## P. 1



# RCRA Box 1883

Prepped byOllie Stewart



# Document

Number: 

# 96 ) ll-B-25 8

Docket Number: 

# A-90-1 9

Printed 12/3/200810:42:16

AM Sheet 96 of 171

## P. 2 

# RADIA N

CORPORATIO N MEMORANDU

M 

# A-90-1 9 ll-B-25 8

DATE : Decembe r 22 , 199 1
TO : HO

NProjec t Fil e
FROM : Bar t Ferrer o
SUBJECT : Baselin e Emission s Methodolog

. 

# jj) I 

# LLLLU 1 

# ljj ]
!Fi' ' SE PI4199 2;iA '

CKETj rocess* * Vent s

Th e purpos e o f thi s memorandu m i s t o describ e th e methodologyuse d t o estimat e proces s ven t emission s fro mU.S

. facilitie s i n th e "baselin e case " (prio r t o th e enactmen t o f th e HO Nregulations ) an

d t o presen t th e tota l industrybaselin e emissio n estimates

. Th e contro l statu s o f proces s vent s throughou t th e countryvarie s considerably

. Some proces s ven t

source s ar e totall yuncontrolle d wher e other s hav e varying degree s o f contro l a s a resul t o f Federal , Stat e o r loca l regulations

. Calculation s ar e illustrate d b yth e exampl e presente d i n Attachmen t A

. Mode l proces s ven t stream s wer e assigne d t o represen t th e uncontrolle d emission s fro ma proces s unit

. Th e mode l assigne d t o eac hproces s ven t strea mhad an associate d productio n capacit y (Gg/yr) , uncontrolle d HA P emissio n rat e (Mg/yr) , an d VO C uncontrolle d emissio n rat e (Mg/yr)

. Thes e uncontrolle d emissio n rat e factor s wer e derive d base d o n previou s EPAstudies , questionnair e response s unde r Sectio n 11 4 o f th e Clean Ai r Ac t

an d testing dat a an

d wer e expresse d o n a mas s o f pollutan t pe r productio n basi s (i.e. , Kg VOC/Gg o f product)

. Th e emissio n factor s o f a HONven t strea mwer e develope d a s th e rati o o f th e mode l HA P emissio n rat e t o th e mode l productio n capacity

. Proces s uni t specifi c productio n capacit ydat a wer e multiplie d b y th e appropriat e mode l ven t strea memissio n facto r t o deriv e uncontrolle d VO C an d HA P emissio n estimate s fro meac hvent

.

bemethod(ht

m OD(ts )

Progres s Center/320 0 E

. Chape l Hil l Rd./Nelso n Hwy./P.O

. Bo x13000/Researc h Triangl e Park , N.C

. 27709/(919)541-910 0

# P. 3



# Uncontrolle d HAP Emission s = cap * Ehap M , cap

Where : s 

# ca p = Strea mProductio n Capacit y M 

# ca p = Mode l Productio n Capacit y E 

# ha p = Mode l HAP Emission s Rat e

Uncontrolle d VO C Emission s = CAP * E M , cap vo c

Where : s 

# ca p = Strea mProductio n Capacit y M 

# ca p = Mode l Productio n Capacit y E V 

# o c = Mode l VO C Emissio n Rat e

An exampl e o f a n uncontrolle d emission s calculatio n i s presente d i n Attachmen t A

. Adjustment s wer e mad e t o th e uncontrolle d emissio n estimate s wher e appropriat e t o reflec t emissio n control s require d b yth e viny l chlorid e NESHAP an d Stat e regulations

. Th e regulation s
wer e evaluate d t o develop estimate s o f th e require d contro l efficienc ybase d o n equipmen t o r emissio n limi t requirements

. Th e contro l efficienc yapplie d fo r VO C wa s assume d t o appl yt o

4 .. . 

# HAP a s wel l

. Th e controlle d o r baselin e emission s wer e estimate d b

yapplying th e leve l o f contro l require d b yth e regulatio n t o th e calculate d uncontrolle d emissions :

Baselin e Uncontrollle d Emission s = Emission s * Estimate s Estimat e (10 0 - % Control ) 10 0

A n exampl e o f a baselin e emission s calculatio n i s presente d i n Attachmen t A

. Fo r ven t stream s tha t wer e no t assume d t o hav e emissio n o r contro l requirement s a t th e Stat e o r federa l level , baselin e emission s wer e equa l t o th e uncontrolle d emissions

. Usin g th e describe d methodology , th e tota l baselin e emission s fo r eac hproduc t proces s wer e the n calculate d b y

bemethod(ht

m 01)(ls )

# P. 4



# summing th e individua l ven t emission s a t everyproces s ven t using
a specifi c produc t process
. Attachmen t B contain s th e 198 9 VO C

an d HA P baselin e emissio n estimate s fo r eac ho f th e 1 3 6 Category Aproduc t processes
. A s describe d i n previou s submittals , CategoryAproduc t processe s ar e thos e wher e availabl e informatio n i s judge d t o b e o f sufficien t qualit yfo r regulatory decisio n making

. Th e emissio n value s presente d i n Attachmen t B reflec t combine d total s fo r ai r oxidatio n vents , reacto r vents , an d distillatio n vent s fro mal l proces s units

. Th e column s title d minimu

man d maximu

mshowth e rang e o f emission s fro mth e individua l proces s unit s using th e produc t process
. Attachmen t C present s th e emission s distribute d betwee n ven t type s fo r eac h produc t process
. Attachmen t Acontain s an exampl e calculatio n presenting th e baselin e emission s calculatio n fo r th e produc t proces s chloronitrobenzen e productio n vi a nitratio n o f chlorobenzene

.

cc : Projec t Fil e 6. 1 (M

. Haley ) Thoma s R

. Olsen , Radia n

bemethod(ht

m OD(ls )

# REFERENCE S

1

. Memorandu

m fro mFerrero , B

. J. , Radia n Corporation , t o HO N Projec t File

. "HO

NProces s Vent s Mode l Assignment. " Decembe r 17 , 1991

. 2

. Memorandu

mfro m Olsen , T

. R. , Radia n Corporation , t o Evans , L. , EPA/CPB

. "Developmen t o f Mode l Emissio n Sourc e Characteristic s fo r SOCM I Proces s Vents. " Septembe r 17 , 1991

. 3

. Memorandu

mfro m Olsen , T

. R. , Radia n Corporation , t o King , B. , Radia n Corporation , "Viny l Chlorid e NESHAP Interpretatio n int o th e Proces s Vent s Framework. " Octobe r 11 , 1991

.

