13339 Hagers Ferry Road

Huntersville, NC 28078-7929

McGuire Nuclear Complex - MG03A2

Phone: 980-875-5245 Fax: 980-875-4349

Order Summary Report

Analytical Laboratory

Order Number: J11120297

Lab Contact: Jason C Perkins

Date: 1/17/2012

Customer Address: 253 Plant Allen Road

Customer Name(s): BILL KENNEDY, RON LAWS, ALLEN STOWE, DONNA BURRELL, GREG PHIL

Belmont, NC 28012

Phone: 980-875-5348

Report Authorized By:

(Signature)

Program Comments:

Please contact the Program Manager (Jason C Perkins) with any questions regarding this report.

Data Flags & Calculations:

Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality 

system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) 

under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted.

Data Package:

This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of 

the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except 

in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The 

order of individual sections within this report is as follows:

Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, 

Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & 

Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)

Certification:

The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina 

(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of 

specific methods. 

Analytical Laboratory 

Page 1 of 57
Sample ID's & Descriptions:

Sample ID Plant/Station

Collection 

Date and Time Collected By Sample Description

2011027219 ALLEN 15-Dec-11 8:57 AM JBW FGD Purge Eff 

2011027221 ALLEN 15-Dec-11 9:08 AM JBW BioReactor 1 Inf 

2011027222 ALLEN 15-Dec-11 9:01 AM JLD/BS BioReactor 1 Inf BLANK 

2011027223 ALLEN 15-Dec-11 9:13 AM JBW BioReactor 2 Eff 

2011027224 ALLEN 15-Dec-11 9:04 AM JLD/BS BioReactor 2 Eff BLANK 

2011027225 ALLEN 14-Dec-11 9:00 AM CW FILTER PRESS SLUDGE CAKE 

2011027226 ALLEN 15-Dec-11 11:39 AM JBW Filter Blk 

7 Total Samples

Analytical Laboratory 

Page 2 of 57
COC and .pdf report are in agreement with sample totals 

and analyses (compliance programs and procedures).

All Results are less than the laboratory reporting limits.

All laboratory QA/QC requirements are acceptable.

The Vendor Laboratories have been qualified by the 

Analytical Laboratory

Yes No

Technical Validation Review

Checklist:

Yes No

Yes No

Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results

Sample Identification Customer Specific Data Sheets, Reports, & Documentation

Technical Validation of Data Package Customer Database Entries

Analytical Laboratory Certificate of Analysis

Analytical Laboratory QC Report

Chain of Custody

Reviewed By: DataBase Administrator Date: 1/17/2012

Yes

Electronic Data Deliverable (EDD) Sent Separately

Analytical Laboratory 

Page 3 of 57
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J11120297

2011027219

Collection Date: 15-Dec-11 8:57 AM

Site: FGD Purge Eff 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

ALKALINITY (FIXED END POINT 4.5)

Vendor Parameter COMPLETE V_PRISM

Carbonate, Bicarbonate, and Hydroxide Alkalinity

Bicarbonate (HCO3) COMPLETE V_PRISM

Carbonate (CO3) COMPLETE V_PRISM

Hydroxide (OH) COMPLETE V_PRISM

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) 130 mg-N/L 1 EPA 353.2 21-Dec-11 10:24 BGN9034

INORGANIC IONS BY IC

Bromide 45 mg/L 0.1 EPA 300.0 28-Dec-11 17:22 JAHERMA

Chloride 2700 mg/L 0.1 EPA 300.0 28-Dec-11 17:22 JAHERMA

Sulfate 2400 mg/L 0.1 EPA 300.0 28-Dec-11 17:22 JAHERMA

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) 162 ug/L 0.05 EPA 245.1 22-Dec-11 08:12 AGIBBS

Mercury Dissolved (cold vapor) in Water (Filtered)

Mercury (Hg) 85.0 ug/L 0.05 EPA 245.1 22-Dec-11 11:10 AGIBBS

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 266 mg/L 0.05 EPA 200.7 29-Dec-11 15:04 SLS2560

Calcium (Ca) 2140 mg/L 0.01 EPA 200.7 29-Dec-11 15:04 SLS2560

Cobalt (Co) 0.089 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Lithium (Li) 0.351 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Magnesium (Mg) 1510 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Potassium (K) 79.4 mg/L 0.1 EPA 200.7 29-Dec-11 15:04 SLS2560

Sodium (Na) 55.8 mg/L 0.05 EPA 200.7 29-Dec-11 15:04 SLS2560

DISSOLVED METALS BY ICP-MS

Selenium (Se) 2530 ug/L 10 EPA 200.8 20-Dec-11 10:55 MHH7131

Analytical Laboratory 

Page 4 of 57
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J11120297

2011027219

Collection Date: 15-Dec-11 8:57 AM

Site: FGD Purge Eff 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) 8.52 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Arsenic (As) 185 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Beryllium (Be) 10.3 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Cadmium (Cd) 3.89 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Chromium (Cr) 222 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Copper (Cu) 127 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Lead (Pb) 153 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Nickel (Ni) 250 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Selenium (Se) 2000 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Silver (Ag) < 1 ug/L 1 EPA 200.8 29-Dec-11 14:00 DJSULL1

Zinc (Zn) 230 ug/L 2 EPA 200.8 29-Dec-11 14:00 DJSULL1

SELENIUM SPECIATION

Vendor Parameter COMPLETE V_AS&C

TOTAL DISSOLVED SOLIDS

Vendor Parameter COMPLETE V_PRISM

TOTAL SUSPENDED SOLIDS

TSS 3000 mg/L 5 SM2540D 22-Dec-11 11:30 TJA7067

2011027221

Collection Date: 15-Dec-11 9:08 AM

Site: BioReactor 1 Inf 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

ALKALINITY (FIXED END POINT 4.5)

Vendor Parameter COMPLETE V_PRISM

Carbonate, Bicarbonate, and Hydroxide Alkalinity

Hydroxide (OH) COMPLETE V_PRISM

Carbonate (CO3) COMPLETE V_PRISM

Bicarbonate (HCO3) COMPLETE V_PRISM

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) 100 mg-N/L 1 EPA 353.2 21-Dec-11 10:27 BGN9034

