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## Jnne 10, 2009
To: Mr. Jeff Telander U.S. EPA Mailroom (13243-02) U. S. Environmental Protection Agency 109 T.W. Alexander Drive Research Triangle Park, N.C. 27711 Re: Emissions Tests Dear Mr. Telander, Enclosed are the Emission Test Results that were performed at StonePeak Ceramics, Inc. here in Crossville, Tn. I hope this is enough information for you to work with. These tests 

## were performed on the Kilns. The Galze Spray Booths do not have any test data. If you have any questions; please do not hesitate to E-Mai1 me wsmithna,stonepeakcelramics.com 

## or call me at the numbers below. Thank you for your tune.
' r ' • ' ' 11

/ Ord I%



## WILLIAM SMITH STONEPEAK CERAMICS, INC. 238 PORCELAIN TILE DRIVE 

## CROSSVILLE, TN. 38555 TeI: (931) 459-2509 Fax: (931) 459-2545 Cell: (931) 510-2083

StonePeak Ceramics, Inc. 314 West Superior Chicago, lllinois 60610 t (312) 335-0321 f (312) 335-0533 w stonepeakceramics.com Production Facility 238 Porcelain Tile Orive CrossviHe, Tennessee 38555

## SUMMARY OF RESULTS EPA METHOD 6 Determination of Sulfur Dioxide Emissions ° 0 

## Stonepeak Ceramics 

## Crossville, TN Kil n Stack N ~7~ ONR0IUNO.IIVC. 

## Run Number 1 2 3 Avg Date: 10/12/05 10/12/05 10/12/05 --- 

## Start Time 845 1106 1214 --- Stop Time 905 1126 1234 --- 9 Net Time of Test, minutes 20 20 20 --- Pbar Barometric Pressure, in. Hg 28.11 28.11 28.08 28.10 P g Static Pressure, in. Hg -0.022 -0.022 -0.022 -0.022 P $ Stack Pressure, Absolute, in. Hg 28.088 28.088 28.058 28.078 V m Actual Meter Volume Sampled, liters 19.15 19.85 20.38 19.79 y Dry Gas Meter Calibration Factor 0.991 0.991 0.991 0.991 T M Avg. Gas Meter Temp., Deg. F 63.6 65.3 90.4 73.1 V SM Volume Sampled at Stand. Cond., cu. ft. 0.63 0.66 0.64 0.64 V c Volume of Water Collected, ml 1.0 1.0 1.1 1.0 V Wc Volume of Water Vapor at Std. Cond., SCF 0.05 0.05 0.05 0.05 B WS Moisture Content of Gas Stream 0.069 0.067 0.075 0,070 P M „ Percent Moisture in Stack 6.9 6.7 7.5 7.0 M F p Mole Fraction of Dry Gas 0.931 0.933 0.925 0.930 %0 2 Percent Oxygen, Dry 19.0 19.5 19.0 19.2 %CO 2 Percent Carbon Dioxide, Dry 1.0 1.0 1.0 1.0 %CO Percent Carbon Monoxide, Dry 0.0 0.0 0.0 0.0 M d Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 28.920 28.940 28.920 28.927 M S Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.166 28.207 28.105 28.159 Cp Pitot Tube Constant 0.84 0.84 0.84 0.84 APS Avg. Sqrt. Delta P, in. H 2 0 0.368 ; 

## 0.363 0.365 0.366 T S Avg. Stack Temp., Deg. F 259.4 260.0 260.3 259.9

:

## SUMMARY OF RESULTS EPA METHOD 6 Determination of Sulfur Dioxide Emissions 0 ° Stonepeak Ceramics ° Crossville, TN Kiln Stack Ri AH MONRONO. W[.


## V S Avg. Stack Velocity, ft/sec 

## A Area Stack, ft 2 QsD Gas Volume Flow, Dry Std. Cond., CFM Q A Actual Gas V olume Flow, CFM Q SW Gas Volume Flow, Wet Std. Cond., CFM Sulfur Dioxide Concentrations And Emission Rates N

~ 

## Normality of Bariurn Perchlorate, g-eq./liter V soi „ Volume of Sample Solution, ml V t Volume of Titrant Used in Sample, ml V tb Volume of Titrant Used in Blank, ml V a Volurne of Sample Aliquot Titrated, rnl CS0 2 Sulfur Dioxide Concentration, lbsldscf C AW Sulfur Dioxide Emission Rate, lbslhr 25.2 24.8 25.1 25.0 10.559 10.559 10.559 10.559 

## 10250 10111 10105 10155 15980 15741 15886 15869 11010 10836 10920 10922

0.0099 0.0099 0.0099 0.0099 100.0 100.0 100.0 100.0 0.35 0.50 0.40 0.42 0.05 0.05 0.05 0.05 10.0 10.0 10.0 10.0 

