### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report 

# Analytical Laboratory

Order Number: J12110225 Project Name: Flex Fuel Absorber 2

Lab Contact: Jason C Perkins 

## Date: 12/14/2012 Customer Address: 3195 Pine Hall Rd Customer Name(s): Bill Kennedy, Wayne Chapman

Mailcode: Belews Steam Station Belews Creek, NC 28012

Phone: 980-875-5348 Report Authorized By: (Signature)


### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

# Sample ID's & Descriptions:

Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2012024420 BELEWS 12-Nov-12 5:40 AM W. Chapman 2A ABS PRIM CLASS FEED LIQ 2012024421 BELEWS 12-Nov-12 5:40 AM W. Chapman 2A ABS PRIM CLASS FEED SOL 2012024422 BELEWS 12-Nov-12 5:50 AM W. Chapman 2B ABS PRIM CLASS FEED LIQ 2012024423 BELEWS 12-Nov-12 5:50 AM W. Chapman 2B ABS PRIM CLASS FEED SOL 2012024424 BELEWS 12-Nov-12 4:50 AM W. Chapman GYPSUM CAKE BELT 2012024425 BELEWS 12-Nov-12 5:55 AM W. Chapman 2A ABS PURGE LIQUIDS 2012024426 BELEWS 12-Nov-12 5:55 AM W. Chapman 2A ABS PURGE SOLIDS 7 Total Samples

### COC and .pdf report are in agreement with sample totals

and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No



# Technical Validation Review Checklist:

Yes No

Yes No



# Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### DBA Account Date: 

### 12/14/2012 Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024420 Collection Date: 12-Nov-12 5:40 AM 

## Site: 2A ABS PRIM CLASS FEED LIQ Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF ALKALINITY - (Analysis Performed by Prism Labs) Vendor Parameter Complete Vendor Method V_PRISM
INORGANIC IONS BY IC Bromide 110 mg/L EPA 300.0 11/19/2012 23:29 JAHERMA 5 50 Chloride 7300 mg/L EPA 300.0 11/19/2012 23:29 JAHERMA 100 1000 Fluoride 13 mg/L EPA 300.0 11/19/2012 23:29 JAHERMA 5 50 Sulfate 1700 mg/L EPA 300.0 11/19/2012 23:29 JAHERMA 100 1000 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 2.5 ug/L EPA 245.1 11/15/2012 14:32 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 188 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 0.5 10 Calcium (Ca) 3270 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 0.1 10 Iron (Fe) < 0.1 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 0.1 10 Magnesium (Mg) 789 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 0.05 10 Manganese (Mn) 7.33 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 0.05 10 Potassium (K) 24.8 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 1 10 Sodium (Na) 45.5 mg/L EPA 200.7 11/26/2012 10:52 MHH7131 0.5 10 TOTAL RECOVERABLE METALS BY ICP-MS Aluminum (Al) 294 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 20 10 Antimony (Sb) < 10 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Arsenic (As) < 10 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Beryllium (Be) < 10 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Chromium (Cr) < 10 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Cobalt (Co) 40.8 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Lead (Pb) < 10 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Nickel (Ni) 214 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Selenium (Se) 744 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 Strontium (Sr) 11400 ug/L EPA 200.8 11/27/2012 12:25 KRICHAR 10 10 SELENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Complete Vendor Method V_AS&C
TOTAL DISSOLVED SOLIDS TDS 18000 mg/L SM2540C 11/20/2012 15:27 SWILLI3 100 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024421 Collection Date: 12-Nov-12 5:40 AM 

