July 30, 2008 

Charlie 

i AIR fcNFORCEMENTBRANCH 

iU.S . EPA. REGION 5 

JUL 3 0 2008 

Attached is the June, 2006 Test Report for Unit 3. This report contains 

information on the arsenic issue from May, 2006 and the subsequent testing 

results from June, 2006 that demonstrate compliance with the LVM standards. In 

addition, information that was sent to Sarah Marshall regarding the arsenic issue 

is also included. Please call if you have any questions. 
TECHNICAL SOLUTIONS 

NORT H AMERIC A 

ENVIRONMENTAL SERVICES 

JUL 8 0 2008 

October 30, 2006 

Ms. Sarah Marshall 

Air and Radiation Division 

United States Environmental Protection Agency 

Region 5 

77 West Jackson Blvd 

Chicago, II 60604-3590 

R E : Veolia ES Technical Solutions, L.L.C. 

Notice of Violation and Finding of Violation 

EPA-5-06-28-IL 

Dear Ms. Marshall: 

Pursuant to your request during our meeting on October 23, 2006, Veolia ES 

Technical Solutions, L.L.C. is submitting the following: 

• Test report for the "Evaluation of Metals, Particulate Matter and 

PCDD/PCDF Emissions for Fixed Hearth Incinerator Unit 3, 

June 2006." 

• Historical Arsenic Emissions for Incinerators 2, 3 and 4 from 

2001 through 2006. 

• Arsenic concentrations from port and stack samples, May, 2006 

and June, 2006. 

Veolia is finalizing the emissions calculations from Material Processing Areas 1 

and 2 and will be submitting that information to you by November 13, as 

requested. 

Please call me or Dennis Warchol, at (618) 271-2804, if you have any questions 

or need any additional information. 

Doug Harris 

General Manager 

Veolia ES Technical Services, Inc. 

#7 Mobile Ave, Sauget, IL 62201 

tel: 618 2712804 - fax: 6i3 2712128 

www.VeoliaES.com 
Att. 

cc: Greig Siedor 

Joe Kellmeyer, Thompson-Cobum, LLP 

USEP A File 
Historical Arsenic Emissions for Veolia ES - Sauget 

Test Date Unit Run 1 Run 2 Run 3 Average 

(ug/dscm) (ug/dscm) (ug/dscm) (ug/dscm) 

Apr-01 4 14.16 14.16 24.16 17.49 

Apr-01 2 2.81 4.21 3.04 3.35 

May-02 4 1.89 3.45 2.67 

May-02 4 3.67 3.65 3.66 

May-02 3 1.13 0.38 0.76 

Aug-02 4 48.15 37.68 52.13 45.99 

Aug-02 3 3.22 1.72 2.47 

Aug-02 3 1.62 1.83 1.72 

Nov-02 3 1.32 2.54 1.93 

Nov-02 2 16.02 6.71 11.37 

Nov-02 4 1.71 1.33 1.29 1.44 

Sep-03 4 12.4 11.1 63.9 29.1 

Sep-03 2 1.4 1.5 0.63 1.2 

May-06 3 6.14 126 557 230 

Jun-06 3 3.4 1.9 2.98 2.8 

The above table shows the historical arsenic emission results for Veolia incinerators 

during.testing conducted in 2001, 2002, 2003, and 2006. The total LV M emissions for 

all ofthe above tests were below 97 ug/dscm with the exception of the May 2006 test 

performed on Unit 3. No scrutiny was given to any of the results for arsenic in the pre2006 tests since the total LV M emissions were below the Interim MACT Standard 

emission limit of 97 ug/dscm. Although the magnitude is not as great, the results for Unit 

4 testing in August 2002 and for one run in September 2003 may have been falsely 

elevated due to similar contamination from rust/scale from the sampling ports as was 

determined for the Unit 3 May 2006 testing. 
Laboratory Analyses for Rust/Scale Samples from Unit 3 Stack 

During the investigation to determine the cause ofthe elevated arsenic 

results observed during the emissions testing in May 2006 on Unit 3, 

analyses were performed on rust/scale samples obtained from the Unit 3 

stack. Four samples were taken on May 30 and two more samples were 

taken on June 8. Below are the analytical results obtained: 

May 30— 279 ppm (sample taken inside stack around sample port) 

May 30 — 4375 ppm (sample taken inside stack around sample port) 

May 30 — 1830 ppm (sample taken inside stack around sample port) 

May 30 — 463 ppm (sample taken inside stack around sample port) 

June 8 — 2676 ppm (sample taken from inside flange in stack) 

June 8 — 82 ppm (sample scraped off of removable blank flange) 

Kevin Mattison and Michael Reed of the Illinois Environmental Protection 

Agency were on-site during the June 8 sampling. 
Evaluation of Metals, Particulate Matter 

and PCDD/PCDF Emissions for Fixed 

Hearth Incinerator Unit 3 

June 2006 

ENSR Corporation 

September 2006 

Document No.: 10002-017 

ENSR AECOM 
Prepared for: 

Veolia ES Technical Solutions 

Sauget, Illinois 

Evaluation of Metals, Particulate Matter 

and PCDD/PCDF Emissions for Fixed 

Hearth Incinerator Unit 3 

June 2006 

Prepared By: Jeffrey T. Gorman, Project Manager 

Reviewed By: Craig R. Doolittle, rE , Manager, Air Measurements 

ENSR Corporation 

September 2006 

Document No.: 10002-017 

ENSR AECOM 
ENSR 

Contents 

) 

1.0 Introduction 1-1 

1.1 Program Summary 1-1 

2.0 Incinerator Process Description 2-1 

2.1 Process Overview.. 2-1 

2.2 Waste Feed Systems [40 CFR §63.1207(f)(1)(iii)(D)(E) and (f)(1)(ii)(C)] 2-1 

2.3 Manufacturer, Make and Model of the Incinerator [40 CFR §63.1207(f)(1)(iii)(A)] 2-1 

2.4 Air Pollution Control Equipment [40 CFR §63.1207(f)(1)(iii)(G)] 2-2 

2.4.1 Lime System 2-2 

2.4.2 Spray Dry Absorber 2-3 

2.4.3 Fabric Filter 2-3 

2.4.4 Induced Draft Fan and Stack 2-3 

3.0 Summary of Results 3-1 

3.1 Introduction 3-1 

3.2 Stack Emission Results for PCDDs/PCDFs 3-1 

3.3 Stack Emission Results for Target Metals and Particulate Matter 3-1 

\ 3.4 Metals Sampie Contamination 3-2 

4.0 Sampling and Analytical Procedures 4-1 

4.1 Sampling Procedures 4-1 

4.1.1 Velocity, Moisture and Fixed Gas Determinations 4-1 

4.1.2 PCDD/PCDF Sampling 4-1 

4.1.3 Metals and Particulate Sampling 4-1 

4.2 Analytical Procedures 4-1 

4.2.1 PCDD/PCDF Analyses 4-1 

4.2.2 Metals Analyses 4-2 

4.3 Process Operating Conditions 4-2 

5.0 Quality Assurance 5-1 

5.1 Introduction 5-1 

5.1.1 Pre-Sampling Activities 5-1 

5.1.2 Equipment Calibration 5-1 

5.1.3 Glassware Preparation 5-2 

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List of Appendices 

Appendix A Facility Operating Data 

Appendix B Reference Method Field Data and Calculations 

Appendix C Reference Method Calibrations, Verifications, and Certifications 

Appendix D Stack Configuration, Sampling Port and Traverse Point Locations 

Appendix E Laboratory Data 

List of Tables 

Table 3-1 PCDD / PCDF Emission Results - TEQ Basis 3-3 

Table 3-2 Emission Results for LVM Metals - May 2006.. 

Table 3-3 Emission Results for LVM Metals - June 2006 

Table 3-4 Emission Results for SVM Metals and Mercury 

Table 3-5 Summary of Target Metals 

3-4 

3-5 

3-6 

3-7 

Table 3-6 Emission Results for Particulate Matter - May 2006.. 

Table 3-7 Emission Results for Particulate Matter - June 2006 3-9 

3-8 

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1.0 Introduction 

1.1 Program Summary 

ENSR was retained by Veolia ES Technical Solutions (Veolia), formerly Onyx Environmental 

Services to conduct stack gas emission sampling during the weeks of May 8, 2006 and June 19, 

2006. The sampling was performed on the Fixed Hearth Hazardous Waste Incinerator Unit 3 at their 

facility in Sauget, Illinois. The purpose of this Performance Test was to evaluate the performance of 

the incinerator relative to the emissions standards for existing incinerators found in 40 CFR Part 63, 

Subpart EEE (the HWC MACT regulations). To this end, the specific objectives of this Performance 

Test were to demonstrate emissions of the following pollutants: 

• Mercury 

• Low Volatile Metals (arsenic, beryllium, and chromium) 

• Semi-volatile Metals (lead and cadmium) 

• Dioxins and Furans 

• Particulate Matter 

The Performance Test included feeding certain types of wastes and materials into the incinerator, 

sampling and analyzing these feedstreams, monitoring certain process parameters while 

concurrently conducting emissions testing. 

The results from this testing indicate that emissions for the above pollutants met the emission 

standards for the HWC MACT regulations. A summary of the test results can be found in Section 3 

of this report. 

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2.0 Incinerator Process Description 

2.1 Process Overview 

Veolia operates 2 Fixed Hearth Dual Chambered Incinerators (Units 2 and 3) and one rotary kiln 

(Unit 4) at the Sauget, IL facility. The two fixed hearth units are rated at 16 million Btu/hr each. 

Incineration Unit No. 3 is a mirror image of Unit No. 2. Both of these units have their own waste 

handling systems as described in the sections that follow. The only difference being Unit No. 2 is 

equipped with four (4) baghouse modules, while Unit No. 3 is equipped with three (3) baghouse 

modules. Unit 4 is rated at 50 million Btu/hr and is equipped with its own tank farm system, drum 

storage, bulk solids storage and feed systems. 

2.2 Waste Feed Systems [40 CFR §63.1207(f)(1 )(iii)(D)(E) and (f)(1 )(ii)(C)] 

Fixed hearth incinerator no. 3 is designed to receive containers, aqueous liquid wastes; organic 

liquid wastes fed through air-atomizing nozzles, specialty liquid feeds and direct inject liquids fed 

through the aqueous or organic liquid feed systems. This unit can receive any combination of 

wastes ~ liquid, semi-solid, or solid -- with a heat value of up to 16 million Btu/hr. 

Each of the fixed hearth incinerators are supported by storage/blend tanks located in Tank Farm #1. 

Rates of feed are controlled at each incinerator. Segregated liquid wastes are stored until utilized in 

the waste blending facilities. At that time, liquids are delivered to the blending tanks where the daily 

liquid feed to the incinerator is formulated, tested, and released to the incinerator. Blending of 

stored liquid wastes to achieve optimum heating value and viscosity for incineration takes place in 

Tanks 2, 4, 6 & 8. Six additional tanks (10,20,30,40, 50 & 60) are used to segregate different 

waste stream types for blending of liquid feed to the incinerator. Several criteria are important in 

designing a blend from available wastes that have been segregated principally by physical and 

chemical properties. These include compatibility, proper range of heating value, and permit 

restrictions regarding elemental composition (based on emission limitations). 

In compliance with the Benzene NESHAP, all tanks are vented to individual carbon adsorption 

canisters for removal of organics before vapor is discharged to the atmosphere. Each carbon 

adsorber canister is essentially equivalent to a 55 gallon container or greater, if necessary. All tanks 

are equipped with conservation vents, in addition to the carbon canister adsorber. All tanks are 

grounded, and flame arrestors are installed between the carbon adsorbers and the tanks. 

2.3 Manufacturer, Make and Model of the Incinerator [40 CFR §63.1207(f)(1 )(iii)(A)] 

Incinerator unit no. 3 features a two-stage combustion process. Ignition of waste material takes 

place in the primary (lower) combustion chamber. A secondary (upper) combustion chamber serves 

as an "after-burner" for process gases. Ignition of the waste takes place at temperatures in excess 

of 1,600 degrees F. The secondary combustion chamber maintains a minimum temperature of 

1,800 degrees F. These temperatures are presented in current operating conditions. 

The Series 2 incinerator has a total of two burners, one burner, a North American burner, rated at 

12.0 million Btu/hr., is used in the lower chamber to maintain temperatures. It will burn only natural 

gas or No. 2 fuel oil. A second burner is mounted in the upper chamber; it too will be used to supply 

additional heat and will be fueled with natural gas or #2 fuel oil. This burner is a North American 

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Burner, rated at 6.0 million Btu/hr. Liquid or gaseous wastes are injected through separate feed 

nozzles as described in section 2.2, above. 

The primary and secondary chambers have an external diameter of 9 feet, and are 17.5 feet long. 

The interior walls of both chambers are lined with approximately 10 inches of brick refractory and 

insulation backing, making the internal operating diameter approximately 7'2". The cross-sectional 

area of the chambers is thus 40.3 square feet. Combustion air is controlled separately in the upper 

and lower chambers. 

Following ignition of the waste material under controlled or starved-air conditions in the lower 

chamber, off-gases travel through a refractory-lined flue gas passage into the upper chamber, which 

acts as an afterburner. Turbulence is achieved by the tangential introduction of air and additional 

fuel in the upper chamber. Gas temperatures are normally maintained at 1,800-2,200 degrees F in 

the upper chamber and 1500-1900 degrees F in the lower chamber, pursuant to current Illinois EPA 

permit operating conditions. 

Leaving the upper chamber, the hot gas stream travels through 28 feet of refractory-lined stack 

sections before reaching the start of the gas scrubbing system. The combined volume of the upper 

and lower chambers, the flue gas passage and the hot crossover section is approximately 1,567 

cubic feet. The total retention time of combustion gases within the system is approximately 5 

seconds. The incinerator is rated at 16 million Btu/hr., with a design unit heat release of 

approximately 10,000 Btu per cubic foot. Maximum gas volume when firing a heat release of 16 

million Btu/hr. is about 15,000 acfm at 400 degrees F. 

2.4 Air Pollution Control Equipment [40 CFR §63.1207(f)(1 )(iii)(G)] 

The air pollution control system consists of a spray dryer absorber and fabric filter baghouse. The 

air pollution control system neutralizes acidic compounds and removes particulate from the exhaust 

gas. Two subsystems, the spray dryer absorber and the fabric filter, carry out the chemical 

neutralization and particulate removal functions, respectively. A third subsystem, the lime system, is 

used to prepare and provide lime slurry to the spray dryer absorber for use in the chemical 

neutralization process. The induced draft fan and stack provide the mechanical energy required to 

transport the flue gas through the interconnecting ductwork, to its eventual discharge point to 

atmosphere. 

2.4.1 Lime System 

The lime system prepares lime slurry for use in the chemical neutralization process in sufficient 

supply and concentration to maintain continuous flue gas treatment in the spray dryer absorber. 

The system has been designed for batch mixing to provide this service. 

Hydrated lime is stored in a storage bin above the lime preparation area. The storage bin is sized to 

hold enough hydrated lime to maintain several days of system operation at the maximum 

combustion rate of the incinerator. Lime is discharged through the conical storage bin bottom. The 

flow of the material from the bin is aided by a vibrating "live bottom," or bin activator. A variable 

speed rotary feeder is used to meter the hydrated lime in the proportions required for batch mixing 

lime siurry. The lime is mixed with water in a tank beneath the lime storage bin. The rotary feeder 

speed and the rate that water is added to the lime slurry tank are variable so that the desired 20% 

lime solids concentration can be achieved in the tank. The variable feed adjustments allow water 

and lime to be added to the lime slurry tank at a rate that will allow a batch mode of mixing. An 

agitator is provided in the slurry tank to mix the water and lime and to maintain the suspension of 

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lime solids. The mixed lime slurry is pumped at a continuous rate of flow through a recirculation 

loop to the atomizer. 

2.4.2 Spray Dry Absorber 

Slurry flow to the spray dryer absorber is metered by a flow control valve to obtain the proper feed 

concentration to the spray dryer absorber atomizer. Automatic (or manual) adjustment to the flow is 

made as a function of the output from a hydrochloric acid (HCI) analyzer in the gas duct downstream 

of the Fabric filter. The amount of slurry metered is proportional to the amount of HCI monitored. 

The slurry passes through a stationary swirl-type liquid distributor into the atomizer wheel where 

induced centrifugal force from the rapidly spinning wheel discharges the slurry through the wheel 

nozzles at high velocity. The design of the atomizer wheel, its rate of spin, and the discharge 

velocity of the slurry, create a cloud of finely divided droplets around the periphery of the atomizer 

wheel. A feedback signal from the atomizer power transmitter provides verification that water flow to 

the atomizer increases or decreases in proportion to the spray dryer absorber outlet temperature. 

Flue gas enters from the bottom of the spray dryer absorber through a vertical, centrally located 

disperser. The disperser directs the flue gas through the zone filled by the atomized slurry cloud 

where the flue gas and slurry mix, and most of the absorption occurs. 

The spray dryer absorber features a two-point product discharge. A portion of the dried spent 

chemicals and ash settle to the bottom of the chamber. This material is discharged at the base of 

the powder discharge cone. It then passes through a lump breaker which reduces large 

agglomerations of material to a manageable size. Finally, it is discharged through a rotary valve to 

the conveying system. The remainder of the spent chemicals is carried from the module entrained in 

the flue gas. 

2.4.3 Fabric Filter 

Gas exhausted from the spray dryer absorber is distributed by manifold ducts to three fabric filter 

modules at Unit 3. Within each filter module, the gas is passed through Teflon-coated fiberglass 

cloth bags. The gas passes from the outside to the inside of the filter bags. Particulate, entrained in 

the gas stream, is mechanically deposited on the outside of the filter bags as the gas passes 

through the cloth. 

The fabric filter cleaning mechanism utilizes jets of air to clean the filter bags. Periodically, the 

cleaning sequence will be initiated. The sequence is either started at the end of a timed cycle, or 

when the differential pressure across the filter reaches a predetermined setpoint of approximately 

7.0" w.c. The controller then sequences to each row of filter bags in each module, releasing a burst 

of air opposite to the direction of gas flow. The quickly released burst of air dislodges dust cake on 

the exterior of each bag as it travels from the top to the bottom of the bags. Released from the bag, 

the dust cake falls by gravity into the hopper at the bottom of the module. 

The dust cleaned from the filter bags is removed at the base of the hopper through a rotary valve for 

discharge to the conveying system. Treated by the spray dryer absorber and filtered by the fabric 

filter, the cleaned flue gas exits the fabric filter modules to an outlet manifold for exhaust. 

2.4.4 Induced Draft Fan and Stack 

The induced draft fan and stack are located downstream of the fabric filter. Combustion gases are 

drawn through the system by a 75 hp induced draft (ID) fan, rated at 15,000 acfm at 400° F 

saturated, and 22' water column pressure. The induced draft fan provides the mechanism for 

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transporting the incinerator flue gas through the spray dryer absorber, Fabric filter, and all 

interconnecting ducts. The velocity of the gas within the ducting and treatment devices is regulated 

by the damper associated with the fan. Treated gasses exhausted from the induced draft fan to the 

atmosphere through a 90-ft. high stack. The stack diameter for Unit 3 is 39 inches I.D. The stack is 

equipped with instrument sampling ports and a sampling platform for emissions testing. Appendix D 

provides details on the design and sample port locations and configurations for Unit 3. 

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3.0 Summary of Results 

ENSR 

3.1 Introduction 

This section summarizes the test program results. Appendix B presents copies of ENSR's field data 

and calculations. Emission data is summarized in this section and feed and process operating data 

are included in Appendix A. 

3.2 Stack Emission Results for PCDDs/PCDFs 

Method 0023A required separate analysis of the front-half and back-half sample train fractions. 

Program samples were submitted to Alta Analytical Laboratories in El Dorado Hills, CA for all 

analysis of all target parameters. A summary of the PCDD/PCDF emission results on a TEQ basis 

for Unit 3 are included in Table 3-1. 

• The PCDD/PCDF emissions for Unit 3 (average emissions for runs 1, 2 and 3 were 0.024 

ng/m3 @ 7% 02 ) are below the HWC MACT emission standard of 0.2 ng/m3 @ 7% 02 . 

3.3 Stack Emission Results for Target Metals and Particulate Matter 

A summary of the metals and particulate matter emissions for Unit 3 is included in Tables 3-2 

through 3-7. Tables 3-2 and 3-3 provide a detailed summary of the Low Volatile Metals (LVM) 

emissions from the May 2006 and June 2006 testing. A detailed summary of metals emissions 

categorized by Semi-volatile Metals (SVM) and mercury is provided in Table 3-4. Table 3-5 provides 

a summary of all six target metals. Tables 3-6 and 3-7 summarize the particulate matter emissions 

from the May 2006 and June 2006 testing. 

. The LVM metals emissions for Unit 3 from the May 2006 testing (average emissions for runs 1,2 

and 3 were 249 ug/m3 @ 7% 02for LVMs) were higher than the HWC MACT emission standards 

of 97 ug/m3; 

. The LVM metals emissions for Unit 3 from the June 2006 testing (average emissions for runs 1, 

2 and 3 were 7.61 ug/m3 @ 7% 02for LVMs) were lower than the HWC MACT emission 

standards of 97 ug/m3; 

. The SVM and mercury emissions for Unit 3 (average for runs 1, 2 and 3 were 16.6 ug/m3 @ 7% 

O2 for SVMs and 61.5 ug/m3 @ 7% 02for mercury) were below the HWC MACT emission 

standards of and 240 pg/m3 (corrected to 7% 02 ) and 130 pg/m3 @ 7% 0 2 for SVMs and 

mercury respectively; 

. The particulate matter emissions for Unit 3 from the May 2006 testing (average emissions for 

runs 1, 2 and 3 were 6.39 mg/m3 @ 7% 02 ) is below the HWC MACT emission standard of 34 

mg/m3 @ 7% 02 ; 

• The particulate matter emissions for Unit 3 from the June 2006 testing (average emissions for 

runs 1, 2 and 3 were 2.66 mg/m3 @ 7% 02 ) is below the HWC MACT emission standard of 34 

mg/m3 @ 7% 02 . 

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3.4 Metals Sample Contamination 

During the May 2006 testing, high arsenic levels, which were inconsistent among the three runs, 

were detected in sample results from the Method 29 train. A detailed review was conducted by both 

ENSR and Veolia personnel to assess possible causes and/or sources of cross contamination. This 

review included: 

• Sample train clean-up and preparation procedures 

• Sample port access and preparation for sampling 

• Sampling anomalies (i.e., observations of filter, sample train and procedures) 

• Lab contamination or incorrect results (duplicate samples were analyzed at a separate 

laboratory) 

• Operating or equipment issues that could have caused non-representative particulate matter 

containing high arsenic to be collected in the sample train 

It was concluded that there was cross-contamination of the sample train during sampling that was 

most likely caused by dislodgement and re-entrainment in the flue gas of scale that had built up on 

the inside of the stack sample port over time, causing a non-representative result. Also, during this 

review it was determined that the number of traverse points for the ports used for the dioxin and 

furan sampling was incorrect based on Method 1 criteria, although results were well within the 

MACT emission standards. 

As a result, Unit 3 was re-tested in June to further evaluate low volatile metal and dioxin and furan 

emissions performance. Ports were cleaned prior to testing and the correct number of traverse 

points was used for the selected sampling locations. Dioxin and furan results were again well within 

the emission standard. Low volatile metal results were also well within the emission standard. 

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Table 3-1 PCDD / PCDF Emission Results - TEQ Basis 

Run No. Run 1 Run 2 Run 3 

Date 19-Jun-06 20-Jun-06 21-Jun-06 

Start Time 14:40 09:30 09:30 

Stop Time 17:59 13:05 11:43 

Units 

Sample Volume dscf 128.363 129.710 126.379 

Sample Volume m

3 3.63 3.67 3.58 

Moisture Content % v/v 44.4 47.7 45.6 

0 2 Concentration % v/v (dry) 10.00 8.20 9.60 

C 0 2 Concentration % v/v (dry) 7.40 7.60 7.40 

Isokinetics % 99 104 100 

Stack Flowrate dscfm 5,441 5,212 5,280 

PCDD/PCD F pg ng/m3 

pg ng/m3 

pg ng/m3 

Parameters TEF a TEQ TEQ TEQ 

2,3,7,8-TCDD 1.00 0.00 0.0E+00 3.44 9.4E-04 0.00 0.0E+00 

1,2,3,7,8-PeCDD 0.50 17.0 2.3E-03 17.6 2.4E-03 16.7 2.3E-03 

1,2,3,4,7,8-HxCDD 0.10 19.1 5.3E-04 16.8 4.6E-04 14.6 4.1 E-04 

1,2,3,6,7,8-HxCDD 0.10 46.1 1.3E-03 34.7 9.4E-04 35.7 1.0E-03 

1,2,3,7,8,9-HxCDD 0.10 37.0 1.0E-03 27.1 7.4E-04 26.3 7.3E-04 

1,2,3,4,6,7,8-HpCDD 0.01 190 5.2E-04 175 4.8E-04 156.0 4.4E-04 

OCDD 0.001 247 6.8E-05 175 4.8E-05 151 4.2E-05 

2,3,7,8-TCDF 0.10 30 8.1 E-04 32.8 8.9E-04 31.8 8.9E-04 

1,2,3,7,8-PeCDF 0.05 36 4.9E-04 41 5.6E-04 41 5.7E-04 

2,3,4,7,8-PeCDF 0.50 65 9.0E-03 70 9.6E-03 76 1.1 E-02 

1,2,3,4,7,8-HxCDF 0.10 36 9.9E-04 33 9.0E-04 38 1.1 E-03 

1,2,3,6,7,8-HxCDF 0.10 32 8.8E-04 32 8.6E-04 34 9.4E-04 

2,3,4,6,7,8-HxCDF 0.10 44 1.2E-03 42 1.1 E-03 45 1.3E-03 

1,2,3,7,8,9-HxCDF 0.10 10 2.8E-04 12 3.2E-04 11 3.1 E-04 

1,2,3,4,6,7,8-HpCDF 0.01 78 2.1 E-04 67 1.8E-04 71 2.0E-04 

1,2,3,4,7,8,9-HpCDF 0.01 8 2.2E-05 5 1.4E-05 7 2.0E-05 

OCDF 0.001 20 5.6E-06 15 4.0E-06 13 3.7E-06 

Total TEQs (ng/m3) = 0.020 0.020 0.021 

Total TEQs (ng/m3 @ 7 % 02) = 0.025 0.022 0.026 

% of Standard" = 12% 11% 13% 

a

 U.S.EPA (1989) Toxic Equivalency Factor 

" PCDD/PCDF Standard = 0.20 ng/dscm @ 7% 02 

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Table 3-2 Emission Results for LVM Metals - May 2006 

Run No. Run 1 Run 2 Run 3 

Date 10-May-06 10-May-06 11-May-06 

Start Time Units 10:08 15:00 11:25 

Stop Time 12:51 17:16 13:39 AVGS 

Sampling Parameters -

Barometric Pressure in. Hg 29.10 29.02 29.05 29.06 

Volume Metered def 81.248 83.546 76.761 80.518 

Sample Volume dscf 79.598 84.056 76.269 79.974 

Moisture % v/v 43.0 43.6 44.6 43.7 

0 2 at Stack %dry 12.40 9.40 10.00 10.60 

Avg. Stack Temp. °F 381 371 371 375 

Stack Flowrate dscfm 5,576 5,691 5,088 5,451 

Isokinetics % 109 101 102 104 

Arsenic (As) ~ LVM 

Quantity Collected M9 8.50 248 945 401 

Stack Cone. @ 7% 02 ug/m3 6.14 126 557 230 

Stack Emission Rate Ib/hr 7.88E-05 2.22E-03 8.34E-03 3.55E-03 

g/sec 9.92E-06 2.80E-04 1.05E-03 4.47E-04 

Beryllium (Be) — LVM 

Quantity Collected ug 0.10 0.10 0.10 0.10 

Stack Cone. @ 7% 02 ug/m3 0.07 0.05 0.06 0.06 

Stack Emission Rate Ib/hr 9.27E-07 8.96E-07 8.82E-07 9.02E-07 

g/sec 1.17E-07 1.13E-07 1.11E-07 0.00 

Total Chromium (Cr) -- LVM 

Quantity Collected ug 16.7 28.0 54.8 33.2 

Stack Cone. @ 7% 02 Mg/m3 12.1 14.2 32.3 19.5 

Stack Emission Rate Ib/hr 1.55E-04 2.51 E-04 4.83E-04 2.96E-04 

g/sec 1.95E-05 3.16E-05 6.09E-05 0.00 

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ENSR 

Table 3-3 Emission Results for LVM Metals - June 2006 

Run No. Run 1 Run 2 Run 3 

Date 19-Jun-06 20-Jun-06 21-Jun-06 

Start Time Units 15:12 10:06 10:06 

Stop Time 17:29 12:29 12:44 AVGS 

Sampling Parameters -

Barometric Pressure in. Hg 29.55 29.55 29.50 29.53 

Volume Metered def 78.244 82.902 81.745 80.964 

Sample Volume dscf 72.247 76.482 75.573 74.768 

Moisture % V/V 46.7 47.8 45.5 46.7 

0 2 at Stack %dry 10.00 8.20 9.60 9.27 

Avg. Stack Temp. °F 386 388 386 387 

Stack Flowrate dscfm 4,730 4,915 5,114 4,920 

Isokinetics % 104 106 i_ 101 104 

Arsenic (As) — LVM 

Quantity Collected pg 5.53 3.69 5.20 4.81 

Stack Cone. @ 7% 0 2 pg/m3 3.44 1.86 2.98 2.76 

Stack Emission Rate Ib/hr 4.79E-05 3.14E-05 4.65E-05 4.19E-05 

g/sec 6.03E-06 3.95E-06 0.00 0.00 

Beryllium (Be) — LVM 

Quantity Collected pg 0.00 0.0870 0.00 0.0290 

Stack Cone. @ 7% 0 2 pg/m3 0.00 0.0439 0.00 0.0146 

Stack Emission Rate Ib/hr 0.00E+00 7.39E-07 0.00E+00 2.46E-07 

g/sec 0.00E+00 9.32E-08 0.00E+00 3.11E-08 

Total Chromium (Cr) -- LVM 

Quantity Collected pg 9.91 3.85 11.2 8.30 

Stack Cone. @ 7% 0 2 pg/m3 6.17 1.94 6.40 4.84 

Stack Emission Rate Ib/hr 8.58E-05 3.27E-05 9.98E-05 7.28E-05 

g/sec 1.08E-05 4.12E-06 1.26E-05 9.17E-06 

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Table 3-4 Emission Results for SVM Metals and Mercury 

Run No. Run 1 Run 2 Run 3 

Date 10-May-06 10-May-06 11-May-06 

Start Time Units 10:08 15:00 11:25 

Stop Time 12:51 17:16 13:39 AVGS 

Sampling Parameters — 

Barometric Pressure in. Hg 29.10 29.02 29.05 29.06 

Volume Metered def 81.248 83.546 76.761 80.518 

Sample Volume dscf 79.598 84.056 76.269 79.974 

Moisture % v/v 43.0 43.6 44.6 43.7 

0 2 at Stack %dry 12.40 9.40 10.00 10.60 

Avg. Stack Temp. °F 381 371 371 375 

Stack Flowrate dscfm 5,576 5,691 5,088 5,451 

Isokinetics % 109 101 102 104 

Cadmium (Cd) - SVM 

Quantity Collected pg 0.34 1.04 2.42 1.27 

Stack Cone. @ 7% 0 2 pg/m3 0.25 0.53 1.43 0.73 

Stack Emission Rate Ib/hr 3.15E-06 9.31 E-06 2.14E-05 1.13E-05 

g/sec 3.97E-07 1.17E-06 2.69E-06 0.00 

Lead (Pb) - SVM 

Quantity Collected Mg 21.2 19.6 37.9 26.2 

Stack Cone. @ 7% 0 2 pg/m3 15.3 9.9 22.3 15.9 

Stack Emission Rate Ib/hr 1.96E-04 1.76E-04 3.34E-04 2.35E-04 

g/sec 2.47E-05 2.21 E-05 4.21 E-05 2.97E-05 

Mercury (He) ~ VM 

Quantity Collected pg 97.3 121 89.4 . 103 

Stack Cone. @ 7% 0 2 pg/m3 70.3 61.5 52.7 61.5 

Stack Emission Rate Ib/hr 9.01 E-04 1.09E-03 7.88E-04 9.25E-04 

jj/sec 1.14E-04 1.37E-04 9.93E-05 1.17E-04 

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3-6 September 2006 
Table 3-5 Summary of Target Metals 

Low Volatile Metals Emissions - micrograms/m3 

May 2006 Test 

Metals Run 1 Run 2 Run 3 Average 

As 6.14 126 557 230 

Be 0.07 0.05 0.06 0.06 

Cr 12.05 14.2 32.3 19.5 

Total LVM 18.3 140 589 249 

June 2006 Test 

Metals Run 1 Run 2 Run 3 Average 

As 3.4 1.9 2.98 2.8 

Be 0.00 0.04 0.00 0.01 

Cr 6.17 1.94 6.40 4.84 

Total LVM 9.61 3.85 9.38 7.61 

LVM Regulatory Standard = 97 micrograms/m 3 

Semi-Volatile IV etal Emissions - micrograms/m3 

Metals Run 1 Run 2 Run 3 Average 

Pb 15.3 9.9 22.3 15.9 

Cd 0.25 0.53 1.43 0.73 

Total SVM 15.6 10.5 23.8 16.6 

SVM Regulatory Standard = 240 micrograms/m3 

Mercury Emissions - micrograms/m3 

Metals Run 1 Run 2 Run 3 Average 

Hg 70.3 61.5 52.7 61.5 

Mercury Regulatory Standard = 130 micrograms/m3 

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3-7 
ENSR 

Table 3-6 Emission Results for Particulate Matter - May 2006 

Run No. Run 1 Run 2 Run 3 

Date 10-May-06 10-May-06 11-May-06 

Start Time Units 10:08 15:00 11:25 

Stop Time 12:51 17:16 13:39 AVGS 

Samplinq Parameters --

Barometric Pressure in. Hg 29.10 29.02 29.05 29.06 

Volume Metered dcf 81.991 84.128 81.699 82.606 

Volume of Gas Collected dscf 79.526 83.462 80.402 81.130 

Moisture % v/v 44.4 44.8 44.1 44.4 

0 2 at Stack %dry 12.50 9.40 10.00 10.63 

C 02 at Stack %dry 6.40 6.80 7.00 6.73 

Avg. Stack Temp. °F 376 366 364 369 

Stack Flowrate dscfm 5,468 5,483 5,287 5,413 

Isokinetics % 109 100 100 103 

Particulate Emission Results -

Front Half Rinse g 0.0031 0.0066 0.0058 0.0052 

Particulate Filter g 0.0030 0.0081 0.0071 0.0061 

Total Particulate mg 6.10 14.7 12.9 11.2 

PM Loading @ 7% 0 2 mg/dscm 4.46 7.51 7.21 6.39 

Grain Loading gr/dscf 0.0012 0.0027 0.0025 0.0021 

Grain Loading @ 7% 02 gr/dscf 0.0019 0.0033 0.0031 0.0028 

Particulate Matter Standard = 34 mg/dscm @ 7% 02 

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ENSR 

Table 3-7 Emission Results for Particulate Matter - June 2006 

Run No. Run 1 Run 2 Run 3 

Date 19-Jun-06 20-Jun-06 21-Jun-06 

Start Time Units 15:12 10:06 10:06 

Stop Time 17:29 12:29 12:44 AVGS 

Sampling Parameters --

Barometric Pressure in. Hg 29.55 29.55 29.50 29.53 

Volume Metered dcf 78.244 82.902 81.745 80.964 

Volume of Gas Collected dscf 72.247 76.482 75.573 74.768 

Moisture % v/v 46.7 47.8 45.5 46.7 

0 2 at Stack %dry 10.00 8.20 9.60 9.27 

C 0 2 at Stack %dry 7.40 7.60 7.40 7.47 

Avg. Stack Temp. °F 386 388 386 387 

Stack Flowrate dscfm 4,730 4,915 5,114 4,920 

Isokinetics % 104 106 101 104 

Particulate Emission Results — 

Front Half Rinse g 0.0040 0.0028 0.0017 0.0 

Particulate Filter g 0.0022 0.0017 0.0016 0.0 

Total Particulate mg 6.20 4.46 3.25 4.64 

PM Loading @ 7% 0 2 mg/dscm 3.86 2.25 1.87 2.66 

Grain Loading gr/dscf 0.0013 0.00090 0.00066 0.0010 

Grain Loading @ 7% 0 2 gr/dscf 0.0017 0.0010 0.0008 0.0012 

a

 Particulate Matter Standard = 34 mg/dscm @ 7% 02 

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3-9 September 2006 
4.0 Sampling and Analytical Procedures 

ENSR 

4.1 Sampling Procedures 

Several different sampling and monitoring techniques were used to provide the required data to 

meet the goals of this test program. Three (3) runs each were conducted on Unit 3 for EPA Method 

0023A, EPA Method 29, and EPA Method 5. The sampling activities described below were 

conducted during all runs. All field activities were documented in accordance with EPA accepted 

procedures and copies of all field notes and data sheets are included in Appendix B of this report. 

