# Patent

## Title
Liquid pavement marking compositions

## Abstract

Reference is made to commonly-assigned copending U.S. patent application Ser. No. 09/170,660, filed of even date herewith, U.S. Pat. No. 60,053,438 HEC) entitled Process for Making an Ink Jet Ink, by Romano et al., the teachings of which are incorporated herein by reference.

## Background
This invention relates to a process for making an ink jet ink using a hydrocarbon carrier and a polyamine/fatty acid condensation polymer dispersant to produce a dispersion characterized by nanometer-size pigment particles.

Ink jet printing is a non-impact method for producing images by the deposition of ink droplets on a substrate (paper, transparent film, fabric, etc.) in response to digital signals. Ink jet printers have found broad applications across markets ranging from industrial labeling to short run printing to desktop document and pictorial imaging. The inks used in ink jet printers are generally classified as either dye-based or pigment-based.

In pigment-based inks, the colorant exists as discrete particles. These pigment particles are usually treated with addenda known as dispersants or stabilizers which serve to keep the pigment particles from agglomerating and settling out of the carrier. Such a dispersant is necessary to produce a colloidally stable mixture and an ink that can be "jetted" reliably without clogging the print head nozzles.

Dispersing agents in an ink jet ink have the dual function of helping to break down pigments to sub-micron size during the milling process and of keeping the colloidal dispersion stable and free from flocculation for a long period of time. In general, dispersions suffer from poor colloidal stability due to particle agglomeration and/or sedimentation, thus limiting the usefulness of the dispersions in inks.

Although a wide variety of dispersing agents are known for pigmented ink jet inks, they are not without certain problems. For example, many dispersing agents are very selective as far as being able to disperse pigments to sub-micron size. In many instances, each class of pigments may require a specific dispersing agent. Another problem encountered with some polymeric dispersing agents is that they tend to impart an undesirably high viscosity to the resulting inks. Thus, there is a continuing need for improved dispersing agents for pigmented inks, especially for non-aqueous inks.

Dispersing agents for non-aqueous ink jet inks previously used include metal salts of styrene-acrylic copolymers, metal salts of sulfonated styrene-acrylic copolymers, phosphonium salts or quaternary ammonium salts of styrene-acrylic copolymers.

U.S. Pat. No. 5,679,138 relates to a process for preparing an ink jet ink wherein the pigment particle size distribution obtained is quite small. There is a problem with this process, however, in that the carrier medium is limited to water. It would be desirable to provide ink jet inks which employ non-aqueous carriers in order to avoid paper deformation upon printing. However, dispersing agents commonly used for aqueous dispersions generally do not work in non-aqueous dispersions.

WO96/24642 and WO97/15633 disclose the use of a polyamine/fatty acid condensation polymer dispersant in a non-aqueous ink jet pigmented ink. However, there is a problem with inks prepared by the milling method disclosed in these references in that the particle size of the pigment particles is larger than one would like. A smaller particle size dispersion is desirable in order to provide a wider color gamut.

It is an object of this invention to provide a method for making a non-aqueous, pigment dispersion for an ink jet ink with a low particle size in order to obtain better covering power and which would have less tendency to clog the ink jet nozzles. It is another object of this invention to provide a method for making a non-aqueous, pigment dispersion for an ink jet ink which employs a dispersant which enables the production of nanometer-size pigment particles.

These and other objects are achieved in accordance with this invention which relates to a process for making an ink jet ink comprising: polyamine/fatty acid condensation polymer dispersant; .mu.m; below about 100 nanometers (nm); pigment concentration suitable for ink jet printers.

The dispersant used in the process of the invention is highly effective in reducing pigment particles to a size of less than about 100 nm when milled in the presence of very fine milling media. The resulting dispersion is characterized by nanometer-size pigment particles. The dispersing agents employed are useful with a wide variety of pigments.

As noted above, the ink jet ink composition used in the process of the invention contains a polyamine/fatty acid condensation polymer dispersant. The dispersant is preferably used in a ratio of dispersant:pigment from about 0.1:1 to about 5:1. In a preferred embodiment, the ratio of dispersant:pigment is from about 0.5:1 to about 2:1.

