### Prepared by: CHROMIUM PLATING COMPANY, INC. 

### TULSA, OKLAHOMA



### Submitted By: RMC Environmental, Inc.

11311-B Douglas Street Huntley, Illinois 60142



### RMCEI Reference Number: 98-016-311

October 19, 1998



### TPTALCHROMIUM EMISSIONS 

### TEST REPORT For Chromium Plating Company, 

### Inc. Tulsa, OklahomaRMC Environrnent:al, Inc. PO &x 1008 Elgin, Illinois 60121-1008

10 November 1998 800-532-3391 Voice 847-669-5389 Fax

I. Rachel M. Chleborowicz, 

### certifY that the Chromium Emissions Testing conducted on the hard chrome plating scrubbers installed at the Chromium Plating Company, Inc. facility in Tulsa, Oklahoma, 

### was conducted under my supervision. All ofthe results obtained during this testing are authentic and accurate.

# ~- Rache blebor

# ~ p . er

### Table ofContents

1.0 PROJECT SUMM.ARY

..................................... _....................................... 1-1 

### 1.1 Source Infonnation.......................................................................................... I-I 1.2 Testing Finn 

### Information.................................................................................. 1-1 

### 1.3 Test Infonnation............................................................................................... 1-1 2.0 SUMM.ARY OF .RESULTS

... "

....,...............-.-... _.................................... 2-1 

### 3.0 SOURCE DESCRJ:ItTION

.............................................._..................._....... 3-1 4.0 TEST PROCEDURES AND EMISSIONS DETERMINATION___ 4-1 4.1 Test

### Procedures.......................

...................................................................... 4-1 

### 4.2 Emissions Detenninations................................................................................ 4-1

Appendix A - Reference Measmement Data With Emission Rate Calculations Appendix B - Field DataSheets ForTotal ChrOmilDD 

### Appendix C - Analytical Data ForTotal Chromiwn Analysis Appendix D - Reference MeasurementPerformance Checks and CalibmtioD, Chain OfCustody 

### and QAlQC 

### Documentation

### Chromium Plating Company, Inc. Tulsa, Ok/ahoma

1.0 PROJECf SUMMARY 1.1 Source Information PlantName and Address:

Units Tested: FacilityID Number:

1.2 TestingFirm Information
Finn Name and Address:

Firm Contact: TelephoneNumber:

.
1.3 TestInformation
Test Requested By: Finn Contact: Telephone Number:

TestObjective:

TestMethods:
Test Date:
Test Coordinators:
Test Personnel: Chromium PlatingCompany, Inc. 412 North Cheyenne Tulsa, Oklahoma SCRUBBER 1&:.2

RMC Environmental, Inc. I 131 1-B Douglas Street Huntley, Dlinois 60142
Rachel ChJeborowicz

- ProjectManager 800-532-3391 Voice**847~69-5389** Fax

Chromium Plating Company, Inc. Mr. BruceMcAllester 918-583-4118 Phone 918-583-4112 Fax 98-016-311

Conduct total chrome, moisture and flow rate testing on plating tanks in accordance with theMACTregulations and EPAMethod 306 (40 CFR 63, Appendix A). EPAMethods 1,2,3,4 and 306 October 19. 1998 Mr. BruceMcAllester
Rachel Chleborowicz

- ProjectManager Greg Chleborowicz

- ProjectManager Ryan DaUghtrey

- Environmental Technician



## I-IChromIUm Plaflll g Com pan y, Inc
. 

### T

ul

sa, Oklahoma
2.0 SUMMARY O F ItESUL ; rs 98·016·311

The r esults of the emissions rctesting perf omlcd on thc 1 : l.Tge chrome tank stacks arc presentc.. "CI in Table 2· 1. .J.)etailed results ofall ofth e testing completed on this l ocat ion are located in**App~ndix** A The field data and the analytical

r esults are presented in AplJendix D and C, r especti vely. Calibration sheets and equipment perfonnance checks arc pr

esented in Appendix D , along with the chain ofcustody. A cyclonic flowcheck

....'llS perf onned at the s,'1mpling 1 0C3.tion to delennine t he existence ofabnonnal now. The observed averageyawangJ e f

or SCRUBBER 1 was 7

.7& SCRUBBER 2 was 4

. ' &

. Seclion 2

.5 of EPA Method 1 indicates Ihat a sampling location with an avcmge yaw angle of

## s: 20' is acceptable

. As indiC3.t cd by the average ofthe three lest runs, Iheconccntrntions Oflhc chromium emissions wer e below the p...[ACT r egulation standards of0

.0 15 mgfDSCM for compos ite mesh pad scrubber systems on hard chrome plat ing tanks

.

T A BLE 2·1 SUMMARY O F TOTAL CHROMIUM RESULTS Chromium I'laling Company, Inc. Oclober 19, 1998

Localion T C!II'lIl11 nteler I{ esull Speciricalion SCRUBBER # 1

# ~~**'** D.OIZS :5 0

.0 15 mglDSCM for hard chrome plating Flow nile DSCFM IK

.838 sources SCRUBBER #2 mg/ DSCM O

.O

Ull :5 0

.0 15 mg/DSCM for har d chrome plati ng Flow mle DSCFM 2 1,800 sour ces



### 2· 1Chromium PIOIing CompallY , Inc. Tulsa, Oklahoma 

### 3.0 so unCE DESCRIPTJON 9 8
-016
-311

Scrubber I i s a 19,000 CFM v cmilatioll syst cm w ith four (4) Model SCSU4,750 CRvl thr ee stage ven ical chrome separators, 'nu::sescp;1f3torn go t hroug h an autornaticlpcriodic washdown

. TIle scrubber is designed to remove 99

.8% of the chrome mist two micr ons and larger and exhaust l ess than 0

.015 m glDSCM ofchrome into the atmosphere. Scrubber 2 is a 19,000 CFM v entilation system with fiv e (5) ModelSCSU hoods (2,000 CFM

. 2,500 CFM, 4,000 CFM, 4,500 CFM and 6,000 CFM) three stage venical chrome separat ors. These separators also go through an
aut omatic/periodic wasbdown. This scrubber system i s designed to remove 99

.8% ofthe chrome mist t wo microns and larger and exhaust less than 0

.0 15 mgIDSCM ofchr ome into the atmosphere

. o(h scrubbe employ a three stage composite mes pa(] system : one course multi

-layer pad (Stage I ) , one medium multi

-layer pad (Stage 2) and one fine multi-layer pad (Stage 3)

. St age I & 2 ar c involved in the washdown. Magnahelic gauges arc installed between C3ch oflhe stages t o m C3Sur e the diff erential pressures acr oss each stage as well
as across the cnlirc system.



### 3

- 1

### Chromium Plating Company, Inc. Tulsa, Oklahoma
4.0 TEST PROCEDURES AND EMISSIONS DETERMINATIONS 98-016-311

Thesampling and analytical requirements for this program includethe determination oftotal chrome, O/COl , moisture and volumetric flowrates from the stack effluent The plating process was operated at 100% capacity. Figure 4-1 illustrates the sampling system used for thetotal chrometesting. Thespecificequipment and procedures that were used
are detailed below. 4.1 Test Procedures Total chrome compliance testing was completed on the exhaust stacks from the chrome plating tanks. The compliancetestingconsisted ofthreetwo-hourtest runs utilizing EPAMethods I, 2, 3B (40 CFR 60, Appendix A) and 306 (40 CFR 63, Appendix A). Thenumberand location ofthe sampling points were determined according to the procedures outlined in EPA Method 1. Theexhaust stack cross section 

### was divided into 24 equal areas with 12 sampling points on each to two axes. A cyclonicflow checkwas performed at thesampling location to detennine theflow angles at each point An S-type pitot, oil manometer, and an angle finder were used forthesedeterminations. At each point, the Pitot was positioned at a right angle to the flow, the pitot was then rotated until a null reading was obtained. Theangles ofrotation werethen noted. The flue gas velocity and volumetric flow rates were determined according to EPA Method 2. Velocity head measurements (delta P) were made using an S-type Pitot tube conforming to the geometric specifications indicated in Method 2 and each Pitot has been assigned a coefficient of0.84. The differential pressures weremeasured using an oil manometeroftheappropriate range. Flue gas temperatures were obtained with chromel-alumel thermocouples equipped with a digital readout. Thecomposition ofthe flue gas was determined utilizing the procedures outlined in Method 3B. The percent moisture content ofthe flue gas was obtained from the amount ofmoisture collected in the Method 306 sampling train. Analysis for carbon dioxide and oxygen were was performed using a Fyrite analyzer and the analytical results were used in the calculation offlue gas composition and molecular weight. 4.2 Emissions Determinations The total chrome samples were drawn isokinetically from the source using an EPA method 306 sampling train. Thesamplingtrain consisted ofa glass nozzle and probe liner, an attached Type S Pitot tube, four glass impinger chilled and a metering console. No filter is used for this method. The first impinger is left empty, the second and third impingers contain 100 ml of0.1 N sodium hydroxide (NaOH) in placeofwater, and the fourth impinger contains 200g ofpreweighed silica gel for moisture removal. Each of the twenty-four points were sampled for 5 minutes resulting in a net run time of 120 minutes. After sampling, the reagents were returned to their original container, weighed, the weights recorded on the label and the liquid level marked. Thesilicagel was returned to the original container, weighed and the weight recorded on the label. The volume ofwater vapor condensed in the impingers and the volume ofwater collected in the silica gel were summed and entered into the moisture content calculations. All samplingcomponents exposed to the effluent were rinsed three time with NaOH and the rinses were added to the reagent containers. Thecombined samples and rinses were analyzed for total chrome using ion chromatography (IC) coupled with
4-1

### Chromium Plating Company. 

### Inc. Tulsa. Oklahoma

a post-column reactor (peR). 98-016-311

## IMPINGER TRAIN

ICE 

## BATH



# VACUUM GAUGE • :" •• '

.. I 

# 1{·;);'.· TEFLON"

## '~~~~:;'**SA~PLlNG** 

# HOSE

RUBBER SAMPLING HOSE .' 

### '. 

# SAMPLING NOZZLE

UNHEATED SAMPUNG PROBE



# r r THERMOCOUPLE 

## GAS flOW
UMBILICAL



# o . 

# . 

# e e**eOD~** 

# e**~§**

.. CONTROL UNITFigure4-1 Method 306 Total Cbrome SamplingTrain

### Appendix A - Re,ference MeasurementData With Emission Rate CalculationsRMC Environmental, Inc. Emissions Testing & Consulting

Plant: Chromium Plating Company, Inc. Date: 11/09/98 Project 

### #: 98-016-311 Location: Unit 1 - Mesh Pad System Sample Identification U1-M306-1 U1-M306-2 U1-M306-3 Test Date 10119/98 10119/98 10119198 Start 830 1108 1356 Finish 1047 1319 1600 Total 120 120 120 Cp Pitot Coefficient (CF) 0.84 0.84 0.84 A Area of stack 

### sq. inches 907.92 907.92 907.92 Pbar Barometric Pressure (in HG) 30.27 30.26 30.28 Wm Volume of Condensate (mg) 21.5 24.2 24.3 Ts Temperature 

### of Effluent (F) 66.2 72.7 76.9 Pavg Average Delta P 0.784 0.785 0.806 Pg Static Pressure (in H2O) 4.80 4.80 4.60 OH Delta H, Orifice pressure differentiaf (in H2O) 1.90 1.86 1.89 Tm MeterboxTemperature (F) 60.3 78.2 82.7 Vm Volume ofsample metered (CF) 93.441 94.568 95.682 

### Y Meter correction factor 0.9875 0.9875 0.9875 On Nozzle Diameter (in) 0.22 0.22 0.22 CO2 Percent Carbon Dioxide 

### (%) 1.00 0.90 1.10 02 Percent Oxygen 

### (%) 20.10 20.10 19.80 CO Percent Carbon Monoxide (%) 0 0 0 N2 Percent Nitrogen 

### (%) 78.90 79.00 79.10 Ms Molecular Weight (wet) (Ibllb-m) 28.85 28.82 28.84 Laboratory Results Total Chrome (mg) 3.88E-02 3.60E-02 2.52E-02

Ps Absolute pressure of Flue Gas (in HG) 30.62 30.61 30.62 Vwstd Volume ofWaterVapor (SCF) 1.01 1.14 1.15 Vmstd Volume ofMetered Gas (DSCF) 95.133 93.039 93.422 M Moisture 

### (%) 1.05 1.21 1.21 Vs Velocity (FPS) 49.07 49.44 50.29 

### Qaw Volumetirc Flow (ACFM) 18,562 18,704 19,024 

### Qsd Volumetric Flow (DSCF) 18,862 18,739 18,913 Chromium Concentration (mg/DSCM) 0.014 0.014 0.010 Chromium Concentration (lblHr) 1.02E-03 9.58E-04 6.75E-04

