## From: Keith Barnett/RTP/USEPA/US To: Cortney_Higgins@omb.eop.gov Cc: Charlotte Bertrand/DC/USEPA/US@EPA Date: 07/31/2010 11:28 PM Subject: Emailing: MEMO Organic HAP 8

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‐ 1 0.pdf

I put together the actual docket memo. You can delete the previous version.

Keith W. Barnett USEPA/OAQPS/SPPD/MMG Mail Code D243

‐ 02 Research Triangle Park, NC 27711 919

‐ 541

‐ 5605 barnett.keith@epa.gov (See attached file: MEMO Organic HAP 8

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## MEMORANDUM

TO: Portland Cement NESHAP Docket

FROM: Keith Barnett

Subject: Summary of Organic HAP Test Data

Date: August 6, 2010

Attached is information on the organic HAP contribution to totla THC emission for Portland cement kilns.

## O rganic HAP Laney, Michael N.

to: Keith Barnett 04/23/2010 03:36 PM Cc: Barrett Parker Show Details

Keith,

Based on the revised table, the percent of THC represented by the listed organic HAP is 35%.

The previous table was revised with the following changes:

- “BDL” was replaced by the reported detection limits.

- Added one additional row of data for Ash Grove, Montana.

- Revised some of the previous concentrations after QA of the conversions (from the Test Data Details tab).

Also, note the following:

- the THC concentrations for Ash Grove Seattle (38.87) and Ash Grove Durkee (30.84) are from different test reports than those containing the organic HAP results. Is that a problem?

- phenol and hexane results are all BDL

– indicates there is not much there; they could be dropped.

- Naphthalene detection limits are very high for 3 out of 5 kilns.

Michael Laney RTI International TEL: 919

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- 3413 FAX: 919

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- 3420 EMAIL: mnl@rti.orgOrganicHAP 042310_kdb.xls7/31/2010 Company Location Kiln Type Average THC (as propane), ppm @ 7% O2 Formaldehyde, ppmvd@7%O2 Benzene, ppmvd@7

%O2 Toluene, ppmvd@ 7%O2 Ethyl benzene, ppmvd@ 7%O2 m,pXylene, ppmvd@ 7%O2 Styrene, ppmvd@ 7%O2 o-Xylene, ppmvd@ 7%O2 Acetaldehyde, ppmvd@7%O 2 Phenol, ppmvd@ 7%O2 Hexane, ppmvd@7%O 2 Naphthal
ene, ppmvd@ 7%O2 Total organic HAP, ppmvd@ 7%O2 Org. HAP as % of THC Napthalene Method Moisture Ash Grove Cement (2000) Montana City, MT wet <0.41 0.06 <0.01 <0.005 <0.005 <0.05 <0.014 <0.28 <0.04 <5.52 6.38 M320 33 Moisture is an FTIR interference; higher MDL Ash Grove Cement (1994) Montana City, MT wet 0.41 0.04 <0.02 <0.019 <0.019 <0.019 <0.019 0.14 34.50 Ash Grove Inkom, ID wet <0.37 0.16 0.15 <0.02 <0.02 <0.03 <0.04 <0.37 <0.06 <4.90 6.12 M320 33 Moisture is an FTIR interference; higher MDL Lafarge Ravena, NY wet 25.29 <0.28 0.59 0.037 0.007 0.91 3.59 M23 28 Different method; lower MDL Ash Grove (2002) Durkee, OR PH/PC 3.71 0.57 0.23 0.10 0.28 0.27 <0.24 <0.003 1.69 45.54 M320 13 Lower moisture; lower MDL? California PC (2005, 2) Colton, CA long dry 1.32 0.46 0.06 <0.02 <0.01 <0.02 <0.04 <0.63 <0.63 <0.10 3.30 California PC (2005, 1) Colton, CA long dry 1.66 0.30 0.05 <0.02 <0.01 <0.02 <0.03 <0.50 <0.50 <0.08 3.15 Ash Grove Seattle, WA PH/PC 38.87 3.59 0.13 0.05 0.01 0.03 0.05 <0.06 <0.28 <0.30 <5.56 10.07 25.90 M320 13 ??? Lehigh Glen Falls, NY PH/PC 4.79 <1.32 <1.32 <1.32 <1.32 <2.96 <1.32 14.33 California PC (2002) Colton, CA long dry 3.81 0.71 0.30 <0.02 <0.02 <0.02 <0.04 <0.77 <0.39 <0.09 6.16 Lafarge Sugar Creek, MO PH/PC 7.55 0.59 0.40 0.35 0.98 0.54 0.41 10.82 Ash Grove (2001) Durkee, OR PH/PC 30.84 18.88 0.21 0.09 <0.014 0.25 0.24 <0.023 <0.093 19.81 64.22 Average 6.91 34.75

