Page 1 of 9 Revision date 06/11/2008 

# Material Safety Data Sheet

1. PRODUCT AND COMPA NY IDENTIFICATION

CR 842D

Revision date: 06/11/2008

Supplier ROHM AND HAAS CANADA LP

A Subsidiary of The Dow Chemical Company

2 MANSE ROAD

WEST HILL

, ON M1E 3T9 Canada

For non

- emergency information contact: 416

- 284

- 4711

Fax: 416

- 287

- 4495

For non

- emergency information contact: 215

- 592

- 3000

Emergency telephone number

989

- 636

- 4400

Local emergency telephone number

989

- 636

- 4400



### 2. COMPOSITION/INFOR MATION ON INGREDIENT S

Component CAS

- No. Concentration

Polymeric isocyanate Not Hazardous 46.0

- 48.0%

Ethyl acetate 141

- 78

- 6 27.0

- 29.0%

1,6

- diisocyanatohexane, homopolymer 28182

- 81

- 2 24.0

- 26.0%

Natural oil Not Hazardous 1.0

- 3.0%

Isophorone diisocyanate 4098

- 71

- 9 < 0.3%



### 3. HAZARDS IDENTIFIC ATION

Emergency Overview



### Appearance

Form liquid

Form clear

Colour colorless to pale yellowCR 842D

Page 2 of 9 Revision date 06/11/2008 Odour solvent



### Hazard Summary WARNING !

FLAMMABLE LIQUID AND VAPOR.

INHALATION OF VAPOR OR MIST CAN CAUSE TH E

FOLLOWING:

SHORTNESS OF BREATH

TIGHTNESS IN THE CHE ST

IRRITATING TO EYES A ND SKIN.

MAY CAUSE SENSITIZAT ION BY INHALATION AN D SKIN

CONTACT.

CLOSED CONTAINERS MA Y EXPLODE WHEN HEATE D OR

CONTENTS CONTAMINATE D WITH WATER.

PROLONGED OR REPEATE D OVEREXPOSURE TO TH E

SOLVENT (S) IN THIS MATERIAL CAN CAUSE THE FOLLOW ING:

KIDNEY DAMAGE

LIVER DAMAGE

HEART DAMAGE

CENTRAL NERVOUS SYST EM (CNS) EFFECTS

BLOOD CHANGES

LUNG DAMAGE

Potential Health Effects

Primary Routes of Entry: Eye contact

Inhalation

Skin contact

Eyes: Material can cause the following:

Moderate irritation.

burning sensation

tearing

reddening

Skin: May cause sensitization by skin contact.

Material can cause the following:

Moderate irritation.

burning sensation

reddening

Itching

Ingestion: Material can c ause the following:

severe irritation of the mouth, throat, and digestive tract

diarrhea

nausea

Vomiting

Abdominal pain

Inhalation: Inhalation of vapor or mist can cause the following:

coughing

irritation of nose, throat, and lungs

tightness in the chest

Shortness of breath

May cause severe allergic respiratory reaction.

SensitisationCR 842D

Page 3 of 9 Revision date 06/11/2008 Chronic Exposure: Long term exposure to diisocyanates may cause lung damage, including reduced

lung function, which may be permanent.

Prolonged or repeated overexposure to t he solvent(s) in this material can cause the following:

heart damage

Blood changes

central nervous system (CNS) effects

kidney damage

liver damage

lung damage



### 4. FIRST AID MEASURE S

Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Call

a physician immediately.

Skin contact: Take off all contaminated clothing immediately. Wash off immediately with soap and

plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re

- use.

Eye contact: Flush eyes with water as a precaution. If eye irritation persists, consult a specialist.

Ingestion: Never give anything by mouth to an unconscious person. If a person vomits when lying on

his back, place him in the recovery position. Do NOT induce vomiting. Rinse mouth. Immediately

give large quantities of water to drink. Call a physician immediately.

Notes to physician: Bronchial constriction may develop after extensive exposure t o isocyanates,

even in individuals who have not been shown to be previously sensitized.



