# Patent

## Title
Vertical channel transistor structure and manufacturing method thereof

## Abstract

A vertical channel transistor structure is provided. The structure includes a substrate, a channel, a cap layer, a charge trapping layer, a source and a drain. The channel is formed in a fin-shaped structure protruding from the substrate. The cap layer is deposited on the fin-shaped structure. The cap layer and the fin-shaped structure have substantially the same width. The charge trapping layer is deposited on the cap layer and on two vertical surfaces of the fin-shaped structure. The gate is deposited on the charge trapping layer and on two vertical surfaces of the fin-shaped structure. The source and the drain are respectively positioned on two sides of the fin-shaped structure and opposite the gate.

## Background
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates in general to a vertical channel transistor structure and a manufacturing method thereof, and more particularly to a vertical channel transistor structure with a narrow channel and a manufacturing method therefor.
2. Description of the Related Art
Along with other advances in semiconductor manufacturing technology, the resolution of current semiconductor elements has reached the nanometer level. For example, the reduction in gate length and element pitch in memory units is carried on continually. Although the technology of photolithography has improved greatly, currently manufactured planar transistor structures have reached the limit of resolution, and the transistor elements manufactured thereby are apt to have the problems of electrostatic discharge (ESD), leakage, and decrease in electron mobility, resulting in short channel effect and drain induced barrier lowering (DIBL) effect. Thus, the double-gate or tri-gate vertical channel transistors capable of providing higher packing density, better carrier transport and device scalability, such as the fin field effect transistor (fin FET) for instance, have become transistor structures with great potential.
The fin FET transistor has a vertical channel that can be formed on the two lateral surfaces of the fin FET transistor and turns on the current by the double-gate or the tri-gate, hence having higher efficiency than conventional planar channel transistors.
When manufacturing a fin FET element with high resolution, expensive processes such as the photolithography process and the E-beam process are required. Therefore, the throughput can hardly be increased and large-scale production is difficult to achieve. There is another manufacturing method which reduces the channel width by applying oxidation to the etched channel. However, the element formed according to the above method has poor uniformity and unstable quality.
SUMMARY OF THE INVENTION
It is therefore an object of the invention to provide a vertical channel transistor structure and manufacturing method thereof. The fin-shaped structure whose width ranges between 10 nm-60 nm can be formed without changing the pitch of the element formed by way of exposing, such that the driving current for writing/reading data is effectively increased without incurring short channel effect or DIBL effect. The fin FET transistor formed according to the invention is small-sized, so the memory density can be improved significantly.
The invention achieves the above-identified object by providing a vertical channel transistor structure. The structure includes a substrate, a channel, a cap layer, a charge trapping layer, a source and a drain. The channel of the transistor structure is formed on a semiconductor body which protrudes from the substrate in a fin-shaped structure. The cap layer is deposited on the top of the fin-shaped structure. The cap layer and the fin-shaped structure have substantially the same width. The charge trapping layer is deposited on the cap layer and on two vertical surfaces of the fin-shaped structure. The gate straddles on the charge trapping layer and is positioned on the two vertical surfaces of the fin-shaped structure. The source and the drain are respectively positioned on two sides of the gate in the fin-shaped structure.
The invention further achieves the above-identified object by providing a manufacturing method of a vertical channel transistor structure. First, a substrate is provided. Next, a first SiN layer is formed on the substrate. Then, the SiN layer is etched to form a first patterned SiN layer. Next, the first patterned SiN layer is trimmed to form a second patterned SiN layer. Then, the substrate is etched to form at least a fin-shaped structure protruding from the substrate. Afterwards, a silicon oxide (SiO) layer is formed on the top surface of the substrate. Next, an oxide-nitride-oxide (ONO) layer is formed on two vertical surfaces of the fin-shaped structure. Then, a gate material layer is formed on the ONO layer. Next, the gate material layer is etched to form at least a gate positioned on two lateral surfaces of the fin-shaped structure so that a straddle gate is formed over a vertical surface of the fin-shaped structure. Then, ions are implanted to two sides of the gate to form a source and a drain on the fin-shaped structure.
Other objects, features, and advantages of the invention will become apparent from the following detailed description of the preferred but non-limiting embodiments. The following description is made with reference to the accompanying drawings.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1A is a top view of a vertical channel transistor structure according to a first embodiment of the invention;
FIG. 1B is a cross-sectional view along a cross-sectional line AA′ of FIG. 1A;
FIGS. 2A ̃2J are manufacturing procedures of the vertical channel transistor structure according to the first embodiment;
FIG. 3 is a step flowchart of manufacturing the vertical channel transistor structure according to the first embodiment;
FIG. 4A is a top view of the vertical channel transistor structure according to a second embodiment of the invention;
FIG. 4B is a cross-sectional view along a cross-sectional line BB′ of FIG. 4A;
FIG. 5A ̃5J are manufacturing procedures of the vertical channel transistor structure according to the second embodiment; and
FIG. 6 is a step flowchart of manufacturing the vertical channel transistor structure according to the second embodiment.