4.1.1 Velocity, Moisture and Fixed Gas Determinations 

Gas stream velocity and temperature were determined in conjunction with each manual sampling 

method. A type "S" pitot tube connected to an inclined water manometer was used to determine 

velocity head of the flue gas at each duct traverse point as specified in EPA Reference Method 2. 

The temperature profile of the flue gas at each duct traverse point was obtained by taking readings 

with a thermocouple and pyrometer concurrent with the velocity head measurements. Moisture 

content was determined as specified in EPA Method 4. Velocity and temperature measurement 

profiles were established prior to testing to aid in sample train set-up. Samples for the determination 

of the fixed gas composition were collected using the integrated bag technique detailed in EPA 

Reference Method 3. 

4.1.2 PCDD/PCDF Sampling 

Sampling for dioxins and furans was completed in accordance with EPA Method 23A (40 CFR 60, 

Appendix A). Each sampling run was 192 minutes in duration covering 16 sampling points at 12 

minutes per point. 

4.1.3 Metals and Particulate Sampling 

The EPA Multiple Metals Train (EPA Method 29,40 CFR 60 Appendix A) was utilized during the 

testing program for the collection of the following metals: arsenic, beryllium, cadmium, chromium, 

lead, and mercury. Prior to metals analyses the tared filter and front half acetone rinse were 

analyzed gravimetrically for particulate matter in accordance with EPA RM 5. Each run was 120 

minutes in duration covering 16 sampling points at 7.5 minutes per point. 

4.2 Analytical Procedures 

4.2.1 PCDD/PCDF Analyses 

PCDD/PCDF analyses were performed by Alta Analytical Laboratory, Inc. in El Dorado Hills, CA. 

Sample fractions were extracted, concentrated and analyzed by EPA Method 8290 (High 

Resolution Gas Chromatograph / High Resolution Mass Spectrophotometer (HRGC/HRMS)). The 

train fractions recovered for analysis of PCDDs/PCDFs include the front half rinse, the particulate 

filter, the back half rinse and the XAD resin trap. The analytical results for the front half and back 

half fractions were analyzed and reported separately. 

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4.2.2 Metals Analyses 

Metals analyses for the waste feed samples were completed using two separate procedures. First, 

samples were prepared and analyzed for arsenic, beryllium, cadmium, chromium, and lead as 

specified in EPA Method 6020 (ICP-MS), SW846,3r d Edition. Mercury was analyzed via method 

7471 A. Metals analyses were performed by Maxxam Analytical Inc. of Burlington, Ontario 

(Canada). 

4.3 Process Operating Conditions 

Throughout the field program, detailed process information was collected continuously by the 

facility's process control computers and data acquisition system (DAS). Process data including 

minimum, maximum and average values for key process variables recorded during each test 

condition. In general, target-operating conditions specified were achieved. 

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5.0 Quality Assurance 

5.1 Introduction 

This section presents the results of all QA/QC measures implemented during the field sampling 

program and all phases of subsequent analysis. Data generated for the program are judged to be 

valid as overall accuracy and precision results are consistent with general objectives. Analytical 

QA/QC data are presented to support all sample results used for determining compliance with 

performance criteria or emission standards. Throughout the overall program, all sampling was 

performed using sampling protocols described herein and approved by USEPA and the Illinois 

Environmental Protection Agency. 

5.1.1 Pre-Sampling Activities 

Pre-sampling activities included equipment calibration, sample media preparation, cleaning of 

sample train glassware, preparation of computer-generated sample labels and other miscellaneous 

tasks. Each of these activities are described or referenced in the following subsections. Other presampling activities included such details as team meetings, equipment packing and shipment, 

equipment setup, and finalization of all details leading up to the coordinated initiation of the sampling 

program. 

5.1.2 Equipment Calibration 

A most important aspect of pre-sampling preparations was the inspection and calibration of all 

equipment used for the field effort. Equipment was inspected for proper operation and durability 

prior to calibration. Calibration of equipment was conducted in accordance with the procedures 

outlined in the EPA document entitled "Quality Assurance Handbook for Air Pollution Measurement 

Systems; Volume III—Stationary Source Specific Methods" (EPA-600/4-77-027b). Equipment 

calibration was performed in accordance with EPA guidelines and/or manufacturer's 

recommendations. Copies of theses calibrations are presented in Appendix C. Examples of field 

equipment used and typical calibration requirements follows: 

• PROBE NOZZLES (QA Handbook Section 3.4.2, pg. 19) - measurements of the nozzle ID (to 

the nearest 0.001-in.) along three different diameters with a micrometer. Difference between 

the high and low values should not exceed 0.004 in. Post-test checks - inspect for damage. 

• PITOT TUBES (QA Handbook Section 3.1.2, pp. 1 -13) - measured for appropriate spacing and 

dimensions or calibrate in a wind tunnel. Rejection criteria given on the calibration sheet. 

Post-test checks - inspect for damage. 

• THERMOCOUPLES (QA Handbook Section 3.4.2, pp. 15-18) - verify against a mercury-in-glass 

thermometer at two or more points including the anticipated measurement range. 

Acceptance limits - impinger ±2°F; DGM ±5.4°F; stack ±1.5 percent of stack temperature. 

• DRY GAS METERS (QA Handbook Section 3.4.2, pp. 1 -12) - calibrate against a wet test meter. 

Acceptance criteria - pretest Yi = Y + 0.2; post test Y = ± 0.05 Yi. 

• FIELD BAROMETERS (QA Handbook Section 3.4.2, pp. 18-19) - compare against a mercuryin-glass barometer or use Airport Station BP and correct for elevation. Acceptance criteria -

± 0.02 in. Hg; post-test checks - same. 

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5.1.3 Glassware Preparation 

Sample train glassware and sample containers required specialized pre-cleaning to avoid 

contamination of the sample from the collection container or devices. Cleaning/storage procedures 

for sample train glassware are summarized below. Note that all bottle caps are fitted with Teflon 

liners, which were cleaned in the same manner as the bottles themselves. Sample containers used 

for waste feed streams are purchased pre-cleaned and sealed to specified EPA protocols. 

• EP A METHOD 0010 / 0023A GLASSWARE AND CONTAINERS (PCDDS/PCDFS) - washed with 

soap and water, rinsed three times with deionized (DI) water, baked at 400°C for 2-hours, 

rinsed three times with pesticide grade methylene chloride, rinsed three times with pesticide 

grade toluene and air dry. 

• EP A METHOD 5/ 29/ 0060 GLASSWARE AND CONTAINERS (METALS AND PARTICULATE MATTER) 

- washed with soap and water, rinsed with hot tap water and rinsed three times with reagent 

water. The glassware was soaked in a 10% nitric acid solution for a minimum of 4-hours, 

rinsed three times with reagent water, rinsed a final time with acetone and air-dried. All 

glassware openings where contamination can occur are covered with Parafilm until the 

sampling train was assembled prior to sampling. 

5.1.3.1 Sample Media Preparation 

All reagents were checked in accordance with ENSR's existing QC Program to minimize the 

probability of using contaminated solvents. This included the use of the proper grade 

reagents/solvents as specified in the test method, selection of reagents from the same lot and 

collection and analysis of the appropriate blanks. Sampling media was procured and prepared in 

accordance with the appropriate test methods as described below: 

• XAD resin used in the Method 0023A train was purchased new and packed in specially 

designed sorbent traps. All glass cleaning and sorbent packing procedures followed the 

protocols specified in EPA Method 0023A. 

• Quartz filters used in the Method 5/ 29 / 0060 sampling train were supplied by Maxxam 

Analytics, Inc. who pre-screen filters for metals content. 

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Appendix A 

Facility Operating Data 

S:\_JOB\2006\Onyx\Performance Test\Report\Onyx 2006 

Test Report.doc 

September 2006 
Unit #3 

) Run #1 

Date: 05/10/06 

Test Time: 09:47 to 13:51 

Run Length: 199 minutes 

PPM PPM PPM PPM 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic 

PCC High Btu 6820 0.5 0.3 0.13 2.5 1 5 

PCC Low Btu 500 0.5 0.33 0.05 2.5 ! 5 

(Chlorine Spike) 500 85.5 0.1 0.13 2.5 1 5 

PCC Sp Fdr 500 0.5 0.1 0.05 2.5 i 5 

(Chromium Spike) 500 0.5 23.4 0.13 2.5 1 1.3 

PCC Solid Charges 500 0.5 81.8 0.21 20.1 1 8.6 

(Lead Spike) 500 0.5 66.4 0.13 630000 208 6 

(Chlorine Spike) 500 63.5 96.3 0.13 2.5 1 5 

(Mercury Spike) 500 0.5 0.1 600 2.5 1 5 

Totals 
) 

Average Thermal Chlorine Ash Mercury Lead 

PPM Feed rate Loading Loading Loading Loading Loading 

lium Chromium (Ib/hr) (MMBtu/hr; (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.1 2.5 982 6.70 4.91 2.95 0.000128 0.00 

0.1 2.5 1715 0.86 8.58 5.66 0.000086 0.00 

0.1 2.5 117 0.06 100.04 0.12 0.000015 0.00 

0.1 2.5 458 0.23 2.29 0.46 0.000023 0.00 

0.1 180000 251 0.13 1.26 58.73 Q.000033 0.00 

0.29 26.1 619 0.31 3.10 506.34 0.000130 0.01 

0.1 2.5 92 0.05 0.46 61.09 0.000012 57.96 

0.1 2.5 138 0.07 87.63 132.89 0.000018 0.00 

0.1 2.5 1.35 0.00 0.01 0.00 0.000810 0.00 

4373 8.39 208.26 768.24 0.00125 57.98 
Cadmium Arsenic 

Loading Loading 

(Ib/hr) (Ib/hr) 

0.00 0.00 

0.00 0.01 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.00 0.01 

0.02 0.00 

0.00 0.00 

0.00 0.00 

Beryllium Chromium 

Loading Loading 

(Ib/hr) (Ib/hr) 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.00 45.18 

0.00 0.02 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.02 0.02 0.00 45.20 
Unit #3 

1 Run #2 

Date: 05/10/06 

Test Time: 14:51 to 18:17 

Run Length: 206 minutes 

PPM PPM PPM PPM 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic 

PCC High Btu 6720 0.56 0.28 0.13 2.5 1 5 

PCC Low Btu 500 0.5 0.32 0.05 2.5 1 5 

(Chlorine Spike) 500 85.5 0.1 0.13 2.5 1 5 

PCC Sp Fdr 500 0.5 0.1 0.05 2.5 1 5 

(Chromium Spike) 500 0.5 23.4 0.13 2.5 1 2.6 

PCC Solid Charges 500 0.5 82 0.19 19.6 1 9.5 

(Lead Spike) 500 0.5 66.4 0.13 630000 221 1.6 

(Chlorine Spike) 500 63.5 96.3 0.13 2.5 1 5 

(Mercury Spike) 500 0.5 0.1 600 2.5 1 5 

Totals 
Average Thermal Chlorine Ash Mercury Lead 

PPM Feed rate Loading Loading Loading Loading Loading 

Hum Chromium (Ib/hr) (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.1 2.5 992 6.67 5.56 2.78 0.000129 0.00 

0.1 2.5 1681 0.84 8.41 5.38 0.000084 0.00 

0.1 2.5 100 0.05 85.50 0.10 0.000013 0.00 

0.1 2.5 461 0.23 2.31 0.46 0.000023 0.00 

0.1 180000 255 0.13 1.28 59.67 0.000033 0.00 

0.43 28.1 719 0.36 3.60 589.58 0.000137 .0.01 

0.1 2.5 108 0.05 0.54 71.71 0.000014 68.04 

0.1 2.5 161 0.08 102.24 155.04 0.000021 0.00 

0.1 2.5 1.58 0.00 0.01 0.00 0.000948 0.00 

4479 8.41 209.42 884.72 0.00140 68.06 
Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading 

(Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.02 

0.00 

0.00 

0.00 

0.01 

0.00 

0.00 

0.00 

0.01 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

45.90 

0.02 

0.00 

0.00 

0.00 

0.03 0.02 0.00 45.93 
Unit #3 

! Run #3 

Date: 05/11/06 

Test Time: 11:25 to 14:48 

Run Length: 203 minutes 

PPM PPM PPM PPM 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic 

PCC High Btu 7630 0.66 0.28 0.13 2.5 1 5 

PCC Low Btu 500 0.5 0.31 0.05 2.5 1 5 

(Chlorine Spike) 500 85.5 0.1 0.13 2.5 1 5 

PCC Sp Fdr 500 0.5 0.1 0.05 2.5 1 5 

(Chromium Spike) 500 0.5 23.4 0.13 2.5 1 2 

PCC Solid Charges 500 0.5 82.6 0.35 36.8 1 11.2 

(Lead Spike) 500 0.5 66.4 0.13 630000 283 9.1 

(Chlorine Spike) 500 63:5 96.3 0.13 150 1 5 

(Mercury Spike) 500 0.5 0.1 600 2.5 1 5 

Totals 
Average Thermal Chlorine Ash Mercury Lead 

PPM PPM Feedrate Loading Loading Loading Loading Loading 

Beryllium Chromium (Ib/hr) (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (ib/hr) 

0.1 2.5 1000 7.63 6.60 2.80 0.000130 0.00 

0.1 2.5 1931 0.97 9.66 5.99 0.000097 0.00 

0.1 2.5 92 0.05 78.66 0.09 0.000012 0.00 

0.1 2.5 448 0.22 2.24 0.45 0.000022 0.00 

0.1. 180000 245 0.12 1.23 57.33 0.000032 0.00 

0.9 26.3 723 0.36 3.62 597.20 0.000253 0.03 

0.1 1.3 106 0.05 0.53 70.38 0.000014 66.78 

0.1 2.5 158 0.08 100.33 152.15 0.000021 0.02 

0.1 2.5 1.55 0.00 0.01 0.00 0.000930 0.00 

4705 9.48 202.86 886.39 0.00151 66.84 
Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading 

(Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.00 0.01 0.00 0.00 

0.00 0.01 0.00 0.00 

0.00 0.00 0.00 0.00 

0.00 0.00 0.00 0.00 

0.00 0.00 0.00 44.10 

0.00 0.01 0.00 0.02 

0.03 0.00 0.00 0.00 

0.00 0.00 0.00 0.00 

0.00 0.00 0.00 0.00 

0.03 0.03 0.00 44.13 
Unit #3 

Run #1 

Date: 06/19/06 

Test Time: 14:40 to 18:05 

Run Length: 205 minutes 

PPM PPM PPM PPM 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic 

PCC High Btu 9930 3.2 1.5 0.413 18.8 1.98 2.5 

PCC Low Btu 500 0.5 0.2 0.0202 1.27 0.0372 0.272 

(Chlorine Spike) 3170 85.5 0.1 0.011 0.1 0.02 0.2 

PCC Sp Fdr 500 0.5 0.1 0.00035 1.38 0.0052 12.1 

(Chromium Spike) 500 0.5 25.9 0.002 800 970 880 

PCC Solid Charges 880 0.6 70.6 0.025 12.93 0.30 6.73 

(Lead Spike) 500 0.5 65.6 0.02 630000 27 25 

(Chlorine Spike) 500 63.5 97.4 0.02 170 5 25 

(Mercury Spike) 500 0.5 0.1 646 0.1 0.02 0.2 

Totals 
) 

Average Thermal Chlorine Ash Mercury Lead 

PPM Feedrate Loading Loading Loading Loading Loading 

lium Chromium (Ib/hr) (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.1 13.3 1110 11.02 35.52 16.65 0.000458 0.02 

1.001 0.462 1896 0.95 9.48 3.79 0.000038 0.00 

0.05 0.04 95 0.30 81.23 0.10 0.000001 0.00 

0.01 0.0121 569 0.28 2.85 0.57 0.000000 0.00 

960 180000 251 0.13 1.26 65.01 0.000001 0.20 

0.37 157.81 798 0.70 4.71 563.74 0.000020 0.01 

4.8 2 119 0.06 0.60 78.06 0.000002 74.97 

2.5 2 179 0.09 113.67 174.35 0.000004 0.03 

0.05 0.04 1.75 0.00 0.01 0.00 0.001131 0.00 

5019 13.53 249.30 902.27 0.00166 75.24 
Cadmium 

Loading 

(Ib/hr) 

0.00 

0.00 

0.00 

0.00 

0.24 

0.00 

0.00 

0.00 

0.00 

Arsenic 

Loading 

(Ib/hr) 

0.00 

0.00 

0.00 

0.01 

0.22 

0.01 

0.00 

0.00 

0.00 

Beryllium 

Loading 

(Ib/hr) 

0.00 

0.00 

0.00 

0.00 

0.24 

0.00 

0.00 

0.00 

0.00 

Chromium 

Loading 

(Ib/hr) 

0.01 

0.00 

0.00 

0.00 

45.18 

0.13 

0.00 

0.00 

0.00 

0.25 0.24 0.24 45.32 
Unit #3 

) Run #2 

Date: 06/20/06 

Test Time: 09:30 to 13:05 

Run Length: 215 minutes 

PPM PPM PPM PPM 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic 

PCC High Btu 9000 2.3 4.9 0.413 4 0.35 2.5 

PCC Low Btu 500 0.5 0.2 0.00192 0.04 0.0034 0.253 

(Chlorine Spike) 3170 85.5 0.1 0.014 0.1 0.02 0.2 

PCC Sp Fdr 500 0.5 0.1 0.0002 0.0914 0.002 0.186 

(Chromium Spike) 500 0.5 25.9 0.002 100 20 200 

PCC Solid Charges 824 0.6 69.9 0.038 16.45 0.37 6.25 

(Lead Spike) 500 0.5 65.6 0.02 630000 32 25 

(Chlorine Spike) 500 63.5 97.4 0.02 42 5 25 

(Mercury Spike) 500 0.5 0.1 646 0.1 0.02 0.2 

Totals 
Average Thermal Chlorine Ash Mercury Lead 

PPM PPM Feedrate Loading Loading Loading Loading Loading 

Beryllium Chromium (Ib/hr) (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.1 13 1126 10.13 25.90 55.17 0.000465 0.00 

0.001 0.0579 1959 0.98 9.80 3.92 0.000004 0.00 

0.05 0.046 102 0.32 87.21 0.10 0.000001 0.00 

0.001 0.0116 543 0.27 2.72 0.54 0.000000 0.00 

50 180000 250 0.13 1.25 64.75 0.000001 0.03 

0.31 11.88 805 0.66 4.96 563.01 0.000030 0.01 

7.8 2 117 0.06 0.59 76.75 0.000002 73.71 

2.5 2 176 " 0.09 111.76 171.42 0.000004 0.01 

0.05 0.04 1.72 0.00 0.01 0.00 0.001111 0.00 

5080 12.64 244.18 935.67 0.00162 73.76 
Cadmium 

Loading 

(lb/hr) 

0.00 

0.00 

0.00 

0.00 

0.01. 

0.00 

0.00 

0.00 

0.00 

Arsenic 

Loading 

(Ib/hr) 

0.00 

0.00 

0.00 

0.00 

0.05 

0.01 

0.00 

0.00 

0.00 

Beryllium 

Loading 

(Ib/hr) 

0.00 

0.00 

0.00 

0.00 

0.01 

0.00 

0.00 

0.00 

0.00 

Chromium 

Loading 

(Ib/hr) 

0.01 

0.00 

0.00 

0.00 

45.00 

0.01 

0.00 

0.00 

0.00 

0.01 0.07 0.01 45.02 
Unit #3 

) Run #3 

Date: 06/21/06 

Test Time: 09:30 to 13:19 

Run Length: 229 minutes 

PPM PPM PPM PPM 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic 

PCC High Btu 10220 3.1 0.4 0.679 3.85 0.83 6.77 

PCC Low Btu 500 0.5 0.2 0.00184 0.04 0.0054 0.257 

(Chlorine Spike) 3170 85.5 0.1 0.0045 0.1 0.02 0.2 

PCC Sp Fdr 500 0.5 0.1 0.0002 0.0432 0.002 0.0709 

(Chromium Spike) 500 0.5 25.9 0.002 100 20 200 

PCC Solid Charges 793 0.5 70.8 0.157 18.46 0.44 5.76 

(Lead Spike) 500 0.5 65.6 0.02 630000 42 25 

(Chlorine Spike) 500 63.5 97.4 0.02 18 5 25 

(Mercury Spike) 500 0.5 0.1 646 0.1 0.02 0.2 

Totals 
Average Thermal Chlorine Ash Mercury Lead 

PPM PPM Feed rate Loading Loading Loading Loading Loading 

Beryllium Chromium (Ib/hr) (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

0.1 5.74 1079 11.03 33.45 4.32 0.000733 0.00 

0.001 0.0586 2039 1.02 10.20 4.08 0.000004 0.00 

0.05 0.04 96 0.30 82.08 0.10 0.000000 0.00 

0.001 0.0408 547 0.27 2.73 0.55 0.000000 0.00 

50 180000 249 0.12 1.25 64.49 0.000000 0.02 

0.35 12.47 815 0.65 4.31 577.29 0.000128 0.02 

8.1 2 119 0.06 0.60 78.06 0.000002 74.97 

2.5 2 178 0.09 113.03 173.37 0.000004 0.00 

0.05 0.04 1.74 0.00 0.01 0.00 0.001124 0.00 

5124 13.55 247.65 902.25 0.00200 75.02 
Cadmium Arsenic 

Loading Loading 

(Ib/hr) (Ib/hr) 

0.00 0.01 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.00 0.05 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.00 0.00 

Beryllium Chromium 

Loading Loading 

(Ib/hr) (Ib/hr) 

0.00 0.01 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.01 44.82 

0.00 0.01 

0.00 0.00 

0.00 0.00 

0.00 0.00 

0.01 0.07 0.01 44.84 
) 

Unit 3 Operating.Parameters 

June, 2006 

Baghouse Inlet Temp. (Deg F) 

(Ave. of test run ave.'s) 

PCC Temp. (Deg F) 

(Ave. of test run ave.'s) 

SCC Temp. (Deg F) 

(Ave. of test run ave.'s) 

Stackflow (ACFM) 

(Ave. of max. HRA's of each test run) 

Pumpable Waste Feed (Lb/hr) 

(Ave. of max. HRA's of each test run) 

(Includes average spiked liquids flows) 

Total Waste Feed (Lb/hr) 

(Ave. of max. HRA's of each test run) 

(Includes average spiked liquids flows) 

Mercury Feed (Lb/hr) 

(Ave. of test run ave.'s) 

Ash Feed (Lb/hr) 

(Ave. of test run ave.'s) 

LVM Feed (Lb/hr) 

(Ave. of test run ave.'s) 

SVM Feed (Lb/hr) 

(Ave. of test run ave.'s) 

Chlorine Feed (Lb/hr) 

(Ave. of test run ave.'s) 

Run 1 Run 2 Run 3 Average 

420 421 421 420 

1735 1725 1741 1734 

1845 1850 1851 1849 

14888 15349 15267 15168 

4147 4161 4172 4160 

346 352 345 na 

5273 5367 5391 5344 

346 352 345 na 

0.0017 0.0016 0.0020 0.0018 

902 936 902 913 

46 45 45 45 

7 5 ' 74 75 75 

249 244 248 247 
Unit 3 Operating Parameters 

May, 2006 

Run 1 

420 

1713 

1845 

14873 

3718 

368 

AIM 

368 

0.0013 

768 

45 

58 

208 

Run 2 

420 

1715 

1845 

15428 

3683 

355 

4862 

355 

0.0014 

885 

46 

68 

209 

Run 3 

420 

1712 

1846 

14468 

3800 

337 

4793 

337 

0.0015 

886 

44 

67 

203 

Average 

420 

1713 

1845 

14923 

3734 

na 

4791 

na 

0.0014 

846 

45 

64 

207 
ENSR 

Appendix B 

Reference Method Field Data and Calculations 

S:\_JOB\2006\Onyx\Performance Test\Report\Onyx 2006 

Test Report.doc 

September 2006 
May 2006 Test 
) 

Particulate Matter Data 
Veolia ES Technical Solutions 

Fixed Hearth Incinerator #3 

Method 5 Sampling Parameters 

Run No. Run 1 Run 2 Run 3 

AVGS 

Date 10-May-06 io-May-06 11-May-06 

AVGS 

Start Time Units 10:08 15:00 11:25 

Stop Time 12:51 17:16 13:39 AVGS 

Nozzle Diameter inches 0.412 0.440 0.440 0.431 

Barometric Pressure in. Hg 29.10 29.02 29.05 29.06 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 81.991 84.128 81.699 82.606 

Avg. DGM Temp. °F 85.9 72.5 77.1 78.5 

Avg Delta H in H2 0 1.57 1.73 1.56 1.62 

Avg Delta H in. Hg 0.1158 0.1274 0.1146 0.1193 

DGM Calibration Factor -

1.0270 1.0270 1.0270 1.0270 

Gas Sample Volume dscf 79.526 83.462 80.402 81.130 

Total Water Collected mL 1344.7 1438.7 1343.8 1375.7 

Volume of Water Vapor scf 63.403 67.835 63.360 64.866 

Moisture (measured) % v/v 44.4 44.8 44.1 44.4 

Moisture (@ saturation) % v/v I 102.8 103.0 103.0 102.9 

Dry Mole Fraction, 100-%M -

0.5564 0.5516 0.5593 0.5558 

C Oz at Stack %dry 6.40 6.80 7.00 6.73 

0 2 at Stack %dry 12.50 9.40 10.00 10.63 

CO + N2 %dry 81.10 83.80 83.00 82.63 

Dry Molecular Weight Ib/lb-mole 29.52 29.46 29.52 1 29.50 

Wet Molecular Weight Ib/lb-mole 24.41 24.32 24.44 24.39 

Excess Air at Stack % 140.3 73.9 83.9 99.4 

Stack Diameter inches 39.0 39.0 39.0 39.0 

Stack Area sq. in. 1194.6 1194.6 1194.6 1194.6 

Static Pressure in H2 0 0.22 0.22 0.07 0.17 

Stack Pressure inHg 29.12 29.04 29.06 29.07 

Avg. Stack Temp. °F 376.4 366.2 364.3 369.0 

Avg. Sqroot of Delta P — 0.4125 0.4145 0.3946 0.4072 

SDE Average — 11.931 11.915 11.330 11.725 

Pitot Coefficient — 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,928 1,932 1,832 1,897 

Stack Flowrate wet acfm 15,998 16,027 15,198 15,741 

Stack Flowrate wet scfm 9,827 9,940 9,453 9,740 

Stack Flowrate dscfm 5,468 5,483 5,287 5,413 

Isokinetics % 109 100 100 103 

Meter Box No. — 80610 80610 80610 — 

Delta H @ in HaO 1.803 1.803 1.803 --

Field QA Yqc — 1.0465 1.0591 1.0375 1.0477 

[Deviation] Pre-Y % 1.90% 3.13% 1.02% 2.02% 

S:\_JOB\2006\OnyiAPetformance TesRTest 0ata\Otiyx May 2006\(MS PM #3 May 2006 day 2.xls]DATA 
Metho

d 5 Sampling Parameters 

PT 

Runl Ru

n 2 Run 3 

PT Delta P SQRT 

Delta P 

DGM IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM IN 

DGM 

OUT 

Delta H STACK 

TEMP 

a1 0.15 0.3873 

70 

70 1.38 346 0.18 0.4243 

76 

75 1.90 370 0.13 0.3606 70 69 1.30 350 

a2 0.20 0.4472 

77 

72 1.81 378 0.20 0.4472 

75 

74 1.99 370 0.16 0.4000 74 69 1.58 364 

a3 0.20 0.4472 

82 

74 1.81 378 0.21 0.4583 

76 73 2.09 368 0.17 0.4123 77 70 1.68 369 

a4 0.21 0.4583 

85 75 1.89 388 0.20 0.4472 

77 

72 1.99 366 0.19 0.4359 

80 71 1.88 369 

a5 0.20 0.4472 

86 

80 1.82 390 0.19 0.4359 

75 71 1.90 363 0.17 0.4123 81 72 1.70 368 

a6 0.18 0.4243 

90 

82 1.66 374 0.19 0.4359 

71 

69 1.90 364 0.16 0.4000 82 73 1.60 362 

a7 0.15 0.3873 

92 

82 1.38 375 0.15 0.3873 

76 

69 1.50 362 0.16 0.4000 83 74 1.60 364 

a8 0.11 0.3317 

93 

83 1.02 374 0.11 0.3317 

76 

69 1.10 363 0.14 0.3742 

83 75 1.40 365 

b1 0.16 0.4000 

86 

84 1.48 374 0.12 0.3464 

69 

68 1.20 365 0.15 0.3873 75 74 1.50 363 

b2 0.18 0.4243 

93 

85 1.67 377 0.16 0.4000 

74 

68 1.60 365 0.17 0.4123 80 75 1.70 366 

b3 0.18 0.4243 

94 

86 1.67 378 0.18 0.4243 

75 68 1.80 365 0.17 0.4123 83 75 1.70 366 

b4 0.16 0.4000 

96 

88 1.48 379 0.18 0.4243 

76 

69 1.80 366 0.17 0.4123 84 76 1.70 365 

b5 0.18 0.4243 

96 

88 1.66 379 0.18 0.4243 

75 

68 1.80 364 0.16 0.4000 84 76 1.60 365 

b6 0.19 0.4359 

96 

88 1.75 378 0.20 0.4472 

76 68 1.98 372 0.15 0.3873 85 77 1.50 368 

b7 0.15 0.3873 

97 

90 1.39 378 0.18 0.4243 

77 

68 1.78 372 0.13 0.3606 

82 77 1.30 364 

b8 0.14 0.3742 

98 

91 1.32 377 0.14 0.3742 

78 68 1.40 364 0.12 0.3464 84 77 1.20 ' 361 

AVG 0.17 0.4125 85.9 1.57 376 0.17 0.4145 72.5 1.73 366 0.16 0.3946 77.1 1.56 364 
ENS. MtCO M EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

LEAK CHECKS: 

SAMPLING TRAIN: M5/ Particulate BAROMETRIC PRESSURE: INITIAL VAC. In. CFM . 00 6 

PLANT: ONYX Environmental STATIC PRESSURE (+/-): 22. MID VAC. In. CFM 

DATE: Probe/Pltot Number: A5 - S-W FINAL VAC. in. CFM 003 

TEST LOCATION: Unit #3 Fixed Hearth Pitot Coefficient: 0.84 

RUN NUMBER: Rl Filter Box No.: 14 ft. ? v 

ya 3" 

Stack Diameter - Inches: 39" Meter Box Number: 5 tOUD INIT. PITOT V yFILTER DATA 

Orifice Coefficient (Y): .or? FINAL PITOT y y iNUMBBRi. 

