# SAMPLE QAQC 

# PLAN
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### PLAN IS A MODIFIED VERSION OF AN ACTUAL DOCUMENT SUBMITTEDTO AND APPROVED BY 

### SCAQMD. 

### THENAMES OF THE COMPANIES, MANUFACTURERS, 

### PRODUC-RE- AND PERSONS HAVE BEEN ALTERED AND/OR DELETED FROM THE ORIGINAL DOCUMENT. 

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## CONTINUOUS EMISSIONS MONITORING SYSTEM QUALITY ASSURANCEjQUALITY CONTROL PLAN

PREPARED BY: 

## John Doe Environmental Services December 1, 

## 1998 FOR



# INDUSTRY INTERNATIONAL INC. LOS ANGELES FACILITYINDUSTRY INTERNATIONALINC. LOS ANGELES, CA Continuous Emissions ~onitorin~.~~stem Quality Assurance/Quality Control Plan SectionNo. Distribution Date: 01 -Dec-99 Page No.: 2 of 67 Revision No. 0 Revision Date: 01 -Dec-99



### Distribution Table

Delivered To: Number ofCopies
Industry International, Los Angeles Facility Industry International, Corporate Office Industry International, Regional Office SCAQMD

Approved by:



### Ronald Emil, Ph.D. Vice-President and General Manager Industry International Inc., Los Angeles FacilityINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions ~onitorin~~~~stem Quality AssuranceIQualityControl Plan SectionNo. Table of Contents Date: 01-Dec-98 Page No.: 3 of 67 Revision No. 0 Revision Date: 0 1-Dec-98



### TABLE OF CONTENTS



## .

DESCRIPTION PAGE NO. COVERSHEET 

# . 1 

### TABLE OF CONTENTS 

# . 2 1.0 

### INTRODUCTION 

# . . 6 1.1 Program Goals 

# . . 6 1.2 Organizational Chart 

# . 6 2.0 

### INSTALLATION 

# . . 6



### .- 3.0 

### CEMS GENERAL DESCRIPTION 7 3.1 General Description 

# . 7 3.2 Analyzers Supplied 

# . 7 3.3 Calibration Gases Required 

# . . 8 3.4 PLC Control System 

# . . 8 3.5 Shelter Equipment Controls 

# . 9 4.0 

### ANALYZER SPECIFICATIONS (See Appendix B) 

# . . 10 4.1 Raymond Model 70R (02) OxygenAnalyzer, Range 0- 10%

# . 10 4.2 Raymond Model 12 1 B (NOINOX) Nitric Oxidemitrogen Dioxide Analyzer, Range 0-5Oppm 

# . . 10 4.3 Raymond Model 890 SulfixDioxide (SO2)Analyzers, Ranges 0-250 ppm and 0-5OOppm 

# . 

# . 11 4.4 Rach Series 20 Oxygen (02) Wet Analyzers, Ranges 0-10%and0-25% 

# . . 11 4.5 RachFlo Series 30 Stack Flow Analyzer Systems, Ranges 0-5,839 schand 0-171,429 scfm 

# . . 12 4.6 4R Scientific's SulfixDetectTM Model 6200 Total Sulfur Analyzer, Range 0-200 ppmv 

# . 13 4.7 Rach Cal 50 Series Calorimeter, Ranges 900-1400 btulscf High Heating Value and 0.6-1.0 Specific Gravity 

# . 

# . 14

# - INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions ~onitorin~'~~stern Quality Assurance/Quality Control Plan Section No. Table ofContents Date: 01-Dec-98 Page No.: 4 of67 RevisionNo. 0 Revision Date: 01-Dec-98 

### TABLE OF CONTENTS (Continued) 

### DESCRIPTION 

### 5.0 SAMPLEHANDLING SYSTEM 

# . 5.1 Probe Design and Heated SampleLine Design 

# . 5.2 Heated Sample Line 

# . 5.3 Filtering and Conditioning 

# . 5.4 Flow Measurement Devices 

# . 5.5 Leak Checking 

# . .. 5.6 Interlocks 

### 6.0 DESRIPTION OF SYSTEM CALIBRATION 

# . 6.1 Remote Calibration 

# . 6.1.1 Automatic Remote Calibration

as.. 

### 6.1.2 Manual Remote Calibration 

# . 6.2 Local Calibration (Sample Bypass Testing) 

# . 7.0 

### DESCRIPTIONOF SYSTEM OPERATIONPROCEDURES 

# . 7.1 Scheduled Calibration Procedures 

# . 7.1.1 Automatic Calibration. 7.2 Procedurefor Measurement Correction 7.3 Procedurefor Determination of Out-of-Control Conditions. 

# . 7.4 Corrective Action Procedures to Correct Out-of-Control Conditions 7.5 Documentationof System Operations 

### 8.0 PREVENTATIVE MAINTENANCEPROCEDURES 

# . 8.1 Daily Maintenance 

# . 8.1.1 Instruction for Completing Form Q 

### (See Appendix 

### B) 9.0 

### DATA ACQUISITION SYSTEM 

# . 9.1 Equipment Descriptions 

# . 9.1.1 Raymond Programmable Logic ControllerPLC 5/20 9.1.2 Raymond Operator Interface Module 

# . 9.1.3 Raymond 45-IFE Analog Input Modules 

# . 9.1.4 Raymond 45-OFE Analog Output Modules 

# . PAGE NO.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring-System Quality AssuranceIQuality Control Plan SectionNo. Table of Contents Date: 01-Dec-98 Page No.: 5 of 67 RevisionNo. 0 Revision Date: 01-Dec-98


### TABLE OF CONTENTS (Continued) 

### DESCRIPTION PAGE NO. 9.1.5 Raymond 45-IBD Digital Input Modules 

# . 9.1.6 Raymond 45-OW

### 16 Digital Output Modules. 

### 9.1.7 Infoconcentrator PLC

# . 9.1.8 DCNX System 

### 9.2 CalculationsPerformed in the PLC Control System (CEMS PLC) 

### 9.2.1 Zero and Span Calibration Error Calculation. 

### 9.2.2 Automatic Correction Calculation 

# . 9.3 CalculationsPerformed in the DCNX 

### 9.3.1 Determination ofEmission Rate 

# . 9.3.2 Determination ofFuel Gas Flow Rate 

### 9.4 Missing Data Procedures 

# . 

# - 10.0 QUALITYASSURANCE 

# . 

# . 35 10.1 Data Validation Criteria 

# . 35 10.2 Data Reduction Criteria 

# . 36 

### 11.0 SCHEDULE OF ACTIVITIES 

# . ' 

# . 36 1

### 1.1 Frequency of System Calibration 

# . . 36 

### 11.1.1 Daily Calibration 

# . . 36 1 

### 1.2 Frequency ofPreventive Maintenance 

# . 37 

### 1 1.3 Scheduleof SystemAudi-RE- 

# ., 37 

### 11.3.1 RelativeAccuracy Test Audit. 

# . 37 

### 12.0 SYSTEMAUDIT PROCEDURES. 

# . 38 12.1 RelativeAccuracy Test Audit. 

### 38 12.1.1 RelativeAccuracy Test Audit for Emission Rate Measuremen-RE- 

### 3 8 12.1.2 RelativeAccuracy Test Requirement for Stack Gas Volumetric Flow Measurement System

. 

### 38 12.1.3 Bias Test 

# . 39. . INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions ~onitoring's~stem Quality AssuranceIQuality Control Plan Section No. Table of Contents Date: 0 1 -Dec-98 Page No.: 6 of 67 Revision No. 0 Revision Date: 01 -Dec-98 

### TABLE OF CONTENTS (Continued) DESCRIPTION PAGE NO. 12.2 CylinderGas 

### Audit 

# . 

# . 39 12.3 Record Keeping 

# . . 39 APPENDICES: Appendix A 

## - SystemConfiguration 

# . 

# . 40 Appendix B 

### - Daily~Weekly Operational CheckForm 

# . 43 Appendix C 

## - Routine MaintenanceOperations 

# . 45 Appendix D 

### - Recommended SparePar-RE- Inventory 

# . 48 Appendix 

### E 

## - DiagnosticTes-RE- 

# . 60INDUSTRY INTERNATIONAL INC. 

### I 

### .- LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. 1 & 2 Date: 01-Dee98 Page No. 7 of 66 Revision No. 0 Revision Date: 01-Dec-98



### 1.0 INTRODUCTION 

## - INDUSTRY INTERNATIONALINC.'s Los Angeles Facility is required to demonstrate compliance with the Regional Clean Air Incentives Market (RECLAIM). This program was established by the South Coast Air Quality Management District's (SCAQMD) Regulation 

### XX, which was adopted on October 15, 1993, and air pollution emission regulations 

### as listed 

### in the Code ofFederal Regulations (CFR), Title 40, Part 60, February 21, 1991.To ensure all aspec-RE- of compliance, INDUSTRYINTERNATIONALINC. has developed and implemented this Quality AssuranceIQuality Control Program (QAIQC). This program will outline two very important aspec-RE-. The first aspect is the assessment of the quality of data collected by estimating precision, reliability, accuracy and timeliness. The second aspect is the control and improvement of the quality of the Continuous Emission Monitoring Systems (CEMS) data by implementingquality control policies and defining necessary corrective actions. This document will also dictate the (- 

### measures tobe taken when data qualityhas 

### deteriorated. 

### 1.1 Program Goals 1. To provide 100% data capturewhen heaters are active. 2. To achieve a 

### 95% confidence coefficient for all collected data. 3. 

### Track calibrationdrift

### to eliminate out ofcontrol periods. 4. To provide steps in determining instrumentperformance. 

### 1.2 Organizational 

### Chart Dayto day operations and maintenance will be provided by maintenancepersonnel. Data assessment and reporting will be done by the environmental department manager who will assessthe effectivenessof this manual and initiatechange when warranted. 2.0 

### INSTALLATION 

## - The monitoring systems are located such that the air contaminant and diluent gas concentrationmeasuremen-RE- are representativeofthe stack emissions of the 

### individual processes. The location selection followsthe general guidelines as specified in 40 CFR 60, Appendix 

### B, Performance Specification2, 

### Section 3, and SCAQMD guidelines.

### INDUSTRYINTERNATIONAL INC. 

### LOS ANGELES, CA 

### Continuous Emissions

### MonitoringSystem Quality 

### Assurance/Quality Control Plan SectionNo. 3 

### Date:' 01-Dec-98 Page 

### No.: 8 of66 Revision

### No. 0 Revision

### Date: 01

### -Dec-98 3.0 CEMS GENERAL DESCRIPTION 

## - 3.1 

### General Discussion The Continuous Emissions Monitoring Systems (CEMS) provided has been designed to extract a gaseous sample from Facility exhaust stacks. The CEMS systems continuously measure all parameters necessary to directly determine mass emissions of RECLAIM pollutan-RE- such as Oxides ofNitrogen (NOx) and Oxidesof Sulfur (SOx). This system is also designed to meet all performance standards for CEMS set forth in the RECLAIM Protocols for Reporting and Recording the accumulated data. The Data Acquisition System collec-RE- all of the accumulated data from each of the CEMS systems and calculates the NOx, SOx and stack flow. NOx is calculated fiom nitrogen oxides and oxygen concentrations, SO, is calculated from total sulfur in the fuel gas, and stack flow is calculated fiom the fuel gas flow, heat content and Fd factor per Rule 20 1 1. 3.2 

### Analyzers SuppIied Each ofthe CEMS systems is supplied with an 0, Dry Analyzer and a NOx Analyzer. A 

### couple of them have been equipped with O2 Wet, SO2and Stack Flow Analyzers. The analyzer span ranges selected are based on the expected concentrations of pollutan-REproduced by each source. Refer to the CEMSUnit Specifications Table 3.2.1 for the list of analyzers supplied for each CEMS unit. The following is a summary of analyzers supplied forthe CEMS systems:

a. Raymond Model 70R 

## - Oxygen (0,) Dry Analyzers, Ranges 0-10% and 0-25% b. Raymond Model 121B 

## - Nitric Oxide / 

### Nitrogen Dioxide (NO/NOx) Analyzers, Ranges 0-25 ppm, 0-50 ppm, 0-100 pprn and 0-250pprn c. Raymond Model 890 

### - Sulfur Dioxide (SO2)Analyzers, Ranges 0-250 ppm, 0-500 pprn and 0-2000 ppm. d. Rach Series 2000 

## - Oxygen (02) Wet Analyzers, Ranges 0- 10% and 0-25% e. RachFlo Series 3000 

## - Stack Flow Analyzer Systems, Ranges 0-2,223,000 scfm and 0-171,429 sch f. 4R Scientific's Sulfur Model 1000 

## - Total SulfurAnalyzer, Range 0-200pprn g. Rach Cal 50 Series Calorimeter, Range 900-1400 btulscfHigh Heating Value and 0.6-1.0 Specific GravityINDUSTRY INTERNATIONALINC. LOS ANGELES, CA ContinuousEmissions Monitoring System

#- QualityAssurance/QualityControl Plan Section No. 3 Date: 0 1-Dec-98 Page No.: 9 of 66 RevisionNo. 0 Revision Date: 0 1 -Dec-98 

### 3.3

- 

### calibration Gases Required EPA Protocol 1 gases shall be used to calibrate analyzers. When EPA Protocol 1 gases are not available because National Institute for Standards and Testing (NIST) does not produce Standard Reference Materials (SRM's) for these gases at the appropriate concentration, EPA Protocol 2 may be used to certify calibration gas standards. In the case where no SRM's are available, the facility shall submit a gas calibration protocol for approval, which specifies the steps to be taken for analyzing the concentration and stabilityofcalibrationgases. All calibration gases used during certification tes-RE- and quality assurance and quality control activities shall be certified according to the latest protocol approved by the SCAQMD. The calibrationgas concentrations are selected based on a minimum of 80 percent of the analyzer span range. Refer to the CEMS Unit Specifications Table 3.2.1 for the list of analyzer span ranges supplied in 

### each CEMS unit. Calibration gases required for the CEMS system are summarized as follows:

a. N, zero gas to calibrate the low-level spanrange of all analyzers b. 