## 3.30E-06 4.78E-06 3.80E-06 3.96E-06 2.027 2.903 2.305 2.412



# 29

### 1 2 10/12/05 10/12I05 

## 845 800 

## 1058 820 60 60 28.11 28.11 -0.022 -0.022 28.088 28.088 120.21 120.07 1.00 1.00 78.8 96.8 3.91 3.78 

## 5.8 6.0 0.273122 0.28254 0.065 0.070 

## 6.5 7.0 0.935 0.930 

## 19.00 18.90 3



### 10112105 

## 800 

## 820 60 29.94 -0.022 29.918 120.15 1.00 99.3 4.01 6.3 0.296667 0.069 

## 6.9 0.931 18.90 

## Avg

28.72 -0.022 28.698 120.14 1.00 91.6 3.90 

## 6.0 0.2841 0.068 6.8 0.932 18.93 

## SUMMARY OF RESULTS EPA METHOD 26 Determination of HC1 & HF Emissions Stonepeak Ceramics Crossville, TN Kiln Stack ~ 

# 1
~~ f

~ !j ' 3 / 1
~e~ 

## EGRf'fY

0

Pba, 

## P B P s 

# V M OH T M

VsTD 

# V c Vwc Bws

PMV

MFD 

### %02 

## %C 0 2 %CO 

# M d 

# M s Cp APS T S Run Number Date: 

## Run Start Time

Run Stop Time Net Time of Test, minutes Barometric Pressure, in. Hg Static Pressure, in. Hg Stack Pressure, Absolute, in. Hg Actual Meter Volume Sampled, liters Avg. Delta H, in. H 2 0 Avg. Gas Meter Temp., Deg. F Volume Sampled at Sta.nd. Cond., cu. ft. Volume of Water Collected, ml Volume of Water Vapor at Std. Cond., SCF Moisture Content of Gas Stream Percent Moisture in Stack Mole Fraction of Dry Gas Percent Oxygen, Dry Percent Carbon Dioxide, Dry 2.80 2.90 2.90 2.87 Percent Carbon Monoxide, Dry 0.00 0.00 0.00 0.00 Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.208 29.220 29.220 29.216 Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.476 28.439 28.447 28.454 Pitot Tube Constant 0.84 0.84 0.84 0.84 Avg. Sqrt. Delta P, in. H20 0.368 0.363 0.365 0.366 Avg. Stack Temp., Deg. F 259.4 260.0 260.3 259.9



# 30

## SUMMARY OF RESULTS EPA IVfETHOD 26 

## Determination of HCl & HF Emissions Stonepeak Ceramics Crossville, TN Kiln Stack ~ 

### e e

aeR

~ owrtoewo. rac 

## V S Avg. Stack Velocity, ft/sec A A.rea Stack, ft` Q so Gas Volurne Flow, Dry Std. Cond. CFM Q A Actual Gas Volume Flow, CFM Q SW Gas Volume Flow, Wet Std. Cond., CFM TP Tile Production Rate, tons/hr HC1 Concentration and Emission Rate M Wc Mole Weight of HC1


## m o HCI Catch, mg C d HC1 Concentration, ppm C, HC1 Concentration, gr/dscf C" HCl Concentration, mg/dscm C AW HC1 Emission Rate, Ibs/hr 

## C 7P HCI Emission Rate, lbs/ton of tile HF Concentration and Emission Rate Mwc Mole Weight of HF

m n HF Catch, mg C d HF Concentration, ppm C, HF Concentration, gr/dscf Cas HF Concentration, mg/dscm C AW HF Emission Rate, lbs/hr C T P HF Emission Rate, Ibs/ton of tile 25.1 24.7 24.1 24.7 10.559 10.559 10.559 10.559 10235 10041 10436 10237 15892 15676 15292 15620 

## 10950 10792 11208 10983 5.79 5.79 5.79 5.79

36.47 36.47 36.47 36.47 0.37 0.29 0.31 0.32 

## 2.2 1.8 1.8 1.9 0.0015 0.0012 0.0012 0.0013 3.35 2.71 2.73 2.93 0.13 0.10 0.11 O.l l 0.022 0.018 0.018 0.019

20.01 20.01 20.01 20.01 <0.020 <0.020 <0.020 <0.020 <0.22 - <0.22 <0.21 <0.22 <0.00008 <0.00008 <0.00008 <0.00008 <0.18 <0.19 <0.18 <0.18 <0.0069 <0.0070 <0.0069 <0.0069 <0.0012 <0.0012 <0.0012 <0.0012



# 31

## SUMMA.RY OF RESULTS EPA MET1rIOD 26 Determination of HC1 & HF Emissions ~ ~ 

## Stonepeak Ceramics ~ 

## Crossville, TN 

## Kiln Stack AIR MONRORiNO. iNC. 

## Example Calculations Run 1 Stack Pressure, Absolute, in. Hg 

## P S = Pba, + P g = 28.088 Volume Sampled at Stand. Cond., cu. ft.

17.647 * V M

* (Pbar + AH / 13.6) V Sm = -------------------------------------------------- = 3.9



