P. 1


# OAR Box 1672 Prepped by Charmelle Mathews

o 

### Document

Number:
Docket Number: 

# A-98-1 3

Printed 9/30/200811:01:00AM

Sheet 22 of 132P. 2

• a , 

# AS?-13

TO :

FROM : DATE : MEMORANDU M
Project Fil e Organi c Liquid s Distributio n NESHA P ES D Project

No
. 96/0 5 Bern d Hanek e an d Greg LaFla

m Pacifi c Environmenta

l Services , IriC

? Decembe r 10,199 9 SUBJECT : Sit

e Visi t to Union Carbide' s Texa s Cit y Marine Termina

l I . Purpos e Th e purpos e of

thi s sit e visi t wa s to tou r th e facilit y i n a n effor t to collec t informatio n relate d to ai

r emission s fromth e operations
. Thi s wor k i s in suppor

t ofth e developmen

t of nationa l emissio n standard s fo

r hazardou s ai

r pollutant s (NESHAP

) fo r th e organi c liquid s distributio n (non-gasoline ) sourc e category . II . Locatio n an

d Dat e Unio n Carbid

e Corporation-Texa s Cit

y Marine Termina

l 280 0 Loo p 19 7 Sout h Texa s City , Texa s 7759 0 Octobe r 22 , 199 8 (8:55-11:3 0 a.m. ) III . Participant

s Union Carbid

e Corporatio n Stacy Dotson - Advanced Distributio n Enginee r Benoit Lamarche - HS E Coordinato r Dan aNeely - Senio

r Environmenta

l Enginee r Joh n Soic e - Ai

r Issue s Manage

r U.S
. Environmenta

l Protectio n Agenc

y (EPA) Steve Shed

d - OAQPS/ESD/WCPG , Research Triangl e Park , NC Texa s Natura

l Resourc e Conservation Commission (TNRCC ) Sun e Nanta h - Environmenta

l Investigator , Ai

r Progra mP. 3

Sit e Visi t Memo-Unio n Carbid

e Decembe r 10,199 9 - Draf

t Repor t Pag e 2 Pacifi c Environmenta l Services
. Inc
. (PES ) Bern d Hanek

e - Research Triangl e Park , N C Gre g LaFla

m- Research Triangl e Park , N C IV . Pre-Tou r Discussio n Unio n Carbide Corporatio n Upo n enterin g th e Unio n Carbid e Texa s Cit

y Mai n Plant , th e EPA/PE S projec t tea mwa s shown asafet

y vide o fo r th e Texa s Cit

y Marine Terminal
. Followin g thi s video , Unio n Carbide representative s drov e th e EPA/PE S projec t tea mto th e Marine Terminal
. A t thi s facilit y Unio n Carbide representative s an

d projec t tea mmember s assembled in th e conferenc e room . EP A Introductio n Afte r th e participant s introduce d themselves , Steve Shedd , EPA , bega n th e meetin g b y discussin g th e backgroun d ofth e EPA' s regulatio n o f hazardou s ai

r pollutant (HAP ) emissions
. Prio r t o th e Clea

n Air Ac t Amendment s of

199 0 (CAAA) , regulation s wer e base d o n individua

l HA P and alimite d numbe

r of regulation s wer

e completed
. Th

e CAA A include d aHA

P lis t an d prescribe d tha

t rule s b e develope d fo

r categorie s of

source s (industria

l types)
. The stringenc y of th e Organi c Liquid s Distributio n (non-Gasoline ) rul e (fo r existin g sources ) wil l b e base d o n "floor " level s o f

contro l representin g th e contro l achieved b y th e averag e ofth e to p 1 2 percent of facilitie s in thi s category . Th e standard s ar

e slate d t o b e propose d i

n 1999 , wit

h promulgatio n o f th e final rul e in Novembe

r 2000
. Mr
. Shedd mentione d tha

t th e EP A project tea mha d selecte d th e Unio n Carbide Corporation' s Texa s Cit

y Marine Termina

l based upon th e locatio n ofth e facilit y and becaus e it containe d dataof

interes t t o th e developmen

t ofth e Organi c Liquid s Distributio n NESHAP
. H e als o describe d th e EPA' s procedure s fo r handlin g information tha

t th e compan

y consider s to b e confidentia

l busines s informatio n (CBI)
. Th e compan y will have a

n opportunit

y to revie w th e draf t sit e visi t repor t prepare d by PES , an

d to commen

t on it s accuracy an

d identif y an y CBI
. Th e report , wit

h an y CB I removed , wil l b e mad e apar t ofth e publi c recor

d fo r thi s rulemaking
. The representative s of

Unio n Carbid

e wer e asked if an y ofth e information presente d wa s confidentia

l an d n o CB I wa s identified durin g o r afte r th e meeting
. Facilit y Descriptio n Unio n Carbide' s Texa s Cit y Marine Termina

l i s located o

n th e Housto n Shi

p Channel nea r Texa s City
. The facilit

y i s als o locate d clos e t

o Union Carbide' s Texa s Cit y Main Plant , but th e compan

y doe s no t conside r th e tw o facilitie s to b e collocated
. Th e termina l operate s o n a2

4 hr/day , 7 day/week , 5 2 wk/y r schedule
. The termina

l serve s a s adistributio n cente r fo r al l mainland Unio n Carbide facilities , an d it s main custome

r i s th e Texa s Cit

y Main Plant
.P. 4

Sit e Visi t Memo-Unio n Carbid e Decembe r

10,199 9 - Draf

t Repor t Pag e 3 Furthermore , i t

i s Unio n Carbide' s onl y dee p wate r terminal
. Th e termina l consist s o f dee p wate r tanke r docks , barg e docks , an d so-calle d "overland " rack s tha t loa d bot h tan k

truck s an d railcars
. Chemical s ar e receive d vi apipelin e o r ar e unloade d frommarin e an d overlan d transpor t vessels
. Som e chemical s ar e store d at th e termina l unti l the y ar e pumpe d t o th e Texa s Cit y Mai n Plan t o r loade d int o anothe r

transpor t vessel
. Othe r

chemical s ar e transloaded ; tha t is , materia l i s unloade d fromon e transpor t vessel , suc h a s aship , int o atan k an d the n loade d int o anothe r transpor t vessel , suc h a s atan k

truc k o r railcar
. A s chemical s ar e loaded , th e vapor s ar e eithe r vente d t o th e atmosphere , route d t o aflare , o r collecte d i n avapo r

retur n lin e tha t

pipe s th e vapor s bac k

t o th e storag e tank
. Chemical s tha t hav e vapo r

pressure s greate r

tha n o r equa l t o 0.5 1 psi aat

8 8 degree s F ar e route d t o aflare
. Th e termina l ha s approximatel y 12 0 storag e tank s i n service , o f whic h 2 2 ar e use d t o stor e "surveye d liquids " (define d i n th e EPA' s 199 8 industry surve y a s havin g 1,000 ppm w o f HA P o r mor e an d avapo r pressur e o f

0. 1 psi ao r

more)
. Th e breakdow n i s abou t 2 0 interna l floatin g roof

, 4 externa l floatin g roof

, an d th e remainde r

fixed-roof

tanks
. Tw o o f

thes e fixed-roof

tank s hav e vapo r balanc e capabilit y for

us e durin g barg e loading
. MAC T Coverag e Unio n Carbide' s termina l i s subjec t t o th e emission s estimatio n an d recordkeepin g requirement s ofth e Marin e Vesse l Loadin g MAC T rul e (4 0 CF RPart 63 , subpart

Y) , althoug h th e HA P emission s fromth e termina l ar e belo w th e leve l at whic h additiona l emissio n control s ar e required
. N o HA P ar e unloade d frommarin e vessel s at th e terminal
. A n ethano l denaturin g facility at th e termina l wil l b e covere d b y th e Miscellaneou s Organi c NESHA P (MON)
. Accordin g t o th e surve y respons e submitte d b y Unio n Carbide , tan k truc k an d railca r loadin g rack s a s wel l a s variou s storag e tank s ar e expecte d t o b e affecte d b y th e future Organi c Liquid s Distributio n NESHAP
. Equipmen t

Leak s Th e EPA/PE S projec t

tea mrequeste d informatio n regardin g th e equipmen t leak emissio n factor s tha t

th e compan y use s t o calculat e fugitiv e emissions
. Unio n Carbid e representative s informe d th e projec t

tea mtha t

i t wa s usin g modifie d SOCM I emissio n factor s (withou t ethylene) , issue d b y th e TNRCC
. Contro l Equipmen t Th e facility ha s thre e flare system s i n operation , tw o o f whic h ar e associate d wit h OL D operations
. A wate r

scrubbe r i s als o i n operatio n a

t th e ethano l denaturin g facilit y (th e denaturant s ar e HAP)
. 

