p. 1


# OAR Box 1384 Prepped by Charmelle Mathews



## Document

Number: 

# '2&fill-E-19

7 Docket Number: 

# A-94-5 2

Printed 7/2/2008 8:42:11 AM

Sheet 237of 264P-2

DEC.29.199B" " 1 5 4BP H ARE ! LOBB Y -NO.bbf c ydtd



### From : Date : Contact : Company : Contac t Repor t ShawnMcKee , Pacific Environmenta l Services , IncLl^ES): TM Novembe r 12,199 8 an

dDecembe

r 9,199 8 \~ Mr . Clyde Riche

y A.R.E.,Inc . 

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### Telephon e Number . (330 ) 830-4500 ext.21 1 Fa x Numbe n(330)830-454 5 Contac t Summary : Mr . Clyde Richey wa s contactedto updat e informationpreviously provide db y A.R.E. , Inc . i nregard s t o th e usag e o f toolin g resin s fo

r mold-making a

t thei r Mount Eato nan dMassiUon facilities . Inrespons e t o m y question s Mr . Riche

y indicatedth e following : TotUtXo Q£? r 

### '

r 

### C5tf4G> The Moun t Eato nfacilitynases/two resin s intiieir mold-making process : Ashlan dAropo l AM E5000B andAshlandL D 1192-27'OGACC . Th

e AshlandAropo l AME5000B ha s a hazardou s air

pollutan t (HAP) conten

t of 3 1 % b y weigh

t as supplied . Th e Ashlan dL B 119 2 2 7 • • tt 5^0^*S GAC Gha s aHA Pcontent of-36 % by weigh

t as supplied . AshlandAropo l G^5406 resi ni s n o longer used . i V/.7% > i ^ l LB fl92.-2.7-SG, 4 e**) 

# W gsri/fta-re- /W^*M<- USAGE'- 

## A/xesoooB- ?73/ y

### ^//$2O?-5S/K C 

## - a<t3.£3Q-&- Th e tw o resin s stil l inus e ar e combinedto achieve aharder finishedproduct . Approximately twent

y percent ofth e tooling resi napplicationi s done b y han dlay up , an deight y percent i s done b y mechanica

l spray-up . Afiller

i s addedto th e resin . Mr . Richey di dno t hav e informatio no nth e rati o o f resinuse . p f

possibl e pleas e indicat e wha t th e ratio is. ] ,i<fi-D FOA TooUAJG

&£*'** AprQUCJlT'otJ 

### Ther e i s currently

JieH c control device'a

t the Moun t Eato nfacility . There i s acontro l devic e a t th e MassiUo

nfacility . Af

f ^mission s ar

e ventedthroughthe contro l device . N o toolin g resi ni s use dat

th e MassiUo

nfacility , but

som e tooling gel coa

t i s usedfo r mol drepairs .

INFORMATIO NI S ACCURATE . 

# c?J^^l?«Jff '&*/&P. 3

DEC.29.199 B 1:46P M AR E LOBB Y NO.65 6 P. 1 

# BSE The Top Line For Your Truck 400Nav9RdSE P.O. Box

//OO MassiUon, OH

44648-0802 Office 330430-4500 Fax 330-830-4545

COMPANY

HAMS ATTSffTlON: FAX NUMBER: 

## STf/sW*;

/#c £.££- DATs 

### /*-/jd9/9mP PHONE NUMBER QURGBNT

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z _ULL.ir.iyyt i y^lH H HK t LUtiti T P. 4 nu.D^ r•r. 3 MATERIA L SAFET YOAT ASHEE T Ashlan dChemica l Co. , AROPO L C 540 6 ACC G P pag e OO I Dat e Prepared : 07/17/9 7 Dat e Printed : 07/19/9 7 MSD S No : 0238404-004.00 1
1 . CHEMICA L PRODUC TAN D COMPAN

YIDENTIFICATIO N 

## Materia l Identit y Produc t Name : AROPO L C 540 6 AC C G P Genera l o r Generi c ID : UNSATURATE D POLYESTE R RESI N Compan y Ashlan dChemica l Co . P.O . Bo x 221 9 Columbus , O

