# AECOM

Appendix C Referenc e Metho d Calibrations , Verifications , an d Certification s



# VES01854 3

# AZCOM
Calibrator

. Mik e O'tool e Referenc e Thermometer

. SYR-CAL- 1 

## Filte rBo xCalibratio n Ho t Bo x# 5 HotBox#8 D Manufacturer

: Seria l No. : Dat e received/place

d i n servi c 

## Anderso

n NUTEC H N/ A Pr e 199 5 

## Manufacturer : Seria l No. : ' Dat e received/place

d i n servic * 

## Anderso

n NUTECH N/ A Pr e 199 5 

## Calibratio n Date : 8-Jan-0 9 Calibratio n Date : 8-Jan-0 9 Ambien t Ho t Ambien t Ho

t Referenc e Temperature

s 6

7 25

0 Referenc

e Temperature

s 6

9 25

0 Actua l Temperature

s 6

6 24

9 Actua

l Temperature

s 6

9 24

9 Tem p Differenc

e (tol . = +-2 ) 1 1 Tem p Differenc

e (tol . = +-2 ) 0 1 

## Ho t Bo x# 6 Ho t Bo x# 9 Manufacturer

: Anderso

n NUTEC H Manufacturer : Anderso

n NUTECH Seria l No. : N/ A Seria l No. : N/ A Dat e received/place

d i n servi c Pr e 199 5 Dat

e received/place

d i n servi a Pr e 199 5 

## Calibratio n Date : 8-Jan-0 9 Calibratio n Date : 8-Jan-0 9 Ambien t Ho t Ambien t Ho

t Referenc e Temperature

s 6

9 25

0 Referenc

e Temperature

s 6

8 25

1 Actua l Temperature

s 6

9 25

0 Actua

l Temperature

s 6

8 25

0 Tem p Differenc

e (tol . = +-2 ) 0 0 Tem p Differenc

e (tol . = +-2 ) 0 1 

## Ho t Bo x# 7 Ho t Bo x#1 0 Manufacturer

: Anderso

n NUTEC H Manufacturer : Anderso

n NUTECH Seria l No. : N/ A ' Seria l No. : N/ A Dat e received/place

d i n servi c Pr e 199 5 Dat

e received/place

d i nservi o Pr e 199 5 

## Calibratio n Date : 8-Jan-0 9 Calibratio n Date : 8-Jan-0 9 Ambien t Ho t Ambien t Ho

t Referenc e Temperature

s 6

8 25

0 Referenc

e Temperature

s 7

1 25

0 Actua l Temperature

s 6

9 24

9 Actua

l Temperature

s 7

1 25

0 Tem p Differenc

e (tol . = +-2 ) - 1 1 Tem p Differenc

e (tol . = +-2 ) 0 0 

## HotBox#7

A Ho t Bo x#1 1 Manufacturer

. Anderso

n NUTEC H Manufacturer : Anderso

n NUTECH Seria l No. : Dat e received/place

d i n servi c N/ A Pr e 199 5 Seria l No. : Dat e received/place

d i nservi c N/

A Pr e 199 5 

## Calibratio n Date : 8-Jan-0 9 Calibratio n Date : 7-Jan-0 9 Ambien t Ho t Ambien t Ho

t Referenc e Temperature

s 6

9 25

0 Referenc

e Temperature

s 7

0 25

1 Actua l Temperature

s 6

9 24

9 Actua

l Temperature

s 6

9 25

0 Tem p Differenc

e (tol . = +-2 ) 0 1 Tem p Differenc

e (tol . = +-2 ) 1 1 

## Ho t Bo x# 8 Manufacturer

: Seria l No. : Dat e received/place

d i n servi c 

## Anderso

n NUTEC H N/ A Pr e 199 5 

## Calibratio n Date : 8-Jan-0 9 Ambien t Ho t Referenc e Temperature

s 6

9 25

0 Actua l Temperature

s 6

9 24

8 Tem p Differenc

e (tol . = +-2 ) 0 2 

## Checke d amp h connector

, t-coupl e an d plug s Q C 

## checke d b y S Mil o 2/9/0 9



# VES01854 4

# AZCOM Calibrator : Date : Steve

n Mil o Referenc e Thremomete

rID: CL-100

0 12/16/200

8 LastImpinqe

rThermocouple Calibration 200 7 Thermocouple Referenc e Difference (+/

- 2° ) Thermocouple , Referenc e Difference (+/

- 2° ) LI- 1 Ho t 21

0 21

2 -

2 Ll-1 8 Ho t 21

0 21

2 -2 LI- 1 Col d 3

2 3

3 -

1 Ll-1 8 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer : Anderso n NUTECH Seria l No. : Seria l No, : Dat e received/place

d i n service : Pr

e 199 0 T-coupl

e 200 6 Dat e received/olace

d i n service : Pr

e 199 0 LI- 3 Ho t 211 21 3 -

2 LI-2

0 Ho t 211 21 2 -1 LI- 3 Col d 3

2 3

2 0 LI-2 0 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer : Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 LI- 4 Ho t 21

2 21

3 -1 LI-2 2 Ho t 21

3 21

2 1 LI- 4 Col d 3

2 3

2 0 LI-2 2 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTEC H Manufacturer: Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 T-coupl

e 200 6 Dat e received/place

d i n service : Pr

e 199 0 LI- 3 Ho t 21

2 21

3 - 1 LI-22 A Ho t 210 21 2 -2 LI- 3 Col d 3

2 3

2 0 LI-22 A Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer: Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 Ho t 0 LI-2 4 Ho t 21

0 21

2 - 2 Col d 0 LI-2 4 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTEC H Manufacturer: Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 Ho t 0 LI-2 5 Ho t 21

2 21

2 0 Col d 0 LI-2 5 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTEC H Manufacturer: Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/olace

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 LI-1 3 Ho t 21

0 21

2 -

2 LI-2

8 Ho t 21

3 21

2 1 LI-1 3 Col d 3

3 3

2 1 LI-2 8 Col d 3

2 3

2 0 Manufacturer

: Manufacturer: Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/olace

d i n service : Pr

e 199 0 Dat e received/place

d I nservice : Pr

e 199 0 LI-1 5 Ho t 21

0 21

2 -2 LI-1 5 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTEC H Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Afte rcalibratio

n showe rhead s wer e cleane d an d lea kchecke d Q C chec kS . Mil o



# VES01854 5Calibrator : Date : Bil l Hard y 1/18/201 0 Referenc e Thremomete

rID : CL-100

0
Las tImpinge

rThermocouple Calibratio n 200 7 Thermocouple Referenc e Differenc

e (+/ - 2° ) Thermocouple Referenc e _ , Difference 2° ) LI-1 Ho

t 21

0 21

2 -

2 LI-2

0 Ho t 211 21 2 -

1 LI-1 Col

d 3

2 3

2 0 LI-2 0 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer : Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 T-coupl

e 200 6 Dat

e received/place

d i n service : Pr

e 199 0 LI- 3 Ho t 21

2 21

2 0 LI-2 2 Ho t 211 21 2 -

1 LI- 3 Col d 3

2 3

2 0 LI-2 2 Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer: Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 LI- 4 Ho t 21

0 21

2 -

2 LI-22

A Ho t 211 21 2 -1 LI- 4 Col d 3

2 3

2 0 LI-22 A Col d 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer: Anderso n NUTEC H Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 T-coupl

e 200 6 Dat

e received/place

d i n service : Pr

e 199 0 LI-1 3 Ho t 21

2 21

2 0 LI-2 4 Ho t 211 21 2 -

1 LI-1 3 Col d 3

3 3

2 1 LI-2 4 Cold 3

3 3

2 1 Manufacturer

: Manufacturer : Anderso n NUTEC H Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr e 199 0 LI-1 5 Ho t 211 21 2 -

1 LI-2

S Ho

t 21

0 21

2 -

2 LI-1 5 Col d 3

3 3

2 1 LI-2 S Cold 3

3 3

2 1 Manufacturer

: Anderso n NUTEC H Manufacturer: Anderso n NUTEC H Seria l No. : Seria l No. : Dat e received/place

d i n service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 LI-18 Ho

t 21

0 21

2 -

2 LI-2

8 Ho

t 211 21 2 -1 LI-18 Col

d 3

3 3

2 1 LI-2 8 Cold 3

2 3

2 0 Manufacturer

: Anderso n NUTECH Manufacturer: Anderso n NUTECH Seria l No. : Seria l No. : Dat e received/place

d in service : Pr

e 199 0 Dat e received/place

d i n service : Pr

e 199 0 Afte rcalibratio

n showe rhead s wer e cleane d an d lea kchecke d Q C checks . Mil

o



# VES01854 6

# AECOM
M5 Thermocoupl e Calibration s - 200 9 Date : 12/16/0

8 BP : 30.08 Referenc e Thermomete rID#: Manufacture : Dat e place d i n Service : Calibrator : Steve n Mil o Ambien t Tem p (F) : 6

5 CL-100 0 Fluk

e Digita l RT D 213103

5 Fluk e Pr e 198 0 Ic e Bat h Boilin g Wate r Thermocoupl e ID # Referenc e

Tem p XA D

Tem p Tem p

Differenc e To l = +-2 F Referenc e

Tem p XA D

Tem p Tem p

Differenc e To l = + - 2 F M5-TC 1 21 2 21 2 0 3 2 3 3 1 M5-TC 2 21 2 21 1 - 1 3 2 3 3 1 XAD- 6 3 2 3 2 0 21 3 21 2 - 1 XAD- 7 3 2 3 2 0 21 3 21 2 - 1 Q C chec k

S
. Mil o



# VES01854 7

# AECOM
M5 Thermocoupl e Calibration s - 201 0 Date : 1/17/201 0 Calibrator : Bil l Hardy BP : 30.0

8 Ambien t Tem p (F) : 6 5 Referenc e Thermomete rID#: CL-100 0 Fluk e Digita l RT D 213103

5 Manufacture : Fluk e Dat e place d i n Service : Pre 198 0 Ic e Bat h Boilin g Wate r Thermocoupl e ID # Referenc e

Tem p XA D

Tem p Tem p

Differenc e To l = +-2 F Referenc e

Tem p XA D

Tem p Tem p

Differenc e To l = +- 2 F M5-TC 1 3 2 3 3 1 21 2 21 2 0 M5-TC 2 3 2 3 3 1 21 2 21 1 - 1 XAD- 6 3 2 3 2 0 21 3 21 2 - 1 XAD- 7 3 2 3 2 0 21 2 21 2 0 Q C chec k

S
. Mil o



# VES01854 8

# AZCOM DR YGA S METE R CALIBRATIO N Mete rBo x No. : 2 Chec k one : Annua l Calibratio n Recalibratio n Date : 7/10/200 9 I Operator : S . Mil o Barometri c Pressure : 29.8 1 (i n Ho ) Theoretica l Critica l Vacuum : 14.0 6 (i n Hg ) Manufacturer: Environmental Suppl y Dat e Received/Place

d m service ; 200 2 Seria l No. : 2 Pretes t Lea k Check s Allowable Actual Positiv e 0 0.0 0 (a l 5-7in.H 2 0 ) in . H 2 0 pe rmin . Negativ e 0 0.00 0 (a t 3in.Hg ) d m cf m

OR YGA S METE R DAT A CRITICA L ORIFIC E DAT A

Volum e Tem p Critica l I C Orific e Actual Ambien t Temperatur

e A H Tima Initia l Fina l Tota l initial Fina l Orific e Calibrato r Vacuu m Initia l Fina l Average (i n HjO) (min

) (ft 3 ) (ft 1 ) (ft 3 ) " F ° F Serial * Coefficie n (InHg ) ° F ° F ° F 0.2 9 2 0 0.05 0 6.37 B 6.32 8 7 1 7 3 4 0 0.24 0 2 4 7 0 7 1 7 1 0.6 4 1 5 6.40 2 13.32 5 6.92 3 72 7 6 4 8 0.35 0 22. 5 7 2 7 2 7 2 1.1 5 1 5 13.39 6 22.53 3 9.13 7 7 5 7 7 5 5 0.46 0 2 1 7 3 72 7 3 1.9 0 1 0 22.57 7 30.45 1 7.87 4 7 7 79 6 3 0.59 4 1 9 7 3 72 7 3 3.7 0 1 0 30.50 7 41.27 1 10.76 4 7 8 8 2 7 3 0.80 9 1 6 7 3 7 4 7 4

CORRECTE D VOLUM E Dr y Gas Critica l DRYGA S METE R DR YGA S METE R Meter Orific

e CALIBRATIO N CALIBRATIO N V m (st d ft

3 ) Ve r(st

d ft

3 ) FACTO R Y FACTO R AH ® 6.25 9 6.21 2 0.99 3 0.00 1 1.69 1 -0.11 1 6.83 1 6.77 9 0.99 2 0.0 0 1.76 2 -0.03 9 8.98 9 8.91 9 0.99 2 0.0 0 1.83 0 0.02 B 7.73 2 7.66 8 0.99 2 0.0 0 1.81 8 0.0 2 10.58 2 10.44 6 0.96 7 0.0 0 1.90 7 0.1 1 | Avg . Y0.99 1 | | | Avg . AH @ 1.80 1 [ | Notes : 1 ) Fo rvali d tes t results , th

e Actual Vacuu m should b e 1 t o 2 in . H g greater tha

n the Theoretica l Critica l Vacuu m show n above . 2 ) Th e Critica l Orific

e Coefficient, K , mus

t b e entere d i n English units, (ft) ft 3"(de g R)*0.5/((in.Hg)*(mirO). 3 ) Th e minimu m numbero fsample volum

e require d pe rorific

e i s 5 cubi c feet. 4 ) Fo rCalibration Facto rY , th e ratio o fth e readin g o

fIh e calibralio n 

## meter

t o Ih e dr y ga s meter , acceplable toleranc

e o findividual value

s fro m th e averag e is *0.02 5 ) Fo rOrific

e Calibratio n FactorAH@ , Ih e orific e differential pressur

e i n inche s o fHj O tha t equate s t o 0,7 5 cf m o fai ra t 6 8 F an d 29.9 2 inche s o fHg , acceptable toleranc

e o findividual value

s fro m Ih e average ! s ±0,2 .
Dr y Ga s Meter Thermocoupl e Calibratio n Ref.TCIO * RE F -SY R -TC 2 Inle t ID# : 002-I N Outle t ID * 002-OU T Ref. Sourc

e Ref," F T A A Amb . Ai r 6 5 6 6 - 1 6 6 1 Ho t Water 11 8 11 8 0 11 7 - 1 Potentiomete rCalibratio n Lo w 10

0 

## °e 9 9 Mi d 40

0 ° F 40 0 Hig h 90

0 " F 89 9

1 ) Ho t Wate r t o b e i n th e rang e o f10 4 -12 2 °F . 2) Toleranc

e allowe d fo ral l thermocoupl

e individual readings : ±5. 4 ° F 3 ) Toleranc

e allowe d foral ) potentiomete

r individual readings : ±2 ° F 

## y= »(«/ )



## VES01854 9

## AECOM SAMPL E PROB E CALIBRATIO

N DAT A FOR M TYP E "S " PITO

T TUB E ASSEMBL

Y AN D NOZZL E 

## T hermocoupl e Calibratio n PROB E 10

: S-M6-4 D ft.i.r.t.e . ThiriTHmcM

fI D * : ENS R RT D #213103

5 Cneg l CI100I1 , #0602220 0 Omeg a CI10DO

, #0602220

0 PROB E 10

: S-M6-4 D ft.i.r.t.e . ThiriTHmcM

fI D * : Tub . Furrnc a (300 ' •W h PROB E 10

: S-M6-4 D w TM . mhTM» » T C re ' . Twr p - T C T

C . Imp. Tn* . M H • F ••• . "•!(• ' ' . *r- :, TWmm' . '. V . ••. M.m-_;'..•- : 'T

C ' ' . T

C ; Tin. . .- . '.T C . .y.'TO'^ ' Ttif * . . . ...T«

V 'j .PTfTTM?.. " > M h VR*TM . ; ';-T C T C T«T

> •'"T C ' '. . 'T

C " ~ '.'"^'TtBT . Tm » CKom . Date ; 1/26/200 9 S-M5-4 D 3 4 27 4 3 4 27

4 0 21 2 373 . 21 2 37 3 0. 0 . 45 1 50 6 45 0 50 5 -0. 1 S-M5-4 D 34 27 4 34 27

4 0 21 2 373 21 2 373 Q. O 451 50 6 45 0 50 5 -0. 1 34 27

4 34 27

4 0 21 2 373 21 2 373 0.0 45 1 50 6 45 0 50 5 -0. 1 *" » 3

4 27

4 34 27

4 0 21 2 37 3 21 2 373 0. 0 451 50 6 45 0 50 5 -0. 1 

## Typ e "S " Pito t Tub e Calibration :

# > Pi .

» 

## 0 . - Leve l an d Perpendicula r Obstructio n Damage d a , (-10° £a , <-H0° ) et a (-10* S o 2 s 110° ) IS , (-5" s B , =

s *5° ) IS , (-5" s fij S *5" )

z = ATany(± S 0.125" ) W= ATan©(± £0.03125" ) D , (3/1 6 

# S

0, S 3/8" ) A A/2D , (1.0

5 s 1.5

) BVpX M Nltlteillfie-MXM

t * •eHmlnlnt y tha n eeltMiat e Z . 

## Pito t Tub e t o Nozzl e Calibration :

1 ) 

## PSal

t o noioS e separatio n |2 > Trwrnocoupi

e t o psto t sapualiD n 13 ) Pho t andi o pnib o unio n dlittne . >3/ V (vrf.SO O fwaha )


## Prob e Informatio n [Manufacturer

: Ape x Dat e Receive

d an d place d I n Service : pre-199 5 (Conditio n o fProb e wtie n place d in service : flEVV U J joWQ C Check ^Completenes

s _X

_Legibilit y __X „ certif y tha t th e Typ e S pito t tube/prob

e 10» SM5-4D, |criteri a and/o r applicabl

e desig n feature s an d I s hereb y assigne d a pito t tub e calibratio

n facto r C , o f0.6 4 RECONDITIONE

D (circl e one )

_meet s o rexceed s a B Specifications, Specification s _X _ Reasonablenes s

jCertifie d bv : Steve

n Mil p 1/28/0 9 Personne l (Signature/Date

) Steve n Mii o 2/18/0 9 Team . Leade r (Signature/Date

) [Al l constructio

n criteri a fe r a n isolate d "S ° typ e plta t ar e withi n give n tolerance

s prescribe

d I n Qualit y Assuranc

e Handboo

k fa rAi rPoKutia

n Measuremen

t Systems: Volum

e til , Stationar

y Source-Specifi

c Methods

. EPA/600/R-9*/03Bc. Septembe r 193 4



# VES01855 0

## DAIL Y CALIBRATIO N REPOR T Date : 12/1/2009 Star t Time : 07:48:57 En d Time : 08:27:22 Methods : 3A , 6C , 7 E an d 1 0 Jo b Number : 12010

9
Para m C0 2 TH C Spa n

Valu e 1 1 9 Mid-Ga s

Standar d 5.0 2 5.13 Analyze r

Zer o Respons e 0.0 7 N/ A Analyze r

Mi d Respons e 4.9 7 N/ A Zer o

Ca l Erro r 0.7 % 0.2 % Mi d

Ca l Erro r -0.4 % -2.5 % Syste m

Zer o Respons e 0.0 9 0.0 2 Calibratio n Erro r= 100 % x (Analyze rRespons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Syste m Bia s = 100 % x (Syste m Respons e - Analyze rResponse ) / (Spa n Value ) Fo rTH C Measurements : Calibratio n Erro r= 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Cylinde rGa s Standar d Value ) Syste m Bia s = 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Syste m Mi d Respons e 4.9 5 5 . Syste m

Zer o Bia s 0.1% 0.2 % Syste m

Mi d Bia s -0.2 % -1.4 %



## VES01855 1

## CALIBRATIO N CHEC KREPOR T Ru n ID : R1B Date : 12/1/2009 Star t Time : 13:13:05 En d Time : 16:59:38 EP A Methods : 3A , 6C , 7 E an d 1 0 Jo b Number : 12010

9 Analyze rAnalyze r Zer o Mi d Para m Respons e Respons e C0 2 0.0

7 4.9

7 TH C N/

A N/

A Syste m Bias = Syste m Drift = Syste m Syste m Syste m Syste m Syste m Syste m Syste m Syste m Pre-Zer o Pre-Mi d Pre-Zer o Pre-Mi d Post-Zer o Post-Mi d Post-Zer o Post-Mi d Respons e Respons e Bia s Bia s Respons e Respons e Bia s Bia s 0.0 5 5. -0.2 % 0.3

% 0.01 5.0 4 -0.6% 0.7 % 0.14 5.13 1.5 % 0.0

% 0.12 5.0 5 1.4

% -0.9 % 100 % x (Syste m Respons e - Analyze rResponse ) / (Spa n Value ) 100 % x (Syste m Pos t Respons e - Syste m Pr e Response ) / (Spa n Value ) Fo rTH C Measurements : Syste m Bias - 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Zer o Drif t -0.3% -0.2 % Mi d Drif t