## Site: 2A ABS PRIM CLASS FEED SOL Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF Dionex Analysis of Gypsum Leachate Bromide < 200 mg/kg CS-3612 M-2 12/10/2012 22:38 JAHERMA 200 20 Chloride 1700 mg/kg CS-3612 M-2 12/10/2012 22:38 JAHERMA 200 20 Fluoride 390 mg/kg CS-3612 M-2 12/10/2012 22:38 JAHERMA 200 20 Sulfate 130000 mg/kg CS-3612 M-2 12/10/2012 22:38 JAHERMA 2000 200 TOTAL METALS BY ICP Aluminum (Al) 1020 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Antimony (Sb) < 20 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 20 10 Arsenic (As) < 13.3 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 13.3 10 Beryllium (Be) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Boron (B) 49.3 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 33.3 10 Cadmium (Cd) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Calcium (Ca) 147000 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 6.67 10 Chromium (Cr) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Cobalt (Co) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Copper (Cu) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Iron (Fe) 1160 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 6.67 10 Lead (Pb) < 20 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 20 10 Magnesium (Mg) 704 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Manganese (Mn) 7.17 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Nickel (Ni) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 Potassium (K) 414 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 66.7 10 Selenium (Se) 49.9 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 20 10 Strontium (Sr) 88.2 mg/Kg EPA 6010b 12/03/2012 10:14 MHH7131 3.33 10 METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by SGS North America Inc.) Vendor Parameter Complete Vendor Method V_SGS



## 2012024422 Collection Date: 12-Nov-12 5:50 AM 

## Site: 2B ABS PRIM CLASS FEED LIQ Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF ALKALINITY - (Analysis Performed by Prism Labs) Vendor Parameter Complete Vendor Method V_PRISM
INORGANIC IONS BY IC Bromide 120 mg/L EPA 300.0 11/19/2012 23:48 JAHERMA 5 50 Chloride 8200 mg/L EPA 300.0 11/19/2012 23:48 JAHERMA 100 1000 Fluoride 12 mg/L EPA 300.0 11/19/2012 23:48 JAHERMA 5 50 Sulfate 1600 mg/L EPA 300.0 11/19/2012 23:48 JAHERMA 100 1000

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024422 Collection Date: 12-Nov-12 5:50 AM 

## Site: 2B ABS PRIM CLASS FEED LIQ Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 2.5 ug/L EPA 245.1 11/15/2012 14:35 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 207 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 0.5 10 Calcium (Ca) 3600 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 0.1 10 Iron (Fe) < 0.1 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 0.1 10 Magnesium (Mg) 855 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 0.05 10 Manganese (Mn) 8.16 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 0.05 10 Potassium (K) 26.3 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 1 10 Sodium (Na) 49.7 mg/L EPA 200.7 11/26/2012 10:56 MHH7131 0.5 10 TOTAL RECOVERABLE METALS BY ICP-MS Aluminum (Al) 273 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 20 10 Antimony (Sb) < 10 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Arsenic (As) < 10 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Beryllium (Be) < 10 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Chromium (Cr) < 10 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Cobalt (Co) 47.9 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Lead (Pb) < 10 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Nickel (Ni) 252 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Selenium (Se) 370 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 Strontium (Sr) 13000 ug/L EPA 200.8 11/27/2012 12:29 KRICHAR 10 10 SELENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Complete Vendor Method V_AS&C
TOTAL DISSOLVED SOLIDS TDS 19000 mg/L SM2540C 11/20/2012 15:27 SWILLI3 100 1



## 2012024423 Collection Date: 12-Nov-12 5:50 AM 

## Site: 2B ABS PRIM CLASS FEED SOL Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF Dionex Analysis of Gypsum Leachate Bromide < 200 mg/kg CS-3612 M-2 12/10/2012 23:16 JAHERMA 200 20 Chloride 870 mg/kg CS-3612 M-2 12/10/2012 23:16 JAHERMA 200 20 Fluoride 390 mg/kg CS-3612 M-2 12/10/2012 23:16 JAHERMA 200 20 Sulfate 130000 mg/kg CS-3612 M-2 12/10/2012 23:16 JAHERMA 2000 200

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024423 Collection Date: 12-Nov-12 5:50 AM 

## Site: 2B ABS PRIM CLASS FEED SOL Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF TOTAL METALS BY ICP Aluminum (Al) 943 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Antimony (Sb) < 20 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 20 10 Arsenic (As) < 13.3 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 13.3 10 Beryllium (Be) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Boron (B) < 33.3 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 33.3 10 Cadmium (Cd) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Calcium (Ca) 139000 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 6.67 10 Chromium (Cr) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Cobalt (Co) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Copper (Cu) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Iron (Fe) 1060 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 6.67 10 Lead (Pb) < 20 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 20 10 Magnesium (Mg) 428 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Manganese (Mn) 5.54 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Nickel (Ni) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 Potassium (K) 368 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 66.7 10 Selenium (Se) 62.5 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 20 10 Strontium (Sr) 80.5 mg/Kg EPA 6010b 12/03/2012 10:18 MHH7131 3.33 10 METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by SGS North America Inc.) Vendor Parameter Complete Vendor Method V_SGS



