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HYDROGEN FLUORIDE EMISSION EVALUATION

ON DRY LIME SCRUBBER FOR ` PALMETTO BRICK COMPANY CHERAW, SOUTH CAROLINA ti

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### MARCH, 1999 DAVIS & FLOYD, INC. JOB NUMBER 60823.00

PREPARED BY DAVIS & FLOYD, INC. ENVIItONMENTAL DIVISION GREENWOOD, SOUTH CAROLINA

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~ ; P.O. Drawer 428 Greenwood, SC 29648 • 816 East Durst Avenue Greenwood, SC 29649 •(864) 229-4413 (office) (864) 229-7119 (fax)



### March 22, 1999 Serial No. HGA-038-99 Job No.: 60823.00



### Mr. Henry Moore Palmetto Brick Company P.O. Box 430 Cheraw, SC 29520 Reference: Emission Testing on Dry Scrubber Dear Mr. Moore: Davis & Floyd, Inc. conducted source test sampling at Palmetto Brick Company, Cheraw, South Carolina, on March 4, 1999. These, tests. were conducted on the outlet gases of the dry lime scrubber.

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### Two copies of the report containing the results of this project are enclosed. A copy of this report has =y been mailed to Mr. Antliony Keeler, South Carolina Department of Health and Environmental Control,

Bureau of Air Quality, 2600 Buil Street, Columbia, SC, 29201. We would like to express our appreciation to you and the Palmetto Brick Company personnel involved in this project for their assistance in the areas of scheduling, physical arrangements, etc. Should you have any questions regarding this work or report, or if we may be of additional assistance, please do not hesitate to contact us. Sincerely, 

### DAVIS & FLOYD, INC.



# ~ H. Gary Anderson, Jr. 

# ~ Field Services



### Environmental Division Enclosures: As stated in letter

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### 1.0 INTRODUCTION 1.1 2.0 TEST OBJECTIVES 2.1 3.0 PROCESS DESCRIPTION 3.1 4.0 SAMPLING AND ANALYTICAL PROCEDURES 4.1 4.1 Velocity Traverse Point Locations 4.1 4.2 Volumetric Flow Rate 4.1 4.3 Moisture and Molecular Weight 4.1 

### 4.4 Hydrogen Fluoride Concentrations 4.2 5.0 SAMPLING RESULTS 5.1 Table 5.1 Hydrogen Fluoride Emission Results Table 5.2 Chloride Emission Results 6.0 ACCEPTABILITY OF RESULTS 6.1 APPENDICES APPENDIX I EPA Metliod 26 Data Reduction APPENDIX II Calculations APPENDIX III Field Data Field Equipment Calibrations APPENDIX IV Laboratory Data Production Data

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### 1.0 INTRODUCTION

Palmetto Brick Company, located in Cheraw, South Carolina, is a manufacturer of ceramic brick. A part of this process is the drying or curing of the brick, which is done in ovens referred to as kilns. On March 4, 1999, emission tests were conducted for the halide hydrogen fluoride and the halogen chlorine on the outlet gases of the recently installed dry lime scrubber. Stanley Broome and Brandon Wilson of Davis & Floyd, Inc. performed this testing. The purpose of the testing was to determine permit compliance.
These tests were observed by South Carolina Department of Health and Environmental Control (SCDHEC) representative, Anthony Keeler.

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### 2.0 TEST OBJECTIVES



### The objective of this testing was to demonstrate compliance with South Carolina Department of Health and Environmental Control (SCDHEC) established air standards for hydrogen fluoride using EPA Method 26A (Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources — Isokinetic Method). This testing, in conjunction with tSCST3 air dispersion modeling, analysis, was used to demonstrate compliance, since compliance is at the facility boundaries, not emission source. The HF emission, rate for this test was 0.224 pounds per hour and is less than 1.80 pounds per hour: Compliance has been demonstrated based on previously submitted and approved modeling. .

2.1 Applicable State Regulations 

### SC Reg. 62.5 Standard No. 2 Ambient Air Quality Standards♦ 

### 1-lydrogen Fluoride: 12-Hr. Ave. = 3.7 ug/m 3 24 Hr. Ave. = 2.9 ug/m 3 1-Wk Ave. = 1,6 ug/m 3 

### 1-Month Ave. = 0.8 ug/m 3♦ 

### HF Emission Rate <1.80 lb/hr has dem onstrated compliance based on previously submitted and approved modeling.

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3.0 PROCESS DESCRIPTION The tested processes consist of two brick manufacturing operations. Raw materials (clay, shale, kaolin, etc.) are mixed together with water and are extruded into brick shapes. The brick is placed on cars that are air dried prior to being placed into kiln (01) or (02) for curing. As a result of curing the brick at approximate temperatures of 1800°F, fluorine contained in the raw materials (clay, shale, etc.) combines with water vapor and is released to the atmosphere as gaseous Iiydrogen fluoride. The dry lime sorption scrubber captures the hydrogen fluoride emissions by combining it with lime, used as the sorption media. The lime material becomes coated with captured fluorine material. The curing process is considered continuous.


### Cmissions from each of the two kilns are routed tlirough a common inlet duct into the dry lime sorption scrubber. Fluorine present in the raw materials will be released to the scrubber as gaseous hydrogen fluoride, where it will be adsorbed onto the limestone.
A time control system associated with the discharge of spent lime from the scrubber ensures that the limestone continues to fall down evenly from the storage silo over the cascades, thus making sure that adsorption of the hydrogen fluoride and the utilization of the limestone granules are optimal.
The supply of flue gas to the scrubber is controlled by means of a differential pressure measuring transducer depending on vacuum in the kilns. This transducer compares the actual and desired values and generates a signal to a frequency converter, which adjusts the scrubber fan motor torque and speed continuously at constant pressure to ensure the proper quantity of flue gas is extracted from each kiln.
The process rate and kiln temperature of each kiln were recorded by Palmetto Brick personnel. It was the responsibility of each kiln supervisor to collect this information. PLOTHRIDU-IGA99\60823-3.DOC 

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### 4.0 SAMPLING AND ANALYTICAL PROCEDURES

4.1 Velocity Traverse Point Locations The velocity traverse point locations were selected in accordance with EPA Method 1, "Sample and Velocity Traverses for Stationary Sources". The scrubber exhaust is equipped witli a circular stack that is 60 inches in diameter. Two sample ports were located horizontally across the stack at a location that was approximately 48 feet downstream of the nearest flow disturbance and 20 feet upstream from the top of the stack. Twelve (12) traverse points were selected for velocity determinations, 6 along each sample port cross-section (see Figure 1).

4.2 Volumetric Flow Rate Stack gas volumetric flow rate was determined in accordance with BPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate". This was performed in conjunction with EPA Method 26A.

4.3 Moisture and Molecular WeiQht Stack gas moisture content was determined as per EPA Method 4, "Determination of Moisture Content in Stack Gases" in conjunction with EPA Method 26A. Stack gas molecular weight was determined by obtaining samples and analyzing for oxygen and carbon dioxide concentrations using a Teledyne Max-5 combustion analyzer.

4.4 Hydrogen Fluoride Concentration Hydrogen Fluoride concentrations were determined in accordance with EPA Method 26A, "Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources - Isokinetic Method". Three one-hour test runs were conducted. The sample train consisted of a one-piece 

# ~ glass-lined probe and glass nozzle, a glass fiber filter (Teflon mat, Paliflex), EPA Method 5 glass

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impingers, and an EPA Method 5 control console. The first two impingers contained 100 ml each of 0.1 N sulfuric acid, the third and fourth impingers each contained 0.1N sodium hydroxide, and the fifth impinger contained 200 milligrams of silica gel. After the testing was completed, the samples were transported to the laboratory where the volume of the impinger catch was measured, the silica gel was weighed, and the impinger solution was transferred to EPA protocol washed glass sample bottles. The impingers were then rinsed with a known volume of D. 1. water, and the rinse was combined with the samples. The samples were then analyzed using ion cliromatography as specified in the method.

PLOTH RI D\HGA99\60823-3. DOC nAvIS & Fld)vfl INC

### 5.1

5.0 SAMPLING RESULTS On March 4, 1999, stack gas emission studies were conducted at Palmetto Brick Company, Cheraw, South Carolina. The results of this testing are found in Tables 5.1 and 5.2.

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### ABLE Sa::ry Hydrogen Fluoride Emission Results Outlet to Dry Lime Scrubber Palmetto Brick Company Cheraw, South Carolina Test conducted: March 4, 1999 Test Time Air Sample

Volume dscm Stack Gas

Flow Rate (dscfm) Emission

Concentration HF mg/m 3 Emission Rate

(lb/hr) Run 41 0906-1011 1.1674 27,648 2.2 0.228 Run 42 1021-1124 1.1743 27,606 2.0 0.207 Run 43 1 1132-1235 1.1671 1 26,384 1 2.4 1 0.237 

### Calculations: 1. Lbs/hr = 1 Ib/454,000 mg x mg/m 3 x Std. Ft. 3 /Min x m 3 /35.31 ft 3 x 60 min/hr. NOTE: Standard cubic feet per minute at 29.92 inches of inercury and 68 degrees F. H2SO4 O.1N Blank = <400 Ivlicrograms HF D.I. Water Blank = <300 Micrograms Chlorine D.I. Water Blank = <400 Micrograms HF
TABLE 5.2 Chlorine Emission Results Outlet to Dry Lime Scrubber Palmetto Brick Company Cheraw, South Carolina Test conducted: March 4, 1999 Test Time Air Sample

Volume dscm Stack Gas

Flow Rate dscfm Emission

Concentration Chlorine mg/m 3 Emission Rate lbs/hr Run # 1 0906-1011 1.1674 27,648 0.6 0.062 Run #2 1021-1124 1.1743 27,606 0.5 1 0.052 Run #3 1132-1235 1.1671 1 26,384- 0.5 1 0.049 

### Calculations: l. Lbs/hr = 1 lb/454,000 mg x mg/m 3 x Std. Ft. 3 1Min x m 3 /35.31 ft 3 x 60 min/hr. NOTE: Standard cubic feet per minute at 29.92 inches of inercury and 68 degrees F. D.I. Water Blank = <300 Micrograms Chlorine 0.1N Na OH Blank = <300 Micrograms Chlorine

PLOTHRID\HGA99\60823-3. DOC nAVIC X. G`r nvn lIUr /D

### 6.1

6.0 ACCEPTABILITY OF RESULTS Isokinetic percentage refers to how closely the sampling rate matches the stack gas flow rate. EPA Method 5 data is acceptable if the isokinetics of the test runs are ] 00 ±] 0 percent. The isokinetic rate of these test runs were as follows:

OUTLET TO DRY LIME SCRUBBER RUN 1 96.85 RUN 2 97.55 RUN 3 98.97

PLOTI-IRIDUiGA99160823 -3. DOC navIc R. ri nvn inir; ,r 4



### APPENDIX 1 EPA Method 26 Data Reduction

PLOTHRIDU-IGA99\60823-3. DOC n6vm r. vi nvn inir 17~FOR:PALMETTO BRICK CO. LOCATION:CHERAW, SC --,,.... ~..~_~ ..., . ... ~ ,,.,..... ~~~ .. TEST METHOD:EPA M26A SAMPLE DATE:3-4-99 

### DAVIS & FLO.YD INC.

POST OFFICE DRAWER 428. GREENWOOD, SOUTH CAROLINA 29648

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### RUN 1

"CO2 CONCENTRATION 0.50 PERCENT 02 CONCENTRATION 20.20 PERCENT CO CONCENTRATION 0.00 PERCENT N2 CONCENTRATION 79.30 PERCENT DRY MOLECULAR WEIGHT OF GAS 28.89 POUND/POUND-MOLE . FINAL IMPINGER WATER VOLUME 470.0 MILLILITERS ..:INITIAL IMPINGER WATER VOLUME 400.0 MILLILITERS SILICA GEL VOLUME INCREASE 9.3 MILLILITERS `'TOTAL MOISTURE COLLECTED 79.3 MILLILITERS TOTAL MOISTURE COLLECTED 3.7430 STANDARD CUBIC FEET MOISTURE CONTENT OF STACK GAS 8.324 PERCENT tMEASURED DRY GAS VOLUME THROUGH METER 39.833 CUBIC FEET 113AROMETERIC PRESSURE 29.75 INCHES OF MERCURY AVERAGE GAS TEMPERATURE THROUGH METER 49.3 DEGREES FAHRENHEIT -AVERAGE GAS DELTA H 1.800 INCHES OF WATER

~ DRY GAS VOLUME THROUGH METER 41.2244 STANDARD CUBIC FEET J MOISTURE CONTENT OF STACK 0.0832 DIMENSIONLESS -.WET MOLECULAR WEIGHT OF GAS 27.98 POUND/POUND-MOLE PITOT TUBE COEFFICIENT 0.84 DIMENSIONLESS `AVERAGE STACK GAS TEMPERATURE 302.7 DEGREES FAHRENHEIT AVERAGE SQUARE ROOT OF DELTA P 0.541 INCHES OF WATER /,STATIC STACK PRESSURE -0.14 INCHES OF WATER II PRESSURE OF STACK 29.74 INCHES OF MERCURY STACK GAS VELOCITY 37.2005 FEET PER SECOND 1 - CROSS-SECTIONAL AREA OF STACK 19.6350 SQUARE FEET

~ 1 STACK GAS VOLUMETRIC FLOW RATE 27647.8148 STD. CFM (68 & 29.92) STACK GAS VOLUMETRIC FLOW RATE 43825.7824 ACFM '_WET BULB STACK GAS TEMPERATURE N/A DEGREES FAHRENHEIT ,'TOTAL PARTICULATE COLLECTED 0.0 MILLIGRAMS PARTICULATE CONCENTRATION 0.0000 GRAINS PER SCF :4PARTICULATE CONCENTRATION @%12 CO2 0.0000 GRAINS PER SCF IPARTICULATE EMISSION RATE 0.0000 POUNDS PER HOUR TOTAL SAMPLING TIME 60.00 MINUTES rDIAMETER OF SAMPLING NOZZLE 0.304 INCHES ;CROSS-SECTIONAL AREA OF SAMPLING NOZZLE 5.0405E-04 SQUARE FEET PERCENT OF ISOKINETIC SAMPLING 96.85 PERCENT

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## DAVIS & FLOYD INC.

