# Patent

## Title
System and method for carbon dioxide capture and sequestration from relatively high concentration CO2 mixtures

## Abstract

A system and method of reducing the net carbon dioxide footprint of an industrial process that generates power from the combustion of hydrocarbon fuels in which ambient air is admixed with up to 50% by volume of an effluent gas from the power generator of the industrial process, in order to substantially increase the CO2 concentration in the air prior to treatment. The treatment comprises adsorbing CO2 from the admixed ambient air utilizing a cooled, porous substrate-supported amine adsorbent, wherein the porous substrate initially contacts the mixed ambient air containing condensed water in its pores, which act as an intrinsic coolant with respect to the exothermic heat generated by the adsorption process. In addition, prior to regenerating the supported adsorbent, air pressure is substantially reduced in the sealed regeneration chamber and the low pressure chamber is placed in fluid connection with a higher pressure regeneration chamber containing steam and carbon dioxide, to preheat the sorbent to be regenerated and to quickly cool the regenerated sorbent prior to use for further CO2 adsorption.

## Background
This application is a division of U.S. patent application Ser. No. 13/886,207 filed on May 2, 2013, and claims the benefit or priority pursuant to 35 U.S.C. 119(e) from a U.S. Provisional Patent Application having Application No. 61/643,103 filed Apr. 30, 2010; from a U.S. Provisional Patent Application having Application No. 61/330,108 filed Apr. 30, 2010; from a U.S. Provisional Patent Application having Application No. 61/351,216 filed Jun. 3, 2010 and from a U.S. Provisional Patent Application having Application No. 61/443,061 filed Feb. 15, 2011, and from U.S. application Ser. No. 13/098,370, filed on Apr. 29, 2011, now U.S. Pat. No. 8,500,855.


