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# MATERIAL SAFETY DATA SHEET

1 PRODUCT AND COMPANY IDENTIFICATION

Product Name: Experimental Imidazolines

Synonyms:

Manufacturer Name: Emergency Telephone:

1-800-424-9300

Non-emergency Telephone:

Intended Use: For Research and Development

Purposes Only

2 HAZARDS IDENTIFICATION

Emergency Overview

Physical State: Liquid to solid

Color: Brown

Odor: No data available.

DANGER!

Causes skin and eye burns. Mist or vapor irritating to eyes and respiratory tract. The toxicological

properties of this material have not been fully investigated.

Potential Health Effects

Inhalation: Causes respiratory tract irritation.

Eye Contact: Causes eye burns.

Skin Contact: Causes skin burns.

Ingestion: Causes digestive tract burns.

Target Organ(s): | Respiratory system | Eye | Lung | Skin |

OSHA Regulatory Status: This product is hazardous according to OSHA 29CFR 1910.1200.Experimental Imidazolines

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3 COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name CAS

- No. Concentration *

Not assigned > 90%

†Glycerin 56

- 81

- 5 < 10%

* All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

† This chemical is hazardous according to OSHA/WHMIS criteria.

4 FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing stops, provide artificial respiration. For breathing difficulties,

oxygen may be necessary. Get medical attention.

Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact

lenses. Get medical attention immediately.

Skin Contact: Immediately flush with plenty of water for at least 15 minutes while removing

contaminated clothing and shoes. Get medical attention immediately. Wash contaminated clothing before

reuse. Destroy or thoroughly clean contaminated shoes.

Ingestion: Call a physician or poison control center immediately. DO NOT induce vomiting. if victim is

fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. I f

vomiting occurs, keep head lower than the hips to help prevent aspiration.

5 FIRE

- FIGHTING MEASURES

Extinguishing Media: Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

Unsuitable Extinguishing Media: None.

Special Fire Fighting Procedures: Self-contained breathing apparatus and full protective clothing must

be worn in case of fire.

Unusual Fire & Explosion Hazards: None known.

Hazardous Combustion Products: Carbon Oxides, Nitrogen Oxides

6 ACCIDE NTAL RELEASE MEASURES

Personal Precautions: Wear appropriate personal protective equipment.

Spill Cleanup Methods: Absorb spill with vermiculite or other inert material, then place in a container for

chemical waste. Large Spillages: Flush area with water. Prevent runoff from entering drains, sewers, or

streams. Dike for later disposal.

Environmental Precautions: Avoid discharge into drains, water courses or onto the ground.

7 HANDLING AND STORAGE

Handling: Avoid breathing mist or vapor. Do not get in eyes, on skin, on clothing. Do not taste orExperimental Imidazolines

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swallow. Use only with adequate ventilation. Wash thoroughly after handling.

Storage: Store away from incompatible materials.

8 EXPOSURE CONTROLS / PERSONAL P ROTECTION

Exposure Limits:

Chemical Name Source Type Exposure Limits Notes

Glycerin (Mist.) CA. Alberta OELs TWA 10 mg/m3

Glycerin (Mist.) CA. British Columbia

OELs TWA 10 mg/m3

Glycerin (Respirable mist) CA. British Columbia

OELs TWA 3 mg/m 3

Glycerin (Mist.) CA. Ontario OELs TWA 10 mg/m3

Glycerin (Mist.) MEX. OELs TWA 10 mg/m3

Glycerin (Mist.) US. ACGIH TLV TWA 10 mg/m3

Glycerin (Respirable fraction.) US. OSHA Z

- 1 PEL TWA 5 mg/m3

Engineering Controls: Good general ventilation (typically 10 air changes per hour) should be used.

Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust

ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.

If exposure limits have not been established, maintain airborne levels to an acceptable level.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below

recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure

limits have not been established), an approved respirator must be worn. In the United States of America, if

respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152,

January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved

(where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or

manufacturer for specific information.

Eye Protection: Wear safety glasses with side shields (or goggles) and a face shield. Wear a full-face

respirator, if needed.

Hand Protection: Wear chemical-resistant gloves. Contact glove manufacturer for specific information.

Skin Protection: Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the

material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective

equipment to remove contaminants.

Environmental Exposure Controls: Environmental manager must be informed of all major spillages.

9 PHYSICAL AND CHEMICAL PROPERTIES

Color: Brown

Odor: No data available.

Odor Threshold: No data available.

Physical State: Liquid to solid

pH: 11.5Experimental Imidazolines 7-May-2013

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Freezing Point: No data available.

Boiling Point: No data available.

Flash Point: >200°C (392°F) (Open Cup)

Evaporation Rate: No data available.

Flammability (Solid): No data available.

Flammability Limit - Upper (%): No data available.

Flammability Limit - Lower (%): No data available.