0.4 % -0.9% Syste m

Avg-Zer o Respons e 0.0 3 0.13 Syste m

Avg-Mi d Respons e 5.0 2 5.0 9



## VES01855 2

## DAIL YCALIBRATIO N REPOR TStar t Time : 07:53:46

Methods : 3A , 6C , 7 E an d 1 0 Date : 12/272009 En d 

## Time : 08:24:17 Jo b Number : 12020 9
Para m C0 2 TH C Spa n

Valu e 11 9 Mid-Ga s

Standar d 5.0 2 5.13 Analyze r

Zer o Respons e -0.01 N/ A Analyze r

Mi d Respons e 5.0 3 N/ A Zer o

Ca l Erro r 0.0 % 0.3 % Mi d

Ca l Erro r 0.1 % -0.7% Syste m

Zer o Respons e -0.0 3 0.0 3 Calibratio n Erro r= 100 % x (Analyze rRespons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Syste m Bia s = 100 % x (Syste m Respons e - Analyze rResponse ) / (Spa n Value ) ForTH C Measurements : Calibratio n Erro r= 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Cylinde rGa s Standar d Value ) Syste m Bia s = 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Syste m Mi d Respons e 4.99 5.0 9 Syste m

Zer o Bia s -0.2 % 0.3 % Syste m

Mi d Bia s -0.3% -0.4 %



# VES01855 3

## CALIBRATIO N CHEC KREPOR T Ru n ID : R2B Date : 12/2/2009 Star t Time : 11:23:21 En d Time : 16:18:21 EP A Methods : 3A , 6C , 7 E an d 1 0 Jo b Number : 12020

9 Analyze rAnalyze rSyste m Syste m Syste m Syste m Syste m Syste m Syste m Syste m Zer o Mi d Pre-Zer o Pre-Mi d Pre-Zer o Pre-Mi d Post-Zer o Post-Mi d Post-Zer o Post-Mi d Para m Respons e Respons e Respons e Respons e Bia s Bia s Respons e Respons e Bia s Bia s Zer o Drif t Mi d Drif t C0 2 -0.01 5.0 3 0.0

8 5.0

4 0.7

% 0.1% 0.0 7 5.0

5 0.7

% 0.2

% 0.0

% 0.1% TH C N/

A N/

A 0.0

8 ' 5.1 1 0.8 % -0.2% 0.0 9 5.16 1.0 % 0.4

% 0.2

% 0.6

% Syste m Bias = 100 % x(Syste m Respons e - Analyze rResponse ) / (Spa n Value ) Syste m Drift = 100 % x(Syste m Pos t Respons e •Syste m Pr e Response ) / (Spa n Value ) Fo rTH C Measurements : Syste m Bias = 100 % x(Syste m Respons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Syste m Avg-Zer o Respons e 0.0 8 0.0 8 Syste m

Avg-Mi d Respons e 5.0 4 5.14



# VES01855 4

## DAIL YCALIBRATIO N REPOR T Date : 12/3/2009 Star t Time : 08:11:50 En d Time : 08:43:17 Methods : 3A , 6C , 7 E an d 1 0 Jo b Number : 12030

9 Spa n Para m Valu e C0 2 11 TH C 9 Calibratio n Erro r= Syste m Bia s = Mid-Ga s Standar d 5.0 2 5.13 Analyze r

Zer o Respons e 0.0 2 N/ A Analyze r

Mi d Respons e 5.0 2 N/ A Zer o

Ca l Erro r 0.2 % 0.3 % Mi d

Ca l Erro r 0.1 % -1.6% Syste m

Zer o Respons e 0.0 3 0.0 3 Syste m

Mi d Respons e 4.9 9 5.0 5 100 % x (Analyze rRespons e •Cylinde rGa s Standar d Value ) / (Spa n Value ) 100 % x (Syste m Respons e - Analyze rResponse ) / (Spa n Value ) ForTH C Measurements : Calibratio n Erro r= 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Cylinde rGa s Standar d Value ) Syste m Bia s = 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Syste m Zer o Bia s 0.1 % 0.3 % Syste m

Mi d Bia s -0.3% -0.9%



# VES01855 5

## CALIBRATIO N CHEC KREPOR T Ru n ID : R3B Date : 12/3/2009 Star t Time : 12:12:16 En d Time : 16:38:32 EP A Methods : 3A , 6C , 7 E an d 1 0 Jo b Number : 12030

9 Analyze rAnalyze r Zer o Mi d Para m Respons e Respons e C0 2 0.0

2 5.0

2 TH C N/

A N/

A Syste m Bias = Syste m Drift = Syste m Syste m Syste m Syste m Syste m Syste m Syste m Syste m Pre-Zer o Pre-Mi d Pre-Zer o Pre-Mi d Post-Zer o Post-Mi d Post-Zer o Post-Mi d Respons e Respons e Bia s Bia s Respons e Respons e Bia s Bia s -0.0 5 5. -0.7% -0.2% 0.0 4 5.01 0.1 % -0 .1 % 0.1 1 5.0

5 1.2

% -0.9 % 0.0 7 5.0

2 0.6

% -1.3 % 100 % x (Syste m Respons e - Analyze rResponse ) / (Spa n Value ) 100 % x (Syste m Pos t Respons e - Syste m Pr e Response ) / (Spa n Value ) ForTH C Measurements : Syste m Bias = 100 % x (Syste m Respons e - Cylinde rGa s Standar d Value ) / (Spa n Value ) Zer o Drif t 0.8 % -0.4 % Mi d Drif t

0.1% -0.4 % Syste m

Avg-Zer o Respons e -0.01 0.0 9 Syste m

Avg-Mi d Respons e 5.0 1 5.0 3



## VES01855 6

## TH C cals120109Unit3.XL S 

# Initia l TH C Monito rCalibration s Facilit yVeoli a E S Technica l Solutio n Projec t No . 6013321 6 Sourc e Uni t 3 Operato rT . Sroczynsk i Polluntan t TH C Analyze rI.D . VI G Mode l 2 0 s n 0700179 4 Dat e 01Dec0 9 Spa n Valu e 1 0 (ppm )

Cylinde r value, , pp m Zer o an d spa n

syste m response , pp m Lo wan d Mi d Calibratio n error , % Cylinde r value, , pp m Zer o an d spa n

syste m response , pp m syste m re s ponse , pp m Calibratio n error , % Cylinde r value, , pp m Zer o an d spa n

syste m response , pp m Predicte d Actua l Calibratio n error , % Zer o ga s 0 0.0 2 Lo wga s 2.49 3 2.5 1 2. 5 -0.3 1 Mi d ga s 5.13 3 5.1 4 5 -2.7 7 Hig h ga s 8.49 8 8. 5 Cylinde rIdentificatio n Number s

Cylinde rI.D . Zer o ga s Ultr a Zer o Grad e Lo wga s CC21247 0 Mi d ga s SG9108555BA L Hig h ga s SG909599AL B

m = (Hig h ga s respons e - Zer o ga s response ) / Hig h Cylinde rValu e b = Hig h ga s respons e - ( m * Hig h Cylinde rvalue ) predicte d respons e = m * Cylinde rvalu e + b
Calibratio n Erro r= actua l syste m respons e - predicte d syste m respons e * 10 0 cylinde rvalu e Criteri a <=5 %



# VES01855 7

# AECOM Initia l Monito rCalibration s

Comments : 

## Plan t I.D . \l%pL(4 S)AU(jeT

lUiuoiS Projec t No . -g Q I "5 3 . 2 /

6 Sourc e I.D . UN

i ~3

Operato rT i £ Ro<lz.j A J f K ' Pollutan t Analyze rI.D . fry n Ha X Dat e 1 1 A l / 2 - co< 7 Spa n Valu e I 1 Analyze rSeria l No . Ity j ^c/o . ~7 O C R A ^ 6 c?'^^ 4


## Initia l Calibratio n (Tim e <3ff\ 2 7 ) Cylinde rValue ; (pp m o r%) Analyze r

Respons e (pp m o r% ) Calibratio n

Erro r ( % o fSpan ) Syste m

Respons e (pp m o r%

) Syste m ' Bia s ( % o fSpan ) Zer o Ga s 

# O ,o6 on o, 

# o f Lo wLeve l Ga s — . —

— — . 

## Mi d Leve l Ga s Hig h Leve l Ga s / 0
. 

# 96 

# 10.98 

# \6AS

Cylinde rI.D . Zer o Ga s A J o 

# ULTRA H^d /f foiTi Lo wLeve l Ga s Mi d Leve l Ga s 

# sa 3 Hig h Leve l Ga s

Calibratio n Erro r(Analyze rRespons e - Cylinde rValue ) X 10 0 Spa n Valu e Syste m Bia s = (Syste m Respons e - Analyze rResponse ) X 10 0 Spa n Valu e



# VES01855 8

## TH C cals120209Unit3.XL S 

# Initia l TH C Monito rCalibration s Facilit yVeoli a E S Technica l Solutio n Projec t No . 6013321 6 Sourc e Uni t 3 Operato rT . Sroczynsk i Polluntan t TH C Analyze rI.D . VI G Mode l 2 0 s n 0700179 4 Dat e 02Dec0 9 Spa n Valu e 1 0 (ppm )

Cylinde r value , pp m Zer o an d spa n

syste m response , pp m Lo wan d Mi d Calibratio n error , % Cylinde r value , pp m Zer o an d spa n

syste m response , pp m syste m re s ponse , pp m Calibratio n error , % Cylinde r value , pp m Zer o an d spa n

syste m response , pp m Predicte d Actua l Calibratio n error , % Zer o ga s 0 0.0 3 Lo wga s 2.49 3 2.5 1 2.4 5 -2.4 8 Mi d ga s 5.13 3 5.1 4 5.0 9 -0.9 8 Hig h ga s 8.49 8 8.4 9 Cylinde rIdentificatio n Number s

Cylinde rI.D . Zer o ga s Ultr a Zer o Grad e Lo wga s CC21247 0 Mi d ga s SG9108555BA L Hig h ga s SG909599AL B

m = (Hig h ga s respons e - Zer o ga s response ) / Hig h Cylinde rValu e b = Hig h ga s respons e - ( m * Hig h Cylinde rvalue ) predicte d respons e = m * Cylinde rvalu e + b
Calibratio n Erro r= actua l syste m respons e - predicte d syste m respons e * 10 0 cylinde rvalu e Criteri a <=5 %



# VES01855 9

# AECOM Initia l Monito rCalibration s

Comments : 

## Plan t I.D . \ffo LI ASAufVT j I lUMot S Project No . 3 ~ 3 0 I £ Sourc e I.D . ( J M ( T3 Operato r"T « < S 

# ^Qt-JtoS, Kl Pollutan t ' Analyze rI.D . g'EfVV o "t * ^ 0 O 

## Dat e ( 

# X

fo£L13-d

& c 

# f Spa n Valu e 0-2 05 . ft Aw6 S Analyze rSeria l No . /

/.£7< g ^

S P a» j i I
Initia l Calibratio n (Time 69 Cylinde rValu e Analyze r

Respons e (§@S¥33r-%

) Calibratio n

Erro r ( % o fSpan ) Syste m

Respons e (pp m o r%

) Syste m Bia s (%o f Span ) Zero Ga s 

# 0,00 -0,6 I C O Lo wLeve l Ga s
— - — , — • 

## Mi d Leve l Ga s 5 . 0 3 0 . 1 

## Hig h Leve l Ga s 

# 11 .00 0 , < r

Cylinde rI.D , Zer o Ga s N a . Lo wLeve l Ga s Mi d Leve l Ga s Hig h Leve l Ga s


## Calibratio n Erro r(Analyze rRespons e - Cylinde rValue ) X 10 0 Spa n Valu e Syste m Bia s = (Syste m Respons e - Analyze rResponse ) X 10 0 Spa n Valu e



# VES01856 0

## TH C cals120309Unit3.XL S 

# Initia l TH C Monito rCalibration s Facilit yVeoli a E S Technica l Solutio n Projec t No . 6013321 6 Sourc e Uni t 3 Operato rT . Sroczynsk i Polluntan t TH C Analyze rI.D . VI G Mode l 2 0 s n 07001

79 4 Dat e 03DecQ 9 Spa n Valu e 1 0 (ppm )

Cylinde r value , PP m Zer o an d spa n

syste m response , pp m Lo wan d Mi d Calibratio n error , % Cylinde r value , PP m Zer o an d spa n

syste m response , pp m syste m re s ponse , pp m Calibratio n error , % Cylinde r value , PP m Zer o an d spa n

syste m response , pp m Predicte d Actua l Calibratio n error , % Zer o ga s 0 0.0 3 Lo wga s 2.49 3 2.5 0 2.4 9 -0.2 9 Mi d ga s 5.13 3 5.1 1 5.0 5 -1.1 7 Hig h ga s 8.49 8 8.4 4 Cylinde rIdentificatio n Number s

Cylinde rI D . Zer o ga s Ultr a Zer o Grad e Lo wga s CC21247 0 Mi d ga s SG9108555BA L Hig h ga s SG909599AL B

m = (Hig h ga s respons e - Zer o ga s response ) / Hig h Cylinde rValu e b = Hig h ga s respons e - ( m * Hig h Cylinde rvalue ) predicte d respons e = m * Cylinde rvalu e + b
Calibratio n Erro r= actua l syste m respons e - predicte d syste m respons e * 10 0 cylinde rvalu e Criteri a <=5 %



# VES01856 1

## Initia l Monito rCalibration s Plan t I.D . i M SauGe^IUJ HQI S Projec t No . £O / 3 3, 2 f £ Comments : 

## Sourc e I.D . U K j J 3 Pollutan t d. & o Dat e Operato r/ - - S / ? o cz/ a 7 f/C / Analyze rI.D

. S&K-ye

W V ' t *» 0 / 2 A 3 A oa f Spa n Valu e < ? fa»6e Analyze rSeria l No . fty/S C / X, 70 £
Initia l Calibratio n (Timedg
. V3 ) Cylinde rValu e (pp m o r%) . Analyze r

Respons e (pp m o r% ) Calibratio n

Erro r ( % o f Span ) Syste m

Respons e (pp m o r%

) Syste m

Bia s (%o f Span ) Zer o Ga s 

## D>o 

# £>. / Lo wLeve l Ga s — . — — — - 

## Mi d Leve l Ga s 

# 5,014, 0 0 / Hig h Leve l Ga s 

# 16. U 0 . i •^• 3

Cylinder
. I.D . Zer o Ga s M a . (3 LTR A \hCHfuHi7 t 

## Lo wLeve l Ga s Mi d Leve l Ga s 

# SC

<U(>HS/3 Hig h Leve l Ga s

Calibratio n Erro r(Analyze rRespons e - Cylinde rValue ) X 10 0 Spa n Valu e Syste m Bia s = (Syste m Respons e - Analyze rResponse ) X 10 0 Spa n Valu e



# VES01856 2

## J

!

I



# f

VES01856 3

# AECOM

Appendi xD Laborator yDat a



# VES01856 4

## Metho d 5/26 A



# VES01856 5AFXOIv l Repor t Environmen t


## Cas e Narrativ e R e Gravimetri cAnalysi s o f Filte ran d Fron t Hal fProb e Rins e Sample s - Veoli a E S Tec h Sauget , I L Projec t # : 6013321 6 LA B ID# : 09-064 , 09-067 , 09-06 9 ANALYTICA L PROCEDURE : Eleve n (11 ) Teflon ®

typ e filters an d 1 2 fron t hal faceton e rins e sample s were analyze d vi a EP AMetho d 5 Gravimetri cAnalysi s a s governe d b yAECOM' s SO P 2629-300 . Consecutiv e gravimetri cweight s offilters an d beake rresidue s were take n wit h a n annuall ycalibrate d Mettle rbalance , an d weighe d withi n specifie d limit s a s outline d i n EP AMetho d 5 an d AECOM' s SO P 2629-300 .
1 . Fo rtwo o

f thre e shipment s received , 09-06 7 an d 09-069 , on e fiel d blan k o f bot h filte ran d aceton e wer e analyze d a s specifie d b yEP AMetho d 5 Gravimetri cAnalysi s an d AECOM' s SO P 2629-300 . Th e firs t se t of samples , 09-064 , containe d on e aceton e blank , bu t n o filte rblan k wa s received . 2 . Laborator

yblank s o f bot h filte ran d aceton e wer e analyze d fo reac h o

f th e thre e set s of sample s pe rth e sam e Metho d an d SO P a s liste d above . 1 . Fo rth e firs t se t o f sample s received , La b ID : 09-064 , two o f th e aceton e sampl e bottles , M5-Acetone-R B an d M5-U3-AR-R3 , di d no t hav e th e leve l o

f aceton e marke d o n th e bottle . Additionally , followin g evaporatio n o f th e first ofthes e two samples , i.e . th e fiel d blank , a moist , oily-appearin g residu e was observe d i n th e sampl e beaker . Th e gravimetri cresul t fo rtha t sampl e indicate d a net gai n o f 1. 9 mg . 2 . Forth e thir

d se t of samples , La b ID : 09-069 , on e ofth e aceton e rins e sampl e bottles , M5-U4-FHR-R2 , wa s foun d t o contai n a piec e of aluminu m foil , whic h wa s remove d durin g th e aceton e rins e procedure an d prio rt o weighing . , QUALIT YCONTROL :

DISCUSSION :

Dat e Sainple s Receive d byth e Laboratory : 12/04 , 12/1 1 & 12/21/0 9 Dat e Analysi s Started : 12/07/0 9 R:\AirDBase\M5DBWIetho d 5 DatabaseXMETHO D 5 CLIEN TFILESWeoIia\09-064_067_069_CaseNarrative.do c



## Pag e 2 o f 1 4

## AECO M Metho d 5 Expose d Filte rDat a Shee t Balanc e Used : Projec t Manager : Projec t Name : Projec t Number : Analysi s Method : Jef fGorma n Veoli a 6013321 6 Ove n Drie d Mettl e r 3 Da y Dat e ' Tim e ' 

### R.H.(% ) R.T . m Analys t J Star t Monda y 12/7/200 9 9:1 8 4 4 6 8 w v Wt . 

### 1 Frida y 12/11/200 9 8:4 4 3 7 6 7 w v Wt . 2 Monda y 12/14/200 9 10:0 9 3 6 6 8 A C Wt . 3 Wt. 4 Q A Shee t Paga * InlBal.WelBh t L

_=illt " •r.SQmpl^ ' •{Run.Date . r* Sampl e I D Filte r, Typo/Sire ' . 1s t Wt .

-.;.Gram s 2n d Wt .

Gram s A1&2WI .

Grams 3rdW t

Gram s ; 4 2& 3 W t

. Gram s - 4t h Wt

Gram s A 3 M W t

Gram s Fina l Wt .

Gram s . A FW-I W

Tota l Gram s Q A Shee t Paga * Dat e Gram s L

_=illt " •r.SQmpl^ ' •{Run.Date . r* Sampl e I D Filte r, Typo/Sire ' . 1s t Wt .

-.;.Gram s 2n d Wt .

Gram s A1&2WI .

Grams 3rdW t

Gram s ; 4 2& 3 W t

. Gram s - 4t h Wt

Gram s A 3 M W t

Gram s Fina l Wt .

Gram s . A FW-I W

Tota l Gram s 8 8 11/25/0 9 0.390 2 T182 7 - — LA B FILTE R BLAN K 82.6m m 0.390 2 0.390 1 0.000 1 o k b y Wt . 0.390 2 0.000 3 8 7 11/25/0 9 0.398 9 T181 7 12/01/0 9 M5-U3-F-R 1 82.6m m 0.399 6 0.399 5 0.000 1 o k b y Wt . 0.399 6 0.000 7 8 8 11/25/0 9 0.402 0 T182 2 12/02/0 9 M5-U3-F-R 2 82.6m m 0.403 5 0.403 5 0.000 0 o k b y Wt . 0.403 5 0.001 5 8 8 11/25/0 9 0.401 4 T182 1 12/03/0 9 M5-U3-F-R 3 82.6m m 0.402 5 0.402 6 0.000 1 o k b y Wt . 0.402 6 0.001 2
f D o

Rite rType : G=G!ass 

## HI^^^^ M Q=Quart z 1 . Delt a Weight toleranc

e +/ - G.0005 g o ftota l weigh

t less tar e weigh t betwee n tw

o consecutiv

e weightings oraverag e weight. 2 . Filter s mus t b e weighe d wit h !h e propercondition s (R H = 25-5 0 % an d R T= 59-7 8 deg f ) 3 . Filler s mus t b e propert y conditioned (2

4 hou rdesiccation ; Furthe rConditionin g > 6 hours) . 4 . Conditionin g fa rove n method ; Ove n drie d a t 10 5 deg c f o 2- 3 hours ; Furtherconditionin g > 6 hours . 5 . Tota l grams belo

wo requa l t

o .000 5 (LDl ) i s presente

d a s .0003 .

