## ATTACHMENT HEADER SHEET
Attachment Number 019 Attachment Name Attachment 19 Chemical #4(PLZT) MVSDS



## Associated PMN Section Number N/A Does not contain CBI



## Report Number CONSi 10317786855351

### Attachment 19
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### Lanthanum Lead Titanium Zirconium Oxide MSDS REPORT#

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### CONS110317786855351 

## MATERIAL SAFETY DATA SHEET
SECTION 1- PRODUCT INFORMATION Manufacturer's Name: Lockheed Martin Health 3 497 Electronics Parkway Flammability 0 Syracuse, N.Y. 13088 Reactivity I Emergency Telephone (315) 456-3723 8am-5pm -EST (315) 456-2917 24 Hours

Information Telephone: (315) 456-3723
Chemical Name: Lanthanum Lead Titanium Zirconium Oxide Trade Name: PLZT, LM-55, LM-21, High Coupling PZT
SECTION II- HEALTH HAZARD IDENTIFICATION
EMERGENCY OVERVIEW Caution may cause eye, skin and respiratory tract irritation. May cause damage to the nervous and immune systems, kidneys, blood andproduce adverse reproductive effects. May cause cancer. ROUTES OFEXPOSURE Inhalation: Inhalation ofdust or fume may cause respiratory irritation. Ingestion: Ingestion ofdust may result fromhand to mouth contact or ingestion ofdust SkinContact: Contact with skin may cause irritation. SkinAbsorption: Notexpected from dusts. Eye Contact: Dust or fume contact with eyes maycause irritation.
POTENTIAL HEALTH EFFECTS SingleAcute Overexposure: Mayproduce eye, skin andrespiratory tract irritation, effects onthe nervous system and kidneys, gastrointestinal distress and anemia. Common symptoms are a loss of appetite, nausea, vomiting, stomach cramps, constipation, anxiety, difficulty in sleeping, fatigue, moodiness, headache, jointor muscle aches and decreased sexual drive. Extreme overexposure may lead to tremors, convulsions, paralysis, stupor, coma anddeath. Chronic, Prolonged or Repeated Children have enhanced absorption and retention ofingested lead and are Overexposure particularly sensitive to the chronic effects oflead, with slowed cognitive development andreduced growth. May produce effects on the blood, nervous and immune systems, blood pressure, kidneys as well as skin and pulmonary inflammatory tissue masses, rickets-like bone deformities, decreased sperm count and spontaneous abortion. Common symptoms are a loss ofappetite, metallic taste

### Attachment 19
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### Lanthanum Lead Titanium Zirconium Oxide MSDS REPORT#

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### CONS110317786855351
inthe mouth, anxiety, constipation, nausea, pallor, fatigue, 

### weakness, insomnia, headache, nervous irritability, muscle andjoint painor soreness, fine tremors, numbness, dizziness, hyperactivity and abdominal pain. Maternal overexposure may produce lowbirth weight, birth defects and slowed postnatal neurobehavioral development in theoffspring. Extreme overexposure may lead to vomiting, drowsiness, stupor,poor memory, restlessness, irritability, tremor, convulsions, coma anddeath. Muscular weakness may develop and progress to paralysis observed as 'wrist-drop" and/or "foot-drop". Component Carcinogenicity Lead Compounds Inorganic IARC: Group 2A
- Probably Carcinogenic to Humans. NTP: Reasonably anticipatedto be a humiancarcinogen

EMERGENCY AND FIRST AID PROCEDURES Inhalation: Ifaperson breathes large amounts ofthischemical, move the exposed person to fresh air at once. Ifbreathing has stopped, perform artificial respiration. Keep the affected person warm and atrest. Getmedical attention as soon as possible. Ingestion: Ifthis chemical has been swallowed, get medical attention immediately. Skin Ifthis chemical contacts the skin, promptly flush thecontaminated skin with soap and water. Ifthis chemical penetrates the clothing, promptly remove theclothing and flush the skin with water. Ifirritation persists after washing, getmedical attention. Eye Ifthis chemical contacts the eyes, immediately wash (irrigate) theeyes with large amounts ofwater, occasionally lifting thelower andupper lids. Get medical attention immediately.

NOTE TOPHYSICIAN': Damage to the central nervous system in general and thebrain (encephalopathy) inparticular is one ofthemost severe forms oflead poisoning. The most severe, often fatal, form ofencephalopathy may be preceded by vomiting, a feeling ofdullness progressing to drowsiness and stupor, poor memory, restlessness, irritability, tremor, and convulsions. It may arise suddenly with the onset ofseizures, followed bycoma, and death. There is a tendency for muscular weakness to develop at the same time. This weakness may progress to paralysis often observed as acharacteristic "wrist drop" or "foot drop" and is a manifestation ofa disease to thenervous systemcalled peripheral neuropathy. Those chronically intoxicated may have gingival lead lines, i.e. blue discoloration.
SECTION III- HAZARDOUS INGREDIENTS Material orComponent C.A.S. # Weight % TLV-TWA mg/m3 8hr PEL- TW A mg/m3 8hr Lanthanum Lead Titanium Zirconium Oxide 1227908-26-0 100 0.05(as Pb) 0.05(as Pb)

This product is considered a lead compound. Pleaserefer to the Code ofFederal Regulations CER Title 29 1910.1025 Lead Standard for industrial workers.