# 3P. 5

Sit e Visi t Memo-Unio n Carbide Decembe r 10,199 9 - Draf

t Repor t Pag e 4 Th e EPA/PE S projec t tea mrequeste d information regardin g th e cost s o f operatin g th e flare s a t th e terminal , but

only wide rangin g estimate s an d no t actua l figure s wer

e available
. A s actua l figure s wer

e no t available , no figure s ar

e presente d i

n thi s memo . V . Tou r o f

th e Facilit

y Loadin g Rack s Th e first sto p on adrivin g tou

r ofth e facilit

y wer e tan k truck/railca

r loadin g rack

nos . 5 , 6 , an d 7
. Viny l acetat

e (vapo r pressur e ~ 1.7 8 psi aa

t 70°F ) wa s observe d bein g loade d into a railca r a t rac k no . 6
. Loadin g emission s fromrack nos . 6 an d 7 ar e controlle d b y aflare , whil e rack no . 5 i s uncontrolled
. Low volatilit y liquid s (v.p
. < 0.5 1 psi aa t 8 8 °F ) ar e loade d only a

t rack no . 5 , i n respons e to emissio n requirement s in th e TNRC C regulations
. The grou p spen t considerabl e tim

e a t thes e rack s s o tha

t th e project

tea mcoul d observ e and as k question s abou

t th e loadin g equipmen

t an d procedures
. Th

e quantit y o f liqui d bein g loade d int o tan k truck s i s monitore d in tw o ways . Th e primar y mean s i s atruc k

scal e situate d a

t each truc k loadin g position
. A s abackup , th e drive r als o use s agaug e ro d inserte d into th e tank
. For railcars , onl

y amagneti c gaug e ro d i s used
. Liqui d i s loade d throug h a

n opening in th e top ofth e tan k using ato p loadin g vapo r recover y adapter
. A

n OP W "donut " typ e sea

l i s lowered int

o th e opening an

d inflate d to provid e atight sea l around th e opening
. The

n adrop tub e (t

o provide submerged loadin g ofth e liquid ) an d aprob e fo

r overfill protectio n ar

e attached through thi s adapter
. Earl y version s ofth e donut sea l ha d to b e replace d ever

y 2 months , but

mor e recen t model s hav e bee

n mor e durable
. Vapor s ar e returne d to th e contro l devic e through athir d connecto

r on th e to p ofth e tank , which include s apressur

e gauge . Loading i s performed unde r avacuu mof abou t 1 0 inche s of wate r (to prevent

vapor leakag e a s loading i s takin g place)
. Flar e The grou p next observe d th e vapo

r contro l devic e used to contro l emission s fromrack nos . 6 and 7 , a

n enclose d flare manufactured b y Joh n Zin k Company
. Thi s flar

e als o control s marin e (ship an

d barge ) loadings
. Natura

l ga s i s used a s asupplementa l fuel ; however , there i s no monitorin g o

r recordin g ofth e combustio n temperature . Th e syste mha s a n automati c shutdow n featur

e in cas e of

excessiv e temperature . Du e t o th e high frequency of

loadings , th e flar e i s alway s i

n operation
.



## *4P J „

Sit e Visi t Memo-Unio n Carbid

e Decembe r 10,199 9 - Draf

t Repor t Pag e 5 VI . Followup Discussio n Followin g th e facilit

y tour , th e grou

p reconvened in th e terminal' s conferenc e room . Th e EPA/PE S projec t

tea mrequeste d tha

t th e compan

y provide the

mwit h acopy o f

tw o documents : 1 ) Union Carbide' s 199 5 flexible permit fromthe TNRCC (include d a s Attachmen t 1) , an d 2 ) th e company' s manua

l describin g th e operatio n ofth e loading rac k loadin g and emissio n contro l systems . The compan

y personnel agreed t

o suppl y thes e documents
. N o othe r significan t discussio n occurred , an

d th e sit e visi t wa s conclude d a

t 11:3 0 a.m .



# S~P. 7

Barr y R
. McBee

, Chairman R.B."Ralph " Mirquez, Commissioner f=fc^B> ] UNCONTROLLE D COP

Y John M
. Baker, Commissioner Da n Pearson , Executive Director

TEXA S NATURA L RESOURC E CONSERVATIO N COMMISSIO N

Protecting Texas by Reducing and Preventing Pollution Ma y 6 , 199 6

Ms
. Dan aM
. Neel

y Senior Environmenta

l Enginee r UNIO N CARBIDE CORPORATIO N P.O
. Bo x 47 1 Texa s City , Texa s 77592-047 1 Re : Permi t

Amendmen

t Permi t No
. 328 4 Texa s Cit y Marin e Termina

l Texa s City , Galveston Count y Accoun t I D No
. GB-0077- H Dea r Ms
. Neely : Thi s i s i n respons e t

o you r letter datedSeptembe

r 5 , 199 5 an

dpermi t application , FormPI-1 , concernin g the propose damendmen t t o Permi t No
. 3284
. We understan dtha t yo u propos e t o consolidat e marin e termina l Permi t Nos
. 2197 , 2238 , 2346 , 2788 , 4938 , 5439 , 5729 , and2206 8 int o aflexibl e permit
. W e als o understan dtha

t you wil l implemen

t th e 2 8 RC T fugitiv e monitoring program , monito r pum p an dcompresso

r seal s a t 50 0 ppm v eac h quarter , andprovid e a n overal l volatil e organi c compoundreductio n o f 55 6 ton s pe r

year . Thi s will acknowledge tha

t you r applicatio n fo

r th e above-reference damendmen t i s technicall y complete a s o

f Decembe r 8 , 1995
. Pursuant

t o 3 0 TA C Sectio n 116.116(a) (Regulatio n VI) , Permi t No
. 328 4 i s hereby amendedan dconverte dint

o aflexibl e permit
. Enclose dare th e revise dSpecia

l Condition s an

d a n "Emissio n Source s - Emissio n Cap s andIndividual Limitations " table
. Thi s amendmen

t wil l be automaticall

y voi dupo n th e occurrenc e o f an y o f the following , as pe

r §116.115(b)(1) : 1
. Failur e t

o begin constructio n o

f th e change s authorize dby thi s amendmen t withi n 1 8 month s fro

mthe dat e o f thi s authorization
. 2
. Discontinuance o

f constructio n o

f th e change s authorize db y thi s amendmen t fo r aperio d o f 1 8 consecutiv e month s or more .

