### P. 1



# OAR Box 1851
Prepped by Keeia Richards



# Document

Number: 

# 27 ) ll-A- 1

Docket Number: 

# A-90-1 9

Printed 11/19/2008 11:19:51 AM Sheet 27 of 41

# P. 2



# fl 

# A-90-1 9 I ll-A- 1 

# r EPA-450/3-73-005 a



# SURVE Y REPORT S ON ATMOSPHERI C EMISSJ^r * — FROM TH E PETROCHEMICA L

INDUSTR Y SPA ui?ai«i v VOLUME I k

# t»ijii 5,i r

Prepare db y J

. W

. Pervier

. R

. C

. Barley

. D

. E

. Field

. B.M

. Friedman , R

. B

. Morris , an dW

. A

. Schwart z

Houdr y Divisio n Ai r Product s an dChemicals , Inc

. P

. O

. Bo x 42 7 Marcu s Hook , Pennsylvani a1906 1

Contrac t No

. 68-02-025 5

EP AProjec t

Officer : Lesli e B

. Evan s

Prepare dfo r ENVIRONMENTA LPROTECTIO NAGENC Y Offic e o f

Ai r an dWate r

Program s Offic e o f

Ai r Qualit y Plannin g an dStandard s Researc hTriangl e Park , N

. C

. 2771 1

Januar y 197 4

### P. 3



# Thi s repor ti s issue d b y th e Environmenta l Protectio nAgenc y t o repor t technica l dat ao f

interes tt o alimite d numbe ro f readers . Copie s ar e availabl efre eo f

charg et o Federa l employees , curren tcontractor s an d grantees , an d nonprofi torganization s - a s supplie s permi t- fro m th e Ai rPollutio nTechnica l Informatio nCenter , Environmenta l Protectio n Agency , Researc h Triangl e Park , Nort h Carolin a27711 , o rfro m th e Nationa l Technica l Informatio nService , 528 5 Por tRoya l Road , Springfield , Virgini a22151 .

Thi s repor twa s furnishe d t o th e Environmenta l Protectio nAgenc y b y Houdr y Division , Ai rProduct s an d Chemicals , Ine. , Marcu s Hook , Pennsylvania , i nfulfillmen to f Contrac tNo . 68-02-0255 . Th e content s o f thi s repor tar ereproduce d herei na s receive d fro m th e Houdr y Division , Ai rProduct s an d Chemicals , Inc . Th e opinions , findings , an d conclusion s expresse d ar ethos eo f th eautho ran d no tnecessaril y thos eo f

th eEnvironmenta l Protectio nAgency . Mentio no f compan y o r produc tname s i s no tt o b e considere d a s a nendorsemen tb y th e Environmenta l Protection , Agency .

Publicatio nNo . EPA-450/3/73/005 a

u

> •

# 1 ^ ^ " f" f" f

. I, I, I, IJ t| L

_

EP A Plan tCod e No . Capacit y - Ton s o f Acetaldehyde/Yr . Productio n- Ton s ol Acetaldehyde/Yr . Emission s t o th e Atmospher e Strea m 1 . D . No . Strea m TABL E ACD-U I NATIONAL EMISSION S INVENTOR Y ACETALDEHYD

E VI A ETHYLEN

E PROCEFS
1- 2 225,00 0 220,00 0

Regenerato rOff-(a s Scrubhe r*'en t Ligh tEnd p Scrubhe r"en t
Flo v- Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t i f Intermitten t - llrs./Yr . Compositio n- Tons/To no f Acetaldehyd e Ethylen e Methy l Chlorid e Ethy l Chlorid e Carbo nDioxid e Wate r Nitroge n Argo n Oxyge n Analysi s Sampl e Ta pLocatio n Frequenc y

o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ga s Temperatur e - F ° SCF M Emissio nContro l Device s Typ e Summar y

o f Ai r Pollutant s Hydrocarbon s - Ton/To no f Acetaldehyd e Particulate s - Ton/To no f Acetaldehyd e NO, , - Ton/To no f Acetaldehyd e S 0 X- Ton/To no f Acetaldehvd e C O - Ton/To no f Acetaldehyd e 40,87 1 (1) Continuou s

.0004 1 .0000 4 .0082 8 .0004 0 .7452 4 .0128 8 .0043 0 Ye s I nstream C 2 H 4 & C« 2 Continuou s - Other s Weekl y C2H 4 Infrare d- Other s Chromatograp h N o Ye s 2 (3 ) 10 0 1 6 5 9 450 0 Ye s Scrubbe r
.0009 2 0 0 0 0 767 5 (I) 

### Continuou s

0002 5 0000 7 .0001 5 .0045 9
0050 2 (2 )

Ye s I nstrea m CJH A & CO , Continuou s - Other s Weekl y 

### C,H , & CO j Infrare

d- Other s Chromatograp h N o Ye s 2 (3 ) 8 0 4 5 9 5 0 Ye s Scrubbe r

(1 ) Plan t ha s tw o Identica l system s s o actuall y tw o identica l scrubber s o f thi 6 typ e ar e employed . (2 ) Fro

m acetaldehyd e storag e tan k purge . (3 ) Fo r eac hscrubber . Flo v i 6 tota l for eac hscurbber .

# 1

TABL E HAC-I U NATIONA L EMISSION S INVENTOR Y ACETI C ACI D FRO

M METHANO L AN D C O
Plan t EP

A Cod e No
. Capacity , Ton s IIAC/Yr

. Rang e o fProduction , 7 .i fMax
. Emission s t o Atmospher e- Strea m Flo v- Lbs./Mr . Flo vCharacteristi c Composition , Ton/To n I1A C IIA C 36,48 0 (• > Continuou s N . A . 2- 3 50,00 0 0
2.20 9 <• > Continuou s N A . 'A ^ 3.08 5 (1 ) Continuou s N
. A
. 2- 6 150,00 0 0 (B) Ni l Ope nonl y

i nemergenc y (C ) 29 7 (• ) Con t i nuo u N A . 