Isokenetic 

### (%) 100.39 98.82 98.31

### RMC Environmental, Inc. Emissions Testing 

### &Consulting

Plant: Chromium Plating Company, Inc. Date: 11/09/98 

### Project#: 98-016-311 Location: Unit 2 - Mesh Pad System Sample Identification U2-M306-1 U2-M306-2 U2-M306-3 Test Date 10119/98 10/19198 10/19198 

### Start 815 1107 1338 Finish 1021 1312 1543 Total 120 120 120 Cp Pitot Coefficient (CF) 0.84 0.84 0.84 A Area 

### of stack sq. inches 907.92 907.92 907.92 Pbar Barometric Pressure (in HG) 30.27 30.29 30.30 Wm Volume of Condensate (mg) 16.8 21.7 17.8 Ts Temperature of Effluent (F) 63.4 69.4 75.6 Pavg Average Delta P 1.037 1.034 1.088 Pg Static Pressure (in H20) 4.70 4.20 4.50 

## DH Delta H, Orifice pressure differential (in H2O) 1.73 1.69 1.89 Tm Meterbox Temperature (F) 56.3 65.0 71.8 Vm Volume of sample metered (CF) 82.061 83.216 85.745 Y 

### Meter correction factor 1.003 1.003 1.003 

### On Nozzle Diameter (in) 0.197 0.197 0.197 CO2 Percent Carbon Dioxide 

## (%) 0.90 1.10 1.00 02 Percent Oxygen 

## (%) 20.10 19.90 20.00 CO Percent Carbon Monoxide (%) 

### 0 0 0 N2 Percent Nitrogen 

## (%) 79.00 79.00 79.00 Ms Molecular Weight (wet) (lbnb-m) 28.85 28.84 28.86 Laboratory Results Total Chrome (mg) 5.71E-02 2.47E-02 O.OOE+OO
Ps Absolute pressure of 

### Flue Gas (in HG) 30.62 

### 30.60 30.63 Vwstd Volume of

### Water Vapor (SCF) 0.79 1.02 0.84 Vmstd Volume of 

### Metered Gas (DSCF) 85.481 85.296 86.834 M 

### Moisture 

## (%) 0.92 1.19 0.96 Vs Velocity (FPS) 

### 56.30 56.56 58.31 

### Caw Volumetirc Flow (ACFM) 21,297 21,397 22,060 Qsd 

### Volumetric Flow (DSCF) 21,782 21,566 22,051 Chromium Concentration (mgIDSCM) 0.024 0.010 0.000 Chromium Concentration (lblHr) 1.92E-03 8.26E-04 O.OOE+OO
/sokenetic (%) 

### 97.41 98.17 97.75AppendixB

- Field

### nata SheetsForTotal Chrome



## . 

## .

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FINAL • FILTER EXIT for NJ Method ,. FILTER BOX for .11 others• •• PROBE EXIT' , (probe ,**filt~r** heat off) apply to NJ Method 1. COHO. EXIT applies if sampling train has a condenSer.- 11..0 

## 1S'. 

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## V Min. 

### ee) Vm**(~)Z** tin ts 011 F-1112 (Page Ii rev. 9-94

### Appendix C - ADalytical 

### Data forTotal Chromium 

### , , 

### I I I 

## ," t

"I 

### , !

j" I
I i
, 

### .. I

# pace Analytical

RMC Environmental, Inc. P.O. Box 1008 Elgin, IL 60121-1008

Attn: Ms. Rachel Chleborowicz Phone: Solid results are reported on a wet weight basis Pace Sample No: 10904266 Client Sample ID: UNIT 11 Ul-306-01 Parameters Volume Results

Metals Units

Method: EPA 6010 DATE: 11/03/98 PAGE: 1

Pace Project Number: 1010387 Client Project ID: CHROMIUM PLATING CO.

Date Collected: 10/19/98 10/22/98 Matrix:Hater Date Received: PRL Analyzed Analyst CASI Footnotes

Prep Method: EPA 3010**~tals,** ICP Chromium 310 mls. 125 ug/L 10 11/02/98 10/27/98 TEM 7440-47-3 Date Digested

Pace Sample No: Client Sample ID: Parameters

Metals

Metals, ICP Chromium Date Digested 10904274 UNIT 11 Ul-306-02 Volume Results Units

Method: EPA 6010 330 mls. 109 ug/L 0. 0 368"'6- Date Collected: 10/19/98 10/22/98 Matrix:Hater Date Received: PRL Analyzed Analyst CAS# Footnotes

10 11/02/98 10/27/98 Prep Method: EPA 3010 TEM 7440-47-3 0.031.0-,-

# pace Analytical

Pace Sample No: Client Sample ID: Parameters

Metals

Metals, rep Chromium Date Digested

Pace Sample No: Client Sample ID: Parameters

'ls Metals, Iep Chromium Date Digested

Pace Sample No: Client Sample ID: Parameters

Metals Metals, ICP Chromium Date Digested

Pace Sample No: Client Sample ID: Parameters Metals Metals, ICP Chromium Date Digested 10904282 UNIT #1 Ul-306-03 Volume Results Units

Method: EPA 6010 DATE: 11/03/98 PAGE: 2 Pace Project Number: 1010387 Client Project ID: CHROMIUM PLATING CO. Date Collected: 10/19/98 10/22/98 Matrix:Water Date Received:
PRL Analyzed Analyst CAS# Footnotes

Prep Method: EPA 3010 347 mls. 72.6 ug/L 10 11/02/98 10/27/98 TEM 7440-47-3

10904290 UNIT #1 Ul-306-04 Volume

277 mls.

10904308 Results Units

NO Method: EPA 6010 ug/L

UNIT #2 U2-306-01 Volume Results Units

Method: EPA 6010 386 mls. 148 ug/L

10904316 UNIT #2 U2-306-02 Volume Results Units

Method: EPA 6010 

### 0.02S2...,.. Date Collected:

Date Received: 10/19/98 10/22/98
PRL Analyzed Analyst CAS# Matrix:Water

Footnotes

Prep Method: EPA 3010 10 11/02/98 10/27/98 TEM 7440-47-3

Date Collected: 10/19/98 10/22/98 Date Received:
PRL Analyzed Analyst CAS# Matrix:Water

Footnotes

Prep Method: EPA 3010 10 11/02/98 10/27/98 TEM 7440-47-3



### o.D5"l'-r Date Collected:

Date Received: 10/19/98 10/22/98 Matrix:Water

PRL Analyzed Analyst CAS# Footnotes

Prep Method: EPA 3010 361 mls. 68.5 ug/L 10 11/02/98 10/27/98 TEM 7440-47-3

# pace Analytical

Pace Sample No: 10904324 Client Sample IO: UNIT 12 U2-306-03 Parameters Volume Results Units

Metals Method: EPA 6010 Pace Project Number: 1010387DATE: 11/03/98 PAGE: 3

Client Project IO: CHROMIUM PLATING 00. Date Collected:

Date Received: 10/19/98 10/22/98 Matrix:Water

PRL Analyzed Analyst 

### CASH Footnotes

Prep Method: EPA 3010 Metals, Iep Chromium 336 mls. ND ug/L 10 11/02/98 10/27/98 TEM 7440-47-3 Date Digested 0.000 

# "'1-

# pace Analytical

PARAMETER FOOTNOTES ND Not Detected NC Not Calculable PRL Pace Reporting Limit Pace Project Number: 1010387 DATE: 11/03/98 PAGE: 4

Client Project ID: CHROMIUM PLATING 00.

# pace Analytical

QUALITY CONTROL DATA

Pace Project Number: 1010387 DATE: 11/03/9:1 PAGE: 5

RMC Environmental, Inc. P.O. Box 1008 Client Project ID: CHROMIUM PLATING CO. Elgin, IL 60121-1008

Attn: Ms. Rachel Chleborowicz Phone: QC Batch Method: EPA 3010 Analysis Description: Metals, ICP QC Batch ID: 18021 Analysis Method: EPA 6010 Associated Pace Samples: 10904266 10904274 10904282 10904290

METHOD BLANK: 10910800 Associated Pace samples: l0904324 10904316

10904266

Parameter Units Chromium ug/L 10904324

10904274 Method Blank 10904282 10904290

Result PRL Footnotes
NO 10

MATRIX SPIKE &**~TRIX** SPIKE DUPLICATE: 10910818 10910826 Matrix Parameter Units Footnotes



## ------------------------------ ---------- Chromium ug/L

LABORATORY CONTROL SAMPLE: 10910834 Parameter Units Chromium ug/L Spike 10899995 Conc.



## ---------- ------- 1.000 1000

Spike LCS Conc. Result 1000 1021 Spike Spike Result " Rec



## ---------- 1003 100

Spike "Rec Footnotes 102 10904308

10904308 10904316

Matrix Spike Sp. Dup. Dup Result " Rec RPD



### ---------- 961.8 96.1 4

# pace Analytical

QUALITY CONTROL DATA PARAMETER FOOTNOTES Pace Project Number: 1010387 DATE: 11/03/98 PAGE: 6
Client Project ID: CHROMIUM PLATING CO.

Consistent with EPA guidelines unrounded concentrations are displayed and have been used to calculate , Rec and RPD values. ND Not Detected Ne Not Calculable PRL Pace Reporting Limit RPD Relative Percent DifferenceAppendix D - Reference MeasurementCalibration, Cbam ofCustodyand QAlQCDocumentationDATE: 

### 2123/98



# -------

0.921 3.00 ·3.90 1.0000 0.0 10.000 10.000 0.920 3.00 ·3.90 1.0000 0.0 10.000 10.000 0.318 0.50 ·2.00 1.0000 0.0 5.000 5.000 0.317 0.50 ·2.00 1.0000 0.0 5.000 5.000 0.653 1.50 ·2.50 1.0000 0.0 10.000 10.000 0.652 1.50 ·2.50 1.0000 0.0 10.000 10.000

Nomenclature Pb Barometric:Pressure (in. Hg) Q AowRate (c:fm) Mi OrifiCEPressure Differential (in H2O) M' Inlet Pressure Differential (in. HzO) V

d Gas MeterVolume· Dry (ft3) V

ds Stardard MeterVolume· Dry(ft3) T d AverageMeterBox Temperature (oF) To Outlet Meter BoxTemperature (OF) Tds Averaf!J! Standard MeterTemperature(OF) Yd MeterCorrection Factor (unitless) Y

ds Staroard MeterCorrection Factor(unitless) Mi@ OrifiCEPressure Differential giving0.75 dm ofairat 68°Fand 29.92 in.Hg On H20) 

# Meter Box FuL**~** 

# est Calibration

089.085 099.240 10.155 69.0 69.0 69.0 099.240 109.409 10.169 69.0 69.0 69.0 119.800 124.909 5.109 69.0 69.0 69.0 124.909 130.011 5.102 69.0 69.0 69.0 149.131 159.379 10.248 69.0 69.0 69.0 159.379 169.644 10.265 69.0 69.0 69.0

Vacuum Gauge Thermometers
Standard Vacuum (in. Hg) Gauge

## S~?;;ro Inlet Outlet



### 5.1 5.0 10.0 10.0 15.2 15.0 20.1 20.0 24.9 25.0 

### J. Buchen 

### Operator:



# -------------------

94.0 94.0 81.0 87.0 94.0 94.0

Q 83.0 88.5 10.51 83.0 88.5 10.58 83.0 85.0 12.88 83.0 85.0 12.92 86.0 90.0 14.90 86.0 90.0 14.93 

### AVERAGE
Equations



# = 17.64 (Viii) (It) (fds 

### + 460)(9) 1.0034 1.0020 1.0019 1.0033 1.0044 1.0027 

### 1.0030 1.8811 1.8901 1.8680 1.8796 1.8646 1.8721 

### 1.8770

## Pyrometer No.: 66-8 Office: Palatine, 11



# -------- Calibrated By: J. Buchen Client: RIVIC£r 

## Date: 2/23/98 

## Job Number: 

## '1t-o,r. -311



## Calibration Reference Settings Pyrometer Reading for Fahrenheit Scale 50 of 

## 50 of 

## 100 of 

## 100 of 

## 150 of 

## 150 of 

## 200 of 

## 201°F 250 of 

## 252 of 

## 300 of 

## 302 of 

## 350 of 

## 351 of 

## 400 of 

## 400 of 

## 450 of 

## 450 of 

## 500 of 

## 500 of 

## 550 of 

## 551 of 

## 600 of 

## 601 of


# Calibration Reference Information

Reference Used: Omega CI-23A 

## ---""------- Serial No: T-123216 Calibrated By: J.H. Metrology Co. Date: 3/4/97 

## Report No: 9734-R26517

# .. MeterBox Post Test Calibration DATE: 

### 10fl7J98



# ------- Operator. D. Rybmsti**---~----** 

### ProjectNumber:**~**

### .. 

# --...:....:.---

o.as 2.SS -2.20 JJXXIO 0.0 10.000 IDlXlJ 125m 734917 91140 '1O.D 70.0 7ClD I3JJ 14.0**~** 11.41 l.02lD 1.9013 0.&$ 2.S.S -:uQ 1.0000 OJ) JIUJDO lO.lXlO n4.9J7 74U17 9.910 '1O.D 10.0 70..0 15.0 7SJ) 80.0 JI.41 1.Dlj9 J.9010 