## 2012024424 Collection Date: 12-Nov-12 4:50 AM 

## Site: GYPSUM CAKE BELT Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF Dionex Analysis of Gypsum Leachate Bromide < 200 mg/kg CS-3612 M-2 12/10/2012 23:35 JAHERMA 200 20 Chloride < 200 mg/kg CS-3612 M-2 12/10/2012 23:35 JAHERMA 200 20 Fluoride 270 mg/kg CS-3612 M-2 12/10/2012 23:35 JAHERMA 200 20 Sulfate 130000 mg/kg CS-3612 M-2 12/10/2012 23:35 JAHERMA 2000 200

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024424 Collection Date: 12-Nov-12 4:50 AM 

## Site: GYPSUM CAKE BELT Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF TOTAL METALS BY ICP Aluminum (Al) 532 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Antimony (Sb) < 20 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 20 10 Arsenic (As) < 13.3 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 13.3 10 Beryllium (Be) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Boron (B) < 33.3 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 33.3 10 Cadmium (Cd) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Calcium (Ca) 159000 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 6.67 10 Chromium (Cr) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Cobalt (Co) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Copper (Cu) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Iron (Fe) 611 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 6.67 10 Lead (Pb) < 20 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 20 10 Magnesium (Mg) 310 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Manganese (Mn) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Nickel (Ni) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 Potassium (K) 186 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 66.7 10 Selenium (Se) 29.3 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 20 10 Strontium (Sr) 90.4 mg/Kg EPA 6010b 12/03/2012 10:22 MHH7131 3.33 10 METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by SGS North America Inc.) Vendor Parameter Complete Vendor Method V_SGS


## 2012024425 Collection Date: 12-Nov-12 5:55 AM 

## Site: 2A ABS PURGE LIQUIDS Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF ALKALINITY - (Analysis Performed by Prism Labs) Vendor Parameter Complete Vendor Method V_PRISM
INORGANIC IONS BY IC Bromide 120 mg/L EPA 300.0 11/20/2012 00:07 JAHERMA 5 50 Chloride 8400 mg/L EPA 300.0 11/20/2012 00:07 JAHERMA 100 1000 Fluoride 9.0 mg/L EPA 300.0 11/20/2012 00:07 JAHERMA 5 50 Sulfate 1500 mg/L EPA 300.0 11/20/2012 00:07 JAHERMA 100 1000 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 2.5 ug/L EPA 245.1 11/15/2012 14:42 AGIBBS 2.5 50

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024425 Collection Date: 12-Nov-12 5:55 AM 

## Site: 2A ABS PURGE LIQUIDS Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF TOTAL RECOVERABLE METALS BY ICP Boron (B) 201 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 0.5 10 Calcium (Ca) 3640 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 0.1 10 Iron (Fe) < 0.1 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 0.1 10 Magnesium (Mg) 879 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 0.05 10 Manganese (Mn) 8.32 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 0.05 10 Potassium (K) 27.7 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 1 10 Sodium (Na) 50.9 mg/L EPA 200.7 11/26/2012 11:00 MHH7131 0.5 10 TOTAL RECOVERABLE METALS BY ICP-MS Aluminum (Al) 28.1 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 20 10 Antimony (Sb) < 10 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Arsenic (As) < 10 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Beryllium (Be) < 10 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Chromium (Cr) < 10 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Cobalt (Co) 46.1 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Lead (Pb) < 10 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Nickel (Ni) 279 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Selenium (Se) 152 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 Strontium (Sr) 13100 ug/L EPA 200.8 11/27/2012 12:32 KRICHAR 10 10 SELENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Complete Vendor Method V_AS&C
TOTAL DISSOLVED SOLIDS TDS 20000 mg/L SM2540C 11/20/2012 15:27 SWILLI3 100 1 TOTAL SUSPENDED SOLIDS TSS 2900 mg/L SM2540D 11/19/2012 10:27 SWILLI3 250 1



