Date Report Issued: May 24, 2010

AGRIUM U. S., INC.

KENNEWICK FERTILIZER OPERATIONS (KFO)

KENNEWICK, WASHINGTON

PLANT #9 NITRIC ACID PLANT STACK

NSPS INFORMATION COLLECTION REQUEST

MARCH 31, 2010

ATAQ PROJECT #2803-008

HCG, Inc. d.b.a. AmTest Air Quality

Preston, Washington
CERTIFICATIONS

SENIOR REPORT REVIEW

I certify that the information contained herein is accurate, complete, and representative of 

the actual emissions to the best of my knowledge.

Kris A. Hansen, QEP

Senior Consultant

I certify that the information contained herein is accurate, complete, and representative of 

the actual emissions to the best of my knowledge.

Angela F. Hansen, QSTI

Principal Scientist

TEST TEAM LEADER

I certify that the information contained herein is accurate, complete, and representative of 

the actual emissions to the best of my knowledge.

Ken B. Allmendinger

Senior Test Lead

HCG, Inc. d.b.a. AmTest Air Quality

Preston, Washington
Name and Address of Facility

Agrium U.S., Inc.

Kennewick Fertilizer Operations

Plant #9

227515 Bowles Road

Kennewick, Washington 99337

Name, Address, and Contact for the Facility

Mr. Thomas J. Klein

Environmental Specialist

Agrium U.S., Inc.

Kennewick Fertilizer Operations

227515 E. Bowles Rd.

Kennewick, WA 99336-0618

Tel: 509-586-5488

tklein@agrium.com

Emission Units Tested

Plant #9 Stack

Date of Performance Tests

March 31, 2010

Name, Address, and Contact for Source Testing Consultant

Mr. Ken Allmendinger

Senior Test Lead

AmTest Air Quality, a Division of Hoefler Consulting Group

PO Box 525

Preston, Washington 98050

Tel: 425-222-7746

Fax: 425-222-7849

kallmendinger@hoeflernet.com
i

TABLE OF CONTENTS

Pages

1.0 INTRODUCTION 1-2

2.0 SUMMARY OF RESULTS 3-6

Summary of Pollutants, Methods, Dates and Times 4

2.1 EPA Methods 1, 2, 3A, 4, and 320 - Nitrogen Oxides (NOx) Emissions 5-6

Summary of Results - EPA Methods 3A and 320 6

3.0 PROJECT OVERVIEW/EXCEPTIONS 7-8

4.0 SOURCE AND CEMS DESCRIPTION 9

5.0 SAMPLING AND ANALYSIS PROCEDURES 10-17

5.1 EPA Methods 1 and 2 - Velocity, Temperature and Airflow 10

5.2 EPA Method 3A - Molecular Weight and Oxygen 10-13

5.3 EPA Method 4 - Moisture 13-14

5.4 EPA Method 320 – Nitrogen Oxides Using FTIR 14-17

6.0 QUALITY ASSURANCE PLAN 18-22

6.1 Calibration Procedures and Frequency 18-21

6.2 Sample Recovery and Field Documentation 21

6.3 Data Reduction, Validation and Reporting 21-22

7.0 METHODOLOGY REFERENCES 23

APPENDIX A - Computer Printouts of Results 24-37

Summary of Results - EPA Methods 1, 2, 3A, and 4 25-27

EPA Methods 1, 2, 3A, and 4 Results, Runs 1-9 28-36

Summary of Reference FTIR Results 37

APPENDIX B - Process Data 38-45

Copy of Section 114 ICR Letter 39-42

Letter to Allow Method 320 43

Copy of Emission Test Template (ETT) Sent to EPA 44

Production Rate Data 45

APPENDIX C - Example Calculations and Field Data Sheets 46-106

Example Calculation - Moisture and Airflow 47-48

Example Calculation - NOx Gaseous Emission Rate Using Method 320 49

Stack Schematic and Location of Sample Points - Velocity and Temperature Traverse 50

Velocity and Temperature Traverse Data Sheets 51-53

Method 4 Moisture Data Sheets 54-56

Sample Train Information Data Sheet, Method 4 57

Analyzer Configuration Data Sheet 58

Response Time Test 59

STRATA Configuration 60-62
ii

TABLE OF CONTENTS (continued)

Pages

APPENDIX C - Example Calculations and Field Data Sheets (continued) 46-106

Calibration Error Test 63

Initial System Bias Check 64

1-Minute O2 and CO2 STRATA Data 65-82

Continuous Analyzer Checklist 83

Gas Cylinder Checklist 84-85

FTIR Quality Assurance Data (Pre and Post Test Cals and Dynamic Spiking) 86-87

EPA Method 320 Spike Recovery Data 88

FTIR Reference Method Data, Runs 1-9 (averaged) 89-106

APPENDIX D - Miscellaneous Supporting Information 107-159

Figure 1. Methods 3A, 6C, 7E, and 10 Sample Train Schematic 108

Figure 2. EPA Method 4 Sample Train Schematic 109

Figure 2. EPA Method 320 Sample System Schematic 110

Method 1 - Location of Traverse Points 111

Method 1 - Minimum Number of Traverse Points 112

Method 2 - Stack Gas Velocity and Volumetric Flow Calculations 113

Method 3 - Molecular Weight and Excess Air Calculations 113

Method 4 - Stack Gas Moisture Calculations 114

Nomenclature - Method 5 Calculations 115-116

Alternative Method 5 Post-Test Calibration Procedure 117-118

Dry Gas Meter Calibration Information 119-121

Standard Dry Gas Meter Calibration Information 122-124

Type S Pitot Tube Inspection Data Form 125

Thermocouple Calibration Data Sheet 126

Alternative Method 2 Thermocouple Calibration Procedure 127

NIST-Traceable Calibration Certificates 128

CAI Series 600 O2 and CO2 Analyzer Specifications 129-135

FTIR Specifications 136-139

Calibration Gas Certificates 140-146

Professional Resumes of Project Personnel 147-155

AmTest Air Quality Capabilities 156-159
1.0

INTRODUCTION

Agrium U.S., Inc. contracted AmTest Air Quality (ATAQ) of Preston, Washington, a 

Division of Hoefler Consulting Group, to measure emissions of nitrogen oxides (NOx) 

from the Plant #9 stack at Agrium’s Kennewick Fertilizer Operations (KFO) acid plant in 

Kennewick, Washington. This testing was in response to an information collection 

request (ICR) that the U.S. Environmental Protection Agency (EPA) sent to nitric acid 

production facilities asking them to conduct emission testing by May 2, 2010. Plant #9 is 

a nitric acid plant which was constructed in 1977 and is subject to federal new source 

performance standards (NSPS) contained in 40 CFR 60, Subpart G. The facility is 

regulated by the Benton Clean Air Agency (BCAA) under Title V air operating permit 

#05-0002 dated July 11, 2008. This ICR testing was performed on March 31, 2010. 

Testing and analysis procedures used for this project are presented in the EPA document 

Title 40, Code of Federal Regulations, Part 60 (40 CFR 60), Appendix A, Methods 1, 2, 

3A, and 4; in 40 CFR 63, Appendix A, Method 320; and on the EPA Technology 

Transfer Network Emission Measurement Center (EPA-TTN-EMC) website, Test 

Methods Section www.epa.gov/ttn/emc/. EPA Methods 1 and 2 were performed to 

measure the stack gas velocity and temperature for calculating the volumetric flow rate. 

EPA Method 3A was performed to measure concentrations of oxygen (O2) and carbon 

dioxide (CO2) in the stack gas for calculating the molecular weight and correcting 

emissions for dilution air. EPA Method 4 was performed to measure the moisture content 

of the stack gas. EPA Method 7E was performed to measure the NOx concentration in the 

stack gas using a chemiluminescent analyzer. EPA EPA Method 320 was performed to 

measure the NOx concentration in the stack gas using Fourier Transform Infrared 

Spectroscopy (FTIR). 

1
Mr. Ken B. Allmendinger, Mr. Daniel R. Soderberg, and Mr. Ryan D. Radonski of 

ATAQ performed field testing. ATAQ’s laboratory, technical writing, and management 

staff performed the sample recovery, data reduction, report preparation, and quality 

assurance review. Mr. Thomas Klein of Agrium U.S., Inc. coordinated this project and 

provided process data.

2
2.0

SUMMARY OF RESULTS

The following section of this report presents relative accuracy comparisons for the 

CEMS. Refer to the Table of Contents to locate specific information. Appendix A 

contains reference method (RM) data. Appendix B contains process data. Appendix C 

contains example calculations of results and copies of the original field data sheets. 

Appendix D contains miscellaneous supporting information. An overview of the quality 

assurance requirements; discussions of any exceptions to the test plan, sampling, or 

analysis; and/or any process difficulties may be found in Section 3.0, “Project 

Overview/Exceptions.” 

A table detailing the method performed, the test dates, run times is included on the 

following page in a table titled “Summary of Pollutants, Methods, Dates and Times.” 

On September 16, 2009 the EPA issued Guideline Document 51F (revised September 18, 

2009) and asked data for Information Collection Requests to be flagged as follows: 

• BDL (below detection level) - all analytical values used to calculate and report an 

in-stack emissions value are less than the laboratory’s reported detection level(s)

• DLL (detection level limited) - at least one but not all values used to calculate and 

report an in-stack emissions value are less than the laboratory’s reported detection 

level(s)

• ADL (above detection level) - all analytical values used to calculate and report an 

in-stack emissions value are greater than the laboratory’s reported detection 

level(s)

The data presented in the accompanying Emission Test Template (ETT) is presented 

using these flags. EPA also requested that zeros not be used in sums and averages and 

that the in-stack detection limit be used for reporting non-detects. 

3
SUMMARY OF POLLUTANTS, METHODS, DATES AND TIMES

Pollutant Method Run # Date Time

Velocity, Airflow, and EPA Methods 1, 2 and 3A 1 (1) 3/31/10 1302-1323

Molecular Weight 1 (2) 3/31/10 1339-1400

1 (3) 3/31/10 1410-1431

2 (4) 3/31/10 1450-1511

2 (5) 3/31/10 1522-1543

2 (6) 3/31/10 1554-1615

3 (7) 3/31/10 1643-1704

3 (8) 3/31/10 1714-1735

3 (9) 3/31/10 1745-1806

Moisture EPA Method 4 1 3/31/10 1302-1430

2 3/31/10 1450-1614

3 3/31/10 1643-1805

Nitrogen Oxides EPA Method 320 1 3/31/10 1304-1431

2 3/31/10 1450-1615

3 3/31/10 1643-1806

EPA Method 1, 2, 3A, and 4 testing was performed concurrent with Method 320 testing. Three 

60-minute Method 4 tests were performed as part of a RATA; during each Method 4 test three 

Method 2 velocity and temperature traverses were performed; the three Method 4 and the nine 

Method 2 and 3A runs were grouped into three 63-minute runs. Nine 21-minute M320 tests 

were performed as part of a RATA; the nine runs were grouped into three 63-minute compliance 

runs. 

4
2.1 EPA Methods 1, 2, 3A, 4, and 320 - Nitrogen Oxides (NOx) Emissions 

Nitrogen oxides (NOx) emission data were collected on March 31, 2010 during the annual 

relative accuracy test audit (RATA) for the Plant #9 continuous emissions monitoring 

(CEMS) system. To report data to demonstrate compliance with the ICR, compliance test 

data were obtained by averaging three 21-minute RATA runs, making each compliance 

run length 63 minutes. A summary table detailing the RATA run and compliance run 

times is located in Appendix A of this report. The compliance test data are summarized 

in the following computer printout titled “Summary of Results - EPA Methods 3A and 

320.” 

NOx emission concentrations were recorded continuously during each test period in wet 

parts per million (ppm) using Fourier Transform Infrared Spectroscopy (FTIR). NOx

emission concentrations are considered to be the sum of the individual NO and NO2

concentrations. Percent (%) levels of O2 and CO2 were also measured continuously using 

Method 3A instrumental analyzers. NOx emission concentrations were converted to dry 

ppm corrected to 0% O2. NOx emission rates were calculated in pounds per hour (lb/hr). 

NOx emission factors were calculated in pounds per ton (lb/ton). The stack gas velocity, 

temperature, molecular weight, and moisture data collected using Methods 2, 3A, and 4 

were used to calculate the volumetric flow rate (airflow) in standard cubic feet per minute 

(scf/min) to use in lb/hr emission rate calculations. Because the airflow used to convert 

the wet ppm NOx concentrations to lb/hr and lb/ton was also on a wet basis (standard 

cubic feet per minute (scfm)), the lb/hr and lb/ton are on a dry basis. The lb/hr emission 

rates were converted to pounds per ton (lb/ton) emission factors using acid production 

data in tons per day supplied by Agrium. 

5
File Name: 2803-008\Agrium Plant 9 - M1-4, M320

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Run 

Run 1 Run 2 Run 3 Run 4 Run 5 Run 6 Run 7 Run 8 Run 9 *R

Date: 3/31/10 3/31/10 3/31/10 3/31/10 3/31/10 3/31/10 3/31/10 3/31/10 3/31/10 3/3

Reference Method Start Time: 1304 1339 1410 1450 1522 1554 1643 1714 1745 

Reference Method Stop Time: 1325 1400 1431 1511 1543 1615 1704 1735 1806 

Reference Method Sample Length (minutes): 21 21 21 21 21 21 21 21 21 

Oxygen (%): 5.5 5.5 5.6 5.5 5.5 5.6 5.6 5.5 5.4 

Oxygen Correction (%): 0 0 0 0 0 0 0 0 0 

Percent Moisture (%): 0.27 0.27 0.27 0.05 0.05 0.05 0.23 0.23 0.23 

Moisture (Bws): 0.0027 0.0027 0.0027 0.0005 0.0005 0.0005 0.0023 0.0023 0.0023 0.0

Stack Temperature (°F): 309.8 314.8 310.4 310.7 310.4 308.8 309.8 308.6 309.0 3

Measured Airflow (acfm): 71832 69504 68886 70372 71019 71937 70764 70267 70498 70

Measured Airflow (scf/min): 48176 46309 46160 47141 47590 48309 47460 47198 47327 46

Measured Airflow (dscf/min): 48046 46184 46036 47118 47567 48286 47353 47092 47221 46

Production Rate (tons/hr): 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 

EPA METHOD 320 (FTIR) - NITROGEN OXIDES (NOX)

NOX Emission Concentration (ppm-wet): 40.0 37.4 36.8 36.8 37.5 37.3 36.8 36.5 36.0 

NOX Emission Concentration (ppm-dry): 39.9 37.3 36.7 36.8 37.4 37.3 36.7 36.4 36.0 

NOX Emission Concentration @ 0 % O2 ppm: 54.2 50.5 50.0 50.1 50.7 50.9 50.2 49.4 48.6 

NOX Emission Rate (lb/hr) (dry): 13.8 12.4 12.2 12.4 12.8 12.9 12.5 12.3 12.2 

NOX Emission Factor (lb/ton) (dry): 0.585 0.526 0.515 0.527 0.541 0.547 0.530 0.523 0.518 0

* Runs 1-3 are used for compliance Run 1; Runs 4-6 are used for compliance Run 2; Runs 7-9 are used for compliance Run 3.

SUMMARY OF RESULTS - EPA METHODS 3A AND 320

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Plant #9 Stack
3.0

PROJECT OVERVIEW/EXCEPTIONS

An acceptable leak check of less than 0.02 cfm at the highest vacuum rate (or greater) 

used during the test preceded and followed each moisture test. Acceptable calibration 

error and sampling system bias checks were obtained for the gaseous emission tests. 

Section 5.4 of this report discusses the quality assurance procedures performed for 

Method 320. 

Since the data for this project was collected during an annual RATA, three Method 3A 

and 320 RATA runs were averaged together for each compliance run. One 60-minute 

moisture run was performed during each three Method 3A and 320 RATA runs. Velocity 

and temperature data were also collected during each RATA run.

All NOx values measured for this project were above the detection limit (ADL). The 

FTIR analyst does not calculate a specific detection limit when the specific analyt is 

found at significant levels. The analyst did estimate that a conservative detection limit for

NOx would be approximately 1 ppm-wet. This value was used to calculate the detection 

limit for each run and is included in brackets in the emission test template (ETT) being 

used to report data to the EPA. 

When this project was originally scheduled, ATAQ was planned to use Method 7E to 

demonstrate compliance with the Section 114 Information Collection Request (ICR) letter 

dated February 2, 2010 that Agrium received. On March 24, 2010, EPA approved the use 

of EPA Method 320 in lieu of Method 7 for nitric acid plants, so Agrium elected to use 

Method 320 data for the ICR instead of Method 7E. 

7
ATAQ used two approved EPA alternative calibration procedures for this project. The 

first procedure is Alternative Method 009 (ALT-009) titled “Alternative Method 5 PostTest Calibration.” This procedure uses a calculation to check the meter box calibration 

factor rather than requiring a physical post-test meter box calibration using a standard dry 

gas meter. The average calculated meter box percent (%) error for the tests resulted in a 

percent error of within ±5% as allowed by Alternative Method 009; therefore, a physical 

post-test meter box calibration was not required. The second procedure ATAQ used is 

Alternative Method 011 (ALT-011) titled “Alternative Method 2 Thermocouple 

Calibration Procedure.” This procedure involves a single-point in-field check using a 

reference thermometer to confirm that the thermocouple used to measure the stack gas 

temperature was operating properly. This check eliminates the need to conduct a twopoint post-test calibration.

8
4.0

SOURCE AND CEMS DESCRIPTION

Agrium U. S., Inc. owns and operates the Kennewick Fertilizer Operations (KFO) Plant 

located east of Kennewick, Washington. Agrium U. S., Inc.’s business is the manufacture 

and wholesale distribution of nitrogen fertilizer products. Plant #9 is one of three nitric 

acid plants at the facility, which are used to produce a weak nitric acid solution. On 

March 31, 2010 Agrium produced 566.9 tons 100% nitric acid basis, or 23.6 tons per 

hour. Process data provided by Agrium is included in Appendix B of this report. 

9
5.0

SAMPLING AND ANALYSIS PROCEDURES

5.1 EPA Methods 1 and 2 - Velocity, Temperature, and Airflow

EPA Method 1 procedures were used to assure that representative measurements of 

volumetric flow rate were obtained by dividing the cross-section of the stack or duct into 

a number of equal areas, and then locating a traverse point within each of the equal areas. 

Refer to the “Stack Schematic and Location of Sample Points” data sheet and/or the 

figure titled, “Location of Sampling Ports and Traverse Points,” located in the appendices 

of this report, for a schematic of the stack and the point locations selected for testing. 

EPA Method 2 was performed to measure the stack gas velocity using a type S or a 

standard pitot tube, and the gas temperature using a calibrated thermocouple probe 

connected to a digital thermocouple indicator. The pitot tubes were connected with 

tubing to an oil-filled inclined manometer, a Shortridge Instruments, Inc. Air Data 

Multimeter ADM-850, which is a special low flow pressure measurement device, or 

magnehelic gauges to obtain velocity measurements. The pitot tube lines were leakchecked and the pressure measurement device was leveled and zeroed prior to use. A 

check for cyclonic flow was performed in each stack prior to beginning a series of test. 

Calibration information for each pressure and temperature measurement device used are 

included in the appendices of this report. 

5.2 EPA Method 3A - Molecular Weight and Oxygen (O2) 

EPA Method 3A was performed to determine the molecular weight of the stack gas based 

on percent-level measurements of the concentration of oxygen (O2) and carbon dioxide 

(CO2). Average percent O2 data was also used to correct emission concentrations for 

dilution air using EPA Method 3B procedures. EPA Method 3A uses instrumental 

analyzers to measure O2 and CO2. A paramagnetic analyzer was used to measure the 

10
percent (%) O2 and a non-dispersive infrared (NDIR) analyzer was used to measure the % 

CO2. The manufacturer and model number for the specific analyzers used for this test 

were recorded on a form titled “Continuous Analyzer Checklist,” which is included in the 

appendices of this report. This form was used to determine which analyzer specifications 

to include in the appendices of this report. Several EPA Protocol No. 1 calibration gases 

were utilized to check the calibration of the analyzers used for this test. A form titled 

“Gas Cylinder Checklist” is included in the appendices of this report. This form was used 

to determine which certificates of analysis to include in the appendices of this report. 

The Method 3A sample system is illustrated in the figure titled “EPA Method 3A, 6C, 7E, 

and 10 Sample Train” in the appendices of this report. Reference method samples were 

collected at three measurement points in one of the sample ports. The gaseous emission 

probe was moved to three points across the stack during each test, which were 16.7, 50.0, 

and 83.3 percent of the measurement line. An effluent gas sample was drawn through a 

stainless steel sampling probe and out-of-stack filter, which were sufficiently heated to 

prevent condensation. A sampling tee was connected to the inlet of the probe for the 

purpose of introducing calibration gas to flood the probe. The gas sample passed through 

a refrigerator-type moisture removal system, which continuously removed condensate 

from the sample gas. A Teflon sample line was used to transport the gas sample to the 

continuous monitoring system. A Teflon-coated leak-free pump was utilized to pull the 

sample gas through the system at a flow rate sufficient to minimize the response time of 

the measurement system. A sample flow rate control valve and rotameter were used to 

maintain a constant sampling rate within 10 percent. Prior to testing, probes, sample 

tubing, conditioning equipment, analyzers, and pumps were determined to be leak-free. 

The sampling system was leak checked by capping off the end of the sample line and 

pulling at least 10 inches of mercury (Hg) vacuum in the system and observing the 

rotameter drop to zero. 

11
After the measurement system was prepared for use, a calibration error check was 

performed by introducing low-level, mid-level, and high-level EPA Protocol No. 1 

calibration gases to the measurement system upstream of the analyzers. No adjustments 

were made to the system except those necessary to achieve the correct calibration gas 

flow rate to the analyzers. A data acquisition system named STRATA recorded the 

responses and calculated whether the concentration displayed by the analyzers exceeded ± 

2% of the span for any of the calibration gases. If this specification was exceeded, the 

data was flagged by STRATA and the analyzer calibration error check was repeated until 

acceptable performance was achieved.

Before the first run, a sampling system bias check was performed by introducing 

calibration gases at the sampling tee installed at the outlet of the sampling probe. The 

low-level gas and either the mid-level or high-level gas, whichever most closely 

approximated the effluent concentration, were used for this check. The measurement 

system response time was determined by observing the times required to achieve a stable 

response for both the low and upscale gases. The longer of the two times was used as the 

response time and was taken into consideration when performing other calibration 

checks. STRATA recorded the responses and calculated whether the concentration 

displayed by the analyzers exceeded ± 5% of the span for either the low or upscale 

calibration gas. If this specification was exceeded, the data was flagged by STRATA, the 

sampling system underwent troubleshooting to discover and correct the problem, and then 

the sampling system bias check was repeated until acceptable performance was achieved.

Once the testing commenced, measurements from the instruments were recorded at least 

once per minute using STRATA, which automatically averages the data at the end of each 

run. After each run, low and upscale bias and drift tests were performed to check the drift 

12
of the analyzer and to collect data to allow STRATA to bias-correct the average result 

based on the amount of drift from the beginning to the end of the run. STRATA recorded 

the responses and calculated whether the concentration displayed by the analyzers 

exceeded ± 3% of the previous average span value for either the low-level or upscale 

calibration gas. If this specification was exceeded, the data was flagged by STRATA, the 

sampling system underwent troubleshooting to discover and correct the problem, and then 

the calibration error check and the sampling system bias check were repeated before 

repeating the run. 

When both the low-level and upscale calibration values were within the sampling system 

bias specification, the average gas concentration was calculated by STRATA from the 

average gas concentration displayed by the gas analyzer, adjusted for the low-level and 

upscale sampling system bias checks. An example calculation of this bias-correction 

calculation is included in the appendices of this report. 

5.3 EPA Method 4 - Moisture

The sample train used for moisture sampling was an EPA Method 4 design as illustrated 

in the figure titled “Method 4 Sample Train” in the appendices of this report. The gas 

was pulled through a heated probe liner using a pump into an impinger train that was 

immersed in an ice water bath. The probe tip was positioned at a point of average 

velocity in the gas stream. Per Method 4, gas was sampled at a constant rate of less than 

0.75 cubic feet per minute (cfm). The sample volume was greater than the minimum 

required 21 dry standard cubic feet (dscf) for each run. The first impinger was a modified 

Greenburg-Smith type containing 100 milliliters (mL) of deionized water. The second 

Greenburg-Smith impinger also contained 100 mL of water. The third impinger was 

empty, and the fourth bubbler contained indicating silica gel desiccant to absorb any 

moisture from the stack gas before it entered the control box. The impinger section was 

13
maintained at a temperature below 68oF by keeping ice on the impingers. The 

temperature at the outlet of the silica gel bubbler was monitored to verify that it did not 

exceed 68oF during a test. Prior to each run, the sample train was leak-checked following 

the procedures in Method 5. Upon completion of each test, the probe was removed from 

the stack and a post-test leak check was performed.

The sample train was connected to a control box by means of an umbilical cord. The 

control box contains a vacuum hose, pitot lines, thermocouple wires, and a 4-wire 

electrical cord. The control box (meter box) is used to monitor stack conditions. The 

control box consists of a leak-free pump used to pull the gas through the sample train, 

fine and coarse metering valves to control the sampling rate, a vacuum gauge to measure 

the pressure drop from the sampling nozzle to the metering valves, and a calibrated dry 

gas meter readable to 0.001 cubic feet. The dry gas meter inlet and outlet temperatures 

were monitored by thermocouples connected to the multi-channel thermocouple 

indicator. The dry gas meter calibration factor, Y, is determined by calibrating the meter 

against a standard laboratory dry gas meter.

Before and after each run, the impingers in the sample train were removed and weighed 

with a readability of 0.1 grams using an electronic top loading balance. The difference 

between the initial and final weights of the condenser section constitutes the amount of 

moisture gained during the run. 

5.4 EPA Method 320 – Nitrogen Oxides (NOx) Using FTIR

Nitrogen oxides (NOx) data were collected using EPA Method 320, “Vapor Phase 

Organic and Inorganic Emissions by Extractive FTIR.” Sample gas was extracted from 

the stack through a heated stainless steel probe. Gas was passed through a heated glassfiber filter and fed to a heated diaphragm pump. Sample gas was then fed to the FTIR 

14
sample cell through a short flexible stainless line. The FTIR uses a 0.2 liter sample call 

with a fixed path of 5.11 meters. All portions of the sampling system were maintained at

150°C. Reference method samples were collected at three measurement points in one of 

the sample ports. The sample probe was moved to three points across the stack during 

each run, which were 16.7, 50.0, and 83.3 percent of the measurement line. 

