p. 1



# OAR Box 1413 Prepped by Ollie Stewart



## Document

Number: 

# 32 ) 11-1-3 2 Docket Number: 

# A-94-5 2

Printed 7/9/2008 3:11:21 PM

Sheet 32 of 114—."•"

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# J 

# RECEIVE D JU N 2 2 199

4 W VO F ENVIRONMENTA L QUAUTY PERMIT S 4 ENFORCEMEN T 

## A-04-5 2

EMISSION S COMPLIANCE TEST S STYRENE AND VISIBLE EMISSION S Fiberglas s Reinforce d Plasti cLay-up Facilit y Idah o Permi t

T o Construc t

860-003 5 GEA/Thermal-Dynami c Towers Inc . 12600 W
. Colfa

x Ave. , Ste
. C50 0 Lakewood , C O 8021 5 dba : Dynami c Fabricator s 173 5 W
. Highwa

y 5 3 Rathdrum , Idaho 8383 5 (208 ) 773-178 7 August 26, 1993

By Biso nEngineering , Inc
. P.O
. Box 170

3 3 0 S
. Ewing Helena , M T5960 1 (406 ) 442-576 8 Repor t Date : Octobe

r 1 , 199 3P. 3



# TABLE OF CONTENTS

EXECUTIV E SUMMAR Yii i CERTIFICATIO N O F REPORTINTEGRIT Yi v 1. 0 INTRODUCTIO N 1 1. 1 Purpos e 1 1. 2 Emissio n Sourc e Descriptio n 1 1. 3 Contro l Equipmen t Descriptio n 2 1. 4 Sourc e Tes t Date s 2 1. 5 Pollutant s Teste d 2 1. 6 Personne l 2 1.6. 1 Biso n Engineering , In c2 1.6. 2 Dynami cFabricator s 3 2. 0 TES TRESULT S SUMMAR Y4 2. 1 Emissio n Result s 4 2. 2 Proces s Dat a 4 3. 0 SAMPLIN G AN D ANALYSI S 5 3. 1 Sampl e Locatio n 5 3. 2 Samplin g Procedure s 5 3. 3 Fiel d Note s an d Specia l Circumstance s 5 3. 4 Dat a Reductio n an d Calculation s 6 4. 0 QUALIT YASSURANC E 7 

# APPENDICES A B C D E F Pretes t Protocol/Permi t t o Construc t #860-003 5 Fiel d Data/Calculation s Operatin g Data/Ra wMateria l Usage s Laborator yDat a wit h Chai n o fCustod yFor m Nomenclature , Formula e an d La b Method s Calibratio n Dat a



## £ ~P. 4



# EXECUTIV

E SUMMAR

Y
Biso n Engineering , Inc

. (Bison ) performe d Titl e 40,Cod e o fFedera l Regulation s (CFR) , Par t 60 , Appendi xA , Metho d 1 , "Sampl e an d Velocit yTraverse s fo rStationary Sources" , Metho d 2 , "Determinatio n o fStac k Ga s Velocit yan d Volumetri cFlo wRat e (Typ e S Pito t Tube)" , Metho d 3 , "Ga s Analysi s fo rCarbo n Dioxide , Oxygen , Exces s Ai ran d Dr

yMolecula rWeight" , Metho d 9 , "Visua l Determinatio n o fth e Opacit yo f Emission s fro m StationarySources"

. Biso n als o determine d stac k moistur e conten t usin g wet/dr ybul b temperature s alon g wit h a psychrometri cchar t an d teste d fo r fugitiv e styren e emission s i n th e stacks a t th e facilit ynea rRathdrum , Idaho

. Permi t t o Construc t 860-003 5 require s complianc e testin g fo rcombine d fugitiv e styren e an d visua l emission s i n tw o stacks i n accordanc e wit h th e abov e methods

. Th e combine d stac k

limi t fo rstyren e emission s i s 8. 1 pound s pre hou r(lb/hr ) an d opacit yca n no t excee d 20 % durin g an y3-minut e period

. Thi s report present s detaile d procedures , fiel d data , tes t results , an d conclusions

. Th e followin g tabl e summarize s th e results : 

## Table1 Summar y of TestResults

Nort h 1 Styren e (Ib/hr

) Eas t 2 Styren e (Ib/hr

) Combine d Styren e (Ib/hr

) Opacity , % Ru n 1 10.00 6 6.68 0 16.68 6 0 Ru n 2

7.07 3 8.73 1 15.80 4 0 Ru n 3

10.30 4 9.51 7 19.82 1 0 Averag e

9.12 7 8.30 9 17.43 6 C^ 0 

### Althoug h th e methodolog yuse d fo rthi s testin g i s no t new , th e applicatio n i s an d i s perhap s th e firs t tim e i t has bee n used i n th e State

. Th e result s appea rt o be significantl y.highe rtha n thos e thatcoul d b e predicte d b yusin g AP4 2 calculations

. Althoug h th e testin g wa s don e i n stric t adherenc e t o th e approve d Protocol , i t i s possibl e tha t futur e sampling/testin g procedure s nee d t o be re-evaluated

.

i nP. 5



# CERTIFICATIO

N OF REPOR

T INTEGRIT

Y

Biso n Engineering , Inc . certifie s thi s report represent s th e emission s teste d o n Augus t 26 , 1993 . Everyeffor t wa s mad e t o obtai n accurat e an d representativ e dat a accordin g t o emissio n testin g requirement s ofIdah o Permi t t o Construc t 860-0035 . Th e tes t tea m complie d wit h th e procedure s specifie d i n Titl e 40 , Cod e ofFedera l Regulation s (CFR) , Part 60 , Appendi xA , Method s 1 throug h 3 , an d Metho d 9 . (Method s revise d throug h Jul y1 , 1992 , correcte d a t 5 7 F R 2455 0 [Jun e 10 , 1992)) . Moistur e conten t o fth e stac k wa s determine d usin g wet/dr ybul b temperature s an d psychrometri c charts . Th e styren e samplin g apparatu s generall yconforme d t o Metho d 6 , 4 0 CF R 60 , Appendi xA ; an d testin g wa s accomplishe d i n accordanc e wit h a pro toco l approve d byth e Idah o Departmen t ofHealt h an d Welfare , base d upo n a modifie d NIOS H metho d 1501 .

Tea m Leader : Robert G . Richard s Title : Staf fEnginee r Signature : Date : Reviewer : Davi d L . Kinqhor n Title : Senio rProjec t Enginee r 

# MfX Signature : _, . , •/t^ - 

# Date : J0 

# J f 

# J 9l

I

V 

# 4 -

# 1.0 INTRODUCTIO N 1. 1 Purpos e GE ADynami cFabricator s (GEA) operate s a fiberglas s reinforce d plasti c(FRP ) facilit y a t Rathdrum , Idaho

. Operator s la yu p variou s pane l design s o n mold s an d mandrel s wit h wove n roving , cloth , ma t an d choppe d fiberglas s strand s a s required

. The ythe n spra yth e la yu p wit h polystyren e resin

. Resi n form s th e materia l matri xan d bond s th e fiber s together

. Afte rcuring , th e finishe d panel s ar e use d i n coolin g tower s an d corrosion-resistan t pip e installations

. I n accordanc e wit h Sectio n 4 o fth e Permit , GE Acontracte d Biso n t o submi t a tes t metho d fo rapprova l b yth e Stat e an d conduc t th e testin g a s define d above

. Xfaere ar e n o approve d methods_fQr_tfiSting_styren e i n thi s applicatio n s o a modificatio n o f NIOS H 150 1 wa s submitted^andapproved

. Energ yLaboratorie s wa s selecte d t o per for m th e absorbe rtub e analysi s an d worke d wit h Biso n i n designin g th e test
. Additionally , i n accordanc e wit h Sectio n 4 o fth e Permit , visibl e emission s wer e observe d durin g styren e testing

. 

## 1. 2 Emissio nSourc eDescription Th e FR P buildin g i s sectione d int o a spra yboot h (#1) , a pip e windin g are a an d pum p roo m (#2) , an d a curin g are a (#3)

. Resin , gelcoat , catalys t an d solven t ar e store d i n a secondar yconcret e containmen t are a unde ra canop yattache d t o th e FR P building

. Whe n sprayin g operation s ar e bein g conducted , th e buildin g i s floode d wit h fres h ai r i n orde rt o mee t th e Occupationa l Safet yan d Healt h Administratio n standar d fo r styrene
. Fugitiv e styren e an d particulat e emission s develo p fro m forming , curing , an d handlin g o fth e products

. I n particular , sprayin g an d curin g operation s produc e styren e emissions

. Tw o induce d draf t (ID ) fan s ventilat e th e wor k area s throug h filter s t o remov e particulat e an d conve ystyren e fume s t o tw o stacks

. Thre e booth s ar e use d i n th e productio n proces s a s note d above ; boot h 1 exclusivel yexhaust s int o stac k 1 (north ) an d booth s 2 an d 3 exhaus t int o stac k 2 (east)

.



# s -P. 7



## "~ ^ 1. 3 Control EquipmentDescriptio n j Styren e emission s are limite d b yth e operationa l condition s an d resi n formulations

.

N o additiona l control s are used

. 

## r ! T o reduc e particulat e matte remissions , th e exhaus t ai ri s cleane d b ya two-inc h thic k

graduate d densit yfiberglass-filte rmedi a whic h i s incorporate d int o eac h boot h wal l vent
. Verylittl e particulat e matte rwit h a mea n aerodynami cdiamete rles s tha n 1 0 micrometer s i s produced , an d th e remova l efficiencyo fth e filter s i s estimate d t o b e 80%
. Therefore , n o additiona l contro l equipmen t i s necessary . 

## 1. 4 Sourc eTes tDate s Biso n personne l arrive d a t th e sit e fo rsetu p o n Augus t 26 , 1993
. The yteste d bot h stack s o n tha t day

. Sinc e th e testin g methodolog yi s new , on e absorbe rtub e wa s sen t t o th e laboratorytha t da yfo ranalysis

. Preliminar ydat a fro m th e la b indicate d th e result s wer e nea rthos e estimate d b yAP4 2 calculations

. Becaus e o fthi s preliminary indication , th e tes t cre wan d operatin g personne l fel t th e result s wer e representativ e an d deeme d th e tes t complete

. 

## 1. 5 Pollutants Teste d Th e Pretes t Protoco l (Appendi xA ) detail s th e tes t method s use d an d thei rrevisio n dates

. Additionally , containe d i n Appendi xE i s a cop yo fNIOS H Metho d 1501
. Biso n performe d thre e vali d complianc e run s o n eac h stack , eac h fo rfugitiv e styren e emissions , an d visibl e emission s (Metho d 9 ) i n accordanc e wit h Permi t 860-0035
. 

## 1. 6 Personnel 1.6. 1 Biso n Engineering

. Inc

. Bo b Richard s (lea d engineer) manage d th e program , operate d sampl e trains , analyze d data , an d coordinate d mobil e la b operations

. Richar d Myracl e assiste d i n operatin g th e samplin g syste m an d performe d a s on-sit e technician

.

G ?P. 8


# r 1.6. 2 Dynami cFabricators j ; Joh n Krisman , Facilit yManager , an d Do n Osburn , FR P Sho p Manager , supervise d th e

operatio n an d gathere d th e operationa l data

. Th e efficien t manne ri n whic h the y directe d operation s wa s greatl yappreciated

.

i



# ^=hP. 9

. > 

# 2. 0 TES T RESULT S SUMMAR Y 2. 1 Emissio nResult s Thi s sectio n discusse s th e result s o fth e testin g accomplishe d as describe d above

. Appendi xB contain s Biso n fiel d dat a sheets

. Idah o Permi t t o Construc t 860-0035 , Sectio n 2 , state s "Th e combine d emission s fro m th e Stac k

No

. 1 an d No

. 2 shal l no t excee d 8. 1 pound s pe rhou ra s determine d

.. . analysis

. Annua l styren e emission s shal l no t excee d 21. 1 ton s pe ryear.. . operate(s). " Sectio n 4. 2 o fth e Permi t state s "Visibl e emission s shal l b e observe d durin g th e tes t usin g th e method s i n th e .. . Control. " Tabl e 2 summarize s th e result s o fthe.testing : 

## Tabl e2 Styren eand Visibl eEmissions

Styren e Nort h 1 (Ib/hr) Styren e Eas

t 2 (Ib/hr) Combine d (Ib/hr ) Opacit y(% ) Ru n 1

10.00 6 6.68 0 16.68 6 0 :: ;f : ^Run.2' ; .*

. • 7.07 3 8.73 1 15.80 4 0 Ru n 3

10.30 4 9.51 7 19.82 1 0 Averag e

9.12 7 8.30 9 17.43 6 0 

## 2. 2 Proces s Dat a Appendi xC contain s th e fiel d dat a sheet s indicatin g th e usage s o feac h typ e o fresi n o rgelcoa t alon g wit h th e productio n schedul e durin g th e test
. Additionally , fugitiv e emission s are estimate d usin g AP4 2 calculations

. A s indicate d i n Joh n Krisman' s letter , FRP productio n i s a batc h proces s an d no t a continuou s one ; therefore , clos e coordinatio n wa s necessar yi n orde rt o ru n a produc t mi xtha t woul d mos t closel yapproximat e th e maximu m productio n rate
. A s indicated , thi s goa l wa s achieved

. I t seeme d pruden t a t thi s poin t t o emphasiz e th e fac t tha t productio n wa s schedule d t o maximiz e fugitiv e styren e emission s an d doe s no t neces saril yrepresen t a norma l operatin g schedule

.P.1 0



# 3. 0 SAMPLIN

G AN D ANALYSIS 3. 1 Sampl e Locatio n Appendi xA , Pretes t Protoco l an d Permi t t o Construc t contai n a schemati co fth e facilit ylay-ou t an d th e stack s wit h samplin g por t location

. 

## 3. 2 Samplin g Procedure s Th e Pretes t Protoco l (Appendi xA ) contain s a schemati co fth e styren e samplin g train

. Appendi xB contain s th e fiel d dat a sheet s use d durin g th e sampling

. A ' 16-poin t travers e wa s use d fo rvelocity/stac k flow-rat e calculations

. Asingl e centrioda l poin t wa s use d fo rstyren e sampling

. Operator s performe d a Metho d 2 velocit ytravers e durin g eac h styren e ru n t o quantif y cycloni cflo wan d determin e stac k flow

. Acertifie d observe rlogge d Metho d 9 visibl e emission s fro m eac h stac k fo r1 2 minute s concurrentl ywit h eac h vali d styren e run . 

## 3. 3 Fiel dNote s an dSpecial Circumstance s Thi s sectio n discusse s samplin g an d analysi s procedure s whic h deviate d fro m accepte d tes t method s o rth e Protocol

. Th e testin g wen t smoothly , thank s t o th e organizatio n o fth e facilit ypersonnel , an d di d no t deviat e fro m th e approve d Protocol

. Thi s facilit yi s th e firs t i n th e Stat e o fIdah o tha t ha s bee n teste d fo rfugitiv e styren e emissions

. Althoug h th e methodolog yi s no t new , th e applicatio n is

. Usin g th e AP4 2 handboo k

emissio n factor , th e followin g emission s ar e estimated : 

## Tabl e 3 AP4 2 Estiinate dEmission s 

# I j Nort h 1 Styren e (Ib/hr ) Eas t 2 Styren e (Ib/hr

) | Combine

d Styren e (Ib/hr

) Ru n 1

4.6 5 3.4 4 8.0 9 Ru n 2

4.0 8 3.2 7 7.3 5 Run : 3' :;:f :

/E ' 3.0 7 5.2 5 8.3 2 Average

3.9 3 

### 3.99 1 7.9 2 ^ . *



# 9P.1 1



### A s ca n b e seen , th e actua l fugitive styren e emission s ar e not i n th e rang e ofth e estimated values . Discussion s wit h resi n manufacturer s indicat e th e resul t determined i n thi s test are significantl yhighe rtha n expected . Furthe rinvestigatio n ma yb e necessar yt o determin e i fsamplin g o rlaborator yprocedures someho

wallowe d fo r error s i n th e testing . 

## 3. 4 Dat aReductionan

d Calculation

s Method 2 travers e data wa s entere d int o spreadsheet

s fo rcalculations . Those calculation s are containe d i n Appendi xB. Additionally , th e emissio n rat e calculation s ar e contained i n th e Appendix . Contained i n Appendi xD are th e result s o fth e analysi s o

fth e absorbe rtubes alon g wit h a blank. Included ar e calibratio n dat

a and supportin g information . Appendi xE contain s Nomenclature , Formulae , an d Lab Methods .P.1 2



# 4. 0 QUALIT

Y ASSURANC

E
Biso n Engineering' s practice s confor m t o EP AQualit vAssuranc e Handboo k fo rAi r Pollutio n Measuremen t Systems

. Volum e 3 , EPA-600/4-77-0276 ; 197 7 a s amended

. A s noted , a n absorbe rtub e blan k wa s use d t o verif yconcentration s a t Energ y Laboratories

. Appendi xF contain s copie s o fcalibratio n dat a fo rth e samplin g train

. A t Bison , dat a qualit yassuranc e procedure s includ e independen t revie wo fdata entry an d calculations

.



