## March 11, 2013
Carey Willoughby Monitoring and Analysis Division Source Test Engineering South Coast Air 

## Quality Management District 21865 Copley Drive Diamond Bar, CA 91765-4182 Subject: 

## Initial Source Test Report for Unit 4 CPV Sentinel, LLC (CEC Docket No. 07-AFC-3) SCAQMD Title V (A/N 472137, Facility ID No. 152707)

Dear Mr. Willoughby: • 

# sierra research 1801 

### J Street Sacramento CA 95811 Tel: (916) 444-6666 Fax: (916) 444-8373 Ann Arbor MI Tel: (734) 761-6666 Fax: (734) 761-6755



## On behalf of CPV Sentinel, LLC, I am submitting the enclosed initial source test report for Unit 4 at the CPV Sentinel Energy Project. Testing was conducted in accordance with Condition of Certification AQ-7 and Section H, Condition D29.3 of the facility's Title V Permit. Should you have any questions or require additional information related to this submittal, please contact me at (916) 444-6666. Sincerely, 

# -r--c:---**~** P"L
____ ____ 

## Tom Andrews Senior Engineer

cc: Roy Olivares, SCAQMD Craig Hoffinan, California Energy Commission EPA Region 9 

## (r9.aeo@epa.gov) Charles Aldred, EPA Region 9 Mark McDaniels, CPV Sentinel, LLC

# SOURCE TEST REPORT FOR INITIAL COMPLIANCE TESTING AT CPV SENTINEL ENERGY PROJECT UNIT 4
PREPARED FOR: GEMMA POWER SYSTEMS CALIFORNIA, INC. 

## 2461 MAIN STREET GLASTONBURY, CONNECTICUT 06033 FOR SUBMITTAL TO: SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 

## 21865 COPLEY DRIVE DIAMOND BAR, CALIFORNIA 91765-4178 PREPARED BY: DELTA AIR QUALITY SERVICES, INC . 

## 1845 N
. CASE ST. ORANGE, CALIFORNIA 92865 714-279-6777 ARLENE BELL 

# I ROBERT 

# A. FINKEN MARCH 7, 2013 REPORT NUMBER: R0410688

# /Jella**~** Air Quality Services, Incorporated

## CONFIDENTIALITY STATEMENT

This information contained in this communication 

# is intended exclusively for the individual or entity 

# to which 

# it is addressed. This communication may contain information that 

# is proprietary, privileged or confidential or otherwise legally exempt from disclosure. If you are not the named addressee, you are not authorized 

# to read, print, retain, copy, or disseminate this message or any part 

# of it.

R041 0688 ii

## REPORT REVIEW AND CERTIFICATION

I certify that all work performed in the preparation and production of this report was performed by me or under my supervision and that all data presented is authentic.

Arlene Bell Vice President, Analytical Services

I certify that I have also reviewed this report, both in form and content , and that all data , calculations, and presentations are authentic, accurate , and complete.

# ~ 

# Lf (,! 

# J I Date**----------~ ~~** **,~ --** **----------**



## R0410688 

## Robert 

## A. Finken President

iii

## CONTENTS SECTION 1.0 INTRODUCTION AND SUMMARy
........... . .... ............ ................ ........ . .......... ...... .. . ... 1 2.0 UNIT DESCRIPTION AND TEST CONDITIONS
..... .. .... .. .... .. ......... .. ............. .. .. ....... 3 2.1 UNIT DESCRIPTION
............................................. ........ .. ... ............................. 3 2.2 TEST CONDITIONS
......... .... .. ..... .. ........ ........ .. .. ............. ... .... ... ........................ 5 2
. 3 SAMPLE LOCATION
............ . .. ........ . ..... ................ .......... .. .......... ...... ........ ....... 6 3
. 0 TEST DESCRIPTION
.................................................... .. .... .. ......... .... .. ....... ............. 9 3
. 1 O 2 • 

## CO 2 , 

## NOx AND CO
.............. . .. ... ..................... . .. .... ................. ......... ......... 10 3.2 NH3 BY SCAQMD METHOD 207
. 1
................................... .. .... .... ... ..... ........... 11 3.3 SOx BY SCAQMD METHOD 307.91
.............................................................. 11 3.4 ROG BY MODIFIED SCAQMD METHOD 25.3
........... .. ............ ......... .. .......... 11 3
. 5 PM BY SCAQMD METHOD 5.1
.. ........ .... . ... .......... . .. ...... . ..... .............. ... .... ... .. 14 4.0 RESULTS
................... . ....... .. .. .. ............................ . ............. ... .... .................... ......... 16 5
. 0 DISCUSSION AND TEST CRITIQUE
...................... .. .... .. .......... .. ........................... 24 APPENDICES A QUALITY ASSURANCE
................................................. .. ... .. .......... .. ......... .. ......... A-1 A
. 1 Quality Assurance Program Summary
................. .... ...... .. .. ......... . ................. A-2 A
. 2 SCAQMD and CARB Certifications
........................................ .... .... ...... ........ .A-7 A.3 Equipment Calibration and Calibration Gas Certificates
................ ................ A-8 A.4 Delta CEM System Description and SCAQMD Method 100.1 Calibration and Test Sequence
........................................................ . .. .. ....... .A-9 B PROCESS DATA
. ...... ... ............ ..... .. ... . ....... ............. .. ......... .. .. ... ...... .. .................... B-1 B
. 1 Process and CEMS Data
............................................................................... B-2 B.1.1 Sentinel Unit 4 Stratification Test
........................................ .. .... .. ........ B-3 B.1.2 Sentinel Unit 4 Ammonia, ROG, and 

## NOx/CO Testing
........ .. ..... .. ...... . B-4 B.1.3 Sentinel Unit 4 PM Testing
.................................................................. B-5 B
. 2 Fuel Analysis Data
... .......... ........................................................................... B-6 C TEST DATA
................. ......................... ..... .................. ...... .. .. .......... .. .... .. .... ..... .... C-1 C
. 1 Stratification and Preliminary Flow Rate Tests
............................................. C-2 C
. 2 CEM Data
..................................................................................................... C-3 C
. 2.1 CEM Quality Assurance Measurements
............................................. C-4 C.2.2 NO x and CO Compliance
................................................................... C-5 C.2.3 One Minute Data Logger Data
.................... ............. ...... .... ................. C-6 C.3 Ammonia Data by SCAQMD Method 207.1
.................................................. C-7 C.4 SOx by SCAQMD Method 307.91
... .. .. ................... ........ .... . .......... . ............... C-8 C
. 5 ROG by Modified SCAQMD Method 25
. 3
..................................................... C-9 C
.6 PM by SCAQMD Method 5.1
... .... .... ............... ..... .. ... .. ... ............ .. .. ... .. ........ C-10

R041 0688 iv

## D GENERAL EMISSIONS CALCULATIONS
. ... ....... .. .... . .... "
.... . ....... . ....................... D-1 E CHAIN OF CUSTODY
. ... . ........... . ... .. .. . ........... . .... . ...... . ....................... . .... . . . .. . . . ... . .. E-1 F INSTRUMENT STRIP CHARTS
....................... .. .. . .. .. . .. . ... . .. . . . .. . ... . . . .. . . . .. ..... . ..... .. .. F- 1 G FACILITY PERMIT TO OPERATE CONDITION D29 .1
.. . ... .. ... .. . . .............. ... ......... G - 1 H CORRESPONDENCE AND TEST PLAN
.. . ... . ..... .. .. . .. ......... . ... . ........... . ... ... . . ........ . H-1

R041 06 88 v

## 1.0 INTRODUCTION AND SUMMARY Delta Air Quality Services, Inc. has been contracted by Gemma Power Systems California, Inc. (GEMMA) to perform the initial Permit to Operate Compliance Testing at the CPV Sentinel Energy Project Units 1, 2, 3, 4, 5, 6, 7, and 8. Condition 029.1 of the Permit to Operate requires source tests within 180 days of initial startup. This document is the test report for the initial compliance for CPV Sentinel Unit 4. Tests were performed at three load conditions to determine oxides of nitrogen (NO x ), carbon monoxide (CO), oxides of sulfur (SOx), reactive organic gases (ROG), particulate matter (PM), and ammonia (NH3) emissions. Bob Finken was the Senior Program Manager for Delta and can be reached at (714) 279-6777. No conflict of interest, as defined in SCAQMD Rule 304, exists between Gemma or CPV Sentinel Energy Project and Delta. Testing was conducted on February 11-12, 2013. The Delta test crew consisted of Ali Aleshaiker, Ray Madrigal, Shannon Scrugham, and Justin Miller. The fuel sampling was repeated on February 22, 2013. There was insufficient sample in the original samples to complete the anaysis. Table 1-1 contains a summary of the test results and applicable limits. This table also compares the results at three load conditions, 50%, 75%, and 100%, that were tested. All test results showed the unit to meet the permit limits. Section 2.0 of this document provides a description of the facility and sample locations. A description of the sampling strategy and test methods is provided in Section 3.0. Section 4
. 0 contains detailed test results. Section 5 contains a discussion and test critique. The appendices contain all test and laboratory data, calculations, and quality assurance data.

R0410688 1

## TABLE 1-1 CPV SENTINEL ENERGY PROJECT UNIT4 STACK TEST RESULTS SUMMARY Parameter Units 100% 75% 50% Limit Rule ppm@ 15%0, 2
. 26 2
. 18 2
. 01 2
. 5 1703(a)(2) NO, ppm @ 15% 0, 2
. 26 2.18 2
. 01 15 40 CFR 60 Ib/MMscf 8
. 97 842 8
. 29 12
. 26(1) 2012 CO ppm@ 15% 0, 1.80 1
. 03 0
. 35 4 1703(a)(2) NH3 ppm@ 15% 0, 1.9 0.92 0
. 83 5 1303(a)(1) gr/dscf @ 3% 0, 0
. 0033 0
. 0010 0.0018 0.01 475 Particulate gr/dsc! @ 12% CO, 0
. 0039 0
. 0011 0.0022 0.1 409 Ib/hr 4.38 1.12 142 11 475 PM1I)/PM '5 Ib/MMscf 4.95 1
. 60 2
. 65 5
. 71(' ) SO/3 ) Ib/MM8tu 0
. 00002 0
. 06 40 CFR 60 gr H,S/1 

### 00 sci 0.009 0
. 25 ( 4 ) SCAQMD Permit Condition 861
. 1 ROGs ppm @ 15% 0, 0.58 0
. 56 0
. 55 2.0 1303(a)(1 ) (1) The 12.261b/MMscf is a RECLAIM emission factor , not a limit. (2) This is stated in the perm it as an emission factor. (3) SO, results calculated based on 100 % load condition. (4) 0.25 gr H , S/100 

### scf sulfur content limit is based on annual average of monthly sample results
.

R0410688 

## 2

# 2.0 UNIT DESCRIPTION AND TEST CONDITIONS
2.1 UNIT DESCRIPTION 

## CPV Sentinel Energy Project is located at 62575 Powerline Road, Desert Hot Springs, California 92240. The facility consists of eight (8) identical generating units. The CPV Sentinel Energy Project consists of eight (8) LMS100PA combustion turbines in simple cycle operation. The units are natural gas fired with a rated heat input of 891
. 7 MMBtu per hour at 72 degrees Fahrenheit. Each LMS 1DOPA employs water injection and is equipped with a CO catalyst and Selective Catalytic Reduction (SCR) system for NO, control. The LMS100PA is a General Electric (GE) combustion turbine with an intercooler located between the low pressure compressor (LPC) and high pressure compressor (HPC)
. Off engine combustion air to closed loop water intercooling is used for increased gas turbine thermal efficiency
. Heat removed from the off-engine intercooler is circulated through a closed loop cooling system
. Heat is rejected from the closed loop cooling system to an open loop cooling system via a shell and tube heat exchanger. The open loop system rejects heat via a mechanical draft counterflow cooling tower. The cooling tower is provided with drift elimination to comply with air emissions limits. Figure 2-1 presents a block diagram of the units
. Figure 2-2 shows a general arrangement of the major components.

R041 0688 

## 3

## FIGURE 2-1 SIMPLIFIED PROCESS BLOCK DIAGRAM CPV SENTINEL ENERGY PROJECT COMBUSTION TURBINES

Simplified Process Flow Diagram


## Air Water

Air Cooling Tower

Closed Loop Cooling

LMS100PA

Water Natural Gas Fuel Demineralized

R041 0688 

## Air Water Heat

Exhaust to Atm.

Exhaust CO Catalyst SCR 

# -

Ammonia 19% Aqueous



## 4

## FIGURE 2·2 GENERAL ARRANGEMENT OF MAJOR COMPONENTS

C I to ,. J,



## 2.2 TEST CONDITIONS 

## The permit requires that the tests will be performed at three operating conditions; 1) maximum, 2) average, and 3) minimum load. 

## Full load is nominally 100 megawatts and minimum load is approximately 50 megawatts. Since these will be the initial tests for the units and no long term average will have been established , average conditions will be approximated at 75% of capacity or approximately 75 megawatts
.

R041 0688 

## 5

## Unit operating data was collected during the tests by the facility from the CEMS DAS
. Table 2-1 below presents the average operating condition for each parameter. 

## TABLE 2-1 AVERAGE OPERAT I NG CONDITIONS Parameter 50% Load 75% Load 100% Load Fuel Flow Rate, hscfh 5,354 6 ,974 8 , 845 Turbine Generating Output (MW) 55
. 0 80
. 5 106.5 Ammon i a Flow , Ib/hr 105
. 0 112
. 3 110.0 Exhaust Temperature , ' F 769 752 786 Exhaust Flow Rates, kscfh 14 ,959 18 , 145 21 , 154 Notes: Data from facility DAS except exhaust gas temperature where PM test data was used
. Data collected during PM test intervals at each condition.



## Process data obtained during testing is contained in Appendix B. 

## 2.3 SAMPLE LOCATION There are four 4" test ports located at 90 degrees apart around the circumference of the 13'6 " diameter stacks. The ports are located 323 " downstream (2.0 diameters) of the nearest flow disturbance (duct breeching) 84 " upstream (0
. 5 diameters) of the nearest flow disturbance (silencers). The sampling location meets the minimum requirements of SCAQMD Method 2
. 1; at least 2 diameters downstream and at least 0
. 5 diameters upstream of the nearest flow disturbances. Figure 2-3 presents the details of the sample location
.

R0410688 6Stack Exit 1080 ,0 in. Silencer Bottom 925.9 in.
Ports 841 .6 in. Platform 789.6 in.

Base of Stack 518.5 i n.

Grade 0 .0 in. 

## FIGURE 2-3 SAMPLE LOCATION DETAILS

Inside Diameter, in . 

### --+- 162 

## +-- 

# I 84 Distance A , inches, 0 . 5 Diameters 

# ! Sam pie ports 

# T
323 Distance B, inches , 2.0 Diameters



# 1
.._--,E",x""haust Flow

Elevation View 

### 90 ft.



### 66 ft.



### Oft



## Prior to performing the tests, gaseous stratification was investigated with a 12 point traverse as described in 40 CFR 

## 75, and the presence of cyclonic flow was checked using the techniques described in SCAQMD Method 2. The results of the yaw angle and stratification checks indicate that the angle criteria was met. The average angle was 0.9' which meets the SCAQMD criteria of 10 degrees or less. The stratification criteria was not met. Results of the stratification checks are presented in Table 2-2. 12-point traverses were used for ammonia, NO x , 

## and CO compliance tests.

R0410688 7

## TABLE 2-2 12-POINT STRATIFICATION CHECK RESULTS GEMMA POWER SYSTEMS CPV SENTINEL UNIT 4 0, CO, NO, CO Port Point % % ppm ppm South 3 13
. 18 4.56 3.14 1.50 South 2 13.18 4
. 56 3.02 1.89 South 1 13
. 13 4
. 59 3.03 1.84 East 3 13
. 15 4
. 58 3.15 2.03 East 2 13.19 4
. 55 3.01 2.75 East 1 13
. 19 4
. 56 2.76 2.51 West 3 13.19 4
. 55 3
. 28 3.11 West 2 13.19 4.56 3
. 30 2.98 West 1 13.18 4
. 56 3
. 28 2.81 North 3 13.20 4
. 54 3
. 32 3.01 North 2 13.22 4.53 3.43 2.72 North 1 13.21 4
. 54 3
. 50 2.83 Average 13.2 4.6 3
. 2 2.5 

### Maximum 13.2 4
. 6 3
. 5 3.1 

### Minimum 13.1 4.5 2
. 8 1
.5 

### Maximum Difference from Average 0.1 0.0 0.4 1.0 Max Difference (% of average) 0.4% 0.7% 13.4% 40
. 0% 

### Criteria:

If 

### < 10% , use single point. Action Taken:

12-point traverse used for RATA runs Runs in conjunction with NH3 test , use 12-point traverse 

## Table 

## 2-3 illustrates the location of sample traverse points for each type of test. TABLE 2-3 SAMPLE POINT LAYOUT PM (24 pts.) Cyclonic Flow Check (16 pts.) Strat.lNH3, NO;.;, and CO Compliance (12 Pts . ) Sample 

### % of in. 

### % of in . 

### % of in.

Po in t 

### Diameter from Wall Diameter from Wall D i ameter from Wall 

### 2.1 3.4 3
. 2 5.2 4.4 7
. 1 2 6.7 10.9 10.5 17
. 0 14
.6 23.7 3 11
. 8 19 .1 19.4 31.4 29.6 48.0 4 17.7 28 .7 32
. 3 52.3 70.4 114.0 5 25 40.5 67
.7 109.7 85.4 138.3 6 35.6 57 .7 80.6 130.6 95.6 154.9 7 64.4 104.3 8 75 121.5 9 82.3 133.3 10 86.4 140
. 0 11 93.3 151
. 1 12 97.9 158
.6

R0410688 

## 8

## 3.0 TEST DESCRIPTION Table 3-1 summarizes the test methods and techniques that were used as the reference methods. The test matrix has been developed to meet the requirements of Section 29.1 of the facility Permit (Application Number 472137) dated April 15, 2011. The test matrix indicates the number of runs that were performed for each parameter and each condition
. The permitted emission limits are summarized in Table 3-2. The following sections describe each method in further detail. Flue gas oxygen and carbon dioxide concentration were measured in conjunction with all tests using SCAQMD Method 100.1. The flue gas flow rate was measured in conjunction with each ammonia and particulate test. This measured flue gas flow rate was used for all emission rate calculations of NOx , CO, NH 3 , 

## ROGs and SOx. TABLE 3-1 TEST MATRIX SENTINEL UNIT 4 Parameter Method 50% Load 75% Load 100% Load Test Duration NO x 

### SCAOMD 100
. 1 2 runs' 

## 2 runs* 

## 2 runs"" 60 minutes
02 

## /C0 2 

### SCAOMD 100.1 With each run

CO SCAOMD 100.1 2 runs' 2 runs' 2 runs' 60 minutes NH3 SCAOMD 207.1 2 runs 2 runs 2 runs 60 minutes S02 SCAOMD 307
. 91 Fuel Sample, 2 Samples N/A PM SCAOMD 5
. 1 1 run 1 run 1 run 240 minutes ROG Mod ified SCAOMD 25
. 3 1 pair 1 pair 1 pair - 60 minutes (1 ) 

### 1) ROG tests were nominally 60 minutes. Flow controllers will be setup for 60 minutes
. The test was performed until the canister vacuum reaches approximately 10 "Hg. Actual test time may be less than or more than 60 minutes per sample . 

### • Additional runs performed compared to test plan.

R041 0688 

## 9

## TABLE 3-2 CPV SENTINEL ENERGY PROJECT PERMITTED EMISSION LIMITS Parameter Units ppm@ 15%02 NO, ppm @ 15% O 2 Ib/MMscf 

# co ppm @ 15% O 2 NH3 ppm @ 15% O 2 gr/dscf @ 3% O 2 Particulate gr/dscf @ 12% CO 2 Ib/hr PM lO

### / PM 2 .5 

### Ib/MMscf SO, Ib/MM8tu gr H 2 S/100 scf ROGs ppm @ 15% O 2 (1) The 12
. 261b/MMscf is a RECLAIM emission factor, not a limit. (2) This is stated in the permit as an emission factor. Limit 2
. 5 15 12
. 26 11 ) 4 5 0
. 01 0
. 1 11 5.71 12)

0.06 0.25 13 )

2
. 0 Rule 1703(a)(2) 40 CFR 60 2012 1703(a)(2) 1303(a)(1 ) 475 409 475

40 CFR 60 SCAQMD Perm it Condition 861.1 1303(a)(1 ) (3) 0.25 gr H2 S/1 00 scf sulfur content lim it is based on annual average of monthly sample results.



## 3 ,1 

## O 2 • 

## CO 2 • 

## NO 

## x AND CO 

## O 2 , 

## CO 2 , 

## NO, and CO concentrations were measured using SCAQMD Method 100.1. These measurements were made with one of Delta ' s mobile emission measurement laboratories. The system consists of a stainless steel or glass probe , heated Teflon line , moisture removal system , sample pump, sample filter , unheated Teflon line, and individual component analyzers
. The measured concentrations are averaged over each sampling period , then corrected for system bias and analyzer drift. All quality assurance procedures required by SCAQMD Method 100.1 were performed including pre- and post-test Calibration Error, Sample System Bias and Analyzer Drift. The sampling was performed using a 12-point traverse at each test condition
. For some test runs, the compliance test was performed concurrently with the Relative Accuracy Test Audit (RATA). In this case, data from the RATA was used to demonstrate compliance with the NO, and CO emission limits
.

R0410688 10 

# jJe!!i!A

## NO, concentrations were measured on a 0-5 ppm range . CO concentrations were measured on a 0-10 ppm range . CO 2 

## concentrations were measured on a 0-10 % range . O 2 

## concentrations were measured on a 0-20 % range . The measured concentrations are averaged over each sampling period , then corrected for system bias and analyzer drift
. The drift and bias corrected result were then used to calculate emissions in units required by the permit i ncluding ppm , ppm corrected to 15% O 2 , 

## pounds per hour, and pounds per million standard cubic feet of natural gas. 

## 3.2 

## NH3 BY SCAQMD METHOD 

## 207.1 Duplicate flue gas samples were collected non-isokinetically at each test condition using SCAQMD Method 207
. 1
. A 12-point traverse was performed during each NH 3 slip test. The sample gas is drawn through a glass probe , Teflon sample line , two impingers each containing approximately 100 ml of 0
. 1 N H 2 

## S0 4 , 

## an empty impinger , an impinger containing silica gel , and a dry gas meter. The optional nozzle and filter were not used since the units are natural gas fired
. The contents of the probe, sample line and the first three impingers are recovered and analyzed by SCAQMD Method 207
. 1 for ammonia concentration using the Ion Selective Electrode technique. One reagent blank sample, one DI water sample, and one field blank sample was analyzed
. Ammonia slip is reported in un its of ppm, corrected to 15% O 2 . 

## The tests were performed over a peri od of at least 60 minutes
. 

## 3.3 SOx BY SCAQMD METHOD 

## 307 . 91 O xi des of sulfur were measured us i ng SCAQMD Method 307-91
. Two fuel samples were collected in Tedlar bags and sent to Saybolt Laboratory for sulfur analysis as total reduced sulfur as H 2

## S
. 

## 3.4 ROG BY MODIFIED SCAQMD METHOD 

## 25.3 Sampling and analyses are performed using Modified SCAQMD Method 25
. 3 procedures. The sample apparatus and analyses are provided by Atmospheric Analysis and Consulting (MC) in Ventura California
. At each test condition , two (one paired sample , consist of 2 canisters) flue gas samples are ex tracted simultaneously from four pOints (one per port) in the stack through pre-cleaned (high temperature conditioned) stainless steel probes connected to an outof-stack flow controller , into stainless steel Summa polished canisters
. The flow controller i s set to fill the evacuated canister to a pressure of -400 mm Hg over a period of a period of one hour.

R041 0688 11

## Modifications to the Method 25
. 3 sampling procedures suggested or accepted by SCAQMD are: • Elimination of the in-stack filter • Elimination of the water vial portion of the 25
. 3 equipment • The final pressure in the Summa Canisters is maintained at between 

## 400 and 

## 500 mm HG 

## (10 -14 in
. Hg) absolute. Figure 3-1 presents a schematic drawing of the sample apparatus
. FIGURE 

## 3-1 MODIFIED SCAQMD METHOD 

## 25 . 3 SAMPLING APPARATUS



## Filter Probe

Flow Controller

R041 0688 

## 12

## The samples are analyzed for NMNEOC (Non-Methane Non-Ethane Organic Compounds, i.e
. Reactive Organic Compounds ROG) using modified SCAOMD Method 25.3 TCA procedures. Analysis consists of a fore-flush and back-flush of a gas chromatography (GC) column, followed by an oxidizer, a methanizer, and a flame ionization detector (FID)
. The GC separates the NMNEOC from other constituents of the samp l e (methane, ethane, CO 2 , 

## H 2 

## 0, O 2 , 

## N 2 , 

## etc.). The ox i dizer converts the NMNEOC to carbon dioxide
. The methanizer converts the resulting CO 2 

## to methane
. The methane content is detected by the FID as ppmc. ,bo n . Modifications suggested by SCAOMD to the Method 25.3 analytical procedures approved for MC under the LAP are : • Pressurization of the canisters to 900 mm Hg with Ultra High Purity (UHP) helium analyzed /certified to contain less than 0.05 ppmv of total hydrocarbons as carbon • Analyzing only the Summa canister fraction of the normal 25.3 sample
. No water vial used in sampling , no water vial analysis
. • Utilization of a larger (-2 ml) sampling loop • Development of a custom low level (0
. 1 - 5
. 0 ppmV propane) calibration curve • Performance of a Minimum Detection Limit (MDL) study • Determination of a Practical Ouantitation Limit (POL) from the MDL study Results are reported in parts per million by volume as carbon to 2 significant digits, corrected to 15% O 2 

## using the O 2 

## from the CEM measurements. The average of the results for the duplicate samples is compared to the Emission Standard for determination of the compliance status. Detailed procedures from SCAOMD concerning the application of the modified SCAOMD Method 25
. 3 to perm it condition D29
. 1 are located in the test plan in Appendix H
.



## R041 0688 13

## 3.5 PM BY SCAQMD METHOD 5
. 1 Particulate matter was measured using SCAQMD Method 5
. 1. SCAQMD Method 5
. 1 is cited as the table in Condition D29
. 1 lists District Method 5. District Method 5
. 1 measures total particulate
. This total particulate measurement could include material >10 microns
. Use of the cyclone as in 201A prevents overstating of PM 10 

## emissions if all of the PM emissions from these units are not PM, o. It was assumed for reporting purposes that the SCAQMD Method 5.1 total PM results will be used to determine PM 10 

## compliance
. A single test was performed at each of the three conditions ; 100% , 75% , and 50% load conditions
. Flue gas is drawn through a stainless steel nozzle , glass or stainless steel probe , unheated Teflon line followed by four impingers
. Impingers #1 and #2 contain approximately 100 ml of deionized water , impinger #3 is empty , and imp i nger 

## #4 contains silica gel. A backup filter is placed between impingers #3 and 

## #4 . The sample was collected isokinetically (90 - 110%) using a 24-point traverse at the exhaust stack location
. Each point was sampled for 10 minutes resulting in a 240 minute sample t i me per test. Figure 3-3 presents a diagram of the sampling system
.

R041 0688 14Temperature Sensor Probe

# ~

PitotTube



# / S ·T ype**P~otTube**



### R041 0688 

## FIGURE 

## 3-3 SCAQMD METHOD 

## 5.1 SAMPLE SYSTEM

Manometer


## Orifice Connecting 

### Teflon Tubing Filter Temperature



# : _________

# impinge~ _

# ~_en~or

Temperature Sensors



## Dry Gas

Meter

15 Water 

## , ------ -----**--~** Empty Silica Gel 

### Vacuum Line 

### Vacuum Gauge

# 4.0 RESULTS The test results are presented in the following tables : Table 

## 4-1 Table 4-2 Table 

## 4-3 Table 

## 4-4 Table 

## 4-5 Table 

## 4-6 Table 

## 4-7 NO " CO , Ammon i a (NH 3 ), 

## and 

## RaG -100% load PM results - 100% load NO " CO, NH 3 , 

## and 

## RaG - 75% load PM results - 75% load NO " CO , NH 3 , 

## and 

## RaG - 50% load PM results - 50 % load 

## SO , results Additional test runs were performed for some parameters to ensure that sufficient data were collected. Table 3-1 contains a test matrix with this informat i on . Additional data is presented in the Appendices , including all field data , laboratory data , and calculations
.



## R041 0688 16

### TABLE 4-1 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 4 NO., CO, NH 3, AND ROG 100% LOAD FEBRUARY 11, 2013 Test Number Run 1 Run 2 Average Limit Condition 106 MW 107 MW Test Date 

## 2/11/2013 2/11/2013 Start Time 10 : 06 11 :40 Stop Time 11: 19 12:54 Fuel Flow, hscfh 8,830 8,854 Stack Flow Rate , dscfm 383,018 357 , 556 Stack 

## 0, (%) 13.29 13
. 15 13
. 22 Stack NO, (ppm) 

## @ 15% 

## 0, 2.34 2.18 2.26 2.5 Stack NO, (lb/MMscf) 9.52 8.42 8.97 12.26 1 ') 

### Stack CO (ppm) 

## @ 15% 

## 0, 2.08 1
. 52 1.80 4 Moisture Fraction (%) 0.105 0.085 PPM NH3 (flue gas) 245 2.50 248 PPM NH3 

## @ 15% 

## 0, 1.90 1.91 1.90 5 Ib/hr NH3 2.52 240 2.46 Ib/MMscf fuel NH3 2
. 85 2.72 2,79 Stack ROG I1 ), 

### ppm 

## @ 15% 

## 0, 0.58 0
. 58 2.0 1) Collected as a simultaneous pair. 2) The 12
. 26 Ib/MMscf is a RECLAIM em ission factor , not a limit.

R0410688 

## 17

## TABLE 4-2 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENT I NEL UNIT 4

Test Number Condition Test Date Start Time Stop Time Fuel Flow , hscfh Stack Flow Rate , dscfm Stack O 2 , 

### % Stack CO 2 , 

### % Moisture Fraction , %

Gra i n Loading, 

## gr/dscf Grain Loading 

## @ 3% 

### O 2 

### Grain Loading 

## @ 15% O 2 

### Grain Loading 

## @ 12% CO 2 

### Mass Emissions, I b/hr 

### Emission Rate, Ib/MMscf 

## PM -100% LOAD FEBRUARY 11, 2013

S-4/STK-PM-100-1 107 MW 

### 2/11/2013 8:41 12 : 55 8 , 845 350,311

12.99 4.44 0
. 099 Particulate Emissions 0
. 0015 

## 0.0033 0.0011 

## 0.0039

4.38 4.95 (1) 11 bl/hr PM limit from SCAQMD Rule 475. (2) This is stated in the permit as an em i ssion factor.



### R0410688 18 Average

0
. 0015 

## 0.0033 0 .0011 0.0039

4.38 4.95 Limit



## 0.01

0 . 1 5.71(2)

## TABLE 4-3 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 4 NO., CO, NH 3 , AND ROG 75% LOAD FEBRUARY 11, 2013 Test Number Run 1 Run 2 Average Limit Condition 81 MW 80MW Test Date 2/11/2013 2/ 11 /2013 Start Time 15 :45 17 : 10 Stop Time 16 : 52 18 : 19 Fuel F low , hscfh 7 , 018 6,961 Stack Flow Rate , dscfm 304 , 102 311 , 648 Stack 

## 0, (%) 13 .8 1 13.80 13 .8 1 Stack NO, (ppm) 

## @ 15% 

## 0, 2.07 2.30 2
. 18 2.5 Stack NO, (lb/MMscf) 7.84 9.01 8.42 12
. 26 1 ') 

## Stack CO (ppm) 

## @ 15% 

## 0, 1.02 1.03 1
. 03 4 Moisture Fraction (%) 0
. 094 0
. 073 PPM NH 3 (fi ue gas) 1
.22 0
. 98 1
. 10 PPM NH3 

## @ 15% 

## 0, 1.02 0
. 81 0.92 5 Ib/ hr NH 3 1
. 00 0.82 0.91 Ib/MMscf fuel NH3 1.42 1
. 18 1 .3 0 Stack ROG ( 1), 

## ppm 

## @ 15% 

## 0, 0
. 56 0
. 56 2.0 1) Collected as a simultaneous pair. 2) 

## The 12
.26 Ib/M Mscf is a RECLAIM emission factor. not a limit.

R041 0688 19

## TABLE 4-4 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 4

PM 

## -75% LOAD FEBRUARY 

## 11, 2013 Test Number S-4/STK-PM-75-1 Average Limit Condition 81 MW Test Date 2/11/2013 

## Start Time 14:48 Stop Time 18:56 Fuel Flow , hscfh 6 , 974 Stack Flow Rate , dscfm 336 , 734 Stack 

## 0" % 13
. 83 Stack CO" % 4.05 Moisture Fraction, % 0.092 Particulate Emissions Grain Loading, gr/dscf 0.0004 0
. 0004 Grain Loading 

## @ 3% 0, 

## 0.0010 0.0010 0.01 Grain Loading 

## @ 15% 

## 0, 0
. 0003 0
. 0003 Grain Loading 

## @ 12% CO, 0.0011 0 . 0011 0 . 1 Mass Emissions, Ib/hr 

## 1.12 1.12 11(1) Emission Rate, Ib/MMscf 

## 1.60 1.60 5.71(') (1) 11 

## bl/hr PM 

## limit from SCAQMD 

## Rule 475. (2) 

## This is stated in the permit as an emission factor.

R0410688 20 

# !!.t lla 

# !:"

### TABLE 4-5 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 4 NO., CO, NH 3, AND ROG 50% LOAD FEBRUARY 12, 2013 Test Number Run 1 Run 2 Average Lim it Condition 55 MW 55MW Test Date 

### 2/12/2013 2/12/2013 Start Time 11 : 58 13:30 Stop Time 13 : 07 14:39 Fuel Flow , hscfh 5,337 5,341 Stack Flow Rate, dscfm 270 , 908 267,286 Stack O 2 

### (%) 14
. 27 14.26 14.26 Stack NO x 

### (ppm) 

## @ 15% O 2 

### 2.16 1.86 2.01 2
. 5 Stack NO x 

### (lb/MMSCF) 8
. 97 7.61 8
. 29 12.26(2) Stack CO (ppm) 

## @ 15% O 2 

### 0
. 32 0.38 0
. 35 

## 4 Moisture Fraction (%) 0
. 086 0
. 082 PPM NH3 (flue gas) 0
. 88 0.98 0
. 93 PPM NH 3 

## @ 15% O 2 0.78 0.87 0.83 5 Ib/hr NH3 0.64 0.71 0.67 Ib/MMscf fuel NH3 1.20 1.32 1
. 26 Stack ROG(1), ppm 

## @ 15% O 2 

### 0.55 0.55 2
. 0 1) Collected as a simultaneous pair. 

### 2) The 12.26 Ib/MMscf is a RECLAIM emission factor, not a limit.

R0410688 21

## TABLE 4-6 COMPLIANCE TEST RESUL T S CPV SENTINEL ENERGY PROJECT SENTINEL UN I T 4

PM 

## -50% LOAD FEBRUARY 

## 12,20 1 3 Test Number S-4/STK-PM-50-1 Average Limit Condition 55MW Test Date 2/12/2013 

## Start T i me 11 :45 Stop Time 15 : 52 Fuel Flow , hscfh 5,354 Stack Flow Rate , dscfm 241,434 Stack 

## 0 " % 14.23 Stack CO" % 3
. 79 Moisture Fraction , % 0
. 079 Particulate Emissions Grain Loading , gr/dscf 0
. 0007 0
. 0007 Grain Loading 

## @ 3% 

## 0, 0.0018 0
. 0018 0.01 Grain Loading 

## @ 15% 

## 0, 0
. 0006 0.0006 Grain Loading 

## @ 12% 

## CO, 0.0022 0
. 0022 0.1 Mass Emissions, Ib/hr 1.42 1.42 11111 Emission Rate, Ib/MMscf 2.65 2.65 5.71 1 '1 (1) 11 

## bll hr PM 

## limit from SCAQMD 

## Rule 475
. 

### (2) 

## This is stated in the permit as an emission factor.

R0410688 22

# jJell**~**

### R0410688 Test Number Condition Test Date 

## SOx, Ib/MMBtu gr H,S/1 00 

## sci TABLE 4-7 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 4 SOx FROM FUEL ANALYSIS FEBRUARY 22,2013 Average

100% 

### 2/22/2013

0.00002

0.009 Limit

0.06 0.25 (1) (1) 0.25 H,S/100 

### sci sulfur content limit is based on annual average of monthly sample results.



## 23

## 5.0 DISCUSSION AND TEST CRITIQUE Testing was conducted according to the test plan and reference methods
. All tests demonstrated compliance with the permit limits
. The following should be noted: • Two runs were conducted for NO, and CO at the 100% , 75% 

## and 50% 

## load conditions to ensure that sufficient valid data were collected
.

R0410688 

## 24

## APPENDIX A QUALITY ASSURANCE

R041 0688 A-1

## Appendix A . 1 Quality Assurance Program Summary

R041 0688 

### A-2

## QUALITY ASSURANCE PROGRAM SUMMARY 

## Delta Air Quality Services , Inc
. is committed to providing emission related data which is complete , precise , accurate , representative , and comparable
. Delta ' s quality assurance program and procedures are des i gned to ensure that the data meet or exceed the requirements of each test method for each of these items. The quality assurance program consists of the following items: • Assignment of an Internal QA Officer • Development and use of an internal QA Manual • Personnel training • Equipment maintenance and calibration • Knowledge of current test methods • Chain-of-custody • QA reviews of test programs Assignment of an Internal QA Officer : Delta has assigned an internal QA Officer who is responsible for administering all aspects of the QA program. Internal Quality Assurance Manual : Delta has prepared a QA Manual according to the guidelines issued by EPA. The manual documents and formalizes all of Delta ' s QA efforts
. The manual is a "living" document which is revised as Delta adds capabilities and procedures. The QA manual provides details on the items provided in this summary . Personnel Training : Personnel training is essential to the production of high quality test results
. Delta's training programs include : • A requirement for all technical personnel to read and understand the test methods performed • A requirement for all technical personnel to read and understand the Delta QA manual • In-house training • Quality Assurance rneetings • Attendance at EPA sponsored training courses • Maintenance of training records
. Equipment Maintenance and Calibration: All laboratory and field equipment used as a part of Delta's emission measurement programs is maintained according to manufacturer's recommendations
. A summary of the major equipment maintenance schedules is summarized in Table A-1. In addition to routine maintenance , calibrations are performed on all sampling equipment according to the procedures outlined in the applicable test method
. The calibration intervals and techniques for major equipment components is summarized in Table A-2
. Knowledge of Current Test Methods : Delta maintains current copies of EPA , ARB , and SCAQMD Source Test Manuals and Rules and Regulations
. Delta personnel coordinate, attend , and present papers at emission testing related conferences
. Delta personnel maintain memberships in the Air and Waste Management Association and Source

R041 0688 

### A-3

## Evaluation Society
. Delta personnel continually work with industry and regulatory agenc i es in monitoring and developing new methods and rules. Chain-of-Custody: Delta maintains chain-of- custody documentation on all data sheets and samples
. Samples are stored in a locked area accessible only to Delta source test personnel. Data sheets are kept in the custody of the originator, program manager, or in locked storage until return to Delta's office
. Upon return to the office , copies are made and stored in a locking file
. The original data sheets are used for report preparation and any additions are initialed and dated
. OA Reviews: Every Delta report is reviewed by someone separate from the report author. The reviewer is selected based on knowledge of the test methods used and the source tested. Periodic field , laboratory , and report reviews are performed by the OA Officer
. Test plans are reviewed to ensure proper test methods are selected and reports are re v iewed to ensure that the methods were followed and any deviations from the methods are justified and documented
.

R0410688 A-4

## TABLE A-1 EQUIPMENT MAINTENANCE SCHEDULE Equipment Pumps

Flow Meters Sampling Instruments Acceptance Limits 1 . Absence of leaks 2. Ability to draw manufacturers required vacuum and flow 1
. Free mechanical movement 1
. Absence of malfunction 2
. Proper response to zero, span gas Integrated sampling 1
. Absence of leaks tanks Mobile van sampling 1. Absence of leaks system
Sampling lines 1. Sample

R041 0688 degradation less than 

## 2 % Frequency of Service Every 500 hours of operation or 6 months , whichever is less Every 500 hours of operation or 6 months , whichever is less As recommended by manufacturer Methods of Service 1. Visual inspection 2
. Clean 3
. Replace parts 

## 4 . Leak check 1. Visual inspection 2
. Clean 

## 3 . Calibrate As recommended by manufacturer Depends on nature of 1
. Steam clean use 2
. 

### Leak check Depends on nature of 1
. Change filters use 2
. Change gas dryer 

## 3 . Leak check 

## 4 . Check for system contamination After each test series 1
. Blow dry , inert gas

A-5 through line until dry
.

## TABLE A-2 MAJOR SAMPLING EQUIPMENT CALIBRATION REQUIREMENTS Sampling Equipment Calibration Frequenc y Calibration Pro ce dure 

### Acceptable Calibration Criteria Continuous Analyzers 

### Before and after each 3-point calibration error < 

### 2% 

### of analyzer range 

### test day test Continuous Analyzers 

### Before and after each 2-point sample system < 

### 5% 

### of analyzer range 

### test run 

### bias check Continuous Analyzers 

### After each test run 2-point analyzer drift < 

### 3% 

### of analyzer range 

### determination CEMS System Beginning of each da y leak check < 

### 1 in . Hg decrease in 5 

### min
. at> 20 in
. Hg 

### Continuous Analyzers Daily 3-point linearity < 

### 1

### % of analyzer range NO , Analyzer Daily NO, -> NO converter > 

### 90% 

### efficien cy S-type pitot tube Semi-annually 

### Dimensional calibration Meet dimensional criteria of Method 2 S-type pitot tube Annually Wind tunnel calibration 

### Defined in Method 2 S-type pitot tube Prior to each project Visual inspection Meet dimensional 

### criteria of Method 2 

### Differential Pressure Semi-annually Correction factor based +/- 

### 5% 

### Gauges (except for on 5-point comparison to manometers) 

### standard Differential Pressure 

### Bi-monthly 3-point comparison to +/- 

### 5% Gauges (except for 

### standard, no correction manometers) factor 

### Manometer Semi-annually Clean and replace fluid 

### Barometer Semi-annually Adjusted to mercury-in- + /- 

### 0.1 i nches Hg glass or Nat iona l 

### Weather Service Station Dry gas meter Semi-annually Calibration check at 4 +/- 2% flow rates using a NIST

traceable standard Dry gas meter Bi-monthly Calibration check at 2 +/- 

### 2%,1 of semi-annual flow rates using a NIST factor

traceable standard Dry gas meter orifice 

### Annually 4-point calibration for LlH@ 

### Temperature sensors Semi-annually 

### 3-point calibration vs. +/- 

### 1 . 5% NIST traceable standard

R041 0688 

### A-6

## Appendix A.2 SCAQMD and CARB Certifications

R041 0688 

### A-7

# South Coast Air Quality Management District 21865 Copley Drive, Diamond Bar, CA 91765-4178 (909) 396-2000 • www.aqmd.gov 

## December 19,2012
Mr. Robert 

## A. Finken Delta Air Quality Services, Inc. 1845 N . Case Street Orange, CA 92865 Subject: LAP Approval Notice Reference # 96LA 1220 Dear Mr. Finken: We completed our review ofthe renewal application you submitted for approval under the South Coast Air Quality Management District's Laboratory Approval Program (AQMD LAP). We are pleased to inform you that your firm is approved for the period beginning January 31, 2013, and ending January 31, 2014 for the following methods, subject to the requirements in the LAP Conditions For Approval Agreement and conditions listed in the attachment to this letter: SCAQMD Methods 1-4 SCAQMD Method 100.1 SCAQMD Methods 25 . 1 and 25.3 (Sampling) SCAQMD Methods 5.1,5.2,5 . 3, and 6.1 SCAQMD Rule 1420

- (Lead) Ambient Sampling USEPA CTM-030 and ASTM D6522-00 Thank you for participating in the SCAQMD LAP. Your cooperation helps us to achieve the goal of the LAP: to maintain high standards of quality in the sampling and analysis of source emissions
. You may direct any questions or information to LAP Coordinator, Glenn Kasai. He may be reached by telephone at (909) 396-2271, by facsimilie at (909) 396-2099, or via e-mail at gkasai@aqmd.gov.

RE : GKlgk 

## cc: Mike Garibay Glenn Kasai 121218 LapRenewal.doc

# ~**R,dyF4~. s,~**  Laboratory Services & 

## Source Test Engineering

# State of California 

# Air Resources Board Approved Independent Contractor 

# Delta Air Quality**Servic~s~** 

# Incorporated



# . This is to certify that the company'listed above has been approved by the AirResources Board to conduct comp. nance testing pursuant to tHle 17, California**Goqe of-Regulatlons,~ection**  

# 91207 until**Jun~** 

# 30, 

# 2013: for thOse 

# teSt methods ' Ii$ted below:

. ARB 

# s'll'itrce
. TestMethods: I 

# 1-; 2. 3,

# 4;**5,** 6,8,17,20, SQl 100 (CO,**~,** 

# NO.. 

# Qz, 8( 2) . .


## Alberto**Aya~.** 

## Ph.D. , M.S.E. Chief, Monitoring and Laboratory Division

# State of California 

# Air Resources Board Approved Independent Contractor 

# Delta Air Quality**Servic~,** 

# Incorporated This is to certify that the company ' listed above has been approved by the Air Resources Board 'to tonducleoil-tpl\ance testing pursuant to title 17, California Coqe of ·Regulatlons. section 91207 until June 30, 2013: 

# f-or those 

# test metf\o'ds Hl?ted below:

, ,

ARB Source,Test Methods: " , 1-,2,3; ,4,-5,6,-8, 17,**20~.5qr**



## 100 ' (Co., COz, NO.. 

# Qz, 

# 80 2)


# . 

# ... . -


## Alberto**Aya~,** 

## Ph.D" M.S.E, Chief, Monitoring and Laboratory Division

## Appendix A.3 Equipment Calibration and Calibration Gas Certificates

R041 0688 A-8Pnlxair 5700 SOllth Alameda Street Los Angeles, 

### ell 90058 DocNumber 000045707 Tel: (323) 585-21 54**Fax~714)** 

### 54 i ·6689 r(jVPIl): F22012 

# CERTIFICATE OFANALYSIS / EPA PROTOCOL GAS {IISfO , CA /-,1/1)",, ·**10/~1I20 '7.**  

### Delta Air Quality 1845 N. Case 

# st. Orange, CA 92865 {Jrawir Ord e r Numher: 21912990 OWoml!r P
. 

### 0. 'vI/mInI"" 04138286 ( 'us/ollle/'Referel1ce .Numh e r: I'wl 

### ::" ",he,.. L V NICDOXI (e AS 109:>3Cib06 7050**():I/I;kI'S~I'lc** & ()lrIk! AS CCA!J90 

# OJ...

# q .q 8**r-E-xp- -ra-t-io-n-D-at-e-----l-l-/l-:-~2-ro-f;:..** **·** 5_le_d_C_{)_I1_C_e_It_I_rt_rl_i_o_n_:
___

# N_IS_T'_:_':_~_:_'**~_;:_~'_~'_"_"_'_""_'''....,JJ''':** 

# r**~** 

# ",

# q, Cyirnder Number: CC72997 Analytical Uncertainty: 

# \...V'I-t**~** 4.96 % CARBON D I OXI()E ± 1 % :'000**~s;g** 

# 1l1l7 9.9B 

### % OXYGEN ± 1 

### % 

# cc. 7.2....,., Balance NITROGEN 

# €f.f 

# 11/1'**11~~ r----------------1**  Cel'fifca fi(}11 II!formflfion: Certification Date : 11116/2012 Term: 3b Months Expiration Date : 11/1612015 ThiS cylinder was certified according to the 1997 EPA Traceability Protocol, Document #EPA-600/R -97 /121, using Procedure G1 Do Not Use this Standard If Pressure is less than 150 PSIG Allalytictll Du((l: (H Nc frmn r. c Sta ndDrd i'
.Zero G,15. C' G DS CiJndid<Jtc)

, . Component: CARBON DIOXIDE f{cq ucsl <..>O (;on<..or1ll
. ,llon**~** % C': I\, j,cd COr1CCnlIHl lOl l -1 96 % Ilistrument US .)o.l Il -;r ;t n VI/\ · . 1r"l !;I!'J**~80{O't\** I\n <lIf\K: , I M Olhoo NIlII< L.nl Mullipoint Ca libration· 11/11 00 12 First Analysis Data: 

### z , 0 R' £i
. 15 R ' :iY; 

### z, 0 

### z· 0 

### c: 

# <,. UQM; % 2. Component; OXYGEN H, quested**COI\cel'l~rat.o n:**  C",1iflCd Con ccn lrat i on Instrumenl Used Ana l ,l l n! Ml.lhod 1. :\S I Mullipoinl Calio ral ion
. First Analysis Data : Z, 

### o Oale: C, 

# ",,, Conc· C: 

# '''' Conc, R,**!>. ~**  Conc: Mean Test Assay :

1 0 %**9~8** % O)(YMAT5[ I'AHAMAGNI ·l IC '1/1 1 //01? Date 9.98 Conc: 11/12/2012 -1.95 -1.96 < . 913 -1,96 "!.

99 a R: lO U 1 R ; 1001 Z; 0 C: 9.98 Cone; 9 . 98 Z, 

### o 

### c, 9,J8 UOM: HolofCl)Cf)**Stlln~;lfd** T l pe He! Sid C :;l l ndor it B el Std Cone :**I~cf** fild i"raceab l e to**sr~ M**  /J St{M Samp l l) II S){M Cyi.ndcr It Second Analys i s Data : Z 0 R, 0 R, 0 Z, 0 Z, 0 C, 0 GM1S CC2<13320 5.15",.**v~ .**  1<,7-1b 1- I' - 3? CI\t.Ol-!G45 Date: C, 0 Cone: C, 0 Cone: R, 0 Cone: UDM : % Moan Test Assay : Hdercncc Slono urd T ype Het Sid Cytind<!r # . Her Sid , CMt; H d Std. Tracc ab lo 10 SHM # : SHI , I Samp lo ;l SHM Cyl i nder II
. Second Analysis Data: 

### z: 0 R, 0 R, 0 Z, 0 

### z, 0 

### c, 0 

### c C· R' GMIS SA159?!;. 1001% 7658a ,2·;'>0

- 8 CI M·.{)()6696



### o 

### o o Dalc· Cone : Cone : Cone: 0 0 0 0"



### o o o UOM: '\ Mean Tesl Assay; 0 % 1 -10cu fI

" Analyzed 

### bY·'" 

# T '\', "J
. ,"'8 % 

# R, 10 C, 7[2C OO' 9 . 98
RO I D1 a aywood Certified by:

# --s==l.-----~~ Shameela Jiffrey 

# ,

Info rmlll i o " conta in ed nero;n hJ5 boen prcpawd ;:I t your request b y qualified experts Wi thin Pm ""'1 rlisl n bu \IOIl. In e Wh i le we be ll cl'o tha t Iho Informat i on is accurate**.\I th~** **l** Iho lim its o f ii lf) .1 0il ;, IrQll met hod s {) oployrd and I S compl.-lc 10 II>!! oxlonl of the speCIfiC ana ty ses perforrnoo. WQ nlSKn no w W In!y or represemalion ,] s to tho**suilab~ ly**  of 1m , usc of the ,nfOlm .1 1Ion for ,my**purpo~o** Ill , . H1fmmal io**i~** of:owd w llh lhe undo rSlil ndl n g thai ;Jfl Y us c ot tho IIl ror mo l icm is (lit ho solo discretIon and risk of I ho uscr In n o ove nt shal l the ), ablii!, of Praxillr D is tnbuliofl. Inc
..**ans~ng** oul 01 tim 

### o w 0' "" ,,101m"'"", coo " ",,,,0 '"ro"**,,~""m** 

# ,," ""obe",,, ,,, P'0"""9 M"**",'~m "'oc**  

# I**~ ~** 

# / 7_ I 2/**~** 

# I

# Hffli!6PRAXAIR

DocNumber: 000036684



# - - -- -**.....,,~ -----c--..:.;.:..:.:.:_;---_~** 

# .•**~.~, ~a~**  

### Praxair 5700 South Alameda Street Los Angeles, CA 90058 Telephone: (323) 585-2154 Facsimile: (714) 542-6689 

# CERTIFICATE OFANALYSIS/ EPA PROTOCOL GAS Customer & Order Information: Fill /Jail! : 312312012 -,
DELTA AIR QUALITY SERVICE INC Praxair Order Number: 19799780 Customer P. 

### 0. Number: 

### GARY Customer Reference Number: F'(f/ Number: Nt CD9.503E-AS Lol Number; 109208304 ORANGE CA 928654 Cylinder Style & Olltlet: AS eGA 590 

# ,,,., 11,90**~'"** 

# 'I., t,/ Expiration Date : Cylinder Number: 9,62 18,90 

### % % 

## Certified Concentration: 4/4/2015 CC199067 CARBON DIOXIDE OXYGEN**('}fil~(er** l'rt ' : lIrc & I'oll/me : NIST Traceable Analytical Uncertainty :

± 1 

### % ± 

### 1 

### % 

# : c ,qqO,7 Balance NITROGEN

# !,y.ff)tf/8+"~ 

# ___ -------l Cerf/fcmiotl Iliformatioll: 

### Certification Date: 4/412012 Term : 36 Months 

### Expiration Oats: 4/4/2015 2000 psig

This cylinder was certified according to the 1997 EPA Traceability Protocol, Document #EPA-600/R-97/121, using Procedure G1 Do Not Use this Standard 

### if Pressure is less than 150 PSIG PGVP 1.0.# F22012 Analytical Data: (R:Referef1ce Standard, Z-::.Zero Gas, C:Gas Candida/e)

1 . Component : CARBON O!OXIDE Requested ConcentraUo n : 9.5 % Certified Concentration: 9
. 62 % Instrumenl Used : Si emens Ultramat SE SIN A 12 -730 Analytical Method' NOtR Last Mult i po in t Ca l ibration : 311112012 First Analysis Data: Date: 414/2012 

# I 96, 

### z. 0 R. 10.06 C. 9.62 Cone: 

### z. 0 C: 9
. 62 Cone: 9.62 9
. 62 

# I Z. 0 C. 9.62 R: 10 .08 Conc: UOM: 

# .. Mean Test Assay: 

# I

R. 10.0.



# - - ...

# -- 9
. 62 %



## -- - -- -' 2. Component: OXYGEN Requested Co ncenlration. 19 % Certi fied Concentration : 18
. 90 % Instrument Used : OXYMAT SE Analytical Method PARAMAGNET IC last Mull ipo i ni Ca libration: 311112012 

# f ;Ir;

### AnaIYSIS**;-a~ --** **-- --** **D-; ;;** **~';~~~ ---l**  I Z: 0 R: 20 C: 169 Cone: 1B
. 9 

# I ! R: 20 Z; 0 C: 18
. 9 Conc: 18. 9 Reference Standa rd Type : Ref
. Std. Cyltnder # : Ref
. Std. Cone: Ref
. Std. Traceable to SRM fI : SRM Semple fI : SRM Cylinder # . GMIS SA1471 10
. 08% vs. 16750 6-F-Sl CAL014538 

# i Second Analysis Data: Date:

# !~**~.~**

Z: 0 C: 0 UDM: 0", 

## _. '- 

# ---- - c: C. R. 

### o o o Conc: Cone: Cone: Mean Test Assay: Reference Standerd Type : GMIS Ref. Std. Cylinder # : SA12B32 ReI
. Std. Cone: 20.00% Ret Std
. Traceable to SRM # : 2659a SRM Samp le # : 71 - 37-B SRM Cylinder # . CLM-008734
: Second Analysis Data: Date:



## z. 0 R . 

## i R: 0 Z: 

# , 0 0 

### c. C. 

### o o Conc : Cone: 

### o o o 0%



### o o 140 cu. It.



# I

I Z: 0 C; 18
. 9 R: 20 Conc: 18.9 I' I UOM: % MeanTOstAssay : 16
. 9% Z: 0 C: 0 

# , I UOM : % R: 0 Cone: 0

# ~~**n** Test AS8
. aY

_ :

_ _ _

# ~J Analyzed by: Certified by:**~** ___ _ 

# ") Shameela Jiffrey

Infonnation contained herein has been prepared al your request by qualified experts within PrB:l:a ir Dis tri bu tion, Inc , VVhil e we believe th at the InfOfmat i on is accurate wi thin the limBs of the analyt i ca l methods employe{j and i s c:ompJele to the eJdef11 of the spec ific analyses performed. we make no warranty or representat ion as to the suitabi lity of the us e of the I nf ormation for any purpose. The i nformaHon Is offered with the understand i ng [hat any use of the information is at the sole discretion and risk of the user In n o event shai l lhe liab ili ty of Praxa i r O i stnbulion, Inc. , arising out of the u se of the informa Hon con lained here in exceed the fee established for pro .... i d i ng s uch information
. 

# c(- 

# --/7 

# -/2- Y

# !fff~PRAXAIR Praxair 5700 South Alameda St reet Los Angeles, CA 90058 DocNumber ; 000046490 Tel : (323 ) 585-2 1 54 Fax : (7 1 4) 542-6689 PGV PID : F22012 

# CERTIFICATE OFANALYSIS/ EPA PROTOCOL GAS ClIsto 

# • FIJI Ou r. " ""212012 

### Delta Ai r Qua li ty 1845 N
. Case St. Orang e , CA 92865 

# - Praxair Order Numbe r : 22054687 Customer P . 

### 0. Number: 04159883 

### C

ustomer Reference Numb er: }Jorl 

## Nil"''''',. !.mN""'''''r: N I N02
. SMZ1 E-AS 109231805 C, : ylint1c r**l> 'l~**  & O llfl ol

: AS eGA 660

# NO~".~Z**Cc.'~S2.**

# ~/"IIO/l Expirat i on Date : Cylinder Number : 2 . 52 ppm Balance

NOx= 

### Certified Concentration: 12110/2015 CC7352 NITRIC OXIDE (as NOx ) NITROGEN Iylllltkr**n.·~ I1"** **"** & 1'",1,,111:: N IS T Traceable Analyt ical U ncert ai nty:

±2 %

NOx for Reference Only Cerli/catiOlt Inf o rmatio n : Certificar ion Date : 12/ 10

/20 12 Tenn : 36 Months Expira tion Dale : 12/10/2015 2000 ps i g

This cylinder was certified acc ord in g 

### 10 Ihe 1997 EPA T race ability Protocol, Document #EPA-600/ R-97/121, using P roce dure G1 Do Not Use this Standard if Pressure is less than 150 PSIG 140 cu . ft.



### rNO]= 2.48 ppm;for re fe rence only, The cert ification expiration date**i~ ,**  assigned using the May 2012 re vision o f the EPA Traceability Protocol document. Allolyti cal Dntu: {R= Reference SI<Jndard, 2"Zero Gas, C :; Gas Candi da te } 1
. Component: NITRIC OXiOE t as NOx) RequOlltao Concsn t ration
. Cert ified Concentrat i on : Instrument Used
. Ana lyl i cel Method : Last Mu l tipo i nt Calibrat i on .

### r;**AnilIY S~** **---** 

# I**~** 0 R 968 I R 968 Z 0 I 

### z : a C : 2
. 51

### O!,,: ppm Analyzed by : 2 5ppm 2
. 52 ppm Th e rmo Electron 4 2C SIN 516112467 Chemilum in e scence 1111 1120 1 2 Oalo: t tf2S120t2 C , 2 . 51 Con c: 251 C , 2 . 51 Cone : 2 . 51 R, 9
. sa C lme: 2 . 51 Mo an Test Assay : 2 .5 1 ppm 

# l I I Referenc e Siandard Type : Ref
. Std
. Cy linder # , Ref Std
. Cone: Ref
. SId. Traceab l e to SRM II : SRM Sample 1# : SRM Cy li nde r N :
Z : 0 R: 9 . 88 R: 9 . 88 Z : 0 Z: 0 C : 2
. 53 U OM : ppm G MI S CC335699 9sa ppm 262ge 5Q.G · l09 FF31631 Date: 2
. S3 Con e: 2
. 53 Cone : 9
. 88 Cone ; 12!J12012 2
. 53 2 5 3 2 . 53

### ~O**AA 'Y** **;' ~'~~** **;**



# - - -- -----,...<:::-=- ---

I nforma tiQr1 conta i n ed herein has been prepared at yo ur request by qua lified experts within Praxeir Disl r ibu tlon , Inc:
. While we believe that the information 1& accu ra lo within the limits of the analytical me thods employed and is com plete to the e xten t 01 the spec i lic: analyses pericrmed , we make no Wllrra nty or representation as to the su il abWty of the use of th e in f orma t ion for sn y purpose . Th e information i s o ffered w ilh the understanding that any use of tho I nformation 1& at the $ol e discretion and risk o f t he user , In no event shall the liabi lity of P(8)(a i r DiSlribut i Or'l, Inc. , arising out o f the use of lho inform at ion con ts in od herein exceed the f ee estab lis hed for providing SUCh I nfo rmation "? I**,, ~**  

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DocNumber: 000038766 I'
.. axa;r 5700 South .\Inmcd<l Sirect Los Angeles. CA 90058 Telephone : (323) 585·2151- Facsimile: (714 ) 542-6689 

# CERTIFICATE OFANALYSIS / EPA PROTOCOL GAS

CA 413012012 

### Delta Air Quality 1845 N. Case 

# st. Orange, CA 92865 Praxair Order Nu m ber: 20155225 Customer P. O. N um ber: 03870012 ells/omer Reference Nllmber: 

### ,'"n ,Vllmh.,.. l,tJ/ ,yUh " ", ' ,. : (')'limkr**Sl yl~** **~** Gillin : NI N04
. 7MZE -AS 109217109 AS CGA660

# No~tf·it, 

# CC**,~.",** 

# 'J 

# 09 

# fy.ros/f,cfp Exp iration Date: Cylinder Number : 4 . 82 ppm Balance 

### Cerl!fied Con ce ntration: 5/2412014 CC362309 NITRIC OXIDE { as NOx) NITROGEN NIST Traceable Analytical Uncertainty :



### ± 2 %

Cali/cOli()" In/ormation: Certification Date: 5/24/2012 Term:**~4** Months Expiration Date: 5/24/201 4 2000**ig**

This cyli nde r was certified acco rd ing to the 1997 E PA Traceability P ro tocol , Document**#EPA~600/R~97/121,** using Procedure G 1 Do Not Use this Standard if Pressure is le ss than 150 PSIG INO]=4
. 80 ppm ( f or reference on l y). PGVP 1.0 .# F22012 Analytical Dato : (RoBe/cronce SI<Jndard , 7. . Zero Gas, C"'Gas Candida/e) 1 , Comp o nont : N I TR IC OXIOE (as NO)!:) Requested COOC l mtrllilon Cort<ll .;- d Conc l mtr;l\l on Instrum e nt Usoo**,r ~tlc,,1**  MO l hod : l. 1St l
. tulliPO ll11 Calibration ' First Analysis D ata : 

### o R: 10 . 03 Z: 0 UOM: ppm R : 10,03 Z : 0 C: 4 ,61 4.7 ppm <l
. 82:pp m Tnermo Etcclron <12C SIN 5181 12467 Cncmi l uminesccnce 5/1012012: Oate: :.Jl1 i 20 12 C, ' .86 Cone : '.M C, 4 ,61 Cone: 4 ,6 1 R, 1 0,03 Cone: <1,81 Mean Test Ass il y : 4,83 ppm Analyzed**bY ~** 

# ~ Roference Standard Type: Rof Std , Cylinder 1# : Ref Sid Cone: Ref. Sid Traee abie 1 0 SRM II SRM Samplo# SRM Cylinder # : Second A natysis Data : Z, 0 R, 10,03 C, R, 10.03 Z, 0 C , Z, 0 C, 4.133 R, G MIS CC3352 10.03 ppm 2629a 50 · G·109 F F 316 3 1Dato: 4 . 81 Cone: 4 , 82 Cone: 1003 Cone: UOM: p pm M8an Test Assay : Certified by ,

# ~ 5fl{V ?012 

# '" 4 . 82 4 . 83 482 p prn

# ~ \ 40 cu. II

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. 000047511 rd (3n) :'IRS':! 15 i l'iI-,;:( i 11)**:q2-{,() ~"**  [l( ; V]'!!) : F2 2 0 1 3 

# ('ERTIFICATE OF ANALYSIS / EPA PROTOCOL GAS ('11 .\"1(1 

### De lta A i r Qua li ty 1845 N. Case St. Orange , CA 9286 5 Prawlir Order ,\ ' l/IlIh(.T 223 55996 ('/Is/nine" V 0. .\'WI,/J1'r 

### 04 204 373 ("".\"/UIII,.I'**f«('r~'/"<.!I:cc** .', ' /111111<'1'

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# 6~r**D7/09f~~_B"_ anc** **TR _OGE_** **N** _____ -----'

Cr'I"(ifi'lIfilill**rorlllll'i ()** **II. '**  Certification Date " 1/91201 3 Term : 6 Months Expirdtion Oale 719/201 3 t:> .711:>o t / I
....• N1NX 'U 11 1 u .1 ? J

- , : )7 AS ;;,,}{) (lS

Th i s cy li nde r was certified accord i ng to t he 1997 EPA T rac eability Prt ,tocol, Docurnent**#EPA~600/R 97/121,**  us i ng P rocedure G1 00 N ot Use thiS Standard I f Pres s ure i s l ess than 150 PSIG [NO]=O,06 pprn : fo r refe r ence o nl y 1 Componunt :**r~lrrlOGEN** D I OXIDE (a5 NOx)**ih .-** **!"('~I <**  r ';on ', .n t,**~11** (;UI.1o.'1 (; ') f. :, 11,r;lh(m II": ;,1 le ,, 1 'J. ' 1111
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## " e, J ;If R**~) .1I**  Z, 1. : () c: UQM.**'~** III A n alyzed by -"l pp:n " O? ppm r 1. 'InC) 1' 1 . ;I (**,~** ,p,**IN** (J**~'r ·);** **"l::. ~'C**  CII!. n,lurnl rl()sc, 11<:('; lI1r '{)1;! Date: 1 '0l 1 "0 1 " C , , 01 Cone: ·1()1 C , -I.U :' Cone: 'ltl;> 

### eo 0 " C o ne' '1,j;.> MeilH Tns t Assay' -"lO ;'>ppm

# ~ 

# w U'CAWI Jack Fu HCJte em . '.' SI; l!I d .Id l , pe Hd SId C yh w1:Jr iI Hd Std Com: SIUI SHmpk , II SI.(n C hl1:::!' n**~** Second An-,Iysis Da la: z· " R, ' :G R, <llll; Z, {) Z, 

# , C. '10" UOM PJ)1Il C C· R ( ;MiS**CC:kx ~'**  !H ..I ppm

::., 1 :'0 C 109 I I ,H, ;:, ' Dale oj " ;'> Co n e: 1111 Cone: U W C " n e : Mean Te s t Assay: Certified b y**1~** ;'>')\3 " " 1 ' ,1**.** 0;.>

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# f!ff1!!lPRAXAlR Praxair 5700 South Alameda Street Los Angeles, CA 90058 DocNumber: 

### 000041947 Tel : (323) 585-2154 F4x :(7 14) 542-6689 PGYPID : F22012 

# CERTIFICATE OFANALYSIS/ EPA PROTOCOL GAS CuSIO 

### Delta Air Quality 1845 N. Case St. Orange , CA 92865 Praxair Order Number ' Custom er P. 

### O. Number: Customer Reference N umber: 21015531 

### 03998407 

# co '/·'19 Certified Concentration: Expiration Dale : 

### 212012013 CC325462 

# cc "':t '" 

# I!! •**~~.,**:llnder N 4 um

49

ber ppm 

# iI**~ ~** **~** 

# _ CARBON MONOXIDE 

# "''''/')(,w ""rlNl(mi)t;L" 1.01 N"mm:r: (")'lmdiU" SI) Ie**~** O"llel; Cyli" <l cr I' n'

, " ,l'IIrc & V()/lI m (" NIST Traceable Analytical Uncerta in ty:

±2% Balance NITROGEN

# ~~o/~~**-----------~** Certijcation Informalion: Certification 

### Date: 8/20/2012 Term : 6 Months 

### Expiration Date : 212012013 7/2 71201 2 NI C04
. 7ME-AS 109220904 AS e G A 350 2000 p s lQ 140 cu, fl

This cy li nder was cert ified accord i ng to the 1997 EPA Traceab ilit y Protocol, Document**#EPA 600/R-97/121,**  us i ng Procedure G1 Do Not Use this Standard if Pressure is less than 150 PSIG Analytical Data: (R=Re fc re nce Standard, Z"'Zero Gas , C"'Gas Candide/e)

1 . Component : CARBON MONOXIDE Requested Concentration Can in e<! Concentration Instr um ent Used
. Ana t yt l ca l Met ho d : L ast M ut1 1 pomt Calibration ! First Analys i s Data:



### z· 0 R, 84.3 R, 84.1 Z , 0 Z , 0 C, 369 UOM : pp m 1 7 pp m 4 I\$l porn Horibl) VtA -510 SIN 5 768760 15 NDIR 8111/20 12 Dale: 61712012 C, 368 Cone: 4 ,45 C, 37 Cone : 4 . 49 R, 84 Cone: 4.48 Mean Test Assay: 4.47 ppm Analyzed

## ~:¢/ Ref erence Slanda rd Type : GMIS ReI. SId. Cylinder /I : SA66B7 Ref. SId , Conc ' 10
. 2 ppm Ref
. Std
. Tra ceable to SRM /I : 1677 c SRM Sample II : 5-1-42 SRM Cy l inder 1/ X F oo2 1 43B

, Second Analysis Data : Date' 811512012

Z, 0 R, B4 . 3 C, 37 . 3 Cone' 

# ", R, B4A Z , 0 C , 37.4 Cene : 451 Z, 0 C, 37,3 R, 84.4 Cone : 45 UOM: ppm Mean Test Assay: 4 S1 ppm Certified 

### by :

I nfor ma t '(){1 conta i ned herein has been prepared <i t your request by qua l;ri od p.xpans wilh in**P(a~a (**  Distribution , Inc l/IIhile we**belie~e** that tho i nfo rma tion IS accurate wlth i(lthe li 'f , il s of the ana l] tic a l mothods employed and i s compiete to the**e~tef1t** of the specif ic analysos pertormed , we make no WtllTan t y o r rep r esentatio n as to the suitabi l tty of the use 01 tho i nfo rmat i on for any p u rpos e , Tho informat l oo i s offered w ith t h e underst and in g t h at any use of tho In format i on is at the so le d : screti on and risk of the u ser In no event shal l the liability 01 Pra:>:a ir D i stribut io n, Inc
. . ariSi n g out o / th e "" of Ih o 

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# ;0/ ' IDoc Number: 000041846 PnlXllir 5700 South Alameda Street Los Angeles, CA 90058 Tel: (323) 585·2154 Fax · (714) 542·6689 PGVPID F22012 

# CERTIFICATE OFANALYSIS / EPA PROTOCOL GAS CuMOI Fill Date' 712612012 

### Delta Air Quality 1845 N. Case St. Orange, CA 92865 Praxair Order Number: 20981153 Customer 

### P. 

### 0. Numb!!,.. 03994448 Customer 

### Reference Number: PWI Number" NI COR5ME·AS I, VI Nllm/>.!r; 109220812 Cyfmdu r Sryle,{ (JIII!..'I: AS CGA 350 

# Co 

# 'I,'/-, Cc. '311 

# ca

# ~('OI/1'/1 Certified Concentration: ryli"", : r**I'r~ssllu** <f: I**(}III"' '**  2000 psig 140 cu fl. Expiration Date: Cylinder Number : 9,47 ppm Balance 811612015 CC313840 CARBON MONOXIDE NITROGEN NIST Traceable Analytical Uncertainty:

± 

### 1 

### %

CertifcotiOlr1nformation: Certification Date: 8/16/2012 Term: 36 Months Expiration Date: 8/16/2015 This cylinder was certified according to the 1997 EPA Traceab i lity Protocol , Document #EPA-600fR-97/121, using Procedure G1 

### 00 Not Use this Standard if Pressure is less than 150 PSIG Analytical Data; (R=Reference Standard, Z=Zero Gas, C::.Gas Candidate)

1
. Component: CARBON MONOXIDE Requc$ted Concoolralion ; 9.5 ppm Certified Conccntrntion' 9 , ' 17 ppm Inslrumenl Used ' Hori ba VIA-510 StN 576876015 Analytical Method NDIR l ast Mult i po i nt Calibfation : 711112012

### ~~**IYSIS** Data

- -

Z 

# ° R 845 R 844 Z 0 Z 0 C 789 UOM ppm 

## _**~** 

## ____.____ -,---__ ,--_J Dale: 8/212012 C, 78.2 Cone: 9.44 C, 76.4 Cone: 9.47 R, 84.4 Cone: 9.54 Mean Test Assay: 948 ppm Analyzed by :

# ~ Shameela J i Hrey Reference Slano'ard Type ' Ref
. Std
. Cy li nder # : Ref. Std. Cone : Ref. Std Traceable to SRM Ii : SRM Sample II ; SRM Cylinder /I GMIS SAS68 7 10,2 ppm l677 c 5-1-42 XF 002 1 436 

# I**SeeOnd~aIYS! :-;;~** **---- -~** **Oate ~;;;;-** **l** 

# I Z 0 R 844 C· 783 Cone 942 

# I

Z: 0 C ; 78 . 7 R: 84 . 5 Cone: 9 . 49 1 

## I. R. " . 5 Z. 0 C 786 Cone
. 9 . 48**UOM _~p_m**  Mean Test**A~~ :.:.** ___**9. ~**  ppm 

### J Certified by:

Informa: i on conta i ned herein has been prepared at your request by qualified experts within Praxair Distribullon, lne Wh il e we believe thai the informat i on is accurale w ithin the lim l ls of the anal yt ica l methodS employed and is complete to the extent of the spec if ic analyses performed
. we make no walranty or represe n tation as t o the su itab i lity of Ihe use of the inforfTl<ltion fOI any purpose . The Iflforrnal i on is offered with the understanding thai any lJse Of thE! information I s :31 the sola ciscreti{)n a(ld ri sk 01 the user. In no event shalilhe liabiflly of Praxair Oist ri pUlion. Inc ., OIrising out of the 

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# J/f~PRAXAIR**.** Praxair Distribution, Inc. 5700 S. A lam eda St. Los Angeles, CA 90058 Te i: 323 - 585-2154 Fax : 714-542-6689 

### 10/22/20 12 

### Delta Air Quality 18 45 N
. Case St. Orange, CA 92865 

# - Praxair Order No. 

# 21690846 Customer Reference No
. P roduct LoVBatch No. 

# N109228006 Praxair Part No
. 

## NI 5.5CE.AS

Analytes Nitrogen Carbon Dioxide Carbon Monoxide Total Hydrocarbons Oxides of Nitrogen Oxygen Sulfur Dioxide Water Analytical In s truments:

Cylinde r Style Cylinder Pressure @70F: 

### Cylinder Volume: Valve Outlet Connection: Cylinder No (s). 

# CERT IFI CATE OF ANALYSIS Nitrogen, 

# 5.5 Continuous Emission Monitoring Zero Analytical Analytical**S~ecification** 

### Results**Pr nci~le**  

### >99.9995 % >99.9995 % N 

### < 1 ppm 

### < 0.019 ppm L 

### < 0,5 ppm 

### < 0.020 ppm L 

### < 0.1 ppm 

### < 0.05 ppm Q 

### < 0.1 ppm 

### < 0_0034 ppm U 

### < 0.5 ppm 

### < 0.5 ppm W 

### < 0.1 ppm <0.1 ppm 

### Z < 2 ppm < 1.1 ppm P Horiba Instruments Inc.-GA-360E-NDIR-Non-dispersive Infrared Analytical Acc ura cy 

## ± 10% 

## ± 15 % ± 

### 15 % 

## ± 15 % 

## ± 15 % 

## ± 15 % 

## ± 0.4 ppm Rosemount Analytical-NGA-2000-THC - Total Hydrocarbon Analyzer-FlO· Flame Ion ization Detector Thermo Environmental-42i-Nitric Oxide Analyzer-Chemiluminescence DeltaF-Nanotrace-Trace Oxygen-Electrochemical AMETEK-921 CE-UV S02 Analyzer-Ultraviolet Absorption Meeco-Aquavolt -Moisture-Electolytic Hygrometer AS F illi ng Method : 2000 psig Date of F i ll : 168 ft3 CGA·580 CC93915 Tern perature/P ressu re 10/06/2012



### Analyst: Henry Koung 

# ob Approved Signer:

I ,

A E Gn**Cl'Irom~l0gr;0llhy** with**~** PhoIomelllC Oeledor Ou CIIrom,IOQf'pny wiI1I Re'I).ldion Gas Anatyz8r M Min SpeClt_ry. illS 01 GC/'MS Q Tol.! Hyorocarbon AnalYZIr U ClI'milOJmit\eseeflce Y Pulsed Flt/ofeilGllftCe IMPORTANT B Gu Chrom. log r.phy w.tn OIl.C!la<ge lonolf\lOn**.,...,~** f On Chromillogr.ptly
...It. Htijum lo :'l/ zaUon**Ofl"'~** J G.s ChromilIOOJf'pt:y w,lh Th4! "II ll l**Cooouoel/Y~y** O<tteClQ( N By**Oil'fe~m;e** 01 TypiullmPl-'liel R Wet Cherl'ltc.1 V Gravlmelrie Z W Sp&drometry C Gas CtvomalOgrllJl/l y wM ElealOlyUc.**COllduc1~y** D'iector G Gas ClwOmatClgfaphy wih Ml!Ihan lzerC..oonlz.If K Binary Gas Anolyter willt**~rm"** CondoolYity Oelectar o P."megnelic; $ DeteClar Tube W Elodrotytie CeNS.ctrodlell"ical o GIS Cllfomacograpny WIllI**amllOriz~** Oetector H GIS (;hrOfl1itooraJlhy
...**~h** Photoiof'Oiutioo [)ele(;far l Infrlled·**fT~** Or NDIR P Sl)KIr,c Wale. Ane;y<tr 

# ,**"'~** X Pt'lQloIotIitlllion
Th e informalion contained heruln has been prepar e d at your request by pef$OOIl&i with,n Praxair Distribution,**Wh~e** we be li eYe !he informalion is accurate w i thin the limits of the analytical methods employed and is completo to t ho oxton! of the specific analyses per/ormed, we make no warran ty or representation as to the suitability of tne use 01 !he InforrnOition for any particular purpose, The in formation is offered Wi t h the understanding that any usc of the I nformation is £It tha sole discre1ion and risk of !he user. In n o even!**sh liliabil~y**  of Praxair Dis tribution, inc: , aristng out 01 the use o f the Inlo(lnatfQr1 contained horein exceed the fee estab lished for providtng such information Pg.1 of 1 

# /2.-/ 1 -/ 2

# ;POrifice Me thod · T nplicale Runs/Four Calibration Points Engl i sh Mete r BOK Units , English K' Factor SEMI · ANNUAL DRY GAS METER/ORIFICE CALIBRAT ION

Model # : 10 # : Filename : F , \compda la \Delia**PubliclCalibrations\Melers\17-wcs1201~Sem i·** **Annua l**  MeIer Callbrallon 9 · 19-12 wcs . KlsJWCS Date : C5000 17WCS 9/19/2012 Fi l e Mod ified F roor APEX 522 Series MeIe r boK Calibration Ba r. Pressure : 29
. 79 (In
. Hg) ReVised 4/812005 Perform ed By : 3A,RY BR I DG E
DRY GAS MET ER READINGS CRlTlCAL ORIFICE READIN GS Volume Vo lu me Vo lu me In it ial Temps Final Temps Orifice K'Orifice Actual dH Time In itial Final Total I n let Outlet Inl el Outie! Senal# Coeffici e n t Vacuum Initial in H 2O) (min) (cu tt) (cuft) (cu It) 

# 'do, Fi 

# do, , (d
. eg F) (d eC! F) (numt)e r) (see**abo~e** in Hg)
. (d., ') 0
. 1 I 26.00 368.900 374
. 275 5
. 375 74.0 73.0 74.0 73.0 33 0
. 1553 23
. 5 73.0 0
. 11 26
. 00 37 4
. 275 379
. 658 5
. 383 74.0 730 770 75 .0 33 0,1553 23.5 73.0 0
. 11 26 00 380
.200 385
. 581 5
. 381 

### J 770 750 77.0 75
. 0 33 0
. 1553 23
. 5 73.0 0
. 55 12
. 00 389,200 39 4, 650 5450 73.0 73
. 0 740 73.0 

# " 0
. 3465 2 0
. 0 74.0 0
. 55 12
. 00 394
.650 400,128 5
. 4 78 740 73.0 75.0 74
. 0 

# " 0, 3465 20
. 0 74.0 0
. 55 12
. 00 4 00
. 128 4 05,593 5
. 465 75
.0 74
. 0 760 74 .0 

# " 0 ,3465 20
. 0 74
.0 170 700 405.593 411.028 5435 760 740 77.0 75
.0 63 05888 16
. 5 74
.0 1
. 70 7 .00 411.028 416.485 5.457 770 750 78
. 0 75
.0 

### I 63 0 .5888 16
. 5 74 .0 1
. 70 700 4 16. 485 421.937 5 .45 2 780 750 790 76
.0 63 0
.5888 '65 74
. 0 3 . 30 500 4 21937 42 7
. 253 5316 790 76
. 0 81.0 76
.0 73 08202 13
.0 74
. 0 330 500 4 27253 

### I 432
. 550 5297 8 1
. 0 76
.0 82 . 0 76.0 73 0
.8202 13
. 0 74 .0 330 5 .00 4 32.550 437.886 5336 820 76
.0 63 .0 77.0 73 08202 13
. 0 74
.0

DRY GAS METE R ORIF I CE DRY GAS METER ORIFICE CALIBRATION FACTOR CALIBRATION FACTOR Individu a l In d ividu a l VOLU M E VOLUME VOLUME VOLU ME VOLUME Roo Orifice CORRECTED CORRECTED CORRECTED CORRECTED N O MIN AL Y dH@

V m(s td) Vm(std) VCl"{std) Vcr(std) Vee Value Value 0
. 95 < Y YmaK· Ym in (00 ' ) (lit ers) (cu ft) (liters) (eu tt) (numbe r) (in H2O) < lOS? < 0.010? 5
. 296 150 ,0 5
. 2 10 147 ,6 5285 0.984 1 ,52 0 Pass 5
. 291 149 ,8 5
.210 147,6 5
. 28 5 0
.985 1,517 Pass 5
. 277 1 49
.4 5
. 208 147,5 5287 0,987 1
. 515 Pa ss Average 0.985 1
. 517 Pass 5 , 378 152
. 3 5
. 360 15 1
. 8 5.447 0
. 997 1
. 529 Pass 5 , 398 152
. 9 5.360 15 1 8 5 44 7 0
. 993 1
. 528 Pa ss 5
. 376 1523 536<l 1518 5 44 7 0997 1
. 5 26 Pass Aver"ge 0.995 1
. 528 Pass 5
. 356 151.7 5
. 313 1505 5399 0992 1
. 632 Pass 5370 1521 5.313 1 505 5
. 399 0
. 989 1
. 631 P ass 5358 15 1.7 5.313 1 50
. 5 5399 0
. 992 1
. 629 Pass Average 0
. 991 1
.631 Pa ss 5235 148
. 2 5
.287 149
. 7 5372 1 0 1 0 1
.628 Pass 52<>9 1475 5
.287 1 4 97 5
. 372 1
.015 1
.628 Pass 5
. 240 1484 5
.284 1497 5375 '008 1
.628 Pass AveraQe 1.011 1.628 Pass A lle r age Yd: 0.996 dH@ : 1.576 Q@dH=1 : 0.597 SIGN ED : Date ' Ambient Temperature Final**erage** ,d., ') (d ., ') 73.0 73
.0 73
. 0 73
. 0 74.0 735 74,0 74 ,0 74,0 74 ,0 74
. 0 74 .0 74.0 74
. 0 74 .0 740 74
. 0 7<0 74.0 740 7 4
. 0 740 75
. 0 745

Orifice Or ifice Average Average 0
.98 < YlYd dH@ · dH @av

< 1
.02?

Pass

Pa ss

Pass

Pass < 0 ISS ?

Pass

Pa ss

Pass

Pa ss

Semi·Annual Meter C, l it><III"" 9· 19·12 WC I WCS 

# ,no,,,, 2.SPMOrifice Method - Triplicate Runs/Four Calibrat i on Paints English Meter Bo)( Units, English K' Factor SEMI-ANNUAL DRY GAS METER/ORIFICE CALIBRATION

Filename' F:\compdataIDelta PublicICalibrations\Me tersI9-P&M\2012\[Semi-Annual Meter Calibration -9-pm 9-21-12
. xlsjWCS Model # : 10. Da te 9P&M 912112012 File Modified From: APEX 522 Series Meter box Calib r ation Bar
. Pressure: 29.72 (in, Hg) Revised' 4/812005 Performed By M. Edmondson
DRY GAS METER READINGS CRITICAL ORifiCE READINGS Volume Volume Volume Initial Temps F i nal Temps
. Orifice K' Orifice Actual dH Time Initial Final Total Inlet Outlet I nlet Out l et Serial# Coefficient Vacuum In itia l (in H2O) (min) (cu tt) (eu tt) (eu tt) (deg F) (deg f) (deg F) (deg F) (number) (see above) (in Hg) (d eg F)

0. 14 26
.00 383.400 388
. 805 5 . 405 78 ,0 77
.0 79
. 0 78,0 33 0 , 1553 23.0 770 0
. 14 26
. 00 388
. 805 394
. 205 5.400 79,0 78
. 0 80
. 0 79,0 33 0.1553 23 .0 78.0 0.14 26
. 00 394.205 399
. 615 5.410 80,0 79.0 81 . 0 80,0 33 0 , 1553 23.0 79.0 0.64 12
. 00 350
. 820 356.270 5.450 75
.0 74
. 0 75.0 74 ,0 

# " 0,3465 20
. 0 75
.0 0.64 12
. 00 

### I 356,270 

### I 361
. 730 5.460 75
. 0 7 4 ,0 76
. 0 75,0 

# " 0 , 3465 20 ,0 75 .0 064 1 2 .00 361 .7 30 367 , 175 5 ,445 76.0 75,0 770 76 ,0 

# " 0,3465 20.0 76.0 1,90 7
. 00 

### I 367
. 175 

### I 372,585 5.410 770 76,0 770 76.0 63 0 , 5888 17.0 77
.0 1 ,90 7.00 372.585 377990 5.405 77.0 76 ,0 78 ,0 77.0 63 0 , 5888 17,0 77
.0 1
.90 700 377990 383 ,400 5.410 78.0 770 78 ,0 77.0 63 0
. 5888 17
. 0 78
. 0 3.70 5.00 334.700 340,065 5,365 720 72.0 730 73.0 73 0.8202 15 ,0 73.0 3
. 70 5.00 340.065 345.430 5
. 365 73,0 73
. 0 74.0 74,0 73 0
. 8202 15,0 74
. 0 3.70 500 

### I 345.430 350
. 810 

### I 5
. 380 74 ,0 74.0 74
. 0 74
. 0 73 0.8202 15.0 74,0

DRY GAS METER ORIFICE DRY GAS METER ORIFICE CALIBRATION FACTOR CALIBRATION FACTOR Individual Individual VOLUME VOLUME VOLUME VOLUME VOLUME Roo Orifice CORRECTED CORRECTED CORRECTED CORRECTED NOMINAL Y dH@

Vm(std) Vm(std) Ver(std) Vcr(sld) V" Va lue Va l ue 0,95 <: Y Ymax- Ym i n (cu tt) liters) (eu ttl ( li te rs) (eu tt) (number) (in H2O) <: 1,05? <: 0
.010? 5,269 149.2 5.176 146.6 5 , 307 0
. 982 1
. 939 Pass 5,254 148
. 8 5
. 171 146.5 5 , 312 0.984 1
. 939 Pass 5,254 148
. 8 5.167 146,3 5,317 0.983 1,939 Pass Average 0.983 1.939 Pass 5.354 151 ,6 5,343 151,3 5.452 0
. 998 1.784 Pass 5
. 359 151 ,8 5,340 151 ,2 5.455 0,997 1.784 Pass 5,334 151
. 1 5,335 151.1 5.460 1 ,000 1
. 78 4 Pass Average 0.998 1 .7 84 Pass 5,311 150.4 5.286 149.7 5.41 4 0
. 995 1.834 Pass 5
. 302 150
. 1 5
. 284 149.6 5 ,417 0.997 1.834 Pass 5 , 302 150
. 1 5
. 281 1 49
. 6 5.419 0
. 996 1
. 834 Pass Average 0
. 996 1.834 Pass 5
. 330 151,0 5,277 149.4 5
. 370 0,990 1 ,840 Pass 5
. 320 150,7 5 ,274 149 ,4 5.372 0 ,991 1 ,839 Pass 5.330 151
.0 5,274 149
.4 5
. 372 0.990 1
.837 Pass Average 0
. 990 1.839 Pass AverageYd: 0.992 dH@ : 1.849 Q@dH><I : 0
. 552 SIGNED : Signature on File Da te ' 912112012 Ambient Temperature final Average (deg F) (deg F) 78.0 77,5 79.0 78 , 5 80 ,0 79 , 5 75,0 75 ,0 76.0 75 , 5 770 76 ,5 770 770 78.0 77,5 78,0 78,0 74 ,0 73 ,5 74.0 74,0 74 ,0 74 ,0

Orifice Orifice Average Average 0,98 <: YfYd dH@-dH@av

<: 1
. 02? <: 0
. 155?

Pass Pass

Pass Pass

Pass Pass

Pass Pass

Se fni.A nnua l M eter C a libration -9 - pm 9-21-12 WCS 212612013 2 ;49 PM

### Standard Pitot Tube Dimensional Calibration Record
A 

# -

, @ A "2 

## , 

# " Okood Sedion AA 

# • 02 

# r

Tip ccep,I,:,lllly Crileria y" y" 

# "" "" "" 

# " , . -0.101 M1 :>6 01 M2:>801 Hemispherical, 90 · Bend wIth PitotlO Dale Calibrated B Elliptical , or &urved or m ite r e d 01 0' M1 M' Ratio 02101 601 801 Status Coni&al Tip junct io n 8 y y 0 . 31 0 . 029 2 . 110 2 . 550 0 .094 1 . 860 2 . 5 

### Pass

# 1



# __ ---e A 

# "JEt

, Side View
Acceptability

Criteria z < 1/8" w < 1 132"

Side View, Side View,

Impact Impact openings openings Pito tlD Date Calibrated By Properly Properly aligned , Z < aligned , W 1/8" < 1/32" 026 y 

### Y 

### S Type Pitot Tube Dimensional Calibration Record 

# l



# .. i

"3/16" < 01 < y" 3/8"

Tubing PazPb Diameter, dt



### Y 0 . 374

# ~ M , 

# -I**~ ~**  M,

# ~ End View

n/. 

# n" nl'



### M1 M2 M3

0.882 0.870 0 . 882 n/. n/.



### M' MS

0 . 876 0.437

Reference "A Type - S Pilot Tube Calibration Study, Robert F
. Volla ro , October IS, 1975 If tube is not visibly deformed it i s assumed that Pa '" Pb"
. 5 x avg . of Ml M2, and that average lace open i ng plane angles represent individual angles to tube axis 

### M.

n/.



### M.

0.457 

# -- I M, 

# r- ;< 

# ;t( P:b 

# i

-,- M : 

### M

, p, 

# + 

# L 

# --I**~** Too View
1.050t<P<1.5 10 degrees 5 degrees Ot Average Face Average Face Opening Plane Opening P lane Angle, offset Frontal An g le from Ratio of PlOt St atus perpendicular from para1Jello to transverse Longitud i nal axis Axis 0 . 9 0.4 1.2 

### Pass

...

### S Type Pitot Tube Dimensional Calibration Record 

# cccccC A 

# B31J

, 

# 1 

# t:xij**~** M,

# ~**~** 

# i Side View End View Acceptability "3/16" <: Dt <

Criteria z < 116" w < 1132" y" 3/8" 

# "'a "'a 

# ",. ",. ",.

Side View, Side View,

Impact Impact PilotlD Date Calibrated By openings openings Pa :Pb Tubing MI M2 MJ M' M' Properly Properly Diameter , dt aligned, Z <: aligned, W 118" <: 1132"
04B y 

### Y Y 0 . 373 1 .030 1.010 1.009 1.004 0.40B

Reference "A Type-S Pito t Tube Calibra t ion Study, Robert F. Vallare, October 15,1975 If lube is not visibly deformed it is assumed that Pa = Pb = .5 x 3\19. of Ml M2, and that ave ra ge fa ce opening plane angles represent individual angles to tube axis -/ M, 

# r-**~;:=:::::::::;;-. ~**  P:b 

# 1

- , - M ; M

, Pa 

# + 

# 1 M, 

# -/**~** Too View
1 . 050t <P< 1 . 5 

# "'a 10 degrees 5 degrees 01 Average Face Average Face Opening Plane Angle , offset Opening Plane M6 from Frontal Angle Ratio of PlOt Status perpendicular from parallel to to transverse Longitudinal axis Axis 0.414 1 .5 0 .3 1.4 PassWATER PTC·S OIL PTC-10 WATER PTC-10

Oi

l PTC-11 WATER PTC - 11

WATER

I OIL PTC·23 WATER PTC-23

OIL PTC-24 WATER PTC-2 4

I

Calibrated By : DMW , RM, RMO, DA, ME 361 212 362 213

21' 360 21' 361 21' TEMPERATURE SY STEM CALIBRATION STANDARD

361 212 362 21'

21' 360 214 361 213 21' 361 212 362 213

213 360 21. '61 21' 

## #8

361 212 362 21'

21' 360 21. 361 21' 360 21' 360 

# ,,,

212 360 212 360 212 212 360 212

212 360 21' 360 212 212 360 212

January 2 , 2013Reference Thermometer LD TIC Readout 1.0 LD. 

# .. Reading 1 OIL PTC-25 362 WATER PTC-25 213

ICE PTC-2S 31 OIL PTC-26 362 WATER PTC-26 211

ICE PTC-26 32 OIL PTC-27 362 WATER PTC-27 213

ICE PTC-27 30 OIL PTC-28 361 WATER PTC-28 213

ICE PTC-28 33 OIL PTC-29 362 WATER PTC-29 213

ICE PTC-29 32 OIL PTC-30 360 WATER PTC-30 212

ICE PTC-3D 32 OIL TRO-l 360 WATER TRO-l 213

ICE TRO-l 31 OIL TRO-4 359 WATER TRO-4 213

ICE TRO-4 31 OIL TRO-5 361 WATER TRO-5 213

ICE TRO-5 33 OIL TRO-6 360 WATER TRO-6 211

ICE TRO-6 30 OI

L TRO-a 361 WATER TRO-a 213

ICE TRO-a 33 OIL TRO-9 359 WATER TRO-9 211

ICE TRO-9 32 OIL TRO-11 359 WATER TRO-" 213

ICE TRO-l1 33 OIL TRO -12 360 WATER TRO-12 212

I CE TRO-12 32 OIL TRO-13 360 WATER TRO-13 21'

ICE TRO-13 31 OIL TRO-1S 360 WATER TRO-1S 213

ICE TRO-1S 30 OIL TRO-16 361 WATER TRO-16 213

ICE TRO-16 31 OIL TRO-18 361 WATER TRO-18 213

ICE TRO-18 34 OIL TRO-19 360 WATER TRO-19 212

ICE TRO-19 33 OIL TR0-20 362 WATER TRO-20 213

ICE TRO-20 32 OIL TRO-22 363 WATER TRO-22 213

ICE TRO-22 32 OIL TRO-23 363 WATER TRO-23 213

ICE TRO-23 32 OIL TRO-24 362 WATER TRO-24 211

ICE TRO-24 32

Calibrated By: DMW, RM , RMO, DA. ME T1 TEMPERATURE SYSTEM CALIBRATION STANDARD 

### #8 F95-195 T2 F95-195 TO F95-Hl5 TIC - Readout Reference Thermometer 'F 'F Reading 2 Readin9 3 Average Reading 1 Reading 2 Reading 3 Average 3'" 362 362 360 360 360 360 213 213 213 212 212 212 212 31 31 31 32 32 32 32 362 362 362 360 360 360 360 211 211 211 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 30 3lJ 30 32 32 32 32 361 361 361 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 2" 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 212 2" 2" 212 212 2" 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 213 213 213 212 212 212 212 31 31 31 32 32 32 32 359 359 359 360 360 360 360 213 213 213 212 212 212 212 31 31 31 32 32 32 32 361 361 361 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 360 360 360 360 360 360 360 211 211 211 212 212 2" 212 30 30 30 32 32 32 32 361 361 36 1 360 360 360 360 213 2" 213 212 212 212 212 33 33 33 32 32 32 32 359 359 359 360 360 360 360 211 211 211 212 212 212 212 32 32 32 32 32 32 32 359 359 359 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 2" 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 21' 21. 21. 212 2" 212 212 31 31 31 32 32 32 32 360 360 360 360 360 360 360 213 213 213 212 212 212 212 30 3lJ 30 32 32 32 32 361 361 361 360 360 360 360 213 213 213 212 212 212 2" 31 31 31 32 32 32 32 361 361 361 360 360 360 360 213 213 213 212 212 212 212 34 34 34 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 2" 212 212 33 33 33 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 363 363 363 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 363 363 363 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 211 211 211 212 212 212 212 32 32 32 32 32 32 32 Difference 'F 2 1 1 2 1 0 2 1 2 1 1 1 2 1 0 0 0 0 0 1 1 1 1 1 1 1 1 0 1 2 1 1 1 1 1 0 1 1 1 0 0 0 0 2 1 0 1 2 1 1 1 1 1 2 0 0 1 2 1 0 3 1 0 3 1 0 2 1 0 %,C'R) 0.2% 0 . 1% 0 . 2% 0.2%**.1 ·~**  0.0% 0 . 2% 0.1% 0.4% 0 . 1% 0.1% 0.2% 0.2% 0.1% 0.0% 0 . 0% 0 . 0% 0 . 0% 0,0% 0.1% 0.2% 0 . 1% 0.1% 0.2% 0.1% 0.1% 0.2% 0.0% 0.1% 0.4% 0 . 1% 0 . 1% 0 . 2% 0.'% 0.1% 0.0% 0.1% 0 . 1% 0 . 2% 0.0% 0 . 0% 0.0% 0 . 0% 0.3% 0.2% 0.0% 0.1%**0.4·~** 0.1% 0 . 1% 0.2% 0.1% 0.1% 0.4% 0.0% 0.0% 0,2% 0 . 2% 0.1% 0 . 0% 0,4% 0,1% 0 . 0% 0.4% 0,1% 0 . 0% 0,2% 0.1% 0 . 0% P 

# '" '" '" P P P 

# '"

'" '" P P P 

# '"

'" '" '" 

# '" '" '" P P P P P P P 

# '"

'" '" '" '" 

# '" '" '" '" 

# '" '" '" 

# '" '" '" 

# '" '" '" '" '" 

# '" '" 

# '" '" '" '" '" '" 

# '" '" 

# '" '" 

# '" '" 

# '" '" '" '" '" '" '" '" 

# '" '" '" '" '" 

# '" '" '" '" '" 

# '" '" 

# '" '" P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P

January 2, 2013WATER PTC-22 OIL PTC-23 WATER PTC-23

OIL PTC-24 WATER PTC-24

I

Calibrated By : DMW , RM, RMO, DA, ME 213 363 211 361 212 213 363 211 361 212 TEMPERATURE SYSTEM CALIBRATION STYPE

213 363 211 361 

# '" 363 211 361 212 212 360 212 360 212 212 360 212 360 212 212 360 212 360 212 212 360 212 360 212 

### o

January 2, 2013Reference Thennometer 1. 0 .: TIC Readout 1.0. 

### ID 

# '26 Reading 1 

### all PTC-2S 362 WATER PTC-2S 213

ICE PTC-2S 32 

### all PTC-26 362 WATER PTC-26 212

ICE PTC-26 31 

### all PTC-27 363 WATER PTC-27 213

ICE PTC-27 30 

### all PTC-28 362 WATER PTC-28 212

ICE PTC-28 30 

### all PTC-29 361 WATER PTC-29 211

ICE PTC-29 31 

### all PTC-30 361 WATER PTC-30 212

ICE PTC-3D 31 

### all TRO-1 361 WATER TRO-1 212

ICE TRO-1 33 

### all TRO -4 362 WATER TRO-4 211

ICE TRO-4 32 

### all TRO-S 362 WATER TRO-S 214

ICE TRO-S 32 

### all TRO-6 362 WATER TRO-6 212

ICE TRO-6 31 

### all TRO-8 362 WATER TRO-8 213

ICE TRO-8 35 

### all TRO-9 361 WATER TRO-9 212

ICE TRO-9 32 

### all TRO- 1 1 360 WATER TRO-11 214

ICE TRO-11 31 

### all TRO-12 360 WATER TRO-12 213

ICE TRO-12 32 

### all TRO-13 361 WATER TRO-13 212

ICE TRO-13 31 

### all TRO-15 364 WATER TRO-1S 213

ICE TRO-1S 31 

### all TRO-16 364 WATER TRO-16 212

ICE TRO-16 32 

### all TRO-18 362 WATER TRO-1 8 213

ICE TRQ-18 32 

### all TRO-19 363 WATER TRO-19 213

ICE TRO-19 31 

### all TRO-20 364 WATER TRO-20 212

ICE TRO-20 33 

### all TRO-22 363 WATER TRO-22 213

ICE TRO-22 31 

### all TRO-23 362 WATER TRO-23 212

ICE TRO-23 31 

### all TRO-2 4 362 WATER TRO-24 213

ICE TRO-24 32

Calibrated By : DMW, RM, RMO, DA , ME T1 TIC TEMPERATURE SYSTEM CALIBRATION STYPE 

## #26 F95-195 T2 F95-195 T3 F9S-195

- Readout Reference Thermometer

of of ReadinJ:l2 Reading 3 Average Reading 1 Reading 2 ReadinQ 3 Average 362 362 362 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 212 212 212 212 212 212 212 31 31 31 32 32 32 32 363 363 363 360 360 360 360 213 213 213 212 212 212 212 30 30 30 32 32 32 32 362 362 362 360 360 360 360 212 212 212 212 212 212 212 30 30 30 32 32 32 32 361 361 361 360 360 360 360 211 211 211 212 212 212 212 31 31 31 32 32 32 32 361 361 361 3'" 360 360 360 212 212 212 212 212 212 212 31 31 31 32 32 32 32 361 361 361 360 360 360 360 212 212 212 212 212 212 212 33 33 33 32 32 32 32 362 362 362 360 360 360 360 211 211 211 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 214 214 214 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 212 212 212 212 212 212 212 31 31 31 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 35 35 35 32 32 32 32 361 361 361 360 360 360 360 212 212 212 212 212 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 214 214 214 212 212 212 212 31 31 31 32 32 32 32 360 360 360 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 361 361 361 360 360 360 360 212 212 212 212 212 212 212 31 31 31 32 32 32 32 364 364 364 360 360 360 360 213 213 213 212 212 212 212 31 31 31 32 32 32 32 364 364 364 360 360 360 360 212 212 212 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 363 363 363 360 360 360 360 213 213 213 212 212 212 212 31 31 31 32 32 32 32 364 364 364 360 360 360 360 212 212 212 212 2 12 212 212 33 33 33 32 32 32 32 363 363 363 360 360 360 360 213 213 213 212 212 212 212 31 31 31 32 32 32 32 362 362 362 360 360 360 360 212 212 212 212 212 212 212 31 31 31 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 Difference of 2 1 0 2 0 1 3 1 2 2 0 2 1 1 1 1 0 1 1 0 1 2 1 0 2 2 0 2 0 1 2 1 3 1 0 0 0 2 1 0 1 0 1 0 1 4 1 1 4 0 0 2 1 0 3 1 1 4 0 1 3 1 1 2 0 1 2 1 0 %,fR) 0.2% 0.1% 0 . 0% 0.2% 0.0% 0 . 2% 0 .4% 0 . 1% 0.4% 0.2% 0.0% 0.4% 0.1% 0.1% 0.2% 0.1% 0.0% 0.2% 0.1% 0.0% 0.2% 0 . 2% 0 . 1% 0 . 0% 0.2% 0 . 3% 0.0% 0.2% 0 . 0% 0.2% 0 . 2% 0 . 1% 0.6% 0 . 1% 0 . 0% 0.0% 0 . 0% 0 . 3% 0.2% 0.0% 0 . 1% 0.0% 0.1% 0 . 0% 0.2% 0.5% 0.1% 0.2% 0 . 5% 0 . 0% 0 . 0% 0.2% 0 . 1% 0 . 0% 0.4% 0.1% 0.2% 0.5% 0 . 0% 0 . 2% 0.4% 0 . 1% 0.2% 0.2% 0 . 0% 0.2% 0 . 2% 0 . 1% 0.0% Pess Pass Pass Pass Pass Pass Pass Pass Pass P 

## '" Pass P 

# '"



# '" '" 

# '" '" 

# '" '" '" 

# '" '" '" '" '" '" 

# '" '" '" '" '" 

# '" '" '" '" 

# '" '" '" '" 

# '" '" '" '" '" 

# '" '" '" '" '" 

# '" '" '" '" '" '" '" '" P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P 

# '"

'" '" '" '" 

# '" '" P P P P P P 

# '"

'" '" '" 

# '" '"

January 2, 2013Reference Thennometer 1.0 .: TIC Readout 1.0. 1.0 . #48 Readina 1 OIL 3WCS 358 WATER 3WCS 212

ICE 3WCS 

# " OIL SWCS 360 WATER SWCS 212

ICE SWCS J2 OIL 6WCS 357 WATER 6WCS 212

ICE 6WCS 32 OIL 7WCS 358 WATER 7WCS 213

ICE 7WCS 34 OIL 12WCS 359 WATER 12WCS 212

ICE 12WCS JJ OIL 14WCS 358 WATER 14WCS 211

ICE 14WCS J2 OIL 17WCS 360 WATER 17WCS 211

ICE 17WCS 30 OIL laWCS 360 WATER lawcs 213

ICE laWCS 30 OIL 19W CS 360 WATER 19WCS 213

ICE 19WCS 32 OIL PTC-a 360 WATER PTC-8 213

ICE PTC-8 J2 OIL PTC-9 361 WATER PTC-9 212

ICE PTC-9 32 OIL PTC-IO 360 WATER PTC-tO 212

ICE PTC-l0 JJ all PTC-l1 361 WATER PTC-l1 212

I CE PTC-lt 34 all PTC-12 360 WATER PTC-12 214

ICE PTC-12 33 all PTC-13 359 WATER PTC-13 213

ICE PTC-13 J2 all PTC-14 360 WATER PTC-14 213

ICE PTC-14 34 all PTC-1S 358 WATER PTC-1S 212

ICE PTC-1S J2 all PTC-16 358 WATER PTC-t6 211

ICE PTC-t6 32 all PTC-,7 360 WATER PTC-17 212

ICE PTC-17 30 all PTC-20 360 WATER PTC-20 213

ICE PTC-20 3S all PTC-21 361 WATER PTC-21 212

ICE PTC-21 33 Oil PTC-22 361 WATER PTC-22 212

ICE PTC-22 J2 all PTC-23 360 WATER PTC-23 211

ICE PTC-23 J2 all PTC-24 360 WATER PTC-24 212

ICE PTC-24 34

Calibrated By : DMW, RM, RMO, DA, ME T1 TEMPERATURE SYSTEM CALIBRATION STYPE 

## #48 F9S-19S T2 F9S-19S T3 F95-19S TIC - Readout Reference Thennometer 'F 'F Readina 2 Readina 3 Averaae Readina 1 Reading 2 Reading 3 Average

358 358 358 360 360 360 360 212 212 212 212 212 212 212 

# " " " J2 J2 J2 J2 360 360 360 360 360 360 360 212 212 212 212 212 212 212 J2 J2 J2 J2 J2 J2 J2 357 357 357 360 360 360 360 212 212 212 212 212 212 212 J2 J2 J2 J2 32 32 J2 358 358 358 360 360 360 360 213 213 213 212 212 212 212 34 34 34 J2 32 32 32 359 359 359 360 360 360 360 212 212 212 212 212 212 212 JJ JJ JJ J2 J2 32 32 358 358 358 360 360 360 360 211 211 211 212 212 212 212 J2 J2 32 J2 32 32 J2 360 360 360 360 360 360 360 211 211 211 212 212 212 212 30 30 30 32 32 32 J2 360 360 360 360 360 360 360 213 213 213 212 212 212 212 30 30 30 J2 J2 J2 J2 360 360 360 360 360 360 360 213 213 213 212 212 212 212 J2 J2 J2 J2 J2 32 J2 360 360 360 360 360 360 360 213 213 213 212 212 212 212 J2 J2 J2 32 32 32 32 361 361 361 360 360 360 360 212 212 212 212 212 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 212 212 33 33 33 32 32 32 32 361 361 361 360 360 360 360 212 212 212 212 212 212 212 34 34 34 32 32 32 32 360 360 360 360 360 360 360 214 214 214 212 212 212 212 33 33 33 32 J2 J2 J2 359 359 359 360 360 360 360 213 213 213 212 212 212 212 J2 J2 J2 J2 J2 J2 J2 J60 360 360 360 360 360 360 213 213 213 212 212 212 212 34 34 34 J2 J2 J2 32 358 358 358 360 360 360 360 212 212 212 212 212 212 212 32 32 32 32 32 32 32 358 358 358 360 360 360 360 211 211 211 212 212 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 212 212 30 30 30 32 J2 32 32 360 360 360 360 J60 360 360 213 213 213 212 212 212 212 3S 3S 3S 32 32 32 32 361 361 361 360 360 360 360 212 212 212 212 212 212 212 33 33 33 32 J2 J2 J2 361 361 361 360 360 360 360 212 212 212 212 212 212 212 J2 J2 J2 J2 J2 J2 32 360 360 360 360 360 360 360 211 211 211 212 212 212 212 J2 J2 J2 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 212 212 34 34 34 32 32 32 32 Oifference 'F %,(OR) 2 0.2% 0 0.0% 1 0 .2% 0 0.0% 0 0 . 0% 0 0 . 0% 3 0.4% 0 0.0% 0 0 ,0% 2 0,2% 1 0,1% 2 0,4% 1 0 . 1% 0 0.0% 1 0.2% 2 0 . 2% 1 0 . 1% 0 0.0% 0 0.0% 1 0 . 1% 2 0,4% 0 0 . 0% 1 0,1% 2 0.4% 0 0.0% 1 0 . 1% 0 0 . 0% 0 0 . 0% 1 0.1% 0 0 . 0% 1 0 .1 % 0 0 . 0% 0 0 . 0% 0 0 . 0% 0 0 . 0% 1 0.2% 1 0 . 1% 0 0 . 0% 2 0.4% 0 0.0% 2 0,3% 1 0.2% 1 0 . 1% 1 0.1% 0 0 . 0% 0 0 . 0% 1 0.1% 2 0.4% 2 0.2% 0 0 . 0% 0 0,0% 2 0 . 2% 1 0 . 1% 0 0.0% 0 0.0% 0 0 . 0% 2 0 . 4% 0 0 . 0% 1 0.1% 3 0 .6% 1 0 . 1% 0 0.0% 1 0.2% 1 0 .1% 0 0.0% 0 0.0% 0 0.0% 1 0 . 1% 0 0.0% 0 0 . 0% 0 0 . 0% 2 0 .4% Pass Pass Pass Pass P 

# '"

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# '"

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# '" '" P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P

# '"

'" '" P P P 

# '"

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# '"

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January 2 , 2013OIL WATER

I 1.0 . PTC-25 PTC-25

Calibrated By : DMW , RM , RMO, DA , ME 356 213 TEMPERATURE SYSTEM CALIBRATION STYPE

356 213 

## #48

358 213 360 212

January 2, 2013

## NOZZLE CALIBRATION DATA 

## Nozzle 1.0. 4 .v.J .JM'·( (!J • 

## ..>.3 

## ' i 5z -51iL Date ) - i).6- 1 3 

## Material 

# 55 

# By .;::! 

# tA**t/i..~A...** 

## Configuration (L or Hook) l.f.vtAC

O 2 

## = 

# O J- 33

Maximum Difference D j - 

## Dj 

# = 

# 0·,,1. (must 

## be 0
. 004") 

## Average Dn 

# = 

# 0

- J 3 vI

Note : Measure three diameters with micrometer

D5934098 

# _A Date of last revision 

## 9/28/2012 Master Document 5torage\FormslDatasheetslCalibration Forms

## Appendix A.4

R041 0688 

## Delta CEM System Description and SCAQMD Method 100 . 1 Calibration and Test Sequence

A-9

## SCAQMD METHOD 100.1 CALIBRATION SEQUENCE AND CALCULATIONS 

## DEFINITIONS: 1) Analyzer Calibration :
2) Calibration Error:

3) Analyzer Linearity :

4) Sample System Bias :

R041 0688 

## Zero and span gas(es) are introduced directly to the analyzer
. Adjustments are made to the analyzer zero and upscale readings, as necessary to match the certified concentrations of the calibration gas. Zero, mid (40-60% of full scale), and high (80-100% of full scale) calibration gases are introduced directly to the analyzer and the analyzer response to each gas is recorded (without adjustment to the analyzer). The Calibration Error (difference between the analyzer response to the calibration gas and the certified concentration of the calibration gas) must not exceed ±2% of the analyzer full scale for any of the three gases. Analyzer linearity is defined as the difference between an analyzer response to the mid range gas and the predicted analyzer response to the mid range gas based on the analyzer response to the zero and high range gas . The Analyzer Linearity test is required on a semi-annual basis and must not exceed ± 1

## % of the analyzer range. It should be noted that this linearity requirement is more stringent than the best available calibration standards (+/-2%) for the low CO and NO, concentrations expected during this test program . For this reason, an analyzer linearity of less than 2% will be considered as acceptable for this program. The sample system bias test involves introducing zero and one upscale (mid or high) calibration gas to the entire sampling system and recording the analyzer response . The analyzer response to the calibration gas after it has passed through the entire sample system is compared to the analyzer response to same the calibration gas injected directly to the analyzer. The test is used to determine the effect which the sample system has on the species of interest and correct the measured values for any effect which the system has
. The sample system bias is required to be less than ± 5% of the analyzer range for both the zero and upscale gas.

