p.1 

OAR Box 1384 

Prepped by Charmelle Mathews 

Document Number: 

'2&fi ll-E-197 

Docket Number: 

A-94-52 

Printed 7/2/2008 8:42:11 AM Sheet 237of 264 
P-2 

DEC.29.199B"" 15 4BPH ARE! LOBBY -NO.bbfc ydtd 

From: 

Date: 

Contact: 

Company: 

Contact Report 

Shawn McKee, Pacific Environmental Services, IncLl^ES):TM 

November 12,1998 and December 9,1998 \~ 

Mr. Clyde Richey 

A.R.E.,Inc. 

~7C-E- \C\<\ 

j '"*'•' .'.lH!Jnrj(::j' 

Telephone Number. (330) 830-4500 ext.211 

Fax Numben (330)830-4545 

Contact Summary: 

Mr. Clyde Richey was contacted to update information previously provided by A.R.E., 

Inc. in regards to the usage of tooling resins for mold-making at their Mount Eaton and MassiUon 

facilities. In response to my questions Mr. Richey indicated the following: 

TotUtXo Q£?r' rC5tf4G> 

The Mount Eaton facilitynases/two resins in tiieir mold-making process: Ashland Aropol 

AME 5000B and Ashland LD 1192-27'OG ACC. The Ashland Aropol AME 5000B has a 

hazardous air pollutant (HAP) content of 31 % by weight as supplied. The Ashland LB 1192 27 •• 

tt 5^0^ * SG ACG has a HAP content of-36% by weight as supplied. Ashland Aropol G^5406 resin is no 

longer used. i V/.7%> i ^ l LB fl92.-2.7-SG, 4 e** ) 

W 

gsri/fta-re- /W^*M<- USAGE'- A/xesoooB- ?73/ y ^//$2O?-5S/K C -a <t3.£3Q-&-

The two resins still in use are combined to achieve a harder finished product. 

Approximately twenty percent ofthe tooling resin application is done by hand lay up, and eighty 

percent is done by mechanical spray-up. A filler is added to the resin. Mr. Richey did not have 

information on the ratio of resin use. pf possible please indicate what the ratio is.] 

,i<fi-D FOA TooUAJG &£*'** AprQUCJlT'otJ 

There is currentlyJieHc control device'at the Mount Eaton facility. There is a control 

device at the MassiUon facility. Aff ^missions are vented through the control device. No tooling 

resin is used at the MassiUon facility, but some tooling gel coat is used for mold repairs. 

INFORMATION IS ACCURATE. 

c?J^^l?«Jff '&*/& 
P.3 

DEC.29.199B 1:46PM ARE LOBBY NO.656 P.1 

BSE The Top Line For Your Truck 

400Nav9RdSE 

P.O. Box //OO 

MassiUon, OH 44648-0802 

Office 330430-4500 

Fax 330-830-4545 

COMPANY HAMS 

ATTSffTlON: 

FAX NUMBER: 

STf/sW*; /#c £.££- DATs 

/*-/jd9/9mP 

PHONE NUMBER 

QURGBNT Ejtep'yASAP/ \J Please Comment/ Q Please Review/ \\£ For your Information/ 

Tctal pages, including caver sheet: 

I 

COMMENTS: \mmm_ 

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ULL.ir.iyyt i y^lH H HKt LUtitiT 

P.4 

nu.D^r • r. 3 

MATERIAL SAFETY OATA SHEET 

Ashland Chemical Co., 

AROPOL C 5406 ACC GP 

page OOI 

Date Prepared: 07/17/97 

Date Printed: 07/19/97 

MSDS No: 0238404-004.001 

1 . CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Material Identity 

Product Name: AROPOL C 5406 ACC GP 

General or Generic ID: UNSATURATED POLYESTER RESIN 

Company 

Ashland Chemical Co. 

P.O. Box 2219 

Columbus, OH 43216 

614-790-3333 

Emergency Telephone Number: 

1-900-ASHLAND (1-800-274-5263) 

24 hours everyday 

Regulatory Information Number: 

1-800-325-3751 

2 . COMPOSITION/INFORMATION ON INGREDIENTS 

ingredient(s) CAS Number % (by weight) 

STYRENE 

POLYESTER RESIN 

100-42-5 

Trade Secret 

42.0- 42.0 

53.0- 58.0 

3. HAZARDS IDENTIFICATION 

Potential Health Effects 

Eye 

Skin 

Can cause eye irritation. Symptoms include stinging/ tearing, redness, and 

swelling of eyes. 