# I

/P.1 3



# APPENDI X A : PRETES T PROTOCOL/PERMI T T O

CONSTRUC

T #860-0035



# /z -P.1 4 I >mm& - 3 0 SOUT

H E\WN G P.O . 80X170 3 HELEN \ M TS962 4 

# BISO N ENGINEERING , INC . PHONE : 404-442-576 8 FAX : 406-449-665 3 

### Jul y23 , 199 3

Ro n Hil l Divisio n o f Environmenta l Qualit y 141 0 Nort hHilto n Statehous e Mai l Boise , I D 83720-900 0 Re : Styrene Emission s Complianc e Test s a t GE A Dynami c Fabricators ; Rathdrum , Idah

o Dea r Mr . Hill : GE ADynami c Fabricator s ha s engage d Biso n Engineerin g t o perform styren e emissio n complianc e test s a t thei r Rathdru mfacility . I hav e bee n unabl e t o find a suitabl e EP Areferenc e metho d fo r thi s test . Biso n ha s designe d a tes t campaig n whic hshoul d giv e vali d styren e emissio n dat a fo r thi s source . Th e attache d Pretes t Protoco l describe s th e propose d tes t i n detail . Pleas e revie wi t and cal l m e i f yo u hav e an yquestion s o r comments . Biso n personne l wil l repor t t o th e sit e th e afternoo n o f Augus t 25 , 1993 , fo r setup . Test s wil l commenc e th e nex t day . I f yo u hav e an

yquestions , pleas e contac t m e a t (406 ) 442-5768 . Sincerely ,
Rober t G . Richard s Lea d Enginee r Ene . c c : Joh nKrisma n


# 13P.1 5 

## 1 I 

### SOURC E TES TPROTOCO L

1. 0 INTRODUCTIO N 3 Corporat e Addres s an d Plan t Location : GE ADynami cFabricator s 173 5 Wes t Highwa y5 3 Rathdrum , Idah o 8385 8 (208 ) 773-178 7 Permi t Number(s) : Sourc e an d Tes t Summary : 

## • 860-003 5 (Feb
. 5 , 1993 )
Complianc e test s o n tw o stack s fo rstyren e (C 6 

### H 5 

### CHCH 2 

### ) emissions ; concurren t visibl e emission s observation s fo rinformatio n
2. 0 EMISSIO N SOURC E INFORMATIO N
2
. 1 Facility

Description

and Process Information GE ADynami cFabricator s operate s a fiberglas s reinforce d plasti c(FRP ) facilit y a t Rathdrum , ID

. Operator s la yu p variou s pane l design s o n mold s an d mandrel s wit h wove n roving , cloth , mat , an d choppe d fiberglas s stran d a s required

. The ythe n spra y th e la yu p wit h polystyren e resin

. Resi n form s th e materia l matri xan d bond s th e fiber s together

. Afte rcuring , th e finishe d panel s ar e use d i n coolin g tower s an d corrosion-resistan t pip e installations

. 2.2 Emission

Source Description Se e th e Attachment s fo rstac k schematics

. Fugitiv e styren e an d particulat e emission s develo p fro m forming , curing , an d handling

. I n particular , sprayin g an d curin g operation s produc e styren e emissions

. Tw o I D fan s ventilat e th e wor k are a throug h filter s t o remov e th e particulat e an d conve ystyren e fume s t o tw o roo fstacks

. Safet yan d Access

. Yello wcautio n tap e wil l aler t plan t personne l t o overhea d wor k i fneeded

. GE A wil l suppl ysuitabl e platform s o ra scissor s lif t fo rstac k por t access . Personne l


# J 4— *



# ' 1

-* -

- a

• - 

### 3. 0

3.1

3.2

3.3 P.1 6 \

* T 

### Safetv

. Tes t Dersonne l wil l hav e th e followin q safet yequipmen t a t hand : 1
. Har d hat

. 2
. Ful l lengt h pants , shirts , and/o rcoveralls

. 3
. Ful l lengt h wor k boots

. 4
. Respirato rwit h organi cfum e an d HEP Acartridges

. 5
. Hearin g protection

. 6
. Wor k

gloves

. 7
. Safet yglasse s wit h sid e shields

. SOURC E TES TPROGRA M DESCRIPTIO N Testing Contractor Biso n Engineering , Inc

. P.O

. Bo x170 3 Helena , Montan a 5962 4 (406 ) 442-576 8 FA X (406 ) 449-665 3 Projec t Manager : Bo b Richards , Lea d Enginee r Personnel Bo b Richard s (lea d engineer ) wil l operat e sampl e train s an d reduc e laborator y data

. Dav e Kinghor n (senio rprojec t engineer ) wil l revie wreport s an d qualit ycontro l procedures

. Joh n L

. Krisma n (facilit ymanager ) i s th e primaryon-sit e contact
. Energ yLaboratories , Inc

. (P.O

. Bo x30916 ; Billings , M T59107-0916 ; (406 ) 252-€23£ ) wil l analyz e th e styren e absorbe rtubes

. 

## C3^S * Test Program

Objectives Idah o Permi t t o Construc t #0860-003 5 limit s styren e emission s t o 8. 1 Ib/h r fro m bot h stack s combined

. Thi s Protoco l specifie s a tes t metho d an d projec t campaig n t o quantif yth e styren e emissions

. Acertifie d observe rwil l lo g visibl e emission s concurren t wit h styren e test s accordin g t o th e Permit' s Sectio n 4 "Monitorin g Requirements. "

2P.1 7



## 1 

## *


# 1 Tes t an d Repor t Date s

Biso n personne l wil l arriv e a t th e sit e Augus t 25 , 1993
. Test s wil l commenc e th e nex t day

. Th e Complianc e Tes t Repor t wil l b e submitte d withi n 3 0 day s o f th e en d o fth e tes t campaign

. 4. 0 SOURC E TESTIN G PROCEDURE S 4.1 Equipment

Description Se e Attachment s fo ra sampl e trai n schematic

. 4.2 Test Methods Biso n wil l sampl e th e source s fo ractua l flow , correcte d flow , composition , moisture , styren e an d visibl e emissions

. Styren e conten t (mg/m 3 

### o fstac k gas ) wil l b e correlate d wit h EPAreferenc e method s fo rstac k velocit yan d flo wt o arriv e a t Ib/h remissio n rate
. Tes t personne l wil l emplo yth e followin g Titl e 4 0 CF R 60 , Appendi xA(EP A reference ) method s fo rstac k flo wan d visibl e emissions : Samplin g Locatio n an d Travers e Points : Metho d 1 , "Sampl e an d Velocit y Traverse s fo rStationar ySources " Velocit yan d Volume : Metho d 2 , "Determinatio n o fStac k Ga s Velocit yan d Volumetri cFlo wRat e (Typ e S Pito t Tube) " Composition : Metho d 3 , "Ga s Analysi s fo rCarbo n Dioxide , Oxygen , Exces s Air , an d Dr yMolecula rWeight " Visibl e Emissions : Metho d 9 "Visua l Determinatio n o fth e Opacit yo fEmission s fro m Stationar ySources " Acertifie d observe rwil l recor d visibl e emission s fo r(one ) 12-minut e perio d concurrentl ywit h eac h styren e samplin g run . I fweathe rcondition s prohibi t suitabl e observations , the ywil l b e complete d a s soo n a s practicabl e followin g th e styren e tes t runs . Al l th e method s abov e ar e revise d throug h Jul y1 , 1991 ; correcte d a t 5 7 F R 24550 , Jun e 10 , 1992
. Researc h ha s no t reveale d an yreferenc e method s fo rstyren e emission s measuremen t fro m stationar ysources . Biso n propose s th e followin g metho d t o obtai n vali d data

.



# lbP.1 8



### • 1 Moistur e Content :

Stac k ga s consist s o fatmospheri cai rpulle d fro m th e workrooms

. Hig h relativ e humidit yaffect s th e "breakthrough " capacit yofth e absorbe rtubes

. Volumetri c wate rcontent , however , wil l no t likel yexcee d 1 % (vol ) eve n a t 100 % relativ e humidity

. i 

### Becaus e th e relativ e humidit yvalu e i s a n importan t paramete rfo rth e styren e test , th e tes t operato rwil l obtai n we t bulb/dr ybul b temperature s prio rt o eac h tes t run . H e wil l deriv e relativ e humidit yan d volum e % wate rconten t fro m psychrometri ccharts

. Stvren e Emissions : General Considerations Th e Permi t impose s a styren e emissio n limi t o f8. 1 Ib/h rfro m bot h stack s combined

. I fw e assum e th e facilit ymeet s th e limit , an d emission s ar e evenl y divide d betwee n th e tw o stacks ; eac h stac k ma yemi t u p t o 4.0 5 lb/h r(183 7 g/hr)

. Th e Permi t quote s stac k velocit ya t 456 5 feet/mi n (138 5 m/min ) wit h a-24 " (0.609 6 m ) diameter

. Stac k are a i s 0.29 2 m 2



### . Stac k flow , therefore , i s abou t 40 4 m 3 

### /mi n o r24,27 0 m 3 

### /hr

. A t th e permi t limit , w e expec t abou t 75. 7 mg/m 3 

### o fstyren e i n th e stac k ga s (approximatel y18. 7 ppmv)

. Proposed

Styrene Test Method Biso n propose s a modificatio n o fNIOS H metho d 150 1 (issue d 2/15/84)

. I n tha t method , a persona l samplin g pum p draw s breathin g zon e ai rthroug h a double sectio n coconu t charcoa l absorbe rtube

. Th e charcoa l absorb s aromati c hydrocarbon s fo rlate ranalysis

. Afte rsampling , a contrac t la b desorb s th e tw o section s wit h carbo n disulfide

. Ga s chromatograph yquantifie s styren e conten t i n th e "front " section

. A s a qualit ycheck , an ystyren e number s fro m th e "back " sectio n sho w breakthrough

. Th e styren e conten t divide d b yth e actua l ga s volum e pulle d throug h th e tub e yield s styren e pe runi t volume

. Correlatio n wit h actua l stac k ga s volum e flowrat e pe rhou rdurin g th e sampl e ru n provide s th e styren e emissio n rate
. Proposed

Sampling

Method Th e propose d sampl e pum p an d dr yga s meterin g syste m confor m t o Titl e 4 0 CF R 6 0 Appendi xA , Metho d 6 (Determinatio n o fSulfu rDioxid e Emission s fro m Stationar ySources ) Sectio n 2 requirement s fo rapparatus
. Th e probe , dryin g



# ttP.1 9



### tube , an d absorbe rtub e appropriat e tubing

. wil l b e plumbe d int o th e meterin g syste m wit h
Biso n propose s tha t eac h complianc e tes t ru n las t fo ron e (1 ) hour

. Th e tw o stack s wil l b e sample d simultaneously

. Samplin g rat e wil l b e 1/2 litr e pe r minut e (l/min) , fo ra tota l sampl e volum e o f3 0 litres

. I feac h stac k emit s it s permitte d 75.6 8 mg/m 3 

### (75.6 8 //g/l) , eac h sampl e wil l contai n 2.27 0 m g o f styrene
. Thi s wil l provid e a representativ e sampl e fro m eac h stack

. Immediatel yprio rt o eac h tes t run , tes t operator s wil l perfor m Metho d 2 velocit ytraverse s t o quantif ystac k flow.

. &*w-%* - Th e tes t operator s wil l the n instal l absorbe rtube s i n th e sampl e trains , se t th e sampl e flo wrate , an d inser t th e prob e i n th e stack

. Bot h train s wil l b e starte d an d stoppe d simultaneously

. Durin g eac h run , operator s wil l recor d dr yga s mete rvolume , an d mete rtemperature s ever y5 minutes

. Tester s ma yop t t o us e a critica l orific e selecte d fo r1/2 l/mi n flo wa s describe d i n th e "Alternativ e Methods " sectio n o fMetho d 6
. I n thi s event , th e critica l orific e wil l b e calibrate d an d use d accordin g t o Metho d 6 , Sectio n 7.2
. Absorber

Tube Capacity Metho d 150 1 employ s a "100/50 " absorbe rtube

. Thi s mean s th e fron t sectio n contain s 10 0 m g o fcharcoal , th e bac k sectio n 5 0 mg . Th e absorbe rtub e vendo r(SKC , Inc. ) an d th e laborator y(Energ yLabs ) agre e that , a t thes e concentrations , eve n smal l sampl e volume s ma ybrea k through

. Th e test s wil l emplo y"400/200 " (SK C Cat

. # 226-09 ) absorbe rtube s t o P-n tthi 

### , \^^ ) I carbo n disulfide

. Fo rth e large r I b e needed

. Thi s wil l chang e th e ub e sample

. Thi s leve l represent s Detection

Umits and Interferences Metho d 150 1 require s desorbtio n w ( 

### tubes , Bil l Brow n o fEnerg yLab s fee l minimu m detectio n limi t t o 2 0 pg sty r less tha n 1 % o fth e theoretica l sampl e (T.2 7 mg) , an d i s reasonable

. Hig h relativ e humidit yi s a potentia l samplin g interferant

. Moistur e contaminatio n reduce s absorbe rcapacity

. Adryin g tub e wil l b e installe d ahea d o fth e absorbe rtub e t o preven t this

. Th e mos t significan t potentia l analysi s interferant s ar e xylen e isomers , particularl yortho-xylene

. Th e facilit ymanage rindicate d tha t GE Ause s n o xylene-base d solvents

. Mos t solvent s an d cleaner s ar e water-base d wit h som e aceton e use d fo rspra ygu n cleanup

. Aceton e shoul d elut e quickl yi n th e GC column ; an yaceton e peak s shoul d occu rwel l befor e th e styren e analyt e peak

.



# rtP.2 0

•m 

### 4.3

Analytical

Methods Molecula rWeight

. Tes t personne l wil l sampl e stac k ga s wit h a bul b pum p an d analyz e wit h Orsa t o rFyrit e instrument s as appropriate

. Psychrometri cchart s provid e moistur e dat a fro m we t bulb/drybul b temperatures
. Stac k Ga s an d Sampl e Volume

. Metho d 2 traverse s provid e flo wdata

. Stac k ga s an d sampl e volume s wil l be reporte d as actua l m 3 

### (f3 

### ) an d drystandar d m 3 

### (dscf)

. Stvren e Content

. Energ yLab s wil l desor b th e tube s an d analyz e fo rstyren e accordin g t o NIOS H Metho d 150 1 vi a gas chromatograph y(FI D detector)

. Styren e conten t wil l b e correlate d wit h actua l stac k flo wt o arrive - a t a g/h r (Ib/hr) emissio n rate
. General

. Dat a reductio n method s follo wthos e outline d i n Titl e 4 0 CFR 60, - Appendi xAan d wil l be conducte d at Biso n Engineerin g (3 0 S

. Ewing , Helena , MT)

. "«, 

### 4.4 Production

Data Plan t operator s wil l record th e amoun t an d typ e o fresin s an d gelcoa t use d durin g styren e tes t run s 5. 0 QUALIT

YASSURANC E PROCEDURE S Biso n Engineering' s test , laboratory , reporting , an d qualit yassuranc e procedure s confor m t o th e requirement s specifie d i n th e Qualit yAssuranc e Handboo k

fo rAi rPollutio n Measuremen t Systems

. Vol

. III

. StationarySourc e Specifi cMethod s publishe d byth e U.S

. Environmenta l Protectio n Agencyi n August , 197 7 as revise d an d amende d (cat

. # EPA-600/4-77-027b)

. Blanks

. Biso n wil l documen t on e fiel d blan k t o verifyhandlin g procedures

. Th e operato rwil l ope n th e tube , instal l i t i n th e samplin g train , adjus t th e trai n fo r rope rflow , an d retur n th e tub e t o th e carrying container

. Th e laboratorywil l analyz e th e blan k

alon g wit h th e workin g samples

. Sample Handling

Protocols Operator s complet e an d initia l fiel d dat a sheets , char t records , etc
. befor e leavin g th e site

. Sampl e Chain-of-Custod yform s ar e attached

.



# i< ?P.2 1

- I * 

## • 5.2 Data VaUdation

'• t



### - I n general , th e Projec t Manage ri s responsibl e fo rdat a validation . Whe n on e j perso n enters dat a o rcalculation s int o a for m o rspreadsheet , a differen t perso n

review s it . Reviewer s perfor m cross-checks an d tria l calculation s a s

. 1 appropriate .



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# to U 4 Clien t Descriptio n

Projec t No . Tota l No . o fSample s Dat e Sampl e I.D .

Dat e Compan yName/Addres s Receive d b y Metho d

•

Shippin g No . Typ e o fSampl e
Dat e Sampl e I.D .

Dat e Compan yName/Addres s Receive d by Samplers ' Signatur e Analytica l Metho d Requeste d
Metho d

Shippin g No . Dat e Sampl e I.D .

Dat e Compan yName/Addres s Receive d b y Metho d 

# J

; Shippin g No .