### 5. FIRE

- FIGHTING MEASURES

Flash point 5 °C ( 41 °F )

Lower explosion limit no data available

Upper explosion limit no data available

Thermal decomposition Heating or fire conditions liberates toxic gas.

Combustion Products: Hydrogen Cyanide

Carbon monoxide

Carbon dioxide

Nitrogen oxide (NO2)

Suitable extinguishing media: Foam

Carbon dioxide (CO2)

Dry powder

Specific hazards during fire fighting: Vapors can travel to a source of ignition and flash back.

Heated material can form flammable or explosive vapors with air. Closed containers may rupture via

pressure build

- up when exposed to fire or extreme heat.

S pecial protective equipment for fire

- fighters: Wear self

- contained breathing apparatus and

protective suit.

Further information: For safety reasons in case of fire, containers should be stored separately in

closed containments.

Cool closed containers expo sed to fire with water spray.

EXPLOSION HAZARD. Fight advanced fires from a protected location.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local

regulations.CR 842D

Page 4 of 9 Revision date 06/11/2008 

### 6. ACCIDENTAL RELEAS E MEASURES

Personal precautions

Use personal protective equipment.

Refer to protective measures listed in sections 7 and 8.

MATERIAL IS A POTENTIAL SENSITIZER.

If exposed to material during clean

- up operations, IMMEDIATELY remove all contaminated clothing

and wash exposed skin areas with soap and water. See SECTION 4, Fir st Aid Measures, for further

information.



### Environmental precautions

Do not flush into surface water or sanitary sewer system.



### Methods for cleaning up

Evacuate personnel to safe areas.

Remove all sources of ignition.

Ensure adequate ventilation.

Contain s pillage, and then collect with non

- combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for disposal according to local / national

regulations (see section 13).



### 7. HANDLING AND STOR AGE

Handling

Provide sufficient air exchange and/or exhaust in work rooms. Avoid exceeding of the given

occupational exposure limits (see section 8). In case of insufficient ventilation, wear suitable

respiratory equipment. Do not breathe vapours or spray mist. Wear perso nal protective equipment.

For personal protection see section 8. Keep away from heat and sources of ignition. Take necessary

action to avoid static electricity discharge (which might cause ignition of organic vapours). Ensure all

equipment is electrica lly grounded before beginning transfer operations. May cause sensitization of

susceptible persons by skin contact. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since

emptied containers retain product residue follow all MSDS and label warnings even after cont ainer is

emptied.



### Storage

Storage conditions: Material can burn; limit indoor storage to approved areas equipped with

automatic sprinklers. Keep container tightly closed in a dry and well

- ventilated place. Keep away from

heat and sources of ignition. E lectrical installations / working materials must comply with the

technological safety standards.



### 8. EXPOSURE CONTROLS /PERSONAL PROTECTION

Exposure limit(s)

Exposure limits are listed below, if they exist.

Component Regulation Type of listing Value

Ethy l acetate Rohm and Haas TWA 150 ppm

Rohm and Haas STEL 300 ppm

ACGIH TWA 400 ppm

NIOSH/GUIDE REL 1,400 mg/m3 400 ppm

OSHA_TRANS PEL 1,400 mg/m3 400 ppm

Z1A TWA 1,400 mg/m3 400 ppm

Component Regulation Type of listing Value

1,6

- d iisocyanatohexane,

homopolymer Rohm and Haas TWA 0.1 mg/m3

Rohm and Haas STEL 0.3 mg/m3

Component Regulation Type of listing ValueCR 842D

Page 5 of 9 Revision date 06/11/2008 Isophorone diisocyanate Rohm and Haas TWA 0.005 ppm

Rohm and Haas STEL 0.02 ppm

ACGIH TWA 0.005 ppm

NIOSH/GUIDE REL 0.045 mg/m3 0.005

ppm

NIOSH/GUIDE STEL 0.180 mg/m3 0.02 ppm

NIOSH/GUIDE SKIN_DES

Z1A TWA 0.005 ppm

Z1A STEL 0.02 ppm

Z1A SKIN_FINAL

TX ESL ST ESL 0.05 ppm

TX ESL AN ESL 0.005 ppm

TX ESL

Eye protection: Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent).

