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TS-DL12Y4 GPC Data.doc

2

Based on the 11 narrow standards of PMMA, MMA and 1-Phenylhexane, a 4th order calibration curve 

and one equation were generated by the software. Figure 1 shows the calibration curve, and the raw 

data and the calibration equation were also listed. Sample chromatogram and the results are shown in 

Figure 2. Table 2 lists slice data for Amix 1000 product.

Log Mol Wt

2.00

2.50

3.00

3.50

4.00

4.50

5.00

5.50

6.00

Retention Time

12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50

Retention Time Mol Wt Log Mol Wt

12.49 1916000 6.28

13.11 625500 5.80

14.26 138600 5.14

15.00 52550 4.72

15.55 27600 4.44

16.30 10290 4.01

16.90 5000 3.70

17.41 2810 3.45

18.49 645 2.81

19.28 162 2.21

19.86 100 2.00

Calibration Method: System 3_Plgel_THFN_102814_PMMA

y = 0.00150696x4- 0.10100046x3 + 2.51549408x2- 28.14848748x + 125.55486179

R2 = 0.99932510

Figure 1. The calibration curve of the standards, the raw data and the calibration equation.
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TS-DL12Y4 GPC Data.doc

3 MV

0.00

50.00

100.00

150.00

200.00

250.00

300.00

Minutes

15.00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 20.00 20.50

Label Sample Name Mn Mw MP Mz Mz+1 Polydispersity Mz/Mw Mz+1/Mw

U10271430 33264R38(01) Amix 1000 218 336 187 539 786 1.54 1.60 2.34

Figure 2. The GPC chromatogram of TS-DL12Y4 Amix 1000 & Fatty acids product and the 

average molecular weight.

Table 2. Slice Data for TS-DL12Y4 (FA & Amix 1000 product)

Slice No. Slice MW Slice Log MW Slice EV Slice Area Cumulative %

1 2898 3.46 17.33 0 0

2 2833 3.45 17.35 68 0

3 2770 3.44 17.37 149 0

4 2708 3.43 17.38 250 0

5 2647 3.42 17.40 355 0

6 2588 3.41 17.42 474 0

7 2530 3.40 17.43 607 0

8 2473 3.39 17.45 749 0

9 2417 3.38 17.47 929 0

10 2363 3.37 17.48 1128 0

11 2309 3.36 17.50 1350 0

12 2257 3.35 17.52 1586 0

13 2206 3.34 17.53 1855 0

14 2156 3.33 17.55 2161 0

15 2107 3.32 17.57 2501 0

16 2060 3.31 17.58 2868 0

17 2013 3.30 17.60 3282 0

18 1967 3.29 17.62 3733 0

19 1922 3.28 17.63 4222 0

20 1879 3.27 17.65 4762 0

21 1836 3.26 17.67 5354 0

22 1794 3.25 17.68 6012 0

23 1753 3.24 17.70 6716 0

24 1713 3.23 17.72 7481 0
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Slice No. Slice MW Slice Log MW Slice EV Slice Area Cumulative %