### O,/CO span gas mixture to calibrate the high-level span range of the 02and CO analyzers (CO analyzers are for INDUSTRY INTERNATIONAL INC.'s use only.) c. NOx span gas to calibrate the high-level spanrange ofthe NOx analyzers d. SO, span gas to calibratethe high-level spanrange ofthe SO, analyzers e. Multi-componant sulfur span gas to calibrate the high-level span range of the Total Sulfur analyzer f. Ethylenemethane (C, H6 / 

### CH,) span gas mixture to calibrate the high-level span range ofthe 

### BTU analyzer 3.4 

### PLC Control System The Programmable Logic Controller (PLC) system automatically calibrates the analyzers once each day. The calibration is performed by introducing zero and span calibration gases into the sample system. This is accomplished by applying calibration gas at the sampleprobe and allowingthe samplepump to pull the calibration gas through the heated sample line as if it were an actual sample. The PLC control system computes and applies a correction factor to the raw analyzer inpu-RE- by calculating the ratio of the expected gas versus the difference between the actual measured gas and the zero drift factor. The major tasks ofthe PLC control system provided are as follows:

a. Performs 1 -minute rolling averages and 15-minuteblock averages for each of the analyzers.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System ( *< ' Quality AssurancelQuality ControlPlan SectionNo. 3 Date: 01-Dec-98 PageNo.: 10 of 66 RevisionNo. 0 RevisionDate: 01-Dec-98

b. Performs calibrationto correct the following: 1) raw analog input signals from each analyzer 

### in order to apply the corrected analog output signalsto each analyzer 

### 2) 1-minuterolling averages for each analyzer 

### 3) 15-minuteaverages for each analyzer

c. Provides measurement correction and invalidation. d. Collec-RE- and storesthe calibration data for up to 10-days,the 1-minute rolling averages for 1 -hour, and 15-minute averages for up to 10-days. 

### In some cases, the 15-minute averages are stored for only 7 or 8 days due to the PLC's memory capacity limitations.

e. Provides dry contactoutpu-RE- for system alarms. f. 

### In some cases, initiate a sample pump shutdown when chiller failure or moisture in sample is detected. f. Provides analog outpu-RE- to strip chart recorder for recording all raw and corrected analyzerdata.
g. Monitors calibration error alarms and system malfunction alarms. h. Repor-RE- system status, calibration data and analyzer data to the Data Acquisition System via the InfoConcentrator PLC. 

### 3.5 Shelter Environment Controls Each of the CEMS shelters have been provided with environmental controls such as an 

### air conditioning system,pressuring blower, temperature control alarm and pressure purge system. The air conditioning system runs continuously to cool down all instrumen-REand equipment in the shelter at about 70 OF. The pressuring blower provides continuous 

### air flow

### in the shelter independent ofthe air conditioning system. The temperature alarm is designed to alarm when the shelter temperature exceeds about 85 OF, which is within the manufacturers temperature requiremen-RE- for the instrumen-RE- and equipment in the CEMS shelter. The pressure purge system is used for declassifying purposes.INDUSTRY INTERNATIONALINC. LOS ANGELES, CA Continuous Emissions Monitoring System 

## f -- Quality Assurance/Quality ControlPlan SectionNo. 4 Date: 01-Dec-98 Page No.: 11of66 RevisionNo. 0 Revision Date: 01-Dec-98



### 4.0 ANALYZER SPECIFICATIONS(See Appendix 

### A 

## - System Configuration) 

## - The selected analyzers meet or exceed the performance requiremen-RE- set forth 

### in RECLAIM Protocol SCAQMD Rules 201 1 and 20 12, and minimum specifications as presented in SCAQMD Reference Method 100.1, 

### , and 40 CFR 60, Appendix B, Performance Specification 2, Section 4. Instrument specifications will also be consistent with requiremen-RE- in EPA Reference Methods 

### 3A, 6C, 7E, or 10, as applicable for method of detection, sensitivity, noise, precision, linearity, and interference. Detailed system information can be found in the specific technical manuals or in the system documentationprovided by each analyzer manufacturer. 4.1 Raymond Model 70R (03Oxygen

### Dry Analyzers, Ranges 0-10% and 0-25% The Raymond Model 70R Oxygen Dry Analyzer provides continuous readout of the oxygen content of a flowing gas sample. The determination is based on measurement of the magnetic susceptibility of the sample gas. Oxygen is strongly paramagnetic while most other common gases are weakly diamagnetic. The instrument provides direct readout of 0 to 10% or 25% oxygen concentration on a fiont panel digital display. In addition, a field-selectable voltage output of 0 to +5V is provided as standard. An 

### isolated current output of 0 to 20 ma or 4 to 20 ma is obtainable through plug-in of an optional circuit board. Current and voltage outpu-RE- may be utilized simultaneously if desired. An alarm option is also available by way of a relay assembly that moun-RE- at the rear of the case with a cable that plugs into the Control Board. Customer connections are available on this assembly. The. basic electronic circuitry is incorporated into two master boards designated the Control Board assembly and the Power Supply Board assembly. The Control Board has receptacles that accept optional plug-in current outputboard and alarm features. 4.2 Raymond Model 121B(NO/NOx)Nitric Oxide / 

### Nitrogen Dioxide Analyzers, Ranges 0-25 ppm, 0-50 ppm, 0-100 ppm and 0-250 ppm The Raymond Model 121B NO/NOx Analyzer continuously analyzes a 

### flowing gas sample performing one oftwo switch selectabledeterminations: 1. 

### Nitric Oxide (NO); or 2. Combinednitric oxide (NO) and nitrogen dioxide (NOz)designatedNOx. By definition [NOx]= 

### [NO] 

### + WO2].INDUSTRY INTERNATIONALINC. LOS ANGELES, CA Continuous Emissions Monitoring System (- Quality Assurance/Quality Control Plan SectionNo. 4 Date: 01 -Dec-98 PageNo.: 12 of66 Revision No. 0 Revision Date: 01-Dec-98 The analyzer utilizes the Chemiluminescent method of detection in the nitric oxide determination, sample NO is quantitatively converted into NO2 by gas-phase oxidation with molecular ozone produced within the analyzer from air or oxygen supplied by an external cylinder. A characteristic of this reaction is elevation of approximately 

### 10% of the NO2molecules to 

### an electronically excited state, followed by immediate reversion to the non-excited state accompaniedby the emissionofphotons. The emitted photons impinge on a photo-multiplier detector generating a low-level DC current. The current is amplified to drive a front panel meter and 

### an accessory potentiometric recorder 

### if desired. 

### 4.3 

### Raymond Model 890 

### SulfurDioxide (SO,) Analyzers, Ranges 0-250 

### ppm, 0-500 

### and 0-2000 

### ppm The Raymond Model 890 Sulfur Dioxide (SO,) Analyzer provides continuous measurement of sulfur dioxide content of a flowing gas sample. This analyzer utilizes an ultraviolet source which emi-RE- a pulsed (80Hz)beam of energy. This energy is splitby a beam splitter, each beam being directedto pairs of detectorsbefore and after the sample cell. This analyzer uses a spectrally selective mirror to isolate the sample and reference spectral passbands for the detectors. They reflect energy below a wavelength region and transmit the remaining, higher wavelengths, all with much lower energy loss than the more commonly used bandpass interferencefilters. Four detectors are used in this system,two before the sample cell and two after



### . These four detectors measure SO, concentration and correct for NO, interference and 

### UV lamp fluctuations. The differencebetween detector determinationsis the SO, concentration. The sample is introduced to the sample cell and the component of interest absorbs ultraviolet energy 

### in proportion to the concentration of the gas. The difference between the signals of the detectors located at both ends of the sample cell determines the concentration of SO, in the sample. Additionally, the adjacent (non-SO,-absorbing) reference wavelengths are used as a baseline for measurement and correction of sample interferencecomponen-RE-,particularlyNO,. 4.4 

### Rach Series 2000 

### Oxygen (02)Wet Analyzers, Ranges 0-10% 

### and 0-25% The Rach Series 2000 Oxygen Wet Analyzer provides continuous measurement of oxygen content of a flowing gas sample. This analyzer consis-RE- of an oxygen sensing cell, aspirator assembly, control unit and temperature system.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System 

## i 

# - Quality Assurance/Quality Control Plan SectionNo. 4 Date: 01-Dec-98 ' PageNo.: 13of 66 Revision No. 0 Revision Date: 01-Dec-98 A sample is drawn from the process stream by means of an air-operated aspirator and is immediately returned to the process. A portion of this gas rises past the oxygen sensing cell and returns to the primary loop. All sample wetted par-RE- are heated to maintain the sample above the dewpoint of the gas. The working element of the oxygen gas sensor is a closed-end tube made of a ceramic oxide, Zirconium Oxide. When the sensing cell is hot, it becomes a conductor of electricity because of the mobility of the oxygen ions in i-RE- crystal structure. Thus, a voltage is produced that is logarithmically proportional to the ratio of the oxygen concentration of the gas on the reference side of the cell (usually ambient 

### air) and the oxygen concentration of the sample. The percent oxygen value will appear on the microprocessor control unit display. The sensing cell is a partial pressure device and responds directly to changes in samplepartial pressure. When the two electrode coatings are in contact with gases (at the same nominal pressure) that have different levels of oxygen concentration (or different partial pressures), a voltage is produced that is dependent upon their ratio. If the oxygen gas is known (the reference gas is normally air at 

### 20.9% 

### 03, the oxygen of the other then is indicated directlyby the voltage fiom the cell. 4.5 RachFlo Series 3000 StackFlow Analyzer Systems, Ranges 0-2,223,000 scfm and 0-171,429 scfm The RachFlo Series 

### 3000 Stack Flow Analyzer provides continuous, accurate, and reliable volumetric flow monitoring for stacks of any size and configuration. RachFlo's flow monitoring system consis-RE- of in-stack flow measurement equipment (STACKprobes), auto-purge system and flow monitoring instrumentation. The RachFlo STACK-probe is used to accurately monitor the average flow and temperature of the stack emissions based on differential pressure (Pitot-Fechheirner) method for measuring airflow. Each STACK-probe consis-RE- of two separate round tube self-averaging manifolds; one to measure the stack total pressure, and the other to measure stack static pressure. Flow rate monitoring is performed by sensing individual flow componen-RE- at multiple poin-RE- (traversing) across one or more diameters for circular stacks or along multiple parallel traverses for rectangular stacks, and averaging the obtained values. Similarly, average stack temperature is measured using a thermocouple probe with multiple temperature sensing elemen-RE- spaced along the probe length. The RachFlo AUTO-purge system required for differential pressure flow monitoring systems is a back purging means to insure that the in-stack flow monitor probe has i-REpressure sensing por-RE- and averaging manifold maintained fiee of particulate or condensation. This system sequentially operates a combination of valves to periodicallyINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System i 