INORGANIC IONS BY IC

Bromide 60 mg/L 0.1 EPA 300.0 28-Dec-11 17:37 JAHERMA

Chloride 2800 mg/L 0.1 EPA 300.0 28-Dec-11 17:37 JAHERMA

Sulfate 2100 mg/L 0.1 EPA 300.0 28-Dec-11 17:37 JAHERMA

Analytical Laboratory 

Page 5 of 57
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J11120297

2011027221

Collection Date: 15-Dec-11 9:08 AM

Site: BioReactor 1 Inf 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

MERCURY 1631 - DISSOLVED

Vendor Parameter COMPLETE V_BRAND

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) 87.7 ug/L 0.05 EPA 245.1 22-Dec-11 08:15 AGIBBS

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 217 mg/L 0.05 EPA 200.7 29-Dec-11 15:04 SLS2560

Calcium (Ca) 1880 mg/L 0.01 EPA 200.7 29-Dec-11 15:04 SLS2560

Cobalt (Co) < 0.005 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Lithium (Li) 0.147 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Magnesium (Mg) 1150 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Potassium (K) 29.5 mg/L 0.1 EPA 200.7 29-Dec-11 15:04 SLS2560

Sodium (Na) 50.6 mg/L 0.05 EPA 200.7 29-Dec-11 15:04 SLS2560

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) 1.94 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Arsenic (As) 1.57 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Beryllium (Be) 1.87 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Cadmium (Cd) < 1 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Chromium (Cr) 50.4 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Copper (Cu) < 1 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Lead (Pb) < 1 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Nickel (Ni) 2.20 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Selenium (Se) 2030 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Silver (Ag) < 1 ug/L 1 EPA 200.8 29-Dec-11 14:04 DJSULL1

Zinc (Zn) < 2 ug/L 2 EPA 200.8 29-Dec-11 14:04 DJSULL1

SELENIUM SPECIATION

Vendor Parameter COMPLETE V_AS&C

2011027222

Collection Date: 15-Dec-11 9:01 AM

Site: BioReactor 1 Inf BLANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

MERCURY 1631

Vendor Parameter COMPLETE V_BRAND

Analytical Laboratory 

Page 6 of 57
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J11120297

2011027223

Collection Date: 15-Dec-11 9:13 AM

Site: BioReactor 2 Eff 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

ALKALINITY (FIXED END POINT 4.5)

Vendor Parameter COMPLETE V_PRISM

Carbonate, Bicarbonate, and Hydroxide Alkalinity

Carbonate (CO3) COMPLETE V_PRISM

Hydroxide (OH) COMPLETE V_PRISM

Bicarbonate (HCO3) COMPLETE V_PRISM

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) 10 mg-N/L 0.1 EPA 353.2 21-Dec-11 10:29 BGN9034

INORGANIC IONS BY IC

Bromide 73 mg/L 0.1 EPA 300.0 28-Dec-11 17:53 JAHERMA

Chloride 2400 mg/L 0.1 EPA 300.0 28-Dec-11 17:53 JAHERMA

Sulfate 2700 mg/L 0.1 EPA 300.0 28-Dec-11 17:53 JAHERMA

MERCURY 1631

Vendor Parameter COMPLETE V_BRAND

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) < 0.05 ug/L 0.05 EPA 245.1 22-Dec-11 08:17 AGIBBS

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 141 mg/L 0.05 EPA 200.7 29-Dec-11 15:04 SLS2560

Calcium (Ca) 1660 mg/L 0.01 EPA 200.7 29-Dec-11 15:04 SLS2560

Cobalt (Co) < 0.005 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Lithium (Li) 0.140 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Magnesium (Mg) 950 mg/L 0.005 EPA 200.7 29-Dec-11 15:04 SLS2560

Potassium (K) 45.6 mg/L 0.1 EPA 200.7 29-Dec-11 15:04 SLS2560

Sodium (Na) 45.5 mg/L 0.05 EPA 200.7 29-Dec-11 15:04 SLS2560

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) 12.9 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Arsenic (As) 3.34 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Beryllium (Be) 2.53 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Cadmium (Cd) < 1 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Chromium (Cr) < 1 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Copper (Cu) < 1 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Lead (Pb) < 1 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Nickel (Ni) 1.26 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Selenium (Se) 7.84 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Silver (Ag) 2.74 ug/L 1 EPA 200.8 29-Dec-11 13:44 DJSULL1

Zinc (Zn) < 2 ug/L 2 EPA 200.8 29-Dec-11 13:44 DJSULL1

Analytical Laboratory 

Page 7 of 57
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J11120297

2011027223

Collection Date: 15-Dec-11 9:13 AM

Site: BioReactor 2 Eff 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

SELENIUM SPECIATION

Vendor Parameter COMPLETE V_AS&C

2011027224

Collection Date: 15-Dec-11 9:04 AM

Site: BioReactor 2 Eff BLANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

MERCURY 1631

Vendor Parameter COMPLETE V_BRAND

2011027225

Collection Date: 14-Dec-11 9:00 AM

Site: FILTER PRESS SLUDGE CAKE 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

METALS ANALYSIS BY VENDOR LAB

Vendor Parameter COMPLETE V_PACE

2011027226

Collection Date: 15-Dec-11 11:39 AM

Site: Filter Blk 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

DISSOLVED METALS BY ICP-MS

Selenium (Se) < 1 ug/L 1 EPA 200.8 20-Dec-11 10:55 MHH7131

The 1631 Hg bottles were not labeled. There was no smell to any of the samples. No analysis was performed.

-- Additional Information --

Analytical Laboratory 

Page 8 of 57
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample 

Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed 

according to the referenced methods. 

Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case 

narrative.

NC Certification No. 402

SC Certification No. 99012

NC Drinking Water Cert No. 37735

Case Narrative

12/27/2011

Duke Energy Corporation (04)

Jay Perkins

13339 Hagers Ferry Road

Huntersville, NC 28078

Project: HAPS/MACT Testing Allen

Project No.: J11120297

Lab Submittal Date: 12/16/2011

Prism Work Order: 1120514

Please call if you have any questions relating to this analytical report.

Respectfully,

PRISM LABORATORIES, INC.

VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:

HT Sample received and analyzed outside of the hold time.