A-10 

# /III/tall

## PROCEDURES AND CALCULATIONS: Figure 1 presents a flow chart for the SCAQMD Method 100.1 calibration sequence. All calibrations are documented as one-minute averages from the reference method Data Acquisition System. Following assembly of the system, analyzer warm up time, and a successful leak check of the sample system, the calibration/test sequence presented in Figure 1 can begin
. An Analyzer Calibration is performed as necessary by adjusting the zero and span settings of the analyzer. These calibrations are not necessarily recorded on the chart recorder
. Calibration Error is then determined at three levels for each range (which is expected to be used) of each analyzer. This check is performed, at a minimum, once at the beginning and once at the end of each test day. The calibration error must not exceed ±2% of the full range of the analyzer as determined by the following equation: Calibration Error Analyzer Response - Cal. Gas Value * 

## 100% Analyzer Range The data from the Calibration Error test can be used to determine Analyzer Linearity
. The analyzer response to the mid gas is predicted using linear regression and the analyzer response to the zero and high calibration gas and the zero and high calibration gas values. The analyzer linearity must be demonstrated on a semi-annual basis using the following equation: Analyzer Linearity 

## = Analyzer Response - Predicted Response 

## * 100% Analyzer Range where: Response to High Gas - Response to Zero Gas Predicted Response = * 

### M id Gas Value + 

### Response to Zero Gas High Gas Value 

## The Sample System Bias test is performed before and after each test run and must not exceed ± 5% of the analyzer range for both the zero and upscale span gas. The system bias is calculated using the following equation: Response to System Bias - Response to Analyzer Cal Sample System Bias 

# = * 

## 100% Analyzer Range

R041 0688 A-11

## where : Response to Analyzer Cal 

## = The analyzer response to the last t i me the same calibration gas was introduced directly to the analyzer (this may be the pre-test calibration error value or a more recent analyzer calibration adjustment) Zero and Calibration Drift are calculated for each test run based on the analyzer response during the pre- and post-test sample system bias test. Zero and upscale drift must not exceed ± 3% of the analyzer range . Post - T es t S ys

te m Bia s R e sonse - Pre - Test S ys tem Bias R es p o n se Anal yzer Dri ft = • 

## 100% 

## A nalyzer Range The pre- and post-test analyzer response during the sample system bias test are used to correct the raw test average for any sample system bias and analyzer drift. The drift/bias corrected data are the actual reported concentrations and are used for subsequent calculations (mass emission rates
. Ib/ MMBtu
. corrections to 3% or 15% O 2 • 

## etc
. )
. The drift/bias corrections i s performed using the following equation :

where : C , 

## = Drift/bias corrected concentration C 

# = Raw Test Average C m 

## = Average of pre- and post-test response to sample system bias span Co = 

## Average of pre- and post-test to sample system bias zero C m • 

## = Span gas value ADDITIONAL QUALITY ASSURANCE CHECKS: SCAQMD Method 

## 100 . 1 specifies the allowed analyzer interferences for each analyzer type
. No interference checks are required for O 2 

## or NO , analyzers. Interference tolerances are g iven for CO
. CO 2 • 

## and S0 2 analyzers
. The analyzers used by Delta are certified by the manufacturers to have interference responses which meet the requirements of Method 

## 100 . 1 . SCAQMD has published a draft method for determining the efficiency of a N0 2 

## to NO converter. This test will be performed once on the day of the test. The converter efficiency must be 90% or greater
.

R041 0688 A-12

## Analyzer Cal Cal No Error 

## < 2% Yes 

# I Yes No System 

## Nn System Bias 

## < 5% Problem? Yes Don 't Know Stratified No Location? Yes Multi-Point Single Point Test Test System No Bias 

## < 5% Yes Cal No Drift 

## < 3% 

# 1

Yes Note : AQMD policy allows multiple 

## Another No Analyzer Cal test runs to be validated by one set of pre- and post-test sample system 

## Test? (if neCeSSary) bias tests as long as the 

### bias 

# 1 checks are performed within 2 hours 

## Yes of the previous bias check. 

## No No Analyzer Cal Cal? Error 

## < 2% Yes 

# 1 Yes No Yes System 

# ( Finish 

# 1 Bias 

## < 5% t

## FIGURE 1: SCAQMD METHOD 100.1 CALIBRATION AND TEST SEQUENCE

R041 0688 

### A-13

## APPENDIX B PROCESS DATA

R041 0688 8-1

## Appendix B.1 Process and CEMS Data

R041 0688 

### 8-2

## Appendix 8.1.1 Sentinel Unit 4 Stratification Test

R041 0688 

## B·3

# Data Summary Report Company : CPV Sentinel, LLC 62575 Powerline Road Source : 

### Data Group: Report Na me : 

### Start of Report: 

### Desert Hot Springs, CA 92240 Turbine 4 4>1-Min Cales 4>Summary

- I-Min RATA 

### 02/11/2013 09,02

# S~nllt 

# \ 

# UV'i+ L{ 

# s¥ 1\



# +- (,£\((.1L

End of Report, 02/11/2013 09,36 G3 4 -C4 G34-Cll G34-C20 G34 -C3 G34 -Cl3 

# TRACE Enviro nm e nt a l S y ste m s, In c .

Validation: All Available Data G34 -CIO G34-C6 G34-C7 G34

- C8 G34-C18 G34-C 

### Group#-Channel# 

### Long -Descrip
. Short Descrip. 

### Units G34-C2 4,Stk NOx

Stk NOx 

### 4>St k 02 4 >NOx Mass 4>StkFlow 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk CDc 4>Gas Flow 4>NH3 Inj 4>MW La 

### Range 02/11/2013 09:02 02/11/2013 09:03 02/11/2013 09:04 02/11/2013 09:05 02/11/2013 09;06 02/11/2013 09:07 02/11/2013 09:08 02/11/2013 09:09 02/11/2013 09:10 02/11/2013 09:11 02/11/2013 09:12 02/11/2013 09:13 02/11/ 2 013 09:14 02/11/ 2 013 09:15 02/11/ 2 013 09:16 02/11/ 2 013 09:17 02/11/2013 09;18 02/11/2013 09:19 02/11/2013 09:20 02/11/2013 09:21 02/11/2013 09:22 02/11/20 1 3 09:23 02/11/20 1 3 09:24 02/11/2013 09:25 02/11/2013 09:26 02/11/2013 09:27 02/11/2013 09:28 02/11/ 2 013 09:29 02/11/ 2 01 3 09:30 02/11/2013 09:31 

### Date/Time Printed: ppm 0-150 2.9 2.9 3.0 3.0 2.9 3.0 3.0 2.9 

### 2.9 3.0 2.8 2.9 2.9 2.8 2.9 

### 2.9 2.8 2.9 2.9 

### 2.9 2.9 2.9 2.9 3.0 2.8 3.0 2.9 2.8 

### 2.9 3.0 St k 02 

# • 0-25 12.90 12.91 12.89 12.88 12.88 12.88 12.88 12.88 12.88 1 2 .87 12.91 12.92 12.9 2 12 .9 3 12. 9 0 12.89 1 2 .91 12.90 12.91 12.90 12.92 12. 9 1 12.9 1 12.88 12 . 90 12.89 12 . 89 12 . 91 12 .91 12.91 

### 02/11/2013 09,49 NOx Mass 

### Ib/hr 0-100 7.44 7.43 7.45 7.47 7.45 7.46 7.45 7.46 7.47 7.48 7.42 7.40 7.43 7.40 7.45 7.43 7.41 7.42 7.42 7.42 7.39 7.40 7.40 7.42 7.40 7.42 7.42 7.40 7.40 7.41 

### StkFlow kscfh 0-300000

21172 21150 21164 21185 2 1 145 21172 21129 21159 21191 21190 21121 21113 21185 21115 21181 21119 21105 21118 21127 21099 21073 21081 21071 21061 21058 21091 21078 21081 21075 21103 Stk CO 

### ppm 0-1000

l.7 2.0 2.1 2.2 2.2 2.3 2.2 2.3 2.3 

### 2.3 2.7 

### 3.1 2.9 3.3 3.3 2.8 3 . 0 

### 2.9 3.0 2.8 

### 2.9 2.9 2.8 

### 2.6 2.8 2.7 2.5 2.8 3.0 2.9 CO Mass 

### Ib/hr 0-100 2.79 2.78 2.79 3.73 3.73 3.73 3.72 3.73 3.73 3.74 3.71 4.63 4.64 4 . 62 4 . 65 4.65 4.63 4.64 4.64 4.64 4.62 4.63 4.62 3.71 4.63 3.71 3.71 4 .63 4.63 4.63 

### NOx Rate 

### Ib!mmBtu 0-1 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0 . 008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 Stk NOXc 

### ppm 0-300 2.14 2.14 2.21 2.21 2.13 2.21 2.21 2.13 2.13 2.20 2.07 2.14 2.14 2.07 2.14 2.14 2.07 2.14 2.14 2.14 2.14 2.14 2.14 2.21 2.07 2.21 2.14 2.07 2.14 2.22 Stk CDc Gas 

### hscfh hscfh 0 -1 0000 

### ppm 0-1000

1. 25 1 .4 8 1. 55 1. 62 1. 62 1. 69 1. 62 1. 69 1. 69 1. 69 1. 99 2 . 29 2 . 1 4 2 .4 4 2 .43 2 . 06 2 . 22 2.14 2.22 2.07 2.14 2.14 2.07 1. 91 2.07 1. 99 1. 84 2.07 2 .2 2 2.1 4 8861.4 8841.0 8869.2 8889.0 8872.2 8883.6 8865.6 8878.2 8891.4 8902.2 8829.0 8814.6 8844.6 8804.4 8865.0 8850.0 8822.4 8838.6 8831.4 8830.8 8797.8 8812.2 8808.0 8836.8 8813.4 8838.6 8833.2 8812.2 8809.8 8821.2 

### NH3Inj Ib/hr 0 -1 000 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 MW La 0-1 107. : 107 .. 107. ( 107. 108.1 106. 106.: 107. : 107. ! 107. : 106. ! 106. ! 106. : 106.! 106. ' 106.: 106 106. 106. 106, . 105 .. IDS. ! 106. 106 . : 106. ! 106 .. 106. ! 106 .. 105 . : 106, ' 

### PagE

### Group#-Channel# Long Descrip. Short Descrip. Units Range 02/11/2013 09:32 02/11/2013 09:33 02/11/2013 09:34 02/11/2013 09:35 02/11/2013 09:36 

### Period Average Period Max Value Period Min Value Period Totals 

## = Period 

### % Recovery



### Date/Time Printed: G34-C 4 G34

- C11 G34-C13 G34-C10 G34-C6 G34-C7 G34

- C8 G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass G34-C20 4>StkFlow

StkFlow

kscfh 0

- 300000 G34-C3 4>Stk CO

Stk CO 

### ppm 0-1000 4>CO Mass 4>NOx Rate 4>Stk NO X e 4>Stk CDc 4>Gas Flow G34

- C18 4>NH3 Inj NH3Inj



### lb/hr 0-1000 G34-C 4>MW Lo

MW Lo Stk 02 % 0-25 NOx Mass 

### lb/hr 0-100 CO Mass 

### lb/hr 0

- 100 2.9 12.91 7.42 21128 2.6 3 . 71 3.0 12.90 7.44 21149 2.7 3 . 72 2.9 12.90 7.43 21142 2.7 3.72 2.8 12.91 7.40 21084 2.9 4.63 2.8 12.90 7.42 21112 3.1 4.64 2.9 12 .9 0 7.43 21124 2.7 4.11 3.0 1 2.93 7.48 21191 3 . 3 4.65 2.8 12.87 7.39 21058 1.7 2.78 1.0170E+2 4.5149E+2 2.5993E+2 7.3932E+5 9.3300E+1 1.4386E+2 100.0 100 . 0 100.0 100.0 100.0 100.0

02/11/2013 09 , 49 NOx Rate lb/mmBtu 0-1 0.008 0.008 0 . 008 0.008 0 . 008 0.008 0.008 0.008 2.8000E-1 1 00.0 Stk NOXc 

### ppm 0-300 2.14 2.21 2 . 14 2.07 2 . 07 2.14 2.22 2.07 7.5010E+1 100.0 Stk COe Gas 

### ppm 0-1000 hscfh hsefh 0

- 10000 0-1 1.92 8832.0 110.0 107. ( 1.99 8851.8 110.0 106. : 1.99 8848.8 110.0 106.' 2.14 8813.4 110.0 106.' 2.29 8836.2 110 . 0 107. ( 1.97 8841.4 110.0 106.6 2.44 8902 .2 110.0 108. 1.25 8797.8 110.0 105. 6.8820E+1 3.0945E+5 3.8500E+3 3.7335E+ 100.0 100 . 0**100.~** 100.



### 4>Summary

- I-Min RATA

- Continued PagE

## Appendix B.1.2 Sentinel Unit 4 Ammonia, 

## ROG and 

## NOxlCO Testing



## R041 0688 8-4

# Data Summary Report Company : CPV Sentinel, LLC 62575 Powerline Road Desert Hot Springs, CA 92240 

# 5li'.\Vu\ L{

# Co~p \1

# ~vt 

# I**70~** S ource : Turbine 4 Data Group : Report Name : 

### Start of Report : 4>1-Min Cales 

### 4>Summary

- I-Min RATA 02/12/ 2 013 11,58 G34 -C4 

### End of Report, 02/12/2013 13 , 07 G34-Cll G34-C13 G34 -CIO 

# TRACE
EIU J i ronm elllai S.lIs l ems , I n c .

validation: 

### All Available Data G34-C6 G34-C7 G34-Ca 

### Group#- Channel# 

### Long Descrip
. Short Descrip
. Units G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4 >NOx Mass G34-C20 4>StkFlow



### StkFlow

kscfh 0-300000 G34-C3 4>Stk CO

Stk 

### co 4>ca Mass 4>NOx Rate 4>Stk NQXc 4>Stk COc 4>Gas Flow 

### Stk CDc Gas hscfh G34-C18 

### 4>NH3 Inj NH3Inj

Ib/hr 0-200 G34-C 

### 4>MW Lo

MW Lo Range 02/12/20 1 3 11:58 02/12/2013 11:59 02/12/ 2 013 12:00 02/12/2013 12:01 02/12/2013 12:02 02/12/2013 12:03 02/12/2013 12:04 02/12/ 2 013 12:05 02/12/2013 12:06 02/12/2013 12:07 02/12/2013 12:08 02/12/2013 12:09 02/12/2013 12:10 02/12/2013 12:11 02/12/2013 12:12 02/12/2013 12:13 02/12/2013 12:14 02/12/ 2 013 12:15 02/12/2013 12:16 02/12/2013 12:17 02/12/2013 12:18 02/12/2013 12:19 02/12/2013 12:20 02/12/2013 12:21 02/12/2013 12:22 02/12/2013 12:23 02/12/2013 12:24 02/12/ 2 013 12:25 02/12/2013 12:26 02/12/2013 12:27 

### Date/Time Printed: 1.6 1.6 1.6 1.6 1.6 1.7 1.7 1.8 1.8 1.7 1.7 1.7 1.7 1.8 1.8 1.9 1.8 1.B 1.7 1.B 1.9 1.9 1.9 1.9 1.9 

### 2.0 1.9 1.9 1.9 1.9 Stk 02 \ 0-25 14.09 14.09 14.10 14 .10 14 .10 14 .10 14 .10 14.09 14.09 14.08 14.08 14.08 14.08 14.08 14.08 14.08 14.09 14.09 14.10 14.10 14 .10 14 .10 14 .10 14 . 09 14.08 14.09 14.09 14.08 14.09 14.09 

### 02/12/2013 12,56 NOx Mass 1b/hr 0-100 2.82 2.81 2.81 2.82 2.81 2.82 2.80 3.38 3.40 2.84 2.83 2.83 2.81 3.39 3.39 3.39 3.39 3.38 2.81 3.37 3.37 3.37 3.37 3 . 36 3.36 3.36 3.35 3.34 3.35 3.36 15062 15032 15049 15103 15029 15078 14995 15035 15165 15138 15111 15116 15020 15059 15081 15099 15082 15074 1503 4 15054 15044 15037 15035 14978 14951 14966 14941 14877 14907 14953 

### ppm 0-1000



### D.' D.' D.' D.' 

### D.' D.' D.' 

### D.' D.' D.' D.' D.' 

### D.• D.' D.' D.' D.' D.' 

### D.' D.' 

### 0.5 0.5 

### 0.5 0.5 

### D.' 

### 0.5 0.5 0.5 

### 0.5 0.5 

### CO Mass 1b/hr 0-100 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.57 0.56 0.56 0.57 0.57 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 

### N Ox Rate Ib/mmBtu 

### 0-1 0.005 0.005 0.005 0 . 005 0.005 0.005 0.005 0.006 0.006 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXc 

### ppm 0-300 1. 39 1. 39 1. 39 1. 39 1. 39 1.48 1.48 1. 56 1. 56 1.47 1.47 1. 47 1.47 1. 56 1. 56 1.64 1. 56 1. 56 1.48 1. 56 1. 65 1. 65 1. 65 1. 65 1. 64 1. 73 1. 65 1. 64 1. 65 1. 65 ppm hscfh 0-1000 0-10000 0.35 0.35 0 . 35 0 . 35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0 . 35 0.35 0 . 35 0.35 0.35 0.35 0 . 35 0.35 0.43 0.43 0.43 0 .4 3 0.35 0 . 43 0.43 0.43 0 . 43 0 . 43 5366.4 5355.6 5353.8 5373.0 5346.6 5364.0 5334.6 5356.8 5403.0 5401.2 5391.6 5393.4 5359 . 2 5373.0 5380 . 8 5387.4 5373.6 5370.6 5348 .4 5355.6 5352.0 5349.6 53 4 9.0 533 6 .4 5334.6 5332.2 5323.2 5308.2 5311 . 2 5327.4 109.5 111.2 109.5 109.0 108.3 108.8 106.3 106.5 108 . 8 109.3 108.3 108.3 106.7 107.2 108.2 108.5 107.3 106.5 105.3 105.2 105.7 103.5 104 . 3 104.7 103.7 102.8 103.8 102.2 101.5 102. 2 

### 0-1 55.: 55. ! 55.' 55.' 55.1 55.: 54.: 55.' 55. 55.' 55.: 55.' 55. ! S5. : 55. : 56.1 5S. : 55. ! 55. ! 55.! S5.1 55.1 S4. : S5. 1 54. ! 55.1 54. : 54. : 54. : 55.1 

### pagE

### Group#-Channel# Long Descrip. S h o rt De scrip
. Units Range 02/12/2013 12:28 02/12/2013 12:29 02/12/2013 12:30 02/12/2013 12:31 02/12/2013 12:32 02/12/2013 12:33 02/12/2013 12:34 02/12/2013 12;35 02/12/2013 12;36 02/12/2013 12:37 02/12/2013 12;38 02/12/2013 12:39 02/12/2013 12:40 02/12/2013 12 : 41 02/12/2013 12;42 02/12/2013 12:43 02/12/2013 12:44 02/12/2013 12:45 02/12/2013 12:46 02/12/2013 12:47 02/12/2013 12:48 02/12/2013 12;49 02/12/2013 12:50 02/12/2013 12;51 02/12/2013 12:52 02/12/2013 12:53 02/12/2013 12;54 

### Period Av e rage Period Max Value Period Min Value Period Totals ::: Period 

### % Recovery

Date/Time Printed: G3 4- C4 G34-C11 G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass

2.0 2.0 2.1 2.2 2.' 2.6 2.' 2.6 2.7 2.' 2.6 2.7 2.' 2.' 2.' 2.' 2.' 2.' 2.' 2.' 2.' 2.2 2.B 2.9 3.2 3.0 2.9 2.1 3.2 1.6 1.2130E+2 82,6 

### Stk 02 t 0-25 14.09 14.09 14.09 14.09 14.10 14.08 14.09 14.09 14.08 14.09 14.09 14.09 14.09 14.09 14.08 14.09 14.09 14.08 14.08 14.09 14.09 14.09 14.09 14.10 14.09 14 .10 14.09 14.09 14 .10 14.08 8.0312E+2 8 2 .6

02/12/2013 12:56 NOx Mass Ib/hr 0-100 3.34 3.35 3.91 3.92 4.48 4.49 4.47 4.46 5.03 4.45 4.45 5.04 4.46 4.45 4.46 4.45 4 .46 4 .47 4.48 4.47 4.47 3.90 5.01 5.00 5.57 5.56 5.02 3.79 5.57 2.80 2.1611E+2 82.6 G34-C20 4>StkFlow

StkFlow

kscfh 0-300000 G34-eJ 4>Stk CO

Stk CO 

### ppm 0-1000 14890 0.5 14909 0.5 14922 0.5 14960 0.4 15007 0.4 14995 0.4 14934 0.4 14907 0.5 14906 0.4 14855 0.5 14877 0.5 14981 0.5 14912 0.5 14853 0.5 14885 0.5 14880 0.5 14899 0.5 14926 0.5 14954 0.4 14949 0.5 14938 0.5 14884 0.5 14872 0.5 14867 

### O.S 14889 0.5 14877 0.5 14912 0.5 14978 0.5 15165 0.5 14853 0.4 8.5374E+5 2.5800E+l 82.6 82.6 G34-C13 G34-C10 G34-C6 4>CO Mass 4>NOx Rate 4>Stk NOXe

CO Mass NOx Rate lb/hr ' lb/mmBtu 0-100 0-1 0.56 0.5 6 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.5 6 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.56 3 . 1980E+l 82.6 0.006 0.006 0.007 0.007 0.008 0.008 0.008 0.008 0.009 0.008 0.008 0.009 0.008 0.008 0.008 0.008 0 . 008 0.008 0.008 0.008 0.008 0.007 0 . 009 0.009 0.010 0 . 010 0.009 0.007 0.010 0.005 3.8600E-1 82.6 Stk NOXe 

### ppm 0-300 1. 73 1. 73 1. 82 1. 91 2.08 2.25 2.08 2.25 2.34 2.08 2.25 2.34 2.17 2.08 2.16 2.17 2.17 2.16 2.08 2.08 2.08 1. 91 2.43 2.52 2.77 2.60 2.51 1. 84 2.77 1. 39 1.0514E+2 82.6 G34-C7 G34-C8 4 >Stk COe 4>Gas Flow

Stk COe Gas hsefh ppm hsefh 0-1000 0-10000 0.43 0.43 0.43 0.35 0.35 0.35 0.35 0. 4 3 

## o 3. 0.43 0.43 0.43 0.43 0 . 43 0.43 0.43 0 . 43 0.43 0.35 0. 4 3 0.43 0.43 0.43 0.43 0.43 0 . 43 0.43 0.39 0.43 0.35 2.2350E+1 8 2 . 6 5305.2 5311. 8 5316.6 5329.8 5338.8 5350.2 5320.8 5311.2 5318.4 5292.6 5300.4 5337.6 5313. 

## a 5292.0 5311. 2 5301.6 5308.2 5325.6 5335.8 5326.2 5322.0 5302.8 5298.6 5289.0 5304.6 5292.6 5313.0 5336.5 5 4 03,0 5289.0 3.04 1 8E+5 82.6 G34-C18 4>NH3 Inj NH3Inj



### 1b/hr 0-200 101.7 101.7 102.7 100.5

98.3 99.0 98.0 97 . 5 98.0 97.7 96.5 98.5 97.3 97.2 96.7 97.8 97 . 7 97.8 99.3 99.2 99.2 97.5 93.8 92.2 93.2 92.3 95.0 102.3 111. 2

92.2 5,8294E+3 82 . 6

4>Summary

- 

### I-Min RATA

- 

### Continued G34

- C 4>MW Lo

MW Lo

0

- 1 54. : 54.: 54 .. 55.1 55.1 55.: 54. ! 54.1 54.: 54.: 54.: 54.' 54.1 54.1 54.' 54. ! 54. : 54. ' 55.1 54.: 54. ! 54.: 54." 54. ' 54. : 53: 54.' 54.8

56. 53. 3.1273E+ B2.



### PagE

# Data Summary Report C

o mpany : CPV Sentinel, LLC 62575 Powerline Road Desert Hot Springs, CA Source: Data Group: Report Name: 

### Start of Report : 

### Turbine 4 4>1-Min Cales 4>Summary

- l-Min RATA 02/12/2013 13,30 G34-C4 92240 

# if 5eAfi,f(,l**C(?~f\iW1Lt** 

# Z ?o'l, End of Report, 02/12/2013 14,39 G34

- Cl1 G34 - C13 

# TRACE Enviro nm e nt a l Sy st e m s, II/C.

Validation: All Available Data G34-CIO G34-C6 G34-C7 G34-CB G34-C 

### Group#-Channel# 

### Long Descrip
. Short Descrip
. Units G34 -C 2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass G34 -C20 

### 4;:.StkF!ow



### StkFlow

kscfh 0-300000 G34 -C 3 4>Stk CO

Stk CO 

### ppm 0-1000 4>CO Mass 4>NOx Rate 4>Stk NQXc 4>Stk COc 4 >Gas Flow G34 -C18 4>NH3 Inj NH3Inj



### lb(hr 0

- 200 4>MW La 

### Range 02/12/2013 13:30 02/12/2013 13:31 02/12/2013 13: 32 02/12/2013 13:33 02/12/2013 13:34 02/1 2 /2013 13:35 02/12/2013 13:36 02/12/2013 13:37 02/12/2013 13:38 02/12/2013 13:39 02/12/2013 13:40 02/12/2013 13:41 02/12/2013 13:42 02/12/2013 13:43 02/12/2013 13:44 02/12/2013 13:45 02/12/2013 13:46 02/12/2013 13:47 02/12/2013 13:48 02/12/2013 13:49 02/12/2013 13:50 02/12/2013 13:51 02/12/2013 13:52 02/12/2013 13:53 02/12/2013 13:54 02/12/2013 13:55 02/12/2013 13:56 02/12/2013 13:57 02/12/2013 13:58 02/12/2013 13:59 

### Date/Time Printed: 1.6 1.8 1., 1.8 1.7 1.7 1.8 1.8 1.8 1.. 1.. 2.0 1.8 1.8 2.0 1.' 1.. 

### 1.. 2.1 1.. 1.. 1.. 2.0 2.1 1.' 1.8 1.8 1.8 1.8 1.8 Stk 02 % 0-25 14.07 14.06 1 4.06 14.06 14 . 07 14.07 14.07 14.07 14.06 14.06 14.06 14.06 14 . 07 14.07 14.07 14.07 14.07 14.07 14.07 14.07 14.07 14 . 07 14.06 14.05 14.05 14.05 14.04 14.04 14.0 4 14.04
02/12/2013 17,45 

### NOx Mass 

### lb(hr 0

- 100 2.79 3.36 3.38 3.37 2.79 2.78 3.35 3.35 3.35 3.36 3.35 3.35 3.34 3.34 3.33 3.33 3.34 3.34 3.90 3.34 3.34 3.36 3.36 3.94 3.39 3.39 3.40 3.40 3.38 3.39 14880 14896 14969 14951 14891 14810 14864 14889 14857 14884 14880 14880 14825 14820 14805 14796 14832 14827 14833 14835 1 4 845 1 4 917 14897 14946 15011 15026 15034 15034 1 4 934 14976 

### D.' D.' D.' 0 . 4 0.4 0.5 0.4 0.5 0.4 0.4 

### D.' 0.4 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.4 0.5 0.4 0.4 0.4 0.4 0.4 D.' 0.4 0.4 0.4 CO Mass 

### lb(hr 0-100 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.56 0.56 NOx Rate 

### IbjmmBtu 0-1 0.005 0.006 0.006 0 . 006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.00 6 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.00 6 0.00 6 0.006 0.007 0.006 0.006 0.006 0 . 00 6 0.00 6 0.006 Stk NDXc 

### ppm 0-300 1. 38 1. 55 1. 64 1. 55 1. 47 1. 47 1. 55 1. 55 1. 55 1. 64 1.64 1. 73 1. 55 1. 55 1.73 1. 64 1. 64 1. 64 1. 81 1. 64 1. 64 1. 64 1. 73 1. Bl 1.64 1.55 1. 55 1.55 1.55 1. 55 Stk COc Gas 

### hscfh ppm 0-1000 0.35 0.35 0.35 0.35 0.35 0.43 0 . 35 0.43 0.35 0.35 0.35 0.35 0 .4 3 0 . 43 0.43 0.43 0.43 0.43 0.43 0 . 35 0.43 0 . 35 0.35 0.34 0.34 0.34 0.34 0.34 0 . 3 4 0.34 

### hscfh 0-10000 5317.2 5330.4 5356.8 5350.2 5320.8 5292.0 5311.2 5320.2 5316.6 5326.2 5325.0 5325.0 5297.4 5295 . 6 5290.2 5287.2 5299.8 5298.0 5300.4 5301. 

## a 5304.6 5330.4 5331. 

## a 5356.2 5379.6 5385.0 5395.8 5395.8 5359.8 5374.8 107.7 107.5 107.0 10B.S 10 7 .2 104.8 105.0 106.7 105.5 105.2 106.7 10 4 .7 105.5 103.2 103.2 104.5 103.2 103.7 104.3 103.5 103.7 104.2 104.2 104.2 109.2 109.B 109 .7 110.8 109.2 108.7 MW La 0-1 54. 55. r S5.: 54. : 54. : 54 . . 55. r 54 .. 54 . . 54.: 54 . . 54. : 54. r 54.1 54.: 54 . . 54 . . S4.1 54.' 54.' 54.' 55.1 54.' 54.: 55, ' 55,' 55.! 55,: 55 . ' S5. ! 

### pagt

### Group#-Channel# Long Descrip
. Short Descrip
. units Range 02/12/2013 14:00 02/12/2013 14:01 02/12/2013 14:02 02/12/2013 14:03 02/12/2013 14:04 02/12/2013 14:05 02/12/2013 14:06 02/12/2013 14;07 02/12/2013 14:08 02/12/2013 14;09 02/12/2013 14:10 0 2 / 12 / 2 013 14:11 02/1 2 /2013 14;12 02/12/2013 14:13 02/12/ 2013 14;14 02/12/2013 14:15 02/12/2013 14:16 02/12/2013 14;17 02/12/2013 14:18 02/12/2013 14:19 02/12/2013 14;20 02/12/2013 1 4:2 1 02/12/2013 14:22 02/12/2013 14;23 02/12/2013 1 4:24 02/12/2013 14:25 02/12/2013 14;26 02/12/2013 14:27 02/12/2013 14:28 02/12/ 2 013 14;29 02/12/2013 14:30 02/ 12 / 2 013 14:31 02/12/2013 14:32 02/12/2013 14:33 02/12/ 2013 14:34 02/12/2013 1 4:3 5 02/12/2013 14:36 02/12/2013 14;37 02/12/2013 14;38 02/12/2013 14;39 Date/Time Printed: G34-C4 G34 -ell G3 4 -C20 G34-C2 

### 4>Stk NOx

Stk NOx 

### ppm 0-150 

### 4>Stk 02 

### 4>NOx Mass 4>StkFlow

1.8 1.9 1.9 1.8 1.9 1.9 1.9 1.9 1.9 1.9 2.0 2.0 1.8 1.6 1.6 1.6 1.6 1. 6 1.7 1.7 1.7 1.8 1.7 1.8 1.7 

### 1 . 7 1.8 1.8 1.7 1.8 1.8 1.9 1.9 1.9 2.0 1.8 1.9 1.9 1.9 1.9 

### Stk 02 

# • 0-25 14.04 14.03 1 4.02 14.03 14.03 14.04 14.04 14.05 14. OS 14.05 14.05 14.05 14.04 14.05 14.04 14.05 14.04 14.04 14.03 14.04 14. 04 14 . 03 14.04 14.04 14.04 14.04 14.04 14 . 04 14.04 14.04 14.03 14.04 1 4. 0 4 1 4.04 14.03 14.03 14.04 14.05 14.05 14. OS 

### 02/12/2013 17,45 NOx Mass lb/hr 0

- 100 3.38 3.39 3.40 3.40 3.39 3.37 3.36 3.36 3.36 3.35 3.3 5 3.37 3.36 2.81 2.81 2.80 2.81 2.81 2.81 2.81 2.81 3.38 2.81 3.37 2.81 2.80 3.37 3.37 2.80 3.36 3.37 3.36 3.36 3.37 3.38 

### 3.38 3.37 3.37 3.37 3.37 

### StkFlow kscfh 0-300000

14934 14964 15007 15004 14972 14921 14867 14896 14860 14839 14845 1 4921 14869 14907 14916 14899 14937 14899 14906 14912 14929 14922 14892 14892 14887 14857 14887 14919 14864 14881 14877 14864 14852 14897 14936 14911 14901 1 4 914 14912 14944 G34-C3 G34-C13 G34-C10 G34-C6 G34-C7 G34 -C8 G34-C18 

### G34-C 4>Stk CO 4>C O Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH3 Inj 4>MW La

Stk CO 

### ppm 0-1000

0.4 0.4 0.4 0.4 0.' 0.4 0.4 0.4 0. ' 0. 4 0 .• 0.4 0.' 0. 4 0 .' 0.4 0.4 0. 4 0.4 0.' 0 . 5 0.' 0.' 0.4 0 .4 0.' 0.' 0.' 0 .4 

### 0.4 0.4 

### 0.4 0.4 

### 0.4 0 .4 0.' 

### 0.4 0.5 0.5 

### 0.5 CO Mass lb/hr 0-100 0.56 0.56 0.57 0.57 0.57 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0 .56 0 . 56 0.56 0.56 0 . 56 0 . 56 0 . 56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 

### NOx Rate Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.006 0.005 0.005 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.006 0.006 

### Stk 

### NOXc 

### ppm 0-300 1. 55 1. 63 1. 63 1. 55 1. 63 1. 63 1. 63 1. 64 1. 64 1. 64 1. 72 1. 72 1. 55 1. 38 1. 38 1. 38 1. 38 1. 38 1. 46 1. 46 1. 46 1. 55 1.46 1. 55 1.46 1. 46 1. 55 1. 55 1. 46 1. 55 1. 55 1. 63 1. 63 1. 63 1.72 1. 55 1. 63 1. 64 1. 64 1. 64 

### Stk COc Gas hscfh ppm 

### hscfh 0-1000 0-10000 0 . 34 0.34 0.34 0.3 4 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.3 4 0.34 0.3 4 0.3 4 0.34 0.34 0.34 0 .34 0.34 0.43 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.3 4 0 .34 0.34 0 .3 4 0.34 0.34 0.34 0.43 0.43 

### 0.43 5359.8 5378. 4 5401.8 5392.8 5381.4 5355.0 5335.8 5338.2 5325.6 5317.8 5320.2 5347.2 5336.4 534 2 .4 5353.2 5339.4 5361.0 5347.2 5357.4 5352.0 5358.0 5363.4 53 44.S 5344.8 5343.0 5332.2 5343.0 5354.4 5334.6 5340.6 5347.2 5334.6 5330.4 5346.6 536S.2 5359.2 5347.8 534 4. 

### f! 5344.2 5355.6 

### NH3Inj 

### 1b/hr 0

- 200 107.5 10S.5 108.S 109.2 10S.3 10S.3 106.8 106.2 106.3 104.8 104.7 106.S 109.8 110.8 110.3 110.2 110.2 Ill. 7 110.0 110.2 109.5 109.3 109 .2 107.7 108.5 107.7 107.3 108.7 107.7 106.7 108.3 1 06.8 104.8 105.S 106.0 106.S 106.0 105.0 105.5 105.3 4 >S ummary - I-Min RATA

- Continued MW Lo 0-1 55. ' 55 55 . . 55. ' 55 .. 55. : 54 .. 55. : 54. : 54. : 5 ' 54 55. : 55 . . 55. : 55. : 55.1 55.: 55 .**~** 55.: 55.1 55.1 55.1 54 .. 55 . . 5 4. 5 4. : 55. : 54.: 54.: 55 . . 54. : 54 . . 55.1 55. : 55 . . 5 4. : 55. : 5' 55.: pagE

### Period Average E: 

### loB 14 . 05 3.26 14901 0.4 0.56 0.006 1. 58 0.36 5340.8 107.0 54.9 

### Period Max Value 2.1 14.07 3.94 15034 0.5 0.57 0.007 1. 81 0.43 5401.8 111. 7 55. 

### Period Min Value 1.6 14.02 2.78 14796 0.4 0.56 0.005 1. 38 0.34 5287.2 103.2 54. 

### Period Totals = 1.2820E+2 9.8344E+2 2.2827E+2 1.0430E+6 2.9400E+l 3.9260E+1 4.0700E

- 1 1.1042E+2 2 . 5190E+l 3.7385E+5 7.4933E+3 3.8448E+ 

### Period 

### % Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

# Data Summary Report Company: CPV Sentinel, LLC 62575 Powerline Road 

### Desert Hot Springs, CA 92240

# 5v.h~\ 

# '1**~r:"rlt.<. ~{**  So urce : Turbine 4 Data Group : 4>1-Min Cales Report Name : 

### Start of Report : 4>Summary

- I-Min RATA 02/11/2013 15,45 G)4-C4

# 1?~ End of Report: 02/11/2013 16:52 G34-Cll G34-C20 G34 -C 13

# Q~~l{ 

# TRACE

--- 

## .-. 

## EnlJi ronm e ntal Systems, Illc
.

validation: 

### All Available Data G34-CIO G34 -C6 G34 -C7 G3 4-CB G34-C 

### Group#-Channel# 

### Long Descrip
. Short Descrip. Units G34-C2 4>Stk NOx

Stk NOx ppm 0-150 4>Stk 02 4>NOx Mass 

### 4 >StkFlow StkFlow

kscfh 0 -30000 0 G34-C3 4>Stk CO

Stk CO ppm 0-1000 4>C O Mass 4>NOx Rate 4>Stk NOXc 4>Stk CDc 4>Gas Flow 

### Stk CDc Gas hscfh G34 -C18 4>NH3 Inj NH3Inj



### Ib/hr 0-200 4>MW Lo MW Lo 

### Range 02/11/20 13 15:45 02/1 1/2013 15:46 02/11/ 2 013 15:47 02/11/2013 15:48 02/11/2013 15:49 02/11/20 13 15:50 02/11/2013 15:51 02/11/2013 15:52 02/11/20 13 15:53 02/11/ 2013 15 :54 02/1 1 / 2013 15 :55 02/11/2013 15: 56 02/11/2013 15:57 02/11/2013 15:58 02/ 11 /2013 15:59 02/11/ 2013 16:00 02/11/2013 16:01 02/11/2013 16:02 02/11/20 13 16:03 02/1 1 /2013 16:04 02/11/2013 16:05 02/11/ 2013 16:06 02/11/ 2 013 16:07 02/ 11/2013 16:08 02/11/2013 16:09 02/ 11 /2013 16:10 0 2 /11/2013 16:11 02/11/ 2013 16:12 0 2 / 11/2013 16:13 02/11/2013 16;14 

### Date/Time Printed : 2.2 2.2 2.2 2.0 2.0 2.1 2.1 2.2 2.1 2.0 2.1 2.1 2.1 2.1 2.0 2.0 2.1 2.2 2.1 2.2 2.3 2.1 2.1 2.2 2.1 2.1 2.1 2.2 2.3 2.3 Stk 02 % 0-25 13.52 13.52 13.52 13.53 13.53 13.54 13.54 13.5 4 13 .54 13.54 13.54 13.53 13.54 13.54 13 .54 13 .55 13.55 13.55 13.54 13 .55 13.55 13.55 13.5 4 13.53 13.5 4 13.54 13 .54 13.53 13.53 13 .53
02/11/2013 19,07 NOx Mass 

### 1b/hr 0-100 4.42 4.42 4.42 4.41 4.40 4.39 4.39 4 .3 9 4.39 4.39 4 .40 4.41 4.41 4.42 4.41 4 .40 4 .40 5.15 4.41 5 .14 5.15 4.41 4.42 4.42 4.40 4.41 4.39 4.41 5.15 5.16 18163 18172 18183 18164 18111 18114 18100 18086 18108 18089 18139 18135 18180 18202 18195 18142 18172 18218 18183 18176 18211 18215 18202 18199 18156 18187 18111 18169 18163 18217 1.7 1.8 1.6 1.6 1.9 2.2 2.3 2.3 2.6 2.3 2.0 1.9 1.7 1.6 1.6 1.7 1.8 1.6 1.6 1.6 1.3 1.2 1.' 1.' 1.. 1.5 1.6 1.6 1.5 1.5 CO Mass 

### 1b/hr 0-100 2.21 2.21 2.21 2.21 2.20 2.93 2.93 2.92 3.66 2.93 2 . 93 2.20 2.21 2.21 2.21 2.20 2.20 2.21 2.21 2.20 1.47 1.47 2.21 2.21 2.20 2.21 2.20 2.21 2.21 2.21 

### NOx Rate Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.007 0.007 0.006 0 . 006 0.006 0.006 0.006 0.006 0.006 0.00 7 0.007 Stk NOXc ppm 0-300 1. 76 1. 76 1. 76 1. 60 1. 60 1. 68 1. 68 1. 76 1. 68 1. 60 1.68 1. 68 1. 68 1. 68 1. 60 1. 61 1. 69 1. 77 1. 68 1. 77 1. 85 1. 69 1. 68 1. 76 1. 68 1. 68 1. 68 1. 76 1. 84 1. 84 

### ppm hscfh 0-1000 0-10000

1. 36 1.44 1. 28 1. 28 1. 52 1. 76 1. 84 1. 84 2.08 1.84 1.60 1. 52 1. 36 1.28 1. 28 1. 36 1. 44 1. 28 1. 28 1. 28 1.04 0.96 1.12 1.12 1.12 1.20 1.28 1.28 1.20 1.20 7012.8 701 6.4 7020 .6 7003.8 6983.4 6975.0 6969 . 6 6964.2 6972.6 6965.4 6984.6 6992.4 7000.2 7008.6 7006 .2 6976.2 6987.6 7005 .6 7001.4 6989.4 7002.6 7004. 4 7008.6 7017.0 6991. 2 7003.2 6973.8 7005.6 7003.2 7024.2 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 11 0.0 110.0 110.0 110.0 110.0 1 1 0.0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 11 0.0 110.0 110.0 110.0 0

- 1 81.' 81.1 81." 81.! 80 . ! 80. : 80. : 79. 80 . . 80.1 80. : 80.: 81.1 81.1 81.' 80 .. 80 .. 81. : 80. : 80 .. 81.: 80 . . 81.1 81.: 80. : 81.: 80 . . 81.: 80. : 81."**Pag~**

### Group#-Channel# Long Descrip. Short Descrip. Units Range 02/11/2013 16:15 02/11/2013 16:16 02/11/20 13 16:17 02/11/2013 16:18 02/11/2013 16:19 02/11/2013 16:20 02/11/2013 16:21 02/11/2013 16:22 02/11/2013 16:23 02/11/2013 16:24 02/11/2013 16;25 02/11/2013 16:26 02/11/2013 16:27 02/11/2013 16:28 02/11/2013 16:29 02/11/2013 16:30 02/11/2013 16:31 02/11/2013 16:32 02/11/2013 16:33 02/11/2013 16:34 02/11/2013 16:35 02/11/2013 16:36 02/11/2013 16:37 02/11/2013 16:38 02/11/2013 16 : 39 02/11/2013 16:40 02/11/20 13 16:41 02/11/2013 16,42 02/11/2013 16:43 02/11/2013 16:44 02/11/2013 16:45 02/11/2013 16:46 02/11/2013 16:47 02/11/2013 16:48 02/11/2013 16:49 02/11/2013 16;50 02/ 11 /2013 16 : 51 02/11/2013 16:52



### Date/Time Printed: G34-C4 G34-C11 G34-C20 G34 -C3 G34-C13 G34-C10 G34-C6 G34-C7 G34-C8 G34-C18 G34-C G34-C2 4>Stk NOx Stk NOx 

### ppm 0-15 0 4>Stk 02 4>NOx Mass 4>StkFlow 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH3 Inj 4>MW Lo

2.1 2.1 2.2 2.2 2.2 2.2 2.3 2.4 2 .• 3.0 2.9 2.9 2.8 2.8 2.8 2.6 2.8 2.8 2.7 2.8 2.7 2.7 2.6 2.7 2.7 2.7 2 .• 2.4 2.5 2.6 2.6 2.7 2.6 2.6 2.5 2.5 2.' 2.3 Stk 02 

# • 0-25 13.53 13.53 13.53 13.53 13.53 13.53 13.5 4 13.53 13.53 13.54 13.55 13.55 13.55 13.55 13.55 13.55 13.53 13 .54 13.54 13.55 13.55 13.55 13 .55 13.54 13.55 13.54 13 .54 13.53 13.52 13.52 13.52 13.53 13.52 13.53 13.54 13.54 13.55 13 .56

02/11/2013 19,07 NOx Mass 1b/hr 0-100 4.42 4.42 4.42 4.42 4.43 4.42 5.17 5.16 5.90 6.66 6.63 6.64 5.90 5.92 5.91 5.87 5.89 5.92 5.91 5.89 5.89 5.89 5.89 5.91 5.90 5.92 5.93 5.19 5.18 5.93 5.93 5.93 5.94 5.95 5.19 5.20 5.19 5.16 StkFlow kscfh 0-300000

18197 18177 18178 18178 18245 18211 18264 18211 18220 18300 18233 18270 18261 18321 18295 18175 18199 18289 18258 18250 18247 18242 18228 18284 18261 18312 18320 18298 18264 18287 18276 18314 18317 18362 183 25 18368 18379 18282 Stk CO 

### ppm 0-1000

1., 1.4 1.5 1.5 1.7 1.4 1.3 1.2 1.2 1.0 1.0 1.0 1.0 1.0 1.0 1.1 1.1 1.0 1.0 1.0 1.1 1.1 1.1 1.1 1.0 1.0 0.9 1.0 1.0 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 1.0 Co Mass 1b/hr 0-100 2.21 2.21 2.21 2.21 2.22 2.21 1. 48 1.47 1. 48 1.48 1.47 1.48 1.47 1.48 1.48 1. 47 1. 47 1.48 1.48 1.47 1.47 1. 47 1. 47 1.48 1.47 1. 48 1. 48 1.48 1.48 1.48 1.48 1.4B 1. 49 1. 49 1. 4B 1.49 l.4B 1.47 NOx Rate 

### Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.007 0.008 0 . 009 0.009 0.009 

### O.OOB 0.008 0.008 

### O . OOB 0.008 

### O.OOB 0.008 0.008 0.008 

### O.OOB 0.008 0.008 0.008 0.008 0.008 0.007 0.007 0.008 0.008 

### O.OOB 0.008 0.008 0.007 0.007 0 . 007 0.007 Stk NOXc 

### ppm 0-300 1. 68 1. 68 1. 76 1. 76 1. 76 1. 76 1. 84 1. 92 2.08 2.40 2.33 2.33 2.25 2.25 2.25 2.09 2.24 2.24 2.16 2.25 2.17 2.17 2.09 2.16 2.17 2.16 2.08 1. 92 2.00 2.08 2.08 2.16 2.08 2.0B 2.00 2.00 1. 93 1. 85 Stk COc Gas hscfh ppm hscfh 0-1000 0-10000

1.12 7016.4 1.12 7008.6 1.20 7009.2 1.20 7009.2 1.36 7035.0 1.12 7021. 8 1.04 7032.6 0.96 7021.8 0.96 7025.4 0.80 7046.4 0.80 7011.0 0.80 7025.4 0.80 7021.8 0 . 80 7045 .2 0.80 7035.0 0.88 6988.8 0.88 7017.0 0.80 7042.2 0.80 7030.2 0.80 7017.6 0.88 7016.4 0.88 7014.6 0.88 7009.2 0.88 7040.4 0.80 7021.8 0.80 7051.2 0.72 0.80 0.80 0.72 0.72 0.72 0.72 0.72 0.72 0.72 0. 72 0 . 80 7054.2 7055.4 7051.8 7060.8 7056.6 7061. 4 7072.2 7080.0 7056.0 7072.8 7067.4 7020.6 NH3Inj 1b/hr 0-200 110.0 110.0 118.5 118.5 119.2 117.7 120.2 119.2 114.5 116.2 115.0 113.7 115.5 118.2 116.0 116.0 116.2 118.7 118.2 118.3 117.2 116.0 116.3 118.3 118.2 119.3 120.3 120.5 121.7 122.3 121.0 122.8 122.0 124.2 121. 2 121. 3 123.3 117.7



### 4>Summary

- I-Min RATA

- Continued MW Lo 0 -1 81.! 81.1 81.! 81.! 81. 82.1 80 .. 81.: 81. ! 81.: 81.: 81. : 81.' 81.! 82.1 81.: 81. . 82. : 81. : 81. : 81. : 80 . . 81.: 81.: 81. . 81.! 82. [ 82.: 83.1 82. r 82. : 82 . ! 81.' 82. : 82. ! 81.: 81. . 81.!

PaqE

### Period Average :c 2.' 13.54 5.12 18220 

### 1.. 1. 92 0.007 1. 90 1.10 7017.5 114.6 81. 2 

### Period Max Value 3.0 13 .S6 6.66 18379 2.6 3.66 0.009 2.40 2.08 7080.0 124.2 83. 

### Period Min Value 2.0 13.52 4.39 18086 0.' 1.47 0.006 1.60 0.72 6964.2 110.0 7'. 

### Period Totals :IE 1.61S0E+2 9.2059E+2 3.479lE+2 1.2389E+6 9.3l00E+l 1.3034E+2 4.7200E-l 1. 293 9E+2 7 . 4480E+l 4.7719E+S 7.7934E+3 S.S27lE+ 

### Period % 

### Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

# Da t a Summa ry Repo r t Company : CPV Sentinel, LLC 62575 Powerline Road 

### Desert Hot Springs, CA 92240 

### S ource : Turbine 4 Da t a Group : 4>1-Min Cales Report Name: S tart of R e po r t : 4>Summary

- I-Min RATA 02/11/2013 17,10

# 5e;.~' 

# tf c,.... p

# l;(Jr1«. ;If-t. 

# 1-7'%
End of Report: 02/11/2013 18:19 G34-C4 G34

- Cl1 G34

- C20 G34

- C3 G34 -C13 

# (2Ifff\- {2wt 

# 5 

# T RAC E Envi ronm en tal S y s tems, In c.

Validation: All Available Data G34-CIO G34

- C6 G34-C7 G34-CB G34 -C18 G34-C 

### Group#-Channel# Lo ng Descrip
. S hort Descrip. Units G34-C2 4>Stk NOx



### Stk NOx ppm 0-150 

### 4>Stk 02 4>NOx Mass 4>StkFlow 

### 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk CDc 4>Gas Flow 4>NH3 Inj 4>MW La 

### Range 02/11/2013 17:10 02/11/2013 17:11 02/11/2013 17:12 02/11/2013 17:13 02/11/2013 17:14 02/11/2013 17:15 02/11/2013 17:16 02/11/2013 17:17 02/11/2013 17:18 02/11/2013 17:19 02/11/2013 17:20 02/11/2013 17:21 02/1 1 /2013 17:22 02/11/2013 17:23 02/11/2013 17:24 02/11/2013 17:25 02/11/2013 17:26 02/11/2013 17:27 02/11/2013 17;28 02/11/2013 17:29 02/11/2013 17:30 02/11/2013 17:31 02/11/2013 17:32 02/11/2013 17:33 02/11/2013 17:34 02 / 11/2013 1 7:3 5 02/11/2013 17:36 02/11/2013 17:37 02/11/2013 17:38 02/11/2013 17:39 

### Date/Time Printed: 2.8 2.B 2.8 2.7 2.7 2.6 2.6 2.5 2.5 2.5 2.' 2.3 2.' 2.5 2.6 2.5 2.5 2.5 2.6 2.5 2.5 2.' 2 . 5 2.7 2.7 2.7 2.7 2.6 2.7 2.7 Stk 02 \ 0-25 13.54 13.54 13.5 4 13 .54 13 .56 13.56 13.55 13.55 13.56 13.56 13.56 13 . 57 13.56 13.57 13.58 13.58 13.58 13.56 13.55 13.56 13.56 13.57 13.57 13.55 13.55 13.56 13.55 13.55 13.55 13.54
02/11/2013 19,07 

### NOx Mass 1b/hr 0-100 5.89 5.89 5.89 5.89 5.90 5.91 5.92 5.18 5.18 5.18 5.17 5.16 5.17 5.16 5.90 5.15 5.14 5.15 5.90 5.14 5.14 5.12 5.11 5.84 5.B4 5.83 5.86 5.85 5. BS 5.86 

### StkFlow kscfh 0-300000

18200 18205 18200 18203 18293 18315 18332 18329 18359 18356 18332 18295 18332 18310 18329 18281 18260 18251 18265 18212 18193 18157 18123 18083 1B072 18059 18128 18115 18111 18 127 Stk CO 

### ppm 0-1000

1.3 1.3 1.3 1.3 1.2 1.2 1.1 1.1 1.1 1.0 1.1 1.1 1.1 1.1 1.1 1.2 1.3 1.3 1.2 1.3 1.3 1.3 1.5 1.5 1.5 1.5 1.5 1.3 1.3 1.3 

### CO Mass 

### 1b/hr 0-100 1.47 1. 47 1. 47 1. 47 1.48 1.48 1.48 1.48 1.48 1. 48 1.48 1.47 1 .4 8 1.47 1. 47 1.47 1.47 1.47 1.48 1. 47 1.47 1.46 2.19 2.19 2.19 2.18 2.20 1.46 1.46 1.47 N Ox Rate 

### Ib/mmBtu 0-1 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.008 0.007 0.007 0.007 0.008 0.007 0.007 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 Stk NOXc 

### ppm 0-300 2.24 2.24 2.24 2.16 2.17 2.09 2.09 2.01 2.01 2.01 1. 93 1. 85 1. 93 2.01 2.10 2.02 2.02 2.01 2.09 2.01 2.01 1. 93 2.01 2.17 2.17 2.17 2.17 2 . 09 2.17 2.16 

### Stk CDc 

### Gas hscfh ppm hscfh 0-1000 0-10000

1.04 1.04 1. 04 1.04 0.96 0.96 0.B8 0.88 0 . 88 0.80 0.88 0.89 0.88 0.89 0.B9 0.97 1. 05 1.04 0.96 1. 04 1. 04 1.05 1.21 1.20 1.20 1. 21 1. 20 1. 04 1. 04 1.04 7008.0 7009 . 8 7008.0 7009.2 7024.8 7033.2 7049 . 4 7048.2 7050.0 7048.8 7039.8 7015.8 7039 . 8 7021.8 7019.4 7000.8 6993.0 7008.6 7023.6 6993.6 6986.4 6963.0 69 4 9.8 6953.4 6949.2 6934.8 6970.8 6966.0 696 4 .2 6979.8 NH3Inj 

### 1b/hr 0-200 115.0 113.7 115.7 114.5 I1B.2 117.3 118.8 118.7 119.8 119.8 119.8 11B.7 118 . 3 118.3 117.2 115.5 115.2 115.8 117.5 116.0 114.8 116.7 112.3 111.8 111. 

## a 111.0 112.0 114.0 114 .3 114.5 MW La 0-1 81. : 80 .. 81.1 80. : 81. : 81. : 81. . 81.' 82.1 81.**~** 81.: 82.1 82.1**81.~** 81. .**Sl.~** BO .. 81.: 81 81 81 80. SO
.. 

### so .**~** 80. : 79. : 80.: 80. : 80 . . 80. : Pagt

### Group#-Channel# Long Descrip . Short Descr i p . Units Range 02/11/2013 17,40 02/11/2013 17:41 02/11/ 2 013 17:42 02/11/2013 17:43 02/11/2013 17:44 02/11/2013 17:45 02/11/2013 17:46 02/11/2013 17:47 02/11/2013 17:48 02/11/2013 17:49 02/11/2013 17:50 02/11/2013 17:51 02/11/ 2 013 17:52 02/11/ 2 013 17:53 02/11/2013 17:54 02/11/2013 17:55 02/11/2013 17:56 02/11/2013 17:57 02/11/2013 17:58 02/11/2013 17:59 02/11/2013 18:00 02/11/2013 18:01 02/11/2013 18:02 02/11/2013 18:03 02/11/2013 18:04 02/11/2013 18:05 02/11/2013 18:06 02/11/ 2 013 18,07 02/11/2013 18:08 02/11/2013 18:09 02/11/2013 18:10 02/11/2013 18:11 02/11/2013 18:12 02/11/2013 18:13 02/11/2013 18:14 02/11/2013 18 :15 02/11/2013 18:16 02/11/2013 18:17 02/11/2013 18:18 02/11/2013 18:19 Date/Time Printed: G34-C4 G34-Cll G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass

2.7 2.7 2.6 2.5 2.' 2.7 2 . 5 2.9 2 . 9 2.8 2.8 2.7 2.6 2.6 2 . 7 2.7 2.7 2 .7 2.6 2.6 2.5 2.5 2. 6 2.5 2.5 2.6 2.5 2.5 2.5 2.5 2.7 3.1 3.1 3.1 2.9 3.0 3.0 2.8 2.B 2.8 Stk 02 

# • 0-25 13 . 55 13.55 13.56 13.56 13.58 13.57 13.57 13.58 13.58 13.58 13.57 13 .58 13.59 13 .58 13.58 13.57 13.57 13.57 13.57 13.58 13.58 13.58 13.57 13.56 13.57 13.57 13.57 13.57 13.57 13.56 13 .56 13.56 13 .5 6 13.5 7 13.57 13.58 13.58 13.57 13.58 13.58 02/11/2013 19, 07 NOx Mass lb/hr 0-100 5.85 5.86 5.85 5.13 5.09 5.85 5.10 6.57 6.56 5.84 5.84 5.82 5.81 5.80 5.80 5.82 5.82 5.81 5.80 5.79 5.06 5.06 5.80 5.10 5.08 5.82 5.08 5.09 5.09 5.09 5.B2 6.55 6.57 6.54 6.55 6.53 6.55 5.83 5.81 5.B2 G34 -C 20 4>StkFlow

StkFlo w

kscfh 0

- 300000

1810B 1B144 1B145 IB159 18096 18166 18107 1B151 1B140 18138 1B140 18099 1 8072 18031 18027 1 8071 18059 18044 17999 17988 17984 17963 18016 18067 18038 18054 18038 18055 18046 1B021 18054 18064 18093 18054 18073 18055 18111 18087 18064 18097 G34-C3 4 >Stk CO

Stk CO 

### ppm 0-1000

1.3 1.4 1.3 1.3 1., 1., 1.4 1.4 1.5 1., 1.' 1.5 1.6 1.7 1.6 1.6 1.4 1.4 1.5 1.6 1.6 1.7 1.7 1.' 1.' 1.5 1.5 1.5 1.5 1.4 1.4 1.4 1.4 1.4 1.5 

### loS 1.5 1.5 1.5 1.5 G34-C13 G34

- CI0 G34-C6 4>CO Mass 4>NOx Rate 4>Stk NOXc

CO Mass 

### 1b/hr 0

- 100 1. 46 2.20 1. 46 1. 46 2.18 2.19 2.19 2.19 2.19 2.19 2.19 2.18 2.18 2.18 2.17 2.18 2.18 2.18 2.17 2.17 2.17 2.17 2.18 2.19 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.19 2.18 2.1B 2.18 2.18 2.18 2.18 2.18 NOx Rate l b /mmBtu 0-1 0.008 0.008 0.008 0.007 0.007 0.008 0.007 0.009 0.009 0.008 0.008 0.008 0.008 0.008 0.00 8 0 . 008 0.008 0.008 0.008 0.008 0.007 0.007 0.008 0.007 0.007 0.008 0.007 0 . 007 0.007 0.007 0.008 0.009 0.009 0.009 0.009 0.009 0.009 0.008 0.008 0.008 Stk N OXc 

### ppm 0-300 2.17 2.17 2.09 2.01 1. 93 2.17 2.01 2.34 2.34 2.26 2.25 2.18 2.10 2.10 2.18 2 . 17 2.17 2 . 17 2.09 2.10 2.02 2.02 2.09 2.01 2.01 2.09 2.01 2.01 2.01 2.01 2.17 2.49 2 . 4 9 2.50 2.33 2.42 2.42 2.25 2.26 2.26 G34-C7 G34 -C8 4>Stk CDc 4>Gas Flow

Stk CDc Gas hscfh ppm hscfh 0-1000 0-10000

1. 04 1.12 1. 04 1. 04 1.13 1.13 1.13 1.13 1. 21 1.13 1.13 1.21 1.29 1.37 1. 29 1. 29 1.13 1.13 1. 21 1. 29 1.29 1.37 1. 37 1.13 1.13 1.21 1. 21 1. 21 1.21 1.13 1.13 1.13 1.13 1.13 1. 21 1.21 1.21 1. 21 1. 21 1 21 6963.0 6976.8 6967.8 6973.2 6930.0 6966.6 6943.8 6951 . 0 6946.8 6946.2 6956 . 4 6931 . 2 6911. 4 6905.4 6903.6 6930.0 6925 . 2 6919.8 6902.4 688 8 .6 6887.4 6879.0 6909 . 0 6937 . 8 6917.4 6923.4 6917.4 6924.0 6920.4 6920.4 6933.0 6936.6 69 48 .0 6923.4 6930.6 6914.4 6936 . 0 6936 . 0 6918 . 0 6930.6 G34-C18 4>NH3 Inj NH3Inj



### 1b/hr 0-200 113 .3 115.0 114 . 5 114.8 112.5 114.7 112.0 109.7 111.2 109. 5 Ill. 8 110.0 109.5 109.5 110.7 109.2 111. 8 112.0 109.7 1 1 0.7 109.2 110.7 109.2 113.0 112.2 112.8 113.2 110.7 111.7 113.8 109.8 109.0 108 .2 108. 2 108.5 109.0 108 . 7 110.8 110.0 110.8 4>Summary

- 1-Min RATA - Continued G34-C 4>MW Lo



### MW Lo 0-1 80 .**~** 80. : 

### BO. BO 79.: 80.1 79. : 80. ! 80.: BO. : 80.**~** 79. : 79. ! 79.: 79.: 79. : 79 .. 80. c 79 .. 79.1 7B .. 79.: 79. : 79. ! 79. : BO .1 79. : 80. : 79.! 79. : 80.: 79 .. BO . ! 80. C 80.1 79 .. 80 .. 79.! 79.! 79 . : Pag(

### Period Average 

# = 2.6 13.57 5.67 1B139 1.' 1. 90 O.OOB 2.13 1.11 6960.6 113 .1 80.3 

### Period Max Value = 3.1 13.59 6.57 1B359 1.7 2.20 0.009 2.50 l.37 7050.0 119.8 82. 

### Period Min Value**~** 2.3 13.54 5.06 17963 1.0 1. 46 0.007 1. B5 O.BO 6B79.0 10B.2 78. 

### Period Totals = 1.B540E+2 9.4957E+2 3.96B2E+2 1.26 9 7E+6 9.6600E+1 1 .32B5E+2 5.4300E-1 1.4915E+2 7.7720E+l 4.B724E+5 7.917BE+3 5.6275E+ 

### Period % 

### Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 1 00.0 100.0 100.

# Data Summary Report Com pany: CPV Sentinel, LLC 62575 Powerline Road 

### Desert Hot Springs, CA Source : Turbine 4 D

a ta Gr o up : 

### Report Narne : Start of Report : 4>1 -M in Cales 4>Summary

- I-Min RATA 02/11/2013 10,06 G34

- C4 92240

# ~i1.u.\ l)""rL-f**Co v'\** **~l.v.L ~** 

# \ \CifJf +

# ~**f\**
End of Report: 02/11/2013 11:19 G34

- Cll G34 -C 20 G34 -C3 G34 -CD G34

- CI0 

# TRAC E EnlJi ro nm enlal Syste ms , In c.

validation: All Available Data G34

- C6 G34

- C7 G3 4 -C8 G34

- C18 G34

- C 

### Group#

- Channel# Lo ng De s crip
. 

### Short Desc rip
. Unit s G34 -C2 

### 4 :>Stk NOx

Stk NOx 

### ppm 0-150 

### 4 >St k 02 4>NOx Mass 4>StkFlow 4>Stk C O 4 >CO Mass 4>NOx Rate 4>Stk NOXc 4 >Stk CDc 4>Gas Flow 4>NH3 Inj 4>MW Lo 

### Range 02/11/2013 10 : 06 02/11/2013 10:07 02/11/2013 10:08 02 /1 1/2013 10:09 02/11/2013 10:10 02/11/2013 10:11 02/11/2013 10:12 02/11/2013 10:13 02/11/20 13 10:14 02/11/2013 10:15 02/11/2013 10:16 02/11/2013 10:17 02/11/2013 10:18 02/11/2013 10:19 02/11/2013 10:20 02/11/2013 10:21 02 / 11/2013 10 : 22 02/11/2013 10:23 02/11/2013 10:24 02/11/2013 10,25 02/11/2013 10:26 02/11/2013 10:27 02/11/2013 10:28 02/11/2013 10:29 02/11/2013 10:30 02/11/2013 10:31 02/11/2013 10:32 02/11/2013 10:33 02/11/2013 10:34 02/11/2013 10:35 

### Date/Time Printed: 2.8 2.7 2.8 2.7 2.8 2.9 2 .7 2.7 2.9 2.8 2.8 2.8 2.8 2.7 2.7 2.6 2.7 2.8 2.7 2.6 2.7 2.7 2 .6 2.7 2.7 2.7 2.7 2.6 2.7 2.6 Stk 02 t 0-25 12.91 12.93 12.93 12.93 12.93 12.92 12.94 12.94 12.92 12.91 12.91 12.91 12.94 12.94 12.95 12.95 12.95 12.93 12.9 4 12.96 12.94 12.95 12.97 12.96 12.95 12.95 12.96 12.97 12.96 12.97
02/11/2013 11,4 7 

### NOx Mass 1b/hr 0-100 7.44 6.50 7.44 6.50 7.4.3 7.45 6.49 6.48 7 . 44 7.44 7.44 7.44 7.42 6.46 6.46 6.45 6.45 7.40 6.45 6 .44 6.45 6.43 6.42 6.44 6 . 45 6.44 6.45 6.43 6.44 6.44 

### StkFlow kscfh 0-300000

21186 21210 21236 21213 21223 21245 21198 21175 21201 21186 21186 21186 21209 21101 21124 21093 21092 21118 21084 21092 21074 21038 21047 21092 21092 21079 21134 21086 21097 21106 Stk 

### co ppm 0-1000

2.8 3.1 3.2 3.' 3.1 3.1 3.0 3.1 2.8 2.8 2.8 2.8 2 . 9 3.2 3 .2 3.2 3.2 2.7 2.9 3.1 3.1 3 .0 3.3 3.3 3.0 2.9 3.0 3.0 3 . 2 3.2 CO Mass 

### 1b/hr 0-100 4.65 4.64 4 . 65 5.57 4.65 4.66 4.63 4.63 4.65 4.65 4.65 4.65 4.64 4.61 4.61 4.61 4.61 3.70 4.61 4.60 4.61 4.59 5.50 4.60 4.61 4.60 4.61 4.59 4.60 4.60 NOx Rate 

### Ib/mmBtu 0-1 0.008 0 . 007 0.008 0.007 0.008 0.008 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0 . 007 0.007 0.007 0.007 0.008 0.007 0.007 0.007 0 .007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 

### Stk NOXc ppm 0-300 2.07 2.00 2.07 2.00 2.07 2.14 2.00 2.00 2 .1 4 2.07 2.07 2.07 2.08 2.00 2.00 1. 93 2.00 2.07 2.00 1. 93 2.00 2.00 1. 93 2.01 2.00 2.00 2 .0 1 1. 93 2.01 1. 93 Stk CDc Gas hscfh ppm hscfh 0-1000 0-10000 2.07 8856.0 2.29 8844.0 2 .37 885 4 .8 2.52 2.29 2.29 2.22 2.30 2.07 2.07 2.07 2.07 2.15 2.37 2.37 2.37 2.37 2 . 00 2.15 2.30 2.30 2.23 2.46 2.45 2.23 2.15 2.23 2.23 2.38 2.38 8845.2 8849.4 8869.8 8827.8 8818.2 8851.2 8856.0 8856.0 8856.0 8832 . 6 8787.6 8785.8 8773.2 8772.6 8805.6 8780.4 8761.8 8776.2 8750.4 8731.8 8761.8 8772.6 8767.2 8779.2 8748.0 8763.6 8756.4 NH3Inj 

### 1b/hr 0-1000 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 .0 110 . 0 110.0 110.0 110.0 110 .0 110.0 110.0 110.0 MW Lo 0-1 107 . 1 10 7.1 106 .**~** 106.1 106. : 106.1 106. : 106 .. 107 106. : 106. : 1 0 6 .: 106 .**~** 106.1 1 06. : 105 .. 105. : 106 .. IDS. : 106 .. 106.1 IDS. : 105. : 105.: 106. : 106. 1 106. : 105 .**~** 106 . : 105 . : Pag(

### Group#-Chann e l # Long De scrip
. Short Descri p . Units Ran g e 02/11/2013 10:36 02/11/2013 10:37 02/11/2013 10,38 02/11/2013 10:39 02/11/2013 10:40 02/11/2013 10:41 02/11/2013 10:42 02/11/2013 10:43 02/11/2013 10:44 02/11/2013 10:45 02/11/2013 10:46 02/11/2013 10:47 02/11/2013 10:48 02/11/2013 10:49 02/11/2013 10:50 02/11/20 1 3 10:51 02/11/2013 10:52 02/11/2013 10,53 02/11/2013 10:54 02/11/2013 10 :5 5 02/11/2013 10:56 02/11/2013 10:57 02/11/2013 10:58 02/11/2013 10:59 02/11/2013 11:00 02/11/2013 11:01 02/11/2013 11 :0 2 02/11/2013 11:03 02/11/2013 11:04 02/11/2013 11:05 02/11/2013 11:06 02/11/2013 11:07 02/11/2013 11:08 02/11/2013 11:09 02/11/2013 11:10 02/11/2013 11:11 02/11/2013 11 :1 2 02/11/2013 11:13 02/11/2013 11:14 02/11/2013 11:15 

### Date/Time Printed: G34-C4 G34-Cll G34 -C20 G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4 >St k 02 4>NOx Mass 4>StkFlow

2.7 2.7 2.7 2.7 2.7 2.7 2.8 2.7 2.8 2.7 2.8 2.7 2.7 2.7 2.7 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.9 2.8 2.8 2.8 2.8 2.8 2.8 2.7 2.8 2.9 2.7 2.7 Stk 02 

# • 0-25 12.95 12.95 12.95 12.94 12.94 12.94 12.93 12.93 12.91 12.92 12.92 12.93 12.93 12.94 12.93 12.92 12.91 12.90 12.91 12.90 12.90 12.90 12.90 12.88 12.89 12.89 12.88 12.89 12.87 12.87 12.88 12.88 12.88 12.89 12 . 89 12.90 12.91 12.90 12.91 12.92 02/11/2013 lL 47 NOx Mass 

### lb/hr 0-100 6.47 6.46 6.45 6.47 6.46 6.47 7.40 6.47 7.42 6.48 7.42 6.47 6.49 6.47 6.48 7.42 7.45 7.46 7.-45 7.45 7 . 47 7.46 7.47 7.47 7.46 7.45 7.46 7.46 7.48 7.48 7.47 7 . 48 7.48 7 . 47 7.47 6 . 52 7.43 7 . 46 6. SO 6.48 StkFlow kscfh 0-300000

21148 21121 21101 21126 21119 21130 21128 21120 21134 21116 21143 21107 21181 21145 21155 21172 2 1217 21217 21217 21201 21235 21221 21237 21192 21186 21170 21164 21182 21196 21195 21192 21234 21232 21233 21219 21179 21170 21209 21156 21125 G34-C3 G34-C13 G34-C10 G34-C6 G34 -C 7 G34-C8 G34-C18 G34-C 4 >St k CO 4 >C O Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH3 Inj 4>MW Lo

Stk co 

### ppm 0-1000

3.0 3.0 3.1 3.0 3.0 2.9 3.0 2.9 2.7 2.7 2.9 2.8 3 . 0 2.9 3.1 2.9 2.6 2.' 2 . 5 2.5 2.' 2.5 2.2 2.1 2.0 1.9 2.0 2.0 2.0 2.0 1.9 1.8 1.8 1.8 1.7 2.0 2.0 2.0 2.0 2.' CO Mass 

### lb/hr 0-100 4.62 4 .61 4.61 4.62 4.62 4.62 4.63 4.62 3.71 3.70 4 .63 4.62 4.64 4.62 4 .63 4.64 3.73 3.73 3.73 3.73 3.73 3.73 3.73 2.80 2.80 2.79 2.80 2.80 2.81 2.80 2.80 2.81 2.81 2.80 2.80 2 . 79 2.79 2.80 2.79 3.70 

### NOx Rate 

### Ib/mmBtu 0-1 0.007 0.007 0.007 0.007 0.007 0.007 0.008 0.007 0.008 0.007 0.008 0. 0 07 0.007 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0 . 008 0.008 0.008 0.008 0.008 0.008 0.008 0.007 0.008 0.008 0.007 0.007 stk NOXc 

### ppm 0-300 2.00 2.00 2.00 2.00 2.00 2.00 2.07 2.00 2.07 2.00 2.07 2.00 2.00 2.00 2.00 2.07 2.07 2.07 2.07 2.07 2.07 2.07 2.07 2.06 2.06 2.06 2.06 2.06 2.13 2.06 2.06 2.06 2.06 2.06 2.06 1. 99 2.07 2.14 1. 99 2.00 Stk COc Gas hscfh ppm hscfh 0-1000 0-10000 2.23 8796.0 2.23 8784.6 2.30 8776.2 2.22 8797.8 2.22 8794.8 2.15 8799.6 2.22 8809.8 2.15 8806.2 1.99 8834.4 2.00 8815.8 2.14 8827.2 2.07 8800.8 2.22 8832 . 0 2.15 8805.6 2.29 2.14 1. 92 1. 77 1. 85 1. 84 1. 77 1. 84 1. 62 1. 54 1. 47 1.40 1.47 1.47 1.47 1.47 1.40 1. 32 1. 32 1. 33 1.25 1.48 1.48 1.48 1.48 1. 7 7 88 2 1.2 8839.2 8869. 2 8880.0 8869.2 8873. 4 8887.8 8881.8 8888.4 8892.0 8878.2 8871.6 8880.0 8876.4 8904 . 6 8904.0 8892.0 8909.4 8908.8 8898.0 8892.0 8864. 4 8849.4 8877.0 8843.4 8819.4 NlBlnj 

### lb/hr 0-1000 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 

### 4>Summary

- l-Min RATA

- Continued MW Lo 0

- 1 106 .**~** 106. : 106 .: 106. : 106. : 106. : 105.: 107 . t 105 .. 106. : 105. : 106. : 105.1 106 .. 107. t 106. : 107. t 106 .**~** 106. : 106.**~** 108. t 107 .: 107. : 106. : 106 .. 106. ! 108. ( 107. : 107. : 107. : 107. ( 106 . . 1 07. : 106 .. 107.: 105. : 106 . . 107 106 106.1 

### Pag(

### Group#-Channel# G34-C2 G34-C4 G34-C11 G34 -C20 G34 -C3 G34-C13 G34-C10 G34-C6 G34 -C7 G34 -C8 G34-C1S G34-C 

### Long Descrip. 4 >Stk NO x 4>Stk 02 4>NOx Mass 4>StkFlow 4 >Stk CO 4>CO Mass 4 >NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4 >NH3 Inj 4>MW 

### La 

### S hort Descrip . Stk NOx Stk 02 NOx Mass StkFlo
..... Stk CO CO Mass NOx Rate Stk NOXc Stk COc Gas hscfh NH3Inj MW 

### Lo 

### Units ppm 

# • lb/hr kscfh 

### ppm lb/hr 

### Ib/mmBtu ppm ppm hscfh 

### lb/hr 

### Range 0

- 150 0-25 0-100 0-300000 0-1000 0-100 0-1 0-300 0-1000 0-10000 0-1000 0

- 1 02/11/2013 11:16 

### '.7 12.93 6.48 21141 '.7 3.70 0.007 2.00 2.00 8815.2 110.0 106. : 02/11/2013 11:17 '.7 12.92 6.49 21139 

### '.6 3.71 0.007 2.00 1. 92 8825.4 110.0 106 .: 02/11/2013 11:18 2.7 12.93 6.48 21143 

### '.6 3.70 0.007 2.00 1. 92 8S15.S 110 . 0 106. ! 02/11/2013 11:19 2.8 12.91 7.43 21173 '.4 3.72 0.008 2.07 1. 77 8850.6 110.0 106.! 

### P er i od Average ' . 7 12.92 6.94 21158 '.7 4.07 0.007 2.03 1. 99 8830.4 110 .0 106.4 

### Period Max Value 2.9 12.97 7.48 21245 3.4 5.57 0.008 2.14 2.52 8909.4 110.0 108. 

### Period Min Value '.6 12.87 6.42 21038 1.7 2.79 0.007 1. 93 1.25 8731.8 110.0 105. 

### Period Totals 

# = 2.0330E+2 9.5629E+2 5.1382E+2 1.5657E+6 1.9910E+2 3.0115E+2 5.S400E-l 1.5035E+2 1. 4729E+2 6.5344E+5 8.1400E+3 7.8748E+ 

### Period 

### % Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

Date/Time Printed: 02/11/2013 11,4 7 4>Summ ary - l- M in RATA

- Continued 

### pag(

# Data Summary Report Company: CPV Sentinel, LLC 62575 Powerline Road Desert Hot Springs, CA 92240 

### Source : Turbine 4 Data Group : 

# 5Q.J\ 

# \\oM- \ \**~o'7t** 

# 1..\ 

# lOW\f 

# y, W'lLt 

# TRACE**~~ ~**  

# 1.- Environmental Systems, Inc . Report Name: 

### start of Report : 4>1-Min Cales 4>Summary

- I-Min RATA 02/11/2013 11,40 End of Re port , 02/11/2013 12,54 

### Validation : All Available Data Group#-Channel# Long Descrip. Short Descrip. 

### units Range 02/11/2013 11:40 02/11/2013 11:41 02/11/2013 11:42 02/11/2013 11:43 02/11/2013 11:44 02/11/2013 11:45 02/11/2013 11:46 02/11/2013 11:47 02/11/2013 11:48 02/11/2013 11:49 02/11/2013 11:50 02/11/2013 11:51 02/11/ 2 013 11:52 02/11/2013 11:53 02/11/2013 11:54 02/11/2013 11:55 02/11/2013 11:56 02/11/2013 11:5 7 02/ 1 1/2013 11:58 02/11/2013 11:59 02/11/2013 12:00 02/11/2013 12:01 02/11/2013 12:02 02/11/20 13 12:03 02/11/2013 12:04 02/11/2013 12:05 02/11/2013 12:06 02/11/2013 12:07 02/11/2013 12:08 02/11/2013 12:09 

### Date/Time Printed: G34-C4 

### G34-Cl1 G34-C2 

### 4>Stk NOx



### Stk NOx ppm 0-150 4>Stk 02 4>NOx Mass

2.6 3.6 2.8 2.7 2.' 

### 2.3 2.6 2.8 

### 3.4 3.1 2.8 

### 2.8 2.6 2.7 2.8 2.8 2.8 

### 2.8 2.8 

### 3.2 3.2 2.7 2.4 2.7 2.7 2.7 2 . 8 2.7 2.7 2.7 Stk 02 t 0-25 12 .90 12.90 12.95 12.93 12.93 12.92 12.90 12.91 12.91 12.94 12.93 12.91 12.92 12.90 12.89 12.90 12.90 12.89 12.89 12.90 12.92 12.91 12.93 12.91 12 .91 12.92 12.90 12.90 12.92 12.92


### 02/11/2013 13,18 

### NOx Mass 

### 1b/hr 0-100 6.51 9.28 7.38 6.48 6.48 5.56 6.52 7.43 8.36 7.40 7.41 7.43 6.49 6.52 7.46 7.44 7.45 7.45 7.46 8.36 8.34 6.49 6.48 6.51 6.51 6.50 7.46 6.51 6.49 6.49 GJ4-C20 4>StkFlow



### StkFlow

kscfh 0-300000

21156 21119 21119 21134 21150 21151 21189 21169 21163 21160 21145 21148 21163 21202 21182 21169 21185 21164 21182 21136 21140 21134 21154 21190 21193 21175 21207 21168 21163 21163 G34

- C3 

### 4>Stk CO

Stk CO 

### ppm 0-1000



### 3.0 2.4 

### 0.3 0.3 0.5 1.7 

### 3.2 3.7 3 . 3 0.5 

### 0.4 0.4 0.9 2.6 

### 3.2 3.3 

### 3.2 3.5 3.4 3.5 0.5 

### 0.4 0.7 1.2 1.7 2.2 

### 2.1 2.2 

### 2.3 2.5 G34-C13 G34-CIO G34-C6 

### 4>CO Mass 4>NOx Rate 4>Stk NOXc



### CO Mass 1b/hr 0-100 4.65 3.71 0.00 0.00 0.93 2.78 4.66 5.57 4.64 0.93 0.93 0.93 0.93 3.73 4.66 4.65 4.66 5.59 5.59 5.57 0.93 0.93 0.93 1.86 2.79 3.71 2.80 3.72 3.71 3.71 

### NOx Rate 

### Ib/mmBtu 0-1 0.007 0.010 0.008 0.007 0.007 0.006 0.007 0.008 0.009 0.008 0.008 0.008 0.007 0.007 0.008 0 . 008 0.008 0.008 0.008 0.009 0.009 0.007 0.007 0.007 0.007 0.007 0.008 0.007 0.007 0.007 

### Stk NOXc ppm 0-300 1.92 2.66 2.08 2.00 1.78 1.70 1.92 2.07 2.51 2.30 2.07 2.07 1. 92 1. 99 2.06 2.07 2.07 2.06 2.06 2.36 2.37 1. 99 1. 78 1.99 1. 99 2.00 2.07 1. 99 2.00 2.00 G34-C7 G34 -CB 4>Stk CDc 4>Gas Flow



### Stk CDc Gas hscfh ppm hscfh 0

- 1000 0- 10000 2 . 21 1. 77 0.22 0.22 0.37 1. 26 2.36 2.73 2.44 0.37 0.30 0.30 0.67 1. 92 2.36 2.43 2.36 2.58 2.50 2.58 0.37 0.30 0.52 0.89 1.26 1.63 1. 55 1. 62 1. 70 l. 85 8854.8 8839.2 8784. 

## a 8812.2 8818.8 8830.2 8868.6 8848.8 8846 . 4 8812.2 8817.0 8840.4 8835.6 8874.0 8876.4 8860.2 8866.8 8869.2 8876.4 8846.4 8826.0 8834.4 8820.6 8857.8 8859.0 8840.4 8875.8 8859.6 8835.6 8835.6 G34-CIB 4>NlB Inj 

### NH3Inj



### 1b/hr 0- 1000 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110. 

## a 110.0 110.0 110.0 110.0 110 .0 110.0 110 .0 110.0 110.0 110.0 110.0 110.0 110.0 110 .0 110.0 110.0 11 0.0 110.0 110.0 110.0 G34-C 4>MW Lo

MW Lo



### 0-1 106. ! 106 .. 106.1 107.1 105. ! 105. : 106. : 106 .. 106.1 106. ! 106.1 106 .. 105. : 106. ! 107.: 106.1 106. : 106.! 107.: 106.1 106. : 106.: 105 .. 105 .. 106. ! 106. : 106. : 106. : 106.: 106.: pagt

### Group#-Channel# Long De s crip. S hort Descrip . Units Range 02/11/2013 12:10 02/11/2013 12:11 02/11/2013 12:12 02/11/2013 12:13 02/11/2013 12:14 02/11/2013 12:15 02/11/2013 12:16 02/11/2013 12:17 02/11/2013 12:18 02/11/2013 12:19 02/11/2013 12:20 02/11/2013 12:21 02/11/2013 12:22 02/11/2013 12:23 02/11/2013 12:24 02/11/2013 12:25 02/11/2013 12:26 02/11/2013 12:27 02/11/2013 12:28 02/11/2013 12:29 02/11/2013 12:30 02/11/2013 12:31 02/11/ 2 013 12:32 02i11/2013 12:33 02/11/2013 12:34 02/11/2013 12:35 02/11/2013 12:36 02/11/2013 12:37 02/11/2013 12:38 02/11/2013 12:39 02/11/2013 12:40 02/11/2013 12:41 02/11/2013 12:42 02/11/2013 12:43 02/11/2013 12:44 02/11/2013 12:45 02/11/2013 12:46 02/11/2013 12:47 02/11/2013 12:48 02/11/2013 12:49 

### Date/Time Printed: G34-C4 G34-C11 G34 -C20 G34-C2 4>Stk NOx

Stk NOx 4>Stk 02 4>NOx Mass 4>StkFlow 

### ppm 0-150 2.7 2.6 2.8 2.7 2.6 2.6 2.6 2.6 2.7 2.8 2.8 2.8 2.8 2.8 2.8 2.7 2.7 2.7 2.7 2.6 2.7 2.6 2.7 2.7 2.7 2.6 2.7 2.7 2.6 2.7 2.6 2.6 2.6 2.7 2.6 2.6 2.7 2.7 2.7 2.7 Stk 02 

# • 0-25 12.93 12.92 12.91 12.91 12.92 12.92 12.91 12.90 12.89 12.89 12.88 12.87 12.88 12.89 12.88 12.88 12.89 12.90 12 . 91 12.90 12.89 12.91 12.90 12.90 12.90 12.91 12.89 12.89 12.89 12.88 12 . 88 12.87 12.88 12.88 12.87 12.88 12.88 12.88 12.87 12 . 88 02/11/2013 13,18 NOx Mass 

### lb/hr 0-100 6.48 0.00 M 7.42 6.49 6.48 6.48 6.50 6.49 6.51 7.45 7 . 46 7.46 7.46 7.45 7.44 6.52 6.51 0 . 00 M 6 . 51 6.52 6.52 6.50 6.51 6.51 6.51 6.50 6.5 1 6.52 6.52 6 . 52 6 . 52 6.52 6.51 6.52 6.53 6.52 6.53 6.52 6.53 6.52 StkFlow ksefh 0-300000

21140 21079 21121 21121 21100 21113 21144 21112 21131 21157 21159 21153 21165 21170 21119 21157 21144 21191 2 1200 21192 21169 21147 2 1168 21168 21146 21143 21144 21164 21172 21152 21157 21129 21117 21147 21136 21134 21159 21152 21159 21151 G34-C3 G34-C13 G34-C10 G34-C6 G34-C7 G34 -C8 G34

- C18 G34-C 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXe 4>Stk COe 4>Gas Flow 4>NH3 Inj 4>MW Lo

Stk 

### co ppm 0-1000

2.3 2.3 2.1 1.7 1.6 1.5 1.6 1.8 2.0 1.9 2.0 1.8 1.7 1.7 1.8 2.2 2. 5 2.7 2.8 3.0 3.0 3.3 3.1 2.9 3.2 3.3 3.2 2.9 2.8 2.7 2.7 2.9 3.2 3.2 3.2 3.2 3.1 3.0 2.9 3.0 CO Mass 

### lb/hr 0-100 3.70 0.00 M 2.78 2.78 2.78 1. 8S 2.78 2.78 2.79 2.79 2.80 2.80 2.80 2.79 2.79 3.73 3.72 0.00 M 4.65 4.66 4.66 4.64 4.65 4.65 4.65 4.64 4.65 4.66 4.66 3.73 3.73 4.66 4.65 4.66 4.66 4.66 4.66 4.66 4.67 4.66 NOx Rate Ib/mmBtu 0-1 0.007 0.007 0.008 0.007 0.007 0.007 0.007 0.007 0.007 0 .00 8 0.008 0.008 0.008 0.008 0.008 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 Stk NOXe ppm 0-300 2.00 1. 92 2.07 1. 99 1. 92 1. 92 1. 92 1. 92 1. 99 2.06 2.06 2.06 2.06 2.06 2.06 l. 99 1.99 1. 99 1. 99 1. 92 l. 99 1. 92 1. 99 1. 99 1. 99 1. 92 1. 99 1. 99 1. 92 1. 99 1. 91 1. 91 1. 91 1. 99 1. 91 1. 91 1. 99 1. 99 1. 98 1. 99 Stk Cae Gas hsefh hscfh 0-10000 

### ppm 0-1000

1. 70 1. 70 1. 55 1. 26 1.18 1.11 1.18 1. 33 1. 47 1.40 1. 47 1.32 1.25 1.25 1. 32 1. 62 1. 84 1. 99 2.07 2.21 2.21 2.44 2.29 2.14 2.36 2.44 2.36 2.14 2.06 1. 99 1. 99 2.13 2.35 2.35 2.35 2.35 2.28 2.21 2.13 2.21 8814.6 8800 . 2 8829.0 8829.0 8809.2 8814.6 8838.G 8836.2 8855.4 8866.2 8878.2 8886.G 8880.6 8871.6 8861.4 8877.0 8860.8 8869.2 8862.0 8869.8 8871.0 8839.8 8859.6 8859.6 8850.6 8838.0 8860 .8 8869.2 8872.2 8875.2 8877.0 8876 . 4 8860.2 8872.8 8879.4 8867.4 8878.2 8875.2 8889.0 8874.6 NH3Inj 

### lb/hr 0-1000 110 . 0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 . 0 110.0 110.0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 4>Summary

- I

- Min RAT A

- Continued MW La 0-1 105 .. IDS.! 106.! 106. : 106.! 106. : 106. : 106. : 107.: 106 .. 107.1 107.1 107. 107 1 06 .. 106. : 106. ! 107 .. 107. ( 107. ! 107 .. lOG .: 106.l 106.! 106. l 106.: 106 .. 107.: 106 . : 106.: 107. : 107. : 106. ! 107.1 106. : 106. ! 106 .. 107. : 107. ! 106 .. Pagt

### Group#-Channel# G34-C2 G34-C4 G34-Cll G34-C20 G34-C3 

### GJ4-C13 

### G34 -CI O G34 -C 6 G34-C7 G34-C8 G34 -C18 

### G34-C 

### Long Descr i p . 4>Stk NOx 4>Stk 02 

### 4 :> NOx Mass 4>StkFlow 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 

### 4>Stk CDc 4>Gas Flow 4>NH3 Inj 

### 4>MW La 

### S hort Descr i p. Stk N Ox Stk 02 NOx Mass 

### StkFlow Stk CO 

### CO Mass N Ox Rate Stk NOXc Stk CDc Gas 

### hscfh NH3Inj MW Lo 

### unit s ppm % 1b/hr 

### kscfh ppm 1b/hr 

### Ib/mmBtu ppm ppm hscfh 1b/hr 

### Range 0-150 0-25 0-100 0-300000 0-1000 0-100 0-1 0-300 0-1000 0-10000 0-1000 0-1 02/11/2013 12:50 2.7 12.88 6.53 21161 2.9 4.66 0.007 1. 99 2.13 8878.8 110.0 106 .. 02/11/2013 12:51 2.7 12.87 6.51 21093 2.8 4.65 0.007 1. 98 2.06 8861.4 110.0 107. c 02/11/2013 12:52 2.7 12.88 6.52 21134 2.8 4.66 0.007 1. 99 2.06 8867.4 110 . 0 107 .. 02/11/2013 12:53 2.7 12.87 6.53 21133 2.8 4 .66 0.007 1. 98 2.06 8878.2 110.0 107. : 02/11/2013 12;54 2.7 12.87 6.52 21113 2.8 4.66 0.007 1. 98 2.06 BB69.8 110.0 106. : 

### Period Average 2.7 12.90 6.66 21152 2.3 3.47 0.007 2.01 1.72 8853.B 110.0 106.6 

### P e riod Max Value 3.6 12.95 9.28 21207 3.7 5.59 0.010 2.66 2.73 8889.0 110 . 0 107. 

### Period Min Value 2.3 12.87 0.00 21079 0.3 0.00 0.006 1. 70 0.22 8784.0 110.0 105. 

### Period Totals = 2.0450E+2 9.6744E+2 4.9923E+2 1.5863E+6 1.7500E+2 2.6052E+2 5.5100E-l 1.5084E+2 1.2901E+2 6.6403E+5 8.2500E+3 7.9957E+ 

### Period 

### % Reco ve ry 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 1 00.0 100.0 100.0 100.



### Date/Time Printed: 02/11/2013 13,18**4~Summary** 

### - I-Min RATA

- Continued**Pag~**

## Appendix 

## B.1.3 Sentinel Unit 4 PM Testing

R041 0688 

## 8-5

# Data Summary Report Company: CPV Sentinel, LLC 62575 Powerline Road

# ~ 1\o1J.. \ 

# L{ Desert Hot Springs , CA 92240 

# fM Source: Turbine 4 Data Group: 4>!-Min Cales Report Name: 

### Start of Report : 4>Summary

- I-Min RATA 02/11/2013 08,41 G34-C4 

# 100'\
End of Report , 02/11/2013 12,55 G34 -el l G34 -C 13 

# TRACE Ellv irnnm e ntal Systems, Illc
.

validation : 

### All Available Data G34 -CIO G34-C6 G34-C7 G34 -CB 

### Group#-Channel# Long Descrip. 

### Short Descrip. Units G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass G34-C20 4>StkF!ow



### StkFlow

kscfh 0 -3 00000 G34-C3 4>Stk CO



### Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk CDc 4>Gas Flo w 

### Stk CDc Gas hscfh G34 -CIB 4>NH3 Inj NH 3Inj



### Ib/hr 0-200 G34-C 

### 4>MW Lo

MW La 

### Range 02/11/2013 08:41 02/1 1 /2013 08:42 02/11/ 20 13 08: 4 3 02/11/2013 08:44 02/11/2013 08:45 02/11/2013 08:46 02/11/2013 08:47 02/1 1 /2013 08:48 02/11/2013 08:49 02/11/201 3 08:50 02/11/ 2013 08:51 02/11/2013 08:52 02/11/2013 08:53 02/11/2013 08:54 02/11/2013 08:55 0 2/11/2013 08:56 02/11/20 13 08:57 02/11/2013 08:58 02/11/2013 08:59 02/11/2013 09:00 02/11/2013 09:01 02/11/2013 09:02 02/1 1 /2013 09:03 02/11/2 0 13 09:04 02/11/2013 09:05 02/11/2013 09:06 02/11/2013 09:07 02/11/2013 09:08 02/11/2013 09:09 02/1 1/ 2013 09:10 

### Date/Time Printed: 3.0 2.9 3.0 3.1 3.1 2.9 3.0 2.9 3.1 3.0 

### 3.6 3.0 2.7 2.9 

### 2.9 2.9 

### 2.9 3.0 2.9 

### 3.0 3.0 2.9 

### 2.9 3.0 

### 3.0 2.9 3.0 3.0 2.9 2.9 Stk 02 % 0-25 12.88 12.88 12. 88 12.88 12.88 12.87 12.8 7 12.87 12.87 12.87 12.89 12.89 12.89 12.88 12.91 12.91 12.91 12.89 12.90 12.90 12 .89 12.90 12.91 12 .89 12.88 12.88 12.88 12 .88 1 2.88 12.88 

### 02/11/2013 16,39 NOx Mass 

### 1b/hr 0-100 7.52 7.51 7.51 7.52 7.51 7.51 7.52 7.51 7.52 7.51 9 . 36 7. 4 8 6.55 7.48 7.45 7.43 7.44 7.46 7.46 7.45 7.47 7.44 7.43 7.45 7.47 7.45 7.46 7.45 7.46 7.47 21324 21300 21301 21332 21302 21294 21307 21284 21297 21274 21276 21259 21267 21220 21225 21163 2 11 93 21186 21231 21197 21212 21172 21150 21164 21185 21145 21172 2 11 29 21159 21191 

### ppm 0-1000

1.8 2.0 2.1 2.1 1.9 

### 2.1 2.' 2.7 

### 2.6 2.5 1.6 

### 0.3 0.6 1.3 1.8 1.7 1.7 1.5 1.7 1.6 1.8 1.7 2.0 2.1 2.2 2.2 

### 2.3 2.2 

### 2 .3 2.3 CO Mass 

### Ib/hr 0-100 2.82 2.82 2.82 2.82 2.82 2.82 3.76 3.76 3.76 3.75 2.81 0 .0 0 0.94 1. 87 2.79 2.79 2.79 1. 86 2.80 2.79 2.80 2.79 2.78 2.79 3.73 3.73 3.73 3.72 3.73 3.73 NOx Rate 

### Ib/mmBtu 0-1 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.010 0.008 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 Stk NOXc 

### ppm 0-300 2.21 2.13 2 .21 2.28 2.28 2.13 2.20 2.13 2.28 2.20 2 .65 2.21 1. 99 2.13 2.14 2.14 2.14 2.21 2.1 4 2.21 2.21 2.14 2.14 2.21 2.21 2.13 2.21 2.21 2.13 2.13 

### ppm hscfh 0-1000 0-10000

1. 32 1.47 1. 54 1. 54 1.40 1. 54 1. 76 1. 98 1. 91 1. 84 1.18 0.22 0.44 0.96 1. 33 1.26 1.26 1.10 1. 25 1.18 1.33 1.25 1.48 1. 55 1. 62 1. 62 1. 69 1. 62 1. 69 1. 69 8947.2 8937.0 8937.6 8950.8 8938.2 8 946.0 8951.4 8941. 8 89 4 7.2 8937.6 8916.0 8908.8 8912.4 8903.4 8872.2 8846.4 8859.0 8878.2 8886.0 8871.6 8889.0 886 1 .4 8841.0 8869.2 8889.0 8872.2 8883.6 8865.6 8878.2 8891.4 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 .0 11 0.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 0-1 107. ; 109.: 107. ; 107. ; 107. 108.! 107. : 107. : 107. : 108. « 107. c 107 .. 1 0 7. 107 . . 106. 106. ! 107. « 107 .. 107. : 106 . . 107.: 107. : 107. : 107. c 107.! 108. « 106. 106. : 107. : 107. ! 

### Pag E

### Group#-Channel# Long Descrip
. Short Descrip
. Units 

### Range 02/1 1 /2013 09:11 02/11/2013 09:12 02/11/2013 09:13 02/11/2013 09:14 02/11/2013 09:15 02/11/2013 09:16 02/11/2013 09:17 02/ 1 1/ 20 13 09:18 02/11/2013 09:19 02/11/2013 09:20 02/11/2013 09:21 02/11/2013 09:22 02/11/2013 09:23 02/11/2013 09:24 02/11/ 2 013 09:25 02/11/2013 09:26 02/11/20 1 3 09:27 02/11/2013 09:28 02/11/2013 09:29 02/11/2013 09:30 02/11/2013 09:31 02/11/2013 09:32 02/11/2013 09:33 02/ 1 1/2013 09:34 02/11/2013 09:35 02/11/2013 09:36 02/11/2013 09:37 02/11/2013 09:38 02/11/2013 09:39 02/11/ 2 013 09:40 02 /1 1 /2 013 09:41 02/11/2013 09:42 02/11/2013 09:43 02/11/2013 09:44 02/11/2013 09:45 02/11/ 2 013 09:46 02/11/ 2 013 09:47 02/11/ 2 013 09:48 02/11/2013 09:49 02/11/2013 09:50 

### Date/Time Printed: G34

- C4 G34 -C11 G34-C20 G34-C2 4>Stk NOx

Stk NOx ppm 0

- 150 4>Stk 02 4>NOx Mass 4>StkFlow

3.0 2.8 2.9 2.9 2.8 2.9 2.9 2.8 2.9 2.9 2.9 2 . 9 2.9 2.9 3.0 2.8 3.0 2.9 2.8 2.9 3.0 2.9 3.0 2.9 2.8 2.8 2.9 2.9 3.0 2.8 2.9 3.0 3.0 2.8 2.9 2.9 2.9 3.0 2.9 2.9 Stk 02 % 0-25 1 2.8 7 12 . 91 12.92 12.92 12.93 12.90 12.B9 12 . 91 12.90 12.91 12.90 12.92 12.91 12.91 12 . 8 8 12 .9 0 12 . 89 12 . 89 12.91 12.9 1 12.91 12.91 12. 90 1 2 .90 12 . 91 12.90 12.89 12.91 12 . 89 12 . 91 12 .9 0 12 .9 0 12.91 12.91 12.91 12.92 12 . 92 12 .9 3 1 2. 92 12.94 02/11/2013 16,39 NOx Mass 

### lb/hr 0-100 7.48 7.42 7.40 7.43 7.40 7.45 7.43 7.41 7.42 7.42 7.42 7.39 7.40 7.40 7.42 7.40 7.42 7.42 7.40 7.40 7.41 7.42 7.44 7.43 7.40 7.42 7.42 7.41 7.43 7.40 7.41 7.40 7.39 7.39 7.39 7.38 7.39 7.39 7.40 7.38 StkFlow kscfh 0-300000

2 1190 21121 21113 21185 21115 21181 21119 21105 2 1118 21127 21099 21073 21081 21071 2 1061 2 1058 21091 21078 21081 21075 21103 21128 21149 21142 21084 21112 21090 21111 21120 21074 2 1070 21050 21045 21054 21038 21053 21063 21091 2 109 6 21096 G34-C3 G34-C13 G34-C10 G34-C6 G34 -C7 G34-C8 G34-C18 G34-C 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH3 Inj 4>MW La

Stk CO ppm 0

- 1000

2.3 2.7 3.1 2.9 3.3 3.3 2 .• 3.0 2.9 3.0 2 .• 2.9 2.9 2 .• 2.6 2 .• 2.7 2.5 2 .• 3.0 2.9 2.6 2.7 2.7 2.9 3.1 3.0 2.7 2 .• 2.7 2.9 2.5 1.9 2.1 2.5 2.1 1.9 1.. 1.6 1.3 CO Mass 

### lb/hr 0-100 3.74 3.71 4.63 4.64 4.62 4.65 4.65 4.63 4.64 4.64 4.64 4.62 4.63 4.62 3 . 71 4 .63 3.71 3.71 4.63 4.63 4.63 3.71 3.72 3 . 72 4.63 4.64 4.64 3.71 4.65 3.70 4.63 3.70 2.77 2.77 3.69 2.77 2.77 2.77 2.77 1. 84 NOx Rate lb/mmBtu 0-1 0.008 0.008 0.008 

### O.OOB 0.008 0.008 0.008 0.008 0.008 0 . 008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0 . 008 0.008 0.00 8 0.008 0.008 0.008 0.008 0.008 0.008 

### O.OOB 0.008 0.008 

### O.OOB 0.008 0.008 0.008 0.008 0 . 00 8 0 . 008 Stk NOXc ppm 0-300 2.20 2.07 2.14 2.14 2.07 2.14 2.14 2.07 2.14 2.14 2.14 2.14 2.14 2.14 2.2 1 2.07 2.21 2.14 2.07 2.14 2.22 2.14 2.21 2.14 2.07 2.07 2.14 2.14 2.21 2.07 2 . 1 4 2.21 2.22 2.07 2.14 2.14 2.14 2.22 2.14 2.15 Stk COc Gas hscfh 

### ppm hscfh 0-1000 0

- 10000

1 . 69 8902.2 1.99 8829.0 2.29 8814.6 2.14 8844.6 2.44 2.43 2.06 2. 22 2.14 2.22 2.07 2.14 2.14 2 . 07 1. 91 2.0 7 1. 99 1. 84 2.07 2.22 2.14 1. 92 1. 99 1. 99 2.14 2 . 29 2.21 1. 99 2.06 1. 99 2 . 14 1. 8 4 1.40 1. 55 1. 85 1. 55 1. 40 1.33 1. 18 0 . 96 8804.4 8865.0 8850.0 8822. 4 8838.6 8831. 4 8830.8 8797.8 8812.2 8808.0 8836.8 8813.4 8838.6 8833.2 8812.2 8809.8 8821.2 8832.0 8851.8 8848.8 8813.4 8836.2 8838.0 8824.8 8850.6 8809.2 8818.8 8810.4 8797.2 8800.8 8794.2 8789.4 8793.6 8 7 94.2 8807.4 8785.2 NH3Inj 

### lb/hr 0-200 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 1 1 0.0 110.0 110.0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 1 1 0.0 110.0 110 . 0 

### 4>Summary

- I-Min RATA

- Continued MW Lo 0-1 107. : 106.**~** 106. ! 106. : 106. 106 .. 106. : 106 . 106. 106.! 106 . . 105 .. 105 . 106. ! 106 . : 106 . 106 .. 106. ! 106 .. 105. : 106. ! 107.1 106.: 106 .. 106 .. 107.1 105. ! 106 . . 106. 106.: 105 .. 106 . . lOS.! 106. : 106.! 105 .. 106.: 106.1 106. 1 106. ! 

### PagE

### Group#-Chann e l# Long Descrip
. Short Descrip
. Units Range 02/11/2013 09:51 02/11/2013 09:52 02/11/2013 09:53 02/11/2013 09:54 02/11/2013 09:55 02/11/2013 09:56 02/11/2013 09:57 02/11/2013 09:58 02/11/2013 09:59 02/11/2013 10:00 02/11/2013 10:01 02/11/2013 10:02 02/11/2013 10:03 02/11/2013 10:04 02/11/2013 10:05 02/11/2013 10:06 02/11/2013 10:07 02/11/2013 10:08 02/11/2013 10:09 02/1 1 /2013 10:10 02/11/2013 10:11 02/11/2013 10:12 02/11/2013 10:13 02/11/2013 10:14 02/11/2013 10:15 02/11/2013 10:16 02/11/2013 10:17 02/11/2013 10:18 02/11/2013 10:19 02/11/2013 10:20 02/11/2013 10:21 02/11/2013 10:22 02/11/2013 10:23 02/11/2013 10:24 02/11/2013 10:25 02/11/2013 10:26 02/11/2013 10:27 02/11/2013 10:28 02/11/2013 10:29 02/11/2013 10:30 

### Date/Time Printed: G34-C4 G34-Cll G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass

2.8 

### 3.0 2.9 

### 3.0 2.9 2.8 2.8 2.8 2.8 2.8 2.9 2.7 2.7 2.8 2.8 2.8 2.7 2.8 2.7 2.8 2.9 2.7 2.7 2.9 2.8 2.7 2.8 2.7 2.7 2.7 2.6 2.7 2.8 2.7 2.6 2.7 2.7 2.6 2.7 2.7 Stk 02 

# , 0-25 12.92 12.91 12.91 12.90 12.9 1 12.91 12.91 12.91 12.91 12.92 12.91 12.93 12.94 12.93 12.93 12.91 12.93 12.93 12.93 12.93 12.92 12.94 12.9 4 12.92 12.91 12.95 12.94 12.93 12.94 12.95 12.95 12.95 12 . 93 12.94 12.96 12.94 12.95 12.97 12.96 12.95 02/11/2013 16,39 NOx Mass 

### lb/hr 0

- 100 7.40 7.42 7.41 7.44 7.42 7.44 7.43 7.43 7.42 7.42 7.42 6.49 6.47 7.42 7.43 7.44 6.50 7.44 6.50 7.43 7.45 6.49 6.48 7.44 7.44 6.47 7.42 6.48 6.46 6.46 6.45 6.45 7.40 6.45 6.44 6.45 6.43 6.42 6.44 6.45 G34-C20 4>StkFlow

StkFlow

ksefh 0-300000

21089 21123 21113 21155 21137 21193 21170 21170 21118 21145 21131 21161 21133 21194 21223 21186 21210 21236 21213 21223 21245 21198 21175 21201 21186 21152 21209 21135 21101 21124 21093 21092 21118 21084 21092 21074 21038 21047 21092 21092 G34 -C3 4>Stk CO

Stk CO 

### ppm 0-1000

1.4 1.7 1.5 1.2 1.3 1.1 1.2 1.1 1.3 1.5 1.6 1.8 2.7 2.9 2.8 2.8 3.1 3.2 3.4 3.1 3.1 

### 3.0 3.1 2.8 2.8 2.8 2.9 2.8 3.2 3.2 3.2 3.2 2.7 2.9 3.1 3. 1 

### 3.0 3.3 3.3 3.0 G34 -C13 G34-C10 G34 -C6 4>CO Mass 4>NOx Rate 4>Stk NOXe

CO Mass lb/hr 0

- 100 1. 85 2.78 1. 85 1. 86 1. 86 1. 86 1. 86 1. 86 1. 85 1. 85 2.78 2.78 3.70 4.64 4.6 5 4.65 4.64 4.65 5.57 4.65 4.66 4.63 4.63 4.65 4.65 4.62 4.64 4.63 4.61 4.61 4.61 4.61 3.70 4.61 4.60 4.61 4.59 5.50 4.60 4.61 NOx Rate lb/mmBtu 0-1 0.008 0.008 0 . 008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.007 0.007 0.008 0.008 0.008 0.007 0.008 0.007 0.008 0.008 0.007 0.007 0.008 0.008 0.007 0.008 0.007 0.007 0.007 0.007 0.007 0.008 0 .0 07 0.007 0.007 0.007 0.007 0.007 0.007 Stk NOXe 

### ppm 0

- 300 2.07 2.22 2.14 2.21 2.14 2.07 2.07 2.07 2.07 2.07 2.14 2.00 2.00 2.07 2.07 2.07 2.00 2.07 2.00 2.07 2.14 2.00 2.00 2.14 2.07 2.00 2.08 2.00 2.00 2.00 1. 93 2.00 2.07 2.00 1. 93 2.00 2.00 1. 93 2.01 2.00 G34 -C7 G34-C8 4>Stk COe 4>Gas Flow

Stk COe Gas hsefh ppm hscfh 0-1000 0

- 10000

1. 04 1. 26 1.11 0.89 0.96 0.81 0.89 0.81 0.96 1.11 1.18 1. 33 2.00 2.15 2.07 2.07 2.29 2.37 2.52 2.29 2.29 2.22 2.30 2.07 2.07 2.08 2.15 2.07 2.37 2.37 2 . 37 2.37 2.00 2.15 2.30 2.30 2.23 2.46 2.45 2.23 8804.4 8829.6 8825.4 8854.2 8835.6 8859.0 8849.4 8849 . 4 8827.8 8827.8 8833.2 8823.6 8800.8 8837.4 8849.4 8856.0 8844.0 8854.8 8845.2 8849.4 8869.8 8827.8 8818.2 8851.2 8856.0 8797.8 8832.6 8812.8 8787.6 8785.8 8773.2 8772.6 8805.6 8780.4 8761.8 8776.2 8750.4 8731.8 8761.8 8772.6 G34 -C 18 4>NH3 Inj NH3Inj

lb/hr 0-200 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110. 