H 4321 6 614-790-333 3 Emergenc y Telephon e Number : 1-900-ASHLAN

D (1-800-274-5263 ) 2 4 hour s everyda y Regulator y Informatio nNumber : 1-800-325-375 1 2 . COMPOSITION/INFORMATIO N O N INGREDIENT S ingredient(s ) CA S Numbe r % (b

yweight ) STYRENE POLYESTE R RESI N 100-42- 5 Trad e Secre t 42.0

- 42. 0

53.0

- 58. 0 

## 3 . HAZARD S IDENTIFICATION Potentia l Healt hEffect s Ey e Ski n Ca n caus e eye irritation . Symptom s includ e stinging / tearing , redness , an d swelling o f eyes . Ca n caus e ski n irritation . Prolonge d o r repeate d contac t maydryth e skin . Symptom s ma

yinclud e redness / burning , an d dryin g an d cracking o f skin , burn s and othe r ski n damage . Passag e o f thi s materia l int o th e bod ythroug hth e ski n i s possible , bu t i t i s unlikel ytha t thi s woul d resul t i n harmfu l effect s during saf e handling an d use . Swallowin g Singl e dos e ora l toxicit yi s low . swallowin g smal l amount s durin g norma l handling i s no t likel yt o caus e harmfu l effects ; swallowing larg e amount s may b e harmful . Thi s materia l ca n ente r the . lung s durin g swallowin g o r vomitin g and caus e lun

g inflammatio n and/o r damage . Inhalatio n Breathing o f vapo r o r mis t i s possible . Exposur e t o aeroso l and/o r mis t i s possibl e whe n materia l i s sprayed . Aeroso l and mis t maypresen t a greate r ris k o f injur

ybecaus e mor e matena l ma yb e presen t i n th e ai r tha n fro mvapo r alone . Short-ter

minhalatio n toxicit yi s low . Breathin g smal l amount s during norma l handling i s no t likel yt o caus e harmfu l effects ; breathin g larg e amount s mayb e harmful . Symptom s ar e mor e typicall ysee n a t ai r concentration s exceeding th e recommende d exposur e limits . Symptom s o f Exposur e metalli c taste , gastrointestina l irritatio n (nausea , vomiting , diarrhea) , irritatio n (nose , throat , respiratorytract) , centra l nervou s system(CNS ) depressio n (dizziness , drowsiness , weakness , fatigue , nausea , headache , unconsciousness ) an d othe r CN S effects , impaire d coordination , confusion , live r damage . Continue d o n nex t pag e 

### ODtC.lV.iyyb y:*dlH H HK L LUBB Y i*iu.-x> r r. q MATERIA L SAFETY DAT

ASHEE T Ashlan d Chemica l Co . Pag e 00 2 , , ... . # Dat e Prepared : 07/17/9 7 • " \ Dat e Printed : 07/19/9 7 ' 3 MSD S No : 0238404-004*00 1 

## AROPO L C 540 6 AC C G P Targe t Orga nEffect s Overexposur e t o thi s materia l (or it s components ) ha s bee n suggeste d a s a caus e o f the followin g effect s i n laboratoryanimals , and ma yaggravat e pre-existin g disorder s o f thes e organ s i n humans : mild , reversibl e kidne yeffects , effect s o n hearing , respiratorytrac t damag e (nose , throat , an d airways) , testi s damag e live r damage , overexposur e t o thi s materia l (or it s components ) ha s bee n suggeste d a s a caus e o f th e following effect s i n humans , an d ma yaggravat e pre-existing disorder s o f thes e organs : centra l nervou s syste meffects , mil d . effect s o n colo r vision , effect s o n hearing , respiratorytrac t damag e (nose , throat , an d airways ) Developmenta l Informatio n This , materia l (or a component ) ha s bee n show n t o caus e har mt o th e fetu s i n laboratoryanima l studies . Harmt o th e fetu s occur s onl ya t exposur e level s tha t harmth e pregnan t animal . Th e relevanc e o f thes e finding s t o human s i s uncertain . Cance r Informatio n I n 1993 , th e Internationa l Agenc yfo r Researc ho n cance r (IARC ) classifie d styren e i n grou

