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HYDROGEN FLUORIDE EMISSION EVALUATION 

ON DRY LIME SCRUBBER FOR 

` PALMETTO BRICK COMPANY 

CHERAW, SOUTH CAROLINA 

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MARCH, 1999 

DAVIS & FLOYD, INC. JOB NUMBER 60823.00 

PREPARED BY 

DAVIS & FLOYD, INC. 

ENVIItONMENTAL DIVISION 

GREENWOOD, SOUTH CAROLINA 

PLOTHRI D\HGA99\60823-3. DOC 

DAVIS & FLOYD, INC. 
I DAIV I S Engineeriog ~ 

; Arc6itecture 

° FL D Environmenlal & Laboratory Services 

~ 

; P.O. Drawer 428 Greenwood, SC 29648 • 816 East Durst Avenue Greenwood, SC 29649 •(864) 229-4413 (office) (864) 229-7119 (fax) 

March 22, 1999 

Serial No. HGA-038-99 

Job No.: 60823.00 

Mr. Henry Moore 

Palmetto Brick Company 

P.O. Box 430 

Cheraw, SC 29520 

Reference: Emission Testing on Dry Scrubber 

Dear Mr. Moore: 

Davis & Floyd, Inc. conducted source test sampling at Palmetto Brick Company, Cheraw, South 

Carolina, on March 4, 1999. These, tests. were conducted on the outlet gases of the dry lime scrubber. 

~ Two copies of the report containing the results of this project are enclosed. A copy of this report has 

=y been mailed to Mr. Antliony Keeler, South Carolina Department of Health and Environmental Control, 

Bureau of Air Quality, 2600 Buil Street, Columbia, SC, 29201. 

We would like to express our appreciation to you and the Palmetto Brick Company personnel involved in 

this project for their assistance in the areas of scheduling, physical arrangements, etc. Should you have 

any questions regarding this work or report, or if we may be of additional assistance, please do not 

hesitate to contact us. 

Sincerely, 

DAVIS & FLOYD, INC. 

~ 

H. Gary Anderson, Jr. 

~ Field Services 

Environmental Division 

Enclosures: As stated in letter 

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TABLE OF CONTENTS 

PAGE 

1.0 INTRODUCTION 1.1 

2.0 TEST OBJECTIVES 2.1 

3.0 PROCESS DESCRIPTION 3.1 

4.0 SAMPLING AND ANALYTICAL PROCEDURES 4.1 

4.1 Velocity Traverse Point Locations 4.1 

4.2 Volumetric Flow Rate 4.1 

4.3 Moisture and Molecular Weight 4.1 

4.4 Hydrogen Fluoride Concentrations 4.2 

5.0 SAMPLING RESULTS 5.1 

Table 5.1 Hydrogen Fluoride Emission Results 

Table 5.2 Chloride Emission Results 

6.0 ACCEPTABILITY OF RESULTS 6.1 

APPENDICES 

APPENDIX I 

EPA Metliod 26 Data Reduction 

APPENDIX II 

Calculations 

APPENDIX III 

Field Data 

Field Equipment Calibrations 

APPENDIX IV 

Laboratory Data 

Production Data 

PLOTHRID\HGA99\60823-3.DOC . 

nAVIC R mnvn iN!` 3 
1.0 INTRODUCTION 

Palmetto Brick Company, located in Cheraw, South Carolina, is a manufacturer of ceramic brick. A part 

of this process is the drying or curing of the brick, which is done in ovens referred to as kilns. On March 

4, 1999, emission tests were conducted for the halide hydrogen fluoride and the halogen chlorine on the 

outlet gases of the recently installed dry lime scrubber. Stanley Broome and Brandon Wilson of Davis & 

Floyd, Inc. performed this testing. The purpose of the testing was to determine permit compliance. 

These tests were observed by South Carolina Department of Health and Environmental Control 

(SCDHEC) representative, Anthony Keeler. 

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~. 2.0 TEST OBJECTIVES 

The objective of this testing was to demonstrate compliance with South Carolina Department of Health 

and Environmental Control (SCDHEC) established air standards for hydrogen fluoride using EPA 

Method 26A (Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources — 

Isokinetic Method). This testing, in conjunction with tSCST3 air dispersion modeling, analysis, was used 

to demonstrate compliance, since compliance is at the facility boundaries, not emission source. The HF 

emission, rate for this test was 0.224 pounds per hour and is less than 1.80 pounds per hour: Compliance 

has been demonstrated based on previously submitted and approved modeling. . 

2.1 Applicable State Regulations 

SC Reg. 62.5 Standard No. 2 Ambient Air Quality Standards 

♦ 1-lydrogen Fluoride: 12-Hr. Ave. = 3.7 ug/m3 

24 Hr. Ave. = 2.9 ug/m 3 

1-Wk Ave. = 1,6 ug/m 3 

1-Month Ave. = 0.8 ug/m3 

♦ HF Emission Rate <1.80 lb/hr has dem onstrated compliance based on previously 

submitted and approved modeling. 

PLOTHRI D\HGA99\60823-3. DOC 

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3.1 

3.0 PROCESS DESCRIPTION 

The tested processes consist of two brick manufacturing operations. Raw materials (clay, shale, kaolin, 

etc.) are mixed together with water and are extruded into brick shapes. The brick is placed on cars that 

are air dried prior to being placed into kiln (01) or (02) for curing. As a result of curing the brick at 

approximate temperatures of 1800°F, fluorine contained in the raw materials (clay, shale, etc.) combines 

with water vapor and is released to the atmosphere as gaseous Iiydrogen fluoride. The dry lime sorption 

scrubber captures the hydrogen fluoride emissions by combining it with lime, used as the sorption media. 

The lime material becomes coated with captured fluorine material. The curing process is considered 

continuous. 

Cmissions from each of the two kilns are routed tlirough a common inlet duct into the dry lime sorption 

scrubber. Fluorine present in the raw materials will be released to the scrubber as gaseous hydrogen 

fluoride, where it will be adsorbed onto the limestone. 

A time control system associated with the discharge of spent lime from the scrubber ensures that the 

limestone continues to fall down evenly from the storage silo over the cascades, thus making sure that 

adsorption of the hydrogen fluoride and the utilization of the limestone granules are optimal. 

The supply of flue gas to the scrubber is controlled by means of a differential pressure measuring 

transducer depending on vacuum in the kilns. This transducer compares the actual and desired values 

and generates a signal to a frequency converter, which adjusts the scrubber fan motor torque and speed 

continuously at constant pressure to ensure the proper quantity of flue gas is extracted from each kiln. 

The process rate and kiln temperature of each kiln were recorded by Palmetto Brick personnel. It was 

the responsibility of each kiln supervisor to collect this information. 

PLOTHRIDU-IGA99\60823-3.DOC 

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4.0 SAMPLING AND ANALYTICAL PROCEDURES 

4.1 Velocity Traverse Point Locations 

The velocity traverse point locations were selected in accordance with EPA Method 1, "Sample 

and Velocity Traverses for Stationary Sources". The scrubber exhaust is equipped witli a circular 

stack that is 60 inches in diameter. Two sample ports were located horizontally across the stack 

at a location that was approximately 48 feet downstream of the nearest flow disturbance and 20 

feet upstream from the top of the stack. Twelve (12) traverse points were selected for velocity 

determinations, 6 along each sample port cross-section (see Figure 1). 

4.2 Volumetric Flow Rate 

Stack gas volumetric flow rate was determined in accordance with BPA Method 2, 

"Determination of Stack Gas Velocity and Volumetric Flow Rate". This was performed in 

conjunction with EPA Method 26A. 

4.3 Moisture and Molecular WeiQht 

Stack gas moisture content was determined as per EPA Method 4, "Determination of Moisture 

Content in Stack Gases" in conjunction with EPA Method 26A. Stack gas molecular weight was 

determined by obtaining samples and analyzing for oxygen and carbon dioxide concentrations 

using a Teledyne Max-5 combustion analyzer. 

4.4 Hydrogen Fluoride Concentration 

Hydrogen Fluoride concentrations were determined in accordance with EPA Method 26A, 

"Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources - Isokinetic 

Method". Three one-hour test runs were conducted. The sample train consisted of a one-piece 

~ glass-lined probe and glass nozzle, a glass fiber filter (Teflon mat, Paliflex), EPA Method 5 glass 

PLOTHRI D\HGA99\60823-3.DOC 

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impingers, and an EPA Method 5 control console. The first two impingers contained 100 ml each 

of 0.1 N sulfuric acid, the third and fourth impingers each contained 0.1N sodium hydroxide, and 

the fifth impinger contained 200 milligrams of silica gel. After the testing was completed, the 

samples were transported to the laboratory where the volume of the impinger catch was 

measured, the silica gel was weighed, and the impinger solution was transferred to EPA protocol 

washed glass sample bottles. The impingers were then rinsed with a known volume of D. 1. 

water, and the rinse was combined with the samples. The samples were then analyzed using ion 

cliromatography as specified in the method. 

PLOTH RI D\HGA99\60823-3. DOC 

nAvIS & Fld)vfl INC 
5.1 

5.0 SAMPLING RESULTS 

On March 4, 1999, stack gas emission studies were conducted at Palmetto Brick Company, Cheraw, 

South Carolina. The results of this testing are found in Tables 5.1 and 5.2. 

~~

.. 

 ABLE Sa::ry 

Hydrogen Fluoride Emission Results 

Outlet to Dry Lime Scrubber 

Palmetto Brick Company 

Cheraw, South Carolina 

Test conducted: March 4, 1999 

Test Time Air Sample 

Volume 

dscm 

Stack Gas 

Flow Rate 

(dscfm) 

Emission 

Concentration HF 

mg/m3 

Emission Rate 

(lb/hr) 

Run 41 0906-1011 1.1674 27,648 2.2 0.228 

Run 42 1021-1124 1.1743 27,606 2.0 0.207 

Run 43 1 1132-1235 1.1671 1 26,384 1 2.4 1 0.237 

Calculations: 

1. Lbs/hr = 1 Ib/454,000 mg x mg/m3x Std. Ft. 3 /Min x m3 /35.31 ft3x 60 min/hr. 

NOTE: Standard cubic feet per minute at 29.92 inches of inercury and 68 degrees F. 

H2SO4 O.1N Blank = <400 Ivlicrograms HF 

D.I. Water Blank = <300 Micrograms Chlorine 

D.I. Water Blank = <400 Micrograms HF 

TABLE 5.2 

Chlorine Emission Results 

Outlet to Dry Lime Scrubber 

Palmetto Brick Company 

Cheraw, South Carolina 

Test conducted: March 4, 1999 

Test Time Air Sample 

Volume 

dscm 

Stack Gas 

Flow Rate 

dscfm 

Emission 

Concentration 

Chlorine mg/m3 

Emission Rate 

lbs/hr 

Run # 1 0906-1011 1.1674 27,648 0.6 0.062 

Run #2 1021-1124 1.1743 27,606 0.5 1 0.052 

Run #3 1132-1235 1.1671 1 26,384- 0.5 1 0.049 

Calculations: 

l. Lbs/hr = 1 lb/454,000 mg x mg/m 3x Std. Ft. 31Min x m3/35.31 ft3x 60 min/hr. 

NOTE: Standard cubic feet per minute at 29.92 inches of inercury and 68 degrees F. 

D.I. Water Blank = <300 Micrograms Chlorine 

0.1N Na OH Blank = <300 Micrograms Chlorine 

PLOTHRID\HGA99\60823-3. DOC 

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6.1 

6.0 ACCEPTABILITY OF RESULTS 

Isokinetic percentage refers to how closely the sampling rate matches the stack gas flow rate. EPA 

Method 5 data is acceptable if the isokinetics of the test runs are ] 00 ±] 0 percent. The isokinetic rate of 

these test runs were as follows: 

OUTLET TO DRY LIME SCRUBBER 

RUN 1 96.85 

RUN 2 97.55 

RUN 3 98.97 

PLOTI-IRIDUiGA99160823 -3. DOC 

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APPENDIX 1 

EPA Method 26 Data Reduction 

PLOTHRIDU-IGA99\60823-3. DOC 

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FOR:PALMETTO BRICK CO. 

LOCATION:CHERAW, SC 

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TEST METHOD:EPA M26A 

SAMPLE DATE:3-4-99 

DAVIS & FLO.YD INC. 

POST OFFICE DRAWER 428. 

GREENWOOD, SOUTH CAROLINA 29648 

aawawwwwwa++++waww+aaa+awwww++w++rrwr 

*** SOURCE SAMPLING DATA REPORT *** 

awwrwwwawwaaww+waaaa+wrww+wwwwwa++rw+ 

RUN 1 

"CO2 CONCENTRATION 0.50 PERCENT 

02 CONCENTRATION 20.20 PERCENT 

CO CONCENTRATION 0.00 PERCENT 

N2 CONCENTRATION 79.30 PERCENT 

DRY MOLECULAR WEIGHT OF GAS 28.89 POUND/POUND-MOLE 

. FINAL IMPINGER WATER VOLUME 470.0 MILLILITERS 

..:INITIAL IMPINGER WATER VOLUME 400.0 MILLILITERS 

SILICA GEL VOLUME INCREASE 9.3 MILLILITERS 

`'TOTAL MOISTURE COLLECTED 79.3 MILLILITERS 

TOTAL MOISTURE COLLECTED 3.7430 STANDARD CUBIC FEET 

MOISTURE CONTENT OF STACK GAS 8.324 PERCENT 

tMEASURED DRY GAS VOLUME THROUGH METER 39.833 CUBIC FEET 

113AROMETERIC PRESSURE 29.75 INCHES OF MERCURY 

AVERAGE GAS TEMPERATURE THROUGH METER 49.3 DEGREES FAHRENHEIT 

-AVERAGE GAS DELTA H 1.800 INCHES OF WATER 

~ DRY GAS VOLUME THROUGH METER 41.2244 STANDARD CUBIC FEET 

JMOISTURE CONTENT OF STACK 0.0832 DIMENSIONLESS 

-.WET MOLECULAR WEIGHT OF GAS 27.98 POUND/POUND-MOLE 

PITOT TUBE COEFFICIENT 0.84 DIMENSIONLESS 

`AVERAGE STACK GAS TEMPERATURE 302.7 DEGREES FAHRENHEIT 

AVERAGE SQUARE ROOT OF DELTA P 0.541 INCHES OF WATER 

/,STATIC STACK PRESSURE -0.14 INCHES OF WATER 

IIPRESSURE OF STACK 29.74 INCHES OF MERCURY 

STACK GAS VELOCITY 37.2005 FEET PER SECOND 

1

- CROSS-SECTIONAL AREA OF STACK 19.6350 SQUARE FEET 

~1STACK GAS VOLUMETRIC FLOW RATE 27647.8148 STD. CFM (68 & 29.92) 

STACK GAS VOLUMETRIC FLOW RATE 43825.7824 ACFM 

'_WET BULB STACK GAS TEMPERATURE N/A DEGREES FAHRENHEIT 

,'TOTAL PARTICULATE COLLECTED 0.0 MILLIGRAMS 

PARTICULATE CONCENTRATION 0.0000 GRAINS PER SCF 

:4PARTICULATE CONCENTRATION @%12 CO2 0.0000 GRAINS PER SCF 

IPARTICULATE EMISSION RATE 0.0000 POUNDS PER HOUR 

TOTAL SAMPLING TIME 60.00 MINUTES 

rDIAMETER OF SAMPLING NOZZLE 0.304 INCHES 

;CROSS-SECTIONAL AREA OF SAMPLING NOZZLE 5.0405E-04 SQUARE FEET 

PERCENT OF ISOKINETIC SAMPLING 96.85 PERCENT 

~ 3 
DAVIS & FLOYD INC. 

POST OFFICE DRAWER 428 

GREENWOOD, SOUTH CAROLINA 29648 

aa++rrrr+ra+w++rrar+r+ar++ttttra+r+tt 

'+a SOURCE SAMPLING DATA REPORT tta 

+a++a+ar+t++tt++++rr++++++rt+attara++ 

RUN 2 

FOR:PALMETTO BRICK CO. TEST METHOD:EPA M26A 

a OCATION:CHERAW, SC SAMPLE DATE:3-4-99 

-jOURCE:DRY LIME SCRUBBER DAVIS & FLOYD, INC. JOB#:60823.00 

CO2 CONCENTRATION 0.40 PERCENT 

.02 CONCENTRATION 20.40 PERCENT 

-O CONCENTRATION 0.00 PERCENT 

N2 CONCENTRATION 79.20 PERCENT 

---DRY MOLECULAR WEIGHT OF GAS 28.88 POUND/POUNG-MOLE - 

rINAL IMPINGER WATER VOLUME 485.0 MILLILITERS 

INITIAL IMPINGER WATER VOLUME 400.0 MILLILITERS 

.SILICA GEL VOLUME INCREASE 9.7 MILLILITERS 

TOTAL MOISTURE COLLECTED 94.7 MILLILITERS 

L TOTAL MOISTURE COLLECTED . 4.4698 STANDARD CUBIC FEET 

;'VIOISTURE CONTENT OF STACK GAS 9.731 PERCENT 

;VIEASURED DRY GAS VOLUME THROUGH METER 40.477 CUBIC FEET 

BAROMETERIC PRESSURE 29.75 INCHES OF MERCURY 

AVERAGE GAS TEMPERATURE THROUGH METER 54.7 DEGREES FAHRENHEIT 

;qVERAGE GAS DELTA H 1.872 INCHES OF WATER 

DRY GAS VOLUME THROUGH METER 41.4641 STANDARD CUBIC FEET 

-MOISTURE CONTENT OF STACK 0.0973 DIMENSIONLESS 

;JVET MOLECULAR WEIGHT OF GAS 27.82 POUND/POUND-MOLE 

`'PITOT TUBE COEFFICIENT 0.84 DIMENSIONLESS 

.,AVERAGE STACK GAS TEMPERATURE 304.8 DEGREES FAHRENHEIT 

~AVERAGE SQUARE ROOT OF DELTA P 0.548 INCHES OF WATER 

STATIC STACK PRESSURE -0.14 INCHES OF WATER 

PRESSURE OF STACK 29.74 INCHES OF MERCURY 

'STACK GAS VELOCITY 37.8265 FEET PER SECOND 

:=~ICROSS-SECTIONAL AREA OF STACK 19.6350 SQUARE FEET 

STACK GAS VOLUMETRIC FLOW RATE 27606.1267 STD. CFM (68 & 29.92) 

;STACK GAS VOLUMETRIC FLOW RATE 44563.3127 ACFM 

"✓1/ET BULB STACK GAS TEMPERATURE N/A DEGREES FAHRENHEIT 

TOTAL PARTICULATE COLLECTED 0.0 MILLIGRAMS 

;PARTICULATE CONCENTRATION 0.0000 GRAINS PER SCF 

~ARTICULATE CONCENTRATION @%12 CO2 0.0000 GRAINS PER SCF 

PARTICULATE EMISSION RATE 0.0000 POUNDS PER HOUR 

;TOTAL SAMPLING TIME 60.00 MINUTES 

,.;:DIAMETER OF SAMPLING NOZZLE 0.304 INCHES 

CROSS-SECTIONAL AREA OF SAMPLING NOZZLE 5.0405E-04 SQUARE FEET 

, PERCENT OF ISOKINETIC SAMPLING 97.55 PERCENT 

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DAVIS & FLOYD INC. 