The sampling system was leak-checked prior to sampling by plugging the inlet to the 

sample probe and verifying the absence of flow at the outlet of the FTIR with a rotameter. 

Concentrations of N2O, NO, NO2, NH3, SF6, CO, CO2, ethylene, H2O and CH4 were 

recorded. Sample cell temperature and pressure were also recorded. The FTIR obtained 

spectra approximately once per second and thirty-two scans were averaged for each data 

point, which provided readings at 30-second intervals. Those data were averaged into 21-

minute reference method runs. A total of nine 21-minute Method 320 runs were 

performed. Emission concentrations were measured in wet parts per million (ppm). 

Since the FTIR also quantifies moisture, emissions can be converted to a dry basis if 

needed. NOx is the sum of NO and NO2. 

The quantification routine was verified by passing a 500.2 ppm N2O certified standard 

gas through the analytical system. The response to this gas was 481.9 ppm, which was 

96.3% of the certificate value.

Ultra-high purity (UHP) nitrogen gas was passed through the entire sampling and 

analytical system at the beginning and end of each run to confirm the absence of 

interferences from contamination. The N2O background was found to be approximately 1 

ppm, which is 0.3% of the sample concentration. 

15
A 99.6 ppm ethylene calibration transfer standard (CTS) was measured by the FTIR 

before and after the test series. The response to the CTS was within the 95% - 105% 

criterion.

Dynamic analyte spiking with a certified 500.2 ppm N2O calibration gas was performed 

for quality assurance. With this procedure, a known quantity of N2O was spiked into the 

gas stream at the back end of the sample probe, upstream of the primary filter. The 

analyte concentration in the spiked sample gas was compared to the average analyte 

concentration in unspiked gas before and after the spiking interval. The quantity of N2O 

injected was determined by measuring the concentration of a sulfur hexafluoride (SF6) 

tracer that was also present in the certified standard at a concentration of 10.0 ppm. 

Spiking was performed after every third run (after runs 3, 6, and 9). The recoveries were 

109.6%, 98.82%, and 89.0%, repectively, which is within the 70-130% criterion. 

A sampling system bias check was performed after every third run (pre-test and post-test 

after runs 3, 6, and 9). The 500.2 ppm N2O certified standard was passed through the 

entire sampling system to the FTIR. The system response to all bias checks was within 

the 95-105% criterion. 

All quantifications were performed using the spectral library provided by the instrument 

manufacturer. Detection limits were not calculated because observed concentrations 

exceeded the theoretical detection limit by several orders of magnitude. The 

quantification routine was optimized to eliminate bias from interferences and to select 

analytical regions with optimal absorption. The residual error from the least-squares 

regression for the N2O measurement was less than 0.2%. 

16
For this project, AmTest Air Quality subcontracted Mr. Daniel Soderberg to perform the 

FTIR measurements. An MKS Instruments Multigas 2030 FTIR spectrometer was used. 

Copies of the certificates of analysis for the calibration gases used and specifications for 

the FTIR used are included in Appendix D of this report. 

17
6.0

QUALITY ASSURANCE PLAN

The purpose of the quality assurance plan is to provide guidelines for achieving quality 

control in air pollution measurements. The detailed procedures, which are utilized, are 

included in the Environmental Protection Agency’s (EPA’s) reference manual titled 

Quality Assurance Handbook for Air Pollution Measurement Systems, Volume 3, EPA600/4-77-027b. These procedures are followed throughout equipment preparation, field 

sampling, sample recovery, analysis, and data reduction. ATAQ’s quality assurance 

procedures are discussed below. 

6.1 Calibration Procedures and Frequency

Field equipment utilized for on-site measurements is calibrated at a frequency 

recommended by the equipment manufacturer or industry practice. Prior to field use, 

each instrument due for calibration is calibrated and the calibration value is recorded. If 

any measuring or test device requiring calibration cannot immediately be removed from 

service, the Project Manager may extend the calibration cycle providing a review of the 

equipment’s history warrants the issuance of an extension. Equipment is not extended 

more than twice a calibration cycle, nor will the extension exceed one-half the prescribed 

calibration cycle. Test equipment consistently found to be out of calibration is repaired or 

replaced.

 The dry gas meters (mounted inside of the meter boxes) used to accurately measure 

sample volumes are calibrated at 6-month intervals using a standardized laboratory 

dry gas meter. A copy of the current calibration for each dry gas meter used on this 

project is included in the appendices of this report. ATAQ typically follows the 

EPA’s Emission Measurement Center Alternative Method 5 Post-Test Calibration 

(ALT-009) procedure to check the meter box calibration for each project. If the 

calculations in ALT-009 do not meet the +5% criterion, a post-test meter box 

calibration is performed. If a post-test calibration of the meter was performed, a copy 

of the calibration is included in the appendices of this report. 

18
 The standard dry gas meters used for the periodic recalibrations discussed above 

remain in the ATAQ laboratory and are sent for recalibration against an N.I.S.T. 

traceable spirometer annually as discussed in Section 16.1 of Method 5. A copy of 

the standard dry gas meter used to calibrate the meter box dry gas meter is included in 

the appendices of the report. 

 The type S pitot tubes utilized for velocity determination are calibrated using Method 

2, Section 10.1, and are inspected regularly for wear. Each type S pitot tube is 

marked with a unique identification number. A copy of the current calibration for 

each type S pitot tube used on this project is included in the appendices of this report. 

If a standard pitot tube was used, the Cp is 0.99 and no calibration information is 

included in the report. 

 The magnehelic gauges used for differential pressure measurements are calibrated 

against an oil-filled manometer. These gauges are permanently mounted in a meter 

box or in a separate magnehelic box. They are recalibrated when they are put into 

service, when they fail, or when the control boxes are overhauled.

 The digital thermocouple indicators used to provide a digital readout of temperatures 

from the sample train have a readability of 1 degree Fahrenheit. These temperature 

indicators are permanently mounted in the meter boxes, so they are identified by the 

meter box ID number. They are sent to the manufacturer for recalibration when they 

fail or the meter box is overhauled. 

 Each thermocouple probe used to monitor stack gas temperature is calibrated when it 

is put into service at three temperature settings (ice bath, boiling water, and boiling 

oil). An in-field check was performed for the stack temperature thermocouple at 

ambient temperature as allowed by the EPA’s Emission Measurement Center 

Alternative Method 2 Thermocouple Calibration Procedure (ALT-011). The stack 

gas temperature thermocouple was compared to a thermometer that has been 

calibrated against an ASTM reference thermometer at ambient temperature. The 

temperatures must agree within +2o

F. The in-field thermometers are periodically 

checked against the ASTM reference thermometer and the difference is recorded on a 

log that is kept in the ATAQ laboratory. 

 Thermocouple probes used to monitor the temperature at the inlet and outlet of the 

dry gas meters are calibrated against a mercury-in-glass thermometer when a meter 

box is built or overhauled or when the dry gas meter is recalibrated. Copies of the 

calibrations for these thermocouples are included with the dry gas meter calibration in 

the appendices of this report. 

 A barometer readable to 0.01 inches of mercury was used in the field to obtain 

barometric pressure readings. The in-field barometers are periodically checked 

against a NOVA mercury-filled barometer (primary standard, ID #0439) that is 

19
mounted in the ATAQ laboratory in Preston, Washington. The difference is recorded 

on a log that is kept next to the barometer. 

 Top loading analytical balances readable to 0.1 grams were used to weigh the 

impingers before and after each run where a moisture determination was made. These 

balances have an internal calibration procedure that is performed prior to each 

weighing session. The calibration of the top-loading balances is checked on a yearly 

basis using an outside contractor. 

Copies of calibration information for each measurement device used are included in the 

appendices of this report. All reagents used for this project conform to the specifications 

established by the Committee on Analytical Reagents of the American Chemical Society, 

or the best available grade.

The gaseous measurement systems are capable of meeting the system performance 

specifications detailed in 40 CFR 60, Appendix A, Method 6C, Section 4. For meeting 

these specifications, the analyzer’s calibration error must be less than ± 2% of span for 

the low-level, mid-level, and high-level calibration gases. The sampling system bias must 

be less than ± 5% of span for the low-level and mid- or high-level calibration gases. The 

low-level and calibration drift must be less than ± 3% of the span over the period of each 

run. Copies of certificates of analysis for each tank of calibration gas used are included in 

the appendices of this report. The calibration gases were analyzed following the EPA 

Traceability Protocol No. 1, or next best available. Purified nitrogen was utilized as zero 

gas. 

Support equipment is defined as all equipment, not previously discussed, that is required 

for completing an environmental monitoring or measurement task. This equipment may 

include storage and transportation containers, sample recovery glassware, and 

communications gear. Support equipment is periodically inspected to maintain the 

20
performance standards necessary for proper and efficient execution of all tasks and 

responsibilities.

During a project, a systems audit is performed, consisting of an on-site qualitative 

inspection and review of the total measurement system. The Project Leader conducts this 

inspection on a daily basis. During the systems audit, the auditor observes the procedures 

and techniques of the field team in the following general areas:

• Setting up and leak testing the sample train

• Final leak check of the sample train

• Sample recovery

Visual inspections of pitot tubes, glassware, and other equipment are also made. The 

main purpose of a systems audit is to ensure that the measurement system will generate 

valid data, if operated properly. 

6.2 Sample Recovery and Field Documentation

Data collected during each test, were immediately inspected for completeness and placed 

under the custody of the Project Leader until custody was transferred when the samples 

were returned to the Air Quality laboratory. Sample recovery was carried out in a suitable 

area free from particulate matter and other outside contamination. Each sample was 

assigned an identifying lab number to assist the chemists in tracking the sample.

6.3 Data Reduction, Validation, and Reporting 

Raw data are handled according to strict guidelines when being transposed into computer 

files or to other logs. The guidelines include document receipt control procedures, file 

review, and sign-off by a project assistant. Raw data were entered into the appropriate 

computer spreadsheet by a “processor,” then the entered figures were checked for 

21
accuracy by a “checker,” different from the “processor.” Any mistakes were corrected, 

and figures were rechecked and signed off by the “checker.” In addition, an example 

calculation check of each Excel® workbook was made using separate Excel® spreadsheets

showing the formulas that were used that reference the cells in the workbook and confirm 

the calculations. Each example calculation is labeled with the reporting units to 

demonstrate unit cancellation. The “senior reviewer” reviewed all of the data generated 

by each phase of the laboratory or field-sampling program. The “senior reviewer” signed 

off on the data package prior to releasing the data for report preparation. 

The test results were calculated according to EPA 40 CFR 60 criteria. Copies of the 

pertinent equations used to derive these results are included in the appendices of this 

report. Standard conditions are 68o F and 29.92 inches of mercury. The average values 

from instrumental analyzer readings were computed and bias-corrected for each test 

period. The average gas effluent concentration was determined from the average gas 

concentration displayed by the analyzer, adjusted for the low-level and upscale sample 

system bias checks. Calculations are on a dry basis using the following equation: 

Cgas = (C - Co) * (Cma/(Cm - Co))

where:

 Cgas = Effluent gas concentration, dry basis 

 C = Average gas concentration indicated by analyzer, dry basis

 Co = Average of initial and final sample system bias check responses for the 

low-level gas

 Cma = Actual concentration of the upscale calibration gas

 Cm = Average of initial and final sample system bias check responses for the 

upscale calibration gas

22
7.0

METHODOLOGY REFERENCES

EPA. Title 40 Code of Federal Regulations, Part 60 (40 CFR 60), Appendix A, Methods 

1, 2, 3A, and 4. July 1, 2008. 

EPA. Title 40 Code of Federal Regulations, Part 63 (40 CFR 63), Appendix A, 

Reference Method 320. July 1, 2008. 

EPA Guideline Documents 51, 51A, 51B, 51C, 51D, 51E, and 51F. Located at 

www.epa.gov/ttn/emc/guidlnd.html

EPA. Technology Transfer Network Emission Measurement Center (EPA-TTN-EMC) 

website, Test Methods Section, www.epa.gov/ttn/emc/. 

EPA. EPA APTI Course, “Course 468 - Source Sampling For Gaseous Pollutants.” 

EPA. Quality Assurance Handbook for Air Pollution Measurement Systems, Volume 3, 

EPA-60/4-77-027b. 

23
APPENDIX A

Computer Printouts of Results

24
File Name: 2803-008\Agrium RATA

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Run 1 Run 2 Run 3 Average

Date: 3/31/10 3/31/10 3/31/10

Start Time (M2): 1302 1339 1410

Stop Time (M2): 1323 1400 1431

Start Time (M4): 1302 1302 1302

Stop Time (M4): 1430 1430 1430

Sample Length (minutes): 60 60 60

Volume Sampled (ft3): 41.545 41.545 41.545 41.545

Volume Sampled (dscf): 40.097 40.097 40.097 40.097

Volume Sampled (dscm): 1.136 1.136 1.136 1.136

Stack Gas Moisture (%): 0.27 0.27 0.27 0.27

Barometric Pressure ("Hg): 29.35 29.35 29.35 29.35

Static Pressure ("H2O): -1.3 -1.3 -1.3 -1.3

Stack Pressure ("Hg): 29.25 29.25 29.25 29.25

Stack Temperature (°F): 309.8 314.8 310.4 311.7

Stack Temperature (°R): 769.8 774.8 770.4 771.7

Average Concentration O2 (%): 5.5 5.5 5.6 5.5

Average Concentration CO2 (%): 0.08 0.05 0.08 0.07

Molecular Weight (dry, g/g-mole): 28.23 28.23 28.23 28.23

Molecular Weight (wet, g/g-mole): 28.21 28.20 28.21 28.20

Average Velocity Head ("H2O): 2.01 1.87 1.85 1.91

Pitot Tube Cp: 0.84 0.84 0.84

Stack Gas Velocity (ft/sec): 98.3 95.1 94.3 95.9

Stack Area (ft2): 12.2 12.2 12.2

Stack Gas Airflow (dscf/min): 48046 46184 46036 46755

Stack Gas Airflow (scf/min): 48176 46309 46160 46882

Stack Gas Airflow (acf/min): 71832 69504 68886 70074

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

SUMMARY OF RESULTS - EPA METHODS 1, 2, 3A, AND 4

Plant #9 Stack

25
File Name: 2803-008\Agrium RATA

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Run 4 Run 5 Run 6 Average

Date: 3/31/10 3/31/10 3/31/10

Start Time (M2): 1450 1522 1554

Stop Time (M2): 1511 1543 1615

Start Time (M4): 1450 1450 1450

Stop Time (M4): 1614 1614 1614

Sample Length (minutes): 60 60 60

Volume Sampled (ft3): 40.636 40.636 40.636 40.636

Volume Sampled (dscf): 39.010 39.010 39.010 39.010

Volume Sampled (dscm): 1.105 1.105 1.105 1.105

Stack Gas Moisture (%): 0.05 0.05 0.05 0.05

Barometric Pressure ("Hg): 29.35 29.35 29.35 29.35

Static Pressure ("H2O): -1.3 -1.3 -1.3 -1.3

Stack Pressure ("Hg): 29.25 29.25 29.25 29.25

Stack Temperature (°F): 310.7 310.4 308.8 309.9

Stack Temperature (°R): 770.7 770.4 768.8 769.9

Average Concentration O2 (%): 5.5 5.5 5.6 5.5

Average Concentration CO2 (%): 0.04 0.05 0.10 0.06

Molecular Weight (dry, g/g-mole): 28.23 28.23 28.24 28.23

Molecular Weight (wet, g/g-mole): 28.22 28.22 28.24 28.23

Average Velocity Head ("H2O): 1.93 1.96 2.02 1.97

Pitot Tube Cp: 0.84 0.84 0.84

Stack Gas Velocity (ft/sec): 96.3 97.2 98.5 97.3

Stack Area (ft2): 12.2 12.2 12.2

Stack Gas Airflow (dscf/min): 47118 47567 48286 47657

Stack Gas Airflow (scf/min): 47141 47590 48309 47680

Stack Gas Airflow (acf/min): 70372 71019 71937 71109

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

SUMMARY OF RESULTS - EPA METHODS 1, 2, 3A, AND 4

Plant #9 Stack

26
File Name: 2803-008\Agrium RATA

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Run 7 Run 8 Run 9 Average

Date: 3/31/10 3/31/10 3/31/10

Start Time (M2): 1643 1714 1745

Stop Time (M2): 1704 1735 1806

Start Time (M4): 1643 1643 1643

Stop Time (M4): 1805 1805 1805

Sample Length (minutes): 60 60 60

Volume Sampled (ft3): 41.222 41.222 41.222 41.222

Volume Sampled (dscf): 39.638 39.638 39.638 39.638

Volume Sampled (dscm): 1.123 1.123 1.123 1.123

Stack Gas Moisture (%): 0.23 0.23 0.23 0.23

Barometric Pressure ("Hg): 29.35 29.35 29.35 29.35

Static Pressure ("H2O): -1.3 -1.3 -1.3 -1.3

Stack Pressure ("Hg): 29.25 29.25 29.25 29.25

Stack Temperature (°F): 309.8 308.6 309.0 309.1

Stack Temperature (°R): 769.8 768.6 769.0 769.1

Average Concentration O2 (%): 5.6 5.5 5.4 5.5

Average Concentration CO2 (%): 0.06 0.05 0.07 0.06

Molecular Weight (dry, g/g-mole): 28.23 28.23 28.23 28.23

Molecular Weight (wet, g/g-mole): 28.21 28.20 28.20 28.21

Average Velocity Head ("H2O): 1.95 1.93 1.94 1.94

Pitot Tube Cp: 0.84 0.84 0.84

Stack Gas Velocity (ft/sec): 96.9 96.2 96.5 96.5

Stack Area (ft2): 12.2 12.2 12.2

Stack Gas Airflow (dscf/min): 47353 47092 47221 47222

Stack Gas Airflow (scf/min): 47460 47198 47327 47328

Stack Gas Airflow (acf/min): 70764 70267 70498 70510

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

SUMMARY OF RESULTS - EPA METHODS 1, 2, 3A, AND 4

Plant #9 Stack

27
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1302 hours

Location: Kennewick, Washington Stop Time (M2): 1323 hours

Sample Site: Plant #9 Stack Start Time (M4): 1302 hours

Stop Time (M4): 1430 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 1 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

742.3 747.0 -4.7 Stack Length: inches

721.8 722.0 -0.2 Stack Diameter: 47.25 inches

566.6 566.0 0.6 Stack Area: 12.2 ft2

946.4 939.8 6.6 Meter Temperature: 79.2 °F

Total H2O Gain: 2.3 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.11 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.27 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0027 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.27

Actual Bws: 0.0027

Initial Meter Volume (ft3): 746.900 Average Conc. O2: 5.5 percent

Final Meter Volume (ft3): 788.445 Average Conc. CO2: 0.08 percent

Volume Sampled (ft3): 41.545 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 40.097 Molecular Weight: 28.21 g/g-mole-wet

Standard Volume (dscm): 1.136

Y Factor: 1.001 Y Factor Cal. Check: 0.998

Delta H @: 1.885 Percent Error: -0.3 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 2.10 310

5 2.20 310

4 2.00 310

3 1.95 310

2 1.85 310

1 1.80 310

B 6 1.90 310

5 2.20 310

4 2.30 310

3 2.10 309

2 1.95 309

1 1.80 309

Stack Gas Temperature: 309.8 °F 769.8 °R

Average Velocity Head: 2.009 " of H2O

Stack Gas Velocity: 98.3 ft/second

71832 acf/min 48046 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Stack Gas Airflow:

EPA METHODS 1, 2, 3A, AND 4

28
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1339 hours

Location: Kennewick, Washington Stop Time (M2): 1400 hours

Sample Site: Plant #9 Stack Start Time (M4): 1302 hours

Stop Time (M4): 1430 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 2 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

742.3 747.0 -4.7 Stack Length: inches

721.8 722.0 -0.2 Stack Diameter: 47.25 inches

566.6 566.0 0.6 Stack Area: 12.2 ft2

946.4 939.8 6.6 Meter Temperature: 79.2 °F

Total H2O Gain: 2.3 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.11 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.27 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0027 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.27

Actual Bws: 0.0027

Initial Meter Volume (ft3): 746.900 Average Conc. O2: 5.5 percent

Final Meter Volume (ft3): 788.445 Average Conc. CO2: 0.05 percent

Volume Sampled (ft3): 41.545 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 40.097 Molecular Weight: 28.20 g/g-mole-wet

Standard Volume (dscm): 1.136

Y Factor: 1.001 Y Factor Cal. Check: 0.998

Delta H @: 1.885 Percent Error: -0.3 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 1.90 315

5 2.10 315

4 2.20 315

3 2.05 315

2 1.95 315

1 1.90 315

B 6 1.60 315

5 2.20 315

4 2.40 314

3 1.60 314

2 1.30 315

1 1.40 315

Stack Gas Temperature: 314.8 °F 774.8 °R

Average Velocity Head: 1.868 " of H2O

Stack Gas Velocity: 95.1 ft/second

69504 acf/min 46184 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Stack Gas Airflow:

EPA METHODS 1, 2, 3A, AND 4

29
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1410 hours

Location: Kennewick, Washington Stop Time (M2): 1431 hours

Sample Site: Plant #9 Stack Start Time (M4): 1302 hours

Stop Time (M4): 1430 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 3 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

742.3 747.0 -4.7 Stack Length: inches

721.8 722.0 -0.2 Stack Diameter: 47.25 inches

566.6 566.0 0.6 Stack Area: 12.2 ft2

946.4 939.8 6.6 Meter Temperature: 79.2 °F

Total H2O Gain: 2.3 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.11 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.27 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0027 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.27

Actual Bws: 0.0027

Initial Meter Volume (ft3): 746.900 Average Conc. O2: 5.6 percent

Final Meter Volume (ft3): 788.445 Average Conc. CO2: 0.08 percent

Volume Sampled (ft3): 41.545 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 40.097 Molecular Weight: 28.21 g/g-mole-wet

Standard Volume (dscm): 1.136

Y Factor: 1.001 Y Factor Cal. Check: 0.998

Delta H @: 1.885 Percent Error: -0.3 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 1.50 309

5 1.90 310

4 2.10 311

3 1.85 311

2 1.45 311

1 1.60 311

B 6 1.85 311

5 2.10 311

4 2.20 310

3 2.05 310

2 1.95 310

1 1.70 310

Stack Gas Temperature: 310.4 °F 770.4 °R

Average Velocity Head: 1.846 " of H2O

Stack Gas Velocity: 94.3 ft/second

Stack Gas Airflow: 68886 acf/min 46036 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

EPA METHODS 1, 2, 3A, AND 4

30
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1450 hours

Location: Kennewick, Washington Stop Time (M2): 1511 hours

Sample Site: Plant #9 Stack Start Time (M4): 1450 hours

Stop Time (M4): 1614 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 4 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

706.8 714.3 -7.5 Stack Length: inches

712.8 713.2 -0.4 Stack Diameter: 47.25 inches

617.0 616.1 0.9 Stack Area: 12.2 ft2

885.8 878.4 7.4 Meter Temperature: 82.1 °F

Total H2O Gain: 0.4 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.02 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.05 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0005 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.05

Actual Bws: 0.0005

Initial Meter Volume (ft3): 789.651 Average Conc. O2: 5.5 percent

Final Meter Volume (ft3): 830.287 Average Conc. CO2: 0.04 percent

Volume Sampled (ft3): 40.636 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 39.010 Molecular Weight: 28.22 g/g-mole-wet

Standard Volume (dscm): 1.105

Y Factor: 1.001 Y Factor Cal. Check: 1.023

Delta H @: 1.885 Percent Error: 2.1 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 1.70 311

5 2.00 311

4 2.00 311

3 1.85 311

2 1.70 311

1 1.75 311

B 6 2.00 310

5 2.20 310

4 2.30 310

3 2.20 311

2 1.90 311

1 1.60 310

Stack Gas Temperature: 310.7 °F 770.7 °R

Average Velocity Head: 1.927 " of H2O

Stack Gas Velocity: 96.3 ft/second

70372 acf/min 47118 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Stack Gas Airflow:

EPA METHODS 1, 2, 3A, AND 4

31
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1522 hours

Location: Kennewick, Washington Stop Time (M2): 1543 hours

Sample Site: Plant #9 Stack Start Time (M4): 1450 hours

Stop Time (M4): 1614 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 5 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

706.8 714.3 -7.5 Stack Length: inches

712.8 713.2 -0.4 Stack Diameter: 47.25 inches

617.0 616.1 0.9 Stack Area: 12.2 ft2

885.8 878.4 7.4 Meter Temperature: 82.1 °F

Total H2O Gain: 0.4 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.02 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.05 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0005 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.05

Actual Bws: 0.0005

Initial Meter Volume (ft3): 789.651 Average Conc. O2: 5.5 percent

Final Meter Volume (ft3): 830.287 Average Conc. CO2: 0.05 percent

Volume Sampled (ft3): 40.636 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 39.010 Molecular Weight: 28.22 g/g-mole-wet

Standard Volume (dscm): 1.105

Y Factor: 1.001 Y Factor Cal. Check: 1.023

Delta H @: 1.885 Percent Error: 2.1 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 2.00 311

5 2.00 311

4 2.05 311

3 1.90 311

2 1.95 310

1 1.85 311

B 6 2.00 310

5 2.10 310

4 2.20 310

3 2.00 310

2 2.00 310

1 1.55 310

Stack Gas Temperature: 310.4 °F 770.4 °R

Average Velocity Head: 1.964 " of H2O

Stack Gas Velocity: 97.2 ft/second

71019 acf/min 47567 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Stack Gas Airflow:

EPA METHODS 1, 2, 3A, AND 4

32
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1554 hours

Location: Kennewick, Washington Stop Time (M2): 1615 hours

Sample Site: Plant #9 Stack Start Time (M4): 1450 hours

Stop Time (M4): 1614 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 6 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

706.8 714.3 -7.5 Stack Length: inches

712.8 713.2 -0.4 Stack Diameter: 47.25 inches

617.0 616.1 0.9 Stack Area: 12.2 ft2

885.8 878.4 7.4 Meter Temperature: 82.1 °F

Total H2O Gain: 0.4 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.02 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.05 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0005 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.05

