### U.S. ENVIRONMENTAL PROTECTION AGENCY 

# EPA PREMANUFACTURE NOTICE SUBSTANCES OFFICER OFFICE OF POLLUTION PREVENTION AND TOXIC SUBSTANCES, 7407 U.S. E.P.A. 401 M STREET, SW W D.C, 20460**Ul:;"~n..n,** ... 

### INSTRUCTIONS pr' 1\_ "". r"**O;~FT** \..::,,.It

• \I 

## lOr .' In' :-;::'**~f'(''''''** tr" <**tl'~** .J' _.J

........... iI>' I 

## Company Sanitized

• You must provide all information requested in this form to the extent that it is known to or reasonably ascertainable by you. Make reasonable estimates ifyou do not have actual data, • Before you complete this form, you should read the "Instructions Manual for Premanufacture Notification" (the Instructions Manual is available from the Toxic Substances Control Act (TSCA) Information Service by calling 202·554·1404, or faxing 202·554.5603). Ifa user fee has been remitted for this notice (40 CFR 700,45), indicate in the boxes above the TS·user fee identification numberyou have generated, Remember, your user fee lD number must also appear on your corresponding fee remittance, which is sent to EPA, HQ Accounting Operations Branch (PM·226), PO 360399M, Pittsburgh, PA 15251-6399, Attn, TSCA User fee, Part [- GENERAL INFORMATION You must provide the currently correct Chemical Abstracts (CA) Name ofthe new chemical substance, even ifyou claim the identity as confidential You may authorize another person to submit chemical identity information for you, but your submission will not be complete and the review will not begin until EPA receives this information, A letter in support ofyour submission should reference your TS user fee identification number, You must submit an original and two copies ofthis notice including all test data, Ifyou claimed any information as confidentia1, a single sanitized copy must also be submitted. Part ll- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Ifthere are several manufacl:Ul'e, processing, or use operations to be described in Part II, sections A and B ofthis notice, reproduce the sections as needed. Part 111- UST OF ATTACHMENTS Attach additional sheets iftherc not enough space to answer a question fully. Label each continuation sheet with the**~nding** sectiOIl beading, InPart ill, list these attachments, any test data or other data and any optional information included in the notice.
OPTIONAL INFORMATION You may include any information that you Wllllt EPA to consider in evaluating the new substance, On page II ofthis form, space has been provided for you to des<:ribed pollution prevention and recycling information you may have regarding the new substance, So-called "binding" boxes are included throughout this form for you to indicate your willingness to be bound to certain statements you make in this section, such as use, production volume, protective equipment. ,. This Optioll is intended to reduce delays that routinely accompany the development ofCOQSel\( orden or Significant New Use Rules, Except in the case ofexemption applications (such as TMEA. LVB, LOREX) where certain information provided in SIICh notification is binding on the submitter when the Agency approves the exemption application, checking a binding box ill this notice by itselfprohibit the submitter from later deviating from the information (except chemical identity) reported in the form. CONFIDENTIALITY CLAIMS You may claim any information in this notice as confidential To assert a claim on the form, mark (X) the confidential box next to the information that you claim as confidential, To assert a claim in an attachment, cin:le or bracket the information you claim as confidential. I{You clajm information in !he notices as confidential you must also DTOvide a sanitized version of!he notict. (jncludjng attac!unenW. For additional instructions on claiming information as confidential, read the Instructions Manual. 

# D Marie. (x) ifany information in this notice is claimed as confidential. TEST DATA AND OTHER DATA You are required to submit all test data in your possession orcontrol and to provide a description ofall otherdata known to or reasonably ascertainable by you, ifthese data are related to the health and environmental effects on the manufacture, processing, distribution in commerce, use, or disposal ofthe new chemical substance. Standard literature citations may be submitted for data in the open scientific literatunt Comolete test data <written in English), not summanes ofdata. mustbe submitted ifthev do not aDoear in the ODen literature. You should clearly identitY whether test data is on the substance oron an analog, Also, the chemical composition ofthe tested rrwerial should be characterized Following are examples oftest data and other data. Data should be submitted according to the requirements of §720.50 ofthe Premanufacture Notification Rule (40 CFR Part 720),
Test Data (Check Below any included in this notice) Environmelltal fate data 

## lfJ Yes Other data 0 Yes Health effects data 

### 0 Yes Risk assessments Environmental effects data 

### 0 Yes Structure/activity relationshlps Physical/Chemical Properties· 

### KI Yes Test data not in the posseSSlon or control ofthe submitter • Aphysical and chemical properties worksheet is located on the last page ofthis form. TYPE OF NOTICE (Check Only One)

### ~**~** 

## IX] PMN (Premanufacture Notice) .::l: ;1:'.. 0:::0 -< ."'];1 

# D lNTERMEDIATE PMN (submitted in sequence witkSnaI**p""e}'~)** 

## o -In, 

# D SNUN (Significant New Use Notice) 

# D TMEA (Test Marketing Exemption Application) 

# s> D LVE (Low Volume Exemption) @40 CFR

### 123.5~1) 

# D LOREX (Low ReleaselLow Exposure Exemption) @40Cm 723.50(cX2) LVEModification LOREX Modification IS THIS ACONSOLIDATED PMN? Yes 

# D D D # ofchemicals (Prenotice Communica tion 1# required, enter 1# on page 3)
EPA FORM 7710·25 (Rev. 5·95) Replaces previous editions ofEPA Form 77\0·25. 

### PUBLIC COpy

### Public reportmg burden tor thiS collection ot Intonnatlon IS 

### estimated to average 110 

### nours per response, Includmg ttme tor reviewing instructions, searching existing data 

### sources, gathering and maintaining the data

### needed, and completing and reviewing the collection of infonnation. Send comments regarding the burden estimate or any other aspect 

### ofthis collection ofinformation, including suggestions for reducing this burden. to 

### Chie( Information Policy Branch. PM-223, U.S. Environmental ProtectionAgency, 401 M. St, 

### S.W., Washington, D.C. 20460; and to 

### the Office ofManagement and Budget, Paperwork Reduction Act (2070-0012). Washington, D.C. 20'03. 

## CERTIFICATION I certify that to the best ofmy knowledge and belief: 1. 

### The company named in Part I, section A, subsection la ofthis notice form intends to 

### manufacture or import for a commercial purpose, other than in small quantities solely for research and development, the substance identified in Part I, Section B. 2. All information provided in this notice is complete and truthful as ofthe date ofsubmission. 3. I am submitting with this notice all test data in my possession or control and a description ofall other data known to or reasonably ascertainable by me as required by §720.50 ofthe Premanufacture Notification Rule. Additional Certification Statements: Ifyou are submitting a PMN, Intermediate PMN, Consolidated PMN, or SNUN, check the following user fee certification statement that applies: 

### [gI The Company named in Part I, Section A has 

### remitted the fee of$2500 specified in 40 CFR 700.45(b), or 

# o The Company named in Part I, Section A has 

### remitted the fee of$1000 for an Intermediate PMN (defined @ 40 CFR 700.43) in accordance with 40 CFR 700.45(b), or 

# o The Company named in Part I Section A is a small business concern under 40 CFR 700.43 and bas remitted a fee of$100 in accordance with 40 CFR 700.45(b). Ifyou are**submittin~** 

### a low volume exemption (LVE) application in accordance with 40 CFR 723.50(c)(l) or a Low release and low exposure exemption (LoRex) application in accordance with 40 CFR 723.50(c)(2), check the following certification statements: 

# o The manufacturer submitting this 

### notice intends to manufacture or import the new chemical substance for commercial purposes, other than in small quantities solely for research and development, under the terms of40 CFR 723.50. 

# o The manufacturer is familiar with the terms ofthis section and will comply with those terms; and 

# o The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

# o Ifthis application 

### is for an LVE 

### in accordance with 40 CFR 723.50(c)(I), the manufacturer intends to commence

Confidential 

### manufacture ofthe exempted substance for commercial purposes within I year ofthe date ofthe expiration ofthe 30 day review period.

EPA FORM 7710-25 (Rev. 5-95) Page 2la Person Submittinl Notice (in U.S.)

### -icD;;;.;;J~a~m~e:....::s~M~u~m:.::b:...t.. 

## _______**...L-_D_~_·** 

## r_e_c_t_o_r_,=--_E_H_&_S

________

b. Agent (if applicable) 

## VANTICO CORP. 281 Fields Lane Brewster, NY 10509

Telephone

c. Ifyou are submit1tiilgtithiiiisiinouiOili'

## ce;;aasSipartPliioof:fal]joi01iiiinttisaiiubbrmiiiissss:iiiion~,~miUarkiiki(X)XfthiiiiiS'**sbOiC:-:~====~=====::::=====.Lr** Joint Submitter (if applicable)

Contact (in U.S.) Company



## Dr. Jame 

## VANTICO CORP. and street) 

## 281 Fields Lane Code 

## Brewster, NY 10509 Director, E H & S

Telephone 

## 914 785-3382 3.

4. substance**~vered** by tllillIOtice. ... the CXIIIIIpIioa 1IUIIIberlllipeelby EPA. Ifyou previously submitted. PMN forlllil subaace

__ tile PMN number lllipodby EPA (i.e. witbdrawn or ilIcompl.). .. 5. for the chemical sub

__**~vered** by tIIiI notice, ... tile nacice number assigned by EPA. .. I. Manufilcture 6. Type ofNotice •Mark (X) Only 

# D SindinlOption Mark 

## 52-000000135 2. Import Only 

# D Sindinl Option Mark Mark (X) to 

## [!l ifnone Mark (X) to 

### [Xl if

### none Mark (X) 

## ... 

# D ifnone 3. 

# D Both

EPA FORM 7710·25 (Rev. 5·95) Page 3X 

## Part I - GENERAL INFORMATION
- Continued Section B - 

### CHEMICALIDENTITY INFORMATION: Yw .... aCWl'lllU, c:rlmKtQcUcalAbllI'Ida (CA)
- 01WIIoI

__ bUIlt 011 W Nl'ltII CaIl«llwlM. (9C) 01 CA ruleI and COIIIWlltiGN. Campllta lith...i ..... 1 IC'Lue 1 or 2 ...bfiUce.) or 2 lPolymln» .. appropriate. Compl... aU other ita... I.f another

