# Documents in Support of a

Significant New Use Rule for

Premanufacture Notice (PMN) P-14-0821

Docket ID Number

EPA-HQ-OPPT-2015-0220

# Table of Contents

1. Sanitized SAT Report for P-14-0821

2. Sanitized Engineering Report for P-14-0821

3. Sanitized Exposure Report for P-14-0821

# Sanitized SAT Report for P-14-0821

## SAT Report

PMN Number: P-14-0821

SAT Date: 9/11/2014

Related cases :

Health related cases:

Ecotox related cases:

Concern levels :



### Type of Concern: Health Eco Comments

Level of Concern: 2-3 2

Persistence Bioaccum Toxicity Comments

2 12

Exposure Based Review :

Health: N o

Ecotox: N o

Routes of exposure : Health: Dermal Drinking Water Inhalation

Ecotox: All releases to water

Fate: ;

Keywords :

Keywords: SENSIT; MUTA; ONCO; DEVEL; REPRO; LIVER; KIDNEY;

UNCERT NEURO

Summary of Assessment :

Fate :

Fate Summary: P-14-0821

FATE:

Solid with MP = 151-153 C (M)

log Kow = -3.39 (E)

S > 10 g/L at 25 C (E)

VP < 1.0E-6 torr at 25 C (E)

BP = Dec. >170 C (Analog)

H < 1.00E-8 (E)

log Koc = 0.87 (E)

log Fish BCF = 0.50 (E)

### Ecotox Factors Comments:

SAT Chair: Viktor Morozov

# Sanitized Engineering Report for P-14-0821

### INITIAL REVIEW ENGINEERING REPORT

PMN: 14-0821

USE:

Number of Sites/ Location: 1

Industrial Specialty Chemicals Harvey IL 60426

Days/yr: 200

# Sanitized Exposure Report for P-14-082110/24/2014 Page of



### POST FOCUS EXPOSURE REPORT

Chemical ID: P -14-0821 Reviewer: Kwon/EN

Results Table: Dose, Concentration, and Days Exceeded Results Summary

Exposure Scenario 1 Water Landfill Stack Air Fugitive Air

Release activity(ies) 2 ;

exposure c alculation(s) 3 Drinking Water Fish Ingestion 7Q10 4

CC = 28 PDM

Days

Exceeded LADD ADR LADD ADR LADD

ADR LADD ADR LADD

mg/k g/day mg/kg/day mg/kg/day mg/kg/day μg/l # Days mg/kg/day mg/kg/day mg/kg/day mg/kg/day mg/kg/day

MFG: Max ADR: max

acute eco 4.04E

- 04

--- 2.18E

- 05

--- 1.85E+01

--- --- --- --- --- ---

MFG: PDM1

--- --- --- --- 1.85E+01

--- --- --- --- ---

MFG: Max L ADD

--- 5.96E

- 06

--- 1.36E

- 07

--- --- --- --- --- --- ---

USE: Max LADD

--- --- --- --- --- --- 1.25E

- 04

--- --- --- ---

1 Exposure scenario titles consist of release activity followed by exposure calculation abbreviation.

2 Release activities are from engineering report's Manufacturing (Mfg), Processing (Proc) and Use release activity labels.

Multiple release activities are combined in one exposure scenario if their releases occur at same location.

3 Exposure calculations are Acute Dose Rate (ADR), Li fetime Average Daily Dose (LADD), and Probabilistic Dilution

Model (PDM). There may be one, two, or all three exposure calculations per exposure scenario.

CC is the aquatic concentration of concern.

4 This column displays concentration values for the 7Q10 streamflow, which is defined as the average daily streamflow

of the seven consecutive days of lowest flow within a ten year period.