DETAILED DESCRIPTION OF THE INVENTION
First Embodiment
FIG. 1A is a top view of a vertical channel transistor structure according to a first embodiment of the invention. FIG. 1B is a cross-sectional view along a cross-sectional line AA′ of FIG. 1A. As shown in FIG. 1B, the vertical channel transistor structure 100 includes a substrate 110a, a fin-shaped structure 112 protruding from the substrate 110a and a cap layer 140 deposited on the top of the fin-shaped structure 112. The cap layer 140 and the fin-shaped structure 112 have substantially the same width. In the present embodiment of the invention, the cap layer 140, an intermediate product during the manufacturing process, includes a silicon dioxide (SiO2) layer and a silicon nitride (SiN) layer. The SiN layer is positioned on the SiO2 layer. A charge trapping layer 162 is deposited on the cap layer 140 and straddles the fin-shaped structure 112. The charge trapping layer 162 is contained between a first SiO layer 161 and a second SiO layer 163. The first SiO layer 161 is positioned between the charge trapping layer 162 and the fin-shaped structure 112. The second SiO layer 163 is positioned between the charge trapping layer 162 and the gate 170a. The charge trapping layer 162 is made from SiN, aluminum oxide (Al203) or other material with high dielectric constant. In the present embodiment of the invention, the charge trapping layer 162 is made from SiN. The charge trapping layer 162, the first SiO layer 161 and the second SiO layer 163 together form an oxide-nitride-oxide (ONO) layer as a storage structure, such that the vertical channel transistor structure 100 has data-writing/data-erasing function. The gate straddles the charge trapping layer 162 and two vertical surfaces on the fin-shaped structure 112. The gate 170a can turn on the circuit on the two vertical surfaces of the fin-shaped structure 112, and the structure formed thereby is called the double-gate structure. The gate 170a can be made from N+ polysilicon, P+ polysilicon, or metal. As shown in FIG. 1A, the source 192 and the drain 194 are respectively positioned on the two sides of gate 170a. The present embodiment of the invention is a NAND gate structure, so the source and the drain can be exchanged, and the source or the drain between any two vertical channel transistor structures 100 is not only a source for one transistor but also a drain for another. The line width of the fin-shaped structure 112 approximately ranges between 10 nm-60 nm.
As shown in FIG. 1B, the vertical channel transistor structure 100 further includes a thick SiO layer 150 positioned on the substrate 110a. The purpose of the thick SiO layer 150 is to prevent substrate being turned on to cause leakage.
The application of the present embodiment of the invention is exemplified below by the manufacturing process of a NAND memory. Referring to FIGS. 2A-2J, manufacturing procedures of the vertical channel transistor structure according to the first embodiment are shown. Also referring to FIG. 3, a step flowchart of manufacturing the vertical channel transistor structure according to the first embodiment is shown.
First, referring to FIG. 2A, at step 301, a substrate 110 is provided. The substrate 110 can be a bulk silicon substrate or a silicon-on-insulator (SOI) substrate.
Next, referring to FIG. 2B, a first SiN layer 130 is formed on the substrate 110 as indicated in step 302. In the present embodiment of the invention, a pad SiO layer 120 is preferably formed between the substrate 110 and the first SiN layer 130. The present embodiment of the invention forms a transistor structure with N-type channel. Therefore, in the present step, P-type ions are implanted to the substrate 100 for enabling the substrate 100 to have better functions function in subsequent processing of forming the channel. However, the present embodiment of the invention is not limited thereto. If a transistor having P-type channel is to be formed, then N-type ions are implanted to the substrate 100.
Then, referring to FIG. 2C, the first SiN layer 130 is etched to form a first patterned SiN layer 130a as indicated in step 303. Step 303 includes the sub-steps of forming a first patterned photoresist layer (not illustrated) on the first SiN layer 130; etching the first SiN layer 130 to form the first patterned SiN layer 130a; and removing the first patterned photoresist layer. The first patterned SiN layer 130a has a pattern with line width D1. The present step can be performed using a reactive ion etching (RIE) method.
Next, referring to FIG. 2D, the first patterned SiN layer 130a is trimmed to form a second patterned SiN layer 130b as indicated in step 304. After the trimming process, the second patterned SiN layer 130b has a pattern with line width D2. The line width D2 approximately ranges between 10 nm ̃60 nm. Since the hot-phosphoric-acid (HDP) possesses excellent etching selectivity towards SiN and SiO, that is used to trim the first patterned SiN layer 130a in the present step.
