413-1

RULE 413 Organic Liquid Loading - Adopted 4/18/72, Amended 8/27/84, 8/22/89, 4/11/91, 9/19/91, 4/6/95, 3/7/96 I. Applicability This Rule shall apply

to organic liquid loading facilities as defined in this Rule loading 4,000 gallons, or

more in any one da

y. This Rule shall not

apply to gasoline bulk pla

nts subject to requirements of Rule 412. II. Definitions A. Class I Organic Liquid L oading Facility : any facility load ing 20,000 gallons,

or more on anyone day of organic liquids with a true vapor pressure of 1.5 psia, or greater into tank trucks, trailers , or railroad tan k cars. B. Class II Organic

Liquid Loading Fac

ility : any facility loading 4,000 gallons, or more but less than 20,000 gallons on any one day of organic liquids with a true vapor pressureof 1.5 psia, or grea

ter into tank truck

s, trailers, or ra

ilroad tank cars

. C. ExcessOrganic Liquid Drainage : more than ten milliliters liquid drainage. Su ch liquid drainage for disconnect operations shall be determined by computing average drainage from three conse

cutive disconnec

ts at any one permi

t unit. D. Leak : dripping of liquid organic compounds at a ra te of m ore than three drops per minute; or detection of or ganic compounds i

n excessof 10,000 ppm as methane when measured with a portable

hydrocarbon detection instrument calibrated with methane and conducted in accordance with U.S. EPA Method 21. E. Org anic L iquid : any liquid contain ing VOC's and havin

g a true vapor pr

essure (TVP) greater than 1.5

psia at actual loa

ding conditions. F. Organic

Liquid Loa ding Facility : any aggr egate, or combination of organic liquid loading and vapor control equipment, from the connection a

t the inlet of the or

ganic liquid pump to, and including, the hose end connector at the portable delivery tanks and the discharge of the vapor control device(s). G. Portable

Hydrocarbon Detection Instrument : hydrocarbon an alyzer using fla

me ionizat io ndetection or thermal conductivity and satisfying U.S. EPA Method 21, 40 CFR, Part 60. Output of any such i nstrument shall be equivalent to calibration on methane and a sampling rate of one liter per minute. H. Vo latile Organic Compound ( VOC) : any compound containing at least one atom of carbon except for compounds exempted by Rule 102, Subsection L.413-2

III. Exemptions A. Requirements

of Subsection IV. of this Rule shall not apply to organic liquid load ing facilities used exclusively for loading of less than 4,000 gallons of organic

liquids in any one day. B. Requirements

of this Rule shall not

apply toloading facilities subject to requirements of R ule 412 - Gasoline Transfer into Stationary Storage Containers, Gasoline Delivery Vessels, and Gas

oline Bulk Plants. C. Requirements

of this Rule

shall not apply to

loading of organic liquids with true vapors pressure less than 1.5 psia at actual loading temperature. IV. Requirements A. Emission Limits

Loading Facility VOC Emission Limit Class I 0.08 pounds per 1,000 gallons loaded Class II 95% combined collection/control efficiency B. Equipment 1. Class I facilities shall be equipped with pr

ovis ions for bottom loading, vapor collection, and va

por disposal. 2. Class II facilitie

s shall be equipped with provisions for vapor collection, and vapor disposal. 3. Anyvapor collection and controlsystem serving a ga soline tank truck s

hall operate with a pres sure in the delivery tank being loaded of not more than 18 inches water column. 4. All delivery tanks previously containing organic liquids with a true vapor pressure greater than 1.5 psia at lo

ading condit

ions shall be filled only at loading facilities conforming to Subse

ctions IV.A. and B. 5. Loading and vapor

collection equipment shall be designed, installed, maintained and operated without

leaks or excess o

rganic liquid dra

inage at disconne

ctions. 6. Construction of

any new top loading facility or reconstruction, as defined in Rule 422

- NSPS, or expansion of

any existing top loading facility with top loading equipment413-3 shall not be allowed after May 6, 1991. 7. Not withs tanding Subsection IV.B.1., above, organic liquid loading facilities exclu si vely

handling liquified petroleum gas need not utilize bottom loading, provided the operator com

plies with emission li

mit of Subse cti on IV.A. and provisions of Subsection IV.B.5. V. Administrative Requirements A. Record Keeping 1. Facilities exempted

by Section III. of this Rule shall maintain accurate daily records of liquid throughput, loading tem perature and liquid true vapor pressure and make suchrecords readily availab le to Distri ct staff upon request. All records shall be maintained at the f

acility or a minimum o

f two years. 2. Class I and Class

II facili ties shall maintain d

aily records of l

iquid throughput, loading temperature, and liquid true vapo r pressu re and make such

records readil

y available to District staff upon request. All records shall be maintained at th

e facility for a minimum of two y

ears. B. Test Methods 1. Analysisof exempt halogenated exempt compounds shall be by CARB Method 432. 2. Compliance with Subsections IV.A. and IV.B. shall be determined, for initial compliance determination and whe n inspection reveals conditions indicative of performanceless effective than during previous compliance determination(s), using 40 CFR 60.503 "Test

Methods and Proce

dures" and U.S. EPA

Reference Methods 2A, 2B, 25A and 25B and CARB Method 432, or CARB Method 2-4. 3. True vapor pressure

shallbe measured using Reid vapor pressure ASTM Method No. D-323-82 modified by maintaining ho t water bath at storage temperature. Where storage temperature is above 100 F, true vapor pressure may be determined by R

eid Vapor pressure at 100 F and California Air Resources Board-approved calculations. Organic liquid listed in

Table I shall be de

emed in complianc

e with appropriate vapor pressure limits for material, provided actual storage temperature does not exceed the corresponding maximum temperature listed.413-4 TABLE I MAXIMUM STORAGE TEMPERATURES FOR ORGANIC LIQUIDS

FOR PURPOSES OF SUBSECTION IV.B.3. Vapor Pressure Lim

it Maximum St orage Temp( F ) Gravity Initial Boiling 0.5 1.5 ORGANIC LIQUID oAPI PointoF (psia) (psia) Middle Distillates Kerosene 42.5 350 195 250 Diesel 36.4 372 230 290 Gas Oil 26.2 390 249 310 Stove Oil 23 421 275 340
Jet Fuels JP-1 43.1 330 165 230 JP-3 54.7 110

---- 25 JP-4 51.5 150 20 68 JP-5 39.6 355 205 260 JP-7 44-50 360 205 260 JP-8 37-51

--- 167 222 Fuel Oils No. 1 42.5 350 195 250 No. 2 36.4 372 230 290 No. 3 26.2 390 249 310 No. 4 23 421 275 340 No. 5 19.9 560 380 465 Residual 19.27

---- 405

---- No. 6 16.2 625 450

---- Asphalts 60 - 100 pen.

---- ---- 490 550 120 - 150 pen.

---- ---- 450 500 200 - 300 pen.

---- ---- 360 420