Arizona Department of Environmental Quality 

AQS Data Certification Detail Report 

SECTION 1 

2011 ADEQ DATA TO BE CERTIFIED 

Tables 1, 2, and 3 (Appendix A) list monitors with data reported to AQS requiring certification 

for the year 2011. They include several special purpose monitors (SPM), ADEQ’s State and 

Local Agency Monitoring Station (SLAMS) monitors, monitors in the Photochemical 

Assessment Monitoring Stations (PAMS) program, PM2.5 Chemical Speciation Network (CSN) 

monitors, National Air Toxics Trends Sites (NATTS) monitors, and Urban Air Toxics 

Monitoring Program (UATMP) monitors. A detailed description of these data and monitors 

follows. 

1.1 2011 CRITERIA POLLUTANT DATA FROM ADEQ SLAMS and SPM SITES 

Table 1 (Appendix A) lists the sites and parameters with 2011 data that ADEQ reported to AQS 

after completing our data review procedures. Attachments 1 and 2 (Appendix B) are the AQS 

AMP450 and AMP450NC reports verifying submittal completeness of the 2011 data for these 

monitors. The AMP255 report, summarizing the 2011 precision and accuracy data submittal for 

the criteria pollutant monitors, is also included as part of this certification letter (Attachment 3). 

While most of the data summarized in the attached reports are accurate and complete, ADEQ 

staff did encounter some challenges throughout the year. The following is a description of these 

challenges as well as some clarifications that are needed. 

1.1.1 Ozone Monitoring Challenges 

Beginning in 2011, ADEQ deployed new API ozone instrumentation to replace the aging TEI 

equipment that had been used for years. While the start of the ozone season went smoothly, 

technicians faced challenges during the second half of the season for two reasons. In an attempt 

to increase the efficiency for which ozone verifications occurred, ADEQ staff attempted to 

utilize the internal ozone generators within the API analyzers to perform remote zero, span, and 

precision checks. This practice began around June, 2011. After some comparability issues 

between the precision checks conducted with the internal ozone generators and the on-site 

transfer standards, ADEQ staff realized that the internal ozone generators were not properly 

certified. Since only one site had an actual adjustment performed based on the uncertified ozone 

generators, only a small amount of data were in need of invalidation because of this issue. The 

larger affect can be seen in the 1-point QC check data completeness numbers within the 

AMP255 report. Several precision checks were not reported to AQS due to the invalid nature of 

those checks. 

The second challenge that occurred in the second half of the ozone season was attributed to a 

combination of unfamiliarity with the new API instruments and an unusually dusty environment 

due to repeated monsoon dust storms. The dusty environment resulted in a relatively frequent 

occurrence of clogging of the inline filters. As a result, several of the sites’ monitors experienced 

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reduced flow rates which led to a positive systematic bias in ambient concentrations during 

specific periods of time. All data affected by this bias were invalidated based on the results of the 

bi-weekly zero, span, precision checks. As can be seen in the AMP450 report, this resulted in 

data completeness of 85% for two sites and 90% for another. Prior to the start of the 2012 ozone 

season, the instruments were equipped with a second inline filter to help prevent clogging of the 

sample lines and internal plumbing. 

1.1.2 Carbon Monoxide and Sulfur Dioxide Trace Level Monitoring at ADEQ’s NCore 

site, JLG Supersite 

 

ADEQ operates trace level carbon monoxide (CO) and sulfur dioxide (SO2) monitors at the JLG 

Phoenix Supersite (AQS ID 04-013-9997) as part of the NCore requirements. As can be seen in 

the AMP255 and AMP450 reports for CY2011, the abovementioned monitors did not meet the 

minimum requirements for data completeness and data quality. As have many agencies 

throughout the country, ADEQ monitoring staff faced several challenges implementing these 

trace level monitors. 

One significant issue that ADEQ technicians discovered was that the mutli-gas calibrator used to 

calibrate and verify the CO and SO2 analyzers was determined to be faulty due to incorrect 

internal programming by the manufacturer. The issue was not realized until after several months 

of troubleshooting. The multi-gas calibrator was sent back to the manufacturer, re-programmed, 

and a successful calibration occurred in October. Data from June through October had to be 

invalidated due to erroneous calibrations that occurred during the time. In addition to the 

calibrator issue, the CO instrument failed routine quality control checks and it was determined 

that the infrared source within the instrument needed to be replaced. Due to funding limitations, 

ADEQ did not (and still does not) have spare trace-level instruments available. Additionally, due 

to the upcoming change in fiscal year, funding approval for the repair of the instrument was 

delayed. After entering the new fiscal year and receiving approval, the instrument was sent to the 

vendor for repairs. In late September, it was returned to ADEQ, reinstalled at the site, and put 

back into service. 

ADEQ also experienced challenges with low level performance evaluation (PE) audits, 

particularly at the lowest level audit values. Initially, ADEQ was having trouble meeting the 

EPA suggested acceptance criteria of ± 3 ppb for SO2 and ± 30 ppb for CO. The SO2 challenges 

were quickly resolved in October and were believed to be at least partially due to the calibrator 

issues discussed above. However, ADEQ continued to struggle to meet the EPA suggested 

acceptance criteria for CO. One issue that was eventually corrected was the way in which the CO 

zero air supply and scrubbers were plumbed. The order of the scrubbers were arranged to more 

optimally produce ‘truer’ amounts of zero air. Upon this re-plumbing, QA audits and technician 

verifications were more aligned with one another. Still, both the auditor and technicians often 

flirted with the EPA suggested acceptance criteria of 30 ppb for low level audits and 

verifications. ADEQ hopes to work with EPA to establish appropriate acceptance criteria for the 

low level CO checks. 

While the valid data reported to AQS is believed to be accurate to the best of our knowledge, due 

to the challenges that ADEQ staff faced with trace level monitoring in 2011, ADEQ does not 

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wish to certify these trace level CO and SO2 data for CY2011. ADEQ expects improved 

confidence in these data for CY2012 and will provide a follow up on these trace level data in the 

2012 data certification letter. 

1.1.3 Douglas Red Cross PM10 Sampler 

As was discussed in the specific Douglas / Paul Spur data certification letter submitted to EPA 

on February 28th, 2012, the Douglas Red Cross PM10 sampler (AQS ID 04-003-1005-81102-1) 

did not meet the data completeness criteria required for PM10 SLAMS. Despite data 

completeness for CY2011 being above 75% (90%), this monitor fell short of the 75% quarterly 

completeness criteria in the 4th quarter of 2011 (73%). Four run days during this quarter were 

invalidated due to a combination of instrumentation issues that resulted in over-runs and operator 

errors that resulted in double runs on the same filter. Similar issues were reported in the 2010 

data certification letter. ADEQ continues to evaluate the filter-based PM network and ways to 

improve upon and eliminate these instrumentation and operator error issues. 

1.1.4 Continuous PM2.5 FDMS TEOM Monitor 

As mentioned in previous years’ data certification letters, ADEQ’s Data Management & Quality 

Assurance (DM&QA) staff has identified possible biases in the continuous FDMS TEOM PM2.5

data collected at the JLG Supersite. While this monitor regularly passed the monthly flow 

verifications and semi-annual flow audits, there are concerns with the performance of the internal 

dryer which may be causing instrument drift over time. Statistical analyses have revealed time 

dependent biases and step-like changes that are believed to be associated with dryer 

replacements. At this time, ADEQ does not elect to certify these data (AQS monitor ID 04-013-

9997-88500-3) due to the concerns mentioned above. Paired BAM monitors were installed in 

November, 2010 to meet the PMcoarse requirement at ADEQ’s NCore site. The data from these 

BAM monitors have confirmed the suspected biases in the PM2.5 FDMS TEOM data. Due to 

satisfactory performance of the PM2.5 BAM instrument, ADEQ monitoring staff removed the 

FDMS TEOM unit from operation in 2012. 

1.1.5 PM10 and PM2.5 Semi-Annual Flow Audit Completeness 

As can be seen in the Semi-Annual Flow Rate section of the AMP255 report, there are six PM10

and three PM2.5 monitors that contain an ‘N’ in the ‘Criteria Met?’ column. One of each of the 

PM10 and PM2.5 monitors contain this ‘N’ indicator due to an oversight on the QA group’s 

behalf. The JLG Phoenix Supersite PM BAM monitors (04-013-9997-81102-3 and 04-013-9997-

88101-3) were only audited once in CY2011 instead of the two audits that was required. Despite 

the oversight, the data are accurate and complete to the best of our knowledge. 

For the other five PM10 monitors and two PM2.5 monitors, the ‘N’ in the ‘Criteria Met?’ column 

exists due to a technicality in the timing of the audits. While not specifically required in the CFR, 

the report shows the N indicator when the two flow audits for each monitor are spaced further 

apart than 5-7 months. For these seven monitors, the two audits were either slightly less than five 

months apart or slightly more than seven months apart. While the QA groups strives to meet this 

5-7 month recommendation, the geographic spread of the monitors coupled with resource 

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limitations makes it difficult to always meet this recommendation. ADEQ QA staff will continue 

to meet the 5-7 month spread recommendation in subsequent years. Despite the ‘N’ indicator in 

the ‘Criteria Met?’ column, for the PM monitors mentioned in this section, the ambient 

concentration data and QC data are accurate and complete to the best of our knowledge. 

Taking into consideration the exceptions mentioned above in Section 1.1, I certify that for the 

monitors listed in Table 1 and Attachments # 1 and # 2, the ambient concentration data and the 

quality assurance data are completely submitted to AQS and that the ambient data are accurate to 

the best of my knowledge, taking into consideration the quality assurance findings. 

1.1.6 JLG Supersite PM2.5 Flow Verification QC Statistics 

As can be seen in the AMP255 report, the JLG Supersite PM2.5 secondary sampler (04-013-

9997-88101-2) contains anomalously high bias and average percent difference numbers (±35 and 

12.11 respectively) for the flow rate verification summaries. These QC statistics are very 

sensitive to outliers and the anomalous numbers are a result of one failed QC check that occurred 

in June, 2011. The ambient data associated with this failed QC check were invalidated in 

accordance with ADEQ standard validation procedures. ADEQ data management staff have been 

communicating with EPA headquarters on this issue and have been directed to only report QC 

data that are associated with valid ambient data in AQS. ADEQ has begun this practice 

beginning with 2012 data. 

1.1.7 Lead (Pb) Performance Evaluation Program (PEP) Data 

As can be seen in the AMP255 report, no Pb PEP data have been reported to EPA’s AQS 

database. EPA is responsible for submitting PEP data to AQS. ADEQ believes the issue is a 

combination of EPA PEP sampler performance issues as well as coordination issues between 

EPA, RTI, and state and local monitoring agencies. ADEQ was recently made aware of the online chain-of-custody (COC) data reporting mechanism through RTI’s website. ADEQ staff will 

be using this reporting mechanism for the PEP collocated sample COC information and 

hopefully this will help alleviate the delay and lack of data from the PEP samples. 

1.1.8 Freeport McMoRan PM10 Data 

As can be seen in the AMP255 report, the PM10 collocation summary data from the Miami Golf 

Course site (AQS ID 04-007-8000) shows a low completeness percentage of 40%. Nearly all 

data from both the primary and collocated monitor have been submitted to AQS, so ADEQ is not 

sure why the report shows a 40% completeness metric for collocation completeness. ADEQ 

believes it has something to do with a method code change that occurred near the end of the 1st

quarter in 2011. The number of valid samples listed in the AMP255 report matches exactly with 

the number of collocated pair samples collected under the 773 method code. ADEQ had been 

instructed by EPA to use the 773 method code for these data as the Thermo Partisol Dichot 

sampler had not been approved as an FEM or FRM for PM10 sampling. Recently though 

(March, 2011), the EPA approved the Thermo Partisol Dichot sampler as an FEM for PM10, 

therefore the method code was changed in AQS to reflect this approval. It appears as though t

AMP255 report does not handle this change in method code well. The actual collocation 

he 

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completeness percentage for the Miami Golf Course site is over 100% due to the collocation 

schedule being once every sixth day instead of the required once every twelfth day. In 

to the collocation completeness value being incorrect, the associated CV value is also incorrect

as it does not account for all collocation data. Instead of the 8% CV listed in the AMP255 

report, the true CV for the collocation data

addition 

 is 13%. 

ADEQ became aware of some issues with the Miami Golf Course collocation numbers toward 

the end of CY2011 and into the 1st quarter of 2012. While the differences in the collocated 

values were larger than normal for this period, the calculated CV is representative of the 

precision of the PM10 data. For any data being used for regulatory purposes, ADEQ urges the 

use of these QC metrics to help determine potential error in the ambient concentration data. 

1.1.9 Mexico PM Monitors 

Throughout CY2010 and CY2011, ADEQ contractors operated three PM sites on the Mexican 

side of the U.S. / Mexico border. Prior to January of 2008, the U.S. Department of State did not 

require individuals to display a U.S. passport in order to return to the U.S. after crossing the 

border into Mexico. Due to changes in these federal regulations and ADEQ procurement 

concerns, ADEQ monitoring staff was not supplied with U.S. passports beginning in CY 2008. 

As a result, ADEQ staff could not conduct filter exchanges or perform flow verifications and 

semi-annual flow audits on the Mexico PM monitors. During CY 2008, a contract was 

developed with a consulting firm to install new instrumentation in Mexico and conduct flow 

verifications and semi-annual flow audits as required in 40 CFR Part 58 Appendix A. This work, 

however, did not begin until the 1st quarter of 2009. Repeated instrumentation problems led to a 

backlog in reporting the data to the AQS database. During the spring of 2010, the Mexico 

instrumentation was switched from the troublesome Partisol Dichots to the more familiar Partisol 

2000s that ADEQ uses throughout its SLAMS network. As a result, the confidence in the quality 

of the data increased for CY2011 data, though ADEQ staff are still in the process of uploading 

the remaining data to EPA’s AQS database. Due to funding constraints, the Mexico PM monitors 

were discontinued in July, 2011. At this time, ADEQ does not wish to certify the Mexico 

monitor data for CY 2010 or 2011. ADEQ is working with the EPA Border Program as part of 

the U.S. – Mexico Border Air Policy Forum and the Air Monitoring Working Group to evaluate 

the adequacy of air quality monitoring networks along the border. Through this effort, 

relationships between EPA, ADEQ, Secretariat of Environment and Natural Resources 

(SEMARNAT), and Commission for Ecology and Sustainable Development (CEDES) are 

expected to develop, such that quality data can be shared across the border. 

1.2 2011 DATA FROM ADEQ PAMS MONITORS 

In 2011, ADEQ operated three sites (see Table 2 in Appendix A) for the collection of ozone, 

trace level reactive oxides of Nitrogen (NOy), volatile organic compounds (VOCs), carbonyls, 

and meteorology to comply with PAMS requirements. 

ADEQ contracts the laboratory analysis of their VOC and carbonyl samples to Eastern Research 

Group (ERG). ADEQ staff review the data and then give permission to ERG to load the data to 

AQS upon approval. In the 2010 data certification letter, ADEQ reported issues with carbonyl 

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monitoring and resultant data quality issues. These issues were corrected in 2011 prior to the 

start of the PAMS’ season. As a result, carbonyl data were collected and reported to AQS with 

no issues in 2011. However, 2010 data were affected by the carbonyl monitoring issue. See 

section 2.2 for a detailed description of the issue and a summary of the final resolution. 

ADEQ reports meteorology data to AQS from two sites to support the PAMS program. Standard 

meteorology data (ambient temperature, relative humidity, wind speed and wind direction) are 

collected and reported from the JLG Supersite (AQS ID 04-013-9997) while solar radiation data 

are collected and reported from the Vehicle Emissions Laboratory site (AQS ID 04-013-9998). 

Historically, the solar radiation data included measurements of total solar radiation and 

ultraviolet radiation. ADEQ has had repeated issues with the ultraviolet solar radiation 

instrument over the previous two years, and as a result, has elected to not report these data to 

AQS until the instrument is working properly and collecting valid data. In July, 2011, the 

ultraviolet solar radiation instrument was reinstalled and functioned properly. As a result, ADEQ 

began reporting these ultraviolet solar radiation data to AQS once again. 

As mentioned above, ADEQ has historically reported meteorological data from two sites to 

EPA’s AQS database. In 2011, the Data Management & Quality Assurance group recognized a 

deficiency in the PAMS data reporting requirement in that meteorological data were not 

collected or reported from the Queen Valley PAMS site. Since recognizing this deficiency, 

meteorological equipment was installed in 2011 and the data from these instruments will be 

reported to AQS beginning in 2012. 

Attachment # 2 (Appendix B) is the AQS AMP450NC report which includes an annual summary 

of the PAMS parameters collected at these sites. Currently, the data from the RASS sampler 

(wind profiler) are not submitted to AQS due to the complexity of the data. 

No precision or accuracy data are required to be reported to AQS for the PAMS data. Routine 

checks and audits of the meteorological equipment are conducted and are used to validate the 

meteorological data before submitting to AQS. Performance audits were conducted on NOy

monitors beginning in 2007 and continued throughout CY 2010. Additionally, biweekly 

precision checks and maintenance of these NOy monitors were performed and these QC data 

were submitted to AQS. The QC results from the biweekly precision checks suggest that the 

NOy monitors may be somewhat unstable. Due to concerns regarding the accuracy of these NOy

data, ADEQ does not wish to certify these data at this time. 

All PAMS data were carefully reviewed by our DM&QA staff with special attention to the 

quality control checks that were available. With the exception of the NOy data mentioned above, 

I certify that for the monitors listed in Table 2 and Attachment # 2, the ambient concentration 

data and required quality assurance data are completely submitted to AQS and that the ambient 

data are accurate to the best of my knowledge taking into consideration the quality assurance 

findings. This letter does not certify ERG (the analyzing laboratory) operations since those are 

not within ADEQ’s control.

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1.3 2011 DATA FROM ADEQ CSN AND NATTS MONITORS 

Table 3 (Appendix A) lists the monitors that are part of the CSN and NATTS monitoring 

programs. 

1.3.1 PM2.5 Chemical Speciation Network (CSN) 

 

ADEQ participates in the CSN program with two monitors operating at the JLG Supersite (Met 

One Super SASS and URG samplers). The samples from these monitors are processed by 

Research Triangle Institute (RTI). ADEQ reviews the data results each month before RTI loads 

the data into their AQS screening group. Attachment # 2 (Appendix B) is the AQS AMP450NC 

report which includes an annual summary of these data. 

Monthly quality control checks, annual calibrations, and quarterly audits are performed by 

ADEQ staff on the samplers. Until recently, there was is no mechanism to report these QA data 

to RTI or to enter these data into the AQS. RTI has since developed a tool for agencies to upload 

the monthly flow verification and audit data to their website. From there, the data are loaded to 

EPA’s AQS database. For CY2011, ADEQ DM&QA staff successfully loaded all monthly flow 

verification and quarterly flow audit data to the RTI website, which was in turn loaded to the 

AQS database. This letter certifies that the monitors were operated in accordance with the EPA 

QAPP for this program and proper and regular maintenance of the monitors occurred to ensure 

accurate data collection. However, this letter does not certify RTI operations since those are not 

within ADEQ’s control. 

1.3.2 National Air Toxics Trends Sites (NATTS) 

1.3.2.1 PM10 Metals Speciation 

In 2006, ADEQ began PM10 Metals Speciation monitoring at the JLG Supersite. In the past, 

filters used for PM10 NAAQS compliance were first quality assured and weighed internally for 

PM10 mass concentration and then sent to the ERG laboratory in quarterly batches for PM10

speciation analysis. This resulted in significant delays in PM10 speciation data reporting. 

Beginning July 1st, 2009, ADEQ used a continuous PM10 FEM monitor as the primary PM10

monitor for NAAQS compliance, but continued to use the filter-based PM10 monitor for PM10

speciation purposes. This allowed for a more timely analysis of PM10 speciation data by ERG 

(the analyzing laboratory). ADEQ reviews the data results before ERG reports the data into their 

AQS screening group. Attachment # 2 (Appendix B) is the AQS AMP450NC report which 

includes an annual summary of these data. 