4

. Memorandu

mfrom Ferrero , B. , Radia n Corporation , t o Evans , L. , EPA/CPB

. "HO NContro l Technologyfo r HO NProces s Vents. " Novembe r 19 , 1991

.

bemethod(ht

m OD(ls )

## P. 6



# ATTACHMENT A
EXAMPL E BASELINE EMISSION S CALCULATION

FOR CHLORONITROBENZENE PRODUCTIONVI ANITRATIONO F CHLOROBENZENE

# P. 7



# Exampl e Baselin e Emission s Calculatio n

PURPOSE : Th e purpos e o f thi s attachmen t i s t o presen t an exampl e o f calculating th e baselin e HAP an d VO C emission s fo r a produc t process
. Th e produc t proces s selecte d a s th e exampl e i s chloronitrobenzen e productio n vi a nitratio n o f chlorobenzen e (produc t proces s numbe r 100005A)

. APPROACH : A s identifie d b

yth e SOCM I characterization , thi s produc t proces s i s classifie d a s having a reacto r an d a distillatio n vent

. Th e proces s reactio n i s nitratio n an d th e distillatio n colum n wa s classifie d a s a vacuu moperation

. Tw o proces s unit s hav e bee n identifie d a s producer s o f chloronitrobenzen e b yth e nitratio n o f chlorobenzene

. Th e proces s uni t specification s are : Proces s Uni t 1 ha s a capacit yo f 38. 6 gigagram s an d i s locate d i n St

. Clai r Count yIllinois , an d Proces s Uni t 2 ha s a capacit yo f 27. 3 gigagram s an

d i s locate d i n SalemCounty , Ne wJersey

. Mode l proces s ven t stream s ar e assigne d t o eac hfacility

. Fo r thi s exampl e proces s unit , tw o mode l ven t stream s ar e assigne d base d upo n th e classificatio n o f th e proces s vent s a s determine d b

yth e SOCM I characterization

. Sinc e ther e i s no t a compound-specifi c mode l availabl e fo r chloronitrobenzen e productio n b

ynitratio n o f chlorobenzene , th e generi c nitratio n mode l an

d th e generi c vacuu m distillatio n mode l ar e assigned

. Show n belo wi s th e methodologyfo r developing th e uncontrolle d

an d baselin e emission s fo r eac hven t fo r eac ho f th e facilities

.

bemethodCht

m OD(ls )

## P. 8



# Emission s Calculation s fo r Proces s Uni t

Numbe r 1

Reacto rMode

lDescription : Th egeneri c nitratio nmode lha s th efollowin g characteristics : Nitratio nModelProductio nCapacity : 48.1 2 Gg/yr ; Nitratio nMode lUncontrolle dHA PEmission : 38.1 6 Mg/yr ; Nitratio nMode lUncontrolle dVO C Emission : 38.1 6 Mg/yr

.
Uncontrolle dReacto rEmission s Calculation : Th euncontrolle demission s ar ecalculate dfo r th e chloronitrobenzen eproduc t proces s b y scalin g th ereacto r emission s b y th enitratio nmode lan dth eproces s uni t capacities , Th euncontrolle demission s are :

Uncontrolle dHA

PEmissio n= Mode lHA PEmissio n* Proces s Uni t Capacit y Mode lCapacit y
Uncontrolle dHA

PEmissio n- 38.1 6 Mg/y r * (38. 6 Gg/48.1 2 Gg )

Uncontrolle dHA

PEmissio n= 30.6 1 Mg/y r

Uncontrolle dVO

C Emissio n- Mode lVO C Emissio n* Proces s Uni t Capacit y Mode lCapacit y
Uncontrolle dVO

C Emissio n- 38.1 6 Mg/y r * (38. 6 Gg/48.1 2 Gg)

Uncontrolle dVO

C Emissio n= 30.6 1 Mg/y r

bemethodCht m OD(ls )

## P. 9



# Baseline Reactor Emission s Calculation : Sinc e Proces s Uni t Numbe r 1 i s locate d i n St

. Clai r County , Illinois , th e Stat e regulatio n require s reacto r emission s t o b e controlle d i f th e emissio n cap o f 3 1 Mg/yr i s exceeded

. Sinc e th e HA P an

d VO C emission s ar e bot hles s tha n th e emissio n cap , n o emissio n contro l i s require d b yth e Stat e o f Illinois

.

Reacto r Baselin e HAP Emissio n = 30.6 1 Mg/yr
Reacto r Baselin e VO C Emissio n = 30.6 1 Mg/yr
Vacuu m DistillationGeneri c Mode l Description :

Vacuu mDistillatio n Mode l Productio n Capacity : 85.3 5 Gg/yr ;
Vacuu mDistillatio n Mode l Uncontrolle d HAP Emission : 6.6 2 Mg/yr ;
Vacuu mDistillatio n Mode l Uncontrolle d VO C Emission : 12.7 1 Mg/yr

. UncontrolledVacuu

m Distillatio

nEmission s Calculation : Th e uncontrolle d emission s ar e calculate d fo r th e chloronitrobenzen e produc t proces s b yscaling th e vacuu m distillatio n emission s b yth e vacuu

mdistillatio n mode l an d th e proces s uni t capacities

. Th e uncontrolle d emission s are :

Uncontrolle dHA P Emissio n« • Mode l HA P Emissio n* Proces s Uni t Capacit y Mode l Capacit y

