysene-d12 100 29156000 - n 17:32 1.7125 1.462 n n n Benzo[b]fluoranthene-d12 100 15721000 - n 19:40 0.6889 0.6883 n n n Benzo[k]fluoranthene-d12 100 28172000 - n 19:43 1.2345 1.0588 n n n

Benzo[a]pyrene-d12 100 20958000 - n 20:16 0.9184 0.7977 n n n Perylene-d12 100 19335000 - n 20:26 0.8473 0.7883 n n n Indeno[1,2,3-cd]pyrene-d12 100 17077000 - n 22:18 0.7483 0.5329 n n n Dibenzo[a,h]anthracene-d14 100 * - n NotFnd * 0.3723 y n n

Benzo[g,h,i]perylene-d12 100 18067000 - n 22:43 0.7917 0.588 n n n Acenaphthene-d10 100 11256000 - n 10:23 - - n n n Pyrene-d10 100 17025000 - n 15:07 - - n n n Benzo[e]pyrene-d12 100 22820000 - n 20:10 - - n n n

F1 Lock Mass 0 * NotFnd - - n n F2 Lock Mass 0 * NotFnd - - n n F3 Lock Mass 0 * NotFnd - - n n F4 Lock Mass 0 * NotFnd - - n n F5 Lock Mass 0 * NotFnd - - n n F6 Lock Mass 0 * NotFnd - - n n DUMMY LINE 0 * NotFnd - - n n 0Sam p le Name Sam p lin g Date ALS Sam p le ID H4-14-CCV-0452 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e CCV Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A23 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units % Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Tar g et Anal y tes Time % Rec Limit s
Naphthalene 7:35 88 70-130 2-Me-Naphthalene 8:44 98 70-130 1-Me-Naphthalene 8:53 100 70-130

Acenaphthylene 10:10 93 70-130

Acenaphthene 10:27 99 70-130
Fluorene 11:18 96 70-130
Phenanthrene 12:51 87 70-130

Anthracene 12:56 88 70-130
Fluoranthene 14:47 89 70-130 Pyrene 15:10 88 70-130 Benz[a]anthracene 17:32 84 70-130 Chrysene/Triphenylene 17:36 96 70-130

Benzo[b]fluoranthene 19:44 90 70-130 Benzo[k]fluoranthene 19:47 101 70-130 Benzo[e]pyrene 20:15 88 70-130 Benzo[a]pyrene 20:21 91 70-130 Perylene 20:30 94 70-130 Indeno[1,2,3-cd]pyrene 22:22 91 70-130 Dibenzo[a,h]anthracene 22:26 103 70-130

Benzo[g,h,i]perylene 22:47 96 70-130

Field Spike Standards % Rec Limits

Fluorene-d10 11:15 100 70-130 p-Terphenyl-d14 15:35 113 70-130

Extraction Standards % Rec Limits

Naphthalene-d8 7:33 103 70-130 2-Me-Naphthalene-d10 8:41 101 70-130 Acenaphthylene-d8 10:09 97 70-130
Phenanthrene-d10 12:48 100 70-130

Anthracene-d10 12:54 106 70-130
Fluoranthene-d10 14:45 101 70-130 Benz[a]anthracene-d12 17:30 102 70-130 Chrysene-d12 17:33 101 70-130 Benzo[b]fluoranthene-d12 19:41 102 70-130 Benzo[k]fluoranthene-d12 19:45 96 70-130 Benzo[a]pyrene-d12 20:18 95 70-130 Perylene-d12 20:27 103 70-130 Indeno[1,2,3-cd]pyrene-d12 22:20 109 70-130 Dibenzo[a,h]anthracene-d14 22:23 122 70-130

Benzo[g,h,i]perylene-d12 22:44 111 70-130 

# ALS Environmental

Continuin g Calibration Report

CCV n/a n/a Approved: CARB 429 Modified 1 Ella Gd y cz y nski n/a --e-si g nature--
QC 1 17-Nov-2014

16-Nov-14 01:18

Flags



### ALS Canada Ltd L1535265 Data Package 141208a Page 58 of 73Sam p le Name Sam p lin g Date ALS Sam p le ID H4-14-CCV-0453 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e CCV Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115B01 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units % Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Tar g et Anal y tes Time % Rec Limit s
Naphthalene 7:33 87 70-130 2-Me-Naphthalene 8:42 95 70-130 1-Me-Naphthalene 8:51 98 70-130

Acenaphthylene 10:08 92 70-130

Acenaphthene 10:26 100 70-130
Fluorene 11:16 101 70-130
Phenanthrene 12:49 86 70-130

Anthracene 12:54 93 70-130
Fluoranthene 14:46 92 70-130 Pyrene 15:08 91 70-130 Benz[a]anthracene 17:31 90 70-130 Chrysene/Triphenylene 17:35 88 70-130

Benzo[b]fluoranthene 19:42 100 70-130 Benzo[k]fluoranthene 19:45 97 70-130 Benzo[e]pyrene 20:13 90 70-130 Benzo[a]pyrene 20:19 91 70-130 Perylene 20:28 95 70-130 Indeno[1,2,3-cd]pyrene 22:20 92 70-130 Dibenzo[a,h]anthracene 22:25 104 70-130

Benzo[g,h,i]perylene 22:45 94 70-130

Field Spike Standards % Rec Limits

Fluorene-d10 11:14 101 70-130 p-Terphenyl-d14 15:33 115 70-130

Extraction Standards % Rec Limits

Naphthalene-d8 7:31 95 70-130 2-Me-Naphthalene-d10 8:39 95 70-130 Acenaphthylene-d8 10:07 91 70-130
Phenanthrene-d10 12:47 91 70-130

Anthracene-d10 12:52 91 70-130
Fluoranthene-d10 14:44 96 70-130 Benz[a]anthracene-d12 17:28 93 70-130 Chrysene-d12 17:32 100 70-130 Benzo[b]fluoranthene-d12 19:39 91 70-130 Benzo[k]fluoranthene-d12 19:43 93 70-130 Benzo[a]pyrene-d12 20:16 96 70-130 Perylene-d12 20:25 102 70-130 Indeno[1,2,3-cd]pyrene-d12 22:18 117 70-130 Dibenzo[a,h]anthracene-d14 22:21 130 70-130

Benzo[g,h,i]perylene-d12 22:42 117 70-130 

# ALS Environmental

Continuin g Calibration Report

CCV n/a n/a Approved: CARB 429 Modified 1 Ella Gd y cz y nski n/a --e-si g nature--
QC 1 17-Nov-2014

16-Nov-14 01:52

Flags



### ALS Canada Ltd L1535265 Data Package 141208a Page 59 of 73Sam p le Name Sam p lin g Date ALS Sam p le ID H4-14-CCV-045 4 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e CCV Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115B2 2 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units % Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Tar g et Anal y tes Time % Rec Limit s
Naphthalene 7:35 77 70-130 2-Me-Naphthalene 8:45 88 70-130 1-Me-Naphthalene 8:53 88 70-130