### penon will submitchemical identityinlonnatioa for you (lor either illlan 1 or 2), mek ()O the box Itthe

### rtpt. 

# 0 ill a continuation sheet. .... the 1. ClaM 1 or 2 c:hemicallUbltUlc" (lor de:finiliona 01 cla. 1 and

## a- 2**subltan~** _ the but:nactioa. Manuij 

## •. au.01 substance
- Mark 00 1 

# [gJ a.. 1 01' 2 

# D a.. 2 b. Otemical name (Currentlycorrect OIemical AbII:ncts (00 Name thatII canslltent withTSC.A lnveneory Iist1npfor Ii.mil.ar subltanca For C ... 1 subltanca I CA lnc:lu NI.IM mUll be provict.d. Far 

### a.a. 2**,~ethe** I CA lnc:lu NI.IM or CA Prtt.,-edName be provided;. whichev.. 11 appropriate bued01\CA 9CI noDMndalW'e I\Il.a andconventllDnL).

c. Please identify which method you usecllodlMtlop or obtain the IpId.Iled chtmicall.ndcltltyinlcrmatlcn NpCII'ted III t.hiI ftOt:\c:c

(check one). 

# D Method 1 (CAS Inventory Expert

## s.mc. . a copy 01 the Ideli&:atloD OMethod2 (Oth.. Soun::.) report obtainedfrom theCAS Inveneory 

### Expert Service mUll be submitted .. anattactuMnt tot.hiI notice)


# • X
e. For a cia.. 1 subltana. provide a QOD\pIna andccnectc::l'Iemkalltl'\lCtUftdLagrlDL Far I ca..1IUbItancI- (1) UIt the lmmedllta precunor IUbltaJ.'Ica With their repedlveCASReptryNum'-r. 0.) o.crtbIthe natun01 tbI....::tiaD or (3) Indicata the X range01 COII'IpoIitioa and the typical cccnpolitloD (wh.. IppoprIale). (4) Provide I a:ma:t ..t1ve or partial chemical ,t:tuctI.\redjaWam, .. cccnpleta .. c:III\ beknown. II oMca be r.toaably**~** 

### X

FURM EPA 71lG-25 CRw.5-95) Pap"

## Part I - GENERAL INFORMA nON
­ Continued**~** 

### Section B - CHEMICAL ID'ENTlTY INFORMAnON
- 

### Continued 

### z. PoIymas (For a de6nitiOftofpoI)'1Mf, ,. the IDRnlctlOil. MauL) 

## Not Applicable (N/A) Caafl. 4mdal a. Indicate the numba'-averap

### weptofthe Iowwt&nOlecular 

### -&hi campalitiaD 01 the

### poI)'1Mf

### you Inlef 110 m.eulactur& Indicate muim1Ull

## wept**~t** 01 lowmolecular wept tpec:W (notlDdudJrlll"llidulllllClllCllllln.t..... ordv....) bIIow 500 andbelow I,CXXI abIolutemollcu.lar weisht 01 that campaliticn. Duc:ribe the methoa oim........entorthe

# INa. far yau.r .ltiInatecGPC 

# 0 OtNrD ! (SpIdfy) I) 10'" ftUlZlbc IYII'IIp 

### w4li8ht: U) m&1dIm.Im w.qht below 5ClO moIIIcWaI' WIIIpt: Iii) II\IlCia\UIZI**~t** below 1000 moIIIcWaI''MIIflIl: 

# o Mark CO this box j.f you attach a COl'Itb'luation .....

b, Yau mUlt make !lllpU'ate CXlft8denttalJ.ty c::I.aUN far II'IIClIlClIMI'or other ractutI.dmtlty, campolitkla INonnaIioa. andreriduallniormatlcn. Mark 00 the "Confldaltial- box natto any I .. youc::I.II.III • ClIlftftdmtlal. (1) - Provide the sped.8cc.hcalaIl nama andCAS R.eptry Numba' (Ifa num_aiIta)

# 01-= IftCIlOI:Mr oroth"ractant UIId.ln the 

## N / A IJW\Wacture ofthe polymer. . (2)
- Mark 00 thiscolumn j.f

### _ayincolWM (1) II con8_1W. (3)
- Indicate the typical wept per<alt0I1iId\ meaomer orotherr.:tantlD the r.l)'1Mf. (4)
- Mark UO the td.ntity' cahuDa II 1011 waata _om.. or ........C'IIIiit 11M .. two 

### w.tptpaaatorlIM tobe lUted .. putofthe polymer dftCriptiaa 011 theTSCA. QIIIIIkalSabItaDce laY......,.. . (5)
- Mark 00 this coIUD.'ID j.f_tn.·1ncolumnt (3) and (4) In ClIlftftdmtlal. (6)
- Indica..the muim1Ullwtipt .-c-t

# 01-= mea... or oth8'reKtant that may be**~t.** a rlillldWIIlD 1Mpol)'1Mf. manufactured far CIXl'IIDtI'dal**~** 

# m- Mark 00 this column j.f

### _ay III colUDUl (6) lit c:on8_1W. Moncm.. or other r.ctantandCAS R.eptry Num_ Coa.ft,.

### ~. Identity 

## o.a. Maximum

# 1= (1) d..tiaI 

### Gi Mark

### 00 deadal AlidWII (2) (4) (51 (6) ('7) 

## N/A 

# " " 

# " ." 

# " " " 

# " 

# " '5 

# " '"' , , 

# " 

# " 

# o Mark (X)thisbox ifyou attach.cantb'luatIcD .... e. PI... identify wb1ch mlllbod 

### you 1II1II todewlaporoMIDl theIpIdIled c:MtrdaIl.dmtitytnIarmadi:Ia ..... in thia DOt.IcL (cbec:k cae).



# o Method 1 (CAS IDventary 

# =s.mc.-a CICIpfoithekilatllcltlaa 

### rapan 

# 0 Metbod2 ( .... 1DUIa) obtaiDed fram In'Mltory rxp.t

# s.w..". be IIIbmitIIId• . an attac.hmmt to tJU.**~** d. Thecurrmdy CXlIl'C QemicalAbItndI (CA) ftIIIDIfarthe pal"..thatlit wtIb 1'SCA laftlltoryIIItInpfar

### IUN1ar pal,..... 

### W/A e. Provide a correctiept_bld.. or

### patWch.aIaltII"IIII:tUre ......... campWI.<*lbt

## mow.. tlOM<*lbt**~1-.t1ined.** 

## N/A '.



## -



# o MarkOO tIU boxII you attacb a caatilluatlaa ..... P1Ip5 

## .s. 

# ­ '.(a)· Identify e8I:b impurity that may be reasonably anticipated to be present in the chemical substance u manufactured for commercial purpose. Provide the CAS Registry Number ifavailable. Ifthen! are unidentified impurities, enter "unidentified." Number Confidential % 

### X % 

### X % 

### X % % % %

Marlt (X) this box ifyou attach a continuation sheet. in subsection 1 or 

### RD 2000-040

" 

# o Marlt (X) this box ifyou attach • continuation sheet. 6. Generic you must ageneric name for your the specific chemical identity ofthe new chemical substance to the max.imum extent possible. Refer to the TSCA Chemical Substance Inventory, 198.5 Edition, Appendix B for guidance on developing generic names. 

### polyphenol, 2H-l,3-benzoxazine derivative

use, or 

### None X

the CAS Registry

EPA FORM 7710-2.5 (Rev. 5-95) Page 6

## Part 1- GENERAL INFORMATION
- Continued Section C ­ PRODUCTION, IMPORT, AND USE INFORMATION: Mark (X) the "ConfidentiaP' box next to any item you claim as confidential. 1. ProductioD volume
- 

### Estimate the maximum production volume during the 

### fltSt 12 months ofproduction. Also estimate the maximum production volume for any consecutive 12-month period during the first three years ofproduction. Estimates should be on 100010 new chemical substance basis. For 

### aLow Volume Exemption application, ifyou choose to have your notice reviewed at 

### alower production volume than 10,000 kg/yr, S'DCCify the volume and 

## mark(x) in the binding box. Ifgranted, you are bound to this volume Maximum 

### first 12-montb production (kglyr) Maximum 12-month production (kglyr) Confi- Binding ( 1

00% new chemical substancebasis) (100% new chemical substance basis) dential Option Mark: (x) kg/yr kg/yr 

### X 1. Use InformatioD
- You must make separate confidentiality claims for the description ofthe category ofuse, the percent ofproduction volume devoted to each category, the formulation of the new substance, and otheruse information. Mark (X) the "Confidential" Box next to any item you claim 

### as confidential. 

### a. (I) ­ Describe each intended category ofuse ofthe new chemical substance by function and application.. (2)
-­ Mark (X) this column ifentry column (I) is confidential business information (CBI). (3) _. Indicate your willingness to have the information provided in column (I) binding. (4)
­ Estimate the percent oftotal production for the first three years devoted to each category ofuse. (5)­ Mark (X) this column ifentry in column (4) is confidential business information (CBl). (6)
­ Estimate the percent ofthe new substance 

### as formulated in mixtures, suspensions, emulsions, solutions, or gels 

### as manufactured for commercial purposes at sites under your control associated with each category ofuse. (7)
­ Mark (X) this column ifentry in column (6) is confidential business information (CBI). (8)­ Indicate % ofproduct volume expected for the listed "use" sectors. Mark more than one box ifappropriate. Mark (X) to indicate your willingness to have the use type provided in (8) binding. (9)­ Mark (X)this column ifentrr'(ies) in column (8) istare) confidential business information (CBl). Category ofuse (1) CBI BlndiIII Produc· CBI %in CBI %ofsubstance expected per use CBI o,tiooo tion% Fonn­ (S) (by function amd application i.e.• dispersive dye M.t(x) ulation Site- Con-· Indus· Com- Binding • for fmishing polyesterfibers) (2) (3) (4) (5) (6) (7) limited sumcr trial mercial Option (9)

Resin for electronic 

### X X 

### X laminates % 0;' Adhesives Resin 

### X X 

### X 0;. % Encapsulants Resin 

### X % 

### X 

### X e;.. I 

### X X 

### X 

## I Composites ResiQ, 0;. 0;. i

• % % 0;. 0;. % % • [(you have identified. "consumer" use, please provide on.continuation sheet adetailed description ofthe use(s) ofthis dtemical substance in consumer products.

