# Patent

## Title
Composite treatment of ceramic tile armor

## Abstract

An improved ceramic tile armor has a core of boron nitride and a polymer matrix composite (PMC) facing of carbon fibers fused directly to the impact face of the tile. A polyethylene fiber composite backing and spall cover are preferred. The carbon fiber layers are cured directly onto the tile, not adhered using a separate adhesive so that they are integral with the tile, not a separate layer.

## Background
STATEMENT REGARDING FEDERALLY FUNDED RESEARCH THE UNITED STATES GOVERNMENT
The United States Government has rights in this invention pursuant to contract number DE-AC05-000R22725 between the United States Department of Energy and U.T. Battelle, LLC.


FIELD OF THE INVENTION
This invention relates to improvements in application of polymer matrix composite materials useful in a ballistic armor.
BACKGROUND OF THE INVENTION
Modern ballistic armor involves a classic balancing of weight versus penetration resistance. Two classes of materials predominate. Metal armor can be fabricated to almost any thickness and alloyed for increased hardness. It is heavy but tends to deform when impacted, allowing it to survive multiple impacts. Ceramic armor is lighter than metal, harder but more fragile. Even when not penetrated it may shatter and be comprised for further use. Personal armor tends toward light ceramics and there is a needed to strengthen the ceramic tiles to withstand multiple impacts.
Multiple layered armor using epoxy adhesives is disclosed in U.S. Pat. No. 5,705,764 to Schade et al. Infiltration of porous ceramics is disclosed in U.S. Pat. No. 6,451,385 to Hilden et al. An armor, including multiple layers of fibers in an elastomeric matrix bonded to a hard metal or ceramic plate, in a perimeter wrapped tile mounted on a backing plate, is disclosed in U.S. Pat. No. 6,601,497 to Ghiorse et al.
BRIEF DESCRIPTION OF THE INVENTION
It is a first objective of this invention to provide a new form of polymer composite matrix facing for a ceramic tile. It is a second object of this invention to provide a different method for preparing a composite tile armor. It is a third object of this invention to provide an armor tile which can withstand multiple impacts without shattering the underlying tile.
These and other objects of the invention can be obtained by providing an oriented fiber composite face to a hardened ceramic tile armor by direct heat and pressure bonding of a non-woven high tensile strength fabric to a ceramic tile.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows a prior art armor tile without the facing layers of this invention.
FIG. 2 shows one embodiment of the composite armor tile of this invention.