Veolia-_09-064_6013321 6 email.xl s 

# VES01856 7

## AECO M Metho d 5 Fron tHal f Aceton e Prob e Rins e Dat aShee t Balanc e Used : Metlle r3 Projec t Manager : Projec t Name : Projec t Number : Analysi s Method : Jef fGorma n - -Day ^ . Dat e Tim e R.H.(% ) R.T..CF ) Analys t Projec t Manager : Projec t Name : Projec t Number : Analysi s Method : Veoli a Hea t ADDlicatio n Star t Wednesda y 12/9/200 9 10:4 6 4 3 6 8 P T Projec t Manager : Projec t Name : Projec t Number : Analysi s Method : 6013321 6 Hea t ADDlicatio n Wt . 1 Frida y 12/11/200 9 9 1 2 3 7 6 7 W V Projec t Manager : Projec t Name : Projec t Number : Analysi s Method : NatOralfEvabotatlbn . ? V Hea t ADDlicatio n Wt. 2 Monda y 12/14/200 9 9 5 3 3 5 6 8 A C Projec t Manager : Projec t Name : Projec t Number : Analysi s Method : Wt . 3 Tuesda y 12/15/200 9 8 3 0 4 0 6 8 w v Wt . 4 Wednesda y 12/16/200 9 8 3 0 3 8 6 8 M W Q A Shee t Page ? Initia l Wt . :. . Beaker . # • Sampl e Ru n Dat e Sampl e I D Fiel d * m L ' La b

m L 1s t Wt .

Grams 2n d Wt . ; Grams - - A t&2Wt .

. . Gram s 3r d Wt .

Gram s A2& 3 Wt .

Gram s 4t h Wt .

Gram s A 3& 4 Wt .

Gram s Fina l Wt .

Gram s AFW-I W

Tota l Gram s Q A Shee t Page ? Dat e ' vGrams : . , :. . Beaker . # • Sampl e Ru n Dat e Sampl e I D Fiel d * m L ' La b

m L 1s t Wt .

Grams 2n d Wt . ; Grams - - A t&2Wt .

. . Gram s 3r d Wt .

Gram s A2& 3 Wt .

Gram s 4t h Wt .

Gram s A 3& 4 Wt .

Gram s Fina l Wt .

Gram s AFW-I W

Tota l Gram s 48 5 12/07/0 9 114.399 9 223 3 LA B ACETON E BLAN K 5 0 114.400 1 114.399 6 0.000 5 okbyWt . 114.399 9 0.000 3 48 4 12/01/0 9 108.711 9 225 1 12/03/0 9 M5-Acetone-R B 15 3 6 0 108.714 0 108.713 6 0.000 4 o k b y Wt . 108.713 8 0.001 9 48 4 12/01/0 9 106.792 5 40 8 12/01/0 9 M5-U3-AR-R 1 4 8 5 0 106.795 4 106.794 9 0.000 5 o k b y Wt . 106.795 2 0.002 7 48 4 12/01/0 9 105.005 5 2 2 12/02/0 9 M5-U3-AR-R 2 5 9 5 0 105.007 7 105.007 4 0.000 3 o k b y Wt . 105.007 6 0.002 1 48 4 12/01/0 9 109.996 0 229 1 12/03/0 9 M5-U3-AR-R 3 6 0 5 0 109.998 2 109.997 6 0.000 6 109.998 5 0.000 9 109.997 3 0.001 2 109.997 9 0.001 9

Aceton e Manufacturer/Lo t No. : Fisher/092950 . Aceton e Rinse = 2 5 mi s twic e -(5 0 mis total) 1 . Delt a Weight toleranc

e +/ - O.OGOS g o ftota l weigh

t les s tar e weigh t betwee n tw

o consecutiv

e weightings or averag e weight. 2 . Beaker

s mus t b e weighe d wit h th e prope rcondition s (R H = 25-5 0 % an d R T= 59-7

8 de g 0 3 . Beaker

s mus t b e propeil y conditione

d (2 4 hou rdesiccation ; Furthe rConditionin g > 6 hours) . 4 . Natura l Evaporatio n Melho d = Evaporat e t o dryness a

t room temperatur

e undera hoo

d / watc h glas s cove r 5. Hea t Applicatio n = Unde ra hood and watch glass ove rsample , apply hea t belo wthe boilin g poin

t o fsampl e unti l evaporated t o 2 5 mis : then follo

wste p 4 (above

) fo rremainin g portion . 6 . Tota l gram s belo

wo requa l t

o .0005 (LDL) I

s presented as .0003 .



# VES01856 8SAMPL E LOG-I N & RECEIP TCHECKLIS T 

## Client/Proi # £ " S 

## I ecj.J fobj ^9-1L Projec t Mgr: _ La b Poo l # : Inspecte d & Logge d i n by : /\ l 

## (^grfe-t-rlfi._Dat e & Time: _ Sdiiip h Matri x Numbe rof

/.Samples' : Analysi s R.CC|UGStCC l 

## Hol d Tim e &

Du o by(date) Storag e

Locatio n \

Disposa l - I 1'"-'id'at e ' •1 

## filte r 

# * 3 Tw Ut,
-7—"— —J- fi f 

## Due r

## )0-l)${fs HT : Due : 1 t Circl e th e appropriat e response : 

## 1 ) (Shipp^ /

Han d delivere d 2 ) CQC^prisel^ /

no t presen t o n receip t 3 ) Sample s broke n / leakin g (^tia$£> o n receip t 4 ) Sample s ^mbient ychille d o n receip t 5 ) Sample s preserve d correctl y/ incorrectl y/ ( 

## fic^ilicommend|g ' 6 ) Receive d ^^^in)/outsid e holdin g tim e 7 ) CO C tape s presen t /^^Tot ^resenho n sample s / N A 9 ) Discrepancie s /^[Odiscrepancies^note d betwee n COC s an d sample s Additiona l Comments : 1 U/h t>r^r,n^J>r,ffi-eS ; 

## MS- Afefpnr^-/Z£

a^/ 

## jnf-A ^t/QuTil /W, /

fear/ 1 

## Jjprff ^ 

# C

r L 

# £

5 8 

## Page 1 2 o f 1 4 8/26/200 8


## VES01856 9

## Sampl e Traceabilit yLis t AECO M Sit e o fProgram : Veoli a E S Tec h Sampl e Date : 

## /SL// - /2./3/c& Projec t Location : Sauget , I L P.O.# : Typ e o fProgram : CP T Dat e Shipped : / O/S/i ? Laboratory : AECO M Environmen t Harvard , M A Proiect# : 6013321 6 Proqra m Office : Syracus e N Y Shipper / ' ' Steve n Mil o Recovery : Jef fGorma n Laboratory : AECO M Environmen t Harvard , M A Progra m Contact : Jef fGorma n FedE xAi rBil l # : Ite m Sampl e I D Cod e Sampl e Matri x Sampl e Descriptio n Analitica l Parameter s Specia l Instruction s 1 

## M5-U3-F-R 1 Filter M5 , Filter , Ru n 1 Particulat e Matte r

# g ^f-foC <-f — / 2 

## M5-U3-AR-R 1 Aceton e M5 , F H Aceton e Rinse , Ru n 1 Particulat e Matte r / 5 ~ 3 4 

## M5-U3-F-R 2 Filter M5 , Filter , Ru n 2 Particulat e Matte r

# Q Cf—Q 

# I. *-j 5 

## M5-U3-AR-R 2 Acetone M5 , F H Aceton e Rinse , Ru n 2 Particulat e Matte r p Cj y _ 6 7 

## M5-U3-F-R 3 Filter M5 , Filter , Ru n 3 Particulat e Matte r

## rflCjf- fil\ Lf — " 3 8 

## M5-U3-AR-R 3 Acetone M5 , F H Aceton e Rinse , Ru n 3 Particulat e Matte r

## fltA—fi/^U 9 1 0 1 1 - 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 

## M5-Acetone-R B Acetone M5 -Aceton e Blan k Particulat e Matte r Q -J > tr9 "t £ 

## Fiel d N c >tes / Comment s Pag e o f Relinquishe d B y (print) : Date : Signature : , Time : Relinquishe d B y (print) : Date : Signature : 

## ^^_^Jm& ss1 

## ''^ Relinquishe d B y (print) : Date : Signature : Time : Receive d b y La b (print) : Date : . Signature : ^ _Time : Receive d B y (print) : Date : Signature : ^Tjmgj=^- — 

## Receive d B y(print)

: ^ Signature : Time : 

## Receive d B y(print)

: Datel" ' Signature^^--(£j / Time : 7 —• Analytica l Laborator y Destination : AECO M Environmen t 32 5 Aye rRoa d Harvard , M A 0145 1 Attn : Mr . Pau l Tavern a (978 ) 772-234 5 Ex t 3 2 

## VES01857 0

# 1



# TestAmeric a

TH E LEADE R I N ENVIRONMENTA L TESTIN G 

## TestAmeric a Laboratories , Inc .


# ANALYTICA L REPOR T

PROJEC T HO . 5013321 6 Veoli a- K S Tec h L o t # : H9L07040 5

Jef f Gorma n AECOM , In c 510 5 Campuswoo dDriv e

Suit e 10 4 Eas t Syracuse , N Y1305 7

TESTSMERIC ALABORATORIES , INC .

Kevi nS . Woodcoc k Projec t

Manage r

Decembe r

10 , 200 9

581 5 Middlebroo kPik e Knoxville, T N 37921 te l 865.291.300 0 fax 865.584.431 5 www.testamericainc.co m 

# VES01857 1

# ANALYTICA L METHOD S SUMMAR Y
H9L07040 5

ANALYTICA L PARAMETE RMETHO D Chlorin e Emission s KNO X0050/26 AMo d Hydroge nChlorid e Emission s KNO X0050/26 AMo d R e f ereaices : KNO XTestAmeric aLaboratorie s Inc. , Knoxvill e Laborator y Standar d

Operatin g Procedur e

## 3 

# SAMPL E SUMMAR Y

H9L0.7040 5

W O #SAMPLE #CLIEN TSAMPL EI D SAMPLE D SAM P DAT ETIM E LOL O 4 LQLO B LQL1 E LQL1 M LQL1 V LQL1 X LQL2 K LQL2 P LQL2 T 0 0 1

0 0 2 0 0 3 0 0 4 0 0 5 0 0 6 0 0 7 0 0 8 0 0 9 CPT-CL2-F B

CPT-U3-HCL-IMP 1 CPT-U3-CL2-IMP 5 CPT-U3-HCL-IMP 1 CPT-U3-CL2-IMP 5 CPT-U3-HCL-IMP 1 CPT-U3-CL2-IMP 5 CPT-DIWATER-F B CPT-HCL-F B 4 - R1A/ B 6 - R1 4 - R2A/ B 6 - R2 4 - R3A/ B 6 - R3 12/01/0 9 12/01/0 9 12/02/0 9 12/02/0 9 12/03/0 9 12/03/0 9 12/03/0 9 12/03/0 9 12/03/0 9 NOT E(S ) :

- The analytica

l result s ol ' th

e sample s liste dabov e ar e presente

do ntli e followin g pages . • Al l calculation s ar

e performe dbefore roundin g to avoi dround-of f error s i ncalculatedresults .

- Results note

da s "ND " wer

e ao i detecte

da t o r above th e state dlimit .

- TIli s report

mus t no t b e reproduced , except

li t full , without

di e writtenapproval o f

di e laboratory .

- Results fo r

th e followin g parameler s ar e neve r reportedo nadr

y weigh t basis : color , corrosiviiy , density , flashpoint , ignitability , layers , odor , pain t litte r test . pH . porosit

y pressure , reactivity , redo x potential , specifi c graviiy , spo t tests , solids , solubility , temperature , viscosity , an dweight .



# VES01857 3

## 4 

# PROJEC T NARRATIV E H9L07040 S Th e result s reporte d herei n ar e applicabl

e t o th e sample s submitte

d foranalysi

s only . This repor

tshal l no tb e reproduce

d excep ti n full , withou

tth e writte n approva

l o f th e laboratory

. Th e origina

l chai n o f custod y documentatio

n i s include d wit h thi s report . Sampl e Receip t Custod y seal s wer e no tpresent . Sample s wer e receive d i n tw o shipment

s o n 12/3/0 9 an d 12/4/09 . Qualit y Control an

d Dat aInterpretatio

n Unles s otherwis

e noted , al l holdin g time s an d Q C criteri

awer e me tan d th e tes tresult s show n i n thi s repor tmee tal l applicabl

e NELA C requirements

. Sample s wer e analyze d fo rchlorid e b y io n chromatograph

y usin g SO Pnumbe r KNOX-WC-005 (base

d o n BP A method

s 9056,905

7 an d 26A) . Al l sampl

e result s wer e reporte d a s tota l jig hydroge

n chlorid e (HCI ) an d tota l u g chlorin e (CI2) . Result

s wer e calculate d usin g th e followin

g equations :

Ch , u g = (Chloride,ug/ml) * (SampleVolume,mL) * Benc h Dilutio n NaO H impinge

rsample s wer e treate d wit h sodiu m thiosulfat

e (NajSzOj ) prio

rt o th e fina l analysi s in orde rt o conver tresidua l hypochlorit

e (OC1" ) t o chlorid e ion . Note : A sampl

e volum e o f 10 0 m L wa s use d t o conver tth e result s t o tota l u g fo rth e metho d blanks , laborator

y contro l samples , an d clien treagen tblank s i n orde rt o standardiz

e th e analyt e sampl e total ,
TestAmeric aKnoxvill e maintain s the followin g certifications , approval s an daccreditations : Arkansa s DE Q La b #88
- 0688 , Californi aDH S ELA PCert . #2423 . Colorad o DPHE , Connecticu t DP H La b #PH-0223 , Florid aDO H La b #E87177 , Georgi aDN RLa b #906 , Hawai i DOH , Illinoi s EP ALa b #200012 , Indian aDO H Lab #C-TN-02 , Iow aDN R La b #375 . Kansa s DH ECert . #E-10349 , Kentuck y DE PLa b #90101 , Louisian aDE Q Cert . #03079 , Louisian aDOHH , Marylan dDO ECer t

#277 , Michiga nDE Q La b #9933 , Nevad aDEP , Ne w Jersey.DE PLa b #TN001 , Ne w Yor k DO H La b #10781 , Nort hCarolin aDP H La b #21705 , Nort hCarolin aDEHN RCert . #64 , Ohi o EP AVA PLa b #CL0059 , Oklahom aDE Q La b #9415 , Pennsylvani aDE PLa b #68-00576 , SouthCarolin aDHE C Cer t #84001001 , Tennesse e D O H La b #02014 , Texa s CEQ , UtahDO H La b #QUAN3 , Virgini aDG S La b #00165 , Washingto nDO ELa b # C 1314 , Wes t Virgini aDE PCer t

#345 , Wes t

Virgini aDHH RCer t

#9955C , Wisconsi nDN RLa b #998044300 , Nava l Facilitie s Engineerin g Servic e Cente r an dUSD ASoi l Permi t #S-46424 . Thi s lis t

o f approval s i s subjec t

t o chang e an ddoe s no t impl y tha

t laboratory certificatio ni s availabl e fo r al l parameter s reporte di nthi s environmenta l sampl e datareport . 

## HCI , u g = (Chloride

, ug/mL) * (Sampl

e Volume,mL)* Molecula

rWeigh tHC I Molecula rWeigh tC l * Benc h Dilutio n



# VES01857 4

# PROJEC T NARRATIV E H9L07040 5 Fo rdemonstratio

n of analytica l metho d performanc

e o nthes e samples

, TestAmeric

a Knoxville analyze

d matri x spike s (MS) an d matri x spik e duplicate

s (MSD) . Acceptabl

e recoverie s o f thes e spike s demonstrat

e tha tquantitatio

n fro m thi s particula

rstac kga s matri x i s accurat e an d acceptable

. Impinge rsample s containin

g 0.1 N H2SO4 an

d 0.1 N NaO H displa

y matri x interferenc

e effect s causin g poo rmetho d performanc

e an d possibl y givin g unreliabl

e dat aunles s th e interferenc

e i s removed

. Therefore

, th e sample s wer e dilute d i nth e la b t o remov e th e interferenc

e fo ramor e accurat e chlorid e response

. Th e sample s ma y b e analyze d a tincreasin

g dilution s alon g wit h matri x spike s unti l matri x spike s recove rfro m th e sampl e withi n laborator

y contro l limits. Th

e io nchromatograp

h calibratio n rang e use d t o quantitat

e th e sampl e result s permit s astandar

d ten-fol d sampl e dilutio n whil e supportin

g th e reportin g limi twit h th e lo w calibratio

n standard

. . Th e dilutio n facto rreporte d o nth e sampl e resul tfor m doe s no trepresen tth e benc h dilutio n factor . I ti s actuall y th e combinatio

n of factor s require d b y th e method , t o conver t th e anio n reportin

g limi tan d metho d detectio

n limi tfro m ug/m L t o tota l ug. . I tma y appea rt o b e elevate d becaus e i tinclude s th e tota l sampl e volum e i nmL .

## 6 

# Q C DAT A ASSOCIATIO N SUMMAR Y
H9L07040 5

Sampl e Preparatio nan dAnalysi s Contro l Number s

SAMPLE # 0 0 1 0 0 2 0 0 3 0 0 4 0 0 5 0 0 6 0 0 7 0 0 8 0 0 9 MATRI X

, AI R A I R A I R A I R A I R A I R A I R A I R A I R ANALYTICA L

METHO D KNO X0050/26 AMo d KNO X0050/26 AMo d KNO X005O/26 AMo d KNO X0O5O/26 AMo d KNO X0050/26 AMo d KNO XO0SO/26 AMo d K2TO X0050/26 AMo d KNO X0050/26 AMo d KNO X0O5O/26 AMo d LEAC H BATC H # PRE P BATC H # 934329 6 934318 7 934329 6 934318 7 934329 6 934318 7 934329 7 934329 8 934318 7 M S RUN #

934321 8 934313 2 934321 8 934313 2 934321 8 934313 2 934325 4 934408 2 934313 2



# VES01857 6

## 7

Sampl e Dat a Summar y



# VES01857 7

## 8

AECOM , In c Clien t

Sampl e ID ; CET-TJ3-HCL-IMP1-4- E1A/ B

Genera l Chemistr y lot-Sampl e : H9L070405-00 1 Wor k Orde r

#... : LQL0 4 Matri x : AI R Dat e Sample d: 12/01/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL T• R LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e 1410 0 212 0 u g KNO X0050/26 AMo d12/07/0 9 934329 6 Dilutio nFactor : 21165.0 7 MD L: 89 0



# VES01857 8

## 9

AECOM , In c Clien t

Sampl e ID ; CPT-03-CI.2-IMP5-6- RX

Genera l Chemistr y Lot-Sampl e #-.. : H9L070405-00 2 Wor k Orde r

#.. . : LQL0 8 Matri x : : AI R Dat e Sampled. : 12/01/0 ? Dat e Received.12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Chlorin e N D 49 0 u g KNO X0050/2S AMo d12/08/0 9 934318 7 Dilutio nFactor s 490 0 MD L: 21 0



# VES01857 9

# 1 0

AECOM , In c Clien t

Sampl e ID : CPT-U3-HCL-rMPl-4- R2A/ B

Genera l Chemistr y Lot-Sampl e #... : H9L070405-00 3 Wor k Orde r

#... : LQL1 EMatri x : AI R Dat e Sampled. : 12/02/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e 1480 0 220 0 u g KNO X0050/2S AMo d12/07/0 9 934329 6 Dilutio nFactor s 21967.2 5 HD Ls 92 0



# VES01858 0

## 1 1

AECOM , In c Clien t

Sampl e ID : CPT-D3-CL2-IMPS-S-j R2

Genera l Chemistr y tot-Sampl e #... : H9L070405-00 4 Wor k Orde r

LQL1 M Matri x : AI R Dat e Sampled... : 12/02/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR L• • UNIT S METHO D ANALYSI S DAT EBATC H # Chlorin e N D 48 0 u g KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 460 0 HD L: 20 0



# VES01858 1

## 1 2

AECOM , In c Clien t

Sampl e ID : CPT-D3-HCI.-IMP1-4- R3A/ B

Genera l Chemistr y Lot-Sampl e #... : H9L070405r-00 5 Wor k Orde r

#... : LQL1 V Matri x : AI R Dat e Sampled. . . : 12/03/0 9 Dat e Received . . : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e 2740 0 401 0 u g KNO XO050/26 A Mo d12/07/0 3 934329 6 Dilutio nFactor s 40149.B 8 MDL.- . : 170 0



# VES01858 2

## 1 3

Lot-Sampl e # . Dat e Sampled . AECOM , In c Clien t

Sampl e ID : CPT-D3-CL2-IMP5-S- R3

Genera l Chemistr y
: H9L070405-00 S Wor k Orde r

#... : LQL1 X

. : 12/03/0 9 Dat e Received . . : 12/04/0 9 Matri x i : AI R

PARAMETE R Chlorin e RESUL TR L M D UNIT S METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # 5 5 0 u g Dilutio nFactor : .550 0 KNO X0050/2S AMo d12/08/0 9 MDI . : 23 0 934318 7



# VES01858 3

## 1 4

AECOM, . In c Clien t

Sampl e ID : CPT-DIWATER-F B Genera l Chemistr y Lot-Sampl e : H9L070405-00 7 Wor k Orde r

: LQL2 K Matri x : AI R Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/Q 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e N D 10 3 u g KNO X0050/26 AMo d12/08/0 9 934329 7 Dilutio nFactor : 1028.4 3 MD L: 4 3



# VES01858 4

## 1 5

AECOM , In c Clien t

Sampl e 10 : CPT-HCL-F B Genera l Chemistr y Lot-Sampl e #... : H 9 L 070405 T :00 8 Wor k Orde r

LQL2 PMatri x : AI R Dat e Sampled.. ; : 12/03/0 9 Dat e Received.. : 12/04/0 9

• PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S . . METHO D ANALYSI S DAT EBATC H # "Hydroge nchlorid e N D 41 1 u g KNO X0050/26 AMo d12/09/0 9 934329 8 Dilutio nFactor : 4X13.7 2 MD L: 17 0 .