Acenaphthylene 10:11 84 70-130

Acenaphthene 10:28 97 70-130
Fluorene 11:20 132 70-130
Phenanthrene 12:52 85 70-130

Anthracene 12:56 88 70-130
Fluoranthene 14:48 81 70-130 Pyrene 15:11 81 70-130 Benz[a]anthracene 17:33 76 70-130 Chrysene/Triphenylene 17:37 82 70-130

Benzo[b]fluoranthene 19:45 89 70-130 Benzo[k]fluoranthene 19:48 96 70-130 Benzo[e]pyrene 20:16 85 70-130 Benzo[a]pyrene 20:22 85 70-130 Perylene 20:31 92 70-130 Indeno[1,2,3-cd]pyrene 22:23 77 70-130 Dibenzo[a,h]anthracene 22:28 90 70-130

Benzo[g,h,i]perylene 22:48 84 70-130

Field Spike Standards % Rec Limits

Fluorene-d10 11:16 141 70-130 p-Terphenyl-d14 15:36 120 70-130

Extraction Standards % Rec Limits

Naphthalene-d8 7:33 81 70-130 2-Me-Naphthalene-d10 8:41 97 70-130 Acenaphthylene-d8 10:10 87 70-130
Phenanthrene-d10 12:49 76 70-130

Anthracene-d10 12:55 84 70-130
Fluoranthene-d10 14:46 101 70-130 Benz[a]anthracene-d12 17:31 66 70-130 Chrysene-d12 17:34 83 70-130 Benzo[b]fluoranthene-d12 19:42 80 70-130 Benzo[k]fluoranthene-d12 19:45 90 70-130 Benzo[a]pyrene-d12 20:19 99 70-130 Perylene-d12 20:28 107 70-130 Indeno[1,2,3-cd]pyrene-d12 22:21 139 M 70-130 Dibenzo[a,h]anthracene-d14 22:24 167 70-130

Benzo[g,h,i]perylene-d12 22:45 143 70-130

M Indicates that a p eak has been manuall y inte g rated. 

# ALS Environmental

Continuin g Calibration Report

CCV n/a n/a Approved: CARB 429 Modified 1 Ella Gd y cz y nski n/a --e-si g nature--
QC 1 17-Nov-2014