# -- Quality Assurance/QualityControl Plan Section No. 4 Date: 01-Dec-98 Page No.: 14of 66 Revision No. 0 Revision Date: 01-Dec-98 and automatically back purge the sensing lines and the STACK-probes with high volurne/high pressure compressed air for a short duration, while simultaneously locking in the transmitter output and isolatingthe transmitter fiom over-pressurization. The RachFlo Series 

### 3000 flow monitoring instrumentation is the means to amplify, linearize, and scale the differential pressure flow signals received fiom the in-stack probes to generate a continuous output signal representing the volumetric flow 

### in SCFM (wet basis) being discharged into the atmosphere. The Flowmeter is an ultra-low differential pressure transmitter with built-in signal conditioning, square-root extractor, scaling multiplier, auto-calibration circuitry and circuitry for temperature and pressure correction of ACFM to SCFM. An integral LED digital display provides local readout of stack SCFM and temperature. 4.6 

### 4R Scientific's Sulfur Model 1000 Total Sulfur Analyzer, Range 0-200 ppmv 4R Scientific's SulfurDetectTM precision series of analyzer provide on-line analytical measurement ofhydrogen sulfide (H2S)concentrations. The ~ach~hem~ technology provides H2S-specific, interference-fiee, detection and measurement. Hydrogen sulfide detection and concentration analysis by the use of RachChemTM are based on chemical factors and physical constan-RE-, which confirm the unique analytical precision of the technology. 4R Scientific's SulfurDetectTM H2S monitor utilizes a single optical sensor and light sourceto detect and measure the rate of lead sulfide formation. The single optical sensor used in SulfurDetectTM series functions as both a reference and measurement optical sensor. At the beginning of each measurement cycle the tape advances to a new or unexposed portion of the tape. Instantly, asthe tape stops, the optical sensor value is fed into a circuit driving a preamplifier into an

### AD converter, and the resultant voltage level is stored in the microprocessor memory section. A new optical sensor reading is comparedto the stored information. At this point, the microprocessor determines the level of H2S by comparing the two readings, and displays the result on the digital display in engineering uni-RE- as selected at the time of order, such as PPM by volume, weight or grains11

### 00 standard cubic feet or mole %. Simultaneously, the second reading is stored in the memory for later comparison to a third reading. The cycle is repeated on an average of every second, until the tape is too dark for further accurate readings and the complete cycle star-RE- again. Effectively, a new zero or reference point is selected with each reading after the initial period. Temperature drift is virtually eliminated, as it is confined to a time span of less than 10-seconds.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. 4 Date: 0I-Dec-98 Page No.: 15 of 67 Revision No. 0 Revision Date: 01 -Dec-98

As the 

### H,S level is displayed, it is used to actuate any alarms, if the level is above the alarm setpoint, and drive the optional 4-20mA loop and chart recorder. 

### Rach Cal50 Series Calorimeter, Ranges 900-1400 btulscfHigh Heating Value and 0.6-1.0 Specific Gravity The Rach Cal 50 Series Calorimeter is a high-speed (6 to 

### 8 seconds response) instrument. The variations in the rate of heat released from a continuously burning gas are fed back via a thermal expansion element to a flapper-nozzle control system, which adjust the flow of cooling air to the air orifice and subsequently the burning chamber. The varying flow of air is used to control the temperature of the combustion product. Thus, the air flow varies according to the heat released by the gas. Measuring the air flow would provide a direct measurement ofthe heat value ofthe burning gas. The pressure across the air orifice is measured by a differential pressure transducer. The pressure differential across the air orifice is an indication of a change 

### in flow rate of the air. This is proportional to the measured heat value within the calibrated range of the Calorimeter. Utilizing the constant volume positive displacement metering pump allows the Calorimeter to measure the Calorific Value instead of Wobbe Index. Thus, the calorimeter would measure, with a calculated offset, the gross calorific value. The calorific value, measured in BTUISCF, is defined 

### as: Calorific Value =Heat Energy Unit Volume at standard pressure and temperature 30" Hg 

### @ 60°F = BTUISCF 760rnrn Hg, 0°C for ~cal/~m~. As stated, calorific value, the heat value at standard conditions is expressed as the Gross Heating Value, which is the theoretical heat value of the sample gas at standard conditions. The Calorimeter uses a programmable low pressure transmitter for accurate differential pressure measurement. The micro-processor based transmitter monitors the differential pressure across the air orifice supplying a continudus 4-20mAdc output signal, which is proportional to the heat value.

### INDUSTRY INTERNATIONALINC. LOS ANGELES, CA ContinuousEmissions

### MonitoringSystem 

### (- Quality 

### AssuranceIQualityControlPlan Section

### No. 5 Date: 0 

### 1-Dec-98 Page

### No.: 16of 66 Revision

### No. 0 Revision Date: 01 -Dec-98



### SAMPLE HANDLING SYSTEM .The gas sample extraction and conditioning equipment (probe, filter, pump, conditioner, connective plumbing, etc.) associated with each monitoring system will meet or exceed minimum specifications as described in SCAQMD Reference Method 100.1 and RECLAIM guidelines. The function of the sample handling system is to extract a gaseous sample continuously fiom the point of measurement of the flue gas stream, condition and cool the sample to below the dew point, and deliver a dry sample to the analyzers. A heated sample line is used between the point of measurement and the sample conditioning cabinet to keep the gaseous stream above the 40°F dew point. A temperature controller holds the heated sample linetemperatureto between 275°F and 350°F. 5.1 ,- 

### Probe Design and Sample Line Design The probe is constructed of a 3/4-inch stainless steel horizontal element filter with a maximum temperature rating of 400°F. The heated sample line contains two heated-and hvo unheated Teflon tubes. The heated tubes accommodate the sample 'gas and calibration gas, while the unheated tubes are not used. The sample gas, calibration gas and air blowback flow are controlled by two solenoid valves. During normal operations, both solenoidvalves are in the "off"position, which allowsthe sample gas from the stack to go throughtheprobe and sample line and down to the analyzers. During blowback and remote calibration,both solenoid valves are in the "on" position, which allows air to be blown back into the probe, filter and sample lines, as well as, allow calibration gas to pass through the probe and sample line and downto the analyzers. 

### 5.2 Heated Sample Line The heated sample line temperatures are controlled using individual temperature 'controllers, panel items TC1 and TC2, respectively. 

### In both cases, a two (2) wire temperature element is used to sense the temperature. 208 VAC power is applied as necessary to the heating element to control the sensed temperature of the set point value which should be 275350°F. 

### 5.3 Filtering and Conditioning The.sample handling system contains a single stage 

### AD1 @IA-VAL 19310T) sample pump. 

### This system is located on the wall of the analyzer shelter. The sample is introduced into the Universal Analyzer, Inc. (Model 1050) single channel sample cooler where the outlet sample dew point is 41°F (5°C). The water that is dropped out duringINDUSTRY INTERNATIONAL INC. LOSANGELES, CA Continuous Emissions MonitoringSystem Quality Assurance/Quality Control Plan SectionNo. 5 Date: 01-Dec-98 Page No.: 17of67 Revision No. 0 Revision Date: 01 -Dec-98 this stage is collected in a built-in reservoir. The reservoir is drained continuously by a 4R Peristalic pump. Once the sample gas has passed through the sample pump, it is pushed into the sample dryer assembly. Before the sample leaves the sample dryer assembly, it passes through a moisture monitor which detec-RE- if any moisture is left in the sample gas indicating improper dryer operation. If moisture is detected, an alarm is generated and the sample pump is automatically shutdownto protect the analyzers. 

### 5.4 Flow Measurement Devices Once the sample gas has passed through the sample dryer assembly, the sample gas is directed to the instrument panel IP which is mounted on the cabinet. Sample pressure is indicated on a pressure gage. Sample pressure is also monitored using pressure switch VPS. 

### An alarm contact is activated if the sample pressure drops below the normal value. The pressure gage normally reads between 4 to 

### 6 PSIG. The sample gas flow is split by using two needle valves with flow indication. The two valves are piped in parallel. The valve labeled "BY-PASS FLOW" direct the sample gas to an ambient vent. The valve labeled "SAMPLE FLOW" direct the sample gas to the analyzers. The two valves must be adjusted together to set up the correct flowto the analyzers which is approximately 50- 500 cclmin at 10PSIG maximum for the Oxygen analyzer and 2000 cclmin for the NOx analyzer. The Oxygen analyzer receives the sample via gas flow through the 

### 0, analyzer solenoid valve. The 

### 0, analyzer output a linear 0 to +5 VDC signal proportional to the oxygen content in the sample gas. This output is wired to the PLC and strip recorder. The analyzer also has a vent which direct the measured sample gas to atmosphere. Refer to the Model 70R instruction book number 01 5-748213-5 for detailed information concerning the operation ofthe oxygen analyzer. The NOx analyzer receives it's sample via gas flow through the NOx analyzer solenoid valve. The NOx analyzer output a linear 0 to +5 VDC signal proportional to the NOx content in the sample gas. This output is wired to the PLC and strip recorder. This analyzer also has a vent which direct the measured sample gas to atmosphere. Refer to the Model 121B instruction book number 01 5-556383-U. It is important to note that each of the above described solenoids is a normally closed valve which are held open, energized under normal operating conditions. This sample conditioning system contains interlocks which will close the solenoid

. valve automatically, to protect the analyzers, if the proper operating conditions are not met. These interlocks will be described in Section 5.6 below. 

### 5.5 Leak CheckingINDUSTRY INTERNATIONALINC. LOS ANGELES, CA Continuous Emissions Monitoring System (- Quality Assurance/Quality Control Plan Section No. 5 Date: 0 1 -Dec-98 Page No.: 18of 66 Revision No. 0 Revision Date: 01-Dec-98

Leaks in the sample lines can be checked by manually performing a remote and local calibration (sample bypass testing), and comparing the raw input signals going into the analyzers. The analyzer input measuremen-RE- resulting fiom local calibration should match the values resulting fiom remote calibration. 

### A mismatch in measuremen-RE- may indicate a leak in the sample lines. 

### A second test method is to reduce the gas pressure on the Zero calibration gas bottle to less than 

### 5 psig and observe the 

### O2reading during a remote manual zero gas calibration. Because the gas pressure is low, the sample pump will increase suction and if there are any leaks in the sample system, air will be drawn into the sample system and you will see an increase in the 

### O2reading. This increased reading is due to a leak in the sample system. 5.6 

### 'Interlocks Several safety interlocks have been provided with this system to protect the analyzers fiom being damaged. The goal is to keep the analyzersfiom being subjected to moisture. Below is a list of interlocks which, if not satisfied, will automatically shut down the sample pump.

a. ChillerFailure b. High MoistureContent in Sample A chiller failure alarm indicates a high moisture content in the samples resulting fiom the chiller malfunction. When this alarm condition occurs, alarm messages shall be indicated on the PLC operator interface display. The alarm messages will clear only when the problem indicated on the alarm messages are fixed.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System 

### i 

# - Quality Assurance/Quality Control Plan Section No. 6 Date: 01 -Dec-98 Page No.: 19 of 66 Revision No. 0 Revision Date: 01 -Dee-98



### DESCRIPTION OF SYSTEM CALIBRATION calibration gases are used to calibrate the analyzers. The CEM systems supplied offers several options for applying calibration gas to the analyzers. Calibration gas can be injected "automatically" or "manually"in remote mode, or "manually" in local mode. Per 40 CFR Part 60, zero and span gases must be applied once every 

### TWENTY FOUR HOURS to calibrate analyzers. The following discussion will describe the various methods for calibration. 

### 6.1 Remote Calibration b Remote calibration is the method most often used for this application. Remote injection means that the calibration gas is introduced to the sampling system by injecting the gas at the sampleprobe. The calibration gas is then drawn into the sample conditioning system the same as a normal sample as described above. This allows the whole system to be exposed to the calibration gas which will show any malfunctions such as leaks. Remote calibration operation can be initiated manually or automatically. It is important to note that automatic and manual initiation of calibration is accommodated throughathe PLC operator interface. 