## a 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 

### 4>Summary

- I-Min RATA

- continued G34

- C 4>MW Lo

MW La

0-1 105 .. 106.1 105. : 107. : 107. t 107. t 106 . . 106. ! 106. ! 106 .. 106. 105 105. : 106. 106. 107. t 107.1 106. 106.1 106. : 106. t 106 .. 106 .. 107. : 106. : 106 106. 106 .. 106. t 106. : 105. : 105 .. 106. ' 105. : 106. : 106. ( 105. 105. : lOS. : 106. : Pagt

### Group#-Channel# Lo ng Descrip. Short Descrip. U

nits Range 02/11/2013 10:31 02/11/2013 10:32 02/11/2013 10:33 02/11/2013 10:34 02/11/2013 10:35 02/11/ 2 013 10:36 02/11/2013 10:37 02/11/2013 10:38 02/11/2013 10:39 02/11/2013 10:40 02/11/2013 10:41 02/11/2013 10:42 02/11/2013 10:43 02/11/2013 10:44 02/11/2013 10:45 02/11/2013 10:46 02/11/2013 10:47 02/11/2013 10:48 02/11/2013 10:49 02/11/2013 10:50 02/11/2013 10:51 02/11/2013 10:52 02/11/2013 10:53 02/11/2013 10:54 02/11/2013 10:55 02/11/2013 10:56 02/11/2013 10:57 02/11/2013 10:58 02/11/2013 10:59 02/11/2013 11:00 02/11/2013 11:01 02/11/2013 11: 02 02/11/2013 11:03 02/11/2013 11:04 02/11/2013 11:05 02/11/2013 11:06 02/11/2013 11:07 02/11/2013 11.08 02/11/2013 11:09 02/11/2013 11:10 

### Date/Time Printed: G34-C4 G34 -Cll G34-C20 G34-C2 

### 4>Stk NOx

Stk NOx 

### ppm 0

- 150 

### 4 >Stk 02 

### 4 >NOx Mass 4 >StkFlo w

2.7 2.7 2.6 2.7 2.6 2.7 2.7 2.7 2.7 2.7 2.7 2.8 2.7 2 .8 2.7 2.8 2.7 2.7 2.7 2.7 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.8 2.9 2.8 2.8 2.8 2.8 2.8 2.8 

### Stk 02 % 0-25 12.95 12.96 12.97 12.96 12.97 12 .9 5 12 .95 12.95 12 . 94 12.94 12 .94 12.93 12.93 12.91 12.92 12.92 12.93 12.93 12.94 12.93 12. 9 2 12 . 91 12.90 12.91 12.90 12.90 12 .9 0 12.90 12.88 12.89 12.89 12.88 12 . 89 12.87 12 .87 12 .88 12.88 12 .8 8 12.89 12.89 

### 02/11/2013 16,39 NOx Mass 

### lb/hr 0-100 6.44 6.45 6.43 6.44 6.44 6.47 6.46 6.45 6.47 6.46 6.47 7.40 6.47 7.42 6.48 7.42 6 .47 6.49 6.47 6.48 7.42 7.45 7.46 7.45 7.45 7.47 7.46 7.47 7.47 7.46 7.45 7.46 7.46 7.48 7.48 7.47 7. 48 7.48 7.47 7.47 

### StkFlow ksefh 0-300000

21079 21134 21086 21097 21106 21148 21121 21101 21126 21119 21130 21128 21120 21134 21 1 16 21143 21107 21181 21145 21155 21172 21217 21217 21217 21201 21235 21221 21237 21192 21186 21170 21164 21182 21196 21195 21192 21234 21232 21233 21219 G34-C3 G34-C13 G34

- CI0 G34-C6 G3 4 -C7 G34-C8 G34-C18 G34-C 

### 4>Stk CO 4>CO Mass 4 > NOx Rate 4>Stk NOXe 4>Stk COe 4>Gas Flow 4>NH3 Inj 4>MW La Stk CO 

### ppm 0-1000

2.9 3.0 3.0 3.2 3.2 3.0 3.0 3.1 3.0 3.0 2.9 3.0 2.9 2.7 2.7 2.9 2.8 3.0 2.9 3.1 2.9 

### 2.6 2.' 2.5 2.5 2.4 2.5 2.2 

### 2.1 2.0 1.9 

### 2.0 2.0 2.0 2.0 1.9 1.8 1.8 1.8 1.7 

### CO Mass 

### Ib/hr 0-100 4.60 4.61 4.59 4.60 4 . 60 4.62 4.61 4.61 4.62 4.62 4.62 4.63 4.62 3.71 3.70 4.63 4.62 4.64 4.62 4.63 4.64 3.73 3.73 3.73 3.73 3. 7 3 3.73 3.73 2.80 2.80 2.79 2.80 2.80 2.81 2.80 2.80 2.81 2.81 2.80 2.80 

### NOx Rate 

### Ib/mmBtu 0

- 1 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.008 0.007 0.008 0.007 0.008 0.007 0.007 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 

### O.OOB O.OOB 0.008 

### O.OOB 0.008 

### O.OOB 0 . 008 

### O.OOB O.OOB 0 . 008 0.008 

### Stk NOXe 

### ppm 0-300 2.00 2.01 1. 93 2.01 1. 93 2.00 2.00 2.00 2.00 2.00 2.00 2.07 2.00 2.07 2.00 2.07 2.00 2.00 2.00 2.00 2.07 2.07 2.07 2.07 2.07 2.07 2.07 2.07 2.06 2.06 2.06 2.06 2.06 2.13 2.06 2.06 2.06 2.0 6 2.06 2 .06 

### Stk COe Gas 

### ppm 0-1000 

### hsefh hsefh 0

- 10000 2.15 2.23 2 . 23 2 . 38 2.38 2.23 2.23 2.30 2.22 2.22 2.15 2.22 2.15 1. 99 2.00 2.14 2.07 2.22 2.15 2.29 2.14 1. 92 1. 77 1. 85 1. 84 1. 77 1. 8 4 1. 62 1. 54 1.47 1.4 0 1. 47 1.47 1.47 1.47 1.40 1. 32 1. 32 1. 33 1. 2 5 B767.2 8779.2 8748.0 8763.6 8756.4 8796.0 8784.6 8776.2 8797.8 8794.8 8799.6 8809.8 8806.2 8834.4 8815.8 8827.2 8800.8 8832.0 8805.6 8821.2 8839.2 8869.2 8880.0 8869.2 8873.4 8887.8 8881.8 8888.4 8892.0 8878.2 8B71.6 8B80.0 8876.4 8904.6 8904.0 8892.0 8909.4 890B.8 8898.0 8892.0 

### NH3Inj 

### lb/hr 0-200 110.0 110.0 1l0.0 110.0 110.0 110.0 110.0 1 1 0.0 110.0 110.0 110.0 110 .0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 .0 110.0 110.0 110.0 110.0 110.0 110.0 1l0.0 llO.O 110.0 110.0 110 0 110.0 110.0 llO.O 110.0 llO. 

## a 110.0 110 .0 110.0 

### 4>Summary

- I-Min RATA

- Continued MW La 0-1 106. c 106 . . 105 .**~** 106 . . 105 .. 106. 106. 106 106. : 106.: 106 . : 105. 107. c 105 . . 106 .. 105.: 106 .. 105. : 106 . . 107. c 106.: 107. c 106. 106. 106 . 108. ( 107 .. 107. 106 . . 106 .. 106. 108. r 107.: 107. : 107.: 107.1 106 .. 107 .. 106 .. 107.: 

### Pag{

### Group#-Channel # Long De s crip
. Short Descri p. Un i ts Range 02/11/20 13 11: 11 02/11/2013 11:12 02/11/2013 11:13 02/11/2013 11:14 02/11/2013 11:15 02/11/2013 11:16 02/11/2013 11:17 02/11/2013 11:18 02/11/2013 11:19 02/11/ 2 013 11:20 02/11/2013 11:21 02/11/2013 11:22 02/11/2013 11:23 02/11/2013 11:24 02/11/2013 11:25 02/11/2013 11:26 02/11/2013 11:27 02/11/2013 11:28 02/11/2013 11:29 02/11/2013 11:30 02/11/2013 11:31 02/11/2013 11:32 02/11/2013 11:33 02/11/2013 11:34 02/11/2013 11:35 02/11/2013 11:36 02/11/2013 11:37 02/11/2013 11:38 02/11/2013 11:39 02/11/2013 11:40 0 2 /11/ 2013 11:41 02/11/2013 11:42 02/11/2013 11:43 02/11/2013 11:44 02/11/2013 11:45 02/11/2013 11:46 02/11/2013 11:47 02/11/2013 11:48 02/11/2013 11:49 02/11/2013 11:50 

### Date/Time Printed: G34 -C4 G34-C11 G34-C2 

### 4>Stk NOx

Stk NOx 

### ppm 0-150 

### 4>Stk 02 

### 4>NOx Mass

2.7 2.8 2.' 2.7 2.7 2.7 2.7 2.7 2.8 2.6 2.7 2.7 2.7 2.7 2.8 2.7 2.7 2.7 2.8 2.8 2.8 2.7 2.8 2.' 3.8 3.0 2.8 2.7 2.7 2.6 3.6 2.8 2.7 2.4 2.3 2.6 2.8 3.4 3.1 2.8 

### Stk 02 % 0-25 12.90 12.91 12.90 12.91 12.92 12.93 12.92 12 . 93 12 . 91 12.93 12.91 12.93 12.92 12.92 12.91 12.92 12.92 12.92 12 . 92 12.90 12.90 12.90 12.90 12.90 12 . 90 12.91 12.89 12.90 12.91 12.90 12.90 12.95 12.93 12.93 12.92 12.90 12.91 12 . 91 12.94 12.93 02/11/2013 16,39 

### NOx Mass 

### Ib/hr 0-100 6.52 7.43 7.46 6.50 6.48 6.48 6.49 6.48 7.43 6.47 6.49 6.48 6.49 6.48 7.43 6.49 6.48 6.48 7.42 7.44 7.44 6.51 7.43 7.45 9.30 7.45 7.46 6.52 6.51 6.51 9.28 7.38 6.48 6.48 5.56 6.52 7.43 8.36 7.40 7.41 G34-C20 

### 4>StkFlow

StkFlow

kscfh 0-300000

21179 21170 21209 21156 21125 21141 21139 21143 21173 21121 21110 21141 21136 21122 21148 21139 21123 21132 21149 21158 21168 21161 21138 21179 21172 21212 21190 21182 21193 21156 21119 21119 21134 21150 21151 21189 21169 21163 21160 21145 G34-C3 

### 4>Stk CO

Stk CO 

### ppm 0-1000

2.0 2.0 2.0 2.0 2.' 2.7 2.6 2.6 2.4 2.6 2.6 2.6 2.7 2.' 3.0 2.8 2.8 3.0 2.8 2.6 2.6 2.7 2.6 2.6 2.6 2.5 2.6 2.5 2.8 3.0 2.4 0.3 0.3 0.5 1 7 3.2 3.7 3.3 0 . 5 0.4 G34 -C13 G34-CI0 G34-C6 

### 4>CO Mass 4>NOx Rate 4>Stk NOXc

CO Mass



### Ib/hr 0-100 2.79 2.79 2.80 2.79 3.70 3 . 70 3.71 3.70 3.72 3.70 3.71 3.70 3.71 4.63 4.64 4.63 4.63 4.63 4.64 3.72 3.72 3.72 3.72 3.72 3.72 3.72 3.73 3.72 4.65 4.65 3.71 0.00 0.00 0.93 2.78 4.66 5.57 4.64 0.93 0.93 

### NOx Rate lb/mmBtu 0-1 0.007 0.008 0.008 0.007 0.007 0.007 0.007 0.007 0.008 0.007 0.007 0.007 0 .00 7 0.007 0.008 0.007 0.007 0.007 0.008 0.008 0.008 0.007 0.008 0.008 0.010 0.008 0.008 0.007 0.007 0.007 0.010 0.008 0.007 0.007 0.006 0.007 0.008 0.009 0.008 0.008 

### Stk NOXc 

### ppm 0-300 1. 99 2.07 2 . 14 1. 99 2.00 2.00 2.00 2.00 2.07 1. 92 1. 99 2.00 2.00 2.00 2.07 2.00 2.00 2.00 2.07 2.07 2.07 1. 99 2.07 2.14 2.80 2.22 2.06 1. 99 1. 99 1. 92 2.66 2.08 2.00 1. 78 1. 70 1. 92 2.07 2.51 2.30 2.07 G34-C7 G34-C8 

### 4>Stk COc 4>Gas Flow

Stk COc Gas hscfh ppm hscfh 0-1000 0-10000

1.48 1. 48 1.48 1.48 1. 77 2.00 1. 92 1. 92 1. 77 1. 92 1. 92 1. 92 2.00 2.14 2.22 2.07 2.07 2.22 2.07 1. 92 1. 92 1. 99 1. 92 1. 92 1. 92 1. 85 1. 92 1. 84 2.07 2.21 1. 77 0.22 0.22 0.37 1. 26 2.36 2.73 2.44 0.37 0.30 8864.4 8849.4 8877.0 8843.4 8819.4 8815.2 8825.4 8815.8 8850.6 8806.8 8824.2 8815.2 8824.2 8818.2 8840.4 8825.4 8818.8 8822.4 8829.6 8855.4 8859 . 6 8856.6 8847.0 8864.4 8861.4 8866.8 8880.0 8865.6 8859.0 8854.8 8839.2 8784.0 8812.2 8818.8 8830.2 8868.6 8848.8 8846.4 8812.2 8817.0 G34-C18 4 >NH3 Inj NH3Inj



### Ib/hr 0-200 110.0 110.0 11 0.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 .0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 11 0 . 

### a 110. 

## a 110.0 110.0 110.0 110. 

## a 110.0 110.0 110.0 110.0 

### 4>Summary

- I-Min RATA

- Continued G34-C 

### 4>MW Lo

MW Lo

0- 1 105. : 106. : 107. : 106. : 106. ! 106 . . 106. : 106 . 106. 105 . . 106 . . 105. 105. 107. 106.1 106. : 105. 106 .. 105. ! 106. 106. : 106 . . 106.: 106.: 106. 107. ! 106 .. 106 .. 1 06. 106. 106 .. 106. ! 107. [ 105. 105 . : 106. 106 .. 106.1 106 106.1 

### PagE

### Group#-Channel# Long Descrip. Short Descrip. Units Range 02/11/2013 11:51 02/11/2013 11:52 02/11/2013 11:53 02/11/2013 11:54 02/11/2013 11:55 02/11/2013 11:56 02/11/2013 11:57 02/11/2013 11 :58 02/11/2013 11:59 02/11/ 2 013 12:00 02/11/2013 12;01 02/11/2013 12:02 02/11/2013 12;03 02/11/2013 12:04 02/11/2013 12:05 02/11/2013 12:06 02/11/2013 12:07 02/11/2013 12:08 02/11/2013 12:09 02/11/ 2 013 12:10 02/11/ 2 013 12:11 02/11/2013 12:12 02/11/2013 12:13 02/11/2013 12:14 02/11/2013 12:15 02/11/2013 12:16 02/11/2013 12:17 02/11/ 2 013 12:18 02/11/2013 12:19 0 2 /11/2013 12:20 02/11/2013 12:21 02/11/2013 12:22 02/11/2013 12:23 02/11/2013 12:2 4 02/11/2013 12:25 02/11/2013 12:26 02/11/2013 12:27 02/11/2013 12:28 02/11/2013 12:29 02/11/2013 12:30 

### Date/Time Printed: G34-C4 G34 -C11 G34-C2 4>Stk NOx

Stk NOx 4>Stk 02 4>NOx Mass 

### ppm 0-150 2.B 2.6 2.7 2.B 2.B 2.B 2.B 2 . B 3.2 3.2 2. 7 2.4 2.7 2.7 2 . 7 2.B 2.7 2.7 2.7 2.7 2.6 2.B 2.7 2.6 2.6 2.6 2.6 2.7 2.B 2.B 2.B 2.B 2.B 2.B 2.7 2.7 2.7 2.7 2.6 2.7 Stk 02 % 0-25 12.91 12.92 12.90 12.89 12.90 12 .9 0 1 2.89 12.89 12.90 12.92 12.91 12.93 12.91 12 .9 1 12.92 12.90 12 . 90 12.92 12.92 12.93 12.92 12.91 12.91 12.92 12.92 12.91 12.90 12.89 12 . 89 12.88 12.87 12.88 12 . 89 12.88 12.88 12.89 12.90 12 . 91 12.90 12.89 02/11/2013 16,39 NOx Mass lb/hr 0-100 7.43 6.49 6.52 7.46 7.44 7.45 7.45 7.46 8.36 8 . 34 6.49 6.48 6.51 6.51 6.50 7.46 6.51 6.49 6.49 6.48 6. 4 7 7.42 6.49 6.48 6.48 6.50 6.49 6 . 51 7.45 7.46 7.46 7.46 7.45 7.44 6.52 6.51 6.52 6.51 6.52 6.52 G34-C20 4>StkFlow

StkFlow

kscfh 0-300000

21148 21163 2 1202 21182 21169 21185 21164 21182 21136 21140 21134 21154 21190 21193 21175 21207 21168 21163 21163 21140 21079 21121 21121 21100 21113 21144 21112 21131 21157 21159 21153 21165 21170 21119 21157 21144 21191 21200 21192 21169 G34 -C3 4>Stk CO

Stk CO 

### ppm 0-1000

0.4 0.9 2.6 3.2 3.3 3.2 3.5 3.4 3.5 0.5 0.4 0.7 1.2 1.7 2.2 2.1 2.2 2.3 2.5 2.3 2.3 2.1 1.7 1.6 1.5 1.6 

### loB 2.0 1.9 2.0 

### loB 1 . 7 1.7 

### loB 2.2 2.5 2.7 2.B 3.0 3.0 G34-C13 G34-C10 G34-C6 4>CO Mass 4>NOx Rate 4>Stk NOXc

CO Mass

lb/hr 0-100 0 . 93 0 . 93 3.73 4 . 66 4.65 4.66 5.59 5.59 5.57 0.93 0.93 0.93 1. 86 2.79 3.71 2.80 3.72 3.71 3.71 3.70 3.70 2.78 2 . 78 2.78 1. 85 2 .78 2.78 2.79 2 . 79 2.80 2 . 80 2.80 2.79 2.79 3.73 3 . 72 3 . 73 4.65 4.66 4.66 NOx Rate l b/mmBtu 0-1 0.008 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.009 0.009 0.007 0.007 0.007 0.007 0 . 007 0.008 0.007 0.007 0.007 0 . 007 0 . 007 0.008 0 . 007 0.007 0.007 0.007 0.007 0 . 007 0.008 0.008 0.008 0.008 0 . 008 0.008 0.007 0.007 0.007 0.007 0.007 0.007 Stk NOXc 

### ppm 0-300 2.07 1. 92 1. 99 2.06 2.07 2 . 07 2.06 2.06 2.36 2.37 1. 99 1. 78 1. 99 1. 99 2.00 2.07 1. 99 2.00 2.00 2.00 1. 92 2.07 1. 99 1. 92 1. 92 1. 92 1. 92 1. 99 2.06 2.06 2.06 2.06 2.06 2.06 1. 99 1. 99 1. 99 1. 99 1. 92 1. 99 G3 4 -C7 G34-C8 4>Stk COc 4>Gas Flow

Stk COc Gas hscfh ppm hscfh 0-1000 0-10000 0.30 0.67 1. 92 2.36 2.43 2.36 2.58 2.50 2.58 0 . 37 0.30 0 . 52 0 . 89 1. 26 1. 63 1. 55 1. 62 1. 70 1. 85 1. 70 1. 70 1. 55 1. 26 1.18 1.11 1.18 1. 33 1. 47 1. 40 1. 47 1. 32 1. 25 1.25 1.32 1. 62 1. 84 1. 99 2.07 2.21 2.21 8840.4 8835.6 8874.0 8876.4 8860.2 8866 . 8 8869 . 2 8876.4 8846.4 8826 . 0 8834 . 4 8820.6 8857.8 8859.0 8840.4 8875.8 8859.6 8835.6 8835.6 8814 . 6 8800.2 8829.0 8829.0 8809.2 8814.6 8838.6 8836 . 2 8855 .4 8866.2 8878.2 8886.6 8880 . 6 8871.6 8861. 4 8877.0 8860.8 8869 . 2 8862.0 8869.8 8871.0 G34-C18 4>NH3 Inj NH3Inj



### 1b/hr 0-200 110.0 110.0 110.0 110.0 110.0 110 . 0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 . 0 110.0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 

### 4>Summary

- l-Min RATA

- Continued G34-C 4>MW Lo

MW Lo 0-1 106 .. 105. : 10 6. ! 107. : 106.1 106 .. 106. 107. : 106. 106. : 106. ; 105 .. 105 .. 106. 106 .. 106. : 10 6 .. 106. : 106 .. 105 . 105. 106.! 106. 106. 106 .. 106. 106. 107. : 106 .. 107.1 107.1 107. ' 107. : 106 .. 106. 106. 107 . 107. ( 107. 107 ..**Pag~**

### Gr o up# - Channel# Long Descrip . Short Descrip. Units Range 02/11/2013 12:31 02/11/2013 12:32 02/11/2013 12:33 02/11/2013 12:34 02/11/2013 12:35 02/11/2013 12:36 02/11/2013 12:37 02/11/2013 12:38 02/11/2013 12:39 02/11/2013 12:40 02/11/2013 12:41 02/11/2013 12:42 02/11/2013 12:43 02/11/2013 12:44 02/11/2013 12:45 02/11/2013 12:46 02/11/2013 12:47 02/11/2013 12:48 02/11/2013 12:49 02/11/2013 12:50 02/11/2013 12:51 02/11/2013 12:52 02/11/2013 12:53 02/11/2013 12:54 02/11/2013 12:55 

### Period Average Period Max Value Period Min Value Period Totals 

## = Period % Recovery

Date/Time Printed: G3 4 -C2 4>Stk NOx

Stk NOx ppm 0-150 2.6 2.7 2.7 2.7 2.6 2.7 2 . 7 2.6 2.7 2.6 2.6 2.6 2.7 2.6 2 . 6 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.6 2.8 3.8 2.3 G3 4 -C4 G34 -C11 G34-C20 4>Stk 02 4>NOx Mass 4>StkFlow

Stk 02 % 0-25 12 . 91 12.90 12.90 12.90 12.91 12.89 12.89 12.89 12 . 88 12.88 12 . 87 12.88 12.88 12 . 87 12.88 12.88 12 . 88 12.87 12.88 12.88 12.87 12.88 12.87 12.87 12.89 12.91 12 . 97 12.87 NOx Mass 

### Ib/hr 0-100 6.50 6.51 6.51 6.51 6.50 6.51 6.52 6.52 6.52 6.52 6.52 6.51 6.52 6.53 6.52 6.53 6.52 6 . 53 6 . 52 6.53 6.51 6.52 6.53 6.52 6.51 7.07 9.36 5.56 StkFlow ksefh 0-300000

21147 21168 21168 21146 21143 21144 21164 21172 21152 21157 21129 21117 21147 21136 21134 21159 21152 21159 21151 21161 21093 21134 21133 21113 21127 21154 21332 21038 G34-C3 G34 -CD G34-C10 G34-C6 G34-C7 G34 -C8 G34

- C18 G34-C 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXe 4>Stk Cae 4>Gas Flow 4>NH3 Inj 4>MW Lo

Stk CO ppm 0-1000

3.3 3.1 2.9 3.2 3.3 3.2 2 . 9 2.8 2.7 2.7 2 . 9 3.2 3.2 3. 2 3.2 3.1 3.0 2.9 3.0 2.9 2.8 2.8 2.8 2.8 2.9 2. 4 3.7 0.3 CO Mass 

### Ib/hr 0-100 4.64 4 . 65 4.65 4.65 4.64 4.65 4.66 4.66 3.73 3.73 4.66 4.65 4.66 4.66 4.66 4.66 4.66 4.67 4.66 4 . 66 4.65 4.66 4.66 4.66 4.65 3.69 5.59 0.00 NOx Rate 

### Ib/mmBtu 0-1 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0 . 007 0.007 0.007 0 . 007 0.007 0.007 0.007 0.007 0 . 007 0.007 0.007 0 . 007 0.007 0.007 0 . 007 0.007 0.008 0.010 0.006 Stk NOXe ppm 0-300 1. 92 1. 99 1. 99 1. 99 1. 92 1. 99 1. 99 1.92 1. 99 1. 91 1. 91 1. 91 1. 99 1. 91 1. 91 1. 99 1. 99 1. 98 1. 99 1. 99 1. 98 1. 99 1. 98 1. 98 1. 92 2.07 2.80 1. 70 Stk COe Gas ppm hsefh hscfh 0-1000 2.44 2 . 29 2.14 2.36 2.44 2.36 2.14 2 . 06 1. 99 1. 99 2.13 2.35 2 . 35 2.35 2.35 2.28 2.21 2 .13 2.21 2.13 2 . 06 2.06 2.06 2.06 2.14 1. 79 2.73 0.2 2 0-10000 8839.8 8859.6 8859.6 8850.6 8838.0 8860.8 8869.2 8872.2 8875.2 8877 . 0 8876.4 8860.2 8872.8 8879 . 4 8867.4 8878.2 8875.2 8889.0 8874.6 8878.8 8861 . 4 8867 . 4 8878.2 8869 . 8 8853.6 8845.2 8951. 4 8731.8 NH3Inj 

### Ib/hr 0-200 110 . 0 110 . 0 110.0 110.0 110.0 110.0 110.0 110 . 0 110.0 110.0 110.0 110 . 0 110.0 110 . 0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110 . 0 110.0 110 . 0 110 . 0 110 . 0 MW Lo 0-1 106. : 106. : 106. ! 106.1 106 . . 106 .. 107. : 106. : 106. 107. 107. : 106. ! 107. 1 106 . 106. 106 .. 107 . . 107.! 106 .. 106 .. 107.1 107.: 107.: 106.: 106 .. 106.5

109 . 105. 7.1410E+2 3.2915E+3 1.8019E+3 5.3943E+6 6.1890E+2 9.3972E+2 1.9399E+0 5.2719E+2 4.5692E+2 2.2555E+6 2 . 8050E+4 2.7175E+ 100.0 100.0 100 . 0 100 . 0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

02/11/2013 16,39 

### 4>Summary

- I-Min RATA

- Continued**Pag~**

# Data Summary Report Com pany: CPV Sentinel, LLC 62575 Powerline Road

# 7uh~\ L{

Desert Hot Springs , CA 92240 

# PM**:}-7~** Source : Turbine 4 Data Group: 4>1-Min Cales Rep o rt Name: 

### Start of Report : 

### 4>Summary

- l-Min RATA 02/11/2013 14,48 G34-C4 

### End of Report, 02/11/2013 18,56 G34 -CII G34

- C20 G34-C3 G34-C13 

# TRACE Em J iro n me llt a i S y stems, Inc.

Validation: 

### All Available Data G34

- CIO G34-C6 G34-C7 G34-C8 G34

- C18 G34-C 

### Group#-Channel# Long Descrip. Short Descrip. 

### Units G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 

### 4>Stk 0 2 4>NOx Mass 4>StkFlow 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH3 Inj 4>MW La 

### Range 02(11(2013 14:48 02(11( 2 013 14:49 02(11(2013 14:50 02(11(2013 14:51 02(11(2013 14:52 02(11(2013 14:53 02(11(2013 14:54 02(11/2013 14:55 02(11(2013 14:56 02(11(2013 14:57 02(11(2013 14:58 02(11(2013 1 4 :59 02(11( 2 013 15:00 0 2 (11(2013 15:01 02(11(2013 15:02 02(11(2013 15:03 02(11(2013 15;04 02(11(2013 15;05 02(11(2013 15:06 02(11/2013 15:07 02/11/2013 15:08 02/11(2013 15:09 02/11(2013 15:10 02/11/2013 15:11 02/11/2013 15:12 02/11/2013 15:13 02/11/2013 15:14 02(11(2013 15;15 02(11(2013 15:16 0 2 (11(2013 15:17 

### Date/Time Printed: 1.9 2.0 1.9 2.0 

### 2.1 2.0 2.0 2.0 

### 2.0 2.0 

### 2.1 2.0 

### 2.1 2.1 2.0 

### 2.1 2.2 

### 2.1 2.1 2.2 

### 2.1 2.1 2.0 

### 2.0 2.2 

### 2.2 2.2 

### 2.0 1.7 1.9 St k 02 

# • 0

- 25 13.56 13.55 13.56 13
_54 13.53 13.54 13.53 13.53 13.53 13.53 13 . 53 13.55 13 . 55 13 . 55 13.55 13.57 13.55 13.56 13.56 13.55 13.56 13.56 13.56 13 . 56 13 . 55 13.56 13 . 56 13.55 13.54 13 . 54


### 02/11/2013 19,08 

### NOx Mass Ib/hr 0-100 4.38 4.39 4.37 4.40 4.42 4.40 4.40 4.41 4.41 4.40 4.40 4.38 4.38 4.39 4.39 4.37 5.12 4.37 4.37 5.11 4.38 4.37 4.38 4.38 5.11 5.12 5 . 10 4.39 3.66 4.39 

### StkFlow kscfh 0-300000

18107 18125 18076 18152 18185 18141 18129 18150 18150 18108 18130 18087 18069 18122 18117 18104 18126 18076 18075 18089 18087 18081 18103 18092 18064 18137 18075 18125 18086 18092 Stk CO 

### ppm 0-1000



### 0 . 5 0.6 0.6 0.6 0.6 

### 0.6 0.6 

### 0.6 0.6 0.6 0.6 

### 0.6 0.6 0.6 0.6 0.6 

### 0.6 0.6 0.7 0.7 0.7 0.7 0.6 0.7 0.6 0.7 0.6 0.7 1. 4 

### 2.3 

### CO Mass Ib/hr 0-100 0.73 0.73 0.73 0.73 0.74 0.73 0.73 0.73 0.73 0.73 0.73 0 . 73 0 . 73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0.73 0 . 73 0.73 2.19 2.93 

### NOx Rate Ib/mmBtu 

### 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 

### O.OOG O.OOG 0.007 0.006 

### O.OOG 0.007 0.006 0.006 0.006 0.006 0.007 0.007 0.007 0.006 0.005 0.006 

### Stk NOXc ppm 0

- 300 1. 53 1. 61 1. 53 1. 60 1. 68 1. 60 1. 60 1. 60 1. 60 1. 60 1. 68 1. 61 1. 69 1. 69 1. 61 1. 69 1. 77 1. 69 1. 69 1. 77 1. 69 1. 69 1. 61 1. 61 1. 77 1. 77 1. 77 1. 61 1.36 1. 52 Stk CDc Gas 

### hscfh ppm 0-1000 0. 4 0 0. 4 8 0. 4 8 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0. 4 8 0.48 0.48 0.48 0.48 0.48 0.56 0.56 0.5G 0.56 0.48 0.56 0.48 0.56 0.48 0.56 1.12 1. 84 

### hscfh 0

- 10000 6953.4 6969.G 6941. 4 6989.4 7011.6 6985.2 6990.0 6998.4 6998.4 6982.2 6990.6 6955.2 6948.0 6968.4 6966.6 6942.6 6970.2 6941. 4 6940.8 6955.8 6945. G 6943 . 2 6951. 6 6947.4 6946.2 6964.8 69 4 0.8 6969.6 696 4 .2 6966.6 NH3Inj Ib(hr 0

- 200 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 

### MW La 0-1 80 _. 

### BO. BO. 81.:**81. ~**  80 . . 81.( 80 .**~** 81. : 81.' 80. ' 80. : 80 . 1 80. : 80. : 80. : 80. : 80. : 

### BO. 80.1 80 . . 80. : 80 .. 80 .. 80. t 80 . . 79. B1. 

### 80 80.: 

### PagE

### Group#-Channel# Long Descrip. Short Descrip
. units Range 02/11/2013 15:18 02/11/2013 15:19 02/11/2013 15:20 02/11/2013 15:21 02/11/2013 15:22 02/11/2013 15:23 02/11/2013 15:24 02/11/2013 15:25 02/11/2013 15:26 02/11/2013 15:27 02/11/2013 15:28 02/11/2013 15:29 02/11/ 2013 15:30 02/11/2013 15:31 02/11/2013 15:32 02/11/2013 15:33 02/11/2013 15:34 02/11/2013 15:35 02/11/2013 15:36 02/11/2013 15:37 02/11/2013 15:38 02/11/2013 15:39 02/11/2013 15:40 02/11/2013 15:41 02/11/2013 15:42 02/11/2013 15:43 02/11/2013 15:44 02/11/2013 15:45 02/11/2013 15:46 02/11/2013 15:47 02/1 1 /2013 15:48 02/11/2013 15:49 02/11/2013 15:50 02/11/2013 15:51 02/11/2013 15:52 02/11/ 2 013 15:53 02/11/2013 15:54 02/11/2013 15:55 02/11/2013 15:56 02/11/2013 15:57 

### Date/Time Printed: G34-C4 G34

- C11 G34

- C2 4 , Stk NOx

Stk NOx ppm 0-150 4>Stk 02 4>NOx Mass

2.2 2.1 2.1 2.1 2.1 2.2 2.1 2.1 2.1 2.1 2 . 3 2.2 2.0 2.1 2.1 2.2 2.1 2.2 2.2 2.3 2.1 2.2 2.1 2.1 2.1 2.1 2.1 2.2 2.2 2.2 2.0 2.0 2.1 2.1 2.2 2.1 2.0 2.1 2.1 2.1 Stk 02 

# • 0-25 13 .52 13.52 13.51 13.52 13.51 13.50 13.5 2 13.51 13.53 13.54 13 . 53 13.53 13.54 13.54 13.53 13.53 13.54 13.54 13.53 13.53 13.54 13.53 13.53 13.54 13.53 13 . 53 13.52 13.52 13.52 13.52 13.53 13 .53 13.54 13.54 13.54 13.54 13.54 13.54 13.53 13.54 02/11/2013 19,08 NOx Mass Ib/hr 0-100 4.40 4.39 4.40 4.41 4.41 4.42 4.41 4.42 4.40 4.40 5.15 4.41 4.39 4.39 4.40 4.41 4.40 4.40 4.40 5.15 4.41 4.42 4.41 4.40 4.41 4.42 4.43 4.42 4.42 4.42 4.41 4.40 4.39 4.39 4.39 4.39 4 .39 4.40 4 . 41 4.41 G34-C20 4>StkFlow

StkFlow

ksefh 0-300000

18092 18060 18075 18130 18112 18111 18137 18140 18101 18130 18171 18174 18108 18097 18101 18146 18131 18130 18130 18153 18173 18186 18175 18134 18166 18189 18191 18163 18172 18183 18164 18111 18114 18100 18086 18108 18089 18139 18135 18180 G34-C3 4>Stk CO

Stk CO ppm 0-1000

2.0 1.6 1.7 1.7 1.8 1.7 1.7 1.8 2.0 2.3 2.2 2.0 2.4 2.5 2.7 2.3 2.3 2.3 2.3 1.9 1.8 1.9 1.7 1.9 1.9 1.7 1.7 1.7 1.8 1.6 1.6 1.9 2.2 2.3 2.3 2.6 2.3 2.0 1.9 1.7 G34 -CD G34

- C10 G34

- C6 4>CO Mass 4>NOx Rate 4>Stk NOXe

CO Mass lb/hr 0-100 2.93 2.20 2.20 2.21 2 . 21 2.21 2.21 2.21 2.93 2.93 2.94 2.94 2.93 2.93 3.66 2.94 2.93 2.93 2.94 2.21 2.20 2.21 2.21 2.20 2.21 2.21 2.21 2.21 2.21 2.21 2.21 2.20 2.93 2.93 2.92 3.66 2.93 2.93 2.20 2.21 NOx 

### Rate lb/mmBtu 0

- 1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXe ppm 0-300 1. 76 1. 68 1. 68 1. 68 1. 68 1. 75 1. 68 1. 68 1. 68 1. 68 1. 84 1. 76 1. 60 1. 68 1. 68 1. 76 1. 68 1. 76 1. 76 1. 84 1. 68 1. 76 1. 68 1. 68 1. 68 1. 68 1. 68 1. 76 1. 76 1. 76 1. 60 1. 60 1. 68 1. 68 1. 76 1. 68 1. 60 1. 68 1 .68 1. 68 G34-C7 G34-C8 4>Stk COe 4>Gas Flow

Stk COe 

### Gas hsefh 

### ppm hsefh 0-1000 0-10000

1. 60 1. 28 1. 36 1. 36 1.44 1.36 1. 36 1.44 1. 60 1. 84 1. 76 1. 60 1. 92 2.00 2.16 1. 84 1. 84 1. 84 1. 84 1. 52 1.44 1. 52 1. 36 1. 52 1. 52 1 36 1.36 1.36 1. 44 1.28 1.28 1. 52 1. 76 1. 84 1. 84 2.08 1. 84 1. 60 1. 52 1.36 6985.2 6973.2 6988.2 7000.2 7002.6 7011.6 7002.6 7013.4 6979.2 6981.0 7006.2 7007.4 6972.6 6968.4 6979.2 6996.6 6981.6 6981.0 6990.6 6999.6 6997.8 7012.2 7008.0 6982.8 7004.4 7013.4 7023.6 7012.8 7016.4 7020.6 7003.8 6983.4 6975.0 6969.6 6964.2 6972.6 6965.4 6984.6 6992.4 7000.2 G34

- C18 4 >NH3 Inj NH3Inj

Ib/hr 0-200 110.0 110.0 110.0 110 .0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 

### 4>Summary

- I-Min RATA

- Continued G34

- C 4>MW La

MW Lo 0-1 80. 80. 80 .**~** 80. 80 .. 81. : 81. : 81.t 80 .. 80.1 80. 80 .. 80. : 79. 80.

- 80 .. 80. 80. 80. 81.1 80. 

### Bl.: 81.: 80 . . 81 BO .. B1.: 81.t 81.1 81.: B1.! 80. 80 80.: 79. BO .. BO .1 80 . . 80 . . 81.1 

### PagE

### Group#-Channel# Long Descr i p. Short Des c r i p . units Rang e 02/11/2013 15:58 02 /11/20 13 15:59 02/11/2013 16:00 02/11/2013 16:01 02/11/2013 16:02 02/11/2013 16:03 02/11/2013 16:04 02/11/2013 16:05 02/11/2013 16:06 02/11/2013 16:07 02/11/2013 16:08 02/11/2013 16:09 02/11/2013 16:10 02/11/2013 16:11 02/11/2013 16:12 02/11/2013 16:13 02/11/2013 16:14 02/11/2013 16:15 02/11/2013 16:16 02/11/2013 16:17 02/11/2013 16:18 02/11/2013 16:19 02/11/2013 16:20 02/11/2013 16:21 02/11/2013 16:22 02/11/2013 16:23 02/11/2013 16:24 02/11/2013 16:25 02/11/2013 16:26 02/11/2013 16:27 02/11/2013 16:28 02/11/2013 16:29 02/11/2013 16:30 02/11/2013 16:31 02/11/2013 16:32 02/11/2013 16:33 02/11/2013 16:34 02/11/2013 16:35 02/11/2013 16:36 02/11/2013 16:37 

### Date/Time Printed: G34 -C4 G34 -C11 G34-C20 G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass 4>StkFlow

2.1 2.0 2.0 2.1 2.2 2.1 2.2 2.3 2.1 2.1 2.2 2.1 2.1 2.1 2.2 2.3 2.3 2.1 2.1 2.2 2.2 2.2 2.2 2.3 2.4 2.6 3.0 2.9 2.9 2.8 2.8 2.8 2.6 2.8 2.8 2.7 2.8 2.7 2.7 2.6 Stk 02 % 0-25 13.54 13.54 13.55 13.55 13.55 13.54 13 . 55 13.55 13 . 55 13.54 13.53 13 .54 13.54 13.54 13.53 13.53 13.53 13.53 13.53 13.53 13.53 13.53 13.53 13.54 13.53 13.53 13.54 13.55 13.55 13.5S 13.55 13.55 13.55 13 . 53 13.54 13. S4 13 . 55 13 . 55 13.55 13 . 55 02/11/2013 19,08 NOx Mass 

### lb/hr 0-100 4.42 4.41 4.40 4.40 5.15 4.41 5.14 S .15 4.41 4.42 4.42 4.40 4.41 4.39 4.41 5.15 5.16 4.42 4.42 4.42 4.42 4.43 4.42 5.17 5.16 5.90 6.66 6.63 6.64 5.90 5.92 5.91 5.87 5.89 5.92 5.91 5.89 5.89 5.89 5.89 StkFlow ksefh 0-300000

18202 18195 18142 18172 18218 18183 18176 18211 18215 18202 18199 18156 18187 18111 18169 18163 18217 18197 18177 18178 18178 18245 18211 18264 18211 18220 18300 18233 18270 18261 18321 18295 18175 18199 18289 18258 18250 18247 18242 18228 G34-C3 G34

- CD G34-C10 G34-C6 G34-C7 G34 -C8 G34-C18 G34-C 4>Stk CO 4>CO Mass 4 >NOx Rate 4>Stk NOXe 4>Stk COe 4>Gas Flow 4>NH3 Inj 4>MW Lo

Stk CO 

### ppm 0-1000

1.6 1.6 1.7 1.8 1.6 1.6 1.6 1.3 1.2 1.4 1.4 1.4 1.5 1.6 1.6 1.5 1.5 1.4 1.4 1.5 1.5 1.7 1.4 1.3 1.2 1.2 1.0 1.0 1.0 1.0 1.0 1.0 1.1 1.1 1.0 1.0 1.0 1.1 1.1 1.1 CO Mass 

### lb/hr 0-100 2.21 2.21 2.20 2.20 2.21 2.21 2.20 1. 47 1.47 2.21 2.21 2.20 2.21 2.20 2.21 2.21 2.21 2.21 2.21 2.21 2.21 2.22 2.21 1.48 1.47 1.4B 1.4B 1.47 1. 48 1. 47 1. 4B 1.48 1. 47 1. 47 1. 48 1. 48 1.47 1.47 1.47 1.47 NOx 

### Rate Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0 .007 0.006 0.007 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.007 0.008 0.009 0.009 0.009 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 

### O.OOB Stk NOXc 

### ppm 0-300 1. 68 1. 60 1. 61 1. 69 1. 77 1. 68 1. 77 1. 85 1. 69 1. 68 1. 76 1. 68 1. 68 1. 68 1. 76 1. 84 1. 84 1. 68 1. 68 1. 76 1. 76 1. 76 1. 76 1. 84 1. 92 2.08 2.40 2.33 2.33 2.25 2.25 2.25 2.09 2.24 2.24 2.16 2.25 2.17 2.17 2.09 Stk COc Gas hscfh ppm hscfh 0-1000 0-10000

1.28 1. 28 1.36 1.44 1.28 1.28 1. 28 1. 04 0.96 1.12 1.12 1.12 1.20 1. 28 1. 28 1. 20 1.20 1.12 1.12 1. 20 1. 20 1. 36 1.12 1. 04 0 . 96 0.96 

### O.BO 0.80 0.80 0.80 0.80 0.80 0.88 0 . 88 

### O.BO 0.80 0 . 80 0.88 0.88 0.88 7008.6 7006.2 6976.2 6987.6 7005.6 7001.4 6989.4 7002.6 7004.4 7008.6 7017.0 6991.2 7003.2 6973.8 7005.6 7003.2 7024.2 7016.4 7008.6 7009.2 7009.2 7035.0 7021.8 7032.6 7021.8 7025.4 7046.4 7011.0 7025.4 7021. 8 7045.2 7035.0 6988.8 7017.0 7042.2 7030.2 7017.6 7016.4 7014.6 7009.2 NH3Inj 

### lb/hr 0-200 1 10 .0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 110.0 118.5 118.S 119.2 117.7 120.2 119.2 114.5 116.2 115.0 113.7 115.S 118 .2 116.0 116.0 116.2 118.7 118.2 118.3 117.2 116.0 116.3 

### 4>Summary

- 1-Min RATA

- Continued MW Lo 0-1 81.1 81.1 80 .. 80 .. 81.: 80. : 80 .. 81.: 80 .. 81.1 81. 80. 81. . 80 81.: 80. 81. 81. 81.1 81. 81.! 81.1 82. I 

### BO .. 81. : 81.! 81. : 81.: 81.' 81.' 81. 82.1 81.: 81. . 82.: 81. . 81. 81. 80 .. 81.: Pag(

### Group#-Channel# Long Descrip
. Short Descrip
. Units Range 02/11/2013 16:38 02/11/2013 16:39 02/11/2013 16:40 02/11/2013 16:41 02/11/2013 16:42 02/11/2013 16:43 02/11/2013 16:44 02/11/2013 16:45 02/11/2013 16:46 02/11/2013 16:47 02/11/2013 16:48 02/11/2013 16:49 02/11/2013 16:50 02/11/2013 16:51 02/11/2013 16:52 02/11/20 1 3 16:53 02/11/2013 16:54 02/11/2013 16:55 02/11/2013 16:56 02/11/2013 16:57 02/11/2013 16:58 02/11/2013 16:59 0 2 /11/2013 17:00 02/11/ 2 013 17:01 02/11/2013 17:02 02/11/2013 17:03 02/11/2013 17:04 02/11/2013 17:05 02/11/2013 17:06 02/11/2013 17:07 02/11/2013 17:08 02/11/2013 17:09 02/11/2013 17:10 02/11/2013 17:11 02/11/2013 17:12 02/ 1 1/2013 17:13 02/11/2013 17:14 02/11/2013 17:15 02/11/ 2 013 17:16 02/11/2013 17:17 

### Date/Time Printed: G34-C4 G34-C11 G34 -C2 4>Stk NOx

Stk NOx ppm 0-150 4>Stk 02 4>NOx Mass

2.7 2.7 2.7 2.6 2.4 2.5 2.6 2.6 2.7 2.6 2.6 2.5 2.5 2.4 2.3 2.6 2.9 3.1 3.1 3.1 3.0 3.0 2.8 3.0 2.8 2.8 2.9 2.9 2.8 2.8 2.7 2.7 2.8 2.8 2.8 2.7 2.7 2.6 2.6 2.5 Stk 02 % 0-25 13.54 13.55 13 . 54 13.54 13.53 13.5 2 13.5 2 13 . 52 13 . 5 3 13.5 2 13.53 13 . 54 13 . 54 13.55 13.56 13.56 13.56 13.56 13.54 13 . 54 13 . 55 13.55 13 . 55 13 . 55 13.54 13.56 13.55 13.56 13.55 13.54 13.54 13.55 13 . 54 13.5 4 13 . 54 13.54 13.5 6 13.56 13 . 55 13.55 02/11/2013 19,08 NOx Mass lb/hr 0-100 5.91 5.90 5.92 5.93 5.19 5.18 5.93 5.93 5.93 5.94 5.95 5.19 5.20 5.19 5.16 5.B8 6.58 6.57 6.57 6 .58 6.56 6.57 5.82 6.57 5.84 5.83 6.58 6.60 5.87 5.87 5.86 5.87 5.89 5.89 5.89 5.89 5.90 5.91 5.92 S.18 G34-C20 4>StkFlow

StkFlow

kscfh 0-300000

18284 18261 18312 18320 18298 18264 18287 18276 18314 18317 18362 18325 18368 18379 18282 18243 18134 18096 18061 18085 18056 18092 18017 18086 18061 18071 18120 18178 18162 18153 18113 18170 18200 18205 18200 18203 18293 18315 18332 18329 G34 -C3 4>Stk CO

Stk CO ppm 0-1000

1.1 1.0 1.0 0.9 1.0 1.0 0 . 9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 1.0 1.2 1.2 1.4 1.4 1.4 1.4 1.5 1.5 1.6 1.5 1.5 1.5 1.4 1.4 1.3 1.4 1.3 1.3 1.3 1.3 1.3 1.2 1.2 1.1 1.1 G34-C13 G34-C10 G34-C6 4>CO Mass 4>NOx Rate 4>Stk NOXc

CO Mass 1b/hr 0-100 1.48 1.47 1.48 1.48 1.48 l.48 1.48 1.48 1.48 1.49 l.49 l. 48 1.49 l.48 l.47 1 47 1.46 2.19 2.19 2.19 2.19 2.19 2 . 18 2.19 2.19 2.19 2.19 2.20 2.20 1. 47 2.20 1. 47 1. 47 1. 47 1. 47 l. 4 7 l.48 1. 48 l.48 l.48 NOx Rate lb/mmBtu 0-1 0.008 0.008 0.008 0.008 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.007 0.007 0.007 0.007 0.008 0.009 0.009 0.009 0.009 0.009 0.009 0.008 0.009 0.008 0.008 0.009 0.009 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.007 Stk NOXc ppm 0-300 2.16 2.17 2.16 2.08 1. 92 2.00 2.08 2.08 2.16 2.08 2.08 2.00 2.00 1. 93 1 85 2.09 2.33 2.49 2.49 2.49 2.41 2.41 2.25 2.41 2.24 2.25 2.33 2.33 2.25 2.24 2.16 2.17 2.24 2.24 2.24 2.16 2.17 2.09 2.09 2.01 G34 -C7 G34-C8 4>Stk COc 4>Gas Flow

Stk COc Gas hscfh ppm hscfh 0-1000 0-10000 0.88 0.80 0.80 0.72 0.80 0.80 0 . 72 0 . 72 0 . 72 0.72 0.72 0.72 0.72 0.72 0.80 0.96 0.96 l.13 1.12 1.12 l.12 1. 2 0 1. 20 1. 28 l. 20 1.21 l. 20 l.13 l.12 1.04 l. 1 2 1. 04 1. 04 l. 04 1.04 l.0 4 0.96 0.9 6 0 .8 8 0 . 88 7040.4 7021.8 7051.2 7054.2 7055.4 7051.8 7060.8 7056.6 7061.4 7072.2 7080.0 7056.0 7072.8 7067.4 7020.6 7005.6 6963.6 6949.2 6954.6 6963.6 6943.2 6957.0 6928.2 6954.6 6954.6 6939.6 6967.8 6980.4 6984.0 6990.0 6974.4 6987.0 7008.0 7009.8 7008.0 7009.2 7024.8 7033.2 7049.4 7048.2 G34-C18 4>NH3 Inj NH3Inj

1b/hr 0-200 118.3 118.2 119.3 120.3 120.5 121.7 122.3 121.0 122.8 122.0 124.2 121. 2 121. 3 123.3 117.7 111. 8 110.3 109.8 109.5 109.2 109.3 109.3 110.3 109.8 110.8 110.5 111. 3 112.3 112.7 115.8 113. 7 113.5 115.0 113.7 115.7 114.5 118.2 117.3 118.8 118.7 

### 4 >Summary - I-Min RATA

- Continued G34-C 4;:.MW La

MW Lo

0-1 8l. : 81.'**81.~** 82.1 82 83.1 82.1 82 . . 82.1 81. . 82.: 82. I 8l.: 81 81.! 81.' 80 . . 80 .. 80. ! 80 .. 79 . 80 .. 79. : 80 .. 80. 79 .. 80 .. 80. 81. 1 81.- 80 . . 80. 81.: 80 .. 81.1 80. 81 81. . 81. . 81. . 

### PagE

### Group#-Channel# Long Descrip. Short Descrip. Units Range 02/ 11 /2013 17:18 02/11/2013 17:19 02/11/2013 17:20 02/11/2013 17:21 02/11/2013 17:22 02/11/2013 17:23 02/11/2013 17:24 02/11/2013 17:25 02/11/2013 17:26 02/11/2013 17:27 02/11/2013 17:28 02/11/2013 17:29 02/11/2013 17:30 02/11/2013 17:31 02/11/2013 17:32 02/11/2013 17:33 02/11/2013 17:34 02/11/2013 17:35 02/11/2013 17:36 02/11/2013 17:37 02/11/2013 17:38 02/11/2013 17:39 02/11/2013 17:40 02/11/2013 17:41 02/11/2013 17:42 02/11/2013 17:43 02/11/2013 17:44 02/11/2013 17:45 02/11/2013 17:46 02/11/2013 17:47 02/11/2013 17:48 02/11/2013 17:49 02/11/2013 17:50 02/11/2013 17:51 02/11/2013 17:52 02/11/Z013 17: 53 02/11/2013 17:54 02/11/ 20 13 17:55 02/11/2013 17:56 02/11/2013 17:57 

### Date/Time Printed: G34-C4 G34-C11 G34 -C2 4>Stk NOx

S t k NOx 

### ppm 0-150 4>Stk 02 4>NOx Mass

2.5 2.5 2.4 2.3 2.4 2.5 2.6 2.5 2.5 2.5 2.6 2.5 2.5 2.4 2.5 2.7 2.7 2.7 2.7 2.6 2.7 2.7 2.7 2.7 2.6 2.5 2. ' 2.7 2.5 2.9 2.9 2.8 2.8 2.7 2.6 2.6 2.7 2.7 2.7 2.7 Stk 02 \ 0-25 13.56 13.56 13.56 13.57 13.56 13 . 57 13 . 5 8 13 . 58 13. 58 13.56 13.55 13.56 13.56 13.57 13.57 13.55 13.55 13.56 13.55 13.55 13.55 13.54 13.55 13.55 13 . 56 13.56 13.58 13.57 13.57 13.58 13.58 13.58 13.57 13.58 13.59 13.58 13.58 13.57 13.57 13.57 02/11/2013 19,08 NOx Mass 

### Ib/hr 0 -10 0 5.18 5.18 5.17 5.16 5.17 5.16 5.90 5.15 5.14 5.15 5.90 5.14 5.14 5.12 5.11 5.84 5.84 5.83 5.86 5.85 5.85 5.86 5.85 5.86 5.85 5.13 5.09 5.85 5.10 6.57 6.56 5.84 5.84 5.82 5.81 5.80 5.80 5.82 5.82 5.81 G34-C20 4>StkFlow

StkFlow

kscfh 0-300000

18359 18356 18332 18295 18332 18310 18329 18281 18260 18251 18265 18212 18193 18157 18123 18083 18072 18059 18128 18115 18111 18127 18108 18144 18145 18159 18096 18166 18107 18151 18140 18138 18140 18099 18072 18031 18027 18071 18059 18044 G34-C3 4>Stk CO

Stk CO 

### ppm 0-1000

1.1 1.0 1.1 1.1 1.1 1.1 1.1 1.2 1.3 1.3 1.2 1.3 1.3 1.3 1.5 1.5 1.5 1.5 1.5 1.3 1.3 1.3 1.3 1.4 1.3 1.3 1.. 1.4 1.4 1.4 1.5 1.4 1.4 1.5 1.6 1.7 1.6 1.6 1.4 1.4 G34-C13 G34-C10 G3 4 -C6 4>CO 

### Mass 4>NOx Rate 4>Stk NOXc

CO 

### Mass 1b/hr 0-100 1.48 1.48 1. 48 1. 47 1.48 1. 47 1.47 1.47 1.47 1.47 1.48 1.47 1.47 1.46 2.19 2.19 2.19 2.18 2.20 1.46 1.46 1. 47 1. 46 2.20 1. 46 1. 46 2.18 2.19 2.19 2.19 2.19 2.19 2.19 2.18 2.18 2.18 2 . 17 2.18 2.18 2.18 NOx Rate 

### Ib/mmBtu 0-1 0.007 0.007 0.007 0.007 0.007 0.007 0.008 0.007 0.007 0.007 0.008 0.007 0.007 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.007 0.007 0.008 0.007 0.009 0.009 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 Stk NOXc 

### ppm 0-300 2.01 2.01 1. 93 1. 85 1. 93 2.01 2.10 2.02 2.02 2.01 2.09 2.01 2.01 1. 93 2.01 2.17 2.17 2.17 2.17 2.09 2.17 2.16 2.17 2 . 17 2.09 2.01 1. 93 2.17 2.01 2.34 2.34 2.26 2.25 2.18 2.10 2.10 2.18 2.17 2.17 2.17 G34-C7 G34 -C8 4>Stk COc 4>Gas Flow

Stk COc Gas 

### hscfh ppm hscfh 0-1000 0-10000 0.88 0.80 0.88 0 . 89 0.88 0.89 0.89 0.97 1. 05 1. 04 0 . 96 1. 04 1. 04 1. 05 1. 21 1.20 1.20 1.21 1.20 1. 04 1. 0 4 1. 04 1. 04 1.12 1. 04 1. 04 1.13 1.13 1.13 1.13 1. 21 1.13 1.13 1.21 1.29 1.37 1.29 1. 29 1.13 1.13 7050.0 7048.8 7039.8 7015.8 7039.8 7021. 8 7019.4 7000.8 6993.0 7008.6 7023.6 6993.6 6986.4 6963.0 6949.8 6953.4 6949.2 6934.8 6970.8 6966.0 6964.2 6979.8 6963.0 6976.8 6967.8 6973.2 6930.0 6966.6 6943.8 6951.0 6946.8 6946.2 6956.4 6931. 2 6911.4 6905.4 6903.6 6930.0 6925.2 6919 . 8 G34

- C18 4 >

NH3 Inj

NH3Inj



### lb / hr 0

- 200 119.8 119.8 119.8 118.7 118.3 118.3 117.2 115.5 115.2 115 .8 117.5 116.0 ll4.8 116.7 112.3 111.8 111.0 111.0 112.0 114. 

## a 114.3 114.5 113.3 115.0 114.5 114.8 112.5 114.7 112.0 109.7 111.2 109.5 111. 8 110. 

## a 109.5 109.5 110.7 109 . 2 ll1.8 112.0 

### 4>Summary

- I-Min RATA

- Continued G34-C 4>MW Lo

MW Lo 0-1 82. t 81. ! 81. 82. 1 82. 1 81. 81.' 81. 80 .. 81.: 81. : 81.: 81.: 80 . . 80 .. 80. ! 80.: 79. 1 80. : 80 .. 80 . . 80.: 80. ! 80. : 80. : 80 .. 79 80.1 79. 1 80. ! 80 .: 80 .. 80. 79. 79. 79 . . 79.: 79. : 79 .. 80.1 Pag{

### Group#-Channel# Long Descrip . Short Descrip. Units Range 02/11/2013 17:58 02/11/2013 17:59 02/11/2013 18:00 02/11/2013 18:01 02/11/2013 18:02 02/11/2013 18:03 02/11/2013 18:04 02/11/2013 18:05 02/11/2013 18:06 02/11/2013 18:07 02/11/2013 18:08 02/11/2013 18:09 02/11/2013 18:10 02/11/2013 18:11 02/11/2013 18:12 0 2 /11/2013 18:13 02/11/2013 18:14 02/11/2013 18:15 02/11/2013 18:16 02/11/2013 18:17 02/11/2013 18 : 18 02/11/2013 18:19 02/11/2013 18:20 02/11/2013 18:21 02/11/2013 18;22 02/11/2013 18:23 02/11/2013 18:24 02/11/2013 18:25 02/11/2013 18:26 02/11/2013 18:27 02/11/2013 18:28 02/11/2013 18:29 02/11/2013 18:30 02/11/2013 18:31 02/11/2013 18:32 02/11/2013 18:33 02/11/2013 18:34 02/11/2013 18:35 02/11/2013 18:36 02/11/2013 18:37 

### Date/Time Printed: G34

- C4 G34-C11 G34-C20 G34

- C2 4>Stk NOx

Stk NOx 4>Stk 02 4>NOx Mass 4>StkFlow 

### ppm 0-150 2.6 2.6 2.5 2.5 2.6 2. 5 2.5 2.6 2.5 2.5 2.5 2.5 2.7 3.1 3.1 3.1 

### 2.9 3.0 3.0 

### 2.8 2.8 2.8 2.B 2.7 2.6 2.6 2.7 

### 2.8 2.7 2.7 2 . 6 2.5 2.5 2.5 2.5 2.5 2.7 2.7 2.7 

### 2.8 Stk 02 

# • 0-25 13 .57 13.58 13.58 13.58 13 .5 7 13.56 13.57 13.57 13.57 13.57 13.57 13 . 56 13 . 56 13.56 13 . 56 13.57 13.57 13.58 13.58 13.57 13.58 13 . 58 13.58 13.58 13.59 13.59 13.59 13.5 9 13.59 13.59 13.58 13 .60 13.60 13.59 13.59 13.59 13 . 58 13.59 13.59 13.59 

### 02/11/2013 19,08 NOx Mass 

### 1b/hr 0-100 5.80 5.79 5.06 5.06 5.80 5.10 5.08 5.82 5.08 5.09 5.09 5.09 5.82 6.55 6.57 6.54 6.55 6.53 6.55 5.83 5.81 5.82 5.82 5.82 5.82 5.83 5.83 5.82 5.82 5.83 5.83 5.09 5.08 5.09 5.09 5 . 07 5.81 5.80 5.80 5.80 StkFlow kscfh 0-300000

17999 17988 17984 17963 18016 18067 18038 18054 18038 18055 18046 18021 18054 18064 18093 18054 18073 18055 18111 18087 18064 18097 18107 18093 18103 18146 18141 18127 18111 18161 18110 18123 18103 18092 18091 18050 18058 18069 18061 18058 G34 -C3 G34-C13 G34

- C10 G34

- C6 G34-C7 G34-C8 G34 -C18 G34-C 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXe 4>Stk COe 4>Gas Flo w 4>NH3 Inj 4>MW Lo

Stk 

### co ppm 0-1000

1.5 1.6 1.6 1.7 1.7 1.4 1. 4 1.5 1.5 1.5 1.5 1.4 1.4 1.4 1.4 1.4 1.5 1.5 1.5 1.5 1.5 1.5 1.6 1.6 1.6 1.6 1.6 1.7 1.7 1.6 1.6 1.7 1.8 1.8 1.7 1.6 1.8 1.7 1.9 1.8 CO Mass 

### 1b/hr 0-100 2.17 2.17 2.17 2.17 2 .1 8 2.19 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.19 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.18 2.19 2.19 2.18 2.18 2 .19 2.18 2.18 2.18 2.18 2.18 2.17 2.18 2.18 2.18 2.18 NOx Rate 

### Ib/mmBtu 0-1 0.008 0.008 0.007 0.007 0 . 008 0.007 0.007 0.008 0.007 0.007 0.007 0.007 0.008 0.009 0.009 0.009 0.009 0.009 0.009 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0 . 008 0.007 0 . 007 0.007 0.007 0.007 0.008 0 . 008 0.008 0.008 Stk NOXe 

### ppm 0-300 2.09 2.10 2.02 2.02 2.09 2.01 2.01 2.09 2.01 2.01 2.01 2.01 2 . 17 2.49 2.49 2.50 2.33 2.42 2.42 2.25 2.26 2.26 2.26 2.18 2.10 2 . 10 2 . 18 2.26 2.18 2.18 2.10 2.02 2.02 2.02 2.02 2.02 2.18 2.18 2.18 2.26 Stk COe Gas hscfh ppm hscfh 0-1000 0-10000

1.21 1.29 1.29 1.37 1.37 1.13 1.13 1. 21 1.21 1.21 1. 21 1.13 1.13 1.13 l.13 1.13 l. 21 1. 21 1. 21 1. 21 1. 21 1.21 1. 29 1.29 1.29 1. 29 l. 29 1. 37 1. 37 1. 29 1. 29 1. 37 1. 45 1. 45 1. 37 1.29 1.45 1.37 1. 53 1.45 6902.4 6888.6 6887.4 6879.0 6909.0 6937.8 6917.4 6923.4 6917.4 6924.0 6920.4 6920.4 6933.0 6936.6 6948.0 6923 . 4 6930.6 6914.4 6936.0 6936 .0 6918.0 6930.6 6934.2 6928 . 8 6923.4 6939.6 6937.8 6932.4 6926.4 6945.6 6935.4 6921. 6 6913.8 6919.2 6918.6 6903.0 6915 .6 6910.2 6907.2 6906.0 NH3Inj 

### Ib/hr 0-200 109.7 110.7 109.2 110.7 109.2 113.0 112.2 11 2.8 113 .2 110.7 111. 7 113.8 109.8 109.0 108.2 108.2 108.5 109.0 108.7 110 .8 110.0 110.8 111.8 110.8 111.3 111 .2 112 . 5 111. 2 110 . 7 111. 8 111 .8 112.0 110.2 111.2 111.0 11 2.2 109.5 109.7 109.2 109 . 7 

### 4>Summary

- I-Min RATA

- Continued MW Lo 0-1 79 . . 79. ! 78 . . 79. : 79 . 79. 79. 80. ( 79. 80 . : 79. 79 . : 80. : 79 .. 80. ! 80. ( 80 . ( 79 . . 80 .. 79 .**~** 79. ! 79.: 80 . ( 80. ( 80. ( 79 . . 80.: 80.: 79 .. 80 .**~** 80.1 79.: 79 .**~** 79 .. 79 .. 79 .**~** 79. 79. : 80. ( 79.: 

### PagE

### Group#-Channel# Long Des crip. Short Descrip. Units Range 02/11/2013 18:38 02/11/2013 18:39 02/11/2013 18:40 02/11/2013 18 :41 02/11/2013 18:42 02/11/2013 18:43 02/11/2013 18:44 02/11/2013 18 : 45 02/11/2013 18:46 02/11/2013 18:47 02/11/2013 18:48 02/11/2013 18:49 02/11/2013 18:50 02/11/2013 18:51 02/11/2013 18:52 02/11/2013 18:53 02/11/2013 18:54 0 2 /11/2013 18:55 02/11/2013 18:56 

### Period Average Period Max Value Period Min Value Period Totals 

## = Period 

### % Recovery

Date/Time Printed: G34-C2 4>Stk NOx

Stk NOx 

### ppm 0-150 2.8 2.7 2.6 2.6 2.6 2.6 2.6 2 . 5 2.6 2.5 2.4 2.7 2.8 2.8 2.7 2.7 2.4 2.7 2.7 2.5 3 . 1 1.7 G34-C4 G34 -C11 G34-C20 4>stk 02 4>NOx Mass 4>StkFlow

Stk 02 

# • 0-25 13.58 13.58 13.58 13.58 13.58 13.58 13.58 13.58 13.58 13.58 13.58 13 . 59 13.59 13.58 13.59 13.58 13.59 13.59 13.59 13.55 13.60 13.50 NOx Mass 

### 1b/hr 0-100 5.81 5.80 5.81 5.80 5.80 5.80 5 . 82 5.07 5.81 5.08 5.08 5.80 5.81 5.82 5.81 5.80 5.06 5.79 5.80 5.28 6.66 3.66 StkFlow kscfh 0-300000

18055 18025 18050 18033 18041 18025 18088 18006 18066 18058 18030 18061 18078 18080 18075 18039 18014 18037 18040 18145 18379 17963 G34

- C3 G34-C13 G34-C10 G34-C6 G34-C7 G34-C8 G34-C18 G34-C 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXe 4>Stk COe 4>Gas Flow 4>NH3 Inj 4>MW Lo

Stk CO 

### ppm 0-1000

1.7 1.7 1.7 1.6 1.8 1.7 1.6 1.7 1.6 1.6 1.7 1.9 1.8 1.7 1.7 1.8 2.0 1.9 1.9 1.4 2 . 7 0.5 CO Mass Ib/hr 0-100 2.18 2.17 2 . 18 2.18 2.18 2.17 2.18 2.17 2.18 2.18 2 . 18 2 .18 2 . 18 2.18 2.18 2.18 2.89 2.17 2.17 1. 90 3.66 0.73 NOx Rate Ib/mmBtu 0-1 0.008 0 . 008 0 . 008 0.008 0.008 0.008 0.008 0.007 0.008 0.007 0.007 0 . 008 0.008 0.008 0.008 0.008 0.007 0.008 0.008 0.007 0.009 0.005 Stk NOXc 

### ppm 0-300 2.26 2.18 2.10 2.10 2.10 2.10 2.10 2.02 2.10 2 . 02 1. 93 2.18 2 .2 6 2.26 2.18 2.18 1. 94 2.18 2.18 1. 98 2.50 1. 36 Stk COe Gas 

### ppm 0-1000

1.37 1.37 1. 37 1. 29 1. 45 1. 37 1. 29 1. 37 1. 29 1. 29 1.37 1. 53 1.45 1.37 1. 37 1.45 1. 61 1. 53 1. 53 1.13 2.16 0.40 hsefh hscfh 0

- 10000 6914.4 6903.0 6912.6 6906.0 6909.0 6903.0 6927.0 6895.8 6918.6 6915.6 6904.8 6907.2 6913.8 6924.0 6912.6 6908.4 6889.2 6898.2 6899.4 6974 . 0 7080 . 0 6879 . 0 NH3Inj 

### 1b/hr 0-200 111. 3 1 10 .7 111. 2 111.7 109.7 111.3 111.7 111. 5 112.7 112 . 3 110.7 108.3 107.8 109.2 109.5 110 . 3 108.3 109.0 108 . 0 112.3 124 . 2 107.8 MW Lo 0-1 79 .. 79 .. 80 .. 79 .. 78. : 80. ! 79 . . 79.! 79. 79 . . 79.: 79 79. 79 .. 79. 80. ! 79. ! 79. : 79. : 80.5

83. 78. 6.1250E+2 3.3748E+3 1.3141E+3 4.S182E+6 3.5200E+2 4.7350E+2 1.7950E+0 4.9208E+2 2.8244E+2 1. 7365E+6 2.7964E+4 2.0066E+ 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

02/11/2013 19,08 

### 4>Summary

- I-Min RATA

- Continued PagE

# Data Summary Report Company : CPV Sentinel, LLC 62575 Powerline Road 

### Source: Data Group : Report Na me : 

### Start of Report: 

### Desert Hot Springs, CA 92240 Turbine 4 

### 4>!-Min Cales 4>Summary

- I-Min RATA 02/12/2013 11,45 

# StM1"'-\ L{ 0"\ 

# 7 rfl o

End of Report, 02/12/2013 15,52 G34-C4 G34

- Cll G34 -C2 0 G34-C3 G34-C13 

# TRACE Env i ro nm ental S y ste m s, III C.



### Validat ion : All Available Data G)4-CIO G34-C6 G34-C7 G34-CB G34-C18 G34 -C 

### Group#-Channel# Long Descrip
. Short Descrip. Units G34-C2 4>Stk NOx Stk NOx 

### ppm 0-150 

### 4>Stk 02 4>NOx Mass 4>StkFlow 4>Stk CO 4>CO 

### Mass 4>NOx Rate 4>Stk NOXc 4>Stk CDc 4>Gas Flow 4>NH) Inj 4>MW La 

### Range 02/12/2013 11:45 02/12/2013 11:46 02/12/2013 11:47 02/12/2013 11:48 02/12/2013 11:49 02/12/2013 11:50 02/12/2013 11:51 02/12/2013 11:52 02/12/2013 11:53 02/12/2013 11:54 02/12/2013 11:55 02/12/2013 11:56 02/12/2013 11:57 02/12/2013 11:58 02/12/2013 11:59 02/12/2013 12:00 02/12/2013 12:01 02/12/2013 12:02 02/12/2013 12:03 02/12/2013 12:04 02/12/ 2 013 12:05 02/12/2013 12:06 02/12/2013 12:07 02/12/2013 12:08 02/12/2013 12;09 02/12/2013 12:10 02/12/2013 12:11 02/12/2013 12:12 02/12/2013 12:13 02/12/2013 12:14 

### Date/Time Printed: 2.' 2.G 

### 2.5 2.5 2.3 2.2 

### 2.0 loG 

### 1.5 loG loG 

### 1.5 1.5 loG loG lo G loG loG 

### 1.7 1.7 1.8 1.8 1.7 1.7 1.7 1.7 1.8 1.8 1.. 1.8 Stk 02 

# • 0-25 14 .13 14 .11 14 .11 14.10 14.09 14.09 14.09 14.08 14.09 14.08 14.08 14.09 14.09 14.09 14.09 14 .10 14.10 14.10 14.10 14 .10 14.09 14.09 14.08 14.08 14.08 14.08 14.08 14.08 1 4 .08 14.09


### 02/12/2013 17,44 NOx Mass 

### 1b/hr 0-100 4.43 4.48 4.49 4.50 3.95 3.9 4 3.37 2.82 2.82 2.83 2.83 2.83 2.81 2.82 2.B1 2.81 2.B2 2.81 2.82 2.80 3 . 38 3.40 2.84 2.83 2.83 2.81 3.39 3.39 3.39 3.3 9 StkFlow kscfh 0-300000

14882 15009 15034 15047 15067 15037 15018 15060 15088 15097 1 5116 15116 15040 15062 15032 15049 15103 15029 15078 14995 15035 15165 15138 15111 15116 15020 15059 15081 15099 15082 

### Stk CO 

### ppm 0-1000

D.' 

### D.' D.' D.' D.' 

### D.' D.' 

### D.' D.' 

### D.' D.' D.' D.' 

### D.' D.' 

### D.' D.' 

### D.' D.' D.' D.' D.' D.' D.' D.' D.' D.' D.' D.' D.' CO Mass 

### Ib/hr 0-100 0.55 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.57 0.56 0.56 0.57 0.57 0.56 NOx Rate 

### Ib/mmBtu 0-1 0.008 0.008 0.00 8 0.008 0.007 0.00 7 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 Stk NOXc 

### ppm 0-300 2,09 2.26 2.17 2.17 1. 99 1. 91 1. 73 1. 38 1. 30 1. 38 1. 38 1.30 1.30 1.39 1. 39 1. 39 1. 39 1. 39 1. 48 1. 48 1. 56 1. 56 1.47 1.47 1.47 1. 47 1. 56 1. 56 1. 64 1. 56 Stk CDc Gas 

### ppm hscfh hscfh 0-1000 0.35 0.35 0.35 0.35 0.35 0,35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0-10000 5271 . 0 5331. 6 5340.6 5353.2 5368.2 5357. 4 5350.8 5373.6 5375.4 53 86.8 5393.4 5385.6 5358,6 5366.4 5355.6 5353.8 5373.0 5346.6 5364 . 0 5334.6 5356 . 8 5403.0 5401.2 5391,6 5393.4 5359.2 5373.0 5380.8 5387.4 5373.6 NH3Inj 

### Ib/hr 0-200 99 . 0 101. 8 101. 3 101. 3 1 03 .2 101,8 107.S 111.2 112.2 112.0 112.0 110.8 109.S 109.5 111.2 109.5 109.0 10B.3 108.8 106.3 106.5 108.8 109.3 108.3 108.3 106.7 107.2 10S.2 108.5 107.3 MW Lo 0

- 1 53. : 55.1 55.1 55.! 56.1 

### 55 ' 55. : 55.' 55.: 

### 55. 55.' 55.! 

### 55. 55, ' 55, ! 55 . . 55, . 55.1 55, ' 54.: 

### 55 55.: 55, ' 

### 55. 55,' 55. ! 55.: 55. : 56.1 55.: 

### Pag(

### Group#-Channe l# Long Des c rip . Short Descrip . Units Range 02/12/2013 12:15 02/12/2013 12:16 02/12/2013 12:17 02/12/2013 12:18 02/12/2013 12:19 02/12/2013 12:20 02/12/2013 12:21 02/12/2013 12:22 02/12/2013 12:23 02/12/2013 12:24 02/12/2013 12:25 02/12/2013 12:26 02/1 2 /2013 12:27 02/12/2013 12:28 02/12/2013 12:29 02/12/2013 12:30 02/12/2013 12:31 02/12/2013 12:32 02/12/2013 12:33 02/12/2013 12:34 02/12/2013 12:35 02/12/2013 12:36 02/12/2013 12:37 02/12/2013 12:38 02/12/2013 12:39 02/12/2013 12:40 02/12/2013 12:41 02/12(2013 12:42 02(12(2013 12:43 02(12(2013 12:44 02/12/2013 12:45 02/12(2013 12:46 02(12/2013 12:47 02(12(2013 12:48 02(12/2013 12:49 02/12(2013 12:50 02/12/2013 12:51 02/12/2013 12:52 02/1 2 /2013 12:53 02/12/2013 12:54 

### Date/Time Printed: G34 -C4 G34 -C11 G34-C2 4>Stk NOx

Stk NOx 

### ppm 0

- 150 4>Stk 02 4>NOx Mass

1.8 1.7 1.8 1.9 1.9 1.9 1.9 1.9 2.0 1.9 1.9 1.9 1.9 2.0 2.0 2.1 2.2 2 . 4 2.6 2.4 2.6 2.7 2.4 2.6 2.7 2.5 2.4 2.5 2 .5 2.5 2.5 2.4 2.4 2.4 2.2 2.8 2.9 3.2 3.0 2.9 Stk 02 

# • 0-25 14.09 14.10 14 .10 14 .10 14.10 14 . 1 0 14.09 14.08 14.09 14.09 14.08 14.09 1 4. 09 14 . 09 14.09 14. 09 14 . 09 14 .10 14 . 08 14.09 14.09 14.08 14.09 14.09 14.09 14.09 14.09 14 . 08 14 . 09 14.09 14.08 14.08 14.09 14.09 14.09 14.09 14.10 14.09 14 . 10 14 . 09 02/12/2013 17,44 NOx Mass 

### 1b/hr 0-100 3.38 2.81 3.37 3.37 3.37 3.37 3.36 3.36 3.36 3.35 3.34 3.35 3.3 6 3.3 4 3.35 3.91 3.92 4.48 4.49 4.47 4.46 5.03 4. 4 5 4.45 5.04 4.46 4.45 4.46 4 . 45 4.46 4.47 4.48 4.47 4.47 3.90 5.01 5.00 5.57 5.5 6 5.02 G34-C20 4>StkFlow

StkFlow

kscfh 0-300000

15074 15034 15054 15044 15037 15035 14978 14951 14966 14941 14877 14907 14953 14890 14909 14922 14960 15007 14995 14934 14907 14906 14855 14877 14981 14912 14853 14885 14880 14899 14926 14954 14949 14938 14884 14872 14867 14889 14877 14912 G34 -C3 4>Stk CO

Stk
.CO 

### ppm 0-1000

0.4 0.4 0.4 0.5 0.5 0.5 0.5 0.4 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.4 0.4 0.4 0.4 0.5 0.4 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.4 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 G34 -C l3 G34 -C 10 G34

- C6 4>CO Mass 4>NOx Rate 4>Stk NOXc



## co Mass 

### 1b/hr 0-100 0.56 0.56 0 . 56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 NOx Rate Ib/mmBtu 0-1 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.007 0.007 0.008 0.008 0.008 0.008 0.009 O.OOS O.OOS 0.009 0.008 O.OOS 0.008 O.OOS O.OOS 0.008 0.008 0.008 0.008 0.007 0.009 0.009 0.010 0.010 0.009 Stk NOXc 

### ppm 0-300 1. 56 1. 4S 1. 56 1. 65 1.65 1. 65 1. 65 1. 64 1. 73 1. 65 1. 64 1. 65 1. 65 1. 73 1. 73 1. S2 1. 91 2.08 2.25 2.08 2.25 2.34 2.08 2.25 2.34 2.17 2.0S 2.16 2.17 2.17 2.16 2.08 2.08 2.08 1. 91 2.43 2.52 2.77 2.60 2.51 G34-C7 G34-C8 G34-C18 4>Stk COc 4 >Gas Flow 4>NH3 Inj

Stk COc Gas hscfh NH3Inj ppm hscfh Ib/hr 0-1000 0-10000 0-200 0.35 0.35 0.35 0.43 0.43 0.43 0.43 0.35 0.43 0.43 0.43 0.43 0. 4 3 0.43 0.43 0.43 0.35 0 . 35 0.35 0.35 0.43 0.35 0.43 0.43 0.43 0.43 0.43 0 . 43 0 . 43 0.43 0.43 0.35 0.43 0 .4 3 0.43 0.43 0.43 0.43 0.43 0.43 5370.6 5348.4 5355.6 5352.0 5349.6 5349.0 5336 . 4 5334.6 5332.2 5323.2 5308.2 5311.2 5327 . 4 5305.2 5311.8 5316 . 6 5329.8 5338 .8 5350.2 5320.S 5311.2 531S.4 5292 . 6 5300.4 5337.6 5313.0 529 2 .0 5311.2 5301.6 5308.2 5325.6 5335.8 5326 . 2 5322 . 0 5302.8 5298.6 5289.0 5304.6 5292 . 6 5313.0 106.5 105.3 105 .2 105.7 103.5 104.3 104.7 103 . 7 102.8 103.8 102.2 101.5 102. 2 101.7 101.7 102.7 100.5

98 . 3 99.0 98.0 97.5 98.0 97 . 7 96 . 5 98.5 97.3 97.2 96. 7 97 . 8 97.7 97.8 99.3 99.2 99 .2 97.5 93.S 92.2 93 . 2 92 . 3 95.0 

### 4>Summary

- I-Min RATA

- Continued G34-C 4>MW Lo

MW Lo 0-1 55 .**~** 5S .**~** 55 . S5. t 55. t 54 55.1 54. 55.1 54. : 54. : 54. : 55.1 54. : 54. : 54 . . 55.1 55 . 1 55.: 54. 54. 1 54. : 54. : 54. : S4 .. 54.1 S4.1 54 .. 54.! 54.: 54. 55.1 54.1 54.' 54.: 54.' 54.' 5 4. ' 53 54.' PagE

### Group#-Channel# Long Descrip . S hort Descrip. unit s Range 02/12/2013 12:55 02/12/2013 12:56 02/12/2013 12:57 02/12/2013 12:58 02/12/2013 12:59 02/12/201) 1):00 02/12/2013 13:01 02/12/2013 13:02 02/12/2013 13:03 02/12/2013 1):04 02/12/2013 13:05 02/12/2013 13:06 02/12/2013 13:07 02/12/2013 13:08 02/12/2013 13:09 02/12/2013 13:10 02/12/2013 13:11 02/12/2013 13:12 02/12/2013 13:13 02/12/2013 13:14 02/12/2013 13:15 02/12/2013 13:16 02/12/2013 13:17 02/12/2013 13:18 02/12/2013 13:19 02/12/2013 13;20 02/12/2013 13:21 02/12/2013 13:22 02/12/2013 13:23 02/12/2013 13;24 02/12/2013 13:25 02/12/2013 13:26 02/12/2013 13:27 02/12/2013 13:28 02/12/2013 13:29 02/12/2013 13:30 02/12/2013 13:31 02/12/2013 13:32 02/12/2013 13:33 02/12/2013 13;34 

### Date/Time Printed: G34-C4 G34

- Cll G)4

- C2 4>Stk NOx Stk NOx 4>Stk 02 4>NOx Mass ppm 0-150 3.1 2.9 2.B 3.0 2.7 2.B 2.G 2.7 2.B 2.5 2.G 2.5 2.5 2.4 2.5 2.5 2.5 2.4 2.5 2.3 2.5 2.4 2.4 2.4 2.3 2.2 2.2 loB loG loG l.5 1.7 1.7 l.7 loB loG loB 1.9 1.B 1.7 Stk 02 t 0-25 14.08 14.09 14.08 14.08 14.08 14.06 14.07 14 . 06 14.06 14.06 14.06 14.06 14.05 14.06 14.06 14.05 14. 

### as 14.06 14.06 14.06 14. 07 14.06 14 . 07 14 . 06 14. 07 14.07 14.06 14.07 14.07 14.07 14. 07 14.07 14. 07 14.06 14.06 14. 07 14.06 14 . 06 14.06 14 . 07 02/12/2013 17,44 NOx Mass Ib/hr 0

- 100 5.61 5.03 5.02 5.60 5.04 5.06 4.51 5.09 5.09 4.52 4.53 4.54 4.55 4.53 4.53 4.54 4.53 4.53 4.54 3 . 95 4.51 4.51 4.49 4.49 3.92 3.92 3.91 3.36 2.80 2.81 2.80 2.80 2.79 2.79 3.37 2.79 3.36 3.38 3.37 2.79 G)4-C20 4>StkFlow

StkFlow

kscfh 0-300000

14973 14953 14887 14936 14936 14964 15010 15048 15046 15036 15058 15098 15115 15080 15083 15085 15060 15058 15103 15008 15011 14998 14964 14941 14934 14919 14877 14916 14939 14964 14911 14902 14874 14832 14936 14880 14896 14969 14951 14891 G34-C3 4 > Stk CO

Stk CO ppm 0

- 1000

0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.5 0.5 0.5 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 G34

- C13 G34 -CI0 G34

- C6 4>CO Mass 4>NOx Rate 4>Stk NOXc

CO Mass lb/hr 0-100 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 NOx Rate Ib/mmBtu 0-1 0.010 0.009 0.009 0.010 0.009 0.009 0.008 0.00 9 0.009 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.007 0.008 0.008 0.008 0.008 0.007 0.007 0.007 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.006 0.006 0.006 0.005 stk NOXc ppm 0

- 300 2.68 2.51 2.42 2.60 2.34 2.42 2.25 2.33 2.42 2.16 2.24 2.16 2.15 2.07 2.16 2.15 2.15 2.07 2.16 1. 98 2.16 2.07 2.07 2.07 1. 99 1. 90 1. 90 1. 55 1. 38 1. 38 1.30 1.47 1.47 1.47 1. 55 1. 38 1. 55 1. 64 1. 55 1. 47 G34-C7 G34-C8 4>Stk COc 4>Gas Flow

Stk COc Gas hscfh ppm hscfh 0-1000 0-10000 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.35 0 . 35 0.35 0.35 0.35 0.34 0.35 0.35 0.34 0.34 0.35 0.35 0.35 0.35 0.35 0.35 0 . 35 0.35 0.35 0.43 0.43 0.43 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0 . 35 0 . 35 0.35 5342.4 5327.4 5311.8 5329.2 5329.2 5355.0 5363.4 5385.0 5384.4 5380.8 5388.6 5403.0 5416.8 5396.4 5397.6 5406.0 5397.0 5388.6 5404.8 5370.6 5364.0 5367.0 5347.2 5346.6 5336.4 5331.0 5323.8 5329.8 5338.2 5347.2 5328.0 5325.0 5314.8 5307.6 5344.8 5317.2 5330.4 5356.8 5350.2 5320.8 G34 -C18 4>NH3 Inj NH3Inj

Ib/hr 0-200 95.0 94.7 96.0 95.5 96.2 99.3 97.3 100 . 0 100.0 101.5 100.8 101.7 103.3 102.3 102.8 103.0 103.0 102.8 103.8 102.0 102.5 102.5 101.7 100.2 101.0 100.3 103.0 108.2 108.7 110.2 109.3 108.0 106.7 108.5 106.8 107.7 107.5 107.0 108.5 107.2 

### 4>Summary

- I-Min RATA

- Continued G34-C 4 >MW La

MW Lo

0-1 55. ( S5.: 55.( 54. : 54.: 55.: 55 .. 55 . 55 55. ! 55. : 55. 56.: 55 .. 56.: 55 .. 55 .. 55 .. 55 .. 55 .. 55. : 55 . . 54 .. 55. ( 55. ( 54 .. 54.: 54 .. 55. ( 55. ( 54. ! 54 .. 54. 54. ( S4 .. 54. 55. ( 55 .. 54. 54 pagE

### Gr o up#-Channel# Long Descr i p . Short Descrip . units Range 02/12/2013 13:35 02/12/2013 13:36 02/12/2013 13:37 02/12/2013 13:38 02/12/2013 13:39 02/12/2013 13:40 02/12/2013 13:41 02/12/2013 13:42 02/12/2013 13:43 02/12/2013 13:44 02/12/2013 13:45 02/12/2013 13:46 02/1 2 /2013 13:47 02/12/2013 13 : 48 02/12/2013 13:49 02/12/2013 13:50 02/12/2013 13:51 Q2/12/2013 13:52 02/12/2013 13:53 02/12/2013 13:54 02/12/2013 13:55 02/12/2013 13:56 02/12/2013 13:57 02/12/2013 13:58 02/12/2013 13:59 02/12/2013 14:00 02/12/2013 14:01 02/12/2013 1 4 :02 02/12/2013 14:03 02/12/2013 14:04 02/12/2013 14:05 02/12/2013 14:06 02/12/2013 14;07 02/12/2013 14:08 02/12/ 2 013 14:09 02/12/2013 14:10 02/12/2013 14:11 02/12/2013 14:12 02/12/ 2 013 14 : 13 02/12/2013 14 : 14 

### Date/Time**P~inted:** G34-C4 G3 4 -C11 G34 -C20 G34 -C2 4>Stk NOx

Stk NOx ppm 0-150 4>Stk 02 4>NOx Mass 4>StkFlow

1.7 1.8 1.8 1.8 1.9 1.9 2.0 1.8 1.8 2.0 1.9 1.9 1.9 2.1 1.9 1.9 1.9 2.0 2.1 1.9 1.8 1.8 1.8 1.8 1.8 1.8 1.9 1.9 1.8 1.9 1.9 1.9 1.9 1.9 1.9 2.0 2.0 1.8 1.6 1.6 Stk 02 % 0-25 14 . 07 14.07 1 4 .07 14 . 06 14.06 14.06 14.06 14 . 07 14.07 14.07 1 4. 07 14.07 14.07 14 . 07 1 4 .07 14.07

. 14.07

14.06 14.05 14 . 05 14.05 14.04 14.04 14.04 14.04 14.04 14.03 14.02 14.03 14.03 14 . 04 14.0 4 14.05 1 4 .05 14.05 14.05 14.05 14.04 14.05 14.04 

### 02/12/2013 17,44 NOx Mass lb/hr 0-100 2.78 3.35 3 . 35 3.35 3.36 3.35 3.35 3.34 3 . 34 3.33 3.33 3.34 3 . 34 3.90 3.34 3.34 3.36 3.36 3 . 94 3.39 3.39 3.40 3.40 3.38 3.39 3.38 3.39 3.40 3.40 3.39 3.37 3.36 3.36 3.36 3.35 3.35 3.37 3.36 2.81 2.81 StkFlow kscfh 0-300000

14810 14864 14889 1 4 857 1488 4 14880 14880 14825 14820 14805 14796 14832 1 4 827 14833 14835 14845 14917 14897 149 4 6 15011 15026 15034 15034 14934 14976 14934 14964 15007 15004 14972 14921 14867 14896 14860 1 4 839 14845 14921 14869 14907 14916 G34-C3 G3 4 -C13 G34-C10 G34-C6 G34-C7 G3 4 -C8 G34 -C18 G34

- C 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NO X c 4>Stk COe 4>Gas Flow 4>NH3 Inj 4>MW Lo Stk CO ppm 0-1000

0.5 0.4 0.5 0.4 0.4 0.4 0.4 0.5 0.5 0.5 0.5 0.5 0 . 5 0.5 0.4 0.5 0.4 0.4 0.4 0.4 0. 4 0.4 0.4 0.4 0. 4 0.4 0.4 0.4 0.4 0.4 0.4 0 . 4 0. 4 0.4 0 . 4 0.4 0.4 0.4 0.4 0.4 CO Mass lb/hr 0-100 0.56 0.56 0.56 0.56 0.56 0 . 56 0.56 0.56 0 . 56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.56 0.56 0.56 0 . 56 0.57 0 . 57 0.57 0.56 0 . 56 0.56 0.56 0 . 56 0.56 0.56 0.56 0.56 0.56 NOx Rate lb/mmBtu 0-1 0.005 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 0 . 006 0 . 006 0 . 006 0 . 006 0.006 0 . 007 0 . 006 0.006 0.006 0.006 0.007 0.006 0.006 0 . 006 0 . 006 0 . 006 0.006 0.006 0.006 0.006 0 . 006 0 . 006 0 . 006 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.005 0.005 stk NO X e ppm 0-300 1.47 1. 55 1. 55 1. 55 1. 64 1. 64 1. 73 1. 55 1. 55 1. 73 1. 64 1. 64 1. 64 1. 81 1. 64 1. 64 1. 64 1. 73 1. 81 1. 64 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 63 1. 63 1. 55 1. 63 1. 63 1. 63 1. 64 1. 64 1. 64 1. 72 1.72 1. 55 1.38 1. 38 Stk COe Gas ppm hsefh hsefh 0-1000 0.43 0.35 0.43 0.35 0.35 0.35 0 . 35 0 . 43 0.43 0.43 0.43 0.43 0 . 43 0 . 43 0.35 0 . 43 0.35 0.35 0 . 34 0.34 0.34 0.3 4 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.3 4 0 . 3 4 0.34 0.3 4 0.34 0.34 0.3 4 0.34 0 . 34 0.34 0.34 0-10000 5292 . 0 5311.2 5320.2 5316.6 5326.2 5325.0 5325.0 5297 . 4 5295.6 5290.2 52B7.2 5299.B 529B.O 5300.4 5301.0 5304.6 5330.4 5331.0 5356.2 5379.6 5385 . 0 5395.B 5395.B 5359.B 5374.8 5359 . 8 537B.4 5401.8 5392. B 5381.4 5355.0 5335.B 5338 . 2 5325.6 5317. B 5320.2 5347.2 5336.4 5342.4 5353.2 NH3Inj lb/hr 0-200 104.8 105 . 0 106.7 105.5 105.2 106 . 7 104.7 105.5 103.2 103.2 104.5 103.2 103 . 7 104.3 103.5 103.7 104.2 104.2 104.2 109.2 109.8 109 . 7 110 . 8 109.2 10B.7 107.5 108 . 5 108.B 109 . 2 108.3 10B.3 106 . 8 106.2 106.3 104.8 104.7 106 . 8 109.8 110.B 110.3 

### 4>Summary

- l-Min RATA

- Continued MW Lo 0

- 1 54. 55. c 54 .. 54. : 54. : 54 .. 54. : 54. c 54. c 54. : 54.: 54 .. 54. c 54 . . 5 4 . 54.: 55. c 5 4 .. 5 4 . : 55 .. 55 .. 55 .**~** 55. : 55 . 55. 55. ! 55. ! 55 .. 55. 55 .. 55 .. 54 .. 55. : 54. : 54. : 5 4 . : 54 . : 55.: 55 . . 55 . . pagE

### Group#-Channel# Long Descri p. Short Descrip . Uni t s Ran ge 02/12/2013 14:15 02/12/2013 14:16 02/12/2013 14:17 02/12/2013 14:18 02/12/2013 14:19 02/12/2013 14:20 02/12/2013 14:21 02/12/2013 14;22 02/12/2013 14:23 02/12/2013 14:24 02/12/2013 14:25 02/12/2013 14:26 02/12/2013 14 : 27 02/12/2013 14:28 02/12/2013 14:29 02/12/2013 14:30 02/12/2013 14:31 02/12/2013 14:32 02/12/2013 14:33 02/12/2013 14:34 02/12/2013 14:35 02/12/2013 14:36 02/12/2013 14:37 02/12/2013 14:38 02/12/2013 14:39 02/12/2013 14:40 02/12/2013 14:41 02/12/2013 14:42 02/12/2013 14:43 02/12/2013 14:4 4 02/12/2013 14:45 02/12/2013 1 4 :46 02/12/2013 14:47 02/12/2013 14:48 0 2 /12/2013 14:49 02/12/2013 14 : 50 02/12/2013 14:51 02/12/2013 14:52 02/12/2013 14:53 02/12/2013 14:54 

### Date/Time Printed: G34 -C4 G34 -C11 G34-C20 G34-C2 

### 4>Stk NOx

Stk NOx 4>Stk 02 

### 4>NOx Mass 4>StkFlow 

### ppm 0-150

1.6 1.6 1.6 1.7 1.7 1.7 1.8 1.7 1.8 1.7 1.7 1.8 1.8 1.7 1.8 1.8 1.9 1.9 1.9 2 . 0 1.8 1.9 1.9 1.9 1.9 1.9 1.8 1.8 1.8 1.7 1.8 1.8 1.8 1.9 1.8 1.8 1.9 1.8 1.9 1.8 

### Stk 02 

# • 0-25 14.05 14 . 04 14.04 14 . 03 1 4. 0 4 14.04 14.03 14.04 14.04 14.04 14.04 14.04 14.04 14 . 04 14.04 14 . 03 14 . 04 14.04 1 4 .04 14 . 03 14.03 14 . 04 14.05 14.05 14.05 14.05 14.04 14.05 14 . 04 14.05 14 . 04 1 4 .04 1 4 .04 14.04 14.0 4 14.04 14.03 14 . 03 14.03 14.03 02/12/2013 17,44 

### NOx Mass lb/hr 0-100 2.80 2.81 2.81 2 . 81 2.81 2.81 3.38 2.81 3.37 2.81 2.80 3.37 3.37 2.80 3.36 3.37 3.36 3.36 3.37 3.38 3.38 3.37 3.37 3.37 3.37 3.38 3 . 39 3.38 3.39 2.81 3 . 38 3.38 3.38 3.39 3 . 39 3.40 3 . 40 3 . 40 3.40 3.38 

### StkFlow kscfh 0-300000

14899 14937 14899 14906 14912 14929 14922 14892 14892 14887 14857 1 4887 14919 14864 14881 14877 14864 14852 14897 14936 14911 14901 14914 14912 14944 14956 14981 14981 1 4 974 14919 14949 14956 14947 14986 14993 15053 15016 15019 1502B 14931 G34 -C3 G34

- Cl3 G34-CIO G34-C6 G34 -C7 G34-C8 G34-C18 G34-C 

### 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH3 Inj 4>MW Lo Stk CO 

### ppm 0-1000

0.4 0. 4 0.4 0.4 0.4 0.5 0.4 0.4 0.4 0.4 0.4 0 .4 0.4 0.4 0.4 0.4 0.4 0.4 0 . 4 0.4 0.4 0.4 0.5 0.5 0.5 0.4 0.4 0.4 0.4 0 . 4 0.4 0.4 0.4 0. 4 0 . 4 0.4 0.4 0. 4 0.4 0.4 

### CO Mass 

### lb/hr 0-100 0.56 0.56 0.56 0 . 56 0.56 0 . 56 0.56 0.56 0.56 0 . 56 0 . 56 0.56 0.56 0.56 0.56 0 . 56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0 . 56 0.56 0.56 0 . 56 0 . 56 0.56 0.56 0.56 0 . 56 0.56 0.56 0.57 0.57 0.57 0 . 57 0.57 0.56 

### NOx Rate Ib/mmBtu 0-1 0.005 0 . 005 0 . 005 0.005 0.005 0.005 0.006 0.005 0 . 006 0.005 0.005 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 

### Stk NOXc 

### ppm 0-300 1. 38 1. 38 1. 38 1. 46 1. 46 1. 46 1. 55 1. 46 1. 55 1.46 1.46 1. 55 1. 55 1.46 1. 55 1. 55 1. 63 1. 63 1. 63 1. 72 1. 55 1. 63 1. 64 1. 64 1. 64 1. 64 1. 55 l.55 l. 55 1.46 1. 55 l. 55 l. 55 1. 63 1. 55 1. 55 l. 63 1. 55 1. 63 1. 55 

### Stk COc Gas hscfh ppm hscfh 0-1000 0-10000 0.34 5339.4 0.34 5361 . 0 0.34 5347.2 0.34 5357.4 0.34 5352.0 0 . 43 5358.0 0.34 5363.4 0.34 5344.8 0 . 34 5344.8 0.34 5343.0 0 . 34 5332.2 0.34 5343.0 0.34 5354. 4 0.34 5334.6 0.34 5340.6 0.34 5347.2 0.34 5334.6 0.34 5330.4 0.34 5346.6 0 . 34 5368 . 2 0.34 5359.2 0 . 34 5347 . 8 0.43 5344.8 0.43 5344.2 0.43 5355.6 0.34 5359.8 0.34 5376.6 0.34 0 . 34 0.34 0 . 34 0.34 0 . 34 0.34 0 . 34 0 . 3 4 0.34 0.34 0.34 0.34 5368.8 5374.2 5346.6 5365.2 5367.6 5364.6 5378.4 5380 . 8 5402.4 5397.0 539B.2 5401.2 5366.4 

### NH3Inj Ib/hr 0-200 110.2 110.2 1 1 1 . 7 110.0 110.2 109.5 109.3 109.2 107.7 10B . 5 107 . 7 107 . 3 108.7 107.7 106 . 7 108.3 106.8 104.8 105.8 106.0 106 . 8 106.0 105 . 0 105.5 105.3 106 . 8 108 . 0 108 . 5 109.0 108 . 8 108.3 10B . 2 106.8 108 . 2 107 . 7 108.8 107.3 108 . 3 10B . 2 105.8 

### 4>Summary

- I-Min RATA

- Continued MW Lo 0-1 55. : 55.1 55 55. 55. ; 55.1 55 . ( 55 . 1 54 .. 55.: 54. ! 54.: 55.: 54.: 54.: 55 . : 54.: 54.' 55.1 55.: 55.: 54.: 55. ' 54.: 55 . ' 55 . : 55. 55.1 55.1 54.' 54.: 55 . 1 55.: 55.1 55.: 55. ! 55 .. 55.! 55.' 55.: 

### Pag(

### Group#-Channel# Long Descrip. Short Descrip. Units Range 02/12/2013 14:55 02/12/2013 14:56 02/12/2013 14:57 02/12/2013 14:58 02/12/2013 14:59 02/12/2013 15:00 02/12/2013 15:01 02/ 1 2/ 2 013 15:02 02/12/2013 15:03 0 2 /12/2013 15:04 02/12/2013 15:05 02/12/2013 15:06 02/12/2013 15:07 02/12/2013 15:08 02/12/2013 15:09 02/12/2013 15:10 02/12/2013 15:11 02/12/2013 15:12 02/12/2013 15:13 02/12/2013 15:14 02/12/2013 15:15 02/12/ 2 013 15:16 02/12/2013 15:17 02/12/2013 15:18 02/12/2013 15:19 02/12/2013 15:20 02/12/2013 15:21 02/12/2013 15:22 02/12/2013 15:23 02/12/2013 15:24 02/12/2013 15:25 02/12/2013 15:26 02/12/2013 15:27 02/12/2013 15:28 02/12/2013 15:29 02/12/2013 15:30 02/12/2013 15:31 02/1 2 /2013 15:32 0 2 /12/2013 15:33 02/12/2013 15:34 

### Date/Time Printed: G34 -C4 G34-Cl1 G34-C2 4>Stk NOx

Stk NOx 4>Stk 02 4>NOx Mass 

### ppm 0-150

1.9 1.9 2.0 1.8 1.9 2.0 1.9 1.9 2.0 2.1 2.0 2.0 2.0 2.0 2.0 1.8 1.8 1.7 1.8 1.8 1.8 1.8 1.9 1.8 1.7 1.9 1.8 1.9 1.9 1.8 1.9 1.9 1.9 1.9 1.8 1.9 1.9 2.0 1.9 2.0 stk 02 

# • 0-25 14.03 14.03 14.03 14.03 14 . 05 14.05 14.05 14. OS 14.05 14.04 14.04 14.05 14.04 14.04 14.03 14.03 14.02 14.02 14.02 14.03 14.03 14.03 14 . 03 1 4 .03 14.03 14.02 14.03 14.02 14.03 14.03 14.03 14.03 14.03 14.02 14 . 03 14.03 1 4 .03 1 4. 03 14 . 03 14.03 02/12/2013 17,44 NOx Mass 

### 1b/hr 0-100 3.39 3.39 3.40 3.37 3.37 3.38 3.36 3.36 3.37 3.95 3.39 3.38 3.38 3.39 3.39 3.38 3.40 2.82 3.37 3.37 3.38 3.39 3.41 3.40 2.82 3.42 3.42 3.41 3.42 3.42 3.41 3.40 3.41 3.42 3.39 3.38 3.39 3.38 3.38 3.38 G34-C20 4>StkFlow

StkF!ow

kscfh 0

- 300000

14964 14981 15012 14891 14926 14963 14870 14877 14934 14991 14993 14971 14966 15008 14971 14939 14972 14914 14861 14884 14936 14989 15038 15006 14954 15076 15089 15059 15096 15094 15054 15031 15038 15072 14984 14936 14964 14937 14911 14936 G34 -C3 4>Stk CO

Stk 

### co ppm 0-1000

0.5 0.4 0.4 0.4 0.5 0.4 0.5 0.5 0.5 0.5 0.4 0.5 0.5 0.4 0.4 0.5 0.5 0.5 0.5 0.5 0.5 0.4 0.5 0 . 4 0.4 0.4 0.4 0.4 0.4 0.4 OA 0.4 0.4 0.4 0.4 0.4 0.4 0 . 5 0 . 5 0.5 G34-C13 G34-CI0 G34-C6 4>CO Mass 4>NOx Rate 4>Stk NOXc



### CO Mass 

### 1b/hr 0-100 0.56 0.57 0.57 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.56 0.56 0.57 0.57 0.56 0.57 0.56 0.56 0.56 0.56 0.57 0.57 0.57 0.56 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.56 0.56 0.56 0.56 0 . 56 NOx Rate 

### Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXc 

### ppm 0-300 1. 63 1. 63 1. 72 1. 55 1. 64 1. 72 1. 64 1. 64 1. 72 1. 81 1. 72 1. 72 1. 72 1.72 1.72 1. 55 1. 54 1.46 1. 54 1. 55 1. 55 1. 55 1. 63 1. 55 1. 46 1. 63 1.55 l. 63 1. 63 1.55 1.63 l. 63 1. 63 1. 63 1. 55 1. 63 1. 63 1. 72 1. 63 1. 72 G3 4 -C7 G34

- C8 4>Stk 

### CDc 4>Gas Flow stk 

### CDc Gas hscfh 

### ppm hscfh 0-1000 0-10000 0.43 0.34 0.34 0.34 0.43 0.34 0 . 43 0 . 43 0.43 0.43 0.34 0.43 0.43 0.34 0.34 0.43 0 . 43 0.43 0.43 0.43 0.43 0.34 0 . 43 0.34 0.34 0.34 0.3 4 0.3 4 0.34 0.34 0.34 0.34 0.34 0.34 0.3 4 0.3 4 0.34 0.43 0.43 0. 4 3 5378.4 5384.4 5395.8 5352.0 5349. 

## a 5362.2 5329.2 5331. 6 5352.0 5380.2 5380.8 5365.2 5371.2 5386.2 5380.8 5369.4 5389.2 5368.2 5349.0 5349.6 5368.2 5387.4 5404 . 8 5393.4 5374.8 5426.4 5423.4 5420.4 5425.8 5425.2 5410.8 5402.4 5404.8 5425.2 5385.6 5368.2 5378.4 5368.8 5359.2 5368 . 2 G34 -C18 4>NH3 Inj NH3Inj



### 1b/hr 0-200 106.5 107.7 108.2 106.8 104.3 104.5 103.2 104.0 103.3 104.8 104.5 105.3 104.8 104.8 106.3 108.2 107.8 108.7 107.7 105.8 108.5 108.7 108.0 108.7 107.2 108.7 108.7 108.5 109.0 108.3 108.2 106.2 106.8 107.7 106.3 106 . 2 107.0 105.3 104.5 104.0 

### 4>Summary - I

- Min RATA

- Continued G34-C 4>MW 

### Lo

MW Lo

0-1 55. : 55. : 55. ! 54. : 54 .. 54. : 54 . 54. : 54. : 55 .. 55. 55 . : 54. : 55 .. 55.1 55 .. 55 .. 55.: 55.: 55. : 55 . . 55 .. 55. ! 55.: 55.: 56.1 56.: 55.' 55.' 55. ' 55. : 55. ' 55.: 56.1 55.1 55. ! 55. ( 55 . : 55 .. 55 . . 

### PagE

### Group#-Channel# Long Descrip . Short Descrip . Units Range 02/12/201) 15:35 02/12/2013 15:36 02/12/201) 15:37 02/12/2013 15:38 02/12/2013 15:39 02/12/2013 15:40 02/12/2013 15:41 02/12/ 2 013 15:42 02/12/2013 15:43 02/12/2013 15:44 02/12/2013 15:45 02/12/2013 15:46 02/12/2013 15:47 02/12/2013 15:48 02/12/2013 15:49 02/12/2013 15:50 02/12/2013 15:51 02/12/2013 15:52 

### Period Average Period Max Value Period Min Value - Period Totals = 

### Period 

### % Recovery

Date/Time Printed: G34-C2 

### 4>Stk NOx

Stk NOx 

### ppm 0-150

1.9 2.1 2.0 1.9 2.0 1.9 1.8 1.8 2.0 2.0 2.0 2.0 1.9 2.1 2.6 2.7 3.0 3.0 2.0 3.2 1.5 G34-C4 G34

- ell G34-C20 

### 4>Stk 02 

### 4>NOx Mass 4>StkFlow

Stk 02 

# • 0-25 14.03 14.03 14.03 14.04 14.04 14.04 14.04 14 . 04 14.04 14.04 14.04 14.03 14.04 14.03 14.03 14.03 14.02 14.03 14.06 14.13 14.02 

### NOx Mass 

### 1b/hr 0-100 3.38 3.96 3.38 3.37 3.38 3.39 3.39 3.37 3.39 3.38 3.39 3.39 3.38 3.95 4.52 5.07 5.11 5.12 3.60 5.61 2.78 

### StkFlow kscfh 0-300000

14946 14979 14906 14899 14949 14991 15013 14899 14974 14939 14971 14966 14939 14942 14959 14936 15011 15061 14959 15165 14796 G34-C3 G34 -CD G34-CIO G34-C6 G34

- C7 G34

- C8 G34

- C18 G34-C 

### 4>Stk CO 4>CO Mass 4>NOx Rate 4>Stk NOXc 4>Stk COc 4>Gas Flow 4>NH) Inj 

### 4>MW La



### Stk CO 

### ppm 0-1000

0.5 

### D.• D.• 0.5 0.5 0.5 

### D.• D.• D .• 0.5 

### D.• D .• 0.5 

### D.• 0.5 0.5 0.5 

### D.• D .• 0.5 

### D.• CO Mass 

### 1b/hr 0-100 0.56 0.57 0.56 0.56 0.56 0.56 0.57 0 . 56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.56 0.57 0.57 0.56 0.57 0 . 55 

### NOx Rate 

### Ib/mmBtu 0-1 0.006 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007 0.008 0.009 0.009 0.009 0.006 0.010 0.005 

### Stk NOXc 

### ppm 0-300 1. 63 1. 80 1. 72 1. 63 1. 72 1. 63 1. 55 1. 55 1. 72 1. 72 1. 72 1. 72 1. 63 1. 80 2.23 2.32 2.57 2.58 1. 74 2.77 1.30 

### Stk COc Gas hscfh 

### ppm hscfh 0-1000 0-10000 0.43 5371.8 0.34 5383.8 0.34 5357.4 0.43 5347.2 0.43 5365.2 0.43 5380.2 0.34 5388.0 0 . 34 5347.2 0.34 5374.2 0.43 5361.6 0.34 5373.0 0.34 5379.0 0 .43 5361.6 0.34 5370.6 0.43 5376.6 0.43 5368.2 0.43 5403.0 0.34 5413.2 0.37 5354.1 0.43 5426.4 0.34 5271.0 NH3Inj 

### 1b/hr 0-200 105.0 106.2 105.5 104.8 105.3 106.8 106.8 105.7 107.0 105.3 105.7 107.3 103.5 103.7

97.8 97.8 98.8 99.3 105.0 112.2

92.2 

### MW Lo 0-1 55.: 55. : 55. : 5'. 54. : 55 .. 55 .. 55 55 55.1 55.

- 55. 55.: 55.: 54.: 55.1 55. 56.1 55.0

56. 53. 4.9940E+2 3.4865E+3 8 . 9270E+2 3.7099E+6 1.0730E+2 1.3942E+2 1.5880E+0 4.3087E+2 9.2360E+1 1.3278E+6 2.6040E+4 1.3658E+

- 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

02/12/2013 17 : 44 

### 4>Summary

- I-Min RATA

- Continued PagE

## Appendix B.2 Fuel Analysis Data



## R041 0688 8-6

# 5aybolt A [ORC L AlORATORICS (I"'AIIY 

### SAY BOLT LP 2 173 0 S . Wilmin gto n Av e nu e Suite 201 Cars on , CA 90810 3 10- 5 18-4400 Tel e ph o ne 3 10- 5 18-44 5 5 Fac s imil e 

# F ast To The P oint 

# S ayboIt LP Certificate of Analysis DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 Report Date : Job No : Sample Number : Client Ref : Test 2/ 27/2013 

## 13091-00008630 1300169-01 Sentinel 

## Refinery Gas Analys i s Hydrogen Carbon Dioxide Carbon Mono x ide Nitrogen Oxygen Methane Ethylene Ethane Propane Propylene Isobutane n-Butane 1-Butene Isobutylene t- 2 - Bute n e c -2 - Butene 1 , 3-Butadiene Isopentane n - Pentane Hexanes Plus Total Molar Mass Rat i o Relative Density Compressability Factor Gross Heat i ng Value (Dry-Ideal) Gross Heat i ng Value ( Dry-Real ) Gross Heat i ng Value (Wet-Ideal) Net Heating Value ( Dry-Ideal) Method ASTM 01945/ 01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945101946 ASTM 01945/ 01946 ASTM 01945/01946 ASTM 01945/01946 ASTM 01945 / 01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01 94510194 6 ASTM 01945/ 01946 ASTM 01945101946 ASTM 01945101946 ASTM 01945101946 ASTM 01945/ 01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945101946 ASTM 01945101946 ASTM 0- 3588 ASTM 0- 3588 ASTM 0 -3 588 ASTM 0- 3588 ASTM 0-3588 ASTM 0 - 3588 ASTM 0- 3 588 Oate Sampled : 2/22/ 2013 

## Product: Location : Sample 10 : Vessel : Result

<0
. 001 0.469 < 0
. 001 2
. 634 0.038 92
.299 <0.001 3
. 904 0
. 51 3 <0
. 001 0
. 032 0
. 069 < 0
. 001 < 0
. 001 < 0
. 001 < 0
. 001 < 0
. 001 0
. 016 0.014 0
. 011 99.999 0
. 59574 0
. 59787 0
. 996 1019 1023 1002 918 Natural Gas Location 4 Sample #S4 / Fuel Sulfur - 1A U n its mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole % mole% mole %

BTU/ cf BTU/cf BTU/ cf BTU/ cf Issuer warrants that il has exercised due diligence and care with respect 10 the information and professiORlI judgments embodied in this report. This report reflects only the findings Bllhe time and place ofinspccrion and testing
. Issuer expressly disc::laims any**furth~** indemnity of any kind
. This report is not a guarantee or policy of insurance with respect to Ihe goods o.-Ihe conlfactual penonllance of any party . Any person relying upon this report should be aware that issuer's activities are carried OUT under their general terms and conditions
.

