p.1 

OAR Box 1413 

Prepped by Ollie Stewart 

Document Number: 

32) 11-1-32 

Docket Number: 

A-94-52 

Printed 7/9/2008 3:11:21 PM Sheet 32 of 114 
—."•"— ^ r >v^.'J!-."^t/vy 

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RECEIVED 

JUN 2 2 1994 

WV OF ENVIRONMENTAL QUAUTY 

PERMITS 4 ENFORCEMENT 

A-04-52 

EMISSIONS COMPLIANCE TESTS 

STYRENE AND VISIBLE EMISSIONS 

Fiberglass Reinforced Plastic Lay-up Facility 

Idaho Permit To Construct 860-0035 

GEA/Thermal-Dynamic Towers Inc. 

12600 W. Colfax Ave., Ste. C500 

Lakewood, CO 80215 

dba: 

Dynamic Fabricators 

1735 W. Highway 53 

Rathdrum, Idaho 83835 

(208) 773-1787 

August 26, 1993 

By 

Bison Engineering, Inc. 

P.O. Box 1703 

30 S. Ewing 

Helena, MT 59601 

(406) 442-5768 

Report Date: October 1, 1993 
P.3 

TABLE OF CONTENTS 

EXECUTIVE SUMMARY iii 

CERTIFICATION OF REPORT INTEGRITY iv 

1.0 INTRODUCTION 1 

1.1 Purpose 1 

1.2 Emission Source Description 1 

1.3 Control Equipment Description 2 

1.4 Source Test Dates 2 

1.5 Pollutants Tested 2 

1.6 Personnel 2 

1.6.1 Bison Engineering, Inc 2 

1.6.2 Dynamic Fabricators 3 

2.0 TEST RESULTS SUMMARY 4 

2.1 Emission Results 4 

2.2 Process Data 4 

3.0 SAMPLING AND ANALYSIS 5 

3.1 Sample Location 5 

3.2 Sampling Procedures 5 

3.3 Field Notes and Special Circumstances 5 

3.4 Data Reduction and Calculations 6 

4.0 QUALITY ASSURANCE 7 

APPENDICES 

A 

B 

C 

D 

E 

F 

Pretest Protocol/Permit to Construct #860-0035 

Field Data/Calculations 

Operating Data/Raw Material Usages 

Laboratory Data with Chain of Custody Form 

Nomenclature, Formulae and Lab Methods 

Calibration Data 

£~ 
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EXECUTIVE SUMMARY 

Bison Engineering, Inc. (Bison) performed Title 40,Code of Federal Regulations (CFR), 

Part 60, Appendix A, Method 1, "Sample and Velocity Traverses for Stationary 

Sources", Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate 

(Type S Pitot Tube)", Method 3, "Gas Analysis for Carbon Dioxide, Oxygen, Excess 

Air and Dry Molecular Weight", Method 9, "Visual Determination of the Opacity of 

Emissions from Stationary Sources". Bison also determined stack moisture content 

using wet/dry bulb temperatures along with a psychrometric chart and tested for 

fugitive styrene emissions in the stacks at the facility near Rathdrum, Idaho. 

Permit to Construct 860-0035 requires compliance testing for combined fugitive 

styrene and visual emissions in two stacks in accordance with the above methods. 

The combined stack limit for styrene emissions is 8.1 pounds pre hour (lb/hr) and 

opacity can not exceed 20% during any 3-minute period. This report presents detailed 

procedures, field data, test results, and conclusions. The following table summarizes 

the results: 

Table 1 

Summary of Test Results 

North 1 Styrene (Ib/hr) 

East 2 Styrene (Ib/hr) 

Combined Styrene (Ib/hr) 

Opacity, % 

Run 1 

10.006 

6.680 

16.686 

0 

Run 2 

7.073 

8.731 

15.804 

0 

Run 3 

10.304 

9.517 

19.821 

0 

Average 

9.127 

8.309 

17.436 C^ 

0 

Although the methodology used for this testing is not new, the application is and is 

perhaps the first time it has been used in the State. The results appear to be 

significantly .higher than those thatcould be predicted by using AP42 calculations. 

Although the testing was done in strict adherence to the approved Protocol, it is 

possible that future sampling/testing procedures need to be re-evaluated. 

in 
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CERTIFICATION OF REPORT INTEGRITY 

Bison Engineering, Inc. certifies this report represents the emissions tested on 

August 26, 1993. Every effort was made to obtain accurate and representative data 

according to emission testing requirements of Idaho Permit to Construct 860-0035. 

The test team complied with the procedures specified in Title 40, Code of Federal 

Regulations (CFR), Part 60, Appendix A, Methods 1 through 3, and Method 9. 

(Methods revised through July 1, 1992, corrected at 57 FR 24550 [June 10, 1992)). 

Moisture content of the stack was determined using wet/dry bulb temperatures and 

psychrometric charts. The styrene sampling apparatus generally conformed to Method 

6, 40 CFR 60, Appendix A; and testing was accomplished in accordance with a protocol approved by the Idaho Department of Health and Welfare, based upon a 

modified NIOSH method 1501. 

Team Leader: Robert G. Richards 

Title: Staff Engineer 

Signature: 

Date: 

Reviewer: David L. Kinqhorn 

Title: Senior Project Engineer 

Signature: _ ,MfX ., •/t^ -

Date:

 J0Jf

J

9l 

IV 

4-
1.0 INTRODUCTION 

1.1 Purpose 

GEA Dynamic Fabricators (GEA) operates a fiberglass reinforced plastic (FRP) facility 

at Rathdrum, Idaho. 

Operators lay up various panel designs on molds and mandrels with woven roving, 

cloth, mat and chopped fiberglass strands as required. They then spray the lay up 

with polystyrene resin. Resin forms the material matrix and bonds the fibers together. 

After curing, the finished panels are used in cooling towers and corrosion-resistant 

pipe installations. 

In accordance with Section 4 of the Permit, GEA contracted Bison to submit a test 

method for approval by the State and conduct the testing as defined above. Xfaere are 

no approved methods_fQr_tfiSting_styrene in this application so a modification of 

NIOSH 1501 was submitted^andapproved. Energy Laboratories was selected to perform the absorber tube analysis and worked with Bison in designing the test. 

Additionally, in accordance with Section 4 of the Permit, visible emissions were 

observed during styrene testing. 

1.2 Emission Source Description 

The FRP building is sectioned into a spray booth (#1), a pipe winding area and pump 

room (#2), and a curing area (#3). Resin, gelcoat, catalyst and solvent are stored in 

a secondary concrete containment area under a canopy attached to the FRP building. 

When spraying operations are being conducted, the building is flooded with fresh air 

in order to meet the Occupational Safety and Health Administration standard for 

styrene. Fugitive styrene and particulate emissions develop from forming, curing, and 

handling of the products. In particular, spraying and curing operations produce styrene 

emissions. 

Two induced draft (ID) fans ventilate the work areas through filters to remove 

particulate and convey styrene fumes to two stacks. Three booths are used in the 

production process as noted above; booth 1 exclusively exhausts into stack 1 (north) 

and booths 2 and 3 exhaust into stack 2 (east). 

s-
P.7 

"~^ 1.3 Control Equipment Description 

j Styrene emissions are limited by the operational conditions and resin formulations. 

No additional controls are used. 

r! To reduce particulate matter emissions, the exhaust air is cleaned by a two-inch thick 

graduated density fiberglass-filter media which is incorporated into each booth wall 

vent. Very little particulate matter with a mean aerodynamic diameter less than 10 

micrometers is produced, and the removal efficiency of the filters is estimated to be 

80%. Therefore, no additional control equipment is necessary. 

1.4 Source Test Dates 

Bison personnel arrived at the site for setup on August 26, 1993. They tested both 

stacks on that day. Since the testing methodology is new, one absorber tube was 

sent to the laboratory that day for analysis. Preliminary data from the lab indicated the 

results were near those estimated by AP42 calculations. Because of this preliminary 

indication, the test crew and operating personnel felt the results were representative 

and deemed the test complete. 

1.5 Pollutants Tested 

The Pretest Protocol (Appendix A) details the test methods used and their revision 

dates. Additionally, contained in Appendix E is a copy of NIOSH Method 1501. 

Bison performed three valid compliance runs on each stack, each for fugitive styrene 

emissions, and visible emissions (Method 9) in accordance with Permit 860-0035. 

1.6 Personnel 

1.6.1 Bison Engineering. Inc. 

Bob Richards (lead engineer) managed the program, operated sample trains, analyzed 

data, and coordinated mobile lab operations. Richard Myracle assisted in operating the 

sampling system and performed as on-site technician. 

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r 

1.6.2 Dynamic Fabricators 

j ; John Krisman, Facility Manager, and Don Osburn, FRP Shop Manager, supervised the 

operation and gathered the operational data. The efficient manner in which they 

directed operations was greatly appreciated. 

i 

^=h 
P.9 

. > 

2.0 TEST RESULTS SUMMARY 

2.1 Emission Results 

This section discusses the results of the testing accomplished as described above. 

Appendix B contains Bison field data sheets. 

Idaho Permit to Construct 860-0035, Section 2, states "The combined emissions from 

the Stack No. 1 and No. 2 shall not exceed 8.1 pounds per hour as determined ... 

analysis. Annual styrene emissions shall not exceed 21.1 tons per year... operate(s)." 

Section 4.2 of the Permit states "Visible emissions shall be observed during the test 

using the methods in the ... Control." Table 2 summarizes the results of the.testing: 

Table 2 

Styrene and Visible Emissions 

Styrene North 1 (Ib/hr) 

Styrene East 2 (Ib/hr) 

Combined (Ib/hr) 

Opacity (%) 

Run 1 

10.006 

6.680 

16.686 

0 

::;f:

^Run.2'; .*. • 

7.073 

8.731 

15.804 

0 

Run 3 

10.304 

9.517 

19.821 

0 

Average 

9.127 

8.309 

17.436 

0 

2.2 Process Data 

Appendix C contains the field data sheets indicating the usages of each type of resin 

or gelcoat along with the production schedule during the test. Additionally, fugitive 

emissions are estimated using AP42 calculations. 

As indicated in John Krisman's letter, FRP production is a batch process and not a 

continuous one; therefore, close coordination was necessary in order to run a product 

mix that would most closely approximate the maximum production rate. As indicated, 

this goal was achieved. It seemed prudent at this point to emphasize the fact that 

production was scheduled to maximize fugitive styrene emissions and does not necessarily represent a normal operating schedule. 
P.10 

3.0 SAMPLING AND ANALYSIS 

3.1 Sample Location 

Appendix A, Pretest Protocol and Permit to Construct contain a schematic of the 

facility lay-out and the stacks with sampling port location. 

3.2 Sampling Procedures 

The Pretest Protocol (Appendix A) contains a schematic of the styrene sampling train. 

Appendix B contains the field data sheets used during the sampling. A' 16-point 

traverse was used for velocity/stack flow-rate calculations. A single centriodal point 

was used for styrene sampling. 

Operators performed a Method 2 velocity traverse during each styrene run to quantify 

cyclonic flow and determine stack flow. 

A certified observer logged Method 9 visible emissions from each stack for 12 minutes 

concurrently with each valid styrene run. 

3.3 Field Notes and Special Circumstances 

This section discusses sampling and analysis procedures which deviated from 

accepted test methods or the Protocol. The testing went smoothly, thanks to the 

organization of the facility personnel, and did not deviate from the approved Protocol. 

This facility is the first in the State of Idaho that has been tested for fugitive styrene 

emissions. Although the methodology is not new, the application is. Using the AP42 

handbook emission factor, the following emissions are estimated: 

Table 3 

AP42 Estiinated Emissions 

I 

j North 1 Styrene (Ib/hr) 

East 2 Styrene (Ib/hr) 

| Combined Styrene (Ib/hr) 

Run 1 

4.65 

3.44 

8.09 

Run 2 

4.08 

3.27 

7.35 

Run:3':;:f

:

/E' 

3.07 

5.25 

8.32 

Average 

3.93 

3.99 1 

7.92 

^ 

. * 

9 
P.11 

As can be seen, the actual fugitive styrene emissions are not in the range of the 

estimated values. Discussions with resin manufacturers indicate the result determined 

in this test are significantly higher than expected. Further investigation may be 

necessary to determine if sampling or laboratory procedures somehow allowed for 

errors in the testing. 

3.4 Data Reduction and Calculations 

Method 2 traverse data was entered into spreadsheets for calculations. Those 

calculations are contained in Appendix B. Additionally, the emission rate calculations 

are contained in the Appendix. 

Contained in Appendix D are the results of the analysis of the absorber tubes along 

with a blank. Included are calibration data and supporting information. 

Appendix E contains Nomenclature, Formulae, and Lab Methods. 
P.12 

4.0 QUALITY ASSURANCE 

Bison Engineering's practices conform to EPA Qualitv Assurance Handbook for Air 

Pollution Measurement Systems. Volume 3, EPA-600/4-77-0276; 1977 as amended. 

As noted, an absorber tube blank was used to verify concentrations at Energy 

Laboratories. 

Appendix F contains copies of calibration data for the sampling train. 

At Bison, data quality assurance procedures include independent review of data entry 

and calculations. 

I/ 
P.13 

APPENDIX A: PRETEST PROTOCOL/PERMIT TO 

CONSTRUCT #860-0035 

/z-
P.14 

I >mm & -

30 SOUTH E\WNG 

P.O. 80X1703 

HELEN\ MT S9624 

BISON 

ENGINEERING, INC. 

PHONE: 404-442-5768 

FAX: 406-449-6653 

July 23, 1993 

Ron Hill 

Division of Environmental Quality 

1410 North Hilton 

Statehouse Mail 

Boise, ID 83720-9000 

Re: Styrene Emissions Compliance Tests at GEA Dynamic Fabricators; 

Rathdrum, Idaho 

Dear Mr. Hill: 

GEA Dynamic Fabricators has engaged Bison Engineering to perform 

styrene emission compliance tests at their Rathdrum facility. 

I have been unable to find a suitable EPA reference method for this 

test. Bison has designed a test campaign which should give valid 

styrene emission data for this source. The attached Pretest 

Protocol describes the proposed test in detail. Please review it 

and call me if you have any questions or comments. 

Bison personnel will report to the site the afternoon of August 25, 

1993, for setup. Tests will commence the next day. 

If you have any questions, please contact me at (406) 442-5768. 

Sincerely, 

Robert G. Richards 

Lead Engineer 

Ene. 

c c : John Krisman 

13 
P.15 

1 

I 

SOURCE TEST PROTOCOL 

1.0 INTRODUCTION 

3 Corporate Address and Plant Location: 

GEA Dynamic Fabricators 

1735 West Highway 53 

Rathdrum, Idaho 83858 

(208) 773-1787 

Permit Number(s): 

Source and 

Test Summary: 

• 860-0035 (Feb. 5, 1993) 

Compliance tests on two stacks for styrene 

(C6H5CHCH2) emissions; concurrent visible emissions 

observations for information 

2.0 EMISSION SOURCE INFORMATION 

2. 1 Facility Description and Process Information 

GEA Dynamic Fabricators operates a fiberglass reinforced plastic (FRP) facility 

at Rathdrum, ID. 

Operators lay up various panel designs on molds and mandrels with woven 

roving, cloth, mat, and chopped fiberglass strand as required. They then spray 

the lay up with polystyrene resin. Resin forms the material matrix and bonds 

the fibers together. After curing, the finished panels are used in cooling towers 

and corrosion-resistant pipe installations. 

2.2 Emission Source Description 

See the Attachments for stack schematics. 

Fugitive styrene and particulate emissions develop from forming, curing, and 

handling. In particular, spraying and curing operations produce styrene 

emissions. Two ID fans ventilate the work area through filters to remove the 

particulate and convey styrene fumes to two roof stacks. 

Safety and Access. 

Yellow caution tape will alert plant personnel to overhead work if needed. GEA 

will supply suitable platforms or a scissors lift for stack port access. Personnel 

J4 
—* 

'1 

-*-

- a 

• -

3.0 

3.1 

3.2 

3.3 

P.16 

\ 

*T 

Safetv. Test Dersonnel will have the followinq safety equipment at hand: 

1. Hard hat. 

2. Full length pants, shirts, and/or coveralls. 

3. Full length work boots. 

4. Respirator with organic fume and HEPA cartridges. 

5. Hearing protection. 

6. Work gloves. 

7. Safety glasses with side shields. 

SOURCE TEST PROGRAM DESCRIPTION 

Testing Contractor 

Bison Engineering, Inc. 

P.O. Box 1703 

Helena, Montana 59624 

(406) 442-5768 FAX (406) 449-6653 

Project Manager: Bob Richards, Lead Engineer 

Personnel 

Bob Richards (lead engineer) will operate sample trains and reduce laboratory 

data. 

Dave Kinghorn (senior project engineer) will review reports and quality control 

procedures. 

John L. Krisman (facility manager) is the primary on-site contact. 

Energy Laboratories, Inc. (P.O. Box 30916; Billings, MT 59107-0916; (406) 

252-€23£) will analyze the styrene absorber tubes. 

C3^S* 

Test Program Objectives 

Idaho Permit to Construct #0860-0035 limits styrene emissions to 8.1 Ib/hr 

from both stacks combined. This Protocol specifies a test method and project 

campaign to quantify the styrene emissions. A certified observer will log visible 

emissions concurrent with styrene tests according to the Permit's Section 4 

"Monitoring Requirements." 

2 
P.17 

1 * 

1 

Test and Report Dates 

Bison personnel will arrive at the site August 25, 1993. Tests will commence 

the next day. The Compliance Test Report will be submitted within 30 days of 

the end of the test campaign. 

4.0 SOURCE TESTING PROCEDURES 

4.1 Equipment Description 

See Attachments for a sample train schematic. 

4.2 Test Methods 

Bison will sample the sources for actual flow, corrected flow, composition, moisture, 

styrene and visible emissions. Styrene content (mg/m3 of stack gas) will be correlated 

with EPA reference methods for stack velocity and flow to arrive at Ib/hr emission 

rate. Test personnel will employ the following Title 40 CFR 60, Appendix A (EPA 

reference) methods for stack flow and visible emissions: 

Sampling Location and Traverse Points: Method 1, "Sample and Velocity 

Traverses for Stationary Sources" 

Velocity and Volume: Method 2, "Determination of Stack Gas Velocity and 

Volumetric Flow Rate (Type S Pitot Tube)" 

Composition: Method 3, "Gas Analysis for Carbon Dioxide, Oxygen, Excess 

Air, and Dry Molecular Weight" 

Visible Emissions: Method 9 "Visual Determination of the Opacity of Emissions 

from Stationary Sources" 

A certified observer will record visible emissions for (one) 12-minute period 

concurrently with each styrene sampling run. If weather conditions prohibit 

suitable observations, they will be completed as soon as practicable following 

the styrene test runs. 

All the methods above are revised through July 1, 1991; corrected at 57 FR 

24550, June 10, 1992. 

Research has not revealed any reference methods for styrene emissions measurement 

from stationary sources. Bison proposes the following method to obtain valid data. 

lb 
P.18 

•1 

Moisture Content: 

Stack gas consists of atmospheric air pulled from the workrooms. High relative 

humidity affects the "breakthrough" capacity ofthe absorber tubes. Volumetric 

water content, however, will not likely exceed 1 % (vol) even at 100% relative 

humidity. 

i 

Because the relative humidity value is an important parameter for the styrene 

test, the test operator will obtain wet bulb/dry bulb temperatures prior to each 

test run. He will derive relative humidity and volume % water content from 

psychrometric charts. 

Stvrene Emissions: 

General Considerations 

The Permit imposes a styrene emission limit of 8.1 Ib/hr from both stacks 

combined. If we assume the facility meets the limit, and emissions are evenly 

divided between the two stacks; each stack may emit up to 4.05 lb/hr (1837 

g/hr). 

The Permit quotes stack velocity at 4565 feet/min (1385 m/min) with a-24" 

(0.6096 m) diameter. Stack area is 0.292 m2. Stack flow, therefore, is about 

404 m3/min or 24,270 m3/hr. 

At the permit limit, we expect about 75.7 mg/m3 of styrene in the stack gas 

(approximately 18.7 ppmv). 

Proposed Styrene Test Method 

Bison proposes a modification of NIOSH method 1501 (issued 2/15/84). In that 

method, a personal sampling pump draws breathing zone air through a doublesection coconut charcoal absorber tube. The charcoal absorbs aromatic 

hydrocarbons for later analysis. 

After sampling, a contract lab desorbs the two sections with carbon disulfide. 

Gas chromatography quantifies styrene content in the "front" section. As a 

quality check, any styrene numbers from the "back" section show 

breakthrough. 

The styrene content divided by the actual gas volume pulled through the tube 

yields styrene per unit volume. Correlation with actual stack gas volume 

flowrate per hour during the sample run provides the styrene emission rate. 

Proposed Sampling Method 

The proposed sample pump and dry gas metering system conform to Title 40 

CFR 60 Appendix A, Method 6 (Determination of Sulfur Dioxide Emissions from 

Stationary Sources) Section 2 requirements for apparatus. The probe, drying 

tt 
P.19 

tube, and absorber tube 

appropriate tubing. 

will be plumbed into the metering system with 

Bison proposes that each compliance test run last for one (1) hour. The two 

stacks will be sampled simultaneously. Sampling rate will be 1/2 litre per 

minute (l/min), for a total sample volume of 30 litres. If each stack emits its 

permitted 75.68 mg/m3 (75.68 //g/l), each sample will contain 2.270 mg of 

styrene. This will provide a representative sample from each stack. 

Immediately prior to each test run, test operators will perform Method 2 

velocity traverses to quantify stack flow.. &*w-%* -

The test operators will then install absorber tubes in the sample trains, set the 

sample flow rate, and insert the probe in the stack. Both trains will be started 

and stopped simultaneously. During each run, operators will record dry gas 

meter volume, and meter temperatures every 5 minutes. 

Testers may opt to use a critical orifice selected for 1/2 l/min flow as described 

in the "Alternative Methods" section of Method 6. In this event, the critical 

orifice will be calibrated and used according to Method 6, Section 7.2. 

Absorber Tube Capacity 

Method 1501 employs a "100/50" absorber tube. This means the front section 

contains 100 mg of charcoal, the back section 50 mg. The absorber tube 

vendor (SKC, Inc.) and the laboratory (Energy Labs) agree that, at these 

concentrations, even small sample volumes may break through. 

The tests will employ "400/200" (SKC Cat. # 226-09) absorber tubes to 

P-n tthi , \^^ ) 

I carbon disulfide. For the larger 

I be needed. This will change the 

ube sample. This level represents 

Detection Umits and Interferences 

Method 1501 requires desorbtion w( 

tubes, Bill Brown of Energy Labs feel 

minimum detection limit to 20 pg styr 

less than 1 % of the theoretical sample (T.27 mg), and is reasonable. 

High relative humidity is a potential sampling interferant. Moisture 

contamination reduces absorber capacity. A drying tube will be installed ahead 

of the absorber tube to prevent this. 

The most significant potential analysis interferants are xylene isomers, 

particularly ortho-xylene. The facility manager indicated that GEA uses no 

xylene-based solvents. Most solvents and cleaners are water-based with some 

acetone used for spray gun cleanup. Acetone should elute quickly in the GC 

column; any acetone peaks should occur well before the styrene analyte peak. 

rt 
P.20 

•m 

4.3 Analytical Methods 

Molecular Weight. Test personnel will sample stack gas with a bulb pump and 

analyze with Orsat or Fyrite instruments as appropriate. Psychrometric charts 

provide moisture data from wet bulb/dry bulb temperatures. 

Stack Gas and Sample Volume. Method 2 traverses provide flow data. Stack 

gas and sample volumes will be reported as actual m3 (f3) and dry standard m3 

(dscf). 

Stvrene Content. Energy Labs will desorb the tubes and analyze for styrene 

according to NIOSH Method 1501 via gas chromatography (FID detector). 

Styrene content will be correlated with actual stack flow to arrive- at a g/hr 

(Ib/hr) emission rate. 

General. Data reduction methods follow those outlined in Title 40 CFR 60,-

Appendix A and will be conducted at Bison Engineering (30 S. Ewing, Helena, 

MT). 

"«, 

4.4 Production Data 

Plant operators will record the amount and type of resins and gelcoat used 

during styrene test runs 

5.0 QUALITY ASSURANCE PROCEDURES 

Bison Engineering's test, laboratory, reporting, and quality assurance 

procedures conform to the requirements specified in the Quality Assurance 

Handbook for Air Pollution Measurement Systems. Vol. III. Stationary Source 

Specific Methods published by the U.S. Environmental Protection Agency in 

August, 1977 as revised and amended (cat. # EPA-600/4-77-027b). 

Blanks. Bison will document one field blank to verify handling procedures. The 

operator will open the tube, install it in the sampling train, adjust the train for 

roper flow, and return the tube to the carrying container. The laboratory will 

analyze the blank along with the working samples. 

Sample Handling Protocols 

Operators complete and initial field data sheets, chart records, etc. before 

leaving the site. 

Sample Chain-of-Custody forms are attached. 

i<? 
P.21 

- I * 

• 5.2 Data VaUdation 

'• t 

- In general, the Project Manager is responsible for data validation. When one 

j person enters data or calculations into a form or spreadsheet, a different person 

reviews it. Reviewers perform cross-checks and trial calculations as 

.1 appropriate. 

