# Patent

## Title
Method and composition for enhancing coverage and displacement of treatment fluids into subterranean formations

## Abstract

A method of injecting a treatment fluid into a portion of a subterranean formation, comprising providing a treatment fluid having a viscosity; determining the breakdown pressure of the portion of the subterranean formation; calculating the maximum sustainable flow rate for the treatment fluid; and, injecting the treatment fluid into the portion of the subterranean formation at a flow rate less than or equal to the maximum sustainable flow rate for the treatment fluid. A method of injecting a treatment fluid into a portion of a subterranean formation, comprising providing a treatment fluid having a viscosity; determining the breakdown pressure of the portion of the subterranean formation; calculating the maximum allowable treatment fluid viscosity; adjusting the viscosity of the treatment fluid to a viscosity less than or equal to the maximum allowable treatment fluid viscosity; and injecting the treatment fluid into the subterranean formation at the selected treatment fluid flow rate.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation of U.S. patent application Ser. No. 10/961,508, filed Oct. 8, 2004 now U.S. Pat. No. 7,757,768, which is herein incorporated by reference in its entirety.


BACKGROUND
The present invention relates to chemical treatments for oil and gas wells. More particularly, the present invention relates to methods and compositions for enhancing the coverage and displacement of treatment fluids into subterranean formations.
Chemical treatments for oil and gas wells often involve sequential injections of one or more fluids, such as a preflush, chemical agent, spacer, and/or afterflush. Typically treatment fluids are injected into a subterranean formation at the matrix flow rate, i.e., the rate at which the treatment fluid enters laminar flow inside the formation. At this rate the treatment fluid enters the interstitial spaces of the formation at a flow rate low enough to avoid generating areas of high pressure within the formation that could cause the formation to fracture inadvertently. The success of these treatments often relies on the effective coverage and displacement of one fluid by another. Unfortunately, problems of uneven distribution or placement of treatment fluids are often encountered in well bores containing multiple layers with highly variable permeabilities.
Previously, acid stimulation treatments have applied Paccaloni's maximum pressure differential and injection rate (“MAPDIR”) method, which uses the injection rate as the key parameter to obtain a desired bottomhole pressure differential. However, Paccaloni's MAPDIR method and other methods involving high injection rates have not been widely adopted outside of acid stimulation treatments. This is due to the fact that many other treatment fluids, such as curable resins, are too viscous to be pumped into a formation at a flow rate sufficiently high enough to maximize the pressure differential without fear of inadvertently fracturing the formation. Furthermore, traditional solvents that could be used to lower the viscosity of the treatment fluids also tend to render the fluids less capable of adequately coating the formation, sometimes defeating the purpose of injecting the fluids into the formation.
SUMMARY
The present invention relates to chemical treatments for oil and gas wells. More particularly, the present invention relates to methods and compositions for enhancing the coverage and displacement of treatment fluids into subterranean formations.
A method of injecting a treatment fluid into a portion of a subterranean formation, comprising providing a treatment fluid having a viscosity; determining the breakdown pressure of the portion of the subterranean formation; calculating the maximum sustainable flow rate for the treatment fluid; and, injecting the treatment fluid into the portion of the subterranean formation at a flow rate less than or equal to the maximum sustainable flow rate for the treatment fluid.
A method of injecting a treatment fluid into a portion of a subterranean formation, comprising providing a treatment fluid having a viscosity; determining the breakdown pressure of the portion of the subterranean formation; calculating the maximum allowable treatment fluid viscosity; adjusting the viscosity of the treatment fluid to a viscosity less than or equal to the maximum allowable treatment fluid viscosity; and injecting the treatment fluid into the subterranean formation at the selected treatment fluid flow rate.
The features and advantages of the present invention will be readily apparent to those skilled in the art upon a reading of the description of the preferred embodiments that follows.