Uncontrolle dHA P Emissio n» 6.6 2 Mg/y r * (38. 6 Gg/85.3 5 Gg )

Uncontrolle dHA P Emissio n=2.9 9 Mg/y r

Uncontrolle dVO C Emissio n= Mode l VO C Emissio n* Proces s Uni t Capacit y Mode l Capacit y

Uncontrolle dVO C Emissio n= 6.6 2 Mg/y r * (38. 6 Gg/85.3 5 Gg )

Uncontrolle dVO C Emissio n* 5.7 5 Mg/y r

bemathod(ht

m 01)(Ls )

## P.1 0



# Baseline Vacuu

m Distillatio

nEmission s Calculatio n Sinc e Proces s Uni t Numbe r 1 i s located.i n St

. Clai r County , Illinois , th e Stat e regulatio n require s reacto r emission s t o b e controlle d i f th e emissio n cap o f 3 1 Mg/yr i s exceeded

. Sinc e th e HAP an

d VO C emission s ar e bot hles s tha n th e emissio n cap , n o emissio n contro l i s require d b yth e Stat e o f Illinois

.

Vacuu mDistillatio n =2.9 9 Mg/yr Baselin e HA P Emissio n

Vacuu mDistillatio n =5.7 8 Mg/yr Baselin e VO C Emissio n

betnethod(htn ) 01 ) (ls )

## P.1 1



# Emission s Calculation s fo r Proces s Uni t Numbe r 2

Reactor Mode l Description : Th e generi c nitratio n mode l ha s th e following characteristics :

Nitratio n Mode l Productio n Capacity : 48.1 2 Mg/yr ; Nitratio n Mode l Uncontrolle d HAP Emission : 38.1 6 Mg/yr ; Nitratio n Mode l Uncontrolle d VO C Emission : 38.1 6 Mg/yr

.

UncontrolledReactor Emission s Calculation : Th e uncontrolle d emission s ar e calculate d fo r th e chloronitrobenzen e produc t proces s b yscaling th e reacto r emission s b

yth e nitratio n mode l an d th e facilit ycapacities

. Th e uncontrolle d emission s are :

Uncontrolle dHA P Emissio n= Mode l HA P Emissio n* proces s uni t capacit y
mode l capacit y
Uncontrolle dHA P Emissio n= 21.6 5 Mg/y r
Uncontrolle dVO C Emissio n= Mode l VO C Emissio n* proces s uni t capacit y mode l capacit y Uncontrolle dVO C Emissio n= 38.1 6 Mg/y r * (27. 3 Gg/48.1 2 Gg ) Uncontrolle dVO C Emissio n= 21.6 5 Mg/y r

bemethod(ht

m 01)(ls )

# Baselin eReacto rEmission s Calculation :

Sinc eProces s Uni t

Numbe r 2 i s locate di nSale mCounty , Ne w Jersey , th eStat eregulatio ni s base do nvapo r pressur ean dth e weigh t percent

. Usin g th eHAP/VO C weigh t

percen t

an d chloronitrobenzen evapo r pressure , th eStat erequire daminimu m contro lefficienc y o f 8 3 percent

. N

o contro ldevic ei s specified

.

Reacto r Baselin eHA

PEmissio n= Uncontrolle dHA P* ( 1 - 0.83 ) Reacto r Baselin eHA

PEmissio n= (21.6 5 Mg/yr ) * ( 1 - 0.83 ) Reacto r Baselin eHA

PEmissio n=3.6 8 Mg/y r

Vacuu mDistillatio nGeneri cMode lDescription :

Vacuu mDistillatio nMode lProductio nCapacity : 85.3 5 Gg/yr ; Vacuu mDistillatio nMode lUncontrolle dHA PEmission : 6.6 2 Mg/yr ; Vacuu mDistillatio nMode lUncontrolle dVO C Emission : 12.7 1 Mg/yr

.
Uncontrolle dVacuu

mDistillatio nEmission s Calculation : Th euncontrolle demission s ar ecalculate dfo r th e chloronitrobenzen eproduc t proces s b y scalin g th evacuum distillatio nemission s b y th evacuumdistillatio nmode lan dth e facilit y capacities

. Th euncontrolle demission s are :

Uncontrolle dHA

PEmissio n= Mode lHA PEmissio n* proces s uni tcapacit y

mode lcapacit y Uncontrolle dHA

PEmissio n= 6.6 2Mg/y r* (27. 3 Gg/85.3 5 Gg) Uncontrolle dHA

PEmissio n»2.1 2Mg/y r Uncontrolle dVO

C Emissio n= ModelVO C Emissio n* proces s uni tcapacit y

mode lcapacit y Uncontrolle dVO

C Emissio n= 12.7 1 Mg/y r* (27. 3 Gg/85.3 5 Gg) Uncontrolle dVO

C Emissio n=4.0 6 Mg/y r

bamethod(ht

m OD(ls )

## P.1 3



# Baseline Vacuu

m Distillatio

nEmission s Calculation : Sinc e Proces s Uni t Numbe r 2 i s locate d i n Salem County , Ne w Jersey , th e Stat e regulatio n i s base d o n vapo r pressur e an d th e weigh t percent

. Using th e HAP/VO C weigh t percen t an d chloronitrobenzen e vapo r pressure , th e Stat e require s a minimu m contro l efficienc yo f 8 3 percent

. N o contro l devic e i s specified

.