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BISON ENGINEERING INC. - CHAIN OF CUSTODY RECORD 

Page ol 

to 

U4 

Client Description 

Project No. 

Total No. of Samples 

Date Sample I.D. 

Date 

Company Name/Address 

Received by 

Method 

• 

Shipping No. 

Type of Sample 

Date Sample I.D. 

Date 

Company Name/Address 

Received by 

Samplers' Signature 

Analytical Method Requested 

Method 

Shipping No. 

Date Sample I.D. 

Date 

Company Name/Address 

Received by 

Method 

J 

; 

Shipping No. 

Rev? 7/93 
P.25 

U 

I I 

JUN-22-1993 12:36 FROM DYNAMIC FABRICATORS TO 14064496653 P.02 

OAMO OEPAATMENT 

Of HEALTH ANO WEUME 

OIVISION OF 

jjfc ENVIRONMENTAL QUALITY 

1410 Nonh Hilua StatihouM M**. Boin. IO 8372O-90C0. (208) 334-OSM •Coca 0. Anew, Go»«.-rr 

fi •J J K-<cc 

February 5, 1993 

CERTIFIED MAIL # Pill 446 599 

John L. Krisman 

Facility Manager 

GEA/Thermal-Dynamic Towers, Inc. 

12600 W. Colfax Avenue 

Suite C500 

Lakewood, CO 80215 

RE: Permit to Construct #860-00035 

GEA/Thermal-Dynamic (Rathdrum) — P-921204 (Modification to 

Fiberglass Manufacturing Process) 

Dear Mr. Krisman: 

On December 15, 1992, DEQ received your Permit to Construct 

application for a modification to a fiberglass manufacturing 

process currently operating in Rathdrum, Idaho. The application 

was declared complete on January 11, 1993. Based on that 

application, we now find that the proposed source meets the 

provisions of IDAPA 16.01.01012 of the Rules and Regulations for 

the Control of Air Pollution in Idaho. Therefore, enclosed is your 

Permit to Construct #860-00035, which supersedes the original 

Permit to Construct #0860-0035 issued January 30, 1990. 

Please pay particular attention to the reporting requirements 

contained in Paragraph E of the General Provision Section of the 

permit. This information is needed to properly track the progress 

of the project. Please refer to the appropriate permit number when 

submitting reports required in the Reporting Requirements Section 

of the Permit. 

You, as well as any other entity, may have the right to appeal this 

final agency action pursuant to the Idaho Department of Health and 

Welfare Rules and Regulations, Title 5, Chapter 3, "Rules Governing 

Contested Case Proceedings and Declaratory Rulings,11 by filing a 

petition with the Hearing Coordinator, Department of Health and 

Welfare, Administrative Procedures Section, 450 West state Street -

10th Floor, Boise, Idaho 83720-5450, within (30) thirty days of 

the date of this decision. 

i£ 
P.26 

JUN-22-1993 12:37 FRCT DYNAMIC FABRICATORS TO 14064496653 P.03 

•s 

John L. Krisman 

February 5, 1993 

Page 2 

If you have any questions regarding the terms or conditions of the 

enclosed permit, please contact Martin Bauer, Bureau Chief, 

Construction Permits Bureau, Permits and Enforcement, DEQ, at 

(208) 334-5898. 

Sincerely, 

orville D. Green 

Assistant Administrator 

Permits ahd Enforcement 

ODG/AR/tdt.ltr 

Enclosure 

cc: G. Burr, NIRO 

D. Cole, EPA-IOO 

T. Harman, NIRO 

J. Markley, City Engineer 

A. Ray 

P. Rayne 

Source File 

File Manual 

COF 1.1, 

2£T 
P.27 

3 

JUN-22-1993 12:38 FROM DYNAMIC FABRICATORS TO 14064496653 

Page 

P.i)4 

1_ Of 

STATE OF IDAHO 

PERMIT SO CONSTRUCT AN 

AIR POLLUTION EMITTING SOURCE 

PERMIT NUMBER 

AQCR CLASS 8IC 

Emu cm 13 io 17»i 

ZONE UTM COORDINATE (ka) 

ECO ISToTT}. |T) 15 12 19 Ib I 0 

1. PERMITTEE 

GEA/Thermal-Dynamic Towers, Inc. 

2. PROJBCT 

Fiberglass fabrication facility 

3. MAILING ADDRESS 

12600 W. Colfax Avenue, Suite CS00 

4. SITE LOCATION COUNTS 

Kootenai 

CITX 

Lakewood 

NO. OF FULL TIME EMPLOZEBS 

20 to 60 

PERSON TO CONTACT 

John L. Krisman 

STATE 

CO 

ZIP CODE 

80215 

PROPERTY AREA AT SITE (Acreage) 

10 acres 

TITLE 

Facility Manager 

TELEPHONE NUMBER 

(208) 773-1787 

EXACT PLANT LOCATION 

1735 W. Highway 53, Rathdrum, Idaho 83858 

GENERAL NATURE OF BUSINESS AND KINDS OF PRODUCTS 

Fiberglass reinforced plastic panel and pipe production 

GENERAL CONDITIONS 

This pernit is issued according to the Rules and Regulations for the Control 

of M r Polltrfciou in Idaho, Section 16.01.01012, and pertains only to ena.sflions 

of air contaminants which are regulated by the State of Idaho and to the sources 

specifically allowed to be constructed by this permit. 

This permit (a)' does not affect the title of the premises upon which the 

equipment is to be located, (b) does not release the permittee from any 

liability for any loss due to damage to person or property caused by, resulting 

from, or arising out of the design, installation, maintenance, or operation 

of the proposed equipment, (c) does not release the permittee from compliance 

with other applicable federal, state, tribal or local laws, regulations, or 

ordinances, (d) in no manner implies or suggests that the Department of Health 

and Welfare, or its officers, agents, or employees, assumes any liability, 

directly or indirectly, for any loss due to damage to person or property causedby, resulting from, or arising out of design, installation, maintenance, or 

operation of the proposed equipment. 

This permit is not transferable to another person, place, piece or set of 

equipment. This permit will expire if construction has not begun within two years 

of its issue date or if construction is suspended for one year. 

THIS PERMIT HAS BEEN GRANTED ON THB BASIS OF DESIGN INFORMATION PRESENTED WITH 

ITS APPLICATION. CHANGES OF DESIGN OR EQUIPHENT THAT RESULT IN ANY CHANCE IN 

THB NATURE OR AMOUNT OF EMISSIONS MUST BE APPROVED IN ADVANCE BY THE DEPARTMENT. 

2d, 
P.28 

JUN-22-1993 12:39 FROM DYNAMIC FABRICATORS TO 14064496653 P.05 

PERMIT TO CONSTRUCT. 

PERMITTEE, PROJECT, AND LOCATION 

GEA/Thermal-Dynamic Towers 

Rathdrum, Idaho 

SOURCE 

Polyester Resin Operation 

Page 2 of 7 

PERMI T NUMBE R 

0 8 6 0 - 0 0 3 5 

1. SOURCE DESCRIPTION 

1.1 process Description. The facility manufactures, fiberglass 

reinforced plastic (FRP) panel segments which function as external 

covering for cooling tower framework. Additionally, large diameter 

FRP cooling tower pipe and corrosive-resistant pipe liners are 

produced. 

The fiberglassing building is sectioned into a spray booth, a pipe 

winding area, a pump room, and a curing area. Resins, gelcoat, 

catalyst and solvent are stored in a secondary concrete containment 

area under a canopy attached to the fiberglassing building. 

When spraying operations are being conducted, the building is 

flooded with fresh air in order to meet the Occupational Safety and 

Health Administration (OSHA) workplace standard for styrene. 

Styrene emissions are due to resin overspray and the FRP curing 

process. The contaminated air is exhausted through two (2) wail 

vents and sent up separate stacks. 

1.2 control Description. Styrene emissions are limited by the 

operational conditions specified in Section 3 of this permit. No 

add-on controls are provided. 

To reduce particulate matter (PM) emissions, the air is cleaned by 

" a two (2) inch thick graduated density fiberglass filter media 

which is incorporated into each wall vent. The removal efficiency 

is estimated to be eighty percent (80%) for PM. Very little 

particulate matter with a mean aerodynamic diameter less than 10 

micrometers (PM-10) is produced. Therefore, PM-10 control 

equipment is not required. 

1.3 Stack Specifications. Stacks listed shall meet the following 

specifications. Gas velocities are denoted in feet per minute 

(FPM): 

1.3.1 Stack No. l: 28 feet height, 2 feet diameter and/4545/ 

FPM; \^_y 

<P\ / 

ASSISTANT ADMINISTRATOR 

DATE: February 5, 1-9*93 

-7^-
P.29 

JUN-22-15S3 12=40 FROM DYNAMIC FABRICATORS TO 14064496653 P.K 

Page o* __L 

PERMIT TO CONSTRUCT 

PERMITTEE, PROJECT, AND LOCATION 

GEA/Thermal-Dynamic Towers 

Rathdrum, Idaho 

PERMI T NUNBE R 

0 8 6 0 - 0 

SOURCE 

Polyester Resin Operation 

1.3.2 Stack No. 

FPM. 

2: 28 feet height, 2 feet diameter and 4545 

2. EMISSION LIMITS 

2.1 The combined styrene emissions from Stack No. 1 and Stack No. 2 

shall not exceed 8.1 pounds per hour as determined by the 

Department's emission estimation methods used in this permit 

analysis. Annual styrene emissions shall not exceed 21.1 tons per 

year, as determined by multiplying the allowable pound per hour 

emission rate by the actual hours per year that the process(es) 

which vent to these stacks operate(s). 

2.2 Volatile organic compound emissions (other than styrene) from Stack 

No. 1 and Stack No. 2 combined shall not exceed 0.65 pounds per 

hour as determined by the Department's emission estimation methods 

used in this permit analysis. Annual volatile organic compound 

emissions (other than styrene) shall not exceed 1.69 tons per year, 

as determined by multiplying the allowable pound per hour emission 

rate by the actual hours per year that the process (es) which vent 

to these stacks operate(s). 

2.3 Emissions of particulate matter (PM) from Stack No. 1 and Stack No. 

2 combined shall not exceed 2.19 pounds per hour as determined by 

the Department's emission estimation methods used in this permit 

analysis. Annual PM emissions shall not exceed 5.68 tons per year 

as determined by multiplying the allowable pound per hour emission 

rate by the actual hours per year that the process (es) which vent 

to these stacks operate(s). 

2.4 Emissions of particulate matter with a mean aerodynamic diameter 

less than or egual to 10 micrometers (PM-10) (see IDAPA 

16.01.01003,73 of the Rules and Regulations for the Control of Air 

Pollution in Idaho) from Stack No. 1 and Stack No. 2 combined shall 

not exceed 2.19 pounds per hour as determined by the Department's 

emission estimation methods used in this permit analysis. Annual 

PM-10 emissions shall not exceed 5.68 tons per year, as deterained 

by multiplying the allowable pound per hour emission rate by the 

actual hours per year that the process (es) which vent to these 

stacks operate(s). 

JK 

ASSISTANT ADMINISTRATOR 

PERMITS AND ENFORCEMENT 

DAZE: February S,-1993 

-2&. 
P.30 

JLM-22-1993 12M1 FROM DYNAMIC FABRICATORS TO 14064496653 P.07 

PERMIT TO CONSTRUCT 

PERMITTEE, PROJECT, AND LOCATION 

GEA/Thermal-Dynamic Towers 

Rathdrum, Idaho 

SOURCE 

Polyester Resin Operation 

Page 4 o f 7 

PERMI T NUMBE R 

0 8 6 0 0 0 3 5 

3. OPERATING REQUIREMENTS 

3.1 The permittee shall use polyester resins with a monomer content of 

no more than thirty-five percent (35%) by weight. This provision 

shall not apply to the use of gelcoat, resin used for mold 

construction and corrosion-resistant resin. 

3.2 Excluding the gelcoat and specialty resins, ninety percent (90%)'by 

weight of all polyester resins used by the permittee shall have a 

styrene monomer content of no more than thirty-five percent (35%) 

by weight. 

3.3 The permittee shall use a gelcoat with a styrene monomer content of 

no more than forty-three percent (43%) by weight. 

3.4 The permittee shall use a soap based cleaner, ND-165 and acetone as 

the cleaning solvent. The amount of acetone is restricted to 2 

gallons per day. 

3.5 Airless spray gums shall be used 

including gelcoat application. 

for all spray-up processes 

3.6 Neither stack No. 1 nor Stack No. 2 shall be equipped with a rain 

cap or any other obstruction that would result in the downward 

deflection of the exhaust gas stream. 

3.7 The permittee shall at all times keep all exterior doors and/or 

windows of the building used for fiberglassing operations tightly 

closed except for the explicit purpose of moving necessary 

equipment, materials or personnel into or out of the building. 

3.8 The permittee shall use closed containers for the disposal -of all 

gelcoat, resin, catalyst and cleaning materials in such a manner as 

to effectively control styrene and VOC emissions to the surrounding 

air. 

3.9 The permittee shall at no time allow containers of gelcoat, resin, 

catalyst or cleaning materials to be open to the atmosphere other 

than to transfer material to or from the container or to insert a 

pump. This shall apply to full, partially full and empty 

AL 

ASSISTANT ADMINISTRATOR 

DATE: February 5, 1*953 

29 
. „ „ P.31_ 

JUN-22-1993 12^42 FROM DYNAMIC FABRICATORS TO 14064496653 P.&3 

P a9° - S of 7 

PERMIT TO CONSTRUCT 

PERMI T NUMBE R 

PERMITTEE, PROJECT, AND LOCATION 

GEA/Thermal-Dynamic Towers 

Rathdrum, Idaho 

0 8 6 0 - 0 0 3 S 

SOURCE 

Polyester Resin Operation 

containers. 

3.10 Resins and gelcoat shall be stored out of direct sunlight. 

3.11 Resins, gelcoat, fiberglass and catalyst are restricted to a 

maximum usage as follows in any calendar year, as per applicant's 

submittal: 

Resins 720,000 pounds per year 

Gelcoat 103,000 pounds per year 

Fiberglass 400,000 pounds per year 

Catalyst 17,500 pounds per year 

4. MONITORING REQUIREMENTS 

4.1 The permittee shall submit, in writing, the proposed test methods 

for the initial performance test to measure styrene emissions from 

each of the stacks (Stack Nos. 1 and 2). The permittae shall 

receive Department approval of the proposed test methods prior to 

the scheduling of such testing. 

4.2 The permittee shall conduct an initial performance test to measure 

styrene emissions from each of the stacks (Stack Nos. l and 2) in 

accordance with DEQ's "Procedures Manual for Air Pollution Control" 

and General Provision F of this permit. Visible emissions shall be 

observed during the test using the methods in the DEQ's "Procedures 

Manual for Air Pollution Control." 

4.2.1 During the performance test, the following data shall be 

recorded: amount of resins and gelcoat used (i.e., pounds 

per hour) and the type of gelcoat and resins used. 

4.3 Performance tests shall be conducted for particulate emissions if 

the visible emissions exceed twenty (20) percent opacity for more 

than three (3) minutes in any sixty minute period from either of 

the Stack Nos. 1 or 2. The tests shall be conducted while the 

operation is performed at maximum capacity. 

4.3.1 During the performance test, the following data shall be 

recorded: amount of resins, gelcoat, catalyst and 

ASSISTANT ADMINISTRATOR 

PERMITS AND ENFORCEMENT 

DATE: Februar y 5 , ±993 

36 
P.32 

JUN-22-1993 12:42 FRC DYNAMIC FABRICATORS TO 14064496653 P.Qg 

Page of T 

PERMIT TO CONSTRUCT 

PERMITTEE, PROJECT, AND LOCATION 

GEA/Thermal-Dynamie Towers 

Rathdrum, Idaho 

PERMI T NUMBE R 

0 8 6 0 - 0 0 3 5 

SOURCE 

Polyester Resin Operation 

fiberglass used and the type of resins and gelcoat used. 

5. REPORTING REQUIREMENTS 

5.1 The permittee shall submit a performance test report required in 

Sections 4.2 and 4.3 of this permit. All information shall be 

submitted to the Department within thirty (30) days of the date on 

which the. performance tests were conducted. 

5.2 The permittee shall maintain weekly records on site for the most 

recent two (2) year period. Access to these records shall be 

granted to Department representatives upon request. The records 

shall contain the following: 

5.2.1 The manufacturers' names and the amounts used of gelcoat, 

resins, catalyst and cleaning solvent. 

5.2.2 The weight percent of styrene monomer in the gelcoat and 

resins used. 

5.2.3 The number of hours the facility operated. 

AL 

ASSISTANT ADSINISTRATOR 

PERMITS AND ENFORCEMENT 

DATE: •'Februar y 5 , 1993 

&\ 
GEA/THERMAL DYNAMIC TOWERS 

1992 STYRENE USAGE REPORT 

CTURERNAME 

i)CT 

PASHLAND 

P RHCHOLO 

•1' ASHLAND 

•Q ASHLAND 

•O REICHOLD 

l» DION 

/NLDOW . 

LG ASHLAND 

n.a REICHOLD 

•AfGYCOOK 

ATGYREFCOA 

\T OP COOK 

VTOPREFCOA 

•UTLGCOOK 

PERCENT 

•STYRENE 

35% 

35% 

45% 

•48% 

45% 

45% 

45% 

45% 

35% 

45% 

35% 

35% ' 

35% 

35% 

45% 

MT 50 NORAC 

'•oT 30 NORAC • 

1 If NE CHLORIDE 

'IF. GREAT WESTERN 

•n OF HOURS OF OPERATION 

. JAN 

USAGE 

20360 

0 

0 

4S00 

0 

0 

0 

0 

0 

0 

4400 

0 

0 

0 

0 

280 

32 

100 

0 

173 

FEB 

USAGE 

0 

0 

0 

21500 

0 

0 

0 

0 

0 

0 

Z7S0 

0 

0 

0 

46 

960 

0 

210 

0 

347 

MAR 

USAGE 

40580 

0 

0 

16000 

0 

970 

15000 

2700 

0 

0 

2750 

0 

0 

2222 

46 

704 

0 

310 

0 

520 

APR 

USAGE 

0 

0 

0 

5500 

0 

0 

45300 

0 

0 

0 

500 

0 

0 

6000 

0 

192 

460 

0 

205 

520 

MAY 

USAGE 

0 

0 

0 

9500 

0 

1940 

45300 

0 

0 

0 

6600 

0 

0 

0 

46 

352 

064 

0 

2B5 

520 

JUN 

USAGE 

40840 

2490 

0 

11000 

1922 

2910 

0 

0 

0 

0 

8800 

0 

0 

0 

0 

384 

608 

0 

285 

520 

JUL 

USAGE 

20480 

2500 

0 

4000 

0 

6303 

0 

0 

485 

0 

6050 

0 

0 

0 

109 

176 

672 

0 

285 

520 

AUG 

USAGE 

40520 

0 

4500 

955 

0 

0 

0 

0 

0 

300 

3850 

0 

0 

0 

92 

288 

640 

0 

286 

520 

SEPT 

USAGE 

40840 

0 

0 

2000 

0 

5820 

0 

0 

0 

300 

9350 

0 

0 

0 

94 

224 

9S2 

0 

28S 

520 

OCT 

USAGE 

0 

40960 

0 

1000 

0 

O 

0 

0 

0 

0 

7150 

0 

0 

0 

102 

320 

960 

0 

190 

347 

NOV 

USAGE 

0 

42000 

0 

4410 

0 

7760 

0 

0 

0 

300 

7700 

Q 

0 

0 

0 

1248 

320 

0 

100 

347 

OEC 

USAGE 

0 

11332 

0 

. 0 

0 

0 

0 

0 

0 

0 

0 

2616 

0 

0 

0 

0 

0 

0 

95 

173 

TOTAL 

USAGE 

203620 

99282 

4500 

80366 

1922 

2S706 

106600 

2700 

465 

900 

59900 

2616 

0 

6222 

625 

5136 

5566 

620 

2185 

5027 

ri I3INLB9 LEGEND: GENERAL PURPOSE - GP 

ISOTHAJLIC - ISO 

FIRE FIETARDANT - F/R 

VINYL E3TER-VNL 

TOOLING - TLG 

GREY GELCOAT-GY 

0PTI0NALCOLOR = OP 

1 

to 

10 

8 

8 

u 

ti. 

•0 

co 

co 
P.34 

APPENDIX B: FIELD DATA/CALCULATIONS 

.3*> 
P.35 

FILEVELVOL 

GAS VELOCITY AND VOLUME 

GEA Fabricator! [LOCATION Rathdrum, Ig STACK ID TSZ 

tor. 0930 |i 

dare, ENTER 

TIME OPERATOR RGR IDIA, IN. 

m FT AREA Eta REtf. BUdK 

24 

Altitude 

Barom. Read 

02% 

WetBlbTmp 

2290 

30 32 

21.0 

53.6 

Alt. Corr 

Pbar.sU 

C02% 

EstH20% 

—nr 27.91 

0.0 

03 

Amb. Temp 

P»,InH20 

m% 

Wet Mole Wt 

Tnr-"" •0.7 

79.0 

28.76 

ARE A • — 

Pa, Abi . 

Dry Mol Wt 

Pitot Cp 

3.14 

27.86 

2834 

0.840 

NOTE: INSERT OR DELETE ROWS FOR SAMPLING POINTS 

fRuVW 

3AI 

A2 

A3 

A.4 

A5 

A6 

A7 

A8 

31 

32 

33 

34 

35 

36 

B7 

38 

BECTAT— 

0.62 

0.92 

1.00 

0.9S 

1.30 

1.20 

1.10 

1.00 

0.82 

0.82 

033 

0.94 

1.10 

1.10 

1.10 

1.00 

TSTACK 

77 

77 

77 

77 

79 

81 

79 

79 

79 

79 

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77 

79 

75 

75 

45 

so 

10 

0 

20 

20 

20 

25 

20 

30 

30 

20 

20 

30 

25 

30 

NOTE; Enue blank 

Dau points OR Insert 

is req'd in ©Sqrt 

array at L16 . 

AVG DELTA P 

MNSQRT DP 

AVG TEMP STACK 

AVG T STACK. ABS 

LOW 

0.9976 

77.9 

537.9 

U.1 

(WB/DBDELT 

•STACK VEL, F/SEC 

FLOW RATE, FH/MIN 

FLOW DSCF/MIN 

FLOWDSCF/HR 

24.3 

58.70 

11100 

10100 

606000 

ACFM 

lALTCOR 

ANCLE 

CDIOX 

CP 

DIA 

DSCFM 

MNSQRT 

MNSQRT 

MNSQRT 

MOLDRY 

MOLWET 

G35 

D9 

E16-E31 

H9 

Dll 

H12 

H5 

G36 

M32 

L32 

N32 

HU 

F12 

NITROGE Fil 

OXYGEN 

PABS 

PBAR 

PSTATIC 

PSTATIO 

TS 

TSABS 

VELSTK 

WATER 

WBULB 

TSABS 

VELSTK 

WATER 

WBULB 

BU 

H10 

BIO 

no 

D10 

D36 

D37 

034 

D12 

B12 

D33 

G30 

D12 

B12 

3 1+ 
P.36 

Form #M2-01 

* 

GAS VELOCITY AND VOLUME DATA FORM 

Plant &£k 

Dato *(u hi 1 T c ft. - **\ 

Loutio mi u l/Jlr^-. 

Run No. W> 

Stack ID No. •c/ M 

Stack Dimension 

Altitude •VStifo-mmmZ-f 0 AU. Corf, '!£&£?•' V ' Ambient Temp. 3. £ C. 

Barometric Reading 1,01^ 2-

Local Barometric Pretture l^"^-. ^ f 

Stack Static Pressure -.r7 

Molecular Weight •*" 2-g , g> y 

Method g^f-?W<^ 

Pitot C, g~rV 

•" Traverse > 

- % ^ ' r V \ 

?'«• Point '<••, 

^Number.'' 

' 4 * " , 1 

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f\ru 

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/VS /U 

A n 

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4 

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£ r' 

2 

!,\ -? * -: V -^' ; £&"<* -V^V^F*td Data;- dt'l*:/^:^^<w^.v V 

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<.*tt 

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i.r 

1.3 

l.X 

1-OfT 

C % Stack -*•; 

" VJe'mp.^ v \ ;• 

*• *<•' • ^' S > -*., 1 * >* * 

Average Ap, 

Mean Sqrt Ap, 

- 1 N '*

 5 N •£ ,\Cyclonic Flow betermfnatioaN.V/V V" " - A 

~ ' E> -Reference ^^H" ^ 

• • 

j . 

Average 

Stack 

Temp. 

• 

" - • 

Average Angle (o)' 

' Average of a must be <10» to be acceptable. 

