### 1544 Sawdust Road, Suite 302, The Woodlands TX 77380 281.292.0636, fax: 281.298.2550 http://www. denovo-nv.com 

# 2007 INITIAL RELATIVE ACCURACY TEST AUDIT (RATA) ON THE NITRIC ACID TAIL GAS UNIT CEMS COFFEYVILLE RESOURCES NITROGEN FERTILIZERS COFFEYVILLE, KANSAS

Final Report

DNV-5283.02

### 1544 Sawdust Road, Suite 302, The Woodlands TX 77380 281.292.0636, fax: 281.298.2550 http://www. denovo-nv.com January 11, 2008

Mr. Doug Robker Coffeyville Resources Nitr ogen Fert ilizers P.O. Box 5000 Coffeyville, Kansas 67337

Re: 2007 CEMS Initial Certification Test for the Nitric Acid Tail Gas Unit, Coffeyville Resources Nitrogen Fertilizers Facility Coffeyville, Kansas

Dear Mr. Robker:
Enclosed are 3 hard copies and 1 copy on CD of the final test report for the 2007 Initial CEMS Certification Test for the Nitric Acid Tail Gas Unit at the Coffeyville Resources Nitrogen Fert ilizers facility located in Coffeyville, Kansas.
If you have any questions or comments, please do not hesitate to call me at: (281)292-0636 Ext. 14. Denovo appreciates th is opportunity and we look forward to continuing our successful and lasting relationship.
Sincerely,

Louis M. Esposito

LME/th Enclosures

## SUM M A RY

Den ov o Gl obal Technol og ies , I nc. ( Den ov o) co nduct ed th e Ini ti al CE MS C erti ficat ion
Test o n the N it ri c A ci d Tail Gas U nit ( NA TGU) EU -1 004, Con ti nuous Emi ss ion s Monito ring Systems (CEMS) associate d w ith Cof f eyv ille Resources Nitrogen Fertiliz ers (C RN F) pl ant o per ati ons, C off ey v il le, Kans as. Test ing w as condu cte d for the p oll utant

x 2 

### Ox ide s o f Ni tr og en ( NO ) and di lue nt O x y g en ( O ). Thi s t est w as per formed to pr ov ide
document ati on of compl ian ce w it h q ual it y as sur ance pr ov is ion s c ontai ned i n Kans as Dep ar tment of Heal th an d Env ir onment o per ati ng per mit.

The tes ti ng w as condu cte d on Oct ober 11, 2007. The tes t pr ocedu re s w er e per formed
in accorda nce wi th 40 CFR, Part 60 , App end ix F, Section 5.1. 1 using perf orma nce specif ication proced ures 2 an d 3, loca ted in 40 CFR Part 60, Ap pen dix B. EPA T est

2 x 

### Me t h o d s 3 A a n d 7 E we re u t il ize d f o r c e rt if ic a t io n o f O a n d NO re s p e c t ive ly.

Mr . D oug R obker

of CR NF w as the p ro

jec t c oor din ator

. The team l eader for D enov o

w as Mr . Lou is Es posi to.

Bas ed on t he resu lt s o f th is t est , t he Ni tr ic A cid T ail Gas U ni t pass ed th e In it ial
CEMS certific ation and 7 Day Drift Performa nce Certific ation.

L o u i s M

. E sp o si to
Pro ject M ana ger De No v o-nv , Inc

.

### i 

## TABLE OF CONTENTS

SEC TI ON PAGE

S E C T I O N 1

. 0 I N T R O D U C T I O N

... ... ... ... ... ... ... ... ... ... ... . Pag e - 1-

SECT ION 2.0 TES T M ET HOD AND EQUIPMENT SUMMARY

. . . . . . . . . Pag e - 2-

SE C TI ON 3 .0 S U M M AR Y O F TE ST R ES U LTS

. . . . . . . . . . . . . . . . . . . . . . Pag e - 3-
SEC TION 3.1 R ELATIVE AC CU RA CY AN D 7 D AY

D RI FT TEST

. . . Pag e - 3-
SEC TION 3.2 SAM PLIN G AN D AN ALY TICAL PR OC ED UR ES

. . . . . Pag e - 3-
3

. 2

. 1 R M I n s t r u m e n t a t i o n

... ... ... ... ... ... ... ... ... . . Pag e - 3-
3.2 .2 RM C alibratio n Proce dure

. . . . . . . . . . . . . . . . . . . . . . . . Pag e - 4-
3

. 2

. 3 R M S a m p l i n g P r o c e d u r e

... ... ... ... ... ... ... ... . Pag e - 4-
3.2.4 RM D ata C oll ect ion and Red uct ion

. . . . . . . . . . . . . . . . . Pag e - 4-
3.2.5 7 D ay

D ri ft Dat a C oll ect ion and Red uct ion

. . . . . . . . . . . . Pag e - 5-
SEC TION 3.3 U nit M ass Emi ss ion D eter minat ion

. . . . . . . . . . . . . . . . Pag e - 5-

T able 3-1: Nitric Acid T ail Gas Unit CEMS Relativ e Accura cy Te st

. . . . . . . . . Pag e - 6-

T able 3-2: Nitric Acid T ail Gas Unit CEMS 7 Day Dri f t Te st

. . . . . . . . . . . . . Pag e - 6-

Table 3- 3: N it ri c A ci d Tail Gas U nit Emi ss ion D ata

. . . . . . . . . . . . . . . . . . Pag e - 7-

AP PE N D IX

A - C EM S R EL ATI VE A C C U R AC Y D ATA

. . . . . . . . . . . . . . . . . . . . . . . . . . . A P P E N D I X

B - C E M S 7 D A Y D R I F T D A T A

... ... ... ... ... ... ... ... ... ... ... . . A P P E N D I X

C - U N I T E M I S S I O N A N A L Y S I S

... ... ... ... ... ... ... ... ... ... ... . APPEN DI X

D - GAS C ALIBR ATION C ER TIFIC ATES

. . . . . . . . . . . . . . . . . . . . . . . . . . . A P P E N D I X

E - E X A M P L E C A L C U L A T I O N S

... ... ... ... ... ... ... ... ... ... ... . A P P E N D I X

F - Q U A L I T Y A S S U R A N C E

... ... ... ... ... ... ... ... ... ... ... ... .

### Pag e - 1- 

## SEC TION 1.0 INT ROD UC TION

Den ov o c onduc ted a n Ini ti al Cer ti ficat ion Test on the CE MS ser v ing the Ni tr ic Ac id Tail Gas Unit ope ration s at the CRN F fa cility in Co f f eyv ille, Kansa s. Th e Initia l Certificat ion T est

ser ies w as condu cte d w hil e the uni t w a s o p e ra ti ng at a > 90% loa d c ondi ti on. The Ini ti al
Cer ti ficat ion te st c ondi ti on c onsi ste d of a mi nimum o f (9) tw enty -o ne mi nute ru ns and a 7 day per formance dr ift t est

.

T he su bseque nt sect ions of this report prese nt results f or the te sts as f ollows:

Sect io n 2.0

— T est Meth od a nd Equipm ent Sum ma ry Sect io n 3.0

— Summary of Test R esul ts

T he a ppe ndice s provi de d ocum ent ation a nd su ppo rting data. T he a ppe ndice s are organiz ed a s f ollows:

A pp end ix A

— CE M Rel ati v e Ac cur acy D ata
A pp end ix B

__ CE MS 7 D ay D ri ft Dat a
A pp end ix C

__ Unit Em ission Ana ly sis
A pp end ix D

__ Gas C ali br ati on C erti ficat es
A pp end ix E

__ Ex ample Cal cul ati ons
A pp end ix F

__ Quality Assurance

### Pag e - 2-



## SECTI ON 2.0 T EST METHOD AND EQUI PMENT SUMMARY

The tes t pr og ra m w as desi g ned t o pr ov ide dat a f o r docu mentati on of compl ian ce w it h
federal r eg ula ti ons ass oci ated with N ew Sour ce Poi nt S tandar ds (N SPS) and sta te

ope rating perm it requireme nts r elate d to the initial certif ication of the CEMS u n its.

x 

### Spe cif ically , testin g f or t he CRNF f acility co nsisted o f

samp ling on th e Am ete k NO CEMS

s e rvi n g t h e Ni t ri c A c id T a il G a s Un it

. O 2 s a m p li n g wa s p e rf o rm e d t o ve ri f y sys t e m in t e gr it y. The foll ow ing i s a des cr ipt ion of the C EM S:

Ni tr ic A cid T ail Gas U ni t CE MS

x 

### NO Anal y z er

- Ametek
I.D N o. 81 61T
Mo del : 400 0B

x 

### Spa n Range-0-50 0 pp m NO

T h e P la n t Da t a A c qu is it io n S ys t e m (D A S ) i s m a n a ge d b y a Ho n e ywe ll T o t a l D is t ri b u t ive
Con tr ol (TD C) pr oces sor w hic h c ompil es data poi nts from th e u nit C EM S i nto t he
Ho n e yw e ll P la n t His to ry Da ta b a se (PH D). T h e PHD syst e m pro vide s o n e m in u te ave ra ge data.

T he N it ri c A ci d Tail Gas U nit F lue Gas sa mples ar e ex tr act ed from t he s our ce and
tr anspo rt ed by

heat ed l ine to the C EM sh elt er

. The sampl e i s t hen c ondi ti o n e d a nd th e CE MS i s a ll ow ed to dr aw a dr y co ndi ti oned s ample.

### Pag e - 3- 

## SECTI ON 3.0 SUMMARY OF TEST RESULTS

A sum ma ry

of the CEMS Initia l Perf orma nce T est an d 7 Day Drift are giv en in Tab le 3-1

SEC TI ON 3.1 R ELA

TI VE A CC UR

A CY A ND 7 D A

Y D RI FT T EST

Rel ati v e Acc ur acy (R A) tes ti ng w as per formed on the N it ri c A ci d Tail Gas U nit to ev alu ate

x 

### the Rel ati v e Accur acy

of the uni t NO analy z er

on Oct ober

11, 2007. A minimum o f nine
test run s w ere use d to calcu late th e average fo r the f inal RA det ermin ation f or the CEMS
d a ta. This av er ag e w as then compar ed w it h the R eferenc e M ethod (R M) av e ra ge cal cul ati ons to de ter mine the u n it rel ati v e ac cur acy

. The RA Per formance Spec ific ati on

x 

### for N O ca lc ula ti ons spec ifies the CE MS to be w it hin 20% of the R M v alu e, or 10% o f the

2 

### app licable sta nda rd. O m onito ring w as perf orme d to v erif y sy stem integrity

during the test

ser ies

.