P.O
. Bo x 13087 • Austin , Texa s 78711-308 7 • 512/239-100 0 prir.:c\i .n i recvi'tr d ;MCe r -jjin ^ sov-basct

i in x 

# 7P. 8

Ms
. Dan aM
. Neel

y Pase 

# ? ' UNCONTROLLE D COP Y Ma y 6 , 199 6 Permi t No
. 328 4 3
. No t completin g th e change s authorize d b y thi s amendmen t withi n areasonabl e time
. W e hav e enclose d tw o operation s certificatio n form s (For mPI-3 A an d For mPI-3B)
. Sectio n 116.110(b ) require s you to certif y tha t operation s addresse d i n thi s permi t are i n conformanc e wit

h representation s i n th e permit application
. Pleas e file thes e certification s wit h both th e Texa s Natural Resourc e Conservatio n Commissio n (TNRCC ) New Sourc e Revie w Divisio n in Austi n and th e appropriate TNRC C Regiona l Office i n atimely manner . You r cooperatio n i n thi s matter i s appreciated
. I

f you hav e furthe

r questions , pleas e contac t Mr
. Pau l E
. Mix , P.E. , o f ou r Office of

Ai r Quality , New Sourc e Review Divisio n a t (512 ) 239-1564
. Sincerely ,
)a n Pearso n Executiv e Directo r Texa s Natura

l Resourc e Conservatio n Commissio n DP/PM/j s Enclosure s cc : Ms
. Karen Atkinson , Ai r Progra mManager , Housto n Mr
. Ro n Schultz , Director , Pollutio n Contro l Division , Galvesto n Count y Healt h District , L aMarqu e



## €P. 9 

# TEXAS NATUR E RESOURC

E CONSERVO N COMMISSIO

N AI R QUALIT

Y - FLEXIBL E PERMI T A PERMIT

IS HEREBY

ISSUED

TO 

## UNIO N CARBID

E CORPORATIO N ^ AUTHOR/ZING

THE.CONTINUED

OPERATION

OF <0£^ " 

## Texa s Cit y Marin e Termina l ^ v 

## o^J ^ LOCATED

AT \ # 

## Texa s City , Galvesto n County , Texa s LATITUDE

29 ° 22 ' 00 " LONGITUDE 094 ° 57 ! 00 " 1.Ti e facilitie s covere d b y thi s permi t shal l b e constructe d an d operate d a s specifie d i n th e applicatio n fo rth e permit
. Al l representation s regardin g constructio n plan s an d operatio n procedure s containe d i n th e permi t applicatio n shal l b e condition s upo n whic h th e permi t i s issued , variation s fro m thes e representation s shal l b e unlawfu l unles s th e permi t holde rfirs t make s applicatio n t o th e Executiv e Directo rof th e Texa s Natura l Resourc e Conservatio n Commissio n (TNRC C o rCommission ) to amen d thi s permi t i n tha t regar d an d suc h amendment i s approved
. I t shal l b e unlawfu l fo rany perso n t o var y fro m suc h representatio n o r flexibl e permi t provisio n i f th e chang e wil l caus e a chang e i n th e metho d o f contro l o f emissions , th e characte rof th e emissions , o rwil l resul t i n a significan t increas e i n emissions , unless applicatio n i s mad e to th e TNRC C Executiv

e Directo rto amen d th e flexibl e permi t i n tha t regar d an d suc h amendmen t i s approve d b y th e Executive Director
. (3 0 TA C 116.721 ) 2
. Voidin g o f Permit A flexible permi t o rflexibl e permi t amendmen t unde rthi s subchapte ri s automaticall y voi d i f th e holde rfail s t o complet e constructio n a s specifie d i n th e flexibl e permi t Upo n request , th e Executiv e Directo rma

y gran t a on e tim e 12-mont h extensio n o f th e dat e to complet e construction
. Thi s sectio n doe s no t aopl y t o physica l o roperationa l change s allowe d withou t an amendmen t unde r§116.72 1 o f thi s titl e (relatin g t o Amendment s an d Alterations)
. (3 0 TAC 1 ^.715(c)(1) ) 3
. Constructio n Progress
. Th e star t of construction , constructio n interruption s exceedin g 4 5 days , an d completio n o f constructio n shal l b e reporte d t o th e appropriat e regiona l offic e o f th e TNRC C no t late r tha n 1 5 workin g day s afte r occurrenc e ofth e event . (3 0 TA C 116.715(c)(2) ) 4
. Start-u p Notification
. Th e appropriat e Ai rProgra m Regiona l Offic e o f th e TNRC C an d an y loca l progra m havin g jurisdictio n shal l b e notifie d prio rto th e commencemen t o

f operation s o f th e facilitie s authorize d b y th e permi t i n suc h a manne rtha t a representativ

e o f th e TNRC

C ma y b e present
. Phased construction , whic h ma y involv e a serie s o f facilitie s commencin g operation s a t differen t times , shal l provid e separate notificatio n fo rth e commencemen t o f operation s fo reac h facility
. (3 0 TAC 116.715(c)(3) ) 5
. Samplin g Requirements
. I f samplin g of stack s o rprocess vent

s i s required , th e flexibl e permi t holde rshal l contac t th e TNRC C Offic e o f Ai rQuality prio rt o samplin g t o obtai n th e prope rdata form s an d procedures
. Al l samplin g an d testin g procedure s must b e approve d b y th e Executive Directo ran d coordinate d wit h th e appropriat e Ai rProgra m Regiona l Office of th e TNRCC
. Th e flexibl e permi t holde ri s als o responsibl e fo rprovidin g samplin g facilitie s an d conductin g th e samplin g operation s o rcontractin g wit h a n independen t samplin g consultant
. (3 0 TA C 116.71 5 (c)(4) ) 6
. Equivalenc y o f Methods
. I t shal l b e th e responsibilit y o f th e flexibl e permi t holde rt o demonstrat e o rotherwis e justif y th e equivalenc

y o f emissio n contro l methods , samplin g o rothe remissio n testin g methods , an d monitorin g method s propose d a s alternative s t o method s indicate d i n th e condition s o f th e flexibl e permit
. Alternative method s shal l b e applie d fo ri n writin g an d mus t b e reviewe d an d approve d b y th e Executiv

e Directo rprio rto thei ruse i n fulfillin g an y requirements o

f th e permit
. (3 0 TA

C 116.715(c)(5) ) 7
. Recordkeeping
. A cop y o f th e flexibl e permi t alon g wit h informatio n an d data sufficien t t o demonstrat e continuou s complianc e wit h th e emissio n cap s an d individua l emissio n limitation s containe d i n th e flexibl e permi t shal l b e maintaine d i n a fil e at th e plan t sit e an d mad e availabl e at th e request o f personne l fror r th e TNRC C o ran y ai rpollutio n contro l progra m havin g jurisdiction
. Fo rfacilitie s that normall y operat e unattended , thi s infonnatio n shal l b e maintaine d a t th e neares t staffe d locatio n withi n Texas specifie d b y th e permi t holde ri n th e permi t application
. Thi s informatio n ma y include , bu t i s no

t limite d to , emissio n ca p an c individua l emissio n limitatio n calculation s base d o n a 12-month rollin g basi s an d productio n record s an d operatin g hours
. Additiona l recordkeepin g requirement : ma y b e specifie d i n specia l condition s attache d t o th e flexibl e permit
. Informatio n i n th e fil e shal l b e retaine d fo ra t least tw o year

s followin g th e dat e that the informatio n o rdata i s obtained
. (3 0 TA C 116.71 5 (c)(6) ) 6
. Maximu m Allowabl e Emissio n Rates
. A flexibl e permi t cover s onl y thos e source s o f emission s an d thos e ai rcontaminant s liste d i n th e tabl e entitle s "Emissio n Sources - Emission s Cap s an d Individua l Emissio n Limitations " attache d t o th e flexibl e permit
. Flexibl e permitte d source s ar e limite d t o th e ernissio r limit s an d othe rcondition s specifie d i n th e tabl e attache d t o th e flexibl e permi t (3 0 TA C 116.71 5 (c)(7) ) 9
. Emissio n Ca p Readjustmen t I f a schedul e t o instal l additiona l control s i s include d i n th e flexibl e permi t an d a facilit y subjec t to suc h a schedul e i s take i ou t of service , th e emissio n ca p containe d i n th e flexibl e permi t wil l b e readjuste d fo rth e perio d th e uni t i s ou t of servic e t o a leve l as i f n o schedul e ha d bee i established
. Unless a specia l conditio n specifie s th e metho d o f readjustmen t o