OPERATOR: Delta H@: 1. Mi 3931 

START TIME: loOS Nozzle Size: ORSAT Initial: 

STOP TIME: U 5 i XAD Thermocouple ID: ORSAT Final: 

Impinger Outlet ID: 

IMPINGER VOL'S: 

JNIT,^;FINAL.. 

SAMPLE 

POINT 

CLOCK 

TIME 

VELOCITY : 

HEAD 

ORIFICE 

METER VOL. 

GAS METER 

VOLUME 

. «« 

TEMPERATURE READINGS, °F PUMP 

VACUUM COMMENTS 

SAMPLE 

POINT 

CLOCK 

TIME 

VELOCITY : 

HEAD 

ORIFICE 

METER VOL. 

GAS METER 

VOLUME 

. «« 

STACK • PROBE ,:<: FILTER BOX 

, »*»..,. 

IMPINGER 

. 

XAD Trap 

.,.«•* . . 

GAS METER ' i 

PUMP 

VACUUM COMMENTS 

SAMPLE 

POINT 

CLOCK 

TIME 

VELOCITY : 

HEAD 

ORIFICE 

METER VOL. 

GAS METER 

VOLUME 

. «« 

STACK • PROBE ,:<: FILTER BOX 

, »*»..,. 

IMPINGER 

. 

XAD Trap 

.,.«•* . . 

IN.,,.. QUT...I 

PUMP 

VACUUM COMMENTS 

,M 0 1.3? tl 70 *( 

? 7-5 •Oft I.ftl ,17ft 53 asi 77 75 H 

"> K .an L 9 \ Hlfc. 1 37fi 3 53 1^ H 

M ^ 1 i-<3^ H3I.5 39S> S( 270 ss 7 f H 

5 3 9 0 268 SO H 

(, .If. 5 •IS 3 W Mi. qo 

7 137.<? 37S S3 Ht 

2 •w 1.6,3 N^. 7 311 a 50 5 f a7R 

t> 1 |.<*0 a w 5!? 

A U.5 . \ K (-d>1 s s i .q 311 3 5/5 H 9 ^ £ > ((SI res W 

T> • «S 1-G7 151. a T?7S? 2S | 5{ <w »t 

% sa.s . ((P i.HS a s i S 3 i t Si 9 H 

5 . < « U b 3-H £H % «2 H 

L u s •Ii L15 m;. s 37/? a S l 9 * 

7 103 .15 l.3<) SIS .2 51 aM7 Ga ,a<u <n 10 *) \H \.3 3 377 <I4 K 

i 

aaaa'tiaaiai 

100 

100 

m . 

3 3 3 

a n 

Final Vol. 

Volumes 

ORSAT DATA 

F O R MOISTURE CALC : 

N E T GAIN: (^M't l ml. 
ENSRI AECO M EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

SAMPLING TRAIN: 

PLANT: 

DATE: 5/10/2006 

TEST LOCATION: 

RUN NUMBER: R2 

Stack Diameter - inches: 

OPERATOR: 

START TIME: 

STOP TIME: 

M5 BAROMETRIC PRESSURE: 

Onyx STATIC PRESSURE (+/-): 

Probe/Eitot Number: 

Unit #3 Pitot Coefficient: 

• Filter Box No.: 

39 Meter Box Number: 

Orifice Coefficient (Y): 

J. Gorman Delta H@: 

I 5QQ Nozzle Size: 

[ 1 )(? XAD Thermocouple ID: 

2<\ -03 

JU. 

*5.-S-H . 

INITIAL VAC. 

MID VAC. 

FINAL VAC. 

LEAK CHECKS: 

14 in. CF M 0.003 

in. CFM ____ _ 

& In. CF M ,CQ 3 

0.84 

80610 

1.027 

1.803 

0.440 

-nSTC-S 

INIT. PITOT 

FINAL PITOT 

ORSAT Initial: 

ORSAT Final: 

/ ^ FIL 

1 7 

FILTER DATA 

NUMBER* TARE 

SAMPLE: 

•POINT TIME 

•* . '-' ''Y 

VELOCITY 

- ' HEAD • ; 

©ertaft Inwc-

•"• ORIFICE., 

METER yet: 

,,D«lt»H, m'yrc 

GAS MEIER '': 

;.,/- Yp|iJME' .". 

TEMPERATURE READINGS, °F •

1 

•

 1 PUMP 

•.'.VACUUM:. 

..i'in.Ho, 

'" . "- V-N^COMMENT S •;..,<;• -v - • - . 

SAMPLE: 

•POINT TIME 

•* . '-' ''Y 

VELOCITY 

- ' HEAD • ; 

©ertaft Inwc-

•"• ORIFICE., 

METER yet: 

,,D«lt»H, m'yrc 

GAS MEIER '': 

;.,/- Yp|iJME' .". . * STACK, • PROBE . .fJLTER BOX 

; • . 

IMPINGER V , ,*.Fil>r puttat ' '. -•. GAS METER " . 

•

 1 PUMP 

•.'.VACUUM:. 

..i'in.Ho, 

'" . "- V-N^COMMENT S •;..,<;• -v - • - . 

SAMPLE: 

•POINT TIME 

•* . '-' ''Y 

VELOCITY 

- ' HEAD • ; 

©ertaft Inwc-

•"• ORIFICE., 

METER yet: 

,,D«lt»H, m'yrc 

GAS MEIER '': 

;.,/- Yp|iJME' .". . * STACK, • PROBE . .fJLTER BOX 

; • . 

IMPINGER V , ,*.Fil>r puttat ' 

. OUT , .. 

•

 1 PUMP 

•.'.VACUUM:. 

..i'in.Ho, 

A1 0 l« l.1_ 370 211 i t 7 5 w A2 7.50 \M 4*3. q 370 2 Si? 75 Tf 

A3 15.00 WW .to 2.50 1% 5t 7fe 75 

M 22,50 ao 265, Y 3.52L 2Hfi 5 6 17 7.7 H 

A5 30.00 6>a 7 5 • 71 

Afi 37.50 i.q bib. 5 2M§ 6 3 2<U 71 6<l 

A7 45.00 15 1.5 J W 253 5ft lb 4 

A8 52.50 •M 3t>3 250 a s o 76 *f ^o?M Q flo^i fort- CUAijf 

B1 90.00 

• a i i •3 31. ^ 3 6 5 ^ S l i n <i 

82 67.50 i t s a n 7V 

B3 75.00 ? 1.9 $ ^ 0 .is St>5 2 50 7 5 «1i * 

BA 82.50 •is 2 Co u 2 76 -76 i. 

B5 90.00 

•IR S S I .'5 1 a 52 f t •75 L 

B6 97.50 1 - 98 SSfe . T XI 7lX 76 ' 5 

B7 105.00 

\l 11JL s o 77 rf 5 

BS 112.50 %y 2 5'0 2,41 7 5 

120.00 

i 

.; ...IMPINGER VOLS. ! Rinse 

.INII.... FINAL/ ^Volumes 

0 

100 

100 \% 

0 10 

m 

SILICA GEL 

2.51.0 m i 

ORSAT DATA 

cof 'Oa.-., 

FOR MOISTURE CALC : 
ENSk i AI£C O EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

SAMPLING TRAIN: M5/ Particulate 

PLANT: ONYX Environmental 

DATE: 

TEST LOCATION: 

RUN NUMBER: 

Stack Diameter - inches: 

OPERATOR: 

START TIME: 

STOP TIME: 

Unit S3 Fixed Hearth 

39" 

1339 

BAROMETRIC PRESSURE: 

STATIC PRESSURE (+/•): 

Probe/Pltot Number: 

Pilot Coefficient: 

Filter Box No.: 

Meter Box Number: 

Orifice Coefficient (Y): 

Delta H@: 

Nozzle Size: 

XAD Thermocouple ID: 

Impinger Outlet ID: 

INITIAL VAC. 

MID VAC. 

FINAL VAC. 

^LEAK CHECKS: 

\b In. CFM 

0.84 

HB-a. 

i on 

ns TC-3 

INIT. PITOT 

" FINAL PITOT 

ORSAT Initial: 

ORSAT Final: 

i t 

In. CFM 

(p in. CFM , (jfli/ ' 

7 " / FILTER DATA 

.sNMMBERai 

./SAMPLE.! 

POINT 

CLOCK 

TIME 

VELOCITY 

HEAD 

ORIFICE 

METER VOL. 

GAS METER 

VOLUME 

.. ..If. 

TEMPERATURE READINGS, °F PUMP 

VACUUM 

...A m Ha ,. 

COMMENTS 

./SAMPLE.! 

POINT 

CLOCK 

TIME 

VELOCITY 

HEAD 

ORIFICE 

METER VOL. 

GAS METER 

VOLUME 

.. ..If. 

.STACK PROBE 

. .»wa» .. 

FILTER BOX 

.. *»«? ... 

IMPINGER FirtgJBItrf GASMETER"' ' 

PUMP 

VACUUM 

...A m Ha ,. 

COMMENTS 

./SAMPLE.! 

POINT 

CLOCK 

TIME 

VELOCITY 

HEAD 

ORIFICE 

METER VOL. 

GAS METER 

VOLUME 

.. ..If. 

.STACK PROBE 

. .»wa» .. 

FILTER BOX 

.. *»«? ... 

IMPINGER FirtgJBItrf ..IN , ., , .,.,O.UT ; 

PUMP 

VACUUM 

...A m Ha ,. 

COMMENTS 

K | 0 •13 l . f 575. 7 I* 350 S$i D SQ t,0 230. 10 fi9' 

7-5 • 10, L S S 577. 3 a 56 24<) 45 I f /,<? • f 

3 15 

''1 (.6,8 251 249 Ht ,2*3 77 7£ w 

4 :?as • rt s m 2.531 2Hi 50 ?L\ ao 71 4 5 •o 1.7 593 3 36 fl 25 2 M l SH 7M 91 7* . 

37.5 u 598-7 25 347 U 211 $2 73 Y 

7 4 5 (,03 0 iw .250 248 276 43 74 Y S 1.4 3t5 251 244 54 2SI 75 | ~ i — 

<&>*4

 ! 

B i t o • 5 1.5 3 ^ 2S3 56 2 4f> 7 5 74

 ! 

•P 1.1 C>($ • 9 *52 21.7 SO 75

 1 

J '75 •n 1.7 U4.I .!(,(, 

* 5 | 2-50 H7 219 <?3 7 5

 ; 

4 .i i I.7 C29.S lis 251 2.1ft 4fl 280 7fe "4 s TO 'Id l.u U 4 . 9 251 a48 52 279 S4 7& f 

<o S7.5 l . b &4D.2 3&J? 251 -247 55 214 55 71 > V 

7 IP5 (o45./ 2f0 ana fc4 X5(o 82 71 ! -4—" 

8 IU.5 •1? 1.3 G49.9 A 50 248 5 3 2t0 $4 77 1 

120 (.51. Mi l 

IMPINGER VOLS Rinse 

.. INIT*. 1 FJ NAL ! Volumes 

0 

100 370 

, 100 

I $2 0 O 

24i>.4 

Final Vol. 

22U 

ORSAT DATA 

FOR MOISTURE CALC.: 

NET GAIN: 1743 $ ml. 
J 

Metals Data 
Veolia ES Technical Solutions 

Fixed Hearth Incinerator #3 

Method 0060 (Metals) Sampling Parameters 

Run No. Run 1 Run 2 Run 3 

AVGS 

Date 10-May-06 10-May-06 11-May-06 

AVGS 

Start Time Units 10:08 15:00 11:25 

Stop Time 12:51 17:16 13:39 AVGS 

Nozzle Diameter inches 0.408 0.431 0.431 0.423 

Barometric Pressure in. Hg 29.10 29.02 29.05 29.06 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 81.248 83.546 76.761 80.518 

Avg. DGM Temp. °F 86.8 71.2 78.0 78.7 

Avg Delta H in H2 0 1.57 1.76 1.42 1.58 

Avg Delta H in. Hg 0.1156 0.1292 0.1041 0.1163 

DGM Calibration Factor -

1.0390 1.0390 1.0390 1.0390 

Gas Sample Volume dscf 79.598 84.056 76.269 79.974 

Total Water Collected mL 1271.1 1380.4 1300.2 1317.2 

Volume of Water Vapor scf 59.932 65.086 61.304 62.108 

Moisture (measured) % v/v 43.0 43.6 44.6 43.7 

Moisture (@ saturation) % v/v 102.8 103.0 103.0 102.9 

Dry Mole Fraction, 100-%M — 0.5705 0.5636 0.5544 0.5628 

C 0 2 at Stack %dry 6.40 6.80 7.00 6.73 

0 2 at Stack %dry 12.40 9.40 10.00 10.60 

CO + N 2 %dry 81.20 83.80 83.00 82.67 

Dry Molecular Weight Ib/lb-mole 29.52 29.46 29.52 29.50 

Wet Molecular Weight Ib/lb-mole 24.57 24.46 24.39 24.47 

Excess Air at Stack % 137.2 73.9 83.9 98.3 

Stack Diameter inches 39.0 39.0 39.0 39.0 

Stack Area sq. in. 1194.6 1194.6 1194.6 1194.6 

Static Pressure in H2 0 0.22 0.21 0.07 0.17 

Stack Pressure in. Hg 29.12 29.04 29.06 29.07 

Avg. Stack Temp. °F 381.2 371.1 371.4 374.6 

Avg. Sqroot of Delta P — 0.4128 0.4235 0.3843 0.4069 

SDE Average — 11.972 12.209 11.082 11.754 

Pitot Coefficient — 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,929 1,974 1,794 1,899 

Stack Flowrate wet acfm 16,001 16,377 14,883 15,753 

Stack Flowrate wet scfm 9,774 10,097 9,178 9,683 

Stack Flowrate dscfm 5,576 5,691 5,088 5,451 

Isokinetics % 109 101 102 104 

Meter Box No. — 80184 80184 80184 --

Delta H @ in H2 0 1.8810 1.8810 1.8810 -

Field QA Yqc — 1.0340 1.0500 1.0313 1.038 

[Deviation] Pre-Y % 0.48% 1.06% 0.74% 0.8% 
Method 0060 (Metals) Sampling Parameters 

PT 

a1 

b1 

AVG 

Runl AVGSMETALS 

Delta P SQRT 

Delta P 

0.15 0.3873 

0.20 0.4472 

0.20 

0.21 

0.4472 

0.4583 

0.21 0.4583 

0.18 0.4243 

0.15 0.3873 

0.11 

0.14 

0.17 

0.20 

0.18 

0.18 

0.20 

0.15 

0.12 

0.17 

0.3317 

0.3742 

0.4123 

0.4472 

0.4243 

0.4243 

0.4472 

0.3873 

0.3464 

0.4128 

DGM 

IN 

73 

78 

81 

84 

88 

89 

90 

91 

88 

93 

94 

95 

95 

96 

96 

97 

86.8 

DGM 

OUT 

72 

74 

75 

77 

83 

84 

85 

85 

86 

87 

88 

89 

90 

91 

91 

92 

Delta H 

1.38 

1.80 

1.80 

1.92 

1.92 

1.65 

1.40 

1.00 

1.30 

1.56 

1.80 

1.65 

1.65 

1.80 

1.40 

1.12 

1.57 

STACK 

TEMP 

366 

379 

381 

385 

382 

383 

382 

381 

367 

385 

386 

386 

386 

385 

383 

382 

381 

Run2 AVGS--METALS Run 3 AVGS — META LS 

Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H | STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

0.12 0.3464 79 77 1.20 359 0.16 0.4000 71 71 1.50 367 

0.21 0.4583 76 75 2.00 375 0.17 0.4123 75 71 1.60 372 

0.20 0.4472 74 74 1.90 376 0.18 0.4243 77 72 1.70 373 

0.21 0.4583 72 73 2.00 376 0.17 0.4123 79 72 1.60 373 

0.21 0.4583 72 71 2.00 373 0.16 0.4000 80 74 1.50 374 

0.20 0.4472 70 68 1.90 371 0.15 0.3873 81 75 1.45 373 

0.17 0.4123 71 68 1.60 368 0.12 0.3464 81 76 1.15 372 

0.12 0.3464 72 68 1.20 367 0.10 0.3162 81 76 0.95 357 

0.15 0.3873 69 68 1.45 358 0.12 0.3464 78 77 1.15 369 

0.17 0.4123 72 68 1.60 371 0.16 0.4000 81 77 1.55 366 

0.20 0.4472 73 69 1.90 375 0.18 0.4243 83 78 1.70 374 

0.17 0.4123 72 68 1.60 376 0.17 0.4123 83 78 1.60 375 

0.20 0.4472 71 67 1.90 376 0.15 0.3873 83 79 1.45 375 

0.20 0.4472 72 68 1.90 376 0.15 0.3873 83 79 1.45 375 

0.19 0.4359 73 68 1.80 376 0.12 0.3464 82 79 1.15 374 

0.17 0.4123 73 68 1.60 364 0.12 0.3464 84 80 1.15 374 

0.18 0.4235 71.2 1.76 371 0.15 0.3843 78.0 1.42 371 
ENSR 

Multi-Metals Blank Correction 

FRONT HALF BACK HALF 

TOTAL 

Element 

Sample 

fg 

Rd Blk 

ug 

Default 

Value (a) 

5% of 

Sample 

Corrected 

Front Half 

l»g 

Sample 

"g 

HdBlk 

ug 

Default 

Value 

"g 

5% of 

Sample 

Mg 

Corrected 

Back Half 

Corrected 

FH + BH 

f«g 

Silver (Ag) 0.00 0.00 13.78 0.00 0.00 0.00 1.00 __ 0.00 0.00 

Aluminum (Al) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Arsenic (As) 9.26 0.76 * 13.78 0.46 8.50 0.00 0.00 1.00 -

0.00 8.50 

Barium (Ba) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 -

0.00 0.00 

Beryllium (Be) 0.10 (0.10) 13.78 0.01 0.10 0.00 0.00 1.00 - 0.00 0.10 

Cadmium (Cd) 0.68 0.34 * 13.78 0.03 0.34 0.00 0.00 1.00 -

0.00 0.34 

Cobalt (Co) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Chromium (Cr) 17.70 1.01 * 13.78 0.89 16.69 0.00 0.00 1.00 - 0.00 16.69 

Copper (Cu) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 - 0.00 0.00 

Manganese (Mn) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 - 0.00 0.00 

Nickel (Ni) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Lead (Pb) 23.90 2.70 * 13.78 1.20 21.20 0.00 0.00 1.00 - 0.00 21.20 

Antimony (Sb) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 - 0.00 0.00 

Selenium (Se) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Thallium (Tl) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 -

0.00 0.00 

Vanadium (V) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Zinc (Zn) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -- 0.00 0.00 

If FHB is between 0 to 13.78 ug use blank value to correct 

If FHB> 13.78 ug then use the greater of 13.78 ng or the lesser value between FHB or 5% of FHS . 

* - value used for blank correction 

MERCURY: 

(a) - based on a 3.54 - in. filter size 

If BHB is >0 but <=1 ng then use the BHB value to correct 

If BHB is >1 ug use the greater of either 1 ug or 5% of BH 

( ) Not Detected / Reportable Detection Limit 

Mercury 

Fraction 

Sample 

eg 

Fid Blk 

I'g 

Default 

Value 

n 

5% of 

Sample 

"g 

Corrected 

Amount Hg 

Hg 

FRONT HALF (0.03) (0.03) 6.00 (0.00) (0.03) 

BACK HALF 97.33 0.04 * 6.00 4.87 97.29 

1 TOTAL Hg 97.29 

CLIENT : Onyx Environmental Service, Inc. 

PROGRAM : Fixed Hearth Kiln #3 

1 

RUN NO. Run 1 

If FB is >0 but <=6 ug then use the FB value to correct 

If FB is >6 ug use the greater of either 6 ng or 5% of FH 

( ) Not Detected / Reportable Detection Limit 

* Indicates value used for blank correction 
ENSR AECOM 

Multi-Metals Blank Correction 

FRONT HALF BACK HALF 

TOTAL 

Element 

Sample 

ug 

Fid Blk 

ug 

Default 

Value (a) 

ug 

5% of 

Sample 

ug 

Corrected 

Front Half 

ug 

Sample 

ug 

Fid Blk 

ug 

Default 

Value 

ug 

5% of 

Sample 

ug 

Corrected 

Back Half 

ug 

Corrected 

FH + BH 

ug 

Silver (Ag) 0.00 0.00 13.78 0.00 0.00 0.00 1.00 0.00 0.00 

Aluminum (Al) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Arsenic (As) 249.00 0.76 * 13.78 12.45 248.24 0.00 0.00 1.00 - 0.00 248.24 

Barium (Ba) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Beryllium (Be) 0.10 (0.10) 13.78 0.01 0.10 0.00 0.00 1.00 - 0.00 0.10 

Cadmium (Cd) 1.38 0.34 * 13.78 0.07 1.04 0.00 0.00 1.00 -0.00 1.04 

Cobalt (Co) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Chromium (Cr) 29.00 1.01 * 13.78 1.45 27.99 0.00 0.00 1.00 0.00 27.99 

Copper (Cu) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Manganese (Mn) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Nickel (Ni) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 -

0.00 0.00 

Lead (Pb) 22.30 2.70 * 13.78 1.12 19.60 0.00 0.00 1.00 -

0.00 19.60 

Antimony (Sb) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Selenium (Se) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 -- 0.00 0.00 

Thallium (Tl) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -0.00 0.00 

Vanadium (V) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Zinc (Zn) 0.00 0.00 13.78 -- 0.00 0.00 0.00 1.00 - 0.00 0.00 

If FHB is between 0 to 13.78 ug use blank value to correct 

If FHB > 13.78 pg then use the greater of 13.78 ug or the lesser value between FHB or 5% of FHS . 

* - value used for blank correction 

MERCURY: 

(a) - based on a 3.54 - in. filter size 

If BHB is >0 but <=1 ug then use the BHB value to correct 

If BHB is >1 ug use the greater of either 1 ng or 5% of BH 

( ) Not Detected / Reportable Detection Limit 

Mercury 

Fraction 

Sample 

ug 

Fid Blk 

ug 

Default 

Value 

ug 

5% of 

Sample 

ug 

Corrected 

Amount Hg 

ug 

FRONT HALF 0.10 (0.03) 6.00 0.01 0.10 

BACK HALF 121.23 0.04 * 6.00 6.06 121.19 

I TOTAL Hg 121.29 

CLIENT : Onyx Environmental Service, Inc. 

PROGRAM : Fixed Hearth Kiln #3 

RUN NO. Run 2 

If FB is >0 but <=6 ng then use the FB value to correct 

If FB is >6 ug use the greater of either 6 ng or 5% of FH 

( ) Not Detected / Reportable Detection Limit 

* Indicates value used for blank correction 
ENSR 

Multi-Metals Blank Correction 

FRONT HALF BACK HALF 

TOTAL 

Corrected 

FH + BH 

Element "g 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value (a) 

ug 

5% of 

Sample 

ug 

Corrected 

Front Half 

Hg 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value 

Hg 

5% of 

Sample 

Mg 

Corrected 

Back Half 

Hg 

TOTAL 

Corrected 

FH + BH 

"g 

Silver (Ag) 0.00 0.00 13.78 0.00 0.00 0.00 1.00 0.00 0.00 

Aluminum (Ai) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 . 0.00 0.00 

Arsenic (As) 946.00 0.76 * 13.78 47.30 945.24 0.00 0.00 1.00 - 0.00 945.24 

Barium (Ba) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Beryllium (Be) 0.10 (0.10) 13.78 0.01 0.10 0.00 0.00 1.00 - 0.00 0.10 

Cadmium (Cd) 2.76 0.34 * 13.78 0.14 2.42 0.00 0.00 1.00 -0.00 2.42 

Cobalt (Co) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Chromium (Cr) 55.80 1.01 * 13.78 2.79 54.79 0.00 0.00 1.00 -

0.00 54.79 

Copper (Cu) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Manganese (Mn) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Nickel (Ni) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Lead (Pb) 40.60 2.70 * 13.78 2.03 37.90 0.00 0.00 ' 1.00 - 0.00 37.90 

Antimony (Sb) 0.00 0.00 13.78 - 0.00 0.00 .0.00 1.00 - 0.00 0.00 

Selenium (Se) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Thallium (Tl) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Vanadium (V) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 - 0.00 0.00 

Zinc (Zn) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

If FHB is between 0 to 13.78 pg use blank value to correct 

If FHB > 13.78 pg then use the greater of 13.78 pg or the lesser value between FHB or 5% of FHS . 

* - value used for blank correction 

MERCURY: 

(a) - based on a 3.54 - in. filter size 

If BHB is >0 but <=1 ug then use the BHB value to correct 

If BHB is >1 pg use the greater of either 1 ug or 5% of BH 

( ) Not Detected / Reportable Detection Limit 

Mercury 

Fraction 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value 

Hg 

5% of 

Sample 

Hg 

Corrected 

Amount Hg 

Hg 

FRONT HALF 0.27 (0.03) 6.00 0.01 0.27 

BACK HALF 89.12 0.04 * 6.00 4.46 89.08 

1 TOTAL Hg 89.35 

CLIENT: 

PROGRAM: 

RUN NO. 

Onyx Environmental Service, Inc. 

Fixed Hearth Kiln #3 

Run 3 

If FB is >0 but <=6 pg then use the FB value to correct 

If FB is >6 pg use the greater of either 6 pg or 5% of FH 

( ) Not Detected / Reportable Detection Limit 

* Indicates value used for blank correction 
ENS, ACCO M EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

SAMPLING TRAIN: M29/Metals 

PLANT: ONYX Environmental 

DATE: 

TEST LOCATION: Unit #3 Fixed Hearth 

RUN NUMBER: / 

Stack Diameter - Inches: 39" 

OPERATOR: 

START TIME: 

STOP TIME: 

BAROMETRIC PRESSURE: 

STATIC PRESSURE (+/-): 

Probe/Pitot Number: 

Pitot Coefficient: 

Filter Box No.: 

Meter Box Number: 

Orifice Coefficient (Y): 

Delta H@: 

Nozzle Size: 

XAD Thermocouple ID: 

Impinger Outlet ID: 

tor-*-? 

INITIAL VAC. 

MID VAC. 

FINAL VAC. 

LEAK CHECKS: 

in. CFM 

CFM 

CFM 

in. 

in. 

0.84 

/•(Pi? 

7 W 

6-4 08 

INIT. PITOT 

" FINAL PITOT 

ORSAT Initial: 

O^SAT FinalFILTER DATA 

IMPINGER VOL'S Rinse ORSAT DATA 

SdNiTliilSi&E I Volumes 

0 n\ 

100 

100 

0 (S 

100 

100 100 

I2K.I . 

^.siypA. 

FOR MOISTURIE CALC: 

Final Vol. 151 NET GAIN: < / ml. 

SAMPLE 

POIMT 

CLOCK 

TIME 

VELOCITY; 

HEAO 

DedaRKwc 

. ORIFICE 

METER VOL. 

,.D<*aH.lnv(C 

; OAS METER ' 

VOLUME 

ff 

TEMPERATURE READINGS. °F PUMP 

VACUUM 

. . In.Ha. .. 

COMMENTS 

SAMPLE 

POIMT 

CLOCK 

TIME 

VELOCITY; 

HEAO 

DedaRKwc 

. ORIFICE 

METER VOL. 

,.D<*aH.lnv(C 

; OAS METER ' 

VOLUME 

ff 

STACK PRO&E FILTER BOX 

,, t 

IMPIKIOEA ; I XAD Trap 

. , . . .. 

GAS METER • 1 

PUMP 

VACUUM 

. . In.Ha. .. 

COMMENTS 

SAMPLE 

POIMT 

CLOCK 

TIME 

VELOCITY; 

HEAO 

DedaRKwc 

. ORIFICE 

METER VOL. 

,.D<*aH.lnv(C 

; OAS METER ' 

VOLUME 

ff 

STACK PRO&E FILTER BOX 

,, t 

IMPIKIOEA ; I XAD Trap 

. , . . .. . . IN'. f „ , OUT, i 

PUMP 

VACUUM 

. . In.Ha. .. 

COMMENTS 

ttt' ' 0 16 o.isr TO 2-S 7 Ho 

1. i<r is 270 . XI - 7 f i 

i. if U J 

' a .10 * J t 7 h ta-0 

l£T > h.o Sn><° to S 3 

?«• us 0,1/ ISO 

\ /.* r 2 £ 3 B f 

ten * 3 in . &f srt> 

5XC (tD Q>lt ?3f -2.5X7 B t " s s r 

Sn>/° Pave oJhtsssfrx-

<//<S.ZTLO iLy • 2 ^ A/A - BB 

a -0-/ 7 38S " 2-Ss r 6 7 

i r e * I f ? f t f>8 

US'<jt> O.ig 3 8 £ 2 4 .S n s^o 

5 *0.(& q& < T o 

Y> -0,1a Z S C .<r-o 

1 let*/A / -*/ o 

h y 

n /ns'/k * 0JJ L 2 S O 

K f— 

6 < 

^ 7 

V f 5-

\ 
ENSl v 

SAMPLING TRAIN: 

PLANT: 

DATE: 

EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

M28 

Onyx 

5/10/2006 

TEST LOCATION: Unit #3 

RUN NUMBER: R2 

Stack Diameter - inches: 39 

OPERATOR: B. Hardy 

START TIME: 

STOP TIME: 

/Sao 

BAROMETRIC PRESSURE: 

STATIC PRESSURE (+/-): 

Probe/Pitot Number: 

Pltot Coefficient: 

Filter Box No.: 

Meter Box Number: 

Orifice Coefficient (Y): 

Delta H@: 

Nozzle Size: 

XAD Thermocouple ID: 

~S~F 

INITIAL VAC. 

MIDVAC. 

FINAL VAC. 

LEAK CHECKS: 

14 In. 

In. 

In. 

0,84 4-

80184 

1.039 

1.881 

0.431 

INIT. PITOT 

FINAL PITOT 

ORSAT Initial: 

ORSAT Final: 

CFM 

CFM 

CFM 

0.004 

FILTER DATA 

HWBER TARE. 

SAMPLE 

POINT 

CLOCK 

TIME :.: 

VELOCITY.. 

HEAD. 

DeitaP.Inwc 

ORIFICE . 

METER VOL.; 

-rWH. Inwc-

..'.'GAS METER' 

: . VOLUME ; ' 

..x$ ' 'ft* iTv..-,,t; 

TEMPERATURE READINGS, • . PUMP > 

VACUUM ' 

,t ln«a.. . 

b

 COMMENTS ^ * fc 

SAMPLE 

POINT 

CLOCK 

TIME :.: 

VELOCITY.. 

HEAD. 

DeitaP.Inwc 

ORIFICE . 

METER VOL.; 

-rWH. Inwc-

..'.'GAS METER' 

: . VOLUME ; ' 

..x$ ' 'ft* iTv..-,,t; 

. STACK PROBE . 

'•248.2a ••. 

'•• FILTER BOX 

sv?««» , •. 