In a preferred embodiment of the invention, the polyamine/fatty acid condensation polymer dispersant is poly(hydroxy stearate-co-ethyleneimine). These dispersants are available commercially as: hydrocarbon from Zeneca Inc.; and

In the present invention, any of the known pigments can be used. Pigments can be selected from those disclosed, for example, in U.S. Pat. Nos. 5,026427; 5,086,698; 5,141,556; 5,160,370; and 5,169,436, the disclosures of which are hereby incorporated by reference. The exact choice of pigments will depend upon the specific color reproduction and image stability requirements for the printer and application. The pigment must be totally insoluble in the carrier. For four-color printers, combination of cyan, magenta, yellow, and black (CMYK) pigments should be used. An exemplary four color set is bis(phthalocyanyl-alumino) tetraphenyl-disiloxane cyan, quinacridone magenta (p.r.122), Hansa.RTM. Brilliant Yellow 5GX-02 (p.y.74), and carbon black (p.b.7).

As noted above, the pigment particle size obtained using this process is below about 100 nm. This figure is understood to mean the 50.sup.th percentile value (half of the particles have a particle size below that value and half are above). Particle size distributions can be measured on diluted millgrind samples (about 50: 1) using a Leeds & Northrop Ultrafine Particle Analyzer (UPA).

The process of preparing inks from pigments commonly involves two steps: (a) a dispersing or milling step to break up the pigment to the primary particle, and (b) a dilution step in which the dispersed pigment concentrate is diluted with a carrier and other addenda to a working strength ink. In the milling step, the pigment is usually suspended in a carrier along with rigid, inert milling media less than about 100 .mu.m. The dispersing agent is added at this stage. Mechanical energy is supplied to this pigment dispersion, and the collisions between the milling media and the pigment cause the pigment to deaggregate into its primary particles.

There are many different types of materials which may be used as milling media, such as glasses, ceramics, metals, and plastics. In a preferred embodiment, the grinding media can comprise particles, preferably substantially spherical in shape, i.e., beads consisting essentially of a polymeric resin.

In general, polymeric resins suitable for use as milling media are chemically and physically inert, substantially free of metals, solvent and monomers and of sufficient hardness and resilience to enable them to avoid being chipped or crushed during milling. Suitable polymeric resins include crosslinked polystyrenes, such as polystyrene crosslinked with divinylbenzene, styrene copolymers, polyacrylates such as poly(methylmethacrylate), polycarbonates, polyacetals such as Derlin.RTM., vinyl chloride polymers and copolymers, polyurethanes, polyamides, poly(tetrafluoroethylenes), e.g. Teflon.RTM., and other fluoropolymers, high density polyethylenes, polypropylenes, cellulose ethers and esters such as cellulose acetate, poly(hydroxyethylmethacrylate), poly(hydroxyethyl acrylate), silicone containing polymers such a polysiloxanes and the like. The polymer can be biodegradable. Exemplary biodegradable polymers include poly(lactides), poly(glycolids) copolymers of lactides and glycolide, polyanhydrides, poly(imino carbonates), poly(N-acylhydroxyproline)-esters, poly(palmitoyl hydroxyproline) esters, ethylene-vinylacetate copolymers, poly(orthoesters), poly(caprolactones), and poly(phosphazines). The polymeric resin can have a density from 0.9 to 3.0 g/cm.sup.3. Higher density resins are preferred inasmuch as it is believed that these provide more efficient particle size reduction. Most preferred are crosslinked or uncrosslinked polymeric media based on styrene.

Milling can take place in any suitable grinding mill. Suitable mills include an airjet mill, a roller mill, a ball mill, an attritor mill and a bead mill. A high speed mill is preferred, such as those manufactured by Morehouse-Cowles, Hockmeyer, or Premier Mills.

By high speed mill is meant a milling device capable of accelerating milling media to velocities greater about 5 meters per second. The mill can contain a rotating shaft with one or more impellers. In such a mill the velocity imparted to the media is approximately equal to the peripheral velocity of the impeller, which is the product of the impeller rev/min and the impeller diameter. Sufficient milling media velocity is achieved, for example, in Cowles-type saw tooth impeller having a diameter of 40 mm when operated at 9,000 rev/min. The preferred proportions of the milling media, the pigment, the carrier and dispersing agent can vary within wide limits and depend, for example, upon the particular material selected and the size and density of the milling media, etc.