### 1.00 0
Ven t Stack s Numbe r Heigh t - Fee t Diamete r- Inche s Exi tCa s Temp . SCFM/Stac k Emissio nContro l Device s Flare/Incinerato r Absorber/Scrubbe r Condenaer/K . O . Drum Othe r Analysi s Dat e o r Frequenc y o f Samplin g Sampl e Ta pLoactio n Typ e o f Analysi s Odo r Proble m Summar y

o f Ai r Pollutant s Hydrocarbons , Ton/To nIIA C Aerosol s an

dParticulates , Ton/To nHA C NO. . Ton/To nHA C 1 10 0 4 8 3600 ° F 730 0 (1 )
Incinerato r

Neve r Non e Non e Non e No Dat a 1 10 0 4 1 1 0 9 6 3400 ° F 42 6 ( »
Incinerato r

Spo t 7 Non e N o N o Dat a 1 19 9 1 6 N . A . 47 5
Flar e



### Ye a

S 0 X C O Ton/To nHA C Ton/To nHA C 1 1 0 8 Ambien t 109 0

Non e

Neve r Non e Non e

0.000 0 1.000 0 0.000 0 0.000 0 0.000 0 N . A

Incinerato r

N . A .

N o dat a

(1) Calculation s fro m compositio nandlbs./hr . o f feedt o incinerato r o r flare , a nestimate .

• a ?f«.« r

# 1

EP A Cod e No . Capacit y

- Ton s o f Aceti c Aci d Productio n- Ton s o f Aceti c Aci d Emission s t o Atmospher e Strea m No . Strea m

Flo w - Lbs./Hr . Flo w Characteristi c i f Intermitten t Compositio n Ethan e Methan e Butan e Carbo nDioxid e Carbo nMonoxid e Oxyge n Nitroge n Nitroge nOxide s Wate r Argo n Hydrocarbon s (assorted ) Aceton e Acetaldehyd e Methy l Acetat e Continuou s or Intermitten t Hrs./Yr . TABL E ACA-II I NATIONA L EMISSION S INVENTOR Y



### 2 Reacto r I Sectio nven t
14,06 5 Continuou s

.0036 7 .0024 5 .0174 3 .1528 9 .0068 5 ACETI C ACI D VI A BUTAN E OXIDATIO N 

### 2- 1 260,00 0 260.00 0


### 2 Reacto r I 1 Sectio nVen t 2



### 1. 4 Continuou s

.0000 1 

### +
.0049 9

.0207 6 'V.0040 9 + .0000 1 Reacto r I I Sectio nven t I A
800 5 Continuou s

.0014 9 .0007 5 .0013 6 .1095 4

.0023 0

.0058 5 .0034 8 Pag e 1 o f 3

Reacto r I I Sectio nVen t I B
677 0 Continuou s

0013 4 .0018 5 0077 4 0579 0 0066 9
.0075 0

0717 0 0076 7 Reacto r II I Sectio nVen t 7
1. 4 Continuou s

0000 1 +

- f +

+ 0000 1

Analysi s Sampl e Ta pLocatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Temp . - F ° Flow Rat e - SCF M

pe r stac k Emissio nContro l Devic e Typ e - Incinerato r

Scrubbe r Summar y

o f Emission s Tota l Hydrocarbo nEmission s - Ton/To no f Aceti c Aci d Tota l Particulat e Emission s - Ton/To no f Aceti c Aci d Ton/To no f Aceti c Aci d Emission s - Ton/To no f Aceti c Aci d Tota l CO " Emission s - Ton/To no f Aceti c Aci d Tota l N0 XEmission s Tota l S0

_ 

### Ye s Sid e 

### of 3 time s Mas s 

### N o Ye s 

### 1 9 0 1 0 10 0 202 3 

### N o Unit s 

### a Spec t wee k romete r 

### Ye s

Non e O nr Mas s 

### N o Ye s 

### 1 2 0 

### 2 8 0



## . 2 N o eques t Spectromete r 

### Ye s Sid e o f Uni t 3 time s a vee k Haa s Spectromete r 

### N o Yea 

### 1 10 0 1 0 9 0 1,15 4 

### N o Ye s Sid e o f 3 time s Uni t

a vee k Mas s Spectromete r 

### N o Ye s 

### 1 10 0 1 0 8 6 1.04 3 

### N o Ye s Non e O nremies t Mas s Spec t 

### No Ye * 

### 1 1 ? 

### 5 8 0 .? 

### N o

Continue d

### ft TABL E ACA-II I NATIONAL EMISSION S INVENTOR Y

ACETI C ACI D VI A BUTAN E OXIDATIO N Pag e 2 o f 3

EPA Cod e No . Capacit y

- Ton s o f Aceti c Aci d Productio n- Ton s o f Aceti c Aci d Emission s t o Atmospher e Strea m No . Strea m

Flo w - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr . Compositio n Ethan e Methan e Butan e Carbo nDioxid e Carbo nMonoxid e Oxyge n Nitrogen ! 1 Nitroge nOxide s Wate r Argo n Hydrocarbon s (assorted ) Aceton e Acetaldehyd e Methy l Acetat e Analysi s Sampl e Ta p Locatio n Dat eo rFrequenc y o f Samplin g Typ eo f Analysi s Odo rProble m Ven tStack s Numbe r Heigh t- Ft . Diamete r - Inche s Temp . - F ° Flo w Rat e - SCF M

pe r stac k Emissio nContro l Device s Typ e - Incinerato r

Flar e Scrubbe r Summary o f Emiaelon s Tota l Hydrocarbo nEmission s - Ton/To no f Aceti c Aci d Tota l Particulate s andAerosol s - Ton/To no f Aceti c Aci d Tota l N0 X- Ton/To no f Aceti c Aci d Tota l S0 X- Ton/To no f Aceti c Aci d Tota l C O - Ton/To no f Aceti c Aci d 2- 1 260,00 0 260,00 0