DESCRIPTION OF THE PREFERRED EMBODIMENTS
The present invention relates to chemical treatments for oil and gas wells. More particularly, the present invention relates to methods and compositions for enhancing the coverage and displacement of treatment fluids into subterranean formations.
In accordance with the present invention, a treatment fluid may be injected into a subterranean formation at a combination of a flow rate and a viscosity selected to maximize down hole pressure and yet remain below the “breakdown pressure.” The term “breakdown pressure,” as used herein, refers to a pressure at which the treating pressure exceeds the strength of the rock and the formation fractures. By injecting the treatment fluid at such a maximum down hole pressure, the method of the present invention allows for the enhanced coverage and displacement of the treatment fluid into the formation, often without the need for a diverting agent. In the methods of the present invention, the flow rate is generally selected by calculating the maximum sustainable flow rate that will not result in the fracturing of the formation, given the chosen viscosity of the treatment fluid. This flow rate may be thought of as the maximum rate condition that can be achieved while staying below the fracture gradient. In particular embodiments, the viscosity of the treatment fluid may also be adjusted in addition to, or in place of, adjusting the flow rate, to maximize the down hole pressure.
The ability to inject treatment fluids into a subterranean formation at or near the breakdown pressure of the formation may offer numerous benefits. In particular embodiments of the present invention, maximizing the down hole pressure by controlling the flow rate and/or the viscosity of the treatment fluid may allow the coverage of the treatment fluid to be extended into the subterranean formation, despite the presence of portions of the subterranean formation to be treated having areas of varying permeabilities along the length of the well bore. By maximizing the well bore pressure down hole without fracturing the formation, the highest possible pressure difference is created between the reservoir and the well bore, helping to force the treatment fluid to enter lower permeability regions of the formation that it might not have reached otherwise. Furthermore, in particular embodiments of the present invention, the coverage of a fluid in the formation and/or its displacement efficiency may be enhanced by adjusting the injection rate and/or viscosity of a later-introduced treatment fluid. Because each fluid in the treatment has its own viscosity, the injection rate of each fluid may be adjusted such that the maximum allowable injection pressure for each fluid is maintained while that fluid is being injected down hole without fracturing the formation. Thus, using tailored flow rates and tailored viscosities combined with MAPDIR pumping procedures, longer intervals of the well bore may be treated more effectively.
A variety of treatment fluids may be injected into a subterranean formation in accordance with teachings of the present invention. In some embodiments, the treatment fluid may comprise a curable resin. Other embodiments of the present invention may use a treatment fluid comprising a water controlling agent.
Resins suitable for use as treatment fluids in the present invention include all resins known in the art that are capable of forming a hardened, consolidated mass. Many such resins are commonly used in subterranean consolidation operations, and some suitable resins include two component epoxy based resins, novolak resins, polyepoxide resins, phenol-aldehyde resins, urea-aldehyde resins, urethane resins, phenolic resins, furan resins, furan/furfuryl alcohol resins, phenolic/latex resins, phenol formaldehyde resins, polyester resins and hybrids and copolymers thereof, polyurethane resins and hybrids and copolymers thereof, acrylate resins, and mixtures thereof. Some suitable resins, such as epoxy resins, may be cured with an internal catalyst or activator so that when pumped down hole, they may be cured using only time and temperature. Other suitable resins, such as furan resins generally require a time-delayed catalyst or an external catalyst to help activate the polymerization of the resins if the cure temperature is low (i.e., less than 250° F.), but will cure under the effect of time and temperature if the formation temperature is above about 250° F., preferably above about 300° F. It is within the ability of one skilled in the art, with the benefit of this disclosure, to select a suitable resin for use in embodiments of the present invention and to determine whether a catalyst is required to trigger curing.