.-."•i-lMPINGER^ ft ' ;Filt8f Ou|ief. 

-*- W 

. : OAS METER f . . 

• . PUMP > 

VACUUM ' 

,t ln«a.. . 

b

 COMMENTS ^ * fc 

SAMPLE 

POINT 

CLOCK 

TIME :.: 

VELOCITY.. 

HEAD. 

DeitaP.Inwc 

ORIFICE . 

METER VOL.; 

-rWH. Inwc-

..'.'GAS METER' 

: . VOLUME ; ' 

..x$ ' 'ft* iTv..-,,t; 

. STACK PROBE . 

'•248.2a ••. 

'•• FILTER BOX 

sv?««» , •. 

.-."•i-lMPINGER^ ft ' ;Filt8f Ou|ief. 

-*- W it-,".; IN •_?»,,. : .OUT 

• . PUMP > 

VACUUM ' 

,t ln«a.. . 

b

 COMMENTS ^ * fc 

A1 0 0 12- " l5t ' NA "77 

• ci 

A2 7.50 Q,U S O NA 

A3 15.00 O'lO LS"2- r/ NA l¥ I 

M 22.50 Q-t[ o NA 13 

A5 30.00 p 3 ^ NA 7i- n{ 

A6 37.50 4 ?7| NA 7<? UK to 

A7 45.00 6.(7 i-V r/ NA •?( U 

AS 52.50 e.tx / A s i . 

NA 71 G8 r B1 60.00 <T<T NA k$ bt 

B2 67.50 C tJ 1.0 m srv NA IV s~ ST* An. tfi(G>' 4 < 

83 75.00 /,<? S t , NA 7 ? la 

82.50 on l-u> zed r ? NA •71. B5 90.00 0 oc 1-9 111* 190 fr? NA 1 H Be 07.50 l-Y Sit , 5 ^ NA T l 

B7 105.00 / . A HA 18, 

Bfi 112.50 /.( . r?>.u - ? r NA 

120 00 NA 

\iP 

! 

1 •'•..\:s.. 

, 

j 

1 

. ; ........ . 

r 

5.M;jMi.>:ia 

•?.,,JMPiyGERVOj.'S,';;;.": 

100 

100 

100 

100 

FINAL 

IM. 

ill . lo 

loo 

SILICA GEL 

Volumes 

ORSAT DATA 

[jreWMOISTURE CALC : 
ENSk /He C O EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

1 LEAK CHECKS: 

SAMPLING TRAIN: M29/Metals BAROMETRIC PRESSURE: INITIAL VAC. 

PLANT: ONYX Environmental STATIC PRESSURE (+/-): MID VAC. 

DATE: fK-ll-f X Probe/Pitot Number: FINAL VAC. 

TEST LOCATION: Unit #3 Fixed Hearth Pltot Coefficient: 0.84 

RUN NUMBER: 3 Filter Box No.: MB- S 

Stack Diameter - Inches: 39" Meter Box Number: INIT. PITOT 

Orifice Coefficient (Y): 1.03$ FINAL PITOT 

OPERATOR: VO . rWdl / Delta H@: \<m 

START TIME: //^ O Nozzle Size: ORSAT Initial: 

STOP TIME: /33 ? XAD Thermocouple ID: A* /A ORSAT Final: 

Impinger Outlet ID: ^.r-/ L 

Ik Jn- CFM ,002 

In. CFM 

7 in, CFM t 0Q<j 

y y 

V / V / FILTER DATA 

.NUMBER; , IAR£ 

IMPINGER VOL'S. 

M L 

100 

100 

100 

100 

i0»l 

us 

l O l 

100 

SILICA GEL 

Final Vol. 

Volumes 

ORSAT DATA 

FOR MOISTURE CALC.: 

NET GAIN: | "^6 D-3, ml. 

SAMPLE 

POINT 

CLOCK 

TIME 

VELOCITY 

HEAD 

OfttwP ln.fc 

ORIFICE 

METER VOL. 

. Oaten, m.wc. 

. OAS METER 

VOLUME 

rr1 

TEMPERATURE READINGS, *F . PUMP 

VACUUM 

.. '. h Ha..-.. 

COMMENTS 

SAMPLE 

POINT 

CLOCK 

TIME 

VELOCITY 

HEAD 

OfttwP ln.fc 

ORIFICE 

METER VOL. 

. Oaten, m.wc. 

. OAS METER 

VOLUME 

rr1 

STACK PROBE 

. ..*««« ., 

••.FILTER BOX. 

. utts,. . 

' IMPIWOfcR, 

.{,'<.. • « 

XAOTrap 

• ".V MM.,.;./ : 

<5AS METER 

. PUMP 

VACUUM 

.. '. h Ha..-.. 

COMMENTS 

SAMPLE 

POINT 

CLOCK 

TIME 

VELOCITY 

HEAD 

OfttwP ln.fc 

ORIFICE 

METER VOL. 

. Oaten, m.wc. 

. OAS METER 

VOLUME 

rr1 

STACK PROBE 

. ..*««« ., 

••.FILTER BOX. 

. utts,. . 

' IMPIWOfcR, 

.{,'<.. • « 

XAOTrap 

• ".V MM.,.;./ : IN , OUT .. 

. PUMP 

VACUUM 

.. '. h Ha..-.. 

COMMENTS 

Ai t . T 5fc>7 7S~1 -

a ' C-C 7 5n't<| » - 370 - 7-<i> 1 • f* IS" I f 

3 ' cu d {•-} 5~i<?~<n~ * 7 3 '71 7 2 -

H >2iT 017 / , L 2u i 5V < ^ 

5 le n> t £ VI f &o 7 f 6 

b hHS 2 7 3 S ^ ' a\ t S 

7 M S - 172 - &< 7 0 

fl ZH<\ "Uo\ 6 1 ."74 

577 , 

B l "Oil . i-/<r 7 7 

'{is- ? r I - Z 5 « " / SI 7 7 

<-7 s

l t l 

k

l S i r V" U ( f S<?3U ~ x?f m 

S <^V "37 7*1 

(> 0 -tt r IMG" 175T ^ X20 

2 1 

1 OS l/Xi ' ©- a | .1S T 6>ff7.ofif «J7« f 

9 iO SI To > 7 ¥ as- ) \ / So sr 

fe(S.69^ 

—*rL —=—1 

mmm, 
) 

ENSR 

1 PLANT: 

AECOM 

ORSAT ANALYSIS (EPA METHOD 31 

ONYX Environmental Services 

I DATE : -

• LOCATION Unit #3 Fixed Hearth 

SAMPL E TYPE : 

OPERATOR : 

Intergrated Bag 

Shea^, Ua^M 

PRE-LEA K CHECK : 

POST-LEA K CHECK : 

NOTE: Check: Liquid level must not fall 

below bottom of capillary tubing in 4 minutes 

and meniscus must not change by more than 

0.2 mL in 4 minutes. 

DATA CRITERIA 

CO, : 

O , : 

When greater than 4%, difference between readings shall be 0.3% or less. 

When less than 4%, difference between readings shall be 0.2% or less. 

When greater than or equal to 15%, difference between readings shall be 0.2% or less.' 

When less than 15%, difference between readings shall be 0.3% or less. 

Run#1 Reading A Reading B Reading C Avg. | 

Net E 

Volume ( 

GAS Actual Net Actual Net Actual Net 

Avg. | 

Net E 

Volume ( 

C 0 2 

o2 * (Z H n - . o ns j 

Run #2 Reading A Reading B Reading C Avg. J 

Net E 

Volume | 

GAS Actual Net Actual Net Actual Net 

Avg. J 

Net E 

Volume | 

C 0 2 

0 2 * 7</ q.f 

Run #3 Reading A Reading B Reading C Avg. 

Net 

Volume 

GAS Actual Net Actual Net Actual Net 

Avg. 

Net 

Volume 

C U 2 HHHH H 

o2 * n-o /V n o /O.D JO.Q 

•9 

Net 0 2 is actual 0 2 minus actual C0 2 reading. 
June 2006 Test 
Particulate Matter Data 
Veolia ES Technical Solutions 

Fixed Hearth Incinerator #3 

Method 5 Sampling Parameters 

Run No. Run 1 Run 2 Run 3 

AVGS 

Date 19-Jun-06 

15:12 

20-Jun-06 

10:06 

21-Jun-06 

10:06 

AVGS 

Start Time Units 

19-Jun-06 

15:12 

20-Jun-06 

10:06 

21-Jun-06 

10:06 

Stop Time 17:29 12:29 12:44 AVGS 

Nozzle Diameter inches 0.431 0.431 0.431 0.431 

Barometric Pressure in:.H.a 29.55 29.55 29.50 29.53 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 78.244 82.902 81.745 80.964 

Avg. DGM Temp. °F 110.6 111.2 109.0 110.3 

Avg Delta H in H2 0 1.31 1.43 1.41 1.38 

Avg Delta H !.n.:.H.g. 0.0964 0.1049 0.1034 0.1016 

DGM Calibration Factor 1.0070 1.0070 1.0070 1.0070 

Gas Sample Volume dscf 72.247 76.482 75.573 74.768 

Total Water Collected mL 1341.0 1487.9 1340.1 1389.7 

Volume of Water Vapor scf 63.228 70.154 63.186 65.523 

Moisture (measured) I % Wv 46.7 47.8 I 45.5 46.7 I 

Moisture (@ saturation) % v/v 101.3 101.3 101.5 101.3 

Dry Mole Fraction, 100-%M -0.5333 0.5216 0.5446 0.5332 

C 0 2 at Stack %dry 7.40 7.60 7.40 7.47 

O z at Stack %dry 10.00 8.20 9.60 9.27 

CO + N 2 %dry 82.60 84.20 83.00 83.27 

Dry Molecular Weight Ib/lb-mole 29.58 29.54 29.57 29.57 

Wet Molecular Weight Ib/lb-mole 24.18 24.02 24.30 24.17 

Excess Air at Stack %

 1 84.7 58.5 78.0 73.7 

Stack Diameter inches 39.0 39.0 39.0 39.0 

Stack Area sq. in. 1194.6 1194.6 1194.6 1194.6 

Static Pressure in H2 0 -0.15 -0.15 -0.13 -0.14 

Stack Pressure in.-.H.g. 29.54 29.54 29.49 29.52 

Avg. Stack Temp. °F 386.2 387.9 385.9 386.6 

Avg. Sqroot of Delta P - 0.3701 0.3922 0.3930 0.3851 

SDE Average - 10.765 11.420 11.429 11.205 

Pitot Coefficient -0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,736 1,847 1,840 1,808 

Stack Flowrate wet acfm 14,399 15,326 15,262 14,996 

Stack Flowrate wet scfm 8,870 9,422 9,390 9,228 

Stack Flowrate dscfm 4,730 4,915 5,114 4,920 

Isokinetics % 104 106 101 104 

Meter Box No. — 80754 80754 80754 — 

Delta H @ in H2 0 1.832 1.832 1.832 -

Field QA Yqc -- 1.0066 0.9918 0.9974 0.9986 

[Deviation] Pre-Y % 0.04% 1.51% 0.95% 0.84% 

S:\_JOB\2006\Onyx\Performance TestVTest DataUune 2006\2nd Retest\[PM.x!s]DATA 
Metho

d 5 Sampling Parameters 

PT 

Run l Ru

n 2 Run 3 

PT Delt

a P SQRT 

Delta P 

DGM IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM IN DGM 

OUT 

Delta H STACK 

TEMP 

a1 0.07 0.2646 104 102 0.66 382 0.10 0.3162 102 

99 0.92 382 0.17 0.4123 

89 87 1.53 379 

a2 0.12 0.3464 104 102 1.13 387 0.10 0.3162 106 102 0.92 383 0.15 0.3873 

92 89 1.35 380 

a3 0.19 0.4359 109 104 1.79 386 0.16 0.4000 108 103 1.47 386 0.14 0.3742 

95 90 1.26 379 

a4 0.19 0.4359 111 104 1.79 387 0.18 0.4243 111 104 1.66 389 0.14 0.3742 108 106 1.26 384 a5 0.15 0.3873 114 106 1.41 388 0.14 0.3742 112 105 1.29 387 0.18 0.4243 112 106 1.62 388 a6 0.16 0,4000 115 107 1.50 388 0.15 0.3873 112 106 1.38 385 0.18 0.4243 114 107 1.62 388 a7 0.12 0.3464 115 106 1.13 383 0.18 0.4243 115 107 1.66 385 0.12 0.3464 116 108 1.08 387 a8 0.15 0.3873 116 104 1.41 382 0.15 0.3873 116 109 1.38 388 0.10 0.3162 117 109 0.90 381 b1 0.07 0.2646 113 111 0.66 382 0.18 0.4243 110 110 1.66 386 0.22 0.4690 112 111 1.98 384 b2 0.14 0.3742 113 111 1.32 383 0.18 0.4243 114 111 1.66 388 0.17 0.4123 112 111 1.53 388 b3 0.11 0.3317 115 111 1.03 389 0.18 0.4243 116 112 1.66 390 0.18 0.4243 116 112 1.62 389 b4 0.13 0.3606 116 111 1.22 391 0.16 0.4000 118 112 1.47 391 0.19 0.4359 118 113 1.71 390 b5 0.14 0.3742 116 112 1.32 390 0.18 0.4243 119 113 1.66 392 0.18 0.4243 120 114 1.62 390 b6 0.15 0.3873 116 112 1.41 387 0.16 0.4000 121 114 1.47 395 0.16 0.4000 120 115 1.44 392 b7 0.17 0.4123 117 112 1.60 388 0.14 0.3742 121 114 1.29 392 0.12 0.3464 120 115 1.08 391 b8 0.17 0.4123 117 112 1.60 386 0.14 0.3742 122 115 1.29 387 0.10 0.3162 120 115 0.90 384 

A V G 0.14 0.3701 110.6 1.31 386 0.16 0.3922 111.2 1.43 388 0.16 0.3930 109.0 1.41 386 
ENSR 

Sampling Train 

Hun Number 

Clieut 

Facility Location 

Source 

Date 

Operator 

Stack Din.-la. 

Start Time 

Slop I line 

EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Barometric Pressure 

Sialic Pressure (+/-) 

- - n 

aia/isii 

l'robc/Pltot Number f\ $ - H -

PltqtCoefficleut . § H 

Filter Box No. \\ 8 -g 

Meter Box No. jSPlSH 

Orifice Coefficient (Y) 

Delta H(i£ 

Nozzle Size/No. 

XAD Thermocouple IP: 

LEAK CHECKS In "Hg 

INITIAL VAC. IL la. CFM 

MID VAC. ln. CFM 

FINAL. VAC. In. CFM 

+ / . / 

IN1T. PITOT ' * FINAL PITOT 

• OQ I 

I-OPT FILTER DATA 

•XNOMBER: : •.•y.-XKBS.-y. 

>INIT:.'-:-.:-

X L 

•EINALX RINSE 

(OCsO 

•S3Q 

.3? 

SILICA GE L : 

: SAMPLE 

POINT 

CLOCK 

IJMK 

VIXOC'ITV 

Uc'A» 

OcltaP, ID WC 

flftlhlCr 

MOTKfcVOX 

|*|lftll>|u*e 

CAS MWCR 

VOLUME 

re 

TEMPERATURE READINGS, °F 

COMMENTS 

: SAMPLE 

POINT 

CLOCK 

IJMK 

VIXOC'ITV 

Uc'A» 

OcltaP, ID WC 

flftlhlCr 

MOTKfcVOX 

|*|lftll>|u*e 

CAS MWCR 

VOLUME 

re STACK PR0UE 

OltC&NfC 

MOGULS: ?WPir*;if* 

•;;;:|>!dii$Mi*E»;i;i;| VACUUM COMMENTS 

: SAMPLE 

POINT 

CLOCK 

IJMK 

VIXOC'ITV 

Uc'A» 

OcltaP, ID WC 

flftlhlCr 

MOTKfcVOX 

|*|lftll>|u*e 

CAS MWCR 

VOLUME 

re STACK PR0UE 

OltC&NfC 

MOGULS: ?WPir*;if* 

VACUUM COMMENTS 

A J 0 07 — • fc>7 / 

x < • \ a I.I X 99/.(n JO — -

fo<-( hi I 

3 IS • n n q a n — W /©<•/ 

•\<\ l-lQ iDOl . 8 381 — 5ft HI J 

s 15 l-Mf lbol.1* — / 0 6 3 

I T S • it 1-50 IOI2 .9 am — J 

1 lOK .0 JS3 — 164 3 

sa.5 t.* « lrt^.<? a«r* — S3 low 

! Mk,r /6 a 9 

n i .(?(, loa-?. , i«2 IH) / — 61 Ml u< 

41. 5 1.32 /0 3I.5 — 50 ii^ 1// 

.3 TS ii 1-03 i 8f so MS •

 1 1 / 

ill a. 

is 1.2 1 1 9 / a«<l AW . ?i lit «f 3. 

10 •w 1.32 lo</6.0 i9D 2 to 53 KG i a a 

& f-H/ lo&.H 327 S3 l/fr l/x 

7 ( 0 5 •n UO toS L t 3 ^ MS — 4<J |n ua 

•17 ID£>0 • q — in 1/2 a 

r 

i • -

1 

Orsat 

:cor. •y.oi:-

7.5 

IH .10.0 

lA 

[Final Purge Rate 
ENSR!AtCO M 

Sampling Train A\ 2 i / /M5 

EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Run Number 

Cllcul 

_&2_ 

Facility Location {ftuftevf- , I L 

Source 

Dale 

Operator 

Slack Dia. - iu. 

Start Time 

Stop Time 

too ^ 

Barometric Pressure 

Static Pressure (+/-)_ 

Probe/Pitot Number 

Pilot Coefficient 

Filter Box No. 

Meter Box No. 

Orifice Coefficient (V) 

Delta H@ 

Nozzle Size/No. 

XAD Thermocouple ID: 

Inm Outlet TC ID: 

mo 

-B 

LEAK CHECKS In "Hg 

INITIAL VAC. | f 

MID VAC. 

FINAL VAC. 7 

In. 

In. 

In. 

INIT. PITOT 

C F M 

C F M 

CFM-N, •OOl 

FINAL PITOT 

FILTER DATA 

:IABE X 

: IMPINGE* \.Ot/S.\-

.mix:. 

\DO 

lee 

/MP 

7ft 77t*. 

oEiNAi:-: 

1 ho. 

3>3LO 

l-SIidCA-BED.'-

WT7 

•H1NSE 

\0O 

Orut 

:co2: •:-:o2v 

7.6 n 

l.L 

to 

Final Purge Rate 

Final PH 

• SAMPLE; 

POINl 

<LCK.K: vfiLfx'ijy 

ttlAB 

DeltaP, In wc 

ORIHICE 

MereavoL 

Dc|tal), |n *f 

<5AS METER 

VOLUME 

W 

TEMPERATURE READINGS. °F > 

COMMENTS 

• SAMPLE; 

POINl 

<LCK.K: vfiLfx'ijy 

ttlAB 

DeltaP, In wc 

ORIHICE 

MereavoL 

Dc|tal), |n *f 

<5AS METER 

VOLUME 

W STACK PROBE oveH 

ORGSANfC 

M0pui4: iMrthfOE* 

i!i'iil:iti*5EWf*6K:|i|i!i 

iiiiiiiiiii! 

COMMENTS 

• SAMPLE; 

POINl 

<LCK.K: vfiLfx'ijy 

ttlAB 

DeltaP, In wc 

ORIHICE 

MereavoL 

Dc|tal), |n *f 

<5AS METER 

VOLUME 

W STACK PROBE oveH 

ORGSANfC 

M0pui4: iMrthfOE* mmm\ iiiiiiiiiii! 

COMMENTS 

Al 0 I d i n 23k 5*11 — 66 ^ ' 

2 7.< •10 \r,-\\.0 3?A 23« « 0 

-

£1 /C6 I6Z 

IC • It M 7 10-15. 2 2 Vp, <& (oa l o S 

M •Ifc (6%o.3 33T 2 to 2Ya 

5 .10 •U i.aq 3S7 Oil «rq Id ICS 

C n.< 1.30 J95 • ux i 

7 .16 |.(& «>«». 1 , 53 I07 

8 S).< tS l.*« ft> iio\.8 3$ft f a lit Ie9 

iUpPeJP Hot* 

B ( LO •16 3?,fc> 241 no M O 

a. -T.< - 19 — fS Iff 

3 i< •Ift Ufa un. » lift L 

• l£ M l 1133.3, a to — 5

J no 5 

5 • tt -m . us 

q?.5 I-H7 il3M .2 •/? MY 

7 aft 0A2 — m */ 

?! H<tM. 4 - uc V 

lW<?.t>7G 

I 

I 

! 

! 

| 

i!i|:|:i:i:|:i:i:|:i:i:i:iiiiii;|i|i:i 
ENS R j A L C O M EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

:::iMp:iKGfift.voLjs;::-: Orsat 

Sampling Train /AJ T / /"\ 5 Barometric Pressure fc5^ LEAK CHECKS In "Hg ::INITI:-::- ym wo:-:-:-:-: •RINSE :co2 •::o2-:-

Hun Number jVi Static Pressure (+/-) - . IL INITIAL VAC. |L in. CFM • e>cgi 6 

Client '7-M f W v Probe/Pitot Number A S MID VAC. In. CFM ^ 0 3&8 '7-M 

Facility Location ^ftU^Cf i I L Pilot Coefficient FINAL VAC. i , in. CFM 

Source Filter Box No. 

r- J 1-1 + /• / VI" 0 1 1-1 

Date Meier Box No. INIT. PITOT V V FINAL P1T01 

Operatur 1.1 T .(.ft'MfltJ Orifice Coefficient (Y) 1 .DOI FILTER DATA 1.1 

Stack Ula.-lu. Delta H @ 1/93?. 

•XNOMBER:- X-MAREX- : 

Start Time iru, Nozzle Size/No. ! Ti T 

Stop Time XAD Thermocouple ID: — /3./3L vX-X-SmCABE&XvX. Final Purge Rate 

Imp Outlet TC ID: L X -12 Final ril 

SAMPLE CLOCK VELOCITY ORIFICE «AS Mi-TER TEMPERATUR E READINGS. ° F 

fOINT JtMb IWAD Mffl LR.VQL VOLUME ORGANfC VACUUM COMMENTS 

Belt*!1, lo wc Pe|tmi,|n*r re STACK PK.OBE MOGULS iM,pi(sfc5Brt iil|iii3(|i)Fi!i!; 

M O n I.S ^ — 1 

a 1.S" -IC" 1-35 _ Ho \ 3 K .IV no. a 31T -- \ 

M ib5. I a w 1<? 106 1 

s Ift U D 3 S S — l i |i| P IcO^, 1 

n . c . w U 3 115.1 JRS 211 — c< / c i 1 

7 • IX L O S no s 3 87 1H0 — 57 U6 loi? / 

% S3. ? 'iO 3 81 — in 1*? ) 

— 

6 I C O >21 Lif t M . U — h ( 

1 •IT I. S i l4$,C — tu 2 

3 7S' I.C2 ZHO — 1.6 (12 a 

s a c .1? M l .'•510 J»vt 33fl — 113 a 

S A O - i p U i 3 ? 0 2H) — - KM 3 

4 <nc • i t m a * m a m S t \t< 2 

7 » o r .12 222. <? 391 — S3 US 

$ M2.5 • 10 .90 ICO — S3 120 US 1 \70 — 

— 

' 

— • 

i 

1 
1 

Metals Data 

) 
Veolia ES Technical Solutions 

Fixed Hearth Incinerator Unit 3 

Method 0060 (Metals) Sampling Parameters 

Run No. Run 1 Run 2 Run 3 

AVGS 

Date 19-Jun-06 20-Jun-06 21-Jun-06 

AVGS 

Start Time Units 15:12 10:06 10:06 

Stop Time 17:29 12:29 12:44 AVGS 

Nozzle Diameter inches 0.431 0.431 0.431 0.431 

Barometric Pressure in. Hg 29.55 29.55 29.50 29.53 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 78.244 82.902 81.745 80.964 

Avg. DGM Temp. °F 110.6 111.2 109.0 110.3 

Avg Delta H in H2 0 1.31 1.43 1.41 1.38 

Avg Delta H in. Hg 0.0964 0.1049 0.1034 0.1016 

DGM Calibration Factor — 1.0070 1.0070 1.0070 1.0070 

Gas Sample Volume dscf 72.247 76.482 75.573 74.768 

Total Water Collected mL 1341.0 1487.9 1340.1 1389.7 

Volume of Water Vapor scf 63.228 70.154 63.186 65.523 

Moisture (measured) % V/V 46.7 47.8 45.5 46.7 

Moisture (@ saturation) % v/v 101.3 101.3 101.5 101.3 

Dry Mole Fraction, 100-%M — 0.5333 0.5216 0.5446 0.5332 

C O a at Stack %dry 7.40 7.60 7.40 7.47 

0 2 at Stack %dry 10.00 8.20 9.60 9.27 

CO + N 2 %dry 82.60 84.20 83.00 83.27 

Dry Molecular Weight Ib/lb-mole 29.58 29.54 29.57 29.57 

Wet Molecular Weight Ib/lb-mole 24.18 24.02 24.30 24.17 

Excess Air at Stack % 84.7 58.5 78.0 73.7 

Stack Diameter inches 39.0 39.0 39.0 39.0 

Stack Area sq. in. 1194.6 1194.6 1194.6 1194.6 

Static Pressure in H2 0 -0.15 -0.15 -0.13 -0.14 

Stack Pressure in. Hg 29.54 29.54 29.49 29.52 

Avg. Stack Temp. °F 386.2 387.9 385.9 386.6 

Avg. Sqroot of Delta P — 0.3701 0.3922 0.3930 0.3851 

SDE Average — 10.765 11.420 11.429 11.205 

Pitot Coefficient — 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,736 1,847 1,840 1,808 

Stack Flowrate wet acfm 14,399 15,326 15,262 14,996 

Stack Flowrate wet scfm 8,870 9,422 9,390 9,228 

Stack Flowrate dscfm 4,730 4,915 5,114 4,920 

Isokinetics % 104 106 101 104 

Meter Box No. ~ 80754 80754 80754 — 

Delta H @ in H2 0 1.8320 1.8320 1.8320 -

Field QA Yqc — 1.0066 0.9918 0.9974 0.999 

[Deviation] Pre-Y % 0.04% 1.51% 0.95% 0.8% 
Method 0060 (Metals) Sampling Parameters 

PT 

Runl AVGS--METALS Run 2 AVGS--METALS Run 3 AVGS--METALS 

PT Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H |STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

a1 0.07 0.2646 ^ 104 102 0.66 382 0.10 0.3162 102 99 0.92 382 0.17 0.4123 89 87 1.53 379 

2 0.12 0.3464 104 102 1.13 387 0.10 0.3162 106 102 0.92 383 0.15 0.3873 92 89 1.35 380 

3 0.19 0.4359 109 104 1.79 386 0.16 0.4000 108 103 1.47 386 0.14 0.3742 95 90 1.26 379 

4 0.19 0.4359 111 104 1.79 387 0.18 0.4243 111 104 1.66 389 0.14 0.3742 108 106 1.26 384 

5 0.15 0.3873 114 106 1.41 388 0.14 0.3742 112 105 1.29 387 0.18 0.4243 112 106 1.62 388 

6 0.16 0.4000 115 107 1.50 388 0.15 0.3873 112 106 1.38 385 0.18 0.4243 114 107 1.62 388 

7 0.12 0.3464 115 106 1.13 383 0.18 0.4243 115 107 1.66 385 0.12 0.3464 116 108 1.08 387 

8 0.15 0.3873 116 104 1.41 382 0.15 0.3873 116 109 1.38 388 0.10 0.3162 117 109 0.90 381 

b1 0.07 0.2646 113 111 0.66 382 0.18 0.4243 110 110 1.66 386 0.22 0.4690 112 111 1.98 384 

2 0.14 0.3742 113 111 1.32 383 0.18 0.4243 114 111 1.66 388 0.17 0.4123 112 111 1.53 388 

3 0.11 0.3317 115 111 1.03 389 0.18 0.4243 116 112 1.66 390 0.18 0.4243 116 112 1.62 389 

4 0.13 0.3606 116 111 1.22 391 0.16 0.4000 118 112 1.47 391 0.19 0.4359 118 113 1.71 390 

5 0.14 0.3742 116 112 1.32 390 0.18 0.4243 119 113 1.66 392 0.18 0.4243 120 114 1.62 390 

6 0.15 0.3873 116 112 1.41 387 0.16 0.4000 121 114 1.47 395 0.16 0.4000 120 115 1.44 392 

7 0.17 0.4123 117 112 1.60 388 0.14 0.3742 121 114 1.29 392 0.12 0.3464 120 115 1.08 391 

8 0.17 0.4123 117 112 1.60 386 0.14 0.3742 122 115 1.29 387 0.10 0.3162 120 115 0.90 384 

AVG 0.14 0.3701 110.6 | 1.31 386 0.16 0.3922 111.2 1.43 388 0.16 0.3930 109.0 1.41 386 
ENSR 

Multi-Metals Blank Correction 

FRONT HALF BACK HALF 

TOTAL 

Element 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value (a) 

Hg 

5% of 

Sample 

Hg 

Corrected 

Front Half 

Hg 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value 

Hg 

5% of 

Sample 

Hg 

Corrected 

Back Half 

Hg 

Corrected 

FH + BH 

Mg 

Silver (Ag) 0.00 0.00 13.78 0.00 0.00 0.00 1.00 _ 0.00 0.00 

Aluminum (AI) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Arsenic (As) 5.81 0.61 * 13.78 0.29 5.20 0.33 0.00 1.00 0.02 0.33 5.53 

Barium (Ba) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 - 0.00 0.00 

Beryllium (Be) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Cadmium (Cd) 0.00 0.00 13.78 - . 

0.00 0.00 0.00 1.00 -0.00 0.00 

Cobalt (Co) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Chromium (Cr) 9.64 0.79 * 13.78 0.48 8.85 1.06 0.00 1.00 0.05 1.06 9.91 

Copper (Cu) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 - 0.00 0.00 

Manganese (Mn) 0.00 0.00 13.78 -- 0.00 0.00 0.00 1.00 -

0.00 0.00 

Nickel (Ni) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 -

0.00 0.00 

Lead (Pb) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -0.00 0.00 

Antimony (Sb) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Selenium (Se) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -

0.00 0.00 

Thallium (TJ) 0.00 0.00 13.78 -

0.00 0.00 0.00 1.00 -0.00 0.00 

Vanadium (V) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 -

0.00 0.00 

Zinc (Zn) 0.00 0.00 13.78 -- 0.00 0.00 0.00 1.00 - 0.00 0.00 

If FHB is between 0 to 13.78 ng use blank value to correct 

If FHB > 13.78 ng then use the greater of 13.78 ug or the lesser value between FHB or 5% of FHS . 

* - value used for blank correction 

MERCURY: 

(a) - based on a 3.54 - in. filter size 

If BHB is >0 but <=1 ng then use the BHB value to correct 

If BHB is >1 [ig use the greater of either 1 (tg or 5% of BH 

( ) Not Detected / Reportable Detection Limit 

Mercury 

Fraction 

FRONT HALF 

BACK HALF 

Sample 

Hg 

0.00 

0.00 

Fid Blk 

Hg 

0.00 

0.00 

Default 

Value 

Hg 

6.00 

6.00 

5% of 

Sample 

Hg 

0.00 

0.00 

Corrected 

Amount Hg 

Hg 

0.00 

0.00 

CLIENT : Veolia ES Technical Solutions 

PROGRAM : Fixed Hearth Incinerator Unit 3 

RUN NO. Run 1 

TOTAL Hg 0.00 

If FB is >0 but <=6 ug then use the FB value to correct 

If FB is >6 ng use the greater of either 6 ng or 5% of FH 

( ) Not Detected / Reportable Detection Limit 

* Indicates value used for blank correction 
ENSR 

Multi-Metals Blank Correction 

FRONT HALF BACK HALF 

TOTAL 

Element 

Sample 

Hg 

Fid Blk 

Mg 

Default 

Value (a) 

Hg 

5% of 

Sample 

Mg 

Corrected 

Front Half 

Hg 

Sample 

Hg 

Fid Blk 

HS 

Default 

Value 

Hg 

5% of 

Sample 

Hg 

Corrected 

Back Half 

Hg 

Corrected 

FH + BH 

Mg 

Silver (Ag) 0.00 0.00 13.78 0.00 0.00 0.00 1.00 „ 0.00 0.00 

Aluminum (Al) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 -

0.00 0.00 

Arsenic (As) 4.30 0.61 * 13.78 0.22 3.69 0.00 0.00 LOO - 0.00 3.69 

Barium (Ba) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Beryllium (Be) 0.00 0.00 13.78 -

0.00 0.09 0.00 1.00 0.00 0.09 0.09 

Cadmium (Cd) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Cobalt (Co) 0.00 0.00 13.78 - 0.00 0.00 0.00 LOO 0.00 0.00 

Chromium (Cr) 3.98 0.79 * 13.78 0.20 3.19 0.66 0.00 LOO 0.03 0.66 3.85 

Copper (Cu) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 -0.00 0.00 

Manganese (Mn) O.OO 0.00 13.78 - 0.00 0.00 0.00 LOO - 0.00 0.00 

Nickel (Ni) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Lead (Pb) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Antimony (Sb) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Selenium (Se) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Thallium (Tl) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Vanadium (V) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Zinc (Zn) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

If FHB is between 0 to 13.78 ug use blank value to correct 

If FHB > 13.78 ng then use the greater of 13.78 ng or the lesser value between FHB or 5% of FHS . 

