From:   Keith Barnett/RTP/USEPA/US                                                       

To:     Cortney_Higgins@omb.eop.gov                                                      

Cc:    Charlotte Bertrand/DC/USEPA/US@EPA                                               

Date:        07/31/2010 11:28 PM                                                              

Subject: Emailing: MEMO Organic HAP 8‐6‐10.pdf                                            

I put together the actual docket memo.  You can delete the previous version.

Keith W. Barnett

USEPA/OAQPS/SPPD/MMG

Mail Code D243‐02

Research Triangle Park, NC  27711

919‐541‐5605

barnett.keith@epa.gov

(See attached file: MEMO Organic HAP 8‐6‐10.pdf)
MEMORANDUM

TO: Portland Cement NESHAP Docket

FROM: Keith Barnett

Subject: Summary of Organic HAP Test Data

Date: August 6, 2010

Attached is information on the organic HAP contribution to totla 

THC emission for Portland cement kilns.
Organic HAP

Laney, Michael N. 

to:

Keith Barnett

04/23/2010 03:36 PM

Cc:

Barrett Parker

Show Details

Keith,

Based on the revised table, the percent of THC represented by the listed 

organic HAP is 35%.

The previous table was revised with the following changes:

-“BDL” was replaced by the reported detection limits.

-Added one additional row of data for Ash Grove, Montana.

-Revised some of the previous concentrations after QA of the conversions 

(from the Test Data Details tab).

Also, note the following:

-the THC concentrations for Ash Grove Seattle (38.87) and Ash Grove 

Durkee (30.84) are from different test reports than those containing the 

organic HAP results. Is that a problem?

-phenol and hexane results are all BDL – indicates there is not much 

there; they could be dropped.

-Naphthalene detection limits are very high for 3 out of 5 kilns.

Michael Laney

RTI International

TEL: 919-316-3413

FAX: 919-316-3420

EMAIL: mnl@rti.org
OrganicHAP 042310_kdb.xls7/31/2010

Company Location Kiln Type

Average 

THC (as 

propane), 

ppm @ 

7% O2

Formaldehyde, 

ppmvd@7%O2

Benzene, 

ppmvd@7

%O2

Toluene, 

ppmvd@

7%O2

Ethyl 

benzene, 

ppmvd@

7%O2

m,pXylene, 

ppmvd@

7%O2

Styrene, 

ppmvd@

7%O2

o-Xylene, 

ppmvd@

7%O2

Acetaldehyde, 

ppmvd@7%O

2

Phenol, 

ppmvd@

7%O2

Hexane, 

ppmvd@7%O

2

Naphthal

ene, 

ppmvd@

7%O2

Total 

organic 

HAP, 

ppmvd@

7%O2

Org. HAP 

as % of 

THC

Napthalene 

Method Moisture

Ash Grove Cement (2000) Montana City, MT wet <0.41 0.06 <0.01 <0.005 <0.005 <0.05 <0.014 <0.28 <0.04 <5.52 6.38 M320 33 Moisture is an FTIR interference; higher MDL

Ash Grove Cement (1994) Montana City, MT wet 0.41 0.04 <0.02 <0.019 <0.019 <0.019 <0.019 0.14 34.50

Ash Grove Inkom, ID wet <0.37 0.16 0.15 <0.02 <0.02 <0.03 <0.04 <0.37 <0.06 <4.90 6.12 M320 33 Moisture is an FTIR interference; higher MDL

Lafarge Ravena, NY wet 25.29 <0.28 0.59 0.037 0.007 0.91 3.59 M23 28 Different method; lower MDL

Ash Grove (2002) Durkee, OR PH/PC 3.71 0.57 0.23 0.10 0.28 0.27 <0.24 <0.003 1.69 45.54 M320 13 Lower moisture; lower MDL?