POST OFFICE DRAWER 428 GREENWOOD, SOUTH CAROLINA 29648

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### RUN 2 FOR:PALMETTO BRICK CO. TEST METHOD:EPA M26A a OCATION:CHERAW, SC SAMPLE DATE:3-4-99 -jOURCE:DRY LIME SCRUBBER DAVIS & FLOYD, INC. JOB#:60823.00

CO2 CONCENTRATION 0.40 PERCENT .02 CONCENTRATION 20.40 PERCENT

- O CONCENTRATION 0.00 PERCENT N2 CONCENTRATION 79.20 PERCENT ---DRY MOLECULAR WEIGHT OF GAS 28.88 POUND/POUNG-MOLE - rINAL IMPINGER WATER VOLUME 485.0 MILLILITERS INITIAL IMPINGER WATER VOLUME 400.0 MILLILITERS .SILICA GEL VOLUME INCREASE 9.7 MILLILITERS TOTAL MOISTURE COLLECTED 94.7 MILLILITERS

L TOTAL MOISTURE COLLECTED . 4.4698 STANDARD CUBIC FEET ;'VIOISTURE CONTENT OF STACK GAS 9.731 PERCENT ;VIEASURED DRY GAS VOLUME THROUGH METER 40.477 CUBIC FEET BAROMETERIC PRESSURE 29.75 INCHES OF MERCURY AVERAGE GAS TEMPERATURE THROUGH METER 54.7 DEGREES FAHRENHEIT ;qVERAGE GAS DELTA H 1.872 INCHES OF WATER DRY GAS VOLUME THROUGH METER 41.4641 STANDARD CUBIC FEET -MOISTURE CONTENT OF STACK 0.0973 DIMENSIONLESS ;JVET MOLECULAR WEIGHT OF GAS 27.82 POUND/POUND-MOLE `'PITOT TUBE COEFFICIENT 0.84 DIMENSIONLESS .,AVERAGE STACK GAS TEMPERATURE 304.8 DEGREES FAHRENHEIT

~ AVERAGE SQUARE ROOT OF DELTA P 0.548 INCHES OF WATER STATIC STACK PRESSURE -0.14 INCHES OF WATER PRESSURE OF STACK 29.74 INCHES OF MERCURY 'STACK GAS VELOCITY 37.8265 FEET PER SECOND

: =~ I CROSS-SECTIONAL AREA OF STACK 19.6350 SQUARE FEET STACK GAS VOLUMETRIC FLOW RATE 27606.1267 STD. CFM (68 & 29.92) ;STACK GAS VOLUMETRIC FLOW RATE 44563.3127 ACFM
" ✓ 1/ET BULB STACK GAS TEMPERATURE N/A DEGREES FAHRENHEIT TOTAL PARTICULATE COLLECTED 0.0 MILLIGRAMS ;PARTICULATE CONCENTRATION 0.0000 GRAINS PER SCF

~ ARTICULATE CONCENTRATION @%12 CO2 0.0000 GRAINS PER SCF PARTICULATE EMISSION RATE 0.0000 POUNDS PER HOUR ;TOTAL SAMPLING TIME 60.00 MINUTES ,.;:DIAMETER OF SAMPLING NOZZLE 0.304 INCHES CROSS-SECTIONAL AREA OF SAMPLING NOZZLE 5.0405E-04 SQUARE FEET , PERCENT OF ISOKINETIC SAMPLING 97.55 PERCENT

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## DAVIS & FLOYD INC.

POST OFFICE DRAWER 428 GREENWOOD, SOUTH CAROLINA 29648

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### RUN 3 FOR:PALMETTO BRICK CO. TEST METHOD:EPA M26A -,LOCATION:CHERAW, SC SAMPLE DATE:3-4-99 SOURCE:DRY LIME SCRUBBER DAVIS & FLOYD, INC. JOB#:60823.00

CO2 CONCENTRATION

, ?02 CONCENTRATION ;CO CONCENTRATION N2 CONCENTRATION -:,DRY MOLECULAR WEIGHT OF GAS FINAL IMPINGER WATER VOLUME

~ INITIAL IMPINGER WATER VOLUME ,SILICA GEL VOLUME INCREASE TOTAL MOISTURE COLLECTED

- `TOTAL MOISTURE COLLECTED ;
~ ,MOISTURE CONTENT OF STACK GAS

~ MEASURED DRY GAS VOLUME THROUGH METER
" g BAROMETERIC PRESSURE _ AVERAGE GAS TEMPERATURE THROUGH METER "AVERAGE GAS DELTA H I'DRY GAS VOLUME THROUGH METER MOISTURE CONTENT OF STACK ?:WET MOLECULAR WEIGHT OF GAS _iPITOT TUBE COEFFICIENT AVERAGE STACK GAS TEMPERATURE ;<AVERAGE SQUARE ROOT OF DELTA P !STATIC STACK PRESSURE PRESSURE OF STACK 1

~ :STACK GAS VELOCITY Z , , ~ CROSS-SECTIONAL AREA OF STACK STACK GAS VOLUMETRIC FLOW RATE °

~ ,STACK GAS VOLUMETRIC FLOW RATE

~ , kWET BULB STACK GAS TEMPERATURE TOTAL PARTICULATE COLLECTED ,.,PARTICULATE CONCENTRATION 1PARTICULATE CONCENTRATION @ %12 CO2 PARTICULATE EMISSION RATE ,TOTAL SAMPLING TIME `DIAMETER OF SAMPLING NOZZLE 0. CROSS-SECTIONAL AREA OF SAMPLING NOZZLE ::PERCENT OF ISOKINETIC SAMPLING 0.40 20.50 0.00 79.10 28.88 481.0 400.0 12.0 93.0 4.3896 9.844 39.432 29.75 56.9 1.718 40.2026 0.0984 27.81 0.84 305.5 0.524 -0.14 29.74 36.2326 19.6350 26383.9453 42685.5339 

### N/A 0.0 0.0000 0.0000 0.0000 60.00 0.304 5.0405E-04 98.97 

### PERCENT PERCENT PERCENT PERCENT POUND/POUND-MOLE

MILLILITERS MILLILITERS MILLILITERS MILLILITERS STANDARD CUBIC FEET



### PERCENT CUBIC FEET INCHES OF MERCURY DEGREES FAHRENHEIT INCHES OF WATER STANDARD CUBIC FEET DIMENSIONLESS POUND/POUND-MOLE DIMENSIONLESS DEGREES FAHRENHEIT INCHES OF WATER INCHES OF WATER INCHES OF MERCURY FEET PER SECOND 

### SQUAREFEET STD. CFM (68 & 29.92)



### ACFM DEGREES FAHRENHEIT

MILLIGRAMS GRAINS PER SCF GRAINS PER SCF POUNDS PER HOUR

MINUTES INCHES 

### SQUAREFEET PERCEN7

## DAVIS & FLOYD INC.

POST OFFICE DRAWER 428 GREENWOOD, SOUTH CAROLINA 29648

***.«.*..**.*..*««.*.....**.,«...*.«. *** SOURCE SAMPLING DATA SUMMARY ***

TOR:PALMETTO BRICK CO. TEST METHOD:EPA M26A LOCATION:CHERAW, SC SAMPLE DATE:3-4-99 'SOURCE:DRY LIME SCRUBBER DAVIS &FLOYD, INC. JOB#:60823.00

`% CO2 0.50 0.40 0.40 0.43

1 % 02 20.20 20.40 20.50 20.37 ;% CO 0.00 0.00 0.00 0.00 N2 79.30 79.20 79.10 79.20 Dry molecular weight (MD) 28.89 28.88 28.88 28.88 ' Final impinger volume (VF) 470.0 485.0 481.0 478.7 -'=lnitial impinger volume (VI) 400.0 400.0 400.0 400.0 Silica gel vol. increase (VS GEL) 9.3 9.7 12.0 10.3 'Total moisture collected (VIC) 79.3 94.7 93.0 89.0 _,:.Total moist. collected (VM STD) 3.7430 4.4698 4.3896 4.2008 Stack gas moist.content (B WO) 8.324 9.731 9.844 9.300 rMeter dry gas volume (VM) 39.833 40.477 39.432 39.914 _'Barometric pressure (P BAR) 29.75 29.75 29.75 29.75

~ Dry gas meter temp (TM) 49.3 54.7 56.9 53.6 iDry gas orifice pressure (DELTA) 1.800 1.872 1.718 1.797 _iMeter dry gas volume (VM STD) 41.2244 41.4641 40.2026 40.9637 Stack gas moist.content (B WO) 0.0832 0.0973 0.0984 0.0930 Wet molecular weight (MS) 27.9817 27.8213 27.8126 27.8719 A

~ Pitot coefficient (CP) 0.84 0.84 0.84 0.84 Avg stack gas temp (TS AVG) 302.7 304.8 305.5 304.3 ,,(AVG SQ/R DELTA P) 0.5411 0.5479 0.5245 0.5378

~ -Static stack pres. (STATIC P) -0.140 -0.140 -0.140 -0.140

~ Pressure of stack (PS) 29.7397 29.7397 29.7397 29.7397 Stack gas velocity (VS) 37.2005 37.8265 36.2326 37.0865 4 i 1 'Cross-sectional stack area (A) 19.6350 19.6350 19.6350 19.6350

- *Stack gas flow (QS STD CFM) 27647.8148 27606.1267 26383.9453 27212.6290 Stack gas flow (QS ACFM)
~ 43825.7824 44563.3127 42685.5339 43691.5430 Wet bulb temp (WB/T) N/A N/A N/A N/A

~ !Particulate gain (MN) 0.0000 0.0000 0.0000 0.0000 Particulate concent. (C/S) 0.0000 0.0000 0.0000 0.0000 C/S @ %12 CO2 N/A N/A N/A #DIV/0! { Particulate emission rate (CS) 0.0000 0.0000 0.0000 0.0000 Total Sampling Time (TIME) 60.0 60.0 60.0 60.0

~ ';Nozzle diameter (DN) 0.3040 0.3040 0.3040 0.3040

~ Area of nozzle (AN) 5.0405E-04 5.0405E-04 5.0405E-04 5.0405E-04 Percent isokinetic (1) 96.85 97.55 98.97 97.79

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### APPENDIX 2 Calculations



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Determination of Dry Molecular Weight: Md = molecular weight of stack gas (dry basis), Ib/Ib-mole Md = 0.44 (%CO2) + 0.32(%02) +0.28(%N2 + %CO)


### Determination of Stack Gas Moisture: Vi = initial volume of impinger contents, ml V f = final volume of impinger contents, ml Vsgel = moisture collected in silica gel, ml Vi c = total volume of liquid collected in impingers and silica gel, ml Vwstd = volume of water vapor in the gas sample (standard conditions), ft 3 Vwstd = 0.0472 ft 3 /ml x Vic Vmstd = volume of gas through the dry gas meter (std conditions), ft 3 y = calibration factor, dimensionless V m = volume of gas sample through dry gas meter (actual conditions), ft 3 Pbar = barometric pressure at the dry gas meter, in. Hg T m = absolute temperature at meter, oR H = average pressure drop across the meter orifice, in. H20 

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### Vmstd = (17.64 oR/in. Hg) x(V m ) x(y) x ~ 3.6 

### T m B wo = proportion by volume of water vapor in the gas stream, dimensionless M s = molecular weight of stack gas (wet basis), Ib/lb-mole

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### = V wstd + V mstd 

### M s = Md( 1- Bwo) + 1 8 (Bvvo) Determination of Stack Gas Velocity: usavg = stack gas velocity, ft/s K p = 85.49 ft/s(Ib/lb-mole oR) 0 • 5 , constant C p = pitot tube coefficient, dimensionless Tsavg = average absolute stack gas temperature, oR P s = absolute stack pressure, in.Hg P = average velocity head of stack gas, in.H2O

F Ms;( g p — , — ) V savg = K p Cp ( ~ 

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### Deterniination of Stack Gas Volumetric Flow Rate:

Q s = volumetric flow rate, dry basis (std conditions), ft 3 /min A = cross-sectional area of stack, ft 2 Pstd = 29.92 in. Hg Tstd = 528 oR 

### Qs = 60 ( 1- Bwo) x(Vsavg) x(A) x 

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### Determination of Particulate Concentration: C' s = concentration of particulate matter in stack gas, dry basis, grains/std ft 3 M n = total mass of particulate collected, mg
C' s = 0.0154 grains/mg x( Vms.d M n 

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Determination of Particulate Emission Rate: C s = particulate emission rate, dry basis, lb/lir
C = (60min / hr)(QS )(C'S ) s 7,000 

### Determination of Acceptability of Sampling Results 1 = percent of isokinetic sampling An = cross-sectional area of nozzle, ft 2 6 = total sampling time, min

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_ (ml)( 0 R) ~~ ••m se \ bar 13.6 \ c / (e)(Vsa11 s )(P 5 )(A n ) 

### Hydrogen Halide and Halogen Emissions Calculations Retain at least one extra decimal figure beyond those contained in the available data in intermediate calculations, and round off only the final answer appropriately. Nomenclature. Same as Method 5, In addition: 1 BX_ = Mass concentration of applicable absorbing solution blank, mg halide ion

(Cl-, Br-, F-)/ml, not to exceed l mg/ml which is 10 times the published analytical detection limit of 0.1 mg/ml. (It is also approximately 5 percent of the mass concentration anticipated to result from a one-hour sample at 10 ppmv HCI.) C = Concentration of hydrogen halide (HX) or halogen (X2), dry basis, mg/dsem. MHX ° Mass of HC1, HBr, or HF in sample, mg/ MX2 = Mass of C12 or Br2 in sample, mg.
P LOTH RI D W G A 99\60823 -3 . DOC nAvIQ R. vt nvn inlr 

### g

## ~ -., 

### SX-- = Analysis of sample, mg halide ion (CI-, Br-, F-)/ml.

VS = Volume of filtered and diluted sample, ml. Average Dry Gas Meter Temperature and Average Orifice Pressure Drop. See data sheet (Figure 5-2 of Method 5). 

### Dry Gas Volume. Calculate Vm(std) and adjust for leakage, if necessary, using the equation in Section 6.3 of Method 5. Volume of Water Vapor and Moisture Content. Calculate the volume of water vapor Vw(std) and moisture content BWS from the data obtained in this method (Figure 5-2 of Method 5); use Equations 5- 2 and 5-3 of Method 5. lsokinetic Variation and Acceptable Results. Use Method 5, Sections 6.11 and 6.12. Total mg HC1, HBr, or HF Per Sample. MHX = K Vs(SX--BX-) Eq. 26A-4 where: KHCl = 1.028 (mg HCl/mg-mole)/(mg C1-/mg-mole). KHB r = 1.013 (mg HBr/mg-mole)/(mg F-/mg-mole). Total mg C12 or Br2 Per Sample. MX2 = Vs(SX--BX-) Eq. 26A-5 

### Concentration of Hydrogen Halide or Halogen in Flue Gas. C =K mHX,X2/Vm(std) Eq. 26A-6 

### where: K = 10 10 -mg/mg Stack Gas Velocity and Volumetric Flow Rate. Calculate the average stack gas velocity and volumetric flow rate, if needed.

PLOTHRID\HGA99\60823-3. DOC nel/tC V. LIN nvn wntlr .70

### CHANNEL A iNJECT 03/17/99 18:03:19 STORED TO B1N ti 27

. .,

DATA SAVED TO BIN 

### tt 27

INPUT OVERRANGE AT RT= 1.73
EPA 26 03/17/99 18:03:19 CH= `A` PS= 1. FILE 5. METHOD 5. RUN 11 INDEX 1 BIN 27
NAME PPI-1 RT PK HT BC RF 1 0. 0.84 1090008 01 \ 2 0. 5.79 8816 01 TOTALS 0. 1098824
WARNING - h1EMORY AT 5. K- UNPROTECTED CHRONATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 18:14:37 STORED TO BIN 4 28

T5 1 1

. 