MDL Method Detection Limit

BRL Below Reporting Limit

RPD Relative Percent Difference

*

Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and 

reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 8

Analytical Laboratory 

Page 9 of 57
Sample Receipt Summary

12/27/2011

Prism Work Order: 1120514

Client Sample ID Lab Sample ID Matrix Date Sampled Date Received

2011027219/FGD Purge Eff 1120514-01 Water 12/15/11 12/16/11

2011027221/BioReactor 1 Inf 1120514-02 Water 12/15/11 12/16/11

2011027223/BioReactor 2 Eff 1120514-03 Water 12/15/11 12/16/11

Samples received in good condition at 2.3 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 8

Analytical Laboratory 

Page 10 of 57
Laboratory Report

12/27/2011

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Duke Energy Corporation (04) Project: HAPS/MACT Testing Allen

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 1120514-01

Prism Work Order: 1120514

Time Collected: 12/15/11 08:57

Time Submitted: 12/16/11 17:05

2011027219/FGD Purge Eff

J11120297

General Chemistry Parameters

pH 7.0 HT pH Units 1 *SM4500-H B 12/20/11 10:30 JAB P1L0466

Total Alkalinity 72 mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0529

Carbonate Alkalinity BRL mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0530

Bicarbonate Alkalinity 72 mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0531

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 8

Analytical Laboratory 

Page 11 of 57
Laboratory Report

12/27/2011

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Duke Energy Corporation (04) Project: HAPS/MACT Testing Allen

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 1120514-02

Prism Work Order: 1120514

Time Collected: 12/15/11 09:08

Time Submitted: 12/16/11 17:05

2011027221/BioReactor 1 Inf

J11120297

General Chemistry Parameters

pH 7.6 HT pH Units 1 *SM4500-H B 12/20/11 10:30 JAB P1L0466

Total Alkalinity 94 mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0529

Carbonate Alkalinity BRL mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0530

Bicarbonate Alkalinity 94 mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0531

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 8

Analytical Laboratory 

Page 12 of 57
Laboratory Report

12/27/2011

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Duke Energy Corporation (04) Project: HAPS/MACT Testing Allen

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 1120514-03

Prism Work Order: 1120514

Time Collected: 12/15/11 09:13

Time Submitted: 12/16/11 17:05

2011027223/BioReactor 2 Eff

J11120297

General Chemistry Parameters

pH 7.5 HT pH Units 1 *SM4500-H B 12/20/11 10:30 JAB P1L0466

Total Alkalinity 180 mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0529

Carbonate Alkalinity BRL mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0530

Bicarbonate Alkalinity 180 mg/L 5.0 1.4 1 *SM2320 B 12/22/11 11:15 JAB P1L0531

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 8

Analytical Laboratory 

Page 13 of 57
12/27/11

Level II QC Report

13339 Hagers Ferry Road Project No: J11120297

Duke Energy Corporation (04) Project: HAPS/MACT Testing Allen

Huntersville, NC 28078

Attn: Jay Perkins

Prism Work Order: 1120514

Time Submitted: 12/16/2011 5:05:00PM

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

General Chemistry Parameters - Quality Control

Batch P1L0466 - NO PREP

LCS (P1L0466-BS1) Prepared & Analyzed: 12/20/11 

pH 6.86 pH Units 6.860 100 99-101

Batch P1L0529 - NO PREP

Blank (P1L0529-BLK1) Prepared & Analyzed: 12/22/11 

Total Alkalinity BRL 5.0 mg/L

LCS (P1L0529-BS1) Prepared & Analyzed: 12/22/11 

Total Alkalinity 256 5.0 mg/L 250.0 102 90-110

LCS Dup (P1L0529-BSD1) Prepared & Analyzed: 12/22/11 

Total Alkalinity 257 5.0 mg/L 250.0 103 90-110 0.4 200

Batch P1L0530 - NO PREP

Blank (P1L0530-BLK1) Prepared & Analyzed: 12/22/11 

Carbonate Alkalinity BRL 5.0 mg/L

LCS (P1L0530-BS1) Prepared & Analyzed: 12/22/11 

Carbonate Alkalinity 256 5.0 mg/L 90-110

LCS Dup (P1L0530-BSD1) Prepared & Analyzed: 12/22/11 

Carbonate Alkalinity 257 5.0 mg/L 90-110 0.4 200

Batch P1L0531 - NO PREP

Blank (P1L0531-BLK1) Prepared & Analyzed: 12/22/11 

Bicarbonate Alkalinity BRL 5.0 mg/L

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 8

Analytical Laboratory 

Page 14 of 57
12/27/11

Level II QC Report

13339 Hagers Ferry Road Project No: J11120297

Duke Energy Corporation (04) Project: HAPS/MACT Testing Allen

Huntersville, NC 28078

Attn: Jay Perkins

Prism Work Order: 1120514

Time Submitted: 12/16/2011 5:05:00PM

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

General Chemistry Parameters - Quality Control

Batch P1L0531 - NO PREP

LCS (P1L0531-BS1) Prepared & Analyzed: 12/22/11 

Bicarbonate Alkalinity 256 5.0 mg/L 250.0 102 90-110

LCS Dup (P1L0531-BSD1) Prepared & Analyzed: 12/22/11 

Bicarbonate Alkalinity 257 5.0 mg/L 250.0 103 90-110 0.4 200

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 8

Analytical Laboratory 

Page 15 of 57

January 12, 2012

LIMS USE: FR - TERRY WHITNER

LIMS OBJECT ID: 92109838

92109838

Project:

Pace Project No.:

RE:

Terry Whitner

Duke Energy Carolinas, LLC

PO Box 37929

DPEHS

Charlotte, NC 28237

J11120297

Dear Terry Whitner:

Enclosed are the analytical results for sample(s) received by the laboratory on January 09, 2012.

The results relate only to the samples included in this report. Results reported herein conform to the

most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless

otherwise noted in the body of the report.

Analyses were performed at the Pace Analytical Services location indicated on the sample analyte

page for analysis unless otherwise footnoted.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Kevin Herring

kevin.herring@pacelabs.com

Project Manager

Enclosures

cc: Mr. Jay Perkins, Duke Energy

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 1 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 17 of 57
CERTIFICATIONS

Pace Project No.:

Project:

92109838

J11120297

Asheville Certification IDs

2225 Riverside Dr., Asheville, NC 28804

Florida/NELAP Certification #: E87648

Massachusetts Certification #: M-NC030

North Carolina Drinking Water Certification #: 37712

North Carolina Wastewater Certification #: 40

South Carolina Certification #: 99030001

Virginia Certification #: 00072

West Virginia Certification #: 356

Virgina/VELAP Certification #: 460147

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 2 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 18 of 57
SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

92109838

J11120297

Lab ID Sample ID Method

Analytes

Analysts Reported Laboratory

92109838001 FGD PURGE EFF SM 2540C SMW 1 PASI-A

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 3 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 19 of 57
HITS ONLY

Pace Project No.:

Project:

92109838

J11120297

Parameters Result Analyzed

Lab Sample ID 

Method Units Report Limit Qualifiers

Client Sample ID

92109838001 FGD PURGE EFF

SM 2540C Total Dissolved Solids 10500 mg/L 500 01/11/12 15:08 H1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 4 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 20 of 57
PROJECT NARRATIVE

Pace Project No.:

Project:

92109838

J11120297

Method:

Client: Duke Energy

SM 2540C

Date: January 12, 2012

Description: 2540C Total Dissolved Solids

General Information:

1 sample was analyzed for SM 2540C. All samples were received in acceptable condition with any exceptions noted below.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

H1: Analysis conducted outside the EPA method holding time.