* Values denoted with "<" are method detection limits. Maybe drop the naphthalene FTIR data (M320)?

Note that the THC value for Ash Grove, Seattle is from a different test report (1996). Note that the THC value for Ash Grove, Durkee (2001) is from a different test report (2006).

## Organic HAP test data Laney, Michael N.

to: Keith Barnett 09/29/2008 09:14 AM Cc: "Branscome, Marvin R." Show Details

Keith,

I compiled all the organic HAP test data I could find that we got with the 114 ICR responses. In most of the cases, I was able to convert the data
to ppmvd@7%O2. I ended up with about 15 useable data sets. In some cases, only one organic HAP was reported, but in others several organic HAP were measured. Where they also reported THC, I included that. I incorporated these data into the table we have that summarizes the THC test data. In just a couple of instances did I find organic HAP data for kilns in our THC data sets. I was able to calculate the HAP concentration as a percentage of THC for 5 sets of data (two tests were for the same kiln, but the results of the two tests were quite different, so I kept them separate for now). Lots of the totals are below 5 ppm, with the average being 3.4. The average percentage of THC that is HAP is 24%, pretty close to the earlier report of 23%.

Michael Laney Environmental Engineering Environmental Health & Safety Division RTI International TEL: 919

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- 3413 FAX: 919

- 316

- 3420 EMAIL: mnl@rti.org9/29/2008 Summary of Organic HAP Test Data

OrganicHAP 092908.xls P age 1 C ompany Location Kiln Kiln Type Raw Mill Average THC (as propane), ppm @ 7% O2 Formalde hyde, ppmvd@7 %O2 Benzene, ppmvd@7 %O2 Toluene, ppmvd@7 %O2 Ethyl benzene, ppmvd@7 %O2 m,pXylene, ppmvd@7 %O2 Styrene, ppmvd@7 %O2 o-Xylene, ppmvd@7 %O2 Acetaldeh yde, ppmvd@7 %O2 Phenol, ppmvd@7 %O2 Hexane, ppmvd@7 %O2 Naphthale
ne, ppmvd@7 %O2 Total organic HAP, ppmvd@7 %O2 Org. HAP as % of THC Ash Grove Cement Montana City, MT 1 wet no 0.41 ND 0.06 ND ND ND ND ND ND ND 0.06 14.68 Ash Grove Cement Midlothian, TX 3 wet no 13.83 Ash Grove Cement Leamington, UT 1 preheater/calciner yes 14.14 Ash Grove Cement Seattle, WA 1 preheater/calciner yes 14.23 2.78 0.13 0.05 2.96 20.80 Ash Grove Cement Inkom, ID 2 wet no 20.50 Ash Grove Cement Inkom, ID 1 wet no ND 0.16 0.15 ND ND ND ND ND ND ND 0.31 Ash Grove Cement Durkee, OR 1 preheater/calciner yes 30.84 15.54 0.21 0.09 0.25 0.24 ND ND 16.33 52.94 Ash Grove Cement (new) Durkee, OR 1 preheater/calciner yes 3.72 0.29 0.23 0.1 0.28 0.27 0.002 1.172 31.51 Holcim Trident Kiln #1 wet no 5.56 Holcim