I A Flar e Stac kEmission s Reacto r Sectio nI Flar e (1 )
338 0 (2) Continuou s

.0387 5



### Negligibl e .0124 5 .0004 1

Non e

(2) No Ye a 1 71 0 2 4 Unknown '66 0 Ye a

Ye s I B Flar e Stac k Emission s Reacto r Sectio nI I Flar e (3)
^670 0 (2 ) Continuou s

.0869 1

Negligibl e .0143 3 .0008 7

Non e

<2) N o Ye s 1 71 0 2 4 Unknown 115 0 Ye s

Ye s

Continue d 3 A Toppin g Colua n Ventur i Scrubbe r Ven t

Intermitten t No t Specifie d 

### (4 )

+

Non e

Ye s Ye s 7 5 8 3 9 0 4 2

6 8 6



### ve p

(1 ) Approximatel y 282 5 lbs./hr . o f ligh t hydrocarbon s an d7 5 lbs./hr . o f liqui dalcohols , acid s an dketone s ar e Incinerate dI nthi s flare . (2) Combustio nproduct s estimate db y Houdr y

assumin g complet e conversio nt o C0 j an dH2 O and3 0 PP M NO xformation . (3) Approximatel y 361 0 lbs./hr . o f light hydrocarbon s an d10 0 lbs./hr . o f liqui dalcohols , acid s an dketone s ar e incinerate di nthi s flare . (4 ) Infrequen t pressur e releas e o f methan e pad . (5 ) Mostl y

methane .EP

A Cod e No . Capacit y - Ton s o f Aceti cAci d Productio n - Ton s o f Aceti cAci d Emission s t o Atmospher e Strea m No . Strea m

Flo w- Lbs./Hr . Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Compositio n Ethan e Methan e Butan e Carbon Dioxid e Carbo n Monoxid e Oxygen Nitroge n Nitroge n Oxide s Wate r Argo n Hydrocarbon s (assorted ) Aceton e Acetaldehyd e Methy l Acetat e Analysi s Sampl e Ta

p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProble m Ven tStack s Numbe r Heigh t- Ft . Diamete r- Inche s Temp. - F ° Flo w Rat e - SCF M

pe r stac k Emissio nContro l Device s Typ e - Incinerato r

Flar e Scrubbe r Summar y

o f Emission s Tota l Hydrocarbo nEmission s - Ton/To no f Aceti c Aci d Tota l Particulat e an dAerosol s - Ton/To no f Aceti c Aci d Tota l N0 X- Ton/To no f Aceti c Aci d Tota l S0 X- Ton/To no f Aceti c Aci d Tota l C O - Ton/To no t Aceti c Aci d TABL E ACA-I H NATIONA

L EMISSION S INVENTOR Y ACETI C ACID VI A BUTAN E OXIDATION
2- 1 260,00 0 260.00 0

Crud e Separatio n Column , Ventur i Scrubbe rVen t(4 )
? 0 Intermitten t No tSpecifie d

(5 )



## + +
None

Ye s Ye s 2 5 5 3 9 8 5 5

3 9 8 pag e 3 o f 3

Flu e Gas Liqui d Wast e Boiler s 49,26 7 (2 ) Continuou s

.4619 2 Storag e Tan kVent s 57. 8 Purificatio n Relie f Valv e P» 0 Intermitten t No t Specifie d

0000 4 .2635 6

Non e

(2 ) N o No t Specifie d

N o

.0391 1 0 .0000 4 0 .0115 4 .0008 7

Non e

Calculate d N o

No Non e

N o No

N o

flar e (1 ) Approximatel y 282 5 lbs./hr . o f light liydrocarbon s an d7 5 lbs./hr . o f liqui dalcohols , acid s an dketone s ar e incinerate di nth i (2 ) Combustio nproduct s estimate dh y Houdr y

assumin g complet e conversio nt o CO , an dH,0 . an

d3 0 PP M

N0 Xformation . Approximatel y

361 0 lbs./hr . o f ligh t hydrocarbon s an d10 0 lb s /h

r o f liqui dalcohols , acid s an dketone s ar e incinerate dI nthi s flar e Infrequen t pressur e releas e o f methan e pad Mostl y methane . (3 ) (4 ) (5 )

0 0TABL E ACE-i1 1 NATIONAL EMISSION S INVENTOK Y ACF.T1 C ACI D VI A ACETALDEHYD

E OXIDATIO N
EP A Plan tCod eNo . Capacit y - Ton s o f Aceti cAcid/Yr . Productio n- Ton s o i Aceti cAcid/Yr . Emission s t o Atmospher e Strea m 2 - 5 lb2.50 0 <1 > 72.00 0
Scrubbe rVen t


### Flo w - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten

t if Intermittent - Hrs./Yr . Composition- Tons/Tono f Aceti c Aci d Acetaldehyd e Ethy l Acetat e CarbonDioxide CarbonMonoxide Wate r Oxygen Nitroge n Analysi s Sampl e TapLocatio n Frequency

of Samplin

g Typ e o f Analysi s Odor Proble

m Vent Stack s Numbe r Height - F

t . Dlaaiete

r - Inche s Exi t Ga s Temp . - F ° Flo w - SCFM/Stack EmissionContro l Device s Typ e tr y o f Ai r Pollutant s Hydrocarbon s - Ton/To nAceti c Acid Particulate s - Ton/To nAceti c Aci d NO x

### - Ton/TonAceti c Aci d S O - Ton/To

nAceti c Aci d C O - Ton/To

nAceti c Acid 22,45 7 Con t i nuou s

.0048 1 .0050 2 .0708 9 .0020 2 .000 7 7 .0452 9 1.2686 9 Ye e On-strea

m t o contro l roo

m 3 tlmes/veek Ga s Chromatograp

h- Orsat N o Ye s 1 7 5 6 6 4 5 500 0 Yea Tv o Absorber s
.0098 3 0 0 0 .0020 2

( 1 ) Publishe d capacity .

