Lime Unit1 The PM is the fiterable PM From UNC, file date 2013-02-04; resaved so visible on screen when not maximized

Uncontrolled PM10 Speciation from AP-42 Tables 1.3-2 & 1.3-5

Uncontrolled Industrial Residual Oil Boiler 

assumes firing of # 2 oil with a sulfur content of 0.05 %S; therefore, A = 0.426 f(RH) = 1

Assumes heating value of 140,000 Btu/Gal and a heat input of 8.172 mmBtu/hr

Uncontrolled PM10 Emissions (Bold Values from Tables 1.3-2 and 1.3-5.)

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (lb/mGal) (lb/mGal) (lb/mGal) Coef. (lb/mGal) (lb/mGal) Coef. (lb/mGal) Coef. (lb/mGal) (lb/mGal) Type Ext.Coef. (lb/mGal) Type Ext.Coef.

Industrial 4.55 3.05 1.07 0.6 1.99 1.84 1 0.15 10 1.5 1.28 SO4 3*f(RH) 0.23 SOA 4

Uncontrolled PM10 Emissions

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (% of Total) (% of Total) (% of Total) Coef. (% of Total) (% of Total) Coef. (% of Total) Coef. (% of Total) (% of Total) Type Ext.Coef. (% of Total) Type Ext.Coef.

Industrial 100% 67.1% 23.4% 0.6 43.7% 40.4% 1 3.2% 10 32.9% 28.0% SO4 3*f(RH) 4.9% SOA 4

Uncontrolled PM10 Emissions 

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef.

Industrial 0.033 0.022 0.008 0.6 0.014 0.013 1 0.001 10 0.011 0.009 SO4 3*f(RH) 0.002 SOA 4

If you are given Total PM10 emissions in lb/hr:

Uncontrolled PM10 Emissions (Bold Value is Input by user.)

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (lb/hr) (lb/hr) (lb/hr) Coef. (lb/hr) (lb/hr) Coef. (lb/hr) Coef. (lb/hr) (lb/hr) Type Ext.Coef. (lb/hr) Type Ext.Coef.

Industrial 7.651 5.1 1.8 0.6 3.3 3.1 1 0.2 10 2.5 2.1 SO4 3 0.4 SOA 4

Weighted Extinction 1.1 3.1 2.5 6.4 1.5 1.9

If you are given Total PM10 emissions in lb/mmBtu:

Uncontrolled PM10 Emissions (Bold Value is Input by user.)

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef.

Industrial 0.033 0.022 0.008 0.6 0.014 0.013 1 0.001 10 0.011 0.009 SO4 3 0.002 SOA 4

Uncontrolled PM10 Emissions (Bold values from Table 1.3-2 and from Table 6 of EPA’s January 2002 DRAFT “Catalog of Global Emissions Inventories and Emission Inventory Tools for Black Carbon.”)

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (% of Total) (% of Total) (% of Filterable) Coef. (% of Filterable) (% of Filterable) 1 (% of Filterable) Coef. (% of Total) (% of Condensible) Type Ext.Coef. (% of Condensible) Type Ext.Coef.

Industrial 100% 67.1% 34.9% 0.6 65.1% 60.3% 1 4.8% 10 32.9% 85% SO4 3 15% SOA 4

(% of Fine) Coef. (% of Fine) Coef.

92.6% 1 7.4% 10

If you are given Filterable PM10 emissions in lb/hr:

Uncontrolled PM10 Emissions (Bold Value is Input by user.)

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (lb/hr) (lb/hr) (lb/hr) Coef. (lb/hr) (lb/hr) Coef. (lb/hr) Coef. (lb/hr) (lb/hr) Type Ext.Coef. (lb/hr) Type Ext.Coef.

Industrial 7.651 5.1 1.8 0.6 3.3 3.1 1 0.2 10 2.5 2.1 SO4 3 0.4 SOA 4

If you are given Filterable PM10 emissions in lb/mmBtu:

Uncontrolled PM10 Emissions (Bold Value is Input by user.)

Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle 

Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef.

Industrial 0.033 0.022 0.008 0.6 0.014 0.013 1 0.001 10 0.011 0.009 SO4 3 0.002 SOA 4

Coarse 23.4% Coarse 1.8

Fine Soil 40.4% Fine Soil 3.1

Fine EC 3.2% Fine EC 0.2

CPM IOR 28.0% CPM IOR 2.1

CPM OR 4.9% CPM OR 0.4

100.0% 7.7
23.4%

40.4%

3.2%

28.0%

4.9%

Uncontrolled Residual Oil-fired Industrial Boiler PM10 Speciation Profile

Coarse

Fine Soil

Fine EC

CPM IOR

CPM OR
1.8

3.1

0.2

2.1

0.4

Uncontrolled Resdiual Oil-fired Industrial Boiler PM10 Emissions (lb/hr)

Coarse

Fine Soil

Fine EC

CPM IOR

CPM OR
Uncontrolled Residual Oil-fired Industrial Boiler

from AP-42 Table 1.3-5

(User inputs filterable emission rate in lb/hr)

Particle Cumulative Mass Fraction of PM10 Particle Filterable

Size < Stated Size < Stated Size Size Range by size

(um) Unc (%) (um) Emissions

10 86% 100% 10-6 0.5

6 77% 90% 6-2.5 1.3

2.5 56% 65% 2.5-1.25 1.0

1.25 39% 45% 1.25-1.0 0.2

1 36% 42% 1.0-625 0.4

0.625 30% 35% 0.625-0 1.8

CALPUFF Filterable Filterable

Particle Particle Size Fraction Emissions Extinction Emissions

Size (um) Range (um) (% of Total) (lb/hr) Coef. (g/sec)

8 10-6 10% 0.537 0.600 0.07

4.25 6-2.5 24% 1.3 0.6 0.16 35% Coarse >/= 2.5 micron

1.88 2.5-1.25 20% 1.0 1 0.13 65% Fine Soil </= 2.5 micron

1.25 1.25-1 3% 0.2 1 0.02

0.813 1.6-25 7% 0.4 1 0.05

0.625 0.625-0 35% 1.8 1 0.19

10 0.03 7.4% of Fine Soil

Totals 100% 5.1 0.65
10%

24%

3% 20%

7%

35%

Uncontrolled Residual Oil-fired Industrial Boiler Fraction of Filterable PM10

10-6

6-2.5

2.5-1.25

1.25-1

1.6-25

0.625-0
0.5

1.3

1.0 0.2

0.4

1.8

Uncontrolled Residual Oil-fired Industrial Boiler Filterable PM10 Emissions (lb/hr) in Each Size Range

10-6

6-2.5

2.5-1.25

1.25-1.0

1.0-625

0.625-0