AECOM 

Appendix C 

Referenc e Metho d Calibrations , Verifications , an d Certification s 

VES018543 
AZCOM 

Calibrator. Mike O'toole Reference Thermometer. SYR-CAL-1 

Filter Box Calibration 

Hot Box #5 HotBox#8D 

Manufacturer: 

Serial No.: 

Date received/placed in servic 

Anderson NUTECH 

N/A 

Pre 1995 

Manufacturer: 

Serial No.: ' 

Date received/placed in servic* 

Anderson NUTECH 

N/A 

Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 8-Jan-09 

Ambient Hot Ambient Hot 

Reference Temperatures 67 250 Reference Temperatures 69 250 

Actual Temperatures 66 249 Actual Temperatures 69 249 

Temp Difference (tol. = +-2) 1 1 Temp Difference (tol. = +-2) 0 1 

Hot Box #6 Hot Box #9 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: N/A Serial No.: N/A 

Date received/placed in servic Pre 1995 Date received/placed in servia Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 8-Jan-09 

Ambient Hot Ambient Hot 

Reference Temperatures 69 250 Reference Temperatures 68 251 

Actual Temperatures 69 250 Actual Temperatures 68 250 

Temp Difference (tol. = +-2) 0 0 Temp Difference (tol. = +-2) 0 1 

Hot Box #7 Hot Box #10 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: N/A ' Serial No.: N/A 

Date received/placed in servic Pre 1995 Date received/placed in servio Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 8-Jan-09 

Ambient Hot Ambient Hot 

Reference Temperatures 68 250 Reference Temperatures 71 250 

Actual Temperatures 69 249 Actual Temperatures 71 250 

Temp Difference (tol. = +-2) -1 1 Temp Difference (tol. = +-2) 0 0 

HotBox#7A Hot Box #11 

Manufacturer. Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: 

Date received/placed in servic 

N/A 

Pre 1995 

Serial No.: 

Date received/placed in servic 

N/A 

Pre 1995 

Calibration Date: 8-Jan-09 Calibration Date: 7-Jan-09 

Ambient Hot Ambient Hot 

Reference Temperatures 69 250 Reference Temperatures 70 251 

Actual Temperatures 69 249 Actual Temperatures 69 250 

Temp Difference (tol. = +-2) 0 1 Temp Difference (tol. = +-2) 1 1 

Hot Box #8 

Manufacturer: 

Serial No.: 

Date received/placed in servic 

Anderson NUTECH 

N/A 

Pre 1995 

Calibration Date: 8-Jan-09 

Ambient Hot 

Reference Temperatures 69 250 

Actual Temperatures 69 248 

Temp Difference (tol. = +-2) 0 2 

Checked amph connector, t-couple and plugs 

QC checked by S Milo 2/9/09 

VES018544 
AZCOM 

Calibrator: 

Date: 

Steven Milo Reference Thremometer ID: CL-1000 

12/16/2008 

Last Impinqer Thermocouple Calibration 2007 

Thermocouple Reference Difference (+/- 2°) Thermocouple , Reference Difference (+/- 2°) 

LI-1 Hot 210 212 -2 Ll-18 Hot 210 212 -2 LI-1 

Cold 32 33 -1 

Ll-18 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No,: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/olaced in service: Pre 1990 

LI-3 Hot 211 213 -2 LI-20 Hot 211 212 -1 LI-3 

Cold 32 32 0 

LI-20 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-4 Hot 212 213 -1 LI-22 Hot 213 212 1 LI-4 

Cold 32 32 0 

LI-22 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/placed in service: Pre 1990 

LI-3 Hot 212 213 -1 LI-22A Hot 210 212 -2 LI-3 

Cold 32 32 0 

LI-22A 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

Hot 0 LI-24 Hot 210 212 -2 

Cold 0 

LI-24 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

Hot 0 LI-25 Hot 212 212 0 

Cold 0 

LI-25 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/olaced in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-13 Hot 210 212 -2 LI-28 Hot 213 212 1 LI-13 

Cold 33 32 1 

LI-28 

Cold 32 32 0 

Manufacturer: Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/olaced in service: Pre 1990 Date received/placed In service: Pre 1990 

LI-15 Hot 210 212 -2 LI-15 

Cold 32 32 0 

Manufacturer: Anderson NUTECH 

Serial No.: 

Date received/placed in service: Pre 1990 

After calibration shower heads were cleaned and leak checked 

QC check S. Milo 

VES018545 
Calibrator: 

Date: 

Bill Hardy 

1/18/2010 

Reference Thremometer ID: CL-1000 

Last Impinger Thermocouple Calibration 2007 

Thermocouple Reference Difference (+/- 2°) Thermocouple Reference _, Difference 2°) 

LI-1 Hot 210 212 -2 LI-20 Hot 211 212 -1 LI-1 

Cold 32 32 0 

LI-20 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/placed in service: Pre 1990 

LI-3 Hot 212 212 0 LI-22 Hot 211 212 -1 LI-3 

Cold 32 32 0 

LI-22 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-4 Hot 210 212 -2 LI-22A Hot 211 212 -1 LI-4 

Cold 32 32 0 

LI-22A 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 T-couple 2006 Date received/placed in service: Pre 1990 

LI-13 Hot 212 212 0 LI-24 Hot 211 212 -1 LI-13 

Cold 33 32 1 

LI-24 

Cold 33 32 1 

Manufacturer: Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-15 Hot 211 212 -1 LI-2S Hot 210 212 -2 LI-15 

Cold 33 32 1 

LI-2S 

Cold 33 32 1 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

LI-18 Hot 210 212 -2 LI-28 Hot 211 212 -1 LI-18 

Cold 33 32 1 

LI-28 

Cold 32 32 0 

Manufacturer: Anderson NUTECH Manufacturer: Anderson NUTECH 

Serial No.: Serial No.: 

Date received/placed in service: Pre 1990 Date received/placed in service: Pre 1990 

After calibration shower heads were cleaned and leak checked 

QC checks. Milo 

VES018546 
AECOM 

M5 Thermocouple Calibrations - 2009 

Date: 12/16/08 

BP: 30.08 

Reference Thermometer ID#: 

Manufacture: 

Date placed in Service: 

Calibrator: Steven Milo 

Ambient Temp (F): 65 

CL-1000 Fluke Digital RTD 2131035 

Fluke 

Pre 1980 

Ice Bath Boiling Water 

Thermocouple 

ID# 

Reference 

Temp 

XAD 

Temp 

Temp 

Difference 

Tol = +-2F 

Reference 

Temp 

XAD 

Temp 

Temp 

Difference 

Tol = +- 2 F 

M5-TC1 212 212 0 32 33 1 

M5-TC2 212 211 -1 32 33 1 

XAD-6 32 32 0 213 212 -1 

XAD-7 32 32 0 213 212 -1 

QC check S. Milo 

VES018547 
AECOM 

M5 Thermocouple Calibrations - 2010 

Date: 1/17/2010 Calibrator: Bill Hardy 

BP: 30.08 Ambient Temp (F): 65 

Reference Thermometer ID#: CL-1000 Fluke Digital RTD 2131035 

Manufacture: Fluke 

Date placed in Service: Pre 1980 

Ice Bath Boiling Water 

Thermocouple 

ID# 

Reference 

Temp 

XAD 

Temp 

Temp 

Difference 

Tol = +-2F 

Reference 

Temp 

XAD 

Temp 

Temp 

Difference 

Tol = +-2 F 

M5-TC1 32 33 1 212 212 0 

M5-TC2 32 33 1 212 211 -1 

XAD-6 32 32 0 213 212 -1 

XAD-7 32 32 0 212 212 0 

QC check S. Milo 

VES018548 
AZCOM 

DRY GAS METER CALIBRATION 

Meter Box No.: 2 

Check one: 

Annual Calibration Recalibration 

Date: 7/10/2009 I 

Operator: S. Milo 

Barometric Pressure: 29.81 (in Ho) 

Theoretical Critical Vacuum: 14.06 (in Hg) 

Manufacturer: Environmental Supply 

Date Received/Placed m service; 2002 

Serial No.: 2 

Pretest Leak Checks 

Allowable Actual 

Positive 0 0.00 

(al 5-7in.H20) in. H20 per min. 

Negative 0 0.000 

(at 3in.Hg) dm cfm 

ORY GAS METER DATA CRITICAL ORIFICE DATA 

Volume Temp Critical IC Orifice Actual Ambient Temperature 

AH Tima Initial Final Total initial Final Orifice Calibrator Vacuum Initial Final Average 

(in HjO) (min) (ft3) (ft1

) (ft3

) "F °F Serial* Coefficien (InHg) °F °F °F 

0.29 20 0.050 6.37B 6.328 71 73 40 0.240 24 70 71 71 

0.64 15 6.402 13.325 6.923 72 76 48 0.350 22.5 72 72 72 

1.15 15 13.396 22.533 9.137 75 77 55 0.460 21 73 72 73 

1.90 10 22.577 30.451 7.874 77 79 63 0.594 19 73 72 73 

3.70 10 30.507 41.271 10.764 78 82 73 0.809 16 73 74 74 

CORRECTED VOLUME 

Dry Gas Critical DRY GAS METER DRY GAS METER 

Meter Orifice CALIBRATION CALIBRATION 

Vm (std ft3) Ver (std ft3) FACTOR Y FACTOR AH® 

6.259 6.212 0.993 0.001 1.691 -0.111 

6.831 6.779 0.992 0.00 1.762 -0.039 

8.989 8.919 0.992 0.00 1.830 0.02B 

7.732 7.668 0.992 0.00 1.818 0.02 

10.582 10.446 0.967 0.00 1.907 0.11 

| Avg. Y 0.991 || | Avg. AH@ 1.801 [| 

Notes: 1) For valid test results, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above. 

2) The Critical Orifice Coefficient, K, must be entered in English units, (ft)ft3"(deg R)*0.5/((in.Hg)*(mirO). 

3) The minimum number of sample volume required per orifice is 5 cubic feet. 

4) For Calibration Factor Y, the ratio of the reading of Ihe calibralion meter to Ihe dry gas meter, acceplable tolerance of individual values from the average is *0.02 

5) For Orifice Calibration Factor AH@, Ihe orifice differential pressure in inches of HjO that equates to 0,75 cfm of air at 68 F and 29.92 inches of Hg, 

acceptable tolerance of individual values from Ihe average !s ± 0,2. 

Dry Gas Meter Thermocouple Calibration 

Ref.TCIO* REF -SYR -TC2 Inlet ID#: 002-IN Outlet ID* 002-OUT 

Ref. Source Ref,"F T A A 

Amb. Air 65 66 -1 66 1 

Hot Water 118 118 0 117 -1 

Potentiometer Calibration 

Low 100 °e 99 

Mid 400 °F 400 

High 900 "F 899 

1) Hot Water to be in the range of 104 -122 °F. 

2) Tolerance allowed for all thermocouple individual readings: ± 5.4 °F 

3) Tolerance allowed for al) potentiometer individual readings: ± 2 °F 

y = 

»(«/) 

VES018549 
AECOM 

SAMPLE PROBE CALIBRATION DATA FORM 

TYPE "S" PITOT TUBE ASSEMBLY AND NOZZLE 

T hermocouple Calibration 

PROBE 10: 

S-M6-4D 

ft.i.r.t.e. 

ThiriTHmcMf ID *: 

PROBE 10: ENSR RTD #2131035 Cnegl CI100I1, #06022200 Omega CI10DO, #06022200 

S-M6-4D 

ft.i.r.t.e. 

ThiriTHmcMf ID *: 

Tub. Furrnca (300' • W h 

PROBE 10: 

S-M6-4D w TM . mhTM»» TC re ' . Twrp -

TC TC . Imp. Tn*. M H 

•F • • •. "•!(•' ' . *r- :, 

TWmm'. '.V .• • . M.m-_;'..•-: 'TC ' ' . TC ; Tin.. .-. 

'.TC . .y.'TO'^ ' Ttif* . . . ...T«V 'j .PTfTTM?.." > 

M h VR*TM . ;';-TC TC T«T> 

•'"TC ' '.. 'TC "~ '.'"^'TtBT. Tm» CKom. 

Date; 1/26/2009 

S-M5-4D 

34 274 34 274 0 212 373. 212 373 0.0 . 451 506 450 505 -0.1 

S-M5-4D 34 274 34 274 0 212 373 212 373 Q.O 451 506 450 505 -0.1 

34 274 34 274 0 212 373 212 373 0.0 451 506 450 505 -0.1 

*"» 34 274 34 274 0 212 373 212 373 0.0 451 506 450 505 -0.1 

Type "S" Pitot Tube Calibration: 

#> Pi. 

» 

0 . -

Level and Perpendicular 

Obstruction 

Damaged 

a, (-10°£ a, <-H0° ) 

eta (-10*S o 2 s 110°) 

IS, (-5"s B, =s *5° ) 

IS, (-5"s fijS *5") 

z = ATany(±S 0.125") 

W = ATan©(±£ 0.03125") 

D, (3/16 S 0,S 3/8") 

A 

A/2D, (1.05 s 1.5) 

BVpXM Nltlteillfie-MXMt * 

•eHmlnlnty than eeltMiate Z. 

Pitot Tube to Nozzle Calibration: 

1) PSal to noioSe separation 

|2> Trwrnocoupie to pstot sapualiDn 

13) Phot andio pnibo union dlittne. 

>3/V (vrf.SOO fwaha) 

Probe Information 

[Manufacturer: Apex 

Date Received and placed In Service: pre-1995 

(Condition of Probe wtien placed in service: flEVV UJ 

joWQC Check 

^Completeness _X _ Legibility __X„ 

certify that the Type S pitot tube/probe 10» SM5-4D, 

|criteria and/or applicable design features and Is hereby assigned a pitot tube calibration factor C, of 0.64 

RECONDITIONED (circle one) 

_ meets or exceeds aB Specifications, 

Specifications _X_ Reasonableness 

jCertified bv: Steven Milp 1/28/09 

Personnel (Signature/Date) 

Steven Miio 2/18/09 

Team. Leader (Signature/Date) 

[All construction criteria fer an isolated "S° type pltat are within given tolerances prescribed In 

Quality Assurance Handbook far Air PoKutian Measurement Systems: Volume til, Stationary Source-Specific Methods. 

EPA/600/R-9*/03Bc. September 1934 

VES018550 
DAILY CALIBRATION REPORT 

Date: 12/1/2009 

Start Time: 07:48:57 

End Time: 08:27:22 

Methods: 3A, 6C, 7E and 10 

Job Number: 120109 

Param 

C02 

THC 

Span 

Value 

11 

9 

Mid-Gas 

Standard 

5.02 

5.13 

Analyzer 

Zero Response 

0.07 

N/A 

Analyzer 

Mid Response 

4.97 

N/A 

Zero 

Cal Error 

0.7% 

0.2% 

Mid 

Cal Error 

-0.4% 

-2.5% 

System 

Zero Response 

0.09 

0.02 

Calibration Error = 100% x (Analyzer Response - Cylinder Gas Standard Value) / (Span Value) 

System Bias = 100% x (System Response - Analyzer Response) / (Span Value) 

For THC Measurements: 

Calibration Error = 100% x (System Response - Cylinder Gas Standard Value) / (Cylinder Gas Standard Value) 

System Bias = 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Mid Response 

4.95 

5. 