f th e emissio n cap , a permi t alteratio n shal l b e obtained
. (3 0 TA C 116.71 5 (c)(8 ) 10
. Maintenanc e o f Emissio n Control
. Th e facilitie s covered b y th e flexibl e permi t shal l no t b e operate d unles s al l ai rpollutio n emissio n captur e an d abateme n equipmen t i s maintaine d i n goo d workin g orde ran d operatin g properl y durin g norma l facility operations
. Notificatio n fo rupsets an d maintenance shal l b e mad i i n accordance wit h §101. 6 an d §101. 7 o f thi s titl e (relatin g to Notificatio n Requirement s fo rMajo rUpse

t an d Notificatio n Requirements fo rMaintenance)
. (3 0 TA C 116.71 5 (c)(9) ) 11
. Complianc e wit h Rules
. Acceptanc e of a flexibl e permi t b

y a permi t applican t constitute s a n acknowledgemen t an d agreemen t that th e holde rwil l comp l wit h al l Rules , Regulations , an d Order s of th e Commissio n issue d i n conformit y wit h th e Texa s Clea n Ai rAct an d th e condition s preceden t t o th e grantin g of t h permit
. I f mor

e tha n on e stat e o rfedera l rul e o rregulatio n o rflexibl e permi t conditio n ar e applicable , the n th e mos t stringen t limi t o rconditio n shal l gover n a n b e th e standar

d b y whic h compliance shal l b e demonstrated
. Acceptance include s consen t to th e entrance o f Commissio n employee s an d agent s int o t h permitte d premise s a

t reasonabl e time s t o investigate condition s relatin g to th e emissio n o rconcentratio n of ai rcontaminants , includin g complianc e wit h th e flexib l permit
. (3 0 TA

C 116.71 5 (c)(10) ) 12
. Thi s permi t ma

y b e appeale d pursuan t t o Sectio n 263.3 6 o f th e Genera l Rules o

f th e TNRC C an d Sectio n 382.03 2 o f th e TCAA
. Failur

e t o take suc h appe ; constitute s acceptance b

y th e applican t of al l term s of th e permit
. (Tex
. Gov' t Cod e Ann
. § 2001 , e t sea. ) 13
. Thi s permi t ma

y no t b e transferred , assigne d o rconveye d b y th e holde rexcep t a

s provide d b

y rule
. (3 0 TA

C 116.110(c) ) 14
. Thi s permi t expire s 1 0 year s fro m dat e o f issuance unles s renewe d a s provide d i n Sectio n 382.05 5 o f th e TCA A unles s a shorte rtim e perio d i s specifi e i n th e specia l condition s o f thi s permit
. 15
. Ther e ma y b e additiona l specia l condition s attache d t o a flexibl e permi t upo n issuanc e o ramendmen t ofth e permit
. Suc h condition s i n a flexibl e per n ma y b e mor e restrictiv e tha n th e requirement s of Titl e 3

0 o f th e Texas Administrativ e Code
. (3 0 TA C 116.715(d) ) 16
. Emission s fro m thi s facilit y mus t no t caus e o rcontribut e t o a conditio n of 'ai rpollution ' as define d i n Sectio n 382.003(3 ) o f th e Texa s Clea n Ai rAc t (TCA
. o rviolat e Sectio n 382.085 ofth e TCAA
. I f th e Executiv e Directo rdetermine s that suc h a conditio n o rviolatio n occursxth e holde rshal l implemen t additio n abatemen t measure s a

s necessar

y t o contro l o rpreven t th e conditio n o rviolation
. PERMI T 323 4 DAT E 5-6-9 6 Texa s Natura l Resou r n
, cto r servatio n Commissio nP.1 0

SPECIA L CONDITION S y. Permi t No
. 328 4 «*tf^^^ HVOSSIO N CAP S AN

D INDIVIDUA

L EMISSIO N LIMITATION S 1
. Thi s permi t

cover s onl

y thos e source s of

emission s liste d in th e attache d tabl e entitle d "Emissio n Source s - Emissio n Cap s and Individua l Emissio n Limitations, " an d thos e source s are limited t

o th e emissio n cap s an d othe r condition s specified i n that attache d table
. OPERATIN G CONDITION S AN D PARAMETER S 2
. Flare s shal l b e designe d an d operate d i n accordanc e wit h Titl e 4 0 Code of

Federa l Regulation s Part

60.1 8 (4 0 CF

R60.18 ) includin g specification s o f minimu mheatin g valu e o f the wast e gas , maximu

mti p velocity , an

d pilo t flam e monitoring
. I f

necessar y t o insure adequat e combustion , sufficien

t fue l gas shal l b e adde d t o mak e th e gase s combustible
. A n infrared monitor

i s considered equivalen

t t o athermocoupl e fo

r flam e monitorin g purposes . 3
. Barge , ship , an

d loadin g control s ar

e t o b e i n plac e n o late

r tha n Novembe r

15 , 1996
. 4
. Al l supplementa

l fue l ga s t o the flares shal l contai n n o mor e tha n 2 0 ppmv o r

1.2 5 grain s of total sulfur/10 0 scf

. 5
. Chemical s handled a

t th e facilit y represented in th e permi t applicatio n mus t

meet on e o f the followin g criteria : A
. Th e chemica

l mus t appea r on th e "Approve d Chemical s List " o r B
. Th e propose d chemica l off-sit e concentration , predicte d b y Scree n 2 Mode l fo r al l sources , shal l b e les s tha n tw o time s th e Texa s Natura l Resourc e Conservatio n Commission (TNRCC ) Effects Screenin g Leve l (ESL ) a t th e neares t

off-sit e receptor . ESL s shal l b e thos e publishe d o n th e TNRC C ES L lis t date d Apri l 10 , 1995
. If th e ES L lis t o f Apri l 10 , 199 5 doe s no t

includ e th e compoun d t o b e added , th e ES L shal l b e obtaine d i n writin g fro mthe Toxicolog y and Ris k Assessment

Sectio n of

th e TNRCC
. C : Thi s flexibl e permi t doe s no t

preclud e authorization s availabl e under 3 0 TA C Sectio n 116.211
. Dat aan d supporting documentation demonstratin g tha t th e propose d chemical meet s on e o f th e abov e requirement s shall b e kep t o n fil e an

d b e made availabl e upo n reques t t o representative s o

f the TNRC C an

d loca l program s having jurisdiction
. Th e handlin g o f an y othe r chemical s shal l b e prohibite d withou t prio r approva l o f th e TNRC C Executiv e Director
.