16-Nov-14 13:53

Flags



### ALS Canada Ltd L1535265 Data Package 141208a Page 60 of 73Quantification Report OPUS v3.6Sample ID H4-14-CCV-0452Comments C429ALS-CS#3-016Sample size 1Filename 4-141115A23Acquired 16-Nov-2014 01:18Processed 16-Nov-2014 10:04Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 1Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 19792000 - n 7:35 88.2231 0 0.130282 88.2 n n 9896000 2129900 2584 824.3 - - - - 1.0045 7:33 7:372-Me-Naphthalene1 9366400 - n 8:44 97.8825 0 0.044234 97.9 n n 4683200 956800 344 2781.4 - - - - 1.0049 8:42 8:461-Me-Naphthalene1 9147800 - n 8:53 99.7719 0 0.046166 99.8 n n 4573900 961990 344 2796.5 - - - - 1.0231 8:51 8:55Acenaphthylene1 19094000 - n 10:10 92.5437 0 0 92.5 n n 9547200 1811300 0 Div0 - - - - 1.002 10:08 10:12Acenaphthene1 10004000 - n 10:27 98.5992 0 0.020847 98.6 n n 5002200 1008100 164 6146.8 - - - - 1.0306 10:26 10:30Fluorene1 8781800 - n 11:18 95.7884 0 0 95.8 n n 4390900 748500 0 Div0 - - - - 0.8829 11:15 11:19Phenanthrene1 22534000 - n 12:51 86.9387 0 0 86.9 n n 11267000 2056100 0 Div0 - - - - 1.0031 12:48 12:52Anthracene1 25940000 - n 12:56 87.5827 0 0 87.6 n n 12970000 1819600 0 Div0 - - - - 1.0021 12:54 12:58Fluoranthene1 17039000 - n 14:47 88.8859 0 0 88.9 n n 8519300 1506900 0 Div0 - - - - 1.0022 14:45 14:49Pyrene1 18098000 - n 15:10 88.0179 0 0 88 n n 9049200 1632800 0 Div0 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 14071000 - n 17:32 84.2806 0 0 84.3 n n 7035300 1241300 0 Div0 - - - - 1.0024 17:31 17:35Chrysene/Triphenylene1 22747000 - n 17:36 95.9762 0 0 96 n n 11373000 1510700 0 Div0 - - - - 1.0032 17:34 17:38Benzo[b]fluoranthene 1 14098000 - n 19:44 90.4604 0 0 90.5 n n 7048800 1379500 0 Div0 - - - - 1.0021 19:42 19:46Benzo[k]fluoranthene1 20194000 - n 19:47 100.647 0 0 100.6 n n 10097000 1299100 0 Div0 - - - - 1.0021 19:46 19:50Benzo[e]pyrene1 16018000 - n 20:15 87.6754 0 0 87.7 n n 8008800 1451200 0 Div0 - - - - 1.0028 20:12 20:16Benzo[a]pyrene1 15928000 - n 20:21 90.6828 0 0 90.7 n n 7964200 1127100 0 Div0 - - - - 1.0024 20:19 20:23Perylene1 22933000 - n 20:30 94.0631 0 0 94.1 n n 11467000 1794600 0 Div0 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 9992700 - n 22:22 90.7071 0 0 90.7 n n 4996300 749040 0 Div0 - - - - 1.0016 22:21 22:25Dibenzo[a,h]anthracene1 14120000 - n 22:26 103.359 0 0 103.4 n n 7059800 879200 0 Div0 - - - - 1.0025 22:24 22:28Benzo[g,h,i]perylene1 14726000 - n 22:47 96.4862 0 0 96.5 n n 7363100 1001900 0 Div0 - - - - 1.0018 22:45 22:49Fluorene-d101 6438800 - n 11:15 100.36 0 0 100.4 n n 3219400 559420 0 Div0 - - - - 0.8791 11:09 11:19p-Terphenyl-d141 8564100 - n 15:35 113.068 0 0 113.1 n n 4282100 617550 0 Div0 - - - - 1.0559 15:29 15:39Naphthalene-d81 17554000 - n 7:33 102.886 0 0.030483 102.9 n n 8777200 1940000 436 4449.5 - - - - 0.7249 7:27 7:372-Me-Naphthalene-d101 6282600 - n 8:41 100.787 0 0 100.8 n n 3141300 638230 0 Div0 - - - - 0.8343 8:35 8:45Acenaphthylene-d81 14232000 - n 10:09 97.081 0 0 97.1 n n 7115800 1379300 0 Div0 - - - - 0.9749 10:03 10:13Phenanthrene-d101 23699000 - n 12:48 100.473 0 0 100.5 n n 11850000 2151200 0 Div0 - - - - 1.2304 12:43 12:53Anthracene-d101 26140000 - n 12:54 106.15 0 0 106.1 n n 13070000 1823200 0 Div0 - - - - 1.2395 12:48 12:58Fluoranthene-d101 12846000 - n 14:45 101.042 0 0 101 n n 6422900 1147700 0 Div0 - - - - 0.9749 14:40 14:50Benz[a]anthracene-d121 12970000 - n 17:30 101.992 0 0 102 n n 6484900 1228200 0 Div0 - - - - 1.1557 17:24 17:34Chrysene-d121 21188000 - n 17:33 100.518 0 0 100.5 n n 10594000 1437100 0 Div0 - - - - 1.1595 17:27 17:37Benzo[b]fluoranthene-d121 13375000 - n 19:41 101.942 0 0 101.9 n n 6687600 1264600 0 Div0 - - - - 0.9751 19:35 19:45Benzo[k]fluoranthene-d121 19310000 - n 19:45 95.6813 0 0 95.7 n n 9655200 1388500 0 Div0 - - - - 0.9779 19:38 19:48Benzo[a]pyrene-d121 14491000 - n 20:18 95.296 0 0 95.3 n n 7245300 1089000 0 Div0 - - - - 1.0053 20:12 20:22Perylene-d121 15462000 - n 20:27 102.902 0 0 102.9 n n 7730800 1107900 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 11059000 - n 22:20 108.879 0 0 108.9 n n 5529500 585930 0 Div0 - - - - 1.1061 22:13 22:23Dibenzo[a,h]anthracene-d141 8676600 - n 22:23 122.252 0 0 122.3 n n 4338300 500490 0 Div0 - - - - 1.1086 22:17 22:27Benzo[g,h,i]perylene-d121 12471000 - n 22:44 111.27 0 0 111.3 n n 6235500 882440 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 9650400 - n 10:24 86.1099 0 - - n n 4825200 1011200 0 Div0 - - - - 0.6876 10:14 10:34Pyrene-d101 14417000 - n 15:08 87.2698 0 - - n n 7208700 1326200 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 19061000 - n 20:11 96.1759 0 - - n n 9530700 1740800 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 00Quantification Report OPUS v3.6Sample ID H4-14-CCV-0453Comments C429ALS-CS#3-016Sample size 1Filename 4-141115B01Acquired 16-Nov-2014 01:52Processed 16-Nov-2014 10:12Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 1Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 20620000 - n 7:33 87.1469 0 0.14048 87.1 n n 10310000 2259100 2976 759.1 - - - - 1.0046 7:31 7:352-Me-Naphthalene1 9716000 - n 8:42 94.5005 0 0.046586 94.5 n n 4858000 970360 392 2475.4 - - - - 1.006 8:40 8:441-Me-Naphthalene1 9613900 - n 8:51 97.5908 0 0.04862 97.6 n n 4806900 997200 392 2543.9 - - - - 1.0232 8:49 8:53Acenaphthylene1 20286000 - n 10:08 91.7103 0 0 91.7 n n 10143000 1920600 0 Div0 - - - - 1.002 10:06 10:10Acenaphthene1 10875000 - n 10:26 99.9759 0 0.024888 100 n n 5437400 1096200 208 5270.2 - - - - 1.0307 10:24 10:28Fluorene1 9533100 - n 11:16 100.725 0 0 100.7 n n 4766500 820310 0 Div0 - - - - 0.8825 11:14 11:18Phenanthrene1 23110000 - n 12:49 86.3687 0 0 86.4 n n 11555000 2077000 0 Div0 - - - - 1.0031 12:47 12:51Anthracene1 26942000 - n 12:54 92.771 0 0 92.8 n n 13471000 1855800 0 Div0 - - - - 1.002 12:52 12:56Fluoranthene1 17707000 - n 14:46 91.6884 0 0 91.7 n n 8853700 1581700 0 Div0 - - - - 1.0023 14:44 14:48Pyrene1 18942000 - n 15:08 91.4371 0 0 91.4 n n 9471100 1669600 0 Div0 - - - - 1.0022 15:06 15:10Benz[a]anthracene1 14458000 - n 17:31 89.5535 0 0 89.6 n n 7228900 1225000 0 Div0 - - - - 1.0024 17:29 17:33Chrysene/Triphenylene1 22154000 - n 17:35 88.4998 0 0 88.5 n n 11077000 1455600 0 Div0 - - - - 1.0032 17:33 17:37Benzo[b]fluoranthene 1 15632000 - n 19:42 100.035 0 0 100 n n 7816200 1438000 0 Div0 - - - - 1.0025 19:40 19:44Benzo[k]fluoranthene1 21303000 - n 19:45 97.2897 0 0 97.3 n n 10652000 1414400 0 Div0 - - - - 1.0018 19:44 19:48Benzo[e]pyrene1 18651000 - n 20:13 89.5608 0 0 89.6 n n 9325500 1676600 0 Div0 - - - - 1.0025 20:11 20:15Benzo[a]pyrene1 18141000 - n 20:19 90.6035 0 0 90.6 n n 9070400 1343300 0 Div0 - - - - 1.0024 20:17 20:21Perylene1 25945000 - n 20:28 94.9837 0 0 95 n n 12973000 1959600 0 Div0 - - - - 1.0024 20:25 20:29Indeno[1,2,3-cd]pyrene1 12187000 - n 22:20 91.6029 0 0 91.6 n n 6093400 924670 0 Div0 - - - - 1.0019 22:19 22:23Dibenzo[a,h]anthracene1 16957000 - n 22:25 103.781 0 0 103.8 n n 8478500 1071600 0 Div0 - - - - 1.0025 22:22 22:26Benzo[g,h,i]perylene1 