# Lime Unit1 The PM is the fiterable PM From UNC, file date 2013-02-04; resaved so visible on screen when not maximized

**Uncontrolled PM10 Speciation from AP-42 Tables 1.3-2 & 1.3-5 Uncontrolled Industrial Residual Oil Boiler**  assumes firing of # **2** oil with a sulfur content of **0.05** %S; therefore, A = 0.426 f(RH) = **1** Assumes heating value of **140,000** Btu/Gal and a heat input of **8.172** mmBtu/hr
Uncontrolled PM10 Emissions**(Bold**Values from Tables 1.3-2 and 1.3-5.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mGal) (lb/mGal) (lb/mGal) Coef. (lb/mGal) (lb/mGal) Coef. (lb/mGal) Coef. (lb/mGal) (lb/mGal) Type Ext.Coef. (lb/mGal) Type Ext.Coef. Industrial 4.55 **3.05** 1.07 0.6 **1.99** 1.84 1 0.15 10 **1.5** 1.28 SO4 3*f(RH) 0.23 SOA 4

Uncontrolled PM10 Emissions Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (% of Total) (% of Total) (% of Total) Coef. (% of Total) (% of Total) Coef. (% of Total) Coef. (% of Total) (% of Total) Type Ext.Coef. (% of Total) Type Ext.Coef. Industrial 100% 67.1% 23.4% 0.6 43.7% 40.4% 1 3.2% 10 32.9% 28.0% SO4 3*f(RH) 4.9% SOA 4

Uncontrolled PM10 Emissions Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef. Industrial 0.033 0.022 0.008 0.6 0.014 0.013 1 0.001 10 0.011 0.009 SO4 3*f(RH) 0.002 SOA 4

**If you are given Total PM10 emissions in lb/hr:** Uncontrolled PM10 Emissions**(Bold**Value is**Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/hr) (lb/hr) (lb/hr) Coef. (lb/hr) (lb/hr) Coef. (lb/hr) Coef. (lb/hr) (lb/hr) Type Ext.Coef. (lb/hr) Type Ext.Coef. Industrial **7.651** 5.1 1.8 0.6 3.3 3.1 1 0.2 10 2.5 2.1 SO4 3 0.4 SOA 4 Weighted Extinction 1.1 3.1 2.5 6.4 1.5 1.9 **If you are given Total PM10 emissions in lb/mmBtu:** Uncontrolled PM10 Emissions**(Bold**Value is**Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef. Industrial **0.033** 0.022 0.008 0.6 0.014 0.013 1 0.001 10 0.011 0.009 SO4 3 0.002 SOA 4

Uncontrolled PM10 Emissions**(Bold**values from Table 1.3-2 and from Table 6 of EPA’s January 2002 DRAFT “Catalog of Global Emissions Inventories and Emission Inventory Tools for Black Carbon.”) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (% of Total) (% of Total) (% of Filterable) Coef. (% of Filterable) (% of Filterable) 1 (% of Filterable) Coef. (% of Total) (% of Condensible) Type Ext.Coef. (% of Condensible) Type Ext.Coef. Industrial 100% 67.1% 34.9% 0.6 65.1% 60.3% 1 4.8% 10 32.9% **85%** SO4 3 **15%** SOA 4 (% of Fine) Coef. (% of Fine) Coef. 92.6% 1 **7.4%** 10 **If you are given Filterable PM10 emissions in lb/hr:** Uncontrolled PM10 Emissions**(Bold**Value is**Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/hr) (lb/hr) (lb/hr) Coef. (lb/hr) (lb/hr) Coef. (lb/hr) Coef. (lb/hr) (lb/hr) Type Ext.Coef. (lb/hr) Type Ext.Coef. Industrial 7.651 **5.1** 1.8 0.6 3.3 3.1 1 0.2 10 2.5 2.1 SO4 3 0.4 SOA 4 **If you are given Filterable PM10 emissions in lb/mmBtu:** Uncontrolled PM10 Emissions**(Bold**Value is**Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef. Industrial 0.033 **0.022** 0.008 0.6 0.014 0.013 1 0.001 10 0.011 0.009 SO4 3 0.002 SOA 4

Coarse 23.4% Coarse 1.8 Fine Soil 40.4% Fine Soil 3.1 Fine EC 3.2% Fine EC 0.2 CPM IOR 28.0% CPM IOR 2.1 CPM OR 4.9% CPM OR 0.4

100.0% 7.7

# 23.4%

40.4% 3.2% 28.0% 4.9% 

# Uncontrolled**Residual Oil** 
**- fired Industrial Boiler PM10** **Speciation Profile** 

Coarse Fine Soil Fine EC CPM IOR CPM OR

# 1.8

3.1 0.2 2.1 0.4 

# Uncontrolled**Resdiual Oil** 
**- fired Industrial Boiler PM10** **Emissions (lb/hr)** 

Coarse Fine Soil Fine EC CPM IOR CPM OR

# Uncontrolled Residual Oil-fired Industrial Boiler

**from A P-42 Table 1.3-5**  (User inputs**filterable**emission rate in lb/hr) Particle Cumulative Mass Fraction of PM10 Particle Filterable Size < Stated Size < Stated Size Size Range by size (um) **Unc** (%) (um) Emissions 10 86% 100% 10-6 0.5 6 77% 90% 6-2.5 1.3 2.5 56% 65% 2.5-1.25 1.0 1.25 39% 45% 1.25-1.0 0.2 1 36% 42% 1.0-625 0.4 0.625 30% 35% 0.625-0 1.8

**CA LPUFF**  **Filterable Filterable**  Particle Particle Size Fraction Emissions Extinction Emissions Size (um) Range (um) (% of Total) (lb/hr) Coef. (g/sec) 8 10-6 10% 0.537 0.600 0.07 4.25 6-2.5 24% 1.3 0.6 0.16 35% Coarse >/= 2.5 micron 1.88 2.5-1.25 20% 1.0 1 0.13 65% Fine Soil </= 2.5 micron **1.25** 1.25-1 3% 0.2 1 0.02 0.813 1.6-25 7% 0.4 1 0.05 **0.625** 0.625-0 35% 1.8 1 0.19 10 0.03 7.4% of Fine Soil Totals 100% 5.1 0.65

# 10%

24%

20% 3% 7% 35% 

# Uncontrolled **Residual Oil** 
**- fired** **Industrial Boiler Fraction** **of Filterable PM10** 

10-6 6-2.5 2.5-1.25 1.25-1 1.6-25 0.625-0

# 0.5

1.3

1.0 0.2 0.4 1.8 **Uncontrolled Residual** **Oil**
**- fired Industrial Boiler Filterable PM10 Emissions** **(lb/hr) in Each Size Range**

10-6 6-2.5 2.5-1.25 1.25-1.0 1.0-625 0.625-0