The 7 day dri ft tes t w as per formed f ro m Nov ember 09, 2007 thr oug h Nov ember 15, 2007

w hic h c onsi ste d of moni tor ing the dai ly ins tr ument Zer o and Sp an c ali br ati on to dete rmi ne

x 

### ov er all i nst ru ment s tabi li ty . The I nit ial dr ift per formance sp e cif icati on for NO anal y z er

re q uir es that the d a ily l o w e n d a n d hi g h end cal ibr ati on c heck be w it hin ± 2.5% of span
each day for seven conse cutive days w ith no e x terna l maint ena nce a djustm ent s. Delay in

p e rf o rm a n ce of

the 7 day

dr ift w as the r esul t of the Ni tr ic Ac id Tail Gas U nit bei ng sh ut
dow n from O cto ber

19, 2007 t hr oug h N ov ember 01, 2007.

SEC TI ON 3.2 SA MP LI NG A ND A NA LY TI CA L PR OC ED UR ES

3.2 .1 RM Instrumentation

x 2 

### The compoun ds cal ibr ated for w er e Ox ide s of N it ro g en (N O ) and Ox y g en ( O ). The

2 

### O was d ete cted u sing a Calif ornia An alytical Instru me nts Mode l 600 Pa rama gnetic

2 x 

### O anal y z er . N O anal y si s w a s p e r fo r me d u t i l i z ing a C ali forni a Anal y ti cal Ins tr uments
Mode l 600 CLD Chem ilumin escen ce an alyz er.

### Pag e - 4-

3.2.2 RM C alib rat io n Pro cedu re
Al l anal y z er s w er e c ali br ated usi ng EPA pr otoc ol 1 g as mix tur es. Ea ch anal y z er

w as z er oed w it h ul tr a- pur e ni tr og en, fol low ed by a mi d and hig h r ang e c ali br ati on
sta ndar d, c or re spond ing to betw een 40% and 60% for th e mi d r ang e, an d 100% of
the a nal y z er

full sp an v alu e. For

the Ni tr ic Ac id Tail Gas U nit the cal ibr ati on r ang es

2 x x 

### w ere as f ollows: O : 0 - 9.9 8 %, NO : 0 - 74. 3 ppm

. N0 converter ef f ic ie n c y is

2 

### checke d using 46.7 4 pp m N0

.

A s y ste m bi as chec k w as per formed befor e and after each tes t r un us ing the midra ng e g as mix tur e thr oug h the enti re sa mpli ng sy ste m to c heck f o r li ne
cont aminat ion and lea ks

. Cal ibr ati on c or re cti on factor s w er e det er mined and us ed
to c or re ct the r aw

R M conc entr ati ons.

A sy stem leak check was perf orme d be f ore an d after the test series.

3.2.3 RM Sam pl in g Pro cedu re The flue g as sampl es pr esent in the ex haust sta ck g as w er e sample d and

me a su re d ac co rd in g to th e requ ire m e n ts an d pro ce d u re s o f EP A Re f e re n ce Method

2 x 

### 3A (O ) and 7E (NO ). Samp les w e re d ra wn f rom thre e po ints across th e stack
dia meter , 16. 7%, 50%, and 83.3% us in g a multi por t pr obe. Fr om the pr obe, the sampl e w as then tr ansfer re d thr oug h a h eated li ne to the mobil e l abor ator y

. Upo n

e n t e r i n g t h e l a b
, t h e s a mp l e p a s s e d t h r o u g h a s e v e n mi c r o n fi l t e r a s s embly to

re mov e par

ti cul ate, a U niv er sal Anal y z er M odel 9010 to r emov e moi stu re , and a

ma nif old, u sed to control f low to the ana ly z ers.

3.2 .4 RM D ata Collec tion and R eduction
The RM data w as col lec ted and av er ag ed on a M easur ement S y ste ms D SM D ata
Processo r w ith La bT ech d ata acquisition sof tw are. T he d ata w as collecte d every

secon d, w ith on e min ute av erages printe d out

. Re lative Accu racyt esting on ea ch
CE MS co n s is t e d o f

a m in im u m o f

(9 ), t we n t y-o n e m in u t e t e s t ru n s

. T h e re la t ive

ac c ur ac y w as t he n av er ag ed a nd c al c ul at ed for e ac h s y s te m.

### Pag e - 5-

3.2 .5 7 Day

Drift Data Collec tion and R eduction

x 

### T he a uto ma ti c d a ily

calibration tests on the NO ana ly z er w as mo nitore d f or 7

cons ecut iv e day s t o determi ne max imum i nst ru ment dr ift. D ur ing the tes t per iod
, no mai ntenanc e or

ca li br ati on w or k w as per formed on the analy z er othe r than w hat

w hic h i s a utomati cal ly

per formed by

the ins tr ument.

SECTION 3.3 Unit M ass Emiss ion Determination
I n it ia l t e s t in g wa s p e rf o rm e d t o d e m o n s t ra t e in it ia l C E MS Re la t ive A c c u ra c y. Addi ti onal pos t R ATA tes ti ng w as per formed to dete rmi n e m a ss emi ss ion s a nd

X 

### Lb_ NO /ton HNO3. Mass emission a nalysis w as det ermin ed f or the o pera ting unit
based on col lec ted pr oces s a nd R M NO x and O2 c oncen tr ati ons col lec ted d ur ing
the Ini ti al CE MS Rel ati v e Acc ur acy Test A udi t ( RA TA) and from flow measu re ments
tak en us ing M ethods 1,2, and 4 on J anuar y 11, 2008. The meas ur ed flow data w as then co rre la ted w it h pl ant mas s b ala nce based flow data and pr oduct ion r ates to
deter mine the r ela ti v e f low duri ng the Oct ober

tes t per iod

. Var iat ion i n pr oduct ion
and mas s b ala nce flow betw een t he 10/ 11/07 and 0 1 /1 1/08 tes t per iod s w as deter mined to be l ess the 4%. Res ult s a re pr esent ed i n Tabl e 3.3

.

### Pag e - 6-



## T ab l e 3- 1: N i tr i c A ci d T ai l G as U ni t C EM S R el at i v e Ac cu ra cy T es t

Run No. RM

x NO ( p p m) C EM

x NO ( p p m)

1. 40. 01 37. 92

2. 42. 67 41. 74

3. 42. 25 41. 20

4. 40. 77 38. 82

5. 49. 66 42. 83

6. 49. 58 43. 23

7. 55. 59 49. 10

8. 57. 20 49. 42

9. 44. 82 42. 17

A vg 46. 95 42. 94

M ean
D i f f er ence 4. 01

S t dD e 2. 450

Co nC

. 2. 077

R A % 13. 00

Ac /S td % N /A

Ab s . D if. N /A

St at us Pass



## T ab l e 3- 2: N i tr i c A ci d T ai l G as U ni t C EM S 7 D ay D ri ft T es t

I n s tru m e n t M a x i m u m Z e ro
D ri ft M a x i m um Up

S ca l e D ri ft U n it L im it P a s s / F a il

x NO pp m 5. 01 9. 80 12. 50 Pass

### Pag e - 7- 

## T ab l e 3- 3: N i tr i c A ci d T ai l G as U ni t E m i ssi on D at a

I nst r um ent M easur ed or C al cul at ed Per m i t ( 7 day aver age)

X *N O E m i s s i o n s (l b / h r) 1 7 .8 0 N /A

3 N H O P ro d u c tio n R a te (to n / h r) 2 4 .9 8 N /A

X 3 E m i s s i on r a t e ( l b * NO / t on NHO ) 0. 712

. 8624

X A v e r a g e R M * N O ( p p m) 4 6 .9 5 N /A

X 3 * NO / pp m - Ton o f HNO f a c t or 0 .0 1 5 2 N /A

X 2 

### * Fo r c a l c u l a t i o n p u r p o s e s , NO a s s u m e d t o b e a l l NO

## A PPEN DIX A - C EM S R EL ATI VE A C C U R AC Y D ATA

# DeNovo-nv, Inc. ENVIRONMENTAL ENGINEERING AND TESTING SERVICES

CLIENT: DATE: PLANT LOCATION: PROJECT NO.:

SOURCE TESTED: LOAD:

Crew Information
Part 60: X J. Brown Part 75: J Brown Subpart J: Subpart Db: Facility Permit: Plant Representative(s) D. Robker Plant CEMS Brett Wet Dry X in, HG Time Applicable Standards Pretest - Start 14 11:25 Pretest - End 14 11:30
SO 2, ppm Leak Rate (In-HG / Min) SO2, lb/MMBtu in, HG Time NOx, ppm Post Test - Start 14 18:25 NOx, lb/MMBtu 1 Post Test - End 14 18:30 CO, ppm Leak Rate (In-HG / Min) Fuel Flow (scfh) Heat Input (mmbtu/h) Line Temperature O F Line 1 Line 2 Steam Flow (lb/hr) 248.2 N/A

RM Corrections Chiller Temperature O C 3.7 % O2 Correction % Moisture (bwa). RM Sample Dry X Load Basis: HP Mmbtu/hr RM Corrections X % O2 Correction: 0

NO X O 2 CO NO X Converter Efficiency: 98.77% Component Deviation % : Stack Stratified : No Non-Stratified Probe Settings(inches): 1 0.0 Stack Information Depth Width 2 0.0 Stack Diameter (inches): N/A 3 0.0 Sample Point Height (feet): Nozzle Extension NH3 Plant 10/11/2007 5283.020

0.00 0.00 RM System Leak Check 1544 Sawdust Road, Suite 302 The Woodlands, TX 77380

40 Code of Federal Regulations: TESTING INFORMATION >50% CRNF Coffeyville, Ks

## DeNovo-nv, Inc. ENVIRONMENTAL ENGINEERING AND TESTING SERVICES

The Woodlands, TX 77380

CLIENT: CRNF DATE: 10/11/2007 PLANT LOCATION: Coffeyville, Ks PROJECT NO.: 5283

SOURCE TESTED: NH3 Plant

Plant CEMS: RM Protocol Gases Fuel Factor Dry (Fd) 8710 Cylinder RM Fuel Factor Wet (Fd) Cylinder No. Concentration SPAN

Carbon Monoxide Monitor CO
Manufacturer: SG9905181A Zero 0.00 Serial Number: Low Model No. Mid Range: High