17114000 - n 22:45 94.4038 0 0 94.4 n n 8557000 1178800 0 Div0 - - - - 1.0022 22:43 22:47Fluorene-d101 6715600 - n 11:14 101.395 0 0 101.4 n n 3357800 576320 0 Div0 - - - - 0.8786 11:08 11:18p-Terphenyl-d141 8741100 - n 15:33 114.547 0 0 114.5 n n 4370600 651680 0 Div0 - - - - 1.056 15:28 15:38Naphthalene-d81 18515000 - n 7:31 95.184 0 0.023683 95.2 n n 9257400 2072100 376 5510.9 - - - - 0.7242 7:26 7:362-Me-Naphthalene-d101 6750300 - n 8:39 94.9862 0 0 95 n n 3375200 690580 0 Div0 - - - - 0.8331 8:34 8:44Acenaphthylene-d81 15257000 - n 10:07 91.2896 0 0 91.3 n n 7628400 1465300 0 Div0 - - - - 0.9748 10:02 10:12Phenanthrene-d101 24466000 - n 12:47 90.9806 0 0 91 n n 12233000 2199400 0 Div0 - - - - 1.2311 12:42 12:52Anthracene-d101 25632000 - n 12:52 91.2984 0 0 91.3 n n 12816000 1773400 0 Div0 - - - - 1.2403 12:47 12:57Fluoranthene-d101 12942000 - n 14:44 95.8753 0 0 95.9 n n 6471000 1157800 0 Div0 - - - - 0.9748 14:39 14:49Benz[a]anthracene-d121 12542000 - n 17:28 92.8901 0 0 92.9 n n 6271000 1194600 0 Div0 - - - - 1.1563 17:23 17:33Chrysene-d121 22379000 - n 17:32 99.9931 0 0 100 n n 11190000 1481800 0 Div0 - - - - 1.1601 17:26 17:36Benzo[b]fluoranthene-d121 13412000 - n 19:39 90.6741 0 0 90.7 n n 6705900 1305600 0 Div0 - - - - 0.9747 19:34 19:44Benzo[k]fluoranthene-d121 21074000 - n 19:43 92.6251 0 0 92.6 n n 10537000 1413600 0 Div0 - - - - 0.9779 19:37 19:47Benzo[a]pyrene-d121 16518000 - n 20:16 96.357 0 0 96.4 n n 8258900 1187300 0 Div0 - - - - 1.005 20:11 20:21Perylene-d121 17323000 - n 20:25 102.266 0 0 102.3 n n 8661300 1224700 0 Div0 - - - - 1.0128 20:21 20:31Indeno[1,2,3-cd]pyrene-d121 13355000 - n 22:18 116.636 0 0 116.6 n n 6677700 717020 0 Div0 - - - - 1.1058 22:12 22:22Dibenzo[a,h]anthracene-d141 10378000 - n 22:21 129.705 0 0 129.7 n n 5188900 608320 0 Div0 - - - - 1.1087 22:16 22:26Benzo[g,h,i]perylene-d121 14813000 - n 22:42 117.237 0 0 117.2 n n 7406500 1024500 0 Div0 - - - - 1.1261 22:37 22:47Acenaphthene-d101 11002000 - n 10:23 98.17 0 - - n n 5501000 1122500 0 Div0 - - - - 0.6869 10:13 10:33Pyrene-d101 15308000 - n 15:07 92.6608 0 - - n n 7654000 1402700 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 21489000 - n 20:10 108.423 0 - - n n 10744000 1897500 0 Div0 - - - - 1.3346 19:60 20:20F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:08 25:280 0 0 0Quantification Report OPUS v3.6Sample ID H4-14-CCV-0454Comments C429ALS-CS#3-016Sample size 1Filename 4-141115B22Acquired 16-Nov-2014 13:53Processed 16-Nov-2014 17:17Instrument HRMS-4Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 1Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 13878000 - n 7:35 76.5932 0 0.072653 76.6 n n 6939200 1442900 1112 1297.6 - - - - 1.0046 7:33 7:372-Me-Naphthalene1 8312100 - n 8:45 87.6251 0 0.039194 87.6 n n 4156100 845830 308 2746.2 - - - - 1.0059 8:42 8:461-Me-Naphthalene1 8036400 - n 8:53 88.4174 0 0.040905 88.4 n n 4018200 854940 308 2775.8 - - - - 1.0231 8:51 8:55Acenaphthylene1 16008000 - n 10:11 84.446 0 0 84.4 n n 8004000 1519900 0 Div0 - - - - 1.002 10:09 10:13Acenaphthene1 9017400 - n 10:28 96.7318 0 0.01918 96.7 n n 4508700 917990 136 6749.9 - - - - 1.0305 10:27 10:31Fluorene1 9418100 - n 11:20 132.07 0 0 132.1 y n 4709100 741470 0 Div0 - - - - 0.8841 11:16 11:20Phenanthrene1 17169000 - n 12:52 85.1579 0 0 85.2 n n 8584300 1467400 0 Div0 - - - - 1.0031 12:49 12:53Anthracene1 21284000 - n 12:56 88.0895 0 0 88.1 n n 10642000 1285600 0 Div0 - - - - 1.002 12:55 12:59Fluoranthene1 15242000 - n 14:48 81.1267 0 0 81.1 n n 7621000 1207100 0 Div0 - - - - 1.0022 14:46 14:50Pyrene1 16399000 - n 15:11 81.3708 0 0 81.4 n n 8199500 1345000 0 Div0 - - - - 1.0022 15:08 15:12Benz[a]anthracene1 8099600 - n 17:33 76.342 0 0 76.3 n n 4049800 705130 0 Div0 - - - - 1.0028 17:32 17:36Chrysene/Triphenylene1 15731000 - n 17:37 82.0723 0 0 82.1 n n 7865300 891710 0 Div0 - - - - 1.0032 17:35 17:39Benzo[b]fluoranthene 1 8436800 - n 19:45 88.5596 0 0 88.6 n n 4218400 807900 0 Div0 - - - - 1.0025 19:43 19:47Benzo[k]fluoranthene1 14195000 - n 19:48 96.1173 0 0 96.1 n n 7097500 814550 0 Div0 - - - - 1.0021 19:46 19:50Benzo[e]pyrene1 12662000 - n 20:16 85.4746 0 0 85.5 n n 6331200 1105400 0 Div0 - - - - 1.0028 20:13 20:17Benzo[a]pyrene1 12142000 - n 20:22 85.2472 0 0 85.2 n n 6070900 825560 0 Div0 - - - - 1.0024 20:20 20:24Perylene1 18249000 - n 20:31 91.7441 0 0 91.7 n n 9124600 1267100 0 Div0 - - - - 1.0024 20:28 20:32Indeno[1,2,3-cd]pyrene1 8524400 - n 22:23 77.1777 0 0 77.2 n n 4262200 588210 0 Div0 - - - - 1.0017 22:22 22:26Dibenzo[a,h]anthracene1 13160000 - n 22:28 89.7926 0 0 89.8 n n 6580200 729100 0 Div0 - - - - 1.0025 22:25 22:29Benzo[g,h,i]perylene1 12944000 - n 22:48 83.9993 0 0 84 n n 6471800 833740 0 Div0 - - - - 1.0023 22:46 22:50Fluorene-d101 7036900 - n 11:16 141.011 0 0 141 n n 3518500 565610 0 Div0 - - - - 0.8791 11:10 11:20p-Terphenyl-d141 8872000 - n 15:36 119.508 0 0 119.5 n n 4436000 558330 0 Div0 - - - - 1.0558 15:30 15:40Naphthalene-d81 14178000 - n 7:33 80.8986 0 0.025954 80.9 n n 7089200 1497100 368 4068.1 - - - - 0.7246 7:28 7:382-Me-Naphthalene-d101 6228100 - n 8:41 97.2665 0 0 97.3 n n 3114000 644930 0 Div0 - - - - 0.8339 8:36 8:46Acenaphthylene-d81 13075000 - n 10:10 86.8312 0 0 86.8 n n 6537600 1243200 0 Div0 - - - - 0.9749 10:04 10:14Phenanthrene-d101 18434000 - n 12:49 76.0821 0 0 76.1 n n 9217000 1606100 0 Div0 - - - - 1.2301 12:44 12:54Anthracene-d101 21325000 - n 12:55 84.3024 0 0 84.3 n n 10662000 1258600 0 Div0 - - - - 1.2392 12:49 12:59Fluoranthene-d101 12590000 - n 14:46 100.856 0 0 100.9 n n 6295200 1012500 0 Div0 - - - - 0.9749 14:41 14:51Benz[a]anthracene-d121 8242300 - n 17:31 66.0091 0 0 66 n n 4121100 750820 0 Div0 - - - - 1.1556 17:25 17:35Chrysene-d121 17135000 - n 17:34 82.7861 0 0 82.8 n n 8567400 1003000 0 Div0 - - - - 1.1594 17:28 17:38Benzo[b]fluoranthene-d121 8176200 - n 19:42 79.5469 0 0 79.5 n n 4088100 795390 0 Div0 - - - - 0.9751 19:36 19:46Benzo[k]fluoranthene-d121 14214000 - n 19:45 89.8992 0 0 89.9 n n 7106800 877060 0 Div0 - - - - 0.9779 19:39 19:49Benzo[a]pyrene-d121 11750000 - n 20:19 98.6392 0 0 98.6 n n 5875100 767490 0 Div0 - - - - 1.0054 20:13 20:23Perylene-d121 12615000 - n 20:28 107.166 0 0 107.2 n n 6307300 818900 0 Div0 - - - - 1.0132 20:23 20:33Indeno[1,2,3-cd]pyrene-d121 11088000 - n 22:21 139.346 0 0 139.3 y n 5543900 516060 0 Div0 - - - - 1.1062 22:14 22:24Dibenzo[a,h]anthracene-d141 9309000 - n 22:24 167.428 0 0 167.4 n n 4654500 463450 0 Div0 - - - - 1.1088 22:18 22:28Benzo[g,h,i]perylene-d121 12591000 - n 22:45 143.402 0 0 143.4 n n 6295500 819290 0 Div0 - - - - 1.126 22:39 22:49Acenaphthene-d101 9912800 - n 10:25 88.4519 0 - - n n 4956400 1002500 0 Div0 - - - - 0.6878 10:15 10:35Pyrene-d101 14157000 - n 15:09 85.6925 0 - - n n 7078400 1173600 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 14933000 - n 20:12 75.3441 0 - - n n 7466300 1254900 0 Div0 - - - - 1.3334 20:02 20:22F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 0F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:10 25:300 0 0 00