California PC (2005, 2) Colton, CA long dry 1.32 0.46 0.06 <0.02 <0.01 <0.02 <0.04 <0.63 <0.63 <0.10 3.30

California PC (2005, 1) Colton, CA long dry 1.66 0.30 0.05 <0.02 <0.01 <0.02 <0.03 <0.50 <0.50 <0.08 3.15

Ash Grove Seattle, WA PH/PC 38.87 3.59 0.13 0.05 0.01 0.03 0.05 <0.06 <0.28 <0.30 <5.56 10.07 25.90 M320 13 ???

Lehigh Glen Falls, NY PH/PC 4.79 <1.32 <1.32 <1.32 <1.32 <2.96 <1.32 14.33

California PC (2002) Colton, CA long dry 3.81 0.71 0.30 <0.02 <0.02 <0.02 <0.04 <0.77 <0.39 <0.09 6.16

Lafarge Sugar Creek, MO PH/PC 7.55 0.59 0.40 0.35 0.98 0.54 0.41 10.82

Ash Grove (2001) Durkee, OR PH/PC 30.84 18.88 0.21 0.09 <0.014 0.25 0.24 <0.023 <0.093 19.81 64.22

Average 6.91 34.75

* Values denoted with "<" are method detection limits. Maybe drop the naphthalene FTIR data (M320)?

Note that the THC value for Ash Grove, Seattle is from a different test report (1996).

Note that the THC value for Ash Grove, Durkee (2001) is from a different test report (2006).
Organic HAP test data

Laney, Michael N. 

to:

Keith Barnett

09/29/2008 09:14 AM

Cc:

"Branscome, Marvin R."

Show Details

Keith,

I compiled all the organic HAP test data I could find that we got with 

the 

114 ICR responses. In most of the cases, I was able to convert the data 

to 

ppmvd@7%O2. I ended up with about 15 useable data sets. In some cases, 

only one organic HAP was reported, but in others several organic HAP were 

measured. Where they also reported THC, I included that. I incorporated 

these data into the table we have that summarizes the THC test data. In 

just a couple of instances did I find organic HAP data for kilns in our 

THC data sets. I was able to calculate the HAP concentration as a 

percentage of THC for 5 sets of data (two tests were for the same kiln, 

but the results of the two tests were quite different, so I kept them 

separate for now). Lots of the totals are below 5 ppm, with the average 

being 3.4. The average percentage of THC that is HAP is 24%, pretty close 

to the earlier report of 23%.

Michael Laney

Environmental Engineering

Environmental Health & Safety Division

RTI International

TEL: 919-316-3413

FAX: 919-316-3420

EMAIL: mnl@rti.org
9/29/2008 Summary of Organic HAP Test Data 

OrganicHAP 092908.xls Page 1

Company Location Kiln Kiln Type Raw Mill

Average THC 

(as propane), 

ppm @ 7% O2

Formalde

hyde, 

ppmvd@7

%O2

Benzene, 

ppmvd@7

%O2

Toluene, 

ppmvd@7

%O2

Ethyl 

benzene, 

ppmvd@7

%O2

m,pXylene, 

ppmvd@7

%O2

Styrene, 

ppmvd@7

%O2

o-Xylene, 

ppmvd@7

%O2

Acetaldeh

yde, 

ppmvd@7

%O2

Phenol, 

ppmvd@7

%O2

Hexane, 

ppmvd@7

%O2

Naphthale

ne, 

ppmvd@7

%O2

Total 

organic 

HAP, 

ppmvd@7

%O2

Org. HAP 

as % of 

THC

Ash Grove Cement Montana City, MT 1 wet no 0.41 ND 0.06 ND ND ND ND ND ND ND 0.06 14.68

Ash Grove Cement Midlothian, TX 3 wet no 13.83

Ash Grove Cement Leamington, UT 1 preheater/calciner yes 14.14

Ash Grove Cement Seattle, WA 1 preheater/calciner yes 14.23 2.78 0.13 0.05 2.96 20.80

Ash Grove Cement Inkom, ID 2 wet no 20.50

Ash Grove Cement Inkom, ID 1 wet no ND 0.16 0.15 ND ND ND ND ND ND ND 0.31

Ash Grove Cement Durkee, OR 1 preheater/calciner yes 30.84 15.54 0.21 0.09 0.25 0.24 ND ND 16.33 52.94