Actual Bws: 0.0005

Initial Meter Volume (ft3): 789.651 Average Conc. O2: 5.6 percent

Final Meter Volume (ft3): 830.287 Average Conc. CO2: 0.10 percent

Volume Sampled (ft3): 40.636 Molecular Weight: 28.24 g/g-mole-dry

Standard Volume (dscf): 39.010 Molecular Weight: 28.24 g/g-mole-wet

Standard Volume (dscm): 1.105

Y Factor: 1.001 Y Factor Cal. Check: 1.023

Delta H @: 1.885 Percent Error: 2.1 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 2.10 309

5 2.20 309

4 2.20 309

3 2.00 309

2 2.00 309

1 1.80 309

B 6 2.00 309

5 2.20 309

4 2.30 309

3 2.10 308

2 1.80 308

1 1.60 308

Stack Gas Temperature: 308.8 °F 768.8 °R

Average Velocity Head: 2.020 " of H2O

Stack Gas Velocity: 98.5 ft/second

Stack Gas Airflow: 71937 acf/min 48286 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

EPA METHODS 1, 2, 3A, AND 4

33
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1643 hours

Location: Kennewick, Washington Stop Time (M2): 1704 hours

Sample Site: Plant #9 Stack Start Time (M4): 1643 hours

Stop Time (M4): 1805 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 7 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

696.4 701.8 -5.4 Stack Length: inches

715.4 715.7 -0.3 Stack Diameter: 47.25 inches

601.8 601.5 0.3 Stack Area: 12.2 ft2

866.3 859.0 7.3 Meter Temperature: 81.2 °F

Total H2O Gain: 1.9 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.09 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.23 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0023 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.23

Actual Bws: 0.0023

Initial Meter Volume (ft3): 831.265 Average Conc. O2: 5.6 percent

Final Meter Volume (ft3): 872.487 Average Conc. CO2: 0.06 percent

Volume Sampled (ft3): 41.222 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 39.638 Molecular Weight: 28.21 g/g-mole-wet

Standard Volume (dscm): 1.123

Y Factor: 1.001 Y Factor Cal. Check: 1.007

Delta H @: 1.885 Percent Error: 0.6 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 2.00 309

5 2.20 311

4 2.10 310

3 1.95 310

2 1.90 310

1 1.80 310

B 6 1.90 310

5 2.10 310

4 2.20 310

3 1.90 309

2 1.80 309

1 1.60 309

Stack Gas Temperature: 309.8 °F 769.8 °R

Average Velocity Head: 1.950 " of H2O

Stack Gas Velocity: 96.9 ft/second

70764 acf/min 47353 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Stack Gas Airflow:

EPA METHODS 1, 2, 3A, AND 4

34
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1714 hours

Location: Kennewick, Washington Stop Time (M2): 1735 hours

Sample Site: Plant #9 Stack Start Time (M4): 1643 hours

Stop Time (M4): 1805 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 8 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

696.4 701.8 -5.4 Stack Length: inches

715.4 715.7 -0.3 Stack Diameter: 47.25 inches

601.8 601.5 0.3 Stack Area: 12.2 ft2

866.3 859.0 7.3 Meter Temperature: 81.2 °F

Total H2O Gain: 1.9 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.09 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.23 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0023 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.23

Actual Bws: 0.0023

Initial Meter Volume (ft3): 831.265 Average Conc. O2: 5.5 percent

Final Meter Volume (ft3): 872.487 Average Conc. CO2: 0.05 percent

Volume Sampled (ft3): 41.222 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 39.638 Molecular Weight: 28.20 g/g-mole-wet

Standard Volume (dscm): 1.123

Y Factor: 1.001 Y Factor Cal. Check: 1.007

Delta H @: 1.885 Percent Error: 0.6 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 2.10 308

5 2.10 308

4 2.00 309

3 1.90 308

2 1.90 308

1 1.80 308

B 6 1.85 309

5 1.95 309

4 1.95 309

3 2.00 309

2 2.10 309

1 1.50 309

Stack Gas Temperature: 308.6 °F 768.6 °R

Average Velocity Head: 1.926 " of H2O

Stack Gas Velocity: 96.2 ft/second

70267 acf/min 47092 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

Stack Gas Airflow:

EPA METHODS 1, 2, 3A, AND 4

35
File Name: 2803-008\Agrium RATA Lab #: NA

Client: Agrium U.S., Inc. Start Time (M2): 1745 hours

Location: Kennewick, Washington Stop Time (M2): 1806 hours

Sample Site: Plant #9 Stack Start Time (M4): 1643 hours

Stop Time (M4): 1805 hours

Sample Date: 3/31/10 Sample Length: 60 minutes

Run #: 9 - Method 1-4

Operators: KBA,RDR

Impinger Weights

Final Initial Net Pitot Tube Cp: 0.84

grams grams grams Stack Width: inches

696.4 701.8 -5.4 Stack Length: inches

715.4 715.7 -0.3 Stack Diameter: 47.25 inches

601.8 601.5 0.3 Stack Area: 12.2 ft2

866.3 859.0 7.3 Meter Temperature: 81.2 °F

Total H2O Gain: 1.9 Barometric Pressure: 29.35 inches Hg

Total Volume (scf): 0.09 Static Pressure: -1.3 inches H2O

Measured Moisture (%): 0.23 Stack Pressure: 29.25 inches Hg

Measured Bws: 0.0023 Orifice Pressure: 1.50 inches H2O

Psychrometric Moisture (%): NA Meter Pressure: 29.46 inches Hg

Actual Moisture (%): 0.23

Actual Bws: 0.0023

Initial Meter Volume (ft3): 831.265 Average Conc. O2: 5.4 percent

Final Meter Volume (ft3): 872.487 Average Conc. CO2: 0.07 percent

Volume Sampled (ft3): 41.222 Molecular Weight: 28.23 g/g-mole-dry

Standard Volume (dscf): 39.638 Molecular Weight: 28.20 g/g-mole-wet

Standard Volume (dscm): 1.123

Y Factor: 1.001 Y Factor Cal. Check: 1.007

Delta H @: 1.885 Percent Error: 0.6 %

Sample Velocity Temperature Sample Velocity Temperature

Point (" of H2O) °F Point (" of H2O) °F

A 6 1.90 309

5 1.90 309

4 2.00 309

3 1.85 309

2 1.90 309

1 1.80 309

B 6 2.10 309

5 2.20 309

4 2.15 309

3 2.10 309

2 1.90 309

1 1.50 309

Stack Gas Temperature: 309.0 °F 769.0 °R

Average Velocity Head: 1.937 " of H2O

Stack Gas Velocity: 96.5 ft/second

Stack Gas Airflow: 70498 acf/min 47221 dscf/min

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

EPA METHODS 1, 2, 3A, AND 4

36
Run Run Time NO ppm NO2 ppm NOx ppm

1 1304-1325 26.1 13.9 40.0

2 1339-1400 24.3 13.1 37.4

3 1410-1431 23.6 13.1 36.8

4 1450-1511 23.7 13.1 36.8

5 1522-1543 24.0 13.5 37.5

6 1554-1615 23.8 13.5 37.3

7 1643-1704 23.8 13.0 36.8

8 1714-1735 23.5 13.0 36.5

9 1745-1806 23.4 12.7 36.0

Summary of Reference FTIR Results

37
APPENDIX B

Process Data

38
39
40
41
42
43
Worksheet Title: NOx Alternate Emission Test Results Template (Methods 7, 7A, 7B, 7C, and 7D)

Who Should Complete this Spreadsheet?

Company Name:

Facility Name: Agrium U.S. Inc.’s Kennewick Fertilizer Operations

Address: PO Box 5797

City: Kennewick

State: Washington, 99337

Nitric Acid Production Line Name:

Control Device Configuration: 

Parameter

Sample #1Sample #2Sample #3

Test Average

Units

Units Other 

Description

Test Method Used Test Location 

Enter the name of the Test Method used.

Indicate whether the test 

occurred upstream or 

downstream of a control 

device(s)

For all pollutants, prov

you think is necessary 

Sample Date (mm/dd/yyyy) 3/31/2010 3/31/2010 3/31/2010

NOX Concentration 51.6[<1.4] 50.6[<1.4] 49.4[<1.4] 50.5[<1.4] ppm @ 0% oxygen EPA Method 320, plus Methods 3A and 4 None All values are ADL. S

(ADL) the values of th

in brackets. See attach

NOX Emission Rate 12.8[<0.3] 12.7[<0.3] 12.4[<0.3] 12.6[<0.3] lb/hr EPA Method 320, plus Methods 1-4 None All values are ADL. S

(ADL) the values of th

in brackets. See attach

NOX Emission Factor 0.542[<0.014] 0.538[<0.014] 0.524[<0.014] 0.535[<0.014] lb/ton EPA Method 320, plus Methods 1-4 None All values are ADL. S

(ADL) the values of th

in brackets. See attach

Moisture Percentage 0.27 0.05 0.23 % See attached report.

Flowrate 70074 71109 70510 acfm See attached report.

Temperature 311.7 309.9 309.1 F See attached report.

Notes:

Enter NOX concentration value in parts per 

million (ppm), pound per hour, and pound per 

ton of nitric acid. If the test results are below 

detection limit, please note the detection limit in 

brackets 

(e.g., [< 0.010]). 

Peach shaded cells indicate areas where the user will enter a response

Facilities that do not use Method 7E to test for NOX

Agrium U.S. Inc.

Kennewick

None
Production Rate Data for Plant 9 (per e-mail)

On March 31st we produced 566.9 tons 100% nitric acid basis or 23.6 tons per hour.

Tom Klein

45
APPENDIX C

Example Calculations and Field Data Sheets

46
File Name: 2803-008\Agrium Plant 9 - M1-4, M320

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Site: Plant #9 Stack

Date:

Run #: 1 - Method 1-4

Dry Gas Meter Standard Volume - Equation 5-1

Vmstd = 17.647(oR/"Hg (constant) ) * volume sampled * Yfactor * (Pbar + ΔH / 13.6) / (460 + TM)

= ft3 * 1.001 *( 29.35 + 1.500 / 13.6 ) / ( 460 + 79.2 oF)

= 40.097 = 1.136 dscm

Moisture - Equation 5-2 and 5-3

Vwstd = 2.3 grams of H2O collected in impingers = scf H2O

BWS = ( 0.11 0.11 scf + * 100% = % H2O

0.27 % Psychrometric Moisture = %

0.27 %

Molecular Weight - Equation 3-2

Md = 0.440 *( 0.08

 = 28.23

Ms = 28.23

 = 28.21

√

Yqa = θ * = * * 29

Vm ΔH@ * (Pm) * Md 1.885 * * 28.23

 = 0.998 [Pm = (Pbar + ΔH / 13.6) = 29.35 + 1.500 = 29.46 ]

% Error = Y = =( 0.998 - 1.001 ) / 0.998

 = -0.3 %

539.2

Md*(1-BWS)+18.0 *BWS = g/g-mole *(1- 0.0027

√

5.5

0.0027

0.0319 *

g/g-mole (dry)

5.5

impossible for the % moisture to be higher than the psychrometric moisture. If the psychrometric moisture is higher than the 

% O2) + 0.280 *(100% -

)+18.0g/g-mole*

g/g-mole (wet)

%CO2 -

The above calculations are from the 40 CFR 60 and assume English units.

(Yqa - Y) / Yqa * 100 % 1.001

Percent error must be less than 5% or a post test dry gas meter calibration is required.

* 100% =

0.11

40.097

0.0027

0.27

Actual BWS =

0.0027

 NA

dscf ) =

3/31/10

 ) scf /(

41.545

35.31 ft3/m3

0.04715 ft3/gm *

17.647 * 

Actual Moisture =

√ 29.46

measured moisture it is reported as NA.

0.08

0.0319 * Tm * ΔHavg * 29 60 1.500

Meter Box Calibration Error

41.545

 / 13.6

EXAMPLE CALCULATION SHEET

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

dscf /

%O2(%CO+%N2 %CO2)+0.320*( ))

EPA METHODS 1, 2, 3, AND 4

Measured Moisture =

BWS

Actual moisture is determined by the lower of the measured moisture vs. the psychrometric moisture; since it is theoretically 

47
File Name: 2803-008\Agrium Plant 9 - M1-4, M320

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Site: Plant #9 Stack

Date:

Lab #:

Run #: 1 - Method 1-4

Stack gas velocity and volumetric flow rate - Equations 2-9 and 2-10

Vs = 85.49 * Cp √ (ΔP * Ts oR / (Ms g/gmole * PS "Hg) [Ps = Pbar + Pstatic / 13.6 ]

 = * √ * /( * ) [ = + -1.300 / 13.6 ] 

 =

Qstd = 60 * (1 -Bws )*Vs * As * Tstd/Ts * Ps/Pstd [ As = π (Sdia)2 / 4 /1 44 (ft2

) ] or [As = W * L / 144 (ft2

)]

 = 60 *(1 - )* * * / * /

 = dscf/min (dry standard cubic feet per minute)

acfm = * ft2 * 60 sec/min

 = acfm (actual cubic feet per minute)

scfm = dscf/min / (1 - %H2O) / 100)

= dscf/min / / 100)

= scfm

The above calculations are from the 40 CFR 60 and assume English units.

48046 (1 - 0.27

48176

29.35

29.25 29.92

ft/sec

29.25

48046

12.2

12.2

71832

98.3

528

2.009 28.21 29.25

0.0027 98.3 770

NA

ft/sec

770

98.3

EXAMPLE CALCULATION SHEET 

EPA METHODS 1, 2, 3A, AND 4

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

3/31/10

85.49 0.84

48
File Name: 2803-008\Agrium Plant 9 - M1-4, M320

Client: Agrium U.S., Inc.

Location: Kennewick, Washington

Site: Plant #9 Stack

Date:

Run #: 1

Percent Moisture: = % Bws:

= %

= dscf/min /

= scf/min / ( 1 - ) = 

Production Rate = tons/hr

NITROGEN OXIDES (NOx) EMISSIONS

NOx Measured by FTIR = 

NOx = ppm-wet * scf/min * min / hr

= lb/hr-dry lb/scf is a conversion factor for NOx as specified in EPA Method 19, Table 19.1.

NOx = ppm-wet * ( 1 - )

= ppm-dry

NOx = ppm * - 0

= ppm @

NOx = / tons/hr

 = = lb/ton - dry

39.9 ( 20.9

(1 - Bws) = scfm

48046 0.0027

48046

48176

0.585

13.8 23.6

0.0027

EXAMPLE CALCULATION SHEET

EPA METHOD 320 (FTIR) - NITROGEN OXIDES (NOX)

AMTEST AIR QUALITY, A DIVISION OF HOEFLER CONSULTING GROUP

3/31/10

0.27

lb/hr-dry

1.194E-07

1.194E-07 lb/scf *

% O2 )

60

54.2 0 % O2

13.8

40.0 48176

40.0

39.9

0.0027

Oxygen Concentration

Stack Gas Airflow(STD)

48176

23.6

5.5

Stack Gas Airflow(STD)

% O2 ) / ( 20.9 % O2 - 5.5

49
CIRCULAR STACK SCHEMATIC AND LOCATION OF SAMPLE POINTS

Client

Date Prepared

 Y

Project Date

Location

Sampling Location

Inside of far wall to outside

of port (distance, X)

Inside of near wall to outside

of port (distance, Y)

Stack I.D. (distance X - distance Y)

Initials/Date

Percentage Stack Traverse Point

of Duct Inside Location from

Traverse Length (or Diameter Column Distance Outside of Port

Point Fraction) (inches) 2 X 3 Y Columns 4 + 5

Stack Height =

Port Diameter (ID)=

Distance A = downstream

Distance B = 480" upstream

FLOW DIAGRAM

55'

3"

240"

CROSS SECTION STACK, CONTROL DEVICE AND PROCESS

12

11

10

9

8

7

43.4

6 95.6

3 29.6

45.2 48.2

5 85.4 40.4

4 70.4 33.3 36.3

14.6 6.9 9.9

17.0

 Schematic of Sampling Location

KBA 3-30-10

1 2 3

14.0

3.0 5.1

2

3.0

1 4.4 47.3 2.1

47.25

Agrium Kennewick X

3/31/2010

3/31/2010

4 5 6

Kennewick, WA

Plant 9

50.25

50
51
52
53
54
55
56
57
CLIENT:

LOCATION:

SITE:

TEST TEAM: DATE:

RUN #'s: METHOD:

Filter In-Stack Out of Stack

Sintered Metal 47mm Heated Cartridge

Probe Type: regular tubing Calibration Tee: tip of probe probe exit

Sample Line: Heated Not Heated

Filter Media: quartz fiber glass fiber Teflon® other

Gas Conditioner: Glass Knockout Teflon Knockout TRS Train

Electric Chiller

Gas Conditioner Location: After Probe After Sample Line

If this information is not accurate for all runs, note all exceptions.

X

X

X

X

Legend - = Cal Tee = Filter = Gas Conditioner

X

ANALYZER CONFIGURATION DATA SHEET

Fill out one sheet per sample site and per CEMS system.

3/30/2010

3

Agrium Kennewick

Kennewick, WA

Plant 9

KBA

7E

Please draw in Locations: 

X

X

X

Analyzers

Stack

58
Client: Agrium Kennewick

Location: Kennewick, WA

Site Location: Plant 9

Date & Time: 3/30/10 Time

Operator: KBA

Analyzer type/ID: Thermo 42i-HL NOx

UPSCALE

1 45 seconds

2 44 seconds

3 45 seconds

Average Upscale Response 44.7 seconds

DOWNSCALE

1 44 seconds

2 44 seconds

3 46 seconds

Average Downscale Response 44.7 seconds

SYSTEM RESPONSE TIME

System Response Time 44.7 seconds

RESPONSE TIME TEST

AmTest Air Quality

59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
Final System Bias Check for Run 9 . STRATA Version 3.01