BACKGROUND
The present invention relates to systems and methods for removing greenhouse gases from the atmosphere, and in particular to systems and methods for removing carbon dioxide from a stream of gas, including ambient air.
As a further improvement to the system described in U.S. application Ser. No. 13/098,370, filed on Apr. 29, 2011, a suitable system and process is presented that it is now recognized can be utilized for a broader range of use than disclosed in that earlier application, especially when further modified. The disclosure of that copending application is incorporated by reference herein as if repeated in full, as modified by the new disclosure presented herein.
There is much attention currently focused on trying to achieve three somewhat conflicting energy related objectives: 1) provide affordable energy for economic development; 2) achieve energy security; and 3) avoid the destructive climate change caused by global warming. However, there is no feasible way to avoid using fossil fuels during the rest of this century if we are to have the energy needed for economic prosperity and avoid energy shortfalls that could lead to conflict.
It is mostly undisputed by scientists that an increase in the amount of so-called greenhouse gases like carbon dioxide (methane and water vapor are the other major greenhouse gases) will increase the average temperature of the planet.
It is also clear that there is no solution that only reduces the ongoing human contributions to carbon dioxide emissions that can successfully remove the risk of climate change. Removing additional CO2 from the atmosphere is also necessary. With air extraction and the capability to increase or decrease the amount of carbon dioxide in the atmosphere, one can in principle compensate for other greenhouse gases like methane (both naturally occurring and from human activity) that can increase their concentrations and cause climate change.
Until the recent inventions by the present applicant, it was the generally accepted belief among experts in the field that it was not feasible to capture carbon dioxide directly from the atmosphere because of the low concentration of that compound. It was subsequently shown by the copending prior application that it was in fact practical and efficient to carry out such CO2 reductions under specified conditions.
It was shown that under ambient conditions CO2 can be efficiently extracted from the air using a suitable regenerable sorbent system and a low temperature stripping or regeneration process.
SUMMARY OF THE PRESENT INVENTION
The present invention provides further new and useful systems and methods for removing carbon dioxide from a mass of carbon dioxide laden air.
This invention has now been further improved by the discovery that the same low temperature system can also be applied to the capturing of CO2 from a mixture of gases having enhanced carbon dioxide concentration by admixing air with relatively concentrated CO2-containing, flue derived gases diluted with a predominant amount of ambient air; as a further surprise, this further improves efficiency. This can result in a CO2-negative system event for such otherwise “dirty” sources such as power plants, or refineries, or cement manufacturing plants. In such circumstances, it is usually preferable to pre-treat the flue gas to remove particulates and certain destructive compounds, such as sulfur and nitrogen oxide compounds, before contacting the carbon dioxide sorbent, for example where the gas is derived from the burning of coal.
Generally, with extraction directly from the atmosphere, and the capability to increase the concentration of carbon dioxide in the ambient air being treated, by admixing with a high CO2-content gas mixture, such as flue-originated gases, one can reduce previously existing CO2 concentrations, in the atmosphere, thus providing a combined carbon-negative process, and compensate for other greenhouse gases, such as methane, being added to the atmosphere that may otherwise increase their concentrations. It is now possible to thus reduce, or even reverse, climate change.
In our earlier work, it was realized that a highly efficient system for removing CO2 from the relatively low concentration in ambient air could be achieved without requiring significant energy use to regenerate the CO2-loaded sorbent, using saturated process steam. It has now been found that an improved result is obtained by utilizing an array of the relatively thin, large surface area, monolithic, porous substrate, as the support for the active sorbent sites, in tandem with each other. For such a system, substantial quantities of flue-originated gases can be mixed with the ambient air, to increase the concentration of CO2 in the air being treated, by an order of magnitude, and possibly even more, while continuing to improve upon the low temperature efficiency previously achieved for ambient air alone, by varying the conditions and operating in tandem with another monolith system.
In such an improved system, the tandem pairs are phased such that when one of the pair is completing being regenerated in its regeneration box, the second member is just entering its regeneration box. The second regeneration box is sealed, as described in the copending application and again below, and the trapped atmosphere is exhausted from the second regeneration box, to below 0.4 BarA, and preferably below 0.3 BarA and optimally down to between 0.1 and 0.2 BarA. The first regeneration box, which had also had its air exhausted, has been regenerated with saturated steam, which condensed within the pores of the monolith as the CO2 was stripped from the sorbent. When regeneration had reached its desired endpoint, the monolith contained hot, condensed water and the surrounding atmosphere in the sealed box, containing some steam vapor and remaining CO2, had been increased to at least about 0.7 BarA. The interiors of the two tandem regeneration boxes are then interconnected, so that there is a sharp, quick change in the pressures towards equalization; the hot condensed water in the first monolith is vaporized at the lower pressure, and when the vapor encounters the second monolith, that is warmed and some CO2 is released, while the vapor condenses on the second monolith; thus quickly cooling the first monolith and preparing it for movement out of the first Box and into contact with the CO2-laden gas mixture. This tandem operation is continued for all members of the array in order to achieve a substantially continuous treatment of the CO2-laden gas mixture, and continuously repeated.
It must be understood that a ‘porous substrate’ is one having open pores, where a gas or vapor can enter a pore at the front surface and exit from the rear surface, so that the gas or vapor can pass fully through the substrate thickness via the open pores. The thickness of the monolith is preferably at least an order of magnitude less than either of the dimensions of the monolith surface transverse to the direction of flow of the CO2-laden gas mixture to be treated.
The term “ambient air”, as used in this specification, means and includes unenclosed air under the conditions and concentrations of materials present in the atmosphere at a particular geographic location. The term “flue-originated gases” refers to gases containing a high concentration of CO2 and exiting from the combustion of carbon-containing materials, such as so-called fossil fuels, including gases which may have been pre-treated after exhausting from the point of combustion.
It has been found that this process is successful with almost any admixture with ambient air that comprises at least a predominant quantity of ambient air, by volume, to dilute the flue-originated gases. The flue-originated gases will greatly increase the concentration of CO2 in the mixture, as compared with the ambient air, and are fully mixed into the air by a system, for example, as shown in FIGS. 25 and 26 of the prior copending application, to form a substantially uniform, high CO2-content gas mixture.
The CO2 laden gas mixture, at ambient temperature, is treated by directing it through a sorbent structure comprising a relatively thin, high surface area, porous monolith, supporting active CO2-sorbent sites, that can bind (capture) CO2, and then regenerating the sorbent by causing the release of the sorbent CO2 from the sorbent, by treating the sorbent structure with low temperature, preferably saturated, process steam, at a temperature of not greater than about 120° C., and withdrawing the released CO2 (thereby effectively regenerating the sorbent structure) and obtaining high quality CO2. The sorbent preferably exothermically adsorbs the CO2 which allows for the relatively low temperature stripping of the CO2 from the sorbent.
In this application, the substrate structure preferably comprises an amine that binds to CO2, and which is carried by the substrate structure. The sorbent will be preferably held on the surfaces of the substrate, including the surfaces within the pores. It was previously thought that when carbon dioxide concentration was much above that of ambient air, the CO2 sorbent temperature would be too high due to the exothermic heat from the adsorption of the CO2, which would raise the temperature of the monolith. It is known that the effectiveness of the sorbent, in the presence of air, would be degraded, at such higher temperatures. It was expected the effectiveness for capturing CO2, would be diminished, and would require a higher temperature to regenerate the sorbent.
It is known that the fraction captured by adsorption depends upon the temperature of the exothermic sorbent, in a way given by its Langmuir isotherm; for the available primary amine sorbents. The isotherm is exponential with temperature, because of the adsorbent's high heat of reaction with CO2, i.e., about 84 kj/mole. For example, a temperature increase from 25° C. to 35° C. reduces the percent of amine sites that can capture CO2, at equilibrium, by about e−1. As a result, the ambient temperature in cold weather, i.e., winter in the mid or higher latitudes or elevations, reduces this problem, or allows a higher concentration of CO2 to be treated. For example, if the ambient temperature is 15° C., a rise of 10° C. would yield the same performance as the 25° C. case ambient location treating a lower concentration of CO2. The Langmuir isotherm for a primary amine is close to optimal at about 15° C. in terms of the fraction of amine sites in equilibrium and the sensible heat needed to strip and collect CO2 from the sorbent, so as to regenerate the sorbent effectively at about 100° C. A conceptual design is shown in FIG. 27 of the prior copending application, where the effluent gas is fully mixed with the air through a suitable apparatus, and the temperature rise is analyzed.
A particularly efficient embodiment of this invention is achieved if it is integrated into a CO2 generating process, such as a power plant, which includes a prior art treatment process, which at the least removes particulates and sorbent poisons, such as oxides of sulfur and nitrogen. Generally, most coal-burning plants in North America or Europe provide a post-combustion treatment using a process generally referred to as CSS technologies. One generally used such process is the so-called “post-combustion MEA process”, as practiced by the Costain Group PLC, of England, and as shown diagrammatically in FIG. 3, showing its use in a coal fired power plant, and its treated effluent being passed to the process of the present invention. The effluent from the CSS Process, which is free of particulates and the usual poisons of the sorbent used in the process of the present invention, is admixed with ambient air for treating with the present process to capture the combined CO2. The incremental cost per tonne of CO2 removal by the CSS Process increases sharply as one increases the percent of CO2 removed from the gas mixture and becomes very costly as one goes from 90% to 95% removal. On the other hand, as one reduces the percent captured by the CSS Process, alone, it often becomes costly because the penalty for the CO2 not captured increases in situations where CO2 emissions are regulated, thus reducing the value of the whole process. For these reasons the target for CSS is usually 90%.