Selection of a suitable resin may be affected by the temperature of the subterranean formation to which the fluid will be introduced. By way of example, for subterranean formations having a bottom hole static temperature (“BHST”) ranging from about 60° F. to about 250° F., two-component epoxy-based resins comprising a hardenable resin component and a hardening agent component containing specific hardening agents may be preferred. For subterranean formations having a BHST ranging from about 300° F. to about 600° F., a furan-based resin may be preferred. For subterranean formations having a BHST ranging from about 200° F. to about 400° F., either a phenolic-based resin or a one-component HT epoxy-based resin may be suitable. For subterranean formations having a BHST of at least about 175° F., a phenol/phenol formaldehyde/furfuryl alcohol resin may also be suitable.
Water controlling agents may also be suitable treatment fluids in the present invention. A variety of agents have been used to reduce the water permeability of subterranean formations, such as surfactants formed of one or more fatty acid imidazolyl compounds and water-resistant polymers. Water-resistant polymers, also known as relative permeability modifiers, act, inter alia, to adsorb onto the surfaces within the pores of a formation to reduce the formation's water permeability. A variety of water-resistant polymers are suitable for use as water controlling agents in the present invention. Examples of particularly suitable polymers include, but are not limited to, polyacrylamide, hydrolyzed polyacrylamide, xanthan, scleroglucan, polysaccharides, amphoteric polymers made from acrylamide, acrylic acid, diallyldimethylammonium chloride, vinyl sulfonate/vinyl amide/acrylamide terpolymers, vinyl sulfonate/acrylamide copolymers, acrylamide/acrylamido-methylpropanesulfonic acid copolymers, acrylamide/vinylpyrrolidone copolymers, sodium carboxymethyl cellulose, poly [dialkylaminoacrylate-co-acrylate-g-poly(ethyleneoxide)], acrylamide/octadecyldimethylammoniumethyl methacrylate bromide copolymer, dimethylaminoethyl methacrylate/vinyl pyrrolidone/hexadecyldimethylammoniummethyl methacrylate bromide terpolymer, acrylamide/2-acrylamido-2-methyl propane sulfonic acid/2-ethylhexyl methacrylate terpolymer, and combinations thereof. As used herein “-g-” in a formula means that the immediately following molecule in the formula is grafted to the preceding polymer molecule.
Regardless of the chosen treatment fluid, before it is injecting into the subterranean formation, the breakdown pressure of the subterranean formation must first be determined. The breakdown pressure of the subterranean formation may be determined using a variety of techniques well-known in the art. Examples of such techniques include, but are not limited to, the analysis of Step Rate Injection Tests, Full Wave Sonic or Dipole Sonic logging tools for mechanical rock properties and stress, the analysis of borehole breakouts during drilling, and minifrac analysis. During treating the near well bore, it is preferable that the treating bottom hole pressure is maintained below that of the breakdown pressure. Because once the fractures are generated, the treatment fluids will tend to flow or leak off into the fractures, defeating the purpose of treating the near well bore area. With the benefit of this disclosure, it should be within the ability of one skilled in the art to select an appropriate method of determine the reservoir stress or fracture gradient.
Having determined the breakdown pressure of the subterranean formation, particular embodiments of the present invention manipulate the flow rate of the treatment fluid to maintain a down hole pressure less than the breakdown pressure of the formation. This flow rate may be calculated by determining the maximum sustainable flow rate that will not result in the fracturing of the formation, given the breakdown pressure of the formation and the viscosity of the treatment fluid to be injected into the formation. Assuming pseudo-steady-state flow, the maximum non-fracturing injection flow rate qi,max is related to the breakdown pressure, pbd, by the following equation:




  
    q
    
      
        i
        ,
        
          m
          ⁢
          
            
          
          ⁢
          ax
        
      
      ⁢
      
        
      
    
  
  =
  
    
      
        (
        
          
            p
            bd
          
          -
          
            p
            e
          
        
        )
      
      ⁢
      kh
    
    
      141.2
      ⁢
      
        
      
      ⁢
      
        μ
        ⁡
        
          [
          
            
              ln
              ⁡
              
                (
                
                  
                    r
                    b
                  
                  
                    r
                    w
                  
                
                )
              
            
            +
            s
          
          ]
        
      
    
  




where pe is the average reservoir pressure, k is the permeability of the formation, h is the net pay, μ is the viscosity of the fluid, rb is the radius of the formation cylinder in which the majority of the pressure drop takes place, rw is the well bore radius, and s is the skin factor for the well bore. Additional information on the relationship between injection flow rates, fluid viscosities, and breakdown pressures may be found in MICHAEL J. ECONOMIDES, A DANIEL HILL & CHRISTINE EHLIG-ECONOMIDES, PETROLEUM PRODUCTION SYSTEMS CH. 14 (Prentice Hall Petroleum Engineering Series 1994) and G. PACCALONI, M. TAMBINI & M. GALOPPINO, KEY FACTORS FOR ENHANCED RESULTS OF MATRIX STIMULATION TREATMENTS, SPE 17154 (1988), the relevant disclosures of which are hereby incorporated by reference. In particular embodiments, the selected flow rate may be adjusted downwards from the maximum non-fracturing flow rate as an additional measure to further ensure the formation does not fracture inadvertently. In particular embodiments of the present invention, the selected flow rate may be range from about 80% to about 90% of the maximum non-fracturing flow rate. Additionally, the flow rate is typically monitored in real time to ensure that the desired flow rate is being achieved, as well as to determine when a sufficient amount of the treatment chemical has been injected into the formation.