O2 CO2 CO NOx O2 CO2 CO NOx

% % ppm ppm Volts Volts Volts Volts

3/31/2010 18:08:04 2.751 0.391 4.831 37.27 1.1 0.157 0.966 3.727

3/31/2010 18:09:05 0.102 0.34 1.558 1.46 0.041 0.136 0.312 0.146

3/31/2010 18:10:04 0.094 0.343 0.596 0.52 0.038 0.137 0.119 0.052

3/31/2010 18:11:05 9.459 9.708 33.727 0.39 3.784 3.883 6.745 0.039

3/31/2010 18:12:03 11.826 12.164 49.994 0.33 4.73 4.866 9.999 0.033

3/31/2010 18:13:04 3.347 3.588 49.995 10.16 1.339 1.435 9.999 1.016

3/31/2010 18:14:05 0.111 0.371 22.478 26.79 0.044 0.149 4.496 2.679

Final System Bias Check for Run 9 

Operator: KBA

Plant Name: Agrium Plant 9

Location: Kennewick, WA

Reference Cylinder Numbers

Zero Span

O2 Nitrogen EB0017560

CO2 Nitrogen EB0017560

CO Nitrogen EB0014533

NOx Nitrogen ALM030505

Date/Time 3/31/2010 18:14:30 PASSED

Analyte O2 CO2 CO NOx

Units % % ppm ppm

Zero Ref Cyl 0 0 0 0

Zero Cal 0.017 0.022 0.167 0.02

Zero Avg 0.096 0.341 0.686 0.63

Zero Bias% 0.3 1.3 1 0.6

Zero Drift% 0 0 -0.6 0

Span Ref Cyl 12.02 12.05 25.4 26

Span Cal 11.834 11.856 24.97 25.84

Span Avg 11.809 12.127 24.254 26.87

Span Bias% 0.1 1.1 1.4 1

Span Drift% -0.1 -0.2 -1 0.2

Ini Zero Avg 0.094 0.335 0.979 0.68

Ini Span Avg 11.827 12.167 24.739 26.71

Run Avg 5.396 0.402 1.941 39.15

Co 0.095 0.338 0.833 0.65

Cm 11.818 12.147 24.496 26.79

Correct Avg 5.435 0.065 1.19 38.3

82
Client: Date:

Oxygen (O2) Analyzers

Servomex Model 1420B #1 #2 #3 #4

Infrared Industries Model 2200 #1 #2

CAI 100 Series - oxygen only

CAI 200 Series - oxygen and carbon dioxide

CAI 600 Series - oxygen and carbon dioxide #1 #2 X

Carbon Dioxide (CO2) Analyzers

Servomex Model 1410B #1 #2 #3

Automated Custom Systems Model 3300

Infrared Industries Model 702D

CAI 200 Series - oxygen and carbon dioxide

CAI 600 Series - oxygen and carbon dioxide #1 #2 X

Carbon Monoxide (CO) Analyzers

Thermo Model 48 #1 #2 #3 #4 X #5 #6

Automated Custom Systems Model 3300

CAI 600 Series - Carbon Monoxide #1 #2

Sulfur Dioxide (SO2) Analyzers

BOVAR Western Research Model 721 AT #1 #2

BOVAR Western Research Model 721 M #1 #2

Ametek Western Research 921CE #1 #2

Nitrogen Oxides (NOx) Analyzers

Thermo Model 42H #1 #2 #3 #4

Thermo Model 42i-HL #1 X #2

CAI Model 400-CLD #1 #2

Hydrocarbon Analyzers

Thermo Model 51 HC Analyzer #1 #2 #3

J.U.M. Engineer Model 109A Non-Methane HC Analyzer #1 #2

Infrared Industries Model 702D HC Analyzer

Infrared Industries Model 703 HC Analyzer

Thermo Model 680 Methane Analyzer

Gas Chromatography

SRI Model 8610A GC

Data Aquisition Systems

STRATA X

Yokogawa w/STRATA

Manually Recorded

Bubble Meters

Gilian Bubble Meter #1 (SN 18844-S), #2 (SN 18445-S) #1 #2 #3 X

Relative Humdity and Temperature

Meterman Model TRH22

AMPROBE Model THWD-3

Continuous Analyzer Checklist

Agrium Kennewick 3/30/2010

83
CLIENT:

Cylinder # Gas Concentrations Exp. Date

Carbon Monoxide, Carbon Dioxide, Oxygen

1L1314 909 ppm CO, 22.2% CO2, 22.0% O2 01/31/11

AAL19120 890 ppm CO, 22.3% CO2, 22.1% O2 05/09/11

ALM012276 895 ppm CO, 22.3% CO2, 22.1% O2 05/09/11

ALM030006 01/31/11

ALM030118 886 ppm CO, 22.3% CO2, 22.1% O2 05/09/11

ALM037628 482 ppm CO, 12.0% CO2, 12.1% O2 10/01/10

ALM048513 886 ppm CO, 22.3% CO2, 22.1% O2 05/09/11

ALM065030 05/09/11

CC88772 483.3 ppm CO, 12.02% CO2, 12.14% O2 07/14/12

CC100852 985.5 ppm CO, 21.56% CO2, 22.02% O2 07/29/12

CC159104 514.3 ppm CO, 11.87% CO2, 12.06% O2 04/14/12

CC159124 529.1 ppm CO, 12.05% CO2, 12.11% O2 10/16/11

CC162057 908 ppm CO, 21.9% CO2, 22.1% O2 (In Anchorage) 01/17/10

CC184204 989.9 ppm CO, 21.35% CO2, 21.02% O2 07/29/12

CC184234 515.4 ppm CO, 11.93% CO2, 12.06% O2 04/14/12

CC184990 482.6 ppm CO, 12.02% CO2, 12.10% O2 07/14/12

CC185105 49.89 ppm CO, 12.28% CO2, 12.07% O2 10/16/11

CC185227 511.4 ppm CO, 11.83% CO2, 12.05% O2 04/14/12

CC231291 483.7 ppm CO, 11.85% CO2, 12.22% O2 07/14/12

CC231299 484.1 ppm CO, 11.89% CO2, 12.15% O2 07/14/12

CC231322 487.0 ppm CO, 12.01% CO2, 12.11% O2 07/14/12

CC231530 483.1 ppm CO, 12.00% CO2, 12.10% O2 07/14/12

CC251832 981.1 ppm CO, 21.23% CO2, 22.22% O2 07/29/12

CC251937 517.5 ppm CO, 11.89% CO2, 12.05% O2 04/14/12

EB0015841 950.5 ppm CO, 21.37% CO2, 21.85% O2 04/14/12

X EB0015845 959.8 ppm CO, 21.47% CO2, 22.02% O2 04/14/12

EB0015979 989.8 ppm CO, 22.62% CO2, 21.97% O2 07/29/12

X EB0017560 480.8 ppm CO, 12.05% CO2, 12.02% O2 04/14/12

Sulfur Dioxide, Nitrogen Oxides, Carbon Monoxide

ALM017643 194 ppm SO2, 195 ppm NOx, 192 ppm CO 02/12/10

ALM047586 899 ppm SO2, 901 ppm NOx, 900 ppm CO 05/16/10

ALM065347 90.3 ppm SO2, 91.3 ppm NOx, 89.6 ppm CO 05/27/10

CC35365 90.2 ppm SO2, 96.6 ppm NOx, 97.0 ppm CO 12/18/10

CC56575 47.8 ppm SO2, 48.0 ppm NOx, 47.5 ppm CO 12/17/10

CC56682 47.6 ppm SO2, 48.6 ppm NOx, 47.4 ppm CO 12/17/10

CC88824 191.1 ppm SO2, 190.4 ppm NOx, 197.9 ppm CO 12/19/10

CC115883 47.8 ppm SO2, 47.9 ppm NOx, 47.6 ppm CO 12/17/10

CC115920 190.1 ppm SO2, 194.4 ppm NOx, 195.4 ppm CO 12/19/10

CC116004 25.9 ppm SO2, 24.4 ppm NOx, 25.3 ppm CO 07/13/11

CC165345 25.7 ppm SO2, 24.2 NOx, 24.1 ppm CO 04/10/11

CC165595 47.6 ppm SO2, 48.3 ppm NOx, 47.6 ppm CO 12/17/10

CC184264 25.7 SO2, 24.5 ppm NOx, 25.2 ppm CO 07/13/11

CC184278 25.4 ppm SO2, 24.4 ppm NOx, 25.2 ppm CO 07/13/11

CC185096 25.9 ppm SO2, 24.7 ppm NOx, 25.3 ppm CO 07/13/11

CC185312 953.2 ppm SO2, 1000.2 ppm NOx, 1001.3 ppm CO 10/16/10

CC185354 47.7 ppm SO2, 48.0 ppm NOx, 47.6 ppm CO 12/17/10

CC185395 47.6 ppm SO2, 47.7 ppm NOx, 47.5 ppm CO 12/17/10

CC231260 93.8 ppm SO2, 98.0 ppm NOx, 98.0 ppm CO 07/09/11

CC310800 4.48 ppm SO2, 171.9 ppm NOx, 114.6 ppm CO 10/28/09

GAS CYLINDER CHECKLIST

DATE: 3/30/2010

889 ppm CO, 22.3% CO2, 22.1% O2

913 ppm CO, 22.2% CO2, 21.9% O2

Agrium Kennewick

84
GAS CYLINDER CHECKLIST

Methane

1L23320 20.0% Methane 02/06/10

AAL601 506 ppm Methane 05/09/11

AAL8079 9900 ppm Methane 08/28/10

AAL14151 1990 ppm Methane 05/09/11

ALM006318 998 ppm Methane 05/09/11

ALM036593 5170 ppm Methane 08/28/10

ALM045773 5010 ppm Methane 08/28/10

ALM046623 203 ppm Methane 05/09/11

ALM050039 30.2 ppm Methane 05/06/11

ALM052126 103 ppm Methane 05/06/11

ALM062797 9920 ppm Methane 08/28/10

CC58365 49.8 ppm Methane 06/04/10

CC122579 49.8 ppm Methane 06/04/10

EB0018680 89.7 ppm Methane 08/24/12

EB0018681 87.8 ppm Methane 08/28/12

EB0018683 52.8 ppm Methane 08/24/12

EB0018695 52.5 ppm Methane 08/24/12

EB0018696 89.5 ppm Methane 08/24/12

EB0018957 33.6 ppm Methane 08/19/12

EB0018965 33.5 ppm Methane 08/19/12

EB0018969 33.2 ppm Methane 08/19/12

EB0018970 52.9 ppm Methane 08/24/12

Hydrogen Sulfide

AAL5680 7.89 ppm H2S 05/06/09

ALM017264 5.18 ppm H2S 05/19/09

ALM065339 7.647 ppm H2S 04/16/09

CC88789 5.1 ppm H2S 02/04/10

CC231285 11.6 ppm H2S 02/04/10

CC184966 174.6 ppm H2S 12/29/09

CC251496 17.6 ppm H2S 02/04/10

CGA Gases

1L3386 211 ppm SO2, 1090 ppm CO, 9.65% O2 12/05/09

CC17610 99.8 ppm SO2, 490 ppm CO, 5.03% O2 12/04/09

CC60182 811 ppm Ethylene Oxide 04/24/10

CC85164 253 ppm Ethylene Oxide 04/24/10

EB0014690 256.5 SO2, 10.15% O2 02/04/11

SX22912 210 ppm SO2, 113 ppm CO, 9.98% O2 12/08/10

SX44598 105 ppm SO2, 518 ppm CO, 5.19% O2 12/04/09

SX46199 5.17% O2 11/03/11

Other Mixtures

AAL021820 1810 ppm CO (in Anchorage) 04/11/11

ALM040825 754 ppm Carbonyl Sufide Nitrogen 03/14/09

ALM053492 4790 ppm CO (in Anchorage) 04/11/11

RD333472 2.04% Methanol 02/06/09

CC112029 2484 ppm CO 02/10/12

CC233810 53.1 ppm NO2 / Air 06/17/09

Rental Cylinders

X CC149894 13.4 ppm NO2 in N2 2/17/2012

X ALM030505 26.0 ppm NO2 in N2 2/16/2012

X CC230373 50.0 ppm NO2 in Air 2/17/2012

85
 CTS (99.6 ppm Ethylene)

Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene H2O% 

Pre Test

AGRIUM_WA_RUN 1_000002.LAB 3/31/2010 12:48:00 0.695 0.326 0.082 0.274 -0.003 8.572 0.003 100.82 0.125 

AGRIUM_WA_RUN 1_000003.LAB 3/31/2010 12:48:30 0.595 0.387 0.066 0.319 -0.001 8.458 0.007 100.59 0.112 

Average 100.70 101.1%

Post Run 1

AGRIUM_WA_RUN 1_000231.LAB 3/31/2010 14:42:17 0.544 0.321 0.242 0.219 -0.007 9.521 0.015 100.55 0.089 

AGRIUM_WA_RUN 1_000232.LAB 3/31/2010 14:42:47 0.509 0.286 0.231 0.220 -0.007 9.492 0.010 100.52 0.084 

Average 100.53 100.9%

Post Run 2

AGRIUM_WA_RUN 2_000185.LAB 3/31/2010 16:22:31 2.273 0.306 0.434 0.122 -0.008 9.604 0.024 100.32 0.123 

AGRIUM_WA_RUN 2_000186.LAB 3/31/2010 16:23:01 1.602 0.306 0.414 0.112 -0.009 9.715 0.017 100.29 0.108 

Average 100.31 100.7%

Post Run 3

AGRIUM_WA_RUN 3_000199.LAB 3/31/2010 18:15:57 0.931 0.280 0.175 0.081 -0.007 9.514 0.011 100.61 0.072 

AGRIUM_WA_RUN 3_000200.LAB 3/31/2010 18:16:27 0.736 0.234 0.147 0.124 -0.006 9.402 0.013 100.42 0.073 

Average 100.52 100.9%

 Zero Nitrogen

Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene H2O% 

Pre Test

AGRIUM_WA_RUN 1_000025.LAB 3/31/2010 12:59:31 0.708 0.182 0.030 0.268 0.004 8.646 0.014 0.096 0.086 

AGRIUM_WA_RUN 1_000026.LAB 3/31/2010 13:00:01 0.699 0.221 0.028 0.245 0.002 8.693 0.007 0.035 0.084 

Average 0.703 0.201 0.029 0.257 0.003 8.670 0.010 0.065 0.085 

Post Run 1

AGRIUM_WA_RUN 1_000214.LAB 3/31/2010 14:33:49 0.852 0.327 0.206 0.232 -0.005 9.012 0.019 -0.112 0.105 

AGRIUM_WA_RUN 1_000215.LAB 3/31/2010 14:34:19 0.753 0.289 0.218 0.248 -0.004 9.000 0.017 -0.049 0.105 

Average 0.803 0.308 0.212 0.240 -0.005 9.006 0.018 -0.081 0.105 

Post Run 2

AGRIUM_WA_RUN 2_000193.LAB 3/31/2010 16:26:30 0.923 0.097 0.372 0.163 -0.009 9.434 0.022 -0.190 0.082 

AGRIUM_WA_RUN 2_000194.LAB 3/31/2010 16:27:00 0.846 0.269 0.344 0.145 -0.008 9.729 0.032 -0.135 0.081 

Average 0.884 0.183 0.358 0.154 -0.009 9.582 0.027 -0.162 0.082 

Post Run 3

AGRIUM_WA_RUN 3_000186.LAB 3/31/2010 18:09:28 0.917 0.172 0.182 0.059 -0.006 9.248 0.013 0.121 0.089 

AGRIUM_WA_RUN 3_000187.LAB 3/31/2010 18:09:58 0.804 0.214 0.172 0.078 -0.006 8.988 0.007 0.102 0.080 

Average 0.860 0.193 0.177 0.068 -0.006 9.118 0.010 0.111 0.085 

FTIR QUALITY ASSURANCE DATA
 500.2 ppm N2O/10.0 ppm SF6 

Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene H2O% 

AGRIUM_WA_RUN 1_000008.LAB 3/31/2010 12:50:59 481.57 0.688 0.062 0.413 9.981 8.596 0.008 0.181 0.087 

AGRIUM_WA_RUN 1_000009.LAB 3/31/2010 12:51:29 482.02 0.599 0.075 0.431 9.989 8.580 0.012 0.190 0.086 

AGRIUM_WA_RUN 1_000010.LAB 3/31/2010 12:51:59 481.95 0.692 0.079 0.416 9.987 8.580 0.011 0.102 0.084 

AGRIUM_WA_RUN 1_000011.LAB 3/31/2010 12:52:29 482.12 0.793 0.089 0.398 9.988 8.553 0.013 0.116 0.083 

Average 481.92 96.3%

 500.2 ppm N2O/10.0 ppm SF6 Dynamic Spiking

Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene H2O% 

Run 1

AGRIUM_WA_RUN 1_000235.LAB 3/31/2010 14:44:17 323.83 23.396 12.639 0.236 -0.005 9.537 0.060 0.050 0.093 

AGRIUM_WA_RUN 1_000236.LAB 3/31/2010 14:44:47 319.23 23.332 12.835 0.222 -0.007 9.380 0.062 -0.012 0.105 

Pre-Spike Average 321.53 -0.006

AGRIUM_WA_RUN 1_000242.LAB 3/31/2010 14:47:46 329.38 22.074 12.608 0.267 0.439 10.152 0.062 0.345 0.121 

AGRIUM_WA_RUN 1_000243.LAB 3/31/2010 14:48:16 331.71 22.096 12.668 0.225 0.418 10.087 0.055 -0.042 0.115 

Spike Average 330.55 0.428

AGRIUM_WA_RUN 1_000245.LAB 3/31/2010 14:49:16 319.69 23.274 13.207 0.184 -0.005 9.329 0.065 -0.142 0.127 

AGRIUM_WA_RUN 1_000246.LAB 3/31/2010 14:49:46 320.49 23.337 13.129 0.201 -0.004 9.433 0.062 -0.123 0.124 

Post-Spike Average 320.09 -0.004

Run 2

AGRIUM_WA_RUN 2_000171.LAB 3/31/2010 16:15:32 322.05 23.984 13.464 0.167 -0.014 9.614 0.063 -0.074 0.129 

AGRIUM_WA_RUN 2_000172.LAB 3/31/2010 16:16:03 319.90 23.919 13.413 0.122 -0.013 9.587 0.062 -0.066 0.132 

Pre-Spike Average 320.98 -0.014

AGRIUM_WA_RUN 2_000175.LAB 3/31/2010 16:17:32 333.15 22.407 12.483 0.135 0.696 10.109 0.062 -0.131 0.145 

AGRIUM_WA_RUN 2_000176.LAB 3/31/2010 16:18:02 333.15 22.359 12.525 0.113 0.700 10.177 0.069 -0.220 0.144 

Spike Average 333.15 0.698

AGRIUM_WA_RUN 2_000179.LAB 3/31/2010 16:19:32 322.44 23.941 13.384 0.044 -0.014 9.334 0.062 -0.089 0.139 

AGRIUM_WA_RUN 2_000180.LAB 3/31/2010 16:20:02 319.87 24.145 13.395 0.077 -0.016 9.284 0.057 -0.096 0.139 

Post-Spike Average 321.15 -0.015

Run 3

AGRIUM_WA_RUN 3_000227.LAB 3/31/2010 18:29:55 328.17 22.159 12.410 0.113 -0.007 9.647 0.052 0.080 0.119 

AGRIUM_WA_RUN 3_000228.LAB 3/31/2010 18:30:25 325.92 22.306 12.432 0.036 -0.007 9.452 0.052 0.045 0.121 

Pre-Spike Average 327.04 -0.007

AGRIUM_WA_RUN 3_000231.LAB 3/31/2010 18:31:54 335.50 20.322 11.160 0.058 0.914 10.261 0.057 -0.026 0.122 

AGRIUM_WA_RUN 3_000232.LAB 3/31/2010 18:32:24 334.34 20.319 11.254 0.103 0.917 9.885 0.061 0.029 0.123 

Spike Average 334.92 0.915

AGRIUM_WA_RUN 3_000235.LAB 3/31/2010 18:33:54 321.533 22.272 12.314 0.039 -0.008 9.495 0.045 0.138 0.124 

AGRIUM_WA_RUN 3_000236.LAB 3/31/2010 18:34:24 317.851 22.313 12.312 0.080 -0.009 9.384 0.051 0.129 0.123 

Post-Spike Average 319.69 -0.008
SF6 10.0

N2O 500.2

Initial Native Concentration ppm 321.53 

Final Native Concentration ppm 320.09 

Average Native Concentration ppm 320.81 

RPD % 0.4

Sample Gas Response SF6 0.428

Analyte 330.55

Spike Ratio % 4.3%

Background ppm 307.07

Spike Amount ppm 21.43

Expeced Concentration ppm 328.50

Spike Recovery ppm 23.48

Recovery % 109.6

Initial Native Concentration ppm 320.98 

Final Native Concentration ppm 321.15 

Average Native Concentration ppm 321.07 

RPD % 0.1

Sample Gas Response SF6 0.698

Analyte 333.15

Spike Ratio % 7.0%

Background ppm 298.63

Spike Amount ppm 34.95

Expeced Concentration ppm 333.58

Spike Recovery ppm 34.52

Recovery % 98.8

Initial Native Concentration ppm 327.04 

Final Native Concentration ppm 319.69 

Average Native Concentration ppm 323.37 

RPD % 2.3

Sample Gas Response SF6 0.915

Analyte 334.920

Spike Ratio % 9.2%

Background ppm 293.75

Spike Amount ppm 45.81

Expeced Concentration ppm 339.56

Spike Recovery ppm 41.17

Recovery % 89.9

EPA Method 320 Spike Recovery

Tank Value

Run 1

Run 2

Run 3

88
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene 

AGRIUM_WA_RUN 1_000034.LAB 3/31/2010 13:04:01 338.985 25.455 14.105 0.256 0.000 8.601 0.051 0.043 

AGRIUM_WA_RUN 1_000035.LAB 3/31/2010 13:04:31 335.994 25.607 14.044 0.268 0.000 8.940 0.060 0.065 

AGRIUM_WA_RUN 1_000036.LAB 3/31/2010 13:05:01 329.274 25.635 14.078 0.284 0.000 9.009 0.051 0.033 

AGRIUM_WA_RUN 1_000037.LAB 3/31/2010 13:05:30 322.074 25.831 14.058 0.286 0.001 8.836 0.055 -0.019 

AGRIUM_WA_RUN 1_000038.LAB 3/31/2010 13:06:00 315.855 25.896 14.131 0.292 0.001 8.858 0.061 -0.027 

AGRIUM_WA_RUN 1_000039.LAB 3/31/2010 13:06:30 313.258 25.869 14.096 0.276 0.000 8.869 0.056 0.061 

AGRIUM_WA_RUN 1_000040.LAB 3/31/2010 13:07:00 313.076 25.950 14.118 0.264 0.000 8.711 0.056 0.021 

AGRIUM_WA_RUN 1_000041.LAB 3/31/2010 13:07:30 312.088 25.880 14.013 0.262 -0.002 8.589 0.052 -0.075 

AGRIUM_WA_RUN 1_000042.LAB 3/31/2010 13:08:00 312.988 25.950 14.065 0.275 -0.001 8.853 0.050 -0.055 

AGRIUM_WA_RUN 1_000043.LAB 3/31/2010 13:08:30 315.950 25.936 14.015 0.262 -0.001 8.711 0.056 -0.041 

AGRIUM_WA_RUN 1_000044.LAB 3/31/2010 13:09:00 319.757 25.889 14.066 0.249 -0.002 8.779 0.054 -0.027 

AGRIUM_WA_RUN 1_000045.LAB 3/31/2010 13:09:30 323.414 26.076 14.073 0.251 -0.001 8.751 0.059 -0.007 

AGRIUM_WA_RUN 1_000046.LAB 3/31/2010 13:10:00 323.720 26.221 14.316 0.310 -0.001 8.937 0.057 0.024 

AGRIUM_WA_RUN 1_000047.LAB 3/31/2010 13:10:30 325.568 26.419 14.327 0.283 -0.003 8.738 0.060 -0.030 

AGRIUM_WA_RUN 1_000048.LAB 3/31/2010 13:10:59 324.594 26.569 14.196 0.262 -0.003 8.559 0.058 -0.046 

AGRIUM_WA_RUN 1_000049.LAB 3/31/2010 13:11:29 325.232 26.789 14.236 0.304 -0.001 8.858 0.059 -0.078 

AGRIUM_WA_RUN 1_000050.LAB 3/31/2010 13:11:59 325.250 26.735 14.183 0.295 -0.001 8.702 0.064 -0.095 

AGRIUM_WA_RUN 1_000051.LAB 3/31/2010 13:12:29 325.984 26.952 14.072 0.262 -0.001 8.713 0.056 -0.011 

AGRIUM_WA_RUN 1_000052.LAB 3/31/2010 13:12:59 325.827 27.011 13.840 0.300 -0.003 8.805 0.062 -0.034 

AGRIUM_WA_RUN 1_000053.LAB 3/31/2010 13:13:29 326.748 26.961 13.576 0.313 -0.002 8.748 0.061 -0.100 

AGRIUM_WA_RUN 1_000054.LAB 3/31/2010 13:13:59 329.360 26.943 13.425 0.279 -0.003 8.888 0.063 -0.050 

AGRIUM_WA_RUN 1_000055.LAB 3/31/2010 13:14:29 328.551 26.799 13.237 0.275 -0.003 9.084 0.055 -0.055 

AGRIUM_WA_RUN 1_000056.LAB 3/31/2010 13:14:59 326.038 26.574 12.971 0.283 -0.003 9.246 0.055 0.006 

AGRIUM_WA_RUN 1_000057.LAB 3/31/2010 13:15:29 325.888 26.570 12.962 0.291 -0.003 8.946 0.058 -0.020 

AGRIUM_WA_RUN 1_000058.LAB 3/31/2010 13:15:59 324.252 26.539 12.944 0.274 -0.002 8.859 0.059 -0.013 

AGRIUM_WA_RUN 1_000059.LAB 3/31/2010 13:16:29 325.182 26.417 13.005 0.312 -0.002 8.791 0.057 -0.098 

AGRIUM_WA_RUN 1_000060.LAB 3/31/2010 13:16:59 327.048 26.281 13.230 0.275 -0.003 8.747 0.056 0.005 

AGRIUM_WA_RUN 1_000061.LAB 3/31/2010 13:17:28 323.181 26.089 13.458 0.313 -0.001 8.694 0.066 0.015 

AGRIUM_WA_RUN 1_000062.LAB 3/31/2010 13:17:58 321.311 26.023 13.525 0.318 -0.002 8.850 0.058 -0.010 

AGRIUM_WA_RUN 1_000063.LAB 3/31/2010 13:18:28 320.949 25.935 13.651 0.322 -0.002 8.865 0.054 -0.141 

AGRIUM_WA_RUN 1_000064.LAB 3/31/2010 13:18:58 323.687 25.974 13.775 0.275 -0.002 8.763 0.061 -0.026 

AGRIUM_WA_RUN 1_000065.LAB 3/31/2010 13:19:28 326.035 25.951 13.820 0.290 -0.002 8.908 0.057 -0.091 

AGRIUM_WA_RUN 1_000066.LAB 3/31/2010 13:19:58 324.882 25.921 13.914 0.321 -0.001 8.768 0.060 -0.006 

AGRIUM_WA_RUN 1_000067.LAB 3/31/2010 13:20:28 323.774 26.017 13.976 0.299 0.000 8.614 0.064 -0.079 

AGRIUM_WA_RUN 1_000068.LAB 3/31/2010 13:20:58 320.483 25.799 14.057 0.333 0.000 8.757 0.052 -0.084 

AGRIUM_WA_RUN 1_000069.LAB 3/31/2010 13:21:28 320.293 25.813 13.975 0.301 0.000 8.809 0.051 -0.076 

AGRIUM_WA_RUN 1_000070.LAB 3/31/2010 13:21:58 320.809 25.856 14.021 0.297 -0.001 8.812 0.061 -0.073 

AGRIUM_WA_RUN 1_000071.LAB 3/31/2010 13:22:28 319.807 25.847 14.028 0.296 0.000 8.875 0.050 -0.067 

AGRIUM_WA_RUN 1_000072.LAB 3/31/2010 13:22:57 321.853 25.792 14.137 0.260 -0.002 8.685 0.055 -0.016 

AGRIUM_WA_RUN 1_000073.LAB 3/31/2010 13:23:27 323.189 25.781 14.230 0.316 -0.002 8.891 0.049 -0.032 

AGRIUM_WA_RUN 1_000074.LAB 3/31/2010 13:23:57 324.748 25.682 14.134 0.265 -0.001 8.684 0.060 -0.078 

AGRIUM_WA_RUN 1_000075.LAB 3/31/2010 13:24:27 323.787 25.500 14.038 0.258 -0.002 8.826 0.053 -0.017 

AGRIUM_WA_RUN 1_000076.LAB 3/31/2010 13:24:57 320.469 25.586 13.945 0.282 -0.002 8.794 0.054 -0.004 

323.284 26.124 13.862

AGRIUM_WA_RUN 1_000105.LAB 3/31/2010 13:39:25 322.237 24.527 13.228 0.267 -0.003 9.309 0.058 -0.026 

AGRIUM_WA_RUN 1_000106.LAB 3/31/2010 13:39:55 320.194 24.646 13.195 0.230 -0.003 9.194 0.058 -0.015 
Date Time

3/31/2010 13:04:01

3/31/2010 13:04:31

3/31/2010 13:05:01

3/31/2010 13:05:30

3/31/2010 13:06:00

3/31/2010 13:06:30

3/31/2010 13:07:00

3/31/2010 13:07:30

3/31/2010 13:08:00

3/31/2010 13:08:30

3/31/2010 13:09:00

3/31/2010 13:09:30

3/31/2010 13:10:00

3/31/2010 13:10:30

3/31/2010 13:10:59

3/31/2010 13:11:29

3/31/2010 13:11:59

3/31/2010 13:12:29

3/31/2010 13:12:59

3/31/2010 13:13:29

3/31/2010 13:13:59

3/31/2010 13:14:29

3/31/2010 13:14:59

3/31/2010 13:15:29

3/31/2010 13:15:59

3/31/2010 13:16:29

3/31/2010 13:16:59

3/31/2010 13:17:28

3/31/2010 13:17:58

3/31/2010 13:18:28

3/31/2010 13:18:58

3/31/2010 13:19:28

3/31/2010 13:19:58

3/31/2010 13:20:28

3/31/2010 13:20:58

3/31/2010 13:21:28

3/31/2010 13:21:58

3/31/2010 13:22:28

3/31/2010 13:22:57

3/31/2010 13:23:27

3/31/2010 13:23:57

3/31/2010 13:24:27

3/31/2010 13:24:57

3/31/2010 13:39:25

3/31/2010 13:39:55

Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF6 resi

0.958 0.067 0.005 0.039 0.006 1.684 0.025 0.274 0.016 0.001 

0.958 0.061 0.005 0.039 0.005 1.637 0.026 0.273 0.017 0.001 

0.958 0.058 0.005 0.041 0.005 1.539 0.028 0.278 0.016 0.002 

0.958 0.063 0.006 0.042 0.005 1.414 0.026 0.283 0.017 0.001 

0.958 0.067 0.006 0.036 0.005 1.334 0.027 0.277 0.016 0.001 

0.958 0.053 0.005 0.036 0.006 1.284 0.024 0.283 0.016 0.001 

0.958 0.069 0.005 0.047 0.005 1.280 0.030 0.289 0.014 0.002 

0.958 0.063 0.006 0.039 0.005 1.277 0.026 0.294 0.015 0.001 

0.958 0.059 0.005 0.042 0.006 1.301 0.027 0.292 0.016 0.002 

0.958 0.071 0.005 0.035 0.005 1.330 0.024 0.294 0.017 0.001 

0.958 0.070 0.006 0.041 0.005 1.387 0.026 0.296 0.017 0.001 

0.959 0.067 0.005 0.036 0.006 1.430 0.027 0.290 0.018 0.001 

0.959 0.063 0.006 0.039 0.005 1.466 0.027 0.293 0.015 0.001 

0.958 0.069 0.005 0.044 0.005 1.476 0.029 0.304 0.017 0.002 

0.958 0.073 0.006 0.043 0.005 1.472 0.029 0.327 0.017 0.002 

0.958 0.060 0.006 0.039 0.006 1.473 0.027 0.320 0.018 0.001 

0.958 0.073 0.006 0.037 0.006 1.488 0.024 0.339 0.017 0.001 

0.958 0.066 0.006 0.040 0.005 1.491 0.026 0.355 0.019 0.001 

0.958 0.071 0.007 0.033 0.005 1.502 0.027 0.383 0.019 0.001 

0.958 0.070 0.007 0.035 0.005 1.499 0.026 0.398 0.019 0.001 

0.958 0.072 0.007 0.034 0.005 1.526 0.027 0.405 0.020 0.001 

0.957 0.063 0.007 0.037 0.006 1.512 0.026 0.412 0.020 0.001 

0.958 0.069 0.008 0.037 0.006 1.477 0.029 0.408 0.020 0.002 

0.957 0.063 0.007 0.038 0.006 1.478 0.024 0.400 0.021 0.001 

0.957 0.064 0.007 0.038 0.005 1.459 0.028 0.389 0.018 0.001 

0.958 0.071 0.007 0.037 0.005 1.483 0.027 0.369 0.018 0.001 

0.958 0.077 0.007 0.037 0.006 1.512 0.026 0.361 0.020 0.001 

0.958 0.069 0.007 0.041 0.005 1.480 0.028 0.361 0.017 0.001 

0.958 0.070 0.006 0.040 0.005 1.434 0.026 0.349 0.017 0.001 

0.958 0.067 0.006 0.038 0.006 1.420 0.028 0.347 0.018 0.001 

0.957 0.063 0.006 0.038 0.005 1.446 0.026 0.347 0.019 0.001 

0.958 0.067 0.006 0.037 0.005 1.466 0.027 0.338 0.020 0.001 

0.958 0.076 0.006 0.038 0.006 1.479 0.028 0.341 0.018 0.001 

0.958 0.068 0.007 0.036 0.005 1.464 0.027 0.344 0.018 0.001 

0.957 0.072 0.006 0.034 0.006 1.405 0.026 0.337 0.018 0.001 

0.957 0.065 0.006 0.040 0.006 1.400 0.029 0.334 0.018 0.002 

0.957 0.072 0.006 0.039 0.006 1.420 0.028 0.331 0.017 0.001 

0.957 0.065 0.006 0.039 0.005 1.398 0.028 0.333 0.018 0.002 

0.957 0.067 0.006 0.043 0.006 1.409 0.029 0.323 0.021 0.002 

0.957 0.065 0.007 0.040 0.006 1.431 0.028 0.328 0.019 0.001 

0.957 0.068 0.006 0.039 0.006 1.454 0.028 0.322 0.018 0.002 

0.957 0.067 0.006 0.038 0.006 1.435 0.027 0.326 0.019 0.001 

0.956 0.063 0.006 0.039 0.005 1.390 0.028 0.327 0.019 0.001 

0.957 0.071 0.005 0.038 0.005 1.415 0.028 0.266 0.016 0.001 

0.957 0.064 0.005 0.044 0.005 1.408 0.028 0.267 0.017 0.002 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene 