. !' "Precision parameters apply in the evaluation of the test resuhs specified above
. Please also refcr to ASTM 0J244 (except for analysis of RFG) and I P 367 with respect to the utili1.ition ofthe test data to determine confonnance with specifications
. " 

### Page 1 of 6

### SAYBOLT LP 21730 S. Wilmington Avenue Suite 20 I 

# Fast To The Point 

# 5aybolt A (ORE LABOIIATOHltS CD M PA NY 

### Carson , CA 90810 310-518-4400 Telephone 310-518-4455 Facsimile 

# Certificate of Analysis DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 

# Saybolt LP

Date Sampled : 2/22/2013 

## Report Date : 2/27/2013 

## Job No: 13091-00008630 Sample Number : 1300169-01 Client Ref: Sentinel Test Refinery Gas Analysis Pressure Base Ethylene Ethane Propane Propylene Isobutane n-Butane 1-Butene Isobutylene t-2-Butene c-2-Butene 1,3-Butadiene Isopentane n-Pentane Hexanes Plus Total Carbon Hydrogen Nitrogen Oxygen Gross Heating Value Fuel Factor (FO) Average Molecular Weight Sulfur Speciation Hydrogen Sulfide Carbonyl Sulfide Sulfur Dioxide Methyl Mercaptan Product: Location : Sample 10 : Vessel : Method Result ASTM 0-3588 14
. 696 ASTM 0-3588 <0.001 ASTM 0-3588 1042 ASTM 0-3588 0
. 141 ASTM 0-3588 <0.001 ASTM 0-3588 0.010 ASTM 0-3588 0
. 022 ASTM 0-3588 <0.001 ASTM 0-3588 <0.001 ASTM 0-3588 <0
. 001 ASTM 0-3588 <0.001 ASTM 0-3588 <0.001 ASTM 0-3588 0
. 006 ASTM 0-3588 0.005 ASTM 0-3588 0.004 ASTM 0-3588 1
. 230 ASTM 0-3588 71.536 ASTM 0-3588 23.246 ASTM 0-3588 4
.278 ASTM 0-3588 0.941 ASTM 0-3588 22018 ASTM 0-3588 8822 ASTM 0-3588 17
.25 AQMO 307/ASTM 05504 <0.1 AQMO 307/ASTM 05504 <0
. 1 AQMO 307/ASTM 05504 <0.1 AQMO 307/ASTM 05504 <0.1 Natural Gas Location 4 Sample #S4/Fuel Sulfur - 1A Units psi GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM wt% wt% wt% wt% BTU lib SCF/mm BTU
ppm v/v ppm v/v ppm v/v ppm v/v

. Issuer warrams that it has exercise<:! due diligence lind care with respect to the information and professional judgments embodied in this report . This report reflects only the findings at (he lime and place 

### or inspection

and testing. Issuer expressly disclaims any further indemnity of any kind. This report is not a guarantee or policy of**inS\lranc~** with respect to the goods or Ihe contractual performance of any party. Any person relying o.lpon this report should be aware that issuds activities afe carried out under their general terms and conditions "Precision parameters apply in the evaluation oflhe test results specified above
. Please alw r efer 10 ASTM D3244 (except for analysis of RFG ) and II' 367 wilh respect 10 the utilization of the te st data to determine conform a nce with specifications " 

### Page 2 of 6

### SAYBOLT LP 21730 S. Wilmingto n Av e nu e Suite 201 

# Fast To The Point 

# 5aybolt A [ORt L AIIDRATCR ICS C OMPANY 

### C ar son , CA 908 I 0 3 10- 5 18-4400 Te le phon e 3 10- 5 18-44 5 5 Facs im il e 

# Certificate of Analysis DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 

# Saybolt LP

Date Sampled : 

## 2 / 22/2013 Report Date : 

## 2/27/2013 Job No : 13091-00008630 Sample Number : 1300169-01 Client Ref : Sentinel Test Sulfur Speciation Ethyl Mercaptan Dimethyl Sulf i de Ca r bon Disulfide 2 - Propanethiol tert-Butyl Mercaptan 1-Propanethiol Thiophene Diethyl Sulfide n-Butyl Mercaptan Dimethyl Disulfide tetra-Hydro Thiophene n - Pentanethiol Diethyl Disulfide Tota l Unknown Mercaptan Total Reduced Sulfur Product: Location : Sample ID : Vessel : Method Result AQMD 307/ ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 307 /ASTM D5504 < 0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 307 / ASTM D5504 <0.1 AQMD 307/ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 30 7/ ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 <0
. 1 AQMD 30 7/ASTM D5504 <0
. 1 AQMD 307/ASTM D5504 0
. 1 AQMD 30 7/ASTM D5504 0
. 1

Approved 

## By: Natural Gas Location 4 Sample #S4 / Fuel Sulfur - 1A
Units ppm v /v ppm v /v ppm v/v ppm v /v ppm 

## v / v ppm 

## v/v ppm v/v ppm 

## v / v ppm 

## v / v ppm 

## v /v ppm 

## v/ v ppm 

## v / v ppm v/v ppm 

## v / v ppm v /v

Signature On File

Francine Hanby Laborato ry Manager

Issuer warrants that it has c1tcrci5l':d due diligence and care with respect 10 the information and profes siOlll.1 judgments embodied i n this rcpo« .**Thj~** report renects only the findings 81 th e lime and place of inspection and testing
. lswer expressly disclaims any further indemnity of any kind. This repon is no! a guarantee or policy of insunmce wi l h respect to th e goods or the conlraClu.1 performance of Bny pany Any person relying upon Lhi s report should be
..... 'aTC that issuers activities are carried 001 under their general terms and conditions

' "Prec,sion parameters apply in the evaluation of the lest results specified above
. Please also r e fer to ASTM D3244 (excepl for analysis of RFG) and IP 367 with respecl 10 lhe utilization oflhe lc,t data to determine coofonnancc: with specifications " 

### Page 3 016

# 5aybolt: A [OR E lABOIIATO JlI [S COMPA N Y 

### SAY BOLT LP 2 173 0 

### S. Wilmin g to n Avenue S uite 20 I Cars on . CA 90810 310-518-4400 Te leph o ne 3 10-518-4455 Fa cs imil e 

# F as t To The Point 

# Saybolt LP Certificate of Analysis DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 Report Date : Job No : Sample Number : Client Ref : Test 

## 2/27/2013 13091-00008630 1300169-02 Sentinel Refinery Gas Analysis Hydrogen Carbon Dioxide Carbon Monoxide Nitrogen Oxygen Methane Ethylene Ethane Propane Propylene Isobutane n-Butane 1-Butene Isobutylene t-2 - Butene c -2-Butene 1 , 3-Butadiene Isopentane n-Pentane Hexanes Plus Total Molar Mass Ratio Relative Dens i ty Compressability Fa ctor Gross Heating Value (Dry-Ideal) Gross Heating Value (Dry-Real) Gross Heating Value (Wet-Ideal) Net Heating Value (Dry-Ideal) Method ASTM 01945101946 ASTM 01945101946 ASTM 01945101946 ASTM 01945101946 ASTM 01945/ 01946 ASTM 01945/01946 ASTM 01945/01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945/01946 ASTM 01945/01946 ASTM 01945/ 01946 ASTM 01945101946 ASTM 01945101946 ASTM 01945/ 01946 ASTM 01945101946 ASTM 01945/01946 ASTM 01945101946 ASTM 01945101946 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 Date Sampled : 

## 2/22/2013 Product: Location : Sample 10 : Vessel : Result <0
. 001 0452 < 0
. 001 2
. 774 0
. 048 92
. 073 <0
. 001 3
. 957 0
. 531 < 0
. 001 0
. 038 0.084 <0.001 <0.001 <0
. 001 <0
. 001 <0
. 001 0.013 0.015 0
. 014 99.999 0
. 59701 0
. 59915 0
. 996 1019 1023 1002 918 Natural Gas Location 4 Sample #S4/ Fuel Sulfur - 1 B
Units mole% mole % mole % mole % mole% mole% mole% mole % mole % mole % mole % mole% mole% mole% mole % mole % mole % mole % mole% mole% mole %

BTU/cf BTU/cf BTU/cf BTU /cf Issuer warran t s that it his cilcrcised due diligence aoo care with respeclto the information and professional Judgmen ts embodied in this rcpon This reporl renew only the findings lIthe lime and place ofinspeaion and testmg . Issuer express ly disclaims any funh er i ndemni ty of any kind This repan is not II. guarantee or polity ofinsuTllnce with respect 1 0 the goods or the conlrKrual performance of any party Any pcrn!II relying upon this report should be aware that issuer's activities are carried OU1 under thelT gC1!ef1I1 terms 100 COfldilions**"~is.ion** parameters apply in the eva luation orlhe lest results specified above
. Please also refer 10 ASTM 01244 (extep l for analysis of RFG) and lP ]67 IVith resp«t to the utilization of the tesl data (0 determi l\e conform a nce with specifications
. " 

### Page 4 016

### SAYBOLTLP 21730 S. Wilmington Avenue Suite 201 

# Fast T o Th e P oint 

# 5 aybol t: Cars on , CA 90810 310-518-4400 Telephone 310-518-4455 Facsimile A [DII E LABDRATDRI[S COM.PANY



## DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N. CASE ORANGE , CA 92865 Report Date : 2/27/2013 Job No: 13091-00008630 Sample Number 1300169-02 Client Ref : Sentinel Test Refi n ery Gas Analys i s Pressure Base Ethylene Ethane Propane Propylene Isobutane n-Butane 1-Butene Isobutylene t-2-Butene c-2-Butene 1 , 3-Butadiene Isopentane n- Pentane Hexanes Plus Total Carbon Hydrogen Nitrogen Oxygen Gross Heating Value Fuel Factor (FO) Average Molecular Weight Sulfur Speciation Hydrogen Sulfide Carbonyl Sulfide Sulfur Dioxide Methyl Mercaptan 

# Ce rti f i cate of A n alysis

Date Sampled : Product: Location : Sample 10 : Vessel : Method Result ASTM 0-3588 14
. 696 ASTM 0 - 3588 <0
. 001 ASTM 0-3588 1
. 056 ASTM 0-3588 0
. 146 ASTM 0-3588 < 0
. 001 ASTM 0-3588 0.012 ASTM 0-3588 0
. 026 ASTM 0-3588 <0001 ASTM 0-3588 < 0001 ASTM 0-3588 < 0
. 001 ASTM 0-3588 < 0
. 001 ASTM 0-3588 < 0
. 001 ASTM 0-3588 0.005 ASTM 0-3588 0
. 005 ASTM 0-3588 0
. 006 ASTM 0-3588 1
.256 ASTM 0-3588 71.393 ASTM 0 - 3588 23
. 186 ASTM 0-3588 4496 ASTM 0-3588 0
. 926 ASTM 0-3588 21968 ASTM 0-3588 8823 ASTM 0-3588 17
. 29 AQMO 307/ASTM 05504 <0.1 AQMO 307/ASTM 05504 <0
. 1 AQMO 307/ASTM 05504 < 0.1 AQMO 307/ASTM 05504 <0.1 

# Saybolt 

# LP

2/22/2013 Natural Gas Location 4 Sample #S4/Fuel Sulfur - 1 B Units psi GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM wt% wt% w1 % wt% BTUllb SCF/mm BTU
ppm v /v ppm v /v ppm v/v ppm v/v Issuer warrants that it has e xercised due diligence and care with respect to lhe information and professional judgments embodied in this rcpoM. This report renecls only the fllldings allhe time and place of inspection and testing
. Issuer expressly disclaims any funher indemnity of any kind. This report is not a guarantee or policy of insurance with respect \0 the goods or**Ih ~**  conlraclU a l performanc e of a ny party . Any person relying upon this repon should b e aware that is s uer's activities are carried out under th eir general terms and conditiOils "Prec ision parameters apply in th e evaluation of the test results specified above
. Please also r e fer to AS TM D 324 4 (except for analysis of RFG) and IP 367 with respect to the utilizatio n of the test data to de tennine conformance with specificatiOllS" 

### Page 5 016

### SAYBOLT LP 21730 S . Wilmington Avenue Suite 20 I 

# F ast T o T he P oin t 

# 5 ayb(] l t: A [ORE**lAB~IIATnR[[S** COMPA N Y 

### Carson, CA 9 0810 3 10-518-4400 Telephone 3 10-518-4455 Fac s imil e 

# Ce rti f icate o f A n a lys is DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 

# Say b o lt 

# LP

Date Sampled : 2/22 /2013 Report Date : 2/27/2013 Job No: 1 3091-00008630 Sample Number : 1300169-02 Client Ref: Sentinel Test Sulfur Spec i at ion Ethyl Mercaptan Dimethyl Sulfide Carbon Disulfide 2-Propanethiol tert-Butyl Mercaptan 1-Propanethiol T hiophene Diethyl Sulfide n-Butyl Mercaptan Dimethyl Disulfide tetra-Hydro Th iophene n- Pentanethiol Diethyl Disulfide Total Unknown Mercaptan Total Reduced Sulfur Product: Location : Sample 10 : Vessel : Method Result AQMD 307/ ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0.1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0.1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ ASTM 05504 < 0
. 1 AQMD 307/ ASTM 05504 < 0.1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 < 0
. 1 AQMD 307/ASTM 05504 0
.2 AQMD 307/ASTM 05504 0
.2

Ap p roved By : Natural Gas Location 4 Sample #S4/ Fuel Sulfur - 1 B Units ppm v/v 

## ppm v/v 

## ppm v/v 

## ppm vlv ppm v /v 

## ppm v/v 

## ppm v/v 

## ppm v/v 

## ppm v/v 

## ppm vlv ppm v /v 

## ppm v/v 

## ppm v/v 

## ppm v /v 

## ppm v/v



## Signature On File

Francine Hanby Lab o ratory Manager

Issuer warrants that il has exercised duc diligence and care with respect to the information and professional judgments embodied in this report . This report reflects only the findings at the time and place of inspection and testing
. Issue r expressly disclaims any further indemnity of any kind
. This report is nOl a guarantee or policy of insurance with respect to the goods or the contractual performance of any party . Any person relying upon this report should be aware that is suer's activities are carried out under their general tenns and condition. "Precision parameters apply in the evaluation of the test results specified above_ Please also refer to AST M 03244 (e xcept for analysis of RFG) and IP 367 with respeer to the utilization of the test data to determine confonnance wi th specifications
. " 

## Pa ge 6 of 6

## APPENDIX C TEST DATA

R041 0688 

### C-1

## Appendix 

## C.1 Stratification and Preliminary Flow Rate Tests

R041 0688 

## C·2

## 12-POINT STRATIFICATION CHECK Gemma 4 

## 2/1112013 02 CO2 NOx CO Port Point % % ppm ppm S 3 13
. 18 4
. 56 3
. 14 1
. 50 S 2 13.18 4
. 56 3
. 02 1
. 89 S 1 13.13 4
. 59 3
. 03 1
. 84 E 3 13
. 15 4
. 58 3
. 15 2
. 03 E 2 13.19 4.55 3
. 01 2
. 75 E 1 13.19 4.56 2.76 2.51 

## W 3 13.19 4.55 3
. 28 3.11 

## W 2 13
. 19 4.56 3.30 2.98 

## W 1 13.18 4
. 56 3.28 2.81 N 3 13.20 4.54 3.32 301 N 2 13.22 4.53 3.43 2.72 N 1 13.21 4
. 54 3.50 2.83 Average 13.2 4
. 6 3
. 2 2
. 5 Maximum 13
. 2 4
. 6 3
. 5 3
. 1 Minimum 13
. 1 4
. 5 2
. 8 1.5 Maximum Differenl 0
. 1 0
. 0 0.4 1
. 0 Max Difference (% 0.4% 0
. 7% 13.4% 40.0% Criteria : If < 

## 10%, use single point. Action Taken : 12-point traverse used for RATA runs Runs in conjunction with NH3 test, use 12-point traverseRELATIVE ACCURAC Y TEST DATA AND WORKSHEET CPV Sentinel-4-CEMS-107-STRAT TEST CONSTANTS Station : CPV Sentinel Unit 4 Performed By : AA, SS, RM , JM Cp : 0 . 84 Tref : 68 'F Stack Area : 143 . 14 ft' Meter Y d : 0 . 992 METHOD 2 . 1 DATA dP Temp Vel. Point (in . H 2 O) sqrt(dP) ' F (Ips)

4 2 . 10 1 .4491 765 1 25 .73 3 2 .60 1 .6125 766 139 .96 2 2 .70 1 .6432 767 142 .68 1 2 .5 0 1 .58 11 766 137 .24 4 1 .60 1 . 2649 767 109 . 84 3 2 . 10 1.449 1 768 125.88 2 2 .20 1.4 832 767 128 . 79 1 1 .60 1 . 2649 766 109.79 4 1 .50 1 . 2247 764 106.22 3 1.40 1 . 1832 766 102 . 70 2 1 .80 1 . 3416 767 116 . 50 1 2 .40 1 .5492 766 134.47 4 1 . 60 1.2649 765 109 .75 3 2 . 10 1.4491 767 125 .83 2 2.20 1.4832 768 1 28 .85 1 2.40 1 .5 492 767 134.52 Average 2 .0294 1.4246 766.4 123 .67

Stack Flow Rate : 1 ,062.1 kwacfm Stack Flow Rate : 407 .8 kdscfm Dry Gas Meter Time Vol. T m( in) Tm(out) #/Matl. Start 5 1 5 . 560 70 67 H,O 68 67 H,O 70 68 Emply End 534 .976 71 68 SG U ne Rinse Total 19.416 68 .6 Total 

### NO . ppm NO . , ppm@ 15% O 2 NO. I blMMBtu NO .I b/hr CO ppm CO, ppm@ 15% O 2 CO Iblhr 0, % Stack Flow dscfh CT Fuel F low hscfh Turbine Wate r Injection gpm



## 011l1liRlrqulIl/1Y58MC8S 1845 N . Case Street Orange, California 92865 714-279 -6 777 CTLoad MW SCR NH3 Injection Iblhr NO, IblMMSCF CO IblMMBtu CO IblMMSCF TEST VARIABLES Start Date : 2/1 1 / 2013 Start/End Time : 9 :02 Load (MW)fReplicate# 107 Barom. Pressure : 29 . 64 Pstack: 2.40 Pstack: 29.82 MW: 28.05 METHOD 100 .1 DATA 

### 0, CO, Analyzer Range 20 10 Cal Gas Value 9 .98 4 .96 Pre-Test Direct Zero 0 . 1 1 -0 .02 Pre-Test Direct Span 10 .00 5 . 11 Pre-Test System Zero 0 . 17 002 P r

e-Test Svstem Soan 10 .35 5.05

Post-Test System Zero 0 .24 0 .0 6 Post-Test System Span 9 .88 5 .09 Post-Test Direct Zero 0 . 10 0 .01 Post-Test Direct Span 10 .04 5 . 12 Average 13 . 19 4 . 56 Corr. results 13 .07 4.45 Pre-test zero bias 0 . 3% 0.4% Pre-test span bias 1 . 7% -0 .6% Post-test zero b ias 0 . 7% 0 . 5% Post- test span bias -0 .8 % -0 . 3% Zero drift 0 .4% 0.4% Span drift -2 . 3% 0.4% METHOD 4 . 1 DATA Impingers End Start Diff . 824.1 683 .9 140.2 Meter Pressure : 660 . 8 660.0 0 . 8 580 . 8 580 . 1 0 . 7 Sample Votume: 974.4 968 .4 6 . 0 H 2 0 Vo l ume : 1 00 .0 -100 .0 Mo isture Content: 47 .7 RESULTS Ref. Meth CEMS Diff. Ditt . 

### % 3.22 2.90 0 .32 9 .8% 2.42 2 . 14 0.28 11 .7% 0 . 009 0 .008 0 .001 11 . 1% 9 .39 7.43 1 .96 20 .9% 2.55 2 . 70 -0 . 15
- 5 . 7% 1 .93 1 .97 -0.04
- 2 . 3% 4 . 54 4 . 11 0.43 9 .5% 1 3.07 12 .90 0 . 17 1 .3% 24,465,874 21,12 4, 000 3,341,874 13 . 7%



## - 8,841.4 

## -

-

# ~ - 

## -

- 

## - -

- 110 .0 

## - - 10 .62 0 .004 4 . 53 9 :35 STRAT "'9 "Hg Iblltrmole NO, CO 5 10 2 .52 9.47 0.Q1 -0 .01 2.54 9 .51 0 .01 -0.05 2.49 9.50

0 .03 -0 . 09 2 . 5 1 9.40 0 .03 0 .02 2 .5 1 9.47 3 . 18 2 . 50 3.22 255 -0.1% -0.4 % -1.0% -0 . 1% 0 . 1% -1 .0% -0 . 2% -D . 7% 0.4% ...().4% 0 .2% - 1 .0%

2 .0 iwg 19 . 151 dscf 2.251 se t

10 .5 %

Sentinel Un it 4 RATA.x ! s 2/15/2013

1:25PM

### Port Point Angle N 4 1 

### N 3 0 N 

## 2 3 N 1 

### 0 E 4 0 E 3 0 E 

## 2 1 E 1 0 S 4 

## 2 S 3 0 S 

## 2 0 S 1 1 W 4 3 W 3 

## 2 W 

## 2 0 W 1 Average 0.9 Average Angle 

## < 10 deg.? Yes No Points w/Reverse Flow? Yes Less Than 4 Points> 30 Deg.? Yes PASS

## FLUE GAS VELOCITY DATA AND WORKSHEET 

# CLIENT: 

# Cc rv1rri

## r4- 

# PERFORMED BY: 

# .Rf-l "I' -

# ~ \ 

# : 0 LOCATtpN:

# " <f dlq 

# 7 BAR. PRESSURE:

# ~.':t UNIT:-/' 

# 't STATIC PRESSURE:-,-,:-.C -f'-"""-i-',_y.L-
____ _ TEST DATE : 2 -' 

# 1/

- I ' ) 

# TC READOUT 

# 10:,--,,::-, ' "itf-'-'-...!..I...!./....:IJ-''---'G.5'''--
____ _ 

# TEST NUMBER: 

# ::> - 'i\r;rK- c'1(\"",,< - I<1)- ' \ 

# TC 

# 10: :-**. ~-**  

# ') LEAK CH EC K

# PRE~ 

# r" _c 

# POST
_ Y t- ,./ 

# P'TOT--:T==-U':::B:-::E:-C'=D=--:

# -;:1:""::::-'''''-q 17l 

# 9''1

-------

# ~P INDICATOR TYPE: 

# C/o -/c '

# ~ I PITOT TUBE COEFFICIENT:--..: C c- ) _' ..= :::',,-

' c:./

_ '
___ _

## ~P 

# INDICATOR 

# 10: / 7 - '.A_" " . \ 

# ZERO: 1'- , , . ( 

# LEVEL:-;,lt- " -,,

' C"'-c--' ) C-
__ _ j 

## Yaw Angle,**~P,** 

## Temperature, Time Port Point Degrees(1) inches H 2

## O 

# of I ) 

### :F' <t'**,** 

# hi Y**~** 

# \.5" fbo**~** 

# tJ 

# l , '-\ 

# I S-q 

# .2 3 L;? 1S"'j

J 

# ro '2.1\ '1 '\. \ \ , (0 """**~l "\.**  

# ( )**,~** 

# ..>'2 E 

# L/ 0 

# l. h**~'i.1** 

# 3 f) 

# z. . \ tb( 

# 2- l 1..2--- 7LI



# / tJ L(, 

# iQ' ..-9;;; artJ 'l 

# 5 2./ 

# L 

# 1 . \ fL:::'- 

# 3 (] 

# 2(. 

# 11;("'" 2 

# 0 

# 2- .1 1G .,



# f 

# I 2..
. -::, 

# , 'lick> ()'lI J 

## LA-.! 

# t/- 

# <, 

# 1.1. 

# 7y-s '3 2..... '2. \ 7?-.eJ 

# 2. b -Z ,.2.., 

# 1'(' l

J 

# \ 2.,,-\ 

# " 1)'''\

Comments: 1) Positive yaw angles correspond to clockwise rotation of the probe ,

Date of last revision 

## 11/13/08 DS834033 Master Document StoragelForms\DatasheetslField Datasheets

## WET CHEMICAL SAMPLING SYSTEM DATA AND WORKSHEET - STANDARD CLIENT : 

# 0.tf\k.AA LOCATION : 

## ';,5 wr:'VA DATE : 

# 2../ l, 

# I ,'S 

### RUN NO : ' 

# F.< --**/~** 

# / '-'**~** OPERATOR : 

## L-**'~ ./.7**  

### MET E R BOX NO : 

## '1 1",,1', '-"! METER L1 H@ : ", '" q 

# '7 METER Yd : 

# q, "**~** 

# ',,
_ STACK AREA
. FY: 

## i':f'? A,,\ 

### TRAVERSE POINTS. MIN/POINT: 2fib**L1 H=** **Ll P:**  

### Probe Condition
. pre l po s t test: --.-;J'--
__ _ Silica Gel Expanded
. Y I N: 

## tJ Filter Condition after Test:- -'/-- -- Check Weight:

### ~ Meter LI P Point 

### Time 

### Volume , ft ' in , H , O 

# 1 5 3 0701-.**~>.** 

### 5(;,0**~** t , 

## 2- 

## 0'/0,/ 

# , : . ,- f 

## d'lOL 

# - ' :!.. 

### '7 

## b 

## 8 109., :i 

### i c/ , &,)L , ! 

### 2 , \ 

# t: :;: ,)**~ll l** **5~'00b '1**  

### i, 

### C-

- -'2 

### t)q /3 

# , .c .' I 

### /**'if'** 

## s - '- 

### 2 . .2.. 

# a ,)</ ( 

## 7 <' "' V'. 1,:,, 'V I 

# i. ( , N "(**(J~** 

## J ,)**;..~:;.** of**1/-6** 

## ':- 

# " /, s- :;;a " (, ).- 'l- I 

## I , 

## </ I ,.0, j 'I**~** 

### / ' p, 

## U**~ "I'~**  

# v) : 52 ';. vb' i 

### .2 , , - / 

## iN ;'**~~J** 

# '?2 '1 1,,(, "" • 

### 116: 

## ;z, C Cj'1 1, 

# , ,J, . 

## I I 

# ,,' 1**?,~** 

### , 

## 21-- (J 

# ''I... L- 

### ;':1"-/ . 

## 17/"" ' 2, 

## </ AveraQe : AMBIENT TEMPERATURE : "7 

### 6 BAROMETRI C PRESSURE':-:

## -l-~----;;~a'1'--;-""'-i'-----**--** ASSUMED MOISTURE: 

## '\[.u , PITOT TUBE COEFF
. C:-p- :

### 1/,c'-**~. '-** **~""?'--"ll---- --**  PROBE ID NO/ MATERIAL : 

# ¥ &<ii¥ 

# 'f-YJ 5" 5 PROBE LENGTH : (? 

# r 7 - NOZZLE ID NO I 

### MATERIAL :7-j N ':'<0"'-

_______ _ NOZZLE DIAMETER :

_ -;J:- ' '' '','''

',,

'--

___ ____ _ FILTER NOfTYPE : 

# V(.' PRE-TEST LEAK R "' A"'T"'E;-: : "'

: 

## T

i**O- '-** **Q" -::** **''- ;-:** **-' C'''F=:M7@~** **--:-\**, - ----,i;-:n-., H 7 

### g- ,- POST-TEST LEAK RATE :**~Q ""**  

### 7,. CFM@ I c ±' n , H , PITOT LEAK CHECK - PRE : l.-- 

### POST : ' CHAIN OF CUSTODY : SAMPLE CUSTODIAN Imp , 

### # Contents Post -Test - Pre -Test = Differenc e



# , I AI 

# H J 

## lOLl 

## i?2<\ 

# I 

# c,,'b>.9 1- , lrV 

# f!, SO,! lsidJ, 

# '2l**~bO.()** 

# -**~** 

# ,fT 53b,o/"l 

# S 'bO·l

'-( 

# <; (7)**q(L(,~** 

# "fb'b. 

# '1 cL 

# H1, 

# U \(JU SAMPLER 

## R
.. SAMPLE CUSTODIAN =::::M: Total :

_ _ _ _ ___ _ __ ___ _ L1 H Sta c k Probe Filte r Imp , Out Meter Temp , 

### o f Vacuum 

## 0 , p , stati c in , H , O Temp
. 

### o f Temp
. 

### o f Temp
. 

### o f Temp
. 

### o f In Out in , Hg , 

### % in , H 2 

### O 

## Z ,D 7 (.:.**~** 

## 'X 

## tA 

# :;; e:; 70 

# : "-7 ¥ -(2 , 1.{' 

## .7 L <v 

### ''-' J**1~** 

### (, 

# :.:z . L ' 

### 7/1, 

## 7 

## 'I :A**~2-** 

### he. 

## £/ 

## </ ??> 

### 8' 

### ?tv'1 

### ' 7'" ;:, 

### .2, LC 

### 7<-- <I 

# "- Y 

# :; ' v-- 70> &;, (" -'I 

## q 7&(" :Jl
. 7 '7 

## c.' L



## A 0 7&- :; 

# -i I. -c,,( 

### 71 t" c)

### ~ 

### 7?- '/ ? (; 

## <-: ? c ' 

### -7
Comments :

____________________________________________________________________________________________________________________ __

Date of last revision 

### 1/25 / 2013 Page
__ of
__ 

### DS834049 Master Document Storage\ Forms\ Datasheets\ Field Datasheets

## Appendix C.2 CEM Data

R041 0688 C-3

## Appendix 

## C.2.1 CEM Quality Assurance Measurements

R041 0688 

## C-4

### Client: Gemma 

# DeltaAirQualilY SelViees CEMS PERFORMANCE DATA SHEET Location : CPV Sentinel Unit 4 Date: 2/11/2013 Performed By: AA, SS, RM, JM CEMS 10# : .:::5c..:-C::;E:;:M:.:.:S"--
__________ _ Analyzer : O 2 CO 2 NO, CO Manufacturer : AMI CAl CAl TECO Serial Number : 021119-3 W06004-M V10043 CM0490048 CEMS Probe: Material: S.S. Length: 8' Heated Line Material: Teflon Length: 6' Sample Conditioner : Type: Universal CEMS Line: Material: Teflon Length 200' Bias Line : Material: Teflon Lenqth 200' Upscale Response Time: 30 Downscale Response Time :

Sample Pressure (psi): 

## 6 TECO Vacuum (" Hg) : Sample Flow Rate: 8 SCFH S02



# --
Gas Temp : Gas Temp : Gas Temp :

30 NA 750 

## o f 285 

## o f 33 

## of

seconds

Sentinel Unit 4 CEMS QA 

### 2/21/2013 11:58AM

### Source Test Date AETB Name AETB Phone Number AETB e - mail QI Last Name QI First Name QI Middle Initial QI Exam Date Exam Provider E xam Contact Gemma CPV Sentinel Unit 4 

## 2

/11 / 201 3 Delta A i r Quality Services , Inc. 714-279 -6777 contact@deltaags
. com Aleshaiker Ali M November 21 , 2008 Source Evaluation Society gst i pro g ram @ gma ii.com

# D8/la Ai, 

# qualityServices SPAN GAS RECORD AND SCAQMD CALIBRATION ERROR/LINEARITY CLiENT/LOCATION: Gemma CPV Sentinel Unit 4 DATE: 2/11/13



### TRUC K/C EM I.D .:**~5~ C::.:E::::M::.:S::-**  

### __________ _ BY : AA , 

### SS , RM , JM Exp. Vendor 

## %01 Gas Cyl i nder # Value Date 10 

### Range ZERO Low CC93915 0
. 0 10/6/17 

### F220 12

O2 

### Mid CC72997 9.98 11 /16/ 15 

### F22012 49.9 % O2 

### High CC199067 1 8
. 90 4 / 4/15 

### F22012 94.5% CO 2 

### Mid CC72997 4
. 96 11 /16 /15 

### F22012 49 .6% CO 2 

### High CC199067 9
.62 4 / 4

/ 15 

### F22012 96
. 2% NO x 

### Mid CC7 352 2.52 12/10/ 15 

### F22 0 12 50.4% NO x 

### High CC362309 4 .8 2 5/2 4 114 

### F22012 96.4% N0 2 

### N0 2 

### CC11 340 4 402 7/9113 

### F220 1 3 80.4% CO Mid CC325462 4.49 2/20/ 1 3 

### F22 0 1 2 44 .9% CO High CC313840 9.47 8/16 / 1 5 

### F220 12 94
. 7% PRE-TEST I NSTRUMENT CALIBRATION ERROR ANALYZER O 2 

### CO 2 

### NO x 

### CO Analyzer Range 20 10 5 10 Zero Gas Value 0
. 0 0
. 0 0.0 0
. 0 Analyzer Reads 0
. 11 -002 0.01 - 001 Error (% 

### of sca l e) 0
. 5% -0.2% 0.2% -0.1%

High Gas Value 18
. 90 9
. 62 4
. 82 9.47 Analyzer Reads 18.86 9.71 4.79 9
. 51 Error (% 

### of scale) -0
. 2 % 0
. 9 % -0
. 6 % 0.4 %

Mid Gas Value 9
. 98 4
. 96 2
. 52 4.49 Analyzer Reads 10
. 00 5
. 11 2
. 54 4.52 Error (% of scale) 0
. 1 % 1
. 5% 0.4 % 0 .3% Linearity at Mid Point -0
. 1% 1
. 1 % 0
. 6% 0
. 2% POST-TEST INSTRUMENT CALIBRATION ERROR ANALYZER O 2 

### CO 2 

### NO x 

### CO Analyzer Range 20 10 5 10 Zero Gas Value 0
. 0 0
. 0 0
. 0 0.0 Analyzer Reads 0
. 10 0
. 03 0
. 02 0
. 12 Error (% of scale) 0
. 5 % 0
. 3% 0.4 % 1
. 2 %

High Gas Value 18
. 90 9
. 62 4.82 9.47 Analyzer Reads 19
. 09 9.73 4 .83 9
. 52 Error (% of scale) 1
. 0 % 1
. 1 % 0
. 1 % 0
. 5%

Mid Gas Value 9
. 98 4 .96 2.52 4.49 Analyzer Reads 10.05 5
. 14 2
. 53 4
. 60 Error (% of scale) 0
. 3% 1
. 8 % 0
. 2% 1
. 1 % Linearity at Mid Point -0.4 % 1
. 1 % -0.1% 0 .3% STATUS



## --

-- PASS



# --

-- PASS



# - -

-- PASS PASS

STATUS



# --

-- PASS



## -



# -- PASS



## --

-- PASS PASS Sentine l Un it 4 CE MS QA 31112013 11 :28 AM

# DellaAirQualllY Services SPAN GAS RECORD AND SCAQMD CALIBRATION ERROR/LINEARITY CLiENT/LOCATION: Gemma CPV Sentinel Un it 4 DATE : 

### 2/12/13

TRUCK/CEM LD .:**.:::5...::-C::::E:::M::.::S~**

### _________ _ BY : AA , SS , RM , 

### JM Exp . Vendor %of Gas Cylinder # Value Date 

### 10 Range ZERO Low CC93915 0.0 

### 10/6/17 F220 1 2



### O2 

### Mid CC72997 9.98 

### 11 /16/15 F22012 49 .9% 

### O 2 

### H i gh CC199067 18.90 

### 4/4/15 F220 12 94.5% 

### CO 2 

### Mid CC72997 4
. 96 

### 11 /16/ 15 F22012 49
. 6% 

### CO 2 

### High CC199067 9
. 62 

### 4 / 4

/ 15 F22012 96
. 2% 

### NO, Mid CC7352 2
. 52 

### 12/10 /15 F2 2012 50.4% 

### NO, High CC362309 4.82 

### 5 /2 4 1 14 F22012 96.4% 

### N0 2 

### N0 2 

### CC113404 4
. 02 

### 7/9113 F22 013 80.4% 

### CO Mid CC32 5462 4.49 

### 2/20/13 F22012 44
. 9% 

### CO High CC313840 9.47 

### 8/16/15 F220 1 2 94
. 7% 

### PRE -T EST INSTRUMENT CALIBRATION ERROR ANALYZER O 2 

### CO 2 

### NO, CO Analyzer Range 20 10 5 10 

### Zero Gas Value 0
. 0 0
. 0 0
. 0 0
. 0 

### Analyzer Reads 0
. 12 0.00 0
. 02 0.08 

### Error (% of scale) 0
. 6 % 0.0% 0.4% 0
. 8%



### High Gas Value 18
. 90 9
. 62 4.82 9 .47 

### Analyzer Reads 18.97 9
. 66 4.81 9.62 

### Error (% of scale) 0.4% 0.4 % -0
. 2% 1
. 5 %



### Mid Gas Value 9
. 98 4
. 96 2.52 4.49 

### Analyzer Reads 10.03 5.09 2.52 4
. 61 

### Error (% 

### of scale) 0 .2% 1 .3% 0
. 0 % 1.2% 

### Linearity at M i d Point -0.2% 1
. 1 % 0 .0% 0
. 0 % 

### POST-TEST INSTRUMENT CALIBRATION ERROR ANALYZER O 2 

### CO 2 

### NO, CO Analyzer Range 20 10 5 1 0 

### Zero Gas Value 0
. 0 0
. 0 0
. 0 0
. 0 

### Analyzer Reads 0 .11 0
. 1 3 000 0.05 

### Error (% of scale) 0
. 5 % 1
. 3% 0
. 0 % 0
. 5 %



### High Gas Value 18
. 90 9.62 4.82 9.47 

### Analyzer Reads 19.01 9.66 4.77 9.60 

### Error (% of scale) 0
. 5% 0.4% -0
. 9% 1.3%



### Mid Gas Value 9
. 98 4
. 96 2
. 52 4.49 

### Analyzer Reads 10
. 04 5.16 2.50 4
. 59 

### Error (% of scale) 0
. 3 % 2
. 0 % -0
. 5 % 1
. 0 % 

### Linearity at Mid Point -0.2% 1 .1% 0.0% 0
. 1 % 

### STATUS



## --

-- PASS



## --

-- PASS



## --

-- PASS PASS



### STATUS



# --

-- PASS



## --

-- PASS



## --

-- PASS PASS Sentinel Uni t 4 CEMS QA 3/ 1/20 13 11 : 29AM

### GAS Zero Zero NO NO N0 2 N0 2 

# DellaAilQuality SelViGes N0 2 

### to NO Converter Efficiency Test Analyzer Manufacturer: Analyzer Model : Analyzer Serial Number : Date : ANALYZER MODE

NO x 

### NO NO x 

### NO NO NO x



### Abs
. Value C O

### -C , : Abs
. Value C 2 -C , : 

## C, /C 2 

### CE 

# =D 2 

## /O, • 100%: Gemma CPV SentindIJOr1ilai Gas Value: 4.82 6 00CLD V10043 

### 2/11/13

4.0 3.9 0% 96% N02 Cal Gas Value : 4.02

ANALYZER RESPONSE 0 .01 0.01 4.82 4.82 0.02 3.87
Label

D, D2 

## D3 Performed By : AA CEMS ID# : 5-CEMS CAL CORRECTED LABEL

0.0 3.9 Requirement

<5% > 

### 90% C , C 2

Sentinel Unit 4 CEMS QA 

### 2/21/2013 11 : 59 AM

### GAS Zero Zero NO NO NO , NO , 

# D811aAirqualilY SI/MelJS NO, to NO Converter Efficiency Test Analyzer Manufacturer : Analyzer Model : Analyzer Serial Number : Date : ANALYZER MODE

NO, NO NO , NO NO NO,

Abs. Value C O

### -C , : Abs
. Value C , -C , : 

## C, / C

, CE 

## = Di D, • 100 %: Gemma CPV SentinEIIIOr1iJ:aI Gas Value : 4.82 600CLD V10043 

## 2/12/13

4
. 0 3
. 8 0% 96 % NO , Cal Gas Value : 4.02

ANALYZER RESPONSE 0.01 0.01 4.81 4
. 83 0.03 3.86
Label



## 0 , 0 , 0 3 

### Performed By : AA 

### CEMS 

## 10# : 5 - CEMS CAL CORRECTED LABEL

0
. 0 3.9 Requirement

< 5 % > 

### 90 % C , C ,

Sentinel Unit 4 CEMS QA 

## 2/21/2013 11 :59 AM

## Appendix C.2.2 NO

## x and CO Compliance

R041 0688 C-5COMPLIANCE TEST DATA A N D WORKSHEE T CPV Sen ti n el-4· CE M S · 100 - 1 TEST CONSTANTS Station : CPV Sentinel Unit: 4 Performed By: AA, SS, RM, JM Cp: 0.99 Tref: 60 

### ' F Stac k Area: 1 43.1 4 If Me ter Yd : 0.992 METHOD 2
. 1 DATA dP Temp Vel. Point (in
. H 2 O) sqrt(dP) 

### 'F (Ips)

4 1 .30 1.1402 767 116 . 53 3 1
.40 1
. 1832 7 68 120 . 98 2 1 .60 1.2649 768 129 . 34 1 1 .50 1 .2247 766 125 . 13 4 0 . 92 0 .9592 768 98 .07 3 0 .93 0 .9644 759 98
. 24 2 1
. 70 1 .3038 760 1 32 . 88 1 1 .60 1 .2649 762 129 . 02 4 0 .90 0 .9487 762 96 . 77 3 1 .30 1 . 1402 765 116.44 2 1
. 10 1 .0488 760 106 . 89 1 1
.40 1
. 1832 758 120.49 4 0
. 95 0.9747 760 99 . 34 3 1
. 50 1.2247 757 124.67 2 1 .70 1 .30 3 8 758 1 32.77 1 1
. 60 1 .2 64 9 7 6 0 128 . 9 1 Average 1
.3217 1
. 149 6 762.4 117
. 28

Stack Flow Rate : 1 , 007.2 kwacfm Slack Flow Rale : 383
. 0 kdscfm Ory Gas Meter Time Vol. T m( i n) T m( ou t ) N / Mal!
. Start 536
. 846 62 57 H , O 62 56 H , O End 582.187 61 55 Empty 63 57 

### SG Total 45
.34 1 59
. 1 Tota l

N O x ppm N O x , pp m @ 15% O 2 NO x I b/M M 8 t u NO x Ib/h r CO ppm CO , ppm@ 15% O 2 CO Iblhr O 2 % Stack F low dscfh CT Fue l F low hsct h Turb i ne Water I nject ion gp m



## 8,118A1,QuaIIlYSIIMcIIS 1845 N. Ca se Street Ora nge , Ca li fo rni a 

### 9 2865 7 14- 279 -6777 CTLoad MW SCR NH3 Injection Iblhr NO x Ib/ MMSCF CO I blMMBtu CO Ibl M MSC F TEST VARIABLES Start Date : 2/11 / 13 Start/End Time: 10 :06 11 : 19 Lo a d (MW)/Replicale# 100 1 Barom. P ressure : 29 .64 Pstack: P sta c k : M W: Analyze r R a n g e Cal Gas Value Pre-T est Direc1 Z e ro Pre-Test Direct Soan Pre-Test System Z ero Pre-Test System Span

Post-Test System Zero Post-Test System Span Post-Test Dire c t Zero Post-Test Direct Spa n Average Ca rr. resul t s P re-tes t zero bi a s Pre-test span b i as Post-test zero bias Post-test span bias Zero drift Span drift METHOD 4

_ 1 DATA I mpingers E n d Sta rt Di ff
. 3045 . 0 684 . 5 2360
. 5 666 .0 <;66 . 0 581
. 6 -58 1
. 6 899 . 6

-899 . 6 Ir 100 1 13.3 RESULTS Ref. Meth CE M S 3.02 2
. 70 2 .3 4 203 0.009 0.007 8.4 1 6
. 94 2.68 2.70 2 . 08 1
. 99 4.48 4
. 07 1 3
. 29 12
. 92 22 , 981 ,081 21 , 158,000



## - 8 ,830



## -

- 106



## - 110 9 .52 0 . 005 4 .90 3.40 iwg 29 .89 "Hg 28 .06 Ib/lb-mo l e METHOD 100
. 1 DATA 

### 0, CO, NO, CO 20 10 5 10 9 .98 4 . 96 2
. 52 9.47 0
. 10 0 . 01 0 .03 0 .02 10 .04 5 . 12 2 . 51 9.47 0
.24 0 . 06 0 .03 -0 . 09 9 .88 5 .09 2 . 51 9.40

0 .1 6 0 .0 3 0.Q4 0 .02 10
. 04 5 .08 2
. 53 9.50 0.10
- 0 .01 0 .03 0.01 10 . 03 5 , 1 0 2
.52 9.5 4 13 . 20 4
. 53 301 2.65 13
. 29 4.42 3.02 2.68 0 ,7% 0
. 5% 0.1% - 1 .0% -0
. 8% -0 .3 % -0
.2% -0.7% 0
.3% 0
. 3% 0
. 1% 0 , 1% 0
. 0% -0
.2% 0 .2 % -0.3% -0
.4% -0
.3% 0
. 2% 1
. 0% 0
. 8% -0
. 1% 0
. 5% 1
. 0%

Meter Pressure : 1
. 5 iwg Samp l e Volume : 44
. 795 dscf H 20 Volume : 5
. 267 scf Moisture Content: 10
. 5 %

S e n t inel Unit 4 100% NOx·NH3 - ROG Com p l i ance . x l s 2/ 1 5/2 013

1 : 54 P M3 2 4 3 2 1 4 3 2 1 4 3 2 Ave ra ge

Start End i Unit: Performed By : Cp : Tref : Stack Area : Meter

1 . 20 1 . 0954 1.40 1 . 1832 0 .92 0 .9592 0 .98 0 .9899 1 . 30 1 . 1402 1 . 70 1 . 3038 1.40 1 . 1832 0 .99 0 . 9950 1 .20 1 . 0954 1 . 10 1 . 0488 0 .90 0 .9467 0 . 91 0 .9539 0 . 97 0.9849 1 . 00 1 .0000 1 . 1170 1 .0569

583.299 61 63 631 . 745 61 4 M , SS , RM , JM 0 .99 60 o f 143 . 14 

### It' 0.992

766 766 765 766 767 768 767 766 766 766 765 766 767 767 766 . 1 COMPLIANCE TEST DATA AND WORKSHEET CPV Sentinel-4-CEMS-100-2

111 .62 120 .56 97 .69 100.87 116.22 1 32.96 120 .61 101 .38 111 .62 106 .87 96.63 97 .20 100 . 39 101.94 107 .69 Start Date : StarVEnd Time : Load (MW }/Repl i cate# 8aram . Pressure : Pstack : Pstack : MW:

bias 0 . 3% bias 0 . 0 % zero bias 0 . 4 % span b ias -0 . 1 % 0 . 1 %

#/Matl. End 2 /11 /13 11 : 40 100 29 .64 2.40 29.82 28.28

0 .3% -0 .2% 0.4 %

- 0 . 3 % 0 .0% -0 . 1%

57 H,O 674 .3 Pressure : 58 H , O 58 Empty

NO. ppm NO., ppm@ 1 5% O 2 N O. Ib/MMBlu NO . lblhr CO ppm C O, pp m @ 15% O 2 CO t blhr O2 % 661A 582 . 1

2.67 2.18 0 .008 7 .46 2 .00 1 .52 3 . 11 13.15 660 .8 581 . 8

2 . 70 2 .01 0 .007 6 . 66 2.30 1 . 72 3 .47 12 .90 0 . 3 Content 1 2 :54 2 i wg "Hg Ibllb-mole

0 . 1% 0 . 1% 0 .2 % - 0 . 3% 0 .2 % -0 .1% 0 . 1 % - 0 .6% 0 .0 % -0 . 1% -0 . 1%

1 .5 iwg 47 . 828 dscf 4.463 scf

8 .5 %

Turbine Water In jection 9pm



## 8,1tJI AllQualityS,lVIe" 1845 N. Case Street Orange, California 92865 714-279 -6777 CT load MW I N O . IblMMSCF 8 .42 CO I blMMBlu 0 . 003 I
Sentine l Unit4 100% NOx-NH3 - ROG Comp l ian ce .xis 2/151 2 0 1 3

1 :54PMPort 

## w w w w 

# w w w w w w w w w w w N N N N
N N N N N N N N N E E E E E E E E E E E E E E E 

## s s s s s 

## s s s s s 

## s s s s s Average Point 

### 3 3 3 

### 3 3 2 2 2 2 2

3 3 3 3
2 2 2 2

3 3 3 3 3 2 2 2 2 2

3 

### 3 3 

### 3 3 2 2 2 2 2 Date 211112013 211112013 21111 2013 21 1112013 21 1112013 21 1112013 211112013 211112013 211112013 211112013 211112013 211112013 21 1112013 211112013 211112013 211112013 211112013 211112013 211112013
21 1112013 21 1112013 21 1112013 211112013 2111 / 2013 2111 / 2013 2/11/2013 211112013 21 11 / 2013 21 1 1/ 2013 21 1112013 21 11 / 2013 2111 / 2013 2111 / 2013 2111/2013 2/11/2013 211112013 21 11 / 2013 21 11 / 2013 21 11 / 2013 21 11 / 2013 211112013 2111 / 2013 2111/2013 2/11/2013 211112013 2111 / 2013 2 /11 / 2013 2111 1 2013 21 11120 1 3 21 11 / 2013 2111 / 2013 2 /11 / 2013 2/11/2013 2111/2013 2 / 11/2013 2111 / 2013 21 1112013 211112013 

# 8.H.A1IQU.IIIYS.MC.S 1845 N. Case Street 

### Orange, California 92865 714·279-6777 REFERENCE METHOD 1·MINUTE AVERAGE DATA Time O2 CO 2 NO" CO 10 : 07 13 .223 4.527 3 . 256 2 . 867 1 0 :08 10 :09 1 0 : 10 10 : 11 10 : 12 10:13 10:14 10:15 10:16 10:17 10:16 10 : 19 10 : 20 10 : 21 10 : 27 10 : 29 10 : 30 10 : 31
10 : 34 10 : 35 10 :3 6 10 : 37 10 : 36 10:39 10:40 10:41 10:42 1 0:45 1 0 :46 10:47 1 0 :46 10 :49 10 : 50 10:51 10:52 10 : 53 10 :54 10 : 55 10 : 56 10 : 57 10 : 56 10:59 11 :05 11 :06 11 :07 11:06 11 :09 11 : 10 11 :11 11 : 12 11 : 13 11 :14 11 : 15 11 : 16 11 : 17 11 : 16 11 : 19 13 .222 13 .227 13 .222 13 .219 13 .219 13 .211 13 .227 13 .216 13 .205 13 .222 13 .252 13 .231 1 3. 254 13 .255 13.224 13.216 13.233 13.211
13 .206 13 .215 13.21 13 . 207 13.203 13 . 207 13.197 13 . 191 13 . 192 13 . 193 13 . 167 13 . 194 13 . 197 13 . 199 13 . 196 13.206 13 . 192 13 . 165 13 . 182 13 . 179 13 . 177 13 . 162 13 . 171 13 . 163 13.176 13 . 163 13 . 166 13 . 176 13 . 164 13 . 172 13.173 13 . 179 13.166 13.17 1 13.152 13 . 166 13 . 164 13 . 169 13 . 172 13.20 4 . 528 4 . 526 4 . 526 4 . 532 4 . 526 4 . 533 4 . 524 4 . 531 4 . 543 4 . 529 4 . 514 4 . 523 4 . 512 4 . 512 4 . 522 4 . 521 4 . 515 4 . 524
4.523 4 . 517 4 . 52 4 . 521 4.526 4.524 4 .528 4 . 529 4 . 53 4 . 531 4 . 534 4.529 4 .526 4.525 4.529 4 . 521 4 . 533 4 . 542 4 . 546 4 . 549 4 . 551 4 . 556 4 . 554 4.56 4.547 4 . 552 4.55 4.543 4 . 551 4 . 546 4 . 544 4 . 536 4.546 4 . 541 4.55 4.541 4 . 543 4 .54 4 . 54 4.53 3 . 16 3 . 216 3 . 176 3 . 267 3 . 163 3 . 343 3 . 131 3 . 244 3.25 3 . 224 3 . 266 3.422 3 . 234 3 . 279 3 . 079 3 . 096 3 . 069 3.12
3 . 054 3 . 027 3 . 034 3 . 036 3 . 05 2 .964 2.967 3 . 063 3 . 002 2 . 972 2 . 936 2 . 901 2.952 2.901 2.699 2.746 2 . 666 2 . 911 2 . 922 2 . 647 2 . 766 2 . 768 2 .772 2 . 659 2 . 926 2 . 953 2 . 947 2 . 937 2 . 925 2 . 938 2 . 974 2 . 617 2 . 656 2 . 611



### 3 2 . 614 2 . 775 2 . 73 2 . 651 3 . 01 3 . 113 3 . 325 3.414 3.405 3 . 355 3 . 073 3 . 236 3 . 102 2 . 902 2 . 693 3 . 196 3 . 037 3 .416 3 .463 3.261 3.356 3.506 3.241
3 . 017 3.166 3 .232 3.207 2 . 99 3 . 10 1 3.034 2.966 2.946 2.757 2 .571 2 .629 2.704 2.91 2.71 2.933 2 . 737 2.488 2 .263 2 .284 2 . 225 2 . 105 2.132 1.966 1.631 1.734 1 . 776 1 .6 1 .603 1 . 569 1 .602 1 .652 1 .656 1.661 1.551 1.99 2 . 155 2 . 179 2 .034 2.65 02·ln NOx-ln CO-In THe·ln 13 . 291 32 .887 109 . 561 25 . 926 13 . 31 32.466 120.645 30 . 51 13 . 313 32.49 122 . 197 30 . 369 13 . 353 32 . 191 130 .969 34 . 33 13 . 352 32 . 527 121 . 007 29 . 921 13 . 311 32.61 1 19 .006 26 . 312 13.327 32 . 397 114.493 26 . 213 13.32 32.349 117 . 66 26.621 13.301 32.946 106.015 23.609 13.296 32.676 107.629 24.429 13.359 32.279 106.441 25.239 13 . 34 32.576 111.424 25 .647 13 . 35 32.267 111 .772 26 . 14 13 . 356 32 .005 123 .935 31 . 175 13 . 366 31 .654 124 .21 31 . 566 13 . 324 32 . 231 119.052 30 . 009 13 . 364 31.26 129.429 34.451 13 . 339 31 . 782 128.403 34.006 13.327 32.087 119.159 30.587
13 . 329 31 .84 117 .541 29 .67 13 . 324 31 . 952 1 22 .26 32 . 126 13 . 346 31 .614 123 .5 6 32 .049 13 . 329 32 .363 1 1 5 26 .616 13 . 319 32 .214 115 . 394 29 .226 13 . 31 32.097 119 . 669 30.744 13 .294 32.109 116 . 514 30.264 13.264 32.203 11 5. 746 26 . 756 13 .296 32.242 114.07 27 .777 13 .271 32 .966 104 . 941 23 .977 13 .294 32 .542 107 . 106 24 . 941 1 3. 292 32 . 715 111.473 26 .68 13 . 306 32.341 111.962 27.449 13.296 32.672 116.533 29.236 13.314 32 . 21 117 . 075 29.709 13.294 32.606 120 . 056 30 .544 13 . 26 32 .946 109 . 534 26 . 069 13 .273 33 . 559 97 . 155 20 . 701 13 .266 33 . 567 93 . 202 19 . 247 13 .269 33 . 391 95 . 262 20 . 096 13 . 264 33.456 95 . 135 19 .961 13 .252 33.462 95 . 05 20 . 132 13 .26 33.497 94 . 64 1 9 . 743 13 .266 33.762 65.923 16.176 13 . 23 34.42 75 .062 12.256 13 . 24 34.166 77 . 609 13 . 297 13 .241 34 .341 73 . 927 11 . 696 13 . 21 34 . 561 69.496 10 . 652 13 .2 15 34 . 682 66 . 261 10 . 159 13 .215 34 .519 69 . 653 10 . 712 13 .22 9 34.442 66.699 9 . 539 13 . 256 33 . 775 76 .536 13.744 13 . 271 33.666 77.911 13 . 567 13 . 256 34.201 77.147 13 . 035 13 . 277 33.367 62 .667 15.449 13 .264 33 . 04 94 . 276 19 . 753 13 .267 32.76 104 . 766 24.661 13 .276 33 . 115 96 . 171 21. 529 13 .274 33.053 101 . 122 22 .876 13.30 32.65 105 . 09 Sent i nel Unit 4 100% NOx-NH3-AOG Compliance.xls 2115/2013

1 : 54 PMPort 

### 5 S S S S 

### 5 5 S S S S 

### 5 S S S E E E E E E E E E E E E E E E N N N N N N N N N N N N N N N 

## w 

## w w w w w 

# w w w
w w 

# w w Average Point 3 3 3 3 3 2 2 2 2 2

3 3 3 3 

### 3 

### 2 2 2 2 2



### 3 3 3 

### 3 3 2 2 2 2 2

3 3 3 3 3 2 2 

### 2 2 Date 211112013 21 11 /2013 2111/2013 2111/2013 2111 / 2013 2111/20 13 2111/20 13 2111/2013 2111/2013 2111/2013 2111 / 2013 2111120 13 2111/20 13 2111/2013 2111/2013 2111/2013 2111/2013 2111/2013 211 1 / 2013 2111/2013 211112013 211112013 2111/2013 211112013 211112013 2111/2013 2111/2013 2/11/2013 2/11/2013 211112013 21 11 12013 21 11 / 2013 2111/2013 2111/2013 211112013 211112013 21 11 12 013 2111/2013 21 1112013 211112013 2111/2013 21 11 /2 013 21 1 1120 13 21 1112013 211112013 2/11/2013 2/11/2013 211112013 21 11 12013 21 11 12013 2111/2013 2111/2013 211112013 211112013
2111/2013 2111/2013 211112013 2111 / 2013 

## DeltaAIrQualItY SeMen 1845 N . Case Street 

### Orange, California 92865 714-279-6777 Time 11 :41 11 :42 11 :43 11 :44 11 :45 11 :46 11:47 11 :48 11 :49 11 : 50 11 : 51 1 1 : 52 11 : 53 11:54 11:55 12 : 01 12 : 02 12 : 03 12 : 04 12:05 12:06 12:07 12:08 12 :09 12 : 10 12 :1 1 12 :12 12:13 12:14 12 :1 5 12 : 21 12 : 22 12 : 23 12 : 24 12 : 25 12:2 6 12 : 27 12 : 28 12 : 29 12:30 12 : 31 12:32 12:33 12 : 34 12 : 35 12:40 12:41 12 :42 12 :43 12 :44 12 :45 12 :46 12:47 12:48
12 : 51 12:52 12:53 12 :54 REFERENCE METHOD 1-MINUTE AVERAGE DATA 

### 0, 13 . 163 13.151 13.184 13.202 13.187 13.188 13 .16 13 . 159 13.16 13.173 13.185 13.153 13 . 135 13.149 13.111 13 .17 4 13.196 13 . 185 13 . 187 13 .172 13.177 13.179 13.173 13 . 177 13.192 13.187 13.198 13.191 13.184 13 . 188 13.174 13 . 162 13.159 13 .156 13.155 13.157 13.156 13 . 164 13.178 13.174 13.172 13.168 13 . 178 13 . 174 13.176 13.176 13.169 13.165 13.157 13.164 13.145 13.134 13.143 13 . 139
13.128 13.124 13.127 13 . 129 13.16 CO, 4 . 523 4 . 529 4.505 4.494 4 . 508 4 . 505 4 . 526 4.528 4 . 529 4 .519 4 . 512 4 . 536 4 . 548 4.543 4.568 4 . 534 4 . 515 4 . 522 4 . 523 4.537 4.534 4.532 4 .537 4.535 4 . 521 4.525 4.518 4.525 4.533 4 . 528 4 . 533 4 . 54 4 .541 4 .543 4 . 544 4 . 542 4 . 542 4 .537 4.528 4 . 531 4 . 531 4 . 534 4.528 4.531 4 .5 31 4 . 527 4 . 531 4 . 533 4 . 534 4 . 527 4 . 536 4 . 538 4 . 531 4 . 534
4 .544 4.549 4 . 548 4.548 4.53 NO, 2 .85 2.779 3.696 3.055 2 . 779 2 .5 25 2 .632 2.776 3.08 3.651 3 . 012 3 . 012 3 . 006 2.645 2 . 965 3.915 3 . 099 2 . 777 2 .701 2 .887 2.854 2 . 819 2 . 848 2 . 784 2.805 2.839 2.71 2 .664 2.721 2 .621 3 . 003 2 . 97 3.007 3 . 021 2 . 969 2 .9 2 . 867 2 . 811 2 . 795 2 . 829 2 . 759 2 .6 82 2 .681 2.728 2 . 653 2 . 785 2.808 2.825 2.79 2 . 793 2.86 2.801 2 . 685 2 . 783
2 . 849 2.909 2.841 2.908 2 . 88 CO 2.467



### 3 0.865 0.148 0 . 19 0.51 2 .259 2.811 3.226 1.528 0.265 0.257 0.415 1.361 2.305 2.333 0.488 0 .502 0.936 1 . 29 1.891 2.126 1 . 899 2 . 127 2 . 234 2.223 2.206 1.954 1.625 1.351 1 .866 1 .835 1.642 1 .596 1.664 1.938 2 . 283 2.678 2 .647 2 . 713 2.817 2 . 723 2 . 914 2 .646 2.696 2.55 2.42 2 .503 2.745 2.926 2.823 2 .75 2 . 711 2 .621
2.551 2.496 2.476 2.433 2.01 02-ln 13.274 13.288 13.314 13 . 303 13 . 294 13 . 296 13 .263 13.284 13.292 13.296 13 .291 13.306 13 . 284 13 . 265 13 .2 7 13.287 13.277 13.297 13.269 13.278 13.28 9 13.261 13.272 13 . 297 13 . 291 13.303 NOx-ln 31.741 37.77 39.121 38.449 36 . 096 32 . 668 32 .1 81 31 . 356 34 .657 37 .015 37 .042 36 .656 33 .8 57 32 . 755 32.386 38 .34 37 . 143 34 .852 34 .635 33 .679 33 .2 33.864 33 . 271 33 . 153 33 .2 33.126 CO-In 123.685 86.846 13.841 14.528 23.496 73.698 124.009 142.823 1 1 5.755 23.988 22 . 16 23 .474 49.377 102 . 665 122.938 19 .737 19.699 35 .267 48.973 69.809 88.112 81.728 85.912 92 . 354 95 .837 90 . 993 THe-In 31.977 20.282 -0 . 009 -0 . 009 0 . 17 14 .808 32.295 39 . 716 29 .76 0 . 129 -0.01 -0 .0 1 6 . 034 24 .465 30.993 0.166 -0 . 01 1 .674 4 .7 11 . 331 17 . 957 15.329 17 . 188 19.461 21 . 312 19 . 761 13.285 33.309 92.261 20.283 13.272 33.723 79 . 013 14.654 13.268 33 .984 64.498 9 . 185 13.282 33 .581 66 . 664 10 .523 13.213 33 .887 76 . 19 13.489 13.208 34 . 226 71.447 11.836 13 . 213 34 . 029 68.483 10.788 13.22 33 . 936 69.025 11. 444 13.218 33.584 72.957 12.7 13 . 205 33 . 139 89.128 18.661 13.234 32 . 739 98.762 22 . 513 13 . 241 32 . 696 103.782 24 . 951 13.268 32 . 296 108.94 27 .405 13 . 246 32 . 284 111 . 631 28.44 13.22 32 .28 114 . 703 29 . 072 13 . 259 31 .815 124.366 34 .533 13.247 32 . 507 116.334 29 .706. 13 .249 32 . 397 112.498 28 . 257 13.242 32.186 119.216 31.125 13.228 32.837 102 . 615 24 . 02 13 . 234 32.835 101.848 24 . 144 13.22 32.599 110.113 26 . 967 13 . 217 32.113 120 .677 31 . 935 13.21 32.276 119 . 395 30 .964 13 . 202 32.199 121 .694 32 . 46 13 . 189 32.124 119.433 31.011 13 . 185 32 . 304 117.908 30 . 282 13 . 179 32 .516 113.128 28 . 043
13.197 32 .607 111 . 052 27.552 13.199 32.595 106.728 25.04 13 . 201 32 .644 107.829 26 . 085 13 .1 98 32 .814 105.663 25.002 13.25 33 . 64 87.21 Sentinel Unit 4100 % NOx-NH3-ROG Compliance. xis 2115/2013

1:54 PMCOMPLIANCE TEST DATA AND WORKSHEET CPV Sentlnel-4-CEMS-7 5-1 TEST CONSTANTS Station : CPV Sent inel Un it: 4 Performed By: 

### AA. SP . SS . JM Cp : 0.99 Tref : 60 ' F Slack Area : 14 3.14 It' MeterYd : 0.992 METHOD 2.1 DATA dP Temp Vel. Point (in . H 2O) sqrt(dP) 'F (Ips )

4 0 . 75 0 . 8660 750 87 . 85 3 0 . 76 0 . 87 1 8 752 88.51 2 0 .84 0 . 9165 749 92.94 1 0 . 72 0 . 8485 750 86.08 4 0 . 75 0 . 8660 752 87 .93 3 0.84 0 . 9 165 753 93 .09 2 0 . 79 0.8888 749 90 . 13 1 0 . 80 0 .8944 748 90 . 66 4 0 . 75 0.8660 753 87 . 96 3 0 . 84 0 .9165 753 93 .09 2 0 . 92 0 .9592 750 9 7. 30 1 0 . 87 0 .9327 748 94 . 54 4 0 . 86 0 .9274 750 94 .08 3 0 . 92 0.9592 752 97 . 38 2 0 . 75 0 .8660 751 87.89 1 0 . 80 0.894 4 752 9081 Average 0 . 8089 0 .8994 750 . 8 91.27

Stack Flow Rate : 783 .8 kwacfm Stack Flow Rate : 304.1 kdscfm Dry Gas Meter Time Vol. Tm(in) Tm (out) #/Matl. Start 665 . 812 62.0 57 .0 H,O 60.0 57 .0 H,O End 703 .677 60 .0 57 .0 Empty 60 .0 56 . 0 SG Total 37 .865 58 .6 Total
NO. ppm NO., ppm@ 1 5% O2 NO. Ib/MMBtu NO. Iblh r CO ppm CO , ppm@ 15% O2 CO Iblhr O2 

### % Stack Flow dscfh CT Fue l Flow hscfh Turbine Water Injection gpm



## 8II1I1I AIrqualfIY S'MCIIS 1845 N. Case Street Orange, California 92865 714·279 ·6777 CT Load MW SCR NH3 In ·ection Iblhr NO . I blMMSCF CO IblMM8tu CO IblMMSCF TEST VARI ABLES Start Dale : 2111 /13 Start/End Time : 15 :45 16 :52 Load (MW)1Repl i cate# 

### 75 1 Ba r om. Pressure : 29.64 Pstack : Pstack: MW: Analyzer Range Cal Gas Val ue Pre-Test Direct Zero Pre-Test Direct Span Pre-Test Syste m Zero Pre-Test Sys t em Span

Post-Test System Zero Post-Test Syste m Span Post-Test Direct Zero Post-Test Direct Span Average Corr. results Pre-test zero bias Pre-test span bias Post-test zero bias Post-test span bias Zero drift Span drift METHOD 4 . 1 DATA Impingers End Start Diff . 855 .7 689 . 1 166.6 666 . 3 665 . 9 0.4 487 .9 481 . 6 6 . 3 948 . 6 938 . 8 9 .8

I r 1 00 83 . 1 RESULTS Ref. Meth CEMS 2,49 2,40 2.07 1.90 0 . 008 0 .007 5 . 50 5 . 12 1 . 23 1 . 40 1 . 02 1 . 10 1 .63 1 .92 13 .81 13 . 54 18,246 , 119 18.220.000 7 .018

. 

### I 81

. 115 7 .84 0 .002 2 .4 1 

# . 2.40 iwg 29.82 "H9 28.15 Ib/lb-mo le METHOD 100.1 DATA 

### 0, CO, NO, CO 20 10 

### 5 10 9 . 99 4 .96 2 .52 9.47 0 . 10 0 .0 1 0 .03 0 .02 10 .04 5 . 11 254 9 . 56 0 .20 0 . 06 0.03 -0 .01 10 .02 5.11 2.52 9 . 51

0 . 22 0 .08 0 .03 ·0 .04 10 .05 5 . 1 3 2 .51 9 .50 0 . 10 0 .03 0 .02 0 .03 10 .06 5 . 15 2 . 53 9 .55 13 .8 1 4.20 2.49 1.21 13 .81 4 .06 2.49 1 .23 0 . 5% 0 .5% 0 . 1% -0 .3% -0 . 1% -0 . 1% -0 . 3<1/" -0 .5% 0 .6% 0 .5% 0 . 2% -0 . 7% -0 . 1% -0 .2% -0.4% -0 .5 % 0 . 1 % 0 .2% 0 .0% -0 .3% 0 . 1% 0.3% -0 .2% -0 . 1%

Meier Pressure : 1 .5 iwg Sample Volume : 37.445 dscf H2 0 Volume : 3 . 863 s c f Mo isture Conle nt 9.4 %

Sentinel Unit 4 75% NOx-NH3-ROG Comp l ianc e .xis 2/15/2013

2:0 4 PMCOMPLIANCE TEST DATA AND WORKSHEET CPV Sentin el -4-CEMS - 75·2 TEST CONSTANTS Station : CPV Sent i nel Unit: 4 Performed By : AA
. SP
. SS
. JM Cp o 0 . 99 Tret : 60 

### ' F Stack Area: 143
. 14 ft' MeterYtj : 0.992 METHOD 2
. 1 DATA dP Temp Vel. Po i nt (in. H 2O) sqrt(dP) 

### ' F (Ips)

4 0 . 72 0 . 8485 749 85
.69 3 0 .80 0
. 8944 750 90 .37 2 0 .8 4 0
. 9165 751 92
.64 1 0 .80 0
. 8944 750 90
. 37 4 0 .90 0
. 9487 751 95.89 3 0.92 0 . 9592 752 96.99 2 0
. 94 0 . 9695 752 98
.04 1 0.94 0
. 9695 750 97.96 4 0 . 70 0 . 8367 750 84
.53 3 0 .93 0
. 9644 751 97
.47 2 0 . 72 0
. 8485 748 85 .66 1 0 .80 0 .8944 750 90 . 37 4 0
. 87 0.9327 752 94
. 32 3 0 . 75 0
.8660 751 87.53 2 0 . 70 0 .8367 752 84
.60 1 0.80 0
.89 44 749 90 . 33 Average 0 . 8184 0
. 9047 750
. 5 91.42

Stack Flow Rate : 785
. 2 kwacfm Stack F l ow Rate : 311.6 kdscfm Dry Gas Meter Time Vol. Tm(in) Tm(out) #/Matl. Start 704
. 925 60 55 H,O 61 58 H ,O End 744
.425 59 55 Empty 58 55 SG Total 39 . 500 57
.6 Tola l
NO. ppm NO., ppm@ 15% O2 NO. IblMMBtu NO. Iblhr CO ppm CO , ppm@ 15 % O 2 CO Iblhr O 2 % Stack Flow dscfh CT Fuel Flow hscfh Turb in e Water Injection gpm



## 811118AIr qualItY SIIMCIIS 1845 N. Case Street O range, California 92865 7 14-279 -6777 CT Load MW SCR NH3 Iniection Iblhr NO. IblMMSCF CO IblMMB l u CO IblMMSCF TEST VARIABLES Start Date: 2/11/ 1 3 StarVEnd Time : 17 : 10 18 : 19 Load (MW)/Replicate# 75 2 Barom
. Pressure : 29 .64 Pstack: Pstack : MW: Analyzer Range Cal Gas Value Pre-Tes t Direct Zero Pre-Test Direct Span Pre-Test System Zero Pre-Test System Span

Post-Test Sys t em Zero Post-Test Syste m Span Post-Test Direct Zero Post-Test Direct Span Average Co rr . r esults Pre-test zero bias Pre-test span bias Post-test zero bias Post -test span b i as Zero drift Span drift METHOD 4
. 1 DATA Impingers End Start Ditt. 837.2 682 . 7 1 54.5 658 .7 658 . 6 0 . 1 581
.6 580 .9 0 . 7 844
. 5 833 . 7 10
. 8

I , 100 66 . 1 RESULTS Ref
. Meth CEMS 2.77 2 . 60 2 .30 2.13 0.008 0.008 6
.27 5 .67 1 . 24 1.40 1 .03 1
. 11 1
.68 1 .90 13
.80 13.57 1 8,698,872 18.139 ,000



## - 6.96 1



### - 

## I



## - 80



### - 113 9.01 

### - 0 . 002 

### - 2.42 

## - 2.40 iwg 29.82 "Hg 28.38 I b/lb-mole METHOD 100
. 1 DATA 

### 0, CO, NO, CO 20 10 5 10 9 .98 4 . 96 2
.52 9
.47 0 . 10 0 . 03 0 .02 0 .03 10 .

06 5
. 15 2
. 53 9 . 55 0 . 22 0 . 08 0.03 -0
. 04 10 . 05 5
. 13 2
. 51 9.50

0
.21 0 .09 0 .03
-0 .02 10.03 5
. 13 2
. 52 9.49 0
. 10 0.04 0 .02 0 .02 10 .05 5.16 2 . 53 9 . 56 13 . 80 4.20 2.76 1
. 21 1 3
.80 4 .05 2.77 1
. 24 0
.6% 0
. 5% 0.2% -0
.7% -0
. 1% -0
.2% -0.4% -0 .5% 0
. 5% 0
. 5% 0.1% -0
. 3 % -0
. 1% -0
.3% -0 .2 % -0
.8% -0
. 1% 0
. 0% -0 .1 % 0
. 2% -0
. 1% 0
.0% 0.1% -0
. 1%

Meter Pressure : 1
. 5 iwg Sample Volume: 39
. 138 dscf H20 Volume: 3
.073 scf Moisture Can lent: 7 .3 

### %

Senlinel Unit 4 7 5% NOx-NH3-ROG Compl i ance. xis 2/151 2 013

2 :04 PMPort 

## s 

# s s s s s s s s
s s 

# s s E E E E
E E E E E E E E E N N N N N N N N N N N N N N N 

# w w w w w w w w w w 

# w w w w w Average Point Date 3 211112013 3 2 1 1112013 3 211112013 3 211112013 3 211112013 2 2111120 13 2 2111120 13 2 211112013 2 2111120 13

3 3 3 3


### 2 2 2 2

3 3 3 3 3 

### 2 2 2 2 

### 2

3 3 3 3 3 2 2 2 2 2 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013
211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 211112013 21 11 12013 21 11 12013 211112013 211112013 211112013 21 1 112013 211112013 211112013 211112013 211112013 211112013 2111120 13 2111120 13 2111120 13 211112013 211112013 211112013 2111 1 2013 211112013 21 11 12013 211112013 211112013 211112013 21 1 112013 

## Dell8A/rQualfIY S.mC'S 1845 N. Case Street 

### Orange , California 92865 714-279-6777 Time 15:46 15 :47 15 :48 15 :49 15 : 50 15 :51 15 : 52 15:53 15 : 54
15:57 15:58 15:59 16 :00 16 :04 16:05 16 :06 16 :07
16:10 16:11 16:12 16 : 13 16 : 14 16:15 16:16 16:17 16 :18 16 :2 1 16 :22 16:23 16:24 16:25 16 :26 16 :2 7 16:28 16:29 16:30 16:31 16 :3 2 16:33 16:34 16:35 16:39 16 :40 16 :41 16:42 16:43 16 :44 16 :45 16:46 16:47 16:48 16 :49 16:50 16:51 16:51 16:52 

### REFERENCE METHOD l-MINUTE AVERAGE DATA 

### 0 , 13.827 13.829 13.824 13.83 13.833 13 .824 13.829 13.821 13.817
13.772 13.773 13.776 13.774 13.83 1 13.832 13.834 13.833
13 .83 13 . 827 13.83 13 . 818 13.805 13.799 1 3.802 13.804 13 . 806 13 . 823 13.814 13.8 11 13.817 13 . 819 13.835 13 . 832 13 .831 13 . 829 13 . 831 13.823 13.796 13 . 797 13 . 807 13.819 13 . 843 13.831 13.829 13 . 83 13.825 13.801 13.799 13.801 13.794 13 .806 13 . 756 13.761 13 . 765 13.765 13 . 769 13 . 81 CO, 4.187 4.187 4.188 4.183 4 . 18 4.187 4.186 4 .1 91 4.196
4 .225 4.226 4.228 4.227

4 .2 4.196 4 . 192 4.194
4.197 4 . 193 4 . 186 4 . 191 4.197 4.201 4.201 4 .201 4 . 202 4.192 4.195 4.198 4 . 196 4 . 195 4 . 188 4 . 187 4 . 19 4.194 4.192 4 .194 4 . 212 4 .21 4 .207 4.2 4.181 4.19 4 . 189 4 . 192 4 . 193 4 . 207 4.21 4.21 4 . 215 4.209 4 . 236 4 . 236 4.236 4.236 4 .24 4 .2 0 

### NO, 2.286 2.229 2.305 2 . 219 2 . 133 2 . 243 2 . 184 2.313 2.253
2 . 185 2 .2 8 2 . 15 2 . 163 2 . 288 2 . 316 2.451 2 . 347
2 . 163 2 . 1 2.152 2.223 2.234 2 . 229 2 . 059 2 . 084 2.077 2 . 362 2.439 2 . 558 2.642 3.151 3.152 3 . 14 3 3 . 106 3.017 3.06 2.833 2.538 2.681 2.532 2.578 2.676 2.769 2 . 782 2 .72 2 . 579 2 .629 2.738 2.585 2.799 2.583 2 . 761 2 . 717 2.739 2.739 2 . 699 2 .49 CO 1.55 1.671 1.529 1.473 1 . 721 1.911 1.861 1.794 1.979
1.436 1.279 1.231 1.228 1.55 1 . 569 1.322 1 . 174
1 . 344 1.469 1.489 1 . 575 1.4 1.39 1 . 285 1.324 1 .3 74 

### 1.4 1 . 335 1.229 1 .145 1.089 1 . 037 1.053 1 .043 1.03 1 . 014 1.044 1.058 0 . 949 0 . 915 0 . 934 0 .9 77 0.886 0.922 0.842 0 . 864 0 . 788 0 .68 8 0 .68 0.68 0.705 0.68 0.675 0.711 0.711 0.738 1.21 02-1n 13.845 13 .844 13.846 13.854 13.862 13.872 13 .872 13 .877 13 .865 NOx-ln CO-In THC-In 26.189 92.085 14 .417 26.207 99.379 18 . 71 26 .3 66 87.895 12.693 26 . 001 91.769 14.313 25 . 511 107.669 21 . 741

25 . 2 121.053 29 . 526 25 . 025 127.066 32.946 25 . 072 125.007 32 .3 52 25 .1 6 137 . 838 40.409
13 .86 25 . 969 104.595 20.844 13 .876 26.137 92 . 304 14.216 13.863 26 . 32 87.058 11.92 13 . 86 26 . 086 90.055 13 . 338 13.894 26 . 241 84.851 11.209 13 . 904 26.249 86 .049 11.419 13.885 27 . 017 71.316 6.732 13.886 26 . 764 68.261 6.081
13 .877 26.335 77.949 9.005 13.873 26 . 312 81 . 901 10.211 13 .879 25 . 799 87 . 147 12.107 13 .854 26 . 301 84.435 11 . 179 13 .854 26 . 254 80.409 9.846 13.842 26.533 77.234 8 .872 13.846 26.46 76.394 8 .5 51 13.866 26 .42 6 78.046 8.954 13.854 26.492 79 . 314 9 . 392 13.855 26 .667 76.664 8 .668 13.851 26 . 815 72.161 7 .1 98 13.849 26 .9 18 67.277 5.933 13.842 27.104 64.487 5.104 13 . 855 27.32 59.029 3 .588 13 . 867 27 .1 21 59 . 785 3 . 613 13 .862 27.19 60 . 119 3 .672 13.861 27 . 327 58.687 3.426 13.87 27.411 57.24 3 . 1 13.869 27.445 56.467 2.957 13 . 861 26 . 996 61 . 277 4 .1 41 13.85 27.15 62.89 4.416 13 . 853 27 . 371 57.425 3 . 023 13.858 27 . 263 56 . 889 3 . 051 13.873 27.203 57 .5 13 2.954 13.881 27.376 58.904 3.494 13.85 27.197 56.918 3 . 119 13.852 27.381 55 . 924 2 . 944 13 . 871 27 .3 86 54.231 2.478 13 .872 27.549 53.914 2.467 13.871 27.66 54.112 2.629 13.884 27.73 51.273 2 . 034 13 . 872 27.673 52.769 2 . 371 13 . 887 27 .674 51 . 004 1.773 13 . 868 27 .563 52 . 745 2.435 13.869 27.598 52.048 2.204 13.885 27.33 54.034 2 . 548 13.889 27.536 53.316 2 . 35 1 13 . 889 27.536 53.316 2.351 13.908 27.517 53.502 2 .35 9 13.87 26.71 75.35 Sentinel Unit 475% NOx-NH3-ROG Compliance.xls 2115/2013

2:04 PM

### Port 

### 5 S S S


## s s s s s s s s s E E E E
E E E E E E E E E N N N N N N N N N N N N N N N 

## w w w w w 

## w w 

# w w w 

## w w 

## w w w Average Point 

### 3 3 3 3
2 

### 2 2 

### 2

3 3 3 3
2 2 2 2



### 3 

### 3 3 3 3 

### 2 2 2 2 2



### 3 

### 3 3 3 3 

### 2 2 2 2 

### 2 Date 211112013 211112013 211112013 211112 01 3
211112013 211112013 211112013 211112013 211112013 211112013 211112013 21 11 12013 211112013 211112013 211112013 211112013 211112013
211112013 211112013 211 1 12013 21 11 /2013 211112013 211112013 211112013 211112013 21 1112013 21 1 1120 13 21 1 1120 13 21 1 112013 211112013 21 11 120 13 211112013 211112013 211112013 211112013 211112013 21 1 1120 13 211112013 2111 1 2013 211112013 211112013 211112013 211112013 21 1 112013 211112013 211 1 1 2013 211 1 12013 211112013 211 112013 211112013 211112013 211112013 21 1112013 21 1 1120 13 21 1 1120 13 21 1 1120 13 

## 8BItaAl,QualllY SBMCIIS 1845 N . Case Street 

### Orange, California 92865 714·279·6777 REFERENCE METHOD 1·MINUTE AVERAGE DATA 17:11 13 .79 4.192 2 . 924 1.121 17 :12 17 : 13 17 :1 4

17:17 17:18 17:19 17:20 17:21 17 : 22 17 : 23 17:24 17 :25 17:29 17:30 17:31 17:32
17:35 17:36 17:37 17 : 38 17:39 17:40 17:41 17:42 17 :43 17 :47 17 :48 17 :49 17 :5 0 17 ;51 17 : 52 17 : 53 17:54 17:55 17 : 56 17 : 57 17 : 58 17 : 59 18 :00 18:01 18:05 1 8 :06 18 :07 18 :08 18 :09 1 8 : 10 18:11 18:12 18:13 18:14 18 : 15 18 : 16 18:17 18 :1 8 18 : 19 13 .789 13.794 13.799
13.786 13.783 13.785 1 3.775 13 .765 13.74 13 . 753 13 . 756 13.754 13.803 13.804 13.827 13.822
13.799 13.785 13 . 788 13 . 778 13.773 13 . 747 13.765 13.755 13.757 13.825 1 3.822 13 .817 13 . 808 13.809 13 . 806 13.818 13.821 13.814 13 .814 13 .804 13.793 13.797 13 .805 13.805 13.806 13.805 13.807 13.816 13 .814 13.807 13 .812 13.809 13.807 13.812 13 .81 13 . 803 13.804 13 . 808 13 .81 13 . 80 4.193 4.193 4 . 193
4.201 4.204 4.205 4.2 11 4 .219 4 . 23 4.228 4.225 4.226 4 . 204 4.205 4.194 4.197
4.21 4 . 218 4.218 4.225 4.23 4.245 4 .237 4 . 245 4 . 248 4 . 201 4 .1 98 4.199 4.197 4.195 4 .19 4.184 4.179 4 . 185 4 . 186 4 . 194 4 . 201 4 . 201 4 . 193 4 . 193 4 . 187 4.189 4.19 4.187 4.19 4 . 195 4 . 197 4 . 197 4 . 201 4 .199 4 .202 4 .207 4 .208 4 . 21 4 .212 4.20 2.918 2.886 2.769
2 .6 91 2 . 712 2.642 2 .841 2 .5 11 2 .6 77 2.463 2.61 3 2 . 759 2.674 2 . 574 2 . 593 2 . 692
2.712 2 .9 57 2 .875 2 .884 2.788 2 .805 2.717



### 3 2 .928 2 .617 2.951 3.066 3 . 133 2 . 992 2.863 2.741 2 .66 2.704 2 . 754 2 .817 2 .633 2 . 542 2.46 2.458 2.596 2 . 72 2.653 2.741 2.7 12 2 . 55 2.492 2.98 3.243 3.073 2 . 952 2 . 837 2 . 881 2 .796 2 . 622 2 . 76 1 . 117 1 . 121 1.102
0 . 89 0.806 0.837 0.821 0 .808 0 . 842 0.884 0.817 0.868 1.077 1.067 1.146 1.164
1.135 1. 143 1 . 178 1 . 061 1.025 0.995 0 .93 4 0 . 988 0 . 971 1.313 1 . 353 1 . 391 1.379 1.372 1.388 1.478 1.585 1 . 624 1.58 1.455 1 . 356 1.352 1.464 1 .516 1.389 1.434 1.41 1.431 1.432 1.418 1 . 366 1 . 333 1.293 1.326 1.416 1.35 

### 1 . 38 1.338 1 . 36 1.21 02·10 NOx-ln CO-In THe-In 13.805 26.714 69.369 6.265 13 .819 26 . 73 68.916 6 . 149 13 . 84 26.925 67 .541 6 . 014 13 .835 26.953 68 .591 6.25
13 .872 27.295 59 .876 3.994 13.831 27.272 58.603 3.501 13.845 27.221 58.149 3.327 13 . 922 27.223 57.217 3.159 13 .843 27 . 22 58.783 3 .5 26 13.84 27 .065 60.019 3 .8 53 8 . 842 18 .686 56 .853 8.784 0.07 0.749 5 .84 45 . 244 0.043 0 . 589 0 . 106 46.703 13 . 881 26.844 63 . 866 5.201 13 .9 28 26.584 67 . 747 5 . 201 13 . 942 26.529 71.76 5 . 201 13.96 26.283 72.58 5.201
13 . 954 26.186 81 . 977 5.201 13 . 954 25 . 945 83 . 571 5 . 2 13.918 26.341 80.178 5.2 13.918 26.509 72 .653 5.2 13.937 26 . 534 72 . 136 5.2 13.935 26.85 72.598 5.201 13.937 26.674 71.899 5.201 13.903 26 .706 74.177 5.201 13 .9 21 26 . 636 71 .262 5.201 13 .943 26 . 271 75 .02 5 . 199 13 .933 26 .235 76.539 5.199 13.929 26 .201 78 . 564 5 . 199 13 . 949 26.31 76.641 5 . 199 13 .94 26.37 75 . 359 5 .1 99 13 .977 25.904 80.29 5 . 2 13 .958 25.597 86 . 009 5.2 13 . 941 25.633 91.446 5 . 2 13 . 927 25.779 88.955 5.201 13.914 26.105 85.967 5 . 201 13.905 26.298 79 . 37 5 . 2 13.918 26.204 78 . 669 5 . 2 13 . 927 25.928 63 . 189 5 . 2 13 . 915 25.666 88 . 673 5 . 201 13 . 939 25.487 91.334 5.201 13.929 25.955 80.377 5.2 13.93 26 .029 79.319 5.2 13.939 25 . 966 82 .0 75 5.201 13 .9 35 26 . 059 81 . 721 5 .2 02 13 . 94 26 . 118 81 .625 5.202 13 .938 26 . 198 78.1 1 1 5 .202 13 .9 39 26.463 74.791 5 .202 13 . 946 26.292 76.712 5 .201 13.94 26.439 73.232 5.201 13 .939 26 . 004 77.954 5.2 13 .949 25.965 80.262 5.2 13 .955 25 . 822 81 .957 5 . 201 13.936 26.09 80.462 5 .201 13 . 948 26.126 80 .7 55 5 . 201 13 .96 2 25.962 83 . 375 5 . 201 13 . 37 25.39 72.71 Sentinel Un it 4 75% NOx-NH3-ROG Compl i ance. xis 211512013

2:04 PMCOMPLIANCE TEST OATA AND WORKSHEET CPV Sentlnel-4-CEMS-50-1 TEST CONSTANTS Stat i on : CPV Sentinel Unit 4 Performed 

### By : M,MC,RM,JM Cp : 0
. 99 Tref : 60 'F S lac k Area : 143 . 14 ft' MeterYd : 0
.992 METHOD 2.1 DATA dP Temp Vel. Point (i n . H 2O) sqrt{dP) ' F (fps)

4 0 .67 0 . 8185 779 83
.80 3 0
.82 0
. 9055 781 92
.78 2 0
.85 0
. 9220 782 94
.50 1 0 . 79 0
. 8888 780 91
.03 4 

### DAD 0
. 6325 78 1 64
.80 3 0.46 0 . 6762 782 69
.52 2 0
. 71 0 . 8426 783 86.40 1 0 . 77 0 .8775 781 89 .91 4 0
.42 0 .6481 780 66 . 37 3 0.47 0
.6856 782 70 . 27 2 0 . 5 1 0.7141 782 73
. 20 1 0.48 0.6928 781 70
.98 4 0
.7 1 0
.8426 782 86
. 37 3 0 .76 0.8718 782 89
. 36 2 0.89 0.9434 783 96
. 74 1 0
.82 0
.9055 781 92
. 78 Average 0 .6470 0.8043 781.4 82.42

Stack Fl ow Rate : 7 07 .9 kwacfm Stack Flow Rate : 270 .9 kdscfm Dry Gas Meter Time Vol . Tm (i n) Tm(ou t) #lMati . Start 848 .550 81 77 H , O 82 78 H , O End 894.424 83 83 Empty 68 69 

### SG Total 45 .874 77.6 Tolal
NO x ppm N Ox , ppm@ 15 % O 2 NO x Ib/MMBtu NO x Ib/hr CO ppm CO, ppm@ 15% O2 CO Ib/hr O 2 % Stack Flow dscfh C T Fuel Flow hscfh Turbine Wa te r I njection gpm


# 8,It8A1rQu.11IY S'Me,S 1845 N . Case Street Orange, California 92 865 714-279-6777 CTload MW SCR NH3 Injection Iblhr NO x Ib/MMSCF CO IblMMBtu CO IblMMSCF TEST VARIABLES Start Date : 2/12/13 Start/End Time : 11 :5 8 13 :07 Load (MW)/Replicate# 50 1 Barom . Pressure : 29
. 74 Pstack: Pstack: MW: Analyze r Range Cal Gas Valu e Pre-Test Direct Zero Pre-Test Direct Span Pre-Test System Zero Pre-Test System Soan

Post-Test System Zero Post-Test System Span Post-Te st Direct Zero Post-Test Direct Span Average COIT. results Pre-test zero bias Pre-test span bias Post-t est zero bias Post-test span bias Zero drift Soan drift METHOD 4
. 1 DATA Impingers End Start D itt . 862
.6 687
. 3 1 75 .3 664
.8 662 . 1 2
. 7 488 . 2 487 .3 0
.9 918
. 5 908.2 10 . 3

Ir 100 89
. 2 RESULTS Ref . Meth CEMS 2
. 43 2.10 2
. 16 1 .84 0
.008 0 . 007 4 . 79 3.79 0
.36 0
.50 0
.32 0
.39 0
.43 0 .56 14 . 27 14 .09 16 ,254.483 1 4 , 978,000 5.337 

# -.

55 102 8
.97 0
.001 

### - 0
. 76 

## - 2.40 iwg 29
. 92 "Hg 28,2 1 Ib/lb-rnole METHOD 100.1 DATA 

### 0, CO, NO, CO 20 10 5 10 9.98 4
. 96 2
. 52 9.47 0 . 10 0 . 10 0 . 01 0
.06 10 .05 5
. 20 2 . 51 9 .62 0 . 13 0. 12 0
. 02 0 .07 1 0 .03 5 . 18 2.5 0 9
. 58

0 , 14 0 , 15 0
.02 0 .0 5 10 .00 5 .2 0 2.49 9 .58 0.10 0 . 11 0.D1 0
.06 10
.02 5.2 1 2 . 5 1 958 14 . 26 4
.00 2.4 1 0.43 14 .27 3
.80 2.43 0
.36 0 . 1% 0 . 3% 0 . 3% 0 . 1% -0 . 1 % - 0 . 2% -0 . 2% -0.4% 0 . 2% 0 .4 % 0 . 2% -0.1% -0 . 1% -0 . 2% -0 . 3% 0 .0% 0 . 1% 0 .3% 0 .0 % -0.2% -0 . 2% 0 .2% -0 . 3% 0 .0 %

Meter Pressure : 1 . 5 iwg Samp le Vo l ume : 43 .909 dscf H 2 0 Volume : 4 . 146 scf Moisture Content: 8 .6 %

Sentinel Unit 4 50% NOx- NH3-AOG Compliance. xis 2/15/2013

1 : 54 PMCOMPLIANCE TEST DATA AND WORKSHEET CPV Sentlnel-4-CEMS -5 0-2 TEST CONSTANTS Station : CPV Sentinel Unit : 4 Perfonned By : M,MC,RM , JM Cp: 0.99 Tref : 60 "F Stack Area : 143
. 14 II ' Meier Y d : 0
.992 METHOD 2.1 DATA dP Temp Vel. Point (in
. H2O) sqrt(dP) "F (Ips)

4 0 . 52 0
.7211 788 74 .03 3 0 . 63 0.7937 790 81
.55 2 0.68 0
.8246 792 84 . 80 1 0 .82 0.9055 790 93.04 4 0.49 0.7000 793 72.0 1 3 0.52 0.721 1 79 4 74 . 21 2 0 . 54 0.7348 793 75
.60 1 0 . 52 0
.7211 792 74. 1 5 4 0.46 0.6782 795 69 .83 3 0 . 50 0.7071 796 72
.83 2 0 . 64 0 .8000 796 82
.40 1 0
.77 0
.8775 794 90 . 31 4 0.64 0
.8000 793 82 .30 3 0 .83 0 .9110 795 93 . 80 2 0 .87 0.9327 796 96.07 1 0 .78 0 .8832 794 90 . 89 Average 0 .6312 0.7945 793 . 2 81
. 74

Stack Flow Rate : 702
.0 kwacfm Stack Flow Rate : 267
.3 kdscfm Dry Gas Meier Time Vol. Tm(in) Tm(out) #/Matl. Start 895
.949 73 71 H,O 69 69 H,O End 937
.886 68 68 Empty 70 69 

### 5G Total 41
. 937 69 . 6 Total
NO x ppm NO x , ppm @ 1 5% O 2 NO x I b/MMBtu N O x Iblhr CO ppm CO, ppm@ ' 5%0 2 CO Iblhr O 2 % Stack Flow dscfh CT Fuel Flow hscfh Turbine Water Injecti on gpm



## 811118AIrQUIlIItySIIMCII' 1845 N. Case Streel O range, California 92865 7 14-279-6777 CT load MW SCR NH3 hectlon Ib/hr NO, IblMMSC F CO IblMM9 tu CO IbiMMSCF TEST VARIABLES Start Date : 2/12/13 Start/End Time : 13:30 14 : 39 load (MW)lReplicate# 50 2 Barom
. Pressure : 29.74 Pslack : Ps ta ck: MW: Analyzer Range Cal Gas Val ue Pre- Test Direct Zero Pre-Test Direct Span Pre-Test System Zero Pre-Test Syste m Span

Pos t -Test System Zero Post-Test System Spa n Post- Test Direct Zero Post-Test Direct Span Average Corr
. results Pre-test zero bias Pre-test span bias PosHest zero b i as Post-test span bias Zero drift Span drift METHOD 4 . 1 DATA Impingers End Start Oitt. 844
. 8 680.8 164
. 0 658 .0 657.3 0.7 580
. 2 580 .2 0 .0 858.4 844
.5 13.9

I r 100 78 .6 RESULTS Ref
. Meth CEMS 2.09 1 .80 1 .86 1 .58 0
. 007 0
.01 4.06 3 .26 0
. 43 0.40 0 .38 0 .36 0 .50 0 .56 14
. 26 14
.05 16,037 ,165 14,901,000 5 , 341 

## L. 55 107 7
. 61 

### - 0 .001 

### - 0
. 91 

# - 2.40 iwg 29.92 "Hg 28.2 6 I bllb-mole METHOD 100 . 1 DATA 

### 0, CO, NO, CO 20 10 5 10 9 .98 4
. 96 2
. 52 9
.47 0
. 1 0 0
. 11 0
.01 0 .06 10 .02 5.21 2
. 51 9 . 58 0
. 14 0.15 0.02 0.05 1 0 .00 5.20 2.49 9.58

0
. 14 0
. 18 0 .03 0 .04 10 .00 5.24 2 . 50 9 .59 0
. 10 0. 1 3 0 .00 0
.05 10.00 5.25 2
. 50 9 . 60 14
. 22 4.02 2
. 07 0.48 14
. 26 3 . 79 209 0.43 0 ,2% 0.4% 0
. 2% -0
. 1% -0.1% -0.2% -0
.3% 0 .0% 0
. 2% 0.4% 0
. 5% -0
. 1% 0 . 0% 0
.0% 0
. 0% -0
. 1% 0 .0% 0
. 3% 0.2% -0
. 1 % 0
.0% 0.5% 0
. 1% 0
.0%

Mete r Pressure: 1 .5 iwg Sample Volume: 40
. 747 dscf H 2 

### 0 Volume : 3
.654 scf Moisture Content: 8 . 2 %

Sentinel Unit 4 50% NOx-NH3 - ROG Compliance. xis 2/15/ 201 3 1 :54 PMPort 5 

### S S S S 

## s s s s s s s s s 

## s E E E E E E E E E E E E E E E N N N N N N N N N N N N N N N 

## w w w w
w w w w w 

# w w w w Average Point 3 3 3 3 3 2 

### 2 2 

### 2 2

3 3 3 3 3 2 2 2 2 

### 2

3 3 3 

### 3 3 

### 2 2 2 2 2



### 3 3 

### 3 3
2 2 2 2 Date 2112/2013 2112/2013 211212013 211212013 211212013 211212013 211212013 211212013 211212013 211212013 2112/2013 2112/2013 211212013 211212013 211212013 211212013 2112/2013 211212013 211212013 2112/2013 211212013 211212013 2112120 13 211212013 211212013 211212013 211212013 2/12/2013 211212013 211212013 2112/2013 211212013 211212013 211212013 211212013 2/1212013 2/1212013 211212013 2 /1212013 211212013 211212013 211212013 211212013 211212013 2/1212013 2112/2013 2/12/2013 211212013 211212013
211212013 211212013 2/1212013 2/12/2013 211212013 2112/2013 211212013 211212013 211212013 

## Of/haA/rOua/fIY S'Me,S 1845 N. Case Street Orange, California 92865 714·279·6777 Time 11 :59 12:00 12:01 12:02 12:03 12 :04 12 : 05 12:06 12:07 12:08 12:09 12:10 12:11 12: 12 12:13 12 : 17 12:18 12 :19 12:20 12:21 12:22 12:23 12 : 24 12 : 25 12 : 26 12 :27 12:28 12:29 12:30 12:31 12:35 12:36 12 : 37 12 : 38 12 : 39 12:40 12:41 12 :42 12:43 12:44 12:45 12 :46 12:47 12:48 12:49 12:53 12:54 12:55 12 : 56
12:59 13:00 13:01 13:02 13:03 13 : 04 13 : 05 13 : 06 13 : 07 REFERENCE METHOD 1·MINUTE AVERAGE DATA 14.269 4.003 1 . 739 0.345 14 .268 14.27 14 .283 14 . 279 14.277 14.242 14 . 263 14.263 14 .246 14.241 14.204 14 .2 04 14 .204 14 . 198 14 .286 14 .285 1 4 .277 14.278 14.268 14.274 14.271 14 .266 14.265 14.264 14.268 14 . 266 14.259 14 .264 14 . 261 14.241 14 .252 14 . 238 14.242 14 . 251 14.23 14.207 14.257 14 .259 14 .255 14 .255 14 . 191 14 . 176 14 . 18 14.19 14 .28 6 14.288 14.283 14 . 277
14.286 14 . 282 14.279 14.279 14 . 264 14 . 262 14.257 14.259 14 . 256 14.26 4.002 4 . 001 3 . 994 3 . 998

4 4 . 017 4.005 4.007 4.015 4.021 4.047 4 . 048 4 .05 4 .049 3.995 3 . 994 3.997 3.995 3.999 3.996 3 . 996 3.994 3.993 3.991 3 . 988 3 . 989 3 .99 2 3 . 989 3.99 3 . 999 3 . 993

4 3 . 999 3.995 4 . 007 4 .0 18 3 . 991 3 . 994 3 . 995 3 . 996 4 . 035 4 . 041 4 .04 4 .033 3 .9 81 3 .978 3.982 3.983
3.978 3.982 3 . 983 3 . 983 3.992 3.991 3.995 3 . 992 3.996 4 . 00 1 . 765 1 . 705 1.683 1.818 1 . 785 2.245 2 . 268 2 . 255 2 . 32 2 . 111 2 . 246 2 . 178 2.273 2 .293 1 . 871 1 .87 1 . 888 1 . 932 2.004 1.84 1 1.851 1 . 812 1 . 914 1 . 825 1.849 1.886 1 . 788 1.798 1 . 897 2 .7 98 2 . 637 2 .947 2 . 776 2 .698 3 . 103 3 .322 3 .063 3 . 034 2 .952 2 .99 1 3 .004 3 . 117 2 .916 2.804 3 .228 3 . 192 3 . 13 3 . 101
2 .648 2 .817 2.696 2.561 2 . 571 2.506 2.449 2 . 333 2.403 2.41 0.329 0.35 0.353 0 . 362 0 . 344 0.288 0.263 0.235 0.237 0.231 0.308 0.336 0.365 0.334 0.508 0.553 0.535 0.556 0.542 0.542 0.567 0.564 0 . 525 0.577 0.537 0.579 0.517 0 . 542 0.528 0 . 385 0.407 0 . 388 0 . 369 0.373 0.349 0 . 266 0.263 0.274 0.267 0.275 0 . 379 0 .354 0 . 35 0.344 0.542 0.553 0 . 543 0.535
0.526 0 .524 0.503 0 . 533 0.492 0.479 0.456 0.492 0.467 0.43 02-ln 14.323 14 . 337 14 .338 14 .3 4 14 . 342 14 . 34 NOx-ln 26 . 852 26.781 26.731 26 . 731 26 . 562 26.692 50.558 50 .6 21 51 .083 51 .714 51 .892 51.607 THe-In 1 . 33 1.263 1.238

1.3 1.469 1.44 14.343 26.497 53 . 01 1 . 535 14 . 343 26 . 678 51 . 98 1.524 14.342 27 .0 12 49.591 1 . 124 14 . 342 27 . 046 48.418 0 . 968 14.343 26 . 859 49.444 1.172 14 . 344 26 . 806 49.908 1 . 249 14 . 347 26 . 595 51.292 1 . 322 14 .3 45 26 . 713 51.26 1 . 337 14.342 26.821 50.506 1.156 14.338 26.468 52 . 756 1.485 14 . 332 26.463 53.195 1 .665 14.319 26.47 52.917 1 .59 14.318 26.404 53.891 1.62 14 . 317 26.414 53 . 217 1.591 14.317 26 . 364 53 . 887 1.697 14.317 26 . 391 53.529 1.623 1 4 . 317 26 . 392 54 . 084 1.628 1 4 .31 7 26 . 347 53 .774 1 . 587 14 . 317 26.212 54 . 987 1.753 14 . 318 26. 164 55 . 822 1 . 678 14 . 317 26.353 54.852 1.568 14 . 317 26.195 55 . 237 1.738 14.317 26.235 55.727 1 . 864 14 .3 17 14.317 14 . 317 14 . 317 1 4 . 317 14 . 317 14 . 317 14 . 335 14 . 34 14 .3 35 14 . 34 26.354 26.388 26.327 26 .499 26.25 26.181 26.496 26.251 26.086 26 . 36 26 . 237 54.492 53 . 085 54 . 767 53.048 55 . 11 56 . 07 53 .822 54.292 56 . 39 55 . 162 54 . 94 1.713 1.434 1.648 1.419 1 . 613 1 . 763 1.467 1 . 586 1 . 927 1.797 1 .638 14 . 341 26 . 189 55 . 55 1 . 788 14 .338 26 . 382 54 . 88 1 . 724 14 .332 26.491 52.693 1.402 14 .333 26.385 53.528 1.449 14.33 26.396 53.554 14.337 26.219 55 .276 14 . 342 26.084 56 .717 14.338 26 . 251 54 .649 14.339 26 .522 53 .049
14 . 339 26.428 53 .688 14.337 26.399 53 .634 1 4.328 26.66 1 51.413 14 . 332 26.628 51.871 1.544 1 . 757 1 . 931 1.57 1.483
1.548 1.496 1.258 1.185 14 .326 26.803 50 .053 1.01 14 . 321 26.921 49 .355 0 . 815 14 . 317 26.912 48 . 919 0 . 935 14 .3 17 26 .901 49 . 249 0 . 933 1 4 . 317 27.027 48 . 319 0 . 791 14.33 26.50 52.93 Sentinel Unit 4 50% NOx-NH3-ROG Compliance.xls 211512013

1:54 PMPort 

## s 

## s s s
s 

## s s
s s s s E E E E
E E E
E E E E N N N N N N N N N
N N N N 

## w w w w w w w 

# w w w w w w 

## w 

## w Average Point Date 3 2112/2013 3 211212013 3 211212013 3 2112/ 2013
2 211212013 2 211212013 2 2112/2013

3 3 3 3
2 2 2

3 

### 3 3 3 3 2 2 2 2

3 3 3 3 

### 3 2 2 2 2 2 21 1 21 2013 211212013 2112/2013 211212013 211212013 211212013 211212013 2112/2013
211212013 2112/2013 211212013
2112/ 2013 2112120 1 3 211212013 211212013 211212013 2112/2013 211212013 211212013 211212013 211212013 211212013 211212013 211212013
211212013 211212013 211212013 211212013 2/1212013 211212013 21 1 212013 211212013 211212013 211212013 211212013 211212013 211212013 2/12/2013 211212013 211 21 2013 211212013 211212013 211212013 

## 88118A1,QU8//tyS8rr1C8S 1845 N. Case Street Orange, California 92865 714-279-6777 Time 13 :31 13 : 32 13 : 33 13 : 34
13 : 37 13 : 38 13 : 39
13 :42 1 3 :43 13 :44 13 :45 13 :49 13 : 50 13 : 51 13 : 52
13 : 55 13 : 56 13 : 57
14 : 00 14:01 14 : 02 14 : 03 14 : 07 14 : 08 14 : 09 14 : 10 14 : 11 14 : 12 14:13 14 : 14 14 : 15
14 : 18 14 : 19 14 :20 14 : 21 14 :25 14 :26 14 : 27 14 :28 14 :29 14 : 30 14 : 31 14 : 32 14 : 33 14:34 14 : 35 14 : 36 14 : 37 14 : 38 14 : 39 REFERENCE METHOD I-MINUTE AVERAGE DATA 

### 0, 14 . 213 14 . 227 14 . 214 14 . 208
14 . 201 14 . 205 14 . 203
14 . 171 14 . 162 14.171 14.171 14 .259 14 .25 14 . 252 14 . 251
14 . 235 14.232 14 .232
14 . 233 14 .231 14 .224 1 4 .217 14 .203 14 .203 14 . 2 14 .203 14 .203 14 .203 14 .201 14 . 203 14 . 203
14.2 14 . 203 14 . 203 14 . 199 14 . 226 14 . 227 14 . 225 14 . 224 14 . 216 14 . 224 14 . 225 14 . 232 14 . 237 14.234 14 . 229 14 .225 14 . 232 14 . 234 14.236 14 . 22 CO, 3 .999 3 .992 3 .997 4.001
4 .016 4 . 01 4 .015
4 . 037 4.038 4 .033 4 .036 3 . 988 3.995 3 .995 3 .996
4 .007 4.008 4 . 009
4 .012 4 . 014 4 . 018 4 . 022 4 .037 4 .036 4 . 041 4 . 038 4.041 4 . 042 4 . 045 4 . 041 4 . 041
4 . 049 4 . 047 4 . 047 4 . 051 4.03 4 . 028 4 . 031 4 . 035 4 . 035 4 . 032 4 . 032 4 . 028 4.027 4.029 4.032 4 .033 4 .029 4.027 4.027 4.02 NO, 2 . 009 1.816 1.974 2.014
2 .35 2.228 2 . 263
2 .416 2 .466 2.312 2.482 1 . 919 2 . 075 1 . 993 1 .896
2 . 009 1 . 797 1.653
1 .665 1 .721 1.663 1 .708 2 . 374 2.308 2 . 347 2 . 304 2 . 394 2.401 2 . 366 2 . 013 1 .927
1.871 1 . 798 1.97 2.028 2 .027 1 .941 1 .908 1 .934 2.008 2 . 044 2 . 07 2 .082 2 . 182 2 . 178 2 . 275 2 . 233 2 . 279 2.236 2 . 343 2.07 CO 0.34 0 . 378 0 . 36 0.291
0 .288 0.252 0.25
0.249 0.292 0 .299 0 . 329 0.73 0 .705 0 .686 0 . 632
0 . 549 0.527 0 . 509
0.526 0.494 0.495 0.479 0 .525 0.559 0 . 544 0 . 561 0 .595 0 .541 0 . 513 0 . 559 0 . 53
0 . 514 0 . 503 0 . 533 0.49 0.506 0.538 0.496 0.492 0 . 501 0 . 516 0.51 0 . 518 0 . 563 0.566 0 . 553 0 . 531 0 . 511 0.544 0 . 546 0.48 02-ln 14.316 14.316 14 . 316 14 . 316
14 . 32 14.322 14.327 NOx-ln CO-In THC-In 26.433 51 . 774 1 . 327 26 .52 52 . 101 1.41 26 .826 50 .003 1 .059 26 . 829 49.395 0 .828
26.433 53 . 395 1 .542 26 . 508 52.933 1 .285 26.534 52.248 1.235
14 . 339 26 . 591 5 1. 725 1. 008 14 . 342 26 . 309 53 . 934 1.439 14 . 341 26 . 276 54 . 979 1 .644 14.342 26 . 361 53 . 97 1.467 14.34 . 26.484 53 . 72 1 .804 14 . 342 26.413 53 . 267 1 .608 14.34 26.459 53.09 1 .473 14 . 33 26.618 52.512 1 . 29
14 . 317 27 . 021 48 . 737 0 .868 14 . 317 27.104 47 . 989 0 . 788 14 . 316 27 . 181 47.472 0 .759
14.316 27.064 48.423 0 .931 14.315 26.918 49.046 0 .945 14.316 27.133 47.779 0 .724 14 .314 27 .281 46 .688 0 . 696 14 . 316 26 . 966 49.114 0 .871 14.315 26.92 49.886 0.999 14.317 26.778 50 .266 1 . 131 14.317 26.732 51.159 1 . 162 14 . 317 26 .819 50 .565 1 .03 14.315 26 . 965 49.802 0.894 14.317 26.832 49 .73 0 . 949 14 . 316 26 .814 50 .224 0 . 934 14 . 314 26 .859 49 .818 0 . 952
14.309 26.945 48.684 0 . 782 14 . 311 26.875 49 . 839 0 .909 14 . 311 26.838 49.709 0 . 921 14 . 297 26 . 944 49.17 0 .869 14.297 26.896 49 .659 0.961 14.298 26.799 50 . 309 0.915 14 .292 26.952 49 .718 0 .979 14.291 27.019 48.931 0 .851 14.296 26 .84 3 49.592 0.866 14.293 26.899 49 . 881 0 . 911 14.294 27.036 49 . 03 0 .766 14 . 314 26.783 50 . 338 1.078 14 .314 26.664 51.466 1 , 151 14.304 26 . 845 50 . 625 0.945 14 .294 27 .011 49 . 689 0 .874 14 . 305 26 . 887 50 . 163 0 . 85 14.314 26.765 50 . 8 0 . 95 14.314 26.664 52 .528 1 . 148 14 . 314 26 . 673 52 . 979 1 . 351 14 . 32 26.78 50 .5 8 Sentine l Unit 4 50% NOx-NH3-ROG Compliance.xls 2/15/2013

1 : 54PM

## Appendix 

## C.2.3 One Minute Data Logger Data

R041 0688 C-6Date Time 

### 0, % 

### CO, % 2/11/2013 7:31:00AM 19.788 0.489 2/11/2013 7:32:00AM 19.755 0 .488 NO, PPM 

### CO PPM 

### 0, % NO, PPM 0.011 -0.346 16.94 -0.003 0.011 -0.336 16.92 -0.008 

### CO PPM 0.028 0.046 THC PPM 0. 427 N2/NOx Mode 0.478 2 /11/2013 7:33:00 AM 19.741 0.486 0.012 - 0.335 16 .8 98 -0.011 0.043 0.533 N2INO Mode 211112013 U4:00AM 19.726 0.487 2.008

-0.331 16 . 892 1.824 0.046 0.433 211112013 7:35:00 AM 19.7 11 0.488 4 .8 22 -0.333 16 .861 4 .6 54 0.041 0.517 NO/NOx Mode 211 1 12013 7:36 :00 AM 19.708 0 .488 4 .6 31 -0 .336 16 .66 4 .6 44 0.089 1 .323 2111/2013 7 :37 :00 AM 19.706 0.489 4 .623 -0.337 16 .878 4 .645 0.065 .0 .005 NO/NO Mode 2111/2013 7:38 :00 AM 19 .6 97 0.489 2 .217 -0.322 16 .871 2 . 319 0.104 -0.005 ITHC Zero 2111/ 2013 7:39:00AM 19.726 0.488 0.021 -0.337 16.868 0 .002 0.139 -0.004 N02/NOMode 2111/2013 7:40:00AM 19.799 0.486 3.186 -0.332 16 .87 4 3.289 0.077 61.553 2/11/2013 7:41 :00 AM 19 .3 16 0 .484 3.666 -0.335 16.893 3 .686 0.071 78 .00 3 N02lNOx Mode 211112013 7:42 :00 AM 9.121 0.484 2.095 -0.327 16.951 2 . 207 0.067 80.356 2111/2013 7 :43 :00 AM 5 .2 73 0.486 0.131 -0.348 16 .99 0 . 117 0.035 85.136 ITHC Ca l H; gh 211 1 / 2013 7:44 :00 AM 5 . 639 0.488 0.131 -0.353 16.963 0.059 0.03 85.45 2111/2013 7:45 :00 AM 5 .996 0.485 0.102 -0.342 16 . 985 0.043 0.032 73.552 2111/2013 7:46 :00 AM 6.452 0.485 0.088