### o.as us -2.2D UlOOO 0.0 ID.OOO Hum 1«.8%7 15UD1 9..980 '1U.O 70.0 7D.D 17.0 16.0 11.5 ItA' Int16 1.9075 AVERAGE 1.0160



### Nomenclature 

### Equations 

### JIb**&romebk~Cin.Hg)** Q Flow Rate Cdm) :: (YctJ

# [V-I1d + 460

# 1 Ph 

### + AP

### /13h] Ali tlzi&:eJ'JeMaeDifferential (hi.H2O) 

## Yc. IJP lDJetPl'essnreDiffen:ntia1 (in.HzO) 

# V 4 

## 1d. + 

### 460 P b 

### + 

### AH/l3.6



# .. Vd GasMeterVolume- DIy(fl3) Vds SludardMda-Vclumt;- Dry (fl3) 

### AH@ 

### = 0D319(AH). 

# [0:.. + 

### 460)8}1 Td**A~**M.eIft BoxTempemfure("'f) 

### P1><To 

### + 460) 

### (V.><Y') TD**OIIt1etMeleJ'BaxT~("F)** Td,s**A~Sbll!Ct** ...d Me!erTempe:ratureC"f) 

## = 17M (V.J 

### @) Yd MderComctianFaclw(uuitJess) 

### Q Yds 5ImdimIMeIer'Cmrectioo.FitClor (UDilIei5) 

### lTda + 460)(9) 

# I .mG 0dfIcePttssweDilren!IIIialglviDgQ15dm ofairal68"Pand 29.92in. Hg (in.**~)** (] o :-1 N OJ



# - o


# .. -.lDATE: 

### 11125197

0.972 3.00 -2.70 1.0000 0.0 10.000 0.972 3.00 -2.70 1.0000 0.0 10.000 0.394 0.50 -1.80 1.0000 0.0 8.000 0.394 0.50 -1.80 1.0000 0.0 6.000 0.684 1.50 -2.20 1.0000 0.0 10.000 0.684 1.50 -2.20 1.0000 0.0 10.000



### Nomenclature Ph Barom:!tricPressure (in. Hg) Q FlowRate(cfm) AH OrilimPressure DiHerential (in H20) l1P Inlet PleSSure Differential (in. H20) V

d Cas MeterVolume

- Dry (ftJ) V

ds Standard MEterVolume

- 01)' (ft3) Td AverageMeter BoxTemperature (OF) To Outlet Meter BoxTemperature'(°F) T

ds Average Standard MeterTemperature 

### f'F) Yd MeterConedion Factor (unitless) Y

ds Standard Meter CorrectionFactor(unitle;s) Mi@ Orifim Pressure Differential giving Q.75dm of airat 68°Fand29.92 in. Hg (in**H~)** 10.000 10.000 8.000 6.000 10.000 10.000 

# Meter Box Full Test Calibration

161.207 171.496 171.496 181.788 196.539 204.842 204.842 211.059 224.807 235.156 235.156 245.502

Vacuum Gauge
Standard Vacuum (in. Hg) Gauge



### 4.8

. 5.0 9.9 10.0 15.0 15.0 20.1 20.0 25.4 25.0 10.289 10.292 8.303 6.217 10.349 10.346 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0

Thermometers

Standard Inlet Outlet 

# rF) 94.0 94.0 87.0 87.0 91.0 91.0

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## AVERAGE 0.9875 1.7052
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# ------- Date: 11/25197 

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## Serial No: T-123216 Calibrated By: 

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## Report No: 9734-R26517



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### .Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 1 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 CAS #: 000544923 FORMULA: CU CN 

### CHEM. FAMILY: inorganic salts CHEMICAL NAME AND SYNONYMS: Copper Cyanide; Cyanide of Copper; MSDS 000410 DETAIL 00165 Date: 16-NOV-200S 09:45:18.62 100# DRUM MSDS No. 000410 Revision No./Date 02 970107 Detail Number 00165/01

SUPPLIERS 

### NAME: Harcros Chemicals Inc. 5200 Speaker Road Kansas City KS 66106-1095 SUPPLIERS PHONE NUMBER : TRANSPORTATION EMERGENCY PlIONE NUMBER 913-321-3131 1-800-424-9300 S.A.R.A. INFORMATION**~S** : Acute PHYSICAL DATA: Pure solid SECTION I HAZARDOUS INGREDIENTS



## --------------------------------.------ -----------.-------------------------------------------- Ingredient Cas Number Copper Cyanide Cupric Cyanide (CAS # 544-92-3

SECTION II HEALTH HAZARDS POTENTIAL EFFECTS OF EXPOSURE MAX SARA AIR CONTAMlNENT LEVELS

, APPLIES W/W 312 313 372 100.0 y

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# __**I~~~I~~** Y As Cyanide (From Copper Cyanide) TWA 5 mg/m3 OSHA y CEILING 5 mg/m3 ACGIB DESIGNATED SKIN HAZARD OSHA/ACGIH As Copper TWA/TLV Dusts & Mists 1 mg/m3 OSHA/ACGIB 

# ----------1-----------1----------1----1-----

This product contains potassium, sodium, or other metal cyanides which can be absorbed through all body tissues includ1ng the skin, lungs, and stomach. The cyanide ion (CN-) inactivates cellular respiration within the body resulting in rapid cell death. The symptoms of cyanide poisoning, which occur in rapid succession, include salivation, gidiness,

Continued On Page 2 

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....... w wHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 2 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 Date: 16-NOV-200S 09:45:18.95 100# DRUM SECTION II HEALTH HAZARDS (CONTINUED) headache, heart palpitations, difficult¥ breathing, unconsciousness, and death. A cyanide antidote kit must be available at all t1mes.

EYES Bye contact with product may cause irritation burns irreversible damage even death

SKIN Skin contact may cause irritation burns even death Absorption thru skin may cause symptoms described under inhalation and ingestion.

INHALATION Inhalation may cause headache dizziness nausea breathing difficulty vomiting unconsciousness

convulsions even death INGBSTION Ingestion may cause headache dizziness nausea breathing difficulty vomiting unconsciousness

convulsions even death TARGET ORGANS OVEREXPOSURE MAY CAUSE DAMAGE TO, DISORDERS OF, OR ADVERSELY AFFECT THE FOLLOWING SYSTEMS, FUNCTIONS, ORGANS: blood pressure FIRST AID FIRST AID EYES FOR CYANIDE EXPOSURE: Immediately flush eyes with plenty of water, remove contaminated clothing, and keep patient quiet and warm. If symptoms of cyanide exposure occur, see first aid for skin, below. Call a physician.

FIRST AID SKIN FOR CYANIDE EXPOSURE: Wash skin promptly to remove the cyanide while removin!1 all contaminated clothing, including shoes. Do not delay. Skin absorption can occur from CYan1de dust, solutions, or BCN vapor. Absorption is slower than inhalation, usually measured in 1lll.nutes compared to seconds for inhalation. Patient should be watched for at least 1 to 2 hours because absorbed cyanide can continue to work into the bloodstream. Wash clothing before reuse and destroy contaminated shoes. Call a phrsician. UNCONSCIOUS BUT BREATHING: Break an amyl nitrite ampule n a cloth and hold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 minutes until the patient regains consciousness (usually 1-4 ampules). Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, consiaer holding the amyl nitrite under the nose continuously for the first ampule or more. Call a physician. NOT BREATHING: Give artificial respiration (100% oxygen), preferably with an oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule inside the resuscitator face piece,**bein~** careful that the ampule does not enter the patient'S mouth and cause choking. Give oxygen s1multaneously. Call a physician.

FIRST AID INHALATION FOR CYANIDE EXPOSURE: carry patient to fresh air. Lay**~atient** down. Administer oxygen and amyl nitrite. Keep patient quiet and warm. Even with inhalat10n poisoning, thoroughly check clothing

Continued On Page 3 (SI \D 

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### ..... w wHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 3 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 SECTION II HEALTH HAZARDS Date: 16-NOV-200S 09:45:19.31 100# DRUM (CONTINUED) and skin to assure no cyanide is present. Call a physician. Rescuers of patients in an HCN environment should wear SCBA equipment. CONSCIOUS: For inhalation and/or absorption if the patient is alert, oxygen may be all that is needed. But if the patient is not fully conscious or shows signs of poisoning, see below. Call a physician. UNCONSCIOUS BUT BREATHING: Break 

### an amyl nitrite ampule in a cloth and bold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh**a~ule** every 3 minutes until the patient regains consciousness (usually 1-4 ampules).

Give oxygen s1multaneously to aid recovery. Where more severe poisoning bas occurred, consider**holdin~** the amyl nitrite under the nose continously for the first ampule or more. Call a physic1an. NOT BREATHING: Give artificial respiration (1001/; oxygen),**~referably** with an oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule 1nSide the resuscitator face piece, being careful that the ampule does not enter the patient'S mouth and cause choking. Give oxygen simultaneously. Call a physician.

FIRST**~D** INGBSTION FOR CYANcrDE EXPOSURE: Conscious: Immediately give patient one pint of 11/; sodium thiosulfate solution (or plain water) by mouth and induce vomiting by having patient stick finger into throat. Repeat until vomit fluid is clear. Never give anything by mouth to an unconscious person. Give oxygen. Call a physician. UNCONSCIOUS BUT BREATHING: Break an amyl nitrite ampule in a cloth and hold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessarr' use a fresh ampule every 3 minutes until the patient regains consciousness (usually 1-4 ampu es). Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, consider holding the amyl nitrite under the nose continuously for the first ampule or more. Call a physician. NOT BREATHING: Give artificial respiration (1001/; oxygen), preferably with an oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule inside the resuscitator face piece, being careful that the ampule does not enter the patient's mouth and cause choking. Give oxygen simultaneously. Call a physician.

OTHER INFORMATION NOTES TO PHYSICIAN MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Medical treatment is normally provided by a phYSician, but might be provided by a professionally trained "qualified medical person" where a need exists and where State and local laws permit. Specific training for handling cyanide poisoning emergencies is eBsential, as well as being "in practice" for giving intravenous injections. Du Pont trains all personnel working with cyanide to use the first aid procedures, but not the medical treatment**~rocedure.** While**preparin~** for sodium nitrite and sodium thiosulfate inject10ns, use amyl nitrite and oxygen as outl1ned in First Aid. When ready and if the patient is not responding to first aid, first inject the solution of sodium nitrite (10 mI. of a 

### 3' solution) intravenouslr at the rate of 

### 2.5 mL/minute, then immediately inject the sodium thioBulfate (50 

### mL of a 25\ so ution) at the same rate, taking care to avoid extravasation. This is a fairly lengthy treatment (24 minutes) since a total of 10 + 50, or 60 

### mL, is injected at a rate of 2.5 mL per minute. Consideration should be given to the size and

Continued On Page 4 

## '"

....
..... w wHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 4 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 Date: 16-NOV-200S 09:45:19.66 100# DRUM



## -------------------------------------------------------------------------------------------------- SECTION II HEALTH HAZARDS (CONTINUED) condition if the patient as treatment is proceeding. The above sodium nitrite injection is about 1/3 of a lethal dose (see below), so care should be taken to avoid excessive use. It is not essential that full quantities be given, just because treatment was started. Injections can be stopped at any point if recovery is evident, but be sure to keep track of quantities administered in case treatment needs to be restarted. Relapse is abnormal if cyanide intake is not continuing, unless a large intake from**swallowin~** occurred. Don't overreact. While prompt treatment is essential where poison1ng has occurred, treatment of a lucid, conscious patient would rarely be necessary. The effects of cyanide**~oisoning** are immediate, not delayed, and a conscious person that can communicate does not have**s~gnificant** cyanide poisoning. For most accidental pOisoning, complete recovery occurs within 1-2 hours. If cyanide exposure was severe, watch patient continuously for 24-49 hours. If there is any return of**sym~toms** during this period, consider repeating this treatment using one half the amounts of sod1um nitrite and sodium thiosulfate solutions. Blood chemistry should monitored during prolonged treatment. caution should be used to prevent overuse of medical treatment chemicals as the prescribed dose is about 1/3 the lethal dose for an average individual. The nitrite converts hemoglobin to methemoglobin which reduces the oxygen carrying capacity of the blood. This is done purposely as methemoglobin attracts cyanide away from the body cells, but nitrite use must be limited to prevent hemoglobin deficiency. Du Pont has not experienced nitrite overdose problems; but being alert to this is important information to medical personnel. If signs of excess methemoglobinemia develop (i.e., blue skin and mucous membranes, vomiting, shock and coma), 1t methylene blue solution should be given intravenously. Administering up to a 1 to 2 mg/kg of body weight over a period of five to ten minutes should be considered and repeated in one hour if necessary. NOTE: This procedure can free cyanide from cyanomethemoglobin. The free cyanide can again bind with cytochrome oxidase and, therefore, repoison the patient. If methylene blue is used, it must be used very carefully. It is best to avoid overuse of nitrite so corrective action is not needed. Historically, Du Pont has not had to use methylene blue to counter exceoD nitrite use. In addition, oxygen inhalation will be helpful. Transfusion of whole fresh blood may be considered if there has been mechanical injury with external bleeding and simultaneous cyanide exposure. When handling potential cyanide poisoning emergencies, keep in mind: 1. Cyanide acts rapidly, usually within seconds once it enters the bloodstream. Delayed effects would only be expected during brief periods (e.g., up to about 20 minutes) when (a) cyanide was absorbed into the bloodstream from the stomach after ingestion or (b) absorption through the skin occurred prior to skin washing, but entry into the blood was not complete. In treatment, therefore, treat what you see; don't overreact. It's rare when "preventive" use of the antidotes would be warranted. If you can converse normally with the patient, cyanide intake is limited and no action is called for other than to closely monitor the patient and keep him calm by reassurance of his condition during the following 20-30 minute period. 2. The half-life of cyanide in the body is estimated at 20-90 minutes. The body routinely destroys cyanides from foods, cigarette smoke, etc. so cyanide is not a cumulative poison. In case of accidental cyanide intake, normal body action**~icklY** begins cyanide destruction. In diagnosis and monitor1ng as mentioned in item 1, the cr1tical