AGRIUM_WA_RUN 1_000107.LAB 3/31/2010 13:40:24 317.966 24.734 13.137 0.224 -0.002 8.856 0.058 -0.024 

AGRIUM_WA_RUN 1_000108.LAB 3/31/2010 13:40:54 318.396 24.646 13.174 0.273 -0.002 8.857 0.065 -0.033 

AGRIUM_WA_RUN 1_000109.LAB 3/31/2010 13:41:24 319.197 24.733 13.224 0.245 -0.002 8.814 0.057 -0.111 

AGRIUM_WA_RUN 1_000110.LAB 3/31/2010 13:41:54 316.952 24.599 13.161 0.255 -0.003 8.807 0.058 0.018 

AGRIUM_WA_RUN 1_000111.LAB 3/31/2010 13:42:24 319.248 24.514 13.152 0.263 -0.002 8.821 0.060 0.049 

AGRIUM_WA_RUN 1_000112.LAB 3/31/2010 13:42:54 324.792 24.449 13.219 0.238 -0.001 8.843 0.062 -0.123 

AGRIUM_WA_RUN 1_000113.LAB 3/31/2010 13:43:24 324.500 24.399 13.326 0.235 -0.002 8.973 0.063 0.002 

AGRIUM_WA_RUN 1_000114.LAB 3/31/2010 13:43:54 335.826 24.416 13.212 0.240 -0.002 8.959 0.059 -0.136 

AGRIUM_WA_RUN 1_000115.LAB 3/31/2010 13:44:24 342.237 24.187 13.153 0.265 -0.002 9.088 0.061 0.027 

AGRIUM_WA_RUN 1_000116.LAB 3/31/2010 13:44:54 337.245 24.330 13.138 0.240 -0.004 8.985 0.056 -0.025 

AGRIUM_WA_RUN 1_000117.LAB 3/31/2010 13:45:24 330.464 24.205 13.064 0.253 -0.002 8.991 0.061 0.001 

AGRIUM_WA_RUN 1_000118.LAB 3/31/2010 13:45:54 327.163 24.437 13.100 0.242 -0.002 8.924 0.062 -0.022 

AGRIUM_WA_RUN 1_000119.LAB 3/31/2010 13:46:23 329.811 24.411 13.184 0.230 -0.002 8.888 0.059 -0.036 

AGRIUM_WA_RUN 1_000120.LAB 3/31/2010 13:46:53 331.201 24.361 13.267 0.235 -0.002 9.018 0.060 -0.063 

AGRIUM_WA_RUN 1_000121.LAB 3/31/2010 13:47:23 327.394 24.487 13.197 0.251 -0.003 8.842 0.061 -0.031 

AGRIUM_WA_RUN 1_000122.LAB 3/31/2010 13:47:53 325.315 24.500 13.262 0.232 -0.002 8.890 0.058 0.016 

AGRIUM_WA_RUN 1_000123.LAB 3/31/2010 13:48:23 323.614 24.363 13.180 0.254 -0.003 8.851 0.062 -0.023 

AGRIUM_WA_RUN 1_000124.LAB 3/31/2010 13:48:53 325.672 24.307 13.170 0.262 -0.003 8.728 0.059 -0.037 

AGRIUM_WA_RUN 1_000125.LAB 3/31/2010 13:49:23 328.402 24.214 13.279 0.254 -0.001 8.984 0.056 -0.071 

AGRIUM_WA_RUN 1_000126.LAB 3/31/2010 13:49:53 327.433 24.245 13.200 0.242 -0.002 8.928 0.059 0.039 

AGRIUM_WA_RUN 1_000127.LAB 3/31/2010 13:50:23 323.056 24.393 13.078 0.238 -0.002 8.942 0.056 -0.005 

AGRIUM_WA_RUN 1_000128.LAB 3/31/2010 13:50:53 319.910 24.350 13.102 0.275 -0.002 8.937 0.057 -0.070 

AGRIUM_WA_RUN 1_000129.LAB 3/31/2010 13:51:23 318.062 24.339 13.096 0.238 -0.003 8.819 0.062 -0.027 

AGRIUM_WA_RUN 1_000130.LAB 3/31/2010 13:51:53 319.697 24.197 13.025 0.234 -0.002 8.811 0.062 0.060 

AGRIUM_WA_RUN 1_000131.LAB 3/31/2010 13:52:22 321.929 24.307 13.008 0.264 -0.002 8.895 0.062 0.000 

AGRIUM_WA_RUN 1_000132.LAB 3/31/2010 13:52:52 320.520 24.434 12.933 0.273 -0.002 9.032 0.052 0.000 

AGRIUM_WA_RUN 1_000133.LAB 3/31/2010 13:53:22 316.422 24.518 12.923 0.246 -0.002 9.033 0.061 -0.039 

AGRIUM_WA_RUN 1_000134.LAB 3/31/2010 13:53:52 320.992 24.301 12.921 0.256 -0.004 9.050 0.051 -0.026 

AGRIUM_WA_RUN 1_000135.LAB 3/31/2010 13:54:22 331.472 24.072 12.998 0.270 -0.002 9.052 0.057 0.011 

AGRIUM_WA_RUN 1_000136.LAB 3/31/2010 13:54:52 338.170 24.025 12.934 0.242 -0.001 8.807 0.051 -0.085 

AGRIUM_WA_RUN 1_000137.LAB 3/31/2010 13:55:22 338.379 24.096 12.921 0.281 -0.004 8.834 0.049 -0.039 

AGRIUM_WA_RUN 1_000138.LAB 3/31/2010 13:55:52 333.821 24.162 12.878 0.305 -0.004 8.829 0.057 -0.054 

AGRIUM_WA_RUN 1_000139.LAB 3/31/2010 13:56:22 329.757 24.125 12.882 0.264 -0.002 8.979 0.052 -0.009 

AGRIUM_WA_RUN 1_000140.LAB 3/31/2010 13:56:52 325.298 24.210 12.859 0.240 -0.003 8.884 0.054 0.007 

AGRIUM_WA_RUN 1_000141.LAB 3/31/2010 13:57:22 321.495 24.183 12.782 0.239 -0.004 9.003 0.054 -0.012 

AGRIUM_WA_RUN 1_000142.LAB 3/31/2010 13:57:52 320.052 24.177 12.804 0.232 -0.003 9.031 0.051 0.048 

AGRIUM_WA_RUN 1_000143.LAB 3/31/2010 13:58:21 319.188 24.303 12.876 0.232 -0.002 9.023 0.052 -0.104 

AGRIUM_WA_RUN 1_000144.LAB 3/31/2010 13:58:51 321.811 24.194 12.907 0.281 -0.003 9.087 0.054 -0.008 

AGRIUM_WA_RUN 1_000145.LAB 3/31/2010 13:59:21 324.485 24.204 12.886 0.254 -0.003 8.958 0.056 -0.003 

AGRIUM_WA_RUN 1_000146.LAB 3/31/2010 13:59:51 322.309 24.207 12.931 0.222 -0.003 9.005 0.055 -0.030 

AGRIUM_WA_RUN 1_000147.LAB 3/31/2010 14:00:21 319.722 24.145 12.981 0.242 -0.004 8.942 0.053 0.004 

325.158 24.341 13.069

AGRIUM_WA_RUN 1_000167.LAB 3/31/2010 14:10:19 320.879 23.604 13.108 0.227 -0.004 9.106 0.064 -0.030 

AGRIUM_WA_RUN 1_000168.LAB 3/31/2010 14:10:49 320.542 23.574 13.093 0.227 -0.003 8.882 0.066 -0.055 

AGRIUM_WA_RUN 1_000169.LAB 3/31/2010 14:11:19 321.882 23.650 13.191 0.205 -0.005 8.857 0.065 -0.029 

AGRIUM_WA_RUN 1_000170.LAB 3/31/2010 14:11:49 325.553 23.589 13.236 0.208 -0.004 9.096 0.057 -0.012 
Date Time

3/31/2010 13:40:24

3/31/2010 13:40:54

3/31/2010 13:41:24

3/31/2010 13:41:54

3/31/2010 13:42:24

3/31/2010 13:42:54

3/31/2010 13:43:24

3/31/2010 13:43:54

3/31/2010 13:44:24

3/31/2010 13:44:54

3/31/2010 13:45:24

3/31/2010 13:45:54

3/31/2010 13:46:23

3/31/2010 13:46:53

3/31/2010 13:47:23

3/31/2010 13:47:53

3/31/2010 13:48:23

3/31/2010 13:48:53

3/31/2010 13:49:23

3/31/2010 13:49:53

3/31/2010 13:50:23

3/31/2010 13:50:53

3/31/2010 13:51:23

3/31/2010 13:51:53

3/31/2010 13:52:22

3/31/2010 13:52:52

3/31/2010 13:53:22

3/31/2010 13:53:52

3/31/2010 13:54:22

3/31/2010 13:54:52

3/31/2010 13:55:22

3/31/2010 13:55:52

3/31/2010 13:56:22

3/31/2010 13:56:52

3/31/2010 13:57:22

3/31/2010 13:57:52

3/31/2010 13:58:21

3/31/2010 13:58:51

3/31/2010 13:59:21

3/31/2010 13:59:51

3/31/2010 14:00:21

3/31/2010 14:10:19

3/31/2010 14:10:49

3/31/2010 14:11:19

3/31/2010 14:11:49

Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF6 resi

0.958 0.076 0.005 0.042 0.005 1.386 0.030 0.281 0.015 0.002 

0.958 0.073 0.006 0.038 0.005 1.401 0.029 0.275 0.014 0.002 

0.957 0.069 0.006 0.040 0.006 1.413 0.029 0.283 0.015 0.002 

0.957 0.067 0.005 0.037 0.005 1.370 0.032 0.281 0.014 0.002 

0.957 0.068 0.006 0.039 0.005 1.409 0.028 0.287 0.015 0.001 

0.957 0.072 0.005 0.035 0.006 1.468 0.028 0.280 0.016 0.001 

0.957 0.072 0.005 0.035 0.005 1.466 0.027 0.279 0.016 0.001 

0.957 0.074 0.005 0.035 0.005 1.665 0.026 0.294 0.015 0.001 

0.957 0.073 0.006 0.040 0.006 1.764 0.028 0.293 0.016 0.001 

0.957 0.072 0.005 0.038 0.006 1.659 0.027 0.288 0.016 0.001 

0.957 0.064 0.006 0.037 0.005 1.578 0.026 0.293 0.017 0.001 

0.957 0.070 0.006 0.037 0.005 1.505 0.026 0.297 0.016 0.001 

0.957 0.068 0.006 0.037 0.005 1.547 0.028 0.299 0.015 0.001 

0.957 0.076 0.005 0.037 0.006 1.572 0.027 0.295 0.016 0.001 

0.957 0.070 0.006 0.037 0.005 1.519 0.026 0.298 0.016 0.001 

0.957 0.068 0.006 0.037 0.005 1.476 0.029 0.294 0.016 0.001 

0.957 0.069 0.006 0.039 0.005 1.457 0.028 0.296 0.016 0.001 

0.957 0.068 0.006 0.037 0.005 1.487 0.026 0.296 0.017 0.001 

0.957 0.067 0.006 0.036 0.005 1.525 0.027 0.299 0.016 0.001 

0.957 0.076 0.006 0.038 0.005 1.513 0.027 0.297 0.015 0.001 

0.957 0.070 0.005 0.038 0.005 1.449 0.026 0.304 0.016 0.001 

0.957 0.063 0.006 0.035 0.005 1.375 0.025 0.301 0.016 0.001 

0.957 0.063 0.006 0.036 0.005 1.369 0.027 0.299 0.016 0.001 

0.957 0.065 0.005 0.038 0.005 1.387 0.027 0.304 0.015 0.001 

0.957 0.069 0.006 0.036 0.005 1.419 0.026 0.308 0.016 0.001 

0.957 0.072 0.006 0.036 0.006 1.402 0.025 0.305 0.016 0.001 

0.957 0.069 0.006 0.040 0.005 1.325 0.028 0.303 0.016 0.002 

0.957 0.069 0.006 0.038 0.005 1.414 0.027 0.308 0.016 0.001 

0.957 0.071 0.005 0.036 0.005 1.588 0.025 0.310 0.016 0.001 

0.957 0.066 0.006 0.037 0.006 1.708 0.028 0.314 0.015 0.002 

0.957 0.074 0.006 0.031 0.005 1.712 0.026 0.315 0.016 0.001 

0.957 0.071 0.006 0.034 0.004 1.644 0.028 0.320 0.015 0.001 

0.957 0.067 0.006 0.035 0.005 1.561 0.026 0.315 0.015 0.001 

0.957 0.076 0.005 0.039 0.005 1.459 0.026 0.315 0.018 0.001 

0.957 0.073 0.005 0.038 0.006 1.430 0.027 0.312 0.017 0.001 

0.957 0.070 0.006 0.037 0.006 1.382 0.028 0.311 0.016 0.001 

0.956 0.063 0.006 0.038 0.005 1.377 0.026 0.313 0.017 0.001 

0.956 0.067 0.006 0.038 0.006 1.416 0.026 0.309 0.018 0.001 

0.956 0.067 0.006 0.034 0.005 1.453 0.025 0.316 0.016 0.001 

0.957 0.076 0.006 0.037 0.005 1.416 0.026 0.313 0.018 0.001 

0.957 0.071 0.005 0.038 0.005 1.381 0.025 0.319 0.016 0.001 

0.956 0.073 0.006 0.040 0.006 1.418 0.031 0.262 0.015 0.002 

0.956 0.077 0.006 0.039 0.006 1.401 0.030 0.261 0.016 0.002 

0.956 0.077 0.005 0.037 0.006 1.418 0.027 0.265 0.016 0.001 

0.956 0.067 0.005 0.043 0.006 1.459 0.030 0.267 0.017 0.002 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene 

AGRIUM_WA_RUN 1_000171.LAB 3/31/2010 14:12:19 323.437 23.618 13.218 0.250 -0.003 9.079 0.060 -0.023 

AGRIUM_WA_RUN 1_000172.LAB 3/31/2010 14:12:49 318.268 23.801 13.238 0.233 -0.003 9.320 0.055 0.008 

AGRIUM_WA_RUN 1_000173.LAB 3/31/2010 14:13:19 319.381 23.345 13.181 0.193 -0.004 9.038 0.056 -0.048 

AGRIUM_WA_RUN 1_000174.LAB 3/31/2010 14:13:49 324.307 23.646 13.152 0.261 -0.004 9.094 0.054 -0.115 

AGRIUM_WA_RUN 1_000175.LAB 3/31/2010 14:14:19 329.537 23.529 13.177 0.261 -0.004 8.975 0.060 -0.038 

AGRIUM_WA_RUN 1_000176.LAB 3/31/2010 14:14:49 336.753 23.394 13.171 0.229 -0.004 8.800 0.061 -0.091 

AGRIUM_WA_RUN 1_000177.LAB 3/31/2010 14:15:18 334.455 23.543 13.144 0.231 -0.004 8.912 0.062 -0.009 

AGRIUM_WA_RUN 1_000178.LAB 3/31/2010 14:15:48 327.696 23.661 13.182 0.251 -0.003 8.895 0.061 -0.047 

AGRIUM_WA_RUN 1_000179.LAB 3/31/2010 14:16:18 322.959 23.892 13.200 0.249 -0.004 8.762 0.064 -0.018 

AGRIUM_WA_RUN 1_000180.LAB 3/31/2010 14:16:48 319.956 23.491 13.170 0.245 -0.003 8.963 0.062 -0.136 

AGRIUM_WA_RUN 1_000181.LAB 3/31/2010 14:17:18 325.881 23.447 13.185 0.242 -0.004 8.872 0.054 -0.065 

AGRIUM_WA_RUN 1_000182.LAB 3/31/2010 14:17:48 327.133 23.424 13.156 0.236 -0.004 8.852 0.060 -0.116 

AGRIUM_WA_RUN 1_000183.LAB 3/31/2010 14:18:18 322.847 23.436 13.132 0.226 -0.004 8.881 0.061 -0.175 

AGRIUM_WA_RUN 1_000184.LAB 3/31/2010 14:18:48 316.675 23.518 13.085 0.232 -0.005 8.827 0.060 -0.062 

AGRIUM_WA_RUN 1_000185.LAB 3/31/2010 14:19:18 314.831 23.667 13.064 0.219 -0.004 8.849 0.060 -0.037 

AGRIUM_WA_RUN 1_000186.LAB 3/31/2010 14:19:48 323.979 23.584 13.101 0.206 -0.004 9.006 0.056 -0.006 

AGRIUM_WA_RUN 1_000187.LAB 3/31/2010 14:20:18 331.952 23.429 13.001 0.202 -0.005 8.950 0.054 -0.087 

AGRIUM_WA_RUN 1_000188.LAB 3/31/2010 14:20:48 333.377 23.492 12.998 0.230 -0.004 8.938 0.054 -0.082 

AGRIUM_WA_RUN 1_000189.LAB 3/31/2010 14:21:17 330.547 23.565 13.013 0.246 -0.005 9.084 0.058 -0.155 

AGRIUM_WA_RUN 1_000190.LAB 3/31/2010 14:21:53 325.203 23.628 13.044 0.211 -0.006 9.115 0.062 0.036 

AGRIUM_WA_RUN 1_000191.LAB 3/31/2010 14:22:22 321.306 23.567 13.056 0.254 -0.005 8.995 0.058 -0.022 

AGRIUM_WA_RUN 1_000192.LAB 3/31/2010 14:22:51 318.582 23.553 13.146 0.234 -0.005 8.948 0.055 -0.026 

AGRIUM_WA_RUN 1_000193.LAB 3/31/2010 14:23:21 316.905 23.574 13.064 0.233 -0.005 8.788 0.066 -0.075 

AGRIUM_WA_RUN 1_000194.LAB 3/31/2010 14:23:51 317.867 23.679 13.098 0.225 -0.005 8.872 0.055 -0.069 

AGRIUM_WA_RUN 1_000195.LAB 3/31/2010 14:24:21 318.621 23.489 13.058 0.229 -0.005 8.789 0.061 -0.062 

AGRIUM_WA_RUN 1_000196.LAB 3/31/2010 14:24:51 317.583 23.655 13.085 0.223 -0.006 8.966 0.061 -0.005 

AGRIUM_WA_RUN 1_000197.LAB 3/31/2010 14:25:20 316.865 23.692 13.091 0.252 -0.006 8.919 0.062 -0.026 

AGRIUM_WA_RUN 1_000198.LAB 3/31/2010 14:25:50 317.306 23.690 13.094 0.277 -0.006 8.846 0.058 -0.044 

AGRIUM_WA_RUN 1_000199.LAB 3/31/2010 14:26:20 318.888 23.693 13.162 0.262 -0.006 9.081 0.056 -0.037 

AGRIUM_WA_RUN 1_000200.LAB 3/31/2010 14:26:50 319.006 23.639 13.157 0.261 -0.006 8.998 0.056 -0.072 

AGRIUM_WA_RUN 1_000201.LAB 3/31/2010 14:27:20 318.783 23.689 13.254 0.245 -0.006 8.887 0.057 -0.059 

AGRIUM_WA_RUN 1_000202.LAB 3/31/2010 14:27:50 318.816 23.726 13.265 0.259 -0.006 8.896 0.058 -0.084 

AGRIUM_WA_RUN 1_000203.LAB 3/31/2010 14:28:20 318.710 23.829 13.154 0.258 -0.007 8.973 0.058 -0.141 

AGRIUM_WA_RUN 1_000204.LAB 3/31/2010 14:28:50 320.854 23.712 13.175 0.228 -0.007 9.101 0.053 -0.105 

AGRIUM_WA_RUN 1_000205.LAB 3/31/2010 14:29:20 322.373 23.676 13.204 0.236 -0.007 8.974 0.061 -0.077 

AGRIUM_WA_RUN 1_000206.LAB 3/31/2010 14:29:50 322.006 23.773 13.172 0.265 -0.006 8.934 0.057 -0.099 

AGRIUM_WA_RUN 1_000207.LAB 3/31/2010 14:30:20 321.711 23.781 13.138 0.269 -0.007 8.931 0.058 -0.114 

AGRIUM_WA_RUN 1_000208.LAB 3/31/2010 14:30:49 321.930 23.755 13.119 0.254 -0.006 9.030 0.053 -0.049 

AGRIUM_WA_RUN 1_000209.LAB 3/31/2010 14:31:19 323.096 23.717 13.139 0.268 -0.007 9.058 0.059 -0.173 

322.540 23.614 13.137
Date Time

3/31/2010 14:12:19

3/31/2010 14:12:49

3/31/2010 14:13:19

3/31/2010 14:13:49

3/31/2010 14:14:19

3/31/2010 14:14:49

3/31/2010 14:15:18

3/31/2010 14:15:48

3/31/2010 14:16:18

3/31/2010 14:16:48

3/31/2010 14:17:18

3/31/2010 14:17:48

3/31/2010 14:18:18

3/31/2010 14:18:48

3/31/2010 14:19:18

3/31/2010 14:19:48

3/31/2010 14:20:18

3/31/2010 14:20:48

3/31/2010 14:21:17

3/31/2010 14:21:53

3/31/2010 14:22:22

3/31/2010 14:22:51

3/31/2010 14:23:21

3/31/2010 14:23:51

3/31/2010 14:24:21

3/31/2010 14:24:51

3/31/2010 14:25:20

3/31/2010 14:25:50

3/31/2010 14:26:20

3/31/2010 14:26:50

3/31/2010 14:27:20

3/31/2010 14:27:50

3/31/2010 14:28:20

3/31/2010 14:28:50

3/31/2010 14:29:20

3/31/2010 14:29:50

3/31/2010 14:30:20

3/31/2010 14:30:49

3/31/2010 14:31:19

Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF6 resi

0.956 0.063 0.005 0.042 0.005 1.436 0.030 0.272 0.016 0.002 

0.956 0.067 0.006 0.042 0.007 1.357 0.030 0.267 0.017 0.002 

0.956 0.077 0.006 0.042 0.006 1.368 0.029 0.273 0.018 0.002 

0.956 0.076 0.006 0.042 0.006 1.460 0.028 0.275 0.016 0.002 

0.956 0.069 0.005 0.039 0.006 1.564 0.029 0.281 0.016 0.002 

0.956 0.080 0.006 0.044 0.006 1.656 0.030 0.278 0.017 0.002 

0.956 0.081 0.005 0.044 0.006 1.638 0.032 0.279 0.016 0.002 

0.956 0.084 0.006 0.044 0.007 1.522 0.031 0.286 0.017 0.002 

0.956 0.080 0.006 0.043 0.006 1.448 0.031 0.286 0.015 0.002 

0.955 0.079 0.006 0.043 0.006 1.406 0.031 0.292 0.018 0.002 

0.955 0.076 0.006 0.041 0.006 1.475 0.029 0.290 0.018 0.002 

0.955 0.081 0.006 0.045 0.007 1.497 0.032 0.288 0.018 0.002 

0.956 0.084 0.006 0.045 0.006 1.428 0.032 0.296 0.019 0.002 

0.955 0.079 0.006 0.045 0.006 1.336 0.032 0.300 0.017 0.002 

0.955 0.079 0.006 0.045 0.006 1.319 0.033 0.301 0.019 0.002 

0.955 0.069 0.006 0.045 0.006 1.436 0.031 0.294 0.018 0.002 

0.955 0.072 0.006 0.046 0.007 1.554 0.030 0.299 0.020 0.002 

0.955 0.078 0.006 0.046 0.007 1.589 0.031 0.296 0.019 0.002 

0.955 0.076 0.007 0.043 0.006 1.527 0.032 0.292 0.018 0.002 

0.955 0.074 0.006 0.041 0.007 1.456 0.032 0.300 0.019 0.002 

0.955 0.074 0.006 0.045 0.006 1.394 0.032 0.298 0.019 0.002 

0.955 0.076 0.006 0.041 0.007 1.354 0.033 0.295 0.021 0.002 

0.955 0.084 0.006 0.044 0.008 1.341 0.035 0.298 0.020 0.002 

0.955 0.081 0.006 0.044 0.008 1.354 0.034 0.303 0.019 0.002 

0.955 0.082 0.007 0.045 0.008 1.367 0.035 0.302 0.018 0.002 

0.955 0.080 0.007 0.044 0.007 1.342 0.034 0.300 0.019 0.002 

0.955 0.080 0.006 0.045 0.008 1.338 0.034 0.300 0.019 0.002 

0.955 0.074 0.006 0.050 0.008 1.333 0.037 0.301 0.019 0.002 

0.955 0.078 0.006 0.050 0.008 1.351 0.034 0.303 0.019 0.002 

0.955 0.081 0.007 0.048 0.008 1.351 0.036 0.297 0.020 0.002 

0.955 0.079 0.007 0.046 0.007 1.351 0.036 0.297 0.020 0.002 

0.955 0.069 0.006 0.047 0.008 1.353 0.035 0.301 0.022 0.002 

0.955 0.083 0.007 0.049 0.008 1.368 0.035 0.305 0.021 0.002 

0.955 0.080 0.006 0.049 0.008 1.381 0.037 0.308 0.021 0.002 

0.955 0.085 0.007 0.052 0.008 1.413 0.038 0.304 0.020 0.002 

0.955 0.073 0.007 0.053 0.008 1.404 0.038 0.308 0.021 0.002 

0.955 0.084 0.006 0.051 0.008 1.395 0.039 0.301 0.021 0.002 

0.955 0.084 0.007 0.049 0.008 1.415 0.036 0.313 0.020 0.002 

0.955 0.079 0.007 0.052 0.008 1.418 0.039 0.309 0.022 0.002 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethyle

AGRIUM_WA_RUN 2_000001.LAB 3/31/2010 14:50:48 328.157 23.265 13.023 0.237 -0.004 9.440 0.057 -0.08

AGRIUM_WA_RUN 2_000002.LAB 3/31/2010 14:51:18 330.269 23.438 12.990 0.267 -0.005 9.514 0.057 -0.06

AGRIUM_WA_RUN 2_000003.LAB 3/31/2010 14:51:48 331.195 23.479 13.025 0.264 -0.005 9.450 0.055 -0.14

AGRIUM_WA_RUN 2_000004.LAB 3/31/2010 14:52:17 327.937 23.521 12.992 0.246 -0.005 9.539 0.049 -0.19

AGRIUM_WA_RUN 2_000005.LAB 3/31/2010 14:52:48 323.146 23.607 12.973 0.254 -0.004 9.688 0.060 -0.05

AGRIUM_WA_RUN 2_000006.LAB 3/31/2010 14:53:17 319.838 23.497 12.893 0.248 -0.004 9.412 0.054 -0.08

AGRIUM_WA_RUN 2_000007.LAB 3/31/2010 14:53:47 320.347 23.665 12.893 0.253 -0.004 9.380 0.058 -0.15

AGRIUM_WA_RUN 2_000008.LAB 3/31/2010 14:54:17 323.407 23.678 12.942 0.255 -0.004 9.181 0.057 -0.14

AGRIUM_WA_RUN 2_000009.LAB 3/31/2010 14:54:47 322.084 23.749 12.970 0.276 -0.006 9.252 0.059 -0.11

AGRIUM_WA_RUN 2_000010.LAB 3/31/2010 14:55:17 320.423 23.767 12.948 0.249 -0.006 9.239 0.065 -0.04

AGRIUM_WA_RUN 2_000011.LAB 3/31/2010 14:55:47 318.012 23.668 12.858 0.261 -0.005 9.373 0.065 -0.21

AGRIUM_WA_RUN 2_000012.LAB 3/31/2010 14:56:17 319.119 23.725 12.805 0.266 -0.005 9.147 0.057 -0.16

AGRIUM_WA_RUN 2_000013.LAB 3/31/2010 14:56:47 320.716 23.639 12.861 0.263 -0.005 9.296 0.060 -0.06

AGRIUM_WA_RUN 2_000014.LAB 3/31/2010 14:57:17 323.800 23.599 12.986 0.245 -0.006 9.207 0.066 -0.12

AGRIUM_WA_RUN 2_000015.LAB 3/31/2010 14:57:47 324.812 23.562 12.995 0.230 -0.006 9.145 0.065 -0.07

AGRIUM_WA_RUN 2_000016.LAB 3/31/2010 14:58:16 322.457 23.521 12.982 0.231 -0.007 9.249 0.063 -0.09

AGRIUM_WA_RUN 2_000017.LAB 3/31/2010 14:58:46 322.491 23.532 12.931 0.225 -0.006 9.133 0.064 -0.22

AGRIUM_WA_RUN 2_000018.LAB 3/31/2010 14:59:16 325.333 23.612 13.070 0.225 -0.008 9.116 0.058 -0.04

AGRIUM_WA_RUN 2_000019.LAB 3/31/2010 14:59:46 324.869 23.544 13.034 0.191 -0.007 9.067 0.057 -0.12

AGRIUM_WA_RUN 2_000020.LAB 3/31/2010 15:00:16 321.808 23.692 13.016 0.232 -0.007 9.187 0.055 -0.09

AGRIUM_WA_RUN 2_000021.LAB 3/31/2010 15:00:46 321.521 23.739 12.982 0.210 -0.007 9.009 0.060 -0.14

AGRIUM_WA_RUN 2_000022.LAB 3/31/2010 15:01:16 323.318 23.727 13.016 0.187 -0.008 8.949 0.059 -0.11

AGRIUM_WA_RUN 2_000023.LAB 3/31/2010 15:01:46 323.977 23.740 13.083 0.217 -0.007 9.042 0.063 -0.11

AGRIUM_WA_RUN 2_000024.LAB 3/31/2010 15:02:16 321.773 23.778 13.028 0.217 -0.007 9.119 0.060 -0.06

AGRIUM_WA_RUN 2_000025.LAB 3/31/2010 15:02:46 320.260 23.688 13.017 0.230 -0.007 9.280 0.059 -0.05

AGRIUM_WA_RUN 2_000026.LAB 3/31/2010 15:03:16 320.798 23.744 13.099 0.213 -0.008 9.116 0.062 -0.08

AGRIUM_WA_RUN 2_000027.LAB 3/31/2010 15:03:45 322.152 23.813 13.050 0.199 -0.007 9.134 0.058 -0.13

AGRIUM_WA_RUN 2_000028.LAB 3/31/2010 15:04:15 325.107 23.814 13.088 0.200 -0.008 9.004 0.064 -0.05

AGRIUM_WA_RUN 2_000029.LAB 3/31/2010 15:04:45 326.706 23.815 13.131 0.183 -0.008 9.035 0.059 -0.05

AGRIUM_WA_RUN 2_000030.LAB 3/31/2010 15:05:15 326.621 23.871 13.157 0.182 -0.009 9.100 0.064 -0.02

AGRIUM_WA_RUN 2_000031.LAB 3/31/2010 15:05:45 327.382 23.888 13.092 0.195 -0.009 8.996 0.061 -0.01

AGRIUM_WA_RUN 2_000032.LAB 3/31/2010 15:06:15 329.993 23.775 13.211 0.171 -0.008 9.199 0.062 -0.12

AGRIUM_WA_RUN 2_000033.LAB 3/31/2010 15:06:45 330.439 23.843 13.204 0.184 -0.009 9.254 0.064 -0.05

AGRIUM_WA_RUN 2_000034.LAB 3/31/2010 15:07:15 328.548 23.978 13.275 0.152 -0.009 9.069 0.069 -0.03

AGRIUM_WA_RUN 2_000035.LAB 3/31/2010 15:07:45 325.423 23.767 13.354 0.148 -0.009 9.327 0.054 -0.01

AGRIUM_WA_RUN 2_000036.LAB 3/31/2010 15:08:15 317.233 24.123 13.323 0.172 -0.009 9.019 0.064 -0.07

AGRIUM_WA_RUN 2_000037.LAB 3/31/2010 15:08:44 308.937 24.099 13.326 0.145 -0.010 8.961 0.058 -0.14

AGRIUM_WA_RUN 2_000038.LAB 3/31/2010 15:09:14 310.869 24.097 13.342 0.196 -0.009 9.242 0.060 -0.12

AGRIUM_WA_RUN 2_000039.LAB 3/31/2010 15:09:44 316.995 24.075 13.311 0.133 -0.010 8.930 0.060 -0.03

AGRIUM_WA_RUN 2_000040.LAB 3/31/2010 15:10:14 330.038 23.992 13.310 0.166 -0.010 9.113 0.056 -0.05

AGRIUM_WA_RUN 2_000041.LAB 3/31/2010 15:10:44 337.452 23.959 13.282 0.170 -0.009 8.968 0.070 -0.08

AGRIUM_WA_RUN 2_000042.LAB 3/31/2010 15:11:14 333.199 23.897 13.373 0.146 -0.011 9.080 0.053 -0.06

323.785 23.738 13.077
Date Time

3/31/2010 14:50:48

3/31/2010 14:51:18

3/31/2010 14:51:48

3/31/2010 14:52:17

3/31/2010 14:52:48

3/31/2010 14:53:17

3/31/2010 14:53:47

3/31/2010 14:54:17

3/31/2010 14:54:47

3/31/2010 14:55:17

3/31/2010 14:55:47

3/31/2010 14:56:17

3/31/2010 14:56:47

3/31/2010 14:57:17

3/31/2010 14:57:47

3/31/2010 14:58:16

3/31/2010 14:58:46

3/31/2010 14:59:16

3/31/2010 14:59:46

3/31/2010 15:00:16

3/31/2010 15:00:46

3/31/2010 15:01:16

3/31/2010 15:01:46

3/31/2010 15:02:16

3/31/2010 15:02:46

3/31/2010 15:03:16

3/31/2010 15:03:45

3/31/2010 15:04:15

3/31/2010 15:04:45

3/31/2010 15:05:15

3/31/2010 15:05:45

3/31/2010 15:06:15

3/31/2010 15:06:45

3/31/2010 15:07:15

3/31/2010 15:07:45

3/31/2010 15:08:15

3/31/2010 15:08:44

3/31/2010 15:09:14

3/31/2010 15:09:44

3/31/2010 15:10:14

3/31/2010 15:10:44

3/31/2010 15:11:14

Temp (C) Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF

191.4 0.955 0.084 0.006 0.055 0.010 1.510 0.041 0.281 0.022 

191.4 0.955 0.089 0.006 0.053 0.009 1.548 0.042 0.279 0.022 

191.5 0.955 0.081 0.006 0.057 0.009 1.572 0.039 0.290 0.024 

191.3 0.955 0.089 0.006 0.054 0.008 1.524 0.041 0.286 0.021 

191.3 0.955 0.086 0.006 0.054 0.009 1.435 0.040 0.281 0.023 

191.2 0.955 0.085 0.006 0.052 0.009 1.387 0.039 0.288 0.021 

191.2 0.956 0.085 0.006 0.052 0.008 1.422 0.040 0.302 0.024 

191.2 0.955 0.089 0.006 0.054 0.008 1.466 0.040 0.296 0.023 

191.3 0.955 0.093 0.007 0.058 0.009 1.449 0.042 0.296 0.021 

191.2 0.955 0.090 0.007 0.054 0.009 1.413 0.042 0.297 0.022 

191.2 0.955 0.085 0.007 0.053 0.009 1.388 0.045 0.296 0.020 

191.2 0.955 0.093 0.006 0.053 0.008 1.409 0.041 0.292 0.021 

191.2 0.955 0.099 0.006 0.058 0.008 1.427 0.043 0.293 0.022 

191.2 0.955 0.092 0.007 0.055 0.009 1.475 0.045 0.295 0.020 

191.2 0.955 0.093 0.007 0.054 0.009 1.494 0.042 0.302 0.021 

191.2 0.955 0.087 0.006 0.055 0.008 1.467 0.042 0.304 0.021 

191.2 0.955 0.099 0.007 0.059 0.007 1.430 0.041 0.296 0.021 

191.3 0.955 0.097 0.006 0.055 0.009 1.489 0.038 0.295 0.022 

191.3 0.955 0.085 0.006 0.057 0.009 1.477 0.042 0.297 0.024 

191.3 0.955 0.087 0.006 0.054 0.008 1.422 0.040 0.299 0.022 

191.3 0.955 0.092 0.006 0.053 0.008 1.428 0.038 0.297 0.021 

191.3 0.955 0.086 0.006 0.054 0.008 1.446 0.041 0.300 0.022 

191.3 0.955 0.092 0.006 0.052 0.008 1.468 0.041 0.300 0.021 

191.3 0.955 0.096 0.006 0.052 0.008 1.439 0.040 0.295 0.021 

191.3 0.955 0.083 0.006 0.056 0.007 1.417 0.041 0.301 0.021 

191.3 0.955 0.086 0.006 0.053 0.008 1.409 0.038 0.300 0.022 

191.3 0.955 0.090 0.007 0.054 0.009 1.433 0.042 0.302 0.023 

191.3 0.955 0.093 0.006 0.052 0.009 1.472 0.039 0.299 0.021 

191.3 0.955 0.089 0.006 0.052 0.009 1.498 0.041 0.296 0.020 

191.3 0.955 0.092 0.006 0.050 0.008 1.498 0.040 0.300 0.020 

191.3 0.955 0.089 0.006 0.052 0.009 1.514 0.041 0.298 0.023 

191.3 0.955 0.084 0.006 0.054 0.009 1.543 0.043 0.289 0.021 

191.3 0.955 0.090 0.007 0.057 0.008 1.538 0.043 0.296 0.022 

191.3 0.955 0.088 0.006 0.053 0.009 1.515 0.042 0.297 0.022 

191.3 0.955 0.085 0.006 0.057 0.008 1.471 0.042 0.297 0.022 

191.3 0.955 0.087 0.006 0.054 0.008 1.343 0.041 0.296 0.021 

191.3 0.955 0.086 0.006 0.056 0.009 1.239 0.042 0.304 0.022 

191.3 0.955 0.082 0.007 0.056 0.009 1.263 0.042 0.304 0.022 

191.3 0.955 0.088 0.006 0.056 0.009 1.350 0.045 0.303 0.022 

191.3 0.955 0.078 0.006 0.056 0.008 1.544 0.044 0.301 0.024 

191.3 0.955 0.085 0.006 0.056 0.009 1.672 0.044 0.310 0.022 

191.3 0.955 0.079 0.007 0.058 0.008 1.599 0.043 0.300 0.022 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethyle

AGRIUM_WA_RUN 2_000064.LAB 3/31/2010 15:22:12 322.283 23.596 13.492 0.153 -0.008 9.474 0.064 -0.13

AGRIUM_WA_RUN 2_000065.LAB 3/31/2010 15:22:42 320.840 23.933 13.288 0.204 -0.007 9.436 0.055 -0.11

AGRIUM_WA_RUN 2_000066.LAB 3/31/2010 15:23:12 319.757 23.978 13.332 0.175 -0.008 9.257 0.064 -0.22

AGRIUM_WA_RUN 2_000067.LAB 3/31/2010 15:23:42 321.549 23.879 13.351 0.209 -0.008 9.041 0.066 -0.13

AGRIUM_WA_RUN 2_000068.LAB 3/31/2010 15:24:12 323.773 23.807 13.403 0.136 -0.008 9.122 0.059 -0.14

AGRIUM_WA_RUN 2_000069.LAB 3/31/2010 15:24:42 325.115 23.744 13.427 0.108 -0.008 9.307 0.056 -0.09

AGRIUM_WA_RUN 2_000070.LAB 3/31/2010 15:25:12 326.561 23.891 13.417 0.153 -0.008 9.272 0.061 -0.06

AGRIUM_WA_RUN 2_000071.LAB 3/31/2010 15:25:41 327.715 23.879 13.423 0.140 -0.008 9.417 0.058 -0.06

AGRIUM_WA_RUN 2_000072.LAB 3/31/2010 15:26:12 327.466 23.813 13.415 0.150 -0.008 9.282 0.062 -0.09

AGRIUM_WA_RUN 2_000073.LAB 3/31/2010 15:26:41 327.803 23.940 13.457 0.148 -0.008 9.503 0.063 -0.07

AGRIUM_WA_RUN 2_000074.LAB 3/31/2010 15:27:11 326.895 23.999 13.429 0.158 -0.007 9.444 0.057 -0.09

AGRIUM_WA_RUN 2_000075.LAB 3/31/2010 15:27:41 321.867 23.982 13.399 0.176 -0.008 9.544 0.059 -0.08

AGRIUM_WA_RUN 2_000076.LAB 3/31/2010 15:28:11 321.700 23.953 13.422 0.151 -0.007 9.684 0.058 -0.09

AGRIUM_WA_RUN 2_000077.LAB 3/31/2010 15:28:41 329.974 23.970 13.450 0.178 -0.008 9.309 0.061 -0.14

AGRIUM_WA_RUN 2_000078.LAB 3/31/2010 15:29:11 342.790 23.762 13.448 0.135 -0.008 8.945 0.062 -0.11

AGRIUM_WA_RUN 2_000079.LAB 3/31/2010 15:29:41 343.504 23.839 13.504 0.137 -0.008 9.230 0.061 -0.07

AGRIUM_WA_RUN 2_000080.LAB 3/31/2010 15:30:11 333.486 23.955 13.475 0.149 -0.009 9.105 0.057 -0.06

AGRIUM_WA_RUN 2_000081.LAB 3/31/2010 15:30:41 323.816 24.022 13.375 0.184 -0.007 9.220 0.056 -0.10

AGRIUM_WA_RUN 2_000082.LAB 3/31/2010 15:31:10 317.082 24.134 13.333 0.179 -0.008 9.197 0.055 -0.10

AGRIUM_WA_RUN 2_000083.LAB 3/31/2010 15:31:40 316.216 24.211 13.410 0.147 -0.010 9.321 0.058 -0.12

AGRIUM_WA_RUN 2_000084.LAB 3/31/2010 15:32:10 316.102 24.185 13.349 0.172 -0.009 9.310 0.064 -0.13

AGRIUM_WA_RUN 2_000085.LAB 3/31/2010 15:32:40 315.861 24.118 13.336 0.147 -0.010 9.274 0.067 -0.10

AGRIUM_WA_RUN 2_000086.LAB 3/31/2010 15:33:10 315.864 24.218 13.364 0.155 -0.010 9.174 0.065 -0.09

AGRIUM_WA_RUN 2_000087.LAB 3/31/2010 15:33:40 328.758 23.970 13.350 0.149 -0.010 9.155 0.059 -0.09

AGRIUM_WA_RUN 2_000088.LAB 3/31/2010 15:34:10 346.392 23.761 13.434 0.140 -0.011 9.453 0.052 -0.11

AGRIUM_WA_RUN 2_000089.LAB 3/31/2010 15:34:40 339.011 23.862 13.489 0.132 -0.011 9.439 0.063 -0.17

AGRIUM_WA_RUN 2_000090.LAB 3/31/2010 15:35:10 330.776 23.871 13.456 0.129 -0.010 9.274 0.068 -0.05

AGRIUM_WA_RUN 2_000091.LAB 3/31/2010 15:35:40 330.772 23.916 13.509 0.148 -0.011 9.172 0.060 -0.09

AGRIUM_WA_RUN 2_000092.LAB 3/31/2010 15:36:10 327.485 23.952 13.596 0.106 -0.010 9.130 0.064 -0.08

AGRIUM_WA_RUN 2_000093.LAB 3/31/2010 15:36:39 321.704 24.107 13.542 0.142 -0.011 9.132 0.059 -0.06

AGRIUM_WA_RUN 2_000094.LAB 3/31/2010 15:37:09 316.204 24.166 13.610 0.145 -0.012 9.196 0.062 -0.07

AGRIUM_WA_RUN 2_000095.LAB 3/31/2010 15:37:39 315.811 24.080 13.553 0.142 -0.011 9.234 0.063 -0.14

AGRIUM_WA_RUN 2_000096.LAB 3/31/2010 15:38:09 317.827 24.066 13.595 0.113 -0.010 9.241 0.063 -0.09

AGRIUM_WA_RUN 2_000097.LAB 3/31/2010 15:38:39 319.799 24.125 13.564 0.125 -0.013 9.204 0.059 -0.05

AGRIUM_WA_RUN 2_000098.LAB 3/31/2010 15:39:09 323.932 24.207 13.566 0.091 -0.012 9.123 0.066 -0.07

AGRIUM_WA_RUN 2_000099.LAB 3/31/2010 15:39:39 325.733 24.164 13.614 0.065 -0.012 9.073 0.061 -0.08

AGRIUM_WA_RUN 2_000100.LAB 3/31/2010 15:40:09 326.733 24.081 13.652 0.084 -0.012 9.413 0.065 -0.01

AGRIUM_WA_RUN 2_000101.LAB 3/31/2010 15:40:39 327.368 23.958 13.602 0.106 -0.013 9.126 0.069 -0.12

AGRIUM_WA_RUN 2_000102.LAB 3/31/2010 15:41:09 326.709 24.033 13.602 0.093 -0.013 9.189 0.063 -0.05

AGRIUM_WA_RUN 2_000103.LAB 3/31/2010 15:41:39 325.132 24.048 13.566 0.113 -0.014 9.334 0.066 -0.05

AGRIUM_WA_RUN 2_000104.LAB 3/31/2010 15:42:08 325.940 24.069 13.561 0.090 -0.013 9.335 0.064 -0.06

AGRIUM_WA_RUN 2_000105.LAB 3/31/2010 15:42:38 326.196 24.069 13.537 0.116 -0.014 9.212 0.061 -0.02

AGRIUM_WA_RUN 2_000106.LAB 3/31/2010 15:43:08 325.428 24.120 13.514 0.102 -0.015 9.177 0.065 -0.01

325.482 23.987 13.470
Date Time

3/31/2010 15:22:12

3/31/2010 15:22:42

3/31/2010 15:23:12

3/31/2010 15:23:42

3/31/2010 15:24:12

3/31/2010 15:24:42

3/31/2010 15:25:12

3/31/2010 15:25:41

3/31/2010 15:26:12

3/31/2010 15:26:41

3/31/2010 15:27:11

3/31/2010 15:27:41

3/31/2010 15:28:11

3/31/2010 15:28:41

3/31/2010 15:29:11

3/31/2010 15:29:41

3/31/2010 15:30:11

3/31/2010 15:30:41

3/31/2010 15:31:10

3/31/2010 15:31:40

3/31/2010 15:32:10

3/31/2010 15:32:40

3/31/2010 15:33:10

3/31/2010 15:33:40

3/31/2010 15:34:10

3/31/2010 15:34:40

3/31/2010 15:35:10

3/31/2010 15:35:40

3/31/2010 15:36:10

3/31/2010 15:36:39

3/31/2010 15:37:09

3/31/2010 15:37:39

3/31/2010 15:38:09

3/31/2010 15:38:39

3/31/2010 15:39:09

3/31/2010 15:39:39

3/31/2010 15:40:09

3/31/2010 15:40:39

3/31/2010 15:41:09

3/31/2010 15:41:39

3/31/2010 15:42:08

3/31/2010 15:42:38

3/31/2010 15:43:08

Temp (C) Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF

191.3 0.955 0.084 0.006 0.057 0.009 1.413 0.042 0.251 0.023 

191.3 0.955 0.080 0.007 0.051 0.008 1.422 0.039 0.267 0.022 

191.3 0.955 0.086 0.006 0.056 0.008 1.415 0.040 0.273 0.023 

191.3 0.955 0.085 0.007 0.055 0.009 1.440 0.040 0.282 0.022 

191.3 0.955 0.100 0.007 0.055 0.009 1.466 0.043 0.271 0.023 

191.3 0.955 0.088 0.006 0.057 0.009 1.476 0.039 0.271 0.023 

191.3 0.955 0.091 0.006 0.052 0.009 1.486 0.039 0.272 0.024 

191.3 0.955 0.084 0.006 0.052 0.009 1.510 0.042 0.277 0.023 

191.3 0.955 0.090 0.006 0.054 0.009 1.487 0.040 0.280 0.024 

191.3 0.955 0.080 0.006 0.054 0.009 1.498 0.041 0.279 0.024 

191.2 0.955 0.077 0.007 0.052 0.009 1.490 0.041 0.286 0.022 

191.3 0.955 0.077 0.006 0.058 0.009 1.407 0.042 0.284 0.023 

191.2 0.955 0.081 0.007 0.055 0.009 1.402 0.042 0.282 0.022 

191.3 0.955 0.086 0.006 0.054 0.009 1.569 0.041 0.290 0.022 

191.3 0.955 0.093 0.006 0.062 0.010 1.757 0.043 0.288 0.023 

191.2 0.955 0.086 0.007 0.053 0.010 1.766 0.042 0.293 0.023 

191.3 0.955 0.095 0.006 0.057 0.009 1.617 0.041 0.288 0.022 

191.3 0.955 0.087 0.007 0.055 0.009 1.453 0.040 0.294 0.023 

191.3 0.955 0.086 0.006 0.057 0.009 1.375 0.040 0.301 0.022 

191.4 0.955 0.080 0.006 0.059 0.008 1.337 0.043 0.295 0.023 

191.4 0.955 0.088 0.006 0.055 0.008 1.349 0.043 0.298 0.024 

191.4 0.955 0.090 0.007 0.056 0.010 1.361 0.045 0.296 0.022 

191.4 0.955 0.096 0.006 0.061 0.010 1.353 0.048 0.301 0.025 

191.4 0.955 0.093 0.007 0.056 0.009 1.541 0.042 0.296 0.022 

191.3 0.955 0.080 0.007 0.061 0.009 1.790 0.042 0.291 0.025 

191.3 0.955 0.084 0.006 0.057 0.009 1.684 0.044 0.291 0.023 

191.3 0.955 0.092 0.007 0.060 0.010 1.563 0.044 0.302 0.021 

191.3 0.955 0.090 0.007 0.063 0.009 1.563 0.045 0.309 0.024 

191.3 0.955 0.091 0.007 0.057 0.010 1.511 0.045 0.301 0.025 

191.3 0.955 0.089 0.006 0.064 0.010 1.429 0.045 0.301 0.022 

191.3 0.955 0.096 0.007 0.068 0.009 1.348 0.049 0.301 0.022 

191.3 0.955 0.093 0.007 0.062 0.009 1.341 0.049 0.299 0.022 

191.3 0.955 0.096 0.006 0.059 0.010 1.368 0.045 0.298 0.024 

191.3 0.955 0.086 0.007 0.062 0.010 1.402 0.046 0.298 0.024 

191.3 0.955 0.098 0.007 0.060 0.009 1.460 0.049 0.303 0.023 

191.3 0.955 0.096 0.007 0.065 0.010 1.473 0.048 0.301 0.024 

191.3 0.955 0.093 0.006 0.062 0.010 1.494 0.048 0.300 0.024 

191.3 0.955 0.096 0.007 0.070 0.010 1.504 0.049 0.302 0.025 

191.3 0.955 0.095 0.007 0.065 0.011 1.494 0.048 0.301 0.024 

191.3 0.955 0.094 0.007 0.064 0.010 1.461 0.049 0.301 0.026 

191.3 0.955 0.089 0.007 0.060 0.010 1.478 0.049 0.299 0.023 

191.3 0.955 0.093 0.007 0.065 0.010 1.478 0.050 0.297 0.025 

191.3 0.955 0.092 0.007 0.066 0.010 1.464 0.049 0.301 0.023 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethyle

AGRIUM_WA_RUN 2_000128.LAB 3/31/2010 15:54:06 328.042 23.502 13.838 0.166 -0.008 9.782 0.062 -0.12

AGRIUM_WA_RUN 2_000129.LAB 3/31/2010 15:54:36 325.438 23.680 13.698 0.211 -0.007 9.499 0.068 -0.14

AGRIUM_WA_RUN 2_000130.LAB 3/31/2010 15:55:06 323.869 23.671 13.655 0.223 -0.008 9.480 0.063 -0.17

AGRIUM_WA_RUN 2_000131.LAB 3/31/2010 15:55:36 324.776 23.703 13.744 0.192 -0.009 9.427 0.070 -0.17

AGRIUM_WA_RUN 2_000132.LAB 3/31/2010 15:56:06 323.401 23.710 13.674 0.170 -0.009 9.484 0.064 -0.15

AGRIUM_WA_RUN 2_000133.LAB 3/31/2010 15:56:36 321.862 23.729 13.717 0.180 -0.009 9.544 0.067 -0.04

AGRIUM_WA_RUN 2_000134.LAB 3/31/2010 15:57:06 322.415 23.842 13.759 0.187 -0.009 9.326 0.065 -0.11

AGRIUM_WA_RUN 2_000135.LAB 3/31/2010 15:57:36 323.318 23.692 13.796 0.195 -0.008 9.656 0.070 -0.08

AGRIUM_WA_RUN 2_000136.LAB 3/31/2010 15:58:06 321.561 23.538 13.581 0.168 -0.009 9.405 0.071 -0.16

AGRIUM_WA_RUN 2_000137.LAB 3/31/2010 15:58:35 323.670 23.641 13.657 0.160 -0.010 9.546 0.069 -0.10

AGRIUM_WA_RUN 2_000138.LAB 3/31/2010 15:59:05 323.536 23.651 13.470 0.150 -0.009 9.606 0.062 -0.18

AGRIUM_WA_RUN 2_000139.LAB 3/31/2010 15:59:36 319.828 23.681 13.471 0.175 -0.010 9.739 0.061 -0.18

AGRIUM_WA_RUN 2_000140.LAB 3/31/2010 16:00:05 317.092 23.796 13.532 0.152 -0.009 9.916 0.067 -0.13

AGRIUM_WA_RUN 2_000141.LAB 3/31/2010 16:00:35 318.128 23.824 13.506 0.145 -0.009 9.666 0.065 -0.17

AGRIUM_WA_RUN 2_000142.LAB 3/31/2010 16:01:05 319.874 23.756 13.482 0.148 -0.009 9.624 0.064 -0.14

AGRIUM_WA_RUN 2_000143.LAB 3/31/2010 16:01:35 320.135 23.780 13.522 0.134 -0.009 9.607 0.064 -0.11

AGRIUM_WA_RUN 2_000144.LAB 3/31/2010 16:02:05 315.789 23.851 13.490 0.150 -0.009 9.684 0.067 -0.02

AGRIUM_WA_RUN 2_000145.LAB 3/31/2010 16:02:35 310.053 24.022 13.428 0.168 -0.009 9.435 0.062 -0.13

AGRIUM_WA_RUN 2_000146.LAB 3/31/2010 16:03:05 312.205 23.866 13.427 0.162 -0.009 9.635 0.066 -0.07

AGRIUM_WA_RUN 2_000147.LAB 3/31/2010 16:03:35 321.878 23.839 13.363 0.177 -0.009 9.873 0.068 -0.16

AGRIUM_WA_RUN 2_000148.LAB 3/31/2010 16:04:04 337.002 23.670 13.371 0.208 -0.010 9.627 0.064 -0.16

AGRIUM_WA_RUN 2_000149.LAB 3/31/2010 16:04:34 345.539 23.510 13.446 0.207 -0.011 9.563 0.067 -0.06

AGRIUM_WA_RUN 2_000150.LAB 3/31/2010 16:05:04 342.516 23.473 13.462 0.198 -0.011 9.374 0.064 -0.05

AGRIUM_WA_RUN 2_000151.LAB 3/31/2010 16:05:34 335.346 23.640 13.465 0.175 -0.010 9.571 0.069 -0.15

AGRIUM_WA_RUN 2_000152.LAB 3/31/2010 16:06:04 328.751 23.658 13.447 0.204 -0.009 9.587 0.058 -0.09

AGRIUM_WA_RUN 2_000153.LAB 3/31/2010 16:06:34 323.373 23.794 13.451 0.171 -0.010 9.638 0.059 -0.10

AGRIUM_WA_RUN 2_000154.LAB 3/31/2010 16:07:04 319.918 23.777 13.441 0.170 -0.011 9.879 0.057 -0.20

AGRIUM_WA_RUN 2_000155.LAB 3/31/2010 16:07:34 319.460 23.851 13.365 0.176 -0.009 9.833 0.056 -0.13

AGRIUM_WA_RUN 2_000156.LAB 3/31/2010 16:08:04 320.134 23.887 13.422 0.183 -0.011 9.801 0.059 -0.19

AGRIUM_WA_RUN 2_000157.LAB 3/31/2010 16:08:34 321.974 23.848 13.420 0.152 -0.012 9.754 0.066 -0.17

AGRIUM_WA_RUN 2_000158.LAB 3/31/2010 16:09:04 324.004 23.789 13.508 0.108 -0.011 9.683 0.066 -0.08

AGRIUM_WA_RUN 2_000159.LAB 3/31/2010 16:09:33 322.541 23.746 13.520 0.145 -0.012 9.790 0.067 -0.10

AGRIUM_WA_RUN 2_000160.LAB 3/31/2010 16:10:03 319.978 23.820 13.575 0.137 -0.011 9.590 0.068 -0.13

AGRIUM_WA_RUN 2_000161.LAB 3/31/2010 16:10:33 319.193 23.836 13.603 0.174 -0.012 9.522 0.065 -0.12

AGRIUM_WA_RUN 2_000162.LAB 3/31/2010 16:11:03 319.348 23.675 13.525 0.147 -0.012 9.593 0.061 -0.10

AGRIUM_WA_RUN 2_000163.LAB 3/31/2010 16:11:33 320.682 23.777 13.473 0.142 -0.012 9.899 0.069 -0.10

AGRIUM_WA_RUN 2_000164.LAB 3/31/2010 16:12:03 322.868 23.890 13.441 0.158 -0.012 9.866 0.062 -0.03

AGRIUM_WA_RUN 2_000165.LAB 3/31/2010 16:12:33 323.628 23.832 13.412 0.148 -0.012 9.886 0.066 -0.07

AGRIUM_WA_RUN 2_000166.LAB 3/31/2010 16:13:03 322.722 23.952 13.479 0.148 -0.013 9.872 0.058 -0.13

AGRIUM_WA_RUN 2_000167.LAB 3/31/2010 16:13:33 323.387 23.829 13.444 0.116 -0.013 9.690 0.069 -0.15

AGRIUM_WA_RUN 2_000168.LAB 3/31/2010 16:14:03 326.434 23.819 13.451 0.138 -0.012 9.837 0.060 -0.16

AGRIUM_WA_RUN 2_000169.LAB 3/31/2010 16:14:33 327.676 23.864 13.556 0.091 -0.014 9.462 0.063 -0.11

AGRIUM_WA_RUN 2_000170.LAB 3/31/2010 16:15:02 325.540 23.854 13.499 0.083 -0.015 9.413 0.063 -0.09

323.462 23.757 13.525
Date Time

3/31/2010 15:54:06

3/31/2010 15:54:36

3/31/2010 15:55:06

3/31/2010 15:55:36

3/31/2010 15:56:06

3/31/2010 15:56:36

3/31/2010 15:57:06

3/31/2010 15:57:36

3/31/2010 15:58:06

3/31/2010 15:58:35

3/31/2010 15:59:05

3/31/2010 15:59:36

3/31/2010 16:00:05

3/31/2010 16:00:35

3/31/2010 16:01:05

3/31/2010 16:01:35

3/31/2010 16:02:05

3/31/2010 16:02:35

3/31/2010 16:03:05

3/31/2010 16:03:35

3/31/2010 16:04:04

3/31/2010 16:04:34

3/31/2010 16:05:04

3/31/2010 16:05:34

3/31/2010 16:06:04

3/31/2010 16:06:34

3/31/2010 16:07:04

3/31/2010 16:07:34

3/31/2010 16:08:04

3/31/2010 16:08:34

3/31/2010 16:09:04

3/31/2010 16:09:33

3/31/2010 16:10:03

3/31/2010 16:10:33

3/31/2010 16:11:03

3/31/2010 16:11:33

3/31/2010 16:12:03

3/31/2010 16:12:33

3/31/2010 16:13:03

3/31/2010 16:13:33

3/31/2010 16:14:03

3/31/2010 16:14:33

3/31/2010 16:15:02

Temp (C) Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF

191.3 0.955 0.089 0.007 0.063 0.011 1.519 0.046 0.257 0.026 

191.3 0.955 0.103 0.008 0.065 0.011 1.518 0.047 0.279 0.025 

191.3 0.955 0.099 0.007 0.068 0.011 1.475 0.048 0.283 0.026 

191.2 0.955 0.098 0.007 0.068 0.011 1.491 0.049 0.269 0.025 

191.2 0.955 0.107 0.007 0.066 0.011 1.450 0.049 0.275 0.025 

191.3 0.955 0.104 0.007 0.070 0.012 1.419 0.051 0.284 0.026 

191.2 0.955 0.098 0.007 0.068 0.010 1.419 0.049 0.280 0.027 

191.3 0.955 0.102 0.007 0.065 0.012 1.446 0.047 0.282 0.026 

191.3 0.954 0.104 0.008 0.068 0.010 1.437 0.049 0.280 0.024 

191.3 0.954 0.091 0.007 0.066 0.011 1.435 0.047 0.287 0.028 

191.2 0.954 0.089 0.007 0.061 0.011 1.445 0.047 0.282 0.026 

191.2 0.954 0.088 0.007 0.061 0.010 1.392 0.047 0.283 0.026 

191.3 0.954 0.089 0.007 0.066 0.011 1.350 0.044 0.287 0.028 

191.3 0.954 0.094 0.006 0.066 0.011 1.358 0.047 0.288 0.028 

191.3 0.954 0.093 0.007 0.069 0.011 1.381 0.048 0.286 0.027 

191.3 0.954 0.091 0.007 0.066 0.011 1.383 0.048 0.288 0.028 

191.3 0.954 0.097 0.007 0.069 0.011 1.320 0.050 0.288 0.027 

191.3 0.954 0.106 0.008 0.067 0.011 1.254 0.050 0.289 0.028 

191.3 0.954 0.089 0.007 0.069 0.011 1.285 0.051 0.287 0.027 

191.3 0.954 0.094 0.007 0.067 0.010 1.426 0.049 0.283 0.028 

191.3 0.954 0.102 0.007 0.071 0.011 1.676 0.049 0.294 0.027 

191.3 0.954 0.096 0.007 0.071 0.011 1.811 0.050 0.292 0.026 

191.3 0.954 0.107 0.007 0.068 0.011 1.756 0.051 0.286 0.027 

191.3 0.954 0.098 0.008 0.069 0.011 1.665 0.053 0.297 0.025 

191.3 0.954 0.103 0.008 0.071 0.011 1.557 0.054 0.299 0.026 

191.3 0.954 0.090 0.008 0.066 0.011 1.462 0.050 0.298 0.027 

191.3 0.954 0.087 0.007 0.068 0.011 1.391 0.050 0.293 0.028 

191.3 0.954 0.098 0.007 0.068 0.011 1.387 0.051 0.293 0.028 

191.3 0.954 0.092 0.007 0.071 0.012 1.404 0.049 0.298 0.028 

191.3 0.954 0.095 0.008 0.072 0.011 1.426 0.054 0.286 0.029 

191.3 0.954 0.086 0.007 0.068 0.012 1.460 0.052 0.293 0.027 

191.3 0.954 0.094 0.007 0.067 0.012 1.423 0.053 0.288 0.028 

191.3 0.954 0.085 0.007 0.072 0.012 1.396 0.054 0.288 0.027 

191.3 0.954 0.099 0.008 0.072 0.012 1.365 0.052 0.289 0.028 

191.3 0.954 0.094 0.007 0.074 0.011 1.393 0.054 0.287 0.029 

191.3 0.954 0.088 0.008 0.072 0.011 1.418 0.053 0.296 0.028 

191.3 0.954 0.097 0.008 0.073 0.012 1.441 0.053 0.287 0.027 

191.3 0.954 0.092 0.008 0.071 0.012 1.454 0.054 0.287 0.027 

191.3 0.954 0.095 0.008 0.072 0.013 1.427 0.053 0.288 0.030 

191.2 0.954 0.082 0.007 0.073 0.012 1.445 0.056 0.287 0.028 

191.2 0.954 0.089 0.008 0.074 0.012 1.492 0.055 0.291 0.029 

191.3 0.954 0.087 0.007 0.071 0.011 1.502 0.055 0.281 0.028 

191.3 0.954 0.092 0.007 0.074 0.012 1.483 0.054 0.282 0.029 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene 

AGRIUM_WA_RUN 3_000013.LAB 3/31/2010 16:43:14 311.255 24.183 12.597 0.133 -0.005 9.321 0.054 0.074 

AGRIUM_WA_RUN 3_000014.LAB 3/31/2010 16:43:44 322.894 24.024 12.793 0.125 -0.005 9.219 0.059 0.030 

AGRIUM_WA_RUN 3_000015.LAB 3/31/2010 16:44:14 331.390 23.759 12.770 0.131 -0.005 9.422 0.054 0.099 

AGRIUM_WA_RUN 3_000016.LAB 3/31/2010 16:44:44 333.236 23.758 12.827 0.114 -0.005 9.446 0.051 0.006 

AGRIUM_WA_RUN 3_000017.LAB 3/31/2010 16:45:13 329.006 23.795 12.878 0.108 -0.006 9.234 0.057 0.042 

AGRIUM_WA_RUN 3_000018.LAB 3/31/2010 16:45:43 321.467 23.875 12.899 0.155 -0.006 9.253 0.051 0.065 

AGRIUM_WA_RUN 3_000019.LAB 3/31/2010 16:46:13 317.222 23.916 12.901 0.195 -0.005 9.536 0.063 0.080 

AGRIUM_WA_RUN 3_000020.LAB 3/31/2010 16:46:43 316.905 23.855 12.912 0.187 -0.007 9.286 0.059 0.069 

AGRIUM_WA_RUN 3_000021.LAB 3/31/2010 16:47:13 315.241 23.905 12.916 0.179 -0.006 9.299 0.056 0.086 

AGRIUM_WA_RUN 3_000022.LAB 3/31/2010 16:47:43 310.827 23.991 12.975 0.169 -0.007 9.277 0.045 0.010 

AGRIUM_WA_RUN 3_000023.LAB 3/31/2010 16:48:13 307.006 23.955 12.932 0.207 -0.007 9.573 0.046 0.041 

AGRIUM_WA_RUN 3_000024.LAB 3/31/2010 16:48:43 307.698 24.016 12.933 0.213 -0.007 9.566 0.052 0.081 

AGRIUM_WA_RUN 3_000025.LAB 3/31/2010 16:49:13 311.631 23.894 12.907 0.216 -0.005 9.490 0.054 -0.019 

AGRIUM_WA_RUN 3_000026.LAB 3/31/2010 16:49:43 313.907 23.867 12.919 0.234 -0.006 9.289 0.051 0.021 

AGRIUM_WA_RUN 3_000027.LAB 3/31/2010 16:50:13 315.209 23.856 12.886 0.216 -0.007 9.302 0.059 0.026 

AGRIUM_WA_RUN 3_000028.LAB 3/31/2010 16:50:42 319.936 23.891 13.065 0.260 -0.007 9.425 0.054 0.110 

AGRIUM_WA_RUN 3_000029.LAB 3/31/2010 16:51:12 321.015 23.876 13.001 0.222 -0.008 9.541 0.055 0.036 

AGRIUM_WA_RUN 3_000030.LAB 3/31/2010 16:51:42 316.889 23.880 12.903 0.186 -0.008 9.587 0.051 -0.017 

AGRIUM_WA_RUN 3_000031.LAB 3/31/2010 16:52:12 314.369 23.899 12.999 0.240 -0.007 9.596 0.058 0.042 

AGRIUM_WA_RUN 3_000032.LAB 3/31/2010 16:52:42 315.318 23.784 13.104 0.193 -0.008 9.548 0.052 0.026 

AGRIUM_WA_RUN 3_000033.LAB 3/31/2010 16:53:12 317.505 23.796 13.061 0.221 -0.007 9.729 0.049 0.089 

AGRIUM_WA_RUN 3_000034.LAB 3/31/2010 16:53:42 318.987 23.774 13.065 0.251 -0.007 9.481 0.061 0.015 

AGRIUM_WA_RUN 3_000035.LAB 3/31/2010 16:54:12 322.346 23.714 13.024 0.220 -0.007 9.617 0.056 0.149 

AGRIUM_WA_RUN 3_000036.LAB 3/31/2010 16:54:42 322.507 23.716 13.050 0.210 -0.007 9.490 0.052 0.044 

AGRIUM_WA_RUN 3_000037.LAB 3/31/2010 16:55:12 319.411 23.737 12.993 0.207 -0.008 9.493 0.059 0.007 

AGRIUM_WA_RUN 3_000038.LAB 3/31/2010 16:55:42 315.822 23.860 13.030 0.187 -0.008 9.489 0.051 0.085 

AGRIUM_WA_RUN 3_000039.LAB 3/31/2010 16:56:11 316.176 23.815 13.078 0.201 -0.008 9.545 0.054 0.072 

AGRIUM_WA_RUN 3_000040.LAB 3/31/2010 16:56:41 316.864 23.834 13.031 0.230 -0.007 9.676 0.048 0.080 

AGRIUM_WA_RUN 3_000041.LAB 3/31/2010 16:57:11 318.350 23.794 13.090 0.210 -0.010 9.681 0.053 0.150 

AGRIUM_WA_RUN 3_000042.LAB 3/31/2010 16:57:41 318.104 23.695 13.096 0.216 -0.009 9.514 0.057 0.086 

AGRIUM_WA_RUN 3_000043.LAB 3/31/2010 16:58:11 318.172 23.645 13.094 0.227 -0.010 9.395 0.057 0.110 

AGRIUM_WA_RUN 3_000044.LAB 3/31/2010 16:58:41 321.554 23.594 13.102 0.193 -0.011 9.569 0.053 0.112 

AGRIUM_WA_RUN 3_000045.LAB 3/31/2010 16:59:11 325.330 23.635 13.104 0.165 -0.011 9.388 0.059 0.126 

AGRIUM_WA_RUN 3_000046.LAB 3/31/2010 16:59:41 324.735 23.658 13.185 0.183 -0.010 9.407 0.054 0.042 

AGRIUM_WA_RUN 3_000047.LAB 3/31/2010 17:00:11 320.947 23.700 13.122 0.218 -0.010 9.498 0.058 0.143 

AGRIUM_WA_RUN 3_000048.LAB 3/31/2010 17:00:41 319.379 23.585 13.118 0.178 -0.011 9.460 0.050 0.096 

AGRIUM_WA_RUN 3_000049.LAB 3/31/2010 17:01:11 319.210 23.749 13.107 0.196 -0.009 9.444 0.054 0.101 

AGRIUM_WA_RUN 3_000050.LAB 3/31/2010 17:01:40 320.077 23.629 13.093 0.217 -0.009 9.523 0.059 0.126 

AGRIUM_WA_RUN 3_000051.LAB 3/31/2010 17:02:10 320.208 23.558 13.068 0.158 -0.011 9.487 0.050 0.083 

AGRIUM_WA_RUN 3_000052.LAB 3/31/2010 17:02:40 321.297 23.553 13.109 0.156 -0.012 9.506 0.053 0.162 

AGRIUM_WA_RUN 3_000053.LAB 3/31/2010 17:03:10 324.262 23.600 13.177 0.150 -0.012 9.291 0.053 0.094 

AGRIUM_WA_RUN 3_000054.LAB 3/31/2010 17:03:40 326.088 23.532 13.171 0.139 -0.011 9.390 0.059 0.118 

AGRIUM_WA_RUN 3_000055.LAB 3/31/2010 17:04:10 322.752 23.650 13.200 0.153 -0.010 9.532 0.061 0.153 

319.128 23.786 13.007
Date Time

3/31/2010 16:43:14

3/31/2010 16:43:44

3/31/2010 16:44:14

3/31/2010 16:44:44

3/31/2010 16:45:13

3/31/2010 16:45:43

3/31/2010 16:46:13

3/31/2010 16:46:43

3/31/2010 16:47:13

3/31/2010 16:47:43

3/31/2010 16:48:13

3/31/2010 16:48:43

3/31/2010 16:49:13

3/31/2010 16:49:43

3/31/2010 16:50:13

3/31/2010 16:50:42

3/31/2010 16:51:12

3/31/2010 16:51:42

3/31/2010 16:52:12

3/31/2010 16:52:42

3/31/2010 16:53:12

3/31/2010 16:53:42

3/31/2010 16:54:12

3/31/2010 16:54:42

3/31/2010 16:55:12

3/31/2010 16:55:42

3/31/2010 16:56:11

3/31/2010 16:56:41

3/31/2010 16:57:11

3/31/2010 16:57:41

3/31/2010 16:58:11

3/31/2010 16:58:41

3/31/2010 16:59:11

3/31/2010 16:59:41

3/31/2010 17:00:11

3/31/2010 17:00:41

3/31/2010 17:01:11

3/31/2010 17:01:40

3/31/2010 17:02:10

3/31/2010 17:02:40

3/31/2010 17:03:10

3/31/2010 17:03:40

3/31/2010 17:04:10

Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF6 res

0.955 0.077 0.006 0.033 0.004 1.302 0.024 0.340 0.017 0.00

0.955 0.069 0.006 0.040 0.004 1.480 0.025 0.338 0.015 0.00

0.955 0.066 0.005 0.035 0.005 1.615 0.026 0.330 0.018 0.00

0.955 0.070 0.005 0.035 0.005 1.619 0.024 0.318 0.018 0.00

0.955 0.069 0.005 0.034 0.004 1.567 0.025 0.321 0.016 0.00

0.955 0.076 0.006 0.033 0.004 1.461 0.023 0.317 0.015 0.00

0.955 0.079 0.006 0.039 0.004 1.400 0.027 0.315 0.016 0.00

0.955 0.080 0.006 0.037 0.005 1.389 0.027 0.313 0.016 0.00

0.955 0.081 0.006 0.037 0.004 1.362 0.025 0.318 0.016 0.00

0.955 0.088 0.006 0.044 0.005 1.329 0.029 0.322 0.016 0.002 

0.955 0.078 0.006 0.039 0.004 1.256 0.027 0.323 0.017 0.002 

0.955 0.076 0.006 0.041 0.005 1.255 0.028 0.322 0.017 0.002 

0.955 0.072 0.006 0.043 0.005 1.340 0.027 0.321 0.017 0.002 

0.955 0.080 0.006 0.041 0.006 1.372 0.029 0.324 0.017 0.002 

0.955 0.088 0.006 0.043 0.006 1.393 0.027 0.327 0.015 0.002 

0.955 0.083 0.006 0.040 0.004 1.439 0.028 0.312 0.016 0.002 

0.955 0.071 0.005 0.042 0.005 1.456 0.029 0.314 0.015 0.002 

0.955 0.083 0.006 0.040 0.005 1.409 0.026 0.329 0.016 0.00

0.955 0.078 0.006 0.045 0.005 1.368 0.029 0.318 0.016 0.002 

0.955 0.084 0.006 0.046 0.005 1.392 0.029 0.318 0.017 0.002 

0.955 0.076 0.007 0.043 0.005 1.400 0.029 0.323 0.015 0.002 

0.955 0.072 0.006 0.042 0.004 1.429 0.029 0.316 0.015 0.002 

0.955 0.079 0.005 0.043 0.005 1.491 0.029 0.319 0.014 0.002 

0.955 0.077 0.005 0.041 0.005 1.490 0.029 0.317 0.016 0.002 

0.954 0.081 0.005 0.040 0.005 1.427 0.030 0.319 0.016 0.002 

0.955 0.074 0.006 0.047 0.005 1.403 0.030 0.315 0.016 0.002 

0.955 0.090 0.006 0.046 0.006 1.390 0.032 0.314 0.015 0.002 

0.955 0.077 0.006 0.047 0.005 1.420 0.030 0.322 0.015 0.002 

0.955 0.076 0.005 0.046 0.005 1.415 0.030 0.309 0.016 0.002 

0.955 0.081 0.005 0.046 0.005 1.406 0.029 0.315 0.015 0.002 

0.954 0.086 0.006 0.047 0.004 1.401 0.031 0.310 0.016 0.002 

0.955 0.078 0.005 0.047 0.005 1.447 0.030 0.317 0.017 0.002 

0.955 0.080 0.005 0.045 0.005 1.519 0.031 0.316 0.016 0.002 

0.955 0.083 0.005 0.045 0.005 1.510 0.030 0.316 0.018 0.002 

0.955 0.077 0.006 0.054 0.005 1.457 0.033 0.317 0.016 0.002 

0.955 0.081 0.005 0.047 0.005 1.403 0.032 0.315 0.016 0.002 

0.955 0.079 0.005 0.048 0.004 1.412 0.031 0.321 0.016 0.002 

0.955 0.085 0.006 0.051 0.005 1.444 0.032 0.312 0.016 0.002 

0.955 0.092 0.005 0.050 0.004 1.429 0.033 0.316 0.016 0.002 

0.955 0.085 0.006 0.053 0.006 1.455 0.031 0.316 0.016 0.002 

0.955 0.081 0.005 0.050 0.005 1.503 0.034 0.313 0.017 0.002 

0.955 0.084 0.005 0.053 0.006 1.528 0.034 0.314 0.017 0.002 

0.955 0.084 0.005 0.055 0.006 1.473 0.033 0.318 0.017 0.002 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene 