## T M +460 Moisture Content of Gas Stream B WS = (SVP - (0.000367 * PS * ( DB-WB) * (1 + (WB-32) / 1571))) = 0.07 Percent Moisture in Stack PN,v = B WS * 100 0.00 

## Mole Fraction of Dry Gas

100 - P r , n , 1VIFD = ----------------------- = 0 

### .935

100 

## Mole. Wt. Stack Gas, Dry Basis, lb/lb mole M d = 0.44 * %CO 2 + 0.32 * %0 2 + 0.28 * (100 - %CO 2 - %0 2 ) = 29.208 

## Mole. Wt. Stack Gas, Wet Basis, lb/lb mole M S = M d *(1 - B, ys ) + 18.0 * B ws = 28.476 Avg. Stack Velocity, ft/sec (T S + 460) V S = 85.49 * C P * APS * SQRT — ------------------------- — 25.1 

## (PS * MS) Gas Volume Flow, Dry Std. Cond. CFM

1058.82 * V S * A* P S *(1 - B WS )
QsD 

### = --------------------------------------------------- = 10235



## T S + 460 Actual Gas Volume Flow, CFM Q A = V 5 * A* 60 = 15892 

## Gas Volume Flow, Wet Std. Cond., CFM Qsw = Qsn * [1/(1-B Ws )] = 10950 

## HCl Concentration, gr/dscf (At Standard Conditions) 

# CS=0 .0154*m/VS

~ 

## = O 

# .oc ~



## a

## SUMMARY OF RESULTS EPA METHOD 26 Deterrnination of HCl & HF Emissions Stonepeak Ceramics 

## Crossville, TN Kiln Stack HC1 Concentration, ppm 24.054048 Cd= Cas * ------------------------------------------------- _



## MWC HCl Concentration, mg/dscm (At Standard Conditions) C

~ 

## = m a / (VSTD * 0.0283) _ HCl Ernission Rate, lbs/hr (At Standard Conditions) C A , = 0.00857 * C $ * QsD = 

## HC1 Emission Rate, lbs/ton of tile (At Standard Conditions) CTP = CAW / TP = 

## Standard Conditions 68 Deg. F, 29.92 in. Hg ~ x~ 

# ~ ~~ %1
~; ~ y / ~►

~~ 

## rEGRiTY

2.21

3.35

0.128

0.021



## 33A

^ a

/n, ,/"""rx"mnl/",p"inm E P -t i'vletbodl ~ DerormlnadonofSum}diog Poinm

suMpun
~ v ' uLv

s o "xnmmm^mmercxIcom/m°o`q

- X'.c" w ^'xmm 

## ms ^ --'--................. umtaxec*rmuwomNexremommmxwce
oummmu"

52

### EPA 

## Nletliod 2 — 

## Fiel(i Data Sheet
(* , ie,-IE .- (,2rC-IvA5I Cily—slate—

- -- - Smipling Locatio,, - Rut) [lite l'ime Bammerric l l resstirc. in. I

- IL' Pitot 'I'ubc 

### I.D. K41o. 

## P G L 'ek S-auc Pressure. Ilitot l'ube Leak 

## C r- ield Dal(i

Tmvene point Number VCIOCICY 110HI Ali Inches

fi l o 

# A, ~ Iixir "ell ,

4~ I eterimnatlawAp. wt 00 Reference. 

### -Afigle NIVIkh Yields a 4ull Ap 

### OWH
L 

## 6.0 C71 

## D o 0.0 

### 10, 

## 1 

## to

- 

## 2 ta 

### 0 Q 6 - ek 

## &.o'-; ').Q 

## V.- Z) lo t 

### va ;p 49.0

_ g_ , 0 

### 0.0 0 , 0 

# 10. i4 

## eD
6. to 

## a. L) 0,0 10-0 

## ELOD: 67. 

# 0

Averages -Suick Temperature. Dr

. %. 

### "T iA, Stack- Fe-nipel-ature. wer-F (11) Df Merence IA - 11) PreHminary Percenz.Moisturz:
Comments


## 53~ !

~~ 

## EPa Vlethod 3- Molecular Weight Determination — Pield Data Sheet Conipanv Nanze ~~ - ~ on e- 4-4 

### L 2 ~ vi C 

### ~ Project Number V`J City/State __-_- ~ rc; ` f .;tk Ttv Sample Date Q Sampling Location l: 1 I t, (,• G --_ Operator Analyzer Type __ VYA h. Oxyg;n CaEibration 9 1, b Fue) Type 11 4 4 Orsat Leak Check: Burette j) t L - 15. 1., =<0.2 ml?