### 1 .43 A I

### FILE S. METHOD 5. RUN 11 INDEX 1 BIN 27

NAME PPI9 RT PK HT BC RF 1 0. 0.84 1090008 01 \ 

### 2 0. 5.79 8816 01 TOTALS 0. 1098824 WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 18:14:37 STORED TO BIN 4 28

ER 0 DATA SAVED TO BIN 

### tt 28

EPA 26 FILE 5. METHOD 5
NAME PPM CL- 0.6 TOTALS 0.6 03/17/99 18:14:37 CH= "A" PS= 1. RUN 12 INDEX 1 BIN 28 RT PK HT BC RF 1.43 8408 01 14013.333

8408 ' J



### WARNING - MEIIORY AT 7. K- UNPROTECTED CHROMATOGRAMS wILL BE REPLACED ZZ

### WARNING - MEMORY AT 7. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 18:25:55 STORED TO BIN tk 29

ER 0 DATA SAVED TO BIN 9 29

EPA 26 03/17/99 18:25:55 CH= "A" PS= 1. 

### FiLE 5. IIETHOD 5. RUN 13 iNDEX 1 BIN 29
NAME PPP1 RT PK HT BC RF 1 0. 0.82 769549 02 CL- 2.354 1.53 428339 02 181962.05 3 0. 1.76 73635 02 4 0. 1.96 47757 03 5 0. 3.1 14416 01 f ~ 

### 6 0. 5.21 104305 02 J 7 0. 5.49 1030611 03 TOTALS 2.354 2468612 

### WARNING - MEMORY AT 7. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED

CHANNEL A INJECT 03/17/99 18:37:14 STORED TO BIN 4 30

15 1 

### Z3

T i A M ":i 

### NAME PPM RT PK HT BC RF

~ 1 0. 0.82 829907 01 ; 2 0. 5.63 1032320 01 , ;

R 

# ~ TOTALS 0. 1862227 ` t 

# ~ WARNING - MEMORY AT 0. K- UNPROTECTED CHROIIATOGRAt9S WILL BE REPLACED 

### . k ..:; 

### CHANNEL A INJECT 03/17/99 18:48:32 STORED TO BIN tt 31



# ~

~

~ 3 

# ~ ER 0 DATA SAVED TO BIN 4 31



# ~ EPA 26 

# ~

~ FILE 5. METHOD 5.



# ~ NAME PPM RT PK HT BC RF " 1 0. 0.82 862453 02
~ CL- 2.11 1.55 362755 02 171921 .643

3 0. 1.77 79896 02 

### ; 4 0. 1.96 40920 03 V 

# ~ 5 0. 3.1 14589 01

6 0• 5.2 188293 02 7 0 • 5.48 1032643 03 TOTALS 2.11 2581549

~ ~ 

### uARti 1 t1C - MEtt10RY AT 0 K - UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 03/17/99 18:48:32 CH= 'A" PS= 1.



### RUN 15 INDEX 1 BIN 31

7-4v,. . V , '1. 1 - i.11 - r,



### FILE S. METHOD 5. RUN 1 INDEX 1 BIN 38 NA('1E PPM RT PK HT BC RF 1 0. 0.82 875104 01 - ~ 

### CL- 2.009 ~~ 

### ` 1.52 336541 01 167516 .841 

### TOTALS 2.009 1211645 WARNING - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS W1LL BE REPLACED

CHANNEL A INJECT 03/18/99 09:58:30 STORED TO BIN tt 39

ER 0 DATA SAVED TO BIN 4 39

EPA 26 

### 03/18/99 09:58:30 CH= 'A' PS= 1. FILE 5 METHOD 5. RUN 2 INDEX 1 BIN 39
NAME PPM RT PK HT BC RF.



## : , S 0. 0.82 886085 02 3.302 1.57 704968 08 213497.274 0. 1.79 18717 05 0. 1.99 24773 05 0. 3.14 15527 01 0. 5.22 120925 02 

### 0. 5.5 1029897 03 1

### CL3 4 5 6 

### 7 

### Z$ TOTALS 3.302 2tt00892

## CHANNEL A INJECT 03/18/99 10:15:19 STORED TO BIN 4 42

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EPA 26 03/18/99 10:15:19 CH= 'A' PS= 1. 

## FILE 5. METHOD 5. RUN 1 INDEX 1 B1N 42
NAME PPM RT PK HT BC RF 1 0. 0.82 890723 02 CL— 3.283 1.56 699211 08 212979.185 - ~ 

### 3 0. 1.78 18635 05 4 0. 1.98 14024 05 5 0. 3.11 15292 01 ~ 

### 6 0. 5.44 1037989 01 

### TOTALS 3.283 26"5873 

## WARNING — MEI90RY AT 0. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/18/99 10:26:37 STORED TO BIN U 43

r5 I 

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### CHANNEL A INJECT 03/17/99 19:11:98 STORED TO BIN tt 33

ER 0 

### DATA SAVED TO B1N 4 33

EPA 26 03/17/99 19•11:08 CH= "A" PS= 1. 

### FILE 5. t9ETHOD 5. RUN 17 INDEX 1 BIN 33
NAt9E PPM RT PK HT BC RF 1 0. 0.82 867344 02 CL- 2.098 1.55 359813 02 171503.019 ` 3 0. 1.77 83477 02 4 0. 1.97 42072 03 ~ 5 0. 3.1 16644 01 6 0. 5.47 1032409 01 TOTALS 2.098 2401760 

### WARNING - MEMORY AT 1. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 19:22:26 STORED TO BIN it 34

T6 0 •82 

# al Ll R

### 'i ~t



# ~ CHANNEL A

~



# ~ ER 0 DATA SAVED TO BIN 4 35

~



# ~ ~ 

### INJECT 03/17/99 19:33:44 STORED TO BIN tt 35 

# ~
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### FILE 5. ;•ILTHOij 5. RUN 18 1 NDEX 1 E.: I(a 34 \ 

# ~
NAME PPM RT PK HT BC RF 

# ~ 1 0. 0. 82 8 5? ^' 2 01

? 0. 3 .08 6031 01 3 0. 5.16 200 7 6 02 4 0. 5.64 1023481 03

~ 

### TOTALS 0. 19018"1

,. ~

~ 

### . . ~ 

## WARNING — MEMORY AT 0. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED



# ~ INPUT OVERRANGE AT RT= 1.48
EPA 26 03/17/99 19:33:44 CH= 'A' PS= 1..


# ~ F1LE S. METHOD 5. RUN 19 1NDEX 1 B1N 35

!!! 

### NAME PPh: ~ RT PK HT BC RF ~

1 0. 

# C \ 0.82 839685 01 CL— 2.857 1.51 57086t A1 199811 _457i 

### ~ 

### CHANNEL A INJECT 03/18/99 09:47:12 TORI::ll IU t31N u iu

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# J J ER 0 DATA SAVED TO BIN 4 38

INPUT OVERRANGE AT RT= 1.49
EPA 26 03/18/99 09:47:12 CH= 'A' PS= 1. 

### FILE 5. METHOD 5. RUN 1 INDEX 1 BIN 38 NAME PPM RT PK HT BC RF 1 0. s1 0.82 875104 01 / 

### ✓ CL- 2.009 \~~ V 1 

### .52 336541 01 167516 .841 

### TOTALS 2.009 1211645 

### WARNING - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/18/99 09:58:30 STORED TO BIN tt 39

### i ' NAME PP1-1 RT PK HT BC RF

~ 1 0. 0.82 890723 02


### ~ CL— 3.283 1.56 69921 1 08 212979 . 185

3 0. 1.78 18635 05 4 0. 1.98 14024 05 

## ~ 5 0. 3.11 15292 01

6 0. 5.44 1037989 01



## ~ TOTALS 3.283 2675873

INJECT 03/18/99 10:26:37 STORED TO BIN tt 43

; k

~ ~

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# l DATA SAVED TO BIN tt 43



## ~ ~ 

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### CHANNEL A

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# ~ EPA 26 

# ~ FILE 5
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## ~ 1 CL— 

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### 03/18/99 10:26:37 CH= 'A' PS= 1 RUN 2 INDEX 1 BIN 43 RT PK HT BC RF



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## Palmetto Brick Co. Readings for Emmissions testing

4-Mar-99

Kilni 

# ~ G Production 30 cars per day 

# ~ Type of Brick Old Marlboro modular 

# ~ 

# 1 Type of Body Red 

# ~) ~ Fired weight 3.47 Ibs. Brick per Car 5400 brick per car Kiln 2
Production 30 cars per day TXpe of Brick Ship Ballast modular Type of Body Brown Fired weiglit 3.26 Ibs. Brick per Car 5400 brick per car 

### e



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## Palmetto Brick Co. Readings for Emmissions testing

4-Mar-99

Test 1 Time Time Time Time Tirne



### O` ' a oC.,.. 9' a w. ' 0 4-- L#1 Tem 

### 198(, l o l / L#2 Tem 

### U ; 

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— Lq 02 , LL 00 CF 0,000 CF Gal. L#2 Gas 2 0 (o Oil For Both 

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Test 2 Time Time Time Time Time



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### O o K 2 U 

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. 9 Oil For Both y C33 S Z ~ L 0 3 32 2
Jop Goodin 

# 01, 00 CF 0,000 CF Gal.

00 CF 0,000 CF Gal.



## 3 4+ •i

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## Palmetto Brick - Co. Readings for Emmissions lesting

~ hnluhc

~ +C Me«S , rt~J ~,~ 4-Mar-99 

### Scrubber pfE•

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# 9 '. 05 '; Zo 5 ~ Photohelic 1,, 1,0 Hertz 31 

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l6:20 

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### Hertz

Test 3 Time Time Time Tirne Time



### l(:
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## 37.4o 33. q 37.5



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# ._.. ,.. .. ... . , . .. ....... ,._. .,..._...........e.., ___........ .__. . i

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03/17/99 16:10:18 STORED TO BIN 4 17



# ~

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# . ~ T6 0 •82
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## ~ :X 

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# ~ ER 0 DATA SAVED TO BIN 4 17 

## E ~ s


# ~ INPUT OVERRANCE AT RT= 1.6
EPA 26 03/17/99 16:10:18 CH= 'A' PS= 1.



## ~ FILE S. METHOD S. RUN 1 INDEX 1 CALIB B1N 17
NAME PPM RT PK HT BC RF


## ~ 1 0. 0.82 851952 01 CL— 1. 1.52 87680 01 

## ~ 

# ~ TOTALS 1. 939632


# ~ WARN I NG — I9EI-tORY AT 1. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED



# ~ CHANNEL A INJECT 03/17/99 16:21:35 STORED TO BIN tt 18 T5 1



## ~ T6 0 •82



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### 2,7 DATA SAVED TO BlN 4 18

~~ ~~ 

### lMpUT OVEBRANCE AT RT= 1.47
EPA 26 03/17/99 16:21:35 CH= ^A^ PS= 1. F|LE 5. METHOD S. RUN 2 lMDEX 2 CALlB BlN 18
NAME PPM RT pK HT BC RF | ~ 

### 1 0. 092 860069 01 CL- 1.5 1.5 224357 03 3 0. 2.91 10990 02 - 7 4 0. 3.07 10336 03 5 0. 5.87 10881 01 

## /- 7 ) TOTALS 1.5 1116633
WARNlNG - MEMOBY AT 2. K - UNPBOTECTED CHROMATOGRAM3 WlLL BE REPLACED

~ ~ 

### . CHANNEL A lMJECT 03/17/99 16:32:53 STORED TO BlN U 19

- --

~~ 

### )\ ~~ `/

### CHANNEL A INJECT 03/17/99 RTnPFn Tn RIN 

### 4 19

ER 0 DATA SAVED rO BIN 4 19 

## T INPUT OVERRANCE AT RT= 1.48

EPA 26 03/17/99 16:32:53 Cli= *A" PS= 1. BIN 19 FILE 5. METHOD 5. RUN 3 INDEX 3 CALIB
NAPIE ppil RT PK HT BC RF 1 0. 0.82 846221 01 CL- 2. 1.51 324013 01 3 0. 3.07 14227 01 TOTALS 2. 1184461 WARN I NG - MENORY AT 5. K - UNPROTECTED CHPOMATOGRAMS I LL BE REPLACED
CHANNEL A INJECT 03/17/99 16:44:11 STORED TO 

### B I 'a tt 20 

## T T5 I



### 5 T6 0 .82 39

### ' WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED


# ~ CHANNEL A INJECT 03/17/99 16:44:11 STORED TO BIN # 20 T5 1 ~ :.~ 

### T6 0 •E 2 .t 9

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### 5.90



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# ~ DATA SAVED TO BIN # 20


# -~ INPUT OVERRANGE AT RT= 1.48
EPA 26 03/17/99 16:44:11 CH= 'A" PS= 1. 

# ~ FILE 5. METHOD 5. RUN 4 INDEX 4 CALIB BIN 20



# ~ NAME PPM RT PK HT BC RF 

# 1 0. 0.82 849995 01 

# ~ ~ CL- 2.5 1.51 466875 01 3 0. 5.9 7593 01 C 

# ~ TOTALS 2.5 1324463



# ~ 

# ~ WARNING - I9EMORY AT 7. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED



# ~

~ CHANNEL A INJECT 03/17/99 16:55:30 STORED TO BIN 4'.1 T5 1 T6 0 •82

1 C • 

### 40

# ~ WARNING - 14EMORY AT 7. K- UNPROTECTED ('HROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 16:55:30 STORED TO BIN tt 21



## ER 0 DATA SAVED TO BIN ri 21

INPUT OVERRANGE AT RT= 1 .48 

## EPA 26 03/17/99 16:55:30 CH= 'A' PS= 1. 

### FILE 5. t9ETHOD 5 

## RUN 5 INDEX 5 CALIB BIN 21
NAME PPt9 RT PK HT BC RF 1 0. 0.82 846731 01 ' CL- 3. 1.51 615800 01 3 0. 5.84 16862 01 , TOTALS 3. 1479393 

## COEFFICIENTS OF LEAST SQUARES FIT TO A QUADRATIC EQUATION FILE ENTRY KA KB KC 1 0 .1934^+05 0 .1824^+06 - . 108^+06 

## WARNING - MEI10RY AT 1. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

# .1 `
~ 

# ` CHANNEL A INJECT 03/17/99 17:06:48 STORED TO BIN 1t 22 Tr , S- h

•-. i NARN 1 NG

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### AT 1. K UNPROTECTED CHI20.lATOGRAMS W I LL BE REPLACED

~
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### CHANNEL A INJECT 03/17/99 17:06:48 STC'RED TO BIN # 22 

## ~ T5 1 

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## ~ ~ INPUT OVERRANGE AT RT= 1.48
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# .~ F1LE 5. METHOD 5. RUN 6 lNDEX 1 BIN 22

~ 

### NAME RT PK HT BC RF 

## ~ PPM 

## , ~ 1 0. 0.82 850856 01 

## ~ ~ CL- 1.946 1.51 320075 03 164478 .246 TOTALS 1.946 1170931



## ~ WARN I NG - P1EM0RY AT 3. K- UNPROTECTED CHROIrIATOGRAMS WILL BE REPLACED



## ~ CHANNEL A INJECT 03/17/99 17:18:06 STORED TO BIN tt 23 1 1 T5 1 T6 0 • 82 %-:



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INPUT OVERRANGE AT RT= 1.59
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### FILE 5. METHOD 5. RUN 7 I NDEX 

## 1 BIN 23
NAME PP(9 RT PK HT BC RF 1 0. 0.82 848747 01 CL— 0.992 r 1.51 91936 01 92677.419 '?

. 