System 

Zero Bias 

0.1% 

0.2% 

System 

Mid Bias 

-0.2% 

-1.4% 

VES018551 
CALIBRATION CHECK REPORT 

Run ID: R1B Date: 12/1/2009 

Start Time: 13:13:05 

End Time: 16:59:38 

EPA Methods: 3A, 6C, 7E and 10 

Job Number: 120109 

Analyzer Analyzer 

Zero Mid 

Param Response Response 

C02 0.07 4.97 

THC N/A N/A 

System Bias= 

System Drift= 

System System System System System System System System 

Pre-Zero Pre-Mid Pre-Zero Pre-Mid Post-Zero Post-Mid Post-Zero Post-Mid 

Response Response Bias Bias Response Response Bias Bias 

0.05 5. -0.2% 0.3% 0.01 5.04 -0.6% 0.7% 

0.14 5.13 1.5% 0.0% 0.12 5.05 1.4% -0.9% 

100% x (System Response - Analyzer Response) / (Span Value) 

100% x (System Post Response - System Pre Response) / (Span Value) 

For THC Measurements: 

System Bias- 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

Zero Drift 

-0.3% 

-0.2% 

Mid Drift 

0.4% 

-0.9% 

System 

Avg-Zero 

Response 

0.03 

0.13 

System 

Avg-Mid 

Response 

5.02 

5.09 

VES018552 
DAIL Y CALIBRATIO N REPOR T Start Time: 07:53:46 Methods: 3A, 6C, 7E and 10 

Date: 12/272009 En d Time: 08:24:17 Job Number: 120209 

Param 

C02 

THC 

Span 

Value 

11 

9 

Mid-Gas 

Standard 

5.02 

5.13 

Analyzer 

Zero Response 

-0.01 

N/A 

Analyzer 

Mid Response 

5.03 

N/A 

Zero 

Cal Error 

0.0% 

0.3% 

Mid 

Cal Error 

0.1% 

-0.7% 

System 

Zero Response 

-0.03 

0.03 

Calibration Error = 100% x (Analyzer Response - Cylinder Gas Standard Value) / (Span Value) 

System Bias = 100% x (System Response - Analyzer Response) / (Span Value) 

For THC Measurements: 

Calibration Error = 100% x (System Response - Cylinder Gas Standard Value) / (Cylinder Gas Standard Value) 

System Bias = 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Mid Response 

4.99 

5.09 

System 

Zero Bias 

-0.2% 

0.3% 

System 

Mid Bias 

-0.3% 

-0.4% 

VES018553 
CALIBRATIO N CHEC K REPOR T 

Run ID: R2B Date: 12/2/2009 

Start Time: 11:23:21 

End Time: 16:18:21 

EPA Methods: 3A, 6C, 7E and 10 

Job Number: 120209 

Analyzer Analyzer System System System System System System System System 

Zero Mid Pre-Zero Pre-Mid Pre-Zero Pre-Mid Post-Zero Post-Mid Post-Zero Post-Mid 

Param Response Response Response Response Bias Bias Response Response Bias Bias Zero Drift Mid Drift 

C02 -0.01 5.03 0.08 5.04 0.7% 0.1% 0.07 5.05 0.7% 0.2% 0.0% 0.1% 

THC N/A N/A 0.08 ' 5.11 0.8% -0.2% 0.09 5.16 1.0% 0.4% 0.2% 0.6% 

System Bias= 100% x (System Response - Analyzer Response) / (Span Value) 

System Drift= 100% x (System Post Response • System Pre Response) / (Span Value) 

For THC Measurements: 

System Bias= 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Avg-Zero 

Response 

0.08 

0.08 

System 

Avg-Mid 

Response 

5.04 

5.14 

VES018554 
DAIL Y CALIBRATIO N REPOR T 

Date: 12/3/2009 

Start Time: 08:11:50 

End Time: 08:43:17 

Methods: 3A, 6C, 7E and 10 

Job Number: 120309 

Span 

Param Value 

C02 11 

THC 9 

Calibration Error = 

System Bias = 

Mid-Gas 

Standard 

5.02 

5.13 

Analyzer 

Zero Response 

0.02 

N/A 

Analyzer 

Mid Response 

5.02 

N/A 

Zero 

Cal Error 

0.2% 

0.3% 

Mid 

Cal Error 

0.1% 

-1.6% 

System 

Zero Response 

0.03 

0.03 

System 

Mid Response 

4.99 

5.05 

100% x (Analyzer Response • Cylinder Gas Standard Value) / (Span Value) 

100% x (System Response - Analyzer Response) / (Span Value) 

For THC Measurements: 

Calibration Error = 100% x (System Response - Cylinder Gas Standard Value) / (Cylinder Gas Standard Value) 

System Bias = 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

System 

Zero Bias 

0.1% 

0.3% 

System 

Mid Bias 

-0.3% 

-0.9% 

VES018555 
CALIBRATION CHECK REPORT 

Run ID: R3B Date: 12/3/2009 

Start Time: 12:12:16 

End Time: 16:38:32 

EPA Methods: 3A, 6C, 7E and 10 

Job Number: 120309 

Analyzer Analyzer 

Zero Mid 

Param Response Response 

C02 0.02 5.02 

THC N/A N/A 

System Bias= 

System Drift= 

System System System System System System System System 

Pre-Zero Pre-Mid Pre-Zero Pre-Mid Post-Zero Post-Mid Post-Zero Post-Mid 

Response Response Bias Bias Response Response Bias Bias 

-0.05 5. -0.7% -0.2% 0.04 5.01 0.1% -0.1% 

0.11 5.05 1.2% -0.9% 0.07 5.02 0.6% -1.3% 

100% x (System Response - Analyzer Response) / (Span Value) 

100% x (System Post Response - System Pre Response) / (Span Value) 

For THC Measurements: 

System Bias= 100% x (System Response - Cylinder Gas Standard Value) / (Span Value) 

Zero Drift 

0.8% 

-0.4% 

Mid Drift 

0.1% 

-0.4% 

System 

Avg-Zero 

Response 

-0.01 

0.09 

System 

Avg-Mid 

Response 

5.01 

5.03 

VES018556 
THC cals120109Unit3.XLS 

Initial THC Monitor Calibrations 

Facility Veolia ES Technical Solution Project No. 60133216 

Source Unit 3 Operator T. Sroczynski 

Polluntant THC Analyzer I.D. VIG Model 20 sn 07001794 

Date 01Dec09 Span Value 10 (ppm) 

Cylinder 

value,, 

ppm 

Zero and span 

system 

response, ppm 

Low and Mid Calibration 

error, 

% 

Cylinder 

value,, 

ppm 

Zero and span 

system 

response, ppm 

system res ponse, ppm 

Calibration 

error, 

% 

Cylinder 

value,, 

ppm 

Zero and span 

system 

response, ppm Predicted Actual 

Calibration 

error, 

% 

Zero gas 0 0.02 

Low gas 2.493 2.51 2.5 -0.31 

Mid gas 5.133 5.14 5 -2.77 

High gas 8.498 8.5 

Cylinder Identification Numbers 

Cylinder I.D. 

Zero gas Ultra Zero Grade 

Low gas CC212470 

Mid gas SG9108555BAL 

High gas SG909599ALB 

m = (High gas response - Zero gas response) / High Cylinder Value 

b = High gas response - (m * High Cylinder value) 

predicted response = m * Cylinder value + b 

Calibration Error = actual system response - predicted system response * 100 

cylinder value 

Criteria <=5% 

VES018557 
AECOM Initia l Monito r Calibration s 

Comments: 

Plant I.D. \l%pL(4 S)AU(jeT lUiuoiS Project No. -g Q I "5 3 .2 / 6 

Source I.D. UN i ~ 3 Operator T i £ Ro<lz.j AJ f K ' 

Pollutant Analyzer I.D. fryn Ha X 

Date 1 1 A l / 2- co< 7 Span Value I 1 

Analyzer Serial No. Ity j ^c/o . ~7 O C R A ^ 6 c?'^^ 4 

Initial Calibration (Time <3ff\2 7 ) 

Cylinder Value; 

(ppm or %) 

Analyzer 

Response 

(ppm or %) 

Calibration 

Error 

(% of Span) 

System 

Response 

(ppm or %) 

System 

' Bias 

(% of Span) 

Zero Gas O ,o6 on o, o f 

Low Level Gas — 

. — 

— — . 

Mid Level Gas 

High Level Gas 

/ 0 . 96 10.98 \6AS 

Cylinder I.D. 

Zero Gas AJ o ULTRA H^d/f foiTi 

Low Level Gas 

Mid Level Gas sa 3 

High Level Gas 

Calibration Error (Analyzer Response - Cylinder Value) X 100 

Span Value 

System Bias = (System Response - Analyzer Response) X 100 

Span Value 

VES018558 
THC cals120209Unit3.XLS 

Initial THC Monitor Calibrations 

Facility Veolia ES Technical Solution Project No. 60133216 

Source Unit 3 Operator T. Sroczynski 

Polluntant THC Analyzer I.D. VIG Model 20 sn 07001794 

Date 02Dec09 Span Value 10 (ppm) 

Cylinder 

value, 

ppm 

Zero and span 

system 

response, ppm 

Low and Mid Calibration 

error, 

% 

Cylinder 

value, 

ppm 

Zero and span 

system 

response, ppm 

system res ponse, ppm 

Calibration 

error, 

% 

Cylinder 

value, 

ppm 

Zero and span 

system 

response, ppm Predicted Actual 

Calibration 

error, 

% 

Zero gas 0 0.03 

Low gas 2.493 2.51 2.45 -2.48 

Mid gas 5.133 5.14 5.09 -0.98 

High gas 8.498 8.49 

Cylinder Identification Numbers 

Cylinder I.D. 

Zero gas Ultra Zero Grade 

Low gas CC212470 

Mid gas SG9108555BAL 

High gas SG909599ALB 

m = (High gas response - Zero gas response) / High Cylinder Value 

b = High gas response - (m * High Cylinder value) 

predicted response = m * Cylinder value + b 

Calibration Error = actual system response - predicted system response * 100 

cylinder value 

Criteria <=5% 

VES018559 
AECOM Initia l Monito r Calibration s 

Comments: 

Plant I.D. \ffo LIA SAufVTj I lUMotS Project No. 3 ~3 0 I £ 

Source I.D. (J M ( T 3 Operator "T« <S ^Qt-JtoS, Kl 

Pollutant ' Analyzer I.D. g'EfVVo "t * ^ 0 O 

Date ( X fo£L 13-d & cf Span Value 0-2 0 5. ft A w 6 S 

Analyzer Serial No. / /.£7<g ^ S P a »j i I 

Initial Calibration (Time 69 

Cylinder Value 

Analyzer 

Response 

(§@S¥33r-%) 

Calibration 

Error 

(% of Span) 

System 

Response 

(ppm or %) 

System 

Bias 

(%of Span) 

Zero Gas 

0,00 -0,6 I C O 

Low Level Gas 

— 

- — , — • 

Mid Level Gas 5 . 0 3 0 . 1 

High Level Gas 11.00 0 , <r 

Cylinder I.D, 

Zero Gas N a. 

Low Level Gas 

Mid Level Gas 

High Level Gas 

Calibration Error (Analyzer Response - Cylinder Value) X 100 

Span Value 

System Bias = (System Response - Analyzer Response) X 100 

Span Value 

VES018560 
THC cals120309Unit3.XLS 

Initial THC Monitor Calibrations 

Facility Veolia ES Technical Solution Project No. 60133216 

Source Unit 3 Operator T. Sroczynski 

Polluntant THC Analyzer I.D. VIG Model 20 sn 07001794 

Date 03DecQ9 Span Value 10 (ppm) 

Cylinder 

value, 

PPm 

Zero and span 

system 

response, ppm 

Low and Mid Calibration 

error, 

% 

Cylinder 

value, 

PPm 

Zero and span 

system 

response, ppm 

system res ponse, ppm 

Calibration 

error, 

% 

Cylinder 

value, 

PPm 

Zero and span 

system 

response, ppm Predicted Actual 

Calibration 

error, 

% 

Zero gas 0 0.03 

Low gas 2.493 2.50 2.49 -0.29 

Mid gas 5.133 5.11 5.05 -1.17 

High gas 8.498 8.44 

Cylinder Identification Numbers 

Cylinder I D. 

Zero gas Ultra Zero Grade 

Low gas CC212470 

Mid gas SG9108555BAL 

High gas SG909599ALB 

m = (High gas response - Zero gas response) / High Cylinder Value 

b = High gas response - (m * High Cylinder value) 

predicted response = m * Cylinder value + b 

Calibration Error = actual system response - predicted system response * 100 

cylinder value 

Criteria <=5% 

VES018561 
Initia l Monito r Calibration s 

Plant I.D. i M SauGe^IUJHQIS Project No. £ O / 3 3, 2 f £ 

Comments: Source I.D. U Kj J 3 

Pollutant d. & o 

Date 

Operator / - -S / ? o c z/a7 f/C / 

Analyzer I.D. S&K-ye W V 't*»0 

/ 2 A 3 A oa f Span Value <? fa»6e 

Analyzer Serial No. fty/S C / X, 70 £ 

Initial Calibration (Timedg. V3 ) 

Cylinder Value 

(ppm or %) 

. Analyzer 

Response 

(ppm or %) 

Calibration 

Error 

(% of Span) 

System 

Response 

(ppm or %) 

System 

Bias 

(%of Span) 

Zero Ga s 

D>o £>./ 

Low Level Gas — . — — — -

Mid Level Ga s 5,014, 0 0 / 

High Level Gas 16. U 0 . i •^• 3 

Cylinder. I.D. 

Zero Gas M a. (3 LTR A \hCHfuHi7t 

Low Level Gas 

Mid Level Gas SC <U(>HS/3 

High Level Gas 

Calibration Error (Analyzer Response - Cylinder Value) X 100 

Span Value 

System Bias = (System Response - Analyzer Response) X 100 

Span Value 

VES018562 
J 

! 

I 

f 

VES018563 
AECOM 

Appendi x D 

Laborator y Dat a 

VES018564 
Metho d 5/26 A 

VES018565 
AFXOIvl Report Environment 

Cas e Narrative 

Re Gravimetric Analysis of Filter and Front Half Probe Rinse Samples - Veolia ES Tech 

Sauget, IL 

Project #: 60133216 

LAB ID#: 09-064, 09-067, 09-069 

ANALYTICAL PROCEDURE: 

Eleven (11) Teflon® type filters and 12 front half acetone rinse samples were 

analyzed via EPA Method 5 Gravimetric Analysis as governed by AECOM's SOP 

2629-300. 

Consecutive gravimetric weights of filters and beaker residues were taken with an 

annually calibrated Mettler balance, and weighed within specified limits as outlined 

in EPA Method 5 and AECOM's SOP 2629-300. 

1. For two of three shipments received, 09-067 and 09-069, one field blank of 

both filter and acetone were analyzed as specified by EPA Method 5 

Gravimetric Analysis and AECOM's SOP 2629-300. The first set of samples, 

09-064, contained one acetone blank, but no filter blank was received. 

2. Laboratory blanks of both filter and acetone were analyzed for each of the 

three sets of samples per the same Method and SOP as listed above. 

1. For the first set of samples received, Lab ID: 09-064, two of the acetone 

sample bottles, M5-Acetone-RB and M5-U3-AR-R3, did not have the level of 

acetone marked on the bottle. Additionally, following evaporation of the first 

of these two samples, i.e. the field blank, a moist, oily-appearing residue was 

observed in the sample beaker. The gravimetric result for that sample 

indicated a net gain of 1.9 mg. 

2. Forthe third set of samples, Lab ID: 09-069, one ofthe acetone rinse sample 

bottles, M5-U4-FHR-R2, was found to contain a piece of aluminum foil, which 

was removed during the acetone rinse procedure and prior to weighing. 

, QUALITY CONTROL: 

DISCUSSION: 

Date Sainples Received by the Laboratory: 12/04, 12/11 & 12/21/09 

Date Analysis Started: 12/07/09 

R:\AirDBase\M5DBWIethod 5 DatabaseXMETHOD 5 CLIENT FILESWeoIia\09-064_067_069_CaseNarrative.doc 

Page 2 of 14 
AECO M 

Method 5 Exposed Filter Data Sheet 

Balance Used: 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Jeff Gorman 

Veolia 

60133216 

Oven Dried 

Mettle r 3 

Day Date ' Time ' R.H.(%) R.T. m Analyst J 

Start Monday 12/7/2009 9:18 44 68 wv 

Wt. 1 Friday 12/11/2009 8:44 37 67 w v 

Wt. 2 Monday 12/14/2009 10:09 36 68 A C 

Wt. 3 

Wt. 4 

QA Sheet 

Paga * 

InlBal.WelBht 

L_ =illt" 

•r.SQmpl^' 

•{Run.Date. 

r * 

Sample ID 

Filter , 

Typo/Sire' 

. 1st Wt. 

-.;.Grams 

2nd Wt. 

Grams 

A1&2WI. 

Grams3rdWt Grams ; 

4 2&3 Wt 

. Grams -

4th Wt 

Grams 

A 3 M Wt 

Grams 

Final Wt. 

Grams 

. A FW-IW 

Total Grams 

QA Sheet 

Paga * Date Grams L_ =illt" 

•r.SQmpl^' 

•{Run.Date. 

r * 

Sample ID 

Filter , 

Typo/Sire' 

. 1st Wt. 

-.;.Grams 

2nd Wt. 

Grams 

A1&2WI. 

Grams3rdWt Grams ; 

4 2&3 Wt 

. Grams -

4th Wt 

Grams 

A 3 M Wt 

Grams 

Final Wt. 

Grams 

. A FW-IW 

Total Grams 

88 11/25/09 0.3902 T1827 - — LAB FILTER BLANK 82.6mm 0.3902 0.3901 0.0001 ok by Wt. 0.3902 0.0003 

87 11/25/09 0.3989 T1817 12/01/09 M5-U3-F-R1 82.6mm 0.3996 0.3995 0.0001 ok by Wt. 0.3996 0.0007 

88 11/25/09 0.4020 T1822 12/02/09 M5-U3-F-R2 82.6mm 0.4035 0.4035 0.0000 ok by Wt. 0.4035 0.0015 

88 11/25/09 0.4014 T1821 12/03/09 M5-U3-F-R3 82.6mm 0.4025 0.4026 0.0001 ok by Wt. 0.4026 0.0012 

fD 

o 

Riter Type: G=G!ass HI^^^^M Q=Quartz 

1. Delta Weight tolerance +/- G.0005g of total weight less tare weight between two consecutive weightings or average weight. 

2. Filters must be weighed with !he proper conditions (RH = 25-50 % and RT = 59-78 deg f) 

3. Fillers must be property conditioned (24 hour desiccation; Further Conditioning > 6 hours). 

4. Conditioning far oven method; Oven dried at 105 deg c fo 2-3 hours; Further conditioning > 6 hours. 

5. Total grams below or equal to .0005 (LDl) is presented as .0003. 

Veolia-_09-064_60133216 email.xls 

VES018567 
AECO M 

Method 5 Front Half Acetone Probe Rinse Data Sheet 

Balance Used: Metller 3 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Projec Jeff Gorman - -Day^ . Date Time R.H.(%) R.T..CF) Analyst t Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Veolia 

Heat ADDlication 

Start Wednesday 12/9/2009 10:46 43 68 PT 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

60133216 

Heat ADDlication 

Wt. 1 Friday 12/11/2009 9 12 37 67 WV 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: NatOralfEvabotatlbn. ?V Heat ADDlication Wt. 2 Monday 12/14/2009 9 53 35 68 A C 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Wt. 3 Tuesday 12/15/2009 8 30 40 68 wv 

Wt. 4 Wednesday 12/16/2009 8 30 38 68 MW 

QA Sheet 

Page? 

Initial Wt. 

:.. Beaker. #• 

Sample 

Run Date Sample ID 

Field * 

mL ' 

Lab 

mL 

1st Wt. 

Grams2nd Wt. 

;

 Grams- -

A t&2Wt. 

.. Grams 

3rd Wt. 

Grams 

A2&3 Wt. 

Grams 

4th Wt. 

Grams 

A 3&4 Wt. 

Grams 

Final Wt. 