p 2 B (possibl ycarcinogeni c t o humans) . IAR C conclude d tha t ther e wa s n o convincin g evidenc e fo r carcinogeni c actio n o f styren e i n animal s base d o n th e anima l studie s whic hexiste d a t tha t time . Rather , th e IAR C 2 B listing wa s base d o n dat a fo r styren e oxide , a metabolit e o f styrene . Tw o recen t lifetim e studie s wit hstyrene , on e i n rat s and on e i n mice , hav e bee n complete d sinc e th e 199 3 review . Ther e wa s n o increas e i n cance r i n styrene-expose d rats . However , ther e wa s a n increas e i n lung cance r i n styrene-expose d mice . Th e relevanc e o f th e mous e lun g cance r t o human s i s uncertain . Styren e exposur e ha s no t bee n associate d wit ha n Increase d incidenc e o f cance r i n worker s includin g thos e i n th e reinforce d plastic s and composite s plastic s industries . Othe r Healt hEffect s Styren e readil yreact s wit hlo wconcentration s o f halogen s (fo r example , fluorine , chlorine , bromine , o r iodine ) t o for ma tear-producin g substance . Primar y

Route(s ) o f Entr y Inhalation , Ski n absorption , Ski n contact , Ey e contact . 

## 4 . FIRS T AI D MEASURE S Eye s I f symptom s develop , immediatel ymov e individua l awa yfro mexposur e an d int o fres h air . .Flus

h eye s gentl ywit hwate r fo r a t leas t 1 5 minute s whil e holdin g eyelid s apart ; see k immediat e medica l attention . Ski n Remov e contaminate d clothing . Flus hexpose d are a wit hlarg e amount s o f water . I f ski n i s damaged , see k immediat e medica l attention . I f ski n i s no t damage d and symptom s persist , see k medica l attention . Launde r clothin g befor e reuse . Swallowin g D o no t induc e vomiting . Thi s materia l i s a n aspiratio n hazard . I f individua l i s drows yo r unconscious , plac e o n lef t sid e wit hth e h«a d down . See k medica l attention . I f possible , d o no t leav e individua l unattended .

Continue d o n nex t pag e



# 4UtL.17.iyy b y-e^H N HK L LUBB Y P 6

MATERIA L SAFETY DAT

ASHEE T Ashlan d Chemica l Co . ' Pag e 00 3 Dat e Prepared ; 07/17/9 7 Dat e Printed : 07/19/9 7 MSD S No : 0238404-004.00 1 

## AROPO L C 540 6 AC C G P Inhalatio n I f symptom s develop , mov e individua l awayfromexposur e an d int o fres h air . I f symptom s persist , see k medica l attention . I f breathing i s difficult , administe r oxygen . Kee p perso n war mand quiet ; see k immediat e medica l attention . Not e t o Physician s Thi s materia l i s a n aspiratio n hazard , potentia l dange r fro maspiratio n mus t b e weighe d agains t possibl e ora l toxicit y(Se e Sectio n 3 - Swallowing ) whe n deciding whethe r t o induc e vomiting . Preexistin g disorder s o f th e following organ s (o r orga n systems ) ma yb e aggravate d b

yexposur e t o thi s material : respirator

ytract , skin , lung

- (for example , asthma-lik e conditions) , liver , central•nervou s system , mal e reproductiv e system , auditorysystem .

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## 5 . FIR E FIGHTINGMEASURE S Flas h Poin t 73. 0 - 100. 0 F (22. 7 - 37. 7 C ) Explosiv e Limi t (fo r component ) Lowe

r 1. 1 Upper

6. 1 % •* . Autoignitio nTemperatur e N o dat a Hazardou s Product s o f Combustio n Mayform : carbon , dioxid e an d carbo n monoxide , variou s hydrocarbons . Fir e an dExplosio nHazard s vapor s ar e heavie r tha n ai r ari d maytrave l alon g the ground o r mayb e move d b y ventilatio n an