Carbon Dioxide Monitor CO 2
Manufacturer: California Analytical SG9905181A Zero 0.00 Serial Number: 12237 Mid Model No. 200 - Paramagnetic High Range:
Oxygen Monitor O 2
Manufacturer: California Analytical SG9905181A Zero 0.00 9.98 Serial Number: 12237 CC118059 Mid 5.01 Model No. 200 - Paramagnetic CC141137 High 9.98 Range: 9.98

NOx Monitor NOx
Manufacturer: Ametek California Analytical SG9905181A Zero 0.00 74.30 Serial Number: 6161T T-02015 CC82688 Mid 35.10 Model No. 4000B 600 CLD CC204451 High 74.30 Range: 500 ppm 74.30
Sulphur Dioxide Monitor SO 2
Manufacturer: SG9905181A Zero 0.00 Serial Number: Mid Model No. High Range: RM INSTRUMENTATION CEMS INSTRUMENTATION 1544 Sawdust Road, Suite 302ENVIRONMENTAL ENGINEERING AND TESTING SERVICESThe Woodlands, TX 77380DATE:UNIT:RUN NOx CO SO2O2RM Bias Corrected DataNUMBER TIME C Cma Cm Co C Cma Cm Co C Cma Cm Co C Cma Cm Co NOx C0 SO2O21 13:00 40.00 35.1 35.10 0.043.33 5.01 5.06 0.0940.01 3.272 13:30 42.69 35.1 35.12 0.043.35 5.01 5.04 0.1142.67 3.303 13:59 42.12 35.1 35.00 0.043.40 5.01 5.04 0.1342.25 3.344 14:28 40.62 35.1 34.98 0.043.41 5.01 5.04 0.1440.77 3.355 15:27 49.82 35.1 35.23 0.043.31 5.01 4.99 0.0749.66 3.306 16:26 49.82 35.1 35.28 0.043.34 5.01 4.95 -0.0349.58 3.397 16:55 55.85 35.1 35.28 0.043.33 5.01 4.98 -0.0555.59 3.378 17:26 57.18 35.1 35.21 0.313.33 5.01 5.00 -0.0557.20 3.369 17:56 44.36 35.1 34.84 0.473.33 5.01 4.97 -0.0544.82 3.38101112RUNRM Bias Corrected DataNOXSO2CEM Corrected DataNOx SO2NUMBER TIMENOXCOSO2O2Lb/mmBTU Lb/mmBTUNOx COSO2O2NOx COSO2O2Lb/mmBTU Lb/mmBTU1 13:00 N/A40.01 3.27 0.049337.92 N/A37.92 #VALUE!2 13:30 N/A42.67 3.30 0.052741.74 N/A41.74 #VALUE!3 13:59 N/A42.25 3.34 0.052341.20 N/A41.20 #VALUE!4 14:28 N/A40.77 3.35 0.050538.82 N/A38.82 #VALUE!5 15:27 N/A49.66 3.30 0.061342.83 N/A42.83 #VALUE!6 16:26 N/A49.58 3.39 0.061543.23 N/A43.23 #VALUE!7 16:55 N/A55.59 3.37 0.068949.10 N/A49.10 #VALUE!8 17:26 N/A57.20 3.36 0.070949.42 N/A49.42 #VALUE!9 17:56 N/A44.82 3.38 0.055642.1742.17 #VALUE!PROJECT NO.:Fd-FACTOR:CRNFCoffeyville, Ks>50%10/11/20075283.028710NH3 PlantDeNovo-nv, Inc.9CLIENT:1544 Sawdust Road, Suite 302NO. OF RUNS COMPLETED:LOAD:LOCATION:O2CorrectionRM SUMMARYCEM SUMMARYRM CALIBRATION CORRECTION DATAO2CorrectionCEM Data - UncorrectedMoisturePercentENVIRONMENTAL ENGINEERING AND TESTING SERVICES

CLIENT: DATE: LOCATION: LOAD: ANALYZER: UNIT:

RUN NUMBER TIME RM CEMS Diff

1 13:00 40.01 37.92 2.09
2 13:30 42.67 41.74 0.93
3 13:59 42.25 41.20 1.05
4 14:28 40.77 38.82 1.95
5 15:27 49.66 42.83 6.83
6 16:26 49.58 43.23 6.35
7 16:55 55.59 49.10 6.49
8 17:26 57.20 49.42 7.78
9 17:56 44.82 42.17 2.65

Average 46.95 42.94 4.01

NOx

RM AVERAGE: 46.9500 ppmv CEMS AVERAGE: 42.9367 ppmv ARITHMETIC MEAN: 4.0133 STANDARD DEVIATION: 2.7798 CONFIDENCE COEFFICIENT: 2.077 ACCURACY VS. RM AVERAGE: 13.0 % ACCURACY VS. APPLICABLE STANDARD: N/A %

Relative Accuracy for Nox

X , FAILS 

## DeNovo-nv

The Woodlands, TX 77380 1544 Sawdust Road, Suite 302

RELATIVE ACCURACY TESTING SUMMARY - NOx ANALYZER

PPMV

THE ABOVE DATA CERTIFIES THAT THE C.E.M. FOR WHICH THIS DATA IS THE RELATIVE ACCURACY TEST PROVIDED PASSES The table below contains the results of testing and calcultions performed on the date(s) listed. The testing was performed in accordance with 40 CFR Part 60, Appendix A, Method 7E and Appendix B, Performance Specification 2.

'*Shall not exceed 20.0 percent of the mean value of the reference method test data or 10 percent of the Relative Standard, wh ichever is greater. APPLICABLE STANDARD: ANALYZER ID: PERSONNEL: PROJECT NO.:

NH3 Plant 10/11/2007 5283.020 J. Brown 0 N/A CRNF Coffeyville, Ks >50% AmetekPlant Name CRNF Plant Rep. D. Robker Unit NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 1 Date 10/11/07

Calibration Initial Final System Correction Cylinder Calibration Difference Calibration System Bias System Drift Factor Value Response (% of Span) Response Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 0.07 0.50 0.11 0.40 0.09 O2 Mid 5.01 5.01 0.00 5.04 -0.30 5.07 -0.30 5.06 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.03 0.04 0.04 -0.01 0.04 NOx Mid 35.10 35.04 0.08 35.12 -0.11 35.07 0.07 35.10 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.30 Pass Pass Pass Pass SO2

Plant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 2 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 0.11 -0.90 0.11 0.00 0.11 O2 Mid 5.01 5.01 0.00 5.07 -0.60 5 0.70 5.04 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.04 0.03 0.04 0.00 0.04 NOx Mid 35.10 35.04 0.08 35.07 -0.04 35.17 -0.13 35.12 NOx High 74.30 74.37 -0.09 SO2 Zero 0.00 #VALUE! SO2 Mid 0.00 #VALUE! SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2 RM RUN CALIBRATION DATA

RM RUN CALIBRATION DATA SYSTEM BIAS CHECK PRETEST POST TEST CALIBRATION ERRORPlant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 3 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 0.11 -0.90 0.14 -0.30 0.13 O2 Mid 5.01 5.01 0.00 5.00 0.10 5.08 -0.80 5.04 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.04 0.03 0.04 0.00 0.04 NOx Mid 35.10 35.04 0.08 35.17 -0.17 34.83 0.46 35.00 NOx High 74.30 74.37 -0.09 SO2 Zero 0.00 #VALUE! SO2 Mid 0.00 #VALUE! SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2

Plant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 4 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 0.14 -1.20 0.13 0.10 0.14 O2 Mid 5.01 5.01 0.00 5.08 -0.70 5 0.80 5.04 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.04 0.03 0.04 0.00 0.04 NoxMid 35.10 35.04 0.08 34.83 0.28 35.13 -0.40 34.98 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2 RM RUN CALIBRATION DATA

RM RUN CALIBRATION DATAPlant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 5 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 0.13 -1.10 0 1.30 0.07 O2 Mid 5.01 5.01 0.00 5.00 0.10 4.97 0.30 4.99 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.04 0.03 0.04 0.00 0.04 NOx Mid 35.10 35.04 0.08 35.13 -0.12 35.32 -0.26 35.23 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2

Plant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 6 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 0.00 0.20 -0.05 0.50 -0.03 O2 Mid 5.01 5.01 0.00 4.97 0.40 4.92 0.50 4.95 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.04 0.03 0.03 0.01 0.04 NOx Mid 35.10 35.04 0.08 35.32 -0.38 35.24 0.11 35.28 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2 RM RUN CALIBRATION DATA

RM RUN CALIBRATION DATAPlant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 7 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 -0.05 0.70 -0.05 0.00 -0.05 O2 Mid 5.01 5.01 0.00 4.92 0.90 5.03 -1.10 4.98 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.03 0.04 0.04 -0.01 0.04 NOx Mid 35.10 35.04 0.08 35.24 -0.27 35.31 -0.09 35.28 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2

Plant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 8 Date 10/11/07

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 -0.05 0.70 -0.05 0.00 -0.05 O2 Mid 5.01 5.01 0.00 5.03 -0.20 4.96 0.70 5.00 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.04 0.03 0.57 -0.71 0.31 NOx Mid 35.10 35.04 0.08 35.31 -0.36 35.10 0.28 35.21 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2 RM RUN CALIBRATION DATA

RM RUN CALIBRATION DATAPlant Name CRNF Plant Rep. D. Robker Location NH3 Plant Crew Chief J. Brown Project Number 5283.02 CEMS Operator J Brown Run Number 9 Date 10/11/07 Final Run Yes: x

SYSTEM BIAS CHECK CALIBRATION ERROR PRETEST POST TEST Calibration Analyzer System Correction Cylinder Calibration Difference System Bias System Drift Factor Value Response (% of Span) Response (% of Span) Response (% of Span) Co/Cm CO Zero CO Low CO Mid CO High CO2 Zero CO2 Mid CO2 High O2 Zero 0.00 0.02 -0.20 -0.05 0.70 -0.05 0.00 -0.05 O2 Mid 5.01 5.01 0.00 4.96 0.50 4.97 -0.10 4.97 O2 High 9.98 9.98 0.00 NOx Zero 0.00 0.06 -0.08 0.57 -0.69 0.36 0.28 0.47 NOx Mid 35.10 35.04 0.08 35.10 -0.08 34.58 0.70 34.84 NOx High 74.30 74.37 -0.09 SO2 Zero SO2 Mid SO2 High