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including: for Laboratory Method Blanks: - Laboratory Method Blank Analysis Reports - Individual Quantitation Reports

for LCS: -Laboratory Control Sample Analysis Reports - Individual Quantitation Reports

for MS: - Matrix Spike Analysis Reports - Individual Quantitation Reports

for Others (eg. Reference Data): - QC Sample Analysis Reports - Individual Quantitation Reports 

# SVOC DATA PACKAGE

SECTION 5: QC SAMPLE DATASam p le Name Sam p lin g Date ALS Sam p le ID WG1980014- 2 Extraction Date Anal y sis Method Sam p le Size Ana ly sis T yp e LCS Moisture Content Sample Matrix Split Ratio

Run Information Run 1

Filename 4-141115A1 0 Run Date Final Volume 1000 u L Dilution Factor 1 Anal y sis Units % Instrument - Column HRMS-4 Rxi5Sil1117926

Ret. Tar g et Anal y tes Time % Rec Limit s
Naphthalene 7:34 123 50-150 2-Me-Naphthalene n/s 1-Me-Naphthalene n/s

Acenaphthylene 10:10 98 50-150

Acenaphthene 10:27 103 50-150
Fluorene 11:18 105 50-150
Phenanthrene 12:50 99 50-150

Anthracene 12:55 101 50-150
Fluoranthene 14:47 102 50-150 Pyrene 15:10 92 50-150 Benz[a]anthracene 17:32 103 50-150 Chrysene/Triphenylene 17:36 97 50-150

Benzo[b]fluoranthene 19:43 109 50-150 Benzo[k]fluoranthene 19:47 103 50-150 Benzo[e]pyrene n/s Benzo[a]pyrene 20:20 89 50-150 Perylene n/s Indeno[1,2,3-cd]pyrene 22:21 111 50-150 Dibenzo[a,h]anthracene 22:26 104 50-150

Benzo[g,h,i]perylene 22:46 104 50-150

Field Spike Standards % Rec Limits

Fluorene-d10 11:15 n/s p-Terphenyl-d14 15:34 n/s

Extraction Standards % Rec Limits

Naphthalene-d8 7:32 85 20-150 2-Me-Naphthalene-d10 8:40 81 20-150 Acenaphthylene-d8 10:08 84 20-150
Phenanthrene-d10 12:48 80 30-150

Anthracene-d10 12:53 74 30-150
Fluoranthene-d10 14:45 91 30-150 Benz[a]anthracene-d12 17:29 56 30-150 Chrysene-d12 17:33 50 30-150 Benzo[b]fluoranthene-d12 19:40 85 30-150 Benzo[k]fluoranthene-d12 19:44 79 30-150 Benzo[a]pyrene-d12 20:17 75 30-150 Perylene-d12 20:27 79 30-150 Indeno[1,2,3-cd]pyrene-d12 22:19 79 30-150 Dibenzo[a,h]anthracene-d14 22:22 80 30-150

Benzo[g,h,i]perylene-d12 22:44 81 30-150

n/s Indicates that this standard has not been s p iked. 

