## SAFETY DATA SHEET



# CPAR LCC O

Page 1 of 

### 8

1. IDENTIFICATION

Material N ame : Long Chain Chlorinated Olefin (LCC O ) 

### Revision Date : 11

- 14

- 12

W

- 50 AO 48 % chlorine (Cl) by weight

W

- 40AO 43% chlorine (Cl) by weight



### Chemical D escription : Alkanes, C 24

- 28 , chloro

CAS # 

### : 1402738

- 52

- 6



### Product Use: Lubri cant Additive, Flame Retardant



### Manufacturer I nformation : Trinity Manufacturing, Inc. 11 EV Hogan Drive

Hamlet, NC, 28345, USA

910

- 582

- 5650

CHEMTREC (U.S. and Canada) 1

- 800

- 424

- 9300 (For emergencies occurring while in transportation)

CHEMTREC (Outside the U.S.) 1

- 703

- 527

- 0585



### 2. HAZARDS IDENTIFICATION

GHS Classification This product does not have health or physical hazards that meet the classification criteria

under the OSHA Hazard Communication GHS scheme

. This product does not have health, physical, or environmental hazards that meet the

classification criteria under the United Nations (UN) GHS scheme . However, it may have potential to persist in the aquatic environment, therefore the Hazard Statement and Precautionary Statements proscribed by the UN GHS for classification under Category 4 of

Hazardous to the Aquatic Environment

– Long

- Term Hazard, are included bel ow.



### Signal Word None

GHS Hazard Statement

• H413

– May cause long lasting harmful effects to aquatic life

GHS Precautionary

Statements • P273

– Avoid release to the environment

.

• P501

– Dispose of contents/container in accordance with government regulations

and in accordance with manufacturer instructions in Section 13 of this

SDS.



### 3. COMPOSITION / INFORMATION ON INGREDIENTS

Components Synonyms CAS Number % by Weight

Chlorinated Alkenes

40

- 52 % chlorine by weight Long Chain Chlorinated

Olefin 1402738

- 52

- 6 99

Epoxidized Soybean Oil (Stabilizer) 8013

- 07

- 8 1

* The stabilizer does not contribute to the classification of this product

.

## SAFETY DATA SHEET



# CPAR LCC O

Page 2 of 8



### 4. FIRST AID MEASURES

Inhalation Move to fresh air. Get medical attention, if needed.



### Eye Contact Hold eyelids apart and flush eyes with plenty of water for at least 1 5 minutes. If irritation persists

, get medical attention.



### Skin Contact Wash with soap and water. Get medical attention if irritation develops or persists.



### Ingestion Have victim rinse mouth thoroughly with water. Do not induce vomiting without medical advice. If ingestion of a large amount does occur, seek medical attention.



### Most Important Symptoms/Effects, Acute and Delayed Repeated or prolonged exposure may cause slight irritation of eyes and skin of susceptible persons. Inhalation of vapors in high concentration may cause irritation of the respiratory

system.



### Indication of

Immediate Medical Attention or Special

Treatment This product does not have health hazards that require special first aid measures

. If you feel

unwell, seek medical advice (show the label or SDS where possible).



### Notes to Physi ci an Treat symptomatically

.



### 5. FIRE FIGHTING MEASURES

Suitable Extinguishing

Media Water Fog. Dry Chemical, Foam



### Unsuitable Extinguishing

Media High volume water jet. If use water jet as an extinguisher, this will spread the fire

.



### Specific Hazards Arising

From the Chemical Irritating and toxic gases or fumes may be released during a fire.

Containers may explode when heated. May burn, but does not ignite readily.



### Hazardous Combustion

Products Hydrogen chloride

, carbon oxides



### Protective Equipment and Precautions for Firefighters In event of fire, wear self

- contained pressure

- demand breathing apparatus with full protective gear

. 

### Fire Fighting Equipment/Instructions Use water spray to cool unopened containers. Move containers from fire area, if you can

do so without risk.



### 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Keep unnecessary personnel away. Ensure adequate ventilation. Use personal protective equipment. Avoid touching spilled materials.



### Methods for Containment ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Prevent t his material from contaminating soil or from entering sewage an d drainage systems that lead to waterways.



### Methods for Cleaning Up Spills Wear appropriate protective equipment and clothing during clean

- up . Should not be

released into the environment.



### Large Spills Stop the flow of material, if safe to do so. Dike the spilled material, if possible. Dike far ahead of liquid spill for later disposal. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Absorb with earth, sand or other non

- combustible

material and transfer to contain ers for later disposal. Following product recovery, use oil absorbent to collect any residual material.