## 10p . 1 1

SPECIA L CONDITION S Permi t No
. 328 4
. ...„AUTDn U F_ D COP V Pag e 2 

# UNCOKTOOUfl )

6
. N o singl e chemica

l ma y be stored i n more tha

n 1 0 percent

o f th e terminal' s storag e tank s at an y specifi c time
. Th

e onl y exception s to thi s ar

e ethano l and ethylen e glycol , which ma y eac h b e store d in u

p t o 2 0 percen t

o f th e terminal' s storag e tanks
. 7
. Carbo n canister s shall b e used in conjunctio n wit h Ethy l an

d Buty l Acrylat

e Tanks , Tan

k Nos
. L- 2 and L-7 , fo

r odo r control
. Carbo n canister s shal l b e change d onc e pe r year . 8
. When in acetic aci

d service , Storage Tan

k No
. 375 3 shall ven

t t o acausti c scrubber

havin g acausti c concentration greate r tha n l A weigh t percen t o r mor e i n order to assur e 9 9 percent neutralizatio n o

f th e acetic acid
. Th e causti c solutio n shal l b e replace d afte r th e low concentratio n alar

mi s triggere d a

t 2 percent , but

befor e th e causti c concentratio n reache s V i weight percent . I n order t o demonstrat

e complianc e wit

h th e contro l efficiency o

f th e aceti c aci d scrubber , th e conductivit

y of the scrubbing liqui d shal l b e recorde d prio r to eac h vessel containin g aceti c aci d bein g loaded int o Tan k No
. 3753
. Tan

k No
. 375 3 ma

y no t accep t aceti c aci d i f th e percen

t causti c in the scrubbin g liqui d i s les s tha n x h weigh

t percent . Thes e record s shal l b e mad

e availabl e t

o representative s o

f th e TNRC C upo n request . 9
. Vapor s associate

d wit h th e loadin g o f buty l acrylat

e an d ethy l acrylate shal l b e capture d by avapo r balanc e system . Whe

n used , th e vacuu

mloadin g systemfo

r an y chemica l shal l hav e avacuu

mof a t leas t 1. 5 inc h water

colum n and the ven

t shal l b e route d t o acontro l devic e achievin g aminimu mo f 9 8 percent

remova l efficiency,
. Loadin g systemvacuum shal l b e measure d onc e during loadin g a t alocatio n upstrea

mof th e detonatio n arrestor . Measurement s shal l b e logge d an d record s o

f thes e log s shal l b e maintaine d in accordanc e wit h Specia l Conditio n No
. 12
. STORAG E AN D LOADING O

F VOLATIL

E ORGANIC COMPOUND S (VOC ) 10
. A
. Fo r

an y tan k equippe d wit h afloating roof

, the floating roof

shall b e equippe d wit

h on e o f th e followin g closur e device s betwee

n th e wall o

f th e storag e vessel an

d th e edg e o

f th e interna l floating roof

: (1 ) aliquid-mounte d seal , (2 ) tw o continuou s seal s mounte d on e abov e th e other , or

(3 ) amechanica

l sho e seal
. Installatio n o f th e equivalent contro l require s prio r

review and approva

l b y th e TNRC C Executiv e Director
.

/ /P.1 2

SPECIA L CONDITION S Permi t No
. 328 4 Pag e 3 

# UNCONTROLLE D COP Y

B
. An open-top tan

k containin g afloating roo f (externa l floatin g roo f

tank ) whic h use s double sea l o r secondar y sea l technolog

y shall b e a

n approve d contro l alternativ e to a n interna l floating roo f

tan k provide d the primar

y sea l consist s of

eithe r a . mechanica

l sho e sea l or aliquid-mounte d sea

l an d the secondar

y sea l i s rim-mounted
. A weathershiel d i s no t

approvabl e a s asecondar

y sea l unles s specificall y reviewe d an d determine d t o b e vapor-tight
. C
. Fo r any tan k equippe d wit

h afloating roof

, the holder

of thi s permi t

shal l follo w 4 0 CF R60.113b , Testin g and Procedures , to verif y sea l integrity
. Additionally , th e permi t holde r shal l follo w 4 0 CF

R60.115b , Reportin g an d Recordkeepin g Requirements , t

o provide record s o

f th e date s seal s were inspected , sea l integrity , and correctiv e action s taken
. D
. Th e floatin g roo f

desig n shal l incorporat

e sufficien

t flotatio n to confor

mto th e requirement s o

f AP I Cod e 650 , o r

an equivalen

t degre e of

flotation , excep t

tha t a n interna l floatin g cove r nee d no t b e designe d t

o mee t rainfal l suppor

t requirement s an

d th e material s o

f constructio n ma

y b e steel or

othe r materials
. E
. Uninsulate d tan

k exterio r surface s exposed t

o th e su n shal l b e white o r aluminum
. F
. Operatio n without

visibl e liqui d leak s o r spill s shal l b e maintaine d at al l loading/unloadin g facilitie s regardles s o f vapor pressure . Thi s doe s no t apply t o momentar y dripping associate d wit

h th e initia

l connectio n o r

disconnectio n o

f fittings
. Sustaine d dripping fromfitting s durin g loading/unloadin g operation s i s no t permitted
. An y liqui d spil l tha

t occur s durin g loading/unloadin g activitie s shal l b e reporte d pursuan t t o Section s 101. 6 or

101. 7 o f th e TNRC C Genera

l Rule s an d shal l b e cleane d u p immediatel

y to minimiz e ai r

emissions
. PIPING
. VALVES
. FLANGES
. PUMPS
. AN D COMPRESSOR S I N VO C SERVIC E - INTENSIV E DIRECTE

D MAINTENANC E 11
. Excep t

as ma y b e provide d fo

r i n th e specia

l condition s of

thi s permit , th e followin g requirement s appl

y to th e above-reference d equipment
. A
. Thes e condition s shal

l no t appl y (1 ) wher e the VO C hav e a

n aggregate partia l pressure o r vapor pressure o

f les s tha n 0.04 4 psi aa

t 68° F o r (2 ) operatin g pressur e i s a t leas t 5 kilopascal s (0.72 5 psi ) belo w ambien t pressure . Equipment

exclude d fromthi s conditio n shal l b e identifie d i n alis t to b e mad

e availabl e upo n request .



## / ?P.1 3

SPECIAL CONDITION S Permi t No
. 328 4 ««^ w 

## pag = 4 UNCONTROLLE D COP Y

B
. Constructio n of

new an d reworked piping , valves , pum p systems , and compresso r system s shal l confor

mt o applicable ANSI , API , ASME , o r equivalen t codes
. C
. Ne w an d reworke d undergroun d proces s pipeline s shal l contai n no burie d valve s suc h tha t fugitiv e emissio n monitorin g i s rendere d impractical
. D
. T o the exten

t tha t goo d engineerin

g practic e wil l permit , ne

w an d reworke d valve s an d pipin g connection s shal l b e s o located t o b e reasonably accessibl e fo r leak-checkin g durin g plan t

operation
. Non-accessibl e valves , a s defined b y Regulatio n V , shal l b e identifie d i n alis t

t o b e mad

e availabl e upo n request . E
. Ne w an

d reworke d piping connection s shal l b e welde d o r flanged
. Screwe d connection s are permissibl e onl y o n pipin g smaller

tha n two-inc h diameter
. N o late r tha n th e next schedule d quarterl

y monitorin g afte

r initia l installatio n or

replacement , al l ne w o r reworke d connection s shall b e gas-teste d o r hydraulically-teste d at

n o les s tha n norma l operatin g pressur

e an d adjustment s mad

e a s necessar

y t o obtai n leak-fre e performance
. Flange s shal l b e inspected by visual , audible , and/o r olfactor y mean s a

t leas t weekl y b y operatin g personnel walk-through
. Eac h open-ende d valv e or lin e shall b e equippe d wit

h acap , blin d flange, plug , o r a secon d valve
. Except

during sampling , maintenanc e work , an d whe n connectin g hoses , th e second valv e shal l b e closed
. F
. Accessibl e valve s shal l b e monitored b y leak-checkin g fo

r fugitiv e emission s a

t leas t quarterl y usin g a

n approve d ga s analyze

r wit h adirecte d maintenanc e program . Sealless/leakles s valve s (including , but no t limite d to , welde d bonne t bellow s an d diaphragmvalves ) and relie f valve s equippe d wit

h arupture dis c upstrea

mo r ventin g t o acontro l devic e are no

t required t o b e monitored
. For

valve s equippe d wit

h ruptur e discs , apressure gaug e shall b e installe d betwee n th e relie f valv e an d rupture dis c to monitor dis c integrity
. All leaking disc s shal l b e replace d a t the earlies t

opportunit

y bu t no later tha n th e nex t proces s shutdown
. An approve d ga s analyze r shal l confor

mt o requirement s liste d i n 4 0 CF R60.485(a)-(b)
. A directe d maintenanc e progra mshal l consis t

of the repai r

an d maintenanc e o

f component s assiste d simultaneousl y by th e us e o

f a n approve d ga s analyze

r suc h tha t aminimu mconcentratio n o

f leaking VO C i s obtaine d fo r eac h componen

t bein g maintained
. Replace

d component

s shal l b e re-monitore d within 1 5 day s o f bein g place d back int o VO C service
. 

