**AQS ID: Audit Date:**  **Audit Type:**



### Degrees Minutes

Latitude 33 21.799 Longitude 117 5.416 Altitude (Ft.) 335

Teledyne 400E

1.03500 -1.40000



### 087 1

**Manufacturer/serial #** API 401 258-S **Concentration Cert. expiration date** 



### Model # **Serial # Certification**  **expiration**

Comments:

**Instrument Ozone**  **CO Manufacturer**  TECO TECO

**Instruments** 49C PS

Transfer 201 713 

### TTP Audit Site Information

**SO2 NO/NOX** 



### Station Instrument Information

**CO Ozone**  1.62600 **Intercept Model**  **Serial Number Pala**  **Kevin Woodruff / ICF International**

**SO2 NO/NOX** 



### Station Pollutant Standards

**CO Calibration Date**  **Site Name: Auditor:**  **Station Manager:**

**Standards Calibration Date**  **Slope** 2/6/11 0.99880

**Ozone**



### Station Gas calibrator(s) **Manufacturer Notes**  **Type** 48C 703 Calibrated on day of audit 

### AUDIT AGENCY

2" glass manifold **AQS Method Code / POC** 

### GPS Readings

**TTP PE Lab Instument and Standards**

**Slope/Intercept Indicated Flow**  Bi-weekly 752 mL/min **NPAP-TTP 060731201**  **5/23/2011 Frank Spurgeon** 

**In-Line Filter Change Manifold type**  **Manufacturer/Model # Property Number** 

**Local Primary Standard** PHOTOMETER (VERIFIED)

### Site Name: Pala AQS ID: 060731201 Auditor: Kevin W oodruff / ICF International Audit Date: 05/23/11 Site Manager: Frank Spurgeon

**Environics Ozone**  **setting Inside**  **Outside %D**  **corrected for zero**  **0.39 Pre Z** **ero 0.0008**  **0.0008 0.15**  **0.150 0.1477**  **0.1476 -0.07**  **0.27 0.080**  **0.0769 0.0777**  **1.05 1.0027**  **0.050 0.0498**  **0.0499 0.20**  **Post Z ero**  **0.0008 0.0008**  **Ave. Z ero**  **0.0008 0.0008**  **Date** 2/6/2011 **Slope** 0.9988 **Intercept** 0.1626

**Audit Point #**  **Audit Point**

**Description Environics** 

**Ozone setting**  **NPEP**

**Thermo 49 CPS**  **Response (ppm)**  **NPEP Thermo**

**49 CPS Corrected for**  **line loss (ppm) Audited Station** 

**Response (ppm)**  **%**

**Difference 1**  **Level 5 O3 0.400**  **2 Level 4 O3**  **0.250 3**  **Level 3 O3 0.150**  **0.1444 0.145**  **0.112 -22.6**  **4 Level 2 O3**  **0.080 0.0763**  **0.077 0.052**  **-33.0 5**  **Level 1 O3 0.050**  **0.0486 0.049**  **0.029 -40.0**  **6 Ze** **ro 0.000**  **0.0004 0.000**  **0.001** 

## Average %

**Difference -31.9** 

**NPEP Thermo 49 CPS Verification**



# Ozone Audit 

# Ozone Line Loss Test (04/27/11)

**Current Qtr. Line Loss= Current Line Loss Factor=**  **Ave % Difference=**  **Prev. Qtr Line Loss=**



# TTP Ozone A**udit**Site Name: Pala AQS ID: 060731201

Auditor: Kevin Woodruff / ICF International Audit Date: 05/23/11 Site Manager: Frank Spurgeon 

### Color Code: = data from the TTP trailer - auditor fills in = data from the TTP trailer - auditor fills in post audit = data from the audited station - auditor fills in = data for computation and results, values imported from "Audit Fill In Chart Step By Step" = data for CO calibration cylinder, auditor fills in
**Cylinder CO**  **SO2 NO**  **NOx Serial #**  **CGA VA** **LVE** Ultrapure 0 0 0 0 **CC67179** 590 Brass High CO 40.2 0 0 0 **FF13044** 590 Brass Low CO 8.31 0 0 0 **CC56848** 590 Brass Superblend 10220 102.7 107 107 **JA 02451**  660 SS Superblend NO2 impurity (ppm) 0.0

**Instrument Response**  **True Value % Difference**  Pre Audit Ultrapure Zero 0.00 High CO 40.20 #VALUE! Low CO 8.32 #VALUE! Environics zero 0.00 Post Audit Environics zero 0.00 

### Array for regression calculation for CO analyzer **NPEP Cylinder Information**

**NPEP CO A naly** **zer Calibration**

Post Audit Environics zero 0.00 Ultrapure Zero 0.00 High CO 40.20 #VALUE! CO Analyzer slope #DIV/0! CO Analyzer Intercept #DIV/0! #DIV/0! #DIV/0!

