ATTACHMENT HEADER SHEET

Attachment Number 019

Attachment Name

Attachment 19 Chemical #4 (PLZT) MVSDS

Associated PMN Section Number

N/A

Does not contain CBI

Report Number

CONSi 10317786855351
Attachment 19 - Lanthanum Lead Titanium Zirconium Oxide MSDS

REPORT# - CONS110317786855351

MATERIAL SAFETY DATA SHEET

SECTION 1 - PRODUCT INFORMATION

Manufacturer's Name: Lockheed Martin Health 3

497 Electronics Parkway Flammability 0

Syracuse, N.Y. 13088 Reactivity I

Emergency Telephone

(315) 456-3723 8am-5pm -EST

(315) 456-2917 24 Hours

Information Telephone: (315) 456-3723

Chemical Name: Lanthanum Lead Titanium Zirconium Oxide

Trade Name: PLZT, LM-55, LM-21, High Coupling PZT

SECTION II - HEALTH HAZARD IDENTIFICATION

EMERGENCY OVERVIEW

Caution may cause eye, skin and respiratory tract irritation. May cause

damage to the nervous and immune systems, kidneys, blood and produce

adverse reproductive effects. May cause cancer.

ROUTES OF EXPOSURE

Inhalation: Inhalation of dust or fume may cause respiratory irr itation.

Ingestion: Ingestion of dust may result from hand to mouth contact or ingestion of dust

Skin Contact: Contact with skin may cause irritation.

Skin Absorption: Not expected from dusts.

Eye Contact: Dust or fume contact with eyes may cause irritation.

POTENTIAL HEALTH EFFECTS

Single Acute Overexposure: May produce eye, skin and respiratory tract irritation, effects on the nervous system

and kidneys, gastrointestinal distress and anemia. Common symptoms are a loss of

appetite, nausea, vomiting, stomach cramps, constipation, anxiety, difficulty in

sleeping, fatigue, moodiness, headache, joint or muscle aches and decreased sexual

drive. Extreme overexposure may lead to tremors, convulsions, paralysis, stupor,

coma and death.

Chronic, Prolonged or Repeated Children have enhanced absorption and retention of ingested lead and are

Overexposure particularly sensitive to the chronic effects of lead, with slowed cognitive

development and reduced growth. May produce effects on the blood, nervous and

immune systems, blood pressure, kidneys as well as skin and pulmonary

inflammatory tissue masses, rickets-like bone deformities, decreased sperm count

and spontaneous abortion. Common symptoms are a loss of appetite, metallic taste
Attachment 19 - Lanthanum Lead Titanium Zirconium Oxide MSDS

REPORT# - CONS110317786855351

in the mouth, anxiety, constipation, nausea, pallor, fatigue, weakness, insomnia,

headache, nervous irritability, muscle and joint pain or soreness, fine tremors,

numbness, dizziness, hyperactivity and abdominal pain. Maternal overexposure

may produce low birth weight, birth defects and slowed postnatal neurobehavioral

development in the offspring. Extreme overexposure may lead to vomiting,

drowsiness, stupor, poor memory, restlessness, irritability, tremor, convulsions,

coma and death. Muscular weakness may develop and progress to paralysis

observed as 'wrist-drop" and/or "foot-drop".

Component Carcinogenicity

Lead Compounds Inorganic

IARC: Group 2A - Probably Carcinogenic to Humans.

NTP: Reasonably anticipated to be a humian carcinogen

EMERGENCY AND FIRST AID PROCEDURES

Inhalation: If a person breathes large amounts of this chemical, move the exposed person to

fresh air at once. If breathing has stopped, perform artificial respiration. Keep the

affected person warm and at rest. Get medical attention as soon as possible.

Ingestion: If this chemical has been swallowed, get medical attention immediately.

Skin If this chemical contacts the skin, promptly flush the contaminated skin with soap

and water. If this chemical penetrates the clothing, promptly remove the clothing

and flush the skin with water. If irritation persists after washing, get medical

attention.

Eye If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large

amounts of water, occasionally lifting the lower and upper lids. Get medical

attention immediately.

NOTE TO PHYSICIAN': Damage to the central nervous system in general and the brain (encephalopathy) in particular

is one of the most severe forms of lead poisoning. The most severe, often fatal, form of encephalopathy may be

preceded by vomiting, a feeling of dullness progressing to drowsiness and stupor, poor memory, restlessness,

irritability, tremor, and convulsions. It may arise suddenly with the onset of seizures, followed by coma, and death.

There is a tendency for muscular weakness to develop at the same time. This weakness may progress to paralysis often

observed as a characteristic "wrist drop" or "foot drop" and is a manifestation of a disease to the nervous system called

peripheral neuropathy. Those chronically intoxicated may have gingival lead lines, i.e. blue discoloration.