# VES01858 5

## 1 6

AECOM , In c Clien t

Sampl e ID : CPT-CL2-F B Genera l Chemistr y Lot-Sampl e : H9L070405-00 9 Wor k Orde r

#... : LQL2 TMatri x : AI R Dat e Sampled,.. : 12/03/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRBSOL TR LONIT S METHO D ANALYSI S DAT EBATC H Chlorin e . • N D 10 0 u g KNO X0050/26 AMo d12/08/0 9 934318 7 Dilution . Factor : 100 0 MDI / : 4 2



# VES01858 6

## 1 7

Clien t

Lo t #... : H9L07040 S METHO D BLAN K EEPOR T Genera l Chemistr y Matrix . A I R
PARAMETE R RESUL T Chlorin e REPORTIN G LIMI TUNIT S METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # Wor k Orde r

# : LQQW31A AM B Lot-Sampl e .# : H9L090000-18 7 N D 10. 0 u g ICNO X0050/26 AMo d12/08/0 9

Dilutio nFactor : 10 0 934318 7 Hydroge nchlorid e Wor k Orde r

# : LQRXV1A AM B Lot-Sampl e # : H9L090000-29 6 N D 10. 3 u g ICNO X0050/26 AMo d12/07/0 9

Dilutio nFactor : 102. 8 934329 6 Hydroge nchlorid e Wor k Orde r

# : LQR7V1A AM B Lot-Sampl e # : H9L090000-29 7 N D 10. 3 u g . KNO X0050/26 AMo d12/08/0 9

Dilutio nFactor : 102. 8 934329 7 Hydroge nchlorid e Wor k Orde r

# : LQT4G1A AM B Lot-Sampl e # : H9L090000-29 8 N D 10. 3 u g ICNO X0050/26 AMo d12/09/0 9

Dilutio nFactor : 102. 8 934329 8

NOTECS ) : Calculation s are performe dbefore roundin s t o avoi dround-of

f error s i ncalculate dresults .



# VES01858 7

## 1 8

LABORATOR YCONTRO LSAMPL EEVALUATIO NREPOR T Genera l Chemistr y Lot-Sampl e H9L07040 S Matrix . A I R

PARAMETE R Chlorin e PERCEN T RECOVER Y 9 9 9 7 RECOVER YRP D PREPARATION
- PRE P

LIMIT S RP D LIMIT S METHO D ANALYSI S DAT EBATC H # W0#:LQQW31AC-LCS/LQQW31AP-LCS D LC S Lot-Samplet : H9L090000-18 7 ( 9 0 - 110 ) KNO X0050/26 AMo d12/08/09 . 934318 7 ( 9 0 - 110 ) 2. 1 (0-20 ) KNO X0050/2S AMo d12/08/0 9 934318 7

Dilutio nFactor : 10 0 Hydroge nchlorid e 9 4 9 4 W0#-.LQRXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Satnple# : H9L090000-29 6

( 9 0 - 110 ) KNO X0050/2S AMo d• 12/07/0 9 934329 6 ( 9 0 - 110 ) 0.0 9 (0-20 ) KNO X0050/26 A Mo d12/07/0 9 934329 6

Dilutio nFactor s 102. 6 Hydroge nchlorid e 9 9 9 7 W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Sample# : H9L090OO0-29 7

( 9 0 - 110 ) KNO X0050/26 AMo d12/08/0 9 934329 7 ( 9 0 - 110 ) 2.1 . (0-20 ) ICNO X0050/26 AMo d12/08/0 9 934329 7

Dilutio nFactor : 102. 8 Hydroge nchlorid e 1 0 0 9 7 W0#:LQT4G1AC-LCS/LQT4G1AD-LCS D LC S Lot-Sample# : H9L090000-29 8

( 9 0 - 110 ) KNO X0050/26 AMo d12/09/0 9 934329 8 ( 9 0 - 110 ) 2. 8 (0-20 ) KNO X0050/26 A Mo d12/09/0 9 934329 8

Dilutio nFactor : 102. 8

NOT EIS ) : . _ Calculation s arc performe dbefor e rounding i o avoi dround-of f error s i ncalculatedresults .



# VES01858 8

## 1 9

LABORATOR YCONTRO LSAMPL EDAT AREPOR T

Genera l Chemistr y Lot-Sampl e

## it...: H9L 0 7040 5 . Matrxx . A I R

PARAMETE R Chlorin e SPIK EMEASORE D PERCN T AMOUN TAMOUN TUNIT S RECVR YRP D METHO D 75. 0 75. 0 PREPARATION
- PRE P ANALYSI S DAT EBATC H # WO#:LQQW31AC-LCS/LQQW3IAD-LCS D LC S Lot-Sampleft : H9L090000-18 7 74. 0 u g 9 9 KNO X0050/26 AMo d12/08/0 9 93431B 7 72. 4 u g 9 7 2. 1 KNO X005O./26 AMo d12/08/0 9 934318 7

Dilutio nFactor s io o Hydroge nchlorid e 77. 1 77. 1 W0S:LQEXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Sample*- . H9L090000-29 S

72. 5 u g 9 4 KNO XO05O/2S AMo d12/07/0 9 934329 6 72. 6 u g 9 4 0.0 9 KNO X0050/26 AMo d12/07/0 9 934329 6

Dilutio nFactor : 102. B Hydroge nchlorid e 77. 1 77. 1 • W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Sample# : H9L090OO0-29 7

76. 1 u g 9 9 KNO X0050/26 AMo d12/08/0 9 934329 7 74. 5 u g 9 7 2. 1 KNO X005O/26 AMo d12/08/0 9 934329 7

Dilutio nFactor : 102. 8 Hydroge nchlorid e 77. 1 77. 1 W0#:LQT4G1AC-LCS/LQT4G1AD-LCS D LC S Lot-Sample# : H9L090000-29 8

77. 3 u g 10 0 KNO X0050/26 AMo d12/09/0 9 934329 8 75. 1 u g 9 7 2. 8 KNO X0050/26 AMo d12/09/0 9 934329 8

Dilutio nFactor : 102. B
NOTB(S ) Calculation s ar c performe dbefor e roundio g t

o avoi dround-of

f error s i ncalculate dresults .



# VES01858 9

## 2 0

MATRI XSPIK ESAMPL EEVALUATIO NREPOR T

Clien t

Lo t #.. , Dat e Sampled.. . : H9L07040 5 : 12/02/0 9 Genera l Chemistr y
Dat e Received.. : 12/04/0 9 Matri x : AI R

PARAMETE R Chlorin e ,PERCEN TRECOVER Y RECOVER YLIMIT S R P D R P D LIMIT S METHO D PREPARATION
- ANALYSI S DAT E PRE P BATC H # 1 0 0 1 0 1 WO# : LQL1M1AC-MS/LQL1M1AD-MS D M S Lot-Sampl e # : H9L07040S-00 4

( 7 5 . - 125 ) KNO X0050/26 AMo d12/08/0 9 934318 7 ( 7 5 - 125 ) 0.9 3 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934318 7

Dilutio nFactor : 480 0 Hydrogre nchlorid e 9 0 8 6 WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e # : H9L0704O5-00 3

( 7 5 - 125 ) KNO X0050/26 AMo d12/07/0 9 934329 6 ( 7 5 - 125 ) 0.9 6 (0-20 ) KNO X0050/26 AMo d12/07/0 9 934329 6

Dilutio nFactor : 2196 7 NOT E(S ) : ' Calculation s ar

e pcribrme dbefore rouodin g t o avoi dround-ot

T error s i ncalculate dresults .



# VES01859 0

# 2 1

MATRI XSPIK ESAMPL EDAT AREPOR T

Genera l Chemistr y Clien t

Lo t # . Dat e Sampled . H9L07040 5 12/02/0 9 Dat e Received.. : 12/04/0 9 Matrix . AIR .
SAMPL ESPIK EMEASR D PARAMETE RAMOUN TAM T Chlorin e N D

N D 9 6 0

9 6 0 AMOUN TUNIT S PERCN T RECVR YRP D METHO D PREPARATIO N- PRE P ANALYSI S DAT EBATC H # WO# : LQLIMIAC-MS/LQLIMIAD-MS D M S Lot-Sampl e # : H9L07O405-0O 4 9 5 9 u g . 10 0 KNO X0050/26 A12/08/0 9 934318 7 9 6 8 u g 10 1 0.9 3 KNO X0050/26 A12/08/0 9 934318 7 Dilutio nFactor : 4 800 . Hydroge nchlorid e

1480 0 439 0 1480 0 439 0 WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e # : H9L07O405-00 3 1880 0 u g 9 0 KNO X0050/26 A12/07/0 9 934329 6 1860 0 u g 8 6 0.9 6 KNO X0050/26 A 12/07/0 9 934329 6 Dilutio nFactor : 2196 7 NOT E(S ) : Calcubtion s ar

c pcrrormc dbefor e roundin s t o avoi dround-of

f error s i ncalculate dresults .



# VES01859 1

## 2 2

Clien t

Lo t #... : H9L07040 5 Dat e Sampled... : 12/01/0 9 SAMPL EDDPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

: LQL04-SM P

LQL04-DU P Dat e Received.. : 12/04/0 9

PARA M RESUL T DUPLICAT E RESUL T Hydroge nchlorid e

1410 0 1410 0 UNIT S R P D R P D LIMI T METHO D Matri x : AI R

PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e # : H9L0704Q5-0O 1 u g 0.3 2 (0-20 ) ICNO X0050/2S AMo d12/07/0 9 934329 6 Dilutio nFactor : 21165.0 7



# VES01859 2

## 2 3

H9L07040 5 12/01/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

LQL08-SM P

LOLO8-DU P Dat e Received.. ; 12/04/0 9 . .

N D Matrix . A I R

UNIT S R P D

R P D LIMI T METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e #:•H9L070405-00 2 u g 0 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor i 490 0



# VES01859 3

## 2 4

Clien t

Lo t #... : H9L07040 5 Dat e Sampled... : 12/02/0 9 SAMPL EDDPLICAT EEVBLTJRTIO H REPOR T Genera l Chemistr y Wor k Orde r

#... : LQL1E-SM P

LQL1E-DU P Dat e Received-. : 12/04/0 9

PARA M RESUL T DUPLICAT E RESUL T Hydroge nchlorid e

1480 0 1460 0 UNIT S R P D R P D LIMI TMETHO D Matri x : . AI R

PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e # : H9L070405-00 3 u g 1. 5 (0-20 ) KNO X0050/26 AMo d12/07/0 9 934329 6 Dilutio nFactor ; 21967.2 5



# VES01859 4

## 2 5

Clien t

Lo t # . Dat e Sampled. .
PARA M RESUL T Chlorin e

N D H9L07040 5

12/02/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

#... : LQL1M-SM P

LQUM-DU P Dat e Received...
- 12/04/0 9

N D UNIT S R P D R P D LIMI TMETHO D Matri x : AI R

PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e #.
- H9L070405-0O 4 u g 0 (0-20 ) KNO X0050/2S AMo d12/08/0 9 934318 7 Dilutio nFactor : 480 0



# VES01859 5

## 2 6

Clien t

Lo t H9L0704D 5 Dat e Sampled... : 12/03/0 9 

### SAMPL E DUPLICAT E EVALUATIO N REPOR T Genera l Chemistr y Wor k Order . #... : LQL1V-SM P LQL1V-DU P Dat e Received.. : 12/04/0 9 DUPLICAT E RESUL T PARA M RESUL T Hydroge nchlorid e

2740 0 2780 0 Matrox . . : AI R

UNIT S R P D R P D LIMI TMETHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # T ' S D Lot-Sampl e # : H9L07D405-00 5 u g 1. 5 (0-20 ) KNO X0050/26 AMo d12/07/0 9 934329 6 Dilutio nFactor : 40149.8 6



# VES01859 6

## 2 7

Clien t

Lo t #... : H9L07040 5 Dat e Sampled. . . : 12/03/0 9 SAMPL EDDPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

# . .. i LQL1X-SM P

LQL1X-DU P Dat e Received.. ! 12/04/0 9 .. .
PARA M RESUL T Chlorin e

N D DUPLICAT E RESUL T N D Matrix . 

### A I R

UNIT S R P D •

R P D LIMI TMETHO D PREPARATION
- PRE P ANALYSI S DAT E, BATC H # • S D Lot-Sampl e # : H9L070405-00 6 u g 0 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 550 0



# VES01859 7

## 2 8

Clien t

Lo t # . Dat e Sampled .
PARA M RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y H9L070405 . . Wor k Orde r

#... : LQL2K-SM P

LQL2K-DU P 12/03/0 9 Dat e Received.. : 12/04/0 9 DUPLICAT E RESUL T UNIT S R P D R P D LIMI TMETHO D Matri x : AI R

PREPARATIO N- PRE P ANALYSI S DAT EBATC H # Hydroge nchlorid e

N D N D S D Lot-Sampl e # : H9L070405-00 7 u g 0 (0-20 ) KNO X0050/2S AMo d12/08/0 9 934329 7 Dilutio nFactor : 1028.4 3



# VES01859 8

## 2 9

. , Clien t

Lo t # . .. : H9L07040 5 Dat e Sampled.-. : 12/03/0 9 SAMPL EDUPLICAT EEVALUATIO NEEPOR T Genera l Chemistr y . Wor k Orde r

#... : LQL2P-SM P

LQL2P^DU P Dat e Received.. : 12/04/0 9

PARA M RESUL T DUPLICAT E RESUL T Hydroge nchlorid e

N D N D UNIT S R P D R P D LIMI T METHO D Matrix . A I R

PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e # : H9L070405-00 8 u g 0 (0-20 ) KNO X0050/2S AMo d12/09/0 9 Dilutio nFactor : 4X13.7 2 934329 8



# VES01859 9

## 3 0

Cliea t

Lo t # . Dat e Sampled .
PARA M RESUL T Chlorin e

N D . : H9L07040 5

. : 12/03/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

# . - . : LQL2TrSM P

LQL2T-DU P Dat e Received.. : 12/04/0 9

N D UNIT S R P D R P D LIMI TMETHO D . Matri x : AI R

PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e # : H9L070405-00 9 u g 0 (0-20 ) KNO X0050/2S AMo d12/08/0 9 934318 7 Dilutio nFactor : 100 0



# VES01860 0

## 3 1



# Sample Receip t

Documentation

VES01860 1

## Sampl e Traceabilit yLis t AECO M Sit e o f Prorjram : VeoliaE S Tech . Sampl e Date : ta i i- lZ./3/rt V Projec tLocation : Sauget , I L LabPO#' : Typ e of Program : CP T Dat e Shipped : l't/-4/6 < ? Laboratory : TestAmerica, Inc . Knoxville , T N Project * 60133218 Progra m Office : Syracuse N Y Shipper/

Steve n Mil o Recovery : Jef f Gorma n Laboratory : TestAmerica, Inc . Knoxville , T N Progra m Contac tJef f Gorma n FedE x Ai rBil l 8 : He m Sampl e I D Code Sampl e Matri x Sampl e Descriptio

n Analytica l Parameter

s Specia l Instruction

s 1 CPT-U3-HCL-HWP1-4- R1 A 0.1N H2S04 Uni t3 , Impinger

s 1-4 , Ru n 1 A HCL 2 CPT-U3^HCL-IMP1-4- R1 B 0.1N H2S04 Uni t3, Impinger

s 1-4 , Ru n 1 B HC L 3 CPT-U3-CI2-IMP5-6- R1 0.1N NaOH Uni t3, Impinger

s 5-6 , Ru n 1 4 5 CPT-U3-HCL-1MP1-4- R2 A 0.1N H2S04 Uni t3, Impinger

s 1-4 , Ru n 2 A HCL 

## &{a\a 6 CPT-U3-HCL-IMP1-4- R2 B 0.1NH2SO 4 Uni t3 , Impinger

s 1-4 , Ru n 2 B 

## HC L i*i4(M.-r s 7 CPT-U3-CI2-IMP5-6-R 2 0.1 N NaOH Uni t3 , Impinger

s 5-6 , Ru n 2 6 1 9 CPT-U3-HCL-HVIP 1 -4- R3 A 0.1 N H2S04 Uni t3, Impinger

s 1-4 , Ru n 3 A HCL 10 CPT-U3-HCL-IMP1-4- R3 B 0. 1 N H2S04 Uni t3 , Impinger

s 1-4 , Ru n 3 B HCL ' 1 1 CPT-U3-CI2-IMP5-6- R3 0. 1 N NaO H Uni

t3, Impinger

s 5-6 , Ru n 3 CI

2 1 2 1 3 1 4 1 5 1 6 1 7 O X Vhlstci ' b t

## vAerpWr i SU^C - hcl/Cb . 1 8 CPT-HCL-F B 0.1NH2SO 4 0.1NH2SO 4 Fiel d Blan k HCL ' 19 CPT-CI2-F B 0. 1 N NaOH 0.1N NaOH Fiel d Blan k CI 2 2 0 Field Notes

/ Comment

s Page of Relinquishe

d B y (print) : Date : Steven Mil o 

## l2/3/e<} Signature : . Time : 

## A//^y> -WlL /7oa Relinquishe d B y (print) : Date : Signature : Time : Relinquishe d B y (print) : Date : Signature : Time : ^ ~ Receive d b y La b (print) : Date : Sjinatuia/ " J , Time : 

# ^%rtrVIV \

mvi s Receive d B y (print) : Date : Signature : Time : Receive d B y (print) : Date : Signature ; Time : Receive d By (print) : Date : Signature : Time : Analytica l Laborator

y Destination : Tes tAmeric aInc . 6815 Middlebroo

kPik e Knoxville , T N 37921 Attn : Mr . Kevi n Woodcoc

k865-291-300

0 C O

r o 

# VES01860 2

## TESTAMERIC A KNOXVILL E SAMPL E RECEIPT/CONDITIO N UPO N RECEIP T ANOMAL Y CHECKLIS T Lo tNumber: 

# .M W

VfrlODiO b Revie w Item s N D N A PW» 1 I f No , wha t

wn s th e problem ? Comments/Action s Take n I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : I . D o sampl e containe r label s matc hCOC ? (IDs , Dates , Times ) 

# J

iO l aD o no t matc hCO C 0 l b Incomplet e informatio n 0 l c Markin g smeare d O l dLabe l to m D i e N o labe l
• 1 r CO C no t

receive d B i g Other : 2 . I s th e coole r

temperatur e withi nlimits ? ( > freezing temp , o f wate r t o 6°C;NC , 1668,1613B : 0-4°C ; VOST : 10*C ; MA:2-6°C ) 

# J • 2 aTem p Blan k = 2 . I s th e coole r

temperatur e withi nlimits ? ( > freezing temp , o f wate r t o 6°C;NC , 1668,1613B : 0-4°C ; VOST : 10*C ; MA:2-6°C ) 

# J 0 2 b Coole r Tem p = 2 . I s th e coole r

temperatur e withi nlimits ? ( > freezing temp , o f wate r t o 6°C;NC , 1668,1613B : 0-4°C ; VOST : 10*C ; MA:2-6°C ) 

# J 3 . Wer e sample s receive dwit hcorrec t chemica l preservativ e (excludin g Encore} ? f 

# j 0 3 aSampl e preservativ e = 3 . Wer e sample s receive dwit hcorrec t chemica l preservativ e (excludin g Encore} ? f 

# j 0 3 aSampl e preservativ e = 4 . Wer e custod y seal s present/intac t o ncoole r

and/o r containers ? 

## 1 

# I H4 aNo t presen t 0 4 b No t

intac t D 4 c Other : 4 . Wer e custod y seal s present/intac t o ncoole r

and/o r containers ? 

## 1 

# I H4 aNo t presen t 0 4 b No t

intac t D 4 c Other : 4 . Wer e custod y seal s present/intac t o ncoole r

and/o r containers ? 

## 1 

# I H4 aNo t presen t 0 4 b No t

intac t D 4 c Other : 5 . Wer e al l ofth e sample s liste do nth e CO C received ? 

## J

- • 5 aSample s received-noto nCO C 0 5 b Sample s no t

received-o nCO C 5 . Wer e al l ofth e sample s liste do nth e CO C received ? 

## J

- • 5 aSample s received-noto nCO C 0 5 b Sample s no t

received-o nCO C 6 . Wer e al l o f

th e sampl e container s receive dintact ? 

## I D 6 aLeakin g • 6 b Broke n 7
- Wer e VO Asample s receive dwithou t headspace ? 

# / 

# I • 7 aHeadspac e (VO Aonly ) 8 . Wer e sample s receivedi nappropriat e containers ? 

## ... 1 .. 0 8 aImprope r

containe r 9 . Di dyo u chec k

fo r residua l chlorine , i f

necessary ? 

# J • 9 aCoul dno t b e determine ddu e t o matri x interferenc e 9 . Di dyo u chec k

fo r residua l chlorine , i f

necessary ? 

# J • 9 aCoul dno t b e determine ddu e t o matri x interferenc e 10 . Wer e sample s receive dwithi nholdin g time ? 010 aHoldin g tim e expire d i l . Fo r ra dsamples , wa s sampl e activit y info , provided ? 