C OPlan t- EP

A Cod eNo . Capacity , Ton s Aceti cAnhydride/Yr . Rang ei nProduction , 7 o f Max . Emi86ion 6 t o Atmospher e

Strea m

Flov , Lb./Hr . Flo v Characteristic , Continuou s o r Intermitten t TABL E ANA-H I NATIONA L [.MISSION S INVENTOR Y ACETI C ANHYDRID E FROM ACETI C ACI D (KETEN E ROUTE )

30,00 0 Est . Non e (live

n Fina l Scrubhe r Off-Ce o

Strea m goe s t o flar e n o comp . o f flare d ga s give n 18 0 Con t inuon s 3- 2 30,00 0 Est . Non e Give n Ta r Incinerato r Flu e Ga s

145 8 Est . Con t inuou s 30,00 0 Est . Non e Cive n Vaporise r Emergenc y Ruptur e Dis c

llnknov n Ope nonl y i nemergencie s 3- 1 425,00 0 Non e Cive n Fina l Scrubbe rOff-Ga s



### 180 0 Con ti nuou s Composition , Lb./Lh . Aceti cAnhydrid e Particulat e Carbo nDioxid e Carbo nMonoxid e Propodien e Ethylen e Methan e Wate r Ethan e Diketen e Aceti c Anhydrid e Oxyge n Nitroge n Aceti c Aci d Hydroge n Propan e Ven t Stack s Numbe r Height , Ft . Diameter , Inche s Exi t Ga s Temp . ° F SCFM/Stac k
Emissio nContro l Device s Flare/Incinerato r Absorber/Scrubbe r Analysi s Dat e o r Frequenc y

o f Samplin g Sampl e Ta pLocatio n Typ e o f Analysi s Odo r Problem Summar y

o f Ai r Pollutant s Hydrocarbon s - Lb./Lb . Aceti c Anhydrid e Aerosol s 6 . Particulate s - Lb./I.h . Aceti c Anhydrid e N0 X- Lb./Lb . Aceti c Anhydrid e SO x- Lb./Lb . Aceti c Anhydrid e C O - Lb./Lb . Aceti c Anhydrid e + 0.0040 5 0.0097 5 0.0011 2 0.0036 8 0.0027 9 0.00241 0.0001 0 0.0000 7 0.0005 0 0.0003 4 0.0013 6

N o Dat a

In e inerato r

Neve r
Calculate d N o N o Dat a 0 2 7

99.8 7

Non e

1400 " F Unknown

Incinerato r

Neve r Stac kTo p Non e No No Dat a Normall y Close d

Non e

Neve r

No t Ap p 0.00790 7 0.00814 4 0.00002 1 0.00311 3 0.00266 0
0.00008 2

0.00043 3 0.00185 6 0.000000 ? 0.00014 4 0.00175 8

7 9 0 7 5 8 6 10 0 30 0 6 0

Non e

Annuall y Sum p G.C . N o
0.00447 4 0 0 0 0.00814 4



# T* " '•>•/"«• • >IM » * m 

## ••WiPrJB ?Plan t- EP

A Cod eNo . Capacity , Ton s o f Adlpi cAcid/Yr . hverag e Production , Ton s o f Adlpi cAcid/Yr . Rang ei nProductio n- 7. o f Max . Emission s t o Atmospher e Strea m TABL H AA-Il l NATIONAL EMISSION S INVENTOR Y ADIPI C ACI D PRODUCTIO N VI A NITRI C ACI D OXIDATIO N O F CYCLOHEXANOI./CYCLOHEXANON E 5- 1 65,00 0



### Reactor Ven

t Pag e 1 o f 4

Combine d HNO 3 C«n

c 6. Pro dPurificatio

nVen t
Flo w - lbte./hr . Flo w Characteristic , Continuou s o r Intermittent i f Intermittent , hrs./yr . flo w Composition , Ton/tonof Adlpi c Aci d Nitri c Oxide NitrogenDioxide Nitrou s Oxide Nitrogen Oxygen Carbo nMonoxide CarbonDioxide Wate r Adlpi c Aci d Nitri c Aci d 779 6 Con t inuou s

.0036 3
.3384 6 .0672 6 .0153 9
.0528 6 .0021 5 Unknow n Con t inuous

0000 8

Ven t Stack s Number Height " Ft . Diamete r - Inche s Exi t Ca s Temp . - F ° SCFM/Stac k EmlsalonContro l Device s Abaorber/Scrubbe r Incinerator/Flar e Condensor/ K0 . Dru m Othe r Analysi s Dat e or Frequenc

y o f Samplin

g Ta pLocation Typ e o f Analysi s Odor Proble

m Summar y of Ai r Pollutant s Hydrocarbons , Ton/To no f Adlpi c Acid Particulates . Ton/To nof Adlpi c Aci d N0 X

### - Ton/Tono

f Adlpi c Aci d Ton/Tono f Adlpi c Aci d Ye s 1 14 0 4 2 7 0 126 0 Ye s - AA- 1 

## +

Varie s phenoldlsulfonl c Aci d N o 

# k

SO , C O Ton/Tono f Adlpi c Aci d 0 0 .0037 1 0 0 

# 4 , 

# f Ye s 1 6 3 8 11 0 Unknov n Ye s - AA- 2 +

Neve r Non e Estimat e N o

anairwin a ai A niimuodlD WTABL EAA-II l NATUINA1

. Et'ISFION T INVENTORY AIHPI C ACI D PRODUCTIO N

VI A •HTR1 C ACI D OXIDATIO NO FCYCLOHEXANOL/CYCLOHEXANON E Pag e 2 o f 4

Plan t- EP

A Cod e No

. Capacity , Ton s o f Adipi c Acid/Yr

. Averag eProduction , Ton s o f Adipi c Acid/Yr

. Rang ei nProductio n- "I. o f Max

. Emission s t o Atmospher e Strea m

Flo w - Lbs./Hr . Flo w Characteristic , Continuou s o r Intermitten t i f Intermittent , Hrs./Yr . Flo w Composition , Ton/to no f Adipi c Aci d Nitri c Oxid e Nitroge nDioxid e Nitrou s Oxid e Nitroge n Oxyge n Carbo nMonoxid e Carbo nDioxid e Wate r Adlpi c Aci d Nitri c Aci d 5- 2 2 70,00 0

