# Final

Technical Support Document for HWC MACT Standards

Volume VI
Development of Comparable Fuels Specifications

U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response (5305) 401 M Street, SW Washington, D.C. 20460

MAY 1998

# i 

# ACKNOWLEDGEMENTS

This document was prepared by the U.S. EPA’s Office of Solid Waste, Waste Management Division. Energy and Environmental Research Corporation (EER) provided technical support under EPA contract No. 68-D2-0164. Paradigm Laboratories Incorporated performed all of the analyses on the fuel oils as a subcontractor to EER under EPA contract No. 68-D2-0164.

# ii 

# ABSTRACT

This report provides detailed tests results for the analysis of eight (8) gasoline samples, eleven (11) No. 2 fuel oil samples, one (1) No. 4 fuel oil sample, and seven (7) No. 6 fuel oil samples from various geographic regions around the country. The combustion fuel samples collected for the program were characterized for the chemical and physical properties and the presence of the hazardous constituents listed in 40 CFR Part 260 Appendix VIII. Then statistical analyses, to estimated percentiles from the distribution of concentrations and from each chemical compound within each fuel type, was performed by Science Applications International Corporation (SAIC). For each individual fuel type, the 90th percentile was estimated for each chemical compound. For the composite fuel types, estimates of the 90th and 99th percentiles were calculated for each chemical compound.

# iii 

# TABLE OF CONTENTS Section Page

1.0 INTRODUCTION

................................................ 1-1 1.1 Benchmark Fuel Selection Basis

................................ 1-6 1.2 Parameters and Rationale for Comparable Fuels Specifications

......... 1-9 1.2.1 Heating Value

....................................... 1-10 1.2.2 Kinematic Viscosity

.................................. 1-10 1.2.3 Flash Point

......................................... 1-11 1.2.4 Total Halogens

...................................... 1-11 1.2.5 Total Nitrogen

...................................... 1-13 1.2.6 Metals

............................................. 1-14 1.2.7 Organics

........................................... 1-14 1.3 Parameters and Rationale for Synthesis Gas Fuel Specifications

........ 1-15 1.3.1 Heating Value

....................................... 1-15 1.3.2 Hydrogen Sulfide

.................................... 1-17 1.3.3 Nitrogen (other than N 2 

# )

............................... 1-18 1.4 Collection of Liquid Fossil Fuel Samples Used for Analysis to Determine Benchmark

..................................... 1-18 References

................................................ 1-20

2.0 SAMPLING AND ANALYSIS

...................................... 2-1 2.1 Analysis of Samples

......................................... 2-1 2.2 GC/MS Volatiles

........................................... 2-5 2.2.1 Method Summary

.................................... 2-5 2.2.2 Sample Preparation

................................... 2-5 2.2.3 Instrumental Analysis

................................. 2-7 2.2.4 Quality Control

...................................... 2-7 2.2.5 Analytical Difficulties

................................. 2-9 2.3 GC/MS Semi-Volatiles

...................................... 2-9 2.3.1 Method Summary

.................................... 2-9 2.3.2 Sample Preparation

................................... 2-10 2.3.3 Instrumental Analysis

................................. 2-10 2.3.4 Quality Control

...................................... 2-10 2.3.5 Analytical Difficulties

................................. 2-12 2.4 High Pressure Liquid Chromatography (HPLC)

.................... 2-12 2.4.1 Method Summary

.................................... 2-12 2.4.2 Sample Preparation

................................... 2-13 2.4.3 Instrumental Analysis

................................. 2-13 2.4.4 Quality Control

...................................... 2-13 2.4.5 Analytical Difficulties and Recommendations

............... 2-14

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# TABLE OF CONTENTS (Cont.) Section Page

2.5 Dioxins and Dibenzofurans

................................... 2-15 2.5.1 Method Summary

.................................... 2-15 2.5.2 Sample Preparation

................................... 2-17 2.5.3 Instrumental Analysis

................................. 2-17 2.5.4 Quality Control

...................................... 2-17 2.5.5 Analytical Difficulties and Recommendations

............... 2-17 2.6 Herbicides

................................................ 2-18 2.6.1 Method Summary

.................................... 2-18 2.6.2 Sample Preparation

................................... 2-18 2.6.3 Instrumental Analysis

................................. 2-18 2.6.4 Quality Control

...................................... 2-18 2.6.5 Analytical Difficulties and Recommendations

............... 2-19 2.7 Metals

................................................... 2-19 2.7.1 Method Summary

.................................... 2-19 2.7.2 Sample Preparation

................................... 2-19 2.7.3 Instrumental Analysis

................................. 2-19 2.7.4 Quality Control

...................................... 2-20 2.7.5 Analytical Difficulties and Recommendatiions

............... 2-21 2.8 Pesticides and PCBs

......................................... 2-21 2.8.1 Method Summary

.................................... 2-21 2.8.2 Sample Preparation

................................... 2-21 2.8.3 Instrumental Analysis

................................. 2-22 2.8.4 Quality Control

...................................... 2-22 2.8.5 Analytical Difficulties and Recommendations

............... 2-22 2.9 Heating Value

............................................. 2-23 2.9.1 Method Summary

.................................... 2-23 2.9.2 Quality Control

...................................... 2-23 2.10 Specific Gravity

............................................ 2-23 2.10.1 Method Summary

.................................... 2-23 2.10.2 Quality Control

..................................... 2-23 2.10.3 Analytical Difficulties and Recommendations

............... 2-24 2.11 Flash Point

................................................ 2-24 2.11.1 Method Summary

.................................... 2-24 2.11.2 Quality Control

..................................... 2-24 2.12 Total Halogens

............................................ 2-24 2.12.1 Method Summary

.................................... 2-24 2.12.2 Quality Control

..................................... 2-25 2.12.3 Analytical Difficulties and Recommendations

............... 2-25 2.13 Total Nitrogen

............................................. 2-26

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# TABLE OF CONTENTS (Cont.) Section Page

2.13.1 Method Summary

.................................... 2-26 2.13.2 Quality Control

..................................... 2-26 2.14 General Matrix Spike and Laboratory Control Sample Recovery

....... 2-27 2.15 Analysis for Total Aromatic Hydrocarbons and Total Polynuclear Aromatic Hydrocarbons

........................ 2-27

3.0 RESULTS

...................................................... 3-1 3.1 Statistical Analysis Results (SAIC)

.............................. 3-1 3.1.1 Estimates for Each Individual Fuel

....................... 3-4 3.1.2 Estimates from Composite 246

.......................... 3-6 3.1.3 Estimates from Composite of All Fuel Types

................ 3-7 3.1.4 Estimates from Additional Halogen Data

................... 3-9
Appendices

APPENDIX A - LABORATORY DATA APPENDIX B - CONSTITUENT LEVELS APPENDIX C - SAIC - STATISTICAL ANALYSIS RESULTS APPENDIX D - MDL LEVELS APPENDIX E - QUALITY ASSURANCE RESULTS APPENDIX F - CONSTITUENTS NOT IN FINAL RULE

# vi 

# LIST OF TABLES Section Page

Table 1-1 Analytical Parameters and Constituents

for Comparable Fuel Study

................................... 1-5 Table 1-2 Comparison of the Metal and Halogen Content of Coal, Gasoline,

and Fuel Oils

.............................................. 1-8 Table 1-3 Geographic Regions where Fuel Samples were Collected

............. 1-19 Table 2-1 Analytes from Appendix VIII Not Determined During Study

.......... 2-6 Table 2-2 Comparable Fuels Procedure - Organics

.......................... 2-8

# 1-1

1.0 INTRODUCTION

This document provides technical background for the comparable fuel exclusion that is being
considered for the final rule. As part of an April 19, 1996 proposed (60 FR 17459) rulemaking, EPA has developed a comparable fuel exclusion. A comparable fuel would be an ignitable waste or coproduct production stream, both of which are currently defined as a hazardous waste, which meet the specifications of the exclusion. Comparable fuels are burned for energy recovery, in lieu of fossil fuels, due to their high BTU value. Benefits derived from this procedure include decreased use of fossil fuels and reduced operational costs. Under this provision, a comparable fuel would be excluded
from the Research Conservation and Recovery Act (RCRA), Subtitle C Regulation, as long as it meets the comparable fuel exclusion and is burned. Industry contends these waste streams are cleaner
than the fuels displaced and that burning these waste streams provides an overall environmental benefit. EPA’s goal is to provide a comparable fuel exclusion that is both useful to the regulated

c ommunity and assures that comparable fuel poses no greater risk than what otherwise would be associated with the burning of fossil fuels.

The Agency’s current approach is to base a comparable fuel exclusion on constituent

concentrat ions normally found in fossil fuels. For this “benchmark” approach, the concept is to permit hazardous constituents in the comparable fuel which are no greater in concentration than those
of the same constituents naturally occurring in commercially available fossil fuels. Additionally, the

current approach will not allow detectable levels of toxic synthetic chemicals, such as pesticides, in
the comparable fuels. This approach will assure EPA that the comparable fuel, when burned, will
pose no greater risk than a fossil fuel. This document contains data on as many toxic organics from
40 CFR, Part 261, Appendix VIII as could be quantitated for each fuel sample collected during this study. The EPA developed a series of constituent specifications based on the following parameters:
kinematic viscosity, total nitrogen, total halogens, individual metals, Appendix VIII organics, and
BTU content of each fuel. EPA is proposing that these specifications apply to all hazardous gaseous and liquid fuels, with the exception of viscosity, which is not relevant

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for gaseous fuels. Table 1-1 gives the units of measure for each of these constituents and the individual metals analyzed.

In the proposed rule for comparable fuels, EPA presented several options to establish a
benchmark specification. This document presents the data used to develop the initial specification for the proposed rule and the specifications for the final rule. This document summarizes the
rationale of the ?

benchmark” approach used to set the specifications and discusses, with some detail, the analytical approach used to characterize the constituents of concern.

1.1 Benchmark Fuel Selection Basis

Potential benchmark fuels (on which to base the comparable fuel specifications) that were
considered include the commercially available fossil fuels of: (1) gases (such as natural gas and propane); (2) liquids (such as gasoline and fuel oils); and (3) solids (such as coal, coke, and peat). However, the benchmark fuels have been limited to liquid fossil fuels, including gasoline and Nos. 2, 4, and 6 fuel oils. This is because, as discussed below, solid fuels tend to have higher levels of hazardous constituents that are not destroyed in the incineration process, while gases tend to have hazardous constituent levels that are sufficiently low to make the specification of limited practical use.

Solid fuels (such as coal, wood, and biomass) will not be used to base the comparable fuels specification. Solid fuels are used widely throughout the U.S. as legitimate energy sources. However, the comparable fuel specification, which would exclude a hazardous waste fuel from RCRA Subtitle C regulation, will not be based on solid fossil fuels (in particular, coal) since they can have high levels of toxic constituents that will not be destroyed or detoxified by burning (e.g., metals and halogens). It is generally desired to minimize the feed rate of metals and halogens into waste incineration systems because these constituents are not destroyed in the incineration process (unlike organics which are destroyed; inorganics are found in the bottom ash, air pollution control system residues, or stack gas emissions). It is not the intent of the comparable fuels exclusion to set

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TABLE 1-1. ANALYTICAL PARAMETERS AND CONSTITUENTS FOR COMPARABLE FUEL STUDY

Property of Interest Units Described As
Heating Value BTU/lb min. or range Kinematic Viscosity cSt at 100 F min. or range Specific Gravity at 15 C range and average Flash Point F minimum Total Nitrogen weight % maximum Total Halogens: ppm w 

# as Cl

- 

# maximum Fluorine maximum Chlorine maximum Bromine maximum Iodine maximum Metals: Antimony ppm w 1 

# maximum Arsenic ppm w 1 

# maximum Barium ppm w 1 

# maximum Beryllium ppm w 1 

# maximum Cadmium ppm w 1 

# maximum Chromium ppm w 1 

# maximum Cobalt ppm w 1 

# maximum Lead ppm w 1 

# maximum Manganese ppm w 1 

# maximum Mercury ppm w 1 

# maximum Nickel ppm w 1 

# maximum Selenium ppm w 1 

# maximum Silver ppm w 1 

# maximum Thallium ppm w 1 

# maximum Appendix VIII Organics ppm w 1 

# maximum Total Aromatics wt. % maximum Total PNAs Wt. % maximum

1 

# ppm w 

# = mg/kg

# 1-4

specifications based on the ? dirtiest” fossil fuels. Comparison with these solid fuels could result in

a least common denominator approach whereby a hazardous waste-derived fuel would be ? comparable” if it was no more dangerous to burn than the most contaminated fossil fuels. Such ? comparabili ty” is not congruent with the overall objective of RCRA in order to protect human health
and the environment. It is also inconsistent with the specific directive to regulate combustion of hazardous waste-derived fuels where necessary to protect human health and the environment (RCRA
Section 3004(q)). Thus, although a benchmark approach is used rather than a risk-based approach, the benchmark fossil fuels that are selected, in general, have lower contaminant levels for constituents that are not destroyed in the incineration process.

Metals and halogen concentrations in coal are compared with that of gasoline and fuel oils (Nos. 2, 4, and 6) in Table 1-2. For coal, median, maximum, and minimum levels are shown, based

on data from a recent IEA Coal Research report (Clarke and Sloss, 1992) and the Electric Power Research Institute (EPRI) PISCES database (Wetherold et al., 1995). Data for the liquid fossil fuels are given from three sources: (1) 90th percentile levels based on the recent EPA-sponsored testing specifically for developing the comparable fuels specifications; (2) for No. 2, 4, and 6 fuel oil, average
level s based on that from the EPRI Pisces database (Wetherold et al., 1995); and (3) for fuel oil, levels from the EPA/OSW database on hazardous waste burning combustors (including boilers and incinerators).

None of the Clean Air Act metals were detected in the gasoline samples. Pb, Ni, Sb, and Se

are the only metals typically found in the fuel oil samples (with the metals levels generally increasing
with the fuel oil number). Metals levels in coal can vary tremendously, depending on the origin of the fossil fuels. The No. 6 fuel oil high-end 90th percentile levels for Pb and Ni are comparable to the average coal levels. The average coal levels for As, Ba, Co, Cr, Mn, and Pb are typically 10 to
100 times higher than that of the liquid fossil fuels. Levels of Hg and Be in fuel oils are also typically
much less than that of coal. The chlorine content of coal and fuel oils can range widely from less than
50 to greater than 2,000 ppmw. Typically though, coal has a chlorine level that can be 2 to 10 times higher than that of fuel oils.

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TABLE 1-2: COMPARISON OF THE METAL AND HALOGEN CONTENT OF COAL, GASOLINE, AND FUEL OILS

Constituent Concentration (ppmw)
Coal a 

## Gasoline

90th % b 

## Fuel Oil

No. 2 90th % b 

## Fuel Oil

No. 4 90th % b 

## Fuel Oil

No. 6 90th % b 

## Fuel Oil

No. 2, 4, 6 Average c 

## Fuel Oils e 

## Avg. Min. Max. Avg. Min. Max.
Antimony 1 0.05 10 < 7 < 6 < 11 6.5 0.2 Arsenic Barium 10

200 0.5 20 80 1000 < 0.14 < 14 < 0.12

< 12 < 0.2

< 23 < 0.2

< 20 0.3

NA 0.1

0.3 Beryllium Cadmium 2

0.5 0.1 0.1 15 3 < 0.7 < 0.7 < 0.6

< 0.6 < 1.2

< 1.2 < 1

< 1 0.2

0.3 0.1

0.5 Chromium Cobalt 20

5 0.5 0.5 60 30 < 1.4 < 2.8 < 1.2

< 2.4 < 2.3

< 4.6 < 2

< 4.1 0.7

2 0.5

Lead Manganese 40

70 2 5 80 300 < 7 < 0.7 6.6

< 0.6 9.9

< 1.2 30

< 1 2.6

0.2 Mercury Nickel 0.1

20 0.02 0.5 1 50 < 0.1 < 2.8 < 0.1

< 2.4 < 0.2

16 < 0.2

36 0.03

31 < 0.1

Selenium Silver 1

0.1 0.2 0.02 10 2 < 0.14 < 1.4 0.07

< 1.2 0.13

< 2.3 0.12

< 2 0.2

NA Thallium Chlorine < 1

1000 50 2000 < 14 < 25d < 12

< 25d < 23

< 0d < 20

< 10d NA

36 500 50 3000 Fluorine 150 20 500 NM NM NM NM NA

a Source: Clarke and Sloss (1992) e From hazardous waste burning combustors b Source: EPA (1996) NM: Not measured c Source: Wetherold et al. (1995) NA: Not reported

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Gases are also not selected as benchmark fuels. Generally, basing the comparable fuel specification on a gaseous fuel would be overly conservative and have no practical use to the regulated industry (i.e., it is unlikely that many hazardous wastes would meet a fuel specification based on natural gas). Note that separate benchmark specifications are defined for a hazardous waste-derived fuel synthesis gas (syn-gas), as discussed below.

Additionally, non-petroleum liquid based fuels, including turpentine and tall oil, are not considered as benchmark fuels:

• Turpentine -- Turpentine has a very high energy content and is used as a fuel (and a
manufact uring feedstock) both within and outside the forest products industry. However, turpentine has not been selected since: (1) turpentine is not a widely used

c ommercial fuel; and (2) there are no ASTM standards for turpentine fuel which specify the minimum properties. This must be met for the product to be considered as a
commercial fuel.

• Tall oil -- Tall oil is a traditional fuel source, and EPA has acknowledged that tall oil is a legitimate non-waste fuel under the BIF rule low risk waiver exemption (LRWE) and DRE trial burn exemptions (see 56 FR 7193, February 21, 1991). However, tall oil is not used because of lack of quality constituent data.

Liquid fossil fuels of Nos. 2 and 6 fuel oils, and gasoline, have been selected as the benchmark
fuels. Liquid fuels are widely used by industry, readily combusted, and do not have the inconsistencies of solid or gaseous fuels. Gasoline has been included even though it is not typically utilized in industrial
boilers and furnaces. Gasoline is a highly used, commercially available, liquid fuel, for which complete hazardous constituent analysis is available (allowing for a more complete and useable benchmark specification).

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1.2 Parameters and Rationale for Comparable Fuels Specifications

Benchmark fuel specifications are being set for: (1) physical specifications, including energy

content (heating value) and kinematic viscosity; (2) general constituent specifications for total nitrogen
and total halogens; and (3) individual hazardous constituents, including individual metals (including Sb, As, Ba, Be, Cd, Cr, Co, Pb, Mn, Hg, Ni, Se, Ag, and Tl), and Appendix VIII organics. Rationale for the selection of these parameters is discussed in the following.

Since most comparable fuels are expected to have a lower BTU content than fossil fuels, more comparable fuel will be needed to produce the same heating value. This situation will potentially
in crease the environmental loading of hazardous constituent emissions from the comparable fuel. More comparable fuel would be burned to achieve the same heat input leading to greater environmental loading of potentially toxic substances than if fossil fuel was burned. This would not follow the intent of the comparable fuel exclusion. To address environmental loading, a minimum heating value specification comparable to the BTU content of the benchmark fossil fuels is used. Constituent levels have been corrected from the fuel’s heating value (approximately 20,000 Btu/lb) to 10,000 Btu/lb.

1.2.1 Heating Value

A benchmark specification limit on minimum waste energy content is set. This is to ensure that
the comparable fuel has a legitimate use as a fuel (note that the comparable fuels exclusion only applies

to waste fuels that are ultimately burned). For solid and liquid wastes, a level of 5,000 Btu/lb (11,500 J/g) has been selected. This level has been traditionally used as a reasonable cutoff for determining if

a waste is being burned for energy recovery. Note that it is based on the typical heating value of wood.

1.2.2 Kinematic Viscosity

Liquid waste viscosity affects the efficiency of combustion by influencing the atomization characteristics of the liquid waste. Note that viscosity is an important design specification for liquid

# 1-8

burners. Thus the purpose of a viscosity specification is used to ensure that a comparable fuel is as burnable as the benchmark fuel.

The viscosity specification is based on that of No. 6 residual fuel oil (the heaviest, most viscous, liquid fossil fuel) at normal firing conditions. The comparable fuel viscosity specification is set at 50 cSt, as-fired. This is based on the ASTM standard for No. 6 fuel of 50 cSt (at 100 C, which is a

common firing temperature for No. 6 oil). Note that No. 6 residual oil must be heated (from 30 to
50 C) for handling and pumping purposes due to high viscosity at normal ambient temperatures. For atomization and burning, it must be heated further to reduce the viscosity needed for efficient atomization and combustion, usually to temperatures in the range of 70 to 130 C (160 to 270 F). The

exact temperature (and corresponding viscosity) requirement depends on factors including the burner design, atomization method (steam assisted, mechanical pressure, etc.), and viscosity characteristics
of the No. 6 fuel oil (note that there is no one No. 6 oil; different No. 6 oils can have significantly different viscosities at the same temperature). Typically, mechanical pressure atomization nozzles require that the oil have a viscosity of 15 to 30 cSt (70 to 150 SSU), while steam assisted burner nozzles can handle higher viscosities ranging from 30 to 70 cSt (150 to 300 SSU). The 50 cSt ASTM
value is an upper limit on what can be expected for No. 6 fuel oils at a typical firing temperature of
100 C (Perry and Green, 1994; Reed, 1986).

Additionally, the viscosity specification only applies to liquid waste fuels (not gaseous fuels, which are inherently less viscous than liquids, and not solids, for which viscosity is not applicable).

1.2.3 Flash Point

A specification on flash point is not being used since: (1) DOT and OSHA have regulations that control the hazards of flash point explosions; (2) it would preclude the inclusion of materials that are normally fuels such as methanol.

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1.2.4 Total Halogens

A comparable fuel specification for total halogens is used, generally in-lieu of meeting the individual specifications of chlorinated Appendix VIII compounds (expect PCBs for the most part).
Limitation of the chlorine feed to the combustor is desired from an environmental protection perspective to: (1) reduce the emissions of the hazardous air pollutants of HCl and Cl 2 

# , both of whose
formation is directly related to the chlorine content of the waste feed; and (2) prevent the formation of chlorinated products of incomplete combustion (PICs), which includes PCDD/PCDF as well as
chlorinated benzenes, biphenyls, phenols, etc. Limiting the waste feed chlorine level reduces the potential for the formation of chlorinated PICs through (Dellinger et al., 1990):

• Limiting the release from the combustion zone of undestroyed and/or partially fragmented chlorinated precursors contained in the waste feed. Note that kinetic theory and experimental work indicate the chlorination of unchlorinated hydrocarbons is very unlikely at combustion temperatures (i.e., chlorinated PICs are not formed from unchlorinated hydrocarbons in the combustion zone). Thus, the emissions of
chlorinated PICs from the combustion zone is related directly to the chlorinated organic constituents in the waste feed. It is highly desired to minimize the level of chlorinated
precursors in the combustion gases since the major route to formation of high molecular weight chlorinated PICs is through reactions of already chlorinated
precursors.

• Limiting the potential for the formation of chlorinated PICs due to radical-radical association reactions as the combustion gas is cooled -- in particular organic radical
reactions with Cl radicals formed in the combustion zone.

• Ensuring adequate flame stability (and corresponding combustion efficiency) and reducing flame sooting. Increasing levels of chlorine are known to increase flame sooting and decrease flame stability and efficiency. Cl atoms scavenge H atoms,

# 1-10 depleting the flame radical pool that drives the combustion reactions.

Note that a total halogen limit may have only a secondary effect on controlling PCDD/PCDF emissions. Analysis of PCDD/PCDF data from full-scale waste combustion systems indicates that the

waste feed chlorine level does not have a dominant impact on PCDD/PCDF emissions (generally of pri mary importance is the PM air pollution control device temperature). However, the waste feed
chlo rine level may have a secondary influence. Certain well-controlled pilot-scale experimental studies indicate there can be a strong relationship between HCl and Cl 2 

# levels in the flue gas and PCDD/PCDF emissions (e.g., Gullett et al., 1994).

Additionally, a limit on total halogens, including both organic and inorganic forms, is appropriate since both forms in the waste fuel can contribute to halogenated PIC emissions. For example, PCDD/PCDF and other chlorinated PICs have been detected from sources burning both inorganic (e.g., salts) and/or organic chloride (e.g., plastics) containing wastes (e.g., Wikstrom et al., 1994; Fangmark et al., 1991; Christiansen, 1990; Nielsen, 1989). Inorganic chlorine salts have also been shown to act as a direct chlorine source for PCDD/PCDF formation at low de-novo synthesis temperatures (Addink and Olie, 1995).

No te that under well-controlled combustion conditions, the vast majority of organic halogens
in the waste fuel feed will leave the combustor gas as HCl, HF, etc. Smaller levels will be in the
combustion gas in the form of Cl 2 

# , F 2 

# , and halogenated organics, and some may also be present in the solid bottom and fly ash as salts. Inorganic halogen salts will also decompose to a lesser degree as HCl, HF, Cl 2 

# , F 2 

# , and PICs in the combustion gas; with the remainder as salts in the bottom and fly ash. Inorganic halogen salts are sometimes believed not to react at combustion temperatures due to high melting temperatures. However, work by Uchida et al., (1988) have shown that inorganic salts can directly contribute to HCl combustion gas levels (water vapor and zeolites participate in a reaction transforming chlorine salts to HCl). Thus, for halogenated hydrocarbon waste fuels, containing either inorganic or organic halogens, there is potential that under less optimum combustion conditions (higher CO, insufficient oxygen and mixing, etc.) halogenated PIC emissions may form.

# 1-11

1.2.5 Total Nitrogen

A specification on total nitrogen is used, in addition to those on nitrogenated Appendix VIII compounds. Under oxidative conditions of typical hazardous waste combustors, the majority of waste nitrogen will be emitted as N 2 

# (not of environmental concern) or NO x 

# (a criteria air pollutant whose emissions levels are covered under the Clean Air Act ambient air quality standards for ozone control). However, under starved air (reducing) conditions, nitrogen will primarily form the HAPs HCN and
NH 3 

# . Starved air transient ? puffs” can occur in hazardous waste combustors due to chamber overcharging (possibly due to unexpected surges in waste volatile composition), poor waste/air mixing, and poor liquid atomization. Additionally, nitrile radicals (CN ) can form nitrogenated PICs (such as
HAPs including hydrogen cyanide, acetonitrile, acrylonitrile, nitrophenols, nitrotoluenes, nitrobenzenes, aniline, acetamide, acrylamide, etc.) through radical-radical and radical-molecule reactions which occur as the combustion gas is cooled (Dellinger et al., 1990).

1.2.6 Metals

Benchmark specifications are set for the individual metals of Sb, As, Ba, Be, Cd, Cr, Co, Pb, Mn, Hg, Ni, Se, Ag, and Tl (which include both Clean Air Act Title III and RCRA Appendix VIII metals). Limitation of the metals feed to the incinerator results in a direct reduction of metals emissions since, like chlorine, metals are not destroyed in the combustion process.

1.2.7 Organics

Specifications are set for RCRA Appendix VIII organics. Note that specifications are not set
for some of the compounds on the Appendix VIII list because a routine analytical method is not available.

Specifications are set for oxygenates (at non-detect levels determined by the benchmark fuel analytical results). Oxygenates generally burn well and contribute to the combustion of other

# 1-12

constituents in the fuel (organically bound oxygen provides a source of oxygen for the combustion process). Oxygenates are added intentionally to clean-burning ? reformulated” gasoline to enhance the completeness of combustion in internal combustion engines. However, under poor combustion conditions, breakdown of the oxygenate at the oxygen bond can lead to the production of free radicals (Weitzman, 1991). These radicals can recombine with other radicals or compounds to form higher molecular weight chlorinated PICs. Thus, a comparable fuel specification for oxygenates is used.

1.3 Parameters and Rationale for Synthesis Gas Fuel Specifications

Comparable fuel specifications are set for ? synthesis” gas (syn-gas) separately from solid and
li quid hazardous wastes. The combustion of syn-gases meeting these specifications would be excluded from regulation as a hazardous waste. Syn-gas is generated by the gasification of hazardous wastes. Syn-gas is a mixture of primarily H 2 

# and CO, as well as the inerts of N 2 

# , CO 2 

# , Cl 2 

# , S, etc. The syn-gas characteristics depend primarily on: (1) the composition of the material that is being gasified (to date, mostly natural gas, oil, or coal, although systems for wood, plastics, sludges, and other types of wastes

are more recently being developed); (2) the use of oxygen vs. air for the gasification process; and (3)
the amount of steam utilized for the gasification process (which affects the CO/H 2 

# ratio). Syn-gas has

uses as:

• Feedstock in the chemical industry for making products such as ammonia, alcohols,

acetic acid, MTBE, etc., as well as other hydrocarbons. Also, it is used as a source of hydrogen in the petrochemical industry for hydrogenation processes. For this, a well defined and homogeneous material (usually some fossil fuel) is generally used for the syn-gas generation; and

• Fuel for power generation, heating, etc.

To ensure that the combustion of syn-gas is comparable to that of fossil fuels, specifications

are set on: (1) heating control; (2) general constituents for total chlorine, total nitrogen, and hydrogen

# 1-13

sulfide; and (3) individual Appendix VIII constituents. Rationale for the selection and determination of these specifications is discussed in the following.

1.3.1 Heating Value

A minimum heating value limit of 100 Btu/scf is set for syn-gas. The minimum specification
of 100 Btu/scf is based on syn-gas from the gasification of coal with oxygen. It is commonly required for gas turbine energy production.

For fuel usage related purposes, syn-gases are classified as either medium or low-BTU gases (medium generally being produced with pure oxygen, low-BTU generally with air). Medium BTU syngases generated from the gasification of fuels (including coal, fuel oil, biomass, municipal solid wastes, plastics, etc.) with pure oxygen can have heating values from 250-400 Btu/scf (Stultz and Kitto, 1992).
Low-BTU syn-gases generated from the gasification of fuels with air can have heating values from
about 100-200 Btu/scf. The heating value of the syn-gas depends primarily of the diluent content (nitrogen, carbon dioxide, chlorine, sulfur, moisture, etc.), which is a strong function of the syn-gas
feed material composition and gasification process (particularly if air or pure oxygen is used for the gasification process). The heating value is not a strong function of the H 2 

# /CO ratio since both gases
have similar heating values on a Btu/scf basis (although a low H 2 

# /CO ratio can adversely affect flame stability).

Syn-gas used as a fuel for power production in gas turbines typically requires a heat content
from 250-450 Btu/scf, with a lower limit of around 200 Btu/scf. Intentionally manufactured syn-gases

can have heating content levels as low as 100 Btu/scf (e.g., coal gasifiers with air). However, this gas by itself, although it may be quite burnable, does not achieve temperature and expansion ratios needed for thermodynamically efficient power generation. Thus, it is usually mixed with higher energy sources, and is not generally desired for most applications. Note that there are certain specially designed gas turbines (with very large ?

silo” combustion chambers) that can handle very low-BTU (100 Btu/scf) syngases for power generation (for example, see Geiling (1992) and Gas Turbine World (1990)).

# 1-14

Additionally, other low-BTU by-product gases are also used effectively for their fuel value (e.g., the blast furnace byproduct gas from steel manufacturing, with a heating level of about 50 Btu/scf and enhanced with gas and oil, is used in the furnace heating stoves).

Because syn-gas is sometimes used as a chemical feedstock, an absolute lower limit on heating value for comparable fuel classification may not be appropriate or needed because the syn-gas is not being used for energy recovery or supplementary purposes, making its heat content irrelevant. However, as a practical matter, whether or not syn-gas is being used as a chemical feedstock or fuel,
the syn-gas is always being produced for its CO and/or H 2 

# content -- thus all gasification related syngases will have some appreciable heat content.

It is important to note that the heating value specification is expressed on a volumetric basis of Btu/scf (as opposed to Btu/lb for solid and liquids) because: (1) is it not appropriate to compare the heating value of different gases expressed in units of Btu/lb since the ratio of the weight-to-volume
differs between different gases (particularly H 2 

# and CO); and (2) industry standard practice is to classify syn-gases based on the energy content per unit volume of gas.

1.3.2 Hydrogen Sulfide

A hydrogen sulfide (H 2 

# S) specification of 200 ppmv is set. The sulfur content of the material
used to produce the syn-gas is converted almost entirely into H 2 

# S in the gasification process, with smaller amounts of COS. Thus, syn-gases produced from low sulfur content material such as wood, biomass, natural gas, and low sulfur fuel oil and coal, do not contain any appreciable H 2 

# S. Once the
syn-gas is burned under oxidizing conditions, the H 2 

# S, if not removed prior to completing combustion,

is converted to SO x



# (primarily SO 2 

# ). SO x



# emissions are regulated through the issuance of local air permits and the Clean Air Act national ambient air quality standards.

The H 2 

# S content of high sulfur coal-based syn-gases can be over 1,000 ppmv (Stultz and Kitto,

# 1-15

1992). However, in these cases, H 2 

# S removal processes such as those based on the Claus process or regenerable metal sorbents are almost always used to reduce H 2 

# S to well below 10 ppmv prior to syngas usage as a feedstock or for fuel value (for two technical reasons: (1) H 2 

# S is much more easily removed than SO x



# which are formed from syn-gas combustion, and (2) the syn-gas has a much lower
flue gas volume than the gas produced from syn-gas full combustion). For use as a fuel, the technical limitation on the H 2 

# S content of syn-gas is due to corrosion of downstream gas handling equipment,
such as turbine blades, fans, etc. Generally levels below 200 ppmv can be tolerated. Note that for use as a feedstock, levels under 1 ppmv are usually required.

1.3.3 Nitrogen (other than N 2 

# )

A nitrogen compound level (NH 3 

# +HCN, other than N 2 

# ) of 300 ppmv is set. This is based on
the typical nitrogen compound levels (NH 3 

# +HCN) from syn-gases manufactured by coal from 100 to
300 ppmv (Stultz and Kitto, 1992). Nitrogen compounds in syn-gases are mostly in the form of NH 3 

# , with smaller amounts of HCN and other nitrogenated organics. When syn-gases are burned, the nitrogen is converted primarily to NO x 

# , which is regulated through the issuance of local air permits and
the Clean Air Act national ambient air quality standards. However, due to the increased potential to form nitrogenated PICs (as discussed previously for the comparable fuel specification for total nitrogen
in solid and liquid wastes), especially from incomplete combustion conditions associated with inefficient incinerators, a specification on total nitrogen (other than N 2 

# ) is set.

1.3.4 Total Halogens

A total halogen specification for syn-gas of 1 ppmv is set. For use as a feedstock, a total halogen level of under 1 ppmv is usually required. For use as a fuel, lower concentrations of total halogens are desired to prevent corrosion in the downstream syn-gas burning equipment. In typical gasification processes, the majority of the halogens contained in the feedstreams are converted to syngas as gaseous halides and/or halogens. (Note that in some cases where the feedstream also contains
alkali constituents such as sodium or lime, halogens may also be found in the bottom or entrained ash

# 1-16

as solid salts). The raw halogen content of the syn-gas is thus a direct function of the halogen content of the material used to generate the syn-gas. For low halogen content materials, such as natural gas,
and some fuel oils, coal, wood, and biomass streams, the syn-gas will not contain appreciable halogen levels. Alternatively, for some higher halogen content materials, such as certain coals with halogen

contents of greater than 1000 ppmv, the concentration of halogen in the resulting syn-gas may be greater than 50 ppmv. However, as discussed above for hydrogen sulfide, when the syn-gas halogen content is high, halogen removal processes are used prior to syn-gas use as a fuel or feedstock. Halogen removal efficiencies are usually very high, i.e., greater than 99%. Thus, a level of 1 ppmv is reasonably achievable even for high halogen content syn-gas materials.

1.4 Collection of Liquid Fossil Fuel Samples Used for Analysis to Determine Benchmark

Commercially available fossil fuels are very diverse. The constituents in fuels can vary, depending on where fuels are refined, the condition of the catalysts used, and the origin of the raw
material. Typically, fuels found on the East Coast are refined from Venezuelan and Middle East crude. Fuels on the West Coast are refined from domestic crude, although they can contain Venezuelan crude.
This makes it almost impossible to determine the source of a given fuel. All fossil fuels are prepared

to meet a series of American Standards for Testing Materials (ASTM) specifications, which were adopted as commercial standards by the National Bureau of Standards. These standards have been revised many times to meet changes in supply, so it is likely that they will continue to change as supplies change. The specifications focus on the physical parameters of the fuels, such as distillation temperatures, specific gravity, and viscosity.

To set the preliminary specification for comparable fuels, the EPA needed data on the
concentrations of hazardous constituents in these fuels, as well as data on the physical parameters (viscosity, heating value, etc). Since this data is not readily available, EPA collected, from various geographic locations around the country (Table 1-3), representative samples from the end uses of conventional liquid fuels. This approach was designed to ensure a representative sampling, since constituents can vary, depending on the point of origin.

# 1-17

TABLE 1-3. GEOGRAPHIC REGIONS WHERE FUEL SAMPLES WERE COLLECTED

LOCATION SAMPLES COLLECTED Irvine, California Gasoline and Nos. 2, 4, and 6 fuel oils North West New Jersey Gasoline and No. 2 fuel oil North East Connecticut Gasoline and Nos. 2 and 6 fuel oils Coffeyville, Kansas Gasoline and No. 2 fuel oil Fredonia, Kansas Gasoline and No. 2 fuel oil Norco, Louisiana Gasoline and Nos. 2 and 6 fuel oils Hopewell, Virginia Gasoline and Nos. 2 and 6 fuel oils Research Triangle Park, North Carolina Gasoline and No. 2 fuel oil

A database comparing emissions using comparable fuels and fossil fuels does not exist. Since

a comparison cannot be made between these fuels, a database on the toxic constituents of fuels being burned needs to be developed. This study analyzed each fossil fuel for all 40 CFR, Part 261, Appendix
VIII toxic organic constituents for which a reasonable approach exists under SW-846 methodologies. The study also covered physical parameters, using ASTM protocols.

Based on the results of this study, a specification can be derived for comparable fuels that ensures they contain no more toxic constituents than the ? benchmark” fuel(s). In addition, method detection limits (MDLs) were determined for each SW-846 Method used, in accordance with 40 CFR,
Part 136, Appendix B. Section 2 of this document discusses the process used for determining the MDLs in more detail.

# 1-18

References:

ASME (American Society of Mechanical Engineers), ? The Relationship Between Chlorine in Waste
Streams and Dioxin Emissions from Waste Combustor Stacks,” American Society of Mechanical Engineers, 1996.

Clarke, L.B. and L.L. Sloss, Trace Elements - Emissions From Coal Combustion and Gasification , IEA Coal Research, London, England, IEACR/49, July 1992.

Dellinger, B., P. Taylor, and D. Tirey, ? Minimization and Control of Hazardous Combustion Byproducts,” EPA/600/S2-90/039, August 1990.

Gas Turbine World, ?

Kellogg’s PFB-Hybrid Combined Cycle Concept Based on UTC/KWU V84.4 Turbines,” Gas Turbine World , pp. 20-23, Nov/Dec 1990.

Geiling, D. (editor), Proceedings of the 9th Annual Coal-Fueled Heat Engines, Advanced Pressurized Fluidized-Bed

Combustion, and Gas Stream Cleanup Systems Contractors Review Meeting , U.S. DOE Office of Fossil Energy, DOE/METC-93/6129, October 1992.

Gullett, B.K., P.M. Lemieux, and J.E. Dunn, ? Role of Combustion and Sorbent Parameters in
Prevention of Polychlorinated Dibenzo-p-dioxin and Polychlorinated Dibenzofuran Formation during Waste Combustion,” Environmental Science and Technology , Vol. 28, pp. 107-118, 1994.

Lanier, S., et al., ?

Dioxin Compliance Strategies for the HWC MACT Standards,” 1996 Incineration Conference , pp. 587-593, Savannah, Georgia, May 1996.

Perry R.H. and D. Green (editors), Perry’s Chemical Engineering Handbook , 6th Edition, McGraw Hill, pp. 9-13, 1994.

# 1-19

Reed, R.J., North American Combustion Handbook , Third Edition, North American Manufacturing Company, Cleveland, OH, p. 30, 1986.

Stultz, S.C. and J.B. Kitto (editors), Steam: Its Generation and Use , 40th Edition, Babcock and Wilcox, 1992.

Weitzman, L., ?

Engineering Handbook for Hazardous Waste Incineration,” Draft No. 3, Prepared for the EPA Center for Environmental Research Information under Contract No. 68-08-0011, Work Assignments 1-30, January 31, 1991.

Wetherold, R.G., D.A. Orr, J.M. Leonard, and B. Toole O’Neil, ? The EPRI Pisces Database: Summary of Fuels Information,” EPRI/DOE International Conference on Managing Hazardous and Particulate
Air Pollutants , Toronto, Ontario, Book 2, August 15-17, 1995.

Addink, R. and K. Olie, ? Mechanisms of Formation and Destruction of Polychlorinated Dibenzo-pdioxins and Dibenzofurans in Heterogeneous Systems,” Environmental Science and Technology , Vol. 29, No. 6, pp. 1425-1435, 1995.

Ch ristiansen, K., A. Grove, et al., Environmental Assessment of PVC and Selected Alternative Materials , Danish National Agency of Environmental Protection, 1990.

Fangmark, I., S. Marklund, and C. Rappe, ? Use of Synthetic Refuse in a Pilot Combustion System for Optimizing Dioxin Emission, Part II,” Chemosphere , Vol. 23, pp. 1233-1243, 1991.

Nielsen, P., ?

Significance of Operating Conditions and Chlorine Sources on Dioxin Formation: Experience of the Danish Incinerator Study,” Proceedings of the 1989 International Conference on Municipal Waste Combustion , Hollywood, FL, April 11, 1989.

# 1-20

Uchida, S., H. Kamo, and H. Kubota, ? The Source of HCl Emissions from Municipal Refuse Incinerators,” Ind. Eng. Chem. Res., Vol. 27, No. 11, pp. 2188-2190, 1988.

Wikstrom, E., G. Lofvenius, S. Marklund, and C. Rappe, The Role of Organic Chlorine (PVC), Inorganic Chlorine (CaCl2), Total Chlorine, and Copper in the Formation of Dioxin and Chlorobenzenes During Combustion of a Synthetic Fuel in a Pilot Reactor , Report from the Institute of Environmental Chemistry, Umea University, December 1994.

# 2 - 1

2.0 SAMPLING AND ANALYSIS

As stated previously, EPA collected and characterized samples of gasoline and Nos. 2, 4, and
6 fuel oils in order to provide data on which to base a ? benchmark” fuel. Altogether, EPA collected

ten (10) gasoline samples, eleven (11) No. 2 fuel oil samples, one (1) No. 4 fuel oil sample, and seven (7) No. 6 fuel oil samples from various geographic regions around the country.

EPA worked with the Chemical Manufacturers Association (CMA) and its member organizations in obtaining fuel samples. CMA supplied a list of members to contact, as well as a letter endorsing EPA’s efforts in this area. Contact was initiated with each company by telephone. They were questioned as to the nature of the fuels they burned in their boiler systems and, if one or

more was a fuel of concern, whether they would they be willing to supply EPA with a one-liter sample for characterization and quantification.

Many industrial users were either skeptical about participation in a program of this type or had converted their units to natural gas. However, approximately 10% of those contacted were willing to cooperate. A number of industries had switched from No. 6 fuel oil to No. 2 fuel oil and/or
natural gas, due to the difficulties and energy required to handle No. 6 fuel oil, especially in colder weather. Also, a very limited number of companies in the United States use No. 4 fuel oil. With

narrow time constraints for this program, the limited use of Nos. 4 and 6 fuel oil by U.S. industries, and the corporate restraints on participating in these type of programs, EPA was limited in the number of Nos. 4 and 6 fuel oil samples it could obtain.

2.1 Analysis of Samples

This aspect of the program focused on the analysis of the combustion fuel samples (gasoline and Nos. 2, 4, and 6 fuel oils) collected for the program in order to characterize the chemical and physical properties and the presence of the hazardous constituents listed in 40 CFR, Part 261, Appendix VIII. From a historical perspective, 40 CFR, Part 261, Appendix VIII is the reference list

# 2 - 2

of potential hazardous constituents which need to be quantitated in the fossil fuels in order to set a specification. From a practical perspective, however, the essence of such a list and testing for the
substances in the list present significant problems. The problems and some of the difficulties they impose are as follows:

1. The chemicals listed in 40 CFR, Part 261, Appendix VIII, are listed as they would
exist in a pure state, as opposed to the forms they would take after being dispersed into the environment;

2. In developing 40 CFR, Part 261, Appendix VIII, no consideration was given to
factors such as the environmental fate or the level of production of a given chemical. The list contains both prevalent, mobile, and toxic chemicals, that present major risks, and some chemicals that present a lesser risk due to low prevalence or instability in a matrix such as fuel oil or water; and

3. Analysis of many constituents from 40 CFR, Part 261, Appendix VIII would be impossible and/or impractical for the matrix being considered in this study for a variety of reasons: there are indefinitely large classes of compounds, many of which
would not exist in fossil fuels; and standards do not exist for many other compounds.

The fundamental concern for EPA in developing the comparable fuel exclusion is to create

a database by quantitating as many of the constituents from 40 CFR, Part 261, Appendix VIII as
could readily and reliably be identified in the fossil fuels. However, the development and validation of new methodologies was not within the scope of this program. Thus, it was necessary to take an approach that used existing methodologies to quanitate as many of the constituents in 40 CFR, Part 261, Appendix VIII as possible.

To quanitate each fossil fuel sample, EPA chose to use the methodologies defined for the constituents from 40 CFR, Part 261, Appendix VIII subject to the following criteria:

# 2 - 3

1) It must be practical to analyze fossil fuels for the constituent under consideration.

The chemistry of fossil fuels, the processes involved in their production, and the availability of practical and reliable analytical methodologies and standards were used to identify whether
constituents fit the later consideration.

SW-846, ?

Testing Methods for Evaluating Solid Waste,” presents the methods most commonly used for quantitating organic and metal constituents in various matrices. Since matrices vary in waste streams, the methods have some flexibility. The analyst is then allowed to adjust the sample preparation procedures for the matrix being analyzed. The following information pertains to all analytical data generated to date for the Appendix VIII analytes.

In all cases the laboratory attempted to use approved and published methodologies. There

was not time to determine what procedures were under development for fuel oil analysis by EPA or other agencies/laboratories at the time the analyzes took place.

Many of these analytes presented special analytical challenges since methods for their analysis

were not available in SW-846 or CLP methods. Additionally, the gasoline and fuel oil matrices compounded the difficulties experienced in these analyses. Consequently, data for all the targets are not presented in this report. Table 2-1 details analytes for which data is not provided and why these data points were not generated.

It is important to note that compounds marked as not detected by VOA, semi-VOA, or HPLC

were not detected using instrument conditions attempted to date. These compounds may be
detectable at concentrations greater than 200 ppm by different instrument conditions than those attempted. Compound by compound research would be required to determine an approach for their analysis.

# 2 - 4

Many metallic compounds appearing in the target lists were not specifically analyzed. Samples were analyzed for metallic elements, not organo-metallic compounds. Direct analysis for organo-metallic compounds would have been preferable, however, to the best of our knowledge, methods are not available to measure organo-metallics in these types of matrices. For example, thallium (1) acetate was reported as total thallium or lead phosphate reported as total lead.

Due to time constraints for this project, other categories were too broad for complete analysis. There are cases where the number of compounds, categories such as chlorinated fluorocarbons, are

too great to analyze for every possible isomer. In situations like these, three of the more common chlorinated freons, dichlorodifluoromethane, trichlorofluoromethane, and 1,1,2-trichloro-1,2,2-
trifluoroethane have been analyzed during the analytical phases of the clean fuels initiative. Results for chlorinated freons can be expressed as the sum of these compounds. Some of these reported compounds are listed by a synonym of the name found in Appendix VIII.

In all the analyses performed, the hydrocarbon matrix presented analytical difficulties. Most notable were the VOA and semi-VOA analyses performed by mass spectrometry. In most cases, the analyst had to manually integrate internal standards, surrogates, and targets, especially targets in the matrix spikes. These manual integrations were subjective, but were never done to intentionally misrepresent the data. In every manual integration, an honest attempt was made to isolate only the areas of interest. It must be noted that other analysts or data reviewers may have made the manual integrations differently.

For this study, each sample was collected in a pre-cleaned, 1-liter amber glass sample bottle with a Teflon ® 

# -lined cap. This type of sample bottle is available commercially with a certificate of analysis. All sample bottles were pre-cleaned according to EPA protocol. Samples were collected through purge valves, located on the main system feed lines prior to the burner. The fuel was allowed

to purge through the valve and into a waste container, ensuring the collection of a fresh sample and removing any debris which may have collected in the line or valve.

# 2 - 5

The following discussion summarizes the sample preparation, instrumental analysis and quality control procedures used to generate the data collected for each of these samples. Each section also briefly discusses any analytical difficulties encountered by the laboratory.

2.2 GC/MS Volatiles

2.2.1 Method Summary

A method for analyzing the volatile compounds was developed based on SW-846, Method
8240. A gas chromatograph with a fused silica capillary column and mass spectrometer was used to separate, identify, and quantitate the target analytes. Standards containing the target analytes in methanol were prepared at five levels. One microliter of each of these standards was used to calibrate
the analytical system. Samples were treated as if they were at high concentrations and diluted weight to volume prior to analysis. This preparation was then injected into a heated injection port thereby transferring the sample to the analytical system. The direct injection technique was chosen over purge and trap because of the high volatile organic background in the matrix.

2.2.2 Sample Preparation

Method 8240 calls for a 2.5x weight to volume sample dilution/extraction with methanol. The
methanol is the analyzed portion. To provide the lowest detection limits, a 2x dilution/extraction was performed. Actual sample weights were recorded and used to calculate the true dilution factor. Surrogate compounds were prepared in a methanol solution. The sample was diluted with methanol and surrogates were added. For gasoline, 1 g was diluted with 10 mls of methanol. In the case of
No. 2, 4, and 6 fuel oils, 4 g was extracted with 10 mls of methanol, since the fuel oils were not miscible with methanol.

# 2 - 6

Table 2-1 Analytes from Appendix VIII Not Determined During Study

Analyte Reason Data Could Not be Generated. Azaserine Compound toxicity too great to safely handle Epinephrine A solvent compatible with analysis not found Ethylenedithiocarbamic acid Standard not available Mitomycin C A solvent compatible with analysis not found alpha-naphthylthiourea A solvent compatible with analysis not found Reserpine A solvent compatible with analysis not found Selenourea Too reactive in air and water Streptozoticin A solvent compatible with analysis not found Thiosemicarbizide A solvent compatible with analysis not found Cyanogen Standard not available Nitrogen mustard Standard not available Methyl hydrazine Not detected by voa, semi-voa, or HPLC analysis Trypan blue Not detected by voa, semi-voa, or HPLC analysis Warfarin Not detected by voa, semi-voa, or HPLC analysis Chloromethoxy methane Not detected by voa, semi-voa, or HPLC analysis Chloroacetaldehyde Not detected by voa, semi-voa, or HPLC analysis Formic acid Not detected by voa, semi-voa, or HPLC analysis 2-Methyl azidrine Not detected by voa, semi-voa, or HPLC analysis Dimethyl sulfate Not detected by voa, semi-voa, or HPLC analysis Tetranitromethane Not detected by voa, semi-voa, or HPLC analysis Aldicarb Not detected by voa, semi-voa, or HPLC analysis 3,4-Diaminotoluene Not detected by voa, semi-voa, or HPLC analysis Methylthiouracil Not detected by voa, semi-voa, or HPLC analysis Ethyl carbamate Not detected by voa, semi-voa, or HPLC analysis Maleic anhydride Not detected by voa, semi-voa, or HPLC analysis Tetraethyl pyrophosphate Not detected by voa, semi-voa, or HPLC analysis Chloromethyl methyl ether Not detected by voa, semi-voa, or HPLC analysis Creosote Chromatographically identical to and inseparable from fuel oil Coal tar creosote Chromatographically identical to and inseparable from fuel oil Nitroglycerine Not detected by voa, semi-voa, or HPLC analysis N-nitrosodiisopropylamine Standard could not be procured in time for analysis N-Nitrosodiethanolamine Standard could not be procured in time for analysis 1,1-dichloropropane Standard could not be procured in time for analysis N-nitroso-N-ethylurea Not detected by voa, semi-voa, or HPLC analysis N-nitroso-N-methylurea Not detected by voa, semi-voa, or HPLC analysis Dithiobiuret Not detected by voa, semi-voa, or HPLC analysis Ethylene glycol monoethyl ether Not detected by voa, semi-voa, or HPLC analysis Methanol Not detected by voa, semi-voa, or HPLC analysis Phosphoricdithioic acid, Trimethyl Ester Standard not available

# 2 - 7

2.2.3 Instrumental Analysis

SW-846, Method 8240 was employed for the instrumental analysis. A gas chromatograph with a fused silica capillary column and mass spectrometer was used to separate, identify, and quantitate the target analytes. One microliter of each methanol extract was injected into a heated injection port thereby transferring the sample to the analytical system.

2.2.4 Quality Control

Method 8240 was followed as closely as the analyte target list and sample matrix would allow.
See Table 2-2 for additional information regarding specific procedures utilized on this project. A method blank was analyzed for each matrix. Section 2.14 of this report presents a discussion of surrogate spiking compound results for each sample and matrix spike as well as laboratory control sample (LCS) results for each analysis type. The QC results for surrogates are in Appendix D. The following specific criteria were used for this project:

50 ng of bromofluorobenzene (BFB) was analyzed at least every twelve hours with the tuning fragmentation pattern meeting the criteria specified in 8240;

A five-point initial calibration curve with each volatile target was analyzed prior to sample analysis. However, since documentation on the behavior of these compounds could not be found, arbitrary limits were not set for the initial calibration. This data should be used as a first attempt to determine practical limits for these compounds;

A continuing calibration was analyzed after each 12-hour BFB tune. Again, arbitrary limits were not set until practical recovery limits can be established; and

The following Internal Standards and surrogates were used during the analysis.

# 2 - 8 Internal Standards Concentration Surrogates Concentration
Bromochloromethane 50 mg/kg 1,2-Dichloroethane-d 4 

## 50 mg/kg 1,4-Difluorobenzene 50 mg/kg Toluene-d 8 

## 50 mg/kg Chlorobenzene-d 5 

## 50 mg/kg Bromofluorobenzene 50 mg/kg



# Table 2-2 Comparable Fuels Procedures - Organics

Volatiles Analyses
Gasoline No. 4 & 6 Fuel Oil No. 2 Fuel Oil Sample Prep Diluted with Methanol

Matrix soluble in Methanol Methanol Solvent
Matrix not

soluble in
Methanol Methanol Solvent
Matrix not

soluble in
Methanol

LCS Standards Spiked into

Methanol Standards Spiked into
Methanol Standards Spiked into
Methanol

Matrix Spiking & Surrogates Gasoline diluted with

Methanol then MS Standards & Surrogates Added Methanolic Standards Spiked into Fuel Oil, then extracted
with Methanol Methanolic Standards Spiked into Fuel Oil, then
extracted with Methanol

Comments None See Section 2.1.5 for related

comments. See Section 2.1.5 for related

comments.

Semi-Volatiles Analyses Sample Prep Diluted with MeCl

Matrix soluble in MeCl.
Extract was solvent exchanged to facilitate evaporation of interfering compounds such as xylenes. Diluted with MeCl
Matrix soluble in MeCl GPC Cleanup Diluted with MeCl
Matrix soluble in MeCl GPC Cleanup

LCS Standards Spiked into MeCl Standards Spiked into MeCl Standards Spiked into MeCl

Matrix Spiking & Surrogates Standards Spiked into

Gasoline, then diluted with

MeCl Standards Spiked into Fuel

Oil, then diluted with MeCl Standards Spiked into Fuel Oil, then diluted with MeCl

Comments None None None

# 2 - 9 HPLC 

# Analyses Sample Prep Extracted with TCLP

Extraction Fluid Extracted with TCLP
Extraction Fluid Extracted with TCLP
Extraction Fluid

LCS Standards Spiked into

Hexane then extracted Standards Spiked into Hexane
then extracted Standards Spiked into
Hexane then extracted

Matrix Spiking & Surrogates Standards Spiked into

Gasoline/TCLP fluid mixture, then extracted Standards Spiked into Fuel Oil/TCLP fluid mixture,
then extracted Standards Spiked into
Fuel Oil/TCLP fluid mixture, then extracted

Comments Mixed equal volume of

gasoline and TCLP extraction fluid, rotated 18 hrs. Analyzed TCLP fluid. Mixed equal volume of Fuel
Oil and TCLP extraction fluid, rotated 18 hrs. Analyzed TCLP fluid. Mixed equal volume of Fuel
Oil and TCLP extraction fluid, rotated 18 hrs. Analyzed TCLP fluid.



# 2.2.5 Analytical Difficulties

The oily matrix of these samples posed the largest problem. Gasoline samples were miscible with methanol, but the fuel oil samples were not. Since the fuel oil samples were not miscible with

m ethanol, results are likely to be biased low since the entire sample was not analyzed. As stated above, surrogate compounds were prepared in a methanol solution. This surrogate solution was then added directly to the specific matrix. For gasoline, which was soluble with methanol this does not
po se a problem, however, for the fuel oils, since they were not soluble with methanol, the surrogates and matrix spike results may not be truly indicative of analyte recovery from the actual matrix. Headspace analysis may be a viable alternative to SW-846 8240, methanol dilution for future work. Another significant problem was the high frequency of instrument maintenance required to maintain analyt ical reliability. Also, several target analytes showed non-linear or inconsistent responses. Although exceeding 50% RSD, epichlorohydrin and benzenethiol were all present in each initial calibration point.

# 2 - 10

2.3 GC/MS Semi-Volatiles

2.3.1 Method Summary

SW-846, Method 8270A was followed as closely as possible for the on-instrument analysis and Method 3520 was used to clean-up samples by gel permeation chromatography to allow their analysis at the lowest possible dilutions.

2.3.2 Sample Preparation

Th e gasoline samples were prepared by solvent exchange into methylene chloride. This procedure removed some of the volatile hydrocarbon background allowing analysis at lower dilutions
than untreated gasoline. Surrogates were added prior to the solvent exchange to monitor analyte
recovery. Based on the results from the MDL study (Appendix C) the solvent exchange procedure had no apparent impact on the semi-volatile results.

No. 2, 4, and 6 fuel oils were prepared by weighing 1 gram of sample, adding surrogate spiking compounds, then diluting to 10 mls with methylene chloride. The resulting solution was run through a gel permeation chromatography clean-up prior to analysis.

2.3.3 Instrumental Analysis

SW-846, Method 8270A was employed for the instrumental analysis. A gas chromatograph with a fused silica capillary column and mass spectrometer was used to separate, identify, and quantitate the target analytes. One microliter of each methylene chloride extract was injected into a heated injection port thereby transferring the sample to the analytical system.

2.3.4 Quality Control

Method 8270A was followed and included the following QC procedures. See Table 2-2 for
additional information regarding specific procedures utilized on this project. A method blank was

# 2 - 11

analyzed for each matrix. The following specific criteria were used for this project:

A 50 ng DFTPP tune was run every twelve hours and met the criteria found on page 8270-9 of SW-846, Method 8270A before any other analyses were run.

A five-point initial calibration containing each additional analyte was analyzed and average
response factors for each compound calculated. Since no documentation on the behavior of these compounds could be found, arbitrary limits were not set for the initial calibration.

Every twelve hours, immediately following the DFTPP tune, a continuing calibration was analyzed. However, for reasons listed above, arbitrary acceptance limits were not set. All samples were quantitated against the associated batch continuing calibration.

Samples were run as undiluted as possible. Dilutions were made to prevent detector saturation by non-target peaks.

Six (6) surrogate compounds, three (3) acid and three (3) base neutral extractable compounds, were spiked into each sample prior to the sample's preparation for analysis
as follows:

Surrogates Concentration Surrogates Concentration
Phenol-d 6 

## 100 ppm on-column 2-Fluorobiphenyl 100 ppm on-column 2-Fluorophenol 100 ppm on-column Nitrobenzene-d 5 

## 100 ppm on-column 2,4,6-Trichlorophenol 100 ppm on-column 4-Terphenyl-d 14 

## 100 ppm on-column



# Six (6) internal standards were used for target quantitation. All six (6) internal standards

met +/- 50% recovery in each sample as compared to the associated continuing calibration for the sample analysis to be considered valid.

Internal Standards Concentration Internal Standards Concentration 1,4-Dichlorobenzene-d 4 

## 40 ppm final dilution Phenanthrene-d 10 

## 40 ppm final dilution Naphthalene-d 8 

## 40 ppm final dilution Chrysene-d 12 

## 40 ppm final dilution Acenaphthene-d 10 

## 40 ppm final dilution Perylene-d 12 

## 40 ppm final dilution

# 2 - 12

2.3.5 Analytical Difficulties

Most problems involved contamination of the analytical instrumentation by the fuel oil matrix which caused occasional peak broadening, baseline elevation, and reduced sensitivity of easily degraded analytes. However, routine maintenance to the injection port inlet after each batch of fuel oil analysis kept the GC/MS system within acceptable operating parameters.

Most analytes performed linearly in the initial calibration. However, endothall, 6-propyl-2-
thi ouracil, and strychnine, while present in all calibration points, were greater than 50% RSD. Several other compounds exhibited poor response factors which contributed to the inability to detect them in matrix spikes.

The matrix spikes presented the greatest analytical problems. To yield meaningful recovery data, No. 2 fuel oil was diluted 10:1 with methylene chloride and spiked with compounds in a
methanol solution. The resulting solution was cleaned up by GPC, then diluted 4:1 in methylene chloride for analysis. This solution minimized fuel oil interferences. All spiked compounds recovered
within the calibration range except 4-aminopyridine, m -phenylenediamine, 3,3'-dimethoxybenzidine, and 6-propyl-2-thiouracil.

The gasoline matrix spike was solvent exchanged into methylene chloride to reduce as much
of the aromatic background as possible. No further dilution was made prior to analysis. In this mix, the following compounds, if recovered, were masked by the matrix background and reported as not detected; 2,3-dichlorophenol, 2,5-dichlorophenol, 3,4-dichlorophenol, 3,5-dichlorophenol, 3- chlorophenol, 4-chlorophenol, acetone cyanohydrin, 2,3,4-trichlorophenol, 2,3,5-trichlorophenol, 2,3,6-trichlorophenol, thiofanox, and 4-aminopyridine. Due to the time restraints of this project, a matrix spike for fuel oils No.4 and No. 6 was not prepared and analyzed.

# 2 - 13

2.4 High Pressure Liquid Chromatography (HPLC)

2.4.1 Method Summary

Amethod for analyzing fuel oils was developed modeling similar HPLC methods such as SW846, Method 8310 as closely as possible. A modified TCLP type extraction was performed and a diode array HPLC detector was used to measure analyte concentration.

2.4.2 Sample Preparation

Fuel oils were extracted with a Toxicity Characteristic Leaching Procedure (TCLP) extraction fluid by adding equal volumes of gasoline or No. 2 fuel oil with the TCLP fluid in a 22 ml vial. No.
4 and 6 fuel oils were first diluted 10:1 with hexane due to their viscous properties which allowed thorough mixing of sample and extraction fluid. The 22 ml vial was sealed and agitated on a TCLP
extraction apparatus for a minimum of 12 hours. Additional cleanup of the TCLP extract was not required.