Audit Point # Audit Point Description Environics Concentration Setting Environics

Ozone Setting NPEP Thermo

48C CO reading SO2 CO NO NO2 NOx 1 Pre Zero 0.00 2 Level 5 CO, SO2, NO/Nox 67.29 3 Level 5 NO2 67.29 0.350 4 Level 4 NO/Nox 5 Level 4 NO2 0.155 6 Level 4 CO, SO2, Level 3 NO 23.93 7 Level 3 NO2 23.93 0.055 8 Level 3 SO2, Level 2 NO 8.97 9 Level 3 CO 8.45 10 Post Zero 0.00 

### *Prior to starting the audit, clear cells by 1) highlighting cells F39 to K48, 2) right clicking the mouse, 3) and clicking "clear contents"*

Station Analyzer readings 

# Au **dit Fill In Chart Step By Step**Audit Point # Audit Point Description Environics Low MFC Setting NPEP Thermo

48C CO reading SO2 CO SO2 CO SO2 CO 1 Pre Zero 0.00 0.00 2 Level 5 SO2/CO 67.29 0.00 6 Level 4 SO2/CO 23.93 0.00 8 Level 3 SO2 8.97 0.00 9 Level 3 CO 8.45 0.00 10 Post Audit Zero 0.00 0.00

Audit Point # Audit Point Description Environics Low MFC Setting NPEP Thermo

48C CO reading NO NO2 NOx NO NO2 NOx NO NOx 1 Pre Zero 0.00 0.00 2 Level 5 NO/NOx 67.29 0.00 4 Level 4 NO/NOx 0.00 6 Level 3 NO/NOx 23.93 0.00 8 Level 2 NO/NOx 8.97 0.00 10 Post Audit Zero 0.00 0.00 #VALUE! #VALUE! NPEP Trailer Readings Actual Concentration (ppm)

NPEP Trailer Readings

## SO2 and CO Station A**udit**

**NO and NOx Station A udit**  Actual Concentration (ppm) Station readings (ppm) % Difference Station readings (ppm) % Difference

10 Post Audit Zero 0.00 0.00 #VALUE! #VALUE!

Audit Point # Audit Point Description Environics Low MFC Setting Environics

Ozone Setting NPEP Thermo

48C CO reading NO original (Pre

O3 addition) NO Remaining NO2 NOx NO NO2 NOx % NO2 Bias 2 Zero NO2 67.29 0.000 0.00 3 Level 5 NO2 67.29 0.350 0.00 5 Level 4 NO2 0.155 0.00 7 Level 3 NO2 23.93 0.055 0.00

NO NOx NO2 SO2 CO Slope #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! Intercept #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

A B C

#VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE! Average converter efficiency= #DIV/0! 

## NO2 Station A**udit**

delta NO Delta NOx Conversion Efficiency Station readings (ppm) Actual Concentration (ppm) NPEP Trailer Readings



### Regression Curves

**Converter Efficiency**

### Site Name: Pala AQS ID: 060731201 Auditor: Kevin Woodruff / ICF International Audit Date: 05/23/11 Station Manager: Frank Spurgeon

Instrument: Ozone CO Manufacturer: TECO TECO Model: 49C PS 48C Serial Number: 713 703 Calibration Date: 02/06/11 Calibrated Slope 0.9988 on Intercept 1.626 day of audit

STATION INSTRUMENT INFORMATION Instrument: Manufacturer/Model #: Teledyne 400E Property Number: Calibration Date: Slope/Intercept: 1.0350 -1.4000 Indicated Flow: In-Line Filter Change: Manifold Type:

Pass/Fail Warning Ozone Audit Level 5 **N/A** Ozone Audit Level 4 **N/A** Ozone Audit Level 3 **Fail** Ozone Audit Level 2 **Fail** Ozone Audit Level 1 **Fail** Audit Limits Auditor Pass Less than or equal to ±10% Print Fail Greater than ±10% Warning Greater than ±7% Signature EPA person notified in case of audit failure
Comments: 0 **0.077 0.052**  **-33.0**