## J • Incomplet e informatio n 12 . Fo r 1613 B wate r

sample s i s pH<9 ? 

# J I f no , wa s p H adjuste dt o p H 7 - 9 wit hsulfuri c acid ? 12 . Fo r 1613 B wate r

sample s i s pH<9 ? 

# J I f no , wa s p H adjuste dt o p H 7 - 9 wit hsulfuri c acid ? 13 . Ar e the shippin g container s intact ? • 13 aLeakin g 0 I3 b Other : 14 . Wa s CO C relinquished ? (Signed/Dated/Timed ) • 14 aNo t relinquishe d 15 . Ar e tests/parameter s liste dfo r eac hsample ? 

# j 0 15 aIncomplet e informatio n 16 . I s th e matri x o f

th e sample s noted ? 

# h • 15 nIncomplet e infonnatio n 17 . I s th e date/tim e o f sampl e collectio nnoted ? • 15 aIncomplet e informatio n 18 . I s th e clien t

an dprojec t

name/ #identified ? • 15 aIncomplet e informatio n 19 . Wa s th e sample r

identifie do nth e COC ? Ouoteff : 

## <?Y?3? P M Instructions :



## ( ~ \ A

## ^rr^Z

6 Sampl e Receivin EAssociate : 

## ^fffi U ^TWd KDate :l2 - 

# S\tP QA026R21.doc , 09040 9

C O C O 

## VES01860 3

## 3 4



# We t Chemistry

VES01860 4

## 3 5


# Sampl e Summar

y

VES01860 5

## 3 6

AECOM , in c Clien t

Sampl e ID : CPT-rj3-HCL-IMPl-4- R1A/ B

Genera l Cnemistr y Lot-Sampl e H9L070405-00 1 Wor k Orde r

LQL0 4 .Matri x : AI R Dat e Sampled... : 12/01/0 9 Dat e Received . - : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e 1410 0 212 0 u g KNO X0050/26 AMo d12/07/0 9 934329 6 Dilutio nFactor : 21165.0 7 HSI > , : B9 0



# VES01860 6

## 3 7

AECOM , m c Clien t

Sampl e ID : CPT-03-CL2-IMP5-6- R1

Genera l Chemistr y Lot-Sampl e #... : H9L0704O5-00 2 Wor k Orde r

ft... : LQL0 8 Matri x : AI R Dat e Sampled... : 12/01/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LOMIT S METHO D ANALYSI S DAT EBATC H # Chlorin e N D 49 0 u g KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 490 0 HD L: 21 0



# VES01860 7

## 3 8

AECOM , In c Clien t

Sampl e ID : CPT-TJ3-HCL-IMP1-4- R2A/ B

..Genera l Chemistr y LotTSampl e #... : H9L070405-00 3 Wor k Orde r

#... : LQL1 EMatEbc r : AI R Dat e Sampled... : 12/02/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nChlorid e 1480 0 220 0 u g KNO X0050/26 AMo d12/07/0 9 934329 S Dilutio nFactor : 21967.2 5 MD L: 92 0



# VES01860 83 9

AECOM , In c Clien t

Sampl e ID : CPT-TJ3-CL2-IKP5-6- R2

Genera l Chemistr y Lot^Sarapl e #....
- H9L07040S-00 4 . Wor k Orde r

#... : LQL1 M Matrix...
- AI R Dat e Sampled... : 12/02/0 9 Dat e Received.12/04/0 3 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Chlorin e N D 48 0 u g KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 480 0 MDL... . : 20 0



# VES01860 9

## 4 0

AECOM , In c Clien t

Sampl e ID : CPT-TJ3-HCL-IMP1-4- R3A/ B

Genera l Chemistr y Lot-Sampl e : H9L070405.-.D0 5 . .Work-Orde r : LQL1 V Matri x AI R Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LTJHIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e 2740 0 401 0 u g KNO X005O/26 AMo d12/07/0 9 934329 6 Dilutio nFactor : 40149.8 8 MD L: 170 0



# VES01861 0

## 4 1

AECOM , In c Clien t

Sampl e TDz CPT-TB-CL2-IMPS-S- R3

Genera l Chemistr y Lot-Sampl e #..H9L070405-00 6 Wor k Order : LQL1 XMatri x : AI R Dat e Sampled,.. r 12/03/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESOL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Chlorin e N D 55 0 u g KNO X005Q/26 AMo d12/08/0 9 934318 7 Dilutio nFactor ; 550 0 MD L: 23 0



# VES01861 1

## 4 2

AECOM , In c Clien t

Sampl e ID : CPT-DIWATBR-F B Genera l Chemistr y Lot-Sampl e ft-..: H9L070405-00 7 . Wor k Orde r

#... : LQL2 K ... . ..Matri x : AI R Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/0 9 PREPARATION
- PRE P PARAMETE RRESUL TR LUNIT S METHO D ANALYSI S DAT EBATC H # Hydroge nchlorid e N D 10 3 u g KNO X005Q/26 AMo d12/08/0 9 934329 7 Dilutio nFactor : 1028.4 3 MDL.. . 4 3



# VES01861 2

## 4 3

AECOM , In c Clien t

Sampl e ID : CPT-HCL-F B Genera l Chemistr y Lot-Sampl e #-.. : H9L070405.T00 8 .. . Wor k Orde r

: LQL2 P Matri x : AI R. . Dat e Sampled... : 12/03/0 9 Dat e Received.. : 12/04/0 9 PREPARATION - PRE P PARAMETE RRESUL T R L UNIT S METHO D ANALYSI S DAT E BATC H # Hydroge nchlorid e N D 41 1 u g KNO X0050/26 A Mo d12/09/0 9 934329 8 Dilutio nFactor : 4113.7 2 MDL . : 17 0



# VES01861 3

## 4 4

Lot-Sampl e # . Dat e Sampled .
PARAMETE R AECOM , In c Clien t

Sampl e ID : CPT-CL2-F B Genera l Chemistr y

. : H9L07O4OS-OO 9 Wor k Order.LQL2 T

. : 12/03/0 9 Dat e Received.. : 12/04/0 9

RESUL T R L UNIT S METHO D Matri x : AI R
PREPARATION
- PRE P ANALYSI S DAT EBATC H # Chlorin e N D 1 0 0 u g Dilutio nFactor : 100 0 KNO X0050/26 AMo d12/08/0 9 MDI . : 4 2 934318 7



# VES01861 4

## 4 5



# Q C Summar

y

VES01861 5

## 4 6

METHO D BLAN K

REPOR T Genera l Chemistr y Clien t

Lo t # . . . : H9L07040 5

PARAMETE R . REPORTIN G RESUL TLIMI TUNIT S METHO D Matri x : AI R PREPARATION
- PRE P ANALYSI S DAT EBATC H # Chlorin e N D Wor k Orde r

# : LQQW31A AM B Lot-Sampl e # : H9L090000-18 7 10. 0 u g KNO X0050/26 AMo d12/08/0 9 Dilutio nFactor : 10 0 934318 7
Hydroge nchlorid e Wor k Orde r

# : LQRXVIA AM B Lot-Sampl e # : H9L090000-29 6 N D 10. 3 u g KNO X0050/26 AMo d12/07/0 9

Dilutio nFactor : 102. E 934329 6
Hydroge nchlorid e Wor k Orde r

# : LQR7V1A AM B Lot-Sampl e # : H9L090000-29 7 N D 10. 3 u g KNO X0050/26 AMo d12/08/0 9

Dilutio nFactor : 102. 8 934329 7
Hydroge nchlorid e Wor k Orde r

# : LQT4G1A AM B Lot-Sampl e # : H9L090000-29 8 N D 10. 3 u g ICNO X0D50/26 AMo d12/09/0 9

Dilutio nFactor : 102. 8 934329 8
NOT E <S ) ; Catcufaion s arc performe dbefore roundin g l o avoi dround-off error s i ncalculatedremits .



# VES01861 6

## 4 7

LABORATOR YCONTRO LSAMPL EEVALUATIO NREPOR T Genera l Chemistr y Lot-Sampl e H9L07040 S Matrix .
PARAMETE R Chlorin e PERCEN T RECOVER Y 

### 9 9 9 7 RECOVER Y

LIMIT S R P D R P D LIMIT S METHO D PREPARATION
- ANALYSI S DAT E : AI R PRE P BATC H # WO#!LQQW31AC-LCS/LQQW31AD-LCS D LC S Lot-Sample# : H9L090000-18 7 ( 9 0 - 110 ) KNO X0050/26 A Mo d12/08/0 9 934318 7 ( 9 0 - 110 ) 2. 1 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 10 0 Hydroge nchlorid e 9 4 9 4 W0#:LQRXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Sample# : H9L09OO0O-29 S

( 9 0 - 110 ) KNO X00S0/2S AMo d12/07/0 9 934329 6 ( 9 0 - 110 ) 0.0 9 (0-20 ) KNO X0050/26 A Mo d12/07/0 9 934329 6

Dilutio nFactor : 102. S Hydroge nchlorid e 9 9 9 7 W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Sample# : H9L090000-29 7

( 9 0 - 110 ) KNO X0050/26 AMo d12/08/0 9 934329 7 ( 9 0 - 110 ) 2. 1 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934329 7 Dilutio nFactor : 102. 8 Hydroge nchlorid e 1 0 0 9 7 WO#:LQT4GlAC-LCS/LQT4GlAD-LCS D LC S Lot-Sample# : H9L090000-29 8

( 9 0 - 110 ) KNO X00S0/26 AMo d12/09/0 9 934329 8 ( 9 0 - 110 ) 2. 8 (0-20 ) KNO X0050/26 AMo d12/09/0 9 934329 8

Dilutio nFactor : 102. 8


### NOTB(S ) : Calculation s arc perforate dbefor e roundin g t

o avoi dround-of

f error s i ncalculatedresults .



# VES01861 7

## 4 8

LABORATOR YCONTRO LSAMPL EDAT AREPOR T

Genera l Chemistr y LotT -Sampl e #. ,
PARAMETE R Chlorin e H9L0704Q 5 SPIK EMEASURE D AMOUN TAMOUN TUNIT S Matxajc . 

### AI R PERCN T RECVR YRP D METHO D PREPARATION
- ANALYSI S DAT E 75. 0 75. 0 PRE P BATC H# WO#:LQQW31AC-LCS/LQQW31AD-LCS D LC S Lot-Sample# : H9L09OO0O-18 7 74. 0 u g 9 9 KNO X0050/26 AMo d12/08/0 9 934318 7 72. 4 u g 9 7 2. 1 KNO X0050/26 AMo d12/08/0 9 934318 7

Dilutio nFactor : 10 0 Hydroge nchlorid e 77. 1 77. 1 W0#:LQRXV1AC-LCS/LQRXV1AD-LCS D LC S Lot-Sample# : H9L090000-29S .

72. 5 u g 9 4 KNO X0050/26 AMo d12/07/0 9 934329 6 72. 6 u g 9 4 0.0 9 KNO X0050/26 AMo d12/07/0 9 934329 6

Dilutio nFactor : 102. 8 Hydroge nchlorid e 77, 1 77. 1 W0#:LQR7V1AC-LCS/LQR7V1AD-LCS D LC S Lot-Satnple# : H9L090000-29 7

76. 1 u g 9 9 KNO X0050/26 AMo d12/08/0 9 934329 7 74. 5 u g 9 7 2. 1 KNO X0050/26 AMo d12/08/0 9 934329 7

Dilutio nFactor : 102. 8 Hydroge nchlorid e 77. 1 77. 1 W0#:LQT4G1AC-LCS/LQT4G1AD-LCS D LC S Lot-Sampled : H9L090000-29 8

77. 3 u g 10 0 KNO X0050/26 AMo d12/09/0 9 934329 8 75. 1 u g 9 7 2. 8 KNO X0050/26 AMo d12/09/0 9 934329 8

Dilutio nFactor : 102. 8
NOTE(S ) : Calculaiion s are performe dbefor e rounding to avoi dround-of f error s i ncalculatedresults .



# VES01861 8

## 4 9

MATRI XSPIK ESAMPL EEVALUATIO NREPOR T

Genera l Chemistr y Clien t

Lo t tt. Dat e Sampled
-
PARAMETE R Chlorin e H9L07040 5 12/02/0 9 PERCEN TRECOVER Y RECOVER YLIMIT S Dat e Received.. : 12/ 0 4/ 0 9

R P D R P D

LIMIT S METHO D Matri x : AI R
PREPARATION
- ANALYSI S DAT E PRE P BATC H # 1 0 0 1 0 1 WO# : LQLIMIAC-MS/LQL-IMIAD-MS D M S Lot-Sampl e # : H9LO7040S-O0 4

( 7 5 - 125 ) KNO X0050/26 AMo d12/08/0 9 9343L8 7 ( 7 5 - 125 ) 0.9 3 (0-20 ) KHO X0050/26 AMo d12/08/0 9 934318 7

Dilutio nFactor : 480 0 Hydroge nchlorid e 9 0 (7 5 8 6 (7 5 WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e # : H9L070405-00 3 125 ) KNO X0050/26 AMo d12/07/0 9 934329 6 125 ) 0.9 6 (0-20 ) KNO X0O50/26 AMo d12/07/0 9 934329 6 Dilutio nFactor : 2196 7 NOTB<S) : Calculation s ar

e performe dbefor

e roundin g t

o avoi dround-of

f error s i ncalculatedresults.



# VES01861 9

## 5 0

MATRI XSPIK ESAMPL EDAT AREPOR T

Genera l Chemistr y Clien t

Lo t H9L07040 S Dat e Sampled.-. : 12/02/0 9 Dat e Received.. : 12/04/0 9 Matrix . AIR ,

SAMPL ESPIK EMEASR D PARAMETE RAMOUN TAMT . Chlorin e N D

N D 9 6 0

9 6 0 AMOUN TUNIT S PERCN T RECVR YRP D METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H# WO#:'LQLIMIAC-MS/LQLIMIAD-MS D M S Lot-Sampl e # : H9LO70405-0O 4 9 5 9 u g 10 0 KNO X0050/26 A12/08/0 9 934318 7 9 6 8 u g 10 1 0.9 3 KNO X0050/26 A12/08/0 9 934318 7 Dilutio nFactor : 480 0 Hydroge nchlorid e

1480 0 439 0 1480 0 439 0 WO# : LQLIEIAC-MS/LQLIEIAD-MS D M S Lot-Sampl e # ; H9LO70405-OO 3 1880 0 u g 9 0 KNO X0050/26 A12/07/0 9 934329 6 1860 0 u g 8 6 0.9 6 KNO X0050/26 A12/07/0 9 934329 6 Dilutio nFactor : 2196 7 NOT E CS ) Calculaiion s ar c performe dbefore rounding t o avoi dround-of

f error s i ncalculatedresults .



# VES01862 0

## 5 1

Clien t

Lo t #. . Dat e Sampled. .
PARA M RESUL T H9L07040 5 12/01/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

#... : LQL04-SM P

LQL04-DU P Dat e Received.. : 12/04/0 9

Hydroge nchlorid e

1410 0 ' 1410 0 Matrxx . A I R

UNIT S R P D

R P D LIMI TMETHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e ff : H9L070405-00 1

U g 0.3 2 (0-20 ) KNO X0050/26 AMo d12/07/0 9 934329 6 Dilutio nFactor : 21165.0 7



# VES01862 1

## 5 2

Clien t

Lo t # . Dat e Sampled .
PARA M RESUL T Chlorin e

N D H9L07040 5

12/01/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

#... : LQL08-SM P-

LOLO8-DU P Dat e Received.. : 12/04/0 9

N D Matrix . 

## AI R

UNIT S R P D

R P D LIMI T METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e # : H9L070405-00 2 t i g 0 (0-20 ) KNO X0050/2S AMo d12/08/0 9 934318 7 Dilutio nFactor : 490 0



# VES01862 2

## 5 3

Clien t

Lo t #... : H9L07040 S Dat e Sampled... : 12/02/0 9 SAMPL EDDPLICAT EEVALUATIO NEEPOR T Genera l Chemistry
- Wor k Orde r

4f . . . : LQL1E-SM P

LQL1E-DU P Dat e Received12/04/0 9

PARA M RESUL T DUPLICAT E RESUL T Hydroge nchlorid e

1480 0 1460 0 Matrxx . 

## AI R

UNITS ' R P D

R P D LIMI TMETHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e #.
- H9L070405-OO 3 u g 1. 5 (0-20 ) KNO X0050/2S AMo d12/07/0 9 934329 6 Dilutio nFactor : 21357.2 3



# VES01862 3

## 5 4

Clien t

Lo t # . Dat e Sampled .
PARA M RESUL T Chlorin e

N D . : H9L07040 5

. : 12/02/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistry
- Wor k Orde r

#... : LQL1M-SM P.

LQL1M-DU P Dat e Received.. : 12/04/0 9

N D UNIT S R P D R P D LIMI TMETHO D Matri x : AI R

PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e # : H9L070405-00 4 u g 0 (0-20 ) KNO X0050/2S AMo d12/08/0 9 934318 7 Dilutio nFactor ! 480 0



# VES01862 4

## 5 5

Clien t

Lo t ft...: H9L07040 5 Dat e Sample d: 12/03/0 9 SAMPL E DUPLICAT E EVALUATIO N REPOR T Genera l Chemistry ' Wor k orde r

ft...: LQL1V -SM P

LQL1V -DU P Dat e Received.. : 12/04/0 9 DDPLICAT E RESUL T PARA M RESUL T Hydroge nchlorid e

2740 0 2780 0 J4atrix . 

### AI K

UNIT S R P D

R P D LIMI T METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D Lot-Sampl e ft: H9L070405-00 5 u g 1. 5 (0-20 ) KNO X0050/26 AMo d12/07/0 9 934329 6 Dilutio nFactor ; 40149.8 8



# VES01862 5

## 5 6

Clien t

Lo t ft. Dat e Sampled .
PARA M RESUL T Chlorin e

N D H9L07040 5

12/03/0 9 DUPLICAT E RESUL T SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y

. Wor k

Orde r

ft...: LQL1X-SM P

LQL1X-DU P Dat e Received-. : 12/04/0 9

N D Matrix . A I R

UNIT S • RP D

R P D LIMI T METHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H ft
' " S D Lot-Sampl e # : H9L070405-00 6 u g o <0-20 ) KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 550 0



# VES01862 6

## 5 7

Clien t

Lo t #... : H9L07040 S Dat e Sampled... : 12/03/0 9 DDPLICAT E PARAM.RESUL TRESUL T Hydroge nchlorid e

N D N D SAMPL EDUPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

If... : LQL2K-SM P... .

LQL2K-DU P Dat e Received.. : 12/04/0 9 Matrxx . A I R

UNIT S R P D

R P D LIMI TMETHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H # S D LOt-Sampl e # : H9L070405-00 7 u g 0 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934329 7 Dilutio nFactor : 1028.4 3



# VES01862 7

## 5 8

Clien t

Lo t .ft.. . : H9L0. 7 040 5 Dat e Sampled... : 12/03/0 9 DDPLICAT E SAMPL EDDPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

ft...: LQL2P-SMP •

LQL2P-DU P Dat e Received.. : 12/04/0 9 .. .
PARA M RESUL T RESUL T Hydroge nchlorid e

N D N D Matrix . .AI R

UNIT S R P D

R P D LIMI TMETHO D PREPARATION
- PRE P ANALYSI S DAT EBATC H ft S D Lot-Sampl e ft: H9L07O405-0O 8 u g 0 (0-20 ) KNO X0050/25 AMo d12/09/0 9 934329 8 Dilutio nFactor : 4113.7 2



# VES01862 8

## 5 9

H9L0704.0 5 12/03/0 9 DDPLICAT E RESUL T SAMPL EDDPLICAT EEVALUATIO NREPOR T Genera l Chemistr y Wor k Orde r

#.. . : LQL2T-SM P•

LQL2T-DU P Dat e Received.. : 12/04/0 9

N D Matrix . A I R

UNIT S R P D

R E D LIMI TMETHOD ' PREPARATION
- PRE P ANALYSI S DOB . BATC H # S D Lot-Sampl e # : H9L070405-OO S u g 0 (0-20 ) KNO X0050/26 AMo d12/08/0 9 934318 7 Dilutio nFactor : 100 0



# VES01862 9

## Metho d 0023 A



# VES01863 0

## •Vist a Analytical Laborator y 

## Decembe r18,200 9 Vist aProjec

tLD. : 3224

4 Mr . Jeffre

y Gorma n AECO M Environmen

t 501 5 Campuswoo

d Driv e Suit e 10 4 Eas tSyracuse

, N Y 13057-423

2 Dea rMr . Gorman

, Enclosed ar

e th e result s forth e fourMM 5 sample

s receive d a tVist aAnalytica

l Laboratory

- o n Decembe r04 , 200 9 unde ryou rProjec tNam e "60133216" . Th

e fron tan d bac khalve s of thes e sample s wer e extracte

d an d analyze

d usin g Metho d 0023 A fo rtetra-through-oct

achlorinate

d dioxin s an d furans . Th e fron tan d bac khalve s of th e Fiel d Blan

kwer e combine

d fo rextractio

n an d analysis . A standar

d turnaroun

d tim e wa s provide d fo rthi s work . Th e following repor

tconsist s of aSampl e Inventor

y (Sectio n I), Analytica

l Result s (Sectio n II ) an d th e Appendix

, whic h contain s th e chain-of-custody, alis to f dat aqualifier

s an d abbreviations

, Vista' s curren

tcertifications, an

d copie s of th e ra wdat a(i f requested). VistaAnalytica

l Laborator

y i s committe

d t o servin g you effectively. I

f yo u requir e additiona

l information, pleas

e contac tm e a t916-673-152

0 o rb y emai l a tmmaier@vista-analytical.com . Than kyo u fo rchoosin g Vist aa s par tof you ranalytica

l suppor tteam . Sincerely ,

Laborator

y Directo r
Vista Analytical

Laboraloiy certifies that the report

herein meets all

the requirements set

forth byMLACforthose applicable test mefhods. Results relate only lo the samples as received by the laboratory. This report should not be reproduced

except In full is. -without

the written approval

qf Vista Analytical

Laboratory.