Vacuu mDistillatio n = Uncontrolle d Emissio n * ( 1 -Efficiency ) Baselin e HA P Emissio n
Vacuu mDistillatio n =2.1 2 Mg/yr * ( 1 - 0.83 ) = 0.3 6 Mg/yr Baselin e HA P Emissio n
Vacuu mDistillatio n = Uncontrolle d Emissio n * ( 1 - Efficiency ) Baselin e VO C Emissio n
Vacuu mDistillatio n =4.0 6 Mg/yr * ( 1 - 0.83 ) = 0.6 9 Mg/yr Baselin e VO C Emissio n

bmetho d(ht

m 01 ) (ls )

## P.1 4



# Tota l Produc t Proces s Baselin e Emission s

Th e tota l produc t proces s emission s ar e determine d b yadding th e baselin e HA P an d VO C emission s fo r eac hven t fo r th e tw o proces s units

. Th e tota l produc t proces s baselin e emission s are :

Tota l Baseline Reactor Emissions :
Tota l Reactor = Proces s Uni t 1 Emission s + Proces s Uni t 2 Emission s
Tota l Reactor HA

P = 30.6 1 Mg/y

r +3.6 8 Mg/y

r = 34.2 9 Mg/y

r Tota l Reactor VOC = 30.6 1 Mg/y r +3.6 8 Mg/y

r = 34.2 9 Mg/y

r



# Tota l Baseline Distillatio nEmissions :
Tota l Distillatio

n= Proces s Uni t 1 Emission s + Proces s Uni t 2 Emission s
Tota l Distillatio

nHA P =2.9 9 Mg/y

r + 0.3 6 Mg/y

r =3.3 5 Mg/y

r Tota l Distillatio

nVOC =5.7 5 Mg/y

r +0.6 9 Mg/y

r =6.4 4 Mg/y

r


# Tota l Produc t Proces s Emissions :
Tota l Emission s = Tota l Reactor + Tota l Distillatio n
Tota l Emission s HA

P = 34.2 9 Mg/y

r +3.3 5 Mg/y

r = 37.6 4 Mg/y

r Tota l Emission s VOC = 34.2 9 Mg/y r +6.4 4 Mg/y

r = 40.7 3 Mg/y

r

b«n«thod(ht m

0 1 His )

# ATTACHMENT B
CATEGORYAPRODUC T PROCES S BASELINE EMISSION SProduct-Procoa a (P-P I Raaall m

(•latio nSourc * Tva a Ca l ••Ion s Sourc a Tvo *

Procaa a Vant a Paa a I e « S



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### •orvuwi KVI Ain—LYSI S OFACRYLMITAIL S FMFIONI C ACI B VI *Al *SIIBATIO N OFPHOPIOHALKHY K ACRYLI C ACI B VI *OIIBATIO H O FACMLCIN

. ACBOLSI N FBi n OIIBATIO H O FPMPYLS N CW.OROACTTI C ACI B VI AHALOSCMATIO H O FACCTI C ACI S OCOROACCTI C ACI B VI *MYSNOLVSI S O FCM.ORJMCSTV L CM.MI K MTMY L ACSTAT

C VI * MYBRSLYSI S OFPOLYVINY L ACC1A U B VMTHAHO L TSTHACMLSBOCTHM M (1.1.2.2- 1 VI *HALOSCHATI WOFACCTYLC M TSTMCMONMTMA M II.1.2.2- 1 VI *HALOSCMATIO H OFCTHYLC M BIIPMHD L •VI *COMKHIATIO H OFFMMO L A M ACCTO M CUM M NYMOPCRO^I KVI * OIIBATIO H O FCUM M MTHY L MTMRCaYLATC VI * HYSMLYSI S AH * ALKYLATIO H O FACCTO M CTAMOHYMI H

•VI ABSHTBROLYSI S OF0CH2OYLBEN2OI C ACI B U.S

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. 4 4 1.2 *

T J

C OProduc t-Procaa a (P-P ) Saaalln a Calsalon * Sourc a Typ a

Cataalo n Sourc a Typ * •Procaa a Vant a 12/20/4 1 rPaa a S o « 5

P- P I B P- P Daacrlatlv a Haa *

A M SUTABIC M



## ! M M UIHO M VI * COM8CNSATI0 H S FNAPMTHASUI N WHO M VI * HYBRMIMRIIATIO H O FSTYAC M PHTHALI C AAMVMI KVI * Al * OIIBATIO H O FO-IYLC M PHTHALI C AHMTMI M VI * Al * SIIMTIO N S FNAPHTHALS M PSHTACMLRMPMMO L VI * H4LRSCHATI0 H O FPMMO L CTHY L TH I I*8 WVI * STNVLATI M O FfTIIULM C HAPTHALC M F80 N PtTBOLSW I BCALKVLATIO N MPNTMALS M FMOT

I COA L TA * BIS TILLATIO N BIPMHT L VI * BSMVSaaSCMTIO N O FB8MIC M IVLS M (•- ) VI * FMCTIOHA L SISTILLATIO N S FH I IC O IVLS M CM.0MTOLUC M (B- l VI * HALOSCHATI M O FTOLUC M RCHIC M SULFONI C ACI S VI * COHTIMUOUS SULFONATIO N M / OLCUM BSN2C M SULFONI C ACI B VI * SULFONATIO H S COHTIMUOUS CITRACTIO N RCHIC M SULFONI C ACI S VI ASULFONATIO N S RCHOHA L OFI M TOLUC M SULFONYL CMLMI KVI AMAC ! I OH O FTOLM M M / CMLOSOSULFONI C ACI B CUM M VI * ALKYLATIt N OFBSNIC M MIT M PMPVLC M BBM18VL OCOBI KVI * MAC TIO N O FKNIOI C ACI B « M SCMOTRICM.ORI K HITMSSMIS M VI AMITBATI M O FRCHIC M U.S

.