Reacto r Emergenc y Ven t

• 1 2, 50 0 Intermitten t
• « 0. 1
*.0000 1 /i . 0000 1 

### *-. 0000 1 ^.0000 1
^.0000 1 

### s". 0000 1 /• . 0000 1 Reacto r Off-Ga s

556 7 Continuou s

.0000 5 .0000 8
).0756 4 

# )

.0037 6 Prod

. Purlf i Ven t
290 3 Continuou s

.0000 3 .0000 5 ).0395 4 cat l o n Adlpi c Aci d Drie r Ven t
80.96 3 Continuou s

) 1.1200 3 

## )

.0018 5 .0365 9 .0001 4 Adlpi c Aci d Melte r Ven t

222 0 Continuou s

.0317 1 •^.0000 1 -i . 0000 1 Nitri c A c i d Recover y Ven t
58,55 0 ContInuou s

.011 0 .01b 9 .297 1 .452 1 .014 1
.045 1

Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ga s Temp . - F ° SCFH/Stac k Emissio nContro l Device s Absorber/Scrubbe r Incinerator/Flar e Condenser/ KO . Dru m Othe r Analyel a Dat e o r Frequenc y o f Samplin g Ta pLocatio n Typ e o f Analysi s Odo r Proble m Summar y

o f Ai r Pollutant s Hydrocarbons , Ton/To no f Adlpi c Aci d Particulates . Ton/To no f Adlpi c Aci d NO, , Ton/To no f Adlpi c Aci d SO, , Ton/To no f Adipi c Aci d C O . Ton/To no f Adlpi c Aci d Ye s 2 10 0 2 4 17 0 100 0 N o

Neve r Non e Calc . No Ye s 2 8 0 1 2 12 0 

### ~62 5 Yea - 

## + AA- 3 Ye s 3 9 0 1 2 12 0 

### i'22 0 Ye s 

## +

Neve r
Calc . N o AA- 4

Neve r Non e Calc . N o
0 .0001 4 .030 0 0 0 Ye s - AA- 5 Ye s 2 8 5 8 18 0 "39 0 Ye s - + AA- 6

Neve r Non e Calc . o rEst . No Neve r Non e Calc . N o Ye s 1 7 5 4 8 0

N o

Accessibl e Variou s N o


# J

## : -> '

TABL E AA-II 1 NAT_IONAl^_EMISj S I ONF_I NVF.NTOR Y AP I PI C ACI D "PRODUCTIO N VI A K I 11 ' 1 r. ACI D OXIDATIO N O K(TYCI.OHEXAN01./CYCLOHKXANON E Pag e3 o f 4
Plan t- EP

A Cod eNo . Capacit y - Ton s o f Adlpi cAcid/Yr . Averag eProduction , Ton s o f Adipi cAcid/Yr . Rang ei nProductio n- 7 o f Max . Emission s t o Atmospher e Strea m

Flo w - Lbs./Hr . Flo w Characteristic , Continuou s o r Intermitten t i f intermittent . Hrs./Yr . Flo w Compositio n- Ton/To no f Adipi c Aci d Nitri c Oxid e Nitroge nDioxid e Nitrou s Oxid e Nitroge n Oxyge n Carbo nMonoxid e Carbo nDioxid e Wate r Adipi c Aci d Nitri c Aci d

Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ga s Temp . F ° SCFM/Stac k Emissio nContro l Devic e Absorber/Scrubbe r Incinerator/Flar e Condenser/ k O . Drum Othe r Analysi s Dat e o i Frequenc y o f Samplin g Sampl e Ta plocatio n Typ e o f Analysi s Odo r Proble m Summar y

o f Ai r Pollutant s Hydrocarbons , Ton/To no f Adlpi c Aci d Particulates , Ton/To no f Adlpi c Aci d N 0 X , Ton/To no f Adlpi c Aci d r.<\ , Ton/To no f Adipi c Aci d C O , Ton/To no f Adipi c Aci d Ueacto r<A ) Ven t 30,00 0 Continuou s 5 - 3 150,00 0
0
HNO 3 Recover y Ven t
5.00 0 Cont . i nuou s Prod . Purif . Ven t
V>.00 0 Cont i nuou s Pneumati c Conveyo r Ven t 13,50 0 Con tinuou s 5- 4 4 0 4 0
Proces s (B ) Ven t Heade r
559 7 Con ti nuou s 00 0

00 0 0 Adipi cAci d Drie r Ven t
4 5,lli 9 Continuou s Heav y End s Incinera to r Flu e Ga s 886 b Con ti nuou s

( .025 y .246 4 .4515 5 .0521 8

.1465 0 .0120 4 ).0001 0



# ) )1.0033 4

+ stea m

boile r ).8695 7 

# )

.0000 9

+ ba g filte r Infrequentl y
Mas s Spec
. N o Neve r Non e Calc . N o
0 .0000 9 .02 6 0 0 0 Neve r

Non e Calc . N o ).4515 5

N o

Ye s - + AA- 7 Ye s

1 6 4 3 6 183 2
Ye s 0
A A 8 Y e s

1 6 4 3 6 150 °
Ye s - AA- 9 Ye s I 6 4 3 6 15 0
Ye s AA-1 0

+ cyclon e sep .
Neve r
Estimat e N o ,0683 4 ,3627 4 .0829 9 .0004 d .0451 4

N o (C )

Ye s (C )