DETAILED DESCRIPTION OF THE INVENTION
The invention is a composite ceramic-based armor which provides improved resistance to penetration upon initial impact and residual resistance to impact after the initial impact. The composite tile of this invention withstands multiple impacts because the high tensile strength bonded facing strengthens the underlying ceramic tile, moderates shock waves throughout the tile, controls tensile stress changes through the bulk of the ceramic and holds the tile together in the event that the tile is penetrated.
The tile component is selected primarily on the basis of hardness. Non-limiting examples of suitable ceramic materials include aluminum oxide, aluminum nitride, silicon carbide, silicon nitride, boron carbide, titanium diboride and titanium carbide. Mixed ceramics and infused ceramics are encompassed within the scope of the useful ceramics. The salient characteristic is that the ceramic be harder than the incident projectile and have a high compressive strength. The ceramic tile must be able to erode and break up hardened steel penetrators without being destroyed itself.
When the shock wave from the projectile reflects off the back face of a tile it becomes a tensile stress. Excessive tensile stress results in cracks and/or disintegration. Methods to moderate or relieve stress have focused upon laminations of various materials over or around the ceramic tile.
We have discovered that fibers such as glass, aramid, PBO, M5, Rusar and carbon in prepregged form. adhered directly to tile faces provide enhanced impact resistance compared to systems applying adhesives to attach fibers to ceramics. Furthermore, we have discovered that multiple layers of fibers arranged in layers oriented at 90° to each other show superior performance when compared to random orientations (chopped fiber).
Boron carbide (B4C) was selected because of its hardness and availability in armor grade as pressure assisted densification (PAD) material from Cercom Inc., CA, USA. Prepregged carbon fibers, polyacrylonitrilebased (PAN) in oriented tapes were used for laying up the polymer matrix.
The tapes were arranged at 0°/90° in the plane of the tile. The coated tiles were isotactically compressed in a bag which was evacuated and the sealed bag heated to 250° F. for 2-3 hours. Table I shows the construction of the samples.
FIG. 1 shows the prior art tile 1. A backing layer 3 such as Spectra Shield Plus® supports a B4C tile 5, to the face of which is applied adhesively a spall cover of woven polyethylene fabric. The projectile direction is indicated by arrow 9. FIG. 2 shows the armor of this invention. The adhered carbon fiber composite 11, 11′ is adhered to both sides of the B4C tile.
The ballistic impact testing was conducted versus the armor piercing 7.62 mm AP M61 (NATO .308) round. The powder charge in the cartridge was adjusted to produce varying impact velocities at the target location. The ceramic tile thickness that was selected, 6.2 mm, was chosen to assure that complete penetration of the armor tiles could be achieved within the range of velocities available. The armor targets were mounted on the back surface of a steel plate (relative to the impact direction) using a bolted-on window frame holder that applied a uniform clamping force around the perimeter of the armor tile. The central 76×76 mm (3×3 in.) area of the back face of the armor tile was unsupported during the test. The steel plate with the mounted armor tile was held in a rigid frame at a muzzle-to-target distance of 10 m (30 ft.). A universal receiver on a fixed pedestal was used to fire the rounds at the target. After the bullet was fired, the armor tiles were examined to determine whether the impact resulted in a complete penetration or a partial penetration, in which the armor is partially penetrated, but the projectile is stopped within the armor system. Every effort was made to be consistent in tile preparation, mounting, and testing to assure valid side-by-side comparison of the ballistic impact performance.
Results and Discussion
The results of the ballistic impact tests are summarized in Table II. V50 indicates that the tile was penetrated one-half of the time. In all cases where a partial penetration was recorded, the armor tiles having a PMC facing showed improved ballistic impact performance compared to the baseline armor tile without the PMC facing. Although the areal density of the tiles was generally increased by the addition of the PMC facing, this was more than offset by the improvement in penetration resistance. For example, the areal density of sample number 4 with 8 PMC layers was 9% higher than the baseline armor tile, but the apparent ballistic V50 was increased by more than 40%.
It has been found that increasing the number of plies in the PMC facing increased the penetration resistance of the armor tile for the range of values tested. Ballistic performance improved monotonically as the number of plies was increased from 0 to 8. It also is apparent that the orientation of the fibers in the PMC plies had an effect on the test results. Fibers arranged at 90° to each other show best results. Differences, if any, in the prepreg resins were not apparent.
The reason for the improvement in ballistic impact performance when the PMC facing layers were present is not yet fully understood, while not being bound by any theory. It may be speculated that the composite layers act to delay the onset of fracture and fragmentation of the ceramic material. The composite layers may provide a lateral constraint on the ceramic tile, which could slow the spread of cracks and the separation of tile fragments. Based on the observed effect of the fiber orientation, it is also possible that the PMC layers may provide a form of acoustical damping that affects the propagation of stress waves in the ceramic tile resulting in delayed fracture.
It is not known whether similar effects would be observed with B4C from other suppliers or with alternative ceramic armor materials such as Al2O3, SiC, and Si3N4.
The invention has been described on the basis of representative examples which are in no way limitative of the invention. Modifications apparent to a person with skill in the art are included within the scope of the invention.
INDUSTRIAL UTILITY
Armored tiles, according to this invention have utility in any occupation in which a person might be subject to being shot, such as in law enforcement and transportation of money and precious gems. Scatter shields for protection against mechanical equipment failure are also envisioned for the invention.







TABLE I







Identification and characteristics of


fibers used to form the PMC facing layers.











Sample


Elastic
Tensile


Number
Fiber
Material
Modulus
Strength





2-6
Toray T700a
Carbon
Intermediate
High


7
Granoc XN-05b
Carbon
Low
Low


8
Toray M46Ja
Carbon
High
High


9
Granoc CN-80b
Carbon
Ultra-high
Low


10 
Zylon ® (PBO)c
Polymer
Intermediate
High





aToray Carbon Fibers America, Inc.;


bNippon Graphite Fiber Corp.;


cToyobo Company, Ltd.