• FGD PURGE EFF (Lab ID: 92109838001)

Method Blank:

All analytes were below the report limit in the method blank with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Duplicate Sample:

All duplicate sample results were within method acceptance criteria with any exceptions noted below.

Additional Comments:

This data package has been reviewed for quality and completeness and is approved for release.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 5 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 21 of 57
ANALYTICAL RESULTS

Pace Project No.:

Project:

92109838

J11120297

Sample: FGD PURGE EFF Lab ID: 92109838001 Collected: 12/15/11 08:57 Received: 01/09/12 16:30 Matrix: Water

Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual

2540C Total Dissolved Solids Analytical Method: SM 2540C

Total Dissolved Solids 10500 mg/L 500 1 01/11/12 15:08 H1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 01/12/2012 04:31 PM Page 6 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 22 of 57
QUALITY CONTROL DATA

Pace Project No.:

Project:

92109838

J11120297

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

WET/19291

SM 2540C

SM 2540C

2540C Total Dissolved Solids

Associated Lab Samples: 92109838001

Parameter Units

Blank

Result

Reporting

Limit Qualifiers

METHOD BLANK: 708975

Associated Lab Samples: 92109838001

Matrix: Water

Analyzed

Total Dissolved Solids mg/L ND 25.0 01/11/12 15:07

Parameter Units

LCS

Result

% Rec

Conc. % Rec Limits Qualifiers

LABORATORY CONTROL SAMPLE: 708976

Spike LCS

Total Dissolved Solids mg/L 250 244 98 80-120

Parameter Units

Dup

Result Result RPD Qualifiers

92109939002

SAMPLE DUPLICATE: 708997

Total Dissolved Solids mg/L 295 268 10

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 01/12/2012 04:31 PM Page 7 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 23 of 57
QUALIFIERS

Pace Project No.:

Project:

92109838

J11120297

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of

the sample aliquot, or moisture content.

ND - Not Detected at or above adjusted reporting limit.

J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.

MDL - Adjusted Method Detection Limit.

S - Surrogate

1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate)

MS(D) - Matrix Spike (Duplicate)

DUP - Sample Duplicate

RPD - Relative Percent Difference

NC - Not Calculable.

SG - Silica Gel - Clean-Up

U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for

each analyte is a combined concentration.

Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

LABORATORIES

PASI-A Pace Analytical Services - Asheville

ANALYTE QUALIFIERS

H1 Analysis conducted outside the EPA method holding time.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 01/12/2012 04:31 PM Page 8 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 24 of 57
QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

92109838

J11120297

Lab ID Sample ID QC Batch Method QC Batch Analytical Method

Analytical

Batch

92109838001 FGD PURGE EFF SM 2540C WET/19291

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 01/12/2012 04:31 PM Page 9 of 9

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 25 of 57
December 27, 2011

LIMS USE: FR - TERRY WHITNER

LIMS OBJECT ID: 92108666

92108666

Project:

Pace Project No.:

RE:

Terry Whitner

Duke Energy Carolinas, LLC

PO Box 37929

DPEHS

Charlotte, NC 28237

J11120297

Dear Terry Whitner:

Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2011.

The results relate only to the samples included in this report. Results reported herein conform to the

most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless

otherwise noted in the body of the report.

Analyses were performed at the Pace Analytical Services location indicated on the sample analyte

page for analysis unless otherwise footnoted.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Bonnie McKee for

Kevin Herring

kevin.herring@pacelabs.com

Project Manager

Enclosures

cc: Mr. Jay Perkins, Duke Energy

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 1 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 26 of 57
CERTIFICATIONS

Pace Project No.:

Project:

92108666

J11120297

Asheville Certification IDs

2225 Riverside Dr., Asheville, NC 28804

Florida/NELAP Certification #: E87648

Massachusetts Certification #: M-NC030

North Carolina Drinking Water Certification #: 37712

North Carolina Wastewater Certification #: 40

South Carolina Certification #: 99030001

Virginia Certification #: 00072

West Virginia Certification #: 356

Virgina/VELAP Certification #: 460147

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 2 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 27 of 57
SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

92108666

J11120297

Lab ID Sample ID Method

Analytes

Analysts Reported Laboratory

92108666001 2011027225 EPA 6010 JMW 7 PASI-A

EPA 7470 SHB 1 PASI-A

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 3 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 28 of 57
HITS ONLY

Pace Project No.:

Project:

92108666

J11120297

Parameters Result Analyzed

Lab Sample ID 

Method Units Report Limit Qualifiers

Client Sample ID

92108666001 2011027225

EPA 7470 Mercury 0.31 ug/L 0.20 12/27/11 11:37

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 4 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 29 of 57
PROJECT NARRATIVE

Pace Project No.:

Project:

92108666

J11120297

Method:

Client: Duke Energy

EPA 6010

Date: December 27, 2011

Description: 6010 MET ICP, TCLP

General Information:

1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Sample Preparation:

The samples were prepared in accordance with EPA 3010 with any exceptions noted below.

Initial Calibrations (including MS Tune as applicable):

All criteria were within method requirements with any exceptions noted below.

Continuing Calibration:

All criteria were within method requirements with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Duplicate Sample:

All duplicate sample results were within method acceptance criteria with any exceptions noted below.

Additional Comments:

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 5 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 30 of 57
PROJECT NARRATIVE

Pace Project No.:

Project:

92108666

J11120297

Method:

Client: Duke Energy

EPA 7470

Date: December 27, 2011

Description: 7470 Mercury, TCLP

General Information:

1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Sample Preparation:

The samples were prepared in accordance with EPA 7470 with any exceptions noted below.

Initial Calibrations (including MS Tune as applicable):

All criteria were within method requirements with any exceptions noted below.

Continuing Calibration:

All criteria were within method requirements with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Duplicate Sample:

All duplicate sample results were within method acceptance criteria with any exceptions noted below.