Batch Milling A slurry of <100 .mu.m milling media, carrier, pigment, and dispersing agent(s) is prepared using simple mixing. This slurry may be milled in conventional high energy batch milling processes such as high speed attritor mills, vibratory mills, ball mills, etc. This slurry is milled for a predetermined length of time to allow comminution of the active material to a minimum particle size. After milling is complete, the dispersion of active material is separated from the grinding media by a simple sieving or filtration.

The milling time can vary widely and depends upon the pigment, mechanical means and residence conditions selected, the initial and desired final particle size, etc.

The carrier can be any of the high boiling hydrocarbons such as isoparaffinic hydrocarbon solvents, e.g., Isopar-G.RTM. (Exxon Chemical Co.) or Exxsol.RTM. D130 from Exxon Chem. Co. Selection of a suitable solvent depends on the requirements of the specific application, such as viscosity, surface tension, drying time of the pigmented ink jet ink, and the type of receiver on which the ink will be printed. The amount of the carrier employed is in the range of about 20 to 40 weight %, preferably about 25 to about 35 weight %, based on the total weight of the slurry.

Ink Preparation.

In general, it is desirable to make the pigmented ink jet ink in the form of a concentrated millgrind, which is subsequently diluted to the appropriate concentration for use in the ink jet printing system. This technique permits preparation of a greater quantity of pigmented ink from the equipment. The millgrind is diluted with appropriate solvent to a concentration best for viscosity, color, hue, saturation density, and print area coverage for the particular application.

In the case of organic pigments, the ink may contain up to about 30% pigment by weight, but will generally be in the range of about 0.1 to 10%, preferably about 0.25 to about 5%, by weight of the total ink composition for most of the ink jet printing applications.

Acceptable viscosities, as determined using Brookfield apparatus and related methods are generally not greater than 20 centipoise, and are preferably in the range of about 1 to 15 centipoise.

The ink has physical properties compatible with a wide range of ejecting conditions, i.e., driving voltages and pulse widths for thermal ink jet printing devices, driving frequencies of the piezo element for either a drop-on-demand device or a continuous device, and the shape and size of the nozzle.

Ingredients, other than pigment(s), carrier and dispersing agent may be employed in the ink such as milling aids, dewetting agents, charge agents, thickeners, conductive enhancing agents, drying agents, etc.

The ink jet inks provided by this invention are employed in ink jet printing wherein liquid ink drops are applied in a controlled fashion to an ink receptive substrate, by ejecting ink droplets from plurality of nozzles, or orifices, in a print head of ink jet printers.

Commercially available ink jet printers use several different schemes to control the deposition of the ink droplets. Such schemes are generally of two types: continuous stream and drop-on-demand.

In drop-on-demand systems, a droplet of ink is ejected from an orifice directly to a position on the ink receptive layer by pressure created by, for example, a piezoelectric device, an acoustic device, or a thermal process controlled in accordance digital data signals. An ink droplet is not generated and ejected through the orifices of the print head unless it is needed. Ink jet printing methods, and related printers, are commercially available and need not be described in detail.

The ink jet inks provided by this invention are employed in ink jet printing wherein liquid ink drops are applied in a controlled fashion to an ink receptive layer substrate, by ejecting ink droplets from the plurality of nozzles, or orifices, in a print head of ink jet printers

Ink-receptive substrates useful in ink jet printing are well known to those skilled in the art. Representative examples of such substrates are disclosed in U.S. Pat. Nos. 5,605,750; 5,723,211; and 5,789,070 and EP 813 978 A1, the disclosures of which are hereby incorporated by reference.

The following examples illustrate the utility of the present invention.

A yellow dispersion was prepared by mixing the following ingredients: Co.) hydrocarbon solvent (Zeneca Inc.)

