Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

KW-2

Page 5 of 5

HESI102413
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: KWIK SEAL ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: KWIK SEAL ADDITIVE

Synonyms: None

Chemical Family: Blend of natural fibers

Application: Loss Circulation Material

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

KWIK SEAL ADDITIVE

Page 1 of 5

HESI102414
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown

Odor: Woody

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.3

KWIK SEAL ADDITIVE

Page 2 of 5

HESI102415
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 15.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

KWIK SEAL ADDITIVE

Page 3 of 5

HESI102416
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

KWIK SEAL ADDITIVE

Page 4 of 5

HESI102417
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

KWIK SEAL ADDITIVE

Page 5 of 5

HESI102418
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LAP-1

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LAP-1

Synonyms: None

Chemical Family: Polymer

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyvinyl alcohol 9002-89-5 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

LAP-1

Page 1 of 5

HESI102419
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to off white

Odor: Mild

pH: 5 - 7

Specific Gravity @ 20 C (Water=1): 1.32

LAP-1

Page 2 of 5

HESI102420
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 41.5

Bulk Density @ 20 C (lbs/ft3): 50

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 5

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): >600

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains polyvinyl alcohol (PVA). PVA has produced local cancers in experimental

animals when PVA sponges were implanted under the skin. Implanted powder,

however, did not produce any local cancers.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

LAP-1

Page 3 of 5

HESI102421
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

LAP-1

Page 4 of 5

HESI102422
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LAP-1

Page 5 of 5

HESI102423
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-5M

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-5M

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Petroleum distillate 64741-44-2 30 - 60% Not applicable Not applicable

Guar gum derivative 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause headache, dizziness, and other central nervous system effects. May

cause eye, skin, and respiratory irritation. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-5M

Page 1 of 6

HESI102424
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 170

Flash Point/Range (C): 77

Flash Point Method: TCC

Autoignition Temperature (F): > 431

Autoignition Temperature (C): > 225

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 6

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from heat, sparks, and open flames.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Gel

Color: Yellowish

Odor: Hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): Not Determined

LGC-5M

Page 2 of 6

HESI102425
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 400-700

Boiling Point/Range (C): 204-371

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 3.65

Vapor Density (Air=1): 4.25

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

LGC-5M

Page 3 of 6

HESI102426
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Distillates)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

LGC-5M

Page 4 of 6

HESI102427
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

LGC-5M

Page 5 of 6

HESI102428
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-5M

Page 6 of 6

HESI102429
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-IV WITH DIESEL

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-IV WITH DIESEL

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 30 - 60% Not applicable Not applicable

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-IV WITH DIESEL

Page 1 of 6

HESI102430
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 150

Flash Point/Range (C): 65

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter. In high concentrations, supplied air

respirator or a self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-IV WITH DIESEL

Page 2 of 6

HESI102431
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Gel

Color: Yellowish

Odor: Diesel

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.62

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 300

Boiling Point/Range (C): 148

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

LGC-IV WITH DIESEL

Page 3 of 6

HESI102432
Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals. Limited studies on oils that are very active carcinogens have

shown washing the animals' skin with soap and water between applications greatly

decreases the incidence of tumors. In light of these studies, good personal hygiene

is essential with the use of this product.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Diesel Fuel Solution, Combustible Liquid, NA1993, III

LGC-IV WITH DIESEL

Page 4 of 6

HESI102433
Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

LGC-IV WITH DIESEL

Page 5 of 6

HESI102434
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-IV WITH DIESEL

Page 6 of 6

HESI102435
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LIME , HYDRATED

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LIME , HYDRATED

Synonyms: None

Chemical Family: Inorganic

Application: Component

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium hydroxide 1305-62-0 60 - 100% 5 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LIME , HYDRATED

Page 1 of 5

HESI102436
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from acids. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 12.2

Specific Gravity @ 20 C (Water=1): 2.24

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 75

LIME , HYDRATED

Page 2 of 5

HESI102437
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.2

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 74.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns on prolonged contact.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7340 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

LIME , HYDRATED

Page 3 of 5

HESI102438
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

LIME , HYDRATED

Page 4 of 5

HESI102439
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LIME , HYDRATED

Page 5 of 5

HESI102440
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LIME

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LIME

Synonyms: None

Chemical Family: Inorganic

Application: pH Control

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium hydroxide 1305-62-0 60 - 100% 5 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LIME

Page 1 of 5

HESI102441
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not Determined

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from acids. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 12.2

Specific Gravity @ 20 C (Water=1): 2.24

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 75

LIME

Page 2 of 5

HESI102442
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.2

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 74.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns on prolonged contact.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7340 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

LIME

Page 3 of 5

HESI102443
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 100-500 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM96: 478,520 ppm (Mysidopsis bahia) SPP @ 8 ppb

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Empty container completely. Transport with all closures in place. Return for reuse or

dispose in a sanitary landfill according to national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

LIME

Page 4 of 5

HESI102444
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LIME

Page 5 of 5

HESI102445
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LOSURF-259 SURFACTANT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LOSURF-259 SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 5 - 10% 5 mg/m3 5 mg/m3

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May cause allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage.

LOSURF-259 SURFACTANT

Page 1 of 6

HESI102446
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 63

Flash Point/Range (C): 17

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.8

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves. Polyvinylchloride gloves.

Butyl rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

LOSURF-259 SURFACTANT

Page 2 of 6

HESI102447
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.92

Density @ 20 C (lbs./gallon): 7.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 198

Boiling Point/Range (C): 92

Freezing Point/Range (F): -50

Freezing Point/Range (C): -45.5

Vapor Pressure @ 20 C (mmHg): 83

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): 1.9

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns. May cause an allergic skin reaction.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

LOSURF-259 SURFACTANT

Page 3 of 6

HESI102448
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10-33 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, II, (17.2 C)

(Contains Isopropanol, Heavy Aromatic Naphtha)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, UN1993, II, (17.2 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II

LOSURF-259 SURFACTANT

Page 4 of 6

HESI102449
Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (17.2 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 14,705 Pounds based on Naphthalene (CAS: 91-

20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

LOSURF-259 SURFACTANT

Page 5 of 6

HESI102450
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LOSURF-259 SURFACTANT

Page 6 of 6

HESI102451
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LoSurf-300D

Revision Date: 06-May-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LoSurf-300D

Synonyms: None

Chemical Family: Blend

Application: Non-ionic Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethanol 64-17-5 30 - 60% 1000 ppm 1000 ppm

Heavy aromatic petroleum

naphtha

64742-94-5 10 - 30% 5 mg/m3 5 mg/m3

Naphthalene 91-20-3 1 - 5% 10 ppm 10 ppm

1,2,4 Trimethylbenzene 95-63-6 0 - 1% 25 ppm Not applicable

Poly(oxy-1,2-ethanediyl),

alpha-(4-nonylphenyl)-

omega-hydroxy-, branched

127087-87-0 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

LoSurf-300D

Page 1 of 6

HESI102452
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 57

Flash Point/Range (C): 14

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 3.3

Flammability Limits in Air - Upper (%): 19

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0 , PPE: H

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing

mist. Wash hands after use. Launder contaminated clothing before reuse. Ground

and bond containers when transferring from one container to another.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

Store in a cool well ventilated area. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

LoSurf-300D

Page 2 of 6

HESI102453
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Butyl rubber gloves. Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 7

Specific Gravity @ 20 C (Water=1): .903

Density @ 20 C (lbs./gallon): 7.53

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 173.1

Boiling Point/Range (C): 78.4

Freezing Point/Range (F): -76.9

Freezing Point/Range (C): -60.51

Vapor Pressure @ 20 C (mmHg): 40 (etoh)

Vapor Density (Air=1): > 10

Percent Volatiles: 55-65

Evaporation Rate (Butyl Acetate=1): < 3.3

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

LoSurf-300D

Page 3 of 6

HESI102454
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity

The International Agency for Research on Cancer (IARC) has evaluated naphthalene

and determined it to be a possible carcinogen to humans (Group 2B, based on

sufficient evidence in experimental animals and inadequate evidence in humans).

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

LoSurf-300D

Page 4 of 6

HESI102455
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol, Heavy Aromatic Naphtha), 3, II, (14 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Ethanol, Heavy Aromatic Naphtha), 3, UN1993, II, (14 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol, Heavy Aromatic Naphtha), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Ethanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol, Heavy Aromatic Naphtha), 3, II, (14 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

LoSurf-300D

Page 5 of 6

HESI102456
EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

1,2,4-Trimethylbenzene//95-63-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1122 Gallons based on Naphthalene (CAS: 91-20-

3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B2 Flammable Liquids

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LoSurf-300D

Page 6 of 6

HESI102457
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-66

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-66

Synonyms: None

Chemical Family: Inorganic acid

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum chloride 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-66

Page 1 of 6

HESI102458
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator with a dust/mist filter.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Odorless

pH: 1.5

MO-66

Page 2 of 6

HESI102459
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.28

Density @ 20 C (lbs./gallon): 10.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 230

Boiling Point/Range (C): 110

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 48

Vapor Density (Air=1): Not Determined

Percent Volatiles: 49.3

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Hydrogen chloride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

MO-66

Page 3 of 6

HESI102460
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Aluminum Chloride Solution, 8, UN2581, III

NAERG 154

Canadian TDG

Aluminum Chloride Solution, 8, UN2581, III

ADR

UN2581,Aluminum Chloride Solution, 8, III

Air Transportation

ICAO/IATA

UN2581,Aluminum Chloride Solution, 8, III

Sea Transportation

IMDG

UN2581,Aluminum Chloride Solution, 8, III

MO-66

Page 4 of 6

HESI102461
EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

MO-66

Page 5 of 6

HESI102462
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-66

Page 6 of 6

HESI102463
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-75 OIL GELLING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-75 OIL GELLING AGENT

Synonyms: None

Chemical Family: Phosphate Ester Salt

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phosphate ester 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-75 OIL GELLING AGENT

Page 1 of 6

HESI102464
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless to pale yellow

Odor: Pungent

pH: 3.5

MO-75 OIL GELLING AGENT

Page 2 of 6

HESI102465
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.09

Density @ 20 C (lbs./gallon): 9.09

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of phosphorus. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation Causes redness and tearing. May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

MO-75 OIL GELLING AGENT

Page 3 of 6

HESI102466
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Acidic, Organic, N.O.S., 8, UN3265, III

(Contains Phosphate Esters)

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, UN3265, III

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III

(Contains Phosphate Esters Solution)

MO-75 OIL GELLING AGENT

Page 4 of 6

HESI102467
Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

MO-75 OIL GELLING AGENT

Page 5 of 6

HESI102468
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-75 OIL GELLING AGENT

Page 6 of 6

HESI102469
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-76 ACTIVATOR

Revision Date: 31-Mar-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-76 ACTIVATOR

Synonyms: None

Chemical Family: Blend

Application: Activator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum chloride 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-76 ACTIVATOR

Page 1 of 6

HESI102470
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 76

Flash Point/Range (C): 24

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Neutralize to pH of

6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter. In high concentrations, supplied air

respirator or a self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MO-76 ACTIVATOR

Page 2 of 6

HESI102471
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear brown

Odor: Alcohol

pH: 3-4

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.19

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 205

Boiling Point/Range (C): 96

Freezing Point/Range (F): -10

Freezing Point/Range (C): -23

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 14

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Causes severe respiratory irritation.

Skin Contact Causes burns. May be absorbed through the skin and produce effects similar to

those caused by inhalation and/or ingestion.

Eye Contact May cause severe eye irritation. May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause headache, dizziness,

nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

MO-76 ACTIVATOR

Page 3 of 6

HESI102472
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Aluminum Chloride), 3, (8), III, (24 C)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Aluminum Chloride), 3, (8), UN2924, III, (24 C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Aluminum Chloride), 3, (8), III

MO-76 ACTIVATOR

Page 4 of 6

HESI102473
Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Isopropanol, Aluminum Chloride Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Aluminum Chloride), 3, (8), III, (24 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

MO-76 ACTIVATOR

Page 5 of 6

HESI102474
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-76 ACTIVATOR

Page 6 of 6

HESI102475
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-86

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-86

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dibutylaminoethanol 102-81-8 10 - 30% 0.5 ppm Not applicable

Ferric sulfate 10028-22-5 30 - 60% 1 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-86

Page 1 of 6

HESI102476
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water spray or fog may be used to knock down corrosive vapor cloud. Water may

be applied to the sides of the containers exposed to flames provided the water does

not come in contact with the tank contents.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Brown

MO-86

Page 2 of 6

HESI102477
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Amine

pH: 1.75

Specific Gravity @ 20 C (Water=1): 1.3508

Density @ 20 C (lbs./gallon): 11.27

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): < 1

Vapor Density (Air=1): > 1

Percent Volatiles: 66

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of phosphorus. Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

MO-86

Page 3 of 6

HESI102478
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Contains Ferric Sulfate), 8, III

NAERG 154

Canadian TDG

Corrosive Liquid, Acidic, Inorganic, N.O.S.(Contains Ferric Sulfate), 8, UN3264, III

ADR

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Contains Ferric Sulfate), 8, III

Air Transportation

ICAO/IATA

MO-86

Page 4 of 6

HESI102479
UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S., 8, III

(Contains Ferric Sulfate Solution)

Sea Transportation

IMDG

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Contains Ferric Sulfate), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

MO-86

Page 5 of 6

HESI102480
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-86

Page 6 of 6

HESI102481
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-86M

Revision Date: 08-Apr-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-86M

Synonyms: None

Chemical Family: Amine

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dibutylaminoethanol 102-81-8 5 - 10% 0.5 ppm Not applicable

Amine 5 - 10% 2 ppm 10 ppm (S)

Ferric sulfate 10028-22-5 30 - 60% 1 mg/m3 Not applicable

Alkyl Amine Blend in a Metal

Salt Solution

HMIRC5871 Jan04 60 - 100% C; R34 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-86M

Page 1 of 6

HESI102482
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Brown

Odor: Slight

pH: 1.7 (100%)

MO-86M

Page 2 of 6

HESI102483
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.351

Density @ 20 C (lbs./gallon): 11.274

Bulk Density @ 20 C (lbs/ft3): 84

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): < 1

Vapor Density (Air=1): >1

Percent Volatiles: < 30

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of phosphorus. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

MO-86M

Page 3 of 6

HESI102484
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2922, Corrosive Liquid, Toxic, N.O.S.(Contains Ferric Sulfate, Dibutylaminoethanol), 8, (6.1), III

RQ (Ferric Sulfate - 1281 kg)

NAERG 154

Canadian TDG

Corrosive Liquid, Toxic, N.O.S.(Contains Ferric Sulfate, Dibutylaminoethanol), 8, (6.1), UN2922, III

ADR

UN2922, Corrosive Liquid, Toxic, N.O.S.(Contains Ferric Sulfate, Dibutylaminoethanol), 8, (6.1), III

Air Transportation

ICAO/IATA

UN2922, Corrosive Liquid, Toxic, N.O.S., 8, (6.1), III

MO-86M

Page 4 of 6

HESI102485
(Contains Ferric Sulfate, Dibutylaminoethanol Solution)

RQ (Ferric Sulfate - 1281 kg)

Sea Transportation

IMDG

UN2922, Corrosive Liquid, Toxic, N.O.S.(Contains Ferric Sulfate, Dibutylaminoethanol), 8, (6.1), III

RQ (Ferric Sulfate - 1281 kg)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 250 Gallons based on Ferric Sulfate (10028-22-5).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

MO-86M

Page 5 of 6

HESI102486
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-86M

Page 6 of 6

HESI102487
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-IV LIQUID BREAKER

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-IV LIQUID BREAKER

Synonyms: None

Chemical Family: Organic hydrocarbon

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Magnesium oxide 1309-48-4 30 - 60% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

MO-IV LIQUID BREAKER

Page 1 of 6

HESI102488
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: TAG

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 6.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

MO-IV LIQUID BREAKER

Page 2 of 6

HESI102489
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Milky white

Odor: Paraffinic

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.085

Density @ 20 C (lbs./gallon): 9.04

Bulk Density @ 20 C (lbs/ft3): 67.6

Boiling Point/Range (F): 348-375

Boiling Point/Range (C): 176 - 191

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 4.5

Vapor Density (Air=1): 5.51

Percent Volatiles: 65

Evaporation Rate (Butyl Acetate=1): 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperature over 200 F (93 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause chemical pneumonia.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

MO-IV LIQUID BREAKER

Page 3 of 6

HESI102490
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

MO-IV LIQUID BREAKER

Page 4 of 6

HESI102491
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

MO-IV LIQUID BREAKER

Page 5 of 6

HESI102492
***END OF MSDS***

MO-IV LIQUID BREAKER

Page 6 of 6

HESI102493
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-V

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-V

Synonyms: None

Chemical Family: Metal oxide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Inorganic particulate 30 - 60% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

MO-V

Page 1 of 5

HESI102500
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location. Store in a cool well ventilated area. Product has a shelf

life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Odorless

MO-V

Page 2 of 5

HESI102501
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 10.5

Specific Gravity @ 20 C (Water=1): 3.81

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 20 - 40

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 40.32

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Oxides of nitrogen. Metal oxides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

MO-V

Page 3 of 5

HESI102502
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

MO-V

Page 4 of 5

HESI102503
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-V

Page 5 of 5

HESI102504
MATERIAL SAFETY DATA SHEET

Product Trade Name: MonoProp ProppantRevision Date: 20-Aug-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MonoProp ProppantSynonyms: NoneChemical Family: PolymerApplication: ProppantManufacturer/Supplier Halliburton Energy Services

P.O. Box 1431Duncan, Oklahoma 73536-0431Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Nylon fibers 25038-54-4 10 - 30% Not applicable Not applicable

Titanium dioxide 13463-67-7 1 - 5% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation Not a hazard under normal use conditions.Skin If molten polymer gets on skin, cool rapidly with cold water. Do not attempt to peel

polymer from skin. Seek immediate medical attention. Wash with soap and water.