-0.337 16.989 0 .043 0 .033 46.836 2/11/2013 7:47:00 AM 6.879 0.487 0.11 -0.348 17.032 0 .042 -0.015 46.68 2 ITHC M ;d 2/11/2013 7:48:00 AM 5.192 0.47 0.083 -0.378 12.834 0 . 029 0.002 47.118 2/11/2013 7:49:00AM 0.131 0.428 0.018 -0.423 0.084 -0.003 -0.118 31.233 2/11/2013 7:50:00 AM 0.108 0.0 49 0.014 -0.016 0.033 -0.006 0.124 25.337 THC Low 2111/2013 7:51 :00 AM L-,0:;'.;:10;;,7,---::-0'i.0;,;1;-7
__**0;.;.0;,1;.:1~--i-0:,:.0;.:1~1 _-:0:::'::,** **03,"3,--:-O;,;.006;,:::._-:0'=',,;;12:;7 :;-1**  24.507 Cat Zero 2111/2013 7:52 :ooA M 15 .205 8.041 3 .543 -0.021 12 .427 24 . 75 51 .957 3 .80 7 2111/2013 7:53 :oo AM 18.736 9.698 4 .792 -0.016 19.047 48 .728 238 .759 0.838 2111/2013 7:54 :00 AM 18 .829 9.701 4 .789 .0.01 19.044 48 .752 242.562 0 .6 12 211112013 7:55:00 AM

# 1r.1~8~.8~62i:-~9;";.7:ii**05 :i--::'4'i** **.7'"9""** -0 .007

# L.,1;.;9.:;.0,.2;;.4_.;;48;;;**.;;784;,;..~2,;:42;;;.9;;;84;.;,J1** 0.685 Cal H;gh 2/1112013 7:56:00 AM**--,1.;;2':.;1i'-24--'--i6,-:.1.;;63;-_3;;;.5~7:-i1...,** 9.42 14.376 33 .068 232.594 0.692 2/11/2013 7:57:00 AM ILr...,.,1;.:O;.,.-_.::5:;.1,;:07:,......;2;;;.:;.54;.:2'-1 9.591 L.,1;,:;0,;;.0;,:;8;,.1_.;:2;;;5',;;.07;.:1...;..,1.,;.41;,;.6.:;.1,"2;.J1 0.796 M;d 211112013 7:58:00AM 18.04 1.224 0.914 9 .511 16.459 12.149 101 .171 0.79 2111/2013 7:59:00AM 20.873 0.049 0.Q35 9 .5 12 21.091 0.199 2 . 619 0.661 211112013 8:00:00 AM 20.894 0.048 211112013 8 :0 1 :00AM 20 .896 0.046 2111/2013 8 :02:00 AM 20.909 0.044 2111/2013 8:03:00 AM 20.922 0.044 2/11/2013 8:04:00 AM 20.918 0.046 2/1112013 8:05:00 AM 20.917 0.046 2/11/2013 8:06:00 AM 20.916 0.046 2/11/2013 8:07:00 AM 20 . 919 0.046 2 / 11/2013 8:08 :00 AM 20 .925 0 .045 2111/2013 8:09:00 AM 20.94 0.044 211112013 8 :10:00 AM 20 .946 0.048 2111/2013 8 : 11 :00AM 20 .95 7 0.051 2 /1 1 / 2013 8:12 :00 AM 20 .969 0.047 2/11/2013 6:13:00AM 20.97 0 .052 2/11/2013 8:14 :00AM 21 . 117 0.048 2111/2013 8:15:00 AM 21.246 0.047 0.035 0.04 0.035 0.04 0.035 0.022 0.024 0 .029 0.027 0.034 0.038 0.037 0.041 0.037 0.035 0 .051 9 .5 11 21.098 0.139 8.999 21.116 0.123 4 .697 21.119 0.122 4.522 21.14 0.127 1.947 21 . 162 0.102 0.196 21.136 0.086 0.374 0.301 0.327 0.401 0 . 375 0.277 0.634 CO Cat High 0.617 0.799 0.697 

### CO Mid 0.688 0 . 69 0 . 186 21 . 149 0.097 0.355 0 . 542 0.183 21.221 0.095 0.423 0.676 0.184 15.488 23 . 254 8.878 0.738 0.193 13.252 34.884 33.301 2.131 0. 18 3 13 . 267 35.189 30.641 1 .592 0 . 204 13.262 35.828 29.259 0.926 0.203 13 . 265 36.16 29.099 0.949 0.195 13 . 318 34.37 34.446 1.928 0.204 13.328 33.57 57.377 7 . 646 0.213 13.324 33 . 804 84.046 9 . 623 2111/2013 8:16:00AM 21 .099 0.047 0.056 0.213 13 .269 35.258 41.922 3.134 0.319 0.469 2111/2013 8:17:00 AM 21 .0 21 0 . 048 0.032 0.221 13 . 254 36.692 25.703 2111120 13 8:16:00 AM 20 .6 24 0.298 0.024 0.224 12 .208 26 .347 27.269 2111/20 13 8:19 :00 AM

## 1...-i1';;**0.'i34~5:i---i5;:;.0~5i-1 --:0;;;** **.0 ;;;0~7""**  -0 . 254 10 .1 19 0.692 5 . 651 -0.009 02lC02 bias 2111/2013 8:20:00AM 6.549 3 .071 0.623 -0.338 4.466 27 . 164 1.01 2111/2013 8:21 :00 AM

## 1r--:0;;;**i-17:i4-~0;:;.0~18:;-""'2;;;.4~9:i3""'--i-0:': .0** **::;4';;6--:0i- ~05ii7"-"";;'48;'** **8;'4;;;9~-On.'i35;;;9""** -0.011

-0.01 NOx bia s 2/11/2013 8:22:00 AM 0 . 156 0.008 1.941 0.849 0.058 26 . 878 38.467 -0.009 2111/2013 8:23:00AM 0 . 129 0.004 0 . 019 8.881 0.032 0.42 234.891 -0.001 2111/2013 8:24:00AM 0.129 0.001 0 . 013 9.5 0.032 0.329 1242 .6521 

## o CO bias 2111/2013 8:25:00 AM 3.326 1.317 0.703 8.694 8.032 19 .8 29 189 .483 0.185 2111/2013 8:26 :00 AM 13 .0 87 4 .543 3.146 1.326 13.256 35 .50 1 35.333 1.264 2111/2013 8 :27 :ooA M 13 .12 5 4 .559 3 . 341 0.679 13 .3 35 .517 32 . 133 1 .26 21 11 / 2013 8 :28:ooAM 13 .1 26 4 .567 3 .38 1 0.684 13 . 304 35.571 32.493 1 .3 25 2111/2013 8:29 :oo AM 13 .1 41 4.559 3.11 0.655 13.287 35 .58 32.588 1.467 2/11 / 2013 8 : 30 :00 AM 13 . 146 4.558 3.12 0.617 13.29 35.554 31.988 1.266 2111/20 13 8:31:00AM 13.15 4.558 3.145 0 . 598 13.286 35.673 31.482 1 .259Date 2111/2013 2/11/2013 Time 8 : 32 :00 AM 8033 0 00 AM 2111/2013 8 : 34 :00 AM 2111 / 2013 8 :35 :00 AM 21 11 / 2013 8 :36 :00 AM 2/11 / 2013 8 :37 :00 AM 2/11 / 2013 8 : 38 :00 AM 211112013 8039 0 00 AM 2111/2013 8 :40:00 AM 2111 / 2013 8 :41 :00AM 211112013 8042 0 00 AM 211112013 8043000 AM 2 /11/2013 8 :44 :00 AM 2111 / 20 13 8:45 :ooAM 21 11 / 2013 8:46 :00 AM 2/11 / 2013 8:47 :00AM 2111 / 2013 8:46 :00 AM 211112013 8049 0 00 AM 2 /11 / 2013 8:50 :00 AM 2/11/2013 8:51:00 AM 2/11/2013 8:52:00 AM 2 /1112013 6:53:00 AM 211112 0 13 6:54:00 AM 2111 / 2013 6:55:00 AM 2111 / 2013 8 : 56 :00 AM 211112 0 13 8 :57 :00 AM 211112013 8058000 AM 211 112013 8059000 AM 211112013 9000000 AM 211112013 9001000 AM 211112013 9 0 02 0 00 AM 21 11 / 2013 9 :03 :00 AM 21 11 120 13 9004 0 00 AM 211112 0 13 9 0 05 0 00 AM 2111 / 2013 9:06 :00 AM 2111 / 2013 9:07 :00 AM 2111/2013 9:08:00 AM 2/11/2013 9:09:00 AM 2/11/2013 9:10:00 AM 2111/2013 9 : 11:00 AM 21 11 / 20 13 9 : 12:00 AM 2111 12 013 9 : 13 :00 AM 211112013 9 : 14 :00 AM 2 /1 1 / 20 13 9:15:00AM 2 /11/2013 9:16:ooAM 2/11/2013 9:17:00AM 2/11/2013 9:18:00 AM 2111/2013 9:19 :00AM 211112013 9020 0 00 AM 2111 / 2013 9 :21 :00 AM 211 11 2013 9 0 22 0 00 AM 21 11 12013 9 :23:00 AM 2 /11 / 2013 9 :24:00 AM 2 / 1112013 9 0 25000 AM 2/11/2013 9:26:00 AM 2111/2013 9:27 :00 AM 2111/2013 9:28 :00 AM 211112013 9 0 29 0 00 AM 211112013 9 :3 0: 00 AM 211 112013 903 1000AM 211112 0 13 9:32 :00 AM 2111 / 2013 9:33 :00 AM 211112013 9:34 :00 AM 

### 0 , % 13.147 13.151 13 . 155 13 . 158 13 . 157 13 . 156 13 . 159 13 . 158 13 . 151 13 . 148 13 . 139 13 . 141 13.143 13 . 146 13 . 153 13.153 13.155 13 . 148 13 . 15 13 . 156 13 . 176 13 . 178 13 . 176 13 . 168 1 3. 189 13 . 193 13.191 13.186 13 . 188 13 . 18 13 . 187 13 . 182 13 . 199 13 . 182 13 . 156 13 . 128 13 . 111 15 .583 15 . 526 13 . 1 6 9 13 . 152 13 . 176 13 . 191 13 . 163 13 . 188 13 . 152 13 . 853 15.494 13 . 186 1 3. 193 13 . 183 13 . 189 13 . 183 13 . 182 13 . 163 13 . 176 16.19 13 . 199 13 . 2 13 . 204 13 . 207 13 . 224 13 . 219 

### CO , % 4.562 4.562 4.564 4 . 565 4 .566 4.567 4.565 4.566 4.566 4.57 4.574 4.574 4.574 4 . 572 4 .572 4.573 4.571 4.574 4.574 4.568 4 .557 4 . 557 4 . 556 4 . 559 4.54 4.541 4.542 4.552 4.546 4 . 552 4.55 4 . 556 4 . 544 4 . 561 4.572 4.588 4.6 3 .032 3 . 358 4 . 568 4 . 576 4 . 558 4 . 55 4.556 4 . 556 4 . 583 4 . 068 3.342 4.565 4 . 554 4 . 567 4.557 4 . 561 4.558 4.567 4 . 56 2 . 81 4.549 4.544 4.543 4 . 544 4.533 4.538 

### NO , PPM 3 . 167 3 . 125 3 . 097 3 .0 52 3 . 171 3 . 115 3 . 157 3 . 162 3 . 10 3 3 . 083 3 . 148 3 . 056 3 . 141 3 . 211 3 . 171 3 .063 3 .1 15 3 . 066 3. 163 3 . 206 3 .633 3 . 228 2 . 895 2 .953 2 .998 3 . 123 3 . 076 3 .1 99 3.059 3 . 196 3.1 0 4 3.143 3 .00 1 3 .0 24 2 . 99 3 . 026 3 . 09 2 . 161 2 . 033 3 .051 3 . 15 3 .0 1 3 .0 0 8 2 . 936 2 . 756 3 . 01 2.926 2 . 154 3.461 3 . 28 3.433 3 . 296 3 . 3 0 3 3.275 3.294 3 . 111 2 . 084 3 . 358 3 .2 64 3 . 322 3.383 3 . 427 3 . 523 

### CO PPM 0.572 0.609 0 . 703 1 . 121 1.126 1.254 1 . 237 1.19 1 . 217 1 . 319 1 .527 1 . 71 1 . 888 1 . 839 1 . 656 1.766 2.06 2.406 2 . 369 2 . 221 1661 0. 185 0. 391 1 .045 1 . 549 1 . 537 1 . 487 1 . 383 1 . 467 1.414 1 . 574 1 . 499 1 . 739 1 . 885 1.757 1.841 1.994 1.746 1 . 019 2 . 058 2 . 032 2 . 276 2 . 752 2 . 319 2 . 514 2.598 2.277 1.887 3 . 008 3 . 113 2 . 863 2 . 982 2 . 951 2 . 81 2.661 2 . 691 1 . 87 2 . 509 2.786 3.014 2.987 2.724 2.767 

### 0 , % 13.278 1 3.275 13 . 273 13 . 27 13 . 241 13.226 13.227 13.217 13 . 225 13 . 219 13 . 21 13.203 13 . 212 13 . 219 13 .236 13 . 234 13.223 13.219 13.227 13.22 13 .231 13 . 234 13 . 272 13 . 266 13.295 13.297 13.29 13.254 13.279 13.322 13 .2 96 13 . 299 13 . 30 8 13 . 281 13 . 271 13.277 13.269 13.269 13 . 294 13.337 13 . 342 13 . 367 13 . 288 13 . 307 13 . 301 13.259 13 .272 13 . 312 13 . 308 13 . 333 13 . 296 13 . 323 13 . 292 13.285 13.329 13.339 13 . 318 13 . 333 1 3 . 351 13 . 34 13 . 326 13 . 364 13.31 

### NO , PPM 35.781 35 . 724 35 . 298 34 . 914 34 . 882 34 . 748 34 . 921 34 . 954 34 . 712 34.422 34 . 135 33 . 777 33 . 781 34 . 125 34 . 309 33 . 723 33 . 378 33 . 073 33.4 33 . 244 38 . 227 37 . 954 35 . 7 9 2 34 . 575 33 . 695 33 . 875 34 . 143 34 . 405 34 . 403 34 . 08 34 . 343 33 . 824 3 3 . 326 33 .535 33 . 594 33 . 093 33 . 382 33 . 371 33 . 277 33 . 384 33 . 425 32 . 128 32 . 28 32 . 663 3 1. 838 32 . 774 32 . 835 32.34 32 . 685 32 . 525 3 2 . 593 32 . 228 32 .6 1 32 . 651 33 . 097 32 . 604 33 . 184 32 . 793 32.403 32 . 556 32 . 901 33 . 039 33.077 

### CO PPM 31 . 157 31.754 36.171 49.491 49.262 55 . 1 6 7 51 .48 9 49 . 893 52 . 282 59 . 893 67.779 76.571 82.795 77.163 73 .009 62 . 217 94 . 551 1 0 2.716 99.684 95.02 51.291 17.606 26.264 45 . 949 62 . 617 57 . 991 54 . 915 49 . 741 55.795 54 . 062 59 . 172 59 . 526 7 0. 379 75 . 088 76.456 80 . 618 81 . 343 78 . 882 83 . 598 84 . 807 83 . 447 104 . 54 121 .947 112 .449 137.19 132.093 118.911 126.354 121.049 127 .662 116 . 87 123 . 484 118 . 714 117.671 107.71 117.572 109.783 106 .907 117.813 123 . 327 116 .094 107.271 107.669 

### THC PPM 1 . 313 1.421 1 . 984 5 . 078 4 . 842 6. 39 5 . 245 5 .07 5 . 716 7 . 789 9 . 826 12 . 372 14 . 547 12 .652 11.521 14 . 795 18 . 355 18.3 0 3 17.206 16.34 7 . 082 -0 .00 7 1 . 027 4 . 051 7 . 574 6 .575 5 . 755 4.644 6 . 013 5 . 622 6 . 45 8 6 . 554 9 . 277 10 . 329 10.54 6 12 . 019 11.835 11.524 13. 1 61 13 . 3 8 9 12. 69 1 20 . 344 29 . 134 25 . 277 35 . 372 32 . 548 27 . 523 31 . 27 28 . 189 31 . 791 27 . 334 30 .1 2 27 . 951 27 . 268 23.335 27.757 24 .41 23.376 27 .4 0 2 29 . 88 9 27 . 539 24 . 219 24 . 066

### 0, CO, 

### % NO. CO O2 NO. CO THe Dale T ime 

### % 

### PPM PPM % PPM PPM PPM 2111/2013 9:35:00 AM 13 .2 1 4.542 3 .495 2 . 832 13 . 316 32.837 111.128 25.358 2/11/2013 9;36 ;OQ AM 13.215 4.54 3.422 3.033 13.315 32.255 121 2111/2013 9:37:00AM 5 .694 1.734 1.477 5.454 1.305 5.797 187.373 211112013 9:38 : 00 AM 0 . 167 0.046 0.034 9.403 0.059 0.978 1 242.65 

## 1 2111/20 13 9:39 : 00 AM**r-:i' 0.i;-** **74::i3:-....;0i 50iii-6_-:i-0** **'ii0~39~** 9 . 374 5.076 0 . 925 202.052 2111/2013 9 :40 : 00 AM LI-:;;9 . :;88,.,3;..........,;;;5 .;,09::,..._;;0. ;;02;:9;,..J 1 .544

# r.1~0:i:**066~--;0:;; 7;;;2~6-,1**  8.511 21 11 / 2013 9:41 :00 AM 8 .786 4 .334 0.254 -0 .359 5 .217 20 . 715 -0.09 2111/2013 9:42 :00 AM

### rl-:i-**0.-:;24~4:---;O;':.0~58+--;;2.~50~5 ;-.....,-o:;;** **0~8::i8,....-:i-0.'ii05i1,........;4;;;8,:.; 5-;1'-~0;,;.2ii22::-,**  2/1112013 9:43 :00AM 0.126 0.019 1 . 1 0.011 0.034 29 .269 0 .249 2111/2013 9:44:00 AM 0.105 0.009 0.026 0.007 0.031 0.162 0.111 2/1112013 9:45:00 AM

## rl-:i-0.~10~4:--i0;':.0;;0:::8--:i-0**'ii02~6:--i0:;;.0~1';5--:i-0.'ii0"'31:--i0::-.1:;2;;;5-.....:;0;-' .1** **"1'--,** 2/11/2013 9:46:00 AM 8.533 4.528 3 . 736 4.944 7.376 32.059 66.852 2 /11 / 2013 9:47:00 AM

## rl...,1~**0:i:.0::i3;.7--:5i". 1i':1;;8-,**  4.584 9 . 474 10.135 48 . 663 240.9391 21 11 / 2013 9:48:00AM 7.067 1.039 2 .582 5 .42 12.062 39 .337 179.542 2/11 / 2013 9:49:00 AM 20.852 0.078 2 .513 0.278 13 .338 33 .9 24 71 . 114 2/111 2013 9:50:00 AM 20.954 0.066 0.497 0.153 13 .333 34 .266 61.765 2111/2013 9:51 : 00 AM 20 . 966 0.065 0.03 0.143 13.347 34 . 378 50.024 2111/2013 9:52:00 AM 20 . 972 0.065 0 . 035 0.137 13.32 34 . 202 55.886 2/11/2013 9:53:00 AM 2/11/2013 9:54:00 AM 2/11/2013 9:55:00 AM 211 1 /2013 9:56:00 AM 21 11 / 2013 9:57:00 AM 211 112013 9:58:00 AM 2111/20 13 9:59 :00 AM 211 1 /2013 10:00:00 AM 2111/201310:01:00AM 2/11/2013 10:02:00AM 2/11/2013 10:03:00 AM 2111/2013 10 :04:00 AM 2I11/201310:05:00AM 2I 11 / 201310:06: ooAM 21 11 / 201310 : 07 : ooAM 21 11 / 2013 10 :08:ooAM 211 1 / 2013 10:09:00 AM 2/11/2013 10:10:00 AM 2/11/201310:11:00AM 2/11/201310:12 : 00AM 2/11/201310:13 : 00AM 2111/2013 10:14 :00 AM 2111 /201310:15 :ooAM 211112013 10 :16:00 AM 2I11/ 201310 : 17:00AM 2111/2013 10 : 18 :00 AM 2/1112013 10:19:00 AM 2111/2013 10:20:00 AM 2111/2013 10:21 :00 AM 2/11/2013 10:22:00 AM 21 11 /2013 10:23:00 AM 21 11 / 2013 10 :24 :ooAM 21 1112013 10 : 25 :00 AM 2111/2013 10 :26:00AM 21 11 /2013 10 :27 :00AM 2111/2013 10 :28:00AM 2/1112013 10:29:00 AM 2/11/2013 10 :30:00 AM 2111/2013 10:31:00 AM 2111 / 2013 10 :32:00 AM 211112013 10 :33:00 AM 211112013 10:34:00 AM 2111 / 2013 10: 35 :00 AM 2/1112013 10:36:00 AM 20.979 20.983 20 . 989 20 . 993 20 . 997 17 . 673 13 . 221 13 . 207 13.216 13 .21 5 13.225 13 . 234 13.25 13 . 234 1 3.223 13 . 222 1 3.227 13 . 222 13.219 13.219 13.211 13.227 13 .218 13.205 13 . 222 13.252 13.231 13 .254 13 . 255 13 . 26 16 . 098 13 .215 13 .212 13 . 232 1 3.224 13 .211 13.216 13 .233 13 .211 13 . 201 13.209 13 . 208 13.215 13 . 21 0 .064 0.03 0.178 13.3 34.346 64.216 0.063 0.028 0.166 13.305 34.76 56.504 0.063 0 .05 0 . 157 13.221 35.135 47.33 0.063 0 . 037 0 . 156 13.308 34.836 50 . 414 0.063 0 . 035 0 . 155 13 .297 35 . 131 44.855 2.145 1 .2 75 0.357 13 .287 35 .055 45.96 4.519 3 .2 45 1.141 13.275 35 . 165 42.413 4.527 3 . 175 1.236 13.294 34 .716 47.396 4.524 3 . 119 1.442 13.312 34 .426 54.289 4.526 3.267 1.617 13.293 34.403 58 .571 4.523 3.253 1 . 676 13.317 33.428 70.803 4.521 3 . 125 2.383 13.328 32.282 104.215 4.513 3 .1 52 3 .07 13.312 32 .678 109 .86 4.519 3 .307 2 .922 13.313 32 .899 107.018 4 .527 3 .256 2 .867 13 .291 32 .887 109.561 4 .528 3 .16 3.113 13 .31 32.468 120.845 4.526 3.218 3.325 13 .313 32 .49 122.197 4 . 528 3 . 178 3.414 13.353 32 . 191 130.989 4.532 3.287 3.405 13.352 32.527 121.007 4.528 3.183 3.355 13 .311 32 .81 119.008 4.533 3 .343 3 .073 13 . 327 32 .39 7 114.493 4 .524 3 . 131 3.236 13 .32 32.349 117 .88 4 .531 3 .244 3 . 1 02 13 . 301 32.946 106.015 4 . 543 3 .25 2 .902 13.298 32 . 878 107 .629 4.529 3 . 224 2 . 893 13.359 3 2.279 108.441 4.514 3.266 3 . 196 13 .34 32.576 111.424 4.523 3.422 3.037 13.35 32.287 111.772 4.512 3.234 3.418 13.358 32.005 123.935 4.512 3 . 279 3.463 13.366 31.854 124.21 4.509 3 . 273 3.448 13.343 31 . 868 124.372 2.875 1 .96 4 2 .291 13.342 32 . 151 123 .371 4.531 3 .352 2.975 13 .332 32 .773 101 .839 4.529 3 . 103 2.969 13 .345 32 .30 2 111 .863 4 .5 19 3 . 114 3.133 13 .349 31 .901 119.414 4 . 522 3.079 3.261 13.324 32.231 119.052 4.528 3.222 3.17 13.366 31.798 118.291 4.521 3.098 3.358 13.364 31.26 129.429 4.515 3 .069 3.506 13 . 339 31.782 128.403 4.524 3 . 12 3.241 13.327 32 .087 119 . 159 4 .531 3 . 122 2 .98 6 13.348 32 .0 33 112.072 4.524 3 .0 51 3 . 11 13 . 337 32 .055 115.475 4 . 523 3 .0 54 3 . 017 13 . 329 31.84 117 .541 4 . 517 3.027 3 . 188 13 .324 31 . 952 122.26 4 . 52 3.034 3.232 13.348 31.814 123.56 28 . 618 14.08 0.001 CO bias 0.028 -0.01 02/C02 bia s -0.01 -0.009 NOx bias -0.005 11 .541 18.33 Oirect Zero 22.978 15.313 Direct Span 14.045 10.48 NOx Direct Span 8 . 231 4.687 6.929 8.76 6.598 4.452 5 . 21 3
. 558 3.868 3 .031 4.278 6.216 7.071 12 . 073 24 .5 97 25 . 573 24 .968 Start 1 00% Compliance Test 1 & RATA 1 25 . 926 30.51 30.369 34.33 29 .921 28 . 312 28 . 213 28 .8 21 23 .609 24.429 25 . 239 25 . 847 26.14 31.175 31.588 32 . 171 31 .784 21 .963 27 .04 30 .5 18 30.009 29.871 34.451 34.008 30 . 587 27 .1 94 28 . 534 29 .67 32 . 126 32.049Date T ime 2111/2013 10 :37:00 AM 2111 / 2013 10 : 38 :00 AM 2111 / 2013 10:39 :00 AM 211112013 10 :40:00 AM 21111201310:41:00AM 211112013 10:42:00 AM 

### 0, % 13 . 207 13 . 203 13.207 13.197 13.191 13 . 192 2111/2013 10:43:00 AM 15.938 2111 / 2013 10 :44:00 AM 13 . 208 2I11/201310:45:00AM 13.193 2I11/201310:46:00AM 13.187 2111/201310:47:00AM 13.194 2111/2013 10:48:00 AM 13.197 2111/201310:49:ooAM 13
. 199 2111 / 2013 10 :50:00 AM 13 . 196 2111 / 201310 : 51:00AM 13 .208 2111/201310 : 52:00AM 13.192 2111/201310:53:00AM 13 .185 2111/201310:54:00AM 13 . 182 2111/2013 10:55:00 AM 13.179 211112013 10:56:00 AM 211112013 10:57:00 AM 2111/201310:58:00AM 2/11/201310 :59:00 AM 2111/2013 , 1:00:00 AM 211112013 11 :01 :00AM 2111 / 201311:02:00AM 2111/2013 11 :03:00 AM 21111201311:04:00AM 13 . 177 13.162 13.171 13.163 13 . 162 17 . 735 13 . 1 94 13.179 13.175 2111/2013 11 :05:00 AM 13.178 21111201311:06:00AM 13 . 163 2111/201311 :0 7:00AM 13.166 211112013 11:08:00 AM 13 . 178 2I111201311:09:00AM 13.164 2/11/201311:10:00AM 13.172 2/11/20 13 11 : 11 :00 AM 13.173 2111/201311 : 12:00AM 13.179 2111/201311 : 13:00AM 13.166 2I11/201311 : 14:00AM 13.171 2I11/201311:15:00AM 13.152 2111/201311:16:00AM 13.166 21111201311:17:00AM 2111/2013 11:18:00AM 211112013 11:19:00 AM 21111201311:20:00AM 211112013 11:21:00 AM 2111/201311 :22:00AM 211112013 11 :23:00 AM 2111/201311:24:00AM 211112013 11:25:00 AM 211112013 11 :26:00 AM 2111/2013 11:27:ooAM 2/11/2013 11:28:00AM 2111/201311:29:00AM 2111/2013 11 :30:00 AM 211112013 11:31:00 AM 2I111201311:32:00AM 2111/2013 11 :33:00 AM 2111/201311:34:00AM 211112013 11 :35:00 AM 2111/201311:36:ooAM 2111/2013 11 :37:00 AM 2111/2013 11 : 38:00 AM 2111/2013 11 :39:00 AM 13.164 13.169 13.172 13.149 5.232 0.185 0.167 0 . 157 9.036 10.041 8.736 0.26 0.155 0.457 0 . 605 0.209 0.104 8 .6 59 10.027 10.034 11 .434 13 . 155 13.141 CO 2 NO x CO % PPM PPM 4 .521 3.036 3.207 4.526 3 .0 5 2 . 99 4.524 2 .984 3.101 4.528 2.967 3 . 034 4.529 3.063 2.986 4.53 3.002 2.946 2.948 1 .905 1.967 4.521 2 .908 2.72 4.531 2.972 2 .757 4 .53 4 2.938 2 .571 4.529 2.901 2.829 4.528 2.952 2.704 4.525 2 .90 1 2.91 4.529 2 .899 2.71 4.521 2.748 2.933 4 . 533 2.868 2 .737 4.542 2.911 2.488 4 .548 2.922 2 .263 4.549 2.847 2.284 

### 0, % 13 .329 13 . 319 13.31 13.294 13.284 13.296 13 .293 13.288 13.271 13.294 13.292 13.306 13 .298 13 .3 14 13.294 13.28 13.273 13.266 

### NO, 

### PPM 32.363 32.214 32 .097 32.109 32.203 32.242 32 . 236 32 . 36 32.966 32.542 32.715 32 . 341 32 .672 32.21 32.606 32.946 33.559 33.587 CO 

### PPM 115 115.394 119.689 118 .514 115.748 114.07 117.193 112 .733 104.941 107.106 111.473 111.962 116.533 117 .075 120.056 109.534 97.155 93.202 

### THC PPM 28.618 29 .22 8 30 .744 30 . 264 28 . 756 27.777 29.335 27 .485 23 . 977 24.941 26.68 27.449 29 . 236 29 . 709 30 . 544 26.069 20 . 701 19.247 13.269 33.391 95.262 20 .096 4.551 2.786 2 .225 13.264 33.456 95.135 19 . 961 4.558 2.768 2.105 13.252 33.482 95.05 20.132 4 .55 4 2.772 2.132 13.26 33.497 94.64 19.743 4.56 2.859 1.986 13.268 33.762 85.923 16 . 176 4 .561 2 .734 1.884 13.258 34.221 81.039 14 . 124 1.919 1 . 171 0.881 13 .254 34.164 78.271 13 .30 2 4.541 2 .955 1.572 13 .263 34 .24 77.263 13.145 4.548 2.998 1 .767 13.258 34 . 272 78.154 13.327 4 .548 2.963 1.772 13.257 34 . 193 79.875 14.517 4.547 2.928 1 .8 31 13.23 34.42 75.082 12.258 4.552 2.953 1.734 13.24 34.168 77.609 13.297 4 . 55 2.947 1 .776 13.241 34 .341 73.927 11.896 4.543 2.937 1 . 6 13 .2 1 34 . 581 69.496 10.652 4.551 2 .9 25 1.603 13 . 215 34 . 682 68 . 261 10.159 4.546 2.938 1.589 13 . 215 34 . 519 69.653 10 .712 4 .544 2.974 1.602 13.229 34.442 66.699 9.539 4 . 538 2.817 1 .652 13.256 33 . 775 78.538 13.744 4.548 2.858 1.656 13.271 33 . 668 77.911 13.587 4.541 2.8 11 1 .681 13 .256 34 .201 77.147 13 .035 4.55 3 1.551 13.277 33.367 82.687 15 .449 4.541 2.814 1.99 13 . 284 33.04 94.278 19.753 4 .543 2.775 2.155 13.287 32.78 104.788 24.681 4.54 2.73 2 . 179 13.278 33 . 115 98.171 21.529 4 .54 2 .6 51 2.034 13 . 274 33 . 053 101.122 22.878 4.554 2 . 963 2.1 11.696 32.592 91.549 18.72 1.477 1 . 3 4.149 0.158 1.884 193.71 3.9 0.03 0.044 9.286 0.056 0 . 868 242.691 0.002 0.021 0.036 9.503 0.033 0 . 732 

# I 242.8451 0.002 CO bias 0.017 0.033 9.513 5.869 4 .088 198.816 2.154 4.788 0.034 3.095 10 . 105 0 .62 8.491 0.011 5.079 0 .037 -0.317 10 . 117 0.537 -0.11 6 -0 .01 02lC02 bias 4.252 0.266

-0.349 4 . 143 25.67 -0.054 -O.Q1 0.047 2.522 -0.098 0.047 48 .556 0.267 -0 .009

## L..::0**.~0::26 ~_~2'i** **.5 ~3::-_::0.~0~15~_~0** **~0:;;31~_4,:,8:i' .5~8:i'5_-::0.;;:** **2.,:42;:-._-::-O;: .0::1** **i-1INOX** bias, THC Zero 0.036 2.384 0 .006 0.03 12.82 0.323 2.306 0.046 1.529 0 .023 0.03 0.422 0 .518 32 .223 0.002 0. 117 0.011 0.044 0.182 0.327 47.512

## L..-O.;::,:.0:;:0:;.8_....,;0;;:**.0:,;3;,-_;;0.;;0;;09;.... _:,** **0.::;0 ;;31:..---:;;0** **.~1 ;,23::,....--:;:,0.;.:1;:,05:::-_4;;7,;;** **.9;::6;;3 ..JID** **irect** Zero ; THe Mid 4.537 2.008 7.861 7 .65 32 .3 41 54.172 48.012 5.102 2.532 9.72 10 .087 48 . 815 239.701 48.099 5 .1 2.522 9.537 10.093 48 .78 243.01 

# I 47 .19 8 Direct Span 4.542 2.773 5.929 8 .321 37.734 144.759 35 .846 4.521 3 .09 6 2.379 13.248 32.936 96.056 22.227 4 .537 2.945 2.173 13.26 32.686 100.24 22.528Dale Time 2I11/201311:40:00AM 2I11/201311:41:00AM 2/11/201311:42:00AM 2 /1 1/2013 11 :43 :00 AM 2I1 1 / 201311 : 44 : 00AM 2I 11 / 201311 : 45:00AM 2I1 1 / 201311 : 46 :00 AM 211112013 11 :47 :00 AM 2111/2013 11 :48 :00 AM 2I1 1/20 1311 :49:00AM 2I11/201311:50:00AM 2/111201311:51 :00 AM 2I11/2013":52:00AM 2/11/2013 1' :53 :oo AM 2I11120131 1 :54 :oo AM 2111 / 201311 :55:00AM 2111 / 201311 :56:ooAM 2111 / 201311 :57:00AM 211112013 11:58:00 AM 2/11/2013 11:59:00 AM 2111/2013 12 :00:00 PM 2111/2013 12 :01 :00 PM 2111 / 2

0 13 12:02 :00 PM 2111/2013 12 :03:00 PM 2111 / 2013 12:04:00 PM 21111201 3 12:05:00 PM 2 / 11/2013 12:06:00 PM 2/11/2013 12:07:00 PM 2/11/2013 12:08:00 PM 2/11/2013 12 :09:00 PM 2111/2013 12:10:00 PM 21111201312:11:00 PM 2I111201312: 12 :oo PM 21 11 / 2013 12 : 13 :00 PM 21 11 / 2013 12 : 14 :00 PM 2 /11 / 2013 12 : 15 :00 PM 2/11/2013 12:16:00 PM 2/11/2013 12:17:00 PM 2/11/2013 12;18:00 PM 2111/2013 12 : 19 :00 PM 211 1 / 2013 12 : 20:00 PM 211112013 12 : 21 : 00 PM 211112013 12:22:00 PM 2111/2013 12:23:00 PM 2/11/2013 12 :24:00 PM 2/11/2013 12:25:00 PM 2/11/2013 12:26;00 PM 211112013 12:27 :00 PM 2111/20 13 12:28 :00 PM 2111/2013 12 :29 :00 PM 

### 0, % 13 . 164 13 . 163 1 3.151 13 . 184 13.202 13 .1 87 13 .1 88 13 . 16 1 3.159 13.16 13.173 13.185 13 . 153 13.135 13 . 149 13 . 111 13 .1 24 16 . 839 13.186 13.161 13 .17 4 13.174 13 . 196 13 . 185 13 . 187 13 . 172 13 . 177 13 . 179 13.173 13 . 177 13 . 192 13 . 187 13 . 198 13. 191 13 . 184 13 . 188 13 . 184 16.441 13 . 212 13.187 13 . 179 13 . 174 13 . 162 13 . 159 13 . 156 13 . 155 13.157 13.156 13.164 13.178 21111201312 : 30 : 00 PM 13 . 174 2111 / 2

0 13 12 : 31 :00 PM 13.172 211112013 12:32 :00 PM 13.168 21111201312:33:00 PM 13.178 2/11/2013 12:34:00 PM 13.174 2111/2013 12:35 :00 PM 13 . 176 2I11/201312:36:00PM 13. 181 2111/2013 12:37:00 PM 16.821 211112013 12:38 :00 PM 13 . 1 9 1 2111 / 201312 : 39 : 00PM 13. 173 211 11201312:40;OOPM 13.176 211 1 / 2013 12:41 :00 PM 13.169 21111201312:42:00PM 13.165 

## co, % 4.523 4.523 4.529 4.505 4.494 4.508 4 . 505 4 .526 4.528 4.529 4.519 4.512 4 .536 4 . 548 4 . 543 4.568 4.56 2.421 4.525 4.54 4.535 4.534 4.515 4.522 4.523 4.537 4.534 4.532 4.537 4.535 4.521 4.525 4 . 518 4 . 525 4 . 533 4 .528 4.529 2.648 4.512 4.524 4.53 4 . 533 4 . 54 4 .541 4.543 4.544 4.542 4 .542 4 . 537 4 .528 4.531 4.531 4.534 4.528 4.531 4 . 531 4.524 2.428 4 . 514 4 . 527 4 . 527 4 . 531 4.533 NO, PPM 2 . 815 2 . 85 2 . 779 3 .69 6 3.055 2 . 779 2 . 525 2 .632 2 . 776 3 . 08 3.651 3.012 3 .012 3
.006 2 .645 2 .965 2 .947 1 . 632 3 .024 3.116 2.964 3.915 3.099 2.777 2.701 2.887 2.854 2.819 2.848 2.784 2.805 2 .8 39 2 .71 2 . 664 2 . 721 2 .6 21 2 . 583 1 . 529 2.786 2 . 84 2 . 95 3 . 003 2.97 3 . 007 3 . 021 2 . 969 2.9 2 .867 2 .811 2 . 795 2 .829 2.759 2 . 682 2.681 2.728 2.653 2 . 712 1.452 2 . 868 2 .848 2 . 785 2 .808 2 .8 25 

### CO PPM 2 . 357 2.467

3 0.865 0.148 0 . 19 0.5 1 2 . 259 2 . 811 3 . 226 1.528 0 . 265 0.257 0.415 1 . 361 2 . 305 2 . 692 1 . 709 3 . 039 3.315 3.474 2.333 0.488 0 .50 2 0 . 936 1.29 1 . 891 2 . 126 1 . 899 2 . 127 2 . 234 2 . 223 2.206 1 .954 1.625 1 .35 1 1 . 396 0 . 916 1.421 1 .786 1 . 847 1 . 866 1.835 1 . 642 1 . 596 1 . 664 1 . 938 2.283 2. 6 78 2 .647 2 . 713 2 . 817 2.723 2.914 2.646 2.696 2.808 1 . 758 2.473 2
. 544 2 . 55 2 . 42 2.503 

### 0, % 13 . 279 13.274 13.288 13.314 13.303 13 . 294 13 .296 13 . 263 13.284 13.292 13.296 13.29 1 13 . 306 13 . 284 13 . 265 13 . 27 13 . 282 13 . 284 13.274 13.279 13 . 28 13 . 287 13 . 277 13 . 297 13.269 13.278 13.289 13.261 13.272 13.297 13.291 13.303 13.285 13 . 272 13 . 268 13 . 282 13.279 13.27 13.255 13.245 13.223 13 . 213 13.208 13 . 213 13.22 13 . 218 13.205 13.234 13.241 13 .268 13 . 246 13 . 22 13.259 13.247 13.249 13.242 13 . 25 13 . 224 13 . 223 13 . 224 13.228 13.234 13 . 22 NO, PPM 32.534 31.741 37.77 39 . 121 36 .449 36 . 096 32 .66 8 32 . 181 31 . 356 34 . 657 37.015 37 . 042 36 . 656 33 . 857 32 . 755 32.366 32 . 346 32 . 251 32 . 124 31.836 34 . 993 36 . 34 37 . 143 34 . 852 34 .635 33 .679 33 . 2 33.864 33 . 271 33 . 153 33.2 33 . 126 33 . 309 33 . 723 33 . 984 33 . 581 33.627 33.679 33.503 33 .648 33 . 798 33 . 887 34 . 226 34.029 33.936 33 . 584 33.139 32.739 32.696 32.296 32.264 32.28 31.815 32.507 32.397 32 . 186 31 .8 63 32.421 32 . 578 32.522 32.837 32 .8 35 32 . 599 

### CO PPM 108.847 123 . 685 86.846 13.841 14 . 528 23.496 73 . 698 124.009 142 . 823 115 . 755 23 . 988 22.16 23.474 49 . 377 102 . 665 122.938 126.243 125.419 134.732 131.926 122.866 19.737 19.699 35 . 267 48.973 69.809 88.112 81.728 85.912 92 . 354 95.837 90 .993 92 . 261 79.013 54 . 498 66.664 62.868 64.17 70.782 76.168 75.739 76.19 71 .447 68.483 69.025 72.957 89.128 98.762 103 . 782 108 . 94 111.631 114.703 124.366 116.334 112.498 119.216 123.854 117.435 109 . 746 107.573 102.615 101 . 848 110.113 

### THe PPM 26 . 179 31.977 20 . 282 -0 . 009 -0.009 0. 17 14 . 808 32 . 295 39 . 716 29.76 0 . 129 -0.01 -0.01 6 .034 24 . 465 30 . 993 33 . 113 32.511 36.466 34.74 33 . 474 0. 166 -0.0 1 1 .67 4 4.7 11 . 331 17 .957 15 . 329 17 . 188 19 .461 21 . 312 19 . 761 20 . 283 14 .654 9.185 10 . 523 8.897 9.292 11.519 13 . 249 13 . 336 13 . 489 11 . 836 10 . 788 11.444

12.7 18.661 22.513 24.951 27 .40 5 28.44 29 .072 34 . 533 29.706 28.257 31.125 33 . 981 30.452 26 . 883 26.17 24.02 24 . 144 26.967O 2 CO 2 NO x CO Date Time % % PPM PPM 

### 0, % 2/11/2013 12:43:00 PM 13.157 4.534 2.79 2.745 13.217 2/11/2013 12:44:00 PM 13.164 4.527 2.793 2.926 13.21 2/11/201312:45:00PM 13.145 4 .536 2.86 2.823 13.202 2/111201312:46:00 PM 13.134 4.538 2.801 2.75 13.189 2111/2013 12:47:00 PM 13 .143 4 .53 1 2.685 2.711 13.185 2111/2013 12:48:00 PM 13.139 4.534 2.783 2.621 13.179 2111/201312:49:00 PM 13.13 4.54 2.79 2.512 13.174 2111/2013 12:50:00 PM 13.119 4.547 2.9 2.54 13.189 2111/2013 12:51:00 PM 13.128 4.544 2.849 2.551 13.197 211112013 12:52:00 PM 13.124 4.549 2.909 2.496 13.199 211112013 12:53:00 PM 13.127 4.548 2.841 2.476 13.201 211112013 12:54:00 PM 13.129 4.548 2.908 2.433 13.198 2111/2013 12:55:00 PM 13.128 4.551 2.877 2.33 9.22 2/11/2013 12:56:00 PM 5.274 1 .658 1 .355 4.291 0.074 2 /11 /20 13 12:57:00 PM 0.191 0.034 0.04 9.182 0.044 2 /11 /20 13 12:58:00 PM 0.178 0.023 0.032 9.49 0.031 2111/201312:59:00 PM 0.172 0.019 0.035 9.505 4.258 2111/2013 1:00:00 PM ....,5::,;.:;;52:,:9;,........;2;;;.9;,;';;,3_...;;.0.;;,03:;:5;..., 6.494 10.01 2/11/2013 1:01:00 PM

### LI-":::0;:;.0~'6::.........:5~.0:::6~6_~0.~03:::6:...J -0.003 10.029 211112013 1:02:00 PM 9.728 4.895 0.065 -0.351 10.038 NO, PPM 32.113 32.276 32.199 32.124 32.304 32.516 32.545 32.549 32.607 32.595 32.644 32.814

26.5 1.137 0.868 0.739 0.917 0.595 0.523 0.47 

### CO PPM 120.677 119.395 121.694 119.433 117.908 113.128 111.953 111 .11 111.052 106.728 107 .829 105.663 109.314 219.094 242.752 1 243.0791

217.041

15.1 -0.127 -0.199 2/1112013 1:03:00 PM
....**;;.0.:::4~66::...._;;.0.;:;0;;.8;'**_....;;2;;;.4.;2;'
__**-:;:0;,;.':;2.:.7_...;'.;;.5;:8;,........;38~.2:.;'.;2_..;-:;:0~.0:;:0~5..,** 211112013 1:04:00 PM LI_0;:.,:,17;:4;,.......;0::,.0;:;2;;,5_....;;2.;;.53:;:2;.-....;0::,.0:;:0;;4_....;;0.;;,03:;:5:........::48;:.;;.66,,2:.........,::,0.:;;2::;38:,..J 2/1112013 1:05:00 PM 8.821 4 .5 45 2.535 4 .302 5.898 48 .285 68.717 2/1112013 1:06:00 PM
....**':.::0~.0:::3::.7_....::5.;:;0;:96:;...._.;2:.::.5:;:34;:...._;9.;;;4;;.65:;...._':.::0~.0:.::5::.7_..:4:.::8:;:.8:.;'.::4_.;2:.4';'.;:'5;::5:...,** 2111/2013 1:07:00 PM LI ,.;':::0;,::.0;::44:.........:5:;:.0:;9;;,5_....;2.:;;52:-,;7_.....:9:;:;.5:;5.::,3
__ ':,::0:;:;.0;:;64:....-,;48::,; .;;.67:,:9 ;,....:;2;::43::,;.:;;39::4:.J1 2/1112013 1:08:00 PM 4.046 1.425 0.86 4 .861 4.69 24.647 126.85 211112013 1:09:00 PM ..... 0;:,,;;' 0;;7,.......,;-0;:.0.,1;:;6_....;;0.;;.02:;:7,........;0;:.0;;7;;.6_....;:0".0,;;3:-....;0;;,.1:;6;;.8_....;;0.;:;30:;:2;-, 211112013 1: 1 0:00 PM

## LI_::;0.~1**0:::2:.........::-0:::,.0;':;:8;,......;;.0.;:;0;:28::.......,;0:;;.0;,; :;:8_...;;.0.:;:02;:7;,......,;0:,;..':.:2;::,2_...::0..:.1::.01~**  2/11/2013 1:11:00 PM 11.068 0.575 0.668 0.106 8.906 19.144 26.915 2/11/2013 1:12:00 PM 13.236 4.49 2.726 1.904 13.213 32.479 104.739 2/11/2013 1:13:00 PM 13.156 4 .5 21 2.771 2.504 13.219 32.63 105.728 2/11/2013 1:14:00 PM 13.155 4 .525 2.791 2.466 13.22 32.836 103.139 2/11/2013 1:15:00 PM 13.155 4.53 2.823 2.453 13.219 32.747 105.117 2/11/2013 1:16:00 PM 13.154 4.531 2 .877 2.501 13.222 32.601 105.85 2111/2013 1:17:00 PM 13.156 4.528 2.721 2.455 13.2 19 32.706 105.167 2111/2013 1:18 :00 PM 13.139 4.537 2.862 2.376 13.2 12 32.686 102.603 2111/2013 1:19:00PM 13.146 4 .532 2.733 2.344 13.205 32.645 103.1 211112013 1:20:00PM 13.135 4.534 2.875 2.364 13.211 32.888 100 . 109 2111/2013 1:21:00 PM 13.115 4.546 2.628 2.116 13.205 33.142 96.68 2/11/2013 1:22:00PM 13.102 4 .554 2.705 2.071 13.194 33.034 96.546 2 /1 1/2013 1:23:00 PM 13.102 4.551 2.722 2.061 13.197 33.005 93.301 2/11/2013 1:24:00 PM 17.436 2.045 1.233 1.254 13.196 32.932 93.28 211112013 1:25:00 PM 13.166 4.519 2.816 2.082 13.194 32.993 92.038 2/11/2013 1:26:00 PM 13.134 4.531 2.854 2.435 13.2 33.045 92.133 2/11/2013 1:27:00 PM 13.129 4.537 2.834 2.395 13.2 33.099 92.574 2111/2013 1:28:00 PM 13. 132 4.538 2.798 2.392 13.215 32.691 95.116 2111/2013 1:29:00PM 13. 145 4.535 2.797 2.417 13.214 32.563 99.751 2111/2013 1:30:00PM 13.142 4.539 2.901 2.499 13.212 32.413 98.137 2/11/2013 1:31:00 PM 13.15 4.538 2.76 2.514 13.206 32.715 100 .078 2111/2013 1:32:00 PM 13.148 4 .544 2.855 2.445 13.207 33.032 92.964 2111/2013 1:33:00 PM 13 .139 4.554 2.909 2.232 13.195 33.235 86.712 2/11/2013 1:34:00 PM 13.13 4.563 2.974 2.155 13.194 33.158 88.059 2/11/2013 1:35:00 PM 13 .135 4.563 2.973 2.171 13.193 33.434 82.497 2/11/2013 1:36:00 PM 16 .506 2.62 1.646 1.25 13.193 33.482 82.111 2111/2013 1:37:00 PM 13.163 4.554 3.035 1.9 13 13.2 33.519 77.211 2111/2013 1:38:00 PM 13.154 4.56 3.025 1.974 13.203 33.41 78.995 2111/2013 1:39:00PM 13.149 4.565 3.002 2.13 1 3 .2 11 33.286 79.969 211112013 1:40:00 PM 13.157 4.56 2.978 2 . 198 13. 227 33.234 83.468 2/11/2013 1:41:00 PM 13.157 4.563 3.065 2.121 13.233 33.125 84.066 211112013 1:42:00 PM 13.152 4.567 2.903 2.152 13.22 33.368 82.666 2111/2013 1:43:00 PM 13.155 4.565 2.91 1.991 13.22 33.386 78.742 2/11/2013 1:44 :00 PM 13.158 4 .569 2.766 2.01 13.203 33.896 79.232 2/11/2013 1:45:00 PM 13.128 4.584 2 .792 1.738 13.213 33.627 77.433 THC PPM 31.935 30.964 32.46 31.011 30.282 28.043 27.751 27.027 27.552 25.04 26.085 25.002 24.947 1.144



# ° ° 0.137 -0.01 -0.011 -0.011 -0 .011 CO bias
02lC02 bias
-0 .011 NOx bias 4.199 25.911 26.316 Direct Span 24.361 26.006 22.739 Direct Zero 24.715 25.648 25.181 23.757 24.848 25.196 24.664 23 .708 23.861 22.561 21.093 21.274 19.423 19.457 19.167 19.115 19.38 20.936 22.753 21.995 22.172 19.268 16.888 17.586 14.837 14.954 13.41 14.054 13.944 15.595 15.989 15.247 13.884 14.19 13.37Date 2/11/2013 211112013 

### Time 1:46:00 PM 1:47:00 PM O2 CO 2**NO~** CO O 2 NO x CO 

### % % PPM PPM 

### % PPM PPM 13.155 4.57 2.68 1.9 13.222 33.221 87.183 13.398 4.376 2.731 1.994 13.218 33.334 84.285 2111/2013 1:48:00 PM 16.192 2.872 1 .743 1.183 13.218 33.321 80.311 2/11/2013 1:49:00 PM 13 . 166 4.562 2.896 1.945 13.205 33.19 84.202 2/11/2013 1:50:00 PM 13.168 4 .559 2.901 2.079 13.207 32.998 89.244 2/11/2013 1:51:00 PM 13.157 4 .562 2.851 2.168 13.204 33.363 86.514 2111/2013 1:52:00 PM 13.154 4.565 2.862 2.043 13.215 33.087 86 .066 2111/2013 1:53:00 PM 13.151 4.567 2.756 2.155 13.211 33.109 89.795 2111/2013 1:54 :00 PM 13.133 4.576 2.781 2 . 1 13.211 33.061 89.544 2111/2013 1:55:00 PM 13.131 4.578 2.884 2.098 13.225 32.91 91 .84 2111/2013 1:56:00 PM 13.128 4.58 2.863 2 . 112 13.211 33.465 87.037 2111/2013 1:57:00 PM 13 . 13 4.58 2.834 1.819 13.204 33.803 78 .06 2/11/2013 1:58:00 PM 13.11 4.592 2.87 1.589 13.192 34.002 75 .297 2/11/2013 1:59:00 PM 13.101 4.599 2.757 1.432 8.574 26.293 75 .352 2/11/2013 2:00:00 PM 2.935 0.827 0.902 5.079 0.069 1.098 222.924 211112013 2:01:00 PM 0 .199 0.056 0.034 9.392 0.043 0.869 1242.8031 

### THe PPM 17.38 15.854 14.392 15.655 17.526 16 .81 16.656 18.139 18.07 19.041 17.072 14.006 12.938 9 . 357 0.154 -0.001 CO bias 2111/2013 2:02:00 PM 0.177 0.047 0.03 1 9.512 4.112 0.938 215.791 -0.002 CO bias 2111/2013 2:03:00 PM 0.252 0.159 0.026 9.484 10.029 0.685 14.09 -0.012 2/11/2013 2:04:00 PM**....,9;.6::,;4:::3;..........::5:;:.0:;;3~7_..:;0** . .:;:02;;9:...., 2.353 10.038 0.597 -0.131 -0.013 02 bias 2111/2013 2:05:00 PM LI...;1.;;0.;;.0;:23;;...."""'"5...;.1,,0;;.5_...;:;0 . .;;03;1;,...J -0.318 6.992 11.743 -0.128 -0.013 02/C02 bias 2/11/2013 2:06:00 PM 10.032 5.112 0.033 -0.339 0.06 48.222 0.183 -0.013 2111/2013 2:07:00 PM

### r-6;;;.2;;8;;8~"""'"3:;;.0;;:0;;.5_...;:;0 . .;87:::2:-.....:-0;;.2;;;9;;;2-+....:;;0 .

### .:;02:;;8~....;:48;;.5:;;2;;:9~...;:;0.;23;;;2;,...J -0.013 NOx bias 2111/2013 2:08:00 PM L..,;0;; .**.:;19:::8~.....:;0:;;.0:;;6;2_...;2** . .:;:52;:4;.........:;-0::;.0::;1:;;3.J 0.03 11.555 0.129 -0.014 NOx bias -0.014 2111/2013 2:09:00 PM ,....0;;; ..;,11:;,;4,...."""'"0:;;.0;,;1;;.9_...;:;0 . .;;80::;2:-"""'"0:;;.0:;:2.;.7_...;:;0."02,,8;,.......,0::;.,;.;17:,,...._;0.,,1 0;;,1:-, 211112013 2 :10:00 PM 

# I 0.102 0.009 0.026 0.021 0.028 0.143 0.097 -0.014 Direct Zero 2111/2013 2:11:00 PM 2/11/2013 2:12:00 PM 2111/2013 2:13:00 PM 

### 1 2/11/2013 2:14:00 PM 2/11/2013 2:15:00 PM 2/1112013 2:16:00 PM 2/1112013 2: 17:00 PM 2/11/2013 2:18:00 PM 2/11/2013 2:19:00PM 2/11/2013 2:20:00 PM 2111/20132:21:00PM 2/11/2013 2:22:00 PM 2111/2013 2:23:00 PM 2111/2013 2:24:00 PM 2111/2013 2:25:00 PM 2111/2013 2:26:00 PM 2111/2013 2:27:00 PM 2111/2013 2:28:00 PM 2111/2013 2:29:00 PM 2 /11/2013 2:30:00 PM 2/11/20132:31:00PM 2111/2013 2:32:00 PM 2111/2013 2:33:00 PM 2111/2013 2:34:00 PM 2/11/2013 2:35:00 PM 2111/2013 2:36:00 PM 2111/2013 2:37:00 PM 2/11/2013 2:38:00 PM 2111/2013 2:39:00 PM 2/11/2013 2:40:00 PM 2111/2013 2:41:00 PM 2111/2013 2:42:00 PM 2111/2013 2:43:00 PM 2/11/2013 2:44 : 00 PM 2111/2013 2:45:00 PM 2/11/2013 2:46:00 PM 2/11/2013 2:47:00 PM 5.453 10.037 10.043 12.962 20.865 20.899 20.893 20.895 20.881 15.494 13.834 13 .834 1 3.819 13.83 13.825 13.828 13.812 13.809 13 .811 13 .815 13.826 13.322 13.539 13.814 13.825 13.808 7.033 5.839 13 . 775 13.793 13.794 13.799 13.807 13.821 13.824 13.81 13.806 2.93 1.194 2.237 4.352 17.538 5.116 2.545 9.224 10.065 48 .659 5.114 2.539 9.561 10.074 48.877 1.08 1.277 5.89 12.296 39.968 0.086 0.034 0 . 363 13.914 32 . 098 0.075 0.029 0.142 13.908 32.002 0.078 0.035 0 . 146 13.893 31.735 0.078 0.035 0 . 149 13.888 31.899 0.086 0.D38 0.148 13.886 32.007 3.324 1.245 0.151 13.867 32.173 4.142 1.679 0.262 13.87 31.851 4.146 1.671 0.278 13.853 31.886 4.156 1.712 0.32 13.873 31.319 4 . 155 1.678 0.372 13.877 31.121 4.16 1.725 0.35 13.875 30.996 4.159 1.737 0.358 13.876 31.007 4.163 1.755 0.335 13.861 30.899 4.165 1.721 0.369 13.86 30.14 4.166 1.709 0.428 13 .864 30.022 4.167 1.763 0.416 13.854 30.429 4.162 1.843 0.415 13.876 30.214 3.953 1.876 0.424 13.878 30.318 4.122 1.901 0.392 13.864 30.45 4.162 1.823 0.443 13.861 30.659 4.162 1.858 0.403 13.859 30.464 4.168 1.866 0.446 1 3 .838 30.254 1.968 0.977 0.3 13.832 30.221 1.897 0.801 0.069 13.847 30.068 4.154 1.923 0. 437 13.843 29.993 4.165 2.009 0.451 13.841 29.963 4.168 1.944 0.446 13.858 29.9 4.168 1.879 0.425 13 .847 29.914 4.164 2.025 0.464 13.844 29.762 4.157 1.967 0.497 13 .864 29.594 4.157 1.907 0.479 13.868 29.743 4.16 1 .98 0.468 13.848 29.878 4.165 2.042 0 .497 13.83 1 30.125 15.27 -0.013 222.123 -0.003 243.274 

### 1 -0 .002 167.997 -0 .007 26.654 -0.01 4 25 .51 -0 .0 13 26.354 -0.012 25.797 -0.013 25.317 -0.01 2 24.855 25.69 26.371 28.198 29.112 29.304 29.242 28.912 31.828 33.554 32.63 32.814 32.52 33.174 31.577 31.929 32.643 33.103 33.061 34.207 34.645 34.638 34.623 35.35 37.052 36.79 35.758 34.923 -0 .012 -0.012 -0. 0 11 -0.011 -0.011 -0.011 -0.011 -0.011 -0.011 -0.01 -0.01 -0.01 -0.011 -0.011 -0.01 0.001 0.001 -0.002 -0.005 -0.004 -0.001 -0.009 -0.009 0.002 0.056 -0 .009 0.014 0.028 Direct SpanDale T ime 2/11/20132:48:00PM 2111/2013 2:49:00 PM 2111/20132:50:00PM 2111/20132:51:ooPM 211112013 2:52:00PM 2111/2013 2 :53 :00 PM 2111/2013 2:54:00 PM 2/11/2013 2:55:00 PM 2/11/2013 2:56:00 PM 2111/2013 2:57:00 PM 211112013 2:58:00 PM 2/11/2013 2:59:00 PM 211112013 3:00:00 PM 2/11/20133:01:ooPM 2/11/2013 3:02:00 PM 2/11/2013 3 :03:00 PM 211112013 3:04:00 PM 211112013 3:05 :00 PM 211112013 3:06 :00 PM 211112013 3:07:00 PM 2111/2013 3 :08:00 PM 211112013 3:09:00 PM 2111/2013 3: 10:00 PM 2/11/2013 3:11:00PM 211112013 3 : 12 :00 PM 211112013 3:13:00 PM 2111/2013 3:14:00 PM 2111/2013 3:15 :00 PM 2/1112013 3:16 :00 PM 2/11/2013 3:17:00 PM 2/11/2013 3:18:00 PM 2111/2013 3:19:00 PM 2111/2013 3:20:00 PM 2111/2013 3:21 :00 PM 211112013 3:22:00 PM 211112013 3:23:00 PM 2/11/2013 3:24:00 PM 211112013 3:25:00 PM 211112013 3:26:00 PM 2111/2013 3 :27 :00 PM 2111/2013 3:28 :00 PM 2111/2013 3 : 29 :00 PM 2111/2013 3:30:00 PM 2111/20133:31:00PM 211112013 3:32:00 PM 2111/2013 3:33:00 PM 2111/2013 3:34:00 PM 2111/2013 3:35:00 PM 2/11/2013 3:36:00 PM 2111/2013 3:37:00 PM 211112013 3:38 :00 PM 211112013 3:39 :00 PM 2/11/20133:40:00PM 2/11/2013 3:41:00 PM 2/11/2013 3:42:00 PM 211112013 3:43:00 PM 211112013 3:44 :00 PM 2/11/2013 3 :45 :00 PM 211112013 3 :46 ;00 PM 2/1112013 3 :47 :00 PM 2111/2013 3:48:00 PM 2111/2013 3:49;00 PM 2/11/2013 3:50:00 PM 

### 0, % 13.808 13.822 13 .8 22 13.822 13.821 13 . 803 13 . 806 13.811 13.809 13.807 13 .80 8 13 .809 13.819 13.824 13 .8 32 13.83 13.833 13 .832 13 .8 32 13.836 13.837 13.837 13.836 13 . 835 13 . 837 13.829 13 . 831 13 . 832 13.84 13.82 13.826 13 . 818 13.801 13.798 13.806 13.795 13.79 13.802 13 .803 13 .807 13 .817

13.8 13 .806 13 . 806 13.808 13.816 13.825 13.828 13.829 13 .83 13 .825 13 . 829 13.83 13.823 13.832 13.833 13 .8 32 13 .829 13 .827 13 .829 13 . 824 13.83 13 .833 

## co, % 4.163 4.157 4.157 4.156 4.158 4 . 168 4.168 4.169 4 .17 4.172 4.17 4 . 17 4.166 4.166 4.16 4.166 4.16 4 . 163 4.164 4 . 16 4 . 16 4.161 4 . 159 4 .1 55 4.15 4.154 4.153 4.15 4.144 4.155 4.152 4.159 4.167 4.166 4.165 4.167 4.169 4.165 4 . 167 4.165 4.16 4.169 4.166 4 . 162 4 . 16 4.161 4.168 4.169 4.171 4.171 4.177 4 . 177 4.176 4.179 4.175 4.176 4.18 4 . 185 4.187 4 . 187 4.188 4.183 4.18 

### NO , PPM 2.074 1.994 2 . 107 2 .077 2 .082 2 . 199 2 . 218 2.098 2.119 2.157 2.104 2.115 2.165 2.232 2.208 2.172 2.157 2.234 2.259 2.164 2.283 2.187 2.198 2 . 162 2 . 136 2 . 262 2.263 2 . 337 2.178 1.898 1.938 2 . 216 2 . 326 2.209 2.221 2.291 2.295 2 . 281 2.273 2.297 2.266 2 . 284 2.38 2.191 2.16 2.176 2 .319 2 . 29 2 . 312 2 . 293 2 . 349 2.285 2.274 2.287 2.199 2.181 2.261 2 . 259 2 . 286 2.229 2.305 2.219 2.133 

### CO PPM 0.469 0.473 0.488 0.497 0.509 0.475 0.505 0 . 54 0.508 0.556 0.503 0.508 0.531 0.552 0.591 0 . 56 0.57 0.561 0.558 0.583 0.612 0.601 0.605 0 . 595 0 . 597 0 . 591 0 . 562 0 . 542 0 . 598 1.146 2.047 2 . 045 1 . 568 1.651 1 .583 1.645 1.657 1.621 1 . 721 1 . 816 2 . 102 2.163 1 .917 2 .0 65 2.406 2.56 2.353 2.219 2.221 2.23 1.965 1.725 1.787 1.626 1.762 1.828 1.62 1 .615 1 . 55 1 .671 1.529 1 .473 1.721 

### 0, % 13.865 13.864 13 . 867 13 . 872 13.857 13 . 879 13 .886 13.88 13 .8 79 13 . 882 13.884 13 . 877 13 . 904 13 .906 13.894 13 .902 13.914 13 . 89 13.914 13.917 13 . 91 13.909 13.917 13 . 92 13 .9 14 13.912 13.895 13.914 13.895 13.906 13.915 13.891 13.894 13 .88 4 13 . 882 13 .89 2 13.878 13.885 13.873 13.892 13 . 897 13 . 868 13 .861 13 .883 13.883 13.861 13 .867 13 .883 13 . 879 13 . 868 13.853 13.862 13.838 13.854 13.867 13.849 13.86 13.851 13 . 845 13 .844 13.846 13.854 13.862 

### NO, PPM 29 .60 1 29.533 29 .7 49 29 . 335 29.654 29.55 29 . 313 29.369 29 . 412 29 .3 17 29 . 202 29 . 289 28 . 807 28 . 733 28 . 845 28 . 778 28 .587 28 .9 49 28 .6 73 28.579 28 .999 28 . 839 28 . 817 28 .809 28 .645 28.758 28 .8 47 28.591 27 .8 25.507 25 . 123 25.927 25 . 912 26.115 25 . 929 25.833 25.97 25 . 851 25 . 962 25 . 393 25 . 206 25.814 25.543 24.888 24 .76 2 24.915 25.327 25.273 25.273 25.588 26.012 25.689 25.984 25.897 25.548 25.993 26.141 26.198 26 . 189 26 . 207 26 .366 26 . 001 25 . 511 

### CO PPM 35.199 35.914 35 . 573 36.825 35 . 854 35.922 37.436 37.883 37.547 37.473 37.698 37.063 39.798 40.142 40.409 39.995 40.854 40.242 40.117 42.485 41.461 41.96 41.883 41 . 139 42.411 41 . 441 41 . 147 41.275 45.876 90 . 174 124.417 108.692 92.53 94.206 95.986 97.067 94.923 95.298 97.614 110 . 634 124.89 113 . 548 108 . 781 131 .0 73 139.831 147.471 128.077 129.264 125.935 122.807 104.072 99.11 99.729 93 . 938 104.943 100.569 91.967 93 . 037 92.085 99.379 87.895 91.769 107 . 669 

### THe PPM 0.23 0.109 0.07 0.199 -0 .001

-0.008 0.225 0.023 0.06 0 . 132 0.072 0.008 0.193 0.214 0 .093 0 . 139 0 . 298 0.241 0.165 0.35 0 . 374 0.523 0.569 0.194 0.364 0.322 0.204 0 . 291 1 .0 25 15 . 432 30 . 358 21.576 14.578 15 . 545 15 . 554 16 .917 15 . 265 15 . 336 16 . 53 23.353 31 . 759 24 . 627 22.293 36.453 40 .978 46.222 33.545 34.439 32.491 31.235 19.624 17.192 17.953 15.42 19.887 17.463 13.962 14 . 71 14.417 18 . 71 12 . 693 14 . 3 13 21.741Date 2/11/2013 211112013 Time 3 :51:00 PM 3,52,00 PM 2/11/2013 3:53:00 PM 2111/2013 3 :54 :00 PM 2 /11 / 2013 3:55:00 PM 21 11 / 2013 3 :56 :00 PM 2/11 /2013 3 :57 :00 PM 2I1112{)13 3 , 58 ,00 PM 2111/2013 3 :59:00 PM 211112013 4,00 ,00 PM 2I11/20134:01:00PM 211112013 4 ,02 ,00 PM 2111/2013 4 :03 :00 PM 2111/2013 4 :04 :00 PM 211 1 / 2013 4 :05:00 PM 21 1 112013 4 :06 :00 PM 211112013 4:07:00 PM 2/11/2013 4:08 :00 PM 2/11/2013 4:09:00 PM 2111/2013 4"0,00 PM 2111/2013 4:11 :00 PM 211112013 4:12 :00 PM 2111 / 2013 4 :13:00 PM 21 11 / 2013 4 : 14 :00 PM 21 11 / 2013 4 : 15 :00 PM 2111 / 2013 4:16 :oo PM 2111/2013 4 : 17 :00 PM 211112013 4,18,00PM 2111/2013 4 : 19 :00PM 211112013 4 , 20 ,00 PM 2 /11 / 2013 4 :21 :00PM 211112013 4 :22 :00 PM 2111/20 13 4 : 23 :00 PM 21 1112013 4 : 24 :00 PM 2111 / 2013 4:25:00 PM 2 /11/2013 4:26:00 PM 2111/2013 4:27:00 PM 2111/2013 4:28:00 PM 2111/2013 4 :29 :00 PM 211 1 / 2013 4 :30:00 PM 211112013 4 : 31 :00 PM 211 112013 4 :3 2 :00 PM 2111 / 2013 4:33: 00 PM 2111/2013 4:34: 0 0 PM 211112013 4,35,00 PM 211112013 4,36,00 PM 2111/2013 4:37 :00 PM 211112013 4 , 38 ,00 PM 211112013 4 , 39 ,00 PM 211112013 4 ,40 ,00 PM 2111120 13 4 :41 :00 PM 211112013 4 ,42 ,00 PM 2 /11 / 2013 4 : 43 :00 PM 2/11/2013 4 :44 :00 PM 2/11/2013 4 :45 :00 PM 2111/2013 4 :46 :00 PM 2111/2013 4:47 :00 PM 211112013 4:48 :00 PM 211112013 4:49 :00 PM 2 1 1112013 4 ,SO,00 PM 211112013 4 ,51 ,00 PM 211112013 4:52 :00 PM 2111/2013 4 :53:00 PM 

### 0 , % 13 . 824 13 . 829 13 . 821 13 . 817 13 . 81 13 . 804 13 . 772 13 . 773 13 . 776 13.774 14 . 724 15 . 743 13.832 13.831 13 .832 1 3 .834 13.833 13 . 831 13 . 824 13 .83 13.827 13 . 83 13 .818 13 . 8 05 13 . 799 13 . 802 13 . 804 13 . 806 14 . 67 15 . 36 13 . 823 13 . 814 13.8 1 1 13.817 13.819 13.835 13.832 13.831 13.829 13 .831 13 . 823 13.796 13.797 13 .807 13.819 15 .403 15.01 13 . 839 13 . 843 13 . 831 13.829 13 .8 3 13 .8 25 13.801 13.799 13 .801 13 . 794 13 . 806 13 . 756 13 . 761 13 . 765 13 . 769 13 . 787 

## co, % 4.187 4.186 4.191 4 . 196 4.202 4 . 208 4 . 225 4 . 226 4 . 228 4 .227 3.62 3.154 4 . 193 4 . 2 4 . 196 4.192 4.194 4.201 4.202 4 . 197 4.193 4 . 186 4 . 191 4 . 197 4 . 201 4.201 4 . 201 4 . 202 3 . 65 3.367 4 . 192 4 .1 95 4 . 198 4.196 4.195 4.188 4.187 4.19 4 .19 4 4 . 192 4 .1 94 4 . 212 4 . 21 4.207 4.2 3.225 3 .582 4 . 183 4 . 181 4 . 19 4 . 189 4 .1 92 4 . 193 4.207 4.21 4.21 4 . 215 4 . 209 4 . 236 4 . 236 4 . 236 4.24 4 . 231 

### NO, PPM 2.243 2.184 2 . 313 2 . 253 2.364 2 . 319 2 . 185 2 . 28 2 . 15 2.163 1.996 1.527 2 . 322 2 . 288 2 . 316 2 . 451 2 . 347 2.26 2 . 193 2 . 163 2 . 1 2 . 152 2 . 223 2 . 234 2.229 2 .0 59 2.084 2 .0 77

1.9 1 .6 83 2.362 2 .439 2 . 558 2 .642 3 . 15 1 3.152 3.143 3.106 3.017 3 . 06 2 . 833 2 . 538 2 .6 81 2.532 2.578 2.14 2 . 12 2 . 76 2 .6 76 2 . 769 2 . 782 2.72 2 . 579 2 . 629 2.738 2 . 585 2 . 799 2 . 583 2 . 761 2 . 717 2 .7 39 2.699 2.491 

## co PPM 1 .911 1 . 861 1 . 794 1 .9 79 1 . 799 1 . 604 1.436 1 . 279 1 . 231 1 . 228 1 . 265 1 . 062 1.628 1.55 1 . 569 1 . 322 1 . 174 1.258 1.333 1.344 1.469 1.489 1 . 575

1 .4 1 . 39 1 . 285 1.324 1 . 374 1 . 526 1 . 161

1 . 4 1 . 335 1 . 229 1.145 1.089 1.037 1 .053 1 .043 1.03 1 . 014 1 . 044 1 . 058 0.949 0 .915 0.934 0.928 0 . 684 1 . 013 0.977 0 . 886 0 . 922 0.842 0 .8 64 0 . 788 0 . 688 0 . 68 0 .68 0.705 0.68 0 . 675 0 . 711 0 . 738 0 . 727 

### 0, % 13.872 13 .872 13 . 877 13.865 13 .883 13 .875 13 .86 13.876 13 . 863 13.86 13.878 13.88 13.888 13 .8 94 13 . 904 13 . 885 13 . 886 13.877 13.859 13 . 877 13 . 873 13 . 879 13.854 13.854 13 .842 13.846 13 . 866 13.854 13.852 13.86 13.855 13.851 13 . 849 13 .842 13.855 13.867 13.862 13.861 13 .87 13 . 869 13 .8 61 13 . 85 13 .853 13.858 13.873 13.879 13 .884 13 . 875 13 . 881 13 . 85 13 . 852 13 .871 13 .872 13.871 13.884 13 .872 13.887 13 . 868 13.869 13.885 13 .889 13.908 13.943 

### NO, PPM 25 . 2 25 .025 25.072 25 . 16 25 . 263 25.82 25 .969 26 . 137 26.32 26 .086 25 . 647 25 . 779 26 . 179 26 . 241 26 . 249 27 . 017 26 . 764 26.58 26 . 876 26 . 335 26 . 312 25 . 799 26 . 301 26 . 254 26 . 533 26.46 26.426 26 .492 25 . 916 26 . 394 26 .667 26 . 815 26 .9 18 27 . 104 27.32 27 . 121 27.19 27 . 327 27.411 27 . 445 26.996 27 .1 5 27 . 371 27 . 263 27 .203 27.171 27 . 168 27 . 102 27 . 376 27 . 197 27 .3 81 27 .386 27.549 27 . 66 27 . 73 27 .673 27.674 27 . 563 27 . 598 27 . 33 27 . 536 27 . 517 27 .0 52 

### CO PPM 121.053 127.066 125.007 137 . 838 129 . 776 108 . 662 104 . 595 92.304 87.058 90.055 94.382 95 . 181 88 . 665 64.851 86 .049 71.316 68.261 74.345 75.039 77.949 81.901 87 . 147 84 . 435 80 .409 77.234 76.39 4 78.046 79.314 94.202 89.248 76 . 664 72 . 161 67.277 64.487 59.029 59.785 60.119 58.687 57.24 56.467 61 . 277 62 . 89 57.425 56.889 57.513 59.171 60.234 60.482 58.904 56.918 55.924 54.231 53.914 54.112 51.273 52.769 51.004 52.745 52.048 54 .034 53 . 316 53 .S02 56.682 

### THe PPM 29 . 526 32 . 946 32 . 352 40 . 409 35 .757 2 1. 458 20. 844 14 . 216 11 . 92 13 .338 14 .893 14 . 846 12 . 531 11 . 209 11.419 6 .7 32 6 . 081 7 . 853 7 .946 9.005 10.211 12 . 107 11 . 179 9 . 846 8 .872 8 . 551 8 . 954 9 . 392 15.948 13.496 8 . 668 7 . 198 5 . 933 5.104 3.588 3.613 3.672 3.426

3.1 2 . 957 4 . 141 4.416 3.023 3.051 2.954 3.367 3.786 3.688 3 . 4 94 3.119 2.944 2. 478 2.467 2.629 2.034 2 . 371 1 . 773 2. 435 2 .20 4 2.548 2 . 351 2 . 359 2.696O 2 CO 2 NO . CO O2 NO . CO THC Date T ime 

### % % PPM PPM % PPM PPM PPM 2111 / 2013 4 :54 :00 PM 13 . 797 4.226 2 .662 0 .917 9 . 055 20 .754 73.305 4 .443 211112013 4:55:00 PM 1 .666 0.383 0.414 5.411 0.071 0 .829 220.819 0.013 211112013 4:56:00 PM 0.216 0.073 0 .035 9 . 352 0.043 0 . 65 1 242.9431 -0.002 CO bias 2111 / 2013 4:57 :00 PM 0.201 0.068 0 .039 9 .5 2.775 0 .633 233.797 -0.002 CO bias 21 1112013 4:58 :00 PM 8 .594 4 .522 0.03 3 .831 10 .007 0 .5 1 6 31 . 99 -0 .011 211112013 4 : 59 :00 PM

## 1"1-:'~0'i;**04'::9;-.5"'; '-;33;-~0:f** **;;;03;'2"** -0 . 225 10 . 014 0 .463 -0 . 175 -0 .013 0 2lC02 bi as 211 1/ 20 13 5 :00 :00 PM 6 .566 3 .242 0 .81 -0 . 297 3.522 28 . 324 -0 .082 -0 .013 2111 / 2013 5 :01 :00 PM LI..;;; 0.:;2.;;'8;-_,;:0 . :;;08;;,3;-_,;:2 . :;;5,;:'3;-_-O,;;;; .0:;;38;-_:,0. ;;;0;:,39;.-....,4:;;8,;;.2;;;8:;;8
__ 0,;:

. .,.20;;,7,-_-O';;;; ' 0:i:':;-3.JINOX bias; THC Zero 2/11/2013 5:02:00 PM 0. 143 0 .046 0 .693 0 .013 0.03 16 .909 0.142 0 .039 2/11/2013 5:03:00 PM 

# I 0.102 0.032 0.023 0 .028 0 .028 0 . 175 0.103 8 .901 Direct Zero 2/11/2013 5:04:00 PM 7.691 4.081 1.591 3.514 5.639 21 .846 26.29 10 .78 211112013 5:05:00 PM

### r-:':i;0;i**0.,48;---;5...; '-:-49i;-_2:;;** **~53;;4;---i9:'i.3~6;;-4_.,';;;0:'i 0:;-73;-_48;;** **7:'i6;,;9_-;2.;;3';,.2:;i5,..',** 10 . 058 2111 / 2013 5 : 06 :00 PM 

## 1 1 0.0 63 5 . 149 2 . 533 9 . 549 1 0 .072 48 . 8 243 . 2661 8 . 248 Direct Span 2111 / 2013 5 :07 :00 PM 4.646 1 . 169 2 . 302 6 .351 12 .0 94 37.474 175 .721 7 .655 211112013 5:08 :00 PM 19.473 0 .963 0.456 0.474 13 .831 26 .632 72 .595 6 .78 21 11 1 2013 5:09 :00 PM 2111/2013 5:10:00 PM 2/11/2013 5:11:00 PM 2/11/2013 5:12:00 PM 2/11/20135: 13 : 00PM 2/11/2013 5 : 14 : 00 PM 21 11 /20135 : 15 :00PM 21 1112013 5:16 : 00 PM 2/1112013 5 : 17 :00 PM 2111 / 2013 5 : 18 :00 PM 2111 1 2013 5 : 19 :00 PM 211112013 5 : 20 : 00 PM 2111/20135:21 : 00PM 211112013 5 :22 :00 PM 2 11112013 5 :23 :00 PM 211 112013 5 :24 :00 PM 21 11 1 20 13 5 :25 :00 PM 211112013 5 :26 :00 PM 2/11 / 2013 5 :27 :00 PM 2111/2013 5 :28 :00 PM 211112013 5 :29 :00 PM 2/11/2013 5:30 : 00 PM 2/11/2013 5:31:00 PM 211112013 5:32 : 00 PM 2111 / 2013 5 : 33:00 PM 2111 / 2013 5:34 :00 PM 2111 / 2013 5 :35 :00 PM 2111 / 2013 5 :36 :00 PM 2111 / 2013 5 :37:00 PM 21 1 1/2013 5:38:00 PM 2/11/2013 5:42:00 PM 2/11/2013 5:43:00 PM 2111 / 2013 5:44 :00 PM 2111 / 2013 5:45:00 PM 2111 / 2013 5 : 46 :00 PM 2111 / 2013 5:47 :00 PM 2 /11 / 2013 5 :48:00 PM 2 /1 1/2013 5:49:00 PM 2111/2013 5:50:00 PM 2I11/20135:51:00PM 2/11/2013 5 :52 :00 PM 211112013 5 : 53 : 00 PM 2 /1 11 2013 5 :54 :00 PM 21 1112013 5 :55 :00 PM 2111120 13 5 : 56 :00 PM 21 11 / 2013 5 :57 :00 PM 2111 12013 5:58 :00 PM 13 .844 13.798 13.79 13.789 13 . 794 13 . 799 13 .802 13 .81 13 . 786 13 . 783 13 . 785 13 . 775 13.765 13 . 74 13 .753 13 .756 13 . 754 13 .847 1 6. 925 13.829 13.803 13.804 13.827 13 . 822 13 . 832 13 . 8 0 3 1 3 . 799 13 . 785 13 .788 13.778 13 .755 13 . 757 13 . 806 16 . 399 13 . 821 13 . 825 13 .822 13 . 817 13 . 808 13.809 13 . 806 13 . 818 13.821 13 .814 13 .814 13 . 804 13 . 793 4 . 168 2 .786 1 .013 13 .839 4.187 2 .81 1 . 172 13 .822 4.192 2.924 1 . 121 13 .805 4 . 193 2.918 1.117 13.819 4.193 2 .886 1.121 13.84 4 . 193 2 . 769 1.102 13 . 835 4 . 191 2 .864 1.107 13.889 4 . 189 2 . 595 1.044 13.868 4 . 201 2 .691 0 . 89 13 . 872 4.204 2 . 712 0 . 806 13 . 831 4 .205 2.642 0. 837 1 3 .845 4 .211 2.84 1 0 .821 13 . 922 4.219 2 .511 0.808 13 .843 4.23 2 . 677 0.842 13 .84 4 . 228 2.463 0 .884 8 .842 4 . 225 2 . 613 0 .817 0. 07 4 . 226 2 . 759 0 .868 0 .043 4 . 141 2 . 619 0 .912 3 . 78 2.433 1 .506 0 .612 13 .824 4 . 187 2 .625 1 . 102 13 .885 4 .204 2 .674 1 .077 13 .881 4.205 2 .574 1 .067 13 . 928 4.194 2 .593 1.146 13.942 4.197 2 . 692 1 . 164 13 .96 4.191 2 .47 1 .29 13.961 4 .211 2 .819 1 .254 13 .936 4 .21 2 .7 1 2 1.135 13 . 954 4 .218 2 .957 1.143 13 . 954 4.218 2 .875 1.178 13 . 918 4.225 2 . 884 1.061 13 . 918 4.245 3 0.988 13.903 4.248 2 . 928 0.971 13.921 4.199 2 . 739 0 .964 13 . 966 2.74 1 . 69 0 . 765 13 . 961 4.204 2 . 826 1 . 334 13 . 947 4 .201 2 .617 1 .313 13 .943 4.198 2 .951 1.353 13 .933 4 . 199 3 .06 6 1.391 13 . 929 4.197 3 . 133 1.379 13.949 4.195 2 .992 1.372 13.94 4.19 2 .863 1 . 388 13.977 4.184 2 .741 1.478 13 . 958 4 . 179 2 .66 1 .585 13 .941 4 . 185 2 . 704 1 . 624 13 .927 4.186 2 .754 1.58 13 .914 4. 1 94 2.817 1.455 13 . 905 4.201 2.633 1.356 13.918 26 . 557 26 . 552 26 . 714 26.73 26 . 925 26 . 953 26 . 926 27 . 039 27 . 295 27 . 272 27 .221 27 . 223 27 . 22 27.065 18 . 686 0 . 74 9 0. 589 6 . 326 2 6. 199 26. 578 26. 844 26 . 584 26 . 529 26.283 26. 122 26 . 3 2 8 26 . 186 25 . 945 26 . 341 26 . 509 26 . 706 26 . 636 26 . 746 26 .074 26 . 614 26 . 271 26 .2 35 26 . 201 26.31 26.37 25 . 904 25 . 597 25 . 633 25 . 779 26 . 105 2 6. 298 26 . 204 74 .853 71.41 69.369 68.916 67.541 68.591 64.714 63.889 59.876 58.603 58.149 57.217 58.783 60.019 56.853 5 .84 0 . 106 2 . 711 59.1'4 68.403 63 . 866 67 . 747 71 . 76 72 .58 78.769 8 0. 09 8 1 .977 83.571 80.178 72.653 74.177 71 .262 69.458 76 .696 72.483 75 . 02 76.539 78.564 76.641 75.359 80 . 29 86.009 91.446 88 .955 85.967 79 . 37 78.669 7 . 728 6 .879 6.265 6.149 6.014 6.25 4.854 4 .869 3 .994 3 . 501 3.327 3.159 3.526 3 . 853 8 . 784 45 . 244 46 . 703 ITHe M id 44 .462 8 . 2 6 5 5 . 2 5 . 201 5 . 201 5 . 201 5 .201 5 . 201 5 . 201 5 . 201 5 .2 5 . 2 5.2 5.201 5 . 201 5 . 2 5 . 2 5 . 199 5 . 199 5 . 199 5.199 5.199 5.199 5.2 5 . 2 5 . 2 5 .201 5 .201 5 . 2 5 . 2Date 2/11/2013 2/11/2013 Time 5:59:00 PM 6:00:00 PM O2 CO 2 NO x CO O2 NO x CO 

### % % PPM PPM 

### % PPM PPM 13.797 4.201 2.542 1.352 13 .927 25.928 83.189 13.805 4.193 2.46 1.464 13.915 25.666 88.673 2111/2013 6:01:00 PM 13.805 4.193 2.458 1.516 13.939 25.487 91.334 2/1112013 6:02:00 PM 14.256 3.832 2.28 1.571 13.946 25.415 95.349 2/11/2013 6:03:00 PM 17 .999 1.877 1.085 0 .736 13.93 25.824 91.385 2111/2013 6:04:00 PM 13.821 4.18 2.785 1.352 13.923 26.339 78.327 2/11/2013 6:05:00 PM 13.806 4.187 2.596 1.389 13.929 25.955 80.377 2111/2013 6:06:00 PM 13.805 4 .189 2.72 1.434 13.93 26.029 79.319 2111/2013 6:07:00 PM 13.807 4.19 2.653 1.41 13.939 25.966 82.075 2111/2013 6:08:00 PM 13.816 4.187 2.741 1.431 13.935 26.059 81.721 2111/2013 6:09:00 PM 13.81 4 4.19 2.712 1.4 32 13.94 26.118 81.625 211112013 6:10:00PM 13.807 4.195 2.55 1.418 13.938 26.198 78.111 2111/2013 6:11:00PM 13.812 4.197 2.492 1.366 13.939 26.463 74.791 2/11/2013 6:12:00PM 13.809 4 .197 2.98 1.333 13.946 26.292 76.712 2/11/2013 6:13:00 PM 13.807 4.201 3.243 1.293 13.94 26.439 73.232 2/11/2013 6:14:00 PM 13.812 4 .199 3.073 1.326 13.939 26.004 77.954 2/11/2013 6:15:00 PM 13.81 4.202 2.952 1.416 13.949 25.965 80.262 2/11/2013 6:16:00 PM 13.803 4.207 2.837 1.35 13.955 25.822 81.957 2/11/2013 6:17:00 PM 13.804 4 .208 2.881 1.38 13.936 26.09 80.462 2/11/2013 6:18:00 PM 13.808 4.21 2.796 1.338 13.948 26.126 80.755 2111/2013 6:19:00 PM 13.81 4.212 2.622 1.36 13.962 25.962 83.375 2111/2013 6:20:00 PM 12.808 3.755 2.567 1.415 5.162 13 .051 118.33 2111/2013 6:21:00 PM 0.426 0. 103 0.126 6.942 0.058 0.767 240.049 2111/2013 6:22:00 PM 0.219 0.079 0.032 9.389 0.038 0.623 1 242.9371 2111/2013 6:23:00 PM 0.2 0.072 0.027 9.486 7.002 0.623 161 .578 2111/2013 6:24:00 PM 0.2 0.07 0.028 9.5 10.097 0.49 1.735 2111/2013 6:25:00 PM 0.2 0.068 0.028 9.48 10.098 0.445 -0.167 2111/2013 6:26:00 PM 0.199 0.068 0.018 9.483 3.588 28 .674 0.03 2111/2013 6:27:00 PM**~:::8** .**.::38:::8:........:4:;.:.5~ 1::.** **4_~0.~02;;4:....,** 3.872 0.042 48.327 0.218 2111/2013 6 :28:00 PM

### LI_1:;:0;:;.0::;25::.........;5:;..1:;:3.:.1_....:;;0.~02;;7,...J -0. 19 4 1.393 47.274 0.478 2111/2013 6:29:00 PM 10.044 5.141 0.026 -0.33 13.9 25.864 62.944 211112013 6:30:00 PM 5.083 2.405 1.237 -0.263 14.015 25.379 89.617 2/11/2013 6:31:00 PM

## rl....:;;0.;;20;;;7;.........;0;;;.0:;:8;;.8-....,;;2.;;.5;:;19:-....;-0".0;;;1;;;7~ 14.018 25 .333 93.616 2111/2013 6:32:00 PM 0.125 0.048 0.539 0.034 5.3 11 12.407 79.266 2/11/2013 6:33:00 PM 0.102 0.04 0.023 0.032 0.032 0.204 4.136 2/11/2013 6:34:00 PM rl

## ~0 . .;:10::;2:........;0::;.0;3;,.9-....:;;0.;;02;;3;.........;0;;;.0;.;1:;5-...;0.;02;;:8;.........;0;::.1:.::54:::....-;0. ;:10:;:4:-. 2/11/2013 6:35:00 PM 7.422 3.959 1.646 5.528 6.357 1.449 101.974 2/11/2013 6:36:00 PM .-1:;:0;:;.0:;44;.........;5:;:.1;5:;,8_....;.2,;;.5;;:3,.......,;9::;.4;;9;9_....,.:; 10::;.0:;:9;,..., 2.615 243.153 2/11/2013 6:37:00 PM 

## 1 10.052 5.158 2.531 9.562 10.097 4.865 1243.2461 211112013 6:38:00 PM 7.696 2.781 2.607 5.364 10.102 48.409 243.713 2/11/2013 6:39:00 PM 13.788 4.174 2.853 1.744 10.098 48.813 243.62 211112013 6:40:00 PM 13.818 4 .192 3.037 1.662 10.918 48.954 1241.913 2111/2013 6:41:00 PM 13.83 4.193 2.908 1.7**,....;1:;9;.;.1.;;12:......!:28;:;..9::2::9~** 191.179 2/11/2013 6:42:00 PM 13.83 4 .196 2.882 1.676 19.214 24.89 129.29 2111/2013 6:43:00 PM 13.831 4.198 2.753 1.672 19.182 9.587 139.132 2/11/2013 6:44:00PM 13.827 4.201 2.776 1.719 19.133 0 .401 114.055 2111/2013 6:45:00 PM 13.823 4.204 2 .693 1 .638 19.137 0.331 24.391 2/11/2013 6:46:00 PM 13 .816 4.206 2.654 1 .545 19.128 0.289 4.245 2/1112013 6:47:00 PM 13.813 4.207 2.464 1 .632 19.13 0.275 1.21 2111/2013 6:48:00 PM 13.804 4.212 2.456 1.487 19.117 0.263 0.757 211112013 6:49:00 PM 13.804 4.208 2.318 1.512 19.077 0.247 0.685 2111/2013 6:50:00 PM 13.806 4.208 2 .295 1.616 19.064 0.24 0.708 2111/2013 6:51:00 PM 16.464 2.661 1.562 1.339 19.129 0.228 0.705 2111/2013 6:52:00 PM 13 .875 4 .173 3.007 1.503 19.101 0.217 0.707 2/11f2013 6:53:00 PM 13.832 4.19 3.011 1.679 19.101 0.224 0.706 2/11/2013 6:54:00 PM 13.835 4.19 1 2.868 1.682 19.097 0.205 0.657 2/11/2013 6:55:00 PM 13.841 4.189 2.932 1.729 19.097 0. 195 0.684 2/1112013 6:56:00PM 13 .848 4.185 2.692 2.006 19.082 0.186 0 .581 2/11/2013 6:57:00PM 13.847 4.186 2.797 1.891 19 .0 91 0.186 0.563 2/11/2013 6:58:00 PM 13 .842 4.189 2.723 1.866 19.084 0.178 0.587 2111/2013 6:59:00 PM 13.641 4.189 2.659 1.904 19.082 0.177 0.562 211112013 7:00;00 PM 13.834 4 .193 2.634 1.855 19.071 0.171 0.609 

### THe PPM 5.2 5.201 5.201 5.202 5.201 5.2 5.2 5.2 5.201 5.202 5.202 5.202 5.202 5.201 5.201 5.2 5.2 5.201 5.201 5.201 5.201 5.203 5.208 5.208 5.204 5.197 5.197 5.196 5.197 5.196 5.199 5.2 5.2 5.2 5.197 5.197 5.202 5.208 5.209 5.209 5.208 5.209 5.206 5.203 5 .203 5.202 5.198 5.197 5.197 5.198 5.197 5.197 5.197 5.197 5.197 5.197 5.196 5.196 5.196 5.197 5.196 5.196 CO bias CO bias 02 bias NOx bias 02fC02 bias
NOx bias
Direct Zero
Direct Span
NOx Direct 02 H ig h , NOx Mid CO MidDate 2/11/2013 211112013 Time 7:01 :00 PM 7:02 : 00 PM 2/11/2013 7 : 03 : 00 PM 2/11 / 2013 7 :04 :00 PM 21 11 / 2013 7 :05 :00 PM 2111 / 2013 7 :06 :00 PM 211112 0 13 7 :07 :00 PM 2 /11 / 20 13 7 :0 8 :00 PM 2111 / 2013 7 : 09 : 00 PM 2/11/2013 7:10 :00 PM 2/11/2013 7: 11 :00 PM 211112013 7:12 :00 PM 211112013 7: 13 :00 PM 2111 / 2013 7:14 :00 PM 211112013 7:15 : 00 PM 2 /11 / 2013 7 : 16 :00 PM 2111 / 2013 7 : 17 :00 PM 2 /11/20137:18 : 00PM 2I11/20137:19 : 00PM 2/11/2013 7:20:00 PM 2111/2013 7:21 :00 PM 2111/2013 7:22:00 PM 2111 / 2013 7 : 23:00 PM 2111 / 2013 7 : 24 :0 0 PM 2111 / 2013 7 :25 :00 PM 2111 / 2013 7:26 :00 PM 

### 0, % 13 .832 13 . 825 17.316 13 .873 13 .8 41 13 . 836 13 .835 13 .837 13.83 13 . 827 13.817 13 .8 13 . 775 13.759 16 . 889 13 . 839 13 . 829 13.828 13.832 13.837 13.84 13 . 829 13 .811 13 . 776 13 . 789 13 . 786 CO, 

### % NOs. CO PPM PPM 4.193 2 .471 1.767 4.199 2.527 1 .709 2.18 1 .294 1.128 4 . 167 2 .787 1.442 4.175 2 . 758 1.753 4.176 2 .66 1 .72 4 . 175 2 .561 1 .793 4 . 171 2.574 1 .831 4.176 2 .667 1.884 4.178 2.725 1.869 4.185 2 . 725 1.638 4.194 2 . 654 1 . 379 4 . 208 2 . 649 1 . 248 4 . 221 2 . 653 1 .288 2.421 1 . 699 0 . 8 4 . 178 2.7 05 1 . 236 4.186 2 . 756 1 .33 4.19 2 . 628 1.373 4.183 2 . 656 1.307 4.178 2 . 508 1.386 4.177 2 .55 1 . 396 4.186 2.543 1 . 359 4 . 198 2 . 233 1 . 359 4 .219 2 .435 1.29 4 . 216 2 . 338 1 . 184 4.216 2 . 125 1 .258 2/11/2013 7:27:00 PM 13.803 4.211 1 .887 1.424 2111/2013 7:28:00 PM 14 .809 2.614 1.753 1 .237 2111/2013 7:29:00 PM 11.357 4.251 0.154 0 . 027 211112013 7 : 30:00 PM

## 1'"1-:1:::0;;;**0~84:--~5'i 1':'16:--~0i:'.~03~5"'"**  -0.313 2111 / 2013 7 : 31 :00 PM 10 .07 5 . 118 0 .049 -0 . 352 2111 / 2013 7 : 32 :00 PM 10 .081 5 . 116 0 . 106 ..() . 314 21 11 / 2013 7 : 33 :00 PM 10 .064 5 . 115 0 .0 85 -0 .337 2111 / 2013 7 : 34 :00 PM 8.812 3.527 0 .518 -0 .295 211112013 7 : 35:00 PM 1'"1

### i:-**:;;30"'9~--;O~.0"'7;--;"2;; 5:----;-O;;.0;';1;i;6'**  2111/2013 7:36:00 PM 0.152 0 .059 2 .525 0 .034 2111/2013 7:37:00 PM 0 . 152 0.057 2 .298 0.249 2/11/2013 7:38:00 PM 0.13 0.054 0 .035 7.919 2/11/2013 7 : 39 : 00 PM 0 . 127 0.052 0 .033 9.514 2111 / 2013 7:40 :00 PM 0 . 1 09 0.032 0 .023 5.728 2111 / 2013 7 :41 : 00 PM 1'"1

## ~0i:'**:-:10:i2~--;;0" 0"'26;-~0i:'.0;':2:i2~--;;0:':** **1~1;;-6'** 2111 / 2013 7 :42 : 00 PM 0 . 102 0. 0 24 0 .025 0. 0 36 2111 / 2013 7 :43 :00 PM 0.134 0.04 0.018 0 .038 211 1 12013 7 :44 : 00 PM 9 . 53 5 . 112 2.228 6.055 2/11/2013 7:45:00 PM
..