* - value used for blank correction 

MERCURY: 

(a) - based on a 3.54 - in. filter size 

If BHB is >0 but <=1 ng then use the BHB value to correct 

If BHB is >1 ng use the greater of either 1 ng or 5% of BH 

( ) Not Detected / Reportable Detection Limit 

Mercury 

Fraction 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value 

Hg 

5% of 

Sample 

Hg 

Corrected 

Amount Hg 

Hg 

FRONT HALF 0.00 0.00 6.00 0.00 0.00 

BACK HALF 0.00 0.00 6.00 0.00 0.00 

II TOTAL Hg 0.00 

CLIENT : Veolia ES Technical Solutions 

PROGRAM : Fixed Hearth Incinerator Unit 3 

RUN NO. Run 2 

If FB is >0 but <=6 ng then use Ihe FB value to correct 

If FB is >6 ng use the greater of either 6 ng or 5% of FH 

( ) Not Detected / Reportable Detection Limit 

* Indicates value used for blank correction 
ENSR 

Multi-Metals Blank Correction 

FRONT HALF BACK HALF 

TOTAL 

Element 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value (a) 

Hg 

5% of 

Sample 

Hg 

Corrected 

Front Half 

Hg 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value 

Hg 

5% of 

Sample 

HS 

Conrected 

Back Half 

Hg 

Corrected 

FH + BH 

Hg 

Silver (Ag) 0.00 0.00 13.78 0.00 0.00 0.00 1.00 „ 0.00 0.00 

Aluminum (Al) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Arsenic (As) 5.60 0.61 * 13.78 0.28 4.99 0.21 0.00 LOO 0.01 0.21 5.20 

Barium (Ba) 0.00 0.00 13.78 - 0.00 0.00 0.00 LOO -

0.00 0.00 

Beryllium (Be) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Cadmium (Cd) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Cobalt (Co) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Chromium (Cr) 11.10 0.79 * 13.78 0.56 10.31 0.84 0.00 1.00 0.04 0.84 11.15 

Copper (Cu) 0.00 0.00 13.78 -- 0.00 0.00 0.00 1.00 - 0.00 0.00 

Manganese (Mn) 0.00 0.00 13.78 - 0.00 0.00 0.00 LOO - 0.00 0.00 

Nickel (Ni) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Lead (Pb) 0.00 0.00 13.78 -0.00 0.00 0.00 1.00 - 0.00 0.00 

Antimony (Sb) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Selenium (Se) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 -

0.00 0.00 

Thallium (Tl) 0.00 0.00 13.78 - 0.00 0.00 0.00 1.00 - 0.00 0.00 

Vanadium (V) 0.00 0.00 13.78 - 0.00 0.00 0.00 LOO - 0.00 0.00 

Zinc (Zn) 0.00 0.00 13.78 -- 0.00 0.00 0.00 1.00 -

0.00 0.00 

If FHB is between 0 to 13.78 ng use blank value to correct 

If FHB > 13.78 u-gthen use the greater of 13.78 ng or the lesser value between FHB or 5% of FHS . 

* - value used for blank correction 

MERCURY: 

(a) - based on a 3.54 - in. filter size 

If BHB is >0 but <=1 ng then use the BHB value to correct 

If BHB is >1 ng use the greater of either 1 ng or 5% of BH 

( ) Not Detected / Reportable Detection Limit 

Mercury 

Fraction 

Sample 

Hg 

Fid Blk 

Hg 

Default 

Value 

Hg 

5% of 

Sample 

Hg 

Corrected 

Amount Hg 

Hg 

FRONT HALF 0.00 0.00 6.00 0.00 0.00 

BACK HALF 0.00 0.00 6.00 0.00 0.00 

I TOTAL Hg 0.00 

CLIENT: 

PROGRAM: 

RUN NO. 

Veolia ES Technical Solutions 

Fixed Hearth Incinerator Unit 3 

Run 3 

If FB is >0 but <=6 ng then use the FB value to correct 

If FB is >6 ng use the greater of either 6 ng or 5% of FH 

( ) Not Detected / Reportable Detection Limit 

* Indicates value used for blank correction 
ENS R 

Sampling Train 

Hun Number^ 

Clicot 

Facility Location 

Source 

Date 

Operator 

Slack Ola.-io. 

Start Time 

Stop TIme 

EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

n tQ Sftt.cC-1- , X L 

Barometric Pressure 

Static Pressure (+/-) 

Probe/Pitot Number 

Pilot Coefncleut 

Killer Box No. 

Meter Box No. 

Orifice Coefficient (Y) 

Delta H(ii; 

Nozzle Size/No. 

- • n 

*5-H-ft 

LEAK CHECKS In "Hg 

INITIAL VAC / U 

MID VAC. 

FINAL VAC. 

1 1 

1N1T. PITOT 

In. CFM 

In. CFM 

In. CFM 

FINAL PITOT 

•QCV> 

• OQ / 

FILTER DATA 

2 * . 

XAD Thermocouple ID: 

-::NttMBER:-: X-MAREX-:-

•HNITX 

£2 

•EINXLX 

•S3 Q 

f3? 

SILICABEL: 

RINSE 

Ors*t 

C02: •xojv 

7.5 

74 IO.O 

14 

Final Purge Rate 

SAMPLE 

POINl 

CLOC K 

TtMK 

Vii OC ITY 

flelrdf, In wc 

OKI KICK 

MCTUavOL. 

. :l)e|la|t,:|u;.»<f:-. 

OAS METER 

VOLOMtf 

re 

TEMPERATURE READINGS. °F tm? 

COMMENTS 

SAMPLE 

POINl 

CLOC K 

TtMK 

Vii OC ITY 

flelrdf, In wc 

OKI KICK 

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. :l)e|la|t,:|u;.»<f:-. 

OAS METER 

VOLOMtf 

re SrACK PROW 

PJW&NH: 

iNjPlh&jER 

'<3A*M3Eil!R VACUU M COMMENTS 

SAMPLE 

POINl 

CLOC K 

TtMK 

Vii OC ITY 

flelrdf, In wc 

OKI KICK 

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. :l)e|la|t,:|u;.»<f:-. 

OAS METER 

VOLOMtf 

re SrACK PROW 

PJW&NH: 

iNjPlh&jER iiiiiiiiiii iiiiiiiiiiiii 

COMMENTS 

(\\ 0 •D'l — • fc>7 102 

3 . \ a I.I X — 162 I 

3 is • n 2CI 2<r3 — .SM IV-I 3 

7 •ia tool . 8 381 3 ^ 

— 5 f t M l IV-l J 

i 3 0 I5 \.m /OL>1.b — 4.1 • vl,— \0<c, 3 

b 315 •it, 150 IDI2 .9 am 3*1 ( — I c <T )0l 3 

1 ^5 • n • o K .0 164 3 

8 S2.S 1.Ml In — S3 ton 3 

! 

n i £>0 loll , t a .a 6 ( M 3 «? 

a 61. 5 1,32 10 31.5 5 MO — 50 i n 

3 75 (i 1.03 am So MS ii( 

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11. 5 IT |.H( WQ <- Ux 2 

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wmmmmmmmrnmmBmm 
ENSR i AECOM EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

1 :::iMBiNGE«c.vofs:: : Ortat 

Sampling Trai n Barometric Pressure LEAK CHECKS In "Hg :-:-iflHT.:-:-:-: :-HNAX-:-:>: -RINSE :««: • •:•:<»:• 

R u n Numbe r I O ' Static Pressure (+/-) — o , /? -

INITIAL VAC. In. CF M 

• 0 6 3 0 j 7.6 Clieut Probe/Pitot Number /•V5- 1 - B MID VAC In. CF M loo 7.6 

Facility Location Saw. t-f , X L Pitot Coefficient • SM FINAL VAC. 7 In. CFM. ^ 

/ 

•oo l / C C 8.2 Source Filter Box No. HtVB + /- . 

In. CFM. ^ 

/ + - 0 l o o 8.2 

Date Meier Box No. HASH 1N1T. PITOT ^ FINAL PITOT S6 

Operator T- (sot' Orifice Caefficieut (V) i oa'X FILTE R DAT A 

Stack Dia. - la. Delta 11 (fi. •::NDMBEB:-: TABE . :•: / H P 

Start Time Nozzle Size/No. 7b TAX. 

Stop Time X A D Thermocouple ID: •:::::SIUCA:GED::::-: - Final Purge Kate 

Imp Outlet TC ID: Final PH 

• 

SAMPL* 

?OINT 

CLOCK VKLOC'lTV 

KFAP 

DeltuP, Inwc 

ORIFIOfc 

MJ5TUR.VOL 

MlaU. ln«c 

«A« Mfcl'ER 

YC-LOME 

re 

TEMPERATURE READINGS, "F PSIMP 

COMMENTS 

SAMPL* 

?OINT 

CLOCK VKLOC'lTV 

KFAP 

DeltuP, Inwc 

ORIFIOfc 

MJ5TUR.VOL 

MlaU. ln«c 

«A« Mfcl'ER 

YC-LOME 

re STACK PKOIIE OVEN 

0RGSANK! 

MODULE fMPiwe* 

•i;;!i;jti*S!*Eri!ER;;i:;;; VACUUM COMMENTS 

SAMPL* 

?OINT 

CLOCK VKLOC'lTV 

KFAP 

DeltuP, Inwc 

ORIFIOfc 

MJ5TUR.VOL 

MlaU. ln«c 

«A« Mfcl'ER 

YC-LOME 

re STACK PKOIIE OVEN 

0RGSANK! 

MODULE fMPiwe* •IN . i;i::ii!(|i|Ei!;i; 

COMMENTS 

Al 0 }fi (LWr>.77A 541 • — t6 |oa 

1 7.< •10 \nl\.0 23« -

£1 f06 I6X 

A le- - Ik ID'IS. 2 2 ift , & (OS 

al. < Ift u& (0fco,3 -S99 — 57 HI /CV 

5 •If 2S7 r<? 1(1 105 H 

C n.< -15 icq.? .q J9S AH? — - wa 10b i 

7 •Ift I , 5 3 IOl 

8 v.< \5 teiio\.B 3<3S 2 YD f « lo? 

Bl LO •IB 2MI PI? %f no 

Jl . 15 l.fcfc — IS iW 11/ 1 3 •Ift un. » 5 ^ — 49 1 ^ HA H 

H w.r -i£ -H1 II33.^ — IS 113 5 

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7 ioT •f<r U3H.S 0A2 2| IW 

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—I 

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—j,TM 

i 

1 
ENSR i AECOM EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Sampling Train 

Hun Number 

Clieut 

Facility Location 

Source 

Date 

Operator 

Stack Dia. - In. 

Start Time 

Stop Time 

_&1 

Barometric Pressure 

Static Pressure (+/-)_ 

Probe/Pitot Number 

Pltot Coefficient _ 

Filter Box No. 

Meter Box No. 

Orifice Coefficient (V) 

- -Ik 

LEAK CHECKS In "Hg 

INITIAL VAC. IL 

MID VAC. 

FINAL VAC. 

Mil INIT. PITOT 

In. 

In. 

C F M 

C F M 

Ja. CF M 

@r ' 

FINAL PITOT 

iS2 i 

3 9 " 

lr?(H FILTER DATA 

law 

Delta H@ 1,931 :::TAHE::-: 

Nozzle Size/No. 

XAD Thermocouple ID: 

Imp Outlet TC ID: 

:iMeihfflBtt.VO£;«;.;: 

:iMT::-

z n 

RINSE 

:SIWCA:GEI/: 

Onat 

:c<n: •y.oi:-

•7-M 

1-1 u 

Final Purge I 

Final PH 

SAMPL* 

POINT 

CLOCK V36LOCITV 

ULAD 

ORlPICg 

MI71 bR VOL 

be(l8<!,lor<f 

CASMEI'ER 

VOLOMP 

re 

TEMPERATUR E READINGS, ° F 

STACK OVt!(f 

OJICSANKJ 

MpDljLf 

^AS-MCTBR 

turn 

VACUU M COMMENTS 

J2. am. X L 

i . s o i l a i l 

2H£L 1±_ 

s yo 3M. 2M. 112. 

J15_ 

ill . 101 

i n . 

2 HO -41 116 log 

31 l iL 2^L 211 

7T? 

It 

J3K. 155 iii . LLL 4 

1 JZa, 

i.ca 2& 210 U6 _LL2_ 

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A 

IO 

JL1L 

MM 

I-oft 391 

3HH 

am 

I C O aM6 

_Lii_ 

_UiL. 

us 

us 
J 

PCDD/PCDF Data 
Veolia ES Technical Solutions 

Fixed Hearth Incinerator #3 

Method 0023A Sampling Parameters 

Run No. Runl Run 2 Run 3 

AVGS 

Date 19-Jun-06 20-Jun-06 21-Jun-06 

AVGS 

Start Time Units 14:40 9:30 9:30 

Stop Time 17:59 13:05 11:43 AVGS 

Nozzle Diameter inches 0.435 0.435 0.435 0.435 

Barometric Pressure in. Hg 29.55 29.50 29.50 29.52 

Net Sampling Time min. 192.0 192.0 192.0 192.0 

Volume Metered dcf 135.215 136.331 133.046 134.864 

Avg. DGM Temp. °F 109.3 107.1 107.9 108.1 

Avg Delta H in H2 0 1.71 1.74 1.67 1.71 

Avg Delta H in. Hg 0.1257 0.1282 0.1225 0.1255 

DGM Calibration Factor -- 1.0320 1.0320 1.0320 1.0320 

Gas Sample Volume dscf 128.363 129.710 126.379 128.151 

Total Water Collected mL 2171.7 2509.0 2250.4 2310.4 

Volume of Water Vapor scf 102.396 118.299 106.106 108.934 

Moisture (measured) , % v/v 44.4 47.7 45.6 45.9 

Moisture (@ saturation) % v/v 101.3 101.5 101.5 101.4 

Dry Mole Fraction, 100-%M -- 0.5563 0.5230 0.5436 0.5410 

C 0 2 at Stack %dry 7.40 7.60 7.40 7.47 

0 2 at Stack %dry 10.00 8.20 9.60 9.27 

CO + N2 %dry 82.60 84.20 83.00 83.27 

Dry Molecular Weight Ib/lb-mole 29.58 29.54 I 29.57 29.57 

Wet Molecular Weight Ib/lb-mole 24.44 24.04 24.29 24.26 

Excess Air at Stack % 84.7 58.5 78.0 73.7 

Stack Diameter inches 39.6 39.0 39.0 39.0 

Stack Area sq. in. 1194.6 1194.6 1194.6 1194.6 

Static Pressure in HzO -0.13 -0.15 -0.17 -0.15 

Stack Pressure in. Hg 29.54 29.49 29.49 29.51 

Avg. Stack Temp. °F 390.4 393.1 385.0 389.5 

Avg. Sqroot of Delta P ~ 0.4113 0.4166 0.4062 0.4114 

SDE Average — 11.994 12.168 11.808 11.990 

Pitot Coefficient - 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,923 1,969 1,901 1,931 

Stack Flowrate wet acfm 15,956 16,338 15,773 16,022 

Stack Flowrate wet scfm 9,781 9,966 9,713 9,820 

Stack Flowrate dscfm 5,441 5,212 5,280 5,311 

Isokinetics % 99 104 100 101 

Meter Box No. — 80645 80645 80645 — 

Delta H @ in. Hg 1.881 1.881 1.881 -

Field QA Yqc ~ 1.048 1.050 1.052 1.050 

[Deviation] Pre-Y % 1.6% 1.7% 1.9% 1.7% 

S:\_JOB\2006\Onyx\Performance TesftTest DataVlune 2006\2nd Retesft[M23A Separate Front, Back Half june 20Q6.xls]DATA 
Method 0023A Sampling Parameters 

PT 

R U N 1 AVG S -• PCDDs/PCDFs R U N 2 AVG S -- PCDDs/PCDFs R U N 3 AVG S •- PCDDs/PCDFs 

PT DP SQR T 

DP 

D G M 

IN 

D G M 

O U T 

DH STAC K 

TEM P 

DP SQR T 

DP 

D G M 

IN 

D G M 

O U T 

DH STAC K 

TEM P 

D P SQR T 

D P 

D G M 

IN 

D G M 

O U T 

D H STAC K 

TEM P 

A1 0,22 0.4690 103 100 2.20 389 0.14 0.3742 94 93 1.40 387 0.14 0.3742 96 95 1.40 370 

1 0.25 0.5000 105 101 2.50 389 0.14 0.3742 95 93 1.40 386 0.11 0.3317 97 95 1.10 380 

2 0.25 0.5000 114 103 2.50 389 0.20 0.4472 96 94 2.00 389 0.15 0.3873 98 96 1.50 382 

2 0.21 0.4583 115 105 2.10 389 0.20 0.4472 99 95 2.00 388 0.16 0.4000 101 97 1.60 385 

3 0.22 0.4690 116 106 2.20 390 0.20 0.4472 101 96 2.00 390 0.15 0.3873 102 97 1.50 385 

3 0.21 0.4583 117 108 2.10 389 0.20 0.4472 105 97 2.00 390 0.15 0.3873 105 99 1.50 386 

4 0.12 0.3464 117 109 1.20 390 0.20 0.4472 104 99 2.00 391 0.17 0.4123 107 100 1.70 388 

4 0.16 0.4000 115 108 1.60 389 0.15 0.3873 106 100 1.50 392 0.17 0.4123 107 101 1.70 388 

5 0.20 0.4472 116 109 2.00 390 0,18 0.4243 108 101 1.80 392 0.14 0.3742 106 104 1.40 390 

5 0.16 0.4000 116 108 1.60 389 0.20 0.4472 108 102 2.00 393 0.17 0.4123 107 104 1.70 390 

6 0.16 0.4000 115 109 1.60 391 0.20 0.4472 109 103 2.00 391 0.20 0.4472 109 105 2.00 391 

6 0.14 0.3742 115 108 1.40 391 0.20 0.4472 109 103 2.00 387 0.15 0.3873 110 105 1.50 390 

7 0.13 0.3606 114 109 1.30 383 0.15 0.3873 109 104 . 1.50 384 0.20 0.4472 113 107 2.00 391 

7 0.15 0.3873 114 108 1.50 383 0.17 0.4123 108 104 1.70 385 0.20 0.4472 113 107 2.00 391 

8 0.13 0.3606 113 108 1.30 387 0.15 0.3873 108 104 1.50 384 0.20 0.4472 114 107 2.00 390 

8 0.14 0.3742 112 105 1.40 388 0.15 0.3873 110 104 1.50 390 0.20 0.4472 115 108 2.00 391 

B1 0.17 0.4123 105 106 1.70 392 0.15 0.3873 107 107 1.50 384 0,12 0.3464 109 108 1.20 327 

1 0.17 0.4123 107 106 1.70 392 0.14 0.3742 109 107 1.40 392 0.12 0.3464 109 107 1.20 313 

2 0.19 0.4359 108 106 1.90 394 0.12 0.3464 112 108 1.20 396 0.20 0.4472 110 107 2.00 371 

2 0.17 0.4123 109 105 1.70 394 0.18 0,4243 113 108 1.80 398 0.20 0.4472 113 109 2.00 393 

3 0.15 0.3873 110 106 1.50 394 0.18 0.4243 115 109 1.80 399 0.20 0.4472 114 109 2.00 393 

3 0.15 0.3873 111 106 1.50 395 0.18 0.4243 115 110 1.80 399 0.20 0.4472 115 109 2.00 394 

4 0.13 0.3606 111 107 1.30 388 0.19 0.4359 115 110 1.90 400 0.18 0.4243 114 109 1.80 393 

4 0.10 0.3162 112 107 1.00 383 0.19 0.4359 115 110 1.90 400 0.18 0.4243 115 110 1.80 395 

S 0.15 0.3873 112 107 1.50 388 0.17 0.4123 115 112 1.70 401 0.12 0.3464 115 110 1.20 394 

5 0.16 0.4000 112 107 1.60 390 0.15 0.3873 116 111 1.50 400 0.14 0.3742 115 111 1.40 388 

6 0.18 0.4243 112 107 1.80 394 0.17 0.4123 116 111 1.70 399 0.14 0.3742 115 112 1.40 395 

6 0.20 0.4472 112 107 2.00 393 0.17 0.4123 116 112 1.70 398 0.13 0.3606 116 111 1.30 395 

7 0.17 0.4123 112 107 1.70 395 0.18 0.4243 117 113 1.80 399 0.13 0.3606 115 111 1.30 395 

7 0.17 0.4123 112 107 1,70 395 0.20 0.4472 116 113 2.00 398 0.17 0.4123 116 112 1.70 395 

8 0.18 0.4243 112 107 1.80 395 0.18 0.4243 116 113 1.80 398 0.22 0.4690 116 112 2.20 395 

8 0.18 0.4243 112 107 1.80 395 0.20 0.4472 115 113 2.00 399 0.22 0.4690 116 111 2.20 396 

A V G 0.17 0.4113 109.3 1.71 390 0.17 0.4166 107.1 1.74 393 0.17 0.4062 107.9 1.67 385 
ENSR EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Sampling Train M &3 A DtOYli\f 

Run Number 

/\ \ Facility Location 

( LBV£L-U Source [)M 

Operator 

fc-ti-ok 

Stack Dla.-ln^ 

Start Time 

Stop 

Nvo t_L_ 

3 f i 

/ W o 

Mtue AWO 

/•fen) 7 

Barometric Pressure 

Static Pressure (+/-) 

Probc/Pltot Number 

Pilot Coefficient _ 

Kilter Box No. 

Meter Box No. 

Orifice Coefficleut (Y) 

Delta H @ 

Noxzle Size/No. 

XAD Thermocouple ID: 

Imp Outlet TC1D 

-0-/3 . 

LEAK CHECKS In "Hg 

INITIAL VAC. / 5 

MID VAC. 

FINAL VAC. | S 

CFM 

CFM 

CFM 

0,00 5 

fio£> V<.f 'NIT. PITOT_ 

+ 

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"A 

Appendix C 

Reference Method Calibrations, Verifications, and Certifications 

S:\_JOB\2006\Onyx\Performance Test\Report\Onyx 2006 

Test Report.doc 

September 2006 
ENSR AECOM 

DRY GAS METER CALIBRATION 

Meter Box No.: 80754 

Check one: 

Annual Calibration X Recalibration 

iDate: 3/14/2006 Pretest Leak Checks | 

Operator James Ruckdeschel Allowable Actual | 

(Barometric Pressure: 28.55 (in Hg)l Positive 0 0.00 | 

[Theoretical Critical Vacuum: 13.47 (in Hg)j (at 5-7ln. H20) in. H20 per min. 

Manufacturer: Anderson NUTECH 

Negative 0 0.000 

Manufacturer: Anderson NUTECH (at 3in.Hg) cfm cfm 

Date Received/Placed in service: Pre 1990 

Serial No.: 80754 

DRY GAS METER DATA CRITICAL ORIFICE DATA 

AH 

(in H20) 

Time 

(min) 

Volume Tern 3 Critical 

Orifice 

Serial* 

K' Orifice 

Calibration 

Coefficient 

Actual 

Vacuum . 

(in Hg) 

Ambient Temperature | 

AH 

(in H20) 

Time 

(min) 

Initial 

(ft3) 

Final 

(ft3) 

Total 

(ft3) 

Initial Final 

Critical 

Orifice 

Serial* 

K' Orifice 

Calibration 

Coefficient 

Actual 

Vacuum . 

(in Hg) 

AH Initial Final Average | 

(in H20) 

Time 

(min) 

Initial 

(ft3) 

Final 

(ft3) 

Total 

(ft3) °F °F 

Critical 

Orifice 

Serial* 

K' Orifice 

Calibration 

Coefficient 

Actual 

Vacuum . 

(in Hg) °F °F °F I 

0.24 20 677.300 683.170 5.870 69 70 48 0.225 15 68 68 68 I 

0.91 15 691.800 700.156 8.356 74 74 52 0.427 15 69 73 71 J 

1.50 15 711.600 722.613 11.013 76 79 63 0.562 15 73 74 74 j 

3.80 10 733.800 744.590 10.790 81 83 76 0.831 15 72 73 73 

I S 

CORRECTED VOLUME 

I Dry Gas Critical | DRY GAS METER DRY GAS METER j 

| Meter Orifice I CALIBRATION CALIBRATION I 

I Vm (std it3) Ver (std ft3

) I FACTOR Y FACTOR AH® \ 

J 5.587 5.591 I 1.001 -0.006 || 1.727 -0.104 | 

[ 7.899 7.936 I 1.005 0.00 1.829 -0.003 | 

I 10.359 10.420 [ 1.006 0.00 1.748 -0.083 I 

I 10.124 10.281 I 1.016 0.01 2.022 0.19 I 

i 

| Avg. 1.007 ] I Avg. AH ® 1.832 | 

Notes: 1) For valid test results, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above. 

2) The Critical Orifice Coefficient, rC, must be entered in English units, (fty^'tdeg R)*0.S/((in.Hg)*(mln)). 

3) The minimum number of sample volume required per orifice is 5 cubic feet. 

4) For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of individual values from the average is ±0.C 

5) For Orifice Calibration Factor AH @, the orifice differential pressure in inches of H20that equates to 0.75 cfm of air at 68 F and 29.92 inches of Hg, 

acceptable tolerance of individual values from the average is ± 0.2. 

Dry Gas Mater Thermocouple Calibration 

Ref. TC ID# Fluke RTD 213103! Inlet ID#: 80754-IN Outlet ID#: 80754-OUT 

Ref. Source Ref, °F °F A °F A 

Amb. Air 65 66 -1 66 1 

Hot Water 106 106 0 104 -2 

Potentiometer Calibration | 

Low 50 °F 50 

Mid 450 °F 450 

High 950 °F 952_J 

Notes: 1) Hot Water to be in the range of 104-122 °F. 

2) Tolerance allowed for all thermocouple individual readings : ± 5.4 °F 

3} Tolerance allowed for all potentiometer individual readings: ± 2 °F 

P. + 

V.^ ) = ".64 (y„> 

AH 

13 .6 

t. +460 

cr (std ) 

n{std ) 
ENSR •AECOM 

DRY GAS METER CALIBRATION 

Meter Box No.: 80645 

Check one: 

Annual Calibration X Recalibration 

Date: 12/27/2005 I Pretest Leak Checks 

lOperator: Ryan Burns I Allowable Actual 

barometric Pressure: 29.50 (inHg) 1 Positive 0 0.00 

|Theoretical Critical Vacuum: 13.92 (in Hg) j (at 5 - 7 in. H20) in. H20 per min. 

I Negative 0 0.000 

Manufacturer: Anderson NUTECH j (at 3 in. Hg) cfm cfm 

Date Received/Placed in service: Pre 1990 

Serial No.: 

DRY GAS METER DATA CRITICAL ORIFICE DATA 

AH 

(in H20) 

Time 

(min) 

Volume Tern P Critical 

Orifice 

Serial # 

K' Orifice 

Calibration 

Coefficient 

Actual 

Vacuum 

(inHg) 

Ambient Temperature 

AH 

(in H20) 

Time 

(min) 

Initial 

(ft3) 

Final 

(ft3) 

Total 

(ft3) 

Initial Final 

Critical 

Orifice 

Serial # 

K' Orifice 

Calibration 

Coefficient 

Actual 

Vacuum 

(inHg) 

AH Initial Final Average 

(in H20) 

Time 

(min) 

Initial 

(ft3) 

Final 

(ft3) 

Total 

(ft3) °p V 

Critical 

Orifice 

Serial # 

K' Orifice 

Calibration 

Coefficient 

Actual 

Vacuum 

(inHg) °F °F °F 

0.26 20 826.500 832.327 5.827 81 81 40 0.225 15 68 68 68 

0.99 15 811.800 819.950 8.150 83 83 52 0.427 15 68 68 68 

1.80 15 777.400 788.205 10.805 80 80 63 0.562 15 68 68 68 

4.00 10 857.400 868.228 10.828 80 80 76 0.831 15 68 68 68 

CORRECTED VOLUME 

Dry Gas 

Meter 

Vm (std ft3) 

Critical 

Orifice 

Ver (std ft3) I 

5.609 5.782 

7.830 8.223 

10.459 10.825 

10.539 10.667 

DRY GAS METER 

CALIBRATION 

FACTOR Y 

I 1.031 -0.001 j 

I 1.050 0.02 I 

1.035 .0.00 I 

j 1.012 -0.02 j 

I I 

DRY GAS METER 

CALIBRATION 

FACTOR AH® 

1.750 -0.131 j 

1.853 -0.028 

1.944 0.063 

1.977 0.10 

I 

I Avg. Y 1.032 j j Avg. AH @ 1.881 \ 

Notes: 1) For valid test results, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above. 

2) The Critical Orifice Coefficient, K\ must be entered in English units, (fty^'fdeg Ryvj.5/((in.Hg)*(min)). 

3) The minimum number of sample volume required per orifice is 5 cubic feet. 

4) For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of individual values from the average 

5) For Orifice Calibration Factor AH ®, the orifice differential pressure in inches of H20 that equates to 0.75 dm of air at 68 F and 29.92 inches of Hg, 

acceptable tolerance of Individual values from the average Is ± 0.2. 

Ref.TCIO* 2131035 Inlet ID#: 80645-IN Outlet ID#: 80645-OUTl Low 50 °F 50 

Ref. Source Ref, °F °F A °F A Mid 450 °F 449 

Amb. Air 68 68 0 68 

0 I High 950 °F 948 | 

Hot Water 112 112 0 111 -1 | 

Notes: 1) Hot Water to be in the range of 104 -122 °F. 

2) Tolerance allowed for all thermocouple individual readings : ± 5.4 °F 

3) Tolerance allowed for all potentiometer individual readings : ± 2 °F 

: 17 .64 (ym ] 

p. + 

AH 

/„ + 460 

' («d ) 

m (std 
ENSR AECO M 

DRY GAS METER CALIBRATION 

Meter Box No.: 80184 

Check one: 

Annual Calibration Recalibration 

Date Received/Placed in service: 

Serial No.: 

Date: 12/27/2005 1 Pretest Leak Checks [ 

Operator: Ryan Burns | Allowable Actual j 

Barometric Pressure: 29.50 (in Hg)j Positive 0 0.00 

Theoretical Critical Vacuum: 13.92 (in Hg)| (at 5-7in. H20) in. H20 per min. 

Negative 0 0.000 

Manufacturer: Anderson NUTECH (at 3 in. Hg) cfm cfm 

DRY GAS METER DATA CRITICAL ORIFICE DATA I 

Volume Temp Critical K' Orifice Actual Ambient Temperature I 

AH Time Initial Final Total Initial Final Orifice Calibration Vacuum Initial Final Average j 

(in H20) (min) (ft3

) (ft3) (ft3

) °F °F Serial # Coefficient (inHg) °F °F °F 

0.26 20 103.300 109.115 5.815 78 79 40 0.225 15 68 68 68 

0.99 15 83.300 91.385 8.085 75 76 52 0.427 15 68 68 68 

1.80 15 161.700 172.468 10.768 82 83 63 0.562 15 68 68 68 

4.00 10 134.000 144.631 10.631 83 84 76 0.831 15 68 68 68 

CORRECTED VOLUME 

Dry Gas 

Meter 

Vm (std ft3) 

Critical 

Orifice 

Ver (std ft3) 

5.623 5.782 

7.876 8.223 

10.375 10.825 

10.280 10.667 

DRY GAS METER 

CALIBRATION 

FACTOR Y 

1.028 -0.010 

1.044 0.01 

1.043 0.00 

1.038 0.00 

DRY GAS METER 

CALIBRATION 

FACTOR AH® 

I 1.750 -0.131 I 

1.853 -0.028 

1.944 0.063 

1.977 0.10 

j Avg. Y 1.038 | Avg. AH @ 1.881 | 

Notes: 1) For valid test results, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above. 

2) The Critical Orifice Coefficient, K', must be entered in English units, (ft^S'ldeg R)"0.5/((in.Hg)-(min)). 

3) The minimum number of sample volume required per orifice is 5 cubic feet. 

4) For Calibration Factor Y, the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of individual values from the average is 

5) For Orifice Calibration Factor AH®, the orifice differential pressure in inches of H20 that equates to 0.75 cfm of air at 68 F and 29.92 inches of Hg, 

acceptable tolerance of individual values from the average is ± 0.2. 