Grams 

AFW-IW 

Total Grams 

QA Sheet 

Page? Date ' v Grams: ., :.. Beaker. #• 

Sample 

Run Date Sample ID 

Field * 

mL ' 

Lab 

mL 

1st Wt. 

Grams2nd Wt. 

;

 Grams- -

A t&2Wt. 

.. Grams 

3rd Wt. 

Grams 

A2&3 Wt. 

Grams 

4th Wt. 

Grams 

A 3&4 Wt. 

Grams 

Final Wt. 

Grams 

AFW-IW 

Total Grams 

485 12/07/09 114.3999 2233 LAB ACETON E BLANK 50 114.4001 114.3996 0.0005 okbyWt. 114.3999 0.0003 

484 12/01/09 108.7119 2251 12/03/09 M5-Acetone-RB 153 60 108.7140 108.7136 0.0004 ok by Wt. 108.7138 0.0019 

484 12/01/09 106.7925 408 12/01/09 M5-U3-AR-R1 48 50 106.7954 106.7949 0.0005 ok by Wt. 106.7952 0.0027 

484 12/01/09 105.0055 22 12/02/09 M5-U3-AR-R2 59 50 105.0077 105.0074 0.0003 ok by Wt. 105.0076 0.0021 

484 12/01/09 109.9960 2291 12/03/09 M5-U3-AR-R3 60 50 109.9982 109.9976 0.0006 109.9985 0.0009 109.9973 0.0012 109.9979 0.0019 

Acetone Manufacturer/Lot No.: Fisher/092950. 

Acetone Rinse = 25 mis twice -(50 mis total) 

1. Delta Weight tolerance +/- O.OGOSg of total weight less tare weight between two consecutive weightings or average weight. 

2. Beakers must be weighed with the proper conditions (RH = 25-50 % and RT = 59-78 deg 0 

3. Beakers must be propeily conditioned (24 hour desiccation; Further Conditioning > 6 hours). 

4. Natural Evaporation Melhod = Evaporate to dryness at room temperature under a hood / watch glass cover 

5. Heat Application = Under a hood and watch glass over sample, apply heat below the boiling point of sample until evaporated to 25 mis: then follow step 4 (above) for remaining portion. 

6. Total grams below or equal to .0005 (LDL) Is presented as .0003. 

VES018568 
SAMPL E LOG-I N & RECEIP T CHECKLIS T 

Client/Proi# £" S I ecj.J fobj ^9-1L 

Project Mgr:_ Lab Pool #: 

Inspected & Logged in by: /\ l (^grfe-t-rlfi ._ Date & Time:_ 

Sdiiiph Matrix Number of 

/.Samples': 

Analysis 

R.CC|UGStCCl 

Hold Time & 

Duo by(date) 

Storage 

Location 

\ Disposal - I 

1'"-'id'ate ' • 1 

filte r 

* 

3 Tw Ut, 

-7—"— — J- f i f 

Duer )0-l)${fs 

HT: 

Due: 

1 

t 

Circle the appropriate response: 

1) (Shipp^/ Hand delivered 

2) CQC^prisel^ / not present on receipt 

3) Samples broken / leaking (^tia$£> on receipt 

4) Samples ^mbienty chilled on receipt 

5) Samples preserved correctly / incorrectly / ( fic^ilicommend|g' 

6) Received ^^^in)/outside holding time 

7) COC tapes present /^^Tot^resenhon samples / NA 

9) Discrepancies /^[Odiscrepancies^noted between COCs and samples 

Additional Comments: 1 U/h t>r^r,n^ J>r,ffi-eS ; MS- Afefpnr^-/Z£ a^/ 

jnf-A ^ t/QuTil /W, / fear/1 Jjprff ^ 

C 

r 

L 

£ 

58 

Page 12 of 14 

8/26/2008 

VES018569 
Sampl e Traceabilit y Lis t 

AECO M 

Site of Program: Veolia ES Tech Sample Date: /SL// - /2./3/c& Project Location: Sauget, IL P.O.#: 

Type of Program: CPT Date Shipped: / O/S/i ? Laboratory: AECO M Environment 

Proiect#: 60133216 Harvard, MA 

Proqram Office: Syracuse NY 

Shipper/ ' ' Steven Milo 

Recovery: Jeff Gorman 

Laboratory: AECO M Environment 

Harvard, MA 

Program Contact: Jeff Gorman FedEx Air Bill #: 

Item Sample ID Code Sample Matrix Sample Description Analitical Parameters Special Instructions 

1 M5-U3-F-R1 Filter M5, Filter, Run 1 Particulate Matter g ^f-foC <-f — / 

2 M5-U3-AR-R1 Acetone M5, FH Acetone Rinse, Run 1 Particulate Matter /5 ~ 

3 

4 M5-U3-F-R2 Filter M5, Filter, Run 2 Particulate Matter Q Cf—Q I. *-j 

5 M5-U3-AR-R2 Acetone M5, FH Acetone Rinse, Run 2 Particulate Matter p Cj y_ 

6 

7 M5-U3-F-R3 Filter M5, Filter, Run 3 Particulate Matter rflCjf- fi l\ Lf — "3 

8 M5-U3-AR-R3 Acetone M5, FH Acetone Rinse, Run 3 Particulate Matter fltA—fi/^U 

9 

10 

11 -

12 

13 

14 

15 

16 

17 

18 

19 

M5-Acetone-RB Acetone M5-Acetone Blank Particulate Matter Q -J> tr 9 "t £ 

Field Nc >tes/ Comments 

Page of 

Relinquished By (print): Date: 

Signature: , Time: 

Relinquished By (print): Date: 

Signature: ^^_^Jm&ss1''^ 

Relinquished By (print): Date: 

Signature: Time: 

Received by Lab (print): Date: . 

Signature: ^ _ Time: 

Received By (print): Date: 

Signature: ^Tjmgj=^-— 

Received By (print): ^ 

Signature: Time: 

Received By (print): Datel"' 

Signature^^--(£j / Time: 

7— • 

Analytical Laboratory Destination: 

AECO M Environment 

325 Ayer Road 

Harvard, MA 01451 

Attn: Mr. Paul Taverna (978) 772-2345 Ext 32 

VES018570 
1 

TestAmerica 

THE LEADER IN ENVIRONMENTAL TESTING 

TestAmerica Laboratories, Inc. 

ANALYTICAL REPORT 

PROJEC T HO . 5013321 6 

Veoli a - K S Tec h 

L o t # : H9L07040 5 

Jef f Gorma n 

AECOM , In c 

510 5 Campuswoo d Driv e 

Suit e 10 4 

Eas t Syracuse , N Y 1305 7 

TESTSMERIC A LABORATORIES , INC . 

Kevi n S . Woodcoc k 

Projec t Manage r 

Decembe r 10 , 200 9 

5815 Middlebrook Pike Knoxville, TN 37921 tel 865.291.3000 fax 865.584.4315 www.testamericainc.com 

VES018571 
ANALYTICAL METHODS SUMMARY 

H9L07040 5 

ANALYTICA L 

PARAMETE R METHO D 

Chlorin e Emission s KNO X 0050/26 A Mo d 

Hydroge n Chlorid e Emission s KNO X 0050/26 A Mo d 

R e f ereaices : 

KNO X TestAmeric a Laboratorie s Inc. , Knoxvill e Laborator y Standar d 

Operatin g Procedur e 
3 

SAMPLE SUMMARY 

H9L0.7040 5 

WO # SAMPLE # CLIEN T SAMPL E I D 

SAMPLE D SAM P 

DAT E TIM E 

LOL O 4 

LQLO B 

LQL1 E 

LQL1 M 

LQL1 V 

LQL1 X 

LQL2 K 

LQL2 P 

LQL2 T 

0 0 1 

0 0 2 

0 0 3 

0 0 4 

0 0 5 

0 0 6 

0 0 7 

0 0 8 

0 0 9 CPT-CL2-F B 

CPT-U3-HCL-IMP 1 

CPT-U3-CL2-IMP 5 

CPT-U3-HCL-IMP 1 

CPT-U3-CL2-IMP 5 

CPT-U3-HCL-IMP 1 

CPT-U3-CL2-IMP 5 

CPT-DIWATER-F B 

CPT-HCL-F B 

4 - R 1A/ B 

6 - R 1 

4 - R 2A/ B 

6 - R 2 

4 - R 3A/ B 

6 - R 3 

12/01/0 9 

12/01/0 9 

12/02/0 9 

12/02/0 9 

12/03/0 9 

12/03/0 9 

12/03/0 9 

12/03/0 9 

12/03/0 9 

NOT E (S ) : 

- The analytical results ol' the samples listed above are presented on tlie following pages. 

• All calculations are performed before rounding to avoid round-off errors in calculated results. 

- Results noted as "ND" were aoi detected at or above the stated limit. 

- TIlis report must not be reproduced, except lit full, without die written approval of die laboratory. 

- Results for the following paramelers are never reported on a dry weight basis: color, corrosiviiy, density, flashpoint, ignitability, layers, odor, 

paint litter test. pH. porosity pressure, reactivity, redox potential, specific graviiy, spot tests, solids, solubility, temperature, viscosity, and weight. 

VES018573 
4 

PROJECT NARRATIVE 

H9L07040S 

The results reported herein are applicable to the samples submitted for analysis only. 

This report shall not be reproduced except in full, without the written approval of the 

laboratory. 

The original chain of custody documentation is included with this report. 

Sample Receipt 

Custody seals were not present. 

Samples were received in two shipments on 12/3/09 and 12/4/09. 

Quality Control and Data Interpretation 

Unless otherwise noted, all holding times and QC criteria were met and the test results 

shown in this report meet all applicable NELAC requirements. 

Samples were analyzed for chloride by ion chromatography using SOP number 

KNOX-WC-005 (based on BPA methods 9056,9057 and 26A). All sample results were 

reported as total jig hydrogen chloride (HCI) and total ug chlorine (CI2). Results were 

calculated using the following equations: 

Ch, ug = (Chloride,ug/ml)* (SampleVolume,mL)* Bench Dilution 

NaOH impinger samples were treated with sodium thiosulfate (NajSzOj) prior to the final 

analysis in order to convert residual hypochlorite (OC1") to chloride ion. 

Note: A sample volume of 100 mL was used to convert the results to total ug for the 

method blanks, laboratory control samples, and client reagent blanks in order to 

standardize the analyte sample total, 

TestAmerica Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Lab #88-

0688, California DHS ELAP Cert. #2423. Colorado DPHE, Connecticut DPH Lab #PH-0223, Florida DOH Lab 

#E87177, Georgia DNR Lab #906, Hawaii DOH, Illinois EPA Lab #200012, Indiana DOH Lab #C-TN-02, Iowa DNR 

Lab #375. Kansas DHE Cert. #E-10349, Kentucky DEP Lab #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH, 

Maryland DOE Cert #277, Michigan DEQ Lab #9933, Nevada DEP, New Jersey.DEP Lab #TN001, New York DOH 

Lab #10781, North Carolina DPH Lab #21705, North Carolina DEHNR Cert. #64, Ohio EPA VA P Lab #CL0059, 

Oklahoma DEQ Lab #9415, Pennsylvania DEP Lab #68-00576, South Carolina DHEC Cert #84001001, Tennessee 

D O H Lab #02014, Texas CEQ, Utah DOH Lab # QUAN3, Virginia DGS Lab #00165, Washington DOE Lab #C 1314, 

West Virginia DEP Cert #345, West Virginia DHHR Cert #9955C, Wisconsin DNR Lab #998044300, Naval Facilities 

Engineering Service Center and USDA Soil Permit #S-46424. This list of approvals is subject to change and does not 

imply that laboratory certification is available for all parameters reported in this environmental sample data report. 

HCI, ug = (Chloride, ug/mL)* (Sample Volume,mL)* Molecular Weight HCI 

Molecular Weight Cl 

* Bench Dilution 

VES018574 
PROJECT NARRATIVE 

H9L070405 

For demonstration of analytical method performance on these samples, TestAmerica 

Knoxville analyzed matrix spikes (MS) and matrix spike duplicates (MSD). Acceptable 

recoveries of these spikes demonstrate that quantitation from this particular stack gas 

matrix is accurate and acceptable. Impinger samples containing 0.1N H2SO4 and 0.1N 

NaOH display matrix interference effects causing poor method performance and possibly 

giving unreliable data unless the interference is removed. Therefore, the samples were 

diluted in the lab to remove the interference for a more accurate chloride response. The 

samples may be analyzed at increasing dilutions along with matrix spikes until matrix 

spikes recover from the sample within laboratory control limits. The ion chromatograph 

calibration range used to quantitate the sample results permits a standard ten-fold sample 

dilution while supporting the reporting limit with the low calibration standard. . 

The dilution factor reported on the sample result form does not represent the bench 

dilution factor. It is actually the combination of factors required by the method, to convert 

the anion reporting limit and method detection limit from ug/mL to total ug.. It may 

appear to be elevated because it includes the total sample volume in mL. 
6 

QC DATA ASSOCIATION SUMMARY 

H9L07040 5 

Sampl e Preparatio n an d Analysi s Contro l Number s 

SAMPLE # 

0 0 1 

0 0 2 

0 0 3 

0 0 4 

0 0 5 

0 0 6 

0 0 7 

0 0 8 

0 0 9 

MATRI X 

, AI R 

A I R 

A I R 

A I R 

A I R 

A I R 

A I R 

A I R 

A I R 

ANALYTICA L 

METHO D 

KNO X 0050/26 A Mo d 

KNO X 0050/26 A Mo d 

KNO X 005O/26 A Mo d 

KNO X 0O5O/26 A Mo d 

KNO X 0050/26 A Mo d 

KNO X O0SO/26 A Mo d 

K2TOX 0050/26 A Mo d 

KNO X 0050/26 A Mo d 

KNO X 0O5O/26 A Mo d 

LEAC H 

BATC H # 

PRE P 

BATC H # 

934329 6 

934318 7 

934329 6 

934318 7 

934329 6 

934318 7 

934329 7 

934329 8 

934318 7 

M S RUN # 

934321 8 

934313 2 

934321 8 

934313 2 

934321 8 

934313 2 

934325 4 

934408 2 

934313 2 

VES018576 
7 

Sampl e Dat a Summar y 

VES018577 
8 

AECOM , In c 

Clien t Sampl e ID ; CET-TJ3-HCL-IMP1-4- E 1A/ B 

Genera l Chemistr y 

lot-Sampl e : H9L070405-00 1 Wor k Orde r #... : LQL0 4 Matri x : AI R 

Dat e Sample d : 12/01/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T • R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e 1410 0 212 0 u g KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21165.0 7 MDL : 890 

VES018578 
9 

AECOM , In c 

Clien t Sampl e ID ; CPT-03-CI.2-IMP5-6- R X 

Genera l Chemistr y 

Lot-Sampl e #-.. : H9L070405-00 2 Wor k Orde r #.. . : LQL0 8 Matri x : : AI R 

Dat e Sampled. : 12/01/0 ? Dat e Received.12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Chlorin e N D 49 0 u g KNO X 0050/2S A Mo d 12/08/0 9 934318 7 

Dilutio n Factors 4900 MDL : 210 

VES018579 
10 

AECOM , In c 

Clien t Sampl e ID : CPT-U3-HCL-rMPl-4- R 2A/ B 

Genera l Chemistr y 

Lot-Sampl e #... : H9L070405-00 3 Wor k Orde r #... : LQL1 E Matri x : AI R 

Dat e Sampled. : 12/02/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e 1480 0 220 0 u g KNO X 0050/2S A Mo d 12/07/0 9 934329 6 

Dilutio n Factors 21967.2 5 HDL s 920 

VES018580 
11 

AECOM , In c 

Clien t Sampl e ID : CPT-D3-CL2-IMPS-S-j R 2 

Genera l Chemistr y 

tot-Sampl e #... : H9L070405-00 4 Wor k Orde r LQL1 M Matri x : AI R 

Dat e Sampled... : 12/02/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L • • UNIT S METHO D ANALYSI S DAT E BATC H # 

Chlorin e N D 48 0 u g KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4600 HDL : 200 

VES018581 
12 

AECOM , In c 

Clien t Sampl e ID : CPT-D3-HCI.-IMP1-4- R 3A/ B 

Genera l Chemistr y 

Lot-Sampl e #... : H9L070405r-00 5 Wor k Orde r #... : LQL1 V Matri x : AI R 

Dat e Sampled. . . : 12/03/0 9 Dat e Received . . : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e 2740 0 401 0 u g KNO X O050/26 A Mo d 12/07/0 3 934329 6 

Dilutio n Factors 40149.B8 MDL.-. : 1700 

VES018582 
13 

Lot-Sampl e # . 

Dat e Sampled . 

AECOM , In c 

Clien t Sampl e ID : CPT-D3-CL2-IMP5-S- R 3 

Genera l Chemistr y 

: H9L070405-00 S Wor k Orde r #... : LQL1 X 

. : 12/03/0 9 Dat e Received . . : 12/04/0 9 

Matri x i : AI R 

PARAMETE R 

Chlorin e 

RESUL T R L 

M D 

UNIT S METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

5 5 0 u g 

Dilutio n Factor : .5500 

KNO X 0050/2S A Mo d 12/08/0 9 

MDI. : 230 

934318 7 

VES018583 
14 

AECOM, . In c 

Clien t Sampl e ID : CPT-DIWATER-F B 

Genera l Chemistr y 

Lot-Sampl e : H9L070405-00 7 Wor k Orde r : LQL2 K Matri x : AI R 

Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/Q 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e N D 10 3 u g KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 1028.4 3 MDL : 43 

VES018584 
15 

AECOM , In c 

Clien t Sampl e 10 : CPT-HCL-F B 

Genera l Chemistr y 

Lot-Sampl e #... : H 9 L 070405 T :00 8 Wor k Orde r LQL2 P Matri x : AI R 

Dat e Sampled.. ; : 12/03/0 9 Dat e Received.. : 12/04/0 9 

• PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S . . METHO D ANALYSI S DAT E BATC H # 

"Hydroge n chlorid e N D 41 1 u g KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

Dilutio n Factor : 4X13.7 2 MDL : 170 . 