2.4.3 Instrumental Analysis

A 10 microliter aliquot of extraction fluid was analyzed by HPLC using a 25 cm x 4.6 mm, 5
micron particle, reverse phase ABZ+Plus column. A diode array detector was used to measure analyte concentration.

2.4.4 Quality Control

Method 8310 was followed as closely as the sample matrix would allow. See Table 2-2 for
additional information regarding specific procedures utilized on this project. A method blank was analyzed for each matrix. Section 2.14 of this report presents a discussion of surrogate spiking compound results for each sample and matrix spike as well as laboratory control sample (LCS) results for each analysis type. The QC results for surrogates are in Appendix D. The following specific
criteria were utilized.

# 2 - 14 Internal standards were not used. External calibration procedures were used to measure analyte concentration.

Acetophenone was used as a surrogate to evaluate extraction performance. The surrogate was added to the 22 ml vial just prior to the agitation process. Surrogate was added to produce a concentration of 20 mg/kg on-column.

A five-point calibration curve was analyzed for quantitation of analytes. However, since documentation on the behavior of these analytes could not be found, arbitrary limits on the correlation coefficients of the analytes were not set. Instead, the curves were analyzed
and processed to the best ability of the analyst. This data should be used as a first attempt in determining acceptable calibration curve limits.

A QC check was analyzed at least every twelve hours during sample analysis. An arbitrary limit of +/- 30% recovery for each analyte was adopted for the QC check. The acceptance limit may be reduced when more data about the behavior of these analytes is
collected and evaluated.

No recovery limits for surrogate recovery were arbitrarily set. However, the recovery had to be at least to the compound's detection limit.

2.4.5 Analytical Difficulties and Recommendations

Since each fraction was prepared and analyzed separately, the spiking concentrations ranged from 20 ppm in the gasoline to 100 ppm in the fuel oils. While the gasoline spikes showed recovery for all analytes, some of the recoveries were close to the lower calibration limit. For this reason, subsequent spiking concentrations were increased.

The analytes spiked into the fuels are not readily soluble in a non-polar matrix. For this reason, the spiking solutions were prepared in methanol to get them into a liquid matrix and the methanol
solution was added to the extraction vessel with sample and extraction fluid. Under these conditions,

# 2 - 15

the spiked compounds probably did not dissolve into the fuel oils matrix prior to extraction and therefore, the generated data may only provide very limited information.

Not all spiked compounds recovered ideally. In gasoline, thioacetamide only recovered at 10% and the diamines at about 50%. MNNG and ethylene thiourea were at nearly 200% recovery even though these compounds were not detected in the unspiked sample. Only thioacetamide recovered unusually in No. 2 fuel oil at nearly 300% with no detection of this compound in the unspiked sample. Thioacetamide also recovered high in the No. 6 fuel oil. Additionally, neither MNNG nor ethylene thiourea was detected in the matrix spike of No. 6 fuel oil.

The following are offered as suggestions for possible future studies. Due to the time constraints for this project, these possibilities were not tested. Different analytical columns may improve analyte recovery and chromatographic quality. Also, a much larger range of analytes may be analyzed by HPLC with different columns.

A better way of spiking fuel oils with polar analytes may be possible. However, these procedures may have to be researched and tested on a compound-by-compound basis. Entire classes of analytes were attempted for this project to analyze the largest number of analytes possible. In
addition , other extraction techniques such as solid phase extraction may improve recovery and increase the number of analytes seen by HPLC.

2.5 Dioxins and Dibenzofurans

2.5.1 Method Summary

Due to the large number of individual isomers, analyte toxicity, and the high cost of standards,
the dioxins (PCDD) and dibenzofurans (PCDF) were not analyzed by a published method, but as follows.

A standard was procured and calibrated for one select isomer of each group. For example,
there are seven (7) isomers of tetrachlorodibenzo-p-dioxins, but only 2,3,7,8-PCDD was analyzed.

# 2 - 16

The remaining isomers were searched for as 2,3,7,8-PCDD. The following listing provides specific isomer information.

Tetrachlorodibenzo-p-dioxins (Searched as 2,3,7,8-PCDD)

2,3,7,8-PCDD 1,2,3,4-PCDD 1,3,6,8-PCDD 1,3,7,9-PCDD 1,3,7,8-PCDD 1,2,7,8-PCDD 1,2,8,9-PCDD 

# Pentachlorodibenzo-p-dioxins (Searched as 1,2,3,7,8-PCDD)

1,2,3,7,8-PCDD 1,2,3,4,7-PCDD 

# Hexachlorodibenzo-p-dioxin (Searched as 1,2,3,6,7,8-PCDD)

1,2,3,4,7,8-PCDD 1,2,3,6,7,8-PCDD 1,2,3,7,8,9-PCDD 

# 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin (only hepta isomer)
Octachlorodibenzo-p-dioxin (only octa isomer)

Tetrachlorodibenzofurans (Searched as 2,3,7,8-PCDF)

2,3,7,8-PCDF 1,2,3,4-PCDF 1,3,6,8-PCDF 1,3,7,9-PCDF 1,3,7,8-PCDF 1,2,7,8-PCDF 1,2,8,9-PCDF



# Pentachlorodibenzofurans (Searched as 1,2,3,7,8-PCDF)

1,2,3,7,8-PCDF 1,2,3,4,7-PCDF



# Hexachlorodibenzofurans (Searched as 1,2,3,6,7,8-PCDF)

1,2,3,4,7,8-PCDF 1,2,3,6,7,8-PCDF 1,2,3,7,8,9-PCDF 

# 1,2,3,4,6,7,8-Heptachlorodibenzofuran (only hepta isomer)

Octachlorodibenzofuran (only octa isomer)

A curve was not analyzed for these compounds. Instead, a one-point calibration was run after each 12- hour DFTPP tune. The analytical instrument was calibrated to look for PCDDs and PCDFs

# 2 - 17

in samples in a present or not present mode rather than a quantitative mode.

2.5.2 Sample Preparation

For gasoline, PCDDs and PCDFs were searched concurrently with the semi-volatile analyses. See the semi-volatile sample preparation for details.

For the No. 2, 4, and 6 fuel oil samples, the GPC extracts could not be used for PCDD and PCDF analysis. The No. 2 fuel oil spiked with these compounds had no recovery. It was assumed that the GPC process removed these analytes from the spike.

Instead, No. 2 fuel oil was spiked with PCDDs and PCDFs in a 10:1 dilution then cleaned up
with sulfuric acid. The remaining organic layer was analyzed with no further dilution. To minimize

waste product with PCDDs and PCDFs, only No. 2 fuel oil was spiked. The remaining unspiked fuel oils were prepared in the same way prior to analysis.

2.5.3 Instrumental Analysis

See the semi-volatile instrumental analysis for details.

2.5.4 Quality Control

A method blank was analyzed for each matrix.

2.5.5 Analytical Difficulties and Recommendations

The sample clean-up used for this analysis effectively removed most of the hydrocarbon background. If this clean-up procedure was used with SIM mode mass spectrometry or high
resolution mass spectrometry, much lower detection limits may be possible for PCDDs and PCDFs.

Also, calibration for each isomer in a five-point curve is possible. However, the cost of the

# 2 - 18

standards and waste disposal would be significant.

2.6 Herbicides

2.6.1 Method Summary

SW-846, Method 8150 was followed for the on-instrument analysis and Method 3580 (Waste Dilution) was used in the initial sample preparation.

2.6.2 Sample Preparation

Samples were prepared in hexane as per Method 3580. A 1.0 ml aliquot was taken from the
3580 fraction, added to 0.2 ml methanol and brought to a volume of 5.0 ml with diethyl ether. Samples were then derivitized by the diazomethane bubbler procedure as per Method 8150. Samples were then analyzed by gas chromatography.

2.6.3 Instrumental Analysis

Instrumental analysis was conducted by injecting one (1) μl of extract on dual capillary columns equipped with electron capture detectors (ECD). The capillary columns employed were a DB-608
and a DB-1701.

2.6.4 Quality Control

A five-point external standard calibration procedure was used, with a 12-hour window for valid sample analyses. 2,4-Dichlorophenylacetic acid was used as a surrogate. No limits for surrogate recovery were set. A method blank was analyzed for each matrix.

2.6.5 Analytical Difficulties and Recommendations

The hydrocarbon matrix did not seem to cause interference in the derivitization of the acid

# 2 - 19

herbicides.

2.7 Metals

2.7.1 Method Summary

EPA SW-846, Method 3040 was used for the preparation of all samples in this study. The method is a dissolution procedure. All dissolved samples were then analyzed by the appropriate SW846 flame method, with the exception of arsenic and selenium, where the appropriate graphite furnace atomic absorption method was used. Mercury was analyzed by cold vapor atomic absorption.

2.7.2 Sample Preparation

All samples were prepared using EPA SW-846, Method 3040. All of the samples were diluted 1:10 with xylene. Final results were reported as mg/kg from the original weight.

2.7.3 Instrumental Analysis

Diluted samples were analyzed by the appropriate flame atomic absorption methodology, with the exception of arsenic and selenium, where the graphite furnace atomic absorption was chosen, and
mercury, which was analyzed by cold vapor atomic absorption. The analysis of all of the diluted samples proceeded normally.

2.7.4 Quality Control

In general, a blank and three standards were used to perform initial calibration. Correlation
coeffici ents were calculated for each curve, a QC check sample was analyzed after each curve, with the exception of osmium. An initial calibration verification and an initial blank verification were then performed. After every ten samples or between matrices, a calibration verification and a blank verification were performed. A duplicate sample and a matrix spike were performed on each matrix along with a method blank.

# 2 - 20

For each metal analyte, a standard curve was performed. In all cases, the source for the stock standard was SPEX. The QC check sample was obtained from Conostan. All curves were linear and

most correlation coefficients were better than 0.995. At the beginning and during each run, standard
calibration checks and blank calibration checks were performed. All initial and continuing calibration blanks were less than the established PQL. All initial and continuing calibration verification results

were between 90-110% with the following exceptions: Lead stayed at about 111% for the duration of the run and did not deviate more than 1-2%; and arsenic was variable, although most of the values were 90-110%. Due to its volatile nature, the osmium results were 80-120%.

Sample matrix QC consisted of preparing and analyzing one duplicate and spike for each matrix.
For values significantly above the PQL, the results for relative percent differences were less than 20%. The No. 4 fuel oil’s selenium result at the PQL showed some variability in the duplicate result. This may be due to the matrix. Most of the spike results were very good and fell within the 75-125%
limit with the following exceptions: The barium spike for the No. 6 fuel oil returned a value of 72%. This could be attributed to the matrix; the silver spike results were unusual in that they were all high.
This may be due to some stabilizing effect in the fuel versus xylene solvent; all selenium results were good, except for the No. 4 fuel oil mentioned above. Spike results for mercury were exceptional,
relative to the method used. This round of results gave 36-47% recovery for mercury spike across the matrices.

2.7.5 Analytical Difficulties and Recommendations

The analysis of all of the diluted samples proceeded normally. Most of the spike results were
very good and fell within the 75-125% recovery limit with the following exceptions. Osmium in the gasoline matrix was 59% and tin in the No. 4 and 6 fuel oil was low. While it is unknown why the osmium result was so low, the tin results could be attributed to the matrix.

The mercury method is not as well suited to the matrices encountered in this study. The spike results were the best that could be obtained under these conditions. In the time allowed, we could not find a second standard source for thallium and manganese. Silver displayed some unusual variability in the results for the QC check and the spike. Silver may be more susceptible to certain

# 2 - 21

kinds of matrix enhancements that were not well documented. The furnace methods used to analyze arsenic and selenium needed some extra effort to set up properly, although once the furnace method was set, the results were very good.

2.8 Pesticides and PCBs

2.8.1 Method Summary

SW-846, Method 8080 was followed for the on-instrument analysis and Method 3580 (Waste Dilution) was used in the initial sample preparation. Method 3665 (sulfuric acid) was used to cleanup the samples prior to analysis for the Aroclor PCBs. No clean-up procedure was used for preparation of the extracts for pesticide analysis.

2.8.2 Sample Preparation

The samples were prepared using Method 3580. One (1) gram of sample was diluted to 10 mls.
with Hexane.

2.8.3 Instrumental Analysis

Instrumental analysis was conducted by injecting one (1) μl of extract on dual capillary columns equipped with electron capture detectors (ECD). The capillary columns employed were a DB-608
and a DB-1701.

2.8.4 Quality Control

A method blank was analyzed for each matrix and an Endrin/DDT standard was analyzed prior to calibration and sample analysis, to ensure a <20% breakdown of the pesticides.

A five-point initial external calibration containing each single-response pesticide generated prior

to sample analysis. A single-point external calibration standard was analyzed for all multi- response

# 2 - 22

pesticides and PCBs for qualitative identification. A five-point initial external calibration curve was generated for one of the multi-response compounds (Aroclor 1260), for quantitative analysis.

Two surrogates, dibutylchlorendate and tetrachloro-m-xylene were used to monitor the integrity
of the sample preparation and analytical system. The surrogates were added to produce a concentration of 10 μg/kg on-column. No limits were set for surrogate recovery, however, both surrogates were required to be present to validate each analysis.

2.8.5 Analytical Difficulties and Recommendations

The higher molecular weight components of the fuel oils No. 4 and No. 6 caused some interference with the analyses. The primary problem was difficulty eluting these heavy compounds
from the GC column. This problem was absent from samples for PCB analysis that underwent Method 3665 clean-up. Perhaps a clean-up method suitable for pesticides, such as alumina or florisil column clean-up or Gel-permeation clean-up would produce better results.

2.9 Heating Value

2.9.1 Method Summary

Heat of combustion was determined using ASTM Standard D 240. In this test method, heat of combustion was determined by combusting a weighed sample in an Oxygen Bomb Calorimeter
under controlled conditions. The rate of combustion was computed from temperature readings before and after combustion.

2.9.2 Quality Control

QC procedures consisted of one duplicate determination per every ten (10) samples and an analysis of a certified standard benzoic acid pellet per every ten (10) samples. Method precision and reproducibility were within the ranges specified in the method. Gross heat of combustion was

re ported. No adjustments were made for the heat of combustion of nitrogen and sulfur in the sample.

# 2 - 23

Values were reported as Btu/lb rather than in the SI units of MJ/kg, as stated in the method.

2.10 Specific Gravity

2.10.1 Method Summary

Specific gravity was determined by using ASTM Standard D 1298. This method uses a hydrometer to determine specific gravity after the sample and apparatus were brought to a stable temperature of 60°F. The appropriate hydrometer was lowered into the sample cylinder and allowed

to settle. At positional equilibrium, the hydrometer was read and the temperature of the sample
noted.

2.10.2 Quality Control

The hydrometers used were calibrated in accordance with National Institute of Standards and Technology (NIST) Circular 555, and ASTM specification E 100. All sample temperatures were brought to 60°F for a period of five (5) hours prior to hydrometer readings. Duplicate determinations were performed per every ten (10) samples. All duplicates were within 5% RSD.

2.10.3 Analytical Difficulties and Recommendations

All specific gravity readings were made at 60°C as per ASTM D 1298. Highly viscous opaque samples presented problems in the accurate readings of the hydrometer. Air bubbles trapped in the more viscous samples may have had a minor influence on the reported results.

2.11 Flash Point

2.11.1 Method Summary

Flash point was determined by EPA SW-846, Method 1010, which is similar to ASTM Standard D 93, using a Pensky-Martens closed-cup Flash Tester. The sample was heated at a slow constant

# 2 - 24

rate with continual stirring. A small flame was directed into the cup at regular intervals with simultaneous interruption of stirring. The flash point was the lowest temperature at which application of the test flame ignited the vapor above the sample.

2.11.2 Quality Control

Duplicate determinations were made on each of the ten (10) samples. All duplicates were within 2°C of the original result. Gasoline flash points were below the range attainable by the PenskyMartens Method. These values were reported as less than 0°C.

2.12 Total Halogens

2.12.1 Method Summary

EPA Method 325.3/PARR and ASTM Standard D 4929 were used to analyze the samples for total halogens. The sample was ignited in a PARR bomb as part of the determination of gross heat
of combustion. After combustion of two previously weighed samples, the resulting inorganic residue solution was washed from the inside surfaces of the PARR bomb. The wash water was brought to

a total volume of 10 milliliters and titrated per EPA Method 325.3. Bromine, chlorine, and iodine

are all reported as total chloride. Fluorine does not react with the titrant of EPA Method 325.3 and is not included in the reported values.

2.12.2 Quality Control

In the PARR bomb combustion process, a weighed sample is placed in the PARR bomb under
35 atmospheres of oxygen, approximately 515 psi. Combustion is rapid and complete with no traces
of organic material remaining in the bomb. In order to assure the conversion of organic halide to inorganic halogen ion, samples were spiked with known amounts of methylene chloride prior to
combustion in the bomb. Recovery of spiked halogen was in the range of 87% to 92% for all gasoline and No. 2 fuel oil samples. For Nos. 4 and 6 fuel oil samples, recovery was in the range of 20% to 45%, which was unacceptable. It is probable that the higher nitrogen content of the Nos. 4

# 2 - 25

and 6 fuel oils resulted in the production of significant amounts of nitric acid during the PARR bomb combustion process. The nitric acid resulted in unacceptably high levels of ferric and chromate ions
from the reaction with the stainless steel PARR bomb. Ferric and chromate ions are an interferant in the EPA Method 325.3 titration process.

2.12.3 Analytical Difficulties and Recommendations

In order to obtain reliable halogen values for the Nos. 4 and 6 fuel oils, these samples were analyzed by ASTM Standard D 4929, a method for determining the organic chloride content in crude

o il. This method lists a rinse step to remove inorganic halides from the petroleum product. This step

was omitted so that a total halide value would be determined for these samples. The method involves oxidation of a known weight sample in an oxygen stream at 800 C. The oxygen stream was then led

to a microcoulometric cell, where the halide ions react with coulometrically-generated silver ion. The microequivalents of silver ion consumed in the titration was equal to the microequivalents of titratable
halide ion in the oxidized sample. Bromine and iodine titrate as chloride equivalents. Fluorine does not respond and is not included.

In the oxygen combustion process, approximately 50% of the bromine and iodine form oxyhalides (HOBr and HOI) which do not react in the titration. Bromine and iodine, therefore, provi de an approximate 50% response factor. Calibration curves, replicate analyses, and checks using 2,4,6 trichlorophenol were performed on the sample daily.

2.13 Total Nitrogen

2.13.1 Method Summary

ASTM Standard D 4629 was used to analyze the samples for total nitrogen. The sample of liquid petroleum hydrocarbon was injected into a stream of inert gas. The sample was vaporized and
carried to a high temperature zone where oxygen was introduced converting organic bound nitrogen nitric oxide (NO). The NO contacts ozone and emits light, through a process of chemiluminescence, which was detected by a photo multiplier as a measure of the nitrogen contained in the sample.

# 2 - 26

2.13.2 Quality Control

The instrument was calibrated using nitrogen standards of pyridine or carbazole. Pyridine is used for samples with mid-range boiling points less than 430 F. Carbazole was used for samples of higher boiling ranges. Method blanks were performed using toluene for gasoline samples and cetane for the higher boiling No. 2, 4, and 6 fuel oil samples.

Reprod ucibility values were within the specifications stated in ASTM Standard D 4629. All samples were run as replicate analyses. A calibration curve and a known check sample were run daily.

2.14 General Matrix Spike and Laboratory Control Sample Recovery

Every sample, blank, matrix spiked samples, and laboratory control samples were spiked with surrogate spiking compounds prior to the sample preparation. Recovery criteria for petroleum products is not established in the methodology. Therefore, acceptance limits were not used by the laboratory as a means of rejecting an analysis.

Matrix spikes and LCS samples were analyzed concurrently with the fuel oil samples. Due to the unknown analytical characteristics of the analytes in fuel oil and the unknown affect the sample preparation procedures may have had on these quality control samples, acceptance limits were not used by the laboratory as a means of rejecting an analysis. These data should be viewed as a first attempt to set acceptance limit criteria. Overall the recoveries calculated from the MDL study, which also represents some of the spike results, meet the method criteria except were it has been noted in
the individual method discussions in this section.

Table 2-2 lists the specific procedures utilized for matrix spiking and the laboratory control sample s. It is recommended that the description associated with each analytical fraction be reviewed
for additional details.

# 2 - 27

2.15 Analysis for Total Aromatic Hydrocarbons and Total Polynuclear Aromatic Hydrocarbons

The analysis for total aromatic hydrocarbons and total polynuclear aromatic hydrocarbons yielded results much lower than expected. A small number of specific analytes in these categories

were analyzed and summed into totals. There were numerous analytes and isomers that should have been included in this total, but due to the huge number of compounds, they could not be individually
calibrated and quantitated. The majority of these compounds are not listed in Appendix VIII and do not have validated methods for analysis. Other methods more suited to this type of analysis, other
than identification and quantitation of individual compounds, should be considered for these total numbers.

# 3-1

3.0 RESULTS

3.1 Laboratory Results

Appendix A lists the laboratory results for the semi-volatile, volatile, metals, inorganic parameters, physical parameters, and total aromatic hydrocarbons. These results were submitted to
SAIC for statistical analysis which are presented in Appendix B. Appendix C lists the laboratory
derived Method Detection Limit (MDL) Study results for each analyte. Appendix D lists the QA data results. The QA data includes surrogate spiking compound recovery for semi-volatile and volatile
methods and duplicate and spike recoveries for metals. As stated in Section 2, the results for polynuclear aromatic hydrocarbons and total aromatic hydrocarbons are much lower than expected.
The method used to generate these concentrations was to sum the results of the semi-volatile analysis. The constituents listed in 40 CFR, Part 261, Appendix VIII that could be quantitated only included a small number of the aromatic hydrocarbons which are normally present in fossil fuels.

3.2 Constituents Levels

Appendix B lists the comparable fuel constituent specifications for the final rule. The comparable fuels consist of four fuel types – gasoline and Nos. 2, 4, 6 fuel oils. The available data contain chemical compound concentrations from eight (8) samples from gasoline, 11 samples from No. 2 fuel oil, one (1) sample from No. 4 fuel oil and seven (7) samples from No. 6 fuel oil. The final constituent levels were calculated using the composite at the largest value.

For chemical in which at least one sample was measured above the minimum level of detection, the composite was based on the measured concentrations from the detected samples and

on the quantitation limits from the non-detect samples. The composite values are presented in the table under the column heading “Concentration Limit.” For chemicals in which none of the samples were measured above the minimum level of detection, the composite value was based on the reported quantitation limits and are presented in the table under the column heading “Minimum Required

# 3-2

Detection Limit.” However, the final rule allows metals, hydrocarbons, and oxygenates to be present

at any concentration less than or equal to the detection limits. For these compounds, all composite
value are reported as a concentration limit, using the reported quantitation limits as concentration limit in the case where none of the samples were measured above the minimum detection limit.

For constituents with at least one detected sample, concentration limits have been corrected
from the fuel’s heating value to 10,000 BTU/lb. For constituents with no detected samples, the concentration limits (in the case of metals, hydrocarbons, or oxygenates) or minimum required detection limits are not corrected to 10,000 BTU/lb.

3.3 Estimates from Additional Halogen Data

Additional analysis was performed to calculate the highest value composite for total halogens. Because the analysis for No. 4 and No. 6 fuel oils was based on analytical methods measuring only
total organic and inorganic halogens, additional data was gathered from EPA’s database (i.e., Certificates of Compliance required by the BIF rule) and data submitted by one commenter. The
additional Total Chlorine data is presented in Table 3-1. The total halogen value has been normalized for the fuel’s heating value to 10,000 BTU/lb. This additional data was composited with the gasoline and No.2 fuel oil data contained in this report.

3.4 Statistical Analysis Results (SAIC) (Proposal)

This section presents the results from statistical analyses, performed by Science Applications International Corporation (SAIC), of chemical compound concentrations measured in comparable
fuels for the proposed rule. As discussed previously, the comparable fuels consist of four fuel types

—gasoline and Nos. 2, 4, and 6 fuel oils. Statistical analyses also were conducted on two (2)
combinations of these fuel types: a composite of the three (3) fuel oils (Composite 246); and a composite of all four (4) fuel types. The available data contain chemical compound concentrations
from eight (8) samples from gasoline, 11 samples from No. 2 fuel oil, one (1) sample from No. 4 fuel

# 3-3

oil, and seven (7) samples from No. 6 fuel oil.

This statistical analyses estimated percentiles from the distribution of concentrations of each chemical compound within each fuel type. For each individual fuel type, the 90th percentile was

e stimated for every chemical compound. For the composite fuel types, estimates of the 50th and 90th percentiles were calculated for each chemical compound. Section 3.4.1 of this report presents the
statistical analysis of the individual fuel types. Section 3.4.2 documents the statistical methodology for estimating percentiles from the composite of Nos. 2, 4, and 6 fuel oils. The analysis of the composite of all four fuel types is presented in Section 3.4.3.

The results from the statistical analyses of these fuel types are presented in Appendix C in the following tables:

• Table 1: Estimated 90th percentiles from gasoline;

• Table 2: Estimated 90th percentiles from No. 2 fuel oil;

• Table 3: Estimated 90th percentiles from No. 4 fuel oil;

• Table 4: Estimated 90th percentiles from No. 6 fuel oil;

• Table 5: Estimated 50th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 6: Estimated 90th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 7: Estimated 50th percentiles from the composite of all four fuel types;

• Table 8: Estimated 90th percentiles from the composite of all four fuel types; and

As stated earlier, the samples were analyzed in two rounds based on the availability of clearly defined analytical protocols. For the additional compounds that were found during the second round
of analyses the following tables, in Appendix C, represent the results from the statistical analyses of these fuel types. The methodology and discussion of the analysis conducted on the original set of data still applies to the information displayed in these tables as well.

# 3-4

• Table 1A: Estimated 90th percentiles from gasoline;

• Table 2A: Estimated 90th percentiles from No. 2 fuel oil;

• Table 3A: Estimated 90th percentiles from No. 4 fuel oil;

• Table 4A: Estimated 90th percentiles from No. 6 fuel oil;

• Table 5A: Estimated 50th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 6A: Estimated 90th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 7A: Estimated 50th percentiles from the composite of all four fuel types;

• Table 8A: Estimated 90th percentiles from the composite of all four fuel types; and

Wit hin each table, two (2) sets of estimates are presented. For chemicals in which at least one (1) sample was measured above the minimum level of detection, the estimated percentiles were based

on the measured concentrations from the detected samples and on the quantitation limits from the
non-detect samples. These estimates are presented in the tables under the column heading "Concentration Limit." For chemicals in which none of the samples were measured above the
minimum level of detection, the estimated percentiles were based on the reported quantitation limits and are presented in the tables under the column heading "Minimum Detection Limit."

All chemical concentrations were originally reported in the database with units equal to mg/kg. For the chemicals with at least one (1) detected sample, these concentrations were converted to mg/J using the reported heating values (Btu/lb) and the following conversion formula:

Concentration mg

J Concentration mg kg

2326

. 11 ( lb

kg ) ( J BTU ) Heating Value BTU lb

The estimated percentiles were generated from the mg/J concentrations and were converted
back to mg/kg, for presentation in the tables, based on a heating value of 10,000 Btu/lb. For the

# 3-5

chemicals with no detected samples, the percentiles were calculated from reported quantitation limits in the original units of mg/kg. All results are presented with two (2) significant figures.

3.4.1 Estimates for Each Individual Fuel

Estimated percentiles for the chemical compounds from each individual fuel type (i.e., gasoline
and Nos. 2, 4, and 6 fuel oils) are presented in Appendix B, Tables 1 through 4 and Tables 1A through 4A, respectively. Only the chemicals that are contained in the 40 CFR, Part 261, Appendix
VIII list are presented in these tables. Each of these tables presents the estimated 90th percentile for chemicals with at least one (1) detected concentration and undetected chemicals above the quantitation limit. The percentile estimates from the detected chemicals are presented under the column heading "Concentration Limit," and the percentiles for the non-detected (non-detect) chemicals are presented under the column heading "Minimum Detection Limit." For the chemicals with at least one (1) detected sample, the percentile estimates were based on the measured value for
the detected samples and on the reported quantitation limits for the non-detect samples. For the chemicals with no samples measured above the minimum level of detection, the percentile estimates were based on the reported quantitation limits.

When calculating the quantitation limit for volatile organic compounds (VOCs) in gasoline,
in the analytical methods, there are matrix interferences that cause the calculated quantitation limits to be unreliable. Therefore, for the VOCs that were not detected in any of the gasoline samples, the estimated 90th percentile is not presented in Appendix B, Table 1. For these chemicals, the 90th percentile estimate from the composite of the Nos. 2, 4, and 6 fuel oils is presented in Appendix C, Table 1 as a surrogate for the 90th percentile for gasoline.

The estimated percentiles presented in Appendix C, Tables 1 through 4 and Tables 1A through 4A, were generated nonparametrically. That is, the percentiles are based on the rank order statistics of the sample concentrations. Distributional assumptions were not used in the calculation
of the percentile estimates because of the sparse sample sizes. For gasoline, at least one of the eight

# 3-6

(8) samples was measured above the minimum level of detection for only nine (9) of the 151 chemical compounds found in 40 CFR Part 261 Appendix VIII. For No. 2 fuel oil, at least one (1) of the 11 samples was measured above the minimum level of detection for only 11 of the 151 chemicals. Only

one (1) sample was measured for each chemical compound from No. 4 fuel oil, and only 13 of the
chemical compounds were measured above the minimum level of detection in this sample. For No.
6 fuel oil, at least one (1) of the seven (7) samples was measured above of the minimum level of detection for only 16 of the chemicals.

All of the chemicals originally were reported in units of mg/kg. The 90th percentile estimates for non-detect chemicals, under the column heading "Minimum Detection Limit," are presented in the original units of mg/kg. The percentile estimates for chemicals with at least one (1) detected sample, under the column heading "Concentration Limit," were calculated from concentrations that were
converted from mg/kg to mg/J based on the report heating values (Btu/lb) for each sample. Then, the percentile estimates were converted from mg/J back to mg/kg based on 10,000 Btu/lb.

The nonparametric procedure for calculating the percentile estimates was based on standard procedures, namely PROC UNIVARIATE (Def. 5), in the SAS statistical software package. This standard nonparametric procedure is outlined in the following steps.

1. Let x 1 

# , x 2 

# , x 3 

# , ..., x n 

# represent the chemical concentrations from the n-samples, ranked from lowest to highest, where n equals the total number of samples.

2. To calculate the 90th percentile, let 0.90*n = j + g, where j is the integer part of 0.90*n and g is the fractional part of 0.90*n.

3. The estimated 90th percentile is calculated as:

(xj + xj+1)/2, if g = 0; and (xj + 1), if g > 0.

# 3-7

Example: In No. 6 fuel oil, data were available from seven (7) samples. Therefore, n=7 and 0.90*n=6.3. The integer part (j) is equal to 6, and the fractional part (g) is equal to 3/10. Because the fractional part (g) is not equal to zero, the 90th percentile is equal to the interpolated values of the concentrations between the 6th and 7th samples. That is, the 90th percentile is the average of the largest concentration and the second largest concentration.



# The estimated percentiles from this methodology are presented under the column heading "Concentration Limit" in Appendix C, Tables 1 through 4.

3.4.2 Estimates from Composite 246

In addition to the percentile estimates from each individual fuel type, percentile estimates are presented for a combination of Nos. 2, 4, and 6 fuel oils. This combination of fuel oils is labeled "Composite 246." The estimated percentiles presented under combination of fuel oils are weighted estimates from the chemical concentrations from the three (3) fuel oils. Estimates were generated
from all reported samples of these fuel oils, using the measured concentrations from the detect samples and the reported quantitation limits from the non-detect samples.

Appendix C, Table 5 presents estimated 50th percentiles from the composite of Nos. 2, 4, and
6 fuel oils. Estimated 90th percentiles are presented in Appendix C, Table 6. For chemicals with at least one (1) detected concentration, the percentile estimates are presented under the heading
"Concentration Limit". The percentile estimates for the chemicals with no detected concentrations are presented under the heading "Minimum Detection Limit."

The estimated percentiles were generated by weighting each sample according to the number
of samples available from each fuel type. This adjustment provides equal contribution from each sample to the composite estimate. That is, each fuel type should represent one-third of the population. Therefore, each sample from No. 2 fuel oil, which contained 11 samples, was assigned

# 3-8

a weight of 1/33; the sample from No. 4 fuel oil was assigned a weight of 1/3; and each sample from
No. 6 fuel oil, which contained seven (7) samples, was assigned a weight of 1/21. The chemical
concentrations were then ranked from lowest to highest and the weights were summed across samples until the total weight was equal to 0.50. The corresponding chemical concentration was used as the
estimated 50th percentile. That is, the 50th percentile is the concentration corresponding to the ranked sample for which 50% of the weights were accounted. If the sum of the weights does not equal 0.50 exactly, then the 50th percentile is the interpolated value of the two (2) reported concentrations surrounding the 50th percentile point. Similarly, the 90th percentile was estimated by the corresponding concentration when the sum of the weights was equal to 0.90.

As in the calculation of the percentiles for each individual fuel type, the percentiles for the dete cted chemicals are presented in units of mg/kg at 10,000 Btu/lb, and the percentiles for the nondetect chemicals are presented in the original units of mg/kg. All of the chemicals originally were reported in the database with units of mg/kg. The percentile estimates for chemicals with at least one (1) detected sample, under the column heading "Concentration Limit," were calculated from concentrations converted from mg/kg to mg/J, based on the reported heating values (Btu/lb) for each sample. The percentile estimates then were converted from mg/J back to mg/kg based on 10,000 Btu/lb. For the chemicals with no samples measured above the minimum level of detection, the percentile estimates were based on the reported quantitation limits in the original units of mg/kg.

3.4.3 Estimates from Composite of All Fuel Types

Appendix C, Tables 7, 7A, 8, and 8A present percentile estimates for a combination of all four (4) fuel types (i.e., gasoline and Nos. 2, 4, and 6 fuel oils), labeled "Composite All." The estimated percentiles presented under this combination of fuel types are weighted estimates from the chemical concentrations from the four fuel types. Estimates were generated from all reported samples of these
fue l types, using the measured concentrations from the detected analytes in the samples and the reported quantitation limits from the non-detect analytes in the samples.

# 3-9

Appendix C, Table 7 and Table 7A presents estimated 50th percentiles from the composite of all fuel types. Estimated 90th percentiles are presented in Appendix C, Table 8, and Table 8A.
For chemicals with at least one (1) detected concentration, the percentile estimates are presented under the heading "Concentration Limit." The percentile estimates for the chemicals with no detected concentrations are presented under the heading "Minimum Detection Limit."

The estimated percentiles were generated by weighing each sample according to the number of samples available from each fuel type, so that each fuel type provided equal contribution to the
estimated percentiles. That is, each fuel type should represent one-quarter of the population. Therefore, the samples from gasoline and Nos. 2, 4, and 6 fuel oils were assigned weights of 1/32, 1/44, 1/4, and 1/28, respectively, based on the number of samples from each fuel type. The chemical concentrations were then ranked from lowest to highest, and the weights were summed across samples until the total weight was equal to 0.50. The corresponding chemical concentration was used as the estimated 50th percentile. That is, the 50th percentile is the concentration corresponding to
the ranked sample for which 50% of the weights were accounted. If the sum of the weights does not equal 0.50 exactly, then the 50th percentile is an average of the two (2) reported concentrations that
surround the 50th percentile point. Similarly, the 90th percentiles were estimated by the corresponding concentration when the sum of the weights was equal to 0.90.

In the analytical methods for calculating the quantitation limit for VOCs in gasoline, there are
matrix interferences that cause the calculated quantitation limits to be unreliable. Therefore, for the
VOCs not detected in any of the gasoline samples, the estimated percentiles for the composite of all
fuel types, which includes gasoline, were not presented. For these chemicals, the estimates from the composite of the Nos. 2, 4, and 6 fuel oils (i.e., without gasoline) are presented in Appendix C,
Tables 5, 5A, 6, and 6A as surrogates for the percentile estimates from the composite of all four (4) fuel types.

The percentiles for the detected chemicals are presented in units of mg/kg at 10,000 Btu/lb
and the percentiles for the non-detect chemicals are presented in the original units of mg/kg. All of

# 3-10

the chemicals originally were reported in the database with units of mg/kg. The percentile estimates for chemicals with at least one (1) detected sample (i.e., concentration limit) were calculated from
concentrations converted from mg/kg to mg/J, based on the reported heating values (Btu/lb) for each sample. The percentile estimates then were converted from mg/J back to mg/kg based on 10,000
Btu/lb. For the chemicals with no samples measured above the minimum level of detection, the percentile estimates were based on the reported quantitation limits in the original units of mg/kg.

# 3-11

Table 3-1 Chlorine Content of Fuel Oils Used in Hazardous Waste Burning Boilers and Incinerators (as Reported in CoC Test Reports)

Facility Name and Location Fuel Oil No. Cl Content (ppm w 

# ) Ind. Measurements No. Of Measur. Measurement

Method Comments

Amer. Cyan., Kalamazoo, MI 6 < 45 1 ASTM D3120 Sulfur method, not used 

# Huntsman Poly., Woodbury, NJ 6 < 100 6 SW-846 9020 Organic chlorine, not used 

# Rohm and Haas, Phil., PA 6 108, 110, 171 3 ASTM D 808/D 4327 Below method DL 

# Rohm and Haas, Bristol, PA 6 180 1 ASTM D 808/D 4327 Below method DL


# Rohm and Haas 6 590, 660, 1000 3 EPA 9020 Below/near method DL


# Rohm and Haas 6 840, 840 3 EPA 9020 Dow Chem., Gales Ferry, CT 2 83, 93, 137 3 ASTM D 808 Below method DL, not used 

# Du Pont, Wilmington, DE 2 16, 429, 461, 470, 490, 523 5 ASTM D 808/D 4327

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 1,2,4,5-Tetrachlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,2,4-Trichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,2-Dichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,3,5-Trinitrobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,3-Dichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,4-Dichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,4-Naphthoquinone <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1-Naphthylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,3,4,6-Tetrachlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4,5-Trichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4,6-Trichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dimethylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dinitrophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dinitrotoluene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,6-Dichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,6-Dinitrotoluene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Acetylaminofluorene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Chloronaphthalene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Chlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Naphthylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Nitroaniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Nitrophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Picoline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 3,3'-Dichlorobenzidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 3-3'-Dimethylbenzidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 3-Methylcholanthrene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4,6-Dinitro-2-methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Aminobiphenyl <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Bromophenyl phenyl ether <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Chloro-3-methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Chloroaniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Nitroaniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Nitrophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 5-Nitro-o-toluidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 7,12-Dimethylbenz[a]anthracene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 

### α , 

### α -Dimethylphenethylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Acetophenone <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Aniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Aramite <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90



### Appendix A - SVOC - 1

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 Benzidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[a]anthracene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[a]pyrene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[b]fluoranthene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[k]fluoranthene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Bis(2-chloroisopropyl)ether <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Butyl benzyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Chlorobenzilate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Chrysene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Di-n-butyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Di-n-octyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Diallate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dibenzo[a,h]anthracene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dibenz[a,j]acridine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Diethyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dimethoate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dimethyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dinoseb <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Diphenylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Disulfoton <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Ethyl methanesulfonate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Famphur <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Fluoranthene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Fluorene <270 U 26.7 <1200 U 117 <200 220 19.8 <99 U 9.90 8835-001 Hexachlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachlorobutadiene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachlorocyclopentadiene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachloroethane <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachlorophene <6700 U 26.7 <29000 U 117 <5000 U 19.8 <2500 U 9.90 8835-001 Hexachloropropene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Indeno(1,2,3-c,d)pyrene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Isodrin <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Isosafrole <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Kepone <530 U 26.7 <2300 U 117 <400 U 19.8 <200 U 9.90 8835-001 Methapyrilene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Methyl parathion <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Methyl methanesulfonate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitroso-di-n-butylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosodi-n-propylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosodiethylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosomethylethylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosomorpholine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90



### Appendix A - SVOC - 2

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 N-Nitrosopiperidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosopyrrolidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Naphthalene <270 2500 26.7 <1200 2000 117 <200 660 19.8 <99 170 9.90 8835-001 Nitrobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 O,O,O-Triethylphosphorothioate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 o-Toluidine <270 U 26.7 <1200 U 117 <200 U 19.8 <2000 U 9.90 8835-001 p-Dimethylaminoazobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 p-Phenylenediamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Parathion <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pentachlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pentachloronitrobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pentachlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Phenacetin <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Phenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Phorate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pronamide <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pyridine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Safrole <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Sulfotepp <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Thionzin <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-002 1,2,4,5-Tetrachlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,2,4-Trichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,2-Dichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,3,5-Trinitrobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,3-Dichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,4-Dichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,4-Naphthoquinone <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1-Naphthylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,3,4,6-Tetrachlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4,5-Trichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4,6-Trichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dimethylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dinitrophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dinitrotoluene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,6-Dichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,6-Dinitrotoluene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Acetylaminofluorene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Chloronaphthalene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Chlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Naphthylamine <270 U 26.6 <1200 U 117 <200 U 19.6



### Appendix A - SVOC - 3

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-002 2-Nitroaniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Nitrophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Picoline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 3,3'-Dichlorobenzidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 3-3'-Dimethylbenzidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 3-Methylcholanthrene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4,6-Dinitro-2-methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Aminobiphenyl <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Bromophenyl phenyl ether <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Chloro-3-methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Chloroaniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Nitroaniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Nitrophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 5-Nitro-o-toluidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 7,12-Dimethylbenz[a]anthracene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 

### α , 

### α -Dimethylphenethylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Acetophenone <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Aniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Aramite <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Benzidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Benzo[a]anthracene <270 U 26.6 <1200 U 117 <200 760 19.6 8835-002 Benzo[a]pyrene <270 U 26.6 <1200 U 117 <200 450 19.6 8835-002 Benzo[b]fluoranthene <270 U 26.6 <1200 U 117 <200 210 19.6 8835-002 Benzo[k]fluoranthene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Bis(2-chloroisopropyl)ether <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Butyl benzyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Chlorobenzilate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Chrysene <270 U 26.6 <1200 U 117 <200 700 19.6 8835-002 Di-n-butyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Di-n-octyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Diallate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dibenzo[a,h]anthracene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dibenz[a,j]acridine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Diethyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dimethoate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dimethyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dinoseb <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Diphenylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Disulfoton <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Ethyl methanesulfonate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Famphur <270 U 26.6 <1200 U 117 <200 U 19.6



### Appendix A - SVOC - 4

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-002 Fluoranthene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Fluorene <270 U 26.6 <1200 U 117 <200 220 19.6 8835-002 Hexachlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachlorobutadiene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachlorocyclopentadiene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachloroethane <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachlorophene <6600 U 26.6 <29000 U 117 <4900 U 19.6 8835-002 Hexachloropropene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Indeno(1,2,3-c,d)pyrene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Isodrin <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Isosafrole <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Kepone <530 U 26.6 <2300 U 117 <390 U 19.6 8835-002 Methapyrilene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Methyl parathion <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Methyl methanesulfonate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitroso-di-n-butylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosodi-n-propylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosodiethylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosomethylethylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosomorpholine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosopiperidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosopyrrolidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Naphthalene <270 2600 26.6 <1200 2300 117 <200 550 19.6 8835-002 Nitrobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 O,O,O-Triethylphosphorothioate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 o-Toluidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 p-Dimethylaminoazobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 p-Phenylenediamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Parathion <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pentachlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pentachloronitrobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pentachlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Phenacetin <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Phenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Phorate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pronamide <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pyridine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Safrole <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Sulfotepp <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Thionzin <270 U 26.6 <1200 U 117 <200 U 19.6 8835-003 1,2,4,5-Tetrachlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,2,4-Trichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2



### Appendix A - SVOC - 5

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-003 1,2-Dichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,3,5-Trinitrobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,3-Dichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,4-Dichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,4-Naphthoquinone <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1-Naphthylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,3,4,6-Tetrachlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4,5-Trichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4,6-Trichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dimethylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dinitrophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dinitrotoluene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,6-Dichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,6-Dinitrotoluene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Acetylaminofluorene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Chloronaphthalene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Chlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Naphthylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Nitroaniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Nitrophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Picoline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 3,3'-Dichlorobenzidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 3-3'-Dimethylbenzidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 3-Methylcholanthrene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4,6-Dinitro-2-methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Aminobiphenyl <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Bromophenyl phenyl ether <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Chloro-3-methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Chloroaniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Nitroaniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Nitrophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 5-Nitro-o-toluidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 7,12-Dimethylbenz[a]anthracene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 

### α , 

### α -Dimethylphenethylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Acetophenone <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Aniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Aramite <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Benzidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Benzo[a]anthracene <670 U 66.8 <590 U 59.4 <190 660 19.2



### Appendix A - SVOC - 6

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-003 Benzo[a]pyrene <670 U 66.8 <590 U 59.4 <190 450 19.2 8835-003 Benzo[b]fluoranthene <670 U 66.8 <590 U 59.4 <190 220 19.2 8835-003 Benzo[k]fluoranthene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Bis(2-chloroisopropyl)ether <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Butyl benzyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Chlorobenzilate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Chrysene <670 U 66.8 <590 U 59.4 <190 740 19.2 8835-003 Di-n-butyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Di-n-octyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Diallate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dibenzo[a,h]anthracene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dibenz[a,j]acridine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Diethyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dimethoate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dimethyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dinoseb <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Diphenylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Disulfoton <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Ethyl methanesulfonate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Famphur <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Fluoranthene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Fluorene <670 U 66.8 <590 U 59.4 <190 210 19.2 8835-003 Hexachlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachlorobutadiene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachlorocyclopentadiene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachloroethane <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachlorophene <17000 U 66.8 <15000 U 59.4 <4800 U 19.2 8835-003 Hexachloropropene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Indeno(1,2,3-c,d)pyrene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Isodrin <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Isosafrole <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Kepone <1300 U 66.8 <1200 U 59.4 <380 U 19.2 8835-003 Methapyrilene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Methyl parathion <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Methyl methanesulfonate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitroso-di-n-butylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosodi-n-propylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosodiethylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosomethylethylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosomorpholine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosopiperidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosopyrrolidine <670 U 66.8 <590 U 59.4 <190 U 19.2



### Appendix A - SVOC - 7

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-003 Naphthalene <670 5400 66.8 <590 1300 59.4 <190 550 19.2 8835-003 Nitrobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 O,O,O-Triethylphosphorothioate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 o-Toluidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 p-Dimethylaminoazobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 p-Phenylenediamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Parathion <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pentachlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pentachloronitrobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pentachlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Phenacetin <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Phenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Phorate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pronamide <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pyridine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Safrole <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Sulfotepp <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Thionzin <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-004 1,2,4,5-Tetrachlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,2,4-Trichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,2-Dichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,3,5-Trinitrobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,3-Dichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,4-Dichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,4-Naphthoquinone <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1-Naphthylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,3,4,6-Tetrachlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4,5-Trichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4,6-Trichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dimethylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dinitrophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dinitrotoluene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,6-Dichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,6-Dinitrotoluene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Acetylaminofluorene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Chloronaphthalene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Chlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Naphthylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Nitroaniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Nitrophenol <670 U 66.7 <600 U 59.6 <500 U 50.0



### Appendix A - SVOC - 8

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-004 2-Picoline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 3,3'-Dichlorobenzidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 3-3'-Dimethylbenzidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 3-Methylcholanthrene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4,6-Dinitro-2-methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Aminobiphenyl <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Bromophenyl phenyl ether <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Chloro-3-methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Chloroaniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Nitroaniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Nitrophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 5-Nitro-o-toluidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 7,12-Dimethylbenz[a]anthracene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 

### α , 

### α -Dimethylphenethylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Acetophenone <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Aniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Aramite <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Benzidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Benzo[a]anthracene <670 U 66.7 <600 U 59.6 <500 1900 50.0 8835-004 Benzo[a]pyrene <670 U 66.7 <600 U 59.6 <500 770 50.0 8835-004 Benzo[b]fluoranthene <670 U 66.7 <600 U 59.6 <500 540 50.0 8835-004 Benzo[k]fluoranthene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Bis(2-chloroisopropyl)ether <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Butyl benzyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Chlorobenzilate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Chrysene <670 U 66.7 <600 U 59.6 <500 2700 50.0 8835-004 Di-n-butyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Di-n-octyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Diallate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dibenzo[a,h]anthracene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dibenz[a,j]acridine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Diethyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dimethoate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dimethyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dinoseb <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Diphenylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Disulfoton <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Ethyl methanesulfonate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Famphur <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Fluoranthene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Fluorene <670 U 66.7 <600 U 59.6 <500 U 50.0



### Appendix A - SVOC - 9

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-004 Hexachlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachlorobutadiene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachlorocyclopentadiene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachloroethane <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachlorophene <17000 U 66.7 <15000 U 59.6 <12000 U 50.0 8835-004 Hexachloropropene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Indeno(1,2,3-c,d)pyrene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Isodrin <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Isosafrole <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Kepone <1300 U 66.7 <1200 U 59.6 <1000 U 50.0 8835-004 Methapyrilene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Methyl parathion <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Methyl methanesulfonate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitroso-di-n-butylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosodi-n-propylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosodiethylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosomethylethylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosomorpholine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosopiperidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosopyrrolidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Naphthalene <670 6200 66.7 <600 1700 59.6 <500 U 50.0 8835-004 Nitrobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 O,O,O-Triethylphosphorothioate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 o-Toluidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 p-Dimethylaminoazobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 p-Phenylenediamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Parathion <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pentachlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pentachloronitrobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pentachlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Phenacetin <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Phenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Phorate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pronamide <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pyridine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Safrole <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Sulfotepp <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Thionzin <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-005 1,2,4,5-Tetrachlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,2,4-Trichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,2-Dichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,3,5-Trinitrobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8



### Appendix A - SVOC - 10

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-005 1,3-Dichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,4-Dichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,4-Naphthoquinone <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1-Naphthylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,3,4,6-Tetrachlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4,5-Trichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4,6-Trichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dimethylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dinitrophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dinitrotoluene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,6-Dichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,6-Dinitrotoluene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Acetylaminofluorene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Chloronaphthalene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Chlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Naphthylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Nitroaniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Nitrophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Picoline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 3,3'-Dichlorobenzidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 3-3'-Dimethylbenzidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 3-Methylcholanthrene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4,6-Dinitro-2-methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Aminobiphenyl <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Bromophenyl phenyl ether <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Chloro-3-methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Chloroaniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Nitroaniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Nitrophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 5-Nitro-o-toluidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 7,12-Dimethylbenz[a]anthracene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 

### α , 

### α -Dimethylphenethylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Acetophenone <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Aniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Aramite <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Benzidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Benzo[a]anthracene <130 U 13.4 <590 U 59.5 <200 1600 19.8 8835-005 Benzo[a]pyrene <130 U 13.4 <590 U 59.5 <200 960 19.8 8835-005 Benzo[b]fluoranthene <130 U 13.4 <590 U 59.5 <200 670 19.8



### Appendix A - SVOC - 11

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-005 Benzo[k]fluoranthene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Bis(2-chloroisopropyl)ether <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Butyl benzyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Chlorobenzilate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Chrysene <130 U 13.4 <590 U 59.5 <200 2200 19.8 8835-005 Di-n-butyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Di-n-octyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Diallate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dibenzo[a,h]anthracene <130 U 13.4 <590 U 59.5 <200 250 19.8 8835-005 Dibenz[a,j]acridine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Diethyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dimethoate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dimethyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dinoseb <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Diphenylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Disulfoton <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Ethyl methanesulfonate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Famphur <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Fluoranthene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Fluorene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorobutadiene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorocyclopentadiene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachloroethane <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorophene <3400 U 13.4 <15000 U 59.5 <5000 U 19.8 8835-005 Hexachloropropene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Indeno(1,2,3-c,d)pyrene <130 U 13.4 <590 U 59.5 <200 290 19.8 8835-005 Isodrin <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Isosafrole <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Kepone <270 U 13.4 <1200 U 59.5 <400 U 19.8 8835-005 Methapyrilene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Methyl parathion <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Methyl methanesulfonate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitroso-di-n-butylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosodi-n-propylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosodiethylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosomethylethylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosomorpholine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosopiperidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosopyrrolidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Naphthalene <130 1300 13.4 <590 1700 59.5 <200 260 19.8 8835-005 Nitrobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8



### Appendix A - SVOC - 12

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-005 O,O,O-Triethylphosphorothioate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 o-Toluidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 p-Dimethylaminoazobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 p-Phenylenediamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Parathion <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pentachlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pentachloronitrobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pentachlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Phenacetin <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Phenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Phorate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pronamide <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pyridine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Safrole <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Sulfotepp <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Thionzin <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-006 1,2,4,5-Tetrachlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,2,4-Trichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,2-Dichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,3,5-Trinitrobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,3-Dichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,4-Dichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,4-Naphthoquinone <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1-Naphthylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,3,4,6-Tetrachlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4,5-Trichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4,6-Trichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dimethylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dinitrophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dinitrotoluene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,6-Dichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,6-Dinitrotoluene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Acetylaminofluorene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Chloronaphthalene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Chlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Naphthylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Nitroaniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Nitrophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Picoline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 3,3'-Dichlorobenzidine <140 U 14.1 <290 U 29.3 <980 U 98.0



### Appendix A - SVOC - 13

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-006 3-3'-Dimethylbenzidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 3-Methylcholanthrene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4,6-Dinitro-2-methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Aminobiphenyl <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Bromophenyl phenyl ether <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Chloro-3-methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Chloroaniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Nitroaniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Nitrophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 5-Nitro-o-toluidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 7,12-Dimethylbenz[a]anthracene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 

### α , 

### α -Dimethylphenethylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Acetophenone <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Aniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Aramite <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[a]anthracene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[a]pyrene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[b]fluoranthene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[k]fluoranthene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Bis(2-chloroisopropyl)ether <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Butyl benzyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Chlorobenzilate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Chrysene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Di-n-butyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Di-n-octyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Diallate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dibenzo[a,h]anthracene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dibenz[a,j]acridine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Diethyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dimethoate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dimethyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dinoseb <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Diphenylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Disulfoton <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Ethyl methanesulfonate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Famphur <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Fluoranthene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Fluorene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachlorobutadiene <140 U 14.1 <290 U 29.3 <980 U 98.0



### Appendix A - SVOC - 14

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-006 Hexachlorocyclopentadiene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachloroethane <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachlorophene <3500 U 14.1 <7300 U 29.3 <980 U 98.0 8835-006 Hexachloropropene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Indeno(1,2,3-c,d)pyrene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Isodrin <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Isosafrole <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Kepone <280 U 14.1 <580 U 29.3 <2000 U 98.0 8835-006 Methapyrilene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Methyl parathion <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Methyl methanesulfonate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitroso-di-n-butylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosodi-n-propylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosodiethylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosomethylethylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosomorpholine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosopiperidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosopyrrolidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Naphthalene <140 1100 14.1 <290 U 29.3 <980 1900 98.0 8835-006 Nitrobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 O,O,O-Triethylphosphorothioate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 o-Toluidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 p-Dimethylaminoazobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 p-Phenylenediamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Parathion <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pentachlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pentachloronitrobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pentachlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Phenacetin <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Phenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Phorate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pronamide <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pyridine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Safrole <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Sulfotepp <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Thionzin <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-007 1,2,4,5-Tetrachlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,2,4-Trichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,2-Dichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,3,5-Trinitrobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,3-Dichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,4-Dichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6



### Appendix A - SVOC - 15

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 1,4-Naphthoquinone <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1-Naphthylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,3,4,6-Tetrachlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4,5-Trichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4,6-Trichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dimethylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dinitrophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dinitrotoluene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,6-Dichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,6-Dinitrotoluene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Acetylaminofluorene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Chloronaphthalene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Chlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Naphthylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Nitroaniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Nitrophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Picoline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 3,3'-Dichlorobenzidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 3-3'-Dimethylbenzidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 3-Methylcholanthrene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4,6-Dinitro-2-methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Aminobiphenyl <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Bromophenyl phenyl ether <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Chloro-3-methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Chloroaniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Nitroaniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Nitrophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 5-Nitro-o-toluidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 7,12-Dimethylbenz[a]anthracene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 

### α , 

### α -Dimethylphenethylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Acetophenone <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Aniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Aramite <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[a]anthracene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[a]pyrene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[b]fluoranthene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[k]fluoranthene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Bis(2-chloroisopropyl)ether <270 U 27.4 <2400 U 235 <200 U 19.6



### Appendix A - SVOC - 16

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 Butyl benzyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Chlorobenzilate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Chrysene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Di-n-butyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Di-n-octyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Diallate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dibenzo[a,h]anthracene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dibenz[a,j]acridine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Diethyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dimethoate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dimethyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dinoseb <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Diphenylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Disulfoton <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Ethyl methanesulfonate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Famphur <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Fluoranthene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Fluorene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorobutadiene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorocyclopentadiene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachloroethane <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorophene <6800 U 27.4 <59000.0000000001 U 235 <4900 U 19.6 8835-007 Hexachloropropene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Indeno(1,2,3-c,d)pyrene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Isodrin <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Isosafrole <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Kepone <550 U 27.4 <4700 U 235 <390 U 19.6 8835-007 Methapyrilene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Methyl parathion <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Methyl methanesulfonate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitroso-di-n-butylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosodi-n-propylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosodiethylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosomethylethylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosomorpholine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosopiperidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosopyrrolidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Naphthalene <270 2300 27.4 <2400 3500 235 <200 690 19.6 8835-007 Nitrobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 O,O,O-Triethylphosphorothioate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 o-Toluidine <270 U 27.4 <2400 U 235 <200 U 19.6



### Appendix A - SVOC - 17

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 p-Dimethylaminoazobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 p-Phenylenediamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Parathion <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pentachlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pentachloronitrobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pentachlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Phenacetin <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Phenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Phorate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pronamide <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pyridine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Safrole <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Sulfotepp <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Thionzin <270 U 27.4 <2400 U 235 <200 U 19.6 8835-008 1,2,4,5-Tetrachlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,2,4-Trichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,2-Dichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,3,5-Trinitrobenzene <280 U 27.7 <600 U 59.7 8835-008 1,3-Dichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,4-Dichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,4-Naphthoquinone <280 U 27.7 <600 U 59.7 8835-008 1-Naphthylamine <280 U 27.7 <600 U 59.7 8835-008 2,3,4,6-Tetrachlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4,5-Trichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4,6-Trichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dimethylphenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dinitrophenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dinitrotoluene <280 U 27.7 <600 U 59.7 8835-008 2,6-Dichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,6-Dinitrotoluene <280 U 27.7 <600 U 59.7 8835-008 2-Acetylaminofluorene <280 U 27.7 <600 U 59.7 8835-008 2-Chloronaphthalene <280 U 27.7 <600 U 59.7 8835-008 2-Chlorophenol <280 U 27.7 <600 U 59.7 8835-008 2-Methylphenol <280 U 27.7 <600 U 59.7 8835-008 2-Naphthylamine <280 U 27.7 <600 U 59.7 8835-008 2-Nitroaniline <280 U 27.7 <600 U 59.7 8835-008 2-Nitrophenol <280 U 27.7 <600 U 59.7 8835-008 2-Picoline <280 U 27.7 <600 U 59.7 8835-008 3,3'-Dichlorobenzidine <280 U 27.7 <600 U 59.7 8835-008 3-3'-Dimethylbenzidine <280 U 27.7 <600 U 59.7 8835-008 3-Methylcholanthrene <280 U 27.7 <600 U 59.7



### Appendix A - SVOC - 18

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-008 4,6-Dinitro-2-methylphenol <280 U 27.7 <600 U 59.7 8835-008 4-Aminobiphenyl <280 U 27.7 <600 U 59.7 8835-008 4-Bromophenyl phenyl ether <280 U 27.7 <600 U 59.7 8835-008 4-Chloro-3-methylphenol <280 U 27.7 <600 U 59.7 8835-008 4-Chloroaniline <280 U 27.7 <600 U 59.7 8835-008 4-Methylphenol <280 U 27.7 <600 U 59.7 8835-008 4-Nitroaniline <280 U 27.7 <600 U 59.7 8835-008 4-Nitrophenol <280 U 27.7 <600 U 59.7 8835-008 5-Nitro-o-toluidine <280 U 27.7 <600 U 59.7 8835-008 7,12-Dimethylbenz[a]anthracene <280 U 27.7 <600 U 59.7 8835-008 

### α , 

### α -Dimethylphenethylamine <280 U 27.7 <600 U 59.7 8835-008 Acetophenone <280 U 27.7 <600 U 59.7 8835-008 Aniline <280 U 27.7 <600 U 59.7 8835-008 Aramite <280 U 27.7 <600 U 59.7 8835-008 Benzidine <280 U 27.7 <600 U 59.7 8835-008 Benzo[a]anthracene <280 U 27.7 <600 U 59.7 8835-008 Benzo[a]pyrene <280 U 27.7 <600 U 59.7 8835-008 Benzo[b]fluoranthene <280 U 27.7 <600 U 59.7 8835-008 Benzo[k]fluoranthene <280 U 27.7 <600 U 59.7 8835-008 Bis(2-chloroisopropyl)ether <280 U 27.7 <600 U 59.7 8835-008 Butyl benzyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Chlorobenzilate <280 U 27.7 <600 U 59.7 8835-008 Chrysene <280 U 27.7 <600 U 59.7 8835-008 Di-n-butyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Di-n-octyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Diallate <280 U 27.7 <600 U 59.7 8835-008 Dibenzo[a,h]anthracene <280 U 27.7 <600 U 59.7 8835-008 Dibenz[a,j]acridine <280 U 27.7 <600 U 59.7 8835-008 Diethyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Dimethoate <280 U 27.7 <600 U 59.7 8835-008 Dimethyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Dinoseb <280 U 27.7 <600 U 59.7 8835-008 Diphenylamine <280 U 27.7 <600 U 59.7 8835-008 Disulfoton <280 U 27.7 <600 U 59.7 8835-008 Ethyl methanesulfonate <280 U 27.7 <600 U 59.7 8835-008 Famphur <280 U 27.7 <600 U 59.7 8835-008 Fluoranthene <280 U 27.7 <600 U 59.7 8835-008 Fluorene <280 U 27.7 <600 U 59.7 8835-008 Hexachlorobenzene <280 U 27.7 <600 U 59.7 8835-008 Hexachlorobutadiene <280 U 27.7 <600 U 59.7 8835-008 Hexachlorocyclopentadiene <280 U 27.7 <600 U 59.7 8835-008 Hexachloroethane <280 U 27.7 <600 U 59.7