In addition include estimates ofIbe concentration orthe new chemical substance as expected in consumer prodUds and describe the chemical reactions by which this substance loses its identity in Ibe consumer product. DMark: (X) Ibis box ifyou attadIacontinuation sheet. b. Generic Ifyou claim aD)' category ofusc description in subsection 2.as confidential. enter ageneric description ofthat category. Read the use instructions MmuaI forexamples ofgeneric use descriptions. description 

### N/A

D Mark: (X) this box ifyou attach • continuation sheet. 3. Hazard IoformalioR
­ Include in the notice acopy ofreasonable facsimile ofany hazard warning statement, label, material safety data sheet, or other ! 8lnding

infonnation whidl will be provided to any person who is reasonably likely to be exposed to Ibis substance regarding protective equipment or practices Opuon for the safe handing, transport, use, ordisposal ofIbe new substance. List in part OJ hazard information you include. Mark (x) 

## [!] Marie. (X) Ibis box ifyou attadI hazanl infonnation. 

## MSDS
- Pages 

### 14
- 17 EPA FORM 771(l.25 (Rev. 5·95) Page 7

## Part II
­ HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE



# .. ofthelite It wIUdl the Name



## Not Applicable
- Import only SUe

Uthe same opcradoa will oc:cur at more t.h.ul OM Ii... 1ft.thtnWllw01 Ii_ I_lilytht add1ticNllit.on • contlnuadoa aheIt. and 111ft,01 til. lit.have IIp!cantlydUHret .... ' 

### pt'O<luctSon ru. CI' operatioN,induct. aU the Il\.&JnrIadoa III tl'IiI-=tiCIft fer tbcIe

b. Typa­ 

## N/A

Mark 00 

# o Prooo.ml 

## DUM

1. Bate do Prac..daalptlaft Mark

### 00 _ ladlallt,.... wUUap

__ lIaYe J'OIII' procaI .. (l) DIapun the

### ma;ar unitop.-attoa 'IIIpIU'Id cMIIiaIl CDftYel'!ll.all& IDdude iDIIItm .... IftClIr.........' CItII\tai.ntn (1IIJI'I'CIIy-e." 5pI.\cxI pai.lI. 55 p.IJon drum. rail ca',tank

### Ir'UIck. etc.). (2) 

### Pnmde theidlmlity. theapprox:ImatII M!ipt('by 

### kllday CI'

### ksJ'Deldl oa•**1~** MWcMnic:Il.w..nc. "-11), aMlfttrypoiDt 01 aU ..

# tin, ma..... GadfeedIIeocb r.::IIIIlfll,..".... mel Itc.), mclof
.. produdI...,.. ..... aM "MMa IIIch.ad11

# cIIerIin, dManicaIa (no- fNquecy IInot 1.-.1dilly 01PI" 'betdL). (3) Ideuily by rnunlMr the

### pom. of
....... 

### iftc:ludInI..al CI'In.-.NttantNiIIIIII, to ....**~t** of the MWc:MadCII.lIUbItanca. 

## N/A ·Confid_lill"box next toany iblm you •

## Part II- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE
- Continued Section A ­ lNDUSTRIAL SITES CONTROLLED BY THE SUBMITTER
- Continued 2. Occupational Exposure
- You must malee separate confidentiality claims for the description ofworker activity, physical form ofthe new chemical substance, number ofworks exposed, and duration ofactivity. Marie (X) the "Confidential" box next to any item you claim as confidential. (I)
­ Describe the activities (i.e. bag dumping, tote tilling, unloading drums, sampling, cleaning, etc.) in which workers may be exposed to the substance. (2)
- Marie (X) this column ifentry in column (1) is confidential business information (Cal). 

## N tAl' b 1 (3) - Describe any protective equipment and engineering controls used to protect workers. 0 

### p p 

### cae (4) and (6)
- Indicate)'Our willingness to have the information provided in column (3) or (5) binding. (5) -Indicate the physical formes) ofthe new chemical substance (e.g., solid: crystal, granule, powder, or dust) and % new chemical substance (ifpart ofamixture) at the time ofexposure. (7)
- Mark (X) this column ifentry in column (5) is confidential business information (Cal). (8)
- Estimate the maximum number ofworkers involved in each activity for all sites combined. (9)
- Mark (X) this column ifentry in column (8) is confidential business information (cal). (10) and (11)
- Estimate the maximum duration ofthe activity for any worker in hours per day and days per year. (l2)
- Mark (X) this column ifentries in columnsilO) andtIl) are confidential business information (cal). Worker acuvity CBI Protective Equipment! Bindinl Pbysical forms(s) Bindin. CBI II of CSI Mmumu dlll'lllion CBI m (i.e., bag dumping, filling drums) Engineering Controls 0pIi000 and%_ Opboft Worker HrsIday Oayslyr MItt (x) subltance MItt (x) s (I) (2) (3) (4) (5) (6) (1) Expose (9) (10) (II) (12) d (8) 

## N/A



# [ J Mark (X)this box ifyou attach a continuation sheet.. 3. Environmental Reteue aad Dbpoul- You must make separate confidentiality claims for the release number and the amount ofthe new chemical substance released and other release and disposal information. Mart (X) the "Confidential" box next to each item you claim 

### as confidential. (I) ­ Enter the number ofeach release point identified in the process description, part II, section A. subsection Id(3). (2)
- Estimate the amount ofthe new substance released (a) directly to the environmentor (b) into control technology (in kg/day orkglbatch). (3)
- Mark (X) this column ifentries in columns (I) and (2) are confidential business information (cal). (4)
- Identity the media (stack air. fugitive air (optional__ Instruction Manual), surface water, on-site or otf-site land or incineration, POTW, or other (specify)) to which the new substance will be released ftom thai release point (5)
­ a. Describe control technology, ifany, and control efficiency thai will be used to limit the release ofthe new substance to the environment For releases disposed ofon land, characteri7.e the disposal method and state whether it is approved for disposal ofRCRA hazardous waste. On a continuation sheet. for each site describe any additional disposal methods thaiwill be used and whether the waste is subjectto secondary or tertiary on-site treatment b. Estimate the amount released,to the environment after control technology (in kw'day). (6)
- Mark (X) this column ifentries in columns (4) and (5) lire confidential business information (Cal). (7)
- Identity the dcstination(s) ofreleases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct discharges or NPDES numbers ofthe POTW (Publici Owned Treatment Works). Mart (X) ifthe POTW name or NPDES II is confidential business information (C81). Release AJnountofnewsubstance Cal Mediao( Control technology andeffiCiency (you may wish to optionally attach effiCiency data) cal Number released rel_

(I) (2a) (2b) 

# ....

# -. Blndin& I (3) (4) (Sa) • MItt (X) (5b) (6) I 

## I N/A

I I**~** (7) Mark (X)**th~** 

# D POTW provide name(s) below: eBI 

# D Navipble 

# D Other· Specity provide NPDES # CBI destination(s) of 

## r-­ waterway releases to water. 

## fiLA

] Mark (X)this box ifyou attach a continuation sheet.. EPA FORM 7710-25 (Rev. 5·95) Page 9

## Part II
- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE
­ Continued Section B - INDUSTRIAL SITES CONTROLLED BY 

## 0'nIERS Comp/llte Mdion Bfor**~_** 

# pnlICIIIUl,.. or '13M 

### opatianl iIlvolvillS the new It .. 

### you do.l'IOt**control.~·** for typkai mmufac:turilllor**pr~1** opentkml tile DIIW

### chImk:al .... c.1t SIll

### ouIIIde the

## u.s. that

## you do notccalnlHle**~** Manual Completea..,......Mdlon B

# _-:;mol ort.e:1tGa**iIlYol~** tile 

### newdMadcal........ IIthe ...... opattoa it pertarm.latmore tlwtone ... 

### deIcrUIe tile**~1tGa** CDINDOll to ...... leila addlttoaalll_on a ClXltIm.IItkm aMat. 

### optioDa1 fer ,Ues out31de the UnitedStata· See •. : H. 1. Operation OellC1i.ptiOll • To daUnInformation ill dU MCiion • CCII1IidenIUlL cLrcIeor brac:Ut tile tpId6c that 

### youcWm • CIIlIII.8detial. (1) - 

### Diasnm the major u:nltope'Ition aDd chemk:Il ClXlYIrIIIIona,

## IndudlnfiIltnn ..... and II'anrIpCIt ClXltIU:Ias (8plCify-5 plIeD palla, 55 gallondrumIt, rail 

### an,tank !.nidal. etc). the ldetilyby I.­
_ 

# brWIr, dIIcribe-=h

### wonc. ICtMty. (2)
­ the idettty, theapproxima. weght (by kllday or k,/blaldl, 1 MW

### dMmiaIllU.bItarIct btIU , and Ifttry

### potat01 aU I-.:IIIodc. (IIldudln, r.ctantl, solveI'll. andcatalysts, etc) and01 all produc:tI.**r~** ItnIaDW, and WlIIta &Ic:lude

### c:IeIuI.ins c:MmJcaII (not. II Aot WIed cbIlyor

### per batch). (3)
­ [dent:iIy by numb« the pointl01reltut,

### iIld1.ldi.nS IIIWlor iZltennittIrIt

# r.-... to tile _vlroinmIftt 01 the MWc:hImica1lUb1tanca. Entll' , of 

### .it.. 

## [ 

# CONFIDENTIAL

. 