On the other hand, the costs per unit amount of pure CO2 captured by the process of the present invention are reduced as the percent of CO2 in the process stream entering the process of the present invention increases; this is especially effective when combined with the effluent from such a CSS Process, or other flue gas pretreatment. As the concentration of CO2 in the feed stream increases, however, the process of the present invention must provide the necessary cooling means to insure that the temperature rise from the exothermic capture of the mixed CO2 does not cause the degradation of the effectiveness of the sorbent. There is thus an opportunity to optimize the cost per tonne of CO2 captured by calibrating the relative effect of the combination of the CSS Process and the present invention by reducing the percent of CO2 removed in the CSS stage—say if one backs off to 80% removal of CO2 in the prior art CSS Process, and mixing the remaining relatively high CO2 content CSS effluent (containing, e.g., 2% CO2) with ambient air. In that case, for every 1% of that CSS effluent stream one mixed with the air, one would increase by about 50% the CO2 concentration in the feed gas mixture into the process of the present invention.
The associated temperature rises can be determined, because the temperature rise depends on the rate of CO2 adsorption and thus the concentration of CO2 in the mixed process feed stream. If one mixed in 5% of the CSS effluent, it would reduce the capital costs for the process of the present invention by a factor of 3 (because the concentration is three (3) times higher in the mixed stream than in the air alone) over a stand-alone pure ambient air capture process. The temperature rise for that case is close to the rise when mixing the full flue gas stream version of the carburetor, or about 3.5° C. Most importantly, if the air capture process of the present invention were set to remove only 70% of the CO2 from the mixed stream, the combined processes would remove over 100% of the CO2 emitted by the power plant. It would thus produce carbon-free, or carbon-negative, electrical power or other product, having used the burning of fossil fuel as the energy source. In removing 75-80% of the CO2, by the process of the present invention, from the mixed gases, the result would be a carbon-negative power-generating process.
Besides achieving direct benefits from reducing the cost per tonne of CO2 collected, by having each process optimizing the cost of the other, there are also other benefits from process integration. These benefits include that the exhaust stream from the flue gas processing is clean, removing that problem/cost for the mixing step, and more efficient and lower cost use of energy. There are many different pre-combustion and post combustion CO2 removal processes being pursued, other than the CSS Process, and new ones could well emerge in the future. The details of the amount mixed of the ambient air and the CSS effluent, and possible additional processing of the exhaust from the first stage flue gas process, will vary in detail but the basic advantages of the combined process remain qualitatively the same.
To allow for the capture from a higher concentration of CO2, the present advance is based upon the discovery that allowing condensed steam, as water, to remain in the monolith pores after the stripping of the CO2 is completed, rapid evaporation of a portion of the hot condensate liquid is a highly useful tool to rapidly cool the monolith. The stripped, cooled monolith is then returned to the CO2-capture station and for a further sorption step, while conserving the heat by preheating the CO2-loaded sorbent preliminarily to stripping. The monolith and sorbent would otherwise be undesirably heated during the sorption step, and thus would be more susceptible to degradation when exposed to the CO2-laden air. This effect is most readily achieved in a monolith having a thickness, or length in the direction of the incoming air flow, of preferably not more than 10% of the largest other dimension of the monolith, e.g., a thickness of fifteen (15) centimeters, and a length or width of at least two (2) meters, by 0.5 meters, i.e., a surface area, transverse to air flow, of at least 1 meter square.
The rate of cooling the regenerated substrate can also be improved by pumping the regeneration box pressure down, e.g., preferably to less than 0.3 BarA, and most preferably to between 0.1 and 0.2 BarA, to remove most of the air before starting the flow of process steam through the substrate. This will also enhance the efficiency of the removal of high purity CO2 by eliminating most non-condensable gas before the stripping of the CO2.
In one of its basic aspects, this invention provides additional structures and techniques for capturing carbon dioxide from carbon dioxide laden air, and using process heat to separate carbon dioxide from a sorbent and regenerate the sorbent.
Moreover, in another of its aspects, this invention provides some additional structures and techniques that allow the efficient capture of carbon dioxide from higher concentrations of carbon dioxide in air, without forfeiting the use of low temperature process heat to separate the carbon dioxide from the sorbent and regenerate the sorbent. This invention further allows the capture, by sorption, of carbon dioxide from admixtures of air with flue gas and separation and regeneration. This allows a CO2-generating primary system to be rendered net CO2-negative, and thus reduce the amount of CO2 in the atmosphere.
In addition, this invention provides a relatively low cost and relatively pure source of CO2 for such beneficial uses as feeding algae farms for biofuel production, where the capture costs represents the entire cost of the CO2 supply.
In another embodiment, intended to further improve the performance and efficiency of the system, the regeneration chamber box is constructed so that the back wall (the gas collection side-opposite to the steam injection side) of the regeneration Box 3051 acts as a condenser of any steam passing through the monolith as vapor. If the wall is cooled by circulating water or has enough thermal mass to remove the heat, and then be cooled by air, than the steam will condense on the cool surface, forming water, by transferring its latent heat to the wall. Additional savings are achieved by eliminating an additional heat exchanger. If the back wall is kept at 40° C. or below, by cooling its thermal mass, then the back wall will function as a pump, by reducing the temperature in the closed regeneration box. The inner surface of the back wall can be provided with downwardly slanted ribs, to direct the condensed water to the side edges of the box, so as to prevent a large build up of condensed water on the back wall; such a buildup would slow the cooling. Such a system provides an efficient way to cool the monoliths for the following reasons: 1) it can be done quickly; 2) no additional capital expense is required for separate condenser; and 3) no need to pump water vapor for evaporative cooling, saving a lot of energy.
Although the processes of the present invention are best utilized in colder climates, in order to optimize the effective regeneration of the sorbent, while limiting any potential loss of effectiveness, the difficulty is that in the coldest climates, i.e., at the highest latitudes, there are very few preexisting plant facilities to which to attach the CO2 capture process. It has been realized now, however, that due to the greater efficiencies at such locations there is a basis to provide a stand-alone plant where there are no other facilities to provide either enhanced CO2 concentration or to provide the necessary process heat. A system, in accordance with this embodiment, provides a stand-alone unit which has no accessibility to external process heat or electricity and exists in a colder climate having extremely low temperatures such as the arctic region. The lower the temperature, substantially without limits, will result in a more efficient operating system. As the system is wholly contained, even conditions in an area such as in the Arctic, susceptible to extreme cold and frozen precipitation, should not interfere with the operation of this system. This will be especially true where the system is operating adjacent to or near a long distance pipeline carrying, for example, crude oil or natural gas from, e.g., the far North, to those areas of human habitation where it would generally be more likely useful.
In accordance with one embodiment of the present invention, a system including a generator of heat such as a boiler is connected to an electrical generator to operate the necessary auxiliary systems, e.g., an elevator system, the necessary control devices, valves, and compressor pumps, for the highly pure CO2. The high temperature heat is used to generate high pressure steam to operate the electrical generators, and the flue gas exhaust is utilized by admixing with ambient air so as to proceed in accordance with the earlier-described system. In this manner, the heat and other energy is provided to operate the system and, for no additional cost, the ambient air is further enriched by CO2, so as to allow for a more efficient capture of the combined CO2. Such a system can be almost revenue neutral (but almost always CO2-negative) even where there are energy costs, as long as there is a market or a use for the pure CO2 that is generated. For example, in the circumstance of a long distance pipeline, the purified CO2 can be at least partially stored adjacent the pipeline. In the event of any accidental fire or leakage, the CO2 can be used to snuff out most blazes that can erupt.
It is noted that there may be situations where the value of the purified CO2 is in fact greater than the cost of the fuel for the electricity generation at a particular location. In that circumstance, for example immediately adjacent a pipeline or a high latitude natural gas well, the more energy that is used and the more flue gas generated, the greater the value of the ultimate process for the generation of the pure carbon dioxide. In this case, the greater surprise happens where it is more valuable to use as much energy as possible and thus generating more CO2, rather than to conserve energy in what would be a more common situation. It is unlikely that such a situation would ever exist outside of the higher latitude, but, in that case (such as winters in mid-latitudes), this embodiment would be of great utility.
The substrate for the sorbent can be a monolith, formed, for example, of a silica material, such as cordierite, or an alumina structure, or from a polymeric material having intrinsic adsorption sites, such as a polymer having primary amine side groups. Generally the cordierite monolith would be expected to require more heat than the alumina substrate. In the situation where the CO2 has the enhanced value, a greater profit would then be made.
In operation, a system embodying this energy enhanced process will use a high temperature heat source and micro turbine to generate the necessary electricity. The lower temperature heat discharged from the turbine will be used to regenerate the CO2 sorbent. The feed stock to the CO2 sorbent would comprise a mixture of ambient air plus the exhaust from the heat source. Where the heat source is natural gas there might be very little necessity to pre-treat the exhaust before feeding into the adsorber. However, if coal or fuel oil is used, some initial mitigating pre-treatment would be necessary in order to remove particulate material, which would otherwise clog the substrate pores, as well as to remove certain by-products such as sulfur and nitrous oxide, which might otherwise poison the sorbent.
In computing the cost effectiveness of any system of this invention, the following equations can be utilized, where

