A d cot e L 8 6

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# A D C O TETM L 86-1 1 3

Lami nating A d hesi v e

D e s c ription a n d Fe a t ure s

A d c o te L 8 6 -1 13 is a s o l v e n t b a s e d t w o c o m pon e n t po l y ur et ha ne a d h e si ve wit h h i gh s o l i d c h ar a c t e r i s t ic s

e x c e l l ent h e a t a n d c h em i c al r e s i s t anc e. T h is po l y es t e r ad he s i v e in c o nj u n c t i on wi th v a r i ous is oc y a n a te

te r m inat ed c o r e ac t ants f u nc ti ons as a l a m i nat i n g ad hes i v e f o r

f l ex ib le p a c k agi ng an d in dus tr ia l a p pl ic a t i ons

. A d c o t e L 86

- 1 1 3 p r ovi d e s op ti cal cla r it y an d hi gh b o n d st r e n g t h

.

A d c o te L 8 6 -1 13 ad hes i v e a d h e r e s t o a wi de v a ri et y of s ubs tr ates i n c l ud in g c e l l o p h a ne, tr e a t e d p o l y o l ef ins

, p o l y es t e r

, po l y am id e, al u m inum f o il, p a p e r

, m e ta l i z ed a nd P V D C c o at ed m a ter i a l s

, a n d t h e tr e a t ed s i d e of

h e a t

- s ea la bl e coe x t r ud ed films.

T y p i cal U s e s

A d c o te L 8 6 -11 3 w i th is s u it abl e f o r the lam i nati on of tr ans p a r e n t an d a l um inum

- c o n ta in ing s t ruc t ur es w i t h

a nd with out sa nd wic h pri n ti ng. Pr inc i pa l us es a r e in f l ex ibl e m a ter i als f o r f ood po u c hes , v a c u u m or gas

f l us hed l unc h e on m eats an d c hees e

, c o f f ee pou c hes

, c ond im ent pac k a ging , c a b l e w r ap lam i n a ti ons

, liq uid

p a c k aging, h y gr os c opic p o w der s

, c h em ic als and c o s m etic s.

T y p i cal P r o p ert i e s *

A d co t e L 8 6

- 1 13 C o re ac t a n t F **

(OH Compo n ent) (N CO Co mponent)

S o l i ds 75% 75 %

V i s c os it y 65 00 c p s @ 7 7 ° F (2 5 ° C) 18 00 c p s @ 7 7 ° F (2 5 ° C)

W e ight/G a l lo n 9.1 l b ( 1 .1 0 g/c c ) 9.9 l b ( 1 .1 9 g/c c )

S o lv en t s E t hy l A c e t at e E t hy l a c et a t e

M i x Ra ti o 10 0 p a r t s b y wei g h t 13 par ts b y we ig ht

S h elf Lif e 36 0 d a y s 18 0 d a y s ( u no pe ne d c o nt a i n e r s )

Di lu en ts Met h y l e t h y l k e to ne, t o l u e n e

, or ur e t h a n e gr ad e et h y l ac eta t e

A l te r n a t e Co re a c ta nts ( N C O Comp on e n t)

Cor e a c tant CT Cor e a c tant 9 L 1 0

S o l i ds 70% 75 %

V i s c os it y 14 00 c p s @ 7 7 ° F (2 5 ° C) 13 00 c p s @ 7 7 ° F (2 5 ° C)

W e ight/G a l lo n 9.5 l b ( 1 .1 0 g/c c ) 8.9 l b ( 1 .0 7 g/c c )

S o lv en t s E t hy l A c e t at e E t hy l a c et a t e

M i x Ra ti o 10. 5 par ts b y we ig ht 10

. 5 par ts b y we ig ht

S h elf Lif e 18 0 d a y s 18 0 d a y s ( u no pe ne d c o nt a i n e r s )

Di lu en ts Met h y l e t h y l k e to ne, t o l u e n e

, or ur e t h a n e gr ad e et h y l ac eta t e

*T hes e it em s ar e pr o v i d e d f o r

g e n e r a l inf o r m ati o n o n l y

. T h e y ar e a ppr oxim ate v a lu e s a n d ar e n o t

cons i der ed p a r t of a pr o d uc t s pec if ic a t i on.

** O t h e r c o r e ac t a n t s ar e a v ai la bl e f o r s pec ia l us e s

. C ons ul t y o ur R ohm a n d H aas s a l e s r e pr es e n t a t i ve f o r

fu r t h e r in fo r m a t i o n.

d c o t e L 86 -113 J une 2 0 07 Page 1 of 5 

# PACKAG ING AN D

BUILDIN G MATE RIALS

ADHESIVE S AND SE ALA N TS

ASafety , Hand ling and Stor age

• Store in co ol, dry, well-ve ntilated are a away fr om heat and ignition source s. Keep contai ner ti ghtly

clo s ed.