### 35% to 80% PMN resin 

## + 20% to 65% solvent 

## + other resin 

# t Copper-clad laminate or printed wiring board 

# >­ curing operation 

# W G) 'G) 

# t o Mark 00 th.itt box II youattad:la ClXltImIadan
.... 

### Finished article 2. Worka' Expo.anfIIl'riroe1ll!lelltal

## a...... (1)
­ 

### From tbedlapm

### ebow" providethe

## we. far-=h 

### 1di:I.YUJ.

# Cia,.. 2-1 far .. 

### Idi:I.YUJ**~** (2) - Ettimatethe l\\lIIIbcoi**~""for** 

### aD ... 

### era..... (4)
- Ettimatethe typtalduration oI41XJ'011'ft

### PIIIr W'CIIkIW III (a)hounper .,_(b) .,.. per y... (6)
­ Oeacrt'be phyacaform of
..... and. .. DeWct.atalauJwtencp

### Offa 1IlildLft), II!d ., proIIII:IiwtquipIDIftt and**~.** cantrolt, ilmy UMc:i**to~** 'MIl .... 

## m- Estimate thepIICIIIIlt 01 the MW

## .w.__• fomwIatlld ,... J*bp:Ior .... a rlDal procl1Kt. (9)
­ 

### From the 

### c:IiAIsnm abcml, __theIIUIIIM01 .. 

## r--. paIDt.

# Cia,.. 9-Utor .. 

## r.a- paiNkMDtIW. (10) ­ Estimate the lD\ount01 the MW ....... ..a....d(a)

## diI'IcIl,**tothe~** or (\I) IDtocadrOltIId\ftoiog 110 the .Vir'onIDent (Illtlldayor kll.tdU. • (12)
­ Oeacrt'be media 01 ....... (tIIICSair, 

### 1uiI*M""

# (=**~M.uaD,** 

### ___

### wu.,0IHttaor ..... 1and orIRc::b:IcItiCIl, POtW, arother<sp.:ity» and. ccatral 

### IDY, wm1lll ... 110 limit the

__01 theMW IUhItaDot 110 the.¥ill:mmlat. (14)
- [dtntilybyproductlwbtch ...y NaII.t the aperatka. . (3), (5), (8l 1 (ln, (13) and. (15) •

### tart00t:bII coIuma If-lIlY'01 the 1IddM .. Cl:lllildmtlal bulineallafcnnaItGa 

### (CII>. 

### Lett. '01 CBr Dundal C8I 

### J'rOClKllw Squ1p. 

### I 

# I:c:.. CBI

# .... AmauIltol CBI Contral 01

of Worbn 01 

### ",.., ...... CAAtt:oIIII NumIMr New TIChncIosY Act· 

### ExpoMd 

### ExpoIuN 

### PhJlllCll FanD II!d .. WaIlea**~** ivity DeW ......... rw...l 

### I ('1) <lOU : <lOb) <11 (12) (1) (2) (3) C4a) I ("It) (5) (6) (8) (9) (13)



### A 2 8 I 

### 30 gloves.goggles X 1 

### 0 

# :< lkE 

### Lined landfill I apron,exhaust I 1/day I L 

### I Slo.ves•goggles X 

# WA N/A I'N/A N/A B 

### 2 8 130 

### apron,exhaust I - I 1 I 

### I 

### I I 

### I I I 

### I I I I I 

## • I (14) -1JyprocIuda (5)



### None 

# TI M..x00 box

## ifyou.tIIICh.~ ....

## Part 11- ·HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE
- Continued**~** 

### Section B - INDUSTRIAL SITES CONTROLLED BY O1HEKS CompieM MCtica Bfor typicU procIIIIIinlor \Ale

### opnticNinvolvi.nl the IIoIW tuietanCIIIt
.. 

# you do not (X)ntrol.**~NLl** for typical manufacturinlorpt'OCIIIiDlopIrItXmIlIlYDlvtns the DIWchIaUcI.lll.lllet.alCIIIt
.. ouaide the

# u.s. that

# you do notQlIltroH.**~** MuUII.CoatpIMe • ..,.,... MCI:lca B

### fer

# -:.:mcI. procIIII.nt. or \.e**=tSemlll~** 1M MWcI'IIIIIical tubManc:& Uthe tmleopIl'ItIaI it perfCllmec1.t more thaD OM
.. dllc:ribe the**r;;.~.d.oa** CDINl'IClI'IIIO
..... I addiltoNl !III.. em • canlbludGa

### sMIt. optkeal far sites outside the United. Stata· SIll

## rn. M 1. Opuatiaa OetcriptiOll • To daimInformaticn in thia MCtion • c:&mfide1ilL circM or bracbtthelJ*ificinlonnad.cIIliIatyouclaim.c:on8detW. (1) - Olagram the major u:ni.t operatioa aDd cMmk:al canVftcl:'ll" 1Ddud1ns inteUn ..... Iftd InNIportcantlUMn (tpedfy-5 pike pIibI. 55 gallon c:Iruma, rail cars, IarI.k

## trucb,...,. the

# dial::; IdtIItlfy bylen.and brWlydIIc:rtbe -=II wwlr«lId:lvUy. (2)
­ Provide the

### IcLmttl:y, the approJdm... weight (by 

### kglday orkg/bltcb. 1 newchlDdallUblluCll
....), and ...., poUlt oll1lt.Ultock. (lndudbag r-=tanlll, 501valtl and catalysm.etc:) and 01 all products. fecydl Iftd w--.lnc:ludldeaninlcbeINcaII (note&.quincy ifnot used daily or i* batch). (3)
- ldentilyby numba'the pointaof

### nl-. indudinllll'lall or**in~** 

# re-.tothetIlvinllurlent01 the IIoIWch.mkalIUbttanCil. 

### Enter. of

# .it.. [ ]

# ~ONFIOENTIAL PMN resin 

# (9 

# t heat Hot melt application to adhesive or encapulant substrate 

# t W 

# ® Curing operation 

# n Mark 00 thia box ifyou

# .ttadl. CCIIlIimIIdIcn IMIt. 1. Wariur**~viI'aeIDe.III1** ••"'" (1)
­ Prom thecU.qruD abow,prvv1I:W the IItIiIr lar.c:b,......&:ttvtly. 

### 0.....2-Ilar.c:b III:tlvUy**~** (2)
- EstimIlil the nUlllM

### cI. W'GI':bn
.... for aD Ill..**~** (4)
- Ettimalllthe typical duratla.'l 

### cI. ..... pIrwwka'ill (a)houmfill' .y Iftd(b) day. fill' .,... (6)- DlBatbephylllcll farm

### cI. ecpcIIUNaDd" newcbIadal.JbItaDct(IftDlldxtuN),

# 1IId., pnAIIidiIwequtpmetand**~g** CIXIlrOliI. itmy UMd toprollect 

### wor.... 

# m- EttimaliI the**~t** 01 thenew.abMmce
_ lamulalild ..... pKkIpI CII'

___ • &IIIlprocluI:L (9)
­ From**the~ ~.bow.**  

# til" the**~01""** Nll-.pr:.iUd. c.p-t-U tar .... NIl-.poiIIt lderitls.l (10)
­ &timalllthe all'IOUftt01 the new .............. (a) dlnedy 110 the or(b) IDtocaatn::Il

### ta:hnoIo&Y 110 thI ..vironmIDt (Illkg! day orkg/bMcb). • (12)
- DlBatbemedii01

__

### <ltldialr.

## fu&iaM" (opdOinI.HII**~MeuID,** 

### .... wae., 0IMiIIIor off
..... land or 1adDendca,POTW, aroth.esp.:ify»aDdCCIIltrell**tIch~.."** .....wiD 1111__110 limit the

__01 the I\IIW IU11ItaftCIIIIO the.'YIroIImct. (14)
- identifybyprcduct:lwht.cb 

### may 

### r..at the opnIk& (3), (5), (8), (11), (13) and (15) • Ma-k

### 00 tIdII caIuIaatf .y

### cI. the tIltIW .. ClClDftdetl.ll buIiDIM inlwmatkm (CII)-. Letter '01 CBI 0uratIma CB Proea:dV'e !quip.

### I 

# I". em a.... AmouDto( CBI Cantrell CBI

01 Worbn 01
.... ,;ldal

### CaiDeralltI**~** NIW' 

### TedInolosY Act· 

### ExpaNd ExpoMn 

# JIb,.. ParDlIlld " 

# ....**~** ivtty 

# ....,

# .......... 

# ...... I 

## m ClOl) : Clot. Cll (12) (1) CZ) (3) (oW I (4b) (5) (6) (I) (9) (13) I**~loves,** 

### goggle!: I I 

### I( lkg l 

### Landfill or A 2 

### 8 

# ! 30**~pron,** 

### exhaust X 

### 1 

### 0 

### Iday incinerator B 2 

### 8 : 30

## ~loves, goggles X 

### N/A N/A:NIA N/A I 

### !apron, exhaust I I 

### I 

# : I I 

# n I 

### I I I I 

### • I**(14)-~** (15) 

### None 

# I 0 M.x

### 00tJUboll: ifyvu

# .ttadl. CCIIltlm

__ ....

FORM EPA 1'1lCJ.2S (1ft. 5-95) PaplO 

### a

### Part II-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE
­ Continued Section B - INDUSTRIAL SITES CONTROLLED BY OTHERS Complete se<:tion B for typical processing oruse operations involving the new chemical substance Olt sites you do not control Importen do not have to complete this section for operations outside tho U.S.; however, you must report any processin& or use activities after import. See the Instructions Manual Complete a separale sectionBfor each type ofprocesnng. orlise**o~ration** involving Ihe new chemicailllbstance. Ifthe same operation is performed at more than one site describe the typical operation commonto these sites. Identify additional sites on a continuation sheet 1. Operation Description
- To claim information in this section as confidential, circle or bracket the specific information thatyou claim as confidential. (1) •• Diagram the major unit operation steps and chemical conversions. including interim storage andtransport containers (spe<:ifY. e.g. S gallon pails. S S gallon drums, rail cars, tanktrueb, etc). Onthe diagram. identifY by letter and briefly describe each worker activity. (2)
- Provide the identity, the approximate weight (by kw'day orkglbatch. on an 100% new chemical substance basis). and entry point ofall feedstocks (including reactants, solventl and catalysts. etc) and all products, =ycle 