## 2012024426 Collection Date: 12-Nov-12 5:55 AM 

## Site: 2A ABS PURGE SOLIDS Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF Dionex Analysis of Gypsum Leachate Bromide < 200 mg/kg CS-3612 M-2 12/10/2012 23:54 JAHERMA 200 20 Chloride 1300 mg/kg CS-3612 M-2 12/10/2012 23:54 JAHERMA 200 20 Fluoride 410 mg/kg CS-3612 M-2 12/10/2012 23:54 JAHERMA 200 20 Sulfate 130000 mg/kg CS-3612 M-2 12/10/2012 23:54 JAHERMA 2000 200

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12110225

2012024426 Collection Date: 12-Nov-12 5:55 AM 

## Site: 2A ABS PURGE SOLIDS Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF TOTAL METALS BY ICP Aluminum (Al) 3430 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Antimony (Sb) < 20 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 20 10 Arsenic (As) < 13.3 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 13.3 10 Beryllium (Be) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Boron (B) 48.7 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 33.3 10 Cadmium (Cd) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Calcium (Ca) 167000 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 6.67 10 Chromium (Cr) 9.69 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Cobalt (Co) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Copper (Cu) < 3.33 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Iron (Fe) 3830 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 6.67 10 Lead (Pb) < 20 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 20 10 Magnesium (Mg) 1490 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Manganese (Mn) 21.3 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Nickel (Ni) 3.72 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 Potassium (K) 1430 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 66.7 10 Selenium (Se) 204 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 20 10 Strontium (Sr) 98.5 mg/Kg EPA 6010b 12/03/2012 10:26 MHH7131 3.33 10 METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by SGS North America Inc.) Vendor Parameter Complete Vendor Method V_SGS

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 11/27/2012

Duke Energy Corporation (04) Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Belews Creek (Flex Fuel 2) Absorber 2 Project No.: J12110225 Lab Submittal Date: 11/13/2012 Prism Work Order: 2110306 VA Certification No. 1287 DoD ELAP Certification No. L2307



### This is a Revised Report and supercedes the original laboratory report dated 11/21/12. The project number (order #) was incorrect. 

## Narrative Notes:

Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference: 

### HT Sample received and analyzed outside of the hold time.

Method Detection Limit MDL Below Reporting Limit BRL
Relative Percent Difference RPD


## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 8

# Sample Receipt Summary 11/27/2012 

## Prism Work Order: 2110306 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 2110306-01 11/12/12 2012024420/2A Abs. Primary Class Feed -- Liquid 11/13/12 Water 2110306-02 11/12/12 2012024422/2B Abs. Primary Class Feed -- Liquid 11/13/12 Water 2110306-03 11/12/12 2012024425/#2 Abs. Purge -- Liquid 11/13/12 Water
Samples received in good condition at 1.2 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 8

# Laboratory Report 11/27/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Belews Creek (Flex Fuel 2) Absorber 2 Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2110306-01 Prism Work Order: 2110306 Time Collected: 11/12/12 05:40 Time Submitted: 11/13/12 17:30 2012024420/2A Abs. Primary Cla


### J12110225

General Chemistry Parameters 6.8 *SM4500-H B P2K0366 1 11/17/12 8:30 JAB HT pH Units pH 47 *SM2320 B P2K0382 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2K0384 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Carbonate Alkalinity 47 *SM2320 B P2K0385 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 8

# Laboratory Report 11/27/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Belews Creek (Flex Fuel 2) Absorber 2 Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2110306-02 Prism Work Order: 2110306 Time Collected: 11/12/12 05:50 Time Submitted: 11/13/12 17:30 2012024422/2B Abs. Primary Cla


### J12110225

General Chemistry Parameters 6.1 *SM4500-H B P2K0366 1 11/17/12 8:30 JAB HT pH Units pH 43 *SM2320 B P2K0382 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2K0384 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Carbonate Alkalinity 43 *SM2320 B P2K0385 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 8

# Laboratory Report 11/27/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Belews Creek (Flex Fuel 2) Absorber 2 Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2110306-03 Prism Work Order: 2110306 Time Collected: 11/12/12 05:55 Time Submitted: 11/13/12 17:30 2012024425/#2 Abs. Purge -- Liq