Vapor Pressure: No data available.

Vapor Density (Air=1): No data available.

Specific Gravity: 0.91 - 0.95 (25°C)

Solubility in Water: No data available.

Solubility (Other): No data available.

Partition Coefficient (n-Octanol/water): No data available.

Autoignition Temperature: No data available.

Decomposition Temperature: No data available.

Viscosity: 455 cps @25°C

Explosive Properties: No data available

10 STABILITY AND REACTIVITY

Stability: Stable under the prescribed storage conditions.

Conditions to Avoid: Excessive heat.

Incompatible Materials: Acids. Oxidizing materials.

Hazardous Decomposition Products: No data available.

Possibility of Hazardous Reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Specified Substance(s)

Acute Toxicity:

Test Results: No test data available for the ingredients.

Listed Carcinogens: None.

Product Information

Acute Toxicity:

Test Results: No test data available for the product.

Other Acute: Causes skin and eye burns. Mist or vapor irritating to eyes and respiratory tract. The

toxicological properties of this product have not been thoroughly investigated. Use appropriate

precautions.

Chronic Toxicity: No additional adverse health effects noted.Experimental Imidazolines

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12 ECOLOGICAL INFORMATION

Ecotoxicity: Harmful effect due to pH shift. No data available.

Mobility: No data available.

Persistence and Degradability: No data available.

Other Adverse Effects: No data available.

13 DISPOSAL CONSIDERATIONS

General Information: Do not discharge into drains, water courses or onto the ground. Discharge,

treatment, or disposal may be subject to national, state, or local laws. Empty containers may contain

product residues.

Disposal Methods: No specific disposal method required.

Container: Since emptied containers retain product residue, follow label warnings even after container is

emptied.

14 TRANSPORT INFORMATION

DOT

UN No.: UN3267

Proper Shipping Name: Corrosive liquid, basic, organic, n.o.s. (Imidazoline)

Class: 8

Packing Group: III

Label(s): 8

TDG

UN No.: UN3267

Proper Shipping Name: Corrosive liquid, basic, organic, n.o.s. (Imidazoline)

Class: 8

Packing Group: III

IATA

UN No.: UN3267

Proper Shipping Name: Corrosive liquid, basic, organic, n.o.s. (Imidazoline)

Class: 8

Packing Group: III

Label(s): 8

IMDG

UN No.: UN3267

Proper Shipping Name: Corrosive liquid, basic, organic, n.o.s. (Imidazoline)

Class: 8

Packing Group: III

EmS No.: F-A, S-BExperimental Imidazolines

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15 REGULATORY INFORMATION

Canadian Controlled Products Regulations: This product has been classified according to the hazard

criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required

information.

WHMIS Classification: D2B, E

Mexican Dangerous Statement: This product is dangerous according to Mexican regulations.

Inventory Status

This product or one or more component(s) are not listed on the following inventory: TSCA

US Regulations

CERCLA Hazardous Substance List (40 CFR 302.4): Not regulated.

SARA Title III

Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Not regulated.

Section 311/312 (40 CFR 370):

X Acute (Immediate) Chronic (Delayed) Fire Reactive Pressure Generating

Section 313 Toxic Release Inventory (40 CFR 372): Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):

Not regulated.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Not regulated.

Drug Enforcement Act: Not regulated.

TSCA

TSCA Section 4(a) Final Test Rules & Testing Consent Orders: Not regulated.

TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) (40CFR 721, Subpt. E): Not

regulated.

TSCA Section 5(e) PMN-Substance Consent Orders: Not regulated.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated.

State Regulations

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): Not regulated.

Massachusetts Right- To -Know List: Glycerin

Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection ActExperimental Imidazolines

NORTH AMERICAN MSDS 7 / 7 (Act. 451 of 1994)): Not regulated.

Minnesota Hazardous Substances List: Glycerin

New Jersey Right- To -Know List: Not regulated.

Pennsylvania Right- To -Know List: Glycerin

Rhode Island Right- To -Know List: Glycerin

16 OTHER INFORMATION

HAZARD RATINGS

Health Hazard Fire Hazard Instability Special Hazard

NFPA 3 1 0 NONE

Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe

NFPA Label colored diamond code: Blue - Health; Red - Flammability; Yellow - Instability; White - Special Hazards

Health Hazard Flammability Physical Hazard Personal Protection

HMIS 3 1 0

-- Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe

HMIS Label colored bar code: Blue - Health; Red - Flammability; Orange - Physical Hazards; White - Special

Disclaimer: To t he best of our knowledge, the information contained herein is accurate. However, neither

the above named supplier nor any of its subsidiaries assumes any liability whatsoever or completeness of

the information contained herein. Final determination of suitability of any material is the sole responsibility

of the user. All materials may present unknown hazards and should be used with caution. Although certain

hazards are described herein, we cannot guarantee that these are the only hazards that exist.