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Version 1 Revision Date 01 /09/2014 Print Date 01 /09/2014 

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION 

Product name 

Product Use Description 

Company 

Prepared by 

Telephone 

Visit our web site 

E-mail address 

Emergency telephone 

number 

Intermediate 

SECTION 2. HAZARDS IDENTIFICATION 

Emergency Overview 

Form 

Colour 

Odour 

OSHA Regulatory Status 

liquid 

light yellow 

not significant 

This material is considered hazardous by the OSHA Hazard Communication Standard (29 

CFR1910.1200) 

Potential Health Effects 

Eyes 

Skin 

Ingestion 

Inhalation 

Chronic Exposure 

Aggravated Medical 

Condition 

Contact will probably cause severe irritation. 

Contact will probably cause severe irritation; may cause skin 

sensitization. 

Ingestion will probably cause irritation of the digestive tract. 

May cause severe allergic respiratory reaction. 

Repeated exposure above current occupational limits may 

cause an allergic sensitization of the respiratory tract. This is 

characterized by an asthma-like response upon re-exposure 

to the chemical. The symptoms may include coughing, 

wheezing, shortness of breath, and chest tightness. 

Sensitized persons may develop a hyper-reactive response to 

even minimal concentrations. 

Toluene diisocyanate and 2-methyl-m-phenylene diisocyanate 

are IARC 28 and NTP Group 2 Carcinogens. 

May be very aggravating to some 

skin conditions 

asthma-type conditions 

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Primary Routes of Entry Inhalation 

Ingestion 

Eyes 

Skin Absorption 

Skin contact 

Carcinogenicity: 

I IARC I Toluene diisocyanate 1584-84-9 I 

No component of this product present at levels greater than or equal to 0.1% is identified as a 

carcinoQen or potential carcinoQen by OSHA. 

NTP Toluene diisocyanate 1584-84-9 I 

No component of this product present at levels greater than or equal to 0.1% is identified as a 

carcinogen or potential carcinogen by ACGIH. 

Environmental Effects 

Environmental Effects No information available. 

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 

Chemical nature 

Urea urethane 

Hazardous components 

The specific chemical identity/weight percent of proprietary ingredient(s) is a trade secret 

Component CAS-No. Weight percent 

Urea urethane - 60.00 - 100.00 

Toluene diisocyanate 584-84-9 0.10 - 1.00 

2-Methyl-m-phenylene 91-08-7 0.10 - 1.00 

diisocyanate 

SECTION 4. FIRST AID MEASURES 

First aid procedures 

Inhalation Remove to fresh air. Get medical aid as soon as possible. If 

breathing has stopped, trained personnel should administer 

rescue breathing, and CPR if the heart has stopped. 

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Skin contact 

Eye contact 

Ingestion 

Notes to physician 

Risks 

Revision Date 01 /09/2014 Print Date 01 /09/2014 

Remove contaminated clothing. Wash thoroughly with soap 

and water for at least 20 min. or until material is removed. 

Immediately flush with plenty of water for at least 20 minutes. 

Get medical aid. 

Do not induce vomiting. Get immediate medical attention. 

No information available. 

SECTION 5. FIREFIGHTING MEASURES 

Flammable properties 

Flash point 

Ignition temperature 

Suitable extinguishing 

media 

Unsuitable extinguishing 

media 

Special protective 

equipment for firefighters 

Specific hazards during 

firefighting 

Hazardous decomposition 

products due to incomplete 

combustion 

Further information 

> 100 oc (> 212 <F) 

> 200 oc (> 392 <F) 

Foam 

Carbon dioxide (C02) 

Dry chemical 

No information available. 

In the event of fire, wear self-contained breathing apparatus. 

Will not explode on mechanical impact. 

Cool closed containers exposed to fire with water spray. 

Carbon oxides 

nitrogen oxides (NOx) 

Keep away from heat and sources of ignition. 

Keep away from oxidizing agents. 

SECTION 6. ACCIDENTAL RELEASE MEASURES 

Personal precautions 

Environmental precautions 

Methods for containment 

Methods for cleaning up 

Eliminate all sources of ignition. Ventilate area if indoors. Wear 

self-contained breathing apparatus and full protective clothing. 

Prevent spilled material from entering the ground, water and/or 

air by using appropriate containment methods. 

Stop leak. Dike and contain spill. 