Remarks :10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID : P- 14

- 0821 Assessor: Kwon/EN

ENVIRONMENTAL RELEAS ES

Scenario#: 1 Number of Release Sites:

Release Activity: MFG: Max ADR

Release Description: WATER LANDFILL

Non

- sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non

- sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day ) (kg/site/day) (kg/site/day)

Remarks:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID : P- 14

- 0821

SIC -C ODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 1 Number of Sites: RELEASE ACTIVITY: MFG:

Max ADR

SIC

- CODE DESCRIPTION:

SIC

- CODE (S): EXPOSED POPULATION: Adult

WWT

REMOVAL

(%) REL EASE

DAYS PRETREATMENT

RELEASE

(kg/site/day) POSTTREATMENT

RELEASE

(kg/site/day) DWT

(%) BCF

(L/kg)

0.00 3.16

AQUATIC EXPOSURE ESTIMATES

- SURFACE WATER

PLANT

TYPE % ILE

FACILITY STREAM FLOW (MLD) STREAM CONC. (μg/l)

Harmonic

Mean 30Q5 7Q10 1Q10 Harmonic

Mean 30Q5 7Q10 1Q10

ALL 50 3.54E

- 02 0.11 0.16 0.19

ALL 10 1.98 10.66 18.48 22.08

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES

Exposure Units Drinking Water Results Drinking

Water Units Fish Ingestion Results Fish

Ingestion

Units

50% 10% 50% 10%

Cancer

LADD pot 1.07E

- 07 5.96E

- 06 mg/kg/day 2.43E

- 09 1.36E

- 07 mg/kg/day

LADC pot 8.20E

- 06 4.58E

- 04 mg/L 2.59E

- 05 1.45E

- 03 mg/kg

Acute

ADR pot 4.05E

- 06 4.04E

- 04 mg/kg/day 3.90E

- 07 2.18E

- 05 mg/kg/day

SIC Code Comments:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID : P- 14

- 0821 Assessor: Kwon/EN

ENVIRONMENTAL RELEASES

Scenario#: 2 Number of Release Sites

Release Activity: MFG: PDM1

Release Description: WATER LANDFILL

Non

- sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non

- sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day ) (kg/site/day) (kg/site/day)

Remarks:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID: P- 14

- 0821

SIC CODE EXPOSURES TO SURFACE WATER RELEASES

SCENARIO # : 2 RELEASE ACTIVITY: MFG: PDM1

S IC CODE DESCRIPTION:

ASSOCIATED SIC CODES:

SIC CODE RESULTS

COC (μg/L) Percent of

Year COC

Exceeded Number of

Days COC

Exceeded Release

days/year Loading

(kg/site/day) Waste Water

Treatment (%) High/Avg

Analysis

28.00 High10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID : P- 14

- 0821 Assessor: Kwon/EN

ENVIRONMENTAL RELEASES

Scenario#: 3 Number of Release Sites:

Release Activity: MFG: Max LADD

Release Description: WATER LANDFILL

Non

- sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non

- sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/s ite/day) (kg/site/day ) (kg/site/day) (kg/site/day)

Remarks:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID : P- 14

- 0821

SIC

- CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES

SCENARIO #: 3 Number of Sites: RELEASE ACTIVITY: MFG :

Max LADD

SIC

- CODE DESCRIPTION:

SIC

- CODE (S): EXPOSED POPULATION: Adult

WWT

REMOVAL

(%) RELEASE

DAYS PRETREATMENT

RELEASE

(kg/site/day) POSTTREATMENT

RELEASE

(kg/site/day) DWT

(%) BCF

(L/kg)

0.00 3.16

AQUATIC EXPOSURE ESTIMATES

- SURFACE WATER

PLANT

TYPE % ILE

FACILITY STREAM FLOW (MLD) STREAM CONC. (μg/l)