Routine flow verifications, semi-annual calibrations, and semi-annual flow audits were 

performed on this monitor throughout CY 2011. These QC data had been reported to AQS in 

association with the PM10 data that had previously been reported. However, with the closure of 

the PM10 filter-based monitor in AQS, these QC data are no longer able to be reported. 

This letter certifies that the PM10 Metals Speciation monitor was operated according to ADEQ’s 

QAPP for ‘National Air Toxics Trends Stations, Air Toxics Monitoring Program, & 

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Photochemical Assessment Monitoring Stations’. This letter does not certify ERG operations 

since those are not within ADEQ’s control. 

1.3.2.2 Chrome VI 

In 2006, ADEQ began collection of Chrome VI (hexavalent chromium) samples at the JLG 

Supersite. Sample media are provided by ERG and returned to them for analysis. ADEQ’s 

DM&QA staff reviews the data results before ERG reports the data into their AQS screening 

group. Attachment # 2 (Appendix B) is the AQS AMP450NC report which includes an annual 

summary of these data. 

Audit procedures for this monitor were developed in 2007 and implemented in the field in 2008 

and continued into CY2011. Additionally, flow checks and maintenance on the monitor were 

performed using the SOP developed by ADEQ in 2006 and contained in ADEQ’s QAPP for 

‘National Air Toxics Trends Stations, Air Toxics Monitoring Program, & Photochemical 

Assessment Monitoring Stations’. All Chrome VI data were carefully reviewed by our Data 

Management & QA staff with special attention to the quality control checks that were available. 

This letter certifies that the monitor was operated following standard operating procedures, and 

proper and regular maintenance of the monitor occurred to ensure accurate data collection. This 

letter does not certify ERG operations since those are not within ADEQ’s control. 

1.3.2.3 Semi-volatile Organic Compounds (SVOCs) 

In July of 2007, ADEQ began collection of semi-volatile organic compounds at the JLG 

Supersite using a PUF sampler. Sample media are provided by ERG and returned to them for 

analysis. The DM&QA staff reviews the data results before ERG reports the data into their AQS 

screening group. Attachment # 2 (Appendix B) is the AQS AMP450NC report which includes 

an annual summary of these data. 

No precision data are reported to AQS from the PUF sampler. Audit procedures for this monitor 

were developed in 2010 and implemented in the field. Audits on the PUF sampler were 

conducted three times in 2011. Routine flow checks and maintenance on the monitor were also 

performed using the SOP developed by ADEQ in 2006 and contained in ADEQ’s QAPP for 

‘National Air Toxics Trends Stations, Air Toxics Monitoring Program, & Photochemical 

Assessment Monitoring Stations’. All SVOC data were carefully reviewed by our DM&QA staff 

with special attention to the quality control checks that were available. This letter certifies that 

the monitor was operated following standard operating procedures, and proper and regular 

maintenance of the monitor occurred to ensure accurate data collection. This letter does not 

certify ERG operations since those are not within ADEQ’s control. 

1.3.2.4 Volatile Organic Compounds (VOCs) and Carbonyls 

VOC and carbonyl data are collected at the JLG Supersite as part of the NATTS program. VOC 

data are also collected at the South Phoenix site (AQS ID 04-013-4003), which is part of the 

Urban Air Toxics Monitoring Program (UATMP). These monitors are operated by ADEQ staff 

and the samples are analyzed at ERG. The data are then reviewed by ADEQ’s DM&QA staff 

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before ERG loads the data to AQS. As mentioned in Section 1.2, ADEQ first reported issues 

with carbonyl monitoring and resultant data quality issues in the 2010 data certification letter. 

These issues were corrected in the spring of 2011. As a result, carbonyl data were invalidated for 

the 1st quarter of 2011, with subsequent quarters containing valid data. Please see section 2.2 for 

a detailed description of the issue and a summary of the final resolution. Attachment # 2 

(Appendix B) is the AQS AMP450NC report which includes an annual summary of these data. 

No precision data are reported to AQS from the VOC and Carbonyl samplers and audit 

procedures for these monitors have not yet been developed. All VOC and Carbonyl data were 

carefully reviewed by our DM&QA staff with special attention to the quality control checks that 

were available. This letter does not certify ERG operations since those are not within ADEQ’s 

control. 

Taking into consideration the exceptions mentioned in Section 1.3, I certify that for the monitors 

listed in Tables 2 and 3, and included in Attachment # 2, the ambient concentration data and the 

required quality assurance data are completely submitted to AQS and that the ambient data are 

accurate to the best of my knowledge, taking into consideration the quality assurance findings. 

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SECTION 2 

ADEQ DATA TO BE RE-CERTIFIED 

 

Table 4 (Appendix A) list monitors with data reported to AQS requiring certification or recertification for years prior to 2011 as well as 2011 data requiring re-certification that had been 

initially certified earlier in 2012. 

2.1 Paul Spur PM10 Data 

ADEQ certified PM10 data from the Paul Spur Chemical Lime Plant and Douglas Red Cross 

monitors in February, 2012. The early certification was needed to expedite a Clean Data Finding 

for the Douglas / Paul Spur planning area. Since then, a small reporting error was discovered for 

two data points in CY2011. The reporting error led to the erroneous validation of samples from 

both the primary and secondary monitors at the Paul Spur Chemical Lime Plant site for the 

September 7th, 2011 make up runs. The error was caught when reviewing design value 

documentation for this site. The September 7th, 2011 samples were correctly invalidated in 

August, 2012. The error did not affect design value calculations for the Paul Spur Chemical 

Lime Plant monitors; therefore there is no concern with the accuracy of the Clean Data Finding 

that was recently issued for the area. 

 

2.2 Carbonyl Data Quality Summary and Final Report 

As was discussed in some detail in section 1.3.2.4, ADEQ staff recently identified some issues 

with carbonyl data quality. The purpose of the description below is to summarize the issues that 

occurred and to clarify the quality of the carbonyl data that have been collected over the past 

decade. The findings that were initially reported in the 2010 data certification letter have since 

changed, and the summary below serves as a final update to the carbonyl monitoring issues. 

ADEQ staff identified anomalous carbonyl data during data review procedures in 2010. This 

review indicated significant increases in carbonyl concentrations in February, 2010, which 

persisted throughout the remainder of the year and into the first quarter of 2011. Since the 

increase in carbonyl concentrations coincided with a denuder replacement, it was initially 

suspected that the shift in concentrations marked a period of transition from invalid data to valid 

data (i.e. the problem was corrected with the denuder replacement). This was an important and 

significant discovery as it questioned the validity of years and years of carbonyl data collection 

at JLG Supersite. After careful review by ADEQ’s DM&QA and Monitoring staff, it was later 

determined that the denuder replacement that occurred in February, 2010 was erroneous, and that 

the February, 2010 maintenance actually began a period of invalid carbonyl data. When the 

carbonyl analyzers were certified by the manufacturer in the spring of 2011, the carbonyl data 

showed concentrations returning to pre-February 2010 values. The final determination was that 

the period from February, 2010 through March, 2011 resulted in invalid carbonyl data collection. 

Data prior to February, 2010 were determined valid, as were data collected after the March, 2011 

certification of the analyzers. ADEQ contacted ERG and asked to invalidate all carbonyl data 

associated with the faulty denuder replacement. Most of the data during that period were 

invalidated in AQS, though there were occasional valid data reported throughout 2010 and early 

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2011 due to occasional changes in the specific carbonyl analyzer used to collect samples. ADEQ 

is currently practicing annual certification of the carbonyl analyzers and will continue to do so to 

prevent future occurrences of similar issues. 

To clarify, ADEQ would like to certify all carbonyl data collected through CY 2011. While there 

were some periods of invalid data due to the issue discussed above, those data were properly 

invalidated in EPA’s AQS database and a null data code flag was applied to those samples. 

I certify that for the monitors listed in Table 4 and included in Attachments # 1 (Paul Spur 

Chemical Lime Plant data) and # 4 (carbonyl data), the valid ambient concentration data and the 

required quality assurance data are completely submitted to AQS and that the ambient data are 

accurate to the best of my knowledge, taking into consideration the quality assurance findings.
 

APPENDIX A 
Table 1. 2011 Data to be certified in AQS from ADEQ Criteria Pollutant Monitors 

X – Submitted to AQS 

SLAMS & SPMs Criteria Pollutant Parameters 

AQS Site ID Site Name Classification 

Pb, Temp, Pres 1-in-6 

14129, 68105, 68108 

O3 44201 

CO 42101 

NO, NO2 , NOx

42601,42602,42603 (POC1) 

SO2 & SO2 5 Min Max 

42401 & 42406 

PM10 81102, 85101 1-in-6 

days 

PM10 81102 Hourly 

(POC 3) 

PM2.5 Hourly 88500, 88501 

(POC 3) 

PM2.5 Hourly 88101 

(POC 3) 

PM2.5,, Temp, Pres. 1-in-6 

and 1-in-3 days 88101, 

68105, 68108 

04-003-0011 Paul Spur Chemical Lime Plant SLAMS XC

04-003-1005 Douglas Red Cross SLAMS X X 

04-005-1008 Flagstaff Middle School SLAMS X X X 

04-007-0008 Payson Well Site SLAMS XC

04-007-0009 Miami Ridgeline (ADEQ) SLAMS X 

04-007-0009 Miami Ridgeline (Freeport 

McMoRan) 

SLAMS X 

04-007-0010 Tonto National Monument SLAMS X 

04-007-1001 Hayden Old Jail SLAMS X X 

04-007-8000 Miami Golf Course (Freeport 

McMoRan) 

SLAMS XC

04-007-8000 Miami Golf Course (ADEQ) SLAMS X 

04-007-1002 Globe Highway SLAMS XC

04-012-8000 Alamo Lake SLAMS X 

04-013-8006 Bethune Elementary School SPM X 

04-013-9997 JLG Supersite SLAMS / 

NCORE X X X X X X N X X 

04-015-1003 Bullhead City SLAMS X 

04-019-0001 Ajo SLAMS X 

04-019-0020 Rillito SLAMS X 

04-021-8001 Queen Valley SLAMS X 

04-023-0004 Nogales Post Office SLAMS / SPM X X X XC

04-025-2002 Prescott Valley SLAMS / SPM X X 

04-025-8033 Prescott College AQD SLAMS X 

04-027-8011 Yuma Supersite SLAMS / SPM X X 

80-026-0005 Sonora Nogales Fire Station SPM / NR N N 

80-026-1000 Agua Prieta Fire Station SPM / NR N N 

80-026-8012 San Luis Rio Colorado SPM / NR N N 

 C – Collocated monitors (Pocs 1 & 2) 

 N – ADEQ does not wish to certify these data due to data quality issues 
Table 2. 2011 Data to be certified in AQS from ADEQ PAMS Parameters 

PAMS Parameters 

Site Name AQS ID PAMS Site 

Type 

VOCs 

Carbonyls 

O3 44201 

NOY 42600 

Wind Speed 61101 

Wind Direction 61102 

Temperature 62101 

Relative Humidity 62201 

Solar Radiation 63301 

Ultraviolet Radiation 63302 

Radar Acoustic Sounding System 

(RASS, profiler) 

Phoenix – JLG 

Supersite 

04-013-9997 SLAMS 

(PAMS - 

Type 2) 

XLR XLR X X X X X 

Queen Valley 04-021-8001 SLAMS 

(PAMS – 

Type 3) 

XLR X N NR NR NR NR 

Phoenix - 

Vehicle 

Emissions 

Laboratory 

04-013-9998 Meteorology NR NR NR NR X X NR

 X – Submitted to AQS 

 NR – Collected but not reported to AQS 

 N – ADEQ does not wish to certify these data due to data quality issues 

 LR – Laboratory reported data to AQS after review by ADEQ 

Table 3. 2011 Data to be certified in AQS from ADEQ NATTS, CSN, and UATMP 

Parameters 

Parameters 

Site Name AQS - ID Classification

PM2.5 Chemical Speciation 

Network (RTI Lab) 

PM10 Metals Speciation (ERG Lab) 

Chrome VI (ERG Lab) 

VOCs -- Urban Air Toxics (ERG 

Lab) 

SVOCs -- Urban Air Toxics (ERG 

Lab) 

Carbonyls -- Urban Air Toxics 

(ERG Lab) 

Phoenix – JLG 

Supersite 

04-013-9997 SLAMS, 

CSN, NATTS XLR XLR XLR XLR XLR XLR 

South Phoenix 04-013-4003 SLAMS XLR 

X – Submitted to AQS 

LR – Laboratory reported data to AQS after review by ADEQ. 
Table 4. Data to be re-certified in AQS from ADEQ Monitors 

PAMS & Toxics 

Monitors 

Compliance 

Parameters 

Site Name AQS ID Classification 

Carbonyls 

PM10 (81102 & 85101) 

JLG 

Supersite 

04-013-9997 

NATTS, 

SLAMS 

(PAMS – 

Type 2) 

XLR 

(recertify data 

2001-2010) 

Queen 

Valley 04-021-8001 PAMS 

XLR 

(recertify data 

2001-2003) 

South 

Phoenix 04-013-4003 UATMP 

XLR 

(recertify data 

2003-2006) 

Paul Spur 

Chemical 

Lime Plant 

04-003-0011 SLAMS X 

(recertify 2011 data) 

X – Submitted to AQS 

LR – Laboratory reported data to AQS after review by ADEQ 

 
APPENDIX B 

 
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

QUICKLOOK CRITERIA PARAMETERS

Report Request ID: 1021470 Report Code: AMP450 Sep. 21, 2012

Selection Criteria Page 1

User ID: BNE

State County Site Parameter POC City AQCR UAR CBSA CSA

EPA

Region Method Duration Begin Date End Date

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

QUICK LOOK

PQAO SELECTIONS

Arizona Department Of Environmental 

Quality

Freeport McMoRan Miami, Inc.

SELECTED OPTIONS

EVENTS PROCESSING

MERGE PDF FILES

WORKFILE DELIMITER

Option Type Option Value

EXCLUDE REGIONALLY CONCURRED EVENTS

YES

,

SORT ORDER

1

2

3

4

5

6

7

Order Column

PARAMETER_CODE

STATE_CODE

COUNTY_CODE

SITE_ID

POC

DATES

EDT_ID

GLOBAL DATES

2011

Start Date End Date

2011

Tribal

Code

APPLICABLE STANDARDS

Standard Description

CO 1-hour 1971

CO 8-hour 1971

Lead Quarterly 1978

NO2 1-hour

NO2 Annual 1971

Ozone 1-hour Daily 2005

Ozone 8-Hour 2008

PM10 24-hour 2006

PM25 24-hour 2006

PM25 Annual 2006

SO2 1-hour 2010

SO2 24-hour 1971

SO2 3-hour 1971

SO2 Annual 1971

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 1 of 11

EXCEPTIONAL DATA TYPES

EDT DESCRIPTION

0

1

2

5

NO EVENTS

EVENTS EXCLUDED

EVENTS INCLUDED

EVENTS WITH CONCURRENCE EXCLUDED

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 2 of 11

Carbon monoxide (42101) Arizona Parts per million (007)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH

#

OBS

OBS

>8HR

STD

1ST

MAX

1-HR

OBS

>1HR

STD CERT EDT

04-013-9997 1 0053 Phoenix Maricopa 4530 N 17TH 

AVENUE

2011 588 4263 2.703 2.573 0 2.3 0

1ST

MAX

8-HR

2.1 0

2ND

MAX

1-HR

2ND

MAX

8-HR

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 3 of 11

Sulfur dioxide (42401) Arizona Parts per billion (008)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH OBS CERT EDT

04-007-0009

04-007-1001

04-013-9997

1

3

1

0053

0053

0053

Miami

Hayden

Phoenix

Gila

Gila

Maricopa

4030 LINDEN

STREET

JAIL-CANYON

DR, HAYDEN

4530 N 17TH

AVENUE

2011

2011

2011

060

060

592

8580

8477

5163

4.43 

6.52 

.90*

0

0

0

ARITH

MEAN

AN-STD

Days

>24HR

STD

0

0

0

1ST

MAX

1-HR

2ND

MAX

1-HR

1ST

MAX

24-HR

2ND

MAX

24-HR

180.0

229.0

5.5

121.0

218.0

5.3

41.1

29.5

2.8

30.5

28.6

2.6

4

4

2

96.0

189.0

5.0

COMP

QTRS

99TH

PCTL

1-HR

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 4 of 11

Nitrogen dioxide (NO2) (42602) Arizona Parts per billion (008)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH OBS

COMP

QTRS CERT EDT

04-013-9997 1 0053 Phoenix Maricopa 4530 N 17TH 

AVENUE

2011 074 4 54.0 8637 16.84 0

ARITH

MEAN

98TH

PCTL

PCT

COMP

99

1ST

MAX

1-HR

115.0 59.0

2ND

MAX

1-HR

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 5 of 11

Ozone (44201) Arizona Parts per million (007)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH

VALID

DAYS

MEAS

1ST

MAX

1-HR CERT EDT

04-005-1008

04-007-0010

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

1

1

1

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

Flagstaff

Tonto National 

Monument

Wenden

Phoenix

Queen Valley

Prescott

Yuma

Coconino

Gila

La Paz

Maricopa

Pinal

Yavapai

Yuma

755 W BONITO

SOUTH OF SR88

ALAMO LAKE 

STATE PARK

4530 N 17TH 

AVENUE

10 S QUEEN ANN 

QUEEN VALLEY

330 Grove 

Avenue

2323 S ARIZONA 

AVE

2011

2011

2011

2011

2011

2011

2011

087

087

087

000

087

087

087

212

207

196

361

182

183

210

.082

.092

.086

.103

.096

.081

.090

.074

.092

.080

.101

.092

.077

.088

0

0

0

0

0

0

0

2ND

MAX

1-HR

1-HOUR 

NUM

DAYS

REQ

214

214

214

365

214

214

214

.074

.087

.080

.094

.087

.075

.087

3RD

MAX

1-HR

.073

.084

.079

.094

.086

.075

.086

4TH

MAX

1-HR

DAY

MAX>

STD

0

0

0

0

0

0

0

EST

DAYS>

STD

 0.0

 0.0

 0.0

 0.0

 0.0

 0.0

 0.0

MISS

DAYS<

STD

2

1

2

1

0

1

2

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 6 of 11

Ozone (44201) Arizona Parts per million (007)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH

VALID

DAYS

MEAS

4TH

MAX

8-HR CERT EDT

04-005-1008

04-007-0010

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

1

1

1

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

Flagstaff

Tonto National 

Monument

Wenden

Phoenix

Queen Valley

Prescott

Yuma

Coconino

Gila

La Paz

Maricopa

Pinal

Yavapai

Yuma

755 W BONITO

SOUTH OF SR88

ALAMO LAKE 

STATE PARK

4530 N 17TH 

AVENUE

10 S QUEEN ANN 

QUEEN VALLEY

330 Grove 

Avenue

2323 S ARIZONA 

AVE

2011

2011

2011

2011

2011

2011

2011

087

087

087

000

087

087

087

.079

.083

.081

.084

.083

.078

.082

.072

.077

.076

.084

.080

.073

.080

0

0

0

0

0

0

0

8-HOUR 

NUM

DAYS

REQ

214

214

214

365

214

214

214

.070

.076

.074

.081

.079

.072

.076

.068

.076

.072

.078

.078

.070

.076

DAY

MAX>

STD

1

4

2

6

5

1

5

211

207

193

361

182

182

208

%OBS

99

97

90

99

85

85

97

1ST

MAX

8-HR

2ND

MAX

8-HR

3RD

MAX

8-HR

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 7 of 11

PM10 Total 0-10um STP (81102) Arizona Micrograms/cubic meter (25 C) (001)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH #OBS