25 1674 3.22 17.73 8302 0

26 1636 3.21 17.75 9189 0

27 1598 3.20 17.77 10155 0

28 1562 3.19 17.78 11210 0

29 1526 3.18 17.80 12345 0

30 1491 3.17 17.82 13569 0

31 1457 3.16 17.83 14891 1

32 1423 3.15 17.85 16311 1

33 1391 3.14 17.87 17825 1

34 1359 3.13 17.88 19452 1

35 1327 3.12 17.90 21195 1

36 1297 3.11 17.92 23056 1

37 1267 3.10 17.93 25038 1

38 1238 3.09 17.95 27137 1

39 1209 3.08 17.97 29357 1

40 1181 3.07 17.98 31733 1

41 1154 3.06 18.00 34262 1

42 1127 3.05 18.02 36970 2

43 1101 3.04 18.03 39865 2

44 1076 3.03 18.05 42980 2

45 1051 3.02 18.07 46347 2

46 1027 3.01 18.08 50000 2

47 1003 3.00 18.10 53977 2

48 980 2.99 18.12 58294 3

49 957 2.98 18.13 62996 3

50 935 2.97 18.15 68100 3

51 913 2.96 18.17 73607 3

52 892 2.95 18.18 79512 4

53 871 2.94 18.20 85805 4

54 851 2.93 18.22 92440 4

55 831 2.92 18.23 99355 5

56 812 2.91 18.25 106491 5

57 793 2.90 18.27 113753 6

58 775 2.89 18.28 121057 6

59 757 2.88 18.30 128282 6

60 739 2.87 18.32 135366 7

61 722 2.86 18.33 142212 7

62 705 2.85 18.35 148720 8

63 689 2.84 18.37 154849 9

64 673 2.83 18.38 160562 9

65 657 2.82 18.40 165825 10

66 642 2.81 18.42 170616 10

67 627 2.80 18.43 174938 11

68 613 2.79 18.45 178798 12

69 598 2.78 18.47 182226 12

70 585 2.77 18.48 185243 13

71 571 2.76 18.50 187875 14

72 558 2.75 18.52 190148 14

73 545 2.74 18.53 192073 15

74 532 2.73 18.55 193662 16
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5

Slice No. Slice MW Slice Log MW Slice EV Slice Area Cumulative %

75 520 2.72 18.57 194933 17

76 508 2.71 18.58 195876 17

77 496 2.70 18.60 196500 18

78 485 2.69 18.62 196802 19

79 473 2.68 18.63 196785 19

80 462 2.67 18.65 196465 20

81 452 2.65 18.67 195844 21

82 441 2.64 18.68 194924 22

83 431 2.63 18.70 193756 22

84 421 2.62 18.72 192354 23

85 411 2.61 18.73 190755 24

86 402 2.60 18.75 189025 24

87 393 2.59 18.77 187183 25

88 384 2.58 18.78 185322 26

89 375 2.57 18.80 183508 26

90 366 2.56 18.82 181801 27

91 358 2.55 18.83 180320 28

92 350 2.54 18.85 179138 28

93 342 2.53 18.87 178353 29

94 334 2.52 18.88 178070 30

95 326 2.51 18.90 178390 30

96 319 2.50 18.92 179403 31

97 311 2.49 18.93 181198 32

98 304 2.48 18.95 183859 32

99 297 2.47 18.97 187451 33

100 291 2.46 18.98 192012 34

101 284 2.45 19.00 197547 35

102 278 2.44 19.02 204028 35

103 271 2.43 19.03 211402 36

104 265 2.42 19.05 219549 37

105 259 2.41 19.07 228351 38

106 253 2.40 19.08 237626 39

107 248 2.39 19.10 247163 40

108 242 2.38 19.12 256742 40

109 237 2.37 19.13 266134 41

110 231 2.36 19.15 275118 42

111 226 2.35 19.17 283508 44

112 221 2.34 19.18 291126 45

113 216 2.33 19.20 297831 46

114 211 2.33 19.22 303539 47

115 207 2.32 19.23 308217 48

116 202 2.31 19.25 311861 49

117 198 2.30 19.27 314489 50

118 193 2.29 19.28 316158 51

119 189 2.28 19.30 316927 53

120 185 2.27 19.32 316869 54

121 181 2.26 19.33 316061 55

122 177 2.25 19.35 314598 56

123 173 2.24 19.37 312554 57
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Slice No. Slice MW Slice Log MW Slice EV Slice Area Cumulative %

124 169 2.23 19.38 309968 58

125 165 2.22 19.40 306923 59

126 162 2.21 19.42 303471 61

127 158 2.20 19.43 299653 62

128 155 2.19 19.45 295508 63

129 152 2.18 19.47 291087 64

130 148 2.17 19.48 286398 65

131 145 2.16 19.50 281481 66

132 142 2.15 19.52 276385 67

133 139 2.14 19.53 271117 68

134 136 2.13 19.55 265708 69

135 133 2.12 19.57 260168 70

136 130 2.12 19.58 254515 71

137 128 2.11 19.60 248774 72

138 125 2.10 19.62 242963 73

139 122 2.09 19.63 237090 74

140 120 2.08 19.65 231194 74

141 117 2.07 19.67 225275 75

142 115 2.06 19.68 219323 76

143 112 2.05 19.70 213385 77

144 110 2.04 19.72 207475 78

145 108 2.03 19.73 201589 78

146 106 2.02 19.75 195745 79

147 103 2.01 19.77 189952 80

148 101 2.01 19.78 184220 80

149 99 2.00 19.80 178563 81

150 97 1.99 19.82 172990 82

151 95 1.98 19.83 167506 82

152 93 1.97 19.85 162116 83