VES018585 
16 

AECOM , In c 

Clien t Sampl e ID : CPT-CL2-F B 

Genera l Chemistr y 

Lot-Sampl e : H9L070405-00 9 Wor k Orde r #... : LQL2 T Matri x : AI R 

Dat e Sampled,.. : 12/03/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RBSOL T R L ONIT S METHO D ANALYSI S DAT E BATC H 

Chlorin e . • N D 10 0 u g KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilution . Factor : 1000 MDI/ : 42 

VES018586 
17 

Clien t Lo t #... : H9L07040 S 

METHO D BLAN K EEPOR T 

Genera l Chemistr y 

Matrix . A I R 

PARAMETE R RESUL T 

Chlorin e 

REPORTIN G 

LIMI T UNIT S METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

Wor k Orde r # : LQQW31A A M B Lot-Sampl e .#: H9L090000-18 7 

N D 10. 0 u g ICNOX 0050/26 A Mo d 12/08/0 9 

Dilutio n Factor : 100 

934318 7 

Hydroge n chlorid e Wor k Orde r # : LQRXV1A A M B Lot-Sampl e # : H9L090000-29 6 

N D 10. 3 u g ICNOX 0050/26 A Mo d 12/07/0 9 

Dilutio n Factor : 102. 8 

934329 6 

Hydroge n chlorid e Wor k Orde r # : LQR7V1A A M B Lot-Sampl e # : H9L090000-29 7 

N D 10. 3 u g . KNO X 0050/26 A Mo d 12/08/0 9 

Dilutio n Factor : 102. 8 

934329 7 

Hydroge n chlorid e Wor k Orde r # : LQT4G1A A M B Lot-Sampl e # : H9L090000-29 8 

N D 10. 3 u g ICNOX 0050/26 A Mo d 12/09/0 9 

Dilutio n Factor : 102. 8 

934329 8 

NOTECS) : 

Calculations are performed before roundins to avoid round-off errors in calculated results. 

VES018587 
18 

LABORATOR Y CONTRO L SAMPL E EVALUATIO N REPOR T 

Genera l Chemistr y 

Lot-Sampl e H9L07040 S Matrix . A I R 

PARAMETE R 

Chlorin e 

PERCEN T 

RECOVER Y 

9 9 

9 7 

RECOVER Y RP D PREPARATION - PRE P 

LIMIT S RP D LIMIT S METHO D ANALYSI S DAT E BATC H # 

W0#:LQQW31AC-LCS/LQQW31AP-LCS D LC S Lot-Samplet : H9L090000-18 7 

( 9 0 - 110 ) KNO X 0050/26 A Mo d 12/08/09 . 934318 7 

( 9 0 - 110 ) 2. 1 (0-20 ) KNO X 0050/2S A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 100 

Hydroge n chlorid e 

9 4 

9 4 

W0#-.LQRXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Satnple# : H9L090000-29 6 

( 9 0 - 110 ) KNO X 0050/2S A Mo d • 12/07/0 9 934329 6 

( 9 0 - 110 ) 0.0 9 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factors 102. 6 

Hydroge n chlorid e 

9 9 

9 7 

W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Sample# : H9L090OO0-29 7 

( 9 0 - 110 ) KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

( 9 0 - 110 ) 2.1 . (0-20 ) ICNOX 0050/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 102. 8 

Hydroge n chlorid e 

1 0 0 

9 7 

W0#:LQT4G1AC-LCS/LQT4G1AD-LCS D LC S Lot-Sample# : H9L090000-29 8 

( 9 0 - 110 ) KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

( 9 0 - 110 ) 2. 8 (0-20 ) KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

Dilutio n Factor : 102. 8 

NOT E IS ) : . _ 

Calculations arc performed before rounding io avoid round-off errors in calculated results. 

VES018588 
19 

LABORATOR Y CONTRO L SAMPL E DAT A REPOR T 

Genera l Chemistr y 

Lot-Sampl e it...: H9L 0 7040 5 . Matrxx . A I R 

PARAMETE R 

Chlorin e 

SPIK E MEASORE D PERCN T 

AMOUN T AMOUN T UNIT S RECVR Y RP D METHO D 

75. 0 

75. 0 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

WO#:LQQW31AC-LCS/LQQW3IAD-LCS D LC S Lot-Sampleft : H9L090000-18 7 

74. 0 u g 9 9 KNO X 0050/26 A Mo d 12/08/0 9 93431B 7 

72. 4 u g 9 7 2. 1 KNO X 005O./26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factors io o 

Hydroge n chlorid e 

77. 1 

77. 1 

W0S:LQEXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Sample*- . H9L090000-29 S 

72. 5 u g 9 4 KNO X O05O/2S A Mo d 12/07/0 9 934329 6 

72. 6 u g 9 4 0.0 9 KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 102.B 

Hydroge n chlorid e 

77. 1 

77. 1 • 

W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Sample# : H9L090OO0-29 7 

76. 1 u g 9 9 KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

74. 5 u g 9 7 2. 1 KNO X 005O/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 102. 8 

Hydroge n chlorid e 

77. 1 

77. 1 

W0#:LQT4G1AC-LCS/LQT4G1AD-LCS D LC S Lot-Sample# : H9L090000-29 8 

77. 3 u g 10 0 KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

75. 1 u g 9 7 2. 8 KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

Dilutio n Factor : 102.B 

NOTB(S ) 

Calculations arc performed before roundiog to avoid round-off errors in calculated results. 

VES018589 
20 

MATRI X SPIK E SAMPL E EVALUATIO N REPOR T 

Clien t Lo t #.. , 

Dat e Sampled.. . 

: H9L07040 5 

: 12/02/0 9 

Genera l Chemistr y 

Dat e Received.. : 12/04/0 9 

Matri x : AI R 

PARAMETE R 

Chlorin e 

,PERCEN T RECOVER Y 

RECOVER Y LIMIT S R P D 

R P D 

LIMIT S METHO D 

PREPARATION -

ANALYSI S DAT E 

PRE P 

BATC H # 

1 0 0 

1 0 1 

WO# : LQL1M1AC-MS/LQL1M1AD-MS D M S Lot-Sampl e # : H9L07040S-00 4 

( 7 5 .- 125 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

( 7 5 - 125 ) 0.9 3 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4800 

Hydrogre n chlorid e 

9 0 

8 6 

WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e #: H9L0704O5-00 3 

( 7 5 - 125 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

( 7 5 - 125 ) 0.9 6 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21967 

NOT E (S ) : ' 

Calculations are pcribrmed before rouoding to avoid round-otT errors in calculated results. 

VES018590 
21 

MATRI X SPIK E SAMPL E DAT A REPOR T 

Genera l Chemistr y 

Clien t Lo t # . 

Dat e Sampled . 

H9L07040 5 

12/02/0 9 Dat e Received.. : 12/04/0 9 

Matrix . AIR . 

SAMPL E SPIK E MEASR D 

PARAMETE R AMOUN T AM T 

Chlorin e 

N D 

N D 

9 6 0 

9 6 0 

AMOUN T UNIT S 

PERCN T 

RECVR Y RP D METHO D 

PREPARATIO N - PRE P 

ANALYSI S DAT E BATC H # 

WO# : LQLIMIAC-MS/LQLIMIAD-MS D M S Lot-Sampl e # : H9L07O405-0O 4 

9 5 9 u g . 10 0 KNO X 0050/26 A 12/08/0 9 934318 7 

9 6 8 u g 10 1 0.9 3 KNO X 0050/26 A 12/08/0 9 934318 7 

Dilutio n Factor : 4 800. 

Hydroge n chlorid e 

1480 0 439 0 

1480 0 439 0 

WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e #: H9L07O405-00 3 

1880 0 u g 9 0 KNO X 0050/26 A 12/07/0 9 934329 6 

1860 0 u g 8 6 0.9 6 KNO X 0050/26 A 12/07/0 9 934329 6 

Dilutio n Factor : 21967 

NOT E (S ) : 

Calcubtions arc pcrrormcd before roundins to avoid round-off errors in calculated results. 

VES018591 
22 

Clien t Lo t #... : H9L07040 5 

Dat e Sampled... : 12/01/0 9 

SAMPL E DDPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r : LQL04-SM P 

LQL04-DU P 

Dat e Received.. : 12/04/0 9 

PARA M RESUL T 

DUPLICAT E 

RESUL T 

Hydroge n chlorid e 

1410 0 1410 0 

UNIT S 

R P D 

R P D LIMI T METHO D 

Matri x : AI R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e # : H9L0704Q5-0O 1 

u g 0.3 2 (0-20 ) ICNOX 0050/2S A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21165.0 7 

VES018592 
23 

H9L07040 5 

12/01/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r LQL08-SM P 

LOLO8-DU P 

Dat e Received.. ; 12/04/0 9 . . 

N D 

Matrix . A I R 

UNIT S 

R P D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e #:•H9L070405-00 2 

u g 0 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor i 4900 

VES018593 
24 

Clien t Lo t #... : H9L07040 5 

Dat e Sampled... : 12/02/0 9 

SAMPL E DDPLICAT E EVBLTJRTIO H REPOR T 

Genera l Chemistr y 

Wor k Orde r #... : LQL1E-SM P 

LQL1E-DU P 

Dat e Received-. : 12/04/0 9 

PARA M RESUL T 

DUPLICAT E 

RESUL T 

Hydroge n chlorid e 

1480 0 1460 0 

UNIT S 

R P D 

R P D LIMI T METHO D 

Matri x : . AI R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e # : H9L070405-00 3 

u g 1. 5 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor ; 21967.2 5 

VES018594 
25 

Clien t Lo t # . 

Dat e Sampled. . 

PARA M RESUL T 

Chlorin e 

N D 

H9L07040 5 

12/02/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r #... : LQL1M-SM P 

LQUM-DU P 

Dat e Received... - 12/04/0 9 

N D 

UNIT S 

R P D 

R P D LIMI T METHO D 

Matri x : AI R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e #.- H9L070405-0O 4 

u g 0 (0-20 ) KNO X 0050/2S A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4800 

VES018595 
26 

Clien t Lo t H9L0704D 5 

Dat e Sampled... : 12/03/0 9 

SAMPLE DUPLICATE EVALUATION REPORT 

Genera l Chemistr y 

Wor k Order . #... : LQL1V-SM P 

LQL1V-DU P 

Dat e Received.. : 12/04/0 9 

DUPLICAT E 

PARA M RESUL T RESUL T 

Hydroge n chlorid e 

2740 0 2780 0 

Matrox . . : AI R 

UNIT S R P D 

R P D 

LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

T ' S D Lot-Sampl e # : H9L07D405-00 5 

u g 1. 5 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 40149.8 6 

VES018596 
27 

Clien t Lo t #... : H9L07040 5 

Dat e Sampled. . . : 12/03/0 9 

SAMPL E DDPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r #. .. i LQL1X-SM P 

LQL1X-DU P 

Dat e Received.. ! 12/04/0 9 ... 

PARA M RESUL T 

Chlorin e 

N D 

DUPLICAT E 

RESUL T 

N D 

Matrix . A IR 

UNIT S 

R P D • 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E , BATC H # 

• S D Lot-Sampl e # : H9L070405-00 6 

u g 0 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 5500 

VES018597 
28 

Clien t Lo t # . 

Dat e Sampled . 

PARA M RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

H9L070405 . . Wor k Orde r #... : LQL2K-SM P 

LQL2K-DU P 

12/03/0 9 Dat e Received.. : 12/04/0 9 

DUPLICAT E 

RESUL T UNIT S R P D 

R P D 

LIMI T METHO D 

Matri x : AI R 

PREPARATIO N - PRE P 

ANALYSI S DAT E BATC H # 

Hydroge n chlorid e 

N D N D 

S D Lot-Sampl e # : H9L070405-00 7 

u g 0 (0-20 ) KNO X 0050/2S A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 1028.4 3 

VES018598 
29 

. , Clien t Lo t # . .. : H9L07040 5 

Dat e Sampled.-. : 12/03/0 9 

SAMPL E DUPLICAT E EVALUATIO N EEPOR T 

Genera l Chemistr y . 

Wor k Orde r #... : LQL2P-SM P 

LQL2P^DU P 

Dat e Received.. : 12/04/0 9 

PARA M RESUL T 

DUPLICAT E 

RESUL T 

Hydroge n chlorid e 

N D N D 

UNIT S R P D 

R P D 

LIMI T METHO D 

Matrix . A I R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e #: H9L070405-00 8 

u g 0 (0-20 ) KNO X 0050/2S A Mo d 12/09/0 9 

Dilutio n Factor : 4X13.7 2 

934329 8 

VES018599 
30 

Cliea t Lo t # . 

Dat e Sampled . 

PARA M RESUL T 

Chlorin e 

N D 

. : H9L07040 5 

. : 12/03/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r # . - . : LQL2TrSM P 

LQL2T-DU P 

Dat e Received.. : 12/04/0 9 

N D 

UNIT S R P D 

R P D 

LIMI T METHO D 

. Matri x : AI R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e # : H9L070405-00 9 

u g 0 (0-20 ) KNO X 0050/2S A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 1000 

VES018600 
31 

Sample Receipt Documentation 

VES018601 
Sampl e Traceabilit y Lis t AECO M 

Site of Prorjram: Veolia ES Tech . Sample Date: tai i - lZ./3/rtV Project Location: Sauget, IL LabPO#': 

Type of Program: CPT Date Shipped: l't/-4/6<? Laboratory: Test America, Inc. 

Project* 60133218 Knoxville, TN 

Program Office: Syracuse NY 

Shipper/ Steven Milo 

Recovery: Jeff Gorman 

Laboratory: Test America, Inc. 

Knoxville, TN 

Program Contact Jeff Gorman FedEx Air Bill 8: 

Hem Sample ID Code Sample Matrix Sample Description Analytical Parameters Special Instructions 

1 CPT-U3-HCL-HWP1-4-R 1 A 0.1N H2S04 Unit 3, Impingers 1-4, Run 1 A HCL 

2 CPT-U3^HCL-IMP1-4-R 1 B 0.1N H2S04 Unit 3, Impingers 1-4, Run 1 B HCL 

3 CPT-U3-CI2-IMP5-6-R 1 0.1N NaOH Unit 3, Impingers 5-6, Run 1 

4 

5 CPT-U3-HCL-1MP1-4-R 2 A 0.1N H2S04 Unit 3, Impingers 1-4, Run 2 A HCL &{a\a 

6 CPT-U3-HCL-IMP1-4-R 2 B 0.1NH2SO4 Unit 3, Impingers 1-4, Run 2 B HCL i*i4(M.-r s 

7 CPT-U3-CI2-IMP5-6-R2 0.1 N NaOH Unit 3, Impingers 5-6, Run 2 

6 1 

9 CPT-U3-HCL-HVIP1 -4-R 3 A 0.1 N H2S04 Unit 3, Impingers 1-4, Run 3 A HCL 

10 CPT-U3-HCL-IMP1-4-R 3 B 0.1 N H2S04 Unit 3, Impingers 1-4, Run 3 B HCL 

' 11 CPT-U3-CI2-IMP5-6-R 3 0.1 N NaOH Unit 3, Impingers 5-6, Run 3 CI2 

12 

13 

14 

15 

16 

17 OX Vhlstci' b t vAer pWr i SU^C- hcl/Cb . 

18 CPT-HCL-FB 0.1NH2SO4 0.1NH2SO4 Field Blank HCL' 

19 CPT-CI2-FB 0.1 N NaOH 0.1N NaOH Field Blank CI2 

20 

Field Notes/ Comments 

Page of 

Relinquished By (print): Date: 

Steven Milo l2/3/e<} 

Signature: . Time: 

A//^y> -WlL /7oa 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: ^ ~ 

Received by Lab (print): Date: 

Sjinatuia/" J , Time: 

^%rtrVIV\ mvis 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature; Time: 

Received By (print): Date: 

Signature: Time: 

Analytical Laboratory Destination: 

Test America Inc. 

6815 Middlebrook Pike 

Knoxville, TN 37921 

Attn: Mr. Kevin Woodcock 865-291-3000 

CO 

ro 

VES018602 
TESTAMERICA KNOXVILLE SAMPLE RECEIPT/CONDITION UPON RECEIPT ANOMALY CHECKLIST 

Lot Number: .M W VfrlODiOb 

Review Items ND NA 

PW» 1 

If No, what wns the problem? Comments/Actions Taken 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

I. Do sample container labels match COC? 

(IDs, Dates, Times) J 

iO l a Do not match CO C 

0 l b Incomplete information 

0 l c Marking smeared 

O l d Label tom 

D i e No label 

• 1 r CO C not received 

B i g Other: 

2. Is the cooler temperature within limits? (> freezing 

temp, of water to 6°C;NC, 1668,1613B: 0-4°C; 

VOST: 10*C; MA:2-6°C) 

J 2. Is the cooler temperature within limits? (> freezing • 2a Temp Blank = temp, of water to 6°C;NC, 1668,1613B: 0-4°C; 

VOST: 10*C; MA:2-6°C) 

J 0 2b Cooler Temp = 

2. Is the cooler temperature within limits? (> freezing 

temp, of water to 6°C;NC, 1668,1613B: 0-4°C; 

VOST: 10*C; MA:2-6°C) 

J 

3. Were samples received with correct chemical 

preservative (excluding Encore}? f j 3. Were samples received with correct chemical 0 3a Sample preservative = preservative (excluding Encore}? f j 0 3a Sample preservative = 

4. Were custody seals present/intact on cooler and/or 

containers? 

1 

I H 4a Not present 

0 4b Not intact 

D 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? 