In addition to, or in place of, manipulating the flow rate of the treatment fluid, particular embodiments of the present invention may manipulate the viscosity of the treatment fluid to maximize the bottom hole pressure of the well bore. Such viscosity manipulation may be particularly useful in cases wherein the treatment fluid is curable resin. By lowering the viscosity of curable resin it may possible to inject the resin into the subterranean formation at a higher flow rate. In particular embodiments of the present invention, this reduction in the viscosity of the curable resin may be accomplished by adding a solvent or dispersant to the treatment fluid. Examples of suitable solvents include, but are not limited to, methanol, isopropanol, butanol, glycol ether solvents, and combinations thereof. Suitable glycol ether solvents include, but are not limited to, diethylene glycol methyl ether, dipropylene glycol methyl ether, 2-butoxy ethanol, ethers of a C2 to C6 dihydric alkanol containing at least one C1 to C6 alkyl group, mono ethers of dihydric alkanols, methoxypropanol, butoxyethanol, hexoxyethanol, and isomers thereof. Selection of an appropriate solvent is dependent on the resin composition chosen and is within the ability of one skilled in the art, with the benefit of this disclosure. Generally, the selected solvent is added to the treatment fluid until the treatment fluid has a lower, desired viscosity. In particular embodiments, the treatment fluid may have viscosity of about 5 to about 30 cP.
In addition to being used to introduce single fluids into a subterranean formation, particular embodiments of the present invention may also be used to introduce multiple fluids, in succession, into a subterranean formation. In accordance with the present invention, each fluid in the treatment may be injected in the formation at a flow rate tailored to viscosity of the individual fluid being injected, such that the down hole pressure is maximized for each fluid as it is injected. In addition to enhancing the coverage and displacement of the individual fluids at the time, such an injection technique may also enhance the coverage and/or displacement efficiency of the previously injected fluids, helping treat longer intervals of the well bore more effectively. Such tailoring of injection rate may be particularly useful in operations wherein placement of the treatment fluid is preceded by a preflush fluid and/or followed by the placement of an afterflush fluid.
Preflush fluids suitable for use in the methods of the present invention comprise an aqueous liquid, a surfactant, and an optional mutual solvent. The preflush solution, among other things, readies the formation to receive the integrated consolidation fluid and removes oils that may impede the integrated consolidation fluid from making contact with the formation particles. Suitable aqueous liquids that may be used to form the preflush fluid include, but are not limited to, fresh water, salt water, brine, combinations thereof, or any other aqueous liquid that does not adversely react with the other components used in accordance with this invention. When used, the mutual solvent should be soluble in both oil and water and be capable, among other things, of removing hydrocarbons deposited on particulates. Examples of suitable mutual solvents include, but are not limited to, glycol ethers. Some suitable glycol ethers include ethyleneglycolmonobutyl ether, diethylene glycol monomethyl ether, diethylene glycol dimethyl ether, dipropylene glycol methyl ether, and combinations thereof. Any surfactant compatible with the aqueous liquid and capable of aiding the hardenable resin in coating the surface of unconsolidated particles of the subterranean formation may be suitable for use in the present invention. Examples of surfactants suitable for use in the preflush fluids used in the methods of the present invention include, but are not limited to, ethoxylated nonyl phenol phosphate esters, one or more cationic surfactants, one or more nonionic surfactants, an alkyl phosphonate surfactant (e.g., a C12-C22 alkyl phosphonate surfactant), and mixtures thereof. Some suitable mixtures of one or more cationic and nonionic surfactants are described in U.S. Pat. No. 6,311,773 issued to Todd et al. on Nov. 6, 2001, the disclosure of which is incorporated herein by reference.
The afterflush fluids suitable for use in the methods of the present invention comprise an aqueous liquid or an inert gas. Where the afterflush fluid is an aqueous liquid, it may be fresh water, salt water, brine, or any other aqueous liquid that does not adversely react with the other components used in accordance with this invention. Where an aqueous afterflush fluid is used, a volume of about 1 to about 5 times the volume of the integrated consolidation fluid used is generally suitable for use in the methods of the present invention. Moreover, in some subterranean formations, particularly gas-producing subterranean formations, it may be advantageous to use afterflush fluids that are inert gases, such as nitrogen, rather than an aqueous solution. Such afterflush fluids may prevent adverse interactions between the afterflush fluid and the formation. The afterflush fluid acts, inter alia, to displace the curable resin from the well bore, to remove curable resin from the pore spaces inside the subterranean formation thereby restoring permeability, and to leave behind some resin at the contact points between formation sand particulate to form a permeable, consolidated formation.
In some embodiments, the afterflush fluid further comprises a surfactant. When used, any surfactant compatible with the aqueous liquid and capable of aiding the hardenable resin in coating the surface of unconsolidated particles of the subterranean formation may be suitable for use in the present invention. Examples of surfactants suitable for use in the afterflush fluids used in the methods of the present invention include, but are not limited to, ethoxylated nonyl phenol phosphate esters, one or more cationic surfactants, and one or more nonionic surfactants, and an alkyl phosphonate surfactant (e.g., a C12-C22 alkyl phosphonate surfactant). Mixtures of one or more cationic and nonionic surfactants are suitable and examples are described in U.S. Pat. No. 6,311,773 issued to Todd et al. on Nov. 6, 2001, the disclosure of which is incorporated herein by reference.
In some embodiments of the present invention a preflush fluid comprising a water controlling agent may be placed into a portion of a subterranean formation, followed by the placement of a resin treatment fluid, optionally followed by an afterflush fluid. In such embodiments, generally, at least one water controlling agent is included in the preflush fluid in an amount sufficient to reduce the production of water from the formation. In one embodiment, the water controlling agent is included in the preflush fluid in the range of from about 0.01% to about 10% by weight of the preflush fluid. In another embodiment, the water controlling agent is included in the preflush fluid in the range of from about 0.1% to about 1% by weight of the preflush fluid.
To facilitate a better understanding of the present invention, the following examples of preferred embodiments are given. In no way should the following examples be read to limit or define the scope of the invention.
Examples
A fluid placement simulation was performed to illustrate the effectiveness of the method provided therein. The simulation involved a well bore having three intervals, having permeabilities of 5,000 mD, 1,000 mD, and 500 mD, consecutively, and a reservoir pressure of 2,000 psi at a depth of 5,000 ft. For simulation purpose, an interval length of 10 ft is assumed for each interval. Using a treatment fluid with viscosity of 1 cP, the treatment fluid was injected into the well at 2, 4, 6, and 8 barrels per minute to determine the effect of injection rate on the penetration distance of the treatment fluid into the formation. It was found that most of the treatment fluid penetrates the 5,000-mD interval, and only a small amount of treatment fluid enters the lower permeability intervals. Even as the injection rate was increased to a higher rate, the penetration depth of treatment fluid into the 500 mD interval was increased just a little.