P.ev. 6/92 

ZS 
P.37 

Form IM1-01 

TRAVERSE POINT LOCATIONS, CIRCULAR STACKS 

Plant &-&$- Qyv^^y-l.'lC' F«Lr'-c <i fo/is 

D«f g/2-fXf ? By K(hR 

Sampling^Locat/n &dS T~j iV-ORTH C'.'• JmVnHtaf) 

Inside of Far Wall to Outside of Port (distance, X) ityrf 

Port Depth (distance. Y) rV/>4 

Stack LD. (distance X • distance Y) 

Dist. to upstream disturbance 

Mn. If) ' ?/i,to.am6t.n "V 5 . I 

Z,<f'f 

: 

Dist. to downstream disturbance , 

ft/in. /V/ft •* Diametert $"& 

No. of Traverse Points Roq'd: / / Total g Per Port 

T^ 

X 

• 

Y 

I 

t 

-^~ \ 

llY . 

ZS J 

! 

Port 

SCHEMATIC OF SAMPLING LOCATION 

1 

Traverse 

Point 

Number 

( 

2-

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V 

c 

/T 

^ 

£ 

I;jj£i 

Percent of 

Stack 

I.D. 

) \ Z. 

IO.$-

i?.*f 

•?2m.$ 

£ * ; 

* # . / 

z"?.<r 

fC^ 

3 

Stack 

I.D. 

Inches 

2-/* * 

/ 7 

/ 

/ 

/ 

_ i i / 

/ 

t 

. 

4 

Product of 

Columns 2 and 3 

(to nearest Va In.) 

V* 

*'/ , 

v% 

?*v 

It'/-* 

n*ys 

2-/'/^ 

?-3 'y<v 

! 

5 

Distance 

Y 

4 

/ 

' / 

/ 

A—. 

4 / 

U 

6 

Traverse Point Location 

from Outside of Port 

(sum of columns 4 and 5) 

Vy 

*.'/* . 

</£# 

iy* 

n >y 

/f ^ 

21/ ^ 

2.3 > y 

/ • 

Notes: 

c ^ & 
Form IStyrenel Bo >J6T WftiTE A66W THIS LIME 

STYRENE FIELD DATA FORM 

.Sheet No. of. 

"a"t £<£./4-

Date &/ Z 6/4 3 I Operator tf ft] 

Location tf CL tf% ej-rysr^r. 

Run No. / Absorber Tube ItP/jO'Z. 

£» 

Stack ID A/~d%T Ji 

I 

Stack Dimension <L- </ ° 

Meter No. ~/Q HO 

Altitude W*^Jh3 

Barometric Reading 

Barometric Pres. 

Stack Static Pres. 

Alt. Corr. 

-<S>, 

-m&x-2-i 

3 2 _ 

2~>.7 / 

v/ 

V 

fl, N... 

V y 

Ambient Temp. 

WB Temo. 

DB TemD. 

Moisture Content 

.**\mS' 

N* 

2-V 

>r 

<v 

>r^ 

0.<K«Z 

NOTES: tfcUrY^ J^^H" 

hoooy 

Sampling 

Time 

(min.) 

-or 

51 

(0 

/<f 

Zso 

JL£L 

2°. 

UL 

a°-

isz. 

^ m . 

& ' 

hQ^_ 

,;*•£ 

Clock Time 

(24 hr.) 

Start 

to**-

JU 

mn 

\o---~iIQxi 

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iOi*>ff 

\l>13 

roil 

/0S6> 

(l'0\ 

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Ges Sample 

Volume (cO 

Start 

&%*zme<5iHc\-ci-T 

!5T?&f& 

-**-&&-& I S-& A 

-Q^£&Ls^-Ayfe 

x&rfL. 

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5£r&/~ 

j&jm& 

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Sample Flow Rata 

*?(,55-fr 

ms^A 

• 0{62-'2-S 

•gZrS&Jc QUS.-zgQU .t t 

0I73>*3D 

417*. 7* 

Ot8f ,£T 

OIXH-VO 

£>/U<60 

OlfOm-S' 

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w.ssrl. 

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Outlet Temp. 

O>0 ^. \ 

a j 

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y^zv.yv 

Rw. 7/03 
P.39 

FILEVELVOL 

GAS VELOCITY AND VOLUME 

GEA Fabricator* ILOCATION Rithdrum, nf STACK ID l.'Wth' 

apr. 0900 1 OPERATOR RGR " DIA. IN. 

M6TE: EHM sflk PT AEEA P6ft RE6T. BUffl 

TIME 24 

Altitude 

Barom. Read 

02% 

WetBlbTmp 

-T55T 

3032 

21.0 

57.2 

Alt. Coir 

Pbar, ata 

C02% 

EatH20% 

—nr 

27.91 

0.0 

1.0 

Amb. Temp 

Ps,InH20 

N2% 

Wet Mole Wt 

apr 75 

•0.8 

79.0 

28.74 

AREA 

Pa, Abt 

Dry MolWt 

Pitot Cp 

3.14 

27 JU 

28.84 

0.840 

NOTE: INSERT OR DELETE ROWS FOR SAMPLING POINTS 

m',\rimww-wmM*KmfsAm,\i<]'* IAI 

IA4 

A5 

A6 

A7 

A8 

8 

92 

93 

94 

95 

36 

97 

ba 

0.74 

0.98 

0.76 

0.88 

130 

139 

1.40 

1.10 

0.90 

0.99 

1.10 

1.20 

1.60 

130 

1.10 

0.94 

77 

77 

77 

77 

77 

77 

75 

79 

77 

75 

75 

75 

75 

73 

75 

75 

45 

SO 

10 

0 

20 

20 

20 

25 

20 

30 

30 

20 

20 

30 

25 

30 

W6HS: Erase Uank 

Data points OR insert 

as req'd in @Sqrt 

array at L16 

AVG DELTA P 

MNSQRT D P 

AVG TEMP STACK 

AVG T STACK. ABS 

AVG ANGLE 

i.m 

1.0427 

76.0 

536.0 

24.7 

WB/DBDELT 

STACK VEL, F/SEC 

FLOW RATE, FI3/MIN 

FLOW DSCF/MIN 

FLOWDSCF/HR 

1 

IU 

6137 

11600-

10500 

630000 

LACFM 

LM-TCOR 

[ANGLE 

CDIOX 

CP 

bU 

DSCFM 

MNSQRT 

MNSQRT 

MNSQRT 

MOLDRY 

G35 

D9 

E16..E31 

H9 

Dll 

H12 

H5 

036 

M32 

132 

N32 

Hli 

MOLWET F12 

NITROGE Fil 

OXYGEN 

PABS 

PBAR 

PSTATIC 

PSTATIO 

TS 

TSABS 

VELSTK 

WATER 

WBULB 

TSABS 

VELSTK 

WATER 

WBULB 

BU 

H10 

B10 

no 

D10 

D36 

D37 

G34 

D12 

B12 

D33 

G30 

D12 

B12 
P.40 

Form *M2-0 1 


 

GAS VELOCITY AND VOLUME DATA FORM 

Plant Gtfr 

Date gfelf?'* Operator _ 

Location ' t 

vV*VH 

Run No. +Pr \ 

StaccklpNo. k ID No . / 

Stack Dimentio 

o-H V 

Altitude ^1-1,0 Alt. Corr. "2-. T V 

Barometric Reading "JO < 32— 

Local Barometric Pressure <^f-,^f( 

Stack Static Pressure *P>63r-,lS*

 -

Ambient Temp. *~>s-z-rc 

Molecular Weight n^7Xm-*i 

Method C^Tr^cd- , 

Pitot C, 0.2 ? 4 

SfTrayierit^l 

^Number^ 

.•rfSv<:-<::«'5;.VivS: 

%,i;ri&r&%s!i. 

A< 

•z. 

3 

1 

5" 

£ 

T 

f 

£ ( 

2. 

3 

4 

5" 

G 

*7 

* 

:;®SJ«SS??iye!oeity.«%?i.sssK4 

!S*iWWP 

. ^ 

.<rtf 

. U 

. * * 

/,3 

/.3 

t-H 

IA 

o^O 

• ?? 

/ ^ 

/.A N 

/.£ 

A 3 

A / 

•fi 

^*g?;5:-Stack:^:^w 

^

;

8x^#S|J":^^P*S. 

.&iJ&X&ffi£f\i&g*&$. 

^|l:^P*iS^E#:S| . 

£4 

63 

• / 3 

AH 

UH 

0 

WIT* 

CH 

6>H.s-

&H.SfaS~ 

zs-'S6>Sr£~ 

tsr 

6<r 

t>s~ 

Average Ap. 

Mean Sqrt Ap, 

/•omv 

^Wte f liff&Cyclonic Flow Deterrrunet on^*^»Mfe'5:^^:-

*p|g^lAp*i>j^^®ii^ 

^.5-

^-,5" 

-./ # 

n 

.3 

, 7 ^ 

. 7 

./< / 

-.r 

-.£ -

• * ? -, £ 

•^-.- 5* 

I.O 

/.& 

.7 

.tf 

Average 

Stack 

Temp. 

j&sxss* Angle (olYielding-:S:i:?S. 

i^^^,*Nv.n.^^.^i^^: 

^5° 

DO* 

ho° 

n 

*o° 

2,0° 

-hO° 

42S* 

2 ^ ° 

30° 

3<f>" 

X ^ 

•So' 

3D* 

a^» 

^ 0 * 

Average Angle Co)1 

1

 Average ef o must be < 10o to be acceptable. 

3? 

Rev. 6/92 
Form #Styrcne1 bo N6T VVAITE AOOVE THIS UNE 

STYRENE FIELD DATA FORM 

Sheet No. of 

Plant Cfch 

Date g/ g 6/ 7 3 Operator (£ M 

Location fc^UA ^U»^vv 

Run No. Sk Absorber Tube IDdS,Q(-

Stack ID / /Lf*/tff\ Stack Dimension

 /?vl

| '* 

Meter No. 7<pf<9 

Altitude ^aSri^ff i Corr. Eg$£

 Z ' H( 

Barometric Reading 

Barometric Pres. 

Stack Static Pres. _ 

^m?-

-o.-KT 

Ambient Temp. 

WB Temo. 

DB Terrm. 

Moisture Content 

"U- 7«T 

/ve. ' -2- 2 . " ^ 

I.OKt?. 

NOTES: />/£ f £ r Y* /' ^ ^ ^ 

\ > 

* ' 

K \0 J*^ 

•o** 

Sampling 

Time 

(min.) 

Mr 

i2.*s> i('^' : 

7L5" 

io 

.M: 

4 o 

H£T 

<T<? 

53" 

£0_ 

Clock Time 

{24 hr.) 

Start 

lt-d>X 

ir-37 •sjmo 

i.'-ix 

.XCO*65' 

tl€l 

f-X'-OX^ 

\Xo1 

^IX 

1Z'32_ 

\x:xl 

\-3X 

Gas Sample 

Volume (cf) 

Start 

*<K<rf&mi. D 

'^nrrt^L^fo 

$&r6&-3& 

m&u^-* 

1 M 7 •9&7&%or-

*D <.DH*± 

&*&&}{• 

**&***& 

Sample Flow Rate 

0tiVfFO 

OZ&S.tjT 

t^&&k&-&xt>ci. fo 

^^€[&rh.O^.^JO 

-ex\SJ5 

'O^A'isXS 

g?a^l.3 

0**4.35 

o-x.'&'HS' 

tmr't 

^3^.yr 

Dry Gas Mater 

Outlet Temp. ' 

i. 

1 

31 

32^ 

22. 

* 

s r 

sC-* 

1 

^2. 

^ 3 i 

a 

•x<£ 

li 

^^C^^tanM 

SSII^SL 

3£ 

2dL 

JE 

3^5" 

3& 

2LlW\^k. 

2>{,6 2>6.S 

o 

Z iT 

O 

O 

O 

£> 

o 

<o 

<? 

& 

?v 

go* 

K Rev. 7/93 
FILEVELVOL 

OAS VELOCITY AND VOLUME 

P.42 

ricators ILOCATION RithdrnmHET STACK ID 1,'North' 

RGR DIA. IN. 24 

Altitude 

Barotn. Read 

02% 

Wet Bib Trap 

2290 

3032 

21.0 

57.2 

Alt Corr 

Pbar. sU 

C02% 

E»tH20% 

—nr 

27.91 

0.0 

1.1 

Amb. Temp 

Ps,InH20 

N2% 

Wet Mole Wt 

"aprW 

•0.8 

79.0 

28.72 

AREA 

Ps,Abe 

Dry MolWt 

Pitot Cp 

TIT 

ZULU 

28.84 

0.840 

NOTE: INSERT OR DELETE ROWS FOR SAMPLING POINTS 

Al 

A2 

A3 

A4 

A5 

A6 

A7 

AS 

3 

92 

93 

94 

35 

36 

B7 

B8 

DELTAP 

0.92 

1.05 

1.15 

0.98 

130 

1.40 

1.40 

UO 

1.10 

1.05 

1.10 

130 

1.80 

UO 

1.40 

1 3 

t i\tAtH 

1i 

79 

77 

77 

75 

77 

75 

77 

77 

77 

77 

77 

77 

79 

75 

75 

A?!<5CE1 

ii 

50 

10 

0 

20 

20 

20 

25 

20 

30 

30 

20 

20 

30 

25 

30 j 

ink 

Data points OR insert 

as req'd in @Sqrt 

IL16 

AVG DELTA P 

MNSQRT D P 

AVG TEMP STACK 

AVG T STACK. ABS 

AVG ANGLE 

1241 

1.1097 

76.6 

536.6 

24.7 

WB/DBDELT 

STACK VEL, F/SEC 

FLOW RATE. FT3/MIN 

FLOW DSCF/MIN 

FLOWDSCF/HR 

19.4 

65.26 

12300 

11100 

666000 

ACFM 

ULTCOR 

(ANGLE 

CDIOX 

CP 

DIA 

DSCFM 

MNSQRT 

MNSQRT 

MNSQRT 

G35 

D9 

E16-E31 

H9 

Dll 

H12 

H5 

G36 

M32 

132 

N32 

MOLDRY Hli 

MOLWET F12 

NITROGE Fil 

OXYGEN 

PABS 

PBAR 

PSTATIC 

PSTATIO 

TS 

TSABS 

VELSTK 

WATER 

WBULB 

TSABS 

VELSTK 

WATER 

WBULB 

Bil 

H10 

BIO 

no 

D10 

D36 

D37 

G34 

D12 

B12 

D33 

G30 

D12 

B12 

4-1 
P.43 

Form /TM2-01 

GAS VELOCITY AND VOLUME DATA FORM 

""<«• * 

°" rW*73 Operator _• . 

Location ' . 

Run No. ^ 

Stack 10 No. . . . 

'A/^Um- -L. 

Stack Dimension 

Altitude <233£- "T-z^bO Alt. Corr. ffcw'Z-.V/ 

Barometric Reading ^ 01 2 2— 

Local Barometric Pressure "2. 7 ' « f 

Stack Static Pressure """ # I * 

Ambient Temp. 0^£ C 

Molecular Weight "^ X g\ # y 

Method €^3t^Uutf^ 

Pilot c, (P.^ y •••. 

' Average ef o must be <10« to be acceptable. 

Rev. 6/92 

4,2-
P.44 

FILEVELVOL 

GAS VELOCITY AND VOLUME 

<iEA Factor , |L6gAT16M ftatkJn.m.lb 

OPERATOR RGR DIA, IN. 

rAREAft&REcf.&Utf* 

STACKI ^ 1,4-Jorth* 

24 

''* 

Altitude 

Barom. Read 

02% 

Wet Bib Tnp 

2290 

3032 

21.0 

53.6 

Alt Corr 

Pbar, tu 

C02% 

EstH20% 

—sr 

27.91 

0.0 

OS 

Amb. Temp 

Ps, In H20 

N2% 

Wet Mole Wt 

apr 75 

•0.7 

79.0 

28.79 

AREA 

Ps,Abs 

Dry MolWt 

Pitot Cp 

-nr 

27.86 

28.84 

0340 

NOTE INSERT OR DELETE ROWS FOR SAMPLING POINTS 

JTIvA V PT 

}A1 

A4 

A5 

A6 

A7 

A8 

31 

B2 

B3 

B4 

35 

B6 

B7 

38 

man— 

0.82 

0.98 

0.98 

032 

1.40 

UO 

1.60 

0.88. 

038 

0.98 

l.OS 

130 

1.70 

130 

1.20 

1.05 

YitA6i 

75 

75 

75 

73 

73 

73 

75 

77 

79 

77 

75 

75 

77 

78 

75 

75 

AflSCE45 

50 

10 

0 

20 

20 

20 

25 

20 

30 

30 

20 

20 

30 

25 

30 

^OTE: Erase blank 

Data points OR insert 

is req'd in ©Sqrt 

array at L16 

«AVG DELTA P 

fc^NSQRTDP 

1 IAVG TEMP STACK 

lAVGT STACK. ABS 

l\VG ANGLE 

1.U3 

1.0662 

75.4 

535.4 

24.7 

IWB/DBDELT 

STACK VEL, F/SEC 

FLOW RATE, FT3/MIN 

FLOW DSCF/MIN 

(FLOWDSCF/HR 

1 

21.8 

67.56 

11800 

10800 

648000 

ACFM 

ALTCOR 

ANGLE 

AREA 

CDIOX 

CP 

DIA 

DSCFM 

MNSQRT 

MNSQRT 

MNSQRT 

G35 

D9 

E16..E31 

H9 

Dll 

H12 

H5 

G36 

M32 

132 

N32 

MOLDRY Hli 

MOLWET F12 

NITROGE Fil 

OXYGEN 

PABS 

PBAR 

PSTATIC 

PSTATIO 

TS 

TSABS 

VELSTK 

WATER 

WBULB 

TSABS 

VELSTK 

WATER 

WBULB 

Bil 

H10 

B10 

no 

D10 

D36 

D37 

G34 

D12 

B12 

D33 

G30 

D12 

B12 

4-3 
Form #Styrene1 66 b6T WftiT£ AfcoA/E THIS UKIE 

STYRENE FIELD DATA FORM 

Sheet No. of 

Plant 

Date Operator Q^lf\ 

Location (^XXAIVU ' 

Run No. 3 Absorber Tube ID jEt 

Stack ID / AJrt/f U Stack Dimension *XA 

Meter No. lOQO 

T.-T1-10 

Altitude 3f54^^-Alt 

Barometric Reading 

Barometric Pres. 

Stack Static Pres. 

. Corr. 

30.3, -

•2-7 . 

-^7 -

itfF^i 

?- ! 

t/ 

•% 

% 

y 

y Tf\r 

V

v

 *y\ 

Ambient Temp. 

WB Temo. 

DB Temo. 

Moisture Content 

<x£ ^ 

iz.*r.- 1.G W 

0<H7r< 

NOTES: MeHrY- I.0O0H 

Sampling 

Time 

(min.) 

5" 

IO 

(S 

1S> 

26" 

30 

33-

HO 

V5" 

so 

tt 

60 

Clock Time 

(24 hr.) 

Start 

X-oS" 

X'.IO 

x.\is 

a:3o 

X'XS' 

Z'ZO 

^35 -

Z'-Ho 

v.YS" 

I\&V 

X

%

'5S~ 

h-on 

V.OSGas Sample 

Volume (cf) 

Start 

03A&. ^5** 

QX--O.IO 

oxs^pg 

OXbS.HS' 

oi&i.qg 

o^io.^s 

ox ^lAS 

02.H&SM 

a*HlS.Hlt 

o*£/.dQ 

0'>S^.S% 

ouJ>Lxtf 

oXStAs* 

hTftu/r 

39.nt 

Sample Row Rate 

• 

-

Dry Gas Meter 

Outlet Temp: 

6 

* * 

a^ 

-xh 

*xc> 

x<»£ 

-xi 

*-7 

7 

^?.3T 

a7 

%*£ 

m\$.6' 

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agr 

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9*-& * 7 

*>D 

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3* 

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3 / 

T-VLS 

\ 

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2.3 

a.3 

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TVot»^. 

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o 

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Bd-r 

\A.-

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: \ « 

. / / 

, / * 

-/£-

./<r 

-/<r 

•'5 

. \ * 

Rev. 7/93 
Form AS ty ren d 6 6 U61 U/ftiYE Ub-Ait Tdi* LiKIE Sheet No. 

of 

STYRENE FIELD DATA FORM 

Plant 6><£iPr 

Pate Tr/2,^/^ 3 [Operator ffi£R 

Location ROJ^JAA^,/ 

Run No. / 

lA*. 

Absorber Tube 'P<g, 0V 

Stack ID £^-vfStack Dimension Q.*f 

Meter No. 7OHS 

.-j-'W 

Altitude -a=ai^S > Alt. Cnrr. —f^ A 7...V/ 

Barometric Reading 

Barometric Pres. _ 

Stack Static Pres. 

7°*?V 

S-l-'V 

— Q--6CT 

Cn 

Ambient TemD. 

WB Temp. 

DB TemD. 

Moisture Content 

^7v5 ^ F 

llm'C-

-z.-L'C0< 7e*% 

NOTES: 

I "wC Qgas. T>ek^ 

Meter Y- 1-0OQ6 

Clock Time 

(24 hr.) 

Start 

(012-

r°f~? 

MLk.Z. 

tni-? 

.11133. 

iO'*?*) 

(OH6> 

jl OIL 

HOi-

• i f -l -

Gas Sample 

Volume (cf) 

Start 

Po?43<r 

PQS'/.^-

0*WAQ 

^HZ^ 

w -yo 

~*-/7'ivt$ 

7. 

!T5 

hT4 wli?Ar 

Sample Flow Rate 

±LL 

0,<T 

Q'5~ 

4^CL 

n.T 

Dry Gas Meter 

Outlet Temp. 

hi 

JZ<£ 

-2-5~ 

2£ 

n 

•24 £ 

-^z 

lA 

3 ^ 

3 3 

_5> 1 

M 

1£L_ 

2dL 

23=-

22. 

3D>8 

5tack 

"Te^PO^ 

2.r 

2<T~ 

^r 

?,$-

>7 

a^ 

^ 6 

nX? 

Zsi 

i*r 

zt~. 

TV<x\«* 

\/A ^ 

lm... 

~2-

f . r 

i.t> 

t,s~ 

u<* 

[.(* 

1,6 

IA 

r= 2.Y. r 

Ba*' 

V/o.^. 

z 

X 

Z. 

"2. 

< z^ 

-zuT 

a^T 

2. 

TZ. 

Rnv. 7/93 
P.47 

Form JM2-01 

GAS VELOCITY AND VOLUME DATA FORM 

Plant / - _ &£Ps 

Date t/U/1 Operator H^'ftn 

LocatJoQ, 'fftVt 

Run No. 

••hf I 

Stack IO Ni t/rsrStack Dimension 

Altitude ZLT-rfO 

Barometric Reading 

Local Berometric Pressure 

Stack Static Pressure 

30^1 

^ ? . ?/ 

~ V. (C~ 

Alt. Corr. £ < V / 

* 

Ambient Temp. ^2_£* £ 

Molecular Weight * V 2~ %, fr V 

Method P.Sfrfrut/, 

P^t C. fl, g ^ 

V"«Vu 

$ 

Tr avert* -

°'UumbVr.'' 

V' ' ' 

/ )/ 

z 

3 

^ 

T 

6 

* 

« 

rt< 

Z-

"i 

<f 

c 

< 

?-

£ 

' *S \ A- J. ., \<«\ ' ' V% * 

,

s

 \'^y«»ocity% - -v 

- V; * ° , "?* * 

£?/*?N 

0.<7x 

LO 

AS* 

/ . 3 

/.* -

t'-( 

i.O 

•g? N 

.** * 

, 2 3 

0 ^ 

l.f 

•AA 

hi 

/*o 

Average Ap, 

Mean Sc,rt Ap, 

•rjij-rrs^mmmtmiimMmfm 

•»;,' - -••.,'.•• v 

". „Steck --:. 

\ s ^' ^ \ ,ss ***} 

&&'&> 

a.4 

a.i 

/A.o 

tn.o 

6,1.0 

£7,5" 

£7.5" 

W4 

^ S ~ 

66.S' 

^7 

*7 

47 

/S7 

^7 

J

v > ^Reference ,^>x ,> 

-*l 

- -J 

--. / 

*>*.£ 

,7 

.70 . 

. 6 3 

.5-7-

^ -,tf 

^ -,6 ~ 

^ -.e" 

• ^-*5 " 

.¥4 

.5-3^ 

* 6 £v-

.<$/ ' 

Average 

Stack 

Temo. 