Continued On Page 5**~** 1.0 

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### ..... w wHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 5 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 Date: l6-NOV-200S 09:45:20.29 100# DRUM SECTION II HEALTH HAZARDS (CONTINUED) period 

### is therefore short. Normally what happens in the initial few minutes after exposure will indicate the degree of poisoning. Du Pont's experience in treating cyanide poison cases is that first aid procedures using oxygen and amyl nitrite were effective and the only treatment needed in most cases. Medical treatment, using intravenous injections, was used in a few cases. Both procedures have been successful. For further information, see Du Pont Sodium Cyanide Storage and Handling Bulletin.

ROUTES OF ENTRY eye contact skin contact skin absorption inhalation ingestion OVEREXPOSURE MAY AGGRAVATE DISORDERS OF THE central nervous system CARCINOGEN STATUS No components, present in excess**ofO.~'** by weight are listed as carcinogens by IARC, NTP, or OSHA.

EXTRA INFORMATION FIRST AID MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Treatment for cyanide**~oisoning** can be provided in two ways, aFirst Aid" and "Medical Treatment". Both require l.mmediate action to prevent further harm or death. First aid using oxygen and amyl nitrite is generally given by a layman before trained medical help arrives. Medical treatment is aggressive treatment involving intravenous injections of sodium nitrite and sodium thiosulfate, and must be administered by qualified medical personnel. Even if a doctor or nurse is present, the need for fast treatment dictates using first aid treatment with oxygen and amyl nitrite while medical treatment materials for intravenous injection are being prepared.**~erience** shows that first aid given**~romptly** is usually the only treatment needed for typical accl.dental poisonings. Larger cyanide l.ntake increases the need for medical treatment. Medical treatment is given if the patient does not respond to first aid. It provides a large quantity of antidote including sodium thiosulfate to chemically destroy cyanide in the body. However, even under optimum conditions, amyl nitrite can be administered faster and should be used even if medical treatment follows. Always have on hand the materials listed below. FIRST AID JUID MEDICAL TREATMENT KITS. Actions to be taken in case of cyanide exposure should be planned and practiced before beginning work with cyanides. In most cases, cyanide poisoning causes a deceitively healthy pink to red skin color; however; if a physical injury or lack of oxygen is invo ved, the skin color may be bluish. Reddening of the eyes and pupil dilation are also symptoms cyanide**~oisoning.** workers should be trained to provide immediate first aid using oxygen and amyl n1trite resuscitators. In case of cyanide poisoning, start first

aid treatment immediately, then call a physician. FIRST AID SUPPLIES FOR CYANIDE EXPOSURB: Adequate first aid supplies for cyanide poisoning should be conveniently placed throughout cyanide areas and should be immediately accessible at all times. They should be routinely inspected (typically daily) by people who would use them in an emergency. The total number of each item listed below should be adequate to handle the largest number of exposure cases reasonably anticipated, taking into account that some**su~plie8** may be wasted, destroyed, or

inaccessible in the emergency. 1. Oxygen Resuscl.tators-Tbe Flynn Series III Model Continued On Page 6 

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### ..... W WHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 6 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 Date: 16-NOV-2005 09:45:20.95 100# DRUM



## -------------------------------------------------------------------------------------------------- SECTION II HEALTH HAZARDS (CONTINUED) by O-Two Systems (800-387-3405) has performed well in 

### Du Pont use. It is lightweight, rugged, and easy to use. 2. Amyl Nitrite Ampules (antidote) -One box of one dozen ampules per station is usually satisfactory. Locate stations throughout the cyanide area. CAUTION: Amyl Nitrite is not stable and must be replaced every 1 to 2 years. Store in the original dated box, away from heat. A common Du Pont practice is to use the resuscitator as the storage point for the amyl nitrite ampules. Avoid storage on vehicles where temperatures can reach 140-150 deg F or more. 3. A set of cyanide first aid instructions should be located at each amil nitrite storage location. Workers should be fully trained since in a real emergency there wi 1 be insufficient time to "read the book". 4. Two l-pint bottles of 1\ sodium thiosulfate solution for use in case of cyanide ingestion or plain water can be used. AMYL NITRITE NOTES FOR CYANIDE EXPOSURE: 1. Amyl nitrite is highly volatile and flammable, do not smoke or use around source of ignition. 2. If treating patient in a windy or drafty area, provide something-a rag, shirt, wall, drum, cupped hand, etc,-to prevent the amyl nitrite vapors from being blown away. Keep the ampule upwind from the nose. The objective is to get amyl nitrite into the patient's lungs. 3. Rescuers should avoid amyl nitrite inhalation so theI won't become dizzy and lose**co~etence.** 4. Lay the patient down for treatment to mainta n a good blood supply to the patl.ent's head. Since amyl nitrite dilates the blood vessels and lowers blood pressure, lying down will help prevent unconsciousness. MEDICAL TREATMENT KITS FOR CYANIDE BXPOSURB: Medical Treatment Kits for cyanide poisoning should be conveniently located for easy access by medical**~eople.** Materials for intravenous injection are intended for use only bI a physician or fully quall.fied medical personnel. The location of kits should be careful y planned as part of the emergency preplan. Suggested locations for kits include:

- in or near the cyanide area - plant medical station

- entrance guard house

- local hospital

- doctor's office and residence CAUTION: Do not store amyl nitrite or Medical Treatment Kits on vehicles as heat build-up may ruin the amyl**n~rite.** Kits and amyl nitrite should be accessible but secured against tampering. They should be inspected regularly and the amyl nitrite ampules replaced every 1-2 years. Medical Treatment Kits should contain the following: 1. One box containing one dozen amyl nitrite ampules. 2. Two sterile ampules of sodium nitrite solution (10 mL of a 3\ solution in each)

. 3. Two sterile atl1J?ules of sodium thiosulfate solution (50 mL of a 25% solution in each) . 4 . One 10 ml sterl.le syringe. One 50 mL sterile styringe. Two sterile intravenous needles. One tourniquet. S. One stomach tube. 6 . One dozen gauze pads. 7. A set of cyanide instructions on first aid and medical treatment. NOTE: QAmyI Nitrite" and "Medical Treatment Kits" can be purchased through local pharmacies with a physician'S prescription. As a help, you can inform the pharmacist that Eli Lilly and Co. produces the kit.

SECTION III SPECIAL PROTECTION PROTECTIVE EQUIPMENT PROTECTIVE EQUIPMENT EYES Continued On Page 7 \D


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....... w wHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 7 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 Date: 16-NOV-200S 09:45:22.42 100# DRUM**----~------------------------------------------------- --------------------------------------------**  SECTION III SPECIAL PROTECTION

chemical goggles faceshield PROTECTIVE EQUIPMENT SKIN (CONTINUED)
impervious gloves complete body covering PROTECTIVE EQUIPMENT INHALATION If exposure limits are exceeded, or if exposure may occur, use a NIOSH/MSHA respirator approved for your conditions of exposure. Refer to the most recent NIOSS publications concerning chemical hazards, or consult your safety equipment supplier. Respiratory protection**pr~ams** must be in**co~liance** with OSHA requirements in 29 CPR 1910.134. For emergencies, a NIOSB/MSHA approved pos1tive pressure breathing apparatus should be readily available.

VENTILATION REQUIRED: Adequate ventilation is required to minimize exposure or to maintain exposure levels below OSHA/ACGIH requirements. Local mechanical ventilation may be required.

ADDITIONAL PROTECTIVE MEASURES· Safety shower. eye wash fountain, and washing facilities should be readily available. In case of**eme~ency** or when dusting, misting, or splashing may occur, wear respiratory protection, eye protect1on, gloves, helmet, boots, and complete protective body covering.

SECTION rv FIRE & EXPLOSION HAZARD DATA Flash Point (METHOD): > OR aN/A Flammable Limits (% Volume in Air) HMIS Info Health 4 Fire 0 React 0 Special X EXTINGUISHING MEDIA UPPER: NID Lower: N/D

media appropriate for surrounding fire 00 not use carbon dioxide. FIRE FIGHTING PROCEDURES Prevent human exposure to fire, fumes, smoke, and products of combustion. Evacuate non essential personnel. Firefighters should wear full face, self contained breathing apparatus and impervious protective clothing.

UNUSUAL FIRE & EXPLOSION HAZARDS Toxic fumes may be released. Cyanides dissolve in water; therefore, cyanide solution runoff may occur if containers are opened or burned. Runoff should be contained to avoid environmental or safety problems. Contained cyanide solution can be detoxified with hypochlorite. SECTION V PHYSICAL DATA

Continued On Page 8 m 1.0 

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tV Ul "- W WHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 8 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237 100# DRUM SECTION V PHYSICAL DATA Boiling Point: 

### N/D Freezing Point: 883 deg. F Specific Gravity (H(2)O=l): > OR 

## = 2.9000 @ Vapor Pressure (MM HG.): N/D Vapor Density (AIR=l) : 

### N/D Evaporation Rate (**~** =1): 

### HID Solubility in Water: NIL Percent Volatile by Volume: NID pH: aqueous approx. N/D Appearance: SOLID

- POWDER, CRYSTAL, FLAKE I GRANULE TABLET, PRILL, BRIQtJETTE, ETC. Odor : PLEASANT SECTION VI REACTIVITY DATA STABILITY 68 deg. F

Stable when stored in container under proper conditions. INCOMPATABILITY Date: 16-NOV-200S 09:45:22.93
(CONTINUED)

inorganic acids organic acids bleaching agents (oxidizers) Water or weak alkaline solution can produce dangerous amounts of poisonous hydrogen cyanide in confined areas. Avoid contact with bleaching agents and oxidizers which include chlorine, oxygen, permanganates, perchlorates, percarbonates, peroxides, chromates, hypochlorites, nitric**acid~** and sulfuric acid. HAZARDOUS DECOMPOSITION PRODUCTS hydrogen cyanide Moisture will cause slow decomposition, releasing poisonous hydrogen cyanide and ammonia gas.

HAZARDOUS POLYMERIZATION will not occur SECTION VII SPILL AND LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: FOR CYANIDE SPILLS: Sweep up and shovel into a covered container or plastic bag, pending transfer, to secure the spill. Cover and keep spillage dry. Flush spill area with dilute solution of sodium hypochlorite or calcium hypochlorite to destroy the cyanide. Complr with Federal, State, and local regulations on reporting releasee. The EPA Reportable Quant 

### ty for sodium or potassium cyanide is 10 pounds.

DISPOSAL METHOD FOR CYANIDE DISPOSAL: This material may be a RCRA Hazardous Waste. Do not flush cyanide into Continued 

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...... W WHarcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEBT Page 9 PRODOCT NAME: COPPER CYANIDE PRODOCT CODE: 11237 SECTION VII SPILL AND LEAK PROCEDURES Date: 16-NOV-200S 09:45:23.39 100# DRUM (CONTINUED)
sewers which may contain an acid. Detoxify with sodium hypochlorite, hydrogen peroxide, or calcium hypochlorite. Comply with Federal, State, and local regulations on disposal methods used to achieve the constituent based treatment standard, 

### if permitted; or transfer to a licnesed disposal contractor. SECTION VIII Proper Shipping Name: Hazard Class: Label Requirements: Reportable Quantity: COPPER CYANIDE 6.1, UN1587, PGII POISON All shipments are reportable SECTION IX ADDITIONAL INFORMATION LABBL SIGNAL WORD DANGER POISON PRECAUTIONS Wear protective equipment when handling. Use only with adequate ventilation. Wash thoroughly after handling. Do Not breathe dust. Do Not breathe vapor, mist I or dust. Do Not breathe gas.