Ash Grove Cement (new) Durkee, OR 1 preheater/calciner yes 3.72 0.29 0.23 0.1 0.28 0.27 0.002 1.172 31.51

Holcim Trident Kiln #1 wet no 5.56

Holcim Mason City Kiln #3 long dry no 6.78

Holcim Mason City Kiln #2 long dry no 11.07

Holcim Artesia, MS wet no 18.35

Holcim Theodore, AL Kiln #1 preheater/calciner no 23.74

Holcim Holly Hill, SC preheater/calciner yes 28.48

Holcim Portland, CO Kiln #4 preheater/calciner yes 44.97

Holcim Midlothian, TX Kiln #1 preheater/calciner yes 51.59

Holcim Devil's Slide, UT Kiln #1 preheater/calciner yes 51.91

Holcim Midlothian, TX Kiln #2 preheater/calciner yes 62.82

Holcim Clarksville, MO 121.01

Holcim Dundee Kiln #1 and wet no 748.15

Lafarge Whitehall, PA Kiln 2 preheater no 8.33

Lafarge Whitehall, PA Kiln 3 preheater no 10.81

Lafarge Ravena, NY 1 wet no 25.26

Lafarge Ravena, NY 2 wet no 25.26

Lehigh Evansville, PA Kiln2 preheater/calciner no 1.69

Lehigh York, PA White Cem wet no 1.74

Lehigh Evansville, PA Kiln1 preheater/calciner no 2.18

Lehigh Union Bridge E02-001 preheater/calciner yes 6.83

Lehigh Redding, CA 1 preheater yes 13.62

Lehigh Waco, TX 39 wet no 18.97

Lehigh Mitchell, IN 1 preheater no 49.09

Lehigh Mitchell, IN 2 preheater no 49.09

Lehigh Mason City 8 preheater/calciner yes 50.53

Lone Star Industries Oglesby, IL 3 long dry no 2.25

Lone Star Industries Maryneal 3 preheater no 30.16

Lone Star Industries Pryor 3 long dry no 125.24

Lone Star Industries Pryor 2 long dry no 149.75

Lone Star Industries Pryor 1 long dry no 173.83

TXI Midlothian Kiln E2-22 preheater/calciner 3.96

Lehigh Glen Falls, NY 1 PH/PC yes 3.29 3.29

Lafarge Tulsa 2 long dry no 0.04 0.04

Lafarge Tulsa 1 long dry no 0.02 0.02

California PC Colton 1 long dry no 3.53 0.71 0.3 ND ND ND ND ND ND ND 4.54

California PC Colton 1 long dry no 1.47 0.3 0.05 ND ND ND ND ND ND ND 1.82

California PC Colton 2 long dry no 1.22 0.46 0.06 ND ND ND ND ND ND ND 1.74

Lafarge Davenport, IA 1 preheater/calciner 0.15 0.15

Lafarge Sugar Creek, MO 3 preheater/calciner yes 5.57 0.59 0.4 0.35 0.98 0.54 0.41 8.84