Dry Gas Meter Thermocouple Calibration 

| Ref. TCID# 2131035 Inlet ID*: 80184-IN Outlet ID#: 80184-OUT 

Ref. Source Ref, °F °F A °F A 

Amb. Air 68 68 0 68 0 

Hot Water 111 111 0 111 o 

| Potentiometer Calibration 

Low 50 °F 50 

Mid 450 °F 450 

High 950 °F 951 

Notes: 1) Hot Water to be in the range of 104 -122 °F. 

2) Tolerance allowed for all thermocouple individual readings : ± 5.4 °F 

3) Tolerance allowed for all potentiometer individual readings : ± 2 °F 

•r 
ENSR AECO M SAMPLE PROBE CALIBRATION DATA FORM 

TYPE "S" PITOT TUBE ASSEMBLY AND NOZZLE 

Thermocouple Calibration 

PROBE ID: 

M5-4-A 

Reformc* 

TrrarmomatwID #: 

PROBE ID: ENSR RTD #2131035 Omega cnooo, *06022200 Omega CI1000, #06022200 

M5-4-A 

Reformc* 

TrrarmomatwID #: 

k»BaH) Boiling Wtter TUDoFumaco[300* SOO* 0 

PROBE ID: 

M5-4-A 

« . — _ - • - TC Hr* Tar« y«w a — r l « Jva * 

jl« 3/6/2006 

M5-4-A 

32.59 273.46 34 274 1 212.2 373.3 214 374 0.3 450.0 505.3 451 506 0.1 

ra 

M5-4-A 32.59 273.48 34 274 1 212.1 373.2 214 374 0.3 450.0 505.3 451 506 0.1 

ra 

M5-4-A 

32.60 273.48 34 274 1 212.0 373.1 214 374 0.3 450.0 505.3 451 506 0.1 

32.59 273.48 34 274 1 212.1 373.2 214 374 0.3 450.0 505.3 451 506 0.1 

Type "S" Phot Tube Calibration: 

Level and Perpendicular 

Obstruction 

Damaged 

a, (-10°-: a, £ + 10°) 

ctj (-10° £ o^s +10°) 

B, (-5° 2 6,5+5*) 

S2 (-5°s B2 s +5°) 

T 

e 

z = ATany(±-- 0.125") 

W = ATan9(±s 0.03125") 

D, (3/16 s D,-5 3/8-) 

A/2D, (1.05 £ P W 1-5) 

No 

No 

0.8 

0.5 

0.925 

1.23 

D*ar*« indkwtlns Uv*l po»*ttor. for 

d«t«m(n.naTth«n calculate Z. 

Pitot Tube to Nozzle Calibration: 

1) Pltot to nozzla separation 

2) TriefiTVXOLtpte to pilot separ. 

3) Pltot and lo probe union dial 

>3/4" (H/.500 nozzle) 

>3/4' 

>3.0' 

Probe Information 

(Manufacturer: 

Date Received and placed In Service: 

Condition ol Probe when placed In service: 

.QA/QC Check 

Completeness X_, Legibility 

RECONDITIONED (circle one) 

Accuracy X _ 

certify that the Type S pltot tube/probe ID#_ _M5-4'-A_ _ meets orexceeds afl Specffications, 

icftteria and/or applicable design features and Is hereby assigned a pltot tube calibration (actor Cp of 0.84 

Cartilled by: Fred Sanguodoice / 03-13-2006 

Personnel (Signature/Date) Team Leader (Signature/Date) 

All construction criteria for an Isolated *3" type pltot are within given tolerances prescribed In 

Quality Assurance Handbook tor Air Pollution Measurement Systems: Volume III, Stationary Source-Specific Methods. 

EPA/600/R-94/038c, September 1994 

~>v 06/PS 

WOTES: 
ENS R AECO M SAMPLE PROBE CALIBRATION DATA FORM 

TYPE "S" PITOT TUBE ASSEMBLY AND NOZZLE 

Thermocouple Calibration 

Rajforenca 

TrMnTOTietwrlD #. 

M5-4-B 

M5-4-B 

ENSR RTO #2131035 

273.52 

273.52 

34 

34 

35 

274 

Omega cuooo, #06022200 

212.2 

212.2 

373.3 

373.3 

210 372 

Omega CM 000, #06022200 

Tuba Furnace (300* - SOO* F) 

450.0 

450.0 

505.3 

447 

447 

503 

504 -0.3 

504 -0.3 

32.67 273.52 34 212.2 373.3 210 •0.3 450.0 505.3 447 503 

Type "S" Pitot Tube Calibration: W-* 

> ~*=F 

Level and Perpendicular 

Obstruction 

Damaged 

a, (-10° £ a, £ + 10°) 

a-, (-10° £ a,, £ +10°) 

B, (-5°£ B, £+5°) 

B-. {-5°£ fl2£ +5°) 

1 

0 

z = ATany(±£ 0.125") 

W = ATan0(-t£ 0.03125") 

D, (3/16 £ D,£ 3/8") 

A 

A/2D, (1.05 £ P,/D,£ 1-S) 

O-agrw* indicating Uv«l position for 

dat«mintneYth« n calcutct* Z. 

Yes 

No 

No 

0.1 

0.9 

0.014 

0.375 

Pitot Tube to Nozzle Calibration: 

atria l 

V».7.«aTtfair..) 

= l i 

Bal l 

1) Pilot to nozzle S«f 

2) Thtymocoople to pilot s«par. 

3) Pltot and to probe union dtst 

>3/4' (w/.500nozzte) 

>3/4" 

>3.0" 

0.376 

0.975 

Probe Information 

(Manufacturer 

Date Received and placed In Service: 

I Condition ot Probe when placed In service: 

pre-1995 

QA/QC Check 

Completeness X Legibility _X_ _ 

RECONDITIONED (circiaone) 

Accuracy . Specifications X _ [Reasonableness X 

11 certify that the Type S pitot tube/probe 1D#_ _ meets or exceeds all Specifications, 

criteria and/or applicable design features and Is hereby assigned a pilot tube calibration (actor C^ot 0.84 

Certified by: Fred Sanguedolce / 03-13-2006 

Personnel (Signature/Date) Team Leader {Signature/Date) 

AU construction criteria for an Isolated "S" type pltot are within given tolerances prescribed in 

(Quality Assurance Handbook for Air Pollution Measurement Systems: Volume 111, Stationary Source-Specific Ntetnods. 

EPA/600/R-94/038C. September 1994 

!

^>V06/PS 
ENS R AECO M SAMPLE PROBE CALIBRATION DATA FORM 

TYPE "S" PITOT TUBE ASSEMBLY AND NOZZLE 

Thermocouple Calibration 

MS 5-F 

MS-5-F 32.18 

32.18 

273.25 

273.25 

33 

Omega CM 000 #060 

211.8 

211.8 

373.0 

373.0 

209 371 

371 

-0.4 

-0.4 

-0.4 

Omega CI1000 #0602 

450.0 505.3 

450.0 505.3 

443 

443 

502 -0.7 

501 

273.25 211.8 373.0 209 •0.4 450.0 505.3 443 

Type "S" Pitot Tube Calibration: 

Level and Perpendicular 

Obstruction 

Damaged 

a, (-10° £ a, £ + 10°) 

(-10°£ a-£ +10°) 

B, (-5°£ I3,£+5°) 

13-, <-5°£G2£+5°) 

T 

0 

z = ATany(±£ 0.125") 

W = ATan0(±s 0.03125") 

0, (3/16 £ D,£ 3/8") 

A 

A/2D, (1.05£ PVD|£ 1-5) 

D«gr* « indicating Wv«i poaJtlon for 

detan-itnlnsfthan ctslculat* Z . 

Yes 

0.3 

0.9 

-0.4 

1.12 

Pitot Tube to Nozzle Calibration: 

Yin7,aawn<3ln.) j 

1) Pltot to nozzle separation X 

2) TtiefTTrOCoapla to pltot separ. Z 

3) Pltot end to probe union dist Y 

>a/4' (w/,500 nozzle) 

>3/4* 

>3.0' 

1.027 

1.&45 

Probe Information 

Manufacturer. 

Date Received and placed tn Service: 

iCondttton o( Probe whan placed In service: 

|QA/QC Check 

Completeness Legibility _X _ 

RECONDITIONED (circle one) 

Accuracy X _ Specifications __X__ Reasonableness 

I certify that the Type S pilot tube/probe ID#_ _M5-5'-F_ _ meets or exceeds all Specifications. 

icitterta and/or applicable design features and Is hereby assigned a pitot tube calibration factor CD o10.84 

Certified by: Fred Sarquedolca / 03-13-2006 

Personnel (Signature/Date) Team Leader (Signatura/Date) 

All cor^ructton criteria tor an isolated "S" type pilot are within given tolerances prescribed in 

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III. Stationary Source-Specific Methods. 

|6PA/600/R-94/038c, September 1994 

06/PS 

NOTES: 
ENSR 

Calibrator: Ryan Burns Reference Thremometer ID: DVM CCL050152417 

Date: 3/6/2006 

Last Impinger Thermocouple Calibration 2006 

Thermocouple Reference Difference (+/- 2°) Thermocouple Reference Difference (+/- 2°) 

1 1 o Hot 212 212 0 1 1-91 Hot 211 211 0 

Ll-Z 

Cold 33 32 1 Cold 33 32 1 

Manufacturer Anderson NUTECH Manufacturer Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

1 1 A Hot 211 211 0 Hot 213 212 1 

LI-4 

Cold 33 33 0 Cold 35 33 2 

Manufacturer Anderson NUTECH Manufacturer: 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

1 I-/5 Hot 0 1 1-9'? Hot 211 212 -1 

LI-O 

Cold 0 Cold 35 33 2 

Manufacturer: Anderson NUTECH Manufacturer Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-7 Hot 212 212 0 LI-24 Hot 0 LI-7 

Cold 33 32 1 

LI-24 

Cold 0 

Manufacturer. Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

mm P M 

U-8 Hot 212 212 0 LI-25 Hot 212 212 0 U-8 

Cold 34 33 1 

LI-25 

Cold 33 32 1 

Manufacturer Anderson NUTECH Manufacturer Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-9 Hot 211 212 -1 Ll-26 Hot 214 212 2 LI-9 

Cold 33 33 0 

Ll-26 

Cold 35 34 1 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-10 Hot 212 212 0 LI-27 Hot 210 212 -2 LI-10 

Cold 32 32 0 

LI-27 

Cold 34 33 1 

Manufacturer: Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

Ll-11 Hot 0 1 I-9A Hot 212 212 0 Ll-11 

Cold 0 Cold 33 33 0 

Manufacturer. Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-12 Hot 211 212 -1 1 I-9Q Hot 212 212 0 LI-12 

Cold 32 32 0 Cold 33 33 0 

Manufacturer: Anderson NUTECH Manufacturer Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

Ll-13 Hot 213 212 1 Hot 213 212 1 Ll-13 

Cold 33 33 0 

1.1*0 

Cold 34 33 1 

Manufacturer: Anderson NUTECH Manufacturer Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-20 Hot 211 211 0 1 1 1A Hot 211 211 0 LI-20 

Cold 34 33 1 

Ll- 1 1 

Cold 32 33 -1 

Manufacturer: Anderson NUTECH Manufacturer Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in ser. Pre 1990 Date received/placed in service: Pre 1990 

; chectt vaiire usee for lmpnaj- trfat

 11 
ENSR AECO M 

Calibrator: Fred Sanguedofce Reference Thermometer: Fluke RTD 2131035 

Fitter Box Calibration 

Hot Box #1 Hot Box #11 

Manufacturer: Anderson NUTECH Iv anirfacturer: Anderson NUTECH 

Serial No.: 

Data received/placed In service: 

N/A 

Pre 1995 

S 

D 

erialNo.: 

ate received/placed In service: 

N/A 

Pre 1995 

Calibration Date: 16-Feb-06 C .alibration Date: 16-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 69 247 P eterence Temperatures 72 246 

Actual Temperatures 69 249 A dual Temperatures 71 249 

Temp Difference (tol. - +-2) 0 -2 1 emp Difference (tol. * +-2) 1 -1 

Hot Be >X#2 Hot Box #12 

Manufacturer: Anderson NUTECH t\ rlanufacturen Anderson NUTECH 

Serial No.: N/A •arial No.: N/A 

Date received/placed In service: Pre 1995 r. ate received/placed In service: Pre 1995 

Calibration Date: 15-Feb-06 C Alibration Date: 16-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 66 249 f Reference Temperatures 70 246 

Actual Temperatures 70 247 Actual Temperatures 71 247 

Temp Difference (tol. = +-2) -2 2 emp Difference (tol. = +-2) -1 -1 

Hot Box #3 Hot Box #13 

Manufacturer: Anderson NUTECH vlanufacturer: Anderson NUTECH 

Serial No.: N/A Serial No.: N/A 

Date racervad/placed In service: Pre 1995 Dale received/placed in service: Pre 1995 

Calibration Date: 16-Feb-06 Calibration Date: 1$-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 69 244 Reference Temperatures 67 246 

Actual Temperatures 69 244 Actual Temperatures 67 246 

Temp Difference (tol. = +-2) 0 0 Temp Difference (tol. = +-2) 0 0 

Hot Box #4 Hot Box #14 

Manufacturer Anderson NUTECH Manufacturer. Anderson NUTECH 

Serial No.: 

•ate received/placed In service: 

N/A 

Pre 1995 

Serial No.: 

Date received/placed in service: 

N/A 

Prft1995 

Calibration Date: 1&-Feb-06 Calibration Date: ie-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 71 244 Reference Temperatures 68 247 

Actual Temperatures 71 243 Actual Temperatures 70 247 

Temp Difference (tol. = +-2) 0 1 Temp Difference (tol. = +-2) -2 0 

Hot Box #5 Hot Box #15 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: 

Date received/placed In service 

N/A 

Pre 1995 

Serial No.: 

Date received/placed In service: 

N/A 

Pre 1995 

Calibration Date: 16-Feb-06 Calibration Date: 15-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 66 251 Reference Temperatures 68 247 

Actual Temperatures 66 252 Actual Temperatures 66 247 

Temp Difference (tol. = +-2) 0 -1 Temp Difference (tol. = +-2) 2 0 

HoU 3ox#6 Hot Box #16 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: 

Date received/placed In service 

N/A 

Pre 1995 

Serial No.: 

Date received/placed in service 

N/A 

Pre 1995 

Calibration Date: 16-Feb-06 Calibration Date: 17-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 69 245 Reference Temperatures 71 241 

Actual Temperatures 70 245 Actual Temperatures 69 241 

Temp Difference (tol. = +-2) -1 0 Temp Difference (tol. = +-2) 2 0 

Hot BOX #7 Hot Box #17 

Manufacturer: 

Serial No.: 

Date received/placed In service 

Anderson NUTECH 

U/A 

Pre 1995 

Manufacturer: 

Serial No.: 

Date received/placed in service 

Anderson NUTECH 

N/A 

Pre 1995 

Calibration Date: 16-Feb-06 Calibration Date: 16-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 

Actual Temperatures 

Referenc 71 248 Reference Temperatures 69 245 e Temperatures 

Actual Temperatures 71 250 Actual Temperatures 70 247 

Temp Difference (tol. = +-2) 0 -2 Temp Difference (tol. = +-2) -1 -2 

Hot Box #6 Hot Box #18 

Manufacturer: Anderson NUTECH 

Serial No.: N/A 

Date received/placed In servfca: Pre 1995 

Manufacturer: Anderson NUTECH 

Serial No.: N/A 

Date received/placed in service: Pre 1995 

Calibration Date: 16-Feb-06 Calibration Date: 15-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 70 244 Reference Temperatures 72 247 

Actual Temperatures 71 246 Actual Temperatures 70 248 

Temp Difference (tol, = +-21 -1 •2 Temp Difference (tol. = +-2} 2 -1 

Hot Box #9 Hot Box #19 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: N/A 

Date recetved/placed in service: Pre 1995 

Serial No.: N/A 

Date received/placed in service: Pre 1995 

Calibration Date: 1&-Feb-06 Calibration Date: 16-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 69 249 Reference Temperatures 70 244 

Actual Temperatures 

Temp Difference (tol. = +-2) 

Actua 70 251 Actual Temperatures 71 244 l Temperatures 

Temp Difference (tol. = +-2) -1 -2 Temp Difference (tol. = +-2) -1 0 

Hot Box #10 Hot Box #21 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: N/A 

Date received/placed tn service: Pre 1995 

Serial No.: N/A 

Date received/placed In service: Pre 1995 

Calibration Date: 16-Fetv06 Calibration Date: 17-Feb-06 

Ambient Hot Ambient Hot 

Reference Temperatures 73 247 Relerence Temperatures 66 241 

Actual Temperatures 72 246 Actual Temperatures 69 243 

Temp Difference (tol. = +-2) 1 1 Temp Difference (tol. = -4-2) -1 -2 
ENSR AECOM 

XAD Thermocouple Calibrations - 2006 

date 3/13/2006 

BP: 29.1 

Reference Thermometer ID#: 

Manufacture: 

Date placed in Service: 

Calibrator: James Ruckdeschel 

Ambient Temp (F): 63 

Fluke Digital RTD 2131035 

Fluke 

Pre 1980 

Ice Bath I Ambient 

Thermocouple 

1D# 

Reference 

Temp 

XAD 

Temp 

Temp 

Difference 

Tol = +-2 F 

Reference 

Temp 

XAD 

Temp 

Temp 

Difference 

Tol = +- 2 F 

XAD-1 33 32 -1 62 62 0 

XAD-2 33 33 0 62 63 1 

XAD-3 33 31 -2 62 62 0 

XAD-4 31 31 0 63 63 0 

XAD-5 31 33 2 63 63 0 

XAD-6 32 32 0 63 63 0 

XAD-7 32 32 0 64 64 0 

XAD-8 32 32 0 65 63 -2 

XAD-9 0 0 

XAD-10 32 32 0 66 64 -2 

XAD-11 0 0 

XAD-12 0 0 
ENSR 

Appendix D 

Stack Configuration, Sampling Port and Traverse Point Locations 

S:\JOB\2006\OnyjAPerforrnance Test\Report\Onyx 2006 

Test Report.doc 

September 2006 
T3 

ENSR 

ENSR CORPORATION 

6601 Klrfcvllle Road 

East Syracuse, New York 13057 

AECOM 

FIXED HEARTH INCINERATOR UNIT 3 

VEOLIA ES TECHNICAL SOLUTIONS 

Sauget, Illinois 

i 

1 

PHONE: (315) +32-0506 

FAX: (315) 437-0509 

WEB: HTTP://WWW.ENSR.AEC0M.COM 

PHONE: (315) +32-0506 DRAWN BY: CHECKED BY: DATE: PROJECT NUMBER; DRAWING NUMBER: 

FAX: (315) 437-0509 

WEB: HTTP://WWW.ENSR.AEC0M.COM LLM WW 9/11/0 6 10002-01 7 1 OF 1 

< 
) 

I 

TRAVERSE POINT LOCATIONS 

(Particulate Traverse - Circular Stack) 

FACILTY: Onyx Environmental Services 

STACK IDENTIFICATION: Unit 3 

STACK DIAMETER: 39 inches 

SAMPLING LOCATIONS: 14.95 diameters downstream 

9.85 diameters upstream 

MINIMUM NUMBER OF TRAVERSE POINTS 

AS SPECIFIED BY EPA METHOD 1: 16 

NUMBER OF TRAVERSE POINTS SAMPLED: 16 

Traverse Point Percent of Stack Diameter 

Number From Inside Wall 

Distance in Inches 

From Inside Wall* 

1 3.2 1.2 

2 10.5 4.1 

3 19.4 7.6 

4 32.3 12.6 

5 67.7 26.4 

6 80.6 31.4 

7 89.5 34.9 

8 96.8 37.8 

* For stacks with an inside diameter (ID) of 24 inches or less, no traverse point may be located within 

0.5 inches of the inside wall. For stacks with an ID greater than 24 inches, no traverse point may be 

located within 1.0 inches of the inside wall. Any point not meeting the criteria shall be adjusted. 
ENSR 

Appendix E 

Laboratory Data 

S:\_JOB\2006\Onyx\Performance Test\Report\Onyx 2006 

Test Report.doc 

September 2006 
ENSR AECOM 

ENSR Air Toxics TSP Laboratory 

Analytical Report 

Client: Jeff Gorman Client ID: 10002-017 

ENSR 

6601 Kirkville Road 

E. Syracuse, NY 13057 

Laboratory ID: 06-067 Date Received: 5/12/06 

A l l work contained in this report has been done in accordance with laboratory standard operating procedures. ENSR's Air 

3 Toxics TSP Laboratory follows methodologies based upon standard EPA/NIOSH/OSHA Methods. Data contained herein 

should be considered accurate and complete to the best of our knowledge. This report cannot be dupUcated in part without 

the written pennission of ENSR. 

Arthur Carpenito / Date 

Laboratory Analyst 

ENSR Air Toxics TSP Laboratory 

NYSDOH / NELAC # 11631 

page 1 of 6 
ENSR I ArX.PM 

Method 5 Exposed Filter Data Sheet 

Project Manager: 

Project Name: 

Project Nunrtber: 

Analysis Mathod: 

Project Manager: Jeff Gorman 

Project Name: 

Project Nunrtber: 

Analysis Mathod: 

Onyx Start Friday 05/12/06 16:34 45 72 AC 

Project Manager: 

Project Name: 

Project Nunrtber: 

Analysis Mathod: 

10002-017 Wt. 1 Monday 05716706 15:30 36 72 AC 

Project Manager: 

Project Name: 

Project Nunrtber: 

Analysis Mathod: tttJlrtlf'lWIrnalinrt. * or Oven Dried Wt. 2 Tuesday 05/16/06 9:28 37 72 AC 

Wt.3 

Wt. 4 

OASIflSt Initial Wolahl 

filter* 

Samplo 

ftunDat* 

•k'.y im^i^'.'.b;. i. i 

, *8»mnKilD 

Filter 

J^po/Stlg^ 

1»l wu 

•Sffi'mi1.* 

jlnd Wt. A1UWt 

Grairij|

 J 

•4th wj •" 

OftTM*" 

OASIflS Tsiuvn. AF^HHW I t 

.1, OM».. filter* 

Samplo 

ftunDat* 

•k'.y im^i^'.'.b;. i. i 

, *8»mnKilD 

Filter 

J^po/Stlg^ 

1»l wu 

•Sffi'mi1.* 

jlnd Wt. A1UWt 

Grairij|

 J 

•4th wj •" 

OftTM*" 

Tsiuvn. 

204 01/09/06 0,4093 G3832 N/A LAB FILTER BLANK 90 mm 0.4092 0.4094 0.0002 okbyWt. 0.4093 0.0003 

204 01/09/06 0.4067 G3825 05/09/06 PRETEST-M5-FILTER 90 mm 0.4101 0.4102 0.0001 ok by Wt. 0.4102 0.0035 

204 01/09/06 0.4057 G3827 05710/06 U3-M5-F-R1 90 mm 0.4086 0.4088 0.0002 okbyWt. 0.4087 0.0030 

204 01/00/06 0.4054 G3824 05/10/06 U3-M5-F-R2 90 mm 0.4136 0.4134 0.0002 ok by Wt. 0.4135 0.0081 

204 01/09/06 0.4054 G3828 05/11/06 U3-M5-F-R3 90 mm 0.4126 0.4124 0.0002 ok bv Wt. 0.4125 0.0071 

•o 

0J 

oa 

CD 

w 

o 

Filler Typa Tolion Quail* 

1. Delia Weighl loloranca t/- O.OOOSg of total woighl less tare weigh! between two consecutive weightings or average weight. 

2. Filters must be weighed wilh Ihe proper conditions (RH = 25 - 60 % and RT = 50-78 deg f) 

3. Fillers must be propotly conditioned (24 hour desiccation: Further Conditioning > 6 hours). 

4. Conditioning for oven method; Oven driod at 105 deg c fo 2-3 hours; Further conditioning > 6 hours. 

5. Total grants below or equal to .0005 (I.DL) is presented as .0003. 
ENSR ! .v. . 

Method S Front Half Acetone Probe Rinse Data Sheet 

Balance Used: Matller 3 

Project Manager: 

Project Name: 

Project Number. 

Analvs/s Method: 

Jelf Gorman mm H i 72 

Project Manager: 

Project Name: 

Project Number. 

Analvs/s Method: 

Onyx Start Tuesday 05/16/06 15:40 44 72 AC 

Project Manager: 

Project Name: 

Project Number. 

Analvs/s Method: 

10002-017 Wt. 1 Wednesday 05/17/06 17:06 41 71 AC 

Project Manager: 

Project Name: 

Project Number. 

Analvs/s Method: Namral Kuanoraiinn or !Hfia);Ai&fiMliifi Wt.2 Thursday 05/18/06 8:47 47 69 AC 

" Wt.3 Thursday 05/18/06 14:48 40 73 AC 

Wt.4 

BASIwol .... 

lLBi>akfijlL 

Simple m 

, .^Simpjo ID 

1 Hold Lab* ' * » lilll 'SSSL 

434 05/11/06 115.1666 32 N/A LAB ACETONE BLANK 50 115.1686 115.1678 0.0008 115.1676 0.0000 ok by WL 115.1678 0.0010 

434 05/11/06 86.2956 39 05/09/06 PRETEST-M5-ACETONE 52 50 86.2992 86.2968 0.0004 ok byWt. 86.2990 0.0034 

434 05/11/06 103.5347 64 05/10/06 U3-M5-AR-R1 63 50 103.5383 103.5377 0.0006 103.5378 0.0001 ok by Wt. 103.5378 0.0031 

434 05/11/06 101.0475 120 05/10/06 U3-M6-AR-R2 111 50 101.0542 101.0540 . 0.0002 ok by Wt. 101.0541 0.0066 

434 05/11/06 105.3632 154 05/11/06 U3-M5-AR-R3 95 50 105.3691 105.3689 0.0002 ok byWt. 105.3690 0,0058 

Acetone Manufacturer/tot No.:_F(sher/052584 : 

Acetono Rinse - 25 mis twico • (SQ nils totnl) . . . 

1. Delia Weight tolerance +/-0.0Q05g of total weightless tare weight between two consecutive weightings or average weight. 

2. Beakers must bo weighed with tho proper conditions (RK = 25 * 50 % and RT « 59-78 deg f) 

3. Beakers must bo property conditioned (24 hour desiccation; Further Conditioning > 6 hours). 

4. Natural Evaporation Method = Evaporate to drynossat room temperature under a hood/watch glass cover 

5. Moat Application = Under a hood and watch glass over sample, apply heat below the boiling point of sample until evaporated to 25 mis; then follow step 4 (above) for remaining portion. 

6. Total grams below or equal to .0005 (LDL) is presented as .0003. 
PROJECT NARRATIVE 

Maxzam Analytics (Burlington ON) 

Maxxam; Job #: A644469 

Client: ENSR International 

Client Project: 10002-017-017 ONYX 

L SAMPLE RECEIPT/ANALYSIS 

a) Sample Listing 

Maxxam Client Date Date Date Date 

ID SamplelD Sampled Received Propped Run 

Mercury IB via EPA Method 29 

L99828 U3-M29-R B 06/05/10 06/05/12 06/05/17 06/05/18 

L99829 U3-M29-R1 06/05/10 06/05/12 06/05/17 06/05/18 

L99830 U3-M29-R2 06/05/10 06/05/12 06/05/17 06/05/18 

L99831 U3-M29-R3 06/05/10 06/05/12 06/05/17 06705/18 

Mercury 2B via EPA Method 29 

L99828 U3-M29-RB 06/05/10 06/05/12 06/05/16 06/05/16 

L99829 U3-M29-R1 06/05/10 06/05/12 06/05/16 06/05/16 

L99830 U3-M29-R2 06/05/10 06/05/12 06/05/16 06/05/16 

L99831 U3-M29-R3 06/05/10 06/05/12 06/05/16 06/05/16 

Mercury 3A via EPA Method 29 

L99828 TJ3-M29-RB 06/05/10 06/05/12 06/05/15 06/05/16 

L99829 U3-M29-R1 06/05/10 06/05/12 06/05/15 06/05/16 

L99830 U3-M29-R2 06/05/10 06/05/12 06/05/15 06/05/16 

L99831 U3-M29-R3 06/05/10 06/05/12 06705/15 06/05/16 

Mercury 3B via EPA Method 29 

L99828 U3-M29-R B 06/05/10 06/05/12 06/05/15 06/05/16 

L99829 U3-M29-R1 06/05/10 06/05/12 06/05/15 06/05/16 

L99830 U3-M29-R2 06/05/10 06/05/12 06/05/15 06/05/16 

L99831 U3-M29-R3 06/05/10 06/05/12 06/05/15 06/05/16 

Mercury 3C via EPA Method 29 

L99828 U3-M29-RB 06/05/10 06/05/12 06/05/16 06/05/18 

L99829 U3-M29-R1 06/05/10 06/05/12 06/05/16 06/05/18 

L99830 U3-M29-R2 06/05/10 06/05/12 06/05/16 06/05/18 

L99831 U3-M29-R3 06/05/10 06/05/12 06/05/16 06/05/18 

Metals in Air (Combined) via EPA Method 29 (ICP/MS) 

L99828 TJ3-M29-RB 06/05/10 06/05/12 06/05/17 06/05/19 

L99829 U3-M29-R1 06/05/10 06/05/12 06/05/17 06/05/19 

L99830 U3-M29-R2 06/05/10 06/05/12 06/05/17 06/05/19 

L99831 U3-M29-R3 06/05/10 06/05/12 06/05/17 06/05/19 

R u n Date is defined as the date of injection ofthe last calibration standard (12 hours or less) 

prior to the samples analyzed within that run sequence. Therefore the time of calibration 

injection that defines the run date is always within 12 hours of the time of sample injection. 

b) Shipping Problems: none encountered 

c) Documentation Problems: none encountered 

JH Page 1 of 2 
IL SAMPLE PREP: 

No problems encountered 

UL SAMPLE ANALYSIS: 

See also comments within the appropriate Certificate of Analysis 

a) Hold Times: all within recommended hold times 

b) Instrument Calibration: aU within control limits 

c) Quality Control: All applicable QC meets control criteria, except where otherwise noted. 

I certify that this data package is in compliance with the terms and conditions of the 

contract, both technically and for other than the conditions detailed above. 

In addition, I certify, that to the best of my knowledge and belief, the data as reported are 

true and accurate. Release of the data contained in this data package has been authorized by 

the cognizant laboratory official or his/her designee, as verified by this signature. 