Do Not get in eyes, on skin, or clothing. Do not swallow. HANDLING For industrial use only. ATTENTION: This container hazardous when emptied. Since emptied container contains product residues (vapor or liquid), all labeled hazard precautions must be observed.

STORAGE Keep container closed when not in use. Store in a cool dry place. Store in accordance with NFPA requirements. Keep out of reach of children.

Continued On Page 10 CSl ID 

# .. U1 (1\Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 10 PRODUCT NAME: COPPER CYANIDE PRODUCT CODE: 11237
NAME: GENE TURNER
< '" LESS THAN >
.. MORE THAN 100# DRUM



### N/A 

## = NOT APPLICABLE N/D 

## = NOT DETERMINED NIE = NOT ESTABLISHED Date:**16-NOV~2005** 09:45:23.71

DATE ISSUED: 930121 DATE REVISED: 970107 UNK '" UNKNOWN

The information provided in this Material Saiet¥ data sheet has been obtained from sources believed to be reliable. Harcros Chemicals Inc prov1des no warranties, either expressed or implied and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your information, consideration , and investigation. You should satisfy yourself that you have all current data relevant to your particular use. Barcros Chemicals Inc knows of no medical condition, other than those noted on this material safety data sheet, which are generally recognized as being aggravated by exposure to this product. 

### ,

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### 0,07 06/29/05 PERCBLOROETHYLENE INDUSTRIAL PRODUCT NAME: MSDS NUMBER: DATE ISSUED: SUPERSEDES: ISSUED BY:

PRODUCT NAME: PERCHLOROETHYLENE INDUSTRIAL DW59009 4/15/2002 4/14/2000 008360 This MSDS has been reviewed and is current as of 6/28/2005.

PERCHLOROETBYLENE INDUSTRIAL Distributed by: Univar USA Inc. 6100 Carillon Point Kirkland, WA 98033 425-889-3400 Fax Server

2. COMPOSITION/INFORMATION ON INGREDIENTS TETRACHLOROETHYLENE CAS# 000127-18-4 99.9% 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW 

### ************************************************************************ 

## * COLORLESS LIQUID. IRRITATING ODOR. TOXIC FUMES ARE RELEASED IN 

## * * FIRE SITUATIONS. CAUSES SKIN IRRITATION. B.ARMFUL 

### IF INHALED. 

## * 

## * CAN CAUSE DEATH IF TOO MUCH IS BREATHED. CLEAR ALL PERSONNEL 

## * * FROM AREA. 

### WEAR FULL PROTECTED EQUIPMENT. CONTAIN LIQUID TO 

## * * PREVENT CONTAMINATION OF SOIL, SURFACE WATER OR GROUND WATER. 

## * ************************************************************************ POTENTIAL HEALTH EFFECTS (SEE SECTION 11 FOR TOXICOLOGICAL DATA.) EYE: MAY CAUSE PAIN. MAY CAUSE SLIGHT TRANSIENT (TEMPORARY) EYE IRRITATION. VAPORS MAY IRRITATE THE EYES AT ABOUT 100 PPM PERCHLOROETBYLENE. SKIN: SHORT SINGLE EXPOSURE MAY CAUSE SKIN IRRITATION. PROLONGED OR REPEATED EXPOSURE MAY CAUSE SEVERE SKIN IRRITATION, EVEN A BURN. REPEATED CONTACT MAY CAUSE DRYING OR FLAKING OF SKIN. A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN THE MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. DID NOT CAUSE ALLERGIC SKIN REACTIONS WHEN TESTED IN GUINEA PIGS. INGESTION: SINGLE DOSE ORAL TOXICITY IS CONSIDERED TO BE EXTREMELY LOW. SMALL AMOUNTS SWALLOWED INCIDENTAL TO NORMAL HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY; SWALLOWING AMOUNTS LARGER THAN THAT MAY CAUSE INJURY. IF ASPIRATED (LIQUID ENTERS THE LUNG), MAY BE RAPIDLY ABSORBED THROUGH THE LUNGS AND RESULT IN INJURY TO OTHER BODY SYSTEMS. INHALATION: IN CONFINED OR POORLY VENTILATED AREAS VAPORS CAN READILY ACCUMULATE AND CAN CAUSE UNCONSCIOUSNESS AND DEATH. DIZZINESS MAY OCCUR AT 200 PPM PERCHLOROETBYLENE; PROGRESSIVELY HIGHER LEVELS MAY ALSO CAUSE NASAL IRRITATION, NAUSEA, INCOORDINATION, DRUNKENNESS; AND OVER 1000 PPM, UNCONSCIOUSNESS AND

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DEATH. A SINGLE BRIEF (MINUTES) INHALATION EXPOSURE TO LEVELS ABOVE 6000 PPM PERCHLOROETBYLENE MAY BE IMMEDIATELY FATAL. BASED ON STRUCTURAL ANALOGY AND/OR EQUIVOCAL DATA IN ANIMALS, EXCESSIVE EXPOSURE MAY POTENTIALLY INCREASE SENSITIVITY TO EPINEPHRINE AND INCREASE MYOCARDIAL IRRITABILITY (IRREGULAR HEARTBEATS). ALCOHOL CONSUMED BEFORE OR AFTER EXPOSURE MAY INCREASE ADVERSE EFFECTS. SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE CENTRAL NERVOUS SYSTEM EFFECTS AND ANESTHETIC OR NARCOTIC EFFECTS. OBSERVATIONS IN ANIMALS INCLUDE LIVER AND KIDNEY EFFECTS. CANCER INFORMATION: FOR HAZARD COMMUNICATION PURPOSES UNDER OSHA STANDARD 29 CFR**P~** 1910.1200, THIS CHEMICAL IS LISTED AS A POTENTIAL CARCINOGEN BY IARe AND NTP. PERCBLOROETBYLENE HAS BEEN SHOWN TO INCREASE THE INCIDENCE OF TUMORS IN**CE~AIN** STRAINS OF MICE AND RATS. OTHER LONG-TERM INHALATION STUDIES IN RATS FAILED TO SHOW TUMORIGENIC RESPONSE. HUMAN DATA ARE LIMITED AND HAVE NOT ESTABLISHED AN ASSOCIATION BETWEEN PERCHLOROETBYLENE EXPOSURE AND CANCER. PERCHLOROETBYLENE IS NOT BELIEVED TO POSE A MEASURABLE CARCINOGENIC RISK TO MAN WHEN HANDLED AS RECOMMENDED. TERATOLOGY**(BI~H** DEFECTS):**BI~H** DEFECTS ARE UNLIKELY. EXPOSURES HAVING NO EFFECT ON THE MOTHER SHOULD HAVE NO EFFECT ON THE FETUS. DID NOT CAUSE**BI~H** DEFECTS IN ANIMALS i OTHER EFFECTS WERE SEEN IN THE FETUS ONLY AT DOSES WHICH CAUSED TOXIC EFFECTS TO THE MOTHER. REPRODUCTIVE EFFECTS: IN LABORATORY ANIMAL STUDIES, EFFECTS ON REPRODUCTION HAVE BEEN SEEN ONLY AT DOSES THAT PRODUCED SIGNIFICANT TOXICITY TO THE PARENT ANIMALS. IN ANIMAL STUDIES, BAS BEEN SHOWN NOT TO INTERFERE WITH FERTILITY. 4. FIRST AID EYE: FLUSH EYES**~ITH** PLENTY OF WATER. SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR**TRANSPO~** TO EMERGENCY FACILITY IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE**~IFICIAL** RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. CALL A PHYSICIAN OR**TRANSPO~** TO A MEDICAL FACILITY. NOTE TO PBYSICIAN: BECAUSE RAPID ABSORPTION MAY OCCUR THROUGH LUNGS IF ASPIRATED AND CAUSE SYSTEMIC EFFECTS, THE DECISION OF WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MADE BY A PHYSICIAN. IF LAVAGE IS PERFORMED, SUGGEST ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL. DANGER FROM LUNG ASPIRATION MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH. IF BURN IS PRESENT, TREAT AS ANY THERMAL BURN, AFTER DECONTAMINATION. EXPOSURE MAY INCREASE "MYOCARDIAL IRRITABILITY" • DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY. NO SPECIFIC ANTIDOTE.**SUPPO~IVE** CARE. TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. 5. FIRE FIGHTING MEASURES FLAMMABLE**PROPE~IES** FLASH POINT: NONE

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### METHOD USED: TCC, TOC, COC AUTOIGNITION TEMPERATURE: NONE AVAILABLE. FLAMMABLE LIMITS LFL: NONE. OFL: NONE. BAZARDOUS COMBUSTION PRODUCTS: HAZARDOUS COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO HYDROGEN CHLORIDE. HAZARDOUS COMBUSTION PRODUCTS MAY INCLUDE TRACE AMOUNTS OF PHOSGENE, CHLORINE. OTHER FLAMMABILITY INFORMATION: THIS MATERIAL DOES NOT BURN. CONTAINER MAY VENT AND/OR RUPTURE DUE TO FIRE. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A LONG DISTANCE AND ACCUMULATE IN LOW LYING ARES. VIOLENT STEAM GENERATION OR ERUPTION MAY OCCUR UPON APPLICATION OF DIRECT WATER STREAM. EXTINGUISHING MEDIA: THIS MATERIAL DOES NOT BURN. IF EXPOSED TO FIRE FROM ANOTHER SOURCE, USE SUITABLE EXTINGUISHING AGENT FOR THAT FIRE. MEDIA TO BE AVOIDED: DO NOT USE DIRECT WATER STREAM. FIRE FIGHTING INSTRUCTIONS: KEEP PEOPLE AWAY. ISOLATE FIRE AREA AND DENY UNNECESSARY ENTRY. CONTAIN FIRE RUN-OFF IF POSSIBLE. FIRE WATER RUN-OFF, IF NOT CONTAINED MAY CAUSE ENVIRONMENTAL DAMAGE. DO NOT USE DIRECT WATER STREAM. THIS MATERIAL DOES NOT BURN. FIGHT FIRE FOR OTHER MATERIAL THAT IS BURNING. PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT, PANTS, BOOTS, AND GLOVES. IF PROTECTION EQUIPMENT IS NOT AVAILABLE OR NOT USED, FIGHT FIRE FROM A PROTECTED LOCATION OR SAFE DISTANCE. FOR PROTECTION EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN UP SITUATIONS, REFER TO THE RELEVANT SECTIONS. 6. ACCIDENTAL RELEASE MEASURES (SEE SECTION 15 FOR REGULATORY INFORMATION)

PROTECT PEOPLE: CLEAR ALL PERSONNEL FROM AREA. DO NOT BREATHE VAPORS. VENTILATE AREA OF LEAK OR SPILL. WEAR PROTECTIVE EQUIPMENT INCLUDING POSITIVE PRESSURE SELF CONTAINED OR AIR SUPPLIED BREATHING APPARATUS. FOLLOW CONFINED SPACE ENTRY PROCEDURES: ASTM D-4276 AND OSHA (29 CFR 1910.146). PROTECT ENVIRONMENT: CONTAIN LIQUID TO PREVENT CONTAMINATION OF SOIL, SURFACE WATER OR GROUND WATER. MATERIAL IS HEAVIER THAN WATER AND HAS LIMITED WATER SOLUBILITY. IT WILL COLLECT ON THE LOWEST SURFACE. CLEANUP: FOR LARGE SPILLS: CONTAIN LIQUID; TRANSFER TO PROPERLY LABELED CLOSED METAL CONTAINERS. FOR SMALL SPILLS: MOP OR SOAR UP IMMEDIATELY. PLACE IN PROPERLY LABELED METAL CONTAINERS. 7. HANDLING AND STORAGE HANDLING: TO AVOID UNCONTROLLED EMISSIONS VENT VAPOR FROM CONTAINER TO STORAGE TANK. DO NOT EAT, DRINK, OR SMOKE IN WORKING AREA. REFER TO EXPOSURE CONTROLS/PERSONAL PROTECTION, SECTION 8, OF THE MSDS. CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN VAPORS. DO NOT CUT, DRILL, GRIND, WELD, OR PERFORM SIMILAR OPERATIONS ON OR NEAR EMPTY CONTAINERS. VAPORS 