**0.145**

**0.000 0.001**  **0.049 0.029**  **-40.0 0.112**  **-22.6 NPEP THROUGH-THE-PROBE A** **UDIT REPORT**

MOBILE PE LAB INSTRUMENTS

Bi-weekly 2" glass manifold 752 mL/min 201 01/00/00 **AU DIT A** **GENCY**

Ozone **OZONE REPORT**

**NPEP O3 Concentration**

**(ppm) PRELIMINA** **RY OZONE A UDIT RESULTS**  **Site Response (ppm)**  **Percent Difference**

## Site Name: Pala AQS ID: 060731201 Auditor: Kevin Woodruff / ICF International Audit Date: 05/23/11 Station Manager: Frank Spurgeon

Instrument: Ozone CO Manufacturer: TECO TECO Model: 49C PS 48C Serial Number: 713 703 Calibration Date: 02/06/11 Calibrated Slope 0.9988 on Intercept 1.626 day of audit

STATION INSTRUMENT INFORMATION Instrument: Manufacturer/Model #: 0 0 Property Number: Calibration Date: Slope/Intercept: 0.00 0.00 Indicated Flow: In-Line Filter Change: Manifold Type:

Pass/Fail Wa rning CO Audit Level 5 **N/A** CO Audit Level 4 **N/A** CO Audit Level 3 **N/A** Audit Limits Auditor Pass Less than or equal to ±15% Print Fail Greater than ±15% Wa rning Greater than ±10% Signature EPA person notified in case of audit failure
Comments: 0 **PRELIMINA RY CARBON MONOXIDE A** **UDIT RESULTS NPEP CO Concentration** 

**(ppm) Site Response**  **(ppm) Percent Difference**  **NPEP THROUGH-THE-PROBE A UDIT REPORT** 

**AUDIT AGENCY**

MOBIL PE LAB INSTRUMENTS

CO **CARBON MONOXIDE REPORT**

0 01/00/00 0 1/0/1900Site Name: Pala AQS ID: 060731201 Auditor: Kevin Woodruff / ICF International Audit Date: 05/23/11 Station Manager: Frank Spurgeon

Instrument: Ozone CO Instrument: Manufacturer: TECO TECO Manufacturer/Model #: 0 0 Model: 49C PS 48C Property Number: Serial Number: 713 703 Calibration Date: Calibration Date: 02/06/11 Calibrated Slope/Intercept: 0.000 0.000 Slope 0.9988 on Indicated Flow: Intercept 1.626 day of audit In-Line Filter Change: Manifold Type:

Pass/Fail Wa rning Wa rning **N/A N/A**  **N/A N/A** 

Audit Limits Pass Less than or equal to ±15% Fail Greater than ±15% Wa rning Greater than ±10% Converter Efficiency Audit Limits Pass Between 96% and 104% Fail <96% or >104% Wa rning Between 96%-97% or 103%-104%

Pass/Fail Wa rning Auditor **N/A N/A**  **N/A N/A**  **N/A N/A** 
Comments: EPA person notified in case of audit failure 0 **Converter Efficiency**  **NPEP NO 2** **Concentration**

**(ppm) Percent**  **Difference Percent**  **Difference 0.000**  **SITE RESPONSE (ppm)**  **NPEP NO X** **CONCENTRATION**

**(ppm) NPEP NO Concentration** 

**(ppm) Site Response**  **(ppm) NITROGEN OXIDES REPORT** 

01/00/00 0

Signature

Print **PRELIMINARY NO 2** **AUDIT RESULTS** NOx Audit Level 1 **N/A**

**Site Response (ppm)**  NOx Audit Level 3 NO Audit Level 3 **N/A N/A**  **N/A** NO Audit Level 4 NOx Audit Level 2 **PRELIMINARY NO AUDIT RESULTS PRELIMINARY NOx AUDIT RESULTS** 

Pass/Fail NOx Audit Level 4 **Percent Difference**  1/0/1900 0 **NPEP THROUGH-THE-PROBE AUDIT REPORT**

**AUDIT AGENCY**

MOBIL PE LAB INSTRUMENTS NO/NOX STATION INTRUMENT INFORMATION

Converter Efficiency Point 3 Converter Efficiency Point 2 Converter Efficiency Point 1 NO Audit Level 2

NO2Audit Level 4 NO2Audit Level 3 NO2Audit Level 5 NO Audit Level 1

### Site Name: Pala AQS ID: 060731201 Auditor: Kevin Woodruff / ICF International Audit Date: 05/23/11 Station Manager: Frank Spurgeon

Instrument: Ozone CO Manufacturer: TECO TECO Model: 49C PS 48C Serial Number: 713 703 Calibration Date: 02/06/11 Calibrated Slope 0.9988 on Intercept 1.626 day of audit

STATION INSTRUMENT INFORMATION Instrument: Manufacturer/Model #: 0 0 Property Number: Calibration Date: Slope/Intercept: 0.000 0.000 Indicated Flow: In-Line Filter Change: Manifold Type:

Pass/Fail Warning SO2

### Audit Level 5 **N/A** SO2

### Audit Level 4 **N/A** SO2

### Audit Level 3 **N/A** Audit Limits Auditor Pass Less than or equal to ±15% Fail Greater than ±15% Warning Greater than ±10% EPA person notified in case of audit failure
Comments: 0 **NPEP SO 2** 

### Concentration

**(ppm)** 0 01/00/00 0 SO2

Signature 1/0/1900 0

Print **PRELIMINA RY SULFUR DIOXIDE A** **UDIT RESULTS Percent Difference** 

**Site Response (ppm)**  **PRELIMINA RY** 

**NPEP THROUGH-THE-PROBE A UDIT REPORT**  **AU DIT A** **GENCY**

MOBIL PE LAB INSTRUMENTS **SULFUR DIOXIDE REPORT**

### Site Name: Pala AQS ID: 060731201 Audit Date: 5/23/2011

**N/A N/A**  **Fail Fail**  **Fail**

**N/A N/A**  **N/A**

**N/A N/A**  **N/A N/A**  **N/A N/A**  **N/A N/A**  **N/A N/A**  **N/A N/A**  **N/A N/A** 

**N/A N/A**  **N/A** *** = CFR Appendix A Audit Levels** Ozone Audit level 5*

-40.0 -33.0 0.029 -22.6 0.049 0.112 0.052

NO Audit Level 2 NO Audit Level 1 **SUMMARY AUDIT REPORT AUDIT AGENCY** 

**Ozone Parameter**  **NPEP Lab Response (ppm)**  **Station Response (ppm)**

NO2 Audit Level 4* NOx Audit Level 4 NOx Audit Level 3 NOx Audit Level 1 NOx Audit Level 2
NO2 Audit Level 5* **Percent Difference**  **Pass/Fail**

SO2 Audit Level 3* NO2 Audit Level 3*

**Sulfur Dioxide** Converter Efficiency NO2 Audit Level 5* Converter Efficiency NO2 Audit Level 4* Converter Efficiency NO2 Audit Level 3*

SO2 Audit Level 5* SO2 Audit Level 4* **Oxides of Nitrogen** Ozone Audit level 4* Ozone Audit level 3* Ozone Audit level 2*

CO Audit Level 5* Ozone Audit level 1*

NO Audit Level 4 NO Audit Level 3 **Warning**

CO Audit Level 4* CO Audit Level 3* 0.145 0.077**AQSSiteID AuditDate**  **Pollutant POC**  **Method ActLev1**  **IndLev1 ActLev2**  **IndLev2 ActLev3**  **IndLev3 ActLev4**  **IndLev4 ActLev5**  **IndLev5 AuditType**  **Local Primary Standard**

060731201 5/23/2011 44201 1 087 0.049 0.029 0.077 0.052 0.145 0.112 NPAP-TTP PHOTOMETER (VERIFIED) 060731201 5/23/2011 42101 0 0 NPAP-TTP 0 060731201 5/23/2011 42401 0 0 NPAP-TTP 0 060731201 5/23/2011 42601 0 0 NPAP-TTP 0 060731201 5/23/2011 42603 0 0 NPAP-TTP 0 060731201 5/23/2011 42602 0 0 NPAP-TTP 0 RA|I|06|073|1201| |1|1|007| |||20110523|AUDIT NOT BY RO| |NPAP-TTP|ANALYTICAL|||| RA|I|06|073|1201|44201|1|1|1|007|087|||20110523|AUDIT NOT BY RO|PHOTOMETER (VERIFIED)|NPAP-TTP|ANALYTICAL||||0.049|0.0294|0.077|0.0516|0.145|0.1123| | | | | RA|I|06|073|1201|42101|0|1|1|007|0|||20110523|AUDIT NOT BY RO|0|NPAP-TTP|ANALYTICAL|||||||||||||| RA|I|06|073|1201|42401|0|1|1|007|0|||20110523|AUDIT NOT BY RO|0|NPAP-TTP|ANALYTICAL|||||||||||||| RA|I|06|073|1201|42601|0|1|1|007|0|||20110523|AUDIT NOT BY RO|0|NPAP-TTP|ANALYTICAL|||||||||||||| RA|I|06|073|1201|42603|0|1|1|007|0|||20110523|AUDIT NOT BY RO|0|NPAP-TTP|ANALYTICAL|||||||||||||| RA|I|06|073|1201|42602|0|1|1|007|0|||20110523|AUDIT NOT BY RO|0|NPAP-TTP|ANALYTICAL||||||||||||||



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