### Attachment 19
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### Lanthanum Lead Titanium Zirconium Oxide MSDS REPORT#

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### CONS110317786855351

SECTION IV
- PHYSICAL DATA Boiling Point at 760 mm Hg: NA Specific Gravity (H20 =1): 7.6 -8.1 Melting Point: 1350C Solubility in H20 (g/l): 0.05 Vapor Pressure (mm Hg): % NA Evaporation Rate: NA Volatiles by Volume: NA Molecular Weight 321 to 347 Appearance and Odor: Yellow or Tan or Reddish Tan Powder, Odorless SECTION V
- FIREAND EXPLOSION HAZARD DATA LEL: NA UEL: NA FlashPoint Flammable NA Auto ignition Temperature NA Limits: Extinguishing NA Media Water, C02 and Dry Chemical Special FireFighting Procedures: Wear full body protective clothing, full facepiece and NIOSHIMSHA approved Positive pressure self-contained breathing apparatus. Unusual Fireand Explosion Hazards: Fume, vapor and/ordust may occur and are considered toxic andrespiratory irritants. May react with strong oxidizing agents.
SECTION VI- REACTIVITY DATA Stability Stable to 800 C Incompatibilities: Strong Acids, Conditions to Avoid: Do not heatin the presence ofstrong acids as dissolution oflead may occur. Hazardous Decomposition Products: Elevated temperatures (above 800 C) orfire may produce lead oxide fume, vapor or dust. Hazardous Polymerization: Will not occur. SECTION VII- SPECIAL PROTECTION Respiratory Protection: A NIOSHJ approved respirator withP100 filters shallbe worn whenairborne exposures may exceed OSHAIACGLH permissible air concentrations. Protective Gloves: Latex or nitrile gloves required. Eye Protection: Safety glasses arerecommended for protection against exposures to dusts. Protective Clothing: Full body clothing shouldbe wornto prevent potential exposure to skin. If leadPEL or TLV is exceeded, protective clothing shall be provided in accordance with OSHA Standard 29 CFR 1910.1025. Ventilation: Sufficient mechanical ventilation (general and/or local exhaust) shall be provided to maintain exposures below permissible air concentrations. SECTION VIII- SPILL OR LEAK PROCEDURES Steps to Take intheEvent ofa Spill or Release

### Attachment 19
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### Lanthanum Lead Titanium Zirconium Oxide MSDS REPORT#-CONS110317786855351

In the event ofa spill or leak, avoid inhalation of

### dustor fume. Gloves, goggles and respirators should be worn during clean-up. Small spills should be vacuumed using a high efficiency filter vacuum. Do not use dry sweeping or compressed air. Waste Disposal Method: Waste shall be collected anddisposed ofin accordance with all local, state and federal regulations. Waste may also be recycled in accordance with local, state and federal regulations.. Neutralizing Materials: NotApplicable SECTION IX
- SPECIAL PRECAUTIONS Food and drink shall not be consumed in areas ofuse. Tobacco products and cosmetics shall not be used in areas ofuse. Always wash thoroughly after handling. Dirty shoes andclothing should notleave the workplace. Storethis product away from all foods andfeeds. Do not reuse containers. Containers may retainproduct residues. All labeled precautions mustbe observed. This product is intended for industrial use only. Keep away from children. Store in dry area. Avoid contact with acids and bases. SECTION X
- TRANSPORTATION INFORMATION UN Number
- UN229 1 Proper Shipping Name
- Lead Compound, soluble, ni.o.s. Hazard Class
- 6.1 Packing Group
- PGIII SECTION XI- DEFINITIONS TLV/TWA Threshold Limit Value
- TimeWeighted Average (American Conference of Governmental Industrial Hygienists) PEL Permissible Exposure Limit (Occupational Safety &Health Administration LEL Lower Explosive Limit UEL Upper Explosive Limit NA Not Applicable NE NotEstablished PREPARED BY: Lockheed Martin 497 Electronics Parkway Syracuse, New York 13088 MSDS Revision Date: 1/2011 The information accumulated and set forthherein is believed to be accurate as ofthe date hereof.Lockheed Martin makes no warranty with respect thereto and disclaims all liability fromreliance thereon. Recipients are advised to confirm in advance that theinformation is current, applicable, and suitable for their particular circumstances.