# Enclosure 1

### ENCLOSURE 1


# INFORMATION COLLECTION REQUEST FOR Off

- Site Waste and Recovery Operations

This information collection request is being conducted by the Environmental Protection Agency’s (EPA) Office of Air and Radiation (OAR) to assist the EPA Administrator in developing emission standards for Off

- Site Waste and Recovery Operations under Clean Air Act (CAA) section 112. The survey is being sent under the authority of Section 114 of the CAA.

BACKGROUND:
Section 112 (d) of the Clean Air Act (CAA) calls for EPA to promulgate national technology

- based emission standards for hazardous air pollut ants (NESHAP) for sources emitting one or more of the HAP listed in CAA section 112(b). For major sources, these technology

- based standards must reflect the maximum degree of emissions reductions of HAP achievable (after considering cost, energy requireme nts, and nonair quality health and environmental impacts). In addition, under CAA section 112(d)(6), EPA is required to review the technology

- based standards and revise them “as necessary (taking into account developments in practices, processes, and con trol technologies)” no less frequently than every 8 years. Furthermore, we are required by section 112(f) (2) of the Clean Air Act (CAA) to assess the risk remaining (residual risk) eight years after the promulgation of maximum achievable control technolo gy (MACT) standards under section 112(d). If we find the residual risk fails to protect public health with an ample margin of safety or to prevent (taking into consideration various factors) adverse environmental effects, we are required to promulgate

mor e stringent standards.

The Off

- Site Waste and Recovery Operations maximum achievable control technology (MACT) standards were promulgated on July 1, 1996 (see 61 FR 34140). We are collecting specific detailed information to support development of stand ards as part of our review as described above. Please note this survey is for off

site waste and recovery operations only.
CAA section 114(a) states that the Administrator may require any person who owns or operates any emission source, who manufactures emission control equipment or process equipment, who the Administrator believes may have information necessary for the purposes set forth in section 114(a), or who is subject to any requirement of the CAA (other than certain provisions under Title II), to provide EPA with information for the following purposes:

1. Developing or assisting in the development of the following:

a. State implementation plans (§§ 110 and 111(d)); b. New Source Performance Standards (NSPS) (§ 111);

c. National Emissions Standards for Hazard ous Air Pollutants (NESHAP) (§ 112); d. Solid waste combustion or other related solid waste regulations (§ 129); 2. Determining whether any person is in violation of any standards or requirements developed under the authorities cited above; or 3. Carrying out any provision under the CAA (except certain provisions under Title II).
The Administrator may require that those persons identified above do the following so the Administrator may have the information necessary for the items listed in #1

- 3:

 establish and mai ntain records;

 make reports;

###  install, use, and maintain monitoring equipment, and use audit procedures, or methods;

 sample emissions (in accordance with such procedures or methods, at such locations, at such intervals, during such periods, and in such m anner as the Administrator shall prescribe);

 keep records on control equipment parameters, production variables or other indirect data when direct monitoring of emissions is impractical;

 submit compliance certifications in accordance with section 114(a)( 3); and

 provide such other information as the Administrator may reasonably require.

DIRECTIONS:

 All recipients must complete and return this survey by April 10 , 2013

.

 Please identify clearly any response(s) that you consider to be confidential business information (CBI). Any responses not so identified will be included in a publicly available database. Refer to Enclosures 3, 4, 5, and 6 for more information on the treatment of CBI and a list of information you may be asked to submit later to substantiate a claim of confidentiality.
DEFINITIONS: For the purposes of this ICR only, terms used have the meanings attributed to them in 40 CFR 63.681.
CONFIDENTIAL BUSINESS INFORMATION (CBI) : Please indicate if any CBI is included in this survey re sponse: 

##  Y 

##  N

OFF

- SITE WASTE AND RECOVERY OPERATIONS We believe that you own a facility that has Off

- Site Waste and Recovery Operations . If you believe that this survey does not pertain to you, please indicate your reason below: 

##  The Off

- Site Waste and Recovery Operations are permanently shut down. Please also identify the date the Off

- Site Waste and Recovery Operations w ere shut down, what steps were taken to close the equipment or stop operations , and if you still have a permit

.

_________________________________________________________________________________

________________________________________________________________________________

________________________________________________________________________________ 

##  No Off

- Site Waste and Recovery Operations at this facility. Please identify the operations at the facility.

________________________________________________________________________________

________________________________________________________________________________

________________________________________________________________________________ If you r facility do es not have Off

- Site Waste and Recovery Operations , please respond as soon as possible. We will review that information and respond as to whether you need to complete any other part of the survey.

# Enclosure 2

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 1 of 13 General Information

Name of Legal Owner: Hydrite Chemical Co. Legal Owner Address: 300 N. Patrick Boulevard, Brookfield, WI 53045 Number of Legal Owner Employees: (262) 792-1450 Facility Name: Hydrite Chemical Co. Facility Address: 114 N. Main Street, Cottage Grove, WI 53527 Mailing Address (if different from facility address): Facility Contact Name: Joy Warborg Facility Contact Title: Associate Environmental Manager Facility Contact Phone Number: (608) 839-8153 Facility Contact Email Address: joy.warborg@hydrite.com Number of Company Employees at the Entire Facility: 130

Please enter any other comments regarding general ownership information here:

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 2 of 13 Facility Information

Is the facility a major source for HAP? (see definition below) Major sources are any stationary source or group of stationary sources located within a contiguous area and under common control that emits or has the potential to emit considering controls, in the aggregate, 10 tons per year (TPY) or more of any hazardous air pollutant or 25 TPY or more of any combination of HAP.
Are there one or more off-site waste management or recovery operations at the facility subject to the Off-Site Waste and Recovery Operations (OSWRO) MACT (40 CFR 63, subpart DD)?