Referring to FIG. 2E, the substrate 110 is etched to form a substrate 110a first and form a fin-shaped structure 112 protruding from the substrate 110a as indicated in step 305. In the present embodiment of the invention, the pad SiO layer 120 is preferably etched to form a pad SiO layer 120a according to RIE method first, and then the substrate 110 is etched to form a fin-shaped structure 112 next. The pad SiO layer, 120a and the second patterned SiN layer 130b together form the cap layer 140.
Next, referring to FIG. 2F, a thick SiO layer 150 contacting two lateral surfaces of the fin-shaped structure 112 is formed. In the present step, the thick SiO layer 150 is deposited by high density plasma (HDP) deposition. The thick SiO layer 150 restricts the height of a channel on the fin-shaped structure 112, such that the current can only flow through the part of the fin-shaped structure 112 above the thick SiO layer 150.
Then, referring to FIG. 2G, an oxide-nitride-oxide (ONO) layer 160 is formed as indicated in step 306. The ONO layer 160 is deposited on the cap layer 140, the two vertical surfaces of fin-shaped structure 112 and thick SiO layer 150. The ONO layer includes a first SiO layer 161, a charge trapping layer 162 and a second SiO layer 163. In the present embodiment of the invention, the charge trapping layer 162 is made from SiN, and can be replaced by aluminum oxide (AI203) or other high dielectric constant material.
Next, referring to FIG. 2H, a gate material layer 170 is formed on the ONO layer 160 as indicated in step 307.
Then, referring to FIG. 2I, the gate material layer 170 is etched to form at least a gate straddling the fin-shaped structure as indicated in step 308. Preferably, the following steps are performed before step 308. First, a second SiN layer (not illustrated) is formed on the gate material layer 170. Next, a second patterned photoresist layer (not illustrated) is formed on the second SiN layer. Then, the second SiN layer is etched to form a third patterned SiN layer 180. Next, the second patterned photoresist layer is removed. Then, the third patterned SiN layer 180 is trimmed to form a fourth patterned SiN layer 180a. Then, referring to FIG. 2J, the gate material layer 170 is etched to form a gate 170a according to the pattern of the fourth patterned SiN layer 180a. After the gate 170a is formed, the step of removing the fourth patterned SiN layer 180a is preferably further included. Thus, a gate structure whose line width approximately ranges between 10 nm-60 nm is formed.
Next, ions are implanted in fin-shaped structure 112 the two sides of the gate 170a to form a source/drain 190 as indicated in step 309. Thus, the main structure of the NAND gate memory of the vertical channel transistor structure 100 is formed. The present embodiment of the invention is exemplified by the formation of an N-type channel transistor, so N-type dopants are used in the present step. However, if a P-type channel transistor is to be formed, then P-type dopants are used in the present step.
Second Embodiment
Referring to FIG. 4A and FIG. 4B. FIG. 4A is a top view of the vertical channel transistor structure according to a second embodiment of the invention. FIG. 4B is a cross-sectional view along a cross-sectional line BB′ of FIG. 4A. The vertical channel transistor structure 200 of the present embodiment differs with the vertical channel transistor structure 100 of first embodiment in that the cap layer 140 is removed. As for other elements, the vertical channel transistor structure 200 and the vertical channel transistor structure 100 are substantially the same, so the same reference numbers are used and their functions are not repeated here.
As the oxide layer 140 is removed, the gate 170a can turn on the circuit on the top surface of the fin-shaped structure 112, and the structure formed thereby is called the tri-gate structure.
The application of the present embodiment of the invention is again exemplified by the manufacturing process of a NAND gate memory array structure (NAND memory). Referring to FIGS. 5A ̃5J, manufacturing procedures of the vertical channel transistor structure according to the second embodiment are shown. Also referring to FIG. 6, a step flowchart of manufacturing the vertical channel transistor structure according to the second embodiment is shown.
First, referring to FIG. 5A, a substrate 110 is provided as indicated in step 601.
Next, referring to FIG. 5B, a first SiN layer 130 is formed on the substrate 110 as indicated in step 602. In the present embodiment of the invention, a pad SiO layer 120 is preferably formed between the substrate 110 and the first SiN layer 130. Furthermore, in the present step, P-type ions are implanted to the substrate 110 for enabling the substrate 110 to have better function in subsequent processing of forming the channel. However, the present embodiment of the invention is not limited thereto. If a transistor with P-type channel is to be formed, then N-type ions are implanted to the substrate 110.