Run g ~ 

### Gas ReplicAte I : $epllcate 2,::

~ 

### ' Replicate 3 Avera

~ 

### ePercentlYet Actuat hlet :' Actμal Net '.; ;:Actuat Co 2 O : a~,~ )G,o

~ r.
~ j' S,D a ~.~' 

### 19.t ~ , 

### lq,c 

### co 

# L_ 0 ' ~ 

### F o = ~ Run 'i ~ L 

### Gas Replicate 1 Repliate•2 Replicate 3 Ai erage Per.cent 

### Net Actual Net Actual '11iet ; Aetuul -' 

### co=
oz r~l ~~ ~ ~~s'`~ ~► ~ 

# ' )`

~ 

# ' `l 1 `

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- T A t • ~ (7 ~ ~• ~i G ~ ^ - J



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## ~ Gas Replicate l -- Repiunte 2 Rep>licate•3 Aveft&,- Percent (XxX) ActuAi ."Net -: Actunl hiet Actual Net: CO 2

~ ct Q, ~~ .~a ~ ' v r( 6I• 1 ~ vve / al, l 

### co 

## ILL- , $ 211 v 2

F t .) -- 04 20.9% - °io0, 

### F a

- -------------------

% CO, 

### Fa Ranges-For. Common FOels, . Anthracite Coal .uid Lignite 1,016 - 1 130 Wood '..Ot>n - 1 120 : iitum

~ n.^.its : c»3 1 0!1? - ? == i

~ l•'ood 'e3;uk : 00 : . 1.130 :)isr.ilarc 01i a"i -:.J1: Natur.i! Gas + ' Mxl - f.83h Rcsiclua: Ohl 1:10 • i 370 Ympane ^ ~ 143•1 - I SSr ~



## 54

## r p-"! 

# gmitRf i ff EPA Method2-Field Data Sheet cviy
~ 

### 5 A14C, ov'WoA

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### V' it- 1L o 

### 5 - Sampling Location 

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## A-J - )>, SK 

## —11) v- )I 

# -A I'llo! I'ubc I.D. No. 

### L) L5 - - ) L.cak Check + 

## -3)

Ruti Number 

### Tinic (24-liour (:lock) 

### C ) O () LI 1100 . Barometfic Pressure, in. 

## Hg SEatic 

### Prmure. 

### 1-1,0 49 

### -30 — 0 5 1 

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### Temp., Di.. *F 

### PA Smck 

### Temp., 'Wet. OF Differencc. OF 

### tvioisture. 

### %

0 

### J.. t T 

# p ' r ~ 

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### 149


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## 5q -2 D•5 51. • 

## L-t 

# I o

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## Jit a I

------ 

## 1-5T" (00-:3

55Run Impinger 1 Impinger 2 Impinger 3 Impinger 4 Impinger 5 Impin er 6 Total 

### Final Wei ht, 9 113, ~ 

### 1i 1. 1 1 t3. 7 c 

### 78

~ 

### Initial Wei ht, g 2 l) ~• ~ 

### 9`y, ~ 1~~ 

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### t

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### • Final Wei ht, g 1i3. tp 1$3 h 3.. 't dj.2 2 Initial Wei ht, g 113. ! 10. 3 113•• Z q4•2 W $



### Gain, g 0 Ij 0 • ~ Final Wei ht, g 1 i

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### 3. 1 1) 3. z 

### cl Y

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_ Gain, K 0 0,

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# 54
Final Weight, ! l ~- ~ 1I~ 1, j 1i 3.ti ~ t~ ~lo 5 Initial Wei ht, g ~ i 3.Z 1 ~~}.~ I ) 3.{, i 1 l•~ ..: ;

Gain, g '~~ ~. U~~ 0~! ti~ ~j
~ • b
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IL- 

# F

— Gain, g L 1 •7
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# ,N Z l.; EPA Reference Method 4 Mini-Impinger Sampling Moisture Determination Client jz 