Vist aAnalytica

l Laborator

y | ll04Windfiel d Wa y | E l Dorad o Hills,CA9576

2 I ph: 916-673-152 0 | fx:916-673-0!0

6 I wwww.vista-analytical.co m 

## Projec t 32244 Pag e 1 o f 1 8 

# VES01863 1

# Wist a
Sectio n I : Sampl

e Inventor

y Repor t Dat e Received : Projec tNo. : Projec tName: 12/4/200 9

3224 4 6013321 6
Lab . Sampl

e I D Clien

tSampl e I D Componen tI D 00 1 00 2 00 3 00 4 00 5 00 6 00 7 CPT-U3-M23A-XAD-R 1 CPT-U3-M23A-PF-R 1 CPT-U 3 -M2 3 A-XA D -R 2 CPT-U3-M23A-PF-R 2 CPT-U3-M23A-XAD-R 3 CPT-U3-M23A-PF-R 3 CPT-U3-M23A-F B B H R X A D F H R FILTE R B H R X A D F H R FILTE R B H R X A D F H R FILTE R BLAN K FILTE R X A D

SinpinvgnmmS.rpt

Projec t 3224 4 Pag e 2 o f 1 8 

# VES01863 2

# Vist a

SECTIO N I

I

rojcc l 3224 4 Pa>: c3 o f1 8 

# VES01863 3Metho dBlan k 

## Metho d 0023 A Matrix : MM 5 Q C Batc hNo. : 260 3 La b Sample : 0-MB00 1 Sampl e Size : Sampl e Dat e Extracted : 8-Dec-0 9 Dat e Analyze dDB-5 : 9-Dec-0 9 Dat e Analyze dDB-225 : N A Analyt e Cone . (pg/Sample ) D L aEMP C bQualifier s Labele dStandar d % R LCL-UCL dQualifier s 2,3,7,8-TCD D N D 0.48 0 I S 13C-2,3,7,8-TCD D 90. 8 4 0
- 13 5 1,2,3,7,8-PeCD D N D 0.66 4 13C-l,2,3,7,8-PeCD D 87. 1 4 0
- 13 5 1,2,3,4,7,8-HxCD D N D 0.85 7 13C-1,2,3,6,7,8-HxCD D 92. 6 40-13 5 1,2,3,6,7,8-HxCD D N D 0.86 1 13C-l,2,3,4,6,7,8-HpCD D 86. 6 4 0 - 13 5 1,2,3,7,8,9-HxCD D N D 0.79 1 13C-OCD D 82. 9 40-13 5 1,2,3,4,6,7,8-HpCD D N D 0.89 8 I3C-2,3,7,8-TCD F 93. 3 4 0
- 13 5 OCD D N D 1.0 3 13C-l,2,3,7,8-PeCD F 86. 3 40-13 5 2,3,7,8-TCD F N D 0.51 6 13C-1,2,3,6,7,8-HxCD F 92. 2 4 0
- 13 5 1,2,3,7,8-PeCD F N D . 0.51 9 13C-1,2,3,4,6,7,8-HpCD F 93. 2 40-13 5 2,3,4,7,8-PeCD F N D 0.54 8 13C-OCD F 84. 5 4 0 - 13 5 1,2,3,4,7,8-HxCD F N D 0.51 2 P S 37Cl-2,3,7,8-TCD D 95. 0 . 70-13 0 1,2,3,6,7,8-HxCD F N D 0.51 3 13C-2,3,4,7,8-PeCD F 97. 4 70-13 0 2.3,4,6,7,8-HxCD F N D 0.55 0 13C-1,2,3,4,7,8-HxCD D 98. 1 7 0
- 13 0 1,2.3,7,8,9-HxCD F N D 0.56 1 13C-1,2,3,4,7,8-HxCD F 95. 7 7 0 - 13 0 1.2.3.4.6,7,8-HpCD F N D 0.58 4 13C-l,2,3,4,7,8,9-HpCD F 92. 4 7 0
- 13 0 l.2,3.4,7,S,9-HpCD F N D 0.64 8 A S 13C-l,2,3,7,8,9-HxCD F 10 1 4 0 - 13 5 OCD F N D 0.95 0 Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat a e Tota l TCD D N D 0.48 0 T E Q (Min-Max) : 0 - 1 . 6 5 Tota l PeCD D N D 0.66 4 Tota l HxCD D N D 0.83 6 

## a . Sampl e specifi cestimate d detectio n limi t Tota l HpCD D N D 0.89 8 

## b . Estimate d niaximur

n

## possibl e concentration

. Tota l TCD F N D 0.51 6 

## c . Metho d detectio n limit . Tota l PeCD F N D 0.53 4 

## d . Lowe rcontro l limi t- uppe rcontro l limit . Tota l HxCD F N D 0.53 4 

## e . TE Q base d o n (1989 ) Internationa l Toxi cEquivalen tFactor s (ITEF) . Tota l HpCD F N D 0.61 6 

## Analys tJM H

## Approve d By : Willia mJ . Luksembur g 17-Dec-200 9 13:5 5
Projec t 3224 4 Pag e 4 o f 1 8 

# VES01863 4

# vist a OP RResult s Metho d 0023 A Matrix : M

M 5 Q C Batc h No. : 260 3 

## La b Sample : 0-OPR00 1 

## Sampl e Size : Sampl e Dal e

## Extracted : 8-Dec-0 9 Dat e Analyze dDB-5 : 9-Dec-0 9 Dat e Analyze dDB-225 : N A Analyt e Spik e Cone . Cone . (ng/mL ) O P RLimit s Labele dStandar d % R LCL-UC LQualifie r 2,3,7,8-TCD D 2.5 0 2.4 4 1.7 5 - 3.2 5 I S 13C-2,3,7,8-TCD D 93. 5 4 0
- 13 5 1,2,3,7,8-PeCD D 12. 5 12. 5 8.7 5 - 16 .2 5 13C-l,2,3,7,8-PeCD D 89. 0 40-13 5 1,2,3,4,7,8-HxCD D 12. 5 12. 4 8.7 5 - 16 .2 5 I3C-l,2,3,6,7,8-HxCD D 90. 1 40-13 5 1,2,3,6,7,8-HxCD D 12. 5 12. 7 8.7 5 - 16 .2 5 13C-1,2,3,4,6,7,8-HpCD D 87. 7 4 0
- 13 5 1,2,3,7,8,9-HxCD D 12. 5 12. 7 8.7 5 - 16.2 5 I3C-OCD D 85. 1 40-13 5 1,2,3,4,6,7,8-HpCD D 12. 5 12. 2 8.7 5 - 16.2 5 13C-2,3,7,8-TCD F 93. 3 4 0
- 13 5 OCD D 25. 0 24. 5 17. 5 - 32. 5 13C-l,2,3,7,8-PeCD F 87. 6 4 0
- 13 5 2,3,7,8-TCD F 2.5 0 2.5 2 1.75-3.2 5 l3C-l,2,3,6,7,8-HxCD F 90. 4 4 0
- 13 5 1,2,3,7,8-PeCD F 12. 5 12. 5 8.75-16.2 5 13C-1,2,3,4,6,7,8-HpCD F 95. 8 40-13 5 2,3,4,7,8-PeCD F 12. 5 12. 7 8.7 5 - 16.2 5 13C-OCD F 88. 8 4 0
- 13 5 1,2,3,4,7,8-HxCD F 12. 5 12. 6 8.7 5 - 16.2 5 A S 13C-l,2,3,7,8,9-HxCD F 99. 5 4 0
- 13 5 1,2,3,6,7,8-HxCD F 12. 5 12. 5 8.7 5 - 16.2 5 2,3,4,6,7,8-HxCD F 12. 5 12. 9 8.7 5 - 16.25 . 1,2,3.7,8.9-HxCD F 12. 5 12. 7 8.7 5 - 16.2 5 1,2,3,4,6,7,8-HpCD F 12. 5 12. 6 8.75-16.2 5 1,2,3,4,7,8,9-HpCD F 12. 5 11. 5 8.7 5 - 16.2 5 OCD F 25. 0 24. 3 17. 5 - 32. 5 

## Analyst : JM H

## Approve d By : Willia mJ . Luksembur g 17-Dec-200 9 13:5 5

Projec t 3224 4 Pag e 5 o f 1 8 

# VES01863 5Sampl e ID : 

## CPT-U3-M23A-XAD-R 1 Method 0023 A Clien tDat a 

## Name : Project : Dat e Collected : Tim e Collected : AECO M Environmen t 6013321 6 l-Dec-0 9 N A Sampl e

## Dat a Matrix : MM 5 Sampl e Size : Sampl e 

## Laborator

y Dat a La b Sample : Q C Batc h No. . Dal e Analyze d DB- 5 32244-00 1 

## Dat

e Received : 4-Dec-0 9 260 3 Dal



## < : Extracted

: 8-Dec-0 9 9-Dec-0 9 

## Dal

« Analyze d DB-225 : 10-Dec-0 9 Analyt e Cone . (pg/Sample ) D L EMPC U 

### Qualifier s Labele dStandar d % R LCL-UC L J I S 13C -2,3,7,8-TCD D 86. 4 4 0
- 13 5 J 13C -l,2,3,7,8-PeCD D 84. 9 4 0 - 13 5 J 13C -l,2,3,6,7,8-HxCD D 89. 0 4 0 - 13 5

13C -l,2,3,4,6,7,8-HpCD D 84. 6 4 0 - 13 5

. 1 13C -OCD D 77. 4 4 0
- 13 5

13C -2,3,7,8-TCD F 88. 2 4 0 - 13 5 13C -l,2,3,7,8-PeCD F 82. 2 4 0
- 13 5 13C -l,2,3,6,7,8-HxCD F 88. 9 4 0 - 13 5 J 13C -l,2,3,4,6,7,8-HpCD F 88. 7 4 0
- 13 5

13C-OCD F 80. 4 4 0
- 13 5 P S 37Cl-2,3,7,8-TCD D 94. 4 7 0
- 13 0 P 13C-2,3,4,7,8-PeCD F 95. 7 7 0 - 13 0

I 3 C-I ,2,3,4,7,8- HXCD D 92. 0 7 0
- 13 0 J 1 3 C-1,2,3,4,7,8-HxCD F 89. 0 7 0
- 13 0

13C-l,2,3,4,7,8,9-HpCD F 86. 0 7 0
- 13 0 J A S 13C-l,2,3,7,8,9-HxCD F 90. 5 4 0
- 13 5 2,3,7,8-TCD D 4.6 7 1,2,3,7,8-PeCD D 24. 2 1,2,3,4,7,8-HxCD D 26. 4 1.2.3.6.7.8
- HxCD D 58. 7 1.2.3.7.8.9
- HxCD D 36. 9 1,2,3,4,6,7,8-HpCD D 40 5 OCD D 53 7 2,3,7,8-TCD F33. 3 1,2,3,7,8-PeCD F45. 5 2,3,4,7,8-PeCD F97. 6 1,2,3,4,7,8-HxCD F71. 5 1.2,3,6,7,8-HxCD F60. 8 2.3.4.6.7.8
- HxCD F82. 6 1.2.3.7.8.9
- HxCD F19. 9 1.2.3.4.6.7.8
- HpCD F23 2 1.2.3.4.7.8.9
- HpCD F22. 8 OCD F84. 3 Total s Tota l TCD D Tota l PeCD D Tota l HxCD D Tota l HpCD D Tota l TCD F Tota l PeCD F Tota l HxCD F Tota l HpCD F 247 0 199 0 487 0 99 1 126 0 111 0 69 4 33 4 Toxi c Equivalen t Quotien t

(TEQ ) Dat a

127 0 T E Q (Min-Max) : 11 4 - 11 4



## a . Sampl e specifi cestimate d detectio n limi t b : Estimate d maximu m possibl e concentration

. c . Metho d detectio n limit . d . Lowe rcontro l limi t- uppe rcontro l limit . e . TE Q base d o n (1989 ) Internationa l Toxi cEquivalen tFactor s (ITEF) . Analyst : JM H Approve d By : Willia mJ . Luksembur g I7-Deo200 9 13:5 5

cc t 3224 4 PA 

### ^ 6 O F 1 8 

# VES01863 6

### Sampl e ID : 

## CPT-U3-M23A-PF-R 1 Metho d 0023 A Clien t Dat a Sampl e Data Laborator y Data 

## Name : AECO M Environmen t 

## Project : 6013321 6 

## Dat e Collected : 1 -Dec-0 9 

## Tim e Collected : N A Matrix : Sampl e Size . M M 5 Sampl e 

## La

b Sample . 32244-00 2 

## Q C Batc h No. : 

### 260 3 

## Dat e Analyze d DB-5 " 9-Dec-0 9 

## Dat

e Received : Dat e Extracted : Dat e Analyze d DB-225 : 4-Dec-0 9 8-Dec-0 9 N A Analyt e Cone . (pg/Sample ) D L a 

### EMPC b 

### Qualifier s Labele dStandar d % R LCL-UCL d 

### Qualifier s 2,3,7,8-TCD D N D 0.64 4 I S 13C-2,3,7,8-TCD D 90. 0 4 0 - 13 5 1,2,3,7,8-PeCD D N D 0.91 8 13C-l,2,3,7,8-PeCD D 86. 0 4 0 - 13 5 1,2,3,4,7,8-HxCD D N D 0.84 4 13C-l,2,3,6,7,8-HxCD D 87. 9 4 0 - 13 5 1,2,3,6,7,8-HxCD D N D 0.84 8 13C -l ,2,3,4,6,7,8-HpCD D 83. 7 4 0
- 13 5 1,2,3,7,8,9-HxCD D N D 0.77 9 13C-OCD D 79. 0 4 0 - 13 5 1,2,3,4,6,7,8-HpCD D N D 1.1 1 13C-2,3,7,8-TCD F 91. 1 4 0
- 13 5 OCD D 3.4 6 J 13C-l,2,3,7,8-PeCD F 85. 2 4 0
- 13 5 2,3,7,8-TCD F N D 0.59 5 13C -l ,2,3,6,7,8-HxCD F 87. 6 4 0
- 13 5 1,2,3,7,8-PeCD F N D 0.67 0 13C -l ,2 s 

### 3,4,6,7,8-HpCD F 87. 7 4 0
- 13 5 2,3,4,7,8-PeCD F N D 0.70 8 13C-OCD F 81. 1 4 0
- 13 5 1,2,3,4,7,8-HxCD F N D 0.54 3 E S 37Cl-2,3,7,8-TCD D N A 7 0 - 13 0 H 1,2,3,6,7,8-HxCD F N D 0.54 4 13C-2,3,4,7,8-PeCD F N A 7 0 - 13 0 H 2,3,4,6,7,8-HxCD F N D 0.58 3 13C-l,2,3,4,7,8-HxCD D N A 7 0 - 13 0 H . 1,2,3.7,8,9-HxCD F N D 0.59 5 13C -l ,2,3,4,7,8-HxCD F 0.29 8 7 0 - 13 0 H 1,2,3,4,6,7,8-HpCD F 0.60 0 .1 13C-l,2,3,4,7,8,9-HpCD F N A 7 0 - 13 0 H 1,2,3,4,7,8,9-HpCD F N D 0.74 2 M 13C -l ,2,3,7,8,9-HxCD F 91. 1 4 0
- 13 5 OCD F N D 0.88 6 Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat ae 

### Tota l TCD D 1.0 1 T E Q (Min-Max) : 0.0094 6 - 2.0 5 Tota l PeCD D N D 0.91 8 Tota l HxCD D N D 5.9 6 

## a . Sampl e specifi cestimate d detectio n limi t Tota l HpCD D N D 1.1 1 

## b . Estimate d maximu m possibl e concentration

. Tota l TCD F N D 0.59 5 

## c . Me.tho d detectio n hmit . Tota l PeCD F N D 0.68 9 

## d. Lowe rcontro l limi t- uppe rcontro l limit . Tota l HxCD F N D 0.56 6 0.70 1 

## e TE Q base d o n(1989 ) Internationa l Toxi cEquivalen tFactor s (ITEF ) Tota l HpCD F 0.60 0 

## Approve d By : Willia

m J. Luksembur

g 17-Dec-200

9 13:5 5
Projec t 3224 4 Pag e 7 o f 1 8 

# VES01863 7Sampl e ID : 

## CPT-U3-M23A-XAD-R 2 Metho d 0023 A Clicil l Data Sampl e Data Laborator y Dat a 

## Name : AECO M Environmen t 

## Project : 6013321 6 

## Dat e Collected : 2-Dec-0 9 

## 7'im e Collected : NJ A Matrix : Sampl e Size : M M 5 Sampl e 

## La

b Sample : 32244-00 3 

## Q C Batc h No. . 260 3 

## Dat e Analyze d DB-5 : 9-Dec-0 9 

## Dat

e Received : 4-Dec-0 9 

## Dat e Extracted : 8-Dec-0 9 

## Date s Analyze d DB-22 5 10-Dec-0 9 Analyt e Cone . (pg/Sample ) D L a EMPC b Qualifier s Labele dStandar d % R LCL-UCL dQualifier s 2,3,7,8-TCD D N D 3.0 1 I S 13C-2,3,7,8-TCD D 87. 8 4 0 - 13 5 1,2,3,7,8-PeCD D 16. 2 

## J 13C-l,2,3,7,8-PeCD D 85. 8 4 0
- 13 5 1,2,3,4,7,8-HxCD D 16. 0 

## J 13C-l,2,3,6,7,8-HxCD D 87. 6 4 0 - 13 5 1,2,3,6,7,8-HxCD D 38. 7 

## J 13C-1,2,3,4,6,7,8-HpCD D 89. 0 4 0
- 13 5 1,2,3,7,8,9-HxCD D 26. 1 

## J 13C-OCD D 81. 7 4 0
- 13 5 1,2,3,4,6,7,8-HpCD D 25 2 l3C-2,3,7.8-TCD F 90. 1 4 0
- 13 5 OCD D 32 7 13C-l,2,3,7,8-PeCD F 85. 1 4 0 - 13 5 2,3,7,8-TCD F 25. 0 13C-l,2,3,6,7,8-HxCD F 87. 9 4 0 - 13 5 1,2,3,7,8-PeCD F 30. 9 J 13C-l,2,3,4,6,7,8-HpCD F 91. 6 4 0 - 13 5 2,3,4,7,8-PeCD F 63. 7 13C-OCD F 83. 9 4 0
- 13 5 1,2,3,4,7,8-HxCD F 42. 4 J £ S 37Cl-2,3,7,8-TCD D 10 4 7 0 - 13 0 1,2,3,6.7,8-HxCD F 38. 4 T P 13C-2,3,4,7,8-PeCD F 10 5 7 0 - 13 0 2,3,4,6,7,8-HxCD F 53. 0 13C-l,2,3,4,7,8-HxCD D 10 8 7 0 - 13 0 1.2,3,7,8,9-HxCD F 12. 4 J 13C-l,2,3,4,7,8-HxCD F 10 3 7 0 - 13 0 1,2,3.4,6,7,8-HpCD F 12 2 13C-l,2,3.4,7,8,9-HpCD F 10 5 7 0
- 13 0 1.2,3.4,7.8,9-HpCD F 14. 8 J M 13C-l,2,3,7,8,9-HxCD F 90. 8 4 0 - 13 5 OCD F 44. 8 J Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat ae Tota l TCD D 272 0 273 0 T E Q (Min-Max) : 71.0
- 74. 0 Tota l PeCD D 171 0 Tota l HxCD D 491 0 