POST OFFICE DRAWER 428 

GREENWOOD, SOUTH CAROLINA 29648 

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*** SOURCE SAMPLING DATA REPORT *** 

RUN 3 

FOR:PALMETTO BRICK CO. TEST METHOD:EPA M26A 

-,LOCATION:CHERAW, SC SAMPLE DATE:3-4-99 

SOURCE:DRY LIME SCRUBBER DAVIS & FLOYD, INC. JOB#:60823.00 

CO2 CONCENTRATION 

, ?02 CONCENTRATION 

;CO CONCENTRATION 

N2 CONCENTRATION 

-:,DRY MOLECULAR WEIGHT OF GAS 

FINAL IMPINGER WATER VOLUME 

~ INITIAL IMPINGER WATER VOLUME 

,SILICA GEL VOLUME INCREASE 

TOTAL MOISTURE COLLECTED 

-`TOTAL MOISTURE COLLECTED 

; ~,MOISTURE CONTENT OF STACK GAS 

~MEASURED DRY GAS VOLUME THROUGH METER 

" gBAROMETERIC PRESSURE 

_ AVERAGE GAS TEMPERATURE THROUGH METER 

"AVERAGE GAS DELTA H 

I'DRY GAS VOLUME THROUGH METER 

MOISTURE CONTENT OF STACK 

?:WET MOLECULAR WEIGHT OF GAS 

_iPITOT TUBE COEFFICIENT 

AVERAGE STACK GAS TEMPERATURE 

;<AVERAGE SQUARE ROOT OF DELTA P 

!STATIC STACK PRESSURE 

PRESSURE OF STACK 

1~ :STACK GAS VELOCITY 

Z,,~ CROSS-SECTIONAL AREA OF STACK 

STACK GAS VOLUMETRIC FLOW RATE 

°~,STACK GAS VOLUMETRIC FLOW RATE 

~,kWET BULB STACK GAS TEMPERATURE 

TOTAL PARTICULATE COLLECTED 

,.,PARTICULATE CONCENTRATION 

1PARTICULATE CONCENTRATION @ %12 CO2 

PARTICULATE EMISSION RATE 

,TOTAL SAMPLING TIME 

`DIAMETER OF SAMPLING NOZZLE 

0. 

CROSS-SECTIONAL AREA OF SAMPLING NOZZLE 

::PERCENT OF ISOKINETIC SAMPLING 

0.40 

20.50 

0.00 

79.10 

28.88 

481.0 

400.0 

12.0 

93.0 

4.3896 

9.844 

39.432 

29.75 

56.9 

1.718 

40.2026 

0.0984 

27.81 

0.84 

305.5 

0.524 

-0.14 

29.74 

36.2326 

19.6350 

26383.9453 

42685.5339 

N/A 

0.0 

0.0000 

0.0000 

0.0000 

60.00 

0.304 

5.0405E-04 

98.97 

PERCENT 

PERCENT 

PERCENT 

PERCENT 

POUND/POUND-MOLE 

MILLILITERS 

MILLILITERS 

MILLILITERS 

MILLILITERS 

STANDARD CUBIC FEET 

PERCENT 

CUBIC FEET 

INCHES OF MERCURY 

DEGREES FAHRENHEIT 

INCHES OF WATER 

STANDARD CUBIC FEET 

DIMENSIONLESS 

POUND/POUND-MOLE 

DIMENSIONLESS 

DEGREES FAHRENHEIT 

INCHES OF WATER 

INCHES OF WATER 

INCHES OF MERCURY 

FEET PER SECOND 

SQUAREFEET 

STD. CFM (68 & 29.92) 

ACFM 

DEGREES FAHRENHEIT 

MILLIGRAMS 

GRAINS PER SCF 

GRAINS PER SCF 

POUNDS PER HOUR 

MINUTES 

INCHES 

SQUAREFEET 

PERCEN7 
DAVIS & FLOYD INC. 

POST OFFICE DRAWER 428 

GREENWOOD, SOUTH CAROLINA 29648 

***.«.*..**.*..*««.*.....**.,«...*.«. 

*** SOURCE SAMPLING DATA SUMMARY *** 

TOR:PALMETTO BRICK CO. TEST METHOD:EPA M26A 

LOCATION:CHERAW, SC SAMPLE DATE:3-4-99 

'SOURCE:DRY LIME SCRUBBER DAVIS &FLOYD, INC. JOB#:60823.00 

`% CO2 0.50 0.40 0.40 0.43 

1 % 02 20.20 20.40 20.50 20.37 

;% CO 0.00 0.00 0.00 0.00 

N2 79.30 79.20 79.10 79.20 

Dry molecular weight (MD) 28.89 28.88 28.88 28.88 

' Final impinger volume (VF) 470.0 485.0 481.0 478.7 

-'=lnitial impinger volume (VI) 400.0 400.0 400.0 400.0 

Silica gel vol. increase (VS GEL) 9.3 9.7 12.0 10.3 

'Total moisture collected (VIC) 79.3 94.7 93.0 89.0 

_,:.Total moist. collected (VM STD) 3.7430 4.4698 4.3896 4.2008 

Stack gas moist.content (B WO) 8.324 9.731 9.844 9.300 

rMeter dry gas volume (VM) 39.833 40.477 39.432 39.914 

_'Barometric pressure (P BAR) 29.75 29.75 29.75 29.75 

~ Dry gas meter temp (TM) 49.3 54.7 56.9 53.6 

iDry gas orifice pressure (DELTA) 1.800 1.872 1.718 1.797 

_iMeter dry gas volume (VM STD) 41.2244 41.4641 40.2026 40.9637 

Stack gas moist.content (B WO) 0.0832 0.0973 0.0984 0.0930 

Wet molecular weight (MS) 27.9817 27.8213 27.8126 27.8719 

A~ Pitot coefficient (CP) 0.84 0.84 0.84 0.84 

Avg stack gas temp (TS AVG) 302.7 304.8 305.5 304.3 

,,(AVG SQ/R DELTA P) 0.5411 0.5479 0.5245 0.5378 

~-Static stack pres. (STATIC P) -0.140 -0.140 -0.140 -0.140 

~ Pressure of stack (PS) 29.7397 29.7397 29.7397 29.7397 

Stack gas velocity (VS) 37.2005 37.8265 36.2326 37.0865 

4i 1'Cross-sectional stack area (A) 19.6350 19.6350 19.6350 19.6350 

-*Stack gas flow (QS STD CFM) 27647.8148 27606.1267 26383.9453 27212.6290 

Stack gas flow (QS ACFM) 

~ 

43825.7824 44563.3127 42685.5339 43691.5430 

Wet bulb temp (WB/T) N/A N/A N/A N/A 

~!Particulate gain (MN) 0.0000 0.0000 0.0000 0.0000 

Particulate concent. (C/S) 0.0000 0.0000 0.0000 0.0000 

C/S @ %12 CO2 N/A N/A N/A #DIV/0! 

{ Particulate emission rate (CS) 0.0000 0.0000 0.0000 0.0000 

Total Sampling Time (TIME) 60.0 60.0 60.0 60.0 

~ ';Nozzle diameter (DN) 0.3040 0.3040 0.3040 0.3040 

~Area of nozzle (AN) 5.0405E-04 5.0405E-04 5.0405E-04 5.0405E-04 

Percent isokinetic (1) 96.85 97.55 98.97 97.79 

~ l4 
APPENDIX 2 

Calculations 

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CALCULATIONS 

Determination of Dry Molecular Weight: 

Md = molecular weight of stack gas (dry basis), Ib/Ib-mole 

Md = 0.44 (%CO2) + 0.32(%02) +0.28(%N2 + %CO) 

Determination of Stack Gas Moisture: 

Vi = initial volume of impinger contents, ml 

V f = final volume of impinger contents, ml 

Vsgel = moisture collected in silica gel, ml 

Vi c = total volume of liquid collected in impingers and silica gel, ml 

Vwstd = volume of water vapor in the gas sample (standard conditions), ft 3 

Vwstd = 0.0472 ft3/ml x Vic 

Vmstd = volume of gas through the dry gas meter (std conditions), ft 3 

y = calibration factor, dimensionless 

Vm = volume of gas sample through dry gas meter (actual conditions), ft 3 

Pbar = barometric pressure at the dry gas meter, in. Hg 

Tm = absolute temperature at meter, oR 

H = average pressure drop across the meter orifice, in. H20 

AH 

f'bar + 

Vmstd = (17.64 oR/in. Hg) x(Vm) x(y) x ~ 3.6 

Tm 

Bwo = proportion by volume of water vapor in the gas stream, dimensionless 

Ms = molecular weight of stack gas (wet basis), Ib/lb-mole 

Vwstd B~,o= 

Vwstd + Vmstd 

Ms = Md( 1-Bwo) + 1 8(Bvvo) 

Determination of Stack Gas Velocity: 

usavg = stack gas velocity, ft/s 

Kp = 85.49 ft/s(Ib/lb-mole oR) 0 • 5 , constant 

Cp = pitot tube coefficient, dimensionless 

Tsavg = average absolute stack gas temperature, oR 

Ps = absolute stack pressure, in.Hg 

P = average velocity head of stack gas, in.H2O 

FMs;(gp—,—) 

V savg = KpCp (~) avg 

s 

P LOTHRI D\HGA99\60823-3. DOC 

nsvic Q. Ci AVn lnilr 12 
~ 

~ 

,.r 

~ 

.~ Deterniination of Stack Gas Volumetric Flow Rate: 

Qs = volumetric flow rate, dry basis (std conditions), ft 3 /min 

A = cross-sectional area of stack, ft 2 

Pstd = 29.92 in. Hg 

Tstd = 528 oR 

Qs = 60( 1-Bwo) x(Vsavg) x(A) x I Tsld 1 x l 

l Tsavg J Psld PSJ 

Determination of Particulate Concentration: 

C's = concentration of particulate matter in stack gas, dry basis, grains/std ft 3 

Mn = total mass of particulate collected, mg 

C's = 0.0154 grains/mg x(

Vms.d 

Mn J 

Determination of Particulate Emission Rate: 

Cs = particulate emission rate, dry basis, lb/lir 

C = 

(60min / hr)(QS )(C'S ) 

s 7,000 

Determination of Acceptability of Sampling Results 

1 = percent of isokinetic sampling 

An = cross-sectional area of nozzle, ft 2 

6 = total sampling time, min 

(

S

)r 0.00267(in. Hg)(ft 3) 1 

~ V r ~H 1 r m in 1 100 T l J V +"' I P +—

J 

 I 1.667 — I 

I _ (ml)( 0 R) ~~ ••m se \ bar 13.6 \ c / 

(e)(Vsa11s)(P5 )(A n ) 

Hydrogen Halide and Halogen Emissions Calculations 

Retain at least one extra decimal figure beyond those contained in the available data in intermediate 

calculations, and round off only the final answer appropriately. 

Nomenclature. Same as Method 5, In addition: 

1 BX_ = Mass concentration of applicable absorbing solution blank, mg halide ion 

(Cl-, Br-, F-)/ml, not to exceed l mg/ml which is 10 times the published analytical 

detection limit of 0.1 mg/ml. (It is also approximately 5 percent of the mass 

concentration anticipated to result from a one-hour sample at 10 ppmv HCI.) 

C = Concentration of hydrogen halide (HX) or halogen (X2), dry basis, mg/dsem. 

MHX ° Mass of HC1, HBr, or HF in sample, mg/ 

MX2 = Mass of C12 or Br2 in sample, mg. 

P LOTH RI D W G A 99\60823 -3 . DOC 

nAvIQ R. vt nvn inlr g 
~ 

-., 

SX-- = Analysis of sample, mg halide ion (CI-, Br-, F-)/ml. 

VS = Volume of filtered and diluted sample, ml. 

Average Dry Gas Meter Temperature and Average Orifice Pressure Drop. See data sheet (Figure 5-2 of 

Method 5). 

Dry Gas Volume. Calculate Vm(std) and adjust for leakage, if necessary, using the equation in Section 

6.3 of Method 5. 

Volume of Water Vapor and Moisture Content. Calculate the volume of water vapor Vw(std) and 

moisture content BWS from the data obtained in this method (Figure 5-2 of Method 5); use Equations 5- 

2 and 5-3 of Method 5. 

lsokinetic Variation and Acceptable Results. Use Method 5, Sections 6.11 and 6.12. 

Total mg HC1, HBr, or HF Per Sample. 

MHX = K Vs(SX--BX-) Eq. 26A-4 

where: 

KHCl = 1.028 (mg HCl/mg-mole)/(mg C1-/mg-mole). 

KHBr= 1.013 (mg HBr/mg-mole)/(mg F-/mg-mole). 

Total mg C12 or Br2 Per Sample. 

MX2 = Vs(SX--BX-) Eq. 26A-5 

Concentration of Hydrogen Halide or Halogen in Flue Gas. 

C =K mHX,X2/Vm(std) Eq. 26A-6 

where: 

K = 10 10-mg/mg 

Stack Gas Velocity and Volumetric Flow Rate. Calculate the average stack gas velocity and volumetric 

flow rate, if needed. 

PLOTHRID\HGA99\60823-3. DOC 

nel/tC V. LIN nvn wntlr 

.70 
CHANNEL A iNJECT 03/17/99 18:03:19 STORED TO B1N ti 27 

. ., 

DATA SAVED TO BIN tt 27 

INPUT OVERRANGE AT RT= 1.73 

EPA 26 03/17/99 18:03:19 CH= `A` PS= 1. 

FILE 5. METHOD 5. RUN 11 INDEX 1 BIN 27 

NAME PPI-1 RT PK HT BC RF 

1 0. 0.84 1090008 01 \ 

2 0. 5.79 8816 01 

TOTALS 0. 1098824 

WARNING - h1EMORY AT 5. K- UNPROTECTED CHRONATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 18:14:37 STORED TO BIN 4 28 

T5 1 

1. 

1 .43 

A I 
FILE S. METHOD 5. RUN 11 INDEX 1 BIN 27 

NAME PPI9 RT PK HT BC RF 

1 0. 0.84 1090008 01 \ 

2 0. 5.79 8816 01 

TOTALS 0. 1098824 

WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 18:14:37 STORED TO BIN 4 28 

ER 0 

DATA SAVED TO BIN tt 28 

EPA 26 

FILE 5. METHOD 5 

NAME PPM 

CL- 0.6 

TOTALS 0.6 

03/17/99 18:14:37 CH= "A" PS= 1. 

RUN 12 INDEX 1 BIN 28 

RT PK HT BC RF 

1.43 8408 01 14013.333 

8408 ' J 

WARNING - MEIIORY AT 7. K- UNPROTECTED CHROMATOGRAMS wILL BE REPLACED 

ZZ 
WARNING - MEMORY AT 7. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 18:25:55 STORED TO BIN tk 29 

ER 0 

DATA SAVED TO BIN 9 29 

EPA 26 03/17/99 18:25:55 CH= "A" PS= 1. 

FiLE 5. IIETHOD 5. RUN 13 iNDEX 1 BIN 29 

NAME PPP1 RT PK HT BC RF 

1 0. 0.82 769549 02 

CL- 2.354 1.53 428339 02 181962.05 

3 0. 1.76 73635 02 

4 0. 1.96 47757 03 

5 0. 3.1 14416 01 f~ 

6 0. 5.21 104305 02 J 

7 0. 5.49 1030611 03 

TOTALS 2.354 2468612 

WARNING - MEMORY AT 7. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED 

CHANNEL A INJECT 03/17/99 18:37:14 STORED TO BIN 4 30 

15 1 

Z3 

T i A M ": 
i 

NAME PPM RT PK HT BC RF 

~ 1 0. 0.82 829907 01 

; 2 0. 5.63 1032320 01 

, ; 

R~ TOTALS 0. 1862227 ` 

t ~ 

WARNING - MEMORY AT 0. K- UNPROTECTED CHROIIATOGRAt9S WILL BE REPLACED 

. k ..:; 

CHANNEL A INJECT 03/17/99 18:48:32 STORED TO BIN tt 31 

~ 

~ 

~ 

3 

~ ER 0 

DATA SAVED TO BIN 4 31 

~ 

EPA 26 

~ 

~ 

FILE 5. METHOD 5. 