### TOTALS 0.992 940683 

## WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 17:29:25 STORED TO BIN tt 24

T5 1 ff-Irl.



## 43.- ~ -- - - AT 

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### INPUT OVERRANGE AT RT= 1.57 1 EPA 26 03/17/99 17:29:25 CH= 'A' PS= 1.

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# ~ FILE 5. METHOD S. RUN tt INDEX 1 BIN 24 

## 1 NAME PPM RT PK HT BC RF ` 1 0. 0.82 859661 01 

### ~
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### .~ 

# ~ WARNING - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED


# ~ CHANNEL A INJECT 03/17/99 17:40:43 STORED TO BIN tt 2 

### 5 -~ T 5 1► 

### T6 0 82

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## 44

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~



### .~ 

### CHANNEL A INJECT 03/17/99 17:40:43 STORED TO BIN # 25 T5 1

t = T 6 0 • 82 1.49 E 

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# .~ INPUT OVERRANGE AT RT= 1.46
EPA 26 03/17/99 17:40:43 CH= 'A' PS= 1. 

### FILE 5. hIETHOD 5. RUN 9 INDEX 1 BIN 25
NAME PPI-i RT PK HT BC RF 

# ~ \

1 0. 0.82 850552 01 ' CL— 2.028 ` 

### ~ 1.49 341443 03 168364 .234 

### ~ 3 0. 

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# ~ WARNING — MEI-tORY AT 2. K— UNPROTECTED CHROl9ATOGRAMS WILL BE REPLACED



# ~ n 

### CHANNEL A INJECT 03/17/99 17:52:01 STORED TO B1N tt 26 i.

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# ~ T5 1 T6 0 •82 1.49

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## 46'

### CHANNEL A I NJECT 03/ 17/99 17 : 52: 01 S'1"ORED TO B I N 4 26

DATA SAVED TO BIN tt 26

INPUT OVERRANGE AT RT= 1 .46 ,EPA 26 03/17/99 17:52:01 CH= "A" PS= 1. FILE 5 METHOD 5 RUN 10 INDEX 1 BIN 26
NAI9E 1CL4 5 TOTALS PPt9 RT 0. 0.82 2.039 , 

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CHANNEL A 1NJECT 03/17/99 18:03:19 STORED TO BIN U 27

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NAME PPH RT PK HT BC RF 1 0 0.81 313059 02 F- 4. 1.04 595309 03 / 3 0. 1.81 216299 01 ^

. 4 0. 3.28 10354 01 5 0. 4.54 7878 02 6 0. 4.84 1026131 03 TOTALS 4 2169030 WARN\NC - HEHORY AT 2. K - UNPROTECTED CHROHATOCRAHS W|LL BE REPLACED

CHANNEL A |NJECT 03/17/99 12:02:18 STOBED TO 8IN 4 \\Y

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~ NAME PPf-I RT PK HT BC RF

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## ~ COEFFICIENTS OF LEAST SOUARES F1T TO A OUADRATIC EOUATfON 1 FILE ENTRY Kri KB KC

~ 1 0 1 1 k6 , '+04 0. 1239^+06 0.7786^+05



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## COEFFICIENTS OF LEAS'i SQUARES F1T TO A QUADRATIC EQUATION FILE ENTRY KA KB KC
~ 1 0.1186^+04 0.1239^+06 0.7786^+05 

## WARNINC - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED

CHANNEL A INJECT 03/17/99 12:13:37 STORED TO BIN # 120

EPA 26 03/17/99 12:13:37 CH= 'A' PS= 1. 

## Y 

# ~ FILE 5. METHOD 5. RUN 6 INDEX 1 BIN 120

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### NAME PPM RT PK HT BC RF 1 0. 

### 0.81 310179 02
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### 2.819 1.05 436629 03 154888 .022
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# ~ TOTALS 2,819 1996061

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CHANNEL A INJECT 03/17/99 12:24:55 STORED TO BIN lk 121

ER 0 

## DATA SAVED TO BIN 4 121

INPUT OVERRANGE AT RT= 1.35
EPA 26 03/17/99 12:24:55 CH= "A" PS= 1. 

## FILE 5. METHOD 5. RUN 7 INDEX 1 BIN 121
NAME PPM RT I-1: HT BC RF 1 0. 0.81 347808 01 F- 0.855 1! 

## ~ 'v' 1.06 184733 01 216062 .378 4 D 3 0. ° 1.82 219155 01 

### 4 0. 4.54 6877 02 5 0. 4.84 1024758 03 

### TOTALS 0.855 1783331 

## WARNING - MEMORY AT 2. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 12:36:12 STORED TO BIN Jt 122 

## 50

T5 1

## W1LL BE PEPLACED

CHANNEL A 1NJECT 03/17/99 12:36:12 STORED TO BIN.tt 122

ER 0 DATA SAVED TO BIN 4 122



## INPUT OVERRANGE AT RT= 1.36
EPA 26 03/17/99 12:36:12 CH= 'A' PS= 1. 

## FILE 5. METHOD 5. RUN 8 INDEX i BIN 122
NAME PPM RT PK HT BC RF 

# ~ 1 0. 

## 1 0.81 348907 01 ~ 

### F- -.039 1.13 72992 01 1. 3 0. 1.82 212821 01 4 0. 4.54 6827 02 5 0. 4.84 1026623 03 TOTALS -.039 1668169


## WARNING - MEMORY AT 1. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED

CHANNEL A INJECT 03/17/99 12:47:30 STORED TO BIN #t 123 r5 1 .04

1 .82 

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# 4 PA 26 03/17/99 12:47:30 CH= "A" PS= 1.



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### PPM RT PK HT BC RF l ~ 

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### 2.642 1.04 413563 03 156533.939 

## ~ 3 0. 1.82 217904 01 4 0. 4.54 7640 02 5 0. 4.84 1027422 03



## ~ TOTALS 2 .642 1976350



## ~ 

## UWARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

~

t 

# ~ CHANNEL A INJECT 03/17/99 12:58:48 STORED TO BIN tt 124



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## ; WARNING - MEMORY AT 5. K- UNPROTECTED i,riROMATOGRAMS W1LL BE REPLACED

CHANNEL A INJECT 03/17/99 12:58:48 STORED TO BIN # 124



### DATA SAVED TO BIN tt 124

INPUT OVERRANGE AT RT= 1.34
EPA 26 03/17/99 12:58:48 CH= 'A" PS= 1. 

### FILE 5. METHOD 5. RUN 10 INDEX 1 BIN 124

NAME PPM RT PK HT BC RF 1 0. 0.81 307888 02 

## F- 2.679 1.04 418451 03 156200.572 3 0. 1.82



# ~ _. .. 217147 01 t 4 0. 4.54 8019 02 5 0. 4.84 1027293 03 TOTALS 2.679 1978807 

### WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED
CHANNEL A INJECT 03/17/99 13:10:06 STORED TO BIN 4 125

- 

## 5 - 3

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### CHANNEL A INJECT 03/17/99 13:10:06 STORED TO BIN

ER 0 DATA SAVED TO B I N tt 125



### EPA 26 03/17/99 13:10:06 FILE 5. METHOD 5. RUN 11 INDEX
NAME PPM RT PK H•T BC RF 1 0. 0; 81 299768 02 F- 7.675 1.04 1098941 02 143184.538 

### 3 0. 1.47 1120856 02 4 0. 1.85 342915 02 5 0. 2.83 130653 03 6 0. 3.26 10666 01 

### 7 0. 4.56 11031 02 8 0. 4.88 1024503 03 TOTALS 7.675 4039333 

## WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED

CHANNEL A INJECT 03/17/99 13:21:25 STORED TO BIN 

## t 126 T5 1 

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EPA 26 03/17/99 14:51:50 CH= 'A' PS= 1. 

### FILE 5. METHOD 5. RUN 16 INDEX 1 B1N 6 NAME PPM RT PK HT BC RF 

## ~ 1 0. 0.81 340024 01 

# F- 1.683 1.05 289851 01 172222.618 3 0. 1.49 1115117 02 

# ~ 4 0. 1.79 175837 03 5 0. 2,8 23408 01 6 0. 4.54 .9427 02 7 0. 4.82 1024761 03 TOTALS 1.683 2978425 

### WARNING - MEMORY AT 7. K- UNPROTECTED CHRO14ATOGRAMS WiLL BE REPLACED

CHANNEL A INJECT 03/17/99 15:03:08 STORED TO BiN tt 7 

# SS;HANNEL A INJECT 03/17/99 

## 13:32:43 STOREll TO BIN it 127


# ~ S

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### DATA SAVED TO B 1 N Jk 127

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## FILE 5. METHOD 5.
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### 03/17/99 13:32:43 

## RUN 13 INDEX CH= 'A" PS= 1. 

## 1 BIN 127
; NAME PPM RT PK HT BC RF


# ~ 1 0. 0.81 301216 02 -, F— 7.576 1.04 1084933 02 143206.617 3 0. 1.48 1114912 02 4 0. 1.86 296901 03 

### 5 0. 2.83 89237 01 a 6 0. 3.26 12103 01 

# ~ 7 0. 4.56 10318 02 8 0. 4.89 1026313 03


# ~ TOTALS 7.576 3935934 

## WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A INJECT 03/17/99 13:44:01 STORED TO BIN # 128 15 1



### 1 .47

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## 56

### 03/17/99 15:03:08 CH= 'A' PS= 1. RUN 17 INDEX 1 BIN 7 RT PK HT BC RF 0.81 339563 1.05 278259 1.49 1084960 1.79 112693 2.8 ?1897 4.54 7213 4.82 1025949 

### 2870535 01

01 174675.874 02 03 01 02 v 03 .-.

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~ TOTALS 1.593 7

1 .3 

### INJECT 03/17/99 15:03:08 STORED TO BIN 4 7



# ~ WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED ~


# ~ CHANNEL A INJECT 03/17/99 15:14:26 STORED TO BIN 4 8 TS 1 1.03
~ 

# 575 , 4 272 

### ED CHROMATOGRAMS WILL BE REPLACED
CHANNEL A INJECT 03/17/99 13:55:19 STORED TO BIN 4 1

ER 0 DATA SAVED TO BIN 4 1


### 03/17/99 13:55:19 CH= 'A' PS= 1.

METHOD 5. RUN 15 INDEX 1 BIN 1 PPM RT PK HT BC RF 0. 0.81 299787 02 

# ~ 17 7.694 1.04 1101728 02 143193 .137 ,. 0. 1.48 1112608 02 0. 1.86 289461 03 

# ~ 5 0. 2.82 860 /9 01 6 0. 4.56 8791 02



# ~ ~ 7 0. 4.89 1024467 03


# ~ TOTALS 7.694 3923221


# ~ WARNING - MEMORY AT 6. K- UNPROTECTED CHROMATOGRAMS W[LL BE REPLACED 

# ~ RN=12 CHANNEL A INJECT 03/17/99 14:06:37 STORED TO BIN # 2 571 

# ~ T5 1 

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### TOTALS 7.694 39232?I WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED RN=12 CHANNEL A INJECT 03/17/99 14:06:37 STORED TO BIN # 2

ER 0 DATA SAVED TO BIN tt 2

INPUT OVERRANGE AT RT= 1.3


### EPA 26 03/17/99 14:06:37 CH= 'A' PS= 1. FILE 5. METHOD 5. RUN 13 INDEX 1 BIN 2 

# 05 1IK

NAME PPM RT PK HT BC RF 1 0. 0.81 334587 01 F— 1.761 1.05 2997E4 01 170235.094 3 0. 1.5 1135848 02 —, — 4 0. 1.86 320741 02 5 0. 2.82 73997 

# ~ W 03 `x 

### 6 0. 4.54 5722 02 7 0. 4.84 1026555 03 

### TOTALS 1.761 3197235
WARN I NG — MEI-IORY AT 6. K— UNPROTECTED CHROMATOGRAI9S WILL BE REPLACED 

# Sq

### CHANNEL A IN.IECT 03/17/99 14:17:55 STORED TO BIN 4 3

ER 0 DATA SAVED TO BIN # 3

INPUT OVERRANGE AT RT= 1.53 EPA 26 03/17/99 14:17:55 F1LE 5. METHOD 5. RUN 14 INDEX 1
NAME PPM RT PK HT BC 1 0. 0.82 703053 01 2 0. 2.42 202032 01 3 0. 4.62 1015563 01 TOTALS 0. 1920648 CH= ' A' PS= 1 . BIN 3 RF V

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED

CHANNEL A iNJECT 03/17/99 14:29:14 STORED TO BIN tk 4



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### WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED
CHANNEL A INJECT 03/17/99 14:29:14 STORED TO BIN 4 4

ER 0 DATA SAVED TO BIN 4 4
EPA 26 03/17/99 14:29:14 CH= "A" PS= 1. 

### FILE 5. METHOD 5. 

### RUN 15 INDEX I BIN 4 NAME PPM RT PK HT BC RF 1 0. 1.42 8397 01 2 0. 6.1 110690 01 TOTALS 0. 1 

### ~ 9087 

### WARNING — MEMORY AT 7. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED
CHANNEL A INJECT 03/17/99 14:40:32 STORED TO BIN tt 5



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### EPA 26 03/17/99 14:40:32 CH= 'A' PS= 1.