Mason City Kiln #3 long dry no 6.78 Holcim Mason City Kiln #2 long dry no 11.07 Holcim Artesia, MS wet no 18.35 Holcim Theodore, AL Kiln #1 preheater/calciner no 23.74 Holcim Holly Hill, SC preheater/calciner yes 28.48 Holcim Portland, CO Kiln #4 preheater/calciner yes 44.97 Holcim Midlothian, TX Kiln #1 preheater/calciner yes 51.59 Holcim Devil's Slide, UT Kiln #1 preheater/calciner yes 51.91 Holcim Midlothian, TX Kiln #2 preheater/calciner yes 62.82 Holcim Clarksville, MO 121.01 Holcim Dundee Kiln #1 and wet no 748.15 Lafarge Whitehall, PA Kiln 2 preheater no 8.33 Lafarge Whitehall, PA Kiln 3 preheater no 10.81 Lafarge Ravena, NY 1 wet no 25.26 Lafarge Ravena, NY 2 wet no 25.26 Lehigh Evansville, PA Kiln2 preheater/calciner no 1.69 Lehigh York, PA White Cem wet no 1.74 Lehigh Evansville, PA Kiln1 preheater/calciner no 2.18 Lehigh Union Bridge E02-001 preheater/calciner yes 6.83 Lehigh Redding, CA 1 preheater yes 13.62 Lehigh Waco, TX 39 wet no 18.97 Lehigh Mitchell, IN 1 preheater no 49.09 Lehigh Mitchell, IN 2 preheater no 49.09 Lehigh Mason City 8 preheater/calciner yes 50.53 Lone Star Industries Oglesby, IL 3 long dry no 2.25 Lone Star Industries Maryneal 3 preheater no 30.16 Lone Star Industries Pryor 3 long dry no 125.24 Lone Star Industries Pryor 2 long dry no 149.75 Lone Star Industries Pryor 1 long dry no 173.83 TXI Midlothian Kiln E2-22 preheater/calciner 3.96 Lehigh Glen Falls, NY 1 PH/PC yes 3.29 3.29 Lafarge Tulsa 2 long dry no 0.04 0.04 Lafarge Tulsa 1 long dry no 0.02 0.02 California PC Colton 1 long dry no 3.53 0.71 0.3 ND ND ND ND ND ND ND 4.54 California PC Colton 1 long dry no 1.47 0.3 0.05 ND ND ND ND ND ND ND 1.82 California PC Colton 2 long dry no 1.22 0.46 0.06 ND ND ND ND ND ND ND 1.74 Lafarge Davenport, IA 1 preheater/calciner 0.15 0.15 Lafarge Sugar Creek, MO 3 preheater/calciner yes 5.57 0.59 0.4 0.35 0.98 0.54 0.41 8.84 Lehigh Leeds, AL 5 preheater 6.8 6.8

Test data in other units Lafarge Ravena 1&2 wet no 55.2 0.51 0.92 Average HAP % of THC 24.17

Mean (ppmvd@7%O2) 3.433714 Median (ppmvd@7%O@ 1.78

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Page 1 O rganicHAP 092908.xls Organic HAP Test Data 9/26/2008

Plant/Kiln Lehigh, Glen Falls, NY Test date 2002 Kiln ID Kiln 1 Kiln type PC RM On Moisture, fraction 0.17 %O2 11 Formaldehyde ppmw 2.9 Formaldehyde ppmvd@7%O2 3.38 Acetaldehyde, acrylonitrile, hexane, phenol ND RM Off Moisture, fraction 0.19 %O2 6.73 Formaldehyde ppmw 3 Formaldehyde ppmvd@7%O2 2.39 Acetaldehyde, acrylonitrile, hexane, phenol ND Total Formaldehyde, Wtd avg, ppmvd@7%O2 3.29 Formaldehyde, Wtd avg, tpy 0.95 Total organic HAP 3.29