Can cause skin irritation. Prolonged or repeated contact may dry the skin. 

Symptoms may include redness/ burning, and drying and cracking of skin, burns 

and other skin damage. Passage of this material into the body through the skin 

is possible, but it is unlikely that this would result in harmful effects 

during safe handling and use. 

Swallowing 

Single dose oral toxicity is low. swallowing small amounts during normal 

handling is not likely to cause harmful effects; swallowing large amounts may 

be harmful. This material can enter the. lungs during swallowing or vomiting 

and cause lung inflammation and/or damage. 

Inhalation 

Breathing of vapor or mist is possible. Exposure to aerosol and/or mist is 

possible when material is sprayed. Aerosol and mist may present a greater risk 

of injury because more matenal may be present in the air than from vapor 

alone. Short-term inhalation toxicity is low. Breathing small amounts during 

normal handling is not likely to cause harmful effects; breathing large amounts 

may be harmful. Symptoms are more typically seen at air concentrations 

exceeding the recommended exposure limits. 

Symptoms of Exposure 

metallic taste, gastrointestinal irritation (nausea, vomiting, diarrhea), 

irritation (nose, throat, respiratory tract), central nervous system (CNS) 

depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, 

unconsciousness) and other CNS effects, impaired coordination, confusion, liver 

damage. 

Continued on next page 

O 
DtC.lV.iyyb y:*dlHH HKL LUBBY i*iu.-x>r r.q 

MATERIAL SAFETY DATA SHEET 

Ashland Chemical Co. Page 002 , , .... # 

Date Prepared: 07/17/97 •" \ 

Date Printed: 07/19/97 ' 3 

MSDS No: 0238404-004*001 

AROPOL C 5406 ACC GP 

Target Organ Effects 

Overexposure to this material (or its components) has been suggested as a cause 

of the following effects in laboratory animals, and may aggravate pre-existing 

disorders of these organs in humans: mild, reversible kidney effects, effects 

on hearing, respiratory tract damage (nose, throat, and airways), testis damage 

liver damage, overexposure to this material (or its components) has been 

suggested as a cause of the following effects in humans, and may aggravate 

pre-existing disorders of these organs: central nervous system effects, mild . 

effects on color vision, effects on hearing, respiratory tract damage (nose, 

throat, and airways) 

Developmental Information 

This, material (or a component) has been shown to cause harm to the fetus in 

laboratory animal studies. Harm to the fetus occurs only at exposure levels 

that harm the pregnant animal. The relevance of these findings to humans is 

uncertain. 

Cancer Information 

In 1993, the International Agency for Research on cancer (IARC) classified 

styrene in group 2B (possibly carcinogenic to humans). IARC concluded that 

there was no convincing evidence for carcinogenic action of styrene in animals 

based on the animal studies which existed at that time. Rather, the IARC 2B 

listing was based on data for styrene oxide, a metabolite of styrene. Two 

recent lifetime studies with styrene, one in rats and one in mice, have been 

completed since the 1993 review. There was no increase in cancer in 

styrene-exposed rats. However, there was an increase in lung cancer in 

styrene-exposed mice. The relevance of the mouse lung cancer to humans is 

uncertain. Styrene exposure has not been associated with an Increased 

incidence of cancer in workers including those in the reinforced plastics and 

composites plastics industries. 

Other Health Effects 

Styrene readily reacts with low concentrations of halogens (for example, 

fluorine, chlorine, bromine, or iodine) to form a tear-producing substance. 

Primary Route(s) of Entry 

Inhalation, Skin absorption, Skin contact, Eye contact. 

4. FIRST AID MEASURES 

Eyes 

If symptoms develop, immediately move individual away from exposure and into 

fresh air. .Flush eyes gently with water for at least 15 minutes while holding 

eyelids apart; seek immediate medical attention. 

Skin 

Remove contaminated clothing. Flush exposed area with large amounts of water. 