Is the facility exempt from complying with the OSWRO MACT?

What type(s) of off-site waste does the facility accept? (please include shipment method, physical form (i.e., solid, liquid, sludge), and a general description)

Approximately how many sources (facilities) does that waste come from?

What is the base year for which information is being provided? (please limit reporting years between 2006 and 2012, and provide the most current year)

For this base year, what was the amount of off-site waste received? (please specify units; e.g., gal/yr)

For this base year, what was the HAP content of the off-site waste received? (please specify units; e.g., tons)

How many hours per year are control devices bypassed to the atmosphere to perform routine maintenance?

Are any OSWRO operations scheduled to be discontinued?

Are any OSWRO operations scheduled to be added or expanded?

What is the permitting classification of your facility?

What are the operating permit IDs for the OSWRO operations at your facility?

Is your operating permit available online?

Please provide the coordinates (in decimal degrees) of your facility property boundary at each corner (node). Alternatively, please provide the minimum distance from any OSWRO emission point to the facility property boundary.

Please enter any other comments regarding the facility here: If yes, please provide date(s) that addition(s) and/or expansion(s) will begin production and explain changes: If yes, please provide dates of closure and explain changes:

Please note that an CAAPP Operation Permit Renewal application was submitted to the Wisconsin DNR on 10/26/12. An application completeness determination was received from the Wisconsin DNR on 11/02/12. 2012

19,171,503 pounds of off-site waste was received in 2012

Average incoming waste composition was 18% HAP, or roughly 3,450,871 lbs. If yes, please explain:

None - All equipment is shut down and/or prevented from venting emissions when the control device requires maintenance.

NW - 43.077481, -89.204687 SW - 43.076274, -89.204784

NE - 43.079437, -89.19486 SE - 43.077728, -89.19494 No OSW is stored or processed within 50' of the property line. The facility receives liquid solvents (primarily F005, F003, and D001 waste codes) in bulk tankers and containers (primarily 55-gallon drums).

125 current profiles

Copies of the facility permits are available on the Wisconsin DNR webpage (Air Permit -> http://dnr.wi.gov/topic/AirPermits/) (Waste Permit/Licenses -> http://dnr.wi.gov/topic/waste/licenses.html). A copy of the most recent CAAPP Operating Permit is also attached. Wisconsin FID No. 113063390 Wisconsin CAAPP Operation Permit No. 113063390-P12 EPA ID No. WID000808824 - RCRA Part B Permit License No. 6006 - Storage of Hazardous Waste in Containers License No. 3200 - Storage of Hazardous Waste in Tanks License No. 4437 - Treatment of Hazardous Waste in Tanks

If yes, please provide a link to or a copy of your most recent operating permit. If no, please provide a copy of your most recent operating permit.

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 3 of 13 If no, please explain.

If no, please explain.

If "Other", please explain:

If "Other", please explain:

If neither apply, please explain:

If yes, please describe the control technique(s):



### Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP:

Pumps 7 Compressors 0 Agitators 11 Pressure relief devices 24 Sampling connection systems 0 Open-ended valves or lines 115 Connectors 1065 Instrumentation systems unknown

Please enter any other comments regarding equipment leaks here: What is the number of each type of component for the equipment in OSWRO HAP service (equipment that contacts off-site material having a total HAP concentration ≥ 10% by weight for 300 hours/year or more)? With which subpart do you comply for equipment leaks? Please provide documentation demonstrating the basis for the equipment leak emissions estimates. What type of documentation are you providing? Equipment Leaks

Have you verified and/or corrected the equipment leak emissions for your OSWRO processes in Enclosure 2A?

Have you completed all control information fields for your OSWRO equipment leaks in Enclosure 2A?

What emissions calculation approach was used to estimate the equipment leak emissions?

Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard?

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

If no, please explain.



### Facility OSW transfer systems are comprised entirely of piping. Emissions from transfer systems are limited to fugitive emissions from equipment leaks, and are included in the equipment leak emission calculations.

If "Other", please explain:

If "Other", please explain: Please reference the Equipment Leak Emissions Estimate.

If yes, please describe the control technique(s):



### Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP:

Please enter any other comments regarding transfer systems here: Transfer Systems

Have you entered the OSWRO transfer system emissions in Enclosure 2A?

Have you completed all control information fields for your OSWRO transfer systems in Enclosure 2A?

What emissions calculation approach was used to estimate the transfer system emissions?

Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard? Please provide documentation demonstrating the basis for the transfer system emissions estimates. Are you providing emissions factors or source test data?

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

### The facility does not operate any oil-water or organicwater separators.

If no, please explain.

### The facility does not operate any oil-water or organicwater separators.

If "Other", please explain: None - Not applicable to the facility.

If "Other", please explain: None - Not applicable to the facility.

If yes, please describe the control technique(s):



### Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP:

Please enter any other comments regarding organic or oilwater separators here: Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard? Please provide documentation demonstrating the basis for the oil-water and organic-water separators emissions estimates. Are you providing emissions factors or source test data? Oil-water and organic-water separators

Have you entered the OSWRO oil-water and organic-water separators emissions in Enclosure 2A?