4TH

MAX CERT EDT

04-003-0011

04-003-0011

04-003-1005

04-005-1008

04-007-0008

04-007-0008

04-007-0009

04-007-1001

04-007-8000

04-007-8000

04-013-8006

04-013-9997

04-013-9997

04-015-1003

04-019-0001

04-019-0020

1

2

1

1

1

2

1

3

1

2

1

3

4

1

3

3

0053

0053

0053

0053

0053

0053

1357

0053

1357

1357

0053

0053

0053

0053

0053

0053

Paul Spur

Paul Spur

Douglas

Flagstaff

Payson

Payson

Miami

Hayden

Globe

Globe

Phoenix

Phoenix

Phoenix

Bullhead City

Ajo

Rillito

Cochise

Cochise

Cochise

Coconino

Gila

Gila

Gila

Gila

Gila

Gila

Maricopa

Maricopa

Maricopa

Mohave

Pima

Pima

HOUSING AREA,

PAUL SPUR

HOUSING AREA,

PAUL SPUR

1445-1449 

15TH STREET

755 W BONITO

204 W AERO DR

204 W AERO DR

4030 LINDEN 

STREET

JAIL-CANYON 

DR, HAYDEN

SR 188 & US 

60

SR 188 & US 

60

1310 S. 15TH 

AVENUE

4530 N 17TH 

AVENUE

4530 N 17TH 

AVENUE

BULLHEAD CITY

990 HWY 95

AZ HWY DEPT 

YARD-WELL RD,

AJO

8840 W 

ROBINSON 

STREET, 

RILLITO

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

126

126

126

126

126

126

000

079

000

000

126

122

079

126

079

079

85

108

138

61

39

40

65

210

81

90

60

200

241

132

213

242

0

0

0

0

0

0

0

5

0

0

0

5

5

0

5

5

24-HOUR 

VALID

DAYS

61

61

61

61

61

61

61

365

61

61

61

365

365

61

365

365

DAY

MAX

>STD

0

0

0

0

0

0

0

2

0

0

0

3

4

0

4

4

52

55

55

61

59

56

61

8708

58

59

30

8699

8724

61

8605

8390

%OBS

85

90

90

98

97

92

100

100

95

97

49

100

100

100

99

96

1ST

MAX

2ND

MAX

3RD

MAX

69

98

88

37

38

39

50

205

49

69

51

185

208

38

206

226

47

60

83

35

37

38

40

128

47

49

45

173

199

32

167

209

46

47

64

34

37

34

39

126

35

49

43

150

178

30

157

171

EST

DAYS

>STD

0

0

0

0

0

0

0

2.011

0

0

0

3

4

0

4.067

4.110

22.9 

24.2 

34.5*

15.4 

18.0 

17.6 

14.9 

40.5 

18.7 

19.4 

30.7*

33.9 

30.3 

15.2 

29.0 

41.9 

WTD

ARITH

MEAN

52

55

55

60

59

56

61

364

58

59

30

365

364

61

360

350

NUM

REQ

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 8 of 11

PM10 Total 0-10um STP (81102) Arizona Micrograms/cubic meter (25 C) (001)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH #OBS

4TH

MAX CERT EDT

04-023-0004

04-023-0004

04-025-2002

04-027-8011

1

3

1

3

0053

0053

0053

0053

Nogales

Nogales

Prescott 

Valley

Yuma

Santa Cruz

Santa Cruz

Yavapai

Yuma

300 N MORLEY 

AVE

300 N MORLEY 

AVE

7501 E. CIVIC

CIRCLE, 

PRESCOTT 

VALLEY

2323 S 

ARIZONA AVE

2011

2011

2011

2011

126

122

126

079

126

161

90

225

0

0

0

5

24-HOUR 

VALID

DAYS

61

365

61

365

DAY

MAX

>STD

0

2

0

2

62

8382

57

8529

%OBS

100

96

92

98

1ST

MAX

2ND

MAX

3RD

MAX

109

159

25

178

90

151

20

127

86

138

20

117

EST

DAYS

>STD

0

2.011

0

2.190

39.7 

54.2 

11.4 

29.8 

WTD

ARITH

MEAN

61

350

56

356

NUM

REQ

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 9 of 11

PM2.5 - Local Conditions (88101) Arizona Micrograms/cubic meter (LC) (105)

SITE ID

P

O

C PQAO CITY COUNTY ADDRESS YEAR METH

NUM

CRED

DAYS

4TH

MAX CERT EDT

04-003-1005

04-005-1008

04-013-9997

04-013-9997

04-013-9997

04-023-0004

04-023-0004

04-025-2002

04-027-8011

1

1

1

2

3

1

2

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

Douglas

Flagstaff

Phoenix

Phoenix

Phoenix

Nogales

Nogales

Prescott 

Valley

Yuma

Cochise

Coconino

Maricopa

Maricopa

Maricopa

Santa Cruz

Santa Cruz

Yavapai

Yuma

1445-1449 

15TH STREET

755 W BONITO

4530 N 17TH 

AVENUE

4530 N 17TH 

AVENUE

4530 N 17TH 

AVENUE

300 N MORLEY 

AVE

300 N MORLEY 

AVE

7501 E. CIVIC

CIRCLE, 

PRESCOTT 

VALLEY

2323 S 

ARIZONA AVE

2011

2011

2011

2011

2011

2011

2011

2011

2011

143

143

000

145

170

143

143

143

143

14.8

15.1

37.7

21.4

64.3

29.1

27.9

14.3

15.7

0

0

5

0

5

0

0

0

0

24-HOUR 

98TH

PERCENTILE

VALUE

13.0

14.0

23.0

21.4

27.0

27.2

26.2

10.2

15.6

61

60

120

36

362

58

56

56

58

1ST

MAX

2ND

MAX

3RD

MAX

13.0

14.0

25.2

19.2

48.4

27.2

26.2

10.2

15.6

11.5

11.2

23.0

17.2

38.3

25.1

25.8

7.7

13.7

10.4

10.7

21.8

15.7

35.0

22.9

23.2

6.0

12.7

6.49 

5.16 

8.94 

8.00*

10.05 

9.93 

9.33*

3.80 

7.58 

WTD

ARITH

MEAN

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 10 of 11

42101

42401

42401

42602

44201

44201

81102

81102

81102

81102

88101

88101

88101

88101

588

060

592

074

000

087

000

079

122

126

000

143

145

170

INSTRUMENTAL

INSTRUMENTAL

Instrumental

INSTRUMENTAL

MULTIPLE METHODS

INSTRUMENTAL

MULTIPLE METHODS

INSTRUMENTAL-R&P SA246B-INLET

INSTRUMENT MET ONE 4 MODELS

R - P Co Partisol Model 2000

MULTIPLE METHODS

R & P Model 2000 PM-2.5 Air Sampler w/VSCC

R & P Model 2025 PM-2.5 Sequential Air Sampler

Met One BAM-1020 Mass Monitor w/VSCC

Gas Filter Correlation Ecotech EC9830T

PULSED FLUORESCENT

Ultraviolet Fluorescence EC9850T

CHEMILUMINESCENCE

MULTIPLE METHODS

ULTRA VIOLET ABSORPTION

MULTIPLE METHODS

TEOM-GRAVIMETRIC

BETA ATTENUATION

Gravimetric

MULTIPLE METHODS

Gravimetric

Gravimetric

Beta Attenuation

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

ADEQ ATTACHMENT # 1
Sep. 21, 2012

Note: The * indicates that the mean does

not satisfy summary criteria.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

QUICK LOOK REPORT (AMP450)

Page 11 of 11

PQAOS USED IN THIS REPORT

PQAO AGENCY DESCRIPTION

0053

1357

Arizona Department Of Environmental Quality

Freeport McMoRan Miami, Inc.

ADEQ ATTACHMENT # 1
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

QUICKLOOK ALL PARAMETERS

Report Request ID: 1019000 Report Code: AMP450NC Sep. 13, 2012

Selection Criteria Page 1

User ID: BNE

State County Site Parameter POC City AQCR UAR CBSA CSA

EPA

Region Method Duration Begin Date End Date

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

ALL

PQAO SELECTIONS

Arizona Department Of Environmental 

Quality

Eastern Research Group

Research Triangle Institute RTP, NC

SELECTED OPTIONS

EVENTS PROCESSING

MERGE PDF FILES

Option Type Option Value

EXCLUDE REGIONALLY CONCURRED EVENTS

YES

SORT ORDER

1

2

3

4

5

6

7

Order Column

STATE_CODE

COUNTY_CODE

SITE_ID

PARAMETER_CODE

POC

DATES

EDT_ID

GLOBAL DATES

2011

Start Date End Date

2011

Tribal

Code

APPLICABLE STANDARDS

Standard Description

CO 8-hour 1971

Lead 3-Month 2009

Lead 3-Month PM10 Surrogate 2009

Lead Quarterly 1978

NO2 Annual 1971

Ozone 8-Hour 2008

PM10 24-hour 2006

PM25 24-hour 2006

SO2 1-hour 2010

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

QUICKLOOK ALL PARAMETERS

EXCEPTIONAL DATA TYPES

EDT DESCRIPTION

0

1

2

5

NO EVENTS

EVENTS EXCLUDED

EVENTS INCLUDED

EVENTS WITH CONCURRENCE EXCLUDED

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 2 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

2

1

2

1

1

1

1

1

1

1

1

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 53

 56

 54

 56

 46

 46

 55

 55

 61

 5099

 61

 61

 60

 61

 61

 59

85

108

75

93

32.2

663

138

124

14.8

.079

21.5

598

61

48

15.1

39

69

98

60

87

31.4

663

88

78

13.0

.072

20.9

597

37

29

14.0

38

47

60

40

51

29.3

662

83

74

11.5

.070

20.7

596

35

29

11.2

37

46

47

39

40

28.5

662

64

59

10.4

.068

20.3

596

34

28

10.7

37

23.0 

23.7 

20.4 

20.6 

20.84*

657.9*

34.2*

30.2*

6.48 

.0530 

7.97 

591.7 

15.6 

12.5 

5.17 

18.0 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

81102

81102

85101

85101

68105

68108

81102

85101

88101

44201

68105

68108

81102

85101

88101

81102

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

04-003-0011

04-003-1005

04-005-1008

04-007-0008

Paul Spur

Douglas

Flagstaff

Payson

City:

City:

City:

City:

Cochise

Cochise

Coconino

Gila

Unit

County:

County:

County:

County:

HOUSING AREA, PAUL SPUR

1445-1449 15TH STREET

755 W BONITO

204 W AERO DR

Address:

Address:

Address:

Address:

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 - LC

PM10 - LC

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

Ozone

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

PM10 Total 0-10um STP

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Parts per million

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(25 C)

Meth

126

126

126

126

143

143

126

126

143

087

143

143

126

126

143

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 3 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

2

1

2

1

1

1

3

3

3

3

1

2

1

2

1

2

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 56

 59

 56

 8580

 8580

 5076

 8477

 8517

 8708

 364

 59

 50

 62

 59

 62

 59

40

35

35

180.0

295.1

.083

229.0

1068.4

1253

210

.641

.691

35.0

34.7

715

715

39

34

35

121.0

240.6

.077

218.0

1052.4

963

205

.495

.523

33.9

34.2

714

714

38

33

34

97.0

222.4

.076

195.0

1008.1

860

128

.473

.449

33.8

34.0

713

713

34

33

30

96.0

206.1

.076

189.0

694.8

815

126

.415

.415

33.7

33.7

712

712

17.7 

15.6 

15.4 

20.08 

8.37 

.0568 

47.47 

19.38 

40.9 

40.5 

.1353 

.1445*

21.56 

21.95 

707.4 

707.1 

24 HOUR

24 HOUR

24 HOUR

1 HOUR

1 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

1 HOUR

1 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

5

5

0

0

0

0

0

0

81102

85101

85101

42401

42406

44201

42401

42406

81102

81102

14129

14129

68105

68105

68108

68108

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

04-007-0008

04-007-0009

04-007-0010

04-007-1001

04-007-1002

04-007-8000

Payson

Miami

Tonto National Monument

Hayden

Not in a city

Globe

City:

City:

City:

City:

City:

City:

Gila

Gila

Gila

Gila

Gila

Gila

Unit

County:

County:

County:

County:

County:

County:

204 W AERO DR

4030 LINDEN STREET

SOUTH OF SR88

JAIL-CANYON DR, HAYDEN

SR 77

SR 188 & US 60

Address:

Address:

Address:

Address:

Address:

Address:

PM10 Total 0-10um STP

PM10 - LC

PM10 - LC

Sulfur dioxide

SO2 max 5-min avg

Ozone

Sulfur dioxide

SO2 max 5-min avg

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Lead (TSP) LC

Lead (TSP) LC

Ambient Temperature

Ambient Temperature

Sample Baro Pressure

Sample Baro Pressure

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Parts per billion

Parts per billion

Parts per million

Parts per billion

Parts per billion

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Degrees Centigrade

Degrees Centigrade

Millimeters (mercury)

Millimeters (mercury)

Meth

126

126

126

060

060

087

060

060

079

079

191

191

780

780

780

780

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 4 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

1

6

6

6

6

6

6

6

6

6

6

6

6

0053

0053

0053

0053

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 60

 62

 62

 4749

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

.165

35.0

682

.081

.06

10.77

13.92

.07

2.33

2.08

.16

.05

.02

.05

.67

3.18

.128

33.9

682

.076

.04

9.45

11.68

.04

1.57

1.89

.02

.05

.02

.05

.13

2.90

.117

33.8

680

.074

.04

6.90

7.30

.04

1.14

1.86

.02

.05

.02

.05

.06

2.55

.105

33.5

679

.072

.04

5.76

5.96

.04

1.03

1.50

.02

.05

.02

.05

.06

2.52

.0334 

19.34 

674.4 

.0538 

.022 

3.206 

3.425 

.034 

.522 

.740 

.025 

.048 

.024 

.050 

.077 

1.588 

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

14129

68105

68108

44201

42153

43205

43206

43208

43218

43233

43372

43373

43396

43438

43441

43505

Parameter

Site ID:

Site ID:

Site ID:

04-007-8000

04-012-8000

04-013-4003

Globe

Wenden

Phoenix

City:

City:

City:

Gila

La Paz

Maricopa

Unit

County:

County:

County:

SR 188 & US 60

ALAMO LAKE STATE PARK

33 W TAMARISK AVE, PHOENIX

Address:

Address:

Address:

Lead (TSP) LC

Ambient Temperature

Sample Baro Pressure

Ozone

Carbon disulfide

Propylene

Acetylene

Freon 114

1,3-Butadiene

n-Octane

Methyl tert-butyl ether

Tert-amyl methyl ether

tert-Butyl ethyl ether

Ethyl acrylate

Methyl methacrylate

Acrolein - Unverified

Micrograms/cubic meter

(LC)

Degrees Centigrade

Millimeters (mercury)

Parts per million

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

191

780

780

087

101

101

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 5 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

5.52

.63

.61

.08

1.21

.33

.08

.17

.01

.49

.03

.01

.02

.06

.63

.02

.02

4.76

.59

.61

.02

.92

.29

.08

.16

.01

.41

.02

.01

.02

.05

.34

.02

.02

3.67

.58

.57

.02

.83

.25

.07

.14

.01

.39

.01

.01

.02

.05

.30

.02

.02

3.32

.49

.53

.02

.78

.24

.07

.14

.01

.34

.01

.01

.02

.04

.28

.02

.01

2.541 

.339 

.353 

.020 

.688 

.145 

.038 

.100 

.013 

.303 

.010 

.008 

.022 

.018 

.120 

.024 

.009 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43552

43560

43702

43704

43801

43802

43803

43804

43806

43811

43812

43813

43814

43815

43817

43818

43819

Parameter

Site ID: 04-013-4003 City: Phoenix Maricopa

Unit

County: Address: 33 W TAMARISK AVE, PHOENIX

Methyl ethyl ketone

Methyl isobutyl ketone

Acetonitrile

Acrylonitrile

Chloromethane

Dichloromethane

Chloroform

Carbon tetrachloride

Bromoform

Trichlorofluoromethane

Chloroethane

1,1-Dichloroethane

Methyl chloroform

Ethylene dichloride

Tetrachloroethylene

1,1,2,2-Tetrachloroethane

Bromomethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 6 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

.03

.31

1.09

.11

0

.01

.03

.04

.03

.01

.02

.05

.01

.01

.02

.07

.01

.03

.24

.74

.08

0

.01

.03

.04

.03

.01

.02

.00

.01

.01

.02

.07

.01

.03

.22

.71

.08

0

.01

.03

.04

.03

.01

.02

.00

.01

.01

.02

.07

.01

.03

.21

.67

.05

0

.01

.03

.04

.03

.01

.02

.00

.01

.01

.02

.07

.01

.025 

.184 

.600 

.032 

.0 

.013 

.035 

.038 

.033 

.011 

.016 

.005 

.008 

.009 

.018 

.074 

.008 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43820

43821

43823

43824

43826

43828

43829

43830

43831

43832

43835

43836

43838

43839

43843

43844

43860

Parameter

Site ID: 04-013-4003 City: Phoenix Maricopa

Unit

County: Address: 33 W TAMARISK AVE, PHOENIX

1,1,2-Trichloroethane

1,1,2-Trichloro-1,2,2-

trifluoroethane

Dichlorodifluoromethane

Trichloroethylene

1,1-Dichloroethylene

Bromodichloromethane

1,2-Dichloropropane

trans-1,3-Dichloropropene

cis-1,3-Dichloropropene

Dibromochloromethane

Chloroprene

Bromochloromethane

trans-1,2-Dichloroethylene

cis-1,2-Dichloroethene

Ethylene dibromide

Hexachlorobutadiene

Vinyl chloride

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 7 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

6

6

6

6

6

6

6

6

6

6

6

6

6

1

1

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 30

 30

15.84

10.14

44.73

5.62

6.09

1.73

5.93

1.37

.06

.11

.10

.74

.14

.11

60

60

15.20

8.10

28.98

5.10

5.85

1.54

5.06

1.01

.06

.11

.10

.70

.14

.11

51

51

13.52

6.30

28.49

4.67

5.35

1.30

4.28

.94

.06

.11

.10

.66

.14

.11

45

45

11.84

6.18

27.65

4.32

4.71

1.22

4.10

.91

.06

.11

.10

.46

.14

.11

43

42

5.341 

3.096 

11.886 

1.954 

2.125 

.576 

1.972 

.491 

.063 

.111 

.102 

.249 

.137 

.108 

30.7*

29.9*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45109

45201

45202

45203

45204

45207

45208

45220

45801

45805

45806

45807

45809

45810

81102

85101

Parameter

Site ID:

Site ID:

04-013-4003

04-013-8006

Phoenix

Phoenix

City:

City:

Maricopa

Maricopa

Unit

County:

County:

33 W TAMARISK AVE, PHOENIX

1310 S. 15TH AVENUE

Address:

Address:

m/p Xylene

Benzene

Toluene

Ethylbenzene

o-Xylene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene

Styrene

Chlorobenzene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Benzyl chloride

1,2,4-Trichlorobenzene

PM10 Total 0-10um STP

PM10 - LC

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 8 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

3

3

3

3

3

3

3

3

3

3

3

3

3

3

3

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 62

 7

 57

 57

 57

 57

 57

 57

 57

 57

 57

 57

 57

 57

 57

 57

 57

.00

.00

293.000

3.9000

6.1100

5.8200

12.800

1.0400

3.3200

2.9400

.398

1.5900

1.3200

.6770

.344

.1210

.395

.00

.00

220.000

3.8400

6.1000

5.6500

11.600

1.0100

3.1800

2.7800

.246

1.5400

1.3000

.5550

.328

.1130

.304

.00

.00

211.000

3.7300

5.6900

5.4300

11.000

.8070

2.4500

2.6300

.241

1.5100

1.2100

.5140

.312

.1120

.295

.00

.00

209.000

3.6400

4.4000

4.8800

11.000

.7800

2.3400

2.5900

.222

1.5100

1.1500

.4040

.304

.0983

.280

.000 

.000*

89.3632 

1.87900 

1.18375 

2.90405 

5.8578 

.36516 

.78016 

1.35028 

.0454 

.94582 

.61717 

.14323 

.0726 

.01857 

.0667 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

12115

12115

17141

17147

17148

17149

17150

17151

17158

17159

17160

17201

17204

17208

17211

17212

17215

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Chromium VI (TSP) STP

Chromium VI (TSP) STP

Naphthalene (TSP) STP

Acenaphthene (TSP) STP

Acenaphthylene (TSP) STP

Fluorene (TSP) STP

Phenanthrene (TSP) STP

Anthracene (TSP) STP

Retene (TSP) STP

9-fluorenone (TSP) STP

Cyclopenta[cd]pyrene (TSP) STP

Fluoranthene (TSP) STP

Pyrene (TSP) STP

Chrysene (TSP) STP

Coronene (TSP) STP

Perylene (TSP) STP

Benzo[a]anthracene (TSP) STP

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Meth

920

920

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 9 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