Additional Comments:

This data package has been reviewed for quality and completeness and is approved for release.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Page 6 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 31 of 57
ANALYTICAL RESULTS

Pace Project No.:

Project:

92108666

J11120297

Sample: 2011027225 Lab ID: 92108666001 Collected: 12/14/11 09:00 Received: 12/16/11 10:39 Matrix: Solid

Results reported on a "dry-weight" basis

Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual

6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010

Leachate Method/Date: EPA 1311; 12/22/11 17:40

Arsenic ND mg/L 0.025 1 12/23/11 11:20 12/26/11 14:34 7440-38-2

Barium ND mg/L 0.50 1 12/23/11 11:20 12/26/11 14:34 7440-39-3

Cadmium ND mg/L 0.0050 1 12/23/11 11:20 12/26/11 14:34 7440-43-9

Chromium ND mg/L 0.025 1 12/23/11 11:20 12/26/11 14:34 7440-47-3

Lead ND mg/L 0.025 1 12/23/11 11:20 12/26/11 14:34 7439-92-1

Selenium ND mg/L 0.10 1 12/23/11 11:20 12/26/11 14:34 7782-49-2

Silver ND mg/L 0.025 1 12/23/11 11:20 12/26/11 14:34 7440-22-4

7470 Mercury, TCLP Analytical Method: EPA 7470 Preparation Method: EPA 7470

Leachate Method/Date: EPA 1311; 12/22/11 17:40

Mercury 0.31 ug/L 0.20 1 12/23/11 15:04 12/27/11 11:37 7439-97-6

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 12/27/2011 04:13 PM Page 7 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 32 of 57
QUALITY CONTROL DATA

Pace Project No.:

Project:

92108666

J11120297

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

MERP/3945

EPA 7470

EPA 7470

7470 Mercury TCLP

Associated Lab Samples: 92108666001

Parameter Units

Blank

Result

Reporting

Limit Qualifiers

METHOD BLANK: 704135

Associated Lab Samples: 92108666001

Matrix: Water

Analyzed

Mercury ug/L ND 0.20 12/27/11 11:32

Parameter Units

LCS

Result

% Rec

Conc. % Rec Limits Qualifiers

LABORATORY CONTROL SAMPLE: 704136

Spike LCS

Mercury ug/L 2.5 3.0 120 80-120

Parameter Units

MS

Result

% Rec

Conc. % Rec Limits Qualifiers

MATRIX SPIKE SAMPLE: 704137

Spike MS

Result

92108590001

Mercury ug/L ND 2.5 3.0 119 75-125

Parameter Units

Dup

Result Result RPD Qualifiers

92108846001

SAMPLE DUPLICATE: 704138

Mercury ug/L ND ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 12/27/2011 04:13 PM Page 8 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 33 of 57
QUALITY CONTROL DATA

Pace Project No.:

Project:

92108666

J11120297

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

MPRP/9645

EPA 3010

EPA 6010

6010 MET TCLP

Associated Lab Samples: 92108666001

Parameter Units

Blank

Result

Reporting

Limit Qualifiers

METHOD BLANK: 704107

Associated Lab Samples: 92108666001

Matrix: Water

Analyzed

Arsenic mg/L ND 0.025 12/26/11 14:00

Barium mg/L ND 0.50 12/26/11 14:00

Cadmium mg/L ND 0.0050 12/26/11 14:00

Chromium mg/L ND 0.025 12/26/11 14:00

Lead mg/L ND 0.025 12/26/11 14:00

Selenium mg/L ND 0.10 12/26/11 14:00

Silver mg/L ND 0.025 12/26/11 14:00

Parameter Units

LCS

Result

% Rec

Conc. % Rec Limits Qualifiers

LABORATORY CONTROL SAMPLE: 704108

Spike LCS

Arsenic mg/L 2.5 2.6 104 80-120

Barium mg/L 2.5 2.3 93 80-120

Cadmium mg/L 2.5 2.3 93 80-120

Chromium mg/L 2.5 2.4 95 80-120

Lead mg/L 2.5 2.2 88 80-120

Selenium mg/L 2.5 2.6 105 80-120

Silver mg/L 1.2 1.3 102 80-120

Parameter Units

MS

Result

% Rec

Conc. % Rec Limits Qualifiers

MATRIX SPIKE SAMPLE: 704109

Spike MS

Result

92108590001

Arsenic mg/L ND 2.5 2.6 103 75-125

Barium mg/L 2.0 2.5 4.2 90 75-125

Cadmium mg/L ND 2.5 2.4 96 75-125

Chromium mg/L 0.042 2.5 2.5 97 75-125

Lead mg/L ND 2.5 2.3 92 75-125

Selenium mg/L ND 2.5 2.5 101 75-125

Silver mg/L ND 1.2 1.3 100 75-125

Parameter Units

Dup

Result Result RPD Qualifiers

92108590002

SAMPLE DUPLICATE: 704110

Arsenic mg/L 0.018J ND

Barium mg/L 0.066J .064J

Cadmium mg/L 0.0036J .0034J

Chromium mg/L 0.28 0.28 2

Lead mg/L ND ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 12/27/2011 04:13 PM Page 9 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 34 of 57
QUALITY CONTROL DATA

Pace Project No.:

Project:

92108666

J11120297

Parameter Units

Dup

Result Result RPD Qualifiers

92108590002

SAMPLE DUPLICATE: 704110

Selenium mg/L 0.020J ND

Silver mg/L ND ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 12/27/2011 04:13 PM Page 10 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 35 of 57
QUALIFIERS

Pace Project No.:

Project:

92108666

J11120297

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of

the sample aliquot, or moisture content.

ND - Not Detected at or above adjusted reporting limit.

J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.

MDL - Adjusted Method Detection Limit.

S - Surrogate

1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate)

MS(D) - Matrix Spike (Duplicate)

DUP - Sample Duplicate

RPD - Relative Percent Difference

NC - Not Calculable.

SG - Silica Gel - Clean-Up

U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for

each analyte is a combined concentration.

Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

LABORATORIES

PASI-A Pace Analytical Services - Asheville

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 12/27/2011 04:13 PM Page 11 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 36 of 57
QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

92108666

J11120297

Lab ID Sample ID QC Batch Method QC Batch Analytical Method

Analytical

Batch

92108666001 2011027225 EPA 3010 MPRP/9645 EPA 6010 ICP/8908

92108666001 2011027225 EPA 7470 MERP/3945 EPA 7470 MERC/3873

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Date: 12/27/2011 04:13 PM Page 12 of 12

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Analytical Laboratory 

Page 37 of 57
 

December 27, 2011 

Jay Perkins 

Duke Energy Analytical Laboratory 

Mail Code MGO3A2 (Building 7405) 

13339 Hagers Ferry Rd. 

Huntersville, NC 28078 

(704) 875-5245 

Project: HAPS/MACT Testing Allen (LIMS # J11120297) 

Dear Mr. Perkins, 

Attached is the report associated with three (3) aqueous samples submitted for selenium 

speciation analysis on December 19, 2011. The samples were received in a sealed cooler at -

0.2°C on December 20, 2011. Selenium speciation analysis was performed via ion 

chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICPDRC-MS). Any issues associated with the analysis are addressed in the following report. 

If you have any questions, please feel free to contact me at your convenience. 

 Sincerely, 

 

 Russell Gerads 

 Vice President 

 Applied Speciation and Consulting, LLC 

 

Analytical Laboratory 

Page 38 of 57
Applied Speciation and Consulting, LLC 

Report prepared for: 

Jay Perkins 

Duke Energy Analytical Laboratory 

Mail Code MGO3A2 (Building 7405) 

13339 Hagers Ferry Rd. 

Huntersville, NC 28078 

Project: HAPS/MACT Testing Allen (LIMS # J11120297) 

December 27, 2011 

1. Sample Reception 

Three (3) aqueous samples in 125mL HDPE bottles (provided by Applied Speciation and 

Consulting) were submitted for selenium speciation analysis on December 19, 2011. The 

samples were received on December 20, 2011 in a sealed container at -0.2°C. 

The samples were received in a laminar flow clean hood, void of trace metals contamination 

and ultra-violet radiation, and was designated a discrete sample identifier. An aliquot of each 

sample was filtered (0.45μm) and each filtrate was stored in a secure, monitored cryofreezer 

(maintained at a temperature of -80oC) until selenium speciation analysis could be performed 

via ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry 

(IC-ICP-DRC-MS). 

2. Sample Preparation 

All sample preparation is performed in laminar flow clean hoods known to be free from trace 

metals contamination. All applied water for dilutions and sample preservatives are 

monitored for contamination to account for any biases associated with the sample results. 

Selenium Speciation Analysis by IC-ICP-DRC-MS Prior to analysis, an aliquot of each 

sample was filtered with a syringe filter (0.45μm) and injected directly into a sealed 

autosampler vial. No further sample preparation was performed as any chemical alteration of 

a sample may shift the equilibrium of the system, resulting in changes in speciation ratios. 

3. Sample Analysis 

All sample analysis is preceded by a minimum of a five-point calibration curve spanning the 

entire concentration range of interest. Calibration curves are performed at the beginning of 

Analytical Laboratory 

Page 39 of 57
each analytical day. All calibration curves, associated with each species of interest, are 

standardized by linear regression resulting in a response factor. All sample results are 

instrument blank corrected to account for any operational biases associated with the 

analytical platform. 

Prior to sample analysis, all calibration curves are verified using second source standards 

which are identified as initial calibration verification standards (ICV). 

Ongoing instrument performance is identified by the analysis of continuing calibration 

verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval 

of every ten analytical runs. 

Selenium Speciation Analysis by IC-ICP-DRC-MS Each sample for selenium speciation 

analysis was analyzed by ion chromatography inductively coupled plasma dynamic reaction 

cell mass spectrometry (IC-ICP-DRC-MS) on December 20, 2011. An aliquot of each

sample is injected onto an anion exchange column and mobilized by a basic (pH > 7) 

gradient. The eluting selenium species are then introduced into a radio frequency (RF) 

plasma where energy-transfer processes cause desolvation, atomization, and ionization. The 

ions are extracted from the plasma through a differentially-pumped vacuum interface and 

travel through a pressurized chamber (DRC) containing a specific reactive gas which 

preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A 

solid-state detector detects ions transmitted through the mass analyzer and the resulting 

current is processed by a data handling system. 

Retention times for each eluting species are compared to known standards for species 

identification. 

4. Analytical Issues 

The overall analyses went well and no significant analytical issues were encountered. All 

quality control parameters associated with this sample were within acceptance limits. 

The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are 

generated from replicate analyses of the lowest standard in the calibration curve. Not all 

selenium species are present in preparation blanks; therefore, eMDL calculations based on 

preparation blanks are artificially biased low. 

The eMDL for methylseleninic acid and selenomethionine is calculated from the average 

eMDL of selenite, selenate, and selenocyanate. The calibration does not contain 

methylseleninic acid or selenomethionine due to impurities in these standards which would 

bias the results for other selenium species. 

Analytical Laboratory 

Page 40 of 57
If you have any questions or concerns regarding this report, please feel free to contact me. 

Sincerely, 

Russell Gerads 

Vice President 

Applied Speciation and Consulting, LLC 

Analytical Laboratory 

Page 41 of 57
Sample Results

Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe

Unknown Se 

Species (n)

FGd Purge Eff ND (<4.6) 1760 ND (<3.8) ND (<4.0) ND (<4.0) 0 (0)

BioReactor 1 Inf 3.8 1370 ND (<0.96) ND (<1.0) ND (<1.0) 4.1 (1)

BioReactor 2 Eff 2.5 1.18 ND (<0.96) ND (<1.0) ND (<1.0) 0 (0)