## ~ FILE 5. METHOD S. RUN 16 INDEX I BIN 5

..~ 

### NAME PPM RT PK HT BC RF

.~ s „

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# ~ 1 0. 0.81 319245 02 ` 

### F— 2.454 1.04 389093 03 158554.74

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### `^ 4.54 12255 02 

### .4 5 0. 4.82 1025229 03


# ~ TOTALS 2.454 1957093 p WARNING — MEMORY AT 7. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACEU

.,~ 

## r~ CHANNEL A INJECT 03/17/99 14:51:50 STORED TO BIN tt i T 5 1


# ~ 81 1.79 1.49

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### TOTALS 1.593 1.49 1084Y60 1 .79 1 126`3 2.8 2185'7 4 .54 7213 4 .82 102'

~ 5949 

### 2870535 03

01 02 

## ~ 03 ~

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### WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED



### L CHANNEL A INJECT 03/17/99 15:14:26 STORED TO BIN ri 8



## ER 0 DATA SAVED TO BIN 4 8

INPUT OVERRANGE AT RT= 1 .34 

### EPA 26 

### 03/17/99 15:14:26 CH= 'A' PS= 1. 

## FILE 5. METHOD 5. 

## RUN 18 INDEX 1 BIN 8
NAME PPM 1 RT PK HT BC RF 1 F— 0. J 081 4.376 ~ 1.

.03 312128 643008 02

03 146939.671 ~

~~~ .;.. 3 0. 

### 1.79 215309 01 4 0. 4.54 6728 02 5 0. 4.82 1025216 03 

### TOTALS 4.376 2202389 (, 3

. ~ . 

## WARNING — MEMORY AT 6. K— UNPROTECTED a 

## CHROMATOGRAMS WILL BE ,f• .•• 

## REPi.AC0:-

... . . . ~ 

### ... ~ 

### ., . ':,:, _. • .. ~~,~. ~ : 1



# ~ I NO DATA, CHANNEL A 

# I WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED

CHANNEL A INJECT 03/17/99 15:38:19 STORLD TO B1N 4 10

E R 0 

## ~ DATA SAVED TO BIN tt 10

~ 

### I NPUT OVERRANCE AT RT= 1.3 C 

### /,



# ~ EPA 26 03/17/99 15:38:19 CH= 'A' PS= 1.


## ~ FILE 5. METHOD 5. RUN 1 INDEX 1 BIN 10
NAME PPM RT PK HT BC RF 

## ~ 1 0. 0.81 316248 02 F— 2.588 1.05 40655e_' 03 157091.19 

# ~ 3 0. 1.5 1122581 02 4 0. 1.79 192467 03 5 0 2 8 24003 01 z— 

## ~ 6 0. 4.56 6673 e2 7 0. 4.84 1025486 03 

## ~ r

.~ TOTALS 2.588 3094010 r
— 6A 

## ~ WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOCRAMS W1LL BE REPLACED s t 

# ~

## QUALITY CONTROL DATA

.~

~ ~ 

## Davis & Floyd Clayton Project No..72181.00

Chlorine



## (o S

## AJ,:,,

72-/

✓ / 

# z •' ~ - ° j y / ~ o. - •;: ~ ~" l r4 ~~.~ ~ ~~ ;~,~ ✓ — 41-e

4C~ L~ C. llu L--Z; 

### / ) =- 

### C 3 2~~ 

# 0 ~ - /,-,

~ - ,L7f

i 

# ..'_i

APPENDIX 4 Laboratory Data Production Data

PLOTHRIDIHGA99\60823-3. DOC 

## L1 nAVIC .c. 9?1 nvn INry~
~

~
~ Detroit Regional Office

22345 Roethel Drive Novi, MI 48375 (248) 344-1770 Fax (248) 344-2655 

# Clayton LABORATORY S E R V I C E S
March 18, 1999

-- i Mr. Stanley Broome

~ DAVIS & FLOYD

816 East Durst Street Greenwood, SC 29649

Clayton Project No. 72181.00 Client Reference: 60823.00/PALMETTO BRICK Dear Mr. Broome: 

### Attached is our analytical laboratory report for the samples received on K; .. ~ ~ .')rrRic ~ . !V'Rr

- f 

### x ~ 

### -Marc' ~



### 1.°: ~ 

### ±'^1999: Also enclosed is a copy of the Chain-of-Custody record c 

### _.-._. ... . .: acknowledging receipt of these samples.

= Please note that any unused portion of the samples will be discarded after t
~~ ^J4i - ~ rP,xiTial ~1'~~ 19'9'9; unless you have requested otherwise.



### ,. i We appreciate the opportunity to assist you. If you have any questions
~ 

### concerning this report, please contact a Client Services Representative at

(800) 806-5887. 

### Sincerely,

Laura R. McMahon Supervisor, Client Services Laboratory Services Detroit Regional Office LRM/gt 

### Attachments



# ~ ~0 ~



# ~ >, Clayton Laboratory Services is a Division of Clayton Group Services, Inc.

## Clayton

~ Table 1 LABORATORY 5 E R V I C C S 

# ~ Analytical Results for Page 2 of ~ DAVIS & FLOYD 

## ~ Clayton Project No. 72181.00 Client Reference#: 60823.00/PALMETTO BRICK

r, - Sample Identification: SAMPLE #1 .1N H2SO4 Date Sampled: 03/04/99 Lab Number: OOla Date Received: 03/09/99 Sample Type: Impinger / Bubbler Air Volume (L): 1167.2 Analyst : LK

~ -y 1

-~ Analytical Results

---------------------- LOD Method Date

~ 

# r~ Analyte (ug) (mg/m3) (ug) Reference Analyzed

~ ~ F 

### ~ y Hydrofluoric acid 2f 2.2

~ r 00 v...,. 400 EPA 26 03/ 1 7/9 ~ 

## ~

--------------------------------------------------------------------------------------------



## ~ Sample Identification: SAMPLE #2 .1N H2SO4 Date Sampled: 03/04/99 i 

## ~ Lab Number: 002a Date Received: 03/09/99 Sample Type: Impinger / Bubbler Air Volume (L): 1173.8 Analyst : LK



# ~ Analytical Results

---------------------- LOD Method Date Analyte (ug) (mg/m3) (ug) Reference Analyzed



## ~ ~ Hydrofluoric acid

-------------------------------------------------------------------------------------------- 2400 2.0 400 EPA 26 03/17/9c

4

~

~

Y !

~~ 

## Clayton Table 1 (continued) EABORATORY 

# ~ 5[ R V I C E 5 Analytical Results . for Page DAVIS & FLOYD Clayton Project No. 72181.00



## ~ . Client Reference#: 60823.00/PALMETTO BRICK

•~ .v



## ~ Sample Identification: SAMPLE #3 .1N H2SO4 Date Sampled: ` Lab Number: 003a Date Received: Sample Type: Impinger / Bubbler Air Volume (L): Analyst: LK 

## ~ 3 of ~

03/04/99 03/09/99 1138.2

rn ; M1
( ± ~ f Analytical Results
---------------------- LOD Method Date 

# ;.~ Analyte (ug) (mg/m3) (ug) Reference Analyzed

~ Hydrofluoric acid ~ v 2.4 °` 400 EPA 26 03/IT/3` "; ~ ~ ~ -------------------------------------------------------------------------------------------

.~
~ Sample Identification: H2SO4.1N BLANK Date Sampled: ;• Lab Number: 004a Date Received: Sample Type: Impinger / Bubbler Air Volume (L): ,.; Analyst: LK 03/09/99

Y' Analytical Results
---------------------- LOD Method Date Analyte (ug) (mg/m3) (ug) Reference Analyzed Hydrofluoric acid 

# ~ _•. -- 400 EPA 26 03/17/9 r

-------------------------------------------------------------------------------------------



### ✓ 7 0

## @ 

## Clayton Table 1(continued) RTORY S E B B VI C E S 

# ~ Analytical Results for Page 4 of DAVIS & FLOYD 

# ~ Clayton Project No. 72181.00 Client Reference#: 60823.00/PALMETTO BRICK

. ~
r^r Sample Identification: NAOH.IN BLANK Date Sampled: -- Lab Number: 005a Date Received: 03/09/99 

### Sample Type: Impinger / Bubbler Air Volume (L): -- 

## ~ Analyst: LK

Analytical Results
---------------------- LOD Method Date 

## ~ Analyte (ug) (mg/m3) (ug) Reference Analyzed

f Chlorine <3.,Q.p :. . -- 300 EPA 26 03/17
- 19' 

# ~ -------------------------------------------------------------------------------------------

L 

### ~



## ~ Sample Identification: D.I. WATER BLANK Date Sampled: Lab Number: 006a Date Received: 03/09/99 

### Sample Type: Impinger / Bubbler Air Volume (L): --


# ~ Analyst: LK



## ~ Analytical Results
---------------------- LOD Method Date Analyte (ug) (mg/m3) (ug) Reference Analyzed
Chlorine <300 == 300 EPA 26 03/17/9 , 

## ~ Hydrofluoric acid 

## ~ 400 400 EPA 26 03/17/9 1 +.; ;...

-------------------------------------------------------------------------------------------



### ~

~

~ R ~

. t

:

### i 

## Clayton
~ Table Analytical 1 (continued) Results EABORATORY SE RVIE ,, [S for Page 5 of E DAVIS & FLOYD Clayton Project No. 72181.00 6; Client Reference#: 60823.00/PALMETTO BRICK

3



### ~ M Sample Identification: SAMPLE #1 .1N NAOH Date Sampled: 03/04/99 Lab Number: 007a Date Received: 03/09/99 Sample Type: Impinger / Bubbler Air Volume (L): 1167.2 

### ~ Analyst: LK L. s

~ 31 7

~ S Analytical Results
---------------------- LOD Method Date Analyte (ug) (mg/m3) (ug) Reference Analyzed >►

~ 

# ~ Chlorine 700

-------------------------------------------------------------------------------------------- 0.6 300 EPA 26 03/I7'/9'-



# ~ f~ Sample Identification: SAMPLE #2 .1N NAOH Date Sampled: 03/04/99 c 

### ~ Lab Number: 008a Date Received: 03/09/99 Sample Type: Impinger / Bubbler Air Volume (L): 1173.8 

# s~ Analyst: LK



# ~ ' Analytical Results
---------------------- LOD Method Date Analyte (ug) (mg/m3) (ug) Reference Analyzed 

# '

~ 

# ~ Chlorine

----------------------------------- 600

------------ 0~5

------------- 300

----- EPA
- 26 ---

--- 03/17/9'



# ~

~ 

# ~ -7L

## Clayton Table 1 (continued) LABORATORY S f R V I C E S Analytical Results

for Page DAVIS & FLOYD Clayton Project No. 72181.00 Client Reference#: 60823.00/PALMETTO BRICK 6 of 6

.i

t Sample Identification: SAMPLE #3 1N NAOH ' Lab Number: 009a Sample Type: Impinger / Bubbler I Analyst: LK i

..~ Date Sampled: Date Received: Air Volume (L): 03/04/99 03/09/99 1138.2

i }
y Analytical Results

----------------------
~ Analyte (ug) (mg/m3) 

### ~
? Chlorine 600 0.5, 1 General Notes 

### ~ <: Less than the indicated limit of detection (LOD) 

### ~ --. Information not available or not applicable. LOD Method (ug) Reference
300 EPA 26 Date Analyzed
03/17/39



# 13

## QUALITY CONTFOL DATA
Davis & Floyd C(ayton Project No..72181.00 Hydrofluoric acid

-2~, 30 -~ 

# 3L '%
~ 

# !-;• ~~=~ 

# _z = l rl ~ 

# iD ~ , e

. 

# I
. i ~ /G ' ' 7- z
~

~ — / I 5-. r ( ~ S- n . t / •, - — /^j

/L 

### 7
. ~ 

### K 3 Zlyl - G I ,3G- 3 ~ • / , •

~ . 5 ✓

02- ,36:3 i. ~7~ ✓ ',~ ~ 3 .a-. 63 ~ / ~~~,/'~ ✓ 

## a .~ 

# _ -

( (,4-11cv x'

lt'T(c e:'ou;.v ~ r.c//rilt ~ ~c ~-• ~ - ~ i c.

~ C

~ c~ -t l.C- ~_ '~'~ 'r' ' . ~ s .r ~ JJ_ ~ // '7` rCti ~ ~ Gt ~ LLt .•L- ~
~ ~~ P-c

~ l,.r, r ~ C 'SGC ~ ~ ~ <' )I"
~ .(' ,,4• ` 1

,~

~ J /E / ~ ,~ • , < ~ ~ / <, Sb •5 

# A Lm2 ~ 

### A 

## 1 ~ Jk- . 4 -% 

### - ISq3 n''Q X 

### ~ DF~ 63

~ 

### 2 ,

~ 

### Q = 2®
~ 

### b AA- 14" ~

## NAME PPhI RT PK HT BC

1 0. 0.81 349059 01 F- 1. 1.06 200109 01 3 0. 1.82 213944 01 4 0. 4.54 7987 02 5 0. 4.85 1024009 03 

### .RF

,I 

### o ~ ~ AV ,: I
~ 

# ._ l ~

~


### ~ 

### WARNING - 19EMORY AT 4. K- UNPROTECTED CHrZOMATOGRAMS WILL BE REPLACED

CHANNEL A 1NJECT 03/17/99 1]:]7:06 STORED TO BIN U 115



## ER 0 DATA SAVED TO BIN 4 115

INPUT OVERRANGE AT RT= 1 .35 

## EPA 26 03/17/99 11:17:06 CH= 'A" PS= 1. 

## FILE 5. METHOD 5 RUN 1 INDEX ] CALIB BIN 115

TOTALS 1. 1795108


### WARN I NG - ME190RY AT 3. K- UNPROTECTED CHROth1ATOGRAhIS WILL BE REPLACED

CHANNEL A I NJECT 0_3/ 17 1 1:2-8: 24 STORED TO B 1 N 4 116 7l0 T5 1

### CHANNEL A INJECT 03/17/99 11:28:24 STORED TO BIN 4 116

ER 0 DATA SAVED TO BIN tt 116



### INPUT OVERRANCE AT RT= 1.35
EPA 26 03/17/99 11:28:24 CH= "A" PS= 1. FILE 5. HETHOD 5. RUN ? INDEX ? CALI6 BlN 116
NAh1E PPIlI RT PK HT BC RF 1 0. 0.81 340851 01 

### F- 2. 1.05 339056 01 3 0. 1. ti` 215643 01

~ 4 0. 4.54 8901 02 5 0. 4.t35 1025035 03 TOTALS ? . 1929485


### WARN I NG - h1Eh10RY AT 1. K- UNPROTECTED CHROPIATOCRAhIS WILL BE REPLACED



### CHANNEL A INJECT 03/17/99 11:39:42 STORED TO BIN a 117



### I 15 1 1 .oS 

### 77

## CHANNEL A

~

, ~

~

~ r{ 

### r 9 

### I NJECT 03/ 17/99 1 1: 51 : 00 STORED TO B I N 4 1 1 8 i 

## + .54

:x 4 .85


## ~ E R 0 DATA SAVED TO B1N tt 117

; ~ 

## OVERRANCE AT RT= 1.34 g 

# ~ INPUT
EPA 26 03/17/99 11:39:42 CH= "A" PS= 1. w~ 

## FILE 5. 19ETHOD S. RUN 3 INDEX 3 CAL1B BIN 117 : y NAI-IE PPhI RT PK HT BC RF

.~

1 0. 0.81 313611 02 , '1 

### ~ F- 3. 1.05 451907 03



### ~~ :.. 

### ~ 3 0. 1. 8 215888 01

4 0. 4.54 8461 02 

### ~
~ 5 0. 4.85 1026467 03 