### 6.1.1 Automatic Remote Calibration Automatic remote calibration can be initiated automatically at a preset time once daily or instantaneously by operator command on the PLC operator interface. Initiating automatic calibration at a preset time is the most common calibration method used. Initiating automatic calibration instantaneously is required only after performing manual calibration. Zero and span calibration gases for each analyzer are automatically applied. The automatic calibration determines the numbers used in the calculation of the corrected analog values, 1-minute and 15-minute values. The readings are taken at the time the appropriate cycle is complete. All automatic calibration data, such as date and time of calibration, zero and span calibration gas values (expected values), actual readings and deviation values, are stored in the PLC data files and are retained for 10-days. This data stored shall be transferred to the Infoconcentrator for the DCNX system to access.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System Quality AssuranceIQuality Control Plan SectionNo. 6 Date: 01-Dec-98 PageNo.: 20 of 66 RevisionNo. 0 Revision Date: 01-Dec-98



### 6.1.2 Manual Remote Calibration Manual remote calibration can be initiated at the PLC operator interface. This calibration method allows the operatorto inject any zero or span calibration gas to all analyzers in the CEMS system. For example, if O2 span gas is selected for injection, the PLC processor will operate the following solenoid valves (SOV) to allow the calibration gas to flow up to the sample probe via a second tube in the heated sample line: local/remote SOV is switched to remote position, the O2 span calibration gas SOV is opened, the bubbler SOV is closed, and the sample probe blowback SOV is energized. The test gas is then drawn down the sampletube of the heated sample line and into the CEMS analyzers. With the sample probe blowback SOV energized, instrument 

### air is blown back through the sample probe back flushing it with air to clean and clear it. This blowback occurs duringthe calibrationperiod. Applying other calibration gases to the system result in the same operation except that different set of solenoidvalves open. 6.2 Manual Local Calibration Applying calibration gases locally is an option which can only be accomplished manually. It is used for sample line leak checking or analyzer maintenance. Zero and span calibration gas injection can be locally controlled by the PLC operator interface. It is important to note that when calibration gas in injected locally, it is directed only to the selected analyzer as opposed to all analyzers during aremote operation. For example, if O2 span gas is selected, the PLC processor will operate the following solenoid valves (SOV): locallremote remains in local position, the O2 analyzer SOV is opened, and the bubbler SOV is closed. The sample probe solenoid will remain deenergized, thus cutting off the sample, and the span calibration gas is transported directly to the analyzer. The needle valve just ahead of the analyzer is used to adjust the test gas flow. Applying other calibration gases locallyto the individual analyzers will result in the same operation as described above, except that different solenoid valves open for the other calibration gas selections.INDUSTRY INTERNATIONALINC. LOS ANGELES, CA 

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### DESCRIPTION OF SYSTEM OPERATION PROCEDURES This section will describe procedures developed to meet RECLAIM Protocol SCAQMD Rules 201 1 and 2012, Appendix A. 

### Scheduled Calibration Procedures 

### 7.1.1 Automatic Calibration Initiate the automatic calibration automatically once a day at a preset start time or manually by operator command via PLC operator interface. The auto-calibration shall be initiated instantaneously only after a manual calibration in order for the PLC processor to adjust the calibration factors to the newly calibrated analyzer output. Once the automatic calibration is initiated, the processor will hold the last transmitted sample gas data and will automaticallybegin the following calibration sequence. Note that for the entire duration of the auto-calibration sequence, the bubbler solenoid is closed and the probe solenoid valves are energized. Each calibration gas is applied to the analyzers for 3-minutes, with the exception of the 

### 0, Wet and StackFlow analyzers. Thus, the total duration forthe auto-calibration sequence is dependent on the number ofcalibration gases to be applied. 1. Zero gas is the first gas to be applied to all analyzers via the sample probe and sample line. After 3-minutes, all solenoid valves are reset and the zero calibration errors are calculated. 2. O,/CO Span gas is applied to the 

### 0, Dry and CO analyzers via the sample probe and sample line. After 3-minutes, all solenoid valves are reset and the 02and CO span calibration errors are calculated. (The CO analyzer is for INDUSTRY INTERNATIONALINC.'s use only.) 3. NOx Span gas is applied to NOx analyzervia the sample probe and sample line. After 3-minutes, all solenoid valves are reset and the NOx span calibration errors are calculated. 4. This step is for INDUSTRY INTERNATIONAL INC.'s use only. PreSCR NOx Span gas is applied to the Pre-SCR NOx analyzer via the sample probe and sample line. After 3-minutes, all solenoid valves are reset and the Pre-SCR NOx span calibration error are calculated.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA *. Continuous Emissions Monitoring System Quality AssurancelQuality Control Plan SectionNo. 7 Date: 0 1 -Dec-98 Page No.: 22 of 67 RevisionNo. 0 Revision Date: 01-Dec-98 5. For CEMS systems with SO, analyzer, the SO, Span gas is applied to SO, analyzer via the sample probe and sample line. After 3-minutes, all solenoid valves are reset and the SO, span calibration errors are calculated. 6. For CEMS systems with 0, Wet analyzer, the PLC processor initiates the 

### 0, Wet analyzer calibration by triggering a digital output signal to the analyzer. Prior to calibration, the time duration values for zero and span calibration should be programmed into the analyzer control unit. The time duration values should also be entered into the PLC operator interface for the purpose of monitoring calibration data. Once the 

### 0, Wet analyzer calibration sequence is completed, the 

### 0, Wet zero and span calibration errors are calculated. 

### 7. For CEMS systems with Stack Flow analyzer, the PLC processor initiates the Stack Flow analyzer calibrationby triggering a digital output signal to the analyzer. The analyzer will hold the last transmitted flow value for 60- secondsbefore beginning zero calibration. Zero calibration will occur for 60-seconds. There's a 30-seconds delay prior to the start of Span calibration. Span calibration will occur for 60-seconds prior to resuming the normal sample flow. At the completion of Stack Flow analyzer calibration sequence, the Stack Flow zero and span calibration errors are calculated. 

### 7.2 Procedure for Measurement Correction Measured analyzer signals are corrected when excess analyzer drift is detected. Calibration errors for each span gas and zero gas are calculated and compared to the calibration limit after an automatic calibration. Whenever the calibration limit are exceeded, the raw analog input signals, the 1-minute and 15-rolling averages are corrected based on the calculated correction factor and zero drift factor. These limits are as listed below: NOx Zero Limit - 2.0% of span NOx Spa Limit - 2.5% of span SO, Zero Limit - 2.0% of span SO, Span Limit - 2.5% of span 

### 0, Zero Limit - - 0.5% 

### 0, 0, SpanLimit 

### - - 0.5% 

### 0, 

# - 7.3 

### Procedure for Determination of Out of Control Conditions An out-of-controlperiod occurs when,INDUSTRY INTERNATIONAL INC. LOSANGELES, CA 

### ..". Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. 7 Date: 0 1-Dec-98 Page No.: 23 of 67 Revision No. 0 Revision Date: 01-Dec-98 the calibration error of an 

### 0, analyzer exceeds 

### 1 percent 

### 02, or when the calibration error of a NOx or SO, analyzer exceeds 5 percent based upon the span range value. The out-of-control period.begins with the hour of completion of the failed calibration error test and ends with the hour ofcompletion of following an effective re-calibration. Measured signals are invalidated when the calibration errors exceed the "Out of Range" or "Out of Control" limit Calibration errors or analyzer drift for each span gas and zero gas are calculated and compared to the "Out ofRange" and "Out of Control" limit after an automatic calibration. If any ofthe NOx, SOxor

### 0, zero or span calibration errors exceed the "Out of Control" limit listed below, then the measurement will be flagged as invalid data. NOx Zero or Span Out of Control Limit = 

### 5.0% of span SO, Zero or Span Out of Control Limit = 

### 5.0% of span 

### 0, Zero or Span Out of ControlLimit = 

### 1 

### .O% 0, The NOx measurement will also be flagged as invalid data if the measured sample gas concentration (analyzer raw reading)does not fall within the "Out ofRange" Limit of 

### .Ol 

## - 95% of span. For the SO, analyzer or fuel gas sulfur content analyzer, the same "Out of Range" limiRE- apply. 7.4 

### Corrective Action Proceduresto Correct Out of Control Conditions Out-of-Control conditions occur when calibration fails due to CEMS system malfunction. The CEMS PLC is designed to monitor different par-RE- of the system, in order to determine the source of failure quickly and efficiently. The system malfunctions when the following occurs:

a. sample pump failure b. chiller failure c. probe temperature is high or low d. sample line temperatureis low e. analyzer failure When any of the above malfunctions occur, the CEMS PLC system will trigger an alarm which will be stored in the PLC and displayed on CEMS annunciator panel. The maintenance personnel will investigate and correct system malfunctions as soon as they occur. The analyzers will then be re-calibrated using the manual remote calibration procedure. Adjust the calibration, at a minimum, whenever the daily calibration error exceeds the limit of the applicableperformance specification for the 

### 0, monitor and NOxINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions MonitoringSystem Quality Assurance/QualityControl Plan Section No. 7 Date: 01 -Dec-98 Page No.: 24 of66 Revision No. 0 Revision Date: 01 -Dec-98 NOx monitor. Re-calibration, following an adjustment or repair, will demonstrate that the corrective actions taken were effective. Whenever the failed calibration, corrective action and effective re-calibration occur within the same hour the hour is not out-of control 

### if 

### 2 or more valid 15-minute readings are obtained during that hour. 

### 7.5 Documentation of System Operations INDUSTRY INTERNATIONAL INC. will record and store raw and corrected concentrations 

### in par-RE- per million (ppm) and percent (%) on a strip chart recorder. A chronological file shall be maintained and retained for a minimum of three years, which includes:

a. All strip chart recordings. b. All valid averages. c. Data andresul-RE- for all performance tes-RE- and re-calibrations. d. A record of any repairs, adjustmen-RE- or maintenance to the monitoring system; ofwhich a system log book will be maintained. The following information will be reported electronicallyby a Remote Transmitting Unit (RTU) to the agency on a dailybasis:

a. The previous day's NOx emissions, 

### in pounds, for each Major NOx RECLAIM devicewith status codes. b. The previous day's SOX emissions, 

### in pounds, for each Major SOX RECLAIM device with status codes. INDUSTRYINTERNATIONAL INC.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA

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### PREVENTIVE MAINTENANCE PROCEDURES Preventive maintenance requirement are described in the instruction and operation manual. Due to the method and complexity of these analyzers, daily, bi-weekly and monthly maintenance routines are required to maintain equipment operation. Sample system bias testing shall also be performed on an "as needed" basis to insure relative accuracy of the CEMS system. The following preventive maintenance procedures shall be implemented to minimize CEMS breakdown. 

### 8.1 Daily Maintenance Daily maintenance will be performed to maintain continuous uninterrupted operation of the system. Abnormal findings will be reported immediately to the appropriate maintenance authority. This will assure minimum downtime and accurate data recovery. The daily calibration log generated by the data acquisition system will be used by the Instrument Department to track the operation of the system, as well as, assess the calibration drift of the daily zero and span checks. This data will also be utilized by management to determine the success of the QNQC manual and direct appropriate changes asrequired. 

### 8.1.1 Instruction for 

### CompletingForm Q (See Appendix

### B) The Instrument Department will be responsible for verifying all data printed during each day shift. A daily system verification form will also be completed. The majority of this form requires only a check mark indicating that the specific operating parameter was verified. Any problems found should be reported immediately. Step Procedure A. At Analyzers 1. Proceed to enclosure of first set of analyzers 2. Check and record flow meter settings 

### 3. Check and record systemback pressure 4. Check condensateremoval system for operation and clean drains 

### 5. Record condensertemperature 

### 6. Check and record probe and line temperatures 7. Check calibration cylinder pressure readings. Replace if below 200 PSIINDUSTRY LNTERNATIONALINC. LOS ANGELES, CA 

### *. ContinuousEmissions Monitoring System Quality Assurance/Quality Control Plan Section No. 8 Date: 01 -Dec-98 Page No.: 26 of 67 RevisionNo. 0 Revision Date: 01 -Dec-98 

### 8. Initial check list and proceed to next enclosure B. At Recorders 

### 1. Examine strip chart recorder operation 

## - printing legibly and operatingnormally 

### 2. Check if ink and paper are sufficientto operate for the next 

### 24 hours 

### 3. Reviewthe last automatic calibration data 

### 4. Log actual readings of zero and span, and calculate the zero and span calibration error 

### (drift). 5. Compare the calculated calibration error 

### (drift) to the "Out of Range" and "Out of Control" limits. Ifthe calibration error exceeds the limit, report to the supervisor; take corrective action and log problem; corrective actiontaken, and period ofinvalid dataINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA

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9.0 

### DATA ACQUISITION SYSTEM 

## - 9.1 

### EquipmentDescriptions 9.1.1 

### Raymond Programmable Logic Controller PLC 5/20 The Raymond Programmable Logic Controller PLC 5/20 is a complete PLC control or CEMS PLC system which collect and stores data, performs computations, automatically correct- and invalidates data, performs control sequences, and communicates to a DCNX system via the Infoconcentrator. The PLC for this project has been programmed to perform all of the above functions. The PLC utilizes PLC5 Logistics software in order to run the CEMS PLC program. The following discussion will cover the specifics of this project. Reference the Raymond PLC 5/20 User's Manual for general information about the PLC.