Lehigh, Glen Falls, NY Test date 2006 Kiln ID Kiln 1 Kiln type PC RM On %O2 11 Moisture, fraction 0.139 NMHC ppm@7% O2 2.5 NMHC ppmvd@7% O2 2.15 NMHC lbs/hr 0.98 RM Off %O2 5.90 Moisture, fraction 0.2006 NMHC ppm@7% O2 3.5 NMHC ppmvd@7% O2 2.80 NMHC lbs/hr 1.53 Total NMHC Wtd Avg RM on/off, ppmvd@7%O2 2.22 NMHC Wtd Avg RM on/off, tpy 4.10

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Page 2 O rganicHAP 092908.xls Lafarge, Tulsa Test date 2002 Kiln ID Kiln 2 Kiln type Dry Moisture, fraction 0.1371 Formaldehyde, ppm@7%O2 0.051 Formaldehyde, ppmvd@7%O2 0.04 Formaldehyde, tpy 0.048

Kiln ID Kiln 1 Kiln type Dry Moisture, fraction 0.1292 Formaldehyde, ppm@7%O2 0.027 Formaldehyde, ppmvd@7%O2 0.02 Formaldehyde, tpy 0.028

California PC, Colton Test date 2002 Kiln ID Kiln 1 Kiln type Dry Moisture, fraction 0.04 %O2 13.43 Formaldehyde, ppmw 1.97 Formaldehyde, ppmvd@7%O2 3.53 Formaldehyde, tpy 4.56 Benzene, ppmvd 0.38 Benzene, ppmvd@7%O2 0.71 Benzene, tpy 2.19 Toluene, ppmvd 0.16 Toluene, ppmvd@7%O2 0.30 Toluene, tpy 1.11

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND Total organic HAP, ppmvd@7%O2 4.53

California PC, Colton Test date 2005 Kiln ID Kiln1 Kiln type Dry Moisture, fraction 0.06 %O2 12 Formaldehyde, ppmvw 1 Formaldehyde, ppmvd@7%O2 1.47 Formaldehyde, tpy 2.4 Benzene, ppmvd 0.19 Benzene, ppmvd@7%O2 0.30 Benzene, tpy 1.11 Toluene, ppmvd 0.03 Toluene, ppmvd@7%O2 0.05 Toluene, tpy 0.21

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND Total organic HAP, ppmvd@7%O2 1.81

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Page 3 O rganicHAP 092908.xls California PC, Colton Test date 2005 Kiln ID Kiln 2 Kiln type Dry Moisture, fraction 0.04 %O2 14 Formaldehyde, ppmvw 0.63 Formaldehyde, ppmvd@7%O2 1.22 Formaldehyde, tpy 1.54 Benzene, ppmvd 0.23 Benzene, ppmvd@7%O2 0.46 Benzene, tpy 1.42 Toluene, ppmvd 0.03 Toluene, ppmvd@7%O2 0.06 Toluene, tpy 0.19

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND Total organic HAP, ppmvd@7%O2 1.74

Ash Grove, Seattle Test date 2001 Kiln ID Kiln 1 Kiln type PC RM On Moisture, fraction 0.132 %O2 9.52 Benzene, ppmvd 0.1 Benzene, ppmvd@7%O2 0.12 Benzene, tpy 0.55 Toluene, ppmvd 0.04 Toluene, ppmvd@7%O2 0.05 Toluene, tpy 0.26 Formaldehyde, ppmvw 2.3 Formaldehyde, ppmvd@7%O2 2.44 Formaldehyde, tpy 5.63 Ethyl benzene,mp-xlyene, styrene ND RM Off Moisture, fraction 0.073 %O2 8.73 Benzene, ppmvd 0.21 Benzene, ppmvd@7%O2 0.24 Toluene, ppmvd 0.08 Toluene, ppmvd@7%O2 0.09 Formaldehyde, ppmvw 5.5 Formaldehyde, ppmvd@7%O2 5.82 Total Benzene, Wtd avg, ppmvd@7%O2 0.13 Toluene, Wtd avg, ppmvd@7%O2 0.05 Formaldehyde, Wtd avg, ppmvd@7%O2 2.78 Total organic HAP, ppmvd@7%O2 2.96