~ NAME PPM RT PK HT BC RF 

" 1 0. 0.82 862453 02 

~ CL- 2.11 1.55 362755 02 171921 .643 

3 0. 1.77 79896 02 

; 4 0. 1.96 40920 03 V 

~ 5 0. 3.1 14589 01 

6 0• 5.2 188293 02 

7 0 • 5.48 1032643 03 

TOTALS 2.11 2581549 

~ 

~ 

uARti 1 t1C - MEtt10RY AT 0 K - UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

03/17/99 18:48:32 CH= 'A" PS= 1. 

RUN 15 INDEX 1 BIN 31 

7-4 
v,. . V , '1. 1 - i.11 - r, 

FILE S. METHOD 5. RUN 1 INDEX 1 BIN 38 

NA('1E PPM RT PK HT BC RF 

1 0. 0.82 875104 01 - ~ 

CL- 2.009 ~~ ` 1.52 336541 01 167516 .841 

TOTALS 2.009 1211645 

WARNING - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS W1LL BE REPLACED 

CHANNEL A INJECT 03/18/99 09:58:30 STORED TO BIN tt 39 

ER 0 

DATA SAVED TO BIN 4 39 

EPA 26 03/18/99 09:58:30 CH= 'A' PS= 1. 

FILE 5 METHOD 5. RUN 2 INDEX 1 BIN 39 

NAME PPM RT PK HT BC RF. 

:

, S 

0. 0.82 886085 02 

3.302 1.57 704968 08 213497.274 

0. 1.79 18717 05 

0. 1.99 24773 05 

0. 3.14 15527 01 

0. 5.22 120925 02 

0. 5.5 1029897 03 

1 

CL3 

4 

5 

6 

7 Z$ 

TOTALS 3.302 2tt00892 
CHANNEL A INJECT 03/18/99 10:15:19 STORED TO BIN 4 42 

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EPA 26 03/18/99 10:15:19 CH= 'A' PS= 1. 

FILE 5. METHOD 5. RUN 1 INDEX 1 B1N 42 

NAME PPM RT PK HT BC RF 

1 0. 0.82 890723 02 

CL— 3.283 1.56 699211 08 212979.185 -~ 

3 0. 1.78 18635 05 

4 0. 1.98 14024 05 

5 0. 3.11 15292 01 ~ 

6 0. 5.44 1037989 01 

TOTALS 3.283 26"5873 

WARNING — MEI90RY AT 0. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/18/99 10:26:37 STORED TO BIN U 43 

r5 I 

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CHANNEL A INJECT 03/17/99 19:11:98 STORED TO BIN tt 33 

ER 0 

DATA SAVED TO B1N 4 33 

EPA 26 03/17/99 19•11:08 CH= "A" PS= 1. 

FILE 5. t9ETHOD 5. RUN 17 INDEX 1 BIN 33 

NAt9E PPM RT PK HT BC RF 

1 0. 0.82 867344 02 

CL- 2.098 1.55 359813 02 171503.019 ` 

3 0. 1.77 83477 02 

4 0. 1.97 42072 03 ~ 

5 0. 3.1 16644 01 

6 0. 5.47 1032409 01 

TOTALS 2.098 2401760 

WARNING - MEMORY AT 1. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 19:22:26 STORED TO BIN it 34 

T6 0 •82 

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~ 

~ ER 0 

DATA SAVED TO BIN 4 35 

~ 

~

~ 

INJECT 03/17/99 19:33:44 STORED TO BIN tt 35 

.. ~ 

\~ FILE 5. ;•ILTHOij 5. RUN 18 1 NDEX 1 E.: I(a 34 

NAME PPM RT PK HT BC RF 

~ 1 0. 0. 82 8 5? ^' 2 01 

? 0. 3 .08 6031 01 

3 0. 5.16 2007 6 02 

4 0. 5.64 1023481 03 

~ TOTALS 0. 19018"1 

,. ~ ~ . .~ 

WARNING — MEMORY AT 0. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

~ INPUT OVERRANGE AT RT= 1.48 

EPA 26 03/17/99 19:33:44 CH= 'A' PS= 1.. 

~ F1LE S. METHOD 5. RUN 19 1NDEX 1 B1N 35 

!!! 

NAME PPh: ~ RT PK HT BC RF ~ 

1 0. C\ 0.82 839685 01 

CL— 2.857 1.51 57086t A1 199811 _457 
i ~ CHANNEL A INJECT 03/18/99 09:47:12 TORI::ll IU t31N u iu 

~ 

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DATA SAVED TO BIN 4 38 

INPUT OVERRANGE AT RT= 1.49 

EPA 26 03/18/99 09:47:12 CH= 'A' PS= 1. 

FILE 5. METHOD 5. RUN 1 INDEX 1 BIN 38 

NAME PPM RT PK HT BC RF 

1 0. s1 0.82 875104 01 / ✓ 

CL- 2.009 \~~ V 1 .52 336541 01 167516 .841 

TOTALS 2.009 1211645 

WARNING - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/18/99 09:58:30 STORED TO BIN tt 39 
i 

' NAME PP1-1 RT PK HT BC RF 

~ 1 0. 0.82 890723 02 

~ CL— 3.283 1.56 69921 1 08 212979 . 185 

3 0. 1.78 18635 05 

4 0. 1.98 14024 05 

~ 5 0. 3.11 15292 01 

6 0. 5.44 1037989 01 

~ TOTALS 3.283 2675873 

INJECT 03/18/99 10:26:37 STORED TO BIN tt 43 

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a 

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~ FILE 5 

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03/18/99 10:26:37 CH= 'A' PS= 1 

RUN 2 INDEX 1 BIN 43 

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0 . J 0 .82 872405 01 

2.9 ~ 1.51 583397 01 201171 .494 

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Palmetto Brick Co. 

Readings for Emmissions testing 

4-Mar-99 

Kilni 

~ G Production 30 cars per day ~ 

Type of Brick Old Marlboro modular ~ 1 

Type of Body Red ~) ~ 

Fired weight 3.47 Ibs. 

Brick per Car 5400 brick per car 

Kiln 2 

Production 30 cars per day 

TXpe of Brick Ship Ballast modular 

Type of Body Brown 

Fired weiglit 3.26 Ibs. 

Brick per Car 5400 brick per car 

e 

3z 
PUHG1 1/,\,. ol wn--1 I 

I'A 1~ m('K C "01NIVANY 0793 

01T.11A I F:I,) Fly 

INC 

i HUX 4 30 

. ,I 11'. 1 JAW, S() ~ l I I I CAI 1( X. INA 295;)0

~~--~ Ir,~~~ 

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( -,()MPA NY c 

mm ~.- 

~o c) I-HOM 

I \,K? 

7 7 7.7 

OUAN I ITY AMo()r%i I 

;~ IN,,J d r- (~°1 - -- ~~~-- ~ `. l(l ~ 1 .. 0 ~~ c 

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Imow1pd(j r? ir-cnipt -)I lliis order 

IMPOIITANT 

S lid. 1;1, 1. rl ~ I yoU Wills ~A 

w oldof rimubpt k-n correspoiidaricl?. Ilivoices, Bills of Larlitiq, elc, 

~~IZ- ~ S s- ~o~ { t) 

4)o 1-1 

r-Y 
Palmetto Brick Co. 

Readings for Emmissions testing 

4-Mar-99 

Test 1 Time Time Time Time Tirne 

O` ' a oC.,.. 9' a w. ' 0 4-- 

L#1 Tem 198(, l o l / 

L#2 Tem U ;;2 c) O 

L#1 Gas — Lq 02, LL 00 CF 

0,000 CF 

Gal. 

L#2 Gas 2 0 (o 

Oil For Both D33 S a S 

~ ~ 

i 

~ 

; 

00 CF 

0,000 CF 

Gal. 

i 0 

Test 2 Time Time Time Time Time 

D"do.. /o ,3 s ~~ / o:s o ~~ : oS"a— /.•ao" 

L#1 Tem /5? 

L#2 Temp U o20 `Y,3 ~) 

L#1 Gas 00 CF 

0,000 CF 

Gal. 

Lv s Sq 

L#2 Gas 2 `I 

Oil For Both 3 1S ` o 3 3 

Test 3 Time Tirne Time Time Time 

Z:OV /Z:/b 2:30 r+ 

L#1 Tem o o~ C~ o'Z a 0 D 

L#2 Tem O o K 2 U zfS o?D 

L#1 Gas '] 00 CF 

0,000 CF 

Gal. 

(0s

. 

 6Gl I 

L#2 Gas r7 t. $ 9 L-1 7(c 9 . 9 

Oil For Both y C33 S Z ~ L 0 3 32 2 

Jop Goodin 

01, 

00 CF 

0,000 CF 

Gal. 

00 CF 

0,000 CF 

Gal. 

3 4 
+ 

•i 

, • 

. 

Palmetto Brick - Co. 

Readings for Emmissions lesting 

~hnluhc ~ +C Me«S , rt~J ~,~ 4-Mar-99 

Scrubber pfE• ~ c-I cyelv 

Test 1 Time Time Time Time Time 

9 '. 05 '; Zo 5 ~ 

Photohelic 1,, 1,0 

Hertz 31 .9 Q, /.(o ~ ~ 5 

Test 2 Time Time Time Time Time 

l6:20 !0;' S o: 56 I;oJ I I; Za 

Photohelic l. (o ~ , j , ,4 I ~ Z 

Hertz 

Test 3 Time Time Time Tirne Time 

l(: ~ o ;" ILOO ', IS 1Z; 3 

Photohelic I, S I, 0 

Hertz 37.4o 33. q 37.5 

pf 

~(Oq& 

s/4l`N 

Kevin Mackey 

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Iio i ~ r` Sold Frorn(, ~(~ G3 7 : i{iALLF3 Uf ~t CF~ UB$f _I C::, ,.; DCRI;LI_EY (yUF1ftRY ~ 7 ~~,. 

~,•~..~~. PC 2943f; 

tiy }1 . 9e ',, i: ~13'- 7 5~ f?i..yiCry 

~ r 1 , 1 i•, ^- I 

1/13/9a Tirri ~ ho N~ /1/9E3 I I sCN(pr cl ~ hl meril lnform~tlofi' 

ier: RCQU I~~~ .- IIALLS OF ~ CIM .NTS 

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Toda , n1► ~ r, ~r tTo Dale,f, ,.~ ,, Wei hl MeasUrel"enls ,:•, ;,=~ ; .. i 1 Cash Sale , 

!: G@0 c^ ~ ;A9Jili~ !fii'!' ~0:0.0'~ ' VGros ~ ;yld ~ fbGOl ~"~ 40~03~'ti~)'i'.fh, ~ ., y ' ~~I$'l, rf ; ~ ' ;•~.,~ ` in 

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fiict Number: 078 q y~ 1 I" r Nel: :.503V~N' ~ 2S~ .~ NauIS i„n ~(~~) i ' ~'~' jll .\r, ,~ Ir.. ili: r.w tj.:-rl,...•,. :,:>,,,. ,. . I!'' }; '•-fl w ►• .~ ? ~ h.t+nMlnectidBr 1 

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03/17/99 16:10:18 STORED TO BIN 4 17 

~ 

_. 

. ~ 

T6 0 •82 

# 

...1 

~ 

:X 

~ 

~ ER 0 

DATA SAVED TO BIN 4 17 E 

~ s 

~ INPUT OVERRANCE AT RT= 1.6 

EPA 26 03/17/99 16:10:18 CH= 'A' PS= 1. 

~ 

FILE S. METHOD S. RUN 1 INDEX 1 CALIB B1N 17 

NAME PPM RT PK HT BC RF 

~ 1 0. 0.82 851952 01 

CL— 1. 1.52 87680 01 ~ 

~ TOTALS 1. 939632 

~ WARN I NG — I9EI-tORY AT 1. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

~ CHANNEL A INJECT 03/17/99 16:21:35 STORED TO BIN tt 18 

T5 1 

~ T6 0 •82 

50 31 

~ 
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'^ 

~ 

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2,7 

DATA SAVED TO BlN 4 18 

~~ 

~~ lMpUT OVEBRANCE AT RT= 1.47 

EPA 26 03/17/99 16:21:35 CH= ^A^ PS= 1. 

F|LE 5. METHOD S. RUN 2 lMDEX 2 CALlB BlN 18 

NAME PPM RT pK HT BC RF 

| ~ 1 0. 092 860069 01 

CL- 1.5 1.5 224357 03 

3 0. 2.91 10990 02 -

7 

4 0. 3.07 10336 03 

5 0. 5.87 10881 01 /-7) 

TOTALS 1.5 1116633 

WARNlNG - MEMOBY AT 2. K - UNPBOTECTED CHROMATOGRAM3 WlLL BE REPLACED 

~~ . CHANNEL A lMJECT 03/17/99 16:32:53 STORED TO BlN U 19 

- -- 

~~ )\ ~~ `/ 
CHANNEL A INJECT 03/17/99 RTnPFn Tn RIN 4 19 

ER 0 

DATA SAVED rO BIN 4 19 

T 

INPUT OVERRANCE AT RT= 1.48 

EPA 26 03/17/99 16:32:53 Cli= *A" PS= 1. 

FILE 5. BIN 19 METHOD 5. RUN 3 INDEX 3 CALIB 

NAPIE ppil RT PK HT BC RF 

1 0. 0.82 846221 01 

CL- 2. 1.51 324013 01 

3 0. 3.07 14227 01 

TOTALS 2. 1184461 

WARN I NG - MENORY AT 5. K - UNPROTECTED CHPOMATOGRAMS I LL BE REPLACED 

CHANNEL A INJECT 03/17/99 16:44:11 STORED TO B I 'a tt 20 

T T5 I 

5 

T6 0 .82 

39 
' WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

~ 

CHANNEL A INJECT 03/17/99 16:44:11 STORED TO BIN # 20 

~ T5 1 

:.~ 

T6 0 •E 2 

.t 

9 

f ..1 

1 

; 

~ 

1 

,.~ 

5.90 

~ ER 0 

~ DATA SAVED TO BIN # 20 

-~ 

INPUT OVERRANGE AT RT= 1.48 

EPA 26 03/17/99 16:44:11 CH= 'A" PS= 1. 

~ FILE 5. METHOD 5. RUN 4 INDEX 4 CALIB BIN 20 

~ NAME PPM RT PK HT BC RF 

1 0. 0.82 849995 01 ~ 

~ CL- 2.5 1.51 466875 01 

3 0. 5.9 7593 01 C 

~ TOTALS 2.5 1324463 

~ 

~ WARNING - I9EMORY AT 7. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

~ 

~ 

CHANNEL A INJECT 03/17/99 16:55:30 STORED TO BIN 4'.1 

T5 1 

T6 0 •82 

1 C • 

40 
~ WARNING - 14EMORY AT 7. K- UNPROTECTED ('HROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 16:55:30 STORED TO BIN tt 21 

ER 0 

DATA SAVED TO BIN ri 21 

INPUT OVERRANGE AT RT= 1 .48 

EPA 26 03/17/99 16:55:30 CH= 'A' PS= 1. 

FILE 5. t9ETHOD 5 RUN 5 INDEX 5 CALIB BIN 21 

NAME PPt9 RT PK HT BC RF 

1 0. 0.82 846731 01 ' 

CL- 3. 1.51 615800 01 

3 0. 5.84 16862 01 , 

TOTALS 3. 1479393 

COEFFICIENTS OF LEAST SQUARES FIT TO A QUADRATIC EQUATION 

FILE ENTRY KA KB KC 

1 0 .1934^+05 0 .1824^+06 - . 108^+06 

WARNING - MEI10RY AT 1. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

.1 `~ ` CHANNEL A INJECT 03/17/99 17:06:48 STORED TO BIN 1t 22 

Tr,S 
- h 

•-.i 

NARN 1 NG - 

 MEMORI AT 1. K UNPROTECTED CHI20.lATOGRAMS W I LL BE REPLACED 

~ 

~ 

CHANNEL A INJECT 03/17/99 17:06:48STC'RED TO BIN # 22 

~ T5 1 

=~ 

T6 0 • 82 

5 

 .~ 

T 

[{ 

-~ E R 0 

~ DATA SAVED TO BIN # 22 

~ 

~ 

INPUT OVERRANGE AT RT= 1.48 

EPA 26 03/17/99 17:06:48 CH= 'A' PS= 1. 

.~ F1LE 5. METHOD 5. RUN 6 lNDEX 1 BIN 22 

~ ~ NAME PPM RT PK HT BC RF , 

~ 1 0. 0.82 850856 01 ~ ~ CL- 1.946 1.51 320075 03 164478 .246 

TOTALS 1.946 1170931 

~ 

WARN I NG - P1EM0RY AT 3. K- UNPROTECTED CHROIrIATOGRAMS WILL BE REPLACED 

~ 

CHANNEL A INJECT 03/17/99 17:18:06 STORED TO BIN tt 23 

1 1 T5 1 

T6 0 • 82 

%-: 

qZ 
~-~ 

'. . ~ 16 0 . o c. 

~ 

~ 

~- 

s 

h 

P 

...j: 

;5 

~ 

..~ 

`3 

~ a ~ 

~ 

~ 

_.~ 

~ 

.~ 

I 

~ 

`hn 

:3 

ER 0 

DATA SAVED TO BIN tk 23 

INPUT OVERRANGE AT RT= 1.59 

EPA 26 03/17/99 17:18:06 CH= 'A" PS= 1. 

FILE 5. METHOD 5. RUN 7 I NDEX 1 BIN 23 

NAME PP(9 RT PK HT BC RF 

1 0. 0.82 848747 01 

CL— 0.992 r 1.51 91936 01 92677.419 '? 

. 

TOTALS 0.992 940683 

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 17:29:25 STORED TO BIN tt 24 

T5 1 

ff-Irl. 