Have you completed all control information fields for your OSWRO oil-water and organic-water separators in Enclosure 2A?

What emissions calculation approach was used to estimate the oil-water and organic-water separators emissions?

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

If no, please explain.

If "Other", please explain:



### Please list each OSWRO container requiring Level 1 or Level 2 control:

Container ID Container capacity Container emissions control level implemented Upon receipt each container (drum) of OSW receives a unique authorization number 55-gallons DOT approved packaging 

### Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP: None - Fugitive losses only. If "Other", please explain:



### Please enter any other comments regarding containers here: (add information for more containers as necessary) Containers

Have you entered the OSWRO containers emissions in Enclosure 2A?

Have you completed all control information fields for your OSWRO containers in Enclosure 2A?

What emissions calculation approach was used to estimate the containers emissions?

Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard? Please provide documentation demonstrating the basis for the containers emissions estimates. Are you providing emissions factors or source test data? Containers used for storing off-site waste materials meet the DOT regulations on packaging hazardous materials for transportation. Containers remain closed with covers in place except when the contents are sampled to verify the composition and when the contents are transferred to an OSW process vessel or storage tank. Sampling and material transfers are completed by inserting a wand into the container through a bung opening. Containers are not loaded with OSW at the facility.

Emissions from OSW containers are limited to fugitive losses from the bung opening while removing

or sampling material. Work practices require that the containers be closed as soon as the material transfer or sampling is complete, so these emissions are considered negligible.

If yes, please describe the control technique(s):

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.



### The facility does not operate any surface impoundments.

If no, please explain.



### The facility does not operate any surface impoundments.

If "Other", please explain: None - Not applicable to the facility.

If "Other", please explain: None - Not applicable to the facility.



### Please enter any other comments regarding surface impoundments here: If yes, please describe the control technique(s):



### Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP: Surface Impoundments

Have you entered the OSWRO surface impoundments emissions in Enclosure 2A?

Have you completed all control information fields for your OSWRO surface impoundments in Enclosure 2A?

What emissions calculation approach was used to estimate the surface impoundments emissions?

Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard? Please provide documentation demonstrating the basis for the surface impoundments emissions estimates. Are you providing emissions factors or source test data?

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 8 of 13 If no, please explain.

If no, please explain.

All OSW process vents are routed to a thermal oxidizer through a closed vent system. 

### Please enter any other comments regarding process vents here: If "Other", please explain:

If yes, please describe the control technique(s):



### Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP: Please provide documentation demonstrating the basis for the process vent emissions estimates. Are you providing emissions factors or source test data?

Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard? If "Other", please explain: Process Vent Emissions Information

Have you verified and/or corrected the process vent emissions for your OSWRO processes in Enclosure 2A?

Have you completed all control information fields for your OSWRO process vent streams in Enclosure 2A?

What emissions calculation approach was used to estimate the process vent emissions?

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 9 of 13 Tanks Emissions Information

Please list each OSWRO tank requiring Level 1 or Level 2 control:

Tank ID Tank capacity Tank content MTVP 1 

### Tank content AVP 2 

### Tank height Tank diameter Tank average annual throughput Tank emissions control equipment T212 6,650 gallons 1.55 psia 0.17 psia 14 feet 9.5 feet 358,000 gallons Thermal Oxidizer T213 6,650 gallons 1.12 psia 0.20 psia 14 feet 9.5 feet 24,000 gallons Thermal Oxidizer T214 6,650 gallons 0.16 psia 0.13 psia 14 feet 9.5 feet 221,000 gallons Thermal Oxidizer T215 6,650 gallons 0.26 psia 0.22 psia 14 feet 9.5 feet 17,000 gallons Thermal Oxidizer T218 6,650 gallons 1.55 psia 0.27 psia 14 feet 9.5 feet 439,000 gallons Thermal Oxidizer T219 6,650 gallons 1.12 psia 0.13 psia 14 feet 9.5 feet 20,000 gallons Thermal Oxidizer T220 6,650 gallons No HAP Contents No HAP Contents 14 feet 9.5 feet 44,000 gallons Thermal Oxidizer T221 6,650 gallons 1.55 psia 0.08 psia 14 feet 9.5 feet 160,000 gallons Thermal Oxidizer T241 6,650 gallons 1.55 psia 0.27 psia 14 feet 9.5 feet 115,000 gallons Thermal Oxidizer T242 6,650 gallons 1.55 psia 0.22 psia 14 feet 9.5 feet 66,000 gallons Thermal Oxidizer

1 

### Maximum True HAP Vapor Pressure

2 

### Average HAP Vapor Pressure For each tank with an internal floating roof, please list the slotted ladder information:

Tank ID Number of ladders with slotted legs Gasketed deck cover over slotted ladder(s)? Ladder sleeve over slotted ladder(s)? Pole wipers in place for slotted ladder legs? None



### For each tank with a fixed roof, please list the tank fitting information:

Tank ID Number of access hatches Number of gauge hatches Number of conservation
vents Number of valves/instruments Number of emergency pressure relief vents T212 2 1 0 10 2 T213 2 1 0 10 2 T214 2 1 0 14 2 T215 2 1 0 14 2 T218 2 1 0 11 2 T219 2 1 0 11 2 T220 2 1 0 15 2 T221 2 1 0 11 2 T241 2 1 0 11 2 T242 2 1 0 10 2

1 

### Maximum True HAP Vapor Pressure

For each tank with a floating roof (internal or external), please list the tank information:

Tank ID Annual number of days roof rests on landing legs Length of landing legs None



### Please enter any other comments regarding tanks here: If yes, please describe the control technique(s): 

### Please provide documentation demonstrating the basis for the tanks emissions estimates. Are you providing emissions factors, source test data or other data?