Rev ? 7/9 3P.2 5
U

I I 

### JUN-22-199 3 12:3 6 FROM DYNAMI C FABRICATOR S T O 1406449665 3 P.0 2
OAM O OEPAATMEN

T O fHEALT

H ANO WEUM E 

### OIVISIO N O F jjfc ENVIRONMENTAL QUALIT Y

141 0 Non h Hilu a Statihou M M** . Boin . I O 8372O-90C0 . (208 ) 334-OS M •Coc a 0 . Anew , Go»«.-r r


# fi •J J 

## K-<c c February

5 , 199 3

CERTIFIE DMAI L # Pil l 44 6 59 9

Joh nL . Krisma n Facilit y

Manage r GEA/Thermal-Dynami c Towers , Inc . 1260 0 W . Colfa xAvenu e Suit e C50 0 Lakewood , C O 8021 5
RE : Permi t t o Construc t #860-0003 5 GEA/Thermal-Dynami c (Rathdrum ) — P-92120 4 (Modificationt o Fiberglas s Manufacturing Process ) Dea r Mr . Krisman : O nDecembe r 15 , 1992 , DE Q receivedyour Permi t t o Construc t applicationfo r a modificationt o a fiberglas s manufacturin g proces s currentl y

operating i nRathdrum , Idaho . Th e application wa s declare dcomplet e o nJanuary

11 , 1993 . Base do ntha t application , w e no w fin dtha t the proposedsourc e meet s the provision s o f IDAP A 16.01.0101 2 o f th e Rule s an

dRegulation s fo r the Contro l o f Ai r Pollutioni nIdaho . Therefore , enclose di s your Permi t t o Construc t #860-00035 , whichsupersede s th e origina l Permi t t o Construc t #0860-003 5 issue dJanuar

y 30 , 1990 . Pleas e pay

particula r attentiont o th e reportin g requirement s containedi nParagrap hE o f the Genera l Provisio nSectio no f the permit . Thi s informationi s neede dt o properl y trac kth e progres s o f th e project . Pleas e refe r t o th e appropriat e permi t numbe r whe n submitting report s requiredi nth e Reportin g Requirement s Section o f th e Permit . You , a s wel l a s an

y othe r entity , may

hav e the righ t t o appea l thi s fina l agency

actio npursuan t t o th e Idah o Departmen t o f Healt han d Welfar e Rule s andRegulations , Titl e 5 , Chapte r 3 , "Rule s Governing ContestedCas e Proceeding s an dDeclarator

y Rulings, 1 1 

### b

y filing a petitionwit hth e Hearing Coordinator , Departmen t o f Healt han d Welfare , Administrative Procedure s Section , 45 0 Wes t stat e Stree t - 10t hFloor , Boise , Idaho 83720-5450 , withi n(30 ) thirt y day s o f the dat e o f thi s decision . 

# i £P.2 6



### JUN-22-199 3 12:3 7 FRC T DYNAMI C FABRICATOR S 

## T O 1406449665 3 P.0 3

• s 

## Joh

nL . Krisman Februar y 5 , 199 3 Pag e2 

## I f you hav ean y question s regardin gth eterm s o rcondition s o f th e enclose d permit , pleas econtac tMarti nBauer , Bureau Chief, Constructio nPermit s Bureau , Permit s an d Enforcement , DEQ , a t (208 ) 334-5898 . Sincerely ,
orvill e D . Gree n Assistan t Administrato r Permit s ahd Enforcemen t ODG/AR/tdt.lt r Enclosur e cc : G . Burr , NIR O D . Cole , EPA-IO O T . Harman , NIR O J . Markley , Cit yEnginee r A . Ra y P . Rayn e Sourc e Fil e Fil e Manua l CO F 1.1 ,



# 2£ TP.2 7



# 3 JUN-22-199 3 12:3 8 FRO M DYNAMI C FABRICATORS 

### T O 1406449665 3 Pag e 

### P.i)4 1

_ Of STAT E O F IDAHO PERMI T S O CONSTRUC T A N AI RPOLLUTION

EMITTINGSOURC E PERMI T NUMBE R AQCRCLAS S 8I C 

# Em ucm 1

3 i o

# 17» i ZON E UT M

COORDINAT E (ka ) 

### EC O ISToTT} . |T) 1 5 1 2 1 9 I b I 0 1 . PERMITTE E GEA/Thermal-Dynami c Towers , Inc . 2 . PROJBC T Fiberglas s fabricatio nfacilit y 3 . MAILIN

GADDRES S 1260 0 W . ColfaxAvenue , Suit e CS0 0 4 . SIT E LOCATION

COUNT S Kootena i CITX Lakewoo d NO . O F FULL TIM

E EMPLOZEB S 2 0 t o 6 0 PERSO N T O CONTAC T Joh nL . Krisma n STAT E C O ZI P COD

E 8021 5 PROPERT YAREA

A T SIT E (Acreage ) 1 0 acre s TITL E Facility

Manage r TELEPHONE NUMBE R (208 ) 773-178 7 EXAC T PLANT LOCATIO N 173 5 W . Highway

53 , Rathdrum , Idah o 8385 8 GENERA L NATUR E O F BUSINES S AN DKIND S OF PRODUCT S Fiberglas s reinforce dplasti c pane l an dpip e productio

n GENERA L CONDITION S Thi s perni t i s issue daccording t o th e Rule s an

dRegulation s fo r th e Contro l o f M r Polltrfcio

ui nIdaho , Sectio n16.01.01012 , an

dpertain s onl y

t o ena.sflion

s o f ai r contaminant s whic har e regulate db y th e Stat e o f Idaho an dt o th e source s specificall y

allowe dt o b e constructe db y thi s permit . Thi s permi t (a) ' doe s no t affec t th e titl e o f th

e premise s uponwhic hthe equipmen t i s t o b e located , (b ) doe s no t releas e the permitte e fro m an y liabilit y

for an

y los s du e t o damage t o perso nor propert y

cause dby , resultin

g from , o r arising ou t o f th e design , installation , maintenance , or operatio n o f th e propose dequipment , (c ) doe s no t releas e the permitte e fro m complianc e wit hothe r applicabl e federal , state , triba l or loca l laws , regulations , o r ordinances , (d ) i nno manne r implie s or suggest s tha t th e Departmen t o f Healt h an dWelfare , o r it s officers , agents , o r employees , assume s an y liability , directl y

o r indirectly , fo r an y los s due t o damag e t o perso no r propert y caused by , resulting from , o r arising out o f design , installation , maintenance , o r operationo f th e propose dequipment . Thi s permi t i s no t transferabl e t o anothe r person , place , piec e o r se t o f equipment . Thi s permi t wil l expir e i f constructio nha s no t begunwithi ntw o year s o f it s issue dat e o r i f constructio ni s suspende

dfor on e year . THI S PERMI T HA S BEE N GRANTEDON

TH B BASI S O F DESIG

N INFORMATIO

N PRESENTE DWIT H IT S APPLICATION . CHANGE S O F DESIG N O REQUIPHENT THA

T RESUL T IN

AN YCHANC E I N THB NATURE ORAMOUN T O F EMISSION S MUS T B E APPROVEDI N ADVANC E B

YTH E DEPARTMENT .



# 2d,P.2 8

JUN-22-199 3 12:3 9 FRO M DYNAMI C FABRICATOR S 

## T

O 1406449665 3 P.0 5

PERMI T T

O CONSTRUCT . PERMITTEE , PROJECT , AN DLOCATIO

N GEA/Thermal-Dynami c Tower s Rathdrum , Idah

o
SOURC E Polyeste

r Resi nOperatio

n Pag e 2 of 7
PERMI T NUMBE R 0 8 6 0 - 0 0 3 5



### 1 . SOURC E DESCRIPTIO N 1. 1 proces s Description . Th e facilit y manufactures , fiberglas s reinforce dplasti c (FRP ) pane l segment s whic hfunctio na s externa l coverin g fo r coolin g towe r framework . Additionally , larg e diamete r FR P coolin g towe r pip e an dcorrosive-resistan t pip e liner s ar e produced . Th e fiberglassin g buildin g i s sectione dint o a spra y booth , a pip e windin g area , a pumproom , anda curin g area . Resins , gelcoat , catalys t an dsolven t ar e store di na secondar y concret e containmen t are a unde r a canop y attache dto th e fiberglassin g building . Whe nsprayin g operation s ar e bein g conducted , th e buildin g i s floode dwit hfres hai r i norde r t o mee t th e Occupationa l Safet y an d Healt hAdministratio n(OSHA ) workplac e standar dfo r styrene . Styren e emission s ar e du e t o resi noverspra y an dth e FR P curing process . Th e contaminate dai r i s exhauste dthroug htw o (2 ) wai l vent s andsen t u pseparat e stacks . 1. 2 contro l Description . Styren e emission s ar e limite db y th e operationa l condition s specifie di nSectio n3 o f thi s permit . No add-o ncontrol s ar e provided . T o reduc e particulat e matte r (PM ) emissions , th e ai r i s cleane db y " a two (2 ) inc hthic kgraduate ddensit y fiberglas s filte r medi a whic hi s incorporate dint o eac hwal l vent . Th e remova l efficienc y i s estimate dt o b e eight y percen t (80% ) fo r PM . Ver y littl e particulat e matte r wit ha mea naerodynami c diamete r les s tha n1 0 micrometer s (PM-10 ) i s produced . Therefore , PM-1 0 contro l equipmen t i s no t required . 1. 3 Stac kSpecifications . Stack s liste dshal l mee t th e followin g specifications . Ga s velocitie s ar e denote di nfee t pe r minut e (FPM) : 1.3. 1 Stac kNo . l : 2 8 fee t height , 2 fee t diamete r and / 

### 4545 /



## FPM ; 

## \^_y

<P\ / ASSISTANT ADMINISTRATOR 

### DATE : Februar y 5 , 1-9*9

3 

## -7^

-P.2 9

JUN-22-15S 3 12=4 0 FRO M DYNAMI

C FABRICATOR

S T

O 1406449665 3 P. K

Pag e o *
__ L PERMI T T O CONSTRUC

T PERMITTEE

, PROJECT , AN

D LOCATIO

N GEA/Thermal-Dynami cTower s Rathdrum , Idah o PERMI T NUNBE R 0 8 6 0 - 0

SOURCE Polyeste rResi nOperatio n 

### 1.3. 2 Stac k No .

FPM . 2 : 2 8 fee t height , 2 fee t diamete r an d 454 5 2 . EMISSIONLIMIT S 2. 1 Th e combine d styren e emission s fro mStac k No . 1 an d Stac k No . 2 shal l no t excee d 8. 1 pound s pe r hou r a s determine d b yth e Department' s emissio n estimatio n method s use d i n thi s permi t analysis . Annua l styren e emission s shal l no t excee d 21. 1 ton s pe r year , a s determine d b ymultiplyin g th e allowabl e poun d pe r hou r emissio n rat e b yth e actua l hour s pe r yea r tha t th e process(es ) whic hven t t o thes e stack s operate(s) . 2. 2 Volatil e organi c compound emission s (othe r tha n styrene ) fromStac k No . 1 an d Stac k No . 2 combine d shal l no t excee d 0.6 5 pound s pe r hou r a s determine d b yth e Department' s emissio n estimatio n method s use d i n thi s permi t analysis . Annua l volatil e organi c compoun d emission s (othe r tha n styrene ) shal l no t excee d 1.6 9 ton s pe r year , a s determine d b ymultiplyin g th e allowabl e poun d pe r hou r emissio n rat e b yth e actua l hour s pe r yea r tha t th e proces s (es ) whic hven t t o thes e stack s operate(s) . 2. 3 Emission s o f particulat e matte r (PM ) fro m Stac k No . 1 an d Stac k No . 2 combine d shal l no t excee d 2.1 9 pound s pe r hou r a s determine d by th e Department' s emissio n estimatio n method s use d i n thi s permi t analysis . Annua l P M emission s shal l no t excee d 5.6 8 ton s pe r yea r a s determine d b ymultiplyin g th e allowabl e poun d pe r hou r emissio n rat e byth e actua l hour s pe r yea r tha t th e proces s (es ) whic hven t t o thes e stack s operate(s) . 2. 4 Emission s o f particulat e matte r wit ha mea n aerodynami c diamete r les s tha n o r egua l t o 1 0 micrometer s (PM-10 ) (se e IDAPA 16.01.01003,7 3 o f th e Rule s an d Regulation s fo r th e Contro l o f Ai r Pollutio n i n Idaho ) from Stac k No . 1 and Stac k No . 2 combine d shal l no t excee d 2.1 9 pound s pe r hou r a s determine d byth e Department' s emissio n estimatio n method s use d i n thi s permi t analysis . Annua l PM-1 0 emission s shal l no t excee d 5.6 8 ton s pe r year , a s deteraine d b ymultiplyin g th e allowabl e pound pe r hou r emissio n rat e b yth e actua l hour s pe r yea r tha t th e proces s (es ) whic hven t t o thes e stack s operate(s) . 

# JK ASSISTAN

T ADMINISTRATO

R PERMIT S AN

DENFORCEMENT DAZE : Februar y S, -199 3



# -2&.P.3 0

JLM-22-199 3 12M 1 FRO M DYNAMI

C FABRICATOR

S 

### T

O 1406449665 3 P.0 7

PERMI T T O CONSTRUC T PERMITTEE , PROJECT , AN DLOCATIO

N GEA/Thermal-Dynami c Tower s Rathdrum , Idah

o
SOURC E 

### Polyeste rResi nOperatio n Pag e4 o f 7
PERMI T NUMBE R 0 8 6 0 0 0 3 5



### 3 . OPERATIN G REQUIREMENT S 3. 1 Th e permitte e shal l us e polyeste r resin s wit ha monome r conten t o f n o mor e tha n thirty-fiv e percen t (35% ) b yweight . Thi s provisio n shal l no t appl yt o th e us e o f gelcoat , resi n use d fo r mol d constructio n an

d corrosion-resistan t resin . 3. 2 Excludin g th e gelcoa t an d specialt yresins , ninet ypercen t (90%)'b y weigh t o f al l polyeste r resin s use d byth e permitte e shal l hav e a styren e monome r conten t o f n o mor e tha n thirty-fiv e percen t (35% ) byweight . 3. 3 Th e permitte e shal l us e a gelcoa t wit ha styren e monome r conten t o f n o mor e tha n forty-thre e percen t (43% ) byweight . 3. 4 Th e permitte e shal l us e a soap base d cleaner , ND-16 5 an d aceton e a s th e cleanin g solvent . Th e amoun t o f aceton e i s restricte d t o 2 gallon s pe r day . 3. 5 Airles s spraygum s shal l b e use d includin g gelcoa t application . fo r al l spray-u p processe s 3. 6 Neithe r stac k No . 1 no r Stac k No . 2 shal l b e equippe d wit ha rai n ca p o r anyothe r obstructio n tha t woul d resul t i n th e downwar d deflectio n o f th e exhaus t ga s stream . 3. 7 Th e permitte e shal l a t al l time s kee p al l exterio r door s and/o r window s o f th e buildin g use d fo r fiberglassin g operation s tightl y close d excep t fo r th e explici t purpos e o f movin g necessar y equipment , material s o r personne l int o o r ou t o f th e building . 3. 8 Th e permitte e shal l us e close d container s fo r th e disposa l -o f al l gelcoat , resin , catalys t an d cleanin g material s i n suc ha manne r a s t o effectivel ycontro l styren e an d VO C emission s t o th e surroundin g air . 3. 9 Th e permitte e shal l a t n o tim e allo wcontainer s o f gelcoat , resin , catalys t o r cleanin g material s t o b e ope n t o th e atmospher e othe r tha n t o transfe r materia l t o o r fro mth e containe r o r t o inser t a pump . Thi s shal l appl yt o full , partiall yful l an d empt y 

# AL ASSISTAN T ADMINISTRATO R DATE : Februar y 5 , 1*95 3 

# 2 9. „ „ P.31
_ JUN-22-199 3 12^4 2 FRO M DYNAMI C FABRICATOR S TO 1406449665 3 P.& 3

P a 9 ° - S of 7 PERMI T T O CONSTRUC T PERMI T NUMBE R PERMITTEE , PROJECT , AN DLOCATION GEA/Thermal-Dynami c Tower s Rathdrum , Idaho 0 8 6 0 - 0 0 3 S

SOURCE Polyeste r Resi nOperatio n 

## containers . 3.1 0 Resin s and gelcoa t shal l b e stored ou t o f direc t sunlight . 3.1 1 Resins , gelcoat , fiberglas s an d catalys t ar e restricte d t o a maximu musag e a s follow s i n an ycalenda r year , a s pe r applicant' s submittal : Resin s 720,00 0 pound s pe r yea r Gelcoa t 103,00 0 pound s pe r yea r Fiberglas s 400,00 0 pound s pe r yea r Catalys t 17,50 0 pound s pe r yea r 4 . MONITORIN