Depth of Penetration (inches) of 1-cP Fluid


Permeability of Interval
at 8 barrel/min Injection Rate
















5,000 mD
10


1,000 mD
3


  500 mD
1









As the viscosity of the fluid was increased to 7 cP, a dramatic improvement in the penetration of treatment fluid into all intervals was observed, especially at high injection rate. It was observed that the depth of penetration of treatment fluid into the low permeability intervals of 1,000 mD and 500 mD increased significantly. The increase in viscosity of treatment fluid provides resistance to penetration of the fluid into the high permeability interval, allowing the fluid to divert and penetrate into the lower-permeability intervals.












Depth of Penetration (inches) of 7-cP Fluid


Permeability of Interval
at 8 barrel/min Injection Rate
















5,000 mD
14


1,000 mD
8


  500 mD
7









Therefore, the present invention is well adapted to attain the ends and advantages mentioned as well as those that are inherent therein. While numerous changes may be made by those skilled in the art, such changes are encompassed within the spirit of this invention as defined by the appended claims.

## Claims

1. A method of injecting a treatment fluid into a portion of a subterranean formation having a wellbore therein, comprising:
providing a treatment fluid having a viscosity;
determining the breakdown pressure of the portion of the subterranean formation;
mathematically calculating a maximum sustainable flow rate for the treatment fluid based on: the determined breakdown pressure; the average pressure and permeability of the portion of the subterranean formation; the treatment fluid viscosity; the net pay; the radius of the formation cylinder in which the majority of the pressure drop takes place; and the radius and skin factor of the wellbore; and,
injecting the treatment fluid into the portion of the subterranean formation at a flow rate less than or equal to the maximum sustainable flow rate for the treatment fluid.

2. The method of claim 1 wherein the treatment fluid comprises a water controlling agent.

3. The method of claim 2 wherein the water controlling agent comprises a surfactant formed of one or more fatty acid imidazolyl compounds, a water-resistant polymer, or a combination thereof.

4. The method of claim 1 wherein the treatment fluid comprises a curable resin.

5. The method of claim 4 wherein the resin comprises a two component epoxy based resin, a novolak resin, a polyepoxide resin, a phenol-aldehyde resin, a urea aldehyde resin, a urethane resin, a phenolic resin, a furan resin, a furan/furfuryl alcohol resin, a phenolic/latex resin, a phenol formaldehyde resin, a polyester resin, a hybrid polyester resin, a copolymer polyester resin, a polyurethane resin, a hybrid polyurethane resin, a copolymer polyurethane resin, an acrylate resin, or a combination thereof.

6. The method of claim 5 wherein the treatment fluid further comprises an internal catalyst or activator.

7. The method of claim 4 wherein the treatment fluid comprises a solvent.

8. The method of claim 1 wherein the viscosity of the treatment fluid is from about 5 to about 30 cP.

9. The method of claim 1 wherein the flow rate at which the treatment fluid is injected into the portion of the subterranean formation is less than or equal to about 90% of the maximum sustainable flow rate.

10. The method of claim 1 wherein the flow rate at which the treatment fluid is injected into the portion of the subterranean formation is less than or equal to about 80% of the maximum sustainable flow rate.

11. The method of claim 1 wherein the portion of the subterranean formation comprises a plurality of areas having distinct permeabilities.

12. The method of claim 1 further comprising the steps of:
providing a preflush fluid having a viscosity;
calculating a maximum sustainable flow rate for the preflush fluid, knowing the viscosity of the preflush fluid at which the preflush fluid can be injected without causing the portion of the subterranean formation to breakdown; and, before the step of injecting the treatment fluid into the portion of the subterranean formation,
injecting the preflush fluid into the portion of the subterranean formation at a flow rate less than or equal to the maximum sustainable flow rate for the preflush fluid.

13. The method of claim 12 wherein the preflush fluid comprises an aqueous liquid and a surfactant.

14. The method of claim 13 wherein the preflush fluid further comprises a mutual solvent.

15. The method of claim 12 further comprising the steps of:
providing an afterflush fluid having a viscosity;
calculating a maximum sustainable flow rate for the afterflush fluid; and, after the step of injecting the treatment fluid into the portion of the subterranean formation,
injecting the afterflush fluid into the portion of the subterranean formation at a flow rate less than or equal to the maximum sustainable flow rate for the afterflush fluid.

16. The method of claim 15 wherein the afterflush fluid comprises an aqueous liquid and a surfactant.

17. The method of claim 16 wherein the surfactant comprises an ethoxylated nonyl phenol phosphate ester, a cationic surfactant, a nonionic surfactant, an alkyl phosphonate surfactant, or a combination thereof.

18. The method of claim 1 further comprising the steps of:
providing an afterflush fluid having a viscosity;
calculating a maximum sustainable flow rate for the afterflush fluid; and, after the step of injecting the treatment fluid into the portion of the subterranean formation,
injecting the afterflush fluid into the portion of the subterranean formation at a flow rate less than or equal to the maximum sustainable flow rate for the afterflush fluid.

19. The method of claim 18 wherein the afterflush fluid comprises an aqueous liquid and a surfactant.

20. The method of claim 19 wherein the surfactant comprises an ethoxylated nonyl phenol phosphate ester, a cationic surfactant, a nonionic surfactant, an alkyl phosphonate surfactant, or a combination thereof.