Then, referring to FIG. 5C, the first SiN layer 130 is etched to form a first patterned SiN layer 130a as indicated in step 603. Step 603 includes the following steps of forming a first patterned photoresist layer (not illustrated) on the first SiN layer 130; etching the first SiN layer 130 to form a first patterned SiN layer 130a; and removing the first patterned photoresist layer. The first patterned SiN layer 130a has a pattern with line width D1.
Next, referring to FIG. 5D, the first patterned SiN layer 130a is trimmed to form a second patterned SiN layer 130b as indicated in step 604. The second patterned SiN layer 130b has a pattern with line width D2. The line width D2 approximately ranges between 10 nm ̃60 nm.
Then, referring to FIG. 5E, the substrate 110 is etched to form a substrate 110a and form a fin-shaped structure 112 protruding from the substrate 110a as indicated in step 605. In the present embodiment of the invention, the pad SiO layer 120 is preferably etched to form a pad SiO layer 120a according to RIE method first, then the substrate 110 is etched to form a fin-shaped structure 112 next. Meanwhile, the pad SiO layer 120a and the second patterned SiN layer 130b together form the cap layer 140.
Next, referring to FIG. 5F, a thick SiO layer 150 preventing lower portions of the vertical surfaces of the fin-shaped structure 112 being turned on is formed. Meanwhile, like step 606, the second patterned SiN layer 130b on the channel fin-shaped structure 112 is removed by hot-phosphoric-acid (H3PO4), and the pad SiO layer 120a is preferably removed by hydrofluoric acid (HF). The step of removing the second patterned SiN layer 130b and the pad SiO layer 120a can be performed before or after the step of forming the thick SiO layer 150.
Then, referring to FIG. 5G, an oxide-nitride-oxide (ONO) layer 160 is formed as indicated in step 607. The ONO layer 160 is deposited on the top surface, side wall vertical surfaces of fin-shaped structure 112 and on the thick SIO layer 150. The ONO layer 160 includes a first. SiO layer 161, a charge trapping layer 162 and a second SiO layer 163. In the present embodiment of the invention, the charge trapping layer 162 can be made from SiN or aluminum oxide (Al203) or other high dielectric constant material.
Next, referring to FIG. 5H, a gate material layer 170 is formed on the ONO layer 160 as indicated in step 608.
Then, referring to FIG. 5l, the gate material layer 170 is etched to form at least a gate positioned on the top surface of fin-shaped structure 112 and the vertical surfaces of the fin-shaped structure 112 as indicated in step 609. Preferably, the following steps are performed before step 609. First, a second SiN layer (not illustrated) is formed on the gate material layer 170. Next, a second patterned photoresist layer (not illustrated) is formed on the second SiN layer. Then, the second SiN layer is etched to form a third patterned SiN layer 180. Next, the second patterned photoresist layer is removed. Then, the third patterned SiN layer 180 is trimmed to form a fourth patterned SiN layer 180a. Then, referring to FIG. 2J, the gate material layer 170 is etched to form the gate 170a according to the pattern of the fourth patterned SiN layer 180a. After the gate 170a is formed, the step of removing the fourth patterned SiN layer 180a is preferably further included.
Next, proceeding to step 610, ions are implanted on the fin-shaped structure 112 on the two opposing sides of the gate 170a to form a source/drain 190. Thus, the main structure of the vertical channel transistor structure 200 of the NAND memory is formed.
According to the vertical channel transistor structure and manufacturing method thereof disclosed in the above embodiments of the invention, the line width of the pattern formed by SiN is further reduced by hot-phosphoric-acid, and the vertical channel transistor structure whose fin-shaped structure width ranges between 10 nm-60 nm is manufactured without changing the current exposing apparatus, that is, without changing the pitch of the element formed by way of exposing. The invention effectively increases the driving current for writing/reading data without increasing short channel effect or DIBL effect. The fin FET transistor formed according to the invention is small-sized, so the memory density is improved significantly. A transistor with a narrow fin-shaped structure can be manufactured according to the technology of the invention in large scale production and at low cost without employing expensive exposing apparatus. The invention adopts SiN as a hard mask and has better performance in resisting ion impact than a conventional photoresist layer. Thus, uniform semiconductor elements can be formed by way of etching without increasing the thickness of a photoresist layer according to the technology of the invention.
While the invention has been described by way of example and in terms of preferred embodiments, it is to be understood that the invention is not limited thereto. On the contrary, it is intended to cover various modifications and similar arrangements and procedures, and the scope of the appended claims therefore should be accorded the broadest interpretation so as to encompass all such modifications and similar arrangements and procedures.