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## P.2 1



# ATTACHMENT C
CATEGORYAPRODUC T PROCES S BASELINE EMISSION S B YVENT TYP E

b*m*thod(ht a 01)(ls )chlo robansan a cklarooaazan a C TPRODUC

TPROCES S MA M PROCES S

I00005 ACkloronltrobanian a l*-l*eaar ) vi a nitratio n o l 1000O5ACklaraaltrakanian a (p-laoaar ) vi a nitratio n a f I002I0 ATarapktkall c aci d vi a oaldatlo n a fp-aylan a IM2I M Tarapktkall c aci d vi a kvdralv*! * * fOH l IOMI M Tarapktkall c aci d vi a kydralyal a • « SH T I004I4 ACtkylfcaaian a vl * alkvlatla a a l kaaxan a ult h atkylan a •004I4 AItkylkaaiaa a vi a alkvlatla a a ffcaaiaaa ult k atkylan a I0O42S * Sty ran a araductla n vi a dakydraaaaatla a * 4 atkylbanian * 100425 ASty ran a araductla n vi a aak i * aianatla n * •atkylkanaan a I00425 B Sty ran a vi a dakvdratia a a < aatky l fcaniyl aicaho l I00447 ABaaxy l cklarld a wl * cfclarlnatla a a ftaluon * 100447 * Baasv l cklarld a vi a cklarlaatla * a ftaluan a I005I4 Aaaaiy l alcaka l vi a kyaY-alyal a a fkaaxy l cklarld a I005I4 ABansv l alcaka l vi a kvdralyal * a faaaiy l cklarld a I0M7 M Maaaaatkylaaatatraaia a vl * add i 1 1 a * * 4 unni i t a laraald*kyd * 101408 * M l VI * RCACTI M 4. 4 MTMVLSMCSIAHILI M MIT M FMOSSC M I0I488 AM l VI * MACTI M 4. 4 MTKYLCMBIANILI M MIT M PMMSC M I0I77 M 4.4-Hatkylaaadlaallln a vi a ciidamatla a a 4 anllln a alt k faraaldakyd a I0I77 M 4.4-natkylanadlaallla a vt a caadaaaatla a a 4 anllln a alt k (araaldafcyd a I0IB48 * BIPMMY L OII KVI * HVSMLMI S S FCHLOROMHIC M IMS77 AAcata l vi a cmMaaatla a a fatfcaaa l an d acataldakv d IOS402 ACtpralacta a pradactla n vl * raarraaaaaaa ta l crclokamaaaa a I05M2 AC**r*l*ct* a araductla n vl * raarraaaaaaa ta l cy*la*ia»anan a I0442 M lylaa a (*- > vi a auriflcatla a a fal»a d aylaa a 104445 8 Craaala/craayll c acid * (p-laaaar ) vi a alkal i fuala a * 4 taluan a aulfaa*t* a I0444S S Craaala/craayll c ac td a (*-l**aar > vi a alkal i tuala a a l taluan a aullanata * 10I8IB AEplcklarakydrl a vi a cklar*ky*-atl* a a fally l cklarld a I04BM ACplchlarakydrl n vi a ckl*r*kyar*tl* a a l ally l cklarld a I04M0 ARutadlaa a vi a catalyti c rafaraatla a a fC4 atraaa a IMM M Batadlaa a vi a catalyti c rafaraatla a a fC 4 atraaa a IM** M Batadlaa a vt * dakydraaaaatla a a fC4 caapaund a IMM M Batadlaa a vl * aaknara»anatla a a fC4 caaaauad a 107028 * Acralal a vi a aaldatla a d fpraavlaa a •07051 AAlly l cklarld a vi a kalaaaaatla a a fpraaaa a I07MI * Ally l cklarld a vi a kalaaaaatla a a * praaaa a 107042 * Etkylaa * Blcklarld a vi a cklarlaatlaa/aaycklarlaatla a a fatkylan a 1*70*2 * Ctkylan a Mcklarld a vi a cklarlaatlaa/aaycklarlaatla a a fatkylan a 187111 * AC*YLOHIT*IL C VI * *I B 01 1 BA TI M O FPMPYLS M I07IS M Ctkylaaadlaala a vi a dakyarakalaaaaatta n a fatkylan a dlcklarld a I07IS M Ctkylaaadlaala a vi a dak»«r*kalaaaa«tla a a fatkylaa a dlcklarld a 107IM AALLY L ALCOHOL VI * KYBROLVSI S S FALLY L CMLMI K I071B4 AALLY L ALCOHOL VI * HYBROLVSI S OFALLY L CMLMI K •07IB M ALLY L ALCOHOL VI * ISOMRIIATIO H OFPMPC M OII K 1071*4 * ALLT L ALCOHOL VI * ISOMRIIATI M OFPMFC M OII K 107211 ACtkylaa a alyca l vi a ky*V*lv*l « a fatkylaa a aald * 1*7211 * Ctkylaa a alyca l vi a kydraly*! * a fatkylaa a aala a •07222 * SLV01M

. VI AAI R SIISATIO N OFCTHYLC M SLYCO L 107880 * Butylaa a alyca l ll.l- l vt * kyaraaanatla a a facataldo l I078B0 ABvtylaa a alyca l (I.l- l vl * kvdraaanatla a a facatalda l 107*02 * Praavlaa a «lyc* l aoaaaatky l alka rvi a *lc*H*ly

. praavlaa a aald * k yaatfcana l P- P U.S

. CAPACIT

Y

45

. M 45. M 245*.S O 114.1 0 114.1 0 42IS. M 42IS. M S4M. M 14M. M 544

. M 40.7 * 40.7 * 1.1 8 1.1 8 M . M 415.1 5 411

. I S 142

. n 142.S S 11. M O . M MI. M MI. M IM8. M IS. M 11. M 2*0.2 * 2*0.2 * I1M. M I1M. M MI. M MI. M 11. M 204. M 2M. M 8242. M B242. M I2M. M M . M M . M 27.2 4 27.2 4 27.2 4 27.2 4 281*. M 281*. M 2 . M 11.4 0 11. M 41. M UCH