# / ?P.1 4

SPECIA L CONDITION

S l IMOHMTDA I | r n PAD V 

### Permi t No
. 328 4 UNCONTROLLE D COP Y Pag e 5
G
. Excep t

a s may b e provide dfo

r i n th e specia l condition s o f

thi s permit , al l pum p an d compresso r

seal s shal l b e monitore dwith a n approve dga s analyze r a t leas t quarterl y o r b e equippe dwith ashaf

t sealin g syste mtha t

prevent s o r

detect s emission s o f

VO C fro mth e seal
. Seal system s designe dan d operate dt o preven t emission s o r

seal s equippe dwit h a n automati c sea l failur e detectio n an d alar msyste mnee dno t b e monitored
. Thes e sea l system s ma y includ e (bu t

ar e no t limite dto ) dua l pum p seal s wit h barrie r

fluidat highe r pressur e tha n proces s pressure , seal s degassin g t o ven t contro l system s kep t

i n goo dworkin g order , o r

seal s equippe dwith an automati c sea l failur e detectio n an dalarmsystem . Submerge dpump s o r sealles s pump s (including , bu t no t limite dto , diaphragm , canned , o r magneti c drive n pumps ) ma y b e use dt o satisf y th e requirement s o f

thi s conditio n an dnee dno t

b e monitored
. H
. Damage do r

leakin g valve s o r

flanges foun

dto b e emittin g VO C i n exces s o f 50 0 part s pe r millio n b y volum e (ppmv ) o r foun db y visua l inspectio n t o b e leakin g (e.g. , drippin g liquids ) shall b e tagge dan dreplace do r repaired
. Damage do r

leakin g pum p an dcompresso r

seal s foun dto b e emittin g VO C i n exces s o f 50 0 ppm v o r

foun d by visua l inspectio n t o b e leakin g (e.g. , drippin g liquids ) shal l b e tagge dan d replace d o r repaired
. I
. Every reasonabl e effor

t shal l b e mad e t o repai r

aleakin g component , a s specifie di n thi s paragraph , withi n 1 5 day s afte r th e lea k i s found
. I f

th e repai r o f acomponen t woul drequir e auni t

shutdown , th e repai r

ma y b e delaye dunti l th e nex t

schedule d shutdown
. Al l leakin g component s whic h canno t b e repaire dunti l aschedule d shutdow n shal l b e identifie dfo r suc h repai r

b y tagging
. Th e TNRC C Executiv e Director , at

hi s discretion , ma

y require earl y uni t

shutdow n o r

othe r appropriat e actio n base do n th e numbe r

an dseverit

y o f tagge dleak s awaitin g shutdown
. J
. Pum p an d compresso r

seal s shal l b e monitore da t 50 0 ppm v eac h quarter . Record s shall b e kep t

o f pum p andcompresso r

seal inspections , findings , an dcorrectiv e actio n take n i n accordanc e with paragrap h K o f thi s condition
. K
. Th e result s o f

th e require dfugitive monitorin g andmaintenanc e progra mshal l b e mad e availabl e t o th e TNRC C Executiv e Directo r o r hi s designate drepresentativ e upo n request . Record s shal l indicate appropriat e dates , tes t methods , instrumen t

readings , repai r results , an d correctiv e action s take n for al l components . Record s o f flange inspection s ar e no t

require dunles s alea

k i s detected
. L
. Fugitiv e emissio n monitorin g require db y TNRC C Regulatio n V ma y b e use di n lie u o f Item s F throug h I o f

thi s condition
. 

# HP.1 5



### SPECIA L CONDITION

S . ^ **~, Permi tNo . 328 4 UNCONTROLLE D COP Y Pag e 6 Complianc e wit

h th e requirement s o

f thi s conditio n doe s no t

assur e complianc e wit

h requirement s of

a n applicabl e Ne

w Sourc e Performanc e Standard s o r a n applicabl e Nationa l Emissio n Standar d fo r Hazardou s Ai r

Pollutant s and doe s no t constitute approval o f

alternativ e standard s fo

r thes e regulations
. M
. Th e fugitiv e emission s monitorin g program(2 8 RC T wit h additiona

l monitorin g of pump s an d compresso

r seal s a t 500 ppmv ) wil l b e initiate d no mor e tha n 3 0 day s afte

r permi t issuance
. RECORDKEEPIN G 12
. All record s require d b y thes e condition s shal l b e kep t a t th e facilit y an d maintaine d fo

r a minimu mo

f tw o year s an

d b e mad e availabl e to representative s o f the TNRC C and loca

l program s havin g jurisdictio n upon request . Permi t recordkeepin g requirement s wil l b e initiate d withi n 6 0 day s o

f permit issuance
. Th e record s fo r eac h calenda

r mont h wil l b e complet e an d availabl e fo

r inspectio n b y the en d o

f th e following calenda

r month
. 13
. Th e VOC , nitroge n oxide , an d carbo n monoxide emission s used to calculate an emissio n ca p shal l b e calculated monthl

y fo r eac h pollutan t i n accordanc e wit

h the emissio n ca

p basi s table , date d November

29 , 1995 , i n th e confidentia l sectio n o

f th e permi t

applicatio n i n orde r to provid e th e accumulated hourl y and total annua l emissio n calculation s fo r compariso n wit

h th e establishe

d emission caps . Th e monthl y calculatio n shal l b e performe d usin g actua

l operatin g an

d contro l datafo

r th e month , an

d shal l b e consisten t

wit h th e calculatio n methodolog y use d i n th e development o f th e permi t

application
. Emissio n calculation s wil

l b e base d o n th e monthl y averag e temperature s obtaine d fromth e Galvesto n Weather Burea u for 199 3 an d 1994 , a s follows : Januar y Februar y Marc h Apri l 55.9 F

57.9 F 63.3 F 68.6 F Ma

y Jun e Jul y Augus t 76.2 F

82.4 F 85.2 F 84.9 F Septembe

r October November Decembe r 81.2 F 73.4 F 65.OF 60
. I F 14
. Emission s fo

r tank s an d loading operation s shal l b e calculate d using : (1 ) AP-42 , Fourt h Edition , Compilatio n o

f Ai r Pollutio n Emissio n Factors ; Chapte r 12 , Storag e o f

Organi c Liquids ; and Chapter

4 , Transportatio n an

d Marketin g o

f Petroleu mLiquids ; an d (2 ) th e TNRC C publication s title d "Technica l Guidanc e Packag e fo

r Chemica l Source s - Storag e Tanks " an d "Technica

l Guidanc e Packag e fo

r Loadin g Operations. " 

# /sP.1 6



### SPECIA L CONDITION S llAAllTnA I 

### . r n 

### nnn v Permi t No
. 328 4 UNCONTROLLE D COP Y Pag e 7
15
. Tank s note do n th e "Emissio n Source s - Emissio n Cap s an d Individua l Emissio n Limitations " tabl e wil l comply with TNRC C Regulatio n V b y continuin g t o compl y th e Alternat e Emissio n ("Bubble" ) Policy , Sectio n 101.23 , a s describe do n pag e 3- 2 o f th e permi t amendmen t

applicatio n date dSeptember 1995
.