d ignite d b

ypilo t lights , othe r flames , sparks , heaters, , smoking , electri c motors , stati c discharge , o r othe r ignitio n source s a t location s distan t frommateria l handlin g point . Neve r us e weldin g o r cutting torc ho n o r nea r dru m(eve n empty ) becaus e produc t (eve n jus t residue) ' ca n ignit e explosively . Extinguishin g Medi a regula r foam , wate r fog , carbon-dioxide , drychemical . Fir e Fightin g Instruction s Wea r a self-containe d breathing apparatu s wit ha ful l facepiec e operate d i n th e positiv e pressur e deman d mod e wit happropriat e turn-ou t gea r an d chemica l resistan t persona l protectiv e equipment . Refe r t o th e persona l protectiv e equipmen t sectio n o f thi s MSDS . Polymerizatio n wil l tak e plac e unde r fir e conditions . I f polymerizatio n occur s i n a close d container , ther e i s a possibilit y-i

t wil l ruptur e violently . Coo l storag e containe r wit h water , i f expose d t o fire . NFP A 

### Ratin g Healt h- 2 , Flammabilit y - 3 , Reactivit y - 1 6 . •ACCIDENTA L RELEAS E MEASURE S 

### Smal l Spil l Absor b liqui d o n vermiculite , floo r absorbent , o r othe r absorben t materia l an d transfer ' t b hood .

Continue d o n nex t pag e 

# 5DEC.17.199 B 3-EZm HR E LOBB Y P. 7 NU.ss rr.b MATERIA L SAFET

YDAT A SHEET 

### Ashlan dChemica l Co . Pag e 00 4 Dat e Prepared : 07/17/9 7 Dat e Printed : 07/19/9 7 MSD S No : 0238404-004.00 1 AROPO L C 540 6 AC C G P Larg e Spil l Eliminat e al l ignitio n source s (flares , flame s includin g pilo t lights , electrica l sparks) . Person s no t wearin g protectiv e equipmen t shoul d b e exclude d fromare a o f spil l unti l clean-u p ha s bee n completed , sto p spil l a t source . Preven t fro

menterin g drains , sewers , stream s o r othe r bodie s o f water . Preven t fro

mspreading . I f runof f occurs , notif yauthoritie s a s required . Pum p o r vacuu

mtransfe r spille d produc t t o clea n container s fo r recovery . Absor b unrecoverabl e product . Transfe r contaminate d absorbent , soi l and othe r material s t o container s fo r disposal . 

## 7 . HANDLINGAN

D STORAG E Handlin g Container s o f thi s materia l mayb e hazardou s whe n emptied* . Sinc e emptie d container s retai n produc t residue s (vapor , liquid , and/o r solid) , al l hazar d precaution s give n i n th e dat a shee t mus t b e observed . Al l five-gallo n pail s an d large r meta l containers , including tank car s and tan k trucks , shoul d b e grounde d and/o r bonde d whe n materia l i s transferred . 8 . EXPOSUR E CONTROLS/PERSONA L PROTECTIO N Ey e Protectio n Chemica l splas hgoggle s i n complianc e wit hOSH Aregulation s ar e advised ; however , OSH

Aregulation s als o permi t othe r typ e safet yglasses . Consul t you r safet yrepresentative . Ski nProtectio n Wea r resistan t glove s suc has : polyviny l alcohol,-Wea r norma l wor k clothin g coverin g arm s and leg s Respirator y

Protection s I f workplac e exposur e limit(s ) o f produc t o r an ycomponen t i s exceede d (se e exposur e guidelines) , a NIOSH/MSH Aapprove d ai r supplie d respirato r i s advise d i n absenc e o f prope r environmenta l control . OSHAregulation s als o permi t othe r NIOSH/MSH

Arespirator s (negative pressur e type)-unde r specifie d condition s (se e you r industria l hygiehist) . Engineerin g o r administrativ e control s shoul d b e implemente d t o reduc e exposure . Engineerin g Control s Provid e sufficien t mechanica l (genera l and/o r loca l exhaust ) ventilatio n t o • maintain-exposur e belo wTLV(s) . Exposur e Guideline s Componen t STYRENE (100-42-5 ) OSH AV.PE L 50.00 0 ppm- TW