•- r^Ancl . (ol Yielding?^ 

35* 

V5-

3 ^ ' 

5"° 

1KO* 

<xo° 

<10a 

W 

XO* 

*S° 

• is* 

16° 

If 

2 D a 

x.o° 

* -3^ ^ 

Average Angle (o)1 

1

 Average of a must be < 10« to be acceptable. Wit tlA-7 % llm'O 

Pry tfv/l, ^ %^ocy 

Rev. 6/92 

AU 
P.48 

FILEVELVOL 

GAS VELOCITY AND VOLUME 

FLAM T 6E A Fabrjcator. |L61AT16H ft.ltulJSSHg 

PATE 

pmr 

8/2493 TIME apr. 1250 | OPERATOR RGR |piA.IN. 

tibtH EMTCft m FT AREA Fd»ft RE£T. 6U« s 

STACKIB TEST" 

24 

1 Altitude 

Barom. Read 

02% 

WetBlbTmp 

"TST 

3032 

21.0 

57.2 

AIL Corr 

Pbar, ite 

C0256 

EstH20% 

— W 

nn 

0.0 

u 

Amb. Temp 

Pa, In H20 

N2% 

Wet Mole Wt 

apr 75 

-0.6 

79.0 

28.75 

AREA 

Ps,Aba 

Dry Mol Wt 

Pitot Cp 

5OT 

27 AS 

2&84 

0.840 

NOTE: INSERT OR DELETE ROWS FOR SAMPLING POINTS 

BKAVTT" TJEETAF T&AiK 

Al 

A2 

A3 

A4 

A5 

\6 

A7 

A8 

Bl 

B2 

33 

84 

B5 

36 

B7 

B8 

\m 

0.83 

0.93 

1.01 

1.20 

1.15 

l.OS 

1.10 

0.87 

1.05 

1.10 

UO 

1J0 

1.40 

1-30 

1.10 

7T 

81 

79 

79 

79 

81 

79 

79 

79 

79 

79 

79 

81 

80 

75 

75 

TT 

50 

10 

0 

20 

20 

20 

25 

20 

30 

30 

20 

20 

30 

25 

30 

urns >JOTE: Erase blank 

Data points OR insert 

ts req'd in @Sqrt 

imy at LK • 

JAVG DELTA P 

MNSQRT DP 

AVG TEMP STACK 

AVG T STACK, ABS 

Uvd'AViGLti 

1.114 1 

1.0506 

78.8 

538-8 1 

24.7 j 

WB/DBDHLT 

STACK VEL, F/SEC 

FLOW RATE, FT/MIN 

FLOW DSCF/MIN 

FLOWDSCF/HR 

21.6 

61.87 

11700 

10600 

636000 

ACFM 

ALTCOR 

ANGLE 

AREA 

CDIOX 

CP 

DIA 

DSCFM 

MNSQRT 

MNSQRT 

MNSQRT 

G35 

D9 

E16-E31 

H9 

Dll 

H12 

H5 

G36 

M32 

L32 

N32 

MOLDRY Hli 

MOLWET F12 

NITROGE Fil 

OXYGEN 

PASS 

PBAR 

PSTATIC 

PSTATIO 

TS 

TSABS 

VELSTK 

WATER 

WBULB 

TSABS 

VELSTK 

WATER 

WBULB 

Bil 

H10 

B10 

no 

D10 

D36 

D37 

G34 

D12 

B12 

D33 

G30 

D12 

B12 

4--^ 
Form /fStyrencl 6 6 fcc-T WAITE AA6vE TMIS LIME 

STYRENE FIELD DATA FORM 

Sheet No. of 

Plant k&L 

Date 9> •M/v Operator X.6A 

Location l{jQ/ti1\krU *. (Jct-ho, 

Run No. Absorber Tube ID 0 f. &g 

Stack ID ^9 $ r- <X* Stack Dimension 2** ¥' 

Meter No. ? C HJ$ 

Altitude 3-*-7<9 Alt. Corr.

 r Z - <

r / 

Barometric Reading %Q, 7> 2 -

Barometric Pres. 1.T,°f( 

Stack Static Pres. - O. 6<-( 

(miuytorts' 

^H./JT 

*tf<lX 

Sempllno 

Time 

(min.) 

/<> 

ISL 

2-0 

1£ 

12. 

ISL 

IL 

-ttSSL 

Cd 

Ambient Temp. 

WB Temp. 

DBTemp. 

«/ T<T*F 

N°fy 

UALL 

Moisture Content p.??* 

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Rev. 6/92 

e&~ 
P.54 

BISON ENGINEERING, INC. 

ENGINEER S • SCIENTIST S • PLANNER S 

Visible Emission Observttion Form 

SOURCE NAME 

frefi P/m. ADDRESS , . , 

l-?3r W, tt^Y C3 

^a^chr-^yiA.. 

PHONE 

STATS 

to 

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^*^"^ T°" ^^*-^L 

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OBSERVATION DATE 

S/U/9* s

s£tt 

AfWS 

/ 

2 

3 

4 

S 

e 

7 

8 

9 

10 

n 

12 

^ 7 3 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

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31 

32 

33 

34 

35 

36 

37 

38 

39 

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41 

42 

43 

44 

45 

46 

47 

48 

49 

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51 

52 

53 

54 

55 

56 

57 

58 

59 

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STOP TIME 

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RANGE OF OPACITY READINGS -

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OfyERVER-SffiN/UjREJI <D '"'Z/^A? 

{ORGANIZATION JO '«.A , CL'L K J. J^'C* 

S3 
P.55 

BISON ENGINEERING, INC. 

ENGINEER S • SCIENTIST S • PLANNER S 

Visible Emission Observation Form 

SOURCE NAME 

ADDRESS 

G-B* FM 

17 3f I/. H-w f?3 

CITY 

PHONE 

RcAU riA»^ 

STATE 

\o ZIP 932S2 

PROCESS EQUIPMENT 

SOURCE ID NUMBER 

CONTROirEOUIPMENT 

• EMU 

OPERATING MODE 

DESCRIBE EMISSION POINT 

START %-fa.cK KouVZiSTOP £g_ *„ f. 

OPERATING MODE 

OBSERVATION DATE 

£fc| 

MIN 

I 

£L 

a. 

0 

A 

15 

a. 

a 

o 

A 

A 

30 

0 

A 

A 

LL 

A 

START TIME 

LOL 

45 

0 

0 

0 

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M/A 

31 

32 

33 

34 

35 

36 

37 

38 

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52 

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25 

26 

27 

28 

29 

30 

54 

55 

56 

57 

58 

59 

60 

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HIGHEST PERIOD 0-

NUMBER Of READINGS ABOVE 

2~Q %WERE D 

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OBSERVERS ERS NAME (PRJNTI (PRINT! * - „ 

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5 »w g bC\./ %yKy fsQir%n. /5<jf*.^-Q' ^Uff*g r-sf-a 

f/ ra£f f^U/Jc ~f/j l>ir ORGANIZATION WSOAS PZvvrtfrgefitvKC.S..S th .-•>. * ^A-
P.56 

BISON ENGINEERING, INC. 

ENGINEER S • SCIENTIST S • PLANNER S 

Visible Emission 

SOURCE NAME „ 

CrBA PA& 

ADDRESS 

* 

r\*th<kr\/i+\ 

PHONE 

STATE 

in 

ZIP 

SOURCE IO NUMBER 

vMm.r-ft-t 

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START ?£v.c <*• Mo -t Ui STOP Sd^^e. 

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DISTANCE FROM OBSERVER 

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BACKGROUNfrtOlOR 

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^ 14*1' ""*"-«^_ 

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y& 

COMMENTS A ^ 

Observation Form 

OBSERVATION DATE 

s3rc 

/ 

2 

3 

4 

5 

6 

7 

a 

3 

10 

11 

12 

13 

14 

IS 

16 

17 

18 

1$ 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

30 

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0-

0 

0 

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AVERAGE OPACITY FOR,*. 

HIGHEST PERIOD (/ 

\fEC 

MIN\ 

31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

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52 

53 

54 

55 

56 

57 

58 

59 

60 

o 

STOP TIME 

15 30 45 

• 

NUMBER OF READINGS ABOVE 

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RANGE OFOPAOTY READINGS - * 

1/ MINIMUM O MAXIMUM 

OBSERVERS NAME (PR/NTI . ^ „ 

BpK Jr/ct+/Mffi O^RVpt'SSIGNAJOjE JS KJ 

(-/^Myt-[)iy^/^yOi ^ T <?" */i-isfr 

ORGANIZATION m. .— ^ , 

f6,yon b>m.ot n-e-e^srxj) 

s& 
P.57 

BISON ENGINEERING, INC. 

ENGINEER S • SCIENTIST S • PLANNER S 

Visible Emission Observation Form 

SOURCE NAME 

^£4 F/h5 

ADDRESS 

CITY 

r(.c.f%, J^rif yv\ 

PHONE 

STATE 

[0 

ZIP 

SOURCE IO NUMBER . 

tyd-rrk - / 

PROCESS EQUIPMENT . 

Ir-xfoZ-r-Cf/HrSS Lg^yU 

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START S.-/^U<y MO^CISTOP '* 

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PLUME TYPE: CONTINUOUS O 

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OBSERVATION DATE 

MIN 

I 

10 

11 

12 

13 

14 

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0 

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A 

15 

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30 

0 

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0 

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0 

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31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

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WATER OROPLEL 

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22 

23 

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25 

26 

27 

28 

29 

30 

55 

56 

57 

AVERAGE OPACITY FOR 

HIGHEST PERIOD 

58 

59 

60 

NUMBER OF READINGS ABOVE 

HWERE 

RANGE OF OPACITY READINGS 

MINIMUM MAXIMUM 

OBSERVERS NAME (PRINT! 

COMMENTS 

y-^T-S /frVTHvi /? mr>r*uno. ara.Si 

OBSERVERS SIGNA TURE 

~-^Z7 

DATE 

•f-.'e (h -s Ay Af & <LC -SO SQU^C1 ORGANIZATION 

5& 
ENGINEER S 

BISON ENGINEERING, INC. 

SCIENTIST S • PLANNER S 

P.58 

Visible Emission Observation Form 

SOURCE NAME_ 

(r&A- FAA 

ADDRESS 

• 

PHONE 

STATE 

1* 

ZIP 

SOURCE ID NUMBER 

PROCESS EQUIPMENT 

CONTROLfEQUIPMENT' 

OPfRATING MODE 

i trir, 

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1 

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t 

2 

3 

4 

5 

6 

7 

a 

9 

10 

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12 

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14 

15 

16 

17 

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19 

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22 

23 

24 

25 

26 

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0 

0 

START TIME 

45 

0 

0 

0 

IL 

0 

0 

0 

V 

0 

0 

o 

0 

AVERAGE OPACITY FOR 

HIGHEST PERIOD 0 

MM\ 

31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

61 

52 

53 

54 

55 

56 

57 

58 

59 

60 

o 

STOP TIME 

15 30 45' 

• 

NUMBER OF READINGS ABOVE 

%WERE V 

RANGE OF OPACITY READINGS _ 

© MINIMUM V MAXIMUM 

OBSERVERS NAME (PRINT) . , _ 

Borf K(CHif/{t/S. _ 

OBSfMERJSSIQNATUREY/^ / 6

7^, *AC* ? 

ORGANIZATION /*„*,*- > r C 

IDi 9£fS £r U-o\ t fc e€^y^} 

& • * 
P.59 

OLI\ 

DYNAMIC FABRICATORS 

Thermal-Dynamic 

Cooling Towers 

August 27, 1993 

W. 1735 Hwy. 53. Rathdrum 

P.O. Box 1265 

Post Falls, ID 63854 

Phone (208) 773-1787 

FAX (208) 773-4205 

Mr. David Kinghorn 

Bison Enginering, Inc. 

P.O. Box 1703 

Helena, Montana 59624 

Dear Dave, 

I have written a production summary report noting the conditions and methods used in collecting 

the necessary product usage data for the source testing. I have enclosed the six original log 

sheets along with the AP42 handbook emission factor calculations for each stack during the three 

test runs. 

If you have any questions regarding the data, summary or test conditions, please give me a call. 

Sincerely, 

John L. Krisman 

Facility Manager 

Enclosures 

cc: Tom Glassen 

•r-i.r-i.r^ 

CiT* II 

EHEEBS 

GEK -Group 

Energy-, Environment-, Process Technology 

B€ 
1 

APPENDIX C: OPERATING 

USAGES 

DATA/RAW MATERIAL 

4 , 

P.60 

£9 
i s J_. 

08/26/93 GEA/THERMAL DYNAMIC TOWERS 

1993 STACK EMISSION SOURCE TEST 

MANUFACTURER NAME 

i PRODUCT 

RESIN GP REICHOLD 0**jL 1~ 

RESIN ISO REICHOLD 

RESIN F/R DION 

GEL COAT GY REFCOA 

GELCOAT OP REFCOA 

PERCENT 

STYRENE 

35% 

45% 

45% 

35% 

35% 

LBS PER 

INCH 

/sjrSTART 

READING 

S US -

TIME 

START 

IOAO 

END 

READING 

2 7. S" 

TIME 

END 

/// / o 

NET 

INCHES 

1.1 sr 

NET 

LBS 

Z7./2.6" 

USAGE IS IN LBS 

AREA 

TEST# 

LEGEND: GENERAL PURPOSE = GP 

ISOTHALIC = ISO 

FIRE RETARDANT = F/R 

VINYL ESTER = VNL 

TOOLING = TLG 

GREY GELCOAT « GY 

OPTIONAL COLOR = OP 

4^Z^ 

I 

>ERSON MEASURING Ow*-^ -

Lop6/-J-^/ 
I !*LJ 

ti ) 

08/26/93 GEA/THERMAL DYNAMIC TOWERS 

1993 STACK EMISSION SOURCE TEST 

MANUFACTURER NAME 

•% PRODUCT 

RESIN GP REICHOLD *?f+ 

RESIN ISO REICHOLD »*.H I 

RESIN F/R DION iot4u*i 

GEL COAT GY REFCOA 

GELCOAT OP REFCOA 

PERCENT 

STYRENE 

35% 

45% 

45% 

35% 

35% 

LBS PER 

INCH 

/S.& 

&3t 

/7<S~ 

START 

READING 

ad.Lsim 

IIS/ 

nAir 

TIME 

START 

/oAo 

/D!/o 

/0)IO 

END 

READING 

20. f 

8&T> 

/o,?r 

TIME 

END 

ll:to 

If'.fo 

HAO 

NET 

INCHES 

S.IZiT 

mZ.blS 

.(oZ^ 

NET 

LBS 

/Z^.9 

W0.V7 

ID.°I 

USAGE IS IN LBS 

fr 

\ 

LEGEND: GENERAL PURPOSE = GP 

ISOTHALIC = ISO 

FIRE RETARDANT = F/R 

VINYL ESTER = VNL 

TOOLING - TLG 

GREY GELCOAT = GY 

OPTIONAL COLOR = OP 

AREA 

TEST # I 

PERSON MEASURING Qer^JlS. -ACkJbuA^^ 0/1. 

^v 0&J-^'< 
. :m 

08/26/93 GEA/THERMAL DYNAMIC TOWERS 

1993 STACK EMISSION SOURCE TEST 

MANUFACTURER NAME 

& PRODUCT 

RESIN GP REICHOLD fioc&X 

RESIN ISO REICHOLD <^MZ 

RESIN F/R DION /a<^«^2. 

GEL COAT GY REFCOA 

GELCOAT OP REFCOA 

PERCENT 

STYRENE 

35% 

45% 

45% 

35% 

35% 

LBS PER 

INCH 

IS.T 

15.32, 

11.5" 

START 

READING 

2 0 ' $~ 

G.I*-*"" 

ions 

TIME 

START 

//:3 2^-

ll\3l^ 

m s ^ 

END 

READING 

/3.37 r 

x. r 

fO.o 

TIME 

END 

il.3^— 

IU3-2-

fZ'.3Z~ 

NET 

INCHES 

-7.1*5-

3.fcZ.S-

/?<r 

NET 

LBS 

jio.<f 

SS.lS~ 

niztr 

USAGE IS IN LBS 

Ni 

LEGEND: GENERAL PURPOSE = GP 

ISOTHALIC = ISO 

FIRE RETARDANT = F/R 

VINYL ESTER = VNL 

TOOLING = TLG 

GREY GELCOAT = GY 

OPTIONAL COLOR = OP 

AREA 

TEST# 

PERSON MEASURING Q^/^l»—--_ ^ 

bjf facM? 
L.a.... ..J 

08/26/93 GEA/THERMAL DYNAMIC TOWERS 

1993 STACK EMISSION SOURCE TEST 

MANUFACTURER NAME 

& PRODUCT 

RESIN GP REICHOLD /3<*.fc*2-

RESIN ISO REICHOLD 

RESIN F/R DION 

GEL COAT GY REFCOA 

[GELCOAT OP REFCOA 

PERCENT 

STYRENE 

35% 

45% 

45% 

35% 

35% 

LBS PER 

INCH 

IS .5 " 

START 

READING 

-2.9,^ " 

TIME 

START 

i/:32 . 

END 

READING 

?_q,?r' 

TIME 

END 

/ ^3 £ 

NET 

INCHES 

fi T 

NET 

LBS 

a 

/ 

USAGE IS IN LBS 

5^ 

IN 

LEGEND: GENERAL PURPOSE = GP 

ISOTHALIC = ISO 

FIRE RETARDANT = F/R 

VINYL ESTER = VNL 

TOOLING = TLG 

GREY GELCOAT = GY 

OPTIONAL COLOR * OP 

AREA 

TEST# 2— 

PERSON MEASURING y^jc^- > 'x^oL7 

A ^ <uA^. 
..J -

'"V • I 

08/26/93 GEA/THERMAL DYNAMIC TOWERS 

1993 STACK EMISSION SOURCE TEST 

MANUFACTURER NAME 

iPRODUCT 

1ESIN GP REICHOLD tfr^l 

IESIN ISO REICHOLD fifce/U^ 

tESIN F/R DION (h*$t\H 

.EL COAT GY REFCOAflUtv ^ 

IELCOAT OP REFCOA 

PERCENT 

STYRENE 

35% 

45% 

45% 

35% 

35% 

LBS PER 

INCH 

is-.sr 

\53% 

n.f 

/L%JI 

START 

READING 

<?.r 

VL.O 

L>.Ltf 

H.O 

TIME 

START 

Z;o5" 

2.: o r 

2*xT 

A:o< -

END 

READING 

^.75" 

28. f 2 ^ 

S.4> 

333? 

TIME 

END 

Z\3S 

3:or " 

3:osT 

3^>^r 

NET 

INCHES 

2.75 " 

y&is-

\MV< 

JSlf 

NET 

LBS 

M2.t 

5%<o 

iz-L i*.r 

ISAGE IS IN LBS LEGEND: GENERAL PURPOSE = GP 

ISOTHALIC = ISO 

FIRE RETARDANT = F/R 

VINYL ESTER = VNL 

TOOLING = TLG 

GREY GELCOAT = GY 

OPTIONAL COLOR = OP 

AREA 

(EST # 3 

!-'EPSON MEASURING ^LLl^Arr /) ^2'*r^ A~8 ~~&y 

* ^A^tJ^J^ ^"° 

ApJOuAps-
08/26/93 GEA/THERMAL DYNAMIC TOWERS 

1993 STACK EMISSION SOURCE TEST 

! MANUFACTURER NAME 

j&PRODUCT 

! RESIN GP REICHOLD fontWH 

! RESIN ISO REICHOLD 

; RESIN F/R DION 

(GEL COAT GY REFCOA 

•GELCOAT OP REFCOA 

PERCENT 

STYRENE 

35% 

45% 

45% 

35% 

35% 

LBS PER 

INCH 

It.'T 

s 

/k*7 

s 

START 

READING 

-Vi.iir 

I »' 

X / \ 

TIME 

START 

2:z5~ 

END 

READING 

274SSTIME 

END 

1\°<~ 

NET 

INCHES 

2,4 2>r 

NET 

LBS 

LfO.1 

USAGE IS IN LBS LEGEND: GENERAL PURPOSE = GP 

ISOTHALIC = ISO 

FIRE RETARDANT = F/R 

VINYL ESTER = VNL 

TOOLING = TLG 

GREY GELCOAT = GY 

OPTIONAL COLOR = OP 

AREA

 KmM 1^/ 

TEST # J5 

PERSON MEASURING ^ Q(M* -

\fSrt* 6~f <*^t-*S ""*• 

y 
P.67 

APPENDIX D: LABORATORY DATA WITH CHAIN OF 

CUSTODY FORM 

£/; 
I -iv.. 

..rm 0STK-O1 Page of 

BISON ENGINEERING INC. - CHAIN OF CUSTODY RECORD 

^2 

Client Description £/ = # FfiAA IC/lTOtfS- P I &£ < &L- fiSS frXOO. jk/VAsfajA(^ 

iVoject No. f % O 8 O 

rotal No. of Samples £ - Pd i^rc 0 t~uf?e.S 

Date 

9A<A* 

Sample I.D. 

01 

0 Z. 

ffa* t. 

5faxl< I. 

Type of Sample 

SKC* fids* #&&/?. TuS£ 

#1l& 

"tVOfiiTH," 

"t/oKTH." 

/&&.&$#/* 

AOfU I, F/Z IAST- r^& r 

/f^///. garb: Tu6E 

Samplers' Sionature 

Analytical Method Requested ^«0r 6 <3**^ C- k'romtz fro 

0/&&&' Date Sample I.D. Method 

03 St*cC( ^J *BSsr/ K UiU I, Fro wt- ir-<l?^ 

V OV SUck "s>/isr" dvh/f. 60-CK: Tvbc TiE\JEi\'c.u 

o$r 9 ikicXs/fy. "VOX TH 

i "rfy^z,^ F- tfot/r rut's <tfT'0 3 1993 

o-i $t*c<<l "wtrtt* /Zi/t/z., &4ccc ru/S Bistm 

* 

£JL SUcK z. 9- y/jsr:' x U/U Z M F~ro <* tr 7~ui,. 

see. JZL. 9-tocKT- '£*ST" #wzy /£* ctr Tub-it, 

6e/c Mo 7 It*'* l, "Ayo/?T//« «W}.i $#cic T</& 

v 

/? 

fr 10 SU-df /, "A^/?r// // Avfif.3. P'/toA/r rv/3/= 

11 Sine* Z, "efisr* #vfi/2. F/?o/yr rv/i/~ 

12- /?&£*( z~, "B/fST" ft msi. S/ietr ru/3/~ -5^-

Shipping No. * 

,moan >mpanvy Name/Address^/^^^^- ^ Name/Address, 

•ceived by tf?JtA &. 

/vtr 

ML 

Date 

Company Name/Address 

Received by 

Shipping No. Date 

Company Name/Address 

Received by 

Shipping No. 

r/0T£; Tvt>& «•$.*&*«, b/y 0f.//a «^«> s«^~\ple<!> f3>/)-CKi«srt/{l/)S by error, lOfltft WAfi/TS * 

— Pocuyi&ivr s 

- ~$U f/4(y tof. 

fi p r^orfr. 

'/ "l-Sl" ' " *•" -* ^/"Itmt* U/^aw/J/lt/p vy CmrrVf, I U/f/fC/ \A/ ft IUI > ' 

£TyA£fi/i=. Azcevcry cf-^'o/e^xcy UvV£4 &/* Sites ""J-^VN-V ^7^ \ 

*»CS <?£• or-'gin-v/ Cyhror*ui£-oq r^vvis ^-/(yh you^i^) Rev. 7/95^^) 
P.69 

ENERGY / ENERGY LABORATORIES, INC. 

LABORATORIES 

TO: 

ADDRESS: 

P.O. BOX 30916 * 1107 SOUTH BROADWAY • BILLINGS. MT 59107-0916 • PHONE (406) 2526325 

FAX (406) 252*069 . 1-800-735-4 489 

Robert Richards 

Bison Engineering 

P.O.Box 1703 

Helena, MT 59624 

LABORATORY REPORT 

\*ED 

1993 

LAB NO.: 93-38796-801 

DATE: 09/08/93 da 

U i O QH 

CHARCOAL TUBE ANALYSIS 

Proj. No. 93080, GEA Fabricators-Fiberglass Prod. 

Sampled 08/26/93 

Submitted 08/27/93 

Analyzed 08/27/93 

Lab No. 

93-38796 

93-38797 

93-38798 

93-38799 

93-38800 

93-38801 

Blank 

Identification 

Stack 1, "North" Run 1 

Stack 2, "East" Run 1 

Stack 1;, "North" Run 2 

Stack 2, "East" Run 2 

Stack 1, "North" Run 3 

Stack 2, "East" Run 3 

Charcoal Tube Lot 120 

SKC #226-09 

Styrene, mg/Tube 

Front Corrected for Back 

Tube111 Desorption Efficiency121 Tube 

9.42 10.0 <0.0030 

6.00 6.37 < 0.0030 

5.52 5.86 <0.0030 

6.99 7.42 < 0.0030 

7.17 7.61 <0.0030 

7.71 8.18 <0.0030 

v N/A N/A 

<0.003O V 

"Tw o SKC catalog #226-09 charcoal tubes were exposed in series. The tubes were lot #120 and 

contained 400 mg of charcoal in the primary section and 200 mg in the backup section. Both primary 

and backup sections of the first tube in the series were desorbed as one. Only the primary section of 

the 2nd tube in the series was desorbed to check for breakthrough. 

'"The desorption efficiency was calculated from the average recovery of three charcoal tubes from lot 

#120 spiked with 6.000 mg of Styrene per tube. The average recovery was 94.2%. 

Analysis done by NIOSH Method 1501. 1\ 

0\C\ 

LP, 
P.70 

ENERGY 

I AB ORATORIES 

ENERGY LABORATORIES, INC. 