CE/T equals Cost of Energy Per Ton of CO2 

CE/MMBTU equals Cost of Energy Per Million BTU, i.e., 1.055×109 joules×





  1
  CE




E/T equals Energy Needed Per Ton of CO2, measured in MMBTU

CO2/MMBTU equals quantity of CO2 emitted per million BTU.

REV equals revenue per ton of CO2 

When computing the operational costs of the system, the capital costs of the boiler and electrical generation shall be ignored and it will be assumed that there is no extra capital expense for the fuel generated CO2, just the cost for the fuel. Assuming the case of SH/HR equals 1.2, which translates into E/T equals 4 MMBTU and REV equals $40.00 per ton for natural gas, CE/MMBTU equals $3.00; CO2/MMBTU equals 53 kg so that CE/T equals 4×3 minus 40×4×0.053 equals $3.50 per ton.
For coal, on the other hand, the cost of energy per million BTU is highly variable but can be assumed equal to $2.50; the CO2/MMBTU equals again 0.092 so that the CE/T equals 4×$2.50 minus 40×4×0.092 equals $7.60 per ton. Interestingly, the cost of electricity would be equal to the percentage of CO2 added from the flue, i.e., 21% in the case of natural gas and 37% in the case of coal.
Further, for remote locations for EOR and merchant gas markets, revenue should be far greater than $40.00 per ton, thus further reducing the net cost of any energy provided, assuming that the marginal cost for producing the additional CO2 is low. By utilizing the high temperature energy to produce electricity and the process heat to strip CO2 from the sorbent, the economics become extremely favorable.
These and other features of this invention are described in, or are apparent from, the following detailed description, and the accompanying drawings.



BRIEF DESCRIPTION OF THE FIGURES AND EXHIBITS
FIG. 1 is a block diagram of a system for removing carbon dioxide from the atmosphere according to an exemplary embodiment of this invention;
FIG. 2 is a map illustrating a global system of multiple units, suitable for acting as a global climate modification system, according to an exemplary embodiment of the present invention;
FIG. 3 is a schematic illustration of a prior art pre-treatment system for flue gases, and connected into this system of this invention;
FIG. 4 schematically illustrate the preferred tandem version of a system and technique for removing carbon dioxide from carbon dioxide laden air, and regenerating the sorbent that absorbs or binds the carbon dioxide, according to the principles of the present invention; where Absorption Time is approximately equal to Regeneration Time to achieve the greatest efficiency;
FIG. 5 is a schematic illustration of a vertical version of a monolith medium for removing carbon dioxide from an atmosphere and for removing carbon dioxide from the medium, utilizing a vertical motion system or elevator to move the monolith between the upper air contact position (where the air movement is aided by a mechanical blower) and the lower regeneration position;
FIG. 6 is a schematic illustration of a horizontal version of a monolith medium for removing carbon dioxide from an atmosphere and for removing carbon dioxide from the medium, utilizing a horizontal track; and
FIG. 7 schematically shows a cut-away side view of one of the tandem systems elevator structures of FIG. 4, showing the monolith in the regeneration chamber.
FIG. 8 is a schematic illustration of a carbon dioxide removal system, originally shown in the incorporated prior application Ser. No. 13/098,370, showing one of the added tandem pairs of carbon dioxide removal structures forming a part of the present invention.



DETAILED DESCRIPTION OF INVENTION
Background Description of the System and Method Concepts of application Ser. No. 13/098,370
Following the system shown in the copending application (U.S. Patent Publication 2011/0296872), the following preferred embodiments of the present invention have been found to allow for the treatment of more highly concentrated gas mixtures of CO2. By following the process described herein, ensuring that the substrate meets the requirements set forth in this description, a concentrated CO2 mixture can be successfully treated, efficiently and at low cost, so that not only are the greenhouse gases from, e.g., a power plant, completely removed from the atmosphere, but the present process will result in a net carbon-negative effect, withdrawing more CO2 from the atmosphere than the plant emissions, and thus resulting in an overall reduction of CO2 in the atmosphere.
CO2 laden air is passed through the sorbent structure, which is preferably shaped so that the dimension in the direction of the air flow is much smaller, e.g., at least one and preferably at least two orders of magnitude smaller than the other two dimensions defining the surfaces facing in the path of the air flow. The CO2 binding sites on the surfaces of the substrate structure, e.g., primary amine sites, must be able to spontaneously bind the CO2, usually meaning that it is an exothermic reaction at ambient conditions, until the sorbent structure reaches close to the saturation level; this can be determined, for example, by measuring the concentration of CO2 of the air exiting the sorbent structure, known as the breakthrough amount.
When the desired CO2 breakthrough amount is reached, the sorbent structure is removed from the carbon dioxide laden air stream and isolated from the atmosphere, in a sealed regeneration chamber, and the CO2 is stripped off and the sorbent structure regenerated, in a manner described further below, by being exposed to process heat in the form of low temperature, saturated (at ambient pressure) steam passed through the sorbent structure. The steam will initially condense and transfer its latent heat of condensation to the sorbent structure, heating the structure until the temperature is reached at which the CO2 is stripped from the adsorbent sites and is pushed out of the substrate structure by the steam, as it passes from and through the front part of the sorbent structure until the entire sorbent structure will reach a uniform elevated saturation temperature. As the steam contacts and heats the sorbent, it condenses on the monolith, for each approximately two (2) moles of steam that condenses it provides sufficient latent heat needed to liberate, or strip, one (1) mole of the CO2 from the primary amine sorbent and push out the CO2 from the sorbent structure; an exhaust fan/pump can also be used to collect and remove CO2 from the regeneration chamber, as the CO2 is stripped off. This technique is referred to as “steam stripping” and is also described further below. For energy efficiency and cost reasons, it is desirable to minimize the amount of steam used and that is mixed in with the CO2 effluent, and to reclaim the hot condensate to be reheated to steam. Thus, whatever is (or can be) condensed, upon exiting the regeneration chamber, the condensate can be added to that generated in the regeneration chamber, and recycled to be heated and converted back into steam for further use.
The stripping process usually will be terminated at the onset of steam breakthrough, when the amount of uncondensed steam emerging from the backend of the sorbent structure becomes large compared to the newly stripped CO2. The exact conditions for terminating the injection of new steam will be determined by balancing the increased fraction of CO2 removed with the increased cost of energy as the steam process becomes less efficient in terms of the ratio of CO2 liberated per quantity of steam used. That energy needs to be replaced when the steam and condensate are reheated for the next stripping cycle, i.e., the energy requirement to maintain the equality of the CO2-capture time and the CO2-stripping and cooling time.
The System
In designing the structure of the system incorporating the present invention to be commercialized, the following design parameters should be considered. In general as one increases the loading of the sorbent sites on the substrate, one also wants high amine efficiency as defined by the fraction of amine sites present that are available to bind the CO2. This is the reason for preferring primary amines and also for adjusting the loading so as to minimize pore blockage by excess sorbent. Experimental results indicate that the optimum loading that balances amine efficiency with increased loading is between 40-60% by volume organic amine content relative to the porous substrate/skeleton to which it is attached or onto whose pore surfaces it is deposited. This can be determined by the following calculation, where:

Pcm=Density of the skeleton material (e.g., silica or alumina), in kg/cubic meter

PORc=Porosity, the ratio of the open wall area to the total surface area perpendicular to the direction of air flow

PUR=Ratio of CO2 released to trapped air, purity of CO2,

RH=heat of reaction;

SH/RH=Ratio of sensible heat to heat of reaction RH during regeneration

Savc=Surface area per volume of the skeleton, in 1/meters squared of surface/meters cubed

SH=sensible heat

TA=Time to fill to saturation with CO2, time for adsorption,

TS=Time to regenerate using steam stripping,

w=skeleton pore wall thickness

d=average pore/channel size

These are important design parameters to be considered in the design of this process. In this model, for ease of calculation, PORc is equal to the ratio of the average open channel area to the total average area, ignoring the tortuous nature of the curves in the channels of the walls of the porous medium. Thus, PORc=d2/(d+w)2. The surface area per volume is given by Savc=4 d/(d+w)2=4 PORc/d. The pressure drop is dependent upon the size of the openings in the channel, the void fraction of the monolith, length and velocity of air flow through the pores.

Sorbent Structure and General Operation of Sorbent

One example of a type of substrate that can be used is a silica monolith, produced by Corning, under the trademark CELCOR®. That monolith can be used as the support for a sorbent structure, in accordance with the principles of the present invention. The sorbent (e.g., a primary amine, such as) is carried by (e.g., coated or otherwise immobilized on) the inside of one or more of the CELCOR®, cellular ceramic substrates, which provides a high surface area and low pressure drop, as CO2 laden air flows through the substrate. The sorbent monolith structure can comprise, e.g., a plurality of the CELCOR® cellular, ceramic substrates, stacked as bricks, or a single monolithic substrate, described for example in connection with the copending applications. Other examples include the substrate and sorbent disclosed in published application US2011/0179948, or as described in a journal article by Choi et al, Amine-Tethered Solid Adsorbents Coupling High Adsorption Capacity and Regenerability for CO2 Capture From Ambient Air, by Sunho Choi et al, CHEMSUSCHEM 2011, 4, 628-635 (2011 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim).
The CO2 laden air is directed through the pores of the sorbent structure. It is also contemplated that the sorbent structure can be formed by embedding the sorbent material in an, e.g., alumina coating on the walls of the CELCOR® cellular, ceramic structure to form a monolithic sorbent structure.
It is also noted that an even more preferred structure is formed of bricks of porous alumina, in place of the silica of cordierite. Although the alumina structure is not physically and/or thermally as robust as the silica structure, the less rigorous conditions met in this ambient temperature capture process, and relatively low temperature stripping process, allow the use of the less robust structure. In addition, it should be noted that the substrate, in addition to the above ceramic structures, inorganic materials, the sorbent structure can be an organic material such as is formed from a polymerized polyamine by cross-linking the amine polymer to form a solid polymer, the solid polymer should be capable of being extruded at low enough temperature that the polymer does not volatilize, nor be softened at the temperature of the stripping steam, i.e., at up to 120° C., used for regeneration of the sorbent.
In general as one increases the loading one also wants high amine efficiency as defined by the fraction of amine sites present that are available to bind the CO2. This is the reason for preferring primary amines and also for adjusting the loading so as to minimize pore blockage. Experimental results indicate that the optimum loading that balances amine efficiency with increased loading is between 40-60% by volume organic amine content relative to the porous substrate/skeleton to which it is attached or into whose pores it is deposited.
If Ns is the number of CO2 binding sites per square meter of pore surface, Av is Avogadro's number, and if the density of the material of the skeletal structure is Pcm, the porous skeleton will have a density Pc given by Pc=(1−PORc) Pcm; then the loading L in moles per kilogram of sorbent structure is given by

L=Ns Savc/Av Pc=4 Ns PORc/Av d Pcm(1−PORc)

    
    
        If one solves the above expression for PORc, one finds

L=(4 Ns/Av Pcm)(1/(2w+w2/d))

    
    


Since it is desirable to maximize the loading of CO2 adsorbed by the structure, the polyamine sorbents provide the desired high Ns. In any case the above analysis makes clear that it is preferred to have as thin walls as possible, between the pores/channels in the porous support. The loading in moles/kg is to first order, independent of the size of the pores, with the decrease in Savc, as the porosity is increased by making the pore size larger, cancelled to first order by the decrease in the density of the porous support, Pcm.
One can insert the values for Av and for Pcm of 2,500 Kg/m3 (note: averaging the difference in the values for quartz and fused silica) and convert Ns to Nsn which is the number of attachment sites per square nanometer, where

    
    
        w and d are in nanometers, to find: L=1.33 (Nsn/w(1+w/2d) moles/kg, of the skeleton structure. For Nsn=5 sites per square nanometer and w=2 nanometers, a porosity of about 0.5 results in a surface area per gram of 400 mm2, or 160,000 mm2 and L=2.5 moles/kg. of the skeleton structure.
    
    


The actual loading capacity of CO2, as kg/m3 of air input, Ld/a, where the thickness of the support wall is We and the length (in the direction of airflow) of the monolith is Lm is given by Ld/a=L(0.044)(Pcm(1−PORc)) Savm We Lm, which substituting for L,

Ld/a=(Ns Savc/Av Pcm(1−PORc))×(0.044)(Pcm(1−PORc))×Savm×We×Lm; 

Ld/a=Ns(0.044)/Av)(Save×Savm×We×Lm), Substituting for Savc, 

Ld/a=Ns(0.044)/Av)×(Savm We Lm)×(4/d(1+w/d).sup.2).

In one example, using the Corning 230 cell CELCOR monolith, the pore flow length Lm is 0.146 meter, the surface area per volume of the monolith Savm is about 2000 m2/m3 and the pore wall thickness of the monolith Wm is 0.265 mm., determined from Ld/a=L (0.044 kg/mole) (Pc Savm 0.146 Wm), for an amount of CO2 in kg/m2 area of air input. A general design criteria is to make L and Ld/a as large as possible, constrained by the pressure drop constraint, i.e., limited by the force of the wind and/or fan array, which is met in the first embodiment of the present invention using modeling results for the Savm of the 230 cell Corning monolith, and the pore length, in the direction of air flow, of 0.146 m and input air flow velocity of 2.5 m/sec.
The walls of the monolith should have the desired PORc, and number of attachment sites to provide a high Nsn. Wm is determined based upon optimizing (minimizing) the pressure drop/Savm, which in turn will be constrained by a limit of how small one can make Wm to have acceptable loading, based upon other constraints (see below). It should be noted that L increases as w decreases, and d increases, but Ld/a decreases, with increasing pore size for a fixed w, because as the porosity increases Pc decreases. In general terms, the optimal design has the smallest w possible, and a porosity that balances the impact of the pore size on the performance parameters described below. It must be remembered that the amine compound may be impregnated as a liquid in the pores of the monolith as well as, or in lieu of, being supported on the walls of the pore structure.
Air capture following the present invention, is a relatively mild condition. This feature of the present invention allows the use of a much less robust structure for the monolith. In particular this permits the use of relatively thin walls made out of material with high porosity on to which sorbent is deposited; one such material is alumina. This will save in cost, using materials that are generally less robust and therefore less costly to manufacture. To prevent degradation of the sorbent, it is necessary to cool down the regenerated monolith to below 70° C. before exposing it to air (oxygen), during the sorption stage. The cool down must be done quickly to maximize the time the monolith is adsorbing CO2. The large amount of heat (about 109 joules for the current silica system—only about 2⁄3 as much is required for the alumina case) that needs to be removed in a short time, i.e., 10 to 20 seconds, in the presence of non-condensables, is very challenging; as a further challenge, economics requires avoiding the need for a large condenser with fast water flow. Although this could be shared with several units, spreading out its cost, it would have a cost impact and not be that efficient for heat recovery. In addition, the following solution also has positive impacts on steam and water use and CO2 purity. Furthermore, this concept works for sorbent systems that act in tandem, when using higher concentration gas mixtures, but can also be adapted for the single sorption systems operating on ambient air only.
In this system, as shown in FIG. 4, sealed Box 3051 contains Monolith array 3041 that has just completed steam regeneration and CO2 capture, and has a steam off-pressure of about 0.7 to 0.8 BarA, most of the CO2 having been withdrawn through line 3021, which line has been closed. At that time, Box 3052 contains Monolith array 3042, which has been lowered (after sorbing CO2 from the air mixture) into the regeneration Box 3052, and Box 3052 is being pumped out to lower the pressure in the Box 3052 to 0.1 BarA, which allows for a saturated steam temperature of 45° C. By lowering the box pressure, the ultimate result will be greater purity of the CO2 stripped from the regenerated sorbent because the amount of air, of course, is only 10% of the original 1 BarA atmosphere. The cost to pump the box of air down to the desired pressure when using electricity is less than 10% of the cost to move the air at 100 pascals pressure drop.
An additional amount of steam may be added to Box 3051 to push out most of the remaining CO2 in the box using the force of the steam, which also forces some additional condensate to collect in the pores of Monolith array 3041. When Box 3051 is exposed to the low pressure of Box 3052, through the line 3014, any steam and hot condensate in Box 3051 will suddenly expand and evaporate, creating an initial steam burst into Box 3052. The Box 3051 outlet line 3014 (when Box 3051 and Box 3052 reach equilibrium) is closed off and Box 3052 is put into connection with the steam distributer input pipe 3012. This steam burst from Box 3051, being added to Box 3052 condenses on the cooler Monolith array in Box 3052, raising its temperature. The steam burst also serves to quickly cool Monolith array 3041, as the condensate evaporates and any steam expands. The velocity of this initial steam burst from the water evaporating from Box 3051 Monolith array is designed to reach a velocity of at least 10 times faster than the air flow speed, or 0.5 mps. The two connected boxes, Box 3051 and Box 3052, reach an equilibrium at a temperature lower than Tregen−Tair/2, because a portion of the heat will be removed by the stripped CO2 from Box 3052.
The connection 3014 between Box 3051 and Box 3052, when the lower temperature is reached in Box 3051, is then closed and process steam is introduced through line 3012 into Box 3052 and the pressure is allowed to increase to 0.7-0.8 BarA, the process steam strips the CO2 from the Monolith array 3042. The process steam heats the Monolith array to the Tregen temperature and, when the collection of CO2 drops to a lower rate that signals completion of the regeneration of the sorbent in Box 3042. After the initial steam burst from Box 3051, the lower pressure in Box 3051, which resulted from the evaporation of the hot condensed water on the Monolith array 3041, also quickly reduces the temperature of the Monolith array 3041 to below 70° C., which allows for the introduction of air to further cool the Monolith array 3041 down to its adsorption operating temperature, which is substantially the ambient temperature. The cooled Monolith array 3041 is being raised, as it is air-cooled, to the adsorption position, receiving fresh CO2 laden air or mixed high concentration gasses. This cycle is repeated in reverse, as Monolith array 3042 becomes fully stripped and Monolith array 3041 returns from the air capture zone into sealed Box 3051.
In addition to the greatly reduced cooling time, the advantages in water and heat usage are clear, saving both by at least a factor of 2. Substrates provide a very good heat sink because of their large surface area and thin pore walls. The concentrated carbon dioxide and condensed steam in Box 3052 from Box 3051 is removed from Box 3052 via line 3022 to a capture vessel and the valve in line 3022 is closed and steam passed into Box 3052 from line 3012.
Although the present silica-based Monolith array, i.e., cordierite, has sufficient thermal conductivity, an alumina Monolith array will have further improved conductivity and, thus, will result in even faster cooling when combined with the evaporation of condensed water in Box 3051 and the condensing of the steam burst on Box 3052. It has been shown that the heat change effect is 109 joules, resulting in cooling of Monolith array 3041 within 10 seconds to a temperature below 70° C. This method avoids any additional cost for a separate water-cooled condenser, and water, of course, beyond that used for the process steam, is unnecessary.
It is desirable to minimize as much as possible the time during which no CO2 adsorption is occurring, in either the Monolith array 3041 or Box 3042 Monolith array. This is achieved by operating two sets of monolith arrays in tandem, preferably side by side, so that the cycles for the two boxes can be placed in phase so that when one is adsorbing, the other is being regenerated, so as to allow the cooling of one to create the heating of the other, as explained above. This results in the shortest period during which no adsorption is occurring in both monolith arrays, and, in fact, members of the pair are preferably limited to slightly more than 10 seconds, per cycle for the cooling step. The treating of a higher concentration CO2 gas mixture can be more successful when this double tandem cycle is in use.
As a further energy and apparatus saving, as shown in FIG. 4, the tandem pairs can act as elevator counterweights for each other, thus reducing the amounts of energy needed for each raising and lowering cycle, while also reducing the number of elevator systems, including motors and counterweights, needed if a more conventional counterweight system were used. Such a system, however, does require careful equalizing of the time needed for each of the capturing and stripping cycles, including heating and cooling of the monolith array, and capturing and stripping of the CO2.
It has been demonstrated that fossil fuel combustors, especially natural gas fired co-generation facilities (cogen), can be effectively, but minimally, pretreated to remove some of the CO2 and any potentially blocking or poisonous impurities, with respect to the monolith array of the process of this invention. Subsequently, the pretreatment effluent can be diluted with ambient air, and used as a feed stock to the monolith arrays. Although certain gas-fired burners require only minimal pretreatment to remove problem impurities, in general the flue gas from a coal burning boiler requires extensive pretreatment to remove particulates and any compounds that may be poisonous to the sorbent or which tend to degrade the substrate. In one embodiment, the pretreated flue gas from the co-generation process is injected into the sorption system of this invention, along with additional ambient air. In this mixing process, the CO2 concentration in the air is increased significantly (even with a minor proportion of the additional effluent gas), so that the adsorption step can be performed in a shorter period of time, comparable to that of a regeneration step. In a preferred embodiment, a parallel set of adsorber/regeneration modules operates in tandem with the existing facility. That is, one will be adsorbing CO2 while the other is being regenerated, and vice versa. This mimics a continuous capture of CO2. The process is represented by two stages, CO2 adsorption and regeneration of, for example, turbine exhaust, as described in FIG. 1 of the accompanying drawings. In a preferred system, two pairs are operated together so that each tethered pair can act as counter-balances for each other, thereby saving capital costs for the elevators.
In Stage 1, atmospheric air is mixed with co-generated exhaust gas and the mixture is passed through the CO2 adsorption module. This process uses a low-cost, high porosity ceramic substrate (monolith) such as those used in the automotive catalytic converters, e.g., cordierite, a silica product. CO2 is captured on the solid sorbent which is bonded to and supported by the substrate. The sorbent does not vaporize or dissolve under the operating conditions during both sorption and stripping, or regeneration. Again, the basis for the effectiveness of this invention is the operation of both stripping and adsorption at relatively low temperatures.
As before, Stage 2 provides for the regeneration of the sorbent by stripping the adsorbed CO2, using low temperature processing (steam) in a separate regeneration chamber, preferably located at an elevation different, preferably lower, than the adsorption housing position. This allows for a simple elevator system to move the monolith array adsorbent 3041 between the two levels. In developed regions, where land has value, the vertically off-set arrangement has reduced area. In less developed regions, such as the polar areas, a side-by-side arrangement may be preferred when situations, and sideways movements, e.g., along rails, may preferably be used in place of the elevator.
CO2 and steam condensate are the only effluents from the Stage 2 regenerator. Generally, it has been shown that when operating at the temperatures set forth herein, the steam condensate liquid has substantially no sorbent material removed with it. The process adsorbs CO2 from ambient air and can produce a relatively pure CO2 product gas stream suitable for sequestration or, more significantly, for further industrial use. One example of such use is the generation of new fuel by using CO2 as a feed material to a biological system. CO2 capture efficiency has a measure of energy usage and the adsorber parameters are determined based upon concentration of CO2 in the feed stream, and any naturally available air velocity provided to the adsorption system, i.e., prevailing winds. The efficiency is also further determined by the availability of saturated, relatively low temperature steam from a co-generation process, for the stripping of the CO2 from the sorbent and regeneration of the sorbent. By providing a relatively pure CO2 off gas, the cost of such CO2 removal is minimized or can even be made profitable when the CO2 is used, for example, to grow algae capable of providing new fuel, in oil fields for enhanced oil recovery, or other commercial or industrial applications now presented or which become available in the future. Growing algae for biofuels is expected to be a major profit center for using the carbon dioxide product of this process.
Tandem Operation:
As a further improvement to this process it has been found that capital and energy savings of a significant quantity can be achieved by integrating adjacent modules of the sorption/regeneration units in order to optimize the performance of each of the units.
It has been found that the operation and economics of the system can be optimized by quickly cooling the regenerated monolith to below the temperature at which it would be degraded in contact with ambient air. Although the specific temperature would depend upon the nature of the sorbent and monolith used, for a cordierite substrate and an amine sorbent, this temperature limit is below70° C., in order to avoid excessive degradation of the monolith in the presence of ambient air. In addition, this should be accomplished as part of a regime to minimize to as great an extent as possible, the amount of externally provided heat needed to be added to the process while collecting high purity CO2 removed from the sorbent.
In order to optimize the overall effectiveness of this system, and to obtain an efficiently operating system, the cooling of the monolith after regeneration must be accomplished very quickly, so that the steps of CO2 capture by the sorbent on the monolith can be synchronized with the regeneration step. Most advantageously, the cool-down should preferably be achieved within no more than about 10 seconds in order to minimize the time when carbon dioxide is not being adsorbed by the monolith. Based upon the present invention, this effect is achievable in accordance with the use of the following process parameters:
It has been found that by combining the operation of a plurality of modules in tandem, a highly efficient system is provided when treating a uniform mixture of ambient air with flue-derived gaseous effluents added so as to increase the concentration of CO2 in the feed gas several times above that found in ambient air. In addition, obtaining the desired purity of CO2 from the stripping step requires that the regeneration box have the majority of the air exhausted before the CO2 is stripped from the sorbent. The first array monolith 3041 has just been through a complete steam regeneration cycle and the carbon dioxide off gas pressure is at about 0.7 to 1 BAR. The second monolith array 3042, operating in tandem, has been lowered into the regeneration chamber after completing the CO2 adsorption step and the air in the regeneration chamber 3042 is pumped down to between 0.2 and 0.1 BAR (which provides a steam saturation temperature of between 60° C. and 45° C., respectively). The air evacuation allows for improved purity of the stripped CO2 withdrawn from the regeneration chamber after regeneration, and the cost to exhaust the air after the monolith array has entered the chamber and the chamber was sealed, is relatively a small amount of power (usually in the form of electricity).
The two tandem arrays are synchronized so that these conditions are met, at T=0. At that point, the outlets from the first regenerated array Box 3041 are switched to the input pipe of Box 3042 so that any steam trapped in Box 3041 and created by the evaporative cooling of the monolith array in Box 3051 is pumped into Box 3042, when line 3014 is opened, resulting from the large pressure differences (0.7-1 to 0.2-0.1 BAR), and the steam then condenses on the relatively cool monolith array 3042 in Box 3052, raising its temperature as is required for regeneration. In this manner, the heat removed from the first monolith array, when cooling, is transferred directly to the second monolith array to provide at least an initial heat to increase its temperature. The steam burst from Box 3051 into Box 3052 is occurring at a fast flow rate, and preferably at a flow rate of at least approximately 0.5 meter per second, in order to achieve the ten second target. The large pressure drop between the two regeneration chambers should make this feasible. When the process is completed, the system is at time cool (Tcool).
Box 3052 is preferably pumped down to 0.1 BarA, but Box 3051 is shut off from Box 3052 when Box 3052 reaches a pressure of 0.15 BarA. This will result in a desirable reduction of air in Box 3052 and, thus, a further improvement in the purity of the CO2 ultimately to be removed. After the connection between Box 3051 and Box 3052 is closed, the steam for regeneration is allowed to enter Box 3052 and initially condenses on the monolith array 3042 which has been pre-warmed to a certain extent. The admission of the steam results in a pressure build-up to between about 0.7 and 1 BarA, as the CO2 is removed from the sorbent on the monolith array and passed into Box 3052 and pushed out by the final steam. By allowing the pressure in Box 3052 to increase to 0.7 to 1 as a result of the CO2 and steam collection, Box 3052 ends up as did Box 3051, at T=0, which includes the collection of CO2 as it is removed from the sorbent on the monolith array. The time to reach this point is equal to Tcool+Tcollect (the time to collect the regenerated CO2).
In the meantime, the cooled monolith array 3041 is exposed to air, and ambient temperature, as it is raised to the adsorption position. The time for monolith array 3041 to return to the adsorption position equals Tcool (the time to cool monolith array 3041)+Televator (the time to raise the monolith array to the adsorption position). Monolith array 3041 is exposed to a flow of air and, over a period of Tad, until the adsorption reaches the desired extent, as a percent of saturation, or equilibrium. It is noted that, to operate this in the most efficient manner, adsorption does not continue to equilibrium, but, rather, is terminated by removal from the adsorption position at a lower level, generally in the range of 80% to 90% of the equilibrium amount, for the concentration of CO2 in the feed gas.
To frame this result as a mathematical equation, it can be stated that Tcool+Tcollect2 equals Tcool+2Televator+Tad1. It is noted that Tcollect and Tad can be independently adjusted in order to reach this desired result. As it is generally desirable to maximize Tad, generally Tcool and Tcollect should be minimized to the extent feasible, and Televator should be maintained at a low number.
When dealing with the mixed high CO2 concentration gases, it would be desirable that the two tandem modules each have two modular arrays and the two front boxes of each of the tandem modules and the two back boxes of the two tandem modules would be linked so that the cycle of treating and removing CO2 from air would be only 1⁄2 cycle out of phase with each other; where ambient air, without added CO2 is being treated, a tandem design is unnecessary but Tad can be as high as ten times Tcollect, so that if one were to phase ten units, where unit N would provide 1⁄2 the sensible heat for unit N+1, in principle, the heat from N10 could be re-looped back to N1 but the increase in efficiency may not be sufficient to justify the cost. This type of tandem system results in cutting water and heat usage almost in half, and the use of condensers or other cooling aids is omitted, along with the need for separate cooling water.
The monolith substrates provide a large heat sink. As a result of their large surface area, thin porous walls and, in many cases, good thermal conductivity, so as to provide fast cooling by the condensing steam as the steam passes through the porous monolith.
It has been found that by creating this system of process integration, sorbent lifetime can be increased, heat requirement and water usage can be reduced, while the purity of the CO2 product can be increased. It has also been found that capital and energy savings are obtained by integrating neighboring modules. Moreover, it turns out to have a significant impact on the performance of the individual modules as well. The following three process objectives are, thus, cost effectively addressed:

    
    
        Objective 1. To cool the current embodiment, i.e., cordierite, monolith to below 70° C. before exposing them to air, in order to prevent degradation. It must be noted that future sorbents may be more oxygen resistant so that the temperature need not be reduced quite as much; however, the lower the temperature of the monolith the faster the CO2 adsorption.
        Objective 2. To use as little heat as possible in the process; and
        Objective 3. To collect a high purity CO2.
    
    


Objective 1 has become increasingly important because of the need to cool down the monolith very quickly after stripping, as the monolith arrays, in general, have a large amount of sensible heat at that point in the process. The design target for cooling is 10 seconds, in order to minimize the time spent not adsorbing CO2. The prior art believed that separate condensers were necessary to accomplish this result. However, many options of using condensers have been explored, but, as they all require very large surface areas and a great deal of cooling water, because of the large amount of heat and short time allowed for its removal, they have not been found to be practical. This is true regardless of the nature of the monolith substrate that is in use; although cordierite requires the greatest amount of heat removal, another type, for example, an alumina monolith, requires a smaller amount, by a substantial degree. However, even for those types, separate condensers were not found to be practical. Other adsorbent-supporting monoliths may require even less heat to be removed, but, in any event, the use of condensers has been shown to be inefficient under almost any feasible circumstances.
Objective 2 is also not met by the use of condensers because, transferring heat to cool water, where the water temperature needs to be maintained at a low temperature for effective heat transfer rate, renders it virtually impossible to economically recover the heat and, thus, cannot reduce the net energy requirements for the system.
Finally, Objective 3 requires that trapped air be removed from the regeneration Box 3052 before collecting CO2. In addition, by designing the system for plug flow, so that the evolving CO2 will push out the air before the systems switch to collecting the CO2, the remaining air is first removed from the regeneration chamber. To achieve the target purity of at least 95%, a high degree of plug flow is desirable. Plug flow requires that there be no radial concentration differential of components with temperature and that there be no axial mixing in the direction of the flow of the gases. This can be achieved when treating ambient air in a single module, or when treating high CO2 concentrated gas in a tandem module system. The following text only considers two neighboring tandem molecules to illustrate the process. The process steps are as follows:

    
    
        Box 3051/Monolith array 3041: the monolith array is in the sealed regeneration Box 3051, and has just completed steam regeneration and CO2 collection; —the steam off-pressure is about 0.7-1.0 BarA. This could include introducing some extra steam after breakthrough to push out any remaining CO2 (see below).
        Box 3052/Monolith array 3042 has just been lowered into the sealed regeneration Box 3052, after capturing CO2. The Box 3052 is pumped down to 0.2 to 0.1, bar which provides a 60° C. and 45° C., respectively, steam saturation temperature at those pressures. This evacuation of the air will of course be a big help to purity of the CO2 product, because the amount of air is only 20-10% of ambient air, and the cost to pump one box of air using electricity is less than 10% the cost to move air at 100 pascals pressure drop, and only 5% in the current embodiment.
    
    


Before this process we anticipated only pumping down to cool down after regeneration and would have had to do it twice if we also wanted to pump down for improved purity before regeneration. This integration of two neighboring modules accomplishes both tasks at the same time with a single evacuation. One can schedule two neighboring modules, which have independent cycles, so they both reach their above described condition at the same time. One can call this T=0.
Removal of the carbon dioxide and condensed steam from the carbon dioxide capture is carried out together with some of the steam and condensed steam into a separation chamber before Box 3051 output pipe 3021 is then switched closed and Box 3051 is opened to the steam distributor input pipe 3014 from Box 3052, upon completion of stripping and exhausting of CO2 from the Monolith 3041. The remaining steam trapped in Box 3051 and created by evaporation (cooling) of monolith array 3041 is “pumped” into Box 3052 by the large initial differences in pressure (−0.7-1:0.2-0.1 BarA) and condenses on the cool monolith array in Box 3052, raising its temperature. So the heat removed from monolith array 3041 to cool it, is directly transferred to monolith array 3042, to heat it. The velocity of this initial steam burst from the water evaporating from the monolith array needs to be at least 10 times faster than the current 5 cm speed used for steam regeneration, or 0.5 msec, to meet the 10 second design target. Given the large difference in pressure when there is large mass flow and low pressure drop in the monolith array this should be easy to achieve. The two boxes would reach equilibrium at the saturated vapor temperature of steam at 0.2-0.1 BarA, which is 60-45 C.
To assure that the process is sufficiently fast, it is preferable to reduce the pressure in Box 3052 to 0.1 BarA, but the exit valve from Box 3052 is closed at 0.15 BarA. The temperature sought will depend on what maximum temperature is the limit to minimize degradation. The pump will have a check valve on it and will only be pumping after the initial pump down if there is a buildup of CO2 in Box 3052 which is unlikely because at the low temperature the partial pressure of CO2 is lower than 15% which is what 0.15 BarA would represent. So the sorbent will likely keep the partial pressure of CO2 below 1 percent. One can adjust this by how much of the CO2 we leave in Box 3051 before we open the valve 3014, which in turn can push out the remaining air further increasing the purity even before the regeneration process begins. The time for cooling plus switching and transit time of steam=Tcool: One then closes the connection 3014 between Boxes 3051 and 3052 and introduces the normal steam source, through line 3012, into Box 3052; the steam condenses on the pre-warmed monolith array 3042 and lets the pressure build up to 0.7-1 by the presence of CO2 before beginning CO2 collection and complete the steam regeneration process and collection of CO2 at the slower rate to complete regeneration of Box 3052—ending up with Box 3052 where Box 3051 started. This takes time Tcollect so total elapsed time for Box 3052 is Tcool+Tcollect.
Cooled Box 3051 is returned to ambient pressure, as the cooled monolith array 3041 is raised to the adsorption position. It takes a total time Tcool+Televator, and adsorbs for a period of time Tad and then is lowered for a total elapsed time of Tcool+2 Televator+Tad.
To get the two boxes in phase so they can swap their heat back and forth one needs

Tcool+Tcollect=Tcool+2 Televator+Tad 

Since Tcollect and Tad are independently adjustable this condition can be easily met. To maximize Tad one wants to minimize Tcool and Tcollect and have a low Televator. For the case of the carburetor and tandem design, two neighboring modules would each have two module arrays and one would link the two front boxes from each and the two back boxes so that there is no loss in duty cycle—they would be one half cycle out of phase with each other.

In the case of air only, a non-tandem design is useful; where the Tad might be 10 times Tcollect one could in principle phase 10 units where unit n would provide 1⁄2 the sensible heat for unit n+1. One could in principle also reloop the heat from N10 back to N1 but that would only buy you an extra 5% in heat efficiency, with great additional cost and complexity.
The advantages of this process in water and heat usage are clear, a factor of close to a reduction by a factor of two for both inputs. There is no extra capital cost for a large condenser and no need for any cooling water. The substrates are a great heat sink because of their large surface area and thin walls, and alumina has a good thermal conductivity and thus offers extremely fast “cooling” of the condensing steam possible.
To demonstrate these advantages, the following calculations illustrates the basic performance of this system in being able to remove the heat from the regenerated monolith array at a sufficient rate to meet the 10 second design target utilizing the aforedescribed system. Although the use of monoliths as heat sinks had previously been recognized, using them in this manner, and in the context of this process of CO2 capture from air, has not been known or suggested.
Basic Performance
To operate in the current system, it is necessary to evaporate 22 Kg of water/steam from a hot monolith array of 640 individual monoliths to cool the array, such as monolith array 3042, to 55° C. from 110° C. and to condense the evaporated steam, within ten seconds, onto the cool, e.g., monolith array 3041, to prewarm that array. The latent heat of steam in this temperature range is 2.3×106 joules so one needs to remove HR=50.6×106 joules in T=ten seconds.
The surface area in a single monolith is quite large. There is 6.4 m2 in each 6 in×6 in×6 in monolith (Nc=230 cell/in2, SA=surface area/monolith=4 s Nc L FA) where s is opening=1.3 mm, 36.8×104 cells/m2, L=0.15). For a standard unit array of 640 monoliths, e.g., the units 3041 or 3042, the total surface area is TSA=4,216 m2.
Thus the thermal flux needed is TFN=HR/TSA=12×103 joules/m2 in ten seconds, which is quite low; even if any non-condensable gases remain, the steam will condense quickly enough to cool the unit. The only issue is whether heat can be removed fast enough. It is noted that the condensed water, which tends to limit heat transfer in most condensing systems, is unlikely to be a significant problem in the heat transfer in this case. The 22 kg of water occupies 22×10−3 m3, which if divided by the TSA of 4,216 m2 yields a water depth of only 0.005 mm, even without considering that some of the water will be in the pores of the walls. Furthermore at these low temperatures and pressures the sorbent on the monolith itself will remove and immobilize the CO2, limiting any buildup of concentration of CO2 in the gas phase.
The thermal conductivity k of alumina is 18 watts/m/° K, but because it is porous assume k=10 watts/m° K. Now the TF, thermal flux/m2 in ten seconds in the monolith walls=kT(ΔTemp/w), where w is 1⁄2 the wall thickness of the monolith channels. Taking a conservative value for w of 0.2 mm, and for ΔTemp of only 10° K, TF=5×106 joules/m2, which is much greater than TFN. The potential performance exceeds the requirements by a sufficient amount that it raises the possibility of doing the CO2 collection at a very fast rate. This could enable a very short cycle time, which could have other benefits. Most notably enabling one to use a short monolith array to capture CO2 at very high concentrations in the gas mixing case. Alternatively, one could also consider smaller sized module array units for the minor quantities of flue gases, since their productivity would be so high.
In the basic embodiment, for treating the monolith array in unit 3051 to cool it down after regeneration and at the same time transfer the heat to the neighboring monolith array in unit 3052, loaded with CO2, it might have been assumed that the temperature of the loaded monolith array was the same as the input feed ambient air flue gas mixture which had an 8-fold enhancement in CO2 concentration. It should be noted in some situations it might be desirable to arrange for the monolith array in unit 3052 to heat up due to CO2 adsorption thus storing the heat of reaction. For example by reducing condensed water available for cooling during adsorption; this could raise the overall thermal efficiency of the process even more—