3

3

3

3

3

3

3

1

6

7

1

1

1

1

1

1

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0053

0329

0329

0053

0053

0053

0053

0053

0053

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 57

 57

 57

 57

 57

 57

 57

 4261

 61

 6

 5163

 5935

 6155

 8636

 8637

 8636

 15

 1

 10

 1

1.060

.312

.545

.110

.658

.592

.6110

2.3

1.03

.14

5.5

9.0

216.0

205.0

115.0

245.0

238.00

140.00

2.41

1.54

.765

.238

.379

.089

.652

.543

.5440

2.2

.11

.07

5.3

6.8

214.1

202.0

59.0

239.0

190.00

2.10

.748

.194

.369

.081

.596

.436

.5100

2.2

.10

.04

5.0

5.9

213.4

198.0

57.0

238.0

170.00

2.09

.702

.189

.353

.074

.533

.432

.4300

2.1

.09

.04

4.9

5.6

212.1

198.0

56.0

237.0

143.00

1.91

.1996 

.0486 

.1045 

.0145 

.1503 

.1024 

.12519 

.51 

.068 

.053*

1.87*

1.00*

32.69*

14.21 

16.84 

31.14 

130.460*

140.000*

1.671*

1.540*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG END 

HOUR

24 HOUR

24 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

17220

17223

17224

17231

17237

17242

17243

42101

42153

42153

42401

42406

42600

42601

42602

42603

43102

43102

43127

43127

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Benzo[b]fluoranthene (TSP) STP

Benzo[k]fluoranthene (TSP) STP

Benzo[e]pyrene (TSP) STP

Dibenzo[a,h]anthracene (TSP) STP

Benzo[g,h,i]perylene (TSP) STP

Benzo[a]pyrene (TSP) STP

Indeno[1,2,3-cd]pyrene (TSP) STP

Carbon monoxide

Carbon disulfide

Carbon disulfide

Sulfur dioxide

SO2 max 5-min avg

Reactive oxides of nitrogen (NOy)

Nitric oxide (NO)

Nitrogen dioxide (NO2)

Oxides of nitrogen (NOx)

Total NMOC (non-methane organic 

compound)

Total NMOC (non-methane organic 

compound)

Isobutene & 1-butene

Isobutene & 1-butene

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Parts per million

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion

Parts per billion

Parts per billion

Parts per billion

Parts per billion

Parts per billion

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

118

118

118

118

118

118

118

588

101

101

592

592

000

074

074

074

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 10 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

6

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 61

.76

.46

.22

.22

.22

.22

.05

.05

.13

.13

10.40

2.14

4.86

2.19

8.82

4.14

8.52

.62

.22

.22

.05

.13

5.93

3.69

8.81

7.95

.59

.22

.22

.05

.13

5.07

3.31

8.48

6.42

.53

.22

.22

.05

.13

4.56

3.13

6.45

6.39

.395*

.460*

.215*

.215*

.215*

.215*

.050*

.050*

.130*

.130*

3.759*

2.140*

2.685*

2.190*

4.629*

4.140*

2.647 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43141

43141

43142

43142

43143

43143

43144

43144

43145

43145

43202

43202

43203

43203

43204

43204

43205

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

n-Dodecane

n-Dodecane

Tridecene

Tridecene

n-Tridecane

n-Tridecane

Propyne

Propyne

1-Octene

1-Octene

Ethane

Ethane

Ethylene

Ethylene

Propane

Propane

Propylene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 11 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

8

9

6

7

8

9

6

7

8

9

8

9

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 6

 15

 1

 61

 6

 15

 1

 61

 6

 15

 1

 15

 1

 15

 1

 15

 1

4.11

2.24

1.47

9.30

3.64

2.13

1.16

.05

.05

5.10

3.17

3.12

1.62

.30

.07

.25

.09

3.84

1.78

7.78

3.60

1.79

.05

.04

4.22

2.39

.30

.24

3.00

1.71

7.66

2.64

1.68

.05

.04

3.78

2.32

.27

.19

1.97

1.70

7.56

2.40

1.54

.05

.04

3.54

2.06

.26

.09

2.736*

1.185*

1.470*

2.688 

2.534*

1.101*

1.160*

.036 

.038*

2.390*

3.170*

1.427*

1.620*

.173*

.070*

.113*

.085*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43205

43205

43205

43206

43206

43206

43206

43208

43208

43212

43212

43214

43214

43216

43216

43217

43217

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Propylene

Propylene

Propylene

Acetylene

Acetylene

Acetylene

Acetylene

Freon 114

Freon 114

n-Butane

n-Butane

Isobutane

Isobutane

trans-2-Butene

trans-2-Butene

cis-2-Butene

cis-2-Butene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

126

126

101

101

126

126

101

101

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 12 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 6

 15

 1

 15

 1

 14

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

1.96

.70

.33

.10

5.10

2.86

17.80

13.30

.59

.44

.58

.38

.73

.42

.27

.21

.84

1.31

.65

.31

4.23

17.80

.43

.44

.48

.23

.63

1.22

.46

.25

3.90

14.80

.41

.42

.45

.20

.60

1.14

.28

.21

3.87

13.70

.36

.39

.42

.19

.57

.417 

.413*

.143*

.095*

2.695*

2.860*

11.873*

13.300*

.310*

.440*

.282*

.380*

.311*

.420*

.131*

.210*

.360*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43218

43218

43218

43218

43220

43220

43221

43221

43224

43224

43225

43225

43226

43226

43227

43227

43228

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1,3-Butadiene

1,3-Butadiene

1,3-Butadiene

1,3-Butadiene

n-Pentane

n-Pentane

Isopentane

Isopentane

1-Pentene

1-Pentene

2-Methyl-1-butene

2-Methyl-1-butene

trans-2-Pentene

trans-2-Pentene

cis-2-Pentene

cis-2-Pentene

2-Methyl-2-butene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 13 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

6

7

8

9

8

9

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 1

 15

 1

 15

 1

 15

 1

 61

 6

 15

 1

 15

 1

 15

 1

 15

 1

.55

2.19

1.09

2.21

1.12

1.06

.56

1.38

1.00

.61

.41

.17

.17

.43

.25

.17

.17

1.78

1.71

.96

1.35

.80

.56

.17

.36

.17

1.63

1.54

.94

1.26

.58

.52

.17

.32

.17

1.47

1.42

.90

1.22

.43

.50

.17

.32

.17

.550*

1.051*

1.090*

1.054*

1.120*

.667*

.560*

.603 

.607*

.385*

.410*

.165*

.165*

.218*

.250*

.165*

.165*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43228

43230

43230

43231

43231

43232

43232

43233

43233

43233

43233

43234

43234

43235

43235

43236

43236

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

2-Methyl-2-butene

3-Methylpentane

3-Methylpentane

n-Hexane

n-Hexane

n-Heptane

n-Heptane

n-Octane

n-Octane

n-Octane

n-Octane

4-Methyl-1-pentene

4-Methyl-1-pentene

n-Nonane

n-Nonane

2-Ethyl-1-butene

2-Ethyl-1-butene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

101

101

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 14 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

.68

.47

.62

.35

2.73

1.31

.50

.33

.36

.17

.17

.17

1.17

.55

1.35

.70

1.62

.59

.53

1.70

.48

.17

.17

.93

1.16

1.57

.53

.48

1.63

.44

.17

.17

.79

.97

1.46

.50

.42

1.39

.41

.17

.17

.69

.96

1.41

.355*

.470*

.341*

.350*

1.263*

1.310*

.279*

.330*

.178*

.165*

.165*

.165*

.518*

.550*

.670*

.700*

1.065*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43238

43238

43242

43242

43243

43243

43244

43244

43245

43245

43246

43246

43247

43247

43248

43248

43249

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

n-Decane

n-Decane

Cyclopentane

Cyclopentane

Isoprene

Isoprene

2,2-Dimethylbutane

2,2-Dimethylbutane

1-Hexene

1-Hexene

2-Methyl-1-pentene

2-Methyl-1-pentene

2,4-Dimethylpentane

2,4-Dimethylpentane

Cyclohexane

Cyclohexane

3-Methylhexane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 15 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

.77

3.77

1.83

1.60

.71

.46

.28

1.39

.63

.10

.10

.90

.53

1.92

.95

1.75

.73

2.88

1.03

.40

.90

.10

.86

1.57

1.53

2.57

.97

.34

.63

.10

.85

1.32

1.47

2.38

.90

.33

.60

.10

.72

1.22

1.19

.770*

1.634*

1.830*

.646*

.710*

.223*

.280*

.338*

.630*

.100*

.100*

.545*

.530*

.913*

.950*

1.116*

.730*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43249

43250

43250

43252

43252

43253

43253

43256

43256

43257

43257

43261

43261

43262

43262

43263

43263

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

3-Methylhexane

2,2,4-Trimethylpentane

2,2,4-Trimethylpentane

2,3,4-Trimethylpentane

2,3,4-Trimethylpentane

3-Methylheptane

3-Methylheptane

alpha.-Pinene

alpha.-Pinene

beta.-Pinene

beta.-Pinene

Methylcyclohexane

Methylcyclohexane

Methylcyclopentane

Methylcyclopentane

2-Methylhexane

2-Methylhexane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 16 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

 1

 15

.13

.13

.10

.10

.70

.10

1.41

.74

4.18

2.00

.17

.17

.17

.17

1.85

.83

.66

.13

.10

.62

1.18

3.21

.17

.17

1.58

.65

.13

.10

.31

1.00

2.80

.17

.17

1.34

.57

.13

.10

.26

.94

2.80

.17

.17

1.31

.50

.125*

.125*

.095*

.095*

.202*

.095*

.640*

.740*

1.986*

2.000*

.165*

.165*

.165*

.165*

.949*

.830*

.315*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43279

43279

43282

43282

43283

43283

43284

43284

43285

43285

43289

43289

43290

43290

43291

43291

43292

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1-Nonene

1-Nonene

3-Methyl-1-butene

3-Methyl-1-butene

Cyclopentene

Cyclopentene

2,3-Dimethylbutane

2,3-Dimethylbutane

2-Methylpentane

2-Methylpentane

trans-2-Hexene

trans-2-Hexene

cis-2-Hexene

cis-2-Hexene

2,3-Dimethylpentane

2,3-Dimethylpentane

2-2-3-Trimethylpentane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 17 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

30

31

32

8

9

6

7

6

7

6

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 1

 15

 1

 15

 1

 15

 1

 46

 8

 48

 15

 1

 61

 6

 61

 6

 61

.38

.10

.10

.10

.10

.22

.22

1.4

1.1

2.3

.86

.22

.02

.02

.05

.05

.02

.10

.10

.22

1.2

1.1

2.2

.22

.02

.02

.05

.05

.02

.10

.10

.22

1.2

1.0

1.9

.22

.02

.02

.05

.05

.02

.10

.10

.22

1.2

.8

1.8

.22

.02

.02

.05

.05

.02

.380*

.100*

.100*

.100*

.100*

.220*

.220*

.64*

.78*

.87*

.258*

.215*

.020 

.020*

.048 

.048*

.024 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43292

43298

43298

43299

43299

43328

43328

43329

43329

43329

43330

43330

43372

43372

43373

43373

43396

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

2-2-3-Trimethylpentane

1-Decene

1-Decene

1-Undecene

1-Undecene

1-Heptene

1-Heptene

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Dodecene

Dodecene

Methyl tert-butyl ether

Methyl tert-butyl ether

Tert-amyl methyl ether

Tert-amyl methyl ether

tert-Butyl ethyl ether

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

202

202

202

126

126

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 18 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

6

7

6

7

30

31

32

30

31

32

30

31

32

6

7

30

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 6

 61

 6

 61

 6

 46

 8

 48

 46

 8

 48

 46

 8

 48

 60

 6

 46

.02

.39

.05

.34

.06

5.0

4.5

8.3

5.8

5.3

10.6

1.2

1.0

2.4

3.93

4.38

.0

.02

.05

.05

.30

.06

4.9

3.8

7.5

5.8

4.8

9.5

1.0

.9

2.1

3.45

2.53

.0

.02

.05

.05

.29

.06

4.9

3.7

7.0

5.6

4.5

8.9

1.0

.9

1.7

3.33

2.23

.0

.02

.05

.05

.22

.06

4.9

3.7

6.5

5.5

4.5

7.0

1.0

.8

1.3

3.33

1.49

.0

.024*

.056 

.050*

.078 

.055*

3.35*

3.25*

3.83*

3.12*

3.65*

3.49*

.62*

.72*

.75*

1.818 

2.170*

.01*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43396

43438

43438

43441

43441

43502

43502

43502

43503

43503

43503

43504

43504

43504

43505

43505

43513

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

tert-Butyl ethyl ether

Ethyl acrylate

Ethyl acrylate

Methyl methacrylate

Methyl methacrylate

Formaldehyde

Formaldehyde

Formaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Acrolein - Unverified

Acrolein - Unverified

Isovaleraldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

202

202

202

202

202

202

202

202

202

101

101

202

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 19 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

31

32

30

31

32

30

31

32

30

31

32

30

31

32

6

7

6

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 8

 48

 46

 8

 48

 46

 8

 48

 46

 8

 48

 46

 8

 48

 61

 6

 61

.0

.0

.7

.6

1.6

.5

.4

.8

1.0

.7

2.3

19.4

16.2

25.3

6.44

4.32

.60

.0

.0

.6

.6

1.4

.4

.4

.8

.6

.6

1.6

19.2

14.9

23.6

6.00

3.43

.60

.0

.0

.6

.6

1.4

.4

.4

.6

.6

.4

1.4

16.2

14.3

22.7

4.80

2.94

.58

.0

.0

.6

.5

1.1

.4

.4

.6

.6

.3

1.3

15.8

10.0

22.5

4.40

2.43

.53

.01*

.02*

.36*

.47*

.55*

.24*

.32*

.29*

.35*

.38*

.67*

8.33*

10.23*

11.22*

2.434 

2.781*

.328 

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43513

43513

43517

43517

43517

43518

43518

43518

43528

43528

43528

43551

43551

43551

43552

43552

43560

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Isovaleraldehyde

Isovaleraldehyde

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Acetone

Acetone

Acetone

Methyl ethyl ketone

Methyl ethyl ketone

Methyl isobutyl ketone

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

202

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 20 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

.47

.99

1.41

.28

.28

.88

.75

16.90

.86

.29

.19

.14

.11

.01

.01

.40

.34

.44

.70

1.06

.21

.08

.87

.74

1.28

.67

.20

.14

.14

.10

.01

.01

.35

.32

.41

.66

.93

.19

.02

.82

.66

.72

.33

.18

.09

.14

.10

.01

.01

.35

.29

.31

.65

.74

.17

.02

.81

.65

.70

.22

.18

.07

.14

.10

.01

.01

.34

.29

.351*

.444 

.825*

.037 

.072*

.669 

.673*

.594 

.410*

.075 

.096*

.101 

.096*

.013 

.013*

.297 

.292*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43560

43702

43702

43704

43704

43801

43801

43802

43802

43803

43803

43804

43804

43806

43806

43811

43811

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Methyl isobutyl ketone

Acetonitrile

Acetonitrile

Acrylonitrile

Acrylonitrile

Chloromethane

Chloromethane

Dichloromethane

Dichloromethane

Chloroform

Chloroform

Carbon tetrachloride

Carbon tetrachloride

Bromoform

Bromoform

Trichlorofluoromethane

Trichlorofluoromethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 21 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

.12

.02

.01

.01

.02

.02

.11

.04

2.54

.35

.02

.02

.02

.02

.03

.03

.24

.06

.01

.01

.01

.02

.02

.06

.01

.51

.14

.02

.02

.02

.02

.03

.03

.23

.04

.01

.01

.01

.02

.02

.06

.01

.46

.09

.02

.02

.02

.01

.03

.03

.23

.04

.01

.01

.01

.02

.02

.05

.01

.41

.08

.02

.02

.02

.01

.03

.03

.23

.014 

.011*

.008 

.008*

.022 

.022*

.018 

.015*

.163 

.137*

.024 

.024*

.010 

.011*

.025 

.025*

.191 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43812

43812

43813

43813

43814

43814

43815

43815

43817

43817

43818

43818

43819

43819

43820

43820

43821

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Chloroethane

Chloroethane

1,1-Dichloroethane

1,1-Dichloroethane

Methyl chloroform

Methyl chloroform

Ethylene dichloride

Ethylene dichloride

Tetrachloroethylene

Tetrachloroethylene

1,1,2,2-Tetrachloroethane

1,1,2,2-Tetrachloroethane

Bromomethane

Bromomethane

1,1,2-Trichloroethane

1,1,2-Trichloroethane

1,1,2-Trichloro-1,2,2-

trifluoroethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 22 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

.23

.69

.63

.05

.03

0

0

.05

.01

.03

.03

.08

.04

.10

.03

.01

.01

.21

.65

.59

.05

.03

0

0

.03

.01

.03

.03

.04

.04

.09

.03

.01

.01

.19

.65

.54

.03

.03

0

0

.03

.01

.03

.03

.04

.04

.03

.03

.01

.01

.19

.65

.54

.03

.03

0

0

.01

.01

.03

.03

.04

.04

.03

.03

.01

.01

.194*

.566 

.560*

.026 

.025*

.0 

.0*

.014 

.013*

.035 

.035*

.038 

.038*

.035 

.033*

.011 

.011*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43821

43823

43823

43824

43824

43826

43826

43828

43828

43829

43829

43830

43830

43831

43831

43832

43832

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1,1,2-Trichloro-1,2,2-

trifluoroethane

Dichlorodifluoromethane

Dichlorodifluoromethane

Trichloroethylene

Trichloroethylene

1,1-Dichloroethylene

1,1-Dichloroethylene

Bromodichloromethane

Bromodichloromethane

1,2-Dichloropropane

1,2-Dichloropropane

trans-1,3-Dichloropropene

trans-1,3-Dichloropropene

cis-1,3-Dichloropropene

cis-1,3-Dichloropropene

Dibromochloromethane

Dibromochloromethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 23 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

6

7

6

7

6

7

6

7

6

7

6

7

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 15

 1

 15

.02

.02

.00

.00

.05

.01

.01

.01

.02

.02

.07

.07

.01

.01

.32

.22

.40

.02

.02

.00

.00

.03

.01

.01

.01

.02

.02

.07

.07

.01

.01

.27

.33

.02

.02

.00

.00

.02

.01

.01

.01

.02

.02

.07

.07

.01

.01

.27

.33

.02

.02

.00

.00

.02

.01

.01

.01

.02

.02

.07

.07

.01

.01

.23

.32

.016 

.016*

.004 

.004*

.009 

.008*

.009 

.009*

.018 

.018*

.074 

.074*

.008 

.008*

.160*

.220*

.222*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43835

43835

43836

43836

43838

43838

43839

43839

43843

43843

43844

43844

43860

43860

43954

43954

43960

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Chloroprene

Chloroprene

Bromochloromethane

Bromochloromethane

trans-1,2-Dichloroethylene

trans-1,2-Dichloroethylene

cis-1,2-Dichloroethene

cis-1,2-Dichloroethene

Ethylene dibromide

Ethylene dibromide

Hexachlorobutadiene

Hexachlorobutadiene

Vinyl chloride

Vinyl chloride

n-Undecane

n-Undecane

2-Methylheptane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 24 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

1

6

7

8

9

6

7

8

6

7

8

9

6

7

8

9

0329

0053

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 1

 8673

 61

 6

 15

 1

 61

 6

 14

 61

 6

 15

 1

 61

 6

 15

 1

.26

.084

10.32

6.99

3.00

1.58

7.74

3.99

9.77

22.96

14.14

7.73

4.10

3.69

2.60

1.14

.59

.084

10.08

5.18

2.72

6.24

3.05

1.76

21.21

10.78

5.44

3.65

2.00

1.00

.081

10.08

3.42

2.48

6.06

2.76

1.40

19.88

8.33

5.33

3.64

1.54

.90

.078

9.92

2.75

2.28

5.30

2.03

1.28

19.04

6.15

5.26

3.63

1.06

.87

.260*

.0476 

4.000 

3.903*

1.593*

1.580*

2.525 

2.528*

1.516*

8.413 

8.366*

3.569*

4.100*

1.507 

1.531*

.616*

.590*

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43960

44201

45109

45109

45109

45109

45201

45201

45201

45202

45202

45202

45202

45203

45203

45203

45203

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

2-Methylheptane

Ozone

m/p Xylene

m/p Xylene

m/p Xylene

m/p Xylene

Benzene

Benzene

Benzene

Toluene

Toluene

Toluene

Toluene

Ethylbenzene

Ethylbenzene

Ethylbenzene

Ethylbenzene

Parts per billion 

Carbon

Parts per million

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

000

101

101

126

126

101

101

126

101

101

126

126

101

101

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 25 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