SECTION III- HAZARDOUS INGREDIENTS

Material or Component C.A.S. # Weight % TLV-TWA mg/m3 8hr PEL- TW A mg/m3

8hr

Lanthanum Lead Titanium

Zirconium Oxide 1227908-26-0 100 0.05(as Pb) 0.05(as Pb)

This product is considered a lead compound. Please refer to the Code of Federal

Regulations CER Title 29 19 10.1025 Lead Standard for industrial workers.
Attachment 19 - Lanthanum Lead Titanium Zirconium Oxide MSDS

REPORT# - CONS110317786855351

SECTION IV - PHYSICAL DATA

Boiling Point at 760 mm Hg: NA Specific Gravity (H20 =1): 7.6 -8.1

Melting Point: 1350C Solubility in H20 (g/l): 0.05

Vapor Pressure (mm Hg): % NA Evaporation Rate: NA

Volatiles by Volume: NA Molecular Weight 321 to

347

Appearance and Odor: Yellow or Tan or Reddish Tan Powder, Odorless

SECTION V - FIRE AND EXPLOSION HAZARD DATA

LEL: NA UEL: NA

Flash Point Flammable NA Auto ignition Temperature NA

Limits: Extinguishing NA

Media Water, C02 and Dry Chemical

Special Fire Fighting Procedures: Wear full body protective clothing, full face piece and NIOSHIMSHA

approved Positive pressure self-contained breathing apparatus.

Unusual Fire and Explosion Hazards: Fume, vapor and/or dust may occur and are considered toxic and respiratory

irritants. May react with strong oxidizing agents.

SECTION VI - REACTIVITY DATA

Stability Stable to 800 C

Incompatibilities: Strong Acids,

Conditions to Avoid: Do not heat in the presence of strong acids as dissolution of lead may occur.

Hazardous Decomposition Products: Elevated temperatures (above 800 C) or fire may produce lead oxide fume,

vapor or dust.

Hazardous Polymerization: Will not occur.

SECTION VII - SPECIAL PROTECTION

Respiratory Protection: A NIOSHJ approved respirator with P100 filters

shall be worn when airborne exposures may exceed OSHAIACGLH permissible air

concentrations.

Protective Gloves: Latex or nitrile gloves required.

Eye Protection: Safety glasses are recommended for protection against exposures to dusts.

Protective Clothing: Full body clothing should be worn to prevent potential exposure to skin. If lead PEL

or TL V is exceeded, protective clothing shall be provided in accordance with OSHA

Standard 29 CFR 1910.1025.

Ventilation: Sufficient mechanical ventilation (general and/or local exhaust) shall be provided to

maintain exposures below permissible air concentrations.

SECTION VIII- SPILL OR LEAK PROCEDURES

Steps to Take in the Event of a Spill or Release
Attachment 19 - Lanthanum Lead Titanium Zirconium Oxide MSDS

REPORT# -CONS110317786855351

In the event of a spill or leak, avoid inhalation of dust or fume. Gloves, goggles and

respirators should be worn during clean-up. Small spills should be vacuumed using a

high efficiency filter vacuum. Do not use dry sweeping or compressed air.

Waste Disposal Method:

Waste shall be collected and disposed of in accordance with all local, state and

federal regulations. Waste may also be recycled in accordance with local, state and

federal regulations. .

Neutralizing Materials: Not Applicable

SECTION IX - SPECIAL PRECAUTIONS

Food and drink shall not be consumed in areas of use. Tobacco products and

cosmetics shall not be used in areas of use. Always wash thoroughly after handling.

Dirty shoes and clothing should not leave the workplace. Store this product away

from all foods and feeds.

Do not reuse containers. Containers may retain product residues. All labeled

precautions must be observed. This product is intended for industrial use only. Keep

away from children.

Store in dry area. Avoid contact with acids and bases.

SECTION X - TRANSPORTATION INFORMATION

UN Number - UN229 1

Proper Shipping Name - Lead Compound, soluble, ni.o.s.

Hazard Class - 6.1

Packing Group - PG III

SECTION XI- DEFINITIONS

TLV/TWA Threshold Limit Value - Time Weighted Average (American Conference of

Governmental Industrial Hygienists)

PEL Permissible Exposure Limit (Occupational Safety & Health Administration

LEL Lower Explosive Limit

UEL Upper Explosive Limit

NA Not Applicable

NE Not Established

PREPARED BY: Lockheed Martin

497 Electronics Parkway

Syracuse, New York 13088

MSDS Revision Date: 1/2011

The information accumulated and set forth herein is believed to be accurate as of the date hereof. Lockheed Martin

makes no warranty with respect thereto and disclaims all liability from reliance thereon. Recipients are advised to

confirm in advance that the information is current, applicable, and suitable for their particular circumstances.