Get medical attention if irritation persists.

E

yes In case of contact, immediatel

y flush e

yes with 

plent

y of water for at least 15 minutes
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedFlash Point/Range (C): Not DeterminedFlash Point Method: Not DeterminedAutoignition Temperature (F): > 752Autoignition Temperature (C): > 400Flammability Limits in Air - Lower (%): Not DeterminedFlammability Limits in Air - Upper (%): Not DeterminedFire Extinguishing Media Foam. Water.Special Exposure Hazards Decomposition in fire may produce toxic gases.Special Protective Equipment forFire-Fighters

Full protective clothing and approved self-contained breathing apparatus required forfire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0HMIS Ratings: Health 0, Flammability 1, Physical Hazard 0 , PPE: B

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental PrecautionaryMeasures

None known.

Procedure for Cleaning /Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, EuropeanStandard EN 149, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, shouldbe performed by an Industrial Hygienist or other qualified professional.Not normally necessary.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: PelletColor: GrayOdor: SlightpH: Not DeterminedSpecific Gravity @ 20 C (Water=1): 1.12 - 1.15Density @ 20 C (lbs./gallon): Not DeterminedBulk Density @ 20 C (lbs/ft3): Not DeterminedBoiling Point/Range (F): Not DeterminedBoiling Point/Range (C): Not DeterminedFreezing Point/Range (F): Not DeterminedFreezing Point/Range (C): Not DeterminedVapor Pressure @ 20 C (mmHg): Not DeterminedVapor Density (Air=1): Not DeterminedPercent Volatiles: Not DeterminedEvaporation Rate (Butyl Acetate=1): Not DeterminedSolubility in Water (g/100ml): InsolubleSolubility in Solvents (g/100ml): Not DeterminedVOCs (lbs./gallon): Not DeterminedViscosity, Dynamic @ 20 C (centipoise): Not DeterminedViscosity, Kinematic @ 20 C (centistrokes): Not DeterminedPartition Coefficient/n-Octanol/Water: Not DeterminedMolecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: StableHazardous Polymerization: Will Not OccurConditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Strong acids.

Hazardous DecompositionProducts

Carbon monoxide and carbon dioxide. Hydrogen cyanide. Ammonia.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.Inhalation None known.Skin Contact None known.Eye Contact May cause mechanical irritation to eye.
Oral Toxicity: LD50: > 15000 mg/kg (Rat)

Dermal Toxicity: Not determinedInhalation Toxicity: Not determinedPrimary Irritation Effect: Non-irritatingCarcinogenicity Not determinedGenotoxicity: Not determinedReproductive /Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determinedPersistence/Degradability Not determinedBio-accumulation Not Determined Ecotoxicological Information

Acute Fish Toxicity: Not determinedAcute Crustaceans Toxicity:Not determinedAcute Algae Toxicity: Not determined

Chemical Fate Information Not determinedOther Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restrictedCanadian TDG
Sea Transportation

IMDG Not restrictedOther Shipping InformationLabels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.EPA SARA Title III ExtremelyHazardous Substances

Not applicable

EPA SARA (311,312) HazardClass

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/SuperfundReportable Spill Quantity

Not applicable.

EPA RCRA Hazardous WasteClassification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste asdefined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.MA Right-to-Know Law One or more components listed.NJ Right-to-Know Law One or more components listed.PA Right-to-Know Law One or more components listed.Canadian RegulationsCanadian DSL Inventory All components listed on inventory.WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDSNot applicableAdditional Information For additional information on the use of this product, contact your local Halliburton

representative.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including themanufacturer and other third party sources. The information may not be valid underall conditions nor if this material is used in combination with other materials or in anyprocess. Final determination of suitability of any material is the sole responsibility ofthe user.

***END OF MSDS***
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MURIATIC ACID

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MURIATIC ACID

Synonyms: None

Chemical Family: Inorganic acid

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrochloric acid 7647-01-0 30 - 60% 2 ppm 5 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MURIATIC ACID

Page 1 of 6

HESI102505
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May form explosive mixtures with strong alkalis. Decomposition in fire may produce

toxic gases. Reaction with steel and certain other metals generates flammable

hydrogen gas. Use water spray to cool fire exposed surfaces. Do not allow runoff to

enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 0

HMIS Ratings: Health 3, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize with lime slurry, limestone, or soda ash. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MURIATIC ACID

Page 2 of 6

HESI102506
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless to pale yellow

Odor: Pungent acrid

pH: 0.8

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.68

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 183

Boiling Point/Range (C): 83

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 25

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 36.46

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with alkalis. Avoid contact

with metals such as aluminum, tin, lead, brass, bronze, copper, and zinc.

Incompatibility (Materials to

Avoid)

Strong alkalis. Sulfides.

Hazardous Decomposition

Products

Flammable hydrogen gas. Chlorine. Hydrogen sulfide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

MURIATIC ACID

Page 3 of 6

HESI102507
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: LC50: 3124 ppm/1 hr. (Rat)

Primary Irritation Effect: Draize Rating (Skin): 8.0/8.0 (Rabbit) Corrosive Draize Rating (Eye): 110/110

(Rabbit) Corrosive

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1789,Hydrochloric Acid Solution, 8, II

NAERG 157

Canadian TDG

Hydrochloric Acid Solution, 8, UN1789, II

ADR

UN1789,Hydrochloric Acid Solution, 8, II

Air Transportation

MURIATIC ACID

Page 4 of 6

HESI102508
ICAO/IATA

UN1789,Hydrochloric Acid Solution, 8, II

Sea Transportation

IMDG

UN1789,Hydrochloric Acid Solution, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1640 Gallons based on Hydrochloric acid (CAS:

7647-01-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

MURIATIC ACID

Page 5 of 6

HESI102509
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MURIATIC ACID

Page 6 of 6

HESI102510
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 1/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

1. Substance/preparation and company identification 

Company 24 Hour Emergency Response Information 

BASF CORPORATION 

100 Campus Drive 

Florham Park, NJ 07932, USA 

CHEMTREC: 1-800-424-9300 

BASF HOTLINE: 1-800-832-HELP 

Molecular formula: CHO(CH2)3CHO 

Molecular weight: 100 g/mol 

Chemical family: dialdehydes 

Synonyms: GLUTARALDEHYDE 

2. Composition/information on ingredients 

CAS Number Content (W/W) Chemical name

7732-18-5 75.0 % Water 

111-30-8 25.0 % glutaral 

3. Hazard identification 

Emergency overview

DANGER: CAUSES IRREVERSIBLE EYE DAMAGE. 

HARMFUL IF INHALED. 

CAUSES ASTHMATIC SIGNS AND SYMPTOMS IN HYPER-REACTIVE INDIVIDUALS. 

HARMFUL IF SWALLOWED. 

HARMFUL IF ABSORBED THROUGH SKIN. 

CAUSES SKIN IRRITATION. 

MAY CAUSE ALLERGIC SKIN REACTION. 

Do not get in eyes, on skin, or on clothing. 

Avoid inhalation of mists/vapours. 

Provide local exhaust ventilation to control vapours/mists. 

Wear NIOSH-certified chemical goggles. 

Wear chemical resistant protective gloves. 

Wear protective clothing. 

Eye wash fountains and safety showers must be easily accessible. 

Potential health effects

Primary routes of exposure

Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry 

for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. 

Acute toxicity:

Ingestion may cause moderate to severe gastrointestinal irritation and ulceration including nausea and 

vomiting and pain. Inhalation of aerosols may cause respiratory tract irritation and pulmonary inflammation. 

HESI102511
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 2/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

Irritation:

Causes burns. Risk of serious damage to eyes. 

Sensitization:

May cause sensitization by inhalation and skin contact. 

Medical conditions aggravated by overexposure: 

Contact may aggravate pulmonary disorders. 

Potential environmental effects

Aquatic toxicity: 

Acutely toxic for aquatic organisms. 

Depending on local conditions and existing concentrations, disturbances in the biodegradation process of 

activated sludge are possible. 

4. First-aid measures 

General advice: 

Remove contaminated clothing. 

If inhaled: 

Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. 

Immediate medical attention required. 

If on skin: 

Wash affected areas thoroughly with soap and water. Immediate medical attention required. 

If in eyes: 

In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate 

medical attention required. 

If swallowed: 

Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. 

Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. 

Note to physician

Treatment: Treat according to symptoms (decontamination, vital functions), no known 

specific antidote, administer corticosteroid dose aerosol to prevent pulmonary 

odema. 

5. Fire-fighting measures 

Flash point: Not applicable 

Autoignition: > 275 °C (DIN 51794) 

Suitable extinguishing media: 

water, carbon dioxide, dry extinguishing media, foam 

Hazards during fire-fighting: 

toxic gases/vapours 

Protective equipment for fire-fighting:

Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. 

NFPA Hazard codes:

Health : 3 Fire: 1 Reactivity: 0 Special: 

HESI102512
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 3/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

6. Accidental release measures 

Personal precautions:

Use personal protective clothing. 

Environmental precautions:

Do not discharge into drains/surface waters/groundwater. 

Cleanup:

Spills should be contained, solidified, and placed in suitable containers for disposal. 

For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder). Dispose 

of absorbed material in accordance with regulations. 

For large amounts: Pump off product. 

Further information: 

Pack in tightly closed containers for disposal. 

7. Handling and storage 

Handling

General advice:

Keep away from sources of ignition - No smoking. Handle in accordance with good industrial hygiene and 

safety practice. Keep container tightly sealed. 

Storage

General advice:

Store protected against freezing. 

Storage incompatibility: 

General: Segregate from acids, alkalies or combustible materials. Segregate from oxidizing agents. 

Segregate from incompatible substances. 

8. Exposure controls and personal protection 

Components with workplace control parameters

glutaral 

ACGIH CLV 0.05 ppm ; 

Advice on system design:

Provide local exhaust ventilation to control vapours/mists. 

Personal protective equipment

Respiratory protection:

Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. 

Hand protection:

Chemical resistant protective gloves 

Eye protection: 

Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. 

Body protection: 

Body protection must be chosen based on level of activity and exposure. 

HESI102513
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 4/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

General safety and hygiene measures: 

Eye wash fountains and safety showers must be easily accessible. Wear protective clothing as necessary to 

prevent contact. Avoid inhalation of vapours/mists. Keep away from food, drink and animal feeding stuffs. 

Avoid contact with skin and eyes. Remove contaminated clothing. Handle in accordance with good industrial 

hygiene and safety practice. 

9. Physical and chemical properties 

Form: liquid 

Odour: characteristic

Colour: yellow

pH value: approx. 3.6 

Freezing point: approx. -5 °C ( 1 ATM) 

Boiling point: > 100 °C ( 1 ATM) 

Vapour pressure: approx. 17.5 

mmHg 

( 20 °C) The product has not been tested. 

The statement has been derived from the 

properties of the individual components. 

Density: 1.06 g/cm3 ( 20 °C) 

Relative density: 1.06 ( 20 °C) 

Partitioning coefficient noctanol/water (log Pow): -0.36 ( 23 °C) (OECD Guideline 107)

Solubility in water: soluble 

10. Stability and reactivity 

Substances to avoid:

acids, bases 

Hazardous reactions:

The product is chemically stable. 

Decomposition products: 

Hazardous decomposition products: 

carbon monoxide, carbon dioxide 

Thermal decomposition:

No data available. 

Corrosion to metals: 

Corrosive effect on metals. 

11. Toxicological information 

Acute toxicity

Oral: 

LD50/rat: approx. 320 mg/kg (BASF-Test) 

 

Inhalation: 

LC50/rat: > 0.28 - < 0.39 mg/l / 4 h 

The data refer to a diluted watery solution of the substance. 

 

rat: / 1 h(IRT) 

No Mortality within the stated exposition time as shown in animal studies, however, deaths occurred after 

longer exposure. 

HESI102514
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 5/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

Dermal: 

LD50/rat: > 2,000 mg/kg 

The data refer to a diluted watery solution of the substance. 

 

Skin irritation: 

rabbit: Irritant. (Draize test) 

 

Eye irritation : 

rabbit: Severely irritating. (Draize test) 

 

Sensitization: 

Open epicutaneous test (OET)/guinea pig: sensitizing 

The data refer to a diluted watery solution of the substance. 

Literature data. 

Chronic toxicity 

Genetic toxicity: 

The substance was mutagenic in various test systems with bacterias and cell cultures; however, these 

results could not be confirmed in tests with mammals. 

Carcinogenicity: 

In long-term animal studies in which the substance was given in the drinking water in high concentrations, a 

carcinogenic effect was not observed. 

Reproductive toxicity: 

Animal studies gave no indication of a fertility impairing effect at doses which were not toxic to the parental 

animals. 

Developmental toxicity/teratogenicity: 

No indications of a developmental toxic / teratogenic effect were seen in animal studies. 

12. Ecological information 

Environmental fate and transport

Biodegradation: 

Test method: OECD 301 A (new version) (aerobic), activated sludge, domestic 

Method of analysis: DOC reduction 

Degree of elimination: 90 - 100 % (28 d) 

Evaluation: Readily biodegradable (according to OECD criteria). 

Readily biodegradable (according to OECD criteria). 

Bioaccumulation: 

Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be 

expected. 

Environmental toxicity 

Acute and prolonged toxicity to fish: 

See user defined text. static 

sunfish, bluegill/LC50 (96 h): 13 mg/l 

The details of the toxic effect relate to the nominal concentration. 

Acute toxicity to aquatic invertebrates: 

Directive 84/449/EEC, C.2 static 

HESI102515
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 6/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

Daphnia magna/EC50 (48 h): 29.73 mg/l 

The details of the toxic effect relate to the nominal concentration. 

Toxicity to aquatic plants: 

OECD Guideline 201 static 

green algae/EC50 (72 h): 1.20 mg/l 

The statement of the toxic effect relates to the analytically determined concentration. 

Toxicity to microorganisms: 

bacteria (17 h): 13.3 mg/l 

13. Disposal considerations 

Waste disposal of substance:

Dispose of in accordance with national, state and local regulations. 

It is the waste generator's responsibility to determine if a particular waste is hazardous under RCRA. 

Container disposal: 

Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized 

use of used containers. 

14. Transport information 

Land transport 

USDOT 

Not classified as a dangerous good under transport regulations 

Sea transport 

IMDG

Not classified as a dangerous good under transport regulations 

Air transport 

IATA/ICAO 

Not classified as a dangerous good under transport regulations 

15. Regulatory information 

Federal Regulations

Registration status: 

TSCA, US released / listed 

OSHA hazard category: Acute target organ effects reported, Skin and/or eye irritant, Toxic - oral, 

Highly toxic - inhalation 

SARA hazard categories (EPCRA 311/312): Acute 

State regulations

State RTK

HESI102516
Safety data sheet 

Myacide* GA 25

Revision date : 2008/05/21 Page: 7/7

Version: 2.0 (30174147/MDS_GEN_US/EN)

CAS Number Chemical name State RTK

111-30-8 glutaral MA, NJ, PA 

16. Other information 

HMIS III rating

Health: 3¤ Flammability: 1 Physical hazard: 0 

 

HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the 

substance possesses essentially no hazard; a rating of four indicates high hazard.

Local contact information 

prod_reg@basf.com 

 

Myacide is a registered trademark of BASF Corporation or BASF SE 

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN 

ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR 

GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, 

WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR 

YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER 

EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A 

PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR 

INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE 

USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE 

SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A 

PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND 

AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF 

HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE 

DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH 

BEING GIVEN AND ACCEPTED AT YOUR RISK. 

END OF DATA SHEET

HESI102517
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: National Premium Gold

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: National Premium Gold

Synonyms: None

Chemical Family: Mineral

Application: Additive

Manufacturer/Supplier BENTONITE Performance Minerals LLC

3000 N Sam Houston Parkway East

Houston, TX 77032

Telephone: (281) 871-7900

Fax: (281) 871-7940

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Bentonite 1302-78-9 60 - 100% Not applicable Not applicable

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

Crystalline silica, cristobalite 14464-46-1 0 - 1% 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

Crystalline silica, tridymite 15468-32-3 0 - 1% 0.05 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

National Premium Gold

Page 1 of 7

HESI102518
3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Treat symptomatically.

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

National Premium Gold

Page 2 of 7

HESI102519
Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Do not reuse empty container.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Various

Odor: Odorless

pH: 8-10

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 50-70

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

National Premium Gold

Page 3 of 7

HESI102520
10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause mechanical skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

National Premium Gold

Page 4 of 7

HESI102521
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 10000 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:Not determined

National Premium Gold

Page 5 of 7

HESI102522
Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

National Premium Gold

Page 6 of 7

HESI102523
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

National Premium Gold

Page 7 of 7

HESI102524
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OG-1

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OG-1

Synonyms: None

Chemical Family: Carbonate

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium bicarbonate 1066-33-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause skin and respiratory irritation. May cause eye burns.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

OG-1

Page 1 of 5

HESI102525
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 1

HMIS Ratings: Health 2, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from acids. Store away from alkalis. Store in a cool, dry location. Product

has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Ammonia respirator with a dust/mist filter.