## . .UI11 Vl:U·**U~A 1111~/~OO~**  

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OF THIS PRODUCT ARB HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS SUCH AS PITS, DEGREASERS, STORAGE TANKS, AND OTHER CONFINED AREAS. DO NOT ENTER THESE AREAS WHERE VAPORS OF THIS PRODUCT ARB SUSPECTED UNLESS SPECIAL BREATHING APPARATUS IS USED AND AN OBSERVER IS PRESENT FOR ASSISTANCE. STORAGE: KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. FOR MORE STORAGE AND HANDLING INFORMATION REFER TO BULLETIN 1#100-06170. STORE IN A DRY PLACE. DO NOT STORE IN ALUMINUM, ZINC, ALUMINUM ALLOYS AND PLASTICS. PRODUCT SHOULD NOT BE PACKAGED IN ALUMINUM AEROSOL CANS OR WITH FINELY DIVIDED ALUMINUM OR ITS ALLOYS IN AN AEROSOL CAN. PRODUCT IS DENSER THAN WATER. DESIGN STORAGE CONTAINERS APPROPRIATELY. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES. LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR VENTILATION. PERSONAL PROTECTIVE EQUIPMENT EYE/FACE PROTECTION: USE SAFETY GLASSES. IF VAPOR EXPOSURE CAUSES EYE**DISCOMFO~,** 

### USE A FULL-FACE RESPIRATOR. SKIN PROTECTION: USE PROTECTIVE CLOTHING IMPERVIOUS TO THIS MATERIAL. SELECTION OF SPECIFIC ITEMS SUCH AS FACESHIELD, GLOVES, BOOTS, APRON, OR FULL BODY SUIT WILL DEPEND ON OPERATION. RESPIRATORY PROTECTION: ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN APPROVED AIR-PURIFYING OR POSITIVE-PRESSURE SUPPLIED-AIR RESPIRATOR DEPENDING ON THE POTENTIAL AIRBORNE CONCENTRATION. FOR EMERGENCY AND OTHER CONDITIONS WHERE THE EXPOSURE GUIDELINE MAY BE GREATLY EXCEEDED, USE AN APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS OR POSITIVE-PRESSURE AIRLINE WITH AUXILIARY SELF-CONTAINED AIR SUPPLY. IN CONFINED OR POORLY VENTILATED AREAS, USE AN APPROVED POSITIVE-PRESSURE SUPPLIED-AIR RESPIRATOR. EXPOSURE GUIDELINE (S) : PERCHLOROETHYLENE (TETRACHOROETHYLENE): ACGIH TLV IS 25 PPM TWA, 100 PPM STEL, A3. OSHA PEL IS 25 PPM. PELS ARB IN ACCORD WITH THOSE RECOMMENDED BY OSHA, AS IN THE 1989 REVISION OF PELS. 9. PHYSICAL AND CHEMICAL**PROPE~IES** 

### APPEARANCE: COLORLESS LIQUID. ODOR: IRRITATING ODOR VAPOR PRESSURE: 13 MMBG @ 

### 20C VAPOR DENSITY: 5.76 BOILING POINT: 250F (121.1C) SOLUBILITY IN WATER: 0.015 G/100G 25C SPECIFIC GRAVITY: 1.619 @

### 25/25C 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE SECTION. CONDITIONS TO AVOID: AVOID DIRECT SUNLIGHT OR ULTRAVIOLET SOURCES. AVOID OPEN FLAMES, WELDING ARCS, OR OTHER HIGH TEMPERATURE SOURCES WHICH INDUCE THERMAL DECOMPOSITION. HIGH ENERGY SOURCES SUCD AS WELDING ARCS CAN CAUSE DEGRADATION

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GENERATING CHLORINE, HYDROGEN CHLORIDE AND POSSIBLE PHOSGENE, AND SHOULD BE AVOIDED. INCOMPATIBILITY WITH OTHER MATERIALS: AVOID CONTACT WITH METALS SUCH AS: ALUMINUM POWDERS, MAGNESIUM POWDERS, POTASSIUM, SODIUM, AND ZINC POWDER. AVOID UNINTENDED CONTACT WITH AMlNES. AVOID CONTACT WITH STRONG BASED AND STRONG OXIDIZERS. AVOID PROLONGED CONTACT WITH OR STORAGE IN ALUMINUM OR ITS ALLOYS. HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS DECOMPOSITION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO HYDROGEN CHLORIDE AND TRACE AMOUNTS OF CHLORINE AND PHOSGENE. RAZAlIDOUS POLYMERIZATION: WILL NOT OCCUR. 11. TOXICOLOGICAL INFORMATION (SEE SECTION 3 FOR POTENTIAL HEALTH EFFECTS. FOR DETAILED TOXICOLOGICAL DATA, WRITE OR CALL THE ADDRESS OR NON-EMERGENCY NUMBER SHOWN IN SECTION 1) SKIN: THE LD50 FOR SKIN ABSORPTION IN RABBITS IS 

## > 10 G/KG. INGESTION: THE ORAL LDSO FOR RATS IS 

### > 5000 MG/KG. MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): IN VITRO MUTAGENICITY STUDIES WERE NEGATIVE. ANIMAL MUTAGENICITY STUDIES WERE NEGATIVE. 12. ECOLOGICAL INFORMATION (FOR DETAILED ECOLOGICAL DATA, WRITE OR CALL THE ADDRESS OR NON-EMERGENCY NUMBER SHOWN IN SECTION 1) ENVIRONMENTAL FATE MOVEMENT , PARTITIONING: BIOCONCENTRATION POTENTIAL IS LOW (BCF LESS THAN 100 OR LOG POW LESS THAN 3). BIOCONCENTRATION FACTOR (BCF) IS 49 IN THE BLUEGILL. BIOCONCENTRATION FACTOR (BCF) IS 38. 9 IN THE TROUT. LOG OCTANOL/WATER PARTITION COEFFICIENT (LOG POW) IS 3.4. POTENTIAL FOR MOBILITY IN SOIL IS MEDIUM (KOC BETWEEN 150 AND SOO). LOG SOIL ORGANIC CARBON PARTITION COEFFICIENT (LOG KOC) IS ESTIMATED TO BE 2.1-3.2. HENRY'S LAW CONSTANT (H) IS 1.49E-02 ATM-M3/MOL. LOG AIR/WATER PARTITION COEFFICIENT (LOG KAW) IS ESTIMATED TO BE -0.30 TP 0.37. DEGRADATION' PERSISTENCE: BIODEGRADATION UNDER AEROBIC CONDITIONS IS BELOW DETECTABLE LIMITS. THEORETICAL OXYGEN DEMAND (THOD) IS CALCULATED TO BE 0.19 PIP. BIODEGRADATION MAY OCCUR UNDER ANAEROBIC CONDITIONS (IN THE ABSENCE OF OXYGEN). DEGRADATION IS EXPECTED IN THE ATMOSPHERIC ENVIRONMENT WITHIN DAYS TO WEEKS. BIODEGRADATION RATE MAY INCREASE IN SOIL AND/OR WATER WITH ACCLIMATION. ECOTOXICOLOGY: MATERIAL IS MODERATELY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS (LCSO BETWEEN 1 AND 10 MG/L IN MOST SENSITIVE SPECIES). ACUTE LCSO FOR JAPANESE MEDAKA OR RICE FISH (ORYZIAS LATIPES) IS 1. 

### 6 MG/L. ACUTE LCSO FOR WATER FLEA (DAPHNIA MAGNA) IS 3.2-123 MG/L. ACUTE LCSO FOR RAINBOW TROUT (ONCORHYNCHUS MYKISS) IS 4.8-5.8 MG/L. ACUTE LC50 FOR SHEEPSHEAD MINNOW (CYPRINODON VAEaEGATUS) IS 8.0-52.2 MG/L. ACUTE LC50 FOR AMERICAN FLAGFISH JORDENELLA FLORIDAE IS 8.4- 24 MG/L. ACUTE LCSO FOR BLUEGILL (LEPOMIS MACROCHIROS) IS 13 MG/L. ACUTE LCSO FOR FATHEAD MINNOW (PIMEPBALES PROMELAS) IS 13.4-23-8 MG/L. MAXIMUM ACCEPTABLE TOXICANT CONCENTRATION (MATC) IS 3.1 MG/L IN AMERICAN FLAGFISH.

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, 

# . 13. DISPOSAL CONSIDERATIONS (SEE SECTION 15 FOR REGULATORY INFORMATION) DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. ALL DISPOSAL METHODS MOST BE IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY IN DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR. THE VENDOR BAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF**P~IES** 

### HANDLING OR USING THIS MATERIAL

.. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2 (COMPOSITION/INFORMATION ON INGREDIENTS). FOR UNUSED & 

### UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS INCLUDE SENDING TO A LICENSED, PERMITTED RECYCLER, RECLAlMER, INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE. 14. TRANSPORT INFORMATION DEPARTMENT OF TRANSPORTATION (D.O.T.): FOR D.O.T. REGULATORY INFORMATION, IF REQUIRED, CONSULT TRANSPORTATION REGULATIONS, PRODUCT SHIPPING PAPERS OR CONTACT YOUR VENDOR REPRESENTATIVE. CANADIAN TDG INFORMATION: FOR TOG REGULATORY INFORMATION, IF REQUIRED, CONSULT**TRANSPO~TION** 

### REGULATIONS, PRODUCT SHIPPING PAPERS OR CONTACT YOUR VENDOR REPRESENTATIVE. 15. REGULATORY INFORMATION (NOT MEANT TO BE ALL-INCLUSIVE--SELECTED REGULATIONS REPRESENTED) NOTICE: THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED IS GIVEN. REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE**LO~ION** 

### TO ANOTHER; IT IS THE BUYER'S RESPONSIBILITY TO ENSURE THAT ITS ACTIVITIES COMPLY WITH FEDERAL, STATE OR PROVINCIAL, AND LOCAL LAWS. THE FOLLOWING SPECIFIC INFORMATION IS MADE FOR THE PURPOSE OF COMPLYING WITH NUMEROUS FEDERAL, STATE OR PROVINCIAL, AND LOCAL LAWS AND REGULATIONS. SEE OTHER SECTIONS FOR HEALTH AND SAFETY INFORMATION. SARA 313 INFORMATION: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 eFR PART 

### 372: CHEMICAL NAME CAS NUMBER CONCENTRATION PERCHLOROETBYLENE 000127-18-4 99.9

SARA HAZARD CATEGORY: THIS PRODUCT BAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES" PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: AN IMMEDIATE HEALTH HAZARD A DELAYED HEALTH HAZARD

CALIFORNIA PROPOSITION 65: THE FOLLOWING STATEMENT IS MADE IN ORDER TO**un~va.r U~A**  11116/Z005 

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### COMPLY WITH THE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.

TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE LISTED ON THE TSCA INVENTORY.

STATE RIGHT-TO-KNOW: THE FOLLOWING PRODUCT COMPONENTS ARE 

### CITED ON**CE~IN** 

### STATE LISTS AS MENTIONED. NON-LISTED COMPONENTS MAY BE SHOWN IN THE COMPOSITION SECTION OF THE MSDS. CHEMICAL NAME CAS 

### NUMBER LIST PERCHLOROETHYLENE 000127-18-49 NJl NJ2 NJ3 PAl PA2 PA3 NJ1=NEW JERSEY SPECIAL HEALTH HAZARD 

### SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 0.1%). NJ2=NEW JERSEY ENVIRONMENTAL HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 1.0%). NJ3=NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 1.0%). PA1=PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 1.

### 0%)

. PA2=PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 0.01%). PA3=PENNSYLVANIA ENVIRONMENTAL HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 1.0%).

OSHA HAZARD COMMUNICATION STANDARD: THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200.

COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT (CERCLA, OR SUPERFUND) : THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCE(S) LISTED AS "HAZARDOUS SUBSTANCES" UNDER CERCLA WHICH MAY REQUIRE REPORTING OF RELEASES: CATEGORY: CHEMICAL NAME CAS' 

### RQ % IN PRODUCT
PERCHLOROETHYLENE 000127-18-4 100 99.9



### CANADIAN REGULATIONS ===================== 

### WBMIS INFORMATION: THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WBMIS) CLASSIFICATION FOR THIS PRODUCT IS:

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D1B

- POISONOUS SUBSTANCE DEFINED BY TOG REGULATIONS D2A

- POSSIBLE, PROBABLE OR KNOWN SUMAN CARCINOGEN ACCORDING TO CLASSIFICATIONS BY IARe OR ACGIH D2B

- EYE OR SKIN IRRITANT REFER ELSEWHERE IN THE MSDS FOR SPECIFIC WARNINGS AND SAFE HANDLING INFORMATION. REFER TO THE EMPLOYER'S WORKPLACE EDUCATION PROGRAM. CPR STATEMENT: THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. HAZARDOUS PRODUCTS ACT INFORMATION: THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS walCH ARE CONTROLLED PRODUCTS AND/OR ON THE INGREDIENT DISCLOSURE LIST (CANADIAN BPA SECTION 13 AND 14): COMPONENTS: CAS 

### II AMOUNT (%W/W) TETRACHLOROETHYLENE 000127-18-4 99.9%

16. OTHER INFORMATION HAZARD RATING SYSTEM: NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS: HEALTH 2 FLAMMABILITY 0 REACTIVITY 0 DISPOSAL OF CONTACT WATER: PROCESS WATER IN CONTACT WITH SOLVENT AND/OR WATER SEPARATORS OF CLEANING OR DISTILLATION EQUIPMENT SHOULD BE TREATED AS HAZARDOUS WASTE. DO NOT DISCHARGE WATER FROM WATER SEPARATORS TO DRAIN. GENERAL APPLICATION GUIDELINES: VENDOR DOES NOT RECOMMEND THE USE OF THIS PRODUCT IN APPLICATIONS WHERE:

- SOIL OR GROUND WATER CONTAMINATION IS LIKELY (DIRECT APPLICATIONS TO THE GROUND, SINK DRAINS, SEWERS, OR SEPTIC TANKS) •



### - WHERE OVER EXPOSURE IS LIKELY (SMALL ROOMS OR CONFINED SPACE, OR WHERE THERE WOULD BE INADEQUATE VENTILATION)

.