Mary-Ann< 

JH Page 2 of 2 
2. DATA SUMMARY 

- Certificate of Analysis -

Sample analyte result 

Method blank result 

LCS Results with % Recoveries 

Matrix Spike data with % Recoveries 

Matrix Spike Duplicate data with % Recoveries 

Surrogate recoveries 
2 | ^^^^^ | Driven by service and Science 

Your Project*: 10002-017-017 

Site: ONYX 

Attention: Jeff Gorman 

ENSR International 

6601KirkvilleRd 

East Syracuse, NY 

USA 13057 

Report Date: 200(5/05/20 

CERTIFICATE OF ANALYSIS 

MAXXA M JOB #: A644469 

Received: 2006/05/12,12:00 

Sample Matrix: Filter 

# Samples Received: 4 

Date Date Method 

Analyses Quantity Extracted Analyzed Laboratory Method Reference 

Mercury lB-AirCFilta+Acctone)by CVAA© 4 2006/05/17 2006/05/18 SOPING111 . EPA CFR PTM 29 

Metals in Air (Combined) by ICP/MS© 4 2006/05/17 2006/05/19 SOP TNG 108/109 EPA SW846-6020 

Sample Matrix: Impinger Solution 

# Samples Received: 4 

Analyses Quantity 

Date 

Extracted 

Date 

Analyzed Laboratory Method 

Method 

Reference 

Mercury 3C in Air (HCI Impinger) by CVAA © 

Mercury 3 A in Air (HN03 Rinse) by CVAA Q 

Mercury 2B in Air(HN03/H202 Imp) by CVAA © 

Mercury 3B in Air (KMnO4/H2S04) by CVAA © 

4 2006/05/16 2006/05/18 SOP ING 111 

4 2006705/15 2006/05/16 SOP ING 111 

4 2006/05/16 2006/05/16 SOP ING 111 

4 2006/05/15 2006/05/16 SOP ING 111 

EPA CFR PTM 29 

EPA CFR PTM 29 

EPA CFR PTM 29 

EPA CFR PTM 29 

{1) This test was performed by Maxxam Analytics Burlington 

.72 

Page 1 of 11 

6740 Campobello Road. Misstssauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Tdl free:800-563-6266 Fax: 905-817-5777 
Attention: Jeff Gorman 

ENSR International 

6601KirkvilleRd 

East Syracuse, NY 

USA 13057 

Driven t>y service and Science 

www.wiaxxamanalytlcs.com 

Your Projects. 10002-017-017 

"Site: ONYX 

Report Date: 2006/05/20 

CERTIFICAT E OF ANALYSIS 

-2-

J 

Validated by: 

Total cover pages: 2 

Page2of 11 

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£ AoBlytlcs inc 

Maxxam Job #:A644469 

Report Date: 2006/05/20 

Driven by service and Science 

ENSR International 

Client Project #. 10002-017-017 

Project name: ONYX 

Sampler Initials: 

MERCURY BY COLD VAPOUR AA (FILTER) 

Maxxam ID L99828 L99829 L99829 L99830 L99831 

Sampling Date 2006705/10 2006/05/10 2006/05/10 2006/05/10 2006/05/10 

Units U3-M29-RB U3-M29-R1 U3-M29-R1 

Lab-Dup 

U3-M29-R2 U3-M29-R3 RDL QC Batch MDL 

Total Mercury-1B ug . ND ND ND 0.10 0.27 0.03 972395 0.03 

ND = Not detected 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

Page 3 of 11 

6740 Campobello Road. Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:S00-563-6266 Fax:905-817-5777 
IVi a y&st m 

f w ,s^ Analytic s ir*c 

Maxxam Job #: A644469 

Report Date: 2005/05/20 

Driven by service aitd Science 

www.imixxainanalytics.com 

ENSR International 

Client Project #: 10002-017-017 

Project name: ONYX 

Sampler Initials: 

ELEMENTS BY ICP/MS (FILTER) 

Maxxam ID L99828 L99829 L99829 L99830 L99831 

Samplinq Date 2006/05/10 2006/05/10 2006/05/10 2006/05/10 2006705/10 

Units U3-M29-RB U3-M29-R1 U3-M29-R1 

Lab-Dup 

U3-M29-R2 U3-M29-R3 R D L 3 C Batch M D L 

Total Arsenic (As) ug 0.76 9.29 9.62 249 946 0.40. 972012 0.40 

Total Beryllium (Be) ug ND ND ND ND ND 0.10 972012 0.10 

Total Cadmium (Cd) ug 034 0.68 0.71 1.38 2.76 0.10 972012 0.10 

Total Chromium (Cr) ug 1.01 17.7 19.8 29.0 55.8 0.30 972012 0.30 

Total'Lead (Pb) ug . 2.70 23.9 . . 24.1 22.3 40.6 0.20 972012 0.20 

ND = Not detected 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

Page 4 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N2L8 Tel: 905-817-5700 Toll frae.800-563-6266 Fax:905-817-5777 
Driven by service and Science 

\Tww.maxxamaual}*tic5.com 

ENSR International 

Client Project*: 10002-017-017 

Project name: ONYX 

Sampler Initials: 

MERCURY BY COLD VAPOUR AA (IMPINGER SOLUTION) 

Maxxam ID L99828 L99829 L99829 

Sampling Date 2006705/10 2006/05/10 2006/05/10 

Units U3-M29-RB RDL U3-W29-R1 U3-M29-R1 

Lab-Dup 

RDL Batch MDL 

Total Mercury-2B ug ND 0.3 74.7 75.4 1.6 970091 0.01 

Total Mercury-3A ug ND 0.01 3.38 3.40 0.13 970045 0.05 

Total Mercury-3B ug 0.04 0.02 10.7 10.7 0.5 970066 0.05 

Total Mercury~3C ug ND 0.05 8.55 8.58 0.25 971322 0.05 

ND = Not detected 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

T4 • I-'- IM 

f Analytic* inc 

Maxxam, Job #:A644469 

Report Date: 2006705/20 

Maxxam ID L99830 L99831 

Sampling Date 2006/05/10 2006705/10 

Units U3-M29-R2 3DL U3-M29-R3 .

i

3iw»'!»i:Raiimt M 

Total Mercury-2B ug 104 1.7 78.6 1.5 970091 0.01 

Total Mercury-3A ug 1.29 0.02 1.26 0.02 970045 0.05 

Total Mercury-3B ug 7.99 0.25 1.56 0.05 970066 0.05 

Total Mercury-3C ug 7.95 0.25 7.70 0.25 971322 0.05 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

Page 5 of 11 

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Client Project*; 10002-017-017 

Project name: ONYX 

Sampler Initials: 

Test Summary 

Maxxam 10 

Sample ID 

Matrix 

L99828 

U3-M29-RB 

Filter 

Collected 

Shipped 

Received 

2006/05/10 

2006/05/12 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Mercury 3C in Air (HCI Impinger) bv CVAA CVAA 971322 2006/05/16 2006/05/18 FFS 

Mercury 3A in Air (HN03 Rinse) bv CVAA CVAA 970045 2006/05/15 2006/05/16 FFS 

Mercury 2B in Air(HNO3/H202 Imp) bv CVA CVAA 970091 2006/05/16 2006/05/16 FFS 

Mercury 3B in Air ( KMn04/H2S04) bv CVA CVAA 970066 2006/05/15 2006/05/16 . FFS 

Mercury 1B -Air (Filter+Acetone) bv CVAA CVAA 972395 2006/05/17 2006/05/18 FFS 

Metals in Air (Combined) bv ICP/MS 1CP1/MS 972012 2006/05/17 2006/05/19 N R 

Maxxam ID 

Sample ID 

Matrix 

L99829 

U3-M29-R1 

Filter 

Collected 

Shipped 

Received 

2006/05/10 

2006/05/12 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Mercury 3C in Air (HCI Impinger) bv CVAA CVAA 971.322 2006/05/16 2006/05/18 FFS 

Mercury 3A In Air (HN03 Rinse) bv CVAA CVAA 970045 2006/05/15 2006/05/16 FFS . 

Mercury 2B In AWHNO3/H202 Imp) by CVA CVAA 970091 2006/05/16 2006/05/16 • FFS 

Mercury 3B in Air (KMnO4/H2S04) bv CVA CVAA 970066 2006/05/15 2006/05/16 FFS 

Mercury 1B -Air (Filter+Acetone) bv CVAA CVAA 972395 2006/05/17 2006/05/18 v.. FFS 

Metals "m Air (Combined) bv ICP/MS ICP1/MS 972012 2006/05/17 •2006/05/19 • N R 

Maxxam ID 

Sample ID 

Matrix 

L99829Dup 

U3-M29-R1 

Filter 

Collected 

Shipped 

Received 

2006/05/10 

2006/05/12 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Mercury 3C In Air (HCI Implnqer) bv CVAA CVAA 971322 2006/05/16 2006/05/18 FFS 

Mercury 3A In Air (HN03 Rinse) bv CVAA CVAA 970045 2006/05/15 2006/05/16 • FFS 

Mercury 2B in AiKHN03/H202 Imp) bv CVA CVAA 970091 2006/05/16 2006/05/16 FFS • ' 

Mercury 3B in Air (KMn04/H2S04) bv CVA CVAA 970066 2006/05/15 2006/05/16 " FFS 

Mercury 1B -Air (Filter+Acetone) by CVAA CVAA 972395 2006/05/17 2006/05/18 FFS 

Metals in Air (Combined) bv ICP/MS ICP1/MS 972012 2006/05/17 2006/05/19 N R 

Maxxam ID 

Sample ID 

Matrix 

L99830 

U3-M29-R2 

Fitter 

Collected 

Shipped 

Received 

2006/05/10 

2006/05/12 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Mercury 3C in Air (HCI impinqer) bv CVAA CVAA 971322 2006/05/16 2006/05/18 FFS 

Mercury 3A in Air (HN03 Rinse) bv CVAA CVAA 970045 2006/05/15 2006/05/16 FFS 

Mercury 2B in AWHN03/H202 Imp) bv CVA CVAA 970091 2006/05/16 2006/05/16 FFS 

Mercury 3B in Air (KMnO4/H2S04) bv CVA CVAA 970066 2006/05/15 2006/05/16 FFS 

Mercury 1B -Air (Filter+Acetone) bv CVAA CVAA 972395 2006/05/17 2006/05/18 FFS 

Metals in Air (Combined) bv ICP/MS ICP1/MS 972012 2006/05/17 2006/05/19 N R 

Page 6 of 11 

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IVS a rT 1 

' Analytics Ir 

Maxxam Job #: A644469 

Report Date: 2006/05/20 
. . • Driven by service and Science 

xvww.maxxamanalytics.com 

ENSR International 

Client Project #: 10002-017-017 

Project name: ONYX 

Sampler Initials: 

Test Summary 

Maxxam ID L99831 Collected 2006/05/10 

Sample ID U3-M29-R3 Shipped 

Matrix Filter Received 2006/05/12 

Test Description Instrumentation Batch ' Prepared Analyzed Analyst 

Mercury 3C in Air (HCI Impinger) by CVAA CVAA 971322 ' 2006/05/16 2006/05/18 FFS 

Mercury 3A in Air (HN03 Rinse) by CVAA CVAA 970045 2006/05/15 2006/05/16 FFS 

Mercury 2B In AMHN03/H202 Imp) bv CVA CVAA 970091 ' 2006/05/16 2006/05/16 FFS 

Mercury 3B in Air (KMn04/H2SD4) by CVA CVAA 970066 . 2006/05/15 2006/05/16 FFS 

Mercury 1B -Air (Filter+Acetone) bv CVAA CVAA 972395 ' 2006/05/17 2006/05/18 FFS 

Metals In Air (Combined) bv.lCP/MS ICP1/MS 972012. 2006/05/17 2006/05/19 N R 

Page7of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax:905-817-5777 

tVI at j^y^si m 

Maxxam Job #:A644469 

Report Date: 2006705/20 
IV! Si £>rivert h}- service and Science 

Maxxam Job #:A644469 

Report Date: 2006/05/20 

wwTv.ma xxa manalytlcs.com 

ENSR International 

Client Project ft 10002-017-017 

Project name: ONYX 

Sampler Initials: 

GENERAL COMMENTS 

ICPMS: Post digestion duplicate and spike on sample L99829 

Results relate only to the items tested. 

Page 8 of 11 

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IN/I. a x5^ a m 

ff. try* Anaty:i<« mc 

www.masxamanalytic3.com 

Driven by service mid Science 

ENSR International 

Attention: Jeff Gorman 

Client Project*: 10002-017-017 

P.O.#: 

Project name: ONYX 

Quality Assurance Report 

Maxxam Job Number: GA644469 

QA/QC • 

Batch 

Num Init QCType Parameter 

Date 

Analyzed 

WW/mm/dd Value "/oRecoveiY Units QC Limits 

MATRIX SPIKE 

(L99829) Total Mercury-3A 2006/05/16 0.00, RDL=0.13 102 ug 85- 115 

MATRIX SPIKE 

DUP (L99829) Total Mercury-3A 2006/05/16 0.00, RDL=0.13 105 ug 85- 115 

Spiked Blank - Total Mercury-3A 2006/05/16 0.11, RDL=0.01 106 ug 90- 110 

Spiked Blank DUP Total Mercuty-3A 2006/05/16 0.11,RDL=0.01 107 ug 90- n a 

Method Blank Total Mercury-3A 2006/05/16 ND, RDL=0.01 ug 

RPD Total Mercury-3A 2006/05/16 0.6 % 20 

MATRIX SPIKE 

(L99829) Total Mercury-3B 2006/05/16 0.5, RDL=0.5 105 ug 85- 115 

MATRIX SPIKE 

DUP (L99829) Total Meicury-3B 2006/05/16 0.5, RDL=0.5 107 ug 85- 115 

Spiked Blank Total Mercury-3B 2006/05/16 0.55, RDL=0.05 110 ug 90- 110 

Spiked Blank DUP Total Mercury-3B 2006/05/16 0.54, RDL=0.05 108 ug 90- 110 

Method Blank Total Mercury-3B 2006/05/16 ND, RDL=O.05 ug 

RPD Total Mercury-3B 2006/05/16 0.05 % 20 

MATRIX SPIKE 

(L99829) Total Mercury-2B 2006/05/16 0.0,RDL=1.6 100 ug 85- 115 

MATRIX SPIKE 

DUP (L99829) Total Mercury-2B 2006/05/16 0.0,RDL=1.6 95 ug 85- 115 

Spiked Blank Total Mercury-2B 2006/05/16 0.11, RDL=0.01 107 ug 90- 110 

Spiked Blank DUP Total Mercury-2B 2006/05/16 0.11,RDL=0.01 109 ug 90- 110 

Method Blank Total Mercury-2B 2006/05/16 ND, RDL=0.01 ug 

RPD Total Mercury-2B 2006/05/16 0.9 % 20 

MATRIX SPIKE 

(L99829) Total Mercury-3C 2006/05/18 0.54, RDL=0.25 108 ug 85- 115 

MATRIX SPIKE 

DUP (L99829) Total Mercury-3C 2006/05/18 0.54, RDL=0.25 108 ug 85-•115; 

Spiked Blank Total Mercury-3C 2006/05/18 0.51, RDL=0.05 102 ug- 90-•110 

Spiked Blank DUP Total Mercury-3C 2006/05/18 0.52, RDL=0.05 103 ug- 90-• 110 

Method Blank Total Meroury-3C 2006/05/18 ND, RDL=0.05 "9 

RPD Total Mercury-3C 2006/05/18 0.4 % 20 

MATRIX SPIKE 

(L99829) Total Arsenic (As) 2006/05/19 49.5, RDL=0.40 99 ug 70-•130 

MATRIX SPIKE 

DUP (L99829) Total Arsenic (As) 2006/05/19 49.5, RDL=0.40 99 ug 70-•130 

MATRIX SPIKE 

(L99829) Total Beryllium (Be) 2006/05/19 44.5. RDL=0.10 89 ug 70--130 

MATRIX SPIKE 

DUP (L99829) Total Beryllium (Be) 2006/05/19 45.5, RDL=0.10 91 ug 70 -130 

MATRIX SPIKE 

(L99829) Total Cadmium (Cd) 2006705/19 26.0, RDL=0.10 104 ug 70--130 

MATRIX SPIKE 

DUP (L99829) Total Cadmium (Cd) 2006/05/19 26.3, RDL=0.10 105 ug 70--13© 

MATRIX SPIKE 

(L99829) Total Chromium (Cr) 2006/05/19 52.5, RDL=0.30 105 ug 70 -130 

MATRIX SPIKE 

DUP (L99829) Total Chromium (Cr) 2006/05/19 51.5, RDL=0.30 103 ug 70 -130 

MATRIX SPIKE 

(L99829) Total Lead (Pb) 2006/05/19 50.5, RDL=0.20 101 ug 70 -130 

MATRIX SPIKE 

DUP (L99829) Total Lead (Pb) 2006/05/19 50.5, RDL=0.20 101 ug 70 -130 

Spiked Blank Total Arsenic (As) 2006/05/19 51.5, RDL=0.40 103 ug 85 -115 

Spiked Blank DUP Total Arsenic (As) 2006705/19 51.5, RDL=0.40 103 ug 85 -115 

Spiked Blank Total Beryllium (Be) 2006705/19 47.0. RDL=0.10 94 ug 85 -115 

Spiked Blank DUP Total Beryllium (Be) 2006/05/19 47.0, RDL=0.10 94 ug 85 -115 

970045 FFS 

970066 FFS 

970091 FFS 

971322 FFS 

972012 N R 

Page 9 of 11 

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M a 

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' Driven by service and Science 

fcNSR international 

Attention: Jeff Gorman 

Client Project #: 10002-017-017 

P.O. #: 

Project name: ONYX 

Quality Assurance Report (Continued) 

Maxxam Job Number GA644469 

QA/QC 

Batch 

Num Init QCTvpe Parameter 

Date 

Analyzed 

ww/mm/dd Value % Recovery Units QC Limits 

972012 N_R Spiked Blank Total Cadmium (Cd) 2006/05/19 25.8, RDL=0.10 103 ug 85- 115 

Spiked Blank DUP Total Cadmium (Cd) 2006/05/19 25.8, RDL=0.10 103 ug 85- 115 

Spiked Blank Total Chromium (Cr) 2006/05/19 53.0, RDL=0.30 106 ug 85- 115 

Spiked Blank DUP Total Chromium (Cr) 2006/05/19 53.5, RDL=0.30 107 ug 85- 115 

Spiked Blank Total Lead (Pb) • 2006/05/19 51.0, RDL=0.20 102 ug 85- 115 

Spiked Blank DUP Total Lead (Pb) 2006/05/19 52.0, RDL=0.20 104 ug 85- 115 

* Method Blank Total Arsenic (As) 2006/05/19 ND, RDL=0.40 ug 

Method Blank DUP Total Arsenic (As) 2006/05/19 ND, RDL=0.40 ug 

Method Blank Total Beryllium (Be) 2006/05/19 ND. RDL=0.10 . ug 

Method Blank DUP Total Beryllium (Be) ' 2006/05/19 ND. RDL=0.10 ug 

Method Blank Total Cadmium (Cd) 2006705/19 ND, RDL=0.10 ug 

Method Blank DUP Total Cadmium (Cd) 2006/05/19 ND, RDL=0.10 ug 

Method Blank Total Chromium (Cr) 2006705/19 ND, RDL=0.30 ug 

Method Blank DUP Total Chromium (Cr) 2006/05/19 ND, RDL=0.30 . ug 

Method Blank Total Lead (Pb) 2006/05/19 ND, RDL=0.20 ug 

Method Blank DUP Total Lead (Pb) 2006/05/19 ND, RDL=0.20 ug 

RPD Total Arsenic (As) 2006/05/19 3.5 % 20 

Total Beryllium (Be) 2006/05/19 NC % 20 

Total Cadmium (Cd) 2006/05/19 3.9 % 20 

Total Chromium (Cr) 2006/05/19 11.2 % 20 

Total Lead (Pb) 2006/05/19 0.7 % 20 

972395 FFS • MATRIX SPIKE 

(L99829) Total Mercury-1B 2006/05/18 0.30. RDL=0.03 99 ug . 85- 115 

MATRIX SPIKE 

DUP (L99329) Total Mercury-1 B 2006/05/18 0.30, RDL=0.03 100 ug 85- 115 

Spiked Blank : Total Mercury-1 B 2006/05/18 0.31,RDL=0.03 103 ug 90- 110 

Spiked Blank DUP Total Mercury-1 B 2006/05/18 0.31,RDL=0.03 103 ug 90- 110 

Method Blank Total Mercury-1 B 2006/05/18 ND, RDL=0.03 ug 

RPD Total Mercurv-1B 2006/05/18 NC % 20 

ND = Not detected 

NC = Non-calculable 

RPD = Relative Percent Difference 

SPIKE = Fortified sampie 

Page 10 of 11 

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Validation Signature Paqe 

Maxxam Job #: A644469 

The analytical data and all QC contained in this report were reviewed and validated by the following individuals). 

FRANK MO, B.Sc, Inorganic Lab. Manager 

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of 

ISO/IEC 1702S:2005(E), signing the reports. SCC and CAEAL have approved this reporting process and electronic report format 

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Section I: Sample Inventory Report 

Date Received: 

Project No.: 

Project Name: 

6/22/2006 

27803 

10002-017 

Lab. Sample ID Client Sample ID Component ID 

001 

002 

003 

004 

005 

006 

007 

U3-M23A-XAD-R1 

U3-M23A-PF-R1 

U3-M23A-XAD-R2 

U3-M23A-PF-R2 

U3-M23A-XAD-R3 

U3-M23A-PF-R3 

U3-M23A-XAD-FB 

BH ACE/MeC12/TOL 

XAD 

FH ACE/MeC12/TOL 

FILTER 

BH ACE/MeC12/TOL 

XAD 

FH ACE/MeC12/TOL 

FILTER 

BH ACE/MeC12/TOL 

XAD 

FH ACE/MeC12/TOL 

FILTER 

BH/FH ACE/MeC12/TOL 

FILTER 

XAD 

Project 27803 

SmpinvgnmmS.rpt 

Project 2 of 466 
SECTION n 

Project 27803 Project 3 c 
Method Blank Method 0023A 

Matrix: MM5 QC Batch No.: 8120 Lab Sample: 0-MB001 

Sample Size: Sample Date Extracted: 22-Jun-06 Date Analyzed DB-5: 26-Jun-06 Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) DL

 a EMPC Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 0.879 IS 13C-2,3,7,8-TCDD 93.8 40-135 

1,2,3,7,8-PeCDD ND 0.802 13C-l,2,3,7,8-PeCDD 88.8 40-135 

1,2,3,4,7,8-HxCDD ND 1.69 13C-l,2,3,6,7,8-HxCDD 85.3 40-135 

1,2,3,6,7,8-HxCDD ND 1.43 13C-l,2,3,4,6,7,8-HpCDD 77.3 40-135 

1,2,3,7,8,9-HxCDD ND 1.55 13C-OCDD 59.8 40-135 

1,2,3,4,6,7,8-HpCDD ND 1.82 13C-2,3,7,8-TCDF 82.1 40-135 

OCDD ND 6.95 13C-l,2,3,7,8-PeCDF 77.9 40-135 

2,3,7,8-TCDF ND 1.08 13C-l,2,3,6,7,8-HxCDF 95.9 40-135 

1,2,3,7,8-PeCDF ND 1.45 13C-l,2,3,4,6,7,8-HpCDF 79.6 40-135 

2,3,4,7,8-PeCDF ND 1.33 13C-OCDF 23.2 40- 135 H 

1,2,3,4,7,8-HxCDF ND 0.587 PS 37Cl-2,3,7,8-TCDD 101 70 - 130 

1,2,3,6,7,8-HxCDF ND 0.469 13C-2,3,4,7,8-PeCDF 99.6 70 - 130 

2,3,4,6,7,8-HxCDF ND 0.552 13C-l,2,3,4,7,8-HxCDD 95.2 70-130 

1,2,3,7,8,9-HxCDF ND 0.707 13C-l,2,3,4,7,8-HxCDF 88.0 70 - 130 

l^Aej^HpCD F 0.386 13C-l,2,3,4,7,8,9-HpCDF 73.1 70-130 

i,2,3,4,7,8,9-HpCDF ND 0.846 AS 13C-l,2,3,7,8,9-HxCDF 83.3 40-135 

OCDF ND 7.46 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD ND 0.879 TEQ (Min-Max): 0.00386-2.87 

Total PeCDD ND 0.669 

Total HxCDD ND 1.55 a. Sample specific estimated detection limit. 

Total HpCDD ND 1.82 b. Estimated maximum possible concentration. ; 

Total TCDF ND 1.08 c. Method detection limit. 

Total PeCDF ND 1.39 d. Lower control limit- upper control limit. ; r 

Total HxCDF ND 0.566 e. TEQ based on (1989) International Toxic Equivalent Factors (1TEF). 

Total HpCDF 0.386 

Analyst: RA S Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 4 of 466 
OPR Results Method 0023A 

Matrix: MM5 QC Batch No.: 8120 Lab Sample: 0-OPR001 

Sample Size: Sample Date Extracted: 22-Jun-06 Date Analyzed DB-5: 26-Jun-06 Date Analyzed DB-225: NA 

Analyte Spike Cone. Cone. (ng/mL) OPR Limits Labeled Standard %R LCL-UCL 

2,3,7,8-TCDD 2.50 2.48 1.75-3.25 IS 13C-2,3,7,8-TCDD 84.5 40-135 

1,2,3,7,8-PeCDD 12.5 12.6 8.75 -16.25 13C-l,2,3,7,8-PeCDD 82.3 40-135 

1,2,3,4,7,8-HxCDD 12.8 8.75 - 16.25 13C-l,2,3,6,7,8-HxCDD 79.1 40 -135 

1,2,3,6,7,8-HxCDD 12.5 14.0 8.75-16.25 13C-1,2,3,4,6,7,8-HpCDD 77.4 40-135 

1,2,3,7,8,9-HxCDD 14.0 8.75-16.25 13C-OCDD 62.9 40-135 

1,2,3,4,6,7,8-HpCDD 12.5 12.0 8.75 - 16.25 13C-2,3,7,8-TCDF 78.1 40-135 

OCDD 25.0 17.5-32.5 13C-l,2,3,7,8-PeCDF 75.4 40-135 

2,3,7,8-TCDF 2.50 2.40 1.75-3.25 13C-l,2,3,6,7,8-HxCDF 83.5 40-135 

1,2,3,7,8-PeCDF 12.5 12.5 8.75-16.25 13C-l,2,3,4,6,7,8-HpCDF 78.7 40-135 

2,3,4,7,8-PeCDF 12.5 11.8 8.75-16.25 13C-OCDF 27.2 40-135 

1,2,3,4,7,8-HxCDF ;

.-s;.. - 12.5r/; 12.3 8.75-16.25 AS 13C-l,2,3,7,8,9-HxCDF 90.7 40- 135 

1,2,3,6,7,8-HxCDF 12.5 13.9 8.75-16.25 

2,3,4,6,7,8-HxCDF 12.5 13.6 8.75 - 16.25 

1,2,3,7,8,9-HxCDF 12.5 12.9 8.75-16.25 

1,2,3,4,6,7,8-HpCDF i2;§'.::

,;:. 8.75 - 16.25 

1,2,3,4,7,8,9-HpCDF 12.5 8.92 8.75- 16.25 

OCDF 25.0 24.7 17.5-32.5 

Analyst: RA S Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 5 of 466 
SamplelD: TJ3-M23A-XAD--R1 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 19-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 27803-001 

QC Batch No.: 8120 

Date Analyzed DB-5: 26-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Dates Analyzed DB-225: 27-Jun-06 

Analyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD N D • • • 3 64 IS 13C-2,3,7,8-TCDD 91.6 40-135 

1,2,3,7,8-PeCDD 17.0 J 13C-l,2,3,7,8-PeCDD 88.7 40- 135 

1,2,3,4,7,8-HxCDD 19.1 J 13C-l,2,3,6,7,8-HxCDD 89.2 40-135 

1,2,3,6,7,8-HxCDD 46.1 J 13C-l,2,3,4,6,7,8-HpCDD 96.7 40-135 

1,2,3,7,8,9-HxCDD 37.0 J 13C-OCDD 105 40-135 

1,2,3,4,6,7,8-HpCDD 190 13C-2,3,7,8-TCDF 88.3 40-135 

OCDD 236 13C-l,2,3,7,8-PeCDF 80.4 40-135 

2,3,7,8-TCDF 29.5 13C-l,2,3,6,7,8-HxCDF 97.0 40-135 

1,2,3,7,8-PcCDF 35.5 J 13C-l,2,3,4,6,7,8-HpCDF 92.7 40-135 

2,3,4,7,8-PeCDF 65.4 13C-OCDF 83.4 40-135 

1,2,3,4,7,8-HxCDF 36.0 J £S 37Cl-2,3,7,8-TCDD 86.1 70-130 

1,2,3,6,7,8-HxCDF 31.9 J,D 13C-2,3,4,7,8-PeCDF 91.4 70- 130 

2,3,4,6,7,8-HxCDF 43.8 13C-l,2,3,4,7,8-HxCDD 85.7 70 -130 

1,2,3,7,8,9-HxCDF 10.3 J 13C-l,2,3,4,7,8-HxCDF 85.9 70 - 130 

1,2,3,4,6,7,8-HpCDF 78.1 B 13C-l,2,3,4,7,8,9-HpCDF 77 9 70 - 130 

1,2,3,4,7,8,9-IIpCDF 8.10 J M 13C-I,2,3,7,8,9-HXCDF 95.2 40- 135 

OCDF 20.4 J 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD 1180 TEQ (Min-Max): 71.4 - 75.0 

Total PeCDD 869 

Total HxCDD 1470 a. Sample specific estimated detection limit. 

Total HpCDD Mi2::;:-;:;'';;2;f' b. Estimated maximum possible concentration: 

Total TCDF 1080 c. Method detection limit. 

Total PeCDF 800 D d. Lower control limit - upper control limit. 

Total HxCDF 391 395 D e. TEQ based on (1989) tnternational Toxic Equivalent Factors (ITEF). 

Total HpCDF 112 : B 

Analyst: RAS Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 6 of 466 
SamplelD: U3-M23A-PF-R1 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 19-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 27803-002 

QC Batch No.: 8120 

Date Analyzed DB-5: 26-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 1 18 IS 13C-2,3,7,8-TCDD 91.5 40 - 135 

1,2,3,7,8-PeCDD ND 1.38 13C-l,2,3,7,8-PeCDD 92.8 40-135 

1,2,3,4,7,8-HxCDD ND 2.76 13C-l,2,3,6,7,8-HxCDD 89.4 40 - 135 

1,2,3,6,7,8-HxCDD ND 2.33 13C-1,2,3,4,6,7,8-HpCDD 83.1 40-135 

1,2,3,7,8,9-HxCDD ND 2.53 I3C-OCDD 86.7 40-135 

1,2,3,4,6,7,8-HpCDD ND 2.52 13C-2,3,7,8-TCDF 85.3 40-135 

OCDD 10.8 J 13C-l,2,3,7,8-PeCDF 82.3 40-135 

2,3,7,8-TCDF ND 1.27 13C-l,2,3,6,7,8-HxCDF 97.8 40-135 

1,2,3,7,8-PcCDF ND 1.51 13C-l,2,3,4,6,7,8-HpCDF 80.9 40-135 

2,3,4,7,8-PeCDF ND 1.38 13C-OCDF 69.1 40-135 

1,2,3,4,7,8-1 IxCDF ND 0 923 £S 37Cl-2,3,7,8-TCDD 94.4 70- 130 

1,2,3,6,7,8-HxCDF ND 0.737 13C-2,3,4,7,8-PeCDF 93.9 70-130 

2,3,4,6,7,8-HxCDF ND 0.868 13C-l,2,3,4,7,8-HxCDD 90.7 70-130 

1,2,3,7,8,9-HxCDF ND 1.11 13C-l,2,3,4,7,8-HxCDF 87.4 70-130 

1,2,3,4,6,7,8-HpCDF ND 1.29 13C-l,2,3,4,7,8,9-HpCDF 79.0 70-130 

1,2,3,4,7,8,9-HpCDF ND 1.11 AS 13C-l,2,3,7,8,9-HxCDF 93.7 40-135 

OCDF ND 5.02 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD ND 1.18 TEQ (Min-Max): 0.0108-3.95 

Total PeCDD ND 1.38 

Total HxCDD ND 3.34 a. Sample specific estimated detection limit. 

Total HpCDD • i-77'.r- b. Estimated maximum possible concentration. 

Total TCDF ND 1.27 c. Method detection limit. 

Total PeCDF ND 1.44 d. Lower control limit-.s upper control limit.; 

Total HxCDF ND 0.890 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 1.49 

Analyst: RAS Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 7 of 466 
Sample ID: TJ3-M23A-XAD--R2 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 20-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 27803-003 

QC Batch No.: 8120 

Date Analyzed DB-5: 27-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Dates Analyzed DB-225: 27-Jun-06 

Analyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD 3.44 J IS 13C-2,3,7,8-TCDD 90.7 40-135 

1,2,3,7,8-PeCDD 17.6 J 13C-l,2,3,7,8-PeCDD 96.2 40 - 135 

1,2,3,4,7,8-HxCDD 16.8 J 13C-l,2,3,6,7,8-HxCDD 90.0 40- 135 

1,2,3,6,7,8-IIxCDD 34.7 J 13C-l,2,3,4,6,7,8-HpCDD 89.1 40-135 

1,2,3,7,8,9-HxCDD 27.1 J 13C-OCDD 88.8 40-135 

1,2,3,4,6,7,8-HpCDD 175 13C-2,3,7,8-TCDF 84.8 40-135 

OCDD 175 13C-l,2,3,7,8-PeCDF 91.8 40-135 

2,3,7,8-TCDF 32.8 13C-l,2,3,6,7,8-HxCDF 96.2 40-135 

1,2,3,7,8-PcCDF 41.2 J 13C-l,2,3,4,6,7,8-HpCDF 83.0 40 -135 

2,3,4,7,8-PeCDF 70.2 13C-OCDF 59.8 40- 135 

1,2,3,4,7,8-HxCDF 33.0 J PS 37Cl-2,3,7,8-TCDD 99.4 70-130 

1,2,3,6,7,8-HxCDF 31.7 J,D 13C-2,3,4,7,8-PeCDF 89.2 70-130 

2,3,4,6,7,8-HxCDF 41.8 13C-l,2,3,4,7,8-HxCDD 92.3 70-130 

1,2,3,7,8,9-HxCDF 11.6 J 13C-1,2,3,4,7,8-HxCDF 92.3 70 - 130 

1,2,3,4,6,7,8-HpCDF 66.8 13C-l,2,3,4,7,8,9-HpCDF 83.2 70-130 

1,2,3,4,7,8,9-HpCDF 5.21 J AS 13C-1,2,3,7,8,9-HxCDF 99.2 40-135 

OCDF 14.8 J 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD 1210 TEQ (Min-Max): 75.0 - 75.0 

Total PeCDD 848 

Total HxCDD 1330 a. Sample specific estimated detection limit. 

Total HpCDD 381 b. Estimated maximum possible concentration. 

Total TCDF 1350 c. Method detection limit. 