Dated 5-6-9 6



## / £ <r>P.1 7

APPROVE

D CHEMICAL S LIS T Aceti c Aci d Aceton e Aminoethylethanolamin e Anhydrid e Butano l Buty l Acetat

e Buty l Acrylate Cyclohexanon e Crud e Polyglyco l Diaceton e Alcoho l Diethanolamin e Diethy l Sulfat

e Diethylen e Glyco l Diethylenetriamin e Diisobuty l Carbito l Diisobuty l Keton e Dimethylethanolamin e Dimethy l Heptano l Dipotasiu mPhosphat

e Ethanol , pure , all proof

s Ethanol , denature d Ethano l Denaturant s Ethy l Acetat

e Ethy l Acrylate Ethyl , Hexanol , 2

- Ethy l Hexoi c Acid , 2

- Ethylen e Glyco l Ethyleneamin e Mixture s Ethylenediamin e Ethylhexy l Acrylat

e Gluteraldehyde , 5 0 percent Glyco l Ether s Glyco l Ether

Mixture s Heavy Polyamin e X Hexylen e Glyco l Isobutano l Isobuty l Acetat

e Isobuty l Hepty l Ketone Isopentanoi c Aci d Isophoron e Isopropano l Isopropy l Acetat

e Methano l Methy l Amyl Alcoho l Methy l Butanol , 2

- Methyl Ethyl Keton e Methy l Isobuty l Keton e Methyldiethanolamin e Mixed OX

O Product s Monoethanolamine Monostill Tail s N-Methylethanolamin e (NMEA ) NIA X POLYOL S N-Pentano l Plant Mixtures * PotassiumHydroxid e Primar y Amyl Acetate Primar y Amyl Alcoho l Primar y Amyl Alcohol/Isobutano l Mixture s Propano l Propioni c Aci d Propy l Acetat

e Propylene Glyco l Sodiu mAcetat e Tergitol s (nonioni c surfactants ) Triethanolamin e Triethylen e Glyco l Tetraethylen e Glyco l Tetraethylen e Pentaamin e Triethylen e Tetraamin e Tristil l Tail s UCA REste r EE P (ethyl-3-ethoxypropionate ) UCA RFilmer IB T Valeri c Acid Viny l Acetat

e * A plant mixture i s ablen d o

f an y tw o o r mor e chemical s that

appea r o n th e Approved Chemical s Lis t

o r ablen d o f thos e chemical s an d mixture s wit h water . 

# UNCONTROLLE D COP

Y
Dated 5-9-9 6 

# nP.1 8 

# r EMISSIO N SOURCE S - EMISSION CAP S AN D INDIVIDUA L LIMITATION S Permi t No
. 328 4 UNCONTROLLE D COP Y IM s fcaMe list s th e maximumallowabl e emissio n rate s an d all source s o

f ai r contaminant s o n th e applicant' s prqperty covere d b y thi s permit
. Th e emissio n rate s show n ar e thos e derive d frominformatio n submitte d a s par t of flse applicatio n fo

r permi t and ar e th e maximu

mrate s allowe d fo

r thes e facilities
. An

y propose d increas e i n emissio n rate s ma y requir e a n applicatio

n fo r amodificatio n of

th e facilitie s covere d b y thi s permit
. AI RCONTAMINANT S DAT A

Emission i Poin t No , (1 )

E15A07 9 E15A15 2 E15A15 3

E15A07 9 E15A15 2 E15A15 3 Sourc e

Name Y2 )

Butadien e Flar e Doc k 6 6 Flar e Dock 6 7 Flar e NO x Emissio n Ca

p upo n operatio n ofth e flares , but no t late r tha n Novembe r 15,199 6
Butadiene Flar e Doc k 6 6 Flar e Doc k 67 Flar e NQx
. Air Contaminant Name (3 ) EMISSION S NO x NO x NO x

C O EMISSION S

C O C O C O Emissio n Ca p o r Individual Emissio n Limit* * lb/h r TP Y

7.3 9 5.2 3

* •

• C O Emissio n Ca

p upo n operatio n o

f th e flares, but

no t later tha n Novembe

r 15 , 199 6 63.4 3 44.8 6

VO C EMISSION S E15A15 4 E15A05 7 Dock 6 3 Rack 1 VO C VO C 

# / rPermi t

No
. 328 4 Pag e 2 

# UNCONTROLLE D COP Y

EMISSIO N SOURCES EMISSION CAP S AN D INDIVIDUA

L LIMITATION S AI RCONTAMINANT S DATA P.1 9

Emissio n Poin t No
. Cl ) E15A05 8 E15A06 0 E15AQ6 1 E15A06 2 EI5A06 3 E15A06 5 E15A06 6 E15A06 7 E15A06 8 E16A03 8 F15A001-1 8 through 2 0 F15A01 1 throug h 02 5 F15A03 0 ihrcaigh03 3 F15A04 7 throug h 05 2 F15A08 5 throug h 09 9 F15A0P 1 Sourc e

Nam e (2) Rac k 2 Rac k 5 * Rac k 6 Rac k 7 * Rac k 1 0 Doc k 6 2 Doc k 6 5 Doc k 6 6 Doc k 6 7 Ethano l Rack * Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) Air Contaminan

t Nam e (3 ) VO C VOC VOC VO C VO C VO C VO C VOC VO C VO C VOC VO C VO C
VO C VO C VO C Emissio n Ca p o r Individua l Emissio n Limit* *
. lb/h r TPY



# MPermi t

No
. 328 4 Pag e 3 EMISSIO N SOURCE S EMISSION CAP S AN D INDIVIDUAL UMITATION S AI RCONTAMINANT S DATA P.2 0

EiDJissiGn i Poin t Jifo.
. Cl ) F15A1TO throug h F15A 1 F15A15 7 F15A33ESL

N FL5.AM3SCL

N F1(6AO0M4) 1 iumough4 0

E15ASD8 5 E15A08 6 E15A08 7 E15A08 8 E15A09 O E15A09 2 E15A01 2 E15A!09( 6 E15AW 7 E15A09 8 E15A09 9 E15A01 5 Sourc e

Nam e (2) Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) Fugitive s (4 ) TOTA L VO C FUGITIVE S Tan k 92 0 Tan k 93 0 Tan k 94 1 Tan k 94 2 Tan k 94 8 Tan k 95 2 Tan k 95 4 Tan k 372 0 Tan k 372 1 Tan k 372 3 Tan k 372 4 Tan k 3725 * Emissio n Ca p o r Individual Ai r Contaminan

t Emissio n Limit* * Nam e (3) lb/h r TP Y VO C VO C 

# vo c UNCONTROLLE D COP Y VO C VO C
60.4 8 93.3 6 VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C

~> r^P.2 1 Permi t N o Pag e 4

Emissio n Poin t No
. E15A10 1 E15A10 2 E15A10 3 E15A10 4 E15A10 5 E15A01 8 E15A10 8 E15A10 9 E15A11 0 E15A11 1 E15A11 2 E15A11 3 E15A11 4 E15A02 0 E15A02 1 E15A11 5 E15A02 2

' E15A02 3 E15A024 328 4 i 

# r

EMISSIO N SOURCE S EMISSION CAP S AN D INDIVIDUAL LIMITATION S

fl ) AI RCONTAMINANT S DATA Emissio n Ca

p o r Individua l Sourc e Ai r Contaminan

t Emissio n Limit* * Namef2 ) Nam e (3 ) lb/hr TP Y Tan k 372 7 VO C Tan k 372 9 VO C Tan k 373 0 VO C Tan k 373 1 VO C Tan k 373 2 VO C Tan k 373 5 VOC Tan k 373 6 VOC Tan k 373 7 VOC Tan k 373 8 VOC Tan k 374 0 VOC Tan k 374 1 VO C Tan k 374 2 VOC Tan k 374 3 VO C Tan k 3744 VO C Tan k 374 5 VO C Tan k 374 6 VOC Tan k 374 7 VO C Tan k 374 8 VO C Tan k 374 9 VO C 