1 

I H 4a Not present 

0 4b Not intact 

D 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? 

1 

I H 4a Not present 

0 4b Not intact 

D 4c Other: 

5. Were all ofthe samples listed on the COC received? J 

-

• 5a Samples received-noton CO C 

0 5b Samples not received-on CO C 

5. Were all ofthe samples listed on the COC received? J 

-

• 5a Samples received-noton CO C 

0 5b Samples not received-on CO C 

6. Were all of the sample containers received intact? 

I 

D 6a Leaking 

• 6b Broken 

7- Were VO A samples received without headspace? / I • 7a Headspace (VOA only) 

8. Were samples received in appropriate containers? 

... 1 .. 

0 8a Improper container 

9. Did you check for residual chlorine, if necessary? J • 9a Could not be determined due 

to matrix interference 

9. Did you check for residual chlorine, if necessary? J • 9a Could not be determined due 

to matrix interference 

10. Were samples received within holding time? 010 a Holding time expired 

i l . For rad samples, was sample activity info, provided? J • Incomplete information 

12. For 1613B water samples is pH<9? 

J 

If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

12. For 1613B water samples is pH<9? 

J 

If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

13. Are the shipping containers intact? • 13a Leaking 

0 I3b Other: 

14. Was COC relinquished? (Signed/Dated/Timed) • 14a Not relinquished 

15. Are tests/parameters listed for each sample? j 0 15a Incomplete information 

16. Is the matrix of the samples noted? h • 15n Incomplete infonnation 

17. Is the date/time of sample collection noted? • 15a Incomplete information 

18. Is the client and project name/# identified? • 15a Incomplete information 

19. Was the sampler identified on the COC? 

Ouoteff: <?Y?3? P M Instructions: 

( ~\ A ^rr^Z 6 

Sample ReceivinE Associate: ^fffiU ^TWdK Date:l2- S\tP QA026R21.doc, 090409 

CO 

CO 

VES018603 
34 

Wet Chemistry 

VES018604 
35 

Sample Summary 

VES018605 
36 

AECOM , in c 

Clien t Sampl e ID : CPT-rj3-HCL-IMPl-4- R 1A/ B 

Genera l Cnemistr y 

Lot-Sampl e H9L070405-00 1 Wor k Orde r LQL0 4 .Matri x : AI R 

Dat e Sampled... : 12/01/0 9 Dat e Received . - : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e 1410 0 212 0 u g KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21165.0 7 HSI> , : B90 

VES018606 
37 

AECOM , m c 

Clien t Sampl e ID : CPT-03-CL2-IMP5-6- R 1 

Genera l Chemistr y 

Lot-Sampl e #... : H9L0704O5-00 2 Wor k Orde r ft... : LQL0 8 Matri x : AI R 

Dat e Sampled... : 12/01/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L OMIT S METHO D ANALYSI S DAT E BATC H # 

Chlorin e N D 49 0 u g KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4900 HDL : 210 

VES018607 
38 

AECOM , In c 

Clien t Sampl e ID : CPT-TJ3-HCL-IMP1-4- R 2A/ B 

..Genera l Chemistr y 

LotTSampl e #... : H9L070405-00 3 Wor k Orde r #... : LQL1 E MatEbc r : AI R 

Dat e Sampled... : 12/02/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n Chlorid e 1480 0 220 0 u g KNO X 0050/26 A Mo d 12/07/0 9 934329 S 

Dilutio n Factor : 21967.2 5 MDL : 920 

VES018608 
39 

AECOM , In c 

Clien t Sampl e ID : CPT-TJ3-CL2-IKP5-6- R 2 

Genera l Chemistr y 

Lot^Sarapl e #.... - H9L07040S-00 4 . Wor k Orde r #... : LQL1 M Matrix... - AI R 

Dat e Sampled... : 12/02/0 9 Dat e Received.12/04/0 3 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Chlorin e N D 48 0 u g KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4800 MDL... . : 200 

VES018609 
40 

AECOM , In c 

Clien t Sampl e ID : CPT-TJ3-HCL-IMP1-4- R 3A/ B 

Genera l Chemistr y 

Lot-Sampl e : H9L070405.-.D0 5 . .Work-Orde r : LQL1 V Matri x AI R 

Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L TJHIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e 2740 0 401 0 u g KNO X 005O/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 40149.8 8 MDL : 1700 

VES018610 
41 

AECOM , In c 

Clien t Sampl e TDz CPT-TB-CL2-IMPS-S- R 3 

Genera l Chemistr y 

Lot-Sampl e #..H9L070405-00 6 Wor k Order : LQL1 X Matri x : AI R 

Dat e Sampled,.. r 12/03/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESOL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Chlorin e N D 55 0 u g KNO X 005Q/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor ; 5500 MDL : 230 

VES018611 
42 

AECOM , In c 

Clien t Sampl e ID : CPT-DIWATBR-F B 

Genera l Chemistr y 

Lot-Sampl e ft-..: H9L070405-00 7 . Wor k Orde r #... : LQL2 K .... ..Matri x : AI R 

Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/0 9 

PREPARATION - PRE P 

PARAMETE R RESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # 

Hydroge n chlorid e N D 10 3 u g KNO X 005Q/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 1028.4 3 MDL.. . 43 

VES018612 
43 

AECOM , In c 

Clien t Sampl e ID : CPT-HCL-F B 

Genera l Chemistr y 

Lot-Sampl e #-.. : H9L070405.T008 ... Wor k Orde r : LQL2 P Matri x : AI R .. 

Dat e Sampled... : 12/03/09 Dat e Received.. : 12/04/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydroge n chlorid e ND 411 u g KNOX 0050/26A Mo d 12/09/09 9343298 

Dilutio n Factor : 4113.7 2 MDL. : 170 

VES018613 
44 

Lot-Sampl e # . 

Dat e Sampled . 

PARAMETE R 

AECOM , In c 

Clien t Sampl e ID : CPT-CL2-F B 

Genera l Chemistr y 

. : H9L07O4OS-OO 9 Wor k Order.LQL2 T 

. : 12/03/0 9 Dat e Received.. : 12/04/0 9 

RESUL T R L UNIT S METHO D 

Matri x : AI R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

Chlorin e N D 1 0 0 u g 

Dilutio n Factor : 1000 

KNO X 0050/26 A Mo d 12/08/0 9 

MDI. : 42 

934318 7 

VES018614 
45 

QC Summary 

VES018615 
46 

METHO D BLAN K REPOR T 

Genera l Chemistr y 

Clien t Lo t # . . . : H9L07040 5 

PARAMETE R 

. REPORTIN G 

RESUL T LIMI T UNIT S METHO D 

Matri x : AIR 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

Chlorin e 

N D 

Wor k Orde r # : LQQW31A A M B Lot-Sampl e # : H9L090000-18 7 

10. 0 u g KNO X 0050/26 A Mo d 12/08/0 9 

Dilutio n Factor : 100 

934318 7 

Hydroge n chlorid e Wor k Orde r # : LQRXVIA A M B Lot-Sampl e # : H9L090000-29 6 

N D 10. 3 u g KNO X 0050/26 A Mo d 12/07/0 9 

Dilutio n Factor : 102. E 

934329 6 

Hydroge n chlorid e Wor k Orde r # : LQR7V1A A M B Lot-Sampl e # : H9L090000-29 7 

N D 10. 3 u g KNO X 0050/26 A Mo d 12/08/0 9 

Dilutio n Factor : 102. 8 

934329 7 

Hydroge n chlorid e Wor k Orde r # : LQT4G1A A M B Lot-Sampl e # : H9L090000-29 8 

N D 10. 3 u g ICNOX 0D50/26 A Mo d 12/09/0 9 

Dilutio n Factor : 102. 8 

934329 8 

NOTE <S) ; 

Catcufaions arc performed before rounding lo avoid round-off errors in calculated remits. 

VES018616 
47 

LABORATOR Y CONTRO L SAMPL E EVALUATIO N REPOR T 

Genera l Chemistr y 

Lot-Sampl e H9L07040 S Matrix . 

PARAMETE R 

Chlorin e 

PERCEN T 

RECOVER Y 

99 

97 

RECOVER Y 

LIMIT S R P D 

R P D 

LIMIT S METHO D 

PREPARATION -

ANALYSI S DAT E 

: AI R 

PRE P 

BATC H # 

WO#!LQQW31AC-LCS/LQQW31AD-LCS D LC S Lot-Sample# : H9L090000-18 7 

( 9 0 - 110 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

( 9 0 - 110 ) 2. 1 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 100 

Hydroge n chlorid e 

9 4 

9 4 

W0#:LQRXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Sample# : H9L09OO0O-29 S 

( 9 0 - 110 ) KNO X 00S0/2S A Mo d 12/07/0 9 934329 6 

( 9 0 - 110 ) 0.0 9 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 102. S 

Hydroge n chlorid e 

9 9 

9 7 

W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Sample# : H9L090000-29 7 

( 9 0 - 110 ) KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

( 9 0 - 110 ) 2. 1 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 102. 8 

Hydroge n chlorid e 

1 0 0 

9 7 

WO#:LQT4GlAC-LCS/LQT4GlAD-LCS D LC S Lot-Sample# : H9L090000-29 8 

( 9 0 - 110 ) KNO X 00S0/26 A Mo d 12/09/0 9 934329 8 

( 9 0 - 110 ) 2. 8 (0-20 ) KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

Dilutio n Factor : 102. 8 

NOTB(S) : 

Calculations arc perforated before rounding to avoid round-off errors in calculated results. 

VES018617 
48 

LABORATOR Y CONTRO L SAMPL E DAT A REPOR T 

Genera l Chemistr y 

LotT -Sampl e #. , 

PARAMETE R 

Chlorin e 

H9L0704Q 5 

SPIK E MEASURE D 

AMOUN T AMOUN T UNIT S 

Matxajc . AIR 

PERCN T 

RECVR Y RP D METHO D 

PREPARATION -

ANALYSI S DAT E 

75. 0 

75. 0 

PRE P 

BATC H # 

WO#:LQQW31AC-LCS/LQQW31AD-LCS D LC S Lot-Sample# : H9L09OO0O-18 7 

74. 0 u g 9 9 KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

72. 4 u g 9 7 2. 1 KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 100 

Hydroge n chlorid e 

77. 1 

77. 1 

W0#:LQRXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Sample# : H9L090000-29S . 

72. 5 u g 9 4 KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

72. 6 u g 9 4 0.0 9 KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 102. 8 

Hydroge n chlorid e 

77, 1 

77. 1 

W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Satnple# : H9L090000-29 7 

76. 1 u g 9 9 KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

74. 5 u g 9 7 2. 1 KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 102. 8 

Hydroge n chlorid e 

77. 1 

77. 1 

W0#:LQT4G1AC-LCS/LQT4G1AD-LCS D LC S Lot-Sampled : H9L090000-29 8 

77. 3 u g 10 0 KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

75. 1 u g 9 7 2. 8 KNO X 0050/26 A Mo d 12/09/0 9 934329 8 

Dilutio n Factor : 102. 8 

NOTE(S ) : 

Calculaiions are performed before rounding to avoid round-off errors in calculated results. 

VES018618 
49 

MATRI X SPIK E SAMPL E EVALUATIO N REPOR T 

Genera l Chemistr y 

Clien t Lo t tt. 

Dat e Sampled -

PARAMETE R 

Chlorin e 

H9L07040 5 

12/02/0 9 

PERCEN T RECOVER Y 

RECOVER Y LIMIT S 

Dat e Received.. : 12/ 0 4/ 0 9 

R P D 

R P D 

LIMIT S METHO D 

Matri x : AI R 

PREPARATION -

ANALYSI S DAT E 

PRE P 

BATC H # 

1 0 0 

1 0 1 

WO# : LQLIMIAC-MS/LQL-IMIAD-MS D MS Lot-Sampl e #: H9LO7040S-O0 4 

( 7 5 - 125 ) KNO X 0050/26 A Mo d 12/08/0 9 9343L8 7 

( 7 5 - 125 ) 0.9 3 (0-20 ) KHO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4800 

Hydroge n chlorid e 

9 0 (7 5 

8 6 (7 5 

WO# : LQLIEIAC-MS/LQLIEIAD-MS D MS Lot-Sampl e #: H9L070405-00 3 

125 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

125 ) 0.9 6 (0-20 ) KNO X 0O50/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21967 

NOTB<S) : 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES018619 
50 

MATRI X SPIK E SAMPL E DAT A REPOR T 

Genera l Chemistr y 

Clien t Lo t H9L07040 S 

Dat e Sampled.-. : 12/02/0 9 Dat e Received.. : 12/04/0 9 

Matrix . AIR , 

SAMPL E SPIK E MEASR D 

PARAMETE R AMOUN T AMT . 

Chlorin e 

N D 

N D 

9 6 0 

9 6 0 

AMOUN T UNIT S 

PERCN T 

RECVR Y RP D METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

WO#:'LQLIMIAC-MS/LQLIMIAD-MS D M S Lot-Sampl e # : H9LO70405-0O 4 

9 5 9 u g 10 0 KNO X 0050/26 A 12/08/0 9 934318 7 

9 6 8 u g 10 1 0.9 3 KNO X 0050/26 A 12/08/0 9 934318 7 

Dilutio n Factor : 4800 

Hydroge n chlorid e 

1480 0 439 0 

1480 0 439 0 

WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e # ; H9LO70405-OO 3 

1880 0 u g 9 0 KNO X 0050/26 A 12/07/0 9 934329 6 

1860 0 u g 8 6 0.9 6 KNO X 0050/26 A 12/07/0 9 934329 6 

Dilutio n Factor : 21967 

NOTE CS) 

Calculaiions arc performed before rounding to avoid round-off errors in calculated results. 

VES018620 
51 

Clien t Lo t #. . 

Dat e Sampled. . 

PARA M RESUL T 

H9L07040 5 

12/01/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r #... : LQL04-SM P 

LQL04-DU P 

Dat e Received.. : 12/04/0 9 

Hydroge n chlorid e 

1410 0 ' 1410 0 

Matrxx . A I R 

UNIT S 

R P D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e ff : H9L070405-00 1 

U g 0.3 2 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21165.0 7 

VES018621 
52 

Clien t Lo t # . 

Dat e Sampled . 

PARA M RESUL T 

Chlorin e 

N D 

H9L07040 5 

12/01/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r #... : LQL08-SM P -

LOLO8-DU P 

Dat e Received.. : 12/04/0 9 

N D 

Matrix . AIR 

UNIT S 

R P D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e #: H9L070405-00 2 

t i g 0 (0-20 ) KNO X 0050/2S A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 4900 

VES018622 
53 

Clien t Lo t #... : H9L07040 S 

Dat e Sampled... : 12/02/0 9 

SAMPL E DDPLICAT E EVALUATIO N EEPOR T 

Genera l Chemistry -

Wor k Orde r 4f. . . : LQL1E-SM P 

LQL1E-DU P 

Dat e Received12/04/0 9 

PARA M RESUL T 

DUPLICAT E 

RESUL T 

Hydroge n chlorid e 

1480 0 1460 0 

Matrxx . AIR 

UNITS ' 

R P D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e #.- H9L070405-OO 3 

u g 1. 5 (0-20 ) KNO X 0050/2S A Mo d 12/07/0 9 934329 6 

Dilutio n Factor : 21357.2 3 

VES018623 
54 

Clien t Lo t # . 

Dat e Sampled . 

PARA M RESUL T 

Chlorin e 

N D 

. : H9L07040 5 

. : 12/02/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistry -

Wor k Orde r #... : LQL1M-SM P . 

LQL1M-DU P 

Dat e Received.. : 12/04/0 9 

N D 

UNIT S 

R P D 

R P D LIMI T METHO D 

Matri x : AI R 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e #: H9L070405-00 4 

u g 0 (0-20 ) KNO X 0050/2S A Mo d 12/08/0 9 934318 7 

Dilutio n Factor ! 4800 

VES018624 
55 

Clien t Lo t ft...: H9L07040 5 

Dat e Sample d : 12/03/0 9 

SAMPLE DUPLICATE EVALUATION REPORT 

Genera l Chemistry ' 

Wor k orde r ft...: LQL1V-SMP 

LQL1V-DU P 

Dat e Received.. : 12/04/09 

DDPLICAT E 

PARA M RESUL T RESUL T 

Hydroge n chlorid e 

2740 0 2780 0 

J4atrix . AIK 

UNIT S 

R P D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D Lot-Sampl e ft: H9L070405-00 5 

u g 1. 5 (0-20 ) KNO X 0050/26 A Mo d 12/07/0 9 934329 6 

Dilutio n Factor ; 40149.88 

VES018625 
56 

Clien t Lo t ft. 

Dat e Sampled . 

PARA M RESUL T 

Chlorin e 

N D 

H9L070405 

12/03/0 9 

DUPLICAT E 

RESUL T 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

. Wor k Orde r ft...: LQL1X-SM P 

LQL1X-DU P 

Dat e Received-. : 12/04/0 9 

N D 

Matrix . A I R 

UNIT S 

• RP D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H ft 

' " S D Lot-Sampl e #: H9L070405-00 6 

u g o <0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 5500 

VES018626 
57 

Clien t Lo t #... : H9L07040 S 

Dat e Sampled... : 12/03/0 9 

DDPLICAT E 

PARAM.RESUL T RESUL T 

Hydroge n chlorid e 

N D N D 

SAMPL E DUPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r If... : LQL2K-SM P .... 

LQL2K-DU P 

Dat e Received.. : 12/04/0 9 

Matrxx . A IR 

UNIT S 

R P D 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H # 

S D LOt-Sampl e #: H9L070405-00 7 

u g 0 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934329 7 

Dilutio n Factor : 1028.4 3 

VES018627 
58 

Clien t Lo t .ft.. . : H9L0. 7 040 5 

Dat e Sampled... : 12/03/0 9 

DDPLICAT E 

SAMPL E DDPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r ft...: LQL2P-SMP • 

LQL2P-DU P 

Dat e Received.. : 12/04/0 9 ... 