## a . Sampl e specifi cestimate d detectio n limit . Tota l HpCD D 62 7 

## b . Estimate d maximu m possibl e concentration

. Tota l TCD F S5 2 

## e . Metho d detectio n limi t Tota l PeCD F 70 5 70 9 P 

## d . Lowe rcontro l limi t- uppe rcontro l limit . Tota l HxCD F 42 5 P 

## c . TE Q base d on(l989 ) Internationa l Toxi cE q mvalen tFactor s (ITEF) . Tota l HpCD F IS O 

## Approve d By : Willia mJ . Luksembur g 17-Dec-200 9 13:5 5
Projec t 3224 4 Pag e 8 o f 1 8 

# VES01863 8

# vist a Sampl e ID : 

## CPT-U3-M23A-PF-R2 Method 0023 A Clien tData Sampl e Dat a 

## Laborator y Dat a 

## Name : AECO M Environmen t 

## Project : 6013321 6 

## Dat e Collected : 2-Dec-0 9 

## Tim e Collected : N A Matrix : Sampl e Size : M M 5 Sampl e 

## La

b Sample . 32244-00 4 

## Q C Batc h No. : 260 3 

## Dat e Analyze d DB-5 : 10-Dec-0 9 

## Dat

e Received : Dat e Extracted : Dal e Analyze d DB-225 : 4-Dec-0 9 8-Dec-0 9 N A Analyt e Cone . (pg/Sample ) D L a EMPC b Qualifier s Labele dStandar d % R LCL-UCL d Qualifier s 2,3,7,8-TCD D N D 0.59 2 i § 13C-2,3,7,8-TCD D 83. 1 4 0
- 13 5 1,2,3,7,8-PeCD D N D 0.84 1 I3C-1,2,3,7,8-PeCD D 84. 0 4 0
- 13 5 1,2,3,4,7,8-HxCD D N D 1.3 1 13C-l,2,3,6,7,8-HxCD D 83. 8 40-13 5 1,2,3,6,7,8-HxCD D N D 1.3 1 13C-1,2,3,4,6,7,8-HpCD D 80. 1 4 0
- 13 5 1,2,3,7,8,9-HxCD D N D 1.2 1 13C-OCD D 76. 1 4 0
- 13 5 1,2,3,4,6,7,8-HpCD D N D 1.2 4 13C-2,3,7,8-TCD F 81. 8 4 0
- 13 5 OCD D 3.3 1 J 13C-1,2,3,7,8-PeCD F 81. 4 4 0
- 13 5 2,3,7,8-TCD F N D 0.80 5 13C
- 1,2,3,6,7,8-HxCD F 82. 6 4 0
- 13 5 1,2,3,7,8-PeCD F N D 0.85 7 13C
- 1,2,3,4,6,7,8-HpCD F 84. 6 4 0 - 13 5 2,3,4,7,8-PeCD F N D 0.90 5 13C-OCD F 77. 3 4 0 - 13 5 1,2,3,4,7,8-HxCD F N D 0.75 4 P S 37CI-2,3,7,8-TCD D N A 7 0 - 13 0 H 1,2,3,6,7,8-HxCD F N D 0.75 5 13C-2,3,4,7,8-PeCD F N A 7 0 - 13 0 H 2,3,4,6,7,8-HxCD F N D 0.80 9 l3C-l,2,3,4,7,8-HxCD D N A 7 0 - 13 0 H 1,2,3,7,8,9-HxCD F N D 0.82 6 13C-l,2,3,4,7,8-HxCD F N A 7 0 - 13 0 H 1,2,3,4,6,7,8-HpCD F N D 0.76 1 l3C-l,2,3,4,7,8,9-HpCD F N A 7 0 - 13 0 H 1.2,3,4.7,8,9-HpCD F N D 0.84 4 A S 13C-l,2,3,7,8,9-HxCD F 88. 5 4 0
- 13 5 OCD F N D 1.1 4 Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat ae Tota l TCD D 0.96 8 T E Q (Min-Max) : 0.0033 1 - 2.3 2 Tota l PeCD D N D 0.84 1 Tota l HxCD D 6.3 9 

## a . Sampl e specifi cestimate d detectio n limit . Tota l HpCD D N D 1.2 4 

## b Estimate d maximu m possibl e concentration

. Tota l TCD F N D 0.80 5 

## c . Metho d detectio n limit . Tota l PeCD F N D 0.88 1 

## d . Lowe rcontro l limi t- uppe rcontro l limit . Tota l HxCD F N D 0.78 6 

## e TE Q base d o n (1989 ) Internationa l Toxi cEquivalen tFactor s (ITEF) . Tota l HpCD F N D 0.80 2 

## Approve d By : Willia mJ . Luksembur g 17-Dec-200 9 13:5 5
Pag e 9 o f 1 8 

# VES01863 9

# vist a Sampl e ID : 

## CPT-U3-M23A-XAD-R 3 Metho d 0023 A Clien tDat a 

### Sampl e Data 

## Laborator y Dat a 

## Name : AECO M

## Environmen t Project : 6013321 6 

## Dat e Collected : 3-Dec-0 9 

## Tim e Collected : Matrix : Sampl e Size . M M 5 Sampl e 

## La

b Sample : 32244-00 5 

## Q C Batc h No. : 260 3 

## Dat e Analyze d DB- 5 j 0-Dec-0 9 

## Dat

e Received : 4-Dec-0 9 

## Dat e Extracted . 8-Dec-0 9 

## Date s Analyze d DB-225 : 10-Dec-0 9 Analyt e Cone . (pg/Sample ) D L a 

### EMPC b 

### Qualifier s Labele dStandar d % R LCL-UCL d

### Qualifier s 2,3,7,8-TCD D N D 3.8 6 I § 13C-2,3,7,8-TCD D 82. 0 4 0 - 13 5 1,2,3,7,8-PeCD D 20. 3 

## j 13C -l ,2,3,7,8-PeCD D 79. 9 4 0 - 13 5 1,2,3,4,7,8-HxCD D 17. 0 1 13C-l,2,3,6,7,8-HxCD D 82. 1 4 0 - 13 5 1,2,3,6,7,8-HxCD D 40. 3 

## J !3C-l,2,3,4,6,7,8-HpCD D 79. 0 4 0 - 13 5 1,2,3,7,8,9-HxCD D 25. 6 J 13C-OCD D 72. 8 40-13 5 1,2,3,4,6,7,8-HpCD D 26 8 13C-2,3,7,8-TCD F 83. 0 4 0 - 13 5 OCD D 33 9 13C-l,2,3,7,8-PeCD F 79. 1 4 0 - 13 5 2,3,7,8-TCD F 30. 0 13C-l,2,3,6,7,8-HxCD F 81. 7 4 0 - 13 5 1,2,3,7,8-PeCD F 38. 3 J 13C-l,2,3,4,6,7,8-HpCD F 81. 2 4 0 - 13 5 2,3.4.7.8-PeCD F 88. 0 13C-OCD F 75. 7 4 0 - 13 5 1,2,3,4,7,8-HxCD F 50. 7 E S 37CI-2,3,7,8-TCD D 99. 4 7 0 - 13 0 1,2,3,6,7,8-HxCD F 48. 7 J 13C-2,3,4,7,8-PeCD F 10 1 7 0 - 13 0 2,3,4,6,7,8-HxCD F 69. 5 P 13C-l,2,3,4,7,8-HxCD D 10 1 70-13 0 1,2,3,7,8,9-HxCD F 15. 0 J 13C-l,2,3,4,7,8-HxCD F 98. 3 7 0 - 13 0 1.2,3,4,6,7.8-lIpCD F 12 6 13C-l,2,3,4,7,8,9-HpCD F 90. 8 7 0 - 13 0 1.2,3,4,7,8,9-HpCD F 14. 4 J A S l3C-l,2,3,7,8,9-HxCD F S6. 6 4 0
- 13 5 OCD F 37. 6 J Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat ae 

### Tota l TCD D 401 0 T E Q (Min-Max) : 90. 2 - 94. 0 Tota l PeCD D 209 0 Tota l HxCD D 806 0 

## a . Sampl e specifi cestimate d detectio n limit . Tota l HpCD D 63 9 

## b . Estimate d maximu m possibl e concentration

. Tota l TCD F 124 0 

## cMelho d detectio n limitTota l PeCD F 101 0 P 

## d Lowe rcontro l limi t- uppe rcontro l limit . Tota l HxCD F 54 7 P 

## e TE Q base d o n(1989 ) Internationa l Toxi cEquivalen tFactor s (1TEF) . Tota l HpCD F 18 9 

## Analyst : JM H ApprovedBy : Willia

m J . Luksembur

g 17-Dec-200 9 13:5 5
Projec t 3224 4 Pag e 1 0 o f 1 8 

# VES01864 0

# vist a Sampl e ID : 

## CPT-U3-M23A-PF-R3 Metho d 0023 A Clien tDat a S^moJe Data Laborator y Dat a 

## Name : AECO M Environmen t 

## Project : 6013321 6 

## Dat e Collected : 3-Dec-0 9 

## Tim e Collected . M A Matrix : Sampl e Size : MM 5 Sampl e 

## La

b Sample : 32244-00 6 

## Q C Batc h No . 260 3 

## Dat e Analyze d DB-5 : 10-Dec-0 9 

## Dat

e Received : Dat e Extracte d Dat e Analyze d DB-22 5 4-Dec-0 9 8-Dec-0 9 N A Analyt e Cone . (pg/Sample ) D L a EMPC b Qualifier s Labele dStandar d % R LCL-UCL d Qualifier s 2,3,7,8-TCD D N D 0.73 8 I S 13C-2,3,7,8-TCD D 79. 1 4 0
- 13 5 1,2,3,7,8-PeCD D N D 1.1 4 13C-l,2,3,7,8-PeCD D 76. 9 4 0
- 13 5 1,2,3,4,7,8-HxCD D N D 1.1 3 13C-l,2,3,6,7,8-HxCD D 79. 3 4 0
- 13 5 1,2,3,6,7,8-HxCD D N D 1.1 4 13C-1,2,3,4,6,7,8-HpCD D 75. 0 4 0
- 13 5 1,2,3,7,8,9-HxCD D N D 1.0 5 13C-OCD D 72. 1 4 0
- 13 5 1,2,3,4,6,7,8-HpCD D 3.5 4 

## J 13C-2,3,7,8-TCD F 79. 1 4 0
- 13 5 OCD D 8.9 8 

## J !3C-l,2,3,7,8-PeCD F 75. 5 4 0
- 13 5 2,3,7,8-TCD F N D 0.85 0 13C-1,2,3,6,7,8-HxCD F 78. 8 4 0
- 13 5 1,2,3,7,8-PeCD F N D 0.90 7 13C-l,2,3,4,6,7,8-HpCD F 78. 0 4 0
- 13 5 2,3,4,7,8-PeCD F N D 0.95 8 13C-OCD F 73. 9 4 0 - 13 5 1,2,3,4,7,8-HxCD F N D 0.84 4 £ S 37Cl-2,3,7,8-TCD D N A 7 0 - 13 0 H 1,2,3,6,7,8-HxCD F 1.1 2 .1 13C-2,3,4,7,8-PeCD F N A 7 0 - 13 0 H 2,3,4,6,7,8-HxCD F 1.5 6 . 1 13C-l,2,3,4,7,8-HxCD D N A 7 0
- 13 0 H 1.2,3,7.8,9-HxCD F N D 0.82 0 13C-l,2,3,4,7,8-HxCD F N A 7 0 - 13 0 H 1,2,3,4,6,7,8-HpCD F 4.9 6 J 13C-l,2,3,4,7,8,9-HpCD F N A 7 0
- 13 0 H 1.2.3.4,7,8,9-HpCD F N D 1.2 6 A S 13C-1,2,3,7,8,9-H\CD F 81. 2 4 0
- 13 5 OCD F N D 2.5 6 Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat ae Tota l TCD D N D 1.2 8 T E Q (Min-Max) : 0.36 2 - 2.7 9 Tota l PeCD D N D 1.1 4 Tota l HxCD D 10. 7 

## a. Sampl e specifi cestimate d detectio n limit . Tota l HpCD D 3.5 4 6.6 4 

## b . Estimate d maximu m possibl e concentratio

n Tota l TCD F N D 1.7 5 

## c . Metho d detectio n limit . Tota l PeCD F N D 0.93 2 

## d Lowe rcontro l limi t- uppe rcontro l limit . Tota l HxCD F 4.9 5 9.5 3 

## e TE Q base d o n (1989 ) Internationa

l Toxi cEquivalen tFactor s (ITEF ) Tota l HpCD F 4.9 6 

## Approve d By : Willia

m J . Luksembur

g 17-Dec-200

9 13:5 5
Projec t 3224 4 Pag e 1 1 o f 1 8 

# VES01864 1

# vist a Sampl e ID : 

## CPT-U3-M23A-F B Merho d 0023 A Clien t Dat a Sampl e Data Laboratoc vDat a 

## Name : AECO M Environmen t 

## Project : 6013321 6 

## Dat e Collected : 3-Dec-0 9 

## Tim e Collected : N A Matrix : Sampl e Size : MM 5 Sampl e 

## La

b Sample : 32244-00 7 

## Q C Batc h No. : 260 3 

## Dat e Analyze d DB-5 . 9-Dec-0 9 

## Dat

e Received . 4-Dec-0 9 

## Dat e Extracted : 8-Dec-0 9 

## Dat e Analyze d DB-225 : \J A Analyt e Cone . (pg/Sample ) D L a EMPC b Qualifier s Labele dStandar d % R LCL-UCL dQualifier s 2,3,7,8-TCD D N D 0.85 5 I S 13C-2,3,7,8-TCD D 86. 0 4 0
- 13 5 1,2,3,7,8-PeCD D N D 1.1 1 13C-l,2,3,7,8-PeCD D 84. 3 4 0 - 13 5 1 ,2,3,4,7,8-HxCD D N D 0.97 5 13C-l,2,3,6,7,8-HxCD D 85. 1 4 0
- 13 5 1 ,2,3,6,7,8-HxCD D N D 0.97 9 13C-1,2,3,4,6,7,8-HpCD D 83. 0 4 0
- 13 5 1 ,2,3,7,8,9-HxCD D N D 0.90 0 13C-OCD D 78. 1 4 0
- 13 5 1,2,3,4,6,7,8-HpCD D 3.2 8 J 13C-2,3,7,8-TCD F 85. 6 4 0
- 13 5 OCD D 11. 6 1 13C-l,2,3,7,8-PeCD F 80. 9 4 0 - 13 5 2,3,7,8-TCD F N D 0.81 7 13C-1,2,3,6,7,8-HxCD F 85. 4 4 0
- 13 5 1 ,2,3,7,8-PeCD F 0.99 7 1 13C
- 1,2,3,4,6,7,8-HpCD F 83. 7 4 0
- 13 5 2,3,4,7,8-PeCD F 2.0 0 J 13C-OCD F 79. 9 4 0
- 13 5 1 ,2,3,4,7,8-HxCD F 1.9 4 1 £ S 37CI-2,3,7,8-TCD D 10 4 7 0
- 13 0 1,2,3,6,7,8-HxCD F N D 0.92 5 13C-2,3,4,7,8-PeCD F 10 9 7 0 - 13 0 2,3,4,6,7,8-HxCD F N D 1.1 9 13C-l,2,3,4,7,8-HxCD D 11 1 7 0
- 13 0 1,2,3,7,8,9-HxCD F N D 0.65 9 !3C-l,2,3,4,7,8-HxCD F 10 7 7 0 - 13 0 1,2,3,4,6,7,8-HpCD F 3.7 4 

## J 13C-l,2,3,4,7,8,9-HpCD F 10 9 7 0
- 13 0 1,2,3,4,7.8,9-HpCD F N D 0.95 8 A S 13C-l,2,3,7,8,9-HxCD F 92. 8 4 0
- 13 5 OCD F 1 .9 5 

## J Total s Toxi c Equivalen t Quotien t

(TEQ ) Dat ae Tota l TCD D 2.4 8 T E Q (Min-Max) : 1 .3 3 - 3 .3 9 Tota l PeCD D N D 1.3 6 Tota l HxCD D 3.7 9 

## a . Sampl e specifi cestimate d detectio n limit . Tota l HpCD D 6.1 5 

## b . Estimate d maximu m possibl e concentration

. Tota l TCD F 24. 6 27. 8 

## cMetho d detectio n limi t Tota l PeCD F 14. 0 19. 0 

## d : Lowe rcontro l limit - uppe rcontro l limit . Tota l HxCD F 9.4 2 11. 5 

## e . TE Q base d o n (1989 ) 

## Internationa

l Toxi cEquivalen tFactor s (ITEF) . Tota l HpCD F 3.7 4 

## Approve d By : Willia

m S. Luksembur

g 17-Dec-200

9 13:5 5
Projec t 3224 4 Pag e 1 2 o f 1 8 

# VES01864 2

## APPENDI X

rojcc l 3224 4 Pag e 1 3 o fI K 

# VES01864 3

# DAT A QUALIFIER S & ABBREVIATION S
B Thi

s compoun

d wa s als o detecte d in th e metho d blank. D Dilutio

n E Th

e amoun tdetecte d i s abov e th e High Calibration Limit. PTh

e amoun treporte d i s th e maximu

m possibl

e concentratio

n du e t o possibl e chlorinate

d diphenylethe

rinterference. HRecover

y wa s outsid e laborator

y acceptanc

e limits . I Chemica l Interferenc

e J Th

e amoun tdetecte d i s belo w th e LowCalibration Limit. * Se

e Cove rLetter Cone . Concentratio n D L Sample-specifi cestimate

d detectio

n limi t MD L Th

e minimu

m concentratio

n o f asubstanc

e tha tca n b e measure

d an d reporte d wit h 99 % confidenc

e tha tth e analyt e concentratio

n i s greate r tha n zer o in th e matri x tested. EMP C Estimate d Maximu

m Possibl

e Concentratio

n N A No

tapplicabl

e R L Reportin g Limi t- concentration s tha tcorrespon

d t o lo wcalibratio

n poin t N D No

tDetecte d TE Q Toxi

cEquivalenc

y
Unless otherwis

e noted , soli d sampl e result s ar e reporte

d in dr y weight . Tissu e sample s ar e reporte d i n we tweight .

Projec t 3224 4 Pan e N o f I X 

# VES01864 4

# Vist a CERTIFICATION S
Accreditin g Authorit y Certificat e Numbe r Stat e o fAlaska , DE C CA413-200 8 Stat e o fArizon a AZ063 9 Stat e o fArkansas , DE Q 08-043- 0 Stat e ofArkansas , DO H Reciprocit ythroug h C A Stat e o fCaliforni a - NELA P Primar yA A 02102C A Stat e o fColorad o N/ A Stat e o fConnecticu t PH-018 2 Stat e o fFlorida , DE P E8777 7 Stat e o fIndian a Departmen t o fHealt h C-CA-0 2 Commonwealth.o fKentuck y 9006 3 Stat e o fLouisiana , Healt h an d Hospital s LA0800 0 Stat e o fLouisiana , DE Q 0197 7 Stat e o fMain e 200802 4 Stat e o fMichiga n 993 2 Stat e o fMississipp i Reciprocit ythroug h C A Nava l Facilitie s Engineerin g Servic e Cente r NFESC41 3 Stat e o fNevad a CA004132007 A Stat e o fNe wJerse y CA00 3 Stat e o fNe wMexic o Reciprocit ythroug h C A Stat e o fNe wYork , DO H 1141 1 Stat e o fNort h Carolin a 0670 0 Stat e o fNort h Dakota , DO H R-07 8 Stat e o fOklahom a D991 9 Stat e o fOrego n CA200001-00 6 Stat e o fPennsylvani a 68-0049 0 Stat e o fSout h Carolin a 8700200 1 Stat e o fTennesse e TN0299 6 Stat e o fTexa s T104704189-08-T X U.S
. Arm yCorp s o fEngineer s N/ A Stat e o fUta h CA1640 0 Commonwealt h o fVirgini a 0001 3 Stat e o fWashingto n C128 5 Stat e o fWisconsi n 99803616 0 Stat e o fWyomin g 8TMS- Q

Projec t 3224 4 Pag e 1 5 o fI X 

## VES01864 5

# Sampl e Traceabiiit y Lis t Q

# ^ ^fafr^ f AECO M Sit e of Program : VeoliaE S Tec h Sampl e Date : YL ~i\T IZ./R/O I ProjectLocation : Sauget , I L La

b PO #' : Typ e o f Program : CP T Dat e Shipped : \'2 .^a/o c 

### i Laboratory : Vist aAnalytica

l E l Dorad o Hills, C A Projec t# : . 60133216 Shipper/ Steve n Mil o Recovery : Jef f Gorma n Laboratory : Vist aAnalytica

l E l Dorad o Hills, C A Progra m Office : Syracuse N Y Shipper/

Steve n Mil o Recovery : Jef f Gorma n Laboratory : Vist aAnalytica

l E l Dorad o Hills, C A Progra m Contact : Jef f Gorma n FedE xAi rBil l # : He m Sampl e I D Code Sampl e Matri x Sampl e Descriptio

n Analytica l Parameter

s Specia l Instruction

s 1 CPT -U3 -M23A-XAD -R 1 XAD2 RESI N M2

3 XAD Resin Trap , Ru

n 1 PCDDs/PCDF s EPA 0023 A 2 

### CPT -U3 -M23A -PF-R 1 FILTER M2 3 P M Filter , Ru n 1 PCDDs/PCDF s EPA 0023 A 3 4 

### CPT -U3-M23A-XAD-R 2 XAD2 RESI N M2

3 XAD Resi

n Trap , Ru

n 2 PCDDs/PCDF s EP A 0023 A 5 CPT -U3 -M23A-PF -R 2 FILTER M2 3 P M Filter , Ru n 2 PCDDs/PCDF s EP A 0023 A 6 7 CPT -U3 -M23A-XAD -R 3 XAD2 RESI N M2