Lehigh Leeds, AL 5 preheater 6.8 6.8

Test data in other units

Lafarge Ravena 1&2 wet no 55.2 0.51 0.92

Average HAP % of THC 24.17

Mean (ppmvd@7%O2) 3.433714

Median (ppmvd@7%O@ 1.78
9/29/08

Page 1 OrganicHAP 092908.xls

Organic HAP Test Data 9/26/2008

Plant/Kiln

Lehigh, Glen Falls, NY

Test date 2002

Kiln ID Kiln 1

Kiln type PC

RM On

Moisture, fraction 0.17

%O2 11

Formaldehyde ppmw 2.9

Formaldehyde ppmvd@7%O2 3.38

Acetaldehyde, acrylonitrile, hexane, phenol ND

RM Off

Moisture, fraction 0.19

%O2 6.73

Formaldehyde ppmw 3

Formaldehyde ppmvd@7%O2 2.39

Acetaldehyde, acrylonitrile, hexane, phenol ND

Total

Formaldehyde, Wtd avg, ppmvd@7%O2 3.29

Formaldehyde, Wtd avg, tpy 0.95

Total organic HAP 3.29

Lehigh, Glen Falls, NY

Test date 2006

Kiln ID Kiln 1

Kiln type PC

RM On

%O2 11

Moisture, fraction 0.139

NMHC ppm@7% O2 2.5

NMHC ppmvd@7% O2 2.15

NMHC lbs/hr 0.98

RM Off

%O2 5.90

Moisture, fraction 0.2006

NMHC ppm@7% O2 3.5

NMHC ppmvd@7% O2 2.80

NMHC lbs/hr 1.53

Total

NMHC Wtd Avg RM on/off, ppmvd@7%O2 2.22

NMHC Wtd Avg RM on/off, tpy 4.10
9/29/08

Page 2 OrganicHAP 092908.xls

Lafarge, Tulsa

Test date 2002

Kiln ID Kiln 2

Kiln type Dry

Moisture, fraction 0.1371

Formaldehyde, ppm@7%O2 0.051

Formaldehyde, ppmvd@7%O2 0.04

Formaldehyde, tpy 0.048

Kiln ID Kiln 1

Kiln type Dry

Moisture, fraction 0.1292

Formaldehyde, ppm@7%O2 0.027

Formaldehyde, ppmvd@7%O2 0.02

Formaldehyde, tpy 0.028

California PC, Colton

Test date 2002

Kiln ID Kiln 1

Kiln type Dry

Moisture, fraction 0.04

%O2 13.43

Formaldehyde, ppmw 1.97

Formaldehyde, ppmvd@7%O2 3.53

Formaldehyde, tpy 4.56

Benzene, ppmvd 0.38

Benzene, ppmvd@7%O2 0.71

Benzene, tpy 2.19

Toluene, ppmvd 0.16

Toluene, ppmvd@7%O2 0.30

Toluene, tpy 1.11

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Total organic HAP, ppmvd@7%O2 4.53

California PC, Colton

Test date 2005

Kiln ID Kiln1

Kiln type Dry

Moisture, fraction 0.06

%O2 12

Formaldehyde, ppmvw 1

Formaldehyde, ppmvd@7%O2 1.47

Formaldehyde, tpy 2.4

Benzene, ppmvd 0.19

Benzene, ppmvd@7%O2 0.30

Benzene, tpy 1.11

Toluene, ppmvd 0.03

Toluene, ppmvd@7%O2 0.05

Toluene, tpy 0.21

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Total organic HAP, ppmvd@7%O2 1.81
9/29/08

Page 3 OrganicHAP 092908.xls

California PC, Colton

Test date 2005

Kiln ID Kiln 2

Kiln type Dry

Moisture, fraction 0.04

%O2 14

Formaldehyde, ppmvw 0.63

Formaldehyde, ppmvd@7%O2 1.22

Formaldehyde, tpy 1.54

Benzene, ppmvd 0.23

Benzene, ppmvd@7%O2 0.46

Benzene, tpy 1.42

Toluene, ppmvd 0.03

Toluene, ppmvd@7%O2 0.06

Toluene, tpy 0.19

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Total organic HAP, ppmvd@7%O2 1.74