• Hot org ani c chemical vapo rs can sudd e n ly and witho u t warni ng ig nite whe n mixed with air. Ignition

can o c cur at t y pical elevate d temperature pro c e ss co ndition s. Please eval uate su ch processes to

assure safe h andlin g con d i t ions.

• Suppo rt and grou nd contai ners befo r e o penin g , disp e n sin g , mixing, pourin g or e m ptying. Open with

non-sp arking tools. If container i s wa rm , open bun g slowly to relea s e the interna l pressu re.

• Wa sh tho r ou ghly after han dling. Wa sh contami nated goggle s , face shiel d , and gloves.

Professio nall y launder con t aminated cl o t hing before re-u se.

• ATTENTIO N! Containe r can be ha za rd ous whe n em pty. Follow label wa rnin gs even after co ntainer

is empty. Do not use h eat, spa r ks, ope n flames, to rch e s or ciga rett es on o r nea r empty contai ners.

Do not re use empty contai ner wi th out profession al cle aning.

• Refer to Mate rial Safety Da ta Sheet for more info rma t ion.

Alcohol and si milar mater i al s containing a c tive h y droge n can react with the Adcote L 86-113 and Coreactant

causing inadequate cure. Adcote L 86-113 with Coreactant could p o tentially in ter a ct with other constituen ts

of the lamin ated structures. Retained so lven ts, prin tin g inks, slip ad ditives, fi lm a dditives, antib lock agents,

coatings, contaminated solvents as well a s the pack ed product are some of the components tha t ma y cause property changes of the film and/or adhes ive

.

Recommend ed Operat ing Condit i ons Applica t ion Method Direct gravure

Applica t ion Cylinder 165 - 200 line (65 - 80 line per cm)

Applica t ion Solids 35 - 50 %

Pot Life Sta t ic 8 hours appro x ima tely

Dynamic 24 hours appr oxima tely

Dry Adhesive Weight 1.1 - 2.5 lb /re a m (2

- 4.5 gs m) depending on s t ructure and end use

Drying Web T e mperature 150 - 200 ° F ( 65 - 93 ° C)

Lamination T e mperature 125 - 180 ° F ( 52 - 82 ° C)

Cure Time 5 - 10 days at 70 ° F (21 ° C)

Slitting /Rewinding T ime 4 - 8 hours a t 70 ° F (21 ° C)

Cleaning Solvent Methyl eth y l ketone, e t hyl a c etate or o t he r suitab le org anic solven ts.

Initial bond immediate l y o f f the laminator is good. With in 48 ho urs the bond strength will be sufficient for

further processing, such as slitting and rewinding. Ma ximum properties of heat and chemical re sistance will

develop with in 5 - 10 da ys.



### ________________________ _____________________ ________________________ ADCOTE is a re gistered tradema r k of Rohm and Haas Compan y.

These suggestions and data ar e based on inform at ion we believe to be reliable. T h e y a r e offe red i n good faith, but w i thout

guarantee , as conditions and method of use of ou r products are b e y ond ou r control. We recommend that the pr ospective user

determine the sui t ability of ou r mat e rials and sugges tions before ado pting them on a c o mmercial scale.

Suggestions for uses of our pro d u cts or the inclusion of descriptive material from pa tents and the citation of specific p a tents in this

publication should not be und erst ood as recomme nding the use of our pr o ducts in violation of an y pa t ent or as pe rmission or lic ense

to use an y p a tent s of the Rohm an d Haas Compan y.

V i sit us at htt p :/ /w w w .rohmhaa s

. c o m /A dhe siv e sS eal ant s

R ohm a n d H a a s C o mpa n y

, Midw e s t T e ch nic a l C ent er, 25 31 T e c h n o lo gy D r i v e, S u ite 30 1, E l g i n, IL 6 0 1 2 4

P hon e: 84 7- 64 9- 380 0 F a x : 847 -6 49- 37 60

A d cot e L 8 6

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## Rohm and Haas Food and Drug Opinion

Name: ADCOTE (T M) L 86-113



### Regulation Com p lies 

### Opinion

Date Limitations

21CF R 175.1 0 5 Y 12/04/2006

21CF R 175.3 0 0 Y 12/04/2006

21CF R 175.3 2 0 Y 12/04/2006

21CF R 176.1 7 0 L 12/04/2006

▪ PROVIDED THAT T H E FOOD CONT AC T S URFACE OF THE

PAPER AND P APERBOARD COMPLIES WIT H T H E

EXT R ACT I VES LIMIT A T ION S IN 21CF R 17 6.170 PARAG RAPH (C).