### Appendix A - SVOC - 19

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-008 Hexachlorophene <6900 U 27.7 <15000 U 59.7 8835-008 Hexachloropropene <280 U 27.7 <600 U 59.7 8835-008 Indeno(1,2,3-c,d)pyrene <280 U 27.7 <600 U 59.7 8835-008 Isodrin <280 U 27.7 <600 U 59.7 8835-008 Isosafrole <280 U 27.7 <600 U 59.7 8835-008 Kepone <550 U 27.7 <1200 U 59.7 8835-008 Methapyrilene <280 U 27.7 <600 U 59.7 8835-008 Methyl parathion <280 U 27.7 <600 U 59.7 8835-008 Methyl methanesulfonate <280 U 27.7 <600 U 59.7 8835-008 N-Nitroso-di-n-butylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosodi-n-propylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosodiethylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosomethylethylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosomorpholine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosopiperidine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosopyrrolidine <280 U 27.7 <600 U 59.7 8835-008 Naphthalene <280 2100 27.7 <600 1800 59.7 8835-008 Nitrobenzene <280 U 27.7 <600 U 59.7 8835-008 O,O,O-Triethylphosphorothioate <280 U 27.7 <600 U 59.7 8835-008 o-Toluidine <280 U 27.7 <600 U 59.7 8835-008 p-Dimethylaminoazobenzene <280 U 27.7 <600 U 59.7 8835-008 p-Phenylenediamine <280 U 27.7 <600 U 59.7 8835-008 Parathion <280 U 27.7 <600 U 59.7 8835-008 Pentachlorobenzene <280 U 27.7 <600 U 59.7 8835-008 Pentachloronitrobenzene <280 U 27.7 <600 U 59.7 8835-008 Pentachlorophenol <280 U 27.7 <600 U 59.7 8835-008 Phenacetin <280 U 27.7 <600 U 59.7 8835-008 Phenol <280 U 27.7 <600 U 59.7 8835-008 Phorate <280 U 27.7 <600 U 59.7 8835-008 Pronamide <280 U 27.7 <600 U 59.7 8835-008 Pyridine <280 U 27.7 <600 U 59.7 8835-008 Safrole <280 U 27.7 <600 U 59.7 8835-008 Sulfotepp <280 U 27.7 <600 U 59.7 8835-008 Thionzin <280 U 27.7 <600 U 59.7 8835-009 1,2,4,5-Tetrachlorobenzene <600 U 60.1 8835-009 1,2,4-Trichlorobenzene <600 U 60.1 8835-009 1,2-Dichlorobenzene <600 U 60.1 8835-009 1,3,5-Trinitrobenzene <600 U 60.1 8835-009 1,3-Dichlorobenzene <600 U 60.1 8835-009 1,4-Dichlorobenzene <600 U 60.1 8835-009 1,4-Naphthoquinone <600 U 60.1 8835-009 1-Naphthylamine <600 U 60.1



### Appendix A - SVOC - 20

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-009 2,3,4,6-Tetrachlorophenol <600 U 60.1 8835-009 2,4,5-Trichlorophenol <600 U 60.1 8835-009 2,4,6-Trichlorophenol <600 U 60.1 8835-009 2,4-Dichlorophenol <600 U 60.1 8835-009 2,4-Dimethylphenol <600 U 60.1 8835-009 2,4-Dinitrophenol <600 U 60.1 8835-009 2,4-Dinitrotoluene <600 U 60.1 8835-009 2,6-Dichlorophenol <600 U 60.1 8835-009 2,6-Dinitrotoluene <600 U 60.1 8835-009 2-Acetylaminofluorene <600 U 60.1 8835-009 2-Chloronaphthalene <600 U 60.1 8835-009 2-Chlorophenol <600 U 60.1 8835-009 2-Methylphenol <600 U 60.1 8835-009 2-Naphthylamine <600 U 60.1 8835-009 2-Nitroaniline <600 U 60.1 8835-009 2-Nitrophenol <600 U 60.1 8835-009 2-Picoline <600 U 60.1 8835-009 3,3'-Dichlorobenzidine <600 U 60.1 8835-009 3-3'-Dimethylbenzidine <600 U 60.1 8835-009 3-Methylcholanthrene <600 U 60.1 8835-009 4,6-Dinitro-2-methylphenol <600 U 60.1 8835-009 4-Aminobiphenyl <600 U 60.1 8835-009 4-Bromophenyl phenyl ether <600 U 60.1 8835-009 4-Chloro-3-methylphenol <600 U 60.1 8835-009 4-Chloroaniline <600 U 60.1 8835-009 4-Methylphenol <600 U 60.1 8835-009 4-Nitroaniline <600 U 60.1 8835-009 4-Nitrophenol <600 U 60.1 8835-009 5-Nitro-o-toluidine <600 U 60.1 8835-009 7,12-Dimethylbenz[a]anthracene <600 U 60.1 8835-009 

### α , 

### α -Dimethylphenethylamine <600 U 60.1 8835-009 Acetophenone <600 U 60.1 8835-009 Aniline <600 U 60.1 8835-009 Aramite <600 U 60.1 8835-009 Benzidine <600 U 60.1 8835-009 Benzo[a]anthracene <600 U 60.1 8835-009 Benzo[a]pyrene <600 U 60.1 8835-009 Benzo[b]fluoranthene <600 U 60.1 8835-009 Benzo[k]fluoranthene <600 U 60.1 8835-009 Bis(2-chloroisopropyl)ether <600 U 60.1 8835-009 Butyl benzyl phthalate <600 U 60.1 8835-009 Chlorobenzilate <600 U 60.1



### Appendix A - SVOC - 21

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-009 Chrysene <600 U 60.1 8835-009 Di-n-butyl phthalate <600 U 60.1 8835-009 Di-n-octyl phthalate <600 U 60.1 8835-009 Diallate <600 U 60.1 8835-009 Dibenzo[a,h]anthracene <600 U 60.1 8835-009 Dibenz[a,j]acridine <600 U 60.1 8835-009 Diethyl phthalate <600 U 60.1 8835-009 Dimethoate <600 U 60.1 8835-009 Dimethyl phthalate <600 U 60.1 8835-009 Dinoseb <600 U 60.1 8835-009 Diphenylamine <600 U 60.1 8835-009 Disulfoton <600 U 60.1 8835-009 Ethyl methanesulfonate <600 U 60.1 8835-009 Famphur <600 U 60.1 8835-009 Fluoranthene <600 U 60.1 8835-009 Fluorene <600 U 60.1 8835-009 Hexachlorobenzene <600 U 60.1 8835-009 Hexachlorobutadiene <600 U 60.1 8835-009 Hexachlorocyclopentadiene <600 U 60.1 8835-009 Hexachloroethane <600 U 60.1 8835-009 Hexachlorophene <15000 U 60.1 8835-009 Hexachloropropene <600 U 60.1 8835-009 Indeno(1,2,3-c,d)pyrene <600 U 60.1 8835-009 Isodrin <600 U 60.1 8835-009 Isosafrole <600 U 60.1 8835-009 Kepone <1200 U 60.1 8835-009 Methapyrilene <600 U 60.1 8835-009 Methyl parathion <600 U 60.1 8835-009 Methyl methanesulfonate <600 U 60.1 8835-009 N-Nitroso-di-n-butylamine <600 U 60.1 8835-009 N-Nitrosodi-n-propylamine <600 U 60.1 8835-009 N-Nitrosodiethylamine <600 U 60.1 8835-009 N-Nitrosomethylethylamine <600 U 60.1 8835-009 N-Nitrosomorpholine <600 U 60.1 8835-009 N-Nitrosopiperidine <600 U 60.1 8835-009 N-Nitrosopyrrolidine <600 U 60.1 8835-009 Naphthalene <600 650 60.1 8835-009 Nitrobenzene <600 U 60.1 8835-009 O,O,O-Triethylphosphorothioate <600 U 60.1 8835-009 o-Toluidine <600 U 60.1 8835-009 p-Dimethylaminoazobenzene <600 U 60.1 8835-009 p-Phenylenediamine <600 U 60.1



### Appendix A - SVOC - 22

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-009 Parathion <600 U 60.1 8835-009 Pentachlorobenzene <600 U 60.1 8835-009 Pentachloronitrobenzene <600 U 60.1 8835-009 Pentachlorophenol <600 U 60.1 8835-009 Phenacetin <600 U 60.1 8835-009 Phenol <600 U 60.1 8835-009 Phorate <600 U 60.1 8835-009 Pronamide <600 U 60.1 8835-009 Pyridine <600 U 60.1 8835-009 Safrole <600 U 60.1 8835-009 Sulfotepp <600 U 60.1 8835-009 Thionzin <600 U 60.1 8835-010 1,2,4,5-Tetrachlorobenzene <600 U 59.8 8835-010 1,2,4-Trichlorobenzene <600 U 59.8 8835-010 1,2-Dichlorobenzene <600 U 59.8 8835-010 1,3,5-Trinitrobenzene <600 U 59.8 8835-010 1,3-Dichlorobenzene <600 U 59.8 8835-010 1,4-Dichlorobenzene <600 U 59.8 8835-010 1,4-Naphthoquinone <600 U 59.8 8835-010 1-Naphthylamine <600 U 59.8 8835-010 2,3,4,6-Tetrachlorophenol <600 U 59.8 8835-010 2,4,5-Trichlorophenol <600 U 59.8 8835-010 2,4,6-Trichlorophenol <600 U 59.8 8835-010 2,4-Dichlorophenol <600 U 59.8 8835-010 2,4-Dimethylphenol <600 U 59.8 8835-010 2,4-Dinitrophenol <600 U 59.8 8835-010 2,4-Dinitrotoluene <600 U 59.8 8835-010 2,6-Dichlorophenol <600 U 59.8 8835-010 2,6-Dinitrotoluene <600 U 59.8 8835-010 2-Acetylaminofluorene <600 U 59.8 8835-010 2-Chloronaphthalene <600 U 59.8 8835-010 2-Chlorophenol <600 U 59.8 8835-010 2-Methylphenol <600 U 59.8 8835-010 2-Naphthylamine <600 U 59.8 8835-010 2-Nitroaniline <600 U 59.8 8835-010 2-Nitrophenol <600 U 59.8 8835-010 2-Picoline <600 U 59.8 8835-010 3,3'-Dichlorobenzidine <600 U 59.8 8835-010 3-3'-Dimethylbenzidine <600 U 59.8 8835-010 3-Methylcholanthrene <600 U 59.8 8835-010 4,6-Dinitro-2-methylphenol <600 U 59.8 8835-010 4-Aminobiphenyl <600 U 59.8



### Appendix A - SVOC - 23

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-010 4-Bromophenyl phenyl ether <600 U 59.8 8835-010 4-Chloro-3-methylphenol <600 U 59.8 8835-010 4-Chloroaniline <600 U 59.8 8835-010 4-Methylphenol <600 U 59.8 8835-010 4-Nitroaniline <600 U 59.8 8835-010 4-Nitrophenol <600 U 59.8 8835-010 5-Nitro-o-toluidine <600 U 59.8 8835-010 7,12-Dimethylbenz[a]anthracene <600 U 59.8 8835-010 

### α , 

### α -Dimethylphenethylamine <600 U 59.8 8835-010 Acetophenone <600 U 59.8 8835-010 Aniline <600 U 59.8 8835-010 Aramite <600 U 59.8 8835-010 Benzidine <600 U 59.8 8835-010 Benzo[a]anthracene <600 U 59.8 8835-010 Benzo[a]pyrene <600 U 59.8 8835-010 Benzo[b]fluoranthene <600 U 59.8 8835-010 Benzo[k]fluoranthene <600 U 59.8 8835-010 Bis(2-chloroisopropyl)ether <600 U 59.8 8835-010 Butyl benzyl phthalate <600 U 59.8 8835-010 Chlorobenzilate <600 U 59.8 8835-010 Chrysene <600 U 59.8 8835-010 Di-n-butyl phthalate <600 U 59.8 8835-010 Di-n-octyl phthalate <600 U 59.8 8835-010 Diallate <600 U 59.8 8835-010 Dibenzo[a,h]anthracene <600 U 59.8 8835-010 Dibenz[a,j]acridine <600 U 59.8 8835-010 Diethyl phthalate <600 U 59.8 8835-010 Dimethoate <600 U 59.8 8835-010 Dimethyl phthalate <600 U 59.8 8835-010 Dinoseb <600 U 59.8 8835-010 Diphenylamine <600 U 59.8 8835-010 Disulfoton <600 U 59.8 8835-010 Ethyl methanesulfonate <600 U 59.8 8835-010 Famphur <600 U 59.8 8835-010 Fluoranthene <600 U 59.8 8835-010 Fluorene <600 U 59.8 8835-010 Hexachlorobenzene <600 U 59.8 8835-010 Hexachlorobutadiene <600 U 59.8 8835-010 Hexachlorocyclopentadiene <600 U 59.8 8835-010 Hexachloroethane <600 U 59.8 8835-010 Hexachlorophene <15000 U 59.8 8835-010 Hexachloropropene <600 U 59.8



### Appendix A - SVOC - 24

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-010 Indeno(1,2,3-c,d)pyrene <600 U 59.8 8835-010 Isodrin <600 U 59.8 8835-010 Isosafrole <600 U 59.8 8835-010 Kepone <1200 U 59.8 8835-010 Methapyrilene <600 U 59.8 8835-010 Methyl parathion <600 U 59.8 8835-010 Methyl methanesulfonate <600 U 59.8 8835-010 N-Nitroso-di-n-butylamine <600 U 59.8 8835-010 N-Nitrosodi-n-propylamine <600 U 59.8 8835-010 N-Nitrosodiethylamine <600 U 59.8 8835-010 N-Nitrosomethylethylamine <600 U 59.8 8835-010 N-Nitrosomorpholine <600 U 59.8 8835-010 N-Nitrosopiperidine <600 U 59.8 8835-010 N-Nitrosopyrrolidine <600 U 59.8 8835-010 Naphthalene <600 710 59.8 8835-010 Nitrobenzene <600 U 59.8 8835-010 O,O,O-Triethylphosphorothioate <600 U 59.8 8835-010 o-Toluidine <600 U 59.8 8835-010 p-Dimethylaminoazobenzene <600 U 59.8 8835-010 p-Phenylenediamine <600 U 59.8 8835-010 Parathion <600 U 59.8 8835-010 Pentachlorobenzene <600 U 59.8 8835-010 Pentachloronitrobenzene <600 U 59.8 8835-010 Pentachlorophenol <600 U 59.8 8835-010 Phenacetin <600 U 59.8 8835-010 Phenol <600 U 59.8 8835-010 Phorate <600 U 59.8 8835-010 Pronamide <600 U 59.8 8835-010 Pyridine <600 U 59.8 8835-010 Safrole <600 U 59.8 8835-010 Sulfotepp <600 U 59.8 8835-010 Thionzin <600 U 59.8 8835-011 1,2,4,5-Tetrachlorobenzene <580 U 58.3 8835-011 1,2,4-Trichlorobenzene <580 U 58.3 8835-011 1,2-Dichlorobenzene <580 U 58.3 8835-011 1,3,5-Trinitrobenzene <580 U 58.3 8835-011 1,3-Dichlorobenzene <580 U 58.3 8835-011 1,4-Dichlorobenzene <580 U 58.3 8835-011 1,4-Naphthoquinone <580 U 58.3 8835-011 1-Naphthylamine <580 U 58.3 8835-011 2,3,4,6-Tetrachlorophenol <580 U 58.3 8835-011 2,4,5-Trichlorophenol <580 U 58.3



### Appendix A - SVOC - 25

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-011 2,4,6-Trichlorophenol <580 U 58.3 8835-011 2,4-Dichlorophenol <580 U 58.3 8835-011 2,4-Dimethylphenol <580 U 58.3 8835-011 2,4-Dinitrophenol <580 U 58.3 8835-011 2,4-Dinitrotoluene <580 U 58.3 8835-011 2,6-Dichlorophenol <580 U 58.3 8835-011 2,6-Dinitrotoluene <580 U 58.3 8835-011 2-Acetylaminofluorene <580 U 58.3 8835-011 2-Chloronaphthalene <580 U 58.3 8835-011 2-Chlorophenol <580 U 58.3 8835-011 2-Methylphenol <580 U 58.3 8835-011 2-Naphthylamine <580 U 58.3 8835-011 2-Nitroaniline <580 U 58.3 8835-011 2-Nitrophenol <580 U 58.3 8835-011 2-Picoline <580 U 58.3 8835-011 3,3'-Dichlorobenzidine <580 U 58.3 8835-011 3-3'-Dimethylbenzidine <580 U 58.3 8835-011 3-Methylcholanthrene <580 U 58.3 8835-011 4,6-Dinitro-2-methylphenol <580 U 58.3 8835-011 4-Aminobiphenyl <580 U 58.3 8835-011 4-Bromophenyl phenyl ether <580 U 58.3 8835-011 4-Chloro-3-methylphenol <580 U 58.3 8835-011 4-Chloroaniline <580 U 58.3 8835-011 4-Methylphenol <580 U 58.3 8835-011 4-Nitroaniline <580 U 58.3 8835-011 4-Nitrophenol <580 U 58.3 8835-011 5-Nitro-o-toluidine <580 U 58.3 8835-011 7,12-Dimethylbenz[a]anthracene <580 U 58.3 8835-011 

### α , 

### α -Dimethylphenethylamine <580 U 58.3 8835-011 Acetophenone <580 U 58.3 8835-011 Aniline <580 U 58.3 8835-011 Aramite <580 U 58.3 8835-011 Benzidine <580 U 58.3 8835-011 Benzo[a]anthracene <580 U 58.3 8835-011 Benzo[a]pyrene <580 U 58.3 8835-011 Benzo[b]fluoranthene <580 U 58.3 8835-011 Benzo[k]fluoranthene <580 U 58.3 8835-011 Bis(2-chloroisopropyl)ether <580 U 58.3 8835-011 Butyl benzyl phthalate <580 U 58.3 8835-011 Chlorobenzilate <580 U 58.3 8835-011 Chrysene <580 U 58.3 8835-011 Di-n-butyl phthalate <580 U 58.3



### Appendix A - SVOC - 26

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-011 Di-n-octyl phthalate <580 U 58.3 8835-011 Diallate <580 U 58.3 8835-011 Dibenzo[a,h]anthracene <580 U 58.3 8835-011 Dibenz[a,j]acridine <580 U 58.3 8835-011 Diethyl phthalate <580 U 58.3 8835-011 Dimethoate <580 U 58.3 8835-011 Dimethyl phthalate <580 U 58.3 8835-011 Dinoseb <580 U 58.3 8835-011 Diphenylamine <580 U 58.3 8835-011 Disulfoton <580 U 58.3 8835-011 Ethyl methanesulfonate <580 U 58.3 8835-011 Famphur <580 U 58.3 8835-011 Fluoranthene <580 U 58.3 8835-011 Fluorene <580 U 58.3 8835-011 Hexachlorobenzene <580 U 58.3 8835-011 Hexachlorobutadiene <580 U 58.3 8835-011 Hexachlorocyclopentadiene <580 U 58.3 8835-011 Hexachloroethane <580 U 58.3 8835-011 Hexachlorophene <14000 U 58.3 8835-011 Hexachloropropene <580 U 58.3 8835-011 Indeno(1,2,3-c,d)pyrene <580 U 58.3 8835-011 Isodrin <580 U 58.3 8835-011 Isosafrole <580 U 58.3 8835-011 Kepone <1200 U 58.3 8835-011 Methapyrilene <580 U 58.3 8835-011 Methyl parathion <580 U 58.3 8835-011 Methyl methanesulfonate <580 U 58.3 8835-011 N-Nitroso-di-n-butylamine <580 U 58.3 8835-011 N-Nitrosodi-n-propylamine <580 U 58.3 8835-011 N-Nitrosodiethylamine <580 U 58.3 8835-011 N-Nitrosomethylethylamine <580 U 58.3 8835-011 N-Nitrosomorpholine <580 U 58.3 8835-011 N-Nitrosopiperidine <580 U 58.3 8835-011 N-Nitrosopyrrolidine <580 U 58.3 8835-011 Naphthalene <580 810 58.3 8835-011 Nitrobenzene <580 U 58.3 8835-011 O,O,O-Triethylphosphorothioate <580 U 58.3 8835-011 o-Toluidine <580 U 58.3 8835-011 p-Dimethylaminoazobenzene <580 U 58.3 8835-011 p-Phenylenediamine <580 U 58.3 8835-011 Parathion <580 U 58.3 8835-011 Pentachlorobenzene <580 U 58.3



### Appendix A - SVOC - 27

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-011 Pentachloronitrobenzene <580 U 58.3 8835-011 Pentachlorophenol <580 U 58.3 8835-011 Phenacetin <580 U 58.3 8835-011 Phenol <580 U 58.3 8835-011 Phorate <580 U 58.3 8835-011 Pronamide <580 U 58.3 8835-011 Pyridine <580 U 58.3 8835-011 Safrole <580 U 58.3 8835-011 Sulfotepp <580 U 58.3 8835-011 Thionzin <580 U 58.3



### Appendix A - SVOC - 28

# 1-1

1.0 INTRODUCTION

This document provides technical background for the comparable fuel exclusion that is being
considered for the final rule. As part of an April 19, 1996 proposed (60 FR 17459) rulemaking, EPA has developed a comparable fuel exclusion. A comparable fuel would be an ignitable waste or coproduct production stream, both of which are currently defined as a hazardous waste, which meet the specifications of the exclusion. Comparable fuels are burned for energy recovery, in lieu of fossil fuels, due to their high BTU value. Benefits derived from this procedure include decreased use of fossil fuels and reduced operational costs. Under this provision, a comparable fuel would be excluded
from the Research Conservation and Recovery Act (RCRA), Subtitle C Regulation, as long as it meets the comparable fuel exclusion and is burned. Industry contends these waste streams are cleaner
than the fuels displaced and that burning these waste streams provides an overall environmental benefit. EPA’s goal is to provide a comparable fuel exclusion that is both useful to the regulated

c ommunity and assures that comparable fuel poses no greater risk than what otherwise would be associated with the burning of fossil fuels.

The Agency’s current approach is to base a comparable fuel exclusion on constituent

concentrat ions normally found in fossil fuels. For this “benchmark” approach, the concept is to permit hazardous constituents in the comparable fuel which are no greater in concentration than those
of the same constituents naturally occurring in commercially available fossil fuels. Additionally, the

current approach will not allow detectable levels of toxic synthetic chemicals, such as pesticides, in
the comparable fuels. This approach will assure EPA that the comparable fuel, when burned, will
pose no greater risk than a fossil fuel. This document contains data on as many toxic organics from
40 CFR, Part 261, Appendix VIII as could be quantitated for each fuel sample collected during this study. The EPA developed a series of constituent specifications based on the following parameters:
kinematic viscosity, total nitrogen, total halogens, individual metals, Appendix VIII organics, and
BTU content of each fuel. EPA is proposing that these specifications apply to all hazardous gaseous and liquid fuels, with the exception of viscosity, which is not relevant

# 1-2

for gaseous fuels. Table 1-1 gives the units of measure for each of these constituents and the individual metals analyzed.

In the proposed rule for comparable fuels, EPA presented several options to establish a
benchmark specification. This document presents the data used to develop the initial specification for the proposed rule and the specifications for the final rule. This document summarizes the
rationale of the ?

benchmark” approach used to set the specifications and discusses, with some detail, the analytical approach used to characterize the constituents of concern.

1.1 Benchmark Fuel Selection Basis

Potential benchmark fuels (on which to base the comparable fuel specifications) that were
considered include the commercially available fossil fuels of: (1) gases (such as natural gas and propane); (2) liquids (such as gasoline and fuel oils); and (3) solids (such as coal, coke, and peat). However, the benchmark fuels have been limited to liquid fossil fuels, including gasoline and Nos. 2, 4, and 6 fuel oils. This is because, as discussed below, solid fuels tend to have higher levels of hazardous constituents that are not destroyed in the incineration process, while gases tend to have hazardous constituent levels that are sufficiently low to make the specification of limited practical use.

Solid fuels (such as coal, wood, and biomass) will not be used to base the comparable fuels specification. Solid fuels are used widely throughout the U.S. as legitimate energy sources. However, the comparable fuel specification, which would exclude a hazardous waste fuel from RCRA Subtitle C regulation, will not be based on solid fossil fuels (in particular, coal) since they can have high levels of toxic constituents that will not be destroyed or detoxified by burning (e.g., metals and halogens). It is generally desired to minimize the feed rate of metals and halogens into waste incineration systems because these constituents are not destroyed in the incineration process (unlike organics which are destroyed; inorganics are found in the bottom ash, air pollution control system residues, or stack gas emissions). It is not the intent of the comparable fuels exclusion to set

# 1-3

TABLE 1-1. ANALYTICAL PARAMETERS AND CONSTITUENTS FOR COMPARABLE FUEL STUDY

Property of Interest Units Described As
Heating Value BTU/lb min. or range Kinematic Viscosity cSt at 100 F min. or range Specific Gravity at 15 C range and average Flash Point F minimum Total Nitrogen weight % maximum Total Halogens: ppm w 

# as Cl

- 

# maximum Fluorine maximum Chlorine maximum Bromine maximum Iodine maximum Metals: Antimony ppm w 1 

# maximum Arsenic ppm w 1 

# maximum Barium ppm w 1 

# maximum Beryllium ppm w 1 

# maximum Cadmium ppm w 1 

# maximum Chromium ppm w 1 

# maximum Cobalt ppm w 1 

# maximum Lead ppm w 1 

# maximum Manganese ppm w 1 

# maximum Mercury ppm w 1 

# maximum Nickel ppm w 1 

# maximum Selenium ppm w 1 

# maximum Silver ppm w 1 

# maximum Thallium ppm w 1 

# maximum Appendix VIII Organics ppm w 1 

# maximum Total Aromatics wt. % maximum Total PNAs Wt. % maximum

1 

# ppm w 

# = mg/kg

# 1-4

specifications based on the ? dirtiest” fossil fuels. Comparison with these solid fuels could result in

a least common denominator approach whereby a hazardous waste-derived fuel would be ? comparable” if it was no more dangerous to burn than the most contaminated fossil fuels. Such ? comparabili ty” is not congruent with the overall objective of RCRA in order to protect human health
and the environment. It is also inconsistent with the specific directive to regulate combustion of hazardous waste-derived fuels where necessary to protect human health and the environment (RCRA
Section 3004(q)). Thus, although a benchmark approach is used rather than a risk-based approach, the benchmark fossil fuels that are selected, in general, have lower contaminant levels for constituents that are not destroyed in the incineration process.

Metals and halogen concentrations in coal are compared with that of gasoline and fuel oils (Nos. 2, 4, and 6) in Table 1-2. For coal, median, maximum, and minimum levels are shown, based

on data from a recent IEA Coal Research report (Clarke and Sloss, 1992) and the Electric Power Research Institute (EPRI) PISCES database (Wetherold et al., 1995). Data for the liquid fossil fuels are given from three sources: (1) 90th percentile levels based on the recent EPA-sponsored testing specifically for developing the comparable fuels specifications; (2) for No. 2, 4, and 6 fuel oil, average
level s based on that from the EPRI Pisces database (Wetherold et al., 1995); and (3) for fuel oil, levels from the EPA/OSW database on hazardous waste burning combustors (including boilers and incinerators).

None of the Clean Air Act metals were detected in the gasoline samples. Pb, Ni, Sb, and Se

are the only metals typically found in the fuel oil samples (with the metals levels generally increasing
with the fuel oil number). Metals levels in coal can vary tremendously, depending on the origin of the fossil fuels. The No. 6 fuel oil high-end 90th percentile levels for Pb and Ni are comparable to the average coal levels. The average coal levels for As, Ba, Co, Cr, Mn, and Pb are typically 10 to
100 times higher than that of the liquid fossil fuels. Levels of Hg and Be in fuel oils are also typically
much less than that of coal. The chlorine content of coal and fuel oils can range widely from less than
50 to greater than 2,000 ppmw. Typically though, coal has a chlorine level that can be 2 to 10 times higher than that of fuel oils.

# 1-5

TABLE 1-2: COMPARISON OF THE METAL AND HALOGEN CONTENT OF COAL, GASOLINE, AND FUEL OILS

Constituent Concentration (ppmw)
Coal a 

## Gasoline

90th % b 

## Fuel Oil

No. 2 90th % b 

## Fuel Oil

No. 4 90th % b 

## Fuel Oil

No. 6 90th % b 

## Fuel Oil

No. 2, 4, 6 Average c 

## Fuel Oils e 

## Avg. Min. Max. Avg. Min. Max.
Antimony 1 0.05 10 < 7 < 6 < 11 6.5 0.2 Arsenic Barium 10

200 0.5 20 80 1000 < 0.14 < 14 < 0.12

< 12 < 0.2

< 23 < 0.2

< 20 0.3

NA 0.1

0.3 Beryllium Cadmium 2

0.5 0.1 0.1 15 3 < 0.7 < 0.7 < 0.6

< 0.6 < 1.2

< 1.2 < 1

< 1 0.2

0.3 0.1

0.5 Chromium Cobalt 20

5 0.5 0.5 60 30 < 1.4 < 2.8 < 1.2

< 2.4 < 2.3

< 4.6 < 2

< 4.1 0.7

2 0.5

Lead Manganese 40

70 2 5 80 300 < 7 < 0.7 6.6

< 0.6 9.9

< 1.2 30

< 1 2.6

0.2 Mercury Nickel 0.1

20 0.02 0.5 1 50 < 0.1 < 2.8 < 0.1

< 2.4 < 0.2

16 < 0.2

36 0.03

31 < 0.1

Selenium Silver 1

0.1 0.2 0.02 10 2 < 0.14 < 1.4 0.07

< 1.2 0.13

< 2.3 0.12

< 2 0.2

NA Thallium Chlorine < 1

1000 50 2000 < 14 < 25d < 12

< 25d < 23

< 0d < 20

< 10d NA

36 500 50 3000 Fluorine 150 20 500 NM NM NM NM NA

a Source: Clarke and Sloss (1992) e From hazardous waste burning combustors b Source: EPA (1996) NM: Not measured c Source: Wetherold et al. (1995) NA: Not reported

# 1-6

Gases are also not selected as benchmark fuels. Generally, basing the comparable fuel specification on a gaseous fuel would be overly conservative and have no practical use to the regulated industry (i.e., it is unlikely that many hazardous wastes would meet a fuel specification based on natural gas). Note that separate benchmark specifications are defined for a hazardous waste-derived fuel synthesis gas (syn-gas), as discussed below.

Additionally, non-petroleum liquid based fuels, including turpentine and tall oil, are not considered as benchmark fuels:

• Turpentine -- Turpentine has a very high energy content and is used as a fuel (and a
manufact uring feedstock) both within and outside the forest products industry. However, turpentine has not been selected since: (1) turpentine is not a widely used

c ommercial fuel; and (2) there are no ASTM standards for turpentine fuel which specify the minimum properties. This must be met for the product to be considered as a
commercial fuel.

• Tall oil -- Tall oil is a traditional fuel source, and EPA has acknowledged that tall oil is a legitimate non-waste fuel under the BIF rule low risk waiver exemption (LRWE) and DRE trial burn exemptions (see 56 FR 7193, February 21, 1991). However, tall oil is not used because of lack of quality constituent data.

Liquid fossil fuels of Nos. 2 and 6 fuel oils, and gasoline, have been selected as the benchmark
fuels. Liquid fuels are widely used by industry, readily combusted, and do not have the inconsistencies of solid or gaseous fuels. Gasoline has been included even though it is not typically utilized in industrial
boilers and furnaces. Gasoline is a highly used, commercially available, liquid fuel, for which complete hazardous constituent analysis is available (allowing for a more complete and useable benchmark specification).

# 1-7

1.2 Parameters and Rationale for Comparable Fuels Specifications

Benchmark fuel specifications are being set for: (1) physical specifications, including energy

content (heating value) and kinematic viscosity; (2) general constituent specifications for total nitrogen
and total halogens; and (3) individual hazardous constituents, including individual metals (including Sb, As, Ba, Be, Cd, Cr, Co, Pb, Mn, Hg, Ni, Se, Ag, and Tl), and Appendix VIII organics. Rationale for the selection of these parameters is discussed in the following.

Since most comparable fuels are expected to have a lower BTU content than fossil fuels, more comparable fuel will be needed to produce the same heating value. This situation will potentially
in crease the environmental loading of hazardous constituent emissions from the comparable fuel. More comparable fuel would be burned to achieve the same heat input leading to greater environmental loading of potentially toxic substances than if fossil fuel was burned. This would not follow the intent of the comparable fuel exclusion. To address environmental loading, a minimum heating value specification comparable to the BTU content of the benchmark fossil fuels is used. Constituent levels have been corrected from the fuel’s heating value (approximately 20,000 Btu/lb) to 10,000 Btu/lb.

1.2.1 Heating Value

A benchmark specification limit on minimum waste energy content is set. This is to ensure that
the comparable fuel has a legitimate use as a fuel (note that the comparable fuels exclusion only applies

to waste fuels that are ultimately burned). For solid and liquid wastes, a level of 5,000 Btu/lb (11,500 J/g) has been selected. This level has been traditionally used as a reasonable cutoff for determining if

a waste is being burned for energy recovery. Note that it is based on the typical heating value of wood.

1.2.2 Kinematic Viscosity

Liquid waste viscosity affects the efficiency of combustion by influencing the atomization characteristics of the liquid waste. Note that viscosity is an important design specification for liquid

# 1-8

burners. Thus the purpose of a viscosity specification is used to ensure that a comparable fuel is as burnable as the benchmark fuel.

The viscosity specification is based on that of No. 6 residual fuel oil (the heaviest, most viscous, liquid fossil fuel) at normal firing conditions. The comparable fuel viscosity specification is set at 50 cSt, as-fired. This is based on the ASTM standard for No. 6 fuel of 50 cSt (at 100 C, which is a

common firing temperature for No. 6 oil). Note that No. 6 residual oil must be heated (from 30 to
50 C) for handling and pumping purposes due to high viscosity at normal ambient temperatures. For atomization and burning, it must be heated further to reduce the viscosity needed for efficient atomization and combustion, usually to temperatures in the range of 70 to 130 C (160 to 270 F). The

exact temperature (and corresponding viscosity) requirement depends on factors including the burner design, atomization method (steam assisted, mechanical pressure, etc.), and viscosity characteristics
of the No. 6 fuel oil (note that there is no one No. 6 oil; different No. 6 oils can have significantly different viscosities at the same temperature). Typically, mechanical pressure atomization nozzles require that the oil have a viscosity of 15 to 30 cSt (70 to 150 SSU), while steam assisted burner nozzles can handle higher viscosities ranging from 30 to 70 cSt (150 to 300 SSU). The 50 cSt ASTM
value is an upper limit on what can be expected for No. 6 fuel oils at a typical firing temperature of
100 C (Perry and Green, 1994; Reed, 1986).

Additionally, the viscosity specification only applies to liquid waste fuels (not gaseous fuels, which are inherently less viscous than liquids, and not solids, for which viscosity is not applicable).

1.2.3 Flash Point

A specification on flash point is not being used since: (1) DOT and OSHA have regulations that control the hazards of flash point explosions; (2) it would preclude the inclusion of materials that are normally fuels such as methanol.

# 1-9

1.2.4 Total Halogens

A comparable fuel specification for total halogens is used, generally in-lieu of meeting the individual specifications of chlorinated Appendix VIII compounds (expect PCBs for the most part).
Limitation of the chlorine feed to the combustor is desired from an environmental protection perspective to: (1) reduce the emissions of the hazardous air pollutants of HCl and Cl 2 

# , both of whose
formation is directly related to the chlorine content of the waste feed; and (2) prevent the formation of chlorinated products of incomplete combustion (PICs), which includes PCDD/PCDF as well as
chlorinated benzenes, biphenyls, phenols, etc. Limiting the waste feed chlorine level reduces the potential for the formation of chlorinated PICs through (Dellinger et al., 1990):

• Limiting the release from the combustion zone of undestroyed and/or partially fragmented chlorinated precursors contained in the waste feed. Note that kinetic theory and experimental work indicate the chlorination of unchlorinated hydrocarbons is very unlikely at combustion temperatures (i.e., chlorinated PICs are not formed from unchlorinated hydrocarbons in the combustion zone). Thus, the emissions of
chlorinated PICs from the combustion zone is related directly to the chlorinated organic constituents in the waste feed. It is highly desired to minimize the level of chlorinated
precursors in the combustion gases since the major route to formation of high molecular weight chlorinated PICs is through reactions of already chlorinated
precursors.

• Limiting the potential for the formation of chlorinated PICs due to radical-radical association reactions as the combustion gas is cooled -- in particular organic radical
reactions with Cl radicals formed in the combustion zone.

• Ensuring adequate flame stability (and corresponding combustion efficiency) and reducing flame sooting. Increasing levels of chlorine are known to increase flame sooting and decrease flame stability and efficiency. Cl atoms scavenge H atoms,

# 1-10 depleting the flame radical pool that drives the combustion reactions.

Note that a total halogen limit may have only a secondary effect on controlling PCDD/PCDF emissions. Analysis of PCDD/PCDF data from full-scale waste combustion systems indicates that the

waste feed chlorine level does not have a dominant impact on PCDD/PCDF emissions (generally of pri mary importance is the PM air pollution control device temperature). However, the waste feed
chlo rine level may have a secondary influence. Certain well-controlled pilot-scale experimental studies indicate there can be a strong relationship between HCl and Cl 2 

# levels in the flue gas and PCDD/PCDF emissions (e.g., Gullett et al., 1994).

Additionally, a limit on total halogens, including both organic and inorganic forms, is appropriate since both forms in the waste fuel can contribute to halogenated PIC emissions. For example, PCDD/PCDF and other chlorinated PICs have been detected from sources burning both inorganic (e.g., salts) and/or organic chloride (e.g., plastics) containing wastes (e.g., Wikstrom et al., 1994; Fangmark et al., 1991; Christiansen, 1990; Nielsen, 1989). Inorganic chlorine salts have also been shown to act as a direct chlorine source for PCDD/PCDF formation at low de-novo synthesis temperatures (Addink and Olie, 1995).

No te that under well-controlled combustion conditions, the vast majority of organic halogens
in the waste fuel feed will leave the combustor gas as HCl, HF, etc. Smaller levels will be in the
combustion gas in the form of Cl 2 

# , F 2 

# , and halogenated organics, and some may also be present in the solid bottom and fly ash as salts. Inorganic halogen salts will also decompose to a lesser degree as HCl, HF, Cl 2 

# , F 2 

# , and PICs in the combustion gas; with the remainder as salts in the bottom and fly ash. Inorganic halogen salts are sometimes believed not to react at combustion temperatures due to high melting temperatures. However, work by Uchida et al., (1988) have shown that inorganic salts can directly contribute to HCl combustion gas levels (water vapor and zeolites participate in a reaction transforming chlorine salts to HCl). Thus, for halogenated hydrocarbon waste fuels, containing either inorganic or organic halogens, there is potential that under less optimum combustion conditions (higher CO, insufficient oxygen and mixing, etc.) halogenated PIC emissions may form.

# 1-11

1.2.5 Total Nitrogen

A specification on total nitrogen is used, in addition to those on nitrogenated Appendix VIII compounds. Under oxidative conditions of typical hazardous waste combustors, the majority of waste nitrogen will be emitted as N 2 

# (not of environmental concern) or NO x 

# (a criteria air pollutant whose emissions levels are covered under the Clean Air Act ambient air quality standards for ozone control). However, under starved air (reducing) conditions, nitrogen will primarily form the HAPs HCN and
NH 3 

# . Starved air transient ? puffs” can occur in hazardous waste combustors due to chamber overcharging (possibly due to unexpected surges in waste volatile composition), poor waste/air mixing, and poor liquid atomization. Additionally, nitrile radicals (CN ) can form nitrogenated PICs (such as
HAPs including hydrogen cyanide, acetonitrile, acrylonitrile, nitrophenols, nitrotoluenes, nitrobenzenes, aniline, acetamide, acrylamide, etc.) through radical-radical and radical-molecule reactions which occur as the combustion gas is cooled (Dellinger et al., 1990).

1.2.6 Metals

Benchmark specifications are set for the individual metals of Sb, As, Ba, Be, Cd, Cr, Co, Pb, Mn, Hg, Ni, Se, Ag, and Tl (which include both Clean Air Act Title III and RCRA Appendix VIII metals). Limitation of the metals feed to the incinerator results in a direct reduction of metals emissions since, like chlorine, metals are not destroyed in the combustion process.

1.2.7 Organics

Specifications are set for RCRA Appendix VIII organics. Note that specifications are not set
for some of the compounds on the Appendix VIII list because a routine analytical method is not available.

Specifications are set for oxygenates (at non-detect levels determined by the benchmark fuel analytical results). Oxygenates generally burn well and contribute to the combustion of other

# 1-12

constituents in the fuel (organically bound oxygen provides a source of oxygen for the combustion process). Oxygenates are added intentionally to clean-burning ? reformulated” gasoline to enhance the completeness of combustion in internal combustion engines. However, under poor combustion conditions, breakdown of the oxygenate at the oxygen bond can lead to the production of free radicals (Weitzman, 1991). These radicals can recombine with other radicals or compounds to form higher molecular weight chlorinated PICs. Thus, a comparable fuel specification for oxygenates is used.

1.3 Parameters and Rationale for Synthesis Gas Fuel Specifications

Comparable fuel specifications are set for ? synthesis” gas (syn-gas) separately from solid and
li quid hazardous wastes. The combustion of syn-gases meeting these specifications would be excluded from regulation as a hazardous waste. Syn-gas is generated by the gasification of hazardous wastes. Syn-gas is a mixture of primarily H 2 

# and CO, as well as the inerts of N 2 

# , CO 2 

# , Cl 2 

# , S, etc. The syn-gas characteristics depend primarily on: (1) the composition of the material that is being gasified (to date, mostly natural gas, oil, or coal, although systems for wood, plastics, sludges, and other types of wastes

are more recently being developed); (2) the use of oxygen vs. air for the gasification process; and (3)
the amount of steam utilized for the gasification process (which affects the CO/H 2 

# ratio). Syn-gas has

uses as:

• Feedstock in the chemical industry for making products such as ammonia, alcohols,

acetic acid, MTBE, etc., as well as other hydrocarbons. Also, it is used as a source of hydrogen in the petrochemical industry for hydrogenation processes. For this, a well defined and homogeneous material (usually some fossil fuel) is generally used for the syn-gas generation; and

• Fuel for power generation, heating, etc.

To ensure that the combustion of syn-gas is comparable to that of fossil fuels, specifications

are set on: (1) heating control; (2) general constituents for total chlorine, total nitrogen, and hydrogen

# 1-13

sulfide; and (3) individual Appendix VIII constituents. Rationale for the selection and determination of these specifications is discussed in the following.

1.3.1 Heating Value

A minimum heating value limit of 100 Btu/scf is set for syn-gas. The minimum specification
of 100 Btu/scf is based on syn-gas from the gasification of coal with oxygen. It is commonly required for gas turbine energy production.

For fuel usage related purposes, syn-gases are classified as either medium or low-BTU gases (medium generally being produced with pure oxygen, low-BTU generally with air). Medium BTU syngases generated from the gasification of fuels (including coal, fuel oil, biomass, municipal solid wastes, plastics, etc.) with pure oxygen can have heating values from 250-400 Btu/scf (Stultz and Kitto, 1992).
Low-BTU syn-gases generated from the gasification of fuels with air can have heating values from
about 100-200 Btu/scf. The heating value of the syn-gas depends primarily of the diluent content (nitrogen, carbon dioxide, chlorine, sulfur, moisture, etc.), which is a strong function of the syn-gas
feed material composition and gasification process (particularly if air or pure oxygen is used for the gasification process). The heating value is not a strong function of the H 2 

# /CO ratio since both gases
have similar heating values on a Btu/scf basis (although a low H 2 

# /CO ratio can adversely affect flame stability).

Syn-gas used as a fuel for power production in gas turbines typically requires a heat content
from 250-450 Btu/scf, with a lower limit of around 200 Btu/scf. Intentionally manufactured syn-gases

can have heating content levels as low as 100 Btu/scf (e.g., coal gasifiers with air). However, this gas by itself, although it may be quite burnable, does not achieve temperature and expansion ratios needed for thermodynamically efficient power generation. Thus, it is usually mixed with higher energy sources, and is not generally desired for most applications. Note that there are certain specially designed gas turbines (with very large ?

silo” combustion chambers) that can handle very low-BTU (100 Btu/scf) syngases for power generation (for example, see Geiling (1992) and Gas Turbine World (1990)).

# 1-14

Additionally, other low-BTU by-product gases are also used effectively for their fuel value (e.g., the blast furnace byproduct gas from steel manufacturing, with a heating level of about 50 Btu/scf and enhanced with gas and oil, is used in the furnace heating stoves).

Because syn-gas is sometimes used as a chemical feedstock, an absolute lower limit on heating value for comparable fuel classification may not be appropriate or needed because the syn-gas is not being used for energy recovery or supplementary purposes, making its heat content irrelevant. However, as a practical matter, whether or not syn-gas is being used as a chemical feedstock or fuel,
the syn-gas is always being produced for its CO and/or H 2 

# content -- thus all gasification related syngases will have some appreciable heat content.

It is important to note that the heating value specification is expressed on a volumetric basis of Btu/scf (as opposed to Btu/lb for solid and liquids) because: (1) is it not appropriate to compare the heating value of different gases expressed in units of Btu/lb since the ratio of the weight-to-volume
differs between different gases (particularly H 2 

# and CO); and (2) industry standard practice is to classify syn-gases based on the energy content per unit volume of gas.

1.3.2 Hydrogen Sulfide

A hydrogen sulfide (H 2 

# S) specification of 200 ppmv is set. The sulfur content of the material
used to produce the syn-gas is converted almost entirely into H 2 

# S in the gasification process, with smaller amounts of COS. Thus, syn-gases produced from low sulfur content material such as wood, biomass, natural gas, and low sulfur fuel oil and coal, do not contain any appreciable H 2 

# S. Once the
syn-gas is burned under oxidizing conditions, the H 2 

# S, if not removed prior to completing combustion,

is converted to SO x



# (primarily SO 2 

# ). SO x



# emissions are regulated through the issuance of local air permits and the Clean Air Act national ambient air quality standards.

The H 2 

# S content of high sulfur coal-based syn-gases can be over 1,000 ppmv (Stultz and Kitto,

# 1-15

1992). However, in these cases, H 2 

# S removal processes such as those based on the Claus process or regenerable metal sorbents are almost always used to reduce H 2 

# S to well below 10 ppmv prior to syngas usage as a feedstock or for fuel value (for two technical reasons: (1) H 2 

# S is much more easily removed than SO x



# which are formed from syn-gas combustion, and (2) the syn-gas has a much lower
flue gas volume than the gas produced from syn-gas full combustion). For use as a fuel, the technical limitation on the H 2 

# S content of syn-gas is due to corrosion of downstream gas handling equipment,
such as turbine blades, fans, etc. Generally levels below 200 ppmv can be tolerated. Note that for use as a feedstock, levels under 1 ppmv are usually required.

1.3.3 Nitrogen (other than N 2 

# )

A nitrogen compound level (NH 3 

# +HCN, other than N 2 

# ) of 300 ppmv is set. This is based on
the typical nitrogen compound levels (NH 3 

# +HCN) from syn-gases manufactured by coal from 100 to
300 ppmv (Stultz and Kitto, 1992). Nitrogen compounds in syn-gases are mostly in the form of NH 3 

# , with smaller amounts of HCN and other nitrogenated organics. When syn-gases are burned, the nitrogen is converted primarily to NO x 

# , which is regulated through the issuance of local air permits and
the Clean Air Act national ambient air quality standards. However, due to the increased potential to form nitrogenated PICs (as discussed previously for the comparable fuel specification for total nitrogen
in solid and liquid wastes), especially from incomplete combustion conditions associated with inefficient incinerators, a specification on total nitrogen (other than N 2 

# ) is set.

1.3.4 Total Halogens

A total halogen specification for syn-gas of 1 ppmv is set. For use as a feedstock, a total halogen level of under 1 ppmv is usually required. For use as a fuel, lower concentrations of total halogens are desired to prevent corrosion in the downstream syn-gas burning equipment. In typical gasification processes, the majority of the halogens contained in the feedstreams are converted to syngas as gaseous halides and/or halogens. (Note that in some cases where the feedstream also contains
alkali constituents such as sodium or lime, halogens may also be found in the bottom or entrained ash

# 1-16

as solid salts). The raw halogen content of the syn-gas is thus a direct function of the halogen content of the material used to generate the syn-gas. For low halogen content materials, such as natural gas,
and some fuel oils, coal, wood, and biomass streams, the syn-gas will not contain appreciable halogen levels. Alternatively, for some higher halogen content materials, such as certain coals with halogen

contents of greater than 1000 ppmv, the concentration of halogen in the resulting syn-gas may be greater than 50 ppmv. However, as discussed above for hydrogen sulfide, when the syn-gas halogen content is high, halogen removal processes are used prior to syn-gas use as a fuel or feedstock. Halogen removal efficiencies are usually very high, i.e., greater than 99%. Thus, a level of 1 ppmv is reasonably achievable even for high halogen content syn-gas materials.

1.4 Collection of Liquid Fossil Fuel Samples Used for Analysis to Determine Benchmark

Commercially available fossil fuels are very diverse. The constituents in fuels can vary, depending on where fuels are refined, the condition of the catalysts used, and the origin of the raw
material. Typically, fuels found on the East Coast are refined from Venezuelan and Middle East crude. Fuels on the West Coast are refined from domestic crude, although they can contain Venezuelan crude.
This makes it almost impossible to determine the source of a given fuel. All fossil fuels are prepared

to meet a series of American Standards for Testing Materials (ASTM) specifications, which were adopted as commercial standards by the National Bureau of Standards. These standards have been revised many times to meet changes in supply, so it is likely that they will continue to change as supplies change. The specifications focus on the physical parameters of the fuels, such as distillation temperatures, specific gravity, and viscosity.

To set the preliminary specification for comparable fuels, the EPA needed data on the
concentrations of hazardous constituents in these fuels, as well as data on the physical parameters (viscosity, heating value, etc). Since this data is not readily available, EPA collected, from various geographic locations around the country (Table 1-3), representative samples from the end uses of conventional liquid fuels. This approach was designed to ensure a representative sampling, since constituents can vary, depending on the point of origin.

# 1-17

TABLE 1-3. GEOGRAPHIC REGIONS WHERE FUEL SAMPLES WERE COLLECTED

LOCATION SAMPLES COLLECTED Irvine, California Gasoline and Nos. 2, 4, and 6 fuel oils North West New Jersey Gasoline and No. 2 fuel oil North East Connecticut Gasoline and Nos. 2 and 6 fuel oils Coffeyville, Kansas Gasoline and No. 2 fuel oil Fredonia, Kansas Gasoline and No. 2 fuel oil Norco, Louisiana Gasoline and Nos. 2 and 6 fuel oils Hopewell, Virginia Gasoline and Nos. 2 and 6 fuel oils Research Triangle Park, North Carolina Gasoline and No. 2 fuel oil

A database comparing emissions using comparable fuels and fossil fuels does not exist. Since

a comparison cannot be made between these fuels, a database on the toxic constituents of fuels being burned needs to be developed. This study analyzed each fossil fuel for all 40 CFR, Part 261, Appendix
VIII toxic organic constituents for which a reasonable approach exists under SW-846 methodologies. The study also covered physical parameters, using ASTM protocols.

Based on the results of this study, a specification can be derived for comparable fuels that ensures they contain no more toxic constituents than the ? benchmark” fuel(s). In addition, method detection limits (MDLs) were determined for each SW-846 Method used, in accordance with 40 CFR,
Part 136, Appendix B. Section 2 of this document discusses the process used for determining the MDLs in more detail.

# 1-18

References:

ASME (American Society of Mechanical Engineers), ? The Relationship Between Chlorine in Waste
Streams and Dioxin Emissions from Waste Combustor Stacks,” American Society of Mechanical Engineers, 1996.

Clarke, L.B. and L.L. Sloss, Trace Elements - Emissions From Coal Combustion and Gasification , IEA Coal Research, London, England, IEACR/49, July 1992.

Dellinger, B., P. Taylor, and D. Tirey, ? Minimization and Control of Hazardous Combustion Byproducts,” EPA/600/S2-90/039, August 1990.

Gas Turbine World, ?

Kellogg’s PFB-Hybrid Combined Cycle Concept Based on UTC/KWU V84.4 Turbines,” Gas Turbine World , pp. 20-23, Nov/Dec 1990.

Geiling, D. (editor), Proceedings of the 9th Annual Coal-Fueled Heat Engines, Advanced Pressurized Fluidized-Bed

Combustion, and Gas Stream Cleanup Systems Contractors Review Meeting , U.S. DOE Office of Fossil Energy, DOE/METC-93/6129, October 1992.

Gullett, B.K., P.M. Lemieux, and J.E. Dunn, ? Role of Combustion and Sorbent Parameters in
Prevention of Polychlorinated Dibenzo-p-dioxin and Polychlorinated Dibenzofuran Formation during Waste Combustion,” Environmental Science and Technology , Vol. 28, pp. 107-118, 1994.

Lanier, S., et al., ?

Dioxin Compliance Strategies for the HWC MACT Standards,” 1996 Incineration Conference , pp. 587-593, Savannah, Georgia, May 1996.

Perry R.H. and D. Green (editors), Perry’s Chemical Engineering Handbook , 6th Edition, McGraw Hill, pp. 9-13, 1994.

# 1-19

Reed, R.J., North American Combustion Handbook , Third Edition, North American Manufacturing Company, Cleveland, OH, p. 30, 1986.

Stultz, S.C. and J.B. Kitto (editors), Steam: Its Generation and Use , 40th Edition, Babcock and Wilcox, 1992.

Weitzman, L., ?

Engineering Handbook for Hazardous Waste Incineration,” Draft No. 3, Prepared for the EPA Center for Environmental Research Information under Contract No. 68-08-0011, Work Assignments 1-30, January 31, 1991.

Wetherold, R.G., D.A. Orr, J.M. Leonard, and B. Toole O’Neil, ? The EPRI Pisces Database: Summary of Fuels Information,” EPRI/DOE International Conference on Managing Hazardous and Particulate
Air Pollutants , Toronto, Ontario, Book 2, August 15-17, 1995.

Addink, R. and K. Olie, ? Mechanisms of Formation and Destruction of Polychlorinated Dibenzo-pdioxins and Dibenzofurans in Heterogeneous Systems,” Environmental Science and Technology , Vol. 29, No. 6, pp. 1425-1435, 1995.

Ch ristiansen, K., A. Grove, et al., Environmental Assessment of PVC and Selected Alternative Materials , Danish National Agency of Environmental Protection, 1990.

Fangmark, I., S. Marklund, and C. Rappe, ? Use of Synthetic Refuse in a Pilot Combustion System for Optimizing Dioxin Emission, Part II,” Chemosphere , Vol. 23, pp. 1233-1243, 1991.

Nielsen, P., ?

Significance of Operating Conditions and Chlorine Sources on Dioxin Formation: Experience of the Danish Incinerator Study,” Proceedings of the 1989 International Conference on Municipal Waste Combustion , Hollywood, FL, April 11, 1989.

# 1-20

Uchida, S., H. Kamo, and H. Kubota, ? The Source of HCl Emissions from Municipal Refuse Incinerators,” Ind. Eng. Chem. Res., Vol. 27, No. 11, pp. 2188-2190, 1988.

Wikstrom, E., G. Lofvenius, S. Marklund, and C. Rappe, The Role of Organic Chlorine (PVC), Inorganic Chlorine (CaCl2), Total Chlorine, and Copper in the Formation of Dioxin and Chlorobenzenes During Combustion of a Synthetic Fuel in a Pilot Reactor , Report from the Institute of Environmental Chemistry, Umea University, December 1994.

# 2 - 1

2.0 SAMPLING AND ANALYSIS

As stated previously, EPA collected and characterized samples of gasoline and Nos. 2, 4, and
6 fuel oils in order to provide data on which to base a ? benchmark” fuel. Altogether, EPA collected

ten (10) gasoline samples, eleven (11) No. 2 fuel oil samples, one (1) No. 4 fuel oil sample, and seven (7) No. 6 fuel oil samples from various geographic regions around the country.

EPA worked with the Chemical Manufacturers Association (CMA) and its member organizations in obtaining fuel samples. CMA supplied a list of members to contact, as well as a letter endorsing EPA’s efforts in this area. Contact was initiated with each company by telephone. They were questioned as to the nature of the fuels they burned in their boiler systems and, if one or

more was a fuel of concern, whether they would they be willing to supply EPA with a one-liter sample for characterization and quantification.

Many industrial users were either skeptical about participation in a program of this type or had converted their units to natural gas. However, approximately 10% of those contacted were willing to cooperate. A number of industries had switched from No. 6 fuel oil to No. 2 fuel oil and/or
natural gas, due to the difficulties and energy required to handle No. 6 fuel oil, especially in colder weather. Also, a very limited number of companies in the United States use No. 4 fuel oil. With

narrow time constraints for this program, the limited use of Nos. 4 and 6 fuel oil by U.S. industries, and the corporate restraints on participating in these type of programs, EPA was limited in the number of Nos. 4 and 6 fuel oil samples it could obtain.

2.1 Analysis of Samples

This aspect of the program focused on the analysis of the combustion fuel samples (gasoline and Nos. 2, 4, and 6 fuel oils) collected for the program in order to characterize the chemical and physical properties and the presence of the hazardous constituents listed in 40 CFR, Part 261, Appendix VIII. From a historical perspective, 40 CFR, Part 261, Appendix VIII is the reference list

# 2 - 2

of potential hazardous constituents which need to be quantitated in the fossil fuels in order to set a specification. From a practical perspective, however, the essence of such a list and testing for the
substances in the list present significant problems. The problems and some of the difficulties they impose are as follows:

1. The chemicals listed in 40 CFR, Part 261, Appendix VIII, are listed as they would
exist in a pure state, as opposed to the forms they would take after being dispersed into the environment;

2. In developing 40 CFR, Part 261, Appendix VIII, no consideration was given to
factors such as the environmental fate or the level of production of a given chemical. The list contains both prevalent, mobile, and toxic chemicals, that present major risks, and some chemicals that present a lesser risk due to low prevalence or instability in a matrix such as fuel oil or water; and

3. Analysis of many constituents from 40 CFR, Part 261, Appendix VIII would be impossible and/or impractical for the matrix being considered in this study for a variety of reasons: there are indefinitely large classes of compounds, many of which
would not exist in fossil fuels; and standards do not exist for many other compounds.

The fundamental concern for EPA in developing the comparable fuel exclusion is to create

a database by quantitating as many of the constituents from 40 CFR, Part 261, Appendix VIII as
could readily and reliably be identified in the fossil fuels. However, the development and validation of new methodologies was not within the scope of this program. Thus, it was necessary to take an approach that used existing methodologies to quanitate as many of the constituents in 40 CFR, Part 261, Appendix VIII as possible.

To quanitate each fossil fuel sample, EPA chose to use the methodologies defined for the constituents from 40 CFR, Part 261, Appendix VIII subject to the following criteria:

# 2 - 3

1) It must be practical to analyze fossil fuels for the constituent under consideration.

The chemistry of fossil fuels, the processes involved in their production, and the availability of practical and reliable analytical methodologies and standards were used to identify whether
constituents fit the later consideration.

SW-846, ?

Testing Methods for Evaluating Solid Waste,” presents the methods most commonly used for quantitating organic and metal constituents in various matrices. Since matrices vary in waste streams, the methods have some flexibility. The analyst is then allowed to adjust the sample preparation procedures for the matrix being analyzed. The following information pertains to all analytical data generated to date for the Appendix VIII analytes.

In all cases the laboratory attempted to use approved and published methodologies. There

was not time to determine what procedures were under development for fuel oil analysis by EPA or other agencies/laboratories at the time the analyzes took place.

Many of these analytes presented special analytical challenges since methods for their analysis

were not available in SW-846 or CLP methods. Additionally, the gasoline and fuel oil matrices compounded the difficulties experienced in these analyses. Consequently, data for all the targets are not presented in this report. Table 2-1 details analytes for which data is not provided and why these data points were not generated.

It is important to note that compounds marked as not detected by VOA, semi-VOA, or HPLC

were not detected using instrument conditions attempted to date. These compounds may be
detectable at concentrations greater than 200 ppm by different instrument conditions than those attempted. Compound by compound research would be required to determine an approach for their analysis.

# 2 - 4

Many metallic compounds appearing in the target lists were not specifically analyzed. Samples were analyzed for metallic elements, not organo-metallic compounds. Direct analysis for organo-metallic compounds would have been preferable, however, to the best of our knowledge, methods are not available to measure organo-metallics in these types of matrices. For example, thallium (1) acetate was reported as total thallium or lead phosphate reported as total lead.

Due to time constraints for this project, other categories were too broad for complete analysis. There are cases where the number of compounds, categories such as chlorinated fluorocarbons, are

too great to analyze for every possible isomer. In situations like these, three of the more common chlorinated freons, dichlorodifluoromethane, trichlorofluoromethane, and 1,1,2-trichloro-1,2,2-
trifluoroethane have been analyzed during the analytical phases of the clean fuels initiative. Results for chlorinated freons can be expressed as the sum of these compounds. Some of these reported compounds are listed by a synonym of the name found in Appendix VIII.

In all the analyses performed, the hydrocarbon matrix presented analytical difficulties. Most notable were the VOA and semi-VOA analyses performed by mass spectrometry. In most cases, the analyst had to manually integrate internal standards, surrogates, and targets, especially targets in the matrix spikes. These manual integrations were subjective, but were never done to intentionally misrepresent the data. In every manual integration, an honest attempt was made to isolate only the areas of interest. It must be noted that other analysts or data reviewers may have made the manual integrations differently.

For this study, each sample was collected in a pre-cleaned, 1-liter amber glass sample bottle with a Teflon ® 

# -lined cap. This type of sample bottle is available commercially with a certificate of analysis. All sample bottles were pre-cleaned according to EPA protocol. Samples were collected through purge valves, located on the main system feed lines prior to the burner. The fuel was allowed

to purge through the valve and into a waste container, ensuring the collection of a fresh sample and removing any debris which may have collected in the line or valve.

# 2 - 5

The following discussion summarizes the sample preparation, instrumental analysis and quality control procedures used to generate the data collected for each of these samples. Each section also briefly discusses any analytical difficulties encountered by the laboratory.

2.2 GC/MS Volatiles

2.2.1 Method Summary

A method for analyzing the volatile compounds was developed based on SW-846, Method
8240. A gas chromatograph with a fused silica capillary column and mass spectrometer was used to separate, identify, and quantitate the target analytes. Standards containing the target analytes in methanol were prepared at five levels. One microliter of each of these standards was used to calibrate
the analytical system. Samples were treated as if they were at high concentrations and diluted weight to volume prior to analysis. This preparation was then injected into a heated injection port thereby transferring the sample to the analytical system. The direct injection technique was chosen over purge and trap because of the high volatile organic background in the matrix.

2.2.2 Sample Preparation

Method 8240 calls for a 2.5x weight to volume sample dilution/extraction with methanol. The
methanol is the analyzed portion. To provide the lowest detection limits, a 2x dilution/extraction was performed. Actual sample weights were recorded and used to calculate the true dilution factor. Surrogate compounds were prepared in a methanol solution. The sample was diluted with methanol and surrogates were added. For gasoline, 1 g was diluted with 10 mls of methanol. In the case of
No. 2, 4, and 6 fuel oils, 4 g was extracted with 10 mls of methanol, since the fuel oils were not miscible with methanol.