### ra^"1

~ 

### y City, State ~Xv~iS•~=~L~ , ~ 

### Sampling Location tik-f4 a 

### n



# w e

### ER4 .4lethod 2 -- Fielif Dtiiei S6ee

~~~—.^.—_.--. Project Nwriber

—_-- __---'—



# L N

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## 2 i--

Te



# rg TU

— 

# T (D - Ol 

## a 5f,

55

### Field Data Slieet - 

### EPA iVIetliod 6 

### — Sulfur Dioxide Sainpling
Client Sunee k Ruit Ntimher citv"Stale Cr(. , rssville,,*I*N Date 

# lo/ II/o5
Swnplir g

Location Kiiii 

### Stack Operators JALAJD

Sample * ID No. Console No 

# al vwr- t AHK 

# 1. Y=-- 

# oiqql

Observer A g enc y _ 

### ~~ 

# ETC Stan Time 

# D End Time 

# 5 -

Crock DGas. 4icut=

. itile 

### T

5 lo 

## 2, j ~D Lg~ ~~ (9 1 ) 15 L 

## i 20 

### 4 1 25 30 35 40 45 50 55 60 

# nv

Sy



# M:

~ 

# -1l'ietti Diit(i Slieet 

### - ER-1 Werhod 

### 0 — Suljiir Dioxide.Yintipling
CI ient Ruxi Nuniber Cit•/State Crossville. TN Datc Sampling Location K-in Stack Operators JAL, AID

ComioicNo. Sample 11) \o. _. ~ 

### L Ally Y= - -

Aeume..• Start Time Elid 'I iiiit: ZI KmviA.,

Clock 'r P UMP

... Vhcuum.

~~ Time Cubi&faet `5 

### F-

~ A verage 

### Hg q (0, j!
- ) 

### (OLI Li



## ~ 1;

___ ..__ ~ 

## a . ~ ~ 

## : - _ c~~ ~ ~ s 

## ~ 20 

# ofc
25 30 35 

# _ffi

w

45 50 55 60 

## to ) (01 (p 

## L) (_0 

# t



# miField Data Sli eet - EPA iVetli od 6 -;-Suffiur Dioxide Sampling CHent Sionelleak Ccraiiiics Run Number 

# 3
Citv!state Crossville. TM Date Sampling Location Kiln Stack Operators 

### jAI-,AJD---,.
Siiiiiple iD No. 

### 14D Console 

### No.,-VP57E- AH. y

Observer Agency 

### S= Time End *rime

Dry: Gras Clock t., Meter' er-.*. nat,6

-. - C bi OFS .Jnchesr 0 5 10 15 

## 91 (P5 C, 20 25 1 

# e

NM I M -1 30 )5 40 45 50 55 60 

## J 1 0 

## 5 -



# amField Daur.gheet - ER4 Method 2ti - Hydrogen Citiot-ide

C I tv/'s tat .4 1 

### tte-- DauSaiit u iiiig Locition Operators

Par. Prcss., III H!, Samp I c ID No. 

### LEAK CF•CU Smuc Pmss., In. F-20 Y 0• 01)S--V(, - - 

## r 04F 611 1 Ln. H g. i%.Ictc- ,BoyNo.VO , 51

- 4!~2~ Prr)bcNo. 

### %

~ 

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### 15-i-Pinger Absorbing .13olution 11,804 

### Fu Volume. riii Initi , 

### V

~ 

### K olume, nil 

### 200 Net C2 e iised Volume, 

### rnl I Impinuer 

### Nsorbing Solution NaOH Final Volum 

### I 

### Initial VolunieNfl 200' 

### Net Condensed 

### V u me, rnl 1 

### 'I'otal Condensed V hLq 

### Po-rcent Silica Gre.1 Spciit Final Weight, bli-dal 

### W eighL. g 

### 300 Net Absor : 

### )ed N

~ 7 ater. 

### z



# - Totall Reagen• 

### Collected, z 

### S~ - 'v p p e- 

## 41 i - u 

# n e, 05 o ~



# IsField Data Sheet 

### - EPA .41

- ethod 

### 26 — -FFydrt

~ cyt Clzloi-itle , RLmN-un * ib--r

- 

### Zcim'statc 

### z Date 

### /Z)/Ig J,04 — Sainniffic Location Operators

R I LEAK Cf-1FCX.lV L'T. III FIC S aM pil, I M N o . Static 

### Prcs:,.. im H : O 

### AF! L 

### N' (SO Observer
P-ox No. Probe 

### NC'L Iii: Sample Box No. Probe 

### Tcmp. St:ffing S , .arl, Time F-rid Time 

### jlp 

## ~ o

Aizal ) ,-sis ofAloiscure.Recoveij, 

### J.-npinger Absofbing , Solution Nual Volume, rni ini olume, n-fl '100 Nic- t 

### C ensed 

### Volume, rnl 

### In-,Ping , .-r 'AR

'sorbin. , - 

### Solutioii Na011 Final V(Ilume\

,rnl 

### Initia I Volunia, 

### lql 200 

### Net Condensed Vkunic. rril Total Condensed V( tne , 

### nil

kLi 