Calibration System Zero Calibration Span Values Error <2% Bias <5% Drift <3% Drift <3% CO CO2 O2 9.98 Pass Pass Pass Pass NOx 74.3 Pass Pass Pass Pass SO2 RM RUN CALIBRATION DATADeNovo-nv, Inc. CRNF - NOx CEMS RATA Date is 10-11-2007. Time O2 NOx HH:MM:SS % PPM 11:47:36 9.98 0.00 11:48:36 9.98 0.18 O2 High 11:49:36 7.18 0.26 11:50:36 5.04 0.06 N0x Zero 11:51:36 5.01 -0.02 O2 Mid 11:52:36 0.85 55.32 11:53:36 0.02 74.37 N0x High 11:54:36 0.02 59.46 11:55:36 0.02 34.92 O2 Zero 11:56:36 0.02 35.04 N0x Mid 11:57:36 0.33 35.68 11:58:36 0.44 41.33 11:59:36 0.44 44.53 12:00:36 1.49 28.76 12:01:36 0.13 0.90 12:02:36 0.07 0.22 O2 Zero 12:03:36 4.27 0.03 N0x Zero 12:04:36 5.04 0.04 O2 Mid 12:05:36 1.26 24.11 12:06:36 0.10 35.12 N0x Mid  Plant Value 12:30:02 3.31 34.31 O2 NOx NOx NOx 12:31:02 3.33 34.19 % PPM PPM PPM 12:32:02 3.37 33.14 3.35 36.53 25.09 12:32:00 25.91 12:33:02 3.35 32.35 12:33:00 25.91 12:34:02 3.36 31.97 12:34:00 25.95 12:35:02 3.38 31.40 12:35:00 25.96 12:36:02 3.37 33.33 12:36:00 26.54 12:37:02 3.37 37.00 12:37:00 27.68 12:38:02 3.37 36.94 12:38:00 28.02 12:39:02 3.32 33.34 12:39:00 28.01 12:40:02 3.27 31.98 12:40:00 28.02 12:41:02 3.32 33.24 12:41:00 27.97 12:42:02 3.40 38.73 12:42:00 27.97 12:43:02 3.34 38.57 12:43:00 27.97 12:44:02 3.28 31.56 12:44:00 28.01 12:45:02 3.20 26.96 12:45:00 24.32 12:46:02 3.31 25.93 12:46:00 20.13 12:47:02 3.53 29.25 12:47:00 21.40 12:48:02 3.54 38.05 12:48:00 21.41 12:49:02 3.46 47.03 12:49:00 21.41 12:50:02 3.36 52.19 12:50:00 21.41 12:51:02 3.23 53.91 12:51:00 21.41 12:52:02 3.18 50.29 12:52:00 21.41 12:53:02 3.18 45.99 12:54:02 2.84 44.17 12:55:02 0.05 35.18 12:56:02 0.05 35.12 O2 Zero N0x Mid 12:57:02 4.67 5.80 12:58:02 5.00 0.04 O2 Mid N0x Zero  Plant Value 12:58:47 5.01 0.04 O2 NOx NOx NOx 12:59:47 4.23 14.48 % PPM PPM PPM 13:00:47 3.27 39.06 3.33 40.00 37.92 13:00:00 42.13 13:01:47 3.33 37.59 13:01:00 42.13 13:02:47 3.33 39.25 13:02:00 42.13 13:03:47 3.34 38.60 13:03:00 42.13 13:04:47 3.33 34.11 13:04:00 38.43 13:05:47 3.29 31.42 13:05:00 33.35 13:06:47 3.33 33.99 13:06:00 33.32 13:07:47 3.45 38.46 13:07:00 33.35 13:08:47 3.45 40.11 13:08:00 33.41 13:09:47 3.34 40.57 13:09:00 33.41 13:10:47 3.30 40.89 13:10:00 33.37 13:11:47 3.36 41.67 13:11:00 33.36 13:12:47 3.36 42.70 13:12:00 33.37 13:13:47 3.31 42.62 13:13:00 36.47 13:14:47 3.33 42.74 13:14:00 40.79 13:15:47 3.35 44.96 13:15:00 40.86 13:16:47 3.30 45.85 13:16:00 40.91 13:17:47 3.29 43.49 13:17:00 40.87 13:18:47 3.29 41.30 13:18:00 40.86 13:19:47 3.32 40.07 13:19:00 40.87 13:20:47 3.31 40.46 13:20:00 40.82 CEM Data

Run 1

CEM Data

Run 2 Post-Test Bias

Run 2

Post-Test Bias Pre-Test Calibration

Pre-Test Bias

Run 1 N0x Converter Check13:21:47 3.36 41.20 13:21:00 40.82 13:22:47 3.46 41.99 13:23:47 5.07 3.59 O2 Mid 13:24:47 5.01 0.04 N0x Zero 13:25:47 0.54 28.29 13:26:47 0.11 34.97 O2 Zero 13:27:47 0.11 35.07 N0x Mid  Plant Value 13:28:34 0.10 35.15 O2 NOx NOx NOx 13:29:34 1.66 38.84 % PPM PPM PPM 13:30:34 3.33 46.98 3.35 42.69 41.74 13:30:00 37.63 13:31:34 3.34 44.28 13:31:00 40.03 13:32:34 3.37 41.82 13:32:00 43.33 13:33:34 3.35 41.43 13:33:00 43.35 13:34:34 3.41 44.18 13:34:00 43.39 13:35:34 3.45 49.30 13:35:00 43.40 13:36:34 3.37 55.25 13:36:00 43.39 13:37:34 3.30 53.86 13:37:00 43.40 13:38:34 3.26 48.17 13:38:00 43.35 13:39:34 3.20 44.80 13:39:00 43.43 13:40:34 3.26 39.72 13:40:00 42.63 13:41:34 3.33 38.35 13:41:00 41.43 13:42:34 3.34 39.25 13:42:00 41.43 13:43:34 3.42 37.96 13:43:00 41.34 13:44:34 3.45 38.72 13:44:00 41.33 13:45:34 3.41 42.44 13:45:00 41.38 13:46:34 3.40 43.16 13:46:00 41.34 13:47:34 3.36 40.27 13:47:00 41.29 13:48:34 3.30 37.98 13:48:00 41.33 13:49:34 3.37 35.45 13:49:00 40.04 13:50:34 3.42 33.16 13:50:00 38.20 13:51:34 3.40 34.15 13:52:34 3.42 35.60 13:53:34 0.44 35.12 13:54:34 0.11 35.17 O2 Zero N0x Mid 13:55:34 4.16 9.57 13:56:34 5.00 0.04 O2 Mid N0x Zero  Plant Value 13:57:03 5.01 0.04 O2 NOx NOx NOx 13:58:03 4.24 13.63 % PPM PPM PPM 13:59:03 3.28 37.35 3.40 41.79 41.20 13:59:00 37.16 14:00:03 3.35 34.25 14:00:00 37.20 14:01:03 3.41 33.73 14:01:00 37.25 14:02:03 3.47 34.92 14:02:00 37.25 14:03:03 3.48 39.22 14:03:00 37.21 14:04:03 3.45 44.20 14:04:00 37.16 14:05:03 3.46 45.73 14:05:00 37.16 14:06:03 3.40 46.82 14:06:00 37.16 14:07:03 3.32 44.55 14:07:00 40.08 14:08:03 3.31 40.40 14:08:00 44.08 14:09:03 3.35 38.60 14:09:00 44.10 14:10:03 3.39 38.93 14:10:00 44.10 14:11:03 3.45 40.01 14:11:00 43.54 14:12:03 3.45 40.48 14:12:00 43.54 14:13:03 3.42 40.84 14:13:00 43.54 14:14:03 3.42 44.31 14:14:00 43.58 14:15:03 3.46 44.92 14:15:00 43.59 14:16:03 3.41 48.71 14:16:00 43.54 14:17:03 3.36 47.12 14:17:00 44.13 14:18:03 3.43 45.89 14:18:00 44.94 14:19:03 3.38 46.66 14:19:00 44.94 14:20:03 3.44 45.46 14:21:03 3.52 46.08 14:22:03 5.08 4.27 O2 Mid 14:23:03 5.01 0.04 N0x Zero 14:24:03 1.11 24.42 14:25:03 0.14 34.83 O2 Zero N0x Mid  Plant Value 14:26:11 0.14 34.97 O2 NOx NOx NOx 14:27:11 1.67 34.88 % PPM PPM PPM 14:28:11 3.40 36.73 3.41 42.12 38.82 14:28:00 28.53 14:29:11 3.46 40.41 14:29:00 28.53 14:30:11 3.50 41.02 14:30:00 28.57 14:31:11 3.43 42.35 14:31:00 28.59 14:32:11 3.36 41.79 14:32:00 28.53 14:33:11 3.39 42.15 14:33:00 28.49 14:34:11 3.44 46.35 14:34:00 36.52 14:35:11 3.43 48.49 14:35:00 47.87 14:36:11 3.36 46.10 14:36:00 48.32 Run 4