### streams. and wastes. Include cleaning chemicals (note frequency ifnot used daily orper batch). (3)
- IdentifY by number the points of"release, including small orintermittent releases, to the environment ofthe new chemical substance. (4) Please enter tho /I ofsites (remember to identify the locations of these sites on a continuation sheet): 

# CONFIDENTIAL**~** 

# [ 1 /I ofsites 

### 35% - Formulation containing the PMN chemical 

### + 65% - Carbon or glass fiber

# ~ Prepreg operation 

## :> Molding and curing operation 

# ill @ 

# ® 

# t Finished article 

# o MIIlk (X)this box ifyou attach a continuation sheet. 2. WorkerExposurelEnvironmentai Re1_ (1)
- From Ibe diagram above, provide the letter for each worker activity. Complete 2·8 for each worbr activity described. (2)
- Estimate tho number ofworkers exp080d for all sites combined. (4)
- Estimale the typical duration ofexposure per worlc.er in (a) hours per day and (b) days per year. (6)
- Describe physical form ofexposure and ."new chemical substance (ifin mixture), and any protective equipment and engineering controls, if any, used to protect worIc.er.: (7)
- Estimate the percent ofthe new substance u formulated when packaged or\lied u a fmal product. (9)
­ From the process diagram above, entertho number ofeaclI release point Complete 9-13 for ead! release poiJIl identified. (10)
- Estimate the amount ofthe new substance released (a) directly to the enviroruneDl or (b) into control technology to the environment (in kw'day or kglbatch). (12)
- DesCrIbe media ofrelease i.e. stadt air, fugitive air (optional·see Instructions Manual), surface water, OIHite or off-site land or incineration, POTW, or other (specify) and control technology, ifany, that will be used to limitthe reJeuo ofthe new substance to tho environmml. (14)
- Identify byproducts which may resuh from tbeopenlion.

(3), (5), (8), 11). (13) and (IS)
­ Mark00this column ifany oftho proceeding entries are confidential**business~nformation** (CBI). Letter l#oC CBI Duration CBI Protective Equip. I %in CBI Rel_ Amolllltof CBI Media of Release CBI

of Worlcers of Engineering ControlS{ Form- Number New & Ccntrol Act· Exposed Exposure Physical Form and % u1atioft Substlllco Technology ivity new substance Releucd (\ ) (2) (3) (4a) (4b) (5) (6) (7) (8) (9) (\Oa) (\Ob) (1\) (12) (13) 

### A 

### 2 8 30 gloves, goggles, apron, 

### X 

### 1 0 

## <lkg Lined exhaust 

### !day landfill 

### 8 2 8 30 gloves, goggles, apron, X 

## N/A N/A N/A exhaust

14) •• Byproducts: (15) 

### none EPA FORM 7710·25 (Rev. 5·95) Page 

### lOb

## OPTIONAL POLLUTION PREVENTION INFORMATION To claim infonnation in this section as confidential circle or bracket the specific infonnation that you claim as confidential. 

### In 

## this section you may provide information not reported elsewhere in this form regarding your efforts to reduce or minimize potential 

## risks associated with activities surrounding manufacturing, processing, use and disposal ofthe P?v1N substance. Please include new information pertinent to pollution prevention, including source reduction, recycling activities and safer processes or products available due to the new chemical substance. Source reduction includes the reduction in 

## the amount or toxicity ofchemical wastes by technological modification, process and procedure modification, product reformulation, raw materials substitution, and/or inventory control. Recycling refers to the reclamation ofuseful chemical components from wastes that would otherwise be treated or released as air 

## emissions or water discharges, or land disposal. Descriptions ofpollution prevention, source reduction and recycling should emphasize potential risk reduction subsequent to compliance with existing regulatory requirements and can be 

## either quantitative or qualitative. The EPA is interested in the information to assess overall net reductions in toxicity or environmental releases and exposures, not the shifting ofrisks to other environmental media or non-environmental areas (e.g., occupational or consumer exposure). In addition, information on the relative cost or performance characteristics ofthe PMN substance to potential alternatives may be provided. All information provided in this section will 

## be taken into consideration during the review 

## ofthis substance. See Instructions Manual and PoUution Prevention Guidance manual for guidance and examples. Describe the expected net benefits, such as (1) 

### an overall reduction in risk to human health or the environment; (2) a reduction in the volume manufactured; (3) a reduction in the generation ofwaste materials through recycling, source reduction or other means; (4) a reduction in potential toxicity or human exposure and/or environmental release; (5) an increase in product perfonnance, a decrease in the cost ofproduction and/or improved operation efficiency ofthe new chemical substance in comparison to existing chemical substances used in similar application; or (6) the extent to 

### which the new chemical substance may be 

### a substitute for an existing substance that poses a greater overall risk to human health or the environment.



### Benefits are as follows: The PMN material is more resistant to heat and moisure than the current epoxy systems being used in the target applications. This yields a . longer lifetime in harsh environments, which reduces waste. It prov1des less outgassing than current systems, which also reduces waste. In addition, the higher glass transition**temper~ture** 

### allows higher solder temperatures with lower amounts of lead 1n the solder used.



# . l 

# J Mark (X) this box ifyou attach a continuation sheet. EPA FORM 7710·25 (Rev. 5-95) Page 11

## Part ill -- 

## LIST OF ATTACHMENTS Attach continuation sheets for sections ofthe fonn and test data and other data (including physical/chemical properties and structure/activity infonnation). and optional infonnation after this page. Clearly identify the attachment and the section ofthe fonn to which it relates, ifappropriate. Number consecutively the pages ofthe attachments. In the column below, enterthe inclusive page numbers ofeach attachment Mark (X) the "Confidential" box next to any attachment name you claim as confidential. Read the Instructions Manual for guidance on how to claim any infonnation in an attachment as confidential. You must include with the sanitized copy ofthe notice fonn a sanitized
, version ofany attachment in which you claim infonnation as confidential. Attachment name Attachment pue number(s) 

### Material Safety Data Sbeet tMSDS) 

## 14 

# - 17 Physical & 

### €hemical,Properties Worksheet 

## 13 Conti· dential



### Infrared specturm of PMN substance Differenctial scanning calorimetry 

## 18 19 Thermogravimetric analysis 

## 20 

## - 21 Gel permeation chromatographic analysis Mass spectrometric analysis Partition Coefficient (n-octanol/water) Study 

## 22 

# - 25 26 28 

# - 51 Nuclear Magnetic Resonance Analysis 

## 27

, ,

[ ] Mark (X) this box ifyou attach a continuation sheet. Enterthe attachment name and number. EPA FORM 77l{)"2S (Rev. S·9S) Page 12! 

### PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET To assist EPA's review ofphysical and chemkal properties data, please complete the following worksheet for data you provide and include it in the notice. Identify the property measured. the page ofthe notice on which the property appears, the value ofthe property. the units in which the property is measured (as necessary), and whether or not !he property is claimed as confidential. The physical state ofthe neat substance should be provided. These measured properties should be for the neat (100% pure) chemical substance. Properties that arc measured for mixtures orformu1ations should be so noted (% PMN substance in.-J. You arc not required to submitthis worksheet; hoftVCIr. EPA strongly recommends that you do so, as it will simplify review and ensure that confidential information is properly protected. You should submitthis worksheet as a supplement to your submission oftest data. This worksheet is not a substitute for submission oHest data. Property Mark Page Value lMeasum!o Confi. dentiaJ (Xl if (a) provided 

### Physical state ofneat substance X 

### Vapor pressure X ra>. 

### Temperature 

### °C Density/relative density X 

### Solubility @ 

### Temperature 

### °C

Solvent Solubility in water Temperature 

### 22 °C X 

### Melting temperature X 

### Boiling I 

### sublimation temperaturelOl torr pressure Spectra (infrared, mass spectrum) X 

### Dissociation constant Particle size distribution , 

### Octanoll 

### water partition coefficient X 

### Henry's Law constant Volitalization from water VoUtalization from soil pH@ concentration Flammability , 

### Explodability Adsorption I 

### coefficient Other
- Specify 

## DSC X 

## TGA X 

## GPC X 

## NMR X number (b) (c) 

## 16 (s) X .(l) 

## 16 low 

## 16 1. 

## 18

16 Insoluble 

## 16 60 

## - 80 

# 2l 8,


## 28-5

19 

### 20-21 22-25 27 (g) 

### Torr 2icm3


### JtIL 2IL 

### °C °C Estimate MIlk (X) eM orE) (d)



### M 

### E M

M M
M



### M

t1 

## M M M ATTACHMENT PAGE 13Vantlco Inc. North America 

### Polymer Specialties 281 Fieidl Line Brewatlr. NY 10501 a.m to 4:30pm PhOne: (114) 7IS-3OOO 24-Hour H4MIlthlEnvlronrnentlil EnwgMcy Phone:**1~** 

# vantico

MSDS No: 11075 

### Effective Date: 4/3/02 

### - Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Trade Name: RD 2000-40 Chemical FamUy: Benzoxazine Health 2 Flammability 

### 1 Reactivity 

### 0 Protective Equipment 

### X HMISRATING 2. COMPOSITION IINFORMATION ON INGREDIENTS 

### 0 CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS S H ACGIH OSHA A TWA STEL PEL STEL Confidential Benzouzine NE 

### NE NE 

### NE 

### CARCINOGEN STATUS MFR. IARC NTP OSHA

NE NR NR NR 

### NE

# =Not Established 

### NR

# =Not Reviewed



### 3. HAZARDS IDENTIFICATION Emergency Overview: Caution! The toxicological properties ofthis compound have nol been fully investigated. May 

### be toxic 

### if swallowed, inhaled. or absorbed through the mn. May cause liver. kidney and nervous system damage. 

### Primary Route(s) of

### Entry: Dermal, inhalation. 

### 4. FIRST AID MEASJJRFS Ingestion: Ifswallowed. immediately give at least 3-4 glasses ofwater, but do not induce vomiting. 