Absorb with suitable material and remove with sparkless 

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shovel and/or scoop. 

Additional advice No further information is available. 

SECTION 7. HANDLING AND STORAGE 

Handling 

Handling Harmful in contact with skin. 

Avoid contact with skin and eyes. 

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. 

Keep away from oxidizing agents. 

Keep container closed when not in use. 

Handle as an industrial chemical. 

Storage 

Advice on common storage Keep in a dry, cool and well-ventilated place. 

Keep away from strong acids. 

Keep away from strong bases. 

Keep away from metals. 

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Exposure Guidelines 

Components with workplace control parameters 

Components CAS-No. Value Control Update Basis 

parameters 

Toluene 584-84-9 TWA 0.005 ppm 2010-03-01 ACGIH 

diisocyanate 

STEL 0.02 ppm 2010-03-01 ACGIH 

c 0.02 ppm 2006-02-28 OSHAZ-1 

0.14 mg/m3 

TWA 0.005 ppm 1989-01 -19 OSHA PO 

0.04 mg/m3 

STEL 0.02 ppm 1989-01 -19 OSHA PO 

0.15 mg/m3 

2-Methyl-m- 91 -08-7 TWA 0.005 ppm 2010-03-01 ACGIH 

phenylene 

diisocyanate 

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Engineering measures 

Engineering measures 

Personal protective equipment 

Eye protection 

Hand protection 

Skin and body protection 

Respiratory protection 

Hygiene measures 

Revision Date 01 /09/2014 Print Date 01 /09/2014 

I STEL I 0.02 ppm 1 2010-03-01 I ACGIH 

Use with local exhaust ventilation. 

Goggles 

Safety glasses with side-shields 

PVA 

Protective suit 

Use an air purifying respirator with organic vapor (OV) 

cartridges. For spray/mist applications, use an (N, P, or R) 

1 00 particulate filter in conjunction with the OV cartridge. 

Handle in accordance with good industrial hygiene and safety 

practice. 

Clean long legged, long sleeved work clothes. 

If splashing is possible, wear chemically resistant protective 

clothing. 

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 

Form 

Colour 

Odour 

Odor Threshold 

Flash point 

Ignition temperature 

Lower explosion limit 

Upper explosion limit 

pH 

Melting point/range 

Initial boiling point 

Vapour pressure 

Evaporation rate 

Density 

liquid 

light yellow 

not significant 

no data available 

> 100 'C (> 212 <>F) 

Method: 

> 200 'C (> 392 <>F) 

no data available 

no data available 

no data available 

< 0 'C (< 32 <>F) 

> 200 'C (> 392 <>F) 

at 1,013 hPa 

< 1 hPa 

no data available 

1.15 g/cm3 

at 20 'C (68 <>F) (1 ,013 hPa) 

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Water solubility 

Partition coefficient: noctanoVwater 

Relative vapour density 

Revision Date 01 /09/2014 Print Date 01 /09/2014 

immiscible 

no data available 

no data available 

SECTION 10. STABILITY AND REACTIVITY 

Conditions to avoid 

Materials to avoid 

Hazardous decomposition 

products 

Chemical stability 

no data available 

Strong oxidizing agents 

Acids and bases 

Metals 

no data available 

Stable; polymerization will not occur 

SECTION 11. TOXICOLOGICAL INFORMATION 

Acute oral toxicity (Product) 

Acute oral toxicity 

(Component) 

Acute dermal toxicity 

(Component) 

Acute inhalation toxicity 

(Component) 

no data available 

Component: - Urea urethane 

LD50 

no data available 

Component: 584-84-9 Toluene diisocyanate 

LD50 rat 

Dose: 5,800 mg/kg 

Component: 91-08-7 2-Methyl-m-phenylene diisocyanate 

LD50 rat 

Dose: 5,800 mg/kg 

Component: - Urea urethane 

LD50 

no data available 

Component: 584-84-9 Toluene diisocyanate 

LD50 rabbit 

Dose: > 9,400 mg/kg 

Component: 91-08-7 2-Methyl-m-phenylene diisocyanate 

LD50 

no data available 

Component: - Urea urethane 

no data available 

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Skin irritation (Product) 

Skin irritation (Component) 

Eye irritation (Product) 

Eye irritation(Component) 

Sensitisation (Product) 

Further information 

(Product) 