### P , ;rcent Silica Gel 

### Speiit Fizial W 

### night. g 

### initizil Waight, c 300 Net 

### Absorbed Water, e k* 

### Total Reagent Colltctc

~ 

### d. 

# —A f : Mr. 61•ichl Dula Sht?et - EP4 Mcthod 26 — Hvdr(.-A , c , n Chloride

- rA.) Date Sarmilill" Location 

## i T - Operators

cs s. I SaTnple IL) Na. L E. 4 K CHF. CKS

1 ~ tatic Press- fin. H.--(') %t Y - Obsnrvrr 

### rjkrc ~ 

### - 11*cst4g, cp t 7. (it; 

### _!577_ In. Aizc e 

### C, 00 ncN Post-'7est 

## 01 Li Sart-uh. Bo\ No. Yl '-

::4 Probe Temp. St:ttmg sinn, Fn(]'ri- ,iic '14

I 

# W

- 1 1 1 1 1 1 -l" U

AL

W
i' R

-.2

-4mit V .vis qf:ffohvtu•• Recoveg ,nt)inp-e.-A't)sorb-'ni!Solu*,iL)rj 

### H,SO- I F-"i*V I o t u , n e. m'; Initi a Volume. ril 200



# ~ Net COAensee N"olutiie, in*' I:n inger -Nsorbing Solution NaOl-I Fi.-ial Vohiin\

-pl Lnital Volumc,) 200 Not Condcust:d Va 

### C., ml Total (7

- ondens--d ~ 03E IC. 

### all

P-rccnt S i c aGc; !S -,:at

g liiii-ial Weit!ht, g 30(" 

### Nc: Abs r

1. W ottal Rea g ent Collected, g



### 62~
~f

~ .~ ...... ~ 

### F:PA Nlethod 6Analvsis - Determination of Sulfur Dioxide

l.aboratorv Data Sheet Client: 5tonepeak Ceramics Project Number: 0- 5 -083 CitvlState: CrosSville, '1'N Sample Dates: 10/10-12/05 Sampling Location: Atomizer, Dryer & Kiln Analyst: JA L Date: 1 UI l 7i2005 'olume & Normality of Standard Sulfuric Acid Solution: 25.00 ml 0.0100 N 'olume & Normality of Barium Perchlorate Titrant: 1.) 2i.30 ml 0.00988 N 2.) 2530 ml 0.00988 N Average Volume &: Nor7nality: 2 5.3 0 ml 0.00988 N



### Analvtical Data Sample Number Sample

ldentification Total

Sample Vol. Vsotn Sample

Aliquot Vol. Va Volume of Titrant Vt, ml

lst Titration 2nd

Titration Average

Volume 5083-01 V Drver - Run 1 100 10 0.15 0.10 0.13 5083-02 V Drver - Run 3 100 10 0.10 0.15 0.13 5083-0 3 V Drver - Run 3 100 10 0.10 0.15 0.13 5083-04 Atomizer - Run 1 1000 20 0.15 0.15 0.15 5083-05 Atomizer - Rurn 2 1000 20 0.15 0.15 0.15 5083-06 Atornizer - Kun 3 1000 20 0.15 0.15 0.15 5()8 3-07 Kiln -]Zurn 1 100 l0 0.35 0.35 0.:15 5083-08 Kiln - Run ? 100 10 0.50 0.50 0.50 5083-09 Kilrr - Run a 100 10 0.40 0.=10 0.40

5083-10 IBlank 3°% H2O2 100 1 10 0.05 0.05 0.05 1326 1 QC ID 0592 100 1 20 8.85 8.70 8.78 

### QC Sample True Yalues Sample No. 1'rue Value Obtained Value Percent Recoverv Percent Difference 132fi 66t).0 657.5 ma,'dcsm 99.6 °

~ o r -0.4 "YQ ' Notes: The volume fr tlte blattk must be the sante as that of the sttnrple aliyttot. The uhsoltrtEr value for the l.st and 2nd titration mu.st be eyual to or less tltan 0.2 ml.



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# 0

# Integrity Air Monitoring, Inc. 9548-D Mt. Holly Huntersville Road Huntersville, NC 28078



# Project Number: 05-083

Hydrogen Chloride And Hydrogen Fluoride

EPA Method 26 Analysis
Analytical Report 

# 6053

Element One, Inc. 

# e~ f 5022-C Wrightsville Av., Wilmington, NC 28403 1 

### 910-793-0128 FAX: 910-792-6853 e11ab(cD,e1lab.com



## 67

### October 27, 2005 The following data for Analytical Report 6053 has been reviewed for completeness, accuracy, adherence to method protocol, and compliance with quality assurance guidelines.

Review by:

Report Reviewed and Finalized By:

Ken Smith, Laboratory Director October 27, 2005

etemen$One

. :

# SUMMARY OF RESULTS

el ementOne

## Summary of Analysis
Summary 

### of Hydrogen Chloride and Chlorine 

## Analysis 

## Run 1 Run 2 Run 3 Blank 5083-11 5083-12 5083-13 5083-14 Element Total mg Total mg Total

- mg Total mg HCI 0.37 0.29 0.31 < 