# UNCONTROLLE D COP Y

; ? /P.2 2 Permi t No
. 328 4 IRage 5 EMISSIO N SOURCE S EMISSIO N CAP S AN D INDIVIDUA L LIMITATION S AI RCONTAMINANT S DATA

Emissio n Poin t Ife.
. (fl ) E15A12S 0 E15A15 7 E15AM 8 E15A1I 9 EL5AL032 E15A12 4 E15A12 5 E15AO S E15A10 6 E15A12 7 E15A0 8 E15A13 0 E15A13 2 E15A10 7 E15A13 3 E15A13 S E15A13 9 E15A05 1 E15A05 2 Sourc e

Name C2 ) Tan k 376 1 Tank 375 7 Tank 385 8 Tank 375 9 Tan k 3764 Tank 376 8 Tank 376 9 Tank 377 3 Tank 3733 N Tank 377 5 Tank 377 6 Tan k 378 0 Tank 379 2 Tank 3733 S Tank L- l Tank L-1 0 Tank L-l l Tank L-1 2 Tank L-1 3 Emissio n Ca p o r Individual Air Contaminant

Emissio n Limit* * Nam e f3 ) lb/h r TP Y VO C VO C 

### v n r

# UNCONTROLLE D COPY VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C 

### ?;>
_P.2 3



# r Permi t No
. 328 4 Page< 6 EMISSIO N SOURCE S EMISSIO N CAP S AN

D INDIVIDUAL LIMITATION S AIRCONTAMINANT S DATA

ETnissiro n Pain t No
. C D E15A14 D E15A14 1 E15A13 4 EL5A13 5 E15A04 8 E15A131 S E15AB 7 E15AO5 0 E15A047 E15A04 9 E16A01 7 E16A01 8 E16A01 2 E l 601 9 E16A2 0 EMA02 1 E16A02 2 E16A02 3 E16A024 Sourc e

Nam e (2 ) Tan k L-1 5 Tan k L-1 6 TankL- 3 TankL- 4 Tan k L-5 * TankL- 6 TankL- 8 Tan k L-9 * Tan k L-2 * TankL- 7 Tan k BW-1 9 Tan k BW-2 0 Tan k BW-13 * Tan k 10 1 Tan k 10 2 Tan k 10 3 Tan k 10 4 Tan k 105 Tan k 10 6 Emissio n Ca p o r Individua l Ai r Contaminan

t Emissio n Limit* * Nam e (3 ) lb/h r TPY VO C VO C 

# v o c UNCONTROLLE D COP

Y VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C 

## y^,P.2 4 Permi t No
. 328 4 Pag e 7 

# C

EMISSIO N SOURCE S EMISSION CAPS AN D INDIVIDUAL LIMITATION S AI RCONTAMINANT S DATA

Emissio n Poin t No
. (1 ) E16A02 5 E16A00 2 E16A00 3 E16A03 3 E16A02 6 E16A02 7 EL6AQ5 0 E16A03 2 E16A02 8 E16A02 9 E16A05 5 E16A05 1 E16A05 2 E16A05 3 E1<6A05 4 E15AQ9 1 E15A01 1 E15A09 3 Sourc e

Nam e f2 ) Tan k 10 7 Tan k 10 8 Tan k 10 9 Tan k 11 2 Tan k 11 4 Tan k 11 6 Tank l Tan k 2 Tan k 20 9 Tank 21 1 Tan k 21 6 Tank 20 2 Tank 20 3 Tan k 20 4 Tan k 20 6 Tank 95 0 Tan k 95 1 Tan k 95 3 Air Contaminan

t Nam e f3 ) Emissio n Ca p o r Individual Emissio n Limit* * lb/h r TP Y VO C VO C 

### VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C 

# UNCONTROLLE D COP

Y

r>UP.2 5 

### 7 Permi t No
. 328 4 Page S Z** ^

EMISSIO N SOURCE S EMISSIO N CAP S AN

D INDIVIDUAL LIMITATION S AIRCONTAMINANT S DATA

Emissio n Poin t No
. fl ) E15A09 4 E15A01 3 E15ADI4 E15A10 0 E15A01 6 E15AD1 7 E15A01 9 E15A02 6 E15AQ3 Q E15AO ! E15A03 1 E15AQ3 3 E15A12 2 E15A12 3 E15A12 9 E15AD8 9 E15A02 5 E15A05 3 E15A05 4 Sourc e

Nam e f2 ) Tan k 95 5 Tan k 96 0 Tan k 96 1 Tan k 372 6 Tan k 372 8 Tan k 373 4 Tan k 373 9 Tan k 375 4 Tan k 3760 * Tan k 376 2 Tan k 3763 * Tan k 376 5 Tan k 376 6 Tan k 3767 Tan k 377 7 Tan k 94 3 Tan k 375 0 Pa t Tan k 1 Pat Tan k 2 Ai r Contaminan

t Nam e (3 ) Emissio n Ca p or Individual Emissio n Limit* * lb/h r TPY 

### VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C 

# UNCONTROLLE D COP Y

•z> crP.2 6 Permit No
. 3284 Pag e 9 

# C :

EMISSIO N SOURCE

S EMISSIO

N CAP S AN D INDIVIDUA

L LIMITATIONS AI RCONTAMINANT

S DAT A

Emissio n Poin t No
. O ) E15A05 5 E15A05 6 E16AQ4 5 E16A04 6 E16A04 8 E16AQ49 E15A11 6 E15A11 7 E15A14 2 E15A14 3 E15A14 4 E15A07 9 E15A15 2 E15A15 3 E15A15 1 E16A038 C Sourc e

Name (2) Pa t Tan k 3 Pat Tan k 4 Tank BW-1 8 Tank BW-2 1 Tank BW-2 2 Tank BW-2 3 Tank 375 2 Tank 375 3 Slo p Tank , Doc

k 6 2 Slo p Tank , Doc

k 6 6 Slo p Tank , Doc

k 6 7 Butadien e Flare Doc k 6 6 Flar e Doc k 6 7 Flar e Aceti c Aci d Scrubbe

r DS P Water

Scrubbe r Air

Contamina

n Nam e (3 ) VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C Emissio n Ca p o r Individua l t Emissio n Limit* *

lb/h r TPY
• 

# UNCONTROLLE D COP

Y

%

-y fP.2 7 Permi t No
. 328 4 Pag e 1© 

# r UNCONTROLLE D COP Y EMISSIO N SOURCE S EMISSION CAP S AN D INDIVIDUA L LIMITATION S AI RCONTAMINANT S DAT A

Emissio n Poin t No
. (1 ) Sourc e

Nam e f2 ) Air Contaminan

t Nam e f3 ) Emissio n Ca p o r Individual Emissio n Limit* * lb/h r TP Y VO C Emissio n Ca

p 1318.7 1 239.4 9 (Includin g Fugitives ) upo n operatio n o

f flares , bu t n o late r tha n Novembe r 15 , 199 6 (1 ) Emissio n point

identificatio n - either

specific equipmen

t designatio n o r

emissio n poin t

number from plo t plan
. (2 ) Specifi c point

sourc e name . Fo r

fugitive source s us e are anam e o r fugitive sourc e name . (3 ) VO C - volatil e organi c compound s as defined i n Genera l Rul e 101. 1 NO x - total oxide s of

nitroge n C O - carbo n monoxide {4) Fugitiv e emission s mus t b e include d in the emissio n caps . * Include d i n th e Alternate Metho d O f Contro l (AMOC ) Bubbl e Permi t agreement

(n o permi t

number)
. * * Emissio n cap s are base d o n an d th e facilitie s ar e limite d b y th e following maximu moperatin g schedule : Hrs/da y Days/week

Weeks/yea

r or 8.76 0 Hrs/yea

r

Date d 5-6-9 6

?-l