.- 9.1.2 

### Raymond Operator Interface Module The Raymond operator interface module provides the capability for operators to input data and retrieve data fiom the PLC. It also functions 

### as a message display. The operator interface has the following features:

a. Displays calibration and analyzer data. b. Allows the operator to input zero and span calibration gas data (expected values). c. Allows the operator to set the time for initiating automatic calibration. d. Allows the operator to initiated the automatic calibration sequence manually after performing a manual calibration. e. Allows the operatorto initiate the remote or local manual calibration. f. Allows the operator to set the time duration for zero and span calibration for the 

### 0, Wet analyzer, if applicable. g. Allows the operator to initiate the 

### 0, Wet and Stack Flow analyzer calibration sequence.

9.1.3 

### Raymond 45-IFE 

### Analog Input Modules The analyzers deliver 0 to +5 Volt signals. The analog input channels are configured for -5V to +5V in order to detectzero drift below zero vol-RE-.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA 

# - Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. 9 Date: 01-Dec-98 PageNo.: 28of67 Revision No. 0 Revision Date: 01 -Dec-98 A raw signal from each of the analog input channels is read by the PLC processor once every 10-seconds from which the 1-minute and 15-minute averages are computed and stored. Each CEMS PLC system has been provided with an analog input card containing eight (8) input channels. The input channel designationsvaries with each CEMS system. The first three channels, assignedto NOx, CO and O2analyzers, are typical for all CEMS PLC systems, except 

### in Uni-RE- 41-MG-1 and 88. In Unit 41-MG-1, channel 2 is assigned to a SOX(Lo) analyzer. In Unit 88, the first three channels are assigned to calorimeter for higher heating value, calorimeter for specific gravity and total sulfur analyzer. The fourth channel is typically a spare, but in the case of Uni-RE- 30-LG-301, 56-LG-1,2 58-LG-1, the fourth channel is assigned to a Pre-SCR NOx analyzer (INDUSTRYINTERNATIONALINC.'s use). In Uni-RE- 41-MG- 1 and 6 1-MG1,this channel is assignedto a SOXanalyzer. Channels 

### 5 through 8 are typically assigned to the field devices, and these 

### A1 .channel designations varies with each CEMS system. 

### In Uni-RE- 41-MG-1 and 6 1 -MG-1 

### ,channel 7 is assigned to the Stack Flow analyzer. 9.1.4 Raymond 45-OFE Analog Output Modules The analog output channels are configured for 4-20mA. These channels provide the strip chart recorder with corrected analyzer data. These corrected data are derived from the raw analog input signals automatically corrected based on the correction factor calculated after an automatic calibration. These corrected values are stored in the PLC data files, and sent out to the strip recorder via the analog output card and Data Acquisition System via the Infoconcentrator. The first three A0channels typically registers NOx, CO and O2 corrected data, except in Uni-RE- 41-MG-1 and 88. In Unit 41-MG-1, channel 2 output the corrected SOX(Lo) concentration value. In Unit 88, the first three channels are assigned to calorimeter for higher heating value, calorimeter for specific gravity and total sulfur analyzer. The fourth A0channel is typically a spare, but in the case of Unit 30-LG-301 and 56-LG-1,2, the fourth channel output the corrected Pre-SCR NOx concentration value (INDUSTRY INTERNATIONAL INC.'s use). In Unit 41-MG-1 and 61

### - MG-1

### ,this channel is assigned to the corrected SOX concentration value.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality AssuranceIQuality Control Plan SectionNo. 9 Date: 01 -Dec-98 Page No.: 29 of67 Revision No. 0 Revision Date: 0 1-Dec-98 9.1.5 Raymond 45-IBDDigital Input Modules 

### Each CEMS PLC system is provided with one 16-channel digital input card. This DI card utilizes several status input for CEMS and shelter system alarm status. TheDI channel designations in each CEMS system varies, but have typical digital input descriptions as listed below. In Maintenance Alarm CEMS Pump Failure Alarm Pre-SCR Pump Failure Alarm (For INDUSTRY INTERNATIONAL INC.'s Use only) CEMS Chiller Failure Alarm (moisture) Pre-SCR Chiller Failure Alarm (moisture) (For INDUSTRY INTERNATIONALINC.'s Use only) Pre-SCR Probe HighiLow Temperature Alarm (For INDUSTRY INTERNATIONALINC.'s Use only) CEMS ProbeHigh/Low Temperature Alarm Pre-SCR Sample Line Low Temperature Alarm (For INDUSTRY INTERNATIONALINC.'s Use only) CEMS Sample Line Low Temperature Alarm CEMS Shelter Power Failure Alarm CEMS Shelter Pressure Purge Failure Alarm CEMS Shelter Temperature Control Alarm H2S High Alarm H2S High-High Alarm H2S Reset Button to reset H2S alarm horn Low Instrument Air / 

### Low Calibration Gas Alarm

9.1.6 Raymond 45-0 

### W16 Digital Output Modules 

### Each CEMS PLC system is provided with two to three 16-channel digital output cards. These DO card utilizes several status output for alarm status annunciator panel indication, calibration and blowback system control. The DO channel designations in each CEMS system varies, but have typical digital output descriptions as listed below. The Digital Output Module#I operates all solenoid valves. DO #1 

### - 0, 

### Analyzer Solenoid DO #2 

### - CO Analyzer Solenoid Valve DO #3 

### - NOx Analyzer Solenoid Valve DO#4 

### - Spare DO#5 

### - SpareINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA

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### DO#6 

## - Spare DO #7 

## - LocalIRemote SolenoidValve DO #8 

### - O,/CO Span Calibration Gas Solenoid Valve DO #9 

### - NOx Calibration Gas Solenoid Valve DO#10 

## - Spare DO #11 

## - Zero Calibration Gas Solenoid Valve DO #12 

## - Spare DO # 

### 13 

## - Bubbler SolenoidValve DO #14 

### - Probe Blowback~Calibration Solenoid Valve DO #15 

### - Probe Blowback SolenoidValve DO #16 

## - Sample Pump Shutdown Solenoid Valve The Digital Output Module #2 transmi-RE- the CEMS and shelter system alarms to the H,S alarm devices and annunciator panel. DO #1 

## - H,S Alarm Horn DO #2 

### - H,S Alarm Beacon DO #3 

## - "Maintenance Mode Selected" alarm light DO#4 

### - "Automatic Calibrationin Progress" alarm light DO #5 

### - "Manual Calibrationin Progress" alarm light DO #6 

### - "Low Air Supply Pressure" alarm light DO #7 

## - "Calibration Gas PressureLow" alarm light DO #8

. 

### - "Sample Pump Failure" alarm light DO #9 

### - "Sample Chiller Malfunction" alarm light DO #10 

## - "Sample Line TemperatureLow" alarm light DO #11 

### - "Probe TemperatureLow" alarm light DO #12 

### - Spare DO#13 

## - Spare DO #14 

### - "Shelter Power Supply Failure" alarm light DO #15 

### - "Shelter Purge Failure" alarm light DO #16 

### - "Shelter TemperatureControl Failure" alarm light The Digital Output Module #3 transmit the calibration failure alarms to the annunciator panel. DO # 

### 1 

### - "H,S High" alarm light DO #2 

### - Spare DO#3 

### - "0,

### Analyzer CalibrationFailure" alarm light DO#4 

### - "CO Analyzer CalibrationFailure" alarm light DO#5 

### - "NOx Analyzer Calibration Failure" alarm light DO#6 

### - Spare DO #7 

### - Spare DO #8 

### - "0,

### Analyzer Out-of-Control" alarm light DO #9 

### - "NO, Analyzer Out-of-Control" alarm light DO#10 

### - Spare DO #11 

## - SpareINDUSTRY 

### INTERNATIONALINC. 

### LOS ANGELES, CA ContinuousEmissions Monitoring System QualityAssurance/QualityControl Plan SectionNo. 9 Date: 0 1 -Dec-98 Page No.: 31 of66 Revision No. 0 Revision Date: 01-Dec-98 

### DO#12 

### - Spare DO #13 

### - "NOx Analyzer Out-of-Range" alarm light

. 

### DO#14 

## - Spare

DO #15 

## - "PLC Trouble" alarm

### light DO #16 

### - Spare 9.1.7 InfoConcentratorPLC 

### The InfoConcentrator is an Raymond PLC 5/40 which utilizes ICOM PLC5 Ladder Logistics software to 

### run the InfoConcentrator PLC program. The InfoConcentrator serves as a "mail box" for all the CEMS PLC within the data highway network. The InfoConcentrator is responsible for reading and storing all CEMS system status, calibration data, 1-minute rolling and 15-minute block averages from each of the CEMS PLC's. It will also pick appropriate data from each CEMS and move them into a contiguous file allowing specific data to the accessedby the PLC Gateway, which interfacesbetween the PLC network and the DCNXRTU network. 9.1.8 DCNX System 

### The DCrVX system accesses the InfoConcentrator for each of the CEMS PLC data file through the PLC Gateway. The PLC data file contains information such as system status, calibration data; 1-minute rolling averages and 15-minute averages. The DCNXperforms the following functions:

a. Reads the system status from each CEMS, and determines if the last 15- minute data is valid. This will include monitoring the communications to each CEMS PLC to ensure that the data is being updated. b. Calculates the corrected fuel gas flowrate to the heater based on the differential pressure, pressure, temperature and specific gravity.

c. Calculates the stack flowrate from the corrected fuel gas flowrate, the gas Btu and Fd factor. d. Calculates the SO, emissions from the fuel gas sulfur content and the fuel gas flowrate. e. Calculates the following for every 15-minuteperiod: 1) average stack volumetric flowrate on a dry basis 2) average fuel gas flowrate in scfhINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA 

# - Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan SectionNo. 9 Date: 01-Dec-98 Page No.: 32 of 67 Revision No. 0 Revision Date: 0 1 -Dec-98
3) average NO, emissions rate from the calculated stack flow and NOx analyzer readings 4) average calculated SO, emissions rate from the total sulfur analyzer reading and fuel gas flowrate f. Calculates the following for each hour based on the valid 15-minute data 

# . readings and calculations: 1) hourly average NO, ppm 

### dry readings 2) hourly average O2percentage 3) hourly average stack flowrate 4) hourly average fuel gas flowrate 5) hourly average SO, emissions based on total sulfur and fuel gas flow rate 6) hourly average NO, emissions
g. Calculates the following each day: 1) total mass emissions of SO, from the sum of all valid hourly readings plus the sum of all substituted hourly readings. 2) total mass emissions of NOx from the sum of all valid hourly readings plus the sum of all substituted hourly readings. 3) substitutes data based on Rule 201 1 for SO, and Rule 2012 for NO,. h. Each hour determines if the data for the hour is valid. This will normally require four 15-minute average data point, although an hour may be considered valid, per Rules 201 1 and 2012, during periods of calibrationlmaintenance i. Calculates, on a daily basis, the rolling percentage of the operating hours of the equipment that each NO,, SO, and stack flowrate measurement was available for the previous 365 days. j. Records, on a daily basis, the percent annual NO, monitor availability, SO, and stack flowmeter availability fiom the valid hours as a percentage of stack operating hours over the previous 365 days. k. For each hour, when valid data is not available, substitutes data based on the historical percentage availability and the appropriate historicallfuture data as detailed in the applicable rule. 1. Records the actual Fd factor for the Facilityfuel gas used in the calculations.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA

-* Continuous Emissions Monitoring System Quality AssuranceIQuality Control Plan Section No. 9 Date: 01-Dec-98 Page No.: 33 of 67 Revision No. 0 Revision Date: 01-Dec-98

m. Transmit total NOx and SOx emissions and CEMS status codes to SCAQMD dailyper Rules 201 1 and 201 2. 

