MATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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## Material Safety Data Sheet

Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly

utilizing 3M products is allowed provided that: (1) the informa tion is copied in full with no changes unless prior written agre ement is

obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit

thereon.



## SECTION 1: PRODUCT A ND COMPANY IDENTIFICATION

PRODUCT NAME: { } (Intermediate)

MANUFACTURER: 3M

DIVISION: Materials Resource Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 11/06/12

Supercedes Date: 11/06/12

Document Group: { }

Product Use:

Intended Use: Intermediate



## SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by Wt

Fluoroalkyl Derivative Trade Secret 98 - 100

Fluorochemical Alcohol Trade Secret 0 - 0.75

Carboxylic Acid Trade Secret 0 - 0.5



## SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Specific Physical Form: { }

Odor, Color, Grade: { }

General Physical Form: Solid

Immediate health, physical, an d environmental hazards: Contains a chemical or chemicals wh ich can cause birth defects or other

reproductive harm.



### 3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:

Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.MATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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Page 2 of 7 Skin Contact:

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Inhalation:

If thermal decomposition occurs: May be harmful if inhaled.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Carcinogenicity:

Ingredient C.A.S. No. Class Description Regulation

ALCOHOLIC BEVERAGES SEQ709 Grp. 1: Carcinogenic to

humans International Agency for Research on Cancer

ALCOHOLIC BEVERAGES SEQ709 Known human carci nogen National Toxicology Program Carcinogens



## SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumpti on that appropriate personal an d industrial hygiene practices a re

followed.

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.

Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention.

If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water.

Never give anything by mouth to an unconscious person. Get medical attention.



## SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature Not Applicable

Flash Point No flash point

Flammable Limits(LEL) Not Applicable

Flammable Limits(UEL) Not Applicable

OSHA Flammability Classification: Not Applicable



### 5.2 EXTINGUISHING MEDIA

Non-combustible. Choose material suitable for surrounding fire. Material will not burn.MATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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### 5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Exposure to extreme heat can give rise to thermal decomposition. Wear full protective

equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.

Note: See STABILITY AND REACTIVITY (SECTION 10) fo r hazardous combustion an d thermal decomposition

information.



## SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air. Avoid contact with water.

6.2. Environmental precautions

Place in a closed container approved for tran sportation by appropriate authorities. Dis pose of collected material as soon as p ossible.

Clean-up methods

Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the

spill. Collect as much of the spilled material as possible. Us e wet sweeping compound or water to avoid dusting. Sweep up.

In the event of a release of this materi al, the user should determine if the relea se qualifies as reportable according to

local, state, and federal regulations.



## SECTION 7: HANDLING AND STORAGE

7.1 HANDLING

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not breathe thermal

decomposition products. Avoid prolonged or repeated skin contact . Avoid eye contact with dust or airborne particles.



### 7.2 STORAGE

Store away from heat.



## SECTION 8: EXPOSURE CO NTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS

For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with

appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guid elines.



### 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection

Avoid eye contact.

The following eye protection(s) are recommended: Safety Glasses with side shields

8.2.2 Skin Protection

Avoid prolonged or repeated skin contact.MATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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Page 4 of 7 Select and use gloves and/or protective clot hing to prevent skin contact based on the results of an exposure assessment. Consu lt with

your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.

Gloves made from the following material(s) are recommended: Butyl Rubber

Neoprene

Nitrile Rubber

8.2.3 Respiratory Protection

Avoid breathing of dust. Use a positive pressure supplied-air resp irator if there is a potential for exposure from an uncontro lled

release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequa te

protection.

An exposure assessment may be needed to deci de if a respirator is required. If a respirator is needed, use respirators as part of a full

respiratory protection program. Based on the results of the expo sure assessment, select from th e following respirator type(s) to

reduce inhalation exposure:

Half facepiece or full facepiece ai r-purifying respir ator suitable for organic vapors and particulates

For questions about suitability for a specific applica tion, consult with your respirator manufacturer.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wa sh exposed areas thoroughly with soap and water.



### 8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional Information

Fluorochemical Alcohol Manufacturer

determined TWA 1 mg/m3 Skin Notation *

* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane an d eye,

either by airborne or, more particularly , by direct contact with the substance. Vehicles can alter skin absorption.