## 1..,1"0"**0:;,49,.........:;5;.;.1.,;37:;--2;;.;;52;;8~....:;9;;;.5:.:;1;.9...,** 2/11/2013 7:46 : 00 PM 10 .061 5 . 136 2.528 9.568 2111/2013 7:47 : 00 PM 10 . 068 5.133 2.524 9.56 2 / 11/2013 7:48 : 00 PM 16 . 802 8.83 3 . 896 9.535 2 /11 / 2013 7:49 : 00 PM 19 . 09 9.733 4 . 839 6.544 2111 / 2013 7:50 : 00 PM 11'"-:1;;9. "0;,:94:---;;9".7"'33:;--4.;.8;.:2;;7;-.....:;4;; .6,;0.;.1..., 211112013 7 : 51 : 00 PM 19 . 043 9 . 744 4 . 765 4.533 2111 / 2013 7:52 : 00 PM 18 . 997 9 . 752 2 . 162 4 . 515 2 /1112013 7:53 :00 PM 18.985 9.751 0.417 4.5 2111/2013 7:54 :00 PM 18 .985 9.75 0 .206 4.464 2111/2013 7:55:00 PM 18 .985 9.745 0 . 135 4.437 

### 0 , % 19 . 05 19.022 19.025 19.015 18 .995 18 .986 18 .978 18.966 18.959 18 . 95 18.944 18 . 939 18 . 944 18 . 954 18 . 954 18 . 95 18 . 968 18 .967 18 .963 18 . 957 18 . 938 18 . 943 18 .947 18 .951 18 .951 18 . 951 18 . 956 18 . 953 18.95 18.934 18 . 909 18 .901 18 .9 13 18 .912 18 . 914 18.913 18.92 18.928 18.917 18.912 18 .899 18.882 18.886 18.882 18.872 18.871 18 . 86 18.847 18.844 18 .847 18 . 84 18.839 18.83 18.823 18.818 

### NO , PPM 0.166 0.165 0.164 0 . 151 0 . 147 0 . 143 0 . 142 0 . 144 0. 142 0 . 144 0.14 0 . 141 0 . 134 0 . 126 0 . 141 0 . 134 0 . 126 0.139 0.128 0 . 128 0 . 127 0. 133 0. 133 0 .1 27 0 . 125 0 . 122 0 . 12 0 . 113 0 . 106 0. 111 0. 1 06 0 . 1 0 8 0 . 109 0 . 109 0. 109 0.11 0 . 109 0.101 0.105 0 . 108 0 . 105 0 . 101 0 . 106 0 . 101 0 . 099 0.103 0 . 101 0 . 096 0 .097 0 .092 0 .095 0. 096 0 . 094 0.088 0 . 084 CO PPM 0 . 589 0.565 0.564 0.561 0. 56 0 . 564 0 . 566 0 . 565 0 .565 0 . 564 0.565 0.563 0.564 0.565 0.564 0 . 565 0 .564 0.562 0.536 0.536 0.561 0.567 0 .515 0 .565 0 . 564 0 . 558 0.561 0.479 0.486 0.468 0 . 538 0.482 0.517 0 . 558 0.559 0.488 0.512 0.513 0.563 0.538 0.561 0.512 0.415 0.435 0.413 0.412 0.413 0.412 0.44 0 .437 0 .413 0.413 0.413 0.439 0.414 THC PPM 5.196 5.197 5.197 5 . 1 9 7 5 . 198 5 . 197 5 . 197 5.197 5 . 197 5 . 197 5.197 5 . 197 5 . 197 5 . 196 5 . 196 5 . 196 5.196 5 . 196 5.196 5 . 196 5 . 197 5 . 197 5 . 197 5 . 197 5 . 197 5 . 197 5.197 5 . 197 5 . 197 5. 197 02 / C02 bias 5 . 198 5 . 198 5 .1 97 5 .1 96 5 . 196 5 . 196 5.197 5 . 198 5 . 197 5 . 196 5 . 196 5 . 19 6 5 . 19 6 5.197 5 . 196 5 . 197 5.198 5 . 197 5 . 197 5 . 198 5 . 198 5 . 198 5 . 197 5 . 197 5 . 197 NOx bias

CO bias D ire ct Zero

Direct Span

D irect H igh**~ ~** **N~** 

# ro**~ ~**  

# ro THC PPM Date Time % % PPM PPM 

### % PPM PPM 2/12/2013 

### 7 :47 :00AM 0.393 6 . 13 0.007 0.42 17.933 L..;;;0 .**.;;01;;6~** 

### 0 .792 2/12/2013 

### 7:48:00 AM 0 . 138 0.111 0.01 0.21 6.812 0.012 0 .712 5.212 Zero/NOx Mode 

### 5.211 2/12/2013 

### 7 :49 :00 AM

## 1r-0';;**';;11;';6~"""'"0;;'.0;';0";'2-""';0:';; 0;';07:--0;'.;;;08":'3""""""'"0;;;** **0;';6':;4-"";;0;;;.0';;11;--0';; "'25;;8;-'**  5 .21 Cal Zero; Zero/NO Mode 2/ 12/ 2013 

### 7 : 50 :00AM 13 .913 7 . 231 2 . 141 3.852 5 . 744 1 . 144 0 .916 5 . 209 2/ 12/ 2013 

### 7 : 51 :00AM 1905 9773 48 9814 19604 4853 179524 5 . 216 2/ 12/ 2013 

### 7 : 52 : 00 AM 2112/ 2013 

### 7 : 53:00 AM 2/12/2013 

### 7:54:00 AM 18 .972 

## I 18 .971

11 .725 9.771 4 . 812 9 . 625 9 . 663 4 . 816 9 . 617 5 . 841 4 . 828 9 . 627 2/12/2013 

### 7:55:00 AM 10.03 5.092 4.826 9.581 2/12/2013 

### 7 : 56:00 AM 

### r-: 1 .;,;0:.;;.0;,;27:,---=5;;;.;,;09,;;...., 1.524 7 . 3 2112/2013 

### 7 : 57:00 AM 16 . 698 1 .071 0 .025 4.829 2/ 12/2013 

### 7 : 58:00 AM 20 . 89 0.068 3 . 325 4.605 2/ 12/ 2013 

### 7 : 59 :00AM 20 .925 0 .063 3 . 856 3 . 113 2/ 1212013 

### 8 :00 :00 AM 20 .934 0 .061 1.201 0 . 675 2112/ 2013 

### 8:01 :00 AM 20 .94 0 .06 0 .019 0 . 309 2/ 1212013 

### 8 :02 :00 AM 20 .919 0 .079 3.278 0 . 257 2/12/2013 

### 8:03:00 AM 20.939 0 .065 4 . 805 0.266 2/12/2013 

### 8:04:00 AM 2/12/2013 

### 8 :05:00 AM 2/ 12/ 2013 

### 8 :06:00 AM 2/ 1212013 

### 8:07 :00 AM 2/ 1212013 

### 8 :08 :00 AM 2 / 1212013 

### 8:09 :00 AM 2 / 12/2013 

### 8:10 :00 AM 2/12/2013 

### 8:11 :00AM 2/12/2013 

### 8:12:00 AM 2/12/2013 

### 8:13 :00 AM 2 / 12/ 2013 

### 8 : 14 :00 AM 2 / 12 / 2013 

### 8:15 :00AM 2 / 12/ 2013 

### 8 : 16 :00 AM 2 / 12/ 2013 

### 8:17 :00 AM 2 / 12/2013 

### 8:18 :00 AM 2/1212013 

### 8:19 :00 AM 2/12/2013 

### 8:20:00 AM 20.931 20 .933 20 .932 20.928 20 .925 20 .923 20 .917 20 .916 20.913 20.907 20.903 20 . 899

20 .9 20 .902 20 .932 20.955 20.955 0.064 4.809 0.255 0.065 4.013 0.236 0 .068 3 . 828 0 . 249 0 .071 2 .609 0 . 24 0 .074 2 .521 0.246 0 .076 1 .49 0.254 0 .077 0 .031 0.254 0.079 0 .033 0.247 0.084 0 .034 0.241 0 .084 0 .028 0 . 258 0 .085 0.026 0 . 26 0 .087 0 .025 0 . 258 0 .089 0 .026 0 . 258 0.091 0 .032 0 . 249 0 .092 0 .072 0 . 264 0.091 0 .031 0.262 0.093 0.028 0.245 2/12/2013 

### 8:21:00AM 18.633 0 .764 0.028 0.43 2/ 12/2013 

### 8 :22 :00 AM

## 1.--:1.;:0;;;.0.:;75,...."""'"5;;;**0"8"'9-....;;0.;: 0~13~**  0 . 193 211212013 

### 8 : 23 :00AM 10.039 5 . 113 0 .015 -0 . 295 2/ 1212013 

### 8 :24 :00AM 8 .968 4 .41 0 . 193 -0.298 2/ 1212013 

### 8 : 25 :00 AM 0 . 274 0 .09 2.496 -0.021 2/ 12/2013 

### 8 :26 :00 AM

## 1~0::-**~154;-::---;0;-;.0i::7':-1--::2-; 5~15;--0;i-** **;i:08;;6,...,** 2/1212013 

### 8:27 :00AM 0 . 139 0 .069 1 .579 2.401 2/12/2013 

### 8:28:00 AM 0.129 0.069 0.013 9.435 2/12/2013 

### 8 :29:00 AM 0.129 0.D7 0 .006 9.607 2/ 12/ 2013 

### 8:30 :00 AM 6 .646 0 .735 0 . 145 8 .083 2/ 12/ 2013 

### 8 : 31 :00 AM 13 .852 4 . 153 1.629 1 .542 2/ 12/ 2013 

### 8 : 32 :00AM 13 .832 4 . 167 1.577 1.481 2112/ 2013 

### 8 : 33 :00AM 13 . 831 4 . 174 1 .633 1.555 2112/2013 

### 8 : 34:00 AM 13 . 833 4 . 175 1 . 581 1.668 2112/2013 

### 8 : 35:00 AM 13.821 4.192 1.648 1.459 2/12/2013 

### 8 : 36:00 AM 13 . 818 4.197 1 .717 1.154 2/12/2013 

### 8:37 : 00 AM 13 . 829 4.194 1.638 1 . 23 2 / 12/2013 

### 8:38 :00 AM 13 . 812 4 . 212 1.701 1.109 2 / 12/ 2013 

### 8:39 :00 AM 13 . 814 4.213 1.868 1.115 2 / 12/ 2013 

### 8 :40 :00 AM 13 . 832 4.204 1 .747 1 . 197 2 / 12/ 2013 

### 8 :41 :00AM 13 .925 4 . 11 1.809 1.23 2 / 12/ 2013 

### 8 :42 :00 AM 17 .91 1.988 0 .778 0.624 2/12/2013 

### 8 :43 :00 AM 13 . 858 4.198 1 .907 1.542 19 .026 4 . 866 244 .456 18 .996 4.877 244.417 

## I 12 .422 4 . 886 226 . 315 10.03 4.885 101.868 10.012 1 . 629 139 .913 15 . 072 0.02 140 . 39 16 . 814 3.301 140 . 364 16 . 811 3 .905 124 .784 16 . 803 1 . 373 99 . 245 16 .744 0.019 98 . 963 15.599 28 . 268 53 . 304 4 .721 48 . 615 53.456 0.D76 

### 0.057 0 .052 0 . 805 0 . 126 0.033 0 .031 0 .032

0 . 3 0 .036 0.03 0 .526 0 .035 0 .03 6 . 375 13 . 818 13 . 848 48.352 28.957 24.664 7 . 378 0 .78 0.498 0.453 0.408 0.926 0.343 0 . 302 1.346 0 . 265 0 . 235 10.222 24.255 24.303 1.13 0 . 336 0 . 326 1.194 7 . 836 0.249 0.276 0.22 0 .904 1.401 0 . 187 2 . 117 2 .474 0 . 187 12 .04 84 . 176 92 .58 13.85 24 . 526 92.331 13.852 24 . 618 92.25 13.852 24 . 58 100.21 13 . 848 25 . 255 82.696 13 . 849 25.088 81.148 13 . 855 24 . 978 82 .072 13 . 872 24.645 92.05 13.883 24 . 564 98.108 13 . 892 24 . 822 95.413 5 . 218 NO/NOx Mode 5.218 Cal Hi9h 5 . 215 NOINO Mode 5 . 209 5.211 02/C02 

### Mid 5 . 211 N02/NO Mode 5 . 211 CO M i d 5 . 21 N02/NOx Mode 5 . 871 6 . 588 NOx Cal Zero 

### 1.822 4.733 -0.007 NOx Cal Hi9h -0 . 007 -0 .006 INOx Mid;THC Zero 0 .031 72.455 NOx Mid 89 . 371 85.036 85.133 ITHC Cal Hi9h 85.469 50 . 078 46 . 953 ITHC Mid 46 . 274 26 . 83 25 .995 ITHC Low 21 . 625 9 .582 10.638 10 . 611 10
. 772 02/C02 

### bias 13 . 69 8 . 102 7 . 753 7 . 916 NOxbias 

### 11.005 12 . 926 12 . 133 CObias 13 . 884 25 . 148 89 .024 10 . 386 13 . 884 24 .962 87.429 9 . 66 Start RATA Run 7 13 . 881 24 . 85 93 . 193 11.762 13 . 879 24 .752 97.439 13 . 31 13 . 877 24.735 99 . 308 13 .922 13 . 862 25.214 85.452 9 . 236 13.866 25.247 83.221 8 . 532 13 . 881 25.242 86 . 698 9 . 867 13 . 886 25 . 315 80 .761 7 . 855 13 .903 25 . 132 87 .099 9 .734 13 .917 24 .903 96 . 209 12 .744 13 .912 25.132 90.233 10 .793 13 .902 25.194 90 .087 11 . 171 13.901 25 .079 92.277 11.804

### O 2 CO 2 

### NO. CO Oate Tim e 

### % % PPM PPM 2/12/2013 

### 8:44 :00 AM 13.837 4 .2 08 1.925 1.525 2/12/2013 

### 8:45 :00 AM 13 . 836 4.207 1.897 1 .55 4 2/12/2013 

### 8 :46 :00AM 13 . 832 4 . 211 1 .958 1.469 2/12/2013 

### 8 :47 :00 AM 13 .828 4.219 2.08 1.349 2/ 12/ 2013 

### 8 :48 :00 AM 13 .832 4 . 217 1.824 1.352 21 12/ 2013 

### 8 :49 :00 AM 13 .83 1 4 . 225 1 . 896 1.406 21 12/ 2013 

### 8 :50:00 AM 13 .832 4.227 1 .943 1.285 2112/2013 

### 8:51 :00 AM 13.833 4 .232 1.855 1.256 2112/2013 

### 8 :52:00 AM 13 .82 8 4 . 24 1.891 1.207 2/12/2013 

### 8:53 :00 AM 14.55 3.679 1 .89 0.973 2/12/2013 

### 8 : 54 :00 AM 14 .324 4 .098 2 . 177 0.916 2/12/2013 

### 8 : 55:00AM 13 .832 4 .232 2 .493 1.062 2/ 12/ 2013 

### 8 : 56:00 AM 13 . 833 4 . 233 2 .469 1.086 2/ 12/ 2013 

### 8 : 57 :00 AM 13 .833 4.234 2 .431 1 . 126 2/ 12/ 2013 

### 8 : 58 :00 AM 13 .832 4.238 2 .481 1 .1 49 21 12/2 013 

### 8:59 :00 AM 13.75 4 . 238 2.32 1.195 2/12/2013 

### 9:00 :00AM 13.747 4 . 25 2.232 1 .17 6 2/12/2013 

### 9:01 :0 0 AM 13.801 4 .26 2.292 1.191 2/12/2013 

### 9:02 :00 AM 13.815 4 .25 2.39 1.156 2/12/2013 

### 9 :03:00 AM 13.826 4 .2 44 2 .475 1.052 2/ 12/2 013 

### 9:04 :00AM 13.838 4 . 235 2.561 1.148 2/ 12/ 2013 

### 9:05:00 AM 13 . 834 4 . 233 2 .53 1.13 2/ 12/ 2013 

### 9 :06:00 AM 13 . 833 4 . 229 2 .553 1 . 183 2/ 12/ 2013 

### 9:07 :00 AM 13 . 825 4 .228 2 . 607 1 . 112 2/12/2013 

### 9:08:00 AM 13 . 824 4.224 2.518 1 . 103 2/12/2013 

### 9:09:00 AM 13 . 828 4.216 2 . 162 1.147 2/12/2013 

### 9 : 10 :00 AM 13 . 829 4.211 2 .054 1 . 183 2/12/2013 

### 9:11:00 AM 13.83 4.209 2.036 1 . 277 2/12/ 2013 

### 9:12 : 00 AM 14 . 167 3.902 2.037 1 .3 12 2/ 12 / 2013 

### 9 : 13 :00 AM 16 . 339 2 . 885 1 . 346 0.891 2/ 1212013 

### 9 : 14 :00AM 13 . 867 4 . 186 2 . 141 1 . 316 2/ 1212013 

### 9 : 15 :00 AM 13 .865 4 . 189 2 . 101 1 .383 2/12/2013 

### 9 : 16 :00AM 13 . 875 4 . 186 2 .057 1.484 2/12/2013 

### 9:17:00 AM 13 . 874 4 .186 2 . 224 1.49 2/12/2013 

### 9:18:00 AM 13 . 869 4.192 2.199 1.649 2/12/2013 

### 9:19:00 AM 13 . 847 4.207 2.434 1 . 529 2/12/2013 

### 9:20 : 00 AM 13 .86 4.201 2.56 1 .3 13 2/ 1212013 

### 9:21 :00AM 13 . 878 4 . 194 2.346 1.416 2/ 12/ 2013 

### 9:22 :00 AM 13 . 875 4 . 196 2.42 1 . 338 2/ 1212013 

### 9:23 : 00 AM 10 .541 2.979 1.887 2.115 2/12/2013 

### 9 :24 : 00 AM 0.193 0.113 0 .021 8 .926 2/12/2013 

### 9:25:00 AM 0 . 13 0.104 0.011 9 .575 2/12/2013 

### 9:26 :00 AM 4.504 2 . 6 0.012 7.255 2/12/2013 

### 9 :27 :00 AM 

## 1...-:1.;;0.;, . 0:,;14:---:5,;;.1"'6..,.4-....:,0".0,::1:....., -0 .074 2/12/2013 

### 9 :28 :00 AM**...,4,;;.:,;70:;;3;-~2;;: 2;:2::;2_** 

### ...... 1.:;;2;,;75;.--,-"'0 . "'19;;2;-, 2/ 12/ 2013 

### 9 :29:00 AM 

## IL-O,;: . ,;;13;.:7,.----:O:,;. .1:,;

1;;.3_....;;2. ;;;5;::08;.-_0,;:.;::05:.;7,.-J 2/ 12/ 2013 

### 9 : 30 :00 AM 6 . 346 2 . 18 2.478 0.375 21 12/ 2013 

### 9 : 31 :00 AM 13 . 831 4 . 202 2 . 371 1 . 381 2112/2 013 

### 9 : 32 :00 AM 21 12/2 013 

### 9 :33: 00 AM 2/12/2013 

### 9:34:00 AM 2/1 2/2013 

### 9:35:00 AM 2/12/2013 

### 9 : 36:00 AM 2/ 12/20 13 

### 9:37:00 AM 2/ 12/ 2013 

### 9 : 38:00 AM 2/ 12/ 2013 

### 9 : 39 :00 AM 2/ 12/ 2013 

### 9 :40 :00 AM 2/12/2013 

### 9 :41 :00AM 13 . 846 13 . 869 13.873 13.872 13.888 13 . 876 13 . 876 13 . 864 13 .86 1 13 .942 4.213 2.505 1 . 376 4 . 205 2 . 321 1 .525 4 . 205 2.472 1.477 4 . 203 2.459 1.514 4.193 2.503 1.681 4.195 2.613 1.763 4 . 192 2.631 1 . 695 4 . 198 2 .687 1.511 4.197 2 . 653 1.505 4 . 108 2 . 622 1.514 

### 0 , % 

### 13.897 13 .89 7 13 .889 13 . 882 13 . 897 13 .891 13 . 892 13 .899 13 .882 13 .8 75 13 . 879 13 . 873 13 . 883 13 . 887 13 .91 13 .92 13 . 917

13 .9 13 .8 78

13 .9 13 . 897 13 . 904 13 . 894 13 . 881 13 . 894 13.896 13.896 13.901 13.908 13 .902 13 .907 13 .919 13 .922 13 .92 1 13 .909 13.887 13.901 13.903 13 .918 13 .92 13.924 13.937 13.909 13 .906 13 . 915 13 .907 13 . 908 13 .915 13 .928 13 .934 13.929 13 .937 13 . 94 13 .917 13 .91 13 .898 13 .902 13 . 901 NO, 

### PPM 25.225 25 . 142 25 . 325 25.646 25 . 286 25 . 665 25 .79 25 . 832 26.315 26 . 501 26 . 347 26 . 234 26 . 115 26 .026 25 . 899 25 . 695 25 . 675 26.183 26 . 641 26 . 267 26.344 26 . 141 26 . 22 26.645 26.335 26.156 26.026 25 .763 25.632 25.869 25.885 25.846 25.475 25.399 25.332 25.938 25.898 25.626 25.551 25.734 25.798 25 . 305 25.779 25 . 804 25.486 25 . 652 25 .58 25.604 25.49 25.407 25.573 25 . 317 25.042 25 . 364 25 .434 25 . 558 25.425 25 . 506 

### CO PPM 85.669 88 . 29 82.405 75.774 80 .977 76.525 73 . 842 73.012

67 . 2 60.327 59.613 60.255 60.993 63.345 63.994 67 . 33 64 .994 62.043 57.927 58.369 60.864 63.473 64 . 701 58 . 642 59 .946 63 . 119 64 . 823 70 .026 72 .75 70 . 889 68 .947 69.343 78.929 76.694 85 .339 71.694 66.436 74.058 72 . 822 74.577 69 .038 78.41 75 .578 70 . 579 72.654 71.686 75 .745

72 .8 73.293 80 . 138 76.138 80 . 233 87 . 696 86 .996 84.275 77.73 79.796 80 . 878 

## THC PPM 9 . 277 10 . 5 8 . 631 6.464 7 .958 6 .907 6 . 229 5 .956 4 . 559 3.112 3.152 3.123 3.191 3 . 628 3 . 52 4 . 3 3 . 858 3 . 293 2.796 2.799 3 . 23 3 . 611 3 .985 2.957 3 . 177 3.652 3 . 926 5 . 206 6 . 169 5 . 504 4 .972 4 .902 7.669 6.741 9.465 5 .683 4 . 723 5 . 961 5 . 665 6 .049 4.766 7.024 CO bias 

### 6.767 5
. 301 02/C02 bias 

### 5 . 572 5.471 

### NOx bias 

### 6 . 603 5 .553 Start RATA Run 8 5 .553 7.379 6.348 6 .937 9 . 175 9 .791 8 . 834 7 . 116 7 . 668 8 . 173

### 0, CO, NO . CO Date Time 

### % % PPM PPM 2/12 / 2013 

### 9:42 :00 AM 16.484 2 .745 1 .577 1.003 2/12/2013 

### 9:43 :00 AM 13 . 827 4.228 2 . 652 1.484 2/ 12/2013 

### 9:44 :00 AM 13 . 827 4 . 228 2.428 1.55 2/ 12/ 2013 

### 9 :45 :00 AM 13 . 827 4 . 233 2 . 35 1.532 2/ 12/ 2013 

### 9 :46 :00 AM 13 . 83 4.232 2 . 329 1.592 2/1 2/ 2013 

### 9 :47 :00 AM 13 . 832 4 . 234 2 . 266 1 . 621 2/ 12/ 2013 

### 9:48 :00 AM 13 . 832 4.237 2 . 281 1 . 68 2112/ 2013 

### 9:49 :00AM 13 . 833 4 . 238 2 . 184 1 .705 2/ 12/2013 

### 9:50:00 AM 13 . 831 4.248 2 . 275 1 . 602 2/12/2013 

### 9:51 :00 AM 13 . 832 4.25 2.379 1 . 327 2/12/2013 

### 9 :52 :00 AM 14 . 852 3.508 2 . 18 1.161 2/ 12/2013 

### 9:53 :00AM 16 .038 3.153 1.418 0.714 2/ 12/ 2013 

### 9 : 54 :00 AM 13 . 842 4 . 245 2 . 146 1 . 247 2/ 12/ 2013 

### 9 : 55 :00 AM 13 . 834 4 . 253 2 . 271 1 . 184 211212013 

### 9 : 56 :00 AM 13 . 832 4 . 255 2 . 178 1 . 11 2/ 12/ 2013 

### 9 :57 :00 AM 13 . 836 4 . 251 2 . 116 1 . 177 2/ 12/ 2013 

### 9:58 :00 AM 13 . 831 4.26 2 .092 1.131 2/12/2013 

### 9:59 :00 AM 13 . 832 4.26 2 .072 1.082 2/12/2013 

### 10 : 00 :00AM 13 . 831 4 .265 1 .999 1.1 2/12/2013 

### 10 : 01 :00AM 13.831 4.265 1 . 883 1.225 2/ 12/ 201310 :02 :00AM 

### 13 . 831 4 . 266 1.923 1 . 154 21 12/ 201310 :03 :00AM 

### 15 . 311 3.25 1 .629 1.039 21 12/ 2013 

### 10 :04 :00 AM 14.489 4 .06 2 .019 0.746 2112/ 2013 

### 10:05 :00 AM 13.836 4.263 2 . 321 0.877 2/ 1212013 

### 10 :06 :00 AM 13 . 845 4.257 2 . 201 0.932 2/ 12/2013 

### 10:07:00 AM 13 . 842 4.258 2 . 241 0.964 2/12/2013 

### 10 :08:00 AM 13 . 83 4.269 2 . 386 0.918 2/ 12/2013 

### 10 :09:00 AM 13 . 829 4 . 272 2 . 285 0.851 2/ 1212013 

### 10 : 10 :00 AM 13 . 822 4 . 276 2 . 315 0 . 817 2/ 12 / 2013 

### 10 : 11 :00 AM 13 .787 4 . 297 2.42 0 . 796 2/ 1212013 

### 10 : 12 :00 AM 13 .79 4 . 294 2 . 33 0 . 824 2/ 1212013 

### 10 : 13 :00 AM 12 .612 4.158 2 . 305 0.845 2/ 1212013 

### 10 : 14 :00 AM 

### 1'-:1"0".0"'33:---:5"".1"9""9-"""0"".0"'32::-"1 -0.148 2/ 1212013 

### 10 : 15 :00 AM 4.367 2 .071 1 . 372 -0.187 2/12/2013 

### 10 : 16:00 AM

## 1r-:0;;-**~14:-::7""'--;O~.1;-:;4-:;-1--:;2-;; 5;;:05~-'i:0-;:.0~5""**  2/12/2013 

### 10 : 17 :00AM 0 . 131 0 . 134 0 .794 4 .72 2/ 1212013 

### 10: 18 :00 AM 0 . 129 0 . 13 0 .016 9 . 533 2/ 12/ 2013 

### 10:19:00AM 0 . 129 0 . 127 0 .01 9 . 58 21121201310 :20 :00AM 0 . 129 0 . 125 0.016 9 . 59 2 2/ 121201310 : 21 :00AM 

### 3 .438 1 . 329 0.48 8 . 831 2/ 12/ 201310:22 :00AM 

### 13.79 4 . 232 2 . 192 1 . 662 2/12/2013 

### 10:23:00 AM 13 . 835 4 . 245 2 . 168 1.039 2/12/2013 

### 10:24:00AM 13 . 835 4.252 2 . 156 1 . 103 2/12/2013 

### 10:25:00 AM 13 . 838 4.255 2 . 136 1 .086 2/ 12/ 2013 

### 10:26 :00 AM 13 . 835 4.258 2 . 146 0 .984 2/ 12/ 2013 

### 10 : 27 :00 AM 13 . 829 4.263 2 .038 0 . 971 2/ 12/ 2013 

### 10 : 28 :00 AM 13 . 832 4 . 262 1 .957 0 .927 2/ 12/ 2013 

### 10:29 :00 AM 13 . 833 4 . 26 2 .083 0 .907 2/ 12/ 2013 

### 10:30 :00 AM 13 .794 4.286 2 .053 0 .927 2/ 12/ 2013 

### 10:31 :00 AM 13 .775 4.295 2 . 281 0 .963 2/12/2013 

### 10:32 :00AM 14 .536 3.705 1.896 0.911 2/12/2013 

### 10 : 33:00 AM 15 . 851 2/12/2013 

### 10 : 34 :00 AM 13 . 835 2/ 1212013 

### 10 : 35 :00 AM 13 . 831 21 1212013 

### 10 : 36:00 AM 13 . 83 2/ 1212013 

### 10 : 37 :00 AM 13 . 819 2/ 12/ 2013 

### 10 : 38 :00 AM 13 . 832 2/ 12/ 2013 

### 10 : 39 :00 AM 13.834 3 . 252 1.393 0.742 4 . 253 2 .088 1.161 4 . 261 2 . 127 1 . 176 4 . 261 2 .098 1.107 4 . 265 2 . 188 1.054 4 . 248 2 . 122 1.085 4 . 243 2 .042 1.159 

### 0, % 

### 13.903 13 . 896 13.901 13 .909 1 3. 918 13 . 929 13 .922 13 .929 13 .914 13.913 13 . 902 13 . 912 13 .914 13 .903 13 .904 13 .904 13 .903 13 . 901 13 .912 13 .916 13 .915 13 .908 13 . 898 13 .906 13 .914 13 .914 13 .907

13 .9 13 . 892 13 . 897 13 .907 13 .918 13 .91 13 .919 13 .927 13 .926 13.908 13 .915 13 .909 13 .92 13 .919 13 .923 13 .918 13 . 898 13 . 899 13 .918 13 . 916 13 .913 13 .913 13.906 13.906 13 .902 13 . 899 13 . 894 13 . 888 13 . 879 13 . 901 13 .903 NO. PPM 25.322 25.529 25 .519 25 . 399 25.299 25 . 164 25 . 133 25.042 25.907 26 .079 26 .491 26 . 303 26 .08 26.406 26 . 35 26 . 327 26 .6 26.5 26 . 367 26 . 236 26 . 366 26.467 26 .924 26 . 893 26 . 607 26 . 538 26 . 569 26 .537 26 .731 26 .554 26 . 322 26 . 382 26.422 26 . 255 26 . 161 26 .03 26 . 297 26 . 158 26 .477 26 .462 26 .408 26 . 159 26.032 26.413 26 . 376 26.13 26 . 192 26 . 361 26 . 16 26 . 183 26.109 C O PPM 82 . 666 79 .427 82 .578 81 . 659 87 . 251 87 . 222 89 .949 93 . 323 78 . 289 71 . 686 62 . 172 64 . 225 67 .756 60 .731 60 . 236 62 .525 57 . 341 58.127 58.792 61.938 59.944 57 . 867 54.477 54 . 129 56 . 838 58.422 56 .568 58.145 55 . 357 56 . 332 58 .057 58 . 286 58.389 59 .584 60.079 62 .511 60 . 233 63 . 327 61 .797 59 .064 59 .71 59 .408 62.389 61 . 384 58 .595 59 .957 60 .783 60 . 207 62.474 61.029 61.771 26.132 62.13 26.071 62.32 26 . 327 60 . 798 26 . 317 59 .724 26 .592 56 .74 26 .078 59 .628 25.975 62.429 THC 

### PPM 8.373 7 .633 8 .565 7 .965 9 . 906 10 .099 10 .665 11 . 86 7 .652 5 . 65 3 .53 4 .044 4 .778 3 . 329 3 . 187 3.745 2 . 617 2.645 2.726 3.281 3 .05 2 . 656 2 . 116



### 2 2 . 36 2 . 613 2.433 2 .743 2 . 166 2.473 2 .766 2 . 55 2 . 647 2.725 2 .744 3 . 337 3 .008 3 . 632 3. 392 2 . 807 2 .952 2 . 864 3.397 3.332 2 .78 3 .02 3 . 161 3 . 15 3.338 3 .079 3.347 3.205 3 . 361 2 .977 2 . 814 2.485 2 . 856 3 . 326 02/ C02 bias NOx bias
CO bias
Start RATA Run 9Date Time 

### 0 , % 2/12/2013 

### 10 :40 :00 AM 13 . 832 2/12/2013 

### 10:41 :00 AM 13 . 835 2/12/2013 

### 10:42 :00 AM 13.834 2/ 12 / 2013 

### 10:43 :00 AM 13.833 2/ 12/ 2013 

### 10:44 :00 AM 13 . 833 2/ 121 2013 

### 10:45 :00 AM 15 . 164 2/ 12/ 2013 

### 10 :46 :00 AM 14 . 22 2/ 12/ 2013 

### 10 :47 :00 AM 13 . 827 2/ 12/ 2013 

### 10:48 :00 AM 13.828 2/12/2013 

### 10:49:00 AM 13.825 2/ 1212013 

### 10:50:00 AM 13.831 2/ 12/ 201310 :51:00AM 13
. 833 2/ 12/ 2013 

### 10 : 52 :00 AM 13 . 841 211212013 10 :53 :00 AM 13 . 832 2/ 1212013 

### 10 : 54 :00 AM 13 . 822 2/ 12/ 2013 

### 10 : 55 :00 AM 17 . 214 2/ 12/2013 

### 10 : 56 :00 AM 13 . 866 2/12/2013 

### 10 :57 :00 AM 13.838 2/12/2013 

### 10:58 :00 AM 13 .841 2/ 12/2013 

### 10:59:00 AM 13 . 84 2/ 12/ 2013 

### 11 :00 :00 AM 13 . 839 2/ 12/ 2013 

### 11 :01 :00AM 13 . 843 2/ 12/ 2013 

### 11 :02 : 00 AM 13 . 836 2 / 12/ 2013 

### 11 :03 :00 AM 13 .843 2/ 12/ 201311 :04 :00AM 13
. 834 2/ 12/ 2013 

### 11 :05 :00 AM 13 .795 

### CO, % 

### NO , CO 0, NO, CO PPM PPM 

### % PPM PPM 4 . 244 2.078 1 . 197 13 .902 26.14 62 . 244 4 . 238 2 . 11 1.114 13 .91 26.027 61 . 365 4 . 237 2 . 103 1.188 13 . 901 26.074 63 . 683 4 . 235 1 .987 1.2 13 . 911 25.941 64.45 4 . 237 1 .924 1.13 13 .904 26 . 212 61 . 861 3 . 312 1 .582 1 .098 13 .903 25 . 905 64 .462 4 . 161 2 . 279 1 .008 13 . 891 26 .046 65 .092 4 . 235 2 . 628 1 . 209 13 . 895 26 . 1 61 .927 4 . 236 2 . 594 1.173 13 . 897 26.288 60 . 888 4.238 2 . 628 1.151 13 .902 26.465 58 . 67 4.233 2.479 1.16 13 .912 26 .082 61 . 884 4 . 23 2.436 1.201 13 .936 25 .914 63 . 866 4.227 2 . 3 5 1 . 248 13 .943 25 . 793 66.898 4 . 238 2 .444 1 . 189 13 . 923 26 . 221 63 . 329 4 . 245 2 .6 5 1.055 13.915 26 . 599 57 . 354 2 . 301 1 . 317 0.649 13 .94 26 . 219 58 .755 4.227 2 . 325 0 . 971 13 .926 26 . 288 60.434 4 . 237 2 . 297 0.996 13.914 26 . 599 57.747 4 .236 2 . 16 0 .956 13 .937 26 . 256 58 .975 4 .238 2 . 246 0 .977 13 . 927 26 .404 58 .708 4.242 2 . 174 1.028 13 . 932 26 . 257 59.402 4 . 241 2 . 166 1 .021 13 .947 25 .973 63 . 145 4.247 2 . 319 0 .915 13 .94 7 25 .971 62 .726 4 . 243 2 . 247 0 .952 13 .948 25 .995 64 . 192 4.252 2 . 35 0 .934 13.938 26 . 21 61.938 4 . 281 2 .507 0.867 13.933 26 . 335 59.075 2/12/2013 

### 11 :06 : 00 AM 13 .796 4 . 282 2 .43 0.857 13 . 937 26.351 58.772 2/ 12/2013 

### 11 :07 : 00 AM 13 . 802 4 . 278 2 . 356 0 . 859 13 .935 26.341 58.952 2/ 1212013 

### 11 :08 :00 AM 4 .791 1 . 311 0 .953 4.539 13 .928 26 .468 57.138 21 12/ 2013 

### 11 :09 :00AM 0 . 147 0 . 12 0 .021 9 .522 13 .915 26 . 679 55 .734 21 12/201311 : 10 :00AM 0 . 13 0 . 115 0 .013 9 .58 13 .938 26 .538 54 .078 21 12/ 2013 

### 11:11 :00AM .....**:4;:: 5:::92~_.:;2;:** **6;::6.;.7_....;0::; 0::,1:,......,**  

### 7 . 161 11 . 342 12 . 872 44.482 2/ 12/ 2013 

### 11 : 12 :00

### AMLI_1~0;:**0:::2.::.9_..;5::, 1:,:7;::6_~0;:** **0~19::....J** -0 . 105 10 .051 0 .723 0 .607 2/ 12/2013 

### 11 : 13 :00AM 7 . 852 3.846 0.503 -0 . 281 5 .083 21.913 0 . 264 2/12/2013 

### 11: 14 :00 AM ..... ::,0

. .;.17:.;6:.....--...:0;;,.1:.;3;::5_....::2,;.; . 5;::0.;.1_....;0 . .:;.00:;,1:.....--...:0::;; .0;:5;::8:.........:,4**7~.**

### 9;1:;:6:.........;0. :;.3::,81:...., 2/ 12/2013 

### 11 : 15 :00 AM LI_0::, . .;;12:;:9:.....--...:0::, . 1:,:2:..:1_-..::2,;: .5:;:03::...._::,0 . ;:.07:..:2;.....--...:0::;;.0:::3:;:6:.........:,47:..:8::,9:,:1_....::.0.;:;24::;4:....J 2/ 1212013 

### 11 : 16 :00 AM 0.12 0 .098 0 .702 0 .072 1 . 235 20.862 11 . 939 211 21 2013 11 : 17 :00 AM ..... 0:,:;

. .,::1**0;:3:.....--...:0::;; 0;:9::;4_....::0,;.;** **0.:;.09::-_;.0;..06:,::,..._..;.:.0 :::03;..._..:;0..;** **1~7::,9**

# _....:;2
. ,::10;;;2:...., 21 1212013 

### 11 : 18 :00 AM 

### LI_0::, . .,::1

## 0:::3:.....--...:0::;;**0:::9:;:5_~0,;: 0:;:06::...._::,0**  .

## .:::06:::4:.....--...:0::;;**0:::2;.:9_~0..; 1:::2:4_....,..::0..;** **1:..:1.....J** 2/ 1212013 

### 11 : 19 :00 AM 7 . 218 3 .946 1 . 598 5 . 202 6 . 279 26 . 154 94.841 2/ 12 / 2013 

### 11 :20 :00 AM ,....;1.:;.0:;;.0::4;,2_....,..::5:.; 2;"..._.;2,;.; .5;09::...._:,:;9 . .:;.58;:6:.........:1.:;.0. .:;.04:;:4;........:,4**7~.9:::7:,:1,.....;2.;.43;.;:82;;8;.,** 2/ 1212013 

### 11 :21 :00 AM 

## 1 10.046 5.199 2 .511 9.615 10.052 48.008 243 .676 

## 1 2/12/2013 

### 11:22:00 AM 12.104 1.096 1 . 393 6.487 11.861 39.235 193.475 2/12/2013 

### 11:23:00 AM 20.912 0 . 168 0 .027 0.412 14 . 364 27 . 363 49 . 895 2/ 12/ 2013 

### 11 :24 : 00 AM 20 . 961 0 . 157 0 .018 0 . 197 9.882 22 . 592 51 . 528 2/ 12/ 2013 

### 11:25 :00AM 20 .97 0 . 153 0.01 0 . 195 0.077 0.778 215 . 8 2/ 12/ 201311 : 26 : 00AM 

### 20 .007 0 . 817 0 . 373 0 . 191 0 .047 0 .592 1243 .6871 2/ 12/ 201311 : 27 :00AM 2/ 12/ 2013 

### 11 :28 :00 AM 2/ 12/ 2013 

### 11 :29 :00 AM 2/12/2013 

### 11 :30 : 00 AM 2/ 12/2013 

### 11:31 :00AM 2/ 1212013 

### 11 : 32 :00 AM 2/ 12/ 2013 

### 11 : 33 :00 AM 2/ 1212013 

### 11 : 34 :00 AM 2112/ 2013 

### 11 : 35 :00 AM 2112/ 2013 

### 11 : 36 :00 AM 2/ 12/ 2013 

### 11 : 37:00 AM 14 . 364 14 . 317 14 . 307 14 . 305 9.692 14 . 184 14 . 291 14 . 289 14 . 287 14.285 14 . 283 3 .939 3 . 389 0.196 0 .032 0 .509 244 .608 3.951 3 . 195 0.297 7 .081 11.882 209 . 376 3 . 955 3 0.312 14.35 26.666 56 . 289 3.957 2 .965 0.308 14 . 367 26.717 50 .519 2 . 693 2 . 198 0 . 257 14.366 26.578 50 .757 3 .948 2 . 825 0 . 256 14 . 365 26 . 648 50 .798 3 .963 2 . 877 0 . 314 14 . 355 26 .751 50 . 141 3 .97 2 . 867 0 . 324 14 . 342 26 . 849 49 .025 3 .972 2 . 798 0 . 3 14 . 343 26 . 762 49 .755 3 .973 2 . 798 0 . 294 14 . 34 26 .742 50 . 272 3 .979 2 . 872 0.323 14.339 26 .75 49 . 855 THC 

### PPM 3 . 322 3 . 143 3 . 533 3 . 514 3 . 242 3 . 617 3 .769 3 .019 3 . 171 2 .702 3.076 3.497 3.981 3.418 2. 327 2.535 2.937 2.362 2 .563 2 .634 2 .75 3 . 335 3 . 345 3 . 398 3.05 2.697 2 .571 2 . 558 2. 281 2 .083 1 . 784 1 . 855 -0 .011 -0.011 -0.011 -0 .011 6 . 333 37 . 083 2 .014 2 . 014 2.404 1 . 922 1 .007 0 .718 0 .429 -0 .001 0 .001



## o 0 .074 1 . 251 1 . 348 1 . 313 1 . 329 1 . 221 1 .028 1 .085 1 . 159 1.049 CO bias 02

/ C02 bias
NOx bias
Direct Zero
Direct Span

CO biasDate Time 

### 0, % 2 /12/ 201311:38 :00AM 14
.284 

### 21 1 2120 13 11 : 39 :00 AM 14.283 2 / 12/ 201311 :40 :00AM 14 .2 83 2/12/2013 

### 11 :41:00 AM 14 . 28 4 2/12/2013 

### 11 :42 :00 AM 14 . 275 2/12/ 201311 :43 :00AM 14
.271 2 / 12 120 13 

### 11:44 :00 AM 14 . 282 2 / 12 12 013 

### 11 :45 :00AM 14 . 278 2/12/2013 

### 11 :46:00AM 14.268 2/12/2013 

### 11 :47:00 AM 2/12/2013 

### 11:48:00 AM 2 / 12/ 201311 :49 :00AM 

### 211212013 11 : 50 : 00 AM 2 /12/ 2013 

### 11 : 51 :00 AM 2/12/2013 

### 11 : 52:00 AM 2/1212013 

### 11 : 53:00 AM 211212013 11 : 54 :00 AM 2 /12/ 2013 

### 11 : 55:00AM 2112/ 2013 

### 11 : 56 :00AM 2/12/2013 

### 11 :57:00AM 2/12/2013 

### 11 :58:00 AM 2/12/2013 

### 11:59:00AM 2112/ 2013 

### 12 :00:00 PM 2 /12/ 2013 

### 12 : 01 :00 PM 2 / 12/ 2013 

### 12:02 :00 PM 2/12/2013 

### 12:03 :00 PM 2/12/2013 

### 12:04:00 PM 2/12/2013 

### 12 :05 :00 PM 2 / 1212013 

### 12 :06 :00 PM 2 / 12120 13 

### 12 :07 :00 PM 2/12/ 2013 

### 12 :08 : 00 PM 2/12/2013 

### 12 :09:00 PM 2/12/2013 

### 12 : 10 :00 PM 2112/ 2013 

### 12:11 :00 PM 21 1212013 

### 12:12 :00 PM 2112120 13 12 : 13 :00 PM 2/12/2013 

### 12 : 14 :00 PM 2/1212013 

### 12:15:00 PM 2/12/2013 

### 12:16 :00 PM 2112120 13 12:17 :00 PM 21 1212013 

### 12: 18 :00 PM 2 /12/2013 

### 12 : 19:00 PM 2/12/2013 

### 12 :20:00 PM 2112/2013 

### 12 :21:00 PM 2 / 12/2013 

### 12 :22 :00 PM 2112120 13 12 :23 :0 0 PM 2112/ 2013 

### 12 :24:00 PM 2/12/2013 

### 12 :25:00 PM 2/12/2013 

### 12:26:00 PM 2/1212013 

### 12 :27 :00 PM 2112/20 13 

### 12 :28 :00 PM 21 12/ 2013 

### 12 :29 :00 PM 2/12/ 2013 

### 12 :30:00 PM 2/12/2013 

### 12:31:00 PM 2/12/2013 

### 12 : 32 :00 PM 2/1212013 

### 12 : 33 :00 PM 2 / 1212013 

### 12 : 34 :00 PM 211212013 

### 12:35 :00 PM 2/12/2013 

### 12:36 :00 PM 14 . 285 14 . 278 14 . 268 14 .265 14.255 14 . 244 14.257 14.275 14 . 27 14 . 266 14 . 267 14 . 27 14 . 269 14 . 268 14 . 27 14 . 283 14 . 279 14 . 277 14 . 242 14.263 14.263 14.246 14 .2 41 14 . 204 14 . 204 14 . 204 14 . 198 14 . 197 16 . 57 14 . 612 14 . 286 14 .2 85 14.277 14 . 278 14 . 268 14 . 27 4 14 . 271 14 . 266 14 . 265 14 . 264 14 . 268 14 . 266 14 .2 59 14.264 14.261 14 . 262 16 . 207 14 . 249 14.241 14.252 

# co, % 

### 3 .979 3 .982 3.98 3.983 3.988 3 .983 3 .983 3 .983 3 .977 3.977 3 .987 3 .991 3 .997 3 . 999 3 .996 3 .994 3 .997 3 .999 4 .001 4 . 002 4 .001 4 .003 4 .002 4 .001 3 .994 3 .998

4 

### 4 .017 4 .005 4 .007 4.015 4.021 4.047 4.048 4 .0 5 4 .049 4.052 2.571 3.927 3 .995 3 .994 3 .997 3.995 3 .999 3 .996 3 .996 3 .994 3 .993 3 .991 3 .988 3 .989 3 .992 3 .989 3.99 3.989 2 . 874 3 .996 3.999 3.993 NO, 

### PPM 2.728 2 . 854 2.799 2 . 69 2.714 2.595 2 .741 2 .718 2 . 677 2 . 571 2 .732 2 .715 2 . 623 2.496 2:422 1 .961 1.669 1 . 682 1.771 1.665 1.658 1.739 1 .765 1.705 1.683 1.818 1.785 2 . 245 2 . 268 2 . 255 2 . 32 2.111 2.246 2 . 178 2 . 273 2 . 293 2:402 1.696 1.664 1.871 1 . 87 1.888 1.932 2.004 1.841 1.851 1 .8 12 1 .9 14 1.825 1.849 1.886 1.788 1.798 1.897 1.901 1.773 2 . 665 2 . 798 2 . 637 

## CO PPM 0 . 319 0 . 319 0 . 341 0 . 31 0 . 332 0 . 317 0 . 313 0 . 295 0 . 323 0.344 0.316 0.301 0 . 317 0 . 34 0 . 339 0 . 344 0 . 355 0 . 334 0 . 325 0 . 325 0.307 0.345 0.329 0 . 35 0 . 353 0 . 362 0 . 344 0 . 288 0 . 263 0.235 0 . 237 0 .231 0 . 308 0 . 336 0 . 365 0.334 0 . 327 0 . 311 0 . 386 0 .508 0 .553 0 .535 0.556 0 .542 0 .542 0 .567 0 .564 0 .525 0 .577 0 .537 0 .579 0.517 0 .542 0 .528 0 .527 0 . 323 0 . 375 0.385 0:407 

### 0, % 

### 14 . 338 14 . 337 14 .32 14 .327 14 . 338 NO, 

### PPM 

## CO PPM 26 . 682 50.816 26 .742 51 . 17 26 .944 49 .922 27 .04 49.207 26 .987 48 . 638 14 . 338 26 .98 49 . 501 14 . 345 26 . 899 49 . 171 14.354 26.775 50 .425 14.351 26 .557 52 . 259 14.34 14 .343 14 . 343 14 . 331 14 . 328 14.337 14 .332 14.329 14.325 14.318 14 .3 19 14.322 14.323 14.337 14 . 338 14 . 34 14 . 342 14 . 34 14 . 343 14 . 343 14 .342 14 . 342 14.343 14 .344 14 . 347 14 .3 45 14 . 342 14 .3 4 2 14 .342 14 . 335 14 .338 14.33 2 14.319 14.318 14.317 14.317 14 . 317 14 . 317 14 . 317 14.317 14 . 318 14.317 14 . 317 14 .317 14.317 14.317 14.317 14 . 318 14 . 317 14.317 27 .017 27 .014 26 .94 27 .051 26.771 26.761 26.89 26 . 863 26 .972 27 .002 26 .963 26.72 26.852 26 .781 26.731 26.731 26 . 562 26 . 692 26:497 26 . 678 27 .012 27.046 26.85 9 26 . 806 26.595 26 . 713 26.821 27.055 26.809 26.802 26:468 26:463 26:47 26:404 26.414 26.364 26 . 391 26.392 26.347 26.212 26.164 26.353 26 . 195 26 . 235 26.354 26:411 26.45 1 26 .577 26 . 388 26 . 327 50 . 391 48:441 49 . 573 48 .967 50.394 50.797 50.136 50.251 49 . 865 48 .907 49:456 50.876 50 .558 50 . 621 51.083 51.714 51.892 51.607 53 .01 51 .98 49 .591 48:418 49.444 49.908 51 . 292 51 .2 6 50.506 49.354 50.867 50.977 52 .756 53 . 195 52 .917 53.891 53.217 53 . 887 53 .529 54 .084 53.774 54.987 55.822 54 . 852 55 . 237 55 . 727 54:492 53 . 839 53 . 268 52 . 627 53 .085 54 .767 THe 

### PPM 1 . 153 1 . 284 1.141 1.136 1.031 1.122 1.155 1.285 Start PM 50 % 1.45 1 . 152 1 .047 0 .979 1 .016 1.371 1.365 1 . 321 1 . 089 1.14 1.121 1.193 1.307 1.33 1.263 1 .238 1.3 1.469 1:44 1.535 1 . 524 1.124 0.968 1.172 1.249 1 . 322 1 . 337 1.156 0.914 1 . 204 1 .229 1 .485 1.665 1.59 1.62 1 .591 1.697 1.623 1 . 628 1.587 1.753 1.678 1 .568 1.738 1 . 864 1.713 1 .541 1.47 1.38 1.434 1.648 Start 50% Compliance 1Date Time 

### 0 , % 

### CO , 

### % NO , CO 

### 0, NO , CO THC PPM PPM 

### % PPM PPM PPM 2/12/2013 

### 12:37 :00 PM 

### 14 . 238 4 2 .947 0 . 388 14 . 317 26.499 53 .048 1.419 2/12/2013 

### 12:38 :00 PM 

### 14 . 242 3.999 2.776 0 . 369 14 . 317 26 . 25 55 . 11 1 . 613 2/12/2013 

### 12:39:00 PM 

### 14.251 3.995 2 .698 0.373 14 . 317 26 . 181 56 .07 1 . 763 2 /12/ 2013 

### 12:40:00 PM 

### 14 . 23 4.007 3 . 103 0.349 14 . 317 26.496 53 . 822 1 .467 2 /12/ 2013 

### 12:41 :00 PM 

### 14 . 207 4.018 3 . 322 0 . 266 14 . 335 26 . 251 54 . 292 1 . 586 2/12/ 2013 

### 12:42 :00 PM 

### 14 . 257 3 .991 3 .063 0.263 14 . 34 26 .086 56 . 39 1 .927 2 /12/ 2013 

### 12:43 :00 PM 

### 14 . 259 3 .994 3 .034 0 . 274 14 . 335 26 . 36 55 . 162 1.797 2 /12/ 2013 

### 12 :44 :00 PM 

### 14 . 255 3 .995 2 .952 0.267 14 . 34 26 . 237 54 .94 1 . 638 2 /12/ 2013 

### 12:45:00 PM 

### 14.255 3.996 2 . 991 0.275 14 . 341 26.189 55 .55 1 . 788 2/12/2013 

### 12.46:00 PM 

### 14.191 4.035 3.004 0.379 14 . 338 26.382 54 . 88 1 .724 2/12/2013 

### 12:47:00 PM 

### 14.176 4.041 3 . 117 0 . 354 14 . 332 26 .491 52.693 1.402 2/12/ 2013 

### 12 :48:00 PM 

### 14.18 4 .04 2 . 916 0 . 35 14 . 333 26.385 53 .528 1.449 2/12/ 2013 

### 12 :49 :00 PM 

### 14 . 19 4 .033 2 . 804 0 . 344 14 . 33 26 . 396 53 .554 1 .544 2112/ 2013 

### 12 : 50 :00 PM 

### 14 . 195 4 .032 2 .774 0 . 374 14 . 339 26.189 55.243 1.779 21 12/ 2013 

### 12 : 51 :00 PM 

### 16 .756 2 .556 1 . 759 0 . 316 14 . 336 26.201 55 .021 1 .711 2112/ 2013 

### 12 : 52 :00 PM 

### 14 . 308 3 .972 2 . 875 0 . 523 14 . 339 25 .998 57 . 214 2 .024 2/12/ 2013 

### 12 : 53:00 PM 

### 14.286 3 .981 3 . 228 0 . 542 14 . 337 26 . 219 55.276 1 .757 2/12/ 2013 

### 12 :54:00 PM 

### 14 . 288 3.978 3 . 192 0 .553 14 . 342 26.084 56.717 1.931 2/12/2013 

### 12:55 :00 PM 

### 14 . 283 3 .982 3.13 0 .543 14 . 338 26 . 251 54 .649 1 .57 2/1212013 

### 12:56 :00 PM 

### 14 . 277 3 .983 3 . 101 0.535 14 . 339 26 . 522 53 .049 1.483 2 / 12/ 2013 

### 12 :57 :00 PM 

### 14 . 277 3 .984 3 .022 0.507 14 . 341 26 . 367 53 .619 1 .5 31 2 /1212013 

### 12 :58 :00 PM 

### 14 . 28 3 .983 2.907 0 .549 14 . 341 26.271 53 .949 1 . 637 21 1212013 

### 12 :59 :00 PM 

### 14 . 286 3 .978 2 .648 0 .526 14 . 339 26 .428 53 .688 1 .548 2 / 1212013 

### 1 :00 :00 PM 

### 14 . 282 3 . 982 2 . 817 0 .524 14 . 337 26 . 399 53 . 634 1.496 2 / 12/ 2013 

### 1:01 :00 PM 

### 14 . 279 3 .983 2 . 696 0.503 14 . 328 26.661 51 .413 1 . 258 2 / 12/ 2013 

### 1:02 :00 PM 

### 14 . 279 3 .983 2 .561 0.533 14.332 26 . 628 51.871 1 . 185 2/12/2013 

### 1:03:00 PM 

### 14 . 264 3.992 2 .571 0.492 14.326 26 . 803 50.053 1.01 2/12/2013 

### 1004:00 PM 

### 14.262 3 .991 2 .506 0.479 14 . 321 26 . 921 49 . 355 0 . 815 2 /12/ 2013 

### 1005:00 PM 

### 14 . 257 3 .995 2 .449 0 .456 14 . 317 26 .912 48 .919 0 .935 2 /12/ 2013 

### 1 :06:00 PM 

### 14 . 259 3 .992 2 . 333 0 .492 14 . 317 26 .901 49 . 249 0 . 933 2 /12 12 013 

### 1 :07 :00 PM 

### 14 . 256 3 .996 2.403 0 .467 14 . 317 27 .027 48 . 319 0 . 791 2 / 12/ 2013 

### 1008:00 PM 

### 14 . 25 3 .999 2 . 311 0 .446 14 . 317 27 . 244 46 .977 0 . 599 2 / 12/2013 

### 1 :09:00 PM 

### 19.845 0 . 675 0 .506 0 . 268 4.477 10 . 186 32.451 18.167 2 /12/ 2013 

### 1010 :00 PM 

### 20 .934 0.185 0.027 0.187 0 .06 0.666 0.585 45.229 2/12/2013 

### 1:11:00 PM 

### 20 .943 0.177 0 .023 0.197 0 .048 0 .561 0 . 173 46 . 105 ITHC Mid 2/12/2013 

### 1 : 12 : 00 PM 

### 10 . 229 0.185 0 .041 2.444 0 . 123 0 . 661 31 . 525 42.45 2/12/ 2013 

### 1 : 13 : 00 PM 

### 0.183 0 . 13 0 .009 9 . 378 0 .033 0.446 233 . 266 1 .07 2/1212013 

### 1 : 14 :00 PM 

### 0 . 154 0 . 127 0 .012 9 . 582 0 .033 0.398 1 243 . 2551 0 CO b i as 21 12/ 2013 

### 1 : 15 :00 PM 

### 1.771 1 . 162 0 .012 9.076 6 . 204 0 . 835 177.872 -0 . 004 2112/ 2013 

### 1016 :00 PM 

### 9 .93 5.171 0 .013 0.852 9 .948 0 . 336 3 . 329 -0 .012 2/12/ 2013 

### 1 : 17 : 00 PM 

## 1 9 .996 5.196 0 .017 -0.309 9 .949 0 . 304 -0 . 106 -0.012 02/ C02 bias 2112/2013 

### 1 : 18:00 PM 

### 9 .996 5.204 0 .01 -0 . 308 L..-=7;.;: . 1.,:.98:;-.....,1;;;0.:,.1;;;3;,.1oJ 

### -0 .085 -0 .012 2/12/2013 

### 1:19 :00 PM 

### 3.736 1.814 1 .491 -0.194 0.065 47.3 0 . 221 -0.012 2/12/2013 

### 1 :20:00 PM LI....::;o;,; .

## 1;44:....._~0**~14;:6;..-_!.2 ;49'=-_..:0;;** **0~5;..-_;.0:;::.0:,:3:----;4.:,.7**. ::;4,:,:75;..-.....:0:;: .2;,:,7""5
__

## -:;0~**0:.:.12;,..JINOX** bias; 

### THC Zero 2 / 12/ 2013 

### 1:21 :00 PM 

### 0 . 121 0 . 115 1 .075 0.07 0 .031 26.999 0 . 23 -0 .011 2 /12 / 2013 

### 1 : 22 :00 PM 

### 0 . 103 0 . 105 0 .015 0 .061 0 .029 0 . 151 0 . 115 1 .092 2 /1212013 

### 1: 23 :00 PM 

### LI...::;o . ;,;:l

0::3:........:0::;, ..:,:1

0;,;:5....:.....:0:;: .0;,;:0::,8_...::;0. ;:;06::;2,--_;:;0. ;:;0;:,3

## _.....:0:;.**1~0::.4_...:::0;.,: .**  1.;.17:.....J 2 / 1212013 

### 1 :24 :00 PM 

### 6 .967 3.798 1 .513 3 . 599 5 .7 39 23 . 36 31 .707 2 / 12/ 2013 

### 1 :25:00 PM
..... 

### 1:,:0:;:

.0::..1:,:2;,......,::5:;: .2;.,:1.,:.1_....::2;;; .5;;0::;3_.....:9:;;.4;.:8:::9....:_.,.1::;0:,.,.._..;:4.;.7;.,:.7.;8.::.9_.;;2;:;34; .;61;.:9:..., 2 / 12/ 2013 

### 1 :26:00 PM 

### LI_l.:,:0:;;
.0;::2;.,:1_...::;5 . :,21.:,:3:........:2;;: .5;::0;,;:5_.....::9,;;: .5;,;:8,:.1
__

## 1~0,;;:.0;,;:0.;.1_..;:4,:.7.;,;:8:;:23:......:2~4.::3;.;.7.:,82;..J1 2/12/2013 

### 1:27 :00 PM 

### 7.021 3.19 2 .494 8 . 648 10.778 45 .557 233 . 318 2/12/2013 

### 1 :28:00 PM 

### 14.133 3 .95 2 . 218 1.081 14 . 304 26.498 72.186 2 /1212013 

### 1 :29 : 00 PM 

### 14.218 3 .996 1 . 831 0.384 14 . 316 26 .402 52 . 384 2112/ 2013 

### 1 : 30 :00 PM 

### 14 . 219 3 .997 1.835 0.363 14 . 316 26 . 655 51.483 2/12/ 2013 

### 1 : 31 :00 PM 

### 14 . 213 3 .999 2 .009 0 . 34 14 . 316 26 .433 51.774 2 /1212013 

### 1 : 32 :00 PM 

### 14 . 227 3.992 1 . 816 0 . 378 14 . 316 26 . 52 52 . 101 2112/ 2013 

### 1 : 33 :00 PM 

### 14 . 214 3.997 1 . 974 0 . 36 14.316 26 . 826 50 .003 2/12/ 2013 

### 1:34 :00 PM 

### 14 . 208 4.001 2 .014 0.291 14.316 26 . 829 49 . 395 1.487 1 . 396 1 . 126 1 . 185 1 . 218 1 . 27 1.457 1 . 3 1.327 1.41 1 .059 0 . 828 Direct Zero
Direct Span

Start Compl iance 2Date Time 2112/2013 

### 1 : 35 :00 PM 2112/2013 

### 1 :3 6 :00 PM 2 / 12/ 2013 

### 1:37:00 PM 2/1212013 

### 1: 38 :00 PM 2112/2013 

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### 1 :49 :00 PM 211212013 

### 1:50:00 PM 2112/ 2013 

### 1 :5 1 :00 PM 2112/ 2013 

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### 1 :54 :00 PM 2 /12/2013 

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### 2 :02:00 PM 2/12/2013 

### 2 :03:00 PM 2/12/2013 

### 2 :04:00 PM 2/12/2013 

### 2 :05:00 PM 2/12/ 2013 

### 2 :06 :00 PM 21 12/ 2013 

### 2 :07 :00 PM 2112 / 2013 

### 2 :08 :00 PM 2 / 1212013 

### 2 :09 :00 PM 2 / 1212013 

### 2 : 10 :00 PM 2 / 12120 13 

### 2 : 11:00 PM 2/12120 13 

### 2 : 12:00 PM 2/12/2013 

### 2 : 13 :00 PM 2/12/2013 

### 2:14:00 PM 2/12/2013 

### 2 : 15 :00 PM 2/12/2013 

### 2 : 16 :00 PM 2/12/2013 

### 2 : 17:00 PM 2/12/2013 

### 2 : 18 : 00 PM 2/12/2013 

### 2 : 19 :00 PM 2/12/2013 

### 2:20 :00 PM 2/12/2013 

### 2:21 :00 PM 2 /12/2013 

### 2 :22 :00 PM 2 /12/ 2013 

### 2 :23 :00 PM 2 /12/ 2013 

### 2:24 :00 PM 2112/ 2013 

### 2:25 :00 PM 2112/ 2013 

### 2 :26 :00 PM 2112/ 2013 

### 2 :27 :00 PM 211212013 

### 2 :28 :00 PM 2/1212013 

### 2 :29 :00 PM 2/12/2013 

### 2 : 30 :00 PM 2/12/2013 

### 2:31 :00 PM 2/1212013 

### 2 : 32 :00 PM 2/12/2013 

### 2 : 33 : 00 PM 

### 0, % 14 . 221 14 . 229 14.201 14.205 14.203 14.202 14 .203 14.171 14.162 14.171 14.171 14.168 17.642 14.429 14.259 14.25 14 . 252 14 . 251 14 . 239 14 . 25 14 . 235 14 . 232 14 . 232 14 . 228 14 .22 6 14 .2 33 14 .23 1 14 . 224 14 . 217 14 . 212 19 .004 14 . 302 14 . 203 14 . 203

14 .2 14 . 203 14.203 14.203 14 .201 14.203 14.203 14.203 14 . 197

14.2 14 . 203 14 .2 03 14 . 199 14 . 196 16 . 858 14 .724 14.226 14.227 14 .22 5 14.224 14.216 14.224 14 . 225 14 .23 2 14.237 

# co, % 

### 3 .997 3 .995 4 .016 4.01 4.015 4.016 4 .018 4.037 4.038 4.033 4.036 4.039 1.97 3.963 3.988 3 .995 3 .995 3.996 4 .003 3 .999 4 .007 4 .008 4.009 4 .014 4.016 4.012 4 .014 4 .0 18 4.022 4.025 1 . 238 4 . 022 4 .037 4 .036 4 .041 4 .038 4.041 4.042 4.045 4.041 4.041 4.045 4.048 4.049 4.047 4.047 4 .051 4.052 2.388 3 . 873 4 .03 4 .028 4 .031 4.035 4.035 4.032 4.032 4 .028 4 .027 NO, 

### PPM 1 . 971 1.775 2 . 35 2 . 228 2 . 263 2.368 2.372 2.418 2.466 2.312 2.482 2.541 1.216 1.833 1.919 2 .075 1 .993 1 . 896 2 .07 1 .941 2 .009 1 . 797 1 .653 1 .72 1 . 727 1 . 665 1 . 721 1 .663 1 .708 1 .675 0 .52 2 . 217 2 . 374 2 . 308 2 . 347 2 . 304 2.394 2.401 2.366 2.013 1.927 1.969 2 . 049 1 . 871 1 .798 1 .97 2.028 2 . 103 1.307 1.734 2 .027 1 .941 1 .908 1 .9 34 2.008 2.044 2.07 2.082 2.182 

### CO PPM 0 . 352 0 . 374 0 . 288 0 . 252 0 . 25 0.24 0.235 0 . 249 0 . 292 0.299 0 . 329 0 . 318 0 .494 0.568 0.73 0 .705 0 . 686 0 . 632 0 .573 0 .588 0 .549 0 . 527 0 . 509 0 .484 0 .502 0 .526 0.494 0.495 0.479 0 .439 0 . 286 0 . 399 0 .525 0 .559 0 . 544 0 .561 0 .595 0.541 0 .513 0.559 0.53 0 .534 0.558 0 .514 0 . 503 0 . 533 0.49 0 . 518 0.412 0 . 367 0 .506 0 .538 0 .496 0.492 0 . 501 0 . 516 0.51 0.518 0.563 

### 0, % 

### 14 . 316 14 . 317 14 .32 14 . 322 14 .327 14 . 332 14 . 331 14 . 339 14 .3 42 14.341 14.342 14 . 343 14 . 342 14 . 342 14 . 34 14 . 342 14 . 34 14 .33 14 . 331 14 . 32 14 . 317 14.317 14 . 316 14 . 316 14 .3 16 14.316 14 .315 14.316 14 . 314 14 . 307 14 . 302 14 . 315 14 . 316 14 . 315 14 . 317 14 . 317 14 . 317 14 . 315 14 . 317 14 . 316 14 . 314 14.306 14.3 14.309 14.311 14.311 14.297 14.296 14.296

14.3 14 . 297 14 . 298 14 . 292 14.291 14.296 14.293 14.294 14.314 14.314 NO, 

### PPM 26.565 26.252 26 .433 26.508 26.534 26.539 26.599 26.591 26.309 26.276 26.361 26 . 191 26.275 26.369 26.484 26.413 26 .459 26 .618 26 . 664 26 . 834 27 .021 27.104 27 . 181 27 . 242 27.032 27.064 26.918 27.133 27.281 27.276 27.341 27.086 26.966 26.92 26.778 26.732 26.819 26.965 26.832 26.814 26.859 26.78 26.994 26.945 26.875 26.838 26.944 27 .027 26 . 885 26 . 862 26.896 26.799 26.952 27.019 26.843 26.899 27 .036 26 .7 83 26.664 

### CO PPM 50 . 932 54 .499 53.395 52 . 933 52.248 52.69 51.821 51.725 53.934 54.979 53.97 55 . 576 54 . 932 53 . 833 53.72 53 . 267 53 .09 52 . 512 51 . 148 50.689 48 .737 47 .989 47 .472 46 .738 47 .75 48.423 49 .046 47.779 46 .688 47 .046 46.179 47 . 782 49 .11 4 49 . 886 50.266 51 .159 50.565 49.802 49 .73 50.224 49.818 50.526 49.109 48 .6 84 49 .83 9 49 .709 49 . 17 48 . 332 49 .782 49 . 586 49 . 659 50 . 309 49.718 48.931 49 . 592 49 . 881 49 .03 50 . 338 51.466 

### THe PPM 1 . 116 1 .57 1 .542 1 . 28 5 1 . 235 1 .249 1.021 1 .008 1.439 1.644 1.467 1 .72 1 . 638 1.577 1 .804 1 . 608 1 .473 1 . 29 1 . 109 1 .049 0 . 868 0 .788 0 . 759 0 . 585 0.731 0.931 0.945 0.724 0.696

0.6 0.46 0.616 0.871 0.999 1 .131 1.162 1 .03 0.894 0.949 0 .934 0.952 1 .073 0.832 0 . 782 0.909 0 . 921 0 . 869 0 .752 1 .066 1.037 0 . 961 0.915 0 .979 0.851 0.866 0 . 911 0.766 1 .078 1 .15 1

### 0, CO, NO , CO 0, NO, CO THe Date Time 

### % % PPM PPM 

### % PPM PPM PPM 2112 1 2013 2:34 :00 PM 14.234 4.029 2 . 178 0.566 14 . 304 26 . 845 50 . 625 0 .945 211212013 2 : 35 :00 PM 14 . 229 4.032 2.275 0.553 14 . 294 27.011 49.689 0 . 874 211212013 2:36:00 PM 14.225 4.033 2.233 0.531 14.305 26.887 50 . 163 0 . 85 2 112 1 2013 2:37 :00 PM 14.232 4.029 2 . 279 0.511 14 . 314 26 .765 50 . 8 0 . 95 211212013 2 : 38 :00PM 14 . 234 4 .027 2 . 236 0 .544 14 . 314 26 . 664 52 .528 1 . 148 2112 1 2013 2 : 39 :00 PM 14 . 236 4 .027 2 . 343 0 .546 14 . 314 26 . 673 52 .979 1 . 351 21

1212013 2 :40 :00 PM 14 . 233 4 .028 2 . 288 0 .524 12 .948 23 . 666 50.778 1 .054 2 112 1 2013 2 :41 :00PM 11.032 4.475 1 . 113 0 . 265 9 .977 0 .906 7 .75 -0 .009 2 11212013 2 :42 :00 PM 

### '"1-9""."99"'5:-:-5"'.2"'4"'3---:0"'.0"'2"'5"" -0 . 27 9 . 971 0.642 -0 . 196 -0 .014 021e02 bias 211212013 2:43 :00 PM

## '-9~.~46;"7;-:-4~.8:::6~7---;O:;.0:;;6:;'8"" -0.305 4.56 22.194 0 . 155 -0.014 211212013 2 :44 :00 PM 0.353 0.213 2 .424 -0 .061 0.054 47.522 0.263 -0 .014 2 112 1 2013 2 :45 :00 PM '"I

## ~0**;;1;;39;;"""-';:0;'; 1;';7;;6-"""'"2;;'** **4~9;';6---:0;';.04;;;"3~--:O;;' 0:;;3;':4-"";4;'7;;.5,:;9;;....-0"'** **;;28:;;8~** -0 . 014 NOx bias 2 112 1 2013 2 :46 :00PM 0 . 126 0 . 168 2 .502 0.046 0 .031 36 . 211 13.629 -0 . 013 2 112 1 2013 2 :47 :00 PM 0 . 126 0 . 164 0 . 894 4 . 332 0 .029 0 .596 220 .739 -0 .004 2 112 1 2013 2 :48 :00 PM 0 . 125 0 . 16 0 .011 9.487 0 .03 0 .423 243 . 372

-0.002 2 112 1 2013 2 :49 :00 PM 0 . 126 0 . 158 0 .006 9.585 0 .029 0 . 361 243 . 5051 -0.003 leo bias 211212013 2 :50 :00 PM 8 . 246 4 .51 1 .795 9.586 7 .002 1 . 667 239 . 683 0.193 211212013 2:51 :00 PM 

### 1 9 .995 5 . 245 2.495 9.599 10 .003 2.526 243 .418 

### 1 0 . 965 Direct Span 211212013 2 :52 :00 PM 2 . 261 1 . 17 0 . 844 5.912 4 . 618 1 . 5 178 .702 0 .968 2 11212013 2 : 53 :00 PM 0 . 101 0 . 134 0 .005 0 . 15 0 .028 0 . 102 2.45 2112 1 2013 2 :54 :00 PM

## "1-0:':'**~1 0~1~--:0"** **1;':3"'3---:-0~ 0~0~1--i0.-::05:':3;---:0"** **0:;;2~7"""--;O:'; 0:;;8::-8** **--i0 ":1~09::-11**  2 11212013 2 :55 :00 PM 211212013 2 :56:00 PM 211212013 2:57 :00 PM 2 1 121 2013 2 : 58 :00 PM 211212013 2:59:00 PM 0 . 151 8 .471 20.66 20.778 20 . 835 211212013 3:00:00 PM 18 . 695 2 1 1212013 3 : 01:00 PM 14 . 257 2112 1 2013 3 :02 :00 PM 14.241 21 12 1 2013 3:03 :00 PM 14.24 2112 1 2013 3 :04 :00 PM 14 . 234 2112 1 2013 3 :05 :00 PM 14 . 23 2 11212013 3:06 :00 PM 14.224 211212013 3:07 :00 PM 211212013 3:08 :00 PM 2 11212013 3:09:00 PM 211212013 3:10 :00 PM 2 1 12 1 2013 3:11 :00 PM 2112 1 2013 3:12 :00 PM 2 112 1 2013 3:13 :00 PM 211212013 3:14:00 PM 211212013 3:15:00 PM 211212013 3 : 16:00 PM 2 1 12 1 2013 3 : 17 : 00 PM 2 1 12 1 2013 3:18 : 00 PM 211212013 3 : 19 :00 PM 2 112 1 2013 3 :20 :00 PM 2 112 1 2013 3 :21 :00 PM 2 112 1 2013 3 :22 :00 PM 211212013 3:23 :00 PM 211212013 3:24 :00 PM 211212013 3:25 :00 PM 2 112 1 2013 3 :26 :00 PM 2 112 1 2013 3 :27 :00 PM 2 112 1 2013 3 : 28 :00 PM 2 112 1 2013 3:29 :00 PM 2 112 1 2013 3:30 :00 PM 2 11212013 3:31 :00PM 14.228 14.225 14.223 14 . 208 14 . 213 14 . 22 14.212 14.222 14.225 14.23 14 . 229 14 . 233 14 . 227 14 . 223 14 . 216 14.216 14 . 21 14 . 207 14 . 207 14 . 213 14 . 219 14 . 222 14 . 217 14 . 218 14 . 221 0 . 164 0 1 . 597 5 . 57 5 . 15 0.198 1 . 194 7 . 239 18 .96 24 .701 0.221 4 . 756 7.558 19.008 24 . 296 0 . 209 19.009 24.302 0 . 209 18 .992 38.164

1.6 4.007 4 .012 4 .017 4 .02 4 .019 4.024 4.025 4.026 4.027 4.032 4.03 4 .025 4.028 4.028 4.026 4.023 4.026 4 .023 4 .027 4 .028 4 .032 4 .031 4 .032 4 .031 4 .03 4 .028 4 .025 4 .025 4 .03 4 .029 4.027 0 . 585 2 . 151 2 .04 2 . 107 2.114 2.182 2.219 2.149 2 . 122 2 . 149 2 .213 2 .086 1 . 896 1 .957 1.977 1 . 926 1 .966 1 .97 1 .968 1 .982 1 .987 2 .032 2 . 011 2 .026 2.009 2.023 2 .015 2 .063 1 .992 2 . 162 2 . 102 2 . 112 3 .517 1.12 0.481 0 . 395 0 .405 0.377 0.354 0.351 0.387 0.37 0.372 0 . 369 0 . 377 0 . 357 0.369 0.361 0.372 0.384 0 . 36 0 . 33 0.336 0.369 0 . 348 0 . 347 0.341 0.357 0 . 346 0 . 387 0 . 364 0.328 0.354 0 . 349 18 .983 47.473 18 .963 47 . 859 18 .959 11 . 286 18 .952 0 . 362 18 .952 0 . 293 18 .942 0 . 267 18 .933 0 . 253 18.916 18 .91 18 .909 18 . 896 18 .907 18 . 895 18 . 895 18.887 18.885 18.885 18 . 885 18 . 885 18 . 88 5 18 . 882 18 . 87 18 . 866 18 . 86 18 . 859 18.843 18.835 18 . 835 18 . 836 18.837 18.835 18.834 0 . 241 0 . 236 0 . 232 0 . 227 0 . 212 0 . 201 0 . 199 0 . 19 0 . 192 0 . 18 0.178 0.18 0 . 181 0 . 177 0 . 174 0 . 176 0.165 0.165 0.157 0 . 156 0 . 156 0 . 155 0 . 157 0 . 155 0 . 154 0 .746 123 . 117 135 .434 139.779 118.696 27 . 177 4 . 879 1.384 0 . 845 0 .718 0 .715 0 .715 0.669 0.719 0 .719 0 .691 0 . 694 0 . 669 0 . 669 0 . 646 0.619 0.619 0.615 0 .569 0 .57 0 .573 0 .593 0 .595 0 . 57 0.572 0.597 0.575 0 .573 0 .573 0 .578 0 .574 0.569 0.846 0 .758 0 .96 1 . 1 1 . 115 1 .014 1 . 326 1 .466 Direct Zero



### NOxl02 High, CO Mid CO Mid 1 .295 NOx Direct 

### 1 .704 1 . 611 1 .526 1 . 115 1 . 285 1.46 1 . 274 0 .793 0 .407 0 .407 0.407 DA08 DA08 DA08 0 .407 0 .407 0 .407 0.407 0 .407 0 .408 0.408 0.407 0 .407 0.407 0.407 DA08 DA08 DA08 DA08 DA08Date Time 2/12/ 2013 

### 3:32 :00 PM 2/12/2013 

### 3:33:00 PM 2112/2013 

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### 3 :44 :00 PM 2 / 12/2013 

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### 3:46:00 PM 2/1212013 

### 3:47:00 PM 2 / 1212013 

### 3:48:00 PM 2/12/ 2013 

### 3 :49 :00 PM 2/12/2013 

### 3:50:00 PM 2/12/2013 

### 3:51:00 PM 2 / 1212013 

### 3 :52 :00 PM 2/12/ 2013 

### 3:53 :00 PM 2 / 12/2013 

### 3 :54 :00 PM 2 / 12/ 2013 

### 3 :55:00 PM 2/12/ 2013 

### 3 :56 :00 PM 2/12/ 2013 

### 3 :57 :00 PM 2/12/2013 

### 3 :58 :00 PM 2/12/2013 

### 3 :59 :00 PM 2 / 12/2013 

### 4 :00 :00 PM 2/12/ 2013 

### 4 :01 :00 PM 2/12/2013 

### 4 :02 :00 PM 2/12/2013 

### 4 :03 :00 PM 2/12/ 2013 

### 4:04:00 PM 2 / 1212013 

### 4:05:00 PM 2/12 / 2013 

### 4:06:00 PM 2/12/2013 

### 4:07:00 PM 2 / 12/2013 

### 4:08:00 PM 2 / 12/2013 

### 4:09:00 PM 2/12/ 2013 

### 4:10:00 PM 2/12/2013 

### 4:11 :00 PM 2/12/2013 

### 4:12 :00 PM 2/12/2013 

### 4 : 13 : 00 PM 2112/2013 

### 4 : 14 :00 PM 2/12/2013 

### 4 : 15 :00 PM 2/12/2013 

### 4 : 16 :00 PM 2/12/ 2013 

### 4 : 17 :00 PM 2 / 1212013 

### 4 : 18 :00 PM 2 / 12/2013 

### 4:19:00 PM 2 / 12 / 2013 

### 4:20:00 PM 2 /12/ 2013 

### 4:21:00 PM 2 /12/2013 

### 4:22:00 PM 2/12/ 2013 

### 4:23:00 PM 2/12/2013 

### 4 : 24:00 PM 2112/ 2013 

### 4 : 25:00 PM 2/12/2013 

### 4 : 26 :00 PM 2/12/2013 

### 4 : 27 :00 PM 2/12/2013 

### 4:28 :00 PM 2 / 12/ 2013 

### 4:29:00 PM 

### 0, % 

### CO, % NO, 

### PPM 14.229 4 .024 2.077 14.225 4.026 2 . 125 14 . 225 4.026 2 . 153 14 . 23 4.025 2.208 14 . 229 4.024 2.12 14 . 217 4.031 2.232 14 . 218 4.033 2 . 241 14 . 238 4 .023 2.107 14 . 237 4 .023 2 . 238 14 . 24 4.022 2 . 123 14 . 237 4.025 2 . 03 14.224 4.028 2.123 14 . 232 4.025 2.026 14.236 4.022 2 . 123 14.232 4 .026 2 . 204 14.23 4.027 2 . 158 11 . 687 4.287 1 . 213 10.019 5.229 0 .025 10.019 5.235 0 .021 10.019 5.239 0.027 6.433 3 . 212 0 .028 0.164 0.182 0 .019 0 . 127 0.167 0 .017 3.699 1.094 0.834 0.105 0.132 0 . 022 7.46 4.079 0.016 10. 038**1-;5.;:;24;;6;........;0; 0:;:2~3:...J**  

### 18 . 123 .....

### ;9.:;4:;:92;:..........;0; . ;01:.,:7...., 19 .008 

### 1-.::.9.;::6::;62::..........;0::;.::;01:;:4:...J 20 .006 7.187 0.024 20 . 952 5 . 157 0 . 015 20 . 953 0 .646 0 . 019 20.953 0.192 0 . 015 20.952 0.193 0 .014 20.875 0 . 213 0 .023 20.785 0 . 228 0.054 20.765 0 . 23 0.074 20.756 0 . 235 0.052 20.741 0 . 235 0.05 20 . 736 0 . 234 0.042 20 . 722 0.234 0.047 20 . 711 0.237 0.047 20 . 698 0.243 0.057 20 . 683 0.249 0.053 20 . 681 0.259 0.059 20 . 672 0.27 0.059 20 . 657 0.283 0 . 052 20 . 646 0.296 0 .052 20 . 642 0.311 0 .046 20.641 0 . 327 0 .047 20.637 0 . 342 0 .047 20.631 0.357 0 .048 20.618 0.375 0.046 20 . 607 0.39 0 .041 20 . 606 0.406 0 .047 20 . 598 0.422 0.053 20 . 592 0.437 0.047 20.588 0 .452 0.043 

### CO PPM 0.382 0 . 38 0 . 365 0 . 373 0 . 38 0 . 356 0 . 344 0 . 389 0 .404 0.409 0.402 0.358 0.381 0.369 0.372 0.368 0.784 -0 . 21 -0.299 -0 . 306 -0.27 0.019 0.058 0.118 0.192 0.192 0.199 0 . 201 0.199 0.196 0 . 192 0 . 206 0 . 199 0 . 196 0.212 0.206 0.219 0.207 0.201 0.194 0.195 0 . 202 0 . 206 0 . 207 0.218 0.217 0.224 0.212 0.215 0.207 0 . 215 0.215 0 . 219 0.225 0 .216 0 .224 0.215 0 .228 

### 0, % 

### 18.834 18.834 18.834 18 . 834 18 . 834 18 . 834 18 . 834 18 . 835 18 . 835 18.83 18 . 809 18 . 809 18.803

18.8 18.784 18.784 18.784 18 .781 18.78 18.782 18.781 18.782 18.781 18 .783 18 .771 18.763 18 .76 18 .755 18 .756 18 .738 18 .733 18 .733 18.733 18.733 18.733 18.73 18.715 18.709 18.71 18.709 18.708 18.689 18.685 18 . 672 18 . 659 18 . 65 18 . 648 18 . 659 18 . 661 18.662 18 . 658 18.637 18.636 18.637 18 . 636 18 . 624 18 . 623 18.615 NO, 

### PPM 0 . 147 0.15 0.142 0.139 0.141 0.138 0 . 131 0 . 143 0 . 14 0.129 0.126 0.131 0 . 132 0 . 119 0.122 0.116 0.121 0.12 0.121 0.111 0.112 0.111 0.118 0 . 11 0.111 0.11 0.111 0 . 107 0.107

0 . 1 0.107 0 .098 0.109 0 . 11 0 . 11 0.109 0.113 0.109 0.097 0.098 0.096 0.103 0 .099 0 .093 0 .098 0 .096 0 .093 0 .09 0.095 0.096 0.095 0.093 0.091 0.093 0.093 0.089 0 .094 0 .086 

### CO PPM 0 . 571 0.567 0 . 564 0.564 0.563 0.567 0.569 0.573 0 . 543 0 . 571 0.57 0 . 568 0 . 538 0.562 0 . 514 0 . 568 0 . 542 0 . 569 0 . 568 0 . 567 0 . 564 0 . 561 0 . 564 0 . 563 0 . 562 0 . 561 0.56 0 . 564 0.561 0.538 0 . 563 0 . 536 0.511 0.537 0.535 0.559 0 . 541 0 . 541 0.442 0.419 0.42 0.416 0.44 0.415 0.414 0.443 0.442 0.442 0.418 0.448 0.421 0.417 0.443 0.418 0.418 0.471 0.523 0.449 

### THC PPM 0.407 0.406 0.407 0.408 0 .408 0 .408 0.408 0 .409 0 .409 0.409 0.408 0 .408 0.408 0.407 0.407 0.406 0.408 0.407 02/C02 bias 

### 0.407 0.407 0.407 

### OA07 Zero bias 

### 0.408 0.407 0.407 Direct Zero 

### 0 .407 0 .407 Direct Span 

### 0 .407 0
. 407 02/ C02 High 

### 0 .407 0.407 C02 Mid 0.407 0.408 0.408 0 .408 0.408 0.408 0.408 0.408 0.408 0.408 0.408 0.407 0.408 0.408 0 .407 0.408 0.408 0.408 0 .408 0.408 0.407 0.407 0.408 0.408 0.408 0.408 0.408Date Time 2/ 12/ 2013 

### 4 : 30 :00 PM 2/ 1 21 2013 

### 4 : 31 :00 PM 2/ 121 2013 

### 4 : 32 :00 PM 2/ 12/ 2013 

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### 4.44:00 PM 2/12/2013 

### 4 :45 : 00 PM 2/ 12/ 2013 

### 4 :46 :00 PM 211212013 

### 4 :47 :00 PM 2/ 12/ 2013 

### 4 :46 :00 PM 2/12/2013 

### 4 :49 :00 PM 2/12/2013 

### 4 : 50:00 PM 

### 0 , % 

### 20 .576 20 .564 20 .5 46 20 .537 20 .522 20 .512 20 .505 20.494 15 . 672 14.445 14.474 14.465 14.462 14.463 14.461 14.46 14.453 14.451 14.451 14.451 14.446 2/12/ 2013 

### 4 : 51:00 PM 14.443 2/ 12/ 2013 

### 4 :52 :00 PM 14 .441 2/ 121 2013 

### 4 : 53 : 00 PM 14.443 2/ 1212013 

### 4 : 54:00 PM 14.443 2/12/2013 

### 4 : 55 :00 PM 14.44 2/12/2013 

### 4 :56 : 00 PM 14.436 2/ 12/ 2013 

### 4 :57 :00 PM 2/ 12/ 2013 

### 4 : 56 :00 PM 2/ 12/ 2013 

### 4 : 59 :00 PM 2/ 12/ 2013 

### 5 :00 :00 PM 2/12/2013 

### 5 :01 :00 PM 2/ 12/2013 

### 5 :02:00 PM 14.4 27 14.422 14.416 14.412 14.412 14.409 2/ 1212013 

### 5 :03:00 PM 14.41 2/ 12/ 2013 

### 5 :04 : 00 PM 14 .41 2/ 12/ 2013 

### 5 :05:00 PM 14 .403 2/12/2013 

### 5 :06:00 PM 14.401 2/12/2013 

### 5 :07:00 PM 14 .401 2/ 1212013 

### 5 :06 :00 PM 14.402 2/ 12/ 2013 

### 5 :09 :00 PM 2/ 1212013 

### 5 : 10 :00 PM 2/ 12/ 2013 

### 5 : 11:00 PM 2/12/2013 

### 5 : 12:00 PM 2/12/ 2013 

### 5 : 13 :00 PM 2/ 1212013 

### 5 : 14 :00 PM 2/ 1212013 

### 5 : 15 :00 PM 2/ 121 2013 

### 5 : 16 :00 PM 2/12/2013 

### 5 : 17 :00 PM 2/12/2013 

### 5 : 16 :00 PM 2/ 12/ 2013 

### 5 : 19 :00 PM 2/ 1212013 

### 5 :20 :00 PM 2/ 121 2013 

### 5 :21 :00 PM 14.409 14 .411 14.417 14.425 14.436 14.446 14.451 14.451 14.451 14.451 14.452 14.451 14.455 2/ 12/ 2013 

### 5 :22 :00 PM 14 .462 2/12/2013 

### 5 :23 :00 PM 14.46 2/ 12/ 2013 

### 5 :24:00 PM 14.46 2112/ 2013 

### 5: 25 :00 PM 14 .463 2/ 1212013 

### 5 :26 :00 PM 14.467 2/ 12/ 2013 

### 5 :27 :00 PM 14.465 

# co , % 

### 0.466 0.46 3 0.496 0 .51 2 0.526 0.539 0 .552 0 .564 0 .574 0 .562 0 .59 0 .597 0 . 604 0 . 611 0 . 616 0.624 0 . 63 0 . 636 0 . 642 0 . 646 0 . 656 0 . 663 0 . 669 0 . 676 0 . 663 0 . 669 0 . 694 0 . 699 0 .7 06 0.712 0 . 719 0.723 0.73 0 .735 0.741 0.746 0.751 0 .759 0.765 0 .771 0 .7 77 0.763 0.769 0.794 0 .796 0 . 604 0 . 609 0 . 615 0 . 621 0 . 627 0 . 633 0 . 63 7 0 . 643 0 . 646 0 . 653 0 . 659 0 . 663 0 . 67 NO, 

### PPM 0 .042 0 .043 0 .042 0 .047 0 .042 0 .041 0 .046 0 .046 1.26 1 .96 2 . 16 2 .006 2 .09 1 . 261 0 . 196 0 .093 0 .065 0 .064 0 .074 0 .062 0 .05 0 .045 0 .045 0 .045 0 . 045 0 .044 0 . 051 0 .047 0 .056 0 .044 0 . 046 0 . 044 0 . 04 0 .042 0 .047 0 .047 0 .049 0 .051 0 .046 0 .042 0 .056 0 .059 0 . 046 0 .05 0 .05 0 .054 0 . 057 0 .051 0 .049 0 .051 0 .052 0 .045 0 .046 0.046 0 .043 0 .046 0 .043 0 .041 

## CO PPM 0 . 232 0 . 227 0 . 231 0.232 0 . 227 0.476 0 .534 0 .553 0 . 254 0.066 1.712 4 .51 4 .565 5 .561 3 . 135 3 .951 4 . 65 4 .716 4 .766 4 . 659 4.661 4 .922 4 . 695 4 .906 4 .917 4 .954 4 .971 4 .915 4 .95 1 4 .94 4 .993 4 .957 4 .961 4 .999 5 .004 5 .02 4 .973 4 .975 4 .969 4 .992 4 .964 5 .011 4 .94 4 .919 4 .966 4 .967 5 .014 5 .017 4 .991 4 .02 0 .29 0 .066 0 .064 2 .679 4 . 561 4 . 566 5 . 25 2 5 .406 

### 0, % 

### 16 .611 16 .595 16.569 16.562 16 .576 16 .574 16 .565 16 .564 16.563 16.562 16.563 16 .564 16 .564 16 .565 16.563 16 .562 16 .561 16 .541 16 .541 16 . 536 18.537 16.536 16 .541 16 .55 18 . 541 16 . 545 16 . 536 16 .533 16 .521 16 . 512 16.513 16 . 506 16 . 501 16 .496 16.466 16.46 16.479 16.46 16.46 16.472 16.479 16.467 16.469 16.489 16.495 16 .503 16.507 16.511 16.506 16 .506 16 .501 16 .499 16.499 16.506 16 .513 16 .513 16 .513 16.507 NO, 

### PPM 0 .0 67 0 .069 0 .09 0 .063 0 .063 0 .06 0 .076 0 .072 0 .062 0 .076 0 .061 0 .077 0 .073 0.069 0.074 0 .066 0 .076 0 .076 0.07 0.076 0 . 076 0 .065 0 .0 76 0 .081 0.075 0.067 0.069 0 .065 0 .0 6 0 .056 0 .056 0.066 0.066 0 .06 0 .054 0 .064 0.059 0.057 0 .06 0 .064 0 .06 0 .053 0 .054 0.055 0 .053 0 .053 0 .053 0 .049 0 .055 0 .054 0 .054 0 .053 0 .053 0 . 053 0 .053 0 .051 0 .056 0 .056 

## CO PPM 0 .423 0.42 0.421 0.446 0.469 0 .422 0.495 0.419 0.42 0.419 0.416 0 . 395 0 . 391 0.416 0.416 0 . 367 0 . 366 0.42 0.416 0 .4 2 2 0.42 0.417 0.415 0.415 0.414 0.415 0.414 0.413 0.418 0.416 0 . 395 0 .416 0.416 0 . 393 0 . 392 0.42 0.419 0 .417 0 . 393 0.414 0 . 366 0 . 343 0 . 394 0.419 0 . 395 0.42 0.42 0.417 0.395 0.422 0 . 397 0.417 0.419 0.422 0.422 0.42 0 .544 0.719 

## THe PPM 0.407 0.407 

### DA06 0.406 DA06 0.406 0.409 0 .406 Unspiked background CO 

### 0.406 0.406 System Zero 

### 0.406 0.409 0.409 System bias 

### 0.409 0.409 0.409 0.409 0.41 0 .409 Start CO Spik i ng RATA Run 1 

### DA06 0.406 0.406 

### DA06 0.406 0.406 

### DA06 0.406 0.406 0.406 Start 2 0.406 D.406 0.406 0 .406 0.409 0.409 0.409 0.409 D.406 0.406 Start 3 0.409 0.409 0.409 0.409 0.409 0 .41 0 .409 0.409 0.409 0.409 0.409 0.41 0.409 0.409 Zero bias 

### 0.406 0.408 OA06 Sp a n bias 

### 0.407 0.407Date Time 2/12/2013 

### 5:28 :00 PM 2/12/2013 

### 5 :29 :00 PM 2/12/2013 

### 5:30:00 PM 2/12/2013 

### 5 :3 1 :00 PM 211212013 

### 5 : 32:00 PM 2/ 12/2 013 

### 5:33:00 PM 2/ 12120 13 

### 5 : 34 :00 PM 2/ 12/2 013 

### 5 : 35 :00 PM 2/ 12/ 2013 

### 5 : 36 :00 PM 2/12/2013 

### 5:37 :00 PM 2/12/20 13 

### 5:38:00 PM 2/ 12/2013 

### 5:39:00 PM 2/ 12/ 2013 

### 5:40:00 PM 2/ 12 / 2013 

### 5 :41 :00 PM 21 12120 13 

### 5 :42 :00 PM 2/ 1212013 

### 5 :43 :00 PM 2/ 12/ 2013 

### 5 :44 :00 PM 2/12/2013 

### 5 :45 :00 PM 2/12/2013 

### 5 :46 :00 PM 2/12/2013 

### 5 :47 :00 PM 2/12/2013 

### 5 :48 :00 PM 21 12/2 013 

### 5 :49 :00 PM 2112/2013 

### 5 : 50 :00 PM 21 12/ 2013 

### 5:51 :00 PM 2/ 12/ 2013 

### 5:52:00 PM 

### 0 , % 

### 14.463 14.459 14.461 14.461 14 .452 14.45 14.45 14 .45 14.442 14.427 14 .418 14.411 14.411 14.413 14 .414 14.419 14.42 14.422 14.424 14.425 14.43 14 .435 14.443 14 .45 14 .45 2/12/2013 

### 5:53 :00 PM 14.45 2/ 12/2013 

### 5:54 :00 PM 14.453 2/ 12/2013 

### 5 :55 :00 PM 14.459 2/ 12/ 2013 

### 5 :56 :00 PM 14 .459 2/ 12/2013 

### 5 :5 7 :00 PM 14 .46 2/ 12/ 2013 

### 5 :58 :00 PM 2/ 12/2 013 

### 5 :59 :00 PM 2/12/2013 

### 6 :00 :00 PM 2/12/ 2013 

### 6 :01 :00 PM 2/12/2013 

### 6:02 :00 PM 2/12/2013 

### 6:03 :00 PM 2/12/2013 

### 6:04 :00 PM 2/12/20 13 

### 6 :05 :00 PM 2/12/2013 

### 6 :06 :00 PM 2/12/2013 

### 6 :07 :00 PM 2/ 1212013 

### 6 :08 :00 PM 2/ 12/2013 

### 6:09 :00 PM 2/12/2013 

### 6:10 :00 PM 2/12/2013 

### 6:11 :00 PM 14 .458 14.46 14 .461 14 .466 14.469 14.466 14.466 14 .464 14 .464 14.463 14.461 14.465 14.465 14.468 2/ 12/ 2013 

### 6 : 12 :00 PM 14.471 2/1212013 

### 6 : 13 :00 PM 14.474 21 12 / 2013 

### 6 : 14 :00 PM 14.476 2/ 1212 013 

### 6 : 15 :00 PM 2/ 1212013 

### 6 : 16 :00 PM 2/ 1 2/20 13 

### 6:17 :00 PM 2/12/2013 

### 6:18 :00 PM 2/12/2013 

### 6:19 :00 PM 2/ 12/2013 

### 6:20:00 PM 2/ 12/ 2013 

### 6:21 :00 PM 2/ 1212013 

### 6 : 22 :00 PM 2/ 121 2013 

### 6:23 :00 PM 2/ 12/2013 

### 6:24:00 PM 2/ 12/ 2013 

### 6:25:00 PM 14.477 14.48 14.486 14.491

14.5 14.502 14 .51 14.51 14 .511 14 .513 14 .521 

# co, % 

### 0 . 874 0 . 879 0 . 883 0 . 889 0 . 892 0 . 897 0 . 901 0 .9 06 0 .909 0 .913 0 .918 0 .922 0 .927 0 . 931 0.934 0.939 0.942 0 .946 0.949 0.952 0.955 0.957 0 .96 0 .963 0 .966 0 .969 0 .973 0 .977 0 . 98 0 . 983 0 . 985 0.987 0.991 0 .993 0.995 0.999 1.002 1.004 1 .00 7 1.008 1.009 1.011 1.013 1 .014 1 .016 1 .0 19 1 .02 1 .0 23 1 .025 1 .028 1.03 1.032 1.033 1.035 1 .0 37 1 .037 1 .039 1.04 NO , 

### PPM 0 .044 0 .047 0 .047 0 .05 0 .054 0 .051 0 .052 0 .047 0 .043 0 .0 5 0 . 05 0 .047 0 .045 0 .048 0 .051 0 .048 0.043 0 .042 0.048 0 .047 0 .044 0 .046 0 .049 0 .042 0 .056 0 .042 0.Q35 0 .036 0 .039 0 .041 0 . 04 0 .043 0 .043 0.032 0 .037 0 .037 0 . 034 0 .037 0.Q3 5 0 .042 0.046 0.046 0 .041 0 .033 0 .037 0 .037 0 .04 0 .039 0.039 0 .043 0 .041 0 .036 0.04 0 . 045 0 .038 0 .037 0.04 0 .04 

### CO PPM 5.175 5.149 5 . 112 5 . 156 5 . 157 5 . 168 5 . 206 5.14 5.178 5.172 5.203 5 . 21 5 . 213 5.219 5 . 196 5 . 171 5 . 193 5.145 5.144 5.171 5.121 5 . 116 5 . 149 5 . 158 5 . 201 5.279 5.203 5.262 5 . 283 5.191 5.308 2 .565 0.087 0.06 2.69 4.558 5.267 5.54 

### 5 . 293 5.281 5.271 5 . 324 5.277 5.263 5.281 5.291 5.298 5 . 292 5 . 283 5 . 247 5 . 305 5.249 5.246 5.217 5 . 178 5 . 216 5 . 231 5 . 183 

### 0, % 

### 18.498 18.488 18.477 18 .466 18 .458 18.454 18 .438 18 .438 18.419 18.413 18.41 18.411 18.413 18 .412 18.411 18.412 18.41 2 18 .412 18 .406 18.402 18.403 18.41 18.413 18.411 18.412 18.411 18.41 18.412 18 .406 18 .394 18 .398 18.401 18.405 18.41 18.4 18 .39 18 . 369 18 . 366 18 . 365 18 .362 18 .3 41 18 . 34 18 . 34 18 . 34 18 . 34 18 .3 35 18 . 315 18 . 315 18 . 316 18 . 328 18 . 341 18.341 18.341 18.341 18 . 341 18 . 341 18 .328 18 .3 16 NO , 

### PPM 0 .064 0 .057 0 .058 0 .0 52 0 .053 0 .061 0 .051 0 .053 0 .052 0 .048 0 .05 0 .055 0 .056 0 .05 0 .045 0.039 0.046 0.Q41 0 .041 0 .047 0.043 0 .046 0.043 0 .0 38 0 .035 0 .034 0 .035 0 .034 0 .038 0 .035 0 .036 0 .037 0.038 0 .041 0.038 0 .04 0.048 0.047 0 .046 0 .043 0.053 0.041 0.036 0.038 0.043 0.037 0 .038 0 .039 0.048 0 .039 0.04 0.041 0 .041 0 .038 0 .026 0 .03 0 .029 0 .025 

### CO PPM 0 .675 0 .573 0 .5 72 0.494 0.419 0.417 0.413 0.416 0.416 0.412 0.41 0.415 0 .415 0.415 0 .417 0.415 0.411 0.413 0.415 0 .416 0.414 0.411 0.413 0 .414 0.414 0.415 0.414 0.411 0.432 0 .409 0.411 0.408 0.409 0.408 0.411 0.412 0.412 0.417 0 .413 0.413 0.417 0.416 0.421 0.423 0.418 0 .4 22 0.423 0.419 0 .422 0 .418 0 .418 0.421 0.42 0.419 0.42 0 . 392 0 . 389 0.419 

## THe PPM 0.407 Start 4 Q.408 0.407 0.407 0.407 0 .407 0.408 0 .407 0.407 0 .407 0.407 Start 5 0 .407 Q.408 Q.408 Q.408 0.409 Q.408 Q.408 Q.408 Q.408 0.408 Start 6 Q.408 0.407 Q.4 0 8 Q.408 0.409 0.409 Q.408 0 .407 0.408 0.408 0.408 0.408 0.409 Zero bias 

### 0.408 0 .408 CO bias 

### 0 .409 0.409 0 .408 Start 7 0 .409 0.409 0.41 0.41 0.41 0 .41 0.41 0.41 0.41 0.41 Start 8 0.41 0.41 0.41 0.411 0.411 0.411 0.41 

### 0 .411 0.41

### 0, CO, NO , CO 

### 0, NO, CO THC Date Time % % 

### PPM PPM % 

### PPM PPM PPM 2/12/2013 

### 6:26 :00 PM 14 .519 1.042 0.033 5.214 18.315 0.031 0 .42 0.41 Start 9 2/12/2013 

### 6 :27:00 PM 14 .524 1.043 0 .036 5.207 18.315 0 .033 0.419 0.41 2/12/2013 

### 6 : 28 : 00 PM 14 . 556 1 .06 0 .034 5 . 252 18 . 314 0 .028 0 . 393 0.409 2/ 12/ 2013 

### 6 :29 :00 PM 15 . 656 1.097 0 .031 5.265 18 . 293 0 .026 0 . 394 0.409 2/ 12/ 2013 

### 6 : 30 :00 PM 18.467 1.014 0 . 256 5.261 18 . 29 0 .031 0 . 389 0 .409 2/ 1212013 

### 6 : 31 :00 PM 20 .026 0 . 842 0.461 5.194 18 . 29 0 .034 0 .561 0 .4 0 9 2/ 12/ 2013 

### 6 : 32 :00 PM 20 . 55 0 .687 0.465 5 . 202 18 .29 0 .027 0 .977 0 .409 2112/ 2013 

### 6 : 33 : 00 PM 20 . 723 0.582 0.463 5.244 18 . 295 0 .041 0 . 911 0.409 2/ 12/2013 

### 6 : 34 :00 PM 20 .792 0.515 0.458 5.24 18 . 315 0.028 0 .792 0 .409 2/12/2013 

### 6:35 : 00 PM 20 . 826 0.468 0 . 325 5.278 18 . 315 0.031 0.593 0.408 2/12/2013 

### 6 : 36 :00 PM 20 . 852 0.438 0 . 177 5.28 18.316 0 .033 0.543 0.408 2/ 12/ 2013 

### 6:37 :00 PM 20 . 862 0.417 0 . 101 2 . 346 18 . 315 0 .032 0.414 0.409 2/ 12/ 2013 

### 6 : 38 :00 PM 20 .916 0.496 0 .068 0 . 145 18 . 326 0 .029 0.421 0.409 Zero bias 2/ 1212013 

### 6:39 :00 PM 20 .967 0 . 183 0 .023 0 .557 18 . 338 0 .027 0 .418 0 .409 2/ 12/ 2013 

### 6 :40 :00 PM 20 . 941 0 . 163 0 .014 4 . 321 18 . 34 0 .023 0 .419 0 .41 2/ 12/ 2013 

### 6 :41 :00 PM 20 .953 0.155 0.013 4.566 18 . 34 0 .029 0.417 0 .41 CO bias 2/ 12/ 2013 

### 6:42 :00 PM 20 .971 0 . 144 0 .019 2.657 18 . 34 0 .035 0 .416 0.41 2/12/2013 

### 6:43 :00 PM 20.991 0 . 138 0 .01 0.146 18 . 34 0 .031 0.417 0 .409 Cal Zero 2/12/2013 

### 6:44:00 PM 21.013 0 . 134 0 .019 6.595 18 . 341 0 .026 0.42 0.41 2/ 12/ 2013 

### 6 :45 :00 PM 21 .014 0 . 131 0 .02 9.877 18 . 342 0 .03 0.42 0.41 2/ 12/ 2013 

### 6 :46:0 0 PM 21 .026 0 . 129 0 . 014 9 . 625 18 . 342 0 .032 0 .418 0.41 2/ 12/ 2013 

### 6 :47 :00 PM 21 .047 0 . 127 0 .011 9 . 619 18 . 342 0 .03 0 . 396 0.41 Cal H igh 2/ 12/ 2013 

### 6 :48:00 PM 21 .056 0 . 127 0 .019 6 .765 18 . 352 0 .035 0 . 369 0.409 2/ 12/ 2013 

### 6 :49 :00 PM 21 .063 0 . 127 0 .011 4.599 18 . 363 0 .036 0 .417 0 .409 2/ 12/ 2013 

### 6 : 50:00 PM 21 .062 0 . 127 0 . 011 4 .581 18 . 352 0 .035 0 .414 0.409 CO M i d 2/12/2013 

### 6 : 51 :00 PM 21.055 0.129 0 . 014 2 . 264 18 . 34 0 .032 0.418 0.409

## Appendix 

## C.3 Ammonia Data 

## by SCAQMD Method 207.1

R041 0688 C-7AMMONIA TEST RESULTS SUMMARY Client Gemma Parameter 

### location CPV Sentinel Fuel Unit 4 Oata By Test Number CPV Senlinel-4-NH3-106-1 CPV Sentinel-4-NH3-107-2 Reference T emperalure, F 

### 60 60 Test Date 2/ 11 /2013 2/11/2013 Test Method SCAQMD 207
. 1 SCAQMD 207
. 1 Sample Train 9-P&M 9-P&M Meter Calibration Factor 0.992 0 . 992 Stack Area (sq tt) 143 . 14 143 . 14 Samp l e Time (Min) 

### 60 60 Barometric P ressure (in Hg ) 29.6 4 29 .64 Start T ime 10 :06 11 :40 Stop Time 11:19 12:54 Meter Volume (act) 45 .3 41 48.446 Meter Tem perature ( F) 59 . 1 59.5 Meter Pressure (iwg) 1 . 50 1 . 50 Liquid Volume (m!) 113
. 3 96 .0 

### Stack 02 (%) 13.29 13 . 15 Slac k NOx (ppm)@ 15% 02 2 . 34 2 . 18 Uni t load MW 

### 106 107 F ue l Flow Rate , hscfh 8 , 830 8 , 854 Standard Sample Volume (SC F) 4 4 .795 47
. 828 Mo is t ure Fraction 0
. 105 0
. 085 Stack F low Rate (dscfm , 60 of) 383,018 357 , 556 Stack Flow R ate (dscfm, 70 of) nla nla Gas Constant (ft-Ibflltrmole-R) 1545
. 33 1545
. 33 Standard Pressure (lbfIft2) 2116.224 2116
. 224 M olecular Weight NH3 (Ib/ltrmo le ) 17 

### 17 SpecifiC Molar Volume (ft3/Ib-mole) 379 .50 379
. 50 Ma ss Conversi on (lb/ug) 2
. 20E-09 2
.20E-09 02 Correction Fa ctor (%) 

### 15 15 Mass NH 3 (ug/sample) 2229
. 534 2432
. 571 Mass NH3 (mg) 2
.230 2
.433 Mass NH3 (Ib) 4
. 91E-06 5.36E-06 PPM NH31flue gas) 

### 2.4 2 ,5 PPM NH3 @ 02 Correction 1 , 9 1 , 9 Ib/hr 2
. 52 2
. 40 IblMMscf fuel 2
. 85 

### 2 . 72
NH3 EQUATIONS , ppm NH 3 

### = ( ma ss NH 3 * Gas Const * Ref Temp * 106 )/(Sample vol. • Press· MW) ppm NH3 @ 02 correction 

## =ppm * (20.9-02 Corr)/(20
. 9 -% 02) NH 3 na tural gas AA, SS, RM , JM CPV Senlinel-4-NH3--3 Average Umit

13 . 22 2 . 26



### 2 . 5 1 , 9 5 

### 2.46 2
. 7854AMMONIA TEST RESULTS SUMMARY Client Gemma Parameter 

### location CPV Sentinel Fuel Unit 4 Data By Test N umber CPV Sent in eI4·NH3 ·81·1 CPV Sent inel-4 · NH3 · 80 · 2 Reference Te mperature, F 60 60 Test Date 211112013 211112013 Test Method SCAQMD 207
. 1 SCAQMD 207
. 1 Sample Train 9-P&M 9-P&M Meter Calibration Factor 0.992 0
. 992 Stack Area (sq tt) 143 . 14 143 . 14 Sample Time (Min) 60 60 Barometric Pressure (in Hal 29
. 64 29
. 64 Start Time 15:45 17 : 10 Stop T i me 1652 18 : 19 Meter Volume (act) 37
.865 39.500 Meter Temperature ( F) 58
.6 57
.6 Meter Pressure (iwg) 1
. 50 1.50 Liqu id Vo lum e (mil 83
. 1 661 

### Stack 02 (%) 13
. 81 13
. 80 Stack NOx ( ppm )@ 15% 02 2 , 07 2 , 30 Un it Load MW 81 80 Fue l Flow Rate hscfh 7018 6961 Standard Sample Volume (SCF) 37
.445 39
. 138 Moisture Fraction 0
. 094 0
. 073 Stack Flow Rate (dscfm , 60 of) 304 , 102 311 ,648 Stack Flow Rate (dscfm 70 

### of) nla nla Gas Constant (ft-Ibfllb-mole-R) 1545 . 33 1545 . 33 Standard Pressure (lbf/ft2) 2116 . 224 2116.224 Molecular Weight NH3 (Ibllb-mole) 17 17 Specific Molar Volume (ft3/Ib-mole) 379
. 50 379 , 50 Mass Conversion (Ib/ug) 2.20E-09 2.20E-09 02 Correction Factor (%) 15 15 Ma ss NH3 (ug/sample) 931
. 021 777.1 18 Ma ss NH 3 (mg) 0
. 931 0 . 777 Mas s NH 3 (I b) 2
. 05E-06 1 , 71E-06 PPM NH3 (flue oas) 1
. 2 1 , 0 PPM NH3 @ 02 Correction 1,0 0 , 8 Iblhr 1
.00 0.82 Ib/M M scf fuel 1.42 1
. 18 NH3 EQUATIONS : ppm NH3 

## =(mass NH3* Gas Canst * Ref Temp * 106 )/(Sample vo l. • Press' MW) ppm NH3@02correction= ppm' (20 . 9-02 Corr)/(20 . 9 -% 02) NH3 natural gas AA , SP , 55 JM AveraQe Limit

13
. 8 1 2
. 18

1
. 1 0 , 9 5 0
. 91 1 , 3002AMMONIA TEST RESULTS SUMMARY Cli e nt Gemma Parameter 

### location CPV Sentinel Fuel Unit 4 Oata By Test Number CPV Sentinel-4-NH3·55·1 CPV Sentinel-4- N H3-55-2 Reference Temperature, F 60 60 Test Date 2/1212013 2/12/2013 Test Method SCAQMD 207
. 1 SCAQMD 207.1 Sample Train 9-P&M 9-P&M Meter Calibration Factor 0.992 0992 Slack Area (sq 

### ftl 143
. 1 4 143.14 Sample Time (M in) 60 60 Barometric Pressure in 

### Hql 29.7 4 29
. 74 Start Time 11 : 58 13 :30 Stop T ime 13 :07 14:39 Meter Volume (act) 45.874 41
. 937 Meter Temperature (F ) 77 .6 69
. 6 Meter Pressure (iwg) 150 1
. 50 Liquid Volume (ml) 89
. 2 78
.6 

### Stack 02 (%) 14 .27 14 . 26 Stack NOx (p pm ) @ 15% 02 2
. 16 1
. 86 Un it load MW 55 55 Fue l Flow Rate , hscfh 5 , 337 5,341 Standard Sample Volume (SCF) 43
. 909 40
. 747 Moisture Fraction 0
. 086 0
. 082 Stack Flow Rate (dscfm , 60 of) 270 , 908 267,286 Stack Flow Rate (dscfm, 70 of) nla nla Gas Constant (ft-I bfllb-mole-R) 1545.33 1545 .33 Standard Pressure (lbfIft2) 2116.224 2116.224 Molecular Weight NH 3 (Ib/lb-mole) 17 17 Specific Molar Volume (ft3/1b-mole) 379.50 379.50 Mass Conversion (Ib/ug) 2.20E-09 2.20E-09 02 Correct io n Factor (%) 15 15 Mass NH 3 (ug/sample) 786.041 813
. 625 Mass NH 3 ( mg) 0 . 786 0 .814 Mass NH3 (I b) 1
. 73E-06 1
. 79E-06 PPM NH3 (flue oas) 0
. 9 1
. 0 PPM NH3 

### t8l: 02 Correction 0
. 8 0
. 9 Iblhr 0
. 64 0
. 71 I b

/MMscf fuel 1
. 20 1
. 32 NH3 EQUATIONS : ppm NH3 

### = (mass NH3* Gas Const " Ref Temp" 106 )/(Sample vol. .. Press· MW) ppm NH3@02cor rection= ppm" (20 .9 -02 Corr)/(20 .9-%02) NH 3 natura l gas AA MC RM , JM Averaqe Limit

14
. 26 2
. 0 1

0
. 9 0
. 8 5 0
.67 1
. 2616

## WET CHEMICAL SAMPLING SYSTEM DATA AND WORKSHEET - STANDARD CLIENT : 

### C--1eMMCt, LOCATION : 

## ":>eN ;! ' >V, 

### I DATE : 

### -zlll [13... 

### RUN NO : :; - 

### 'I 

# )(iF IV 

# 1-1; - 

# \PO \ 

# F-"\-,,, \**OPERATOR ~**  

### .**.J.)--,;M;;>-,~**

## ____ _ METER BOX NO : 

## "I PM METER to H@ :· -; \ - ."=

S':!

J-',

c:: , '-------- METER Yd: Q .",,,, 

### 2- STACK AREA, 

### FT' : \'\, ...\'\ TRAVERSE POINT;':S!'-,

# ~M""IN-cI"'PO::07:1 N"'T:-

# ' ;; ""

- 7

/ 1

--: 2 

# =-- toH; 

### p'/Pr X to P : 

# j Probe Condition , pre l post test
. 

## ...-"J '---

_ _ _ Silica Gel Expanded,**"" rJ** **~** 

### ___ _ Filter Co n dition**ft :?"e** **st:. -,-",--,-** **--,~,--** 

## __ _ Check Weight _-'-

____ ___ _ Meter to P Point Time Volume, 

## ft ' in. H , O**.;J ~**  

### 1001..>**.,~,** 

### ;J"l6**~** 

## I. 

# '3

2- 

## ivi 

## I 

# 1 1 / . </ 1 

### '" I '" .'2... 

## i, Go LI 

### 102.1**"\~ QI'"**  

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# 111- X t. P : ' Probe ondition, pre/pos t test: /,/ Silica Gel Expanded, Y I N : 

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# ¥ Check Weight:
______ _ Meter t. P Point 

### Time 

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## :---'''' Z "''1T-

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### PROBE ID NO/MATERIAL: #S", ·

### ,-,**,,- ,--** **,,- ,-** **",Q**

### ______ _ PROBE LENGTH : 

## '7'**NOZZLEIDNO M~A~T=E** **~R~ IA** **-: --------**  NOZZLE DIAMETER :---,;-';-: C';t-

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________ _ FILTER NO/TYPE : 

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### # Contents Post · T est· Pre·Test = Difference 

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## CI CHAIN OF CUSTODY: SAMPLE CUSTODIAN, -:-':- A

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'--
__ SAMPLER 

### (Z..M .)-IV' 

### SAMPLE CUSTODIAN,-.: M .:.:

L ==--

_ _ Tot al:

_____________ _ t. H Stack Pro be Filter Imp , Out Meter Temp , O F Vacuum 

## 0 , P
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### Temp , O F T e mp , O F Temp , O F Temp , O F In Out in
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. 

### % in . 

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### O 

### L'i 

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## '7(, '1' 

# « I II**~** 

### l\I 

## I

. 

### Comments:

____________________________________________________________________________________________________________________ __

Date of last revision 

### 1 /25/2 013 Page
__ of
__ 

### DS834049 Master Document Storage l Forms l DatasheetslField Datasheets

## WET CHEMICAL SAMPLING SYSTEM DATA AND WORKSHEET - STANDARD CLIENT : 

# C:::1f{ll\V\/T' LOCATION : 

# XN\L'"**~\** DATE :?. 

# !..L:?- 

# Iy RUN NO: 

## S**~** 

## '1 

## !)I It..

- 

## ful_\)**Q,1,'kA'~L.** - 

## NH:<, OPERATOR:=,- ,,-,.,.. _____ _ METER BOX NO :

_ "'?

# "Vc..:"' 2-
____ _

# ~~i~~**~~@-, ~\** .

# .:,-;'!';:"~iCL;;.-**------** STACK AREA, FT' : TRAVERSE POI

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: -- Ll. H=
__ XLl.P: Probe Condition, pre lpo st tesl:
____ _ Silica Gel Expanded, YIN:

____ _ _ Filter Condition after Tesl:
_____ _ Check Weighl:
_________ _ Meter Ll. P Point 

### Time 

### Volume, ft ' in . 

### H 2 

### O

Average :

- - - 

### AMBIENT TEMPERATURE : 

# ':;-.0 BAROMETRIC PRESSURE:- : ----''-'''''------ - - ASSUMED MOISTURE: PITOT TUBE COEFF, C '- p-: 

## - 0

:-

. """"'1-------- PROBE ID

### NOIMATERIAL:**r-'lSi;y.~ ?=** **'8** ________ _ PROBE LENGTH: 1 

### NOZZLE ID NO I M''''A'''T=E-=R'''IA'::-L- : 

## -

tJ

"r"''I-:--- ------ NOZZLE DIAMETER :_,-;N-,\{It""-T_--------- FILTER NOfTYPE: 

## NI 'f' PRE-TEST LEAK R"'A"'T"'E"' : "':-i[.'::-e

### :- <o

:1 ')... -:-;;C"' F
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## Mc;;@**::--"'I$'"~-c i::-n** . ..,

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### <0. 

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. PITOT LEAK CHECK - PRE : 

## V POST : <.--- 

### CHAIN OF CUSTODY: SAMPLE CUSTODIAN 

### ML SAMPLER SAMPLE C<;-U"'S""T""O;:CDIC;;-A"'N-, ,,,( :-:--- 6 H Stack Probe Filter Imp. Out in
. H 2 O Temp, O F Temp , O F Temp, O F Temp. OF Imp. 

### # Contents Post-Test - Pre-Test = Difference 

### (j
. \ 

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# H J 

## S0'1 7'b), 

# 2. 

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# Of 1-11. 

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Total : _____________ _ Meter Temp , O F 

### Vacuum 02 P
. static In Out in. Hg. 

### % in . 

### H 2 

### O

I



### Comments :

________________________________________ __________________ _

Date of last revision 

### 1 12512013 Page
__ of
__ 

### D8834049 Master Document Storage l FormslDatasheetslField Datasheets

### AMMONIA ELECTRODE CALIBRATION CURVE "ample t<oom 

### NH 3 concentration log NH3 concentration Ele ctrode potential Temperature Temperature**(~g** 

### NH 3 1 ml as N) (mV) (C) (C) t 0.000 90.8 23.2 23
. 2 5 0 .699 53.1 23.2 23.2 20 1
. 301 18.6 23.2 23.2 100 2.000 -22.2 23.2 23.2 Ammonia Electrode Calibration Curve y = -56.5667< + 

### 91
.6417 

### 2/13/2013 R' = 0
.9996 

## 100
. 0 

# ;;- 80.0 .§.



# .. 60
. 0 

# '" I: 

# " 40
. 0 

# - 0 11. 

# " 20.0 "C 0**~** 

# - 0.0 

# ... 1.500

# ~OO " iii 

# -20.S' 00 0.500 1.000 -40 .0 logarithm of 

### the concentration of 

### ammonia**(~g** 

### NH,I ml 

### as N) slope V-intercept 

### Concentration ("9 NH 31 ml 

### as N) 1 5 20 100 Calculation: -56
. 5667 91
. 6417 Va lue LR line 10349 4
. 8012 19.5546 102.9250 Regression Line : P=M'log("g of NH,I ml as N)+B 

### Difference 0
.0349 -0.1988 -0.4454 2
. 9250

Measured Concentration of Ammonia (C) 

### in "g 1 ml NH3 as N : C=10 ,P.8V M 

### where P = electrode potential , M= slope (must be -57±3) and B= intercept 

### % 

### Difference 3.4857 -3
. 9760 -2.2270 2.9250

All standards were prepared in 0
. 04N H 2 

### S0 4 

### and allowed to equilibrate to room temperature
. 

## 2. 00AMMONIA BY ION SELECTIVE ELECTRODE ANALYS I S CALCULATION Cl ient! Locat ion : Sample Location: District Method: Sample Date : Analys i s Date: Analyst's Initials : Calibration Curve : 

## R' Sample Sentinel Unit 4 100% SCAQMD 207 .1 2/ 12/2013 2/13/2013 

## RF y= -56.5667 x+ 91
. 6417 0.9996 

### P Conc. mV**g** NH 3/ml as N 28 

### ug NH3/ ml as N 10.4**r~-"at** 28 ug NH3/ml as N 10
. 6
1-NH3 - 100 -1 64
. 2 repeat 1- NH3-100-1 65
. 0 2-NH3 - 100- 1 619 repeat 2- NH3 -100-1 62.2

sp i ke 2-NH3 100-1 15
. 6

repeat spike 15.6 28 NH3/ml as N 10
. 7 repeat 28 UQ NH3/ml as N 10.7 Reagent Blank 145
. 6 repeat Reagent Blank 145.0 Fie ld Blank 125.8 repeat Field Blank 126.1

DI H20 Blank 147.5 Repeat DI H20 Blank 146.9 28 NH3/mt as N 11
. 8**r~at** 28 ug NH3Iml as N 11.7
Notes: Measured Concentration of Ammo n ia (C) in**~g** NH3/ ml as N C= 1 O (P-8)/M 

### P = electrode potential (mV), M=slope and B=intercept 27.303 27.082 3
. 056 2.958 3.356 3.315 22
. 094 22
. 094 26
. 972 26
. 972 0.111 0.114 0.2 49 0.246 0
. 103 0.105 25.791 25.896

Average Measured Ammonia Concentrat i on (Cavg) 

## = (C1 + C2)/2 where C1, C2 resu lts from dupl icate analyses ().l g NH3/ml as N) Cavg**(~g** NH,Iml as NH3) = Cavg (" g NH3 1 ml as N)' 17
. 03/14.01**~g** NH3 1sample = Cavg**(~ g**  NH,Im l as NH 3 ) • TV Used 100 ml of samples and standards with 2 ml ISA and constant stirr in g rate . All solutions turned blue and r emained blue with I SA unless otherw ise i ndicated. Sample PH and Temperatures can be found on the laboratory datasheet. CavgasN
27.192

3 .0 07 3 .3 35 22
. 094 26.972 0.1126 0.2475 0.1042 25.843

Maximum samples (including blanks ) between 28 ug/ml check standard is 5 samples ana lyzed in dup licate. TV C avg as NH3**~9** NH,I (ml) sample NA 33
. 054 NA

610 3.655 2229
. 534 600 4.054 2432
. 571 NA 26
. 857 NA NA 32
. 786 NA NA 0.137 NA 405 0
. 301 121
. 823 NA 0
. 127 NA NA 31.414 NA

### AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS QUALITY CONTROL ClienV Location: Sample Location: District Method: Sample Date: Analysis Date: Analyst's Initials:
Sample 28 ug NH3 1 

### ml as N repeat 28 ug NH3/ml as N 1-NH3 -100-1 repeat 1- NH3 -100-1 2-NH3 -100-1 repeat 2- NH3 -100-1

spike 2-NH3 100-1 repeat spike 28 NH3/ml as N repeat 28 ug NH3/ml as N Reagent Blank repeat Reagent Blank Field Blank repeat Field Blank DI H 2 

## 0 Blank Repeat DI H 2 

### 0 Blank

28 NH3/ml as N repeat 28 ug NH3/ml as N 

## Notes: Sentinel Unit4100% SCAQMD 207.1 2/12/2013 2/13/2013 RF

% recovery NA

NA NA 97.88

NA NA NA NA NA
spike: 100 ml sample 

## + 2 ml (1000 fIg NH3 1 ml as N) Matrix Spike Percent Recovery (%R) %R 

# =(C spike*O 104 - Csample*0.1 02)/2 *100 Cspike 

## = average result of matrix spike (fIg NH31 ml as N) RPD % 0
. 81

3.26 1.22 0.00 0.00 -2.44 1
. 22 -2.44 -0.41 RPA % -2.885

NA NA NA -3
. 673

NA NA NA -7
. 703

Relative Percent Difference (RPD) 

## = (C1-C2)1 

### Cavg *100 (must be 5% or less) Relative Percent Accuracy (RPA) (must be 10% or less) RPA = 

### (Cavg-theoretical value of standard)1 theoretical value of standard * 100

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project #:
______ District Method: SCAQMD 207
. 1 Sample Date: 

# ?/12/13 ClienllLocation: 

# S(01.iOe. 

# f Calibration Date:

# ~! 

# /13 Analysis Date: 

# Z./l3/1 

# 3 Sample Location: 

# Una:; L.( Calibration

# Curve:V-~.~1 X

# ~ +9/. 

# "'IN Analyst's Initials: 

# R 

# r -,rO/ 2 

## 0 "-90 Test #'s:
__ 

### ++-""':::!..Lc.!?.2...-
__ 

## R : • 7 

# 'f Sample Electrode TV Cone. 

## Cavg fl9 NH31 Commentsl 

## Temp/pH Potential (ml) fl9 NH 3 - (fl9 NH3 sample

(mV) N Iml 

## - N I 

## mil Standard Check: Percent Recovery: 28 J.Jg NH,Iml 

# IO·V 

# n. 303 Repeat 28 

## 1&.(, 

# 21. Ml 

# nJ'r. 2- 

# /- f/!/, - f(X:) - I (.'(.1. 

## "3. 

# os," 

# &cct /JI/h /00 - \ (,5,-0 

## (Plo 

# 2J1!:>""f 

# :? 

# ·coer 221. 1.!) 

# pH <. 2. 

# T:::23.L( 

# 2·#1/,

- lro

- 

# I (,1-"( 

# <.**~,,(.** 

# 1f6Jl.d 

# 2##, ICfJ

- 

# I {.. 2..J. 

# Iboo 3·3/5" 

# 3-**3~S-** 

# 2 '132. S; 

# I 

# "Ii <:. 2.. 

# 7"='1.32. (

# ~/),'Ile. 2.. 

# il;, 1M

- 1 

# I S.(,. 

# 2. 7. 

# ·01'1



# n. J 

# _'5/)/1(, {S.c, 

# 22.di'-/ 

# 22.6'N 

# re.. r rfl>etl/::'t,j' 

# ,tt o 

# 2fUIL ID.1- 

# 2('·171

# ro:·_~tV 2J.

# k'6~ 

# to. 1**2~.111.** 

# Kent 

# ne.a o.no./-

# p.~K.**Iqs.~** 1'>.111 

# I A II**~oL** 

# t. i Crtt,5 

# IJ:**~~** 

# RfJ. 11./5.0 CJ. 

# /J '{ o. 

# ft2r: 

# -k,·kJ 

# c..C**fi~** fd, 

# n Ir.N>1<. 

# 125-8' ().1'fC, 

# 23.2- 0 

# c.. 

# !/2 'At',c**~** A /7.(,.( D.Nr. 

# o. ),475 

# IDlJ ;r-, A{c,y.,k..**I~T'S** ID.l03

# I~**~** 

# //2,.:1: 

# IY 

# /1.0 t3 I 

# K. 1"1 (,.**~** 

## O·lb:> 

# D./OL{2... Notes: Total volume of samples and standards used: 100 ml Volume of pH adjusting ISA used in ml: 2 ml Absorbing solution: 0
. 1 N H2S04 Calculations: Cone. (fl9 NH3 - N 1 

## ml) 

## = 10 (P-B)IM 

## P 

# =electrode potential, B 

# = y·intercept and M 

# =slope Cavg 

## = average result of duplicate analyses (fl9 NH, - N I 

## ml) 

## = (C1 +C2)/2 

## flg NH31 sample 

## = Cavg* 17.03/14.01 

## * TV mg I 

## sample 

## = fl9 Isample -;- 

## 1000 ppm NH3 

## = mg NH,Isample x 1Nmstd x 1/454000 

## x SVI17 

## x 10·

# 8e//a~**.-~-** 

## DS834059 Date of last revision 12/5/2008 

## Master Document StoragelFormslDatasheetslLab Forms

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project# : _______ Distr ict Method : SCAQMD 207
. 1 Sample Date : 

# .:? 

# /lzJ/3 Client/Location : 

# Seat" 1\ 

# e. ( Calibration Date :

# 2.1/3//'~ Analysis Date : 

# 2/13 /13 Sample Location :

# U()/t~1 Calibration Curve : _________ Analyst's Initials : 

# R:lTest # ' s : 

# IDo 

# /0 R2:



# ------ Sample Electrode TV C on e. 

## Cavg**g** 

## NH 3 1 Comments l Temp/pH Potential (ml )**~g** 

## NH 3 -**~g** 

## NH 3 sample

(mV) N 

## I ml - N 

## I m l - ) Standard Check : Percent Recovery : 28**~g** 

## NH ,I ml

# /I.~ Z S .11 / Repeat 28 

# Ji.1 2S . 5Qt; 

# 2s.N.?

Notes : Tota l volume of samples and standards used : 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculations : Conc
.**(~g** 

## NH 3- N I 

## ml) 

## = 10 (P ·B )IM 

## P 

# =electrode potential , B 

# = y- i ntercept and M 

# =slope Cavg = 

## average result of duplicate ana lyses**(~g** 

## NH 3 - N 

## I ml) = 

## ( Cl+C2)/ 2**~g** 

## NH3 1 sample 

## = Cavg* 

## 17
. 03/14
. 01 * TV mg I 

## sample 

## =**~g** 

## I sample .,. 1000 ppm NH3 

## = mg NH ,I sample x lNmstd x 

## 1/454000 x 

## SV /17 x 10 · 

# Del/a !'1

.......... 