## SAFETY DATA SHEET



# CPAR LCC O

Page 3 of 8

Small Spills Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove

residual contamination.



### Environmental Precauti ons Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Do

not contaminate water.



### Other Information Never return spills in original containers for re

- use. For waste disposal, see Section 13.



### 7. HANDLING AND STORAGE

Precautions for Safe Handling DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Avoid prolonged or repeated skin contact with this material. Wash hands after handling and before eating. Avoid breathing va pors or mists of this product. Wear personal protective equipment. Avoid release to the environment. Handle and open container with care.



### Conditions for Safe Storage , including incompatibilities Keep away from heat, sparks, and flame. Store in a coo l dry place. Keep container

closed when not in use.



### 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure G uidelines : Exposure Limits for this product have not been established. Avoid repeated or prolonged exposure to vapor or mist without appropriate respiratory protection.



### Engineering Controls : Under normal conditions of use, natural v entilation should effectively remove and prevent buildup of any vapor/mist/fume/dust generated from the handling of this product.



### Personal P rotective E quipment :

Eye / Face Protection W ear safety glasses with side

- shields

. If splashes are likely to occur, wear a face shield with safety glasses.



### Skin Protection Normal work clothing (long sleeved shirts and long pants) is recommended. If splashes are likely to occur, use apron or impervious suit, such as a Tyvek coverall. If liquid contact is likely to occur, manufacturer recommends nitrile gloves (ex: N

- DEX Nitrile).



### Respiratory Protection No personal respiratory protective equipment normally required. If mist is g enerated (heating, spraying) and engineering controls are not sufficient, wear NIOSH

- approved organic vapor respirator with (R or P) particulate filter for oil mist.



### Hygiene Considerations Handle in accordance with good industrial hygiene and safety pract ice.



### 9. PHYSICAL & CHEMICAL PROPERTIES

Appearanc e: Clear, y ellow to dark yellow

Physical S tate: Liquid

Odor : S light

Odor T hreshold : Not available

pH : Not applicable

Melting / Freezing Point: Not applicable

Boiling Point: > 4 00 °C

Boiling Point Range Not available

Flash Point: > 450 °F (232 °C) Cleveland Open Cup

## SAFETY DATA SHEET



# CPAR LCC O

Page 4 of 8
Evaporation Rate: Not available

Flammability Will decompose if involved in fire conditions

Flammability limits in Air, Not available

Lower and Upper % by Volume:

Auto

- I gnition T emperature : Not available.

Vapor P ressure : Very low. Not available

Vapor D ensity : Not av ailable

Volatility: (% Loss, 25 hours) 0.8 @ 10 0 °C estimated

Specific Gravity 1. 2 0 g/cm 3

Relative Density (lbs/gal): 10. 2

Solubility ( in water) : Very low

. <0.000005 g/l @ 20 °C

Partition Coefficient : n

- octanol/water: See Section 12.

Decomposition Temperature: Not available

Viscosity SUS @ 210 °F 230

Viscosity Poises @ 77 °F 110

Stability: 0.5

Saturated Vapor Concentration: Not available

Molecular F ormula : C n H 2n+2

- y Cl y n=24

- 28

Molecular Structure: CH 3 (CH 2 CHCl) 9 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 3 (representative)

Flash P oint C lass : 

### Class IIIB Combustible (NFPA)

Oxidi z ing P roperties : None



### 10. CHEMICAL STABILITY & REACTIVITY INFORMATION

Reactivity Not reactive.



### Chemical Stability Stable at normal conditions

. 

### Pos sibility of Hazardous

Reactions Will not occur.



### Conditions to Avoid: High temperatures.



### Incompatible Materials: Strong oxidizing agents, reducing agents.



### H azardous Decomposition

Products Thermal decomposition can lead to release of irritating gases and vapors

- hydrogen chloride gas, carbon oxides.



### 11. TOXICOLOGICAL INFORMATION

Likely Routes of Exposure Skin contact, eye contact, inhalation , ingestion (skin is predominant route of exposure in workplace)



### Signs and Symptoms of Exposure Repeated or prolonged exposure may cause irritation of eyes and skin in sensitive

persons . Inhalation of vapors in high concentration may cause irritation of respiratory

system.

## SAFETY DATA SHEET



# CPAR LCC O

Page 5 of 8 Acute or Delayed Effects:

Eyes Contact with eyes may cause slight irritation.