8

9

6

7

8

9

6

7

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 6

 15

 1

 61

 6

 15

 1

 61

 6

 15

 1

 15

 1

 15

 1

 15

4.09

2.78

1.26

.66

1.08

1.01

.47

.35

3.43

2.94

1.19

.74

.29

.10

.10

.10

.51

4.04

1.97

1.00

1.03

.58

.39

3.41

1.86

.98

.28

.10

.43

3.94

1.26

.97

1.01

.43

.36

3.38

1.30

.96

.24

.10

.38

3.78

1.18

.92

1.01

.41

.35

3.37

1.14

.88

.24

.10

.32

1.565 

1.536*

.658*

.660*

.442 

.515*

.231*

.350*

1.422 

1.535*

.645*

.740*

.148*

.095*

.100*

.100*

.250*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45204

45204

45204

45204

45207

45207

45207

45207

45208

45208

45208

45208

45209

45209

45210

45210

45211

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

o-Xylene

o-Xylene

o-Xylene

o-Xylene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

n-Propylbenzene

n-Propylbenzene

Isopropylbenzene

Isopropylbenzene

o-Ethyltoluene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

126

126

101

101

126

126

101

101

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 26 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

6

7

8

9

8

9

8

9

30

31

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 1

 15

 1

 15

 1

 15

 1

 61

 6

 15

 1

 15

 1

 15

 1

 46

 8

.41

.76

.42

.61

.46

.27

.06

1.14

.51

.13

.13

.39

.25

.44

.29

.9

.8

.65

.59

.27

1.03

.48

.13

.36

.39

.9

.7

.62

.56

.25

.92

.41

.13

.30

.30

.7

.7

.61

.54

.24

.84

.35

.13

.29

.30

.7

.6

.410*

.399*

.420*

.431*

.460*

.193*

.060*

.385 

.367*

.130*

.130*

.205*

.250*

.196*

.290*

.37*

.51*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45211

45212

45212

45218

45218

45219

45219

45220

45220

45220

45220

45225

45225

45228

45228

45501

45501

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

o-Ethyltoluene

m-Ethyltoluene

m-Ethyltoluene

m-Diethylbenzene

m-Diethylbenzene

p-Diethylbenzene

p-Diethylbenzene

Styrene

Styrene

Styrene

Styrene

1,2,3-Trimethylbenzene

1,2,3-Trimethylbenzene

Benzene, 1-ethenyl-4-methyl

Benzene, 1-ethenyl-4-methyl

Benzaldehyde

Benzaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

101

101

126

126

126

126

126

126

202

202

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 27 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

32

30

31

32

30

31

32

6

7

6

7

6

7

6

7

6

7

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 47

 46

 8

 48

 45

 6

 43

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

1.2

.0

.0

.0

2.0

.7

2.7

.06

.06

.11

.11

.10

.10

.56

.34

.14

.14

1.1

.0

.0

.0

.8

.7

2.0

.06

.06

.11

.11

.10

.10

.52

.32

.14

.14

1.0

.0

.0

.0

.7

.5

1.2

.06

.06

.11

.11

.10

.10

.47

.23

.14

.14

.9

.0

.0

.0

.6

.4

1.0

.06

.06

.11

.11

.10

.10

.47

.11

.14

.14

.45*

.01*

.01*

.05*

.37*

.47*

.69*

.063 

.063*

.111 

.111*

.102 

.102*

.203 

.201*

.137 

.137*

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45501

45503

45503

45503

45504

45504

45504

45801

45801

45805

45805

45806

45806

45807

45807

45809

45809

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Benzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

Tolualdehydes

Tolualdehydes

Tolualdehydes

Chlorobenzene

Chlorobenzene

1,2-Dichlorobenzene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

1,4-Dichlorobenzene

Benzyl chloride

Benzyl chloride

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

101

101

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 28 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

1

1

1

1

7

7

1

2

7

7

7

1

2

7

3

3

4

4

1

1

1

1

0329

0329

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 6

 8757

 8757

 8756

 8756

 118

 118

 121

 57

 118

 118

 118

 121

 57

 118

 8699

 365

 364

 8724

 61

 61

 61

 61

.11

.11

14.2

360

116

95

31.1

48.5

38.8

37.7

39.0

739

745

743

744

741

985

227

241

6348

7.88

3.05

.27

.60

.11

.11

13.6

360

115

95

30.8

46.5

37.8

36.4

37.8

739

744

740

741

740

985

200

208

2785

7.11

2.20

.27

.49

.11

.11

13.6

360

115

95

30.6

45.6

37.7

36.0

37.7

737

743

739

739

740

985

185

199

2600

6.45

2.11

.26

.44

.11

.11

13.0

360

114

95

30.4

45.6

37.6

31.5

37.6

736

742

738

737

738

985

173

178

1395

6.13

1.77

.21

.39

.108 

.108*

2.63 

176.1 

73.9 

35.3 

15.16 

31.62 

23.64 

20.67*

23.21 

723.6 

729.9 

729.8 

730.7*

726.2 

34.9 

34.4 

30.4 

32.1 

2.351 

.775 

.048 

.138 

24 HOUR

24 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

1 HOUR

24-HR BLK 

AVG

24-HR BLK 

AVG

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

5

5

5

5

0

0

0

0

45810

45810

61101

61102

62101

62201

68103

68104

68105

68105

68105

68106

68107

68108

68108

68108

81102

81102

81102

81102

82102

82103

82105

82110

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1,2,4-Trichlorobenzene

1,2,4-Trichlorobenzene

Wind Speed - Scalar

Wind Direction - Scalar

Outdoor Temperature

Relative Humidity 

Ambient Min Temperature

Ambient Max Temperature

Ambient Temperature

Ambient Temperature

Ambient Temperature

Sample Min Baro Pressure

Sample Max Baro Pressure

Sample Baro Pressure

Sample Baro Pressure

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Antimony PM10 STP

Arsenic PM10 STP

Beryllium PM10 STP

Cadmium PM10 STP

Parts per billion 

Carbon

Parts per billion 

Carbon

Knots

Degrees Compass

Degrees Fahrenheit

Percent relative 

humidity

Degrees Centigrade

Degrees Centigrade

Degrees Centigrade

Degrees Centigrade

Degrees Centigrade

Millimeters (mercury)

Millimeters (mercury)

Millimeters (mercury)

Millimeters (mercury)

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Meth

101

101

040

040

021

012

810

810

000

145

810

810

810

000

145

810

122

122

079

079

202

202

202

202

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 29 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

1

1

1

1

3

1

2

3

3

7

7

7

7

7

0329

0329

0329

0329

0329

0329

0329

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 61

 61

 61

 61

 61

 61

 8612

 121

 37

 8649

 362

 117

 117

 117

 117

 117

8.19

2.96

.0116

130.00

5.89

.05

.89

910.0

37.7

21.4

674.0

64.3

.091

.003

1.770

.044

.010

7.08

2.54

.0102

117.00

5.36

.04

.65

864.0

25.2

19.2

453.0

48.4

.075

.002

1.320

.032

.007

6.35

2.45

.0097

111.00

4.96

.03

.62

849.0

23.0

17.2

253.0

38.3

.055

.002

.664

.030

.007

6.04

2.28

.0080

85.40

4.38

.03

.57

846.0

21.8

15.7

245.0

35.0

.052

.002

.629

.030

.007

3.033 

.673 

.00401 

22.825 

1.738 

.015 

.245 

23.41 

8.95 

8.12*

10.09 

10.05 

.0219 

.0010 

.1559 

.0095 

.0032 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

1 HOUR

24 HOUR

24 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

5

0

5

5

0

0

0

0

0

82112

82113

82128

82132

82136

82142

82154

86101

88101

88101

88101

88101

88102

88103

88104

88107

88109

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Chromium PM10 STP

Cobalt PM10 STP

Lead PM10 STP

Manganese PM10 STP

Nickel PM10 STP

Mercury PM10 STP

Selenium PM10 STP

PM10-2.5 - Local Conditions

PM2.5 - Local Conditions

PM2.5 - Local Conditions

PM2.5 - Local Conditions

PM2.5 - Local Conditions

Antimony PM2.5 LC

Arsenic PM2.5 LC

Aluminum PM2.5 LC

Barium PM2.5 LC

Bromine PM2.5 LC

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Micrograms/cubic meter

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

202

202

202

202

202

202

202

185

000

145

170

170

811

811

811

811

811

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 30 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

.017

1.280

.049

.003

.029

.380

.044

.023

1.160

.009

.027

.036

.014

.198

.032

.003

.021

.015

.606

.032

.003

.026

.227

.043

.023

.878

.008

.021

.027

.012

.122

.008

.001

.020

.014

.500

.012

.003

.025

.192

.043

.023

.470

.008

.021

.013

.006

.106

.008

.001

.019

.013

.435

.010

.003

.024

.178

.043

.023

.413

.007

.018

.012

.003

.098

.008

.001

.019

.0086 

.1310 

.0024 

.0010 

.0077 

.0458 

.0072 

.0081 

.1782 

.0026 

.0110 

.0038 

.0011 

.0195 

.0057 

.0011 

.0130 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

88110

88111

88112

88113

88114

88115

88117

88118

88126

88128

88131

88132

88136

88140

88152

88154

88160

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Cadmium PM2.5 LC

Calcium PM2.5 LC

Chromium PM2.5 LC

Cobalt PM2.5 LC

Copper PM2.5 LC

Chlorine PM2.5 LC

Cerium PM2.5 LC

Cesium PM2.5 LC

Iron PM2.5 LC

Lead PM2.5 LC

Indium PM2.5 LC

Manganese PM2.5 LC

Nickel PM2.5 LC

Magnesium PM2.5 LC

Phosphorus PM2.5 LC

Selenium PM2.5 LC

Tin PM2.5 LC

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 31 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 117

 108

 108

.089

.006

4.840

.019

.042

.013

.856

.003

1.200

.351

.012

2.16

.42

1.10

6.93

9.830

2.400

.071

.006

3.360

.019

.030

.011

.832

.001

.841

.306

.012

1.93

.40

.34

5.71

7.310

2.300

.037

.006

1.730

.019

.027

.010

.829

.001

.549

.288

.012

1.53

.35

.28

5.42

6.530

2.230

.035

.005

1.720

.019

.025

.009

.807

.001

.388

.248

.012

1.47

.33

.26

4.98

6.450

2.020

.0105 

.0018 

.4275 

.0094 

.0091 

.0023 

.3211 

.0010 

.1413 

.0762 

.0046 

.448 

.114 

.082 

.928 

2.3269 

.5897 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

88161

88164

88165

88166

88167

88168

88169

88176

88180

88184

88185

88301

88302

88303

88306

88355

88357

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Titanium PM2.5 LC

Vanadium PM2.5 LC

Silicon PM2.5 LC

Silver PM2.5 LC

Zinc PM2.5 LC

Strontium PM2.5 LC

Sulfur PM2.5 LC

Rubidium PM2.5 LC

Potassium PM2.5 LC

Sodium PM2.5 LC

Zirconium PM2.5 LC

Ammonium Ion PM2.5 LC

Sodium Ion Pm2.5 LC

Potassium Ion PM2.5 LC

Total Nitrate PM2.5 LC

OC CSN_Rev Unadjusted PM2.5 LC 

TOT

EC CSN_Rev Unadjusted PM2.5 LC 

TOT

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

811

811

811

811

811

811

811

811

811

811

811

812

812

812

812

839

840

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 32 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

7

7

7

7

7

7

7

7

7

7

3

3

7

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 108

 108

 108

 108

 108

 108

 108

 108

 108

 108

 108

 117

 275

 6577

 117

 8678

 3866

9.040

1.490

2.220

2.670

1.260

1.450

3.020

4.350

.233

.032

2.240

2.52

49.7

717.1

34.3

1.56

.08

6.670

1.210

1.630

2.420

1.200

.620

2.860

2.990

.209

.023

1.460

2.49

37.0

310.1

23.0

1.52

.07

6.480

1.170

1.610

2.210

1.180

.610

2.610

2.950

.164

.012

1.250

2.49

35.1

277.1

21.9

1.51

.07

5.820

.932

1.390

2.210

1.170

.599

2.570

2.650

.150

.012

1.120

2.42

33.0

212.5

21.6

1.51

.07

2.1644 

.1565 

.5135 

.7844 

.4572 

.2530 

.7524 

.9387 

.0654 

.0020 

.4156 

.968 

12.35*

12.39 

9.66 

.353 

.016 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

24 HOUR

1 HOUR

1 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

88370

88374

88375

88376

88377

88378

88380

88383

88384

88385

88388

88403

88500

88500

88502

63301

63302

Parameter

Site ID:

Site ID:

04-013-9997

04-013-9998

Phoenix

Phoenix

City:

City:

Maricopa

Maricopa

Unit

County:

County:

4530 N 17TH AVENUE

600 N 40TH ST & FILLMORE ST,PHOENIX

Address:

Address:

OC CSN_Rev Unadjusted PM2.5 LC 

TOR

OC1 CSN_Rev Unadjusted PM2.5 LC

OC2 CSN_Rev Unadjusted PM2.5 LC

OC3 CSN_Rev Unadjusted PM2.5 LC

OC4 CSN_Rev Unadjusted PM2.5 LC

OP CSN_Rev Unadjusted PM2.5 LC 

TOR

EC CSN_Rev Unadjusted PM2.5 LC 

TOR

EC1 CSN_Rev Unadjusted PM2.5 LC

EC2 CSN_Rev Unadjusted PM2.5 LC

EC3 CSN_Rev Unadjusted PM2.5 LC

OP CSN_Rev Unadjusted PM2.5 LC 

TOT

Sulfate PM2.5 LC

PM2.5 Total Atmospheric

PM2.5 Total Atmospheric

Acceptable PM2.5 AQI & Speciation

Mass

Solar radiation

Ultraviolet radiation

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Langleys/minute

Langleys/minute

Meth

838

841

841

841

841

842

831

841

841

841

826

812

761

761

810

011

011

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 33 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

3

3

3

3

1

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 61

 61

 360

 8605

 350

 8390

 3118

 15

 45

 5

 17

 15

 45

 15

 45

132

124

213

1354

242

1988

15.4

285.00

425.00

1.18

1.66

.71

.76

.22

.22

38

37

206

1224

226

1423

14.6

233.00

378.00

1.02

1.46

.68

.73

.22

.22

32

30

167

1099

209

1386

14.6

216.00

184.00

.07

1.46

.62

.72

.22

.22

30

28

157

1034

171

1241

13.7

201.00

179.00

.07

1.38

.53

.70

.22

.22

15.4 

14.9 

29.0 

29.3 

41.7 

42.2 

2.89*

165.740*

123.180*

.479*

.703*

.392*

.350*

.215*

.215*

24 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

24-HR BLK 

AVG

1 HOUR

1 HOUR

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

5

5

5

5

0

0

0

0

0

0

0

0

0

81102

85101

81102

81102

81102

81102

42600

43102

43102

43127

43127

43141

43141

43142

43142

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

04-015-1003

04-019-0001

04-019-0020

04-021-8001

Bullhead City

Ajo

Rillito

Queen Valley

City:

City:

City:

City:

Mohave

Pima

Pima

Pinal

Unit

County:

County:

County:

County:

BULLHEAD CITY 990 HWY 95

AZ HWY DEPT YARD-WELL RD, AJO

8840 W ROBINSON STREET, RILLITO

10 S QUEEN ANN QUEEN VALLEY

Address:

Address:

Address:

Address:

PM10 Total 0-10um STP

PM10 - LC

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Reactive oxides of nitrogen (NOy)

Total NMOC (non-methane organic 

compound)

Total NMOC (non-methane organic 

compound)

Isobutene & 1-butene

Isobutene & 1-butene

n-Dodecane

n-Dodecane

Tridecene

Tridecene

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Parts per billion

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

079

079

079

079

574

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 34 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

.22

.22

.05

.05

.13

.13

5.25

5.98

2.30

3.74

1.74

3.19

.91

1.59

.48

.71

.71

.22

.22

.05

.05

.13

.13

3.92

5.35

2.06

2.37

1.35

2.55

.83

1.55

.42

.46

.55

.22

.22

.05

.05

.13

.13

3.87

5.26

1.78

2.08

1.32

2.48

.80

.98

.42

.45

.45

.22

.22

.05

.05

.13

.13

3.67

5.16

1.57

2.04

1.17

1.89

.69

.91

.37

.39

.36

.215*

.215*

.050*

.050*

.130*

.130*

2.410*

2.404*

1.298*

1.273*

1.024*

1.055*

.546*

.540*

.301*

.280*

.291*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43143

43143

43144

43144

43145

43145

43202

43202

43203

43203

43204

43204

43205

43205

43206

43206

43212

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

n-Tridecane

n-Tridecane

Propyne

Propyne

1-Octene

1-Octene

Ethane

Ethane

Ethylene

Ethylene

Propane

Propane

Propylene

Propylene

Acetylene

Acetylene

n-Butane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 35 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 38

 15

 45

 15

 45

1.01

.49

.36

.35

.48

.09

.09

.10

.27

8.32

2.76

12.80

14.40

.23

.25

.10

.10

.74

.27

.32

.22

.38

.09

.09

.10

.10

.40

2.13

9.22

10.90

.19

.21

.10

.10

.74

.23

.32

.16

.26

.09

.09

.10

.10

.37

.59

8.97

10.10

.18

.21

.10

.10

.62

.23

.31

.15

.18

.09

.09

.10

.10

.34

.49

8.21

8.47

.17

.20

.10

.10

.270*

.148*

.139*

.110*

.097*

.085*

.085*

.095*

.099*

.775*

.321*

6.743*

5.706*

.114*

.110*

.095*

.095*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43212

43214

43214

43216

43216

43217

43217

43218

43218

43220

43220

43221

43221

43224

43224

43225

43225

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

n-Butane

Isobutane

Isobutane

trans-2-Butene

trans-2-Butene

cis-2-Butene

cis-2-Butene

1,3-Butadiene

1,3-Butadiene

n-Pentane

n-Pentane

Isopentane

Isopentane

1-Pentene

1-Pentene

2-Methyl-1-butene

2-Methyl-1-butene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 36 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

.07

.15

.09

.09

.26

.50

.22

.24

.21

.25

.10

.10

.55

.32

.17

.17

.11

.07

.15

.09

.09

.25

.41

.09

.20

.19

.20

.10

.10

.12

.28

.17

.17

.11

.07

.07

.09

.09

.10

.35

.09

.18

.09

.19

.10

.10

.12

.26

.17

.17

.11

.07

.07

.09

.09

.10

.33

.09

.09

.09

.09

.10

.10

.12

.12

.17

.17

.11

.070*

.074*

.090*

.090*

.116*

.147*

.094*

.093*

.105*

.098*

.095*

.095*

.144*

.126*

.165*

.165*

.105*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43226

43226

43227

43227

43228

43228

43230

43230

43231

43231

43232

43232

43233

43233

43234

43234

43235

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

trans-2-Pentene

trans-2-Pentene

cis-2-Pentene

cis-2-Pentene

2-Methyl-2-butene

2-Methyl-2-butene

3-Methylpentane

3-Methylpentane

n-Hexane

n-Hexane

n-Heptane

n-Heptane

n-Octane

n-Octane

4-Methyl-1-pentene

4-Methyl-1-pentene

n-Nonane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 37 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

