P.1 

OAR Box 1867 

Prepped by Ollie Stewart 

Document Number: 

67) ll-B-121 

Docket Number: 

A-90-19 

Printed 12/2/2008 6:27:23 AM Sheet 67 of 95 
P.2 

MEMORANDUM 

TO: Process Vents Docket A-90-19 

FROM: Wanda Floyd 

DATE: November 1991 

A-90-19 

ll-B-121 

\ 

!=1 

SJLLli l 

„ ,. __ _ -_j 

SUBJECT: HON NESHAP: Industry Characteristics/ Acetophenone^ ^»R gQ0<f= 

A product-process summary (PPS) was not formed on this particular chenjieal because it 

was found to be a by-product of phenol(108952A). Therefore, reference should be made 

to all sections of phenol except section 2D. 

i~RtfFn<7: 

Sdilii laiiilii f M 

icon 

irance A-90-19 

x ll-B-252 
P.3 

f\ 

Preparer: 

Date: * /?. i/to 

Reviewer: 

ADMINISTRATIVE NOTES 

Pnjdittt~PfOce$$ Code tftitd A 

Hours spent on this PPS , ?* ' 

P-P Name 

Incomplete Items (parts of 

form you cannot complete) 

Mine » and description) Date Cleared Initials 

ficc/opJLefio** / 3 " fy -j>'S«cf • 3 / f/**+/ /fo* ffr/fm 

fee £ Jen Ad? . 

j>ert*rr*f ^/-us^s. 

Chemicals missing CAS numbers 

Plant with Citv but no Countv (plant name, city, state) 
P.4 

Preparer: fc/ /1/ r 

Date: ?/>/4> 

Reviewer: 

Chej&itar H«i HtthpU**^ 

PRODUCT-PROCESS SUMMARY (PPS) 

•opt 

AlternativeCtemical Hants pne*yl y^ciJijI KcYo»< 

CAM M°i7~ 

Karen Flf W-ClfeiRtcaT Nunfre> MA** 

CHEMICAL SPECIFIC INFORMATION 

1.0 U.S. Production Ref # , Pg I , Ref Year 

(indicate the same reference information for any answers below from a 

different reference) 

LI Urr^T^rprwfucifeft (circle on*) millions of ko or millions of gallons 

1.2 U, S» Cieacitji 

1.3 V* s:' c$*cl ty tmi Nation 

I,A $;:$; 

1.7 Product Price 

1.7*1 Wft$PrM& 

I.jr*2 IM%'ji£¥M$HHHH| $/Kq qr S/qaHQn 

1.8 Comments 
P.5 

2.0 Chemical End-Use Ref # , Pg # ' Ref ye a r 

1&2 Percent 

/(]* d^ 
3.0 U.S. Producers Ref # ., Pg # ., Ref Year 

iPli, 9B£l millions of ko or millions of gallons 

3.2 Name, Location, and Capacity 

Location, 

Process Used 

(use P-P #) ts? 