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Page 4 O rganicHAP 092908.xls Ash Grove, Montana City, MT Test date 2000 Kiln ID Kiln 1 Kiln type Wet %O2 (not reported. Used avg of 3 other wet kilns) 5.86 Benzene, ppmvd 0.06 Benzene, ppmvd@7%O2 0.06 Toluene, phenol, formaldehyde, naphthalene, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Ash Grove, Durkee, OR Date July 2001 Kiln Kiln Kiln type PC RM On Moisture, fraction 0.1768 %O2 6.03 Benzene, ppmvd 0.22 Benzene, ppmvd@7%O2 0.21 Toluene,ppmvd 0.1 Toluene,ppmvd@7%O2 0.09 m,p-Xylene, ppmvd 0.27 m,p-Xylene, ppmvd@7%O2 0.25 Styrene, ppmvd 0.26 Styrene, ppmvd@7%O2 0.24 Formaldehyde, ppmvw 20.2 Formaldehyde, ppmvw@7%O2 15.54 Phenol, naphthalene ND Total organic HAP, ppmvd@7%O2 16.34

Ash Grove, Durkee, OR Date April 2002 Kiln Kiln 1 Kiln type PC RM On Moisture, fraction 0.116266667 %O2 7.7 Benzene, ppmvd 0.22 Benzene, ppmvd@7%O2 0.23 Toluene, ppmvd 0.1 Toluene, ppmvd@7%O2 0.11 m,p-Xylenes, ppmvd 0.27 m,p-Xylenes, ppmvd@7%O2 0.28 Styrene, ppmvd 0.26 Styrene, ppmvd@7%O2 0.27 Formaldehyde, ppmvw 0.3 Formaldehyde, ppmvd@7%O2 0.28 Naphthalene, ppmvd 0.002 Naphthalene, ppmvd@7%O2 0.002 THC(M25A), ppmvd as propane 3.6 THC, ppmvd@7%O2 3.8

Volumetric flow rate dscfm 147929 wscfm 167391

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Page 5 O rganicHAP 092908.xls RM Off Moisture, fraction 0.1368 %O2 5.93 Benzene, ppmvd 0.22 Benzene, ppmvd@7%O2 0.20 Toluene, ppmvd 0.1 Toluene, ppmvd@7%O2 0.09 m,p-Xylenes, ppmvd 0.27 m,p-Xylenes, ppmvd@7%O2 0.25 Styrene, ppmvd 0.26 Styrene, ppmvd@7%O2 0.24 Formaldehyde, ppmvw 0.5 Formaldehyde, ppmvd@7%O2 0.40 Naphthalene, ppmvd 0.008 Naphthalene, ppmvd@7%O2 0.01 THC(M25A), ppmvd as propane 3.3 THC, ppmvd@7%O2 3.1

Volumetric flow rate dscfm 125600 wscfm 145505 Total Benzene, Wtd avg, ppmvd@7%O2 0.23 Toluene, Wtd avg, ppmvd@7%O2 0.10 m,p-Xylenes, Wtd avg, ppmvd@7%O2 0.28 Styrene, Wtd avg, ppmvd@7%O2 0.27 Formaldehyde, Wtd avg, ppmvd@7%O2 0.29 Naphthalene, Wtd avg, ppmvd@7%O2 0.002 Total organic HAP, ppmvd@7%O2 1.18 THC, ppmvd@7%O2 3.72 31.7 HAP% of THC