43 
.-~-- - - 

AT 6. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

j 

~ 

CHANNEL A INJECT 03 /17/S'9 17:29:25 STORED T O BIN 4 24 

~ TS 1 - 

~ 

T6 0 •82 

. 1 

J 

i , > 

~ ~ 

; ER 0 

~ DATA SAVED TO BIN tt 24 

Y 

INPUT OVERRANGE AT RT= 1.57 

1 

EPA 26 03/17/99 17:29:25 CH= 'A' PS= 1. 

, ~ FILE 5. METHOD S. RUN tt INDEX 1 BIN 24 

1 NAME PPM RT PK HT BC RF ` 

1 0. 0.82 859661 01 ~ 

~ 

t~ TOTA S L 0. 859661 

.~ 

~ WARNING - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED 

~ 

CHANNEL A INJECT 03/17/99 17:40:43 STORED TO BIN tt 2 5 

-~ T 5 1 

► 

T6 0 82 

.~ 

44 
WARN I NG — P1F.I90RY AT 0. K — UNPROTECTED CHROIIATOGRAt9S WILL BE REPLACED 

~ 

.~ 

CHANNEL A INJECT 03/17/99 17:40:43 STORED TO BIN # 25 

T5 1 

t 

= 

T 6 0 • 82 

1.49 

I E 

f 

~ 

I 

1 j 

~.~ 

5.84 

ER 0 

~1 DATA SAVED TO B1N tt 25 

.~ INPUT OVERRANGE AT RT= 1.46 

EPA 26 03/17/99 17:40:43 CH= 'A' PS= 1. 

FILE 5. hIETHOD 5. RUN 9 INDEX 1 BIN 25 

~ NAME PPI-i RT PK HT BC RF \ 

1 0. 0.82 850552 01 ' 

CL— 2.028 ` ~ 1.49 341443 03 168364 .234 ~ 

3 0. ~~ 5.84 8745 01 

TOTALS 2.028 1200739 

~ 

WARNING — MEI-tORY AT 2. K— UNPROTECTED CHROl9ATOGRAMS WILL BE REPLACED 

~n 

CHANNEL A INJECT 03/17/99 17:52:01 STORED TO B1N tt 26 

i. ~ . T5 1 

T6 0 •82 

1.49 

~.; 

.~ 

~ 

2.96 .07 

46' 
CHANNEL A I NJECT 03/ 17/99 17 : 52: 01 S'1"ORED TO B I N 4 26 

DATA SAVED TO BIN tt 26 

INPUT OVERRANGE AT RT= 1 .46 

,EPA 26 03/17/99 17:52:01 CH= "A" PS= 1. 

FILE 5 METHOD 5 RUN 10 INDEX 1 BIN 26 

NAI9E 

1 

CL4 

5 

TOTALS 

PPt9 RT 

0. 0.82 

2.039 , ^. 1 .49 

0. 2.96 

0. % 3.07 

0. 5.82 

Q . M 

PK HT BC RF 

851560 01 

344256 01 168835.704 

11751 02 

9793 03 

8526 01 

1225886 

; f . i 

WARNING - I9EMORY AT 3. K- t1NPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A 1NJECT 03/17/99 18:03:19 STORED TO BIN U 27 

y(, 
[R N 

DATA SAUED TO GlN 4 118 

~ 

. 

~ 

~ 

~ 

|NPUT OVERRANCE AT RT= 1.34 

EPA 26 03/17/99 11:51:00 CH= ^A' PS= 1. 

FlLE 5. HETH0D S. RUN 4 INDEX 4 CALI8 BlN 118 

NAME PPH RT PK HT BC RF 

1 0 0.81 313059 02 

F- 4. 1.04 595309 03 / 

3 0. 1.81 216299 01 ^ 

. 

4 0. 3.28 10354 01 

5 0. 4.54 7878 02 

6 0. 4.84 1026131 03 

TOTALS 4 2169030 

WARN\NC - HEHORY AT 2. K - UNPROTECTED CHROHATOCRAHS W|LL BE REPLACED 

CHANNEL A |NJECT 03/17/99 12:02:18 STOBED TO 8IN 4 \\Y 

\ ~ 82 
`. 

~ ? 

r.~...~,' - - ---- •L. . ~ sa.rrt.er~..x•-..__... .., . . , . 

CHANNEL A INJECT 03/17/99 12-`:02:1ts STORED TO B1N ii 119 

: . 

i ! 

e"a 

a 

j 

~ 

~ 

` ER 0 

-~ DATA SAVED TO B I N 0 1 1'% 

?~ 

 INPUT OVERRANCE AT RT= 1.34 

. ~ 

EPA 26 03/ 17/91? 12: 02: 18 CH= "A" PS= 1. 

, 

i FILE 5. I-tETHOD 5. RUN 5 1 NDEX 5 CAL I B B 1 N 119 

~ NAME PPf-I RT PK HT BC RF 

~ 1 0. 0.81 309237 02 

~. 

. ~ 

~ 1 04 7^7^$5 03 L ~ ,r 

3 .0. 1 .rs2 2]774 ~~ 01 

~ 4 0. 4.56 7439 02 

S 5 0. 4.85 1025157 03 ~ 

~ 

] TOTALS 5. 22rs6n6'i 

~ COEFFICIENTS OF LEAST SOUARES F1T TO A OUADRATIC EOUATfON 

1 FILE ENTRY Kri KB KC 

~ 1 0 1 1 k6, '+04 0. 1239^+06 0.7786^+05 

= ~. wARN i NC — f•IEI•1O-Y aT ~4 r— UNPROTECTED CHR01'1ATOCRAI•IS w E LL BE REPLACED 
r 

; DATA SAVED TO B I N 4 120 

..i 

t ; 

' j INPUT OVERRANCE AT RT= 1.34 

~ 

~ 

- 228u869 

COEFFICIENTS OF LEAS'i SQUARES F1T TO A QUADRATIC EQUATION 

FILE ENTRY KA KB KC 

~ 1 0.1186^+04 0.1239^+06 0.7786^+05 

WARNINC - MEMORY AT 0. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED 

CHANNEL A INJECT 03/17/99 12:13:37 STORED TO BIN # 120 

EPA 26 03/17/99 12:13:37 CH= 'A' PS= 1. 

Y 

~ 

FILE 5. METHOD 5. RUN 6 INDEX 1 BIN 120 

~ NAME PPM RT PK HT BC RF 

1 

0. 0.81 310179 02 

~ F - 2.819 1.05 436629 03 154888 .022 

~ 4 0. j t 1 1.82 217557 01 

0. 4.54 7097 02 

5 0. 4.84 1024599 03 

~ TOTALS 2,819 1996061 

K~ 

4a 

. ~ s 

.m WARN 1 NC - MEMORY oT 
; ~ 

: 

f 

-~ 

i 

, 

~ ~ 

~. 

i 

r 

a 

~ 

:

Ir 

I 

-~ „ 

:E 

~ 

~ 

2 

~ 

~ 

~ 

~ 

,~. 

~ 

it 

~ 

RiC 

WARNING - MEMORY AT 1. K- UNPROTECTED CHROMATUGRAMS WILL 6E REPLACED 

CHANNEL A INJECT 03/17/99 12:24:55 STORED TO BIN lk 121 

ER 0 

DATA SAVED TO BIN 4 121 

INPUT OVERRANGE AT RT= 1.35 

EPA 26 03/17/99 12:24:55 CH= "A" PS= 1. 

FILE 5. METHOD 5. RUN 7 INDEX 1 BIN 121 

NAME PPM RT I-1: HT BC RF 

1 0. 0.81 347808 01 

F- 0.855 1!~ 'v' 1.06 184733 01 216062 .378 4D 

3 0. ° 1.82 219155 01 

4 0. 4.54 6877 02 

5 0. 4.84 1024758 03 

TOTALS 0.855 1783331 

WARNING - MEMORY AT 2. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 12:36:12 STORED TO BIN Jt 122 50 

T5 1 
W1LL BE PEPLACED 

CHANNEL A 1NJECT 03/17/99 12:36:12 STORED TO BIN.tt 122 

ER 0 

DATA SAVED TO BIN 4 122 

INPUT OVERRANGE AT RT= 1.36 

EPA 26 03/17/99 12:36:12 CH= 'A' PS= 1. 

FILE 5. METHOD 5. RUN 8 INDEX i BIN 122 

NAME PPM RT PK HT BC RF ~ 

1 0. 

1 

0.81 348907 01 ~ 

F- -.039 1.13 72992 01 1. 

3 0. 1.82 212821 01 

4 0. 4.54 6827 02 

5 0. 4.84 1026623 03 

TOTALS -.039 1668169 

WARNING - MEMORY AT 1. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED 

CHANNEL A INJECT 03/17/99 12:47:30 STORED TO BIN #t 123 

r5 1 

.04 

1 .82 SI 
i, . • . 1 

:'~HANNEL A INJECT 03/17/99 12:47:30 STORED TO BIN U 123 

7~,9ATA SAVED TO B I N tt 123 

<~ 

~. 

E ~ 

INPUT OVERRANGE AT RT= 1.34 

4 PA 26 03/17/99 12:47:30 CH= "A" PS= 1. 

~ ILE 5. METHOD 5. RUN 9 INDEX 1 BIN 123 

iIAME ;a~ PPM RT PK HT BC RF l~ / 

a " 

1 0. 0.81 309821 02 

r F- 2.642 1.04 413563 03 156533.939 

~ 3 0. 1.82 217904 01 

4 0. 4.54 7640 02 

5 0. 4.84 1027422 03 

~TOTALS 2 .642 1976350 

~ 

UWARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

~ 

t~ CHANNEL A INJECT 03/17/99 12:58:48 STORED TO BIN tt 124 

~ ~ 
_,. 1 

i 

.. ~i 

•~: 

; WARNING - MEMORY AT 5. K- UNPROTECTED i,riROMATOGRAMS W1LL BE REPLACED 

CHANNEL A INJECT 03/17/99 12:58:48 STORED TO BIN # 124 

DATA SAVED TO BIN tt 124 

INPUT OVERRANGE AT RT= 1.34 

EPA 26 03/17/99 12:58:48 CH= 'A" PS= 1. 

FILE 5. METHOD 5. RUN 10 INDEX 1 BIN 124 

NAME PPM RT PK HT BC RF 

1 0. 0.81 307888 02 

F- 2.679 1.04 418451 03 156200.572 

3 0. 1.82 ~

_. .. 217147 01 t 

4 0. 4.54 8019 02 

5 0. 4.84 1027293 03 

TOTALS 2.679 1978807 

WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 13:10:06 STORED TO BIN 4 125 -5-3 
=3 

WARNING - MEMORY AT 5. K- UNPROTECTED CHRUMATOi, ' 

• r P4+ 

. .q:~'f<.. 

+ ~ , .+ y • ~ . 

CHANNEL A INJECT 03/17/99 13:10:06 STORED TO BIN 

ER 0 

DATA SAVED TO B I N tt 125 

EPA 26 03/17/99 13:10:06 

FILE 5. METHOD 5. RUN 11 INDEX 

NAME PPM RT PK H•T BC RF 

1 0. 0; 81 299768 02 

F- 7.675 1.04 1098941 02 143184.538 

3 0. 1.47 1120856 02 

4 0. 1.85 342915 02 

5 0. 2.83 130653 03 

6 0. 3.26 10666 01 

7 0. 4.56 11031 02 

8 0. 4.88 1024503 03 

TOTALS 7.675 4039333 

WARNING - MEMORY AT 5. K- UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED 

CHANNEL A INJECT 03/17/99 13:21:25 STORED TO BIN t 126 

T5 1 

54 

n~ 

.81 

CH= "A" PS= 1. 

1 BIN 125 

o~ 

~ 

✓'-.~ . 

1 d7 
CHANNEL A INJECT 03/17/99 14:51:50 STORED TO BIN lt 6 

ER 0 

DATA SAVED TO BIN 4 6 

i . , 

-; 

,s 

.. ~. 

3 ; 

•a 

-~~ 

9 ~ 

! 

•,~ 

.;~

. 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

r ~

~ 

Y rl 

Y 

~ 

INPUT OVERRANGE AT RT= 1.29 

EPA 26 03/17/99 14:51:50 CH= 'A' PS= 1. 

FILE 5. METHOD 5. RUN 16 INDEX 1 B1N 6 

NAME PPM RT PK HT BC RF 

~ 

1 0. 0.81 340024 01 F- 1.683 1.05 289851 01 172222.618 

3 0. 1.49 1115117 02 

~ 

4 0. 1.79 175837 03 

5 0. 2,8 23408 01 

6 0. 4.54 .9427 02 

7 0. 4.82 1024761 03 

TOTALS 1.683 2978425 

WARNING - MEMORY AT 7. K- UNPROTECTED CHRO14ATOGRAMS WiLL BE REPLACED 

CHANNEL A INJECT 03/17/99 15:03:08 STORED TO BiN tt 7 SS 
;HANNEL A INJECT 03/17/99 13:32:43 STOREll TO BIN it 127 

~ S 

~ 

! 

~ 

`{ 

D 

i 

J 

~ e 

i 

; 

~ ER 0 

~ DATA SAVED TO B 1 N Jk 127 

S 

EPA 26 

~ FILE 5. METHOD 5. 

-.~ 

03/17/99 13:32:43 

RUN 13 INDEX 

CH= 'A" PS= 1. 

1 BIN 127 

; NAME PPM RT PK HT BC RF 

~ 1 0. 0.81 301216 02 

-, F— 7.576 1.04 1084933 02 143206.617 

3 0. 1.48 1114912 02 

4 0. 1.86 296901 03 

5 0. 2.83 89237 01 

a 6 0. 3.26 12103 01 

~ 7 0. 4.56 10318 02 

8 0. 4.89 1026313 03 

~ TOTALS 7.576 3935934 

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 13:44:01 STORED TO BIN # 128 

15 1 

1 .47 

: .+ 

~ 

56 
03/17/99 15:03:08 CH= 'A' PS= 1. 

RUN 17 INDEX 1 BIN 7 

RT PK HT BC RF 

0.81 339563 

1.05 278259 

1.49 1084960 

1.79 112693 

2.8 ?1897 

4.54 7213 

4.82 1025949 

2870535 

01 

01 174675.874 

02 

03 

01 

02 v 

03 

.-. 

- ~ ' • 

~ CHANNEL A 

~ 

.~ 

--~. 

:.s ., 

--, 

ER 0 

DATA SAVED TO BIN tt 

a 

~ 

INPUT OVERRANGE AT RT= 

~ 

r EPA 26 

~ FILE 5. METHOD 5 

;< 

NAME PPM 

1 0. 

~ ~

F— 

3 

1 .593 

0. 

4 0. 

5 0. 

~ 6 0. 

7 0. 

~ TOTALS 1.593 

7 

1 .3 

INJECT 03/17/99 15:03:08 STORED TO BIN 4 7 

~

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

~ 

~ CHANNEL A INJECT 03/17/99 15:14:26 STORED TO BIN 4 8 

TS 1 

1.03 

~ 57 
5, 4 272 

ED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 13:55:19 STORED TO BIN 4 1 

ER 0 

DATA SAVED TO BIN 4 1 

03/17/99 13:55:19 CH= 'A' PS= 1. 

METHOD 5. RUN 15 INDEX 1 BIN 1 

PPM RT PK HT BC RF 

0. 0.81 299787 02 ~ 17 

7.694 1.04 1101728 02 143193 .137 ,. 

0. 1.48 1112608 02 

0. 1.86 289461 03 

~ 5 0. 2.82 860 /9 01 

6 0. 4.56 8791 02 

~ 

~ 7 0. 4.89 1024467 03 

~ TOTALS 7.694 3923221 

~ WARNING - MEMORY AT 6. K- UNPROTECTED CHROMATOGRAMS W[LL BE REPLACED 

~ RN=12 

CHANNEL A INJECT 03/17/99 14:06:37 STORED TO BIN # 2 571 

~ T5 1 

~ 

EPA 26 

~ FILE 5 

~ NAME 

.~ 1 

F3 

4 
• i . 

.; ~ 

~ 

'3 •,. ~ 

~a 

i s 

_., R 

,1 

; 

~ 

Y' 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

' 

.~ ~ 

r 

7 0. 4.89 1024467 03 

TOTALS 7.694 39232?I 

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

RN=12 

CHANNEL A INJECT 03/17/99 14:06:37 STORED TO BIN # 2 

ER 0 

DATA SAVED TO BIN tt 2 

INPUT OVERRANGE AT RT= 1.3 

EPA 26 03/17/99 14:06:37 CH= 'A' PS= 1. 

FILE 5. METHOD 5. RUN 13 INDEX 1 BIN 2 

05 1IK 

NAME PPM RT PK HT BC RF 

1 0. 0.81 334587 01 

F— 1.761 1.05 2997E4 01 170235.094 

3 0. 1.5 1135848 02 —, — 

4 0. 1.86 320741 02 

5 0. 2.82 73997 03 ~ W 

`x 

6 0. 4.54 5722 02 

7 0. 4.84 1026555 03 

TOTALS 1.761 3197235 

WARN I NG — MEI-IORY AT 6. K— UNPROTECTED CHROMATOGRAI9S WILL BE REPLACED 

Sq 
CHANNEL A IN.IECT 03/17/99 14:17:55 STORED TO BIN 4 3 

ER 0 

DATA SAVED TO BIN # 3 

INPUT OVERRANGE AT RT= 1.53 

EPA 26 03/17/99 14:17:55 

F1LE 5. METHOD 5. RUN 14 INDEX 1 

NAME PPM RT PK HT BC 

1 0. 0.82 703053 01 

2 0. 2.42 202032 01 

3 0. 4.62 1015563 01 

TOTALS 0. 1920648 

CH= ' A' PS= 1 . 

BIN 3 

RF 

V 

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A iNJECT 03/17/99 14:29:14 STORED TO BIN tk 4 

T5 1 

0 

1 .42 

(s o 
~ ~ 

..~ 

, 

~ 

;z 

. x 

~ 

; 

, 

l. 

s 

-,.. 

n 

~ 

•~ i 

~ 

•1 

~ 

~ 

., 

~ 

-~ 

r a 

~ 

~ 

Y~ 

~ 

~ 

;. 