# ALS Environmental

Laboratory Control Sample Analysis Report

Laborator y Control Sam p l e n/a 28-Oct-14 Approved: CARB 429 Modified 1 Ella Gd y cz y nski n/a --e-si g nature--
QC 1 17-Nov-2014

15-Nov-14 17:53

FlagsSample ID WG1980014-2Comments LCSSample size 1Filename 4-141115A10Acquired 41958.74515Processed 41958.89339Instrument 0Column RXI5SILMS1117926Calibration 4-141115A-CAL6-C429»ES level 10Target Analyte #Hom Resp RA RT Conc Tox #1 DL Rec MM P1? P2? Coding Comments Area1 Hght1 Nois1 S/N 1 Area2 Hght2 Nois2 S/N 2 RRT RT LCL RT UCLNaphthalene1 58117000 - n 7:34 123.263 0 0.857043 123.3 n n 29059000 5849100 31796 184 - - - - 1.0044 7:32 7:362-Me-Naphthalene1 171590 - n 8:43 0.879253 0 0.047379 0.9 n n 85795 15303 868 17.6 - - - - 1.0058 8:41 8:451-Me-Naphthalene1 194070 - n 8:52 1.03789 0 0.049448 1 n n 97037 17301 868 19.9 - - - - 1.0231 8:50 8:54Acenaphthylene1 44062000 - n 10:10 97.7306 0 0 97.7 n n 22031000 5179200 0 Div0 - - - - 1.0033 10:07 10:11Acenaphthene1 22847000 - n 10:27 103.049 0 0.012917 103 n n 11424000 2778900 264 10526.1 - - - - 1.0313 10:25 10:29Fluorene1 19565000 - n 11:18 105.128 0 0 105.1 n n 9782700 2088300 0 Div0 - - - - 0.8828 11:15 11:19Phenanthrene1 52176000 - n 12:50 99.1634 0 0 99.2 n n 26088000 5323600 0 Div0 - - - - 1.0026 12:48 12:52Anthracene1 52660000 - n 12:55 100.996 0 0 101 n n 26330000 4671000 0 Div0 - - - - 1.0026 12:53 12:57Fluoranthene1 33618000 - n 14:47 101.926 0 0 101.9 n n 16809000 3303300 0 Div0 - - - - 1.0023 14:45 14:49Pyrene1 32381000 - n 15:10 91.5262 0 0 91.5 n n 16191000 3096000 0 Div0 - - - - 1.0022 15:07 15:11Benz[a]anthracene1 17865000 - n 17:32 103.075 0 0 103.1 n n 8932700 1632900 0 Div0 - - - - 1.0029 17:30 17:34Chrysene/Triphenylene1 21876000 - n 17:36 97.3937 0 0 97.4 n n 10938000 1580200 0 Div0 - - - - 1.0028 17:34 17:38Benzo[b]fluoranthene1 13833000 - n 19:43 108.765 0 0 108.8 n n 6916500 1331000 0 Div0 - - - - 1.0025 19:41 19:45Benzo[k]fluoranthene1 16626000 - n 19:47 103.093 0 0 103.1 n n 8312900 1206100 0 Div0 - - - - 1.0025 19:45 19:49Benzo[e]pyrene1 103780 - n 20:14 0.735918 0 0 0.7 n n 51888 7513.4 0 Div0 - - - - 1.0025 20:12 20:16Benzo[a]pyrene1 12009000 - n 20:20 88.578 0 0 88.6 n n 6004600 903740 0 Div0 - - - - 1.0025 20:18 20:22Perylene1 406360 - n 20:30 2.21514 0 0 2.2 n n 203180 19124 0 Div0 - - - - 1.0024 20:27 20:31Indeno[1,2,3-cd]pyrene1 8641000 - n 22:21 110.598 0 0 110.6 n n 4320500 669620 0 Div0 - - - - 1.0015 22:20 22:24Dibenzo[a,h]anthracene1 9003400 - n 22:26 103.512 0 0 103.5 n n 4501700 582350 0 Div0 - - - - 1.003 22:23 22:27Benzo[g,h,i]perylene1 11279000 - n 22:46 104.376 0 0 104.4 n n 5639300 789390 0 Div0 - - - - 1.0015 22:45 22:49Fluorene-d101 6347.2 - n 11:15 0.048735 0 0 0 n n 3173.6 597.43 0 Div0 - - - - 0.8789 11:09 11:19p-Terphenyl-d141 996.71 - n 15:34 0.007648 0 0 0 n n 498.35 113.12 0 Div0 - - - - 1.0554 15:29 15:39Naphthalene-d81 36894000 - n 7:32 85.2368 0 0.026887 85.2 n n 18447000 3628800 1128 3217 - - - - 0.7244 7:27 7:372-Me-Naphthalene-d101 12813000 - n 8:40 81.025 0 0 81 n n 6406500 1503500 0 Div0 - - - - 0.8333 8:35 8:45Acenaphthylene-d81 31097000 - n 10:08 83.6206 0 0 83.6 n n 15549000 3583300 0 Div0 - - - - 0.9744 10:03 10:13Phenanthrene-d101 48110000 - n 12:48 80.4001 0 0 80.4 n n 24055000 5015300 0 Div0 - - - - 1.2308 12:43 12:53Anthracene-d101 46019000 - n 12:53 73.6642 0 0 73.7 n n 23010000 4141500 0 Div0 - - - - 1.2388 12:48 12:58Fluoranthene-d101 22103000 - n 14:45 91.4809 0 0 91.5 n n 11051000 2187900 0 Div0 - - - - 0.9747 14:40 14:50Benz[a]anthracene-d121 13465000 - n 17:29 55.7172 0 0 55.7 n n 6732500 1303300 0 Div0 - - - - 1.1553 17:24 17:34Chrysene-d121 20080000 - n 17:33 50.1279 0 0 50.1 n n 10040000 1472100 0 Div0 - - - - 1.1597 17:27 17:37Benzo[b]fluoranthene-d121 10916000 - n 19:40 85.3653 0 0 85.4 n n 5457800 1121800 0 Div0 - - - - 0.9744 19:35 19:45Benzo[k]fluoranthene-d121 15521000 - n 19:44 78.9125 0 0 78.9 n n 7760600 1151500 0 Div0 - - - - 0.9777 19:38 19:48Benzo[a]pyrene-d121 11185000 - n 20:17 75.4749 0 0 75.5 n n 5592500 831740 0 Div0 - - - - 1.005 20:12 20:22Perylene-d121 11634000 - n 20:27 79.4459 0 0 79.4 n n 5816800 828630 0 Div0 - - - - 1.0132 20:22 20:32Indeno[1,2,3-cd]pyrene-d121 7843100 - n 22:19 79.2331 0 0 79.2 n n 3921600 438970 0 Div0 - - - - 1.1057 22:13 22:23Dibenzo[a,h]anthracene-d141 5524500 - n 22:22 79.8696 0 0 79.9 n n 2762200 372210 0 Div0 - - - - 1.1082 22:17 22:27Benzo[g,h,i]perylene-d121 8829400 - n 22:44 80.8343 0 0 80.8 n n 4414700 638190 0 Div0 - - - - 1.1263 22:38 22:48Acenaphthene-d101 24481000 - n 10:24 218.447 0 - - n n 12241000 2966200 0 Div0 - - - - 0.6872 10:14 10:34Pyrene-d101 27399000 - n 15:08 165.85 0 - - n n 13700000 2694700 0 Div0 - - - - * 14:48 15:28Benzo[e]pyrene-d121 18577000 - n 20:11 93.7305 0 - - n n 9288300 1643000 0 Div0 - - - - 1.3337 20:01 20:21F1 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F2 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F3 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F4 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F5 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0F6 Lock Mass0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0DUMMY LINE0 * NotFnd * * - - n * *0 Div0 * 25:09 25:290 0 0 0 000000000000 0