## Claims

1. A method of manufacturing a vertical channel transistor structure, comprising:
(a) providing a substrate;
(b) forming a first layer of cap material on the substrate and a second layer of cap material over the first layer of cap material;
(c) etching the second layer of cap material to form a patterned cap layer;
(d) trimming the patterned cap layer to form a second patterned cap layer of the cap material, the second patterned cap layer having a width less than that of the patterned cap layer;
(e) etching the first layer of cap material and the substrate using the second patterned cap layer as a mask to form a semiconductor fin-shaped structure protruding from the substrate, the semiconductor fin-shaped structure comprising two vertical surfaces;
(f) forming a multilayer charge trapping layer, including a first dielectric layer in contact with upper portions of the two vertical surfaces of the semiconductor fin-shaped structure, a dielectric charge trapping layer on the first dielectric layer, and a second dielectric layer on the dielectric charge trapping layer, the second patterned cap layer being between the multilayer charge trapping layer and the semiconductor fin shaped structure;
(g) forming a control gate material layer on the multilayer charge trapping layer;
(h) etching the control gate material layer to form at least a gate positioned on the two vertical surfaces of the semiconductor fin-shaped structure; and
(i) implanting ions in the semiconductor fin-shaped structure on two sides of the gate to form at least a source/drain.

2. The method according to claim 1, wherein the second layer of cap material comprises silicon nitride and the first layer of cap material comprises silicon oxide.

3. The method according to claim 1 including, before step (f), depositing a silicon oxide material adjacent the fin-shaped structure using high density plasma (HDP) deposition to cover lower portions of the vertical surfaces of the fin-shaped structure and leave upper portions of the vertical surfaces uncovered.

4. The method according to claim 2, wherein step (c) further comprises:
forming a first patterned photo-resist layer on the second cap layer;
etching the second cap layer to form the patterned cap layer; and
removing the first patterned photo-resist layer.

5. The method according to claim 1, wherein after step (e), the method further comprises:
removing the second patterned cap layer.

6. The method according to claim 5, wherein the multilayer charge trapping layer is positioned on a top surface and the two vertical surfaces of the fin-shaped structure.

7. The method according to claim 1, wherein in step (d), the width of the second patterned cap layer approximately ranges between 10 nm ̃60 nm.

8. The method according to claim 1, wherein step (c) adopts reactive ion etching (RIE) method.

9. The method according to claim 1, wherein the second layer of cap material comprises silicon nitride and step (d) uses hot-phosphoric-acid (H3PO4) to trim the patterned cap layer.

10. The method according to claim 1, wherein the second layer of cap material comprises silicon nitride.