+

Infrequen t

GL C N o )4.4300 0

.0 8 "4 0 .0005 0

Ye s 1 3 3 1 8 16 0 10,20 0 Ye s - AA-1 1

+ cyclon e se p

Neve r Non e Estimat e N o
0 .0005 0 .00 3 0 .0004 6 .6551 b .0404 7
1113 0 .0796 8

Ye s 1 3 4 4 8 140 0 2,00 0 Ye s - AA-1 2

Neve r Non e Cal c No

V

## TABLEAA-II I pag e 4 o f 4 EXPLANATIO NO FNOTE S NATIONA LEMISSION S INVENTOR Y
ADIPI C ACI D PRODUCTION

VI A 

# NITRI C ACI D OXIDATIO NO F CYCLOHEXANONE/CYCLOHEXANO L

A ) Operato r state s tha t thi s strea mi s sen t t o boile r hous e an d use d a s 'air ' fo r burners , wher e upo n a n unknown amoun t o f NO x

# a*N 2 + O2

- Compositio n reporte d i n Tabl e II I (ton/ton ) i s base d o n assumptio n tha t N0 X

# i s reduce d b y20 % bythi s treatment
. Actua l N0 X

# concentratio n ma yincreas e o r (unde r specia l conditions ) b e reduce d b yup t o 907»

.
B ) Operato r state s tha t thi s strea mi s sen t t o HM D plan t 'therma l oxidizer 1 

# I t i s assume d tha t thi s devic e i s especiall ydesigne d fo r N0 y

# reduction

. Consequently , a NO reductio n o f 707« (whic hi s reporte d performanc e o f devic e AA-8 ) ha s bee n assume d and th e N0 X

# concentratio n reporte d i n thi s colum

n i s correspondingl ydecreased

. C ) N o ven t stac k fo r thi s strea mi n adipi c aci d plant

. Strea msen t t o therma l oxidize r i n HM D plant

.



# J autiptin g M A•uJiiuodjpv^Ja\W 

# '- 

# » ' ' mmTABLEAN-ll I NATIONALEMISSION S INVENTOR Y ADIPONITRIL E E X BUTADIEN E Pag e 1 o f 6

an tEP ACod e No

. ipaclty

. Ton s o f

Adipon i t r

i le/Y r
. ng ei nProductio n- "I o t Maximu m ilsaion s t o Atmospher e Strea m
Flo w- Lbs./Hr . Flo w Characteristic , Continuou s o r Intermitten t i f Intermittent , Hrs./Yr . - Flo w Composition , Tons/To no f Adiponitril e Propan e Nitroge n Oxyge n Carbo nMonoxid e Carbo nDioxid e Wate r

^ x Misc . Lt . H C Butadien e Chloropren e Viny l Cyclohexan e Benzen e Hydroge nChlorid e Hydroge n Methan e Ammoni a Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ga s Temp . - F ° SCFM/Stac k Ealaaio nContro l Devlce a Flare/Incinerato r Refrlg . Cond/K . 0 . Drum Abaorber/Scrubbe r Othe r Analyai a Dat e o r Frequenc y o f Samplin g Sampl e Ta pLocatio n Typ e o f Analyst s Odo r Proble m Summar y

o f Ai r Pollutant s Hydrocarbons , Ton/To no f Adiponitril e Particulates . Ton/To no f Adiponitril e NO x , Ton/To no f Adiponitril e S0„ , Ton/To no f Adiponitril e 1,700,000/Y r Intermitten t

.0053 1



### N o

Non e

Non e 6- 3 160,00 0 0 Fugitiv e Em

i ss . fro m Kefrig . Uni t Cyanid e Sect . Ven t Inclner . Flu e Ga s Chlorina t ion Sect . By-Produc t Ven t Chlorinatio n Sec t Proces s Ven t 259,93 3 Con t inuou s 'A)
4.8832 1

.5440 3 1.3347 2 .3790 3



### Ye s 

### 4 16 4 1 6

AN- 1 

### + 14 0 17 5 9 0 3 0 6. 5 6



### 9 5

AN- 2 AN- 3 + + 

### Ye s

Non e Calc'd . N o

Se e Continuatio n 65 0 Continuou s

.0135 6 .0006 9
.0036 2

Ye s 1 6 5 2 9 5 14 4 AN- 4 

## +

Cal c d . N o 8 2 Continuou s

.0007 1

.0007 0 .0008 3

Ye s I 9 0 1. 5 12 2

AN- 5

+ +



### CO Ton/To no f Adiponitril e



### T l

### TABLE AN-I U 

### r:Ain-:.Ai . EMISSION S INVENTOR Y

ADIPONITRIL E E X BUTADIEN E Paj; c 2 o f b

n t EP ACod e No
. acity , Ton s o f AdiponiIr i le/Yr

. g e i n Productio n - ) ' o f Maximu m 68ion s t o Atmospher e Strea m
Flo w- Lhs./Hr

. Flo w Characteristic , Continuou s I f Intermittent , Hrs./Yr

. Flo w Composition , Tons/To n o f Adiponitril e Propan e Nitroge n' Oxyge n Carbo nMonoxid e Carbo nDioxid e Wate r "O x Miec . Lt . H C Butadien e Chloropren e Viny l Cyclohexan e Benzen e Hydroge nChlorid e Hydroge n Methan e Ammoni a Ven t Stack a Numbe r Heigh t - Ft . Diamete r - Inche a Exi t Ca a Temp . - F ° SCFM/Stac k Emissio nContro l Device s Flare/Incinerato r Refrig . Cond/K . 0 . Dru m Abaorber /Scrubbe r Othe r Analysi s Dat e o r Frequenc y o f Samplin g Sampl e Ta pLocatio n Typ e o f Analysi s Odo r Proble m Summar y

o f Ai r Pollutant s Hydrocarbon , Ton/To n o f Adiponitril e Particulates , Ton/To n o f Adiponitril e NO , Ton/To n o f Adiponitril e S O , Ton/To no f Adiponitril e CO* . Ton/To no f Adiponitril e 6- 3 160,00 0 0 til l lo r i na t i o n Sec t
. Fug i t iv e Emission s NEmergenc yVent s