If skin is damaged, seek immediate medical attention. If skin is not damaged 

and symptoms persist, seek medical attention. Launder clothing before reuse. 

Swallowing 

Do not induce vomiting. This material is an aspiration hazard. If individual 

is drowsy or unconscious, place on left side with the h«ad down. Seek medical 

attention. If possible, do not leave individual unattended. 

Continued on next page 

4 
UtL.17.iyy b y-e^HN HKL LUBBY 

P6 

MATERIAL SAFETY DATA SHEET 

Ashland Chemical Co. ' Page 003 

Date Prepared; 07/17/97 

Date Printed: 07/19/97 

MSDS No: 0238404-004.001 

AROPOL C 5406 ACC GP 

Inhalation 

If symptoms develop, move individual away from exposure and into fresh air. If 

symptoms persist, seek medical attention. If breathing is difficult, 

administer oxygen. Keep person warm and quiet; seek immediate medical 

attention. 

Note to Physicians 

This material is an aspiration hazard, potential danger from aspiration must 

be weighed against possible oral toxicity (See Section 3 - Swallowing) when 

deciding whether to induce vomiting. Preexisting disorders of the following 

organs (or organ systems) may be aggravated by exposure to this material: 

respiratory tract, skin, lung- (for example, asthma-like conditions), liver, 

central•nervous system, male reproductive system, auditory system. 

•""-----«^--| -*"""""""", ---^i*WI""""""""-^^i^^l *-"""-, ^--^«*---""""""-^^"^-*"«^------^"^iTM^«TMi«»ii^^^^iW^^^i«^pTMi^^ 

5. FIRE FIGHTING MEASURES 

Flash Point 

73.0 - 100.0 F (22.7 - 37.7 C) 

Explosiv e Limit 

(for component) Lower 1.1 Upper 6.1 % •*. 

Autoignitio n Temperature 

No data 

Hazardous Products of Combustion 

May form: carbon, dioxide and carbon monoxide, various hydrocarbons. 

Fire and Explosion Hazards 

vapors are heavier than air arid may travel along the ground or may be moved by 

ventilation and ignited by pilot lights, other flames, sparks, heaters,, 

smoking, electric motors, static discharge, or other ignition sources at 

locations distant from material handling point. Never use welding or cutting 

torch on or near drum (even empty) because product (even just residue)' can 

ignite explosively. 

Extinguishing Media 

regular foam, water fog, carbon-dioxide, dry chemical. 

Fire Fighting Instructions 

Wear a self-contained breathing apparatus with a full facepiece operated in the 

positive pressure demand mode with appropriate turn-out gear and chemical 

resistant personal protective equipment. Refer to the personal protective 

equipment section of this MSDS. Polymerization will take place under fire 

conditions. If polymerization occurs in a closed container, there is a 

possibility -it will rupture violently. Cool storage container with water, if 

exposed to fire. 

NFPA Rating 

Health - 2, Flammability - 3, Reactivity - 1 

6. • ACCIDENTAL RELEASE MEASURES 

Small Spill 

Absorb liquid on vermiculite, floor absorbent, or other absorbent material and 

transfer' tb hood. 

Continued on next page 

5 
DEC.17.199B 3-EZm HRE LOBBY P.7 

NU.ssr r.bMATERIAL SAFETY DATA SHEET 

Ashland Chemical Co. Page 004 

Date Prepared: 07/17/97 

Date Printed: 07/19/97 

MSDS No: 0238404-004.001 

AROPOL C 5406 ACC GP 

Large Spill 

Eliminate all ignition sources (flares, flames including pilot lights, 

electrical sparks). Persons not wearing protective equipment should be excluded 

from area of spill until clean-up has been completed, stop spill at source. 

Prevent from entering drains, sewers, streams or other bodies of water. 

Prevent from spreading. If runoff occurs, notify authorities as required. 

Pump or vacuum transfer spilled product to clean containers for recovery. 

Absorb unrecoverable product. Transfer contaminated absorbent, soil and other 

materials to containers for disposal. 