Hand Protection Normal work gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Ammonia

pH: 7.8

Specific Gravity @ 20 C (Water=1): 1.58

OG-1

Page 2 of 5

HESI102526
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 48

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 79.06

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Silicon dioxide. Ammonia. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact Causes severe eye burns. May cause permanent eye damage.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

OG-1

Page 3 of 5

HESI102527
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

OG-1

Page 4 of 5

HESI102528
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

OG-1

Page 5 of 5

HESI102529
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OXYGON®

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OXYGON®

Synonyms: None

Chemical Family: Organic Salt

Application: Oxygen Scavenger

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Organic acid salt 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

OXYGON®

Page 1 of 6

HESI102530
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 1184

Autoignition Temperature (C): 640

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.28

Flammability Limits in Air - Upper (%): Not Determined

Flammability Limits in Air - Upper (oz./ft3): 0.5

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 36

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

OXYGON®

Page 2 of 6

HESI102531
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid Powder

Color: White

Odor: Odorless

pH: 5.5-8 (5%)

Specific Gravity @ 20 C (Water=1): 1.2

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 45-65

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 15

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

OXYGON®

Page 3 of 6

HESI102532
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

OXYGON®

Page 4 of 6

HESI102533
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

OXYGON®

Page 5 of 6

HESI102534
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

OXYGON®

Page 6 of 6

HESI102535
PAO72 ASPHALTENE DISPERSANT

5.0

PAO72

Asphaltene dispersant.

Baker Petrolite

A Baker Hughes Company

12645 W. Airport Blvd. (77478)

P.O. Box 5050

Sugar Land, TX 77487-5050

For Product Information/MSDSs Call: 800-231-3606

(8:00 a.m. - 5:00 p.m. cst, Monday - Friday) 281-276-5400

3/30/2006

3/30/2006

Material Safety Data Sheet

Product Name

Supplier

Material Uses

Code

Version

Effective Date

24 Hour Print Date

Emergency

Numbers

Section 1. Chemical Product and Company Identification

National Fire Protection

Association (U.S.A.)

Health

2

3 0

Flammability

Instability

Specific Hazard

CHEMTREC 800-424-9300 (U.S. 24 hour)

Baker Petrolite 800-231-3606

(001)281-276-5400

CANUTEC 613-996-6666 (Canada 24 hours)

COR

CHEMTREC Int'l 01-703-527-3887 (International 24 hour)

Skin (Contact), Eyes, Inhalation.

Hazard Summary

Medical Conditions

aggravated by

Exposure

Exposure to this product may aggravate medical conditions involving the following: blood system,

kidneys, nervous system, liver, gastrointestinal tract, respiratory tract, skin/epithelium, eyes.

Section 2. Hazards Identification

Routes of Exposure

Potential acute health

effects

Physical State and

Appearance

State: Liquid., Color: Amber., Odor: Aromatic hydrocarbon.

CERCLA Reportable

Quantity

DANGER. May cause chronic effects. Combustible liquid. At elevated temperatures, vapors can

form an ignitable or explosive mixture with air. Can form explosive mixtures at temperatures at or

above the flash point. Vapors can flow along surfaces to distant ignition sources and flash back.

Static discharges can cause ignition or explosion when container is not bonded. May be corrosive to

eyes, skin and respiratory tract. May cause central nervous system (CNS) effects if inhaled.

May be corrosive to the eyes. May cause eye burns and permanent eye injury.

May be corrosive. Skin contact may produce burns.

May cause central nervous system (CNS) effects if inhaled.

Not considered a likely route of exposure, however, may be aspirated into the lungs if swallowed.

Can result in chemical pneumonitis (irritation) and pulmonary edema (accumulation of fluids)

and hemorrhaging (bleeding).

Eyes

Skin

Inhalation

Ingestion

Alkyl benzenesulfonic acid, 1747 gal. of this product.

Xylene, 692 gal. of this product.

May be harmful if ingested. This product may be aspirated into the lungs during swallowing or

vomiting of swallowed material. Aspiration into the lungs may produce chemical pneumonitis,

pulmonary edema, and hemorrhaging.

See Toxicological Information (section 11)

Additional Hazard

Identification Remarks

Continued on Next Page

HESI102536
PAO72 ASPHALTENE DISPERSANT Page: 2/9

Light aromatic naphtha 64742-95-6 30 - 60

1,2,4-Trimethylbenzene 95-63-6 10 - 30

Alkyl benzenesulfonic acid 68584-22-5 10 - 30

1,3,5-Trimethylbenzene 108-67-8 5 - 10

1,2,3-Trimethylbenzene 526-73-8 1 - 5

Xylene 1330-20-7 1 - 5

Section 3. Composition and Information on Ingredients

Name CAS # % by Weight

See Section 8 for information on permissible exposure limits and threshold limit values.

Section 4. First Aid Measures

Get medical attention immediately. If swallowed, do not induce vomiting unless directed to do so

by medical personnel. Never induce vomiting or give anything by mouth to a victim who is

unconscious or having convulsions.

Immediately flush the eye(s) continuously with lukewarm, gently flowing water for at least 20-60

minutes while holding the eyelid(s) open. Get medical attention immediately.

Remove contaminated clothing and shoes immediately. Wash affected area with soap and mild

detergent and large amounts of lukewarm, gently flowing water until no evidence of chemical

remains (for at least 20-60 minutes). Get medical attention if irritation occurs.

Remove victim from area of exposure if possible. Oxygen may be administered if breathing is

difficult. If not breathing, administer artificial respiration and seek medical attention. Get medical

attention if symptoms appear.

Eye Contact

Skin Contact

Inhalation

Ingestion

Notes to Physician Not available.

Additional First Aid

Remarks

Not available.

Combustible liquid. At elevated temperatures, vapors can form an ignitable or explosive mixture

with air. Can form explosive mixtures at temperatures at or above the flash point. Vapors can flow

along surfaces to distant ignition sources and flash back. Static discharges can cause ignition or

explosion when container is not bonded.

These products are carbon oxides (CO, CO2) sulfur oxides (SO2, SO3...).

In case of fire, use foam, dry chemicals, or CO2 fire extinguishers. Evacuate area and fight fire

from a safe distance. Water spray may be used to keep fire-exposed containers cool. Keep

water run off out of sewers and public waterways. Note that flammable vapors may form an

ignitable mixture with air. Vapors may travel considerable distances and flash back if ignited.

Open Flames/Sparks/Static. Heat.

Not available.

Section 5. Fire Fighting Measures

Flammability of the

Product

Products of

Combustion

Fire Hazards in

Presence of Various

Substances

Fire Fighting Media

and Instructions

Special Remarks on

Fire Hazards

Do not enter fire area without proper personal protective equipment, including NIOSH approved

self-contained breathing apparatus.

Protective Clothing

(Fire)

OSHA Flammability

Class

II

Continued on Next Page

HESI102537
PAO72 ASPHALTENE DISPERSANT Page: 3/9

Put on appropriate personal protective equipment. Keep personnel removed and upwind of spill.

Shut off all ignition sources; no flares, smoking, or flames in hazard area. Approach release

from upwind. Shut off leak if it can be done safely. Contain spilled material. Keep out of

waterways. Dike large spills and use a non-sparking or explosion-proof means to transfer

material to an appropriate container for disposal. For small spills add absorbent (soil may be

used in the absence of other suitable materials) scoop up material and place in a sealed, liquidproof container. Note that flammable vapors may form an ignitable mixture with air. Vapors may

travel considerable distances from spill and flash back, if ignited. Waste must be disposed of in

accordance with federal, state and local environmental control regulations.

Section 6. Accidental Release Measures

Spill

Other Statements If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-

8802.

Additional Accidental Not available.

Release Measures

Remarks

Put on appropriate personal protective equipment. Avoid contact with eyes, skin, and clothing.

Avoid breathing vapors or spray mists. Use only with adequate ventilation. Store in a dry, cool

and well ventilated area. Keep away from heat, sparks and flame. Keep away from

incompatibles. Keep container tightly closed and dry. To avoid fire or explosion, ground

container equipment and personnel before handling product.

Section 7. Handling and Storage

Handling and Storage

Additional Handling Not available.

and Storage Remarks

Section 8. Exposure Controls/Personal Protection

Exposure Limits

Additional Information

on Exposure Limits

Light aromatic naphtha Not available.

1,2,4-Trimethylbenzene Not available.

Alkyl benzenesulfonic acid Not available.

1,3,5-Trimethylbenzene Not available.

1,2,3-Trimethylbenzene Not available.

Xylene ACGIH (United States).

TWA: 434 mg/m3 8 hour/hours.

STEL: 651 mg/m3 15 minute(s).

TWA: 100 ppm 8 hour/hours.

STEL: 150 ppm 15 minute(s).

OSHA PEL 1989 (United States).

TWA: 100 ppm 8 hour/hours.

STEL: 150 ppm 15 minute(s).

TWA: 435 mg/m3 8 hour/hours.

STEL: 655 mg/m3 15 minute(s).

Continued on Next Page

HESI102538
PAO72 ASPHALTENE DISPERSANT Page: 4/9

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of

vapors or particles below their respective threshold limit value. Ensure that eyewash stations and

safety showers are proximal to the work-station location.

Engineering Controls

Respirator use is not expected to be necessary under normal conditions of use. In poorly

ventilated areas, emergency situations or if exposure levels are exceeded, use NIOSH approved

full face respirator.

Chemical safety goggles. Use full face shield if splashes could occur.

Wear long sleeves and chemical resistant apron to prevent repeated or prolonged skin contact.

Chemical resistant gloves. Nitrile or Neoprene gloves.

Chemical resistant boots or overshoes.

Personal Protection

Eyes

Body

Respiratory

Hands

Feet

Other information Nitrile or neoprene gloves.

Additional Exposure

Control Remarks

Not available.

Personal Protective Equipment recommendations are based on anticipated known manufacturing and use conditions.

These conditions are expected to result in only incidental exposure. A thorough review of the job tasks and conditions by a

safety professional is recommended, however, to determine the level of personal protective equipment appropriate for these

job tasks and conditions.

While trimethylbenzene isomers do not have exposure limits, trimethylbenzene (mixed isomers)

(CAS No. 25551-13-7) has TWA value of 25 ppm for both ACGIH and OSHA (revoked limit). The

OSHA permissible exposure levels shown above are the OSHA 1989 levels or from subsequent

OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of

Appeals, Baker Petrolite Corporation recommends that these lower exposure levels be observed

as reasonable worker protection.

Section 9. Physical and Chemical Properties

Liquid.

1.6 - 1.8 (10% product - 75% IPA/25%

water solvent.)

0.91 - 0.922 @ 16°C (60°F)

>1 (Air = 1)

Not Available or Not Applicable for Solids.

Insoluble

Aromatic hydrocarbon.

Amber.

Not Available or Not Applicable for Solids.

6 - 7 cP @ 16°C (61°F)

Physical State and

Appearance

pH

Specific gravity

Vapor Pressure

Vapor Density

Evaporation Rate

Viscosity

Solubility (Water)

Physical Chemical

Comments

Odor

Color

VOC Not available.

Density 7.58 - 7.68 lbs/gal @ 16°C (60°F)

Pour Point -40oC (-40oF)

Boiling Point 101°C (214°F)

Not available.

Flash Points

Flammable Limits

Initial Boiling Point Not available.

Autoignition

Temperature

Closed cup: 53°C (127.4°F). (SFCC)

L.E.L. Not available. U.E.L. Not available.

Not available.

Continued on Next Page

HESI102539
PAO72 ASPHALTENE DISPERSANT Page: 5/9

Section 10. Stability and Reactivity

The product is stable.

Oxidizing material. Alkali.

Hazardous polymerization is not expected to occur.

Not applicable.

Not available.

Stability and Reactivity

Conditions of

Instability

Incompatibility with

Various Substances

Hazardous

Decomposition

Products

Hazardous

Polymerization

Special Stability & Not available.

Reactivity Remarks

Section 11. Toxicological information

Acute Animal Toxicity

Chronic Toxicity Data

Light aromatic naphtha ORAL (LD50): Acute: 2900 mg/kg [Rat]. 8400 mg/kg [Rat].

1,2,4-Trimethylbenzene ORAL (LD50): Acute: 5000 mg/kg [Rat]. VAPOR (LC50):

Acute: 18000 mg/m3 4 hour/hours [Rat].

Alkyl benzenesulfonic acid Not available.

1,3,5-Trimethylbenzene VAPOR (LC50): Acute: 24000 mg/m3 4 hour/hours [Rat].

1,2,3-Trimethylbenzene Not available.

Xylene ORAL (LD50): Acute: 4300 mg/kg [Rat]. 3523 mg/kg [Male

rat]. DERMAL (LD50): Acute: >1700 mg/kg [Rabbit].

VAPOR (LC50): Acute: 5000 ppm 4 hour/hours [Rat].

Component Toxicological Information

1) Light aromatic naphtha

Solvent naphtha (petroleum), light aromatic is a component of this product. Solvent naphtha (petroleum), light aromatic may

cause damage to the peripheral nerves, resulting in numbness or tingling of the extremities with chronic (long term) exposure

to high concentrations. (Micromedex) Rats exposed for 4 months to 1700 ppm of a solvent similar to this product showed

evidence of mild damage to the liver, lungs and kidneys. These effects were not seen in rats exposed for one year to 350

ppm of another similar solvent. Rats exposed to vapors of a similar solvent during pregnancy showed embryo/fetotoxicity at

concentrations producing maternal toxicity.

In response to a TSCA test rule, several studies of a solvent similar to this product were completed. Mutagenicity studies and

a rat inhalation neurotoxicity study were negative. In a mouse developmental effects study, reduced fetal body weight was

seen but no teratogenicity. A rat reproductive effects study demonstrated toxicity but little effect on reproductive parameters.

(Vendor MSDS)

Ingestion has produced Central Nervous System effects in laboratory animals. (EPA/OTS 87-8214199 and 88-920000348)

2) 1,2,4-Trimethylbenzene

Continued on Next Page

HESI102540
PAO72 ASPHALTENE DISPERSANT Page: 6/9

1,2,4-Trimethylbenzene, also know as pseudocumene, is a component of this product. Chronic pseudocumene exposure

may provoke bronchospasm with cough and wheezing (Plunkett, 1976; ACGIH, 1991; Battig et al, 1956). Respiratory

distress was noted in experimental animals following sub acute inhalation exposure (Gage, 1970). Nervousness and anxiety

were noted with chronic occupational exposure (Battig et al, 1956; ACGIH, 1991).

At the time of this review, no studies were found on the potential adverse reproductive effects of pseudocumene in humans,

but trimethylbenzenes (including pseudocumene) can cross the placental barrier (Clayton & Clayton, 1994; Doroty et al,

1976). In an experimental animal study, offspring born to pregnant rats exposed to pseudocumene were healthy at birth and

grew normally (Cameron et al, 1938).

Blood effects such as anemia and delayed clotting time have been noticed in workers chronically exposed to a solvent

containing trimethylbenzene. The blood effects, however, may have been due to a contaminant in the solvent such as

benzene (a known blood toxin).

3) Alkyl benzenesulfonic acid

Alkylbenzene sulfonic acid is a component of this product. Chronic inhalation causes swelling of the lungs, bronchial

emphysema, and dental erosion ( MSDS).

4) 1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene (Mysitylene) is a component of this product. Chronic asthmatic-like bronchitis may be a delayed

chronic hazard (EPA, 1985; Laham, 1987; HSDB, 1997). Nervousness, tension, and anxiety have been noted in chronically

exposed workers with exposure to a mixture of solvents including mesitylene (HSDB, 1997). Elevated alkaline phosphates

and SGOT(liver enzymes) levels have been noted in chronic animal inhalation studies (Clayton & Clayton, 1994). These

effects have not been reported in exposed humans. (Reprotext)

Thrombocytopenia (a lack of platelets in the blood) with bleeding from the gums and nose and mild anemia may occur with

chronic exposure to mesitylene as a component of the commercial solvent mixture, "Fleet-X-DV-99" (Plunkett, 1976; Finkel,

1983; HSDB, 1997). Coagulation (clotting of the blood) times were delayed by about 40% in a group of workers chronically

exposed to a mixture of solvents containing about 30% mesitylene (Laham, 1987). These hematological disorders may have

been due to a contaminant, such as benzene (Hathaway et al, 1996). Thrombocytosis (an increase of platelets in the blood)

and thrombocytopenia have been noted in rabbits (Clayton & Clayton, 1994). (Reprotext)

1,3,5-Trimethylbenzene has been positive in a mutagenicity assay (Lewis, 1992). (Reprotext)

5) 1,2,3-Trimethylbenzene

Not available.

6) Xylene

Xylene (mixed isomers) is a component of this product. Effects of chronic exposure to xylene are similar to those of acute

exposure, but may be more severe. Chronic inhalation reportedly was associated with headache, tremors, apprehension,

memory loss, weakness, dizziness, loss of appetite, nausea, ringing in the ears, irritability, thirst, anemia, mucosal bleeding,

enlarged liver, and hyperplasia, but not destruction of the bone marrow (Clayton & Clayton, 1994; ILO, 1983). Some earlier

reports of effects of chronic exposure to xylene have been questioned, as exposures were not limited to xylene alone.