### Calculations Performed in the PLC Control System (CEMS PLC) Two specific calculations are performed within the CEMS PLC system. These calculations are performed once at the end of each automatic calibration. The resul-REare stored m the CEMS PLC storage data file and read by the Infoconcentrator for DCNX system access. The calculations are listedbelow. 

### 9.2.1 Zero and Span Calibration Error Calculation The following formula is used to determine the zero calibration error and span calibration error for each analyzer.

Where:CE = Percentage calibration error R = Expected value of zero or span calibration gas introduced into the monitoring system A = Actual zero or span calibration gas reading during calibration S = Spanrange ofthe analyzer 

### 9.2.2 Automatic Correction Calculation The automatic correction calculation is only applied whenever the calibration error exceeds the calibration limit outlined in paragraph 7.2 of this QAIQC document. The following formulas are used to determine the corrected analyzer input, and the corrected 1 -minute and 15-minute averagevalues for each analyzer. Zero Drift Factor = Zdf = Az 

### - 

### Rz Correction Factor = Cf = Rs (AS- Zdf) Corrected Value = [Uncorrectedvalue 

### - Zdfl x Cf Where:Az = Actual zero reading duringcalibration 

### Rz = Expected value of zero calibration gasINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA 

### --.. ContinuousEmissions Monitoring System Quality Assurance/Quality Control Plan SectionNo. 9 Date: 0 1-Dec-98 PageNo.: 34 of 67 Revision No. 0 Revision Date: 0 1-Dec-98

As = Actual span reading during calibration 

### Rs = Calibrationgas span 

### 9.3 Calculations Performed in the DCNX 9.3.1 Determination ofEmission Rate 9.3.1.1 Calculates the mass emissions of SO, using fuel gas flow rate and sulfur content Assumption: 15-minutecalculation will be summed for hourly reading. Equation: e =s x q x 1.662 x 1 

## o-~ Where:e = emissions of sulfur oxide in lbh s = sulfur content of fuel gas in ppmv q = fuel gas flow rate in dscfh 

### 9.3.1.2 Calculates the mass emissions of NO, using heat input rate and oxygen concentration Assumptions: a. 15-minutecalculationwill be summed for hourly reading. b. No enriched oxygen is used c. No non-fuel sources of C02are present d. Oxygen content of the stack gas is less than 19percent. e. One type offuel is used f. Fd is a constant Equation: e =a x [20.9/(20.9

### - b)] 

### x 1.195x 10-7 x [Fd x q 

### x V] Where:e = emissionsofnitrogen oxides in lbh a = stack gas concentration of nitrogen oxides on a dry basis inppmv b = stack gas concentrations of oxygen on a dry basis in percent q = fuel flow rate, see calculation (e) below V = higher heating value of the fuel Fd = 

### dry F factor for type of fuel, the ratio of the 

### dry gas volume ofthe product of combustionto the heat content of the fuel in dscf per 

### MMBTUINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System 

## i " QualityAssurance/Quality Control Plan SectionNo. 9 Date: 01-Dec-98 Page No.: 35 of 66 Revision No. 0 Revision Date: 01-Dec-98 

### 9.3.2 

### Determination ofFuel Gas Flow Rate
9.3.2.1 The equation for calculationofthe uncorrected volumetricflow rate at the orifice sizing conditions is 

### as follows: 

### Q,, (uncorrected)=

### K, where, 

### Q,,. (uncorrected) = Volumetric flowrate in standard cubic feet per hour atthe orifice sizing base conditions.


### - KF - A constant representing a flow meter factor derived at the orifice sizingbase conditions.


### - hw - The differentialpressure measured in inches ofwater column acrossthe orifice plate. 

### 9.3.2.2The equation for calculation ofthe volumetric flowrate, corrected to flowing conditions,is as follows:

h 

# a, (corrected)=

# [dpm] P, 

## + 14.7 

### T, 

### +460 

### *

# esClh (uncorrected)

where, 

### QscF (corrected) = Volumetric flow rate in standard cubic feetper hour corrected to flowing conditions. 

### QscF (uncorrected) = Volumetric flowrate in standard cubic feetper hour at the orifice sizing base conditions. 

### pf = Pressurein pounds per square inch gauge at flowing conditions. 

### Pb 

## + 14.7 = 

### Pa = Pressure in pounds per square inch absolute used for orifice sizing calculations. 

### pb - - Pressure in pounds per square inch gauge used for orifice sizing calculations. 

### Tf - - Temperaturein degrees Fahrenheit at flowing conditions.INDUSTRY INTERNATIONALINC. LOS ANGELES, CA ContinuousEmissions Monitoring System QualityAssurance/QualityControl Plan Section No. 9 Date: 01-Dec-98 PageNo.: 36 of 66 RevisionNo. 0 Revision Date: 01 -Dec-98

Tb - - Temperaturein degreesFahrenheit used for orifice sizing calculation. 

### Gf - 

### - Specific gravity measured at flowing conditions. 

### Gb - - Specificgravity used for orifice sizing calculation.



### 9.4 MissingData Procedures For each equipment, whenever a valid hour of NOx and/or SO, pollution concentration data has not been obtained or recorded, the 

### DCNX system shall substitute data using the following procedure. 1. Calculate, on a daily basis, the percent data availability from the NOx and/or SOx pollutant concentration monitoring analyzers or the fuel gas sulfur content monitoring analyzer according to the procedure below.

a. Calculate, on a daily basis, a rolling percentage of the operating hours of each equipment that each concentration monitoring system was available for the previous 90 days. b. - Calculate and record, on a daily basis, the percent annual concentration monitor availability by taking the total operating hours for which the monitor provided quality-assured data during the previous 365 days and dividing this by the total operating hours of the equipment during the previous 365 days, then multiplyingthe result by 100. 2. Whenever the data from the pollutant concentration monitor has been available and recorded for 95 percent or more ofthe total operating hours of the equipment during the previous 365 days, calculate the substitute data for each hour according to the following procedures.

a. For a missing data period less 

### than or equal to 24 hours, substitute data shall be calculated using the 1NProcedure in Attachment A of Rules 201 1 and 2012. b. For a missing data period greater than 24 hours, substitute data shall be calculated using the maximum hourly concentration recorded by the concentration monitor for the previous 30 days. 3. Whenever data from the coneentration monitor has been available for 90 days or more but less than 95 percent of the total operating hours or the equipmentINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System /

&'- Quality Assurance/Quality Control Plan SectionNo. 9 Date: 0 1-Dec-98 Page No.: 37 of66 Revision No. 0 Revision Date: 0 1-Dec-98 during the previous 

### 365 days, calculate the substitute data for each hour according to the followingprocedures.

a. For a missing data period less than or equal to 

### 3 hours, substitute data shall be calculated using the average of the recorded concentration for the hour immediately before the missing data period and the hour immediately after the missing data period. b For a missing data period more 

### than 3 hours but less than or equal to 24 hours, substitute data shall be calculated using the maximum hourly concentration recorded by the concentration monitor for the previous 

### 30 days to the missing data period.

c. For a missing data period greater than 24 hours, substitute data shall be calculated using the maximum hourly concentration recorded by the concentration monitor for the 

### 365 days previous to the missing data period. d. Whenever the data from the concentration monitor has been available for less than 

### 90 percent of the total operating hours of the equipment during the previous 

### 365 days, substitute data shall be calculated using the highest hourly concentrationrecorded duringthe service of the monitoring system.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ' Continuous Emissions Monitoring System

. Quality AssurancefQuality Control Plan Section No. 10 Date: 0 1 -Dec-98 PageNo.: 38of 66 Revision No. 0 Revision Date: 01 -Dec-98

10.0 

### OUALITYASSURANCE 

## - The purpose of quality assurance is to ensure that only the most accurate data is ultimately reported to the agency, and that the highest degree of equipment operation is maintained. 10.1 Data Validation Criteria Data must be considered invalid if any of the following occur:

a. Any part of the monitoring system fails, which affec-RE- the data being collected. b. If the calibration error for the O2 analyzer exceeds the "Out of Control" limit of 1%O2at either the zero or span calibrations.

c. If the calibration error for the NOx analyzer exceeds the "Out of Control" limit of 5% ofNOx span range at eitherthe zero or span calibration. d. If the calibration error for the SO, analyzer exceeds the "Out of Control"

. limit of 5% of SO, span range at both the zero and span calibration.

e. Ifthe NOx raw input value for theNOx analyzer does not fall within the 

### 0- 95% oftheNOx span, indicating an "Out ofRange" condition. f. For the SO, or total sulfur analyzer, the same "Out of Range" limi-RE- in criteria (e) above apply., g. If the calibration error of a stack flow monitor exceeds 

### 6% of the span range. h. If the monitored process is shut down and no emissions or pollution is being emitted.

1. The out of control period begins with the hour of completion of the failed test and ends with the hour of completion of a satisfactory test. 10.2 Data Reduction Criteria

a. All averagesmust be calculatedusing valid data only.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System 

### i. Quality Assurance/Quality Control Plan SectionNo. 10 Date: 01-Dec-98 Page No.: 39 of 66 RevisionNo. 0 Revision Date: 01-Dec-98 b. All valid 1-minute average readings within 

### a 15-minute period will be averaged to produce a valid 15-minuteaverage.

c. 

### An hourly average will be considered valid if it contains either all four 15- minute averages, or under certain conditions, at least two valid 15-minute averages.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System Quality Assurance/QualityControl Plan SectionNo. 11 Date: 0 1 -Dec-98 Page No.: 40 of66 Revision No. 0 Revision Date: 01-Dec-98



### 11.0 SCHEDULEOF ACTIVITIES 

## - 11.1 Frequency of System Calibration The frequency at which the system calibrationmust be performed is asfollows: 

### 11.1.1 Daily Calibrations Perform a calibration to test, record and compute the calibration error of each SO,, NOx and O2 analyzer at least once each day approximately 24-hours apart for determining the SO,, NOx and O2 analyzers zero and span drif-RE-. The calibration error calculations are based on the analyzer parameters summarized below. 

### 11.1.1.1 0,

### Analyzers A. The zero gas shall be N2gas at zero percent concentration. 

### B. The span gas shall be O,/CO gas mixture with .concentrationbased onthe analyzer range. C. The O2analyzer ranges are 0-10% and 0-25%. 

### 11.1.1.2 NOxAnalyzers

a. The zero gas shall be N2gas at zero percent concentration. b. The NO, span gas concentration shall be based on the analyzer range. c. TheNOx analyzerranges are 0-25ppm, 0-SOppm, 0-100ppm and 0- 250ppm. 

### 11.1.1.3 SO, 

### Analyzer

a. The zero gas shall be N2gas at zero percent concentration. b. The SO, span gas concentration shall be based on the analyzer range. c. The SO, analyzer ranges are 0-SOppm, 0-250ppm and 0-5OOppm. 

### 11.1.1.4 Total Sulfur Analyzer

a. The zero gas shall be N2gas at zero percent concentration. b. The sulk span gas concentration shall be based on the analyzer range.INDUSTRY LNTERNATIONAL INC. LOS ANGELES, CA 

# -- ContinuousEmissions Monitoring System Quality AssuranceIQuality Control Plan Section No. 11 Date: 0 1 -Dec-98 Page No.: 4 1of 67 ~evision'~~. 0 Revision Date: 01-Dec-98

c. The total sulkanalyzerrange is 0-200ppm.