3 XAD Resi

n Trap , Ru

n 3 PCDDs/PCDF s 8 

### CPT -U3-M23A -PF -R 3 FILTER M2 3 P M Filter , Ru n 3 PCDDs/PCDF s 9 10 

### CPT -M23A-PF -F B FILTER Particulat e Filte rFiel d Blan k PCDDs/PCDF s EPA 0023 A 1 1 CPT-M23A-XAD -F B XAD 2 RESI N Xad Resi

n Tra p Fiel d Blan k PCDDs/PCDF s EPA 0023 A 1 2 CPT-M23 A



## Fiel d Blan k AcetonG/MeClaToluen s 

### M2 3 Blan k PCDDs/PCDF s EPA0023 A 1 3 1 4 

## CPT-U3-M23A-FHR-R 1 Acetone/MeClz/Toluen e 

### M23 A Fron tHal f Rinse , Ru

n 1 PCDDs/PCDF s EPA 0023 A 1 5 

### CPT -U3-M23A -FHR -R 2 Acetone /MeCl2/Toluen

9 M23

A Fron tHal f Rinse , Ru

n 2 PCDDs/PCDF s EPA 0023 A 1 6 

### CPT -U3 -M23A -FHR-R 3 Acetone/MeClyToluen e 

### M23 A Fron tHal f Rinse , Ru

n 3 PCDDs/PCDF s EPA 0023 A 1 7 1 8 

### CPT -U3-M23A-BHR-R 1 Acetone/MeClj/Toluen e 

### M23 A Bac kHal f Rinse, Ru

n 1 PCDDs/PCDF s EP A 0023 A 1 9 

### CPT-U3 -M23A -BHR-R 2 Acetone/MeClyToluen e 

### M23 A Bac kHal f Rinse, Ru

n 2 PCDDs/PCDF s EPA 0023 A 2 0 

### CPT -U3 -M23A -BHR-R 3 Acelone/MeClyToluen e 

### M23 A Bac kHal f Rinse , Ru

n 3 PCDDs/PCDF s EP A 0023 A Fiel d 

### Notes

/ Comment

s Page 1 o f 1 Relinquishe d 

### B y(print) : Date : Steven Milo /2 / 3 

### /^7 ' Signature : Time : Relinquishe d By (print) : Date : Signature : Time : Relinquishe d B y (print) : Date : Signature : Time : Receive d b y La b (print) : Date : Signature : Time :
Receive d 

### B y(print) : ' . Date : Sianature : (

### Tirrie : Receive d B y(print) : Date : Signature : Time : Receive d B y (print) : Date : Signature : Time : Analytica l Laborator

y Destination : Receive d 

### B y(print) : ' . Date : Sianature : (

### Tirrie : Receive d B y(print) : Date : Signature : Time : Receive d B y (print) : Date : Signature : Time : Vist aAnalytica

l Laboratories, Inc

. 110 4 Windfiel

d Wa y E l Dorad o Hills, C A 9676

2 Attn : Ms.MarthaMaie

r916-673-1520

. Projec t 3224 4 Pag e 1 6 o f 1 8 

# VES01864 6

## Vist a Projec t # : SAMPL E LOG-I N CHECKLIS T V Vist a
• Analytica l Laborator y 

## TA T 

# Uns>pec Sample s Arrival : Date/Tim e Initials : Location : 

# (jj^pShelf/Rack : N

(Ac Logge d In : Date/Tim e 

# ID?? Initials : Location : ^ Shelf/Rack : R / Delivere d By : /^FedEx N

, C 

# J UP S Ca l DH L * a n d 

## Othe r Delivere d Preservation : Ic e Blu e Ic e Dry.Ic e c 

# (^None,J ) Temp° C 

# AvTlbl -eVl k Time : Q&^J - Thermomete rID : IR -1 YES ^ N O N A Adequat e Sampl e Volum e Received ? 

# \/ Holdin g Tim e Acceptable ? l / Shippin g Container(s ) Intact ? 1 / Shippin g Custod ySeal s Intact ? Shippin g Documentatio n Present ? Airbil l Trk#fl£>%><5ai2 - ^fcff i 

## y Sampl e Containe rIntact ? Sampl e Custod ySeal s Intact ? Chai n o fCustod y/

Sampl e Documentatio n Present ? C O C Anomaly/Sampl e Acceptanc e For m completed ? I fChlorinate d o rDrinkin g Wate rSamples , Acceptabl e Preservation ? 

## A N a 2 

## S 2 

## 0 3 Preservatio n Documented ? Shippin g Containe rVist a j^client^ ) Retai n Return ^ ^SisposeN
.



## Kb

Sample Login 3/200? rml\ 

### Projec t 3224 4 Pag e 1 7 o f1 8 

# VES01864 7

## SAMPL E LOG-I N CHECKLIS T Vist a Projec t # : TA T 

# V Vista w Analytica l Laboratory


## Sample s Arrival : Date/Tim e Initials : Location : Shelf/Rack : M

\fK Logge d In : Date/Tim e Initials : Location : ^ j Shelf/Rack : H

(t\ Delivere d By : 

## f r 

## edExJ UP S Ca l DH L _^. a n d


## . Othe r Delivere d Preservation : V 

## * i5 

## *"" e: 

## ""k: e ^_B!u e Ice^ ) DryIc e Non e Tem p ° C 0°C Time : 

# 0^t>>~. Thermomete rID : IR- 1 YES - N O N A Adequat e Sampl e Volum e Received ? Holdin g Tim e Acceptable ? 

# V Shippin g Container(s ) Intact ? Shippin g Custod ySeal s Intact ? Shippin g Documentatio n Present ? Airbil l Trk # 5 ^ & VV^ ? Sampl e Containe rIntact ? 

# '= 

# D&„eJ\~)€l 0U_- > Sampl e Custod ySeal s Intact ? Chai n o f Custod y/

Sampl e Documentatio n Present ? C O C Anomaly/Sampl e Acceptanc e For m completed ? I fChlorinate d o rDrinkin g Wate rSamples , Acceptabl e Preservation ? Na 2 

## S 2 

## 0 3 Preservatio n Documented ? C O C r Sam 

## P l e

## . (^None J Containe rW-.J-S- ^ Shippin g Containe rVist a Clien t Retai n Retur n Dispos e 

## Comments: 

# f! 3 v 

# 4 /

Projec t

3224 4 mpkL<k>" iuOOTrmh ( j Pag e I K

o f 1 8 

## VES01864 8

# Wast e Fee d

VES01864 9

## 1



# TestAmeric a
TH E LEADE R I N ENVIRONMENTA L TESTIN G 

## TestAmeric aLaboratories,In

c



# ANALYTICA L REPOR T

PROJEC T NO . 6013321 6 Veoli a- ES Tec h Lo t# : H9L09042 3


## i Jef f Gorma n AECOM , In c 510 5 Campuswoo d Driv e Suit e 10 4 Eas tSyracuse , NY 1305 7

TESTAMERIC A LABORATORIES , INC .

Kevi n S . Woodcoc k Projec tManage r

Decembe r28 , 200 9
581 5 Middlebroo kPik e Knoxville, TN 37921 te l 865.291300 0 fa x 865.584.431 5 www.testarnericaincxo m 

# VES01865 0

# ANALYTICA L METHOD S SUMMAR Y H9L09042 3

PARAMETE

R ANALYTICA L METHO D As h Conten t Hea to f

Combustio n Hea to f

Combustio n D586 5 Tota l Chlorin e References : AST M Annua l Boo kO f ASTM Standards . ASTM D482-00 a ASTM D240-0 2 ASTM D5865-0 0 KNO X WC-001 6

KNO X TestAmeric aLaboratorie s Inc. , Knoxvill e Laborator y Standar d

Operatin g Procedur e

## 3 

# SAMPL E SUMMAR Y H9L09042 3 SAMPLE D SAM P W O #SAMPLE * CLIEN T SAMPLE I D DAT E LQQM 7 00 1 HBTU-U3-M2S-R 1 12/01/0 9 LQQN H 002 HBTU-U3-M26-R 2 12/02/0 9 LQQNJ 003 HBTU-U3-M26-R 3 12/03/0 9 LQQN L 00 4 LBTTJ-U3-M26-R 1 12/01/0 9 LQQN N 005 LBTU-03-M26-R 2 12/02/0 9 LQQN P 00 6 LBTU-U3-M26-R 3 12/03/0 9 LQQN T 0.0 7 SF-U3-M26A-R 1 12/01/0 9 LQQN O 00 8 SF-U3-M26A-R 2 12/02/0 9 LQQN 2 009 SF-U3-M26A-R 3 12/03/0 9 LQQH 4 01 0 CS-U3-M2SA-R 1 12/01/0 9 LQQQ R O i l CS-U3-M26A-R 2 12/02/0 9 LQQQ W 01 2 CS-U3-M26A-R 3 12/03/0 9 LQQQ 7 01 3 HBTU-U3-M23A-R 1 12/01/0 9 LQQR M 01 4 HBTU-U3-M23A-R 2 12/02/0 9 LQQR O 01 5 HBTU-U3-M23A-R 3 12/03/0 9 LQQR S 01 6 LBT0-U3-M23A-R 1 12/01/0 9 LQQR 7 01 7 LBTU-U3-M23A-R 2 12/02/0 9 LQQR 8 01 8 LBTU-U3-M23A-R 3 12/03/0 9 LQQTA 01 9 SF-U3-M23A-R 1 12/01/0 9 LQQT G 020 SF-U3-M23A-R 2 12/02/0 9 LQQT D 02 1 SF-U3-M23A-R 3 12/03/0 9 LQQT E 022 CS-U3-M23A-R 1 12/01/0 9 LQQT F 02

3 CS-U3-M23A-R 2 12/02/0 9 LQQT G 024 CS-U3-M23A-R 3 12/03/0 9 HOTE(S )

- Th e anaiyiicai rcsuli s o f

(b e sample s listedabove ar c presentedo nin c followin g pages .

- Al lcalculation s ar

e performe dbefore roundin s 1 0 avoi dround-of

f error s i ncalculate dresults .

- Results note da

s "ND " wer

e no t delecteda

t or above th e state dlimit .

- Thi s report

mus t no t b e reproduced , excep

t i nfull , without

th e writtenapprova l o f

th e laboratory .

- Results fo r

th e rollowin s parameters arc neve r reportedo nadr

y weigh t basis : color , corrosiviiy , density , Jlaslipoiiii , isniiabllliy . layers , odor , pain t fille r test, pll , porosit

y pressure , reactivity , redox potential , specifi c gravity , spot lests , solids , solubiliiy . temperature , viscosity , andweight .



# VES01865 2

## 4 

# PROJEC T NARRATIV E H9L09042 3 Th eresult s reporte d herei n ar eapplicabl

e t o th e sample s submitte

d fo ranalysi s only . This repor

tshal l no tb ereproduce

d excep ti nfull , withou

tth e writte n approva

l ofthe laboratory

. Th eorigina

l chai n o f custod y documentatio

n i s include d wit h thi s report . Sampl e Receip t Ther e wer e n o problem

s wit h th e conditio

n of th e sample s received

. Qualit y Control an

d Dat aInterpretatio

n Unles s otherwis

e noted , al l holdin g time s an d Q C criteri

awer e me tan d th e tes tresult s show n i nthi s repor tmee tal l applicabl

e NELA C requirements

. As h Content

: Th eas h conten to f th esample s wa s determine

d usin g SO Pnumbe rKNOX-WC-001 3 (base d o n AST M Method

s A4422 , D482 , an d E830) . A te

n gra m aliquo to f sampl e i s fired i napre-tare

d crucibl e a t750 ° ±25 ° C i

n aforced-draf

tmuffl e furnace . Th etota l weigh to f as h residu e an d th e crucibl e i s measure

d o n a4-plac e analytica

l balance , an d th e residu e weigh ti s determine

d b y difference

. Th erati o o f th e residu e weigh t(mg ) an d th e initia l sampl e weigh t(kg ) i s use d t o calculat

e th e as h conten tofthe sample

. Theduplicat

e RP D resul tfo rsampl e SF-U3-M23A-R

3 i s outsid e contro l limits. Th

e laborator y contro l sampl e showe d acceptabl

e result s indicatin

g tha tth e analysi s wa s i n control. Th

e duplicat e resul ti s attribute

d t o sampl e heterogeneity

. Gros s Calorifi cValue : Thehea to f combustio

n (gros s calorifi cvalue ) of th esample s wa s determine

d usin g SO P numbe rKNOX-WC-001 0 (base d o nAST M Metho

d D586 5 fo rsolid s an d AST M Metho

d
TesiAmeric

aKnoxvill

e maintain

s th e followin g certifications

, approval

s an d accreditations

: Arkansa s DEQ La b #88 - 0688 , Californi

aDH S ELAPCert

. #2423 , Colorad o DPHE , Connecticu

tDP H La b #PH-0223

, Florid aDO H La b #E87177 , Georgi aDN RLa b #906 , Hawai i DOH , Illinoi

s EP A La b #200012

, Indian aDO H La b SC-TN-02

, Iow aDN R La b #375 , Kansa s DH E Cer t#E-10349

, Kentuck y DE PLa b #90101 , Louisian aDEQ Cert

. #03079 , Louisian aDOHH, Marylan d DO E Cert

. #277 , Michiga n DEQ La

b #9933 . Nevad aDEP, Ne

wJerse y DE PLa b #TN001

, Ne wYor kDO H La b #10781 , Nort h Carolin aDP H La b #21705 , Nort h Carolin aDEHN RCert . #64 , Ohi o EP A VA PLa

b #CL0059

, Oklahom aDEQ La b #9415 , Pennsylvani

aDE PLa b #68-00576

, Sout h Carolin aDHE C Cer

t#84001001

, Tennesse

e DO H La b #02014 , Texa s CEQ , Uta

h DO H La b #QUAN3, Virgini

aDG S La b #00165 , Washingto

n DOE La

b #C1314 , Wes tVirgini aDE PCert . #345 , Wes tVirgini aDHH RCer t#9955C , Wisconsi n DN RLa b #998044300

, Nava l Facilitie s Engineerin

g Servic e Cente ran d USD A Soi l Permi i #S-46424

. Thi s lis tofapproval

s i s subjec tt o chang e an d doe s no t impl y tha tlaborator

y certificatio

n i s availabl e fo ral l parameter

s reporte d i nthi s environmenta

l sampl e dat areport .



# VES01865 3

## 5 

# PROJEC T NARRATIV E H9L09042 3 D24 0 fo rliquids) . A wast

e fee d sampl e i s combuste

d i n a n oxyge n bom b tha tha s bee n place d i n abom b calorimeter

. Th e energ y release d durin g thi s combustio

n proces s i s capture d i n th e calorimeter

, an d th e temperatur

e ris e o f awate rbat h surroundin

g th e bom b i s measured

. Th e temperatur

e ris e i s proportiona

l t o th e hea tliberate d durin g th e combustio

n i n calories

. Th e gros s calorifi cvalu e i s calculate

d ftom th e temperatur

e rise, th e sampl e weight , an d th e calibratio

n coefficien

to f th e calorimeter

. Certai n extraneou

s source s of hea tar e assessed

, an d th e effec to f thes e hea tsource s i s accounte

d fo rin th e calculation

, a s wel l a s th e affec to f variou s accelerant

s tha tar e adde d t o enhanc e combustio

n ofth e sample . Th e gros s hea to f combustio

n i s calculate

d in unit s of cal/ g usin g th e followin

g equation:

Q(gross ) =

## [(AtEE)-(e,4-e 2 

## 4-e 3 + 

## e 4 

## ) ] m Where: Q (gross ) = gros

s calorifi cvalu e a tconstan tvolum e a s determined

, cal/g . E E = th

e hea tcapacit y of th e calorimeter

, cal/°C . A t= correcte

d temperatur

e ris e a s measure

d b y th e calorimeter

, °C . e i= Correctio

n fo rhea to f formatio n of nitri caci d in calories

, calculate

d b y th e calorimete

rbase d o n th e energ y release d b y th e sample . 6 2 = Correctio

n fo rsulfur , whic h i s usuall y 0 . e 3 = Correctio

n fo rfus e wire . e 4 = Correctio

n fo rspik e additio n ma ti s calculate

d b y m e calorimete

rusin g th e spik e weigh tbenzoi caci d equivalen

t(grams ) time s th e benzoi c aci d hea to f combustio

n (631 8 cal/gram). m = mas

s o f th e sample , g . Th e result s ar e converte

d t o Btu/lb, a

s necessar

y usin g th e followin

g conversio

n factor: 1 Btu/l b = 1. 8 cal/gra m Tota l Chlorine : Th e sample s wer e prepare d fo rtota l chlorin e usin g SO Pnumbe rKNOX-WC-001 6 (base d o n AST M Metho

d E44 2 an d SW-84 6 Metho d 5050). Th

e sampl e i s oxidize d b y combustio

n in a n oxyge n flaska tatmospheri

cpressur e o rabom b containin

g oxyge n unde rpressure

. Th e liberate d haloge n compound

s ar e absorbe d primaril

y a s halide s in a sodiu m carbonate/sodiu

m bicarbonat

e buffe rsolution

. Th e combustio

n product

s ar e collecte d b y repeate d rinsing ofthe combustio n apparatus

, an d analyze

d b y io n chromatograph

y in accordanc

e wit h SO PKNOX-WC-0005 (base d o n SW-84 6 Metho d 9056) . Th

e result s ar e calculate

d usin g th e followin

g equation:



# VES01865 4

## 7 

# Q C DATA ASSOCIATIO N SUMMAR

Y H9L09042

3 Sampl e Preparatio n an d Analysi s Contro l Number s
SAMPLE* 00 1
00 2
00 3
00 4
00 5
006
00 7
00 8
00 S
010
01 1 ANALYTICA L MATRI X METHO

D WAST E AST

M D482-00 a WAST E KNO

X WC-001 6 WAST E AST

M D240-0

2 WAST E AST

M D482-00 a WAST E KNO

X WC-001 6 WAST E AST

M D240-02 WAST E AST

M D482-00 a WAST E . KNO

X WC-001 6 WAST E AST

M D24Q-0

2 WAST E AST

M D 4 82-00 a WAST E KNO

X WC-001 6 WAST E AST

M D240-02 WAST E AST

M D482-00 a WAST E KNO

X WC-001 6 WAST E AST

M D240-02 WAST E AST

M D482-00 a WAST E KNO

X WC-001 6 WASTE' AST

M D240-02 WAST E AST

M D482-00 a WAST E KNO

X WC-001 6 WAST E AST

M D240-02 WAST E AST

M D482-00 a WAST E KNO

X WC-001 6 WAST E AST

M D240-02 WAST E AST

M 0482-OO a WAST E KNO

X WC-001 6 WAST E AST

M D240-02 SOLI D AST

M D482-00 a SOLI D KNO

X WC-001 6 SOLI D AST

M D5865-0 0 SOLI D AST

M D482~00a SOLI D KNO

X WC-001 6 SOLI D AST

M D5865-0 Q LEAC H BATC H PRE

P BATC H ft 935149 7 934406 0 934807 5 935149 7 9344060 934807 5 935149 7 934406 0 934807 5 935149 7 934406 0 934807 5 935149 7 934406 0 934807 5 935149 7 934406 0 934807 5 935149 7 934506 4 9348075 935149 7 934506 4 934807 5 935149 7 934506 4 9348075 934546 1 934406 0 935003 2 934546 1 934406 0 935003 2 M

S RUN S

935130 2 934402 7 934804 3

9345036

9345279 934402 7 935002 0 {Continue d on nex tpage )



# VES01865 6

# Q C DATA ASSOCIATIO N SUMMAR

Y H9L090423 . Sample Preparatio n an d analysi s Contro l Number s
SAMPLE* MATRI

X ANALYTICA

L METHO D LEAC H BATC H # PRE P

BATC H 

### M

S RON S 01 2 SOLI

D SOLI D SOLI D AST

M D482-O0a KNO X WC-001 6 AST M D5865-00 934546 1 9344060 935003 2 01 3 WAST

E WAST E WAST E AST

M D482-00 a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 934807 5 01 4 WAST

E WAST E WAST E AST

M D482-00 a KNO X WC-001 6 AST M D240-02 935149 7 9345064 934807 5 

## 01 5 WAST

E WAST E WAST E AST

M D482-00 a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 934807 5 934804

3 01 6 WAST

E WAST E WAST E AST

M D4B2-00a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 9348075 01 7 WAST

E WAST E WAST E AST

M D482-00 a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 9348075 018 WAST

E WAST E WASTE . AST

M D482-0O a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 9348075 01 9 WAST

E WAST E WAST E AST

M D482-00 a KNO X WC-0016. AST M D240-02 935149 7 934506 4 934807 5 02 0 WAST

E WAST E WAST E AST

M D482-00 a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 934807 5 9345036 02 1 WAST

E WAST E WAST E AST

M D4B2-00 a KNO X WC-001 6 AST M D240-02 935149 7 934506 4 9348075 935130 2
02 2 SOLI

D SOLI D SOLI D AST

M D482-00 a KNO X WC-001 6 AST M D5865-00 934546 1 9344060 9350032 (Continue d o

n nex tpage )

## 9 

# Q C DATA ASSOCIATIO N SUMMAR

Y H9L09.042

3 Sampl e Preparatio n an d Analysi s Contro l Number s
SAMPLE S MATRI

X ANALYTICA

L METHO D LEAC H BATC H i t PRE

P BATC H » 02 3 SOLI

D SOLI D SOLI D AST

M D482-00 a KNO X WC-001 6

. AST M D5865-00 934546 1 9344060 935003 2 02 4 SOLI

D SOLI D SOLI D AST

M D482-00 a KNO X WC-0016. AST M D5865-00 ' 934546 1 9344060 935003 2



# VES01865 8