A- (se e below ) PSH AVPE L 425.00 0 mg/m 3 - STE L OSH AVPE L 100.00 0 ppm- STE L ACGI H TL

V 20.00 0 ppm- TV

A(Skin ) ACGI H TL

V 40.00 0 ppm- STE L (Skin ) POLYESTE R RESI N' N o exposur e limit s establishe d Continue d o n nex t pag e



# io' P. 8 ULL.ir.iyy b y:dciH n HK LLUtiti Y II U. o o f r.( MATERIAL SAFET

Y DAT ASHEE T Ashlan d Chemica l Co . Pag e 00 5 Dat e Prepared : 07/17/9 7 ! Dat e printed : 07/19/9 7 ' MSD S No : 0238404-004.00 1 

## AROPO L C 540 6 AC C G P OSH Aha s formall yendorse d a styren e industryproposa l fo r a voluntar y5 0 pp m workplac e limi t on styrene . Member s o f th e Styren e Informatio n an d Researc h Counci l (SIRC) , Composite s Institut e (Cl) , Composit e Fabricator s Associatio n (CFA) , Internationa l Cas t Polymer s Associatio n (ICPA ) and Nationa l Marin e Manufacturer s Associatio n (NMMA ) hav e agree d t o us e eithe r engineering

. controls , wor k practice s o r respiratoryprotectio n t o achiev e thi s voluntary limi t fo r .styrene . OSH Aplan s t o enforc e thi s voluntar yworkplac e exposur e limi t i n thes e industries . 9 . PHYSICA L AN DCHEMICA L PROPERTIE S Boilin g Poin t (for.component ) 293. 4 F (145. 2 C ) @ 76 0 mmHg Vapo r Pressur e (fo r component ) 4.50 0 mmH g @ 68.0 0 j Specifi c Vapo r Densit y 3.60 0 @ AIR*= 1 . Specifi c Gravit y ; • 1.05 1 - 1.0S 9 @ 77.0 0 F 

## Liqui d Densit y 8.90 0 lbs/ga l § 77.0 0 F 1.07 0 kg/ 1 <s 25.0 0 C 

## Percen tVolatile s 38. 0 - 42. 0 % Evaporatio nRat e SLOWE R THA

NETHY L ETHE R Appearanc e HAZ Y 

## Stat e LIQUI D Physica l For m HOMOGENEOU S SOLUTIO N 

## Colo r• COBAL T 

### Odo r PUNGEN

T 

### P H . Not applicabl e Viscosit y 615. 0 - 785. 0 cp s

Continue d o n nex t pag e



# 1

### DEC . 17.199 8 9:23R M RR E 

### LOBBY A~~~ ; ^ I i U• "">"" > f r" 1 • t i MATERIA L SAFET

YDAT A SHEET 

### Ashlan dChemica l Co . Pag e 00 6 Dat e Prepared : 07/17/9 7 Dat e Printed : 07/19/9 7 MSD S No : 0238404-004.00 1 AROPO L C 540 6 AC

C G P Solubilit y i nWate r NEGLIGIBL E 

### 10 . STABILIT YAND REACTIVIT Y Hazardou s Polymerizatio n Produc t ca nunderg o hazardou s polymerization . Avoi dexposur e t o excessiv e heat , peroxide s an dpolymerizatio ncatalysts . Hazardou s Decompositio n Ma y form : carbo ndioxid e an dcarbo nmonoxide , variou s hydrocarbons . Chemica l Stabilit y Stabl e - Incompatibilit y Avoi dcontac t

with : halogens , stron g alkalies , stron g minera l acids . 