Ash Grove, Seattle

Test date 2001

Kiln ID Kiln 1

Kiln type PC

RM On

Moisture, fraction 0.132

%O2 9.52

Benzene, ppmvd 0.1

Benzene, ppmvd@7%O2 0.12

Benzene, tpy 0.55

Toluene, ppmvd 0.04

Toluene, ppmvd@7%O2 0.05

Toluene, tpy 0.26

Formaldehyde, ppmvw 2.3

Formaldehyde, ppmvd@7%O2 2.44

Formaldehyde, tpy 5.63

Ethyl benzene,mp-xlyene, styrene ND

RM Off

Moisture, fraction 0.073

%O2 8.73

Benzene, ppmvd 0.21

Benzene, ppmvd@7%O2 0.24

Toluene, ppmvd 0.08

Toluene, ppmvd@7%O2 0.09

Formaldehyde, ppmvw 5.5

Formaldehyde, ppmvd@7%O2 5.82

Total

Benzene, Wtd avg, ppmvd@7%O2 0.13

Toluene, Wtd avg, ppmvd@7%O2 0.05

Formaldehyde, Wtd avg, ppmvd@7%O2 2.78

Total organic HAP, ppmvd@7%O2 2.96
9/29/08

Page 4 OrganicHAP 092908.xls

Ash Grove, Montana City, MT

Test date 2000

Kiln ID Kiln 1

Kiln type Wet

%O2 (not reported. Used avg of 3 other wet kilns) 5.86

Benzene, ppmvd 0.06

Benzene, ppmvd@7%O2 0.06

Toluene, phenol, formaldehyde, naphthalene, hexane, ethyl 

benzene, m,p,o-xylene, styrene ND

Ash Grove, Durkee, OR

Date July 2001

Kiln Kiln

Kiln type PC

RM On

Moisture, fraction 0.1768

%O2 6.03

Benzene, ppmvd 0.22

Benzene, ppmvd@7%O2 0.21

Toluene,ppmvd 0.1

Toluene,ppmvd@7%O2 0.09

m,p-Xylene, ppmvd 0.27

m,p-Xylene, ppmvd@7%O2 0.25

Styrene, ppmvd 0.26

Styrene, ppmvd@7%O2 0.24

Formaldehyde, ppmvw 20.2

Formaldehyde, ppmvw@7%O2 15.54

Phenol, naphthalene ND

Total organic HAP, ppmvd@7%O2 16.34

Ash Grove, Durkee, OR

Date April 2002

Kiln Kiln 1

Kiln type PC

RM On

Moisture, fraction 0.116266667

%O2 7.7

Benzene, ppmvd 0.22

Benzene, ppmvd@7%O2 0.23

Toluene, ppmvd 0.1

Toluene, ppmvd@7%O2 0.11

m,p-Xylenes, ppmvd 0.27

m,p-Xylenes, ppmvd@7%O2 0.28

Styrene, ppmvd 0.26

Styrene, ppmvd@7%O2 0.27

Formaldehyde, ppmvw 0.3

Formaldehyde, ppmvd@7%O2 0.28

Naphthalene, ppmvd 0.002

Naphthalene, ppmvd@7%O2 0.002

THC(M25A), ppmvd as propane 3.6

THC, ppmvd@7%O2 3.8

Volumetric flow rate

dscfm 147929

wscfm 167391
9/29/08

Page 5 OrganicHAP 092908.xls

RM Off

Moisture, fraction 0.1368

%O2 5.93

Benzene, ppmvd 0.22

Benzene, ppmvd@7%O2 0.20

Toluene, ppmvd 0.1

Toluene, ppmvd@7%O2 0.09

m,p-Xylenes, ppmvd 0.27

m,p-Xylenes, ppmvd@7%O2 0.25

Styrene, ppmvd 0.26

Styrene, ppmvd@7%O2 0.24

Formaldehyde, ppmvw 0.5

Formaldehyde, ppmvd@7%O2 0.40

Naphthalene, ppmvd 0.008

Naphthalene, ppmvd@7%O2 0.01

THC(M25A), ppmvd as propane 3.3

THC, ppmvd@7%O2 3.1

Volumetric flow rate

dscfm 125600

wscfm 145505

Total

Benzene, Wtd avg, ppmvd@7%O2 0.23

Toluene, Wtd avg, ppmvd@7%O2 0.10

m,p-Xylenes, Wtd avg, ppmvd@7%O2 0.28

Styrene, Wtd avg, ppmvd@7%O2 0.27

Formaldehyde, Wtd avg, ppmvd@7%O2 0.29

Naphthalene, Wtd avg, ppmvd@7%O2 0.002

Total organic HAP, ppmvd@7%O2 1.18

THC, ppmvd@7%O2 3.72 31.7 HAP% of THC

Ash Grove, Louisville, NE

Date 2005

Kiln Kiln 2

Kiln type PC tpy

Benzene,g/sec, baseline 0.023 0.7

Benzene, g/sec, TDF 0.021 0.7
9/29/08

Page 6 OrganicHAP 092908.xls

Lafarge, Whitehall,PA

Date March 2006

Kiln Kiln 3

Kiln type PH

%O2 5.3

Total THC as methane, ppmvd 64.9

Total THC as propane, ppmvd@7%O2* 19.28

Benzene, ug/dscm@7%O2 143

Benzene, lb/hr 0.0287

Naphthalene, ug/dscm@7%O2 180

Naphthalene, lb/hr 0.0363

Methyl chloride, lb/hr 0.0355

Methyl bromide, lb/hr 0.0255

Acetone, lb/hr 0.00189

Methyl iodine, lb/hr 0.0112

Phenol, lb/hr 0.0517

2-Methylphenol, lb/hr 0.003

3&4-Methylphenol, lb/hr 0.007

Acetophenone, lb/hr 0.004

2-Methylnaphthalene, lb/hr 0.003

Acenaphthylene, lb/hr 0.002

Dibenzofuran, lb/hr 0.003

Diethyl phthalate, lb/hr 0.0004

Bis(2-ethylhexyl)phthalate, lb/hr 0.003

Benzoic acid, lb/hr 0.015

Total org HAP, lb/hr 0.23

*Converted THC methane to THC propane by dividing by 3.