Ash Grove, Louisville, NE Date 2005 Kiln Kiln 2 Kiln type PC tpy Benzene,g/sec, baseline 0.023 0.7 Benzene, g/sec, TDF 0.021 0.7

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Page 6 O rganicHAP 092908.xls Lafarge, Whitehall,PA Date March 2006 Kiln Kiln 3 Kiln type PH %O2 5.3 Total THC as methane, ppmvd 64.9 Total THC as propane, ppmvd@7%O2* 19.28 Benzene, ug/dscm@7%O2 143 Benzene, lb/hr 0.0287 Naphthalene, ug/dscm@7%O2 180 Naphthalene, lb/hr 0.0363 Methyl chloride, lb/hr 0.0355 Methyl bromide, lb/hr 0.0255 Acetone, lb/hr 0.00189 Methyl iodine, lb/hr 0.0112 Phenol, lb/hr 0.0517 2-Methylphenol, lb/hr 0.003 3&4-Methylphenol, lb/hr 0.007 Acetophenone, lb/hr 0.004 2-Methylnaphthalene, lb/hr 0.003 Acenaphthylene, lb/hr 0.002 Dibenzofuran, lb/hr 0.003 Diethyl phthalate, lb/hr 0.0004 Bis(2-ethylhexyl)phthalate, lb/hr 0.003 Benzoic acid, lb/hr 0.015 Total org HAP, lb/hr 0.23 *Converted THC methane to THC propane by dividing by 3.

Lafarge, Whitehall,PA Date Sept 2006 Kiln Kiln 2 Kiln type PH %O2 3.8 Total NMHC as Methane [VOC], ppmvd 22.9 Total NMHC as Methane [VOC], ppmvd@7%O2 18.7 Total NMHC as Methane [VOC], lb/hr 3.2

Kiln Kiln 3 Kiln type PH %O2 5.3 Total NMHC as Methane [VOC], ppmvd 11.4 Total NMHC as Methane [VOC], ppmvd@7%O2 10.2 Total NMHC as Methane [VOC], lb/hr 1.2

Lafarge, Seattle Date June 2000 Kiln Kiln Kiln type Wet Moisture, fraction 0.30 %O2 6.7 Benzene, ug/m3 2417 Benzene, lb/hr 0.726

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Page 7 O rganicHAP 092908.xls Lafarge, Ravena, NY Date February 2004 Kiln Kiln 1&2, common stack Kiln type Wet %O2 6.94 Moisture, fraction 0.286 Naphthalene, mg/M3@7%O2 0.0371 Naphthalene,lb/hr 0.0634 2-Methylnaphthalene, mg/M3@7%O2 0.209 2-Methylnaphthalene, lb/hr 0.291 Phenanthrene, mg/M3@7%O2 0.11 Phenanthrene, lb/hr 0.153 Total org HAP, mg/M3@7%O2 0.3561 Total org.HAP, lb/hr 0.5074 Total NMHC, ppmvd 21.82 Total NMHC, lb/hr 55.2 THC, ppmvd as propane 25.4 THC, ppmvd@7%O2 as propane 25.3 THC, lb/hr as propane 55.2 0.9 HAP% of THC

Lafarge, Davenport IA Date "March 2000 Kiln Kiln 1 Kiln type PC Moisture, fraction 0.11 %O2 9.8 Benzene, ppmv 0.15 Benzene, ppm@7%O2 0.17 Benzene, ppmvd@7%O2 0.15