Are you implementing work practices or other HAP control techniques beyond those required by the MACT standard? If "Other", please explain:

If "Other", please explain:



### (add information for more tanks as necessary)

(add information for more tanks as necessary)

(add information for more tanks as necessary)

(add information for more tanks as necessary) Please provide the additional capital and annual costs of this practice above that required by the OSWRO NESHAP: Have you entered the tanks emissions for your OSWRO processes in Enclosure 2A?

Have you completed all control information fields for your OSWRO storage vessels in Enclosure 2A?

What emissions calculation approach was used to estimate the tank emissions? If no, please explain.

If no, please explain.

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 10 of 13 Off-Site Material Treatment

If you treat off-site waste using biological degradation, please answer the following questions: What method of off-site waste HAP reduction is used?

Thin-Film Evaporation Distillation Fuel Blending OSW Emissions are treated by a Thermal Oxidizer

How do you characterize the components of the waste products you receive that are treated with biological degradation?

Please enter any other comments regarding off-site waste treatment here: Do you perform any testing or other practices to determine whether fouling agents may be in the waste received? If "Other" or more than one of the above applies, please explain.

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 11 of 13 Startup and Shutdown Events

If no for any of the above, please explain:

Please provide the following information about all startup and shutdown events:
1. OSW processes (Luwa 1 - P11 and Column 1 - P01) 2. Emission control device (Thermal Oxidizer) 

### Equipment Leaks

Transfer Systems

Organic and Oil-Water Separators

Containers

Surface Impoundments

Process Vents Organic and Oil-Water Separators

Tanks Process Vents

1. What emissions source types experience startup and shutdown events? T he United States Court of Appeals for the District of Columbia Circuit vacated portions of two provisions in the EPA’s CAA section 112 regulations governing the emissions of HAP during periods of startup, shutdown and malfunction (SSM). Sierra Club v. EPA, 551 F.3d 1019 (D.C. Cir. 2008). Specifically, the Court vacated the SSM exemption contained in 40 CFR 63.6(f)(1) and 40 CFR 63.6(h)(1), that are part of a regulation, commonly referred to as the “General Provisions Rule,” that the EPA promulgated under section 112 of the CAA. When incorporated into CAA section 112(d) regulations for specific source categories, these two, now vacated, provisions exempted sources from the requirement to comply with the otherwise applicable CAA section 112(d) emission standard during periods of SSM. To be consistent with the Court’s decision, facilities must comply with the applicable standards at all time s

.

For each emission source type, do the annual emissions estimate in the Enclosure 2A "Emissions (TPY)" field include the annual emissions from startup and shutdown events that you added in the "STARTUP EMISSIONS (TPY)" and "SHUTDOWN EMISSIONS (TPY)" fields? Please enter a separate response for each emissions point type below:

For each emission source type, can you comply with the emissions limitation and/or work practices in the regulation that apply during normal operation during startup and shutdown events? Please enter a separate response for each emissions point type below: Surface Impoundments

Tanks

Equipment Leaks

Transfer Systems

Containers

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 12 of 13 Startup and Shutdown Events
1. OSW processes are batch operations. 2. Emission control device operates continuously. 1. Start or completion of a batch. 2. Equipment failure or malfunction. 3. Shutdown/re-start for control device malfunction. 4. Shutdown / startup for maintenance.

1. Routine startup/shutdown of OSW processes do not result in operating conditions different from normal operations. Emergency shutdown for an equipment or control device malfunction also should not result in operating conditions different from normal operation. 2. Startup/shutdown of the emission control device (thermal oxidizer) results in the firebox temperature being lower than during normal operations.

1. Emissions from OSW processes vent through a control valve to the thermal oxidizer. During an extreme incident, emissions may vent through a process safety element to a catch tank. 2. Emssions from the control device (thermal oxidizer) release through a vertical stack. 1. Routine startup/shutdown of the OSW processes (Luwa 1 - P11 and Column 1 - P01) occurs daily as batches are started or completed. Emergency shutdowns for equipment or control device malfunctions are less frequent (12 shutdowns for thermal oxidizer malfunctions occurred during 2012). 2. Startup/shutdown of the thermal oxidizer occurs only during malfunctions and for scheduled/planned maintenance activities. Preventative maintenance activities for the thermal oxidizer are schedule at least once each year. 1. Routine startup/shutdown of OSW process between product batches varies from a few hours to several days depending on customer needs and the production schedule. 2. The average duration of an emergency shutdown for a thermal oxidizer malfunction in 2012 was less than 2.2 hours. 3. A planned facility-wide shutdown (all processes and emission control equipment) is scheduled for one week
every year. 1. For OSW processes (Luwa 1 - P11 and Colunn 1 - P01), startup is marked by material being added to the vessel and/or the hot oil or steam system being restarted (i.e. system heating started). 2. For the thermal oxidizer the startup/shutdown event is over when the firebox temperature is back in compliance (1433 °F).