Eye protection worn must be compatible with respiratory protection system employed.

Hand protection: Chemical

- resistant gloves should be worn whenever this mater ial is handled. The

glove(s) listed below may provide protection against permeation. (Gloves of other chemically resistant

materials may not provide adequate protection): 4H Glove (Trademark of Safety 4 A/S of Denmark)

butyl

- rubber Gloves should be rem oved and replaced immediately if there is any indication of

degradation or chemical breakthrough. Before removing gloves clean them with soap and water.

NOTE: Material is a possible skin sensitizer.

Skin and body protection: Complete suit protecting aga inst chemicals Safety shoes

Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2

requirements or equivalent must be followed whenever workplace conditions warrant a respirator ‟ s

use. None required if airborne con centrations are maintained below the exposure limit listed in

Exposure Limit Information. Above the exposure limit: Wear a properly fitted NIOSH approved (or

equivalent) self

- contained breathing apparatus in the pressure demand mode, OR full

- facepiece,

a irline respirator in the pressure demand mode with emergency escape provision.

Hygiene measures: Wash hands before breaks and immediately after handling the product.

Protective measures: Facilities storing or utilizing this material should be equipped wi th an eyewash

facility and a safety shower.



### Engineering measures: Use explosion

- proof local exhaust ventilation with a minimum capture

velocity of 100 ft/min (0.5 m/sec) at the point of vapor evolution. Refer to the current edition of

Industrial Ventilat ion: A Manual of Recommended Practice published by the American Conference of

Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of

exhaust systems.



### 9. PHYSICAL AND CHEM ICAL PROPERTIES

Appearance

Form liq uid

clear

Colour colorless to pale yellow

Odour solvent

pH not applicable

Boiling point/boiling range no data available

Flash point 5 °C ( 41 °F )

Lower explosion limit no data available

Upper explosion limit no data available

Vapour pressure no data available

Relative vapour density no data availableCR 842D

Page 6 of 9 Revision date 06/11/2008 Water solubility insoluble

Relative density 1.09

Viscosity, dynamic 100

- 700 mPa.s

Evaporation rate no data available

Percent volatility 24

- 26 %

NOTE: The physical data p resented above are typical values and should not be construed as a

specification.



### 10. STABILITY AND RE ACTIVITY

Hazardous reactions Stable under recommended storage conditions.

Avoid moisture.

Conditions to avoid Heat, flames and sparks. Exposure to w ater vapour.

Materials to avoid Strong oxidizing agents Water

Hazardous

decomposition

products Hydrogen Cyanide

Acetaldehyde

Isocyanate(s)

polymerization Hazardous polymerization will also occur if contaminated with the

following:

- water (m oisture)



### 11. TOXICOLOGICAL IN FORMATION

No toxicity data are available for this material.

Component: Ethyl acetate

Acute oral toxicity LD50 human 6,100 mg/kg

Component: Ethyl acetate

Acute oral toxicity LD50 rat 5,620 mg/kg

Component: Isophorone diisocyanate

Acute oral toxicity LD50 rat 4,825 mg/kg

Component: Isophorone diisocyanate

Acute inhalation

toxicity LC50 rat 0.67 mg/l

aerosol

Component: Isophorone diisocyanate

Acute dermal toxicity LD50 rat >7,000 mg/kg

Component: Isophorone diisocyanate

Skin irritation rabbit OECD Test Guideline 404 Corrosive

Component: Isophorone diisocyanateCR 842D

Page 7 of 9 Revision date 06/11/2008 Eye irritation rabbit OECD Test Guideline 405 Severe eye irritation

Component: Ethyl acetate

Mutagenicity

Overall, no consistent mutagenic activit y has been reported.



### 12. ECOLOGICAL INFOR MATION

There is no data available for this product.