G REQUIREMENT S 4. 1 Th e permitte e shal l submit , i n writing , th e propose d tes t methods fo r th e initia l performanc e tes t t o measur e styren e emission s fro m eac ho f th e stack s (Stac k Nos . 1 an

d 2) . Th e permitta e shal l receiv e Departmen t approva l o f the propose d tes t method s prior t o th e scheduling o f suchtesting . 4. 2 Th e permitte e shal l conduc t an initia l performanc e tes t t o measure styren e emission s fro meacho f the stack s (Stack Nos . l an d 2 ) in accordanc e wit hDEQ' s "Procedure s Manua l fo r Ai r Pollution Control " an d Genera l Provisio n F o f thi s permit . Visibl e emission s shal l be observe d during th e tes t usin g the method s i n th e DEQ' s "Procedure s Manua l fo r Ai r Pollutio n Control. " 4.2. 1 Durin

g the performanc e test , th e followin g dat a shal l be recorded : amoun t o f resin s an d gelcoa t used (i.e. , pounds pe r hour ) an

d the typ e o f gelcoa t an d resin s used . 4. 3 Performanc e test s shal l be conducted fo r particulat e emission s i f th e visibl e emission s excee d twenty(20 ) percen t opacityfo r mor e than thre e (3 ) minute s in an ysixtyminut e perio d fro meither o f th e Stac k Nos . 1 o r 2 . The test s shal l b e conducte d whil e th e operatio n i s performe d a t maximu m capacity . 4.3. 1 During th e performanc e test , th e following dat a shal l be

recorded : amoun t o f resins , gelcoat , catalys t an d

ASSISTAN T ADMINISTRATO R PERMITS AN

D ENFORCEMEN

T DATE : Februar y 5 , ±993



# 3 6P.3 2

JUN-22-199 3 12:4 2 FR C DYNAMI C FABRICATORS T O 1406449665 3 P.Q g

Pag e o f

T 

### PERMI T T O CONSTRUC

T PERMITTEE , PROJECT , AN DLOCATIO

N GEA/Thermal-Dynami

e Tower s Rathdrum , Idah

o PERMI T NUMBE R 0 8 6 0

- 0 0 3 5



### SOURC E Polyeste r Resi nOperatio

n fiberglas s usedan

dthe type o f resin s an dgelcoa t used . 5 . REPORTIN

GREQUIREMENT S 5. 1 The permitte e shal l submi t a performanc e tes t repor t requiredi n Section s 4. 2 an

d4. 3 o f thi s permit . Al l informatio nshal l be submittedt o the Departmen t withi nthirt y (30 ) days o f th

e dat e o

n whic hthe . performanc e test s wer e conducted . 5. 2 The permitte e shal l maintai nweekl y record s o

nsit e for th e mos t recen t tw

o (2 ) yea r period . Acces s t o thes e record s shal l be grantedt o Departmen t representative s upo nrequest . The record s shal l contai nthe following : 5.2. 1 The manufacturers ' name s an dth e amount s use

do f gelcoat , resins , catalys t an dcleanin

g solvent . 5.2. 2 The weigh t percen t o f styren e monome r inth e gelcoa t an

d resin s used . 5.2. 3 The numbe r o f hour s the facilit y operated .



# AL ASSISTAN TADSINISTRATO R PERMIT S AN

D ENFORCEMEN

T DATE : •'Februar y 5 , 199 3



### &\

## GEA/THERMA L DYNAMI C TOWER S 199 2 STYREN E USAG E REPOR T CTURERNAM E i)C T PASHLAN D P RHCHOL O •1 ' ASHLAN D •Q ASHLAN D
• O REICHOL D l»DIO N /NLDO W. L G ASHLAN D n.a REICHOL D •AfGYCOO K ATGYREFCO A \ TO P COO K VTOPREFCO A •UTLGCOO K PERCEN T •STYREN E 35 % 35 % 45 % •48 % 45 % 45 % 45 % 45 % 35 % 45 % 35 % 35 % ' 35 % 35 % 45 % M T5 0 NORA C '•o T3 0 NORA C • 1 I fN E CHLORID E 'IF. GREA

TWESTER N
•n O F HOUR S O F OPERATIO N . JAN USAG E 2036 0 0 0 4S0 0 0 0 0 0 0 0 440 0 0 0 0 0 28 0 3 2 10 0 0 17 3 FE B USAG E 0 0 0 2150 0 0 0 0 0 0 0 Z7S 0 0 0 0 4 6 96 0 0 21 0 0 34 7 MA R USAG E 4058 0 0 0 1600 0 0 97 0 1500 0 270 0 0 0 275 0 0 0 222 2 4 6 70 4 0 31 0 0 52 0 AP R USAG E 0 0 0 550 0 0 0 4530 0 0 0 0 50 0 0 0 600 0 0 19 2 46 0 0 20 5 52 0 MA

Y USAG E 0 0 0 950 0 0 194 0 4530 0 0 0 0 660 0 0 0 0 4 6 35 2 06 4 0 2B 5 52 0 JU N USAG E 4084 0 249 0 0 1100 0 192 2 291 0 0 0 0 0 880 0 0 0 0 0 38 4 60 8 0 28 5 52 0 JU L USAG E 2048 0 250 0 0 400 0 0 630 3 0 0 48 5 0 605 0 0 0 0 10 9 17 6 67 2 0 28 5 52 0 AU G USAG E 4052 0 0 450 0 95 5 0 0 0 0 0 30 0 385 0 0 0 0 9 2 28 8 64 0 0 28 6 52 0 SEP T USAG E 4084 0 0 0 200 0 0 582 0 0 0 0 30 0 935 0 0 0 0 9 4 22 4 9S 2 0 28 S 52 0 OC T USAG E 0 4096 0 0 100 0 0 O 0 0 0 0 715 0 0 0 0 10 2 32 0 96 0 0 19 0 34 7 NO V USAG E 0 4200 0 0 441 0 0 776 0 0 0 0 30 0 770 0 Q 0 0 0 124 8 32 0 0 10 0 34 7 OE C USAG E 0 1133 2 0

. 0 0 0 0 0 0 0 0 261 6 0 0 0 0 0 0 9 5 17 3 TOTA L USAG E 20362 0 9928 2 450 0 8036 6 192 2 2S70 6 10660 0 270 0 46 5 90 0 5990 0 261 6 0 622 2 62 5 513 6 556 6 62 0 218 5 502 7 

## ri I3INLB 9 LEGEND : GENERA L PURPOS E - G P ISOTHAJLI C - IS O FIR E FIETARDAN T- F/R VINY L E3TER-VN L TOOLIN G - TL G GRE YGELCOAT-G Y 0PTI0NALCOLO R = O P 1 to 1 0 

# 8

8 u ti. • 0

c o c oP.3 4



# APPENDIX B : FIEL D DATA/CALCULATION S

.3* >P.3 5

FILEVELVOL GAS VELOCITY AN D VOLUM E GE A Fabricator ! [LOCATION Rathdrum, I g STACKI D 

## TS Z tor . 093 0 | i 

# dare , ENTE R TIM E OPERATORRG RIDIA , IN . 

### mF T ARE A

### Et aREtf
. BUd K 2

4

Altitude Barom . Rea d 02 % WetBlbTmp 229

0 30 32 21.0 53.6 Alt . Cor

r Pbar.s U C02 % EstH20 % 

# —n r

27.9 1 0. 0 0 3 Amb . Temp P»,InH2 0 

### m% We tMol eW t 

# Tnr-" "

•0.7 79.0 28.76 ARE A • — Pa , Ab i . Dry Mo l W t Pito tC p 3.1 4

27.8 6 283 4 0.84 0 NOTE : INSER

T ORDELET E ROW

S FO RSAMPLIN

G POINT S fRuV W 3A I A 2 A 3 A. 4 A 5 A 6 A 7 A 8 3 1 32 33 34 3 5 3 6 B 7 38 BECTAT —

0.6 2 0.9 2 1.0 0 0.9 S 1.3 0 1.2 0 1.10 1.0 0 0.8 2 0.8 2 03 3 0.9 4 1.10 1.10 1.10 1.0 0 TSTAC K

7 7 7 7 7 7 7 7 7 9 8 1 7 9 7 9 7 9 7 9 7 9 7 7 7 7 7 9 7 5 7 5 4

5 

### s o 1 0 0 20 2 0 2 0 2 5 2 0 30 30 2 0 20 30 25 30 NOTE ; Enu eblan k Da u point

s O RInser t i s req' d i n©Sqr t arra y a tL1 6 .

AV G DELT A P MNSQR T D P AV G TEM PSTACK AV G T STACK

. AB S LO

W 0.997 6 77.9 537.9 

### U.1 (WB/DBDEL T •STAC KVEL , F/SEC FLO W RATE , FH/MIN FLO W DSCF/MI

N FLOWDSCF/HR 24. 3 58.7 0 11100 1010 0 60600 0 ACFM lALTCO R ANCL E CDIO X C P DI A DSCFM MNSQRT MNSQRT MNSQRT MOLDR Y MOLWET G3

5 D9 E16-E3 1 H 9 Dl l H1 2 H 5 G3 6 M3 2 L3 2 N3 2 H U F12 NITROGE Fi l OXYGE N PAB S PBA R PSTATI C PSTATI O T S TSAB S VELST K WATER WBULB TSAB S VELSTK WATER WBULB B U

H10 BI O 

### n o D1 0 D36 D3 7 03 4 D1 2 B1 2 D33 G3 0 D1 2 B12



# 3 1 +P.3 6

For m #M2-0 1

* 

## GAS VELOCIT Y AN D VOLUM

E DAT A FOR M
Plan t 

# &£k Dato 

# *(u hi 

# 1 T c ft. 

# - **\ Loutio i 

# m u l/Jlr^-. Ru n No . 

# W> Stac k I D No . 

# •c/ M
Stac k Dimension

Altitud e •VStifo-mmmZ-f 0 AU

. Corf , '!£&£?•' V' Ambien tTemp . 3 . £ C . Barometri c Readin g 1,01^ 2- Loca l Barometri

cPrettur

e l^"^-. ^ f Stac k Stati c Pressur

e 

# -.r 7 Molecula rWeigh t•*" 2-g , g> y Metho d g^f-?W< ^ Pito tC , 

# g~r V

•" Travers e >

- % ^ ' r

V

\ ?'«•Poin t '<•• , ^Number.' '

' 4 * " , 1 

## A/ f\ru Pt 3 

# A Y /V S 

# / U A 

# n
^ 

# fc/ 7 ~ " 5 

# 4 5 " 

# £ r ' 

# 2 !, \ - ? * - : V -^ ' ; £&"<

* -V^V^F*t d Data; - dt'l*:/^:^^<w^.v V

„ - 0 Vaiocit y> / . * - % V , f^HeadW,)^'\ ' " ' o >H,0 , -«<• ; ; 

# ufxx j f * w1 

## . ? * <.*t t M I& ).& 

## \*6 .J H .TO 1.0?. / . * 

# i.r 1. 3 l.X 1-OfT C %

Stac k -*• ; " VJe'mp.^ v\

;•

* •*<•' •^' S > -*. , 1 * >* *

Averag e Ap ,
Mea n Sqrt Ap , - 1 N ' * 5 N • £,\Cycloni c Flo wbetermfnatioaN.V/ V V " " - A

~ ' E > -Referenc e ^^H" ^

••

j

. Averag e Stac k Temp . •

" - • Averag e Angl e (o) '

' Averag e o f a mus t b e <10 » t

o b e acceptable . P.ev . 6/9 2



# ZSP.3 7

For m IM1-0 1 

## TRAVERS E POIN T LOCATIONS , CIRCULA RSTACK S Plan t&-&$- Qyv^^y-l.'lC'F«Lr'-c <ifo/is D« fg/2-fXf ? B y 

# K(hR Sampling^Locat/

n&dS T~j

iV-ORTH

C'.'• JmVnHtaf) Insid eo f Fa rWal l t o Outsid

eo f Por t(distance , X ) ityrf Por tDept h (distance . Y

) 

## rV/>4 Stac kLD . (distanc eX • distanceY

) Dist . to upstrea

m disturbanc

e Mn. If) '?/i,to.am6t.n " V 5 . I 

## Z,<f' f : Dist . t o downstrea

m disturbanc

e, ft/in . /V/f t•* Diameter

t$"& No . o f Travers ePoint s Roq'd: / /

Tota l gPe

rPor t 

# T ^ X • Y 

# I t -^~ \ 

## llY

. 

# Z S J ! Por t
SCHEMATI C O F SAMPLIN G LOCATIO N

1 Travers e Point Number ( 2 - 

### " 5 

### V 

# c / T ^ 

# £I;jj£i

Percen t o

f Stac k I.D . 

## ) \ Z . IO.$- 

## i?.*f •?2m.$ 

### £ * ; * # . / 

## z"?.<r fC^ 3

Stac k I.D . Inche s 2-/* * / 

# 7
/ / /



## _ i 

# i / /

t

. 4

Produc t o f Column s 2 and 3 (t o neares

t V a In. ) 

# V * *'/ , 

# v % ?*v It'/-* n*ys 2-/'/^ ?-3 'y<v ! 5

Distance Y 

# 4 /

' / / 

# A—. 4 / U 6

Traverse Poin

t Locatio n fro m Outside o

fPor t (su m o fcolumn s 4 and 5 ) 

## V y *.'/* . 

# </£ # iy* 

# n 

# >y / f ^ 21 / ^ 2. 3 > y / •



### Notes :

c ^ &For

m IStyrene l B o >J6 TWftiT E A66 WTHI S LIM E 

## STYREN E FIEL D DATA FOR M .Shee t No . of . 

## "a" t £<£./4
- Dat e &/ Z 6/4 3 I Operato rtf ft] Locatio n tf CLtf % ej-rysr^r. Ru n No . / Absorbe rTub eItP/jO'Z. 

## £ » Stac k I D A/~d%T

Ji 

# I Stac k

Dimensio n <L

- < / ° Mete rNo . ~/Q

HO Altitud e W*^Jh3 Barometri c Readin g Barometri c Pres . Stac k Stati c Pres . Alt . Corr .

-<S> , 

### -m& x 

### -2-i 3 2

_ 2~>.7 / 

# v /

V fl, N .. . 

### V 

# y Ambien t Temp . W B Temo . D B TemD . Moistur e Conten t .**\mS'



## N* 2- V 

# >r <v >r^ 0.<K«Z 

## NOTES : tfcUrY^

J^^H" 

# hoooy

Samplin g Tim e (min. ) 

### -o r 

## 5 1 (0 

### /< f Zso 

## JL£ L 

# 2°. UL 

# a°- 

# isz.

^ m
. & ' 

# hQ^_ ,;*•£ Cloc k

Tim e (2 4 hr. )
Star t 

# to**- JU mn\o---~iIQxi ifr 3 3 iOi*>ff \l>13 

# roil /0S6> 

# (l'0\ 

# JllLA Ge s Sampl e

Volum e (c O
Star t 

## &%*zme<5iH

c 

## \- c 

## i-T !5T?&f& -**-&&-& I

S-& A-Q^£&L

# s^-Ayfe 

# x&rfL. -3-*fr * 5£r&/~ j&jm&
=sc± 

# t&g 

# ^&u~ Sampl e Flo wRat a



## *?(,55-fr ms^A

• 0{62-'2-S •gZrS&Jc QUS.-zgQU .t t 0I73>*3D 417*. 7* Ot8f ,£T OIXH-VO 

# £>/U<60 OlfOm-S'


# n ^ w u - w.ssrl. Dr yGs s Mete r Outle t Temp

.

O> 0 ^. \ 

### a j •7&~ 

# <uf 0 6 •x i 

# 2H. 3£l 

# *7 l °4> M .2 2 3 

# k 2> 3 3N~ 7 

# 23L 28£- 

# 3& 3 / 

# i-

- ^
^ 

# 32
. «^37.. ? I y^zv.y v

Rw . 7/0 3P.3 9

FILEVELVO L GA S VELOCIT Y AN D VOLUM

E GE A Fabricator* ILOCATIO N Rithdrum , nf STACKI D l.'Wth ' apr . 090 0 1 OPERATORRG R" DIA . IN . 