21CF R 176.1 8 0 Y 12/04/2006

21CF R 177.1 2 1 0 Y 12/04/2006

21CF R 177.1 3 9 0 L 12/13/2006

▪ Compos itio na l compli anc e w i th 21 CF R 177. 139 0 req u ires t he use

of anoth e r com pon ent that is li sted in the sam e para g ra ph of 21

CF R 177.1 3 9 0 . In other w o r d s, a compone n t listed in (c)(2) ( v) ma y

NOT be used w i t h a comp on ent list ed i n (c)(2)(vi), unless migratio n

studies h a ve af firmed the com b in ation to b e i n compl i anc e w i t h the

F D A regul ation s

. T h is require ment for use of compon ents in the

same sectio n o f 21 CF R 177.1 390 a p p lies to the use of this material

in comp lia nce w i t h 21 CF R 1 77.13 95 as w e l l

. Paragr aph (c)( 2)(v)(a)

21CF R 177.1 3 9 5 L 12/13/2006

▪ In accorda n c e w i t h the lim itations as d e scr ibe d un der

21CF R 177.1 3 9 0 abov e.

21CF R 177.1 6 3 0 L 12/04/2006

▪ WHEN USED AS A HEA T S EAL MAT E RIA L , IN ACCORDANCE

WIT H PARAGRAPH (E)(3), A ND PROVIDED T H E MA TE RIAL

MEET S T H E APPROPRIAT E REGULAT ION END T E ST UNDER

21CF R 177.1 2 1 0

.



### Legend:

L Yes, this prod uct is cleared w i t h limitatio n s noted

N No, this prod u c t is not cleared

Y Yes, th is p r o d u c t is cleared

. A A f fir m ed as c o mp lian t b ase d o n mig r ation stu d i es.



### Regulations:

21CF R 175.1 0 5 A d h esi v e s

21CF R 175.3 0 0 Re s i nous a n d poly m e r ic c o a t ings

21CF R 175.3 2 0 Re s i nous a n d poly m e r ic c o a t ings for p o l y ole f in films

21CF R 176.1 7 0 Compone nts of pa pe r a nd pa pe rboa rd in c onta c t w i th a que ous a nd f a tty foods

21CF R 176.1 8 0 Compone nts of pa pe r a nd pa pe rboa rd in c onta c t w i th dry food

21CF R 177.1 2 1 0 Closures w i t h sealing gaskets for food c ontainers

21CF R 177.1 3 9 0 L a min a te stru ctu r es fo r u s e at temp eratu r es o f 250F an d ab o v e

21CF R 177.1 3 9 5 L a min a te stru ctu r es fo r u s e at temp eratu r es b e t w een 120F an d 250F

21CF R 177.1 6 3 0 Poly e t h y le ne phtha la te po ly me rs

Disclaim e r: This information relates specifically to this prod uct. We believe this information to be accurate and reliable as of this date.

We recomme nd that our customers make their own dete r mi nation on the suitability of this product f o r their pa rticular appli cation.

We cannot gu arantee th at the i ndirect food addit i ves/f ood-contact status of this product w ill remain unchanged indefi n itel y;

therefor e w e recommend that yo u periodically ver i fy its status.

A d cot e L 8 6

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## Rohm and Haas Food and Drug Opinion

Product Na me: CO REACTA NT F

Regula t ion Number Complies Limitations Opinion Date

21CF R 1 75.1 0 5 L 1 May 12, 2000



### Legend:

L Yes, this prod uct is cl eared with limitations a s noted.



### Limitations:

1 SOLVENT MUST BE COMPLETELY EVAPORATED DURI NG DRYING

AND C U R IN G.



### Regulations:

21CF R 17 5.10 5 ADHESIVES

-- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- - -- -- -- -- -- -- -

Product Na me: CO REACTA NT CT

Regula t ion Number Complies Limitations Opinion Date

21CF R 1 75.1 0 5 L 1 May 12, 2000



### Legend:

L Yes, this prod uct is cl eared with limitations a s noted.



### Limitations:

1 SOLVENT MUST BE COMPLETELY EVAPORATED DURI NG DRYING

AND C U R IN G.



### Regulations:

21CF R 17 5.10 5 ADHESIVES



### Disclaimer:

This info rmati on rel a tes sp ecif ically to this product. We believe this information to

be accu rate a nd relia ble a s of this date.

We recomm end that our customers make their own det ermi nation on the suitability

of this prod uct for their part i cula r appli c at ion.

We cann ot guara n tee that the indire ct food additive s/food-co ntac t status of this

prod uct will remai n un ch ange d ind e finitely; therefore we re co mmend th at you perio dically verify its status.