Total Capacity 
P.7 

PRODUCT-PROCESS SPECIFIC INFORMATION 

4.0 Potential Product-Processes (P-P) Ref I , Pg I 

Commercially % Nat'l 

Items. Viable (y/n) capacity 

p-p 1 

P-P 2 

P-P 3 

P-P 4 

P-P 5 

P-P 6 

4.1 Documentation of P-Ps Excluded 

P-P not 

Commercially Viable Reasons 

in t&t$* 
P.8 

gra« n Ref # , pg # 

Air Oxidation Reaction 

Oxidation Reaction 

Alkylation Reaction 

Carbonylation Reaction 

Halogenation Reaction 

Condensation Reaction 

Dehydrogenation Reaction 

Dehydrohalogenation Reaction 

Esterification Reaction 

Hydrogenation Reaction 

Hydrohalogenatlon Reaction 

Hydroformylatlon Reaction 

Hydrolysis Reaction 

Nitration Reaction 

Oxyacetylation Reaction 

Oxyhalogenatlon Reaction 

Sulfonation Reaction 

Catalytic Reformation 

Hydrodimerizatlon Reaction 

Generic Reaction 

4.4 Explain how you selected the reaction type in line 4.3. 
P.9 

4.5 Written Description 

In the left margin, indicate references and page numbers throughout written 

description. 
P.10 

5.0 Process Flow Diagram (attach at end of package) 

5.1 Flow Diagram Reference: Ref # , Pg # 

5.2 Comments on Flow Diagram 

M* Proms 

Component Types 

Distillation Columns 

Absorbers 

Strippers 

Reactors 

Condensers 

Vaporizers 

Others 

Ref I ., Pg # 

:::x:x^;<404:^:<&«&c<M<tf<35&$ 
P.11 

6.0 Chemical Data 

6.1 Balanced Chemical Reactions Ref # ., Pg # 

6.2 Chemical Tree Ref # ., Pg # 
P.12 

6.4 Stoichlometry Ref # f pg # 

Show calculations and assumptions and then summarize in table on next 

page. 
P.13 

St<ftfolet^ 

um mm ~ ""• * " 

yxvftWxW :x->x:x*x-x« 

6.4.1 Product 

6.4.2 Raw Material(s) 

#1 

#2 

#3 

#4 

#5 

6.4-3 Co-PrQduct$ 

#1 

#2 

#3 

#4 

#5 

6.4.4 Bv-Products 

#1 

#2 ._ 

#3 

#5 

§•4,5. Intermediate? 

# 1 • 

#2 
P.14 

6.4 Stoichlometry Conversion Factors 

a) m^m^wrwrmmim 

c) Cfeti***!*! Factor for co-Pt&Juct t% 

d) Conversion fttUt for Cft-frwfite* 13 

e) Conversion factor"fflr Ce-FttttfkftK i f 

f) Conversion Factor Comments 
P.15 

7.0 Process Vent Emission Sources 

*•* JM*SMHP$»&& ***t mtesnnst (Y/N) 

7*2 WflggffiW>M»i;«ifssl08S| (Y/N) Ref I , Pg # 

7.3 Comments Ref # , Pg # 

7.4 Reactor vent efe1ssfoj*s? (Y/N) Ref # , Pg # 

7.5 Comments Ref I , Pg # _ 
P.16 

«r$&fssf<m$$ •VCSWA->^ .• «. A * 

Ji&sdsZjf. £.?/<<** * 

7.8 •""""" 

(Y/N) Ref # ., Pg # 

7.9 Comments Ref # 

.» Pg # 
P.17 

8.0 Transfer Emission Sources 

& -r ^JllllP^^« c t $ Transferred 

8.2 Mhat fa-H arslransFerred? 

Ref # ., Pg # 

(Y/N) 

8.2.1 Product 

8.2.2 Co-Products 

8.3 Comments Ref # ., Pg # 
P.18 

9.0 Storage Emission Sources Ref # , Pg # 

9.* * ArCJH^n * stored? (Y/N) 

9.2 What;Mterlals are stored? 

Storage Service 

CAS I Type 

9.2.1 Product 

9.2.2 Co-Products 

9.2.3 Raw Materials 

9.2.4 Intermediates 

9.4 Comments 
10.0. Wastewater Emission Sources 

10.2 Describe wastewater 

P.19 

Ref # ., Pg * 

(Y/N) 

Stream Equipment Component 

Number Producing Wastewater Comments on flow 

#1 

#2 

#3 

10.3 Stream Composition 

(provide only if readily available) 

Stream #1 

Ref # 

Steam #2 

., Pg # 

Organics Organics 

HAPs HAPs 

Water 

Other 

Water 

Other 
Stream #3 

Organics . 

HAPs 

Water 

Other 

P.20 

10.4 Comments Ref # __, Pg §