11.2 Frequency 

### ofPreventive Maintenance Preventive maintenance procedures, as outlined 

### in Section 

### 8.0 of this QAIQC, shall be implemented daily, bi-weekly and monthly. This will assure minimum downtime and accurate data recovery for the CEMS system. 11.3 Schedule

### ofSystem Audi-RE11.3.1 Relative Accuracy Test Audit Relative accuracy test audit and bias test shall be performed semi-annually and no less than 4-months apart for each CEMS system, in accordance with the Chapter 2, Subdivision 

### B Paragraphs 10, 11, and 12, and Attachment 

### B of RECLAIM Protocol for Rules 201 1and 2012. Relative accuracy tes-RE- may be performed on an annual basis rather than on a semi-annual basis if the relative accuracy during the previous audit for the monitoring system and the emission rate measurement system is 

### 7.5 percent or less.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA

, r.. Continuous Emissions Monitoring System Quality AssuranceIQuality Control Plan Section No. 12 Date: 01-Dec-98 Page No.: 42 of 67 Revision No. 0 Revision Date: 01-Dec-98

12.0 SYSTEMAUDIT PROCEDURES 

# - System audi-RE- are necessary to 'provide an assessment of the accuracy of the data generatedby the CEMS. The following audit procedureswill be implemented. 12.1 Relative Accuracy Test Audit 

### Test the relative accuracy test data set and the relative accuracy test audit data se-RE- for NOx pollutant concentration monitors, NOx emission rate measurement system, SO, pollutant concentration monitors, fuel gas sulh content monitor, SO, emission rate measurement system and stack gas volumetric flow measurement system, using the procedures outlined below.

12.1.1 Relative Accuracy Test Requirement for Emission Measurement 

### The emission measurement shall meet a relative accuracy requirement of being less than.or equal to 20 percent of the mean value of the reference method test data in unit of lblhr. Relative accuracy is calculatedby the equations in Section 8 of 40 CFR, Part 60, Appendix B, Performance Specification 2. The emissions rate measurement shall also meet the specifications in RECLAIM Protocol SCAQMD rules 201 1 and 2012, Appendix A, Attachment B (Bias Test).

12.1.2 Relative Accuracy Test Requirement for Stack Gas Volumetric Flow Measurement System 

### The stack gas volumetric flow measurement system shall meet a relative accuracy requirement of being less than or equal to 10 percent of the mean value of the reference method test data in unit of DSCFH. Relative accuracy is calculated by the equations in Section 8 of 40 CFR 60, Appendix B, Performance Specification 2. The stack gas volumetric flow measurement system shall also meet the specifications in RECLAIM Protocol SCAQMD rules 201 1 and 2012, Appendix A, Attachment B (Bias Test). 12.1.3 Bias Test 

### The Bias Test compares the CEM test data 

### se-RE- and the Source Tester's test audit data se-RE-. These are checked for NOx and SO, pollutant concentration monitors; fuel gas sulfur content monitors; stack flow monitors and emissions rateINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA *._ Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. 12 Date: 01 -Dec-98 Page No.: 43 of 67 RevisionNo. 0 Revision Date: 01-Dec-98 measurement systems using the procedures outlined in RECLAIM Protocol SCAQMD rules 201 1 and 2012, Appendix A, Attachment B (Bias Test). 12.2 Cylinder Gas Audit All calibration gases used during certification test- and quality assurance and quality control activities shall be certified according to 40 CFR 60, Appendix 

### F, Section 

### 5.1-2. Prior to connecting the cylinder gases to the CEMS system, record the cylinder gas manufacturer, serial number, expiration date and gas concentration. This information and certificationdocument for the cylinder gas shallbe kept. Expiration dates on the cylinder gas must be checked. Expired cylinder gases must not be used for certificationtest or any quality assurance and quality control activities. 12.3 Record Keeping Copies of written report received from testing firms and laboratories of procedures and details specific to the installed CEMS that were to be used by the testing firms and laboratories for relative accuracy test audit, such as sampling and analysis methods, shall be kept.INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System Quality Assurance/Quality Control Plan Section No. App. A Date: 01-Dec-98 Page No.: 44 of 66 Revision No. 0 Revision Date: 01-Dec-98



# APPENDIX A SYSTEM CONFIGURATIONINDUSTRY INTERNATIONALINC. LOS ANGELES, CA ContinuousEmissions MonitoringSystem QualityAssurance/QualityControlPlan Section No. App. A Date: 0 1 -Dec-98 Page No.: 45 of 66 Revision No. 0 Revision Date: 0 1 -Dec-98 TABLE A CEMS UNIT SPECIFICATIONS INDUSTRY INTERNATIONALINC. LOS ANGELES FACILITY
SourceID

ST1

11

-LG- 1000

20-LG-200

30-LG-341 Parameter

02 CO NOx 

### so2 0, CO NOx 

### so2 O2 CO NO, SOz O2 CO NO, SO, 0, CO NOx 

### so2 0, (wet) NOx 02 (dry) SO, (LOW) SO2 (HIGHJ Stack Flow 0, CO NOx 

### so2

02 CO NO, 

### so2 

# - 31 -LG-3000

41-MG-02

56-LG-1,2

58-LG- 1 Manufacturer Raymond Raymond Raymond Calculated Raymond Raymond Raymond Calculated Raymond Raymond Raymond Calculated Raymond 4R Raymond Calculated Raymond Raymond Raymond Calculated 4R Raymond Raymond Raymond RachFlo Raymond Raymond Raymond Calculated Raymond Raymond Raymond Calculated Model Number 70R 88OA 121B

70R 88OA 121B

70R 880A 121B

70R 3300A 121B

70R 88OA 121B

WDG IV 121B 70R 890 890 Mass II 70R 880A 951A

70R 88OA 951A Method Paramagnetic NDIR Chemiluminescence Paramagnetic NDIR Chemiluminescence Paramagnetic NDIR Chemiluminescence Paramagnetic NDlR Chemiluminescence Paramagnetic NDIR Chemiluminescence

Zirconiumoxide Chemiluminescence Paramagnetic UV Fluorescence UV Fluorescence Differentialpressure Paramagnetic NDlR Chemiluminescence Paramagnetic NDIR Chemiluminescence Span Range

0

### - 10% 0

### - 2000 pprn 0

### - 250ppm

0 - 10% 0

### - 400 ppm 0

### - 50ppm

0

## - 10% 0

### - 400ppm 0

### - 50ppm

' 0-10%

0 - 500ppm 0

## - 100ppm

0- 10% 0

### -400ppm 0 - 50ppm

0

### - 25% 0

## - 100ppm 0

### - 25% 0

### - 500ppm 0-2000ppm 0 -2,223,000 scfh 0- 10% 0

### -400 ppm 0

## - 25 ppm
0- 10% 0

### - 400 ppm 0 - 25 ppm Conc.Range

0.4- 7.9 % 37

### - 1969pprn 0

### - 400 ppm 0 

### - <50ppm 3-5% 0

### - 350ppm 0

### - a5 ppm 0 

### - <50ppm 3-5% 0

### - 350ppm 0-a5ppm

0 - <50ppm 0

### - 3.15% 0

### - 40 ppm O 

### - 40ppm 0

### - <50 ppm 3-5% 0 

### -K350ppm 0

### - a5 ppm 0

### - <50ppm 10

### - 20% 0

## - <50ppm 10

### - 20% 0

### - <70 ppm
0- 1,265,000scfh 3-5% 0

### - 35Oppm 0

### - a5 ppm 0 - <50 PPM 3-5% 0

### - 350ppm 0

### - <25ppm 0

### - <50 PPMINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan SectionNo. App. A Date: 0 1 -Dec-98 Page No.: 46 of 66 Revision No. 0 Revision Date: 0 1 -Dec-98

TABLE A (cont.) CEMSUNIT SPECIFICATIONS INDUSTRY INTERNATIONALINC., INC. LOSANGELES FACILITY

Model Number 

# I1 SourceID Method Span Range Conc.Range

02 (wet)

I CO

NO, 

### so2
02(dry) 

# ' StackFlow

Parameter

4R Raymond Raymond Raymond Raymond RachFlo Manufacturer

WDG IV 880A 951A 890 70R Flowmeter Zirconiumoxide NDIR Cherniluminescence W Fluorescence Paramagnetic DifferentialPressure Zirconiumoxide Cherniluminescence NDIR 0

### - 10% 0

### - 200pprn 0 -100pprn 0 -25Oppm 0- 10% 0 

### - 10mmscfh 0 - 10% 0

### - 50pprn 0 

### - 500pprn .9 - 7.4 % 56.7

### - 119.4pprn 1.4

### - 10pprn 36.2

### - 121.0ppm 7-9% 0

### - 200,000 scfh 0

### - 5.5% 0 

### - 40.6pprn 0

## - 350pprn 0

### - 14.2pprn 0.8 

### - lj:5% 0

## - 930pprn 40to 105pprn 0

### - <SO pprn 4R Raymond 4R Calculated 

# JI I I 704~3-1 7 n 

## 1 Raymond (* Paramagnetic NDIR Chemiluminescence 0 - 10% 0 

### - 1000pprn 0

### - 250pprn Raymond Raymond Raymond Calculated ' ',-,-

3.2 - 22.8% 3

### - 56pprn 1- 79pprn 0

### - <SO pprn -2 CO

. NO, 

### so2 Paramagnetic NDIR Cherniluminescence

- - -

Raymond Raymond Raymond Calculated Raymond Raymond Calculated 0

### - 25% 0 

### - 1000ppm 0 

### - 100pprn

1.6 - 20% 7

## -49pprn 0

### - <I50pprn 0 -<50ppm Paramagnetic NDIR Chemiluminescence Paramagnetic 0- 10% 0- 10% 0 

### - 1000ppm 0

### - 250pprn

- - -

Raymond Raymond Raymond Calculated SulfurAlert RachFlo 5000 0 -2OOppm 900

### - 1400 btu/scf 0.6

### - 1.0 spec. 88 SS. Total Sulfur HeatValue/ Spec. Gravity 4R RachFloINDUSTRY INTERNATIONAL INC. Section No. App. B LOS ANGELES, CA Date: 01-Dec-98 ContinuousEmissions Monitoring System Page No.: 47 of66 ( F-. Quality AssuranceIQuality Control Plan RevisionNo. 0 Revision Date: 01-Dec-98



# APPENDIX 

# B

DAILY AND WEEKLY OPERATIONAL CHECK FORMINDUSTRY INTERNATIONAL INC. LOSANGELES, CA 

# - Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan SectionNo. App. B Date: 01 -Dec-99 Page No.: 49 of 67 Revision No. 0 Revision Date: 01-Dec-99

INDUSTRY INTERNATIONALINC. Daily CEMS System VerificationForm 

## FORM 

# 0 Verifyand completethe correspondingcolumn for each day on all of items listed below.

Date

Verified 

### By 

### B 1.
2.

3.

4.

5. StepProcedure at Recorders Examine strip chart recorder operation - printing legibly and operating normally. Check if ink and paper are sufficientto operate for the next 24 hours. Review the last automatic calibration data. Log actual readings of zero and span, and calculatethe zero and span calibration error (drift). Compare the calculated calibration error (drift) to the "Out ofRange" and "Out of Control" limit. Ifthe calibration error exceedsthe limit, report to the supervisor; take corrective action and log problem; corrective action taken, and period of invalid data. 

### M T W 

### Th 

### F S SuINDUSTRY LNTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System Quality Assurance/Quality~Control Plan Section No. App. B Date: 01-Dee99 Page No.: 49 of 66 RevisionNo. 0 Revision Date: 01-Dec-99

INDUSTRY INTERNATIONALINC. 

### Daily CEMS System VerificationForm 

## FORM Q Verify and complete the corresponding column for each day on all ofitems listed below.



### Date

Verified 

### By 

### B 1.
2.

3.

4.

5. 

### StepProcedure at Recorders Examine strip chart recorder operation

## - printing legibly and operating normally. Check if ink and paper are sufficientto operate forthe next 24 hours. Review the last automatic calibration data. Log actualreadings ofzero and span, and calculatethe zero and span calibration error (drift). Comparethe calculated calibration error (drift) tcthe "Out of Range" and "Out of Control" limi-RE-. If the calibration error exceedsthe limit,report to the supervisor; take corrective action and logproblem; corrective action taken, andperiod of invalid daca. 

### M 

### T W



## I Th F S SuINDUSTRY INTERNATIONALINC. LOS ANGELES, CA ContinuousEmissions Monitoring System

h QualityAssuranceIQuality Control Plan SectionNo. App. C Date: 01 -Dec-98 Page No.: 50 of 66 Revision No. 0 Revision Date: 01 -Dec-98



# APPENDIX 

# C

ROUTINE MAINTENANCE OPERATIONSINDUSTRY INTERNATIONALINC. LOS ANGELES, CA
,+,- Continuous Emissions Monitoring System Quality AssuranceIQuality Control Plan Section No. App. C Date: 01 -Dec-98 Page No.: 51 of 67 Revision No. 0 Revision Date: 01-Dec-98

Trends are taken each morning and the CEMS calibration display for all CEMS is printed. Those CEMS that failed deviation specification are looked at first by the Analyzer Technicians assigned to that specific CEMS system. Those CEMS that passed the morning calibration are inspected visually and any problem that is noticeable is,corrected. Scheduled monthly and quarterly preventative maintenance (PM) is done according to scheduled planning. Mandatory PM's are done on a regular basis using INDUSTRY INTERNATIONAL INC.'s Preventative Maintenance work orders. Calibration per manufacturers specifications is a requirement on all mandatory PM's. All trends are to be taken within half hour of start of shift.