# 2 - 6

Table 2-1 Analytes from Appendix VIII Not Determined During Study

Analyte Reason Data Could Not be Generated. Azaserine Compound toxicity too great to safely handle Epinephrine A solvent compatible with analysis not found Ethylenedithiocarbamic acid Standard not available Mitomycin C A solvent compatible with analysis not found alpha-naphthylthiourea A solvent compatible with analysis not found Reserpine A solvent compatible with analysis not found Selenourea Too reactive in air and water Streptozoticin A solvent compatible with analysis not found Thiosemicarbizide A solvent compatible with analysis not found Cyanogen Standard not available Nitrogen mustard Standard not available Methyl hydrazine Not detected by voa, semi-voa, or HPLC analysis Trypan blue Not detected by voa, semi-voa, or HPLC analysis Warfarin Not detected by voa, semi-voa, or HPLC analysis Chloromethoxy methane Not detected by voa, semi-voa, or HPLC analysis Chloroacetaldehyde Not detected by voa, semi-voa, or HPLC analysis Formic acid Not detected by voa, semi-voa, or HPLC analysis 2-Methyl azidrine Not detected by voa, semi-voa, or HPLC analysis Dimethyl sulfate Not detected by voa, semi-voa, or HPLC analysis Tetranitromethane Not detected by voa, semi-voa, or HPLC analysis Aldicarb Not detected by voa, semi-voa, or HPLC analysis 3,4-Diaminotoluene Not detected by voa, semi-voa, or HPLC analysis Methylthiouracil Not detected by voa, semi-voa, or HPLC analysis Ethyl carbamate Not detected by voa, semi-voa, or HPLC analysis Maleic anhydride Not detected by voa, semi-voa, or HPLC analysis Tetraethyl pyrophosphate Not detected by voa, semi-voa, or HPLC analysis Chloromethyl methyl ether Not detected by voa, semi-voa, or HPLC analysis Creosote Chromatographically identical to and inseparable from fuel oil Coal tar creosote Chromatographically identical to and inseparable from fuel oil Nitroglycerine Not detected by voa, semi-voa, or HPLC analysis N-nitrosodiisopropylamine Standard could not be procured in time for analysis N-Nitrosodiethanolamine Standard could not be procured in time for analysis 1,1-dichloropropane Standard could not be procured in time for analysis N-nitroso-N-ethylurea Not detected by voa, semi-voa, or HPLC analysis N-nitroso-N-methylurea Not detected by voa, semi-voa, or HPLC analysis Dithiobiuret Not detected by voa, semi-voa, or HPLC analysis Ethylene glycol monoethyl ether Not detected by voa, semi-voa, or HPLC analysis Methanol Not detected by voa, semi-voa, or HPLC analysis Phosphoricdithioic acid, Trimethyl Ester Standard not available

# 2 - 7

2.2.3 Instrumental Analysis

SW-846, Method 8240 was employed for the instrumental analysis. A gas chromatograph with a fused silica capillary column and mass spectrometer was used to separate, identify, and quantitate the target analytes. One microliter of each methanol extract was injected into a heated injection port thereby transferring the sample to the analytical system.

2.2.4 Quality Control

Method 8240 was followed as closely as the analyte target list and sample matrix would allow.
See Table 2-2 for additional information regarding specific procedures utilized on this project. A method blank was analyzed for each matrix. Section 2.14 of this report presents a discussion of surrogate spiking compound results for each sample and matrix spike as well as laboratory control sample (LCS) results for each analysis type. The QC results for surrogates are in Appendix D. The following specific criteria were used for this project:

50 ng of bromofluorobenzene (BFB) was analyzed at least every twelve hours with the tuning fragmentation pattern meeting the criteria specified in 8240;

A five-point initial calibration curve with each volatile target was analyzed prior to sample analysis. However, since documentation on the behavior of these compounds could not be found, arbitrary limits were not set for the initial calibration. This data should be used as a first attempt to determine practical limits for these compounds;

A continuing calibration was analyzed after each 12-hour BFB tune. Again, arbitrary limits were not set until practical recovery limits can be established; and

The following Internal Standards and surrogates were used during the analysis.

# 2 - 8 Internal Standards Concentration Surrogates Concentration
Bromochloromethane 50 mg/kg 1,2-Dichloroethane-d 4 

## 50 mg/kg 1,4-Difluorobenzene 50 mg/kg Toluene-d 8 

## 50 mg/kg Chlorobenzene-d 5 

## 50 mg/kg Bromofluorobenzene 50 mg/kg



# Table 2-2 Comparable Fuels Procedures - Organics

Volatiles Analyses
Gasoline No. 4 & 6 Fuel Oil No. 2 Fuel Oil Sample Prep Diluted with Methanol

Matrix soluble in Methanol Methanol Solvent
Matrix not

soluble in
Methanol Methanol Solvent
Matrix not

soluble in
Methanol

LCS Standards Spiked into

Methanol Standards Spiked into
Methanol Standards Spiked into
Methanol

Matrix Spiking & Surrogates Gasoline diluted with

Methanol then MS Standards & Surrogates Added Methanolic Standards Spiked into Fuel Oil, then extracted
with Methanol Methanolic Standards Spiked into Fuel Oil, then
extracted with Methanol

Comments None See Section 2.1.5 for related

comments. See Section 2.1.5 for related

comments.

Semi-Volatiles Analyses Sample Prep Diluted with MeCl

Matrix soluble in MeCl.
Extract was solvent exchanged to facilitate evaporation of interfering compounds such as xylenes. Diluted with MeCl
Matrix soluble in MeCl GPC Cleanup Diluted with MeCl
Matrix soluble in MeCl GPC Cleanup

LCS Standards Spiked into MeCl Standards Spiked into MeCl Standards Spiked into MeCl

Matrix Spiking & Surrogates Standards Spiked into

Gasoline, then diluted with

MeCl Standards Spiked into Fuel

Oil, then diluted with MeCl Standards Spiked into Fuel Oil, then diluted with MeCl

Comments None None None

# 2 - 9 HPLC 

# Analyses Sample Prep Extracted with TCLP

Extraction Fluid Extracted with TCLP
Extraction Fluid Extracted with TCLP
Extraction Fluid

LCS Standards Spiked into

Hexane then extracted Standards Spiked into Hexane
then extracted Standards Spiked into
Hexane then extracted

Matrix Spiking & Surrogates Standards Spiked into

Gasoline/TCLP fluid mixture, then extracted Standards Spiked into Fuel Oil/TCLP fluid mixture,
then extracted Standards Spiked into
Fuel Oil/TCLP fluid mixture, then extracted

Comments Mixed equal volume of

gasoline and TCLP extraction fluid, rotated 18 hrs. Analyzed TCLP fluid. Mixed equal volume of Fuel
Oil and TCLP extraction fluid, rotated 18 hrs. Analyzed TCLP fluid. Mixed equal volume of Fuel
Oil and TCLP extraction fluid, rotated 18 hrs. Analyzed TCLP fluid.



# 2.2.5 Analytical Difficulties

The oily matrix of these samples posed the largest problem. Gasoline samples were miscible with methanol, but the fuel oil samples were not. Since the fuel oil samples were not miscible with

m ethanol, results are likely to be biased low since the entire sample was not analyzed. As stated above, surrogate compounds were prepared in a methanol solution. This surrogate solution was then added directly to the specific matrix. For gasoline, which was soluble with methanol this does not
po se a problem, however, for the fuel oils, since they were not soluble with methanol, the surrogates and matrix spike results may not be truly indicative of analyte recovery from the actual matrix. Headspace analysis may be a viable alternative to SW-846 8240, methanol dilution for future work. Another significant problem was the high frequency of instrument maintenance required to maintain analyt ical reliability. Also, several target analytes showed non-linear or inconsistent responses. Although exceeding 50% RSD, epichlorohydrin and benzenethiol were all present in each initial calibration point.

# 2 - 10

2.3 GC/MS Semi-Volatiles

2.3.1 Method Summary

SW-846, Method 8270A was followed as closely as possible for the on-instrument analysis and Method 3520 was used to clean-up samples by gel permeation chromatography to allow their analysis at the lowest possible dilutions.

2.3.2 Sample Preparation

Th e gasoline samples were prepared by solvent exchange into methylene chloride. This procedure removed some of the volatile hydrocarbon background allowing analysis at lower dilutions
than untreated gasoline. Surrogates were added prior to the solvent exchange to monitor analyte
recovery. Based on the results from the MDL study (Appendix C) the solvent exchange procedure had no apparent impact on the semi-volatile results.

No. 2, 4, and 6 fuel oils were prepared by weighing 1 gram of sample, adding surrogate spiking compounds, then diluting to 10 mls with methylene chloride. The resulting solution was run through a gel permeation chromatography clean-up prior to analysis.

2.3.3 Instrumental Analysis

SW-846, Method 8270A was employed for the instrumental analysis. A gas chromatograph with a fused silica capillary column and mass spectrometer was used to separate, identify, and quantitate the target analytes. One microliter of each methylene chloride extract was injected into a heated injection port thereby transferring the sample to the analytical system.

2.3.4 Quality Control

Method 8270A was followed and included the following QC procedures. See Table 2-2 for
additional information regarding specific procedures utilized on this project. A method blank was

# 2 - 11

analyzed for each matrix. The following specific criteria were used for this project:

A 50 ng DFTPP tune was run every twelve hours and met the criteria found on page 8270-9 of SW-846, Method 8270A before any other analyses were run.

A five-point initial calibration containing each additional analyte was analyzed and average
response factors for each compound calculated. Since no documentation on the behavior of these compounds could be found, arbitrary limits were not set for the initial calibration.

Every twelve hours, immediately following the DFTPP tune, a continuing calibration was analyzed. However, for reasons listed above, arbitrary acceptance limits were not set. All samples were quantitated against the associated batch continuing calibration.

Samples were run as undiluted as possible. Dilutions were made to prevent detector saturation by non-target peaks.

Six (6) surrogate compounds, three (3) acid and three (3) base neutral extractable compounds, were spiked into each sample prior to the sample's preparation for analysis
as follows:

Surrogates Concentration Surrogates Concentration
Phenol-d 6 

## 100 ppm on-column 2-Fluorobiphenyl 100 ppm on-column 2-Fluorophenol 100 ppm on-column Nitrobenzene-d 5 

## 100 ppm on-column 2,4,6-Trichlorophenol 100 ppm on-column 4-Terphenyl-d 14 

## 100 ppm on-column



# Six (6) internal standards were used for target quantitation. All six (6) internal standards

met +/- 50% recovery in each sample as compared to the associated continuing calibration for the sample analysis to be considered valid.

Internal Standards Concentration Internal Standards Concentration 1,4-Dichlorobenzene-d 4 

## 40 ppm final dilution Phenanthrene-d 10 

## 40 ppm final dilution Naphthalene-d 8 

## 40 ppm final dilution Chrysene-d 12 

## 40 ppm final dilution Acenaphthene-d 10 

## 40 ppm final dilution Perylene-d 12 

## 40 ppm final dilution

# 2 - 12

2.3.5 Analytical Difficulties

Most problems involved contamination of the analytical instrumentation by the fuel oil matrix which caused occasional peak broadening, baseline elevation, and reduced sensitivity of easily degraded analytes. However, routine maintenance to the injection port inlet after each batch of fuel oil analysis kept the GC/MS system within acceptable operating parameters.

Most analytes performed linearly in the initial calibration. However, endothall, 6-propyl-2-
thi ouracil, and strychnine, while present in all calibration points, were greater than 50% RSD. Several other compounds exhibited poor response factors which contributed to the inability to detect them in matrix spikes.

The matrix spikes presented the greatest analytical problems. To yield meaningful recovery data, No. 2 fuel oil was diluted 10:1 with methylene chloride and spiked with compounds in a
methanol solution. The resulting solution was cleaned up by GPC, then diluted 4:1 in methylene chloride for analysis. This solution minimized fuel oil interferences. All spiked compounds recovered
within the calibration range except 4-aminopyridine, m -phenylenediamine, 3,3'-dimethoxybenzidine, and 6-propyl-2-thiouracil.

The gasoline matrix spike was solvent exchanged into methylene chloride to reduce as much
of the aromatic background as possible. No further dilution was made prior to analysis. In this mix, the following compounds, if recovered, were masked by the matrix background and reported as not detected; 2,3-dichlorophenol, 2,5-dichlorophenol, 3,4-dichlorophenol, 3,5-dichlorophenol, 3- chlorophenol, 4-chlorophenol, acetone cyanohydrin, 2,3,4-trichlorophenol, 2,3,5-trichlorophenol, 2,3,6-trichlorophenol, thiofanox, and 4-aminopyridine. Due to the time restraints of this project, a matrix spike for fuel oils No.4 and No. 6 was not prepared and analyzed.

# 2 - 13

2.4 High Pressure Liquid Chromatography (HPLC)

2.4.1 Method Summary

Amethod for analyzing fuel oils was developed modeling similar HPLC methods such as SW846, Method 8310 as closely as possible. A modified TCLP type extraction was performed and a diode array HPLC detector was used to measure analyte concentration.

2.4.2 Sample Preparation

Fuel oils were extracted with a Toxicity Characteristic Leaching Procedure (TCLP) extraction fluid by adding equal volumes of gasoline or No. 2 fuel oil with the TCLP fluid in a 22 ml vial. No.
4 and 6 fuel oils were first diluted 10:1 with hexane due to their viscous properties which allowed thorough mixing of sample and extraction fluid. The 22 ml vial was sealed and agitated on a TCLP
extraction apparatus for a minimum of 12 hours. Additional cleanup of the TCLP extract was not required.

2.4.3 Instrumental Analysis

A 10 microliter aliquot of extraction fluid was analyzed by HPLC using a 25 cm x 4.6 mm, 5
micron particle, reverse phase ABZ+Plus column. A diode array detector was used to measure analyte concentration.

2.4.4 Quality Control

Method 8310 was followed as closely as the sample matrix would allow. See Table 2-2 for
additional information regarding specific procedures utilized on this project. A method blank was analyzed for each matrix. Section 2.14 of this report presents a discussion of surrogate spiking compound results for each sample and matrix spike as well as laboratory control sample (LCS) results for each analysis type. The QC results for surrogates are in Appendix D. The following specific
criteria were utilized.

# 2 - 14 Internal standards were not used. External calibration procedures were used to measure analyte concentration.

Acetophenone was used as a surrogate to evaluate extraction performance. The surrogate was added to the 22 ml vial just prior to the agitation process. Surrogate was added to produce a concentration of 20 mg/kg on-column.

A five-point calibration curve was analyzed for quantitation of analytes. However, since documentation on the behavior of these analytes could not be found, arbitrary limits on the correlation coefficients of the analytes were not set. Instead, the curves were analyzed
and processed to the best ability of the analyst. This data should be used as a first attempt in determining acceptable calibration curve limits.

A QC check was analyzed at least every twelve hours during sample analysis. An arbitrary limit of +/- 30% recovery for each analyte was adopted for the QC check. The acceptance limit may be reduced when more data about the behavior of these analytes is
collected and evaluated.

No recovery limits for surrogate recovery were arbitrarily set. However, the recovery had to be at least to the compound's detection limit.

2.4.5 Analytical Difficulties and Recommendations

Since each fraction was prepared and analyzed separately, the spiking concentrations ranged from 20 ppm in the gasoline to 100 ppm in the fuel oils. While the gasoline spikes showed recovery for all analytes, some of the recoveries were close to the lower calibration limit. For this reason, subsequent spiking concentrations were increased.

The analytes spiked into the fuels are not readily soluble in a non-polar matrix. For this reason, the spiking solutions were prepared in methanol to get them into a liquid matrix and the methanol
solution was added to the extraction vessel with sample and extraction fluid. Under these conditions,

# 2 - 15

the spiked compounds probably did not dissolve into the fuel oils matrix prior to extraction and therefore, the generated data may only provide very limited information.

Not all spiked compounds recovered ideally. In gasoline, thioacetamide only recovered at 10% and the diamines at about 50%. MNNG and ethylene thiourea were at nearly 200% recovery even though these compounds were not detected in the unspiked sample. Only thioacetamide recovered unusually in No. 2 fuel oil at nearly 300% with no detection of this compound in the unspiked sample. Thioacetamide also recovered high in the No. 6 fuel oil. Additionally, neither MNNG nor ethylene thiourea was detected in the matrix spike of No. 6 fuel oil.

The following are offered as suggestions for possible future studies. Due to the time constraints for this project, these possibilities were not tested. Different analytical columns may improve analyte recovery and chromatographic quality. Also, a much larger range of analytes may be analyzed by HPLC with different columns.

A better way of spiking fuel oils with polar analytes may be possible. However, these procedures may have to be researched and tested on a compound-by-compound basis. Entire classes of analytes were attempted for this project to analyze the largest number of analytes possible. In
addition , other extraction techniques such as solid phase extraction may improve recovery and increase the number of analytes seen by HPLC.

2.5 Dioxins and Dibenzofurans

2.5.1 Method Summary

Due to the large number of individual isomers, analyte toxicity, and the high cost of standards,
the dioxins (PCDD) and dibenzofurans (PCDF) were not analyzed by a published method, but as follows.

A standard was procured and calibrated for one select isomer of each group. For example,
there are seven (7) isomers of tetrachlorodibenzo-p-dioxins, but only 2,3,7,8-PCDD was analyzed.

# 2 - 16

The remaining isomers were searched for as 2,3,7,8-PCDD. The following listing provides specific isomer information.

Tetrachlorodibenzo-p-dioxins (Searched as 2,3,7,8-PCDD)

2,3,7,8-PCDD 1,2,3,4-PCDD 1,3,6,8-PCDD 1,3,7,9-PCDD 1,3,7,8-PCDD 1,2,7,8-PCDD 1,2,8,9-PCDD 

# Pentachlorodibenzo-p-dioxins (Searched as 1,2,3,7,8-PCDD)

1,2,3,7,8-PCDD 1,2,3,4,7-PCDD 

# Hexachlorodibenzo-p-dioxin (Searched as 1,2,3,6,7,8-PCDD)

1,2,3,4,7,8-PCDD 1,2,3,6,7,8-PCDD 1,2,3,7,8,9-PCDD 

# 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin (only hepta isomer)
Octachlorodibenzo-p-dioxin (only octa isomer)

Tetrachlorodibenzofurans (Searched as 2,3,7,8-PCDF)

2,3,7,8-PCDF 1,2,3,4-PCDF 1,3,6,8-PCDF 1,3,7,9-PCDF 1,3,7,8-PCDF 1,2,7,8-PCDF 1,2,8,9-PCDF



# Pentachlorodibenzofurans (Searched as 1,2,3,7,8-PCDF)

1,2,3,7,8-PCDF 1,2,3,4,7-PCDF



# Hexachlorodibenzofurans (Searched as 1,2,3,6,7,8-PCDF)

1,2,3,4,7,8-PCDF 1,2,3,6,7,8-PCDF 1,2,3,7,8,9-PCDF 

# 1,2,3,4,6,7,8-Heptachlorodibenzofuran (only hepta isomer)

Octachlorodibenzofuran (only octa isomer)

A curve was not analyzed for these compounds. Instead, a one-point calibration was run after each 12- hour DFTPP tune. The analytical instrument was calibrated to look for PCDDs and PCDFs

# 2 - 17

in samples in a present or not present mode rather than a quantitative mode.

2.5.2 Sample Preparation

For gasoline, PCDDs and PCDFs were searched concurrently with the semi-volatile analyses. See the semi-volatile sample preparation for details.

For the No. 2, 4, and 6 fuel oil samples, the GPC extracts could not be used for PCDD and PCDF analysis. The No. 2 fuel oil spiked with these compounds had no recovery. It was assumed that the GPC process removed these analytes from the spike.

Instead, No. 2 fuel oil was spiked with PCDDs and PCDFs in a 10:1 dilution then cleaned up
with sulfuric acid. The remaining organic layer was analyzed with no further dilution. To minimize

waste product with PCDDs and PCDFs, only No. 2 fuel oil was spiked. The remaining unspiked fuel oils were prepared in the same way prior to analysis.

2.5.3 Instrumental Analysis

See the semi-volatile instrumental analysis for details.

2.5.4 Quality Control

A method blank was analyzed for each matrix.

2.5.5 Analytical Difficulties and Recommendations

The sample clean-up used for this analysis effectively removed most of the hydrocarbon background. If this clean-up procedure was used with SIM mode mass spectrometry or high
resolution mass spectrometry, much lower detection limits may be possible for PCDDs and PCDFs.

Also, calibration for each isomer in a five-point curve is possible. However, the cost of the

# 2 - 18

standards and waste disposal would be significant.

2.6 Herbicides

2.6.1 Method Summary

SW-846, Method 8150 was followed for the on-instrument analysis and Method 3580 (Waste Dilution) was used in the initial sample preparation.

2.6.2 Sample Preparation

Samples were prepared in hexane as per Method 3580. A 1.0 ml aliquot was taken from the
3580 fraction, added to 0.2 ml methanol and brought to a volume of 5.0 ml with diethyl ether. Samples were then derivitized by the diazomethane bubbler procedure as per Method 8150. Samples were then analyzed by gas chromatography.

2.6.3 Instrumental Analysis

Instrumental analysis was conducted by injecting one (1) μl of extract on dual capillary columns equipped with electron capture detectors (ECD). The capillary columns employed were a DB-608
and a DB-1701.

2.6.4 Quality Control

A five-point external standard calibration procedure was used, with a 12-hour window for valid sample analyses. 2,4-Dichlorophenylacetic acid was used as a surrogate. No limits for surrogate recovery were set. A method blank was analyzed for each matrix.

2.6.5 Analytical Difficulties and Recommendations

The hydrocarbon matrix did not seem to cause interference in the derivitization of the acid

# 2 - 19

herbicides.

2.7 Metals

2.7.1 Method Summary

EPA SW-846, Method 3040 was used for the preparation of all samples in this study. The method is a dissolution procedure. All dissolved samples were then analyzed by the appropriate SW846 flame method, with the exception of arsenic and selenium, where the appropriate graphite furnace atomic absorption method was used. Mercury was analyzed by cold vapor atomic absorption.

2.7.2 Sample Preparation

All samples were prepared using EPA SW-846, Method 3040. All of the samples were diluted 1:10 with xylene. Final results were reported as mg/kg from the original weight.

2.7.3 Instrumental Analysis

Diluted samples were analyzed by the appropriate flame atomic absorption methodology, with the exception of arsenic and selenium, where the graphite furnace atomic absorption was chosen, and
mercury, which was analyzed by cold vapor atomic absorption. The analysis of all of the diluted samples proceeded normally.

2.7.4 Quality Control

In general, a blank and three standards were used to perform initial calibration. Correlation
coeffici ents were calculated for each curve, a QC check sample was analyzed after each curve, with the exception of osmium. An initial calibration verification and an initial blank verification were then performed. After every ten samples or between matrices, a calibration verification and a blank verification were performed. A duplicate sample and a matrix spike were performed on each matrix along with a method blank.

# 2 - 20

For each metal analyte, a standard curve was performed. In all cases, the source for the stock standard was SPEX. The QC check sample was obtained from Conostan. All curves were linear and

most correlation coefficients were better than 0.995. At the beginning and during each run, standard
calibration checks and blank calibration checks were performed. All initial and continuing calibration blanks were less than the established PQL. All initial and continuing calibration verification results

were between 90-110% with the following exceptions: Lead stayed at about 111% for the duration of the run and did not deviate more than 1-2%; and arsenic was variable, although most of the values were 90-110%. Due to its volatile nature, the osmium results were 80-120%.

Sample matrix QC consisted of preparing and analyzing one duplicate and spike for each matrix.
For values significantly above the PQL, the results for relative percent differences were less than 20%. The No. 4 fuel oil’s selenium result at the PQL showed some variability in the duplicate result. This may be due to the matrix. Most of the spike results were very good and fell within the 75-125%
limit with the following exceptions: The barium spike for the No. 6 fuel oil returned a value of 72%. This could be attributed to the matrix; the silver spike results were unusual in that they were all high.
This may be due to some stabilizing effect in the fuel versus xylene solvent; all selenium results were good, except for the No. 4 fuel oil mentioned above. Spike results for mercury were exceptional,
relative to the method used. This round of results gave 36-47% recovery for mercury spike across the matrices.

2.7.5 Analytical Difficulties and Recommendations

The analysis of all of the diluted samples proceeded normally. Most of the spike results were
very good and fell within the 75-125% recovery limit with the following exceptions. Osmium in the gasoline matrix was 59% and tin in the No. 4 and 6 fuel oil was low. While it is unknown why the osmium result was so low, the tin results could be attributed to the matrix.

The mercury method is not as well suited to the matrices encountered in this study. The spike results were the best that could be obtained under these conditions. In the time allowed, we could not find a second standard source for thallium and manganese. Silver displayed some unusual variability in the results for the QC check and the spike. Silver may be more susceptible to certain

# 2 - 21

kinds of matrix enhancements that were not well documented. The furnace methods used to analyze arsenic and selenium needed some extra effort to set up properly, although once the furnace method was set, the results were very good.

2.8 Pesticides and PCBs

2.8.1 Method Summary

SW-846, Method 8080 was followed for the on-instrument analysis and Method 3580 (Waste Dilution) was used in the initial sample preparation. Method 3665 (sulfuric acid) was used to cleanup the samples prior to analysis for the Aroclor PCBs. No clean-up procedure was used for preparation of the extracts for pesticide analysis.

2.8.2 Sample Preparation

The samples were prepared using Method 3580. One (1) gram of sample was diluted to 10 mls.
with Hexane.

2.8.3 Instrumental Analysis

Instrumental analysis was conducted by injecting one (1) μl of extract on dual capillary columns equipped with electron capture detectors (ECD). The capillary columns employed were a DB-608
and a DB-1701.

2.8.4 Quality Control

A method blank was analyzed for each matrix and an Endrin/DDT standard was analyzed prior to calibration and sample analysis, to ensure a <20% breakdown of the pesticides.

A five-point initial external calibration containing each single-response pesticide generated prior

to sample analysis. A single-point external calibration standard was analyzed for all multi- response

# 2 - 22

pesticides and PCBs for qualitative identification. A five-point initial external calibration curve was generated for one of the multi-response compounds (Aroclor 1260), for quantitative analysis.

Two surrogates, dibutylchlorendate and tetrachloro-m-xylene were used to monitor the integrity
of the sample preparation and analytical system. The surrogates were added to produce a concentration of 10 μg/kg on-column. No limits were set for surrogate recovery, however, both surrogates were required to be present to validate each analysis.

2.8.5 Analytical Difficulties and Recommendations

The higher molecular weight components of the fuel oils No. 4 and No. 6 caused some interference with the analyses. The primary problem was difficulty eluting these heavy compounds
from the GC column. This problem was absent from samples for PCB analysis that underwent Method 3665 clean-up. Perhaps a clean-up method suitable for pesticides, such as alumina or florisil column clean-up or Gel-permeation clean-up would produce better results.

2.9 Heating Value

2.9.1 Method Summary

Heat of combustion was determined using ASTM Standard D 240. In this test method, heat of combustion was determined by combusting a weighed sample in an Oxygen Bomb Calorimeter
under controlled conditions. The rate of combustion was computed from temperature readings before and after combustion.

2.9.2 Quality Control

QC procedures consisted of one duplicate determination per every ten (10) samples and an analysis of a certified standard benzoic acid pellet per every ten (10) samples. Method precision and reproducibility were within the ranges specified in the method. Gross heat of combustion was

re ported. No adjustments were made for the heat of combustion of nitrogen and sulfur in the sample.

# 2 - 23

Values were reported as Btu/lb rather than in the SI units of MJ/kg, as stated in the method.

2.10 Specific Gravity

2.10.1 Method Summary

Specific gravity was determined by using ASTM Standard D 1298. This method uses a hydrometer to determine specific gravity after the sample and apparatus were brought to a stable temperature of 60°F. The appropriate hydrometer was lowered into the sample cylinder and allowed

to settle. At positional equilibrium, the hydrometer was read and the temperature of the sample
noted.

2.10.2 Quality Control

The hydrometers used were calibrated in accordance with National Institute of Standards and Technology (NIST) Circular 555, and ASTM specification E 100. All sample temperatures were brought to 60°F for a period of five (5) hours prior to hydrometer readings. Duplicate determinations were performed per every ten (10) samples. All duplicates were within 5% RSD.

2.10.3 Analytical Difficulties and Recommendations

All specific gravity readings were made at 60°C as per ASTM D 1298. Highly viscous opaque samples presented problems in the accurate readings of the hydrometer. Air bubbles trapped in the more viscous samples may have had a minor influence on the reported results.

2.11 Flash Point

2.11.1 Method Summary

Flash point was determined by EPA SW-846, Method 1010, which is similar to ASTM Standard D 93, using a Pensky-Martens closed-cup Flash Tester. The sample was heated at a slow constant

# 2 - 24

rate with continual stirring. A small flame was directed into the cup at regular intervals with simultaneous interruption of stirring. The flash point was the lowest temperature at which application of the test flame ignited the vapor above the sample.

2.11.2 Quality Control

Duplicate determinations were made on each of the ten (10) samples. All duplicates were within 2°C of the original result. Gasoline flash points were below the range attainable by the PenskyMartens Method. These values were reported as less than 0°C.

2.12 Total Halogens

2.12.1 Method Summary

EPA Method 325.3/PARR and ASTM Standard D 4929 were used to analyze the samples for total halogens. The sample was ignited in a PARR bomb as part of the determination of gross heat
of combustion. After combustion of two previously weighed samples, the resulting inorganic residue solution was washed from the inside surfaces of the PARR bomb. The wash water was brought to

a total volume of 10 milliliters and titrated per EPA Method 325.3. Bromine, chlorine, and iodine

are all reported as total chloride. Fluorine does not react with the titrant of EPA Method 325.3 and is not included in the reported values.

2.12.2 Quality Control

In the PARR bomb combustion process, a weighed sample is placed in the PARR bomb under
35 atmospheres of oxygen, approximately 515 psi. Combustion is rapid and complete with no traces
of organic material remaining in the bomb. In order to assure the conversion of organic halide to inorganic halogen ion, samples were spiked with known amounts of methylene chloride prior to
combustion in the bomb. Recovery of spiked halogen was in the range of 87% to 92% for all gasoline and No. 2 fuel oil samples. For Nos. 4 and 6 fuel oil samples, recovery was in the range of 20% to 45%, which was unacceptable. It is probable that the higher nitrogen content of the Nos. 4

# 2 - 25

and 6 fuel oils resulted in the production of significant amounts of nitric acid during the PARR bomb combustion process. The nitric acid resulted in unacceptably high levels of ferric and chromate ions
from the reaction with the stainless steel PARR bomb. Ferric and chromate ions are an interferant in the EPA Method 325.3 titration process.

2.12.3 Analytical Difficulties and Recommendations

In order to obtain reliable halogen values for the Nos. 4 and 6 fuel oils, these samples were analyzed by ASTM Standard D 4929, a method for determining the organic chloride content in crude

o il. This method lists a rinse step to remove inorganic halides from the petroleum product. This step

was omitted so that a total halide value would be determined for these samples. The method involves oxidation of a known weight sample in an oxygen stream at 800 C. The oxygen stream was then led

to a microcoulometric cell, where the halide ions react with coulometrically-generated silver ion. The microequivalents of silver ion consumed in the titration was equal to the microequivalents of titratable
halide ion in the oxidized sample. Bromine and iodine titrate as chloride equivalents. Fluorine does not respond and is not included.

In the oxygen combustion process, approximately 50% of the bromine and iodine form oxyhalides (HOBr and HOI) which do not react in the titration. Bromine and iodine, therefore, provi de an approximate 50% response factor. Calibration curves, replicate analyses, and checks using 2,4,6 trichlorophenol were performed on the sample daily.

2.13 Total Nitrogen

2.13.1 Method Summary

ASTM Standard D 4629 was used to analyze the samples for total nitrogen. The sample of liquid petroleum hydrocarbon was injected into a stream of inert gas. The sample was vaporized and
carried to a high temperature zone where oxygen was introduced converting organic bound nitrogen nitric oxide (NO). The NO contacts ozone and emits light, through a process of chemiluminescence, which was detected by a photo multiplier as a measure of the nitrogen contained in the sample.

# 2 - 26

2.13.2 Quality Control

The instrument was calibrated using nitrogen standards of pyridine or carbazole. Pyridine is used for samples with mid-range boiling points less than 430 F. Carbazole was used for samples of higher boiling ranges. Method blanks were performed using toluene for gasoline samples and cetane for the higher boiling No. 2, 4, and 6 fuel oil samples.

Reprod ucibility values were within the specifications stated in ASTM Standard D 4629. All samples were run as replicate analyses. A calibration curve and a known check sample were run daily.

2.14 General Matrix Spike and Laboratory Control Sample Recovery

Every sample, blank, matrix spiked samples, and laboratory control samples were spiked with surrogate spiking compounds prior to the sample preparation. Recovery criteria for petroleum products is not established in the methodology. Therefore, acceptance limits were not used by the laboratory as a means of rejecting an analysis.

Matrix spikes and LCS samples were analyzed concurrently with the fuel oil samples. Due to the unknown analytical characteristics of the analytes in fuel oil and the unknown affect the sample preparation procedures may have had on these quality control samples, acceptance limits were not used by the laboratory as a means of rejecting an analysis. These data should be viewed as a first attempt to set acceptance limit criteria. Overall the recoveries calculated from the MDL study, which also represents some of the spike results, meet the method criteria except were it has been noted in
the individual method discussions in this section.

Table 2-2 lists the specific procedures utilized for matrix spiking and the laboratory control sample s. It is recommended that the description associated with each analytical fraction be reviewed
for additional details.

# 2 - 27

2.15 Analysis for Total Aromatic Hydrocarbons and Total Polynuclear Aromatic Hydrocarbons

The analysis for total aromatic hydrocarbons and total polynuclear aromatic hydrocarbons yielded results much lower than expected. A small number of specific analytes in these categories

were analyzed and summed into totals. There were numerous analytes and isomers that should have been included in this total, but due to the huge number of compounds, they could not be individually
calibrated and quantitated. The majority of these compounds are not listed in Appendix VIII and do not have validated methods for analysis. Other methods more suited to this type of analysis, other
than identification and quantitation of individual compounds, should be considered for these total numbers.

# 3-1

3.0 RESULTS

3.1 Laboratory Results

Appendix A lists the laboratory results for the semi-volatile, volatile, metals, inorganic parameters, physical parameters, and total aromatic hydrocarbons. These results were submitted to
SAIC for statistical analysis which are presented in Appendix B. Appendix C lists the laboratory
derived Method Detection Limit (MDL) Study results for each analyte. Appendix D lists the QA data results. The QA data includes surrogate spiking compound recovery for semi-volatile and volatile
methods and duplicate and spike recoveries for metals. As stated in Section 2, the results for polynuclear aromatic hydrocarbons and total aromatic hydrocarbons are much lower than expected.
The method used to generate these concentrations was to sum the results of the semi-volatile analysis. The constituents listed in 40 CFR, Part 261, Appendix VIII that could be quantitated only included a small number of the aromatic hydrocarbons which are normally present in fossil fuels.

3.2 Constituents Levels

Appendix B lists the comparable fuel constituent specifications for the final rule. The comparable fuels consist of four fuel types – gasoline and Nos. 2, 4, 6 fuel oils. The available data contain chemical compound concentrations from eight (8) samples from gasoline, 11 samples from No. 2 fuel oil, one (1) sample from No. 4 fuel oil and seven (7) samples from No. 6 fuel oil. The final constituent levels were calculated using the composite at the largest value.

For chemical in which at least one sample was measured above the minimum level of detection, the composite was based on the measured concentrations from the detected samples and

on the quantitation limits from the non-detect samples. The composite values are presented in the table under the column heading “Concentration Limit.” For chemicals in which none of the samples were measured above the minimum level of detection, the composite value was based on the reported quantitation limits and are presented in the table under the column heading “Minimum Required

# 3-2

Detection Limit.” However, the final rule allows metals, hydrocarbons, and oxygenates to be present

at any concentration less than or equal to the detection limits. For these compounds, all composite
value are reported as a concentration limit, using the reported quantitation limits as concentration limit in the case where none of the samples were measured above the minimum detection limit.

For constituents with at least one detected sample, concentration limits have been corrected
from the fuel’s heating value to 10,000 BTU/lb. For constituents with no detected samples, the concentration limits (in the case of metals, hydrocarbons, or oxygenates) or minimum required detection limits are not corrected to 10,000 BTU/lb.

3.3 Estimates from Additional Halogen Data

Additional analysis was performed to calculate the highest value composite for total halogens. Because the analysis for No. 4 and No. 6 fuel oils was based on analytical methods measuring only
total organic and inorganic halogens, additional data was gathered from EPA’s database (i.e., Certificates of Compliance required by the BIF rule) and data submitted by one commenter. The
additional Total Chlorine data is presented in Table 3-1. The total halogen value has been normalized for the fuel’s heating value to 10,000 BTU/lb. This additional data was composited with the gasoline and No.2 fuel oil data contained in this report.

3.4 Statistical Analysis Results (SAIC) (Proposal)

This section presents the results from statistical analyses, performed by Science Applications International Corporation (SAIC), of chemical compound concentrations measured in comparable
fuels for the proposed rule. As discussed previously, the comparable fuels consist of four fuel types

—gasoline and Nos. 2, 4, and 6 fuel oils. Statistical analyses also were conducted on two (2)
combinations of these fuel types: a composite of the three (3) fuel oils (Composite 246); and a composite of all four (4) fuel types. The available data contain chemical compound concentrations
from eight (8) samples from gasoline, 11 samples from No. 2 fuel oil, one (1) sample from No. 4 fuel

# 3-3

oil, and seven (7) samples from No. 6 fuel oil.

This statistical analyses estimated percentiles from the distribution of concentrations of each chemical compound within each fuel type. For each individual fuel type, the 90th percentile was

e stimated for every chemical compound. For the composite fuel types, estimates of the 50th and 90th percentiles were calculated for each chemical compound. Section 3.4.1 of this report presents the
statistical analysis of the individual fuel types. Section 3.4.2 documents the statistical methodology for estimating percentiles from the composite of Nos. 2, 4, and 6 fuel oils. The analysis of the composite of all four fuel types is presented in Section 3.4.3.

The results from the statistical analyses of these fuel types are presented in Appendix C in the following tables:

• Table 1: Estimated 90th percentiles from gasoline;

• Table 2: Estimated 90th percentiles from No. 2 fuel oil;

• Table 3: Estimated 90th percentiles from No. 4 fuel oil;

• Table 4: Estimated 90th percentiles from No. 6 fuel oil;

• Table 5: Estimated 50th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 6: Estimated 90th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 7: Estimated 50th percentiles from the composite of all four fuel types;

• Table 8: Estimated 90th percentiles from the composite of all four fuel types; and

As stated earlier, the samples were analyzed in two rounds based on the availability of clearly defined analytical protocols. For the additional compounds that were found during the second round
of analyses the following tables, in Appendix C, represent the results from the statistical analyses of these fuel types. The methodology and discussion of the analysis conducted on the original set of data still applies to the information displayed in these tables as well.

# 3-4

• Table 1A: Estimated 90th percentiles from gasoline;

• Table 2A: Estimated 90th percentiles from No. 2 fuel oil;

• Table 3A: Estimated 90th percentiles from No. 4 fuel oil;

• Table 4A: Estimated 90th percentiles from No. 6 fuel oil;

• Table 5A: Estimated 50th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 6A: Estimated 90th percentiles from the composite of Nos. 2, 4, and 6 fuel oils;

• Table 7A: Estimated 50th percentiles from the composite of all four fuel types;

• Table 8A: Estimated 90th percentiles from the composite of all four fuel types; and

Wit hin each table, two (2) sets of estimates are presented. For chemicals in which at least one (1) sample was measured above the minimum level of detection, the estimated percentiles were based

on the measured concentrations from the detected samples and on the quantitation limits from the
non-detect samples. These estimates are presented in the tables under the column heading "Concentration Limit." For chemicals in which none of the samples were measured above the
minimum level of detection, the estimated percentiles were based on the reported quantitation limits and are presented in the tables under the column heading "Minimum Detection Limit."

All chemical concentrations were originally reported in the database with units equal to mg/kg. For the chemicals with at least one (1) detected sample, these concentrations were converted to mg/J using the reported heating values (Btu/lb) and the following conversion formula:

Concentration mg

J Concentration mg kg

2326

. 11 ( lb

kg ) ( J BTU ) Heating Value BTU lb

The estimated percentiles were generated from the mg/J concentrations and were converted
back to mg/kg, for presentation in the tables, based on a heating value of 10,000 Btu/lb. For the

# 3-5

chemicals with no detected samples, the percentiles were calculated from reported quantitation limits in the original units of mg/kg. All results are presented with two (2) significant figures.

3.4.1 Estimates for Each Individual Fuel

Estimated percentiles for the chemical compounds from each individual fuel type (i.e., gasoline
and Nos. 2, 4, and 6 fuel oils) are presented in Appendix B, Tables 1 through 4 and Tables 1A through 4A, respectively. Only the chemicals that are contained in the 40 CFR, Part 261, Appendix
VIII list are presented in these tables. Each of these tables presents the estimated 90th percentile for chemicals with at least one (1) detected concentration and undetected chemicals above the quantitation limit. The percentile estimates from the detected chemicals are presented under the column heading "Concentration Limit," and the percentiles for the non-detected (non-detect) chemicals are presented under the column heading "Minimum Detection Limit." For the chemicals with at least one (1) detected sample, the percentile estimates were based on the measured value for
the detected samples and on the reported quantitation limits for the non-detect samples. For the chemicals with no samples measured above the minimum level of detection, the percentile estimates were based on the reported quantitation limits.

When calculating the quantitation limit for volatile organic compounds (VOCs) in gasoline,
in the analytical methods, there are matrix interferences that cause the calculated quantitation limits to be unreliable. Therefore, for the VOCs that were not detected in any of the gasoline samples, the estimated 90th percentile is not presented in Appendix B, Table 1. For these chemicals, the 90th percentile estimate from the composite of the Nos. 2, 4, and 6 fuel oils is presented in Appendix C, Table 1 as a surrogate for the 90th percentile for gasoline.

The estimated percentiles presented in Appendix C, Tables 1 through 4 and Tables 1A through 4A, were generated nonparametrically. That is, the percentiles are based on the rank order statistics of the sample concentrations. Distributional assumptions were not used in the calculation
of the percentile estimates because of the sparse sample sizes. For gasoline, at least one of the eight

# 3-6

(8) samples was measured above the minimum level of detection for only nine (9) of the 151 chemical compounds found in 40 CFR Part 261 Appendix VIII. For No. 2 fuel oil, at least one (1) of the 11 samples was measured above the minimum level of detection for only 11 of the 151 chemicals. Only

one (1) sample was measured for each chemical compound from No. 4 fuel oil, and only 13 of the
chemical compounds were measured above the minimum level of detection in this sample. For No.
6 fuel oil, at least one (1) of the seven (7) samples was measured above of the minimum level of detection for only 16 of the chemicals.

All of the chemicals originally were reported in units of mg/kg. The 90th percentile estimates for non-detect chemicals, under the column heading "Minimum Detection Limit," are presented in the original units of mg/kg. The percentile estimates for chemicals with at least one (1) detected sample, under the column heading "Concentration Limit," were calculated from concentrations that were
converted from mg/kg to mg/J based on the report heating values (Btu/lb) for each sample. Then, the percentile estimates were converted from mg/J back to mg/kg based on 10,000 Btu/lb.

The nonparametric procedure for calculating the percentile estimates was based on standard procedures, namely PROC UNIVARIATE (Def. 5), in the SAS statistical software package. This standard nonparametric procedure is outlined in the following steps.

1. Let x 1 

# , x 2 

# , x 3 

# , ..., x n 

# represent the chemical concentrations from the n-samples, ranked from lowest to highest, where n equals the total number of samples.

2. To calculate the 90th percentile, let 0.90*n = j + g, where j is the integer part of 0.90*n and g is the fractional part of 0.90*n.

3. The estimated 90th percentile is calculated as:

(xj + xj+1)/2, if g = 0; and (xj + 1), if g > 0.

# 3-7

Example: In No. 6 fuel oil, data were available from seven (7) samples. Therefore, n=7 and 0.90*n=6.3. The integer part (j) is equal to 6, and the fractional part (g) is equal to 3/10. Because the fractional part (g) is not equal to zero, the 90th percentile is equal to the interpolated values of the concentrations between the 6th and 7th samples. That is, the 90th percentile is the average of the largest concentration and the second largest concentration.



# The estimated percentiles from this methodology are presented under the column heading "Concentration Limit" in Appendix C, Tables 1 through 4.

3.4.2 Estimates from Composite 246

In addition to the percentile estimates from each individual fuel type, percentile estimates are presented for a combination of Nos. 2, 4, and 6 fuel oils. This combination of fuel oils is labeled "Composite 246." The estimated percentiles presented under combination of fuel oils are weighted estimates from the chemical concentrations from the three (3) fuel oils. Estimates were generated
from all reported samples of these fuel oils, using the measured concentrations from the detect samples and the reported quantitation limits from the non-detect samples.

Appendix C, Table 5 presents estimated 50th percentiles from the composite of Nos. 2, 4, and
6 fuel oils. Estimated 90th percentiles are presented in Appendix C, Table 6. For chemicals with at least one (1) detected concentration, the percentile estimates are presented under the heading
"Concentration Limit". The percentile estimates for the chemicals with no detected concentrations are presented under the heading "Minimum Detection Limit."

The estimated percentiles were generated by weighting each sample according to the number
of samples available from each fuel type. This adjustment provides equal contribution from each sample to the composite estimate. That is, each fuel type should represent one-third of the population. Therefore, each sample from No. 2 fuel oil, which contained 11 samples, was assigned

# 3-8

a weight of 1/33; the sample from No. 4 fuel oil was assigned a weight of 1/3; and each sample from
No. 6 fuel oil, which contained seven (7) samples, was assigned a weight of 1/21. The chemical
concentrations were then ranked from lowest to highest and the weights were summed across samples until the total weight was equal to 0.50. The corresponding chemical concentration was used as the
estimated 50th percentile. That is, the 50th percentile is the concentration corresponding to the ranked sample for which 50% of the weights were accounted. If the sum of the weights does not equal 0.50 exactly, then the 50th percentile is the interpolated value of the two (2) reported concentrations surrounding the 50th percentile point. Similarly, the 90th percentile was estimated by the corresponding concentration when the sum of the weights was equal to 0.90.

As in the calculation of the percentiles for each individual fuel type, the percentiles for the dete cted chemicals are presented in units of mg/kg at 10,000 Btu/lb, and the percentiles for the nondetect chemicals are presented in the original units of mg/kg. All of the chemicals originally were reported in the database with units of mg/kg. The percentile estimates for chemicals with at least one (1) detected sample, under the column heading "Concentration Limit," were calculated from concentrations converted from mg/kg to mg/J, based on the reported heating values (Btu/lb) for each sample. The percentile estimates then were converted from mg/J back to mg/kg based on 10,000 Btu/lb. For the chemicals with no samples measured above the minimum level of detection, the percentile estimates were based on the reported quantitation limits in the original units of mg/kg.

3.4.3 Estimates from Composite of All Fuel Types

Appendix C, Tables 7, 7A, 8, and 8A present percentile estimates for a combination of all four (4) fuel types (i.e., gasoline and Nos. 2, 4, and 6 fuel oils), labeled "Composite All." The estimated percentiles presented under this combination of fuel types are weighted estimates from the chemical concentrations from the four fuel types. Estimates were generated from all reported samples of these
fue l types, using the measured concentrations from the detected analytes in the samples and the reported quantitation limits from the non-detect analytes in the samples.

# 3-9

Appendix C, Table 7 and Table 7A presents estimated 50th percentiles from the composite of all fuel types. Estimated 90th percentiles are presented in Appendix C, Table 8, and Table 8A.
For chemicals with at least one (1) detected concentration, the percentile estimates are presented under the heading "Concentration Limit." The percentile estimates for the chemicals with no detected concentrations are presented under the heading "Minimum Detection Limit."

The estimated percentiles were generated by weighing each sample according to the number of samples available from each fuel type, so that each fuel type provided equal contribution to the
estimated percentiles. That is, each fuel type should represent one-quarter of the population. Therefore, the samples from gasoline and Nos. 2, 4, and 6 fuel oils were assigned weights of 1/32, 1/44, 1/4, and 1/28, respectively, based on the number of samples from each fuel type. The chemical concentrations were then ranked from lowest to highest, and the weights were summed across samples until the total weight was equal to 0.50. The corresponding chemical concentration was used as the estimated 50th percentile. That is, the 50th percentile is the concentration corresponding to
the ranked sample for which 50% of the weights were accounted. If the sum of the weights does not equal 0.50 exactly, then the 50th percentile is an average of the two (2) reported concentrations that
surround the 50th percentile point. Similarly, the 90th percentiles were estimated by the corresponding concentration when the sum of the weights was equal to 0.90.

In the analytical methods for calculating the quantitation limit for VOCs in gasoline, there are
matrix interferences that cause the calculated quantitation limits to be unreliable. Therefore, for the
VOCs not detected in any of the gasoline samples, the estimated percentiles for the composite of all
fuel types, which includes gasoline, were not presented. For these chemicals, the estimates from the composite of the Nos. 2, 4, and 6 fuel oils (i.e., without gasoline) are presented in Appendix C,
Tables 5, 5A, 6, and 6A as surrogates for the percentile estimates from the composite of all four (4) fuel types.

The percentiles for the detected chemicals are presented in units of mg/kg at 10,000 Btu/lb
and the percentiles for the non-detect chemicals are presented in the original units of mg/kg. All of

# 3-10

the chemicals originally were reported in the database with units of mg/kg. The percentile estimates for chemicals with at least one (1) detected sample (i.e., concentration limit) were calculated from
concentrations converted from mg/kg to mg/J, based on the reported heating values (Btu/lb) for each sample. The percentile estimates then were converted from mg/J back to mg/kg based on 10,000
Btu/lb. For the chemicals with no samples measured above the minimum level of detection, the percentile estimates were based on the reported quantitation limits in the original units of mg/kg.

# 3-11

Table 3-1 Chlorine Content of Fuel Oils Used in Hazardous Waste Burning Boilers and Incinerators (as Reported in CoC Test Reports)

Facility Name and Location Fuel Oil No. Cl Content (ppm w 

# ) Ind. Measurements No. Of Measur. Measurement

Method Comments

Amer. Cyan., Kalamazoo, MI 6 < 45 1 ASTM D3120 Sulfur method, not used 

# Huntsman Poly., Woodbury, NJ 6 < 100 6 SW-846 9020 Organic chlorine, not used 

# Rohm and Haas, Phil., PA 6 108, 110, 171 3 ASTM D 808/D 4327 Below method DL 

# Rohm and Haas, Bristol, PA 6 180 1 ASTM D 808/D 4327 Below method DL


# Rohm and Haas 6 590, 660, 1000 3 EPA 9020 Below/near method DL


# Rohm and Haas 6 840, 840 3 EPA 9020 Dow Chem., Gales Ferry, CT 2 83, 93, 137 3 ASTM D 808 Below method DL, not used 

# Du Pont, Wilmington, DE 2 16, 429, 461, 470, 490, 523 5 ASTM D 808/D 4327

# Appendix A

Laboratory Data

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 1,2,4,5-Tetrachlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,2,4-Trichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,2-Dichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,3,5-Trinitrobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,3-Dichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,4-Dichlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1,4-Naphthoquinone <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 1-Naphthylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,3,4,6-Tetrachlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4,5-Trichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4,6-Trichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dimethylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dinitrophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,4-Dinitrotoluene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,6-Dichlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2,6-Dinitrotoluene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Acetylaminofluorene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Chloronaphthalene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Chlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Naphthylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Nitroaniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Nitrophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 2-Picoline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 3,3'-Dichlorobenzidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 3-3'-Dimethylbenzidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 3-Methylcholanthrene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4,6-Dinitro-2-methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Aminobiphenyl <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Bromophenyl phenyl ether <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Chloro-3-methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Chloroaniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Methylphenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Nitroaniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 4-Nitrophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 5-Nitro-o-toluidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 7,12-Dimethylbenz[a]anthracene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 

### α , 

### α -Dimethylphenethylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Acetophenone <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Aniline <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Aramite <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90



### Appendix A - SVOC - 1

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 Benzidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[a]anthracene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[a]pyrene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[b]fluoranthene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Benzo[k]fluoranthene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Bis(2-chloroisopropyl)ether <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Butyl benzyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Chlorobenzilate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Chrysene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Di-n-butyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Di-n-octyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Diallate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dibenzo[a,h]anthracene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dibenz[a,j]acridine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Diethyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dimethoate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dimethyl phthalate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Dinoseb <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Diphenylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Disulfoton <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Ethyl methanesulfonate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Famphur <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Fluoranthene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Fluorene <270 U 26.7 <1200 U 117 <200 220 19.8 <99 U 9.90 8835-001 Hexachlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachlorobutadiene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachlorocyclopentadiene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachloroethane <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Hexachlorophene <6700 U 26.7 <29000 U 117 <5000 U 19.8 <2500 U 9.90 8835-001 Hexachloropropene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Indeno(1,2,3-c,d)pyrene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Isodrin <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Isosafrole <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Kepone <530 U 26.7 <2300 U 117 <400 U 19.8 <200 U 9.90 8835-001 Methapyrilene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Methyl parathion <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Methyl methanesulfonate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitroso-di-n-butylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosodi-n-propylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosodiethylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosomethylethylamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosomorpholine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90



### Appendix A - SVOC - 2

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 N-Nitrosopiperidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 N-Nitrosopyrrolidine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Naphthalene <270 2500 26.7 <1200 2000 117 <200 660 19.8 <99 170 9.90 8835-001 Nitrobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 O,O,O-Triethylphosphorothioate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 o-Toluidine <270 U 26.7 <1200 U 117 <200 U 19.8 <2000 U 9.90 8835-001 p-Dimethylaminoazobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 p-Phenylenediamine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Parathion <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pentachlorobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pentachloronitrobenzene <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pentachlorophenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Phenacetin <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Phenol <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Phorate <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pronamide <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Pyridine <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Safrole <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Sulfotepp <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-001 Thionzin <270 U 26.7 <1200 U 117 <200 U 19.8 <99 U 9.90 8835-002 1,2,4,5-Tetrachlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,2,4-Trichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,2-Dichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,3,5-Trinitrobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,3-Dichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,4-Dichlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1,4-Naphthoquinone <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 1-Naphthylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,3,4,6-Tetrachlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4,5-Trichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4,6-Trichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dimethylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dinitrophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,4-Dinitrotoluene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,6-Dichlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2,6-Dinitrotoluene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Acetylaminofluorene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Chloronaphthalene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Chlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Naphthylamine <270 U 26.6 <1200 U 117 <200 U 19.6



### Appendix A - SVOC - 3

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-002 2-Nitroaniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Nitrophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 2-Picoline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 3,3'-Dichlorobenzidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 3-3'-Dimethylbenzidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 3-Methylcholanthrene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4,6-Dinitro-2-methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Aminobiphenyl <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Bromophenyl phenyl ether <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Chloro-3-methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Chloroaniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Methylphenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Nitroaniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 4-Nitrophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 5-Nitro-o-toluidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 7,12-Dimethylbenz[a]anthracene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 

### α , 

### α -Dimethylphenethylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Acetophenone <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Aniline <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Aramite <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Benzidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Benzo[a]anthracene <270 U 26.6 <1200 U 117 <200 760 19.6 8835-002 Benzo[a]pyrene <270 U 26.6 <1200 U 117 <200 450 19.6 8835-002 Benzo[b]fluoranthene <270 U 26.6 <1200 U 117 <200 210 19.6 8835-002 Benzo[k]fluoranthene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Bis(2-chloroisopropyl)ether <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Butyl benzyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Chlorobenzilate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Chrysene <270 U 26.6 <1200 U 117 <200 700 19.6 8835-002 Di-n-butyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Di-n-octyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Diallate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dibenzo[a,h]anthracene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dibenz[a,j]acridine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Diethyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dimethoate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dimethyl phthalate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Dinoseb <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Diphenylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Disulfoton <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Ethyl methanesulfonate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Famphur <270 U 26.6 <1200 U 117 <200 U 19.6



### Appendix A - SVOC - 4

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-002 Fluoranthene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Fluorene <270 U 26.6 <1200 U 117 <200 220 19.6 8835-002 Hexachlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachlorobutadiene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachlorocyclopentadiene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachloroethane <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Hexachlorophene <6600 U 26.6 <29000 U 117 <4900 U 19.6 8835-002 Hexachloropropene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Indeno(1,2,3-c,d)pyrene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Isodrin <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Isosafrole <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Kepone <530 U 26.6 <2300 U 117 <390 U 19.6 8835-002 Methapyrilene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Methyl parathion <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Methyl methanesulfonate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitroso-di-n-butylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosodi-n-propylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosodiethylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosomethylethylamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosomorpholine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosopiperidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 N-Nitrosopyrrolidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Naphthalene <270 2600 26.6 <1200 2300 117 <200 550 19.6 8835-002 Nitrobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 O,O,O-Triethylphosphorothioate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 o-Toluidine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 p-Dimethylaminoazobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 p-Phenylenediamine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Parathion <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pentachlorobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pentachloronitrobenzene <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pentachlorophenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Phenacetin <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Phenol <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Phorate <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pronamide <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Pyridine <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Safrole <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Sulfotepp <270 U 26.6 <1200 U 117 <200 U 19.6 8835-002 Thionzin <270 U 26.6 <1200 U 117 <200 U 19.6 8835-003 1,2,4,5-Tetrachlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,2,4-Trichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2



### Appendix A - SVOC - 5

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-003 1,2-Dichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,3,5-Trinitrobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,3-Dichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,4-Dichlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1,4-Naphthoquinone <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 1-Naphthylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,3,4,6-Tetrachlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4,5-Trichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4,6-Trichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dimethylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dinitrophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,4-Dinitrotoluene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,6-Dichlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2,6-Dinitrotoluene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Acetylaminofluorene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Chloronaphthalene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Chlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Naphthylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Nitroaniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Nitrophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 2-Picoline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 3,3'-Dichlorobenzidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 3-3'-Dimethylbenzidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 3-Methylcholanthrene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4,6-Dinitro-2-methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Aminobiphenyl <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Bromophenyl phenyl ether <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Chloro-3-methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Chloroaniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Methylphenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Nitroaniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 4-Nitrophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 5-Nitro-o-toluidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 7,12-Dimethylbenz[a]anthracene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 

### α , 

### α -Dimethylphenethylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Acetophenone <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Aniline <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Aramite <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Benzidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Benzo[a]anthracene <670 U 66.8 <590 U 59.4 <190 660 19.2



### Appendix A - SVOC - 6

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-003 Benzo[a]pyrene <670 U 66.8 <590 U 59.4 <190 450 19.2 8835-003 Benzo[b]fluoranthene <670 U 66.8 <590 U 59.4 <190 220 19.2 8835-003 Benzo[k]fluoranthene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Bis(2-chloroisopropyl)ether <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Butyl benzyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Chlorobenzilate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Chrysene <670 U 66.8 <590 U 59.4 <190 740 19.2 8835-003 Di-n-butyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Di-n-octyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Diallate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dibenzo[a,h]anthracene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dibenz[a,j]acridine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Diethyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dimethoate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dimethyl phthalate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Dinoseb <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Diphenylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Disulfoton <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Ethyl methanesulfonate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Famphur <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Fluoranthene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Fluorene <670 U 66.8 <590 U 59.4 <190 210 19.2 8835-003 Hexachlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachlorobutadiene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachlorocyclopentadiene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachloroethane <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Hexachlorophene <17000 U 66.8 <15000 U 59.4 <4800 U 19.2 8835-003 Hexachloropropene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Indeno(1,2,3-c,d)pyrene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Isodrin <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Isosafrole <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Kepone <1300 U 66.8 <1200 U 59.4 <380 U 19.2 8835-003 Methapyrilene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Methyl parathion <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Methyl methanesulfonate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitroso-di-n-butylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosodi-n-propylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosodiethylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosomethylethylamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosomorpholine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosopiperidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 N-Nitrosopyrrolidine <670 U 66.8 <590 U 59.4 <190 U 19.2



### Appendix A - SVOC - 7

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-003 Naphthalene <670 5400 66.8 <590 1300 59.4 <190 550 19.2 8835-003 Nitrobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 O,O,O-Triethylphosphorothioate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 o-Toluidine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 p-Dimethylaminoazobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 p-Phenylenediamine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Parathion <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pentachlorobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pentachloronitrobenzene <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pentachlorophenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Phenacetin <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Phenol <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Phorate <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pronamide <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Pyridine <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Safrole <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Sulfotepp <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-003 Thionzin <670 U 66.8 <590 U 59.4 <190 U 19.2 8835-004 1,2,4,5-Tetrachlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,2,4-Trichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,2-Dichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,3,5-Trinitrobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,3-Dichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,4-Dichlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1,4-Naphthoquinone <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 1-Naphthylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,3,4,6-Tetrachlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4,5-Trichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4,6-Trichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dimethylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dinitrophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,4-Dinitrotoluene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,6-Dichlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2,6-Dinitrotoluene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Acetylaminofluorene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Chloronaphthalene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Chlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Naphthylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Nitroaniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 2-Nitrophenol <670 U 66.7 <600 U 59.6 <500 U 50.0



### Appendix A - SVOC - 8

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-004 2-Picoline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 3,3'-Dichlorobenzidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 3-3'-Dimethylbenzidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 3-Methylcholanthrene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4,6-Dinitro-2-methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Aminobiphenyl <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Bromophenyl phenyl ether <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Chloro-3-methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Chloroaniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Methylphenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Nitroaniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 4-Nitrophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 5-Nitro-o-toluidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 7,12-Dimethylbenz[a]anthracene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 

### α , 

### α -Dimethylphenethylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Acetophenone <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Aniline <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Aramite <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Benzidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Benzo[a]anthracene <670 U 66.7 <600 U 59.6 <500 1900 50.0 8835-004 Benzo[a]pyrene <670 U 66.7 <600 U 59.6 <500 770 50.0 8835-004 Benzo[b]fluoranthene <670 U 66.7 <600 U 59.6 <500 540 50.0 8835-004 Benzo[k]fluoranthene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Bis(2-chloroisopropyl)ether <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Butyl benzyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Chlorobenzilate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Chrysene <670 U 66.7 <600 U 59.6 <500 2700 50.0 8835-004 Di-n-butyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Di-n-octyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Diallate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dibenzo[a,h]anthracene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dibenz[a,j]acridine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Diethyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dimethoate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dimethyl phthalate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Dinoseb <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Diphenylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Disulfoton <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Ethyl methanesulfonate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Famphur <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Fluoranthene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Fluorene <670 U 66.7 <600 U 59.6 <500 U 50.0