### M6TE : EH M sfl kP

T AEE A 

### P6f

tRE6T . BUff l TIME 2 4

Altitud e Barom . Rea d 02 % WetBlbTm p 

### -T55 T

303 2 21. 0 57. 2 Alt . Coi r Pbar, at a C02 % EatH20 % 

# —n r

27.9 1 0.0 1. 0 Amb . Tem p Ps,InH2 0 N2 % We tMol eW t ap r75 •0. 8 79. 0 28.7 4 ARE A Pa , Ab t Dr y MolW t Pito tC p 3.1 4 2 7 JU 28.8 4 0.84 0 NOTE : INSERT O

RDELETE ROW

S FO RSAMPLING POINTS 

## m',\rimww-wmM*Km f 

## sAm,\i<]'* IAI
IA 4 A 5 A 6 A 7 A8 8 9 2 9 3 94 95 3 6 9 7 

## ba 0.7 4 0.9 8 0.7 6 0.8 8 13 0 13 9 1.40 1.1 0 0.9 0 0.9 9 1.1 0 1.20 1.6 0 13 0 1.1 0 0.9 4 7

7 7 7 77 77 7 7 77 7 5 7 9 7 7 7 5 75 75 75 7 3 75 7 5 45

S O 1 0 0 20 20 20 2 5 2 0 30 30 20 2 0 3 0 25 30 W6HS : Eras e Uan k Dat apoint s O Rinser t a s req' d in @Sqr

t arra y a tL1 6

AV G DELT A P MNSQR T D P AV G TEM PSTAC K AV G T STACK . AB S AV G ANGL E 

### i.m 1.0427 76. 0 536. 0 24. 7 WB/DBDEL T STAC KVEL , F/SE C FLO W RATE , FI3/MI N FLO W DSCF/MI N FLOWDSCF/H R 

## 1 I U 613 7 11600 - 1050 0 63000 0 LACF M LM-TCOR [ANGLE CDIO X C P 

### b U DSCF M MNSQR T MNSQR T MNSQR T MOLDR Y G3

5 D 9 E16..E3 1 H 9 Dl l H1 2 H 5 03 6 M3 2 13 2 N3 2 Hl i MOLWE T F1 2 NITROG E Fi l OXYGE N PAB S PBA R PSTATI C PSTATI O T S TSAB S VELST K WATE R WBUL B TSAB S VELST K WATE R WBUL B B U

H1 0 B1 0 

### n o D1 0 D36 D3 7 G3 4 D1 2 B12 D3 3 G3 0 D1 2 B1 2P.4 0

For m *M2-0 1



# 
 GA S VELOCIT Y AN D VOLUM E DAT A FOR M
Plant 

# Gtfr Dat e 

# gfelf?' * Operato r_ Locatio n' t vV*V H Ru nNo . 

# +Pr \ Stac k

I D N o cklpNo. . / Stac k Dimenti o 

## o-H V

Altitud e 

## ^1-1,0 Alt . Corr . "2- . T V Barometri c Reading "JO < 32— Loca l Barometri c Pressur e <^f-,^f( Stac k Static Pressure 

# *P>63r-,lS * - Ambien tTemp . *~>s- 

# z-rc Molecula rWeigh t 

## n^7Xm-*i Metho d C^Tr^cd- , Pito t C , 0.2 ? 4

SfTrayierit^ l ^Number ^ .•rfSv<:-<::«'5;.VivS : %,i;ri&r&%s!i. 

# A< •z. 3 

## 1 5 " 

# £ T f £( 2 . 3 4 5 " 

# G
* 7 * :;®SJ«SS??iye!oeity.«%?i.sssK 4 

# !S*iWW P

. ^ 

## .<rt f

. U . * * 

## /, 3 /. 3 t-H IA o^O 

## •? ? / ^ /.A N 

# /. £ A 3 A / 

# •fi ^*g?;5:-Stack:^:^ w

^ ; 8x^#S|J" : ^^P*S . .& iJ&X&ffi£f\i&g*&$. ^|l:^P*iS^E#:S|

. 

## £ 4 6 3 • / 3 

### AH UH 

# 0 WIT* CH 6>H.s-

## &H.SfaS~zs-'S6>Sr£~ 

# tsr 6<r 

# t>s~ Averag e Ap .
Mea n Sqr

t Ap , 

# /•om v ^Wte fliff&Cycloni c Flo wDeterrrune t on^*^»Mfe'5:^^ : - 

### *p|g^lAp*i>j^^®ii ^ 

## ^.5- ^-,5 " -./ # 

## n

. 3 , 7 ^



## . 7 ./< / 

# -. r -.£ - • * ? -, £ 

### •^-. - 5 * I.O /.&



## . 7 

# .t f Averag e Stac k Temp . j&sxss * Angl e (olYielding-:S:i:?S . 

### i^^^,*Nv.n.^^.^i^^ : 

## ^5 ° DO* 

# ho° n *o° 2,0° -hO° 

# 42S* 2 ^ ° 30 ° 3<f> " X ^ •So' 3D* a^ » ^ 0 * Averag e Angl e Co) 1

1 Averag e e fo mus t be < 10o t o be acceptable . 

# 3? Rev . 6/9 2For m #Styrcne 1 b o N6 TVVAITE AOOV E THI S UN E 

## STYREN EFIEL D DATAFOR M Shee t No . o f 

### Plan t Cfch Dat e g/ g 6/ 7 3 Operato r(£ M Locatio n 

# fc^UA ^U»^v v Ru n No . 

# S k Absorbe rTub eIDdS,Q( - Stac k

I D / /Lf*/tff\ Stac k Dimensio n / ?v l | ' * Mete rNo . 7<pf< 9
Altitud e ^aSri^ff i Corr . Eg$ £ Z ' H( Barometri c Readin g Barometri c Pres. Stac k Stati c Pres . _ 

# ^m?-

-o.-KT Ambien t Temp . W B Temo . D B Terrm . Moistur e Conten t 

## "U - 7« T



# /ve.
' -2 - 2 . " ^ I.OKt?. 

### NOTES: />/ £f£ rY*

/ ' ^ ^ ^

\ > * ' 

# K \ 0

J* ^ •o* * Samplin g

Tim e (min. )


# Mr i2.*s > i('^' : 7L5 " 

# i o 

# .M : 

# 4 o H£T <T< ? 

# 53 " £0_ Cloc

kTime {2 4 hr. )
Star t 

### lt-d>X 

# ir-37 •sjmo i.'-ix .XCO*65' 

# tl€l f-X'-OX^ \Xo1 

# ^IX 1Z'32
_ 

# \x:xl \-3X Ga s Sampl e

Volum e (cf )
Star t 

# *<K<rf&mi. D '^nrrt^L^fo
$&r6&-3& 

# m&u^-* 1 M 7 •9&7&%o r



# - *D <.DH*± &*&&}{• **&***& Sample Flo wRat e



### 0tiV f 

### FO

OZ&S.tjT t^&&k&-&xt> c 

### i. fo 

## ^^€[&rh.O^.^JO



# -ex\SJ5 'O^A'isXS 

# g?a^l. 3 0**4.3 5 

# o-x.'&'HS' tmr't ^3^.y r Dr yGa s Mate r Outle t Temp . ' 

# i

. 1 

# 31 32^ 22.

* 

# s r sC-* 

# 1 ^2. ^ 3 i 

# a •x< £ 

# l i

^^C^^tan M 

# SSII^S L 

# 3£ 2dL 

# JE 3^5 " 

# 3 & 2LlW\^k. 2>{,6 2>6.S 

# o

Z i T O

O O £ > o 

# <o
< ?

& 

# ?v go *

K Rev . 7/9 3FILEVELVOL OA S VELOCIT Y AN D VOLUME P.4 2

ricators ILOCATIO N RithdrnmHE T STAC KI D 1,'North ' RG RDIA . IN. 2 4

Altitud e Barotn . Rea d 02 % We tBi b Trap 229 0

303 2 21. 0 57. 2 Al tCor r Pbar . s U C02 % E»tH20 % 

# —n r

27.9 1 0.0 1. 1 Amb . Tem p Ps,InH2 0 N2 % We tMol eW t "apr

W •0. 8 79. 0 28.7 2 ARE A Ps,Ab e Dr y MolW t Pito tC p TIT ZULU 28.8 4 0.84 0 NOTE : INSER

T O RDELET

E ROW S FO RSAMPLING POINTS A l A 2 A 3 A 4 A 5 A 6 A 7 A S 3 92 9 3 9 4 3 5 36 B 7 B 8 DELTA P 0.9 2

1.05 1.1 5 0.9 8 13 0 1.4 0 1.4 0 U O 1.1 0 1.0 5 1.1 0 13 0 1.8 0 U O 1.40 1 3 ti\tAtH



### 1i 7 9 7 7 7 7 75 7 7 75 77 7 7 7 7 7 7 7 7 7 7 7 9 7 5 7 5 A?!<5CE

1 

### ii 50 10 0 2 0 20 2 0 25 20 30 3 0 2 0 20 30 2 5 3 0 j in k

Dat apoint s O Rinser t a s req' d i n @Sqr t IL1 6

AV G DELT A P MNSQR T D P AV G TEM PSTAC K AV G T STACK . AB S AV G ANGL E 124 1 1.109 7 76. 6 536. 6 24. 7 WB/DBDEL

T STAC KVEL , F/SE C FLO W RATE . FT3/MI N FLO W DSCF/MI N FLOWDSCF/H R 19. 4 65.2 6 12300 1110 0 666000 ACF M ULTCO R (ANGL E CDIO X C P DIA DSCF M MNSQR T MNSQR T MNSQR T G3

5 D 9 E16-E3 1 H 9 Dl l H1 2 H 5 G3 6 M3 2 13 2 N3 2 MOLDR Y Hl i MOLWE T F1 2 NITROG E Fi l OXYGE N PAB S PBA R PSTATI C PSTATI O T S TSAB S VELST K WATE R WBUL B TSAB S VELST K WATE R WBUL B Bi l

H1 0 BI O 

## n o D1 0 D3 6 D3 7 G3 4 D1 2 B12 D3 3 G3 0 D1 2 B1 2



# 4-1P.4 3

For m /TM2-0 1 

## GA S VELOCIT Y AN D VOLUM

E DAT A FORM
""<«• * 

# ° " rW*7 3 Operato r_ •. Locatio n ' . Ru n No . ^ Stac k 1 0 No . . . . 

## 'A/^Um- -L. Stac k Dimensio n
Altitud e<233£ - "T-z^bO Alt . Corr . ffcw'Z-.V / Barometri cReadin g^ 0 1 2 2

— Loca l Barometri cPressur e"2 . 7 ' « f Stac kStati cPressur e"" " #I * Ambien tTemp . 0^ £ C Molecula rWeigh t"^ X g \# y Metho d €^3t^Uutf^ 

### Pilo tc , (P.^ y •••

.

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## n o D1 0 D3 6 D3 7 G3 4 D1 2 B1 2 D3 3 G3 0 D1 2 B12



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## GAS VELOCIT Y AN D VOLUM

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# e&~P.5 4


## BISO N ENGINEERING , INC . ENGINEER S • SCIENTIST S • PLANNER S

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# BISO N ENGINEERING , INC
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# ^A -P.5 6


# BISON ENGINEERING , INC
. ENGINEER S • SCIENTIST S • PLANNER S
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# BISO N ENGINEERING, INC
. ENGINEER S • SCIENTIST S • PLANNER S

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# BISON ENGINEERING, INC
. SCIENTIST S • PLANNER S P.5 8

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_ OBSfMERJSSIQNATUREY/^ / 6 

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/*„*,*- >

r C IDi 9£fS £ rU-o\

t fce€^y^}
& • *P.5 9 

# OLI \
DYNAMI C FABRICATOR S Thermal-Dynami c Coolin g Tower

s Augus t 27 , 199 3 W . 173 5 Hwy . 53 . Rathdru m P.O . Bo x126 5 Pos t Falls , I D 6385 4 Phon e (208 ) 773-178 7 FA X(208 ) 773-420 5



### Mr
. DavidKinghor

n BisonEnginering , Inc
. P.O
. Bo x 170 3 Helena , Montan a59624 Dea r Dave , Ihav e writtenaproductio nsummar y repor t noting the condition s andmethod s usedincollecting th e necessar

y produc t usag e datafo

r th e sourc e testing
. Ihave enclosedth e six origina l lo g sheet s along wit

hth e AP4 2 handbook

emissionfactor

calculation s for

eachstack

during th e thre e tes t runs . If yo uhav e an y question s regarding the data , summar y o r tes t conditions , pleas e giv e m

e acall
. Sincerely ,

JohnL
. Krisma

n Facilit y Manager

Enclosure s

cc : To m Glasse n

•r-i.r-i.r ^ CiT * I I EHEEB S GE K-Grou p Energy- , Environment- , Proces s Technolog y 

# B€1 

# APPENDI

X C : OPERATING

USAGE S DATA/RAW MATERIA L

4 , P.6 0



# £9is 

## J_

. 08/26/9 3 

# GEA/THERMA L DYNAMI C TOWER S 199 3 STAC KEMISSIO N SOURC E TES T MANUFACTURE R NAM E i PRODUC

T RESI N G P REICHOL D 0**jL1~ RESI N IS O REICHOL D RESI N F/ R DIO N GE L COA TGYREFCO

A GELCOA TO P REFCO

A PERCENT

STYREN E 35 % 45 % 45 % 35 % 35 % LB S PE R

INC H

## /sjrSTAR

T READIN G S US
- TIM E

STAR T IOAO EN D

READIN G 2 7
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LB S Z7./2.6 "

USAG E I S I N LB S

AREA TEST# LEGEND : GENERA L PURPOS E = G P ISOTHALI C = ISO FIR E RETARDAN T= F/

R VINY L ESTE R = VN L TOOLIN G = TL

G GREYGELCOA

T« G Y OPTIONA L COLO R = O P 

## 4^Z^ 

# I >ERSON MEASURIN G Ow*-^
-



# Lop6/-J-^/I !*L J t i ) 

### 08/26/9 3 

# GEA/THERMA L DYNAMI C TOWER S 199 3 STAC KEMISSIO N SOURC E TES T 

### MANUFACTURE R NAM E •%PRODUC

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# fr \ 

### LEGEND : GENERA L PURPOS E = G P ISOTHALI C = IS O FIR E RETARDAN T= F/R VINY L ESTE R = VN L TOOLIN G - TL G GRE YGELCOAT= G Y OPTIONA L COLO R = O P 

## ARE A TES T # 

# I PERSO NMEASURIN

G Qer^JlS. -ACkJbuA^^ 0/1 .



# ^

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08/26/9 3 

# GEA/THERMA L DYNAMI C TOWER S 199 3 STAC KEMISSIO N SOURC E TES T MANUFACTURE R NAM E & PRODUC

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# niztr

USAG E I S I N LB S



## N i LEGEND : GENERAL PURPOS E = G P ISOTHALI C = IS O FIR E RETARDANT= F/

R VINY L ESTE R = VN L TOOLIN G = TLG GREYGELCOA

T= GY OPTIONA L COLO R = O P AREA TEST # PERSO N MEASURIN G Q^/^l»—--_ ^



# bjf 

# facM?L.a... . .. J


## 08/26/9 3 

# GEA/THERMA L DYNAMI C TOWER S 1993 STAC KEMISSIO N SOURC E TES T MANUFACTURE R NAM E & PRODUC T RESI N G P REICHOL D /3<*.fc*2
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### USAG E I S I N LBS



## 5 ^ I N LEGEND : GENERAL PURPOS E = G P ISOTHALI C = IS O FIR E RETARDANT= F/

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# 2 — PERSO N MEASURIN G 

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### 08/26/9 3 

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ISAG E I S I N LBS LEGEND : GENERAL PURPOS E = G P ISOTHALI C = IS O FIR E RETARDANT= F/

R VINY L ESTE R = VN L TOOLIN G = TLG GREYGELCOA

T= GY OPTIONA L COLO R = O P ARE A (EST# 

# 3 !-'EPSO N MEASURIN G 

# ^LLl^Arr /) ^2'*r^ A~8

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### 08/26/9 3 

# GEA/THERMA L DYNAMI C TOWER S 199 3 STAC KEMISSIO N SOURC E TES T 

### ! MANUFACTURE R NAM E j&PRODUC T ! RESI N G P REICHOL D fontWH ! RESI N ISO REICHOL D ; RESI N F/

R DIO N (GE L COA

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### ARE A

# KmM

1^/ TEST# J 5 PERSO N MEASURIN G ^ Q(M* - 

# \fSrt* 6~f <*^t-*S

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# APPENDI XD : LABORATOR YDAT A WIT H CHAI N

O F CUSTOD YFOR M

£/ ;I-iv. .

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## ENERGY

/ ENERG

YLABORATORIES , INC

. LABORATORIES

TO : ADDRESS : P.O . BO X3091 6 * 110

7 SOUT H BROADWA Y•BILLINGS . M T59107-091 6 •PHON E (406 ) 252632 5 FA X(406) 252*06 9 . 1-800-735- 4 48 9

Rober t Richard s Biso n Engineerin g P.O.Bo x170 3 Helena , M T5962 4 LABORATOR YREPOR T 

## \*E D 199 3 LA B NO. : 93-38796-80 1

DATE : 09/08/9 3 d a
U i O 

## QH

CHARCOAL TUB E ANALYSI S Proj

. No

. 93080 , GE AFabricators-Fiberglas s Prod

.

Sample d 08/26/9 3 Submitte d 08/27/9 3 Analyze d 08/27/9 3

La b No

. 93-3879 6 93-3879 7 93-3879 8 93-3879 9 93-3880 0 93-3880 1 Blan k Identificatio n

Stac k 1 , "North " Ru n 1 Stac k 2 , "East " Ru n 1 Stac k 1; , "North " Ru n 2 Stac k 2 , "East " Ru n 2 Stac k 1 , "North " Ru n 3 Stac k 2, "East " Ru n 3 Charcoa l Tub e Lo t 12 0 SK C #226-0 9 Styrene , mg/Tub e Fron t Correcte d fo rBac k Tube 11 1 Desorptio n Efficiency 12 1 Tub e 9.4 2 10. 0 <0.003 0 6.0 0 6.3 7 < 0.003 0 5.5 2 5.8 6 <0.003 0 6.9 9 7.4 2 < 0.003 0 7.1 7 7.6 1 <0.003 0 7.7 1 8.1 8 <0.003 0

vN/ AN/ A <0.003 O 

# V

"Tw o SK C catalo g #226-0 9 charcoa l tube s wer e expose d i n series

. Th e tube s wer e lo t #12 0 an d containe d 40 0 m g o fcharcoa l i n th e primarysectio n an d 20 0 m g i n th e backu p section

. Bot h primary an d backu p section s o fth e firs t tub e i n th e serie s wer e desorbe d a s one . Onl yth e primar ysectio n o f th e 2n d tub e i n th e serie s wa s desorbe d t o chec k fo rbreakthrough

. '"Th e desorptio n efficienc ywa s calculate d fro m th e averag e recover yo fthre e charcoa l tube s fro m lo t #12 0 spike d wit h 6.00 0 m g o fStyren e pe rtube

. Th e averag e recover ywa s 94.2%
. Analysi s don e b yNIOS H Metho d 1501
. 