    
    
        In the base case, one-half the sensible heat could be saved—In the present case, it would be the sum of 1⁄2 the heat of reaction+1⁄2 the sensible heat.
        One can think of this as increasing the gas mixing heat efficiency by adjusting its operating Temperature: the optimum will depend upon the temperature dependence of the oxidative degradation of the monolith. Generally, the heat of reaction of the sorbent, and the ratio of sensible heat to heat of reaction per tonne of CO2 (e.g., loading and material and density of monolith walls) will be taken into account.
    
    


Once the concentration non-condensable gases are reduced to a level needed to achieve the rate of condensation required, the next challenge is to remove the heat fast enough. As pointed out by Martin and others—this is both a mass problem (how much coolant-specific heat) and a thermal conductivity problem (how fast can the heat be removed from the condensing surface).
In the embodiment of FIG. 8 (taken from the incorporated prior application Ser. No. 13/098,370, where only one of the pairs of carbon dioxide removal structures is shown but a connection to the second regeneration chamber 2006A is added) the carbon dioxide removal structures are moved between the CO2 capturing zone 2003 and the sealable CO2 stripping/regeneration chamber 2006. When a substrate is moved to the CO2 stripping chamber 2006, i.e., the lower position as shown in FIG. 8, the substrate is at substantially ambient temperature due to the cooling effect of the condensed steam in the substrate when moved out of the carbon dioxide capture chamber, the heat of reaction of the sorption activity having been removed by the evaporative effect of the water combined with the convective effect of the blown mass of air from which the CO2 was removed, which is far greater than the amount of CO2.
Any trapped air in the substrate 2002 and chamber 2006 can be pumped out, e.g., by an air evacuation pump 2023, or even by an exhaust fan, to form a partial vacuum in the chamber 2006. Next, process heat, e.g., in the form of saturated steam from the Steam co-generator 2019, is directed at and through the CO2-laden substrate 2002 in the carbon dioxide capture chamber 2006.
Carbon dioxide is removed from the sorbent (stripped off) by the flow of relatively hot steam; the incoming steam is at a temperature of not greater than 130° C., and preferably not greater than 120° C., and most preferably not greater than 110° C. Under most circumstances a steam temperature of 100° C. is sufficient. The vapor, comprising primarily carbon dioxide and some steam, flows out of the carbon dioxide capture chamber 2006, through exhaust conduit 2008 into a separator 3009, where liquid water is separated as shown and at least some of the steam present is condensed. The liquid condensed water is separated from the gaseous stripped CO2. Some of the steam that is condensed in the sorbent structure itself during the stripping process either will be collected in a drain at the bottom of the regeneration chamber (e.g., by tipping the structure slightly off level and pass into container 20) or will be evaporated upon being exposed to the low pressure in the pumped out second regeneration chamber 2006A of the pair, after the majority of the CO2 had been removed to chamber 3009. The condensed water left in the porous substrate structure will be evaporated when the mixed ambient air is passed through the carbon dioxide removal structure during the adsorption step.
The stripped CO2 from the regenerated sorbent is in turn pumped into a storage reservoir 2012, where it is maintained at slightly elevated pressure for immediate use, e.g., to provide CO2-rich atmosphere to enhance algae growth, or the carbon dioxide gas can be compressed to higher pressures, by means of compressor 2014, for long term storage or to be pipelined to a distant final use, e.g., sequestration or treating of oil wells or natural gas wells to improve production. During any compression phase, the CO2 is further purified by the condensation of any remaining water vapor, which water condensate is in turn separated from CO2, by known means.
The idea works for both the tandem which is the preferred embodiment, but can also be adapted for the non-tandem case as well. Box/Monolith 1 has completed steam regeneration, and the steam shut-off. Box 3052 has just been lowered after adsorbing CO2, and pumping out of the air from Box 3052 is beginning, to reduce the pressure in Box 3052 to 0.2 to 0.1 BarA. The Box 3051 output pipes are switched to the steam distributor input pipes of Box 3052; the steam from the evaporating condensed water in Box 3051 condenses on the relatively cool monolith in Box 3052, raising its temperature. The velocity of this initial steam burst from the water evaporating from the monolith needs to be at least 10 times faster than the current speed, or 0.5 msec; this will help spread out the heating but still will have a sharper front than the air case by 5, so no steam will come out the back end. The two boxes will reach an equilibrium at a temperature less than (Tregen−Tair)/2 because some of the heat will be taken away by the evaporating CO2. The 3051 connection is then closed and steam is introduced into Box 3052 from the steam source to complete the heating to Tregen and collection of CO2 at a slower rate to complete regeneration of Box 3052. Box 3051 containing the cooled monolith array 3041 is then exposed to the ambient air and is raised to the adsorption position.
One process negative is that for a brief time both Box 3051 and Box 3052 are not absorbing CO2 from air. In the case of air capture where the boxes 3051 and 3052 are side by side; the cycles for the two boxes can be phased so both do not have a reduction in duty cycle. Also in another embodiment in the tandem application, if the monoliths were arranged back to back, than one box would be steam stripping in the direction opposite from the capture direction.

## Claims

1. A system for removing carbon dioxide from carbon dioxide laden air, the system comprising
a pair of carbon dioxide removal structures, each structure comprising a sorbent that is capable of absorbing or binding to carbon dioxide, to remove carbon dioxide from the air, and a porous solid mass substrate upon the surfaces of which the sorbent is supported, and a movable structural support for the substrate; the structural support supporting the sorbent in a position to be exposed to a flow of carbon dioxide laden air so as to allow for the removal of CO2 from the air;
a pair of sealable CO2-capture chambers, one for each carbon dioxide removal structure for capturing carbon dioxide from the CO2 loaded removal structure; openable fluid connection means between the carbon dioxide capture chamber and an exhaust pump for reducing the atmospheric pressure within the sealed carbon dioxide capture chamber after the entry of a removal structure; openable fluid connection means between the carbon dioxide capture chamber and a source of process heat steam; openable fluid connection means between the two carbon dioxide capture chambers; and an openable fluid connection means between each carbon dioxide capture chamber and a CO2 collection chamber; and
apparatus for moving a carbon dioxide removal structure into and out of a carbon dioxide capture chamber.

2. The system of claim 1, wherein the pressure in each of the carbon dioxide capture chambers is reduced to not greater than 0.15 BarA.

3. The system of claim 2, wherein the pressure in each of the carbon dioxide capture chambers is reduced to 0.1 BarA.

4. The system of claim 3, wherein the vertically oriented carbon capture structure is configured and operable so that it is alternatively and successively placed in the path of carbon dioxide laden air, to remove the carbon dioxide from the air, and exposed so as to be heated with process heat, to separate the carbon dioxide from the sorbent and regenerate the sorbent.

5. The system of claim 3, comprising an automatically operating valve system designed and adapted to alternatively and successively pass carbon dioxide laden air to the carbon capture structure and to pass process heat to the carbon capture structure to separate the carbon dioxide from the sorbent and regenerate the sorbent.

6. The system as defined in claim 1, wherein the porous solid mass comprises a highly porous monolithic ceramic structure which supports the carbon dioxide sorbent to absorb or bind carbon dioxide from the air.

7. The system of claim 1, comprising a pair of vertically oriented carbon capture structures, each of which is selectively operable in a manner wherein one of the pair of vertically oriented carbon capture structures is alternatively and successively in the path of carbon dioxide laden air while the other of the pair of vertically oriented carbon capture structures is being heated with process heat to separate the previously adsorbed carbon dioxide from the sorbent and regenerate the sorbent on the porous support.