CEM Data

Run 5 CEM Data

Run 3

CEM Data Post-Test Bias

Run 4

Post-Test Bias

Run 5 Run 314:37:11 3.30 42.40 14:37:00 48.36 14:38:11 3.32 39.45 14:38:00 48.37 14:39:11 3.40 38.39 14:39:00 48.32 14:40:11 3.44 41.14 14:40:00 48.36 14:41:11 3.46 43.14 14:41:00 48.37 14:42:11 3.45 42.37 14:42:00 48.32 14:43:11 3.39 40.53 14:43:00 41.50 14:44:11 3.37 39.87 14:44:00 33.97 14:45:11 3.43 41.29 14:45:00 36.43 14:46:11 3.46 44.19 14:46:00 36.46 14:47:11 3.43 44.05 14:47:00 36.41 14:48:11 3.39 42.39 14:48:00 36.41 14:49:11 3.36 42.60 14:50:11 3.37 41.97 14:51:11 0.48 35.78 14:52:11 0.13 35.13 O2 Zero N0x Mid 14:53:11 3.42 14.76 14:54:11 5.00 0.04 O2 Mid N0x Zero  Plant Value 14:55:19 5.01 0.04 O2 NOx NOx NOx 14:56:19 4.36 12.99 % PPM PPM PPM 14:57:19 3.46 43.84 3.43 42.52 33.37 14:57:00 27.26 14:58:19 3.46 45.99 14:58:00 27.31 14:59:19 3.43 45.59 14:59:00 27.27 15:00:19 3.36 40.65 15:00:00 27.22 15:01:19 3.34 36.35 15:01:00 29.47 15:02:19 3.37 36.79 15:02:00 32.90 15:03:19 3.44 39.04 15:03:00 33.37 15:04:19 3.49 39.51 15:04:00 33.32 15:05:19 3.44 42.04 15:05:00 33.32 15:06:19 3.45 42.70 15:06:00 33.32 15:07:19 3.49 42.57 15:07:00 33.32 15:08:19 3.41 41.98 15:08:00 33.35 15:09:19 3.36 41.52 15:09:00 33.37 15:10:19 3.46 39.61 15:10:00 33.83 15:11:19 3.46 39.80 15:11:00 35.87 15:12:19 3.42 44.02 15:12:00 37.71 15:13:19 3.47 51.19 15:13:00 37.68 15:14:19 3.52 49.59 15:14:00 37.67 15:15:19 3.40 47.25 15:15:00 37.72 15:16:19 3.32 43.44 15:16:00 37.72 15:17:19 3.49 39.50 15:17:00 37.72 15:18:19 3.50 42.88 15:19:19 3.51 48.58 15:20:19 5.08 4.53 O2 Mid 15:21:19 5.01 0.04 N0x Zero 15:22:19 2.05 17.73 15:23:19 0.08 34.90 15:24:19 0.01 35.00 O2 Zero N0x Mid  Plant Value 15:25:35 0.00 35.04 O2 NOx NOx NOx 15:26:35 1.54 37.00 % PPM PPM PPM 15:27:35 3.34 40.15 3.31 40.62 42.83 15:27:00 44.85 15:28:35 3.28 40.67 15:28:00 44.89 15:29:35 3.31 40.81 15:29:00 42.93 15:30:35 3.31 40.20 15:30:00 40.18 15:31:35 3.28 39.58 15:31:00 40.20 15:32:35 3.27 38.24 15:32:00 40.22 15:33:35 3.32 36.59 15:33:00 40.16 15:34:35 3.34 35.94 15:34:00 40.20 15:35:35 3.34 35.75 15:35:00 40.25 15:36:35 3.35 36.12 15:36:00 40.22 15:37:35 3.37 40.56 15:37:00 40.24 15:38:35 3.36 44.94 15:38:00 42.20 15:39:35 3.33 40.19 15:39:00 44.78 15:40:35 3.20 35.41 15:40:00 44.81 15:41:35 3.19 36.07 15:41:00 44.80 15:42:35 3.42 39.71 15:42:00 44.81 15:43:35 3.47 45.64 15:43:00 44.76 15:44:35 3.30 46.44 15:44:00 44.76 15:45:35 3.26 46.20 15:45:00 44.76 15:46:35 3.25 46.53 15:46:00 44.76 15:47:35 3.27 47.32 15:47:00 44.76 15:48:35 3.22 44.90 15:49:35 3.22 41.99 15:50:35 0.36 35.78 15:51:35 0.00 35.32 O2 Zero N0x Mid 15:52:35 3.80 11.25 15:53:35 4.96 0.04 Run 7 Run 6

CEM Data CEM Data

Post-Test Bias Post-Test Bias

Run 6

Post-Test Bias

Run 715:54:35 4.97 0.04 O2 Mid N0x Zero  Plant Value 15:55:31 4.97 0.04 O2 NOx NOx NOx 15:56:31 4.30 13.08 % PPM PPM PPM 15:57:31 3.44 43.71 3.31 48.77 35.33 15:57:00 29.62 15:58:31 3.42 47.99 15:58:00 29.56 15:59:31 3.35 57.01 15:59:00 29.56 16:00:31 3.33 52.49 16:00:00 29.60 16:01:31 3.29 40.88 16:01:00 29.66 16:02:31 3.12 38.35 16:02:00 29.62 16:03:31 3.33 37.76 16:03:00 29.56 16:04:31 3.54 41.95 16:04:00 29.56 16:05:31 3.46 47.90 16:05:00 34.06 16:06:31 3.40 54.64 16:06:00 40.26 16:07:31 3.36 58.63 16:07:00 40.31 16:08:31 3.29 58.77 16:08:00 40.26 16:09:31 3.18 63.19 16:09:00 40.22 16:10:31 3.19 59.78 16:10:00 40.24 16:11:31 3.24 53.14 16:11:00 40.31 16:12:31 3.14 49.02 16:12:00 40.26 16:13:31 3.19 45.05 16:13:00 40.29 16:14:31 3.32 42.20 16:14:00 38.81 16:15:31 3.29 41.46 16:15:00 36.74 16:16:31 3.31 43.61 16:16:00 36.75 16:17:31 3.42 46.72 16:17:00 36.69 16:18:31 3.42 51.41 16:19:31 3.38 48.67 16:20:31 5.02 4.39 O2 Mid 16:21:31 4.94 0.04 N0x Zero 16:22:31 2.35 15.10 16:23:31 -0.04 35.64 O2 Zero N0x Mid  Plant Value 16:24:24 -0.06 35.77 O2 NOx NOx NOx 16:25:24 1.39 40.13 % PPM PPM PPM 16:26:24 3.29 49.53 3.34 49.82 43.23 16:26:00 46.16 16:27:24 3.33 49.83 16:27:00 46.16 16:28:24 3.36 50.15 16:28:00 46.16 16:29:24 3.36 48.22 16:29:00 46.12 16:30:24 3.30 46.09 16:30:00 46.11 16:31:24 3.30 46.12 16:31:00 46.16 16:32:24 3.35 46.57 16:32:00 43.88 16:33:24 3.35 48.21 16:33:00 40.86 16:34:24 3.33 49.92 16:34:00 41.00 16:35:24 3.36 49.66 16:35:00 40.97 16:36:24 3.35 48.99 16:36:00 40.91 16:37:24 3.31 48.86 16:37:00 40.91 16:38:24 3.33 46.67 16:38:00 40.95 16:39:24 3.33 46.23 16:39:00 40.97 16:40:24 3.34 47.24 16:40:00 40.91 16:41:24 3.38 49.06 16:41:00 41.94 16:42:24 3.37 50.71 16:42:00 43.42 16:43:24 3.35 52.43 16:43:00 43.58 16:44:24 3.35 55.66 16:44:00 43.59 16:45:24 3.37 57.39 16:45:00 43.54 16:46:24 3.35 58.62 16:46:00 43.54 16:47:24 3.29 55.95 16:48:24 3.25 54.42 16:49:24 0.38 37.56 16:50:24 -0.05 35.24 O2 Zero N0x Mid 16:51:24 3.22 14.89 16:52:24 4.92 0.03 O2 Mid N0x Zero  Plant Value 16:53:49 4.97 0.04 O2 NOx NOx NOx 16:54:49 4.35 15.72 % PPM PPM PPM 16:55:49 3.34 55.33 3.33 55.85 49.10 16:55:00 49.26 16:56:49 3.33 56.07 16:56:00 49.26 16:57:49 3.35 56.18 16:57:00 49.26 16:58:49 3.31 56.91 16:58:00 49.26 16:59:49 3.30 57.90 16:59:00 48.67 17:00:49 3.31 58.85 17:00:00 48.53 17:01:49 3.33 57.02 17:01:00 49.40 17:02:49 3.30 52.70 17:02:00 49.35 17:03:49 3.34 48.45 17:03:00 49.35 17:04:49 3.36 49.55 17:04:00 49.35 17:05:49 3.41 53.40 17:05:00 49.39 17:06:49 3.41 57.83 17:06:00 49.45 17:07:49 3.37 56.94 17:07:00 49.41 17:08:49 3.32 56.02 17:08:00 48.68 17:09:49 3.29 58.02 17:09:00 48.31 Run 10 CEM Data

Run 8

CEM Data

Run 9

CEM Data Post-Test Bias

Run 10 Run 8

Post-Test Bias

Run 917:10:49 3.34 59.19 17:10:00 49.03 17:11:49 3.34 60.27 17:11:00 49.02 17:12:49 3.27 59.27 17:12:00 49.07 17:13:49 3.29 56.46 17:13:00 49.07 17:14:49 3.31 53.53 17:14:00 49.03 17:15:49 3.31 52.90 17:15:00 48.98 17:16:49 3.34 55.97 17:17:49 3.40 54.95 17:18:49 5.03 4.87 O2 Mid 17:19:49 4.96 0.04 N0x Zero 17:20:49 3.33 7.93 17:21:49 -0.05 35.07 17:22:49 -0.05 35.31 O2 Zero N0x Mid 17:23:49 -0.05 35.39  Plant Value 17:24:34 -0.05 35.41 O2 NOx NOx NOx 17:25:34 1.38 42.12 % PPM PPM PPM 17:26:34 3.36 56.31 3.33 57.18 49.42 17:26:00 48.25 17:27:34 3.32 57.47 17:27:00 47.82 17:28:34 3.30 57.25 17:28:00 48.41 17:29:34 3.32 55.98 17:29:00 48.41 17:30:34 3.31 55.96 17:30:00 48.41 17:31:34 3.35 57.72 17:31:00 48.37 17:32:34 3.37 59.98 17:32:00 48.36 17:33:34 3.37 59.01 17:33:00 48.41 17:34:34 3.35 59.16 17:34:00 48.41 17:35:34 3.34 58.44 17:35:00 48.45 17:36:34 3.36 60.71 17:36:00 49.73 17:37:34 3.37 64.65 17:37:00 51.37 17:38:34 3.38 63.12 17:38:00 51.32 17:39:34 3.29 60.27 17:39:00 51.32 17:40:34 3.23 58.52 17:40:00 51.32 17:41:34 3.28 54.61 17:41:00 51.28 17:42:34 3.33 51.86 17:42:00 51.27 17:43:34 3.32 51.33 17:43:00 51.32 17:44:34 3.35 52.62 17:44:00 51.32 17:45:34 3.35 53.41 17:45:00 48.84 17:46:34 3.30 52.47 17:46:00 45.43 17:47:34 3.26 49.66 17:48:34 3.28 46.03 17:49:34 0.32 37.10 17:50:34 -0.05 35.24 O2 Zero 17:51:34 -0.05 35.10 N0x Mid 17:52:34 1.42 28.22 17:53:34 4.95 0.57 N0x Zero 17:54:34 4.96 0.62 O2 Mid