## 0.01 H F < 

## 0.02 < 

## 0.02 < 

## 0.02 < 0.01

Hydrogen Chloride 

### Duplicate 

## Analysis RPD and Spike Recoveries



### Run 1 Run 2 Run 3 Blank Run Number 5083-11 

## 5083-12 5083-13 

## 5083-14 RPD/RSD, % 1.2% 0.6% 3.9% NA Recovery, % 103%

Hydrogen Fluoride Duplicate 

## Analysis RPD and Spike Recoveries



### Run 1 Run 2 Run 3 Blank 

## Run Number 

## 5083-11 5083-12 5083-13 5083-14 RPDIRSD, % NA NA NA NA Recovery, 

## .°/n 98%

zfementOne



### 70

## Element One Analytical Narrative
Client: Integrity Air Monitoring Element One #: 6053 Client ID: Stone Peak Ceramics Analyst: MAL Method: M26 Dates Received: 10/14/05 Analytes: HC 

### I & HF Dates Analyzed: 10/25-26105
Summary of Analysis The sample was prepared and analyzed according to Method 26 protocol. The samp(e was analyzed for chforide and fluoride on a Metrohm 761 /788 ion chromatograph system.

Detection Limits The Metrohm reporting limit was 0.1 Ng/ml for chloride and fluoride. Analysis QAIQC Duplicate analyses relative percent difference (RPD) and spike recovery data are summarized with the results. AII QA/QC data was within the criteria of the method.

Additional Comments The reported results have not been corrected for any blank values or spike recovery values. Nothing unusual was noticed with the sample or analyses.

e i a men-&

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# One AIR TESTING SAMPLE SUBMISSION FORM LablD # 6053 

# DUE DATE: 10.28.05 Project ID/ 

## Number: I 05-083 

## lient: Integrity Date / 

## Time Received: 10.14.05 1417 1
0 :j 

## Lot: H F Lot: HCI 

## Lot: Ref. Method: Volume Markedo

y N 

## Volume Loss Y 1 6 / ? pH < 

## 2.0&N 2- 

## &A T Sample Identi fi 

## cation -nple Identi fi 

## cation 1 M-26A-5083 11 Rl 2 M-26A-5083 

## 12 R2 3 M-26A-5083 13 

## R3 4 M-26A-5083 

## 14 Blank 

# f .._._ ~ 

## _ ..._. . ~ 

## _- -- —
Analy
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## sis Requested Samples 1-4 HCI 

## and HF n 

## aYsi s Requested Spike R3 A

-- --------- -- 

## Impinger 1&2 Impinger 3&4 Notes: WPLE BV, mi FV, m c) l BV, mi FV, mi 

# to 2 3 

## 4

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### Revision 6.0 

## Page 1 

## of 1 Sample Submission Form bvw 

### 10/14/2005 3:08:54 

### PM



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## element4ne 

## M26-HC! IC Data Sheet Lab iD #: 6053

,ient: Integrity Column: Metrosep A Supp 5 Date: 'i 0127/05 Eluenfi: 3.2 mM Na 2 CO 3 / 1.0 mM NaHCO 3 Analyst: MAL F1ow Rate: 0.7mLlmin. Detection Limit, (Ng/ml): 0.10 CI" to HC! factor: 1-028
Cl' Final HCI, Spike, % 

### Sample ID

--------------- 

### Nglml

---------- 

### Dilution

---------- 

### Vol, ml

--- ------- 

### Total mg

---------- 

### pg/ml

---------- 

### Recovery

---------- 

### file name

--------------- 

### date time

--------------- LRB 0.039 1 10 < 0 pa251544.CHW 10125/2005 15:44 LRB 0.065 1 10 < 0 pa251624.CHW 10/25/2005 16:24 LRB Spk 4.712 1 10 0.048 5.00 93% pa251705.CHW 10/2512005 17:05 LRB Spk 4.689 1 10 0.048 5.00 93% pa251745.CHW 10/25/2005 17:45 6053-1 1.803 2 100 0.4 pa252309.CHW 10/25/2005 23:09 60-53-1 dup 1.781 2 100 0.4 pa252350.CHW 10/25/2005 23:50 6053-2 1.431 2 100 0.3 pa260030.CHW 10/26/2005 0:30 6053-2 dup 1.423 2 100 0.3 pa260111.CHW 10l26/2005 1:11 6053-3 1.499 2 100 0.3 pa260151.CHW 10126/20051:51 6053-3 dup 1.558 2 100 0.3 pa260232.CHW 10/26J2005 2:32 6053-3 spk 6.688 2 190 1.4 5.00 103% pa260313.CHW 10/26/2005 3:13 r-053-3 spk 6.692 2 100 1.4 5.00 103% pa260353.CHW 10/26/2005 3:53 J3-4 0.000 1. 100 < 0 pa260514.CHW 10/26/2005 5:14 6053-4 dup 0.000 1 100 < 0 pa260555.CHW 10126l2005 5:55