P.O. BOX 30916 • 1107 SOUTH BROADWAY . BILUNGSTM T 59707-O916 • PHONE (406) 252-632* 

FAX (406) 252-6069 . 1 -800735 4489 

CJ:--

•r* "t-i 

:'j J J 

LABORATORY REPORT 

TO: 

ADDRESS: 

Robert Richards 

Bison Engineering 

P.O. Box 1703 

Helena, MT 59624 

LAB NO.: 93-38796-801 

DATE: 09/08/93 da 

QUALITY ASSURANCE DATA 

Identification 

Blank Spike #1 

08/27/93 

Blank Spike #2 

08/27/93 

Spike Added 

Styrene, 

uo/Tube 

50.0 

50.0 

Spike Recovery 

Styrene, 

//a/Tube 

52.2 

59.1 

% Recovery 

104 

118 

6-9 
P.71 

Report Date : 31-Aug-1993 11:30 

Start Cal Date 

End Cal Date 

Quant Method 

Cal Curve Type 

Origin 

Target Version 

Integrator 

Method file 

Cal Date 

Ihv-Hol ColiVofcon -for Tube fWxtys(< 

RECEiVcD Page l 

SEP A 0 1993 

Energy Laboratories, Inc. BISQiM 

INITIAL CALIBRATION DATA 

27-AUG-93 08:49 

27-AUG-93 10:36 

ESTD 

Linear 

Force 

Target 2.40 

HP RTE 

/disk3/svdata2/082793.b/Styrene.ra 

27-Aug-1993 11:40 

Calibration File Names: 

Level 1: /5970/chem/msd.i/082793, 

Level 2: /5970/chem/msd.i/082793, 

Level 3: /5970/chem/msd.i/082793, 

Level 4: /5970/chem/msd.i/082793, 

Level 5: /5970/chem/msd.i/082793, 

b/27Aug0l01001.d 

b/27Aug0201002.d 

b/sty082793.d 

b/27Aug0301003.d 

b/27Aug0401004.d 

Compound 

1 Styrene 

2 | 5 | 20 | 50 | 100 | | | 

Level 1 j Level 2 j Level 3 j Level -, j Level 5 j RRF jx RS0/RA2 j 

ss I sssssssss I sssssssss | cssssssss | escssssss | sssasnasi | sssassusa I 

172547| 178658| 1627531 U9333| 1267811 1332231 0.986| 

I I I I I I I 

V-o 
P.72 

i i I i i i i I i i i i I i i i i I i i i i I i i i i I i i i i I i i i i I 

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 

firta M0~7) 

i | i i i i | i i i i | i i i i | i i i i | i i 

0.9 1.0 1.1 1.2 1.3 

~7I 
P.73 

H 

Data File: /5970/chem/msd.i/082793.b/27Aug0101001.d 

Report Date: 27-Aug-1993 41:39 ^ v 

Energy Laboratories, Inc. 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

/5970/chem 

27-A0G-93 

tjp i. 

Styrene 2ug/ml 

BNA QUANT RATIO REPORT 

/082793.b/27Aug0101001.d 

Quant Type: ESTD 

Autotune Date: 

Inst ID: msd.i 

Page l 

Sample Matrix: CS2 

/5970/chem/msd. i/082793.b/Styrene.m 

27-Aug-1993 11:39 

27-AUG-93 09:21 Cal File: 27Aug0101001.d 

1 Calibration Sample, Level: 1 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

ssss:ssss:::ss 

1 Styrene 

0UANT SIC 

MASS 

SSS 3 

104.00 

RT 

S 3 

5.774 

RESPONSE 

SSSSSSS3 

345095 

CONCENTRATIONS 

ON-COLUMN 

< U9/D 

«::: » 

2.6 

FINAL 

(ug/ml) 

SSS3S8 3 

2.6 

P-^ 
P.74 

CM 

t l 

<0 

Q. 

1 

o 

o 

o 

o 

o 

o 

- s 

o% 082 

V. 

•a 

HI 

m 

\x Is 

O M 

r» «* 

<r> i 

^ | 

> i ^ r*. 

— CM 

« t> 

*> AJ 

1 <0 

u 

c , 

— Ji 

£ 8 ^ — QC • . 

c m « 

xs^ M M : 7 

. . ti a 

£2l l 

l-n j 

Q c * o o - Ul u > 

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. 

-"j: 

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•o 

ssrA] 

8 

O 

»H 

o 

CM 

&* 

CM 

09 

> 

r». 

< 

,(TT8*S> *«Jfi^S J 

. 

, -

_ _ 

• 

8 9 10 

Hin 

-rs . 

. 

• 

-\0 

•• 

- ' T 

- J: 

J, 

rM-oeDincMOootncMoaowcMoeomcMoaincMooDtncMoaDincM O NSiiflSfljioininmin-ryTxiDMioiiitiiNNNrtrtrtrtOOO O 

<S~0T*> A ' 1 

Tt3 
P.75 

Data File: /5970/chem/msd..i/082793.b/27Aug0201002.d 

Report Date: 27-Aug-1993 11:40 

Page 1 

i'-J 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Aug0201002.d 

Quant Type: ESTD 

27-TAUG-93 09:43 Autotune Date: 

tjp . Inst ID: msd.i 

Styrene 5ug/ml 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 09:43 Cal File: 27Aug0201002.d 

2 Calibration Sample, Level: 2 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

BSSSSSSSSSSSSS 

1 Styrene 

QUANT SIC 

MASS 

ssss 

104.00 

RT 

S 3 

5.787 

RESPONSE 

SSSSSSSS 

893293 

CONCENTRATIONS 

ON-COLUMN 

< ug/D 

ssssssa 

6.7 

FINAL 

(ug/ml) 

BEZS8S S 

6.7 

•44 
Data File. . 5970/che«/(wd.1/082793.b/27Aug0201002.d 

Date : 27-AUG-93 09:43 

Instrument : nsd.l 

Sanple ID : Bison Engineering 

COIUMI phase : XTI-5 Restek 

Volune Injected <cL> : 1.0 

i i *XJ .. . . i I 

Page 2 ) 

Column diamter : 0.25 

2.i-i 

2.0-: 

1.9-: 

i.8-: 

1.7-i 

1.6-i 

1.5-: 

1.4-= 

1.3-: 

1.2-: 

jjUj 

3i.o-: 

,9.9-: 

0.8-i 

0.7-: 

0.6-: 

0.5-: 

0.4-: 

0.3-i 

0.2-: 

M U < 

4 

I 

j 

• 

- . - *—\ 

fs. 

OO 

rs. 

in 

s> 

I 

-h, 

5 ' 6 

/5970/che«»/msd.l/082793.b/27ftug0201002.d 

l l A . 

7 -8 9 10 

Min 

. k . 

11 

A 

12 

1 i 

13 14 

•sj 
P.77 

Data File: /5970/chem/msd.i/082793.b/sty082793.d 

Report Date: 27-Aug-1993 11:39 

Page l 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: WATER 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msa.i/082793.b/sty082793.d 

Quant Type: ESTD 

27-AUG-93 08:49 Autotune Date: 

tjp Inst ID: msd.l 

Styrene 20ug/ml 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:39 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

1 Calibration Sample, Level: 3 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist:- all.sub 

Compounds 

1 Styrene 

QUANT SIG 

MASS 

ssss 

104.00 

RT 

ss 

5.812 

RESPONSE 

csssssss 

3255069 

CONCENTRATIONS 

ON-COLUMN 

( ug/l> 

sssssss 

24.4 

FINAL 

( ug/D 

sssssss 

24.4 

4/« 
..... 1 

-

o. 

B 

? 

0.25 Column dlaneter : 

•a 

ro 

ON 

rs. 

CM 

AJ 

• 

ro 

— Ji 

. «, o 

*o *J « 

*» *l .H 

•s. ON OS • • 

- |8 - J--3 

•s. . h- s^ O K> "O S _ 

rs. ON M -B 

ON | « « . C 

•« I *» S " 3 

SftlSil 

r

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« ti 2 Q. 3 3 

JJ AJ *i 5 —• •»» « « c « o o 

p a « viu > 

. 

ro 

ON 

s 

%! 

AJ 

n 

. 

ro 

ON 

r^ 

M 

Sss . — — 

s 

ON 

(2T8'S) *p-**S 

cMocomcMOooi n 

rs.rs.vAvAvovoini n 

v 

CMOOotncMoaoincMoaoincMea o 

B)U)'»'r-» ,»KIKI|(||l>N'NN'N H 

<9~0T*> k 

ytt 

• 

••H 

« • 

^ 

4 

-< 

-1 

-

_ _ _ 

J 

i n CM o CD i n CM c 

•rt ..-I T* O O O C 

- < M 

' 

.*- < 

* 

8 9 10 

Hin 

-r-s . 

- V O 

*. 

- i n 

> 

> 

P.78 

-

-
P.79 

Data File: /5970/chem/msd.i/082793.b/27Aug0301003.d 

Report Date: 27-Aug-1993 11:40 

Page l 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

* 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Aug0301003.d 

Quant Type: ESTD 

27-AUG-93 10:09 Autotune Date: 

tjp Inst ID: msd.i 

Styrene 50ug/ml 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:09 Cal File: 27Aug0301003.d 

3 Calibration Sample, Level: 4 

1.000 Target Version: Target 2.40 

HP RTS Compound Sublist: all.sub 

Compounds 

ssssssssssssssssssssssssss 

1 Styrene 

QUANT SIG 

MASS 

SSSS 

104.00 

RT 

ss 

5.800 

RESPONSE 

ssssssss 

7466656 

CONCENTRATIONS 

ON-COLUMN 

( ug/l) 

ssssssa 

56.0 

FINAL 

(ug/ml) 

sssssss 

56.0 

Tig 
.J^ 

Data . .e: /5970/chem/msd. l/O82793.b/27AugO3O10O3.d 

Date : 27-AUG-93 10:09 

Instrtnent : nsd.l 

Sanple ID 5 Bison Engineering 

Column phase : XTI-5 Restek 

Volume Injected (uL) : 1.0 

Pat J 

Column diameter : 0.25 

1.5-

1.4-

1.3-; 

1.2:, 

1

'

1

: 

1.0-j 

0.9-; 

ts. < O 

3 0.-7-

>-

o.6-; 

0.5-; 

o.4: 

°«3: 

0.2-j 

0.1-u 

. 

' * __,. 

| 

u IJ 

800) 

i n 

8 . 

1}. 

-Ui 

I. 

4 5* 6 

/5970/chem/m 

.1 

sd. i/082793.b/27fiug0301003.d 

-

7 8 9 10 

Hin 

11 12 

• 

13 

c 

14 

oo 

o 
P.81 

Data File: /5970/chem/rosdli/082793.b/27Aug0401004.d 

Report Date: 27-Aug-1993 11:40 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/rosd. i/082793.b/27Aug0401004.d 

Quant Type: ESTD 

27-AUG-93 10:36 Autotune Date: 

tjp | Inst ID: msd.i 

Styrene lOOug/ml 

/5970/chem/msd. i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

4 Calibration Sample/ Level: 5 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: a11.sub 

Compounds i 

1 Styrene i 

QUANT SIG 

MASS 

104.00 

RT 

sa 

5.800 

RESPONSE 

BSSS3S8 0 

12678118 

CONCENTRATIONS 

ON-COLUMN FINAL 

( ug/1) (ug/ml) 

SSSSSSS 

95.2 

SSSSSS S 

95.2 

f& 
... -,; . .„_ . I I . . 

Data V•ie: /5970/chem/msd.i/082793.b/27Aug0401004 .d 

Date : 27-ftUG-93 10:36 

Instrument : msd.l 

Sample ID : Bison Engineering 

Column phase : XTI-5 Restek 

Volume Injected (uL) : 1.0 

Pagt -' 

Column diameter : 0.25 

/5970/chem/msd.l/082793.b/27Aug0401004.d 

1.9: 

1.8: 

1.7-i 

1.6-i 

1.5: 

1.4-i 

1.3-= 

i.2-: 

i.i-i 

i * 

3o.9: 

0.8: 

0.7-i 

0.6-i 

0.5-i 

0.4: 

0.3-; 

0.2-i 

0.1: 

-I . » II- -JL 

10 11 12 13 14 

JUL 

co 

ro 
a 

P.83 

\ iu n 

Di.ta File: /disk3/svdata2/082793.b/27Augl301013.d 

Report Date: 31-Aug-1993 11:42 

Page^ 

SEP 0 9 1S93 

• .••)i'r»? i 

Energy Laboratories, Inc. 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Augl301013.d 

Quant Type: ESTD 

27-AUG-93 14:42 Autotune Date: 

tjp Inst ID: msd.i 

93-38796 Front x50 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

13 

50.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

ssssssssssssss 

1 Styrene 

QUANT SIG 

MASS 

ssss 

104.00 

RT 

ss 

5.810 

RESPONSE 

BSSSSSSS 

8389762 

CONCENTRATIONS 

ON-COLUMN 

( ug/1) 

sssssss 

62.8 

FINAL 

(ug/ml) 

sssssss 

3140 Xl"-X 

q^°% 

RZ 
P.84 

Data File: /disk3/svdata2/082793.b/27Augl301013.d 

Report Date: 31-Aug-1993 11:42 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Client Name:' 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

Page 2 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

•Styrene_ 3140 
Data Flie: /dlsk3/svdata2/082793.b/27Augl301013.d Page 

oo 
P.86 

DaU File: /disk3/svdata2/082793.b/27ftigl301013.d 

1 Sf^-ene 

Page 4 

Hass 104.00 

Hass 78.00 

4.0 

3.0 

k2.o-: 

x 

>-1.0: 

4.5* 

4.0 

3.5 

3.0 

32.5 

12.0 

1.0 

0.5 

0.0 

Scan 229 (5.810 min) of 27Augi301013.d 

1 

Z

51 

L . .1 ll. 1. 

^^•W* V Wmtm.m* <M 

78s 

^.h , 

* 

89\ 

l 

104"" 

* \ | 

. I . I 1 

0 , 

f 

5055606 5 70 758085909 5 100 105 

m/z 

4-5-

4.0-j 

3.5-1 

3.0-i 

32.5-i 

S2.0i 

Ion 104.00 

in 

.1.5-: 

i.o-1 

o.o-:- JL 

5.2 5.5 5.8 6.0 6.2 6.5 

H]n 

0.0 

5.2 5.5 5.8 6.0 6.2 6.5 

Hin 

Ion 78.00 

2.2-i 

2.0 

1.8 

~1.5-i 

gl.2* 

vO.8-1 

0.5 

0.2 

0.0 

co 

. in 

L 

5.2 5.5 5.8 6.0 6.2 6.5 

Hin 

f^^T 
P.87 

Data File: /disk3/svdata2/082793.b/27Augl401014.d 

Report Date: 31-Aug-1993 11:43 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Snip Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Augl401014.d 

Quant Type: ESTD 

27-AUG-93 15:09 Autotune Date: 

tjp Inst ID: msd.i 

93-38797 FrontX50 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

14 

50.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

CompcxTxds 

II»SSIIZ:I:X 3 

1 Styrene 

QUANT SIG 

MASS 

M M 

104.00 

RT 

M 

5.822 

RESPONSE 

zsxsszs a 

5462413 

CONCENTRATIONS 

0N-C0LUKN 

( ug/l) 

•••••• • 

40.0 

FINAL 

(ug/ml) 

•ui:c i 

2000 *?""*-

(,ooo -y J-h^ 

ft, 
P.88 

Data File: /disk3/svdata2/082793.b/27Augl401014.d 

Report Date: 31-Aug-1993 11:43 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Page 2 

Client Name:' 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

a^ 
Data Flic: /dlsk3/5vdata2/C»2793.b/27Auil401014.d Pate -

* • 

QO 

DO 
P.90 

Data File: /disk3/svdata2A«2793.b/27Augt401014.d Pace 4 

'ri 

I S tva-e ne 

Scan 230 <5.822 uin) of 27ftugl401014.d 

3.2-1 

2.8 

2.4 

~2.0-

£l.6 

~1.2-

>-

0.8-

0.4-

0 0-

•-

/ » 

i L. .„!... 

' 50 55 60 65 

Ion 104.00 

3.2-. 

2.8-

2.4-

~2.0-

^1.6-

*1.2-

>-

0.8-

0.4-

0 0-

:

 1 

ra IO 

5.2 5.5 5.8 6.0 

Hin 

»s 

^l„ 

« 

» \ 97v 

l :. 

70 75 80 85 90 95 

«/z 

6.2 6.5 

1.6-

1.4-

1.2-

31.0-

^0.8-

X 

~0.6-

>-

0.4-

0.2-

0 0-

Ion 78.00 

l 

"§ 

m 

* 

5.2 5.5 5.8 6.0 

Min 

104^ 

. ,1 f 

100 105 

6.2 6.5 

Hass 104.00 

Hass 78.00 

3.0-

2.5-

S1-5-

-1.0 -

"0.5-

0.0-

5.2 5.5 

1 

5.8 

Kin 

"... 

*t 

\ 

6.0 6.2 6.5 

•&? 
P.91 

Data File: /disk3/svdata2/082793.b/27Augl501015.d 

Report Date: 31-Aug-1993 11:43 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Snip Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle: 15 

Dil Factor: 50.000 

Integrator: HP RTE 

Sample Matrix: CS2 

Conpounds 

••—•——••••••••••••• • 

1 Styrene 

Energy Laboratories, Inc . 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Augl501015. d 

Quant Type: ESTD 

27-AUG-93 15:35 Autotune Date : 

t j p Inst ID: msd. i 

93-38798FX50 

/disk3/svdata2/082793.b/Styrene. m 

31-Aug-1993 11:34 user l 

27-AUG-93 10:36 

QUANT SIG 

HASS 

K I I 

104.00 

RT 

5.798 

Cal File : 27Aug0401004.d 

Target Version: Target 2 

Compound Sublist:- all.su b 

RESPONSE, 

>»::::: 

50474-44 

CONCENTRATIONS 

ON-COLUMN FINAL 

( ug/l) <U9/ml) 

r===ss= 

36.8 1840 X 7'1 

6£* aJ 

^c. 
P.92 

Data File: /disk3/svdata2/082793.b/27Augl501015.d 

Report Date: 31-Aug-1993 11143 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Client Name: ' 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

Page 2 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

9> 
i • !..• . I 

Data F /ditk3/svdat«2/0e2793.b/27Autl501015.d Paje 

• ^ 

N 

CO 

CO 
P.94 

4 

Bata File: /dlsk3/svdata2/082793.b/27Auci501015.d 

1 Styrene 

Pace 4 

2.8-

2.4 

2.0-

Il.2 

>"0.8-

0.4-

0 0* 

Scan 228 (5.798 uin) of 27ftu«1501015.d 

104^ 

. 

i 

78s, 

' 

L. .,ii.. . ^\\\ I i . .. . 1 T. 

5055606 5 70 758085909 5 100 105 

*/z 

Ion 104.00 

2.8-

2.4-

2.0-

Co 1.6' 

o 

31.2-

>-o.8-

0.4-

n it-

? 

L« 

5.2 5.5 5.8 6.0 6.2 

Min 

Ion 78.00 

1.4-

1.2-

1.0-

?0.8-

o 

So.6-

*"0.4-

0.2-

l U 

0.U-. ,....,... . 

5.2 5.5 5.8 6.0 6.2 Min 

Ha« 104.00 

Hass 78.00 

2.5-j 

2.0-1 

pM 

3i.o-: 

»-o.5-: 

0.<K.. .— 

5.2 

-

, 

5.5 5.S 

Hin 

/ % 

I 

•6.6 & 

Qs 
P.95 

Data File: /disk3/svdata2/082793.b/27Augl601016.d 

Report Date: 31-Aug-1993 11:43 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Ais bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Augl601016.d 

Quant Type: ESTD 

27-AUG-93 16:02 Autotune Date: 

tjp Inst ID: msd.i 

93-38799FX50 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

16 

50.000 Target Version: Target 2.40 

HP RTE Compound Sublist:-all.sub 

Compounds 

ssssssssssssss 

1 Styrene 

QUANT SIG 

HASS 

ssss 

104.00 

RT 

S 3 

5.810 

RESPONSE 

======== 

6318430 

CONCENTRi 

ON-COLUMN 

( U9/D 

sssssss 

46.7 

a IONS 

FINAL 

(ug/ml) 

SSSSSSS 

2330 

.. < ^ * J 

(. itt "3 

f4 
P.96 

Data File: /disk3/svdata2/082793.b/27Augl601016.d 

Report Date: 31-Aug-1993 11:43 

• Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Page 2 

Client Name:' 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

-Styrene_ 2330 

FT 
P.97 

^ 
P.98 

Data File: /disk3/svdata2/082793.b/27fciilfc01016.d 

1 Styrene 

Pa<e 4 

Hass 104.00 

Hass 78.00 

4 

3.6 

3.2 

2.8 

2.4 

32.0 

0.8 

0.4 

0.0 

Scan 229 (5.810 Hin) of 27Au|16O1016.d 

7 6 \ 

104^ 

/ » 

J I .1.1 ^ ;in 

•N ?\ V" 

50 55 60 65 70 

3.6 

3.2 

2.8 

2.4 

32.0 

Sl.6 

0.8 

0.4 

0.0 

Ion 104.00 

75 80 85 90 

J£ 

95 100 105 

3.0-. 

2.0-i 

i.o-l 

0.0-

5.2 5.5 5.8 6.0 6.2 6.5 

Hin 

ao 

. in 

J 

5.2 5.5 5.8 6.0 6.2 6.5 

Min 

1.8-

1.6-

1.4-

1.2-

gl.O-

?0.8-

^0.6-

0.4-

0.2-

ft A . 

Ion 78.00 

t—© 

fi 

I 

i n 

.1 

5.2 5.5 5.8 6.0 6.2 6.5 

HjT> 

9* 
P.99 

Data File: /disk3/svdata2/082793.b/27Augl701017.d 

Report Date: 31-Aug-1993 11:44 

Page 1 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

Data file : /disk3/svdata2/082793.b/27Augl701017.d 

Quant Type: ESTD 

: 27-AUG-93 16:29 Autotune Date: 

; tjp Inst ID: msd.i 

: 93-33880FX50 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

Ais bottle: 17 

Dil Factor: 50.000 

Integrator: HP RTE 

Sample Matrix: CS2 

Target Version: Target 2.4 0 

Compound Sublist: all.sub 

Compounds 

»K!!ti:r:t:::;:::5ri;::: : 

1 Styren* 

QUANT SIG 

MASS 

sss : 

104.00 

RT 

z s 

5.847 

RESPONSE 

•ssssss s 

6455697 

CONCENTRATIONS 

ON-COLUMN 

( ug/t) 

ssssss s 

47.7 

FINAL 

(ug/ml) 

ssssss s 

2390 

9R 
P.100 

Data File: /disk3/svdata2/082793.b/27Augl701017.d 

Report Date: 31-Aug-1993 11:44 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Page 2 

Client Name:' 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

——————— —. _ ——____—______________—____ _ -— 

2390 

r? 
J _i

u J 

Data hue; /dlsk3/svdata2/Oe2793.b/27Autl701017.d Pat* 

J i 

i 
P.2 

IUU File: /disk3/s>-*data2/082793.b/27flujl701017.d 

1 Sttrene 

Pate 4 

Scan 232 <5.847 r»in> of 27Au«1701017.d 

3.2* 

2.8-

2.4 

~2.0* 

ol. 6 

-5} •=1.2-

*"0.8 

0.4-

0 0-

* * 

/ » 

1 

. 

1 ^ 

1 . . . 1 ll . 1. 

50 55 60 65 

Ion 104.00 

3

-

2

-; R 

2.8-

2.4-

^2.0 -

\0 

i>1.6-

x . _. -1.2 -

>-

0.8-

0.4-

0 0- ' 

in 

Vi 

5.2 5.5 5.8 6.0 

Hln 

104" 

/ 7 8 

7N 

l 1 . . t. 1 1. 

70 75 80 85 90 95 100 105 

M/Z 

6.2 6.5 

Ion 78. 

1.6-

1.4-

1.2-

_uo-

^0.8 -

X 

~0.6 -

>-

0.4-

0.2-

A 0- J 

00 

* 

in 

_. 

5.2 5.5 5.8 6.0 6.2 6.5 

Min 

Hass 104.00 

Hass 78.00 

• 

3.0-i 

2.5-i 

32-°-* 

klM 

-1.0-: 

""0.5-1 

A 0-i 

5.2 5.5 

, 

5.8 

H.n 

'., 

L 

6.0 6.2 6.5 

/Of 
P.3 

Data File: /disk3/svdata2/082793.b/27Augl801018.d 

Report Date: 31-Aug-1993 11:44 

Page l 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

Data file : /disk3/svdata2/082793,b/27Augl801018 .d 

Quant Type: ESTD 

: 27-AUG-93 16:56 Autotune Date: 

: tjp Inst ID: msd.i 

: 93-38801FX50 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle: 18 

Dil Factor: 50.000 

Integrator: HP RTE 

Sample Matrix: CS2 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004 .d 

Target Version: Target 2.4 0 

Compound Sublist:- all.sub 

Cot-pounds 

1 Styrene 

QUANT SIG 

MASS 

t m 

104.00 

RT 

S S 

5.847 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE (ug/l ) (ug/ml) 

sssssss s 

6921170 51.4 

«!:::: « 

2570 

/O'Z-
P.4 

Data File: /disk3/svdata2/082793.b/27Augl801018.d 

Report Date: 31-Aug-1993 11:44 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Page 2 

Client Name:' 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS:. 