 Plant Value 17:54:55 4.96 0.66 O2 NOx NOx NOx 17:55:55 4.35 14.41 % PPM PPM PPM 17:56:55 3.33 46.37 3.33 44.36 42.17 17:56:00 41.19 17:57:55 3.29 44.87 17:57:00 41.19 17:58:55 3.28 42.12 17:58:00 41.19 17:59:55 3.28 40.84 17:59:00 41.19 18:00:55 3.30 40.44 18:00:00 41.19 18:01:55 3.35 41.16 18:01:00 41.19 18:02:55 3.34 43.64 18:02:00 41.19 18:03:55 3.33 48.10 18:03:00 41.98 18:04:55 3.33 48.34 18:04:00 43.02 18:05:55 3.32 45.33 18:05:00 43.01 18:06:55 3.24 42.24 18:06:00 43.07 18:07:55 3.25 40.73 18:07:00 43.11 18:08:55 3.31 40.95 18:08:00 43.12 18:09:55 3.35 43.77 18:09:00 43.07 18:10:55 3.35 45.48 18:10:00 43.07 18:11:55 3.35 45.87 18:11:00 43.03 18:12:55 3.33 43.91 18:12:00 42.62 18:13:55 3.34 42.17 18:13:00 42.05 18:14:55 3.35 43.05 18:14:00 41.98 18:15:55 3.40 47.63 18:15:00 42.04 18:16:55 3.43 54.47 18:16:00 42.00 18:17:55 3.39 60.70 18:18:55 3.32 57.97 18:19:55 5.03 5.06 18:20:55 4.97 0.36 O2 Zero N0x Mid 18:21:55 2.59 13.57 18:22:55 -0.05 34.58 O2 Mid N0x Zero Run 11

CEM Data

Run 12 Post-Test Bias

Run 12

Post-Test Bias Post-Test Bias

Run 11WDuration00:19:4100:0000:1000:2000:3000:4000:5001:00CRNF NH3 Plant NOx RATA, CAL & Bias, 10/11/070102030405060708090100%ofScale00:00 00:10 00:20 00:30 00:40 00:50 01:00WO2 ( % )NOx (ppm)0.09535.12O2 - Min AvgNOx Min Avg0.09735.12SP - 1BIASONOFFBias OnWDuration00:28:2900:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNFNH3 Plant NOxRATA_ RUN 1 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm5.000.036O2 - Min AvgNOx Min Avg5.000.036SP - 1SP - 2SP - 3BiasWDuration00:29:0700:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 2 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm0.1135.11O2 - Min AvgNOx Min Avg0.1135.07SP - 1SP - 2SP - 3BiasWDuration00:28:1100:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 3 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm5.010.036O2 - Min AvgNOx Min Avg5.000.037SP - 1SP - 2SP - 3BiasWDuration00:28:4800:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 4 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm0.1434.93O2 - Min AvgNOx Min Avg0.1434.83SP - 1SP - 2SP - 3BiasWDuration00:28:5000:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 5 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm5.010.036O2 - Min AvgNOx Min Avg5.000.037SP - 1SP - 2SP - 3BiasWDuration00:29:4800:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 6 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm0.001035.07O2 - Min AvgNOx Min Avg0.007135.00SP - 1SP - 2SP - 3BiasWDuration00:29:3600:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 7 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm4.970.036O2 - Min AvgNOx Min Avg4.970.036SP - 1SP - 2SP - 3BiasWDuration00:28:2000:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 8 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm-0.04835.73O2 - Min AvgNOx Min Avg-0.04335.64SP - 1SP - 2SP - 3BiasWDuration00:28:1000:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 9 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm4.920.036O2 - Min AvgNOx Min Avg4.920.034SP - 1SP - 2SP - 3BiasWDuration00:30:3200:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 10 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm-0.05035.37O2 - Min AvgNOx Min Avg-0.04835.39SP - 1SP - 2SP - 3BiasWDuration00:30:0100:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 11 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm4.960.64O2 - Min AvgNOx Min Avg4.960.62SP - 1SP - 2SP - 3BiasWDuration00:29:2800:0000:0500:1000:1500:2000:2500:3000:3500:4000:4500:5000:5401:00CRNF NH3 Plant NOx RATA_ RUN 12 - 10/11/070102030405060708090100%ofRange00:00 00:05 00:10 00:15 00:20 00:25 00:30 00:35 00:40 00:45 00:50 00:54 01:00WO2 (%)NOx ppm-0.04834.60O2 - Min AvgNOx Min Avg-0.04834.59SP - 1SP - 2SP - 3Bias

## A PPEN DIX B - CEMS 7 DAY DRIFT D ATAx 

### CE M CAL I BR AT I ON DRI F T C HECK (NO )

Facility : C offey v ille R esource s N itrog en F ertiliz ers Ana ly z er Mode l #

- A m etek 40 00B Ana ly z er S erial # 8161 T

A cc epta ble Crit eria: <=+ /- 2 .5 % of sp an each da y for Se ve n conse cutive day s.
S PA N 0 

### 500

LO W LEVEL CALI

BRATI O N

GAS

D a t e T i m e C al i br ati on G as V al ue ( p p m V) Initi a l M onit or R espo ns e ( p p m 2

. 4 V) A b s olute D i ff eren ce ( p p m V) P er ce nt of

Span (% ) Co mme n t s M o n i t o r Ca l / Ch e c k e d By ( Si gnat ur e)

11/ 09/ 07 6:05 0 -.77 0.77 0.15% PA SS B.A .M.

11/ 10/ 07 6:04 0 4.23 4.23 0.85% PA SS B.A .M.

11/ 11/ 07 6:04 0 -5.01 5.01 1.00% PA SS B.A .M.

11/ 12/ 07 6:04 0 4.33 4.33 0.87% PA SS B.A .M.

11/ 12/ 07 6:04 0 1.91 1.91 0.38% PA SS B.A .M.

11/ 14/ 07 6:03 0 1.17 1.17 0.23% PA SS B.A .M.

11/ 15/ 07 6:04 0 -1.41 1.41 0.28% PA SS B.A .M.
H I G H LEVEL CALI

BRATI O N

GAS

D a t e T i m e C al i br ati on G as V al ue ( p p m V) Initi a l M onit or R espo ns e ( p p m V) A bso l ut e

D iff e r e nc e t ( p p m V) P er ce nt of

Span (% ) Co mme n t s M o n i t o r Ca l / Ch e c k e d By ( Si gnat ur e)

11/ 09/ 07 6:12 444 437. 1 6. 9 1. 38% PA SS B.A .M.

11/ 10/ 07 6:12 444 443.6 0.4 0.08% PA SS B.A .M.

11/ 11/ 07 6:12 444 436.7 7.3 1.46% PA SS B.A .M.

11/ 12/ 07 6:12 444 439.2 4.8 0.96% PA SS B.A .M.

11/ 12/ 07 6:12 444 447.1 3.1 0.62% PA SS B.A .M.

11/ 14/ 07 6:12 444 435.5 8.5 1.70% PA SS B.A .M.

11/ 15/ 07 6:12 444 453.8 9.8 1.96% PA SS B.A .M.

Ca libr at ion D rif

t = [A BS (Moni tor Re spons e - C al ibra tion Value )/C EM S PA

N * 100 Spe ci f ic at ion: Monit or C al ibra

tion Dr if t

## A PPEN DIX C - U NI T EM ISSI ON AN ALY SISUnit Flow2.xls Run 1 Stack Flow Worksheet

A s = ID =

π =

=

A s =  ft 2 A s =  m 2 A s =  ft 2 A s =  m 2

A s = ft 2 A s = m 2

P s = Static pressure inside the stack measured in inchesof water "H 2 O P bar = P std = Standard Barometric Pressure P cor = K flo w =

K flo w =( / )x x 60 = A s

K flo w =( / )x x 60 = A s A rea of the Stack ( L x W ) or ( π x ( ID/2 ) 2 )

K flow scm/min

28.95 K-Flow is the flow that would exist in the stack based on the ambient pressure and the internal pressure, and corrected to standard conditions

28.95 29.92 9.393 545.37 CNRF

12:10

3.1415927 as a pre-defined constant for circular geometry inside diameter of the stack wall in inches End Time

ID

29.92 0.873 50.67 P cor P std 0.87 Tail Gas 1/11/2008 11:00

L (ength) 1 inch

2.54 cm 105.41 AREA OF THE STACK Plant Unit Date Start Time

41.50 ID L (ength) W (idth) centimeters

Ambient barometric pressure in inches of Mercury "Hg W (idth)

9.39 0.87

KINETIC FLOW IN THE STACK inches

9.39

" H 2 O

28.95 "Hg -3.10
29.18 29.92

sec/min Corrected Barometric Pressure "Hg "Hg

P cor P std sec/min K flow scf/min RUN 1Unit Flow2.xls Run 1 Stack Flow Worksheet

=

=

= =

1
2
3
4
5
6 SG

mL V i c

mL x = scf V i c V k
Allowing that flue gas is composed of CO2 + O2 + N2

=

=

=

=

100 % - ( + ) =

+ += g CO 2 /mol 1.07 g O 2 /mol 26.64 g N 2 /mol 0.66 95.16 %N 2 Distribution of components of the flue gas

M d g/mol of dry flue gas 28.3736 1.5 %O 2 3.34 %CO 2 %O 2 %N 2 Dry Molecular Weight of Theoretical Flue Gas Measured Percentage of CO 2 in the Flue Gas Measured Percentage of O 2 in the Flue Gas Calculated Percentage of N 2 in the Flue Gas M d %CO 2 scm

Dry Molecular Weight

. 0.588 V w std 12.5 0.04707 0.01666 V w std 0

Total Volume of Water Collected 12.5

134.8 11
1.5
0 Difference

134.8 108.0
104.5
104.9 119.0
106.0
104.9 Impinger weights in grams

Impinger # Initial Final V k Total volume of Water collected in Impinger Train Vapor Constant to correct mL of water to scf of water vapor 0.04707 V ic V w std Volume of Water Vapor Corrected to Standard Conditions

Volume of Water Vapor in gas sample Corrected to Standard ConditionsUnit Flow2.xls Run 1 Stack Flow Worksheet