Revision Date 01 /09/2014 

Component: 584-84-9 Toluene diisocyanate 

LC50 rat 

Dose: 14 ppm 

Print Date 01 /09/2014 

Component: 91-08-7 2-Methyl-m-phenylene diisocyanate 

LC50 

no data available 

no data available 

Component: - Urea urethane 

rabbit 

Component: 584-84-9 Toluene diisocyanate 

rabbit 

Result: Moderate skin irritation 

Component: 91-08-7 2-Methyl-m-phenylene diisocyanate 

rabbit 

Result: Moderate skin irritation 

no data available 

Component: 584-84-9 Toluene diisocyanate 

rabbit 

Result: Eye irritation 

Component: 91-08-7 2-Methyl-m-phenylene diisocyanate 

rabbit 

Result: Eye irritation 

no data available 

no data available 

SECTION 12.. ECOLOGICAL INFORMATION 

Additional ecological 

information (Product) 

no data available 

SECTION 13. DISPOSAL CONSIDERATIONS 

Further information Dispose of in accordance with applicable local/municipal, 

state/provincial and federal regulations. 

SECTION 14. TRANSPORT INFORMATION 

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Container sizes: 55 gallon drums, 5 or 6-gallon pails, 2oz/16oz samples) 

DOT Not dangerous goods 

IAT A Not dangerous goods 

IMDG_US Not dangerous goods 

SECTION 15. REGULATORY INFORMATION 

HMIS Classification 

National Fire Protection 

Association (NFPA) Class 

Health hazard: 3 

Chronic Health Hazard: * 

Flammability: 1 

Reactivity: 1 

PPI :X 

1118 

Emergency Planning Community Right-To-Know (EPCRA) 

SARA 302 Components : Not applicable 

Print Date 01 /09/2014 

If listed below, this product contains toxic chemical(s) subject to the reporting requirements of Section 

313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. 

SARA 313 Components Toluene diisocyanate 584-84-9 0.3% 

SARA 311/312 Hazards Acute Health Hazard 

Chronic Health Hazard 

Toxic Substances Control Act (TSCA) 

TSCA Status TSCA Inventory - Not listed. FOR R&D USE ONLY. Pursuant to 

Section 5(h)(3) of TSCA and 40 CFR 720.36(c), this material 

can only be used for research and development purposes. 

In accordance with 40 CFR 720.36(b), any potential risks to 

human health or the environment will be explained in the 

MSDS. 

Clean Air Act & Related Information 

Non-volatile (Wt) 100% 

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Non-volatile information is not a specification. 

Hazardous Air Pollutants 

Toluene diisocynate 584-84-9 

If not listed above, this product does not contain HAPs at 1% or 0.1% or greater. Refer to Section 3 

for HAP weight percentage. 

Resource Conservation and Recovery Act 

EPA Hazardous Waste Not applicable. 

Code(s) 

State Laws 

Massachusetts Right To Toluene diisocyanate 584-84-9 

Know Components 

2-Methyl-m-phenylene 91-08-7 

diisocyanate 

Pennsylvania Right To Urea urethane - Know Components 

Toluene diisocyanate 584-84-9 

2-Methyl-m-phenylene 91-08-7 

diisocyanate 

Benzoyl Chloride 98-88-4 

New Jersey Right To Urea urethane - Know Components 

Toluene diisocyanate 584-84-9 

New Jersey Trade Secret NOT AVAILABLE 

Registry Number for the 

product (NJ TSRN) 

California Prop. 65 This product does not contain any chemicals known to State of 

Components California to cause cancer, birth defects, or any other 

reproductive harm. 

Does not contain heavy metals (according to formulation). 

CONEG Heavy Metal: We certify that this product does not contain Lead, Mercury, Cadmium or 

hexavalent chromium in the sum concentration of 100 ppm by weight or greater. 

Canadian Environmental Protection Act 

Domestic Substances List 

DSL Status Not listed 

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WHMIS Classification D1A 

D2A 

D2B 

SECTION 16. OTHER INFORMATION 

Further information 

Print Date 01 /09/2014 

The information provided in this Safety Data Sheet is correct to the best of our knowledge, 

information and belief at the date of its publication. The information given is designed only as a 

guidance for safe handling, use, processing, storage, transportation, disposal and release and is 

not to be considered a warranty or quality specification. The information relates only to the 

specific material designated and may not be valid for such material used in combination with any 

other materials or in any process, unless specified in the text. 

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