~ 3 

'2 0 . 2 .42 202fo62 01 

3 0. 4.62 1015563 01 

TOTALS 0. 1920648 

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 14:29:14 STORED TO BIN 4 4 

ER 0 

DATA SAVED TO BIN 4 4 

EPA 26 03/17/99 14:29:14 CH= "A" PS= 1. 

FILE 5. METHOD 5. RUN 15 INDEX I BIN 4 

NAME PPM RT PK HT BC RF 

1 0. 1.42 8397 01 

2 0. 6.1 110690 01 

TOTALS 0. 1 ~ 9087 

WARNING — MEMORY AT 7. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 14:40:32 STORED TO BIN tt 5 

m 

lv k 
/99 14 : 40: 32 :;TOhEn rT0 B I N ti 

A 

. ~ 

r ..}; :s 

.~, 

~ 

:s 

~ ,x 

..~ 

> 

~ ER 0 

- DATA SAVED TO BIN 4 5 

-r 

'L 

k INPUT OVERRANGE AT RT= 1.35 

~ 

~ 

,. EPA 26 03/17/99 14:40:32 CH= 'A' PS= 1. 

~ FILE 5. METHOD S. RUN 16 INDEX I BIN 5 

..~ NAME PPM RT PK HT BC RF 

.~ 

s 

„ 

.~ 

~ 1 0. 0.81 319245 02 

` F— 2.454 1.04 389093 03 158554.74 _ 

3 0. 1.8 211269 01 _ -< 

~ 4 0. ~ `^ 4.54 12255 02 

.4 5 0. 4.82 1025229 03 

~ TOTALS 2.454 1957093 

p WARNING — MEMORY AT 7. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACEU 

.,~ 

r~ CHANNEL A INJECT 03/17/99 14:51:50 STORED TO BIN tt 

i T 5 1 

~ 81 

1.79 1.49 

~ 

2 . 80 

1 

loZ 
J , yJ ~ J _. . . _ . ~ ~ ' l~ i I . • t l: ~ .. . ~ ~ 7 

3 0. 

4 0. 

5 0. 

6 0. 

7 0. 

TOTALS 1.593 

1.49 1084Y60 

1 .79 1 126`3 

2.8 2185'7 

4 .54 7213 

4 .82 102'~ 5949 

2870535 

03 

01 

02 ~ 

03 ~ 

, 

WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS WILL BE REPLACED 

L CHANNEL A INJECT 03/17/99 15:14:26 STORED TO BIN ri 8 

ER 0 

DATA SAVED TO BIN 4 8 

INPUT OVERRANGE AT RT= 1 .34 

EPA 26 03/17/99 15:14:26 CH= 'A' PS= 1. 