PARA M RESUL T RESUL T 

Hydroge n chlorid e 

N D N D 

Matrix . .AI R 

UNIT S 

R PD 

R P D LIMI T METHO D 

PREPARATION - PRE P 

ANALYSI S DAT E BATC H ft 

S D Lot-Sampl e ft: H9L07O405-0O 8 

u g 0 (0-20 ) KNO X 0050/25 A Mo d 12/09/0 9 934329 8 

Dilutio n Factor : 4113.7 2 

VES018628 
59 

H9L0704.0 5 

12/03/0 9 

DDPLICAT E 

RESUL T 

SAMPL E DDPLICAT E EVALUATIO N REPOR T 

Genera l Chemistr y 

Wor k Orde r #.. . : LQL2T-SM P • 

LQL2T-DU P 

Dat e Received.. : 12/04/0 9 

N D 

Matrix . A I R 

UNIT S 

R P D 

R E D LIMI T METHOD ' 

PREPARATION - PRE P 

ANALYSI S DOB . BATC H # 

S D Lot-Sampl e # : H9L070405-OO S 

u g 0 (0-20 ) KNO X 0050/26 A Mo d 12/08/0 9 934318 7 

Dilutio n Factor : 1000 

VES018629 
Metho d 0023 A 

VES018630 
•Vist a 

Analytical Laboratory 

December 18,2009 

Vista Project LD.: 32244 

Mr. Jeffrey Gorman 

AECOM Environment 

5015 Campuswood Drive 

Suite 104 

East Syracuse, NY 13057-4232 

Dear Mr. Gorman, 

Enclosed are the results for the four MM5 samples received at Vista Analytical Laboratory- on 

December 04, 2009 under your Project Name "60133216". The front and back halves of these 

samples were extracted and analyzed using Method 0023A for tetra-through-octa chlorinated 

dioxins and furans. The front and back halves of the Field Blank were combined for extraction and 

analysis. A standard turnaround time was provided for this work. 

The following report consists of a Sample Inventory (Section I), Analytical Results (Section II) 

and the Appendix, which contains the chain-of-custody, a list of data qualifiers and abbreviations, 

Vista's current certifications, and copies of the raw data (if requested). 

Vista Analytical Laboratory is committed to serving you effectively. If you require additional 

information, please contact me at 916-673-1520 or by email at mmaier@vista-analytical.com. 

Thank you for choosing Vista as part of your analytical support team. 

Sincerely, 

Laboratory Director 

Vista Analytical Laboraloiy certifies that the report herein meets all the requirements set forth byMLACfor those applicable 

test mefhods. Results relate only lo the samples as received by the laboratory. This report should not be reproduced except In full 

is. -without the written approval qf Vista Analytical Laboratory. 

Vista Analytical Laboratory | ll04Windfield Way | El Dorado Hills,CA95762 I ph:916-673-1520 | fx:916-673-0!06 I wwww.vista-analytical.com 

Project 32244 Page 1 of 18 

VES018631 
Wist a 

Section I: Sample Inventory Report 

Date Received: 

Project No.: 

Project Name: 

12/4/2009 

32244 

60133216 

Lab. Sample ID Client Sample ID Component ID 

001 

002 

003 

004 

005 

006 

007 

CPT-U3-M23A-XAD-R 1 

CPT-U3-M23A-PF-R 1 

CPT-U 3 -M2 3 A-XA D -R2 

CPT-U3-M23A-PF-R 2 

CPT-U3-M23A-XAD-R 3 

CPT-U3-M23A-PF-R 3 

CPT-U3-M23A-F B 

B H R 

X A D 

F H R 

FILTE R 

B H R 

X A D 

F H R 

FILTE R 

B H R 

X A D 

F H R 

FILTE R 

BLAN K 

FILTE R 

X A D 

SinpinvgnmmS.rpt 

Project 32244 Page 2 o f 18 

VES018632 
Vista 

SECTION II 

rojccl 32244 

Pa>:c 3 of 18 

VES018633 
Metho d Blan k Method 0023A 

Matrix: MM 5 Q C Batch No.: 2603 Lab Sample: 0-MB001 

Sample Size: Sample Date Extracted: 8-Dec-09 Date Analyzed DB-5 : 9-Dec-09 Date Analyzed DB-225: N A 

Analyt e Cone. (pg/Sample) D L

 a EMP C b Qualifiers Labeled Standard % R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD N D 0.480 IS 13C-2,3,7,8-TCDD 90.8 4 0 - 135 

1,2,3,7,8-PeCDD N D 0.664 13C-l,2,3,7,8-PeCDD 87.1 4 0 - 135 

1,2,3,4,7,8-HxCDD N D 0.857 13C-1,2,3,6,7,8-HxCDD 92.6 40-13 5 

1,2,3,6,7,8-HxCDD N D 0.861 13C-l,2,3,4,6,7,8-HpCDD 86.6 40 - 135 

1,2,3,7,8,9-HxCDD N D 0.791 13C-OCD D 82.9 40-13 5 

1,2,3,4,6,7,8-HpCDD N D 0.898 I3C-2,3,7,8-TCDF 93.3 4 0 - 135 

OCD D N D 1.03 13C-l,2,3,7,8-PeCDF 86.3 40-13 5 

2,3,7,8-TCDF N D 0.516 13C-1,2,3,6,7,8-HxCDF 92.2 4 0 - 135 

1,2,3,7,8-PeCDF N D . 0.519 13C-1,2,3,4,6,7,8-HpCDF 93.2 40-13 5 

2,3,4,7,8-PeCDF N D 0.548 13C-OCDF 84.5 40 - 135 

1,2,3,4,7,8-HxCDF N D 0.512 P S 37Cl-2,3,7,8-TCDD 95.0 . 70-13 0 

1,2,3,6,7,8-HxCDF N D 0.513 13C-2,3,4,7,8-PeCDF 97.4 70-13 0 

2.3,4,6,7,8-HxCDF N D 0.550 13C-1,2,3,4,7,8-HxCDD 98.1 7 0 - 130 

1,2.3,7,8,9-HxCDF N D 0.561 13C-1,2,3,4,7,8-HxCDF 95.7 70 - 130 

1.2.3.4.6,7,8-HpCDF N D 0.584 13C-l,2,3,4,7,8,9-HpCDF 92.4 7 0 - 130 

l.2,3.4,7,S,9-HpCDF N D 0.648 A S 13C-l,2,3,7,8,9-HxCDF 101 40 - 135 

OCD F N D 0.950 

Totals Toxi c Equivalent Quotient (TEQ ) Dat a 

e 

Total TCD D N D 0.480 T E Q (Min-Max): 0 - 1 . 6 5 

Total PeCD D N D 0.664 

Total HxCD D N D 0.836 a. Sample specific estimated detection limit 

Total HpCD D N D 0.898 b. Estimated niaximurn possible concentration. 

Total TCD F N D 0.516 c. Method detection limit. 

Total PeCDF N D 0.534 d. Lower control limit - upper control limit. 

Total HxCD F N D 0.534 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCD F N D 0.616 

Analyst JM H Approved By: William J. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 4 o f 18 

VES018634 
vista 

OPR Results Method 0023A 

Matrix: MM 5 QC Batch No.: 2603 Lab Sample: 0-OPR001 

Sample Size: Sample Dale Extracted: 8-Dec-09 Date Analyzed DB-5 : 9-Dec-09 Date Analyzed DB-225: N A 

Analyt e Spike Cone. Cone . (ng/mL) O P R Limits Labeled Standard % R LCL-UC L Qualifie r 

2,3,7,8-TCDD 2.50 2.44 1.75 - 3.25 IS 13C-2,3,7,8-TCDD 93.5 4 0 - 135 

1,2,3,7,8-PeCDD 12.5 12.5 8.75 - 16.25 13C-l,2,3,7,8-PeCDD 89.0 40-13 5 

1,2,3,4,7,8-HxCDD 12.5 12.4 8.75 - 16.25 I3C-l,2,3,6,7,8-HxCDD 90.1 40-13 5 

1,2,3,6,7,8-HxCDD 12.5 12.7 8.75 - 16.25 13C-1,2,3,4,6,7,8-HpCDD 87.7 4 0 - 135 

1,2,3,7,8,9-HxCDD 12.5 12.7 8.75 - 16.25 I3C-OCD D 85.1 40-13 5 

1,2,3,4,6,7,8-HpCDD 12.5 12.2 8.75 - 16.25 13C-2,3,7,8-TCDF 93.3 4 0 - 135 

OCD D 25.0 24.5 17.5 - 32.5 13C-l,2,3,7,8-PeCDF 87.6 4 0 - 135 

2,3,7,8-TCDF 2.50 2.52 1.75-3.25 l3C-l,2,3,6,7,8-HxCDF 90.4 4 0 - 135 

1,2,3,7,8-PeCDF 12.5 12.5 8.75-16.25 13C-1,2,3,4,6,7,8-HpCDF 95.8 40-13 5 

2,3,4,7,8-PeCDF 12.5 12.7 8.75 - 16.25 13C-OCDF 88.8 4 0 - 135 

1,2,3,4,7,8-HxCDF 12.5 12.6 8.75 - 16.25 A S 13C-l,2,3,7,8,9-HxCDF 99.5 4 0 - 135 

1,2,3,6,7,8-HxCDF 12.5 12.5 8.75 - 16.25 

2,3,4,6,7,8-HxCDF 12.5 12.9 8.75 - 16.25. 

1,2,3.7,8.9-HxCDF 12.5 12.7 8.75 - 16.25 

1,2,3,4,6,7,8-HpCDF 12.5 12.6 8.75-16.25 

1,2,3,4,7,8,9-HpCDF 12.5 11.5 8.75 - 16.25 

OCD F 25.0 24.3 17.5 - 32.5 

Analyst: JM H Approved By: William J. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 5 o f 18 

VES018635 
Sample ID: CPT-U3-M23A-XAD-R1 Method 0023A 

Client Data 

Name: 

Project: 

Date Collected: 

Time Collected: 

AECO M Environment 

60133216 

l-Dec-09 

N A 

Sample Data 

Matrix: MM 5 

Sample Size: Sample 

Laboratory Data 

Lab Sample: 

QC Batch No.. 

Dale Analyzed DB-5 

32244-001 Date Received: 4-Dec-09 

2603

 Dal<: Extracted: 8-Dec-09 

9-Dec-09 Dal« Analyzed DB-225: 10-Dec-09 

Analyt e Cone. (pg/Sample) D L EMPC U Qualifiers Labeled Standard % R LCL-UC L 

J IS 13C-2,3,7,8-TCDD 86.4 4 0 - 135 

J 13C-l,2,3,7,8-PeCDD 84.9 40 - 135 

J 13C-l,2,3,6,7,8-HxCDD 89.0 40 - 135 

13C-l,2,3,4,6,7,8-HpCDD 84.6 40 - 135 

.1 13C-OCDD 77.4 4 0 - 135 

13C-2,3,7,8-TCDF 88.2 40 - 135 

13C-l,2,3,7,8-PeCDF 82.2 4 0 - 135 

13C-l,2,3,6,7,8-HxCDF 88.9 40 - 135 

J 13C-l,2,3,4,6,7,8-HpCDF 88.7 4 0 - 135 

13C-OCDF 80.4 4 0 - 135 

PS 37Cl-2,3,7,8-TCDD 94.4 7 0 - 130 

P 13C-2,3,4,7,8-PeCDF 95.7 70 - 130 

I3C-I,2,3,4,7,8-HXCDD 92.0 7 0 - 130 

J 13 C-1,2,3,4,7,8-HxCDF 89.0 7 0 - 130 

13C-l,2,3,4,7,8,9-HpCDF 86.0 7 0 - 130 

J A S 13C-l,2,3,7,8,9-HxCDF 90.5 4 0 - 135 

2,3,7,8-TCDD 4.67 

1,2,3,7,8-PeCDD 24.2 

1,2,3,4,7,8-HxCDD 26.4 

1.2.3.6.7.8- HxCD D 58.7 

1.2.3.7.8.9- HxCD D 36.9 

1,2,3,4,6,7,8-HpCDD 405 

OCD D 537 

2,3,7,8-TCDF 33.3 

1,2,3,7,8-PeCDF 45.5 

2,3,4,7,8-PeCDF 97.6 

1,2,3,4,7,8-HxCDF 71.5 

1.2,3,6,7,8-HxCDF 60.8 

2.3.4.6.7.8- HxCD F 82.6 

1.2.3.7.8.9- HxCD F 19.9 

1.2.3.4.6.7.8- HpCD F 232 

1.2.3.4.7.8.9- HpCD F 22.8 

OCD F 84.3 

Totals 

Total TCD D 

Total PeCD D 

Total HxCD D 

Total HpCD D 

Total TCD F 

Total PeCD F 

Total HxCD F 

Total HpCD F 

2470 

1990 

4870 

991 

1260 

1110 

694 

334 

Toxi c Equivalent Quotient (TEQ ) Dat a 

1270 

T E Q (Min-Max): 114 - 114 

a. Sample specific estimated detection limit 

b: Estimated maximum possible concentration. 

c. Method detection limit. 

d. Lower control limit - upper control limit. 

e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Analyst: JMH Approved By: William J. Luksemburg I7-Deo2009 13:55 

cct 32244

 PA ^6 O F 1 8 

VES018636 
Sample ID: CPT-U3-M23A-PF-R1 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 1 -Dec-09 

Time Collected: N A 

Matrix: 

Sample Size. 

M M 5 

Sample 

Lab Sample. 32244-002 

QC Batch No.: 2603 

Date Analyzed DB-5" 9-Dec-09 

Date Received: 

Date Extracted: 

Date Analyzed DB-225: 

4-Dec-09 

8-Dec-09 

N A 

Analyt e Cone . (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d Qualifiers 

2,3,7,8-TCDD N D 0.644 IS 13C-2,3,7,8-TCDD 90.0 40 - 135 

1,2,3,7,8-PeCDD N D 0.918 13C-l,2,3,7,8-PeCDD 86.0 40 - 135 

1,2,3,4,7,8-HxCDD N D 0.844 13C-l,2,3,6,7,8-HxCDD 87.9 40 - 135 

1,2,3,6,7,8-HxCDD N D 0.848 13C-l,2,3,4,6,7,8-HpCDD 83.7 4 0 - 135 

1,2,3,7,8,9-HxCDD N D 0.779 13C-OCDD 79.0 40 - 135 

1,2,3,4,6,7,8-HpCDD N D 1.11 13C-2,3,7,8-TCDF 91.1 4 0 - 135 

OCD D 3.46 J 13C-l,2,3,7,8-PeCDF 85.2 4 0 - 135 

2,3,7,8-TCDF N D 0.595 13C-l,2,3,6,7,8-HxCDF 87.6 4 0 - 135 

1,2,3,7,8-PeCDF N D 0.670 13C-l,2s3,4,6,7,8-HpCDF 87.7 4 0 - 135 

2,3,4,7,8-PeCDF N D 0.708 13C-OCD F 81.1 4 0 - 135 

1,2,3,4,7,8-HxCDF N D 0.543 ES 37Cl-2,3,7,8-TCDD N A 70 - 130 H 

1,2,3,6,7,8-HxCDF N D 0.544 13C-2,3,4,7,8-PeCDF N A 70 - 130 H 

2,3,4,6,7,8-HxCDF N D 0.583 13C-l,2,3,4,7,8-HxCDD N A 70 - 130 H . 

1,2,3.7,8,9-HxCDF N D 0.595 13C-l,2,3,4,7,8-HxCDF 0.298 70 - 130 H 

1,2,3,4,6,7,8-HpCDF 0.600 .1 13C-l,2,3,4,7,8,9-HpCDF N A 70 - 130 H 

1,2,3,4,7,8,9-HpCDF N D 0.742 M 13C-l,2,3,7,8,9-HxCDF 91.1 4 0 - 135 

OCD F N D 0.886 

Totals Toxi c Equivalent Quotient (TEQ ) Data

 e 

Total TCD D 1.01 T E Q (Min-Max): 0.00946 - 2.05 

Total PeCD D N D 0.918 

Total HxCD D N D 5.96 a. Sample specific estimated detection limit 

Total HpCD D N D 1.11 b. Estimated maximum possible concentration. 

Total TCD F N D 0.595 c. Me.thod detection hmit. 

Total PeCD F N D 0.689 d. Lower control limit - upper control limit. 