None

HAP emissions are only calculated when OSW processes continue to operate (do not shutdown) during emission control device (thermal oxidizer) malfunctions, which is a violation of facility procedures. Uncontrolled emissions are calculated using the engineering emission factors determined for the applicable process vents. 

### 6. How do you determine the HAP emissions during the event? 4. What marks the end of the startup or shutdown event?

5. What safety issues are connected with a startup or shutdown event? 2. How often do startup or shutdown events occur?

3. What is the average and range of event duration? 1.d. How are emissions released to the atmosphere (e.g., through a pressure relief device)? 1.c. How does the startup or shutdown event compare to normal operations (e.g., differences in flowrate, temp., pressure, alternate fuels used, alternate control devices used, etc.)? 1.a. Under normal operating conditions, do these emissions sources operate continuously?
1.b. What triggers the equipment to experience a startup or shutdown event (e.g. hot startup, startup after an emergency shutdown, re-start, control device startup)?

### U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 13 of 13 Startup and Shutdown Events All OSW process equipment must shutdown during emission control device malfunctions, and is not allowed to startup until the emission control device is operating in compliance. Checking the process equipment venting and the operation of the control device (thermal oxidizer) is required during system preparations for each batch. Equipment shutdown invloves turing off the hot oil or steam system (stopping system heating), engaging system cooling, shutting down the vaccuum system, and stopping all material transfers. The control valve on the vent line to the emission control device may also be closed.

1. Continuous monitoring of the thermal oxidizer temperature. 2. All control device malfunctions are required to be recorded on a malfunction log. Shift supervisors record the thermal oxidizer shutdown time, the cause of the malfunction, any maintenance or corrective actions performed, the thermal oxidizer startup time, the state of each process, and the process shutdown time.

Facility procedures require that no OSW be processed when the emission control device (thermal oxidizer) is not operating in compliance (temperature is < 1433°F). If a process was unable to be shutdown, due to an equipment failure or safety concern, uncontrolled emissions could still be limited by other in process equipment. The minimum emission level would vary depending upon which materials were being processed. Emergency shutdown procedures require the hot oil or steam (heating) system, the vacuum system, and all material transfers be stopped. If one or more of these systems failed, HAP emissions could still be minimized by the in-line process heat exchangers or demister pads, or by controlling the material reflux ratio. In worst-case scenarios, emissions and process material would be sent through the process safety element (i.e. rupture disk) to a catch tank.

All of these emergency systems are currently in place.

In this scenario, emissions would effectively be the equivalent of an uncontrolled event.



### Please enter any other comments regarding startup or shutdown here: Facility has a written Malfunction Prevention and Abatement Plan (SOP # AC014CG). 

### 7. How are control devices and work practices used to minmize emissions during the startup or shutdown event?

8. What compliance determination method(s) do you use during startup and shutdown events (e.g., monitor with CEMS)?

9.a. Please describe how HAP emissions would be minimized.

9.b. How much would it cost to minimize HAP emissions in this manner?
9.c. How much would HAP emissions be reduced compared to an uncontrolled event? (If "emission factor" is used as basis for emissions estimate, please provide the emission factor and sources of the emission factor. 1 

### ) 9. During startup and shutdown events, if you cannot comply with the emissions limitation and/or work practices in the regulation that apply during normal operation, what is the minimum emissions level that could be achieved?

1 If "source test" is used as basis for emissions estimate, please provide a copy of the
source test.

# Enclosure 2aEnclosure 2a

Page 1 Please complete this table for all OSWRO emission units. Please report all emissions related to the off-site waste handled and/or treated.

Facility Name Emission Unit ID Process ID Emission Release Point ID SCC Code 1 Emissions Start Date Emissions End Date Pollutant CAS Number 2 Pollutant Name (include organic and non-organic pollutants) Actual Emissions (TPY) MACTAllowable Emissions (TPY) 3 Routine Emissions Max Hourly

(lbs/hr) Startup Emissions (TPY) Startup Emissions

(lbs/hr) Shutdown Emissions (TPY) Shutdown Emissions

(lbs/hr) MACT Source Category Emission Release

Point Type4 Stack Height (ft) Exit Gas Temperatu re (° F) Stack Diameter (ft) Exit Gas Velocity (ft/sec) Exit Gas Flow Rate (ft3/sec) FugitiveLength (EW) (ft) Fugitive Width (N-S) (ft) Fugitive Angle (degrees) 5 Longitude (decimal degrees) 6 Latitude (decimal degrees) 6 Is Control Measure In Place? Control Measure 7 Control Measure Efficiency Comments

Hydrite Chemical Co. NA NA NA 50310001 01/01/12 12/31/12 110543 Hexane 0.0003 10.00 0.0001 0.00 0.00 0.00 0.00 Equipment Leaks Fugitive NA NA NA NA NA NA NA NA NA NA Yes Leak Detection and Repair Program Varies by Equipment LDAR Program follows Subpart V with a leak definition of 10,000 ppm. 67561 Methanol 0.16 10.00 0.04 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.91 10.00 0.21 0.00 0.00 0.00 0.00 108883 Toluene 1.61 10.00 0.37 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 1.43 10.00 0.33 0.00 0.00 0.00 0.00 Glycol ethers 0.58 10.00 0.13 0.00 0.00 0.00 0.00

Hydrite Chemical Co. NA NA NA 50310002 01/01/12 12/31/12 NA NA NA NA NA NA NA NA NA Containers Fugitive NA NA NA NA NA NA NA NA NA NA Yes Pollution Prevention Technique 100% Containers of OSW are DOT regulated, and are only opened to sample and transfer material. No containers are filled with OSW.