=

=

=

=

=

=

=

1 2 3 4 5 6 7 8 1.001 x x ( / ) = 9

Y 10 11 12

x = 13 14 15

x = 16 17 18 19 20 / ( + ) / 100 = 21 22 23 24 25

averages Average of the DGM inlet and outlet temperatures o F

sc f 71.0

dscf dscm/dscf V m std

V w std 20.013 0.028317 0.5667 dscm

0.5884

V w std 20.013 V m std 1.1341 E 1

2.86%

B ws 20.600

V dgm 531.5 P c T dgm 29.231

17.647
Ideal Gas Constan t

72.0 71.0 0.70 0.70 0.70 0.70 0.70 0.70 0.70 ∆ H " H 2 O 0.70 0.70 0.70 0.70 0.70 0.70

71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 72.0 72.0

72.0 72.0 Inlet 72.0 72.0 72.0 Outlet DGM Temperatures o F

20.013 V m std 72.0 72.0 72.0

72.0 72.0 Dry Gas Meter Readings Initial Final

0.5884 103.500 124.100

20.6 V dgm

1.1341

E 1 T avg

P c Percentage of Moisture by Volume Volume of gas measured by the Dry Gas Meter (DGM) Dry Gas Meter Volume corrected to standard conditions

T av g corrected to standard temperature Rankin ( o F +460) Y correction Factor for DGM, Determined at calibration of DGM DGM Pressure[(average of Delta H readings / 13.6) + P bar ] V m std

V dgm Percent Moisture by Volume of the Stack Flue Gases

T dgm Y B wsUnit Flow2.xls Run 1 Stack Flow Worksheet

=

=

=
( x ) + ( x ) =

=

=

=

= Average temperature across the stack in Rankin (T s + 460)

= T s

xx= 1 o F avg E 1 2 o F 3 o F 4 o F ( / ( x ) ) 1/2 = 5 o F 6 o F 7 o F 8 o F 9 o F 10 o F x = 11 o F 12 o F 13 o F 14 o F = fps 15 o F 16 o F = mps 17 o F 18 o F 19 o F 20 o F 21 o F 22 o F 23 o F 24 o F 25 o F

Averages 355 353 352

358 Wet Molecular weight of the Flue Gas

V s

E 1 85.48

K p MW H2O M s P dg Percentage of dry gas in the sample. (100 % - B ws ) Wet Molecular Weight of the flue gas measured Molecular weight of water (18 g/mol)

Flue gas velocity in feet per second 2.86% MW H2O

B ws 18 97.14%

P dg 28.374 M d 28.077 M s

T s cor Pitot Tube Constant 85.48 Pitot Tube Coefficient 0.84 Differential pressure across the Pitot Tube in inches of Water "H 2 O K p C p ∆ P g/mol

2.19 357 4.82 ∆ P 4.82 359 2.19 Stack Temp

4.97 4.77 4.56 4.26

2.12 2.11 4.36 4.82 4.56 4.51 4.46 2.23 2.18 2.14

2.14 2.06 2.09 2.19

2.04 340 355 360 357 357

340

4.588 2.14 353.6 153.81

V s Metric 153.74 1.00 153.81 E 2 V s Stack Gas Velocity in feet per Second

28.077 Point

4.16 2.14119 153.74 0.84 C p

T s cor 813.583 P cor 28.95 M s 1.00 E 2

V s English

46.88Unit Flow2.xls Run 1 Stack Flow Worksheet

AVF =

x x=

x x=

T std = T k =

x x = x 60 =

x 60 =

Q sd = P k = T std = T k =

x x x = x 60 =

x x x = x 60 = 92,492.22 SVF in scm/hr 3,266,314.20 SVF in scf/hr

1,541.54 SVF in scm/min A s

K flow SVF in scf/min

89,850.20 Q sd Nm 3 /hr 97.14% 2,454.72

P dg AVF T k P k Q sd Nm 3 /min 0.649 0.968 1,497.50 sec/min V s

Dry Standard Volumetric Flow in the stack (Normal Volumetric Units) 0.649 153.809 545.37 54,438.57

T k V s Temperature correction Coefficient (T std / T s cor)

Temperature correction Coefficient (T std / T s cor)

P dg AVF T k P k Q sd dsft 3 /min 97.14% 0.649 0.968 9.39 Actual Volumetric Flow in the stack

3,173,029.85 60 46.88 0.87 Actual Volumetric Flow In the Stack

60 sec/min 153.81 V s ft 3 / min

Q sd dsft 3 /hr A s AVF 2,454.72 m 3 / min

Standard Temperature in degrees Rankin 528 Pressure correction coefficient (P cor / P std )

52,883.83 86,687.60 86,687.60 AVF

Dry Standard (Normal) Volumetric Flow Rate Standard Volumetric Flow in the Stack

Standard Temperature in degrees Rankin 528Unit Flow2.xls Run 1 Stack Flow Worksheet

x /= =

x x x 60 =

lb NO 2 / ton HNO 3 NO 2 /ppm-ton of HNO 3 24.98
Ton/hr HNO 3 0.712 0.0152 ng/hr NO X x10 6 = 8.0720E+12 8.07E+06 mg/hr NO X SVF scm/min P dg 1,541.54 mg/dscm NO X 89.838 97.14% Mass Per Hour Emissions of Pollutants Conversion of ppm to mg/Nm 3 and then to ng/Nm 3

46.95 ppm NO x 46.000 MW NO x 24.04 l/mol mg/dscm NO x 89.838 8.984E+07 ng/dscm NO x

17.80 75.27
lb/hr NO X ton/yr NO XFI1624x FI1603x FIC1425x FI1405x FI1612x FIC1801x AI1805x TI1409x AI1454xFI1624.PV FI1603.PV FIC1425.PV FI1405.PV FI1612.PV FIC1801.PV AI1805.PV TI1409.PV AI1454.PVSCFM SCFM LB/HR SCFM LB/HR SCFM PPM DEGF %PROCESSAIR OG/AIRMIXERBLEACH AIR TOBLEACHERACID PLANTSUPPLEMENTALO2 FLOWH.P.OFF-GASTOCONVERTERNITRIC ACIDPRODUCTIONH.P.OFF-GASNOX ABATORNOx EMISSIONEXHAUST STKGAUZETEMPERATURETAIL GS OXYEXABSORBERMeasuredEnriched AirHP Off Gas+ Inerts Pure O2AcidProductionCompressed AirFlowTotal StackFlowAcidProductionTotal StackFlowTotal StackFlowTotal StackFlowTimestampmol/hr mol/hr mol/hr mol/hr mol/hr mol/hr Ton/hr mol/hr SCFH SCFM1/11/2008 10:00 36104.4 9264.4 5544.8 11557.9 85091.1 31.9 26.4 1693.3 2.9 7172.9 308.9 173.3 749.3 7280.0 6266.81/11/2008 10:05 36074.0 9243.7 5528.2 11525.3 84299.3 31.9 30.8 1694.3 2.9 7164.9 308.0 172.8 742.3 7191.4 6190.71/11/2008 10:10 36230.5 9298.6 5551.1 11471.3 85774.8 32.0 36.2 1694.0 2.8 7198.3 306.6 173.5 755.3 7318.9 6291.51/11/2008 10:15 36234.6 9277.3 5541.4 11469.5 85896.7 32.1 30.4 1696.9 2.9 7195.6 306.5 173.2 756.4 7352.7 6322.91/11/2008 10:20 36207.4 9251.4 5543.8 11357.9 86052.1 32.3 27.4 1695.5 2.8 7187.2 303.5 173.2 757.8 7349.3 6313.81/11/2008 10:25 36211.1 9268.5 5538.4 11310.1 85216.2 32.3 24.5 1694.1 2.9 7190.5 302.3 173.1 750.4 7295.9 6273.81/11/2008 10:30 36200.8 9270.4 5555.3 11418.1 83273.1 32.2 23.1 1693.4 3.0 7189.1 305.2 173.6 733.3 7121.5 6136.91/11/2008 10:35 36209.6 9288.3 5563.1 11543.5 85433.9 32.1 28.2 1693.5 2.9 7193.4 308.5 173.9 752.3 7316.5 6297.51/11/2008 10:40 36212.5 9284.1 5537.1 11509.4 87271.6 32.0 22.5 1692.6 2.9 7193.1 307.6 173.0 768.5 7480.1 6427.11/11/2008 10:45 36163.3 9264.2 5561.5 11480.7 84285.8 31.7 11.1 1690.5 2.9 7182.2 306.8 173.8 742.2 7204.9 6204.41/11/2008 10:50 36193.4 9278.4 5565.4 11407.9 84647.4 31.7 24.8 1698.9 2.9 7189.2 304.9 173.9 745.4 7233.3 6224.61/11/2008 10:55 36156.5 9270.0 5568.6 11283.9 86914.2 32.0 41.1 1697.4 2.8 7182.1 301.6 174.0 765.3 7428.5 6376.61/11/2008 11:00 36170.4 9254.3 5585.0 11272.5 83867.6 32.0 35.4 1693.2 2.9 7181.8 301.3 174.5 738.5 7158.7 6160.7 23.7 6277.2 2382203.9 39703Date(mm/dd/yy hh)MeasuredEnriched Air(FI1603 &FI1624)HP Off GasInertsincludingCO2Pure O2Added(FIC1425)HNO3ProductionCorrectedCompressed AirFlowTotal StackAcidProductionTotal StackFlowTotalStackFlowmol/hr mol/hr mol/hr mol/hr mol/hr mol/hr Ton/hr SCFH SCFM10/11/07 12:007529.4 330.5 168.7 783.9 7561.7 6496.1 24.70 2465260 4108810/11/07 13:007509.0 330.1 170.1 780.6 7524.9 6466.9 24.59 2454173.4 4090310/11/07 14:007487.8 328.1 170.1 791.8 7656.4 6574.1 24.95 2494852.4 4158110/11/07 15:007478.8 327.7 170.2 780.0 7546.6 6487.5 24.58 2461990.8 4103310/11/07 16:007469.9 327.6 170.4 790.7 7659.0 6578.7 24.91 2496604 4161010/11/07 17:007467.3 328.3 170.5 786.5 7613.1 6542.1 24.78 2482722.9 4137924.75 41266\\Wtx_sbs1\ATD\Clients - Active\Coffeyville Resources Nitrogen Fertilizer\5283.02\RATA Follow Up Data 1-11-08der (3).xls

## A PPEN DIX D - GAS CA LIBR ATION C ER TIFIC ATES

### I nst rum ent C ert i f i cat i on

All instruments are c ertified by the vendor s with reg ards to interf ere nce, r esponse a

nd repe atability . The following limit s are stated for the instrumentation utiliz ed;

• Resolution: 0.1 ppm

• No ise : L e ss t

he n 0 .5 % o f f

ull sc a le

• L ine a ri ty : + /- 0- .5 % o f f ull sc a le

• Re pe a ta

bil ity : B e tte r t

he n 0 .5 % o f f

ull sc a le

• Z e ro a nd

Spa n d ri ft : L e ss t

he n 0 .5 % o f f

ull sc a le in 1 68 ho ur s.