.11

.17

.17

.10

.10

.36

.63

.54

1.03

.16

.16

.17

.17

.17

.17

.12

.12

.11

.17

.17

.10

.10

.20

.41

.44

.74

.07

.15

.17

.17

.17

.17

.12

.12

.11

.17

.17

.10

.10

.16

.21

.40

.73

.07

.07

.17

.17

.17

.17

.12

.12

.11

.17

.17

.10

.10

.15

.20

.39

.73

.07

.07

.17

.17

.17

.17

.12

.12

.105*

.165*

.165*

.100*

.100*

.121*

.119*

.257*

.367*

.076*

.074*

.165*

.165*

.165*

.165*

.115*

.115*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43235

43236

43236

43238

43238

43242

43242

43243

43243

43244

43244

43245

43245

43246

43246

43247

43247

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

n-Nonane

2-Ethyl-1-butene

2-Ethyl-1-butene

n-Decane

n-Decane

Cyclopentane

Cyclopentane

Isoprene

Isoprene

2,2-Dimethylbutane

2,2-Dimethylbutane

1-Hexene

1-Hexene

2-Methyl-1-pentene

2-Methyl-1-pentene

2,4-Dimethylpentane

2,4-Dimethylpentane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 38 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

.10

.45

.07

.33

.28

.23

.39

.53

.08

.08

.10

.33

.10

1.25

.09

.09

.08

.10

.10

.07

.24

.19

.23

.27

.39

.08

.08

.10

.10

.10

.10

.09

.09

.08

.10

.10

.07

.07

.08

.22

.24

.37

.08

.08

.10

.10

.10

.10

.09

.09

.08

.10

.10

.07

.07

.08

.19

.23

.34

.08

.08

.10

.10

.10

.10

.09

.09

.08

.095*

.103*

.070*

.080*

.101*

.092*

.150*

.147*

.080*

.080*

.100*

.105*

.100*

.126*

.090*

.090*

.080*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43248

43248

43249

43249

43250

43250

43252

43252

43253

43253

43256

43256

43257

43257

43261

43261

43262

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

Cyclohexane

Cyclohexane

3-Methylhexane

3-Methylhexane

2,2,4-Trimethylpentane

2,2,4-Trimethylpentane

2,3,4-Trimethylpentane

2,3,4-Trimethylpentane

3-Methylheptane

3-Methylheptane

alpha.-Pinene

alpha.-Pinene

beta.-Pinene

beta.-Pinene

Methylcyclohexane

Methylcyclohexane

Methylcyclopentane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 39 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 45

 15

 45

 15

 45

 15

 45

 14

 44

 15

 45

 15

 45

 15

 45

 15

 45

.08

.47

.52

.13

.13

.10

.10

1.56

.99

.11

.11

1.00

1.36

.17

.17

.17

.17

.08

.34

.37

.13

.13

.10

.10

1.11

.66

.11

.11

.64

.86

.17

.17

.17

.17

.08

.26

.31

.13

.13

.10

.10

.75

.66

.11

.11

.44

.85

.17

.17

.17

.17

.08

.11

.26

.13

.13

.10

.10

.48

.62

.11

.11

.44

.62

.17

.17

.17

.17

.080*

.159*

.136*

.125*

.125*

.095*

.095*

.367*

.223*

.105*

.105*

.383*

.362*

.165*

.165*

.165*

.165*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43262

43263

43263

43279

43279

43282

43282

43283

43283

43284

43284

43285

43285

43289

43289

43290

43290

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

Methylcyclopentane

2-Methylhexane

2-Methylhexane

1-Nonene

1-Nonene

3-Methyl-1-butene

3-Methyl-1-butene

Cyclopentene

Cyclopentene

2,3-Dimethylbutane

2,3-Dimethylbutane

2-Methylpentane

2-Methylpentane

trans-2-Hexene

trans-2-Hexene

cis-2-Hexene

cis-2-Hexene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 40 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

1

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 4401

.22

.22

.13

.13

.10

.10

.10

.10

.22

.22

.84

1.00

.24

.10

.07

.07

.083

.22

.22

.13

.13

.10

.10

.10

.10

.22

.22

.22

.53

.10

.10

.07

.07

.080

.22

.22

.13

.13

.10

.10

.10

.10

.22

.22

.22

.48

.10

.10

.07

.07

.079

.22

.22

.13

.13

.10

.10

.10

.10

.22

.22

.22

.47

.10

.10

.07

.07

.078

.220*

.220*

.130*

.130*

.100*

.100*

.100*

.100*

.220*

.220*

.257*

.251*

.109*

.100*

.065*

.065*

.0578 

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

8-HR RUN 

AVG BEGIN 

HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43291

43291

43292

43292

43298

43298

43299

43299

43328

43328

43330

43330

43954

43954

43960

43960

44201

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

2,3-Dimethylpentane

2,3-Dimethylpentane

2-2-3-Trimethylpentane

2-2-3-Trimethylpentane

1-Decene

1-Decene

1-Undecene

1-Undecene

1-Heptene

1-Heptene

Dodecene

Dodecene

n-Undecane

n-Undecane

2-Methylheptane

2-Methylheptane

Ozone

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per million

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

087

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 41 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 15

 45

 1

 3

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

.12

.29

.11

.11

1.18

1.14

.09

.19

.09

.09

.10

.10

.68

.65

.10

.10

.10

.12

.12

.11

.98

.90

.09

.09

.09

.09

.10

.10

.20

.31

.10

.10

.10

.12

.12

.11

.94

.83

.09

.09

.09

.09

.10

.10

.19

.28

.10

.10

.10

.12

.12

.93

.71

.09

.09

.09

.09

.10

.10

.19

.26

.10

.10

.10

.120*

.124*

.110*

.110*

.769*

.414*

.090*

.092*

.085*

.085*

.095*

.095*

.150*

.124*

.095*

.095*

.100*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45109

45109

45201

45201

45202

45202

45203

45203

45204

45204

45207

45207

45208

45208

45209

45209

45210

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

m/p Xylene

m/p Xylene

Benzene

Benzene

Toluene

Toluene

Ethylbenzene

Ethylbenzene

o-Xylene

o-Xylene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

n-Propylbenzene

n-Propylbenzene

Isopropylbenzene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 42 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

1

2

1

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 15

 45

 44

 65

 60

.10

.10

.10

.09

.09

1.02

.98

.30

.32

.45

.13

.21

.19

.13

.13

31.9

32.2

667

.10

.10

.10

.09

.09

1.00

.69

.21

.27

.13

.13

.21

.18

.13

.13

27.4

31.9

666

.10

.10

.10

.09

.09

.75

.66

.19

.27

.13

.13

.18

.17

.13

.13

27.1

28.7

666

.10

.10

.10

.09

.09

.58

.64

.17

.24

.13

.13

.16

.16

.13

.13

26.9

28.5

665

.100*

.095*

.095*

.085*

.085*

.547*

.433*

.131*

.142*

.151*

.130*

.106*

.086*

.125*

.125*

16.11*

18.60 

662.3 

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45210

45211

45211

45212

45212

45218

45218

45219

45219

45220

45220

45225

45225

45228

45228

68105

68105

68108

Parameter

Site ID:

Site ID:

04-021-8001

04-023-0004

Queen Valley

Nogales

City:

City:

Pinal

Santa Cruz

Unit

County:

County:

10 S QUEEN ANN QUEEN VALLEY

300 N MORLEY AVE

Address:

Address:

Isopropylbenzene

o-Ethyltoluene

o-Ethyltoluene

m-Ethyltoluene

m-Ethyltoluene

m-Diethylbenzene

m-Diethylbenzene

p-Diethylbenzene

p-Diethylbenzene

Styrene

Styrene

1,2,3-Trimethylbenzene

1,2,3-Trimethylbenzene

Benzene, 1-ethenyl-4-methyl

Benzene, 1-ethenyl-4-methyl

Ambient Temperature

Ambient Temperature

Sample Baro Pressure

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Degrees Centigrade

Degrees Centigrade

Millimeters (mercury)

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

143

143

143

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 43 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

2

1

3

3

1

1

2

3

3

1

1

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

 65

 62

 8382

 350

 62

 59

 60

 353

 8440

 58

 58

 57

 57

 57

 4444

666

126

633

161

114

29.1

27.9

49.7

309.0

29.1

638

90

75

14.3

.078

666

109

498

159

100

27.2

26.2

44.1

166.0

28.2

638

25

22

10.2

.073

666

90

492

151

79

25.1

25.8

41.7

165.0

28.1

637

20

17

7.7

.072

665

86

449

138

78

22.9

23.2

40.3

162.0

27.7

637

20

16

6.0

.070

661.9 

39.1 

54.4 

53.9 

34.8 

10.05 

9.69*

9.80 

9.84 

14.52 

632.8 

11.6 

9.8 

3.87 

.0512 

24 HOUR

24 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

68108

81102

81102

81102

85101

88101

88101

88501

88501

68105

68108

81102

85101

88101

44201

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

04-023-0004

04-025-2002

04-025-8033

04-027-8011

Nogales

Prescott Valley

Prescott

Yuma

City:

City:

City:

City:

Santa Cruz

Yavapai

Yavapai

Yuma

Unit

County:

County:

County:

County:

300 N MORLEY AVE

7501 E. CIVIC CIRCLE, PRESCOTT VALLEY

330 Grove Avenue

2323 S ARIZONA AVE

Address:

Address:

Address:

Address:

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

PM2.5 - Local Conditions

PM2.5 Raw Data

PM2.5 Raw Data

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

Ozone

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Parts per million

Meth

143

126

122

122

126

143

143

731

731

143

143

126

126

143

087

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 44 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

3

3

1

0053

0053

0053

0053

0053

0053

2011

2011

2011

2011

2011

2011

 5132

 59

 59

 8529

 356

 59

.082

38.5

766

3089

225

15.7

.080

37.7

765

1383

178

15.6

.076

37.2

762

1162

127

13.7

.076

37.0

759

850

117

12.7

.0514 

24.76 

753.0 

30.2 

29.7 

7.62 

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

0

0

0

5

5

0

44201

68105

68108

81102

81102

88101

Parameter

Site ID: 04-027-8011 City: Yuma Yuma

Unit

County: Address: 2323 S ARIZONA AVE

Ozone

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM2.5 - Local Conditions

Parts per million

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Meth

087

143

143

079

079

143

Cert

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 45 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

12115

14129

17141

17147

17148

17149

17150

17151

17158

17159

17160

17201

17204

17208

17211

17212

17215

17220

17223

17224

17231

17237

17242

17243

42101

42153

42401

42401

42406

42406

42600

42600

42601

920

191

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

588

101

060

592

060

592

000

574

074

LO-VOL-XONTECH 920 or 924

Hi-Vol

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

INSTRUMENTAL

CANISTER SUBAMBIENT PRESSURE

INSTRUMENTAL

Instrumental

INSTRUMENTAL

Instrumental

MULTIPLE METHODS

Instrumental

INSTRUMENTAL

ION CHROMATOGRAPH UV VISIBLE

Inductively Coupled Plasma-Mass Spectrometry Acid filter 

extraction with nitric and hydrochloric acid

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

Gas Filter Correlation Ecotech EC9830T

MULTI DETECTOR GC

PULSED FLUORESCENT

Ultraviolet Fluorescence EC9850T

PULSED FLUORESCENT

Ultraviolet Fluorescence EC9850T

MULTIPLE METHODS

Chemiluminescence Thermo Electron 42C-Y, 42i-Y

CHEMILUMINESCENCE

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 46 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

42602

42603

43102

43127

43141

43142

43143

43144

43145

43202

43203

43204

43205

43205

43206

43206

43208

43212

43214

43216

43217

43218

43218

43220

43221

43224

43225

43226

43227

43228

43230

43231

43232

43233

074

074

126

126

126

126

126

126

126

126

126

126

101

126

101

126

101

126

126

126

126

101

126

126

126

126

126

126

126

126

126

126

126

101

INSTRUMENTAL

INSTRUMENTAL

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

Canister Subambient Pressure

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

CHEMILUMINESCENCE

CHEMILUMINESCENCE

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

Multi Detector GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 47 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43233

43234

43235

43236

43238

43242

43243

43244

43245

43246

43247

43248

43249

43250

43252

43253

43256

43257

43261

43262

43263

43279

43282

43283

43284

43285

43289

43290

43291

43292

43298

43299

43328

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 48 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43329

43330

43372

43373

43396

43438

43441

43502

43503

43504

43505

43513

43517

43518

43528

43551

43552

43560

43702

43704

43801

43802

43803

43804

43806

43811

43812

43813

43814

43815

43817

43818

43819

202

126

101

101

101

101

101

202

202

202

101

202

202

202

202

202

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

SILICA-DNPH-CART-KI O3 SCRUB

SS CANISTER PRESSURIZED

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

CANISTER SUBAMBIENT PRESSURE

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CRYOGENIC PRECONCENTRATION GC/FID

HPLC ULTRAVIOLET ABSORPTION

CRYOGENIC PRECONCENTRATION GC/FID

Multi Detector GC

Multi Detector GC

Multi Detector GC

Multi Detector GC

Multi Detector GC

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

MULTI DETECTOR GC

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

Multi Detector GC

Multi Detector GC

Multi Detector GC

Multi Detector GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 49 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43820

43821

43823

43824

43826

43828

43829

43830

43831

43832

43835

43836

43838

43839

43843

43844

43860

43954

43960

44201

44201

45109

45109

45201

45201

45202

45202

45203

45203

45204

45204

45207

45207

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

126

126

000

087

101

126

101

126

101

126

101

126

101

126

101

126

CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure

Canister Subambient Pressure

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

MULTIPLE METHODS

INSTRUMENTAL

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

MULTI DETECTOR GC

MULTI DETECTOR GC

Multi Detector GC

Multi Detector GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

Multi Detector GC

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTIPLE METHODS

ULTRA VIOLET ABSORPTION

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 50 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

45208

45208

45209

45210

45211

45212

45218

45219

45220

45220

45225

45228

45501

45503

45504

45801

45805

45806

45807

45809

45810

61101

61102

62101

62201

63301

63302

68103

68104

68105

68105

68105

68105

101

126

126

126

126

126

126

126

101

126

126

126

202

202

202

101

101

101

101

101

101

040

040

021

012

011

011

810

810

000

143

145

780

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure

Canister Subambient Pressure

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

Met One SASS

Met One SASS

MULTIPLE METHODS

R & P Model 2000 PM-2.5 FEM Air Sampler

R & P Model 2025 PM-2.5 FEM Sequential Air Sam

INSTRUMENTAL

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

Multi Detector GC

Multi Detector GC

VISUAL AVERAGE

VISUAL AVERAGE

SPOT READING LEVEL 1

HYGROSCOPIC PLASTIC FILM

PYRANOMETER

UV RADIOMETER (PHOTOMETER)

Electronic

Electronic

MULTIPLE METHODS

Electronic

Electronic

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 51 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

68105

68106

68107

68108

68108

68108

68108

68108

81102

81102

81102

82102

82103

82105

82110

82112

82113

82128

82132

82136

82142

82154

85101

86101

88101

88101

88101

88101

88102

88103

88104

88107

88109

810

810

810

000

143

145

780

810

079

122

126

202

202

202

202

202

202

202

202

202

202

202

126

185

000

143

145

170

811

811

811

811

811

Met One SASS

Met One SASS

Met One SASS

MULTIPLE METHODS

R & P Model 2000 PM-2.5 FEM Air Sampler

R & P Model 2025 PM-2.5 FEM Sequential Air Sam

INSTRUMENTAL

Met One SASS

INSTRUMENTAL-R&P SA246B-INLET

INSTRUMENT MET ONE 4 MODELS

R - P Co Partisol Model 2000

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R - P Co Partisol Model 2000

Met One BAM-1020 System

MULTIPLE METHODS

R & P Model 2000 PM-2.5 Air Sampler w/VSCC

R & P Model 2025 PM-2.5 Sequential Air Sampler

Met One BAM-1020 Mass Monitor w/VSCC

Met One SASS Teflon

Met OneSASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

ELECTRONIC

Electronic

Barometric Sensor

Barometric Sensor

MULTIPLE METHODS

Barometric Sensor

Barometric Sensor

BAROMETRIC SENSOR

Barometric Sensor

TEOM-GRAVIMETRIC

BETA ATTENUATION

Gravimetric

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

Gravimetric

Paired Gravimetric Difference

MULTIPLE METHODS

Gravimetric

Gravimetric

Beta Attenuation

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 52 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

88110

88111

88112

88113

88114

88115

88117

88118

88126

88128

88131

88132

88136

88140

88152

88154

88160

88161

88164

88165

88166

88167

88168

88169

88176

88180

88184

88185

88301

88302

88303

88306

88355

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

812

812

812

812

839

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Nylon

Met One SASS Nylon

Met One SASS Nylon

Met One SASS Nylon

URG 3000N w/Pall Quartz filter and Cyclone Inl

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy Dispersive XRF

Energy dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Ion Chromatography

Ion Chromatography

Ion Chromatography

Ion Chromatography

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 53 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

88357

88370

88374

88375

88376

88377

88378

88380

88383

88384

88385

88388

88403

88500

88501

88502

840

838

841

841

841

841

842

831

841

841

841

826

812

761

731

810

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter adn Cyclone Inl

URG 3000N w/Pall Quartz filter adn Cyclone Inl

URG 3000N w/Pall Quartz filter adn Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

Met One SASS Nylon

PM2.5 VSCC

Met-One BAM-1020 W/PM2.5 SCC

Met One SASS Teflon

OC1+OC2+OC3+OC4+(OP(TOT))=(88374+88375+88376+88377+88388)

EC1+EC2+EC3-(OP(TOT))=(88383+88384+88385-88388))

OC1+OC2+OC3+OC4+(OP(TOR))=(88374+88375+88376+88377+88378)

IMPROVE_A

IMPROVE_A

IMPROVE_A

IMPROVE_A

IMPROVE_A TOR

EC1+EC2+EC3-(OP(TOR))=(88383+88384+88385-88378))

IMPROVE_A

IMPROVE_A

IMPROVE_A

IMPROVE_A TOT

Ion Chromatography

FDMS-Gravimetric

Beta Attenuation

Gravimetric

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 54 of 54

PQAOS USED IN THIS REPORT

PQAO AGENCY DESCRIPTION

0053

0329

Arizona Department Of Environmental Quality

Eastern Research Group

ADEQ ATTACHMENT # 2
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

DATA QUALITY INDICATOR REPORT

Report Request ID: 1021468 Report Code: AMP255 Sep. 21, 2012

Selection Criteria Page 1

User ID: BNE

State County Site Parameter POC City AQCR UAR CBSA CSA

EPA

Region Method Duration Begin Date End Date

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

APP_A_PARAMETERS

PQAO SELECTIONS

Arizona Department Of Environmental 

Quality

Freeport McMoRan Miami, Inc.

SELECTED OPTIONS

INCLUDE ONLY APPENDIX A 

MONITORS

RESTRICT TO MONITORING 

SEASONS

MERGE PDF FILES

Option Type Option Value

NO

YES

YES

GLOBAL DATES

2011

Start Date End Date

01 01 2011 12 31

Tribal

Code

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 1 of 14

Code Listing

The following codes may be seen in the "MT" column throughout this report. Please be advised that not all of the 

codes may appear in the report. They are provided for completeness.

NR S

P T

SP I

NC IX

ID N

NA CN

F O

PN ST

VS QA

X SS

SU SU

TS U

UP W

M

NON-REGULATORY SLAMS

PAMS TRIBAL MONITORS

SPECIAL PURPOSE IMPROVE

NCORE INDEX SITE

INDUSTRIAL NAMS

NATTS CASTNET

NON-EPA FEDERAL OTHER

PROPOSED NCORE SCHOOL AIR TOXICS

VOL SCHOOL AT QA COLLOCATED

SECURED SLAMS SPECIATION

SUPLMNTL SPECIATION SUPPLMNTL SPECIATION

TRENDS SPECIATION UNKNOWN

UNOFFICIAL PAMS WHO

WMO

Code Description Description

Notes About this Report

If you see this value for a column in a summarized row, this means that more than one occurence exist in the summary. For example, if you have a PQAO 

summary that spans multiple States, you would see this value in the States column. 

M

Code

For specific information about the fields appearing within this report, please refer to the README.txt file that is included with the WORKFILE output 

for this report. 