(ug/L or ug/KG) ug/ml 

-Styrene_ 2570 

/<3^ 
Data K.e: /dltk3/svdata2/082793.b/27Aucl801018.d Pate 

5> 

1.5-

1.4-

1.3-' 

1.2-' 

1.1-' 

i.o: 

° *9: 

^0.8-

$> 

3,.;-

>-

0.6-* 

0.5-' 

M : 

0.3-' 

°-2~ 

i 

a 

0.1; 

4 5 

£ 2 

in 

i 

aat 

CO 

6 

/d1sk3/svdata2/082793.b/27Aujl801018.d 

7 . 8 9 10 

•11" 

• 

11 

* 

12 13 14 

Tl 

Oi 
P.6 

Data File: /dlsl^sv*Jata2/082793.b/27fll_tl801018.d 

1 Styrene 

Pace 4 

Scan 232 (5.847 nln) of 27ftujl8O1018.d 

4.0J 

3.5-

3.0-

.2.5-

&2.0-

~1.5-

>• 1.0-

0.5-

0 0-

•-

* \ 

/ » 

1 

• 

1 , . ..ll., . .Il l 

8 \ 97 \ 

l i .

 N

. . 

50 55 60 65 70 75 • 80 85 90 95 

m/z 

Ion 104.00 

4.0-; 

3.5-: 

3.0-i 

^2.5*^ 

<>2.0-_ 

•~ 1.5-

>-

l.o-: 

o.s-: 

fl 0 ' ' 

OO 

m 

5.2 5.5 5.8 6.0 6.2 6.5 

Min 

Ion 78.00 

2.0*1 

1.8*1 

1.5-: 

21.2-1 

ki.o-: 

X 

v

o.8-: >• • 

o.s-: 

0.2-; 

O 0*^ '-

OD 

in 

5.2 5.5 5.8 6.0 

Hin 

104^" 

. 1 1? 

100 105 

6.2 6.5 

Hass 104.00 

Kass 78.00 

4.0-. 

3.0-; 

^2.0-: 

**3 X 

«_. 

A 0-

5.2 5.5 

1 

5.8 

Hin 

6.0 6.2 6.5 

/cer 
P.7 

-1 

Da'ca File: /5970/chem/msd,i/082793.b/27Aug0501005.d _Zjr_*l?r.;'?7\ Page 1 

Report Date: 27-Aug-1993 11:41 rifc-w-t-w*^ 

Energy Laboratories, Inc. 

SEP 0 9 1993 

BJSC. 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle: 5 

Dil Factor: 1.000 

Integrator: HP RTE 

Sample Matrix: CS2 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Aug0501005.d 

Quant Type: ESTD 

27-AUG-93 11:03 Autotune Date: 

tjp Inst ID: msd.i 

93-38796 Primary Backup Section 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

Target Version: Target 2.40 

Compound Sublist:- all.sub 

Compounds 

OUANT SIG 

MASS RT RESPONSE 

CONCENTRATIONS 

ON-COLUMN FINAL 

( ug/l) (ug/ml) 

n:x:::i:::::: === = = = ====== ssssssss ======= 

/Of O 
P.8 
P.9 

Data File: /5970/chem/msd.i/082793.b/27Aug0701007.d 

Report Date: 27-Aug-1993 13:18 

Page l 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Aug0701007.d 

Quant Type: ESTD 

27-AUG-93 12:07 Autotune Date: 

tjp Inst ID: msd.i 

93-38797 Back Tube 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

7 

1.000 Target Version: Target 2.4 0 

HP RTE Compound Sublist:. all.sub 

Compounds 

0UAMT SIC 

MASS RT 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE ( ug/l) (ug/ml) 

:==========: ======== = = = = = =*£ 

/dB 
I 

Data File: /5970/chetv'*.sd.i/082793.b/27ftug07010O7.d Pag

e 2 
p.11 

Data File: /5970/chem/msd.i/082793.b/27Aug0901009.d 

Report Date: 27-Aug-1993 l'5:54 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Aug0901009.d 

Quant Type: ESTD 

27-AUG-93 12:56 Autotune Date: 

tjp Inst ID: msd.i 

93-38798 back 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

9 

1.000 Target Version: Target 2.4 0 

HP RTE Compound Sublist:. all.sub 

Compounds 

sssssssssssssssss 

0UANT SIG 

MASS RT 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE ( ug/l) (ug/ml) 

========= ssssssss sssssss 

lia 
P.12 

/ / / 
P.13 

Data File: /5970/chem/msd.i/,082793.b/27Augl001010.d 

Report Date: 27-Aug-1993 lSr'54 

Page l 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27AuglOO1010.d 

Quant Type: ESTD 

27-AUG-93 13:23 Autotune Date: 

tjp Inst ID: msd.i 

93-38799 back 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

10 

1.000 Target Version: Target 2.4 0 

HP RTE Compound Sublist: all.sub 

Compounds 

• S__=_cx_:= === = = = = = = = = = = rsaxs 

QUANT SIG 

MASS 

c m 

RT 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE (ug/l) <ug/ml) 

_: = = __ = = -_ 

//z-
P.M 

CM 

OL 

1 

s 

. -I 

l 

•a 

aj 

.,....,....,....,....,.. . • , ........ . | ........ . , . . . . , ... . , ............ . . , ... . | ... . | ... . | •.. . , ........ . , . .. . , .. . . , . 

rocM->-ioa-o9i-»-v_)in**r»»>cM*<oo*ooi>«taio*<rrocM» H 

C^CMCMeM-M'«H«J-lr<rH-rtr<r4rHTH0 i *O00O00© 0 

<S~0T*> A 

7 / 3 
P.15 

Data File: /5970/chem/msd.i/082793.b/27Augll01011.d 

Report Date: 27-Aug-1993 1*5:55 

Page 1 

<R 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Augll01011.d 

Quant Type: ESTD 

27-AUG-93 13:49 Autotune Date: 

tjp Inst ID: msd.i 

93-38800 back 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

11 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

0UANT SIG 

MASS RT 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE (ug/l) (ug/mO 

i::::::::::::::::::::::;: : ssssssss •s::::J 

liA 
Data File; /5970/cher*/nsd.l/082793.b/27ftu6llO1011.d Page 2 

CD 
P.17 

Data File: /5970/chem/msd.i/082793.b/27Augl201012.d 

Report Date: 27-Aug-1993 15:55 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/082793.b/27Augl201012.d 

Quant Type: ESTD 

27-AUG-93 14:16 Autotune Date: 

tjp Inst ID: msd.i 

93-38801 back 

/5970/chem/msd.i/082793.b/Styrene.m 

27-Aug-1993 11:40 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

12 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist:. all.sub 

Compounds 

QUANT SIG 

MASS RT 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE ( ug/l) (ug/ffll) 

ssss===================== = s====s= s ssssss s 

lift 
-iLuu 

Data File. /5970/chei»/Asd.l/082793.b/27Ai_gl201012.d F*ie 2 

^ 

**:. 

4.0-

3.8-

3.6: 

3.4-

3.2: 

3.0"! 

2.8: 

2- 6: 

2.4-

S2.2-

2.0 

1.8 

i 1.6 

!

 t.<-. 

i 0.8 

0.6-

0.4 

0.2 

/5970/che*«/*sd.l/082793.b/27Augl201012.d 

J____Lf* ^ 

- , . 

8 6 7 B 9 10 11 

—: nm : 

12 13 14 

TJ 

ioo 
P.19 

1 

Data File : /disk3/svdata2/082793.b/27Augl901019.d nE-fiyjym Page 1 

Report Date: 31-Aug-1993 11:45 •fcwwfft-. 

Energy Laboratories, Inc . 

Cjrp 0 9 ISS3 

BJSC. 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Augl901019.d 

Quant Type: ESTD 

27-AUG-93 17:22 Autotune Date: 

tjp Inst ID: msd.i 

Blank Charocoal Tube Lot #120 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

19 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

QUANT SIG 

MASS RT 

CONCENTRATIONS 

0N-COLUMN FINAL 

RESPONSE (ug/l ) (ug/ml) 

s»sss==================== = :at:m i 

ns 
Data File. /dlsk3/svdata2/082793.b/27Aufjl901019.d Pace 2 

-4* 

ro o 
P.21 

Data File: /disk3/svdata2/082793.b/27Aug2001020.d 

Report Date: 31-Aug-1993 11:45 

Page l 

Data file 

i \JL Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Aug2001020.d 

Quant Type: ESTD 

27-AUG-93 17:49 Autotune Date: 

tjp Inst ID: msd.i 

Blank Spike #1 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

20 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublistr all.sub 

Compounds 

========================== 

1 Styren* 

QUANT SIG 

MASS 

• SS S 

104.00 

IT 

s s 

5.848 

RESPONSE 

sssssss s 

2549220 

CONCENTRATIONS 

ON-COLUMN 

( ug/l) 

BSSS3S 3 

17.4 

FINAL 

(ug/ml) 

ssssxs a 

17.4 

^0 OH o, ^ 1 

\1X> 
P.22 

Data File: /disk3/svdata2/082793.b/27Aug2001020.d 

Report Date: 31-Aug-1993 11:45 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Page 2 

Client Name:' 

Client Sample ID: Bison Engineering 

'i Sample Location: 

• Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

Zi 
P.23 

fti 

. M 

<i 

JQ 

. 

*r> 

1 

X (Ot-O'G) -MBflS.ira 

3 

1 

_S 

^ 

09 IO CM 

OD 09 03 

• I * 

.,., 1 -eOC_lflC.O(__)NO_)II1MOaO_.NOO_1(MOSinNOC O 

S O tf O J Ifl Ift If) tt) V V V t W W M M N N N N 

<9~0-p-> A *• ' 

o o in N 

•H © © © 

:IE^ 
P.24 

~ a 

DaU File: /diskVsvdata2/082733.b/27.V_tf001020.d 

1 Styrene 

Pa<e 4 

l ^ & 
P.25 

Data File: /disk3/svdata2/082793.b/27Aug2101021.d 

Report Date: 31-Aug-1993 11:45 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Met'h Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/082793.b/27Aug2101021.d 

Quant Type: ESTD 

27-AUG-93 18:16 Autotune Date: 

tjp Inst ID: msd.i 

Blank Spike #2 

/disk3/svdata2/082793.b/Styrene.m 

31-Aug-1993 11:34 userl 

27-AUG-93 10:36 Cal File: 27Aug0401004.d 

21 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

uitr_s_-ss:=s 

1 Styrene 

0UANT SIG 

HASS 

ssss 

104.00 

RT 

5.872 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE ( ug/l) (ug/ml) 

II8SSSSI 

2845624 19.7 

esssiaa 

19.7 
P.26 

Data File: /disk3/svdata2/082793.b/27Aug2101021.d 

Report Date: 31-Aug-1993 11:45 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Page 2 

Client Name: 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: 

Client SDG: 082793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

T£5~ 
P.27 

. • 1 

*> w 

a> 

CL. 

•S -

•a CM I 

•s 

• 

A • aJ 

i 

£ JC 

n •2 Fl. Data 

*o 

. 

s-r 

8 

a-t 

O T H CM b* <§ 

I-. 

s ro 

s 

© CM •9 

as IO 

3 

1.0-

0.9-0.8-

0.7-

\o m -^ ro 

• • « • 

o o o. o 

••:•? & 

1 

v 4 

- C M 

•at 

1: 

< 

« 

• 

• 

" • 

^ 

• •» < 7 8 9 10 

Hin 

4 6 ' 6 

. 

J-1 

0.2-

0.1-

• 
P.28 

Q 

DaU File: /dlsk3/svdaU2/082793.b/27ttJt2101021.d 

1 St*#**ne 

Pace 4 

Scan 234 (5.872 nin> of 27Auc2101021.d 

1.6 

1.4-

1.2-

£0.8 

"0.6 

"0.4 

0.2 

0.0 

104^ 

/ •78 

Z

51 

°\ 

. l l l. l 

7 4 \ 

,ll l 

8 \ / * 

. . i I . .1 tf7 

50 55 60 65 70 75 80 

X%/Z 

85 90 95 100 105 

Hass 104.00 

Hass 78.00 

1.5-: 

1.2-; 

pi.oi 

|o.8-: 

-0.5-1 

0.2 

0.0 LAJL 

5.2 5.5 5.8 6.0 6.2 6.5 

Hin 

1.6: 

1.4-i 

1.2: 

*0.6*i 

0.4^ 

0.2-i 

0.0-: 

Ion 104.00 

in 

5.2 5.5 5.8 6.0 6.2 6.5 

Hin 

Ion 78.00 

8.0-: 

7.0-j 

6.0-1 

~5.0-= in

 J,v : 

^4.0-: 

K 

~ 3.0-i 

>-

2.0-; 

1.0-j 

o.o-: 

P 

5.2 5.5 5.8 6.0 6.2 6.5 

Hin 

[Z^h 
P.29 

Report Date 07-Sep-1993 12:34 Page 1 

SEP* 

-A •«-»»,•*«. 

Start Cal Date 

End Cal Date 

Quant Method 

Cal Curve Type 

Origin 

Target Version 

Integrator 

Method file 

Cal Date 

Energy Laboratories, Inc. 3i» 

INITIAL CALIBRATION DATA 

27-AUG-93 08:49 

07-SEP-93 11:33 

ESTD 

Linear 

Force 

Target 2.40 

HP RTE 

/disk3/svdata2/090793.b/Styrene.m 

07-Sep-1993 12:33 

Calibration File Names: 

Level 1: /disk3/svdata2/090793, 

Level 2: /disk3/svdata2/090793, 

Level 3: /disk3/svdata2/090793, 

Level 4: /disk3/svdata2/090793, 

Level 5: /disk3/svdata2/090793, 

b/Sep070101001.d 

b/Sep070201002.d 

b/Sep070301003.d 

b/SepO7O401OO4.d 

b/Sep070501005.d 

2 | 5 | 20 | so | ioo | | | 

Level 1 | Level 2 j Level 3 j Level 4 j Level S j RRF jx RS0/RA2 | 

::s==sss3 | essss=ati I sssssssss | sssssssss I ssssssxss I sssssssxs tssssssssss I 

1060H | 123874| 123575| 120184| 95673| 99277| 0.977 | 

I I— I l _ I I I 
P.30 

Ll 

o yyy 
Data File: /disk3/svdata2/090793.b/Sep070101001.d 

Report Date: 07-Sep-1993 12:36 

P.31 

Page l 

\A 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/090793.b/Sep070101001.d 

Quant Type: ESTD 

07-SEP-93 09:21 Autotune Date: 

rh Inst ID: msd.i 

2ug/ml styrene 

/disk3/svdata2/090793. b/Styrene.m 

07-Sep-1993 12:33 

07-SEP-93 09:21 Cal File: Sep070101001.d 

1 Calibration Sample, Level: l 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

1 Styrene 

QUANT SIG 

MASS 

CSS3 

104.00 

RT 

S S 

5.763 

RESPONSE 

ssssssss 

212028 

CONCENTRATIONS 

ON-COLUMN 

< ug/l) 

SSSSSS3 

4.2 

FINAL 

(ug/ml> 

4.2(M) 

QC Flag Legend 

M - Compound response manually integrated. 
P.32 

1 

s 

•3 

wt © 

8 

o 

3 

r-ii© 

i CM 

J * 

_>. t o 

M ON 

*T*I ~ 

5t £in ~ 

- $ " 7. 8 8 

S rl *S « | ? 

k •• 3 « C t 

«§ ,3 £ <J! <S **S 

.ISA 
Data File: /disk3/svdata2/Q90793.b/Sep070201002.d 

Report Date: 07-Sep-1993 11:48 

P.33 

Page l 

R 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/090793.b/Sep070201002.d 

Quant Type: ESTD 

07-SEP-93 09:44 Autotune Date: 

rh Inst ID: msd.i 

5ug/ml styrene 

/disk3/svdata2/090793. b/Styrene.m 

07-^Sep-1993 11:48 

07-SEP-93 09:44 Cal File: Sep070201002.d 

2 Calibration Sample, Level: 2 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

SSSBSSSSSSSSSSSSSSSSSSSSSS 

1 Styrene 

QUANT SIG 

MASS 

ssst 

104.00 

RT 

s> 

5.763 

RESPONSE 

ssssssss 

619371 

CONCENTRATIONS 

ON-COLUMN 

< ug/l) 

sssasea 

2.5 

FINAL 

(ug/ml) 

SSSSSSS 

2.5 

\£>Z:-
Data File; .dlsk3/svdata2/090793.b/Sep070201002.d 

Date : 07-SEP-93 09:44 

Instrument : nsd.l 

Sanple ID : Bison Entlneerlng 

Column phase : XTI-5 Restek 

Volute Injected <uL) : 1.0 

Colum diameter : 0.25 

'' '" 

0*' 

0 

1.2 

1.1 

1.0 

0.9 

0.8 

0.7 

? 0.6 

>*_-» 

> -

"0.5 

0.4-

0.3-' 

0.2-' 

0.1 

'-^J Jkli 

rs. 

(9 

r«-

L 

/dlsk3/svdata2/090793.b/Sep070201002.d 

*•*• ' » »****••» ^»* > • •*»» ,i*w » 

t ... . , 

r a 

*-** * — * --ni u-i ____ 

Jlln. 

10 n 

Pace 2 

^^^V********* 

12 13 14 
P.35 

Data File: /disk3/svdata2/090793.b/Sep070301003.d 

Report Date: 07-Sep-1993 il:48 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/090793.b/Sep070301003.d 

Quant Type: ESTD 

07-SEP-93 10:43 Autotune Date: 

rh Inst ID: msd.i 

20ug/ml styrene 

/disk3/svdata2/090793.b/Styrene.m 

07-Sep-1993 11:48 

07-SEP-93 10:43 Cal File: Sep070301003.d 

3 Calibration Sample, Level: 3 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist:. all.sub 

Compounds 

1 Styrene 

0UANT SIG 

MASS 

SSS S 

104.00 

RT 

ss 

5.764 

RESPONSE 

ssssssss 

2471506 

CONCENTRATIONS 

ON-COLUMN 

( ug/l) 

sssssss 

15.8 

FINAL 

(ug/ml) 

15.8 
Data FIU. .dlsk3/svdata2/090793.b/Sef>070301003.d 

Date : 07-SEP-93 10:43 

InstrtMent : nsd.l 

Sample ID : Bison EntIneerIng 

Column phase : XT I-5 Restek 

Volwe Injected (uL) : 1.0 

Page 2 

i - .... i 

Column diameter : 0.25 

5.2-

5.0-: 

4.8 

4.6 

4.4 

4.2 

4.0*: 

3.8 

3.6 

3.4-: 

3.2 

3.0 

2.8 

£2.6-| 

v

2.4-

^2.2-. 

?.o 

1.8 

1.6 

1.4 

1.2 

1.0 

0.8: 

0.6 

0.4 

0.2 S-i LL 

/dlsk3/svdata2/090793.b/Sep070301003.d 

UlILJi- * m>»••»••>•- —• 

I ... . , 

9 10 

• •» K. 

JUn_ 

11 12 13 14 
Data File: /disk3/svdata2/0£0793.b/Sep070401004.d 

Report Date: 07-Sep-1993 11:48 

P.37 

Page 1 

Data file 

Lab. Id. 

13 Inj Date 

Operator 

Smp Info 

—. Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/090793.b/Sep070401004.d 

Quant Type: ESTD 

07-SEP-93 11:05 Autotune Date: 

rh Inst ID: msd.i 

50ug/ml styrene 

/disk3/svdata2/090793.b/Styrene.m 

07-Sep-1993 11:48 

07-SEP-93 11:05 Cal File: Sep070401004.d 

4 Calibration Sample, Level: 4 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublistt all.sub 

Compounds 

1 Styrene 

QUANT SIG 

MASS 

ssss 

104.00 

RT 

ss 

5.777 

RESPONSE 

ssssssss 

6009200 

CONCENTRATIONS 

ON-COLUMN 

( ug/l) 

SSSSSSS 

41.0 

FINAL 

(ug/ffll) 

sssssss 

41.0 

\&j 
I •.a 

% 

Data File: /dlsk3/svdata2/090793.b^ep070401004.d 

Date : 07-SEP-93 11:05 

Instrument : nsd.l 

Sample ID : Bison Engineering 

Column phase : XTI-5 Restek 

Volume Injected (0.) : 1.0 

Pace 2 

Column diameter : 0.25 

9.6 

9.2; 

8.8-! 

8.4 

8.0 

7.6 

7.2 

6.8*; 

6.4 

6.0 

5.6: 

5.2 

S4.8 

•4.0; 

3.6 

3.2 

2.8 

2.4 

2.0 

1.6; 

1.2 

0.8 

0.4 

VJl U. 

R 

/dlsk3/svdata2/09O793.b/Sep070401O04.d 

U L L 

• 1 

6 

^ 

10 11 12 13 14 

Hin 

Ico 

loo 
P.39 

Data File: /disk3/svdata2/0,90793.b/Sep070501005.d 

Report Date: 07-Sep-1993 12:33 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/disk3/svdata2/090793.b/Sep070501005.d 

Quant Type: ESTD 

07-SEP-93 11:33 Autotune Date: 

rh Inst ID: msd.i 

lOOug/ml styrene 

/disk3/svdata2/090793.b/Styrene.m 

07-Sep-1993 12:33 

07-SEP-93 11:33 Cal File: Sep070501005.d 

5 Calibration Sample, Level: 5 

1.000 Target Version: Target 2.40 

HP RTE Compound Sublist: all.sub 

Compounds 

ssssssssssssssssssssssssss 

1 Styrene 

QUANT SIG 

MASS 

8SS8 

104.00 

RT 

K S 

5.752 

RESPONSE 

SSSSSSSS 

9567329 

CONCENTRATIONS 

ON-COLUMN 

< U9/D 

SSSSSSS 

94.2 

FINAL 

(ug/ml) 

SSSSSS S 

94.2 

vm 
I :'l__ . 

Data Fill.: disk3/svdata2/090793.b/Sep070501O05.d 

Date : 07-SEP-93 11:33 

Instrument : nsd.l 

Sample ID : Bison Entlneering 

Column phase : XTI-5 Restek 

Volume Injected <uL> : 1.0 

I Page 2 

Column diameter : 0.2S 

% 

1.6 

1.5 

1.4 

1.3; 

1.2 

1.1 

1.0 

r»» 

-a o.s 

.0.7 

0.6 

0.5 

0.4; 

0.3 

0.2 

0.1-

/disk3/swdata2/090793.b/Sep070501005.d 

8 r*. 

I l l JU 

10 11 12 13 14 

Hin 

o 
P.41 

I ~ 

Data File: /5970/chem/msd.'i/090793.b/sep070101001.d^__. .. Page 1. 

Report Date: 08-Sep-1993 08:09 iiiiC:- --

! 

c-rp .'j -\ •;• .'• 

Energy Laboratories, Inc. D]3«.,.. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/090793.b/sep070101001.d 

Quant Type: ESTD 

07-SEP-93 13:08 Autotune Date: 

tjp Inst ID: msd.i 

Styrene 6mg/tube Desorption Efficiency Test 

Charcoal Tube Lot 120 

/disk3/svdata2/090793.b/Styrene.m 

07-Sep-1993 12:33 

07-SEP-93 11:33 Cal File: Sep070501005.d 

1 

50.000 Target Version: Target 2.40 

HP RTE Compound Sublist:' all.su b 

Data fil e 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottl e 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Compounds 

sssss==sssssssssss=sssssss 

1 Styrene 

0UANT SIG 

MASS 

csss 

104.00 

RT 

ss 

5.762 

RESPONSE 

SSSSSSSS 

3859003 

CONCENTRATIONS 

OM-COLUMN 

( ug/l) 

sssssss 

36.7 

FINAL 

(ug/ml) 

sssssss 

1830 

/ < * 

£0* - u *% 

^y/ o 
P.42 

!L 

fl 

Data File: /5970/chem/msd-.i;/090793.b/sep070101001.d 

Report Date: 08-Sep-1993 08:09 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Client Name: 

Client Sample ;ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: Charcoal Tube Lot 120 

CAS NO. COMPOUND 

Client SDG: 090793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ral 

Page 2 

14 \ 
Data1 

•. i._.:i___i i. 

/5970/chem/msd.i/090793.b/sep070101001.d 

ri2> "v • * 

Pat. ' 

4.8-

4.6-

4.4-

4.2-

4.0-

3.8-

3.6-

3.4-

3.2-

3.0-

2.8-

^2.6-

§2.4-

>-2.2-

2.0-

->.B-

"1.6-

1.4-

1.2-

1.0-

0.8-

0.6-

0.4-

0.2-

• 

in 

| 

** 

' 

1 

v__ I 4 5* 6 

/5970/chem/msd. l/090793.b/sep070101001.d 

7 8 9 10 

M m 

.*—- . 

11 

A 

i 

12 

i _,._. _ 

13 14 

CO 
P.44 

DaU File: /5970/cheii/Md.l/090793.b/sep070101001.d 

1 Sty-ene 

Pace 4 

Hass 104.00 

Hass 78.00 

1.2*-

i.o.-i 

s°«6i 

*o.4-: 

"0.2^ 

0.0--

fl 

1.2 

1.01 

0.8 

\_0 

>-0.4*| 

0.2 

0.0 

/ » 

Scan 225 (5.762 min) of sep070101001.d 

7 8\ 

104' 

^ 7K 

..ll.. -Ill 

•N *N 

50 55 

• i i 

S" 

60 65 70 75 80 85 90 95 100 105 

___ _ 2& 

5.2 5.5 5.8 6.0 6.2 

Hin 

1.2: 

1.0: 

X 

Zo.4-

0.2: 

0.0-

Ion 104.00 

5.2 5.5 5.8 6.0 6.2 

Hin 

7.0-* 

6.0-. 