Effects on the blood have been reported from chronic exposure to as little as 50 mg/m3 (Pap & Varga, 1987). Repeated

exposure can damage bone marrow, causing low blood cell count and can damage the liver and kidneys (NJ Department of

Health, Hazardous Substance Fact Sheet). Chronic xylene exposure (usually mixed with other solvents) has produced

irreversible damage to the CNS (ILO, 1983). CNS effects may be exacerbated by ethanol abuse (Savolainen, 1980). Xylene

may damage hearing or enhance sensitivity to noise in chronic occupational exposures (Morata et al, 1994), probably from

neurotoxic mechanism. Tolerance to xylene can occur over the work week and disappear over the weekend. (ACGIH, 1992).

Inhalation exposure has produced fetotoxicity and postnatal developmental toxicity in laboratory animals. (API, 1978,

Kensington, MD, EPA/OTS Document No. 878210350 and Hass, U., et al, 1995, Neurotoxicology and Teratology 17: 341-

349 and 1997, Neurotoxicology 18: 547-552)

Continued on Next Page

HESI102541
PAO72 ASPHALTENE DISPERSANT Page: 7/9

Other Adverse Effects Not available.

Target Organs blood system, kidneys, nervous system, liver, gastrointestinal tract, respiratory tract,

skin/epithelium, eyes.

Product Toxicological Information

Acute Animal Toxicity Not available.

Inhalation of hexane has synergistically enhanced the hearing loss caused by inhalation exposure to xylene in laboratory

animals. (Nylén, P., 1996, Food and Chemical Toxicology, 34: 1121-1123 and Nylén, P. and Hagman, M., 1994,

Pharmacology & Toxicology, 74: 124-129)

Xylene has tested positive as a dermal sensitizer. [Altman, A.T. (1977) Archives of Dermatology 113: 1460 and Palmer, K.T.

and Rycroft, R.J. F. (1993) Contact Dermatitis 28: 44]

Section 12. Ecological Information

Not available.

Not available.

An EcoToxTM Report, and/or the material's environmental fate is available upon request at the

following number: 1-800-235-4249, then press 4.

Ecotoxicity

BOD5 and COD

Biodegradable/OECD

Toxicity of the Products

of Biodegradation

Special Remarks

Not available.

Not available.

Section 13. Disposal Considerations

Additional Waste

Remarks

Not available.

Responsibility for proper waste disposal rests with the generator of the waste. Dispose of any waste material in accordance

with all applicable federal, state and local regulations. Note that these regulations may also apply to empty containers, liners

and rinsate. Processing, use, dilution or contamination of this product may cause its physical and chemical properties to

change.

3

FLAMMABLE LIQUID

8

CORROSIVE

Marine Pollutant Alkyl benzenesulfonic acid.

Section 14. Transport Information

DOT Classification

DOT Reportable

Quantity

FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Contains:

Light aromatic naphtha, Alkyl benzenesulfonic acid), 3(8),

UN2924, III

Alkyl benzenesulfonic acid, 1747 gal. of this product.

Xylene, 692 gal. of this product.

Continued on Next Page

HESI102542
PAO72 ASPHALTENE DISPERSANT Page: 8/9

Emergency Response

Guide Page Number

132

Additional DOT

Information

DOT Marine Pollutant if shipped in bulk or by vessel.

U.S. Federal

Regulations

State specific information is available upon request from Baker Petrolite.

Target organ effects. Combustible liquid. At elevated temperatures, vapors can form an ignitable

or explosive mixture with air. Can form explosive mixtures at temperatures at or above the flash

point. Vapors can flow along surfaces to distant ignition sources and flash back. Static discharges

can cause ignition or explosion when container is not bonded. Corrosive.

HCS Classification

Section 15. Regulatory Information

All components are included or are exempted from listing on the US Toxic Substances Control

Act Inventory.

Clean Water Act (CWA) 307 Priority Pollutants: Not applicable to any components in this product.

Clean Water Act (CWA) 311 Hazardous Substances: Xylene;

Clean Air Act (CAA) 112(r) Accidental Release Prevention Substances: Not applicable to any

components in this product.

State Regulations

WHMIS (Canada) B-3, D-2A, D-2B, E

International

Regulations

All components are included or are exempted from listing on the European Inventory of Existing

Commercial Chemical Substances or the European List of Notified Chemical Substances.

European Union

All components are compliant with or are exempted from listing on the Canadian Domestic

Substance List.

International inventory status information is available upon request from Baker Petrolite for the

following countries: Australia, China, Korea (TCCL), Philippines (RA6969), or Japan.

Environmental

Regulations

TSCA Inventory

Status

Other Regulatory No further regulatory information is available.

Information

Canada

This product contains the following components that are subject to the reporting requirements of

TSCA Section 12(b) if exported from the United States: Xylene; Naphthalene.

Threshold

Planning

Quantity (TPQ)

Not applicable.

Extremely Hazardous Substances: Not applicable to any components in this product.

SARA 313 Toxic Chemical Notification and Release Reporting: 1,2,4-Trimethylbenzene; Xylene;

SARA 302/304 Emergency Planning and Notification substances: Not applicable to any

components in this product.

Hazardous Substances (CERCLA 302): Alkyl benzenesulfonic acid; Xylene, 692 gal. of this

product.;

SARA 311/312 MSDS distribution - chemical inventory - hazard identification: fire; immediate

health hazard; delayed health hazard;

Continued on Next Page

HESI102543
PAO72 ASPHALTENE DISPERSANT Page: 9/9

731

10/03/02 - Changes to Sections 2 and 9.

08/20/03 - Changes to Sections 14 and 15.

08/11/04 - Changes to Sections 8 and 15.

03/30/06 - Changes to Sections 2, 3, 5, 8, 9 and 15.

Section 16. Other Information

Other Special

Considerations

Baker Petrolite Disclaimer

NOTE: The information on this MSDS is based on data which is considered to be accurate. Baker Petrolite, however,

makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be

beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for

loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this

product.

This MSDS was prepared and is to be used for this product. If the product is used as a component in another product,

this MSDS information may not be applicable.

In April, 2005, a number of format changes were made. The most notable of these were switching Sections 2

and 3, moving the exposure limits to Section 8, and moving the flash point from Section 5 to Section 9.

HESI102544
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PARAGON

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PARAGON

Synonyms: None

Chemical Family: Aromatic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethyl benzene 100-41-4 10 - 30% 100 ppm 100 ppm

Xylene 1330-20-7 60 - 100% 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

PARAGON

Page 1 of 6

HESI102545
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 81

Flash Point/Range (C): 27

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PARAGON

Page 2 of 6

HESI102546
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Aromatic hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.87

Density @ 20 C (lbs./gallon): 7.25

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 279

Boiling Point/Range (C): 137

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 5

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 90.08

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. This material is an anesthetic. May cause central

nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause headache, dizziness, nausea,

vomiting, gastrointestinal irritation and central nervous system depression. May

cause pulmonary edema.

PARAGON

Page 3 of 6

HESI102547
Aggravated Medical Conditions Skin disorders. Eye ailments. Lung disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and blood effects.

Prolonged or repeated exposure may cause central nervous system and brain

effects. Prolonged or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1307,Xylenes, 3, III, (27.2 C)

RQ (Xylene - 45.4 kg.)

NAERG 130

PARAGON

Page 4 of 6

HESI102548
Canadian TDG

Xylenes, 3, UN1307, III, (27.2 C)

ADR

UN1307,Xylenes, 3, III

Air Transportation

ICAO/IATA

UN1307,Xylenes, 3, III

RQ (Xylene - 45.4 kg.)

Sea Transportation

IMDG

UN1307,Xylenes, 3, III, (27.2 C)

RQ (Xylene - 45.4 kg.)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

CAS:1330-20-7//Chemical Name: Xylene///TPQ: 100

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Xylene//1330-20-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 14 Gallons based on Xylene (CAS: 1330-20-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Listed Waste U239

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PARAGON

Page 5 of 6

HESI102549
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PARAGON

Page 6 of 6

HESI102550
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PERM A CONFORMANCE ADDITIVE

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PERM A CONFORMANCE ADDITIVE

Synonyms: None

Chemical Family: Acetate

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acrylic acid, 2-hydroxyethyl

ester

818-61-1 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be fatal if absorbed through the

skin. May cause allergic skin reaction. May be harmful if swallowed. Poison.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

PERM A CONFORMANCE ADDITIVE

Page 1 of 6

HESI102551
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 214

Flash Point/Range (C): 101

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.8

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 1

HMIS Ratings: Health 3, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store away from reducing

agents. Store away from direct sunlight. Store in a cool well ventilated area. Store at

temperatures between 50 and 100 F (10 and 37.8 C). Do not freeze. Keep

container closed when not in use. Do NOT fill containers completely. Keep

containers oxygenated with air. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Polyvinylchloride gloves.

Skin Protection Rubber boots. Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PERM A CONFORMANCE ADDITIVE

Page 2 of 6

HESI102552
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Mild acrylic

pH: 3.5

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 410

Boiling Point/Range (C): 210

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.11

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 116.13

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: May Occur

Conditions to Avoid Keep away from heat, sparks and flame. UV light exposure. Avoid contact with free

radical initiators.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Free radical initiators. Reducing agents. Nitrogen.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May be fatal if absorbed through the skin. Causes severe skin irritation. May cause

skin burns. May cause an allergic skin reaction.

Eye Contact May cause eye burns. May cause permanent eye damage.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

PERM A CONFORMANCE ADDITIVE

Page 3 of 6

HESI102553
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 540 mg/kg (Rat)

Dermal Toxicity: LD50: 154 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(28 Day): 40% of COD

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 4.8 mg/l (Pimephales promelas) TLM48: 7478 mg/l (Orange-Red Killfish)

Acute Crustaceans Toxicity:TLM96: 0.78 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Toxic Liquid, Corrosive, Organic, N.O.S., 6.1, (8), UN2927, II

(Contains Hydroxyethyl Acrylate)

NAERG 154

Canadian TDG

Toxic Liquid, Corrosive, Organic, N.O.S.(Contains Hydroxyethyl Acrylate), 6.1, (8), UN2927, II

ADR

UN2927,Toxic Liquid, Corrosive, Organic, N.O.S.(Contains Hydroxyethyl Acrylate), 6.1, (8), II

PERM A CONFORMANCE ADDITIVE

Page 4 of 6

HESI102554
Air Transportation

ICAO/IATA

UN2927,Toxic Liquid, Corrosive, Organic, N.O.S., 6.1, (8), II

(Contains Hydroxyethyl Acrylate Solution)

Sea Transportation

IMDG

UN2927,Toxic Liquid, Corrosive, Organic, N.O.S.(Contains Hydroxyethyl Acrylate), 6.1, (8), II

EmS F-A, S-B

Other Shipping Information

Labels: Toxic

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

PERM A CONFORMANCE ADDITIVE

Page 5 of 6

HESI102555
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PERM A CONFORMANCE ADDITIVE

Page 6 of 6

HESI102556
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PERM C CONFORMANCE ADDITIVE

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PERM C CONFORMANCE ADDITIVE

Synonyms: None

Chemical Family: Not applicable

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

2,2`-Azobis(2-amidopropane)

dihydrochloride

2997-92-4 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache and nausea. May cause

allergic skin reaction. May be harmful if swallowed. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Remove contaminated clothing and launder before

reuse. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician None known.

PERM C CONFORMANCE ADDITIVE

Page 1 of 6

HESI102557
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.013

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove. Flush area with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Avoid contact with

persulfate which can lead to the formation of shock and friction sensitive mixtures.

Storage Information Store away from direct sunlight. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep away from friction, impact, and heat. Container

should NOT be closed tightly. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

PERM C CONFORMANCE ADDITIVE

Page 2 of 6

HESI102558
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Off white

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.2

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 74.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 23.2

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with sunlight.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and contribute to the

symptoms listed under ingestion. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause headache, dizziness, nausea,

vomiting, gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

PERM C CONFORMANCE ADDITIVE

Page 3 of 6

HESI102559
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Self-heating, Solid, Organic, N.O.S., 4.2, UN3088, II

(2,2'-Azobis (2-Amidinopropane) Dihydrochloride)

NAERG 135

Canadian TDG

Self-heating, Solid, Organic, N.O.S.(2,2'-Azobis (2-Amidinopropane) Dihydrochloride), 4.2, UN3088, II

ADR

UN3088,Self-heating, Solid, Organic, N.O.S.(2,2'-Azobis (2-Amidinopropane) Dihydrochloride), 4.2, II

PERM C CONFORMANCE ADDITIVE

Page 4 of 6

HESI102560
Air Transportation

ICAO/IATA

UN3088,Self-heating, Solid, Organic, N.O.S., 4.2, II

(2,2'-Azobis (2-Amidinopropane) Dihydrochloride)

Sea Transportation

IMDG

UN3088,Self-heating, Solid, Organic, N.O.S.(2,2'-Azobis (2-Amidinopropane) Dihydrochloride), 4.2, II

EmS F-A, S-J

Other Shipping Information

Labels: Spontaneously Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

PERM C CONFORMANCE ADDITIVE

Page 5 of 6

HESI102561
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PERM C CONFORMANCE ADDITIVE

Page 6 of 6

HESI102562
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PIPESCRUB

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PIPESCRUB

Synonyms: None

Chemical Family: Terpenes

Application: Cleaner

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Citrus, extract 94266-47-4 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

allergic skin reaction. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

PIPESCRUB

Page 1 of 6

HESI102563
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 115

Flash Point/Range (C): 46

Flash Point Method: TCC

Autoignition Temperature (F): 458.0

Autoignition Temperature (C): 236.7

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 6.1

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PIPESCRUB

Page 2 of 6

HESI102564
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless to pale yellow

Odor: Citrus

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.84

Density @ 20 C (lbs./gallon): 7.0

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 310

Boiling Point/Range (C): 154

Freezing Point/Range (F): -133.9

Freezing Point/Range (C): -92.1

Vapor Pressure @ 20 C (mmHg): 2

Vapor Density (Air=1): 4.730

Percent Volatiles: > 95

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): ethers alcohols

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 4.23

Molecular Weight (g/mole): 136.3

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with acids. Avoid contact with

aluminum chloride.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Pentafluoroethylene.

Hazardous Decomposition

Products

Oxides of nitrogen. Acrid fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May cause an allergic skin reaction. May be absorbed

through the skin and produce effects similar to those caused by inhalation and/or

ingestion.

Eye Contact May cause eye irritation.

PIPESCRUB

Page 3 of 6

HESI102565
Ingestion May be fatal if swallowed. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause central nervous system and brain

effects. FDA and WHMIS list D-limonene as Generally Recognized As Safe (GRAS).

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(28 Day): 100% of COD

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

PIPESCRUB

Page 4 of 6

HESI102566
UN2319,Terpene Hydrocarbons, N.O.S., 3, III, (46.1 C)

NAERG 128

Canadian TDG

Terpene Hydrocarbons, N.O.S., 3, UN2319, III, (46.1 C)

ADR

UN2319,Terpene Hydrocarbons, N.O.S., 3, III

Air Transportation

ICAO/IATA

UN2319,Terpene Hydrocarbons, N.O.S., 3, III

Sea Transportation

IMDG

UN2319,Terpene Hydrocarbons, N.O.S., 3, III, (46.1 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

PIPESCRUB

Page 5 of 6

HESI102567
Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PIPESCRUB

Page 6 of 6

HESI102568
Material Safety Data Sheet 

Plexsurf WRS A 

Page 1 of 5 

Chemplex, L.C. 

506 CR 1071 

Snyder, TX 79549 

(325) 573-7298 

DATE PREPARED:........... 05/19/2004 

REVISION DATE:............. 04/16/2007 

EMERGENCY NUMBER:...800-633-8253 

PRODUCT NUMBER:....... 00826 

C hem

P lex

CHEMPLEX 

SECTION I – IDENTIFICATION 

PRODUCT NAME: ........................... Plexsurf WRS A 

SYNONYMS: ................................... N/A 

CHEMICAL FAMILY: . ...................... Surfuctants 

CAS NUMBER: ............................... N/A

PRODUCT USE: .............................. Petrochemical industry 

SECTION II – HAZARDOUS INGREDIENTS 

HAZ INGREDIENT PERCENT CAS NUMBER PEL 

METHYL ALCOHOL 60% 67-56-1 Not Available 

Dodecylbenzene 

Sulfonic Acid Salts 

15-20% 68648-81-7 Not Available 

SECTION III – PHYSICAL DATA 

APPEARANCE: .............................. Pale Yellow liquid 

ODOR: ........................................... Alcohol like. (slight) 

BOILING POINT: ............................. >170o F 

FLASHPOINT: ................................. (56oF) Open Cup 

VAPOR DENSITY (AIR=1): .................1.11 

SPECIFIC GRAVITY (WATER=1): ........0.85 

pH (1% SOLN/WATER):.......................Neutral 

SOLUBILITY....................................Easily soluble in cold water, hot water, methanol, diethyl 

ether. 

WT: ................................................7.12 # per gallon 

SECTION IV – FIRE AND EXPLOSION DATA 

HESI102569
Material Safety Data Sheet 

Plexsurf WRS A 

Page 2 of 5 

FLASHPOINT: ................................. (56°F) Open Cup 

FLAMMABLE LIMITS:.......................LOWER: 6% (Methyl Alcohol) 

UPPER: 36.5 % (Methyl Alcohol) 

FLAMMABLE HAZARDS: .................Highly flammable in presence of open flames and sparks, 

of heat, of combustible materials. 

EXTINGUISHING MEDIA: .................Flammable liquid, soluble or dispersed in water. 

FIRE FIGHTING PROCEDURES: .......SMALL FIRE: Use DRY chemicals, C02, water spray or 

alcohol foam. 