### TOTALS 3. 2016333 ;•.,. 

### WARN i NG - 19EI-10RY AT 5. K - UNPROTECTED CHROt9ATOCRAt9S WILL BE REPLACED



### ` ER 0
~ DATA ;AVED TO Fi I N ti 1 1 ~ t

### APPENDIX 3 Field Data Field Equipment Calibrations

PLOTHRID\HGA99\60823-3.DOC 7"i ~

nat,nc x. ur nvn INc

# --,
~ 

# ..:

~

~ 

# .I

,. ~ 

# ? -=_ DAVIS & FLOYD, INC.

Environmental Services Division ~ 

### ~ 

## . EPA METHOD 5 ~0~ Preliminary Data 

### 816 E. Durst St. Greenwood, South Carolina 29649

(864) 229-5211 CLIENT: PALMETTO BRICK PROJECT NUMBER:60823.00 CITY, STATE: CHERAW, SC CONTACT:KEVIN MACKEY UNIT TESTED: DRY LIME SCRUBBER DATE:3-4-99 RUN NO.: OPERATORS:BROOMENVILSON DIAMETER OF CIRCULAR STACK (in.): 60 ; METER BOX N0.:3 DIMENSIONS OF RECT. STACK (in.): METER )H@: NO. OF )P READINGS:a► 12 IMPINGER BOX NO.: ~ Cp FACTOR:.84 FILTER HOLDER NO.: ~ 1 STATIC PRESSURE (in. H20):-.14 FILTER NO.: ~ L L L jE ~ /_ 9 BAROMETRIC PRESSURE (in. Hg): NOZZLE DIAMETER (in.): . 3 (g y RUN TIME (min.): 60 /

- i6c
~ (i NOZZLE NO.: 4;cu re: - a ~ Post:

~ ~

ft ~ WET BULB / DRY BULB TEMPS (°F): GLASS THERMOMETER TEMP (oF): ASSUMED MOISTURE (%): 10 THERMOCOUPLE READOUT (oF): Pre. - 

### ost: INITIAL IMPINGER VOLUME (ml): 2 , 86 - !,¢Ao PITOT LEAK CHECK: Pre r /Post FINAL IMPINGER VOLUME (ml): 4 70 PROCESS RATE: INITIAL SILICA GEL VOLUME (g): 200 STEAM PRODUCTION: FINAL SILICA GEL VOLUME (g): _ :3 02(%): HEATER BOX SETTING (°F): 250 CO z (%): PROBE HEATER SETTING (°F): 250 CO (ppm): PROBE LENGTH (ft): s DRY MOLECULAR WEIGHT (Ib/Ib mole): PROBE NO.: /_ p/tce-1 „: METER BOX Y FACTOR: PROBE LINER MATERIAL: GLASS DRY GAS METER VOLUME (ft3): 

## 3$

Ar4 ,. 

### n Kce OBSERVER: SCDHEC DRY GAS METER VOLUME x Y( 

### ft 3): ~ j ~ '3 

### 3 . 3 Stack & Process Flow 

# I J

A 

# .i ?D~ l 

### DAVIS & FLOYD 

## , INC.

Environmental Division 

## EPA METHOD 5 Field Data 

### 816 E. Durst St. Greenwood, South Carolina 29649

(864) 229-5211 CLIENT: PALMETTO BRICK UNIT TESTED:DRY LIME SCRUB TEST NUMBER:
SAMPLE POINT # CLOCK

TIME SAMPLE

TIME DRY GAS

METER ft 3 )P

(in. H20) )H

(in. H20) STACK

TEMP oF DRY GAS TEMP oF

INLET OUTLET PUMP VACUUM (in. Hg) FILTER

TEMP oF IMPINGER

TEMP oF

n PORT-

~ 

### t ' ociokA 

# ° 7 93.3q5 ,Lij .,2. 3v3 y '- ~~ 

### 2 S 4 Z
2 5 

### o~ 

## 141 43 2sti yZ 3 10 ~DO~ 1 3 3 0 q 2 '7Z 4 15 

### 1.10 5011, 

## s z q 

### 3.S LI0 5 20 

### I. 6 ov 41S 6 25 p ~ l• ~ Z•1 1'1 1 4 3 q ~ 30

PORT



## , 

# ° ."
~ 

## o I,$a 363 qq 4 Z,S 7 S' 2 5 ~~~ ~ •~ 7 0! '1 Z 3 10 ~ d ` 

## /7 a 15 ,`6 .titi ' 0 1 3.r L(. 

### f 47 5 20 0 3• 7,1.0 '1 ~ 6 25 Zy — ( '1
30 ~~~.• ~ tD l

~
~

INITIAL LEAK RATE: ~ ~~ CFM (81 ~ D in. Hg FINAL LEAK RATE: CFM (81 L in. Hg i COMMENTS: PAGE OF ~ ~ 

# ~

~ 

# n

I 

# 3_.~

;

; 

### DAVIS & FLOYD 

## , INC. Environmental Services Division 

# e~ EPA METHOD 5
a ``\ ~ Prelimina 

### ry Data

~ j l 

### 816 E. Durst St. Greenwood, South Carolina 29649

(864) 229-5211 CLIENT: PALMETTO BRICK PROJECT NUMBER:60823.00 CITY, STATE: CHERAW, SC CONTACT:KEVIN MACKEY UNIT TESTED: DRY LIME SCRUBBER DATE:3-4-99 RUN NO.: a OPERATORS:BROOMENVILSON DIAMETER OF CIRCULAR STACK (in.): 60 METER BOX N0.:3 DIMENSIONS OF RECT. STACK (in.): METER )H@: ; ~ , j` & NO. OF )P READINGS:(f la'C IMPINGER BOX NO.: D Cp FACTOR:.84 FILTER HOLDER NO.: /(/ ~ STATIC PRESSURE (in. H20):-.14 FILTER NO.: ,4LL

— ~~ Z_ Q p BAROMETRIC PRESSURE (in. Hg): NOZZLE DIAMETER (in.): . 30 RUN TIME (min.): 60 NOZZLE NO.: s re: L-- - WET BULB / DRY BULB TEMPS (°F): I GLASS THERMOMETER TEMP (oF): f. ASSUMED MOISTURE (%): 10 THERMOCOUPLE READOUT (oF): Pre:L- - Post:_ INITIAL IMPINGER VOLUME (ml): 290 4.80 PITOT LEAK CHECK: Pre ' ---- Post FINAL IMPINGER VOLUME (ml): 445 PROCESS RATE: INITIAL SILICA GEL VOLUME (g): 200 STEAM PRODUCTION: FINAL SILICA GEL VOLUME (g): 9, 7 O Z (%): HEATER BOX SETTING (°F): 250 CO Z (%): PROBE HEATER SETTING (°F): 250 CO (ppm): PROBE LENGTH (ft): s' DRY MOLECULAR WEIGHT (Ib/Ib mole): PROBE NO.: METER BOX Y FACTOR: PROBE LINER MATERIAL: GLASS DRY GAS METER VOLUME (ft3): 

# 39. qsl OBSERVER: ' ~ SCDHEC DRY GAS METER VOLUME x Y(ft3): Q, LI'7

~ 

### Stack & Process Flow Diagram

~ 

### 2,.; :t :z 

### DAVIS & FLOYD 

## , INC.

Environmental Division 

## EPA METHOD 5
,~~~~ Field Data ~y~ 

### 816 E. Durst St. Greenwood, South Carolina 29649

(864) 229-5211 CLIENT: PALMETTO BRICK UNIT TESTED:DRY LIME SCRUB TEST NUMBER: a
SAMPLE POINT # CLOCK

TIME SAMPLE

TIME DRY GAS

METER f1 3 )P

(in. HZo) )H

(in. HZO) STACK

TEMP oF DRY GAS TEMP oF

INLET OUTLET PUMP VACUUM (in. Hg) FILTER

TEMP oF IMPINGER

TEMP oF PORT- 

## ' 1oZI 1 

## ° 2 5 4%. 7 2 7 3 10 Vk•tk 30 ~ 

## s's - sl 2-54 - 42
4 15 2'(90 ~ 8 S 20 4 (0 Z Z ..Y 0 S 2W 1 0 6 25



### 30 85 r. so 3

PORT-



# , ° 2 5 ' G/ 3 10 l f ~1 190 S ~ Z~O~ ~~ 4 15

~ vGl. ~ ~ ~•~ V oir (A.0 s ' 3 2(rZ If 5 — s 20 goto 

### bo z( o o ~ 

### Cr 6 25 %U`6.`i 1•W o(t (20 S - ~ 2579 ~ 9 Z.~ 30

INITIAL LE4K RATE: CFM (81 S in. Hg FINAL LEAK RATE:
~ 0 Q CFM @ in. Hg COMMENTS: PAGE OF 3

### DAVIS & FLOYD 

## , INC.

Environmental Services Division 

## 6 EPA METHOD 5

~ Preliminary Data h ~ ~,~~`~1 

### 816 E. Durst St. Greenwood, South Carolina 29649

(864) 229-5211 CLIENT: PALMETTO BRICK PROJECT NUMBER:60823.00 CITY, STATE: CHERAW, SC CONTACT:KEVIN MACKEY UNIT TESTED: DRY LIME SCRUBBER DATE:3-4-99 RUN NO.: 3 OPERATORS:BROOME/WILSON DIAMETER OF CIRCULAR STACK (in.): 60 METER BOX N0.:3 DIMENSIONS OF RECT. STACK (in.): METER )H@: NO. OF )P READINGS:M 12. IMPINGER BOX NO.: Cp FACTOR:.84 FILTER HOLDER NO.: ^/ STATIC PRESSURE (in. H20):-.14 FILTER NO.: BAROMETRIC PRESSURE (in. Hg): 

### 73 — NOZZLE DIAMETER (in.): 

### .3 a y RUN TIME (min.): 60 NOZZLE NO.: ~ — P/ea ' t Pre: L-- Post:
~ 0 WET BULB / DRY BULB TEMPS (°F): GLASS THERMOMETER TEMP (oF): ASSUMED MOISTURE (%): 10 THERMOCOUPLE READOUT (oF): Pre: --Post:_' INITIAL IMPINGER VOLUME (ml): 28'04-00 PITOT LEAK.CHECK: Pre_ k ~ Post FINAL IMPINGER VOLUME (ml): Q-.g ( PROCESS RATE: INITIAL SILICA GEL VOLUME (g): 200 STEAM PRODUCTION: FINAL SILICA GEL VOLUME (g): 

### I Z• 0 0 2 (%): HEATER BOX SETTING (°F): 250 CO 2 (%): PROBE HEATER SETTING (°F): 250 CO (ppm): PROBE LENGTH (ft): 5" DRY MOLECULAR WEIGHT (Ib/Ib mole): PROBE NO.: %;. ~ ~_ ~ j E c ~ METER BOX Y FACTOR: ), Oa(o PROBE LINER MATERIAL: GLASS DRY GAS METER VOLUME (ft3): 

## 3g. q33

o
~ 

## v OBSERVER: SCDHEC DRY GAS METER VOLUME x Y(ft3): 9 3,-;? Stack & Process Flow Diagram

~

{ , r 3 

### ~~
a

~ ! ~


# I

### DAVIS & FLOYD 

## , IrrC.

Environmental Division 

## EPA METHOD 5 Field Data 

### 816 E. Durst St. Greenwood, South Carolina 29649

(864) 229-5211 CLIENT: PALMETTO BRICK UNIT TESTED:DRY LIME SCRUB TEST NUMBER: 3 SAMPLE POINT # CLOCK

TIME SAMPLE

TIME DRY GAS

METER ft 3 )P

(in. H20) )H

(in. H20) STACK

TEMP oF DRY GAS TEMP oF

INLET OUTLET PUMP VACUUM (in. Hg) FILTER

TEMP OF IMPINGER

TEMP oF / ~ PORT- T1

1 

### 1131 1 ° 11. 8il 30 

## s' s16 ~ ~ 

## fg 2 5 11 „ ~ .~ p , C 361 zS'Z S3 3 10 

### ~ n K. 4 15 Q ~ 2.(' tc.

. J



### 2 ~ 

## I•Sw 3o S 4 / 3• / 

## S Go 6 Z 5 20 ~j V 

### ~~ ,~ ~Z~ ,1 ~ 

## 01 S`6 N S• ~ 

### Lc

. 

## ( SS' 6 25 0 ~1~ \ 

## J) .~ ~Y ~ 0" 

# k ~ Z 

## 5 0 30 ~

Q ~a~~U
PORT1 0 92. 1S4 IoLA 

## >"'-( 2 5

~ ' I (a , O

. ~ 1

. ~ z s 3 10 

### 0% •`6 (to Lsf - 

### 53 4 15 

## CA07•b .2 ~ 

## I•Nti o t¢l Sle 3.5 ~ 2c.v 

## sLf 5 20 Ans1 0 

### .20 1.713 3OQ I u i
~ 

### P L(.

~ 

### ( Z 6 25 1101.1 ~ ~ lY , 1 1 0 1 

## 1 3 Z6 o J-3 

## z 30 

## 9!1). zs' ~

INITIAL LEAK RATE: .003 CFM in. Hg FINAL LEAK RATE: ~ B0~ CFM C s in. Hg COMMENTS: C PAGE OF pS 

# I

~r-I 

### `A DAVIS & FLOYD, INC. 816 E. Durst St. 

## EPA METHOD 1 Greenwood, South Carolina 29649 Environmental Services Division (864) 229-5211

~ CLIENT:PALMETTO BRICK PROJECT NUMBER:60823.00 CITY, STATE:CHERAW, SC CONTACT:KEVIN MACKEY d' UNIT TESTED:DRY LIME SCRUBBER DATE:3-4-99 ' Duct Depth (in.): 60 Stack Area (ft z ) 0.0000 far wall to outside of port

~ Nipple Length (in.): UPSTREAM DOWNSTREAM

~ Depth of Duct (in.): Nearest Flow

~

~ •. Disturbance (ft): I Width of Duct (in.): ;., Equivalent Dia. (in.): Diameters: 3.0 12.4

LOCATION OF TRAVERSE POINTS IN CIRCULAR STACKS LOCATION OF TRAVERSE POINTS IN RECTANGULAR STACKS 4 6 8 10 12 14 16 18 20 22 24 2 3 4 5 6 7 8 9 10 11 12 iz~ 1 6.7 4.4 3.2 2.6 2.1 1.8 1.6 1.4 1.3 1.1 1.1 1 25.0 16.7 12.5 10.0 8.3 7.1 6.3 5.6 5.0 4.5 4.2 25.0 14.6 10.5 8.2 6.7 5.7 4.9 4.4 3.9 3.5 3.2 2 75.0 50.0 37.5 30.0 25.0 21.4 18.8 16.7 15.0 13.6 12.5 3 75.0 29.6 19.4 14.4 11.8 9.9 8.5 7.5 6.7 6.0 5.5 3 83.3 62.5 50.0 41.7 35.7 31.3 27.6 25.0 22.7 20.8 93.3 70.4 32.3 22.6 17.7 14.6 12.5 10.9 9.7 8.7 7.9 4 87.5 70.0 58.3 50.0 43.6 36.9 35.0 31.8 29.2.. , t 85.4 67.7 34.2 25.0 20.1 16.9 14.6 12.9 11.6 10.5 5 90.0 75.0 64.3 56.3 50.0 45.0 40.9 37.5 ~ 95.6 80.6 65.8 35.6 26.9 22.0 18.8 16.5 14.6 13.2 6 91.7 78.6 68.8 61.1 55.0 50.0 45.8 7 89.5 77.4 64.4 36.6 28.3 23.6 20.4 18.0 16.1 7 92.9 81.3 72.2 65.0 59.1 54.2 8 96.8 85.4 75.0 63.4 37.5 29.6 25.0 21.8 19.4 8 93.6 83.3 75.0 68.2 62.5 82.3 73.1 62.5 38.2 30.6 26.2 23.0 9 94.4 85.0 77.3 70.8 0 

# IT1 91.8 97.4 88.2 79.9 71.7 61.8 36.6 31.5 27.2 10 95.0 86.4 79.2 93.3 85.4 78.0 70.4 61.2 39.3 32.3 11 95.5 87.5 12 97.9 90.1 83.1 76.4 69.4 60.7 39.8 12 95.8 ti 3 94.3 87.5 81.2 75.0 68.5 60.2 4 98.2 91.5 85.4 79.6 73.6 67.7 5 95.1 89:1 83.5 78.2 72.6 16 98.4 92.5 87.1 82.0 77.0

. 

### ^~ 7 95.6 90.3 85.4 80.6 8 98.6 93.3 88.4 83.9 a ~ 9 96.1 91.3 86.8 20 98.7 94.0 89.5 r 1 96.5 92.1 2 98.9 94.5 3 96.8 24 98.9 Point % of Stack Diameter Stack Diameter Distance from Inside Wall Nipple Length Distance from End of Port 1 4.4 36 2.64 2 14.6 8.76 3 29.6 17.76 4 70.4 42.24 5 85.4 51.24 6 95.6 57.36

~d ~--, i



# ~ DAVIS & FLOYD 

# , Irrc.

Environmental Services Division 

# EPA METHOD 1 Cyclonic Flow Test 

### 816 E. Durst St. Greenwood, South Carolina 29649

864 ) 229-5211 CLIENT:PALMETTO BRICK CO. UNIT TESTED:DRY LIME SCRUBBE DATE:3-4-99

PORT TRAVERSE POINT # )P @ 90° ROTATION ANGLE (N) FOR NULL )P 

### A 1 NEG 7 2 

### IJEG 5 3 0 0 4 0 0 5 0 0 6 .03 11



### B 1 NEG 4 2 NEG 5 3 0 0 4 0 0 5 .02 8 6 .07 12

AVERAGE = 4.33 Comments: O:DATA\WORD\STCKTEST\CYCLONIC .DOC 

## S7 r~

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### ~-,+

, 

## 3• 

## ~ DAVIS &. FLOYD, 1NC. Environmental Services Division 

## EPA METHOD 3 816 E. Durst St. Greenwood; South Carolina 29649

(864) 229-5211 CLIENT: PQtMc-WO Gk c, PROJECT NUMBER: 

### tg ~ 

### 3 , Od CITY, STATE: r 

### ~~ S( - CONTACT: Ke_v l " \ ac-lQ UNIT TESTED:" 

### ~ r L;,,,, 

### ~ S~,~(~e~ DATE: 3, y, SAMPLE TYPE: 66te rate / grab FUEL TYPE: r_ S ANALYST: 54 ANALYZER TYPE: O, T

_a\A T nc CO, CF-kc."to , CO M-x S OXYGEN CALIBRATIONS RUN #1 RUN #2 RUN #3
: HIGH ° L01N ' r •HIGH:, ": : LOW ' : ':: ; HIGH LOW 

### Calibration Gas Value

~ 

### (%)

- ~ 

### 0. 9 7.2 1 

### 2 0 .7 7• Z Zo. 9 7.2 An. alyzer Readin9 (%)

~ 

### D ,
~ 

### j 7, Z ,?o. 9 7. 2- 26.19 7. 2- CARBON DIOXIDE CALIBRATIONS 'RUN #3'

~ r ~ 

### HIGH ; ~ ~ ✓ 

### LOW. HIGH ' j LOW HIGH :: LOW Calibration.Gas Value,(%) Calc. Calc. Calc. Calc. Calc. Calc. rialyzer Readin 

## Ag ` (%). Calc. Calc. Calc. Calc. Calc. Calc. GAKt3UN MUNUXIUt GALItiKAI IUN5 

### ; :: RUN=#1 ~ ~ ~ 

### , `„RUN #2 , , RUN #3 :. HIGH ` LOW t HIGH LOW ', HIGH LOW Ca. Gas Value (ppm) S ~ 

### 0

_ ..: 