7. HANDLING AND STORAGE 

Handling 

Containers of this material may be hazardous when emptied*. Since emptied 

containers retain product residues (vapor, liquid, and/or solid), all hazard 

precautions given in the data sheet must be observed. All five-gallon pails 

and larger metal containers, including tank cars and tank trucks, should be 

grounded and/or bonded when material is transferred. 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Eye Protection 

Chemical splash goggles in compliance with OSHA regulations are advised; 

however, OSHA regulations also permit other type safety glasses. Consult your 

safety representative. 

Skin Protection 

Wear resistant gloves such as: polyvinyl alcohol,-Wear normal work clothing 

covering arms and legs 

Respiratory Protections 

If workplace exposure limit(s) of product or any component is exceeded (see 

exposure guidelines), a NIOSH/MSHA approved air supplied respirator is advised 

in absence of proper environmental control. OSHA regulations also permit other 

NIOSH/MSHA respirators (negative pressure type)-under specified conditions (see 

your industrial hygiehist). Engineering or administrative controls should be 

implemented to reduce exposure. 

Engineering Controls 

Provide sufficient mechanical (general and/or local exhaust) ventilation to 

• maintain-exposure below TLV(s). 

Exposure Guidelines 

Component 

STYRENE (100-42-5) 

OSHA V.PEL 50.000 ppm - TWA - (see below) 

PSHA VPEL 425.000 mg/m3 - STEL 

OSHA VPEL 100.000 ppm - STEL 

ACGIH TLV 20.000 ppm - TVA (Skin) 

ACGIH TLV 40.000 ppm - STEL (Skin) 

POLYESTER RESIN ' 

No exposure limits established 

Continued on next page 

io 
' P.8 

ULL.ir.iyyb y:dciHn HKL LUtitiY 

IIU . oo f r.( 

MATERIAL SAFETY DATA SHEET 

Ashland Chemical Co. Page 005 

Date Prepared: 07/17/97 ! 

Date printed: 07/19/97 ' 

MSDS No: 0238404-004.001 

AROPOL C 5406 ACC GP 

OSHA has formally endorsed a styrene industry proposal for a voluntary 50 ppm 

workplace limit on styrene. Members of the Styrene Information and Research 

Council (SIRC), Composites Institute (Cl), Composite Fabricators Association 

(CFA), International Cast Polymers Association (ICPA) and National Marine 

Manufacturers Association (NMMA) have agreed to use either engineering 

. controls, work practices or respiratory protection to achieve this voluntary 

limit for .styrene. OSHA plans to enforce this voluntary workplace exposure 

limit in these industries. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Boiling Point 

(for.component) 293.4 F (145.2 C) @ 760 mmHg 

Vapor Pressure 

(for component) 4.500 mmHg @ 68.00 j 

Specific Vapor Density 

3.600 @ AIR*=1 . 

Specific Gravity ;• 

1.051 - 1.0S9 @ 77.00 F 

Liquid Density 

8.900 lbs/ga l § 77.00 F 

1.070 kg/ 1 <s 25.00 C 

Percent Volatiles 

38.0 - 42.0 % 

Evaporation Rate 

SLOWER THAN ETHYL ETHER 

Appearance 

HAZY 

State 

LIQUID 

Physical Form 

HOMOGENEOUS SOLUTION 

Color • 

COBALT 

Odor 

PUNGENT 

PH . 

Not applicable 

Viscosit y 

615.0 - 785.0 cps 

Continued on next page 

1 
DEC. 17.1998 9:23RM RRE LOBBY A~~ ~ ; ^ 

I i U • "">""> f r"1 • ti 

MATERIAL SAFETY DATA SHEET 

Ashland Chemical Co. Page 006 

Date Prepared: 07/17/97 

Date Printed: 07/19/97 

MSDS No: 0238404-004.001 

AROPOL C 5406 ACC GP 

Solubilit y in Water 

NEGLIGIBLE 

10. STABILITY AND REACTIVITY 

Hazardous Polymerizatio n 

Product can undergo hazardous polymerization. Avoid exposure to excessive 

heat, peroxides and polymerization catalysts. 

Hazardous Decomposition 

May form: carbon dioxide and carbon monoxide, various hydrocarbons. 

Chemical Stabilit y 

Stable -

Incompatibilit y 

Avoid contact with: halogens, strong alkalies, strong mineral acids. 