Lafarge, Whitehall,PA

Date Sept 2006

Kiln Kiln 2

Kiln type PH

%O2 3.8

Total NMHC as Methane [VOC], ppmvd 22.9

Total NMHC as Methane [VOC], ppmvd@7%O2 18.7

Total NMHC as Methane [VOC], lb/hr 3.2

Kiln Kiln 3

Kiln type PH

%O2 5.3

Total NMHC as Methane [VOC], ppmvd 11.4

Total NMHC as Methane [VOC], ppmvd@7%O2 10.2

Total NMHC as Methane [VOC], lb/hr 1.2

Lafarge, Seattle

Date June 2000

Kiln Kiln

Kiln type Wet

Moisture, fraction 0.30

%O2 6.7

Benzene, ug/m3 2417

Benzene, lb/hr 0.726
9/29/08

Page 7 OrganicHAP 092908.xls

Lafarge, Ravena, NY

Date February 2004

Kiln Kiln 1&2, common stack

Kiln type Wet

%O2 6.94

Moisture, fraction 0.286

Naphthalene, mg/M3@7%O2 0.0371

Naphthalene,lb/hr 0.0634

2-Methylnaphthalene, mg/M3@7%O2 0.209

2-Methylnaphthalene, lb/hr 0.291

Phenanthrene, mg/M3@7%O2 0.11

Phenanthrene, lb/hr 0.153

Total org HAP, mg/M3@7%O2 0.3561

Total org.HAP, lb/hr 0.5074

Total NMHC, ppmvd 21.82

Total NMHC, lb/hr 55.2

THC, ppmvd as propane 25.4

THC, ppmvd@7%O2 as propane 25.3

THC, lb/hr as propane 55.2 0.9 HAP% of THC

Lafarge, Davenport IA

Date "March 2000

Kiln Kiln 1

Kiln type PC

Moisture, fraction 0.11

%O2 9.8

Benzene, ppmv 0.15

Benzene, ppm@7%O2 0.17

Benzene, ppmvd@7%O2 0.15

Volumetric flow rate, dscfm 271587

Lafarge, Sugar Creek, MO

Date August 2002

Kiln Kiln 3

Kiln type PC

RM On (95% of time) tpy

Moisture, fraction 0.14

%O2 (not reported, used avg. of 6 PC kilns) 9.2

Benzene, ppmvd 0.5 3.12

Benzene, ppmvd@7%O2 0.59

Toluene, ppmvd 0.34 2.46

Toluene, ppmvd@7%O2 0.40

Ethyl benzene, ppmvd 0.3 2.49

Ethyl benzene, ppmvd@7%O2 0.36

m,p-Xylenes, ppmvd 0.71 5.98

m,p-Xylenes, ppmvd@7%O2 0.84

Styrene, ppmvd 0.46 3.8

Styrene, ppmvd@7%O2 0.55

o-Xylene, ppmvd 0.35 2.95

o-Xylene, ppmvd@7%O2 0.41

Formaldehyde, ppmvw 5.4 14.92

Formaldehyde, ppmvd@7%O2 5.51

Volumetric flow rate, dscfm 122537

Volumetric flow rate, wscfm 141940
9/29/08