### Ifvomiting occurs. give fluids again. 

### Do not give anything by mouth to an unconscious orconvulsing person. Get immediate medical attention. Have physician determine whether vomiting or stoO'la(:h evacuation is 

### necessary. SIdn: For skin contact. wash affected areas with plenty ofwater, and soap, ifavailable. for several minutes. Get medical attention if irritation occurs.

Printed: 411512002 Page lof 4 

# Iii

### RD1OOO-4O Vantko Inc. 

### Effective 

### D.te: 413102 Polymer 

### Specialties Inhalation: 

### Ifinhaled. remove from area to 

### fresh air. Get medical attention ifrespiratory irritation develops or ifbreathing 

### becomes difficult. Eyes: For eye contact. flush 

### eyes with plenty ofwater for several minutes. Get medical attention ifirritation 

### occurs. Medkal Condltlons A.....v.1ed by 

### Exposure: 

### Allergy, eczema or skin conditions. Additional Information: 

### Wash contaminated clothing prior to reuse. 5. FIRE FIGHTING MEASURES Flasb PointMethod Used: 

### Closed Cup (similar product) 

### Fire 

## Fl&btlna 

## ExtInauisbiDa Media: 

### Carbon dioxide. foam. dry

### chemical. water spray. Fire 

## Fl&btlna Equipment: 

### Use self-contained breathing apparatus. FIre and Explosion 

### Hazards: 

### Decomposition and 

### combustion products 

### may be toxic. 6. ACCIDENTAL RELEASE MEASURES 

### Acddental Release 

### Measures: Sweep or vacuum and 

### place into closable container for disposal. Wear protective equipment specified below. 7. 

## HANPUNG AND STORAGE Precautions: 

### Avoid contact with eyes, skin and 

### clothing. Avoid breathing dust and 

### vapors ofheated material. Use with adequate 

### ventilation. Remove**~ontaminated** 

### noft-impervious clothing. wash before reuse. Individuals should wash thoroughly after 

### handling. 

### Avoid dusty conditions. Dust suspended in air 

### may be a tire and 

### explosion hazard. For industrial use only. Sto....e information: 

### Store in cool, dry 

### are 

### in sealed containers. Keep 

### containers closed to prevent moisture absorption and 

### contamination. 8. EXPOSURE CONTROLS I 

### PERSONAL PROTECTION Personal Protedive Equlp_t: Wear

### coveralls. Skin Protection: Wear impervious 

### gloves. Respiratory Protection: 

### Use NIOSH 

### approved dust respirator, if

### needed. Use respiratory equipment approved by NlOSH 

### for protection against aniline mists and 

### vapors. ifnecessary. Eye ProtectIon: Wear chemical goggles ifeye contact is possible. Engineerina Controls: 

### Work in well-ventilated areas. 9. PHYSICAL AND CHEMICAL PRQPERTIF3 

### Printed: 411512002 

### Page 2 of 4 

# IS

### RDlooo-4O V &Dtico InCo Effective Date: 4I3IOl 

### Polymer Specialties Color: Yellow Odor: No Discernable Odor Pbyskal 

### State: Solid 

### SolubiUty in Water: 

### Insoluble Vapor Pressure: Not detennined. but low at ambient tempcratW'es Spedfte 

### GraYity: 1.18 

### Meldq Point: 60
- 80°C (140
- 176 oF) 

### pH: 

### Not Detennined Pereent Volatile: Negligible. 10. 

### STABILITY AND

## REACTMTX StabiUty: Stable. IncompaUbiUty: Stronl oxidizinl aacnts. Hazardous Decomposition Products: Carbon monoxide. carbon dioxide. aldehydes. nitroacn oxides. Hazardous Polymerization: Will not occur. 

### 11. TOXICOLOGICAL INFORMATION Acute Oral Elfedl

### (LD50): Not evaluated. Acute Dermal ToDdty (LD50): Not evaluated. Inbalatlon ToDdty (LC50): Not evaluated. SensitIzation: Potential sensitizer. SkID Irritation: Not evaluated. Eye Irritation: Not evaluated. Cbronle Exposure 

### Elfedl: 

### Not evaluated. 

### 12. 

### ECOLOGICAL INFORMATION AdditloDallnformatlon: No ccoloaica1 information available. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose in accordance with 

### federal. state and 

### local regulations. 11. TRANSPORT

## INFORMATION DepartmentofTransportation: Not regulated. Printed: 411512002 

### Pale30f 4 

# 16RD1Q00.40 V

### utico Inc. 

### Effective Date: 4/3102 

### Polymer Spedalties

15. REGULATORY INf08MATION 

### US Federal Regulations: Occupational Safety and Health

### Act (OSHA): 

### This Material Safety Data Sheet (MSDS) has 

### been prepared in compliance with the federal OSHA Hazard Communication Standard 29 CPR 1910.1200. This product is not considered to be 

### a hazardous chemical under that standard. Resource CODSe"ation and 

### Recovery Act (RCRA): 

### Not a hazardous waste under RCRA (40 CPR 261). TSCA Seetion 8(b) • 

### Inventory 

### Status: This chemical substance is not included on the TSCA Inventory and is transmitted to you solely for research and 

### development 

### purposes and 

### may not 

### be used, 

### processed or distributed for a 

### commercial 

### purpose. In accordance with 40 CPR 720.36 ofthe 

### Premanufacture Notification rule. this substance may only be used 

### by. or directly under 

### the 

### supervision of. technically qualified individuals. 16. OTHER INF08MATION MSDSNo: 

### 1207' Prepared 

### By: M. Slattery Approved 

### By: James 

### E. Mumby 

### Title: Director. Product Safety Approved Date: 

### 04103102 Other Information: 

### For further information. contact Product Safety personnel at (914) 78'·3000. 

### Dlsdalmer: The 

### following supercedes Buyer's documents. SELLER MAKES NO REPRESENTA TION OR WARRANTY. EXPRESS OR IMPLJED. INCLUDING OF MERCHANTABILITY OR FITNESS FOR APARTICULAR PURPOSE. No statements herein are to be

### construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be 

### liable for incidental. consequential or indirect damages for alleged negligence, breach ofwamnty. strict liability. tort orcontract arising in connection with the

### product(s). Buyer's sole remedy and 

### Seller's sole liability for any claims shall be 

### Buyer's purchase price. Data and 

### results are based on controlled or lab work 

### and must be 

### confirmed by Buyerby testing for its intended conditions ofuse. The product(s) has not been tested for, and 

### is therefore not recommended for, 

### uses for which prolonged contact with mucous membranes, abraded skin. orblood is intended; orfor uses for which implantation within the 

### human body is intended.

Printed: 411'12002 Page40f 4 

# 17

### INFRARED SPECTRUM

# .... o

# .a. OeD 

### CU-l

I (I') ••


## ...... c.. IDO 

# ., •• CO CD 

## c.. r-ICD

## ~8 

# u (f) 

# o

teen 0&

I 

## -'0 00 (1')0 1(1') 

# a:. OJ 

# ...... CD r-I 

### 0. •• 

# s CD CO N

## ~U; 

# Iq

## THERMOGRAVIMETRIC ANALYSIS 

# t 

# r CONFIDENTIAL

# l 

# !

II
__ 1"'\



# 20THERMOGRAVIMETRIC ANALYSIS 

# CONFIDENT/AL

21

### GEL PERMEATION CHROMATOGRAPH 

## Ml111pore Corporatlon, Waters Chromatography Division 34 Maple Street, Mllford, Massachusetts 01757



# 22

### GEL PERMEATION CHROMATOGRAPH 

## Ml11ipore Corporation, Waters Chromatograpny Division 34 Maple Street, MIlford, Massachusetts 01757



# 23

### GEL PERMEATION CHROMATOGRAPH 

## Ml111pore Corporatlon, Waters Chromatography Dlvision 34 Map1e Street, Milford, Massachusetts 01757



# 2'1

### Gel**Per~eation Chromato~raph**  

## 1CI',-.-'oAW"". UUY/·...,,·"" .....**"''':''~-~.** -- .... _-**daErf-"VAXUNE-'-"-GVC--Yf'~J~"r-T'IfF'''-** 

### , , 

### 1.15920 20-Mar';'12 2: 

### 16t42



## ;PC Sl1ce Table, continued



# 25

# ,. MASS SPECTROMETRIC ANALYSIS j 

### Millennium Processing Report Page: 1 of 2 

### 'Report Method: Integration_Report Printed: July 11, 1990

Processed: 11/07/90 10:38:04 Version: 2.10
eIBA POLYMERS DIVISION RESINS LABORATORY 

# ,,­

# 27

## Study Title 

## Test Substance Fox: RD 2000-040: Partition Coefficient (n-OctanoVWater) High Performance Liquid Chromatography (HPLC) Method Guidelines 

## OECD Guideline for Testing ofChemicals, Section 1, Number 117

U.S. EPA Product Properties Test Guidelines: OPPTS 830.7570 Sponsor 

## Vantico, Inc. 281 Fields Lane Brewster, New York 10509 Study Initiated 

## March 14,2001 Study Completed 

## April 4 , 2002 Authors 

## Timothy J. 

## Ward Charmaine C. Rondon Robert L. 

## Boeri Testing Facility 

## T.R Wilbury Laboratories, Inc. 40 Doaks Lane Marblehead, Massachusetts 01945

T.R. Wilbury Study Number 2175-VA Page lof 24 

# 28

## I. GOOD LABORATORY PRACflCE COMPLIANCE STATEMENT This study was conducted according to U.S. 

## EPA FIFRA (40 CFR 160, 1993) and OECD 

## Good Laboratory Practice Regulations. The stability ofthe test substance WIder test conditions was assumed but not verified at T.R. 

## Wilbury Laboratories. Characterizations of the test substance and the reference substances were not performed in 

## compliance with GLP rules. The balance 

## used to weigh the sample container of the reference substance l,2,4­ trichlorobenzene before and after 

## use was not calibrated (balances must be calibrated daily before use). The proper handling, storage, and distribution of the reference substances formamide and p-dichlorobenzene 

## can not be verified based on the weight of the sample containers before and after 

## use. Deviations from the study protocol are presented 

## in Section 

# xm oftbis report.

Charmaine C. Rondon Study Director

Sponsor

Submitter

T.R. 

## Wilbury Study Number 2175-VA Page 2 of 24 

# 29

## Submittedby:

Certification:

" 

## ll. QUALfIYASSURANCE STATEMENT


## T.R Wilbury Laboratories, Inc. 40 

## Doaks Lane Marblehead, Massachusetts



## T.R Wilbury Laboratories, Inc., study number 2175-VA, "Test Substance Fox: RD 

## 2000-040: Partition Coefficient (n-OctanoVWater) High Perfonnance Liquid Chromatography (HPLC) Method," was audited by the Quality Assurance Unit for compliance with the protocol, standard operating procedures, and applicable 

## Good Laboratory Practices (U.S. EPA, 1993, OECD, 1997). Quality assurance audits were performed and the 

## findings reported to 

## T.R Wilbury Laboratories management and the study directoron the 

## following 

## dates: Reported Reported Aspect Audit to 

## Study to Audited Date Director Management 

## Protocol: 12FEB01 12FEB01 12FEBOl In-life 15MAY01 18MAYOl 18MAYOl Raw 

## DatalDraft Report llJUNOI BJUNOI llJUNOl Final Report: 04APR02 04APR02 04APR02



## Arthur P. Paradice, RQAP-GLP Quality Assurance Officer

T.R. Wilbury Study Number 2175-V A Page 3 of 24 

# 30

# m. TABLE OF CONTENTS

SECTION: PAGE 

### I. Good Laboratory Practice Compliance Statement 2 

### II. Quality Assurance Statement 3 

## III. Table ofContents 4 

### IV. Index ofTables and Figures 

## 5 V. Summary 

### 6 

## VI. General Information 

### 7 

## VII. Introduction 

### 8 

# vrn. Methods and Materials 

### 8 lX. Results and Discussion 11 

## X. Conclusions 12 " 

## XI. References 22 

### XII. Signature Page 23 

## XIII. Protocol Deviations 24

T.R. Wilbury Study Number 217S-VA Page 4 of 24 

# 31

## IV. INDEX OF TABLES AND FIGURES 

## PAGE Table 1. 

## Calculated log Pow values for the partition coefficient test (n-octanoVwater) with Fox. 13 

## Table 2. 

## Chromatographic peak areas from the partition coefficient test (n-octanoVwater) with Fox. 14 

## Table 3. Temperature measured during the partition coefficient test (n-octanoVwater) with Fox. 22 

## Figure 1. 

## Example chromatogram from the analysis ofthe test solution containing 39 mgIL (nominal) Fox prepared in 

## mobile phase. 15 

## Figure 2. 

## Example chromatogram from the analysis ofthe mixture of reference substances containing each component prepared in mobile phase. 16


## Figure 3. Example chromatogram from the analysis ofthe mobile phase blank containing acetonitrile. 17 

## Figure 4. 

## Example chromatogram from the analysis ofthe acetonitrile blank. 18 

## Figure 5. 

## Example chromatogram from the analysis ofthe forman).ide solution containing 96.0 mgIL (nominal) prepared in 

## mobile phase. 19 

## Figure 6. Correlation graph for the eight reference substances used to determine the partition coefficient ofFox. 

## 20

T.R. Wilbury Study Number 2175-VA 

## Page 5 of 24 

# 32

# V. SUMMARY The determination of the n-octanoJ/water partition coefficient (Pow) of Fox is described in this report. The test was conducted for Vantico, Inc. on May 15, 2001, at T.R. Wilbury Laboratories in Marblehead, Massachusetts. It 

### was conducted according to T.R. Wilbury Protocol Number 2175-VA. A preliminary test was conducted to provide an estimation ofthe run time to be used during the definitive test. This was accomplished by injecting a mixture of the reference substances 

### in the HPLC system and recording the chromatogram for 30 minutes. Thereafter, the solutions were injected 

### in the following sequence: the mixture of reference substances, a blank (acetonitrile diluted 1: 10 with the mobile phase), the fonnamide solution, the test solution 

### (in duplicate except during method validation), a blank (acetonitrile), the mixture of reference substances (reference substances were injected separately during method validation), and the fonnamide solution. The run time for all solutions was established at 30 minutes. The log Pow values for Fox, detectable with the chromatographic system used, were calculated as follows: Peak Number Retention Time log Pow

T.R. Wilbury Study Number 2175-VA Page 6 of 24 

# 33

## VI. GENERAL INFORMATION
Material Tested: Sponsor:
Test Substance Shipped From: Purity: 

## Study Initiation Date: Experimental Initiation Date: Experimental Termination Date: Study Completion Date: Fox: RD 2000-040 Vantico, Inc. 281 Fields Lane Brewster, New York 10509 Vantico, Inc. 281 Fields Lane Brewster, New York 10509 Assumed to be 

## 100% March 14,2001 (protocol signed) April 30, 2001 May 24, 2001 April 4, 2002

T.R. Wilbury Study Number 217S-VA Page 7 

## of 24 

# 3'1

## YD. INTRODUCTION This study was sponsored by Vantico, Inc. The purpose of the study was to detennine the n-octanoVwater coefficient (Pow) of Fox, the ratio of the equilibrium concentrations of the test substance in a 2-phase system consisting of 2 largely immiscible solvents (n-octanol and water). The report contains sections that describe the methods and materials employed in the study and results of the investigation. The final report will be transferred to the sponsor for archiving and the raw data and a copy ofthe final report will be archived at T.R. Wilbury Laboratories for at least 10 years. 

## VIll. METHODS AND MATERIALS TEST SUBSTANCE Fox (T.R. Wilbury Sample Number 1419) was delivered to T.R. Wilbury Laboratories on February 14, 200 1. It was contained in a 20 

## mL clear glass vial that was shipped in a cardboard box. The vial was labeled with the following infonnation: "Fox", The test substance (orange crystals) was shipped from Vantico, Inc., 281 Fields Lane, Brewster, New York 10509. Prior to use, the test substance was stored in the dark at room temperature. Based on infonnation supplied by the sponsor, the test substance is assumed to be 100% pure and stable under storage and exposure conditions. Unused test substance will be returned to the sponsor. 

## REFERENCE SUBSTANCES Eight chemicals, obtained from commercial suppliers and for which the log Pow has been reported, were used to calibrate the elution time in units oflog Pow. The mixture ofreference substances consisted ofthe following: Reference Substance benzyl alcohol (J.T. Baker, 100%) 

### 1.1 toluene (J.T. Baker, 99.7%) 2.7 p-dichlorobenzene (J.T. Baker, 99%) 3.4 1

### ,2,4-trichlorobenzene (E.M. 

### Science, 99.63%) 4.2 bibenzyl (Sigma Chemical Company, 99%) 4.8 fluoranthene (Sigma Chemical Company, 99%) 4.7 triphenylamine (Avocado Research Chemicals, 98%) 5.7 2,4-DDT (Chern Service Inc., 99.4%) 6.2 1 

### log Pow values according to the OECD guideline.

T.R. Wilbury Study Number 2175-VA Page 8 of 24

## TEST PROCEDURES The study was perfonned according to the protocol for T.R Wilbury Study Number**2175~** 

### VA, "Test Substance Fox: Partition Coefficient**(n~OctanollWater)** 

### High Perfonnance Liquid Chromatography (HPLC) Method". Solutions of the reference substances, excluding fonnamide, were prepared in acetonitrile (Burdick & 

### Jackson, lot # CB 620) at a concentration of760 to 870 mgIL. A mixture of the reference substances was prepared by adding a 500 aliquot of each solution (78 mgIL benzyl alcohol, 83 mgIL toluene, 87 mgIL**p~dichlorobenzene,** 

### 84 mgIL 1,2,4-Trichlorobenzene, 76 mgIL bibenzyl, 76 mgIL fluoranthene, 76 mgIL triphenylamine, and 78 mgIL**2,4~DDT)** 

### to a 5.0 

### mL class A volumetric flask and bringing the total volume to 5.0 

### mL with mobile phase (methanollHPLC water; 75/25; v/v). For the detennination ofto (dead time orthe average time it takes for an unretained solvent molecule to 

### pass through the column), a solution of fonnamide (E.M. Science. lot#**FX0420~8)** 

### was prepared in acetonitrile at a concentration of 96 mgIL by adding a 500 J.1L aliquot of solution to a 5.0 

### mL class A volumetric flask and bringing the total volume to 5.0 

### mL with mobile phase. A stock solution ofFox with a nominal concentration of 390 mgIL was prepared by bringing 0.0098 g oftest substance to a total volume of25 

### mL with acetonitrile. The stock solution was diluted by adding a 500 aliquot of solution to a 5.0 

### mL class A volumetric flask and bringing the total volume to 5.0 

### mL with mobile phase. For a preliminary estimation ofthe run time, the mixture ofreference substances was injected in the HPLC system and was recorded for 30 minutes. Thereafter, the solutj.pns were injected in the following sequence: the mixture ofreference substances, a blank (acetonitrile diluted 1:10 with the mobile phase), the fonnamide solution, the test solution (in duplicate except during method validation), a blank (acetonitrile), the mixture of reference substances (reference substances were injected separately during method validation), and the fonnamide solution. The run time for all solutions was established at 30 minutes. The temperature in a flask of deionized water next to the mobile phase was recorded several times during the analysis (thennometer 125). 

## ANALYTICAL METHOD Samples were 

### analyzed using a Hewlett Packard Series 1100 HPLC equipped with a diode arraylUV detector set at 230 nm and a 10 nm bandwidth. Typical instrumental conditions were: Column: Zorbax**SB~C8** 

### (4.6 mm x 150 mm), 5J.1ffi at 25°C Column flow: 1.0 mUminute Total run time: 30 minutes Injection size: 50**~** 

### Mobile phase: 75:25 (v:v) methanol:HPLC grade water Flow program: Isocratic. T.R Wilbury Study Number 2175-VA Page 9 of 24 

# 36

### The analytical method was validated prior to the start of the definitive test. Method validation samples consisting of the mixture of reference substances, a blank (acetonitrile diluted 1: 10 with the mobile phase), the formamide solution, the test solution, a blank (acetonitrile), the eight individual reference substances, the mixture ofreference substances, and the formamide solution were injected to establish the retention time order. 

### CALCULATIONS The capacity factor (k') was determined for each reference substance and the test substance using the following equation: 

## tR- 

## to k' 

# = where: tR 

# = test/reference substance retention time 

# to = the dead time [the average time it takes for an unretained solvent molecule (formamide) to pass through the column]. A linear regression plot of the log k' for the reference substances vs. log Pow values of the reference substances was used to determine the log Pow for each peak identified in the test substance (R2 

# = 0.9938). A comparison ofthe log k values for the test substance with the log k values ofthe reference substances was used to determine the log Pow for the test substance according to the following regression equation:
" 

### y 

# = 0.2919x
- 0.9174 where: y 

# = log k' for the test substance x 

# = log Pow 

### for the test substance

T.R. Wilbury Study Number 2175-VA Page 10 of 24 

# 37

### IX. 

## RESULTS AND DISCUSSION Representative HPLC chromatograms of the test solution, the 

## mixture of reference substances, the blanks (acetonitrile diluted with mobile phase), and the formamide solution are presented in Figures 1 to 5. The 

## to was determined to be 1.630 minutes with a mean value ofboth measurements (1.629 and 1.631 minutes). The mean values ofthe retention times, k' values, log k' values, and log Pow values are summarized in Table 1 and the correlation graph for the eight reference substances is presented in Figure 6. Chromatographic peak areas are presented in Table 2. The temperature ofthe area surrounding the mobile phase was 24°C during the analysis (Table 3). The log P _ values for Fox, detectable with the chromatographic system used and reported using the mean ofdata from duplicate injections, were calculated as follows: PeakNumber Retention Time

The log Pow values calculated individually for each duplicate injec.tion were identical for each peak. Components of Fox with retention times less than 1.5 to 2.0 minutes, and log Pow values below 1.5 would generally be considered hydrophilic and unlikely to be significantly accumulated in organisms**(Ran~** 

### 1995). Components with log Pow values above 6.0 are generally considered to be superhydrophobic and readily accumulated, but their accumulation can be mitigated by the large size of these molecules. Compounds with log P _ values between 1.5 and 6.0 generally accumulate, but the accumulation of individual components of Fox that fall within this log P _ range would need to be evaluated individually for bioaccumulation because factors such as uptake and depuration kinetics, and metabolism could affect accumulation in organisms.
T.R Wilbury Study Number 2175-V A Page II of 24 

# 38

## X. CONCLUSIONS Fourteen individual peaks were identified on duplicate chromatograms produced by HPLC analysis of Fox. The retention times of these peaks were compared to the retention times ofeight reference substances with known log Pow values. The calculated log Pow values for the fourteen peaks identified in the sample of Fox were [ ] 

# ( J

# CONF\DENT\~L

T.R. Wilbury 

### Study Number 

### 217S-VA Page 12 of 24 

# 3<1

## Table 1. 

## Calculated log Pow values for the partition coefficient test (n-octanoUwater) with Fox. Substance**~l** 

### k' 

## logk' Reference Substance 

## Benzyl alcohol 2.003 0.229 -0.641 1.1 Toluene 3.081 0.890 -0.051 2.7 p-dichlorobenzene 3.642 1.234 0.091 3.4 1,2,4-Trichlorobenzene 4.865 1.984 0.298 4.2 Fluoranthene 5.913 2.628 0.420 4.7 Bibenzyl 6.479 2.975 0.473 4.8 Triphenylamine 10.528 5.459 0.737 5.7 2,4-00T 14.792 8.075 0.907 6.2 Test Substance 

## Peak 1 Peak 2 Peak 3 Peak 4 Peak 5 Peak 6 Peak 7 Peak 8 Peak'!) Peak 10 Peak 11 Peak 12 Peak 13 Peak 14 1 

## Mean value ofthe retention times ofthe two reference substance or test substance

chromatograms. 2 

## Reference substance log Pow values according to 

## the OECO guideline.

T.R. Wilbury Study Number 2175-VA Page 13 of 24 

# '-10

## Table 2. Chromatographic peak areas from the 

## partition coefficient test (n-octanol/water) with Fox. Area Mean 

## Retention Time Replicate 1 

## Replicate 2 Mean



## T.R. Wilbury Study Number 2175-

## V A Page 14 of 24 

# 41

# CONFIDENTIAL

DADI A. Sig:23O.10 Ref=ofl (J:IHPCHEMlIIOATAI2175\005-0501,O) mAU 175 150 125 100 7S 50 2S 5 10 15 20 m' o CO

, 

### Figure 1. Example chromatogram from the analysis of the test solution containing 39 mgIL (nominal) Fox prepared in mobile phase

T.R. Wilbury Study Number 2175-VA Page 15 of 24 

# 42DADl A. SIgoo230.10 (J:IHPCHEMl1IOATAI21751OO2-0201.0) rnAU 300 250 

# ! 200 

## ii 150 

# ... 100 50 ;! 

## II 8 ;; 

### g "= 

# 1

...

# ~! ,..:**'---'!!'r~·L\** I 0 0 

### $ 10 15 20 m' 

## Figure 2. Example chromatogram from the analysis of the mixture of reference substances containing each component prepared in mobile phase.

T.R. 

## Wilbury Study Number 2175-VA Page 16 

## of 24 

# 434 2 CADl A.**S9"~.III.l** II

# 1'(""'" (J:IHPCHEMll\OATA121751OO3-0301.CI mAU

a ·2 0

### \~
5 10 15 20 25 ",.,j 

### Figure 3. Example chromatogram from the analysis of the mobile phase blank , ' containing acetonitrile.

T.R. Wilbury Study 

### Number 2175·YA Page 17 of 24OAOI A. Slril-230.10**R.r-.:o«(J:IHPCH~'1DAT"I2175\OO1-4701.0)** mAU 

# -

& 4 2 

# oH -2 -4 ,'5

0 5 10 20 2S mit**~igure** 

### 4. Example chromatogram from the analysis ofthe acetonitrile blank.
,



## T.R. Wilbury Study Number 2175-VA Page 18 of 24 

# 45

# CONFIDENTIAL

OADI A. Slga230.10 RtIPaII (J:lHf'CHEMl1\OATA1217511)09.011C)1 ,0) rMU

30 25 20 15 10 5 Or-,

o 

### Figure S. Example chromatogram from the 

## analysis of the formamide solution containing 96.0 mgIL (nominal) prepared 

## in mobile phase.



## T.R. Wilbury Study Number 2175·

## V A Page 19 of 24 

# 46

### 1 

### 0.8 0.6 0.4 0.2 ::li.I 00 

# .3 0 -0.2 -0.4 -0.6 -0.8 y"0.2919x· 0.9174 

### R2 =0.9938



# •

,

# . 0 1 

### 2 

### 3 4 Log Pow 

### 5 6 7


### Figure 6. Correlation graph for the eight reference substances.used to determine the partition coefficient ofFox.

T.R. Wilbury Study Number 217S-VA Page 20 of 24 

# '-/7

## Table 3. Temperature measured during the partition coefficient test (n-octanoVwater) with 

## Fox. Time Temperature (OC) 

## 1450 24 1500 24 1540 24 1550 24 1610 24 1622 24

T.R. Wilbury Study Number 

## 2175-V A Page 

## 21 of 

## 24

## XI. REFERENCES
OECD. 1997. OECD Principles ofGood Laboratory Practice. [C(91) 1861 

### Final]. OECD Guidelines for Testing Chemicals. 1989. Section 1. 

### No. 117. Partition Coefficient (n-OctanollWater), High 

### Performance Liquid Chromatography (HPLC) Method. Adopted March 30, 1989. Rand, 

### G.M., 1995. Fundamentals ofAquatic Toxicology: Effects, Environmental Fate, and Risk Assessment. Second Edition. Taylor and Francis, Bristol, PA. 1125 pp. U.S. EPA. 1993. 40 CFR Part 160. Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA); Good Laboratory Practice Standards. Code of Federal Regulations, Title 40 Part 160. U.S. EPA. 1996. Product Properties Test Guidelines. OPPTS 830.7570. Partition Coefficient (n-OctanollWater) Estimation by Ljquid Chromatography. EPA 712­ C-96-040.

T.R. Wilbury Study Number 2175-VA Page 22 of 24 

# '-19

## XII. SIGNATURE PAGE

Channaine C. Rondon Date Study Director and Coauthor

# h(1i~~**Ka~** Dlstelbrink Analytical Chemist

Robert 

## L. Boeri Date Coauthor

# T~~ar Date Au or

T.R Wilbury Study Number 217S-VA Page 23 of 24 

# 5()

## Xlll. PROTOCOL DEVIATIONS

No protocol deviations occurred during this study.

, ,



## T.R. Wilbury Study Number 217S-

## V A Page 24 of 24 

# S1