Hydrite Chemical Co. Tank 212 P42 / P200 S60 50310003 01/01/12 12/31/12 110543 Hexane 0.00017 10.00 0.10 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 67561 Methanol 0.00019 10.00 0.10 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.00047 10.00 0.26 0.00 0.00 0.00 0.00 108883 Toluene 0.00022 10.00 0.12 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.00016 10.00 0.09 0.00 0.00 0.00 0.00 Glycol ethers 0.00000 10.00 0.001 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Tank 213 P42 / P200 S60 50310003 01/01/12 12/31/12 67561 Methanol 0.000006 10.00 0.02 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 108101 Methyl isobutyl ketone (Hexone) 0.000017 10.00 0.05 0.00 0.00 0.00 0.00 108883 Toluene 0.000030 10.00 0.08 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.000002 10.00 0.01 0.00 0.00 0.00 0.00 Glycol ethers 0.000000 10.00 0.00 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Tank 214 P42 / P200 S60 50310003 01/01/12 12/31/12 108101 Methyl isobutyl ketone (Hexone) 0.00014 10.00 0.12 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d.

Hydrite Chemical Co. Tank 215 P42 / P200 S60 50310003 01/01/12 12/31/12 108883 Toluene 0.00003 10.00 0.09 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d.

Hydrite Chemical Co. Tank 218 P42 / P200 S60 50310003 01/01/12 12/31/12 110543 Hexane 0.00001 10.00 0.00 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 67561 Methanol 0.00033 10.00 0.15 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.00006 10.00 0.03 0.00 0.00 0.00 0.00 108883 Toluene 0.00189 10.00 0.86 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.00003 10.00 0.01 0.00 0.00 0.00 0.00 Glycol ethers 0.00000 10.00 0.00 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Tank 219 P42 / P200 S60 50310003 01/01/12 12/31/12 67561 Methanol 0.00001 10.00 0.04 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 108101 Methyl isobutyl ketone (Hexone) 0.00006 10.00 0.20 0.00 0.00 0.00 0.00 108883 Toluene 0.00006 10.00 0.19 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.00002 10.00 0.07 0.00 0.00 0.00 0.00 Glycol ethers 0.00000 10.00 0.00 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Tank 221 P42 / P200 S60 50310003 01/01/12 12/31/12 110543 Hexane 0.00001 10.00 0.01 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 67561 Methanol 0.00000 10.00 0.00 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.00031 10.00 0.34 0.00 0.00 0.00 0.00 108883 Toluene 0.00004 10.00 0.04 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.00011 10.00 0.12 0.00 0.00 0.00 0.00 Glycol ethers 0.00000 10.00 0.00 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Tank 241 P42 / P200 S60 50310003 01/01/12 12/31/12 110543 Hexane 0.00001 10.00 0.01 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 67561 Methanol 0.00022 10.00 0.31 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.00006 10.00 0.09 0.00 0.00 0.00 0.00 108883 Toluene 0.00050 10.00 0.70 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.00004 10.00 0.06 0.00 0.00 0.00 0.00 Glycol ethers 0.00000 10.00 0.00 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Tank 242 P42 / P200 S60 50310003 01/01/12 12/31/12 110543 Hexane 0.00001 10.00 0.03 0.00 0.00 0.00 0.00 Tanks Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Fixed Roof Tank Vented to Control Device 99.9% Control Device = Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using TANKS 409d. 67561 Methanol 0.00008 10.00 0.16 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.00008 10.00 0.15 0.00 0.00 0.00 0.00 108883 Toluene 0.00021 10.00 0.41 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.00003 10.00 0.06 0.00 0.00 0.00 0.00 Glycol ethers 0.00000 10.00 0.00 0.00 0.00 0.00 0.00

Hydrite Chemical Co. NA NA NA 50310006 01/01/12 12/31/12 NA NA NA NA NA NA NA NA NA Transfer Systems Fugitive NA NA NA NA NA NA NA NA NA NA Yes Leak Detection and Repair Program Varies by Equipment OSW transfer systems are comprised of piping. Emissions, which consist of fugitive losses from equipment leaks, are included in the equipment leak calculations.

Hydrite Chemical Co. Luwa 1 P11 S60 50310007 01/01/12 12/31/12 110543 Hexane 0.002 10.00 0.14 0.00 0.00 0.00 0.00 Process Vents Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Combustor 99.9% Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using engineering calculations. 67561 Methanol 0.14 10.00 0.14 0.00 0.00 0.00 0.00 108101 Methyl isobutyl ketone (Hexone) 0.38 10.00 0.14 0.00 0.00 0.00 0.00 108883 Toluene 0.42 10.00 0.14 0.00 0.00 0.00 0.00 1330207 Xylenes (isomers and mixture) 0.49 10.00 0.14 0.00 0.00 0.00 0.00 Glycol ethers 0.27 10.00 0.14 0.00 0.00 0.00 0.00

Hydrite Chemical Co. Column 1 P01 S60 50310007 01/01/12 12/31/12 1330207 Xylenes (isomers and mixture) 0.02 10.00 0.45 0.00 0.00 0.00 0.00 Process Vents Vertical 32.5 400 3 2.85 20.15 NA NA NA -89.198085 43.077956 Yes Combustor 99.9% Thermal Oxidizer - Efficiency based on stack test peformed in 12/2008. Emissions estimated using engineering calculations. 67561 Methanol 0.01 10.00 0.83 0.00 0.00 0.00 0.00

1 For SCC Code, please input one of the following codes: SCC SCC Description 50310001 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Equipment Leaks 50310002 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Containers 50310003 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Tanks 50310004 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Organic and Oil-Water Separators 50310005 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Surface Impoundments 50310006 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Transfer Systems 50310007 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Process Vents

2 See List of HAPs in separate worksheet for a table of CAS numbers and HAPs

3 MACT- allowable emissions are the maximum emission levels allowed while in compliance with the MACT standards

4 Emission point type choices include: fugitive, vertical, horizontal, goose neck, vertical with rain cap, or downward-facing vent

5 Fugitive Angle: Specifies the rotation of the source from north (in the clockwise direction). The location coordinates should reflect the southwest corner of the area source as shown in this graphic:

6 Location of stack or southwest corner of a fugitive emissions release point

7 For control measures, please include all control measures used for that emission point, including but not limited to: (annual average if the parameter varies) Vertical Emissions Release Point Parameters Fugitive Emissions Release Point ParametersEnclosure 2a

Page 2 Please complete this table for all OSWRO emission units. Please report all emissions related to the off-site waste handled and/or treated.

Facility Name Emission Unit ID Process ID Emission Release Point ID SCC Code 1 Emissions Start Date Emissions End Date Pollutant CAS Number 2 Pollutant Name (include organic and non-organic pollutants) Actual Emissions (TPY) MACTAllowable Emissions (TPY) 3 Routine Emissions Max Hourly

(lbs/hr) Startup Emissions (TPY) Startup Emissions

(lbs/hr) Shutdown Emissions (TPY) Shutdown Emissions

(lbs/hr) MACT Source Category Emission Release

Point Type4 Stack Height (ft) Exit Gas Temperatu re (° F) Stack Diameter (ft) Exit Gas Velocity (ft/sec) Exit Gas Flow Rate (ft3/sec) FugitiveLength (EW) (ft) Fugitive Width (N-S) (ft) Fugitive Angle (degrees) 5 Longitude (decimal degrees) 6 Latitude (decimal degrees) 6 Is Control Measure In Place? Control Measure 7 Control Measure Efficiency Comments (annual average if the parameter varies) Vertical Emissions Release Point Parameters Fugitive Emissions Release Point Parameters

Activated Carbon Adsorption list specific type in Control Measure Comments column

Combustor list specific type in Control Measure Comments column Electrostatic Precipitator Fabric Filter/Baghouse Flare Pressurized Tank Fixed Roof Tank Fixed Roof Tank Vented to Control Device External Floating Roof Tank
Fixed Roof Tank with Internal Floating Roof Vapor Balancing Floating Membrane Cover Cover Vented to Control Device High-Efficiency Particulate Air Filter (HEPA) Leak Detection and Repair Program Condenser

Scrubber list specific type in Control Measure Comments column

Multiple Controls in Series list specific types in Control Measure Comments column