I ul erm i I I en t 3.400.00 0 Yr
. I •Hermi t t en t

.0106 2



### N o

Ca1 c ' d

. N o Chlorina t ion

. Sec t Storan e Ven t 10 0 Con t i nuou s

.0027 5

Ye s 1 9 0 8 1? 0 2 3 AN- 6 (B )

Calc'd . N o

Se e Continuatio n Chlorina t io n Sect
. Vac
. Ejecto r DiBch

. 12 4 Con t inuou s

.0028 4

.0000 8

.0001 5 .0002 2 .0000 8

Ye s 90/f ; 

### 8 '-. 120 ; 

### 2 6 : AN- 7 

### 'B )

Calc'd . N oTABL EAN-H 1 NATIONA

LEMISSION S INVENTORY ADIPONITRIL E E X BUTADIENE Pa^ e 3 o fh

n tEP ACod e No

. aclty , Ton s o f

Adipon i I rile/Yr

. g e I nProductio n- 'I o f Maximu m aslon at o Atmospher e Strea m
Flo w- Lbs./Hr

. Flo w Characteristlc , Continuou s o r Intermitten t I f Intermittent , llrs./Yr . Flo w Composition , Tons/To no f Adiponitril e Propan e Nitroge n Oxyge n Carbo nMonoxid e Carbo nDioxid e Wate r NO Mlac . Lt . H C Butadien e Chloropren e Viny l Cyclohexan e Benzen e Hydroge nChlorid e Hydroge n Methan e Ammoni a Ven t Stack a Numbe r Heigh t - Ft . Dlaawte r - In . Exi t Ga a Temp . - F ° SCm/Stac k Emissio nContro l Devlce a Flare/Incinerato r Refrig . Cond./K . 0 . Drum Abaorber/Scrubbe r Othe r Analyst s Dat e o r Frequenc y o f Samplin g Sampl e Ta pl.ocato n Typ e o f Analysi s Odo r Proble m Suaaar y

o f Ai r Pollutant s Hydrocarbons , Ton/To no f Adiponitril e Particulates , Ton/To no f Adiponitril e NO , Too/To no f Adiponitril e SO* , Ton/To no f Adiponitril e C O , Ton/To no f Adiponitril e i>- 3 lbO.OO O 0 Chlo r ina i io n Sec t i o nS t or
. Tan k Ven t 6 7 Con t i nuou s

.0018 4 Cyana t i o n6 n e I someriza t

io nC & I C 6 I C4. I C; IC& I Proces s Ven t

Proces s Ven t Proces s Ven t Ejecto r

Effl

. Proces s Ven t Proces s Ven t 78 1 Con t i nuou s

.0210 1 .0004 5 9 2

Con t i nuou s

.0002 2

.0023 0



### N o

AN- 8 (C ) 

### Ye s 

### 1 7 0 

### b 14 0 11 5 

### N o Ye s



### 1 5 5 

### 3 15 8

N o 642 9 fA )

Con t inuou s (A )

.1258 3 .0257 6 .0212 0

.0038 1

Infrequentl y


### Ve t Neve r Non e Calc' d 

### N o Neve r

Non e Calc' d 

### N o

SE E CONTINUATIO N 3 5 Con t i nuou s

0009 4 ? 3 6

Continuou s Continuou s

.0000 6



### N o .0001 3

.0008 6 C 6 I

Proces s Veu t 3 6 Cont i nuou p

.0001 3

.0008 6



### Ye s 

### 1 17 5 6. 5

AN- 3 

### + Ye s



### 1 9 0 

### 6 9 5 

### 8 AN- 9 

### Ye s



### 1 6 5 

### 2 9 5 0. 6 AN-1 0 

### Ye s



### 1 9 0 1. 5 12 2 3. 6 N o Ye s



### 1 9 0 1. 5 12 7 3. 6 N o

.. . J ,*_ia..i!U i •

### lan t EP A Cod e No
. apacity . Ton s o f Adiponitrile/Yr

. ange I n Productio n - 7 o f Maximu m mission s t o Atmospher e Strea m Flo w - Lbs. /Mr . Flo w Characteristic , Continuou s o r Intermitten t I f Intermittent , Urs./Yr

. - Flow Composition , Tons/To n o f Adiponitril e Propane Nitrogen OaTfge n CarbonMonoxide CarbonDioxid

e Wate r N0 X 

### Misc . Lt . H

C Butadiene

- Chloroprene Viny l Cyclohexane Benzene HydrogenChlorid

e Hydrogen Methane Ammoni a Ven t Stack s Numbe r Height - Ft . Diamete r - Inche s Exi t Ga s Temp . - F ° SCFM/Stac k EmissionContro l Device s Flare/incinerator Refrlg . Cood./K . 0 . Dru m Abaorber/Scrubbe r Othe r Analysi s Dat eo rFrequenc y o f Samplin g Sampl e Tap Locatio n Typ eo f Analysi s Odo rProble m Summar y o f Ai rPollutant s Hydrocarbons , Ton/To n o fAdiponitril e Particulates , Ton/To n o fAdiponitril e N O , Ton/To n o fAdiponitril e c f , l Vac . E jec

t o r I nsch . 1 1 5 Con t i nuou s NA T 1DNA1

C i . 1 Proces s 5 8 TABL E AN-ll I



### EMISSION S INVENTOR

Y ADIPONITRIL E E X BUTADIEN E
6- 3 160,00 0 0

C 6 I Ven t Proces s Vent

9 2 Continuou s Continuou s C 6 1 Proces s Ven t 135 3 Con t inuou s F

a ^e . 4 o f 6

C 6 . 1 Proces s Ven t 9 2 Con t inuou s C & I Tan k Vent s 5 Con t inuou s "Bm m 