### Standards 0.1 ppm Std 0.102 4% 102% pa251106.CHW 10/25/2005 11:06 1.0 ppm Std 0.874 4% 87% pa251141.CHW 10/25/2005 11:41 5.0 ppnl Std 4.648 8°l0 93°!o pa251221.CHW 10125l2005 12:21 10.0 ppm Std 10.172 1% 102°lo pa251302.CHW 10/25/2005 13:02 20.0 ppm Std 21.578 2% 108% pa251342.CHW 10125/2005 13:42 0.1 ppm Std 0.098 98% pa261603.CHW 10/26/2005 16:03 1.0 ppm Std 0.913 91 % pa261643.CHW 10/26/2005 16:43 5.0 ppm Std 5.011 100 0 % pa261724.CHW 1 0/26/2005 1 7:24 10.0 ppm Std 10.289 103% pa261804.CH.W 10/26/2005 18:04 20.0 pprn Std 21.955 110%, pa261845.CHW 10/26/2005 18:45

QC Check Std 4.526 91 % pa251423.CHW 10125/2005 14:23 QC 

### Check Std 4.517 90°lo pa251503.CHW 10I25l2005 15:03 nC Check Std 4.761 95% pa260635.CHW 10126/2005 6:35 Check Stc 4.802 96% pa260716.CHW 10126/2005 7:16 QC Check Std 4.842 97% pa261401.CHW 10/26/2005 14:01 QC Check Std 4.625 93% pa261441.CHW 10/26105 14:41 

### 77

### elementOne 

## M26A-HF IC Data Sheet Lab ID 

## #: 6053

Aient: Integrity Column: 

### Metrosep A Supp 5 Date: 10/27/05 Eluent: 

### 3.2 mM Na 2 CO 3 / 1.0 mM NaHCO 3 Analyst: 

### MAL Flow Rate: 

### 0.7mLlmin. Detection Limit, (Ng/ml): 

### 0.10 F' to HF factor: 

### 1.053
C1' Final HCI, Spike, % Sample ID

--------------- Ng/ml

---------- Dilution

---------- Vol, ml

---------- Total mg

---------- Ng/ml

---------- Recovery

---------- file name

--------------- date time
LRB 0.000 1 10 < 0 pa251544.CHW --------------- 10/25/2005 15:44 LRB 0.000 1 10 < 0 pa251624.CHW 10/25/2005 16:24 LRB Spk 4.802 1 10 0.051 5.00 96% pa251705.CHW 10/25/2005 17:05 LRB Spk 4.786 1 10 0.050 5.00 96% pa251745.CHW 10/25/2005 17:45 6053-1 0.037 2 100 < 0.02 pa252309.CHW 10/25/2005 23:09 60-53-1 dup 0.039 2 100 < 0.02 pa252350.CHW 10/25/2005 23:50 6053-2 0.025 2 100 < 0.02 pa260030.CHW 10/26/2005 0:30 6053-2 dup 0.014 2 100 < 0.02 pa260111.CHW 10/26/2005 111 6053-3 0.011 2 100 < 0.02 pa260151.CHW 10i26/2005 1:51 6053-3 dup 0.012 2 100 < 0.02 pa260232.CHW 10i26/2005 2:32 6053-3 spk 4.963 2 100 1.0 5.00 99°/n pa260313.CHW 10/2612005 3:13 R053-3 spk 4.863 2 100 1.0 5.00 97% pa260353.CHW 10126/2005 3:53 53-4 0.000 1 100 < 0.01 pa260514.CHW 100 1 26/2005 5:14 6053-4 dup 0.000 1 100 < 0.01 pa260555.CHW 10126/2005 5:55



### Standards 0.1 ppm Std 0.098 1% 98% pa251106.CHW 10/25/2005 11:06 1.0 ppm Std 1.006 5% 101 % pa251141.CHW 10/25/2005 11:41 5.0 ppm Std 4.735 5°l0 95% pa251221.CHW 10/25/2005 12:21 10.0 ppm Std 10.123 1°io 101 % pa251302.CHW 10/25/2005 13:02 20.0 ppm Std 20.468 2% 102% pa251342.CHW 10/25/2005 13:42 0.1 ppm Std 0.099 99% pa261603.CHW 10/26/2005 16:03 1.0 ppm Sto 0.954 95% pa261643.CHW 1012612005 16:43 5.0 ppm Std 4.999 100% pa261724.CHW 10/26/2005 17:24 10.0 ppm Std 10.251 103% pa261804.CHW 10/26/2005 18:04 20.0 ppm Std 20.850 104% pa261845.CHW 10/26/2005 18:45

QC Check Std 4.531 91 % pa251423.CHW 10/25/2005 14:23 QC Check Std 4.565 91 % pa251503.CHW 10/25/2005 15:03 nC Check Std 4.719 94% pa260635.CHW 10126/2005 6:35 Check Std 4.769 95% pa260716.CHW 10/26/2005 7:16 QC Check Std 4.523 90% pa261401.CHW 10/26/2005 14:01 QC Check Std 4.544 91 % pa261441.CHW 10/26/05 14:41 

### 78

### APPENDIX 4

PKODUCTION DOCUMENTATION

79