All results reflect the applied dilution and are reported in μg/L

ND = Not detected at the applied dilution

SeCN = Selenocyanate

MeSe(IV) = Methylseleninic acid

SeMe = Selenomethionine

Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS

n = number of unknown Se species observed

Report Generated by: Russell Gerads

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: HAPS/MACT Testing Allen

Contact: Jay Perkins

Date: December 27, 2011

LIMS #J11120297

Analytical Laboratory 

Page 42 of 57
Quality Control Summary - Preparation Blank Summary

Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 50x eMDL 200x

Se(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.023 1.1 4.6

Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.018 0.89 3.6

SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.019 0.96 3.8

MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.020 1.0 4.0

SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.020 1.0 4.0

eMDL = Estimated Method Detection Limit

*Please see narrative regarding eMDL calculations

Quality Control Summary - Certified Reference Materials

Analyte (μg/L) CRM True Value Result Recovery

Se(IV) LCS 9.57 9.08 94.9

Se(VI) LCS 9.48 9.15 96.5

SeCN LCS 8.92 8.65 97.0

MeSe(IV) LCS 6.47 5.76 89.0

SeMe LCS 9.32 8.66 93.0

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: HAPS/MACT Testing Allen

Contact: Jay Perkins

LIMS #J11120297

Date: December 27, 2011

Report Generated by: Russell Gerads

Analytical Laboratory 

Page 43 of 57
Quality Control Summary - Matrix Duplicates

Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD

Se(IV) BioReactor 2 Eff 2.5 3.5 3.0 33.0*

Se(VI) BioReactor 2 Eff 1.18 ND (<0.89) NC NC

SeCN BioReactor 2 Eff ND (<0.96) ND (<0.96) NC NC

MeSe(IV) BioReactor 2 Eff ND (<1.0) ND (<1.0) NC NC

SeMe BioReactor 2 Eff ND (<1.0) ND (<1.0) NC NC

ND = Not detected at the applied dilution

NC = Value was not calculated due to one or more concentrations below the eMDL

*Sample concentration is within 10x the eMDL

Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate

Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD

Se(IV) BioReactor 2 Eff 278.0 229.9 82.7 278.0 229.9 82.7 0.0

Se(VI) BioReactor 2 Eff 252.3 211.5 83.9 252.3 210.4 83.4 0.5

SeCN BioReactor 2 Eff 228.8 186.8 81.7 228.8 183.7 80.3 1.7

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: HAPS/MACT Testing Allen

Contact: Jay Perkins

LIMS #J11120297

Date: December 27, 2011

Report Generated by: Russell Gerads

Analytical Laboratory 

Page 44 of 57
Analytical Laboratory 

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December 28, 2011

Duke Energy

ATTN: Jay Perkins

Scientific Support-Laboratory

13339 Hagers Ferry Road

Huntersville NC 28078

jcperkins@duke-energy.com

labcustomer@duke-energy.com

RE: Project DUK-HV1101 Client Project: J11120279

Dear Mr. Perkins,

On December 16, 2011, Brooks Rand Labs (BRL) received three (3) wastewater samples and

three (3) corresponding field blanks. Samples were logged-in for total and dissolved mercury

(Hg) analysis, resulting in twelve (12) samples for analysis. All samples were received, 

prepared, analyzed, and stored according to BRL SOPs and EPA methodology.

For the sample identified as 1st Stage Effluent, there was a discrepancy between the total Hg 

result (sample 1151040-05) and the dissolved Hg result (sample 1151040-06). The total Hg was 

reported to be 39.1 ng/L, while the dissolved Hg was reported to be 110 ng/L. Both of these 

results were confirmed through re-analysis. This same trend was noted with 1st Stage Effluent 

and 2nd Stage Effluent samples reported in BRL work order 1151026 (Duke Project J11120237); 

however, this issue was not noted in previous work orders for samples received on December 9 

and 15, 2011. A follow up e-mail will be issued discussing this unexpected occurrence. 

The results were blank-corrected as described in the calculations section of the applicable 

SOP(s) and may be evaluated using adjusted reporting limits to account for sample aliquot size. 

Please refer to the Sample Results page for sample-specific detection limits and other details. 

BRL, an accredited laboratory, certifies the reported results of all analyses for which BRL is 

NELAP accredited meet all NELAP requirements. For more details, see the Report Information

page of the report. Sample results equal to or less than the MDL were reported at the MDL and 

qualified U. All data was reported without further qualification and all associated quality control 

sample results met the acceptance criteria.

Please feel free to contact us if you have any questions regarding this report.

Sincerely,

 Misty Kennard-Mayer Michelle L. Briscoe

Business Development Manager VP of Analytical Services

misty@brooksrand.com michelle@brooksrand.com

Analytical Laboratory 

Page 46 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Definition of Data Qualifiers

(Effective 9/23/09)

Laboratory Accreditation

BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida 

Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is 

also certified by many other states to perform environmental analyses. For a current list of our 

accreditations/certifications, please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results 

reported relate only to the samples listed in the report.

Report Information

BLK

BRL

BS

CAL

CCV

CRM

D

DUP

ICV

MSD

ND

NR

PS

REC

RPD

RSD

SCV

SOP

method blank 

Brooks Rand Labs

laboratory fortified blank

calibration standard

continuing calibration verification

certified reference material

dissolved fraction

duplicate

initial calibration verification

matrix spike duplicate

non-detect

non-reportable

post preparation spike

percent recovery

relative percent difference

relative standard deviation

secondary calibration verification

standard operating procedure

MDL

MRL

MS

method detection limit

method reporting limit

matrix spike

SRM

T

COC

standard reference material

total recoverable fraction

chain of custody record 

Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand, Ltd ., those found in the EPA SOW ILM03.0, 

Exhibit B, Section III, pg. B-18, and the USEPA Laboratory Data Validation Functional Guidelines for Evaluating Inorganic 

Analyses; USEPA; July 2002. These supersede all previous qualifiers ever employed by BRL.

B Detected by the instrument, the result is > the MDL but ≤ the MRL. Result is reported and considered an estimate.

E An estimated value due to the presence of interferences. A full explanation is presented in the narrative.

H Holding time and/or preservation requirements not met. Result is estimated.

J Estimated value. A full explanation is presented in the narrative.

J-M Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated.

J-N Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated.

M Duplicate precision (RPD) was not within acceptance criteria. Result is estimated.

N Spike recovery was not within acceptance criteria. Result is estimated.

R Rejected, unusable value. A full explanation is presented in the narrative.

U Result is ≤ the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL.

X Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. 

Result is estimated.

Field Quality Control Samples

Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type 

and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be 

done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field 

quality control samples.

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 47 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Sample Information

Sample Lab ID Report Matrix Type Sampled Received

BioReactor Influent 1151040-01 Influent Sample 12/14/2011 12/16/2011

BioReactor Influent 1151040-02 Influent Sample 12/14/2011 12/16/2011

BioReactor Influent Hg Blk 1151040-03 DIW Field Blank 12/14/2011 12/16/2011

BioReactor Influent Hg Blk 1151040-04 DIW Field Blank 12/14/2011 12/16/2011

1st Stage Effluent 1151040-05 Effluent Sample 12/14/2011 12/16/2011

1st Stage Effluent 1151040-06 Effluent Sample 12/14/2011 12/16/2011

1st Stage Effluent Hg Blk 1151040-07 DIW Field Blank 12/14/2011 12/16/2011

1st Stage Effluent Hg Blk 1151040-08 DIW Field Blank 12/14/2011 12/16/2011

2nd Stage Effluent 1151040-09 Effluent Sample 12/14/2011 12/16/2011

2nd Stage Effluent 1151040-10 Effluent Sample 12/14/2011 12/16/2011

2nd Stage Effluent Blk 1151040-11 DIW Field Blank 12/14/2011 12/16/2011

2nd Stage Effluent Blk 1151040-12 DIW Field Blank 12/14/2011 12/16/2011

Batch Summary

Analyte Lab Matrix Method Prepared Analyzed Batch Sequence

Hg Water EPA 1631 12/19/2011 12/20/2011 B112132 1100906

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 48 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Sample Results