5.0-: 

-»4 0-

S3 0-

X°aV . 

N_» >-2.o-: 

1.0-. 

fl ft-. 

Ion 78.00 

• • 

1

xn 

1 

v - 1 

5.2 5.5 5.8 6.0 6.2 

Min 

••& & 
P.45 

Data File: /5970/chem/msd*.i/090793.b/sep070301003.d 

Report Date: 08-Sep-1993 08:09 

Page 1 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Sample Matrix: CS2 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/090793.b/sep070301003.d 

Quant Type: ESTD 

07-SEP-93 14:49 Autotune Date: 

tjp ; Inst ID: msd.i 

Styrene 6mg/tube Desorption Efficiency Test 

Charcoal Tube Lot 120 

/disk3/svdata2/090793.b/Styrene.m 

07-Sep-1993 12:33 

07-SEP-93 11:33 Cal File: Sep070501005.d 

3 

50.000 Target Version: Target 2. 

HP RTE Compound Sublist: all.sub 

40 

Compounds 

1 Styrene 

CONCENTRATIONS 

0UANT SIG ON-COLUMN FINAL 

MASS RT RESPONSE (ug/l) (ug/nl) 

SSS* C33 ssssssss 

104.00 5.750 4131054 

SSSSSSS 

39.4 

^ fr.^r 

\o(k 
P.46 

( 

i 

H 

i 

Data File: /5970/chem/msdii/090793.b/sep070301003.d 

ReDor Reportt Date Date':: 08-SeD-199 08-Sep-19933 08:0 08:09 9 

Page 2 

Energy Laboratories, Inc. 

TARGET COMPOUNDS 

Client Name: 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: Charcoal Tube Lot 120 

CAS NO. COMPOUND 

Client SDG: 090793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

-Styrene_ 1970 

••4-S" 
P.47 

• 

ff 

t 

aa- « l 

tt 

Cu 

3 

..... 

0793.b/sep070301003.d 

-.1 | 

1 

.. 

-a 

aJ 

• *3 

' 

# 

' 

' 

. 

< 

• 

< 

"O 

. 

ro 

8 S o 

r » • • 

•2. 

ro 

"v. 

—« 

*D 

M i 

3 

Is-

•5 

.(OSZ'S) *uajfi*>s — ? 

f 

* 

I 

i J 

. 

wl 

• •*> 

ar* 

mw> 

r-l 

„ © 

. 1 

-ff. 

r 

•CD 

-rv. 

-ve 

• 

- I B 

-•» 

"•V-AT o " » v i 4 CM O CD v i 4r CM © » VO *» CM O CD vO • * CM. O CD vP *» CM O CO vO • » CM © OO vO • » CM 

N\V ' o o v» «s\o in in » w «> **•»» * " M n M " N N N N N d H H H H ° ° ° ° 

(*=U)T*) A -4*

 f 

; f^Rs, 

• 
P.48 

-

m . 

Data File: /5970/chem/msd.l/090793.b/sep070301003.d 

1 Styrene 

2.0H 

1.8-

1.5-

^1.2-

Si-o3o.8-

"0.5-

0.2' 

0.0-

Scan 224 (5.750 min) of sep070301003,d 

104^ 

• 

i 1 

7*\ 

1.. ..il. . .Ml i. ... i. .. . 1 f 

5055606 5 70 758085909 5 100 105 

m/z 

Ion 104.00 

2.0, Mg1.8-i w 

1.K 

~1.2" 

§1.0-

*0.8-

"0.5 

0.2 

0.0 

': 

{ , 

5.2 5.5 5.8 6.0 6.2 

Min 1 

Ion 78.00 

1.0- •? 

0.8-

20.6-

wl 

*0.4-

>-

0.2-; 

A fx'- . _ L I . 

5.2 5.5 5.8 6.0 6.2 

Hin 

H 

Hass 104.00 

Hass 78.00 

2.0-

1.6-i 

31.2: 

30.8-: 

*-o,4-: 

0.0-— > 

Pace 4 

» 

5.2 5.5 5.

1 

8 6.0 6.2 

Hin 

' .^ 
P.49 

Data File: /5970/chem/msd-.i.'/090793.b/styr6mg9793a.d 

Report Date: 08-Sep-1993 08:10 

Page 1 

1 

• i 

Data file 

Lab. Id. 

Inj Date 

Operator 

Smp Info 

Misc Info 

Comment 

Method 

Meth Date 

Cal Date 

Als bottle 

Dil Factor 

Integrator 

Energy Laboratories, Inc. 

BNA QUANT RATIO REPORT 

/5970/chem/msd.i/090793.b/styr6mg9793a.d 

Quant Type: ESTD 

07-SEP-93 15:55 Autotune Date: 

rh Inst ID: msd.i 

Styrene 6mg/Tube Desorption Efficiency Test 

Charcoal Tube Lot 120 

/disk3/svdata2/090793. b/Styrene.m 

07-Sep-1993 12:33 

07-SEP-93 11:33 Cal File: Sep070501005.d 

4 

50.000 Target Version: Target 2. 

HP RTE Compound Sublist: all.sub 

40 

Sample Matrix: CS2 

Compounds 

&_S£3ISE3SS=:S 

1 Styrene 

QUANT SIG 

HASS 

SS33 

104.00 

RT 

ss 

5.762 

£"-££. 

c°°° 

CONCENTRATIONS 

ON-COLUMN FINAL 

RESPONSE ( ug/l) (us/ml) 

ssssssss sssssss sssssss 

3900355 37.1 1850 X3/-£^orrro 

X/0° 

* fJ.S% 0£L 

J 4© 
P.50 

Data File : /5970/chem/msd<i/090793.b/styr6mg9793a.d 

Report Date: 08-Sep-1993 08:10 

Energy Laboratories, Inc . 

TARGET COMPOUNDS 

Page 2 

Client Name: 

Client Sample ID: Bison Engineering 

Sample Location: 

Lab Sample ID: 

Sample Matrix: CS2 

Analysis Type: SV 

Data Type: MS DATA 

Misc Info: Charcoal Tube Lot 120 

Client SDG: 090793.b 

Sample Date: 

Sample Point: 

Date Received: 

Quant Type: ESTD 

Level: LOW 

CAS NO. COMPOUND 

CONCENTRATION UNITS: 

(ug/L or ug/KG) ug/ml 

•Styrene_ 1850 
P.51 

\-*>. 

-a 

A 

-° 

ft 

% 

o 

** I 

•<2$.rs> **-** S 

N_D 

vO 

*«c 

vA 

Cvi 

v_D 

O 

vO 

CD 

I D 

\_D 

m 

-*r 

m 

CM 

i n 

o 

LO 

CD 

•»» 

MT> 

• ' C •<e 

CM 

-*r 

O 

-«r 

OD 

r*> 

vo 

m 

*>r 

t*i w ro CM CM CM CM CM »-« • H «H »-* •.H O O O O 

(WI*) A 

/<3D 
P.52 

Data File: /5970/chem/m-rf.t/090793.b/styr;6mt9793a.d 

1 Styrene 

Page 4 

Hass 104.00 

Hass 78.00 

1.6-. 

vO 

so.8: 

K 

*** 

>-0.4-

0.0-

1.8 

1.6 

1.4 

1.2 

1.0 

S0.8 

:o.6 

0.4 

0.2 

0.0 

S / * 

Scan 225 (5.762 mln> of styr6*«9793a.d 

7

°\ 

104" 

63\ 

...I. , 

^ 

50 55 60 65 

• 

70 

.ll I 

•N

 97\ .06 V. 

75 

m/z 

80 85 90 95 100 105 5.2 5.5 5.8 6.0 6.2 

Hin 

1.8-

1.6-

1.4-

1.2-

31.0-

S0.8-

;o.6-

0.4-

0.2-

n nIon 104.00 

i 

1—CM 

vD 

r*. 

. 

in 

I . 

5.2 5.5 5.8 6.0 6.2 

Mla 

9.0-; 

8.0-i 

7.0-; 

6.0-j 

gs.o-; 

?4.o-; 

••-3.0-; 

2.0-: 

1.0-. 

0.0-W; 

Ion 78.00 

., . . 1 

f-<5_ 

in 

{ , 

5.2 5.5 5.8 6.0 6.2 

Hie 
P.53 

APPENDIX E: NOMENCLATURE, FORMULAE AND LAB 

METHODS 

n ~~~ 

fS2_ 
P.54 

FORMULAE 

is 

1. Dry Gas Volume • Corrected to STP (40 CFR 60. ADD. A. EQ. 5-1) 

*.(.€« - V m 

+ mi 

13. 6 

P.t* 

Y is obtained from post test meter calibrations shown in Appendix E. 

2. Water Vaoor Volume - Corrected to STP (40 CFR 60. ADD. A. Eo. 5-2) 

*~-'-ft)ffi?) 

Note: Wte = Vt e p w 

3. Stack Gas Moisture Content (40 CFR 60 App. A, Eq. 5-3, modified) 

fl.. -

f

v(sttn 

wa v + v 

4. Stack Gas Drv and Wet Molecular Weight (40 CFR 60 ADD. A. Eo. 3-1. 2-5) 

M, = 0.44 0 (%CO,) +0.320 (%0,) +0.28 0 (%i\72 + %CO) 

Mt"Md(l-Bvs) +18. OB 

ws 

I? 
P.55 

5. Average Stack Gas Velocity (40 CFR 60 ADD. A. Eo. 2-9) 

v.-JCC. 

p~p 

Evsp 

72 

T

tUr-g) 

N

 psMs 

6. Average Stack Gas Wet Volumetric Flow Rate 

O.= 60v,A. 

7. Averaoe Stack Gas Drv Flow Rate Corrected to Standard Conditions (40 CFR 

60 ADD. A. Eo. 2-10. modified) 

O.ed-O. (l-B„,) T9td P. 

r

*(«vy) Pstd 

8. TSP Particulate Concentration Corrected to Standard Conditions (40 CFR 60 

ADD. A. EQ. 5-6. modified) 

C

mK 

a =2.205X10-*-—-2— 

* J * V _ __. 

3 __?!___ C. =15.43x1 0 „ 

a(std) 

Note: C i b = Ib/dscf 

CiQf = grains/dscf 

mn = mg 

'/S4-
P.56 

f l 

9. TSP Emission Rate per Hour 

£hr ac.0, t d 60 

10. Percent Isokinetic Sampling Variation (40 CFR 60 ADD. A. Eo. 5-8) 

+ mtmtrrr\ ".mlafitt * ___•/* 100 

I% = 

l

<r,arg)

 vm[Btd)r

0td 

r.«i*-.e V.6 0 (I-B„ ) 

i<55 
P.57 

- I 

NOMENCLATURE 

Stack test standard conditions: 

Pressure - 29.92" Hg 

Temperature - 68°F 

An Nozzle cross sectional area; ft2 

A, Stack cross sectional area; ft 2 

B M Water vapor in the gas stream; volume proportion 

C, Concentration of acetone blank residue; mg/g 

Cp Pitot tube coefficient; 0.84 for type S pitot tube 

C, Concentration of stack gas particulates; dry basis corrected to standard 

conditions; Ib/dscf (pounds/dry std. ft3) or gr/dscf (grains/dry std. cubic 

foot) 

Dso Aerodynamic diameter of particles with 50 percent probability of cyclone 

penetration; p 

E^ Emission rate per hour; Ib/hr 

I Percent sampling rate variation, where 100% = ideal isokinetic 

conditions 

KD Pitot tube constant; 85.49 ft/se c (Ub/lbmole) {"Hcf) \ 

m. Acetone residue weight after evaporation; mg 

Md Stack gas dry molecular weight, from Fyrite or Orsat analysis; Ib/lb-mole 

mf Filter weight gain; mg 

m„ Total weight of collected particulate; mg 

m

n. PMIO Total weight of collected PM10 particulate; mg 

Mw . Molecular weight of water; 18.0 lb/lb mole 

M, Wet molecular weight of stack gas; lb/lb mole 

n 
P.58 

-• 

• • ' 

Jl 

T 

--

•". -J 

-

Pb. 

P, 

P. 

P«d 

Q. 

Q.td 

T„ 

t. 

^"•(•vg) 

T.td 

R 

vte 

v m 

V m (t t d ) 

v. 

V w («td| 

wk 

Y 

Ap 

ST 

V. 

Barometric station pressure (at sampling site); in. Hg 

Stack static pressure; in. H20 

Absolute stack pressure; in. Hg 

Absolute pressure @ standard conditions; 29.92" Hg 

Average stack gas wet volumetric flow rate; cfm (ftVmin) 

Average stack gas dry volumetric flow rate, corrected to standard 

conditions; scfm (dry standard ftVmin) 

Average dry gas meter temperature, abs.; °R 

Average stack gas temperature, °F 

Average stack gas temperature, abs.; °R 

Absolute temperature @ standard conditions; 528°R 

Ideal gas constant; 21.85 in. hg-ft3/°R-lb-mole 

Total volumes of water collected in impingers; ml 

Indicated volume of gas sample measured at dry gas meter; def (dry ft3) 

Volume of gas sample measured at dry gas meter, corrected to standard 

conditions; dscf (dry standard cubic feet) 

Stack gas velocity from Method 2 

Volume of water vapor in the gas sample, corrected to standard 

conditions; scf (standard cubic feet) 

Weight of collected water; g 

Dry gas meter calibration factor 

Stack velocity stagnation pressure recorded by the probe's type S pitot 

tube 

Average pressure differential across orifice meter at control box 

Stack gas absolute viscosity; p poise 

isv 
P.59 

i3 

pw Density of water; 0.9982 g/ml (0.0022 lb/ml) 

6 Total sampling time; min. 

13.6 Specific gravity of mercury 

60 Seconds per minute 

-|S8 
ua ut no i n t«t i«i 

^ ^ ^ -.*---.... . .._^_»._N . -N, ••_ ••* * \ • - --• - - — ?•- --w ^ .*._•_ _^. A._^ . .«_ •-_, *_, .|. M 

18

 "M M 

PSYCHROMETRIC CHART 

NORMAL TEMPERATURES 

SI METRIC UNITS 

Baromatrlc Pratsura 101.325 kPa 

SEA LEVEL 

R«p«odue*4 by p*rml__.on of Ctili Corporation. 

I l l 

tal—a 0*C frafwiln taxi C.llnf.f Club . Itam «>•. M In 

O i l 

Off talk )•*?«___•• 

» It I M 

mprnttmr *C \ 

• I I 

Valam. ml/k, Orr «k 

\ 

tM 

C*r*+t Otmaaaa Clfaaai— ttt% 

Figure 23.2 Psychromctric Chart b> 
ur^-s j uj:*orw riuiu rii:&\ji LAJ_6,' _W. »0 144^ 66 53 

P.61 

fuo3/0'J3 

SKC Gwufe to NIOSH/OSHA Air Sampling Standards 

1 1 I 

: 

. 

\ 

\ 

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t 

ptrntutruman 

l^iO-PM"******-* 

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Saart** 

M W 

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?|-m« 

sue-** 

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S*t*««« 

STf-ra 

SOrfKtCrtJt 

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SaoeuM (Pieue-ytx Eurmni 

SMC-U< (S M Out Too/ crPiientu ttuiw-a) 

Sutttnl 

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Stfoacr* 

StJUM-TOOM 

Sutor**6<M 

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SufclB-ndt 

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SufcreAcd 

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SA«y<FV«rdt 

s.mi(SMO«i_Hci; 

SAST 

2_«i-T 

Toe .FU •*»•*»») 

10c (RttoiraCat. Non-AMUIM.il) 

Tte (Tea.. *an-A£«*lilQ-m| 

TMWI 

Trunin 

Tuaua. tmt. Over Ooa 

TU (S M Z«-rotMn>M&ae)«nM| 

no* 

Trton c-wo*r«eirten Paoue** (S M Ptiytmbn* 

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T-Anj-k 

Ttfenuo 

Ttt_c__n» HmAmid t 

Ttteu n Huift-viO* ( u T«| 

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TMOUBO 

o-T_/*___n»* 

Tirprmin 

T_-fA.«yl». Myd-BCVUtM 

•' *.-;*i--»71 ;f.'M-*'»'';'.«-"-^ 

Ao4*io^ l*ol*pr*tfW 

OSHA USSE B 

OSHA M$22Q 

OSHA MISSUS 

NOSH K M 

OSMA vsatt 

MOSH ISW 

OSHA a 

OSHA MSS100 

MOSH Mi l 

OSHA M3B7 t 

OSHA I t 

OSHA t 

MOSH MO D 

MOSH 1501 

CSHA wisrcs 

OSHA 0_&2SS 

OSHA MSSIO * 

OSHA USS107 

OSHA MSS127 

OSHA mssza 

OSMA tWSSl M 

MOSH 41SXI) 

OSHA S10 4 

OSHA ©10 7 

MOSH K0 4 

MOSH KS244) 

OSHA IA323 M 

OSHA 0*2.2 0 

OSHA WS1V. 

OSHA IMIS2322 

NCSH 1CS1J4) 

N-OSM 79CS 

OSHA OI13 

OSHA DICSM 

NIOSH 1(117) 

NIOSH KSJ«) 

OSHA MSZ__9 

NSSH $001 

OSHA MS324 

NOSH » J 

OSHA MS9030 

OSHA IWS_<_-t 

OSHA OISTI17 

MOSH STSM1) 

OSHA MS2J2S 

MOSH 

OOM MS2127 

UIJ4W/ 

MOSH 7(S30t| 

MOSH 7300 

OSHA c m 

MOSH «S1|7) 

OSHA MISOB 

OSMA MSS34 

OSHA 1463333 

MOSM K31 

OSM w-cms 

OSHA MIS141S 

XCSM l!S2T) 

—r-z—:— • T^T-.. ,-• 

S A M 

Aime r *•«-*•* « 

TWA Unix, 

m m ) (ee<-) 

0.1 

330 oVn -

100 

• 

0.U nViTtM 100 STU 

io ioo sm 

SO 109 

Jtcgm'STE l 

t i * 

t l * 

3 SSTel 

I SSTS. 

Oi 

| 1000 

• 

.01 

C.1 

1 W]F(rT 

i lAQilYr 

lugn-r* 

1 ISSTr. 

3 10 STC 

10 nj**** 

zBQIMr 

Ifnyml 

mewSa->M> 

OJ-VK0.1 RtM1 

J l 

J9«tm> 

e i 

1 

P L 

VU.-OTM. 

mACoiix j 

10 

41 

a 

10 

12 • 

4H 

I N 

1«0 

12 0.73 

10 3 

10 

10 10 

41.000 

to 

N 

100 

to 

<0 IS 

24 3 

IM 

34 

S 

S 

'.H 

-

M0 

M 

•0 

3 

24 U 

119 

ICS 

171 

7St 

MO 

K 

ICO 

S!0 

•no 

723 

723 

M0 

4M 

4tO 

410 

<M 

30 

u 

IS 

1 N G 

nll l (•RlwilHp 

IWACtWn a 

KCS0I 

200 

too 

20(50) 

200 

1CC0 

1300 

3000 

» 

2o;toi 

23 

NIM) 

<o 

2C0 

1009 

K U » 

1000 

IOOO 

iceo 

1C00 

ten 

K0 

•.too 

20 

1300 

200 

20C0 

250 

1CC0 

I* 

100 

1000 

3000 

1K0 

It**} 

2C00 

ICOO 

1S00 

3ooe 

1000 

2S00 

xoo 

2SO0 

1000 

IOOO 

1000 

•oco 

20M 

' 

10M 

2C0 

tuo 

Ttaw 

TWA CtfHnt 

(tool (mlAI 

«)J) 

4 

4 

W J ! 

1 

1 

2 

U 

IS 

Kil l IS 

1 

e,-3j| io 

M 

2 

l i 

l i 

1.3 

1 13 

2 13 

1 

1 

S 

1 

1000 I ! 

2 

4 

« 

« 

lis 

100 4 13 

l i 

1.1 

II 

17 

IXC 

l*_r_n 

i 

13 

AMt)-Uc«l 

Uta-M 

oc-no 

NVW 

NVV 

cm 

OK 

CCFO 

OC-fTO 

AAS 

i-nc 

KKC-IW 

GC-no 

COW 

0C-F» 

ecro 

CJI 

H".C-UV 

nnc 

•OIC 

HHC-UV 

m.c 

T1TRA 

c 

e • 

c 

OCTC 

« » 

c 

NVI4 

S7IEC 

TITSA 

e 

c 

C-J 

CC-FW 

5= 

MPIC4JV 

HW.C-UV 

I W 

GR 

ex 

Ofl 

PES 

GR 

GOTO 

AA 

CP-ACS 

AA 

AA 

AA 

GO^PO 

| FFO 

oc-no 

GC 

| NVM 

1 CC 

. S.M 

• K C CtlKcUn* l«ulp>OOTl «wl P»fll Minta r 

R.TI2S-7 

ST22f)J 

8TOt-lM2 

i'rat-iiMi 

ST22S41 

ST22W1 

aT22!<9 

FVTm- 7 

wns-7 

ST 221-71 

5T2»4t 

ST rt-13-N 

ST 221-31 

NASXC 

FIT 225-7 

FI_TI»-; 

aras-r 

HT.23-S 

•ipns-st-i 

SCN22.-M 

R.T22S-I 

(MP22S-3l-t 

ST22S4C' 

aTais 

Kl022Ha 

soa'-as 

NP22M*-! 

WP223-X-2 

rwT22S-S 

S7*3t-'0a 

R.T2JM 

ST22S--.C43 

MP 133-31-1 

SB 231-3 

sr-m-it 

RT22S-7 

RT 223-7 

aTZH-t-a 

HLD23t4 

aras-i-oi 

aoj-H-i 

ri.T22t-M1 

H.T22J-7 

RT2-H-3 

aT22M-0l 

ST22t-3C-:i 

F1.T22J-J 

FVTIB4 

r.T32t-i 

ST 221-11 

ST22M I 

ST22M0- H 

ST 2H-JO-14 

R T 123-11-07 

SPC 223.21 

aT2_S-7 

araj-s 

34 

17-il 

27-21 

27^1 

v-a 

27-2S 

34 

14 

14 

jf- a 

i7-n 

27-2t 

27-21 

14 

34 

34 

34 

32 

17 

34 

12 

27-a 

34 

34 

42 

31 

32 

34 

27-21 

34 

27-a 

31 

a 

IT-H 

3* 

34 

34 

34 

34 

34 

14 

34 

34 

94 

27-» 

34 

34 

34 

v-a 

tf-» 

27-0 

17-21 

34 

V 

34 

* 

HID Mi l 

H022S-1 

H.02S-3 

R022S-2 

HU) 223-2 

W.032S-2 

hlDJ-fH 

NL9U M 

IT 223-22 

M.022S-2 

IT 223-12 

RT22S-II0 

IT 223-22 

IT 223-23 

HO Si- ) 

I U 233-2 

*T 223-22 

SI 212-03 

HLO 233-1 

HO 223-3 

F/XU3 223-1 

CTCJH-01-a 

FM.022S-1 

CYC223-0l-*3 

HO 223-3 

MJ0 22M 

M.0 223-2 

HO 223-3 

H O 223-3 

H C 223-3 

HU) 223-1 

H O 221-1 

HO 225-2 

HO 229-3 

34 

34 

34 

94 

14 

14 

34 

34 

13 

14 

32 

1 34 

321 

" u" 

14 

34 

12 

42 

3« 

14 

M 

M 

n 

i t i 

34 

34 

34 

3< 

34 

34 

34 

"» 

34 

4<

-

)a?o 
\)l-U- Jjj UJ:4bPM ENEsC-y LABS. INC. TO 14496653 P002/003 

Sample Collection Media 

Sorbent Sample Tube

Sorbent Sample Tubes-Air Sampling Guide Reference Tab

Catalog Number 

22641 

22641GWS 

22649 

2264942 

226-10 

226-1042* 

226-1043 

226-10-04 

226-1006* 

22&-11 

226-12-04 

226-12-05 

226-12-06 

226-12-13 

226-14 

226*1442 

225-15 

226-15GWS 

226-16 

226-1642 

226-17-1A 

226-17-3A 

226-17-4* 

226-18 

226-19 

226-21 

22S-22 

226-23* 

226-24 

226-25 

226-27 

226-28 

226-29* 

226-30 

2264042 

226-3043 ' 

226-3044 

2264045 

226-3006 

22S4O07* 

226-3048 

22640-16 (OVST 

22640-18* 

226-31* 

22642* 

22645 

2264541* 

Sorbent 

Uusf tM tr+rmtty trttltf-tf 

Charcoal. Coconut 

Charcoal, Coconut 

Charcoal, Coconut 

Charcoal. Coconut 

SifcaGel 

SIUCA G a 

SIUCA GEL 

Silica Gel 

SILICA GEL 

Alumina 

Molecular Sieve 4A 

Molecular Sieve 5A 

Molecular Sieve SA 

Molecular Sieve 13X 

Silica Gel 

Silica Gel 

Silca Gel 

Silica Gel 

Charcoal, Coconut 

Charcoal, Coconut 

Hopeafite 

Hopcafite 

CHR0M0S0RBP 

Alumina 

Alumina 

Molecular Sieve SA 

Silica Gel 

XAO-2 

. Charcoal, Coconut 

[

Charcoal, Coconut 

Charcoal, Coconut 

XAO-2 

Soda Ume 

CARBON BEADS 

xad-2 

fxad*2 

L xad-2 

xad*2 '"•'' 

xad-2 

xad-2. 

xad-2 

XAO-2 

xad4 

xad-2/Fiter 

XAO-2 

T CARBON BEADS 

L Humidifier 

CARSON BEAOS 

Tenax 

Tenax 

P"Or » lairx&iq. 