### Skin Prolonged and/or repeated skin contact may result in mild irritation or redness

.



### Inhalation May cause slight irritation of respiratory tract. Avoid breathing vapors or mists of this product

.



### Ingestion Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause injury.



### Chronic Effects From Short and Long Term Exposure :

Specific Target Organ Toxicity • No data available for repeated skin exposure

.

• Liver ( enlargement ) is predominant target in animal studies.

• Kidney nephritis is als o identified as possible target 

### Respiratory or Skin

Sensitization • A vailable data is inconclusive

.



### Mutagenicity (germ cell) • No data available for this product , but it is predicted that LCC O s are not mutagenic



### Reproductive Effects • No ef fects on fertility is expected.

• Slight increase in implantation loss at 5,000 mg/kg/day, rabbit for C22

– 26, 43% Cl



### Endocrine Disruption • No data available

.



### Toxicology Studies:

Acute Toxicity Low acute toxicity has been observed for inhalation or dermal routes. Oral studies on representative products are listed below:

LOAEL, Rat, oral, 90 day 100 mg/kg/day

, for repeated dose toxicity (liver) for LCCP, 43% Cl



### NOAEL, Rat, oral, 14 day 3,000 mg/kg/day

, for repeated dose toxicity (liver)



### NOAEL, Mouse, oral, 2 year 5,000 mg/kg/day

Carcinogenicity

This product is not listed by or considered to be a carcinogen by IARC, NTP, OSHA , or ACGIH

. An increased incidence of malignant lymphoma in male mice was reported at the highest dose tested (5,000 mg/kg/day) for

C 23 avg, 43% Cl



### 12. ECOLOGICAL INFORMATION

There is no specific ecological information for the two LCCO product s . Information provided below is representative of the carbon

chain range and percent of chlorination in the product.



### Ecotoxicity: E cologically significant impacts may have potential to occur if released to water and

sediment. Although there is no established acute aquatic toxicity for this product , they

m ay cause long lasting harmful effects to aquatic life due to studies that they do not readily biodegrade and may therefore p ersist in the environment

.



### Aquatic Toxicity: • C22

- 26, 42% wt. Cl

, 96h LC50 >5,000 mg/l

, Bleak fish species

, No effects seen at solubility.

• C18

- 26, 49% wt. Cl

, 91

- day LC0 >3,400 mg/kg

, Bleak, No effects seen at solubility.

• C>20, 48

– 54% wt. C

, l 96h LC50 >300 mg/l, Bluegill Sunfish

, No effects seen at

## SAFETY DATA SHEET



# CPAR LCC O

Page 6 of 8

solubility.

• C20

- 30, 4 2% wt. Cl

, 96h LC50 >770 mg/l Rainbow Trout , No effects seen at solubility.

• C>20, 43% wt. Cl

, No adverse effects seen over 48 hours, daphnia magna (does not meet Marine toxicity criteria)



### Terrestrial Toxicity No data available.



### Persistence and Degradability: (Environmental Fate) • U nlikely to be readily or inherently biodegradable

. Assumed to be potentially persistent, as a result.

• No data a vailable on degradation in soil or fate in atmosphere.

• Atmospheric half

- life is estimated 20 to 25 hours



### Bioaccumulative Potential: Not considered to be bioaccumulative

. 

### Mobility in Soil: No data available.



### Other Adverse Effects: Ozone Deple tion Potential

– not determined



### Partition Coefficient (n

- octanol/water) Log K

ow = 10.3 is representative value

Koc = 2.77 × 10 8 l/kg is representative value



### BCF: BCF for LCCPs is considered to be <2,000 l/kg. Thus it is extrapolated that LCC O s are unlikely to meet the bioaccumulative criteria as well

.



### 13. DISPOSAL CONSIDERATIONS

Waste C odes Waste codes should be assigned by the user based on the application for which the product

was used.

Disposal I nstructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not

allow this material to drain into sewers/water supplies. This product, in its present state,

when discarded or disposed of, is not a hazardous waste according to Federal regulations (40

CFR 261.4 (b)(4)).

Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Dispose in

accordance with all applicable regulations.

Waste from R esidues and Dispose of in accordance with local regulations.

Unused Products

Contaminated P ackaging Do not re

- use empty containers for other substances

. Empty containers should be taken to an approved waste handling site for recycling or disp osal or returned to the manufacturer.



### 14. TRANSPORT INFORMATION

DOT (United States) Not regulated as hazardous material.