# - . - ..... Date of last re v ision 

## 12/ 5

/ 2008 DS834059 Master Document Sto rage l Forms l Datasheets l Lab Forms

### AMMONIA ELECTRODE CALIBRATION CURVE Sample Room 

### NH3 concentration log NH3 concentration 

### Electrode potential 

### Temperature Temperature**(~g** 

### NH 3 1 ml as N) (mV) (C) (C) 1 0
. 000 90.8 23.2 23.2 5 0
. 699 53.1 23.2 23.2 20 1
. 301 18.6 23.2 23.2 100 2.000 -22.2 23.2 23.2 Ammonia Electrode Cal i bration Curve y = 

### -56 .5667x + 

### 91 . 6417 

### 2113/2013 R' = 

### 0.9996 

## 100.0 

## S- 80.0 

# .s n; 

## 60.0 :;:; 

# " $ 

## 40.0 0 II. 

# " 20
. 0 ." 0 

# - 0.0**~** <) 

# " iii 

## -20.B

- 00 0.500 1.000 1.500 000 2. 00 -40.0 logarithm of the concentration of ammonia (I'g NH31 ml as N) slope y-intercept 

### Concentration (I'g NH31 ml as N) 1 5 20 100 Calculation: -56.5667 91.6417 Value LR line 1
. 0349 4
. 8012 19.5546 102.9250 Regression Line :**P=M'log(~g** 

### of NH,t ml as N)+B Difference 

### 0.0349 -0.1988 -0.4454 2.9250

Measured Concentration of Ammonia (C) in**~g** 

### 1 ml NH3 as N: C=10 (p· B)l M where P = electrode potential, M= slope (must be - 57±3) and B= intercept 

### % Difference 3.4857

- 3.9760 -2.2270 2.9250

All standards were prepared in 0
. 04N H 2 

### S0 4 

### and allowed to equilibrate to room temperature
.AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS CALCULATION C li enV Location: Sample Location: District Method: Sample Date: Analysis Date: Analyst's Initials: Ca li bration Curve: 

## R' Sample Sentinel Unit4 75% SCAQMD 207.1 2/12/2013 2/13/2013 

## RF y= -56.5667 x+ 91.6417 0.9996 

### P Conc. mV**~g** NH3/ml as N 28 ug NH3 / ml as N 10.3 reDeat 28 UQ NH3/ml as N 10.4
l-NH3 -75-1 86.0 repeat 1- NH3 -75-1 86.1 2-NH3 -75-1 89.3 repeat 2- NH3 -75-1 89.2

spike 2-NH3 75-1 17.9

repeat spike 18.0 28 NH3/ml as N 10.4 repeat 

### 28 UQ NH3/ml as N 10
. 6 Reagent Blank 145.6 repeat Reagent Blank 145
.0 Field Blank 125.8 repeat Field Blank 126
. 1

DI H20 Blank 147.5 Repeat 01 H20 Blank 146.9 28 NH3/ml as N 11.8 repeat 

### 28 uq NH3/ml as N 11.7 Notes: Measured Concentration of Ammon ia (C) in )19 NH31 ml as N C= 1 O{P-B)IM 

### P 

## = electrode potential (mV), M=slope and B=intercept 27.414 27.303 1.258 1
. 253 1.100 1.104 20.120 20.038 27.303 27.082 0.111 0.114 0.249 0
. 246 0.103 0.105 25.791 25
. 896

Average Measured Ammonia Concentrat ion (Cavg) = (Cl + C2)/2 where C1, C2 results from duplicate analyses (l1g NH3/m l as N) Cavg ("9 NH,Jml as NH3) = Cavg**(~g** NH31 ml as N) '17.03/14
. 01 I1g NH3/ sample = Cavg (l1g NH:yml as NH 3 ) ... TV Used 100 ml of samples and standards with 2 mllSA and constant stirring rate. All solutions turned blue and remained blue with ISA unless otherwise indicated. Sample PH and Temperatures can be found on the laboratory datasheet. CavgasN
27.359

1.256 1.102 20.079 27.192 0.1126 0.2475 0.1042 25.843

Maximum samples (including blanks) between 28 ug/ml check standard is 5 samples analyzed in duplicate. TV C 

### avg as NH3**~g** NH31 (m l ) sample NA 33.256 NA

610 1.526 931.021 580 1.340 777.118 NA 24.407 NA NA 33
. 054 NA NA 0.137 NA 405 0
. 301 121.823 NA 0.127 NA NA 31.414 NA

### AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS QUALITY CONTROL Client! Location : Sample Location: District Method : Sample Date: Analysis Date: Analyst ' s Initials:
Sample 28 ug NH3 1 ml as N repeat 28 ug NH3/ml as N 1-NH3 -75-1 repeat 1- NH3 -75-1 2-NH3 -75-1 repeat 2- NH3 -75-1

spike 2-NH3 75-1 repeat spike 28 NH3/ml as N repeat 28 ug NH3/ml as N Reagent Blank repeat Reagent Blank Field Blank repeat Field Blank DI H 2 

## 0 Blank Repeat DI H 2 

### 0 Blank

28 NH3/ml as N repeat 28 ug NH3/ml as N Notes: Sentinel Unit 4 75% SCAQMD 207.1 2/12/2013 2/13/2013 RF

% recovery NA

NA NA 98.79

NA NA NA NA NA
spike: 100 ml sample 

## + 2 ml (1000 }1g NH3 1 ml as N) Matrix Spike Percent Recovery (%R) %R 

## = ( C spike*0.1 04 - Csample*0.1 02)/2 *100 Cspike = 

### average result of matrix spike (}1g NH31 ml as N) RPD % 0.41

0.41 -0.41 0.41 0.81 -2.44 1.22 -2.44 -0.41 RPA % -2.290

NA NA NA -2
. 885

NA NA NA -7.703

Relative Percent Difference (RPD) = 

### (C1-C2)1 Cavg *100 (must be 5% or less) Relative Percent Accuracy (RPA) (must be 10% or less) RPA 

## = (Cavg-theoretical value of standard)1 theoretical value of standard * 100

# Oel/aJi
AIr a....lity s.Mc.I. In«IrpGI'II!o1j 

## AMMON IA BY ION SELECT I VE ELECTRODE ANALYSIS Project #:
_______ District Method: SCAQMD 207.1 Sample Date : 

# 2/;2./13 ClientlLocation: 

# Sf-oil oe. ( Calibration Date:

# ~ 

# I!.Vi 3 Analysis Date: 

# Z./l3/<3 Sample Location: 

# ul)a: (I Calibration Curve:y--.st::.6U7 

## X'+9/. 

## t 111 Analyst's Initials: 

# R 

# r**~50~** 2" Co 

## Test#·s : ___**.:...=7,..!../.::.e~**

### __ 

## R: • 

## 779£ Sample Electrode TV Cone. Cavg fig NH31 Commentsl 

## Temp/pH Potential (ml) fig NH 3 - (fig NH3 sample

(mV) N Iml 

## - N I 

## ml-) Standard Check: Percent Recovery: 28**~g** 

## NHsfml 

# /0·3 27.'fN Repeat 28 

# ID.L.{ 

# 2";1.303 

# 71· 355-



# 1- 

# .NI/,

- 7':, - 

# I 

# g·o I· 26f

# ~cci I

# N~ 75; - \**~&'I** 

# (plo J.153 

# I. Zsc. <131. () 

# pH < 2-

## T~23**·1.. (**  

# 2,·111/,

- 

# tS-

- I**~·3** 

# /. Jot>**1.Q~ct** 

# zN'4-t5-1**~ft,2.** 

# Sfo 

# J. /61.( 

# I.J at pl./ <:. 1.. 

# T=" 2n .. ( flp,'t(1!.. 2... 

# A/II, 7[;

- I 

# li·9 20.llC

# f)~""A-**~IKI!..** 

# Jf·o 2

# o ·o3J- 2e>· 0"19 ieCCNeN 

# =-77 ' 

# 2fAlI'/. 

# lo.y 

# n. 3(;>.1

# ~ 

# API'j' 2 f 

# J/I/, JO.(; 

# 27.oh. 2f./9l

I?G 

# ''.'If. 

# pJ()vo.1( Il.Is.(. D. 

# I \ I 

# IA I { soLl.i 0>1.5

# ~**~d** 

# R/j**I~S.o** 

# 6. 

# II"! C>./IU 

# u..st.c.J 6. 

# tfie.ld P./fMK 

# 125.g t; . 2. 

# '/9 

# 13-2.°(.. 

# O.M,-i: 

# F IJ**J2~.** 

# I 

# O,2.'IC 0,2'11.5 

# lilll**~6** fj{CMK. 

# l'ft. oS 

# D·IO] 

# IN '.,4;?G-f 

# Ii /ho /j

# J 

# K.. 

# 1"I(."e, 0.10S' 

# O./D'/Z. Notes: Total volume of samples and standards used: 100 ml Volume of pH adjusting ISA used in ml: 2 ml Absorbing solution: 0.1 N H2S04 Calculations : Conc. (fig NH3 - N 

## I ml) 

## = 10 (p·81IM 

## P 

# = electrode potential
. B 

# = y-intercept and M 

# =slope Cavg 

# =average result of duplicate analyses (fig NH3 - N 

## I ml) 

# =(C1 

## +C2)/2 fig NH31 sample 

## = Cavg* 

## 17.03/14.01 * TV mg 

## I sample 

## = fig Isample .,. 1000 ppm NH3 

## = mg NHslsample x 1Nmstd x 

## 1/454000 x 

## SV/17 x 10 6 

# Oe/lal'1

---- DS834059 Date of last revision 

## 12/5/2008 Master Document StoragelFormslDatasheetslLab Forms**~** 

# °

## AMMONIA BY I ON SELECTIVE ELECTRODE ANALYSIS Project # : _______ D i strict Method : SCAQMD 207
. 1 Sample Date : 

# 2. /12./13 ClienVLocation : 

# Seat,' 1\ 

# e. 

# t Calibration Date : 

# 2. 

# 1;3/13 Analysis Date : .2 

# /13 /13 Sample Location : 

# Un/I: 'I Calibrat ion Curve : _________ ,Analyst's Initials : 

# Rr '"::1r 010 ' 

## Test # 's: I:::' 

## t.:. R :



# ------ Sample Electrode 

## TV Co ne . 

## Cavg flg 

## NH3 1 Commentsl 

## Temp/pH Potential ( ml) flg NH 3 - (fl9 NH3 sample

( mV) N Iml 

## - N I 

## ml) Standard Check : Percent Recovery : 28**~g** 

## NH ,t ml

## I/.~ 25· 7"1/ Repeat 28 

# //.1 21>. 

# H', 25. 

# f't?

Notes : Total volume of samp l es and standards used : 100 ml Vo l ume of pH adjusting ISA used in ml : 2 m l Absorbing solution : 0
. 1 N H2S04 Ca l cu lat ion s : Conc. (fl9 NH 3 - N I 

## ml ) 

## = 10 (p·S)IM 

## P 

# = electrode potential , B 

# = y-intercept and M 

# =slope Cavg = 

## average result of duplicate ana ly ses (fl9 NH3 - N 

## I ml ) = 

## (C1+C2)/2 fl9 

## NH3 1 sample 

## = Cavg* 

## 17.03/14
. 01 * TV mg 

## I sample 

## = flg Isample .. 1000 ppm NH3 

## = mg NH,tsample x 1Nmstd x 

## 1/454000 x 

## SV /17 x 10 6 

# Del/atl

---- DS834059 Date of last re vi sion 

## 12/5 / 2008 Master Document StoragelFormslDatasheets l Lab Forms

### AMMONIA ELECTRODE CA LIBRATION CUR V E Sample Room 

### NH 3 

### con centration log NH , c o n c entral i on Electrode potential 

### Temperature Temperat u re**(~ g**  

### NH , I m l as N ) ( mV) ( C) ( C) 1 0.000 90
. 8 23
. 2 23. 2 5 0
.699 53
. 1 23
.2 23.2 20 1.301 18
. 6 23
. 2 23
. 2 100 2.000 - 22
. 2 23
. 2 23
. 2 Ammonia Electrode Calibrat i on Curve y = -5 6
.566 7 x + 

### 91
.6417 

### 2/13 / 2013 R' = 0
.9996 

## 100
. 0 

# > 80
. 0 .§. 

## l! 60
. 0 1: $ 0 

## 40
. 0 Il. 

# ., 20
. 0 "C 0**~** 

## 0
. 0 U 

## 1.500

# ~OO 

# ., iii 

## -20
. &( 00 0.500 1
. 000 -40
. 0 logarithm of the concentration of ammonia (I'g NH,' ml as N) slope y-inlerc epl Can centr al io n ( I' g NH , I m l a s N ) 1 5 20 100 Calculation: -5 6
. 5667 91
.6417
V alue LR line 1.0349 4.8012 19
. 5546 102.9250 Regression Line :**P=M'log ~g**  

### of NH ,I ml as N)+B 

### D i ffe r e nce 0
.0349 -0
. 1988 -0.4454 2
. 9250

Measured Concentration of Ammonia (C) in**g** 

### 1 ml NH , as N : C =10 I P- B l IM where P = el ectrode potential , M= slope ( musl be -57± 3) and B= i nlercept 

### % Difference 3.4 8 57 -3.9760 -2.2270 2.9250

A l l stand a rd s w ere prepared in 0
.04N H 2 

### S O , and all owed 10 equil i b rate 10 room temperature. 

## 2
. 00AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS CALCULATION Cl ienV Locat ion : Sample Location : Distr ict Method : Sample Date : Analysis Date : Analyst's Initials : Ca li brat ion Curve : 

## R' Sample Sentine l Unit4 50 % SCAQMD 207
. 1 2 / 12/2013 2/13/2013 

## RF y= -56.5667x+ 91.6417 0.9996 

### Conc. 

### p mV ).19 NH 3/ml as N**~** Measured Concentration of Ammonia (C) in ).1 9 NH3 1 m l as N C=10 (P -8)1M 

### P 

## = electrode potential (mV), M=slope and B= i ntercept Average Measured Ammonia Concentration (Ca v g) 

### = (C1 + C2)12 where C1 , C2 results from duplicate analyses (1-19 NH 3/m l as N) Cavg**(~g** NH ,i ml as NH3) 

### = Cavg**(~g** NH3 1 ml as N)' 17
. 03/14
.01**~g** NH ,I sample = Cavg**(~ g**  NH,iml as NH ,) • TV Used 100 ml of samples and standards with 2 mllSA and constant stirring rate. A ll solutions turned blue and remained blue with ISA unless otherwise indicated . Sample PH and Temperatures can be found on the laboratory datasheet. C avg as N

Maximum samples (including blanks) between 28 ug/ml check standard is 5 samples analyzed in duplicate. 

### TV C avg as**~g** NH,t

### AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS QUALITY CONTROL Client! Location: Sample Location: District Method: Sample Date: Analysis Date: Analyst's Initials:
Sample 28 ug 

### NH31 ml as N repeat 28 ug NH3/ml as N
1-NH3 -50-1 repeat 1- NH3 -50-1 2-NH3 -50-1 repeat 2- NH3 -50-1

spike 2-NH3 50-1 repeat spike 28 NH3/ml as N repeat 28 ug NH3/ml as N Reagent Blank repeat Reagent Blank Field Blank repeat Field Blank 01 H 2 

### 0 Blank Repeat 01 H 2 

### 0 Blank 28 NH3/ml as N repeat 28 ug NH3/ml as N 

### Notes: Sentinel Unit 4 50% SCAQMD 207
. 1 

### 2/12/ 2013 2/13/2013 RF

% recovery NA

NA NA 99.28

NA NA NA NA NA
spike : 100 ml sample 

### + 2 ml (1000 I1g NH3 

## 1 ml as N) Matrix Spike Percent Recovery (%R) % R 

## = (C spike*0.1 04 - Csample*0
. 1

### 02)/2 '100 Cspike 

## = average result of matrix spike (l1g 

### NH 3 1 ml as N) RPD % 0.00

3.26 -4
. 07 -041 041 -244 1.22 -244 -041 RPA % -0484

NA NA NA -2
. 290

NA NA NA -7
. 703

Relative Percent Difference (RPD) 

## = (C1-C2)1 Cavg '100 ( must be 5% or l ess) Relative Percent Accuracy (RPA) (must be 10% or less) RPA 

## = (Cavg-theoretical value of standard)1 theoretical value of standard' 100

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project# : ______ District Method : SCAQMD 207.1 Sample Date : 

# 21 /13 Client/Location : 

# SCD-/.ioe. ( Calibration Date: 

# ;;;:! 

# /13 Analysis Date : 

# Z./13/13 Sample Location: 

# UI);';; 

# J.( Calibration

# Curve:y:~.6U7X~+9/.**~fl1** Analyst's Initials: 

# R7 '-'0**o~,** 2 

## 0 

# 9 Test #'s : .J /(., 

### R : • 

## 7'1'f Sample Standard Check : 28 I1g NH,Iml Repeat 28 

# /- .HI/,

- So - I

# 2.·N~ 

# - So

- 

# I

2 CJI1 ) 

# lieM, J>.. / t:N.1<. Electrode Potential

(mV)



# 11
. f

/O . '{ 

# ILl5., /l{6
. 0 

# 12(,. I TV (ml)



# S'lo Cone.**~g** 

### NH 3 - 

## N 1 ml Cavg**(~g** 

### NH3



## - N 1 

## mil


# 27. sr,</ 

# 21. fC.({ 

## I
. JD'{

## D~7 

# j,of.1 /.ISc 2e:>
. 202.



# 0
. /11 

# o.IN**/I7.~**



# D , 

# /OJ

Notes: Total volume of samples and standards used : 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculat i ons : Conc.

## (~g NH3 - N 1 ml) 

## = 10 (p.B )/M 

### P = electrode potential, B = y-intercept and M = slope**~g** 

### NH31 sample



# pis
. 

# C Commentsl Temp/pH Percent Recovery :



## 23 . 2... 0 

## L

Cavg 

## = average result of duplicate analyses (f!g NH3 - N 

## 1 ml) 

## = (C1 

## +C2)/ 2**~g** 

### NH31 sample 

## = Cavg' 

## 17
. 03/14
. 01 • TV mg 

## 1 sample 

## =**~g** 

### Isample + 

### 1000 ppm NH3 

# =mg NH,Isample x 1Nmstd x 

## 1/454000 x 

## SV/17 x 10 6 

# De/lab.

-- -- - DS834059 Date of last revision 

## 12/5/2008 Master Document StoragelFormslDatasheetslLab Forms

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project # : _______ 

## District Method : SCAQMD 207
. 1 Sample Date : ;( 

# /12./13 ClienULocation : 

# Seot,' 1\ 

# e. ( Calibration Date 

# .2./13/13 Analysis Date : 

# 2/13/13 Sample Location : 

# U()/t J./ Calibration Curve : _________ ,Analyst's Initials : 

# & S ' ,-0/0 

## Test#'s : (//' R' :



# ------- Sample Electrode TV Cone. Cavg fig NH31 Commentsl 

## Temp/pH Potential (ml) fig NH 3 - (fig NH3 sample

(mV) N/ml - N 1 

## ml) Standard Check : Percent Recovery : 28**~g** 

## NH,Iml 

# 11·8- 2S.1'1( Repeat 28 

# 11.l-**2.~. 4'1~** 

## 2S'1'i~

Notes : Total volume of samples and standards used: 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculations : Conc. (fig NH 3 - N 

## 1 ml) 

## = 10 (P - B )IM 

## P 

# =electrode potential , B 

# = y-intercept and M 

# =slope Cavg = 

## average result of duplicate analyses (fig NH3 - N 1 

## ml) = 

## (C1 +C2)/2 

## fig NH31 

## sample 

## = Cavg" 17
. 03/ 14 .0 1 • 

## TV mg 1 

## sample 

## = fig Isample -<- 

## 1000 ppm NH3 

## = mg NH,Isample x 1Nmstd 

## x 1/454000 

## x SV/17 

## x 10 6

# Della~ 

# ..

# __ ........... Date of last revision 12/5/2008 

## DS834059 Master Document StoragelFormslDatasheetslLab Forms

## Appendix C.4 SOx 

## by SCAQMD Method 307 .91

R041 0688 

### C-8

### Max Parameter Units Result 

## Limit Rule Ib/MM8tu 0
. 00002 0
. 06 40 CFR 60 Ib/MMsef 0.025 0.67 Rule 2011 SO , grH2S/100sef 0
. 009 0
. 25 SCAQMD Permit 861.1Sentinel 4 Fuel Analysis and Sulfur Calcs Sulfur Client Facility Unit Gemma CPV Sentinel 4



## - - CPV Sentinel-4 Fuel 1&2 HHV Fuel Sulfur Content, (BTU/ft3 MW MW ppmv @60F) (H2S) (S02) Result < 0.15 1021.4 34.00 64.00 Limit
Reference gr/100 scI = ppmv lue1/10'6 x MW (H2S)/SV x gr/lb x 100 Ib/10'6 scI = ppmv lue1/10'6 x MW (H2S)/SV x 10'6 Ib-S02/MMBtu = ppm lue1/10'6 x MW (S02)/SV/HHV x 10'6 (Specific Molar Volume@

60F) 379.5 grllb 7,000 gr-H2S/100 scI 0.009 0.25 SCAQMD

Permit, B61.1 IbsH2S/MMscl

0.013 0.690
Rule 2011 IbS02/MMBtu

0.00002

0.06
40 CFR 60

3/1/20t3 10 : 56 AM

### Client Facility Unit

Load , MW

106.5 Gemma CPV Sentinel 

### 4

Fuel Sulfur Content, ppm 

# <1 0

. 15 Sentinel 4 Fuel Analysis and Sulfur Cales SOx

CPV Sent i nel-4-Fuel-1 &2 Specific

Molar Volume Stack

(SV), Flow Rate Fuel Flow dscf/lb- (Qsd19) , Rate ,

mol dscfm hscfih 02 Ib/hr, S02 379
. 5 350,311 8845 12.99 0
. 02237 S02 Ib/hr = 

### (sulfur ppmv)/1 0'6 x (MW S02)/SV x hscf/hr x 100 scf/hscf ppm S02 = 

### Ib/hr x SV/MW x 1/Qsd19 

### x 10'6/60 

### Stack flow rate , fuel flow and 02 in conjuction with PM tests at 100% load condition ppmv@ ppmv 15% 02 0.006 0.005 S02,Ib/MMscfFuel 0
. 025

3/1/2013 

### 1056 AM

### Client 

## Facility

Unit



## Carbons

1 2 2 3 3 4 4 4 4 4 4 4 5 5 6 Gemma CPV Sentinel 

## 4


## Compound Hydrogen Carbon Dioxide Carbon Monoxide Nitrogen Oxvqen Methane Ethylene Ethane Propane Propylene Isobutane n-Butane 1-Butene Isobutylene t-2-Butene c-2-Butene 1,3-Butadiene Isopentane n-Pentane HexanesPlus Compound Total Reduced Sulfur FUEL F-FACTOR CALCULATIONS

CPV Sentinel-4-Fuel-1&2 

## 1 2 Average detect? 

# I MOLE % detect? 

# I MOLE % detect? 

# I MOLE % < 

## 0.001 < 

## 0.001 < 

## 0.001 0.469 0.452 0.461 < 

## 0.001 < 

## 0.001 < 

## 0.001 2.634 2.774 2.704 0.038 0.048 0.043 92.299 92.073 92.186 < 

## 0.001 < 

## 0.001 < 

## 0.001 3.904 3
. 957 3.931 0.513 0.531 0.522 < 

## 0.001 < 

## 0.001 < 

## 0.001 0.032 0.038 0.035 0
. 069 0.084 0.077 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 < 

## 0.001 0.016 0.013 0
.015 0.014 0.015 0.015 0.011 0.014 0.013 detect? ppm detect? ppm detect? ppm < 

## 0.1 < 

## 0.2 < 

## 0.15

## FUEL F-FACTOR CALCULATIONS Client Gemma Unit 

## 4 Facility CPV Sentinel CPV Sentinel-4-Fuel-1&2 SPECIES MW 

## MOLE 

## % MW*% HHV BTU/SCF 

## C H 

## 0 CO 2 

## 44 0.461 20.27 0.06 0.00 0.15 CO 

## 28 0.001 0.03 321.0 0.003 0.00 0.00 0.00 N2 

## 28 2.704 75.75 0.00 0.00 0.00 O 2 

## 32 0.043 1.38 0.00 0.00 0.01 C , 

## 16 92.186 1478.9 1012.0 932.92 11.06 3.69 0.00 C 2 

## 30 3.932 118.22 1773.0 69
. 71 0
. 94 0.24 0.00 C 3 

## 44 0.523 23.06 2524.0 13.20 0.19 0.04 0.00 C. 

## 58 0.117 6.76 32710 3.81 0.06 0.01 0.00 C 

## s 

## 72 0.029 2
. 09 3998.0 1.16 0.02 000 0.00 C 6 + 

## 86 0.013 1.08 4743.0 0.59 0.01 000 0.00 Ave. / Total 100.01 1630.12 1021.39 12.28 3.98 0.00 Weight, % 

## 99.74 75.31 24.43 0.00

GasMW 16.30 Btu/sef= 1021 @60F Btu/sef= 1037 @68F Btu/lb.= 23,779 Ib.lsef= 0.0430 Fd"(60)= 8,455 

## (0 2 

## Based) Fd"(68)= 8,585 Fe"(60)= 1,001 CO 2 

## Based) Fe"(68)= 1,017
Calculations: 

## Fd"(68) = 10A 6 * [3.64 * (H%) + 

## 1.53 * (C%) + 

## 0.14 * (N%) - 

## 0.46 * (0%)]1 HHV, 

## Btu/lb Fd"(60) = Fd"(68) * 

## 520 R 1 528 R Fe"(68) = 1OA6 

## * [0.321 

## * (C%)] 

## 1 HHV, 

## Btu/lb Fe"(60) = Fe"(68) * 

## 520 R 1528 

## R N 

## 0.00 000 0
. 76 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 000

## Sentinel 4 Fuel Analysis and Sulfur Cales F-Summary Client Facility Unit 

## Gemma CPV 

## Sentinel 4 CPV Sentinel-4-Fuel-1&2 GasMW 16.30 Btu/scf= 1,021 Btu/scf= 1,037 Btullb.= 23 , 779 Ib.lscf= 0.04295 Fd"(60)= 8,455 Fd"(68)= 8 , 585 Fc"(60)= 1 ,001 Fc"(68)= 1 ,017



## 3/112013 10:56AM· t 

## Parameter Fixed Gases HHV Sulfur Method No. ASTM 01945/1946 ASTM 03588 ASTM D5504/ SCAQMD METHOD 307-91 Method Title Analysis of Natural Gas/Reformed Gas by Gas Chromatography Calculating Heat Value, Compressibility Factor , and Relative Density of Gaseous Fuels Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence / Determination of Sulfur In A Gaseous Malrix

## Appendix 

## C.5 ROG by Modified SCAQMD Method 

## 25 . 3

R041 0688 

## C-g

### Client/Location Gemma CPV Sentinel Unit 

## 4 Sample Location Stack Test No. S-4/STK - ROG - 100 - 1A Date 2 1 11 / 2013 

### Test Method Modified SCAQMD 25
. 3 Sample Time (HH:MM) 1 :17 Start Time 10 :06 

### Stop Time 11 :23 Stack O 2 

### (%) 13.29 Results Canister NMNEOC (ppm) 0.85 

### ROG, ppm' 0.85 

### ROG, ppm @ 15% O 2 

### 0.66 

### RPD 2 , 

### % 

# - 1) Includes bias correction of 1.086 2) Relative percent difference less than 20% 3) Samples were collected simultaneously as a pair Results reported at PQL Reference Temp (F) 

## 60 Data By AA , SS , RM , JM

S-4/STK-ROG-100 - 1 B Average 2/ 11 / 2013 

### Modified SCAQMD 25
. 3 1 : 17 10 :06 

### 11 : 23 13.29
0
.65 0
. 65 0
. 75 0.50 0.58



# - 13
. 3 %

## Client/Location Gemma CPV Sentinel Unit 4 Sample Location Stack Test No. S-4/STK-ROG-75-1A Date 2111/2013 

## Test Method Modified SCAQMD 25.3 Sample Time (HH:MM) 1 :20 Start Time 15 :45 Stop Time 17 : 05 Stack O 2 

## (%) 13
. 81 Results Canister NMNEOC (ppm) 0
. 65 ROG, ppm' 0
. 65 ROG, ppm@15%0 2 

## 0
. 54 RPD 2 , 

## % 

# - 1) Includes bias correction of 1,086 2) Relative percent difference less than 20% 3) Samples were collected simultaneously as a pair Results reported at PQL Reference Temp (F) 60 Data By AA , SP , SS , JM

S-4/STK-ROG-75-1 B Average 2/11 / 2013 

## Modified SCAQMD 25
. 3 1:20 15 :45 17 : 05 13
. 81
0
. 70 0
. 70 0
. 68 0
. 58 0
. 56



# - 3
. 7%

## ClientiLocation Gemma GPV Sentinel Unit 4 Sample Location Stack Test No , S-4/STK-ROG-50-1A Date 2112/2013 Test Method Modified SGAOMD 25
. 3 Sample Time (HH:MM) 1:22 Start Time 11 : 58 Stop Time 13 :20 Stack O2 

## (%) 14.27 Results Canister NMNEOC (ppm) 0
. 6 9 ROG, ppm' 0
. 69 ROG, ppm@15%0 2 

## 0
.61 RPD 2 , 

## % 

# - 1) Includes bias correction of 1.086 2) Relative percent difference less than 20% 3) Samples were collected simultaneously as a pair Results reported at PQL Reference Temp (F) 60 Data By AA , MG , RM , JM

S-4/STK-ROG-50-1 B Average 2

/ 12/ 2013 Modified SGAOMD 25
. 3 1 :22 11 :58 13:20 14.27
0
. 55 0
. 55 0
. 62 0.49 0
. 55

- 

## 11
. 3%

## SCAQMD METHOD 25.3 EVACUATED CANISTER SAMPLING DATA ClientlFacility :LlErt\iY!!\- 

# /5c Nf/." A '- Oate:
__

# ;)**' .l.** **13 ",--**  

# ______ _ UnitlLocation: 

## If»!"! 

# 4-(**S~f\lTiNA'-** Performed By :__ 

# '<

_fI'\ -'--
_____ _ S <' : ;;.. . 

## I 

## Probe Material
_____ ::> _____ 

## Probe Length
__ -" ,. J

"--
_____ _ 

## Connecting Tubing Material-,-:..: f1 

### ..L

/.",A
___ 

## Connecting Tubing Length",:, f1 .!....!....« g "---
__ _ 

## /f 

# cUt.- 1 

# &5° Barometric Pressure
__ u ----' "

_ I
____ 

## .Ambient Temperature
______ _ Test No
. 

# I " - L{ 

# Ln I< - V6(.

## -I~- 

## S - '1lsr¥---IC!c - 

## tJo-I 

# t Vial 10 f'll<- 

### {lfiQ. 

## Canister 10 000 '-Di 

### (JOO 0 

## LD**~** 

## Time Vacuum Time Vacuum**~ime** 

## Vacuum Pre-Test Leak Start

## :;t.~**~** 

# 2(1 " Check**O~w** 

## .;, '620 I Pre-Test Leak Stop ,\ 

# 1."\' 

# \ Check 

# (/'5, :00 

# 'd-CI. 

# DC030 Sample Start 

# , ' 

## Z - // 

# \ Collection k. 

# l ' ,) (0 

# '2'; /0.**~** 

## ? 

## .5 1 0 

## 2..<0 

# 2 !r /D.2Cc,

# .f 

# \ L(/ 

# pscJ 

# 41 Izl So I I 

# Ie; \ /(IZ 

# /'0 jJ /;Z 

# Ie;' I 

## Il

)

- 

## j
.. - F' 0 

# t' 

# 112;> 

# /& /(2-) 

# lu \ 

# \



# \ Sample Stop 

# II**;.?~** 

# 16 112'3 /Q 

# \ Collection Post -Test Leak Start 

## / /)U 

# i Check 

# 16 II) v /{.J 

## Post-Test Leak Stop 

# il L /v' 

# I (, 

# 1 1 (/ 

# J /U 

# \ Check 

# \ Line Rinse 

# / / /**~** 

# \ Volume Comments : ________________________ _

Date of last revision 

### 11/13/08 

## 05834043 Master Document StoragelFormslDatasheetslField Datasheets

## SCAQMD METHOD 25.3 EVACUATED CANISTER SAMPLING DATA 

## Client/Facility: 

# G€( v Iva 

# it5i. l-t- :""A. ...{ Date: 

# .2 

# 11/ / I 

# 3

, ; I 

### r 

## 4,1 If(' /f? , ..,- ' / 

## c 3 :? ,; 

## UnitlLocation : J

-

## :-r. 

# \

- 0.(jf..r - /

## ~- 

## k' Performed

## By**,co /-** **o:...c.. /'** **-,- 7j** **-f7 ,--**  _ __ __ _

## ~**~ ~**  // 

## Probe Material .: - Probe Length
-- :,L..{:. ,<.......! , "- ' ------ 

# --- 

# -- Connecting Tubing Material, .,-_____ Connecting Tubing Length
_____ _ Barometric pressure._-= l

_



# Cr ...:.

. _

(

_

L , (
____ .Ambient Temperature 

# .5 c/' Test No, LL ?I 

# 1.;""7 

# ," -=t 

# IS/ ViaiiD J ..-/ 

## (VIY- 

# I... 

# [Vl f Canister ID / 

## \,**f/~-Ku& -/~**  

## <::<;I51>(

## ./GL - 

## -lS

- 1 5 Time Vacuum Time Vacuum ime Vacuum Pre-Test Leak Start 

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# V .../" Volume Comments : _____________________ _

Date of last revision 

## 11 /13 / 08 DS834043 Master Document Storagel Forms l Datasheets l Field Datasheets

## SCAQMD METHOD 25.3 EVACUATED CANISTER SAMPLING DATA Client/Facility :

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... O::::"SoM. ... ... ........ .... 

### Date of l ast revision 11 /13/08 DS834043 Master Document Storage l Form sl Datasheets l Field Datasheets

# Atmospheric Analysis & 

# Consulting, Inc.

CLIENT PROJECT NAME AAC PROJECT NO. REPORT DATE Delta Air Quality Services , Inc. Gemma, Sentinel 4 130160 2115 /2013 On February 13, 2013, Atmospheric Analysis & 

## Consulting, Inc . received six (6) Six-Liter Summa Canisters for TNMNEOC analysis by SCAQMD 25.3 Modified and Fixed Ga ses analysis by EPA 3C. Upon receipt the samples were assigned unique Laboratory ID numbers as follows: Client ID Lab No. Initial 

## Pressure (mmHg) S4/ Stk-VOC-IOO-IA 130160-60984 345.7 S4/Stk-VOC-IOO-IB 130160-60985 459.8 S4/ Stk- VOC-75-1 A 130160-60986 460.2 S4/ Stk-VOC-75-IB 130160-60987 437.2 S4/Stk-VOC-50-IA 130160-60988 437.3 S4/Stk-VOC-50-IB 130160-60989 543.5 Upon receipt at the laboratory , the initial vacuum was recorded and the canister was pressurized to 900 mmHg using dry UHP Helium. The PQL for this modified method was established at 0.10 pp· mV (as Propane) as dictated by the lowest point in the calibration curve. All results were detected below this level and therefore reported as <PQL. One Entech Flow Controller Gauge was damaged upon return. Canisters #000403 and #000411 were not returned with this batch. [ certify that this data is technically accurate, complete and in compliance with the terms and conditions of the contract. Release of the data contained in this hardcopy data package ha s been authorized by the Laboratory Director or his designee , as verified by the following signature. If you have any questions or require an explanation of your data results , please contact the undersigned. 

# -ffL**~**

Marcus Hueppe Laboratory Director
This report consists of 

# 41 pages .



# Page 1

1534 Eastman Ave ., ste
. A • Ventura , • CA 93003 

# @ www .aaclab.com. (80S) 650· 1 642 • FAX (805 ) 650 - 1 644

# ® h CC Atmospheric Analysis & 

### Consulting, Inc. 

# SAMPLE RECEIPT / LOG-IN REPORT 

# AAe Proiect 

## 130160 Received By: 

## J . Zachman Sample Pro 

## i eet Desc Clients 10 

### Matrix Sampling Samnled By 

### Sample # 

### Receipt Date Daterrime 

### 2/ 13/ 2013 

### Delta Air Quality S4 /Stk-VOC-IOO Summa 

### 2111 / 2013 

### Client 60984 1330 -IA 

## Canister Gemma , Sentinel 4 2113/ 2013 

### Delta Air Quality S4/Stk-VOC-IOO 

### Summa 2/ 11 / 2013 

### Client 60985 1330 -18 Cani s ter Gemma, Sentinel 4 

### 2113/ 2013 

### Delta Air Quality S4 /Stk-VOC-75- Summa 

### 2111 / 2013 

### Client 60986 1330 IA 

### Canister Gemma, Sentinel 4 2/13/ 2013 

### Delta Air Quality S4/Stk-VOC-75- 

## Summa 2 1 11 / 2013 

### Client 60987 1330 IE 

### Canister Gemma, Sentinel 4 211312013 Delta Air Quality S4/Stk-VOC-50- 

## Summa 2112/ 2013 

### Client 60988 1330 IA 

## Canister Gemma, Sentinel 4 2/ 13/ 2013 

### Delta Air Quality S4 / Stk- 

### VOC-50- 

## Summa 2/ 1212013 Client 60989 1330 18 Canister 

### Gemma, Sentinel 4

TURN AROUND TIME : Nonnal (lOdays) Lab Due Date: 2 / 20

/ 2013 

### Total Sample s : REMARKS: Client returned 6 x Summa canisters 

## + 6 x Flows. One Entech Flow Controller Gauge was damaged upon return. "Note: Canister #000403 and # 000411 were voided tests. Please do not analyze." Canisters #000403 and #000411 were not returned with this batch. Analysis

. Requested 

### SCAQMD 25.3M
SCAQMD 25.3M
SCAQMD 25.3M
SCAQMD 25.3M
SCAQMD 25.3M
SCAQMD 253M

6



# Page 2

### Client: Date : Delta Air Quality 

### 2/13/2013
Canister 

## # 201 020 129 151 041 107 

# Atmospheric Analysis & 

# Consulting, Inc.

CANISTER PRESSURE LOG Project No .: 

## 130160

Sample 

## # Initial Pressure Final Pressure



## 60984 345.7 906.1 60985 459.8 913.6 60986 460.2 912.4 60987 437 .2 940.6 60988 437.3 919 . 8 60989 543.5 909 . 7

1


# Page 3

# /f//c# 1 30 / raO

CHAIN OF CUSTODY 

### -.:t C LIENT : Ser" url!:: 1 TEST DATE (S): 21 11 1 2013 21 1 212013 (l) 

### 00 • SAMPLER (S) : RM OJ 

### p.. LO CATI O N : SAMPLE LOCATION : u\ PROJECT MANAGER:

### ~ BF TEST METHOD (S): f' ......... A ......**,.. ~**  ... ' ",I"\\ •• [lvn." 

### ' '''' .-> DATE DUE : 21 2 0 1

20 13 OUTSIDE LAB REQUIRED? : Y- - ____________________________ COMPLIANCE TEST? Yes 

## '4- l DATE ; ()q 

## f? ----- ---- 

# _ I**_fiM~**

### _ _



# L _

_ _ TEST#**~** 

### 6 9?!;. - 

### 1>01 8 <1:, 

### ; 0<1 87 \ 

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### #OC : anister; : aniste r i :an l ster: ; an i ster: "z..{ 

## 1""'1**~**

6
RElEASED BY DATEmME --- -- - FRECEf VErfS'Y - - --- 

## f DATEfTIME 

# 3£iJV**/l'~** 

### 2. ( 13ft3. 

## t o: d '"
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## / 33", 

# IY
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### ~ Note : Can iste r #000403 and #000411 were voided tests . Please do not analyze .

# A

# Results

Page 5

# Atmospheric Analysis & 

# Consu l ting, Inc.
LABORATORY ANALYSIS REPORT CLIENT PROJE CT NO. MATRIX UNITS



### Client ID S4/Stk-VOC-IOO-IA S4lS tk

- VOC-lOO-1 B S4/Stk-VOC-75

- IA S4lStk- VOC-75-1 B S4IStk-VOC-50-IA S4/Stk-VOC

- 50-IB 

### Delta Air Quality Services,lnc. 130160 

### Air : ppmC



### T ank Vol Liters Lab ID # 

### (VT "k) 130160-60984 6 . 00 130160-60985 6 . 00 130160-60986 6 . 00 130160-60987 6 .0 0 130160-60988 6 . 00 130160-60989 6. 00 

# SCAQMD 25.3 

# Modified Initial 

### Return Final 

### Pressure Pressure Pressure mmHg(P;) mmHg (P,) mmHg (Pr) 0 . 0 3 45 .7 9 06 . 1 0 . 0 4 59 . 8 9 13 . 6 0 . 0 46 0 . 2 9 12.4 0. 0 437 . 2 940 .6 0 . 0 43 7 .3 9 19 . 8 0.0 54 3 . 5 909 .7 

## * T NMN E O C Includes Bias C orrection=1.086, as per method PQL = 

### 0.10 ppmV Propane x 3.0 (carbon conversion) x T ank Dilution Factor x 1.086 (correction factor) 

# EPA3C

- -- 

### PQL: 0.1 % 

### Analvte Client ID Lab ID # 

### Oxyeen CO S4/Stk- VOC-I OO-IA 130160-60984 12 . 8 <PQ L S4 lS tk-VOC-100-1 B 130160-60985 13 .0 <PQL S4/Stk

- VOC

-75-IA 130160-60986 1 3 .6 <PQL S 4/Stk-VOC-75-IB 130160-60987 13.6 <PQL S4IS tk-VOC

- 50-IA 130160-60988 14 . 1 <PQ L S4/Stk- VOC-50-1 B 130160-60989 14 . 1 <PQ L 

### F

ixed Gases have been nor m

a lized t o 1000 /0 on a dry 

### weight bas is 

### Sample Vol. (L) (VS.mpl
. ) 2. 73 3 . 6 3 3. 63 3.45 3 .45 4 .29



### CO2

6 . 0 5 . 9 5. 4 5 .5 5 . 2 5.1 

### Tank Dil 

### Factor (DFT.,k)

2. 62 1. 99 1.98 2 . 15 2 . 10 1. 67 SAMP L ING DAT E : 2111 , 1212013 R ECEIVING DATE : 02 11 312013 ANALYSIS DATE : 0211412013 R E PORT DATE : 02/ 1512013



### Total PQL NMNEO C * <PQ L 0 . 8 5 <PQL 0 . 6 5 <PQL 0 .65 <PQL 0.70 <PQ L 0.69 <PQ L 0.55

# ~L~ -

. 

# , Marc u s Hu eppe Laboratory Director 

## Page 6 1 5 3 4 Eastm an Ave., Ste. A • Ve nt u r a, • CA 9 3 003 

# * (8 0 5 ) 65 0 -1642 • FA X (8 05) 650- 1 644 • www.aaclab .com

# Method 25.3 Modified Calculation Summary Sheet TNMNEOC - CTCA 

# x DFTank X 

# 3 . 0 

# x 1.086 Where: TNMNEOC = Gaseous concentration of Source, ppmV (as Carbon) CTC A = Average of analysis results from chromatograms, ppmv (as Propane) DF Tank 

## = Dilution factor resulting from tank pressurization upon receipt (PdPr) 3.0 = Conversion of result (as Propane) to (as Carbon) Per method section 4.11, the final concentration includes a 1.086 bias correction factor. 

## Where: Pf = Final canister pressure after pressurization for analysis !fr om Sample Receiving Data Sheet) 

## Pr = Return canister pressure upon sample receipt (from Sample Receiving Data Sheet)



## Page 7

# QA/QC Summary

Page 8

# Atmospheric Analysis & 

# Consulting, Inc.

Quality ControVQuality Assurance Report Date Analyzed : 0211412013 

### Analyst : ZG 

### Units : % 

### J

- ODenin.e: Continu1n1! C alibration Verification· SeA MD25.125.3 

### AACID Analyle 

## 0, 

# N, Spike Cone 5.18 14 .4 

# cev Result 5 .15 15.70 

### % 

## Rec :- · 99.3 109.0 

## 0, MB 

### Concentration 

# II ND ND 

### fiI-Laboratory Control Spike & 

### Du 

### liute

- SCAQMD 25.1,25.3 

### AACID Analyle 

## N, CO, Sample Cone 0.0 0.0 

### Spike Cone 14.4 10.3 

### Lit b C(mtrol LCS Result 15 .6 10.4 

### Standards 

### LCSD Result 15 . 4 10. 7 

### LC S % 

### Rec· 108.1 101.7 

### LCSD %Rec 

### * 107 .0 103.9

G/

o 

### RPD *.* 1.0 2.2 IV

### -Sample & 

### Sample Duplicate

- SCAQMD 25.1,25.3 

### AACID An.lyle 

## 0, 

## N, Sample 6.4 39.7 130160-60985 

### Sample Dup 6.3 39.2 

### Mean 6.3 39.4**%RPD ~** ** 1.4 1.4 

### V-Matrix Spike & 

### Duplicate

- SCA( MD 25.125.3 

### AAC1D Analyte 

## N, CO, Sample Cone 19 .7 1.4 

### Spike Cone 9 .2 10.3 

### MSResult 29.5 12 .0 130160'60985 

### ·, ·MSDReSult 30.4 12.0 

### MS % 

### Rec 

### ** 106.4 10 3 .4 

### MSD % 

### Rec·· 115.7 10 3.3



### % RPD ••• 8.4 0 . 1 

### VI

- OOSiIU! Continuinl! Calibration Verification - S CA OMD 25.125 . 3 

# I MCID 

# I cev • •

MMstbe85-1l5% •• Must be 75-125 % •• tMustbe<25% ND
- Not DeJected 

# . Anatfl. Spike Conc



### Result %Rec·

<RL "" less than Reporting 

### Lima 

# II 0, 

# I 

# N, 5.1S 14.4 5.04 15.S 97.3 110 .0 

# co, 10.3 10 .5 1 102. 5 

### CO, ND


### CIf. 0.0 9.9 9.9 10.0 99.8 100.3 0.5 

### CO, 2.9 2.8 2.9 0.8 

### CIf. 0.0 9.9 10.3 lOA 104 .0 104.5 0.5 

# I CO, 10.3 10.S 105 .0 

# I Instrument ID Calb Date TCD#1 04113/2012 

### Reporting Limit: 0.1 % 

### CIf. CO 9.9 10. 3 9.90 10.33 99.6 99 .8 

### CO 

### ND ND
CO 0.0 10 .3 10 .3 lOA 99.8 100 .5 0.7 

## CH t CO 0.0 0.0 0.0 0 .0 0.0 0.0 0.0 0.0 

### ", CO 0.0 10.3 10.8 10 .9 104 .3 105 .2 0.9



### ' CH. 

# I CO

9.9 10.3 10 .2 10 .6 102 . 5 102.6

# ~~ Marcus Hueppe Laboratory Director 

# I

Page 9 1534 Eastman Ave. , Ste. A • Ventura, • CA 93003 www.aaclab.com • ( 805) 650-1642 • FAX (805) 650-1644

# I

I Atmospheric Analysis & 

# Consulting, Inc.

SCAQMD Method 25.1,3 

## Quality ControVQuality Assurance Report Date Analyzed Analyst 02/1412013 

### ZG
I**~** 

### ODcning Calibration Verification Standard 

### AAeID ' Analvte 

### Concentration O-CV NMNEOC 0.27 O-CV dp NMNEOC 0.27 O-CV tp NMNEOC 0.27 II Method Blank



## - AACID Analvte 

### Result MB 

### NMNEOC ND 111- Matrix Spike & 

### Duplicate

# AAC~ Analyte 

### Sample Concentration 

### 4 NMNEOC 

# I 0.00
IV . I ppm Backflush Standards AAeID · 

# I Analyte 

# I Result 

### Backflush 1 NMNEOC 0.980 Backflush 2 NMNEOC 0.956 Backflush 3 NMNEOC 1.027 Result 0.266 0.274 0.257

Spike 

### Added 

# I S4.3S 

# I % 

### Recovery , " 

### 90.2 87.9 94.5
V Bracketed Closing Calibration Verification Standards



## - AAelD 

# I

C-CV Low C-CV High



### • Must be 90-/10% •• Must be 80-/10% 

## *** Must be 75-125% ***'" 

## Must be < 

### 25% 

## ***** Must he < 

## 10% AnalYte NMNEOC NMNEOC 

# I Concentration 

# I Result 0.27 0.267 2.72 2.48 % 

### Recovery - · 

### 97.9 100.8 94.6

MS 

# I Result 

# I 46.92 

# I I

I % 

### Reeoveryt 

# I 98.3 91.2 MSD Result 

### 46.57 

# I Instrument !D: F!D#4 Units: PPMV 

### Calibration Date:

MS MSD 0/0 

### Ree "' •• % Ree 

# ."'* 86.3 

# I 85.7



### Marcus Hueppe . L

a boratory Director 1/1012013

% RPO
.... 

# I 0.8



## Page 10 1 53 4 Eastm an Ave., S t e. A • Ventura, • CA 93003 www.aaclab .com • (805) 650- 1 642 • FAX (805) 650- 1 644 

# I

# Atmospheric Analysis & 

# Consulting, Inc.

SCAQMD Method 25.1,3 

## Quality Control/Quality Assurance Report Date Analyzed : 02114/2013 Analyst: : ZG Sample Duplicate analysis RPD's 

# I "' AACID 'i 

# I ·-":" ResuU "< 

# I**ResultDu~** 

### 130160-60984 <PQL <PQL 130160-60985 <PQL <PQL 130160-60986 <PQL <PQL 130160-60987 <PQL <PQL 130160-60988 <PQL <PQL 130160-60989 <PQL < PQL



# I Qualitl: Assurance Criteria 

### Cone. (ppmv) 

### %RPD 

## 1·3**~20** 

## 4·6**~15** 

## 7-12 <12 13·30 <10 31-50 <5 

# I



# I Instrument ID: Units: 

### FID#4 PPMV 

### Calibration Date: 1110/2013

> %RPD > 

# I NA NA NA NA NA NA

Marcus Hueppe Laboratory Director



## Page 11 1534 

## Eastman Ave., Ste. A • Ventura, • CA 93003 

# @ www.aaclab.com· (805) 650·1642 • 

## FAX (805) 650

- 1644

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Page 12

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# = C :I Cpmelhodsllnsl #0112012IDI945-01946-3C.MET Oilulion Faclor 

# =1 Calibration File Name 

### = CICpmelhodsllnsl #0112012101945-01 946-3C-041312 - standard
. CAL

Peak # Ret Time Name Amount Amt% Area Area 

### % Type Width 1 7
. 03 Oxygen·MS5A 6
. 385 13
. 043 87492 12.489 BB 0
. 09 2 9
. 15 N itrogen-MS5A 39
. 701 81
. 097 578602 82
. 594 SBB 0
. 11 3 9
. 54 C02-Q bond 2
. 869 5.861 34447 4
. 917 TBB 0
. 20 Total Area 

### = 7005 40.6 Tolal Height 

### = 100279.8 Total Amount 

### = 48
. 95485 24

Printed on 

### 2/14/2013 9:20.11 AM 

# Page**~a1Je** 1 

### of 1Chrom Perfect Chromatogram Repo rt 130160-60985 dp
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## , 0 2 4 6 8 10 12 14 16 18 20 22 24 Ti me - Minutes 

### Sample Name 

### = 130160-60985 dp Instrument = 

### TeO #1 

### Raw File Name 

### = C:ICPDATAllnst#01120131021413.0011.raw 

### Date Taken (end) 

### = 2/14/2013 

### 93639 

### AM Method File Name 

# =C :I Cpmethodsllnst #0112012ID1945-D1946-3C
. MET Dilution Factor 

# = 1 Calibration File Name 

### = C:ICpmethodsllnst #01 12012ID1945-D1946-3C-041312-standard.CAL

Peak 

### # Ret. 

### Time Name Amount 

### Amt% Area Area 

### % Type Width 1 7
. 03 Oxygen-MS5A 6
. 297 13.038 86290 12.485 BB 0.09 2 9
. 15 Nitrogen-MS5A 39.158 81
. 072 570692 82572 SBB 0.11 3 9.54 C02-Q bond 2
. 845 5.890 34159 4
. 942 TBB 0.19 Total Area = 691141 . 7 

### Total Height 

### = 99449.89 Total Amount = 48.30048



### Printed on 2/14/2013 

### 9 : 37:13 AM 

## Page 16 Page 1 of 1Chrom Perfect Chromatogram Report 130160-60986
600
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-100 0 4 6 8 10 12 14 16 18 20 22 24 T ime - Minutes Sample Name 

### = 130160-60986 Instrument 

## = TCD #1 Raw File Name 

### = C:ICPDATAllnst#01120131021413.0014.raw Date Taken (end) = 21141201310:30:48 AM Melhod File Name 

# = CICpmethodsllnst #0112012ID1945-D1946-3C.MET Dilution Factor 

# = 1 Calibra ti on F il e Name 

### = C : ICpmethodsllnst #0112012ID1945-D1946-3C-041312-standard
. CAL

Peak # Ret T i me Name Amount Amt% Area Area 

### % Type Width 1 7.03 Oxygen-MS5A 6.694 13
. 622 91720 13.037 BB 0_09 2 9.15 Nitrogen-MSSA 39
. 801 80.998 580059 82.451 SBB 0
. 11 3 9
. 54 C02-Q bond 2.643 5.380 31737 4.511 TBB 0.20 Total Area 

### = 703516.4 Total Height 

### = 100729 Total Amount 

### = 49.13772

Printed on 21141201310 : 33:40AM 

# Page 17 Page 1 of 1Chrom Perfect Chromatogram Report**130160~0986dp** 600

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### = 130160-60986 dp 

# • Instrument ;;: TeO #1 Raw F ile Name = C:ICPDATAUnst#01120131021413.0015.raw Date Taken (end) 

### = 21141201310:47:21 AM Method File Name 

# = C : ICpmethodsllnst #0112012ID1945-D1946-3C
. MET Dilution Factor 

# = 1 Calibration File Name 

### = C : ICpmethodsllnst #0112012ID1945-D1946-3C-041312-standard.CAL

Peak 

### # Ret. Time Name Amount Amt% Area Area % Type Width 1 7.03 Oxygen-MS5A 6.609 13.642 90565 13.058 BB 0
. 09 2 9
. 15**Nitrogen~MS5A** 39:200 80.911 571306 82.373 SBB 0.11 3 9
. 54 C02-Q bond 2
. 639 5:447 31686 4
. 569 TBB 0.20 Tota l Area 

### = 693556.9 Total Height 

### = 99957.52 Total Amount 

### = 48:44856

Printed on 21141201310:47:51 AM 

# Page 18 Page 1 of 1Chrom Perfect Chromatogram Report 130160-60987 600

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### = 130160-60987 Instrument 

## =TeO #1 Raw FI le Name 

### = C:ICPDATAllnst#01120131021413.0016.raw Date Taken (end) = 

### 2/14/2013 11 :04:54 

### AM Method File Name 

# = C : ICpmethodsl lnst #0112012ID1945-D1946-3C.MET Dilution Factor 

# = 1 Cal i b ration File Name 

### = C:ICpmethodsllnst #0112012ID1945-D1946-3C-041312-standard.CAL

Peak # Ret. Time Name Amount Amt% Area Area % Type Width 1 7.03 Oxygen-MS5A 6.058 13
. 634 83013 13
. 053 BB 0
. 09 2 9.16 Nitrogen-MS5A 35.913 80
. 824 523399 82.298 SBB 0.11 3 9
. 55 C02-Q bond 2.463 5.542 29568 4
. 649 TBB 0.21 Total Area 

# =635980 1 Total He ight 

# = 93820.45 Total Amount 

# =44.43389

Printed on 

### 2/14/201311:06:04 

### AM 

# Page 19 Page 1 of 1Chrom Perfect Chromatogram Report 130160-.60987 dp 600
500

400 0

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## , 0 6 8 10 12 14 16 18 20 22 24 Time - Minutes Samp le Name = 130160-60987 dp Instrument 

## = TeO #1 Raw File Name 

### = C:ICPDATAllnst#01120131021413
. 0017.raw Date Taken (end) 

### = 21141201311:21:13AM Method File Name = C:ICpmethodsllnst #0112012ID1945-D1946-3C.MET Dilution Factor = 1 Calibration File Name = CICpmethodslinst #0112012ID1945-D1946-3C-041312-standard.CAL

Peak 

### # Ret. Time Name Amount Amt% Area Area 

### % Type Width 1 7.03 Oxygen-MS5A 5.932 13.633 81283 13.049 BB 0
. 09 2 9.16 Nitrogen-MS5A 35.217 80.938 513256 82.397 SBB 0.11 3 9.55 C02-Q bond 2.362 5.429 28363 4.553 TBB 0.21 Tola l Area 

### = 622902.6 Total Height 

### = 92448.69 Total Amount 

### = 43.51136

Printed on 211412013 11 :21 :39 AM 

# Page 20 Page 1 of 1Chrom Perfect Chromatogram Report 130160-60988 600
500 

### 400 

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· 100 0 4 6 8 10 12 14 16 18 20 22 24 Time - M inutes 

### Sample Name 

### = 130160·60988 Instrument:;; TeO #1 

### Raw File Name 

### = C:ICPDATAllnst#01120131021413.0018.raw 

### Date Taken (end) 

### = 2/14/2013 

### 11 :39 29 

### AM Method File Name = 

### C :I Cpmethodsllnst #01\2012ID1945-D1946-3C.MET Dilution Factor = 

### 1 Calibration File Name 

### = C:ICpmethodsllnst #01 \2012ID1945-D1946-3C-041312-standard.CAL

Peak # Ret Time Name Amount Amt% Area Area 

### % Type Width 1 703 Oxygen-MS5A 6.397 14.092 87659 13.485 BB 0.09 2 916 Nitrogen -M S5A 

### 36.675 80.788 534501 82.223 SBB 0
. 11 3 9.54 C02-Q bond 2.324 5.120 27905 4 .2 93 

### TBB 0.21 Total Area 

# = 6500646 Total Height 

# = 95324.45 Total Amount:;; 45.39617



### Printed on 2/14/2013 

### 11 :4042 AM 

# Page 21 Page 1 of 1600
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16 18 I 20 22 24

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### = C:ICPDATA\lnst#01120131021413.0019.raw Date Taken (end) = 

### 2/14/2013 

### 11 : 56 :00 AM Method FIle Name 

# = C :I Cpmethodsllnst #0112012ID1945-D1946-3C
. MET Dilution Factor 

# = 1 Cal ib ra tion File Name 

### = C: I Cpmethodsllnst #0112012\D1945-D1946-3C-041312 - standard
. CAL

Pea k # Ret. 

### Time Name Amount Amt% Area Area % Type Width 1 7
. 03 Oxygen - MS5A 6.399 14
. 093 87691 13.489 BB 0.09 2 9
. 16 Nitrogen-MS5A 36.621 80.648 533712 82 .1 00 SBB 0
. 11 3 9.54 C02-Q bond 2
. 388 5.259 28670 4.410 TBB 0.20 Total Area 

# =650072.5 Total He i ght 

# = 95161.16 Total Amount 

# =45.40808

P nnted on 

### 2 / 14/201311 :56:28 AM 

# Page 22 Page 1 of 1600

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# . 0 0- 300 

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### = 130160·60989 Instrument 

## =TCD #1 Chrom Perfect Chromatogram Report



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12 Time· Minutes 14 16 18 20 22 24

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### = C:ICPDATAllnst#01120131021413.0020.raw Date Taken (end) = 

### 2/14/2013 12: 13:24 PM Method File Name 

### = C :I Cpmethodsllnst #01 \2012ID1945·D1946·3C.MET Dilution Factor 

### = 1 Calibration File Name 

### = C:ICpmethodsllnst #01 \2012ID1945·D1946·3C·041312·standard
. CAL

Peak # Ret T i me Name Amount Amt% Area Area % Type W i dth 1 7.02 Oxygen-MS5A 8
. 217 14
. 143 112592 13
. 532 BB 009 2 9 .1 4 Nitrogen - MSSA 46
. 947 80
. 806 684204 82.233 SBB 0
. 12 3 9
. 53 C02-Q bond 2.935 5
. 051 35232 4
. 234 TBB 0
. 26 Total A rea 

# = 832028.5 Total Height 

# = 113797.1 Total Amount 

# =58.09794

Printed on 

### 2/14/201312:13:50 PM 

# Page 23 Page 1 of 1Chrom Perfect Chromatogram Report 130160-{}Q989 dp 600
500

400 

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### = 

### TeO #1 Raw File Name 

### = C:tCPDATA\lnst#01t2013t021413.0021.raw Date Taken (end) 

### = 21141201312 : 30 : 20 PM Method File Name 

# = C :tC pmethodstlnst #01\2012tD1945-D1946-3C
. MET Dilution Factor 

# =1 Calibration File Name 

### = C:tCpmethodstlnst #01 \2012tD1945-D1946-3C-041312-standard.CAL

Peak # Ret. 

### Time Name Amount Amt% Area Area % Type Width 1 7 .02 Oxygen-MS5A 8.228 14
. 129 112749 13.519 BB 0.09 2 9.14 Nitrogen-MS5A 47.064 80.817 685913 82.244 SBB 0.12 3 9
. 53 C02-Q bond 2.943 5.053 35333 4 .2 37 TBB 0.20 Total Area 

# = 833994.2 Total Height 

# = 114081
. 9 Total Amount 

# =58
. 23498

Printed on 

### 2114/201312:30:47 PM 

# Page 24 Page 1 of 1

### -- - - 1600

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### = 130160-60984 Instrument 

## = FlO #4 Chrom Perfect Chromatogram Report

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### = C :I CPDATAllnst#04120131021413_0008.RAW Date Taken (end) = 

### 2/14/2013 7:44:52 AM Method File Name = C:ICpmethodsllnst #04\2013IMethod25.1 , 3_low.met Dilution Factor = 1 Calibration File Name 

### = C:ICpmethodsllnst #04\2013IM251 , 3Iow-Oll013
. CAL

Peak 

### # Ret. Time Name Amount Amt% Area Area 

### % Type Width 1 0.85 Carbon Monox ide 25.998 1.244 368221 0.861 BV 0.20 2 106 Methane 14.563 0.697 284421 0.665 

### W 0.17 3 194 Carbon Dioxide 2049.641 98.058 42115948 98:469 VB 0
. 50 4 5
. 53 NMNEOC 1 0.038 0.002 2043 0.005 BB N 0.13 Total Area 

## =4 .27706 4E+07 Total Height = 1130671 Total Amount 

## = 2090.24-

Printed on 

### 2/14/2013 7:59:39 AM 

# Page 25 Page 1 of 11600
1400
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# . "**~** 800 

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## = FlO 

### #4 Chrom Perfect Chromatogram R eport



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6 .0 u 0 w z 

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### = C :I CPDATA ll nst#04 12 013 102 1413
. 0009.RAW D ate Taken (end) 

### = 2/ 14/2013 7:57 : 24 AM Method File Name 

# =C : \Cpmethods\lnst #0 4\2013\Method2S . 1 ,3_low.met Dilution Factor 

# = 1 Calibrat i on File Name = C : ICpmethodsl l nst #0412013IM25
. 1 , 310w-011 OnCA l

Peak # Ret. Time Name Amo u nt Amt% A r e a Area 

### % Type W id t h 1 0
. 86 Carbon Monoxide 23. 1 30 1.12 1 327598 0
. 775 BV 0.20 2 1
. 06 Methane 14
. 118 0.684 275718 0
. 653 

### W 0
. 17 3 1.87 C a rbon Dioxide 2026
. 839 98.194 4 1 64 7420 98
. 569 V B 0.49 4 5.75 NM NE OC 1 0
. 025 0
. 001 1362 0
. 003 BB N 0
. 23 Total Area 

### = 4.22521 E +07 T otal Height 

### = 1124763 Total Amount 

### = 206 4
. 112

Printed on 

### 2/ 14/2013 7: 5 9 :45 AM 

# Page 26 Pag e 1 of 11600
1400
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# . 0

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### = 130160·60985 Instrument 

### = FlO #4 Chrom Perfect Chromatogram Report**~** 

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### = C:ICPDATAllnst#04120131021413.0012.raw Date Taken (end) = 211412013 8:39:08 AM Method File Name 

### = C:\Cpmethods\lnst #04\2013\Method25 . 1 ,3Jow . met Dilution Factor 

### = 1 Calibration F i le Name 

### = C:ICpmethodsllnst #0412013IM25
. 1 ,310w-011013
. CAL

Peak # Ret. Time Name Amount Amt% Area Area % Type Width 1 0.85 Carbon Monox ide 20.641 0
. 946 292346 0.654 

## BV 0.19 2 1.06 Methane 15.728 0.721 307177 0.687 

## VB 0.17 3 197 Carbon Dioxide 2146,404 98.333 44104240 98657 BB 0.52 4 5
. 69 NMNEOC 1 0
. 020 0.001 1073 0
. 002 BB N 0.17 Total Area 

### = 4,470484E+07 Total Height 

### = 1124409 Total Amount 

### = 2182.793

Pr i nted on 211412013 85505 AM 

# Page 27 Page 1 of 11600

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### = C: I CPDATAllnst#04 12013 1021413.0013 .raw Date Ta ken (end) = 

### 2 / 14 / 2013 8 : 53 : 20 AM Method File Name 

# = C :I Cpme thods l lnst #0412013\Method25
. 1 , 3Jow
. met Dilution Factor 

# = 1 Calibrat io n F ile Na me 

### = C : ICpmethodslln5 t #0412013 I M25
. 1
. 310w-011 onCA l

Peak # 

### Ret. Time Name Amount Amt% Area Area 

### % Type Width 1 0.86 

### Ca rbon Monoxide 18.717 0
. 860 26510 1 0
. 595 BV 0
. 19 2 1.06 

### Metha ne 15
. 616 0
. 718 304985 0
. 684 VB 0
. 18 3 1
. 94 

### Carbon Dioxide 2142
. 022 98.422 44014208 98.720 BB 0.52 4 5
.69 NMNEOC 1 0
. 015 0.001 811 0
. 002 BB N 0.17 T otal Area 

### = 4.45851E+07 T ota l Heig ht 

### = 11 21025 T otal Amount 

### = 2176
. 371

Pr i nted on 

### 2/14/2013 855: 13 AM 

# Page 28 Page 1 of 11 600

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### = 2/14/2013 9 : 0659 AM Method F il e Name:: C : \Cpmethods\lnst #04\20 1 3\Method25.1 , 3Jow.met Dilution Factor:: 1 Cal i bra ti on File Name 

### = C : ICpmethods l lnst #04\2013IM25
. 1 ,3 1 0w-0 1 1OnCAl Peak # Ret. T i me Name Amount Amt% Area Area % Type W i dth 1 0
. 86 Carbon Monoxide 18
. 772 0
. 888 265879 0
. 614 BV 021 2 1.05 Methane 9.448 0.447 184515 0.426 VB 0
. 1'6 3 1
. 98 Carbon Dioxide 2084 .7 29 98
.664 42836936 98
. 958 BB 0.51 4 5.51 NMNEOC 1 0.016 0
. 001 856 0
. 002 BB N 0
. 11 T o tal Are a 

### = 4
. 32 8818E +07 Total He i ght 

### = 1 109342 Total Amount 

### = 2112
. 964

Pr in ted on 2/14/2013 9 : 29 : 50 AM 

# Page 29 Page 1 of 11600
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### Raw File Name; C:ICPDATAllnst#04120131021413.0015.raw Date Taken (end); 2/14/2013 

### 925:21 AM Method File Name = C : \Cpmethods\lnst #04\2013\Method25.1 ,3_low . met D i lution Factor = 1 

### Calibrat i on File Name; C :I Cpmethodsllnst #0412013IM25.1 ,310w-011013.CAL

Peak # Ret. Time Name Amount Amt% Area Area 

### % Type Width 1 085 Carbon Monoxide 

### 17.547 0
. 831 248531 0.575 

## BV 0.20 2 1.06 Methane 

### 9
. 150 0.434 178710 0.413 

## VB 0
. 17 3 1.93 Carbon D ioxide 

### 2084.110 98.734 42824216 99.010 

## BB 051 4 5.52 NMNEOC 1 0.016 0
. 001 880 0.002 

## BB 0. 1 1 Total Area; 4
. 325234E+07 Total Height; 1108594 Total Amount; 2110.823

Printed on 2/14/2013 

### 9:29:56 AM 

# Page ,0' Page 1 of 1

# ~l 1400

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### 2/14/2013 9:40:20 AM Method Fi le Name = C :\Cpmethods\lnst #04\2013\Method25.1 ,3Jow. met Dilution Factor = 1 Calibration Fil e Name 

### = CICpmethodsllnst #04\2013IM25.1 , 310w·011013.CAL

Peak # Ret Time Name Amount Amt% Area 1 0
. 86 Carbon Monox ide 16.236 0
. 788 229966 2 1
. 05 Methane 8
. 154 0.396 159258 3 1.96 Carbon Dioxide 2035.720 98.812 41829908 5 5 .5 3 NMNEOC 1 0
. 010 0.001 553 

### 6 6
. 72 NMNEOC 2 

### < 0
. 065 0003 3467 -.-o,S Tota l Area 

### = 4.222315E+07 Total Height 

### = 1105057

Pnnted on 

### 2/14 /20 13 10004 3 AM Area % Type Width 0
. 545 

## BV 0.20 0
. 377 

## VB 0.16 99
. 069 

## BB 0.49

0.001 

## BB 0.08 0
. 008 

## BB N 0:44 Total Amount 

### = 2060
. 186



# Page 31 Page 1 of 1 

# liJ1-\**\~\I~**1600
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### = 2/14/2013 9:53:44 AM Method File Na m e 

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# = 1 Calib ration File Name 

### = C:ICpmethodsllnst #0412013IM25.1 ,310w-Oll013
. CAL

Peak # Ret. Time Name Amount Amt% Area Area % Type W i dth 1 0
. 85 Carbon Monoxide 15.297 0.746 216665 0.516 

## BV 0.20 2 1
. 05 Methane 8
. 025 0.392 156731 0.373 

## VB 0.16 3 1
. 94 Carbon D iox ide 2026
. 369 98858 41637756 99.101 BB 0:49 5 5
. 53 NMNEOC 1 0
. 009 0 .0 00 505 0.001 BB 0.08 6 6.75 NMNEOC 2 • 0
. 075 0004 4019 0.010 BB N 0:43 

### o
- 0'/)1- T otal Area 

# = 4.201568E+07 Total Height 

# = 1103646 Total Amount 

# =2049.775

Printed on 2/14/2013 10:00:48 AM 

# Page 32 Page 1 of 11600

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_ 0020,raw Date Taken (end) 

### = 21141201310:40:48 AM Method File Name 

# =C : \Cpmethods\lnst #04\2013\Method2S . 1 ,3Jow . met D i lution Factor 

# = 1 Calibrat i on File Name 

### = C:ICpmethodsllnst #0412013IM25
. 1,310w-011 013
. CAL

Peak # Ret T i me Name Amount Amt% Area Area % Type Width 1 0.86 Carbon Monoxide 23.426 1
. 142 331802 0.790 BB 0.23 2 1.96 Carbon Dioxide 2027.373 98
. 857 41658396 99.209 BB 0.49 3 5
. 68 NMNEOC 1 0.010 0
. 000 533 0.001 BB N 0
. 16 Total Area 

# = 4.199073E+07 Total Height 

# = 1092637 Total Amount 

# =2050
. 81

P ri nted on 2 1 1412013 11 : 00:40 AM 

# Page 33 Page 1 of 1"0

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# =C :\ Cpmelhods \lnst #04\2013\Method25 . 1 ,3_low . met D iluti on Factor 

# = 1 Calibration File ' Name = C :I Cpmethods l lnst #0412013 I M25
. 1 , 310w· 011 013
. CAL

Peak # Ret. T ime Name Amount Amt% Area Area 

### % Type W i dth 1 0
. 86 Carbon Monoxide 21.857 1
. 074 309577 0
. 743 BB 0
. 25 2 1.89 Carbon Dioxide 2013.586 98
. 926 41375100 99
. 256 BB 0,49 3 5
. 52 NMNEOC 1 0.011 0
. 001 569 0
. 001 BB N 0
. 10 T otal Area 

### = 4
. 168524E+07 Total He i ght 

### = 1089396 Tota l Amount 

### = 2035.454

Printed on 2/14/2013 11 : 00:45 AM 

# Page 34 Page 1 of 11600
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### 2/14/2013 11 : 10:43 AM Melhod File Name 

# = C :I Cpmelhodsllnsl #0412013IMethod25.1
. 3Jow.met Dilution Factor 

# = 1 Calibration F ile Name 

### = C:ICpmethods l lnst #0412013IM25
. 1
. 310w·011 013.CAL

Peak # Ret 

### Ti me Name Amount Amt % Area Area % Type W idth 1 086 

### Carbon Monox ide 22
. 691 1 .0 54 321381 0
. 729 

### SS 0
. 26 

### 2 1.92 

### Carbon Dioxide 2129
. 163 98
. 945 43749968 99.269 

### SS 0
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. 001 877 0
. 002 

### SS 0
. 09 Tolal Area 

### = 4:407222E+07 Tota l Height 

### = 1089665 Tolal Amount 

### = 2151
. 87

Pri n l ed on 

### 2/14/2013 11 :2639 AM 

# Page 35 Page 1 of 11600
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. 0023
. raw Date Taken (end) 

### = 2 / 14/ 2013 11 : 23 : 52 AM Method Fi le Name = C :I Cpmethods l lnst #04 12013IMe thod25
. 1 , 3_ low.me t Dilut ion Factor = 1 Calibration F il e Na me 

### = C :I Cpmethods l l nst #0412 013I M25
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Peak # 

### Ret. T ime Name Amount Amt % Area Area % Type Width 1 0
. 86 

### Carbon Monoxide 21 .57 5 1.010 305583 0
. 698 

## BB 0.27 2 1 .96 

### Carbon Dioxide 2114
. 615 98
. 989 43451044 99
. 300 

## BB 0
. 51 3 5
. 52 NMN EOC 1 0 .0 14 0
. 001 767 0
. 002 

## BB 0
. 08 Total Area 

### = 4
. 37574 E+0 7 To tal Height 

### = 1087625 T otal Amount 

### = 2136.205

Printed on 

### 2/14/2013 1126:52 AM 

# Page 36 Page 1 of 1

# Calibration Summary

Page 37

### SCAQMD Method 25.1 

## 125.3 Calibration Curve (GC/FID/TCA #4) ANALYTE: TNMNEOC (as Propane) Analysis Date: 1/10 /2 013 Theoretical Retention time Response RPDfrom Std 

### Theoretical Concentration initial result Concentration (ppmv) (min) Area (+1- 20%) Deviation (ppmv)



### 0.11 6 .89 6436 0.11 6 . 84 6635 3.0 140 .71 0.11 0.27 6.85 14293 0.27 6 . 86 14483 1 . 3 134 . 35 0 . 27 0.54 6 . 86 26743 0.54 6 . 85 28478 6 .3 1226 . 83 0.54 1 .09 6 . 85 62346 1.09 6 . 85 65692 5 . 2 2365 .98 1 .09 2.72 6 .84 167066 2.72 6 . 85 156327 5.4 6179.41 2.72 5.44 6.84 282757 5.44 6.84 280611 0.8 1517 . 45 5 .44 AvgRT 

### 6 . 65 RTWindow + /- 0.20 

### min Calibration Verification Standards : CCV Retention Time Result (ppmv 

### % 

### Rec· 2.5 ppmv 

### 6.64 2 .69 106 . 3 2.5 oomv do 

### 6 . 85 2.79 102 .5 'M ust be +/- 10 

### % of Theoretical Concenfration
Analyst (Inti t i al & date) : :i13 \ 

# I\0113 Lab Director (Initial 

### & date) : 

# 1m

# ~**~I** Analyst: Response Area (mean)



### 6536 14388 27611 64019 162697 281684 Calb. Type R2 value: Intercept (8) Lin Const (M) 

### ZG Calculated Concentration (From Mean) 

### 0.12 0 .27 0 .52 1 . 19 3.04 5 .26 

### linear 0 .9925

0
.00 

### 53584 . 69 Recovery (+1- 15 

### % ) 

### 112 99 95 110 112 97 Y=MX+B Must be :> 0, 990 Included 00 M 

# ..,**~** i:l..

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### <C 4
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### 2
. E+05
2
. E+05
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S
. E+04 

# 1/ O
. E+OO 0
. 00 

## TNMNEOC (as Propane) Plot

, 

## , "


# ,



# ., y = 

### 53584
.6911x 

## R

2 = 0.9925



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### ' 

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. 00 2
.00 3
.00 4
. 00 5.00 6.00 

### Concentration (ppmv) 0- M

# ~ p.,

### Date : 0111012013 Analyst: 

## ZG Analvte : Cone. MDL#1 

### NMOC 

### 0 .050 0 .058



### Analvte: Mean 

### Std Dev NMOc 

### 0 .051 0 .005 

## FlO MOL Study per SCAQMO 

## 25.1/25.3 Instrument: GCIFID #4 Units: ppmV MDL#2 MDL#3 MDL#4 MDL#5 MDL#6 MDL#7



### 0 .050 0 .054 0 .043 0 .051 0 .056 0 .047 

### MDL " Method Detection Limit Study per USEPA Guidelines MDL MRL 

### 0.016 0.049 MOL (Method Detection Limit) (7 rep licates) 

### = Sta n dard Deviation x 3 .1 43 MRL ( Min im u m Rep orting Limit) 

### = MOL x 3.0 

### Is the spiked concentration 

### < 10 times the calculated 

### MDL0 N Defi/)ition: MDL- T he minimum concentration of a substa nce that ca/J be Ide/Jtified, me asured and reported 

### wit" a 

### 99% confidence interval, th a t the ana /yte concentration is greater than ze ro and 

### is determined fr om the a nalysis 

### of a sam pl e in 

### a given matrix containing the a na/yt e. Defini tion : MRL - The sm a lle s t measured concen tratio n 

### of a substance th at can be reliably meas ur ed by u sing a g i ven analytica l method
. 

## o 

# "'" .,**~ ~** Analvte: LOD LOa Conc./MDL NM OC 0,01 6 

### 0 , 05 2 3 

### Alternative Supporting Calculations M%Rec S : N Ratio 

### 103 9 . 8 3 L O D { Lim i t of De t ec t ion) ;:,· Sta nd a r d D evia ti o n )( 3 , Q L O Q ( Li mi t of Q u a nti ta t ion)= Stand a rd D e ..' l at io n)( 1 0 ,0 Mea n 

### % Ree • (M ean Rest T r ue Value ) Y. 10 0 % Is the Mean % Ree between 80% and 120% 

# ?<Y) I N C: onc .l M DL - C o nce nt ra t i on I MO L 

### I?\ Is the Conc.lMDL between 2 to 5?1....!J1 N 

### 3i gna l t o Noi s e Ratio · (M e an /StdDe v) Is the signal to Noise Ratio between 2
. 5 and 

### 10'6>1 N De finition : LOD - The lo wes t con c entration that can b e determin ed to be st a ti

s tic a lly differen t fr o m a bra n k. Definition : LOO - The concentration ab o ve which quantitative results c a rl be obtained with 

### a specific degree 

### of confidence
. Analyte: POL RL

### ~ NMOC 0
. 1 04 0
. 1 04 

### Proposed POL and RL Pra c tic al Quan t ita t; on li mit Is the PQL 2 to 5 times higher than the LOQt(Y)1 N R epo lt i n g Li mit Is the 

### Rl equal to or greater than the 

### PQl 

# QI N POL ( Pract i ca l Quan t i ta ti o n Lim it) = E sta bl ish e d b y th e l abo ra tory ba se d o n the a b o v e ca l c ula t i o n s R L ( Re p o rtin g Li mit)::o Es ta bl i s he ( 1

### b y th e la bora t ory ba s ed on the 

### P Q l a n d for m ettl od , Definition, ' PQL· The lowest level tllat c an b e reli a bly achieved wit/fin specified limits o f 

### precision and accuracy during routine laboratory operating c onditions , In addition , if qua t i ta t ing at this level, th e lowest pOint of th e ca libr a t

ion c urve mu s t be s et at this 

### point Co mments : Analyst (s i gn & date) : 

### $3 \ \ \ 0 \ \ 5 Lab D i rector ( sign & date) : 

# ;;&._. 

# ¢7.J 

# - '<t

# ~ p...

## Appendix C.6 PM 

## by SCAQMD Method 5.1

R041 0688 C - 10SCAQMD METHOD 5.1 PARTICULATE TEST DATA SUMMARY ClientJlocatlon. Unit Sample location Test No. Test Method Da te Start Ti me Stopnme Sample Train Pitot Factor Meter Cal Factor Stack. Area (sq ttl Sample Time (M i n) Bar Press (in Hg) Nozzle Diam ( i n) Stack. Press (iwg) Stacll Temp (F) Vel Head (iwg) Stack. 02 (%) Stack C02 (%) Meter Vol (acf) Meter Temp (F) Me ter Press (iwg) Liquid Vo l (mil Sid Sample Vol (SCF) MOisture Fraction Slack Gas Mol Wt Stack Gas Velocity (It/sec) Stack Fl ow Rate (wacfm) Slack. Flow Rate (dscfm) Isoklnelic Ratio ( % ) Facility Average Gas Flow (hscfh)
.. Facility Average Gas Flow (MMscfh)
. Total Weight Gain, mg Particulate EmissIons Grain Loading. gr/dscf
.. . Grain Loading @3%02 Gra i n Load i ng@ 15% 02 Grain Loading@12%C02
. Mass Emissions, Ib/hr ' .• Em i ss i on Ra te . IbfMMSCF 1 ) 11 IbJhr per Rule 475 PM Limrt Gemma Sentinel

4 S-4!STK·PM·loo·1

SCAQMOS
. l

211112013

8 :41 12:55 17-WCS

0,84 0
. 996 143
. 14 240 29
.64 0
. 234 2 .4 0 769.4 1
. 5320 12
.99 4.44 183
. 160

58,6 175 432.2 1 81.978 0.099 28 . 11 107.48 923 , 058 350 , 311 103.70 8845
. 2 0
. 885 1 7 .2 0
. 0015 0
. 0033 0
. 0011 0
.0039 4,38 4 ,95 Reference Temp (F). 60 Fuel Nat. Gas Data By AA Average Limits

2 .4 0 769.4 1 .532 0 13
.0 4.4 183 , 16 58
.6 1
. 75 432
. 2 181
. 978 0
.099 28.11 107.48 923 ,058 350 , 311 103.70 8845
. 2 0,885 17
. 2 0
.0015 0,0033 0,0011 0,0039 4
. 38 4
. 95 Limits 0.01 01 11 5
. 71

Sentinel Un it 4**IOI ~'"**  PM**S"n\JTW~** 2111 120 1 J 2:l 1 PM. I ; I ;

# ~ 

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P age ISC AQ M D METHOD 5 , 1 PARTI C ULATE TEST DATA SUMMARY Cli e n t/ L oc ation , Unit Sample Locatio n Test N o , Test Method Date Start Time Stop Time Sample Train P itot Factor Meter Cal Factor Stack Area (sq ttl Sample Time (M i n) Bar Press ( i n Hg) Nozzl e D i am (in) Stack Press (iwg) Stack Temp (F ) Vel Head ( iwg) Stack 02 (%) Slac k C02 (%) Me t er Vol (act) Me t er Temp (F) Me t er Pr e ss (iwg) liquid Vol (mil Sid Sa mple Vol (SCF) M Ois t ure F raction Slacll G as Mol W t Stack Gas Velocity (flJsec ) Stacll Flow Rate (wacfm) StaCk Flow Ra te (dscfm) Iso kineti c Ratio ! % ) Facil i ty Average Ga s Fl ow (hscfh)
.. Facil i ty Average Gas Flow ( MMscfh) Tol a l Weight Gain , mq .. Parti c ulate Emissions Gra i n Loading, gr/dscf... Grai n Loading @ 3% 02
. . Grain Loading@ 15% 02
. .. Grain Loading@ 12% C02
. Ma ss Em ls s i ons , lblhr ' . Em i ssion Rate , I b/MMSCF 1) 11 Iblhr per Rule 475 PM Li mit Gemma Sentine l 4S·4/STK·PM·75·1

SCAQM 0 5
. 1

2111/2013

14:48 18 : 56 17- wes

0 . 84 0
. 996 143
. 14 240 29.64 0.234 2.40 752.4 1.3751 13.83 4.05 1 74
. 630

52
.6 1.52 380.9 175.437 0
. 09 2 28
. 17 101
. 01 867 , 5 1 8 33 6 , 734 104.01 5:;74 .0 0
.6 9 7 44 0
. 0004 0
. 0010 0
. 0003 0
. 0011

1
. 12 1.60 Referen ce Te mp ( F), 60 Fuel Nat. Gas Data B y AYerag e

2
.4 0 752.4 1
.3751 13.8 4 . 0 174
.63 52
.6 1
. 5 2 380
. 9 175 .4 37 0
.092 28.17 1 01.01 867 , 5 1 8 336 , 734 104.01 6974
.0 0.697 4.4 0
. 000 4 0
. 0010 0
. 0003 0.0011 1
. 12 1
.60 AA Limits

Limits 0
. 01 0 . 1 1 1 5
. 71

Senli"d Unil**~** 15% PM**Su",n' '**  21211200**22 ~**  PMI 

# I 

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### .... SCACMD METHOD 5
. 1 PARTICULATE TEST DATA SUMMARY Client/location. Unit Samp l e Locat km Test No
. Tes\ Mettlod Date Start Time SlOp Time Sample Train Pilot Factor Meier Cal Factor Stack Area (sq ttl Sample Time (Min) Bar Press (in Hg) Nozzle Diam (in) Stack Press (iwg) Stack Temp (F) Vel Head fiwg) Stack 02 (%) Stack C02 (%) Meter Vol ( sct) Meter Temp (F) Meier Press (iwg l Liguid Vol (ml) SId Sample Vot (SCF) Moisture Fraction Slack Gas Mo l IIV\ Slack Gas Velocity (ft/sec ) S1aCk Flow Rate (wacfm) StadI: Flow Rate (dsdm) l50klnet lc Ratio ("to) Faollty Average Gas Flow (hsdh)
. . Facility Average Gas Flow (MMsdh)
.. Total Weight Gain m9
.. Part icu lat e Emissions Grain Loading, gr/dscf
.. Grain Loading 

### tm 3% 02
. Grain Loading 

### tm 15% 02
. . . Grain Loal1ing 

### tm 12% C02 Mass Emissions , Iblhrl.
...... . EmiSSion Rate , IblMMSCF 1) 11 Ibl1"1r per Rule 475 PM Umit Gemma Sentinel

4 S-4!STK-PM-50-1

S CAQMDS . l

2112/2{113

11 . 45 15 : 52 

### H

- wes 084 0 . 996 1 4 3.14 240 2974 0 . 23 4 2.40 785 .6 0 . 7075 1423 379 134 .830

73.6 078 241 . 5 130 . 327 0 . 079 26 . 29 73 . 17 626 , 365 241,434 107.76 5354. 1 0.535



# " 0 .0007 0.0018 0,0006 0,0022

1 ,4 2 2 .65 Reference Temp (F)
. 60 Fuel Nat Gas Oatil By Average

2.40 785 .6 0 . 7075



# '" 3 .8 134 . 83 73 .6 0 . 76 2415 130 . 327 0 . 079 28 . 29 73 . 17 628 . 365 241,434 107.76 535-4 . 1 0535 5 . 8 0 .0007 0 .0016 0.0006 0 . 0022 1.42 2 .65 AA Limits

Limits 0.01 0.1 11 5 . 71

Sc:millci Uni l4**~O %**  PM Summa!) ' 212112013 1:27 PM

# ~**~~.** '.46

# .

# ~

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Page I

### CPV SENTINEL UNIT 4 PARTICULATE TEST STACK 

## 0" CO, DATA Test 

## #: S-4/STK-PM-100-1 Date: 2111/2013 Time: 8:41 12:55 Load: 107 MW O 2 

### CO 2 

### Range 20 10 Cal Gas 9
. 98 4
. 96 Analyzer Zero 0
. 11 -0
. 02 Analyzer Span 10.00 5.11 Pre-Bias Zero 0.17 0.02 Pre-Bias Span 10.35 505 Post-Bias Zero 0.17 0.03 Post-Bias Span 10
. 02 5
. 07 Average Bias Zero 0.17 0.02 Average Bias Span 10.18 5.06 Pre-test zero bias 0.3% 0.4% Pre-test span bias 1.7% -0.6% Post-test zero bias 0
. 3% 0.4% Post-test span bias 0.1% -0.4% Zero Drift 0
. 0% 0.1% Span Drift -1.6% 0.1% 

### Test Results (from data logger average) Average 13.20 4.53 Cal Corrected 12.99 4.44

### O 2 

### CO 2 

### Date Time % % 2/11/2013 8 : 42 : 00 13
. 139 4.574 2/11/2013 8 : 43:00 13
. 141 4.574 2/11/2013 8 : 44 : 00 13
. 143 4
. 574 2/ 11 /2013 8 : 45 : 00 13
. 146 4
. 572 2/11 /2013 8 : 46 : 00 13
. 153 4
. 572 2/11 /2013 8 : 47 : 00 13
. 153 4
. 573 2/ 11 /2013 8 : 48 : 00 13
. 155 4
. 571 2/11/2013 8 : 49 : 00 13
. 148 4
. 574 2/11/2013 8 : 50 : 00 13
. 15 4
. 574 2/ 11/2013 8 : 51 : 00 13
. 156 4
. 568 2/ 11 /2013 8 : 52 : 00 13
. 176 4
. 557 2/ 11/2013 8 : 53 : 00 13
. 178 4
. 557 2/ 11/2013 8 : 54 : 00 13
. 176 4
. 556 2/ 11 /2013 8 : 55 : 00 13
. 168 4.559 2/ 11 /2013 8 : 56 : 00 13
. 189 4
. 54 2/11/2013 8 : 57 : 00 13.193 4
. 541 2/11/2013 8:58:00 13.191 4
. 542 2/ 11 /2013 8:59 : 00 13
. 186 4
. 552 2/ 11 /2013 9 : 00 : 00 13
. 188 4
. 546 2/11 /2013 9 : 01 : 00 13
. 18 4
. 552 2/ 11/2013 9 : 02 : 00 13
. 187 4
. 55 2/ 11/2013 9 : 03 : 00 13
. 182 4
. 556 2/11/2013 9:04:00 13.199 4
. 544 2/11/2013 9 : 05 : 00 13.182 4
. 561 2/ 11 /2013 9 : 06 : 00 13
. 156 4
. 572 2/11 /2013 9 : 07 : 00 13
. 128 4
. 588 2/ 11 /2013 9 : 08 : 00 13
. 111 4
. 6 2/ 11 /2013 9 : 11 : 00 13
. 169 4
. 568 2/11/2013 9 : 12 : 00 13.152 4
. 576 2/11/2013 9 : 13:00 13
. 176 4.558 2/11 /2013 9 : 14:00 13
. 191 4
. 55 2/ 11 /2013 9 : 1500 13
. 183 4
. 556 2/ 11 /2013 9 : 16 : 00 13
. 188 4
. 556 2/11 /2013 9 : 17 : 00 13
. 152 4
. 583 2/ 11/2013 9 : 20 : 00 13
. 186 4
. 565 2/11/2013 9 : 21 :00 13
. 193 4
. 554 2/11/2013 9 : 22 : 00 13.183 4
. 567 2/ 11 /2013 9 : 23 : 00 13
. 189 4
. 557 2/11 /2013 9 : 24 : 00 13
. 183 4
. 561 2/11/2013 9 : 25 : 00 13
. 182 4
. 558 2/ 11 /2013 9 : 26 : 00 13
. 163 4
. 567 2/ 11 /2013 9 : 27 : 00 13
. 176 4
. 56 2/ 11/2013 9 : 29 : 00 13
. 199 4.549 2/ 11 /2013 9 : 30 : 00 13
. 2 4
. 544 2/11/2013 9 : 31 : 00 13.204 4
. 543 2/11 /2013 9 : 32 : 00 13.207 4
. 544 2/11 /2013 9 : 33 : 00 13.224 4
. 533 2/ 11 /2013 9 : 34 : 00 13
. 219 4
. 538 2/11/2013 9 : 35 : 00 13
. 21 4
. 542

### 2/11 / 2013 

## 9 : 36 : 00 13 .215 4 . 54 2/11/2013 

## 9 : 59 : 00 13.221 4 . 519 2/11/2013 

## 10 :00 :00 13.207 4 . 527 2/11 / 2013 

## 10 :01 :00 13.216 4 .524 2/11 / 2013 

## 10 :02 : 00 13.215 4 .526 2/11 / 2013 

## 10 :03 : 00 13 .225 4.523 2/11/2013 

## 10 : 04 : 00 13 .234 4.521 2/11/2013 

## 10 : 05 : 00 13 .25 4 .513 2/11/2013 

## 10:06:00 13.234 4 . 519 2/11/2013 

## 10 : 07 : 00 13.223 4 . 527 2/11/2013 

## 10:08 : 00 13.222 4 . 528 2/11/2013 

## 10 : 09 : 00 13.227 4 . 526 2/11/2013 

## 10 : 10 : 00 13 .222 4 . 528 2/ 11/2013 

## 10 : 11 : 00 13.219 4 . 532 2/ 11 / 2013 

## 10 : 12 : 00 13.219 4 . 528 2/ 11 / 2013 

## 10 : 13 : 00 13.211 4 . 533 2/11 / 2013 

## 10 : 14 : 00 13.227 4 . 524 2/11 / 2013 

## 10 : 15 : 00 13 .218 4 . 531 2

/ 11/2013 

## 10 : 16 : 00 13.205 4 . 543 2/11/2013 

## 10 : 17 : 00 13 .222 4.529 2/11/2013 

## 10 : 18 : 00 13 .252 4.514 2/11/2013 

## 10 : 19 : 00 13.231 4.523 2/11/2013 

## 10 :20 : 00 13 .254 4 . 512 2/11/2013 

## 10 :21 : 00 13 .255 4 . 512 2/11/2013 

## 10 :22 : 00 13.26 4 . 509 2/11/2013 

## 10 :24 : 00 13.215 4 . 531 2/11 / 2013 

## 10 :25 : 00 13 .212 4 . 529 2/ 11 / 2013 

## 10 :26 : 00 13.232 4 . 519 2/ 11 / 2013 

## 10 :27 : 00 13.224 4 . 522 2/11 / 2013 

## 10 :28 : 00 13.211 4 . 528 2/11/2013 

## 10 :29 : 00 13.216 4 . 521 2/ 11/2013 

## 10 : 30 : 00 13.233 4 . 515 2/ 11 / 2013 

## 10 : 31 :00 13.211 4 . 524 2/11 / 2013 

## 10 : 32 : 00 13 .201 4 . 531 2/ 11 / 2013 

## 10 :33: 00 13.209 4 . 524 2/11/2013 

## 10 : 34:00 13.208 4 .523 2/11/2013 

## 10 : 35 : 00 13 .215 4 . 517 2/11/2013 

## 10 : 36 : 00 13 .21 4 . 52 2/11/2013 

## 10 : 37 : 00 13.207 4 . 521 2/11/2013 

## 10 : 38:00 13.203 4 . 526 2/11 / 2013 

## 10 :3 9:00 13207 4 . 524 2/11/2013 

## 10:40 : 00 13.197 4 . 528 2/ 11 /2 013 

## 10 :41 : 00 13 . 191 4 . 529 2/11/2013 

## 10 :42 : 00 13.192 4 . 53 2/11/2013 

## 10:44 : 00 13 .208 4 . 521 2/11/2013 

## 10 :45 : 00 13 . 193 4 . 531 2/11 / 2013 

## 10 :46 : 00 13 . 187 4 . 534 2/11/2013 

## 10 :47 : 00 13 . 194 4 . 529 2/11/2013 

## 10:48 : 00 13.197 4 . 528 2/11/2013 

## 10:49 : 00 13.199 4 . 525 2/11/2013 

## 10 : 50 : 00 13.196 4 . 529

### 2/ 11 / 2013 

## 10 : 51 : 00 13 .208 4 . 521 2/11 / 2013 

## 10 : 52 : 00 13 . 192 4 . 533 2/11/2013 

## 10 : 53 : 00 13 . 185 4 . 542 2/11/2013 

## 10:54:00 13.182 4 . 548 2/11/2013 

## 1055 : 00 13 . 179 4 . 549 2/11 / 2013 

## 10 :56 :00 13 . 177 4 . 551 2/11 / 2013 

## 10 : 57 :00 13 . 162 4 . 558 2/ 11 / 2013 

## 10 : 58 :00 13 . 171 4 . 554 2/1112013 

## 10 : 59 : 00 13.163 4 . 56 2/11 / 2013 

## 11 :00 : 00 13.162 4 . 561 2/11/2013 

## 11 :02 : 00 13 . 194 4 . 541 2/11 / 2013 

## 11 : 03 : 00 13 . 179 4 . 548 2/11 / 2013 

## 11 :04 : 00 13 . 175 4 . 548 2/11/2013 

## 11 : 05 : 00 13 . 178 4 . 547 2/11 / 2013 

## 11 :06 : 00 13 . 163 4 . 552 2/11/2013 

## 11 :07 : 00 13.166 4 . 55 2/11/2013 

## 11 :08 : 00 13.178 4 . 543 2/11/2013 

## 11 :09 : 00 13.164 4 . 551 2/11/2013 

## 11 : 10 : 00 13 . 172 4 . 546 2/11/2013 

## 11 : 11 : 00 13 . 173 4 . 544 2/11/2013 

## 11 : 12 : 00 13 . 179 4 . 538 2/11 / 2013 

## 11 : 13 : 00 13 . 166 4 . 548 2/ 11 / 2013 

## 11 : 14 : 00 13.171 4 . 541 2/11/2013 

## 11 : 15 : 00 13.152 4 . 55 2/11/2013 

## 11 : 16 : 00 13.166 4 . 541 2/11/2013 

## 11 : 17 : 00 13 . 164 4 . 543 2/11 / 2013 

## 11 : 18 : 00 13 . 169 4 . 54 2/11 / 2013 

## 11 : 19 : 00 13 . 172 4 . 54 2/11/2013 

## 11 :20 : 00 13 . 149 4 . 554 2/11/2013 

## 11:38 : 00 13 . 155 4.521 2/11/2013 

## 11 :39 : 00 13 . 141 4 . 537 2/11/2013 

## 11 :40 : 00 13 . 164 4 . 523 2/11 / 2013 

## 11 :41 : 00 13 . 163 4 . 523 2/11/2013 

## 11 :42 : 00 13 . 151 4 . 529 2/11/2013 

## 11 :43 :00 13 . 184 4 . 505 2/ 11/2013 

## 1144 : 00 13.202 4.494 2/11/2013 

## 1145 : 00 13 . 187 4.508 2/11/2013 

## 1146:00 13 . 188 4 . 505 2/11/2013 

## 11 :47 :00 13 . 16 4 . 526 2/ 11 / 2013 

## 11 :48:00 13 . 159 4 . 528 2/11/2013 

## 1149 : 00 13 . 16 4 .529 2/11/2013 

## 11 : 50 :00 13 . 173 4 . 519 2/11/2013 

## 11 :51 : 00 13 . 185 4 . 512 2/11 / 2013 

## 11 :52:00 13 . 153 4 . 536 2/11/2013 

## 11 :53:00 13.135 4 . 548 2/11/2013 

## 11 : 54:00 13 . 149 4.543 2/ 11/2013 

## 11 : 55 :00 13 . 111 4 .568 2/11 / 2013 

## 11 : 56 :00 13 . 124 4 . 56 2/11/2013 

## 11 : 57 :00 16 . 839 2.421 2/11 / 201 3 

## 11 : 58 :00 13 . 186 4 .525 2/11 / 2013 

## 11 :59:00 13 . 161 4 . 54 2/11/2013 

## 12 :0000 13 . 174 4 . 535

### 2 / 11/2013 

## 12 : 01 : 00 13 . 174 4 . 534 2/ 11/2013 

## 12 : 02 : 00 13 . 196 4 . 515 2/11/2013 

## 12 : 03 : 00 13 . 185 4 . 522 2/11/2013 

## 12 : 04 : 00 13 . 187 4 . 523 2

/ 11/2013 

## 12 : 05 : 00 13 . 172 4 . 537 2/11/2013 

## 12 : 06:00 13 . 177 4.534 2

/ 11 / 2013 

## 12 : 07:00 13 . 179 4.532 2/ 11 / 2013 

## 12:08:00 13 . 173 4.537 2/11/2013 

## 12 : 09:00 13 . 177 4.535 2/11/2013 

## 12 : 10:00 13 . 192 4.521 2/11/2013 

## 12 : 11:00 13 . 187 4.525 2/11/2013 

## 12:12 : 00 13 . 198 4 . 518 2/11/2013 

## 12 : 13 : 00 13 . 191 4 . 525 2/11 / 2013 

## 12 : 14 : 00 13 . 184 4 . 533 2/11 / 2013 

## 12 : 15 : 00 13 . 188 4 .528 2/11/2013 

## 12 : 16 : 00 13 . 184 4 . 529 2/11/2013 

## 12 : 18 : 00 13.212 4 . 512 2/11/2013 

## 12 : 19 : 00 13 . 187 4 . 524 2/11/2013 

## 12 :20 : 00 13 . 179 4 . 53 2/11 / 2013 

## 12 :21 : 00 13 . 174 4 . 533 2/11/2013 

## 12:22 : 00 13 . 162 4 . 54 2/ 11/2013 

## 12 :23 : 00 13 . 159 4 . 541 2/11/2013 

## 12 :24 : 00 13 . 156 4 . 543 2/11/2013 

## 12:25 : 00 13.155 4.544 2/11/2013 

## 12:26:00 13.157 4.542 2/11/2013 

## 12:27:00 13.156 4 . 542 2

/ 11/2013 

## 12:28 : 00 13 . 164 4 .537 2/11 / 2013 

## 12:29 : 00 13 . 178 4 . 528 2/11/2013 

## 12 : 30 :00 13 . 174 4 . 531 2/11/2013 

## 12 :3 1 :00 13 . 172 4 . 531 2/11 / 2013 

## 12 :3 2 : 00 13 . 168 4 . 534 2/11/2013 

## 12 : 33 :00 13 . 178 4 . 528 2/11/2013 

## 12 : 34 :00 13 . 174 4 . 531 2/11/2013 

## 12 : 35 :00 13 . 176 4 . 531 2/11/2013 

## 12 : 36 : 00 13 . 181 4 . 524 2/1112013 

## 1238 :00 13 . 191 4 . 514 2/11/2013 

## 12:39:00 13 . 173 4 . 527 2/11/2013 

## 12:40:00 13.176 4 . 527 2/11/2013 

## 12:41:00 13.169 4.531 2/11/2013 

## 12:42:00 13 . 165 4 . 533 2/11/2013 

## 12 :43:00 13 . 157 4 . 534 2/11 /2 013 

## 12 :44:00 13.164 4 . 527 2/11 / 2013 

## 12:45:00 13.145 4 . 536 2/11 / 2013 

## 12:46 : 00 13 . 134 4.538 2/11/2013 

## 12:47 : 00 13 . 143 4 . 531 2

/ 11/2013 

## 12:48 : 00 13 . 139 4 . 534 2/11 / 2013 

## 12 :49 : 00 13 . 13 4 . 54 2/11 / 2013 

## 12 : 50:00 13 . 119 4 . 547 2/11/2013 

## 12 : 51 :00 13 . 128 4 . 544 2/11/2013 

## 12 : 52:00 13.124 4 . 549 2/11/2013 

## 12 : 53:00 13 . 127 4 . 548 2/11/2013 

## 12 : 54:00 13.129 4.548

## 2/11/2013 

## 12:55:00 13.128 4.551

Average 

## 13.20 4.53

## Test 

## # : Date: Time : Load: CPV SENTINEL UNIT 4 PARTICULATE TEST STACK O 2 • 

## CO 2 

## DATA

S-4/STK-PM-75-1 2111/2013 

## 14:48 18:56 81 MW O 2 

## Range 20 Cal Gas 9
. 98 Analyzer Zero 0
. 10 Analyzer Span 10
. 04 Pre - Bias Zero 0.20 Pre - Bias Span 10
. 02 Post-B ias Zero 0
. 21 Post-Bias Span 10
. 03 Average Bias Zero 0.20 Average Bias Span 1002 Pre - test zero bias 0.5% Pre-test span bias -0
. 1 % Post-test zero bias 0
. 5% Post-test span bias -0
. 1% Zero Drift 0
. 0% Span Drift 0
. 0% CO 2 

## 10 4
. 96 0
. 01 5
. 11 0
. 06 5
. 11 0
. 09 5
. 13 0
. 08 5.12 0
.5 %

-0
. 1 % 0
. 8 % 0
.2% 0
. 3% 0
. 3% Test Results (from data logger average) Average 13.81 4
. 19 Cal Corrected 13.83 4.05