### Appendix A - SVOC - 9

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-004 Hexachlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachlorobutadiene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachlorocyclopentadiene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachloroethane <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Hexachlorophene <17000 U 66.7 <15000 U 59.6 <12000 U 50.0 8835-004 Hexachloropropene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Indeno(1,2,3-c,d)pyrene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Isodrin <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Isosafrole <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Kepone <1300 U 66.7 <1200 U 59.6 <1000 U 50.0 8835-004 Methapyrilene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Methyl parathion <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Methyl methanesulfonate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitroso-di-n-butylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosodi-n-propylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosodiethylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosomethylethylamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosomorpholine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosopiperidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 N-Nitrosopyrrolidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Naphthalene <670 6200 66.7 <600 1700 59.6 <500 U 50.0 8835-004 Nitrobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 O,O,O-Triethylphosphorothioate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 o-Toluidine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 p-Dimethylaminoazobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 p-Phenylenediamine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Parathion <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pentachlorobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pentachloronitrobenzene <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pentachlorophenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Phenacetin <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Phenol <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Phorate <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pronamide <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Pyridine <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Safrole <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Sulfotepp <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-004 Thionzin <670 U 66.7 <600 U 59.6 <500 U 50.0 8835-005 1,2,4,5-Tetrachlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,2,4-Trichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,2-Dichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,3,5-Trinitrobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8



### Appendix A - SVOC - 10

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-005 1,3-Dichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,4-Dichlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1,4-Naphthoquinone <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 1-Naphthylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,3,4,6-Tetrachlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4,5-Trichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4,6-Trichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dimethylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dinitrophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,4-Dinitrotoluene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,6-Dichlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2,6-Dinitrotoluene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Acetylaminofluorene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Chloronaphthalene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Chlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Naphthylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Nitroaniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Nitrophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 2-Picoline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 3,3'-Dichlorobenzidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 3-3'-Dimethylbenzidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 3-Methylcholanthrene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4,6-Dinitro-2-methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Aminobiphenyl <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Bromophenyl phenyl ether <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Chloro-3-methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Chloroaniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Methylphenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Nitroaniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 4-Nitrophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 5-Nitro-o-toluidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 7,12-Dimethylbenz[a]anthracene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 

### α , 

### α -Dimethylphenethylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Acetophenone <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Aniline <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Aramite <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Benzidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Benzo[a]anthracene <130 U 13.4 <590 U 59.5 <200 1600 19.8 8835-005 Benzo[a]pyrene <130 U 13.4 <590 U 59.5 <200 960 19.8 8835-005 Benzo[b]fluoranthene <130 U 13.4 <590 U 59.5 <200 670 19.8



### Appendix A - SVOC - 11

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-005 Benzo[k]fluoranthene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Bis(2-chloroisopropyl)ether <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Butyl benzyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Chlorobenzilate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Chrysene <130 U 13.4 <590 U 59.5 <200 2200 19.8 8835-005 Di-n-butyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Di-n-octyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Diallate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dibenzo[a,h]anthracene <130 U 13.4 <590 U 59.5 <200 250 19.8 8835-005 Dibenz[a,j]acridine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Diethyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dimethoate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dimethyl phthalate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Dinoseb <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Diphenylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Disulfoton <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Ethyl methanesulfonate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Famphur <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Fluoranthene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Fluorene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorobutadiene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorocyclopentadiene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachloroethane <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Hexachlorophene <3400 U 13.4 <15000 U 59.5 <5000 U 19.8 8835-005 Hexachloropropene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Indeno(1,2,3-c,d)pyrene <130 U 13.4 <590 U 59.5 <200 290 19.8 8835-005 Isodrin <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Isosafrole <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Kepone <270 U 13.4 <1200 U 59.5 <400 U 19.8 8835-005 Methapyrilene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Methyl parathion <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Methyl methanesulfonate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitroso-di-n-butylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosodi-n-propylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosodiethylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosomethylethylamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosomorpholine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosopiperidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 N-Nitrosopyrrolidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Naphthalene <130 1300 13.4 <590 1700 59.5 <200 260 19.8 8835-005 Nitrobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8



### Appendix A - SVOC - 12

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-005 O,O,O-Triethylphosphorothioate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 o-Toluidine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 p-Dimethylaminoazobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 p-Phenylenediamine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Parathion <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pentachlorobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pentachloronitrobenzene <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pentachlorophenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Phenacetin <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Phenol <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Phorate <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pronamide <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Pyridine <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Safrole <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Sulfotepp <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-005 Thionzin <130 U 13.4 <590 U 59.5 <200 U 19.8 8835-006 1,2,4,5-Tetrachlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,2,4-Trichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,2-Dichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,3,5-Trinitrobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,3-Dichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,4-Dichlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1,4-Naphthoquinone <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 1-Naphthylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,3,4,6-Tetrachlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4,5-Trichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4,6-Trichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dimethylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dinitrophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,4-Dinitrotoluene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,6-Dichlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2,6-Dinitrotoluene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Acetylaminofluorene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Chloronaphthalene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Chlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Naphthylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Nitroaniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Nitrophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 2-Picoline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 3,3'-Dichlorobenzidine <140 U 14.1 <290 U 29.3 <980 U 98.0



### Appendix A - SVOC - 13

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-006 3-3'-Dimethylbenzidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 3-Methylcholanthrene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4,6-Dinitro-2-methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Aminobiphenyl <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Bromophenyl phenyl ether <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Chloro-3-methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Chloroaniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Methylphenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Nitroaniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 4-Nitrophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 5-Nitro-o-toluidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 7,12-Dimethylbenz[a]anthracene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 

### α , 

### α -Dimethylphenethylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Acetophenone <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Aniline <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Aramite <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[a]anthracene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[a]pyrene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[b]fluoranthene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Benzo[k]fluoranthene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Bis(2-chloroisopropyl)ether <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Butyl benzyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Chlorobenzilate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Chrysene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Di-n-butyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Di-n-octyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Diallate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dibenzo[a,h]anthracene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dibenz[a,j]acridine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Diethyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dimethoate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dimethyl phthalate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Dinoseb <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Diphenylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Disulfoton <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Ethyl methanesulfonate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Famphur <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Fluoranthene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Fluorene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachlorobutadiene <140 U 14.1 <290 U 29.3 <980 U 98.0



### Appendix A - SVOC - 14

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-006 Hexachlorocyclopentadiene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachloroethane <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Hexachlorophene <3500 U 14.1 <7300 U 29.3 <980 U 98.0 8835-006 Hexachloropropene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Indeno(1,2,3-c,d)pyrene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Isodrin <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Isosafrole <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Kepone <280 U 14.1 <580 U 29.3 <2000 U 98.0 8835-006 Methapyrilene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Methyl parathion <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Methyl methanesulfonate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitroso-di-n-butylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosodi-n-propylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosodiethylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosomethylethylamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosomorpholine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosopiperidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 N-Nitrosopyrrolidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Naphthalene <140 1100 14.1 <290 U 29.3 <980 1900 98.0 8835-006 Nitrobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 O,O,O-Triethylphosphorothioate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 o-Toluidine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 p-Dimethylaminoazobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 p-Phenylenediamine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Parathion <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pentachlorobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pentachloronitrobenzene <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pentachlorophenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Phenacetin <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Phenol <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Phorate <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pronamide <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Pyridine <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Safrole <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Sulfotepp <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-006 Thionzin <140 U 14.1 <290 U 29.3 <980 U 98.0 8835-007 1,2,4,5-Tetrachlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,2,4-Trichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,2-Dichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,3,5-Trinitrobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,3-Dichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1,4-Dichlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6



### Appendix A - SVOC - 15

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 1,4-Naphthoquinone <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 1-Naphthylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,3,4,6-Tetrachlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4,5-Trichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4,6-Trichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dimethylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dinitrophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,4-Dinitrotoluene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,6-Dichlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2,6-Dinitrotoluene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Acetylaminofluorene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Chloronaphthalene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Chlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Naphthylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Nitroaniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Nitrophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 2-Picoline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 3,3'-Dichlorobenzidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 3-3'-Dimethylbenzidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 3-Methylcholanthrene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4,6-Dinitro-2-methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Aminobiphenyl <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Bromophenyl phenyl ether <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Chloro-3-methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Chloroaniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Methylphenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Nitroaniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 4-Nitrophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 5-Nitro-o-toluidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 7,12-Dimethylbenz[a]anthracene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 

### α , 

### α -Dimethylphenethylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Acetophenone <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Aniline <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Aramite <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[a]anthracene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[a]pyrene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[b]fluoranthene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Benzo[k]fluoranthene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Bis(2-chloroisopropyl)ether <270 U 27.4 <2400 U 235 <200 U 19.6



### Appendix A - SVOC - 16

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 Butyl benzyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Chlorobenzilate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Chrysene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Di-n-butyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Di-n-octyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Diallate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dibenzo[a,h]anthracene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dibenz[a,j]acridine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Diethyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dimethoate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dimethyl phthalate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Dinoseb <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Diphenylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Disulfoton <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Ethyl methanesulfonate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Famphur <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Fluoranthene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Fluorene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorobutadiene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorocyclopentadiene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachloroethane <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Hexachlorophene <6800 U 27.4 <59000.0000000001 U 235 <4900 U 19.6 8835-007 Hexachloropropene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Indeno(1,2,3-c,d)pyrene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Isodrin <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Isosafrole <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Kepone <550 U 27.4 <4700 U 235 <390 U 19.6 8835-007 Methapyrilene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Methyl parathion <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Methyl methanesulfonate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitroso-di-n-butylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosodi-n-propylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosodiethylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosomethylethylamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosomorpholine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosopiperidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 N-Nitrosopyrrolidine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Naphthalene <270 2300 27.4 <2400 3500 235 <200 690 19.6 8835-007 Nitrobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 O,O,O-Triethylphosphorothioate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 o-Toluidine <270 U 27.4 <2400 U 235 <200 U 19.6



### Appendix A - SVOC - 17

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 p-Dimethylaminoazobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 p-Phenylenediamine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Parathion <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pentachlorobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pentachloronitrobenzene <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pentachlorophenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Phenacetin <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Phenol <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Phorate <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pronamide <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Pyridine <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Safrole <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Sulfotepp <270 U 27.4 <2400 U 235 <200 U 19.6 8835-007 Thionzin <270 U 27.4 <2400 U 235 <200 U 19.6 8835-008 1,2,4,5-Tetrachlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,2,4-Trichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,2-Dichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,3,5-Trinitrobenzene <280 U 27.7 <600 U 59.7 8835-008 1,3-Dichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,4-Dichlorobenzene <280 U 27.7 <600 U 59.7 8835-008 1,4-Naphthoquinone <280 U 27.7 <600 U 59.7 8835-008 1-Naphthylamine <280 U 27.7 <600 U 59.7 8835-008 2,3,4,6-Tetrachlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4,5-Trichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4,6-Trichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dimethylphenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dinitrophenol <280 U 27.7 <600 U 59.7 8835-008 2,4-Dinitrotoluene <280 U 27.7 <600 U 59.7 8835-008 2,6-Dichlorophenol <280 U 27.7 <600 U 59.7 8835-008 2,6-Dinitrotoluene <280 U 27.7 <600 U 59.7 8835-008 2-Acetylaminofluorene <280 U 27.7 <600 U 59.7 8835-008 2-Chloronaphthalene <280 U 27.7 <600 U 59.7 8835-008 2-Chlorophenol <280 U 27.7 <600 U 59.7 8835-008 2-Methylphenol <280 U 27.7 <600 U 59.7 8835-008 2-Naphthylamine <280 U 27.7 <600 U 59.7 8835-008 2-Nitroaniline <280 U 27.7 <600 U 59.7 8835-008 2-Nitrophenol <280 U 27.7 <600 U 59.7 8835-008 2-Picoline <280 U 27.7 <600 U 59.7 8835-008 3,3'-Dichlorobenzidine <280 U 27.7 <600 U 59.7 8835-008 3-3'-Dimethylbenzidine <280 U 27.7 <600 U 59.7 8835-008 3-Methylcholanthrene <280 U 27.7 <600 U 59.7



### Appendix A - SVOC - 18

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-008 4,6-Dinitro-2-methylphenol <280 U 27.7 <600 U 59.7 8835-008 4-Aminobiphenyl <280 U 27.7 <600 U 59.7 8835-008 4-Bromophenyl phenyl ether <280 U 27.7 <600 U 59.7 8835-008 4-Chloro-3-methylphenol <280 U 27.7 <600 U 59.7 8835-008 4-Chloroaniline <280 U 27.7 <600 U 59.7 8835-008 4-Methylphenol <280 U 27.7 <600 U 59.7 8835-008 4-Nitroaniline <280 U 27.7 <600 U 59.7 8835-008 4-Nitrophenol <280 U 27.7 <600 U 59.7 8835-008 5-Nitro-o-toluidine <280 U 27.7 <600 U 59.7 8835-008 7,12-Dimethylbenz[a]anthracene <280 U 27.7 <600 U 59.7 8835-008 

### α , 

### α -Dimethylphenethylamine <280 U 27.7 <600 U 59.7 8835-008 Acetophenone <280 U 27.7 <600 U 59.7 8835-008 Aniline <280 U 27.7 <600 U 59.7 8835-008 Aramite <280 U 27.7 <600 U 59.7 8835-008 Benzidine <280 U 27.7 <600 U 59.7 8835-008 Benzo[a]anthracene <280 U 27.7 <600 U 59.7 8835-008 Benzo[a]pyrene <280 U 27.7 <600 U 59.7 8835-008 Benzo[b]fluoranthene <280 U 27.7 <600 U 59.7 8835-008 Benzo[k]fluoranthene <280 U 27.7 <600 U 59.7 8835-008 Bis(2-chloroisopropyl)ether <280 U 27.7 <600 U 59.7 8835-008 Butyl benzyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Chlorobenzilate <280 U 27.7 <600 U 59.7 8835-008 Chrysene <280 U 27.7 <600 U 59.7 8835-008 Di-n-butyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Di-n-octyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Diallate <280 U 27.7 <600 U 59.7 8835-008 Dibenzo[a,h]anthracene <280 U 27.7 <600 U 59.7 8835-008 Dibenz[a,j]acridine <280 U 27.7 <600 U 59.7 8835-008 Diethyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Dimethoate <280 U 27.7 <600 U 59.7 8835-008 Dimethyl phthalate <280 U 27.7 <600 U 59.7 8835-008 Dinoseb <280 U 27.7 <600 U 59.7 8835-008 Diphenylamine <280 U 27.7 <600 U 59.7 8835-008 Disulfoton <280 U 27.7 <600 U 59.7 8835-008 Ethyl methanesulfonate <280 U 27.7 <600 U 59.7 8835-008 Famphur <280 U 27.7 <600 U 59.7 8835-008 Fluoranthene <280 U 27.7 <600 U 59.7 8835-008 Fluorene <280 U 27.7 <600 U 59.7 8835-008 Hexachlorobenzene <280 U 27.7 <600 U 59.7 8835-008 Hexachlorobutadiene <280 U 27.7 <600 U 59.7 8835-008 Hexachlorocyclopentadiene <280 U 27.7 <600 U 59.7 8835-008 Hexachloroethane <280 U 27.7 <600 U 59.7



### Appendix A - SVOC - 19

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-008 Hexachlorophene <6900 U 27.7 <15000 U 59.7 8835-008 Hexachloropropene <280 U 27.7 <600 U 59.7 8835-008 Indeno(1,2,3-c,d)pyrene <280 U 27.7 <600 U 59.7 8835-008 Isodrin <280 U 27.7 <600 U 59.7 8835-008 Isosafrole <280 U 27.7 <600 U 59.7 8835-008 Kepone <550 U 27.7 <1200 U 59.7 8835-008 Methapyrilene <280 U 27.7 <600 U 59.7 8835-008 Methyl parathion <280 U 27.7 <600 U 59.7 8835-008 Methyl methanesulfonate <280 U 27.7 <600 U 59.7 8835-008 N-Nitroso-di-n-butylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosodi-n-propylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosodiethylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosomethylethylamine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosomorpholine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosopiperidine <280 U 27.7 <600 U 59.7 8835-008 N-Nitrosopyrrolidine <280 U 27.7 <600 U 59.7 8835-008 Naphthalene <280 2100 27.7 <600 1800 59.7 8835-008 Nitrobenzene <280 U 27.7 <600 U 59.7 8835-008 O,O,O-Triethylphosphorothioate <280 U 27.7 <600 U 59.7 8835-008 o-Toluidine <280 U 27.7 <600 U 59.7 8835-008 p-Dimethylaminoazobenzene <280 U 27.7 <600 U 59.7 8835-008 p-Phenylenediamine <280 U 27.7 <600 U 59.7 8835-008 Parathion <280 U 27.7 <600 U 59.7 8835-008 Pentachlorobenzene <280 U 27.7 <600 U 59.7 8835-008 Pentachloronitrobenzene <280 U 27.7 <600 U 59.7 8835-008 Pentachlorophenol <280 U 27.7 <600 U 59.7 8835-008 Phenacetin <280 U 27.7 <600 U 59.7 8835-008 Phenol <280 U 27.7 <600 U 59.7 8835-008 Phorate <280 U 27.7 <600 U 59.7 8835-008 Pronamide <280 U 27.7 <600 U 59.7 8835-008 Pyridine <280 U 27.7 <600 U 59.7 8835-008 Safrole <280 U 27.7 <600 U 59.7 8835-008 Sulfotepp <280 U 27.7 <600 U 59.7 8835-008 Thionzin <280 U 27.7 <600 U 59.7 8835-009 1,2,4,5-Tetrachlorobenzene <600 U 60.1 8835-009 1,2,4-Trichlorobenzene <600 U 60.1 8835-009 1,2-Dichlorobenzene <600 U 60.1 8835-009 1,3,5-Trinitrobenzene <600 U 60.1 8835-009 1,3-Dichlorobenzene <600 U 60.1 8835-009 1,4-Dichlorobenzene <600 U 60.1 8835-009 1,4-Naphthoquinone <600 U 60.1 8835-009 1-Naphthylamine <600 U 60.1



### Appendix A - SVOC - 20

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-009 2,3,4,6-Tetrachlorophenol <600 U 60.1 8835-009 2,4,5-Trichlorophenol <600 U 60.1 8835-009 2,4,6-Trichlorophenol <600 U 60.1 8835-009 2,4-Dichlorophenol <600 U 60.1 8835-009 2,4-Dimethylphenol <600 U 60.1 8835-009 2,4-Dinitrophenol <600 U 60.1 8835-009 2,4-Dinitrotoluene <600 U 60.1 8835-009 2,6-Dichlorophenol <600 U 60.1 8835-009 2,6-Dinitrotoluene <600 U 60.1 8835-009 2-Acetylaminofluorene <600 U 60.1 8835-009 2-Chloronaphthalene <600 U 60.1 8835-009 2-Chlorophenol <600 U 60.1 8835-009 2-Methylphenol <600 U 60.1 8835-009 2-Naphthylamine <600 U 60.1 8835-009 2-Nitroaniline <600 U 60.1 8835-009 2-Nitrophenol <600 U 60.1 8835-009 2-Picoline <600 U 60.1 8835-009 3,3'-Dichlorobenzidine <600 U 60.1 8835-009 3-3'-Dimethylbenzidine <600 U 60.1 8835-009 3-Methylcholanthrene <600 U 60.1 8835-009 4,6-Dinitro-2-methylphenol <600 U 60.1 8835-009 4-Aminobiphenyl <600 U 60.1 8835-009 4-Bromophenyl phenyl ether <600 U 60.1 8835-009 4-Chloro-3-methylphenol <600 U 60.1 8835-009 4-Chloroaniline <600 U 60.1 8835-009 4-Methylphenol <600 U 60.1 8835-009 4-Nitroaniline <600 U 60.1 8835-009 4-Nitrophenol <600 U 60.1 8835-009 5-Nitro-o-toluidine <600 U 60.1 8835-009 7,12-Dimethylbenz[a]anthracene <600 U 60.1 8835-009 

### α , 

### α -Dimethylphenethylamine <600 U 60.1 8835-009 Acetophenone <600 U 60.1 8835-009 Aniline <600 U 60.1 8835-009 Aramite <600 U 60.1 8835-009 Benzidine <600 U 60.1 8835-009 Benzo[a]anthracene <600 U 60.1 8835-009 Benzo[a]pyrene <600 U 60.1 8835-009 Benzo[b]fluoranthene <600 U 60.1 8835-009 Benzo[k]fluoranthene <600 U 60.1 8835-009 Bis(2-chloroisopropyl)ether <600 U 60.1 8835-009 Butyl benzyl phthalate <600 U 60.1 8835-009 Chlorobenzilate <600 U 60.1



### Appendix A - SVOC - 21

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-009 Chrysene <600 U 60.1 8835-009 Di-n-butyl phthalate <600 U 60.1 8835-009 Di-n-octyl phthalate <600 U 60.1 8835-009 Diallate <600 U 60.1 8835-009 Dibenzo[a,h]anthracene <600 U 60.1 8835-009 Dibenz[a,j]acridine <600 U 60.1 8835-009 Diethyl phthalate <600 U 60.1 8835-009 Dimethoate <600 U 60.1 8835-009 Dimethyl phthalate <600 U 60.1 8835-009 Dinoseb <600 U 60.1 8835-009 Diphenylamine <600 U 60.1 8835-009 Disulfoton <600 U 60.1 8835-009 Ethyl methanesulfonate <600 U 60.1 8835-009 Famphur <600 U 60.1 8835-009 Fluoranthene <600 U 60.1 8835-009 Fluorene <600 U 60.1 8835-009 Hexachlorobenzene <600 U 60.1 8835-009 Hexachlorobutadiene <600 U 60.1 8835-009 Hexachlorocyclopentadiene <600 U 60.1 8835-009 Hexachloroethane <600 U 60.1 8835-009 Hexachlorophene <15000 U 60.1 8835-009 Hexachloropropene <600 U 60.1 8835-009 Indeno(1,2,3-c,d)pyrene <600 U 60.1 8835-009 Isodrin <600 U 60.1 8835-009 Isosafrole <600 U 60.1 8835-009 Kepone <1200 U 60.1 8835-009 Methapyrilene <600 U 60.1 8835-009 Methyl parathion <600 U 60.1 8835-009 Methyl methanesulfonate <600 U 60.1 8835-009 N-Nitroso-di-n-butylamine <600 U 60.1 8835-009 N-Nitrosodi-n-propylamine <600 U 60.1 8835-009 N-Nitrosodiethylamine <600 U 60.1 8835-009 N-Nitrosomethylethylamine <600 U 60.1 8835-009 N-Nitrosomorpholine <600 U 60.1 8835-009 N-Nitrosopiperidine <600 U 60.1 8835-009 N-Nitrosopyrrolidine <600 U 60.1 8835-009 Naphthalene <600 650 60.1 8835-009 Nitrobenzene <600 U 60.1 8835-009 O,O,O-Triethylphosphorothioate <600 U 60.1 8835-009 o-Toluidine <600 U 60.1 8835-009 p-Dimethylaminoazobenzene <600 U 60.1 8835-009 p-Phenylenediamine <600 U 60.1



### Appendix A - SVOC - 22

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-009 Parathion <600 U 60.1 8835-009 Pentachlorobenzene <600 U 60.1 8835-009 Pentachloronitrobenzene <600 U 60.1 8835-009 Pentachlorophenol <600 U 60.1 8835-009 Phenacetin <600 U 60.1 8835-009 Phenol <600 U 60.1 8835-009 Phorate <600 U 60.1 8835-009 Pronamide <600 U 60.1 8835-009 Pyridine <600 U 60.1 8835-009 Safrole <600 U 60.1 8835-009 Sulfotepp <600 U 60.1 8835-009 Thionzin <600 U 60.1 8835-010 1,2,4,5-Tetrachlorobenzene <600 U 59.8 8835-010 1,2,4-Trichlorobenzene <600 U 59.8 8835-010 1,2-Dichlorobenzene <600 U 59.8 8835-010 1,3,5-Trinitrobenzene <600 U 59.8 8835-010 1,3-Dichlorobenzene <600 U 59.8 8835-010 1,4-Dichlorobenzene <600 U 59.8 8835-010 1,4-Naphthoquinone <600 U 59.8 8835-010 1-Naphthylamine <600 U 59.8 8835-010 2,3,4,6-Tetrachlorophenol <600 U 59.8 8835-010 2,4,5-Trichlorophenol <600 U 59.8 8835-010 2,4,6-Trichlorophenol <600 U 59.8 8835-010 2,4-Dichlorophenol <600 U 59.8 8835-010 2,4-Dimethylphenol <600 U 59.8 8835-010 2,4-Dinitrophenol <600 U 59.8 8835-010 2,4-Dinitrotoluene <600 U 59.8 8835-010 2,6-Dichlorophenol <600 U 59.8 8835-010 2,6-Dinitrotoluene <600 U 59.8 8835-010 2-Acetylaminofluorene <600 U 59.8 8835-010 2-Chloronaphthalene <600 U 59.8 8835-010 2-Chlorophenol <600 U 59.8 8835-010 2-Methylphenol <600 U 59.8 8835-010 2-Naphthylamine <600 U 59.8 8835-010 2-Nitroaniline <600 U 59.8 8835-010 2-Nitrophenol <600 U 59.8 8835-010 2-Picoline <600 U 59.8 8835-010 3,3'-Dichlorobenzidine <600 U 59.8 8835-010 3-3'-Dimethylbenzidine <600 U 59.8 8835-010 3-Methylcholanthrene <600 U 59.8 8835-010 4,6-Dinitro-2-methylphenol <600 U 59.8 8835-010 4-Aminobiphenyl <600 U 59.8



### Appendix A - SVOC - 23

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-010 4-Bromophenyl phenyl ether <600 U 59.8 8835-010 4-Chloro-3-methylphenol <600 U 59.8 8835-010 4-Chloroaniline <600 U 59.8 8835-010 4-Methylphenol <600 U 59.8 8835-010 4-Nitroaniline <600 U 59.8 8835-010 4-Nitrophenol <600 U 59.8 8835-010 5-Nitro-o-toluidine <600 U 59.8 8835-010 7,12-Dimethylbenz[a]anthracene <600 U 59.8 8835-010 

### α , 

### α -Dimethylphenethylamine <600 U 59.8 8835-010 Acetophenone <600 U 59.8 8835-010 Aniline <600 U 59.8 8835-010 Aramite <600 U 59.8 8835-010 Benzidine <600 U 59.8 8835-010 Benzo[a]anthracene <600 U 59.8 8835-010 Benzo[a]pyrene <600 U 59.8 8835-010 Benzo[b]fluoranthene <600 U 59.8 8835-010 Benzo[k]fluoranthene <600 U 59.8 8835-010 Bis(2-chloroisopropyl)ether <600 U 59.8 8835-010 Butyl benzyl phthalate <600 U 59.8 8835-010 Chlorobenzilate <600 U 59.8 8835-010 Chrysene <600 U 59.8 8835-010 Di-n-butyl phthalate <600 U 59.8 8835-010 Di-n-octyl phthalate <600 U 59.8 8835-010 Diallate <600 U 59.8 8835-010 Dibenzo[a,h]anthracene <600 U 59.8 8835-010 Dibenz[a,j]acridine <600 U 59.8 8835-010 Diethyl phthalate <600 U 59.8 8835-010 Dimethoate <600 U 59.8 8835-010 Dimethyl phthalate <600 U 59.8 8835-010 Dinoseb <600 U 59.8 8835-010 Diphenylamine <600 U 59.8 8835-010 Disulfoton <600 U 59.8 8835-010 Ethyl methanesulfonate <600 U 59.8 8835-010 Famphur <600 U 59.8 8835-010 Fluoranthene <600 U 59.8 8835-010 Fluorene <600 U 59.8 8835-010 Hexachlorobenzene <600 U 59.8 8835-010 Hexachlorobutadiene <600 U 59.8 8835-010 Hexachlorocyclopentadiene <600 U 59.8 8835-010 Hexachloroethane <600 U 59.8 8835-010 Hexachlorophene <15000 U 59.8 8835-010 Hexachloropropene <600 U 59.8



### Appendix A - SVOC - 24

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-010 Indeno(1,2,3-c,d)pyrene <600 U 59.8 8835-010 Isodrin <600 U 59.8 8835-010 Isosafrole <600 U 59.8 8835-010 Kepone <1200 U 59.8 8835-010 Methapyrilene <600 U 59.8 8835-010 Methyl parathion <600 U 59.8 8835-010 Methyl methanesulfonate <600 U 59.8 8835-010 N-Nitroso-di-n-butylamine <600 U 59.8 8835-010 N-Nitrosodi-n-propylamine <600 U 59.8 8835-010 N-Nitrosodiethylamine <600 U 59.8 8835-010 N-Nitrosomethylethylamine <600 U 59.8 8835-010 N-Nitrosomorpholine <600 U 59.8 8835-010 N-Nitrosopiperidine <600 U 59.8 8835-010 N-Nitrosopyrrolidine <600 U 59.8 8835-010 Naphthalene <600 710 59.8 8835-010 Nitrobenzene <600 U 59.8 8835-010 O,O,O-Triethylphosphorothioate <600 U 59.8 8835-010 o-Toluidine <600 U 59.8 8835-010 p-Dimethylaminoazobenzene <600 U 59.8 8835-010 p-Phenylenediamine <600 U 59.8 8835-010 Parathion <600 U 59.8 8835-010 Pentachlorobenzene <600 U 59.8 8835-010 Pentachloronitrobenzene <600 U 59.8 8835-010 Pentachlorophenol <600 U 59.8 8835-010 Phenacetin <600 U 59.8 8835-010 Phenol <600 U 59.8 8835-010 Phorate <600 U 59.8 8835-010 Pronamide <600 U 59.8 8835-010 Pyridine <600 U 59.8 8835-010 Safrole <600 U 59.8 8835-010 Sulfotepp <600 U 59.8 8835-010 Thionzin <600 U 59.8 8835-011 1,2,4,5-Tetrachlorobenzene <580 U 58.3 8835-011 1,2,4-Trichlorobenzene <580 U 58.3 8835-011 1,2-Dichlorobenzene <580 U 58.3 8835-011 1,3,5-Trinitrobenzene <580 U 58.3 8835-011 1,3-Dichlorobenzene <580 U 58.3 8835-011 1,4-Dichlorobenzene <580 U 58.3 8835-011 1,4-Naphthoquinone <580 U 58.3 8835-011 1-Naphthylamine <580 U 58.3 8835-011 2,3,4,6-Tetrachlorophenol <580 U 58.3 8835-011 2,4,5-Trichlorophenol <580 U 58.3



### Appendix A - SVOC - 25

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-011 2,4,6-Trichlorophenol <580 U 58.3 8835-011 2,4-Dichlorophenol <580 U 58.3 8835-011 2,4-Dimethylphenol <580 U 58.3 8835-011 2,4-Dinitrophenol <580 U 58.3 8835-011 2,4-Dinitrotoluene <580 U 58.3 8835-011 2,6-Dichlorophenol <580 U 58.3 8835-011 2,6-Dinitrotoluene <580 U 58.3 8835-011 2-Acetylaminofluorene <580 U 58.3 8835-011 2-Chloronaphthalene <580 U 58.3 8835-011 2-Chlorophenol <580 U 58.3 8835-011 2-Methylphenol <580 U 58.3 8835-011 2-Naphthylamine <580 U 58.3 8835-011 2-Nitroaniline <580 U 58.3 8835-011 2-Nitrophenol <580 U 58.3 8835-011 2-Picoline <580 U 58.3 8835-011 3,3'-Dichlorobenzidine <580 U 58.3 8835-011 3-3'-Dimethylbenzidine <580 U 58.3 8835-011 3-Methylcholanthrene <580 U 58.3 8835-011 4,6-Dinitro-2-methylphenol <580 U 58.3 8835-011 4-Aminobiphenyl <580 U 58.3 8835-011 4-Bromophenyl phenyl ether <580 U 58.3 8835-011 4-Chloro-3-methylphenol <580 U 58.3 8835-011 4-Chloroaniline <580 U 58.3 8835-011 4-Methylphenol <580 U 58.3 8835-011 4-Nitroaniline <580 U 58.3 8835-011 4-Nitrophenol <580 U 58.3 8835-011 5-Nitro-o-toluidine <580 U 58.3 8835-011 7,12-Dimethylbenz[a]anthracene <580 U 58.3 8835-011 

### α , 

### α -Dimethylphenethylamine <580 U 58.3 8835-011 Acetophenone <580 U 58.3 8835-011 Aniline <580 U 58.3 8835-011 Aramite <580 U 58.3 8835-011 Benzidine <580 U 58.3 8835-011 Benzo[a]anthracene <580 U 58.3 8835-011 Benzo[a]pyrene <580 U 58.3 8835-011 Benzo[b]fluoranthene <580 U 58.3 8835-011 Benzo[k]fluoranthene <580 U 58.3 8835-011 Bis(2-chloroisopropyl)ether <580 U 58.3 8835-011 Butyl benzyl phthalate <580 U 58.3 8835-011 Chlorobenzilate <580 U 58.3 8835-011 Chrysene <580 U 58.3 8835-011 Di-n-butyl phthalate <580 U 58.3



### Appendix A - SVOC - 26

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-011 Di-n-octyl phthalate <580 U 58.3 8835-011 Diallate <580 U 58.3 8835-011 Dibenzo[a,h]anthracene <580 U 58.3 8835-011 Dibenz[a,j]acridine <580 U 58.3 8835-011 Diethyl phthalate <580 U 58.3 8835-011 Dimethoate <580 U 58.3 8835-011 Dimethyl phthalate <580 U 58.3 8835-011 Dinoseb <580 U 58.3 8835-011 Diphenylamine <580 U 58.3 8835-011 Disulfoton <580 U 58.3 8835-011 Ethyl methanesulfonate <580 U 58.3 8835-011 Famphur <580 U 58.3 8835-011 Fluoranthene <580 U 58.3 8835-011 Fluorene <580 U 58.3 8835-011 Hexachlorobenzene <580 U 58.3 8835-011 Hexachlorobutadiene <580 U 58.3 8835-011 Hexachlorocyclopentadiene <580 U 58.3 8835-011 Hexachloroethane <580 U 58.3 8835-011 Hexachlorophene <14000 U 58.3 8835-011 Hexachloropropene <580 U 58.3 8835-011 Indeno(1,2,3-c,d)pyrene <580 U 58.3 8835-011 Isodrin <580 U 58.3 8835-011 Isosafrole <580 U 58.3 8835-011 Kepone <1200 U 58.3 8835-011 Methapyrilene <580 U 58.3 8835-011 Methyl parathion <580 U 58.3 8835-011 Methyl methanesulfonate <580 U 58.3 8835-011 N-Nitroso-di-n-butylamine <580 U 58.3 8835-011 N-Nitrosodi-n-propylamine <580 U 58.3 8835-011 N-Nitrosodiethylamine <580 U 58.3 8835-011 N-Nitrosomethylethylamine <580 U 58.3 8835-011 N-Nitrosomorpholine <580 U 58.3 8835-011 N-Nitrosopiperidine <580 U 58.3 8835-011 N-Nitrosopyrrolidine <580 U 58.3 8835-011 Naphthalene <580 810 58.3 8835-011 Nitrobenzene <580 U 58.3 8835-011 O,O,O-Triethylphosphorothioate <580 U 58.3 8835-011 o-Toluidine <580 U 58.3 8835-011 p-Dimethylaminoazobenzene <580 U 58.3 8835-011 p-Phenylenediamine <580 U 58.3 8835-011 Parathion <580 U 58.3 8835-011 Pentachlorobenzene <580 U 58.3



### Appendix A - SVOC - 27

## COMPARABLE FUELS RESULTS - SVOC (mg/Kg)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-011 Pentachloronitrobenzene <580 U 58.3 8835-011 Pentachlorophenol <580 U 58.3 8835-011 Phenacetin <580 U 58.3 8835-011 Phenol <580 U 58.3 8835-011 Phorate <580 U 58.3 8835-011 Pronamide <580 U 58.3 8835-011 Pyridine <580 U 58.3 8835-011 Safrole <580 U 58.3 8835-011 Sulfotepp <580 U 58.3 8835-011 Thionzin <580 U 58.3



### Appendix A - SVOC - 28

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-001 1,1,2,2-Tetrachloroethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,1,2-Trichloroethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,1-Dichloroethene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,2,3,-Trichloropropane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,2,4-Trichlorobenzene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,2-Dibromo-3-chloropropane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,2-Dibromoethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,2-Dichlorobenzene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,3-Dichlorobenzene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 1,4-Dichlorobenzene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 2-Butanone <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 2-Chloroethylvinyl ether <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Acetonitrile <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Acrolein <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Acrylonitrile <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Allyl chloride <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Benzene <3300 6400 333 <32 38 3.23 <17 42 1.72 <16 U 8835-001 Bromoform <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Bromomethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Carbon disulfide <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Carbon tetrachloride <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Chlorobenzene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Chloroform <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Chloromethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Chloroprene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 cis-1,2-Dichloroethene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 cis-1,3-Dichloropropene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 cis-1,4-Dichloro-2-butene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Dibromomethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Dichlorodifluoromethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Ethyl methacrylate <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Iodomethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Isobutanol <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 m,p-Xylene <6700 44000 333 <65 1200 3.23 <34 560 1.72 <33 60 8835-001 Methacrylonitrile <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Methyl methacrylate <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Methylene chloride <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 o-Xylene <3300 17000 333 <32 290 3.23 <17 130 1.72 <16 U 8835-001 p-Dioxane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Pentachloroethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Propionitrile <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Tetrachloroethene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Toluene <3300 50000 333 <32 280 3.23 <17 220 1.72 <16 U 8835-001 trans-1,2-Dichloroethene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 trans-1,4-Dichloro-2-butene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Trichloroethene <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-001 Trichlorofluoromethane <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U



## Appendix A - VOC - 1

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-001 Vinyl Chloride <3300 U 333 <32 U 3.23 <17 U 1.72 <16 U 8835-002 1,1,2,2-Tetrachloroethane <3200 U 325 <34 U 3.43 <17 U 8835-002 1,1,2-Trichloroethane <3200 U 325 <34 U 3.43 <17 U 8835-002 1,1-Dichloroethene <3200 U 325 <34 U 3.43 <17 U 8835-002 1,2,3,-Trichloropropane <3200 U 325 <34 U 3.43 <17 U 8835-002 1,2,4-Trichlorobenzene <3200 U 325 <34 U 3.43 <17 U 8835-002 1,2-Dibromo-3-chloropropane <3200 U 325 <34 U 3.43 <17 U 8835-002 1,2-Dibromoethane <3200 U 325 <34 U 3.43 <17 U 8835-002 1,2-Dichlorobenzene <3200 U 325 <34 U 3.43 <17 U 8835-002 1,3-Dichlorobenzene <3200 U 325 <34 U 3.43 <17 U 8835-002 1,4-Dichlorobenzene <3200 U 325 <34 U 3.43 <17 U 8835-002 2-Butanone <3200 U 325 <34 U 3.43 <17 U 8835-002 2-Chloroethylvinyl ether <3200 U 325 <34 U 3.43 <17 U 8835-002 Acetonitrile <3200 U 325 <34 U 3.43 <17 U 8835-002 Acrolein <3200 U 325 <34 U 3.43 <17 U 8835-002 Acrylonitrile <3200 U 325 <34 U 3.43 <17 U 8835-002 Allyl chloride <3200 U 325 <34 U 3.43 <17 U 8835-002 Benzene <3200 6200 325 <34 39 3.43 <17 U 8835-002 Bromoform <3200 U 325 <34 U 3.43 <17 U 8835-002 Bromomethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Carbon disulfide <3200 U 325 <34 U 3.43 <17 U 8835-002 Carbon tetrachloride <3200 U 325 <34 U 3.43 <17 U 8835-002 Chlorobenzene <3200 U 325 <34 U 3.43 <17 U 8835-002 Chloroform <3200 U 325 <34 U 3.43 <17 U 8835-002 Chloromethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Chloroprene <3200 U 325 <34 U 3.43 <17 U 8835-002 cis-1,2-Dichloroethene <3200 U 325 <34 U 3.43 <17 U 8835-002 cis-1,3-Dichloropropene <3200 U 325 <34 U 3.43 <17 U 8835-002 cis-1,4-Dichloro-2-butene <3200 U 325 <34 U 3.43 <17 U 8835-002 Dibromomethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Dichlorodifluoromethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Ethyl methacrylate <3200 U 325 <34 U 3.43 <17 U 8835-002 Iodomethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Isobutanol <3200 U 325 <34 U 3.43 <17 U 8835-002 m,p-Xylene <6500 43000 325 <69 1200 3.43 <33 320 8835-002 Methacrylonitrile <3200 U 325 <34 U 3.43 <17 U 8835-002 Methyl methacrylate <3200 U 325 <34 U 3.43 <17 U 8835-002 Methylene chloride <3200 U 325 <34 U 3.43 <17 U 8835-002 o-Xylene <3200 17000 325 <34 300 3.43 <17 67 8835-002 p-Dioxane <3200 U 325 <34 U 3.43 <17 U 8835-002 Pentachloroethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Propionitrile <3200 U 325 <34 U 3.43 <17 U 8835-002 Tetrachloroethene <3200 U 325 <34 U 3.43 <17 U 8835-002 Toluene <3200 49000 325 <34 290 3.43 <17 76 8835-002 trans-1,2-Dichloroethene <3200 U 325 <34 U 3.43 <17 U 8835-002 trans-1,4-Dichloro-2-butene <3200 U 325 <34 U 3.43 <17 U 8835-002 Trichloroethene <3200 U 325 <34 U 3.43 <17 U



## Appendix A - VOC - 2

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-002 Trichlorofluoromethane <3200 U 325 <34 U 3.43 <17 U 8835-002 Vinyl Chloride <3200 U 325 <34 U 3.43 <17 U 8835-003 1,1,2,2-Tetrachloroethane <3400 U 339 <33 U 3.29 <16 U 8835-003 1,1,2-Trichloroethane <3400 U 339 <33 U 3.29 <16 U 8835-003 1,1-Dichloroethene <3400 U 339 <33 U 3.29 <16 U 8835-003 1,2,3,-Trichloropropane <3400 U 339 <33 U 3.29 <16 U 8835-003 1,2,4-Trichlorobenzene <3400 U 339 <33 U 3.29 <16 U 8835-003 1,2-Dibromo-3-chloropropane <3400 U 339 <33 U 3.29 <16 U 8835-003 1,2-Dibromoethane <3400 U 339 <33 U 3.29 <16 U 8835-003 1,2-Dichlorobenzene <3400 U 339 <33 U 3.29 <16 U 8835-003 1,3-Dichlorobenzene <3400 U 339 <33 U 3.29 <16 U 8835-003 1,4-Dichlorobenzene <3400 U 339 <33 U 3.29 <16 U 8835-003 2-Butanone <3400 U 339 <33 U 3.29 <16 U 8835-003 2-Chloroethylvinyl ether <3400 U 339 <33 U 3.29 <16 U 8835-003 Acetonitrile <3400 U 339 <33 U 3.29 <16 U 8835-003 Acrolein <3400 U 339 <33 U 3.29 <16 U 8835-003 Acrylonitrile <3400 U 339 <33 U 3.29 <16 U 8835-003 Allyl chloride <3400 U 339 <33 U 3.29 <16 U 8835-003 Benzene <3400 6600 339 <33 U 3.29 <16 U 8835-003 Bromoform <3400 U 339 <33 U 3.29 <16 U 8835-003 Bromomethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Carbon disulfide <3400 U 339 <33 U 3.29 <16 U 8835-003 Carbon tetrachloride <3400 U 339 <33 U 3.29 <16 U 8835-003 Chlorobenzene <3400 U 339 <33 U 3.29 <16 U 8835-003 Chloroform <3400 U 339 <33 U 3.29 <16 U 8835-003 Chloromethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Chloroprene <3400 U 339 <33 U 3.29 <16 U 8835-003 cis-1,2-Dichloroethene <3400 U 339 <33 U 3.29 <16 U 8835-003 cis-1,3-Dichloropropene <3400 U 339 <33 U 3.29 <16 U 8835-003 cis-1,4-Dichloro-2-butene <3400 U 339 <33 U 3.29 <16 U 8835-003 Dibromomethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Dichlorodifluoromethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Ethyl methacrylate <3400 U 339 <33 U 3.29 <16 U 8835-003 Iodomethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Isobutanol <3400 U 339 <33 U 3.29 <16 U 8835-003 m,p-Xylene <6800 36000 339 <66 500 3.29 <32 300 8835-003 Methacrylonitrile <3400 U 339 <33 U 3.29 <16 U 8835-003 Methyl methacrylate <3400 U 339 <33 U 3.29 <16 U 8835-003 Methylene chloride <3400 U 339 <33 U 3.29 <16 U 8835-003 o-Xylene <3400 13000 339 <33 270 3.29 <16 63 8835-003 p-Dioxane <3400 U 339 <33 U 3.29 <16 U 8835-003 Pentachloroethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Propionitrile <3400 U 339 <33 U 3.29 <16 U 8835-003 Tetrachloroethene <3400 U 339 <33 U 3.29 <16 U 8835-003 Toluene <3400 68000 339 <33 160 3.29 <16 76 8835-003 trans-1,2-Dichloroethene <3400 U 339 <33 U 3.29 <16 U 8835-003 trans-1,4-Dichloro-2-butene <3400 U 339 <33 U 3.29 <16 U



## Appendix A - VOC - 3

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-003 Trichloroethene <3400 U 339 <33 U 3.29 <16 U 8835-003 Trichlorofluoromethane <3400 U 339 <33 U 3.29 <16 U 8835-003 Vinyl Chloride <3400 U 339 <33 U 3.29 <16 U 8835-004 1,1,2,2-Tetrachloroethane <3400 U 337 <33 U 3.33 <16 U 8835-004 1,1,2-Trichloroethane <3400 U 337 <33 U 3.33 <16 U 8835-004 1,1-Dichloroethene <3400 U 337 <33 U 3.33 <16 U 8835-004 1,2,3,-Trichloropropane <3400 U 337 <33 U 3.33 <16 U 8835-004 1,2,4-Trichlorobenzene <3400 U 337 <33 U 3.33 <16 U 8835-004 1,2-Dibromo-3-chloropropane <3400 U 337 <33 U 3.33 <16 U 8835-004 1,2-Dibromoethane <3400 U 337 <33 U 3.33 <16 U 8835-004 1,2-Dichlorobenzene <3400 U 337 <33 U 3.33 <16 U 8835-004 1,3-Dichlorobenzene <3400 U 337 <33 U 3.33 <16 U 8835-004 1,4-Dichlorobenzene <3400 U 337 <33 U 3.33 <16 U 8835-004 2-Butanone <3400 U 337 <33 U 3.33 <16 U 8835-004 2-Chloroethylvinyl ether <3400 U 337 <33 U 3.33 <16 U 8835-004 Acetonitrile <3400 U 337 <33 U 3.33 <16 U 8835-004 Acrolein <3400 U 337 <33 U 3.33 <16 U 8835-004 Acrylonitrile <3400 U 337 <33 U 3.33 <16 U 8835-004 Allyl chloride <3400 U 337 <33 U 3.33 <16 U 8835-004 Benzene <3400 6600 337 <33 U 3.33 <16 U 8835-004 Bromoform <3400 U 337 <33 U 3.33 <16 U 8835-004 Bromomethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Carbon disulfide <3400 U 337 <33 U 3.33 <16 U 8835-004 Carbon tetrachloride <3400 U 337 <33 U 3.33 <16 U 8835-004 Chlorobenzene <3400 U 337 <33 U 3.33 <16 U 8835-004 Chloroform <3400 U 337 <33 U 3.33 <16 U 8835-004 Chloromethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Chloroprene <3400 U 337 <33 U 3.33 <16 U 8835-004 cis-1,2-Dichloroethene <3400 U 337 <33 U 3.33 <16 U 8835-004 cis-1,3-Dichloropropene <3400 U 337 <33 U 3.33 <16 U 8835-004 cis-1,4-Dichloro-2-butene <3400 U 337 <33 U 3.33 <16 U 8835-004 Dibromomethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Dichlorodifluoromethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Ethyl methacrylate <3400 U 337 <33 U 3.33 <16 U 8835-004 Iodomethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Isobutanol <3400 U 337 <33 U 3.33 <16 U 8835-004 m,p-Xylene <6700 36000 337 <66 1000 3.33 <32 34 8835-004 Methacrylonitrile <3400 U 337 <33 U 3.33 <16 U 8835-004 Methyl methacrylate <3400 U 337 <33 U 3.33 <16 U 8835-004 Methylene chloride <3400 U 337 <33 U 3.33 <16 U 8835-004 o-Xylene <3400 13000 337 <33 290 3.33 <16 U 8835-004 p-Dioxane <3400 U 337 <33 U 3.33 <16 U 8835-004 Pentachloroethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Propionitrile <3400 U 337 <33 U 3.33 <16 U 8835-004 Tetrachloroethene <3400 U 337 <33 U 3.33 <16 U 8835-004 Toluene <3400 69000 337 <33 170 3.33 <16 U 8835-004 trans-1,2-Dichloroethene <3400 U 337 <33 U 3.33 <16 U



## Appendix A - VOC - 4

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-004 trans-1,4-Dichloro-2-butene <3400 U 337 <33 U 3.33 <16 U 8835-004 Trichloroethene <3400 U 337 <33 U 3.33 <16 U 8835-004 Trichlorofluoromethane <3400 U 337 <33 U 3.33 <16 U 8835-004 Vinyl Chloride <3400 U 337 <33 U 3.33 <16 U 8835-005 1,1,2,2-Tetrachloroethane <3200 U 326 <32 U 3.25 <16 U 8835-005 1,1,2-Trichloroethane <3200 U 326 <32 U 3.25 <16 U 8835-005 1,1-Dichloroethene <3200 U 326 <32 U 3.25 <16 U 8835-005 1,2,3,-Trichloropropane <3200 U 326 <32 U 3.25 <16 U 8835-005 1,2,4-Trichlorobenzene <3200 U 326 <32 U 3.25 <16 U 8835-005 1,2-Dibromo-3-chloropropane <3200 U 326 <32 U 3.25 <16 U 8835-005 1,2-Dibromoethane <3200 U 326 <32 U 3.25 <16 U 8835-005 1,2-Dichlorobenzene <3200 U 326 <32 U 3.25 <16 U 8835-005 1,3-Dichlorobenzene <3200 U 326 <32 U 3.25 <16 U 8835-005 1,4-Dichlorobenzene <3200 U 326 <32 U 3.25 <16 U 8835-005 2-Butanone <3200 U 326 <32 U 3.25 <16 U 8835-005 2-Chloroethylvinyl ether <3200 U 326 <32 U 3.25 <16 U 8835-005 Acetonitrile <3200 U 326 <32 U 3.25 <16 U 8835-005 Acrolein <3200 U 326 <32 U 3.25 <16 U 8835-005 Acrylonitrile <3200 U 326 <32 U 3.25 <16 U 8835-005 Allyl chloride <3200 U 326 <32 U 3.25 <16 U 8835-005 Benzene <3200 5400 326 <32 U 3.25 <16 U 8835-005 Bromoform <3200 U 326 <32 U 3.25 <16 U 8835-005 Bromomethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Carbon disulfide <3200 U 326 <32 U 3.25 <16 U 8835-005 Carbon tetrachloride <3200 U 326 <32 U 3.25 <16 U 8835-005 Chlorobenzene <3200 U 326 <32 U 3.25 <16 U 8835-005 Chloroform <3200 U 326 <32 U 3.25 <16 U 8835-005 Chloromethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Chloroprene <3200 U 326 <32 U 3.25 <16 U 8835-005 cis-1,2-Dichloroethene <3200 U 326 <32 U 3.25 <16 U 8835-005 cis-1,3-Dichloropropene <3200 U 326 <32 U 3.25 <16 U 8835-005 cis-1,4-Dichloro-2-butene <3200 U 326 <32 U 3.25 <16 U 8835-005 Dibromomethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Dichlorodifluoromethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Ethyl methacrylate <3200 U 326 <32 U 3.25 <16 U 8835-005 Iodomethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Isobutanol <3200 U 326 <32 U 3.25 <16 U 8835-005 m,p-Xylene <6500 39000 326 <65 360 3.25 <31 U 8835-005 Methacrylonitrile <3200 U 326 <32 U 3.25 <16 U 8835-005 Methyl methacrylate <3200 U 326 <32 U 3.25 <16 U 8835-005 Methylene chloride <3200 U 326 <32 U 3.25 <16 U 8835-005 o-Xylene <3200 14000 326 <32 170 3.25 <16 U 8835-005 p-Dioxane <3200 U 326 <32 U 3.25 <16 U 8835-005 Pentachloroethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Propionitrile <3200 U 326 <32 U 3.25 <16 U 8835-005 Tetrachloroethene <3200 U 326 <32 U 3.25 <16 U 8835-005 Toluene <3200 42000 326 <32 130 3.25 <16 U



## Appendix A - VOC - 5

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-005 trans-1,2-Dichloroethene <3200 U 326 <32 U 3.25 <16 U 8835-005 trans-1,4-Dichloro-2-butene <3200 U 326 <32 U 3.25 <16 U 8835-005 Trichloroethene <3200 U 326 <32 U 3.25 <16 U 8835-005 Trichlorofluoromethane <3200 U 326 <32 U 3.25 <16 U 8835-005 Vinyl Chloride <3200 U 326 <32 U 3.25 <16 U 8835-006 1,1,2,2-Tetrachloroethane <1600 U 161 <34 U 3.44 <21 U 8835-006 1,1,2-Trichloroethane <1600 U 161 <34 U 3.44 <21 U 8835-006 1,1-Dichloroethene <1600 U 161 <34 U 3.44 <21 U 8835-006 1,2,3,-Trichloropropane <1600 U 161 <34 U 3.44 <21 U 8835-006 1,2,4-Trichlorobenzene <1600 U 161 <34 U 3.44 <21 U 8835-006 1,2-Dibromo-3-chloropropane <1600 U 161 <34 U 3.44 <21 U 8835-006 1,2-Dibromoethane <1600 U 161 <34 U 3.44 <21 U 8835-006 1,2-Dichlorobenzene <1600 U 161 <34 U 3.44 <21 U 8835-006 1,3-Dichlorobenzene <1600 U 161 <34 U 3.44 <21 U 8835-006 1,4-Dichlorobenzene <1600 U 161 <34 U 3.44 <21 U 8835-006 2-Butanone <1600 U 161 <34 U 3.44 <21 U 8835-006 2-Chloroethylvinyl ether <1600 U 161 <34 U 3.44 <21 U 8835-006 Acetonitrile <1600 U 161 <34 U 3.44 <21 U 8835-006 Acrolein <1600 U 161 <34 U 3.44 <21 U 8835-006 Acrylonitrile <1600 U 161 <34 U 3.44 <21 U 8835-006 Allyl chloride <1600 U 161 <34 U 3.44 <21 U 8835-006 Benzene <1600 6200 161 <34 U 3.44 <21 U 8835-006 Bromoform <1600 U 161 <34 U 3.44 <21 U 8835-006 Bromomethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Carbon disulfide <1600 U 161 <34 U 3.44 <21 U 8835-006 Carbon tetrachloride <1600 U 161 <34 U 3.44 <21 U 8835-006 Chlorobenzene <1600 U 161 <34 U 3.44 <21 U 8835-006 Chloroform <1600 U 161 <34 U 3.44 <21 U 8835-006 Chloromethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Chloroprene <1600 U 161 <34 U 3.44 <21 U 8835-006 cis-1,2-Dichloroethene <1600 U 161 <34 U 3.44 <21 U 8835-006 cis-1,3-Dichloropropene <1600 U 161 <34 U 3.44 <21 U 8835-006 cis-1,4-Dichloro-2-butene <1600 U 161 <34 U 3.44 <21 U 8835-006 Dibromomethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Dichlorodifluoromethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Ethyl methacrylate <1600 U 161 <34 U 3.44 <21 U 8835-006 Iodomethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Isobutanol <1600 U 161 <34 U 3.44 <21 U 8835-006 m,p-Xylene <3200 22000 161 <69 130 3.44 <42 150 8835-006 Methacrylonitrile <1600 U 161 <34 U 3.44 <21 U 8835-006 Methyl methacrylate <1600 U 161 <34 U 3.44 <21 U 8835-006 Methylene chloride <1600 U 161 <34 U 3.44 <21 U 8835-006 o-Xylene <1600 8300 161 <34 61 3.44 <21 70 8835-006 p-Dioxane <1600 U 161 <34 U 3.44 <21 U 8835-006 Pentachloroethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Propionitrile <1600 U 161 <34 U 3.44 <21 U 8835-006 Tetrachloroethene <1600 U 161 <34 U 3.44 <21 U



## Appendix A - VOC - 6

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-006 Toluene <1600 29000 161 <34 96 3.44 <21 60 8835-006 trans-1,2-Dichloroethene <1600 U 161 <34 U 3.44 <21 U 8835-006 trans-1,4-Dichloro-2-butene <1600 U 161 <34 U 3.44 <21 U 8835-006 Trichloroethene <1600 U 161 <34 U 3.44 <21 U 8835-006 Trichlorofluoromethane <1600 U 161 <34 U 3.44 <21 U 8835-006 Vinyl Chloride <1600 U 161 <34 U 3.44 <21 U 8835-007 1,1,2,2-Tetrachloroethane <1700 U 169 <33 U 3.35 <20 U 8835-007 1,1,2-Trichloroethane <1700 U 169 <33 U 3.35 <20 U 8835-007 1,1-Dichloroethene <1700 U 169 <33 U 3.35 <20 U 8835-007 1,2,3,-Trichloropropane <1700 U 169 <33 U 3.35 <20 U 8835-007 1,2,4-Trichlorobenzene <1700 U 169 <33 U 3.35 <20 U 8835-007 1,2-Dibromo-3-chloropropane <1700 U 169 <33 U 3.35 <20 U 8835-007 1,2-Dibromoethane <1700 U 169 <33 U 3.35 <20 U 8835-007 1,2-Dichlorobenzene <1700 U 169 <33 U 3.35 <20 U 8835-007 1,3-Dichlorobenzene <1700 U 169 <33 U 3.35 <20 U 8835-007 1,4-Dichlorobenzene <1700 U 169 <33 U 3.35 <20 U 8835-007 2-Butanone <1700 U 169 <33 U 3.35 <20 U 8835-007 2-Chloroethylvinyl ether <1700 U 169 <33 U 3.35 <20 U 8835-007 Acetonitrile <1700 U 169 <33 U 3.35 <20 U 8835-007 Acrolein <1700 U 169 <33 U 3.35 <20 U 8835-007 Acrylonitrile <1700 U 169 <33 U 3.35 <20 U 8835-007 Allyl chloride <1700 U 169 <33 U 3.35 <20 U 8835-007 Benzene <1700 4500 169 <33 U 3.35 <20 U 8835-007 Bromoform <1700 U 169 <33 U 3.35 <20 U 8835-007 Bromomethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Carbon disulfide <1700 U 169 <33 U 3.35 <20 U 8835-007 Carbon tetrachloride <1700 U 169 <33 U 3.35 <20 U 8835-007 Chlorobenzene <1700 U 169 <33 U 3.35 <20 U 8835-007 Chloroform <1700 U 169 <33 U 3.35 <20 U 8835-007 Chloromethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Chloroprene <1700 U 169 <33 U 3.35 <20 U 8835-007 cis-1,2-Dichloroethene <1700 U 169 <33 U 3.35 <20 U 8835-007 cis-1,3-Dichloropropene <1700 U 169 <33 U 3.35 <20 U 8835-007 cis-1,4-Dichloro-2-butene <1700 U 169 <33 U 3.35 <20 U 8835-007 Dibromomethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Dichlorodifluoromethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Ethyl methacrylate <1700 U 169 <33 U 3.35 <20 U 8835-007 Iodomethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Isobutanol <1700 U 169 <33 U 3.35 <20 U 8835-007 m,p-Xylene <3400 56000 169 <67 670 3.35 <39 73 8835-007 Methacrylonitrile <1700 U 169 <33 U 3.35 <20 U 8835-007 Methyl methacrylate <1700 U 169 <33 U 3.35 <20 U 8835-007 Methylene chloride <1700 U 169 <33 U 3.35 <20 U 8835-007 o-Xylene <1700 12000 169 <33 320 3.35 <20 33 8835-007 p-Dioxane <1700 U 169 <33 U 3.35 <20 U 8835-007 Pentachloroethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Propionitrile <1700 U 169 <33 U 3.35 <20 U



## Appendix A - VOC - 7

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-007 Tetrachloroethene <1700 U 169 <33 U 3.35 <20 U 8835-007 Toluene <1700 32000 169 <33 240 3.35 <20 29 8835-007 trans-1,2-Dichloroethene <1700 U 169 <33 U 3.35 <20 U 8835-007 trans-1,4-Dichloro-2-butene <1700 U 169 <33 U 3.35 <20 U 8835-007 Trichloroethene <1700 U 169 <33 U 3.35 <20 U 8835-007 Trichlorofluoromethane <1700 U 169 <33 U 3.35 <20 U 8835-007 Vinyl chloride <1700 U 169 <33 U 3.35 <20 U 8835-008 1,1,2,2-Tetrachloroethane <1700 U 170 <33 U 3.35 8835-008 1,1,2-Trichloroethane <1700 U 170 <33 U 3.35 8835-008 1,1-Dichloroethene <1700 U 170 <33 U 3.35 8835-008 1,2,3,-Trichloropropane <1700 U 170 <33 U 3.35 8835-008 1,2,4-Trichlorobenzene <1700 U 170 <33 U 3.35 8835-008 1,2-Dibromo-3-chloropropane <1700 U 170 <33 U 3.35 8835-008 1,2-Dibromoethane <1700 U 170 <33 U 3.35 8835-008 1,2-Dichlorobenzene <1700 U 170 <33 U 3.35 8835-008 1,3-Dichlorobenzene <1700 U 170 <33 U 3.35 8835-008 1,4-Dichlorobenzene <1700 U 170 <33 U 3.35 8835-008 2-Butanone <1700 U 170 <33 U 3.35 8835-008 2-Chloroethylvinyl ether <1700 U 170 <33 U 3.35 8835-008 Acetonitrile <1700 U 170 <33 U 3.35 8835-008 Acrolein <1700 U 170 <33 U 3.35 8835-008 Acrylonitrile <1700 U 170 <33 U 3.35 8835-008 Allyl chloride <1700 U 170 <33 U 3.35 8835-008 Benzene <1700 8000 170 <33 42 3.35 8835-008 Bromoform <1700 U 170 <33 U 3.35 8835-008 Bromomethane <1700 U 170 <33 U 3.35 8835-008 Carbon disulfide <1700 U 170 <33 U 3.35 8835-008 Carbon tetrachloride <1700 U 170 <33 U 3.35 8835-008 Chlorobenzene <1700 U 170 <33 U 3.35 8835-008 Chloroform <1700 U 170 <33 U 3.35 8835-008 Chloromethane <1700 U 170 <33 U 3.35 8835-008 Chloroprene <1700 U 170 <33 U 3.35 8835-008 cis-1,2-Dichloroethene <1700 U 170 <33 U 3.35 8835-008 cis-1,3-Dichloropropene <1700 U 170 <33 U 3.35 8835-008 cis-1,4-Dichloro-2-butene <1700 U 170 <33 U 3.35 8835-008 Dibromomethane <1700 U 170 <33 U 3.35 8835-008 Dichlorodifluoromethane <1700 U 170 <33 U 3.35 8835-008 Ethyl methacrylate <1700 U 170 <33 U 3.35 8835-008 Iodomethane <1700 U 170 <33 U 3.35 8835-008 Isobutanol <1700 U 170 <33 U 3.35 8835-008 m,p-Xylene <3400 28000 170 <67 630 3.35 8835-008 Methacrylonitrile <1700 U 170 <33 U 3.35 8835-008 Methyl methacrylate <1700 U 170 <33 U 3.35 8835-008 Methylene chloride <1700 U 170 <33 U 3.35 8835-008 o-Xylene <1700 10000 170 <33 280 3.35 8835-008 p-Dioxane <1700 U 170 <33 U 3.35 8835-008 Pentachloroethane <1700 U 170 <33 U 3.35