Sample Analyte Report Matrix Fraction Result Qualifier MDL MRL Unit Batch Sequence

1st Stage Effluent

1151040-05 Hg Effluent T 39.1 3.03 8.08 ng/L B112132 1100906

1151040-06 Hg Effluent D 110 0.30 0.79 ng/L B112132 1100906

1st Stage Effluent Hg Blk

1151040-07 Hg DIW T 0.15 U 0.15 0.40 ng/L B112132 1100906

1151040-08 Hg DIW D 0.15 U 0.15 0.40 ng/L B112132 1100906

2nd Stage Effluent

1151040-09 Hg Effluent T 24.7 1.52 4.04 ng/L B112132 1100906

1151040-10 Hg Effluent D 23.5 0.15 0.41 ng/L B112132 1100906

2nd Stage Effluent Blk

1151040-11 Hg DIW T 0.15 U 0.15 0.40 ng/L B112132 1100906

1151040-12 Hg DIW D 0.15 U 0.15 0.41 ng/L B112132 1100906

BioReactor Influent

1151040-01 Hg Influent T 430 15.2 40.4 ng/L B112132 1100906

1151040-02 Hg Influent D 165 0.60 1.59 ng/L B112132 1100906

BioReactor Influent Hg Blk

1151040-03 Hg DIW T 0.15 U 0.15 0.40 ng/L B112132 1100906

1151040-04 Hg DIW D 0.15 U 0.15 0.40 ng/L B112132 1100906

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 49 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Accuracy & Precision Summary

Batch: B112132

Analyte Native Spike Result Units REC & Limits RPD & Limits

Method: EPA 1631

Lab Matrix: Water

Sample

B112132-SRM1 Certified Reference Material (1149037, NIST 1641d 1000x dilution)

Hg 15.68 15.29 ng/L 98% 85-115

B112132-MS2 Matrix Spike (1151039-03)

Hg 102.3 505.1 664.3 ng/L 111% 71-125

B112132-MSD2 Matrix Spike Duplicate (1151039-03)

Hg 102.3 505.1 648.2 ng/L 108% 71-125 242%

B112132-MS3 Matrix Spike (1151039-05)

Hg 39.35 177.4 228.6 ng/L 107% 71-125

B112132-MSD3 Matrix Spike Duplicate (1151039-05)

Hg 39.35 180.9 226.1 ng/L 103% 71-125 241%

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 50 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Method Blanks & Reporting Limits

Batch: B112132

Method: EPA 1631

Matrix: Water

Analyte: Hg

Sample Result Units

B112132-BLK1 0.06 ng/L

B112132-BLK2 0.08 ng/L

B112132-BLK3 0.06 ng/L

B112132-BLK4 0.04 ng/L

Average: 0.06 Standard Deviation: 0.02 MDL: 0.15

Limit: 0.50 Limit: 0.10 MRL: 0.40

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 51 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Instrument Calibration

Sequence: 1100906

Instrument: THG-10 Method: EPA 1631

Date: 12/20/2011

Total Mercury and Mercury Speciation by CVAFS

Analyte: Hg

Lab ID True Value Result Units REC & Limits

1100906-IBL1 3.72 pg of Hg

1100906-IBL2 3.49 pg of Hg

1100906-IBL3 3.46 pg of Hg

1100906-IBL4 4.98 pg of Hg

1100906-CAL1 25.00 24.38 pg of Hg 98%

1100906-CAL2 100.0 98.22 pg of Hg 98%

1100906-CAL3 500.0 482.6 pg of Hg 97%

1100906-CAL4 2500 2687 pg of Hg 107%

1100906-CAL5 10000 10100 pg of Hg 101%

1100906-ICV1 1568 1529 pg of Hg 98% 85-115

1100906-CCB1 6.98 pg of Hg

1100906-CCV1 500.0 532.2 pg of Hg 106% 77-123

1100906-CCV2 500.0 515.4 pg of Hg 103% 77-123

1100906-CCV3 500.0 514.5 pg of Hg 103% 77-123

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 52 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Sample Containers

Lab ID: 1151040-01 Report Matrix: Influent

Sample: BioReactor Influent Sample Type: Sample Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-02 Report Matrix: Influent

Sample: BioReactor Influent Sample Type: Sample Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-03 Report Matrix: DIW

Sample: BioReactor Influent Hg Blk Sample Type: Field Blank Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-04 Report Matrix: DIW

Sample: BioReactor Influent Hg Blk Sample Type: Field Blank Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-05 Report Matrix: Effluent

Sample: 1st Stage Effluent Sample Type: Sample Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-06 Report Matrix: Effluent

Sample: 1st Stage Effluent Sample Type: Sample Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 53 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Sample Containers

Lab ID: 1151040-07 Report Matrix: DIW

Sample: 1st Stage Effluent Hg Blk Sample Type: Field Blank Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-08 Report Matrix: DIW

Sample: 1st Stage Effluent Hg Blk Sample Type: Field Blank Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-09 Report Matrix: Effluent

Sample: 2nd Stage Effluent Sample Type: Sample Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-10 Report Matrix: Effluent

Sample: 2nd Stage Effluent Sample Type: Sample Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-11 Report Matrix: DIW

Sample: 2nd Stage Effluent Blk Sample Type: Field Blank Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

Lab ID: 1151040-12 Report Matrix: DIW

Sample: 2nd Stage Effluent Blk Sample Type: Field Blank Received: 12/16/2011

Collected: 12/14/2011

Des Container Size Lot Preservation P-Lot pH Ship. Cont.

A 71470160

10

Bottle FLPE Hg-T 250 mL none n/a Cooler

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

Page 54 of 57
Project ID: DUK-HV1101

PM: Tiffany Stilwater

Client PM: Jay Perkins

 Client PO: 141391

Shipping Containers

Cooler

Tracking No: 4726 7966 6868 via FedEx

Temperature: 1.7 °C

Coolant Type: Ice

Description: Cooler

Damaged in transit? No

Returned to client? No

Custody seals present? No

Custody seals intact? No

COC present? Yes

Received: December 16, 2011 9:00

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

Analytical Laboratory 

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Analytical Laboratory 

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Analytical Laboratory 

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