Page 8 OrganicHAP 092908.xls

RM Off (5% of time) tpy

Moisture, fraction 0.15

%O2 (not reported, used avg of 4 PC kilns) 6.8

Benzene, ppmvd 0.62 0.19

Benzene, ppmvd@7%O2 0.61

Toluene, ppmvd 0.34 0.12

Toluene, ppmvd@7%O2 0.34

Ethyl benzene, ppmvd 0.27 0.11

Ethyl benzene, ppmvd@7%O2 0.27

m,p-Xylenes, ppmvd 3.71 1.54

m,p-Xylenes, ppmvd@7%O2 3.66

Styrene, ppmvd 0.4 0.16

Styrene, ppmvd@7%O2 0.39

o-Xylene, ppmvd 0.3 0.12

o-Xylene, ppmvd@7%O2 0.30

Formaldehyde, ppmvw 8.2 1.13

Formaldehyde, ppmvd@7%O2 6.88

Volumetric flow rate, dscfm 114961

Volumetric flow rate, wscfm 134567

Total tpy

Benzene, ppmvd 0.51 3.31

Benzene, ppmvd@7%O2 0.59

Toluene, ppmvd 0.34 2.58

Toluene, ppmvd@7%O2 0.40

Ethyl benzene, ppmvd 0.30 2.6

Ethyl benzene, ppmvd@7%O2 0.35

m,p-Xylenes, ppmvd 0.86 7.52

m,p-Xylenes, ppmvd@7%O2 0.98

Styrene, ppmvd 0.46 3.96

Styrene, ppmvd@7%O2 0.54

o-Xylene, ppmvd 0.35 3.07

o-Xylene, ppmvd@7%O2 0.41

Formaldehyde, ppmvw 5.54 16.05

Formaldehyde, ppmvd@7%O2 5.57

Total all organic HAP, ppmd@7%O2 8.85 39.09

Lehigh, Leeds, AL

Date April 2002

Kiln 5

Kiln type PH

Moisture, fraction 0.1313

%O2 14.65

Formaldehyde, ppmvw 3.52 My calculation

Formaldehyde, ppmvd (reported)?? 4.05 3.06

Formaldehyde, ppmvd@7%O2 9.0 6.8

Formaldehyde, lb/hr 3.66

Volumetric flow rate, dscfm 194295

Volumetric flow rate, ascfm 298076
9/29/08

Page 9 OrganicHAP 092908.xls

Ash Grove, Inkom, ID

Date Sept/Oct 2000

Kiln Kiln 1

Kiln type Wet

Moisture, fraction 0.3308

%O2 3.95 tpy

Benzene, ppmvd 0.2 0.26

Benzene, ppmvd@7%O2 0.16

Toluene, ppmvd 0.18 0.27

Toluene, ppmvd@7%O2 0.15

Formaldehyde phenol, naphthalene, hexane, ethyl benzene, m,p,oxylene, styrene ND

Total organic HAP, ppmvd@7%O2 0.31

Volumetric flow rate, dscfm 24604

Volumetric flow rate, wscfm 36777

HAP MW

Formaldehyde 30

Benzene 78

Toluene 92

m,p-Xylene 106

Styrene 104

o-Xylene 106

Hexane 86

Phenol 94