## O 2 

## CO 2 

## Date Time % 

## % 2/11/2013 14:49:00 13.822 4
. 157 

### 2/11/2013 14:5000 13
. 822 4
. 157 

### 2/11/2013 14 : 51 : 00 13
. 822 4
. 156 

### 2/11/2013 14 : 5200 13
. 821 4
. 158 

### 2/11/2013 14 : 53 : 00 13
. 803 4
. 168 

### 2/11/2013 14 : 5400 13
. 806 4
. 168 

### 2/11/2013 14 : 55 : 00 13.811 4
. 169 

### 2/11/2013 14:56:00 13.809 4
. 17 

### 2/11/2013 14:57:00 13.807 4
. 172 

### 2/11/2013 14 : 58:00 13
. 808 4
. 17 

### 2/ 11/2013 14 : 59 : 00 13
. 809 4
. 17 

### 2/ 11/2013 15 : 0000 13
. 819 4
. 166 

### 2/11/2013 15 : 01 :00 13
. 824 4
. 166 

### 2/11/2013 15 : 02 : 00 13
. 832 4
. 16 

### 2/11/2013 15 : 03 : 00 13
. 83 4
. 166 

### 2/11/2013 15 : 04 : 00 13
. 833 4
. 16 

### 2/11/2013 15 : 05:00 13
. 832 4
. 163 

### 2/11/2013 15 : 06 : 00 13
. 832 4.164 

### 2/11/2013 15 : 07 : 00 13
. 836 4
. 16 

### 2/11/2013 15 : 08 : 00 13
. 837 4
. 16 

### 2/11 / 2013 15 : 09 : 00 13
. 837 4
. 161 

### 2/11/2013 15 : 10:00 13
. 836 4
. 159 

### 2/11/2013 15 : 11:00 13
. 835 4.155 

### 2/11/2013 15 : 12 : 00 13
. 837 4.15 

### 2/ 11/2013 15 : 13 : 00 13
. 829 4
. 154 

### 2/ 11 / 2013 15 : 14 : 00 13
. 831 4
. 153 

### 2/11/2013 15 : 15 : 00 13
. 832 4
. 15 

### 2/ 11/2013 15 : 16 : 00 13.84 4
. 144 

### 2/ 11 / 2013 15 : 17 : 00 13.82 4.155 

### 2/11/2013 15 : 18 : 00 13
. 826 4.152 

### 2/11/2013 15:19 : 00 13.818 4.159 

### 2/11/2013 15:20:00 13
. 801 4
. 167 

### 2/11/2013 15:2100 13
. 798 4
. 166 

### 2/11/2013 15 : 22:00 13
. 806 4
. 165 

### 2/11/2013 15 : 23 : 00 13
. 795 4
. 167 

### 2/ 11/2013 15 : 24 : 00 13
. 79 4
. 169 

### 2/ 11/2013 15 : 25:00 13.802 4
. 165 

### 2/11/2013 15 : 26:00 13.803 4.167 

### 2/11/2013 15 : 2700 13
. 807 4
. 165 

### 2/ 11 / 2013 15 : 2800 13
. 817 4
. 16 

### 2/11 / 2013 15 : 29 : 00 13
. 8 4
. 169 

### 2/11 / 2013 15 : 30 : 00 13
. 806 4
. 166 

### 2/11/2013 15 : 31 : 00 13.806 4
. 162 

### 2/11/2013 15 : 3200 13
. 808 4
. 16 

### 2/11/2013 15 : 33:00 13
. 816 4.161 

### 2/11/2013 15 : 34:00 13
. 825 4
. 168 

### 2/11/2013 15 : 35 : 00 13
. 828 4
. 169 

### 2/11 / 2013 15 : 36:00 13
. 829 4
. 171 

### 2/11/2013 15 : 37 : 00 13
. 83 4
. 171 

### 2/ 11 /2 013 15 : 38 : 00 13
. 825 4
. 177 

### 2/11/2013 15 : 39:00 13
. 829 4
. 177 

### 2/11/2013 15:40 : 00 13
. 83 4
. 176

### 2 / 11 / 2013 15:41 : 00 13
. 823 4
. 179 

### 2

/ 11 / 2013 15 : 42 : 00 13
. 832 4
. 175 

### 2

/ 11 / 2013 15 : 43 : 00 13
. 833 4
. 176 

### 2/11/2013 15 :44 : 00 13
. 832 4
. 18 

### 2/1 1/2013 15:45 : 00 13
. 829 4
. 185 

### 2/11 / 2013 15 : 46 : 00 13
. 827 4.187 

### 2/11/2013 15:47 : 00 13
. 829 4
. 187 

### 2/11 / 2013 15 : 48:00 13.824 4
. 188 

### 2/11/2013 15 : 49:00 13.83 4
. 183 

### 2/11/2013 15:50:00 13
. 833 4
. 18 

### 2/11/2013 155100 13
. 824 4
. 187 

### 2/11/2013 15 : 52 : 00 13
. 829 4.186 

### 2/11/2013 15 : 53 : 00 13
. 821 4
. 191 

### 2/11/2013 15 : 54 : 00 13
. 817 4
. 196 

### 2/11 / 2013 15 : 55 : 00 13.81 4.202 

### 2/11 / 2013 15 : 56 : 00 13
. 804 4.208 

### 2/11 / 2013 15 : 57 : 00 13
. 772 4.225 

### 2/11 / 2013 15 : 58 : 00 13
. 773 4.226 

### 2/11/2013 15 : 59 : 00 13
. 776 4.228 

### 2/11 / 2013 16 : 00 : 00 13
. 774 4
. 227 

### 2/11 /2 013 16 : 03 : 00 13
. 832 4
. 193 

### 2/11/2013 16 : 04:00 13
. 831 4.2 

### 2/11/2013 16:05:00 13.832 4
. 196 

### 2/11/2013 16:06:00 13.834 4
. 192 

### 2/11/2013 16:07:00 13.833 4
. 194 

### 2/11/2013 16 : 08:00 13.831 4 .2 01 

### 2/11/2013 16 : 09:00 13
. 824 4.202 

### 2/11 / 2013 16 : 10 : 00 13
. 83 4
. 197 

### 2/11 / 2013 16 : 11 :00 13.827 4
. 193 

### 2

/11 / 2013 16 : 12 : 00 13
. 83 4
. 186 

### 2

/11 / 2013 16 : 13 : 00 13.818 4
. 191 

### 2/11 / 2013 16 : 14 : 00 13
. 805 4
. 197 

### 2

/11 / 2013 16 : 15 : 00 13
. 799 4 .2 01 

### 2/11/2013 16 : 16 : 00 13
. 802 4.201 

### 2/11/2013 16 :1 7 : 00 13
. 804 4
.201 

### 2/11 / 2013 16:18 : 00 13
. 806 4.202 

### 2/11/2013 16.21 : 00 13.823 4
. 192 

### 2/11/2013 16:22:00 13.814 4
. 195 

### 2/11/2013 16:23:00 13
. 811 4
. 198 

### 2/11/2013 16:24:00 13
. 817 4.196 

### 2/11/2013 16:25 : 00 13.819 4
. 195 

### 2/11 / 2013 16.26 : 00 13.835 4
. 188 

### 2/11 / 2013 16 : 27 : 00 13
. 832 4
. 187 

### 2/11/2013 16:28:00 13
. 831 4
. 19 

### 2/11 / 2013 16 : 29 : 00 13
. 829 4
. 194 

### 2/11/2013 16 : 30 : 00 13
. 831 4
. 192 

### 2

/11 / 2013 16 : 31 : 00 13
. 823 4
. 194 

### 2/11 / 2013 16 : 32 : 00 13
. 796 4.212 

### 2

/11 / 2013 16 : 33 : 00 13
. 797 4
. 21 

### 2/11/2013 16 : 34 : 00 13
. 807 4.207 

### 2/11/2013 16 : 35:00 13
. 819 4.2

### 2/11/2013 

## 16 : 38:00 13 . 839 4 . 183 2/11/2013 

## 16 : 3900 13 . 843 4 . 181 2/11/2013 

## 16 :40:00 13.831 4 . 19 2/11/2013 

## 16:4100 13 . 829 4 . 189 2/11/2013 

## 16:42:00 13.83 4 . 192 2/11/2013 

## 16 :43 : 00 13.825 4 . 193 2/11/2013 

## 16 :44:00 13.801 4 .207 2/11/2013 

## 16 :45 : 00 13 . 799 4 .21 2/11/2013 

## 16 :46:00 13.801 4 .21 2/11/2013 

## 16 :47:00 13.794 4 .215 2/11/2013 

## 16 :48:00 13.806 4 .209 2/11/2013 

## 16 :49:00 13.756 4 .236 2/11/2013 

## 16 : 50 :00 13.761 4 .236 2/11/2013 

## 16 : 5100 13.765 4.236 2/11/2013 

## 16:52:00 13.769 4.24 2/11/2013 

## 16 : 53:00 13.787 4 .231 2/11/2013 

## 16 : 5400 13 .797 4 .226 2/11/2013 

## 17:0900 13.844 4 . 168 2/11/2013 

## 17 : 10:00 13.798 4.187 2/11/2013 

## 17 : 11:00 13 . 79 4 . 192 2/11/2013 

## 17 : 12:00 13.789 4 . 193 2/11/2013 

## 17 : 13 :00 13.794 4.193 2/11/2013 

## 17 : 14:00 13.799 4.193 2/11/2013 

## 17 : 15 :00 13 . 802 4.191 2/11/2013 

## 17 : 16:00 13 . 81 4 . 189 2/11/2013 

## 17 : 17 :00 13.786 4 .201 2/11/2013 

## 17 : 18:00 13.783 4 .204 2/11/2013 

## 17 : 19:00 13.785 4.205 2/11/2013 

## 17:20:00 13.775 4.211 2/11/2013 

## 17 :21 :00 13.765 4.219 2/11/2013 

## 17 :22:00 13 . 74 4.23 2/11/2013 

## 17:23:00 13 . 753 4 .228 2/11/2013 

## 17:24 : 00 13 . 756 4 .225 2/11/2013 

## 1725:00 13 . 754 4 .226 2/11/2013 

## 1726:00 13 . 847 4.141 2/11/2013 

## 17:28 : 00 13 . 829 4.187 2/11/2013 

## 1729 : 00 13.803 4 . 204 2/11/2013 

## 17:30 : 00 13.804 4.205 2/11/2013 

## 1731 : 00 13 . 827 4 . 194 2/11/2013 

## 17:32 : 00 13.822 4 . 197 2/11/2013 

## 17:33 : 00 13 . 832 4 . 191 2/11/2013 

## 17:34 : 00 13.803 4 .211 2/11/2013 

## 17:35 : 00 13.799 4.21 2/11/2013 

## 17:36 :00 13 . 785 4 .218 2/11/2013 

## 17:37 : 00 13.788 4 .218 2/11/2013 

## 17:38 : 00 13778 4 .225 2/11/2013 

## 17:39 : 00 13773 4 .23 2/11/2013 

## 17:40 : 00 13 .747 4.245 2/11/2013 

## 17:41 : 00 13 .765 4.237 

# .• 2/11/2013 

## 17:42 : 00 13.755 4 .245 2/11/2013 

## 17:43 : 00 13.757 4.248

### 2/11 / 2013 17:46 : 00 13
. 821 4.204 

### 2/11/2013 17:47 : 00 13
. 825 4
. 201 

### 2/11/2013 17:48 : 00 13
. 822 4
. 198 

### 2/11/2013 17 : 49 : 00 13
. 817 4
. 199 

### 2/11/2013 17 : 50 : 00 13
. 808 4
. 197 

### 2/11/2013 17 : 51 :0 0 13
. 809 4.195 

### 2/11/2013 17 : 52 : 00 13
. 806 4.19 

### 2/11/2013 17 : 53:00 13
. 818 4
. 184 

### 2/11/2013 17 : 54 : 00 13
. 821 4
. 179 

### 2/11/2013 17 : 5500 13
. 814 4.185 

### 2/11/2013 17 : 56:00 13
. 814 4.186 

### 2/11/2013 17 : 57 : 00 13
. 804 4
. 194 

### 2/11/2013 17 : 58 : 00 13
. 793 4
.201 

### 2/11/2013 17 : 59 : 00 13.797 4 .2 01 

### 2/11 /2 013 18 : 00 : 00 13
. 805 4.193 

### 2/11/2013 18 : 01 : 00 13
. 805 4
. 193 

### 2/ 11/2013 18 : 04 : 00 13
. 821 4
. 18 

### 2/11/2013 18 : 05 : 00 13
. 806 4
. 187 

### 2/11 / 2013 18 : 06 : 00 13
. 805 4
. 189 

### 2/11 / 2013 1807:00 13.807 4
. 19 

### 2/11/2013 18 : 08:00 13.816 4
. 187 

### 2/11/2013 18 : 09 : 00 13.814 4
. 19 

### 2/11 / 2013 18:10:00 13
. 807 4
. 195 

### 2/11/2013 18 : 11:00 13.812 4
. 197 

### 2/11/2013 18:12:00 13.809 4
. 197 

### 2/11/2013 18:13:00 13.807 4
.201 

### 2/11/2013 18 : 14 : 00 13
. 812 4
. 199 

### 2/11/20 1 3 18 : 15:00 13
. 81 4
. 202 

### 2/11 / 2013 18 : 16 : 00 13
. 803 4
. 207 

### 2/11/2013 18 : 17 : 00 13
. 804 4.208 

### 2/11/2013 18 : 1800 13
. 808 4
. 21 

### 2/11 / 2013 18 : 19 : 00 13
. 81 4.212 

### 2/11 / 2013 18 : 39 : 00 13
. 788 4
. 174 

### 2/11/2013 18 :4 0 : 00 13
. 818 4
. 192 

### 2/11/2013 18:41 : 00 13
. 83 4
. 193 

### 2/ 11/2013 18:42 : 00 13
. 83 4
. 196 

### 2/11/2013 18 :43 : 00 13.831 4
. 198 

### 2/11/2013 18:44:00 13.827 4.201 

### 2/11/2013 18:45:00 13.823 4
. 204 

### 2/11 / 2013 18 : 4600 13
. 816 4
. 206 

### 2/11/2013 18:47 : 00 13.813 4.207 

### 2/11 /2 013 18:48 : 00 13.804 4
. 212 

### 2/11/2013 18:49:00 13.804 4
. 208 

### 2/11/2013 18 : 50 : 00 13
. 806 4.208 

### 2/ 11 /2 013 18 : 52 : 00 13
. 875 4
. 173 

### 2/11/2013 18 : 53 : 00 13
. 832 4
. 19 

### 2/ 11/2013 18 : 54:00 13
. 835 4
. 191 

### 2/11 / 2013 18 : 55 : 00 13
. 841 4
. 189 

### 2/11 / 2013 18 : 56 : 00 13
. 848 4
. 185

### Average 

## 13.81 4 . 19

### CPV SENTINEL UNIT 4 PARTICULATE TEST STACK O 2 • 

### CO 2 

### DATA Test 

## #: S-4/STK-PM-50-1 Date: 2112/2013 Time: 11:45 15:52 Load: 55MW O 2 

### CO 2 

### Range 20 10 

### Cal Gas 9.98 4.96 Analyzer Zero 0
. 10 0
. 10 Analyzer Span 10.05 5.20 Pre-Bias Zero 0.13 0
. 12 Pre-Bias Span 10
. 03 5
. 18 Post-Bias Zero 0.16 0.18 Post-Bias Span 10
. 02 5.23 Average Bias Zero 0.15 0.15 Average Bias Span 10.02 5.20 Pre-test zero bias 0
. 1% 0.3% Pre-test span bias -0.1% -0.2% Post-test zero bias 0
. 3% 0
. 9% Post-test span bias -0
. 1% 0
. 3% Zero Drift 0.2% 0.6% Span Drift 0.0% 0.5% 

### Test Results (from data logger average) Average 14.23 4.01 Ca I Corrected 14.23 3.79

### O 2 

### CO 2 

### Date Time 

## % % 2/12/2013 11 :46 : 00 14
. 268 3
. 977 

### 2/12/ 2013 11:47 : 00 14
. 285 3
. 977 

### 2/12/ 2013 11 :48 : 00 14
. 278 3
. 987 

### 2/12/ 2013 11 :49 : 00 14
. 268 3
. 991 

### 2/ 12/ 2013 11 : 50 : 00 14.265 3
. 997 

### 2/ 12/ 2013 11 : 51:00 14.255 3
. 999 

### 2/12/2013 11 : 52 : 00 14
. 244 3
. 996 

### 2/12/2013 11 : 53 : 00 14
. 257 3
. 994 

### 2/12/ 2013 11 : 54 : 00 14
. 275 3
. 997 

### 2/12/ 2013 11 : 55 : 00 14.27 3
. 999 

### 2/12/ 2013 11 : 56 : 00 14.266 4
. 001 

### 2/12/ 2013 11 : 57 : 00 14
. 267 4
. 002 

### 2/12/ 2013 11 : 58 : 00 14.27 4
. 001 

### 2/12/2013 11 : 59:00 14.269 4
. 003 

### 2/12/2013 12 : 00 : 00 14
. 268 4
. 002 

### 2/12/ 2013 12 : 01 : 00 14
. 27 4
. 001 

### 2

/ 12/ 2013 12 : 02 : 00 14
. 283 3
. 994 

### 2

/ 12/ 2013 12 : 03 : 00 14
. 279 3
. 998 

### 2/12/ 2013 12 : 04 : 00 14
. 277 4 

### 2/12/ 2013 12 : 05 : 00 14.242 4
. 017 

### 2/12/2013 12 : 06:00 14.263 4
. 005 

### 2/12/2013 12 : 07 : 00 14
. 263 4
. 007 

### 2

/ 12/ 2013 12 : 08 : 00 14.246 4
. 015 

### 2

/ 12/2013 12 : 09 : 00 14
. 241 4
. 021 

### 2/12/ 2013 12 : 10 : 00 14.204 4
. 047 

### 2/12/ 2013 12 : 11 : 00 14.204 4
. 048 

### 2/12/ 2013 12 : 12 : 00 14.204 4
. 05 

### 2/12/2013 12 : 13:00 14
. 198 4049 

### 2/12/2013 12 : 14 : 00 14
. 197 4
. 052 

### 2/12/ 2013 12 : 17 : 00 14
. 286 3
. 995 

### 2/12/2013 12 : 18 : 00 14
. 285 3
. 994 

### 2/12/ 2013 12 : 19 : 00 14
. 277 3
. 997 

### 2/12/ 2013 12 : 20 : 00 14.278 3
. 995 

### 2/12/2013 12 : 21 :00 14.268 3
. 999 

### 2/12/2013 12 : 22 : 00 14.274 3
. 996 

### 2/12/2013 12 : 23 : 00 14
. 271 3
. 996 

### 2/12/ 2013 12 : 24 : 00 14.266 3
. 994 

### 2/12/ 2013 12 : 25 : 00 14
. 265 3. 993 

### 2/12/ 2013 12 : 26 : 00 14
. 264 3
. 991 

### 2/12/ 2013 12 : 27 : 00 14
. 268 3
. 988 

### 2/12/ 2013 12 : 28 : 00 14
. 266 3
. 989 

### 2/12/2013 12 : 29 : 00 14
. 259 3
. 992 

### 2/12/2013 12 : 30 : 00 14
. 264 3
. 989 

### 2

/12/ 2013 12 : 31 : 00 14
. 261 3.99 

### 2/ 12/ 2013 12 : 32 : 00 14
. 262 3
. 989 

### 2

/ 12/2013 12 : 34 : 00 14.249 3
. 996 

### 2/12/ 2013 12 : 35 : 00 14
. 241 3
. 999 

### 2/12/2013 12 : 36 : 00 14.252 3
. 993

### 2/12/2013 

## 12 : 37:00 14 . 238 4 2/12/2013 

## 12 : 38:00 14 . 242 3 .999 2/12/2013 

## 12 : 39:00 14 . 251 3 .995 2/12/2013 

## 12 :40:00 14 .23 4 .007 2/12/2013 

## 12:41 : 00 14 . 207 4 .018 2/12/2013 

## 12 :42 : 00 14 .257 3 . 991 2/12/2013 

## 12 :43 : 00 14 . 259 3 .994 2/12/2013 

## 12 :44 : 00 14 . 255 3 . 995 2

/ 12/2013 

## 12:45 : 00 14 . 255 3 .996 2/12/2013 

## 12:46:00 14 . 191 4.035 2/12/2013 

## 12:47:00 14 . 176 4.041 2/12/2013 

## 12:48:00 14 . 18 4 . 04 2/12/2013 

## 12 :49 : 00 14 . 19 4.033 2/12/2013 

## 12 : 50 : 00 14 . 195 4 . 032 2/12/2013 

## 12 : 52 :00 14.308 3 .972 2/12/2013 

## 12 : 53:00 14.286 3.981 2/12/2013 

## 12 : 54:00 14.288 3.978 2/12/2013 

## 12 : 5500 14 .283 3.982 2/12/2013 

## 12 : 56:00 14 . 277 3.983 2/12/2013 

## 12 : 57:00 14 . 277 3 .984 2/12/2013 

## 12 : 58 :00 14 . 28 3 . 983 2/12/2013 

## 12 : 59 :00 14.286 3 .978 2

/ 12/2013 

## 13 : 00 :00 14.282 3 . 982 2/12/2013 

## 13 : 01 :00 14.279 3.983 2/12/2013 

## 13 : 02:00 14.279 3.983 2/12/2013 

## 13 : 03:00 14 . 264 3.992 2/ 12/2013 

## 13 : 04 : 00 14 . 262 3.991 2/12/2013 

## 13 : 05 : 00 14 .257 3 .995 2

/ 12/2013 

## 13 : 06 :00 14 . 259 3 .992 2/12/2013 

## 13 : 07:00 14.256 3.996 2/12/2013 

## 13 : 08 :00 14 . 25 3 .999 2/12/2013 

## 13 :28:00 14 . 133 3.95 2/12/2013 

## 13 :29 :00 14 . 218 3 .996 2

/ 12/2013 

## 13 : 30 :00 14 . 219 3 .997 2/12/2013 

## 13 : 31 :00 14 .213 3 .999 2/12/2013 

## 13 : 32 :00 14 .227 3 . 992 2/12/2013 

## 13 : 33:00 14.214 3 .997 2/12/2013 

## 13 : 34:00 14.208 4.001 2/12/2013 

## 13 : 35:00 14 . 221 3 .997 2/12/2013 

## 13 : 36:00 14 . 229 3.995 2/12/2013 

## 13 : 37 :00 14 . 201 4 . 016 2/12/2013 

## 13 : 38 : 00 14 . 205 4 . 01 2/12/2013 

## 13 : 39:00 14.203 4 .015 2/12/2013 

## 13:4000 14.202 4.016 2/12/2013 

## 13:41:00 14.203 4.018 2/12/2013 

## 13 :42:00 14.171 4.037 2/12/2013 

## 13 :43 : 00 14 . 162 4 .038 2/12/2013 

## 13:44 : 00 14 . 171 4 . 033 2/12/ 2013 

## 13:45 : 00 14 . 171 4 . 036 2/12/2 013 

## 13 :46 :00 14 . 168 4 .039 2/12/2013 

## 13:49:00 14.259 3.988

### 2 / 12/ 2013 

## 13 : 50 :00 14.25 3 . 995 2/12/ 2013 

## 13 : 51 :00 14.252 3 . 995 2

/ 12/2013 

## 13 : 52 : 00 14 .251 3 . 996 2/12/2013 

## 13 : 53:00 14 .239 4 . 003 2

/ 12/2013 

## 13 : 54 :00 14.25 3 . 999 2

/12/ 2013 

## 13 : 5500 14 .235 4 . 007 2

/ 12/ 2013 

## 13 : 56 : 00 14.232 4 . 008 2

/12/2013 

## 13 : 57 :00 14 . 232 4 . 009 2/12/ 2013 

## 13 : 58 : 00 14 . 228 4014 2

/ 12/2013 

## 13 :59 : 00 14 . 226 4016 2/12/2013 

## 14 : 00 : 00 14 . 233 4012 2/12/ 2013 

## 14 : 01 : 00 14 .231 4014 2/12/ 2013 

## 14 : 02 :00 14.224 4 . 018 2

/12/2013 

## 14 : 03 :00 14 .217 4 . 022 2/12/2013 

## 14 : 04 :00 14 . 212 4 . 025 2

/12/ 2013 

## 14 :06 : 00 14 . 302 4 .022 2/12/2013 

## 14 :07 : 00 14 . 203 4 .037 2/12/2013 

## 14 :08:00 14 .203 4 . 036 2/12/ 2013 

## 14 : 09 : 00 14 .2 4041 2/12/ 2013 

## 14 : 10 : 00 14.203 4 . 038 2

/12/2013 

## 14 : 11 : 00 14.203 4 . 041 2/12/ 2013 

## 14 : 12 : 00 14 .203 4042 2

/12/ 2013 

## 14 : 13 : 00 14 . 201 4045 2

/12/2013 

## 14 : 14 : 00 14 .203 4 .041 2/12/2013 

## 14:15 : 00 14 . 203 4 .041 2/12/2013 

## 14 : 16 : 00 14 .203 4 .045 2

/12/ 2013 

## 14 : 17 :00 14 . 197 4 .048 2

/12/ 2013 

## 14 : 18 : 00 14 . 2 4 . 049 2

/ 12/2013 

## 14 : 19 : 00 14.203 4 .047 2

/ 12/ 2013 

## 14 :20 : 00 14 . 203 4 .047 2/12/2013 

## 14:21 : 00 14 . 199 4 . 051 2/12/2013 

## 14:22 : 00 14 . 196 4.052 2

/12/2013 

## 14:25 : 00 14 . 226 4 .03 2/12/ 2013 

## 14 :26 : 00 14 . 227 4 .028 2

/12/ 2013 

## 14 :27 : 00 14 . 225 4 .031 2/12/ 2013 

## 14 :28 : 00 14 .224 4.035 2

/12/ 2013 

## 14 :29 : 00 14.216 4 . 035 2/12/2013 

## 14 :30 : 00 14 .224 4.032 2/12/2013 

## 14 :31 : 00 14 . 225 4.032 2

/ 12/2013 

## 14 : 32 : 00 14 . 232 4 . 028 2

/12/2013 

## 14 :33 : 00 14 . 237 4027 2/12/ 2013 

## 14 : 34 : 00 14 . 234 4 .029 2/12/ 2013 

## 14 : 35 : 00 14.229 4 . 032 2/12/ 2013 

## 14 : 36 : 00 14.225 4 . 033 2/12/2013 

## 14 : 3700 14 . 232 4 . 029 2/12/2013 

## 1438 : 00 14 . 234 4.027 2/12/ 2013 

## 14 : 39 : 00 14 . 236 4027 2/12/ 2013 

## 14 :40 : 00 14 . 233 4 . 028 2/12/ 2013 

## 15 :0100 14.257 4 . 007 2/12/ 2013 

## 15 :02 : 00 14.241 4 . 012 2/12/2013 

## 15 : 03 : 00 14 .24 4 . 017

### 2/12/2013 15 : 04:00 14
. 234 4
. 02 

### 2/12/2013 15:05:00 14
. 23 4
. 019 

### 2/12/2013 15:06:00 14
. 224 4
. 024 

### 2/12/2013 15 : 07 : 00 14
. 228 4
. 025 

### 2/12/2013 15 : 08 : 00 14.225 4
. 026 

### 2/12/2013 15:0900 14.223 4
. 027 

### 2/12/2013 151000 14.208 4
. 032 

### 2/12/2013 15:11:00 14.213 4
. 03 

### 2/12/2013 15:12:00 14.22 4.025 

### 2/12/2013 151300 14.212 4.028 

### 2/12/2013 15:14:00 14.222 4
. 028 

### 2/12/2013 15:15:00 14.225 4
. 026 

### 2/12/2013 15:16:00 14
. 23 4
. 023 

### 2/12/2013 15:17:00 14.229 4
. 026 

### 2/12/2013 15:1800 14.233 4
. 023 

### 2/12/2013 15:19:00 14.227 4
. 027 

### 2/12/2013 15 : 20 : 00 14
. 223 4
. 028 

### 2/12/2013 15:21 : 00 14
. 216 4
. 032 

### 2/12/2013 15 : 22 : 00 14
. 216 4
. 031 

### 2/12/2013 15 : 23 : 00 14.21 4
. 032 

### 2/12/2013 15 : 24:00 14
. 207 4
. 031 

### 2/12/2013 15:25 : 00 14.207 4
. 03 

### 2/12/2013 15 : 26:00 14.213 4
. 028 

### 2/12/2013 15:27:00 14.219 4.025 

### 2/12/2013 15:28:00 14.222 4
. 025 

### 2/12/2013 15:29:00 14.217 4
. 03 

### 2/12/2013 15:30:00 14.218 4
. 029 

### 2/12/2013 15:31 :00 14.221 4
. 027 

### 2/12/2013 15:32 : 00 14.229 4
. 024 

### 2/12/2013 15 : 33:00 14
. 225 4
. 026 

### 2/12/2013 15 : 34 : 00 14
. 225 4
. 026 

### 2/12/2013 15 : 35:00 14.23 4
. 025 

### 2/12/2013 15 : 36 : 00 14.229 4
. 024 

### 2/12/ 2013 15 : 37 : 00 14
. 217 4
. 031 

### 2/12/2013 15 : 38 : 00 14.218 4
. 033 

### 2/12/2013 15 : 39 : 00 14.238 4
. 023 

### 2/12/2013 15:40:00 14.237 4
. 023 

### 2/12/2013 15:41 : 00 14.24 4
. 022 

### 2/12/2013 15 : 42:00 14.237 4
. 025 

### 2/12/2013 15:43:00 14
. 224 4
. 028 

### 2/12/2013 15 : 44:00 14
. 232 4
. 025 

### 2/12/2013 15:45:00 14.236 4
. 022 

### 2/12/2013 15:46:00 14.232 4
. 026 

### 2/12/2013 15:47:00 14.23 4
. 027

# De//a!J.

...

# __ ...

# - WET CHEMICAL SAMPLING SYSTEM DATA AND WORKSHEET - STANDARD


# . , CLIENT : 

# c- G 1'4 I,-,t 

## I >' LOCATION :

### -;e\;'\:'i""C\.... DATE : 2. 

### 11- I'} 

### RUN NO : 

### 5- 1f611< - /'1>/

- I CC

- I 

### OPERATOR:**K/.\~ '**  

### 1 '1 METER BOX NO : / 

## 7

- '--' "':' METER

## ~H@:**~** 

# t METER Yd:

# 4~?- 1'2 

# htT f STACK AREA, FT : 

# J :5. / TRAVERSE POINTS , MIN!POINT : 

## if)/2 'f**H=** 

### ; , 

## I**X~P:** / 

### Probe Condition , pre l post test: . / Silica Gel Expanded, 

## Y I N:**~,** 

### Filter Condition after Test:

### ~ Check Weight: 

# 7 Meter Point 

## I Time 

## I Volume , ft 3 

## {; I> 

# I 

# c > /'

i:JfX161', 75( i /. I 

## IJ'bi; 1 

## 1 

## 77!5, 1:1 tfJ 

## £/ 

# I 0'lD 

## I 

# I 'l.r'i, 02. 

## v 

# :J I iJq I 

# r 1 7'1'2
. '1-">.2 

## ;2. l o qJ-1 1 /;101·8?O 

## / 10 

# '1 BI 1 <o1/0 . {J**~** 

## 5 

# (' / I IJ"N 

# I I <{,I</, 

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### L/ 

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## J 

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### <f u" 

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## 1:'j
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### in. H,O (
. -:L, 

# /. 

# " I· <'< 

## 2. . 

# ..1. 2.. 2. 

# --z , ,,",,, x. J. 

# . -.L 2. I 

# '1... 1 

# 1 2. '" 

# )- < I 

# , -.!L AMBIENT TEMPERATURE: 

### S 

## <'P BAROMETRIC

## PRESSURE**:-~:""' "'tj,-,** **.** 

# ,,''1r----

-- AS S UMED MOISTURE : '" 

## len PITOT TUBE COEFF , c - p:-"C fo=--'-o'=-".

## <'B~1""--**----**

# ~~g~~**:~~g~~TE ~~** **t** 

# R?c,+; 5) NOZZLE 

### 10 NO ! MATERIAL: 

## £d (!til')**~I** - S5 NOZZLE DIAMETER: 

## Q,2..:;'1 FILTER NOfTYPE :

### 'S~,- 11 G 

# '1 

# 'Sz::£L1I<:> PRE·TEST LEAK RATE: : 

### <0 

### ct 2- CFM@ 

### AU in. Hg
. POST·TEST LEAK RATE : : CFM@ 

### in
. Hg
. PITOT LEAK CHECK· PRE : 

## C-<'O tJ POST: --,-,__ _ CHAIN OF CUSTODY: SAMPLE CUSTODIAN 

## 4·,,-
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### in. H , O 

## I
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## 1 , 1 

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### Stack Temp, O F 

## 7& :; 

# 7c-.**~** 

# 7 tP 

## '7 

## 772., 

# '/

21 7 7 '--' 

# x

. "/C;-7



## 110 '/71 17 

## ';L 

# 17 .?- 17 ; SAMPLER 

# en SAMPLE

## C'""U~So;Ti;OD"'IC7A""N-**A"~ '-** 

Probe Te rllJ>., 0 

### F 

## AI ;.; 

# x )< 

# xx 

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### TerllJ>., 0 

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# L



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## ~ Imp
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## 51 S:2- 

### 5 

## c > 

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### ;><. 

### '5/ <:':; (";J



# "f'1**~'i7** 

### L('C

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# d0 Imp. 

### # Contents Posl·Test· Pre·Test 

### = Difference 

# ;**~'2~;L** 

# <.J3b,b,,;pg2- 

# ;( f!.A1V I';'-"/- 

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### Total :

___ _______ __ _ Meter Temp , O F In lOut 

## 5?:: 

## I <? ' 7 r :.2- l s'?**~.c;**

## . ., I**2** 

### o{, 

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### in. 

## ti9., 

## .3



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### Comments :

____________________________________________________________________________________________________________ ___

Date of last revision 

### 1/25/2013 Page

# ~ of ,;;.-- 

### DS834049 Ma 5 ter Document StoragelFormslDatasheets l Field Datashee ts

# Oe/1a1J.. ."Ouo ......**~** .... ... .. _ .. 

## WET CHEMICAL SAMPLING SYSTEM DATA AND WORKSHEET - STANDARD CLIENT: 

# C -S I/. / '/. 

# i.L-\
. LOCATION : 

# 'b7 k 

### i**~** 

### '- 1**&.~** 

### DATE: 

## ;:::L 2-

- 

## I""'> RUN NO : ';
. . 

## i;/ ,{tl{- 

# 6 '://1 ; , 9 / 11 

## 1 /\ OPERATOR: 

### )-;.-1 c, 

### METER BO X NO : I 

## 7 0:. (V,' 

## S METER 6 H@: /**~** 

## Iv METER Yd : 

# ,'-p- / (.; STACK AREA, 

### FT': TRAVERSF POINT"'S;- ,7



### M

"'1

N'"'

/;;; P:;;O"'I N:;;T"" : 

# '/'

-:;-'1

7

. ,,"

;; 

## -;;>7 6 H=

_'

_ . 

# _ 1
_ X 6 P : 7 

### Prob e Condition, pre/post tesl:
.____ _ Silica Gel E xpa nded, Y / N .: ______ _ Filter Condition after T esl:

_ ____ _ Check Weight..·

________ __ _ Meter 6 P Point 

### Time Volume, 

# fe in
. H 2 O

Average: AMBIENT TEMPERATURE :

# ~C- BAROMETRIC PRESSURE- : - 2. " "

",-:::

·1.,.;'1"'-- ---- ASSUMED MOISTURE: PITOT TUBE COEFF, C-p-:**-.f2.- ,-** **.,,-t::..=--------** 

### PROBE ID NO /M ATERIAL : 

# #;;;2, ?L/I:;-J**PROBELENGTH :·** **~~~ (#~** **r: z=70** **-~ ------**  NOZZLE ID NO/ MATERIAL:**~** 

## 1- 5:' NOZZLE DIAMETER: .."xO;>.. '**1.=,)",, .'-:.** **,** .,-

_ _ ______ _ 

### FILTER NOrTYPE : 

# 1:,;

- 11 \ (, PRE-TEST LEAK

## ~A"'**::':**-:

## -'.**.>' -'.** **,)":',,'".)-: ::** **"" C=CF=M7@=--** **-' ""'** **('~ '-i'-** **n-: .**  H 7 g

-.- POST-TEST LEAK RATE ,.., ,, ' 

## 1 {'2 CFM@ / ( in. Hg
. PITOT LEAK CHECK - PRE : ,/ POST : 

## v--- CHAIN OF CUSTODY: SAMPLE CUSTODIAN ->.. . 

### '

0.:"

'---
__ SAMPLER (,M

## SAMPLEC~U~S~T**~O~ IA** **M~C --**  6 H Stack Probe Filter Imp
. Out in
. H 2 O Temp , O F Temp , O F Temp , O F Temp , O F Imp. 

### # Contents Post-Test - Pre-Test = Difference

### O~ 

# !\ U

### Ib),**~** 

# b 

# <g.s-: So2 

# 01 \13,0 

# 13'l."i J33,.'1 

# l fAi 

# b)3,0 ('33, U**~** 

# sG, $3';,6 

# 13 "/, 0 

# ...!:: 'l- \) 

# I 

# B 1...0 lOO

Total:
_____________ _ Meter Temp, o f Vacuum 

### 0 2 P. static In Out in. Hg
. 

### % in
. H 2O

Comments :

_______________________________ ___________________________ _

Date of last revision 

### 1/ 25 /2 013

# Page**ofL** 05834049 Master Document 5torage l Forms l Datasheets l Fieid Datasheets

# 8811811 PARTICULATE SCAQMD 5.1, WET IMPINGEMENT
Project 

### # Client/Location**5I!.ni.\'n~(** 

### Sample Location 

## u/\; 

# f '{ Test 

### # S"!fitK.-ht/brr/ Item Number 1
. Glass Fiber Filter 

# 5S- (Backup Filter) 

# 11'{o 2
. Insoluble Solids Filter 

# 55'- 

# /fZ'! 3
. Impingers and Probe Catches 

# 11367- a . Water Fraction 

### b. Organic Extraction 

# /136(, 125 ml MeCI2 (5 x 25 ml)



# Dellaf'1

... ...-. ....- ,-.... 

### Date of last revision 11/13/08 Sample Date Water Blank 

### mgfml 

### (l,ooOO Analysis Date MeC" Blank 

### mgfml 0, "00 0 Analyst Initials Final Tare 

### Gain Aliquot Net Gain Weight Weight Weight 

### Correction (mgfSample)

(qj (qj (mol (mlfm/) 

### 0 · ((.20 

## 0.((,/5**o·~** 

# OS

------------- --- 

## 0 . / 5 

# 3">' 

# o./s3'( 01 0, 

# \

----------------

## ~'T.'P2)'i 

## :l'1.ro'f-

## /&~ 

# !tf2 f'Jo /&(,**~~,'2..nO** 

# f10 

# 0 , 0 '2..'U"" I. 

## D , c)

# ~6 Blank based on Total Volume (mql



## -----------------

----- --------- --



## Total Particulate = 

# 17. 'Z.. mg**--------------~~** 

## Method of Sample Prep/Notes

DS834012 Master Document StoragelFormslDatasheetslLab Forms

# 8011a/1 PARTICULATE SCAQMD 5.1, WET IMPINGEMENT
Project 

### # ClienVLocation 5
... 

# "t.'-_ ... ( Sample Location 

# Un:

# to 

# 'i Test 

### # 

## S"¥lSt/(.""', 75-1 

# , Item Number 1. 

### Glass Fiber Filter 

## SS-- (Backup Filter) 

## {1t ( 2
. 

### Insoluble Solids Filter**£~-** 

# 1"n.3 3. Impingers and Probe Catches 

# 1130::> a . Water Fraction b. Organic Extraction 

# /I 3 D 

# ,,! 125 

### ml MeCI2 (5 

### x 25 

### ml)



# Delfa l'1 

# "' - -,""-- Date of last revision 

## 11/13/08 Water Blank 

### mg/ml O.CQ01:> Sample Date Analysis Date Analyst Initials 

## :l/fl/13 MeCl , Blank 

### mg/ml 

### 12.00<>0 Final Tare Gain Aliquot Net Gain Blank based Weight Weight Weight Correction (mg/Sample) on Total

(g) (g) (mg) (ml/ml) Volume (mg) 

### O·IS<;.1 

## o./S':t( 

## o·D 

# 0·0

---------------- -----------------

### <J.15~1**D·/S~o** 

### 0.0



## ---------------- 

# 0.0 ------._--. _--- -- 

# ¥s;r b'l.)"I'Db 2'1.3<j</1. 

# 4.'-( 

# ..---- Ii

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# D·D is r ¥.5'8' O·c)

# ~'l.S'O'11**~ '1.~'IJ**  

## O·c.) 

# ......---- 00 &-Sf

Total Particulate 

## = __ 

# '-f

L 

## ·_L.. L 

# f
___ --'m:..;.9;L Method of Sample Prep/Notes

DS834012 Master Document StoragelFormslDatasheetslLab Forms

# Dclla~ PARTICULATE SCAQMD 5.1, WET IMPINGEMENT
Project 

### # ClienVLocation 

## S .. 

# "i: in**~(** 

### Sample Location 

## UII. i 

# e 'f Test 

### # 

### Sq,st!<. 

# I'll( So-I 

### Item Number 1. Glass Fiber Filter 

# 5S-- (Backup Filter)

## i1/~ 2
. Insoluble Solids Filter 

# SS"- 

# /f22. 3. Impingers and Probe Catches

## 1/3~3 a. Water Fraction b. Organic Extraction 

## /Ij(>l 125 ml MeCI2 (5 x 25 ml)



# De/tab.

...

# _ ........ .

# - ...... Date of last revision 11/13/08 

# 2/ 1 1/1.3 Water Blank mgfml ". 

## woO MeCl, Blank mgfml 0,0000 Sample Date Analysis Date Analyst Initials 

## 1./137/3
Final Tare Gain Aliquot Net Gain Blank based Weight Weight Weight 

### Correction (mgfSample) on Total

(g) (g) (mg) (mlfml) Volume (mg) O.((,'{V 

# O.,.r,y/**~** 

# I 

# f,'f- 0·0 0·0 ---------------- ----------------- 

## 0'/S50; 

## o./,sSS 0·0 ------------.--- 

## 0 , 0 -----------._---- 

# !!S-**~'Y,12.17 2<j.~lset**  

# £r S.S- 

# 0.0**:;').~**

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# 0·0 "12 ,;; O · c) 

# 0·0 

# ----.::**7-2~**



## Total Particulate = __ 

# 5_._g-_----'-m"'9OL. Method of Sample Prep/Notes

DS834012 Master Document StoragelFormslDatasheetslLab Forms

# Dclla~ PARTICULATE SCAQMD 5.1, WET IMPINGEMENT Project 

### # ClienULocation 

# Sczt) l,'ne! Sample Location 

# Und_ q Test 

### # 

# Frdd &I_I<. Item Number 1. Glass Fiber Filter 

# 5f>'- (Backup Filter)

### 17{~ 2. Insoluble Solids Filter**~S-_** 

# IlL/ 3. Impingers and Probe Catches 

# If3D I a. Water Fraction 

### b. Organic Extraction 

## 11300 125 ml MeCI2 (5 x 25 ml) 

## ClII{,-O 

## Il.Lo-.(..( 

# Illlt"**~<Z.** 

## C I 

## J.. 

# 61 "'"**(~** 

# (ll'7'1



# Deltal1 ..

# _ ......... ........... Date of last revision 

### 11/13/08 Water Blank mg/ml 6.0000 

### MeCl, Blank mg/ml 

### o· 00"0 

### Final Tare Gain

# W~tt**W~tt** Weight (mil) 

## o (&,/u 

# o·It-V3 0.0

O·/£S7..**O'/~3** 

## C).V

## ~ 

## Z1.352.1 

# 0.8'" Z''T,H'3S' 

# 2<t·>
. WI 2'i
. S320 6
. c)


# 2.'b 

# .lfl7 

# '1 1. 

# or. (/1 1 ,/ 

## 6·Q

## ~'l.%2S'**2.., ~,n**  

### D·c) Sample Date Analysis Date Analyst Initials Aliquot Net Gain 

# 2./ 11 

# /13 

# R? Blank based Correction 

### (mg/Sample) on Total

(mllml) Volume (mol

------------.--- 

## 00 -------.---------



## ------._.------- 

## 0 · 0

-----------------



# ff3 

# W 0·9- 0 · 0**~** 

# li'.J 0.0 0·0**~**



# '-/ ¥3 

# z.z.l.. 2]"t. 2:;;0



# ----- ZbO

Total Particulate 

## = 

# _---=o:... . ..:Y'---
___ ........:.m"'9"-- Method of Sample Prep/Notes



### DS834012 Master Document StoragelFormslDatasheetslLab Forms

## APPENDIX D GENERAL EMISSIONS CALCULATIONS

R041 0688 D-1

## GENERAL EMISSION CALCULATIONS 1) Stack Gas Velocity

2) 

## A. Stack gas molecular weight, Ib/lb-mole MW ", 

# = 0.44 * 

## %CO, + 

## 0.32 * 

## %0, + 

## 0 . 28 * 

## %N, MW 

# wet = MW

# dry * 

# (1-Bwo) + 

# 18 * 

# Bwo B
. Absolute stack pressure, iwg Ps 

## = Pbar 

## + Psg 

# 13.6 

# c. Stack gas velocity, ftlsec 

# V

s = 

# 2.9 * 

# C p 

## * ..)!1 P 

# *.JT: *
Moisture 

## A. Sample gas volume , dscf Vmstd 

## = 

# 0.03342 * 

# Vm * (Pb ", 

## + B
. Water vapor volume, scf 

# v = 

# 0.0472 * 

## V. * 

# T ref wstd Ie 

# 528 oR 29.92 * 

# 28.95 P

# s * MW

# wet

!1H ) 

## * 

# T,ef * 

# y 13.6 Tm d



# c. Moisture content, dimensionless 

# Bwn = 

# (V mstd + 

## V

# wstd ) 3) Stack gas volumetric flow rate A. Actual stack gas volumetric flow rate, wacfm Q 

# = v * A * 

# 60 s s 

## B
. Standard stack gas flow rate, dscfm



## R041 0688 0-2

## Q 

## = Q * (1-B ) * T ,.,

# *~ sd wo 

## T 2992 s . 

## 4) Gaseous Mass Emission Rates , Ib/hr M 

## = ppm * MW, * Q Sd 

## * 60 SV * 10 6 

## 5) 

## Em i ssion Rates, Ib/ MMBtu 

## Ib ppm * MW , * F * 20
. 9**~-=--=** 

## MMBtu SV*10 6 

## 20
. 9-%0 2 

## 6) Em i ssion Factor , Ib/ MMSCF 

## Ib Ib *HHV MMSCF MMBtu V I. Percent Isokinetic 17.3 2 x 

# T, (V " std ) 

# 52 80 R 

## 1= 

# , x (1

- Bwo) Ox V , x P s x Dn 

# T, ' ,j VII
. Particulate emissions a) Grain loadin9, 

## gr /

dscf C = 

## 0
. 01543 

## (M n Nm sid ) 

## b ) Grain loading at 12 % CO 2 , gr /dscf C ,2 % 

## C02 = 

## C (12 1% 

## CO 2 ) c) Grain loading at 3 % O2 , gr /dscf 

## C3 %02 

## = C' 17 . 9/ (20 . 9-%0 2 ) 

## d) Mass emissions , Ib/ hr M = 

## C x Qsd x (60 min/hr)/(7000 

## gr/lb) e) Particulate emission factor
6 

# lib 20..9 lb 1 10 Btu 

# = ex 7000gr x F x 

# 20.9
_ % 0 ,

R041 0 6 8 8 

## 0-3

## Nomenclature: 

## As 

# B

wo C '2%C02 

## C 3%02 

## C 

# C

p 

## On F H HHV 

## I 

## M

n M; MW M ",



# o**P** 

# P

b ar 

# Ps P Sg 

### Q Q ws 

# Q sd 

## 8V 

# T

m T ref 

## T s 

# V

s V ic 

# V

m V mst d 

## VwStd 

# Y

d



### R041 06 8 8 

## = stack area , ff 

## = flue gas moisture content , dimensionless 

## = part i culate grain loading, gr/dscf corrected to 1 2 % CO 2 

## = particulate grain loading , gr/dscf corrected to 3 % CO 2 

## = part i culate grain loading , gr /dscf 

## = pitot calibration factor , dimensionless 

## = nozzle diameter , in. 

## = fuel F - Factor, dscf/MMBtu 

## @ 0% O 2 

## = orifice differential pressure , iwg 

## = fuel higher heating value, Btu / 8CF 

## = 

## % isokinetics 

## = mass of collected particulate , mg 

## = mass emission rate of specie i , Ib/ hr 

## = molecular weight of flue gas, Ib/lb-mole 

## = molecular weight of specie i : 

## 80 2 : 

## 64 NO x : 

## 46 CO : 

## 28 HC : 

## 16 = sample time, min
. 

## = average velocity head , iwg 

## = ( ..,Jt;P ) ' 

## = barometric pressure , inches Hg 

## = stack absolute pressure , inches Hg 

## = stack static pressure , iwb 

## = wet stack flow rate at actual conditions , wacfm 

## = wet stack flow at standard conditions , wscfm 

## = dry standard stack flow rate , dscfm 

## =**s~ecific** 

## molar volume of an ideal gas at standard conditions,

ft lib-mole 

## = meter temperature , 

## O R = reference temperature , 

## O R = stack temperature , 

## O R = stack gas velocity, fUsec 

## = volume of liquid collected i n impingers, ml 

## = uncorrected dry meter volume , dcf 

## = dry meter volume at standard conditions, dscf 

## = volume of water vapor at standard conditions , scf 

## = meter calibration coefficient

D-4

## APPENDIX E CHAIN OF CUSTODY

R041 0688 E-1CHAIN OF CUSTODY CLIENT : Sentinel TEST DATE(S ) : 2111/ 2013 2112/2013 LOCATION : 4 SAMPLER(S) : "S"-S
___________ _ SAMPLE LOCATION : Stk PROJECT MANAGER : TEST METHOD (S) : SCAQMD 207
. 1 DATE DUE : OUTSIDE LAB REQUIRED? : No COMPLIANCE TEST? 

### 15m 

## ti'2i2ir

__**Rea9e:r~t** 

### lot 

### #'s : 1**~** S4f Stk·1 S4/Stk-1 S4-,-Stk· ;-2 B Blan k**~** 

## 3110020 

# xt ) 207. ) 207 . 

## i20f



## -.l _be , l ine , _be. line, .be, line, .be. line, Probe , line Probe , line, ) , 1 N H2SO4 

### BF 212012013 Yes



## m:;47 

# ? Z 13-\3 

## 10:1£ 

# U2':f;tDck'!::: 2/6,h:3

## (~:("zJ**~SED** BY
.. ---- DATEITIME 

# I RECENED BY DATEITIME 

## I
__ I

# ACHAIN OF CUSTODY CLIENT : Sentine l TEST DATE(S): 2/11/2013 2/1212013 LOCATION : 4 SAMPLER(S) : .!;R"'M'--
__________ _ SAMPLE LOCATION : Stk PROJECT MANAGER: TEST METHOD (S) : SCAQMD 5
. 1 DATE DUE : OUTSIDE LAB REQUIRED? : No COMPLIANCE TEST? .,...It: 

## '1i201**1~~~1**

Water 

### 13 

## iMc CA< Prot 

### Prot .ine, ""t' " ., Filter

line , I mp . , Fille Une , -Imp.

___ Imp . 5 . 1 Filter Blan k 

## I!.ll'I """Dii 

### BF 2120 / 2013 Yes

rWater-



# ??Ql 

# z;e 2._r:

# i 

# lrIME (0-1$ 

# I

# f?8iC p?B! - 

# I z-t 3

# °tT 1 

# :1

- ts:**A**

# ,4,4c;lj**/30/~O** CHAIN OF CUSTODY '<t" CUENT : Sentinel TEST DATE(S) : 2111/2013 211212013 

# ., 4 SAMPLER(S) : RM

## ~ tl.. LOCATION : SAMPLE LOCATION : SII< PROJECT MANAGER : TEST METHOD(S) : SCAQMD 25.3 DATE DUE : OUTSIDE LAB REQUIRED? : Yes**~** 

## ? 

## J?4- 21111201 

## 98'> 21111201**'11?~** 2111/2013 "'" 

### '187 2111/2013 54" 

### "8'1'? 211212013 54/1 7 211212013 84/:



# !tom**~,** 

## ;:;**~** Canister : Canister: 

### Canister: Canister



## -CaillSi8r"' Canister

### ~ ULL COMPLIANCE TEST? 

### BF 212012013 Yes



# F

U

--- -- RELEASED BY - 

# I I DATE/TIME RECElVED'BY' - 

# -T -llATClTlME 

# 1t£JO**/~** 

### z-fr3It3. 

## tCqJ 

# _>2 5)711.11 

# '5 ( 0 3c)

### ~**~** ? 

# ,#,/.2//3 . 

# I;**~** 

# "" , - -?""**~J)j** 

# It::r r.no r ; Note : 

### Canister**~03** 

### and #000411 were 

### Voided tes1$, 

## Please dOnof

## analYze. 

# :MFACl1ENT : CHAIN OF CUSTOOY

### ~ 

# I SenHnel TEST OATE(S) : 

# t 

# 7. 

# 21 

# 3
_ 4 SAMPLER(SG

# ~.iLOCATION : SAMPLE LOCATION: ___________________________________ PROJECT MANAGER: BF TEST METHOO (S) : Fixed Ga s es ASTM 0194511946 DATE DUE : 

# A'5:ItP HH V ASTM D3588 Sulfur ASTM D5504/ SCAQ MD METHOD 307 - 91 OUTSIDE LAB REQUIRED ?: Yes COMPLIANCE TEST? Yes I**~ATE** TIME TE T# Method SAMPLE DE CRIPTION CONTAINERS SAMPLER COMMENTS S4/- Fuel Surfur--1A See Above Tedlar Ba 1 M 'l I 

### II S4/-Fuel S ulfur 18 See Above red lar Sa 1 M 

### \. 

# • S4/- Fuel Su lfur -- 1C See Ab ove red lar 8a 1 M 

### , II 

### I

Total Samples 3 Rea ent 

### 1 ,r, Rea gent Lot #'s : 

### I RELE Y DATEfTlME 

### ,/7 jil£CEIVEO BY / oATEmM, 

### '7 '0_ 

### Y A-o./ 

# , 7--1 

### :2-2- / 

### -7 '-" 

# " I' ( 

### / y 

# " -r / 

### r71 7 

# , 

# -- /



### - or- I



# - 

# Rf/IIA

## APPENDIX F INSTRUMENT STRIP CHARTS

R041 0688 

### F-1

## APPENDIX G FACILITY PERMIT TO OPERATE CONDITION 029.1

R041 0688 G-1

### SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley 

## Drive, Diamond Bar, CA 91765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Facility ID: Revision II: Page: 35 152707 

## o Date: April 15, 20t 1



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: The operator shall also install and maintain a device to continuously record the parameter being measured The measuring device or gauge shall be accurate to within plus or minus 5 percent. It shall be calibrated once every twelve months It shall be calibrated once every twelve months The pressure drop across the catalyst shall not exceed 12 inches water column [RULE 1303(a)(I)-BACT, 5-10-1996; RULE 1303(a)(I)-BACT, 12-6-2002; RULE 1703(a)(2)

- PSD-BACT, 10-7-1988; RULE 2005, 5-6-2005) [Devices subject to this condition: C4, CIO, C16, C22, C28, C34, C40, C46) D12.5 The operator shall install and maintain a(n) non-resettable elapsed time meter to accurately indicate the elapsed operating time from the engine. [RULE 

## J 110.2, 2-1-2008; RULE 1303(b)(2)-Offset, 5-10-1996; RULE 1303(b)(2) -Offset, 12-6-2002; RULE 1470, 6-1-2007; RULE 2012, 5-6-2005) [Devices subject to 

## this condition: 049) D29.1 The operator shall conduct source testes) for the pollutant(s) identified below. Pollutant(s) to Required Test Method(s) Averaging Time 

# I Test Location be tested NOX emissions District method 100.1 1 hour Outlet of the SCR serving this equipment CO emissions 

# I District method 100.1 1 hour 

# IOutlet of the SCR serving this equipment SOX emissions 

# I AQMD Laboratory Method 307-91 Not Applicable 

# I Fuel sample VOC emissions 

# I District Method 25.3 I hour 

# IOutlet of the SCR serving this equipment

## SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91 765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Page: 36 Facility 10 : 152707 

### Revision # ; 

### 0 Date : April 1.5,2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: PMIO emissions NID 

## emissions District Method 

## 5 District method 

## 207 . 1 and 

## 5.3 or EPA method 

## 17 4 hours 1 

## hour 

# I Outlet of the 

## SCR serving this equipment 

# I

Outlet of the 

## SCR serving this equipment

### SOlITH COAST AIR QUALrIY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91765 

# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Seo;tiorl H Page:: 31 Facility 10: 152107 Revision II: 0 Date: April IS, 2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE Tbe operator sball comply witb tbe terms and conditions set fortb below: The test shaH be conducted after AQMD approval of the source test protocol, but no later the later of 180 days after initial start-up or three hundred hours of operations after start-up. The AQMD shaH be notified of the date and time of the test at least 10 days prior to the test The test shaH be conducted to detennine the oxygen levels in the exhaust. In addition, the tests shaH measure the fuel flow rate (CFH), the flue gas flow rate, and the turbine generating output in MW. The test shaH be conducted in accordance with AQMD approved test protocol. The protocol shall be submitted to the AQMD engineer no later than 45 days before the proposed test date and shaH be approved by the AQMD before the test commences. 

## The test protocol shall include the proposed operating conditions of the turbine during the tests, the identity of the testing lab, a statement from the testing lab certifYing that it meets the criteria of Rule 304, and a description of all sampling and analytical procedures The test shall be conducted when this equipment is operating at maximum, average, and minimum loads
. For natural gas fired turbines only, VOC compliance shall be demonstrated as follows: a) Stack gas samples are extracted into Summa canisters maintaining a final canister pressure between 400-500 mm Hg absolute, b) Pressurization of canisters are done with zero gas analyzed/certified to contain less than 0.05 ppmv total hydrocarbon as carbon, and c) Analysis of canisters are per EPA Method TO-l2 (with pre concentration) and temperature of canisters when extracting samples for analysis is not below 70 deg F. The test shaH be conducted for compliance verification of the BACT VOC 2.0 ppmv limit. The test results shaH be 

## reported with two significant digits., ._. .... 

## '

- SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive. Diamond Bar. CA 91765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Facility ID : 

### Revision N; 

### Dale : Page : 38 152707 

## o Apri l 15,2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: [RULE 1303(a)(I).BACT, 5-10-1996; RULE 1303(aXI)-BACT, 12·6-2002; RULE 1303(b)(2)·Offset, 5.10·1996; RULE 1303(b)(2)-Offset, 12-6-2002; RULE 1703(a)(2). PSD-BACT, 10·7·1988; RULE 2005, 5·6-2005] [Devices subjectto this condition: DI, D7, DI3, DI9, D25, D31, 037, D43] D29.2 The operator shall conduct source test(s) for the pollutant(s) identified be low. Pollutant(s) to be tested NH3 emissions Required Test Method(s) District method 207.1 and 5.3 or EPA method 17 Averaging Time I hour 

# I Test Location 

# I

Outlet ofthe SCR serving this equipment The test shall be conducted and the results submitted to the District within 45 days after the test date. The AQMD shall be notified of the date and time of the test at least 7 days prior to the test. The test shall be conducted at least quarterly during the first twe lve months of operation and at least annually thereafter
. The NOx concentration, as determined by the CEMS, shall be simultaneousl y recorded during the ammonia slip test. 

## If the CEMS is inoperable, a test shall be conducted to determine the NOx emissions using District Method 100.1 measured over a 60 minute averaging time period. If the turbine is not in operation during one quarter, then no testing is required during that quarter The test shall be conducted to demonstrate compliance with the Rule 1303 BACT concentration limit [RULE 1303(a)(I)-BACT, 5-10

- 1996; RULE J303(aXI)-BACT, 12-6 · 2002] [Devices subject to this condition: 01, 07, 013, 019, D25, D31, 037, D43J

## APPENDIX H CORRESPONDENCE AND TEST PLAN

R041 0688 

### H-1

## Bob: Here is an answer to one of the issues for the 

# crv Sentinel testing. From: Carey Willoughby [mailto:CWilioughby@aqmd
. gov] 

## Sent: Wednesday, January 09, 2013 10:09 AM 

## To: Tom W. Andrews 

## Subject: RE: CPV Sentinel VOC Tests 

## Mr. Andrews, Simultaneous duplicate sampling (six canister samples vs. nine sample canisters) for VOC is acceptable to the SCAQMD. Sincerely, 

# Carey 1ViCCoUfJfiby**~ir** 

# Q.uaCity 'E1lIJineer II**SC~:MD** 

## 21865 CoyCey 

## Drive 

# Diamond 'Bar,**C~** 

## 91765 

# Tel: (909) 396-3006 

# :Fax: (909) 396-2099 

# cwiflOuefiEy@aqnu£.[JOV

From: Tom W. Andrews [mailto:TAndrews@sierraresearch.com] 

## Sent: Wednesday, January 09, 2013 9 : 39 AM 

## To: Carey Willoughby 

## Cc: W. Andrews, Tom 

## Subject: CPV Sentinel VOC Tests 

## Carey: Per our telecon this morning, for the VOC tests the test team would like to take duplicate simultaneous samples rather than triplicate samples in series at each of the three gas turbine loads. In other words a total of six canister samples vs. nine canister samples
. Could you please confirm this is acceptable to the SCAQMD. Thanks
. Tom Andrews

1801 

# J Street Sacramento, CA 95811 (916) 273-5139 

## (direct/voice) (916) 444-8373 

## ifax)

# SOURCE TEST PROTOCOL FOR INITIAL COMPLIANCE TESTING AT CPV SENTINEL ENERGY PROJECT UNITS 1 - 8
PREPARED FOR: GEMMA POWER SYSTEMS CALIFORNIA, INC. 2461 MAIN STREET GLASTONBURY, CONNECTICUT 06033 FOR SUBMITTAL TO: SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 COPLEY DRIVE DIAMOND BAR, CALIFORNIA 91765-4178 PREPARED BY: DELTA AIR QUALITY SERVICES, INC. 1845 N. CASE ST. ORANGE, CALIFORNIA 92865 714-279-6777 ROBERT 

# A. FINKEN DECEMBER 7,2012 DOCUMENT NUMBER: R0210458-R1

Air Quality Services, Incorporated

## CONFIDENTIALITY STATEMENT

This information contained in this communication is intended exclusively for the individual or entity 

# to which it is addressed. This communication may contain information that is proprietary, privileged or confidential or otherwise legally exempt from disclosure. If

## you are not the named addressee, you are not authorized to read, print, retain, copy, or disseminate this message or any part of it.

R021 0458·R 1 

## ii

## CONTENTS SECTION 1.0 I NTRODUCTION
....................... .. ................................. .... .... . ............................. . ..... 1 2
. 0 UNIT DESCRIPTION AND TEST CONDITIONS
................. .............. ................. .. .... 2 2
. 1 UNIT DESCRIPTION
..... .. ..... ........ ..... . ............................ .... .. .. ............. . ... .. ...... .. 2 2.2 TEST CONDITIONS
................................... . ........ . .... .. .... . ......................... . ........ 4 2
. 3 SAMPLE LOCATION ...... .. . ............ ...... ...... . .......... .. ......... .. ...... . .... . .................... 

# 5 3
. 0 TEST DESCRiPTION ..... .... ... ........................................................................... ...... .. 

## 7 3 .1 O 2 , 

## CO 2 , 

## NO

# x AND CO
....................... ............ .. ...... . ..... ............... ...... ............ .. .. 8 3
.2 

# NH3 8Y SCAQMD METHOD 207.1
. ........ .. .... ............. ..... ................. . ................. 9 3
. 3 SOx 8Y SCAQMD METHOD 307
. 91
........................ . ... ...................................... 9 3
.4 ROG 8Y MODIFIED SCAQMD METHOD 25
. 3
.................................................. 9 3
. 5 PM 8Y SCAQMD METHOD 5.1
....................................................................... 13 4.0 REPORTING
..................... . .... ............. ...... .. ......... ... . .............................. . .. .... .. ... ... . 15 APPENDICES A QUALITY ASSURANCE
......... .. .... .. .. ............. . ....... .. .... . .........................................A - 1 B TEST METHODS
.......... ............ ..... ...... .... .. .......... .... ............... .......... ............... .... .. 

## 8-1 

## C CALCULATIONS
............ ............................. ............. ..................... .. ..................... 

## C -1 

## D FORMS
.................................... .............. ................................ .. .. .. .. . ....... ............... D - 1 E FAC ILI TY PERMIT TO OPERATE CONDITION D29.1
........................... . .............. E-1

R0210458-R1 iii 

# JleltaIJ. 

# '"'---

# 1.0 INTRODUCTION Delta Air Quality Services, Inc. has been contracted by Gemma Power Systems California, Inc. (GEMMA) to perform the initial Permit to Operate Compliance Testing at the CPV Sentinel Energy Project Units 1, 2, 3, 4, 5, 6, 7, and 8
. Condition 029.1 of the Permit to Operate requires source tests within 180 days of initial startup
. This document will serve as the test plan for the aforementioned tests. Tests 

## will be performed at three load conditions to determine oxides of nitrogen (NOx ) , carbon monoxide (CO), oxides of sulfur (SOx), reactive organic gases (ROG ' s), particulate matter (PM) , and ammonia (NH3) emissions
. Bob Finken will be the Senior Program Manager for Delta and can be reached at (714) 279-6777. No conflict of interest, as defined in SCAQMD Rule 304, exists between Gemma or CPV Sentinel Energy Project and Delta
. Section 2.0 of this document provides a description of the facilities and sample locations. A description of the sampling strategy and test methods is provided in Section 3
. 0. Section 4.0 outlines the final source test report format. A more detailed description of the test methods, calculations, and quality assurance procedures is provided in the Appendices.

R0210458-R1 1

# 2.0 UNIT DESCRIPTION AND TEST CONDITIONS


# 2.1 UNIT DESCRIPTION 

## CPV Sentinel Energy Project is located at 62575 Powerline Road, Desert Hot Springs, California 92240. The facility consists of eight (8) identical generating units. The CPV Sentinel Energy Project consists of eight (8) LMS100PA combustion turbines in simple cycle operation. The units are natural gas fired with a rated heat input of 891.7 MMBtu per hour at 72 degrees Fahrenheit. Each LMS100PA employs water injection and is equipped with a CO catalyst and Selective CatalytiC Reduction (SCR) system for NO x 

## control. The LMS100PA is a General Electric (GE) combustion turbine with an intercooler located between the low pressure compressor (LPC) and high pressure compressor (HPC). Off engine combustion air to closed loop water intercooling is used for increased gas turbine thermal efficiency. Heat removed from the off-engine intercooler is circulated through a closed loop cooling system. Heat is rejected from the closed loop cooling system to an open loop cooling system via plate and frame heat exchangers. The open loop system rejects heat via a mechanical draft counterflow cooling tower. The cooling tower is provided with drift elimination to comply with air emissions limits. Figure 2-1 presents a block diagram of the units. Figure 2-2 shows a general arrangement of the major components.

R0210458-R1 

## 2 

# JJeII8!1 

# "'---

## FIGURE 

## 2-1 SIMPLIFIED PROCESS BLOCK DIAGRAM CPV SENTINEL ENERGY PROJECT COMBUSTION TURBINES

Simplified Process 

## Flow Diagram


## Air Water Cooling Tower Air Water Heat

Closed Loop Exhaust to Atm
. Cooling

Air LMS100PA Exhaust CO Catalyst SCR 

## IWater Ammonia Natural Gas Fuel Demineralized 19% Aqueous

R0210458-R1 

## 3

## FIGURE 

# 2·2 GENERAL ARRANGEMENT OF MAJOR COMPONEN T S



# -_ . . . . .... .. ... . ..... . . . .. - . . -- " "--

_ l!==\=H=='l
._ .. . . _ .... .. _ . .. .. ..... -

\ I 

# ./

"''1t'''1'>4 r .t<ll<· ; · t**.~** ("""' :



### v



# 2 . 2 T EST CONDITIONS 

## The permit requires that the tests will be performed at three operating conditions; 1) maximum, 2) average , and 3) minimum load
. Full load is nominally 1 00 megawatts and minimum load will be approximately 50 megawatts. Since these will be the i nitial tests for the units and no long term average will have been established, average conditions will be approximated at 75% of capacity or approximately 75 megawatts.

R021 0458-R 1 

## 4

## Uni t operating data will be gathered during the tests by t he facility from the CEMS DAS
. These data will include , at a minimum : • Fuel flow rate • Turbine generating output (MW) • Ammonia Flow • Exhaust Temperatures • Exhaust Flow Rates 2. 3 SAMPLE LOCATI ON There are four 6" test ports located at 90 degrees apart around the circumference of the 13'6" diameter stacks
. The ports are located 323" downstream (2.0 diameters) of the nearest flow disturbance (duct breeching) 84" upstream (0
. 5 diameters) of the nearest flow disturbance (silencers). The sampling location meets the min i mum requirements of SCAQMD Method 2.1, being >2 diameters downstream and >0.5 diameters upstream of the nearest flow disturbances. Figure 2 -3 presents the details of the sample location
. FIGURE 2 -3 SA M P L E LOCATIO N D ETA I LS

Inside Diameter , in,



### - 1 62 

## +- Stack Exit 

### 1080 .0 i n . 

### Silencer Bottom 925
. 9 in
. 

### Ports 841 . 6 in
. Platform 789
.6 i n .

Base 01 Stack 

### 518 . 5 i n .


### Grade 0
. 0 i n .



## R021 0458-R 1 

# T 84 

### Di stance A , Inches
. 0
.5 Diameters 

# ! Sample ports 

# T
323 Di stance 

## e, i nches , 2
. 0 Diameters

__**E:::;xh:::.ust** Flow 

# .'

Elevation View



## 5 90 fl ,



### 66 It.



# o It.



# /Ie /

II/). 

# "'--
. -

### Sample Point

2 3 4 5 6 7 8 9 10 11 

## Prior to performing the tests, gaseous stratification will be investigated with a 12 pOint traverse as described in 40 CFR 

# 75, and the presence of cyclonic flow will be checked using the techniques described in SCAQMD Method 2. If stratification is less than 10% or less than 1 ppm, all future gaseous concentration measurements will be made from a single point. If stratification is greater than 10% and greater than 1 ppm, all future concentration measurements will be performed using a multi-point traverse (3-point short line, 3-point long line , or 12-points (using 40 CFR Part 

# 75 criteria». A 16-point cyclonic flow traverse will be performed with an S-type pitot tube
. If the average yaw angle is less than 10 degrees , the location will be deemed acceptable for Method 2.1 velocity measurements. Table 2-1 illustrates the location of sample traverse pOints
. TABLE 2-1 SAMPLE POINT LAYOUT
PM (24 pts.) Flow Disturbance (16 pts
. ) Strat.lNH3 (12 Pts
.) 3 pI. Long Line CEMS 3 pI. Short Line CEMS % of in
. 

### % of in
. 

### %of 

### in
. %of in. 

### % of Diameter from Wall Diameter 

### framWall Diameter 

### framWeli Diameter 

### framWall Diameter

2.1 3.4 3.2 5
. 2 4
.4 7
. 1 16
. 7 27
. 1 N/A 6
. 7 10
. 9 10
. 5 17
. 0 14
. 6 23
. 7 50 81
. 0 N/A 11.8 19
. 1 19.4 31.4 29
. 6 48
. 0 17
. 7 28
. 7 32
. 3 52
. 3 70.4 114
. 0 25 40.5 67.7 109.7 35
. 6 57.7 80
. 6 130.6 64
. 4 104
. 3 89
. 5 145
. 0 75 121
. 5 82
. 3 133.3 86.4 140
. 0 93
. 3 151
. 1



## Prior to performing the tests, gaseous stratification will be investigated with a 12 point traverse as described in 40 CFR 

# 75, and the presence of cyclonic flow will be checked using the techniques described in SCAQMD Method 2.1. If stratification is less than 10% or less than 1 ppm, all future gaseous concentration measurements will be made from a single point. If stratification is greater than 10% and greater than 1 ppm, all future concentration measurements will 

# be performed using a multi-point traverse (3-point short line, 3-point long line, or 12-points (using 40 CFR Part 

# 75 criteria». A 16-point cyclonic flow traverse will be performed with an S-type pitot tube. If the average yaw angle is less than 10 degrees, the location will be deemed acceptable for Method 2
. 1 velocity measurements
. R0210456-R1 6 

# /lelia/.). "" 

# .....

# _- i n . (ram Wall 15
. 7 47
. 2

# 3,0 TEST DESCRIPTION Table 3-1 summarizes the test methods and techn i ques which will be used as the reference methods. The test matrix has been developed to meet the requirements of Section 29
. 1 of the facility Permit (Application Number 472137) dated April 15, 2011. The permitted emission limits are summarized in Table 3-2
. The follow i ng sections describe each method in further detail. Flue gas Oxygen and Carbon Dioxide concentration will be measured in conjunction with all tests using SCAQMD Method 100
. 1
. The flue gas flow rate will be measured in conjunction with each particulate test. This measured flue gas flow rate in each duct will be used for all emission rate calculations of NO x , CO, NH 3 , 

## ROG's and SOx' TABLE 3 - 1 TEST MATRIX Parameter Method 50% Load 75% Load 100% Load Test Duration NO , SCAOMD 100
. 1 1 run 1 run 1 run 60 minutes 

## 02 /C02 SCAOMD 100
. 1 With each run CO SCAOMD 100 .1 1 run 1 run 1 run 60 minutes NH 3 SCAOMD 207
. 1 2 runs 2 runs 2 runs 60 minutes S02 SCAOMD 307
. 91 2 samples 

## N/A PM EPA 201A1SCAOMD 5
. 1 1 run 1 run 1 run 240 minutes ROG Modified SCAQMD 25.3 3 runs 3 runs 3 runs - 60 minutes " ) 1) ROG tests will be nominally 60 minutes
. Flow controllers will be setup for 60 minutes
. The test will be performed until the canister vacuum reaches approximately 

### 10 "Hg
. Actual test time may be less than or more than 60 minutes per sample
.



### R021 0458-R 1 

## 7 

# lie /

tal'!" 

# ",--_ ..

## TABLE 3-2 CPV SENTINEL ENERGY PROJECT PERMITTED EMISSION LIMITS 

## Parameter Units ppm@15%02 ppm@ 15% O 2 Ibs/MMscf 

# co ppm@ 15% O2 NH3 ppm@ 15% O 2 gr/dscf @ 3% O2 Particulate gr/dscf 

## @ 12% CO 2 Ib/hr Ibs/MMscl (Ib/hr equivalent) Ib/MMBtu Ibs/MMscf SOx ROG's ppm @ 15% O 2 (1) The 12
. 261bs1MMscf is a RECLAIM emission factor, not a limij. (2) This is stated in the permit as an emission factor. 

# 3,1 O 2• 

# CO 2• 

## NO

## x AND CO 

## Limit 2.5 15 12.26(1) 4 5 0.01 0.1 11 5.71(2) (5.0) 0.06 0
.69 2
. 0 Rule 1703(a)(2) 40 CFR 60 2012 1703(a)(2) 1303(a)(1 ) 475 409 475

40 CFR 60 Rule 2011 1303(a)(I)

O 2 , CO 2 , 

## NO x 

## and CO concentrations will be measured using SCAQMD Method 100
. 1. These measurements will be made with one of Delta's mobile emission measurement laboratories. The system consists of a stainless steel or glass probe, heated Teflon line, moisture removal system, sample pump, sample filter, unheated Teflon line, and individual component analyzers. The measured concentrations are averaged over each sampling period, then corrected for system bias and analyzer drift. All quality assurance procedures required by SCAQMD Method 100.1 will 

## be performed including pre- and post-test Calibration Error, Sample System Bias and Analyzer Drift. The sampling will be performed using a 12-point traverse at each test condition (or a single point if previous testing demonstrates the absence of significant stratification (less than 10% or less than 1 ppm). At the full load condition, the compliance test may be performed concurrently with the Relative Accuracy Test Audit (RATA). In this case, data from the RATA may be used to demonstrate compliance with the NOx 

## and CO emission limits. NOx 

## concentrations will be measured on a 0-5 ppm range. CO concentrations will be measured on a 0-10 ppm range. CO 2 

## concentrations will be measured on a 0-10% range. O 2 

## concentrations will be measured on a 0-20% range. The measured concentrations are averaged over each sampling period, then corrected
R021 0458-R 1 8 

# IleI/aI1


# ..

# _--

## for system bias and analyzer drift. The drift and bias corrected result will then be used to calculate NOx 

## emissions in units of ppm, ppm corrected to 15% O2 , 

## pounds per hour, pounds per million Btu, and pounds per million standard cubic feet of natural gas. 

# 3,2 NH3 BY SCAQMD METHOD 

# 207.1 Duplicate flue gas samples will be collected non-isokinetically at each test condition using a SCAQMD Method 207.1. A 12-point traverse will be performed during each NH3 slip test unless previous tests demonstrate the absence of significant NOx 

## stratification, then Single point sampling will be performed. The sample gas is drawn through a glass probe, Teflon sample line, two impingers each containing approximately 100 ml of 0.1 N H2 

## S0 4 , 

## an empty impinger, an impinger containing silica gel, and a dry gas meter. The optional nozzle and filter will not be used since the units are natural gas fired. The contents of the probe, sample line and the first three impingers are recovered and analyzed by SCAQMD Method 207
. 1 for ammonia concentration using the Ion Specific Electrode technique. One reagent blank sample and one field blank sample will be analyzed
. Ammonia slip will be reported in units of ppm, corrected to 15% O 2 . 

## The tests will be performed over a period of at least 60 minutes. 

# 3 . 3 SOx BY SCAQMD METHOD 

# 307 , 91 Oxides of sulfur will be measured using SCAQMD Method 307-91. Two fuel samples will be collected in a Tedlar bag and sent to Saybolt Laboratory for Sulfur analysis as total reduced sulfur as H 2 

## S
. 

# 3.4 ROG BY MODIFIED SCAQMD METHOD 

# 25.3 Sampling and analyses are performed using Modified SCAQMD Method 25.3 procedures. The sample apparatus and analyses are provided by Atmospheric Analysis and Consulting (MC) in Ventura California. At each test condition, triplicate flue gas samples are extracted sequentially from four points (one per port) in the stack through pre-cleaned (high temperature conditioned) stainless steel probes connected to an out-of-stack flow controller, into stainless steel Summa polished canisters. The flow controller is set to fill the evacuated canister to a pressure of -400 mm Hg over a period of a period of one hour. Modifications to the Method 25.3 sampling procedures suggested or accepted by SCAQMD are: • Elimination of the in-stack filter • Elimination of the water vial portion of the 25.5 equipment • The final pressure in the Summa Canisters is maintained at between 400 and 500 mm HG (10 - 14 in
. Hg) absolute
.
R0210458-R1 9 

# l1li11811 

# ----

## Figure 3-1 presents a schematic drawing of the sample apparatus. FIGURE 

## 3-1 MODIFIED SCAQMD METHOD 

## 25 . 3 SAMPLING APPARATUS



## Filter Probe

Flow Controller

The samples are analyzed for NMNEOC (Non-Methane Non-Ethane Organic Compounds, i.e. Reactive Organic Compounds ROG) using modified SCAQMD Method 25.3 TCA procedures. Analysis consists of a fore-flush and back-flush of a gas chromatography (GC) column, followed by an oxidizer, a methanizer, and a flame ionization detector (FlO)
. The GC separates the NMNEOC from other constituents of the sample (methane, ethane, CO 2 , 

## H 2 

## 0, O 2 , 

## N 2 , 

## etc.). The oxidizer converts the NMNEOC to carbon dioxide. The methanizer converts the resulting CO 2 

## to methane. The methane content is detected by the FlO as ppmcarbon.

R0210458-R1 10 

# 116/11/1 '"'=- -

## Modifications suggested by SCAOMD to the Method 25
. 3 analytical procedures approved for MC under the LAP are: • Pressurization of the canisters to 900 mm Hg with Ultra High Purity (UHP) helium analyzed/certified to contain less than 0
. 05 ppmv of total hydrocarbons as carbon • Analyzing only the Summa canister fraction of the normal 25.3 sample. No water vial used in sampling, no water vial analysis. • Utilization of a larger (-2 ml) sampling loop • Development of a custom low level (0.1 - 5.0 ppmV propane) calibration curve • Performance of a Minimum Detection Limit (MOL) study • Determination of a Practical Ouantitation Limit (POL) from the MOL study Results are reported in parts per million by volume as carbon to 2 significant digits , corrected to 15% O 2 

## using the O2 

## from the canister analysis. The average of the results for the duplicate samples is compared to the Emission Standard for determination of the compliance status. 

## Note: The following message was received on November 9, 2012 and the content was incorporated into this protocol; 

## From: Roy Olivares [mailto:ROlivares@aqmd.gov] Sent: Friday, November 09, 2012 10:19 AM To: Mark McDaniels Subject: Revised VOC testing, condition D29.1 Mark The current VOC section of 

## D29.1 is the following For natural gas fired turbines only, VOC compliance shall be demonstrated as follows: a) 

## Stack gas s41llples are 

## extracted into Summa canisters maintaining a 

## final canister pressure between 400-500 mm Hg absolute, b) Pressurization of 

## canisters are 

## done with zero 

## gas analyzed/certified to 

## contain less than 0.05 ppmv total hydrocarbon as carbon, and c) 

## Analysis of 

## canisters are 

## per EPA Method TO-12 (with pre concentration)and temperature of 

## canisters when extracting samples for analysis is not below 70 deg F. 

## The use of 

## this alternative method for VOC compliance determination does not mean that it is more accurate than AQMD Method 25.3, 

## nor does it mean that it may be used in lieu of

R021 0458-R 1 11

## AQMD Method 25.3 

## without prior approval except for the determination of compliance with the VOC BACT level of 2.0 ppmv calculated 

## as carbon for natural gas fired turbines. Mike Garibay from source testing has proposed the following VOC testing For natural gas fired turbines only, VOC compliance shall be demonstrated 

## as follows 

## an alternative to 

## AQMD Method 25.3 

## for the purpose of demonstrating compliance with BACT 

## as determined by CARB and AQMD, may 

## be the following: a) 

## Triplicate S stack gas samples are extracted directly into Summa canisters, maintaining a 

## final canister pressure between 400-500 rom 

## Hg absolute, b) Pressurization of the Summa canisters are is done with zero gas analyzed/certified to 

## containing less than 0.05 ppmv total hydrocarbons 

## as carbon, and 

## c) Analysis of Summa canisters are is per unmodified EPA Method TO-12 (with preconcentration) or 

## the canister analysis portion of AQMD Method 25.3 

## wi th a 

## minimum detection limit of 0.3 ppmvC or 

## less and reported to 

## two significant figures, and (d) The temperature of the Summa canisters when extracting samples for analysis is not to 

## be below 70 degrees Fahrenheit. The use of this alternative method for VOC compliance determination does not mean that it is more accurate than unmodified AQMD Method 25.3, 

## nor does it mean that it may be used in lieu of AQMD Method 25.3 

## without prior approval, except for the determination of compliance with the VOC BACT level of 2.0 ppmv VOC calculated 

## as carbon set by CARB for natural gas fired turbines
. please have the VOC testing portion of the source test protocol address the above changes roy Roy Olivares Air Quality Engineer II Energy and Public Service Team South Coast 

## Air Quality Management District 21865 Copley Drive Diamond Bar, CA 91765 909-396-2208

R021 0458-R 1 12 

# IJeIl8I'1 

# "'--

## 3.5 PM BY SCAQMD METHOD 

## 5.1 Particulate matter will be measured using EPA Method 201A in conjunction with SCAOMD Method 5 .1. SCAOMD Method 5 .1 is cited as the Table in Condition D29.1 lists District Method 5
. District Method 5
. 1 measures total particulate. This total particulate measurement could include material >10 microns
. Use of the cyclone as in 201A will prevent overstating of PM 10 

## emissions if all of the PM emissions from these units are not PM 1o . 

## A single test will be performed at each of the three conditions; 100%, 75%, and 50% load conditions. Flue gas is drawn through a stainless steel nozzle, glass or stainless steel probe, unheated Teflon line followed by four i mpingers. Impingers #1 and #2 contain approximately 100 ml of de i onized water, impinger #3 is empty, and impinger 

## #4 contains silica gel. A backup filter is placed between impingers #3 and 

## #4 . The sample will be collected isokinetically (90 - 110%) using a 24-point traverse at the exhaust stack location. Each point will be sampled for 10 minutes resulting in a 240 minute sample time per test. Figure 3-3 presents a diagram of the sampling system
.

R0210458-R1 13 

# IJeIlaI1. 

# .......x--Temperature Sensor Probe

# ~

Pitot Tube



### Nozzle


# / S-Type Pitot Tube 

## FIGURE 3-3 SCAQMD METHOD 5.1 SAMPLE SYSTEM

Manometer 

## Orifice Connecting Teflon Tubing 

### Filter Temperature

Gel 

### Line



## The sample is recovered in two fractions: 1) nozzle, probe, connecting line and impinger rinse (DI water) and 2) backup filter. Filter weight gain and water solution weight gain are each determined gravimetrically.

R021 0458-R 1 

# 1Je1flt:. 

# "" --- 14

# 4 .0 REPORTING Following the test, a report will be generated which documents the results of the tests
. The report will be prepared using the following basic outline: I. Title page A. Report Title B. Prepared For: C
. For Submittal To : D. Prepared By : E. 

## Date F. Report Number II. Review Page A. Signatures of person who prepared the report and signature of person who reviewed the report III. Table of Contents I V. Introduction and Summary A. Identifies the client, source, reason for the test , test date(s), test personnel. client/source personnel B
. Presents a summary of the test results C
. Outlines the organization of remainder of the report. V. Unit Description A
. Process description B. Control equipment description C. Sample location(s) description D
. Unit operating condition(s) during the test VI. Test Description A. Test methods, replicates, duration, calculations VII. Test Results and Evaluation A. Re-states the results of the test B
. Results tables with more detail on individual test runs and supporting data C
. Evaluation of the test results and data validity VIII. Appendices A. Test Data

R021 0458-R 1 15 

# lltlliafl

..

# _--

## 1. Data Sheets/Stripcharts 2
. Laboratory Data 3. Quality Assurance Data B. Process data 1
. Unit and control equipment operating data C
. Calculations D
. Quality Assurance Program Summary

R0210458-R1 16 

# 1Je11l!J.
..

# _--

## APPENDIX A QUALITY ASSURANCE

R021 0458-R 1 A-1

## QUALITY ASSURANCE PROGRAM SUMMARY 

## Delta Air Quality Services, Inc
. is committed to providing emission related data which is complete, precise, accurate, representative, and comparable
. Delta's quality assurance program and procedures are designed to ensure that the data meet or exceed the requirements of each test method for each of these items. The quality assurance program consists of the following items: • Assignment of an Internal QA Officer • Development and use of an internal QA 

## Manual • Personnel training • Equipment maintenance and calibration • Knowledge of current test methods • Chain-of-custody • QA reviews of test programs Assignment of an Internal QA Officer: Delta has assigned an internal QA Officer who is responsible for administering all aspects of the QA program. Internal Quality Assurance Manual : Delta has prepared a QA Manual according to the guidelines issued by EPA. The manual documents and formalizes all of Delta's QA efforts. The manual is a "living" document which is revised as Delta adds capabilities and procedures
. The QA manual provides details on the items provided in this summary. Personnel Training: Personnel training is essential to the production of high quality test results. Delta's training programs include : • A requirement for all technical personnel to read and understand the test methods performed • A requirement for all technical personnel to read and understand the Delta QA manual • In-house training • Quality Assurance meetings • Attendance at EPA sponsored training courses • Maintenance of training records. Equipment Maintenance and Calibration: All laboratory and field equipment used as a part of Delta's emission measurement programs is maintained according to manufacturer's recommendations. A summary of the major equipment maintenance schedules is summarized in Table A-1. In addition to routine maintenance, calibrations are performed on all sampling equipment according to the procedures outlined in the applicable test method
. The calibration intervals and techniques for major equipment components is summarized in Table A-2
. Knowledge of Current Test Methods : Delta maintains current copies of EPA, ARB, and SCAQMD Source Test Manuals and Rules and Regulations
. Delta personnel coordinate, attend, and present papers at emission testing related conferences. Delta personnel maintain memberships in the Air and Waste Management Association and Source

R021 045B-R 1 A-2 

# JJelfl/1 

# "'---

## Evaluation Society
. Delta personnel continually work with industry and regulatory agencies in monitoring and developing new methods and rules
. Chain-of-Custody : Delta maintains chain-of-custody documentation on all data sheets and samples
. Samples are stored in a locked area accessible only to Delta source test personnel. Data sheets are kept in the custody of the originator, program manager , or in locked storage until return to Delta's office. Upon return to the office , copies are made and stored in a locking file
. The original data sheets are used for report preparation and any add itions are initialed and dated
. QA Reviews: Every Delta report is reviewed by someone separate from the report author. The reviewer is selected based on knowledge of the test methods used and the source tested
. Periodic f ield, l aboratory, and report reviews are performed by the QA Officer. Test plans are reviewed to ensure proper test methods are selected and reports are reviewed to ensure that the methods were followed and any deviations from the methods are justified and documented
.

R0210458-R1 A-3 

# JJeIfl IJ..

..

# _- -

### Equipment Pumps

Flow Meters Sampling Instruments

Integrated sampling tanks Mobile van sampling system
Sampling lines

R021 0458-R 1 

## TABLE A-1 EQUIPMENT MA IN TENANCE SCHED U LE

Acceptance Limits 1
. Absence of leaks 2
. Ability to draw manufacturers required vacuum and flow 1
. Free mechanical

movement 1
. Absence of

malfunction 2
. Proper response to zero , span gas 1
. Absence of leaks 1
. Absence of leaks

1
. Sample

degradation less than 2%

A-4 Frequency of Service Every 500 hours of operation or 6 months , whichever is less Every 500 hours of operation or 6 months, whichever is less As recommended by manufacturer Depends on nature of use Depends on nature of use

After each test series Methods of Service 1
. Visual inspection 2
. Clean 3
. Replace parts 4
. Leak check 1
. Visual inspection 2
. Clean 3
. Calibrate As recommended by manufacturer

1
. Steam clean 2
. Leak check 1
. Change filters 2. Change gas dryer 3
. Leak check 4
. Check for system

contamination 1
. Blow dry, inert gas

through line until dry
.



# De I

Ia/1 

# ..

# _- -

## TABLEA-2 MAJOR SAMPLING EQUIPMENT CALIBRATION REQUIREMENTS Sampling Equipment Calibration Frequency Calibration Procedure Acceptable Calibration Criteria Continuous Analyzers Before and after each 3-point calibration error < 2% of analyzer range test day test Continuous Analyzers Before and after each 2-point sample system < 5% of analyzer range test run bias check Continuous Analyzers After each test run 2-point analyzer drift < 3% of analyzer range determination CEMS System Beginning of each day leak check < 1 in
. Hg decrease in 5 min. at > 20 in
. Hg Continuous Analyzers Daily 3-point linearity < 1% of analyzer range NO, Analyzer Daily N02 -> NO converter > 90% efficiency S-type pitot tube Semi-annually Dimensional calibration Meet dimensional criteria of Method 2 S-type pitot tube Annually Wind tunnel calibration Defined in Method 2 S-type pitot tube Prior to each project Visual inspection Meet dimensional criteria of Method 2 Differential Pressure Semi-annually Correction factor based +/- 5% Gauges (except for on 5-point comparison to manometers) standard Differential Pressure Bi-monthly 3-point comparison to +/- 5% Gauges (except for standard , no correction manometers) factor Manometer Semi-annually Clean and replace fluid Barometer Semi-annually Adjusted to mercury-in- +/- 0
. 1 inches Hg glass or National Weather Service Station Dry gas meter Semi-annually Calibration check at 4 +/- 2% flow rates using a NIST

traceable standard Dry gas meter Bi-monthly Calibration check at 2 +/- 2% of semi-annual flow rates using a NIST factor

traceable standard Dry gas meter orifice Annually 4-point calibration for &H@ Temperature sensors Semi-annually 3-point calibration vs . +/- 1.5% NIST traceable standard



## R021 0458-R 1 A-5 

# hila/:). 

# "'---

## APPENDIX B TEST METHODS

R021 0458-R 1 8-1 

# /lelia/').

...

# _--

## SCAQMD METHOD 100.1 CALIBRATION SEQUENCE AND CALCULATIONS DEFINITIONS: 

## 1) Analyzer Calibration:
2) Calibration Error:

3) Analyzer Linearity:

4) Sample System Bias:

R0210458-R1 Zero and span gas(es) are introduced directly to the analyzer
. Adjustments are made to the analyzer zero and upscale readings, as necessary to match the certified concentrations of the calibration gas. Zero, mid (40-60% of full scale), and high (80-100% of full scale) calibration gases are introduced directly to the analyzer and the analyzer response to each gas is recorded (without adjustment to the analyzer). The Calibration Error (difference between the analyzer response to the calibration gas and the certified concentration of the calibration gas) must not exceed ±2% of the analyzer full scale for any of the three gases. Analyzer linearity is defined as the difference between an analyzer response to the mid range gas and the predicted analyzer response to the mid range gas. based on the analyzer response to the zero and high range gas. The Analyzer Linearity test is required on a semi-annual basis and must not exceed ±1 % 

## of the analyzer range. It 

## should be noted that this linearity requirement is more stringent than the best available calibration standards (+/-2%) for the low CO and NO, concentrations expected during this test program. For this reason, an analyzer linearity of less than 2% will be considered as acceptable for this program. The sample system bias test involves introducing zero and one upscale (mid or high) calibration gas to the entire sampling system and recording the analyzer response . The analyzer response to the calibration gas after it has passed through the entire sample system is compared to the analyzer response to same the calibration gas injected directly to the analyzer. The test is used to determine the effect which the sample system has on the species of interest and correct the measured values for any effect which the system has. The sample system bias is required to be less than ±5% of the analyzer range for both the zero and upscale gas.

B-2 

# IJefl8l1 

# ._-

## PROCEDURES AND CALCULATIONS: Figure 

## 1 presents a flow chart for the SCAQMD Method 

## 100 . 1 calibration sequence . All calibrations are documented as one-minute averages from the reference method Data Acquisition System. Following assembly of the system, analyzer warm up time, and a successful leak check of the sample system, the calibration/test sequence presented in Figure 1 can begin. An Analyzer Calibration is performed as necessary by adjusting the zero and span settings of the analyzer. These calibrations are not necessarily recorded on the chart recorder. Calibration Error is then determined at three levels for each range (which is expected to be used) of each analyzer. This check is performed , at a minimum, once at the beginning and once at the end of each test day. The calibration error must not exceed ±2% of the full range of the analyzer as determined by the following equation: Calibration Error 

## = Analyzer Response- Cal. Gas Value. 100% Analyzer Range The data from the Calibration Error test can be used to determine Analyzer Linearity. The analyzer response to the mid gas is predicted using linear regression and the analyzer response to the zero and high calibration gas and the zero and high calibration gas values. The analyzer linearity must be demonstrated on a semi-annual basis using the following equation : Analyzer Linearity 

# = Analyzer Response - Predicted Response. 100% Analyzer Range where: Response to High Gas - Response to Zero Gas Predicted Response 

### = • Mid Gas Value + Response to Zero Gas High Gas Value 

## The Sample System Bias test is performed before and after each test run and must not exceed ±5% of the analyzer range for both the zero and upscale span gas . The system bias is calculated using the following equation: Response to System Bias - Response to Analyzer Cal Sample System Bias 

# = • 100% Analyzer Range

R021 0458-R 1 

## 8-3 

# JJe/1I1J. 

# ",-_..

# -

## where: Response to Analyzer Cal 

# =The analyzer response to the last time the same calibration gas was introduced directly to the analyzer (this may be the pre-test calibration error value or a more recent analyzer calibration adjustment) Zero and Calibration Drift are calculated for each test run based on the analyzer response during the pre- and post-test sample system bias test. Zero and upscale drift must not exceed ±3% of the analyzer range . A I D ·ft 

## Post - Test System Bias Resonse - Pre - Test System Bias Response

no yzer n = • 

## 100% Analyzer Range The pre- and post-test analyzer response during the sample system bias test are used to correct the raw test average for any sample system bias and analyzer drift. The drift/bias corrected data are the actual reported concentrations and are used for subsequent calculations (mass emission rates, Ib/MMBtu, corrections to 3% or 15% O2 , etc.). The drift/bias corrections is performed using the following equation: 

# c-c c 

# = 0 

# * 

# c

c 

# C 

# -c ma m 0 

## where: Cc 

# = Drift/bias corrected concentration 

# C 

# = Raw Test Average C m 

## = Average of pre - and post-test response to sample system bias span Co 

# = Average of pre- and post-test to sample system bias zero C ma 

# = Span gas value ADDITIONAL QUALITY ASSURANCE CHECKS : SCAQMD Method 100.1 specifies the allowed analyzer interferences for each analyzer type. No interference checks are required for O2 or NOx 

## analyzers
. Interference tolerances are given for CO, CO2 , and S02 analyzers
. The analyzers used by Delta are certified by the manufacturers to have interference responses which meet the requirements of Method 100.1. SCAQMD has published a draft method for determining the efficiency of a N02 to NO converter. This test will be performed once on the day of the test. The converter efficiency must be 90% or greater
.

R021 0458-R 1 8-4

## Analyzer Cal Cal No Error < 2% No Yes 

# I Yes System Nn 

## System I

## Bias < 5% Problem? Yes Don't Know Stratified No Location? Yes Multi-Point Single Point Test Test 

# 1 System No Bias < 5% Yes Cal No Drift < 3% Yes Note: AQMD policy allows multiple 

## Another No Analyzer Cal test runs to be validated by one set of pre- and post-test sample system 

## Test? (if 

## necessary) bias tests as long as the bias 

# 1 checks are performed within 2 hours 

## Yes of the previous bias check
. 

## No No Analyzer Cal Cal? Error < 2% Yes 

# 1 Yes No Yes System 

# [ Finish 

# ) Bias < 5% 1-1
FIGURE 1: SCAQMD METHOD 100.1 CALIBRATION AND TEST SEQUENCE

R021 045B-R 1 8-5 

# IleIlaI1

...

# _--Temperature

# ~~.
PltotTube



### S-TypePitotTube

# ~ Manometer


## Orifice Connecting Teflon Tubing



## SCAQMD METHOD 5.1 SAMPLING TRAIN

R021 0458-R 1 8-6 Temperature Sensor

Vacuum Gauge



# /Je11l!:1

.. 

# --.-

## Filter Probe

Flow Controller



## MODIFIED SCAQMD METHOD 25.3 SAMPLING APPARATUS

R021 0458-R 1 8-7 

# 0e1l811
........

# --

## APPENDIX C CALCULATIONS

R021 0456-R 1 C-1 

# llellatl

...**~--**

## GENERAL EMISS I ON CALCULATIONS 

## 1) Stack Gas Velocity



# 2) A. Stack gas molecular weight, Ibflb-mole 

# MW dry 

# = 

# 0.44 * 

# %C0 2 

# + 

# 0.32 * 

# %0 2 

# + 

# 0 . 28 * 

# %N 2 

# MW 

# wet 

# = MW dry 

## * 

# (1

- Bwo) 

# + 18 * 

# Bwo B
. Absolute stack pressure , iwg 

## Ps 

# = Pbar 

# + Psg 

# 13 .6 

# c . Stack gas velocity , ftlsec

Vs 

# = 2.9 * 

# C p 

## * 

# -JilP * 

# .JT. * Moisture A. Sample gas volume, dscf V

mstd 

# = 0.03342 * Vm 

## * 

# (P bar 

# + B. Water vapor volume, scf 

# v 

# = 0 . 0472 * V. 

# * T ret 

### wsld Ie 

# 528 

# oR 29 . 92 * 

# 28.95 p. * 

# MW wet



# ilH ) * T ret 

## * 

# Y d 

# 1 3.6 Tm



# c . Moisture content, dimensionless 

# Bwo 

# = 3) Stack gas volumetric flow rate 

## A. Actual stack gas volumetric flow rate, wacfm Q 

# = V 

# * A 

# * 

# 60 s s 

## B. Standard stack gas flow rate , dscfm

R021 0458-R 1 C-2 

# De/Ia/). 

# ..

# __........

## Q 

# = Q 

# * (1- B ) * T ref 

# * P, sd wo Ts 

# 29.92 4) Gaseous Mass Emission Rates. Ib/hr 

# M 

# = ppm * MW, * Q Sd 

# * 60 SV * 

# 10 6 

## 5) Emission Rates. Ib/MMBtu 

# Ib _ppm*MW,*F* 20.9 MMBtu - SV*10· 20.9-%0 2 

## 6) Emission Factor. Ib/MMSCF 

# Ib Ib *HHV MMSCF MMBtu VI. Percent Isokinetic 17.32 

# x 

# T, (Vm sId) _52_8_ 0 

## _R 

## 1= 

# x (1- Bwo)O x V, x Ps x Dn 2 

### Tn! 

## VII. Particulate emissions a) Grain loading, 

## gr/dscf C 

# = 0.01543 (MrlVm SId) 

## b) Grain loading at 

# 12% CO 2 , 

## gr/dscf C 12% C02 

# = C (12/% 

## CO 2) 

## c) Grain loading at 

# 3% O2 , 

## gr/dscf 

# C 3 

### % 02 

# = C· 17.9/(20.9- %0 2 ) 

## d) Mass emissions, Ib/hr M 

# = C x Qsd x (60 min/hr)/(7000 

## gr/lb) e) Particulate emission factor
6 

## lIb 20
.. 9 Ib 

# 110 Btu 

## = 

# C x x F X 0/ 

# 0 7000gr 

## 20.9

- /0 2



## R021 04S8-R 1 C-3 

# /lelia/). 

# "'---

## Nomenclature : 

# As 

# Bwo C12 %C02 

## C 3%02 

# C 

# C

p 

## On 

## F 

# H HHV 

## I 

# Mn M; 

## MW 

# Mwi



# o t.P Pbor 

# Ps Psg 

# o Ow . OSd 

## SV 

# Tm Tref 

# Ts Vs ViC 

# Vm V mstd 

## V wstd 

# Y

d



## R021 0458-R 1 

# = stack area , 

# ft2 

# =

flue gas moisture content, dimensionless 

## = particulate grain loading, gr/dscf corrected to 12% CO 2 

# =

particulate grain loading , gr/dscf corrected to 3% CO 2 

## = particulate grain loading, gr/dscf 

# =

pitot calibration factor , dimensionless 

# = nozzle diameter, in. 

# =

fuel F-Factor, dscf/MMBtu 

## @ 0% O 2 

# =

orifice differential pressure, iwg 

# =

fuel higher heating value, Btu/SCF 

# = % isokinetics 

# =

mass of collected particulate, mg 

# = mass emission rate of specie i, Ib/hr 

# =

molecular weight of flue gas, Ibllb-mole 

# = molecular weight of specie i: 

## 80 2 : 

## 64 NO x: 

## 46 CO: 

## 28 HC: 

## 16 

# = sample time, min
. 

# =

average velocity head, iwg 

## = 

# (.Jt.P) 2 

# = barometric pressure, inches Hg 

# =

stack absolute pressure, inches Hg 

# =

stack static pressure, iwb 

# = wet stack flow rate at actual conditions, wacfm 

# =

wet stack flow at standard conditions, wscfm 

## = dry standard stack flow rate, dscfm 

# =**s~ecific** 

## molar volume of an ideal gas at standard conditions,



## ft lib-mole 

## = meter temperature, 

# oR 

# =

reference temperature, 

# oR 

# = stack temperature, 

# oR = stack gas velocity,
. ft/sec 

# = volume of liquid collect ed in impingers , ml 

# = uncorrected dry meter volume, dcf 

# =

dry meter volume at standard conditions, dscf 

# = volume of water vapor at standard conditions , scf 

## = meter calibration coefficient

C-4 

# DeIl8!:1 

# "'--

## APPENDIX D FORMS

R021 0458-R 1 0-1

# South Coast Air Quality Management District 21865 Copley Drive, Diamond Bar, CA 91765-4178 (909) 396-2000 ' www.aqm d .gov



### Mr. Robert 

### A. Finken Delta Air**Qua~ty** 

### Services , Inc. 1845 N. Case Street Orange, CA 92865 Subject: LAP Approval Notice Reference 

### # 96LA 1220 

### Dear Mr. Finken: January 11,2012



### We completed our review ofthe renewal application you submitted for approval under the South Coast Air Quality Management**Oistric~s** 

### Laboratory Approval Program (AQMD LAP) . We are pleased to inform you th.t your firm is approved for the period beginning January 3 1,2012, and ending January 3 I, 2013 for the following methods: SCAQMD Methods 1-4 SCAQMD Method 1O(j,1 SCAQMD Methods 25.1 and 25.3 (Sampling) SCAQMD Methods 5.1, 

## 5.2, 5.3, and 6.1 SCAQMO Rule 1420

- (Lead) Ambient Sampling USEPA CTM-OJO and ASTM 06522-00 Thank you for participating in the SCAQMD LAP . Your cooperation helps us to achieve the goal of the 

### LAP: to maintain high standards of quality in the sampling and analysis of source emissions. You may direct any questions or information to LAP Coordinator, Glenn Kasai. He may be reached by telephone at (909) 396-2271, by facsimilie at (909) 396-2099, or via e-mail at gkasai@aqmd.gov.

RE : GKlgk 

### cc : Mike Garibay 

### Glenn Kasai 120111 LapRenewal.doc



## R021 0458-R 1

# S;~& /

# ~n, Senior Manager Laboratory Services & Source Test Engineering



## D-2

### ;u 

### a N**~**

## ~ 

# '" to 

## ;0**~**



# o W

# ij~

# ~~ State of California 

# Ai r Resources Board Approved Independent Contractor 

# Delta Air Quality 

# Services, Incorporated This is to certify. that the company fisted iibove' nasbeen approved

, by the Ai , '

## Re~6(j**fE'~** 8OardlO :

## CQ~u.? coi);{iilance testing pursuant to**tit1e 17** **Califorriia** 

## Code;of**Regulation~,** 

## section 91207 until

## Ju~ 

# : 30 ; ', 2013, for those test

## metliods**isted** below: 

## ARB Soare( Te.d 

### Mdh.:Nt.s; 

# " l, 2, , 3, 4, 

### 5, 6,11, 

### 17. 20. ,501 108 

# '(co; co,. NO" 

### 0" SO,)

Alberto Ayal2\, Ph.D " M , S,E. 

### Chief,**Mon~oring** 

### and Laboratory Division

### ;u 

## o I\)**~**

## ~ 

# '" ex> 

## ;0**~**



# o ,I,..



# ,ilii'

# it~ State of California 

# Air Resources Board Approved Independent Contractor 

# Delta Air 

# quality Se'nices;
.lncorporated This is to certify tljilt !he co!.'1pany Iiste<!'above has been approved by the Air**Re--so~s Board** **to colJd~ct**  

## · comP.liance testing pursuant to title '- 11;'; CalifomJa Code ;pf Reriillations. section 

# 91207 until June. 

# :30 ;:i 013 ;' for thOS& 

## test methOds ' ilsted below:
'<. .=, . ,. 1' • .

,1, • '/ •• "



### . ' Visible Emissions 

### Evaluation U.S. EPA Test

### Methods**201A (l~1.ersiO~).**  202,(IP91 

### version) 

# .17
Alberto Ayala •.Pfl.D
. • M.S.E. 

### Chief.**Mon~oring** 

### and laboratory Division

## STATEMENT OF NO CONFLICT OF INTEREST AS AN INDEPENDENT TESTING LABORATORY (To be completed by authorized source testing firm representative and included in source test report) The following facility and equipment were tested by my source testing firm, and are the subjects of this Statement: 

### Facility 10: .,......:--___

## ---:!1~46!!>S~3~6-------------**-- ---**  Date(s) Tested:

_____ T"'e""s"'t"=P""a"'n-,--..,....,,
__ -:---:-___________ _ 

### Facility Name: CPV Sentinel Energy Prolect

## EquipmentAdd~r-es-s-:---9~1~1~B:7lx7b~y~D7r7iv~e~~~~~------------- City of Industrv, California 

## 91748 Equipment Tested:
___

### -=U":n~lt~s=-1,,:'

### 2~,:-:3,,",=4,:,' S=,'-,:6=-:,

### ~7~, 

## &'=78"'=:-:""'7.:--------- Device 10, AlN, P/N:
__ ---'D ...

## 1

....

,..!:D

.... 

## 7

.... , 

# D

...1.!..:3!.L,....**D:..!.1"'9,'-'D~2""S"",**

# .... 31

....

, ... 3",7**,,-,&~42,,--** 

# _______ _
r state , as its legally authorized representative, that the source testing firm of : 

### Source Test Firm: Delta Air Quality Services. Inc. 

### Business Address:**.:.1""84",5"-,-,N~C=as",e,",S""t",re,,,e,,,t**

### __________________ _ Orange, California 92865-4234 is an "Independent Testing Laboratory" as defined in 

### District 

## Rule 304(k): For the purposes of this Rule, when an independent testing laboratory 

## is used for the purposes of establishing compliance with District rules or 

## to obtain 

## a District permit 

## to operate, it must meet all 

## of the following criteria :

(1) The testing laboratory shall have no financial interest in the company or facility being tested
. or in the parent company or any subsidiary thereof- (2) The company or facility being tested, orparent company or any subsidiary thereof, shall have no financial interest in the testing laboratory; (3) Any company or facility responsible for the emission 

## of significant quantities 

## ofpollutants to the atmosphere, or parent company or any subsidiary thereof shall have no financial interest in the testing laboratory ; and (4) The testing laboratory shall not be in partnership with, own or be owned by, in part or in full, the contractor who has provided or installed equipment (basic or control), or monitoring systems, or is providing maintenance for installed equipment or monitoring systems, for the company being tested Furthermore, 

### r state that any contracts or agreements entered into by my source testing firm and the facility referenced above, or its designated contractor(s) , either verbal or written, are not contingent upon the outcome of the source testing, or the source testing information provided to the SCAQMD ;.

_ -""'") , 

### Signature : 

# ( : . ,_

LA- (.,) ) j \.

, <: 

### Bob Finken (Name) 

### President (Title) FORM ST-110 :stevforl.doc (Revised 

## 11/18/98)

R021 0458-R 1 

## 0-5 Date:
___ 

## "'1217

........ 1"'20"'1 ... 2'--
___ _ 714-279-6777 1217/2012 (Phone) (Date)



# 1IeI1lt:,. 

# ""- --

## APPENDIX E FACILITY PERMIT TO OPERATE CONDITION 

# 029.1

R038842-R1 

## E-1

### SOUTH COAST AIR QUALITY MANAGEMENT DISTRlcr 

## 21865 Copley DrIve, Diamond Bar, CA 91 765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Stction H Page ; 35 Facility 10: I Sl701 Revision #: 0 !n1e : ApnllS,20tI



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply w ith the terms and conditions set forth below: The operator shall also install and maintain a device to continuously record the parameter being measured The measuring device or gauge shall be accurate to within plus or minus 5 percent. It shall be calibrated once every twelve months It shall be 

## calibrated once every twelve months The pressure drop across the catalyst shall not exceed 12 inches water column [RULE 

## 1303(a)(I)-BACT, 5-10-1996; RULE 1303(aXI)-BACT, 12-6-2002; RULE 1703(aX2)

- PSD-BACT, 10-7-1988; RULE 

## 1005, 5-6-1005] [Devices subject to this condition: C4, C10, C16. C22, C28, C34, C40, C46] D 12.5 The operator shall install and maintain a(n) non-resettable elapsed time meter to accurately indicate the elapsed operating time from the engine. [RULE 1110.2,2-1-2008; RULE 

## 1303(b)(2)-OfTset, 5-10-1996; RULE 1303(bX2) -Offset, 12-6-2002; RULE 1470,6-1-2007; RULE 

## 1012, S-6-1005] [Devices subject to 

## this condition: D49] D29 . 1 The operator shall conduct source testes) for the pollutant(s) identified below. Po llutant(s) to 

# I Required Test Method(s) 

# I Averaging Time 

# I Test Location be tested NOX emissions District method 100.1 

# I hour Outlet of the SCR serving this equipment CO emissions 

# I District method I00.1 I hour 

# IOutlet of the SCR serving this equipment SOX emissions 

# I AQMD Laboratory 

# I Not Applicable 

# I Fuel sample Method 307-91 VOC emissions 

# I District Method 25.3 

# II hour 

# IOutlet ofthe SCR serving this equipment

## SOUlH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC SettionH**F~ilitv** 10 : Rnisionll : Date : Page : 36 152707 

## o April 15.2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shan comply with the terms and conditions 

# let forth below: PM 

## I 0 

# I District Method 

## 5 emissions 

## NH3 emissions 

# I District method 

## 207.1 and 5.3 

# or EPA method 

## 17 

# I 4 hours 

# II hour 

# IOutlet 

## of the SCR serving this equipment 

# IOutlet 

## of the SCR

serving this equipment

## SOlITH COAST AIR QUAlllY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91765 

# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Pa,gc: 37 

### Facilirv 10 : 152707 Revision M ; 0 Date : April IS, lOll



# SECTION H : PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: The test shall be conducted after 

## AQMD approval of the source test protocol, but no later the later of 180 days after initial start-up 

## or three hundred hours of operations after start-up. The AQMD shall be notified of the date and time of the test at least 10 days prior to the test The test shall be conducted to detennine the oxygen levels in the exhaust. In addition, the tests shall measure the fuel flow rate (CFH), the flue gas flow rate, and the turbine generating output in MW. The test shall be conducted in accordance with AQMD approved test protocol. The protocol shall be submitted to the AQMD engineer no later than 

## 45 days before the proposed test date and shall be approved by the AQMD before the test commences. The test protocol shall include the proposed operating conditions of the turbine during the tests , the identity of the testing lab, a statement from the testing lab certifYing that it meets the criteria of Rule 304. and a description of all sampling and analytical procedures The test shall be conducted when this equipment is operating at maximum, average, and minimum loads
. For natural gas fired turbines only, VOC compliance shall be 

## demonstrated as fonows: a) Stack gas 

## samples are extracted into Summa canisters maintaining a final canister pressure between 400-500 mm Hg absolute, b) Pressurization of canisters are done with zero gas analyzed/certified to contain less than 0 . 05 ppmv total hydrocarbon as carbon, and c) Analysis of canisters are per EPA Method TO-l2 (with pre concentration) and temperature of canisters when extracting samples for analysis is not below 70 deg F . The test shan be conducted for compliance verification of the BACT VOC 2.0 ppmv limit. The test results shall be reported with two significant digits.

## SOUlli COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Page' 

### 3' Facility ID: 152707 

### Revmon' : 0 Date : AptillS,201I



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: [RULE 1303(a)(I)-BACT,5-10-1996; RULE 1303(aXl)-BACT, 12-6-2002; RULE 1303(b)(l}-OffJet, 5-10-1996; RULE 1303(b)(2}-Offsct, 12-6

-2002; RULE 1703(a)(2)- PSD-BACT, 10-7-1988; 

## RULE 2005, 5-6-2005] [Devices subjectto this condition: 01, 07, DI3, 019, D25, D31, 037, D43) 029.2 The operator shall conduct source testes) for the pollutant(s) identified below. Pollutant(s) to 

# IRequired Test Method(s) be tested NH3 emissions 

# I District method 207.1 and 

## 5.3 or EPA method 17 

# IAveraging Time II hour 

# I Test Location 

# IOutlet ofthe SCR

serving this equipment The test shall be 

## conducted and the results submined to 

## the District within 45 days after the test date. The AQMD shall be notified of the date and time of the test at least 7 days prior to the test. The test shall be conducted at least quarterly during the first twelve months of operation and at least annually thereafter
. The NOll concentration, as determined by the CEMS, shall be simultaneously recorded during the ammonia slip test . 

## If the CEMS is inoperable, a test shall be conducted to determine the NOx emissions using District Method 100.1 measured over a 60 minute averaging time period. If the turbine is not in operation during one quarter, then no testing is required during that quarter The test shall be conducted to demonstrate compliance with the Rule 1303 BACT concentration limit 

## [RULE 1303(a)(1}-BACT, 5-10-1996; RULE I303(aXI}-BACT, 12 -6-2002) [Devices subject to this condition: 01, 07, D13, 019, 025, D31, D37, 043)

# END OF DOCUMENT