## Analyzer Read'iii9 (pPm) y 9. 

## D y q. (

~ 

## b q q. - 7 p TEST RESULTS

DRY MOLECULAR WEIGHT CALCULATIONS



## ~ RUN #1: 02 x 0.32 + CO2 x 0.44 + N2 x 0.28 = Ib/Ib dry mole RUN #2: 02 x 0.32 + CO2 x 0.44 + N2 x 0.28 = Ib/Ib dry mole RUN #3: 02 x 0.32 + CO2 x 0.44 + N2 x 0.28 = Ib/Ib dry mole 

## NOTE: CO2 Calc. By Equation: COz= 20.9 - Oz 

### E Fo 

## ~ Where: Oz =% oxygen measured by analyzer

Fo = Mid range value for type of fuel (coal Bit. 1.157, wood 1.060, wood bark 1.066, oif distillate 1.337, oil residual 1.290) 51g COs = Calculated % carbon dioxidei 

# ~

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## i J



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### TEST EQUIPMENT CALIBRATION CALCULATIONS

Where: K' = Critical orifice coefficient

, K, = Constant 17.64, °RIin.Hg

- ~ 

### T, mb = Absolute ambient temperature, °R V. = Volume of gas sample as measured by dry gas meter, dscf ~ 

### V. ( ,, o = Volume of gas sampled passed through the critical orifice,

corrected to standard conditions, dscf Y = Dry gas meter calibration factor Pbw = Barometric pressure, in, Hg OH = Average pressure differential across the dry gas meter

orifice, in. H Z O T. = Absolute average dry gas meter temperature, °R 0 = Time, min. I. Calibration of Critical Orifices

K, V. Y(P b . + DH/13.6) 4T,,,, b 

## K 

# , _ P b .,T m O The individual K' values should not differ by more than t 0.5 percent from the average. The calibration of the critical orifice with a dry gas meter assumes that the dry gas meter has been calibrated with a wet test meter or an altemative primary standard.
II. Using the Critical Orifices as Calibration Standards
P b ,., + (DH/13.6) Vm(.td) = K, V. 

## T



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## K'
` ` amb


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# --__-= P.

Deprr,e Indicatinp lMwl posltbn lor datentininp ai and ai.

1

Deprr,rr Indidtinp bvrrl position for de tbrm ininp (E). 

# ~ ~ ~ ..,t CALIBRATION DATA SHEET Type S Pitot Tube Inspection Level and Perpendicular) ✓ Obstruction) DamaOed ) a t (-10 0 5 a t

5+ 10 0 ) 0 2 (-10 0 S 0 2

S+ 10 0 ) a l (-5 0 s B I s+5°) J 7 6 2 1-5 0 s B Z s+5°l © Y d 6 d z - A tan y(5 0.125') C ~ w - A tan 6( 5 0.03125'1 ~ D t (3/16' 5 D, s 3/8') 

### A U/ Al2D 0.05 5 P/D s 1.5) ,-SS 

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Dt — I—z

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# fr

Deprrre indka0np lravol postlion for delemininp7lhen calculate Z.

QA/QC Check ~ ~ Completeness

V / Lepibility , ~ Accuracy Specifications ` - `
—

Reasonableness ~ ` Cert/l7catfon 1 certify that the Type S pitot tube/probe 10a/ -~7~ meets or exceeds all specifications, criteria and/or applicable desip f res r hereby assipned a pitot tube calibration factor C. of 0.84. Certified by: ~ Per nnel (Sipnature/Date) Team Leader (Sionature/Date)

KCALIBRATION DATA SHEET Type S Pitot Tube Inspection Level and Perpendicular) ✓ ObstructionT Damaped ) 0 1 (-10 0 S a t

s+ 10 0 ) Z

a Z (-10 0 s 0

2 5+ 100) 6 1 (-5 0 s B t

s+5 0 ) Z 9 2 (-5 0 5 1&2 s+5°) L r b
e 0 z = A tan r( s 0.125') ® w- A tan 611 5 0.03125') D r (3/16' s D r s 3/8') ~ Z A A/2D 0.05 s P/D s 1.5) ,Z ~.~ 

# I

— `

a ~ Drrpree Ind

~ callnp levwl postlion ro d.t+rT'tinlnp C[i .nd otL

Doprrrs Indicatinp IMwI posltbn lor determin:, o pr.nd az.



### l

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# I delermininp19. 

# ~ ~ 

# AL EA

~ Dt -- I—Z



# I
~ A 7I aaeee
~ 

# !

Dapns indlcatinp sMvol posltion ror detemininp7then calculate Z.

DA/QC Cbeck 

## ' / ' / Completeness L/ Lepibility `~ Accuracy

. Specifications Reasonableness Cert/ricition I certify that the Type S pitot tube/probe 101 S f
- ryl

~ ~~~ meets or exceeds all specifications, criteria and/or applicable desipn eat res reby assiqned a pitot tube calibration factor C o of 0.84. Certified by: Pers el (Sipnature/Date) e Team Leader (Sipnature/Date) 

# € 

# I

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### _ .

— =r 

# ~ tlt7
Dspree Indicatinp bvrrl posltlon lo delonnlnYny O:r and oti 

# I

CALIBRATION DATA SHEET Type S Pitot Tube Inspection



# ~ ~ I

, i Depree bndicatinp lsvel posttlon lor dslrrrm7ninp pa snd aa.

l 

# "~ 

# -J Deyrno indlcstlnp Ievsl position /or de lermininp E). Level and Perpendicularl ✓ Obstructionl Damapedl
o t (-10 0 S o l S+ 10 0 ) ~ pZ (-100 S 0 2 S+ 10 ° ) Q t (-5° s B t

s+5°) ~ 13 2 (-5° 5 6 1 s+5°1 D r ~ 

## e l

z A tan r(5 0.125') 0
w A tan 6( 5 0.03125') ,C2 Z D l (3/16' S D l

5 3/8'1 ,3 7 Z. 

### A q V/ Al2D (1.05 s P/D s 1.5) ,2

~ D l z

--- f — I 

# i

Depres indlotinp 14v , *I posltion (or detemininprlhen cafcutate Z.



### ~

QNQC Check ~ ~ 

### ' /

Completeness [ ~ Leflibility L/ Aceuracy Csrtl/icitbn 

### / 1 certify that the Type S pitot tube/probe IDat ~~~• criteria and/or applicable desipn eat s a reby as: Certified by: Per nel (Sipnature./pate) .. ~ ` ~ Specifications Reasonableness _

~~ meets or exceeds all specifications, ;iqned a pitot tube calibration factor C p of 0.84. 

### 'e' a - ~ -.T_

~ Team Leader (Sipnature/Datel



# q3

### DAVIS & FLOYD, INC. 816 E. Durst St. 

## Field Nozzle Calibration Greenwood, South Carolina 29649 Environmental Services Division (864) 229-521 1
CLIENT: t 

### PROJECT NUMBER: CITY, STATE: C w DATE: ~ 

### _ _? NOZZLE MATERIAL: &-51- ~ 

### CALIBRATOR: ~ 

### Nozzle D1 D2 D3 D4 D5 D(b) D(c) Identification (in.) (in.) (in.) (in.) (in.) (in) Avg Number Test Number 1 6 PiE - C'kF ' 5 (D • . - 3 0<r

### Test Number 2 /

- • 3 © ~ ~ 

### C9 . ~ 

### B 

### est Number 3 

### iprer'e) - 30

Where: 

### (a)D1,2,3,4,5 = Pive different nozzle diameters (in). Each diameter must be within 0.001 in. (b)D = Maximum difference between any two diameters (in). D 50.004 in. 

### (c)D = Average of D 1, D2, D3, D4, and D5. . 1


# ~
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### ~

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# q4

# ~ ., ; • a • ' r
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# ~

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### 9.

..~ Meter Box #: 3 

# ~ Date: 12-28-98 

# ~

. Calibrator: WSB DAVIS 8 FLOYD, INC. Environmental Senrices Division 816 E. Durst St. Greenwood, South Carolina 29649

EPA METHOD 5 Meter Box Calibration Pre-Test Orifice Method Barometric Pressure: 29.53 Critical Vacuum: 13.93
Volume Initial Temps Final Temps Actual Ambient dH Time Initial Final Total Inlet Outlet Inlet Outlet Orifice K Vacuum Temp in. H20 min cu.ft cu.ft cu.ft deg F deg F deg F deg F Serial No. Factor in. H d F 0.66 12.00 148.542 153.548 5.006 73.0 71.0 74.0 73.0 DH-48 0.329 220 75.0 1.15 10.00 143.086 148.542 5.456 72.0 70.0 73.0 71.0 DH-55 0.4328 20.5 75.0 2.05 7.00 153.548 158.561 5.013 74.0 73.0 75.0 73.0 DH-63 0.5656 19.0 75.0 3.85 6.00 132.247 138.103 5.856 69.0 68.0 71.0 69.0 DH-73 07768 16.5 75.0 6.00 5.00 126.208 132.247 6.039 1 68.0 68.0 69.0 68.0 DH-81 0.9646 14.5 75.0 """' RESULTS ****" DRY GAS METER ORIFICE DRY GAS METER ORIFICE Corrected Nominal Calibration Factor Calibration Factor Corrected Volumes Volume Volume Y dH@ Vm(std) Vm(std) Vcr(std) Vcr(std) Vcr Value Variation Value Value Variation cu.ft liters cu.ft liters cu.ft number number in.H2O mm H20 in.H2O 4.903 138.8 5.040 142.7 5.177 1.028 0.003 2.033 51.63 -0.085 5.363 151.8 5.526 156.5 5.675 1.030 0.005 2.068 52.53 -0.050 4.917 139.2 5.055 143.1 5.191 1.028 0.002 2.149 54.57 0.031 5.819 164.8 5.950 168.5 6.111 1.023 -0.003 2.157 54.80 0.040 6.044 171.1 6.157 174.4 6.324 1 1 1.019 -0.007 1 1 2.183 55.44 0.065 

# ~ AVERAGE Y = 1.026 Note: The acceptable variance for the individual values of thre calibration factor Y is + or - 0.02 from the average. 

# ~ The acceptable variance for the individual values of dH@, the orifice

differential pressure in inches of H20 that equates to 0.75 cfm of air 

# ~ at 68 F and 29.92 in. Hg, is + or - 0.2 from the average



# ~ SIGNED: /// ~ //~ • *4 . -z 2.118 = AVERAGE dH

q 6.DAVIS & FLOYD, INC. Environmental Services Division 816 E D 

## s t St 

## ~ ur Greenwood, South Carolina 29649

EPA METHOD 5 r 

# ~ Meter Box Calibration Post-Test Orifice Method Meter Box M 3 Date: 03-05-1999 Calibrator: MBW Barometric Pressure: 29.14 Critical Vacuum: 13.75
Volume Initial Temps Final Temps Actual Ambient dH Time Initial Final Total Inlet Outlet Inlet Outlet Orifice K Vacuum Temp in. H20 min cu.ft cu.ft cu.ft dog F deg F deg F deg F Serial No. Factor in. H d F 1.20 10.00 514.996 520.368 5.372 69.0 69.0 70.0 70.0 55 0.4328 21.0 73.0 2.00 7.00 520.368 525.368 5.000 70.0 70.0 71.0 70.0 63 0.5656 19.0 73.0 3.80 6.00 525.368 531.145 5.777 71.0 70.0 73.0 71.0 73 0.7768 16.5 73.0

MRRM RESULTS DRY GAS METER ORIFICE DRY GAS METER ORIFICE Con - ected Nominal Calibration Factor Calibration Factor Con
- ected Volumes Volume Volume Y dH@ Vm(std) Vm(std) Vcr(std) Vcr(std) Vcr Value Variation Value Value Variation cu.ft liters cu.ft liters (cu.ft) (number number in.1-12O mm H20 in.H2O 5.231 148.1 5.463 154.7 5.664 1.044 0.007 2.183 55.45 0.032 4.872 137.9 4.997 141.5 5.182 1.026 -0.012 2.128 54.06 -0.023 5.643 159.8 5.883 166.6 6.100 1.042 0.005 2.142 54.40 -0.009 

## ~ AVERAGE Y = 1.038 Note: The acceptable variance for the individual values of the calibration factor Y is + or - 0.02 from the average.


## ~ The acceptable variance for the individual values of dHo, the orifice 

## ~ differential pressure in inches of H20 that equates to 0.75 cfm of air

at 68 F and 29.92 in. Hg, is + or - 0.2 from the averrage



## ~ μ~ SIGNED: -



## ~ 2.151 = AVERAGE dH



### q ~ 

### pDAVIS & FLOYD, INC. POST TEST CALIBRATIONS 816 E. Durst St. BAROMETER,THERMOCOUPLES Greenwood, South Carolina 29649 Environmental Services BALANCE CALIBRATION (864) 229-5211 CLIENT: ~ L DATE: a ^ : 5
— •_ ( ~ CHECKED BY:: 

### BAROMETER REFERENCE BAROMETER (M) F-M +/- 0.1 in.Hg (MERCURY IN GLASS) FIELD BAROMETER (F) TO MEET CRITERION 7 ~ • 

### THERMOCOUPLES REFERENCE TEMPERATURE SET POINT METER BOX _ 

# ~ !; THERMOCOUPLE READING +/- 2 DEGREES F TO MEET CRITERION


### REFERENCE THERMOCOUPLE CALIBRATOR ALTEK-NIST CERTIFIED SERIAL No.22-K-2100F Set Points Zero 

## ~ Avg. Stack Temp Degrees F Avg. Stack Temp. + 50 Degrees F 

# ~ ~ ✓ Avg. Stack Temp. — 50 Degrees F ANALYTICAL BALANCE CALIBRATION 

# L .~ Balance name: Sartorius SERIAL No.:5052299 Classification Of Standard weights: Type S

0.5000 G 1.O00OG 10.00OOG 50.00OOG 100.0000 G Analyst 

### DATE

~ 

### — ~ 

### 0 0- 000 o 

### /O 0• Gc 70 0 c~

ri



### ~ ..J



### ~

n~ . Y



# q1x 

# wil NLN 

## CA' 1 6"T16H

, LABORATORY

v / in Tolerance 3c OLd of Tolerance 

## Calibration Data

End of Datasheet 

## Calibration Standards V 

### NIST Traceable # Instniment ID# Description Model Calibration Date Date Due
1000007183 01-0044 Calibrator 5500A-WISC300 05 JAN IM 05 JAN 2000



### Davis Instruments • 4701 Mount Hope Drive • Baltimore, Maryland 21215 • Phone: 410.358.3900 • Fax: 410.358.0252~s 

## ~ .~


## ..~ 

# A. cauanAnoN IVAIM

~~ 

# AiN. 

# u► 

# eoenmmr Instrument Identification

~ ~ ~ 