A d cot e L 8 6

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### Name: COREACTANT (TM) 9L10

Regula t ion Complies Opinion

Dat e Limitations

21CF R 175.1 0 5 Y 05/12/2004

21CF R 177.1 3 9 0 L 08/16/2005

▪ SOLVENT M U ST BE COM P LET E LY EV APORAT E D D URING

DRYING AND CURING.

▪ PROVIDED THAT I T IS NO MORE T H AN 14% OF T H E

WEIGH T OF THE CURED A DHESIVE.

▪ Compos itio na l compli anc e w i th 21 CF R 177. 139 0 req u ires t he

use of an other compo nent tha t is listed in the same para g ra ph of

21 CF R 17 7.13 90. In other w o rds, a compo nent liste d in (c )(2)(v)

ma y NOT be used w i th a com pon ent liste d in (c)(2)(vi), unle ss migratio n studi es have affirm ed the comb in ation to b e in

compli anc e w i t h the F D A regu latio n s. T h is requir e ment for u s e of

compo nents i n the same secti on of 21 CF R 1 77.13 90 a ppl ie s to

the use of this material i n com p lia nce w i t h 21 CF R 177.13 95 as

w e ll.

Paragr aph (c)( 2)(v)(c)

21CF R 177.1 3 9 0 A 08/16/2005

▪ A = AFFIRMED AS COMPLIANT BASED UPON MIGRATION

ST UDIES. Adcote 81 2 a nd C O REACT A N T (T M) 9L10, us ed at a

ratio of 100: 8, at a maxim u m of 4 g/m2 (2.4 lb/ream), c u red at

49°C (12 0 °F ) for 10 da ys, and has as a food co ntact la yer 7 5

micron (3 m i l ) of cast pol ypr o p y l e n e , ma y be used w i t h n o

limitatio ns as to temperatur e or food-t y pes i n compl i anc e w i t h the

Unite d States F edera l F ood, Drug, a nd C o s m etic Act. Adcote 81 2

and COREAC T A N T (T M) 9L10, use d at a rati o of 10 0: 8, at a

maximum of 4 g/m2 (2.4 lb/r ea m), cure d a t 49°C (1 20°F ) for 4

da ys, a n d h a s a 2 5 m i cron (1 mil) fo od c onta c t la yer, m a y b e us ed

at all temper atures w i t h a q u e ous a nd aci d ic food t y p e s (T yp es I,

II, IVB

, VIB, and VIIB, as defined in 21 CFR 176.170(c) T able 1) in

compli anc e w i th the Unit ed States F eder al F o o d , Dru g , and

Cosmetic Act.

▪ A = Affirmed as compl i ant b a sed u p o n mig r ation stud ies

▪ Adcote 76 X1 59 an d CORE ACT A N T (T M) 9L1 0, used at a ratio

of 100:8, at 2.9 lb/ream, and c u r ed for 8 d a y s at 120F and 3 da ys at room temper ature, ma y be used as a n ad hesiv e la yer i n

multilam i n a te food p a cka gin g materials w i t h aqu eo us food typ e s

w i t h a food c o n t act la yer of at l east 3 mil cast pol yp rop y l e ne und er

all co nditi ons o f use in full co mplia nce w i t h the F eder al F o o d

, Drug a nd Cos m etic Act.

21CF R 177.1 3 9 5 L 08/16/2005

▪ In accorda n c e w i t h the lim itations as d e scr ibe d un der

21CF R 177.1 3 9 0 abov e. 

### Legend:

L Yes, this prod uct is cleared w i t h limitatio n s noted

N No, this prod u c t is not cleared

Y Yes, th is p r o d u c t is cleared

. A A f fir m ed as c o mp lian t b ase d o n mig r ation stu d i es.



### Regulations:

21CF R 175.1 0 5 A d h esi v e s

21CF R 177.1 3 9 0 L a min a te stru ctu r es fo r u s e at temp eratu r es o f 250F an d ab o v e

21CF R 177.1 3 9 0 L a min a te stru ctu r es fo r u s e at temp eratu r es o f 250F an d ab o v e

21CF R 177.1 3 9 5 L a min a te stru ctu r es fo r u s e at temp eratu r es b e t w een 120F an d 250F

D i scla i mer :

T h i s i n f o r m ati o n r e l a tes s peci f i c al l y to thi s pr oduct

. W e bel i e v e th i s i n for m a ti on to be ac cur a te and r e l i a bl e as o f thi s dat e.

W e rec o mmend th a t our c u sto m ers m a k e t heir ow n det erm i n a tion on t he s u ita b ilit y of

t h i s produc t for their parti cular ap pli cati on

. W e c ann ot g u ar a n te e th at t he i n di r e ct f o od

additiv e s/ f o od-con t act status o f t h is pro duct will rem a in unch ang ed i n de f i nitely ; there f ore w e reco m m en d th at y ou periodically v e rif y its status.

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