# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 1 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 

### SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPA NAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL, OCTAHYDRO

MSDS Number : R000RD032422 Product Use Description : Fragrance Ingredient

Company : IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : (732) 264

- 4500

Telefax : (732) 335

- 2551 Emergency telephone number : +1 800 424 9300



### SECTION 2 HAZARDS IDENTIFICATION

Emergency Overview

OSHA Hazards : Moderate skin irritant Moderate eye irritant

Carcinogenicity :

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinog en or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is iden tified as a carcinogen or potential carcinogen by ACGIH.

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 2 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 

### SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

Component CAS

- No.

4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- , 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL, OCTAHYDRO

1464989

- 16

- 9, 1467039

- 69

- 5



### SECTION 4. FIRST AID MEASURES

First aid procedures

Inhalation : Remove from exposure site to fresh air and keep at rest. Obtain

medical advice.

Skin contact : Remove contaminated clothes. Wash thoroughly wit h water (and soap). Contact physician if symptoms persist.

Eye contact : Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist.

Ingestion : Rinse mouth with water and obtain medical advice.



### SECTION 5. FIREFIGHTING MEASURES

Flammable properties

Flash point : > 199 °F ( > 93 °C )

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 3 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 Fire fighting

Suitable extinguishing media : Use water spray, dry chemical, carbon dioxide or appropriate foam.

Protective equipment and precautions for firefighters

Special protective equipment for firefighters : Wear NIOSH approved self

- contained breathing apparatus and full protective clothing when fighting fires involving chemicals. Use water spray to cool containers exposed to fire.



### SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Avoid inhalation and contact with skin and eyes. A self

- contained breathing apparatus is recommended in case of a major spill.

Environmental precautions : Keep away from drains, surface

- and groun dwater and soil.

Methods for containment / Methods for cleaning up : Clean up spillage promptly. Remove ignition sources. Provide adequate ventilation. Avoid excessive i nhalation of vapours. Gross spillages should be contained by use of sand or inert powder and disposed of according to the local regulations.



### SECTION 7. HANDLING AND STORAGE

Handling : Avoid excessive inhalation of concentrated vapors. Follow good manufacturing practices for housekeeping and personal hygiene. Wash any exposed skin immediately after any chemical contact, before breaks and meals, and at the end of each work period.

Contami nated clothing and shoes should be thoroughly cleaned

before re

- use.

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 4 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 If appropriate, procedures used during the handling of this material should also be used when cleaning equipment or removing residual chemicals from tanks or other containers, especially when steam or hot water is used, as this may increase vapor concentrations in the workplace air. Where chemicals are openly handled, access should be restricted to properly trained employees. Keep all heated processes at the lowest necessary temperature i n order to minimize emissions of volatile chemicals into the air.

Advice on protection against fire and explosion : Keep away from ignition sources and naked flame.

Requirements for storage areas and

containers : Store in a cool, dry, ventilated ar ea away from heat sources. Keep containers upright and tightly closed when not in use.



### SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Engineering measures

Engineering measures : Where feasible, i solate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. Where feasible, use closed systems to transfer and process this

material

Personal protective equipment

Eye protection : Use tight

- fitting goggles, face shield or safety glasses with side shields if eye contact might occur.

Hand protection : Avoid skin contact. Use chemically resistant gloves.

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 5 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 Respiratory protection : Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the wor k area to eliminate or reduce possible worker exposures. No respiratory protection is required during normal operations in a workplace where engineering controls such as adequate ventilation,

etc. are sufficient.

If engineering controls and safe work prac tices are not sufficient, an approved, properly fitted respirator with organic vapor cartridges or canisters and particulate filters should be used:

a)while engineering controls and appropriate safe work practices and/or procedures are being implemented; or b)during short term maintenance procedures when engineering controls are not in normal operation or are not sufficient; or c)if normal operational workplace vapor concentration in the air is increased due to heat ; d)during emergencies; or e)if engineering controls and operational practices are not sufficient to reduce airborne concentrations below an established occupational exposure limit.

Hygiene measures : To the extent deemed appropriate, implement pre

- placement and regularly schedul ed ascertainment of symptoms and spirometry testing of lung function for workers who are regularly exposed to

this material. To the extent deemed appropriate, use an experienced air sampling expert to identify and measure volatile chemicals that could be

p resent in the workplace air to determine potential exposures and to ensure the continuing effectiveness of engineering controls and operational practices to minimize exposure.

Protective measures : In December 2003, the National Institute for Occupation al Safety

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 6 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 and Health ("NIOSH") published an Alert on preventing lung disease in workers who use or make flavorings [NIOSH Publication

Number 2004

- 110]. In August 2004, the United States Flavor and Extract Manufacturers Association (FEMA) issued a report en titled "Respiratory Safety in the Flavor Manufacturing Workplace". Both of these reports provide recommendations for reducing employee exposure and for medical surveillance in the workplace. The recommendations in these reports are generally applicable to the use of any chemical in the workplace and you are strongly urged to review both of these reports. The report published by FEMA also contains a list of "high priority" chemicals. If any of these chemicals are present in this product at a

concentration >= 1.0% due to an intentional addition by IFF, the chemical(s) will be identified in this safety data sheet.



### SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical state : liquid

Safety data

Flash point : > 199 °F ( > 93 °C )

Vapour pressure : Note : not determined



### SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Remarks : Direct sources of heat.

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 7 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 Chemical stability : Remarks : Presents no significant reactivity hazard, by itself or in contact with water. Avoid contact with strong acids, alkali or oxidizing agents.

Hazardous decomposition products : Note : Carbon monoxide and unidentified organic compounds may be formed during combustion.



### SECTION 11. TOXICOLOGICAL INFORMATION

SECTION 12. ECOLOGICAL INFORMATION

SECTION 13. DISPOSAL CONSIDERATIONS

Contaminated packaging : Place material into sealed containers and dispose of in accordance with local, state and federal regulations.



### SECTION 14. TRANSPORT INFORMATION

DOT Not dangerous goods

IATA Not dangerous goods

IMDG Not dangerous goods



### SECTION 15. REGULATORY INFORMATION

OSHA Hazards : Moderate skin irritant, Moderate eye irritant

# Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product 4,7

- METHANO

- 1H

- INDENE

- 1

- PROPANAL, OCTAHYDRO

- ; 4,7

- METHANO

- 1H

- INDENE

- 2

- PROPANAL,
OCTAHYDRO

Print Date 11/18/2014 Page 8 ( 8 )

Version : 1

Revision Date : 11/18/2014

IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730 IFF US Fragrances Creative Center 600 State Highway # 36

Hazlet NJ 07730

Telephone : +17322644500 Telefax : +17323352551 SARA 311/312 Hazards : Acute Health Hazard

Reportable Quantity :

HMIS Classification : Health hazard : 1 Flammability : 1 Physical and chemical hazards : 0



### SECTION 16. OTHER INFORMATION

Further information

The information in this MSDS was obtained from current and reliable sources. However the data is provided

without an y warrant, expressed or implied, regarding its correctness or accuracy. Since the use, handling, storage and disposal of this product are beyond IFF control, it is the responsibility of the user both to determine safe conditions for the use of this product and to assume liability of loss, damage, or expense arising out of the product's improper use. No warranty expressed or implied regarding the product described herein shall be created by or inferred from any statement or omission in this MSDS. Various Fe deral, State or Provincial agencies may have specific regulations concerning the transportation, handling, storage, use, or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance

.