The above components were mixed and then milled in a 1 liter double walled vessel obtained from BYK-Gardner using a high energy laboratory dispersator manufactured by Premier Mill Corp. using a 4.0 cm. Cowles-type milling blade rotating at 7,000 rev/min. The mill was run for approximately 6 hours at room temperature. The ink concentrate was diluted with 100 g Isopar-G.RTM. solvent and mixed for few minutes before being separated from the milling media. The dispersion was separated from the milling media by filtering the millgrind through a 10-20 .mu.m KIMAX.RTM. Buchner Funnel obtained from VWR Scientific Products. Particle size distributions were obtained on diluted millgrind samples (about 50:1) using a Leeds & Northrop Ultrafine Particle Analyzer (UPA). The results obtained are a 50% median value. Particle size, as measured by UPA, are listed in Table 1 below.

A cyan dispersion was prepared by mixing the following ingredients: (Eastman Kodak Co.) milled as in Example 1 but using a 2-liter vessel and with a 5.0 cm. milling blade. The results are shown in Table 1 below.

Another cyan dispersion was prepared as follows:

The above ingredients were mixed and milled as in Example 1. The results are shown in Table 1 below.

A magenta dispersion was prepared by mixing the following ingredients:

The above ingredients were mixed and milled as in Example 1. The results are shown in Table 1 below.

Another magenta dispersion was prepared by mixing the following ingredients:

The above ingredients were mixed and milled as in Example 1. The results are shown in Table 1 below.

A black dispersion was prepared by mixing the following ingredients:

The above ingredients were mixed and milled as in Example 1 except milling for 2 hours. The results are shown in Table 1 below.

A black dispersion was attempted to be milled with the following ingredients:

The above ingredients were mixed and milling was attempted as in Example 1. However, milling was discontinued after 3 hours because of poor dispersion of the milling slurry.

Example 7 was repeated but using the control dispersing agents and pigments as listed in Table 1. __________________________________________________________________________ Particle Size Example Dispersant Pigment (nm) __________________________________________________________________________ 1       Solsperse .RTM. 13,940 Hansa .RTM. Brilliant Yellow 20 5GX-02 (p.y.74) 2 Hypermer .RTM.LP-6 Bis(phthalocyanylalumino)tetra 19 phenyl-disiloxane cyan 3 Solsperse .RTM. 13,940 Bis(phthalocyanylalumino)tetra 23 phenyl-disiloxane cyan 4 Hypermer .RTM.LP-6 Chemisperse CM1225 .RTM. 22 Magenta (p.r.122) 5 Solsperse .RTM. 13,940 Magenta (p.r.122) Sunfast .RTM. 24 Quinacridone 6 Solsperse .RTM. 13,940 Black Pearls 880 .RTM. carbon 25 black 7 (Control) Silwet L-722 .RTM. Black Pearls 880 .RTM. carbon * black 8 (Control) Ircosperse 2174 .RTM. Hansa .RTM. Brilliant Yellow * (Lubrizol Co.) 5GX-02 (p.y. 74) 9 (Control) GAFAC RS 610 .RTM. Black Pearls 880 .RTM. carbon * (GAF Corp.) black 10 (Control)  GAFAC RA 600 .RTM. Black Pearls 880 .RTM. carbon * (GAF Corp.) black 11 (Control)  Lauryl methacrylate Bis(phthalocyanylalumino)tetra * (Eastman Kodak. Co.) phenyl-disiloxane cyan __________________________________________________________________________ * Milling was unsuccessful

The above results show that use of the polyaminelfatty acid condensation polymer dispersant in the milling process as described produces pigment particles having a particle size below about 100 nm.

The invention has been described in detail with particular reference to certain preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention.

## Claims

1. A process for making an ink jet ink comprising: polyamine/fatty acid condensation polymer dispersant; particle size less than 100 .mu.m; below about 100 nanometers; pigment concentration suitable for ink jet printers.

2. The process of claim 1 wherein said dispersant is present in a ratio of dispersant:pigment of from about 0.1:1 to about 5:1.

3. The process of claim 1 wherein said dispersant is present in a ratio of dispersant:pigment of from about 0.5:1 to about 2:1.

4. The process of claim 1 wherein said dispersion contains from about 0.1 to 10% by weight of said pigment.

5. The process of claim 1 wherein said polyamine/fatty acid condensation polymer is poly(hydroxy stearate-co-ethyleneimine).

6. The process of claim 1 wherein said hydrocarbon carrier is an isoparaffin.