Volumetric flow rate, dscfm 271587

Lafarge, Sugar Creek, MO Date August 2002 Kiln Kiln 3 Kiln type PC RM On (95% of time) tpy Moisture, fraction 0.14 %O2 (not reported, used avg. of 6 PC kilns) 9.2 Benzene, ppmvd 0.5 3.12 Benzene, ppmvd@7%O2 0.59 Toluene, ppmvd 0.34 2.46 Toluene, ppmvd@7%O2 0.40 Ethyl benzene, ppmvd 0.3 2.49 Ethyl benzene, ppmvd@7%O2 0.36 m,p-Xylenes, ppmvd 0.71 5.98 m,p-Xylenes, ppmvd@7%O2 0.84 Styrene, ppmvd 0.46 3.8 Styrene, ppmvd@7%O2 0.55 o-Xylene, ppmvd 0.35 2.95 o-Xylene, ppmvd@7%O2 0.41 Formaldehyde, ppmvw 5.4 14.92 Formaldehyde, ppmvd@7%O2 5.51

Volumetric flow rate, dscfm 122537 Volumetric flow rate, wscfm 141940

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Page 8 O rganicHAP 092908.xls RM Off (5% of time) tpy Moisture, fraction 0.15 %O2 (not reported, used avg of 4 PC kilns) 6.8 Benzene, ppmvd 0.62 0.19 Benzene, ppmvd@7%O2 0.61 Toluene, ppmvd 0.34 0.12 Toluene, ppmvd@7%O2 0.34 Ethyl benzene, ppmvd 0.27 0.11 Ethyl benzene, ppmvd@7%O2 0.27 m,p-Xylenes, ppmvd 3.71 1.54 m,p-Xylenes, ppmvd@7%O2 3.66 Styrene, ppmvd 0.4 0.16 Styrene, ppmvd@7%O2 0.39 o-Xylene, ppmvd 0.3 0.12 o-Xylene, ppmvd@7%O2 0.30 Formaldehyde, ppmvw 8.2 1.13 Formaldehyde, ppmvd@7%O2 6.88

Volumetric flow rate, dscfm 114961 Volumetric flow rate, wscfm 134567 Total tpy Benzene, ppmvd 0.51 3.31 Benzene, ppmvd@7%O2 0.59 Toluene, ppmvd 0.34 2.58 Toluene, ppmvd@7%O2 0.40 Ethyl benzene, ppmvd 0.30 2.6 Ethyl benzene, ppmvd@7%O2 0.35 m,p-Xylenes, ppmvd 0.86 7.52 m,p-Xylenes, ppmvd@7%O2 0.98 Styrene, ppmvd 0.46 3.96 Styrene, ppmvd@7%O2 0.54 o-Xylene, ppmvd 0.35 3.07 o-Xylene, ppmvd@7%O2 0.41 Formaldehyde, ppmvw 5.54 16.05 Formaldehyde, ppmvd@7%O2 5.57

Total all organic HAP, ppmd@7%O2 8.85 39.09

Lehigh, Leeds, AL Date April 2002 Kiln 5 Kiln type PH Moisture, fraction 0.1313 %O2 14.65 Formaldehyde, ppmvw 3.52 My calculation Formaldehyde, ppmvd (reported)?? 4.05 3.06 Formaldehyde, ppmvd@7%O2 9.0 6.8 Formaldehyde, lb/hr 3.66

Volumetric flow rate, dscfm 194295 Volumetric flow rate, ascfm 298076

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Page 9 OrganicHAP 092908.xls Ash Grove, Inkom, ID Date Sept/Oct 2000 Kiln Kiln 1 Kiln type Wet Moisture, fraction 0.3308 %O2 3.95 tpy Benzene, ppmvd 0.2 0.26 Benzene, ppmvd@7%O2 0.16 Toluene, ppmvd 0.18 0.27 Toluene, ppmvd@7%O2 0.15Formaldehyde phenol, naphthalene, hexane, ethyl benzene, m,p,oxylene, styrene ND Total organic HAP, ppmvd@7%O2 0.31

Volumetric flow rate, dscfm 24604 Volumetric flow rate, wscfm 36777

HAP MW

Formaldehyde 30 Benzene 78 Toluene 92 m,p-Xylene 106 Styrene 104 o-Xylene 106 Hexane 86 Phenol 94