Total HxCD F N D 0.566 0.701 e TEQ based on (1989) International Toxic Equivalent Factors (ITEF) 

Total HpCD F 0.600 

Approved By: William J. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 7 o f 18 

VES018637 
Sample ID: CPT-U3-M23A-XAD-R2 Method 0023A 

Clicill Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 2-Dec-09 

7'ime Collected: NJA 

Matrix: 

Sample Size: 

M M 5 

Sample 

Lab Sample: 32244-003 

QC Batch No.. 2603 

Date Analyzed DB-5: 9-Dec-09 

Date Received: 4-Dec-09 

Date Extracted: 8-Dec-09 

Dates Analyzed DB-225 10-Dec-09 

Analyt e Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD N D 3.01 IS 13C-2,3,7,8-TCDD 87.8 40 - 135 

1,2,3,7,8-PeCDD 16.2 J 13C-l,2,3,7,8-PeCDD 85.8 4 0 - 135 

1,2,3,4,7,8-HxCDD 16.0 J 13C-l,2,3,6,7,8-HxCDD 87.6 40 - 135 

1,2,3,6,7,8-HxCDD 38.7 J 13C-1,2,3,4,6,7,8-HpCDD 89.0 4 0 - 135 

1,2,3,7,8,9-HxCDD 26.1 J 13C-OCD D 81.7 4 0 - 135 

1,2,3,4,6,7,8-HpCDD 252 l3C-2,3,7.8-TCDF 90.1 4 0 - 135 

OCD D 327 13C-l,2,3,7,8-PeCDF 85.1 40 - 135 

2,3,7,8-TCDF 25.0 13C-l,2,3,6,7,8-HxCDF 87.9 40 - 135 

1,2,3,7,8-PeCDF 30.9 J 13C-l,2,3,4,6,7,8-HpCDF 91.6 40 - 135 

2,3,4,7,8-PeCDF 63.7 13C-OCDF 83.9 4 0 - 135 

1,2,3,4,7,8-HxCDF 42.4 J £ S 37Cl-2,3,7,8-TCDD 104 70 - 130 

1,2,3,6.7,8-HxCDF 38.4 T P 13C-2,3,4,7,8-PeCDF 105 70 - 130 

2,3,4,6,7,8-HxCDF 53.0 13C-l,2,3,4,7,8-HxCDD 108 70 - 130 

1.2,3,7,8,9-HxCDF 12.4 J 13C-l,2,3,4,7,8-HxCDF 103 70 - 130 

1,2,3.4,6,7,8-HpCDF 122 13C-l,2,3.4,7,8,9-HpCDF 105 7 0 - 130 

1.2,3.4,7.8,9-HpCDF 14.8 J M 13C-l,2,3,7,8,9-HxCDF 90.8 40 - 135 

OCD F 44.8 J 

Totals Toxi c Equivalent Quotient (TEQ ) Dat a

 e 

Total TCD D 2720 2730 T E Q (Min-Max): 71.0- 74.0 

Total PeCD D 1710 

Total HxCD D 4910 a. Sample specific estimated detection limit. 

Total HpCD D 627 b. Estimated maximum possible concentration. 

Total TCD F S52 e. Method detection limit 

Total PeCDF 705 709 P d. Lower control limit - upper control limit. 

Total HxCD F 425 P c. TEQ based on(l989) International Toxicmvalen Eq t Factors (ITEF). 

Total HpCD F ISO 

Approved By: William J. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 8 o f 18 

VES018638 
vista 

Sample ID: CPT-U3-M23A-PF-R2 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 2-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M 5 

Sample 

Lab Sample. 32244-004 

QC Batch No.: 2603 

Date Analyzed DB-5: 10-Dec-09 

Date Received: 

Date Extracted: 

Dale Analyzed DB-225: 

4-Dec-09 

8-Dec-09 

N A 

Analyt e Cone . (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d Qualifiers 

2,3,7,8-TCDD N D 0.592 i § 13C-2,3,7,8-TCDD 83.1 4 0 - 135 

1,2,3,7,8-PeCDD N D 0.841 I3C-1,2,3,7,8-PeCDD 84.0 4 0 - 135 

1,2,3,4,7,8-HxCDD N D 1.31 13C-l,2,3,6,7,8-HxCDD 83.8 40-13 5 

1,2,3,6,7,8-HxCDD N D 1.31 13C-1,2,3,4,6,7,8-HpCDD 80.1 4 0 - 135 

1,2,3,7,8,9-HxCDD N D 1.21 13C-OCD D 76.1 4 0 - 135 

1,2,3,4,6,7,8-HpCDD N D 1.24 13C-2,3,7,8-TCDF 81.8 4 0 - 135 

OCD D 3.31 J 13C-1,2,3,7,8-PeCDF 81.4 4 0 - 135 

2,3,7,8-TCDF N D 0.805 13C- 1,2,3,6,7,8-HxCDF 82.6 4 0 - 135 

1,2,3,7,8-PeCDF N D 0.857 13C- 1,2,3,4,6,7,8-HpCDF 84.6 40 - 135 

2,3,4,7,8-PeCDF N D 0.905 13C-OCDF 77.3 40 - 135 

1,2,3,4,7,8-HxCDF N D 0.754 P S 37CI-2,3,7,8-TCDD N A 70 - 130 H 

1,2,3,6,7,8-HxCDF N D 0.755 13C-2,3,4,7,8-PeCDF N A 70 - 130 H 

2,3,4,6,7,8-HxCDF N D 0.809 l3C-l,2,3,4,7,8-HxCDD N A 70 - 130 H 

1,2,3,7,8,9-HxCDF N D 0.826 13C-l,2,3,4,7,8-HxCDF N A 70 - 130 H 

1,2,3,4,6,7,8-HpCDF N D 0.761 l3C-l,2,3,4,7,8,9-HpCDF N A 70 - 130 H 

1.2,3,4.7,8,9-HpCDF N D 0.844 A S 13C-l,2,3,7,8,9-HxCDF 88.5 4 0 - 135 

OCD F N D 1.14 

Totals Toxi c Equivalent Quotient (TEQ ) Data

 e 

Total TCD D 0.968 T E Q (Min-Max): 0.00331 - 2.32 

Total PeCD D N D 0.841 

Total HxCD D 6.39 a. Sample specific estimated detection limit. 

Total HpCD D N D 1.24 b Estimated maximum possible concentration. 

Total TCD F N D 0.805 c. Method detection limit. 

Total PeCD F N D 0.881 d. Lower control limit - upper control limit. 

Total HxCD F N D 0.786 e TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCD F N D 0.802 

Approved By: William J. Luksemburg 17-Dec-2009 13:55 

Page 9 o f 18 

VES018639 
vista 

Sample ID: CPT-U3-M23A-XAD-R3 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 3-Dec-09 

Time Collected: 

Matrix: 

Sample Size. 

M M 5 

Sample 

Lab Sample: 32244-005 

QC Batch No.: 2603 

Date Analyzed DB-5 j 0-Dec-09 

Date Received: 4-Dec-09 

Date Extracted. 8-Dec-09 

Dates Analyzed DB-225: 10-Dec-09 

Analyt e Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD N D 3.86 I§ 13C-2,3,7,8-TCDD 82.0 40 - 135 

1,2,3,7,8-PeCDD 20.3 j 13C-l,2,3,7,8-PeCDD 79.9 40 - 135 

1,2,3,4,7,8-HxCDD 17.0 1 13C-l,2,3,6,7,8-HxCDD 82.1 40 - 135 

1,2,3,6,7,8-HxCDD 40.3 J !3C-l,2,3,4,6,7,8-HpCDD 79.0 40 - 135 

1,2,3,7,8,9-HxCDD 25.6 J 13C-OCD D 72.8 40-13 5 

1,2,3,4,6,7,8-HpCDD 268 13C-2,3,7,8-TCDF 83.0 40 - 135 

OCD D 339 13C-l,2,3,7,8-PeCDF 79.1 40 - 135 

2,3,7,8-TCDF 30.0 13C-l,2,3,6,7,8-HxCDF 81.7 40 - 135 

1,2,3,7,8-PeCDF 38.3 J 13C-l,2,3,4,6,7,8-HpCDF 81.2 40 - 135 

2,3.4.7.8-PeCDF 88.0 13C-OCDF 75.7 40 - 135 

1,2,3,4,7,8-HxCDF 50.7 ES 37CI-2,3,7,8-TCDD 99.4 70 - 130 

1,2,3,6,7,8-HxCDF 48.7 J 13C-2,3,4,7,8-PeCDF 101 70 - 130 

2,3,4,6,7,8-HxCDF 69.5 P 13C-l,2,3,4,7,8-HxCDD 101 70-13 0 

1,2,3,7,8,9-HxCDF 15.0 J 13C-l,2,3,4,7,8-HxCDF 98.3 70 - 130 

1.2,3,4,6,7.8-lIpCDF 126 13C-l,2,3,4,7,8,9-HpCDF 90.8 70 - 130 

1.2,3,4,7,8,9-HpCDF 14.4 J AS l3C-l,2,3,7,8,9-HxCDF S6.6 4 0 - 135 

OCD F 37.6 J 

Totals Toxi c Equivalent Quotient (TEQ ) Data

 e 

Total TCD D 4010 T E Q (Min-Max) : 90.2 - 94.0 

Total PeCD D 2090 

Total HxCD D 8060 a. Sample specific estimated detection limit. 

Total HpCD D 639 b. Estimated maximum possible concentration. 

Total TCD F 1240 c Melhod detection limitTotal PeCDF 1010 P d Lower control limit - upper control limit. 

Total HxCD F 547 P e TEQ based on (1989) International Toxic Equivalent Factors (1TEF). 

Total HpCD F 189 

Analyst: JM H ApprovedBy: William J. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 10 o f 18 

VES018640 
vista 

Sample ID: CPT-U3-M23A-PF-R3 Method 0023A 

Client Data S^moJe Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 3-Dec-09 

Time Collected. MA 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32244-006 

QC Batch No. 2603 

Date Analyzed DB-5: 10-Dec-09 

Date Received: 

Date Extracted 

Date Analyzed DB-225 

4-Dec-09 

8-Dec-09 

N A 

Analyt e Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d Qualifiers 

2,3,7,8-TCDD N D 0.738 IS 13C-2,3,7,8-TCDD 79.1 4 0 - 135 

1,2,3,7,8-PeCDD N D 1.14 13C-l,2,3,7,8-PeCDD 76.9 4 0 - 135 

1,2,3,4,7,8-HxCDD N D 1.13 13C-l,2,3,6,7,8-HxCDD 79.3 4 0 - 135 

1,2,3,6,7,8-HxCDD N D 1.14 13C-1,2,3,4,6,7,8-HpCDD 75.0 4 0 - 135 

1,2,3,7,8,9-HxCDD N D 1.05 13C-OCD D 72.1 4 0 - 135 

1,2,3,4,6,7,8-HpCDD 3.54 J 13C-2,3,7,8-TCDF 79.1 4 0 - 135 

OCD D 8.98 J !3C-l,2,3,7,8-PeCDF 75.5 4 0 - 135 

2,3,7,8-TCDF N D 0.850 13C-1,2,3,6,7,8-HxCDF 78.8 4 0 - 135 

1,2,3,7,8-PeCDF N D 0.907 13C-l,2,3,4,6,7,8-HpCDF 78.0 4 0 - 135 

2,3,4,7,8-PeCDF N D 0.958 13C-OCDF 73.9 40 - 135 

1,2,3,4,7,8-HxCDF N D 0.844 £ S 37Cl-2,3,7,8-TCDD N A 70 - 130 H 

1,2,3,6,7,8-HxCDF 1.12 .1 13C-2,3,4,7,8-PeCDF N A 70 - 130 H 

2,3,4,6,7,8-HxCDF 1.56 .1 13C-l,2,3,4,7,8-HxCDD N A 7 0 - 130 H 

1.2,3,7.8,9-HxCDF N D 0.820 13C-l,2,3,4,7,8-HxCDF N A 70 - 130 H 

1,2,3,4,6,7,8-HpCDF 4.96 J 13C-l,2,3,4,7,8,9-HpCDF N A 7 0 - 130 H 

1.2.3.4,7,8,9-HpCDF N D 1.26 A S 13C-1,2,3,7,8,9-H\CDF 81.2 4 0 - 135 

OCD F N D 2.56 

Totals Toxi c Equivalent Quotient (TEQ ) Dat a

 e 

Total TCD D N D 1.28 T E Q (Min-Max): 0.362 - 2.79 

Total PeCD D N D 1.14 

Total HxCD D 10.7 a. Sample specific estimated detection limit. 

Total HpCD D 3.54 6.64 b. Estimated maximum possible concentration 

Total TCD F N D 1.75 c. Method detection limit. 

Total PeCD F N D 0.932 d Lower control limit - upper control limit. 

Total HxCD F 4.95 9.53 e TEQ based on (1989) International Toxic Equivalent Factors (ITEF) 

Total HpCD F 4.96 

Approved By: William J. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 11 of 18 

VES018641 
vista 

Sample ID: CPT-U3-M23A-FB Merhod 0023A 

Client Data Sample Data Laboratocv Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 3-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32244-007 

QC Batch No.: 2603 

Date Analyzed DB-5. 9-Dec-09 

Date Received. 4-Dec-09 

Date Extracted: 8-Dec-09 

Date Analyzed DB-225: \JA 

Analyt e Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD N D 0.855 IS 13C-2,3,7,8-TCDD 86.0 4 0 - 135 

1,2,3,7,8-PeCDD N D 1.11 13C-l,2,3,7,8-PeCDD 84.3 40 - 135 

1,2,3,4,7,8-HxCDD N D 0.975 13C-l,2,3,6,7,8-HxCDD 85.1 4 0 - 135 

1,2,3,6,7,8-HxCDD N D 0.979 13C-1,2,3,4,6,7,8-HpCDD 83.0 4 0 - 135 

1,2,3,7,8,9-HxCDD N D 0.900 13C-OCD D 78.1 4 0 - 135 

1,2,3,4,6,7,8-HpCDD 3.28 J 13C-2,3,7,8-TCDF 85.6 4 0 - 135 

OCD D 11.6 1 13C-l,2,3,7,8-PeCDF 80.9 40 - 135 

2,3,7,8-TCDF N D 0.817 13C-1,2,3,6,7,8-HxCDF 85.4 4 0 - 135 

1,2,3,7,8-PeCDF 0.997 1 13C- 1,2,3,4,6,7,8-HpCDF 83.7 4 0 - 135 

2,3,4,7,8-PeCDF 2.00 J 13C-OCDF 79.9 4 0 - 135 

1,2,3,4,7,8-HxCDF 1.94 1 £ S 37CI-2,3,7,8-TCDD 104 7 0 - 130 

1,2,3,6,7,8-HxCDF N D 0.925 13C-2,3,4,7,8-PeCDF 109 70 - 130 

2,3,4,6,7,8-HxCDF N D 1.19 13C-l,2,3,4,7,8-HxCDD 111 7 0 - 130 

1,2,3,7,8,9-HxCDF N D 0.659 !3C-l,2,3,4,7,8-HxCDF 107 70 - 130 

1,2,3,4,6,7,8-HpCDF 3.74 J 13C-l,2,3,4,7,8,9-HpCDF 109 7 0 - 130 

1,2,3,4,7.8,9-HpCDF N D 0.958 A S 13C-l,2,3,7,8,9-HxCDF 92.8 4 0 - 135 

OCD F 1.95 J 

Totals Toxi c Equivalent Quotient (TEQ ) Data

 e 

Total TCD D 2.48 T E Q (Min-Max): 1.33 - 3.39 

Total PeCD D N D 1.36 

Total HxCD D 3.79 a. Sample specific estimated detection limit. 

Total HpCD D 6.15 b. Estimated maximum possible concentration. 

Total TCD F 24.6 27.8 c Method detection limit 

Total PeCDF 14.0 19.0 d: Lower control limit- upper control limit. 

Total HxCD F 9.42 11.5 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCD F 3.74 

Approved By: William S. Luksemburg 17-Dec-2009 13:55 

Project 32244 Page 12 o f 18 

VES018642 
APPENDIX 

rojccl 32244 Page 13 of IK 

VES018643 
DATA QUALIFIERS & ABBREVIATIONS 

B This compound was also detected in the method blank. 

D Dilution 

E The amount detected is above the High Calibration Limit. 

P The amount reported is the maximum possible concentration due to possible 

chlorinated diphenylether interference. 

H Recovery was outside laboratory acceptance limits. 

I Chemical Interference 

J The amount detected is below the Low Calibration Limit. 

* See Cover Letter 

Cone. Concentration 

DL Sample-specific estimated detection limit 

MDL The minimum concentration of a substance that can be measured and 

reported with 99% confidence that the analyte concentration is greater 

than zero in the matrix tested. 

EMPC Estimated Maximum Possible Concentration 

NA Not applicable 

RL Reporting Limit - concentrations that correspond to low calibration point 

ND Not Detected 

TEQ Toxic Equivalency 

Unless otherwise noted, solid sample results are reported in dry weight. Tissue samples are reported 

in wet weight. 