### 11 . TOXICOLOGICA L INFORMATIO N ' ? N o dat a 

## 12 . ECOLOGICAL INFORMATIO N N o dat a 13 . DISPOSA L CONSIDERATIO N Wast e Managemen t Informatio n Contaminated absorben t ma ybe deposite

d i n a landfil l i n accordanc e wit hlocal , stat e an

d federa l regulations . Destro yb yliqui d incineration i n accordanc e wit h applicabl e regulations . 14 . TRANSPOR T INFORMATIO N DO T Informatio n- 4 9 CF B 172.10 1 DO T Description : RESI NS0LUTI0N,3,UN1S66,II I 

## Container/Mode : 5 5 GA LDRUM/TRUC K

PACKAGE • 

### NOS Component : None j 

### \

Continue

d o n next page—, P.1 0

UtL.lCi.yyt i yJdclHT I HK L LUtiB Y NU
. ;>:>. •r. y MATERIA L SAF.ET

YDAT ASHEE T Ashlan dChemica l Co . Pag e 00 7 Dat e Prepared : 07/17/9 7 Dat e Printed : 07/19/9 7 MSD S No : 0238404-004.00 1 AROPO L C 540 6 AC C G P R Q (Reportabl e Quantity ) - 4 9 CF R172.10 1 Produc t Quantit y (lbs ) Componen t 239 9 STYREN

EMONOME

R 15 . REGULATORYINFORMATIO N US Federa l Regulation s TSC A (Toxi cSubstance s Contro l Act ) Statu s TSC A(UNITE

D STATES

) The intentiona l ingredient s o f thi s produc t

ar e listed , CERCL A R Q - 4 0 CFR302.4(a ) Componen t

R Q (lbs ) STYREN E100 0 SAR A 30 2 Component s - 4 0 CF R35 5 Appendi xA Non e Sectio n 311/31 2 Hazar d Clas s - 4 0 CF R370. 2 immediate(K ) Delayed(X ) Fire(X ) Reactive(X ) sudde nReleas e o f Pressure ( ) SAR A 31 3 Component s - 4 0 CF R372.6 5 Sectio n31. 3 Componen t (s ) CA S Numbe r

Ma x % STYREN E100-42- 5 41-6 8 Internationa l Regulation s Inventor y

Statu s No t determine d Stat e an dLoca l Regulation s Californi a Propositio n6 5 Th e followin g statemen t i s mad e i n orde r .t o compl ywit hth e • Cali f orni a Saf e Drinkin g Wate r and Toxi c Enforcemen t Ac t o f 1986 : Thi s produc t contain s th e followin g substance(s ) know n to.th e stat e o f Californi a t o caus e cancer . • BENZEN E . ETHYLEN E OXID E Th e followin g statemen t i s mad e i n orde r t o compl ywit hth e Californi a Saf e Drinking Wate r an

d Toxi c Enforcemen t Ac t o f 1986 : Thi s produc t contain s the following substance(s ) know n t o th e stat e o f Californi a t o caus e reproductiv e harm . ETHYLENE OXID E ' Ne w Jerse y

RT RLabe l Informatio n STYREN E MONOME R 100-42- 5 Pennsylvani a RT KLabe l Informatio n BENZENE , ETHENYL - 100-42- 5

Continue d o n nex t pag eUL L
. i ci yyt i y* ^H H HK LLUBB Y~ '• ~ Bi±L l

riu.'SDf ' *-*

. i a . - ] MATERIA L SAFETY DAT

ASHEE T Ashlan d Chemica l Co . ' Pag e 00 8 Dat e Prepared : 07/17/9 7 Dat e Printed : 07/19/9 7 MSD S No : 0238404-004.00 1 

## AROPO L C 540 6 AC C G P 16 . OTHE R INFORMATIO N Th e informatio n accumulate d herei n i s believe d t o b e accurat e bu t i s no t warrante d t o b e whethe r originating wit hthe compan yo r not - Recipient s ar e advise d t o confirmi n advanc e o f nee d tha t th e informatio n i s current , applicable , an d suitabl e t o thei r circumstances . \ J

Las t pag e 

# \0'DEC.17.199 8 9*20fl M AR E LOBBY P.1 2 NU.SO Zr. i 

# flffiE The Top Line For Your Truck
400 Nave Rd

SB P.O. Box

//OO MassiUon, OH

44648-0802 Office 330-830-4500 Fax 330-830-4545

jjias^JBJigm?^ ^ COMPANY

NAMS. 

## tffG/F/C £UV)&0. S£MJC6Lf t 

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