# 1

\ 0\C\ LP,P.7 0 

# ENERGY I AB ORATORIES ENERG YLABORATORIES , INC . P.O . BOX3091 6 •110 7 SOUT H BROADWA

Y. BILUNGSTM T59707-O91 6 •PHON E (406) 252-632 *

FAX(406) 252-606 9 . 1 -80073 5 448 9 CJ:-
- •r * "t- i

:'j J J 

### LABORATOR

YREPOR T TO : ADDRESS : Rober

t Richard s Biso n Engineerin g P.O

. Box170 3 Helena , M T5962 4 LA B NO. : 93-38796-80 1 DATE : 09/08/9 3 d a

QUALIT YASSURANC E DATA

Identificatio n Blan k Spik e # 1 08/27/9 3 Blan k Spik e # 2 08/27/9 3 Spik e Adde d Styrene , uo /Tube 50. 0
50. 0 Spik e Recover y

Styrene , //a/Tub e 52. 2
59. 1 % Recovery

10 4
11 8



# 6-9P.7 1


### Repor t Dat e : 31-Aug-199 3 11:3 0

Star t Ca l Dat e En dCa l Dat e Quan t Method Ca l Curve Typ e Origi n Targe t Version Integrato r Metho dfil e Ca l Dat e 

# Ihv-Ho l ColiVofco n -fo rTub e fWxtys( < RECEiVc D Pag el 

# SE P A 0 199 3 Energ y Laboratories , Inc . BISQi M INITIA L CALIBRATIO

N DAT A 27-AUG-9 3 08:4 9 27-AUG-9 3 10:3 6 EST D Linea r Forc e Targe t 2.4 0 H P RT E /disk3/svdata2/082793.b/Styrene.ra 27-Aug-199 3 11:4 0 Calibratio nFil e Names : Leve l 1 : /5970/chem/msd.i/082793 , Leve l 2 : /5970/chem/msd.i/082793 , Leve l 3 : /5970/chem/msd.i/082793 , Leve l 4 : /5970/chem/msd.i/082793 , Leve l 5 : /5970/chem/msd.i/082793 , b/27Aug0l01001. d b/27Aug0201002. d b/sty082793. d b/27Aug0301003. d b/27Aug0401004. d

Compoun d 1 Styren e 2 | 5 | 2 0 | 5 0 | 10 0 | | | Leve l 1 j Leve l 2 j Leve l 3 j Leve l -, j Leve l 5 j RR F j xRS0/R A 2 j s s I ssssssss s I ssssssss s | csssssss s | escsssss s | sssasnas i | sssassus a I 172547 | 178658 | 162753 1 U9333 | 126781 1 133223 1 0.986 | 

## I I I I I I I



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27-A0G-9 3 tj p i . Styren e 2ug/m l BN AQUANT RATI O REPOR T /082793.b/27Aug0101001. d

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Sampl e Matrix : CS 2

/5970/chem/msd . i/082793.b/Styrene. m 27-Aug-199 3 11:3 9 27-AUG-9 3 09:2 1 Ca l File : 27Aug0101001. d 1 Calibratio n Sample , Level : 1 1.00 0 Targe t Version : Targe t 2.4 0 H P RT E Compound Sublist : all.su b

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# •44Dat a File . . 5970/che«/(wd.1/082793.b/27Aug0201002. d

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Dat a fil e Lab . Id . In j Dat e Operato r Sm pInf o Mis c Inf o Commen t Method Met hDat e Ca l Dat e Ai s bottl e Di l Facto r Integrato r Sampl e Matrix : WATE R Energ

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### Dat a File : /5970/chem/msd.i/082793.b/27Aug0301003. d Repor t Date : 27-Aug-199 3 11:4 0 Pag e l

Dat a fil e Lab . Id . In j Dat e Operato r Sm pInf o Mis c Inf o Commen t Method Met hDat e Ca l Dat e Ai s bottl e Di l Facto r Integrato r Sampl e Matrix : CS 2 Energ y Laboratories , Inc . * 

### BN A QUAN T RATI O REPOR T /5970/chem/msd.i/082793.b/27Aug0301003. d Quan t Type : EST D 27-AUG-9 3 10:0 9 Autotun e Date : tj pIns t ID : msd. i Styrene 50ug/ml /5970/chem/msd.i/082793.b/Styrene. m 27-Aug-199 3 11:4 0 27-AUG-9 3 10:0 9 Ca l File : 27Aug0301003. d 3 CalibrationSample , Level : 4 1.00 0 Targe t Version : Targe t 2.4 0 H P RT S Compoun dSublist : all.su

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Dat a fil e Lab . Id . In j Dat e Operato r Sm pInf o Mis c Inf o Comment Method Met hDat e Ca l Dat e Ai s bottl e Di l Facto r Integrato r Sampl e Matrix : CS 2 Energ y Laboratories , Inc . BN A QUANT RATI O REPORT /5970/chem/rosd . i/082793.b/27Aug0401004. d Quan t Type : EST D 27-AUG-9 3 10:3 6 Autotune Date : tj p| Ins t ID : msd. i Styren e lOOug/m

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### Energ y Laboratories , Inc . BN A QUAN T RATIO REPOR

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Yi s obtaine d fro m pos t tes t mete rcalibration s show n i n Appendi xE

. 2
. Wate rVaoo rVolum e - Correcte d t o ST P (4 0 CF R 60
. ADD

. A

. Eo

. 5-2 )



# *~-'-ft)ffi? )

Note : W t e 

### = V t e 

### p w 

### 3
. Stac k

Ga s Moistur e Conten t (4 0 CF R 6 0 App

. A , Eq

. 5-3 , modified )

fl.. - f

v(sttn wa 

### v + v

4
. Stac k

Ga s Dr van d We t Molecula rWeigh t (4 0 CF R 6 0 ADD

. A

. Eo

. 3-1
. 2-5 ) M , = 0.44 0 (%CO,

) +0.32 0 (%0, ) +0.28 0 (%i\7 2

### + %CO)

M t 

### "M d

### (l-B vs 

### ) +18 . O B ws



# I ?P.5 5



### 5
. Averag e Stac k Ga s Velocit y(4 0 CF R 6 0 ADD

. A

. Eo

. 2-9 )

v.-JCC . p~p 

# Evs p

7 2 T

tUr-g) 

## N p

## sMs

6
. Averag e Stac k Ga s We t Volumetri cFlo wRat e

O. = 60v,A .

7
. Averao e Stac k

Ga s Dr vFlo wRat e Correcte d t o Standar d Condition s (4 0 CF R 6 0 ADD

. A

. Eo

. 2-10
. modified )
O.ed-O . (l-B„, ) T 9td 

### P.
r *(«vy ) Pstd



### 8
. TS P Particulat e Concentratio n Correcte d t o Standar d Condition s (4 0 CF R 6 0 ADD

. A

. EQ

. 5-6
. modified )

m K 

### C a 

### =2.205X10-*-—-2 — * J * V

_ __ .
3 __?!__

_ 

### C. =15.43x1 0 „ a(std)


### Note : C i b 

### = Ib/dsc f C iQ f

### = grains/dsc f m n 

### = m g



# '/S4 -P.5 6



# f l 9
. TS P Emissio n Rat e pe rHou r 

### £hr a 

### c.0, t d

### 6 0

10
. Percen t Isokineti cSamplin g Variatio n (4 0 CF R 6 0 ADD

. A

. Eo

. 5-8 )

+ mtmtrrr\ ".mlafitt

* ___•/

* 10 0 

### I % = l <r,arg) vm[Btd) r0td 

## r.«i*-. e V.6 0 (I-B„ )



# i<55P.5 7

- I 

# NOMENCLATUR E Stac k tes t standar d conditions : Pressur e - 29.92 " H g Temperatur e - 68° F A n 

### Nozzl e cros s sectiona l area ; ft 2 

### A , Stac k

cros s sectiona l area ; ft 2 

### B M 

### Wate rvapo ri n th e ga s stream ; volum e proportio n C , Concentratio n o faceton e blan k residue ; mg/ g C p 

### Pito t tub e coefficient ; 0.8 4 fo rtyp e S pito t tub e C , Concentratio n o fstac k ga s particulates ; dr ybasi s correcte d t o standar d conditions ; Ib/dsc f(pounds/dr ystd

. ft 3 

### ) o rgr/dsc f(grains/dr ystd

. cubi c foot ) D s o 

### Aerodynami cdiamete ro fparticle s wit h 5 0 percen t probabilit yo fcyclon e

penetration ; p E ^ Emissio n rat e pe rhour ; Ib/h r I Percen t samplin g rat e variation , wher e 100 % = idea l isokineti c

condition s K D 

### Pito t tub e constant ; 85.4 9 ft/se c(Ub/lbmole) {"Hcf)

\

m . Aceton e residu e weigh t afte revaporation ; m g M d 

### Stac k

ga s drymolecula rweight , fro m Fyrit e o rOrsa t analysis ; Ib/lb-mol e m f

### Filte rweigh t gain ; m g m „ Tota l weigh t o fcollecte d particulate ; m g

m 

### n . PMI O 

### Tota l weigh t o fcollecte d PM 1 0 

### particulate ; m g M w

### . Molecula rweigh t o fwater ; 18. 0 lb/l b mol e M , We t molecula rweigh t o fstac k gas ; lb/l b mol e


# nP.5 8

- •

•• '

J l T

- -

•"

. - J

- Pb .



### P , P . P« d 

### Q . Q.t d 

## T „ t . ^"•(•vg ) 

### T. t d 

### R 

## v t e 

## v m
V m ( t t d )



### v . V w («td |


## w k 

### Y A p 

# S T V. Barometri c statio n pressure (a t samplin g site) ; in . H g

Stac k stati c pressure ; in . H 2 

### 0 Absolut e stac k

pressure ; in . H g Absolut e pressur e @ standar d conditions ; 29.92 " H g Averag e stac k

ga s we t volumetri c flo wrate ; cf m (ftVmin ) Averag e stac k

ga s dryvolumetri c flo wrate , correcte d t o standar d conditions ; scf m (drystandar d ftVmin ) Averag e dryga s mete rtemperature , abs. ; ° R Averag e stac k

ga s temperature , ° F Averag e stac k

ga s temperature , abs. ; ° R Absolut e temperatur e @ standar d conditions ; 528° R Idea l ga s constant ; 21.8 5 in . hg-ft 3 

### /°R-lb-mol e Tota l volume s o fwate rcollecte d i n impingers ; m l Indicate d volum e ofga s sampl e measure d a t dr ygas meter ; de f(dryft 3 

### ) Volum e o fga s sampl e measure d a t dr yga s meter , correcte d t o standar d conditions ; dsc f(drystandar d cubi c feet ) Stac k ga s velocit yfro m Metho d 2 Volum e o fwate rvapo ri n th e gas sample , correcte d t o standar d conditions ; sc f(standar d cubi c feet ) Weigh t o fcollecte d water ; g Dr yga s mete rcalibratio n facto r Stac k velocit ystagnatio n pressure recorde d b yth e probe' s typ e S pito t tub e Averag e pressure differentia l acros s orific e mete ra t contro l bo x Stac k ga s absolut e viscosity ; p poise 

# is vP.5 9



## i 3 p w

### Densit yofwater ; 0.998 2 g/m l (0.002 2 lb/ml )

6 Total samplin g time ; min . 13. 6 Specifi c gravit yo fmercur y 

### 6 0 Second s perminute



# -|S 8u a u t n o i n t« t i« i ^ ^ ^ -.*---....
. .._^_»._N
. -N , ••

_•• * * \• - -- • - - —?•

- --w ^ .*._•

__^
. A._^
. .«

_•-_ , *_ , .|. M 1 8 "M M 

# PSYCHROMETRI C CHAR T NORMA L TEMPERATURE S

S I METRI C UNIT S Baromatrl c Pratsur a 101.32 5 kP a SE A LEVE L R«p«odue*4 b yp*rml__.o n ofCtili Corporation .

I l l tal—a 0* C frafwil n taxi

C.llnf. fClub . Ita m «>• . M I n O i l Of ftal k )•*?«___•• » I t I M mprnttmr*

C \

•I I Valam. ml/k , Or

r« k \ t M C*r*+t

Otmaaaa

Clfaaai—

ttt% 

## Figur e 23. 2 Psychromctri c Char t b >

### ur^-s j uj:*or w riui urii:&\j i LAJ_6, ' 

### _W
. 

## » 0 144 ^ 66 53 P.6 1 

## fuo3/0'J 3 

# SK C Gwuf et o NIOSH/OSHA AirSampling Standards 

# 1 

# 1

I :

. \

\ \

t ptrntutruman l^iO-PM"******- * tajnfrrtKrtaK&x*'** SSTIM-T***-»PMI 4 *w w(S M Cur

t M tot

f*nsnHi

Hmatet) Saart** M W "six * CipfjfMf l 50*W" I -tsoda-tten- M "Sneonioa i (S M Arurwopfett e Orugj ) ?|-m « sue-* * Sl* « S*t*«« « STf-ra SOrfKtCrtJ t ^•OtP^n^CY*** ) Saoeu M (Pieue-yt

xEurmn i SMC-U < (S M Ou t Too

/ cr Piient u

ttuiw-a) Sutttn l *__d_-.a

_ Stfoacr * StJUM-TOO M Sutor**6< M i A * Oiovct

SufclB-nd t juftu-Cfeic a SJl s Octet . SJ*I:I VA StAti s S<_r u Htutund * UteHtuAue-i M SO-tUonecrSv- M Su*__rPin_ftar< i SvhrTrriNon M SurtgneAe

d StMfsM d SiftreAo d SufcreAc d SttftrteAedUr . Sttey i r«gna » SA«y<FV«rd t s.mi(SMO«i_Hci ; SAST 2_«i- T To e .F U •*»•*»» ) 10 c (RttoiraCat . Non-AMUIM.il ) Tt e (Tea. . *an-A£«*lilQ-m | TMW I Truni n Tuaua . tmt . Over

Oo a T U (S M Z«-rotMn>M&ae)«nM | no * Trto n c-wo*r«eirte n Paoue* * (S M Ptiytmbn* Ttkn- a T-Anj- k Ttfenu o Ttt_c__n » HmAmid t Ttteu n Huift-viO * ( u T« | T V * TMOUB O o-T_/*___n» * Tirprmi n T_-fA.«yl» . Myd-BCVUt M

• ' *.-;*i--»7 1 ;f.'M-*'»'';'.«-"- ^ Ao4*io ^ l*ol*pr*tf W OSH A USSE B

OSH A M$22 Q
OSH A MISSU S NOS H K M OSM A vsatt MOS H IS W OSH A a
OSH A MSS10 0 MOS H Mi l OSH A M3B7 t OSH A I t OSH A t MOS H MO D MOS H 150 1 CSH A wisrcs OSH A 0_&2S S OSH A MSSIO * OSH A USS10 7 OSH A MSS12 7 OSH A mssza OSM A tWSSl M MOS H 41SXI )

OSH A S10 4
OSH A ©10 7 MOS H K0 4
MOS H KS244 ) OSH A IA323 M OSH A 0*2.2 0 OSH A WS1V. OSH A IMIS2322 NCS H 1CS1J4

) N-OSM 79C

S OSH A OI1 3 OSH A DICS M NIOS H 1(117

) NIOS H KSJ« ) OSH A MSZ__ 9 NSS H $00 1 OSH A MS32 4 NOS H » J OSH A MS903 0 OSH A IWS_<_-

t OSH A OISTI1 7 MOS H STSM1 ) OSHA MS2J2 S MOS H OO M MS212 7 UIJ4W / MOS H 7(S30t | MOS H 7300 OSH A c m MOS H «S1|7 ) OSH A MISO B OSM A MSS3 4 OSH A 146333 3 MOS M K3 1 OS M w-cm s OSH A MIS141 S XCS M l!S2T ) —r-z—:— • T^T-.

. ,- • S A M Aime r*•«-*•* « TW A Unix, m m ) (ee<- )

0. 1 33 0 oVn - 100 •

0. U nViTt

M 10

0 ST U i o io o s m
SO 10 9 Jtcgm'STE l

t i * t l *

3 SSTe l

I SSTS . O i

| 100 0 • .01 C.1
1 W]F(rT i lAQilYr lugn-r * 1 ISSTr . 3 1 0 ST C

1 0 nj*** * zBQIM r Ifnym l

mew Sa->M > OJ-VK 0. 1 RtM 1 J l J9«tm >

e i
1 P L VU.-OTM . mACoiix j 1 0

4 1 a 1 0 1 2 • 4 H I N 1« 0 1 2 0.7 3 1 0 3 1 0 1 0 1 0 41.000 t o N 10 0 t o

< 0 I S
2 4 3 I M 3 4 S S '. H

- M 0 M
• 0 3 2 4 U
11 9 IC S 17 1 7S t M O K IC O S! 0 •n o 723 72 3 M 0 4 M 4tO 41 0 < M 3 0 u I S 1 N G nll l (•RlwilH p IWACtWn a KCS0 I

20 0 to o 20(50 ) 20 0
1CC 0 130 0 300 0 » 2o;to i 2 3 NIM ) < o 2C 0 1009 K U » 1000 IOOO ice o
1C0 0
te n
K 0 •.to o 2 0

130 0 20 0 20C 0 250 1CC 0 I * 10 0
100 0 300 0 1K 0
It** }
2C0 0 ICO O 1S0 0 3oo e
100 0
2S0 0 xo o 2SO 0 100 0 IOO O 100 0 •oc o 20 M

' 10 M

2C 0

tu o Tta

w TW A CtfHn t (too l (mlA I «)J )

4 4 W J ! 1 1 2 U I S Kil l I S 1 e,-3j | i o

M 2 l i l i
1. 3

1 1 3
2 1 3 1
1 S 1 100 0 I ! 2 4 « « li s 10 0 4 1 3

l i

1. 1

I I

1 7 IX C l*_r_

n i 1 3 AMt)-Uc« l Uta- M oc-n o

NV W NV V c m O K CCF O OC-fT O AA S i-n c KKC-I W GC-n o CO W 0C-F » ecro CJ I H".C-U V nn c •OI C HHC-U V m. c T1TR A

c e • c OCT C « » c NVI4 S7IE C TITS A e c C- J CC-F W 5 = MPIC4JV HW.C-U V I W G R e x Of l PE S G R GOT O A A CP-AC S A A A A A A GO^P O | FFO oc-no G C | NV M 1 C C

. S. M • K C CtlKcUn * l«ulp>OOT l «w l P»fl l Minta r

R.TI2S- 7 ST22f) J

8TOt-lM 2 i'rat-iiM i ST22S4 1 ST22W 1 aT22!< 9 FVTm- 7 wns- 7 S T221-7 1 5T2»4 t S Trt-13- N S T221-3 1 NASX C FI T225- 7 FI_TI»- ; aras- r HT.23- S •ipns-st- i SCN22.- M R.T22S- I (MP22S-3l-t ST22S4C ' aTai s Kl022H a soa'-as NP22M*- ! WP223-X- 2 r w T22S- S S7*3t-'0 a R.T2J M ST22S--.C43 M P 133-31- 1 S B 231- 3 sr-m-i t RT22S- 7 R T223- 7 aTZH-t- a HLD23t 4 aras-i-o i aoj-H- i ri.T22t-M 1 H.T22J-7 RT2-H- 3 aT22M-0 l ST22t-3C-: i F1.T22J- J FVTIB 4 r.T32t- i S T221-1 1 ST22M I ST22M0- H S T2H-JO-1 4 R T123-11-0 7 SP C 223.2 1 aT2_S- 7 araj- s 34

17-i l

27-2 1 27^ 1 v-a 27-2 S
34 1 4 1 4 jf- a i7- n 27-2 t 27-2 1

1 4 3 4 34
3 4 3 2 1 7 3 4 1 2 27- a 34 34 4 2 3 1 3 2 3 4 27-2 1 34 27- a 3 1 a IT- H 3 * 34 34 3 4 34 3 4 1 4 3 4 3 4 94 27- » 3 4 34 34 v-a tf-» 27- 0 17-2 1 3 4 V 3 4 * HI D Mi l

H022S- 1 H.02S- 3 R022S- 2

HU ) 223-2 W.032S- 2 hlDJ-f H NL9U M I T223-22 M.022S- 2 I T223-1 2
RT22S-II 0

IT223-22 IT223-23 H O Si- ) I U 233- 2

* T223-2 2 S I 212-0 3

HL O 233- 1 H O 223- 3 F/XU3 223- 1 CTCJH-01- a FM.022S- 1 CYC223-0l-* 3 H O 223- 3 MJ 0 22 M M. 0 223- 2 H O 223- 3

H O 223- 3 H C 223- 3 HU ) 223- 1

H O 221- 1 H O 225- 2 H O 229- 3 34

3 4 3 4 94

1 4 1 4 3 4 3 4 1 3 1 4 3 2 

## 1 3 4

32 1 " u " 1 4 3 4 1 2 4 2

3 « 1 4 M M n i t i 3 4 3 4 3 4 3 <

3 4 3 4 3 4

" » 3 4 4<
- 

## )a? o

## \)l-U- 

## Jj j UJ:4bP M ENEsC- y LABS . INC . T O1449665 3 P002/00 3 

# Sample Collection Media

Sorbent Sample Tubes 

# Sorbent Sample Tubes-Air

Sampling

Guide Reference

Table
Catalo g Numbe r 2264 1 22641GW S 2264 9 226494 2 226-1 0 226-1042 * 226-104 3 226-10-0 4 226-1006 * 22&-1 1 226-12-0 4 226-12-0 5 226-12-0 6 226-12-1 3 226-1 4 226*144 2 225-1 5 226-15GWS 226-1 6 226-164 2 226-17-1 A 226-17-3 A 226-17-4 * 226-1 8 226-1 9 226-2 1 22S-22 226-23 * 226-24 226-25 226-2 7 226-2 8 226-29 * 226-3 0 226404 2 226-304 3 ' 226-304 4 226404 5 226-300 6 22S4O07 * 226-304 8 22640-1 6 (OVS T 22640-18 * 226-31 * 22642 * 2264 5 2264541 * Sorben t

Uus ft M tr+rmtty

trttltf-t f Charcoal . Coconu t Charcoal , Coconu

t Charcoal , Coconu

t Charcoal . Coconu

t SifcaGe l SIUC AG a SIUC AGE L Silic a Ge l SILIC AGE L Alumina MolecularSiev

e 4 A MolecularSiev

e 5 A MolecularSiev

e S A MolecularSiev

e 13 X Silic a Ge l Silic a Ge l Silca Ge l Silic a Ge l Charcoal , Coconu

t Charcoal , Coconu

t Hopeafit e Hopcafit e CHR0M0S0RB P Alumin a Alumin a MolecularSiev

e S A Silic a Ge l XAO- 2

. Charcoal , Coconu

t 

# [ Charcoal , Coconu

t Charcoal , Coconu

t XAO- 2 Soda Um e CARBO N BEADS xad- 2 fxad* 2 L xad- 2 xad* 2 '"•'' xad- 2 xad-2 . xad- 2 XAO- 2 xad 4 xad-2/Fite r XAO- 2 TCARBO N BEADS L Humidifie

r CARSO N BEAOS Tena x Tena x P"Or» lairx&iq. '*C - 5" 1
- C.33C.r+a £*-^c » -*-., ! Size (mm ) 0 0 xLengt h 6x70 6x70 6x11 0 8xt3 0 6x70 10x11 0 7x11 0 8x11 0 6x70 6x70 6x70 6x70 8X70 6x70 10x150 10x150 8x11 0 8x11 0 10x11 0 10x150 6x70 8x11 0 6x40 6x11 0 10x11 0 10x11 0 10x11 0 6x7 0 8x11 0 T8x11 0 L 8x11 0 8x11 0 7x11 0 8x11 0 6x7 0 r10x11 0 L 10x11 0 6x11 0 8x11 0 8x11 0 8x11 0 8x11 0 6x70 13-4x7 5 6x70 f10x11 0 L 11x11 0 7x17 5 6x70 6x70 Section s Sorben t (mg ) 2
" 2 2 3 2 2 2 2 2 2 2 2 2 2 3 3 2 2 2 2 1 1 1 2 2 2 2 2 2 1 1 2 2 2 2 1 1 2 2 2 2 2 1 2 2 1 . 1 1 2 2 50/10 0

50/10 0 '200/40 0 350/950/35 0 7S15 0 500/100 0 200/40 0 150/30 0 100/20 0 50/10 0 72/145 72/145 200/40 0 72/14 5 150/150/700 150/150/700 260/52 0 26052 0 200*300 200/180 0 20 0 50 0 3 0 200/40 0

- 2OQ/80 O 290/116 0 260/104 0 50/10 0 200/40 0 r20 0 L 40 0 22S/45 0 200/600 250/500 4CV8 0 r30 0 L 60 0 30/10 0 50/10 0 75/15 0 200740 0 50/10 0 10 0 140*27 0 40/8 0 r150 0 L10 0 mm 1500 15(0 0 100) 

### En

d G S G S G S G S G S G S G S G S G O G S G S G S G S G S G S G S G S G S G S G S G S G S G O G S G S G S G S G S G S rG S LG S G S G S G S G S 

## re s LG S G S G S G S G S G S G S G O G S r G S LG S G S G S G O Holde r Separator s A A B C A C B B A A A A B A C C B B C C A B A 8 C C C A B 0 B B . B A O B B B B O f A Pendin g A O O A A CCATtO v TPBA res n-t-an .. . _X_ M n ai___,, , FF W WW W FF W WWW W FFW . 

### www " WWG W WW W WW W FF W FF W FF W FF W FF W
FF W WW W FF W FF W W W W W W W
' FF W FF W FF W FF W WW W WF W
' W W

. W W WW W • * WW W WW W W W W W WW W WW W WW W 

### ww w ww w W W FFG T OO O W W rw v W W FFG W FF W Price/Quantit y $29,95/5 0 55.00/5 0 54.95* 0 104.505 0 39.95/5 0 124405 0 75.005 0 81.50,3 0 - .92.50/5 0 67.505 0 78.00* 0 78.005 0 88.005 0 78.005 0 195.005 0 195.005 0 59.955 0 81.505 0 85.505 0 132.005 0 76.005 0 122.005 0 105.005 0 83.505 0 101.005 0 99.005 0 92.50/5 0 70.005 0 91.005 0 149.005 0 sets 60.00/2 0 108.005 0 100.005 0 64.005 0 185.005 0 set

a 9150/5 0 ' 80X05 0 68X05 0 -107X05 0 37.50/2 0 98X05 0 85X0/1 0 107X0/5 0 122X0/2 0 set

s 44X0/2 0 08.50/5 0 112-505 0 1'(Q\P.6 3

.i'.i'J J \a(..Cii>>. iiVWil i £.l£iW . ' *\0i , lHO . 1 0 l44d003 J rUU< !



## ,H FORMULA : Tabl e 1



### M.W. : Tabl e 1 

## HYDROCARBONS . AROMATI C METHOO : 150 1 ISSUED : 2/15/8 4
OSHA , NIOSH , COMPOUNDS : (Synonyms i nTabl e 1 ) ACGIH : Tabl e 2

benzen e E-tert-butyltoluen e
SAMPLIN G PROPERTIES : Tabl e 1

cumeme a-methylstyren e styren e ethylbenzen e naphthalen e toluen e
MEASUREMEN T viny l toluen e

xylen e

•. . SAMPLER : SOLI O SORBEN T TUB E

(coconu t shel l charcoal , 10 0 mg/5 0 mg ) FLO W RATE , VOLUME : Tabl e 3 SHIPMENT : n

o specia l precaution s SAMPL E STABILITY : no t determine d BLANKS : 2 t o 1 0 fiel dblank s pe r se t BUL KSAMPLE : desirable , 1 t o 1 0 mL ; shi pin

separat e container s fro m sample s
ACCURAC Y RANGE STU0IED , BIA S an d OVERAL

L PRECISIO N (s r ) : Tabl e 3 TECHNIQUE : GA S CHROMATOGRAPHY

. FI O ANALYTES : hydrp«£Jjon s liste d abov e DESORPT10N: ( 1 m L CS 2 ; Stan d 3 0 mi n INJECTIO N VOtiJtg^Li Q TEMPERATURE-INJECTION : 22 5 ° C

-DETECTOR: 22 5 ° C -COLUMN : se e ste p 1 1 CARRIER CAS : N 2 o rHe

. 2 5 mL/mi n COLUMN : glass , 3. 0 m x2 mn , 10 1 OV-275 o n 100/12 0 mesh Chromosorb W-A W o requivalen t CALIBRATION : analyte s i n CS 2 RANG E AN D PRECISION (s r ) : Tabl e 4 ESTIMATE O LOO: 0.00 1 t o 0.0 1 m g pe rsampl e wit h capillar ycolu m Cl ] APPLICABILITY : Thi s metho d i s fo rpeak , ceilin g an d TV M detennination s o faromati chydrocarbon s I t ma yb e use d fo rsimultaneou s measurements , thoug h ther e i s th e possibilit ytha t interaction s betwee n analyte s ma

yreduc e th e breakthroug h volume s an d chanq e desorptio n efficiencies

. INTERFERENCES

: Use o fth e reccnmende d colum n wil l preven t interferenc e b yalkane s (iC-jo K Unde rcondition s o fhig h humidity , th e breakthroug h volume s ma yb e reduce d b yas muc h a s 501 . Othe rvolatil e organi csolvents , e.g. , alcohols , ketones , ether s an d halogenate d hydrocarbons , ar e possibl e interferences

. I finterferenc e i s suspected , us e a les s pola rcolum n o rchang e colum n temperature
. OTHE R METHOOS

: Thi s metho d i s base d o n an d supercede s Method s P&CA M 127 , benzene/styrene , toluen e an d xylen e [2] ; S311 , benzen e [4] ; 522 , p-tert-butyltoluen e [3] ; S23 , cumene [3] ; S29 , ethylbenzen e [3] ; S26 , a-methylstyren e [3] ; S292 , naphthalen e [4] ; S30 , styren e [3] ; S343 , toluen e C41 : S25

. vinyltoluen e [31 ; S318

. xylen e C41

. ; ______ _
2/15/8 4 1501- 1



# teewi i nJJ . L . 1.1 i i'i m m t.iLl\U l 00 , I1K- . i vIHUODd J 

### fuU J P.6 4

HYDROCARBONS . AROMATI C METHOO : 150 1 REAGENTS : 1 . Eluent : Carbo n disulfide* , chromatographi c qualit ycontainin g (optional ) suitabl e interna l standard . 2 . Analytes , reagen t grade* 3 . Nitroge no r helium , purifie d 4 . Hydrogen , prepurified . 5 . Air , filtered . 6 . Naphthalen e calibratio nstoc k solution , 0.4 0 g/m l i nCSj .
*Se e Specia l Precautions . EQUIPMENT : 1 . Sanpler : glas s tube , 7 a nlong , 6 m m 00 , 4 m n10 , flame-seale dends , containin g two section s o f activate d(60 0 °C ) coconu t shel l charcoa l (front • 10 0 mg , bac k= S O mg ) separate db y a 2-rr m urethan e foa m plug . A

silylate dglas s woo l plu g precede s th e fron t sectionan da 3-m m urethan e foa

m plu g follows th e bac ksection . Pressur e dro pacros s th e tub e a t 1 L/mi nairflo

w mus t b e les s than3. 4 icPa . Tube s

. ar e ccmnerciall y

available . L j>. _^ r / ^ 2 . Persona l sampling punps , 0.0 1 t o 1 L/mi n.. . "~"3 ^ (Tabl e 3) , wit hflexibl e connectin g v^^ / tubing . 3 . Ga s chromatograph , FIO , integrator , andcolu m (page 1501-1) . 4 . Vials , glass , 1-mL , wit hPTFE-line dcaps . 5 . Pipet , 1-mL , andpipe t bulb . 6 . Syringes , 5- , 10- , 25 - an d 100-JJL . 7 . Volunetr.i c flasks , 10-mL . 

# 'J

SPECIAL PRECAUTIONS : Carbondisulfid e i s toxi c an dextremel y

flarrmabl e (flas hpoin t = -3 0 8 C ) ; benzen e i s a suspec t carcinogen . Prepar e sample s an dstandard s i

na well-ventilate dhood .

SAMPLING : 1 . Calibrat e eac hpersona l sampling punpwit ha representative sample r i nline . 2 . Breakthe end s o f th e sanple r irmtediately befor e sampling . Attac hsanple r t o persona l samplin g pum pwit hflexibl e tubing . 3 . Sampl e a t a naccuratel y know nflo w rat e betwee n0.0 1 and0. 2 L/mi n(t o 1 L/mi nfo r naphthalene o r styrene ) fo r a tota l sanpl e siz e a s show ni nTabl e 3 . 4 . Ca pthe sampler s wit hplasti c (no t rubber) cap s andpac ksecurel y fo r shipment . SAMPL E PREPARATION : 5 . Plac e th e fron t andbac ksorben t section s o f the sanple r tube i nseparat e vials , th e glas s woo l an dfoa m plugs . 6 . Ad d1. 0 mL eluen t t o eac hvial . Attac hcrinpca pt o eac hvia l immediately . 7 . Allo w t o standa t leas t 3 0 mi nwit hoccasiona l agitation . Discar d

CALIBRATIO

N AN O QUALIT YCONTROL

: 8 . Calibrat e dail ywit h a t leas t fiv e workin g standard s ove rth e appropriat e rang e (ca . 0.0 1 t o 1 0 m g analyt e pe rsample ; see Tabl e 4) . a . Ad d know n arount s o fanalyt e (calibratio n stoc k solutio n fo rnaphthalene ) t o eluen t i n 10-mL volumetri c flask s an d dilut e t o th e mark. b . Analyz etogethe rwit

h sanple s an

d blank s (step s 11 . 1

2 an d 13) . c . Prepar

e calibratio n grap h (pea k are a o fanalyt e vs . m g analyte) .

2/15/8 4 1501-2 

## .xiS&P.6 5 I nv.i . t.«_...w . ' hjxJ, U l v. . I V IfirOOj O ' ~f uu- . " : '

METHOO : 150 1 HYDROCARBONS . AROMATI C 9 . Determin e desorptio nefficienc y (OE ) a t leas t onc e fo r eac hbatc ho f charcoa l use dfor sampling inthe calibratio nrang e (step8) . Prepar e thre e tube s a t eacho f five level s plu s thre e medi a blanks . ." ^ a . Remov e an ddiscar dbac ksorben t sectiono f a medi a blanksampler . b . Injec t a know

namoun t o f analyt e (calibratio nstoc ksolutio nfo r naphthalene ) directl y ont o fron t sorben t sectio nwit ha microlite r syringe . c . Ca pth e tube . Allow t o standovernight . d . Desor b(step s 5 through7 ) andanalyz e together wit hworkin g standard s (step s 11 , 1 2 and13) . e . Prepar e a grap

ho f D E vs . m

g analyt e recovered . 10 . Analyz e thre e qualit y contro l blindspike s an dthre e analys t spike s t o Insur e tha t the calibrationgrap

handD E grap

har e i ncontrol . MEASUREMENT : , 11 . Se t ga s chromatographaccording t o manufacturer' s recommenda tion s andt o condition s given o npag e 1501-1 . Selec t appropriat e colum ntemperature : - 7

Substance 3 benzen e toluen e xylen e (para ) ethylbenzen e xylen e (meta ) cumen e xylen e (ortho ) styren e a-methylstyren e viny l toluen e (meta ) naphthalen e 5 0 ° l 

### 2. 5 4. 3 7. 0 7. 0 7. 2 8. 3 1 0 1 6 Approximat e RetentionTim e (min) . a t Indicate dColu m Temperature^ ' '^v v ^ 10 0 ° C 15 0 " C Programmed* * 

# >P 2. 5 1- 1 4. 2 1- 4 5. 2 1. 4 5. 5 1. 5 5. 6 1. 6 6. 0 1. 9 6. 5 2. 6 7. 6 3. 2 1. 0 8. 1 3. 8 1. 2 8. 5 2 5 4. 3 1 2

a Dat a no t availabl e fo r js-tert-butyltoluene an djj-vinyltoluene , temperatur e program : 5 0 ° C fo r 3 min , then15 °C/mi nt o 20 0 °C . NOTE : Alternatively , colum nan dtemperatur e ma

y be takenfro nTabl e 4 . 12 . Injec t sanpl e aliquo t manuall y using solven t flus

htechniqu e o r wit hautosampler . NOTE : I f peakare a i s abov e the linea r rang e o f th e workin g standards , dilut e wit heluent , reanalyz e andappl y

the appropriat e dilutio nfacto r incalculations . 13 . Measur

epea karea . CALCULATIONS : 14 . Determin e th e mass , m g (correcte d fo rDE

) o fanalyt e foun d i n th e sample fron t (Wf. ) an d bac k (W^ ) sorben t sections , and i n th e average media blan k fron t (Bf ) an d bac k (B*, ) sorben t sections . NOTE: I fUj

j > Wf/10 , repor t breakthroug h an d possibl e sanpl e loss .

2/15/8 4 1501- 3



# •/CP 4> UU J

HYDROCARBONS

. AROMATIC . METHOO: 150 1

. J 15 . Calculat e concentration , C , o fanalyt e i n th e ai rvolun e sampled , V (L) :

C a ( W f . W b - B f - B b )>10' )m9/n| 3 mg/m J

EVALUATION O

F METHOO : Precision s an d biase s liste d i n Tabl e 3 wer e determine d b yanalyzin g generate d atmosphere s containin g one-half , one , an d tw o time s th e OSH A standard . Generate d concentration s wer e independentl yverified . Breakthroug h capacitie s wer e determine d i n dr yair . Storag e stabilit y was no t assessed . Measuremen t precision s give n i n Tabl e 4 wer e determine d b yspikin g sanplin g medi a wit h amounts correspondin g t o one-half , one , an d tw o time s th e OSH

A standar d fo rnomina l a i rvolumes . Desorptio n efficiencie s fo rspike d sampler s containin g onl yon e compoun d exceede d 751 . Referenc e [12 ) provide s mor e specifi c information . REFERENCES : [1 ] Use rcheck , UBTL . NIOS H Sequence 04121- s (unpublished , Decenbe r7 . 1983) . [2 ] NIOS H Manua l o fAnalytica l Methods , 2nd . ed. , V . 1 , P4CA N 127 . U.S . Departmen t o fHealth , Education , an d Welfare , Publ . (NIOSH ) 77-157- A (1977) . [3 ] Ibid , V . 2 , S22 , S23 , S25 , S26. S29 , S30 , U.S . Departmen t o fHealth , Education , an d Welfare , Publ . (NIOSH ) 77-157- B (1977) . [4 ] Ibid , V . 3 , S292 , S311 , S318 , S343 , U.S . Departmen t o fHealth . Education , an d Welfare , Publ . (NIOSH ) 77-157- C (1977) . [5 ] R . D . Oreisbach . "Physica l Propertie s o fChemica l Conpounds" ; Advance s i n Chemistr y Series , No . 15 ; America n Chemica l Society , Washingto n (1955) . [6 ] Cod e o fFedera l Regulations ; Titl e 2 9 (Labor) , Part s 190 0 t o 1910 : U.S . Goverrtnen t Printin g Office . Washingto n (1980) ; 2 9 CF R 1910.1000 . [7 ] Update Criteri a an d Recomnendation s fo ra Revise d Benzen e Standard , U.S . Departmen t o f Health , Education , an d Welfare , (Augus t 1976) . [8 ] Criteri a fo ra Reccrnnende d Standar d Occupationa l Exposure t o Toluene . U.S . Departmen t o fHealth , Education , an d Welfare , Publ . (NIOSH ) 73-1102 3 (1973) . [9 ] Criteri a fo ra Reconnende d Standard....Occupationa l Exposure t o Xylene , U.S . Departmen t o f Health , Education , an d Welfare , Publ . (NIOSH ) 75-16 8 (1975) . [10 ] TLV

s - Threshol d Limi t Value s fo rChemica l Substance s an d Physica l Agent s j n tii e Hbr k Environmen t wit h Intende d Change s fo r1983-84 . ACGIH , Cincinnati , O H (1983) . [11 ] Criteri a fo ra Reccrmiende d Standard...Occupationa l Exposure t o Styrene , U.S . Departmen t o f Healt h an d Huna n Services , Publ . (NIOSH ) 63-11 9 (1983) . [12 3 Documentatio n o fth e NIOS H Validatio n Tests , S22 . S23 , S25 , S26 . S29 , S30 , S292 , S311 , S318 , S343 , U.S . Departmen t o fHealth , Education , an d Welfare ; Publ . (NIOSH ) 77-18 5 (1977) . METHO O REVISE

O BY : R . Ala n Lunsford . Ph.D. , an d Juli e R . Okenfuss ; base d o n result s o fNIOS H

Contrac t COC-99-74-45 .

2/15/8 4 1501

_ 4



## - 

## \t9^P.6 7

¥ < V • V C •-_ •1 ••' •••**-_• •4.. t •*\ V i ' T.. ' 0 1 1.IU , u i-j-;OOJ o fUU O



## 3 fCTHOO: 150 1

Tabl e 1 . Synonyms,
Name/Synonyns benzene CA S #71-43- 2 •

Formula , molecula rweight ,

1 Structur e 

# ; o
^-tert-buty l toluen e - /(yS ( > CA S #98-51- 1 ^£V \ 1-tert-buty l -4-methylbenzen e ajmene CA S #98-82- 8 isopropylbenzen e ethylbenzen e CA S #100-41- 4 

# <O K 

# Q-\
o-methylstyren e //j V / CA S #98-83- 9 ^ZV V 1sopropenylbenzen e ( 1 -meth y1 ethenyl ) -benzen e naphth a 1 ene CA S #91-20- 3 styren e CA S #100-42- S vinylbenzen e toluen e CA S #106-88- 3 methylbenzen e 

# @D <0 K 

# <o^ -
viny l to l uene * -L/f^S- - CA S #25013-15- 4 ^\^ 7 \> methy l styren e (g-viny l toluene ) methylvinylbenzen e ; Empirica l Formul a C6« 6
Cll«1 6

^ 1 2

CaH 1 0 

## W o

c 10" 8 

### <¥%

C7" 8

C9H 1 0 propertie s

Molec ula r Weigh t 78.1 1
148.2 5

120.2 0

106.1 7
118.1 8

128.1 8
104.1 5

92.1 4

118.1 8 (meta) (para ) (ortho ) [5] .

Boilin g Poin t (°C ) 80. 1
192. 8

152. 4

136. 2
165. 4

80.2 *
145. 2

110. 6

167. 7 171. 6 172. 8 169. 8 HYOROCARBONS .
Vapo rPressur e 0 2 5 » C (m m Ho ) 95. 2
0. 7

4. 7

9. 6
2. 5

0. 2
6. 1

28. 4

1. 6 1. 9 1. 8 1. 8 

## .U M 12. 7
0.0 9

0.6 2

1.2 8
0.3 3

0.0 3
0.8 1

3.7 9

0.2 2 0.2 6 0.2 4 0.2 4 AROMATI

C

Densit y * 2 0 * C (9/m U 0.87 9
0.86 1

0.86 2

0.86 7
0.91 1

1.025
0.90 6

O.B6 7

0.89 8 0.91 1 0.91 1 0.90 4 xylene 6 CAS #1330-20- 7 dimethylbenzene (t-xylene ) I5£i i CaHi O 106.1 7 (ortho ) 144. 4 (meta ) 139. 1 (para ) 138. 4 Sitin g point . b Cotnnercla l mixtur e o fmet a an d par a isomers . c Mixtur e o fisomers . 6. 7 0.8 9 0.88 0 8. 4 1.1 2 0.66 4 8. 8 1.1 8 0.861 .

2/15/8 4 1501-5 

### '••IG?(J 3P.6 8

xa i . i ! ' I i i t



### . i

;'"' •

. j w i axj VU-U1.-7 . 1 iw n UlLftU l 'CJ , .Hi t

HYDROCARBONS

. AROMATIC !
Tabl e 2 . Permissibl e exposur e
Substanc e benzen e p-tert-butyltoluen e cumen e ethylbenzen e a-methyIstyren e naphthalen e styren e toluen e vinyltoluen e xylen e

a Maximu m duratio n 1 0 mi n b Haximu m duratio n 5 mi n ' TW A 1 0 1 0 limit s OSH A C 2 5 5 0 (skin ) 10 0 1 0 10 0 20 0 10 0 10 0 i n 8 1 n an y 10

0 20 0 30 0

ir . 3 hr . •

i PP"* .
Pea k 50 3

600* > 500 3 I V 1-H3003 J

C6-11] . NIOS H TW A C 1

5 0 100 10 0 200 * 100 200 * ••ACGIH : suspec t * 10-mi n sample . TL

V fUU' l

4

ACGI H STE L 10* * 25* * 1 0 5 0 10 0 50 1 0 50 10 0 50 10 0
carc i 2 0

7 5 (skin ) 12 5 10 0 I S 10 0 15 0 (skin ) 10 0 15 0 noge n [10] . METHOO: 150 1

mg/ni- * pe rpp n 3.1 9 6.0 6 4.9 1 4.3 4 4.8 3 5.2 4 4.2 6 3.7 7 4.8 3 4.3 4 • •

<•

* * (

Tabl e 3 . Samplin g flowrate 4 , volune , capacity , range , overal l bia s an d precisio n [3,4,12] , Breakthroug h

Substanc e Samplin g Flowrat e Volun e (L ) (L/min ) V0L-N0 M VOL-MAX & Volun e @ Concentratio n (L ) (mg/m3 ) (mg/m 3 )

Rang e a t VOL-NO N Overa 1 1 Bia s (* ) Precisio n

<«r >
benzen e $0.2 0 2 C 3 0 >4 5 14 9 42 - 165 0. 8 B-tert-buty l to l uen e SO . 2 0 1 0 2 9 44 11 2 29 - 11 9 -10. 4 cumen e £0.2 0 1 0 3 0 >4 5 48 0 120 - 48 0 4. 6 ethylbenzen e SO.2 0 1 0 2 4 3 5 91 7 222-88 4 -8. 1 ex-methy l styren e $0.2 0 3 f3 0 >4 5 94 0 236 - 94 3 -10. 8 naphthalene e$1. 0 20 0 20 0 >24 0 8 1 19 - 8 3 -0. 5 (gyrene' V -Sl.O'" - '59- ' 1 4 2 1 171 0 \ . 426-171 0 /-10. 7 ; toluen e $0.2 0 2 C 8 1 2 229 4 548-219 0 3. 8 vinyltoluen e $0.2 0 1 0 2 4 3 6 95 2 256 - 97 0 -9. 5 xylen e $0.2 0 1 2 2 3 3 5 87 0 218-87 0 -2. 1 ^ininu nrecomnende

d flo wi s 0.0 1 L/min. b Approximate1 ytwo-third s th e breakthroug h volume , excep t fo rnaphthalene . c 10-mi n sanple . ^Correcte d value , calculate d fro m dat a i n Referenc e 12 . Naphthalen e show

s poo rdesorptio n efficienc ya t lo wloading ; 100- L minimu m volum e i s recommended . f 15-mi n sanple . 95-mi n sample .

2/15/8 4 1501- 6 }LD^TUi"v.r; j uL'.Clti. nvvtr i CWCR'J ! LABi , INL. 

### I Ul-449bbD J P.6 9 

### F00 8

i 4 * i METHOO : 150 1 Tabl e4 . Measurementrange , precisio nan d conditions 3 [3,4,12] .

Substanc e benzen e p-tert-butyltoluen e cumen e ethylbenzen e a-methylstyren e naphthalen e styren e toluen e! vinyltoluen ei xylen e\ Resorptio n Volum e i <mL )
! 1. 0 i 0. 5 

### I o. s ! O. S 

## : 

## o.s ! i- o ! 0. 5

- 1. 0 0. 5 1. 0 Measurement

RangePrecisio n (">9 ) (s r ) 0.09 - 0.3 5 0.27 - 1.0 9 0.86 - 3.4 6 2.17-8.6 7 0.69 - 3.5 7 4.96-19. 7 2.17-8.4 9 1.13 - 4.5 1 2.41 - 9.6 4 2.60-10. 4 0.03 6

0.02l d 0.01 0 0.01 0 0.01 1 0.01 9 0.013< * 0.01 1 0.00 8 0.01 0 Carrie r

Flow

50 50 50 50 5 0 3 0 50 5 0 50 S O HYDROCARBONS , tormiy

}r

Colum nParameters- * tLength (mL/min ) (°C )
11 5 1) 5 9 9 8 5 11 5 12 5 10 9 IS S 12 0 18 0

a Injectio nvolune , 5. 0 yL ; nitroge ncarrie r gas . -*A1 1 colunn s stainles s steel , 3. 2 n noutsid e diameter . C A , 50/8 0 mes hi-orapa kP ; B , 10 1 FFA

P o n80/10 0 mes hChromosor bW AW-OMCS ; C , 10 1 OV-10 1 o

n100/12 0 mes hSupelcoport ; 0 , 50/8 0 mes hPorapakQ . ^Correcte dvalue , calculate dfro m dat a i n[12) . On ) Packing 0
0. 9 3. 0 3. 0 3. 0 3. 0 3. 0 3. 0 0. 9 3. 0 0. 9 A

B B B 8 C B 0 B 0

2/15/8 4 1501- 7



# i& 8P.7 0



# APPENDI

X F : CALIBRATIO

N DAT A

*c* ^P.7 1



# Proof Record W0 #162 7
GRASEB Y NUTEC

H

Compan yMete rNumbe r 

### H K M PURCHAS E OR . 

### Rockwel l T-11 0 Met r i c P0 #192 1 Av e Yd Hig h Fle w Lo w Flo *

•50032 7 1.000 4 1.000 5 

# &0X$r 70 HO Overal l Averag e Yd = * 1.000 4



# r

- J . > .



### '02 S. Main Street 

# Measurement Controls, Inc.

• P.O. Box 997

• Huntersville, NC 28078 (704) 875-20UP.7 2



## GRASEB YNOTEC H WRHAM , N.C . 

# ProqfJRecord WO #164 2

02 S. Main Street 

# Measurement Controk, Inc.
*P.O.-Box

997 • «•„„,_•.....•/_
. _„.,_- . 

# \m\. Huntersville, NC

28078 (704)875-2034