Other Control Device describe in Control Measure Comments column

Pollution Prevention Technique describe in Control Measure Comments column

Process Modification describe in Control Measure Comments column

# DRAFT

Pollutant Name CAS No. Acetaldehyde 75070 Acetamide 60355 Acetonitrile 75058 Acetophenone 98862 2-Acetylaminofluorene 53963 Acrolein 107028 Acrylamide 79061 Acrylic acid 79107 Acrylonitrile 107131 Allyl chloride 107051 4-Aminobiphenyl 92671 Aniline 62533 o-Anisidine 90040 Asbestos 1332214 Benzene (including benzene from gasoline) 71432 Benzidine 92875 Benzotrichloride 98077 Benzyl chloride 100447 Biphenyl 92524 Bis(2-ethylhexyl)phthalate (DEHP) 117817 Bis(chloromethyl)ether 542881 Bromoform 75252 1,3-Butadiene 106990 Calcium cyanamide 156627 Captan 133062 Carbaryl 63252 Carbon disulfide 75150 Carbon tetrachloride 56235 Carbonyl sulfide 463581 Catechol 120809 Chloramben 133904 Chlordane 57749 Chlorine 7782505 Chloroacetic acid 79118 2-Chloroacetophenone 532274 Chlorobenzene 108907 Chlorobenzilate 510156 Chloroform 67663 Chloromethyl methyl ether 107302 Chloroprene 126998 Cresols/Cresylic acid (isomers and mixture) 1319773 o-Cresol 95487 m-Cresol 108394 p-Cresol 106445 Cumene 98828 2,4-D, salts and esters 94757 DDE 3547044 Diazomethane 334883 Dibenzofurans 132649 1,2-Dibromo-3-chloropropane 96128 Dibutylphthalate 84742 1,4-Dichlorobenzene(p) 106467 3,3-Dichlorobenzidene 91941 Dichloroethyl ether (Bis(2-chloroethyl)ether) 111444 1,3-Dichloropropene 542756 Dichlorvos 62737 Diethanolamine 111422 N,N-Diethyl aniline (N,N-Dimethylaniline) 121697 List of Hazardous Air Pollutants (HAP)Pollutant Name CAS No. List of Hazardous Air Pollutants (HAP)
Diethyl sulfate 64675 3,3-Dimethoxybenzidine 119904 Dimethyl aminoazobenzene 60117 3,3'-Dimethyl benzidine 119937 Dimethyl carbamoyl chloride 79447 Dimethyl formamide 68122 1,1-Dimethyl hydrazine 57147 Dimethyl phthalate 131113 Dimethyl sulfate 77781 4,6-Dinitro-o-cresol, and salts 534521 2,4-Dinitrophenol 51285 2,4-Dinitrotoluene 121142 1,4-Dioxane (1,4-Diethyleneoxide) 123911 1,2-Diphenylhydrazine 122667 Epichlorohydrin (l-Chloro-2,3-epoxypropane) 106898 1,2-Epoxybutane 106887 Ethyl acrylate 140885 Ethyl benzene 100414 Ethyl carbamate (Urethane) 51796 Ethyl chloride (Chloroethane) 75003 Ethylene dibromide (Dibromoethane) 106934 Ethylene dichloride (1,2-Dichloroethane) 107062 Ethylene glycol 107211 Ethylene imine (Aziridine) 151564 Ethylene oxide 75218 Ethylene thiourea 96457 Ethylidene dichloride (1,1-Dichloroethane) 75343 Formaldehyde 50000 Heptachlor 76448 Hexachlorobenzene 118741 Hexachlorobutadiene 87683 Hexachlorocyclopentadiene 77474 Hexachloroethane 67721 Hexamethylene-1,6-diisocyanate 822060 Hexamethylphosphoramide 680319 Hexane 110543 Hydrazine 302012 Hydrochloric acid 7647010 Hydrogen fluoride (Hydrofluoric acid) 7664393 Hydrogen sulfide 7783064 Hydroquinone 123319 Isophorone 78591 Lindane (all isomers) 58899 Maleic anhydride 108316 Methanol 67561 Methoxychlor 72435 Methyl bromide (Bromomethane) 74839 Methyl chloride (Chloromethane) 74873 Methyl chloroform (1,1,1-Trichloroethane) 71556 Methyl hydrazine 60344 Methyl iodide (Iodomethane) 74884 Methyl isobutyl ketone (Hexone) 108101 Methyl isocyanate 624839 Methyl methacrylate 80626 Methyl tert butyl ether 1634044 4,4-Methylene bis(2-chloroaniline) 101144 Methylene chloride (Dichloromethane) 75092 Methylene diphenyl diisocyanate (MDI) 101688 4,4'¬-Methylenedianiline 101779 Naphthalene 91203Pollutant Name CAS No. List of Hazardous Air Pollutants (HAP)

Nitrobenzene 98953 4-Nitrobiphenyl 92933 4-Nitrophenol 100027 2-Nitropropane 79469 N-Nitroso-N-methylurea 684935 N-Nitrosodimethylamine 62759 N-Nitrosomorpholine 59892 Parathion 56382 Pentachloronitrobenzene (Quintobenzene) 82688 Pentachlorophenol 87865 Phenol 108952 p-Phenylenediamine 106503 Phosgene 75445 Phosphine 7803512 Phosphorus 7723140 Phthalic anhydride 85449 Polychlorinated biphenyls (Aroclors) 1336363 1,3-Propane sultone 1120714 beta-Propiolactone 57578 Propionaldehyde 123386 Propoxur (Baygon) 114261 Propylene dichloride (1,2-Dichloropropane) 78875 Propylene oxide 75569 1,2-Propylenimine (2-Methyl aziridine) 75558 Quinoline 91225 Quinone 106514 Styrene 100425 Styrene oxide 96093 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1746016 1,1,2,2-Tetrachloroethane 79345 Tetrachloroethylene (Perchloroethylene) 127184 Titanium tetrachloride 7550450 Toluene 108883 2,4-Toluene diamine 95807 2,4-Toluene diisocyanate 584849 o-Toluidine 95534 Toxaphene (chlorinated camphene) 8001352 1,2,4-Trichlorobenzene 120821 1,1,2-Trichloroethane 79005 Trichloroethylene 79016 2,4,5-Trichlorophenol 95954 2,4,6-Trichlorophenol 88062 Triethylamine 121448 Trifluralin 1582098 2,2,4-Trimethylpentane 540841 Vinyl acetate 108054 Vinyl bromide 593602 Vinyl chloride 75014 Vinylidene chloride (1,1-Dichloroethylene) 75354 Xylenes (isomers and mixture) 1330207 o-Xylenes 95476 m-Xylenes 108383 p-Xylenes 106423 Antimony Compounds 0 Arsenic Compounds (inorganic including arsine) 0 Beryllium Compounds 0 Cadmium Compounds 0 Chromium Compounds 0 Cobalt Compounds 0 Coke Oven Emissions 0Pollutant Name CAS No. List of Hazardous Air Pollutants (HAP)
Cyanide Compounds 0 Glycol ethers 0 Lead Compounds 0 Manganese Compounds 0 Mercury Compounds 0 Fine mineral fibers 0 Nickel Compounds 0 Polycylic Organic Matter 0 Radionuclides (including radon) 0 Selenium Compounds 0

# Other ICR Response Info.