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 2 of 14

1-Point Quality Control

CO

NO2

O3

SO2

Pollutant:

Pollutant:

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

PQAO:

PQAO:

Yes

Yes

Yes

Yes

App A?:

App A?:

App A?:

App A?:

Year

Year

Year

Year

Region

Region

Region

Region

State

State

State

State

Site ID

Site ID

Site ID

Site ID

POC

POC

POC

POC

MT

MT

MT

MT

Begin

Date

Begin

Date

Begin

Date

Begin

Date

End

Date

End

Date

End

Date

End

Date

# Req

# Req

# Req

# Req

# Obs

# Obs

# Obs

# Obs

% 

Complete

% 

Complete

% 

Complete

% 

Complete

CV

CV

CV

CV

Bias

Bias

Bias

Bias

2011

2011

SUMMARY

2011

2011

SUMMARY

2011

2011

2011

2011

2011

2011

2011

2011

SUMMARY

2011

2011

2011

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-013-9997

SUMMARY

04-013-9997

SUMMARY

04-005-1008

04-007-0010

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

SUMMARY

04-007-0009

04-007-1001

04-013-9997

1

1

1

1

1

1

1

1

1

1

3

1

S-NC

S

S

S

S

S-NC

S

S

S

S

S

S-NC

01-JAN-11

01-JAN-11

01-APR-11

01-APR-11

01-APR-11

01-JAN-11

01-APR-11

01-APR-11

01-APR-11

01-JAN-11

01-JAN-11

01-JAN-11

31-DEC-11

31-DEC-11

31-OCT-11

31-OCT-11

31-OCT-11

31-DEC-11

31-OCT-11

31-OCT-11

31-OCT-11

31-DEC-11

31-DEC-11

31-DEC-11

26

26

26

26

26

26

15

15

15

26

15

15

15

116

116

26

26

26

15

15

15

21

21

21

11

9

11

18

14

14

12

89

89

22

21

16

58

58

58

81

81

81

73

60

73

69

93

93

80

77

77

85

81

62

 7.09

 7.09

 7.09

 2.96

 2.96

 2.96

 4.35

 4.98

 4.43

 3.58

 4.60

 4.08

 2.18

 3.14

 3.14

 3.24

 3.87

 2.50

 5.74

 5.74

 5.74

 2.51

 2.51

 2.51

 3.87

 4.02

 3.64

 3.30

 3.84

 3.76

 2.03

 2.77

 2.77

 3.35

 3.74

 2.02

+/-

+/-

+/-

+

+

+

+

+/-

+/-

+

+

+

+

+

+

+

+

+/-

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 3 of 14

1-Point Quality Control

Pollutant: SO2 PQAO: 0053 (Arizona Department Of Environmental Quality) App A?: Yes

Year Region State Site ID POC MT

Begin

Date

End

Date # Req # Obs

% 

Complete CV Bias

2011

SUMMARY

09

09

AZ

AZ

SUMMARY 78

78

59

59

76

76

 3.19

 3.19

 2.87

 2.87

+

+

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 4 of 14

Annual Performance Evaluations

CO

NO2

O3

Pollutant:

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

PQAO:

Yes

Yes

Yes

Year

Year

Year

Region

Region

Region

State

State

State

Site ID

Site ID

Site ID

POC

POC

POC

MT

MT

MT

Begin

Date

Begin

Date

Begin

Date

End

Date

End

Date

End

Date

2011

2011

SUMMARY

2011

2011

SUMMARY

2011

2011

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-013-9997

SUMMARY

04-013-9997

SUMMARY

04-005-1008

04-007-0010

1

1

1

1

S-NC

S

S

S

01-JAN-11

01-JAN-11

01-APR-11

01-APR-11

31-DEC-11

31-DEC-11

31-OCT-11

31-OCT-11

App A?:

App A?:

App A?:

 81.30

 81.30

 81.30

 23.43

 23.43

 23.43

 7.94

 7.94

 7.94

 1.36

 3.41

 2.62

 2.62

 2.62

-1.13

 4.38

0

0

0

3

3

3

0

0

0

0

0

0

0

0

5

0

4

4

4

4

4

4

0

5

0

0

0

0

0

0

0

0

Avg %D / Level

Avg %D / Level

Avg %D / Level

L1/6

L1/6

L1/6

L2/7

L2/7

L2/7

L3/8

L3/8

L3/8

L4/9

L4/9

L4/9

L5/10

L5/10

L5/10

Q1

Q1

Q1

Q2

Q2

Q2

Q3

Q3

Q3

Q4

Q4

Q4

Obs / Q

Obs / Q

Obs / Q

Met?

Met?

Met?

Criteria

Criteria

Criteria

Y

N

Y

Y

100

100

0

0

-9.08

-9.08

-3.73

-3.73

 11.64

 11.64

 5.41

 5.41

Conf. Limits

Conf. Limits

Conf. Limits

Lower

Lower

Lower

Upper

Upper

Upper

50

50

71

71

% Btwn

% Btwn

% Btwn

Conf.

Limits

Conf.

Limits

Conf.

Limits

1-Point

1-Point

1-Point

-1.69

-1.69

-1.69

-1.90

-3.51

-3.51

-3.51

-2.00 -2.02

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 5 of 14

Annual Performance Evaluations

O3

SO2

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

Yes

Yes

Year

Year

Region

Region

State

State

Site ID

Site ID

POC

POC

MT

MT

Begin

Date

Begin

Date

End

Date

End

Date

2011

2011

2011

2011

2011

2011

SUMMARY

2011

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

SUMMARY

04-007-0009

1

1

1

1

1

1

S

S-NC

S

S

S

S

01-APR-11

01-JAN-11

01-APR-11

01-APR-11

01-APR-11

01-JAN-11

31-OCT-11

31-DEC-11

31-OCT-11

31-OCT-11

31-OCT-11

31-DEC-11

App A?:

App A?:

 0.00

 0.00

 0.00

 0.00

 3.73

 9.56

-0.45

 0.00

 2.52

 2.52

-2.25

 1.92

 3.88

-1.38

-2.88

 0.36

 0.36

0

5

0

0

0

5

5

0

0

0

0

5

5

15

15

5

5

5

5

0

0

20

20

0

0

5

0

0

0

5

5

0

Avg %D / Level

Avg %D / Level

L1/6

L1/6

L2/7

L2/7

L3/8

L3/8

L4/9

L4/9

L5/10

L5/10

Q1

Q1

Q2

Q2

Q3

Q3

Q4

Q4

Obs / Q

Obs / Q

Met?

Met?

Criteria

Criteria

Y

Y

Y

Y

Y

Y

100

100

-3.92

-3.92

 7.18

 7.18

Conf. Limits

Conf. Limits

Lower

Lower

Upper

Upper

98

98

% Btwn

% Btwn

Conf.

Limits

Conf.

Limits

1-Point

1-Point

 5.90

-2.00

 2.95

 2.20

-0.80

-3.00

 0.48

 0.48

 5.08

 5.86

-2.46

 2.18

 1.15

-0.85

-2.92

 0.14

 0.14

 4.24 5.10

-0.85

-0.85

-0.85

 5.66

 7.00

-2.93

 1.94

-1.90

-0.82

-2.93

-0.24

-0.24

 4.89

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 6 of 14

Annual Performance Evaluations

Pollutant: SO2 PQAO: 0053 (Arizona Department Of Environmental Quality) Yes

Year Region State Site ID POC MT

Begin

Date

End

Date

2011

2011

2011

SUMMARY

09

09

09

09

AZ

AZ

AZ

AZ

04-007-1001

04-013-9997

SUMMARY

3

1

S

S-NC

01-JAN-11

01-JAN-11

31-DEC-11

31-DEC-11

App A?:

-5.83

-5.83

-5.83

-2.00

-2.00

-2.00

-2.77

-2.77

-2.77

0

3

3

3

0

0

5

5

5

0

5

5

0

4

4

4

Avg %D / Level

L1/6 L2/7 L3/8 L4/9 L5/10 Q1 Q2 Q3 Q4

Obs / Q

Met?

Criteria

Y

Y

100

100

-4.08

-4.08

 6.88

 6.88

Conf. Limits

Lower Upper

76

76

% Btwn

Conf.

Limits

1-Point

-1.08

-11.60

-2.53

-2.53

 1.04

 2.64

 2.64

 0.20

-3.99

 0.44

 0.44

 1.26

 3.46

 3.46

 0.49

-5.97

-0.20

-0.20

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

(Levels 6 thru 10)

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 7 of 14

Flow Rate Verifications

LEAD

PM10

PM10

Pollutant:

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

1357 (Freeport McMoRan Miami, Inc.)

PQAO:

PQAO:

PQAO:

Yes

Yes

Yes

App A?:

App A?:

App A?:

Year

Year

Year

Region

Region

Region

State

State

State

Site ID

Site ID

Site ID

POC

POC

POC

MT

MT

MT

Begin

Date

Begin

Date

Begin

Date

End

Date

End

Date

End

Date

# Req

# Req

# Req

# Obs

# Obs

# Obs

% 

Complete

% 

Complete

% 

Complete

Bias

Bias

Bias

2011

2011

2011

2011

SUMMARY

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

SUMMARY

2011

2011

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-007-1002

04-007-1002

04-007-8000

SUMMARY

04-003-0011

04-003-0011

04-003-1005

04-005-1008

04-007-0008

04-007-0008

04-007-1001

04-013-8006

04-013-9997

04-013-9997

04-015-1003

04-019-0001

04-019-0020

04-023-0004

04-023-0004

04-025-2002

04-027-8011

SUMMARY

04-007-0009

04-007-8000

1

2

1

1

2

1

1

1

2

3

1

3

4

1

3

3

1

3

1

3

1

1

S

S

S

S

QA

S

S

S

QA

S

SP

S

S

S

S

S

S

SP

S

S

ID

ID

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

30-JUN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

4

4

4

12

12

12

12

12

12

12

12

12

6

12

12

12

12

12

12

12

12

12

198

198

12

12

38

41

38

117

117

13

13

13

15

13

13

12

7

11

11

14

14

13

14

14

14

14

218

218

40

39

100

100

100

100

100

100

100

100

100

100

100

100

100

92

92

100

100

100

100

100

100

100

99

99

100

100

 4.24

 3.93

 4.02

 3.76

 3.76

 2.12

 1.27

 0.72

 1.09

 1.35

 1.32

 1.15

 1.57

 0.86

 0.96

 0.60

 1.21

 0.84

 0.80

 1.43

 0.61

 1.54

 0.89

 0.89

 1.66

 1.88

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+/-

+

+

+/-

+/-

+/-

+

+/-

+/-

+/-

+/-

-

+/-

Average

% D

Average

% D

Average

% D

-0.06

-0.71

-1.00

-0.59

-0.59

-0.66

 0.13

 0.21

-0.14

 0.09

 0.34

-0.01

 0.37

 0.17

 0.66

 0.34

 0.46

 0.17

-0.23

 0.65

-0.13

 0.40

 0.16

 0.16

-0.80

-0.43

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 8 of 14

Flow Rate Verifications

PM10

PM2.5

Pollutant:

Pollutant:

1357 (Freeport McMoRan Miami, Inc.)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

Yes

Yes

App A?:

App A?:

Year

Year

Region

Region

State

State

Site ID

Site ID

POC

POC

MT

MT

Begin

Date

Begin

Date

End

Date

End

Date

# Req

# Req

# Obs

# Obs

% 

Complete

% 

Complete

Bias

Bias

2011

2011

SUMMARY

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

SUMMARY

09

09

09

09

09

09

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-007-8000

SUMMARY

04-003-1005

04-005-1008

04-013-9997

04-013-9997

04-013-9997

04-023-0004

04-023-0004

04-025-2002

04-027-8011

SUMMARY

2

1

1

1

2

3

1

2

1

1

ID-QA

S

S

S-NC

QA

PN-QA

S

QA

S

S

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

30-JUN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

12

36

36

12

12

12

6

12

12

12

12

12

102

102

39

118

118

13

14

11

6

11

14

13

14

13

109

109

100

100

100

100

100

92

100

92

100

100

100

100

98

98

 1.33

 1.52

 1.52

 1.05

 1.12

 1.07

 35.05

 0.77

 1.16

 0.76

 1.02

 1.12

 2.40

 2.40

+/-

+/-

+/-

+

+/-

+/-

+/-

+

+/-

+/-

+/-

+/-

+/-

+/-

Average

% D

Average

% D

-0.66

-0.63

-0.63

 0.55

 0.15

 0.44

 12.11

 0.39

 0.23

 0.08

-0.03

 0.23

 0.90

 0.90

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 9 of 14

Semi-Annual Flow Rate Audits

LEAD

PM10

PM10

Pollutant:

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

1357 (Freeport McMoRan Miami, Inc.)

PQAO:

PQAO:

PQAO:

Yes

Yes

Yes

Year

Year

Region

Region

State

State

Site ID

Site ID

POC

POC

MT

MT

Begin

Date

Begin

Date

End

Date

End

Date

2011

2011

2011

2011

SUMMARY

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

SUMMARY

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-007-1002

04-007-1002

04-007-8000

SUMMARY

04-003-0011

04-003-0011

04-003-1005

04-005-1008

04-007-0008

04-007-0008

04-007-1001

04-013-8006

04-013-9997

04-013-9997

04-015-1003

04-019-0001

04-019-0020

04-023-0004

04-023-0004

04-025-2002

04-027-8011

SUMMARY

1

2

1

1

2

1

1

1

2

3

1

3

4

1

3

3

1

3

1

3

S

S

S

S

QA

S

S

S

QA

S

SP

S

S

S

S

S

S

SP

S

S

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

30-JUN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

App A?:

App A?:

App A?:

2

2

2

6

6

2

2

2

2

2

2

2

1

2

2

2

2

2

2

2

2

2

33

33

4

4

4

12

12

2

2

2

2

2

2

2

1

1

2

2

2

2

2

2

2

2

32

32

100

100

100

100

100

100

100

100

100

100

100

100

100

50

100

100

100

100

100

100

100

100

97

97

-0.4

-0.1

 1.1

 0.2

 0.2

-1.2

-0.5

-0.1

 1.1

 0.2

 1.3

 0.9

 2.4

-3.8

 0.2

 0.4

 0.9

 1.7

-0.9

-0.4

 1.1

 1.1

 0.3

 0.3

# Req

# Req

#Q

w/ Data

#Q

w/ Data

Avg

%d

Avg

%d

Met?

Met?

Criteria

Criteria

Y

Y

Y

Y

Y

Y

N

N

N

Y

Y

N

N

Y

Y

Y

Y

Y

N

Y

100

100

65

65

-8.85

-8.85

-1.95

-1.95

 7.67

 7.67

 2.27

 2.27

Conf. Limits

Conf. Limits

Lower

Lower

Upper

Upper

100

100

88

88

% Between

% Between

Conf. Limits

Conf. Limits

Flow Rate

Flow Rate

Flow Rate

% 

Complete

% 

Complete

1

1

1

3

3

1

1

1

0

0

0

1

0

0

0

1

0

0

1

1

0

0

7

7

1

1

1

3

3

0

0

0

1

1

1

0

1

1

1

0

1

1

0

0

1

1

10

10

1

1

1

3

3

1

1

1

0

0

0

1

0

0

0

1

0

0

1

1

0

0

7

7

1

1

1

3

3

0

0

0

1

1

1

0

0

0

1

0

1

1

0

0

1

1

8

8

Q1

Q1

Q2

Q2

Q3

Q3

Q4

Q4

Obs / Q

Obs / Q

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 10 of 14

Semi-Annual Flow Rate Audits

PM10

PM2.5

Pollutant:

Pollutant:

1357 (Freeport McMoRan Miami, Inc.)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

Yes

Yes

Year

Year

Region

Region

State

State

Site ID

Site ID

POC

POC

MT

MT

Begin

Date

Begin

Date

End

Date

End

Date

2011

2011

2011

2011

SUMMARY

2011

2011

2011

2011

2011

2011

2011

2011

2011

2011

SUMMARY

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-007-0009

04-007-8000

04-007-8000

SUMMARY

04-003-1005

04-005-1008

04-013-9997

04-013-9997

04-013-9997

04-023-0004

04-023-0004

04-025-2002

04-027-8011

SUMMARY

1

1

2

1

1

1

2

3

1

2

1

1

ID

ID

ID-QA

S

S

S-NC

QA

PN-QA

S

QA

S

S

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

30-JUN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

App A?:

App A?:

2

2

2

6

6

2

2

2

1

2

2

2

2

2

17

17

2

2

2

6

6

2

2

3

1

1

2

2

2

2

17

17

100

100

100

100

100

100

100

100

100

50

100

100

100

100

94

94

-0.8

-1.1

-1.9

-1.3

-1.3

-0.3

 0.3

-0.5

 7.0

-0.2

-1.4

-0.4

 0.0

-0.1

 0.5

 0.5

# Req

# Req

#Q

w/ Data

#Q

w/ Data

Avg

%d

Avg

%d

Met?

Met?

Criteria

Criteria

Y

Y

Y

Y

N

Y

Y

N

Y

Y

N

Y

100

100

67

67

-3.65

-3.65

-12.05

-12.05

 2.39

 2.39

 13.85

 13.85

Conf. Limits

Conf. Limits

Lower

Lower

Upper

Upper

90

90

100

100

% Between

% Between

Conf. Limits

Conf. Limits

Flow Rate

Flow Rate

% 

Complete

% 

Complete

0

0

0

0

0

1

0

1

0

0

1

1

0

0

4

4

3

3

6

12

12

0

1

0

2

1

0

0

1

1

6

6

0

0

0

0

0

1

0

1

0

0

1

1

0

0

4

4

3

3

3

9

9

0

1

1

0

0

0

0

1

1

4

4

Q1

Q1

Q2

Q2

Q3

Q3

Q4

Q4

Obs / Q

Obs / Q

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 11 of 14

Collocation Detail

LEAD

PM10

PM10

PM2.5

Pollutant:

Pollutant:

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

1357 (Freeport McMoRan Miami, Inc.)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

PQAO:

PQAO:

Yes

Yes

Yes

Yes

App A?:

App A?:

App A?:

App A?:

Year

Year

Year

Year

Region

Region

Region

Region

State

State

State

State

Site ID

Site ID

Site ID

Site ID

POC

POC

POC

POC

MT

MT

MT

MT

Begin

Date

Begin

Date

Begin

Date

Begin

Date

End

Date

End

Date

End

Date

End

Date

# Req

# Req

# Req

# Req

# Obs

# Obs

# Obs

# Obs

% 

Complete

% 

Complete

% 

Complete

% 

Complete

CV

CV

CV

CV

2011

2011

2011

2011

2011

2011

2011

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

04-007-1002

04-003-0011

04-007-0008

04-007-8000

04-013-9997

04-023-0004

04-013-9997

1

1

1

1

1

1

1

S

S

S

ID

S-NC

S

S-NC

01-JAN-11

01-JAN-11

01-JAN-11

01-JAN-11

02-JUL-11

03-JAN-11

03-JAN-11

31-DEC-11

31-DEC-11

31-DEC-11

31-DEC-11

29-DEC-11

29-DEC-11

29-JUN-11

30

30

30

30

15

30

14

50

48

55

12

60

53

97

100

100

100

40

100

100

100

 7.65

 14.27

 8.51

 8.37

 14.53

 9.06

 12.84

14129

81102

81102

81102

88101

88101

88101

Parameter

Code

Parameter

Code

Parameter

Code

Parameter

Code

Method

Method

Method

Method

143

143

145

# Valid

# Valid

# Valid

# Valid

40

46

54

12

60

51

91

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 12 of 14

Collocation Summary

LEAD

PM10

PM10

PM2.5

Pollutant:

Pollutant:

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

1357 (Freeport McMoRan Miami, Inc.)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

PQAO:

PQAO:

Yes

Yes

Yes

Yes

App A?:

App A?:

App A?:

App A?:

Year

Year

Year

Year

Region

Region

Region

Region

State

State

State

State

# Req

# Req

# Req

# Req

# Obs

# Obs

# Obs

# Obs

% 

Complete

% 

Complete

% 

Complete

% 

Complete

CV

CV

CV

CV

2011

SUMMARY

2011

SUMMARY

2011

SUMMARY

2011

2011

2011

2011

SUMMARY

09

09

09

09

09

09

09

09

09

09

09

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

AZ

30

60

30

30

30

30

50

103

12

113

97

0

100

100

100

100

40

40

100

100

0

67

67

 7.65

 7.65

 11.00

 11.00

 8.37

 8.37

 12.43

 12.84

 12.21

 12.21

# Sites

# Sites

# Sites

# Sites

2

13

2

6

1

1

# Collocated 

Required

# Collocated 

Required

# Collocated 

Required

# Collocated 

Required

1

2

1

1

1

1

# Actually

Collocated

# Actually

Collocated

# Actually

Collocated

# Actually

Collocated

1

2

1

2

1

0

% Req. Sites 

Collocated

% Req. Sites 

Collocated

% Req. Sites 

Collocated

% Req. Sites 

Collocated

100

100

100

100

100

100

100

100

0

67

67

143

145

170

SUMMARY

Method

Method

Method

Method

# Valid

Obs

# Valid

Obs

# Valid

Obs

# Valid

Obs

40

40

100

100

12

12

111

91

0

202

202

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 13 of 14

Performance Evaluation Program (PEP)

LEAD

PM2.5

Pollutant:

Pollutant:

0053 (Arizona Department Of Environmental Quality)

0053 (Arizona Department Of Environmental Quality)

PQAO:

PQAO:

Yes

Yes

App A?:

App A?:

Year

Year

Region

Region

State

State

# Collocated

PEP Coll.