FILE 5. METHOD 5. RUN 18 INDEX 1 BIN 8 

NAME PPM 1 RT PK HT BC RF 

1 

F— 

0. J081 

4.376 ~ 1. .03 

312128 

643008 

02 

03 146939.671 

~ 

~~~.;.. 

3 0. 1.79 215309 01 

4 0. 4.54 6728 02 

5 0. 4.82 1025216 03 

TOTALS 4.376 2202389 (, 3 . ~ . 

WARNING — MEMORY AT 6. K— UNPROTECTED a 

CHROMATOGRAMS WILL BE 

,f• .•• 

REPi.AC0:- 

... . . .~...~., . ':,:, _. • ..~~,~ 
. ~ 

: 1 

~ I NO DATA, CHANNEL A 

I WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOGRAMS W I LL BE REPLACED 

CHANNEL A INJECT 03/17/99 15:38:19 STORLD TO B1N 4 10 

E R 0 

~ DATA SAVED TO BIN tt 10 

~ 

I NPUT OVERRANCE AT RT= 1.3 

C/, 

~ EPA 26 03/17/99 15:38:19 CH= 'A' PS= 1. 

~ FILE 5. METHOD 5. RUN 1 INDEX 1 BIN 10 

NAME PPM RT PK HT BC RF ~ 

1 0. 0.81 316248 02 

F— 2.588 1.05 40655e_' 03 157091.19 

~ 3 0. 1.5 1122581 02 

4 0. 1.79 192467 03 

5 0 2 8 24003 01 z— 

~ 6 0. 4.56 6673 e2 

7 0. 4.84 1025486 03 ~r 

.~ TOTALS 2.588 3094010 

r 

— 6A 

~ WARNING — MEMORY AT 6. K— UNPROTECTED CHROMATOCRAMS W1LL BE REPLACED 

s 

~ t 
QUALITY CONTROL DATA 

.~ 

~ 

~ 

Davis & Floyd 

Clayton Project No..72181.00 

Chlorine 

(o S 
AJ,:,, 

72-/ 

✓ / z 

•'~ - ° j y / ~ 

o. 

- •;: ~ ~" l r4 ~~.~ ~ ~~ ;~,~ 

✓ 

— 

41-e 

4C~ L~ C. 

llu 

L--Z; / ) =- C 3 2~~ 

0 

~- /,-, ~-,L7 
f 

i ..'_i 

APPENDIX 4 

Laboratory Data 

Production Data 

PLOTHRIDIHGA99\60823-3. DOC L1 

nAVIC .c. 9?1 nvn INr 
y~ 

~ 

~ 

~ 

Detroit Regional Office 

22345 Roethel Drive 

Novi, MI 48375 

(248) 344-1770 

Fax (248) 344-2655 

Clayton 

LABORATORY 

S E R V I C E S 

March 18, 1999 

--i Mr. Stanley Broome 

~ DAVIS & FLOYD 

816 East Durst Street 

Greenwood, SC 29649 

Clayton Project No. 72181.00 

Client Reference: 60823.00/PALMETTO BRICK 

Dear Mr. Broome: 

Attached is our analytical laboratory report for the samples received on 

K;.. ~ ~.')rrRic~ .!V'Rr

-f 

x ~c-Marc' _.-._. ... . ~1.°:~±'^1999: Also enclosed is a copy of the Chain-of-Custody record 

.: acknowledging receipt of these samples. 

= Please note that any unused portion of the samples will be discarded after 

t ~~^J4i - 

~ rP,xiTial~1'~~19'9'9; unless you have requested otherwise. 

,. i We appreciate the opportunity to assist you. If you have any questions 

~ concerning this report, please contact a Client Services Representative at 

(800) 806-5887. 

Sincerely, 

Laura R. McMahon 

Supervisor, Client Services 

Laboratory Services 

Detroit Regional Office 

LRM/gt 

Attachments 

~ 

~0 ~ 

~

>, 

Clayton Laboratory Services is a Division of Clayton Group Services, Inc. 
Clayton 

~ 

Table 1 LABORATORY 

5 E R V I C C S 

~ Analytical Results 

for Page 2 of ~ 

DAVIS & FLOYD 

~ Clayton Project No. 72181.00 

Client Reference#: 60823.00/PALMETTO BRICK 

r,- 

Sample Identification: SAMPLE #1 .1N H2SO4 Date Sampled: 03/04/99 

Lab Number: OOla Date Received: 03/09/99 

Sample Type: Impinger / Bubbler Air Volume (L): 1167.2 

Analyst : LK 

~-y 

1 

-~ Analytical Results 

---------------------- LOD Method Date 

~ r~ Analyte (ug) (mg/m3) (ug) Reference Analyzed 

~ ~ ~Fy 

Hydrofluoric acid 2f 2.2 

~r

00 v...,. 400 EPA 26 03/ 17/9 ~ ~ -------------------------------------------------------------------------------------------- 

~ 

Sample Identification: SAMPLE #2 .1N H2SO4 Date Sampled: 03/04/99 

i ~ Lab Number: 002a Date Received: 03/09/99 

Sample Type: Impinger / Bubbler Air Volume (L): 1173.8 

Analyst : LK 

~ Analytical Results 

---------------------- LOD Method Date 

Analyte (ug) (mg/m3) (ug) Reference Analyzed 

~ ~ 

Hydrofluoric acid 

-------------------------------------------------------------------------------------------- 

2400 2.0 400 EPA 26 03/17/9c 

4 

~ 

~ 

Y 

! 

~ 
~ 

Clayton 

Table 1 (continued) ~ EABORATORY 

5[ R V I C E 5 

Analytical Results 

. for Page 

DAVIS & FLOYD 

Clayton Project No. 72181.00 

~ . Client Reference#: 60823.00/PALMETTO BRICK 

•~ 

.v 

~ Sample Identification: SAMPLE #3 .1N H2SO4 Date Sampled: 

` Lab Number: 003a Date Received: 

Sample Type: Impinger / Bubbler Air Volume (L): 

~ Analyst: LK 

3 of ~ 

03/04/99 

03/09/99 

1138.2 

rn; M1 

( 

± ~f 

Analytical Results 

---------------------- LOD Method Date 

;.~ Analyte (ug) (mg/m3) (ug) Reference Analyzed 

~ Hydrofluoric acid ";~ ~ v °` 2.4 400 EPA 26 03/IT/3` ~ 

~ ------------------------------------------------------------------------------------------- 

.~ 

~ 

Sample Identification: H2SO4.1N BLANK Date Sampled: ;• 

Lab Number: 004a Date Received: 

Sample Type: Impinger / Bubbler Air Volume (L): 

,.; Analyst: LK 

03/09/99 

Y' 

Analytical Results 

---------------------- LOD Method Date 

Analyte (ug) (mg/m3) (ug) Reference Analyzed 

Hydrofluoric acid ~_•. -- 400 EPA 26 03/17/9 r 

------------------------------------------------------------------------------------------- 

✓7 0 
@ Clayton 

Table 1(continued) RTORY 

S E B B VI C E S 

~ Analytical Results 

for Page 4 of 

DAVIS & FLOYD 

~ Clayton Project No. 72181.00 

Client Reference#: 60823.00/PALMETTO BRICK 

~ . 

r^r 

Sample Identification: NAOH.IN BLANK Date Sampled: -- 

Lab Number: 005a Date Received: 03/09/99 

Sample Type: Impinger / Bubbler Air Volume (L): -- 

~ Analyst: LK 

Analytical Results 

---------------------- LOD Method Date 

~ Analyte (ug) (mg/m3) (ug) Reference Analyzed 

f Chlorine <3.,Q.p :. . -- 300 EPA 26 03/17-19' 

~ ------------------------------------------------------------------------------------------- 

L 

~ 

~ Sample Identification: D.I. WATER BLANK Date Sampled: 

Lab Number: 006a Date Received: 03/09/99 

Sample Type: Impinger / Bubbler Air Volume (L): -- 

~ 

Analyst: LK 

~ Analytical Results 

---------------------- LOD Method Date 

Analyte (ug) (mg/m3) (ug) Reference Analyzed 

~ Chlorine <300 == 300 EPA 26 03/17/9 , 

Hydrofluoric acid ~ 400 400 EPA 26 03/17/9 1 

+.; ;... 

------------------------------------------------------------------------------------------- 

~ 

~ 

~ R ~ 

.t 

: 
i 

Clayton 

~ Table 

Analytical 

1 (continued) 

Results 

EABORATORY 

SE RVIE,,[S 

for Page 5 of E 

DAVIS & FLOYD 

Clayton Project No. 72181.00 

6; Client Reference#: 60823.00/PALMETTO BRICK 

3 

~ 

M 

Sample Identification: SAMPLE #1 .1N NAOH Date Sampled: 03/04/99 

Lab Number: 007a Date Received: 03/09/99 

Sample Type: Impinger / Bubbler Air Volume (L): 1167.2 

~ Analyst: LK 

L. s 

~ 31 

7 

~S Analytical Results 

---------------------- LOD Method Date 

Analyte (ug) (mg/m3) (ug) Reference Analyzed 

>► 

~ 

~ 

Chlorine 700 

-------------------------------------------------------------------------------------------- 

0.6 300 EPA 26 03/I7'/9'- 

~ 

f~ Sample Identification: SAMPLE #2 .1N NAOH Date Sampled: 03/04/99 

c~ Lab Number: 008a Date Received: 03/09/99 

Sample Type: Impinger / Bubbler Air Volume (L): 1173.8 

s~ 

Analyst: LK 

~' Analytical Results 

---------------------- LOD Method Date 

Analyte (ug) (mg/m3) (ug) Reference Analyzed 

' 

~ 

~

Chlorine 

----------------------------------- 

600 ------------ 0~5 ------------- 300 ----- EPA - 26 --- --- 03/17/9' 

~ 

~ 

~ -7L 
Clayton 

Table 1 (continued) LABORATORY 

S f R V I C E S 

Analytical Results 

for Page 

DAVIS & FLOYD 

Clayton Project No. 72181.00 

Client Reference#: 60823.00/PALMETTO BRICK 

6 of 6 

.i 

t 

Sample Identification: SAMPLE #3 1N NAOH 

' Lab Number: 009a 

Sample Type: Impinger / Bubbler 

IAnalyst: LK 

i 

..~ 

Date Sampled: 

Date Received: 

Air Volume (L): 

03/04/99 

03/09/99 

1138.2 

i } 

y Analytical Results 

---------------------- 

~ Analyte (ug) (mg/m3) 

~ 

? Chlorine 600 0.5, 

1 

General Notes 

~ <: Less than the indicated limit of detection (LOD) 

~ --. Information not available or not applicable. 

LOD Method 

(ug) Reference 

300 EPA 26 

Date 

Analyzed 

03/17/39 

13 
QUALITY CONTFOL DATA 

Davis & Floyd 

C(ayton Project No..72181.00 

Hydrofluoric acid 

-2~ 
, 30 

-~ 

3L '% ~!-;• ~~=~ _z = l rl , e ~ iD ~ 

 . 

. i I 

~/G ''7- z 

~ 

 ~ — / 

I 

5-. r ( ~S- n.t / •, - — 

 /^j 

/L 

7 .~K 3 

Zlyl - G I ,3G- 3 ~ • / , • ~. 5 ✓ 

02- ,36:3 i. ~7~ ✓',~ 

~ 3 .a-. 

63 ~ / ~~~,/'~ ✓ a .~ _ - 

( (,4-11cv x' 

lt'T(c e:'ou;.v r.c//rilt ~ ~ ~c ~-• ~ -~i c. ~C 

~ c~-t l.C-~_ '~'~'r' ' .~s 

.r ~JJ_ ~ // '7`rCti~ ~Gt~LLt .•L-~ 

~ ~~P-c ~ l,.r, r ~ C 'SGC ~ ~ ~<' )I"~.(' ,,4•` 

1 

,~ 

~ J /E / ~ ,~ • , < ~ ~ / <, Sb •5 

A

Lm2~ A 1 ~ Jk- .4 -% - ISq3 n''Q X ~ DF~ 63 ~2 , ~Q = 2® ~ 

b AA- 14" ~ 
NAME PPhI RT PK HT BC 

1 0. 0.81 349059 01 

F- 1. 1.06 200109 01 

3 0. 1.82 213944 01 

4 0. 4.54 7987 02 

5 0. 4.85 1024009 03 

.RF 

,Io ~ ~AV,:

I ~._ l 

~ 

~ 

~ 

WARNING - 19EMORY AT 4. K- UNPROTECTED CHrZOMATOGRAMS WILL BE REPLACED 

CHANNEL A 1NJECT 03/17/99 1]:]7:06 STORED TO BIN U 115 

ER 0 

DATA SAVED TO BIN 4 115 

INPUT OVERRANGE AT RT= 1 .35 

EPA 26 03/17/99 11:17:06 CH= 'A" PS= 1. 

FILE 5. METHOD 5 RUN 1 INDEX ] CALIB BIN 115 

TOTALS 1. 1795108 

WARN I NG - ME190RY AT 3. K- UNPROTECTED CHROth1ATOGRAhIS WILL BE REPLACED 

CHANNEL A I NJECT 0_3/ 17 1 1:2-8: 24 STORED TO B 1 N 4 116 7l0 

T5 1 
CHANNEL A INJECT 03/17/99 11:28:24 STORED TO BIN 4 116 

ER 0 

DATA SAVED TO BIN tt 116 

INPUT OVERRANCE AT RT= 1.35 

EPA 26 03/17/99 11:28:24 CH= "A" PS= 1. 

FILE 5. HETHOD 5. RUN ? INDEX ? CALI6 BlN 116 

NAh1E PPIlI RT PK HT BC RF 

1 0. 0.81 340851 01 

F- 2. 1.05 339056 01 

3 0. 1. ti` 215643 01 ~ 

4 0. 4.54 8901 02 

5 0. 4.t35 1025035 03 

TOTALS ? . 1929485 

WARN I NG - h1Eh10RY AT 1. K- UNPROTECTED CHROPIATOCRAhIS WILL BE REPLACED 

CHANNEL A INJECT 03/17/99 11:39:42 STORED TO BIN a 117 

I 15 1 

1 .oS 77 
CHANNEL A 

~ 

, 

~ 

~ 

~ 

r{ 

r 9 

I NJECT 03/ 17/99 1 1: 51 : 00 STORED TO B I N 4 1 1 8 

i 

+ .54 

:x 

4 .85 

~ 

E R 0 

DATA SAVED TO B1N tt 117 

; 

~ 

OVERRANCE AT RT= 1.34 

g~

INPUT 

EPA 26 03/17/99 11:39:42 CH= "A" PS= 1. 

w~ 

FILE 5. 19ETHOD S. RUN 3 INDEX 3 CAL1B BIN 117 

: y 

NAI-IE PPhI RT PK HT BC RF 

.~ 

1 0. 0.81 313611 02 , '1 

~ F- 3. 1.05 451907 03 ~~ :.. 

~ 3 0. 1. 8 215888 01 

4 0. 4.54 8461 02 

~ 

~ 

5 0. 4.85 1026467 03 

TOTALS 3. 2016333 

;•.,. 

WARN i NG - 19EI-10RY AT 5. K - UNPROTECTED CHROt9ATOCRAt9S WILL BE REPLACED 

` ER 0 

~ DATA ;AVED TO Fi I N ti 1 1 ~ t 
APPENDIX 3 

Field Data 

Field Equipment Calibrations 

PLOTHRID\HGA99\60823-3.DOC 

7"i 

~ 

nat,nc x. ur nvn INc 
--, 

~ 

..: 

~ 

~ .I 

,. ~ ? 

-=_ 

DAVIS & FLOYD, INC. 

Environmental Services Division 

~~ . EPA METHOD 5 

~0~ Preliminary Data 

816 E. Durst St. 

Greenwood, South Carolina 29649 

(864) 229-5211 

CLIENT: PALMETTO BRICK PROJECT NUMBER:60823.00 

CITY, STATE: CHERAW, SC CONTACT:KEVIN MACKEY 

UNIT TESTED: DRY LIME SCRUBBER DATE:3-4-99 

RUN NO.: OPERATORS:BROOMENVILSON 

DIAMETER OF CIRCULAR STACK (in.): 60 ; METER BOX N0.:3 

DIMENSIONS OF RECT. STACK (in.): METER )H@: 

NO. OF )P READINGS:a► 12 IMPINGER BOX NO.: ~ 

Cp FACTOR:.84 FILTER HOLDER NO.: ~1 

STATIC PRESSURE (in. H20):-.14 FILTER NO.: ~ L L L jE~ /_ 9 

BAROMETRIC PRESSURE (in. Hg): NOZZLE DIAMETER (in.): . 3 (g y 

RUN TIME (min.): 60 

/- i6c~(i 

NOZZLE NO.: 4;cu re: -a~Post: ~~ft ~ 

WET BULB / DRY BULB TEMPS (°F): GLASS THERMOMETER TEMP (oF): 

ASSUMED MOISTURE (%): 10 THERMOCOUPLE READOUT (oF): Pre.- ost: 

INITIAL IMPINGER VOLUME (ml): 2,86-!,¢Ao PITOT LEAK CHECK: Pre r/Post 

FINAL IMPINGER VOLUME (ml): 4 70 PROCESS RATE: 

INITIAL SILICA GEL VOLUME (g): 200 STEAM PRODUCTION: 

FINAL SILICA GEL VOLUME (g): _ :3 02(%): 

HEATER BOX SETTING (°F): 250 COz (%): 

PROBE HEATER SETTING (°F): 250 CO (ppm): 

PROBE LENGTH (ft): s DRY MOLECULAR WEIGHT (Ib/Ib mole): 

PROBE NO.: /_ p/tce-1 „: METER BOX Y FACTOR: 

PROBE LINER MATERIAL: GLASS DRY GAS METER VOLUME (ft3): 3$ 

Ar4 ,.n Kce 

OBSERVER: SCDHEC DRY GAS METER VOLUME x Y(ft3): 3 . ~j ~ '3 3 

Stack & Process Flow 