## Appendix A - VOC - 8

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-008 Propionitrile <1700 U 170 <33 U 3.35 8835-008 Tetrachloroethene <1700 U 170 <33 U 3.35 8835-008 Toluene <1700 34000 170 <33 300 3.35 8835-008 trans-1,2-Dichloroethene <1700 U 170 <33 U 3.35 8835-008 trans-1,4-Dichloro-2-butene <1700 U 170 <33 U 3.35 8835-008 Trichloroethene <1700 U 170 <33 U 3.35 8835-008 Trichlorofluoromethane <1700 U 170 <33 U 3.35 8835-008 Vinyl chloride <1700 U 170 <33 U 3.35 8835-009 1,1,2,2-Tetrachloroethane <34 U 3.37 8835-009 1,1,2-Trichloroethane <34 U 3.37 8835-009 1,1-Dichloroethene <34 U 3.37 8835-009 1,2,3,-Trichloropropane <34 U 3.37 8835-009 1,2,4-Trichlorobenzene <34 U 3.37 8835-009 1,2-Dibromo-3-chloropropane <34 U 3.37 8835-009 1,2-Dibromoethane <34 U 3.37 8835-009 1,2-Dichlorobenzene <34 U 3.37 8835-009 1,3-Dichlorobenzene <34 U 3.37 8835-009 1,4-Dichlorobenzene <34 U 3.37 8835-009 2-Butanone <34 U 3.37 8835-009 2-Chloroethylvinyl ether <34 U 3.37 8835-009 Acetonitrile <34 U 3.37 8835-009 Acrolein <34 U 3.37 8835-009 Acrylonitrile <34 U 3.37 8835-009 Allyl chloride <34 U 3.37 8835-009 Benzene <34 U 3.37 8835-009 Bromoform <34 U 3.37 8835-009 Bromomethane <34 U 3.37 8835-009 Carbon disulfide <34 U 3.37 8835-009 Carbon tetrachloride <34 U 3.37 8835-009 Chlorobenzene <34 U 3.37 8835-009 Chloroform <34 U 3.37 8835-009 Chloromethane <34 U 3.37 8835-009 Chloroprene <34 U 3.37 8835-009 cis-1,2-Dichloroethene <34 U 3.37 8835-009 cis-1,3-Dichloropropene <34 U 3.37 8835-009 cis-1,4-Dichloro-2-butene <34 U 3.37 8835-009 Dibromomethane <34 U 3.37 8835-009 Dichlorodifluoromethane <34 U 3.37 8835-009 Ethyl methacrylate <34 U 3.37 8835-009 Iodomethane <34 U 3.37 8835-009 Isobutanol <34 U 3.37 8835-009 m,p-Xylene <67 420 3.37 8835-009 Methacrylonitrile <34 U 3.37 8835-009 Methyl methacrylate <34 U 3.37 8835-009 Methylene chloride <34 U 3.37 8835-009 o-Xylene <34 180 3.37 8835-009 p-Dioxane <34 U 3.37



## Appendix A - VOC - 9

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-009 Pentachloroethane <34 U 3.37 8835-009 Propionitrile <34 U 3.37 8835-009 Tetrachloroethene <34 U 3.37 8835-009 Toluene <34 220 3.37 8835-009 trans-1,2-Dichloroethene <34 U 3.37 8835-009 trans-1,4-Dichloro-2-butene <34 U 3.37 8835-009 Trichloroethene <34 U 3.37 8835-009 Trichlorofluoromethane <34 U 3.37 8835-009 Vinyl Chloride <34 U 3.37 8835-010 1,1,2,2-Tetrachloroethane <32 U 3.23 8835-010 1,1,2-Trichloroethane <32 U 3.23 8835-010 1,1-Dichloroethene <32 U 3.23 8835-010 1,2,3,-Trichloropropane <32 U 3.23 8835-010 1,2,4-Trichlorobenzene <32 U 3.23 8835-010 1,2-Dibromo-3-chloropropane <32 U 3.23 8835-010 1,2-Dibromoethane <32 U 3.23 8835-010 1,2-Dichlorobenzene <32 U 3.23 8835-010 1,3-Dichlorobenzene <32 U 3.23 8835-010 1,4-Dichlorobenzene <32 U 3.23 8835-010 2-Butanone <32 U 3.23 8835-010 2-Chloroethylvinyl ether <32 U 3.23 8835-010 Acetonitrile <32 U 3.23 8835-010 Acrolein <32 U 3.23 8835-010 Acrylonitrile <32 U 3.23 8835-010 Allyl chloride <32 U 3.23 8835-010 Benzene <32 U 3.23 8835-010 Bromoform <32 U 3.23 8835-010 Bromomethane <32 U 3.23 8835-010 Carbon disulfide <32 U 3.23 8835-010 Carbon tetrachloride <32 U 3.23 8835-010 Chlorobenzene <32 U 3.23 8835-010 Chloroform <32 U 3.23 8835-010 Chloromethane <32 U 3.23 8835-010 Chloroprene <32 U 3.23 8835-010 cis-1,2-Dichloroethene <32 U 3.23 8835-010 cis-1,3-Dichloropropene <32 U 3.23 8835-010 cis-1,4-Dichloro-2-butene <32 U 3.23 8835-010 Dibromomethane <32 U 3.23 8835-010 Dichlorodifluoromethane <32 U 3.23 8835-010 Ethyl methacrylate <32 U 3.23 8835-010 Iodomethane <32 U 3.23 8835-010 Isobutanol <32 U 3.23 8835-010 m,p-Xylene <65 410 3.23 8835-010 Methacrylonitrile <32 U 3.23 8835-010 Methyl methacrylate <32 U 3.23 8835-010 Methylene chloride <32 U 3.23 8835-010 o-Xylene <32 180 3.23



## Appendix A - VOC - 10

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-010 p-Dioxane <32 U 3.23 8835-010 Pentachloroethane <32 U 3.23 8835-010 Propionitrile <32 U 3.23 8835-010 Tetrachloroethene <32 U 3.23 8835-010 Toluene <32 170 3.23 8835-010 trans-1,2-Dichloroethene <32 U 3.23 8835-010 trans-1,4-Dichloro-2-butene <32 U 3.23 8835-010 Trichloroethene <32 U 3.23 8835-010 Trichlorofluoromethane <32 U 3.23 8835-010 Vinyl chloride <32 U 3.23 8835-011 1,1,2,2-Tetrachloroethane <39 U 3.92 8835-011 1,1,2-Trichloroethane <39 U 3.92 8835-011 1,1-Dichloroethene <39 U 3.92 8835-011 1,2,3,-Trichloropropane <39 U 3.92 8835-011 1,2,4-Trichlorobenzene <39 U 3.92 8835-011 1,2-Dibromo-3-chloropropane <39 U 3.92 8835-011 1,2-Dibromoethane <39 U 3.92 8835-011 1,2-Dichlorobenzene <39 U 3.92 8835-011 1,3-Dichlorobenzene <39 U 3.92 8835-011 1,4-Dichlorobenzene <39 U 3.92 8835-011 2-Butanone <39 U 3.92 8835-011 2-Chloroethylvinyl ether <39 U 3.92 8835-011 Acetonitrile <39 U 3.92 8835-011 Acrolein <39 U 3.92 8835-011 Acrylonitrile <39 U 3.92 8835-011 Allyl chloride <39 U 3.92 8835-011 Benzene <39 75 3.92 8835-011 Bromoform <39 U 3.92 8835-011 Bromomethane <39 U 3.92 8835-011 Carbon disulfide <39 U 3.92 8835-011 Carbon tetrachloride <39 U 3.92 8835-011 Chlorobenzene <39 U 3.92 8835-011 Chloroform <39 U 3.92 8835-011 Chloromethane <39 U 3.92 8835-011 Chloroprene <39 U 3.92 8835-011 cis-1,2-Dichloroethene <39 U 3.92 8835-011 cis-1,3-Dichloropropene <39 U 3.92 8835-011 cis-1,4-Dichloro-2-butene <39 U 3.92 8835-011 Dibromomethane <39 U 3.92 8835-011 Dichlorodifluoromethane <39 U 3.92 8835-011 Ethyl methacrylate <39 U 3.92 8835-011 Iodomethane <39 U 3.92 8835-011 Isobutanol <39 U 3.92 8835-011 m,p-Xylene <78 900 3.92 8835-011 Methacrylonitrile <39 U 3.92 8835-011 Methyl methacrylate <39 U 3.92 8835-011 Methylene chloride <39 U 3.92



## Appendix A - VOC - 11

# COMPARABLE FUELS RESULTS - VOC (mg/Kg )

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code 8835-011 o-Xylene <39 460 3.92 8835-011 p-Dioxane <39 U 3.92 8835-011 Pentachloroethane <39 U 3.92 8835-011 Propionitrile <39 U 3.92 8835-011 Tetrachloroethene <39 U 3.92 8835-011 Toluene <39 380 3.92 8835-011 trans-1,2-Dichloroethene <39 U 3.92 8835-011 trans-1,4-Dichloro-2-butene <39 U 3.92 8835-011 Trichloroethene <39 U 3.92 8835-011 Trichlorofluoromethane <39 U 3.92 8835-011 Vinyl Chloride <39 U 3.92



## Appendix A - VOC - 12D.F. 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64 1.64



## Appendix A - VOC - 13D.F. 1.64 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66 1.66



## Appendix A - VOC - 14D.F. 1.66 1.66 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61 1.61



## Appendix A - VOC - 15D.F. 1.61 1.61 1.61 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62 1.62



## Appendix A - VOC - 16D.F. 1.62 1.62 1.62 1.62 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57 1.57



## Appendix A - VOC - 17D.F. 1.57 1.57 1.57 1.57 1.57 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08



## Appendix A - VOC - 18D.F. 2.08 2.08 2.08 2.08 2.08 2.08 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95 1.95



## Appendix A - VOC - 19D.F. 1.95 1.95 1.95 1.95 1.95 1.95 1.95



## Appendix A - VOC - 20D.F.



## Appendix A - VOC - 21D.F.



## Appendix A - VOC - 22D.F.



## Appendix A - VOC - 23D.F.



## Appendix A - VOC - 24

# COMPARATIVE FUELS RESULTS - METALS (mg/L)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Method Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-001 7040 Antimony <6.67 BQL U 13.35 <5.84 BQL U 11.68 <11.47 BQL U 22.94 <10.19 BQL U 20.39 8835-001 7060 Arsenic <0.13 BQL U 13.35 <0.12 BQL U 11.68 <0.23 BQL U 22.94 <0.20 BQL U 20.39 8835-001 7080 Barium <13.35 BQL U 13.35 <11.68 BQL U 11.68 <22.94 BQL U 22.94 <20.39 BQL U 20.39 8835-001 7090 Beryllium <0.67 BQL U 13.35 <0.58 BQL U 11.68 <1.15 BQL U 22.94 <1.02 BQL U 20.39 8835-001 7130 Cadmium <0.67 BQL U 13.35 <0.58 BQL U 11.68 <1.15 BQL U 22.94 <1.02 BQL U 20.39 8835-001 7190 Chromium <1.34 BQL U 13.35 <1.17 BQL U 11.68 <2.29 BQL U 22.94 <2.04 BQL U 20.39 8835-001 7420 Lead <6.67 BQL U 13.35 <5.84 13.1 11.68 <11.47 19.2 22.94 <10.19 31.4 20.39 8835-001 7460 Manganese <0.67 BQL U 13.35 <0.58 BQL U 11.68 <1.15 BQL U 22.94 <1.02 BQL U 20.39 8835-001 7470 Mercury <0.10 BQL U 1.00 <0.10 BQL U 1.00 <0.18 BQL U 1.00 <0.17 BQL U 1.00 8835-001 7520 Nickel <2.67 BQL U 13.35 <2.34 BQL U 11.68 <4.59 31.9 22.94 <4.08 106 20.39 8835-001 7740 Selenium <0.13 BQL U 13.35 <0.12 BQL U 11.68 <0.23 0.25 22.94 <0.20 0.28 20.39 8835-001 7760 Silver <1.33 BQL U 13.35 <1.17 BQL U 11.68 <2.29 BQL U 22.94 <2.04 BQL U 20.39 8835-001 7840 Thallium <13.35 BQL U 13.35 <11.68 BQL U 11.68 <22.94 BQL U 22.94 <20.39 BQL U 20.39 8835-002 7040 Antimony <6.66 BQL U 13.32 <5.83 BQL U 11.67 <10.14 BQL U 20.28 8835-002 7060 Arsenic <0.13 BQL U 13.32 <0.12 BQL U 11.67 <0.20 BQL U 20.28 8835-002 7080 Barium <13.32 BQL U 13.32 <11.67 BQL U 11.67 <20.28 BQL U 20.28 8835-002 7090 Beryllium <0.66 BQL U 13.32 <0.58 BQL U 11.67 <1.01 BQL U 20.28 8835-002 7130 Cadmium <0.66 BQL U 13.32 <0.58 BQL U 11.67 <1.01 BQL U 20.28 8835-002 7190 Chromium <1.33 BQL U 13.32 <1.17 BQL U 11.67 <2.03 BQL U 20.28 8835-002 7420 Lead <6.66 BQL U 13.32 <5.83 10.4 11.67 <10.14 40.4 20.28 8835-002 7460 Manganese <0.66 BQL U 13.32 <0.59 BQL U 11.67 <1.01 BQL U 20.28 8835-002 7470 Mercury <0.10 BQL U 1.00 <0.10 BQL U 1.00 <0.17 BQL U 1.00 8835-002 7520 Nickel <2.66 BQL U 13.32 <2.33 BQL U 11.67 <4.06 6.8 20.28 8835-002 7740 Selenium <0.13 BQL U 13.32 <0.12 0.18 11.67 <0.20 BQL U 20.28 8835-002 7760 Silver <1.33 BQL U 13.32 <1.17 BQL U 11.67 <2.03 BQL U 20.28 8835-002 7840 Thallium <13.32 BQL U 13.32 <11.67 BQL U 11.67 <20.28 BQL U 20.28 8835-003 7040 Antimony <6.67 BQL U 13.35 <5.94 BQL U 11.88 <10.10 BQL U 20.20 8835-003 7060 Arsenic <0.13 BQL U 13.35 <0.12 BQL U 11.88 <0.20 BQL U 20.20 8835-003 7080 Barium <13.35 BQL U 13.35 <11.88 BQL U 11.88 <20.20 BQL U 20.20 8835-003 7090 Beryllium <0.67 BQL U 13.35 <0.59 BQL U 11.88 <1.01 BQL U 20.20 8835-003 7130 Cadmium <0.67 BQL U 13.35 <0.59 BQL U 11.88 <1.01 BQL U 20.20 8835-003 7190 Chromium <1.33 BQL U 13.35 <1.19 BQL U 11.88 <2.02 BQL U 20.20 8835-003 7420 Lead <6.67 BQL U 13.35 <5.94 9.26 11.88 <10.10 40.5 20.20 8835-003 7460 Manganese <0.67 BQL U 13.35 <0.59 BQL U 11.88 <1.01 BQL U 20.20 8835-003 7470 Mercury <0.10 BQL U 1.00 <0.11 BQL U 1.00 <0.17 BQL U 1.00 8835-003 7520 Nickel <2.67 BQL U 13.35 <2.38 BQL U 11.88 <4.04 6.81 20.20 8835-003 7740 Selenium <0.134 BQL U 13.35 <0.12 BQL U 11.88 <0.20 BQL U 20.20 8835-003 7760 Silver <1.34 BQL U 13.35 <1.19 BQL U 11.88 <2.02 BQL U 20.20 8835-003 7840 Thallium <13.35 BQL U 13.35 <11.88 BQL U 11.88 <20.20 BQL U 20.20 8835-004 7040 Antimony <6.67 BQL U 13.33 <5.96 BQL U 11.92 <10.11 BQL U 20.22 8835-004 7060 Arsenic <0.13 BQL U 13.33 <0.12 BQL U 11.92 <0.20 BQL U 20.22 8835-004 7080 Barium <13.33 BQL U 13.33 <11.92 BQL U 11.92 <20.22 BQL U 20.22



### Appendix A - Metals - 1

# COMPARATIVE FUELS RESULTS - METALS (mg/L)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Method Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-004 7090 Beryllium <0.67 BQL U 13.33 <0.60 BQL U 11.92 <1.01 BQL U 20.22 8835-004 7130 Cadmium <0.67 BQL U 13.33 <0.60 BQL U 11.92 <1.01 BQL U 20.22 8835-004 7190 Chromium <1.33 BQL U 13.33 <1.19 BQL U 11.92 <2.02 BQL U 20.22 8835-004 7420 Lead <6.67 BQL U 13.33 <5.96 6.73 11.92 <10.11 54.2 20.22 8835-004 7460 Manganese <0.66 BQL U 13.33 <0.60 BQL U 11.92 <1.01 BQL U 20.22 8835-004 7470 Mercury <0.10 BQL U 1.00 <0.10 BQL U 1.00 <0.14 BQL U 1.00 8835-004 7520 Nickel <2.67 BQL U 13.33 <2.38 BQL U 11.92 <4.04 5.86 20.22 8835-004 7740 Selenium <0.13 BQL U 13.33 <0.12 BQL U 11.92 <0.20 BQL U 20.22 8835-004 7760 Silver <1.33 BQL U 13.33 <1.19 BQL U 11.92 <2.02 BQL U 20.22 8835-004 7840 Thallium <13.33 BQL U 13.33 <11.92 BQL U 11.92 <20.22 BQL U 20.22 8835-005 7040 Antimony <6.71 BQL U 13.42 <5.94 BQL U 11.89 <10.06 15.7 20.12 8835-005 7060 Arsenic <0.13 BQL U 13.42 <0.12 BQL U 11.89 <0.20 BQL U 20.12 8835-005 7080 Barium <13.42 BQL U 13.42 <11.89 BQL U 11.89 <20.12 BQL U 20.12 8835-005 7090 Beryllium <0.67 BQL U 13.42 <0.59 BQL U 11.89 <1.01 BQL U 20.12 8835-005 7130 Cadmium <0.67 BQL U 13.42 <0.59 BQL U 11.89 <1.01 BQL U 20.12 8835-005 7190 Chromium <1.34 BQL U 13.42 <1.19 BQL U 11.89 <2.01 BQL U 20.12 8835-005 7420 Lead <6.71 BQL U 13.42 <5.94 10.1 11.89 <10.06 56.8 20.12 8835-005 7460 Manganese <0.67 BQL U 13.42 <0.59 BQL U 11.89 <1.01 BQL U 20.12 8835-005 7470 Mercury <0.10 BQL U 1.00 <0.09 BQL U 1.00 <0.20 BQL U 1.00 8835-005 7520 Nickel <2.68 BQL U 13.42 <2.38 BQL U 11.89 <4.02 6.1 20.12 8835-005 7740 Selenium <0.13 BQL U 13.42 <1.19 BQL U 11.89 <2.01 BQL U 20.12 8835-005 7760 Silver <1.34 BQL U 13.42 <0.12 BQL U 11.89 <0.20 BQL U 20.12 8835-005 7840 Thallium <13.42 BQL U 13.42 <11.89 BQL U 11.89 <20.12 BQL U 20.12 8835-006 7040 Antimony <7.05 BQL U 14.10 <5.85 BQL U 11.71 <10.20 BQL U 20.41 8835-006 7060 Arsenic <0.14 BQL U 14.10 <0.12 BQL U 11.71 <0.20 BQL U 20.41 8835-006 7080 Barium <14.10 BQL U 14.10 <11.71 BQL U 11.71 <20.41 BQL U 20.41 8835-006 7090 Beryllium <0.70 BQL U 14.10 <0.58 BQL U 11.71 <1.02 BQL U 20.41 8835-006 7130 Cadmium <0.70 BQL U 14.10 <0.58 BQL U 11.71 <1.02 BQL U 20.41 8835-006 7190 Chromium <1.41 BQL U 14.10 <1.17 BQL U 11.71 <2.04 BQL U 20.41 8835-006 7420 Lead <7.05 BQL U 14.10 <5.85 8.47 11.71 <10.20 35.4 20.41 8835-006 7460 Manganese <0.70 BQL U 14.10 <0.58 BQL U 11.71 <1.02 BQL U 20.41 8835-006 7470 Mercury <0.10 BQL U 1.00 <0.10 BQL U 1.00 <0.25 BQL U 1.00 8835-006 7520 Nickel <2.82 BQL U 14.10 <2.34 BQL U 11.71 <4.08 50.2 20.41 8835-006 7740 Selenium <0.14 BQL U 14.10 <0.12 0.15 11.71 <0.20 BQL U 20.41 8835-006 7760 Silver <1.41 BQL U 14.10 <1.17 BQL U 11.71 <2.04 BQL U 20.41 8835-006 7840 Thallium <14.10 BQL U 14.10 <11.71 BQL U 11.71 <20.41 BQL U 20.41 8835-007 7040 Antimony <6.84 BQL U 13.68 <0.05 BQL U 0.10 <10.11 BQL U 20.22 8835-007 7060 Arsenic <0.14 BQL U 13.68 <0.12 BQL U 11.76 <0.20 BQL U 20.22 8835-007 7080 Barium <13.68 BQL U 13.68 <0.10 BQL U 0.10 <20.22 BQL U 20.22 8835-007 7090 Beryllium <0.68 BQL U 13.68 <0.005 BQL U 0.10 <1.01 BQL U 20.22 8835-007 7130 Cadmium <0.68 BQL U 13.68 <0.005 BQL U 0.10 <1.01 BQL U 20.22 8835-007 7190 Chromium <1.37 BQL U 13.68 <0.010 BQL U 0.10 <2.02 BQL U 20.22



### Appendix A - Metals - 2

# COMPARATIVE FUELS RESULTS - METALS (mg/L)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Method Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-007 7420 Lead <6.84 BQL U 13.68 <0.051 0.1 0.10 <10.11 36.1 20.22 8835-007 7460 Manganese <0.68 BQL U 13.68 <0.005 BQL U 0.10 <1.011 BQL U 20.22 8835-007 7470 Mercury <0.10 BQL U 1.00 <0.10 BQL U 1.00 <0.13 BQL U 1.00 8835-007 7520 Nickel <2.74 BQL U 13.68 <0.020 BQL U 0.10 <4.04 49.5 20.22 8835-007 7740 Selenium <0.14 BQL U 13.68 <0.12 BQL U 11.76 <0.20 BQL U 20.22 8835-007 7760 Silver <1.37 BQL U 13.68 <0.010 BQL U 0.10 <2.02 BQL U 20.22 8835-007 7840 Thallium <13.68 BQL U 13.68 <0.10 BQL U 0.10 <20.22 BQL U 20.22 8835-008 7040 Antimony <6.92 BQL U 13.85 <5.97 BQL U 11.95 8835-008 7060 Arsenic <0.14 BQL U 13.85 <0.12 BQL U 11.95 8835-008 7080 Barium <13.85 BQL U 13.85 <11.95 BQL U 11.95 8835-008 7090 Beryllium <0.69 BQL U 13.85 <0.60 BQL U 11.95 8835-008 7130 Cadmium <0.69 BQL U 13.85 <060 BQL U 11.95 8835-008 7190 Chromium <1.38 BQL U 13.85 <1.19 BQL U 11.95 8835-008 7420 Lead <6.92 BQL U 13.85 <5.97 8.12 11.95 8835-008 7460 Manganese <0.69 BQL U 13.85 <0.60 BQL U 11.95 8835-008 7470 Mercury <0.10 BQL U 1.00 <0.10 BQL U 1.00 8835-008 7520 Nickel <2.77 BQL U 13.85 <2.39 BQL U 11.95 8835-008 7740 Selenium <0.14 BQL U 13.85 <0.12 BQL U 11.95 8835-008 7760 Silver <1.38 BQL U 13.85 <1.19 BQL U 11.95 8835-008 7840 Thallium <13.85 BQL U 13.85 <11.95 BQL U 11.95 8835-009 7040 Antimony <6.01 BQL U 12.02 8835-009 7060 Arsenic <0.12 BQL U 12.02 8835-009 7080 Barium <12.02 BQL U 12.02 8835-009 7090 Beryllium <0.60 BQL U 12.02 8835-009 7130 Cadmium <0.60 BQL U 12.02 8835-009 7190 Chromium <1.20 BQL U 12.02 8835-009 7420 Lead <6.01 7.6 12.02 8835-009 7460 Manganese <0.60 BQL U 12.02 8835-009 7470 Mercury <0.11 BQL U 1.00 8835-009 7520 Nickel <2.40 BQL U 12.02 8835-009 7740 Selenium <0.12 BQL U 12.02 8835-009 7760 Silver <1.20 BQL U 12.02 8835-009 7840 Thallium <12.02 BQL U 12.02 8835-010 7040 Antimony <5.98 BQL U 11.96 8835-010 7060 Arsenic <0.12 BQL U 11.96 8835-010 7080 Barium <11.96 BQL U 11.96 8835-010 7090 Beryllium <0.60 BQL U 11.96 8835-010 7130 Cadmium <0.60 BQL U 11.96 8835-010 7190 Chromium <1.20 BQL U 11.96 8835-010 7420 Lead <5.98 7.79 11.96 8835-010 7460 Manganese <0.60 BQL U 11.96 8835-010 7470 Mercury <0.10 BQL U 1.00



### Appendix A - Metals - 3

# COMPARATIVE FUELS RESULTS - METALS (mg/L)

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6 Sample Method Analyte Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. Q.L. Quantitation Code D.F. 8835-010 7520 Nickel <2.39 BQL U 11.96 8835-010 7740 Selenium <0.12 BQL U 11.96 8835-010 7760 Silver <1.20 BQL U 11.96 8835-010 7840 Thallium <11.96 BQL U 11.96 8835-011 7040 Antimony <11.67 BQL U 23.34 8835-011 7060 Arsenic <0.12 BQL U 11.67 8835-011 7080 Barium <23.34 BQL U 23.34 8835-011 7090 Beryllium <1.17 BQL U 23.34 8835-011 7130 Cadmium <1.17 BQL U 23.34 8835-011 7190 Chromium <2.33 BQL U 23.34 8835-011 7420 Lead <11.67 19.7 23.34 8835-011 7460 Manganese <1.17 BQL U 23.34 8835-011 7470 Mercury <0.10 BQL U 1.00 8835-011 7520 Nickel <4.67 BQL U 23.34 8835-011 7740 Selenium <0.12 BQL U 11.67 8835-011 7760 Silver <2.33 BQL U 23.34 8835-011 7840 Thallium <23.34 BQL U 23.34



### Appendix A - Metals - 4

# COMPARATIVE FUELS RESULTS - PHYSICAL PARAMETERS

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Method Analyte Quantitation D.F. Quantitation D.F. Quantitation D.F. Quantitation D.F. 

### 8835-001 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 < 10 1 8835-001 ASTM D240 Heating Value* (BTU/lb) 19506 1 19583 1 19425 1 18354 1 8835-001 ASTM D1298 Specific Gravity (@ 60 F) 0.759 1 0.864 1 0.892 1 0.988 1 8835-001 ASTM D4629 Total Nitrogen as N 8 1 203 1 2930 1 8950 1 8835-001 SW-846 1010 Flash Point (F) < 0 1 54 1 66 1 81 1 8835-001 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 2.91 1 6.4 1 531 1 8835-002 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 8835-002 ASTM D240 Heating Value* (BTU/lb) 19394 1 19610 1 18715 1 8835-002 ASTM D1298 Specific Gravity (@ 60 F) 0.761 1 0.864 1 0.995 1 8835-002 ASTM D4629 Total Nitrogen as N 8 1 213 1 1860 1 8835-002 SW-846 1010 Flash Point (F) < 0 1 53.5 1 68.5 1 8835-002 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 2.87 1 98 1 8835-003 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 8835-003 ASTM D240 Heating Value* (BTU/lb) 19682 1 19823 1 18410 1 8835-003 ASTM D1298 Specific Gravity (@ 60 F) 0.761 1 0.85 1 0.995 1 8835-003 ASTM D4629 Total Nitrogen as N 6 1 110 1 1820 1 8835-003 SW-846 1010 Flash Point (F) < 0 1 48 1 73 1 8835-003 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 2.66 1 98 1 8835-004 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 8835-004 ASTM D240 Heating Value* (BTU/lb) 19420 1 19755 1 18219 1 8835-004 ASTM D1298 Specific Gravity (@ 60 F) 0.762 1 0.85 1 1.04 1 8835-004 ASTM D4629 Total Nitrogen as N 6 1 104 1 2210 1 8835-004 SW-846 1010 Flash Point (F) < 0 1 44.5 1 117 1 8835-004 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 2.73 1 322 1 8835-005 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 8835-005 ASTM D240 Heating Value* (BTU/lb) 19189 1 19763 1 18138 1 8835-005 ASTM D1298 Specific Gravity (@ 60 F) 0.758 1 0.851 1 1.04 1 8835-005 ASTM D4629 Total Nitrogen as N 22 1 186 1 2150 1 8835-005 SW-846 1010 Flash Point (F) < 0 1 47.5 1 112 1 8835-005 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 3.5 1 331 1 8835-006 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 8835-006 ASTM D240 Specific Gravity (@ 60 F) 19924 1 19891 1 18622 1 8835-006 ASTM D1298 Specific Gravity (@ 60 F) 0.721 1 0.862 1 0.991 1 8835-006 ASTM D4629 Total Nitrogen as N 11 1 341 1 5260 1 8835-006 SW-846 1010 Flash Point (F) < 0 1 77 1 82 1 8835-006 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 4.36 1 656 1



## Appendix A - Physical Parameters - 1

# COMPARATIVE FUELS RESULTS - PHYSICAL PARAMETERS

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Method Analyte Quantitation D.F. Quantitation D.F. Quantitation D.F. Quantitation D.F. 

### 8835-007 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 < 10 1 8835-007 ASTM D240 Heating Value* (BTU/lb) 19373 1 19570 1 18559 1 8835-007 ASTM D1298 Specific Gravity (@ 60 F) 0.744 1 0.859 1 0.99 1 8835-007 ASTM D4629 Total Nitrogen as N 12 1 165 1 5310 1 8835-007 SW-846 1010 Flash Point (F) < 0 1 60 1 92.5 1 8835-007 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 2.34 1 668 1 8835-008 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 < 25 1 8835-008 ASTM D240 Heating Value* (BTU/lb) 19552 1 19865 1 8835-008 ASTM D1298 Specific Gravity (@ 60 F) 0.733 1 0.846 1 8835-008 ASTM D4629 Total Nitrogen as N 17 1 98 1 8835-008 SW-846 1010 Flash Point (F) < 0 1 61.5 1 8835-008 ASTM D445 Kinematic Viscosity (cSt @ 100 F) N/A 2.6 1 8835-009 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 8835-009 ASTM D240 Heating Value* (BTU/lb) 19942 1 8835-009 ASTM D1298 Specific Gravity (@ 60 F) 0.851 1 8835-009 ASTM D4629 Total Nitrogen as N 43 1 8835-009 SW-846 1010 Flash Point (F) 72 1 8835-009 ASTM D445 Kinematic Viscosity (cSt @ 100 F) 3.49 1 8835-010 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 8835-010 ASTM D240 Heating Value* (BTU/lb) 20000 1 8835-010 ASTM D1298 Specific Gravity (@ 60 F) 0.853 1 8835-010 ASTM D4629 Total Nitrogen as N 42 1 8835-010 SW-846 1010 Flash Point (F) 71 1 8835-010 ASTM D445 Kinematic Viscosity (cSt @ 100 F) 3.71 1 8835-011 EPA 325.3/Parr Total Halogens as Cl- (ppmw) < 25 1 8835-011 ASTM D240 Heating Value* (BTU/lb) 19745 1 8835-011 ASTM D1298 Specific Gravity (@ 60 F) 0.86 1 8835-011 ASTM D4629 Total Nitrogen as N 219 1 8835-011 SW-846 1010 Flash Point (F) 58 1 8835-011 ASTM D445 Kinematic Viscosity (cSt @ 100 F) 2.87 1

N/A - Not Applicable



## Appendix A - Physical Parameters - 2

# COMPARABLE FUELS RESULTS - TOTAL AROMATIC HYDROCARBONS

Fuel = Gasoline Fuel = No.2 Fuel = No.4 Fuel = No.6

Sample Analyte Quantitation DF Quantitation DF Quantitation DF Quantitation DF 

### 8835-001 Total Aromatic Hydrocarbons (Weight Percent) 15.6 1.0 2.78 1.0 0.97 1.0 0.37 1.0 8835-002 Total Aromatic Hydrocarbons (Weight Percent) 15.5 1.0 2.95 1.0 1.4 1.0 8835-003 Total Aromatic Hydrocarbons (Weight Percent) 16.9 1.0 1.53 1.0 1.42 1.0 8835-004 Total Aromatic Hydrocarbons (Weight Percent) 17.2 1.0 2.06 1.0 0.36 1.0 8835-005 Total Aromatic Hydrocarbons (Weight Percent) 12.6 1.0 2.19 1.0 0.41 1.0 8835-006 Total Aromatic Hydrocarbons (Weight Percent) 8.1 1.0 0.66 1.0 2.99 1.0 8835-007 Total Aromatic Hydrocarbons (Weight Percent) 12.9 1.0 5.24 1.0 0.85 1.0 8835-008 Total Aromatic Hydrocarbons (Weight Percent) 10.5 1.0 1.36 1.0 8835-009 Total Aromatic Hydrocarbons (Weight Percent) 1.29 1.0 8835-010 Total Aromatic Hydrocarbons (Weight Percent) 1.42 1.0 8835-011 Total Aromatic Hydrocarbons (Weight Percent) 1.22 1.0 8835-001 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.7 1.0 2.9 1.0 1.0 1.0 0.39 1.0 8835-002 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.7 1.0 3.09 1.0 1.5 1.0 8835-003 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.8 1.0 1.52 1.0 1.52 1.0 8835-004 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.9 1.0 2.08 1.0 0.42 1.0 8835-005 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.3 1.0 2.35 1.0 0.49 1.0 8835-006 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.3 1.0 0.7 1.0 3.15 1.0 8835-007 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.6 1.0 5.47 1.0 0.89 1.0 8835-008 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 0.6 1.0 1.41 1.0 8835-009 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 1.36 1.0 8835-010 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 1.5 1.0 8835-011 Total Polynuclear Aromatic Hydrocarbons (Weight Percent) 1.22 1.0



## Appendix A - Aromatic Hydrocarbons - 1

# Appendix B

Constituent Levels

# B-1

Appendix B: Comparable Fuel Specification

Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg) Total Nitrogen as N NA 9000 18400 4900

- Total Halogens as Cl NA 1000 18400 540

- Total Organic Halogens as Cl NA 25 or individual halogenated organics listed below -

Polychlorinated biphenyls, total [Arocolors, total] a 

## 1336-36-3 ND non-detect 1.4
Cyanide, total 57-12-5 ND non-detect 1.0 Metals Antimony, total 7440-36-0 ND 7.9

- Arsenic, total 7440-38-2 ND 0.23

- Barium, total 7440-39-3 ND 23

- Beryllium, total 7440-41-7 ND 1.2

- Cadmium, total 7440-43-9 ND 1.2

- Chromium, total 7440-47-3 ND 2.3

- Cobalt 7440-48-4 ND 4.6

- Lead, total 7439-92-1 57 18100 31

- Manganese 7439-96-5 ND 1.2

- Mercury, total 7439-97-6 ND 0.24

- Nickel, total 7440-02-0 106 18400 58

- Selenium, total 7782-49-2 0.28 18400 0.15

- Silver, total 7440-22-4 ND 2.3

- Thallium, total 7440-28-0 ND 23

- Hydrocarbons Benzo[a]anthracene 56-55-3 ND 1100

- Benzene 71-43-2 8000 19600 4100

- Benzo[b]fluoranthene 205-99-2 ND 960

- Benzo[k]fluoranthene 207-08-9 ND 1900

- Benzo[a]pyrene 50-32-8 ND 960

- Chrysene 218-01-9 ND 1400

- Dibenzo[a,h]anthracene 53-70-3 ND 960

- 7,12-Dimethylbenz[a]anthracene 57-97-6 ND 1900

- Fluoranthene 206-44-0 ND 1900

- Indeno(1,2,3-cd)pyrene 193-39-5 ND 960

- 3-Methylcholanthrene 56-49-5 ND 1900

- Naphthalene 91-20-3 6200 19400 3200

-

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-2 Toluene 108-88-3 69000 19400 36000

- Oxygenates Acetophenone 98-86-2 ND 1900

- Acrolein 107-02-8 ND 37

- Allyl alcohol 107-18-6 ND 30

- Bis(2-ethylhexyl)phthalate [Di-2-ethylhexyl phthalate] 117-81-7 ND 1900

- Butyl benzyl phthalate 85-68-7 ND 1900

- o-Cresol [2-Methyl phenol] 95-48-7 ND 220

- m-Cresol [3-Methyl phenol] 108-39-4 ND 220

- p-Cresol [4-Methyl phenol] 106-44-5 ND 220

- Di-n-butyl phthalate 84-74-2 ND 1900

- Diethyl phthalate 84-66-2 ND 1900

- 2,4-Dimethylphenol 105-67-9 ND 1900

- Dimethyl phthalate 131-11-3 ND 1900

- Di-n-octyl phthalate 117-84-0 ND 960

- Endothall 145-73-3 ND 100

- Ethyl methacrylate 97-63-2 ND 37

- 2-Ethoxyethanol [Ethylene glycol monoethyl ether] 110-80-5 ND 100

- Isobutyl alcohol 78-83-1 ND 37

- Isosafrole 120-58-1 ND 1900

- Methyl ethyl ketone [2-Butanone] 78-93-3 ND 37

- Methyl methacrylate 80-62-6 ND 37

- 1,4-Naphthoquinone 130-15-4 ND 1900

- Phenol 108-95-2 ND 1900

- Propargyl alcohol [2-Propyn-1-ol] 107-19-7 ND 30

- Safrole 94-59-7 ND 1900

- Sulfonated Organics Carbon disulfide 75-15-0 ND non-detect 37 Disulfoton 298-04-4 ND non-detect 1900 Ethyl methanesulfonate 62-50-0 ND non-detect 1900 Methyl methanesulfonate 66-27-3 ND non-detect 1900 Phorate 298-02-2 ND non-detect 1900 1,3-Propane sultone 1120-71-4 ND non-detect 100 Tetraethyldithiopyrophosphate [Sulfotepp] 3689-24-5 ND non-detect 1900
Thiophenol [Benzenethiol] 108-98-5 ND non-detect 30

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-3 O,O,O-Triethyl phosphorothioate 126-68-1 ND non-detect 1900 Nitrogenated Organics Acetonitrile [Methyl cyanide] 75-05-8 ND non-detect 37 2-Acetylaminofluorene [2-AAF] 53-96-3 ND non-detect 1900 Acrylonitrile 107-13-1 ND non-detect 37 4-Aminobiphenyl 92-67-1 ND non-detect 1900 4-Aminopyridine 504-24-5 ND non-detect 100 Aniline 62-53-3 ND non-detect 1900 Benzidine 92-87-5 ND non-detect 1900 Dibenz[a,j]acridine 224-42-0 ND non-detect 1900 O,O-Diethyl O-pyrazinyl phophoro- thioate [Thionazin] 297-97-2 ND non-detect 1900

Dimethoate 60-51-5 ND non-detect 1900 p-(Dimethylamino)azobenzene [4-Dimethylaminoazobenzene] 60-11-7 ND non-detect 1900

3,3'-Dimethylbenzidine 119-93-7 ND non-detect 1900

, -Dimethylphenethylamine 122-09-8 ND non-detect 1900 3,3'-Dimethoxybenzidine 119-90-4 ND non-detect 100 1,3-Dinitrobenzene [m-Dinitrobenzene] 99-65-0 ND non-detect 1900

4,6-Dinitro-o-cresol 534-52-1 ND non-detect 1900 2,4-Dinitrophenol 51-28-5 ND non-detect 1900 2,4-Dinitrotoluene 121-14-2 ND non-detect 1900 2,6-Dinitrotoluene 606-20-2 ND non-detect 1900 Dinoseb [2-sec-Butyl-4,6-dinitrophenol] 88-85-7 ND non-detect 1900

Diphenylamine 122-39-4 ND non-detect 1900 Ethyl carbamate [Urethane] 51-79-6 ND non-detect 100 Ethylenethiourea (2- Imidazolidinethione) 96-45-7 ND non-detect 110

Famphur 52-85-7 ND non-detect 1900 Methacrylonitrile 126-98-7 ND non-detect 37 Methapyrilene 91-80-5 ND non-detect 1900 Methomyl 16752-77-5 ND non-detect 57 2-Methyllactonitrile [Acetone cyanohydrin] 75-86-5 ND non-detect 100

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-4 Methyl parathion 298-00-0 ND non-detect 1900 MNNG (N-Metyl-N-nitroso-N'- nitroguanidine) 70-25-7 ND non-detect 110

1-Naphthylamine, [ -Naphthylamine] 134-32-7 ND non-detect 1900

2-Naphthylamine, [ -Naphthylamine] 91-59-8 ND non-detect 1900

Nicotine 54-11-5 ND non-detect 100 4-Nitroaniline, [p-Nitroaniline] 100-01-6 ND non-detect 1900 Nitrobenzene 98-95-3 ND non-detect 1900 p-Nitrophenol, [p-Nitrophenol] 100-02-7 ND non-detect 1900 5-Nitro-o-toluidine 99-55-8 ND non-detect 1900 N-Nitrosodi-n-butylamine 924-16-3 ND non-detect 1900 N-Nitrosodiethylamine 55-18-5 ND non-detect 1900 N-Nitrosodiphenylamine, [Diphenylnitrosamine] 86-30-6 ND non-detect 1900

N-Nitroso-N-methylethylamine 10595-95-6 ND non-detect 1900 N-Nitrosomorpholine 59-89-2 ND non-detect 1900 N-Nitrosopiperidine 100-75-4 ND non-detect 1900 N-Nitrosopyrrolidine 930-55-2 ND non-detect 1900 2-Nitropropane 79-46-9 ND non-detect 30 Parathion 56-38-2 ND non-detect 1900 Phenacetin 62-44-2 ND non-detect 1900 1,4-Phenylene diamine, [p-Phenylenediamine] 106-50-3 ND non-detect 1900

N-Phenylthiourea 103-85-5 ND non-detect 57 2-Picoline [alpha-Picoline] 109-06-8 ND non-detect 1900 Propythioracil [6-Propyl-2-thiouracil] 51-52-5 ND non-detect 100

Pyridine 110-86-1 ND non-detect 1900 Strychnine 57-24-9 ND non-detect 100 Thioacetamide 62-55-5 ND non-detect 57 Thiofanox 39196-18-4 ND non-detect 100 Thiourea 62-56-6 ND non-detect 57 Toluene-2,4-diamine [2,4-Diaminotoluene] 95-80-7 ND non-detect 57

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-5 Toluene-2,6-diamine [2,6-Diaminotoluene] 823-40-5 ND non-detect 57

o-Toluidine 95-53-4 ND non-detect 2200 p-Toluidine 106-49-0 ND non-detect 100 1,3,5-Trinitrobenzene, [sym-Trinitobenzene] 99-35-4 ND non-detect 2000

Halogenated Organics Allyl chloride 107-05-1 ND non-detect 37 Aramite 140-57-8 ND non-detect 1900 Benzal chloride [Dichloromethyl benzene] 98-87-3 ND non-detect 100

Benzyl chloride 100-44-77 ND non-detect 100 Bis(2-chloroethyl)ether [Dichoroethyl ether] 111-44-4 ND non-detect 1900

Bromoform [Tribromomethane] 75-25-2 ND non-detect 37 Bromomethane [Methyl bromide] 74-83-9 ND non-detect 37 4-Bromophenyl phenyl ether [p-Bromo diphenyl ether] 101-55-3 ND non-detect 1900

Carbon tetrachloride 56-23-5 ND non-detect 37 Chlordane 57-74-9 ND non-detect 14 p-Chloroaniline 106-47-8 ND non-detect 1900 Chlorobenzene 108-90-7 ND non-detect 37 Chlorobenzilate 510-15-6 ND non-detect 1900 p-Chloro-m-cresol 59-50-7 ND non-detect 1900 2-Chloroethyl vinyl ether 110-75-8 ND non-detect 37 Chloroform 67-66-3 ND non-detect 37 Chloromethane [Methyl chloride] 74-87-3 ND non-detect 37 2-Chloronaphthalene [beta-Chloronaphthalene] 91-58-7 ND non-detect 1900

2-Chlorophenol [o-Chlorophenol] 95-57-8 ND non-detect 1900 Chloroprene [2-Chloro-1,3-butadiene] 1126-99-8 ND non-detect 37

2,4-D [2,4-Dichlorophenoxyacetic acid] 94-75-7 ND non-detect 7.0

Diallate 2303-16-4 ND non-detect 1900 1,2-Dibromo-3-chloropropane 96-12-8 ND non-detect 37

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-6 1,2-Dichlorobenzene [o-Dichlorobenzene] 95-50-1 ND non-detect 1900

1,3-Dichlorobenzene [m-Dichlorobenzene] 541-73-1 ND non-detect 1900

1,4-Dichlorobenzene [p-Dichlorobenzene] 106-46-7 ND non-detect 1900

3,3'-Dichlorobenzidine 91-94-1 ND non-detect 1900 Dichlorodifluoromethane [CFC-12] 75-71-8 ND non-detect 37

1,2-Dichloroethane [Ethylene dichloride] 107-06-2 ND non-detect 37

1,1-Dichloroethylene [Vinylidene chloride] 75-35-4 ND non-detect 37

Dichloromethoxy ethane [Bis(2-chloroethoxy)methane 111-91-1 ND non-detect 1900

2,4-Dichlorophenol 120-83-2 ND non-detect 1900 2,6-Dichlorophenol 87-65-0 ND non-detect 1900 1,2-Dichloropropane [Propylene dichloride] 78-87-5 ND non-detect 37

cis-1,3-Dichloropropylene 10061-01-5 ND non-detect 37 trans-1,3-Dichloropropylene 10061-02-6 ND non-detect 37 1,3-Dichloro-2-propanol 96-23-1 ND non-detect 30
Endosulfan I 959-98-8 ND non-detect 1.4
Endosulfan II 33213-65-9 ND non-detect 1.4
Endrin 72-20-8 ND non-detect 1.4 Endrin aldehyde 7421-93-4 ND non-detect 1.4
Endrin Ketone 53494-70-5 ND non-detect 1.4 Epichlorohydrin [1-Chloro-2,3-epoxy propane] 106-89-8 ND non-detect 30

Ethylidene dichloride [1,1-Dichloroethane] 75-34-3 ND non-detect 37

2-Fluoroacetamide 640-19-7 ND non-detect 100 Heptachlor 76-44-8 ND non-detect 1.4 Heptachlor epoxide 1024-57-3 ND non-detect 2.8

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-7 Hexachlorobenzene 118-74-1 ND non-detect 1900 Hexachloro-1,3-butadiene [Hexachlorobutadiene] 87-68-3 ND non-detect 1900

Hexachlorocyclopentadiene 77-47-4 ND non-detect 1900 Hexachloroethane 67-72-1 ND non-detect 1900 Hexachlorophene 70-30-4 ND non-detect 1000 Hexachloropropene [Hexachloropropylene] 1888-71-7 ND non-detect 1900

Isodrin 465-73-6 ND non-detect 1900 Kepone [Chlordecone] 143-50-0 ND non-detect 3600 Lindane [gamma-BHC] [gamma-Hexachlorocyclohexane] 58-89-9 ND non-detect 1.4

Methylene chloride [Dichloromethane] 75-09-2 ND non-detect 37

4,4'-methylene-bis(2- chloroaniline) 101-14-4 ND non-detect 100

Methyl iodide [Iodomethane] 74-88-4 ND non-detect 37 Pentachlorobenzene 608-93-5 ND non-detect 1900 Pentachloroethane 76-01-7 ND non-detect 37 Pentachloronitrobenzene [PCNB] [Quintobenzene] [Quintozene] 82-68-8 ND non-detect 1900

Pentachlorophenol 87-86-5 ND non-detect 1900 Pronamide 23950-58-5 ND non-detect 1900 Silvex [2,4,5- Trichlorophenoxypropionic acid] 93-72-1 ND non-detect 7.0

2,3,7,8-Tetrachlorodibenzo-pdioxin [2,3,7,8-TCDD] 1746-01-6 ND non-detect 30

1,2,4,5-Tetrachlorobenzene 95-94-3 ND non-detect 1900 1,1,2,2-Tetrachloroethane 79-34-5 ND non-detect 37 Tetrachloroethylene [Perchloroethylene] 127-18-4 ND non-detect 37

2,3,4,6-Tetrachlorophenol 58-90-2 ND non-detect 1900 1,2,4-Trichlorobenzene 120-82-1 ND non-detect 1900 1,1,1-Trichloroethane [Methyl chloroform] 71-55-6 ND non-detect 37

## Chemical Name CAS Number Composite

Value (mg/kg) Heating

Value (BTU/lb) Concentration

Limit (mg/kg at 10,000 BTU/lb) Minimum

Required Detection Limit (mg/kg)



# B-8 1,1,2-Trichloroethane [Vinyl trichloride] 79-00-5 ND non-detect 37

Trichloroethylene 79-01-6 ND non-detect 37 Trichlorofluoromethane [Trichlormonofluoromethane] 75-69-4 ND non-detect 37

2,4,5-Trichlorophenol 95-95-4 ND non-detect 1900 2,4,6-Trichlorophenol 88-06-2 ND non-detect 1900 1,2,3-Trichloropropane 96-18-4 ND non-detect 37 Vinyl Chloride 75-01-4 ND non-detect 37



# NA

- Not Applicable ND

- Non-Detect

# Appendix C

SAIC
Statistical Analysis Results

# Table 1. Gasoline - Combined Results (VOC non-detects from Composite 246)

Appendix C - 1 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 9.3

- Total Halogens as Cl non-detect 25 Antimony non-detect 7.0 Arsenic non-detect 0.14 Barium non-detect 14 Beryllium non-detect 0.70 Cadmium non-detect 0.70 Chromium non-detect 1.4 Cobalt non-detect 2.8 Lead non-detect 7.0 Manganese non-detect 0.70 Mercury non-detect 0.10 Nickel non-detect 2.8 Selenium non-detect 0.14 Silver non-detect 1.4 Thallium non-detect 14

, -Dimethylphenethylamine non-detect 670 -Naphthylamine non-detect 670 ß-Naphthylamine non-detect 670 1,1,2,2-Tetrachloroethane non-detect 34 1,1,2-Trichloroethane non-detect 34 1,1-Dichloroethylene non-detect 34 1,2,3,-Trichloropropane non-detect 34 1,2,4,5-Tetrachlorobenzene non-detect 670 1,2,4-Trichlorobenzene non-detect 670 1,2-Dibromo-3-chloropropane non-detect 34 1,2-Dichloroethylene (cis- or trans-) non-detect 17 1,3,5-Trinitrobenzene non-detect 670 1,4-Dichloro-2-butene (cis- or trans-) non-detect 17 1,4-Naphthoquinone non-detect 670 2,3,4,6-Tetrachlorophenol non-detect 670 2,4,5-Trichlorophenol non-detect 670 2,4,6-Trichlorophenol non-detect 670 2,4-Dichlorophenol non-detect 670 2,4-Dimethylphenol non-detect 670 2,4-Dinitrophenol non-detect 670 2,4-Dinitrotoluene non-detect 670 2,6-Dichlorophenol non-detect 670 2,6-Dinitrotoluene non-detect 670 2-Acetylaminofluorene non-detect 670 2-Chloroethyl vinyl ether non-detect 34 2-Chloronaphthalene non-detect 670 2-Chlorophenol non-detect 670

# Table 1. (Continued) Gasoline - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 2 2-Picoline non-detect 670 3,3'-Dichlorobenzidine non-detect 670 3-3'-Dimethylbenzidine non-detect 670 3-Methylcholanthrene non-detect 670 4,6-Dinitro-o-cresol non-detect 670 4-Aminobiphenyl non-detect 670 4-Bromophenyl phenyl ether non-detect 670 5-Nitro-o-toluidine non-detect 670 7,12-Dimethylbenz[a]anthracene non-detect 670 Acetonitrile non-detect 34 Acetophenone non-detect 670 Acrolein non-detect 34 Acrylonitrile non-detect 34 Allyl chloride non-detect 34 Aniline non-detect 670 Aramite non-detect 670 Benzene 3500

- Benzidine non-detect 670 Benzo[a]anthracene 340

- Benzo[a]pyrene 340

- Benzo[b]fluoranthene non-detect 670 Benzo[k]fluoranthene non-detect 670 Bromoform non-detect 34 Butyl benzyl phthalate non-detect 670 Carbon disulfide non-detect 34 Carbon tetrachloride non-detect 34 Chlorobenzene non-detect 34 Chlorobenzilate non-detect 670 Chloroform non-detect 34 Chloroprene non-detect 34 Chrysene 340

- cis-1,3-Dichloropropene non-detect 34 Cresol (o-, m-, or p-) non-detect 670 Di-n-butyl phthalate non-detect 670 Di-n-octyl phthalate 340

- Diallate non-detect 670 Dibenz[a,j]acridine non-detect 670 Dibenzo[a,h]anthracene 340

- Dichlorodifluoromethane non-detect 34 Diethyl phthalate non-detect 670 Dimethoate non-detect 670 Dimethyl phthalate non-detect 670 Dinoseb non-detect 670

# Table 1. (Continued) Gasoline - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 3 Diphenylamine non-detect 670 Disulfoton non-detect 670 Ethyl methacrylate non-detect 34 Ethyl methanesulfonate non-detect 670 Famphur non-detect 670 Fluoranthene non-detect 670 Fluorene non-detect 670 Hexachlorobenzene non-detect 670 Hexachlorobutadiene non-detect 670 Hexachlorocyclopentadiene non-detect 670 Hexachloroethane non-detect 670 Hexachlorophene non-detect 17000 Hexachloropropene non-detect 670 Indeno(1,2,3-cd)pyrene non-detect 670 Isobutyl alcohol non-detect 34 Isodrin non-detect 670 Isosafrole non-detect 670 Kepone non-detect 1300 m-Dichlorobenzene non-detect 670 Methacrylonitrile non-detect 34 Methapyrilene non-detect 670 Methyl bromide non-detect 34 Methyl chloride non-detect 34 Methyl ethyl ketone non-detect 34 Methyl iodide non-detect 34 Methyl methacrylate non-detect 34 Methyl methanesulfonate non-detect 670 Methyl parathion non-detect 670 Methylene chloride non-detect 34 N-Nitrosodi-n-butylamine non-detect 670 N-Nitrosodiethylamine non-detect 670 N-Nitrosomethylethylamine non-detect 670 N-Nitrosomorpholine non-detect 670 N-Nitrosopiperidine non-detect 670 N-Nitrosopyrrolidine non-detect 670 Naphthalene 2800

- Nitrobenzene non-detect 670 o-Dichlorobenzene non-detect 670 o-Toluidine non-detect 670 O,O,O-Triethyl phosphorothionate non-detect 670 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 670 p-(Dimethylamino)azobenzene non-detect 670 p-Chloro-m-cresol non-detect 670

# Table 1. (Continued) Gasoline - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 4 p-Chloroaniline non-detect 670 p-Dichlorobenzene non-detect 670 p-Nitroaniline non-detect 670 p-Nitrophenol non-detect 670 p-Phenylenediamine non-detect 670 Parathion non-detect 670 Pentachlorobenzene non-detect 670 Pentachloroethane non-detect 34 Pentachloronitrobenzene non-detect 670 Pentachlorophenol non-detect 670 Phenacetin non-detect 670 Phenol non-detect 670 Phorate non-detect 670 Pronamide non-detect 670 Pyridine non-detect 670 Safrole non-detect 670 Tetrachloroethylene non-detect 34 Tetraethyldithiopyrophosphate non-detect 670 Toluene 35000

- Trichloroethylene non-detect 34 Trichlorofluoromethane non-detect 34 Vinyl Chloride non-detect 34

# Table 2. No.2 Fuel Oil - Combined Results

Appendix C - 5 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 110

- Total Halogens as Cl non-detect 25 Antimony non-detect 6.0 Arsenic non-detect 0.12 Barium non-detect 12 Beryllium non-detect 0.60 Cadmium non-detect 0.60 Chromium non-detect 1.2 Cobalt non-detect 2.4 Lead 6.6

- Manganese non-detect 0.60 Mercury non-detect 0.11 Nickel non-detect 2.4 Selenium 0.070

- Silver non-detect 1.2 Thallium non-detect 12

, -Dimethylphenethylamine non-detect 1200 -Naphthylamine non-detect 1200 ß-Naphthylamine non-detect 1200 1,1,2,2-Tetrachloroethane non-detect 34 1,1,2-Trichloroethane non-detect 34 1,1-Dichloroethylene non-detect 34 1,2,3,-Trichloropropane non-detect 34 1,2,4,5-Tetrachlorobenzene non-detect 1200 1,2,4-Trichlorobenzene non-detect 1200 1,2-Dibromo-3-chloropropane non-detect 34 1,2-Dichloroethylene (cis- or trans-) non-detect 34 1,3,5-Trinitrobenzene non-detect 1200 1,4-Dichloro-2-butene (cis- or trans-) non-detect 34 1,4-Naphthoquinone non-detect 1200 2,3,4,6-Tetrachlorophenol non-detect 1200 2,4,5-Trichlorophenol non-detect 1200 2,4,6-Trichlorophenol non-detect 1200 2,4-Dichlorophenol non-detect 1200 2,4-Dimethylphenol non-detect 1200 2,4-Dinitrophenol non-detect 1200 2,4-Dinitrotoluene non-detect 1200 2,6-Dichlorophenol non-detect 1200 2,6-Dinitrotoluene non-detect 1200 2-Acetylaminofluorene non-detect 1200 2-Chloroethyl vinyl ether non-detect 34 2-Chloronaphthalene non-detect 1200 2-Chlorophenol non-detect 1200 2-Picoline non-detect 1200

# Table 2. (Continued) No. 2 Fuel Oil - Combined Results)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 6 3,3'-Dichlorobenzidine non-detect 1200 3-3'-Dimethylbenzidine non-detect 1200 3-Methylcholanthrene non-detect 1200 4,6-Dinitro-o-cresol non-detect 1200 4-Aminobiphenyl non-detect 1200 4-Bromophenyl phenyl ether non-detect 1200 5-Nitro-o-toluidine non-detect 1200 7,12-Dimethylbenz[a]anthracene non-detect 1200 Acetonitrile non-detect 34 Acetophenone non-detect 1200 Acrolein non-detect 34 Acrylonitrile non-detect 34 Allyl chloride non-detect 34 Aniline non-detect 1200 Aramite non-detect 1200 Benzene 21

- Benzidine non-detect 1200 Benzo[a]anthracene 610

- Benzo[a]pyrene 610

- Benzo[b]fluoranthene non-detect 1200 Benzo[k]fluoranthene non-detect 1200 Bromoform non-detect 34 Butyl benzyl phthalate non-detect 1200 Carbon disulfide non-detect 34 Carbon tetrachloride non-detect 34 Chlorobenzene non-detect 34 Chlorobenzilate non-detect 1200 Chloroform non-detect 34 Chloroprene non-detect 34 Chrysene 610

- cis-1,3-Dichloropropene non-detect 34 Cresol (o-, m-, or p-) non-detect 1200 Di-n-butyl phthalate non-detect 1200 Di-n-octyl phthalate 610

- Diallate non-detect 1200 Dibenz[a,j]acridine non-detect 1200 Dibenzo[a,h]anthracene 610

- Dichlorodifluoromethane non-detect 34 Diethyl phthalate non-detect 1200 Dimethoate non-detect 1200 Dimethyl phthalate non-detect 1200 Dinoseb non-detect 1200 Diphenylamine non-detect 1200 Disulfoton non-detect 1200

# Table 2. (Continued) No. 2 Fuel Oil - Combined Results)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 7 Ethyl methacrylate non-detect 34 Ethyl methanesulfonate non-detect 1200 Famphur non-detect 1200 Fluoranthene non-detect 1200 Fluorene non-detect 1200 Hexachlorobenzene non-detect 1200 Hexachlorobutadiene non-detect 1200 Hexachlorocyclopentadiene non-detect 1200 Hexachloroethane non-detect 1200 Hexachlorophene non-detect 29000 Hexachloropropene non-detect 1200 Indeno(1,2,3-cd)pyrene non-detect 1200 Isobutyl alcohol non-detect 34 Isodrin non-detect 1200 Isosafrole non-detect 1200 Kepone non-detect 2300 m-Dichlorobenzene non-detect 1200 Methacrylonitrile non-detect 34 Methapyrilene non-detect 1200 Methyl bromide non-detect 34 Methyl chloride non-detect 34 Methyl ethyl ketone non-detect 34 Methyl iodide non-detect 34 Methyl methacrylate non-detect 34 Methyl methanesulfonate non-detect 1200 Methyl parathion non-detect 1200 Methylene chloride non-detect 34 N-Nitrosodi-n-butylamine non-detect 1200 N-Nitrosodiethylamine non-detect 1200 N-Nitrosomethylethylamine non-detect 1200 N-Nitrosomorpholine non-detect 1200 N-Nitrosopiperidine non-detect 1200 N-Nitrosopyrrolidine non-detect 1200 Naphthalene 1200

- Nitrobenzene non-detect 1200 o-Dichlorobenzene non-detect 1200 o-Toluidine non-detect 1200 O,O,O-Triethyl phosphorothionate non-detect 1200 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 1200 p-(Dimethylamino)azobenzene non-detect 1200 p-Chloro-m-cresol non-detect 1200 p-Chloroaniline non-detect 1200 p-Dichlorobenzene non-detect 1200 p-Nitroaniline non-detect 1200

# Table 2. (Continued) No.2 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 8 p-Nitrophenol non-detect 1200 p-Phenylenediamine non-detect 1200 Parathion non-detect 1200 Pentachlorobenzene non-detect 1200 Pentachloroethane non-detect 34 Pentachloronitrobenzene non-detect 1200 Pentachlorophenol non-detect 1200 Phenacetin non-detect 1200 Phenol non-detect 1200 Phorate non-detect 1200 Pronamide non-detect 1200 Pyridine non-detect 1200 Safrole non-detect 1200 Tetrachloroethylene non-detect 34 Tetraethyldithiopyrophosphate non-detect 1200 Toluene 150

- Trichloroethylene non-detect 34 Trichlorofluoromethane non-detect 34 Vinyl Chloride non-detect 34

# Table 3. No.4 Fuel Oil - Combined Results

Appendix C - 9 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 1500

- Total Halogens as Cl non-detect 10 Antimony non-detect 11 Arsenic non-detect 0.23 Barium non-detect 23 Beryllium non-detect 1.2 Cadmium non-detect 1.2 Chromium non-detect 2.3 Cobalt non-detect 4.6 Lead 9.9