LARGE FIRE: Use alcohol foam, water spray or fog. 

Cool containing vessels with water jet in order to prevent 

pressure build-up, autoignition or explosion. 

EXPLOSION HAZARDS:...................Explosive in the form of vapor when exposed to heat or 

flames. Vapor may travel considerable distance to 

source of ignition and flash back. When heated to 

decomposition, it emits acrid smoke and irritating fumes. 

(Methyl alcohol) 

SECTION V – REACTIVITY DATA 

STABILITY: .................................... This product is stable. 

CORROSIVITY: ............................... Non-corrosive in presence of glass. 

REACTIVITY: .................................. Highly reactive with oxidizing agents. 

SECTION VI A - HEALTH HAZARD DATA 

ROUTE OF ENTRY: ......................... Ingestion, Inhalation 

ACUTE EFFECT ON HUMANS: ......... Slightly dangerous to dangerous in case of skin contact 

(irritant), of eye contact (irritant), of ingestion, of 

inhalation. Very slightly to slightly dangerous in case of 

skin contact (permeator). 

CHRONIC EFFECTS ON HUMANS: ... The substance is toxic to the nervous system, the 

reproductive system. 

Passes through the placental barrier. 

SECTION VI B - FIRST AID 

INHALATION: ................................. SLIGHT INHALATION: Allow the victim to rest in a well 

ventilated area. Seek immediate medical attention. 

HAZARDOUS INHALATION: Evacuate the victim to a 

safe area as soon as possible. Loosen tight clothing 

such as a collar, tie, belt or waistband. If breathing is 

difficult, administer oxygen. If the victim is not breathing, 

HESI102570
Material Safety Data Sheet 

Plexsurf WRS A 

Page 3 of 5 

perform mouth-to-mouth resuscitation. WARNING: It 

may be dangerous to the person providing aid to give 

mouth-to-mouth resuscitation when the inhaled material 

is toxic, infectious or corrosive. Seek medical attention. 

INGESTION: ................................... SLIGHT INGESTION: Do not induce vomiting. Have 

conscious person drink several glasses of water or milk. 

Seek immediate medical attention. 

HAZARDOUS INGESTION: Do NOT induce vomiting. 

Examine the lips and mouth to ascertain whether the 

tissues are damaged, a possible indication that the toxic 

material was ingested; the absence of such signs, 

however, is not conclusive. Loosen tight clothing such 

as a collar, tie, belt or waist band. If the victim is not 

breathing, perform mouth-to-mouth resuscitation. Seek 

medical attention. 

EYE CONTACT: .............................. Check for and remove any contact lenses. Immediately 

flush eyes with running water for at least 15 minutes, 

keeping eyelids open. Cold water may be used. Do 

NOT use an eye ointment. Seek medical attention. 

SKIN CONTACT: ............................. If the chemical got onto the clothed portion of the body, 

remove the contaminated clothes as quickly as possible, 

protecting your own hands and body. Place the victim 

under a deluge shower. If the chemical touches the 

victims exposed skin, such as the hands: Gently and 

thoroughly wash the contaminated skin with running 

water and non-abrasive soap. Be particularly careful to 

clean folds, crevices, creases and groin. COLD water 

may be used. Cover the irritated skin with an emollient. 

If irritation persists seek medical attention. Wash 

contaminated clothing before reusing. 

SECTION VII – SPILL, STORAGE AND DISPOSAL DATA 

SPILL: ........................................... SMALL SPILL: Dilute with water and mop up, or absorb 

with an inert DRY material and place in an appropriate 

waste disposal container. 

LARGE SPILL: Keep away from heat. Keep away from 

sources of ignition. Stop leak if without risk. Absorb with 

DRY earth, sand or other non-combustible material. DO 

NOT touch spilled material. Prevent entry into sewers, 

basements or confined areas; dike if needed. Eliminate 

all sources of ignition. 

WASTE DISPOSAL: ......................... Whatever cannot be saved for recovery or recycling 

should be managed in an appropriate and approved 

waste disposal facility. Processing, use or 

contamination of this product may change the waste 

management options. State and local disposal 

regulations may differ from federal disposal regulations. 

HESI102571
Material Safety Data Sheet 

Plexsurf WRS A 

Page 4 of 5 

Dispose of container and unused contents in accordance 

with federal, state and local requirements. 

HANDLING: .................................... Keep locked up. Keep away from heat. Keep away 

from sources of ignition. Ground all equipment 

containing material. DO NOT ingest. Do not breathe 

gas, fumes, vapor or spray. In case of insufficient 

ventilation, wear suitable respiratory equipment. If 

ingested, seek medical advice immediately and show the 

container or the label. Avoid contact with skin and eyes. 

Keep away from incompatibles as oxidizing agents. 

STORAGE: ..................................... Flammable materials should be stored in a separate 

safety storage cabinet or room. Keep away from heat. 

Keep away from sources of ignition. Keep container 

tightly closed. Keep in a cool, well-ventilated place. 

Ground all equipment containing material. A refrigerated 

room would be preferable for materials with a flash point 

lower than 37.8°C (100°F). 

 

SECTION VIII – PROTECTIVE CLOTHING 

RESPIRATORY PROTECTION: ......... Wear appropriate respirator when ventilation is 

inadequate 

PROTECTIVE CLOTHING/EQUIPMENT: ..... Splash goggles, lab coat/apron, gloves 

SECTION IX – TRANSPORTATION DATA 

PROPER SHIPPING NAME: .............. Flammable liquid, n.o.s., 

HAZARD CLASS: ............................ 3 

UN NUMBER: ................................. UN 1993 

PACKAGING GROUP: ..................... II 

RQ: ............................................... N/A 

DOT SHIPPING: .............................. Flammable liquid, n.o.s., (Contains Methyl Alcohol), 3, 

UN 1993, PG II 

 This material is classified as a marine pollutant due to its 

 content of dodecylbenzene sulfonic acid salts. 

SECTION X – OTHER REGULATORY INFORMATION 

 

TSCA STATUS: .............................. All components of this product are listed on the TSCA 

inventory. 

NFPA HEALTH: .............................. 1 

NFPA FLAMMABILITY: .................... 3 

NFPA REACTIVITY: ......................... 0 

HESI102572
Material Safety Data Sheet 

Plexsurf WRS A 

Page 5 of 5 

SECTION XI - ADDITIONAL INFORMATION 

PREPARED BY: .............................. Edward F. Vinson 

 

EMERGENCY RESPONSE NUMBER: .......... 800-633-8253

HESI102573
This information relates only to the specific material designated and may not be valid for such material used in 

combination with any other materials or in any process. Such information is, the best of our knowledge and belief, 

accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its 

accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability and 

completeness of such information for his own particular use. We do not accept liability for any loss or damage that may 

occur from the use of this information nor do we offer any warranty against patent infringement. 

Chemplex, Ltd. * P.O. Box 1071 * Snyder, TX 79550 * (915) 573-7298 

Chemplex, Ltd. 

Product Bulletin 

GENERAL INFORMATION 

Plexsurf WRS-A is a blend of conventional 

anionic and fluorocarbon surfactants, which 

work synergistically to give very low surface 

tensions and negligible absorption to rock in well 

treating fluids. These features promote load 

recovery, particularly in gas well applications. 

Plexsurf WRS-A shows very low tendency to 

form emulsions at recommended loadings. 

PHYSICAL PROPERTIES 

Density: 7.81 lb./gal 

Ionic Charge: Anionic 

Solubility in water: Soluble 

Solubility in diesel: Insoluble 

Appearance: Pale yellow liquid 

Odor: Mild alcohol 

Flash point: 56° F 

CHEMICAL DESCRIPTION 

Plexsurf WRS-A contains fluorosurfactants, and 

conventional anionic surfactants, in an aqueous 

alcohol base. 

RECOMMENDED USES 

Plexsurf WRS-A is recommended for use 

particularly in fracturing treatments on gas 

zones, especially in tighter formations that have 

a history of being slow to unload. The product is 

effective in either sandstone or carbonates. 

TREATING APPLICATIONS 

The typical loading of Plexsurf WRS-A in 

fracturing fluids is 0.5 to 1 gallon per thousand 

gallons throughout the job. Plexsurf WRS-A is 

not known to interfere with crosslinkers, 

breakers, or other fracturing additives at this 

loading; it is, however, incompatible with 

polymeric clay stabilizers. If run in acid 

treatment loadings of up to 2 gallons/1000 may 

be required for optimal surface tension reduction. 

Use of nonionic non-emulsifiers with Plexsurf 

WRS-A, though perfectly acceptable, is often not 

required due to the NE properties of the product. 

PACKAGING 

Plexsurf WRS-A is obtainable in 55-gallon poly 

drums, 330-gallon poly totes and Bulk storage 

DOT information: Flammable liquid, n.o.s., 3, 

UN 1993, PG II

AVAILABILITY 

Plexsurf WRS-A is available from Chemplex, 

Ltd. at any of our stocking locations. 

Updated 4-24-07 

Plexsurf WRS-A 

Water Recovery Surfactant

HESI102574
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: POL-E-FLAKE

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: POL-E-FLAKE

Synonyms: None

Chemical Family: Polymer

Application: Loss Circulation Material

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cellophane 9005-81-6 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation Under normal conditions, first aid procedures are not required.

Skin Under normal conditions, first aid procedures are not required.

Eyes Under normal conditions, first aid procedures are not required.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

POL-E-FLAKE

Page 1 of 5

HESI102575
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Flake

Color: Colorless

Odor: Odorless

pH: 5.5

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): Not Determined

POL-E-FLAKE

Page 2 of 5

HESI102576
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 9

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact None known.

Eye Contact None known.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

POL-E-FLAKE

Page 3 of 5

HESI102577
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

POL-E-FLAKE

Page 4 of 5

HESI102578
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

POL-E-FLAKE

Page 5 of 5

HESI102579
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PolyCrystal

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PolyCrystal

Synonyms: None

Chemical Family: Polymer

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acrylamide copolymer 9003-05-8 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

PolyCrystal

Page 1 of 6

HESI102580
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust. Slippery

when wet.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust. Wash hands after use. Slippery when wet.

Storage Information Store in a dry location. Store between 40.5 F (4.7 C) and 120.5 F (49 C). Store away

from direct sunlight. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls A well ventilated area to control dust levels.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

PolyCrystal

Page 2 of 6

HESI102581
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Granules and Powder

Color: Off white

Odor: Odorless

pH: 6.5-7.5

Specific Gravity @ 20 C (Water=1): .66

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains a small amount (< 0.1%) acrylamide, a suspected carcinogen.

Other Information None known.

Toxicity Tests

PolyCrystal

Page 3 of 6

HESI102582
Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 10000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not readily biodegradable.

Bio-accumulation Will not bio-accumulate.

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: >1000 mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: EC50: > 500 mg/l (Selenastrum capricornutum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

PolyCrystal

Page 4 of 6

HESI102583
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

The EPA Reportable Spill Quantity is well above quantities required for any expected

use of this product.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

PolyCrystal

Page 5 of 6

HESI102584
***END OF MSDS***

PolyCrystal

Page 6 of 6

HESI102585
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Potassium Chloride Solution

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Potassium Chloride Solution

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium chloride 7447-40-7 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

Potassium Chloride Solution

Page 1 of 5

HESI102586
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.7

Potassium Chloride Solution

Page 2 of 5

HESI102587
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Potassium Chloride Solution

Page 3 of 5

HESI102588
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Potassium Chloride Solution

Page 4 of 5

HESI102589
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Potassium Chloride Solution

Page 5 of 5

HESI102590
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: POTASSIUM CHLORIDE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: POTASSIUM CHLORIDE

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium chloride 7447-40-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

POTASSIUM CHLORIDE

Page 1 of 5

HESI102591
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to gray

Odor: Odorless

pH: 9.2

Specific Gravity @ 20 C (Water=1): 1.99

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 72.8

POTASSIUM CHLORIDE

Page 2 of 5

HESI102592
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 25.5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 74.5

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2430 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

POTASSIUM CHLORIDE

Page 3 of 5

HESI102593
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

POTASSIUM CHLORIDE

Page 4 of 5

HESI102594
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

POTASSIUM CHLORIDE

Page 5 of 5

HESI102595
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: POTASSIUM CHLORIDE SOLUTION,

SATURATED

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: POTASSIUM CHLORIDE SOLUTION, SATURATED

Synonyms: None

Chemical Family: Inorganic Salt

Application: Reagent

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium chloride 7447-40-7 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

POTASSIUM CHLORIDE SOLUTION, SATURATED

Page 1 of 5

HESI102596
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.7

POTASSIUM CHLORIDE SOLUTION, SATURATED

Page 2 of 5

HESI102597
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 72.55

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

POTASSIUM CHLORIDE SOLUTION, SATURATED

Page 3 of 5

HESI102598
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

POTASSIUM CHLORIDE SOLUTION, SATURATED

Page 4 of 5

HESI102599
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

POTASSIUM CHLORIDE SOLUTION, SATURATED

Page 5 of 5

HESI102600
HESI102601
HESI102602
HESI102603
HESI102604
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PropStopTM 225A

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PropStopTM 225A

Synonyms: None

Chemical Family: Alcohol

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Butyl lactate 138-22-7 1 - 5% 5 ppm Not applicable

Butyl glycidyl ether 2426-08-6 1 - 5% 3 ppm (S,SEN) 50 ppm

Epoxy resin 10 - 30% Not applicable Not applicable

Diethylene glycol monomethyl

ether

111-77-3 10 - 30% Not applicable Not applicable

Methanol 67-56-1 60 - 100% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. May cause allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

PropStopTM 225A

Page 1 of 6

HESI102605
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 54

Flash Point/Range (C): 12

Flash Point Method: CC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. May be ignited by heat, sparks

or flames. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Ground and

bond containers when transferring from one container to another. Avoid contact with

eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves. Viton gloves Butyl rubber gloves.

Skin Protection Rubber apron.

PropStopTM 225A

Page 2 of 6

HESI102606
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.92

Density @ 20 C (lbs./gallon): 7.66

Bulk Density @ 20 C (lbs/ft3): 57.3

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Prolonged contact with aluminum.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May be absorbed through the skin and produce effects similar to those caused by

inhalation and/or ingestion. May cause skin defatting with prolonged exposure. May

cause severe skin irritation. May cause an allergic skin reaction.

Eye Contact May cause severe eye irritation.

PropStopTM 225A

Page 3 of 6

HESI102607
Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions. May be fatal or

cause blindness if swallowed. May cause kidney damage.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause fetal damage and testicular effects. This product is a suspected carcinogen.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

PropStopTM 225A

Page 4 of 6

HESI102608
DOT

UN1866,Resin Solution, 3, II, (12 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (12 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (12 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Glycol Ethers//111-77-3

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1088 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

PropStopTM 225A

Page 5 of 6

HESI102609
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PropStopTM 225A

Page 6 of 6

HESI102610
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PropStopTM 225B

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PropStopTM 225B

Synonyms: None

Chemical Family: Alcohol

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Modified cycloaliphatic amine

adduct

Mixture 10 - 30% Not applicable Not applicable

Diethylene glycol monomethyl

ether

111-77-3 5 - 10% Not applicable Not applicable

Methanol 67-56-1 60 - 100% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

PropStopTM 225B

Page 1 of 6

HESI102611
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 54

Flash Point/Range (C): 11

Flash Point Method: TCC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. May be ignited by heat, sparks

or flames. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Ground and

bond containers when transferring from one container to another. Avoid contact with

eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves. Viton gloves Butyl rubber gloves.

Skin Protection Rubber apron.

PropStopTM 225B

Page 2 of 6

HESI102612
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.89

Density @ 20 C (lbs./gallon): 7.41

Bulk Density @ 20 C (lbs/ft3): 55.46

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): ~5.6

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause skin defatting with

prolonged exposure.

Eye Contact May cause moderate eye irritation.

PropStopTM 225B

Page 3 of 6

HESI102613
Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions. May be fatal or

cause blindness if swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause fetal damage and testicular effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 5628 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

PropStopTM 225B

Page 4 of 6

HESI102614
DOT

UN1866,Resin Solution, 3, II, (11 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (11 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (11 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Glycol Ethers//111-77-3

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 897 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

PropStopTM 225B

Page 5 of 6

HESI102615
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PropStopTM 225B

Page 6 of 6

HESI102616
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ReversaFoam Surfactant

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ReversaFoam Surfactant

Synonyms: None

Chemical Family: Blend

Application: Non-ionic Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Amine 60 - 100% Not applicable Not applicable

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May cause birth defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treatment should be directed at preventing absorption, administering to symptoms

as they occur, and providing supportive therapy.

ReversaFoam Surfactant

Page 1 of 6

HESI102617
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store away from acids. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

ReversaFoam Surfactant

Page 2 of 6

HESI102618
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Pungent

pH: 9.5 - 10.8

Specific Gravity @ 20 C (Water=1): 1.0927

Density @ 20 C (lbs./gallon): 9.1

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -20

Freezing Point/Range (C): -29

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.01

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): 0.04

Viscosity, Dynamic @ 20 C (centipoise): 105 - 255

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Do not expose to heat or store at temperatures above 120 F (49 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration can be a hazard if this material is swallowed. In

large amounts: May cause heart, kidney and brain disorders.

Aggravated Medical Conditions Liver disorders. Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, heart, blood and brain damage.

Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

ReversaFoam Surfactant

Page 3 of 6

HESI102619
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

ReversaFoam Surfactant

Page 4 of 6

HESI102620
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ReversaFoam Surfactant

Page 5 of 6

HESI102621
ReversaFoam Surfactant

Page 6 of 6

HESI102622
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SALT, EVAPORATED

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SALT, EVAPORATED

Synonyms: None

Chemical Family: Salt

Application: Bridging Agent

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

SALT, EVAPORATED

Page 1 of 5

HESI102623
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 5.2

Specific Gravity @ 20 C (Water=1): 2.16

SALT, EVAPORATED

Page 2 of 5

HESI102624
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 80

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 58.44

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

SALT, EVAPORATED

Page 3 of 5

HESI102625
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 1000 ppm (Oncorhynus mykiss)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

SALT, EVAPORATED

Page 4 of 5

HESI102626
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SALT, EVAPORATED

Page 5 of 5

HESI102627
MATERIAL SAFETY DATA SHEET – SODIUM CHLORIDE

CAUTION – MAY CAUSE SKIN AND EYE IRRITATION

INTREPID POTASH – MOAB, LLC

P.O. Box 1208, Moab, Utah 84532 • Office 435-259-7171 • FAX 435-259-7100

TRANSPORTATION EMERGENCIES: CALL(800)424-9300(CHEMTREC)

 HEALTH EMERGENCIES: CONTACT YOUR LOCAL POISON CENTER

1. PRODUCT INFORMATION 

TRADE NAME & SYNONYMS SALT FORMULA

NACL

CHEMICAL NAME Sodium chloride, Halite CHEMICAL FAMILY

Inorganic Salt

CAS NUMBER 7647-14-5

Listed in: ________OSHA SUBPART Z _______ACGIH TLV LISTS;_______NTP LIST;

________IARC MONOGRAPH; X NONE OF THE ABOVE

2. TYPICAL COMPOSITION % CAS#

INGREDIENTS

Sodium Chloride 98.5

Potassium chloride 1.3 7447-40-7

3. PHYSICAL DATA

BOILING POINT (°F) 2669 MELTING POINT (°F) 1474

VAPOR PRESSURE (mm Hg.) N/A SPECIFIC GRAVITY (H20-1) 2.17

VAPOR DENISTY (AIR-1) N/A PERCENT VOLATILE N/A

SOLUBILITY IN WATER 26.5% @ 77°F EVAPORATION RATE N/A

APPEARANCE White crystalline solid ODOR No

Odor

PH 6.7-7.3 OTHER 65 pounds per cubic foot loose

75 pounds per cubic foot tamped

4. FIRE AND EXPLOSIVE HAZARD INFORMATION

FLASH POINT (METHOD USED) Not Combustible FLAMMABLE LIMITS LEL

N/A

UEL

N/A

EXTINGUISHING MEDIA N/A

SPECIAL FIRE FIGHTING PROCEDURES Use self-contained breathing apparatus and full protective clothing when entering enclosed or

confined areas.

UNUSUAL FIRE AND EXPLOSION HAZARDS When bulk sodium chloride is heated to high temperatures, a vapor is emitted which is

Irritating to the eyes, particularly.

5. HEALTH INFORMATION

THRESHOLD LIMIT VALUE:

None Established. OHSA total nuisance dust limit of 15 mg/m3

 and a respirable faction of 15 mg/m3 and a respirable faction of 5

Mg/m3

. The ACGIH nuisance dust TLV of 10 mg/m3 for the 8 hour time weighted average applies.

EFFECTS OF OVEREXPOSURE:

EYE-irritant, SKIN-Slightly irritating. INHALATION-May irritate nose and upper respiratory tract. INGESTION-Large doses can irritate the

stomach. Low toxicity. (Toxicity LDSO Rat=3.75 g/kg).

EMERGENCY AND FIRST AID PROCEDURES:

EYE-Flush thoroughly with water. Seek medical attention if irritation persists.

SKIN-Wash thoroughly with soap and water.

INHALATION-Remove to fresh air. If discomfort continues, seek medical attention.

HESI102628
INGESTION-If person is conscious, give large amounts of water to drink and induce vomiting. Seek medical attention.

 (N/A = Not Applicable)

MATERIAL SAFETY DATA SHEET – SODIUM CHLORIDE

INTREPID POTASH - MOAB, LLC (continued)

6. REACTIVITY DATA

STABLE Yes SUBJECT TO HAZARDOUS POLYMERIZATION

 No

 CONDITIONS TO AVOID High temperatures CONDITIONS TO AVOID

None

HAZARDOUS DECOMPOSITION PRODUCTS None

INCOMPATIBILITY (Materials to Avoid) Strong acids-can cause release of toxic chloride gases.

7. SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:

Contain as a dry solid. Prevent large quantities from contact with waterways or vegetation.

WASTE DISPOSAL METHOD:

If uncontaminated, recover and reuse product. Consult State or Federal environmental regulatory agencies for acceptable disposal

Procedures and locations.

8. PERSONAL PROTECTION INFORMATION

EYE: Tight fitting goggles should be worn in dusty areas.

SKIN: If irritation occurs, long sleeves and impervious gloves should be worn.

RESPIRATORY: A NIOSH-approved dust respirator should be used when exposure exceeds the OSHA standard of 15 mg/m3

.

9. SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Causes corrosion of many common metals.

OTHER PRECAUTIONS: None

10. ADDITIONAL INFORMATION

Although the information contained herein is offered in good faith, SUCH INFORMATION IS EXPRESSLY GIVEN WITHOUT ANY WARRANTY

(EXPRESS OR IMPLIED) OR ANY GUARANTEE OF ITS ACCURACY OR SUFFICIENCY and is taken at the user’s sole risk. User is solely

responsible for determining the suitability of use in each particular situation. INTREPID POTASH – MOAB, LLC specifically DISCLAIMS ANY

LIABILITY WHATSOEVER FOR THE USE OF SUCH INFORMATION, including without limitation any recommendations which user may construe

and attempt to apply which may infringe or violate valid patents, licenses and/or copyright.

HESI102629
(REVISED 8/18/2004)

WORD/MY DOCS/FORMS/MSDS SALT(LB)

HESI102630
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - PREMIUM BROWN

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - PREMIUM BROWN

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

SAND - PREMIUM BROWN

Page 1 of 6

HESI102637
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

SAND - PREMIUM BROWN

Page 2 of 6

HESI102638
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.63 - 2.67

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 65

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - PREMIUM BROWN

Page 3 of 6

HESI102639
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - PREMIUM BROWN

Page 4 of 6

HESI102640
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SAND - PREMIUM BROWN

Page 5 of 6

HESI102641
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - PREMIUM BROWN

Page 6 of 6

HESI102642
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - PREMIUM WHITE

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - PREMIUM WHITE

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SAND - PREMIUM WHITE

Page 1 of 6

HESI102643
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

SAND - PREMIUM WHITE

Page 2 of 6

HESI102644
Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.63 - 2.67

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 65

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - PREMIUM WHITE

Page 3 of 6

HESI102645
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - PREMIUM WHITE

Page 4 of 6

HESI102646
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SAND - PREMIUM WHITE

Page 5 of 6

HESI102647
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - PREMIUM WHITE

Page 6 of 6

HESI102648
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - SPECIAL SCREENED

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - SPECIAL SCREENED

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SAND - SPECIAL SCREENED

Page 1 of 6

HESI102649
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

SAND - SPECIAL SCREENED

Page 2 of 6

HESI102650
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Tan

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 99.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 65

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - SPECIAL SCREENED

Page 3 of 6

HESI102651
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - SPECIAL SCREENED

Page 4 of 6

HESI102652
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

SAND - SPECIAL SCREENED

Page 5 of 6

HESI102653
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - SPECIAL SCREENED

Page 6 of 6

HESI102654
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - BRADY

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - BRADY

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SAND - BRADY

Page 1 of 6

HESI102631
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

SAND - BRADY

Page 2 of 6

HESI102632
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white to tan

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 93.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - BRADY

Page 3 of 6

HESI102633
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - BRADY

Page 4 of 6

HESI102634
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

SAND - BRADY

Page 5 of 6

HESI102635
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - BRADY

Page 6 of 6

HESI102636
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SandTrap® 350A

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SandTrap® 350A

Synonyms: None

Chemical Family: Not determined

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethanol 64-17-5 10 - 30% 1000 ppm 1000 ppm

Bisphenol A / Epichlorohydrin

resin

25068-38-6 10 - 30% Not applicable Not applicable

Bisphenol A / Novolac epoxy

resin

28906-96-9 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 1 - 5% 200 ppm 400 ppm

Methanol 67-56-1 5 - 10% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause blindness. May be absorbed

through the skin. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. Wash with soap and

water. Get medical attention if irritation persists. Remove contaminated shoes and

discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

SandTrap® 350A

Page 1 of 6

HESI102655
Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 63

Flash Point/Range (C): 17

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard. Vapors are

heavier than air and may accumulate in low areas. Vapors may travel along the

ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Butyl rubber gloves.

SandTrap® 350A

Page 2 of 6

HESI102656
Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): 65.43

Boiling Point/Range (F): Not DeterminedMin: > 149

Boiling Point/Range (C): Not DeterminedMin: > 65

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 11 (23C)

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines. Prolonged contact with

aluminum, lead, or zinc may liberate flammable hydrogen. Certain coatings, plastics,

and rubbers. Strong oxidizers.

Hazardous Decomposition

Products

Formaldehyde. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause an allergic skin

reaction. May cause skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion.

SandTrap® 350A

Page 3 of 6

HESI102657
Eye Contact May cause moderate eye irritation.

Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

SandTrap® 350A

Page 4 of 6

HESI102658
DOT

UN1866,Resin Solution, 3, II, (17.2 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (17.2 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (17.2 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 8932 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

SandTrap® 350A

Page 5 of 6

HESI102659
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SandTrap® 350A

Page 6 of 6

HESI102660
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SandTrap® 350B

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SandTrap® 350B

Synonyms: None

Chemical Family: Not determined

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethanol 64-17-5 10 - 30% 1000 ppm 1000 ppm

Glycol ether 30 - 60% Not applicable Not applicable

4,4`-Diaminodiphenyl sulfone 80-08-0 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 1 - 5% 200 ppm 400 ppm

Methanol 67-56-1 1 - 5% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause blindness. May be absorbed

through the skin. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. Wash with soap and

water. Get medical attention if irritation persists. Remove contaminated shoes and

discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

SandTrap® 350B

Page 1 of 6

HESI102661
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 69

Flash Point/Range (C): 20

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard. Vapors are

heavier than air and may accumulate in low areas. Vapors may travel along the

ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

SandTrap® 350B

Page 2 of 6

HESI102662
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): 65.43

Boiling Point/Range (F): Not DeterminedMin: > 149

Boiling Point/Range (C): Not DeterminedMin: > 65

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 8.3

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines. Prolonged contact with

aluminum, lead, or zinc may liberate flammable hydrogen. Certain coatings, plastics,

and rubbers. Strong oxidizers.

Hazardous Decomposition

Products

Formaldehyde. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause an allergic skin

reaction. May cause skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion.

Eye Contact May cause moderate eye irritation.

SandTrap® 350B

Page 3 of 6

HESI102663
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

SandTrap® 350B

Page 4 of 6

HESI102664
UN1866,Resin Solution, 3, II, (20.6 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (20.6 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (20.6 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

The EPA Reportable Spill Quantity is well above quantities required for any expected

use of this product.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

SandTrap® 350B

Page 5 of 6

HESI102665
Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SandTrap® 350B

Page 6 of 6

HESI102666
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Scalechek® HTM Scale Inhibitor

Revision Date: 06-May-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Scalechek® HTM Scale Inhibitor

Synonyms: None

Chemical Family: Polymer

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Organic acid salt Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician None known.

Scalechek® HTM Scale Inhibitor

Page 1 of 5

HESI102667
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 230

Flash Point/Range (C): Not DeterminedMin: > 110

Flash Point Method: Not Determined

Autoignition Temperature (F): 899

Autoignition Temperature (C): 481

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Physical Hazard 0 , PPE: B

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Slippery when wet.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

Odor: Odorless

pH: 8.27

Scalechek® HTM Scale Inhibitor

Page 2 of 5

HESI102668
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.44

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 43.2

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.095

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Oxides of nitrogen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2000 mg/kg (Rat)

Dermal Toxicity: LD50: > 3000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Scalechek® HTM Scale Inhibitor

Page 3 of 5

HESI102669
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Scalechek® HTM Scale Inhibitor

Page 4 of 5

HESI102670
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Scalechek® HTM Scale Inhibitor

Page 5 of 5

HESI102671
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Scalechek® LP-65 Scale Inhibitor

Revision Date: 13-Aug-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Scalechek® LP-65 Scale Inhibitor

Synonyms: None

Chemical Family: Blend

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 5 - 10% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

Scalechek® LP-65 Scale Inhibitor

Page 1 of 6

HESI102672
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): Not Determined

Flash Point Method: SFCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves.

Skin Protection Rubber apron. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

Scalechek® LP-65 Scale Inhibitor

Page 2 of 6

HESI102673
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Slight

pH: 6.5-7.5 (100%)

Specific Gravity @ 20 C (Water=1): 1.169-1.181

Density @ 20 C (lbs./gallon): 9.74-9.84

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 0

Freezing Point/Range (C): -17.8

Vapor Pressure @ 20 C (mmHg): 19.3 (21C)

Vapor Density (Air=1): > 1

Percent Volatiles: 59

Evaporation Rate (Butyl Acetate=1): <1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Ammonia. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation In high air concentrations:

May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause slight eye irritation.

Ingestion In large amounts: May be harmful if swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Scalechek® LP-65 Scale Inhibitor

Page 3 of 6

HESI102674
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Scalechek® LP-65 Scale Inhibitor

Page 4 of 6

HESI102675
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 6294 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

Scalechek® LP-65 Scale Inhibitor

Page 5 of 6

HESI102676
***END OF MSDS***

Scalechek® LP-65 Scale Inhibitor

Page 6 of 6

HESI102677
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Scalechek® SCP-2 Scale Inhibitor

Revision Date: 20-Aug-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Scalechek® SCP-2 Scale Inhibitor

Synonyms: None

Chemical Family: Silicate

Application: Scale Preventer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glassy calcium magnesium

phosphate

65997-17-3 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

Scalechek® SCP-2 Scale Inhibitor

Page 1 of 6

HESI102678
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

Scalechek® SCP-2 Scale Inhibitor

Page 2 of 6

HESI102679
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: Clear

Odor: Odorless

pH: 7-7.5

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Scalechek® SCP-2 Scale Inhibitor

Page 3 of 6

HESI102680
Toxicity Tests

Oral Toxicity: LD50: 2900 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Scalechek® SCP-2 Scale Inhibitor

Page 4 of 6

HESI102681
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

Scalechek® SCP-2 Scale Inhibitor

Page 5 of 6

HESI102682
***END OF MSDS***

Scalechek® SCP-2 Scale Inhibitor

Page 6 of 6

HESI102683
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 1 of 8

Material Safety Data Sheet

Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this

information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no

changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed

with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000,

HGS10000, HGS18000

MANUFACTURER: 3M

DIVISION: 3M Specialty Materials

ADDRESS: 3M Center

St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 08/14/2002

Supercedes Date: 04/29/2002

Document Group: 16-2219-0

Product Use:

Specific Use: Downhole Oil and Gas Applications

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by Wt

SODA LIME BOROSILICATE GLASS 65997-17-3 97 - 100

AMORPHOUS SILICA 7631-86-9 < 3

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Specific Physical Form: Low Density Fine Powder (less than 10 microns)

Odor, Color, Grade: White, Odorless

General Physical Form: Solid

3.2 POTENTIAL HEALTH EFFECTS

HESI102684
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 2 of 8

Eye Contact:

Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Skin Contact:

Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.

Inhalation:

Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose

and throat pain.

Prolonged or repeated exposure may cause:

Lung Effects: Signs/symptoms may include difficulty breathing, cough, wheezing, weakness, increased heart rate, bluish

colored skin (cyanosis), sputum production and changes in lung function tests.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.

Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature Not Applicable

Flash Point Not Applicable

HESI102685
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 3 of 8

Flammable Limits - LEL Not Applicable

Flammable Limits - UEL Not Applicable

5.2 EXTINGUISHING MEDIA

Non-combustible. Choose material suitable for surrounding fire. Material will not burn.

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure

demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for

exposed areas of the head.

Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition

information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more

information on handling and managing the spill. Ventilate the area with fresh air. Collect as much of the spilled material as possible.

Use wet sweeping compound or water to avoid dusting. Sweep up. Clean up residue. Place in a closed container approved for

transportation by appropriate authorities. Dispose of collected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to

local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. For industrial or

professional use only.

7.2 STORAGE

Store away from oxidizing agents.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS

Conduct air monitoring to determine adequacy of ventilation. Use with appropriate local exhaust ventilation.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection

Avoid eye contact.

The following eye protection(s) are recommended: Safety Glasses with side shields.

HESI102686
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 4 of 8

8.2.2 Skin Protection

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with

your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.

Gloves made from the following material(s) are recommended: Neoprene, Nitrile Rubber.