TDG (Canada) Not regulated as dangerous goods.

IMDG (Water) Not regulated as dangerous goods.

IATA (Air) Not regulated as dangerous goods.



### 15. REGULATORY INFORMATION

US FEDERAL REGULATIONS :

OSHA : This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard

Communication Standard, 29 CFR 1910.1200

## SAFETY DATA SHEET



# CPAR LCC O

Page 7 of 8

DEA : Not regulated under any of the 4 DEA regulations below.

List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2)

DEA Essential Chemical Code Number Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures
(21 CFR 1310.12(c)) DEA Exempt Chemical Mixtures Code Number

CERCLA R eportable Q uantity (RQ) : None

SARA EPCRA 312/313 : Not applicable

Immediate Hazard

– No Delayed Hazard

- No

Fire Hazard

– No

Pressure Hazard

– No Reactivity Hazard

- No

Section 302

- E xtremely H azardous No

S ubstance

Section 311

- H azardous Chemical No

EPA High Production Volume List No

Inventory S tatus for : Alkanes, C 24

- 28 , chloro

* "Yes" indicates that all components of this pr oduct comply with the inventory, requirements administered by the governing country(s).

Country or R egion Inventory N ame On I nventory *

United States & Puerto Rico

...... Toxic Substances Control Act (TSCA) Inventory 8(b)

............. No, PMN submitted

Canada

................................ ....... Domestic Substances List (DSL)

................................ ................................ ......... No

................................ ................... ................................ ........... Yes for CAS 85535

- 86

- 0 For Alkanes, C18

- 28, chloro

Canada

................................ ....... Non

- Domestic Substances List (NDSL)

................................ ............................. No

Mexico

................................ ....... No Established List

................................ ................................ ........... Not Applicable

STATE REGULATIONS:

California This product does not contain a chemical known to the State of California to cause cancer,
birth defects or other reproductive harm

.

CANADA:

CEPA Schedule 1 List No for this product.

WHMIS Not controlled

.



### 16. OTHER INFORMATION

HMIS® R ating : HMIS® is a registered trade and service mark of the American Coatings Association

Health: 1

Flammability: 1

Physical hazard: 0

Personal protection: B

NFPA Rating:

Health: 1

Flammability: 1

Instability: 0

## SAFETY DATA SHEET



# CPAR LCC O

Page 8 of 8

ACRONYMS :

ACGIH American Conference of Governmental Industrial Hygien ist s

BCF Bioconcentration Factor

CAS Chemical Abstracts Service

CEPA Canadian Environmental Protection Act

CERCLA Comprehensive Environmental Response, Compensation, and Liability Act (Superfund)

CFR Code of Federal Regulations

CHEMTREC Chemical Transportation Emergency Center

DOT United States Dep artment of Transportation

EPCRA Emergency Planning and Community Right

- to

- Know

GHS Globally Harmonized System

IARC International Agency for Research on Cancer

IMDG International Maritime Dangerous Goods

K

oc 

### The value of Koc indicates where a chemical is likely to end up

- surface water or ground water. For example, a chemical with large Koc values tend to adsorb onto soil and has potential for contaminating surface water

. LC 50 

### Lethal Concentration

- median dose at which 50% of test animals die from inhalation

LCCO Long Chain Chlorinated Olefin

LCCP Long Chain Chlorinated Paraffin

LOAEL Lowest Observed Adverse Effect Level
Log K

ow 

### Octanol

- Water Partition Coefficient

. The higher the number, the mo re bioavailable
( prefer s partition ing into soil organic matter rather than water).

NFPA National Fire Protection Association

NOAEL No Observed Adverse Effect Level

NTP Normal Temperature and Pressure: 760 mmHg and 20oC or 1 atm and 68o F

NTP National Toxicology Program

OSHA Occupational Health and Safety Administration

RCRA Resource Conservation and Recovery Act

SARA US EPA Superfund Amendments and Reauthorization Act

SDS Safety Data Sheet (formerly known as MSDS

– Material Safety Data Sheet)

TDG Transport of Dangerous Goods (Canada)

TSCA Toxic Substances Control Act

US United States

USA United States of America

WHMIS Workplace Hazardous Materials Identification System (Canada)

Disclaimer:

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the dat e of its publication. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release. The information in the sheet was written based on the best knowledge and experience currently available.

Issue Date: 11

- 14

- 12

Version: North America

Changes: Not appli c abl e as this is original version

For information on this SDS, contact: 910

- 419

- 6566