SOURCE OF EXPOSURE LIMIT DATA:

ACGIH: American Conference of Governmental Industrial Hygienists

CMRG: Chemical Manufacturer Recommended Guideline

OSHA: Occupational Safety and Health Administration

AIHA: American Industrial Hygiene Association Wo rkplace Environmental Exposure Level (WEEL)



## SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Specific Physical Form: { }

Odor, Color, Grade: { }

General Physical Form: Solid

Autoignition temperature Not Applicable

Flash Point No flash point

Flammable Limits(LEL) Not Applicable

Flammable Limits(UEL) Not Applicable

Boiling Point Not Applicable

Vapor Density Not Applicable

Vapor Pressure Not Applicable

Specific Gravity { }

pH Not Applicable

Melting point { }

Solubility in Water NilMATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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Page 5 of 7 Bulk density { }

Evaporation rate Not Applicable

Kow - Oct/Water partition coef No Data Available

Viscosity Not Applicable



## SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid:

10.1 Conditions to avoid

None known

10.2 Materials to avoid

Al or Mg powder and high/s hear temperature conditions

Alkali and alkaline earth metals

Water

Hazardous Polymerization: Hazardous polymerization will not occur.



### Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide During Combustion

Carbon dioxide During Combustion

Hydrogen Fluoride During Combustion

Toxic Vapor, Ga s, Particulate During Combustion



## SECTION 11: TOXICO LOGICAL INFORMATION

Please contact the address listed on the firs t page of the MSDS for Toxicological Information on this material and/or its

components.



## SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.



### CHEMICAL FATE INFORMATION

Not determined.



## SECTION 13: DISPOS AL CONSIDERATIONS

Waste Disposal Method: Reclaim if feasible. Incinerate in an industrial or commercial facility in the presence of a combustible

material. For larger quantities: dispose of waste product in a sa nitary landfill. As a disposal alternative, dispose of waste product in

a facility permitted to accept chemical waste. Combustion pro ducts will include HF. Facility must be capable of handling

halogenated materials.MATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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Page 6 of 7 EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable reg ulations or authorities before disposal.



## SECTION 14:TRANSPORT INFORMATION

{

}

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.



## SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Imme diate Hazard - Yes Delayed Hazard - Yes



### STATE REGULATIONS

Contact 3M for more information.

CALIFORNIA PROPOSITION 65

Ingredient C.A.S. No. Classification

ALCOHOLIC BEVERAGES None **Carcinogen

ALCOHOLIC BEVERAGES None *Developmental Toxin

* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.

** WARNING: contains a chemical which can cause cancer.



### CHEMICAL INVENTORIES

This material is not listed on the TSCA inventory and should be used for research and development purposes only under the direc t

supervision of a technically qualified individual.

Contact 3M for more information.



### INTERNATIONAL REGULATIONS

Contact 3M for more information.



### US LABEL INFORMATION

WARNING! Mild eye irritant. Mild skin irritant. Contains a chemical or chemicals which can cause birth defects or other

reproductive harm. Inhalation of thermal decomposition products may be harmful.

PRECAUTIONS: See MSDS for su ggested first aid and precautions.

This MSDS has been prepa red to meet the U.S. OSHA Hazard Comm unication Standard, 29 CFR 1910.1200.MATERIAL SAFETY DATA SHEET { } Internal Use Only 11/06/12

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## SECTION 16: OTHER INFORMATION

NFPA Hazard Classification

Health: 3 Flammability: 0 Reactivity: 0 Special Hazards: None

National Fire Protection Associa tion (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are

presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings a re primarily based on the

inherent physical and toxic properties of the material but also include the toxic pr operties of combusti on or decomposition pro ducts that are known to

be generated in significant quantities.

HMIS Hazard Cl assification

Health: 1 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.

Hazardous Material Identification System (HMIS®) hazard ratings ar e designed to inform employees of chemical hazards in the wor kplace. These

ratings are based on the inherent properties of the material under expected c onditions of normal use and are not intended for u se in emergency

situations. HMIS® ratings are to be used w ith a fully implemented HMIS® program. HMIS® is a registered mark of the National Pai nt and Coatings

Association (NPCA).

Revision Changes:

Section 2: Ingredient table was modified.

Section 1: Product name was modified.

Page Heading: Product name was modified.

Section 1: Initial issue message was modified.

Section 2: Ingredient table was modified.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M

MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY

OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF

TRADE. User is responsible for determining whether the 3M prod uct is fit for a particular purp ose and suitable for user's meth od of

use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are un iquely

within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit f or a

particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transf er may

have resulted in errors, omissions or alterations in this inform ation, 3M makes no representations as to its completeness or ac curacy.

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M