8.2.3 Respiratory Protection

Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

OSHA regulations: Half facepiece or fullface air-purifying respirator with P95 particulate filters. Consult the current 3M Respiratory

Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of Swallowing

 Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional Information

SODA LIME BOROSILICATE GLASS 3M TWA - as dust 10 mg/m3

AMORPHOUS SILICA CMRG TWA -

specific form

3 mg/m3 as respirable dust

SOURCE OF EXPOSURE LIMIT DATA:

 ACGIH: American Conference of Governmental Industrial Hygienists

 CMRG: Chemical Manufacturer Recommended Guideline

 OSHA: Occupational Safety and Health Administration

 AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Specific Physical Form: Low Density Fine Powder (less than 10 microns)

Odor, Color, Grade: White, Odorless

General Physical Form: Solid

Autoignition temperature Not Applicable

Flash Point Not Applicable

Flammable Limits - LEL Not Applicable

Flammable Limits - UEL Not Applicable

Boiling point Not Applicable

Density 0.12 - 0.63 g/ml

Vapor Density Not Applicable

Vapor Pressure Not Applicable

Specific Gravity 0.12 - 0.63

Melting point No Data Available

Solubility in Water Slight (less than 10%)

HESI102687
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 5 of 8

Evaporation rate Not Applicable

Volatile Organic Compounds Not Applicable

Percent volatile < 0.5 % weight

VOC Less H2O & Exempt Solvents Not Applicable

Viscosity Not Applicable

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid: None known

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance Condition

None known. Not Specified

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its

components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not Determined

CHEMICAL FATE INFORMATION

Not Determined

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Reclaim if feasible. For quantities <100 lbs. (50kg): dispose of waste product in a sanitary landfill. For

larger quantities: Dispose of waste product in a facility permitted to accept chemical waste.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.

HESI102688
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 6 of 8

SECTION 14:TRANSPORT INFORMATION

ID Number(s):

98-0212-2986-3, 98-0212-2987-1, 98-0212-2988-9, 98-0212-2989-7, 98-0212-2990-5, 98-0212-3010-1, 98-0212-3011-9, 98-

0212-3012-7, 98-0212-3013-5, 98-0212-3014-3, 98-0212-3015-0, 98-0212-3016-8, 98-0212-3017-6, 98-0212-3018-4, 98-0212-

3019-2, 98-0212-3038-2, 98-0212-3039-0, 98-0212-3040-8, 98-0212-3085-3, 98-0212-3086-1, 98-0212-3087-9

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this

material.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

STATE REGULATIONS

Contact 3M for more information.

CHEMICAL INVENTORIES

This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.

Contact 3M for more information.

INTERNATIONAL REGULATIONS

Contact 3M for more information.

ADDITIONAL INFORMATION

HESI102689
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 7 of 8

This product is an article as defined by TSCA, EINECS, CDSL, MITI, KECI, AICS, PICCS and CICS regulations, and is exempt

from chemical inventory listing requirements. Korea and China also require product registration.

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard Classification

Health: 1 Flammability: 0 Reactivity: 0 Special Hazards: None

National Fire Protection Association Hazard Codes are designed for use by firefighters, sheriffs, or other emergency response teams who are

concerned with the hazards of burning or exploding materials. These NFPA codes are not intended to address the hazards of this product other than in

a fire situation.

HMIS Hazard Classification

Health: 1 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.

HMIS codes are intended for use in everyday workplace settings to provide a rapid indication of the occupational hazards associated with chemicals

used in the workplace.

Revision Changes:

Section 1: Product use information was modified.

Section 16: NFPA hazard classification for health was modified.

Section 3: Potential effects from inhalation information was modified.

Section 5: Fire fighting procedures information was modified.

Section 6: Release measures information was modified.

Section 7: Handling information was modified.

Section 7: Storage information was modified.

Section 8: Engineering controls information was modified.

Section 13: Waste disposal method information was modified.

Section 8: Eye/face protection information was modified.

Section 8: Respiratory protection - recommended respirators information was modified.

Section 4: First aid for ingestion (swallowing) information was modified.

Section 16: NFPA explanation was modified.

Section 9: Density information was modified.

Sections 3 and 9: Odor, color, grade information was modified.

Section 9: Property description was modified.

Section 9: Specific gravity information was modified.

Section 8: Skin protection - protective clothing text was modified.

Section 15: WHMIS regulations comment was added.

Section 15: WHMIS regulations comment heading was added.

Section 7: Storage comment was deleted.

Section 3: Immediate other hazard(s) was deleted.

Section 15: Ingredient comment heading was deleted.

Section 15: Inventories comment was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M

HESI102690
3M MATERIAL SAFETY DATA SHEET Scotchlite TMGlass Bubbles HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS10000,

HGS18000 08/14/2002

 Page 8 of 8

MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY

OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF

TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of

use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely

within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a

particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may

have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

 3M MSDSs are available at www.3M.com

HESI102691
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SEM-8TM EMULSIFIER

Revision Date: 08-May-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SEM-8TM EMULSIFIER

Synonyms: None

Chemical Family: Alcohol Blend

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium Salt of

Ethoxylated Alcohol Sulfate

60 - 100% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

SEM-8TM EMULSIFIER

Page 1 of 6

HESI102692
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 93

Flash Point/Range (C): 33.9

Flash Point Method: SFCC ASTM D-3828

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store in a dry location. Store in a cool well ventilated area.

Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves. Use Viton or 4H gloves.

SEM-8TM EMULSIFIER

Page 2 of 6

HESI102693
Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Alcohol

pH: 7.0-8.5 @ 5%

Specific Gravity @ 20 C (Water=1): 1.054

Density @ 20 C (lbs./gallon): 8.8

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -20

Freezing Point/Range (C): -29

Vapor Pressure @ 20 C (mmHg): 15.7

Vapor Density (Air=1): > 1

Percent Volatiles: 12

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 71-79 (25C)

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 1.4

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May cause skin defatting with prolonged exposure.

Eye Contact May cause severe eye irritation.

SEM-8TM EMULSIFIER

Page 3 of 6

HESI102694
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions. May affect the heart and cardiovascular system.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability COD: 149 mg O2 per 100 ppm product

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 342 mg/l (Scophthalamus maximus)

Acute Crustaceans Toxicity:TLM48: 23.3 mg/l (Acartia tonsa)

Acute Algae Toxicity: EC50: 78 mg/l (Skeletonema costatum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (33.9 C)

SEM-8TM EMULSIFIER

Page 4 of 6

HESI102695
(Contains Isopropanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (33.9 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (33.9 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

SEM-8TM EMULSIFIER

Page 5 of 6

HESI102696
Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SEM-8TM EMULSIFIER

Page 6 of 6

HESI102697
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SILICALITE - COMPACTED

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SILICALITE - COMPACTED

Synonyms: None

Chemical Family: Not applicable

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Silica, amorphous - fumed 7631-86-9 60 - 100% 2 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

SILICALITE - COMPACTED

Page 1 of 5

HESI102698
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Gray to black

Odor: Odorless

pH: 7

Specific Gravity @ 20 C (Water=1): 2.3

Density @ 20 C (lbs./gallon): Not Determined

SILICALITE - COMPACTED

Page 2 of 5

HESI102699
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 22

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: >8

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.09

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3160 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

SILICALITE - COMPACTED

Page 3 of 5

HESI102700
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

SILICALITE - COMPACTED

Page 4 of 5

HESI102701
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SILICALITE - COMPACTED

Page 5 of 5

HESI102702
SINTER BLAST

Chemical Characteristic Mineralogical Characteristic

Al2O3 (Aluminum Oxide)........ 76,1% Corundum, alfa-Al2O3

SiO2 (Silicon Dioxide)........... 4,40% Hematite, alfa-Fe2O3

TiO2 (Titanium Dioxide)........ 1,40% Maghemite, Fe2O3

Fe2O3 (Iron Oxide)................ 15,4%

CaO (Calcium Oxide)........... 1,55%

K2O (Potassium Oxide) ......... 0,20%

Sieve Analysis (%)

#8/16 #12/20 #20/40 #30/70 #60/120 #120/180G

#6 0

#8 0,6 0

#12 49,7 0,5

#16 45,6 57,6 0

#20 3,9 39,4 0,5

#30 2,3 58,3 0

#40 39,3 3,3

#50 1,7 0,5

#60 89,9 0,8

#70 5,4 14,8

#80 32,8 0,1

#100 1,1 1,0

#120 46,3

#140 50,2

#170 4,1 33,9

#230 13,2

Finos 0,2 0,2 0,2 0,3 0,7 1,6

Physical Characteristics

Bulk Density (g/cm3) 2,01 2,02 2,07 1,99 1,83 1,70

HESI102703
HESI102704
HESI102705
HESI102706
HESI102707
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SODA ASH F.G.

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SODA ASH F.G.

Synonyms: None

Chemical Family: Carbonate

Application: Additive

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium carbonate 497-19-8 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SODA ASH F.G.

Page 1 of 5

HESI102708
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from acids. Store in a cool, dry location. Product has a shelf life of 36

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White to off white

Odor: Odorless

pH: 11.5

SODA ASH F.G.

Page 2 of 5

HESI102709
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 48- 62

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 105.99

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 4220 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

SODA ASH F.G.

Page 3 of 5

HESI102710
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 385 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

SODA ASH F.G.

Page 4 of 5

HESI102711
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SODA ASH F.G.

Page 5 of 5

HESI102712
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SODIUM HYPOCHLORITE SOLUTION

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SODIUM HYPOCHLORITE SOLUTION

Synonyms: None

Chemical Family: Inorganic

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hypochlorite 7681-52-9 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SODIUM HYPOCHLORITE SOLUTION

Page 1 of 6

HESI102713
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Releases oxygen at high temperatures. Decomposition in fire may produce toxic

gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 2 , Oxidizing agent

HMIS Ratings: Health 3, Flammability 0, Reactivity 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from reducing agents. Store in a cool well

ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SODIUM HYPOCHLORITE SOLUTION

Page 2 of 6

HESI102714
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Pungent

pH: 11.2-11.4

Specific Gravity @ 20 C (Water=1): 1.14

Density @ 20 C (lbs./gallon): 9.50

Bulk Density @ 20 C (lbs/ft3): 11.2-11.4

Boiling Point/Range (F): 85

Boiling Point/Range (C): 29

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Reducing agents. Contact with metals. Ammonium compounds.

Hazardous Decomposition

Products

Hydrogen chloride. Chlorine. Hypochlorous acid.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

SODIUM HYPOCHLORITE SOLUTION

Page 3 of 6

HESI102715
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1791,Hypochlorite Solution(10% Available Chlorine), 8, III

RQ (Sodium Hypochlorite - 454 kg.)

NAERG 154

Canadian TDG

Hypochlorite Solution(10% Available Chlorine), 8, UN1791, III

ADR

UN1791,Hypochlorite Solution(10% Available Chlorine), 8, III

Air Transportation

SODIUM HYPOCHLORITE SOLUTION

Page 4 of 6

HESI102716
ICAO/IATA

UN1791,Hypochlorite Solution, 8, III

(10% Available Chlorine)

RQ (Sodium Hypochlorite - 454 kg.)

Sea Transportation

IMDG

UN1791,Hypochlorite Solution(10% Available Chlorine), 8, III

RQ (Sodium Hypochlorite - 454 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 105 Gallons based on Sodium hypochlorite (CAS:

7681-52-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

C Oxidizing Materials

SODIUM HYPOCHLORITE SOLUTION

Page 5 of 6

HESI102717
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SODIUM HYPOCHLORITE SOLUTION

Page 6 of 6

HESI102718
HESI102719
HESI102720
HESI102721
HESI102722
HESI102723
HESI102724
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SSA-1

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SSA-1

Synonyms: None

Chemical Family: Sand

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SSA-1

Page 1 of 6

HESI102725
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

SSA-1

Page 2 of 6

HESI102726
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.63

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 70

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.09

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SSA-1

Page 3 of 6

HESI102727
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SSA-1

Page 4 of 6

HESI102728
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

SSA-1

Page 5 of 6

HESI102729
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SSA-1

Page 6 of 6

HESI102730
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SUPER CBL ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SUPER CBL ADDITIVE

Synonyms: None

Chemical Family: Metal Powder

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum 7429-90-5 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause delayed injury to lungs.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

SUPER CBL ADDITIVE

Page 1 of 6

HESI102731
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 350

Flash Point/Range (C): Not DeterminedMin: > 176

Flash Point Method: Not Determined

Autoignition Temperature (F): 1202

Autoignition Temperature (C): 650

Flammability Limits in Air - Lower (%): 0.04

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Sand. Do NOT use water or carbon dioxide or other liquids on aluminum fires.

Special Exposure Hazards Flammable dust when in finely divided and highly suspended state. Avoid stirring

burning aluminum. Shut off electricity. Isolate material. Ring sand around fire to

contain.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 1

HMIS Ratings: Health 0, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store away from acids. Store away from alkalis. Store

away from water. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Silver

Odor: Odorless

pH: Not Determined

SUPER CBL ADDITIVE

Page 2 of 6

HESI102732
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.7

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 72

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from any contact with water.

Incompatibility (Materials to

Avoid)

Contact with water. Strong acids. Strong alkalis. Strong oxidizers. Halogenated

compounds.

Hazardous Decomposition

Products

Flammable hydrogen gas. Metal oxides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause lung damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

SUPER CBL ADDITIVE

Page 3 of 6

HESI102733
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

SUPER CBL ADDITIVE

Page 4 of 6

HESI102734
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum//7429-90-5

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B6 Reactive Flammable Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

SUPER CBL ADDITIVE

Page 5 of 6

HESI102735
***END OF MSDS***

SUPER CBL ADDITIVE

Page 6 of 6

HESI102736
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SuperFlo 2000

Revision Date: 27-Oct-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SuperFlo 2000

Synonyms: None

Chemical Family: Surfactant Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Methanol 67-56-1 5 - 10% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. May cause allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SuperFlo 2000

Page 1 of 6

HESI102737
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 86

Flash Point/Range (C): 30

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Ground and

bond containers when transferring from one container to another. Avoid contact with

eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing mist.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirators have a short service life.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

SuperFlo 2000

Page 2 of 6

HESI102738
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Straw

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.99

Density @ 20 C (lbs./gallon): 8.25

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -20

Freezing Point/Range (C): -29

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and contribute to the

symptoms listed under ingestion. May cause skin defatting with prolonged exposure.

May cause an allergic skin reaction.

Eye Contact May cause moderate eye irritation.

SuperFlo 2000

Page 3 of 6

HESI102739
Ingestion May be fatal or cause blindness if swallowed. May cause headache, dizziness,

nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Aspiration can be a hazard if this material is swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

May adversely affect or disrupt reproductive development or other hormonally

controlled processes in both humans and animals.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

SuperFlo 2000

Page 4 of 6

HESI102740
DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, III, (30 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, UN1993, III, (30 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Methanol, Terpenes Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, III, (30 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5914 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

SuperFlo 2000

Page 5 of 6

HESI102741
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

D2A Very Toxic Materials

D2B Toxic Materials

B2 Flammable Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SuperFlo 2000

Page 6 of 6

HESI102742
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: TARCHEK

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: TARCHEK

Synonyms: None

Chemical Family: Blend

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 30 - 60% 5 mg/m3 5 mg/m3

Naphthalene 91-20-3 5 - 10% 10 ppm 10 ppm

1,2,4 Trimethylbenzene 95-63-6 1 - 5% 25 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

TARCHEK

Page 1 of 6

HESI102743
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 158

Flash Point/Range (C): 70

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a well ventilated area. Keep from heat, sparks,

and open flames. Keep container closed when not in use. Product has a shelf life of

24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

TARCHEK

Page 2 of 6

HESI102744
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.908

Density @ 20 C (lbs./gallon): 7.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 2.54

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Lung disorders.

TARCHEK

Page 3 of 6

HESI102745
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause central nervous system and brain

effects. Repeated overexposure may cause liver and kidney effects. Contains

petroleum distillates which have been shown to cause skin cancer in laboratory

animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

TARCHEK

Page 4 of 6

HESI102746
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

Ethyl Benzene//100-41-4

Xylene//1330-20-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 244 Gallons based on Xylene (CAS: 1330-20-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1B Toxic Materials

TARCHEK

Page 5 of 6

HESI102747
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

TARCHEK

Page 6 of 6

HESI102748
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

HESI102749
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

HESI102750
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

HESI102751
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

HESI102752
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: TETRASODIUM EDTA LIQUID

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: TETRASODIUM EDTA LIQUID

Synonyms: None

Chemical Family: Blend

Application: Chelating agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylenediaminetetraacetic

acid, tetrasodium salt

64-02-8 30 - 60% Not applicable Not applicable

Nitrilotriacetic acid, trisodium

salt monohydrate

5064-31-3 1 - 5% Not applicable Not applicable

Sodium hydroxide 1310-73-2 1 - 5% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Potential carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

TETRASODIUM EDTA LIQUID

Page 1 of 6

HESI102753
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White, opaque

Odor: Odorless

pH: 12

Specific Gravity @ 20 C (Water=1): 1.31

Density @ 20 C (lbs./gallon): 10.91

TETRASODIUM EDTA LIQUID

Page 2 of 6

HESI102754
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 380.2

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation.

Eye Contact Causes severe eye irritation

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains a small amount (< 1%) of nitrilotriacetic acid, which is listed as a suspect

carcinogen of the urinary tract and kidneys by NTA, based on feeding studies with

laboratory animals. According to the ACGIH guidelines, NTA would "not be

considered an occupational carcinogen of any significance."