T TY M

0 R A 0 R 8 

### a B R R 0 R B R R B 

### a B R B R B B B 8 B B B B 

### a B 

### a A B 

### a B B 

# • B 

### a B B B B B 

# * « * * * nOSC L HA M

DISTILLATIO N N

V HITRATI M 100210 * IM2I M HYDROLYSI S 100414 *

. 100414 * 100 4 25 * 100425 A SCMCRI C MACTIO H OISTILLATI M N

V HALOSSMATI M OISTILLATI M M

V MYMOLYSI S SSMBI C MACTI M BISTILLATIO M M

V SCMMI C MACTI M BISTILLATIO M M

V COMCMSAIIO H HYBROLVSI S COMBSNMTI M 105*02 * 10*402 * BISTILLATIO M M

V BISTILLATIO M N

V SCMCRI C RCACTI M BISTILLATIO M M

V SCMCRI C RCACTI M IMM M CATALYTI C REFORM * IMM M BSNVBB06CIMTI M A1 B OIIMTI M I0703I A 107051 A OISTILLATI M M

V 107042 * 107111 * BISTILLATIO M N

V BSMYBaONALOSCMTia N 107184 * HYBROLVSI S 107184 * SCMMI C *(ACT1 M 10721I A 107211 * AI AOIIMTI M BISTILLATIO M N

V HYSHOSCNATIO H BIST1LLATI M M

V HA

P 

### Hussion s

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### 0.0 0 2011.1 1 II.4 * M.I 4 11.5 1 441.8 5 18.1 4 RS*.4 5 4.7 4 1741. M 1.4 1 O . M O . M 

### M4.I 4 171.4 * 1*44.4 1 O . M O . M O . M 

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C 

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S



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. 55 O . M 

### )*4M. M 15)5.4 5 51.1 2 12.1 * 0.0 7 0.0 1 115.0 2 1*0.42 052.4 * 127.4 2 145.0 1 0.0 1 0.0 0 O . M 

### 0.0 0 24M.I * 17

. M M.l * 14.1 * 014.1 5 18.1 4 1140.4 * 4.7 4 2144.4 2 4.5 7 O . M 

### 0.0 0 454.7 * 220.1 * 7M74.8 S 1.1 2 0.4 7 0.0 0 0.0 7 O . M 

### 74.8 * O . M O . M 

### 5*

. 47 0.7 4 S . M 

### 110.1 1

Wan tTyp* Kay , * •Ai rOxidation

. S •Slatlllatlan

. R •Raacto r

### pmouc i PMCCS S

I0O054 A IMIOI A 1MIOI A I0O247 A 108114 8 I0844 M I0844 M 100*0 7 A I0BM7 * I084I M I08*I M 100*41 * 108*41 * IOBM M IMM M



### I0M*7 * I040*7 A 1101*4 8 

### II0I7 M II0I7B * 11 0 11 0 110841 * 110*41 * 

### IIM77 * IIM77 * 1114MB III4* » III44I C III44J C III7«2 A III7A M 111*44 * 111*44 * II2072 A 112*72 * IISI04 * IISIS4 * IISII7 S 115117 8 IIS77S * II78BS * 

### 1 1 MM * 11*41* * I2MI4 A 120414 * PRODUC

TPROCES

S NA M

Proavlan a slyco l aonoaathy l atha rvl * alcokoly

. propylon * oatd * b yaathano l Vlay l acatat a vi a *xv*c*tyl*tla n o fatkylan a Vlay l atatat * vl * *>v*c*tyl«tl* n a fatkylan a naalty l aald * vi a dakvdratia a a fdiacatan a aa d hydraaanatlo n a fuoufcl a kaa d llaalty l aald a vl * dahydratla n a fdiacatan a aa d kydraaanalia a a fdauki a Ban d ACCTI C AkMVMI KVI AAl * OIIMTI M OFACSTALSCHY K Halal c aakyarld * vl * ai raaldatla a a fkut *

•thyl * •thyl a i anld a a yaatk*

.

i aald a b yaatk*

. claa tvi a aulfaaat a fu*l* n procaa a Cklarabaatan a vi a kalaaanatlo n a fbanian * CklaraBaaxaa a vl * kalaaaaatla a a fbanaaa a Cyclakaiylaala a vi a fcvdraaanatlan a fanllla a Cycl*k»iiylaala a vi a fcvdraaanatlan a fanllla a Cvcl«fcaa*a*a a vi a ky*raaan*tla a a fpfcana l Cycl«k»naaa* * vi a kydraaanatlar a a fphana l Pk*a* l vi a aci d c I aavao * a fcaaaa a kydra**r*«ld a Pkaaa l vi a aci d claavaa * a fcuaan a kydraparanld a Ctavlaa a alyca l a i Ik

. atfca rvi a alcakalyal a • Ctkylaa a alyca l aaaaaatk

. atka rvi a alcakalyal a a Bl*tkvl*al* a vi a atkylatla a a faaaanl a Blatkvlaat M vi a atkvlatla a a faaaanl a Succini c Aci d VI * NVBBOLVSI S O FCTHYLC M SICVAHI K Fuaarl c aci d vi a fcvdratlan a faalal c aakydrld * Fuaart c aci d vi a kyaratla a a faalal c aakydrld a Ctkylaa a alyca l aaaaatk

. atka rvl * alcakalyal a a fatkylaa a aald a b yatkaaa l Ctkylaa a alyca l aaaaatk

. atka rvl * alcakalyal a at atkylan a aald a k yatkaaa l Pyrldla a vl * caadaaaatla a a facataldafcyd a *a d faraaldakyd a Pvrldta a vl * c*ad*a**tla n a facataldahyd * an d faraaldakyd a Cycle*aaaa a vl * fcyaVaaanatlaa a ffcaniana Cyclafcanaa a vl * kydraaaaatla n a fbanaaa a ASIPMITRIL C VI * M8ITI M O FHVMOSC H CYAHI * T O BU TA O IS M MIPONIIBIL S VI * AMITI M O FMYBROSS H CYA N I B T O 8UTMIC M MIFONITBIL S VI * CLCCT*OHY**MIMRIIATI M O FACRVLMITRIL C MIPWITBIL C VI * CLCCT*OHVBM*IMRIIAII M O FACRYLMITRIL C Ctkylaa a alyca l aaaafc

. atka rvi a alcakalyal a a fatkylaa a aald a k ybutano l Ctkylaa a alyca l aanab