TABLE II







Armor tile variations and ballistic impact results.



















Areal

“V”50
FOM2
FOM


Sample

PMC
Fiber
Density
“V50” 1
Increase
V50/Areal
Increase


Number
PMC Fiber
Plies
Orientation
(lb/ft2)
(ft/s)
(%)
Density
(%)


















1
No PMC
—
—
5.26
2050
—
390
—


2
T700
2
0/90
5.20
>2175
>6
>418
>7.1


3
T700
4
0/90/0/90
5.53
2550
24
461
18


4
T700
8
0/90/0/90
5.73
>2880
>40
>503
>29


5
T700
4
+45/−45/+45/
5.41
>2625
>28
485
>24





−45







6
T700
4
0/−45/+45/90
5.44
no partial
—
—
—


7
XN-05
4
0/90/0/90
5.35
2500
22
467
20


8
M46J
4
0/90/0/90
5.42
no partial
—
—
—


9
CN-80
4
0/90/0/90
5.45
>2610
>27
>479
>23


10
Zylon ®
4
0/90/0/90
5.43
>2730
>33
>503
>29



(PBO)





1For most variations, the number of samples tested was insufficient to determine a true ballistic V50 value. V50 is the velocity at which 50% of impacts are complete penetrations and 50% are partial penetrations.


2The Figure of Merit (FOM) is defined as the V50 velocity with units of ft/s divided by the areal density with units of lb/ft2

## Claims

1. An improved polymer matrix composite reinforced ballistic armor tile comprising:
a) a ceramic tile;
b) a backing, and;
c) a polymer matrix composite facing adhered directly to at least one face of said tile under conditions of sealed compression and heat wherein said composite comprises at least two fiber comprising layers wherein fibers in a first layer of said two layers are oriented at 90° relative to second fibers in a second layer of said two layers wherein said polymer matrix composite reinforced ballistic armor tile has a FOM of over 418 lb/ft2.

2. An improved polymer matrix ballistic armor tile according to claim 1 wherein said tile is a ceramic tile selected from the group consisting of aluminum oxide, silicon carbide, silicon nitride, boron carbide, titanium diboride and titanium carbide.

3. An improved polymer matrix composite reinforced ballistic armor tile according to claim 2 wherein said ceramic tile is boron carbide.

4. An improved polymer matrix composite reinforced ballistic armor tile according to claim 1 wherein said backing is a metal plate.

5. An improved polymer matrix composite reinforced ballistic armor tile according to claim 1 wherein said polymer composite facing is a polymer reinforced with fibers from the group consisting of glass, aramid, poly-p-phenylenebenzobisoxazole, poly{diimidazo pyridinylene(dihydroxy)phenylene}, p-phenylene terephtalamide and carbon.

6. An improved polymer matrix composite reinforced ballistic armor tile according to claim 5 wherein said fiber is carbon fiber.

7. An improved polymer matrix composite reinforced ballistic armor tile according to claim 6 wherein said carbon fiber is a polyacrylonitrile based fiber.

8. An improved polymer matrix composite reinforced ballistic armor tile according to claim 1 further incorporating a spall cover.

9. An improved polymer matrix composite reinforced ballistic armor tile according of claim 8 wherein said spall cover is polyethylene fiber composite.

10. An improved polymer matrix composite reinforced ballistic armor tile according to claim 1 wherein said polymer matrix is cured as a coating on one face of said tile.

11. An improved polymer matrix composite reinforced ballistic armor tile according to claim 1 wherein said polymer matrix is adhered to an opposite face from a first face of said at least one face of said tile.

12. An improved polymer matrix composite reinforced ballistic armor tile comprising:
a) a ceramic tile;
b) a backing, and;
c) a polymer matrix composite facing adhered directly to said ceramic tile by pressure and heat comprising at least two fiber comprising layers wherein fibers in a first layer of said two layers are oriented at 90° relative to second fibers in a second layer of said two layers; wherein said polymer matrix composite reinforced ballistic armor tile has a FOM of over 418 lb/ft2.

13. The improved polymer matrix composite reinforced ballistic armor tile of claim 12 with a FOM of over 479 lb/ft2.

14. The improved polymer matrix composite reinforced ballistic armor tile of claim 13 with a FOM of over 503 lb/ft2.