### Davis & F(oyd Incorp. PO# : 980507 220638 Ref# : 289668 Instrument Id: 8397 SO#: 4933 Noun: Thermocouple Calibrator Model: 22-K2100F Mfr: Altek Serial #: 243976 Accuracy: :l; 3°F ( below 32°F)

t0.1%ofRdgt1°F(restofrange)

-~


### ~ f'ertificatinn Tnfnrmatinn


### ~ Reason.For Service: Calibration


### ~ Type Of Calibration: Normal As Found Condition: In Tolerance


### ~ As Left Condition: Left As Found 

### ~ Procedure: 33K5-4-15-1 :

Remarks: Thermocouple Simulator Calibrator Technician: Jozef Sedlacek Cal Date: 08 FEB 99 Cal Due: 08 FEB 00 Temperature: 23.0 °C Humidity: ' 28.0 %

' a l The instrument(s) listed on this certification have been ealibrated against standards traceable to the National Institute oJStandards and

Technology (NIST), derived jrom ratio rype measurements. or compared to nationally or internatlonally recognized coirsensus standards. 

# ~ A calibration uncertalnty rutio oj4:1 was maintained unless otherwise stated.

~ Davis Instruments quality system complies wlth appGcable requirements ojANSI/NCSL Z540-1-1994 and ISO 9002:1994(E)
7 All results contained within this certification relate only to item(s) calibrated. Tbls certificate shall not be reproduced except in jull 

### ~ and with the ivritten consent ojDavts Instruments.

~ a.pproved By: 

# ~
~

. v / In Toleranoe 

### ic out of Toaeranoe Calibration Data : Range Nominal As Found

.. 

### As Left Min 'Max 

# _, F 

# ,_. a _ , ~ . '-, ~ ~ ,
- '~ Q ..;• , 

### : -( ~ { r. • ~ . +'^t. i

T~ 

## et
~ 

## perature ~~ +

. , .... '

- - 0.0 -0.6 ✓ As found -3.0 3.0 100.0 100.0 ✓ Asfound 98.9 101.1 200.0 201.1 ✓ As found 198.8 201.2 300.0 300.1 ✓ Asfound 298.7 301-3 400.0 398.8 ✓ As found 398.6 401.4 500.0 500.0 ✓ As found 498.5 • 501.5 600.0 601.2 ✓ As found 598.4 601.6 700.0 700.1 ✓ As found 698.3 701.7 800.0 801.6 ✓ As found 798.2 801.8 900.0 900.1 ✓ As found 898.1 901.9 Davis Instruments • 4701 Mount Hope Drive • Balumore, Maryland 21215 • Phone: 410.358.3900 • Fax: 410.358.0252 ql

### CERTIFICATE OF CALIBRATION

This is to certify that your Altek Unit has been calibrated using standards whose accuracies are traceable to the National lnstitute of Standards and Technology within the limits of the NIST Calibration Services. Actual records pertaining to these standards are on file and are available for examination. CertiTied by: Altek Industries Corp. Recommended Recalibration: Annually Model Number 

# Z F Factory Calibration Date 2-1 

# —\Q h O t 1 Calibration Due Calibration Technician -, ~ Setial Number I 

# ~I~ ) IIIII 

# ~ I 

# ~ III IIII 

# ~ II In Sernce Date

243976 ,F CONFOR1v>ITt 

# ~ 

# E ` ` . _ The above signatute for Altek Industries Corp., 210 Commeroe Drive, Rnchestet; NY 14623 USA Declares that the equipment specified complies with standatds EN50081-1 and EN50082-1. The product complies with the cssential requiremenu of the EMC Directive 89/3361EEC Drawing # 1-937 REV:A •i

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# j Lahoratory Inxtnimcnt Scrvicc •-t(13 Campbcll Avcnuc • Landrum SC 29356 • (864)457-4878



## Report of Balance Calibration

~ Customer: Date: j( o Mg~~ qg 

### Due: 

## neex On Uaiiiufacttuer Model Serial Location I Capacity 11,, I Resolution nI ,,,, e I H44 I Off- Center test Front Back Left Right Reading — p r6 0.Gb Zo . o 9 

### Zero return 13 1

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# ~ Comment n tolerance as found YES NO In tolerance as left YES NO

l 

### ialuation


# ~ NIST Traceability numbers 1= SC8802181 m 2= SC9104191 m 3= SC9009241 m

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### 1 111#2600 Bull Street Columbia, SC 29201-1708 COMMISSIONER: Douglas E. Bryant 

### April 30, 1999 BOARD: John H. Burriss Chairman William M. Hull, Jr., MD Vice Chairman 

### Palmetto Brick Company Roger Leaks 

### , Jr. P.O. Box 430 Secretary 

### Cheraw, South Carolina 29520 Mark B. Kent 

### Attention: Mr. Henry Moore, VP Mfg. Cyndi C. Mosteller Brian K. Smith Rodney L. Grandy



### Dear Mr. Moore, Enclosed is a r.v's .d 

### summary of the results of the source tests at the indicated facility. This sllmmary includes the emission rates and operating parameters of the source(s) tested. Please review the corrections made in the Visibles (Method 9) section and note that these changes have not affected the compliance status of the source(s) tested. Note: Following the review of the analytical data submitted to the Bureau, I found that Clayton Laboratory Services did not meet all the EPA Reference Method 26A requirements. The following method parameters were lacking in the final report: Sec ion 5.2, C'alibratiori- 

### Inject the appropriate series of calibration standards ... both before and after the injection of the QC check sample, reagent blanks, and field samples. This allows cornpensation for any instrument drift occurring during sample analysis. 2. Section 4.3.3.2: 

### Betweera injections of the appropriate series of calibration standards, inject in duplicate the reagent blanks and field samples. The Bureau evaluates test results on a case by case basis. Considering the concentrations of Hydrogen Fluoride were low and finding that Clayton Laboratory Services had demonstrated good laboratory and matrix spike recoveries, this Bureau will accept the Hydrogen Fluoride resuAts. However, in the future, failure to follow all method requirements may be grounds for the rejection of all final results.

1o~r



### Mr. Henry 1Vloor.e April 30, 1999 Page Two
Please review this data and if I can be of further assistance in these matters please call me at (803) 898-4303. 

## Sincerely, 

## 04XY,A 

# V Anthony V. eeler Environmental Chemist Division of Air Compliance Management Bureau of Air Quality cc: Jerry Chalmers Annie Richardson Shawna Riddle Joseph Eller Don Smith, Pee Dee District Main File

~ 

# 1 pS

### Palmetto Brick Con

- ipany Permit No. 0660-0021 Lingl # 1&# 2 Id. No CA Cheraw, South Carolina Results - Tests of March 4, 1999 Hvdrogen Fluoride (Method 26A) 

### Test Production Capacityl Emissions Allowable # 

### tons/hour % 

### mg/m3 Lbs/hr Lbs/hr 

### 1 22.71 96.2 2.20 0.228 1.80 

### 2 22.71 96.2 2.00 0.207 1.80 

### 3 22.71 96.2 2.40 0.237 1.80 

### Avg. 22.71 96.2 2.20 0.224 1.80 

### 1. Based on a process rate of 23.6 tons per hour of brick produced. Visibles (Method 9) Allowable 

### Test # 3 % Minutes of Observation 30 6 minute sets greater than std. 0 20 

### Average Opacity - % 1 Set Max/min opacity - % 4/0 Operational Notes: 

### 1. Lingl # 1 temperatures ranged from 1982 F to 2021 F and averaged 2000 F during the tests. 2. Lingl #2 temperatures ranged from 2040 F to 2050 F and averaged 2046 F during the tests. 3. Fuel consumption consisted of natural gas; and No. 2 Fuel oil for flashing purposes. 4. Dry Lime Sorption Scrubber minimum cvcle time was set at 8 minutes during the tests. 5. Dry Lime Sorption Scrubber photohelic readings ranged from 1.0 to 1.7 inches of water and averaged 13 inches of water during the tests. 6. Dry Lime Sorption Scrubber fan Hertz ranged from 30.3 to 41.8 Hz and averaged 36.9 Hz during the tests. Status as Tested: 

### S.C. DHEC- BAQ Permit No. 0660-0021-CA (Modeled Emission Rate for HF)........Compliance 

### S.C. DHEC- BAQ Permit No. 0660-0021-CA (Visibles) ...................................Compliance



### cc: Jerry Chalmers Aruiie Richardson Shawna Riddle Joseph Eller Don Smith, Pee Dee District Main File Report Received: 03/26/99 Review Complete: 04/30/99 Reviewer: Anthon

'/ 

### y U. Keeler 

# dK

I p lo, 

# ==•. 

# 1 ~ 

# - ! ~ = _

PROMOTE PROTECT PROSPER 2600 Bull Street Columbia, SC 29201-1708 COMMISSIONER: Douglas E. Bryant BOARD: John H. Burriss Chairman William M. Hull, Jr., MD Vice Chairman Roger Leaks, Jr. Secretary Mark B. Kent Cyndi C. Mosteller Brian K. Smith Rodney L. Grandy 

### Apri122, 1999

Palmetto Brick Company P.O. Box 430 Cheraw, South Carolina 29520 

# ~
~~i ✓ ~ ~~ J


### Attention: Mr. Henry Moore, VP Mfg.

Dear Mr. Moore, A summary of the results of the source tests at the indicated facility is enclosed. This summary includes the emission rates and operating parameters of the source(s) tested. LY41e; Following the review of the analytical data submitted to the Bureau, I found that Clayton Laboratory Services did not meet all the EPA Reference Method 26A requirements. The following method parameters were lacking in the final report: 1. Section 5.2,5_'alibration: 

### Inject the appropriate series of calibration standards ... both before and after the injection of the QC check sample, reagent blanks, and field samples. This allows compensation for any instrument drift occurring during sample analysis. 2. S.ection 4.3.3.2: 

### Between injections of the appropriate series of calibration standards, inject in duplicate the reagent blanks and field samples. The Bureau evaluates test results on a case by case basis. Considering the concentrations of Hydrogen Fluoride were low and finding that Clayton Laboratory Services had demonstrated good laboratory and matrix spike recoveries, this Bureau will accept the Hydrogen Fluoride results. However, in the future, failure to follow all method requirements may be grounds for the rejection of all final results.

`01

# . . , - -

Mr. Henry Moore Apri122, 1999 Page Two
Please review this data and if I can be of further assistance in these matters please call me at (803) 898-4303. Sincerely, 

# ox" \1 IQo" Anthony V. Keeler Environmental Chemist Division of Air Compliance Management Bureau of Air Quality cc: Jerry Chalmers Beth Boland Shawna Riddle Joseph Eller Don Smith, Pee Dee District Main File



### 1 006. I . 

### Palmetto Brick Company Permit No. 0660-0021 Lingl # 1&# 2 Id. No CA Cheraw, South Carolina Results - Tests of March 4, 1999
Hvdrol4en Fluoride (Method 26A) 

### Test Production Capacityl Emissions Allowable # tons/hour % mg/m3 Lbs/hr Lbs/hr 1 22.71 96.2 1 2.20 0.228 1.80 2 22.71 96.2 2.00 0.207 1.80 3 22.71 96.2 2.40 0.237 1.80 Avg. 22.71 96.2 2.20 0.224 1.80 

### 1. Based on a process rate of 23.6 tons per hour of brick produced. Visibles (Method 9) Allowable 

### Test # 3 % No. of 6 Min. Sets 5 Sets greater than std. 0 Average Opacity - % 4 20 

### Set Max/min opacity - % 25/0 Operational Notes: 

### 1. Lingl # 1 temperatures ranged from 1982 F to 2021 F and averaged 2000 F during the tests. 2. Lingl 42 temperatures ranged from 2040 F to 2050 F and averaged 2046 F during the tests. 3. Fuel consumption consisted of natural gas; and No. 2 Fuel oil for flashing purposes. 4. Dry Lime Sorption Scrubber minimum cycle time was set at 8 minutes during the tests. 5. Dry Lime Sorption Scrubber photohelic readings ranged from 1.0 to 1.7 inches of water and averaged 1.3 inches of water during the tests. 6. Dry Lime Sorption Scrubber fan Hertz ranged from 30. 3 to 41.8 Hz and averaged 36.9 Hz during the tests. Status as Tested: 

### S.C. DHEC- BAQ Permit No. 0660-0021-CA (Modeled Emission Rate for HF) ........ Compliance S.C. DHEC- BAQ Permit No. 0660-0021-CA (Visibles) ...................................Compliance

cc: Jerry Chalmers Beth Boland Shawna Riddle Joseph Eller Don Smith, Pee Dee District Main File Report Received: 03/26/99 Review Complete: 04/22/99 Reviewer: Ant 

# ~~y~

V. Keeler

\o 0 ~