- WHERE SKIN CONTACT IS LIKELY (ADHESIVE TAPE REMOVAL FROM SKIN OR AS BAND CLEANER TO REMOVE OILS AND GREASES).

- WHERE THERE IS DIRECT FOOD CONTACT.

- WHERE VAPOR CONCENTRATIONS WOULD BE IN THE FLAMMABLE RANGE.

- WHERE DISPOSAL OF WASTE WOULD POSE AN ENVIRONMENTAL OR HEALTH RISK.

- WHERE CHEMICAL REACTIVITY POSES A DANGER (CONTACT WITH STRONG ALKALI, OR IN AREAS WHERE WELDING IS DONE). MSDS STATUS: NO REVISIONS. REVIEWED FOR CANADIAN REGULATIONS.

-------------------------- FOR ADDITIONAL INFORMATION

-------------------------- CONTACT: MSDS COORDINATOR UNIVAR USA INC. DURING BUSINESS HOURS, PACIFIC TIME (425)889-3400

------------------------------------ NOTICE

------------------------------------ 

## *********** UNIVAR USA INC ("UNIVARII) EXPRESSLY DISCLAIMSUnivar USA**11/1~/~UU~ ~:~/:~~** **~ ~** **~~u~ ~V/V~V**  

### ALL EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A
PARXICULAR PURPOSE, WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN,
AND SHALL UNDER NO CIRCUMSTANCES BE LIABLE FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES.**
DO NOT USE INGREDIENT INFORMATION AND/OR INGREDIENT PERCENTAGES IN THIS MSDS AS A PRODUCT SPECIFICATION. FOR PRODUCT SPECIFICATION INFORMATION REFER TO A PRODUCT SPECIFICATION SHEET AND/OR A**CE~IFI~E** 

### OF ANALYSIS. THESE CAN BE OBTAINED FROM YOUR LOCAL UNlVAR SALES OFFICE. ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMATION IS BELIEVED TO BE ACCURATE, UNIVAR MARES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND UNIVARS CONTROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR**P~ICULAR** 

### PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICATION OR USE OF, OR RELIANCE UPON , INFORMATION CONTAINED HEREIN. THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS. * * * END 0 F M S D S * * *Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 1



## -------------------------------------------------------------------------------------------------- PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 CAS #: 000143339 FORMULA: Na C N CHEM. FAMILY: inorganic salts CHEMICAL NAME AND SYNONYMS: Sodium Cyanide; Cyanide of Sodium; Prussiate of Soda; MSDS 001764 DETAIL 00165 Date: S-JAN-1999 12:01:13.63 220# DRUM-BR MSDS No. 001764 Revision No./Date 02 970107 Detail Number 00165/01

SUPPLIERS NAME: Harcros Chemicals Inc. 5200 Speaker Road Kansas City KS 66106-1095 SUPPLIERS PHONE NUMBER : 913-321-3131 TRANSPORTATION EMERGENCY PHONE NUMBER : 1-800-424-9300 S.A.R.A. INFORMATION HAZARDS : Acute PHYSICAL DATA :. Pure Reactivity Solid SECTION I HAZARDOUS INGREDIENTS



### --------------------------------.------ -----------.--------------------------------------------. Ingredient Cas Number
Sodium Cyanide Prussiate of Soda (CAS # 143-33-9

SECTION II HEALTH HAZARDS POTENTIAL EFFECTS OF EXPOSURE EYES MAX %' 

## w/w 100.0 SARA APPLIES 312 313 372 AIR CONTAMINENT LEVELS

Y Y

# _~1~f;r~

# __**I---~~~;r---I---~;~~:--I~~~~I~~~~** Y As Cyanide TWA/TLV 5 mg/m3 OSHA CEILING 5 mg/m3 ACGIH DESIGNATED SKIN HAZARD OSHA/ACGIH 

# ----------1-----------1----------1----1-----

Eye contact with product may cause irritation burns irreversible damage even death

SKIN Skin contact may cause irritation burns even death Absorption thru skin may cause symptoms described under inhalation and ingestion.

INHALATION Inhalation may cause headache dizziness nausea breathing difficulty vomiting unconsciousness

convulsions even death Continued On Page 2 

# ..Harcros Chemicals Inc Kansas City, Kansas f4ATERIAL SAFETY DATA SHEET Page 2 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 SECTION II HEALTH HAZARDS

INGESTION Date: 5-JAN-1999 12:01:14.69 220# DRUM-BR (CONTINUED) Ingestion may cause headache dizziness nausea breathing difficulty vomiting unconsciousness

convulsions even death TARGET ORGANS OVEREXPOSURE MAY CAUSE DAMAGE TO, DISORDERS OF, OR ADVERSELY AFFECT THE FOLLOWING SYSTEMS, FUNCTIONS, ORGANS: blood pressure FIRST AID FIRST AID EYES FOR CYANIDE EXPOSURE: Immediately flush eyes with plenty of water, remove contaminated clothing, and keep patient quiet and warm. If symptoms of cyanide exposure occur, see first aid for skin, below. Call a physician.

FIRST AID SKIN FOR CYANIDE EXPOSURE: Wash skin promptly to remove the cyanide while removing all contaminated clothing, including shoes. Do not delay. Skin absorption can occur from cyanide dust, solutions, or HCN vapor. Absorption 

### is slower than inhalation, usually measured in m1nutes compared to seconds for inhalation. Patient should be watched for at least 1 to 2 hours because absorbed cyanide can continue to work into the bloodstream. Wash clothing before reuse and destroy contaminated shoes. Call a physician. UNCONSCIOUS BUT BREATHING: Break an amyl nitrite ampule 1n a cloth and hold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 minutes until the patient regains consciousness (usually 1-4 ampules). Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, cons1der holding the amyl nitrite under the nose continuously for the first ampule or more. Call a physician. NOT BREATHING: Give artificial respiration (100% oxygen), preferably with an oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule inside the resuscitator face piece,**bein~** careful that the ampule does not enter the patient's mouth and cause choking. Give oxygen s1multaneously. Call a physician.

FIRST AID INHALATION FOR CYANIDE EXPOSURE: Carry patient to fresh air. Lay**~atient** down. Administer oxygen and amyl nitrite. Keep patient quiet and warm. Even with inhalat10n poisoning,**thorou~hly** check clothing and skin to assure no cyanide is present. Call a physician. Rescuers of pat1ents in an HCN environment should wear SCBA equipment. CONSCIOUS: For inhalation and/or absorption if the patient is alert, oxygen may be all that is needed. But if the patient is not fully conscious or shows signs of**poisonin~,** see below. Call a physician. UNCONSCIOUS BUT BREATHING: Break an amyl n1trite ampule in a cloth and hold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 minutes until the patient regains consciousness (usually 1-4 ampules)

.

Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, consider**holdin~** the amyl nitrite under the nose continously for the first ampule or more. Call a physic1an. NOT BREATHING: Give artificial respiration (100% oxygen), preferably with an oxygen resuscitator. Give amrl nitrite antidote by placing a broken ampule inside the resuscitator face piece, being carefu that the ampule does not enter the patient'S mouth and cause choking. Give oxygen simultaneously. Call a physician.

FIRST AID INGESTION FOR CYANIDE EXPOSURE: Conscious: Immediately give patient one pint of 1% sodium thiosulfate Continued On Page 3Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 3 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 SECTION II HEALTH HAZARDS Date: 5-JAN-1999 12:01:15.63 220# DRUM-BR (CONTINUED) solution (or plain water) by mouth and induce vomiting by having patient stick finger into throat.**Re~eat** until vomit fluid is clear. Never give anything by mouth to an unconscious person. G1ve oxygen. Call a physician. UNCONSCIOUS BUT BREATHING: Break an amyl nitrite ampule in a cloth and hold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 minutes until the patient regains consciousness (usually 1-4 ampules). Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, consider holding the amyl nitrite under the nose continuously for the first ampule or more. Call a physician. NOT BREATHING: Give artificial respiration (100% oxygen),**~referably** with an oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule 1nside the resuscitator face piece, being careful that the ampule does not enter the patient's mouth and cause choking. Give oxygen simultaneously. Call a physician.

OTHER INFORMATION NOTES TO PHYSICIAN MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Medical treatment is normally provided by a physician, but might be provided by a professionally trained "qualified medical personII where a need exists and where State and local laws permit. Specific training for handling cyanide poisoning emergencies is essential, as well as being "in practice" for giving intravenous injections. Du Pont trains all personnel working with cyanide to use the first aid**~rocedures,** but not the medical treatment**~rocedure.** While**preparin~** for sod1um nitrite and sodium thiosulfate inject10ns, use amyl nitrite and oxygen as outl1ned in First Aid. When ready and if the patient is not responding to first aid, first inject the solution of sodium nitrite (10 mI. of a 3% solution) intravenously at the rate of 2.5 mL/minute, then immediately inject the sodium thiosulfate (50 mL of a 25% solution) at the same rate, taking care to avoid extravasation. This is a fairly lengthy treatment (24 minutes) since a total of 10 + 50, or 60 mL, is injected at a rate of 2.5 mL per minute. Consideration should be given to the size and condition if the patient as treatment is proceeding. The above sodium nitrite injection is about 1/3 of a lethal dose (see below), so care should be taken to avoid excessive use. It is not essential that full quantities be given, just because treatment was started. Injections can be stopped at any point if recovery is evident, but be sure to keep track of quantities administered in case treatment needs to be restarted.**Rela~se** is abnormal if cyanide intake is not continuing, unless a large intake from**swallow1n~** occurred. Don't overreact. While prompt treatment is essential where poison1ng has occurred, treatment of a lucid, conscious patient would rarely be necessary. The effects of cyanide**~oisoning** are immediate, not delayed, and a conscious person that can communicate does not have s1gnificant cyanide poisoning. For most accidental poisoning, complete recovery occurs within 1-2 hours. If cyanide exposure was severe, watch patient continuously for 24-48 hours. If there is any return of**sym~toms** during this period, consider repeating this treatment using one half the amounts of sod1um nitrite and sodium thiosulfate solutions. Blood chemistry should monitored during prolonged treatment. Caution should be used to prevent overuse of medical treatment chemicals as the prescribed dose is about 1/3 the lethal dose for an average individual. The nitrite converts hemoglobin to methemoglobin which reduces the oxygen carrying capacity of the blood. This is done purposely as methemoglobin attracts cyanide away from the body cells, but nitrite use must be limited to prevent hemoglobin deficiency. Du Pont has not experienced nitrite overdose problems; but being alert to this is important information to medical personnel.

Continued On Page 4 :

### Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET page 4



### -------------------------------------------------------------------------------------------------- PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 

### Date: 5-JAN-1999 12:01:16.63 220# 

### DRUM-BR



## -------------------------------------------------------------------------------------------------- SECTION II HEALTH HAZARDS 

### (CONTINUED) If signs of excess methemoglobinemia develop (i.e., blue skin and mucous membranes, vomiting, shock and coma), 1t 

### methylene blue solution should be given intravenously. Administering up to a 1 

### to 2 mg/kg of body weight over a period of five to ten minutes should be considered and repeated in one hour if necessary. NOTE: This procedure can free cyanide from cyanomethemoglobin. The free cyanide can again bind with cytochrome oxidase and, therefore, repoison the patient. If methylene blue is used, it must be used verr carefully. It is best to avoid overuse of nitrite so corrective action is not needed. Histor1cally, Du Pont has not had to use methylene blue to counter excess nitrite use. In addition, oxygen inhalation will be helpful. Transfusion of whole fresh blood may be considered if there has been mechanical injury with external bleeding and simultaneous cyanide exposure. When handling potential cyanide poisoning emergencies, keep in mind: 1. 