• I ns tr

ume nt R e sp on se Ti me : 1. 5 to 20 se c on ds (i ns tr ume nt a nd c on fi g ur a tio n d e pe nd a nt)

• All interfer ence < 1%

• All repa irs are perf

ormed by cer tified manufa cture r re prese ntatives

Sy s t em Sam pl e R es ponse:
Denovo ope rate s the sample sy stem at a c onstant flow ra te of a pproxi mately

5 liters / minute and 8 psi sample manifold pressur e. Sample line suction vac uum is allowed to fluctuate w ith the sy ste m de ma nd s. Exc e ss s a mpl e no t di re c te d to the a na ly zer s is e xter

na lly du mpe d to atmosphere

.

Us ing10 0 f

e e t of sa mpl e lin e , th e sa mpl e sy ste m ha s b e e n c a lc ulate d to ha ve a tot a l vo lum e (f ro m sa mpl e pr ob e to i ns tr

ume nt) of a pp ro xima te ly

2. 1 li te rs re su lti ng in a

n in iti a l sa

mpl e response time of 25 seconds. The same c onfig uration, including the bias loop has a c alculate d tot a l vo lum e of

3. 6 li te rs re su lti ng in a

n in iti a l bi a s r e sp on se tim e of 43 se c on ds

.

# Model 600 HCLD NO Interference Data

Interference Response

Date of Test 7/26/2006

Analyzer Type NO Model No. 600-HCLD Serial No. S050301

Calibration Span 3000ppm

Test Gas Type Concentration Analyzer Response (ppm) Wet Dry H2O 2.5% 0 0 CO2 5% 0 0 CO2 15% 0 0 CO 50 0 0 CH4 50 0 0 SO2 N/A N/A N/A NH3 15 0 0 NO N/A N/A N/A N2O 9 0 0 NO2 N/A N/A N/A

## A PPEN DIX E - EXAMPLE CALCULA T IONS

## EXAMPLE CALCULATI ONS

Co r r e c ti on fo r r aw e m iss ion c onc e nt r at ion s t o bi as /dr ift c or r e c te d va lue s:

Eq. 1:

wher e:

cor

r ect ed 

### C = Aver ag e ca libration corr ecte d conce ntration, ppm or per cent

mea s ur ed 

### C = Aver ag e mea sured c oncentr ation, ppm, or perc ent

O 

### C = Av e ra g e of pr e - a nd po st- te st s y ste m bi a s r e sp on se fo r t he zer o g a s,

ppm or perc ent

m 

### C = Av e ra g e of pr e - a nd po st- te st sy ste m bia s re sp on se fo r the up scale

g as, ppm or per cent

ma 

### C = Actual c oncentr ation of the upsca le g as, ppm or per cent

Re lat ive Ac c ur ac y C alc ula ti on:

Eq. 2:

wher e: D = Ar it hm eti c m ean of the dif fer ences betw een t he R M and C EM S v alu es
n = Num ber of data poi nts di = Di ffer ence betw een t he R M and C EM S fo r ind iv idu al data poi nts

Standard Dev iation Calcul ation:

Eq. 3:

whe re :

d 

### S = Standa rd dev iat ion of the d if fer ence betw een t he R M and C EM S v alu e

### Confidence Coefficie nt C alc ulation:

Eq. 4:

whe re : CC = Tw o T ail ed c onfi dence co effi ci ent c or re spond ing to 2.5% er ro r

0.9 75 

### t = t- val ue c or re cti ng fo r n- 1 degr ees of f re edom = 2.306

Relativ e Accura cy of CEMS to RM C alc ulation:

Eq. 5:

whe re : RA = Relative a ccuracy of th e CEMS system to the RM
D = Abso lut e v alu e of the m ean of the dif fer ences CC = Abso lut e v alu e of the c onfi dence co effi ci ent
RM = Averag e RM value or the a pplicab le emission stan dard

Emis sion Rate Calc ulation lbs/MMBtu:

whe re :

E = Pollut ant emission rate, n g/J (lbs/million Btu).

cor r ecte d 

### C = Aver age c ali br ati on c or re cte d c oncen tr ati on, p pm or per cent

MW = Mo lec ula r wei ght o f c om pound, lbs /l b- mo l

d 

### F = Vol um e of com bust ion co mp o n e n ts per uni t of heat co ntent , s cm /J (scf/milli on Bt u).

2d 

### % O = Con cent ra ti on of ox ygen on a dr

y b asi s, per cent

.

## A PPEN DIX F - QU ALITY ASS UR AN CE

## QUA LIT Y A SSU RA NC E / QUA LIT Y C ONT ROL

Specif ic qua lity cont rol mea sur es w ere use d to insure t he g ener a t io n o f r e li able data f rom all sampl in g a nd ana ly si s acti v iti es. Pro per col le cti on and organi z ati on of i nformatio n f ol lo w ed by cl ear

a n d c o n ci se r e p o rt i n g o f th e d a ta w a s a p ri ma ry go a l i n t h e p ro

je ct

.

The o bjecti v e of a qual ity ass uran ce/qual ity con trol (QA/QC) p rogram i s to en sure tha t the pre ci si on

a n d a cc u ra cy

of al l en v i ro n me n ta l da ta gen e ra te d by De N o v o -n v , In c. is co mme n su ra te w i th d a ta qual ity ob jecti v es (DQOs). DQOs a re b ase d o n a co mmon u nde rstandi ng o f t he in tend ed end

u se (s ) o f th e d a ta
, th e me a su re me n t p ro ce ss , a n d t h e a v a i l a b i l i ty o f re so u rc e s. On ce DQO s a re
esta bl is hed , formall y or in f ormal ly , QC proto col ca n b e d efine d for th e me asu rements

.

In th is pro

ject, th e f in al data use rs w il l be Co f f ey v il le Re sou rces Ni trogen Ferti li z ers, US EP A Re gion
V II a n d t h e S ta te o f K a n sa s. Th e D QOs for th i s p ro je ct a re to gen e ra te l e gal l y d e fen si b l e d a ta t o be use d to demons trate compl ia nce w ith Fede ral reg ul ati ons as soc ia ted w ith N SP S Su bpa rt G a nd
state op erati ng pe rmit requi rements relat ed t o ann ual ce rtifica tio n o f co nti nuo us emi ssi on

mo n i to ri n g s y st e ms ( C E M S ).

Tw o b asi c goal s o f

a QC p rogram are to:

1) Co ntrol erro rs; a nd

2) Ve rify tha t the en tire an al y tic al meth od is op erati ng w ith in ac cep tabl e p erformance
li mits.

Use of qual ifie d p erso nne l, rel ia bl e and w el l-ma in tai ned equi pmen t, app ropri ate cal ib rati ons an d
st a n d a rd s, a n d c l o se s u p e rv i si o n o f a l l o p e ra ti o n s a re i mp o rt a n t co mp o n e n ts o f th e QC p ro gra m. The foll ow in g secti ons de scri be the QC re sul ts for mai ntai ni ng i nstru ments and equi pmen t i n a

s t ate of calibration (de f ines the accu rac y or bias err or) , res ults f or m easur ing a continuously
mai ntai ned sta te of

cl ean li nes s (e li min ates i nterferenc e o r co ntami nati on), and the pa per trai l w hi ch
doc umen ts th at the method s w ere pe rf ormed to in structi ons , cali brate d w ith in meth od performance
stan dard s, and/o r traceab le to Na tio nal Tech ni cal Informati on Se rv ic es (NTIS) s tand ard reference
materi al s. Sta nda rds of Q A se t f orth in the Qua li ty A ssu ranc e H and boo k f or A ir Po ll uti on M eas uremen t S y stems, Vo lu me III (U SE PA -600 /4-77 -027 b) w ere stri ctl y foll ow ed.F IE L D D A T A R E D U C T ION

Ex ampl e c al cul ati ons are us ed in the fiel d to ch eck on sa mpl in g cond iti ons an d a l is t of f ormul as

u se d t o r e d u ce t h e fi e l d d a ta

. Th e d a ta c o l l e ct e d w a s re v i e w e d i n the f i e l d by the Pr o je ct M a n a ger

. Erro rs o r disc r ep an ci es were note d o n th e d ata she et. Ap pen di ces of thi s re port pres ent the
stan dard iz ed f orms th at w ere use d to rec ord f ie ld sa mpl in g data

.

INTERNA L QC CHECKS A ND FREQUENCY

QC c hec ks w ere performed to e nsu re the col le cti on of repres enta tiv e s ampl es and the gene rati on

o f v a l i d a n a l y ti ca l r e su l ts o f th e se s a mp l e s. The se ch e cks w e re p e rfor me d b y p ro je ct p a rt i ci p a n ts
th ro u gho u t th e p ro gra m.

QA PROCEDURES

The fol l o w i n g QA

p ro ce d u re s w e re i mp l e me n te d d u ri n g th i s te st p ro gra m:

! Use of de si gnated sampl in g and an al y tic al equi pmen t. T he sa mpl in g equip ment

use d i n th is tes t met al l cal ib rati on and op erati ng cri teri a o f the ap pl ic abl e K ans as De partmen t of He al th a nd En v iro nmen t an d U SE PA M etho ds.

! Sa mpl in g sy stem w as cal ib rated and op erate d a cco rdi ng to Ka nsa s D epa rtment o f
He al th a nd E nvironment and U SE PA do cumen ted proc edu res. A ll si te a cti v iti es i n cl u d i n g a u d i t re su l ts w e re l o gged i n to t h e d a i l y s i te b o o k.

! E q u ip m e n t ca li b r a t io n

. T h e po r t a b le sa m p li n g eq u ip m e n t i s c a l i b r a t e d wit h t wo

co n ce n tr a ti o n s o f U S E P A P ro to co l 1 ga ss e s and a zero gas b e fore t h e fi rs t te st

. Calibration span sett ing s are chec k ed af te r e a ch run. Ot her t est equ ipmen t is
cal ib rated i n a cco rdan ce w ith U SE PA sp eci f ic ati o n s i n Q u a l i t y A ssu ranc e H and boo k
for A i r P o l l u ti o n M e a su re me n t S y st e ms , V o l u me I II ( U S E P A -6 0 0 /4 -7 7 -0 2 7 b ).