I 

J 

A .i ?D 
~ l 

DAVIS & FLOYD , INC. 

Environmental Division 

EPA METHOD 5 

Field Data 

816 E. Durst St. 

Greenwood, South Carolina 29649 

(864) 229-5211 

CLIENT: PALMETTO BRICK UNIT TESTED:DRY LIME SCRUB TEST NUMBER: 

SAMPLE 

POINT # 

CLOCK 

TIME 

SAMPLE 

TIME 

DRY GAS 

METER ft3 

)P 

(in. H20) 

)H 

(in. H20) 

STACK 

TEMP 

oF 

DRY GAS TEMP oF 

INLET OUTLET 

PUMP 

VACUUM 

(in. Hg) 

FILTER 

TEMP oF 

IMPINGER 

TEMP oF 

PORT- n 

' ~ t ociokA ° 7 93.3q5 ,Lij .,2. 3v3 y '-~~ 2 S 4 Z 

2 5 o~ 141 43 2sti yZ 

3 10 

~DO~ 1 3 3 0 q 2 '7Z 

4 15 1.10 5011, s z q 3.S LI0 

5 20 I. 6 ov 41S 

6 25 

p ~ l• ~ Z•1 1'1 14 3 

q~ 

30 

PORT 

, ° ."~ o I,$a 363 qq 4 Z,S 7 S' 

2 5 ~~~ ~ •~ 7 0! '1 Z 

3 10 ~ d ` /7 

a 15 ,`6 .titi ' 0 1 3.r L(. f 47 

5 20 

0 3• 7,1.0 '1 ~ 

6 25 

Zy— ( '1 

30 ~~~.• ~ tD l 

~ 

~ 

INITIAL LEAK RATE: ~ ~~ CFM (81 ~D in. Hg FINAL LEAK RATE: CFM (81 L in. Hg 

i 

COMMENTS: 

PAGE OF ~ ~ 

~ 

~ n 

I 

3 
_.~ 

; 

; 

DAVIS & FLOYD , INC. 

Environmental Services Division 

e~EPA METHOD 5 

a``\~ Prelimina ry Data 

~jl 

816 E. Durst St. 

Greenwood, South Carolina 29649 

(864) 229-5211 

CLIENT: PALMETTO BRICK PROJECT NUMBER:60823.00 

CITY, STATE: CHERAW, SC CONTACT:KEVIN MACKEY 

UNIT TESTED: DRY LIME SCRUBBER DATE:3-4-99 

RUN NO.: a OPERATORS:BROOMENVILSON 

DIAMETER OF CIRCULAR STACK (in.): 60 METER BOX N0.:3 

DIMENSIONS OF RECT. STACK (in.): METER )H@: ;~ , j` & 

NO. OF )P READINGS:(f la'C IMPINGER BOX NO.: D 

Cp FACTOR:.84 FILTER HOLDER NO.: /(/~ 

STATIC PRESSURE (in. H20):-.14 FILTER NO.: ,4LL — ~~ Z_ Q p 

BAROMETRIC PRESSURE (in. Hg): NOZZLE DIAMETER (in.): . 30 

RUN TIME (min.): 60 NOZZLE NO.: s re: L--- 

WET BULB / DRY BULB TEMPS (°F): I GLASS THERMOMETER TEMP (oF): f. 

ASSUMED MOISTURE (%): 10 THERMOCOUPLE READOUT (oF): Pre:L--Post:_ 

INITIAL IMPINGER VOLUME (ml): 290 4.80 PITOT LEAK CHECK: Pre '----Post 

FINAL IMPINGER VOLUME (ml): 445 PROCESS RATE: 

INITIAL SILICA GEL VOLUME (g): 200 STEAM PRODUCTION: 

FINAL SILICA GEL VOLUME (g): 9, 7 OZ (%): 

HEATER BOX SETTING (°F): 250 COZ (%): 

PROBE HEATER SETTING (°F): 250 CO (ppm): 

PROBE LENGTH (ft): s' DRY MOLECULAR WEIGHT (Ib/Ib mole): 

PROBE NO.: METER BOX Y FACTOR: 

PROBE LINER MATERIAL: GLASS DRY GAS METER VOLUME (ft3): 

39. qsl 

OBSERVER: ' ~ SCDHEC DRY GAS METER VOLUME x Y(ft3): Q, LI'7 

~ Stack & Process Flow Diagram 

~ 2 
,.; 

:t 

:z DAVIS & FLOYD , INC. 

Environmental Division 

EPA METHOD 5 

,~~~~ Field Data 

~y~ 

816 E. Durst St. 

Greenwood, South Carolina 29649 

(864) 229-5211 

CLIENT: PALMETTO BRICK UNIT TESTED:DRY LIME SCRUB TEST NUMBER: a 

SAMPLE 

POINT # 

CLOCK 

TIME 

SAMPLE 

TIME 

DRY GAS 

METER f13 

)P 

(in. HZo) 

)H 

(in. HZO) 

STACK 

TEMP 

oF 

DRY GAS TEMP oF 

INLET OUTLET 

PUMP 

VACUUM 

(in. Hg) 

FILTER 

TEMP oF 

IMPINGER 

TEMP oF 

PORT- 

' 1oZI 1 ° 

2 5 4%. 7 2 7 

3 10 

Vk•tk 30 ~ s's- sl 2-54- 42 

4 15 2'(90 ~ 8 

S 20 4 

(0 Z Z ..Y 0 S 2W 1 0 

6 25 

30 

85 r. so 3 

PORT- 

, ° 

2 5 ' G/ 

3 10 

l f~1 190 S ~ Z~O~ ~~ 

4 15 

~ vGl. ~ ~ ~•~ V oir (A.0 s' 3 2(rZ If 5— 

s 20 

 goto bo z(o o ~Cr 

6 25 

%U`6.`i 1•W o(t (20 S-~ 2579 ~ 9 

Z.~ 30 

INITIAL LE4K RATE: CFM (81 S in. Hg FINAL LEAK RATE: ~ 0 Q CFM @ in. Hg 

COMMENTS: 

PAGE OF 3 
DAVIS & FLOYD , INC. 

Environmental Services Division 

6 EPA METHOD 5 

h ~ Preliminary Data ~ 

~,~~`~1 

816 E. Durst St. 

Greenwood, South Carolina 29649 

(864) 229-5211 

CLIENT: PALMETTO BRICK PROJECT NUMBER:60823.00 

CITY, STATE: CHERAW, SC CONTACT:KEVIN MACKEY 

UNIT TESTED: DRY LIME SCRUBBER DATE:3-4-99 

RUN NO.: 3 OPERATORS:BROOME/WILSON 

DIAMETER OF CIRCULAR STACK (in.): 60 METER BOX N0.:3 

DIMENSIONS OF RECT. STACK (in.): METER )H@: 

NO. OF )P READINGS:M 12. IMPINGER BOX NO.: 

Cp FACTOR:.84 FILTER HOLDER NO.: ^/ 

STATIC PRESSURE (in. H20):-.14 FILTER NO.: 

BAROMETRIC PRESSURE (in. Hg): 73— NOZZLE DIAMETER (in.): .3 a y 

RUN TIME (min.): 60 NOZZLE NO.: ~ — 

P/ea't Pre: L-- Post: ~ 0 

WET BULB / DRY BULB TEMPS (°F): GLASS THERMOMETER TEMP (oF): 

ASSUMED MOISTURE (%): 10 THERMOCOUPLE READOUT (oF): Pre: --Post:_' 

INITIAL IMPINGER VOLUME (ml): 28'04-00 PITOT LEAK.CHECK: Pre_k~ Post 

FINAL IMPINGER VOLUME (ml): Q-.g ( PROCESS RATE: 

INITIAL SILICA GEL VOLUME (g): 200 STEAM PRODUCTION: 

FINAL SILICA GEL VOLUME (g): I Z• 0 02 (%): 

HEATER BOX SETTING (°F): 250 CO2 (%): 

PROBE HEATER SETTING (°F): 250 CO (ppm): 

PROBE LENGTH (ft): 5" DRY MOLECULAR WEIGHT (Ib/Ib mole): 

PROBE NO.: %;.~ ~_ ~j E c~ METER BOX Y FACTOR: ), Oa(o 

PROBE LINER MATERIAL: GLASS DRY GAS METER VOLUME (ft3): 

3g. q33 

o ~ v 

OBSERVER: SCDHEC DRY GAS METER VOLUME x Y(ft3): 9 3,-;? 

Stack & Process Flow Diagram 

~ 

{ 

,r 

3 ~~ 

a~

! 

~ 

I 
DAVIS & FLOYD , IrrC. 

Environmental Division 

EPA METHOD 5 

Field Data 

816 E. Durst St. 

Greenwood, South Carolina 29649 

(864) 229-5211 

CLIENT: PALMETTO BRICK UNIT TESTED:DRY LIME SCRUB TEST NUMBER: 3 

SAMPLE 

POINT # 

CLOCK 

TIME 

SAMPLE 

TIME 

DRY GAS 

METER ft3 

)P 

(in. H20) 

)H 

(in. H20) 

STACK 

TEMP 

oF 

DRY GAS TEMP oF 

INLET OUTLET 

PUMP 

VACUUM 

(in. Hg) 

FILTER 

TEMP OF 

IMPINGER 

TEMP oF 

PORT- T1 /~ 

1 1131 1 ° 11. 8il 30 s' s16~ ~fg 

2 5 

11 

„~ .~p , C 361 zS'Z S3 

3 10 ~ n K. 

4 15 Q ~ 2.('tc. 

.J2 ~ I•Sw 3o S 4 3•/ /S Go 6 Z 

5 20 ~jV ~~ ,~ ~Z~ ,1 ~ 01 S`6 N S• ~ Lc. ( SS' 

6 25 ~1~ 0 \ J) .~ ~Y ~ 0"k ~ Z5 0 

30 ~Q~a~~U 

PORT1 0 

92. 1S4 IoLA >"'-( 

2 5 

~' I

(a , O 

. ~ 1 . ~ z s 

3 10 

0% •`6 (to Lsf - 53 

4 15 CA07•b .2~ I•Nti o t¢l Sle 3.5~ 2c.v sLf 

5 20 Ans1 0 .20 1.713 3OQ I u i ~P L(.~( Z 

6 25 

1101.1 ~ ~ lY , 1 1 0 1 1 3 Z6 o J-3 

z 

30 9!1). zs' ~ 

INITIAL LEAK RATE: .003 CFM in. Hg FINAL LEAK RATE: ~ B0~ CFM C s in. Hg 

COMMENTS: C 

PAGE OF pS 

I 

~ 
r-I 

`A DAVIS & FLOYD, INC. 816 E. Durst St. 

EPA METHOD 1 Greenwood, South Carolina 29649 

Environmental Services Division (864) 229-5211 

~ 

CLIENT:PALMETTO BRICK PROJECT NUMBER:60823.00 

CITY, STATE:CHERAW, SC CONTACT:KEVIN MACKEY 

d' 

UNIT TESTED:DRY LIME SCRUBBER DATE:3-4-99 

' Duct Depth (in.): 60 Stack Area (ftz) 0.0000 

far wall to outside of port 

~ Nipple Length (in.): UPSTREAM DOWNSTREAM 

~ Depth of Duct (in.): Nearest Flow 

~ 

~ •. Disturbance (ft): 

I Width of Duct (in.): 

;., Equivalent Dia. (in.): Diameters: 3.0 12.4 

LOCATION OF TRAVERSE POINTS IN CIRCULAR STACKS LOCATION OF TRAVERSE POINTS IN RECTANGULAR STACKS 

4 6 8 10 12 14 16 18 20 22 24 2 3 4 5 6 7 8 9 10 11 12 

iz~

1 6.7 4.4 3.2 2.6 2.1 1.8 1.6 1.4 1.3 1.1 1.1 1 25.0 16.7 12.5 10.0 8.3 7.1 6.3 5.6 5.0 4.5 4.2 

25.0 14.6 10.5 8.2 6.7 5.7 4.9 4.4 3.9 3.5 3.2 2 75.0 50.0 37.5 30.0 25.0 21.4 18.8 16.7 15.0 13.6 12.5 

3 75.0 29.6 19.4 14.4 11.8 9.9 8.5 7.5 6.7 6.0 5.5 3 83.3 62.5 50.0 41.7 35.7 31.3 27.6 25.0 22.7 20.8 

93.3 70.4 32.3 22.6 17.7 14.6 12.5 10.9 9.7 8.7 7.9 4 87.5 70.0 58.3 50.0 43.6 36.9 35.0 31.8 29.2.. , 

t 85.4 67.7 34.2 25.0 20.1 16.9 14.6 12.9 11.6 10.5 5 90.0 75.0 64.3 56.3 50.0 45.0 40.9 37.5 

~ 95.6 80.6 65.8 35.6 26.9 22.0 18.8 16.5 14.6 13.2 6 91.7 78.6 68.8 61.1 55.0 50.0 45.8 

7 89.5 77.4 64.4 36.6 28.3 23.6 20.4 18.0 16.1 7 92.9 81.3 72.2 65.0 59.1 54.2 

8 96.8 85.4 75.0 63.4 37.5 29.6 25.0 21.8 19.4 8 93.6 83.3 75.0 68.2 62.5 

82.3 73.1 62.5 38.2 30.6 26.2 23.0 9 94.4 85.0 77.3 70.8 

0 IT1 91.8 

97.4 88.2 79.9 71.7 61.8 36.6 31.5 27.2 10 95.0 86.4 79.2 

93.3 85.4 78.0 70.4 61.2 39.3 32.3 11 95.5 87.5 

12 97.9 90.1 83.1 76.4 69.4 60.7 39.8 12 95.8 

ti 3 94.3 87.5 81.2 75.0 68.5 60.2 

4 98.2 91.5 85.4 79.6 73.6 67.7 

5 95.1 89:1 83.5 78.2 72.6 

16 98.4 92.5 87.1 82.0 77.0 

.^~ 7 95.6 90.3 85.4 80.6 

8 98.6 93.3 88.4 83.9 

a~ 9 96.1 91.3 86.8 

20 98.7 94.0 89.5 

r1 96.5 92.1 

2 98.9 94.5 

3 96.8 

24 98.9 

Point % of Stack Diameter Stack Diameter Distance from Inside Wall Nipple Length Distance from End of Port 

1 4.4 36 2.64 

2 14.6 8.76 

3 29.6 17.76 

4 70.4 42.24 

5 85.4 51.24 

6 95.6 57.36 

~d ~ 
--, 

i 

~ 

DAVIS & FLOYD , Irrc. 

Environmental Services Division 

EPA METHOD 1 

Cyclonic Flow Test 

816 E. Durst St. 

Greenwood, South Carolina 29649 

864 ) 229-5211 

CLIENT:PALMETTO BRICK CO. UNIT TESTED:DRY LIME SCRUBBE DATE:3-4-99 

PORT TRAVERSE POINT # )P @ 90° ROTATION ANGLE (N) 

FOR NULL )P 

A 1 NEG 7 

2 IJEG 5 

3 0 0 

4 0 0 

5 0 0 

6 .03 11 

B 1 NEG 4 

2 NEG 5 

3 0 0 

4 0 0 

5 .02 8 

6 .07 12 

AVERAGE = 4.33 

Comments: O:DATA\WORD\STCKTEST\CYCLONIC .DOC 

S7 

r~ 

, 

. y 

4 

~ 
-,+ 

, 3• 

~ 

DAVIS &. FLOYD, 1NC. 

Environmental Services Division 

EPA METHOD 3 

816 E. Durst St. 

Greenwood; South Carolina 29649 

(864) 229-5211 

CLIENT: PQtMc-WO Gk c, PROJECT NUMBER: tg ~3 , Od 

CITY, STATE: r~~ S(- CONTACT: Ke_v l"\ ac-lQ 

UNIT TESTED:"~r L;,,,, ~ S~,~(~e~ DATE: 3, y, 

SAMPLE TYPE: 66te rate / grab FUEL TYPE: r_ S ANALYST: 54 

ANALYZER TYPE: O, T _a\ATnc CO, CF-kc."to, CO M-x S 

OXYGEN CALIBRATIONS 

RUN #1 RUN #2 RUN #3 

:HIGH ° L01N ' r •HIGH:, ": : LOW ' : ':: ; HIGH LOW 

Calibration Gas Value ~ (%) 

-~

0. 9 7.2 1 20 .7 7• Z Zo. 9 7.2 

An. alyzer Readin9 (%) ~D , ~j 7, Z ,?o. 9 7. 2- 26.197. 2- 

CARBON DIOXIDE CALIBRATIONS 

'RUN #3' 

HIGH ~r~ HIGH ;~ ~ ✓LOW. HIGH 'j LOW 

:: LOW 

Calibration.Gas Value,(%) Calc. Calc. Calc. Calc. Calc. Calc. 

Agrialyzer Readin ` (%). Calc. Calc. Calc. Calc. Calc. Calc. 

GAKt3UN MUNUXIUt GALItiKAI IUN5 

; :: RUN=#1 ~ ~ ~, `„RUN #2 , , RUN #3 :. 

HIGH ` LOW t HIGH LOW ', HIGH LOW 

Ca. Gas Value (ppm) S~ 0 

_ ..: 

Analyzer Read'iii9 (pPm) y 9. D y q. (~ b q q. -7 p 

TEST RESULTS 

DRY MOLECULAR WEIGHT CALCULATIONS 

~ RUN #1: 02 x 0.32 + CO2 x 0.44 + N2 x 0.28 = Ib/Ib dry mole 

RUN #2: 02 x 0.32 + CO2 x 0.44 + N2 x 0.28 = Ib/Ib dry mole 

RUN #3: 02 x 0.32 + CO2 x 0.44 + N2 x 0.28 = Ib/Ib dry mole 

NOTE: 

CO2 Calc. By Equation: COz= 20.9 - Oz 

E Fo 

~ Where: Oz =% oxygen measured by analyzer 

Fo = Mid range value for type of fuel (coal Bit. 1.157, wood 1.060, wood bark 1.066, oif distillate 1.337, 

oil residual 1.290) 51g 

COs = Calculated % carbon dioxide 
i 

~ 

~ 

~ 

~ _) 

, ~ 

-a 

i J 

~ 

~t 

~ 

~ 

~ 

~ 

TEST EQUIPMENT CALIBRATION CALCULATIONS 

Where: 

K' = Critical orifice coefficient 

, K, = Constant 17.64, °RIin.Hg 

-~T,mb = Absolute ambient temperature, °R 

V. = Volume of gas sample as measured by dry gas meter, dscf ~ 

V.(,,o = Volume of gas sampled passed through the critical orifice, 

corrected to standard conditions, dscf 

Y = Dry gas meter calibration factor 

Pbw = Barometric pressure, in, Hg 

OH = Average pressure differential across the dry gas meter 

orifice, in. HZO 

T. = Absolute average dry gas meter temperature, °R 

0 = Time, min. 

I. Calibration of Critical Orifices 

K, V. Y(Pb. + DH/13.6) 4T,,,,b 

K, _ 

Pb.,Tm O 

The individual K' values should not differ by more than t 0.5 percent from the average. 

The calibration of the critical orifice with a dry gas meter assumes that the dry gas meter 

has been calibrated with a wet test meter or an altemative primary standard. 

II. Using the Critical Orifices as Calibration Standards 

Pb,., + (DH/13.6) 

Vm(.td) = K, V. 

T. 

Pbw 0 

V.(rid) = K' 

` ` amb 

Y= 

Va(std) 

Vm(sId) 

M 

i 

I 

1 

I 

! 

1 

I 

I flsl/IC 0_ ci nv~ reIn 
. t 

1 

.'.j 

! 

... 

~ 

~ 

0 

u N ~ 

W ~ ~ ✓C N •- •- O O d M O 

. • 

O O O 

• 

O O O 

. . 

O O O 

• ~ O O O — ~ ~ 

. 

" 

~ 

W ~ ~~~ P q 

N N N 

N M N N 

M V~ ~~ M 1p~, 

~~/~ 

Y O d 

M v~ ~n 

J y y/ M M1 M M .

Mt Y v v Vqi N Y1 N ~` ,C .O .O 

P P P P 

~ ~ J O O O O O C. O O O O C. O O O O O O O O O 

J u > 

• ^ O C. O • 

V1 Y1 O j O O O yN y~ O' O O O t7 

N N O ~ 

O O O t7 

O V► O> 

O O O 

O vl O> 

l7 

v~i 

W ~ FW- O v 

Z N ~~~ 

O O O 

O O O ~~ 

-C{ 7C O O O .- ~ . N N N M•A M v~ v~ v1 y~ 

