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## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011

DR 

### 1 Identification of the substance/mixture and of the company/undertaking

· P roduct identifier · Trade name:
· Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation · Details of the supplier of the safety data sheet · Manufacturer/Supplier:

· Information department: Product safety department · Emergency telephone number: +49-8171-53-222 

### 2 Hazards identification

· C lassification of the substance or mixture · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. · Information concerning particular hazards for human and environment: When sprayed the respiratory tracts may be irritated by aerosol drops. The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · Label elements · Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. · Classification system: · NFPA ratings (scale 0 - 4) 

# 0 2 0 Health = 0

Fire = 2 Reactivity = 0
· HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 0

2 0 Health = 0 Fire = 2 Reactivity = 0
· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. USA (Contd. on page 2)Page 2/7 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: (Contd. of page 1)

DR 

### 3 Composition/information on ingredients

· C hemical characterization: Mixtures · Description: Preparation of:

· Dangerous components: C R34; Xn R22; N R50 0.5 - 1 % C R34; Xn R22; N R50 ≤ 0.2% · Additional information: For the wording of the listed risk phrases refer to section 16. 

### 4 First aid measures

· Description of first aid measures · General information: By continuous complaints consult a physician. · After inhalation: Supply fresh air; consult doctor in case of complaints. ·After skin contact: Treat affected skin with cotton wool or cellulose. Then wash and rinse thoroughly with water and a mild cleaning agent. ·After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: Seek medical treatment. Do not induce vomiting. Never give anything by mouth to an unconscious person. 

### 5 Firefighting measures

· E xtinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO)+ carbon dioxide (CO2) Hydrogen fluoride (HF) In certain fire conditions, traces of other toxic gases cannot be excluded. ·Advice for firefighters · Protective equipment: Wear self-contained respiatory protective device. ·Additional information Cool endangered receptacles with water spray. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 

### 6Accidental release measures

· Personal precautions, protective equipment and emergency procedures Keep people at a distance and stay upwind. Keep away from ignition sources Refer to protective measures listed in sections 7 and 8. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. (Contd. on page 3) USAPage 3/7 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: (Contd. of page 2)

DR · Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 

### 7Handling and storage

· Handling: · Precautions for safe handling Keep receptacles tightly sealed. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Use polyolefine receptacles. · Information about storage in one common storage facility: Store away from oxidizing agents. · Further information about storage conditions: Protect from frost. · Recommended storage temperature: 5-30°C · Storage Periode: Storage period up to 6 months 

### 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. ·Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Use suitable respiratory protective device only when aerosol or mist is formed. · Recommended filter device for short term use: P2 · Protection of hands:

Protective gloves

· Material of gloves Nitrile rubber, NBR Recommended thickness of the material: ≥ 0.4 mm · Penetration time of glove material Value for the permeation: Level ≥ 6 (480 min) · As protection from splashes gloves made of the following materials are suitable: Butyl rubber, BR Nitrile rubber, NBR (Contd. on page 4) USAPage 4/7 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: (Contd. of page 3)

DR · Eye protection: Safety glasses

· Body protection: Protective work clothing 

### 9 Physical and chemical properties

· Information on basic physical and chemical properties · General Information · Appearance: Form: Color: · Odor: ·pH-value at 20°C (68 °F): · Change in condition Melting point/Melting range: Boiling point/Boiling range: · Flash point: · Auto igniting: · Danger of explosion: · Vapor pressure at 20°C (68 °F): · Density at 20°C (68 °F): · Solubility in / Miscibility with Water: · Viscosity: Kinematic at 20°C (68 °F): 

### 10 Stability and reactivity

· Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No hazardous reactions when stored and handled according to prescribed instructions. · Incompatible materials: Reactions with strong oxidising agents. · Hazardous decomposition products: None, if handled according to order. 

### 11 Toxicological information

· I nformation on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: Oral LD-50 > 7000 mg/kg (Rat) (Contd. on page 5) USAPage 5/7 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: (Contd. of page 4)

DR · Primary irritant effect:

· on the skin: Due to the product composition slight irritations of the skin cannot be excluded. · on the eye: Due to the product composition slight irritations of the eyes cannot be excluded. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. The product has not been tested. The information is derived from the properties of the individual components. When sprayed in inadequately ventilated places, the aerosol drops may seriously irritate the respiratory tract! Therefore it is absolutely necessary to strictly observe the instructions of chapter (para) 8. * 

### 12 Ecological information

· Toxicity · Acquatic toxicity: LC-50 > 50 mg/l (Vertebrata) · Persistence and degradability · Method: OECD 302 B ·Analyzing method: DOC decrease · Degree of elimination: > 80 % · Classification: Readily eliminable from water · Ecotoxical effects: · Behavior in sewage processing plants: EC-50 > 800 mg/l (activated sludge) Elimination > 80 % (OECD 302 B) ·Additional ecological information: · CSB-value: 700 mg/g · BSB5-value: <10 mg/g · AOX-indication: Small amounts fo the product may slightly affect the AOX-value of the waste water. ·According to the formulation contains the following heavy metals and compounds from the EU guideline NO. 76/464 EC: The product does not contain heavy metals in waste water relevant concentrations. · General notes: The ecotoxic effect of the product has not been tested. The information on this was derived from products of similar structure or composition. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 

### 13 Disposal considerations

· Waste treatment methods · Recommendation: Smaller quantities can be disposed of with household waste. After prior treatment product has to be disposed of in an incinerator for hazardous waste adhering to the regulations pertaining to the disposal of particularly hazardous waste. Disposal must be made according to official regulations. (Contd. on page 6) USAPage 6/7 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: (Contd. of page 5)

DR · Uncleaned packagings:

· Recommendation: Disposal must be made according to official regulations. 

### 14 Transport information

· DOT regulations: · Hazard class: - · Land transport ADR/RID (cross-border): · ADR/RID class: - · Maritime transport IMDG: · IMDG Class: - · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: - · Special precautions for user Not applicable. · Transport/Additional information: Not dangerous according to the above specifications. 

### 15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed.
· Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. (Contd. on page 7) USAPage 7/7 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: (Contd. of page 6)

DR · MAK (German Maximum Workplace Concentration)

None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.
· Product related hazard informations: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 

### 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Product safety departement · Contact: Product safety · * Data compared to the previous version altered. USA