'*C- 5"1- C.33C.r+a £*-^c» -*-., ! 

Size (mm) 

0 0 x Length 

6x70 

6x70 

6x110 

8xt30 

6x70 

10x110 

7x110 

8x110 

6x70 

6x70 

6x70 

6x70 

8X70 

6x70 

10x150 

10x150 

8x110 

8x110 

10x110 

10x150 

6x70 

8x110 

6x40 

6x110 

10x110 

10x110 

10x110 

6x70 

8x110 

T 8x110 

L 8x110 

8x110 

7x110 

8x110 

6x70 

r 10x110 

L 10x110 

6x110 

8x110 

8x110 

8x110 

8x110 

6x70 

13-4x75 

6x70 

f 10x110 

L 11x110 

7x175 

6x70 

6x70 

Sections 

Sorbent 

(mg) 

2 

"2 

2 

3 

2 

2 

2 

2 

2 

2 

2 

2 

2 

2 

3 

3 

2 

2 

2 

2 

1 

1 

1 

2 

2 

2 

2 

2 

2 

1 

1 

2 

2 

2 

2 

1 

1 

2 

2 

2 

2 

2 

1 

2 

2 

1 . 

1 

1 

2 

2 

50/100 

50/100 

'200/400 

350/950/350 

7S150 

500/1000 

200/400 

150/300 

100/200 

50/100 

72/145 

72/145 

200/400 

72/145 

150/150/700 

150/150/700 

260/520 

260520 

200*300 

200/1800 

200 

500 

30 

200/400 

- 2OQ/80O 

290/1160 

260/1040 

50/100 

200/400 

r 200 

L 400 

22S/450 

200/600 

250/500 

4CV80 

r 300 

L 600 

30/100 

50/100 

75/150 

2007400 

50/100 

100 

140*270 

40/80 

r 1500 

L100 mm 

1500 

15(00 

100) 

End 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GO 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GS 

GO 

GS 

GS 

GS 

GS 

GS 

GS 

rGS 

LGS 

GS 

GS 

GS 

GS 

res 

LGS 

GS 

GS 

GS 

GS 

GS 

GS 

GO 

GS 

r G S 

LGS 

GS 

GS 

GO 

Holder Separators 

A 

A 

B 

C 

A 

C 

B 

B 

A 

A 

A 

A 

B 

A 

C 

C 

B 

B 

C 

C 

A 

B 

A 

8 

C 

C 

C 

A 

B 

0 

B 

B . 

B 

A 

O 

B 

B 

B 

B 

Of 

A 

Pending 

A 

O 

O 

A 

A 

CCATtO v TPBA res n-t-an .. . _X_M n ai ___,,, 

FFW 

WWW 

FFW 

WWWW 

FFW. 

www" 

WWGW 

WWW 

WWW 

FFW 

FFW 

FFW 

FFW 

FFW 

FFW 

WWW 

FFW 

FFW 

WW 

WW 

WW 

' FFW 

FFW 

FFW 

FFW 

WWW 

WFW 

' WW 

. WW 

WWW 

•* 

WWW 

WWW 

WW 

WW 

WWW 

WWW 

WWW 

www 

www 

WW 

FFGT 

OOO 

r wWv W 

WW 

FFGW 

FFW 

Price/Quantity 

$29,95/50 

55.00/50 

54.95*0 

104.5050 

39.95/50 

1244050 

75.0050 

81.50,30 -

.92.50/50 

67.5050 

78.00*0 

78.0050 

88.0050 

78.0050 

195.0050 

195.0050 

59.9550 

81.5050 

85.5050 

132.0050 

76.0050 

122.0050 

105.0050 

83.5050 

101.0050 

99.0050 

92.50/50 

70.0050 

91.0050 

149.0050 sets 

60.00/20 

108.0050 

100.0050 

64.0050 

185.0050 seta 

9150/50 ' 

80X050 

68X050 

-107X050 

37.50/20 

98X050 

85X0/10 

107X0/50 

122X0/20 sets 

44X0/20 

08.50/50 

112-5050 

1'(Q\ 
P.63 

.i'.i'J J \a(..Cii>>. iiVWili £.l£iW . ' *\0i , lHO. 10 l44d003J rUU<! 

,H 

FORMULA: Table 1 

M.W.: Table 1 

HYDROCARBONS. AROMATIC 

METHOO: 1501 

ISSUED: 2/15/84 

OSHA, NIOSH, 

COMPOUNDS: 

(Synonyms 

in Table 1) 

ACGIH: Table 2 

benzene 

E-tert-bu tyltoluene 

SAMPLING 

PROPERTIES: Table 1 

cumeme a-methylstyrene styrene 

ethylbenzene naphthalene toluene 

MEASUREMENT 

vinyl toluene 

xylene 

•.. 

SAMPLER: SOLIO SORBENT TUBE 

(coconut shell charcoal, 

100 mg/50 mg) 

FLOW RATE, VOLUME: Table 3 

SHIPMENT: no special precautions 

SAMPLE STABILITY: not determined 

BLANKS: 2 to 10 field blanks per set 

BULK SAMPLE: desirable, 1 to 10 mL; ship in 

separate containers from samples 

ACCURACY 

RANGE STU0IED, 

BIAS and OVERALL PRECISION (s r ) : Table 3 

TECHNIQUE: GAS CHROMATOGRAPHY. FIO 

ANALYTES: hydrp«£Jjons liste d above 

DESORPT10N:( 1 mL CS2; Stand 30 min 

INJECTION VOtiJtg^LiQ 

TEMPERATURE-INJECTION: 225 °C 

-DETECTOR: 225 °C 

-COLUMN: see step 11 

CARRIER CAS: N2 or He. 25 mL/min 

COLUMN: glass, 3.0 m x 2 mn, 101 OV-275 on 

100/120 mesh Chromosorb W-AW 

or equivalent 

CALIBRATION: analytes in CS2 

RANGE AND PRECISION (s r ): Table 4 

ESTIMATEO LOO: 0.001 to 0.01 mg per sample 

with capillary colum Cl] 

APPLICABILITY: This method is for peak, ceiling and TVM detenninations of aromatic hydrocarbons 

It may be used for simultaneous measurements, though there is the possibility that interactions 

between analytes may reduce the breakthrough volumes and chanqe desorption efficiencies. 

INTERFERENCES: Use of the reccnmended column wil l prevent interference by alkanes (iC-joK 

Under conditions of high humidity, the breakthrough volumes may be reduced by as much as 501. 

Other volatile organic solvents, e.g., alcohols, ketones, ethers and halogenated hydrocarbons, 

are possible interferences. If interference is suspected, use a less polar column or change 

column temperature. 

OTHER METHOOS: This method is based on and supercedes Methods P&CAM 127, benzene/styrene, 

toluene and xylene [2]; S311, benzene [4]; 522, p-tert-butyltoluene [3]; S23, cumene [3]; S29, 

ethylbenzene [3]; S26, a-methylstyrene [3]; S292, naphthalene [4]; S30, styrene [3]; S343, 

toluene C41: S25. vinyltoluene [31; S318. xylene C41. ; _______ 

2/15/84 1501-1 

tee 
wi in J J . L . 1.1 i i'i m m t.iLl\Ul 00, I1K-. iv IHUODdJ fuUJ 

P.64 

HYDROCARBONS. AROMATIC METHOO: 1501 

REAGENTS: 

1. Eluent: Carbon disulfide*, 

chromatographic quality containing 

(optional) suitable internal 

standard. 

2. Analytes, reagent grade* 

3. Nitrogen or helium, purified 

4. Hydrogen, prepurified. 

5. Air, filtered. 

6. Naphthalene calibration stock 

solution, 0.40 g/ml in CSj. 

*See Special Precautions. 

EQUIPMENT: 

1. Sanpler: glass tube, 7 an long, 6 mm 00, 4 mn 10, 

flame-sealed ends, containing two sections of 

activated (600 °C) coconut shell charcoal (front 

• 100 mg, back = SO mg) separated by a 2-rrm urethane 

foam plug. A silylated glass wool plug precedes the 

front section and a 3-mm urethane foam plug follows 

the back section. Pressure drop across the tube at 

1 L/min airflow must be less than 3.4 icPa. Tubes 

. are ccmnercially available.

 L j>. _^r /^ 

2. Personal sampling punps, 0.01 to 1 L/min ... "~"3^ 

(Table 3), with flexible connecting v^^ / 

tubing. 

3. Gas chromatograph, FIO, integrator, and colum 

(page 1501-1). 

4. Vials, glass, 1-mL, with PTFE-lined caps. 

5. Pipet, 1-mL, and pipet bulb. 

6. Syringes, 5-, 10-, 25- and 100-JJL. 

7. Volunetr.ic flasks, 10-mL. 

'J 

SPECIAL PRECAUTIONS: Carbon disulfide is toxic and extremely flarrmable (flash point = -30

 8 C ) ; 

benzene is a suspect carcinogen. Prepare samples and standards in a well-ventilated hood. 

SAMPLING: 

1. Calibrate each personal sampling punp with a representative sampler in line. 

2. Break the ends of the sanpler irmtediately before sampling. Attach sanpler to personal 

sampling pump with flexible tubing. 

3. Sample at an accurately known flow rate between 0.01 and 0.2 L/min (to 1 L/min for 

naphthalene or styrene) for a total sanple size as shown in Table 3. 

4. Cap the samplers with plastic (not rubber) caps and pack securely for shipment. 

SAMPLE PREPARATION: 

5. Place the front and back sorbent sections of the sanpler tube in separate vials, 

the glass wool and foam plugs. 

6. Add 1.0 mL eluent to each vial. Attach crinp cap to each vial immediately. 

7. Allow to stand at least 30 min with occasional agitation. 

Discard 

CALIBRATION ANO QUALITY CONTROL: 

8. Calibrate daily with at least five working standards over the appropriate range (ca. 0.01 

to 10 mg analyte per sample; see Table 4). 

a. Add known arounts of analyte (calibration stock solution for naphthalene) to eluent in 

10-mL volumetric flasks and dilute to the mark. 

b. Analyze together with sanples and blanks (steps 11. 12 and 13). 

c. Prepare calibration graph (peak area of analyte vs. mg analyte). 

2/15/84 1501-2 

.xiS& 
P.65 

I nv.i. t.«_...w. ' hjxJ, Ul v.. IV IfirOOjO ' ~ f uu-. " : ' 

METHOO: 1501 HYDROCARBONS. AROMATIC 

9. Determine desorption efficiency (OE) at least once for each batch of charcoal used for 

sampling in the calibration range (step 8). Prepare three tubes at each of five levels 

plus three media blanks. 

."^ a. Remove and discard back sorbent section of a media blank sampler. 

b. Inject a known amount of analyte (calibration stock solution for naphthalene) directly 

onto front sorbent section with a microliter syringe. 

c. Cap the tube. Allow to stand overnight. 

d. Desorb (steps 5 through 7) and analyze together with working standards (steps 11, 12 

and 13). 

e. Prepare a graph of DE vs. mg analyte recovered. 

10. Analyze three quality control blind spikes and three analyst spikes to Insure that the 

calibration graph and DE graph are in control. 

MEASUREMENT: , 

11. Set gas chromatograph according to manufacturer's recommenda tions and to conditions given 

on page 1501-1. Select appropriate column temperature: -7 

Substance3 

benzene 

toluene 

xylene (para) 

ethylbenzene 

xylene (meta) 

cumene 

xylene (ortho) 

styrene 

a-methylstyrene 

vinyl toluene (meta) 

naphthalene 

50 °l 

2.5 

4.3 

7.0 

7.0 

7.2 

8.3 

10 

16 

Approximate Retention Time (min). at Indicated Colum Temperature^' '^vv ^ 

100 °C 150 "C Programmed** >P 

2.5 

1-1 4.2 

1-4 5.2 

1.4 5.5 

1.5 5.6 

1.6 6.0 

1.9 6.5 

2.6 7.6 

3.2 1.0 8.1 

3.8 1.2 8.5 

25 4.3 12 

aData not available for js-tert-butyltoluene and jj-vinyltoluene, 

temperature program: 50 °C for 3 min, then 15 °C/min to 200 °C. 

NOTE: Alternatively, column and temperature may be taken fron Table 4. 

12. Inject sanple aliquot manually using solvent flush technique or with autosampler. 

NOTE: If peak area is above the linear range of the working standards, dilute with eluent, 

reanalyze and apply the appropriate dilution factor in calculations. 

13. Measure peak area. 

CALCULATIONS: 

14. Determine the mass, mg (corrected for DE) of analyte found in the sample front (Wf.) and 

back (W^) sorbent sections, and in the average media blank front (Bf) and back (B*,) 

sorbent sections. 

NOTE: If Ujj > Wf/10, report breakthrough and possible sanple loss. 

2/15/84 1501-3 

• /CP 4 
> UU J 

HYDROCARBONS. AROMATIC . METHOO: 1501 

. J 

15. Calculate concentration, C, of analyte in the air volune sampled, V (L): 

C a ( W f . W b - B f - B b )>10' )m9/n| 3 mg/mJ 

EVALUATION OF METHOO: 

Precisions and biases listed in Table 3 were determined by analyzing generated atmospheres 

containing one-half, one, and two times the OSHA standard. Generated concentrations were 

independently verified. Breakthrough capacities were determined in dry air. Storage stability 

was not assessed. Measurement precisions given in Table 4 were determined by spiking sanpling 

media with amounts corresponding to one-half, one, and two times the OSHA standard for nominal 

a ir volumes. Desorption efficiencies for spiked samplers containing only one compound exceeded 

751. Reference [12) provides more specific information. 

REFERENCES: 

[1] User check, UBTL. NIOSH Sequence 04121-s (unpublished, Decenber 7. 1983). 

[2] NIOSH Manual of Analytical Methods, 2nd. ed., V. 1, P4CAN 127. U.S. Department of Health, 

Education, and Welfare, Publ. (NIOSH) 77-157-A (1977). 

[3] Ibid, V. 2, S22, S23, S25, S26. S29, S30, U.S. Department of Health, Education, and 

Welfare, Publ. (NIOSH) 77-157-B (1977). 

[4] Ibid, V. 3, S292, S311, S318, S343, U.S. Department of Health. Education, and Welfare, 

Publ. (NIOSH) 77-157-C (1977). 

[5] R. D. Oreisbach. "Physical Properties of Chemical Conpounds"; Advances in Chemistry 

Series, No. 15; American Chemical Society, Washington (1955). 

[6] Code of Federal Regulations; Titl e 29 (Labor), Parts 1900 to 1910: U.S. Goverrtnent 

Printing Office. Washington (1980); 29 CFR 1910.1000. 

[7] Update Criteria and Recomnendations for a Revised Benzene Standard, U.S. Department of 

Health, Education, and Welfare, (August 1976). 

[8] Criteria for a Reccrnnended Standard Occupational Exposure to Toluene. U.S. Department 

of Health, Education, and Welfare, Publ. (NIOSH) 73-11023 (1973). 

[9] Criteria for a Reconnended Standard....Occupational Exposure to Xylene, U.S. Department of 

Health, Education, and Welfare, Publ. (NIOSH) 75-168 (1975). 

[10] TLVs - Threshold Limit Values for Chemical Substances and Physical Agents jn tiie Hbrk 

Environment with Intended Changes for 1983-84. ACGIH, Cincinnati, OH (1983). 

[11] Criteria for a Reccrmiended Standard...Occupational Exposure to Styrene, U.S. Department of 

Health and Hunan Services, Publ. (NIOSH) 63-119 (1983). 

[123 Documentation of the NIOSH Validation Tests, S22. S23, S25, S26. S29, S30, S292, S311, 

S318, S343, U.S. Department of Health, Education, and Welfare; Publ. (NIOSH) 77-185 (1977). 

METHOO REVISEO BY: R. Alan Lunsford. Ph.D., and Julie R. Okenfuss; based on results of NIOSH 

Contract COC-99-74-45. 

2/15/84 1501_4 

- \t9^ 
P.67 

¥ < V • V C • -_• 1 • •'• • •**-_•• 4..t • *\ V i ' T.. ' 0 1 1.IU , u i-j-;OOJo fUUO 

3 

fCTHOO: 1501 

Table 1. Synonyms, 

Name/Synonyns 

benzene 

CAS #71-43-2 

• 

Formula, molecular weight, 

1 

Structure 

;o 

^-tert-butyl toluene - /(yS ( > 

CAS #98-51-1 ^£V \ 

1-tert-butyl -4-methylbenzene 

ajmene 

CAS #98-82-8 

isopropylbenzene 

ethylbenzene 

CAS #100-41-4 

<OK 

Q-\ 

o-methylstyrene //j V / 

CAS #98-83-9 ^ZV V 

1sopropenylbenzene 

(1 -methy 1 ethenyl) -benzene 

naphtha 1 ene 

CAS #91-20-3 

styrene 

CAS #100-42-S 

vinylbenzene 

toluene 

CAS #106-88-3 

methylbenzene 

@D 

<0K 

<o^-

vinyl tol uene* -L/f^S- -

CAS #25013-15-4 ^\^ 7 \> 

methyl styrene (g-vinyl toluene) 

methylvinylbenzene ; 

Empirical 

Formula 

C6«6 

Cll«16 

^ 1 2 

CaH10 

Wo 

c

10"8 

<¥% 

C7"8 

C9H10 

properties 

Molecular 

Weight 

78.11 

148.25 

120.20 

106.17 

118.18 

128.18 

104.15 

92.14 

118.18 

(meta) 

(para) 

(ortho) 

[5]. 

Boiling 

Point 

(°C) 

80.1 

192.8 

152.4 

136.2 

165.4 

80.2* 

145.2 

110.6 

167.7 

171.6 

172.8 

169.8 

HYOROCARBONS. 

Vapor Pressure 

0 25 »C 

(mm Ho) 

95.2 

0.7 

4.7 

9.6 

2.5 

0.2 

6.1 

28.4 

1.6 

1.9 

1.8 

1.8 

.UM 

12.7 

0.09 

0.62 

1.28 

0.33 

0.03 

0.81 

3.79 

0.22 

0.26 

0.24 

0.24 

AROMATIC 

Density 

* 20 *C 

(9/mU 

0.879 

0.861 

0.862 

0.867 

0.911 

1.025 

0.906 

O.B67 

0.898 

0.911 

0.911 

0.904 

xylene6 

CAS #1330-20-7 

dimethylbenzene (t-xylene) I5£ii 

CaHiO 106.17 

(ortho) 144.4 

(meta) 139.1 

(para) 138.4 

Siting point. 

bCotnnerclal mixture of meta and para isomers. 

cMixture of isomers. 

6.7 0.89 0.880 

8.4 1.12 0.664 

8.8 1.18 0.861. 

2/15/84 1501-5 

'••IG?(J3 
P.68 

xa i. 

i ! ' I i 

i 

t 

. i 

;'"' • 

. j 

w i axj VU-U1.-7 . 1 iw n UlLftU l 'CJ , .Hi t 

HYDROCARBONS. AROMATIC 

! 

Table 2. Permissible exposure 

Substance 

benzene 

p-tert-butyltoluene 

cumene 

ethylbenzene 

a-methyIstyrene 

naphthalene 

styrene 

toluene 

vinyltoluene 

xylene 

aMaximum duration 10 min 

bHaximum duration 5 min ' 

TWA 

10 

10 

limits 

OSHA 

C 

25 

50 (skin) 

100 

10 

100 

200 

100 

100 

in 8 1 

n any 

100 

200 

300 

ir. 

3 hr. 

• 

i PP"*. 

Peak 

503 

600*> 

5003 

IV 1-H3003J 

C6-11]. 

NIOSH 

TWA C 

1 

50 100 

100 200* 

100 200* 

••ACGIH: suspect 

* 10-min sample. 

TLV 

fUU'l 

4 

ACGIH 

STEL 

10** 25** 

10 

50 

100 

50 

10 

50 

100 

50 

100 

carci 

20 

75 (skin) 

125 

100 

IS 

100 

150 (skin) 

100 

150 

nogen [10]. 

METHOO: 1501 

mg/ni-* 

per ppn 

3.19 

6.06 

4.91 

4.34 

4.83 

5.24 

4.26 

3.77 

4.83 

4.34 

•• 

<•* * 

( 

Table 3. Sampling flowrate4, volune, capacity, range, overall bias and precision [3,4,12], 

Breakthrough 

Substance 

Sampling 

Flowrate Volune (L) 

(L/min) V0L-N0M VOL-MAX& 

Volune @ 

Concentration 

(L) (mg/m3) (mg/m3) 

Range 

at 

VOL-NON 

Overa 11 

Bias 

(*) 

Precision 

<«r> 

benzene $0.20 2 C 30 >45 149 42- 165 0.8 

B-tert-butyl tol uene SO. 20 10 29 44 112 29- 119 -10.4 

cumene £0.20 10 30 >45 480 120- 480 4.6 

ethylbenzene SO.20 10 24 35 917 222-884 -8.1 

ex-methyl styrene $0.20 3 f 30 >45 940 236- 943 -10.8 

naphthalenee $1.0 200 200 >240 81 19- 83 -0.5 

(gyrene' V -Sl.O'"- '59- ' 14 21 1710 \. 426-1710 /-10.7

 ; 

toluene $0.20 2C 8 12 2294 548-2190 3.8 

vinyltoluene $0.20 10 24 36 952 256- 970 -9.5 

xylene $0.20 12 23 35 870 218-870 -2.1 

^ininun recomnended flow is 0.01 L/min. 

bApproximate1y two-thirds the breakthrough volume, except for naphthalene. 

c

10-min sanple. 

^Corrected value, calculated from data in Reference 12. 

Naphthalene shows poor desorption efficiency at low loading; 100-L minimum volume is 

recommended. 

f

15-min sanple. 

95-min sample. 

2/15/84 1501-6 

}LD^T 
Ui"v.r;j uL'.Clti. nvvtri CWCR'J! LABi, INL. IU l-449bbDJ 

P.69 

F008 

i 4 * i 

METHOO: 1501 

Table 4. Measurement range, precision and conditions3 [3,4,12]. 

Substance 

benzene 

p-tert-butyltoluene 

cumene 

ethylbenzene 

a-methylstyrene 

naphthalene 

styrene 

toluene ! 

vinyltoluene i 

xylene \ 

Resorption 

Volume 

i <mL) 

!

 1.0 

i 0.5 

I o.s 

! O.S 

: o.s 

! i-o 

! 0.5 

- 1.0 

0.5 

1.0 

Measurement 

Range Precision 

(">9) (sr) 

0.09- 0.35 

0.27- 1.09 

0.86- 3.46 

2.17-8.67 

0.69- 3.57 

4.96-19.7 

2.17-8.49 

1.13- 4.51 

2.41- 9.64 

2.60-10.4 

0.036 

0.02ld 

0.010 

0.010 

0.011 

0.019 

0.013<* 

0.011 

0.008 

0.010 

Carrier 

Flow 

50 

50 

50 

50 

50 

30 

50 

50 

50 

SO 

HYDROCARBONS, tormiy}r 

Column Parameters-* 

t Length 

(mL/min) (°C) 

115 

1)5 

99 

85 

115 

125 

109 

ISS 

120 

180 

aInjection volune, 5.0 yL; nitrogen carrier gas. 

-*A11 colunns stainless steel, 3.2 nn outside diameter. 

CA, 50/80 mesh i-orapak P; B, 101 FFAP on 80/100 mesh Chromosorb W AW-OMCS; 

C, 101 OV-101 on 100/120 mesh Supelcoport; 0, 50/80 mesh Porapak Q. 

^Corrected value, calculated from data in [12). 

On) Packing0 

0.9 

3.0 

3.0 

3.0 

3.0 

3.0 

3.0 

0.9 

3.0 

0.9 

A 

B 

B 

B 

8 

C 

B 

0 

B 

0 

2/15/84 1501-7 

i&8 
P.70 

APPENDIX F: CALIBRATION DATA 

*c* ^ 
P.71 

Proof Record W0# 1627 

GRASEBY NUTECH 

Company Meter Number H K M PURCHASE OR. 

Rockwell T-110 Metr i c P0# 1921 

Ave Yd High Flew Low Flo * 

• 500327 1.0004 1.0005 

&0X$r 70 HO 

Overall Average Yd= * 1.0004 

r 

- J . 

>. 

'02 S. Main Street 

Measurement Controls, Inc. 

• P.O. Box 997 • Huntersville, NC 28078 (704) 875-20U 
P.72 

GRASEBY NOTECH 

WRHAM, N.C. 

ProqfJRecord WO# 1642 

02 S. Main Street Measurement Controk, Inc. 

* P.O.-Box 997 • «•„„,_•.....•/_. _„.,_- . \m\. Huntersville, NC 28078 (704)875-2034