Project 32244 Pane N of IX 

VES018644 
Vista 

CERTIFICATIONS 

Accrediting Authority Certificate Number 

State of Alaska, DEC CA413-2008 

State of Arizona AZ0639 

State of Arkansas, DEQ 08-043-0 

State of Arkansas, DOH Reciprocity through CA 

State of California - NELAP Primary AA 02102CA 

State of Colorado N/A 

State of Connecticut PH-0182 

State of Florida, DEP E87777 

State of Indiana Department of Health C-CA-02 

Commonwealth.of Kentucky 90063 

State of Louisiana, Health and Hospitals LA08000 

State of Louisiana, DEQ 01977 

State of Maine 2008024 

State of Michigan 9932 

State of Mississippi Reciprocity through CA 

Naval Facilities Engineering Service Center NFESC413 

State of Nevada CA004132007A 

State of New Jersey CA003 

State of New Mexico Reciprocity through CA 

State of New York, DOH 11411 

State of North Carolina 06700 

State of North Dakota, DOH R-078 

State of Oklahoma D9919 

State of Oregon CA200001-006 

State of Pennsylvania 68-00490 

State of South Carolina 87002001 

State of Tennessee TN02996 

State of Texas T104704189-08-TX 

U.S. Army Corps of Engineers N/A 

State of Utah CA16400 

Commonwealth of Virginia 00013 

State of Washington C1285 

State of Wisconsin 998036160 

State of Wyoming 8TMS-Q 

Project 32244 Page 15 of IX 

VES018645 
Sample Traceabiiity List Q ^ ^fafr^ f 

AECOM 

Site of Program: Veolia ES Tech Sample Date: YL ~i\T IZ./R/OI Project Location: Sauget, IL Lab PO #': 

Type of Program: CPT Date Shipped: \'2.^a/oc

i Laboratory: Vista Analytical 

Project #: . 60133216 Shipper/ Steven Milo El Dorado Hills, CA 

Recovery: Jeff Gorman 

Laboratory: Vista Analytical 

El Dorado Hills, CA 

Program Office: Syracuse NY 

Shipper/ Steven Milo 

Recovery: Jeff Gorman 

Laboratory: Vista Analytical 

El Dorado Hills, CA 

Program Contact: Jeff Gorman FedEx Air Bill #: 

Hem Sample ID Code Sample Matrix Sample Description Analytical Parameters Special Instructions 

1 CPT-U3-M23A-XAD-R1 XAD2 RESIN M23 XAD Resin Trap, Run 1 PCDDs/PCDFs EPA 0023A 

2 CPT-U3-M23A-PF-R1 FILTER M23 PM Filter, Run 1 PCDDs/PCDFs EPA 0023A 

3 

4 CPT-U3-M23A-XAD-R2 XAD2 RESIN M23 XAD Resin Trap, Run 2 PCDDs/PCDFs EPA 0023A 

5 CPT-U3-M23A-PF-R2 FILTER M23 PM Filter, Run 2 PCDDs/PCDFs EPA 0023A 

6 

7 CPT-U3-M23A-XAD-R3 XAD2 RESIN M23 XAD Resin Trap, Run 3 PCDDs/PCDFs 

8 CPT-U3-M23A-PF-R3 FILTER M23 PM Filter, Run 3 PCDDs/PCDFs 

9 

10 CPT-M23A-PF-FB FILTER Particulate Filter Field Blank PCDDs/PCDFs EPA 0023A 

11 CPT-M23A-XAD-FB XAD2 RESIN Xad Resin Trap Field Blank PCDDs/PCDFs EPA 0023A 

12 CPT-M23A Field Blank AcetonG/MeClaToluens M23 Blank PCDDs/PCDFs EPA0023A 

13 

14 CPT-U3-M23A-FHR-R1 Acetone/MeClz/Toluene M23A Front Half Rinse, Run 1 PCDDs/PCDFs EPA 0023A 

15 CPT-U3-M23A-FHR-R2 Acetone/MeCl2/Toluen9 M23A Front Half Rinse, Run 2 PCDDs/PCDFs EPA 0023A 

16 CPT-U3-M23A-FHR-R3 Acetone/MeClyToluene M23A Front Half Rinse, Run 3 PCDDs/PCDFs EPA 0023A 

17 

18 CPT-U3-M23A-BHR-R1 Acetone/MeClj/Toluene M23A Back Half Rinse, Run 1 PCDDs/PCDFs EPA 0023A 

19 CPT-U3-M23A-BHR-R2 Acetone/MeClyToluene M23A Back Half Rinse, Run 2 PCDDs/PCDFs EPA 0023A 

20 CPT-U3-M23A-BHR-R3 Acelone/MeClyToluene M23A Back Half Rinse, Run 3 PCDDs/PCDFs EPA 0023A 

Field Notes/ Comments 

Page 1 of 1 

Relinquished By (print): Date: 

Steven Milo /2/

3

/^7' 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

Received by Lab (print): Date: 

Signature: Time: 

Received By (print): ' . Date: 

Sianature: ( Tirrie: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Receive Analytical Laboratory Destination: d By (print): ' . Date: 

Sianature: ( Tirrie: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Vista Analytical Laboratories, Inc. 

1104 Windfield Way 

El Dorado Hills, CA 96762 

Attn: Ms.Martha Maier 916-673-1520. 

Project 32244 Page 16 of 18 

VES018646 
Vista Project #: 

SAMPL E LOG-IN CHECKLIS T V Vist a 

• Analytical Laboratory 

TAT Uns>pec 

Samples Arrival: 

Date/Time Initials: Location: (jj^pShelf/Rack: N (Ac 

Logged In: 

Date/Time 

ID?? 

Initials: Location: ^ 

Shelf/Rack: R / 

Delivered By: /^FedEx N 

, C J UPS Cal DHL * a n d

 Other Delivered 

Preservation: Ice Blue Ice Dry.Ice c(^None,J) 

Temp°C AvTlbl-eVlk Time: Q&^J - Thermometer ID: IR-1 

YES ^ NO NA 

Adequate Sample Volume Received? \/ 

Holding Time Acceptable? l / 

Shipping Container(s) Intact? 1 / 

Shipping Custody Seals Intact? 

Shipping Documentation Present? 

Airbill Trk#fl£>%><5ai2 - ^fcff i y 

Sample Container Intact? 

Sample Custody Seals Intact? 

Chain of Custody / Sample Documentation Present? 

C O C Anomaly/Sample Acceptance Form completed? 

If Chlorinated or Drinking Water Samples, Acceptable Preservation? A 

N a 2 S 2 0 3 Preservation Documented? 

Shipping Container Vista j^client^ ) Retain Return ^ ^SisposeN. 

Kb 

Sample Login 3/200? rml\ 

Project 32244 Page 17 of 18 

VES018647 
SAMPL E LOG-IN CHECKLIS T 

Vista Project #: TAT 

V Vista 

w Analytical Laboratory 

Samples Arrival: 

Date/Time Initials: Location: 

Shelf/Rack: M \fK 

Logged In: 

Date/Time Initials: 

Location: ^ j 

Shelf/Rack: H (t\ 

Delivered By: f

r

edEx J UPS Cal DHL _ ^. a n d

 . Other Delivered 

Preservation: V

*

i5*""e:""k:e ^_B!ue Ice^) Dry Ice None 

Temp °C 0°C Time: 0^t>>~. Thermometer ID: IR-1 

YES- NO NA 

Adequate Sample Volume Received? 

Holding Time Acceptable? V 

Shipping Container(s) Intact? 

Shipping Custody Seals Intact? 

Shipping Documentation Present? 

Airbill Trk# 5 ^ & VV^ ? 

Sample Container Intact? '=D&„eJ\~)€l 0U_-> 

Sample Custody Seals Intact? 

Chain of Custody / Sample Documentation Present? 

C O C Anomaly/Sample Acceptance Form completed? 

If Chlorinated or Drinking Water Samples, Acceptable Preservation? 

Na2S2 03 Preservation Documented? C OC r

Sam Pl e

 . (^None J Container W-.J-S- ^ 

Shipping Container Vista Client Retain Return Dispose 

Comments: 

f!3 v 4/ 

Project 32244 

mpk L<k>" iuOOTrmh ( j 

Page IK o f 18 

VES018648 
Waste Feed 

VES018649 
1 

TestAmerica 

THE LEADER IN ENVIRONMENTAL TESTING 

TestAmerica Laboratories,Inc 

ANALYTICAL REPORT 

PROJECT NO. 60133216 

Veoli a - ES Tech 

Lot #: H9L090423 

i 

Jeff Gorman 

AECOM, Inc 

5105 Campuswood Drive 

Suit e 104 

East Syracuse, NY 13057 

TESTAMERICA LABORATORIES, INC. 

Kevin S. Woodcock 

Project Manager 

December 28, 2009 

5815 Middlebrook Pike Knoxville, TN 37921 tel 865.2913000 fax 865.584.4315 www.testarnericaincxom 

VES018650 
ANALYTICAL METHODS SUMMARY 

H9L090423 

PARAMETER 

ANALYTICAL 

METHOD 

Ash Content 

Heat of Combustion 

Heat of Combustion D5865 

Total Chlorine 

References: 

ASTM Annual Book Of ASTM Standards. 

ASTM D482-00a 

ASTM D240-02 

ASTM D5865-00 

KNOX WC-0016 

KNOX TestAmerica Laboratories Inc., Knoxville Laboratory Standard 

Operating Procedure 
3 

SAMPLE SUMMARY 

H9L090423 

SAMPLED SAMP 

WO # SAMPLE* CLIENT SAMPLE ID DATE 

LQQM7 001 HBTU-U3-M2S-R1 12/01/09 

LQQNH 002 HBTU-U3-M26-R2 12/02/09 

LQQNJ 003 HBTU-U3-M26-R3 12/03/09 

LQQNL 004 LBTTJ-U3-M26-R1 12/01/09 

LQQNN 005 LBTU-03-M26-R2 12/02/09 

LQQNP 006 LBTU-U3-M26-R3 12/03/09 

LQQNT 0.07 SF-U3-M26A-R1 12/01/09 

LQQNO 008 SF-U3-M26A-R2 12/02/09 

LQQN2 009 SF-U3-M26A-R3 12/03/09 

LQQH4 010 CS-U3-M2SA-R1 12/01/09 

LQQQR O i l CS-U3-M26A-R2 12/02/09 

LQQQW 012 CS-U3-M26A-R3 12/03/09 

LQQQ7 013 HBTU-U3-M23A-R1 12/01/09 

LQQRM 014 HBTU-U3-M23A-R2 12/02/09 

LQQRO 015 HBTU-U3-M23A-R3 12/03/09 

LQQRS 016 LBT0-U3-M23A-R1 12/01/09 

LQQR7 017 LBTU-U3-M23A-R2 12/02/09 

LQQR8 018 LBTU-U3-M23A-R3 12/03/09 

LQQTA 019 SF-U3-M23A-R1 12/01/09 

LQQTG 020 SF-U3-M23A-R2 12/02/09 

LQQTD 021 SF-U3-M23A-R3 12/03/09 

LQQTE 022 CS-U3-M23A-R1 12/01/09 

LQQTF 023 CS-U3-M23A-R2 12/02/09 

LQQTG 024 CS-U3-M23A-R3 12/03/09 

HOTE(S) 

- The anaiyiicai rcsulis of (be samples listed above arc presented on inc following pages. 

- All calculations are performed before roundins 10 avoid round-off errors in calculated results. 

- Results noted as "ND" were not delected at or above the stated limit. 

- This report must not be reproduced, except in full, without the written approval of the laboratory. 

- Results for the rollowins parameters arc never reported on a dry weight basis: color, corrosiviiy, density, Jlaslipoiiii, isniiabllliy. layers, odor, 

paint filler test, pll, porosity pressure, reactivity, redox potential, specific gravity, spot lests, solids, solubiliiy. temperature, viscosity, and weight. 

VES018652 
4 

PROJECT NARRATIVE 

H9L090423 

The results reported herein are applicable to the samples submitted for analysis only. 

This report shall not be reproduced except in full, without the written approval ofthe 

laboratory. 

The original chain of custody documentation is included with this report. 

Sample Receipt 

There were no problems with the condition of the samples received. 

Quality Control and Data Interpretation 

Unless otherwise noted, all holding times and QC criteria were met and the test results 

shown in this report meet all applicable NELAC requirements. 

Ash Content: 

The ash content of the samples was determined using SOP number KNOX-WC-0013 

(based on ASTM Methods A4422, D482, and E830). A ten gram aliquot of sample is 

fired in a pre-tared crucible at 750° ± 25° C in a forced-draft muffle furnace. The total 

weight of ash residue and the crucible is measured on a4-place analytical balance, and 

the residue weight is determined by difference. The ratio of the residue weight (mg) and 

the initial sample weight (kg) is used to calculate the ash content ofthe sample. 

The duplicate RPD result for sample SF-U3-M23A-R3 is outside control limits. The 

laboratory control sample showed acceptable results indicating that the analysis was in 

control. The duplicate result is attributed to sample heterogeneity. 

Gross Calorific Value: 

The heat of combustion (gross calorific value) of the samples was determined using SOP 

number KNOX-WC-0010 (based on ASTM Method D5865 for solids and ASTM Method 

TesiAmerica Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Lab #88-

0688, California DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Lab #PH-0223, Florida DOH Lab 

#E87177, Georgia DNR Lab #906, Hawaii DOH, Illinois EPA Lab #200012, Indiana DOH Lab SC-TN-02, Iowa DNR 

Lab #375, Kansas DHE Cert #E-10349, Kentucky DEP Lab #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH, 

Maryland DOE Cert. #277, Michigan DEQ Lab #9933. Nevada DEP, New Jersey DEP Lab #TN001, New York DOH 

Lab #10781, North Carolina DPH Lab #21705, North Carolina DEHNR Cert. #64, Ohio EPA VAP Lab #CL0059, 

Oklahoma DEQ Lab #9415, Pennsylvania DEP Lab #68-00576, South Carolina DHEC Cert #84001001, Tennessee 

DOH Lab #02014, Texas CEQ, Utah DOH Lab # QUAN3, Virginia DGS Lab #00165, Washington DOE Lab #C1314, 

West Virginia DEP Cert. #345, West Virginia DHHR Cert #9955C, Wisconsin DNR Lab #998044300, Naval Facilities 

Engineering Service Center and USDA Soil Permii #S-46424. This list ofapprovals is subject to change and does not 

imply that laboratory certification is available for all parameters reported in this environmental sample data report. 

VES018653 
5 

PROJECT NARRATIVE 

H9L090423 

D240 for liquids). A waste feed sample is combusted in an oxygen bomb that has been 

placed in a bomb calorimeter. The energy released during this combustion process is 

captured in the calorimeter, and the temperature rise of a water bath surrounding the 

bomb is measured. The temperature rise is proportional to the heat liberated during the 

combustion in calories. The gross calorific value is calculated ftom the temperature rise, 

the sample weight, and the calibration coefficient of the calorimeter. Certain extraneous 

sources of heat are assessed, and the effect of these heat sources is accounted for in the 

calculation, as well as the affect of various accelerants that are added to enhance 

combustion ofthe sample. The gross heat of combustion is calculated in units of cal/g 

using the following equation: 

Q(gross ) = [(AtEE)-(e,4-e 2 4-e 3 + e 4 )] 

m 

Where: 

Q (gross) = gross calorific value at constant volume as determined, cal/g. 

EE = the heat capacity of the calorimeter, cal/°C. 

At = corrected temperature rise as measured by the calorimeter, °C. 

e i = Correction for heat of formation of nitric acid in calories, calculated by 

the calorimeter based on the energy released by the sample. 

62 = Correction for sulfur, which is usually 0. 

e3 = Correction for fuse wire. 

e4 = Correction for spike addition mat is calculated by me calorimeter using 

the spike weight benzoic acid equivalent (grams) times the benzoic 

acid heat of combustion (6318 cal/gram). 

m = mass of the sample, g. 

The results are converted to Btu/lb, as necessary using the following conversion factor: 

1 Btu/lb = 1.8 cal/gram 

Total Chlorine: 

The samples were prepared for total chlorine using SOP number KNOX-WC-0016 (based 

on ASTM Method E442 and SW-846 Method 5050). The sample is oxidized by 

combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen 

under pressure. The liberated halogen compounds are absorbed primarily as halides in a 

sodium carbonate/sodium bicarbonate buffer solution. The combustion products are 

collected by repeated rinsing ofthe combustion apparatus, and analyzed by ion 

chromatography in accordance with SOP KNOX-WC-0005 (based on SW-846 Method 

9056). The results are calculated using the following equation: 

VES018654 
7 

QC DATA ASSOCIATION SUMMARY 

H9L090423 

Sample Preparation and Analysis Control Numbers 

SAMPLE* 

001 

002 

003 

004 

005 

006 

007 

008 

00S 

010 

011 

ANALYTICAL 

MATRIX METHOD 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE . KNOX WC-0016 

WASTE ASTM D24Q-02 

WASTE ASTM D4 82-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE' ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM 0482-OOa 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

SOLID ASTM D482~00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-0Q 

LEACH 

BATCH 

PREP 

BATCH ft 

9351497 

9344060 

9348075 

9351497 

9344060 

9348075 

9351497 

9344060 

9348075 

9351497 

9344060 

9348075 

9351497 

9344060 

9348075 

9351497 

9344060 

9348075 

9351497 

9345064 

9348075 

9351497 

9345064 

9348075 

9351497 

9345064 

9348075 

9345461 

9344060 

9350032 

9345461 

9344060 

9350032 

MS RUNS 

9351302 

9344027 

9348043 

9345036 

9345279 

9344027 

9350020 

{Continued on next page) 

VES018656 
QC DATA ASSOCIATION SUMMARY 

H9L090423. 

Sample Preparation and analysis Control Numbers 

SAMPLE* MATRIX 

ANALYTICAL 

METHOD 

LEACH 

BATCH # 

PREP 

BATCH MS RONS 

012 SOLID 

SOLID 

SOLID 

ASTM D482-O0a 

KNOX WC-0016 

ASTM D5865-00 

9345461 

9344060 

9350032 

013 WASTE 

WASTE 

WASTE 

ASTM D482-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

014 WASTE 

WASTE 

WASTE 

ASTM D482-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

015 WASTE 

WASTE 

WASTE 

ASTM D482-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 9348043 

016 WASTE 

WASTE 

WASTE 

ASTM D4B2-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

017 WASTE 

WASTE 

WASTE 

ASTM D482-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

018 WASTE 

WASTE 

WASTE. 

ASTM D482-0Oa 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

019 WASTE 

WASTE 

WASTE 

ASTM D482-00a 

KNOX WC-0016. 

ASTM D240-02 

9351497 

9345064 

9348075 

020 WASTE 

WASTE 

WASTE 

ASTM D482-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

9345036 

021 WASTE 

WASTE 

WASTE 

ASTM D4B2-00a 

KNOX WC-0016 

ASTM D240-02 

9351497 

9345064 

9348075 

9351302 

022 SOLID 

SOLID 

SOLID 

ASTM D482-00a 

KNOX WC-0016 

ASTM D5865-00 

9345461 

9344060 

9350032 

(Continued on next page) 
9 

QC DATA ASSOCIATION SUMMARY 

H9L09.0423 

Sample Preparation and Analysis Control Numbers 

SAMPLES MATRIX 

ANALYTICAL 

METHOD 

LEACH 

BATCH it 

PREP 

BATCH » 

023 SOLID 

SOLID 

SOLID 

ASTM D482-00a 

KNOX WC-0016 

. ASTM D5865-00 

9345461 

9344060 

9350032 

024 SOLID 

SOLID 

SOLID 

ASTM D482-00a 

KNOX WC-0016. 

ASTM D5865-00' 

9345461 

9344060 

9350032 

VES018658