~~~ B 

~ x° _V I~ ✓ 

~~~0 

.p 

~~ IU b q ti b . q A ` 

y ~ N d • ~ 

> ~ 

6 

W 

ue K N 

W 19 ~O ~O 

.t V 

O ~O O D. 

p, 

q q ~ 

~ 

t I~ q eD e0 q Z 

p ` "~ L ✓ Q W W V - N 

= 3~~ ~ pbb ► : ~ ~~~ & 

cc 

•- O 

q P 

^ O O O 

M h P 

O C. O 

N!~ P 

O O ~ 

O O. 

~ O O 

M Y 

O O O 

a0 

U N 

V ^ A ~ 

M O N 

y~ 

~- 

4 

N ~p ►~ 

q O q 

N.O .O 

P 

q.- 1~ 

Y N N O!~ 

N O 

f~ OP P ~ ~ f/l F h ~ Y N^ N 

N Y ~ 

.p p. ~ 

N q r%j 

N Vl .p 

S 

W 

5 

fA W+ 

C7 S S " 

4 

V 

~ < 

V 

io 

o 

~ '! O O O O O O O O O O O O O O O V X 

~n 

~ 

n 

K J O 

• p. Mp, O. ~40 ~p O .p .Mp ~O ~Q • 

.O ~O N 

ap O. 

YO I~ •O 

. . 

~ •O vp~. O M e F 

~ ~~ v

, 

 f~ P 

q q q 

N M ~O 

P P P Mf h O 

O N v1 

q M

p, 

Fn 

= y 

aQ 

~q = H W v .M- ~ ~ .M- ~ ~ ~~.qy 

~~ .q- d ~ ^ < 

 O^ N N 

p 

N .p Y.Op 

O. 

~ 

~ ~ N W 

~ N 3~ r O M Q 

q P KO 

1~ O.Q 

CO P lP,~QI 

Y 

q ..p ~pp 

N P 

.O q N 

O~NO ~ 

P 1~ .O 

N M 

✓ 

~ ~"" ~O p Ml h 

CDP q y~ 

C..i

. v ~ ~ ~ M.- ~ .N- 10 10 10 

W ~ 

~ OC J ^ 

~" o 

. . • 

O O O ~ 

. . 

O O O 

. • • 

O O O 

• . • 

O O O 

. . . 

~ v 

d a[ 

OC 

.°..° x •- •- •- ~ ~ .- ~ .- ~ ~ .- .- ~ ~ .- ~ 

✓ y 

~ p 

M N h 1n N V! O O O O O O O O O „C 

~ ~ 

n ~~ N N O 

~ 

W 

~ W ✓ 

tJ W -c Z.; " p 

y y o p - ~ O ' a0 s0 ~ ~O q ti ti 

W ~ 

7R 

W . 

f~ a0 s0 GO N S 

~. 

~ = F

= 

~ O ~ ~ ~ ~ 

~ Y 

. 12 ~ 

J J J . on UN 

N ~ V% P ;2 0

.~ 

V 

F V 

W 7C • 

— W L Y 

p[ ~ ~ ✓ ~ 

• ~ cc o ~ 

' •-~ ~ W W W 

pp V L L •. 

V 

W 

( ~ $ - 5 ~ ~ 

Y ~ ~ S ~ N M ( .- N M ( ~- N MI < ~ N!~1 < VI VI 

m 
— ` a ~ 

® 

— =r 

Dr,pres Indica0no bvel posltion to r 

det.rminlnp 0[i .nd OLi --__-= P. Deprr,e Indicatinp lMwl posltbn lor 

datentininp ai and ai. 

1 

 Deprr,rr Indidtinp bvrrl position for 

de tbrm ininp (E). 

~ 

~ 

~ 

..,t 

CALIBRATION DATA SHEET 

Type S Pitot Tube Inspection 

Level and Perpendicular) ✓ 

Obstruction) 

DamaOed ) 

a t (-10 05 at 5+ 100 ) 

02 (-10 0S 02 S+ 100 ) 

a l (-5 0s BI s+5°) J7 

62 1-5 0s BZ s+5°l © 

Y d 

6 d 

z - A tan y(5 0.125') C~ 

w - A tan 6( 5 0.03125'1 ~ 

Dt (3/16' 5 D, s 3/8') 

A U/ 

Al2D 0.05 5 P/D s 1.5) ,-SS 

r 

^~. 

..~ 

'R 

4 

Dt — I—z 

1 

~— 

7~ 

fr 

Deprrre indka0np lravol postlion for 

delemininp7lhen calculate Z. 

QA/QC Check ~ ~ 

Completeness V/ Lepibility ,~Accuracy Specifications`-`—Reasonableness ~` 

Cert/l7catfon 

1 certify that the Type S pitot tube/probe 10a/-~7~ meets or exceeds all specifications, 

criteria and/or applicable desip f res r hereby assipned a pitot tube calibration factor C. of 0.84. 

Certified by: ~ 

Per nnel (Sipnature/Date) Team Leader (Sionature/Date) 

K 
CALIBRATION DATA SHEET 

Type S Pitot Tube Inspection 

Level and Perpendicular) ✓ 

ObstructionT 

Damaped ) 

0 1 (-10 0 S ats+ 10 0 ) Z 

aZ (-10 0 s 02 5+ 100) 

6 1 (-5 0 s Bt s+50 ) Z 

92 (-5 05 1&2 s+5°) L 

r b 

e 0 

z = A tan r( s 0.125') ® 

w- A tan 611 5 0.03125') 

Dr (3/16' s Dr s 3/8') ~ Z 

A 

A/2D 0.05 s P/D s 1.5) ,Z 

~.~ 

I 

— ` 

a ~ 

Drrpree Ind ~callnp levwl postlion ro 

d.t+rT'tinlnp C[i .nd otL 

Doprrrs Indicatinp IMwI posltbn lor 

determin:,o pr.nd az. 

l 

Depres Indiatinp bvel poskion lor 

I delermininp19. 

~ 

~ 

AL 

EA 

~ Dt -- I—Z 

I 

~ A 7I 

aaeee~

Dapns indlcatinp sMvol posltion ror 

! 

detemininp7then calculate Z. 

DA/QC Cbeck ' / ' / 

Completeness L/ Lepibility `~ Accuracy . 

Specifications Reasonableness 

Cert/ricition 

I certify that the Type S pitot tube/probe 101 S f-ryl~ ~~~ meets or exceeds all specifications, 

criteria and/or applicable desipn eat res reby assiqned a pitot tube calibration factor Coof 0.84. 

Certified by: 

Pers el (Sipnature/Date) e Team Leader (Sipnature/Date) 

€ I 

_I Z 
_ . 

— =r 

~tlt7 

Dspree Indicatinp bvrrl posltlon lo 

delonnlnYny O:r and oti 

I 

CALIBRATION DATA SHEET 

Type S Pitot Tube Inspection 

~ 

~ 

I 

, 

i Depree bndicatinp lsvel posttlon lor 

dslrrrm7ninp pa snd aa. 

l 

"~-J 

Deyrno indlcstlnp Ievsl position /or 

de lermininp E). 

Level and Perpendicularl ✓ 

Obstructionl 

Damapedl 

o t (-10 0 S ol S+ 10 0 ) ~ 

pZ (-100 S 02 S+ 10 ° ) 

Q t (-5° s B t s+5°) ~ 

132 (-5° 5 61 s+5°1 D 

r ~ 

e l 

z A tan r(5 0.125') 0 

w A tan 6( 5 0.03125') ,C2 Z 

Dl (3/16' S Dl 5 3/8'1 ,3 7 Z. 

A q V/ 

Al2D (1.05 s P/D s 1.5) ,2 

~ D l z 

--- f— I i 

Depres indlotinp 14v,*I posltion (or 

detemininprlhen cafcutate Z. 

~ 

QNQC Check ~ ~ ' / 

Completeness [~ Leflibility L/ Aceuracy 

Csrtl/icitbn / 

1 certify that the Type S pitot tube/probe IDat ~~~• 

criteria and/or applicable desipn eat s a reby as: 

Certified by: 

Per nel (Sipnature./pate) 

~ 

..~ ` 

Specifications Reasonableness _ 

~~ meets or exceeds all specifications, 

;iqned a pitot tube calibration factor Cp of 0.84. 

'e' a -~-.T_ 

~ Team Leader (Sipnature/Datel 

q3 
DAVIS & FLOYD, INC. 816 E. Durst St. 

Field Nozzle Calibration Greenwood, South Carolina 29649 

Environmental Services Division (864) 229-521 1 

CLIENT: t PROJECT NUMBER: 

CITY, STATE: C w DATE: ~_ _? 

NOZZLE MATERIAL: &-51-~ CALIBRATOR: ~ 

Nozzle D1 D2 D3 D4 D5 D(b) D(c) 

Identification (in.) (in.) (in.) (in.) (in.) (in) Avg 

Number 

Test Number 1 

6 PiE-C'kF ' 5 (D • . - 3 0<rTest Number 2 

/ - • 3 © ~ 

~ C9 .~ B 

est Number 3 

iprer'e) - 30 

Where: 

(a)D1,2,3,4,5 = Pive different nozzle diameters (in). 

Each diameter must be within 0.001 in. 

(b)D = Maximum difference between any two diameters (in). 

D 50.004 in. 

(c)D = Average of D 1, D2, D3, D4, and D5. 

. 1 

~ 

~ 

r~ 

~ 

~.~ 

q4 
~ 

., 

; • 

a • ' r 

{ •~ 

Lf 

r~ 

9. 

..~ 

Meter Box #: 3 

~ Date: 12-28-98 ~ . Calibrator: WSB 

DAVIS 8 FLOYD, INC. 

Environmental Senrices Division 

816 E. Durst St. 

Greenwood, South Carolina 29649 

EPA METHOD 5 

Meter Box Calibration 

Pre-Test Orifice Method 

Barometric Pressure: 29.53 

Critical Vacuum: 13.93 

Volume Initial Temps Final Temps Actual Ambient 

dH Time Initial Final Total Inlet Outlet Inlet Outlet Orifice K Vacuum Temp 

in. H20 min cu.ft cu.ft cu.ft deg F deg F deg F deg F Serial No. Factor in. H d F 

0.66 12.00 148.542 153.548 5.006 73.0 71.0 74.0 73.0 DH-48 0.329 220 75.0 

1.15 10.00 143.086 148.542 5.456 72.0 70.0 73.0 71.0 DH-55 0.4328 20.5 75.0 

2.05 7.00 153.548 158.561 5.013 74.0 73.0 75.0 73.0 DH-63 0.5656 19.0 75.0 

3.85 6.00 132.247 138.103 5.856 69.0 68.0 71.0 69.0 DH-73 07768 16.5 75.0 

6.00 5.00 126.208 132.247 6.039 1 68.0 68.0 69.0 68.0 DH-81 0.9646 14.5 75.0 

"""' RESULTS ****" 

DRY GAS METER ORIFICE DRY GAS METER ORIFICE 

Corrected Nominal Calibration Factor Calibration Factor 

Corrected Volumes Volume Volume Y dH@ 

Vm(std) Vm(std) Vcr(std) Vcr(std) Vcr Value Variation Value Value Variation 

cu.ft liters cu.ft liters cu.ft number number in.H2O mm H20 in.H2O 

4.903 138.8 5.040 142.7 5.177 1.028 0.003 2.033 51.63 -0.085 

5.363 151.8 5.526 156.5 5.675 1.030 0.005 2.068 52.53 -0.050 

4.917 139.2 5.055 143.1 5.191 1.028 0.002 2.149 54.57 0.031 

5.819 164.8 5.950 168.5 6.111 1.023 -0.003 2.157 54.80 0.040 

6.044 171.1 6.157 174.4 6.324 1 1 1.019 -0.007 1 1 2.183 55.44 0.065 

~ AVERAGE Y = 1.026 

Note: The acceptable variance for the individual values of thre calibration factor Y 

is + or - 0.02 from the average. 

~ The acceptable variance for the individual values of dH@, the orifice 

differential pressure in inches of H20 that equates to 0.75 cfm of air 

~ at 68 F and 29.92 in. Hg, is + or - 0.2 from the average 

~ 

SIGNED: ///~ //~ • 

*4 . -z 

2.118 = AVERAGE dH 

q 6. 
DAVIS & FLOYD, INC. 

Environmental Services Division 

~ 816 E Dur s t St 

Greenwood, South Carolina 29649 

EPA METHOD 5 

r~ Meter Box Calibration 

Post-Test Orifice Method 

Meter Box M 3 

Date: 03-05-1999 

Calibrator: MBW 

Barometric Pressure: 29.14 

Critical Vacuum: 13.75 

Volume Initial Temps Final Temps Actual Ambient 

dH Time Initial Final Total Inlet Outlet Inlet Outlet Orifice K Vacuum Temp 

in. H20 min cu.ft cu.ft cu.ft dog F deg F deg F deg F Serial No. Factor in. H d F 

1.20 10.00 514.996 520.368 5.372 69.0 69.0 70.0 70.0 55 0.4328 21.0 73.0 

2.00 7.00 520.368 525.368 5.000 70.0 70.0 71.0 70.0 63 0.5656 19.0 73.0 

3.80 6.00 525.368 531.145 5.777 71.0 70.0 73.0 71.0 73 0.7768 16.5 73.0 

MRRM RESULTS 

DRY GAS METER ORIFICE DRY GAS METER ORIFICE 

Con-ected Nominal Calibration Factor Calibration Factor 

Con-ected Volumes Volume Volume Y dH@ 

Vm(std) Vm(std) Vcr(std) Vcr(std) Vcr Value Variation Value Value Variation 

cu.ft liters cu.ft liters (cu.ft) (number number in.1-12O mm H20 in.H2O 

5.231 148.1 5.463 154.7 5.664 1.044 0.007 2.183 55.45 0.032 

4.872 137.9 4.997 141.5 5.182 1.026 -0.012 2.128 54.06 -0.023 

5.643 159.8 5.883 166.6 6.100 1.042 0.005 2.142 54.40 -0.009 

~ 

AVERAGE Y = 1.038 

Note: The acceptable variance for the individual values of the calibration factor Y 

is + or - 0.02 from the average. 

~ The acceptable variance for the individual values of dHo, the orifice 

~ differential pressure in inches of H20 that equates to 0.75 cfm of air 

at 68 F and 29.92 in. Hg, is + or - 0.2 from the averrage 

~ 

μ~ SIGNED: - 

~ 

2.151 = AVERAGE dH 

q ~p 
DAVIS & FLOYD, INC. POST TEST CALIBRATIONS 816 E. Durst St. 

BAROMETER,THERMOCOUPLES Greenwood, South Carolina 29649 

Environmental Services BALANCE CALIBRATION (864) 229-5211 

CLIENT: ~L DATE: a ^ :5—•_ (~ CHECKED BY:: 

BAROMETER 

REFERENCE BAROMETER (M) F-M +/- 0.1 in.Hg 

(MERCURY IN GLASS) FIELD BAROMETER (F) 

TO MEET CRITERION 

7 ~ • 

THERMOCOUPLES 

REFERENCE 

TEMPERATURE SET POINT 

METER BOX _ ~!; 

THERMOCOUPLE 

READING 

+/- 2 DEGREES F 

TO MEET CRITERION 

REFERENCE 

THERMOCOUPLE CALIBRATOR 

ALTEK-NIST CERTIFIED 

SERIAL No.22-K-2100F 

Set Points 

Zero 

Avg. Stack Temp Degrees F ~ 

Avg. Stack Temp. + 50 Degrees F ~ ~ ✓ 

Avg. Stack Temp. — 50 Degrees F 

ANALYTICAL BALANCE CALIBRATION 

L

.~ Balance name: Sartorius SERIAL No.:5052299 

Classification Of Standard weights: Type S 

0.5000 G 1.O00OG 10.00OOG 50.00OOG 100.0000 G Analyst 

DATE 

~ — ~0 0- 000 o /O 0• Gc700 

c~ 

ri 

~ ..J 

~ 

n~ 

. Y 

q1 
x 

wil 

NLN CA'16"T16H, 

LABORATORY 

v/ in Tolerance 3c OLd of Tolerance Calibration Data 

End of Datasheet 

Calibration Standards 

V NIST Traceable # Instniment ID# Description Model Calibration Date Date Due 

1000007183 01-0044 Calibrator 5500A-WISC300 05 JAN IM 05 JAN 2000 

Davis Instruments • 4701 Mount Hope Drive • Baltimore, Maryland 21215 • Phone: 410.358.3900 • Fax: 410.358.0252 
~s 

.~ ~ 

..~ A. 

cauanAnoN 

IVAIM~~AiN. 

u►eoenmmr 

Instrument Identification 

~ 

~ 

~ 

Davis & F(oyd Incorp. PO# : 980507 

220638 Ref# : 289668 

Instrument Id: 8397 SO#: 4933 

Noun: Thermocouple Calibrator Model: 22-K2100F 

Mfr: Altek Serial #: 243976 

Accuracy: :l; 3°F ( below 32°F) 

t0.1%ofRdgt1°F(restofrange) 

-~ 

~ f'ertificatinn Tnfnrmatinn 

~ Reason.For Service: Calibration 

~ Type Of Calibration: Normal 

As Found Condition: In Tolerance 

~ As Left Condition: Left As Found 

~ Procedure: 33K5-4-15-1 : 

Remarks: 

Thermocouple Simulator Calibrator 

Technician: Jozef Sedlacek 

Cal Date: 08 FEB 99 

Cal Due: 08 FEB 00 

Temperature: 23.0 °C 

Humidity: ' 28.0 % 

a'l 

The instrument(s) listed on this certification have been ealibrated against standards traceable to the National Institute oJStandards and 

Technology (NIST), derived jrom ratio rype measurements. or compared to nationally or internatlonally recognized coirsensus standards. 

~ A calibration uncertalnty rutio oj4:1 was maintained unless otherwise stated. 

~ 

Davis Instruments quality system complies wlth appGcable requirements ojANSI/NCSL Z540-1-1994 and ISO 9002:1994(E) 

7 All results contained within this certification relate only to item(s) calibrated. Tbls certificate shall not be reproduced except in jull 

~ and with the ivritten consent ojDavts Instruments. 

~ a.pproved By: ~ 

~ . 

v/ In Toleranoe ic out of Toaeranoe Calibration Data : 

Range Nominal As Found 

.. 

As Left Min 'Max 

, ,_. _, a F ~ . '-, ~ _ ~ 

, : -(~{ -'~ Q ..;• , 

r. • ~ . T~et~perature +'^t.i ~~ + . , .... ' 

 - - 

0.0 -0.6 ✓ As found -3.0 3.0 

100.0 100.0 ✓ Asfound 98.9 101.1 

200.0 201.1 ✓ As found 198.8 201.2 

300.0 300.1 ✓ Asfound 298.7 301-3 

400.0 398.8 ✓ As found 398.6 401.4 

500.0 500.0 ✓ As found 498.5 • 501.5 

600.0 601.2 ✓ As found 598.4 601.6 

700.0 700.1 ✓ As found 698.3 701.7 

800.0 801.6 ✓ As found 798.2 801.8 

900.0 900.1 ✓ As found 898.1 901.9 

Davis Instruments • 4701 Mount Hope Drive • Balumore, Maryland 21215 • Phone: 410.358.3900 • Fax: 410.358.0252 ql 
CERTIFICATE OF CALIBRATION 

This is to certify that your Altek Unit has been calibrated using standards whose accuracies are 

traceable to the National lnstitute of Standards and Technology within the limits of the NIST 

Calibration Services. Actual records pertaining to these standards are on file and are available 

for examination. 

CertiTied by: Altek Industries Corp. Recommended Recalibration: Annually 

Model Number Z F Factory Calibration Date2-1—\Q h O t 1 

Calibration Due Calibration Technician -,~ 

Setial Number I ~I~) IIIII ~I ~III IIII ~II In Sernce Date 

243976 ,F CONFOR1v>ITt ~ 

The above signatute for Altek Industries Corp., 210 Commeroe Drive, Rnchestet; NY 14623 USA 

` ` . _ E 

Declares that the equipment specified complies with standatds EN50081-1 and EN50082-1. 

The product complies with the cssential requiremenu of the EMC Directive 89/3361EEC 

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Lahoratory Inxtnimcnt Scrvicc •-t(13 Campbcll Avcnuc • Landrum SC 29356 • (864)457-4878 

Report of Balance Calibration 

~ Customer: Date: j(o Mg~~ qg Due: neex On 

Uaiiiufacttuer Model Serial Location 

I Capacity 11,, I Resolution nI ,,,, e I H44 I 

Off- Center test Front Back Left Right 

Reading — p r6 0.Gb Zo . o 9 

Zero return 13 1 

Accuracy/Linearity test Precision test 

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Trace# Weight Reading Zero return Reading Zero return 

~ Comment n tolerance as found YES NO In tolerance as left YES NO 

l

ialuation 

~ NIST Traceability numbers 1= SC8802181 m 2= SC9104191 m 3= SC9009241 m 

4= SC9502151 m 5= SC9506261 m , 

Technician 
19 . 1265 0 . 1285 0 . 1285 0. 1290/ :/ 0 . 0010 

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1 

1 1 *1111# 
2600 Bull Street 

Columbia, SC 29201-1708 

COMMISSIONER: 

Douglas E. Bryant April 30, 1999 

BOARD: 

John H. Burriss 

Chairman 

William M. Hull, Jr., MD 

Vice Chairman Palmetto Brick Company 

Roger Leaks, Jr. P.O. Box 430 

Secretary Cheraw, South Carolina 29520 

Mark B. Kent Attention: Mr. Henry Moore, VP Mfg. 

Cyndi C. Mosteller 

Brian K. Smith 

Rodney L. Grandy 

Dear Mr. Moore, 

Enclosed is ar.v's .dsummary of the results of the source tests at the indicated facility. 

This sllmmary includes the emission rates and operating parameters of the source(s) tested. 

Please review the corrections made in the Visibles (Method 9) section and note that these 

changes have not affected the compliance status of the source(s) tested. 

Note: Following the review of the analytical data submitted to the Bureau, I found that Clayton 

Laboratory Services did not meet all the EPA Reference Method 26A requirements. 

The following method parameters were lacking in the final report: 

Sec ion 5.2, C'alibratiori- Inject the appropriate series of calibration standards ... both 

before and after the injection of the QC check sample, reagent blanks, and field 

samples. This allows cornpensation for any instrument drift occurring during 

sample analysis. 

2.Section 4.3.3.2:Betweera injections of the appropriate series of calibration standards, 

inject in duplicate the reagent blanks and field samples. 

The Bureau evaluates test results on a case by case basis. Considering the concentrations 

of Hydrogen Fluoride were low and finding that Clayton Laboratory Services had 

demonstrated good laboratory and matrix spike recoveries, this Bureau will accept 

the Hydrogen Fluoride resuAts. However, in the future, failure to follow all method 

requirements may be grounds for the rejection of all final results. 

1o~ 
r 

Mr. Henry 1Vloor.e 

April 30, 1999 

Page Two 

Please review this data and if I can be of further assistance in these matters please call me at 

(803) 898-4303. 

Sincerely, 

04XY,A V 

Anthony V. eeler 

Environmental Chemist 

Division of Air Compliance Management 

Bureau of Air Quality 

cc: Jerry Chalmers 

Annie Richardson 

Shawna Riddle 

Joseph Eller 

Don Smith, Pee Dee District 

Main File 

~ 1 pS 
Palmetto Brick Con-ipany Permit No. 0660-0021 

Lingl # 1&# 2 Id. No CA 

Cheraw, South Carolina 

Results - Tests of March 4, 1999 

Hvdrogen Fluoride (Method 26A) 

Test Production Capacityl Emissions Allowable 

# tons/hour % mg/m3 Lbs/hr Lbs/hr 

1 22.71 96.2 2.20 0.228 1.80 

2 22.71 96.2 2.00 0.207 1.80 

3 22.71 96.2 2.40 0.237 1.80 

Avg. 22.71 96.2 2.20 0.224 1.80 

1. Based on a process rate of 23.6 tons per hour of brick produced. 

Visibles (Method 9) Allowable 

Test # 3 % 

Minutes of Observation 30 

6 minute sets greater than std. 0 20 

Average Opacity - % 1 

Set Max/min opacity - % 4/0 

Operational Notes: 

1.Lingl # 1 temperatures ranged from 1982 F to 2021 F and averaged 2000 F during the tests. 

2. Lingl #2 temperatures ranged from 2040 F to 2050 F and averaged 2046 F during the tests. 

3. Fuel consumption consisted of natural gas; and No. 2 Fuel oil for flashing purposes. 

4. Dry Lime Sorption Scrubber minimum cvcle time was set at 8 minutes during the tests. 

5. Dry Lime Sorption Scrubber photohelic readings ranged from 1.0 to 1.7 inches of water and averaged 

13 inches of water during the tests. 

6. Dry Lime Sorption Scrubber fan Hertz ranged from 30.3 to 41.8 Hz and averaged 36.9 Hz during the tests. 

Status as Tested: 

S.C. DHEC- BAQ Permit No. 0660-0021-CA (Modeled Emission Rate for HF)........Compliance 

S.C. DHEC- BAQ Permit No. 0660-0021-CA (Visibles) ...................................Compliance 

cc: Jerry Chalmers 

Aruiie Richardson 

Shawna Riddle 

Joseph Eller 

Don Smith, Pee Dee District 

Main File 

Report Received: 03/26/99 

Review Complete: 04/30/99 

Reviewer: Anthon'/y U. Keeler dK 

I p lo 
, 

==•.1 ~- ! ~ = _ 

PROMOTE PROTECT PROSPER 

2600 Bull Street 

Columbia, SC 29201-1708 

COMMISSIONER: 

Douglas E. Bryant 

BOARD: 

John H. Burriss 

Chairman 

William M. Hull, Jr., MD 

Vice Chairman 

Roger Leaks, Jr. 

Secretary 

Mark B. Kent 

Cyndi C. Mosteller 

Brian K. Smith 

Rodney L. Grandy 

Apri122, 1999 

Palmetto Brick Company 

P.O. Box 430 

Cheraw, South Carolina 29520 

~ 

~~i✓~ ~~ J 

Attention: Mr. Henry Moore, VP Mfg. 

Dear Mr. Moore, 

A summary of the results of the source tests at the indicated facility is enclosed. This summary 

includes the emission rates and operating parameters of the source(s) tested. 

LY41e; Following the review of the analytical data submitted to the Bureau, I found that Clayton 

Laboratory Services did not meet all the EPA Reference Method 26A requirements. 

The following method parameters were lacking in the final report: 

1. Section 5.2,5_'alibration: Inject the appropriate series of calibration standards ... both 

before and after the injection of the QC check sample, reagent blanks, and field 

samples. This allows compensation for any instrument drift occurring during 

sample analysis. 

2. S.ection 4.3.3.2: Between injections of the appropriate series of calibration standards, 

inject in duplicate the reagent blanks and field samples. 

The Bureau evaluates test results on a case by case basis. Considering the concentrations 

of Hydrogen Fluoride were low and finding that Clayton Laboratory Services had 

demonstrated good laboratory and matrix spike recoveries, this Bureau will accept 

the Hydrogen Fluoride results. However, in the future, failure to follow all method 

requirements may be grounds for the rejection of all final results. 

`01 
. . , - - 

Mr. Henry Moore 

Apri122, 1999 

Page Two 

Please review this data and if I can be of further assistance in these matters please call me at 

(803) 898-4303. 

Sincerely, 

ox" \1 IQo" 

Anthony V. Keeler 

Environmental Chemist 

Division of Air Compliance Management 

Bureau of Air Quality 

cc: Jerry Chalmers 

Beth Boland 

Shawna Riddle 

Joseph Eller 

Don Smith, Pee Dee District 

Main File 

1 006 
. I . 

Palmetto Brick Company Permit No. 0660-0021 

Lingl # 1&# 2 Id. No CA 

Cheraw, South Carolina 

Results - Tests of March 4, 1999 

Hvdrol4en Fluoride (Method 26A) 

Test Production Capacityl Emissions Allowable 

# tons/hour % mg/m3 Lbs/hr Lbs/hr 

1 22.71 96.21 2.20 0.228 1.80 

2 22.71 96.2 2.00 0.207 1.80 

3 22.71 96.2 2.40 0.237 1.80 

Avg. 22.71 96.2 2.20 0.224 1.80 

1. Based on a process rate of 23.6 tons per hour of brick produced. 

Visibles (Method 9) Allowable 

Test # 3 % 

No. of 6 Min. Sets 5 

Sets greater than std. 0 

Average Opacity - % 4 20 

Set Max/min opacity - % 25/0 

Operational Notes: 

1. Lingl # 1 temperatures ranged from 1982 F to 2021 F and averaged 2000 F during the tests. 

2. Lingl 42 temperatures ranged from 2040 F to 2050 F and averaged 2046 F during the tests. 

3. Fuel consumption consisted of natural gas; and No. 2 Fuel oil for flashing purposes. 

4. Dry Lime Sorption Scrubber minimum cycle time was set at 8 minutes during the tests. 

5. Dry Lime Sorption Scrubber photohelic readings ranged from 1.0 to 1.7 inches of water and averaged 

1.3 inches of water during the tests. 

6. Dry Lime Sorption Scrubber fan Hertz ranged from 30. 3to 41.8 Hz and averaged 36.9 Hz during the tests. 

Status as Tested: 

S.C. DHEC- BAQ Permit No. 0660-0021-CA (Modeled Emission Rate for HF) ........ Compliance 

S.C. DHEC- BAQ Permit No. 0660-0021-CA (Visibles) ...................................Compliance 

cc: Jerry Chalmers 

Beth Boland 

Shawna Riddle 

Joseph Eller 

Don Smith, Pee Dee District 

Main File 

Report Received: 03/26/99 

Review Complete: 04/22/99 

Reviewer: Ant~~y~V. Keeler 

\o 0~