Total PeCDF 862 D d. Lower control limit - upper control limit: : 

Total HxCDF 390 D c. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ' 98.0 B 

Analyst: RAS Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 8 of 466 
Sample ID: U3^M23A-PF-R2 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 20-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 27803-004 

QC Batch No.: 8120 

Date Analyzed DB-5: 27-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 1.21 IS 13C-2,3,7,8-TCDD 95.2 40 -135 

1,2,3,7,8-PeCDD ND 3.26 13C-1,2,3,7,8-PeCDD 101 40-135 

1,2,3,4,7,8-HxCDD ND 2 63 13C-l,2,3,6,7,8-HxCDD 94.3 40-135 

1,2,3,6,7,8-HxCDD ND 2.23 13C-1,2,3,4,6,7,8-HpCDD 83.0 40-135 

1,2,3,7,8,9-HxCDD ND 2.41 13C-OCDD 88.2 40-135 

1,2,3,4,6,7,8-HpCDD ND 4.12 13C-2,3,7,8-TCDF 92.6 40-135 

OCDD ND 6.33 13C-l,2,3,7,8-PeCDF 88.9 40 - 135 

2,3,7,8-TCDF ND 0.951 13C-l,2,3,6,7,8-HxCDF 101 40- 135 

1,2,3,7,8-PeCDF ND 3.44 13C-l,2,3,4,6,7,8-HpCDF 79.5 40-135 

2,3,4,7,8-PeCDF ND 3.14 13C-OCDF 61.5 40-135 

1,2,3,4,7,8-HxCDF ND 0.684 ?S 37Cl-2,3,7,8-TCDD 97.5 70 - 130 

1,2,3,6,7,8-HxCDF ND 0.546 13C-2,3,4,7,8-PeCDF 99.4 70-130 

2,3,4,6,7,8-HxCDF ND 0.643 13C-l,2,3,4,7,8-HxCDD 95.0 70-130 

1,2,3,7,8,9-HxCDF ND 0.823 13C-1,2,3,4,7,8-HxCDF 88.7 70- 130 

1,2,3,4,6,7,8-HpCDF ND 0.705 13C-l,2,3,4,7,8,9-HpCDF 79 4 70- 130 

1,2,3,4,7,8,9-HpCDF ND 0.971 AS 13C-1,2,3,7,8,9-HxCDF 92.8 40-135 

OCDF ND 6.38 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD ND 1.21 TEQ (Min-Max): 0-5.74 

Total PeCDD ND 3.26 

Total HxCDD ND 2.41 a. Sample specific estimated detection limit. 

Total HpCDD ND 4 12 b. Estimated maximum possible concentration: :: 

Total TCDF ND 0.951 c. Method detection limit. 

Total PeCDF ND 3.28 d. Lower control limit - upper control limit. •»••: 

Total HxCDF ND 0.660 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 0.817 

Analyst: RAS Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 9 of 466 
Sample ID: U3-M23A-XAD—R3 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 21-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 27803-005 

QC Batch No.: 8120 

Date Analyzed DB-5: 27-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Dates Analyzed DB-225 : 27-Jun-06 

Analyte Cone. (pg/SampIe) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCLd

 Qualifiers 

2,3,7,8-TCDD ND 3.92 JS 13C-2,3,7,8-TCDD 88.3 40-135 

1,2,3,7,8-PeCDD 16.7 J 13C-1,2,3,7,8-PeCDD 94.0 40-135 

1,2,3,4,7,8-HxCDD 14.6 J 13C-l,2,3,6,7,8-HxCDD 89.7 40 - 135 

1,2,3,6,7,8-HxCDD 35.7 J 13C-l,2,3,4,6,7,8-HpCDD 95.2 40-135 

1,2,3,7,8,9-HxCDD 26.3 J 13C-OCDD 95.9 40-135 

1,2,3,4,6,7,8-HpCDD 156 13C-2,3,7,8-TCDF 86.6 40-135 

OCDD 141 13C-l,2,3,7,8-PeCDF 84.3 40-135 

2,3,7,8-TCDF 31.8 13C-i;2,3,6,7,8-HxCDF 95.9 40-135 

1,2,3,7,8-PeCDF 41.1 J 13C-l,2,3,4,6,7,8-HpCDF 90 8 40-135 

2,3,4,7,8-PeCDF 76.2 13C-OCDF 81.0 40-135 

1,2,3,4,7,8-HxCDF ^37.8:'7:'V J PS 37Cl-2,3,7,8-TCDD 98 2 70-130 

1,2,3,6,7,8-HxCDF 33.6 J,D 13C-2,3,4,7,8-PeCDF 97.8 70 - 130 

2,3,4,6,7,8-HxCDF 44.9 13C-l,2,3,4,7,8-HxCDD 92.9 70-130 

1,2,3,7,8,9-HxCDF 11.1 j 13C-1,2,3,4,7,8-HxCDF 90.7 70- 130 

1,2,3,4,6,7,8-HpCDF 70.7 B 13C-l,2,3,4,7,8,9-HpCDF 92.5 70-130 

1,2,3,4,7,8,9-HpCDF 7.15 J AS 13C-l,2,3,7,8,9-HxCDF 91.1 40-135 

OCDF 13.2 . J ' 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD 879 899 TEQ (Min-Max): 74.6 - 78.5 

Total PcCDD 686 

Total HxCDD 1110 a. Sample specific estimated detection limit. 

Total HpCDD 335 b. Estimated maximum possible concentration. 

Total TCDF 1310 c. Method detection limit. 

Total PeCDF 948 D d. Lower control limit- upper control limit:: 

Total HxCDF 410 D e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 102 B 

Analyst: RAS Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 1Q of 466 
SamplelD: U3-M23A-PF-R3 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 21-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 27803-006 

QC Batch No.: 8120 

Date Analyzed DB-5: 27-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Date Analyzed DB-225: NA 

Analyte Cone, (pg/Saraple) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 1.40 IS 13C-2,3,7,8-TCDD 88.4 40-135 

1,2,3,7,8-PeCDD ND 3.83 13C-1,2,3,7,8-PeCDD 93.9 40-135 

1,2,3,4,7,8-HxCDD ND 2.13 I3C-l,2,3,6,7,8-HxCDD , 92.5 40-135 

1,2,3,6,7,8-HxCDD ND 1.81 13C-1,2,3,4,6,7,8-HpCDD 95.6 40-135 

1,2,3,7,8,9-HxCDD ND 1.96 13C-OCDD 94.0 40-135 

1,2,3,4,6,7,8-HpCDD ND 2.53 13C-2,3,7,8-TCDF 89.7 40-135 

OCDD 10.1 J 13C-l,2,3,7,8-PeCDF 84.1 40-135 

2,3,7,8-TCDF ND 1.15 13C-l,2,3,6,7,8-HxCDF 99.3 40-135 

1,2,3,7,8-PeCDF ND 3.00 13C-1,2,3,4,6,7,8-HpCDF 97.3 40 -135 

2,3,4,7,8-PeCDF ND 2.74 13C-OCDF 85.9 40-135 

1,2,3,4,7,8-HxCDF ND 0.641 PS 37Cl-2,3,7,8-TCDD 100 70-130 

1,2,3,6,7,8-HxCDF ND 0.512 13C-2,3,4,7,8-PeCDF 104 70-130 

2,3,4,6,7,8-HxCDF 0 603 13C-l,2,3,4,7,8-HxCDD 94.3 70-130 

1,2,3,7,8,9-HxCDF ND 0.771 13C-l,2,3,4,7,8-HxCDF 90.4 70-130 

1,2,3,4,6,7,8-HpCDF ND 0.819 13C-l,2,3,4,7,8,9-HpCDF 91.8 70-130 

1,2,3,4,7,8,9-HpCDF ND 0.602 AS 13C-l,2,3,7,8,9-HxCDF 99.0 40-135 

OCDF ND 3.84 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD ND 1.40 TEQ (Min-Max): 0.0101 - 5.85 

Total PeCDD ND 3 83 

Total HxCDD 3.35 a. Sample specific estimated detection limit. 

Total HpCDD ND 2.53 b. Estimated maximum possible concenlration. 

Total TCDF ND 1.15 c. Method detection limit. 

Total PeCDF ND 2.86 d. Lower control limit - upper control limit. 

Total HxCDF ND 0.618 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 0.950 

Analyst: RA S Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 11 of 466 
SamplelD: U3-M23A-XAD—FB Method 0023A 

Client Data Sample Data Laboratory Data 

Name: ENSR 

Project: 10002-017 

Date Collected: 20-Jun-06 

Time Collected: 

Matrix: 

Sample Size: 

MM5 . 

Sample 

Lab Sample: 27803-007 

QC Batch No.: 8120 

Date Analyzed DB-5: 26-Jun-06 

Date Received: 22-Jun-06 

Date Extracted: 22-Jun-06 

Date Analyzed DB-225: NA 

Analyte Cone. (pg/SampIe) DL

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 0.845 JS 13C-2,3,7,8-TCDD 88.4 40-135 

1,2,3,7,8-PeCDD ND 0.844 13C-l,2,3,7,8-PeCDD 89.2 40-135 

1,2,3,4,7,8-HxCDD ND 1.38 13C-l,2,3,6,7,8-HxCDD 93.7 40 - 135 

1,2,3,6,7,8-HxCDD ND 1.16 13C-1,2,3,4,6,7,8-HpCDD 80.2 40- 135 

1,2,3,7,8,9-HxCDD ND 1.26 13C-OCDD 84.5 40-135 

1,2,3,4,6,7,8-HpCDD ND 1.42 13C-2,3,7,8-TCDF 85.9 40-135 

OCDD ND 4.29 13C-l,2,3,7,8-PeCDF 81.7 40-135 

2,3,7,8-TCDF ND 0.732 I3C-I,2,3,6,7,8-HXCDF 96.2 40-135 

1,2,3,7,8-PcCDF ND ; 13C-1,2,3,4,6,7,8-HpCDF 81.1 40-135 

2,3,4,7,8-PeCDF ND 1.05 13C-OCDF 59.9 40-135 

1,2,3,4,7,8-HxCDF ND 0.401 ES 37Cl-2,3,7,8-TCDD 95.3 70 - 130 

1,2,3,6,7,8-HxCDF ND 0.320 13C-2,3,4,7,8-PeCDF 96.5 70- 130 

2,3,4,6,7,8-HxCDF ND 0.377 13C-l,2,3,4,7,8-HxCDD 88.0 70 - 130 

1,2,3,7,8,9-HxCDF ND 0.483 13C-l,2,3,4,7,8-HxCDF 90.4 70 -130 

1,2,3,4,6,7,8-HpCDF ND 0.666 13C-l,2,3,4,7,8,9-FIpCDF 76.2 70-130 

1,2,3,4,7,8,9-HpCDF ND 0.918 AS 13C-l,2,3,7,8,9-HxCDF 90.6 40-135 

OCDF ND 3.70 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD ND 0.845 TEQ (Min-Max): 0-2.50 

Total PeCDD ND 0.844 

Total HxCDD ND 1.26 a. Sample specific estimated detection limit. 

Total HpCDD ND 1 42 b. Estimated maximum possible concentration. 

Total TCDF ND 0.732 c. Method detection limit. 

Total PeCDF ND 1.10 d. Lower control limit - upper control limit. 

Total HxCDF ND 0.387 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 0.772 

Analyst: Approved By: William J. Luksemburg 27-Jun-2006 15:11 

Project 27803 Project 12 of 466 
PROJECT NARRATIVE 

Maxxam Analytics (Burlington ON) 

Maxxam Job #: A662175 

Client: ENSR International 

Client Project: 10002-017-820 ONYX 

I. SAMPLE RECEIPT/ANALYSIS 

a) Sample Listing 

Maxxam 

TD 

Client 

Sample ID 

Date 

Sampled 

Date 

Received 

Date 

Prepped 

Date 

Run 

Metals in Air (Back Half) via EPA Method 29 

M73146 M29-RBBH 2006/06/21 2006/06/22 

M73147 M29-U3-R1BH 2006/06/19 2006/06/22 

M73147Dup M29-U3-R1BH 2006/06/19 2006/06/22 

M73148 M29-U3-R2BH 2006/06/20 2006/06/22 

M73149 M29-U3-R3BH 2006/06/21 2006/06/22 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

2006/06/29 

Metals in Air (Front Half) via EPA Method 29 

M73142 M29-RBFH 2006/06721 2006/06/22 2006/06/28 2006/06/29 

M73143 M29-U3-R1FH 2006/06/19 2006/06/22 2006/06/28 2006/06/29 

M73143 Dup M29-U3-R1 FH 2006/06/19 2006/06/22 2006/06/28 2006/06/29 

M73144 M29-U3-R2FH 2006/06/20 2006/06/22 2006/06/28 2006/06/29 

M73145 M29-U3-R3FH 2006/06/21 2006/06/22 2006/06/28 2006/06/29 

Particulates in Air (Acetone Rinse) via EPA Method 5 

M73142 M29-RBFH 2006/06/21 2006/06/22 

M73143 M29-U3-R1FH 2006/06/19 2006/06/22 

M73144 M29-U3-R2FH 2006/06/20 2006/06/22 

M73145 M29-U3-R3FH 2006/06/21 2006/06/22 

2006/06/27 2006/06/28 

2006/06/27 2006/06/28 

2006/06/27 2006/06/28 

2006/06/27 2006/06/28 

Particulates in Air (Filter) via EPA Method 5 ( 

M73142 M29-RBFH 2006/06/21 2006/06/22 

M73143 M29-U3-R1FH 2006/06/19 2006/06/22 

M73144 M29-U3-R2FH 2006/06/20 2006/06/22 

M73145 M29-U3-R3FH 2006/06/21 2006/06/22 

2006/06/26 2006/06/26 

2006/06/26 2006/06/26 

2006/06/26 2006/06/26 

2006/06/26 2006/06/26 

Run Date is defined as tie date of injection of the last calibration standard (12 hours or less) prior to 

the samples analyzed within that run sequence. Therefore the time of calibration injection that defines 

the run date is always within 12 hours of the time of sample injection. 

b) Shipping Problems: none encountered 

c) Documentation Problems: none encountered 

H. SAMPLE PREP: 

No problems encountered 
ffl. SAMPLE ANALYSIS: 

See also comments within the appropriate Certificate of Analysis 

a) Hold Times: all within recommended hold times 

b) Instrument Calibration: all within control limits 

c) Quality Control: All applicable QC meets control criteria, except where otherwise noted. 

I certify that this data package is in compliance with the terms and conditions ofthe contract, both 

technically and for other than the conditions detailed above. 

In addition, I certify, that to the best of my knowledge and belief, the data as reported are true and 

accurate. Release ofthe data contained in this data package has been authorized by the cognizant 

laboratory official or his/her designee, as verified by this signature. 

JUL 0 S 2006 

Mary-Anne Johnson, Project Manager Date 

r 
2. DATA SUMMARY 

Certificate of Analysis -

Sample analyte result 

Method blank result 

LCS Reisults with % Recoveries 

Matrix Spike data with % Recoveries 

Matrix Spike Duplicate data with % Recoveries 

Surrogate recoveries 
Client 

Lab number Issued 

Supplier P/N Lot# 

Filter Dimensions 

Date of Dessication (yyyymmdd hh:mm) 

fe 

Filter pre weight average 

Weight of filter before (g) #1 

Initial Date weighed (yyyymrndd hh:mm) 

II Weight of filter before (g) #2 

1 

i 

Final Dale weighed (yyyymmdd hh:mm) 

O O O s- s-fr % Acceptability 

P g P 

Weigh! of filter difference 

Initial Temperature (14.4 to 25.6 C) 

Initial Humidity (%) 

0.0000 

Initial Balance Zero 

0.3000 

Initial 0.3000 grams 

(O 

o Final Temp (14.4 to 25.6 <3 deg change) 

Final Humidity (%) (<5 % change) 

k> Change in Temperature (C) 

o Change in Humidity (%) 0.0000 

Final Balance Zero 

0.3000 

Final 0.3000 grams. 
IS/I a xx a m ly riven by service and Science 

www.ma xxa inanaly tics.co m 

Your Project #: 10002-017-820 

Site: ONYX 

Attention: Jeff Gorman 

ENSR International 

6601 Kirkville Rd 

East Syracuse, NY 

USA 13057 

Report Date: 2006/09/11 

CERTIFICATE OF ANALYSIS 

MAXXAM JOB #: A662175 

Received: 2006/06/22,13:50 

Sample Matrix: Filter 

# Samples Received: 4 

Date Date Method 

Analyses Quantity Extracted Analyzed Laboratory Method Reference 

Metals in Air (Front Half) by ICP/MS <S 4 2006/06/28 2006/06/29 SOP ING 108/109 EPA SW846-6020 

Particulates in Air (Acetone Rinse) (M5) (P 4 2006/06/27 2006/06/28 SOP ING 505 EPA CFR PTM 5 

Particulates in Air (Filter) <5 4 2006/06/26 2006/06/26 SOP ING 505 EPA CFR PTM 5 

Final Volume of Acetone Probe Rinse $ 4 2006/09/11 2006/09/11 

Sample Matrix: Impinger Solution 

# Samples Received: 4 

Date Date Method 

Analyses Quantity Extracted Analyzed Laboratory Method Reference 

Metals in Air (Back Half) by ICP/MS ® 4 2006/06/29 2006/06/29 SOP ING 108/109 EPA SW846-3010A.60 

(1) This test was perfonned by Maxxam Analytics Burlington 

MAXXAM ANALYTICS INC. 

MARY-ANNE JOHNSON, BA, B.Sc. 

Project Manager 

MAJ/maj 

encl. 

Jl 

Pagel of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax: 905-817-5777 
Driven by service and Science 

www.maxxiamaiialytlcs.com 

Your Project #: 10002-017-820 

Site: ONYX 

Attention: Jeff Gorman 

ENSR International 

6601 Kirkville Rd 

East Syracuse, NY . 

USA 13057 

Report Date: 2006/09/11 

CERTIFICATE OF ANALYSIS 

-2-

Validated by: 

Total cover pages: 2 

Page 2 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax: 905-817-5777 

Anolyti 
Driven by service and Science 

wwwjnaxxamaoalytics.com 

ENSR International 

Client Project*: 10002-017-820 

Project name: ONYX 

Sampler Initials: 

RESULTS OF ANALYSES OF FILTER 

Maxxam ID M73142 M73143 M73144 M73145 

Sampling Date 2006/06/21 2006/06/19 2006/06/20 2006/06/21 

Units M29-RB FH M29-U3-R1 

FH 

M29-U3-R2 

FH 

M29-U3-R3 

FH 

RDL 3C Batch MDL 

Particulate Weight in Acetone Rinse mg ND 4.0 2.8 1.7 0.5 1001275 0.5 

Volume ml 98 57 87 56 1 1049870 1 

Particulate Weight on Filter mg 0.65 2.20 1.65 1.55 0.30 1001265 0.30 

ND = Not detected 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

Page 3 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax: 905-817-5777 

f Analytics I r 

Maxxam Job #: A662175 

Report Date: 2006/09/11 
* .fl*. no ly tl cs Inc 

Maxxam Job #: A662175 

Report Date: 2006/09/11 

Driven by service and Science 

www.maxxaoianalytlcs.com 

ENSR International 

Client Project #: 10002-017-820 

Project name: ONYX 

Sampler Initials: 

ELEMENTS BY ICP/MS (FILTER) 

Maxxam ID M73142 M73143 M73143 M73144 M73145 

Sampling Date 2006/06/21 2006/06/19 2006/06/19 2006/06/20 2006/06/21 

Units M29-RB FH M29-U3-R1 

FH 

M29-U3-R1 

FH Lab-Dup 

M29-U3-R2 

FH 

M29-U3-R3 

FH 

RDL QC Batch MDL 

[Total Arsenic (As) ug 0.61 5.81 6.01 4.27 5.62 0.40 1001008 0.40 

[Total Beryllium (Be) ND ND ND ND ND 0.10 1001008 0.10 

Total Chromium (Cr) ug 0.79 9.64 11.9(1) 3.98 11.1 0.30 1001008 0.30 

ND = Not detected 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

(1 ) Please refer to General Comments page for specific clarification. 

Page 4 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toil free:800-563-6266 Fax:905-817-5777 
fSA £ l 

f Analytics Inc 

Driven by service and Science 

Maxxam Job #: A662175 

Report Date: 2006/09/11 

www.maxxamahalylics.com 

ENSR International 

Client Project #: 10002-017-820 

Project name: ONYX 

Sampler Initials: 

ELEMENTS BY ICP/MS (IMPINGER SOLUTION) 

Maxxam ID M73146 M73147 M73147 M73148 M73149 

Samplinq Date 2006/06/21 2006/06/19 2006/06/19 2006/06/20 2006/06/21 

Jnits M29-RB BH M29-U3-R1 

BH 

M29-U3-R1 

BH Lab-Duo 

M29-U3-R2 

BH 

M29-U3-R3 

BH 

RDL 3C Batch MDL 

Total Arsenic (As) ug ND 0.33 0.33 ND 0.21 0.20 1001758 0.20 

Total Beryllium (Be) ug ND ND ND 0.087 ND 0.050 1001758 0.050 

Total Chromium (Cr) ug ND 1.06 1.02 0.66 0.84 0.15 1001758 0.15 

ND = Not detected 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

Page 5 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tei: 905-817-5700 Toll free:800-563-6266 Fax:905-817-5777 
IVS a 

' Analytics Inc 

Driven by seri*ice and Science 

Maxxam Job #:A662175 

Report Date: 2006/09/11 

www.maxxamaxialytlcs.com 

ENSR International 

Client Project*: 10002-017-820 

Project name: ONYX 

Sampler Initials: 

Test Summary 

Maxxam ID 

Sample ID 

Matrix 

M73142 

M29-RB FH 

Filter 

Collected 

Shipped 

Received 

2006/06/21 

2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Metals in Air (Front Half) bv ICP/MS ICP1/MS 1001008 2006/06/28 2006/06/29 N R 

Particulates in Air (Acetone Rinse) (M5) BAL 1001275 2006/06/27 2006/06/28 IMR 

Particulates in Air (Filter) BAL 1001265 2006/06/26 2006/06/26 VP2 

Final Volume of Acetone Probe Rinse 1049870 2006/09/11 2006/09/11 FMO 

Maxxam ID 

Sample ID 

Matrix 

M73143 

M29-U3-R1 FH 

Filter 

Collected 

Shipped 

Received 

2006/06/19 

2006/06/22 

Test Description instrumentation Batch Prepared Analyzed Analyst 

Metals in Air (Front Half) bv ICP/MS ICP1/MS 1001008 2006/06/28 2006/06/29 N R 

Particulates in Air (Acetone Rinse) (M5) BAL 1001275 2006/06/27 2006/06/28 . IMR 

Particulates in Air (Filter) BAL 1001265 2006/06/26 2006/06/26 VP2 

Final Volume of Acetone Probe Rinse 1049870 2006/09/11 2006/09/11 FMO 

Maxxam ID 

Sample ID 

Matrix 

M73143Dup 

M29-U3-R1 FH 

Filter 

Collected 

Shipped 

Received 

2006/06/19 

2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Metals in Air (Front Half) by ICP/MS ICP1/MS 1001008 2006/06/28 2006/06/29 N_R I 

Maxxam ID 

Sample ID 

Matrix 

M73144 

M29-U3-R2 FH 

Filter 

Collected 

Shipped 

Received 

2006/06/20 

2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Metals in Air (Front Half) bv ICP/MS ICP1/MS 1001008 2006/06/28 2006/06/29 N R 

Particulates in Air (Acetone Rinse) (M5) BAL 1001275 2006/06/27 2006/06/28 IMR 

Particulates in Air (Filter) BAL 1001265 2006/06/26 2006/06/26 VP2 

Final Volume of Acetone Probe Rinse 1049870 2006/09/11 2006/09/11 FMO 

Maxxam ID M73145 Collected 2006/06/21 

Sample ID M29-U3-R3 FH Shipped 

Matrix Filter Received 2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

Metals in Air (Front Half) by ICP/MS ICP1/MS 1001008 2006/06/28 2006/06/29 N R 

Particulates in Air (Acetone Rinse) (M5) BAL 1001275 2006/06/27 2006/06/28 IMR 

Particulates in Air (Filter) BAL 1001265 2006/06/26 2006/06/26 VP2 

Final Volume of Acetone Probe Rinse 1049870 2006/09/11 2006/09/11 FMO 

Page 6 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax:905-817-5777 
IVI a m 

f Analytics Inc 

Maxxam Job #:A662175 

Report Date: 2006/09/11 

Driven by service and Science 

www.maxxamaiudytics.coin 

ENSR International 

Client Project #: 10002-017-820 

Project name: ONYX 

Sampler Initials: 

Test Summary 

Maxxam ID M73146 

SamplelD M29-RB BH 

Matrix Impinger Solution 

Collected 2006/06/21 

Shipped 

Received 2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

IMetals in Air (Back Half) by ICP/MS 1CP1/MS 1001758 2006/06/29 2006/06/29 N_R 

Maxxam ID M73147 

Sample ID M29-U3-R1 BH 

Matrix Impinger Solution 

Collected 2006/06/19 

Shipped 

Received 2006/06/22 

Test Description Instrumentation Batch Prepared 

IMetals in Air (Back Half) by ICP/MS ICP1/MS 1001758 2006/06/29 

Analyzed Analyst 

2006/06/29 N_R 

Maxxam ID M73147Dup 

Sample ID M29-U3-R1 BH 

Matrix Impinger Solution 

Collected 2006/06/19 

Shipped 

Received 2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

IMetals in Air (Back Half) by ICP/MS ICP1/MS 1001758 2006/06/29 2006/06/29 N_R 

Maxxam ID M73148 

SamplelD M29-U3-R2BH 

Matrix Impinger Solution 

Collected 2006/06/20 

Shipped 

Received 2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

IMetals in Air (Back Half) by ICP/MS ICP1/MS 1001758 2006/06/29 2006/06/29 N R 

Maxxam ID M73149 

SamplelD M29-U3-R3BH 

Matrix Impinger Solution 

Collected 2006/06/21 

Shipped 

Received 2006/06/22 

Test Description Instrumentation Batch Prepared Analyzed Analyst 

IMetals in Air (Back Half) by ICP/MS ICP1/MS 1001758 2006/06/29 2006/06/29 N R 

Page 7 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax: 905-817-5777 
IVI a ^ a m 

Analytics Inc 

Maxxam Job #:A662175 

Report Date: 2006/09/11 

Driven by service and Science 

www.max3tamaitaIytIcs.coin. 

ENSR International 

Client Project*: 10002-017-820 

Project name: ONYX 

Sampler Initials: 

GENERAL COMMENTS 

Results relate only to the items tested. 

Page 8 of 11 

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1^ Analytics Inc imw.maxxamanaivtks.com 

Driven by service and Science 

ENSH International 

Attention: Jeff Gorman 

Client Project #: 10002-017-820 

P.O. #: 

Project name: ONYX 

Quality Assurance Report 

Maxxam Job Number GA662175 

QA/QC 

Batch 

Num Init QC Type Parameter 

Date 

Analyzed 

yyyy/mm/dd Value %Recovery Units QC Limits: 

1001008 N_R MATRIX SPIKE 

(M73143) Total Arsenic (As) 2006/06/29 49.5, RDL=0.40 99 ug 70- 130: 

MATRIX SPIKE 

DUP(M73143) Total Arsenic (As) 2006/06/29 49.5, RDL=0.40 99 ug 70- 130 

MATRIX SPIKE 

(M73143) Total Beryllium (Be) 2006/06/29 48.0, RDL=0.10 96 ug 70- 130 

MATRIX SPIKE 

DUP(M73143) Total Beryllium (Be) 2006/06/29 47.0, RDL=0.10 94 ug 70- 130i 

MATRIX SPIKE 

(M73143) Total Chromium (Cr) 2006/06/29 48.5, RDL=0.30 97 ug 70- 130 

MATRIX SPIKE 

DUP(M73143) Total Chromium (Cr) 2006/06/29 47.5, RDL=0.30 95 ug 70- 130 

Spiked Blank Total Arsenic (As) 2006/06/29 48.5, RDL=0.40 97 ug 85- 115 

Spiked Blank DUP Total Arsenic (As) 2006/06/29 49.0, RDL=0.40 98 ug 85- 115 • 

Spiked Blank Total Beryllium (Be) 2006/06/29 59.5, RDL=0.10 119(1) ug 85- 115 

Spiked Blank DUP Total Beryllium (Be) 2006/06/29 58.5, RDL=0.10 117(1) ug 85- 115 

Spiked Blank Total Chromium (Cr) 2006/06/29 53.0, RDL=0.30 106 ug 85- 115 

Spiked Blank DUP Total Chromium (Cr) 2006/06/29 53.0, RDL=0.30 106 ug 85- 1153 

Method Blank Total Arsenic (As) 2006/06/29 ND, RDL=0.40 ug 

Method Blank DUP Total Arsenic (As) 2006/06/29 ND, RDL=0.40 ug 

Method Blank Total Beryllium (Be) 2006/06/29 ND, RDL=0.10 ug 

Method Blank DUP Total Beryllium (Be) 2006/06/29 ND, RDL=0.10 ug 

Total Chromium (Cr) 2006/06/29 ND, RDL=0.30 ug 

Method Blank Total Chromium (Cr) 2006/06/29 ND, RDL=0.30 ug 

RPD Total Arsenic (As) 2006/06/29 3.4 % 20 

Total Beryllium (Be) 2006/06/29 NC / o 20 

Total Chromium (Cr) 2006/06/29 21.2(1) % 20 

1001275 IMR Method Blank Particulate Weight in Acetone Rinse 2006/06/28 ND, RDL=0.5 mg 

1001758 N_R MATRIX SPIKE 

(M73147) Total Arsenic (As) 2006/06/29 48.5, RDL=0.20 97 ug 70 130 

MATRIX SPIKE 

DUP(M73147) Total Arsenic (As) 2006/06/29 50.0, RDL=0.20 100 ug 70 •130' 

MATRIX SPIKE 

(M73147) Total Beryllium (Be) 2006/06/29 57.5, RDL=0.050 115 ug 70 -130: 

MATRIX SPIKE 

DUP (M73147) Total Beryllium (Be) 2006/06/29 58.5, RDL=0.050 117 ug 70 • 130 

MATRIX SPIKE 

(M73147) Total Chromium (Cr) 2006/06/29 50.0, RDL=0.15 100 ug 70 -130 

MATRIX SPIKE 

DUP(M73147) Total Chromium (Cr) 2006/06/29 51.0, RDL=0.15 102 ug 70 -130 

Spiked Blank Total Arsenic (As) 2006/06/29 50.5, RDL=0.20 101 ug 85 -115^ 

Spiked Blank DUP Total Arsenic (As) 2006/06/29 50.0, RDL=0.20 100 ug 85 -115 

Spiked Blank Total Beryllium (Be) 2006/06/29 58.5, RDL=0.050 117 ug 85 -115; 

Spiked Blank DUP Total Beryllium (Be) 2006/06/29 58.0, RDL=0.050 116 ug 85 -115: 

Spiked Blank Total Chromium (Cr) 2006/06/29 52.0, RDL=0.15 104 ug 85 - 115 

Spiked Blank DUP Total Chromium (Cr) 2006/06/29 52.0, RDL=0.15 104 ug 85 -115 

Method Blank Total Arsenic (As) 2006/06/29 ND, RDL=O.20 ug 

Method Blank DUP Total Arsenic (As) 2006/06/29 ND, RDL= =0.20 ug 

Method Blank Total Beryllium (Be) 2006/06/29 ND, RDL=0.050 ug 

Method Blank DUP Total Beryllium (Be) 2006/06/29 ND, RDL=0.050 ug 

Method Blank Total Chromium (Cr) 2006/06/29 ND, RDL=0.15 ug 

Method Blank DUP Total Chromium (Cr) 2006/06/29 ND, RDL=0.15 ug 

RPD Total Arsenic (As) 2006/06/29 NC % 20 

Total Beryllium (Be) 2006/06/29 NC % 20 

Total Chromium (Cr) 2006/06/29 4.2 % 20 

ND = Not detected 

i 

Page 9 of 11 

6740 Campobello Road, Mississauga, Ontario Canada L5N 2L8 Tel: 905-817-5700 Toll free:800-563-6266 Fax:905-817-5777 
Driven fry service and Science 

bNSH International—~~~ 

Attention: Jeff Gorman 

Client Project #: 10002-017-820 

P.O.f: 

Project name: ONYX 

Quality Assurance Report (Continued) 

Maxxam Job Number GA662175 

NC = Non-calculable 

RPD = Relative Percent Difference 

SPIKE = Fortified sample 

1) Please refer to General Comments page for specific clarification. 

X x a m 

• ^/Analytics tne 

Page 10 of 11 

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CTI )^)^<E 1 "in Driven by service anti Science 

f Analytic s inc wvrw.maxxaman.alytics.com 

Validation Signature Page 

Maxxam Job #: A662175 

The analytical data and all QC contained in this report were reviewed and validated by the following individual(s). 

FRANK MO, B.Sc, Inorganic Lab. Manager 

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of 

ISO/IEC 17025:2005(E), signing the reports. SCC and CAEAL have approved this reporting process and electronic report format. 

Page 11 of 11 

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