- Manganese non-detect 1.2 Mercury non-detect 0.18 Nickel 16

- Selenium 0.13

- Silver non-detect 2.3 Thallium non-detect 23

, -Dimethylphenethylamine non-detect 200 -Naphthylamine non-detect 200 ß-Naphthylamine non-detect 200 1,1,2,2-Tetrachloroethane non-detect 17 1,1,2-Trichloroethane non-detect 17 1,1-Dichloroethylene non-detect 17 1,2,3,-Trichloropropane non-detect 17 1,2,4,5-Tetrachlorobenzene non-detect 200 1,2,4-Trichlorobenzene non-detect 200 1,2-Dibromo-3-chloropropane non-detect 17 1,2-Dichloroethylene (cis- or trans-) non-detect 17 1,3,5-Trinitrobenzene non-detect 200 1,4-Dichloro-2-butene (cis- or trans-) non-detect 17 1,4-Naphthoquinone non-detect 200 2,3,4,6-Tetrachlorophenol non-detect 200 2,4,5-Trichlorophenol non-detect 200 2,4,6-Trichlorophenol non-detect 200 2,4-Dichlorophenol non-detect 200 2,4-Dimethylphenol non-detect 200 2,4-Dinitrophenol non-detect 200 2,4-Dinitrotoluene non-detect 200 2,6-Dichlorophenol non-detect 200 2,6-Dinitrotoluene non-detect 200 2-Acetylaminofluorene non-detect 200 2-Chloroethyl vinyl ether non-detect 17 2-Chloronaphthalene non-detect 200 2-Chlorophenol non-detect 200 2-Picoline non-detect 200

# Table 3. (Continued) No. 4 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 10 3,3'-Dichlorobenzidine non-detect 200 3-3'-Dimethylbenzidine non-detect 200 3-Methylcholanthrene non-detect 200 4,6-Dinitro-o-cresol non-detect 200 4-Aminobiphenyl non-detect 200 4-Bromophenyl phenyl ether non-detect 200 5-Nitro-o-toluidine non-detect 200 7,12-Dimethylbenz[a]anthracene non-detect 200 Acetonitrile non-detect 17 Acetophenone non-detect 200 Acrolein non-detect 17 Acrylonitrile non-detect 17 Allyl chloride non-detect 17 Aniline non-detect 200 Aramite non-detect 200 Benzene 22

- Benzidine non-detect 200 Benzo[a]anthracene 100

- Benzo[a]pyrene 100

- Benzo[b]fluoranthene non-detect 200 Benzo[k]fluoranthene non-detect 200 Bromoform non-detect 17 Butyl benzyl phthalate non-detect 200 Carbon disulfide non-detect 17 Carbon tetrachloride non-detect 17 Chlorobenzene non-detect 17 Chlorobenzilate non-detect 200 Chloroform non-detect 17 Chloroprene non-detect 17 Chrysene 100

- cis-1,3-Dichloropropene non-detect 17 Cresol (o-, m-, or p-) non-detect 200 Di-n-butyl phthalate non-detect 200 Di-n-octyl phthalate 100

- Diallate non-detect 200 Dibenz[a,j]acridine non-detect 200 Dibenzo[a,h]anthracene 100

- Dichlorodifluoromethane non-detect 17 Diethyl phthalate non-detect 200 Dimethoate non-detect 200 Dimethyl phthalate non-detect 200 Dinoseb non-detect 200 Diphenylamine non-detect 200 Disulfoton non-detect 200

# Table 3. (Continued) No. 4 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 11 Ethyl methacrylate non-detect 17 Ethyl methanesulfonate non-detect 200 Famphur non-detect 200 Fluoranthene non-detect 200 Fluorene 110

- Hexachlorobenzene non-detect 200 Hexachlorobutadiene non-detect 200 Hexachlorocyclopentadiene non-detect 200 Hexachloroethane non-detect 200 Hexachlorophene non-detect 5000 Hexachloropropene non-detect 200 Indeno(1,2,3-cd)pyrene non-detect 200 Isobutyl alcohol non-detect 17 Isodrin non-detect 200 Isosafrole non-detect 200 Kepone non-detect 400 m-Dichlorobenzene non-detect 200 Methacrylonitrile non-detect 17 Methapyrilene non-detect 200 Methyl bromide non-detect 17 Methyl chloride non-detect 17 Methyl ethyl ketone non-detect 17 Methyl iodide non-detect 17 Methyl methacrylate non-detect 17 Methyl methanesulfonate non-detect 200 Methyl parathion non-detect 200 Methylene chloride non-detect 17 N-Nitrosodi-n-butylamine non-detect 200 N-Nitrosodiethylamine non-detect 200 N-Nitrosomethylethylamine non-detect 200 N-Nitrosomorpholine non-detect 200 N-Nitrosopiperidine non-detect 200 N-Nitrosopyrrolidine non-detect 200 Naphthalene 340

- Nitrobenzene non-detect 200 o-Dichlorobenzene non-detect 200 o-Toluidine non-detect 200 O,O,O-Triethyl phosphorothionate non-detect 200 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 200 p-(Dimethylamino)azobenzene non-detect 200 p-Chloro-m-cresol non-detect 200 p-Chloroaniline non-detect 200 p-Dichlorobenzene non-detect 200 p-Nitroaniline non-detect 200

# Table 3. (Continued) No.4 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 12 p-Nitrophenol non-detect 200 p-Phenylenediamine non-detect 200 Parathion non-detect 200 Pentachlorobenzene non-detect 200 Pentachloroethane non-detect 17 Pentachloronitrobenzene non-detect 200 Pentachlorophenol non-detect 200 Phenacetin non-detect 200 Phenol non-detect 200 Phorate non-detect 200 Pronamide non-detect 200 Pyridine non-detect 200 Safrole non-detect 200 Tetrachloroethylene non-detect 17 Tetraethyldithiopyrophosphate non-detect 200 Toluene 110

- Trichloroethylene non-detect 17 Trichlorofluoromethane non-detect 17 Vinyl Chloride non-detect 17

# Table 4. No.6 Fuel Oil - Combined Results

Appendix C - 13 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 3500

- Total Halogens as Cl non-detect 10 Antimony 6.5

- Arsenic non-detect 0.20 Barium non-detect 20 Beryllium non-detect 1.0 Cadmium non-detect 1.0 Chromium non-detect 2.0 Cobalt non-detect 4.1 Lead 30

- Manganese non-detect 1.0 Mercury non-detect 0.22 Nickel 36

- Selenium 0.12

- Silver non-detect 2.0 Thallium non-detect 20

, -Dimethylphenethylamine non-detect 640 -Naphthylamine non-detect 640 ß-Naphthylamine non-detect 640 1,1,2,2-Tetrachloroethane non-detect 20 1,1,2-Trichloroethane non-detect 20 1,1-Dichloroethylene non-detect 20 1,2,3,-Trichloropropane non-detect 20 1,2,4,5-Tetrachlorobenzene non-detect 640 1,2,4-Trichlorobenzene non-detect 640 1,2-Dibromo-3-chloropropane non-detect 20 1,2-Dichloroethylene (cis- or trans-) non-detect 21 1,3,5-Trinitrobenzene non-detect 640 1,4-Dichloro-2-butene (cis- or trans-) non-detect 21 1,4-Naphthoquinone non-detect 640 2,3,4,6-Tetrachlorophenol non-detect 640 2,4,5-Trichlorophenol non-detect 640 2,4,6-Trichlorophenol non-detect 640 2,4-Dichlorophenol non-detect 640 2,4-Dimethylphenol non-detect 640 2,4-Dinitrophenol non-detect 640 2,4-Dinitrotoluene non-detect 640 2,6-Dichlorophenol non-detect 640 2,6-Dinitrotoluene non-detect 640 2-Acetylaminofluorene non-detect 640 2-Chloroethyl vinyl ether non-detect 20 2-Chloronaphthalene non-detect 640 2-Chlorophenol non-detect 640 2-Picoline non-detect 640

# Table 4. (Continued) No. 6 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 14 3,3'-Dichlorobenzidine non-detect 640 3-3'-Dimethylbenzidine non-detect 640 3-Methylcholanthrene non-detect 640 4,6-Dinitro-o-cresol non-detect 640 4-Aminobiphenyl non-detect 640 4-Bromophenyl phenyl ether non-detect 640 5-Nitro-o-toluidine non-detect 640 7,12-Dimethylbenz[a]anthracene non-detect 640 Acetonitrile non-detect 20 Acetophenone non-detect 640 Acrolein non-detect 20 Acrylonitrile non-detect 20 Allyl chloride non-detect 20 Aniline non-detect 640 Aramite non-detect 640 Benzene 11

- Benzidine non-detect 640 Benzo[a]anthracene 930

- Benzo[a]pyrene 530

- Benzo[b]fluoranthene 420

- Benzo[k]fluoranthene non-detect 640 Bromoform non-detect 20 Butyl benzyl phthalate non-detect 640 Carbon disulfide non-detect 20 Carbon tetrachloride non-detect 20 Chlorobenzene non-detect 20 Chlorobenzilate non-detect 640 Chloroform non-detect 20 Chloroprene non-detect 20 Chrysene 1300

- cis-1,3-Dichloropropene non-detect 20 Cresol (o-, m-, or p-) non-detect 790 Di-n-butyl phthalate non-detect 640 Di-n-octyl phthalate 350

- Diallate non-detect 640 Dibenz[a,j]acridine non-detect 640 Dibenzo[a,h]anthracene 350

- Dichlorodifluoromethane non-detect 20 Diethyl phthalate non-detect 640 Dimethoate non-detect 640 Dimethyl phthalate non-detect 640 Dinoseb non-detect 640 Diphenylamine non-detect 640 Disulfoton non-detect 640

# Table 4. (Continued) No. 6 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 15 Ethyl methacrylate non-detect 20 Ethyl methanesulfonate non-detect 640 Famphur non-detect 640 Fluoranthene non-detect 640 Fluorene 350

- Hexachlorobenzene non-detect 640 Hexachlorobutadiene non-detect 640 Hexachlorocyclopentadiene non-detect 640 Hexachloroethane non-detect 640 Hexachlorophene non-detect 16000 Hexachloropropene non-detect 640 Indeno(1,2,3-cd)pyrene 350

- Isobutyl alcohol non-detect 20 Isodrin non-detect 640 Isosafrole non-detect 640 Kepone non-detect 1300 m-Dichlorobenzene non-detect 640 Methacrylonitrile non-detect 20 Methapyrilene non-detect 640 Methyl bromide non-detect 20 Methyl chloride non-detect 20 Methyl ethyl ketone non-detect 20 Methyl iodide non-detect 20 Methyl methacrylate non-detect 20 Methyl methanesulfonate non-detect 640 Methyl parathion non-detect 640 Methylene chloride non-detect 20 N-Nitrosodi-n-butylamine non-detect 640 N-Nitrosodiethylamine non-detect 640 N-Nitrosomethylethylamine non-detect 640 N-Nitrosomorpholine non-detect 640 N-Nitrosopiperidine non-detect 640 N-Nitrosopyrrolidine non-detect 640 Naphthalene 570

- Nitrobenzene non-detect 640 o-Dichlorobenzene non-detect 640 o-Toluidine non-detect 1300 O,O,O-Triethyl phosphorothionate non-detect 640 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 640 p-(Dimethylamino)azobenzene non-detect 640 p-Chloro-m-cresol non-detect 640 p-Chloroaniline non-detect 640 p-Dichlorobenzene non-detect 640 p-Nitroaniline non-detect 640

# Table 4. (Continued) No.6 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 16 p-Nitrophenol non-detect 640 p-Phenylenediamine non-detect 640 Parathion non-detect 640 Pentachlorobenzene non-detect 640 Pentachloroethane non-detect 20 Pentachloronitrobenzene non-detect 640 Pentachlorophenol non-detect 640 Phenacetin non-detect 640 Phenol non-detect 640 Phorate non-detect 640 Pronamide non-detect 640 Pyridine non-detect 640 Safrole non-detect 640 Tetrachloroethylene non-detect 20 Tetraethyldithiopyrophosphate non-detect 640 Toluene 41

- Trichloroethylene non-detect 20 Trichlorofluoromethane non-detect 20 Vinyl Chloride non-detect 20

# Table 5. Composite 246 50th Percentile - Combined Results

Appendix C - 17 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 1200

- Total Halogens as Cl non-detect 10 Antimony 5.5

- Arsenic non-detect 0.20 Barium non-detect 20 Beryllium non-detect 1.0 Cadmium non-detect 1.0 Chromium non-detect 2.0 Cobalt non-detect 4.1 Lead 8.6

- Manganese non-detect 1.0 Mercury non-detect 0.17 Nickel 3.7

- Selenium 0.11

- Silver non-detect 2.0 Thallium non-detect 20

, -Dimethylphenethylamine non-detect 200 -Naphthylamine non-detect 200 ß-Naphthylamine non-detect 200 1,1,2,2-Tetrachloroethane non-detect 17 1,1,2-Trichloroethane non-detect 17 1,1-Dichloroethylene non-detect 17 1,2,3,-Trichloropropane non-detect 17 1,2,4,5-Tetrachlorobenzene non-detect 200 1,2,4-Trichlorobenzene non-detect 200 1,2-Dibromo-3-chloropropane non-detect 17 1,2-Dichloroethylene (cis- or trans-) non-detect 16 1,3,5-Trinitrobenzene non-detect 200 1,4-Dichloro-2-butene (cis- or trans-) non-detect 16 1,4-Naphthoquinone non-detect 200 2,3,4,6-Tetrachlorophenol non-detect 200 2,4,5-Trichlorophenol non-detect 200 2,4,6-Trichlorophenol non-detect 200 2,4-Dichlorophenol non-detect 200 2,4-Dimethylphenol non-detect 200 2,4-Dinitrophenol non-detect 200 2,4-Dinitrotoluene non-detect 200 2,6-Dichlorophenol non-detect 200 2,6-Dinitrotoluene non-detect 200 2-Acetylaminofluorene non-detect 200 2-Chloroethyl vinyl ether non-detect 17 2-Chloronaphthalene non-detect 200 2-Chlorophenol non-detect 200 2-Picoline non-detect 200

# Table 5. (Continued) Composite 246 50th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 18 3,3'-Dichlorobenzidine non-detect 200 3-3'-Dimethylbenzidine non-detect 200 3-Methylcholanthrene non-detect 200 4,6-Dinitro-o-cresol non-detect 200 4-Aminobiphenyl non-detect 200 4-Bromophenyl phenyl ether non-detect 200 5-Nitro-o-toluidine non-detect 200 7,12-Dimethylbenz[a]anthracene non-detect 200 Acetonitrile non-detect 17 Acetophenone non-detect 200 Acrolein non-detect 17 Acrylonitrile non-detect 17 Allyl chloride non-detect 17 Aniline non-detect 200 Aramite non-detect 200 Benzene 17

- Benzidine non-detect 200 Benzo[a]anthracene 300

- Benzo[a]pyrene 230

- Benzo[b]fluoranthene 120

- Benzo[k]fluoranthene non-detect 200 Bromoform non-detect 17 Butyl benzyl phthalate non-detect 200 Carbon disulfide non-detect 17 Carbon tetrachloride non-detect 17 Chlorobenzene non-detect 17 Chlorobenzilate non-detect 200 Chloroform non-detect 17 Chloroprene non-detect 17 Chrysene 300

- cis-1,3-Dichloropropene non-detect 17 Cresol (o-, m-, or p-) non-detect 200 Di-n-butyl phthalate non-detect 200 Di-n-octyl phthalate 110

- Diallate non-detect 200 Dibenz[a,j]acridine non-detect 200 Dibenzo[a,h]anthracene 110

- Dichlorodifluoromethane non-detect 17 Diethyl phthalate non-detect 200 Dimethoate non-detect 200 Dimethyl phthalate non-detect 200 Dinoseb non-detect 200 Diphenylamine non-detect 200 Disulfoton non-detect 200

# Table 5. (Continued) Composite 246 50th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 19 Ethyl methacrylate non-detect 17 Ethyl methanesulfonate non-detect 200 Famphur non-detect 200 Fluoranthene non-detect 200 Fluorene 110

- Hexachlorobenzene non-detect 200 Hexachlorobutadiene non-detect 200 Hexachlorocyclopentadiene non-detect 200 Hexachloroethane non-detect 200 Hexachlorophene non-detect 5000 Hexachloropropene non-detect 200 Indeno(1,2,3-cd)pyrene 110

- Isobutyl alcohol non-detect 17 Isodrin non-detect 200 Isosafrole non-detect 200 Kepone non-detect 400 m-Dichlorobenzene non-detect 200 Methacrylonitrile non-detect 17 Methapyrilene non-detect 200 Methyl bromide non-detect 17 Methyl chloride non-detect 17 Methyl ethyl ketone non-detect 17 Methyl iodide non-detect 17 Methyl methacrylate non-detect 17 Methyl methanesulfonate non-detect 200 Methyl parathion non-detect 200 Methylene chloride non-detect 17 N-Nitrosodi-n-butylamine non-detect 200 N-Nitrosodiethylamine non-detect 200 N-Nitrosomethylethylamine non-detect 200 N-Nitrosomorpholine non-detect 200 N-Nitrosopiperidine non-detect 200 N-Nitrosopyrrolidine non-detect 200 Naphthalene 330

- Nitrobenzene non-detect 200 o-Dichlorobenzene non-detect 200 o-Toluidine non-detect 200 O,O,O-Triethyl phosphorothionate non-detect 200 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 200 p-(Dimethylamino)azobenzene non-detect 200 p-Chloro-m-cresol non-detect 200 p-Chloroaniline non-detect 200 p-Dichlorobenzene non-detect 200 p-Nitroaniline non-detect 200

# Table 5. (Continued) Composite 246 50th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 20 p-Nitrophenol non-detect 200 p-Phenylenediamine non-detect 200 Parathion non-detect 200 Pentachlorobenzene non-detect 200 Pentachloroethane non-detect 17 Pentachloronitrobenzene non-detect 200 Pentachlorophenol non-detect 200 Phenacetin non-detect 200 Phenol non-detect 200 Phorate non-detect 200 Pronamide non-detect 200 Pyridine non-detect 200 Safrole non-detect 200 Tetrachloroethylene non-detect 17 Tetraethyldithiopyrophosphate non-detect 200 Toluene 98

- Trichloroethylene non-detect 17 Trichlorofluoromethane non-detect 17 Vinyl Chloride non-detect 17

# Table 6. Composite 246 90th Percentile - Combined Results

Appendix C - 21 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 2700

- Total Halogens as Cl non-detect 25 Antimony 5.90

- Arsenic non-detect 0.22 Barium non-detect 22 Beryllium non-detect 1.10 Cadmium non-detect 1.10 Chromium non-detect 2.20 Cobalt non-detect 4.50 Lead 22

- Manganese non-detect 1.10 Mercury non-detect 0.18 Nickel 26

- Selenium 0.12

- Silver non-detect 2.20 Thallium non-detect 22

, -Dimethylphenethylamine non-detect 910 -Naphthylamine non-detect 910 ß-Naphthylamine non-detect 910 1,1,2,2-Tetrachloroethane non-detect 34 1,1,2-Trichloroethane non-detect 34 1,1-Dichloroethylene non-detect 34 1,2,3,-Trichloropropane non-detect 34 1,2,4,5-Tetrachlorobenzene non-detect 910 1,2,4-Trichlorobenzene non-detect 910 1,2-Dibromo-3-chloropropane non-detect 34 1,2-Dichloroethylene (cis- or trans-) non-detect 17 1,3,5-Trinitrobenzene non-detect 1100 1,4-Dichloro-2-butene (cis- or trans-) non-detect 17 1,4-Naphthoquinone non-detect 910 2,3,4,6-Tetrachlorophenol non-detect 910 2,4,5-Trichlorophenol non-detect 910 2,4,6-Trichlorophenol non-detect 910 2,4-Dichlorophenol non-detect 910 2,4-Dimethylphenol non-detect 910 2,4-Dinitrophenol non-detect 910 2,4-Dinitrotoluene non-detect 910 2,6-Dichlorophenol non-detect 910 2,6-Dinitrotoluene non-detect 910 2-Acetylaminofluorene non-detect 910 2-Chloroethyl vinyl ether non-detect 34 2-Chloronaphthalene non-detect 910 2-Chlorophenol non-detect 910 2-Picoline non-detect 910

# Table 6. (Continued) Composite 246 90th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 22 3,3'-Dichlorobenzidine non-detect 910 3-3'-Dimethylbenzidine non-detect 910 3-Methylcholanthrene non-detect 910 4,6-Dinitro-o-cresol non-detect 910 4-Aminobiphenyl non-detect 910 4-Bromophenyl phenyl ether non-detect 910 5-Nitro-o-toluidine non-detect 910 7,12-Dimethylbenz[a]anthracene non-detect 910 Acetonitrile non-detect 34 Acetophenone non-detect 910 Acrolein non-detect 34 Acrylonitrile non-detect 34 Allyl chloride non-detect 34 Aniline non-detect 910 Aramite non-detect 910 Benzene 22

- Benzidine non-detect 910 Benzo[a]anthracene 760

- Benzo[a]pyrene 530

- Benzo[b]fluoranthene 500

- Benzo[k]fluoranthene non-detect 910 Bromoform non-detect 34 Butyl benzyl phthalate non-detect 910 Carbon disulfide non-detect 34 Carbon tetrachloride non-detect 34 Chlorobenzene non-detect 34 Chlorobenzilate non-detect 910 Chloroform non-detect 34 Chloroprene non-detect 34 Chrysene 930

- cis-1,3-Dichloropropene non-detect 34 Cresol (o-, m-, or p-) non-detect 200 Di-n-butyl phthalate non-detect 910 Di-n-octyl phthalate 480

- Diallate non-detect 910 Dibenz[a,j]acridine non-detect 910 Dibenzo[a,h]anthracene 480

- Dichlorodifluoromethane non-detect 34 Diethyl phthalate non-detect 910 Dimethoate non-detect 910 Dimethyl phthalate non-detect 910 Dinoseb non-detect 910 Diphenylamine non-detect 910 Disulfoton non-detect 910

# Table 6. (Continued) Composite 246 90th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 23 Ethyl methacrylate non-detect 34 Ethyl methanesulfonate non-detect 910 Famphur non-detect 910 Fluoranthene non-detect 910 Fluorene 480

- Hexachlorobenzene non-detect 910 Hexachlorobutadiene non-detect 910 Hexachlorocyclopentadiene non-detect 910 Hexachloroethane non-detect 910 Hexachlorophene non-detect 22000 Hexachloropropene non-detect 910 Indeno(1,2,3-cd)pyrene 480

- Isobutyl alcohol non-detect 34 Isodrin non-detect 910 Isosafrole non-detect 910 Kepone non-detect 1800 m-Dichlorobenzene non-detect 910 Methacrylonitrile non-detect 34 Methapyrilene non-detect 910 Methyl bromide non-detect 34 Methyl chloride non-detect 34 Methyl ethyl ketone non-detect 34 Methyl iodide non-detect 34 Methyl methacrylate non-detect 34 Methyl methanesulfonate non-detect 910 Methyl parathion non-detect 910 Methylene chloride non-detect 34 N-Nitrosodi-n-butylamine non-detect 910 N-Nitrosodiethylamine non-detect 910 N-Nitrosomethylethylamine non-detect 910 N-Nitrosomorpholine non-detect 910 N-Nitrosopiperidine non-detect 910 N-Nitrosopyrrolidine non-detect 910 Naphthalene 1000

- Nitrobenzene non-detect 910 o-Dichlorobenzene non-detect 910 o-Toluidine non-detect 1200 O,O,O-Triethyl phosphorothionate non-detect 910 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 910 p-(Dimethylamino)azobenzene non-detect 910 p-Chloro-m-cresol non-detect 910 p-Chloroaniline non-detect 910 p-Dichlorobenzene non-detect 910 p-Nitroaniline non-detect 910

# Table 6. (Continued) Composite 246 90th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 24 p-Nitrophenol non-detect 910 p-Phenylenediamine non-detect 910 Parathion non-detect 910 Pentachlorobenzene non-detect 910 Pentachloroethane non-detect 34 Pentachloronitrobenzene non-detect 910 Pentachlorophenol non-detect 910 Phenacetin non-detect 910 Phenol non-detect 910 Phorate non-detect 910 Pronamide non-detect 910 Pyridine non-detect 910 Safrole non-detect 910 Tetrachloroethylene non-detect 34 Tetraethyldithiopyrophosphate non-detect 910 Toluene 140

- Trichloroethylene non-detect 34 Trichlorofluoromethane non-detect 34 Vinyl Chloride non-detect 34

# Appendix C - 25

# Table 7. Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Appendix C - 26 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 170

- Total Halogens as Cl non-detect 10 Antimony 4.7

- Arsenic non-detect 0.14 Barium non-detect 18 Beryllium non-detect 0.90 Cadmium non-detect 0.90 Chromium non-detect 1.8 Cobalt non-detect 3.6 Lead 7.0

- Manganese non-detect 0.90 Mercury non-detect 0.11 Nickel 2.4

- Selenium 0.090

- Silver non-detect 1.8 Thallium non-detect 18

, -Dimethylphenethylamine non-detect 220 -Naphthylamine non-detect 220 ß-Naphthylamine non-detect 220 1,1,2,2-Tetrachloroethane non-detect 17 1,1,2-Trichloroethane non-detect 17 1,1-Dichloroethylene non-detect 17 1,2,3,-Trichloropropane non-detect 17 1,2,4,5-Tetrachlorobenzene non-detect 220 1,2,4-Trichlorobenzene non-detect 220 1,2-Dibromo-3-chloropropane non-detect 17 1,2-Dichloroethylene (cis- or trans-) non-detect 16 1,3,5-Trinitrobenzene non-detect 220 1,4-Dichloro-2-butene (cis- or trans-) non-detect 16 1,4-Naphthoquinone non-detect 220 2,3,4,6-Tetrachlorophenol non-detect 220 2,4,5-Trichlorophenol non-detect 220 2,4,6-Trichlorophenol non-detect 220 2,4-Dichlorophenol non-detect 220 2,4-Dimethylphenol non-detect 220 2,4-Dinitrophenol non-detect 220 2,4-Dinitrotoluene non-detect 220 2,6-Dichlorophenol non-detect 220 2,6-Dinitrotoluene non-detect 220 2-Acetylaminofluorene non-detect 220 2-Chloroethyl vinyl ether non-detect 17 2-Chloronaphthalene non-detect 220 2-Chlorophenol non-detect 220

# Table 7. (Continued) Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 27 2-Picoline non-detect 220 3,3'-Dichlorobenzidine non-detect 220 3-3'-Dimethylbenzidine non-detect 220 3-Methylcholanthrene non-detect 220 4,6-Dinitro-o-cresol non-detect 220 4-Aminobiphenyl non-detect 220 4-Bromophenyl phenyl ether non-detect 220 5-Nitro-o-toluidine non-detect 220 7,12-Dimethylbenz[a]anthracene non-detect 220 Acetonitrile non-detect 17 Acetophenone non-detect 220 Acrolein non-detect 17 Acrylonitrile non-detect 17 Allyl chloride non-detect 17 Aniline non-detect 220 Aramite non-detect 220 Benzene 21

- Benzidine non-detect 220 Benzo[a]anthracene 140

- Benzo[a]pyrene 140

- Benzo[b]fluoranthene 140

- Benzo[k]fluoranthene non-detect 220 Bromoform non-detect 17 Butyl benzyl phthalate non-detect 220 Carbon disulfide non-detect 17 Carbon tetrachloride non-detect 17 Chlorobenzene non-detect 17 Chlorobenzilate non-detect 220 Chloroform non-detect 17 Chloroprene non-detect 17 Chrysene 140

- cis-1,3-Dichloropropene non-detect 17 Cresol (o-, m-, or p-) non-detect 200 Di-n-butyl phthalate non-detect 220 Di-n-octyl phthalate 120

- Diallate non-detect 220 Dibenz[a,j]acridine non-detect 220 Dibenzo[a,h]anthracene 140

- Dichlorodifluoromethane non-detect 17 Diethyl phthalate non-detect 220 Dimethoate non-detect 220 Dimethyl phthalate non-detect 220 Dinoseb non-detect 220

# Table 7. (Continued) Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 28 Diphenylamine non-detect 220 Disulfoton non-detect 220 Ethyl methacrylate non-detect 17 Ethyl methanesulfonate non-detect 220 Famphur non-detect 220 Fluoranthene non-detect 220 Fluorene 120

- Hexachlorobenzene non-detect 220 Hexachlorobutadiene non-detect 220 Hexachlorocyclopentadiene non-detect 220 Hexachloroethane non-detect 220 Hexachlorophene non-detect 5500 Hexachloropropene non-detect 220 Indeno(1,2,3-cd)pyrene 140

- Isobutyl alcohol non-detect 17 Isodrin non-detect 220 Isosafrole non-detect 220 Kepone non-detect 440 m-Dichlorobenzene non-detect 220 Methacrylonitrile non-detect 17 Methapyrilene non-detect 220 Methyl bromide non-detect 17 Methyl chloride non-detect 17 Methyl ethyl ketone non-detect 17 Methyl iodide non-detect 17 Methyl methacrylate non-detect 17 Methyl methanesulfonate non-detect 220 Methyl parathion non-detect 220 Methylene chloride non-detect 17 N-Nitrosodi-n-butylamine non-detect 220 N-Nitrosodiethylamine non-detect 220 N-Nitrosomethylethylamine non-detect 220 N-Nitrosomorpholine non-detect 220 N-Nitrosopiperidine non-detect 220 N-Nitrosopyrrolidine non-detect 220 Naphthalene 360

- Nitrobenzene non-detect 220 o-Dichlorobenzene non-detect 220 o-Toluidine non-detect 270 O,O,O-Triethyl phosphorothionate non-detect 220 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 220 p-(Dimethylamino)azobenzene non-detect 220 p-Chloro-m-cresol non-detect 220

# Table 7. (Continued) Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 29 p-Chloroaniline non-detect 220 p-Dichlorobenzene non-detect 220 p-Nitroaniline non-detect 220 p-Nitrophenol non-detect 220 p-Phenylenediamine non-detect 220 Parathion non-detect 220 Pentachlorobenzene non-detect 220 Pentachloroethane non-detect 17 Pentachloronitrobenzene non-detect 220 Pentachlorophenol non-detect 220 Phenacetin non-detect 220 Phenol non-detect 220 Phorate non-detect 220 Pronamide non-detect 220 Pyridine non-detect 220 Safrole non-detect 220 Tetrachloroethylene non-detect 17 Tetraethyldithiopyrophosphate non-detect 220 Toluene 110

- Trichloroethylene non-detect 17 Trichlorofluoromethane non-detect 17 Vinyl Chloride non-detect 17

# Table 8. Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Appendix C - 30 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

Total Nitrogen as N 1800

- Total Halogens as Cl non-detect 25 Antimony 5.9

- Arsenic non-detect 0.22 Barium non-detect 22 Beryllium non-detect 1.1 Cadmium non-detect 1.1 Chromium non-detect 2.2 Cobalt non-detect 4.4 Lead 22

- Manganese non-detect 1.1 Mercury non-detect 0.18 Nickel 18

- Selenium 0.12

- Silver non-detect 2.2 Thallium non-detect 22

, -Dimethylphenethylamine non-detect 700 -Naphthylamine non-detect 700 ß-Naphthylamine non-detect 700 1,1,2,2-Tetrachloroethane non-detect 34 1,1,2-Trichloroethane non-detect 34 1,1-Dichloroethylene non-detect 34 1,2,3,-Trichloropropane non-detect 34 1,2,4,5-Tetrachlorobenzene non-detect 700 1,2,4-Trichlorobenzene non-detect 700 1,2-Dibromo-3-chloropropane non-detect 34 1,2-Dichloroethylene (cis- or trans-) non-detect 17 1,3,5-Trinitrobenzene non-detect 900 1,4-Dichloro-2-butene (cis- or trans-) non-detect 17 1,4-Naphthoquinone non-detect 700 2,3,4,6-Tetrachlorophenol non-detect 700 2,4,5-Trichlorophenol non-detect 700 2,4,6-Trichlorophenol non-detect 700 2,4-Dichlorophenol non-detect 700 2,4-Dimethylphenol non-detect 700 2,4-Dinitrophenol non-detect 700 2,4-Dinitrotoluene non-detect 700 2,6-Dichlorophenol non-detect 700 2,6-Dinitrotoluene non-detect 700 2-Acetylaminofluorene non-detect 700 2-Chloroethyl vinyl ether non-detect 34 2-Chloronaphthalene non-detect 700 2-Chlorophenol non-detect 700

# Table 8. (Continued) Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 31 2-Picoline non-detect 700 3,3'-Dichlorobenzidine non-detect 700 3-3'-Dimethylbenzidine non-detect 700 3-Methylcholanthrene non-detect 700 4,6-Dinitro-o-cresol non-detect 700 4-Aminobiphenyl non-detect 700 4-Bromophenyl phenyl ether non-detect 700 5-Nitro-o-toluidine non-detect 700 7,12-Dimethylbenz[a]anthracene non-detect 700 Acetonitrile non-detect 34 Acetophenone non-detect 700 Acrolein non-detect 34 Acrylonitrile non-detect 34 Allyl chloride non-detect 34 Aniline non-detect 700 Aramite non-detect 700 Benzene 3300

- Benzidine non-detect 700 Benzo[a]anthracene 610

- Benzo[a]pyrene 530

- Benzo[b]fluoranthene 390

- Benzo[k]fluoranthene non-detect 700 Bromoform non-detect 34 Butyl benzyl phthalate non-detect 700 Carbon disulfide non-detect 34 Carbon tetrachloride non-detect 34 Chlorobenzene non-detect 34 Chlorobenzilate non-detect 700 Chloroform non-detect 34 Chloroprene non-detect 34 Chrysene 610

- cis-1,3-Dichloropropene non-detect 34 Cresol (o-, m-, or p-) non-detect 200 Di-n-butyl phthalate non-detect 700 Di-n-octyl phthalate 360

- Diallate non-detect 700 Dibenz[a,j]acridine non-detect 700 Dibenzo[a,h]anthracene 360

- Dichlorodifluoromethane non-detect 34 Diethyl phthalate non-detect 700 Dimethoate non-detect 700 Dimethyl phthalate non-detect 700 Dinoseb non-detect 700

# Table 8. (Continued) Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 32 Diphenylamine non-detect 700 Disulfoton non-detect 700 Ethyl methacrylate non-detect 34 Ethyl methanesulfonate non-detect 700 Famphur non-detect 700 Fluoranthene non-detect 700 Fluorene 360

- Hexachlorobenzene non-detect 700 Hexachlorobutadiene non-detect 700 Hexachlorocyclopentadiene non-detect 700 Hexachloroethane non-detect 700 Hexachlorophene non-detect 18000 Hexachloropropene non-detect 700 Indeno(1,2,3-cd)pyrene 360

- Isobutyl alcohol non-detect 34 Isodrin non-detect 700 Isosafrole non-detect 700 Kepone non-detect 1400 m-Dichlorobenzene non-detect 700 Methacrylonitrile non-detect 34 Methapyrilene non-detect 700 Methyl bromide non-detect 34 Methyl chloride non-detect 34 Methyl ethyl ketone non-detect 34 Methyl iodide non-detect 34 Methyl methacrylate non-detect 34 Methyl methanesulfonate non-detect 700 Methyl parathion non-detect 700 Methylene chloride non-detect 34 N-Nitrosodi-n-butylamine non-detect 700 N-Nitrosodiethylamine non-detect 700 N-Nitrosomethylethylamine non-detect 700 N-Nitrosomorpholine non-detect 700 N-Nitrosopiperidine non-detect 700 N-Nitrosopyrrolidine non-detect 700 Naphthalene 1300

- Nitrobenzene non-detect 700 o-Dichlorobenzene non-detect 700 o-Toluidine non-detect 1000 O,O,O-Triethyl phosphorothionate non-detect 700 O,O-Diethyl O-pyrazinyl phosphothioate non-detect 700 p-(Dimethylamino)azobenzene non-detect 700 p-Chloro-m-cresol non-detect 700

# Table 8. (Continued) Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 33 p-Chloroaniline non-detect 700 p-Dichlorobenzene non-detect 700 p-Nitroaniline non-detect 700 p-Nitrophenol non-detect 700 p-Phenylenediamine non-detect 700 Parathion non-detect 700 Pentachlorobenzene non-detect 700 Pentachloroethane non-detect 34 Pentachloronitrobenzene non-detect 700 Pentachlorophenol non-detect 700 Phenacetin non-detect 700 Phenol non-detect 700 Phorate non-detect 700 Pronamide non-detect 700 Pyridine non-detect 700 Safrole non-detect 700 Tetrachloroethylene non-detect 34 Tetraethyldithiopyrophosphate non-detect 700 Toluene 25000

- Trichloroethylene non-detect 34 Trichlorofluoromethane non-detect 34 Vinyl Chloride non-detect 34

# Table 1A. Gasoline - Combined Results (VOC non-detects from Composite 246)

Appendix C - 33 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 34 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 30 1,1-Dichloro-1-propene non-detect 30 1,1-Dichloroethane non-detect 34 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 8.8 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 8.8 1,2,3,4-Tetrachlorobenzene non-detect 14 1,2,3,5-Tetrachlorobenzene non-detect 14 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 8.8 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 8.8 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 8.8 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 8.8 1,2,3-Trichlorobenzene non-detect 14 1,2-Dichloroethane non-detect 34 1,2-Dichloropropane non-detect 34 1,3-Dichloro-2-propanol non-detect 30 1,3-Dichloropropane non-detect 30 1,3-Propane sultone non-detect 14 1-Chloronaphthalene non-detect 14 2,2-Dichloropropane non-detect 30 2,3,4,5-Tetrachlorophenol non-detect 14 2,3,4-Trichlorophenol non-detect 14 2,3,5-Trichlorophenol non-detect 14 2,3,6-Trichlorophenol non-detect 14 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 3.5 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 3.5 2,3-Dichloro-1-propene non-detect 30 2,3-Dichlorophenol non-detect 14 2,4-D non-detect 7.0 2,5-Dichlorophenol non-detect 14 2-Fluoroacetamide non-detect 14 2-Methylnaphthalene 1200

- 2-Nitropropane non-detect 30 3,3'-Dimethoxybenzidine non-detect 14 3,4-Dichlorophenol non-detect 14 3,5-Dichlorophenol non-detect 14 3-/4-Chlorophenol non-detect 14

# Table 1A. Gasoline - Combined Results (VOC non-detects from Composite 246)

Appendix C - 34 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

3-Nitroaniline non-detect 670 4,4'-methylene-bis(2-chloroaniline) non-detect 14 4-Aminopyridine non-detect 14 4-Chlorophenyl phenyl ether non-detect 670 6-Propyl-2-thiouracil non-detect 14 Acenaphthene non-detect 670 Acetone cyanohydrin non-detect 14 Allyl alcohol non-detect 30 Ammonium vanadate non-detect 32 Anthracene non-detect 670 Aroclor-1016 non-detect 1.4 Aroclor-1221 non-detect 1.4 Aroclor-1232 non-detect 1.4 Aroclor-1242 non-detect 1.4 Aroclor-1248 non-detect 1.4 Aroclor-1254 non-detect 1.4 Aroclor-1260 non-detect 1.4 Arsenic acid non-detect 0.27 Arsenic pentoxide non-detect 0.22 Arsenic trioxide non-detect 0.19 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 14 Benzenethiol non-detect 30 Benzyl chloride non-detect 14 Bis(2-chloroethoxy)methane non-detect 670 Bis(2-chloroethyl)ether non-detect 670 Bis(2-ethylhexyl)phthalate non-detect 670 Bromide non-detect 5.0 Bromodichloromethane non-detect 34 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 4.2 Chlordane non-detect 14 Chloride 6.2

- Chloroethane non-detect 34 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6

# Table 1A. Gasoline - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 35 Cyanogen Chloride non-detect 103 Di-selenium-tetra-sulfide non-detect 830 Dibenzofuran non-detect 670 Dibromochloromethane non-detect 34 Endosulfan I non-detect 1.4 Endosulfan II non-detect 1.4 Endothall non-detect 14 Endrin non-detect 1.4 Endrin aldehyde non-detect 1.4 Endrin ketone non-detect 1.4 Epichlorohydrin non-detect 30 Ethyl carbamate non-detect 14 Ethylene glycol monoethyl ether non-detect 14 Ethylenethiourea (2-Imidazolidinethione) non-detect 14 Fluoride non-detect 3.0 Heptachlor non-detect 1.4 Heptachlor epoxide non-detect 2.8 Lead acetate non-detect 13 Lead phosphate non-detect 9.2 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 14 Methomyl non-detect 7.0 N-Nitrosodiphenylamine non-detect 670 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 8.2 Nicotine non-detect 14 Octachlorodibenzodioxin non-detect 18 Octachlorodibenzofuran non-detect 18 Osmium tetroxide non-detect 41 Phenanthrene non-detect 670 Phenylthiourea non-detect 7.0 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 30 Pyrene non-detect 670 Selenium dioxide non-detect 0.20 Selenium sulfide non-detect 0.31 Silver Cyanide non-detect 2.6

# Table 1A. Gasoline - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 36 Silvex non-detect 7.0 Strychnine non-detect 14 Tetra-selenium-tetra-sulfide non-detect 1600 Tetraethyl lead non-detect 11 Thallium acetate non-detect 18 Thallium carbonate non-detect 16 Thallium chloride non-detect 17 Thallium nitrate non-detect 18 Thallium oxide non-detect 15 Thallium sulfate non-detect 17 Thioacetamide non-detect 7.0 Thiofanox non-detect 14 Thiourea non-detect 7.0 Toluene-2,4-diamine non-detect 7.0 Toluene-2,6-diamine non-detect 7.0 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 0.37 alpha-BHC non-detect 1.4 beta-BHC non-detect 1.4 delta-BHC non-detect 1.4 gamma-BHC (Lindane) non-detect 1.4 m-Dinitrobenzene non-detect 670 p-Toluidine non-detect 14 trans-1,3-Dichloropropene non-detect 34

# Table 2A. No.2 Fuel Oil - Combined Results

Appendix C - 37 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 34 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 30 1,1-Dichloro-1-propene non-detect 30 1,1-Dichloroethane non-detect 34 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 75 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 75 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 75 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 75 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 75 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 75 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 34 1,2-Dichloropropane non-detect 34 1,3-Dichloro-2-propanol non-detect 30 1,3-Dichloropropane non-detect 30 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 30 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 30 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 30 2,3-Dichloro-1-propene non-detect 30 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 6.0 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 3400

- 2-Nitropropane non-detect 30 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100 3-/4-Chlorophenol non-detect 100 3-Nitroaniline non-detect 1200

# Table 2A. No.2 Fuel Oil - Combined Results

Appendix C - 38 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 1200 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 1200 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 30 Ammonium vanadate non-detect 28 Anthracene non-detect 1200 Aroclor-1016 non-detect 1.2 Aroclor-1221 non-detect 1.2 Aroclor-1232 non-detect 1.2 Aroclor-1242 non-detect 1.2 Aroclor-1248 non-detect 1.2 Aroclor-1254 non-detect 1.2 Aroclor-1260 non-detect 1.2 Arsenic acid non-detect 0.23 Arsenic pentoxide non-detect 0.18 Arsenic trioxide non-detect 0.16 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 30 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 1200 Bis(2-chloroethyl)ether non-detect 1200 Bis(2-ethylhexyl)phthalate non-detect 1200 Bromide non-detect 5.0 Bromodichloromethane non-detect 34 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 3.6 Chlordane non-detect 12 Chloride non-detect 5.0 Chloroethane non-detect 34 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 370

# Table 2A. No.2 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 39 Dibenzofuran non-detect 1200 Dibromochloromethane non-detect 34 Endosulfan I non-detect 1.2 Endosulfan II non-detect 1.2 Endothall non-detect 100 Endrin non-detect 1.2 Endrin aldehyde non-detect 1.2 Endrin ketone non-detect 1.2 Epichlorohydrin non-detect 30 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 12 Fluoride non-detect 3.0 Heptachlor non-detect 1.2 Heptachlor epoxide non-detect 2.4 Lead acetate non-detect 22 Lead phosphate non-detect 15 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 12 Methomyl non-detect 6.0 N-Nitrosodiphenylamine non-detect 1200 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 7.0 Nicotine non-detect 100 Octachlorodibenzodioxin non-detect 150 Octachlorodibenzofuran non-detect 150 Osmium tetroxide non-detect 40 Phenanthrene 860

- Phenylthiourea non-detect 6.0 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 30 Pyrene non-detect 1200 Selenium dioxide non-detect 0.21 Selenium sulfide non-detect 0.34 Silver Cyanide non-detect 2.6 Silvex non-detect 6.0 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 710

# Table 2A. No.2 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 40 Tetraethyl lead non-detect 18 Thallium acetate non-detect 15 Thallium carbonate non-detect 14 Thallium chloride non-detect 14 Thallium nitrate non-detect 16 Thallium oxide non-detect 12 Thallium sulfate non-detect 15 Thioacetamide non-detect 6.0 Thiofanox non-detect 100 Thiourea non-detect 6.0 Toluene-2,4-diamine non-detect 6.0 Toluene-2,6-diamine non-detect 6.0 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 0.32 alpha-BHC non-detect 1.2 beta-BHC non-detect 1.2 delta-BHC non-detect 1.2 gamma-BHC (Lindane) non-detect 1.2 m-Dinitrobenzene non-detect 1200 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 34

# Table 3A. No.4 Fuel Oil - Combined Results

Appendix C - 41 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 17 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 29 1,1-Dichloro-1-propene non-detect 29 1,1-Dichloroethane non-detect 17 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 72 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 72 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 72 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 72 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 72 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 72 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 17 1,2-Dichloropropane non-detect 17 1,3-Dichloro-2-propanol non-detect 29 1,3-Dichloropropane non-detect 29 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 29 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 29 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 29 2,3-Dichloro-1-propene non-detect 29 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 5.7 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 1000

- 2-Nitropropane non-detect 29 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100 3-/4-Chlorophenol non-detect 100 3-Nitroaniline non-detect 200

# Table 3A. No.4 Fuel Oil - Combined Results

Appendix C - 42 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 200 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 200 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 29 Ammonium vanadate non-detect 68 Anthracene non-detect 200 Aroclor-1016 non-detect 1.1 Aroclor-1221 non-detect 1.1 Aroclor-1232 non-detect 1.1 Aroclor-1242 non-detect 1.1 Aroclor-1248 non-detect 1.1 Aroclor-1254 non-detect 1.1 Aroclor-1260 non-detect 1.1 Arsenic acid non-detect 0.43 Arsenic pentoxide non-detect 0.35 Arsenic trioxide non-detect 0.30 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 29 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 200 Bis(2-chloroethyl)ether non-detect 200 Bis(2-ethylhexyl)phthalate non-detect 200 Bromide non-detect 5.0 Bromodichloromethane non-detect 17 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 6.9 Chlordane non-detect 11 Chloride non-detect 5.0 Chloroethane non-detect 17 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 1300

# Table 3A. No.4 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 43 Dibenzofuran non-detect 200 Dibromochloromethane non-detect 17 Endosulfan I non-detect 1.1 Endosulfan II non-detect 1.1 Endothall non-detect 100 Endrin non-detect 1.1 Endrin aldehyde non-detect 1.1 Endrin ketone non-detect 1.1 Epichlorohydrin non-detect 29 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 110 Fluoride non-detect 3.0 Heptachlor non-detect 1.1 Heptachlor epoxide non-detect 2.3 Lead acetate non-detect 34 Lead phosphate non-detect 24 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 110 Methomyl non-detect 57 N-Nitrosodiphenylamine non-detect 200 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 13 Nicotine non-detect 100 Octachlorodibenzodioxin non-detect 140 Octachlorodibenzofuran non-detect 140 Osmium tetroxide non-detect 40 Phenanthrene 250

- Phenylthiourea non-detect 57 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 29 Pyrene non-detect 200 Selenium dioxide non-detect 0.35 Selenium sulfide non-detect 0.56 Silver Cyanide non-detect 2.6 Silvex non-detect 5.7 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 2400

# Table 3A. No.4 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 44 Tetraethyl lead non-detect 29 Thallium acetate non-detect 30 Thallium carbonate non-detect 26 Thallium chloride non-detect 27 Thallium nitrate non-detect 30 Thallium oxide non-detect 24 Thallium sulfate non-detect 28 Thioacetamide non-detect 57 Thiofanox non-detect 100 Thiourea non-detect 57 Toluene-2,4-diamine non-detect 57 Toluene-2,6-diamine non-detect 57 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 0.75 alpha-BHC non-detect 1.1 beta-BHC non-detect 1.1 delta-BHC non-detect 1.1 gamma-BHC (Lindane) non-detect 1.1 m-Dinitrobenzene non-detect 200 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 17

# Table 4A. No.6 Fuel Oil - Combined Results

Appendix C - 45 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 21 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 26 1,1-Dichloro-1-propene non-detect 26 1,1-Dichloroethane non-detect 21 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 64 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 64 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 64 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 64 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 64 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 64 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 21 1,2-Dichloropropane non-detect 21 1,3-Dichloro-2-propanol non-detect 26 1,3-Dichloropropane non-detect 26 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 26 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 26 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 26 2,3-Dichloro-1-propene non-detect 26 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 5.1 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 4200

- 2-Nitropropane non-detect 26 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100 3-/4-Chlorophenol non-detect 100 3-Nitroaniline non-detect 980

# Table 4A. No.6 Fuel Oil - Combined Results

Appendix C - 46 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 980 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 980 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 26 Ammonium vanadate non-detect 590 Anthracene non-detect 980 Aroclor-1016 non-detect 1.0 Aroclor-1221 non-detect 1.0 Aroclor-1232 non-detect 1.0 Aroclor-1242 non-detect 1.0 Aroclor-1248 non-detect 1.0 Aroclor-1254 non-detect 1.0 Aroclor-1260 non-detect 1.0 Arsenic acid non-detect 0.39 Arsenic pentoxide non-detect 0.31 Arsenic trioxide non-detect 0.27 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 26 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 980 Bis(2-chloroethyl)ether non-detect 980 Bis(2-ethylhexyl)phthalate non-detect 980 Bromide non-detect 5.0 Bromodichloromethane non-detect 21 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 6.1 Chlordane non-detect 10 Chloride non-detect 5.0 Chloroethane non-detect 21 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 1400

# Table 4A. No.6 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 47 Dibenzofuran non-detect 980 Dibromochloromethane non-detect 21 Endosulfan I non-detect 1.0 Endosulfan II non-detect 1.0 Endothall non-detect 100 Endrin non-detect 1.0 Endrin aldehyde non-detect 1.0 Endrin ketone non-detect 1.0 Epichlorohydrin non-detect 26 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 100 Fluoride non-detect 3.0 Heptachlor non-detect 1.0 Heptachlor epoxide non-detect 2.0 Lead acetate non-detect 110 Lead phosphate non-detect 79 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 100 Methomyl non-detect 50 N-Nitrosodiphenylamine non-detect 980 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 330 Nicotine non-detect 100 Octachlorodibenzodioxin non-detect 130 Octachlorodibenzofuran non-detect 130 Osmium tetroxide non-detect 40 Phenanthrene 860

- Phenylthiourea non-detect 50 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 26 Pyrene 610

- Selenium dioxide non-detect 0.40 Selenium sulfide non-detect 0.63 Silver Cyanide non-detect 2.6 Silvex non-detect 5.1 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 2600

# Table 4A. No.6 Fuel Oil - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 48 Tetraethyl lead non-detect 94 Thallium acetate non-detect 26 Thallium carbonate non-detect 23 Thallium chloride non-detect 24 Thallium nitrate non-detect 27 Thallium oxide non-detect 21 Thallium sulfate non-detect 25 Thioacetamide non-detect 50 Thiofanox non-detect 100 Thiourea non-detect 50 Toluene-2,4-diamine non-detect 50 Toluene-2,6-diamine non-detect 50 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 11 alpha-BHC non-detect 5.0 beta-BHC non-detect 5.0 delta-BHC non-detect 1.0 gamma-BHC (Lindane) non-detect 1.0 m-Dinitrobenzene non-detect 980 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 21

# Table 5A. Composite 246 50th Percentile - Combined Results

Appendix C - 49 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 17 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 29 1,1-Dichloro-1-propene non-detect 29 1,1-Dichloroethane non-detect 17 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 68 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 68 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 68 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 68 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 68 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 68 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 17 1,2-Dichloropropane non-detect 17 1,3-Dichloro-2-propanol non-detect 29 1,3-Dichloropropane non-detect 29 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 29 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 29 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 29 2,3-Dichloro-1-propene non-detect 29 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 5.4 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 1000

- 2-Nitropropane non-detect 29 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100 3-/4-Chlorophenol non-detect 100 3-Nitroaniline non-detect 200

# Table 5A. Composite 246 50th Percentile - Combined Results

Appendix C - 50 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 200 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 200 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 29 Ammonium vanadate non-detect 28 Anthracene non-detect 200 Aroclor-1016 non-detect 1.1 Aroclor-1221 non-detect 1.1 Aroclor-1232 non-detect 1.1 Aroclor-1242 non-detect 1.1 Aroclor-1248 non-detect 1.1 Aroclor-1254 non-detect 1.1 Aroclor-1260 non-detect 1.1 Arsenic acid non-detect 0.38 Arsenic pentoxide non-detect 0.31 Arsenic trioxide non-detect 0.27 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 29 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 200 Bis(2-chloroethyl)ether non-detect 200 Bis(2-ethylhexyl)phthalate non-detect 200 Bromide non-detect 5.0 Bromodichloromethane non-detect 17 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 6.1 Chlordane non-detect 11 Chloride non-detect 5.0 Chloroethane non-detect 17 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 650 Dibenzofuran non-detect 200

# Table 5A. Composite 246 50th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 51 Dibromochloromethane non-detect 17 Endosulfan I non-detect 1.1 Endosulfan II non-detect 1.1 Endothall non-detect 100 Endrin non-detect 1.1 Endrin aldehyde non-detect 1.1 Endrin ketone non-detect 1.1 Epichlorohydrin non-detect 29 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 100 Fluoride non-detect 3.0 Heptachlor non-detect 1.1 Heptachlor epoxide non-detect 2.3 Lead acetate non-detect 30 Lead phosphate non-detect 21 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 100 Methomyl non-detect 50 N-Nitrosodiphenylamine non-detect 200 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 10 Nicotine non-detect 100 Octachlorodibenzodioxin non-detect 140 Octachlorodibenzofuran non-detect 140 Osmium tetroxide non-detect 40 Phenanthrene 300

- Phenylthiourea non-detect 50 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 29 Pyrene 300

- Selenium dioxide non-detect 0.28 Selenium sulfide non-detect 0.45 Silver Cyanide non-detect 2.6 Silvex non-detect 5.4 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 1200 Tetraethyl lead non-detect 25 Thallium acetate non-detect 26

# Table 5A. Composite 246 50th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 52 Thallium carbonate non-detect 23 Thallium chloride non-detect 24 Thallium nitrate non-detect 26 Thallium oxide non-detect 21 Thallium sulfate non-detect 25 Thioacetamide non-detect 50 Thiofanox non-detect 100 Thiourea non-detect 50 Toluene-2,4-diamine non-detect 50 Toluene-2,6-diamine non-detect 50 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 0.55 alpha-BHC non-detect 1.1 beta-BHC non-detect 1.1 delta-BHC non-detect 1.1 gamma-BHC (Lindane) non-detect 1.1 m-Dinitrobenzene non-detect 200 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 17

# Table 6A. Composite 246 90th Percentile - Combined Results

Appendix C - 53 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 34 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 30 1,1-Dichloro-1-propene non-detect 30 1,1-Dichloroethane non-detect 34 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 74 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 74 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 74 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 74 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 74 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 74 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 34 1,2-Dichloropropane non-detect 34 1,3-Dichloro-2-propanol non-detect 30 1,3-Dichloropropane non-detect 30 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 30 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 30 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 30 2,3-Dichloro-1-propene non-detect 30 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 6.0 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 3200

- 2-Nitropropane non-detect 30 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100 3-/4-Chlorophenol non-detect 100 3-Nitroaniline non-detect 910

# Table 6A. Composite 246 90th Percentile - Combined Results

Appendix C - 54 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 910 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 910 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 30 Ammonium vanadate non-detect 150 Anthracene non-detect 910 Aroclor-1016 non-detect 1.2 Aroclor-1221 non-detect 1.2 Aroclor-1232 non-detect 1.2 Aroclor-1242 non-detect 1.2 Aroclor-1248 non-detect 1.2 Aroclor-1254 non-detect 1.2 Aroclor-1260 non-detect 1.2 Arsenic acid non-detect 0.42 Arsenic pentoxide non-detect 0.34 Arsenic trioxide non-detect 0.29 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 30 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 910 Bis(2-chloroethyl)ether non-detect 910 Bis(2-ethylhexyl)phthalate non-detect 910 Bromide non-detect 5.0 Bromodichloromethane non-detect 34 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 6.7 Chlordane non-detect 12 Chloride non-detect 5.0 Chloroethane non-detect 34 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 1200

# Table 6A. Composite 246 90th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 55 Dibenzofuran non-detect 910 Dibromochloromethane non-detect 34 Endosulfan I non-detect 1.2 Endosulfan II non-detect 1.2 Endothall non-detect 100 Endrin non-detect 1.2 Endrin aldehyde non-detect 1.2 Endrin ketone non-detect 1.2 Epichlorohydrin non-detect 30 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 110 Fluoride non-detect 3.0 Heptachlor non-detect 1.2 Heptachlor epoxide non-detect 2.4 Lead acetate non-detect 74 Lead phosphate non-detect 53 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 110 Methomyl non-detect 55 N-Nitrosodiphenylamine non-detect 910 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 300 Nicotine non-detect 1300 Octachlorodibenzodioxin non-detect 150 Octachlorodibenzofuran non-detect 150 Osmium tetroxide non-detect 40 Phenanthrene 820

- Phenylthiourea non-detect 55 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 30 Pyrene 600

- Selenium dioxide non-detect 0.34 Selenium sulfide non-detect 0.54 Silver Cyanide non-detect 2.6 Silvex non-detect 6.0 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 2400

# Table 6A. Composite 246 90th Percentile - Combined Results

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 56 Tetraethyl lead non-detect 63 Thallium acetate non-detect 29 Thallium carbonate non-detect 25 Thallium chloride non-detect 26 Thallium nitrate non-detect 29 Thallium oxide non-detect 23 Thallium sulfate non-detect 27 Thioacetamide non-detect 55 Thiofanox non-detect 100 Thiourea non-detect 55 Toluene-2,4-diamine non-detect 55 Toluene-2,6-diamine non-detect 55 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 2.7 alpha-BHC non-detect 1.2 beta-BHC non-detect 1.2 delta-BHC non-detect 1.2 gamma-BHC (Lindane) non-detect 1.2 m-Dinitrobenzene non-detect 910 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 34

# Table 7A. Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Appendix C - 57 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 17 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 29 1,1-Dichloro-1-propene non-detect 29 1,1-Dichloroethane non-detect 17 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 64 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 64 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 64 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 64 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 64 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 64 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 17 1,2-Dichloropropane non-detect 17 1,3-Dichloro-2-propanol non-detect 29 1,3-Dichloropropane non-detect 29 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 29 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 26 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 26 2,3-Dichloro-1-propene non-detect 29 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 5.7 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 1000

- 2-Nitropropane non-detect 29 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100

# Table 7A. Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Appendix C - 58 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

3-/4-Chlorophenol non-detect 100 3-Nitroaniline non-detect 220 4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 220 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 220 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 29 Ammonium vanadate non-detect 31 Anthracene non-detect 220 Aroclor-1016 non-detect 1.1 Aroclor-1221 non-detect 1.1 Aroclor-1232 non-detect 1.1 Aroclor-1242 non-detect 1.1 Aroclor-1248 non-detect 1.1 Aroclor-1254 non-detect 1.1 Aroclor-1260 non-detect 1.1 Arsenic acid non-detect 0.27 Arsenic pentoxide non-detect 0.22 Arsenic trioxide non-detect 0.19 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 29 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 220 Bis(2-chloroethyl)ether non-detect 220 Bis(2-ethylhexyl)phthalate non-detect 220 Bromide non-detect 5.0 Bromodichloromethane non-detect 17 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 4.2 Chlordane non-detect 11 Chloride 2.6

- Chloroethane non-detect 17 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0

# Table 7A. Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 59 Cyanogen Bromide non-detect 6.6 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 420 Dibenzofuran non-detect 220 Dibromochloromethane non-detect 17 Endosulfan I non-detect 1.1 Endosulfan II non-detect 1.1 Endothall non-detect 100 Endrin non-detect 1.1 Endrin aldehyde non-detect 1.1 Endrin ketone non-detect 1.1 Epichlorohydrin non-detect 29 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 14 Fluoride non-detect 3.0 Heptachlor non-detect 1.1 Heptachlor epoxide non-detect 2.3 Lead acetate non-detect 26 Lead phosphate non-detect 18 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 14 Methomyl non-detect 7.0 N-Nitrosodiphenylamine non-detect 220 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 8.2 Nicotine non-detect 100 Octachlorodibenzodioxin non-detect 130 Octachlorodibenzofuran non-detect 130 Osmium tetroxide non-detect 40 Phenanthrene 250

- Phenylthiourea non-detect 7.0 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 29 Pyrene 140

- Selenium dioxide non-detect 0.26 Selenium sulfide non-detect 0.41

# Table 7A. Composite All 50th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 60 Silver Cyanide non-detect 2.6 Silvex non-detect 5.7 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 810 Tetraethyl lead non-detect 22 Thallium acetate non-detect 18 Thallium carbonate non-detect 16 Thallium chloride non-detect 17 Thallium nitrate non-detect 18 Thallium oxide non-detect 15 Thallium sulfate non-detect 17 Thioacetamide non-detect 7.0 Thiofanox non-detect 100 Thiourea non-detect 7.0 Toluene-2,4-diamine non-detect 7.0 Toluene-2,6-diamine non-detect 7.0 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 0.37 alpha-BHC non-detect 1.2 beta-BHC non-detect 1.2 delta-BHC non-detect 1.1 gamma-BHC (Lindane) non-detect 1.1 m-Dinitrobenzene non-detect 220 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 17

# Table 8A. Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Appendix C - 61 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

1,1,1-Trichloroethane non-detect 34 1,1,2-Trichloro-1,2,2-trifluoroethane non-detect 30 1,1-Dichloro-1-propene non-detect 30 1,1-Dichloroethane non-detect 34 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin non-detect 74 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan non-detect 74 1,2,3,4-Tetrachlorobenzene non-detect 100 1,2,3,5-Tetrachlorobenzene non-detect 100 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin non-detect 74 1,2,3,6,7,8-Hexachlorodibenzo-p-furan non-detect 74 1,2,3,7,8-Pentachlorodibenzo-p-dioxin non-detect 74 1,2,3,7,8-Pentachlorodibenzo-p-furan non-detect 74 1,2,3-Trichlorobenzene non-detect 100 1,2-Dichloroethane non-detect 34 1,2-Dichloropropane non-detect 34 1,3-Dichloro-2-propanol non-detect 30 1,3-Dichloropropane non-detect 30 1,3-Propane sultone non-detect 100 1-Chloronaphthalene non-detect 100 2,2-Dichloropropane non-detect 30 2,3,4,5-Tetrachlorophenol non-detect 100 2,3,4-Trichlorophenol non-detect 100 2,3,5-Trichlorophenol non-detect 100 2,3,6-Trichlorophenol non-detect 100 2,3,7,8-Tetrachlorodibenzo-p-dioxin non-detect 30 2,3,7,8-Tetrachlorodibenzo-p-furan non-detect 30 2,3-Dichloro-1-propene non-detect 30 2,3-Dichlorophenol non-detect 100 2,4-D non-detect 6.7 2,5-Dichlorophenol non-detect 100 2-Fluoroacetamide non-detect 100 2-Methylnaphthalene 2500

- 2-Nitropropane non-detect 30 3,3'-Dimethoxybenzidine non-detect 100 3,4-Dichlorophenol non-detect 100 3,5-Dichlorophenol non-detect 100 3-/4-Chlorophenol non-detect 100

# Table 8A. Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Appendix C - 62 Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)

3-Nitroaniline non-detect 700 4,4'-methylene-bis(2-chloroaniline) non-detect 100 4-Aminopyridine non-detect 100 4-Chlorophenyl phenyl ether non-detect 700 6-Propyl-2-thiouracil non-detect 100 Acenaphthene non-detect 700 Acetone cyanohydrin non-detect 100 Allyl alcohol non-detect 30 Ammonium vanadate non-detect 86 Anthracene non-detect 700 Aroclor-1016 non-detect 1.3 Aroclor-1221 non-detect 1.3 Aroclor-1232 non-detect 1.3 Aroclor-1242 non-detect 1.3 Aroclor-1248 non-detect 1.3 Aroclor-1254 non-detect 1.3 Aroclor-1260 non-detect 1.3 Arsenic acid non-detect 0.41 Arsenic pentoxide non-detect 0.34 Arsenic trioxide non-detect 0.29 Barium Cyanide non-detect 3.7 Benzal chloride non-detect 100 Benzenethiol non-detect 30 Benzyl chloride non-detect 100 Bis(2-chloroethoxy)methane non-detect 700 Bis(2-chloroethyl)ether non-detect 700 Bis(2-ethylhexyl)phthalate non-detect 700 Bromide non-detect 5.0 Bromodichloromethane non-detect 34 Calcium Cyanide non-detect 1.8 Calcium chromate non-detect 6.6 Chlordane non-detect 13 Chloride 2.7

- Chloroethane non-detect 34 Copper Cyanide non-detect 1.7 Cyanide non-detect 1.0 Cyanogen Bromide non-detect 6.6

# Table 8A. Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 63 Cyanogen Chloride non-detect 8.6 Di-selenium-tetra-sulfide non-detect 1200 Dibenzofuran non-detect 700 Dibromochloromethane non-detect 34 Endosulfan I non-detect 1.3 Endosulfan II non-detect 1.3 Endothall non-detect 100 Endrin non-detect 1.3 Endrin aldehyde non-detect 1.3 Endrin ketone non-detect 1.3 Epichlorohydrin non-detect 30 Ethyl carbamate non-detect 100 Ethylene glycol monoethyl ether non-detect 100 Ethylenethiourea (2-Imidazolidinethione) non-detect 110 Fluoride non-detect 3.0 Heptachlor non-detect 1.3 Heptachlor epoxide non-detect 2.7 Lead acetate non-detect 74 Lead phosphate non-detect 53 MNNG (N-Metyl-N-nitroso-N'-nitroguanidine) non-detect 110 Methomyl non-detect 54 N-Nitrosodiphenylamine non-detect 700 Nickel Cyanide non-detect 3.5 Nickel carbonyl non-detect 46 Nicotine non-detect 100 Octachlorodibenzodioxin non-detect 150 Octachlorodibenzofuran non-detect 150 Osmium tetroxide non-detect 40 Phenanthrene 730

- Phenylthiourea non-detect 54 Potassium Cyanide non-detect 2.5 Potassium Silver Cyanide non-detect 2.9 Propargyl alcohol non-detect 30 Pyrene 600

- Selenium dioxide non-detect 0.34 Selenium sulfide non-detect 0.53 Silver Cyanide non-detect 2.6

# Table 8A. Composite All 90th Percentile - Combined Results (VOC non-detects from Composite 246)

Chemical Name Concentration Limit (mg/kg at 10,000 BTU/lb) Minimum Detection

Limit (mg/kg)



# Appendix C - 64 Silvex non-detect 6.7 Strychnine non-detect 100 Tetra-selenium-tetra-sulfide non-detect 2300 Tetraethyl lead non-detect 63 Thallium acetate non-detect 28 Thallium carbonate non-detect 25 Thallium chloride non-detect 26 Thallium nitrate non-detect 29 Thallium oxide non-detect 23 Thallium sulfate non-detect 27 Thioacetamide non-detect 54 Thiofanox non-detect 100 Thiourea non-detect 54 Toluene-2,4-diamine non-detect 54 Toluene-2,6-diamine non-detect 54 Vanadium pentoxide non-detect 18 Zinc Cyanide non-detect 2.3 Zinc phosphide non-detect 1.7 alpha-BHC non-detect 1.4 beta-BHC non-detect 1.4 delta-BHC non-detect 1.3 gamma-BHC (Lindane) non-detect 1.3 m-Dinitrobenzene non-detect 700 p-Toluidine non-detect 100 trans-1,3-Dichloropropene non-detect 34

# Appendix D

MDL Data

# METHOD DETECTION LIMIT STUDY BY GCMS 8240 - VOA

Fuel = Gasoline Compound Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

### Dichlorodifluoromethane 40 38 35 41 41 38 37 7 Chloromethane 57 57 54 60 60 56 57 7 Vinyl Chloride 56 57 54 59 59 54 56 6 Bromomethane 56 63 70 65 72 66 64 16 Chloroethane 54 59 55 57 60 53 55 9 Trichlorofluoromethane 50 52 116 52 58 74 52 76 1,1-Dichloroethene 53 53 51 53 53 52 53 3 Acetone 68 65 62 64 61 59 59 10 Iodomethane 54 55 53 55 54 54 54 2 Carbon disulfide 78 80 76 80 81 76 77 6 Allyl chloride 53 54 52 55 53 54 53 3 Methylene chloride 56 50 50 53 51 49 52 7 trans-1,2-Dichloroethene 53 55 53 55 54 54 53 2 1,1-Dichloroethane 46 47 48 48 47 48 47 2 cis-1,2-Dichloroethene 54 53 54 53 53 54 53 2 2-Butanone 54 50 49 50 47 50 47 7 Methacrylonitrile 49 42 44 43 43 44 43 7 Chloroform 46 45 46 47 45 47 45 2 1,2-Dichloroethane 47 46 47 48 47 48 46 2 Vinyl acetate 45 45 45 45 46 44 45 1 1,1,1-Trichloroethane 48 49 49 49 49 48 49 1 Carbon tetrachloride 50 51 50 52 51 50 50 2 Benzene 81 82 81 83 83 81 81 2 Trichloroethene 53 52 52 53 53 52 52 2 1,2-Dichloropropane 47 47 47 47 47 46 47 1 Dibromomethane 49 48 48 48 48 48 48 2 Methyl methacrylate 51 51 51 50 51 51 51 1 Bromodichloromethane 47 45 46 46 46 45 45 2 2-Chloroethylvinyl ether 26 25 26 24 25 24 25 2 cis-1,3-Dichloropropene 48 46 47 46 46 46 46 2 trans-1,3-Dichloropropene 45 44 44 44 44 44 44 2 Ethyl methacrylate 45 43 44 44 44 44 44 2 1,1,2-Trichloroethane 43 41 42 41 42 42 41 2 Dibromochloromethane 44 41 42 41 42 42 42 3 Bromoform 45 42 42 42 41 43 43 4 1,1,2,2-Tetrachloroethane 44 43 43 42 42 44 44 2 Acrolein 405 431 353 415 395 381 406 79 Acetonitrile 66 70 66 68 67 67 69 5 Acrylonitrile 56 46 43 47 45 44 49 14 Propionitrile 47 46 44 45 44 46 46 3 Isobutanol 111 46 46 43 44 44 47 79 p-Dioxane 49 47 46 46 47 47 48 4 cis-1,4-Dichloro-2-butene 45 41 41 42 41 42 42 4 trans-1,4-Dichloro-2-butene 46 45 45 44 44 46 45 3 4-Methyl-2-pentanone 48 47 47 48 48 47 47 1 Toluene 257 266 262 266 264 262 260 10 Tetrachloroethene 56 56 55 56 56 54 54 3 2-Hexanone 49 46 46 45 45 46 45 4 1,2-Dibromoethane 50 49 49 49 49 49 50 2 Chlorobenzene 49 49 48 48 49 49 48 1 

## Appendix D - 1

# METHOD DETECTION LIMIT STUDY BY GCMS 8240 - VOA

Fuel = Gasoline Compound Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

### Ethylbenzene 94 94 94 94 95 94 94 1 m,p-Xylene 132 133 130 132 132 132 131 2 o-Xylene 111 112 110 110 111 112 111 2 Styrene 50 49 48 48 48 49 49 1 1,2,3,-Trichloropropane 53 51 52 51 51 52 43 10 Pentachloraethane 44 43 44 43 43 44 44 2 1,3-Dichlorobenzene 45 44 44 44 44 45 44 1 1,4-Dichlorobenzene 44 43 43 43 43 44 44 2 1,2-Dichlorobenzene 44 43 44 42 43 43 43 2 1,2-Dibromo-3-chloropropane 45 43 43 42 44 43 43 3 1,2,4-Trichlorobenzene 43 42 42 42 43 43 43 1
Comments: 1) All values are in ug/Kg 2) Spiked amount = 50ug/Kg 3) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses



## Appendix D - 2

# METHOD DETECTION LIMIT STUDY BY GCMS 8240 - VOA

Fuel = No.2 Compound Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

### Dichlorodifluoromethane 29 32 37 38 36 37 37 10 Chloromethane 42 44 44 46 42 43 44 4 Vinyl Chloride 41 43 43 45 42 43 44 4 Bromomethane 46 49 54 52 48 58 45 15 Chloroethane 44 52 49 48 48 49 50 8 Trichlorofluoromethane 127 134 137 136 130 137 140 14 1,1-Dichloroethene 44 45 44 46 43 45 46 3 Acetone 60 59 58 57 60 57 57 4 Iodomethane 45 47 47 47 45 47 48 3 Carbon disulfide 64 67 67 67 63 67 68 6 Allyl chloride 45 46 46 45 46 46 47 3 Methylene chloride 44 46 45 45 44 45 46 2 trans-1,2-Dichloroethene 49 51 50 50 49 50 51 3 1,1-Dichloroethane 43 45 44 44 44 43 44 2 cis-1,2-Dichloroethene 49 50 49 49 50 49 49 1 2-Butanone 50 49 50 51 53 49 48 5 Methacrylonitrile 49 45 45 46 47 43 44 6 Chloroform 46 46 47 46 47 45 46 2 1,2-Dichloroethane 50 51 50 50 50 48 50 2 Vinyl acetate 41 42 41 40 39 41 41 3 1,1,1-Trichloroethane 44 45 46 45 44 45 45 2 Carbon tetrachloride 45 46 47 46 45 47 46 2 Benzene 120 124 124 121 120 123 122 6 Trichloroethene 50 50 51 49 50 50 49 2 1,2-Dichloropropane 47 48 48 47 48 47 47 1 Dibromomethane 49 48 49 48 50 50 48 2 Methyl methacrylate 60 60 61 60 61 59 59 2 Bromodichloromethane 45 46 46 45 47 45 47 2 2-Chloroethylvinyl ether 25 25 25 24 25 25 24 2 cis-1,3-Dichloropropene 48 48 48 47 48 47 46 2 trans-1,3-Dichloropropene 47 47 47 47 48 47 46 2 Ethyl methacrylate 50 50 49 48 51 48 48 4 1,1,2-Trichloroethane 45 48 47 47 46 47 46 3 Dibromochloromethane 43 45 45 45 46 45 45 3 Bromoform 40 42 42 42 42 42 42 2 1,1,2,2-Tetrachloroethane 53 55 53 54 53 54 52 2 Acrolein 450 470 438 438 403 483 453 80 Acetonitrile 48 53 50 50 46 53 51 8 Acrylonitrile 34 34 32 31 31 33 33 3 Propionitrile 37 39 38 37 38 38 38 2 Isobutanol 111 122 119 118 109 125 123 19 p-Dioxane 44 45 43 42 42 44 44 3 cis-1,4-Dichloro-2-butene 42 43 43 43 44 45 43 3 trans-1,4-Dichloro-2-butene 43 53 43 50 42 52 44 15 4-Methyl-2-pentanone 49 49 50 50 49 50 50 1 Toluene 419 427 426 422 416 425 426 13 Tetrachloroethene 52 54 54 54 53 54 55 3 2-Hexanone 46 46 48 47 48 46 46 2 1,2-Dibromoethane 46 47 48 48 47 47 47 1 Chlorobenzene 49 49 49 49 49 49 49 1 

## Appendix D - 1

# METHOD DETECTION LIMIT STUDY BY GCMS 8240 - VOA

Fuel = No.2 Compound Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

### Ethylbenzene 170 170 173 172 171 172 173 4 m,p-Xylene 247 245 249 249 248 246 248 4 o-Xylene 211 211 212 214 212 212 213 3 Styrene 52 52 53 53 53 52 53 1 1,2,3,-Trichloropropane 42 41 42 42 42 42 42 1 Pentachloraethane 42 40 42 42 41 41 41 2 1,3-Dichlorobenzene 45 45 46 46 46 45 46 1 1,4-Dichlorobenzene 44 45 45 45 45 45 45 1 1,2-Dichlorobenzene 43 43 44 44 44 43 44 2 1,2-Dibromo-3-chloropropane 44 46 47 45 44 43 47 5 1,2,4-Trichlorobenzene 43 46 53 46 44 44 44 11
Comments: 1) All values are in ug/Kg 2) Spiked amount = 50ug/Kg 3) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses



## Appendix D - 2

# METHOD DETECTION LIMIT STUDY BY GCMS 8240 - VOA

Fuel = No.6 Compound Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

### Dichlorodifluoromethane 48 44 38 49 50 44 44 13 Chloromethane 54 52 42 53 51 49 48 12 Vinyl Chloride 53 51 43 53 52 49 49 11 Bromomethane 53 64 47 73 52 52 63 29 Chloroethane 50 53 48 52 56 50 49 8 Trichlorofluoromethane 52 52 45 53 51 52 50 8 1,1-Dichloroethene 51 50 46 51 50 51 51 5 Acetone 49 51 50 49 52 51 50 3 Iodomethane 51 50 48 51 50 50 51 3 Carbon disulfide 52 52 46 52 50 51 50 7 Allyl chloride 51 51 48 51 49 51 51 3 Methylene chloride 50 50 50 51 49 51 51 3 trans-1,2-Dichloroethene 50 49 49 49 48 50 50 2 1,1-Dichloroethane 50 50 51 51 50 51 51 2 cis-1,2-Dichloroethene 47 46 47 47 47 47 47 2 2-Butanone 49 50 48 49 51 47 47 5 Methacrylonitrile 47 48 47 48 48 48 46 2 Chloroform 50 50 49 50 50 51 50 2 1,2-Dichloroethane 49 50 49 50 50 50 49 2 Vinyl acetate 50 50 50 51 51 51 51 1 1,1,1-Trichloroethane 48 50 50 50 49 50 50 2 Carbon tetrachloride 49 49 50 49 49 49 51 2 Benzene 51 51 51 51 51 51 52 2 Trichloroethene 50 50 50 50 50 51 50 1 1,2-Dichloropropane 51 51 51 51 52 50 51 2 Dibromomethane 47 47 47 47 48 47 48 2 Methyl methacrylate 49 49 48 48 49 47 48 3 Bromodichloromethane 49 50 49 50 51 49 49 2 2-Chloroethylvinyl ether 54 54 51 53 54 52 52 4 cis-1,3-Dichloropropene 51 50 49 50 51 49 50 2 trans-1,3-Dichloropropene 50 51 49 50 51 48 49 4 Ethyl methacrylate 48 49 46 48 50 47 47 4 1,1,2-Trichloroethane 49 49 47 49 51 48 48 4 Dibromochloromethane 49 49 47 49 50 49 47 3 Bromoform 46 46 45 45 46 45 43 4 1,1,2,2-Tetrachloroethane 49 50 48 48 50 48 47 3 Acrolein 37 55 50 32 51 62 48 32 Acetonitrile 46 47 47 46 43 46 47 4 Acrylonitrile 48 48 49 47 48 49 49 2 Propionitrile 44 45 46 44 45 45 44 2 Isobutanol 47 47 44 45 45 45 43 5 p-Dioxane 47 46 46 45 46 45 45 2 cis-1,4-Dichloro-2-butene 48 46 46 45 47 45 44 4 trans-1,4-Dichloro-2-butene 44 45 44 43 45 43 43 2 4-Methyl-2-pentanone 50 50 49 49 50 49 49 1 Toluene 52 53 54 53 53 54 54 3 Tetrachloroethene 48 49 51 50 49 50 51 3 2-Hexanone 50 51 50 51 50 51 50 2 1,2-Dibromoethane 47 48 47 48 47 48 47 1 Chlorobenzene 49 49 49 49 49 50 49 1 

## Appendix D - 1

# METHOD DETECTION LIMIT STUDY BY GCMS 8240 - VOA

Fuel = No.6 Compound Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

### Ethylbenzene 50 50 50 51 49 51 49 2 m,p-Xylene 53 54 53 54 53 53 53 1 o-Xylene 51 51 52 51 52 51 51 1 Styrene 49 49 49 49 49 49 48 1 1,2,3,-Trichloropropane 57 59 46 49 49 48 56 16 Pentachloraethane 46 49 46 48 48 48 46 4 1,3-Dichlorobenzene 50 51 48 50 50 49 48 3 1,4-Dichlorobenzene 49 50 48 49 50 49 48 3 1,2-Dichlorobenzene 48 49 47 48 49 47 46 4 1,2-Dibromo-3-chloropropane 46 47 44 45 46 46 44 3 1,2,4-Trichlorobenzene 46 47 44 46 45 45 44 4
Comments: 1) All values are in ug/Kg 2) Spiked amount = 50ug/Kg 3) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses



## Appendix D - 2

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = Gasoline Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Acenaphthene 24 25 25 24 25 23 25 2 Acenaphthylene 21 21 22 20 21 20 21 1 Acetophenone 17 18 20 13 19 18 18 7 2-Acetylaminofluorene 15 17 18 17 16 18 16 3 4-Aminobiphenyl 19 20 20 19 20 20 20 1 Aniline 27 21 27 21 17 15 21 14 Anthracene 25 24 24 24 24 24 24 1 Aramite 15 14 17 16 15 16 15 3 Benzidine 16 17 19 18 15 19 16 5 Benzo[a]anthracene 19 19 19 19 19 19 19 0.3 Benzo[a]pyrene 19 19 18 19 18 19 18 0.4 Benzo[b]fluoranthene 16 17 16 17 17 15 17 2 Benzo[g,h,i]perylene 14 15 19 18 15 20 15 7 Benzo[k]fluoranthene 23 21 21 21 22 21 21 2 Benzyl Alcohol 19 19 18 18 19 18 19 2 Bis(2-chloroethoxy)methane 17 17 18 17 16 18 16 2 Bis(2-chloroethyl)ether 12 11 18 15 11 9 26 18 Bis(2-chloroisopropyl)ether 6 6 6 6 7 6 6 1 Bis(2-ethylhexyl)phthalate 15 15 17 16 15 16 15 2 4-Bromophenyl phenyl ether 23 23 24 23 23 23 23 2 Butyl benzyl phthalate 16 17 18 17 17 17 17 1 Di-n-butylphthalate 20 19 20 19 20 19 19 1 4-Chloroaniline 27 29 30 29 29 28 30 4 Chlorobenzilate 17 17 19 18 17 18 17 2 4-Chloro-3-methylphenol 23 24 23 22 23 24 24 2 2-Chloronaphthalene 19 20 21 20 20 21 20 2 2-Chlorophenol 13 12 11 12 12 11 13 2 4-Chlorophenyl phenyl ether 19 19 20 19 20 19 20 1 Chrysene 20 20 19 20 20 20 20 1 Diallate 19 19 21 19 19 20 19 2 Dibenz[a,j]acridine 15 15 19 18 14 19 15 7 Dibenzo[a,h]anthracene 15 15 18 17 14 19 14 6 Dibenzofuran 19 20 20 19 20 20 20 1 1,2-Dichlorobenzene 14 14 13 13 14 13 14 1 1,3-Dichlorobenzene 17 18 18 16 18 17 17 2 1,4-Dichlorobenzene 18 17 17 18 18 18 18 2 3,3'-Dichlorobenzidine 18 18 19 19 18 18 18 1 2,4-Dichlorophenol 29 30 29 29 29 28 30 2 2,6-Dichlorophenol 26 27 27 27 26 27 27 1 Diethyl phthalate 19 19 19 18 19 18 19 2 Dimethoate 15 16 18 17 15 18 15 5 p-Dimethylaminoazobenzene 17 17 19 18 17 18 17 2 7,12-Dimethylbenz[a]anthracene 20 20 18 19 20 18 20 3 3-3'-Dimethylbenzidine 15 15 16 16 15 16 15 2 a,a-Dimethylphenethylamine 0 0 0 0 0 0 0 ND 2,4-Dimethylphenol 21 19 21 21 20 21 20 2 Dimethyl phthalate 19 19 20 18 19 18 19 2 m-Dinitrobenzene 19 20 21 19 21 20 21 3 4,6-Dinitro-2-methylphenol 14 15 16 16 16 17 17 3 2,4-Dinitrophenol 11 13 14 13 14 14 15 4 2,4-Dinitrotoluene 18 19 19 18 19 19 20 2 2,6-Dinitrotoluene 17 18 18 17 19 17 19 2 Dinoseb 13 15 16 15 16 16 16 3 Diphenylamine 25 26 26 25 25 25 25 1 Disulfoton 18 19 20 19 19 19 19 2 Ethylmethanesulfonate 27 29 25 28 28 8 30 24 Famphur 16 15 23 23 15 23 15 13 Fluoranthene 22 22 21 21 22 20 22 3 Fluorene 23 23 23 23 23 22 23 1 Hexachlorobenzene 23 23 24 23 23 24 23 2 Appendix D - 1

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = Gasoline Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Hexachlorobutadiene 24 24 25 24 24 26 24 2 Hexachlorocyclopentadiene 13 13 16 15 14 15 14 4 Hexachloroethane 54 191 23 29 27 16 28 195 Hexachlorophene 0 0 0 0 0 0 0 ND Hexachloropropene 19 20 21 21 20 23 21 4 Indeno(1,2,3-c,d)pyrene 18 18 22 21 17 23 18 8 Isodrin 20 20 20 19 20 20 20 1 Isophorone 16 20 17 16 20 20 17 6 Isosafrole 13 13 24 25 19 27 26 19 Kepone 26 25 29 30 24 29 24 8 Methapyrilene 18 18 19 19 18 18 17 2 Methyl parathion 16 15 19 17 15 18 16 5 3-Methylcholanthrene 18 18 18 18 18 18 18 1 Methylmethanesulfonate 28 26 26 28 27 27 31 6 2-Methylnaphthalene 256 249 272 264 248 285 252 44 2-Methylphenol 24 27 25 27 27 22 28 7 4-Methylphenol 19 18 18 17 18 18 18 2 Naphthalene 207 201 232 210 207 240 190 55 1,4-Naphthoquinone 15 14 15 15 15 14 16 2 1-Naphthylamine 22 22 23 21 22 20 22 3 2-Naphthylamine 23 24 23 22 24 22 23 2 2-Nitroaniline 17 17 17 17 18 16 18 2 3-Nitroaniline 22 23 21 21 23 21 23 2 4-Nitroaniline 26 26 24 24 25 22 26 5 Nitrobenzene 22 56 17 14 19 21 26 44 2-Nitrophenol 19 20 21 20 21 21 21 2 4-Nitrophenol 31 13 14 19 11 13 21 21 4-Nitroquinoline-1-oxide 6 7 10 9 7 10 7 5 N-Nitroso-di-n-butylamine 22 23 24 22 22 23 22 2 N-Nitrosodiethylamine 20 20 14 19 16 17 17 7 N-Nitrosodiphenylamine 21 20 21 20 20 20 20 2 N-Nitrosodi-n-propylamine 39 29 25 26 13 14 21 28 N-Nitrosomethylethylamine 9 11 12 12 12 12 13 3 N-Nitrosomorpholine 70 70 34 19 19 16 32 74 N-Nitrosopiperidine 20 20 19 21 21 21 22 3 N-Nitrosopyrrolidine 14 14 13 14 13 13 14 2 5-Nitro-o-toluidine 22 22 22 21 23 20 23 3 Di-n-octylphthalate 16 16 15 16 16 15 16 1 Parathion 18 18 19 19 18 19 19 2 Pentachlorobenzene 20 20 21 20 20 20 21 1 Pentachloronitrobenzene 22 22 23 22 22 22 22 1 Pentachlorophenol 18 18 18 18 18 18 18 1 Phenacetin 20 20 20 20 20 19 20 1 Phenanthrene 20 21 21 20 21 20 21 1 Phenol 18 16 15 15 17 13 17 5 p-Phenylenediamine 14 15 15 15 14 15 14 2 Phorate 15 15 16 15 15 15 15 1 2-Picoline 8 14 15 19 21 18 20 14 Pronamide 19 19 20 19 19 19 19 1 Pyrene 20 20 21 21 20 20 20 1 Pyridine 8 7 9 11 8 9 9 4 Safrole 17 17 18 17 18 19 18 2 Sulfotep 20 20 22 21 20 21 20 3 1,2,4,5-Tetrachlorobenzene 20 20 20 19 20 21 20 1 2,3,4,6-Tetrachlorophenol 23 23 22 22 23 22 24 2 Thionzin 19 20 21 20 20 20 20 2 o-Toluidine 28 21 24 21 26 18 27 12 1,2,4-Trichlorobenzene 23 23 23 23 23 24 23 1 2,4,5-Trichlorophenol 16 17 19 16 17 18 17 3 2,4,6-Trichlorophenol 24 25 24 24 25 23 25 2 Appendix D - 2

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = Gasoline Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL O,O,O-Triethylphosphorothioate 18 18 19 18 18 18 17 2 1,3,5-Trinitrobenzene 12 14 14 14 14 14 15 4

Comments: 1) All values in ug/Kg 2) Spiked amount = 100ug/Kg 3) ND = Not detected 4) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses

Appendix D - 3

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.2 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Acenaphthene 149 134 143 143 137 145 147 17 Acenaphthylene 131 125 131 126 134 129 125 11 Acetophenone 68 78 68 64 71 65 64 15 2-Acetylaminofluorene 114 108 109 111 115 111 113 8 4-Aminobiphenyl 117 119 111 119 117 117 121 10 Aniline 102 113 111 100 104 104 99 17 Anthracene 101 106 103 108 108 100 100 11 Aramite 114 108 110 120 117 115 114 13 Benzidine 94 97 97 92 98 98 97 7 Benzo[a]anthracene 111 107 108 111 112 112 112 7 Benzo[a]pyrene 102 103 103 102 103 102 102 2 Benzo[b]fluoranthene 111 98 105 108 105 106 101 13 Benzo[g,h,i]perylene 132 140 133 125 140 141 141 19 Benzo[k]fluoranthene 91 102 103 91 91 87 96 19 Benzyl Alcohol 94 98 99 93 87 88 88 16 Bis(2-chloroethoxy)methane 110 87 109 112 112 113 105 29 Bis(2-chloroethyl)ether 91 101 96 93 85 94 96 16 Bis(2-chloroisopropyl)ether 62 66 69 65 64 64 64 7 Bis(2-ethylhexyl)phthalate 110 106 105 120 107 110 108 16 4-Bromophenyl phenyl ether 120 118 122 123 118 115 120 8 Butyl benzyl phthalate 111 102 105 116 108 109 106 14 Di-n-butylphthalate 131 132 134 132 128 131 126 8 4-Chloroaniline 119 111 114 115 113 117 114 9 Chlorobenzilate 119 112 116 124 116 118 114 12 4-Chloro-3-methylphenol 71 64 75 68 71 66 71 12 2-Chloronaphthalene 127 131 129 135 127 127 128 10 2-Chlorophenol 66 71 69 67 68 70 67 6 4-Chlorophenyl phenyl ether 110 100 111 107 110 106 99 15 Chrysene 115 111 113 115 115 115 114 5 Diallate 108 109 113 111 107 119 111 12 Dibenz[a,j]acridine 110 115 109 103 114 113 116 15 Dibenzo[a,h]anthracene 108 115 113 107 119 119 117 16 Dibenzofuran 121 108 114 117 116 129 111 22 1,2-Dichlorobenzene 101 108 107 102 100 99 98 13 1,3-Dichlorobenzene 82 118 106 95 103 104 102 35 1,4-Dichlorobenzene 114 92 101 98 73 86 87 40 3,3'-Dichlorobenzidine 105 100 101 102 103 104 107 8 2,4-Dichlorophenol 105 103 108 110 105 114 110 11 2,6-Dichlorophenol 103 98 109 102 107 100 103 12 Diethyl phthalate 80 76 81 80 77 83 82 8 Dimethoate 102 107 106 105 108 102 110 9 p-Dimethylaminoazobenzene 127 117 120 134 126 126 123 17 7,12-Dimethylbenz[a]anthracene 98 94 101 104 97 95 97 11 3-3'-Dimethylbenzidine 115 113 113 107 112 112 108 8 a,a-Dimethylphenethylamine 0 0 0 0 0 0 0 ND 2,4-Dimethylphenol 117 102 111 114 117 121 117 20 Dimethyl phthalate 88 87 86 86 88 90 88 5 m-Dinitrobenzene 78 72 77 81 76 75 79 9 4,6-Dinitro-2-methylphenol 97 103 100 100 106 109 100 13 2,4-Dinitrophenol 93 92 88 88 92 90 91 6 2,4-Dinitrotoluene 82 80 80 77 86 80 80 9 2,6-Dinitrotoluene 101 106 106 107 106 98 104 10 Dinoseb 118 129 121 122 120 117 119 12 Diphenylamine 118 112 119 116 122 115 115 10 Disulfoton 132 137 136 134 129 130 132 10 Ethylmethanesulfonate 106 114 107 106 100 102 107 13 Famphur 207 161 190 154 209 216 212 80 Fluoranthene 138 141 137 143 139 135 132 11 Fluorene 149 116 136 149 148 147 144 38 Hexachlorobenzene 142 147 141 145 140 138 134 13 Appendix D - 1

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.2 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Hexachlorobutadiene 148 147 156 144 150 147 141 15 Hexachlorocyclopentadiene 53 50 60 52 60 57 65 17 Hexachloroethane 89 104 93 86 90 93 87 19 Hexachlorophene 0 0 0 0 0 0 0 ND Hexachloropropene 139 140 138 136 139 143 136 8 Indeno(1,2,3-c,d)pyrene 102 106 100 97 107 109 103 14 Isodrin 155 160 163 152 155 153 151 13 Isophorone 138 158 135 139 135 132 142 28 Isosafrole 141 136 132 129 137 138 138 13 Kepone 50 59 36 33 10 26 24 51 Methapyrilene 120 127 120 121 119 115 114 13 Methyl parathion 158 159 150 155 152 153 158 11 3-Methylcholanthrene 109 110 112 105 113 113 114 10 Methylmethanesulfonate 166 180 171 171 166 158 161 23 2-Methylnaphthalene 276 284 281 268 278 271 289 22 2-Methylphenol 70 79 73 73 77 75 73 9 4-Methylphenol 88 94 84 83 90 91 89 12 Naphthalene 199 197 197 196 198 206 194 12 1,4-Naphthoquinone 0 0 0 0 0 0 0 ND 1-Naphthylamine 79 81 80 79 78 78 76 5 2-Naphthylamine 97 95 96 95 94 98 97 5 2-Nitroaniline 73 74 72 72 76 77 77 7 3-Nitroaniline 68 69 67 69 68 64 66 5 4-Nitroaniline 100 91 96 101 105 102 99 14 Nitrobenzene 83 76 80 82 84 81 82 8 2-Nitrophenol 96 107 102 94 96 96 98 15 4-Nitrophenol 59 67 64 59 60 61 58 10 4-Nitroquinoline-1-oxide 24 22 25 24 28 26 25 6 N-Nitroso-di-n-butylamine 0 0 0 0 0 0 0 ND N-Nitrosodiethylamine 123 128 121 116 117 112 114 17 N-Nitrosodiphenylamine 94 90 95 99 98 97 92 10 N-Nitrosodi-n-propylamine 79 73 83 83 74 83 82 14 N-Nitrosomethylethylamine 146 157 145 145 139 133 133 26 N-Nitrosomorpholine 55 56 54 56 58 55 56 4 N-Nitrosopiperidine 130 109 130 122 136 134 123 29 N-Nitrosopyrrolidine 73 73 79 77 71 69 72 11 5-Nitro-o-toluidine 94 91 96 93 97 96 98 8 Di-n-octylphthalate 115 101 102 133 99 94 97 43 Parathion 156 163 151 161 149 148 155 17 Pentachlorobenzene 114 101 107 106 116 109 95 23 Pentachloronitrobenzene 103 110 107 113 108 106 110 10 Pentachlorophenol 122 132 122 129 118 121 122 15 Phenacetin 157 163 151 156 152 152 154 13 Phenanthrene 102 98 109 104 102 108 108 13 Phenol 91 96 97 91 89 88 88 12 p-Phenylenediamine 0 0 0 0 0 0 0 ND Phorate 84 86 86 86 84 83 82 5 2-Picoline 174 187 189 172 176 172 170 24 Pronamide 105 104 108 112 106 104 105 9 Pyrene 127 120 123 133 129 131 122 15 Pyridine 108 82 101 105 99 97 84 32 Safrole 72 85 75 70 72 76 78 15 Sulfotep 162 165 158 166 158 156 161 12 1,2,4,5-Tetrachlorobenzene 108 98 98 99 110 104 91 21 2,3,4,6-Tetrachlorophenol 114 109 112 115 114 108 104 12 Thionzin 96 94 95 97 82 89 98 18 o-Toluidine 106 111 104 112 109 109 102 11 1,2,4-Trichlorobenzene 114 109 116 108 119 117 112 13 2,4,5-Trichlorophenol 104 104 92 95 108 105 100 18 2,4,6-Trichlorophenol 98 100 100 100 100 95 99 6 Appendix D - 2

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.2 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL O,O,O-Triethylphosphorothioate 145 116 146 144 148 147 142 35 1,3,5-Trinitrobenzene 101 103 104 103 100 102 113 14

Comments: 1) All values in ug/Kg 2) Spiked amount = 100ug/Kg 3) ND = Not detected 4) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses

Appendix D - 3

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.2 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Acenaphthene 149 134 143 143 137 145 147 17 Acenaphthylene 131 125 131 126 134 129 125 11 Acetophenone 68 78 68 64 71 65 64 15 2-Acetylaminofluorene 114 108 109 111 115 111 113 8 4-Aminobiphenyl 117 119 111 119 117 117 121 10 Aniline 102 113 111 100 104 104 99 17 Anthracene 101 106 103 108 108 100 100 11 Aramite 114 108 110 120 117 115 114 13 Benzidine 94 97 97 92 98 98 97 7 Benzo[a]anthracene 111 107 108 111 112 112 112 7 Benzo[a]pyrene 102 103 103 102 103 102 102 2 Benzo[b]fluoranthene 111 98 105 108 105 106 101 13 Benzo[g,h,i]perylene 132 140 133 125 140 141 141 19 Benzo[k]fluoranthene 91 102 103 91 91 87 96 19 Benzyl Alcohol 94 98 99 93 87 88 88 16 Bis(2-chloroethoxy)methane 110 87 109 112 112 113 105 29 Bis(2-chloroethyl)ether 91 101 96 93 85 94 96 16 Bis(2-chloroisopropyl)ether 62 66 69 65 64 64 64 7 Bis(2-ethylhexyl)phthalate 110 106 105 120 107 110 108 16 4-Bromophenyl phenyl ether 120 118 122 123 118 115 120 8 Butyl benzyl phthalate 111 102 105 116 108 109 106 14 Di-n-butylphthalate 131 132 134 132 128 131 126 8 4-Chloroaniline 119 111 114 115 113 117 114 9 Chlorobenzilate 119 112 116 124 116 118 114 12 4-Chloro-3-methylphenol 71 64 75 68 71 66 71 12 2-Chloronaphthalene 127 131 129 135 127 127 128 10 2-Chlorophenol 66 71 69 67 68 70 67 6 4-Chlorophenyl phenyl ether 110 100 111 107 110 106 99 15 Chrysene 115 111 113 115 115 115 114 5 Diallate 108 109 113 111 107 119 111 12 Dibenz[a,j]acridine 110 115 109 103 114 113 116 15 Dibenzo[a,h]anthracene 108 115 113 107 119 119 117 16 Dibenzofuran 121 108 114 117 116 129 111 22 1,2-Dichlorobenzene 101 108 107 102 100 99 98 13 1,3-Dichlorobenzene 82 118 106 95 103 104 102 35 1,4-Dichlorobenzene 114 92 101 98 73 86 87 40 3,3'-Dichlorobenzidine 105 100 101 102 103 104 107 8 2,4-Dichlorophenol 105 103 108 110 105 114 110 11 2,6-Dichlorophenol 103 98 109 102 107 100 103 12 Diethyl phthalate 80 76 81 80 77 83 82 8 Dimethoate 102 107 106 105 108 102 110 9 p-Dimethylaminoazobenzene 127 117 120 134 126 126 123 17 7,12-Dimethylbenz[a]anthracene 98 94 101 104 97 95 97 11 3-3'-Dimethylbenzidine 115 113 113 107 112 112 108 8 a,a-Dimethylphenethylamine 0 0 0 0 0 0 0 ND 2,4-Dimethylphenol 117 102 111 114 117 121 117 20 Dimethyl phthalate 88 87 86 86 88 90 88 5 m-Dinitrobenzene 78 72 77 81 76 75 79 9 4,6-Dinitro-2-methylphenol 97 103 100 100 106 109 100 13 2,4-Dinitrophenol 93 92 88 88 92 90 91 6 2,4-Dinitrotoluene 82 80 80 77 86 80 80 9 2,6-Dinitrotoluene 101 106 106 107 106 98 104 10 Dinoseb 118 129 121 122 120 117 119 12 Diphenylamine 118 112 119 116 122 115 115 10 Disulfoton 132 137 136 134 129 130 132 10 Ethylmethanesulfonate 106 114 107 106 100 102 107 13 Famphur 207 161 190 154 209 216 212 80 Fluoranthene 138 141 137 143 139 135 132 11 Fluorene 149 116 136 149 148 147 144 38 Hexachlorobenzene 142 147 141 145 140 138 134 13 Appendix D - 1

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.2 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Hexachlorobutadiene 148 147 156 144 150 147 141 15 Hexachlorocyclopentadiene 53 50 60 52 60 57 65 17 Hexachloroethane 89 104 93 86 90 93 87 19 Hexachlorophene 0 0 0 0 0 0 0 ND Hexachloropropene 139 140 138 136 139 143 136 8 Indeno(1,2,3-c,d)pyrene 102 106 100 97 107 109 103 14 Isodrin 155 160 163 152 155 153 151 13 Isophorone 138 158 135 139 135 132 142 28 Isosafrole 141 136 132 129 137 138 138 13 Kepone 50 59 36 33 10 26 24 51 Methapyrilene 120 127 120 121 119 115 114 13 Methyl parathion 158 159 150 155 152 153 158 11 3-Methylcholanthrene 109 110 112 105 113 113 114 10 Methylmethanesulfonate 166 180 171 171 166 158 161 23 2-Methylnaphthalene 276 284 281 268 278 271 289 22 2-Methylphenol 70 79 73 73 77 75 73 9 4-Methylphenol 88 94 84 83 90 91 89 12 Naphthalene 199 197 197 196 198 206 194 12 1,4-Naphthoquinone 0 0 0 0 0 0 0 ND 1-Naphthylamine 79 81 80 79 78 78 76 5 2-Naphthylamine 97 95 96 95 94 98 97 5 2-Nitroaniline 73 74 72 72 76 77 77 7 3-Nitroaniline 68 69 67 69 68 64 66 5 4-Nitroaniline 100 91 96 101 105 102 99 14 Nitrobenzene 83 76 80 82 84 81 82 8 2-Nitrophenol 96 107 102 94 96 96 98 15 4-Nitrophenol 59 67 64 59 60 61 58 10 4-Nitroquinoline-1-oxide 24 22 25 24 28 26 25 6 N-Nitroso-di-n-butylamine 0 0 0 0 0 0 0 ND N-Nitrosodiethylamine 123 128 121 116 117 112 114 17 N-Nitrosodiphenylamine 94 90 95 99 98 97 92 10 N-Nitrosodi-n-propylamine 79 73 83 83 74 83 82 14 N-Nitrosomethylethylamine 146 157 145 145 139 133 133 26 N-Nitrosomorpholine 55 56 54 56 58 55 56 4 N-Nitrosopiperidine 130 109 130 122 136 134 123 29 N-Nitrosopyrrolidine 73 73 79 77 71 69 72 11 5-Nitro-o-toluidine 94 91 96 93 97 96 98 8 Di-n-octylphthalate 115 101 102 133 99 94 97 43 Parathion 156 163 151 161 149 148 155 17 Pentachlorobenzene 114 101 107 106 116 109 95 23 Pentachloronitrobenzene 103 110 107 113 108 106 110 10 Pentachlorophenol 122 132 122 129 118 121 122 15 Phenacetin 157 163 151 156 152 152 154 13 Phenanthrene 102 98 109 104 102 108 108 13 Phenol 91 96 97 91 89 88 88 12 p-Phenylenediamine 0 0 0 0 0 0 0 ND Phorate 84 86 86 86 84 83 82 5 2-Picoline 174 187 189 172 176 172 170 24 Pronamide 105 104 108 112 106 104 105 9 Pyrene 127 120 123 133 129 131 122 15 Pyridine 108 82 101 105 99 97 84 32 Safrole 72 85 75 70 72 76 78 15 Sulfotep 162 165 158 166 158 156 161 12 1,2,4,5-Tetrachlorobenzene 108 98 98 99 110 104 91 21 2,3,4,6-Tetrachlorophenol 114 109 112 115 114 108 104 12 Thionzin 96 94 95 97 82 89 98 18 o-Toluidine 106 111 104 112 109 109 102 11 1,2,4-Trichlorobenzene 114 109 116 108 119 117 112 13 2,4,5-Trichlorophenol 104 104 92 95 108 105 100 18 2,4,6-Trichlorophenol 98 100 100 100 100 95 99 6 Appendix D - 2

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.2 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL O,O,O-Triethylphosphorothioate 145 116 146 144 148 147 142 35 1,3,5-Trinitrobenzene 101 103 104 103 100 102 113 14

Comments: 1) All values in ug/Kg 2) Spiked amount = 100ug/Kg 3) ND = Not detected 4) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses

Appendix D - 3

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.6 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Acenaphthene 105 105 120 115 116 120 121 22 Acenaphthylene 112 110 116 119 116 121 124 16 Acetophenone 94 97 116 117 119 117 117 34 2-Acetylaminofluorene 116 113 122 120 107 104 104 24 4-Aminobiphenyl 104 108 106 118 80 81 74 53 Aniline 110 113 134 134 133 132 132 33 Anthracene 100 86 100 90 94 97 88 17 Aramite 123 125 151 141 144 131 140 32 Benzidine 94 98 113 107 104 96 108 22 Benzo[a]anthracene 169 179 205 189 181 189 203 40 Benzo[a]pyrene 170 161 210 122 175 200 178 90 Benzo[b]fluoranthene 138 135 150 166 168 156 153 40 Benzo[g,h,i]perylene 101 101 177 158 169 172 148 102 Benzo[k]fluoranthene 64 87 119 101 75 108 105 61 Benzyl Alcohol 98 96 115 112 114 112 112 25 Bis(2-chloroethoxy)methane 96 97 105 104 100 101 102 11 Bis(2-chloroethyl)ether 87 97 95 95 99 104 104 18 Bis(2-chloroisopropyl)ether 88 90 108 105 107 106 106 26 Bis(2-ethylhexyl)phthalate 135 134 146 145 138 131 150 23 4-Bromophenyl phenyl ether 108 108 115 116 110 109 110 10 Butyl benzyl phthalate 134 128 164 161 138 145 165 48 Di-n-butylphthalate 113 115 118 118 115 114 116 7 4-Chloroaniline 84 77 92 94 96 97 96 23 Chlorobenzilate 147 136 185 160 156 163 179 53 4-Chloro-3-methylphenol 101 104 111 112 113 112 108 15 2-Chloronaphthalene 92 103 122 133 109 132 140 56 2-Chlorophenol 88 90 100 100 100 100 100 16 4-Chlorophenyl phenyl ether 107 107 117 115 113 118 119 15 Chrysene 314 374 436 322 292 309 339 156 Diallate 67 73 80 74 79 76 74 14 Dibenz[a,j]acridine 91 84 148 126 134 93 103 77 Dibenzo[a,h]anthracene 111 102 142 131 136 137 111 50 Dibenzofuran 101 100 110 105 106 109 98 14 1,2-Dichlorobenzene 92 94 103 103 104 103 103 16 1,3-Dichlorobenzene 102 107 113 110 109 107 120 18 1,4-Dichlorobenzene 86 86 98 103 102 104 92 25 3,3'-Dichlorobenzidine 96 109 106 118 94 95 98 28 2,4-Dichlorophenol 109 111 128 127 124 129 129 26 2,6-Dichlorophenol 101 103 110 112 111 113 112 15 Diethyl phthalate 113 113 132 127 121 130 129 24 Dimethoate 52 36 63 61 63 54 60 30 p-Dimethylaminoazobenzene 58 60 114 78 53 55 52 71 7,12-Dimethylbenz[a]anthracene 75 64 75 73 79 69 63 19 3-3'-Dimethylbenzidine 104 101 123 113 92 96 98 34 a,a-Dimethylphenethylamine 71 71 66 73 67 66 66 9 2,4-Dimethylphenol 111 114 140 136 137 137 144 41 Dimethyl phthalate 111 111 122 115 116 119 120 13 m-Dinitrobenzene 0 0 0 0 0 0 0 ND 4,6-Dinitro-2-methylphenol 0 0 0 0 0 0 0 ND 2,4-Dinitrophenol 63 58 85 79 81 71 68 31 2,4-Dinitrotoluene 0 0 0 0 0 0 0 0 2,6-Dinitrotoluene 81 81 81 72 92 122 91 51 Dinoseb 84 53 106 76 87 84 68 52 Diphenylamine 108 103 124 114 110 114 116 21 Disulfoton 103 100 128 122 115 116 118 31 Ethylmethanesulfonate 107 109 121 124 116 119 116 19 Famphur 0 0 0 0 0 0 0 ND Fluoranthene 109 104 91 86 86 94 82 31 Fluorene 111 110 119 116 116 126 124 19 Hexachlorobenzene 94 110 104 93 99 103 93 21 Appendix D - 1

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.6 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Hexachlorobutadiene 108 109 118 117 116 118 118 14 Hexachlorocyclopentadiene 35 29 53 45 38 38 41 24 Hexachloroethane 75 70 86 88 90 85 84 24 Hexachlorophene 0 0 0 0 0 0 0 ND Hexachloropropene 85 85 106 106 102 102 104 30 Indeno(1,2,3-c,d)pyrene 90 86 151 162 147 144 147 97 Isodrin 147 139 101 111 151 106 112 66 Isophorone 109 109 131 133 126 130 130 33 Isosafrole 111 112 120 121 120 127 127 20 Kepone 0 0 0 0 0 0 0 ND Methapyrilene 80 73 92 97 89 83 91 26 Methyl parathion 56 50 65 67 69 57 64 21 3-Methylcholanthrene 122 119 137 125 123 132 108 29 Methylmethanesulfonate 155 154 200 191 190 189 192 60 2-Methylnaphthalene 145 152 158 155 155 155 160 15 2-Methylphenol 96 98 116 114 115 115 115 28 4-Methylphenol 120 118 89 91 92 90 90 44 Naphthalene 115 115 123 132 130 131 132 25 1,4-Naphthoquinone 0 0 0 0 0 0 0 ND 1-Naphthylamine 76 75 84 57 82 62 57 37 2-Naphthylamine 61 54 63 55 65 65 65 14 2-Nitroaniline 95 101 124 118 106 116 120 34 3-Nitroaniline 75 73 116 110 81 97 88 53 4-Nitroaniline 81 78 86 78 84 87 82 11 Nitrobenzene 104 96 114 104 105 101 102 17 2-Nitrophenol 105 113 126 125 126 124 127 27 4-Nitrophenol 79 75 116 102 111 121 113 58 4-Nitroquinoline-1-oxide 0 0 0 0 0 0 0 ND N-Nitroso-di-n-butylamine 118 108 129 123 134 124 125 26 N-Nitrosodiethylamine 102 102 121 117 115 116 116 24 N-Nitrosodiphenylamine 103 103 123 126 120 122 120 30 N-Nitrosodi-n-propylamine 91 94 87 121 121 112 126 51 N-Nitrosomethylethylamine 138 137 115 112 107 111 111 41 N-Nitrosomorpholine 41 41 41 45 47 41 40 8 N-Nitrosopiperidine 108 108 137 135 134 135 138 43 N-Nitrosopyrrolidine 91 96 116 162 105 105 108 75 5-Nitro-o-toluidine 98 102 101 95 102 107 104 12 Di-n-octylphthalate 113 107 119 116 109 108 106 16 Parathion 110 95 124 128 100 94 93 46 Pentachlorobenzene 111 111 117 112 110 118 115 11 Pentachloronitrobenzene 16 29 27 31 25 24 79 66 Pentachlorophenol 122 118 134 127 122 115 111 24 Phenacetin 103 100 106 94 104 104 99 13 Phenanthrene 165 152 170 166 164 173 169 22 Phenol 93 94 106 105 106 107 106 19 p-Phenylenediamine 0 0 0 0 0 0 0 ND Phorate 71 71 104 107 67 73 106 59 2-Picoline 149 149 177 173 170 168 170 35 Pronamide 84 74 97 81 84 86 81 22 Pyrene 252 229 311 282 255 266 294 87 Pyridine 38 43 44 43 43 45 48 9 Safrole 80 82 143 85 97 87 100 69 Sulfotep 121 123 139 136 129 127 133 21 1,2,4,5-Tetrachlorobenzene 102 102 114 107 106 112 115 18 2,3,4,6-Tetrachlorophenol 90 74 94 82 89 96 87 23 Thionzin 105 87 120 107 104 117 108 34 o-Toluidine 81 81 90 91 94 92 92 17 1,2,4-Trichlorobenzene 100 101 107 107 106 108 108 10 2,4,5-Trichlorophenol 135 142 160 144 130 151 155 34 2,4,6-Trichlorophenol 78 73 91 89 87 98 104 34 Appendix D - 2

# METHOD DETECTION LIMIT STUDY RESULTS BY GCMS 8270 - SVOC

Fuel = No.6 Compound Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL O,O,O-Triethylphosphorothioate 116 116 124 124 122 123 125 12 1,3,5-Trinitrobenzene 0 0 0 0 0 0 0 ND

Comments: 1) All values in ug/Kg 2) Spiked amount = 100ug/Kg 3) ND = Not detected 4) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses

Appendix D - 3

# Results for Method Detection Limit Study - Metals



# Metal Rep.#1 Rep.#2 Rep.#3 Rep.#4 Rep.#5 Rep.#6 Rep.#7 MDL Units True Value Antimony 0.57 0.47 0.62 0.38 0.50 0.34 0.23 0.43 mg/L 0.5 Arsenic 9.81 8.58 8.47 9.51 6.63 7.07 9.95 4.13 ug/L 10 Barium 1.02 1.07 0.91 0.82 0.96 0.80 0.71 0.53 mg/L 1 Beryllium 0.109 0.109 0.109 0.110 0.110 0.111 0.110 0.002 mg/L 0.1 Cadmium 0.112 0.108 0.121 0.117 0.117 0.116 0.121 0.015 mg/L 0.1 Chromium 0.415 0.447 0.450 0.472 0.440 0.428 0.471 0.066 mg/L 0.5 Cobalt 0.284 0.282 0.264 0.283 0.296 0.270 0.288 0.034 mg/L 0.2 Lead 0.780 0.787 0.810 0.802 0.821 0.843 0.852 0.085 mg/L 1 Manganese 0.041 0.044 0.041 0.042 0.042 0.040 0.042 0.0039 mg/L 0.05 Nickel 0.217 0.216 0.222 0.218 0.220 0.217 0.222 0.008 mg/L 0.2 Selenium 13.50 11.39 13.61 14.24 13.06 10.52 13.13 4.17 ug/L 10 Silver 0.175 0.178 0.180 0.179 0.171 0.167 0.163 0.020 mg/L 0.2 Thallium 0.77 0.77 0.65 0.74 0.67 0.66 0.60 0.21 mg/L 1

Comments: 1) Since the procedure used for these metals was 3040 Dissolution in Xylene, the above MDL was performed in xylene as the common matrix.
2) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses

Appendix D - 1

## RESULTS FOR METHOD DETECTION LIMIT STUDY - MERCURY



## Fuel = Gasoline Metal Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

## Mercury 0.03 0.02 0.02 0.02 0.02 0.02 0.02 0.012



## Fuel = No.2 Metal Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

## Mercury 0.03 0.04 0.04 0.04 0.04 0.05 0.04 0.018



## Fuel = No.6 Metal Rep.1 Rep.2 Rep.3 Rep.4 Rep.5 Rep.6 Rep.7 MDL 

## Mercury 0.04 0.03 0.03 0.03 0.04 0.03 0.04 0.017

Comments: 

### 1) Units = ug Total 2) True Value of Spike = 0.100 ug 3) MDL = t x sd Where t is the student-t statistic for the 99% confidence limit for n-1 degrees of freedom and sd is the standard deviation in the seven replicate analyses



## Appendix D - 1

# Appendix E

Quality Assurance Results

# E - 1

Appendix E SURROGATE RECOVERY DATA - SEMI-VOLATILE Sample ID 2-Fluorophenol Phenol-d 6 

## Nitrobenzene-d 5 

## 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d 14 

## 2011 14.2 50.6 63.8 86 29.4 73 2012 24.4 79.8 64 80.2 35.2 72.2 2013 D D D D D D 2014 D D D D D D 2015 9.1 48.2 45 77 63.4 77.1 2016 13.9 74.5 48 78.8 66 74.1 2017 16.8 48.8 56.6 90.2 27.4 92.4 2018 22.6 92.6 65.6 94.2 51.8 88.4 2019 93.7 76.3 134 118 103 103 2020 114 96.5 150 123 110 113 2021 106 102 154 114 138 107 2022 100 121 128 125 109 113 2023 114 102 134 108 148 111 2024 100 101 145 94.5 86.2 101 2025 106 83.8 112 117 98.6 112 2026 119 107 165 102 108 103 2027 101 90.5 114 109 127 103 2028 113 101 141 96.4 113 107 2029 104 108 109 111 114 105 2030 84.3 89.6 98.9 99.6 93.4 110 2031 88.5 89.8 99.6 103 94.3 109 2032 101 100 96.1 101 100 120 2033 99.4 75.5 27.7 94.8 79.3 100 2034 125 113 60.9 91.7 131 116 2230 75.4 72.8 78.9 87.4 62.1 87.1 2231 88.8 77.1 92.3 104 92.8 111 2232 112 106 76.3 93.2 90.9 94.7 D = Surrogate Diluted Out. Sample diluted due to high concentration of target compounds.

# E - 2

Appendix E SURROGATE RECOVERY DATA - VOLATILE

Sample ID 1,2-Dichloroethane-d 4 

## Toluene-d 8 

## Bromofluorobenzene
2011 95 114 90 2012 95 115 91 2013 100 105 98 2014 100 111 92 2015 100 111 92 2016 103 95 102 2017 106 100 106 2018 106 97 102 2019 94 101 95 2020 94 102 95 2021 108 101 108 2022 101 97 99 2023 112 95 108 2024 110 96 104 2025 104 101 103 2026 106 95 105 2027 101 103 101 2028 125 79 110 2029 88 93 86 2030 95 101 94 2031 96 97 94 2032 91 101 90 2033 97 102 98 2034 93 95 91 2230 108 96 112 2231 102 105 102 2232 101 106 99

# E - 3

Appendix E QC SUMMARY - METALS

Sample ID Metal Analysis Spiked Sample % Recovery Initial Duplicate 2018 2028 2029 2034 Cobalt

Cobalt Cobalt Cobalt BQL

0.49 BQL BQL BQL

0.58 BQL BQL 97

106 105 101 2018 2028 2029 2034 Beryllium

Beryllium Beryllium Beryllium BQL BQL BQL BQL BQL

BQL BQL BQL 81.2

100 102 104 2018 2028 2029 2034 Silver

Silver Silver Silver BQL

BQL BQL BQL BQL

BQL BQL BQL 110

132 135 126 2018 2028 2029 2034 Cadmium

Cadmium Cadmium Cadmium BQL BQL BQL BQL BQL

BQL BQL BQL 102

107 110 106 2018 2028 2029 2034 Manganese

Manganese Manganese Manganese BQL BQL BQL BQL BQL

BQL BQL BQL 99.2

99.8 102 98.8 2018 2028 2029 2034 Selenium

Selenium Selenium Selenium BQL BQL 11 BQL BQL

BQL 17 BQL 94.4

116 76.3 85.7 2018 2028 2029 2034 Arsenic

Arsenic Arsenic Arsenic BQL

BQL BQL BQL BQL

BQL BQL BQL 76.3

102 70.2 96.9 2018 2028 2029 2034 Nickel

Nickel Nickel Nickel BQL

BQL 1.39 0.30 BQL

BQL 1.39 0.28 104

95.9 116 96.9 2018 2028 2029 2034 Lead

Lead Lead Lead BQL

0.65 0.84 2.8 BQL

0.67 0.85 2.7 120

93 100 84

# E - 4

Appendix E QC SUMMARY - METALS (continued)

Sample ID Metal Analysis Spiked Sample % Recovery Initial Duplicate 2018 2028 2029 2034 Antimony

Antimony Antimony Antimony BQL BQL BQL 0.78 BQL

BQL BQL 1.10 96

92 92 109 2018 2028 2029 2034 Chromium

Chromium Chromium Chromium BQL BQL BQL BQL BQL

BQL BQL BQL 120

104 107 97 2018 2028 2029 2034 Thallium

Thallium Thallium Thallium BQL BQL BQL BQL BQL

BQL BQL BQL 128

126 128 124 2018 2028 2029 2034 Barium

Barium Barium Barium BQL

BQL BQL BQL BQL

BQL BQL BQL 85

80 75 72 2018 2028 2029 2034 Mercury

Mercury Mercury Mercury BQL BQL BQL BQL BQL

BQL BQL BQL 47

45 36 38
Units in mg/L BQL = Below Quantitative Limit

# Appendix F

Constituents Not in Final Rule

# F - 1

Appendix F Table 1: Constituents Not in Final Rule
The following is a list of constituents for which EPA proposed specifications, but will not be including in the final rule. Listed next to the constituent is the reason why it does not appear in the final rule.

Chemical Name Reason why not in final rule 1,2-Dichloroethylene (cis- or trans-) covered by isomers 1,4-Dichloro-2-butene (cis- or trans-) covered by isomers Fluorene not on Appendix VIII 1,1,2-Trichloro-1,2,2-trifluoroethane not on Appendix VIII 1,1-Dichloro-1-propene not on Appendix VIII 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin not on Appendix VIII 1,2,3,4,6,7,8-Heptachlorodibenzo-p-furan not on Appendix VIII 1,2,3,4-Tetrachlorobenzene not on Appendix VIII 1,2,3,5-Tetrachlorobenzene not on Appendix VIII 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin not on Appendix VIII 1,2,3,6,7,8-Hexachlorodibenzo-p-furan not on Appendix VIII 1,2,3,7,8-Pentachlorodibenzo-p-dioxin not on Appendix VIII 1,2,3,7,8-Pentachlorodibenzo-p-furan not on Appendix VIII 1,2,3-Trichlorobenzene not on Appendix VIII 1,3-Dichloropropane not on Appendix VIII 1-Chloronaphthalene not on Appendix VIII 2,2-Dichloropropane not on Appendix VIII 2,3,4,5-Tetrachlorophenol not on Appendix VIII 2,3,4-Trichlorophenol not on Appendix VIII 2,3,5-Trichlorophenol not on Appendix VIII 2,3,6-Trichlorophenol not on Appendix VIII 2,3,7,8-Tetrachlorodibenzo-p-furan not on Appendix VIII 2,3-Dichloro-1-propene not on Appendix VIII 2,3-Dichlorophenol not on Appendix VIII 2,5-Dichlorophenol not on Appendix VIII 2-Methylnaphthalene not on Appendix VIII 3,4-Dichlorophenol not on Appendix VIII 3,5-Dichlorophenol not on Appendix VIII 3-/4-Chlorophenol not on Appendix VIII 3-Nitroaniline not on Appendix VIII 4-Chlorophenyl phenyl ether not on Appendix VIII Acenaphthene not on Appendix VIII Ammonium vanadate covered by metals Anthracene not on Appendix VIII Arochlor-1016 covered by total PCBs Arochlor-1221 covered by total PCBs Arochlor-1232 covered by total PCBs

## Chemical Name Reason why not in final rule



# F - 2 Arochlor-1242 covered by total PCBs Arochlor-1248 covered by total PCBs Arochlor-1254 covered by total PCBs Arochlor-1260 covered by total PCBs Arsenic acid covered by metals Arsenic pentoxide covered by metals Arsenic trioxide covered by metals Barium Cyanide covered by metals Bromide not on Appendix VIII Bromodichloromethane not on Appendix VIII Calcium Cyanide covered by total cyanide Calcium chromate covered by metals Chloride not on Appendix VIII Chloroethane not on Appendix VIII Copper Cyanide covered by total cyanide Cyanogen Bromide covered by total cyanide Cyanogen Chloride covered by total cyanide Di-selenium-tetra-sulfide covered by metals Dibenzofuran not on Appendix VIII Dibromochloromethane not on Appendix VIII Fluoride not on Appendix VIII Lead acetate covered by metals Lead phosphate covered by metals Nickel Cyanide covered by total cyanide Nickel carbonyl covered by metals Octachlorodibenzodioxin not on Appendix VIII Octachlorodibenzofuran not on Appendix VIII Osmium tetraoxide covered by metals Phenanthrene not on Appendix VIII Potassium Cyanide covered by total cyanide Potassium Silver Cyanide covered by total cyanide Pyrene not on Appendix VIII Selenium dioxide covered by metals Selenium sulfide covered by metals Silver Cyanide covered by total cyanide Tetra-selenium-tetra-sulfide covered by metals Tetraethyl lead covered by metals Thallium acetate covered by metals Thallium carbonate covered by metals Thallium chloride covered by metals Thallium nitrate covered by metals Thallium oxide covered by metals

## Chemical Name Reason why not in final rule



# F - 3 Thallium sulfate covered by metals Vanadium pentoxide covered by metals Zinc Cyanide covered by metals Zinc phosphide covered by metals alpha-BHC not on Appendix VIII beta-BHC not on Appendix VIII delta-BHC not on Appendix VIII