Ethyl acetate

Ecotoxicity effects

Toxicity to fish LC50 Rainbow trout (Oncorhynchus mykiss) 96 h

484 mg/l

Toxicity to fish LC50 Fathead minnow (Pimephales p romelas) 96 h

230 mg/l

Toxicity to algae EC50 Algae 96 h

2,000 mg/l

Toxicity to aquatic

invertebrates EC50 Daphnia magna 48 h

717 mg/l



### 13. DISPOSAL CONSIDE RATIONS

Environmental precautions: Do not flush into surface water or sanitary sewer system.



### Disposal

Waste Classification: 40 CFR 261.20

- .24

- Characteristic Waste D001, 100 lbs.

When a decision is made to discard this material as supplied, it is classified as a RCRA hazardous

waste with the characteristic of ignitability.

For disposal, in cinerate this material at a facility that complies with local, state, and federal regulations.

(See 40 CFR 268)



### 14. TRANSPORT INFORM ATION



## DOT

Proper shipping name Resin solution

UN

- Number UN 1866

Class 3

Packing group II

Reportable Quantity Ethyl a cetate



## IMO/IMDG

Proper shipping name RESIN SOLUTION

UN

- Number UN 1866

Class 3

Packing group II

Transportation classifications may vary by container volume and may be influenced by regional or

country variations in regulationsCR 842D

Page 8 of 9 Revision date 06/11/2008 

### 15. REGULATORY INFOR M ATION

Workplace Classification

This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR

1910.1200).

This product is a „ controlled product ‟ under the Canadian Workplace Hazardous Materials Information

System (WHMIS).



### SARA TITLE III : Section 311/312 Categorizations (40CFR370): Fire Hazard

Acute Health Hazard

Chronic Health Hazard



### SARA TITLE III : Section 313 Information (40CFR372)

This product does not contain a chemical which is listed in Section 313 at or above de minimis

concentrations.



### CERCLA Information ( 40CFR302.4 )

This material is regulated under the Comprehensive Environmental Response, Compensation and

Liability Act (CERCLA)and the Superfund Amendments and Reauthorization Act (SARA) Title III

Section 304. This mater ial is or contains chemical(s) listed in 40 CFR Table 302.4 or nondesignated

RCRA ICR substance(s). (Nondesignated ICR substances apply to materials that will not be reused.)

The Reportable Quantity(s) (RQ) are listed below. Releases in excess of its repor table quantity must

be reported to the National Response Center (1

- 800

- 424

- 8802) and to the appropriate state and local

emergency response organizations.

See Section 13, Disposal Considerations, Subsection Disposal, for CERCLA classification.

CERCLA Compo nents: Ethyl acetate 141

- 78

- 6 5,000 lbs RQ



### US. Toxic Substances Control Act ( TSCA ) : All components of this product are in compliance

with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical

Substance Inventory.



### Pennsylvania

Any material listed as “ Not Hazardous ” in the CAS REG NO. column of SECTION 2,

Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the

Pennsylvania Worker and Community Right

- to

- Know Act.



### 16. OTHER INFORMATION

Hazard Rating



### Health Fire Reactivity

HMIS 2* 3 1

HMIS: * = Chronic Effects (See Hazards Identification)



### Legend

ACGIH American Conference of Governmental Industrial Hygienists

BAc Butyl acetate

OSHA Occupational Safety and Health Adminis tration

PEL Permissible Exposure Limit

STEL Short Term Exposure Limit (STEL):

TLV Threshold Limit Value

TWA Time Weighted Average (TWA):

| Bar denotes a revision from prior MSDS.CR 842D

Page 9 of 9 Revision date 06/11/2008 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information

and belief at the date of its publication. The information given is designed only as a guidance for safe

handling, use, processing, storage, transportation, disposal and release and is not to be considered a

warranty or q uality specification. The information relates only to the specific material designated and

may not be valid for such material used in combination with any other materials or in any process,

unless specified in the text.

Version: 1

. 1

Print Date: 11/09/2012

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