AGRIUM_WA_RUN 3_000075.LAB 3/31/2010 17:14:08 321.616 23.456 12.628 0.173 -0.005 9.760 0.052 0.195 

AGRIUM_WA_RUN 3_000076.LAB 3/31/2010 17:14:38 319.972 23.418 12.649 0.185 -0.005 9.563 0.054 0.107 

AGRIUM_WA_RUN 3_000077.LAB 3/31/2010 17:15:08 318.607 23.370 12.787 0.189 -0.005 9.417 0.057 0.192 

AGRIUM_WA_RUN 3_000078.LAB 3/31/2010 17:15:38 316.607 23.344 12.883 0.155 -0.006 9.311 0.056 0.176 

AGRIUM_WA_RUN 3_000079.LAB 3/31/2010 17:16:08 316.151 23.255 12.942 0.173 -0.007 9.458 0.056 0.142 

AGRIUM_WA_RUN 3_000080.LAB 3/31/2010 17:16:38 317.446 23.319 12.934 0.166 -0.007 9.520 0.061 0.196 

AGRIUM_WA_RUN 3_000081.LAB 3/31/2010 17:17:08 317.920 23.426 12.993 0.136 -0.006 9.555 0.058 0.111 

AGRIUM_WA_RUN 3_000082.LAB 3/31/2010 17:17:38 318.430 23.454 12.983 0.142 -0.005 9.559 0.057 0.192 

AGRIUM_WA_RUN 3_000083.LAB 3/31/2010 17:18:08 318.407 23.327 12.929 0.145 -0.006 9.590 0.057 0.136 

AGRIUM_WA_RUN 3_000084.LAB 3/31/2010 17:18:37 319.566 23.428 13.018 0.137 -0.006 9.613 0.054 0.199 

AGRIUM_WA_RUN 3_000085.LAB 3/31/2010 17:19:07 320.297 23.442 12.936 0.137 -0.006 9.760 0.054 0.207 

AGRIUM_WA_RUN 3_000086.LAB 3/31/2010 17:19:37 320.433 23.439 12.965 0.144 -0.006 9.783 0.055 0.278 

AGRIUM_WA_RUN 3_000087.LAB 3/31/2010 17:20:07 317.982 23.523 12.916 0.158 -0.006 9.800 0.046 0.179 

AGRIUM_WA_RUN 3_000088.LAB 3/31/2010 17:20:37 316.248 23.693 12.838 0.165 -0.006 9.821 0.058 0.105 

AGRIUM_WA_RUN 3_000089.LAB 3/31/2010 17:21:07 316.600 23.597 12.847 0.163 -0.005 9.749 0.053 0.217 

AGRIUM_WA_RUN 3_000090.LAB 3/31/2010 17:21:37 318.390 23.572 12.870 0.175 -0.006 9.741 0.051 0.174 

AGRIUM_WA_RUN 3_000091.LAB 3/31/2010 17:22:07 320.238 23.525 12.914 0.161 -0.006 9.594 0.054 0.124 

AGRIUM_WA_RUN 3_000092.LAB 3/31/2010 17:22:37 321.434 23.444 12.871 0.181 -0.006 9.606 0.054 0.246 

AGRIUM_WA_RUN 3_000093.LAB 3/31/2010 17:23:07 321.725 23.551 12.928 0.169 -0.006 9.588 0.045 0.112 

AGRIUM_WA_RUN 3_000094.LAB 3/31/2010 17:23:37 321.762 23.462 12.925 0.149 -0.006 9.513 0.055 0.151 

AGRIUM_WA_RUN 3_000095.LAB 3/31/2010 17:24:06 323.788 23.506 12.833 0.152 -0.008 9.557 0.053 0.154 

AGRIUM_WA_RUN 3_000096.LAB 3/31/2010 17:24:36 322.968 23.456 12.864 0.138 -0.008 9.418 0.050 0.122 

AGRIUM_WA_RUN 3_000097.LAB 3/31/2010 17:25:06 321.306 23.439 12.942 0.114 -0.008 9.485 0.050 0.199 

AGRIUM_WA_RUN 3_000098.LAB 3/31/2010 17:25:36 323.510 23.494 12.942 0.148 -0.008 9.493 0.051 0.174 

AGRIUM_WA_RUN 3_000099.LAB 3/31/2010 17:26:06 325.944 23.494 12.929 0.133 -0.008 9.486 0.055 0.211 

AGRIUM_WA_RUN 3_000100.LAB 3/31/2010 17:26:36 326.316 23.715 12.985 0.117 -0.008 9.473 0.051 0.150 

AGRIUM_WA_RUN 3_000101.LAB 3/31/2010 17:27:06 324.082 23.613 13.045 0.126 -0.009 9.553 0.052 0.187 

AGRIUM_WA_RUN 3_000102.LAB 3/31/2010 17:27:36 324.890 23.513 13.089 0.143 -0.009 9.444 0.050 0.188 

AGRIUM_WA_RUN 3_000103.LAB 3/31/2010 17:28:06 326.708 23.585 13.113 0.083 -0.009 9.383 0.050 0.117 

AGRIUM_WA_RUN 3_000104.LAB 3/31/2010 17:28:36 325.707 23.735 13.159 0.123 -0.010 9.456 0.057 0.158 

AGRIUM_WA_RUN 3_000105.LAB 3/31/2010 17:29:06 316.426 23.616 13.153 0.175 -0.008 9.429 0.047 0.185 

AGRIUM_WA_RUN 3_000106.LAB 3/31/2010 17:29:36 312.673 23.819 13.146 0.159 -0.009 9.448 0.056 0.187 

AGRIUM_WA_RUN 3_000107.LAB 3/31/2010 17:30:05 320.259 23.641 13.108 0.143 -0.010 9.348 0.052 0.216 

AGRIUM_WA_RUN 3_000108.LAB 3/31/2010 17:30:35 330.507 23.467 13.166 0.088 -0.009 9.380 0.056 0.160 

AGRIUM_WA_RUN 3_000109.LAB 3/31/2010 17:31:05 332.852 23.465 13.114 0.088 -0.009 9.449 0.049 0.163 

AGRIUM_WA_RUN 3_000110.LAB 3/31/2010 17:31:35 332.617 23.513 13.151 0.113 -0.010 9.521 0.050 0.236 

AGRIUM_WA_RUN 3_000111.LAB 3/31/2010 17:32:05 331.202 23.573 13.120 0.111 -0.010 9.285 0.056 0.176 

AGRIUM_WA_RUN 3_000112.LAB 3/31/2010 17:32:35 325.806 23.520 13.186 0.094 -0.010 9.347 0.052 0.152 

AGRIUM_WA_RUN 3_000113.LAB 3/31/2010 17:33:05 319.149 23.607 13.162 0.102 -0.010 9.485 0.051 0.220 

AGRIUM_WA_RUN 3_000114.LAB 3/31/2010 17:33:35 319.761 23.629 13.145 0.115 -0.011 9.298 0.050 0.209 

AGRIUM_WA_RUN 3_000115.LAB 3/31/2010 17:34:05 332.142 23.655 13.095 0.095 -0.012 9.223 0.049 0.138 

AGRIUM_WA_RUN 3_000116.LAB 3/31/2010 17:34:35 335.458 23.472 13.039 0.109 -0.010 9.239 0.047 0.186 

AGRIUM_WA_RUN 3_000117.LAB 3/31/2010 17:35:05 323.752 23.612 13.114 0.112 -0.011 9.585 0.053 0.153 

322.271 23.516 12.985
Date Time

3/31/2010 17:14:08

3/31/2010 17:14:38

3/31/2010 17:15:08

3/31/2010 17:15:38

3/31/2010 17:16:08

3/31/2010 17:16:38

3/31/2010 17:17:08

3/31/2010 17:17:38

3/31/2010 17:18:08

3/31/2010 17:18:37

3/31/2010 17:19:07

3/31/2010 17:19:37

3/31/2010 17:20:07

3/31/2010 17:20:37

3/31/2010 17:21:07

3/31/2010 17:21:37

3/31/2010 17:22:07

3/31/2010 17:22:37

3/31/2010 17:23:07

3/31/2010 17:23:37

3/31/2010 17:24:06

3/31/2010 17:24:36

3/31/2010 17:25:06

3/31/2010 17:25:36

3/31/2010 17:26:06

3/31/2010 17:26:36

3/31/2010 17:27:06

3/31/2010 17:27:36

3/31/2010 17:28:06

3/31/2010 17:28:36

3/31/2010 17:29:06

3/31/2010 17:29:36

3/31/2010 17:30:05

3/31/2010 17:30:35

3/31/2010 17:31:05

3/31/2010 17:31:35

3/31/2010 17:32:05

3/31/2010 17:32:35

3/31/2010 17:33:05

3/31/2010 17:33:35

3/31/2010 17:34:05

3/31/2010 17:34:35

3/31/2010 17:35:05

Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF6 res

0.955 0.076 0.005 0.048 0.005 1.448 0.030 0.267 0.014 0.002 

0.955 0.082 0.005 0.048 0.006 1.456 0.033 0.287 0.013 0.002 

0.955 0.090 0.005 0.047 0.006 1.423 0.033 0.288 0.015 0.002 

0.955 0.093 0.005 0.046 0.006 1.399 0.033 0.276 0.014 0.002 

0.955 0.090 0.005 0.048 0.006 1.380 0.032 0.277 0.015 0.002 

0.955 0.081 0.004 0.048 0.006 1.380 0.030 0.282 0.016 0.002 

0.955 0.084 0.005 0.046 0.006 1.385 0.031 0.277 0.017 0.002 

0.955 0.084 0.005 0.047 0.006 1.377 0.029 0.282 0.016 0.002 

0.955 0.084 0.005 0.047 0.005 1.383 0.033 0.284 0.017 0.002 

0.955 0.088 0.005 0.046 0.006 1.413 0.031 0.283 0.017 0.002 

0.955 0.075 0.005 0.049 0.006 1.407 0.030 0.287 0.016 0.002 

0.955 0.083 0.005 0.051 0.006 1.422 0.032 0.288 0.015 0.002 

0.955 0.075 0.005 0.051 0.006 1.380 0.030 0.289 0.016 0.002 

0.955 0.091 0.006 0.048 0.006 1.357 0.033 0.287 0.017 0.002 

0.955 0.082 0.005 0.048 0.006 1.354 0.033 0.294 0.015 0.002 

0.955 0.083 0.005 0.050 0.006 1.401 0.032 0.306 0.016 0.002 

0.955 0.081 0.005 0.051 0.007 1.448 0.032 0.304 0.016 0.002 

0.955 0.080 0.005 0.053 0.005 1.450 0.032 0.301 0.014 0.002 

0.955 0.078 0.005 0.048 0.006 1.457 0.031 0.303 0.015 0.002 

0.955 0.087 0.006 0.052 0.005 1.458 0.033 0.303 0.015 0.002 

0.955 0.084 0.005 0.047 0.006 1.481 0.032 0.295 0.016 0.002 

0.955 0.086 0.005 0.049 0.005 1.463 0.032 0.302 0.016 0.002 

0.955 0.091 0.005 0.048 0.006 1.437 0.032 0.298 0.016 0.002 

0.955 0.086 0.005 0.047 0.006 1.467 0.031 0.298 0.016 0.002 

0.956 0.087 0.005 0.050 0.006 1.514 0.030 0.300 0.014 0.002 

0.956 0.084 0.005 0.049 0.006 1.519 0.033 0.300 0.017 0.002 

0.956 0.088 0.005 0.049 0.006 1.475 0.032 0.299 0.016 0.002 

0.956 0.091 0.005 0.050 0.005 1.489 0.033 0.300 0.016 0.002 

0.956 0.093 0.005 0.050 0.006 1.527 0.033 0.301 0.016 0.002 

0.956 0.076 0.005 0.051 0.006 1.500 0.033 0.298 0.017 0.002 

0.956 0.076 0.006 0.055 0.006 1.382 0.031 0.300 0.015 0.002 

0.956 0.076 0.006 0.055 0.005 1.327 0.035 0.298 0.014 0.002 

0.956 0.076 0.005 0.053 0.005 1.429 0.034 0.303 0.017 0.002 

0.956 0.081 0.005 0.050 0.006 1.587 0.032 0.299 0.015 0.002 

0.956 0.081 0.005 0.053 0.006 1.612 0.034 0.306 0.016 0.002 

0.956 0.084 0.005 0.055 0.006 1.620 0.034 0.298 0.017 0.002 

0.956 0.082 0.005 0.056 0.006 1.596 0.033 0.298 0.015 0.002 

0.956 0.082 0.005 0.055 0.006 1.508 0.035 0.295 0.015 0.002 

0.956 0.080 0.005 0.054 0.005 1.412 0.034 0.301 0.014 0.002 

0.956 0.086 0.005 0.059 0.005 1.413 0.036 0.296 0.016 0.002 

0.956 0.078 0.006 0.049 0.005 1.608 0.034 0.301 0.015 0.002 

0.956 0.079 0.005 0.060 0.006 1.653 0.034 0.298 0.016 0.002 

0.956 0.083 0.005 0.054 0.005 1.482 0.036 0.299 0.016 0.002 
Spectrum Date Time N2O NO NO2 NH3 SF6 CO ppm CO2% Ethylene 

AGRIUM_WA_RUN 3_000137.LAB 3/31/2010 17:45:03 325.082 23.719 12.344 0.135 -0.004 9.252 0.056 0.152 

AGRIUM_WA_RUN 3_000138.LAB 3/31/2010 17:45:33 322.967 23.650 12.436 0.112 -0.005 9.094 0.057 0.098 

AGRIUM_WA_RUN 3_000139.LAB 3/31/2010 17:46:03 321.621 23.578 12.611 0.111 -0.007 9.222 0.059 0.225 

AGRIUM_WA_RUN 3_000140.LAB 3/31/2010 17:46:32 320.740 23.555 12.712 0.124 -0.005 9.474 0.052 0.185 

AGRIUM_WA_RUN 3_000141.LAB 3/31/2010 17:47:02 321.037 23.599 12.762 0.120 -0.005 9.434 0.051 0.152 

AGRIUM_WA_RUN 3_000142.LAB 3/31/2010 17:47:32 320.701 23.515 12.795 0.136 -0.005 9.386 0.047 0.159 

AGRIUM_WA_RUN 3_000143.LAB 3/31/2010 17:48:02 320.717 23.692 12.690 0.135 -0.006 9.323 0.060 0.115 

AGRIUM_WA_RUN 3_000144.LAB 3/31/2010 17:48:32 324.141 23.526 12.739 0.151 -0.006 9.208 0.048 0.126 

AGRIUM_WA_RUN 3_000145.LAB 3/31/2010 17:49:02 326.311 23.362 12.749 0.143 -0.005 8.997 0.056 0.090 

AGRIUM_WA_RUN 3_000146.LAB 3/31/2010 17:49:32 327.676 23.378 12.817 0.142 -0.006 9.079 0.059 0.113 

AGRIUM_WA_RUN 3_000147.LAB 3/31/2010 17:50:02 325.412 23.456 12.791 0.141 -0.007 8.989 0.064 0.142 

AGRIUM_WA_RUN 3_000148.LAB 3/31/2010 17:50:32 323.436 23.424 12.765 0.134 -0.006 8.891 0.052 0.135 

AGRIUM_WA_RUN 3_000149.LAB 3/31/2010 17:51:02 318.348 23.547 12.794 0.153 -0.006 9.098 0.055 0.123 

AGRIUM_WA_RUN 3_000150.LAB 3/31/2010 17:51:32 312.322 23.606 12.767 0.126 -0.006 9.226 0.045 0.100 

AGRIUM_WA_RUN 3_000151.LAB 3/31/2010 17:52:02 319.382 23.465 12.760 0.141 -0.006 8.922 0.054 0.142 

AGRIUM_WA_RUN 3_000152.LAB 3/31/2010 17:52:31 332.803 23.291 12.819 0.080 -0.007 8.927 0.056 0.175 

AGRIUM_WA_RUN 3_000153.LAB 3/31/2010 17:53:01 334.347 23.339 12.820 0.103 -0.009 8.971 0.054 0.114 

AGRIUM_WA_RUN 3_000154.LAB 3/31/2010 17:53:31 331.784 23.353 12.735 0.093 -0.007 8.879 0.060 0.173 

AGRIUM_WA_RUN 3_000155.LAB 3/31/2010 17:54:01 330.571 23.415 12.746 0.068 -0.008 8.840 0.059 0.118 

AGRIUM_WA_RUN 3_000156.LAB 3/31/2010 17:54:31 327.371 23.504 12.688 0.103 -0.007 8.964 0.053 0.114 

AGRIUM_WA_RUN 3_000157.LAB 3/31/2010 17:55:01 330.591 23.523 12.715 0.096 -0.007 8.918 0.051 0.144 

AGRIUM_WA_RUN 3_000158.LAB 3/31/2010 17:55:31 329.458 23.444 12.730 0.078 -0.008 9.003 0.057 0.014 

AGRIUM_WA_RUN 3_000159.LAB 3/31/2010 17:56:01 329.954 23.294 12.744 0.053 -0.009 8.950 0.056 0.128 

AGRIUM_WA_RUN 3_000160.LAB 3/31/2010 17:56:31 329.093 23.386 12.745 0.071 -0.008 9.017 0.054 0.121 

AGRIUM_WA_RUN 3_000161.LAB 3/31/2010 17:57:01 329.493 23.306 12.646 0.093 -0.009 8.856 0.053 0.177 

AGRIUM_WA_RUN 3_000162.LAB 3/31/2010 17:57:31 343.489 23.236 12.674 0.122 -0.008 9.102 0.051 0.114 

AGRIUM_WA_RUN 3_000163.LAB 3/31/2010 17:58:00 340.126 23.147 12.662 0.106 -0.009 9.111 0.053 0.109 

AGRIUM_WA_RUN 3_000164.LAB 3/31/2010 17:58:30 320.850 23.285 12.743 0.082 -0.010 8.748 0.059 0.240 

AGRIUM_WA_RUN 3_000165.LAB 3/31/2010 17:59:00 317.198 23.295 12.688 0.104 -0.009 8.845 0.062 0.136 

AGRIUM_WA_RUN 3_000166.LAB 3/31/2010 17:59:30 325.548 23.350 12.620 0.068 -0.011 8.800 0.058 0.138 

AGRIUM_WA_RUN 3_000167.LAB 3/31/2010 18:00:00 325.521 23.226 12.615 0.040 -0.011 8.770 0.059 0.138 

AGRIUM_WA_RUN 3_000168.LAB 3/31/2010 18:00:30 322.493 23.169 12.587 0.045 -0.009 8.804 0.056 0.110 

AGRIUM_WA_RUN 3_000169.LAB 3/31/2010 18:01:00 320.852 23.320 12.547 0.075 -0.010 8.789 0.055 0.106 

AGRIUM_WA_RUN 3_000170.LAB 3/31/2010 18:01:30 322.822 23.210 12.618 0.049 -0.011 8.742 0.052 0.155 

AGRIUM_WA_RUN 3_000171.LAB 3/31/2010 18:02:00 322.813 23.158 12.579 0.051 -0.010 8.773 0.061 0.163 

AGRIUM_WA_RUN 3_000172.LAB 3/31/2010 18:02:30 320.262 23.211 12.584 0.059 -0.012 8.914 0.054 0.276 

AGRIUM_WA_RUN 3_000173.LAB 3/31/2010 18:03:00 319.263 23.149 12.582 0.056 -0.011 8.706 0.056 0.242 

AGRIUM_WA_RUN 3_000174.LAB 3/31/2010 18:03:29 320.255 23.127 12.597 0.048 -0.012 8.841 0.057 0.147 

AGRIUM_WA_RUN 3_000175.LAB 3/31/2010 18:03:59 323.102 23.200 12.643 0.060 -0.011 8.749 0.059 0.124 

AGRIUM_WA_RUN 3_000176.LAB 3/31/2010 18:04:29 325.277 23.112 12.638 0.002 -0.012 8.862 0.055 0.138 

AGRIUM_WA_RUN 3_000177.LAB 3/31/2010 18:04:59 323.258 23.095 12.636 0.043 -0.012 8.676 0.053 0.142 

AGRIUM_WA_RUN 3_000178.LAB 3/31/2010 18:05:29 323.218 22.986 12.626 0.074 -0.013 8.655 0.056 0.144 

AGRIUM_WA_RUN 3_000179.LAB 3/31/2010 18:05:59 323.731 22.999 12.638 0.052 -0.012 8.840 0.052 0.173 

325.010 23.354 12.679
Date Time

3/31/2010 17:45:03

3/31/2010 17:45:33

3/31/2010 17:46:03

3/31/2010 17:46:32

3/31/2010 17:47:02

3/31/2010 17:47:32

3/31/2010 17:48:02

3/31/2010 17:48:32

3/31/2010 17:49:02

3/31/2010 17:49:32

3/31/2010 17:50:02

3/31/2010 17:50:32

3/31/2010 17:51:02

3/31/2010 17:51:32

3/31/2010 17:52:02

3/31/2010 17:52:31

3/31/2010 17:53:01

3/31/2010 17:53:31

3/31/2010 17:54:01

3/31/2010 17:54:31

3/31/2010 17:55:01

3/31/2010 17:55:31

3/31/2010 17:56:01

3/31/2010 17:56:31

3/31/2010 17:57:01

3/31/2010 17:57:31

3/31/2010 17:58:00

3/31/2010 17:58:30

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Pres. (Atm) CO ppm 

resid CO2% resid Ethylene resid H2O% resid N2O resid NH3 resid NO resid NO2 resid SF6 res

0.956 0.078 0.004 0.039 0.005 1.515 0.026 0.242 0.013 0.00

0.956 0.077 0.005 0.042 0.005 1.464 0.029 0.247 0.015 0.002 

0.956 0.071 0.005 0.040 0.005 1.450 0.029 0.254 0.015 0.002 

0.956 0.074 0.005 0.044 0.006 1.409 0.028 0.256 0.016 0.002 

0.956 0.077 0.005 0.046 0.006 1.408 0.030 0.260 0.016 0.002 

0.956 0.077 0.005 0.049 0.005 1.426 0.031 0.260 0.015 0.002 

0.956 0.086 0.006 0.046 0.005 1.434 0.030 0.268 0.015 0.002 

0.956 0.081 0.006 0.046 0.005 1.504 0.029 0.277 0.015 0.002 

0.956 0.084 0.005 0.045 0.005 1.555 0.031 0.287 0.014 0.002 

0.956 0.082 0.005 0.044 0.005 1.553 0.030 0.274 0.013 0.002 

0.956 0.083 0.005 0.046 0.005 1.536 0.031 0.274 0.014 0.002 

0.956 0.085 0.006 0.046 0.005 1.508 0.030 0.276 0.015 0.002 

0.956 0.085 0.005 0.047 0.006 1.424 0.030 0.280 0.014 0.002 

0.956 0.078 0.005 0.046 0.006 1.311 0.029 0.282 0.016 0.002 

0.956 0.074 0.004 0.044 0.005 1.434 0.028 0.283 0.015 0.002 

0.956 0.076 0.005 0.046 0.006 1.611 0.030 0.275 0.015 0.002 

0.956 0.077 0.005 0.045 0.005 1.645 0.029 0.274 0.016 0.002 

0.956 0.078 0.005 0.045 0.005 1.598 0.030 0.275 0.015 0.002 

0.956 0.078 0.005 0.049 0.006 1.575 0.032 0.270 0.016 0.002 

0.956 0.080 0.005 0.050 0.005 1.530 0.030 0.273 0.015 0.002 

0.956 0.073 0.005 0.048 0.006 1.570 0.029 0.277 0.015 0.002 

0.956 0.073 0.005 0.046 0.005 1.539 0.028 0.280 0.016 0.002 

0.956 0.078 0.005 0.045 0.005 1.552 0.031 0.280 0.017 0.002 

0.956 0.073 0.005 0.047 0.005 1.537 0.031 0.276 0.017 0.002 

0.956 0.073 0.005 0.047 0.005 1.549 0.029 0.278 0.016 0.002 

0.956 0.067 0.005 0.047 0.005 1.786 0.030 0.282 0.015 0.002 

0.956 0.070 0.005 0.046 0.005 1.722 0.031 0.284 0.015 0.002 

0.956 0.071 0.005 0.046 0.005 1.422 0.030 0.280 0.016 0.002 

0.956 0.074 0.005 0.051 0.005 1.379 0.033 0.279 0.015 0.002 

0.956 0.074 0.005 0.043 0.006 1.483 0.029 0.283 0.017 0.002 

0.956 0.078 0.005 0.049 0.005 1.489 0.030 0.277 0.018 0.002 

0.956 0.073 0.006 0.045 0.005 1.439 0.029 0.283 0.015 0.002 

0.956 0.080 0.005 0.051 0.005 1.408 0.032 0.288 0.018 0.002 

0.956 0.076 0.005 0.053 0.005 1.444 0.034 0.285 0.017 0.002 

0.956 0.080 0.006 0.050 0.005 1.443 0.032 0.280 0.017 0.002 

0.956 0.084 0.005 0.052 0.005 1.417 0.034 0.283 0.015 0.002 

0.956 0.081 0.006 0.055 0.005 1.403 0.033 0.282 0.014 0.002 

0.956 0.071 0.005 0.055 0.005 1.409 0.033 0.284 0.017 0.002 

0.956 0.075 0.005 0.051 0.005 1.449 0.032 0.280 0.017 0.002 

0.956 0.072 0.005 0.054 0.005 1.481 0.032 0.280 0.017 0.002 

0.956 0.084 0.005 0.058 0.006 1.456 0.035 0.287 0.015 0.002 

0.956 0.077 0.005 0.054 0.005 1.459 0.034 0.285 0.018 0.002 

0.956 0.076 0.006 0.061 0.005 1.463 0.037 0.284 0.016 0.002 
APPENDIX D

Miscellaneous Supporting Information

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Copyrighted page(s) removed. Copyrighted 

material is not available in Regulations.gov since 

it may not be reproduced without consent of the 

copyright holder. 

Removed pages can be viewed at the USEPA 

Docket Center, Public Reading Room. 

Address: 1301 Constitution Ave, NW 

Room 3334 

Washington, DC 20004 

Telephone: 202-566-1744 

Email: docket-customerservice@epa.gov
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TLtqut\ T,erbnsts gy @nrp o rutf o n

lndustry Leader in Specialty Gases, Equipment and Seruice

Certificate of Analr sis

Customer Soderberg Polwechnic Co (Shawnee. KS)

Date January 19.2010

Delivery Receipt DR-27271

Product: 500 ppm N2O. 500 ppm CH4. 10 ppm SF6Nitrogen - Certified Standard

Mixture Specifications

Cylinder Number: EB-0020403

Components RCgUg$gd Actual

Nitrous Oxide 500.0 ppm 500.2 ppm

Methane 500.0 ppm 504.0 ppm

Sulfur Hexafluoride 10.0 ppm 10.0 ppm

Nitrogen Balance Balance

- Certified Standard -

TraceabiliW Information Traceabilit)'T)'pe Traceable to

Blending Process: Gravimetric Mole Percent

Blend Tolerance: Weight NIST

Analytical Tolerance: Gas Standard NIST

Traceability Certificate: 8221266926-02

Cylinder Data

Cylinder Outlet: ' CGA 590

Cylinder Volume: .140"Cubic Feet

Cylinder Pressure: 2000 psig, 70"F

Analytical Tolerance: +l- 2.0T,

Expiration Date: January 19,2013

fffi'Lfit^*

Mike Duncan

Unmatched Excellence

2564 PemberTon Drive - Apopka, Florida 32703 - phone (407)-292-2990 - Fax (407)-292-3313

- www.li q u i dtech corp.co m., -

Certified by:

145
rrAlR LIOUIDE Air -ou'oe a-re-ca J'a s'eca* -ases r ,

t#J

Scott

REFERENCE CLASS

Dual-Certified Calibration Standard

1290 COMBERMERE STREET, TROY, MI 48083

CERTIFICATE OF ACCURACY:

Phone: 248-589-2950 Fa* 248-589 2134

Reference Class Calibration Standard

Project No.: 05-75392-OO 1

Item No.: 0502OOO'l29OOAL

P.O. No.: FDSSF

Cylinder Number: ALMo6'l 289

Cylinder Size: AL

Certification Date: 23Apr2009

Expiration Date: 23Apr2O 1 1

CERTIFIED CONCENTRATION

Customer

AIRSOURCE TECHNOLOGIES, INC

2O5O5 W 67TH STREET

SHAWNEE, KS 6621 8

Component Name

ETHYLENE

NITROGEN

TRACEABILITY

Concentration

{Moles)

99.6 PPM

BALANCE

Traceability Type

WEIGHT

GAS STANDARDS

Accuracy

l+ l-o/ol

1

Description

BLEND PROCESS TRACEABILITY

ANALYTICAL TRACEABILITY

Traceable To

NIST

Ploduct lnformation

APPROVED

Page 1 ol 2

DArE: l PZ

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