## & i H Tan k Ven t H^ H



# • Continuou s ^ H



### 0031 b ..0015 9 .0371 8

. 0000 9

.0002 2

.0023 0 .0002 2

0073 0

N o

No N o

AN-1 1 (D ) Ye s



## I 2 5 

## 3 15 8

No Ye s 1 3 0 2 10 4 30 6 AN-1 2 <D ) Ye s 1 2 5 3 15 8

N o . 0000 3

N o .0000 2

.0001 6

No

No

SE ECONTINUATIO N 

### S O CO Ton/Tonof Adiponitril e Ton/To nof Adiponitril e



# -~*afMi HTABL EAN-11 1 NATIONA

LEMISSION S INVENTORY ADIPONITRIL E E X BUTADIEN E I'an e 5 o f 6 [an tEP A Cod e No

. Ipacity , Ton s o f

Adiponitr i le/Yr

. •ng e i nProductio n- / o t Maximu m Mission s t o Atmospher e Strea m
Flo w - Lbs. /Hr . Flow Characteristic , Continuou s o r Intermitten t i f Intermittent , Urs./Yr

. - Flo w Composition , Tons/To n o f Adiponitril e Propan e Nitroge n Oxyge n Carbo nMonoxid e Carbo nDioxid e Wate r N0 K Mlac . Lt . H C Butadien e Chloropren e Viny l Cyclohexan e Benzen e Hydroge nChlorid e Hydroge n Methan e Ammoni a Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ga s Temp . - K ° SCFM/Stac k Emissio nContro l Device s Flare/Incinerato r Refrig . Cond./K

. 0

. Dru m Abaorber/Scrubbe r .Othe r Analysi s Dat eo rFrequenc y o f Samplin g Sampl eTa p Locatio n Typ eo f

Analysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbons , Ton/To no f Adiponitril e Particulates . Ton/To no f Adiponitril e N O , Ton/To no l Adiponitril e S O , Ton/To no f

Adiponitril e CO , Ton/To no f

Adiponitril e 6- 3 160,00 0 0 llydrof-ena t

io n Uni t Proces s Ven t 24 1 Con t i nuou s Hydrogen s 1 io n Un i t Ejecto r Discharg e 

### 38 4 Continuou s

.0105 4

.0018 0 .004 7 7 .0000 4 N o



### N o No

.0256 4 .0038 5 .4002 3



## piay3jdjpv• * •IMXuodipv 

# J

### P.2 0



# TABL E AN-II I NATIONA L EMISSION S INVENTOR Y ADIPONITRIL E E X BUTADIEN

E
EXPLANATIO

N O F NOTE S Page 6 of 6
(A ) Responden t reporte dcompositio

no f strea

m prior t o combustion . Combustio n product s estimate

db y Houdry . (B ) Device s AN- 6 an dAN- 7 bot hconsis t o f thre e identica l scrubbers . (C ) Devic e AN- 8 consist s o f sixidentica l scrubbers . (D ) Device s AN-1 1 an dAN-1 2 consis t o f tw o identica l scrubbers .

> a . •5 ' 

## o 3 

## 5 * 

## < 5 * 

## > a. •3 ' 0 ° 

# > i

# - J

TABL E AL-I H

n tEP A Cod e No . acity . Ton s o f

Adiponitrile/Y r. ig e i nProductio n- 'I o f Max. salon s t o Atmospher e Strea m Flo w- Lhs./Hr . Flo w Characteristic , Continuou s o r Intermitten t I f Intermittent , llrs./Yr . Flo w Composition , Tons/To no f Adiponitril e Ammoni a Nitroge n Oxyge n Carbo nDioxid e Wate r Nitroge nOxide s

Ven t Stack s Numbe r Heigh t - F

t . Diamete r - Inche s Exi t Ga a Temp . - F " SCFM/Stac k Emissio nContro l Device s Flar e / 1 ti

c In e ra t o r Abaorbar/Scrubbe r Condenser/K . 0 . Drum Othe r Analyal s Dat e o r Frequenc y o f Samplin g Sampl e Ta pLocatio n Typ e o f Analyal s Odo r Proble m Summar y

o f Ai r Pollutant s Hydrocarbons . Aeroaol a NO, , S 0 X C O Ton/To no f Adiopnitril e Nll- j Recover v Sec tio n Purj; e ? 0 Con tinuou s (A l

+



### + .0018 5 .00027 4 NAI'IONAI

6- 1 13.75 0 0 . EMISSION S INVENTOR Y ADIPONITRIL E E X ADIPI C ACI D

Ligh tEnd s In e inerato r IIu e Ga s 49,51 0 Con ti nuou s

10.9770 6 2.3309 8 .b009 6 .4916 9 +
(Flare )

196 8 Ven t GL C No Ye s 1 1 3 5 7 180 0 11.00 0 Ye s AL- 1 +

Neve r
Calc'd . N o
0 0 .00027 4 0 0 NH- j Recover y Sec t io n Ven t 20 9 Con t inuou s

.0097 8

Ye s 1 7 7 4 77 ° 

### ~3 0 Ye s AL- 2

Neve r Non e Es t imat e N o 6- 2 90,00 0 0 Produc t Purlfica t io

n Ven t "Trace " Con t i nuou s

Ye s 1 7 7 5 212 °

N o

Neve r Non e Estimat e N o
0 .0035 6 0 0 0 Produc t Recover y

Electo r Discharg e 138 0 Continuou s

.0035 6 ) 013 3 

## 1

.0444 4

Ye s 1 12 0 2 21 ? 42 0 N o

Neve r Non e Estimat e N o

A ) Assume dcombustio nproducts . R.sp. : J.M. I repor : > . b y assumin g 10 0 nercin l combustio nandii'i i porce m ..

. - i n doppositio no f stra r prio r l o o<mhus t ii- n(i nflare) , conversio n» 1 containe dnitroge nt o N0 Xvil hmol . vt . o f 40 . Combustio nproduct s wer e estimate d

X I 

### h o