### Cyanide acts rapidly, usually within seconds once it enters the bloodstream. Delayed effects would only be expected during brief periods (e.g., up to about 20 

### minutes) when (a) cyanide was absorbed into the bloodstream from the stomach after ingestion or (b) absorption through the skin occurred prior to skin washing, but entry into the blood was not complete. In treatment, therefore, treat what you see; don't overreact. It's rare when "preventive" use of the antidotes would be warranted. If you can converse normally with the patient, cyanide intake is limited and no action is called for other than to closely monitor the patient and keep him calm by reassurance of his condition during the following 20-30 minute period. 2. The half-life of cyanide in the body is estimated at 20-90 minutes. The body routinely destroys cyanides from foods, cigarette smoke, etc. so cyanide is not a cumulative poison. In case of accidental cyanide intake, normal body action guickly begins cyanide destruction. In diagnosis and monitor1ng as mentioned in item 1, the cr1tical**~eriod** 

### is therefore short. Normally what happens in the initial few minutes after exposure will 1ndicate the degree of poisoning. Du Pont's experience in treating cyanide poison cases is that first aid procedures using oxygen and amyl nitrite were effective and the only treatment needed in most cases. Medical treatment, using intravenous injections, was used in a few cases. Both procedures have been successful. For further information, see Du Pont Sodium Cyanide Storage and Handling Bulletin.

ROUTES OF ENTRY eye contact skin contact skin absorption inhalation ingestion OVEREXPOSURE MAY AGGRAVATE DISORDERS OF THE central nervous system CARCINOGEN STATUS No components, present in excess of O.lt 

### by weight are listed as carcinogens by IARC, NTP, or OSHA.



### EXTRA INFORMATION FIRST AID MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Treatment for cyanide**~oisoning** 

### can be provided in two ways, "First Aid" and "Medical Treatment". Both require 1mmediate action to prevent further harm or death. First aid using oxygen and amyl nitrite is generally given by a layman before trained medical help arrives. Medical treatment is aggressive treatment involving intravenous injections of sodium nitrite and sodium thiosulfate, and must be administered by qualified medical personnel. Even if a doctor or nurse is present, the need for fast treatment dictates using first aid treatment with oxygen and amyl nitrite while medical treatment materials for intravenous injection are being prepared. Experience shows that first aid given**~romptly** 

### is usually the only treatment needed for typical accidental poisonings. Larger cyanide 1ntake

Continued On Page 5Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 5 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 SECTION II HEALTH HAZARDS Date: 5-JAN-1999 12:01:17.86 220# DRUM-BR (CONTINUED) increases the need for medical treatment. Medical treatment is given if the patient does not respond to first aid. It provides a large quantity of antidote including sodium thiosulfate to chemically destroy cyanide in the body. However, even under optimum conditions, amyl nitrite can be administered faster and should be used even if medical treatment follows. Always have on hand the materials listed below. FIRST AID AND MEDICAL TREATMENT KITS. Actions to be taken in case of cyanide exposure should be planned and practiced before beginning work with cyanides. In most cases, cyanide poisoning causes a deceptively healthy pink to red skin color; however; if a physical injury or lack of oxygen is involved, the skin color may be bluish. Reddening of the eyes and pupil dilation are also symptoms cyanide**~oisoning.** Workers should be trained to provide immediate first aid using oxygen and amyl n1trite resuscitators. In case of cyanide poisoning, start first

a1d treatment immediately, then call a physician. FIRST AID SUPPLIES FOR CYANIDE EXPOSURE: Adequate first aid supplies for cyanide poisoning should be conveniently placed throughout cyanide areas and should be immediately accessible at all times. They should be routinely inspected (typically daily) by people who would use them in an emergency. The total number of each item listed below should be adequate to handle the largest number of exposure cases reasonably anticipated, taking into account that some supplies may be wasted, destroyed, or

inaccessible in the emergency. 1. Oxygen Resuscitators-The Flynn Series III Model by O-Two Systems (800-387-3405) has performed well in Du Pont use. It is lightweight, rugged, and easy to use. 2. Amyl Nitrite Ampules (antidote)-One box of one dozen ampules per station is usually satisfactorr' Locate stations throughout the cyanide area. CAUTION: Amyl Nitrite is not stab e and must be replaced every 1 to 2 years. Store in the original dated box, away from heat. A common Du Pont practice is to use the resuscitator as the storage point for the amyl nitrite ampUles. Avoid storage on vehicles where temperatures can reach 140-150 deg F or more. 3. A set of cyanide first aid instructions should be located at each amyl nitrite storage location. Workers should be fully trained since in a real emergency there will be insufficient time to "read the book". 4. Two 1-pint bottles of 1% sodium thiosulfate solution for use in case of cyanide ingestion or plain water can be used. AMYL NITRITE NOTES FOR CYANIDE EXPOSURE: 1. Amyl nitrite is highly volatile and flammable, do not smoke or use around source of ignition. 2. If treating patient in a windy or drafty area, provide something-a rag, shirt, wall, drum, cupped hand, etc,-to prevent the amyl nitrite vapors from being blown away. Keep the ampule upwind from the nose. The objective is to get amyl nitrite into the patient's lungs. 3. Rescuers should avoid amyl nitrite inhalation so they won't become dizzy and lose**co~etence.** 4. Lay the patient down for treatment to mainta1n a good blood supply to the pat1ent's head. Since amyl nitrite dilates the blood vessels and lowers blood pressure, lying down will help prevent unconsciousness. MEDICAL TREATMENT KITS FOR CYANIDE EXPOSURE: Medical Treatment Kits for cyanide poisoning should be conveniently located for easy access by medical**~eople.** Materials for intravenous injection are intended for use only by a physician or fully qual1fied medical personnel. The location of kits should be carefully planned as part of the emergency**~replan.** Suggested locations for kits include:

- in or near the cyanide area - plant med1cal station

- entrance guard house

- local hospital

- doctor's office and residence CAUTION: Do not store amyl nitrite or Medical Treatment Kits on vehicles as heat build-up may ruin the amyl nitrite. Kits and amyl nitrite should be accessible but secured against tampering. They should be inspected regularly and the amyl nitrite ampules replaced every 1-2 years.

Continued On Page 6 :Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 6 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 Date: s-JAN-1999 12:01:19.11 220# DRUM-BR SECTION II HEALTH HAZARDS (CONTINUED) Medical Treatment Kits should contain the following: 1. One box containing one dozen amyl nitrite ampules. 2. Two sterile ampules of sodium nitrite solution (10 mL of a 3% solution in each). 3. Two sterile**am~ules** of sodium thiosulfate solution (SO mL of a 2st solution in each)

. 4. One 10 ml**ster~le** syringe. One SO mL sterile styringe. Two sterile intravenous needles. One tourni9Uet. s. One stomach tube. 6. One dozen gauze pads. 7. A set of cyanide**~nstructions** on first aid and medical treatment. NOTE: "Amyl Nitrite" and "Medical Treatment Kits" can be purchased through local pharmacies with a physician's**~rescription.** As a help, you can inform the pharmacist that Eli Lilly and Co. produces the**k~t.**

SECTION III SPECIAL PROTECTION PROTECTIVE EQUIPMENT PROTECTIVE EQUIPMENT EYES chemical goggles faceshield PROTECTIVE EQUIPMENT SKIN impervious gloves complete body covering PROTECTIVE EQUIPMENT INHALATION If exposure limits are exceeded, or if exposure may occur, use a NIOSH/MSHA respirator approved for your conditions of exposure. Refer to the most recent NIOSH publications concerning chemical hazards, or consult your safety equipment supplier. Respiratory protection programs must be in**com~liance** with OSHA requirements in 29 CFR 1910.134. For emergencies, a NIOSH/MSHA approved**pos~tive** pressure breathing apparatus should be readily available.

VENTILATION REQUIRED: Adequate ventilation is required to minimize exposure or to maintain exposure levels below OSHA/ACGIH requirements. Local mechanical ventilation may be required.

ADDITIONAL PROTECTIVE MEASURES Safety shower, eye wash fountain, and washing facilities should be readily available. In case of emergency or when dusting, misting, or splashing may occur, wear respiratory protection, eye protection, gloves, helmet, boots, and complete protective body covering.

SECTION IV FIRE & EXPLOSION HAZARD DATA
Flash Point (METHOD): > OR**~** N/A Flammable Limits (t Volume in Air) HMIS Info Health 3 Fire 0 React 1 Special X EXTINGUISHING MEDIA UPPER: N/D Lower: N/D

media appropriate for surrounding fire Do not use carbon dioxide. FIRE FIGHTING PROCEDURES Prevent human exposure to fire, fumes, smoke, and products of combustion. Evacuate non Continued On Page 7Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 7 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 SECTION IV FIRE 

### & EXPLOSION HAZARD DATA Date: 5-JAN-1999 12:01:20.30 220# DRUM-BR (CONTINUED) essential personnel. Firefighters should wear full face, self contained breathing apparatus and impervious protective clothing.

UNUSUAL FIRE 

### & EXPLOSION HAZARDS Toxic fumes may be released. Cyanides dissolved in water; therefore, cyanide solution runoff may occur if containers are opened or burned. Runoff should be contained to avoid environmental or safety problems. Contained cyanide solution can be detoxified with hypochlorite. SECTION V PHYSICAL DATA Boiling Point: > OR 

## = 2725 deg. F Freezing Point: 1047 deg. F Specific Gravity (H(2)O=1): > OR = 1.0600 @ Vapor Pressure (MM HG.): 

### NID Vapor Density (AIR=l) : 

### NID Evaporation Rate ( NA =1): 

### NID Solubility in Water: 37% Percent Volatile by Volume: > OR 999.00 pH: aqueous approx. 11.300 to 11.700 Appearance: SOLID

- POWDER, CRYSTAL, FLAKE, GRANULE TABLET, PRILL, BRIQUETTE, ETC. Odor : SHARP
SECTION VI REACTIVITY DATA STABILITY 68 deg. F

Stable when stored in container under proper conditions. INCOMPATABILITY inorganic acids organic acids bleaching agents (oxidizers) Water or weak alkaline solution can produce dangerous amounts of poisonous hydrogen cyanide in confined areas. Avoid contact with bleaching agents and oxidizers which include chlorine, oxygen, permanganates, perchlorates, percarbonates, peroxides, chromates, hypochlorites, nitric acid, and sulfuric acid. HAZARDOUS DECOMPOSITION PRODUCTS hydrogen cyanide Moisture will cause slow decomposition, releasing poisonous hydrogen cyanide and ammonia gas.

HAZARDOUS POLYMERIZATION Will not occur SECTION VII SPILL AND LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: FOR CYANIDE SPILLS: Sweep up and shovel into a covered container or plastic bag, pending Continued On Page 8**.~**

### Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 8 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887 SECTION VII SPILL AND LEAK PROCEDURES Date: 5-JAN-1999 12:01:21.51 220# DRUM-BR (CONTINUED) transfer, to secure the spill. Cover and keep spillage dry. Flush spill area with dilute solution of sodium hypochlorite or calcium hypochlorite to destroy the cyanide. Comply with Federal, State, and local regulations on reporting releases. The EPA Reportable Quant1ty is 10 lb.

DISPOSAL METHOD FOR CYANIDE DISPOSAL: This material may be a RCRA Hazardous Waste. Do not flush cyanide into sewers which may contain an acid. Detoxify with sodium hypochlorite, hydrogen peroxide, or calcium hypochlorite. Comply with Federal, state, and local regulations on disposal methods used to achieve the constituent based treatment standard, if permitted; or transfer to a licnesed disposal contractor. SECTION VIII Proper Shipping Name: Hazard Class: Label Requirements: Reportable Quantity: SODIUM CYANIDE 6.1, UN1689, PGI POISON All shipments are reportable SECTION IX ADDITIONAL INFORMATION LABEL SIGNAL WORD DANGER POISON PRECAUTIONS Wear protective equipment when handling. Use only with adequate ventilation. Wash thoroughly after handling. Do Not breathe dust. Do Not breathe vapor or mist. Do Not breathe gas.

Do Not get in eyes, on skin, or clothing. Do not swallow. HANDLING For industrial use only. ATTENTION: This container hazardous when emptied. Since emptied container contains product residues (vapor or liquid), all labeled hazard precautions must be observed.

STORAGE Keep container closed when not in use. Store in a cool dry place. Store in accordance with NFPA requirements. Keep out of reach of children.

Continued On Page 9

### Harcros Chemicals Inc Kansas City, Kansas MATERIAL SAFETY DATA SHEET Page 9 PRODUCT NAME: SODIUM CYANIDE PRODUCT CODE: 12887
NAME: GENE TURNER

< 

## = LESS THAN > 

## = MORE THAN 

### 220# DRUM-BR

N/A 

## = NOT APPLICABLE N/D 

## = NOT DETERMINED N/E = 

### NOT ESTABLISHED Date: 5-JAN-1999 12:01:22.72

DATE ISSUED: 940104 DATE REVISED: 970107 UNK = UNKNOWN



### The information provided in this Material Safety data sheet has been obtained from sources believed to be reliable. Harcros Chemicals Inc provides no warranties, either expressed or implied and assumes no**res~onsibility** 

### for the accuracy or completeness of the data contained herein. This information 1S 

### offered for your information, consideration , and investigation. You should satisfy yourself that you have all current data relevant to your particular use. Harcros Chemicals Inc knows of no medical condition, other than those noted on this material safety data sheet, which are generally recognized as being aggravated by exposure to this product. '. 

### •