# Collocated

PEP Coll.

%

Complete

%

Complete

Bias

Bias

2011

SUMMARY

2011

SUMMARY

09

09

09

09

AZ

AZ

AZ

AZ

0

0

0

0

88

88

 10.70

 10.70

# Sites

# Sites

2

6

#PEP

Required

#PEP

Required

1

8

# PEP

Collected

# PEP

Collected

0

7

# Collocated

PEP Req

# Collocated

PEP Req

4

0 -

-

-26.96

-26.96

 5.56

 5.56

Conf. Limits

Conf. Limits

Lower

Lower

Upper

Upper

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

DATA QUALITY INDICATOR REPORT Sep. 21, 2012

Page 14 of 14

Audit Strip Analysis

Pollutant: LEAD PQAO: 0053 (Arizona Department Of Environmental Quality) Yes

Year Region State

2011

SUMMARY

09

09

AZ

AZ

App A?:

100

100

100

100

100

100

100

100

Q1 Q2 Q3 Q4

% Completeness

+/-

+/-

 4.02

 4.02

Bias

100

100

Lab Id Year

1394

1394

ADEQ ATTACHMENT # 3
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

QUICKLOOK ALL PARAMETERS

Report Request ID: 1019005 Report Code: AMP450NC Sep. 13, 2012

Selection Criteria Page 1

User ID: BNE

State County Site Parameter POC City AQCR UAR CBSA CSA

EPA

Region Method Duration Begin Date End Date

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

UATMP CARBONYL

PQAO SELECTIONS

Eastern Research Group

Arizona Department Of Environmental 

Quality

SELECTED OPTIONS

EVENTS PROCESSING

MERGE PDF FILES

Option Type Option Value

EXCLUDE REGIONALLY CONCURRED EVENTS

YES

SORT ORDER

1

2

3

4

5

6

7

Order Column

STATE_CODE

COUNTY_CODE

SITE_ID

PARAMETER_CODE

POC

DATES

EDT_ID

GLOBAL DATES

2001

Start Date End Date

2010

Tribal

Code

APPLICABLE STANDARDS

Standard Description

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

QUICKLOOK ALL PARAMETERS

EXCEPTIONAL DATA TYPES

EDT DESCRIPTION

0

1

2

5

NO EVENTS

EVENTS EXCLUDED

EVENTS INCLUDED

EVENTS WITH CONCURRENCE EXCLUDED

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 2 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

1

1

1

1

1

6

6

6

6

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0329

0329

0329

0329

0053

0053

0053

0053

2003

2004

2005

2006

2003

2004

2005

2006

2007

2008

2009

2010

2003

2004

2005

2006

 47

 52

 48

 25

 47

 52

 48

 25

 14

 29

 30

 29

 45

 52

 48

 25

5.5

4.9

5.6

6.1

6.2

6.8

16.4

6.2

3.7

3.0

7.4

5.6

38.7

34.5

21.3

6.0

5.2

4.7

5.2

4.5

6.0

5.4

6.2

5.8

2.5

1.7

6.4

4.9

29.7

24.6

19.5

6.0

5.0

4.5

4.7

4.2

5.8

4.6

5.8

4.8

2.4

1.5

3.0

2.4

24.9

22.5

18.9

5.7

5.0

4.2

4.6

4.0

5.6

4.4

5.2

4.6

2.0

1.4

2.0

2.3

18.9

21.9

18.6

5.7

3.45*

3.05*

3.30*

3.02*

3.39*

3.09*

3.46*

3.09*

1.57*

.98 

1.61 

1.59 

11.50*

12.32*

12.17*

4.03*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43502

43502

43502

43502

43503

43503

43503

43503

43505

43505

43505

43505

43551

43551

43551

43551

Parameter

Site ID:

Site ID:

04-013-4003

04-013-9997

Phoenix

Phoenix

City:

City:

Maricopa

Maricopa

Unit

County:

County:

33 W TAMARISK AVE, PHOENIX

4530 N 17TH AVENUE

Address:

Address:

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acetone

Acetone

Acetone

Acetone

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

102

202

202

202

102

202

202

202

101

101

101

101

102

202

202

202

Cert N

N

N

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 3 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

30

30

30

30

31

31

31

31

32

32

1

1

1

1

1

1

1

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0053

0053

0053

0053

0053

0053

0053

2007

2008

2009

2010

2007

2008

2009

2010

2007

2009

2001

2002

2003

2004

2005

2006

2007

 30

 61

 59

 16

 3

 7

 6

 5

 36

 44

 131

 122

 56

 56

 49

 51

 30

1.8

1.3

1.2

1.4

1.9

1.3

1.2

1.0

1.9

1.3

22.1

5.6

10.4

15.8

7.6

7.5

5.3

1.8

1.3

1.2

1.2

1.2

1.2

.9

.7

1.8

1.0

22.1

5.2

6.5

14.5

7.1

6.7

5.0

1.6

1.2

1.2

1.0

1.1

1.0

.9

.6

1.6

1.0

21.7

5.1

6.1

14.0

6.5

6.1

4.6

1.4

1.1

1.1

1.0

.9

.8

.4

1.6

1.0

20.4

4.8

5.5

7.6

6.4

5.8

4.3

.90*

.61 

.69 

.81*

1.40*

.83*

.86*

.63*

.81*

.52*

9.73*

3.05*

3.49 

4.88 

4.46*

3.88 

3.22*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43329

43329

43329

43329

43329

43329

43329

43329

43329

43329

43502

43502

43502

43502

43502

43502

43502

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Butyraldehyde & isobutyraldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

102

202

202

202

202

Cert

N

Y

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 4 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

2

2

3

30

30

30

30

31

31

31

31

32

32

1

1

1

1

0053

0053

0053

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0053

0053

0053

0053

2003

2007

2007

2007

2008

2009

2010

2007

2008

2009

2010

2007

2009

2001

2002

2003

2004

 29

 25

 14

 30

 61

 59

 16

 3

 7

 6

 5

 36

 44

 139

 122

 56

 56

7.4

5.7

4.4

6.0

4.4

4.8

3.9

6.3

4.4

4.3

4.0

6.7

4.6

9.8

6.0

7.8

6.8

6.1

4.7

4.2

6.0

4.2

4.6

3.7

4.7

4.2

3.5

2.5

5.7

4.5

8.6

5.8

6.6

6.4

4.8

4.1

4.1

5.8

4.0

4.5

3.1

4.1

3.5

3.2

2.5

5.6

4.1

8.4

5.6

6.6

5.8

4.5

3.9

4.0

5.2

4.0

4.3

2.9

3.5

3.1

2.4

5.1

4.1

8.2

5.6

6.2

5.4

3.09*

3.33*

3.24*

4.04*

2.89 

2.94 

2.58*

5.01*

3.31*

3.28*

2.62*

4.11*

3.02*

3.96*

2.55*

3.52 

3.59 

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

3 HOURS

3 HOURS

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43502

43502

43502

43502

43502

43502

43502

43502

43502

43502

43502

43502

43502

43503

43503

43503

43503

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Formaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

102

202

202

202

202

202

202

202

202

202

202

202

202

202

202

102

202

Cert Y

Y

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 5 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

2

2

3

30

30

30

30

31

31

31

31

32

32

30

0053

0053

0053

0053

0053

0053

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2005

2006

2007

2003

2007

2007

2007

2008

2009

2010

2007

2008

2009

2010

2007

2009

2007

 49

 51

 30

 29

 25

 14

 30

 61

 59

 16

 3

 7

 6

 5

 36

 44

 30

6.2

9.2

6.2

7.8

5.6

5.4

6.4

5.4

6.9

5.3

6.6

5.5

4.5

4.0

8.0

5.8

1.2

6.2

7.8

5.2

7.6

5.4

5.2

5.7

5.0

6.0

4.0

3.7

4.3

4.3

3.2

5.7

5.3

.9

5.2

7.2

4.8

6.4

4.8

4.6

5.7

4.8

6.0

3.7

3.4

4.2

3.7

2.7

5.3

4.7

.8

4.8

6.8

4.4

5.8

4.6

3.4

5.6

4.8

5.4

3.6

4.0

3.2

1.5

4.9

3.8

.8

3.34*

3.65 

3.05*

3.20*

3.24*

3.11*

3.67*

2.98 

3.16 

3.16*

4.55*

3.74*

3.60*

2.59*

3.12*

2.50*

.66*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43503

43504

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Propionaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

102

202

202

202

202

202

202

202

202

202

202

202

202

202

Cert N

Y

Y

Y

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 6 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

30

30

30

31

31

31

31

32

32

6

6

6

6

7

7

7

7

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2008

2009

2010

2007

2008

2009

2010

2007

2009

2007

2008

2009

2010

2007

2008

2009

2010

 61

 59

 16

 3

 7

 6

 5

 36

 44

 25

 52

 57

 61

 5

 5

 7

 5

1.0

1.3

1.0

.9

1.1

.9

.9

1.6

1.5

8.9

7.0

30.9

9.1

3.9

1.6

2.6

3.30

1.0

1.2

1.0

.8

1.0

.8

.5

1.3

1.2

5.1

6.2

9.5

6.8

3.8

1.5

1.9

1.98

1.0

1.2

.9

.7

.9

.7

.5

1.0

1.1

4.5

5.6

3.4

3.8

3.2

1.5

1.6

1.46

1.0

1.2

.8

.8

.7

.4

1.0

1.1

4.4

4.4

2.9

3.8

2.0

1.5

1.4

1.24

.62 

.66 

.67*

.84*

.80*

.72*

.52*

.58*

.67*

2.83*

2.02 

2.26*

2.00 

2.81*

1.48*

1.41*

1.765*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43504

43504

43504

43504

43504

43504

43504

43504

43504

43505

43505

43505

43505

43505

43505

43505

43505

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Propionaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Acrolein - Unverified

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

101

101

101

101

101

101

101

101

Cert

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 7 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

30

30

30

30

31

31

31

31

32

32

30

30

30

30

31

31

31

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2007

2008

2009

2010

2007

2008

2009

2010

2007

2009

2007

2008

2009

2010

2007

2008

2009

 30

 61

 59

 16

 3

 7

 6

 5

 36

 44

 30

 61

 59

 16

 3

 7

 6

.6

.5

.3

.0

.2

.2

.0

.0

.5

.3

1.2

.7

.8

.7

1.3

1.0

.9

.4

.3

.3

.0

.0

.0

.0

.0

.4

.3

1.0

.7

.8

.7

1.3

.9

.6

.2

.3

.2

.0

.0

.0

.0

.0

.3

.0

.8

.7

.8

.6

1.1

.9

.5

.0

.3

.0

.0

.0

.0

.0

.0

.0

.7

.7

.7

.5

.8

.5

.06*

.06 

.03 

.02*

.07*

.05*

.01*

.01*

.05*

.03*

.56*

.45 

.45 

.45*

1.26*

.74*

.59*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43513

43513

43513

43513

43513

43513

43513

43513

43513

43513

43517

43517

43517

43517

43517

43517

43517

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

Cert

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 8 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

31

32

32

30

30

30

30

31

31

31

31

32

32

30

30

30

30

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2010

2007

2009

2007

2008

2009

2010

2007

2008

2009

2010

2007

2009

2007

2008

2009

2010

 5

 36

 44

 30

 61

 59

 16

 3

 7

 6

 5

 36

 44

 30

 61

 59

 16

.5

1.3

1.2

.6

1.2

.5

.5

.7

.7

.5

.4

1.1

.5

1.1

.9

1.3

.6

.5

.8

.7

.6

.7

.5

.4

.7

.6

.4

.4

.8

.5

1.0

.9

1.2

.5

.4

.8

.7

.6

.7

.5

.4

.6

.6

.4

.2

.6

.5

.9

.9

1.2

.5

.2

.7

.7

.5

.6

.4

.4

.4

.4

.2

.5

.5

.9

.9

1.1

.5

.32*

.35*

.23*

.39*

.32 

.30 

.33*

.66*

.47*

.39*

.28*

.29*

.15*

.65*

.49 

.57 

.40*

24 HOUR

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43517

43517

43517

43518

43518

43518

43518

43518

43518

43518

43518

43518

43518

43528

43528

43528

43528

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Hexanaldehyde

Hexanaldehyde

Hexanaldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

Cert

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 9 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

31

31

31

31

32

32

1

1

1

1

1

1

1

2

2

3

30

0329

0329

0329

0329

0329

0329

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0329

2007

2008

2009

2010

2007

2009

2001

2002

2003

2004

2005

2006

2007

2003

2007

2007

2007

 3

 7

 6

 5

 36

 44

 145

 122

 56

 56

 49

 51

 30

 29

 25

 14

 30

1.1

1.0

.8

.8

1.4

1.7

104.7

27.3

28.5

20.7

21.3

26.4

16.8

28.5

17.7

17.4

27.3

.8

.9

.7

.4

1.4

1.4

36.6

22.5

28.5

19.5

18.9

22.2

15.3

28.5

16.2

15.0

23.0

.7

.8

.5

.4

1.3

1.3

29.4

19.5

25.2

18.6

15.3

22.2

14.7

25.2

15.6

13.5

21.8

.7

.5

.3

1.2

1.2

28.8

19.2

24.6

18.0

14.4

21.3

14.4

24.3

14.7

13.2

19.2

.84*

.67*

.56*

.44*

.81*

.73*

11.96*

8.83*

11.23 

10.29 

10.00*

11.42 

9.68*

10.59*

9.84*

10.48*

13.58*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43528

43528

43528

43528

43528

43528

43551

43551

43551

43551

43551

43551

43551

43551

43551

43551

43551

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

102

202

202

202

202

102

202

202

202

Cert

N

Y

Y

Y

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 10 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

30

30

30

31

31

31

31

32

32

30

30

30

30

31

31

31

31

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2008

2009

2010

2007

2008

2009

2010

2007

2009

2007

2008

2009

2010

2007

2008

2009

2010

 61

 59

 16

 3

 7

 6

 5

 36

 44

 30

 61

 59

 16

 3

 7

 6

 5

21.5

20.0

15.3

27.9

21.1

14.2

11.8

25.5

16.2

1.4

.9

.9

.8

1.1

.8

.8

.5

20.0

18.3

14.4

15.1

18.5

13.0

9.0

25.5

14.0

1.1

.8

.9

.6

.8

.7

.7

.5

18.4

16.7

12.5

12.6

12.8

12.8

7.8

20.7

13.8

1.1

.8

.9

.6

.7

.7

.7

.4

18.4

16.4

12.1

12.2

11.4

4.7

17.2

12.8

1.1

.8

.8

.6

.7

.7

.2

10.19 

10.45 

10.23*

18.54*

12.99*

11.80*

7.43*

13.24*

9.20*

.66*

.46 

.45 

.46*

.86*

.62*

.64*

.35*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43551

43551

43551

43551

43551

43551

43551

43551

43551

45501

45501

45501

45501

45501

45501

45501

45501

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Acetone

Benzaldehyde

Benzaldehyde

Benzaldehyde

Benzaldehyde

Benzaldehyde

Benzaldehyde

Benzaldehyde

Benzaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

Cert

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 11 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

32

32

30

30

30

30

31

31

31

31

32

32

30

30

30

30

31

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

0329

2007

2009

2007

2008

2009

2010

2007

2008

2009

2010

2007

2009

2007

2008

2009

2010

2007

 36

 44

 30

 61

 59

 16

 3

 7

 6

 5

 36

 44

 30

 61

 58

 16

 3

1.1

.9

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

1.1

1.5

2.5

1.8

1.1

1.1

.7

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

1.0

1.4

1.6

.8

.8

1.1

.7

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

1.0

1.1

1.4

.7

.6

.9

.7

.0

.0

.0

.0

.0

.0

.0

.0

.0

.8

1.0

1.1

.6

.45*

.29*

.04*

.04 

.01 

.02*

.04*

.04*

.01*

.01*

.04*

.01*

.57*

.50 

.66 

.50*

.84*

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45501

45501

45503

45503

45503

45503

45503

45503

45503

45503

45503

45503

45504

45504

45504

45504

45504

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Benzaldehyde

Benzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

Tolualdehydes

Tolualdehydes

Tolualdehydes

Tolualdehydes

Tolualdehydes

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

202

Cert

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 12 of 14

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

31

31

31

32

32

1

1

1

1

1

1

1

1

1

0329

0329

0329

0329

0329

0053

0053

0053

0053

0053

0053

0053

0053

0053

2008

2009

2010

2007

2009

2001

2002

2003

2001

2002

2003

2001

2002

2003

 7

 6

 5

 36

 44

 60

 54

 12

 60

 54

 13

 60

 54

 12

.8

1.2

.5

1.5

1.4

38.7

8.9

8.9

61.2

2.8

4.6

33.3

12.9

8.4

.8

.6

.0

1.2

1.1

22.0

6.8

6.7

41.0

2.6

2.8

31.2

9.0

6.0

.7

.6

.0

1.1

1.1

19.6

6.5

6.5

15.8

2.6

2.0

16.2

8.7

6.0

.6

.5

.0

1.0

1.0

12.4

6.3

4.8

13.4

2.4

2.0

14.4

7.5

5.7

.61*

.64*

.12*

.55*

.62*

4.50*

3.95*

4.43*

4.28*

1.51*

1.99*

7.22*

5.18*

4.95*

24 HOUR

24 HOUR

24 HOUR

3 HOURS

3 HOURS

3 HOURS

3 HOURS

24 HOUR

3 HOURS

3 HOURS

24 HOUR

3 HOURS

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45504

45504

45504

45504

45504

43502

43502

43502

43503

43503

43503

43551

43551

43551

Parameter

Site ID:

Site ID:

04-013-9997

04-021-8001

Phoenix

Queen Valley

City:

City:

Maricopa

Pinal

Unit

County:

County:

4530 N 17TH AVENUE

10 S QUEEN ANN QUEEN VALLEY

Address:

Address:

Tolualdehydes

Tolualdehydes

Tolualdehydes

Tolualdehydes

Tolualdehydes

Formaldehyde

Formaldehyde

Formaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Acetone

Acetone

Acetone

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

102

202

202

102

202

202

102

Cert

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 13 of 14

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43329

43502

43502

43503

43503

43504

43505

43513

43517

43518

43528

43551

43551

45501

45503

45504

202

102

202

102

202

202

101

202

202

202

202

102

202

202

202

202

SILICA-DNPH-CART-KI O3 SCRUB

CARTRIDGE-DNPH-ON-SILICA

SILICA-DNPH-CART-KI O3 SCRUB

CARTRIDGE-DNPH-ON-SILICA

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

CANISTER SUBAMBIENT PRESSURE

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

DNPH-COATED CARTRIDGES

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

MULTI DETECTOR GC

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC (TO-14)

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

ADEQ ATTACHMENT # 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

Sep. 13, 2012

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 14 of 14

PQAOS USED IN THIS REPORT

PQAO AGENCY DESCRIPTION

0053

0329

Arizona Department Of Environmental Quality

Eastern Research Group

ADEQ ATTACHMENT # 4