11. TOXICOLOGICAL INFORMATION ' ? 

No data 

12. ECOLOGICAL INFORMATION 

No data 

13. DISPOSAL CONSIDERATION 

Waste Management Information 

Contaminated absorbent may be deposited in a landfill in accordance with local, 

state and federal regulations. Destroy by liquid incineration in accordance 

with applicable regulations. 

14. TRANSPORT INFORMATION 

DOT Information - 49 CFB 172.101 

DOT Description: 

RESIN S0LUTI0N,3,UN1S66,III 

Container/Mode: 

55 GAL DRUM/TRUCK PACKAGE• 

NOS Component: 

None 

j 

\ 

Continued on next page 
— , P.10 

UtL.lCi.yyt i yJdclHTI HKL LUtiBY 

NU. ;>:>.• r. y 

MATERIAL SAF.ETY DATA SHEET 

Ashland Chemical Co. Page 007 

Date Prepared: 07/17/97 

Date Printed: 07/19/97 

MSDS No: 0238404-004.001 

AROPOL C 5406 ACC GP 

RQ (Reportabl e Quantity ) - 49 CFR 172.10 1 

Product Quantity (lbs) Component 

2399 STYRENE MONOMER 

15. REGULATORY INFORMATION 

US Federal Regulation s 

TSCA (Toxi c Substance s Control Act) Statu s 

TSCA (UNITED STATES) The intentiona l ingredients of this product are listed, 

CERCLA RQ - 40 CFR 302.4(a ) 

Component RQ (lbs) 

STYRENE 1000 

SARA 302 Components - 40 CFR 355 Appendix A 

None 

Sectio n 311/31 2 Hazard Class - 40 CFR 370. 2 

immediate(K) Delayed(X) Fire(X) Reactive(X) sudden Release of 

Pressure( ) 

SARA 313 Components - 40 CFR 372.6 5 

Section 31.3 Component (s) CAS Number Max % 

STYRENE 100-42-5 41-68 

International Regulations 

Inventory Status 

Not determined 

State and Local Regulations 

California Proposition 65 

The following statement is made in order .to comply with the • Calif ornia Safe 

Drinking Water and Toxic Enforcement Act of 1986: This product contains the 

following substance(s) known to.the state of California to cause cancer. • 

BENZENE . 

ETHYLENE OXIDE 

The following statement is made in order to comply with the California Safe 

Drinking Water and Toxic Enforcement Act of 1986: This product contains the 

following substance(s) known to the state of California to cause 

reproductive harm. 

ETHYLENE OXIDE ' 

New Jersey RTR Label Information 

STYRENE MONOMER 100-42-5 

Pennsylvania RTK Label Information 

BENZENE, ETHENYL- 100-42-5 

Continued on next page 
ULL . i c i yyti y * ^H H HKL LUBBY ~ '• ~

 Bi±L l 

riu.'SDf' *-*. i a . - 

MATERIAL SAFETY DATA SHEET 

Ashland Chemical Co. ' Page 008 

Date Prepared: 07/17/97 

Date Printed: 07/19/97 

MSDS No: 0238404-004.001 

AROPOL C 5406 ACC GP 

16. OTHER INFORMATION 

The information accumulated herein is believed to be accurate but is not 

warranted to be whether originating with the company or not- Recipients are 

advised to confirm in advance of need that the information is current, 

applicable, and suitable to their circumstances. 

\

 J 

Last page 

\0 
'DEC.17.1998 9*20flM ARE LOBBY 

P.12 

NU.SOZ r. i 

flffiE The Top Line For Your Truck 

400 Nave Rd SB 

P.O. Box //OO 

MassiUon, OH 44648-0802 

Office 330-830-4500 

Fax 330-830-4545 

COMPANY NAMS. jjias^JBJigm?^ ^ 

tffG/F/C £UV)&0. S£MJC6LftZUC, FROM <?AsJtr fic/se-j 

ATTENTION: 

^/fu/// /yjc/^t 

DATS 

T£T A 

FAX NUMBER: JMBER \Bp: PHONE NUMBER _ _ _ , . 

sec /tgoy/s- SxT. -ZU 

QURGENT [ j Reply ASAPf Q3 Please Comment/ 00Ple Please ; Reviev// Q For your //Tforniatfon/ 

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