. atka rvi a alcakalyal a a fatkylan a aald * b ybutano l

• I atkylan a Slvca l d l an ta yI atka rvl * hydraaanatla a a fdaaa a atfca r BlatkylM d Slvca l alaatfcy l atka rvi a kydraaanalla n a fdaaa a atka r Ctkylaa a alyca l ••••Buty l atka racatat a VI ACSTCRIFICATI M OFa.*.a*.atfca r Ctkylaa a alyca l aanabutv l atfca racatat a VI * CSTCRIFICAII M O Fa.a.afc.atfca r Rlaatky l Ctka r(n.a- ) VI * CATALYTI C BSMYSMTI M O FMTHAHO L Blaatky l Ctka r(n.n- l VI * CATALYTI C SSNVSMTI M O FMTHAHO L laafcutylan a vl * crackla * a fMT K laofcutylan a vl * crackla * a fNI K Paataarytfcrlta l vt * addltla a a ffaraaldakyd a l a acataldafcyd a Tatracfcl*r*pfctk*ll c Aakydrld * VI AHALOCCMATI M O FPHTHALI C AMHYMI K SCBIOI M VI * CSTCBIFICATIM.S FSCNIALSCNV K Baasaafcaaaa a VI AACYLATIO N OFKN1C M S CCMIOYL CM.ORI * BSM1Y L BDUOAT E VI ACSTCRIFICATI M O FBCMIY L ALCOH Slaathv l taraafctkalat a vl * aitarlfIcatla a a fTP A P- P U.S

. CAPACIT

Y

4 1

. M I2S5. M I2SS. M M . M M . M SI*

. 7 4 M2. M IS. M l*. M IM.2 8 IM.2 8 * . M

» . M 272

. M 272

. M 1*14. M 1414. M II. M 11. M S7. M 57. M I . M IS. M IS. M 41. M 41. M 27

. M 27.2 0 M4.4 S SB4.4 S 272

. M 272

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V SCMNI C MACTI M SISTILLATI M N

V CSMRI C RCACTI M MYMOLVSI S SISTILLATI M M

V SCMNI C MACTI M SISTILLATI M N

V 110805 * SISTILLATI M N

V CONKMIATI M 110877 * IIM77 A II14M B SCMCNI C MACTI M III4M C III4M C SISTILLATI M V SCMCNI C RCACTI M SISTILLATI M V MYSaOSCNATI M SISTILLATI M N

M CSTCRIFICATI M SISTILLATI M N

V SCMNI C MACTI M SISTILLATI M M

V SCmi C MACTI M SCMNI C MACTI M HALOCCMATI M CSTCRIFICATI M SSMRI C MACTI M CSTCRIFICATI M 120*14 * HA P EHISSION S

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. Ot 44.0 4 O . M 50.2 0 M.B 1 S7.I 5 M . M M . M M.I O O . M O . M O . M 510.7 0 O . M 110.2 4 24.1 2 440. M 0.0 4 5.4 7 4 . M 2.1 2 M . M 74.7 7 0.1 7 121.4 0 147.4 4 1.1 2 O . M 2.1 2 O . M 4U8.4 S

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Buty l acrvlat a tn Cthaaalaaln a vl * Ctfcaaalaala a vi a aaaa i Hatby l tar t buty l atf c r ) vl * aatarlflcatl m a facryli c aci d alval a a fatkylaa a aald a •lyal a a fatkylaa a aal M
rvl * atfcarlflcatla a a fI utyl * utyl a aa daatfcaaal

andaatfcaaal Natfcy l tar t buty l atfca rul * atfcarlflcatla a a fI M Hatfcv l tar t buty l atha rvl * loaaarliatla a a fbat a Hatfcv l tar t buty l atfca rvl * Imarliatla a a fbat a •Io n Thtacvaaat a VI * PYBOMI S O FMHHMIia t BITHI O Hu n Thlacyaaat a VI * PYBBMI S O F aMBHIUT I BITMI S rlahaaa l vl * altylatla n a fa h ana l
•aa l vl * alkylatta a a fpfcana l Cfclaraafcaaa l •vl * hydralval * a fcfclarabanian a Cklaraafcaaal a vi a hyaralyal a a fcklarak—nn * Palvatfcylaa a slvca l vi a palvaa rHa t I a a a fatkylaa a alyca l •atkylaa a aa W Palyatkylaa a alyca l vi a aalyaarliatla a a fatkylaa a alyca l * atkylaa a aal d Palvaraavlan a (lyca l vl * palvaa ra fpraavlaa a aald a aa d praavlaa a alyca l Palyvraaylan a alyca l vl * palvaa ra fpraavlaa a aald a an d p raa yI an a alyca l CFC-2 2 vi a fcalg—nllaa a fcklarafar a Taluan a allaacyaaata a vl * dlaltr*tl* a a ftaluan a ultf c aaaaaaaaatla a Taluan a allaacyaaata a vl * dlaltrctla a a ftaluan a utt k phaaaaaaatla a P- P U.S

. CAPACIT

Y

I2S4. M 171

. M 171. M S7. M S7. M S . M S . M 124.7 0 1*4.5 4 1*4.5 4 O . M 5.4 0 10.7 0 I . M I . M I . M 7 . M 7 . M 22. M 2M. M 2M. M M . M M . M 71.7 0 0.0 1 18.1 0 18.1 0 lll. M lll. M I2S. M IIS. M IM. M IM. M 1101.0 7 1181.0 7 SIS. M SIS. M 7.7 4 7.7 4 IM. M MI. M M . M M . M 241.2 0 2*1

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V ALKVLATI M AI M OIIMTI M BISTILLATI M M

M I2MI M MVBBOSCIMTI M SCMRI C MACTI M SCMRI C RCACTI M SSMRI C MACTI M MY*RMIM*I!ATI « BCHYOMHALOtSNATI I BISTILLATI M V SCMCRI C MACTI M BCHVBROMALOCCMAT H I27IB4 A HAL06CHSTI M 1271*4 * SCMCRI C MACTI M BISTILLATI M B

V CARSOMYLATI M BISTILLATI M M

V OIIMTI M IMS85 A CSTCRIFICATI M BISTILLATI M N

V CSTCRIFICATI M I4I419 A I4I41S A BISTILLATI M M

V 14140 4 4

A BISTILLATI M V SCMRI C MACTI M BISTILLATI M M SCMRI C RCACTI M BISTILLATI M V 2SI5M2 M BISTILLATI M M

V HYBROLMI S BISTILLATI M H

V SCMRI C MACTI M BISTILLATI M M

V SCMCRI C MACTI M 254*72*4 * BISTILLATI M M

V HYB*OSCH*TI M HAP MISSION S

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Bllaadacy l phthalat a vl * aatarlficatla n u/pfctkalt c anhydrld * an d dacaaa l Sllaadacv l phthalat a vl * aatarl fIcatla n u/pa t Dall e aafcvdrld e an d dacaaa l Rraaanap*thaian a vl * kalaaanatla a a faaahtfcalan a

tha i an a vi a kalaaanatla a a faaahtfcalan a t y l afctfcalat a vl * aatarl fIcatla a ml pfctfcall c ankydrld * S acty l alca h t y l phthalat a vl * aatarlflcatla a ml phthali c ankydrld * S acty l *lc*f c •hvd a fra a dahyavaaanatla a a faatkana l Foroaldafcyd a fra a ««* i * imiHla a a faatfcaaa l Faraa l *•>)« •vi a ai raa l da tI a a a faatfcaaa l Blaltraafcana l 12.4- 1 VI * HYDROLYSI S O F2.4-SINITROCM.OROSCMIt M Blnltraafcaaa l 12.4- 1 VI * MYSROLMI S O F2.4-BIHITMCMLOaOMHZI M Trlaathvlpaatan a 12.2.4- 1 (a- ) VI * ALKVLATI M O FISOSUTYLS M « M IM-BUTM C Trlaathylpaataa a (2.2.4- 1 (a- l VI * ALKYLATI M O FISOMTYLC M A M IM-8UTA M Ctrba a tatracfclarld a vl * chlarlaatla u a fcarba n dlaulfl M Carta * tatrachlarld a vl * cklarlaatla n a l carba a dlaulfld a Carba n tatrachlarld a vi a cfclarlaatla a a ffcy*-acartaa* Carta * tatracfclarld a vl * cfcl*rla*tla a a ffcyaVacartam SLVCI M VI * BIBMTII I 8 FCIS.0MACBII C *CI B SLVCI M VI * WSWNPLMI * S FCH.OHMCCII C ACI B SLTCSM L VI * HYBBOLMI S S FCPICHLOROHVMI H SLYCSM L VI * HYSMLMI S S FCPIOCONOMYMI N ' Praavlaa a alyca l vi a fcydralyal* mt praavlaa a aald a Parchlaraaatfcy l Karcapta a VI * laV-OCCMATI M S FCAM M BISULFI K Parcfclaraaatkv l Harcapta n VI * MALOSCMATIO WS FCAM M BISULFI K MSTMI KVI * BISTILLATI M O FMOSMIU H *CST*T S MCCTAMI KVI * BISTILLATI M S FAMMIU N «CST*T S Hatfcv l laacyanat a vi a afcaaaaaatla * mt aathylaala a Matfcy l laacvaaat * vl * pfcaaaanatia a mt aathylaala a MILI M VI AIIYBB8CIMRTI M S FMITBOBSWS M AMILI M VI AIIISMfCMATI M S FNIT808B1U M MILI M VI * AHIHOLMI S 8 FPNSNB L MILI M VI AMIMLMI S S FPMBMO L ACCTI C MI B VI ACAMONVLATI M O FMTHAM L ACCTI C ACI B VI * CARSOMVLATI M O FMTHAHO L ACCTI C ACI B VI * MIMTI M S FACSTALSSMV M MIT M CATALM T ACSTI C ACI B VI * OIIMTI M S F*CST«LKMT KWI N CATALM T Btaaalaa a VI * COMCMMTI M O FSLYCO L A M F O Maaalaa a VI * COMCMMTI M S FSLVCS L M B FO

v l * kvdraaanatla a mt carba a aanaaid * v i a fcvdraaan«tl*a a l carba a aanaald a Cklarafar a vi a fc*lai«aitlaa a faatfcv l cklarld a Cklarafar a vl * balaoaaatla a a faatfcv l cklarld a Cklarafar a vi a kalaaanatla a a faat k an a Cklarafar a vl * kalaaanatla a a l aatfcaa a •4aatkv tfarai*ld a vi a cartaaylatla * a fdlaatfcylaala a Blaatky l faraaald a vl * carbaavlatla a mt dlaatfcylaala a Maatfcy l faraaald a vl * aalaalyal * mt aatfcv l faraat a Blaatky l faraaafd a vl * aalaalyal * a faatfcv l faraat a Salicyli c aci d vl * avarafaravMtl* * a l aadlu a a h a n it * P- P U.S

. CAPACIT

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704

. M 7M. M O . M O . M 7M. M 704

. M IIM. M 1178. M I1I1. M O . M O . M 0.2 8 0.2 S 118. M 118. M IM. M I4*. M I . M I . M IS. M IS. M 422.1 0 11.4 2 IS. M O . M O . M 18.1 8 IB

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V HYBROLVSI S BISTILLATI M N V ALKYLATI M S42S M SSMBI C RCACTI M SMS M SSMBI C RCACTI M BISTILLATI M M SSMBI C MACTI M BISTILLATI M N

V HYSMLMI S BISTILLATI M NV BISTILLATI M NV N*LOCCN*TI M BISTILLATI M M SSMBI C RCACTI M BISTILLATI M M SCMCBI C RCACTI M 42S1 M •2SS M BISTILLATI M M

V SCMCBI C BCACTI M MIM A CARMNYLATI M 441*7 * OIIMTI M BISTILLATI M N

V COMCMMTI M • I B MIMTI M ATMI * NYSaaSSMTI M BISTILLATI M V HALOCCMATI M BISTILLATI M V HALSSCMII M BISTILLATI M NV CAMONVLATI M BISTILLATI M M

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C EMISSION S

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. CAPACITY

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