### J12110225

General Chemistry Parameters 6.3 *SM4500-H B P2K0366 1 11/17/12 8:30 JAB HT pH Units pH 47 *SM2320 B P2K0382 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2K0384 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Carbonate Alkalinity 47 *SM2320 B P2K0385 1 5.0 11/19/12 10:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 5 of 8

### 11/27/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12110225 Project: Belews Creek (Flex Fuel 2) Absorber 2 Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2110306 Time Submitted: 11/13/2012 5:30:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2K0366 - NO PREP LCS (P2K0366-BS1) 

### Prepared & Analyzed: 11/17/12 pH pH Units 6.81 6.860 99-101 99 

### Batch P2K0382 - NO PREP Blank (P2K0382-BLK1) 

### Prepared & Analyzed: 11/19/12 Total Alkalinity mg/L BRL 5.0 LCS (P2K0382-BS1) 

### Prepared & Analyzed: 11/19/12 Total Alkalinity mg/L 246 5.0 250.0 90-110 99 LCS Dup (P2K0382-BSD1) 

### Prepared & Analyzed: 11/19/12 Total Alkalinity mg/L 246 5.0 250.0 200 90-110 99 0 

### Batch P2K0384 - NO PREP Blank (P2K0384-BLK1) 

### Prepared & Analyzed: 11/19/12 Carbonate Alkalinity mg/L BRL 5.0 

### Batch P2K0385 - NO PREP Blank (P2K0385-BLK1) 

### Prepared & Analyzed: 11/19/12 Bicarbonate Alkalinity mg/L BRL 5.0 LCS (P2K0385-BS1) 

### Prepared & Analyzed: 11/19/12 Bicarbonate Alkalinity mg/L 246 5.0 250.0 90-110 99

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 6 of 8

### 11/27/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12110225 Project: Belews Creek (Flex Fuel 2) Absorber 2 Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2110306 Time Submitted: 11/13/2012 5:30:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2K0385 - NO PREP LCS Dup (P2K0385-BSD1) 

### Prepared & Analyzed: 11/19/12 Bicarbonate Alkalinity mg/L 246 5.0 250.0 200 90-110 99 0

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 7 of 8

## Page 8 of 8

# November 26, 2012

Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5245 Project:Belews CreeK (Flex Fuel 2) Absorber 2 (LIMS #J12110225)

Dear Mr.Perkins, Attached is the report associated with three (3) aqueous samples submitted for selenium speciation on November 13, 2012.The samples were received in a sealed coolerat-0.3°C on November 14, 2012

.Selenium speciation analysis was performed via ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS). Any issuesassociated with the analysis are addressed in the following report. If you have any questions, please feel free to contact me at your convenience.
Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

# Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 Project:Belews CreeK (Flex Fuel 2) Absorber 2 (LIMS #J12110225)

November26, 2012

1. Sample Reception Three (3) aqueous samples in125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for selenium speciation analysis on November 13, 2012. The sampleswere received on November14, 2012in a sealed container at -0.3°C. The samples were received in a laminar flow clean hood,void of trace metals contamination and ultra-violet radiation, and were designated discrete sample identifiers. An aliquot of each sample was filtered (0.45μm) and each filtrate wasstored in a secure, monitored cryofreezer (maintained at a temperature of -80o

# C) until selenium speciation analysis could be performed via ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All applied water for dilutions and sample preservatives are monitored for contamination to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-DRC

-MS Prior to analysis, an aliquot of each sample was filtered with a syringe filter (0.45μm) and injected directly into an autosampler vial. No further sample preparation was performed as any chemical alteration ofasample mayshift the equilibrium of the system,resulting in changes in speciation ratios.

3. Sample Analysis All sample analysis is preceded by a minimum of a five-point calibration curve spanning the entire concentration range of interest. Calibration curves are performed at the beginning of

# each analytical day. All calibration curves, associated with each species of interest, are

standardized by linear regression resulting in a response factor. All sample results are instrument blank correctedto account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are verified using second source standards which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is identified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimum interval of every ten analytical runs. Selenium Speciation Analysis by IC-ICP-DRC

-MS Eachsample for selenium speciation analysis wasanalyzed by ion chromatography inductively coupled plasmadynamic reaction cell mass spectrometry (IC-ICP-DRC-MS) on November 19, 2012

. Analiquot of each sample isinjected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy-transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber (DRC) containing a reaction gas which preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.