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including: - Prep Logs - Run Logs - Quantification tables - Independent calculation checks - Others as listed below: 

# SVOC DATA PACKAGE

SECTION 6: INTERNAL RECORDS

## Date: 15-NOV-14 O p erator: EG Instrument: HRMS-4 MS Method: C429-DB5MS-3 GC Method: C429-DB5MS-3

Column: RXI5SILMS1117926

# Data_file S Vial Sam p le_text Comments Ac q uisition Time

1 4-141115A01 1 1 xxxxxx xxxxxx 15-Nov-2014 12:49 2 4-141115A02 1 1 xxxxxx xxxxxx 15-Nov-2014 13:19 3 4-141115A03 1 1 H4-14-CS#1-0112 C429ALS-CS#1-016 15-Nov-2014 13:53 4 4-141115A04 1 1 H4-14-CS#2-0112 C429ALS-CS#2-016 15-Nov-2014 14:27 5 4-141115A05 1 1 H4-14-CS#3-0112 C429ALS-CS#3-016 15-Nov-2014 15:01 6 4-141115A06 1 1 H4-14-CS#4-0112 C429ALS-CS#4-016 15-Nov-2014 15:35 7 4-141115A07 1 1 H4-14-CS#5-0112 C429ALS-CS#5-016 15-Nov-2014 16:10 8 4-141115A08 1 1 H4-14-CS#6-0112 C429ALS-CS#6-016 15-Nov-2014 16:44 9 4-141115A09 1 1 H4-14-RS#4-0112 C429ALS-RS#4-016 15-Nov-2014 17:18 10 4-141115A10 1 1 WG1980014-2 LCS 15-Nov-2014 17:53 11 4-141115A11 1 1 WG1980014-3A ENI 15-Nov-2014 18:27 12 4-141115A12 1 1 DCM INST BLANK 15-Nov-2014 19:01 13 4-141115A13 1 1 DCM INST BLANK 15-Nov-2014 19:35 14 4-141115A14 1 1 WG1980014-1 METHOD BLANK 15-Nov-2014 20:10 15 4-141115A15 1 1 L1535265-11 SAMPLE X10 15-Nov-2014 20:44 16 4-141115A16 1 1 L1535265-4 SAMPLE X10 15-Nov-2014 21:18 17 4-141115A17 1 1 L1535265-3 SAMPLE X10 15-Nov-2014 21:52 18 4-141115A18 1 1 L1535265-3 SAMPLE X50 15-Nov-2014 22:27 19 4-141115A19 1 1 L1535265-1 DILUTIONX50000 15-Nov-2014 23:01 20 4-141115A20 1 1 L1535265-2 DILUTIONX50000 15-Nov-2014 23:35 21 4-141115A21 1 1 L1535265-5 DILUTIONX50000 16-Nov-2014 00:09 22 4-141115A22 1 1 xxxxxx xxxxxx 16-Nov-2014 00:44 23 4-141115A23 1 1 H4-14-CCV-0452 C429ALS-CS#3-016 16-Nov-2014 01:18 Instrument Runlo gQuantification Tabl

c/q Data File S I AnalyteTable CAL level ES level Size Sample ID Comments

1 c 4-141115A03 1 1 C29ALS-DB5MS-HRMS4-C 10 1 1 H4-14-CS#1-0112 C429ALS-CS#1-016 2 c 4-141115A04 1 1 C29ALS-DB5MS-HRMS4-C 50 1 1 H4-14-CS#2-0112 C429ALS-CS#2-016 3 c 4-141115A05 1 1 C29ALS-DB5MS-HRMS4-C 100 1 1 H4-14-CS#3-0112 C429ALS-CS#3-016 4 c 4-141115A06 1 1 C29ALS-DB5MS-HRMS4-C 200 1 1 H4-14-CS#4-0112 C429ALS-CS#4-016 5 c 4-141115A07 1 1 C29ALS-DB5MS-HRMS4-C 500 1 1 H4-14-CS#5-0112 C429ALS-CS#5-016 6 c 4-141115A08 1 1 C29ALS-DB5MS-HRMS4-C 2000 1 1 H4-14-CS#6-0112 C429ALS-CS#6-016 7 q 4-141115A09 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-RS#4-0112 C429ALS-RS#4-016 8 q 4-141115A10 1 1 C429ALS-DB5MS-HRMS4-CCV 100 10 1 WG1980014-2 LCS 9 q 4-141115A11 1 1 C429ALS-DB5MS-HRMS4-CCV 100 10 1 WG1980014-3A ENI 10 q 4-141115A14 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 WG1980014-1 METHOD BLANK 11 q 4-141115A15 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-11 SAMPLE X10 12 q 4-141115A16 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-4 SAMPLE X10 13 q 4-141115A17 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-3 SAMPLE X10 14 q 4-141115A18 1 1 C429ALS-DB5MS-HRMS4-Q 1 10 1 L1535265-3 SAMPLE X50 15 q 4-141115A19 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-1 DILUTIONX50000 16 q 4-141115A20 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-2 DILUTIONX50000 17 q 4-141115A21 1 1 C429ALS-DB5MS-HRMS4-Q 1 5010 1 L1535265-5 DILUTIONX50000 18 q 4-141115A23 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-CCV-0452 C429ALS-CS#3-016

## Pa g e 1 of 1

Date: 15-NOV-14 O p erator: EG Instrument: HRMS-4 MS Method: C429-DB5MS-3 GC Method: C429-DB5MS-3