,d-- All analyzersthat are manually calibrated will have 

### an automatic calibration done to update the report This will be followed by the latest calibration report. Report required: 1. Calibration Report 1 

### 2. Calibration Report 

### 2 3. Calibration Report 

### 3INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. App. C Date: 0 1 -Dec-98 PageNo.: 52 of66 RevisionNo. 0 Revision Date: 01-Dec-98



## P.M. REPORT Date: 

### 1 2 3 

### 4 5 6 7 8 9 10 1I 

### 12 13 14 15 16 1 0-LG- 1 00 1 1 -LG- 1000 20-LG-200 30-LG-301 3 1 -LG-3000 4 1 -MG-01 56-LG-1,2

58-LG-1 61-ST-1 58-LG-1 70-LG-1,2,3

80-LG- 1 80-LG-2 86-RY-900 1 Calorimeter 

### 88-WW-001 CEM CEM CEM CEM CEM CEM CEM CEM CEM CEM CEM CEM CEM CEM 

### BTU Analyzer

Total SulfurINDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan SectionNo. App. D Date: 01-Dec-98 Page No.: 53 of67 RevisionNo. 0 RevisionDate:01-Dec-98



# APPENDIX D

RECOMMENDED SPARE PARTS INVENTORY-a INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan SectionNo. App. D Date: 01-Dec-98 Page No.: 54 of 67 Revision No. 0 Revision Date: 01-Dec-98



### RECOMMENDED SPARE PARTS LIST

RAYMOND MODEL 755 PARAMAGNETIC OXYGEN 0, 

### (DRY) ANALYZER 

### - PART NO. DESCRIPTION QTY RE-861652 Heater



### . 1 RE-809374 Fuse, 3A, 120VAC,F4 1 (Pkg. of 15) RE-861 649 Fuse, Thermal, F-2, F-3 

### 2 RAYMOND MODEL 121B 

### CHEMILUMINESCENCE 

# - NOINOXANALYZER 

### - PART NO. DESCRIPTION OTY RE-632782 Temperature Sensor

. 

### I Replacement Pens A128969 Replacement Pen Cartridge (For 4-6 Pen Model Only) A243 77 1 Blue Replacement Pens A243772 Red Replacement Pens A243773 Green Replacement Pens A243770 Annotation (For 1-3 Pen Model Only) Replacement Chart Paper Specify Roll or Z-Fold RE-632784 Silicone Rubber Connector RE-617124 Heater-Boot Assembly

## - - INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring System Quality AssuranceIQuality Control Plan Section No. App. D Date: 01-Dec-98 Page No.: 57 of 67 Revision No. 0 Revision Date: 01-Dec-98 

### RECOMMENDEDSPARE PARTS LIST

RACH SERIES2000 

### OXYGEN

### 0, - 

### (WET) ANALYZER

PART NO. DESCRIPTION Sensor: P/N 70409SE FurnaceAssembly P/N 7 1 697KE Type 

### "KThermocouple P/N 80418SE Sensor Board P/N 71063SE Zirconium Oxide Cell P/N 71807KE Thermostat (Lift-off Enclosure) P/N 72589KE Thermostat (Hinged Enclosure) Remote Calibration Unit (RCU): P/N 39003 JE Air Regulator P/N 37013JE Regulator Gauge P/N 36022 JE Aspirator Air SolenoidValve P/N 36023 JE Calibration Gas Solenoid Valve P/N 37030JE Flow Meter Control Unit: P/N 902 19VE Display Module P/N 90253VE Power SupplyKeypadModule P/N 80436SE Auto CalibrationCard P/N 80439SE BackplaneAssembly P/N 80457SE Wiring Card P/N 80440SE ProcessorBoard P/N 42373JE Display

### -. INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring'System Quality Assurance/Quality Control Plan Section No. App. D Date: 01 -Dec-98 Page No.: 58 of 67 Revision No. 0 Revision Date: 01-Dec-98 

### RECOMMENDED SPARE PARTS LIST

RACHFLO SERIES3000 

### STACK FLOW ANALYZER

PART NO. DESCRIPTION QTY Auto-Purge Panel, High Capacity (SST): 205- 160-00 Fuse, 2-Amp SAG



### . 2 205-9 15-00 SolenoidN.C. 2-Way



### . 1 205-920-00 Solenoid N.O. 2-Way



### . 1 865-300-00 Valve, with Mtg. Plates 

# - 1 865-275-00 Valve, 3-Way BallPhact



### . 1 265- 120-00 Filter with Housing



### . 1 265-130-00 Pressure Regulator, 0- 150 psi



### . 1 205-005-00 Relay, PET 1481



### . I 

### 865-1 75-00 Valve, 2-Way Ball



### . 1 

### Flow with Cal: 205-1 60-00 Fuse, 1 -Amp

. 

### 2INDUSTRY INTERNATIONAL INC. SectionNo. App. D LOS ANGELES, CA Date: 01-Dec-98 Continuous Emissions Monitoring System PageNo.: 59 of67 Quality Assurance/Quality Control Plan RevisionNo. 0 Revision Date: 0 1 -Dec-98 

### RECOMMENDED SPAREPARTS LIST

4R SCIENTIFIC'S SULFURDETECT MODEL 6200 TOTAL SULFUR ANALYZER

PART NO. DESCRIPTION QTY 1109-01 Spring 

### ,Pressure Block 2 1 136-02 Belt, Take-up Drive 1 1401-03 Flowmeter, Sample

. 

### 1 140 1-04 Flowmeter,Hydrogen



### . 1

P 

### 1501-01 ReactionTube, Ceramic 10 2127-01 Filter Humidifier



### . 1 2128-01 Flowmeter



### . 1 2 1 75-02 Diode, Rectifier 1 2601-01 Motor, Tape Drive



### . 1 2603-01 Thermocouple, Type S 1 8301-01 PressureBlock 1 8302-01 Detector 1~. - INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions ~onitoring's~stern QualityAssurance/QualityControl Plan SectionNo. App. D Date: 01-Dee98 Page No.: 60 of67 RevisionNo. 0 RevisionDate:01-Dec-98 

### RECOMMENDED SPAREPARTS LIST

RACH CAL 50 SERIES CALORIMETER

PART NO. DESCRIPTION 

### QTY Prec. Gas Req. and Solenoid Valve: 03-101 1-OA00 Coil 110V,50160 

### Hz



### . 1 5 1 

### -1002-OA00 Cover 1 52-1000-OA00 Diaphragm



### . 2 61-1001-OA00 DiaphragmDisc

*b* 

### 2

Control Unit: 61

### -1065-OA00 Disc, ISOP 1100 2 63- 1025-OAOO Ring, ISOP 

### 1100



### . 1 49-1001 -0A00 Spring 2 63- 1001 -0A00 0-Ring 1

49- 1002-OA00 Spring 1 

### 64-1003-OA00 Thermal/ExpansionTube



### . 1

.-a- INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions ~onitoring'systern QualityAssuranceIQuality Control Plan Section No. App. D Date: 01-Dec-98 Page No.: 61 of67 Revision No. 0 Revision Date: 01-Dec-98

59- 1003-OA00 

### Rubber Gasket. 1 18-1082-OA00 

### Temperature Indicator. 1 42- 1002-OA00 

### Air Orifice 1.2mm



### . 1 

### RECOMMENDEDSPARE PARTS LIST

RACH CAL 

### 50 SERIES CALORIMETER (Continued)

PART NO. DESCRIPTION OTY Air Control Valve: 

# - 52- 1001 -0A00 

### Diaphragm



### . 1 61-1016-OA00 

### Diaphragm Disc 1 52-1002-OA00 

### Diaphragm

. 1 49- 1004-OA00 

### Spring 1 61-1017-OA00 

### Spring Disc



### . 2

61-1018-OA00 

### Diaphragm Disc 2



### Base Plate Assembly: 03-1004-OA00 

### Spark Ignitor, 120VAC 

### 1 25-1 103-OAOO 

### Pressure Switch 3" W.C. 

### SPDT 2INDUSTRYINTERNATIONAL INC. 

### i *- LOS ANGELES, CA ContinuousEmissions Monitoring System QualityAssurance/QualityControl Plan Section No. App. D Date: 01-Dec-98 Page No.: 62 of 66 Revision No. 0 Revision Date: 01-Dec-98 

### 25-1012-0A00 

### Pressure Switch411.6" 

### W.C. SPDT



### . 1 89-1098-1AO 

### Electrode 1INDUSTRY INTERNATIONALINC. *- f LOS ANGELES, CA Continuous Emissions Monitoring System Quality Assurance/Quality Control Plan Section No. App. D Date: 01 -Dec-98 PageNo.: 63 of 66 Revision No. 0 Revision Date: 01 -De c-98 

### RECOMMENDED SPARE PAR-RE- LIST

RYAN MODEL HR2400 

### STRIP CHART 

### RECORDER (30- PO^



### PART NO. DESCRIPTION QTY P/N 

### B9627AYChart Paper, 

### 25mm per division on the time axis



### . 3 

### P/N 

### B9627AZ Color Ribbon Cassette 10

## -~ INDUSTRY LNTERNATIONAL INC. LOS ANGELES, CA Continuous Emissions Monitoring'System Quality Assurance/Quality Control Plan Section No. App. D Date: 01 -Dec-98 Page No.: 64 of 67 Revision No. 0 Revision Date: 0 1-Dec-98



### RECOMMENDED SPARE PARTS LIST

RAYMOND PROGRAMMABLE CONTROLLERPLC 5/20 DATA ACQUISITION SYSTEM

PART NO. DESCRIPTION QTY PLC 5/20 Programmable Controller



### . 1 (Processor Module) 45-A2B Universal 110 Chassis



### . 1 

### 45-IFE Analog Input Module



### . 1 

# - 45-OFE Analog Output Module 

### 1 45-IBD Series B DC (1 0-30V) Input Module 

### 1 45-OW16 Series B Electromagnetic Relay Contact Output Module 

### 1 2705-ND002 Series A 

### Redipanel Keypad Module

. 

### 1 (Operator Interface) Power Supply



### . . 

## . 1 

### Lithium Battery 

### 1 Cable between Power Supply and 

### Processor



### . 1INDUSTRY INTERNATIONALINC. 

# - LOS ANGELES, CA ContinuousEmissionsMonitoring'System Quality Assurance/Quality Control Plan SectionNo. App. E Date: 01-Dec-98 Page No.:65 of67 RevisionNo. 0 Revision Date: 01-Dec-98



# APPENDIX E

DIAGNOSTIC TESTS

# - INDUSTRY INTERNATIONAL INC. LOS ANGELES, CA ContinuousEmissions Monitoring System Quality AssuranceIQuality Control Plan Section No. App. E Date: 01-Dec-98 PageNo.: 66 of67 Revision No. 0 Revision Date: 0 1-Dec-98



### SampleSystemBias Test The sample system bias test shall be performed on an "as needed" basis to trouble shoot problems with any NOx or SO, analyzers or sample system using the procedure outlined below. 

### 1. Perform "remote" (calibration gases are applied through sample system and probe assembly back to the analyzers) calibration on all analyzersby initiating zero and span calibrations manually. 2. Record the actual zero and span calibration readings for each analyzer resulting from the above remote calibration. 

### 3. Perform a "local" (calibration gases are applied directly to analyzers bypassing the sample system) calibration on each analyzer by initiating the zero and span calibrationmanually. 4. Record the actual calibration reading for each analyzer resulting from the above local calibration. 5. Determine the bias for each analyzer, by calculating the differences between the zero and span concentration values (in ppm) obtained from calibration data recorded in step 2 and step 4 above. 6. The analyzer passes the bias test if the bias is less than

# * 5% of the range for the zero, and high ranges calibration gasses. Ref. SCAQMD Method 

### 100.1.