4. Analytical Issues The overall analyses went well and no significant analytical issues were encountered. The selenocyanate matrix spike and matrix spike duplicate sample recoveries (35.8% and 39.5%, respectively) were below the lower control limit of 75%. The spiking solution also contained selenite, and the spike recoveries for selenite (169.0% and 167.1%, respectively) were greater than the upper control limit of 125%. An acceptable mass balance of selenium species was obtained; the sum of species was calculated in each case yielding values of 103.6% and 104.6%. The apparent conversion of selenocyanate to selenite is indicative of an oxidizing matrix in the samples. Selenium species conversion was not observed in the bracketing continuing calibration verification standards (CCV), demonstrating adequate stability of selenium species within the analytical platform. No corrective actions were required. All other quality control parameters associated with the samples were within acceptance limits.

# The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are

generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium species are present in preparation blanks; therefore, eMDL calculations based on preparation blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species. If you have any questions or concerns regarding this report, please feel free to contact me. Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

### Sample Results

Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe Unknown Se Species (n) 2A Abs. Primary Class Feed -- Liquid 435 57.1 ND (<1.9) 3.3 ND (<1.6) 0.0 (0) 2B Abs. Primary Class Feed -- Liquid 225 55.4 ND (<1.9) 5.7 ND (<1.6) 0.0 (0) #2 Abs. Purge-- Liquid 23.9 73.8 ND (<1.9) 3.5 ND (<1.6) 0.0 (0) All results reflect the applied dilution and are reported in μg/L ND = Not detected at the applied dilution SeCN = Selenocyanate MeSe(IV) = Methylseleninic acid SeMe = Selenomethionine Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS Report Generated by: Russell Gerads Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Belews CreeK (Flex Fuel 2) Absorber 2

Contact: Jay Perkins

Date: November 26, 2012 LIMS #J12110225

## Quality Control Summary - Preparation Blank Summary

Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 200x Se(IV) 0.00 0.000 0.000 0.000 0.000 0.000 0.0050 1.0 Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.0091 1.8 SeCN 0.00 0.000 0.000 0.000 0.000 0.000 0.0097 1.9 MeSe(IV) 0.00 0.000 0.000 0.000 0.000 0.000 0.0079 1.6 SeMe 0.00 0.000 0.000 0.000 0.000 0.000 0.0079 1.6 eMDL = Estimated Method Detection Limit *Please see narrative regarding eMDL calculations
Quality Control Summary - Certified Reference Materials Analyte (μg/L) CRM True Value Result Recovery Se(IV) LCS 9.57 9.74 101.8 Se(VI) LCS 9.48 9.48 100.1 SeCN LCS 8.92 8.98 100.6 MeSe(IV) LCS 6.47 6.43 99.3 SeMe LCS 9.32 9.09 97.5 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Belews CreeK (Flex Fuel 2) Absorber 2

Contact: Jay Perkins LIMS #J12110225 Date: November 26, 2012 Report Generated by: Russell Gerads

## Quality Control Summary - Matrix Duplicates

Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD Se(IV) #2 Abs. Purge-- Liquid 23.9 20.9 22.4 13.4 Se(VI) #2 Abs. Purge-- Liquid 73.8 72.2 73.0 2.1 SeCN #2 Abs. Purge-- Liquid ND (<1.9) ND (<1.9) NC NC MeSe(IV) #2 Abs. Purge-- Liquid 3.5 3.3 3.4 5.5 SeMe #2 Abs. Purge-- Liquid ND (<1.6) ND (<1.6) NC NC ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL

Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD Se(IV) #2 Abs. Purge-- Liquid 1112 1902 169.0 * 1112 1880 167.1 * 1.1 Se(VI) #2 Abs. Purge-- Liquid 1009 1142 106.0 1009 1155 107.3 1.2 SeCN #2 Abs. Purge-- Liquid 915.0 327.2 35.8 * 915.0 361.5 39.5 * 10.0 *Low/high recovery is attributed to matrix induced species conversion Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Belews CreeK (Flex Fuel 2) Absorber 2

Contact: Jay Perkins LIMS #J12110225 Date: November 26, 2012 Report Generated by: Russell Gerads