Column: RXI5SILMS1117926

# Data_file S Vial Sam p le_text Comments Ac q uisition Time

1 4-141115B01 1 1 H4-14-CCV-0453 C429ALS-CS#3-016 16-Nov-2014 01:52 2 4-141115B02 1 1 DCM INST BLANK 16-Nov-2014 02:27 3 4-141115B03 1 1 DCM INST BLANK 16-Nov-2014 03:01 4 4-141115B04 1 1 L1535265-1 SAMPLE X50 DILX10 R サ 16-Nov-2014 03:35 5 4-141115B05 1 1 L1535265-2 SAMPLE X50 DILX10 R サ 16-Nov-2014 04:10 6 4-141115B06 1 1 L1535265-5 SAMPLE X50 DILX10 R サ 16-Nov-2014 04:44 7 4-141115B07 1 1 L1535265-6 SAMPLE X50 DILX10 R サ 16-Nov-2014 05:18 8 4-141115B08 1 1 L1535265-7 SAMPLE X50 16-Nov-2014 05:52 9 4-141115B09 1 1 L1535265-8 SAMPLE X50 16-Nov-2014 06:27 10 4-141115B10 1 1 L1535265-9 SAMPLE X50 16-Nov-2014 07:01 11 4-141115B11 1 1 L1535265-10 SAMPLE X50 16-Nov-2014 07:35 12 4-141115B12 1 1 L1535265-7 SAMPLE X10 16-Nov-2014 08:10 13 4-141115B13 1 1 L1535265-8 SAMPLE X10 16-Nov-2014 08:44 14 4-141115B14 1 1 L1535265-9 SAMPLE X50 REINJECT 16-Nov-2014 09:18 15 4-141115B15 1 1 L1535265-9 SAMPLE X10 16-Nov-2014 09:53 16 4-141115B16 1 1 L1535265-10 SAMPLE X10 16-Nov-2014 10:27 17 4-141115B17 1 1 L1535265-1 SAMPLE X50 16-Nov-2014 11:01 18 4-141115B18 1 1 L1535265-2 SAMPLE X50 16-Nov-2014 11:36 19 4-141115B19 1 1 L1535265-5 SAMPLE X50 16-Nov-2014 12:10 20 4-141115B20 1 1 L1535265-6 SAMPLE X50 16-Nov-2014 12:44 21 4-141115B21 1 1 DCM INST BLANK 16-Nov-2014 13:19 22 4-141115B22 1 1 H4-14-CCV-0454 C429ALS-CS#3-016 16-Nov-2014 13:53Q uantification Table

c/ q Data File S I Anal y teTable CAL level ES level Size Sam p le ID Comments

1 c 4-141115A03 1 1 C429ALS-DB5MS-HRMS4-C 10 1 1 H4-14-CS#1-0112 C429ALS-CS#1-016 2 c 4-141115A04 1 1 C429ALS-DB5MS-HRMS4-C 50 1 1 H4-14-CS#2-0112 C429ALS-CS#2-016 3 c 4-141115A05 1 1 C429ALS-DB5MS-HRMS4-C 100 1 1 H4-14-CS#3-0112 C429ALS-CS#3-016 4 c 4-141115A06 1 1 C429ALS-DB5MS-HRMS4-C 200 1 1 H4-14-CS#4-0112 C429ALS-CS#4-016 5 c 4-141115A07 1 1 C429ALS-DB5MS-HRMS4-C 500 1 1 H4-14-CS#5-0112 C429ALS-CS#5-016 6 c 4-141115A08 1 1 C429ALS-DB5MS-HRMS4-C 2000 1 1 H4-14-CS#6-0112 C429ALS-CS#6-016 7 q 4-141115B01 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-CCV-0453 C429ALS-CS#3-016 8 q 4-141115B04 1 1 C429ALS-DB5MS-HRMS4- Q 1 5010 1 L1535265-1 SAMPLE X50 DILX10 RES 9 q 4-141115B05 1 1 C429ALS-DB5MS-HRMS4- Q 1 5010 1 L1535265-2 SAMPLE X50 DILX10 RES 10 q 4-141115B06 1 1 C429ALS-DB5MS-HRMS4- Q 1 5010 1 L1535265-5 SAMPLE X50 DILX10 RES 11 q 4-141115B07 1 1 C429ALS-DB5MS-HRMS4- Q 1 5010 1 L1535265-6 SAMPLE X50 DILX10 RES 12 q 4-141115B08 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-7 SAMPLE X50 13 q 4-141115B09 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-8 SAMPLE X50 14 q 4-141115B10 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-9 SAMPLE X50 15 q 4-141115B11 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-10 SAMPLE X50 16 q 4-141115B12 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-7 SAMPLE X10 17 q 4-141115B13 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-8 SAMPLE X10 18 q 4-141115B14 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-9 SAMPLE X50 REINJECT 19 q 4-141115B15 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-9 SAMPLE X10 20 q 4-141115B16 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-10 SAMPLE X10 21 q 4-141115B17 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-1 SAMPLE X50 22 q 4-141115B18 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-2 SAMPLE X50 23 q 4-141115B19 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-5 SAMPLE X50 24 q 4-141115B20 1 1 C429ALS-DB5MS-HRMS4- Q 1 10 1 L1535265-6 SAMPLE X50 25 q 4-141115B22 1 1 C429ALS-DB5MS-HRMS4-CCV 100 1 1 H4-14-CCV-0454 C429ALS-CS#3-016Approved: Ella Gdyczynski --e-signature-- 

### Calculation of RRF for Na p hthalene in H4-14-CS#3-0112

Res p onse of Na p hthalene Concentration of d8-Na p hthalene RRF =

______________________ x

_____________________________ Response of d8-Naphthalene Concentration of Naphthalene

2.24E+07 100 RRF =

______________________ x

_____________________________ = 1.14

1.96E+07 100

Calculation of Na p hthalene amount in L1535265-11

Res p onse of Na p hthalene n g of d8-Na p hthalene s p iked dilution

n g =

______________________ x

____________________________________________ Response of d8-Naphthalene Mean RRF of Naphthalene * Sample Size

1433850 100 # 10.00

n g =

______________________ x

_________________________________________ = 103.472

10843000 1.28 * 1.00

Calculation of d8-Na p hthalene recover y in L1535265-11

Res p onse of d8-Na p hthalene n g of d10-Acena p hthene s p iked * 100% % Recover y =

______________________ x

____________________________________________ Response of d10-Acenaphthene Mean RRF d8-Naphthalene * ng of d8-Naphthalene spiked

10843000 100 * 100 % Recover y =

______________________ x

_________________________________________ = 7 2 %

8479000 1.77 * 100 

# ALS Environmental

Sam p le Calculation Re p ort

17-Nov-2014

## 5420 Mainway Drive, Unit 5, Burlington ON, L7L 6A4

Including: - Airbills - Chain-of-Custody Records - Sample Log-in Sheet(s) - where applicable - Others as listed below: 

# SVOC DATA PACKAGE

SECTION 7: SHIPPING/RECEIVING

DOCUMENTS

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# Envil.onmenrul Qualify Management, Inc. 

# "Q C~lvIro~~rne~rtal Quallly Management, Inc. 

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ALS 

# Environmental

Street Address: 5420 

# Mainway Dr. Unit 5 Street Address:

City/Province: 

# Burlington, ON City/Province: 

# Crown Point, 

# 1b 

# ~

Postal Code: 

# L7L 

# 6A4

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# Acetone 

# / Class 3 

# / UNI 090 

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# II 2 L Postal Code: 

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# / Class 3 

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# / UN1593 

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# Carbonate Buffer Solution (not regulated)

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# 996-6666 (call colle

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Released By: (Shipper) Received By: (Carrier or Consignee)

Date: 20-Oct- 14



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