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

TETRASODIUM EDTA LIQUID

Page 3 of 6

HESI102755
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 0.02 g/g COD: 0.54 g/g Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 410 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3266,Corrosive Liquid, Basic, Inorganic, N.O.S.(Contains Sodium Hydroxide, Ethylenediaminetetraacetic Acid), 8, III

NAERG 154

Canadian TDG

Corrosive Liquid, Basic, Inorganic, N.O.S.(Contains Sodium Hydroxide, Ethylenediaminetetraacetic Acid), 8, UN3266, III

ADR

UN3266,Corrosive Liquid, Basic, Inorganic, N.O.S.(Contains Sodium Hydroxide, Ethylenediaminetetraacetic Acid), 8, III

Air Transportation

ICAO/IATA

UN3266,Corrosive Liquid, Basic, Inorganic, N.O.S., 8, III

(Contains Sodium Hydroxide, Ethylenediaminetetraacetic Acid Solution)

TETRASODIUM EDTA LIQUID

Page 4 of 6

HESI102756
Sea Transportation

IMDG

UN3266,Corrosive Liquid, Basic, Inorganic, N.O.S.(Contains Sodium Hydroxide, Ethylenediaminetetraacetic Acid), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

Nitrilotriacetic Acid//139-13-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 9165 Gallons based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

TETRASODIUM EDTA LIQUID

Page 5 of 6

HESI102757
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

TETRASODIUM EDTA LIQUID

Page 6 of 6

HESI102758
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ULTRAPROP PROPPANT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ULTRAPROP PROPPANT

Synonyms: None

Chemical Family: Silicate

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Silica, amorphous fused 60676-86-0 1 - 5% 10 mg/m3 0.1 mg/m3

Titanium dioxide 13463-67-7 1 - 5% 10 mg/m3 15 mg/m3

Iron oxide 1309-37-1 1 - 5% 5 mg/m3 10 mg/m3

Aluminum oxide 1344-28-1 60 - 100% 10 mg/m3 10 mg/m3

Aluminum silicate 1302-76-7 10 - 30% Not applicable 15 mg/m3

Crystalline silica, cristobalite 14464-46-1 1 - 5% 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

ULTRAPROP PROPPANT

Page 1 of 7

HESI102759
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use.

ULTRAPROP PROPPANT

Page 2 of 7

HESI102760
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark brown

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.17

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 114

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 228.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

ULTRAPROP PROPPANT

Page 3 of 7

HESI102761
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

ULTRAPROP PROPPANT

Page 4 of 7

HESI102762
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

ULTRAPROP PROPPANT

Page 5 of 7

HESI102763
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum Oxide//1344-28-1

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

ULTRAPROP PROPPANT

Page 6 of 7

HESI102764
***END OF MSDS***

ULTRAPROP PROPPANT

Page 7 of 7

HESI102765
VersaLiteTM

1. Chemical Name & Company Identification

PRODUCT NAME: VersaLiteTM (all mesh sizes)

SYNONYM(S): Ceramic Proppant

CHEMICAL FAMILY: Aluminosilicate

MANUFACTURER: Saint-Gobain Proppants

5300 Gerber Road

Fort Smith, Arkansas 72904

24-Hour Emergency (479) 782-2001

2. Component Information

CHEMICAL NAME COMMON NAME % BY WEIGHT (TYPICAL)

Aluminum Silicate Mullite 50-90

Aluminum Oxide Corundum 10-50

3. Hazards Identification

3.1 Emergency Overview 

HMIS RATING

Health: 1. (Slight)

Flammability: 0. (Minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

INHALATION: Prolonged exposure to dusts may cause respiratory 

tract irritation.

INGESTION: No known adverse effects.

EYE CONTACT: May cause irritation on prolonged or repeated contact.

SKIN CONTACT: May cause irritation on prolonged or repeated contact.

4.0 First Aid Measures

INGESTION: Seek medical attention if large quantities are ingested.

INHALATION: Remove to fresh air.

EYE CONTACT: Immediately flush eyes with large quantities of

water. Call a physician if irritation persists.

5.0 Fire Fighting Measures

FLASH POINT: Nonflammable

LOWER EXPLOSION LIMIT: Not applicable

UPPER EXPLOSION LIMIT: Not applicable

AUTOIGNITION TEMPERATURE: Not applicable

Use extinguishing agent suitable 

for type of surrounding fire.

6.0 Accidental Release Measures

SPILLS: No special procedures are required for cleanup of spills or 

leaks. Spherical shape of spilled pellets can create a slip hazard.

7.0 Handling and Storage

Store under dry conditions. Handle with adequate ventilation.

Use a NIOSH/MSHA approved respirator if dust is present.

Material Safety Data Sheet

FOR INDUSTRIAL USE ONLY

HESI102766
8.0 Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creation of dust.

8.2 Personal Protection

Use NIOSH/MSHA approved respiratory protective

equipment when airborne concentrations exceed

acceptable criteria. Wear safety glasses at all times 

to prevent eye irritation.

8.3 Exposure Guidelines

INGREDIENT CAS# %/ OSHA ACGIH-TWA TLV

WT PEL/TWA

Corundum 1302-44-56 10-50 15mg/m3 (Total) 10mg/m3 (Total) 

5mg/m3 (Resp) 3mg/m3 (Resp)

Aluminum 

Silicate 1302-76-7 50-90 15mg/m3 (Total) 10mg/m3 (Total) 

5mg/m3 (Resp) 3mg/m3 (Resp)

9.0 Physical and Chemical Properties

APPEARANCE: Grayish brown to black

free-flowing granules

ODOR: None

FLASH POINT: N/A This material does

not give a flash point by 

conventional methods.

STABILITY: Stable

SPECIFIC GRAVITY: 2.75-2.95

PH: Not applicable

VAPOR PRESSURE @ 25 ̊C: Not applicable

VISCOSITY: Not applicable

SOLUBILITY IN WATER: Nonsoluble

BOILING POINT: Not applicable

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1)

11. Toxicological Information

SEE SECTION 3

LC50 Not available

LD50 Not available

12. Ecological Information

Not determined

13. Disposal Conditions

Dispose of according to local, state/provincial,

and federal requirements.

14. Transportation Information

14.1 U.S. Department of Transportation

Non-regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated

15. U.S Regulatory Information (Selected Regulations)

SARA TITLE III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA): N/A

CERCLA Reportable Quantity: None

Clean Air AmendmentsHazardous Air Pollutants: None

California State Proposition 65: N/A

16. Other Information

The OSHA Hazard Communication Standard 29CFR 1910.1200

requires that the information contained on these sheets be

made available to your workers. Instruct your workers to 

handle this product properly. Consult with appropriate

experts to guard against hazards associated with use of this

product and its ingredients.

Disclaimer

Seller makes no warranty, expressed or implied, concerning 

the product or the merchantability or fitness thereof for any

purpose, except that the product conforms to contracted 

specifications, and that the product does not infringe any

valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the

quantity of product in respect of which damages are claimed.

In no event shall seller be liable for incidental or consequential damages, whether buyer’s claim is based on contract,

breach of warranty, negligence or otherwise.

ISSUE DATE: 7-May-2009

Tel: 479.782.2001

Toll Free: 800.643.2149

Fax: 479.782.9984

www.proppants.saint-gobain.com

5300 Gerber Road

Fort Smith, AR 72904

HESI102767
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: VERSASET

Revision Date: 19-Aug-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: VERSASET

Synonyms: None

Chemical Family: Mineral

Application: Cement Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium aluminate 1302-42-7 60 - 100% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause skin and respiratory irritation. May cause eye burns.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

VERSASET

Page 1 of 6

HESI102768
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove. Do NOT spread spilled product with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a dry location. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

VERSASET

Page 2 of 6

HESI102769
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 11.5

Specific Gravity @ 20 C (Water=1): 2.3

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 50

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 6

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 82

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation.

Eye Contact May cause eye burns. May cause permanent eye damage.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

VERSASET

Page 3 of 6

HESI102770
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Dispose of container according to national or local regulations. Do NOT reuse

container.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted by surface modes.

Canadian TDG

Not restricted by surface modes.

ADR

 Not restricted by surface modes.

Air Transportation

ICAO/IATA

 Not restricted by surface modes.

UN2812, Sodium Aluminate, Solid, 8, III

Sea Transportation

VERSASET

Page 4 of 6

HESI102771
IMDG

 Not restricted by surface modes.

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

VERSASET

Page 5 of 6

HESI102772
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

VERSASET

Page 6 of 6

HESI102773
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-20 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-20 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-20 GELLING AGENT

Page 1 of 6

HESI102774
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 932

Autoignition Temperature (C): 500

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.29

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Slippery when wet. Avoid contact with eyes, skin, or clothing. Avoid creating or

inhaling dust. Avoid dust accumulations.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

WG-20 GELLING AGENT

Page 2 of 6

HESI102775
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White to light straw

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.4

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 40

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 9400 mg/kg (Rat)

WG-20 GELLING AGENT

Page 3 of 6

HESI102776
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

WG-20 GELLING AGENT

Page 4 of 6

HESI102777
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

WG-20 GELLING AGENT

Page 5 of 6

HESI102778
***END OF MSDS***

WG-20 GELLING AGENT

Page 6 of 6

HESI102779
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-22 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-22 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-22 GELLING AGENT

Page 1 of 5

HESI102780
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

WG-22 GELLING AGENT

Page 2 of 5

HESI102781
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bean

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.3

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 42

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WG-22 GELLING AGENT

Page 3 of 5

HESI102782
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WG-22 GELLING AGENT

Page 4 of 5

HESI102783
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-22 GELLING AGENT

Page 5 of 5

HESI102784
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WS-36M

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WS-36M

Synonyms: None

Chemical Family: Fatty-Acid

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Benzenesulfonic acid, C10-

16-alkyl derivs., potassium

salts

68584-27-0 1 - 5% Not applicable Not applicable

Fatty acid, tall oil, hexa esters

with sorbitol, ethoxylated

61790-90-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

WS-36M

Page 1 of 5

HESI102785
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Nitrile gloves. Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

WS-36M

Page 2 of 5

HESI102786
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear amber

Odor: Mild sweet

pH: 5.1 (5%(75%IPA/25% H20))

Specific Gravity @ 20 C (Water=1): 1.011

Density @ 20 C (lbs./gallon): 8.42

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): .093

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Respiratory disorders. Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

WS-36M

Page 3 of 5

HESI102787
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

WS-36M

Page 4 of 5

HESI102788
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WS-36M

Page 5 of 5

HESI102789
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WS-44 EMULSIFYING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WS-44 EMULSIFYING AGENT

Synonyms: None

Chemical Family: Blend

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Xylene 1330-20-7 1 - 5% 100 ppm 100 ppm

Ethoxylated nonylphenol 30 - 60% Not applicable Not applicable

Ethyl benzene 100-41-4 1 - 5% 100 ppm 100 ppm

Naphthalene 91-20-3 0 - 1% 10 ppm 10 ppm

Heavy aromatic petroleum

naphtha

64742-94-5 30 - 60% 5 mg/m3 5 mg/m3

Isopropanol 67-63-0 1 - 5% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May cause allergic skin reaction. Repeated overexposure may cause

liver and kidney effects. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

WS-44 EMULSIFYING AGENT

Page 1 of 6

HESI102790
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 115

Flash Point/Range (C): 46

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.8

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Avoid spraying water directly into storage containers due to danger of boilover.

Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

WS-44 EMULSIFYING AGENT

Page 2 of 6

HESI102791
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Persons with

hypersensitivity to alkyl phenol surfactants should avoid all contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Hydrocarbon

pH: 7.5

Specific Gravity @ 20 C (Water=1): 0.98

Density @ 20 C (lbs./gallon): 8.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 330

Boiling Point/Range (C): 165

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 5

Vapor Density (Air=1): 5

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): 0.1

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

WS-44 EMULSIFYING AGENT

Page 3 of 6

HESI102792
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. This material is an anesthetic. May cause central

nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity This product contains significant amounts of polynuclear aromatic hydrocarbons

(PNA). Certain PNAs have been shown to cause skin cancer in laboratory animals

and may also cause cancer of the lungs and other sites. Contains petroleum

distillates which have been shown to cause skin cancer in laboratory animals.

Formaldehyde and possibly paraformaldehyde may react with hydrochloric acid to

form bis-chloromethyl ether, a known human carcinogen. Repeated overexposure

may cause liver and kidney effects. Prolonged or repeated exposure may cause

embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

WS-44 EMULSIFYING AGENT

Page 4 of 6

HESI102793
Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (46.1 C)

(Contains Petroleum Naphtha)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Petroleum Naphtha), 3, UN1993, III, (46.1 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Petroleum Naphtha), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Petroleum Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Petroleum Naphtha), 3, III, (46.1 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

WS-44 EMULSIFYING AGENT

Page 5 of 6

HESI102794
EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethoxylated Nonylphenol (9016-45-9)

Ethyl Benzene//100-41-4

Isopropanol//67-63-0

Naphthalene//91-20-3

Xylene//1330-20-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 613 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WS-44 EMULSIFYING AGENT

Page 6 of 6

HESI102795
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: X-CIDE 102 BIOCIDE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: X-CIDE 102 BIOCIDE

Synonyms: None

Chemical Family: Aldehyde

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glutaraldehyde 111-30-8 10 - 30% 0.05 ppm Not applicable

Isopropanol 67-63-0 20 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May cause allergic skin and respiratory reaction. Repeated overexposure

may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage.

X-CIDE 102 BIOCIDE

Page 1 of 6

HESI102801
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 82

Flash Point/Range (C): 27

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Use only competent persons for cleanup.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep container closed when not in use. Product has a

shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

X-CIDE 102 BIOCIDE

Page 2 of 6

HESI102802
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Characteristic

pH: 4

Specific Gravity @ 20 C (Water=1): 0.99

Density @ 20 C (lbs./gallon): 8.25

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause damage to nasal and respiratory

passages. May cause central nervous system depression including headache,

dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,

giddiness and unconsciousness.

May cause liver damage. May cause kidney damage. May cause allergic

respiratory reaction.

Skin Contact May cause skin burns. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause liver and kidney

damage.

Aggravated Medical Conditions Skin disorders. Lung disorders.

X-CIDE 102 BIOCIDE

Page 3 of 6

HESI102803
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 790 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (27.8 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (27.8 C)

X-CIDE 102 BIOCIDE

Page 4 of 6

HESI102804
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (27.8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

X-CIDE 102 BIOCIDE

Page 5 of 6

HESI102805
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

X-CIDE 102 BIOCIDE

Page 6 of 6

HESI102806
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: XANVIS L

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: XANVIS L

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cellulose derivative 30 - 60% Not applicable 15 mg/m3

Xanthan gum 11138-66-2 30 - 60% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

XANVIS L

Page 1 of 5

HESI102796
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 156

Flash Point/Range (C): 68

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas. Slippery when wet.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Slippery when wet. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Tan

XANVIS L

Page 2 of 5

HESI102797
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Mild

pH: 7

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 356

Boiling Point/Range (C): 180

Freezing Point/Range (F): -5

Freezing Point/Range (C): -21

Vapor Pressure @ 20 C (mmHg): 0.01

Vapor Density (Air=1): >1

Percent Volatiles: 43

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

XANVIS L

Page 3 of 5

HESI102798
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

XANVIS L

Page 4 of 5

HESI102799
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

XANVIS L

Page 5 of 5

HESI102800
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XRTTM AcFrac® Gold, all sizes Version: 2 Printed: 01/15/2004 

1/6

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: XRTTM AcFrac® Gold, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: XRTTM AcFrac® Gold, all sizes 

PRODUCT CODE: 341930GEN 

PRODUCT TYPE: Resin-coated frac sand 

APPLICATION: Oil/Gas Well Proppant 

SOLD UNDER BORDEN U.S. PATENT NUMBERS 4,694,905, 

4,722,991, 6,528,157 & PATENTS PENDING 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

14808-60-7 *Quartz (SiO2) 70.0 - 100.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Golden, free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

HESI102807
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3.2 Potential Health Effects

Immediate Hazards 

INGESTION: Not expected to be harmful under normal conditions of use. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

14808-60-7 Quartz (SiO2)

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an 

increased incidence of significant disease endpoints such as scleroderma (an immune system disorder 

manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also 

reported to increase the risk of tuberculosis. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

HESI102808
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XRTTM AcFrac® Gold, all sizes Version: 2 Printed: 01/15/2004 

3/6

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact. Wear safety glasses with sideshields at all times to prevent eye 

irritation.

8.3 Exposure Guidelines 

14808-60-7 Quartz (SiO2) 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction; A2 - 

Suspected Human Carcinogen 

OSHA PEL 8-hr TWA 10/(%SiO2+

2) mg/m3 

respirable dust 

8-hr TWA 30/(%SiO2+

2) mg/m3 

total dust 

Remanded TWA 0.1 mg/m3 respirable dust; 1989 PEL 

remanded, but in effect in some 

HESI102809
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XRTTM AcFrac® Gold, all sizes Version: 2 Printed: 01/15/2004 

4/6

states 

NIOSH 8-hr TWA 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline Silica 

9. Physical and Chemical Properties 

Appearance Golden, free flowing granules 

Odor Odorless 

Odor threshold Not available 

Specific gravity 2.5 - 2.6 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Solubility in water Negligible 

Octanol/water partition coefficient Not available 

Vapor pressure Not available 

Vapor density Not available 

Evaporation rate Not available 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

Conditions to avoid: 

Avoid exposure to direct sunlight for long periods of time.

Incompatibilities: 

Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

14808-60-7 Quartz (SiO2) 

LC50: Not available

LD50: Not available

12. Ecological Information 

Not determined 

HESI102810
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XRTTM AcFrac® Gold, all sizes Version: 2 Printed: 01/15/2004 

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13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

HESI102811
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6/6

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI102812