Harmonic

Mean 30Q5 7Q10 1Q10 Harmonic

Mean 30Q5 7Q10 1Q10

ALL 50 N/A N/A N /A N/A

ALL 10 N/A N/A N/A N/A

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES

Exposure Units Drinking Water Results Drinking

Water Units Fish Ingestion Results Fish

Ingestion

Units

50% 10% 50% 10%

Cancer

LADD pot 1.07 E- 07 5.96E

- 06 mg/kg/day 2.43E

- 09 1.36E

- 07 mg/kg/day

LADC pot 8.20E

- 06 4.58E

- 04 mg/L 2.59E

- 05 1.45E

- 03 mg/kg

Acute

ADR pot N/A N/A mg/kg/day N/A N/A mg/kg/day

SIC Code Comments:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID : P- 14

- 0821 Assessor: Kwon/EN

ENVIRONMENTAL RELEASES

Scenario#: 4 Number of Release Sites:

Release Activity: USE: Max LADD

Release Description: WATER LANDFILL

Non

- sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non

- sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day ) (kg/site/day) (kg/site/day)

Remarks:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID: P- 14

- 0821

DRINKING WATER EXPOSURE ESTIMATES FROM LANDFILL RELEASES

SCENARIO #: 4 ACTIVITY: USE: Max LADD

RELEASE DESCRIPTION:

EXPOSED POPULATION: Adult

NUMBER

OF

SITES NON

- SLUDGE

LANDFILL

RELEASE AND

DAYS OF

RELEASE

(kg/site/day ) /(days) LANDFI LLED

SLUDGE 1

AND DAYS OF

RELEASE

(kg/site/day ) /(days) MIGRATION

DESCRIPTOR 2 ADSORPTION

TO

WASTEWATER

SLUDGE

(%) DRINKING

WATER

TREATMENT

(%)

0.00 0. 00

1 Landfilled sludge equals the fraction adsorbed to wastewater treatment sludge times the surface

water pre

- treatment release.

2 Migration Descriptor Log Koc Groundwater Concentration (GWC)

(mg/L per kg release)

Negl igible no migration None

Negligible to slow > 4.5 3.21E

- 6

Slow <4.5 to 3.5 2.67E

- 5

Moderate <3.5 to 2.5 5.95E

- 5

Rapid <2.5 7.55E

- 5

Exposure Units Results ASSUMPTIONS

ED

(years) AT

(years) BW

(kg) IR

(L/day)

Cancer

LADD pot (mg/kg/day) 1.25E

- 04 33.00 78.00 80.00 1.04

LADC pot (mg/L) 9.58E

- 03 33.00 78.00 NA NA

REMARKS:10/24/2014 Page of

POST FOCUS EXPOSURE REPORT

Chemical ID: P

- 14

- 0821

DRINKING WATER EXPOSURE ESTIMATES FROM LANDFILL RELEASES

SCENARIO #: 4 ACT IVITY: USE: Max LADD

RELEASE DESCRIPTION:

EXPOSED POPULATION: Adult

NUMBER

OF

SITES NON

- SLUDGE

LANDFILL

RELEASE AND

DAYS OF

RELEASE

(kg/site/day ) /(days) LANDFILLED

SLUDGE 1

AND DAYS OF

RELEASE

(kg/site/day ) /(days) MIGRATION

DESCRIPTOR 2 ADSORPTI ON

TO

WASTEWATER

SLUDGE

(%) DRINKING

WATER

TREATMENT

(%)

0.00 0. 00

1 Landfilled sludge equals the fraction adsorbed to wastewater treatment sludge times the surface

water pre

- treatment release.

2 Migration Descriptor Log Koc Groundwater Concentration (GWC)

(mg/L per kg release)

Negligible no migration None

Negligible to slow > 4.5 3.21E

- 6

Slow <4.5 to 3.5 2.67E

- 5

Moderate <3.5 to 2.5 5.95E

- 5

Rapid <2.5 7.55E

- 5

Exposure Units Results ASSUMPTIONS

ED

(years) AT

(years) BW

(kg) IR

(L/day)

Cancer

LADD pot (mg/kg/day) 1.25E

- 04 33.00 78.00 80.00 1.04

LADC pot (mg/L) 9.58E

- 03 33.00 78.00 NA NA

REMARKS: