Prepared by: 

CHROMIUM PLATING COMPANY, INC. 

TULSA, OKLAHOMA 

Submitted By: 

RMC Environmental, Inc. 

11311-B Douglas Street 

Huntley, Illinois 60142 

RMCEI Reference Number: 98-016-311 

October 19, 1998 

TPTAL CHROMIUM EMISSIONS 

TEST REPORT 

For 

Chromium Plating Company, Inc. 

Tulsa, Oklahoma 
RMC Environrnent:al, Inc. 

PO &x 1008 

Elgin, Illinois 60121-1008 

10 November 1998 

800-532-3391 Voice 

847-669-5389 Fax 

I. Rachel M. Chleborowicz, certifY that the Chromium Emissions Testing conducted on the hard chrome 

plating scrubbers installed at the Chromium Plating Company, Inc. facility in Tulsa, Oklahoma, was 

conducted under my supervision. All of the results obtained during this testing are authentic and accurate. 

~-Rache 

p . 

blebor ~ er 
Table of Contents 

1.0 PROJECT SUMM.ARY ..................................... _....................................... 1-1 

1.1 Source Infonnation.......................................................................................... I-I 

1.2 Testing Finn Information.................................................................................. 1-1 

1.3 Test Infonnation............................................................................................... 1-1 

2.0 SUMM.ARY OF .RESULTS ... " .... , ............... -.-... _.................................... 2-1 

3.0 SOURCE DESCRJ:ItTION .............................................. _ ................... _....... 3-1 

4.0 TEST PROCEDURES AND EMISSIONS DETERMINATION___ 4-1 

4.1 Test Procedures....................... ...................................................................... 4-1 

4.2 Emissions Detenninations................................................................................ 4-1 

Appendix A - Reference Measmement Data With Emission Rate Calculations 

Appendix B - Field Data Sheets For Total ChrOmilDD 

Appendix C - Analytical Data For Total Chromiwn Analysis 

Appendix D - Reference Measurement Performance Checks and CalibmtioD, Chain Of Custody and 

QAlQC Documentation 
Chromium Plating Company, Inc. 

Tulsa, Ok/ahoma 

1.0 PROJECf SUMMARY 

1.1 Source Information 

Plant Name and Address: 

Units Tested: 

Facility ID Number: 

1.2 Testing Firm Information 

Finn Name and Address: 

Firm Contact: 

Telephone Number: . 

1.3 Test Information 

Test Requested By: 

Finn Contact: 

Telephone Number: 

Test Objective: 

Test Methods: 

Test Date: 

Test Coordinators: 

Test Personnel: 

Chromium Plating Company, Inc. 

412 North Cheyenne 

Tulsa, Oklahoma 

SCRUBBER 1&:.2 

RMC Environmental, Inc. 

I 131 1-B Douglas Street 

Huntley, Dlinois 60142 

Rachel ChJeborowicz - Project Manager 

800-532-3391 Voice 

847~69-5389 Fax 

Chromium Plating Company, Inc. 

Mr. Bruce McAllester 

918-583-4118 Phone 

918-583-4112 Fax 

98-016-311 

Conduct total chrome, moisture and flow rate testing on plating tanks 

in accordance with the MACT regulations and EPA Method 306 (40 

CFR 63, Appendix A). 

EPAMethods 1,2,3,4 and 306 

October 19. 1998 

Mr. Bruce McAllester 

Rachel Chleborowicz - Project Manager 

Greg Chleborowicz - Project Manager 

Ryan DaUghtrey - Environmental Technician 

I-I 
ChromIUm Plaflllg Company, Inc. 

Tulsa, Oklahoma 

2.0 SUMMARY O F ItESUL; rs 

98·016·311 

The results of th e emissio ns rctesting perfomlcd on thc 1:l.Tge chrome tank stacks arc presentc.."CI in Tabl e 2· 1. 

.J.)etailed results of all of the testing completed on this location are located in App~ndix A The fi e ld data and the analytica l 

results are presented in AplJendix D and C, respecti vely. Calibration sheets and equ ipment perfonnance checks arc 

presented in Appendix D, a long with the chain of custody. 

A cyclonic fl ow check .... 'llS perfonned at the s,'1mpling 10C3.tion to delenn ine the existence of abnonnal now. The 

observed averageyawangJe for SCRUBBER 1 was 7.7&SCRUBBER 2 was 4. ' &. Seclion 2.5 of EPA Method 1 ind icates 

Ihat a sampling location with an avcmge yaw angle of s: 20' is acceptable. As indiC3.tcd by the average of the three lest 

runs, Iheconccntrntions Of lhc chromium emissions were below the p...[ACT regulation standards of 0.0 15 mgfDSCM for 

composite mesh pad scrubber systems on hard chrome plating tanks. 

T ABLE 2·1 

SUMMARY O F TOTAL CHROMIUM RESULTS 

Chromium I'la ling Company, Inc. 

Oclober 19, 1998 

Localion T C!II'lIl11 nteler I{esull Specirica lion 

SCRUBBER # 1 

~~' D.O IZS :5 0.0 15 mglDSCM for hard chrome plating 

Flow nile DSCFM IK.838 sources 

SCRUBBER #2 mg/DSCM O.OUll :5 0.0 15 mg/DSCM for hard chrome plati ng 

Flow mle DSCFM 21,800 sources 

2· 1 
Chromium PIOIing CompallY, Inc. 

Tulsa, Oklahoma 

3.0 so unCE DESCRIPTJON 

98-016-311 

Scrubber I is a 19,000 CFM vcmilatioll systcm with four (4) Model SCSU 4,750 CRvl three stage ven ica l chrome 

separators, 'nu::sescp;1f3torn go through an autornaticlpcriod ic washdown. TIle scrubber is designed to remove 99.8% of 

the chrome mist two microns and larger and exhaust less than 0.015 mglDSCM of chrome into the atmosphere. 

Scrubber 2 is a 19,000 CFM ventilation system with fi ve (5) Model SCSU hoods (2,000 CFM. 2,500 CFM, 4,000 

CFM, 4,500 CFM and 6,000 CFM) three stage ven ica l chrome separators. These separators also go through an 

automatic/periodi c wasbdown. This scrubber system is designed to remove 99.8% of the chrome mist two microns and 

larger and exhaust less than 0.015 mgIDSCM of chrome into the atmosphere. 

o(h scrubbe employ a three stage composite mes pa(] system: one course multi-layer pad (Stage I), one 

medium mul ti-layer pad (Stage 2) and one fine multi-layer pad (Stage 3). Stage I & 2 arc involved in the washdown. 

Magnahelic gauges arc installed between C3ch oflhe stages to mC3Sure the differential pressures across each stage as well 

as across the cnlirc system. 

3-1 
Chromium Plating Company, Inc. 

Tulsa, Oklahoma 

4.0 TEST PROCEDURES AND EMISSIONS DETERMINATIONS 

98-016-311 

The sampling and analytical requirements for this program include the determination of total chrome, O/COl , 

moisture and volumetric flowrates from the stack effluent The plating process was operated at 100% capacity. Figure 

4-1 illustrates the sampling system used for the total chrome testing. The specific equipment and procedures that were used 

are detailed below. 

4.1 Test Procedures 

Total chrome compliance testing was completed on the exhaust stacks from the chrome plating tanks. The 

compliance testing consisted of three two-hour test runs utilizing EPA Methods I, 2, 3B (40 CFR 60, Appendix A) and 

306 (40 CFR 63, Appendix A). 

The number and location of the sampling points were determined according to the procedures outlined in EPA 

Method 1. The exhaust stack cross section was divided into 24 equal areas with 12 sampling points on each to two axes. 

A cyclonic flow check was performed at the sampling location to detennine the flow angles at each point An S-type pitot, 

oil manometer, and an angle finder were used for these determinations. At each point, the Pitot was positioned at a right 

angle to the flow, the pitot was then rotated until a null reading was obtained. The angles of rotation were then noted. 

The flue gas velocity and volumetric flow rates were determined according to EPA Method 2. Velocity head 

measurements (delta P) were made using an S-type Pi tot tube conforming to the geometric specifications indicated in 

Method 2 and each Pitot has been assigned a coefficient of 0.84. The differential pressures were measured using an oil 

manometer of the appropriate range. Flue gas temperatures were obtained with chromel-alumel thermocouples equipped 

with a digital readout. 

The composition of the flue gas was determined utilizing the procedures outlined in Method 3B. The percent 

moisture content of the flue gas was obtained from the amount of moisture collected in the Method 306 sampling train. 

Analysis for carbon dioxide and oxygen were was performed using a Fyrite analyzer and the analytical results were used 

in the calculation offlue gas composition and molecular weight. 

4.2 Emissions Determinations 

The total chrome samples were drawn isokinetically from the source using an EPA method 306 sampling train. 

The sampling train consisted of a glass nozzle and probe liner, an attached Type S Pitot tube, four glass impinger chilled 

and a metering console. No filter is used for this method. 

The first impinger is left empty, the second and third impingers contain 100 ml of 0.1 N sodium hydroxide 

(NaOH) in place of water, and the fourth impinger contains 200g of preweighed silica gel for moisture removal. Each of 

the twenty-four points were sampled for 5 minutes resulting in a net run time of 120 minutes. 

After sampling, the reagents were returned to their original container, weighed, the weights recorded on the label 

and the liquid level marked. The silica gel was returned to the original container, weighed and the weight recorded on the 

label. The volume of water vapor condensed in the impingers and the volume of water collected in the silica gel were 

summed and entered into the moisture content calculations. All sampling components exposed to the effluent were rinsed 

three time with NaOH and the rinses were added to the reagent containers. 

The combined samples and rinses were analyzed for total chrome using ion chromatography (IC) coupled with 

4-1 
Chromium Plating Company. Inc. 

Tulsa. Oklahoma 

a post-column reactor (peR). 

98-016-311 
IMPINGER TRAIN 

ICE BATH 

VACUUM GAUGE 

• :" •• ' .. I 1{·;);'.· 

TEFLON" '~~~~:;' 

SA~PLlNG HOSE 

RUBBER SAMPLING HOSE 

.' '. 

SAMPLING NOZZLE 

UNHEATED SAMPUNG PROBE 

r 

r 

THERMOCOUPLE 

GAS flOW 

UMBILICAL 

o . . 

e e 

eOD~ 

e ~§ .. CONTROL UNIT 

Figure 4-1 

Method 306 

Total Cbrome Sampling Train 
Appendix A - Re,ference Measurement Data With Emission Rate Calculations 
RMC Environmental, Inc. 

Emissions Testing & Consulting 

Plant: Chromium Plating Company, Inc. Date: 11/09/98 

Project #: 98-016-311 

Location: Unit 1 - Mesh Pad System 

Sample Identification U1-M306-1 U1-M306-2 U1-M306-3 

Test Date 10119/98 10119/98 10119198 

Start 830 1108 1356 

Finish 1047 1319 1600 

Total 120 120 120 

Cp Pitot Coefficient (CF) 0.84 0.84 0.84 

A Area of stack sq. inches 907.92 907.92 907.92 

Pbar Barometric Pressure (in HG) 30.27 30.26 30.28 

Wm Volume of Condensate (mg) 21.5 24.2 24.3 

Ts Temperature of Effluent (F) 66.2 72.7 76.9 

Pavg Average Delta P 0.784 0.785 0.806 

Pg Static Pressure (in H2O) 4.80 4.80 4.60 

OH Delta H, Orifice pressure differentiaf (in H2O) 1.90 1.86 1.89 

Tm Meterbox Temperature (F) 60.3 78.2 82.7 

Vm Volume of sample metered (CF) 93.441 94.568 95.682 

Y Meter correction factor 0.9875 0.9875 0.9875 

On Nozzle Diameter (in) 0.22 0.22 0.22 

CO2 Percent Carbon Dioxide (%) 1.00 0.90 1.10 

02 Percent Oxygen (%) 20.10 20.10 19.80 

CO Percent Carbon Monoxide (%) 0 0 0 

N2 Percent Nitrogen (%) 78.90 79.00 79.10 

Ms Molecular Weight (wet) (Ibllb-m) 28.85 28.82 28.84 

Laboratory Results 

Total Chrome (mg) 3.88E-02 3.60E-02 2. 52 E-02 

Ps Absolute pressure of Flue Gas (in HG) 30.62 30.61 30.62 

Vwstd Volume of Water Vapor (SCF) 1.01 1.14 1.15 

Vmstd Volume of Metered Gas (DSCF) 95.133 93.039 93.422 

M Moisture (%) 1.05 1.21 1.21 

Vs Velocity (FPS) 49.07 49.44 50.29 

Qaw Volumetirc Flow (ACFM) 18,562 18,704 19,024 

Qsd Volumetric Flow (DSCF) 18,862 18,739 18,913 

Chromium Concentration (mg/DSCM) 0.014 0.014 0.010 

Chromium Concentration (lblHr) 1.02E-03 9.58E-04 6.75E-04 

Isokenetic (%) 100.39 98.82 98.31 
RMC Environmental, Inc. 

Emissions Testing & Consulting 

Plant: Chromium Plating Company, Inc. Date: 11/09/98 

Project#: 98-016-311 

Location: Unit 2 - Mesh Pad System 

Sample Identification U2-M306-1 U2-M306-2 U2-M306-3 

Test Date 10119/98 10/19198 10/19198 

Start 815 1107 1338 

Finish 1021 1312 1543 

Total 120 120 120 

Cp Pitot Coefficient (CF) 0.84 0.84 0.84 

A Area of stack sq. inches 907.92 907.92 907.92 

Pbar Barometric Pressure (in HG) 30.27 30.29 30.30 

Wm Volume of Condensate (mg) 16.8 21.7 17.8 

Ts Temperature of Effluent (F) 63.4 69.4 75.6 

Pavg Average Delta P 1.037 1.034 1.088 

Pg Static Pressure (in H20) 4.70 4.20 4.50 

DH Delta H, Orifice pressure differential (in H2O) 1.73 1.69 1.89 

Tm Meterbox Temperature (F) 56.3 65.0 71.8 

Vm Volume of sample metered (CF) 82.061 83.216 85.745 

Y Meter correction factor 1.003 1.003 1.003 

On Nozzle Diameter (in) 0.197 0.197 0.197 

CO2 Percent Carbon Dioxide (%) 0.90 1.10 1.00 

02 Percent Oxygen (%) 20.10 19.90 20.00 

CO Percent Carbon Monoxide (%) 0 0 0 

N2 Percent Nitrogen (%) 79.00 79.00 79.00 

Ms Molecular Weight (wet) (lbnb-m) 28.85 28.84 28.86 

Laboratory Results 

Total Chrome (mg) 5.71E-02 2.47E-02 O.OOE+OO 

Ps Absolute pressure of Flue Gas (in HG) 30.62 30.60 30.63 

Vwstd Volume of Water Vapor (SCF) 0.79 1.02 0.84 

Vmstd Volume of Metered Gas (DSCF) 85.481 85.296 86.834 

M Moisture (%) 0.92 1.19 0.96 

Vs Velocity (FPS) 56.30 56.56 58.31 

Caw Volumetirc Flow (ACFM) 21,297 21,397 22,060 

Qsd Volumetric Flow (DSCF) 21,782 21,566 22,051 

Chromium Concentration (mgIDSCM) 0.024 0.010 0.000 

Chromium Concentration (lblHr) 1.92E-03 8.26E-04 O.OOE+OO 

/sokenetic (%) 97.41 98.17 97.75 
AppendixB - Field nata Sheets For Total Chrome 

. . 
Sampiing and Veiocity Traverse Point Determination 

EPA Method 1 

CLIEN'r Sce...b A.'K. Ve~ > ~ 

PLANT NAME a~,~ RAn~, (lIZ 

CITY, STATE -r.;h-~ o~ 

SAMPLING LOCATION UN/n 1. ,,2. (j Pt!"NnuH 2 

NO. OF PORTS AVAILABLE 2. 

Z NO. OF PORTS USED ~' PORT. INSIDE DIAMETER 

DISTANCE FROM FAR WALL TO OUTSIDE OF PORT .Jft2 

NIPPLE LENGTH ANDIOR WALL THICKNESS 211 

DEPTH OF STACK OR DUCT .1lJ." 

STACK OR DUCT WIDTH (IF RECTANQULAR, 

EQUIVALENT DIAMETER: 

De - 2 x DEPTH I( WIDTH 2 ( ) ( ) 

- DEPTH. WIDTH = ( = • ) 

DISTANCE· UPSTREAM DOWNSTREAM 

FROM PORTS TO l~" ~f" FLOW DISTURBANCES 

DIAMETERS O.S- 2.0 

STACK/DUCT AREA = = '10'1·5 IN2 

LOCATION OF POINTS pl...CIRCULAR STACKS OR DUCTS 

• & • '0 'I ,. ,. 11 10 zz 24 

, '.7 ••• 1.1 I.' 1.1 '.a I.' 1 •• , .3 1.1 , .1 

I 25.0 14.' '0.1 '.2 '.7 6.7 •• 1 ••• 3.1 1.5 3.2 

3 . 71.0 21.' 111 •• 14.' II.' 1.1 ••• 7.5 •• 7 •• 0 '.11 '. 1113.1 70 .• 32.3 22.' '7.7 1 •• 0 'I.' 10.11 11.7 1.7 7.11 

5 IS.' .7.7 ".2 11.0 20. I U.II 1 •• 1 12.1 11.' 10.S 

• liS •• 10.1 11.1 35.' 21.11 21.0 U •• U.S .... 11.2 

7 111.1 77 .• .... 3'.a 2'.3 U .• 20 •• 11.0 HI.I 

• 11'.1 IS •• 75.0 03 •• n.s 211.' 211.0 21.1 I ••• 

• " .. 12.3 73.' 112.5 1 •• 2 30.' 211.2 2:1.0 

10 n .• 11.2 711.11 71.7 01.0 31 •• :11.11 27.2 

11 \2J IS .• 711.0 70 •• 11.2 :11.:1 :sa.:I 

12 87. 110.1 a3.' 711 .• 01 .• 10.7 :111.1 

n 11'.3 17.S 11.2 75.0 11.5 110.1 

,. 11.2 111.6 IS .• 71.' 73.' 17.7 

II IIS.1 111.1 13.5 71.2 72 •• 

" III •• 112.5 17.1 82.0 77.0 

17 IIs.a 110.:1 85 •• 10 •• 

11 11.1 n.:I II •• IS.II 

11 11'.1 111.3 II.' 20 11.7 11 •• 0 ".5 

II 11.5 112.1 

21 II •• ' 114.' 

U 1141 •• 

:u '1 .• 

LOCATION OF POINTS IN RECTANGULAR STACKS OR DUCTS 

2 ~ • 5 , 7 • II 10 " 12 

1 25.0 16.7 12.5 10.0 •. 3 7.1 1.3 5.' 5.0 • •• 5 4.2 

Z 75.0 50.0 37.5 30.0 25.0 21.4 111.0 10.7 ".0 1:1.' 12.5 

3 13.3 12.~ 50.0 41.7 35.7 31.3 27.1 25.0 22.7 20 .• , 17.5 70.0 111.:1 50.0 43.1 :1 •• 1 3S.0 31.1 211.2 

5 '0.0 15.0 '4 • .:11 5a.:I 50.0 .5.0 CO. II 37.1 

I flI.7 71.' III.' 111.1 55.0 50 ... 45.1 

7 12.' II '.3 72.2 116.0 111.1 1 •• 2 , 13 .• 13.3 75.0 11.2 U.S 

• ".4 15.0 77.' 70 •• 

0 15.0 aa.' 71.2 

'1" III.S n.' 

12 IS.' F-0016 tav. 8-113 

DRAW HORIZONTAL LINE THROUGH DIAMETERS 

If mora I"an • and 2 diam.t.,a ~ II ducl 

dla. i. I ... Ihan 2'·. U5. 8 or , point •. 

VELOCITY 

16 

PARTICULATE 

DIAMETERS 

UP DOWN 

8 - 2.0 I 

7 1.75 

1.5 

24 or 25 

PITOT USED (.I) . TYPE ·s· --L STANDARD_ 

'" OF DISTANCE . DISTANCE 

DUCT FROM INSIDE FROM OUTSIDE 

POINT DEPTH WALL OF PORT 

1 Z., 0·1 2.'2 

2 (p.7 2.3 9,3 

3 II. g '/.0 ".0 

4 11.':1 fD.O 8.0 

5 ZS:D 8.S- /0.S" 

6 ~s:, 12. I Jt!.1 

7 ,,,.tI 21 i 2~ .. 8 

S· 7-S"':0 :1.5.5 2+.S' 

9 82.$ :18.0 30.0 

10 g$'.Z 30.0 32.0 

11 93.$ 3/.(P 33". '" 

12 97.CJ 33 .. '3 3$7 '3 

13 

14 

15 

16 

17 

18 I 

19 

20 

21 

22 

23 

24 

25 I 
- . 

Client 

Plant Hame 

Run Humber 

SamplUlg Date 

ADAJ.ysi. Data 

AnAlyst 

Reagent 1 ( 0.1 ItJ H-DII) 

Final Weig~, 9 

Tared Wej.ght, 9 

WAter catch, 9 

Reagent 2 ( __ ................ __ ) 

Final Weight, 9 

Tared Weight, 9 

CONDEHS!:!) WlL:J:Ea, 9 

Sil.i,ca Gel 

Final Weight, 9 

Tared Weight, 9 

ADSORllED ~, gMOISTURE ANALYTICAL RESULTS 

J. b He. 91. 0 "31/ 

Sampling Lac. u",1°.J. .L 

'- . ,",":~. 

8 

l~~:> tJz ~t 'Z. , 

lS-O ls:.f2 

il If:.. ~...-: LV!..' -z.. 

---------. .... --.... ---

I I tAl ... 30(,-Q.J 

'ik~Ar .. 

ZDO 

;', ....... .. 

(0 

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l50 

,1./."3 

hlanc:a 1110. __ ........ __ Tn- (./) Triple .... _ 11enMlnic.,/' .~ Ia& 110. _ ........ __ 

ecmment. 

L-0016 rev. 5-93 
SA.'IPLlNG DATA - HETHOO(S) _.:::::J~o~E:,~A.:::-.... __ 

~~~T ~et:"~i $:1 .#k, .. <Co RUN 110. 4.1. -11 3oir..-d" 

CITYlSTAT£::7!/Sd,OI< 0 .loa 110. 9g-01',11/ DATE 117117f1~ 

SM'''UIlG LOC. _..ktd1!:""~/.!.·IJ4-_--::-::-::-:::------------:;--::---- TIME START 0 ';1,lD 

SARCMETI 1 C PRESSUR!. III. KG 312. Z 1- STAT I C PRESSURE, III. H2O _C/-.:..:.;..:g~_ TJ ME ,. II' SH :-LI(()~:":'I./~' --::::~_ 

:.e.a~ I. VACWfC III. KG.l£:- ~ TEST PER5alIIEL 4"At:, fl1D 

LEAr RATE. CFM D,f}()o 0.001 PaSTTEST POS PRESS LEAl: I 0(7 • 

• CONDUCT PaSTTEST POSITIVE PRESSURE LEAK CHECK FOLLOWING THE LAST RUN PER LOCATION. FOR OTHER RUNS. ENTER "lilA". 

~I~NT CHECKS iOUIPM~"T 1.0. NUMBERS I.E."': HEClS 

~PJTOT, PRETEST REAGENT BOX METER 8QX '1.1 .. 11 Y ()·21.1~ B B 

PITOT. POSTTEST PITOT H-':/.-l Cp '!:.!:L IIOZ'L H-2-lD OIA. o.Zt.l:> E E 

~ NOZZLE. PRE/POST TC READClIT TC PROlE UMBILICAL '#1-\1' 

ZC/TC ~ ·F PRE SAMPL'G BOX caSAT PUKP TEDLAR BAG B B 

_ TC ..t4- ·F POST E E NOMOGRAPH DATA ~ DRSAT SYSTEM DELTA'HiI " 1=052- B B 

FllTER/XAD TARE WT. KETER TEMP. ~8 E E S,1f..~ /10 EST. XH20 :J. 

"C" FACTca o·2S''./. F:l~1tH, % !9! 

STAa TEMP. ~f ~ .::le:.L O,f1.3 

t:!.", all 2.~ REf DELTA'P 0.1:1.1 ~ ..!..:!L <+5% OF CAL '0 T7 

..<~ "r" FACTOA ,3.. 3~" -- (Y)~(lI)~ . 

L pnOT .. w:J £ GAS TEMPERATURES ·F 

I ClOCX ORT GAS METER METER STAex OP.IFICE ~~rTING, GAUGE O:K~ N SAl4PlE TIME. READING READING, TEMP., TEMP., IN. H 0 VACWfC. FILlEl IMPING. 

E POINT "'NUTES CUBIC FEet III. H2O ., ·F ACTUAL -mEAL IN. KG • Exn EXIT- I 

1 A J I;) I02.J Ob .So lSI 162 J 2 1.1. () :J.S - +S' - 2 2 oS IDS: 32 .~o S2 &'"J .1S .9~ 3.0 - +1 - 3 .J It:) I09.2S-. ,ItJ £2 03 J,o.s- I, OJ ,J,o - ~'t-'? - I. It IS 111410 I If I S.s- hlf /.0 • <:fer 3.t:> - '1-8 - 5 .s 70 /1'1 OJ- ,'73 .5"S 6y l.oS 1 o"J .1.b - '1-8 - 6 6 2S I J /'. 9,j'" .~S ss 6~ l.o.j- 1.06 .:s,o - 1-8 - 7 1- 130 I/Q.10 ~S'3 1...."" . 6S 1 . .2.s I,:;~ 30 - '1-8 - 8 e :IS 122.2 .&f'lJ ..5-1- 6r 2.J 2. 1/ If-.o - '1-& - 9 q 't" 126 8..5- t:jJ IS"~ ts 2.2 12./~ .It. 0 - 1M - 10 It:) tt)- 1$0. , S- • tfo 5'8 ~s .2.1 :1 .1/ +, 0 - ...)0 - 11 II ..Jtp 13S. IS , '12 SB &S .2.2 :2. 16 ~o - S'~ - 12 12 ..s5' 1.1',82- /. J 4-8 6~ 2, b J.f6 .5'..0 - J() - 13 .81 6o 1/'tY 00 .~~ "l (pi:; I.SS I·SS ~.~ - S::> - 1 

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2S ~"J ,;J l) 19f. ';(il I i I . i I I I , ! 

FINAL • FILTER EXIT to~ NJ Method ,. FILTER BOX for all others 

•• PROBE EXIT' J (pro~ , fitter ~aPPIY to NJ Method 1. COMO. EXIT appt ies if sampling t~ain has a condenSer. 

93. yYJ ~ ".2.. JJJD 

Min. Ce) Vm (luP)~ tm . ts tih ,·1112 (Page 1) rev. 9·91. 
CLlEJIT S",.. ..... ( A:,. 

PWT C n"'07;:·h. r-~ I 

CITT/STATE; Q K 

SAMPLING LOC. 4hz)f .1. 

SAMPLING DATA - HETHOO(S) .30& 

IARtMETRIC PRESSURE, IN. HG :J 0, ? , STATIC PRESSURE, IN. "20 _ t.)! 

RI.AI 110. ?t I • 306 - tJ '2 

91·('>1'=· J// DATE /DJ/,h~ 

TIME STAAT iI.,O :P 

TIME FINISH /3 = " 

" ~ LE.U J, YAQUI IN. HG..1..!2.:- ...«C.-

LEAl RATE, CFM 0 ,(tr/O O.t?fll 

T~ST PER$OIfNEL t:E A c.. £11 P 

PQ.<;TTEST POS PRESS LEAr: /1)(7 • _ 

• CONDUCT POSTTEST POSITIVE PRESSURE LEAK CHECK FOLLOWING THE LAST RUN PER LOCATION. FOIl OTHER RUNS, EIITER "N/A". 

EQUIPMENT CHECKS EQUIPM~NT I.D. NUMBERS LEAl( £HECU 

;r PITOT, PRETEST REAGeNT BOX METU lOX 1l-I

' , O~1i'li 8 8 -7 p nOT, POS.TTEST PITOT llJr'/ Cp --!!!:t Nez' L dL. 2.J.. 0 DIA. .,2,1Q E E 

NOZZLE. PRE/POST TC READClIT TC PROlE iM"iILICAL ~1"6 

~c t.S' 0, PRE SAltPL ' G BOX OIlSAT Pl.MP TEDUR .AG • 18 

C ~ /E ·F POST E NOMOGRAPH DATA ____ ORSAT STSTEM DELTA-Hi l.1~S2 "., 8 8 

FlbTER£XAD TARE \lT 1 KETER TW. E 

~'1¥.~ lSi:' :z E 

EST. %H2O .. 

"C" FACTCJI ·1.l~ Fxrhes. X !9! 

STAa: TEMP. 'i JJJ-. 3!!.L.. Q~2%1 N--fJ7I 2-N' REF DELTA-P .1:.1. 1 Lt2.::.. ..J&.. <+51 OF CAL'D T7 

~O, "a:- FACTOR ~ .,l2!:! -- CT)L (N)~ 

L f# GAS GAS TEMPERATURES ·F 

J CLOCK ORT GAS METER PITOT METER STACX OP.IFIC£ SETTING, GAUGE 

N SAMPLE TIME. READING, READING, TEMP. , TEMP., IN. H2O VACUUM, FILTER IMPING. O:II~ 

E POINT MINUTES CUBiC FEET IN. H2O ·F ·F ACTUAL IDeAL IN. HG • EXn EXIT" .J 

1 A J 0 11,J:foD If'=t ,:/-0 '1-0 /. J 1.09 +:0 - .s--~ - !v V 

2 2 S- 11~ ~~ . 'M' 1-0 1-0 1,0S- 1.0'1- IJ.*D - s-e - 3 3 10 ;;10' . ~ .4-0 -=1-+ -=lD ·'3 . q,~ +'D - 54 - 4 It IS' .ln4. "":/-5 .3'( 14 t,~ . q l • q., f-.D - s+ - 5 S ~D lo~.q .4'3 70S IA ,. () I,OtJ 4.0 - 54 - 6 b ;/.) :lIO. 5 .60 ?-, 721 1,4- ,. '31 4.0 - 54 - 7 1- .10 l/~. Col .Sq ':1'l. 1'6 2.05 '2.~ 5".5 - S4 - 8 B 3S- ~ 1'1. q ,q :l. ,:/-1 11 ~./S ".13 11.0 - 55 - 9 4f 'too .2~~.\ .9'8 ;aq -:;&:r 2.45 ';l • :I" '1'.0 - ~S - 10 I~ itS' 2:1.(, .55 J.O ,q rs 'l.~ l.lB ~·D - -~ ::> .. ::> - 11 /I 1iu 2 30 .~1- I. (Jc, 10, ?3 " .25 2.~ ~.6 - 5'5 - 12 /1. !J'S- J.35·t ,.oS 10, 1-3 2·2.5 2.~ ,,".0 - 5"(.- - 13 ~ I /,0 ;1.JQ. ~Ol . 4.3 7:5 ~l. 1.00 ~ (. .0 - ~ - 14 2 b~ 2~J .4 S4 -"1-':1 "93 ,,15 I.lf£ 4. 0 - /5 - 15 3 7 0 l4~ .1- .'1-0 t<l 14 ,. (p /. tol ~.o - 55 - 16 It 15" 1.S(J • .2 .ff, 8' 1-5 ~IO I . 't'?' 5.S - 55 - 17 ~- 'It> .lS,\= • ::J5 . ~ I 'iiI 75 I ,. i'S I.Y~ ~.5 - ~~ - 18 , tS" ~sr . .'6 . qt, Y,.2. -:}> ~.2 ~ . .ll ~,5 - 5<- - 19 1 ~o .2"~ l.;$ I,() >1"? ~ ~.3 :1.:30 <6.0 - 5~ - 20 8 "'5~ J.~ -:f. 00 I f ~~ =1'5 :l.SS ".53 q .0 - S'(. - 21 f lilt) Al'l . ~S I. I -B'2 15 ~·65 1..6.3 '1.0 - S't; - 2% '0 JIIS' 'J.':I-~ I 3D /' I 8;) I ':J5 . 1 ~.~ a.S) 4.0 - 1$ - I 

23 " I/O :l/l.DO ! t. , I jl I 

I 1-3 ~.5'; :J.53 9. tJ I - 5'S - I 

24 J'l. II~- ;)<&5. (p 1- I I. I ~J.. 15 I ~.$ ::L .5-" Cjt) - 55 - 2S r: .. J 1:11> ..290.3' 'I I ....... 

FINAL • FILTER EXIT for NJ Method 1 • FILTER BOX for .11 others. 

•• PROBE EXn , , (probe' fil fer ~IY to IIJ Method I. COHO. EXIT appl ies if s~lin9 train has a condenSer. 

/20 'Il{.SbB ~ ~ 12.1- 1.8c.1) 

"in .. (8) Vm (/6P)Z till ts OH '-1112 (PlIge 1) rev. 9 .. 94 
SAMPLIHG DATA - HETHOD(S) _____ _ 

CLIEHT __ :::S~~ub::;.:..A,:.:.;l-L....~_=::::;~_~ ___________ _ 

PUlIT d~Dt'=.· .. - "'P7Ar,·.. d~ <1'. 

CllT/STATE -n../~z , 0'; .108 NO. 

RUN NO. C./ /- YO~ 63 

1f-a,-Yr DATE /OJ4/<78 

TIME START /3 :d<e 

TIME FINISH If. :DO 

TEST PERSOtIIfEL ({14' l Rl:f1p 

POSTTEST POS PRESS LEAr J DC? • 

" SAMPL!MG LOC. t.I_,'-I :1. 

WCI1ETRIC PRESSURE, IN. HG 3D.2.B STATIC PRESSURE, IN. H2O ~ " 

Le!.x ·f, VACJUM IN. HG ....tE.:-

LEAK RATE, CFM e Pel, 

• CONDUCT POSTTEST POSITIVE PRESSURE LEAK CHECK fOLL~ING THE LAST RUN PER LOCATION. FOR OTHER RUNS, EHTER -N/A-. 

EOUI PMeNT Clf§:crs EOUrPM~NT liD, NUMBERS LEAl( HECICS 

~PITOT. PRETEST REAGENT BOX - M£TtR BOX 1:/-/9 y O·21.i.T I B -5' P I TOT. POS,TTEST PilOT M·q-/ Cp O.I~ NOZ'L N-Zl&> DIA. O.~Zo E E 

NOZZLE. PRE/POST Tt READWT Tt PROft UHB IL I CAL Y'1fte 

~ Tt ~ ·f PRE SAMPL'G BOX DltSAT PUMP TEOLAR BAG I I 

~ TC ~., POST NOMOGRAPH DATA E E 

~ DRSAT SYSTEM DELTA-Hil J. ;!?SZ B B 

FIL TER/rAD TARE \IT I METER TEMP. "fl 

S',-,:,J' I..~o 2 E E 

EST. XH20 

- "C" FACTCIt {2,.'fs-'1 fxrhes, X .!9! 

STACK TEMP .. " ...Q!:..... l1:L Q.2%~ 

N--blt 7PO REF DELTA-P f2: 'i'tl. ~...fL <+5% OF CAL'D T7 

2°~ """ FACTCIt 2.1U ---(nL (11)_' 

L GAS GAS TEMPERATURES ·F 

I CLoa: DRY GAS METER PITOT METER STAa:: ORIFICE SETTING, GAUGE O:II~ N SAMPLE TIME. READING, READING, TEMP., TEIU'. , IN. H2O VACl.UC, FILTER IMPING. 

E POINT MINUTES CUBIC FEET IN. H2O ·F ., ACTUAL IDEAL IN. HG • EXIT EX IT- , 

1 A I 0 "qC). ~8' .53 1-t!- ~ /.2 /,19 3.S - 61 - 2 5 :;q5S .4\ 7{ rJ ,'IS .'1< $.< - 5f .." 

.:l 

3 3 10 29,1, ~ · 42 Tt- -:f.J , ~ ~r • 9T '3-.<;; - S( - 4 4- /s 1£14.4-3 ~4-1. y,(j ~ J(1o ~q" 1».0 - 5( - 5 S ;'0 ..:so'". ~ ,SO ~o '?-6 /.lS I. IS 3.0 - 5"2- - 6 ~ ~5 305".45 .56 ~() -U 1':15 / .')(, 'Z5 - ~~ - 7 1 30 ~(!)K. 1-1- . i'Pl. g., . 1~ /.(jS /. tp' +.0 - S;2. - 8 35 I 

i1 ?,~ ·Sb .qO 3;).. rt- :z. ()S- 2.cx, S~5 I - 53 - 9 9 40 31~.=t3 J .m 9~ 1+ ~.3 2.;2Q It.!) - S.3 - 10 If) /.J~ 3,:2.' ·/~ I. O!) lit "":IT 2.4 ;]·40 Ib.< - s-+ - '1 /I r:o 3;)s.1r- /. {)5 ~+ TT ;/..+ .)·40 (J~ - S4- - 12 /2- 5S' ~'36 .25 /,~ ~j 7-% :2·f 'l.W l.n - Sf- .... 13 81 fJ() ~~4.+ .(,1 9-~ +b , ,4D l.4D 4,0 - S4 - 14 :2 IJ) ~g,33 . fA. h'1 1-Y 1.415 1.410 4.5 - ss - 15 ~ to 341.'\ . 1', ~~ :;8' I .1. G, I . {p;1. 4.5 - 155 - 16 4- 15 34s·&h . ¥o yt 1~ /.95 ,. S'$ 4.S - 55 - 17 5 ~6 34G. t-~ .qO ~5 ?f' 2·0 1.015·0 - 1$ - 18 {, ~ 353·15 I.IJD 'itT 1-8' £:3 ~:ij 5·0 I - 5S - 19 T- illl 358' . (5 1·00 g(, 1-~ :2 • .3> ~.l9 Ct.o - ~~ - 20 <&' fir ~~~ .(p~ {. J 87- ':f.¥' ~·5 ~.Sl (,.0 I -. s~ - 21 'I /{)(J 3~1 .~Lt I. i g~ 9-fl ~.5 ~,~l (".'5 - S'" - 22 /0 10'i 51-~. 00 { . I I ¥IC I 10( i 1.5 ;},S/I C .)1 - s<&. I - I 

23 II IIIJ "3 '1(g . "}I i ,. I I ~~ I 

T~ l..~ ~.s I (,.S I I - I 5"rl - 24 n- I/t( 3~J "51- I. I I ~'i "7<6 12. S ).,.5, !G.S - £1- - 25 E~ '7-4 ".:!>'8'(Q .05 I 

I 

FINAL 

• FILTER EXIT for NJ Method 1. FILTER lOX for all others • 

•• PROBE EXIT' J (probe & filter ~r~ppIY to NJ Method 1. COHO, EXIT applies if sampling train has a condenser. 

120 CjS,(,e;A ..9.B'Sb ~ 1'·9 1.881-

"in. (9) Vm (J'6P)Z tm ts LlK ' F·"1Z (Page 1) rev. 9-94 
.;: . 

MOISTURE ANALYTICAL RESULTS 

i:lient 

Pl&nt H~~ ______ . ________________ ~ ______________________ __ 

Run Nw:aber 

Sampli.ng Date 

AnUy.ia Data 

AnAl.y.t 

Reagent 1 (pol N "'LoH ) 

Final. Weig~, 9 

Tared Weight, 9 

WAter catch, g 

Reagent 2 ( __________ _ 

Fional. Weight, 9 

Tared Weight, 9 

.. : .. :'~'. water' Catch, g 

Reagent 3 ( ___________ , 

COND1!:HSED ~, 9 

sU.i,ca GeJ. 

Final Weight, 9 

':arad Weight, '1 

ADSOR.BJ!:l) ~, 9 

I~ ~ corr Ec:%D, q 

Sampl.ing Lac • 

......,;;.(..1.;....2:.--3<:;D:;.:;."'_ • .,;;O;...:,.1 __ -,I I Lc Z - ~o" -~ 2-

,,4',0, ,~b.,h" y • 

;/10 

-...J.g 

/0 

~ 10. ti' "I. 7:. ~De> ,',1 :b7d.Q 

I 4.ID.~ .. ll.f 

.1. h No. 9'-0 .311 

I I 

I 

c.. 'Z ·";fe~ .. D..J 

,oh,fi;1 

~, 

" 

210 

(0 

10 

I Sf. -? 

~S-O t> 

3:.. 'I 

I .. lance 110. __________ _ T')'pe C./) Triple Ie • ....::::' Elect""",c _ .~t ~Mo, ______ __ 

.. , ... ,. 
SAMPLING DATA - METHOD(S) 30~ 

CLIENT __ ..",.-_--~--__:'---------------

PLAIIT (}I-Ut.D_/M Pl.4n"'fj &. RUM NO. 42.-30(,-01 

CITT/STATE "('w IS4 , OJ' .108 NO. 9E-a"-~11 DATE IDh"/~f 

SAMPLING LOC. _--!:U~N:.:..".:..:f;":::""-_r:---:-:::--___________ -:-::____ TIME START -= 8:/S'" 

BARtMETRIC PRESSURE. IN. KG aO.31 STATIC PRESSURE. IN. H2O X 1 TIME FINISH /0:11 

LEAl J. VA""'" IN. KG ~ ~ TEST PERSO''''EL _I(.",;,.wt.-=~~ ___ _ 

LEAl RATE. eFM 0.00'2. O.Oo.L POSTTEST PaS PRESS LEAl: J CC7 • 

• CONDUCT PasTTEST POSITIVE PRESSURE LEAK CHECK FOLLOWING THE LAST RUN PER LOCATION. FOR OTHER RUNS, ENTER "N/A-. 

EOUI PMENT CHEen EQUIPMENT 1.0. NUMBERS LEAl: ~KECkS 

VI PI1Dr. PRETEST REAGENT BOX - METER IIQX '" ... ¥ , l,003 B I 

3',PI101. POS,TTEST P ITOT ~-~=!i. Cp o. '" 1102 • L N-l~"7- DIA. 0,,9"1:. E E 

___ NOZZLE. PRE/POST TC READaJT TC PROlE UMBILICAL 

~ Te ~ ·F PRE SAMPL'G BOX ORSAT PUMP TEDUR BAli B B 

Te ·F POST E E --- - NCMJGRAPH DATA ~ ORSAT SYSTEM DELTA·H; J. 81:.1-

fiI'j B B 

FIL1EA~ TARE lIT. METER TEMP. 

,p,oo EST. :H2O ~% . E E 

S'"If,. 

"C" FACTOR • JS~ l·o5j Fxrites, % !9! 

STACr: TEMP. h, ~~ ~OOO 

t:!. ... OI!.. aeJ2 REF DELTA·P -EJ;:;f!! l·loa t!o"L ~ <+5% OF CAL'O Y7 

sa~ """ FACTOfl V U& 1,"'0 (n~ (N)_' 

L GAS GAS TEMPERATURES "F 

I ClOCr: DRY GAS METER PITOT METER STAa: OftIFICE SETTING, GAUGE ';K~ N SAMPLE TIME, READING, READING, TEMP., TEMP •• IN. H2O VA"",". FILTER IMPING. 

E POINT MINUTES CUBIC FEET IN. H2O ·F "F ACTUAL JDtU IN. HG • EXIT EXIT- ./ 

1 A-I 0 ~SZ59S' I. + 5'2 ~o 2,n- '2. :1'1- S' N/14 '18 11M I ..... v 

2 2 5 ~5'5.q'l /.i4!J 51 "'2 I 

2,&" 2. " ~ I ~Lj 

3 j 10 it,o.IAB 1.(00 S2 lPZ 2,s'Q .2.$9 t! So 

4 'I 15' L/6,~4'1 /.(00 52 (D2. 2·!i'CJ 2,S'1 L/ $1 

5 S' ~o 4'8. iDS' /.5'0 53 (#"2- 2.1/'3 2.~3 ~ $.3 

6 " ).{- 1./12. 1-&:. 1.4/0 S-3 ":z. ~.21 ~.21 ~ S~ 

7 r 30 '1':/(" '11- 0·1'1 53 ("3 /.3(0 I .. ~~ .3 ~S" 

8 SO 36'" I q'f'J. tj 1 lo.~' 5~ G73 /.31 1.3/ 3 5'3 

9 , _'/0 4'82. '8::1' 0.14 S"3 ~3 1.20 /.20 3 50 

10 IlJ L/5" ~8s:':r afDB SS '-.3 1·/1 1./1 .3 49 

11 " ':>0 ~e~.~z 0.61'1 51, ".:3 /.0,/ /.0'/ Z. ~9 

12 tl « 1/91.15 O.S'I S,? ,,-~ ().83 O.f3 2. ~9 

13 &,1 Go LftJ:3S~2. 0.91 5~ ("3 1.S'9 I,S-q .3 "/9 

14 z (g) 1./'1'. iLl 0.95 .5'8 6,'/ I.S"S- I.Ss' .3 'I? 

15 3 10 500.0:# O. iCf ~ (PL/ l.lI' /.,,~ 3 Iso 

16 f 1( S03 . .:??' 0.'5' 5'11 ~t.J /.39 /.3'1 3 SO I 

17 S" 8tJ 50fa_ JS" O.i3 S-q ""'I /. '3(P 1·3" 3 So 

18 V 15 S09.'I3 o· 1-" '-0 (p4 1.21 /.2.1 ...:3 so 

19 'J.. _'10 !llt.3'1 0.'1'1 (PO fs,l/ j.(,2 /,(p 2 .3 S-I 

20 ~ q(' -'15".1-'3 /.0/ (PO I GIS" /.t,S- I.(PS' t! So 

21 '1 10{) 5"1'1./'1 11.10 /DO &S' 1/.90 I.~ 4 Sf> 

22 IV I()s 512, 1(' I/./S- ' roo i ",s- , I· f'i I,~' 

.. -;;. I,.s-I I I 

123 JI I lIP ! 52(;,34 ! 1.1.0 !"o ifil' I/-Cf" 1.'1('~ sz I I 

24 rz. 115 S30.ofI 4/1- I (., I i bfo I/.tll 1·'11 i 9 S'z I 

25 ~NJ) JZV 533 fo5'b I .. ~ I 11 I"""" v 

FINAL " FILTER EXIT for HJ Method 1 • FILTER BOX for .11 others. 

•• PROBE EXIT' J (probe & filter heat off) apply to NJ Method 1. COHO· EXIT applies if sampling train has a condenser. 

1'Xi) ~l.O"'1 I.OJ"7 5".3 '3.'1 I. 130fd %1:/Dt}.1. 

MIn. (8) Vm (0)2 tm tS uK F-1l12 (PDge 1) rev. 9-91. 
""', 3 

... 

SAMPLIHG DATA - HETHOD(S) ePA _ 30f6 

CLIENT __ ~ ___ --:::-;-_--::;-_____________ _ 

PLAIIT Ch~/'u_ PIAn"1 tb. 

CITT/STATE ~/SA, 01( 

lUll 110. t.H-!JDI.-Z 

.108 110. 9!-~'-.i'{/ DATE l()b~/9r 

SAMPLING LOC _ __ ={J~~';..:.·f_-..;;;Z;;.....------- TIME START __ /~I :..,;O....;?-:.-__ 

IARCl4ETRlC PRESSURE, III. HG .!lO.~' STATI : PRESSUR~, IN."2O i! :t TIM( FINISH .... 1... 3 ... : '_:2. ____ _ LEAl J, VACUUI'I IN_ HG ~ ~ TEST PERSOUIEL ......:;;I&~~;..=:.-__ _ 

LEAl: RATE, CfM (j.ODD 0.001 POSTlEST POS PRESS LEAl: ./ 01:7 • 

• CONOUCT POSTTEST POSITIVE PRESSURE LEAK CHECt FOLL~ING THE LAST RUN PER LOCATION. FOR OTHER RUNS. ENTER NIi/AN. 

EQUiPMeNT CHECKS EQUIPM~NT 1_0: ~UMBERS LEA" HECr:S 

l~lTOT, PRETEST REAGeNT BOX METER BOX t.,,-~ Y 1.. 0 030 B a 

--..L. P ITOT, POSTTEST PITOT H'i-!/' Cp ~ IfQZ'L t:/.-o.Z OIA. f2../f-Z E E 

~NDl2LE, PRE/POST Te READClIT it PROIi1: LtlBILICAL 

~ Te ~ ·F PRE SMPL • G BOX ORSAT PUlP TEOLAR BAG B a 

L Te 1£.. 'F POST NIJ40GRAPH DATA E E 

- ORSAT STSTEM DELTA-Hil 1.8i1= 

B B 

FlbTERlXAO TARE \IT I fETER TEMP. TO E S,1~ EST. XH20 2 . E l!J"O 

"c" FACTOR I.O~ Fxrites• % lSI! 

STAa: TEMP. 10 .12!:- ..et.:L a .. 225 

C/. .. Q.I!. .aoo REF OELTA-' l·lQ.f ~ -1.:..L <+5% OF CAL'O T7 

:lIO "I(" FACTOR l. ",t.O - cnL (10_' 

L GAS GAS TEMPERATURES 'F 

I CLoa: DRT GAS METER PITOT METER STACK OP.IFICE SETTING, GAUGE 

N SMPLE TIME, READING, REAOING, TEMP., TEMP., IN. H2O VAClAM, FILTER IMPING. a:"~ E POINT MINUTES CUBIC FEET IN. H2O 'F 'F ACTUAL IDEAL IN. HG " EXIT EXn"" ./ 

1 .-1 0 533. 83+ /.2- ,"0 (08 I. 'I :{" liS- q Hi! I/f NIA 1'-" V 

2 2- S' 531-. sS- I. IS"' "0 '1- /.'31- I. f7 i' / ,,~ '. 

3 ..3 10 Sl/I.ll /.07- {PI "1- /·1" /. -u, 'I i/fJ 

~ 4 "- ,f' Si/cf.}S 1./1 (PI ('1- f. fl /. ~/ 'I 4Y 

5 5 to S"f~ 1.0/ '" '1' I.'S- l.lP$' .3 5l) 

6 ,;. z'f" SSI. -:;/ O.qq {Pt ~9 f.(11 Z I. ('2 .3 S7> 

7 "1 3D 5S5:13 1.11- {;.S ~(, I.ftl /.a¥ 3 5'"1 

8 r 3r I Ssg.(plJ /.01/ <os ("1- /.-:JO /. 10 3 5'1 

9 , '10 56'Z'/r ,.00 fD3 (j,r I.'LI /.~'I .3 5"2. 

10 ID 'If' S(gS:5'~ O. q'1- "l/ G,8 1.S1'J 1.r1 3 5'2-

11 " Sb 5'8 " O.B~ (,~ (DCJ /.1/('" 1.1./(' 3 S'q 

12 1'2- S"~ 512./2- O.ff (P$' G,Cj '·33 1·33 .:3 S-t/ 

13 

'~I '0 S"1S: 201 O.S't/ filS- fD9 o.C;¥ a·C)? 2- $'2.. 

14 2 bS' 5=11,1/ 0·("3 '''' {g9 1.00{ /.01/ 2- ~Z 

15 3 ;t> 5';0.1/5' O. r,S- (,,"1- 1 1-0 1/.07 1.01- Z 51 

16 4 "1f' SV"J.19 o. lo8 ,,1- 1-J 1./2 1./7- -z. S7 

17 ~ to S"9'.O(P D.1-!; .l.t1 '11 1/.23 1.23 :3 S7 

18 6 fS' s-g't.ol O.8t (Dt- 12- Illfp I.t/b 3 5"2-

19 1- '90 SCf~.:l" D.Cjq ~S I '17.. /.,z 1.'2- 3 ::rl 

20 S' ,~ 595:11 /.2S'" {P11 72 Z.OS- 'Z.os- t/ S"Z. 

21 9 /00 SCJ't.5~ I.SI 1 G.9 1-2- .:;. 'If ,1. 'If ~ 5'1-

22 (0 lor 'o,.1fp 1/.1S ~q I 13 I :2. gr, 1;/. ft? 12)" ~:2. I 

23 I (,()~.;1I 1 <09 ~ 13 Ip.q'l ~ 53 I 

1/ 110 I·fo ~.q,,- I 

24 L1. ,,< (P12. +f /.{PO I 70 I 13 I 2. "2- 1· r,Z S:J. 51/ 

25 lelJJJ rzP '11.0$'3 i ~ ... I.L 

fiNAL • FILTER EXIT for NJ Method 1 • FILTER 80X for .11 others. 

•• PROBE EXIT' J (probe & filter heat off) apply to NJ Method I. tOMD.EXIT applies if sampling train has a condenser. 

I~O (j3.2Ih '.OlL,,/, 61;'0 k,9.¥ '.e/Nf 1./1/.0°.1 

Min. (9) Vm (/@,2 tm H CoH F·1112 (Page 1) re~. 9·9 .. 
SAMPLIHG DATA - HETHOD(S) _____ _ 

CLIENT 'S<!,c~ A,;c. VeNt ..sv~ 

PLANT ChlCD..,lu_ flAn'1 C; RUM 110. y~ a 7D~·t) 3 

CITT/STATE -r;,.ISA, e)k. JOB 110. 9i.cl,* ·111 DATE IOUt/f, 

SAMPLING LOC. Uwi/2. _-,...____ TI~ STAaT --,-1~3:.~~i __ _ 

uaClETRIC PIESSURE, III. HG 3D.30 STATIC PRESSURE, III. H2O 4. S- TI~ FIIIISH 1$:1/3 

LEAJ: J, VAClUC IN. HG ~ ~ TEST PERSOIIIIEL ___ I{:.;::..;.""'.::;... ___ _ 

LLU RATE, CFM D.DD' 0-001 POSTlEST PO$ PlESS LEAl:: J ex7 • 

• CONDUCT POSTTEST POSITIVE PRESSURE LEAK CHECK FOLLOWING THE LAST RU~ PER LOCATIO~. FOR OTHER RUNS. EIITER MiliA". 

EOUlem;NT CHECtS EQUI~HT laD. IIUMBERS LEAl: ~HECI:S 

~PITOT, PRETEST REAGENT lOX - MElt_ BOX ,(,~~ , l·O{2,3 B 

~PITOT, POSTTEST P ITOT t:1.1J:!/. Cp a1:IICOZ'L I: cJ,-197- DIA. at:l. r E 

2 NOZZLE, PRE/POST TC READClST TC PROft UDlIILICAL 

-L TC ..1!2.- ·F PRE SAMPL'G BOX alSAT PUMP TEDLAI lAG I B 

2 TC ..1L. ·F POST E E IIC110GRAPH DATA £ CJtSAT SYSTEM DELTA-H; l. 8?-"1-

1:Q I B 

Fn, TgIl.AD TARE VI a METER TEMP. E 

~,'l~ JfT) :l . E 

EST. JHzO 

"c" FACTOR l·()~ Fl/:rites, % !9! 

sua TEMP. zQ ~ ~ Q·22l. 

tJ."J)/ :JrJO REf DELTA-P /./01 -- ..Qk... ..!.:!L <+51 OF CAL'D T7 

"r" FACTat /. ,,(,() (nL (II)~ 

L GAS GAS TEMPERATURES ·F 

I ClOCt DRY GAS METEI PITOT METER STAa OP.IFICE :UTING, GAUGE ~K~ II SAMPLE TIME, lEADING READING, TEMP., TEMP., IN 20 VAC1JUM, fiLTER IMPlIIG. 

E POI IT MINUTES CUBIC FEet III. H2O ·F ·F ACTUAL IDEAL IN. KG • EXIT EXn- J 

1 13-1 0 '11.~''1 I. I '9 ~IJ /. flo ,. f6 .3 /'J/A .5"'/ ~~ IL 

2 2 S" ,;to. 8" ,~s- 'tt W 2,DY ;l.W 1/ s-¥ # 

I 

3 3 /0 c,:1v.(g Y I.I? '9 ~Y' /.9/ 1.91 l/ $3 \ 

4 'I ,(, ,,~g.3S /.'$0 fit 7t1 7.1'$ 2.13 L/ 53 

5 S'" 20 "3::1. :1.1- 1./0 G.C)' 1'1 I. go I. S'I '" 5'".3 

6 , '21' (" $'.'" {).q~ 10 '11./ 1. (.1 1,(111 .3 s-4 

7 :J... 3tJ '~9..:14 I. IS" ":fQ • 1-5 I.g" I. Df ~ 51/ 

8 ,I' I 

V ~";l.8q /.00 10 7I-S" /.~3 /. fo3 -~ .s-S9 'I '10 (;1./'.21 O.~q 10 ':1-S"" 1/.IIZ /. (g-z. 3 sr 

10 10 'If' ~ 'I1.(pb o.Q4 :10 ";fS- ,·set I.S~ 3 5::;' 

11 II )~ (;,,,.3.01 o. <iiI 1-1 7-S' /.11'1 /.'19 3 ~~ 

12 .2, S-$" " 5'1..2.1- O.S" "1-' 1-5'" 1.'3~ /.31/ -~ 5'"'-

13 A-I flO 6SCJ.331 1.7I-S- '12 :r1- 2.B? Z./? -S- S"8 

14 Z. b!' '''3.95' I. c.o 12 11- 2.bl 2.(,/ S- ~I 

1S 3 to t. 'f.:1" 1.50 +:3 i':l :/.q~ Z.l./J- S- S:J... 

16 1/ 1-( t, 11. 'Ill I.'S- _7'_'!I -"11- .2.10 2·10 S- S'z. 

17 f' If) ~1'. 'ib I.Sf _1~ .110- 1..1,,11-· 2.'11- if- S3 

18 r;, It' ~ ~/.Of/ '.~5" 14 11- t.oS" 2.0S--/ t/ 5J 

19 1- fO G 8'1.1'1 0.9;' 1'1 1" I·s/ J.n! 3 S"2. 

20 g ",t' Gig.lS- O.9S- 1-_~ l' /.s6 I . .>'- 3 sz. 

21 , I Of) C:/I/.SZ 0.82- 1S'" 1-t- /. ~.5""" '.'5S- 3 53 

22 /(1 fi)(" (,,9'1. f,S n. ~4 7-~ 1 11- 1,.1.1, 1/·22 "3 53 I 

23 II 110 ("q 1. (,1 I O. (J) L/ ~- I~ I. nt.. 1.0'" ~ $~[ 

, 

24 I~ liS /OO.3r O.S"q 1W U I o.t;1- 0.11 "2. SY I 

25 e~ I'll> "JO~ooq 'l.. I ;-

FINAL • FILTER EXIT for NJ Method ,. FILTER BOX for .11 others • 

•• PROBE EXIT' , (probe , filt~r heat off) apply to NJ Method 1. COHO. EXIT applies if sampling train has a condenSer.-

11..0 1 S'. 145" I. ()9;ll'l.. ..1t..1... 15'. (, ,-'l'J ,;, ~ (00. V 

Min. ee) Vm (~)Z tin ts 011 F-1112 (Page Ii rev. 9-94 
Appendix C - ADalytical Data for Total Chromium 

, , 

I 

I 

I ," t 

"I , 

! 

j" 

I 

I 

i , .. I 
pace Analytical 

RMC Environmental, Inc. 

P.O. Box 1008 

Elgin, IL 60121-1008 

Attn: Ms. Rachel Chleborowicz 

Phone: 

Solid results are reported on a wet weight basis 

Pace Sample No: 10904266 

Client Sample ID: UNIT 11 Ul-306-01 

Parameters Volume Results 

Metals 

Units 

Method: EPA 6010 

DATE: 11/03/98 

PAGE: 1 

Pace Project Number: 1010387 

Client Project ID: CHROMIUM PLATING CO. 

Date Collected: 10/19/98 

10/22/98 

Matrix: Hater 

Date Received: 

PRL Analyzed Analyst CAS I Footnotes 

~tals, ICP Prep Method: EPA 3010 

Chromium 310 mls. 125 ug/L 10 11/02/98 

10/27/98 

TEM 7440-47-3 

Date Digested 

Pace Sample No: 

Client Sample ID: 

Parameters 

Metals 

Metals, ICP 

Chromium 

Date Digested 

10904274 

UNIT 11 Ul-306-02 

Volume Results Units 

Method: EPA 6010 

330 mls. 109 ug/L 

0. 0 368"'6-

Date Collected: 10/19/98 

10/22/98 

Matrix:Hater 

Date Received: 

PRL Analyzed Analyst CAS # Footnotes 

10 11/02/98 

10/27/98 

Prep Method: EPA 3010 

TEM 7440-47-3 

0.031.0-,-
pace Analytical 

Pace Sample No: 

Client Sample ID: 

Parameters 

Metals 

Metals, rep 

Chromium 

Date Digested 

Pace Sample No: 

Client Sample ID: 

Parameters 

'ls 

Metals, Iep 

Chromium 

Date Digested 

Pace Sample No: 

Client Sample ID: 

Parameters 

Metals 

Metals, ICP 

Chromium 

Date Digested 

Pace Sample No: 

Client Sample ID: 

Parameters 

Metals 

Metals, ICP 

Chromium 

Date Digested 

10904282 

UNIT #1 Ul-306-03 

Volume Results Units 

Method: EPA 6010 

DATE: 11/03/98 

PAGE: 2 

Pace Project Number: 1010387 

Client Project ID: CHROMIUM PLATING CO. 

Date Collected: 10/19/98 

10/22/98 

Matrix:Water 

Date Received: 

PRL Analyzed Analyst CAS # Footnotes 

Prep Method: EPA 3010 

347 mls. 72.6 ug/L 10 11/02/98 

10/27/98 

TEM 7440-47-3 

10904290 

UNIT #1 Ul-306-04 

Volume 

277 mls. 

10904308 

Results Units 

NO 

Method: EPA 6010 

ug/L 

UNIT #2 U2-306-01 

Volume Results Units 

Method: EPA 6010 

386 mls. 148 ug/L 

10904316 

UNIT #2 U2-306-02 

Volume Results Units 

Method: EPA 6010 

0.02S2...,.. 

Date Collected: 

Date Received: 

10/19/98 

10/22/98 

PRL Analyzed Analyst CAS # 

Matrix: Water 

Footnotes 

Prep Method: EPA 3010 

10 11/02/98 

10/27/98 

TEM 7440-47-3 

Date Collected: 10/19/98 

Date Received: 10/22/98 

PRL Analyzed Analyst CAS# 

Matrix: Water 

Footnotes 

Prep Method: EPA 3010 

10 11/02/98 

10/27/98 

TEM 7440-47-3 

o. D5"l'-r 

Date Collected: 

Date Received: 

10/19/98 

10/22/98 

Matrix: Water 

PRL Analyzed Analyst CAS # Footnotes 

Prep Method: EPA 3010 

361 mls. 68.5 ug/L 10 11/02/98 

10/27/98 

TEM 7440-47-3 
pace Analytical 

Pace Sample No: 10904324 

Client Sample IO: UNIT 12 U2-306-03 

Parameters Volume Results Units 

Metals 

Method: EPA 6010 

Pace Project Number: 1010387 

DATE: 11/03/98 

PAGE: 3 

Client Project IO: CHROMIUM PLATING 00. 

Date Collected: 

Date Received: 

10/19/98 

10/22/98 

Matrix: Water 

PRL Analyzed Analyst CASH Footnotes 

Metals, Iep Prep Method: EPA 3010 

Chromium 336 mls. ND ug/L 10 11/02/98 

10/27/98 

TEM 7440-47-3 

Date Digested 

0.000 "'1-
pace Analytical 

PARAMETER FOOTNOTES 

ND Not Detected 

NC Not Calculable 

PRL Pace Reporting Limit 

Pace Project Number: 1010387 

DATE: 11/03/98 

PAGE: 4 

Client Project ID: CHROMIUM PLATING 00. 
pace Analytical 

QUALITY CONTROL DATA 

Pace Project Number: 1010387 

DATE: 11/03/9:1 

PAGE: 5 

RMC Environmental, Inc. 

P.O. Box 1008 Client Project ID: CHROMIUM PLATING CO. 

Elgin, IL 60121-1008 

Attn: Ms. Rachel Chleborowicz 

Phone: 

QC Batch Method: EPA 3010 

Analysis Description: Metals, ICP 

QC Batch ID: 18021 

Analysis Method: EPA 6010 

Associated Pace Samples: 10904266 10904274 10904282 10904290 

METHOD BLANK: 10910800 

Associated Pace samples: 

l0904324 

10904316 

10904266 

Parameter Units 

Chromium ug/L 

10904324 

10904274 

Method 

Blank 

10904282 10904290 

Result PRL Footnotes 

NO 10 

MATRIX SPIKE & ~TRIX SPIKE DUPLICATE: 10910818 10910826 Matrix 

Parameter Units 

Footnotes 

------------------------------ ---------- Chromium ug/L 

LABORATORY CONTROL SAMPLE: 10910834 

Parameter Units 

Chromium ug/L 

Spike 

10899995 Conc. 

---------- ------- 1.000 1000 

Spike LCS 

Conc. Resul t 

1000 1021 

Spike Spike 

Result " Rec 

----------

1003 100 

Spike 

"Rec Footnotes 

102 

10904308 

10904308 10904316 

Matrix Spike 

Sp. Dup. Dup 

Result " Rec RPD 

----------

961.8 96.1 4 
pace Analytical 

QUALITY CONTROL DATA PARAMETER FOOTNOTES 

Pace Project Number: 1010387 

DATE: 11/03/98 

PAGE: 6 

Client Project ID: CHROMIUM PLATING CO. 

Consistent with EPA guidelines unrounded concentrations are displayed and have been used to calculate , Rec 

and RPD values. 

ND Not Detected 

Ne Not Calculable 

PRL Pace Reporting Limit 

RPD Relative Percent Difference 
Appendix D - Reference Measurement Calibration, 

Cbam of Custody and QAlQC Documentation 
DATE: 2123/98 -------

0.921 3.00 ·3.90 1.0000 0.0 10.000 10.000 

0.920 3.00 ·3.90 1.0000 0.0 10.000 10.000 

0.318 0.50 ·2.00 1.0000 0.0 5.000 5.000 

0.317 0.50 ·2.00 1.0000 0.0 5.000 5.000 

0.653 1.50 ·2.50 1.0000 0.0 10.000 10.000 

0.652 1.50 ·2.50 1.0000 0.0 10.000 10.000 

Nomenclature 

Pb Barometric: Pressure (in. Hg) 

Q AowRate (c:fm) 

Mi OrifiCE Pressure Differential (in H2O) 

M' Inlet Pressure Differential (in. HzO) 

V d Gas MeterVolume· Dry (ft3) 

V ds Stardard Meter Volume· Dry (ft3) 

T d A verage Meter Box Temperature (oF) 

To Outlet Meter Box Temperature (OF) 

Tds Averaf!J! Standard Meter Temperature (OF) 

Y d Meter Correction Factor (unitless) 

Y ds Staroard Meter Correction Factor (unitless) 

Mi@ OrifiCE Pressure Differential giving 0.75 dm 

of air at 68°F and 29.92 in. Hg On H20) 

Meter Box FuL ~ est Calibration 

089.085 099.240 10.155 69.0 69.0 69.0 

099.240 109.409 10.169 69.0 69.0 69.0 

119.800 124.909 5.109 69.0 69.0 69.0 

124.909 130.011 5.102 69.0 69.0 69.0 

149.131 159.379 10.248 69.0 69.0 69.0 

159.379 169.644 10.265 69.0 69.0 69.0 

Vacuum Gauge Thermometers 

Standard Vacuum 

(in. Hg) Gauge S~?;;ro Inlet Outlet 

5.1 5.0 

10.0 10.0 

15.2 15.0 

20.1 20.0 

24.9 25.0 

Operator: J. Buchen 

-------------------

94.0 

94.0 

81.0 

87.0 

94.0 

94.0 

Q 

83.0 88.5 10.51 

83.0 88.5 10.58 

83.0 85.0 12.88 

83.0 85.0 12.92 

86.0 90.0 14.90 

86.0 90.0 14.93 

AVERAGE 

Equations 

= 17.64 (Viii) (It) 

(fds + 460)(9) 

1.0034 

1.0020 

1.0019 

1.0033 

1.0044 

1.0027 

1.0030 

1.8811 

1.8901 

1.8680 

1.8796 

1.8646 

1.8721 

1.8770 
Pyrometer No.: 66-8 Office: Palatine, 11 -------- Calibrated By: J. Buchen Client: RIVIC£r 

Date: 2/23/98 Job Number: '1t-o,r. -311 

Calibration Reference Settings Pyrometer Reading for Fahrenheit Scale 

50 of 50 of 

100 of 100 of 

150 of 150 of 

200 of 201°F 

250 of 252 of 

300 of 302 of 

350 of 351 of 

400 of 400 of 

450 of 450 of 

500 of 500 of 

550 of 551 of 

600 of 601 of 

Calibration Reference Information 

Reference Used: Omega CI-23A ---""------- Serial No: T-123216 

Calibrated By: J.H. Metrology Co. Date: 3/4/97 

Report No: 9734-R26517 
.. Meter Box Post Test Calibration 

DATE: 10fl7J98 ------- Operator. D. Rybmsti ---~----

ProjectNumber: ~ .. --...:....:.---

o.as 2.SS -2.20 JJXXIO 0.0 10.000 IDlXlJ 125m 734917 91140 '1O.D 70.0 7ClD I3JJ 14.0 ~ 11.41 l.02lD 1.9013 

0.&$ 2.S.S -:uQ 1.0000 OJ) JIUJDO lO.lXlO n4.9J7 74U17 9.910 '1O.D 10.0 70..0 15.0 7SJ) 80.0 JI.41 1.Dlj9 J.9010 

o.as us -2.2D UlOOO 0.0 ID.OOO Hum 1«.8%7 15UD1 9..980 '1U.O 70.0 7D.D 17.0 16.0 11.5 ItA' Int16 1.9075 

AVERAGE 1.0160 

Nomenclature Equations 

JIb &romebk~Cin.Hg) 

Q Flow Rate Cdm) 

:: (YctJ [V-I 1d + Ali 

4601 Ph + AP /13h] tlzi&:e J'JeMae Differential (hi. H2O) Yc. 

IJP lDJet Pl'essnre Diffen:ntia1 (in.HzO) V4 1d. + 460 Pb + AH/l3.6 .. Vd Gas Meter Volume-DIy (fl3) 

Vds SludardMda-Vclumt;-Dry (fl3) AH@ = 0D319(AH). [0:.. + 460)8}1 

Td A~ M.eIft Box Tempemfure ("'f) P1><To + 460) (V.><Y') TD OIIt1etMeleJ'BaxT~("F) 

Td,s A~Sbll!Ct ... d Me!erTempe:ratureC"f) 

Yd MderComctian Faclw(uuitJess) = 17M (V.J @) Q 

Yds 5ImdimIMeIer'Cmrectioo. FitClor (UDilIei5) lTda + 460) (9) 

I .mG 0dfIce Pttsswe Dilren!IIIial glviDgQ15 dm 

of air al68"P and 29.92 in. Hg (in. ~) 

(] 

o :-1 

N 

OJ 

-

o 

.. 

-.l 
DATE: 11125197 

0.972 3.00 -2.70 1.0000 0.0 10.000 

0.972 3.00 -2.70 1.0000 0.0 10.000 

0.394 0.50 -1.80 1.0000 0.0 8.000 

0.394 0.50 -1.80 1.0000 0.0 6.000 

0.684 1.50 -2.20 1.0000 0.0 10.000 

0.684 1.50 -2.20 1.0000 0.0 10.000 

Nomenclature 

Ph Barom:!tric Pressure (in. Hg) 

Q FlowRate(cfm) 

AH Orilim Pressure DiHerential (in H20) 

l1P Inlet PleSSure Differential (in. H20) 

V d Cas Meter Volume - Dry (ftJ) 

V ds Standard MEter Volume - 01)' (ft3) 

Td Average Meter Box Temperature (OF) 

To Outlet Meter Box Temperature'(°F) 

T ds Average Standard Meter Temperature f'F) 

Yd MeterConedion Factor (unitless) 

Y ds Standard Meter Correction Factor (unitle;s) 

Mi@ Orifim Pressure Differential giving Q.75dm 

of air at 68°F and 29.92 in. Hg (in H~) 

10.000 

10.000 

8.000 

6.000 

10.000 

10.000 

Meter Box Full Test Calibration 

161.207 171.496 

171.496 181.788 

196.539 204.842 

204.842 211.059 

224.807 235.156 

235.156 245.502 

Vacuum Gauge 

Standard Vacuum 

(in. Hg) Gauge 

4.8 . 5.0 

9.9 10.0 

15.0 15.0 

20.1 20.0 

25.4 25.0 

10.289 

10.292 

8.303 

6.217 

10.349 

10.346 

71.0 71.0 71.0 

71.0 71.0 71.0 

71.0 71.0 71.0 

71.0 71.0 71.0 

71.0 71.0 71.0 

71.0 71.0 71.0 

Thermometers 

Standard Inlet Outlet rF) 

94.0 

94.0 

87.0 

87.0 

91.0 

91.0 

Operator: Michael Redel 

Q 

------------------

84.0 89.0 9.98 0.9905 1.6919 

85.0 89.5 9.98 0.9912 1.6888 

83.0 85.0 19.68 0.9832 1.7165 

83.0 85.0 14.77 0.9848 1.7188 

84.0 87.5 14.18 0.9871 1.7078 

85.0 88.0 14.19 0.9882 1.7071 

AVERAGE 0.9875 1.7052 

Equations 

= (Y~)[Vda][~ + 460][Pb + M'/136] Vd Tda + 460 1\ + ~H/13.6 

= 17.64 (VcJ (It) 

(fda + 460) (9) 
Pyrometer No.: 71-19 Office: Palatine, n ------- Calibrated By: Michael Redel Client: ------- Date: 11/25197 Job Number: 

Calibration Reference Settings Pyrometer Reading for Fahrenheit Scale 

50 of 50 of 

100 of 99 OF" 

150 of 149 of 

200 of 199 of 

250 of 250 of 

300 of 300 of 

350 of 351°F 

400 of 401°F 

450 of 450 of 

500 of 500 of 

550 of 551°F 

600 of 600 OF 

, 

Calibration Reference Information 

Reference Used: Omega Cl-23A -----.;;:~---

Serial No: T-123216 

Calibrated By: J .H. Metrology Co. Date: 3/4/97 

Report No: 9734-R26517 

-- .-
Meter Box Post Test Calibration 

DA'J'E; HVZ7J98 ---_._--

OJxnfor. D. Rybarslci ------~~------

Project Number: 9-~ Co ,.. 

0.70 1.5C ·2.00 J.fJOOO 0.0 10.mo 10.000 G.500 4J9.5Z1 695 15.0 76.0 80.5 13.99 1.0091 1.67J9 

0.70 1.50 .2.00 1.0000 0.0 tOlD) 10.000 419.Sl7 4191iDB Jo.O&1 69.5 flU (,9.5 un 19.0 ltu 13.96 Ul093 J.65SS 

0.70 1.so -2.00 1.0000 0.0 10JD) 10.000 429.608 439.711) 10.1 tl 69.5 695 695 90.0 10.0 SS.O 13.91 JJlOIJl 1.M'72 

AVERAGE 1.0092 

-... " -- Namendature Equations 

l"b Baromefrlc Pre:s&ure (in. Hg} 

Q Row lab! (dm) 

AU Ori&e = (Ydt>[V",!T. + 460J[Pb_~l1P 113.6] Pnsme Di.ffen:ntial (in. I~) y .. 

liP lniet PreMe 00krentW (in. JI:lO) Y.t T. + 460 It + AIl/13.6 

Vd Gas MeIer Volume -Dry (ft3) I 

Viis SIanda:rd Meta-VoJuroe· Dry Cft3) = O.m19(4H) [cr. + 460) e] 2 f 

Td A~MeIel'BoxTemperalml>("'F) . .dH@ 

To 0aIIeI Meler'loK rempeniture ("J-) 

1\ ('To + 460) (V.) (Y.) I 

Tds Al'I!IIlgeSllmdard Meter Temperature (o:F) I • :II 17.64 (v.}{P.} i 

'Yd MecerComdiOll Fador CunilIesBl Q l 

Yds Stimdard Mefrr Com!dion Padnr (unJt1ess) (T .. + 460) (6) j 

lalla Orifice P1eisme DifCemttial giving 0.75 am ~I ofair at 6S"FBDd 29.92 in.IIg (in_~ 1 

== . -.:-- - .... _ .. .- .-. J 

" G 

"' c 

... 

., 

'0 

> 

n 

~'
j 

) lolo-'bcnl 

F ~Ut:N r CHAIN OF CUSTODY 

JInD: {<WIt:- ~Nvi",.~ ~ 

11'111-13 ~/,,"r Sr-. 

}/tI~, IL &tJtL/7-

J>rojed: ehnJ_, '-- Pfl1ri~ 6J . 

CClCltaa: Rachel Odeburowicz 

1'l1cme: ·gOO·~ s-n- ""J3~1 

Fa'Jl: '.f'l1- -6~9- S"lg, 

r.o",; ,/1-0/' -}..!.L- , 

U the data will be reportrd 10 is state agency, which one? rJK... 

STANO. Dale Time Camp Grab Sampleld.l s..leAmt. 

%1, V"" lA '·30t. -01 -l/P().A-

, 

V U/- 30' -0'2. 

, 

,. tl 

II. ....... iJI-'3o~ -03 " 

'I V lJ ( -'l 0(' -0 <I- -i 

'( """ U2-1o~-ol if. 

I, ,/ lJz -10(, -07..- .. II ./ LI Z -'JOb -03 

- TatalllJmber of 

Containers: 

J 

().IroI 

/Vat tl 

.. 

" 

., 

I, 

" 

" 

Quote 

Analysis Wanted: 

10rnl 

t)A,IfJ--

Remarb 

f 0 4 L..f}, (:, 

'1/) l{2, 7 <f 

f /) l.fz,~ 

~f)'I2-qo 

fbt.!30cg 

? p 'ISifo 

?;} l.f3z..,Y: 

Datemme Rlceived ByISIgn. 

/{)-'Z~..fft- I l>VV 

DaIIiIIIH ReceIved BylSIgn. ftelnquilhed ByISIgn. OatdTIme Rec.lved ByISlgn. 

. 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 1 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

CAS #: 000544923 

FORMULA: CU CN 

CHEM. FAMILY: inorganic salts 

CHEMICAL NAME AND SYNONYMS: 

Copper Cyanide; Cyanide of Copper; MSDS 000410 DETAIL 00165 

Date: 16-NOV-200S 09:45:18.62 

100# DRUM 

MSDS No. 000410 Revision No./Date 02 970107 

Detail Number 00165/01 

SUPPLIERS NAME: Harcros Chemicals Inc. 

5200 Speaker Road 

Kansas City KS 66106-1095 

SUPPLIERS PHONE NUMBER : 

TRANSPORTATION EMERGENCY PlIONE NUMBER 

913-321-3131 

1-800-424-9300 

S.A.R.A. INFORMATION 

~S : Acute 

PHYSICAL DATA: Pure solid 

SECTION I HAZARDOUS INGREDIENTS 

--------------------------------.------ -----------.-------------------------------------------- Ingredient 

Cas Number 

Copper Cyanide Cupric Cyanide 

(CAS # 544-92-3 

SECTION II HEALTH HAZARDS 

POTENTIAL EFFECTS OF EXPOSURE 

MAX SARA AIR CONTAMlNENT LEVELS , APPLIES 

W/W 312 313 372 

100.0 y 

_~!;f~~ __ I ___ ~~~t ___ I ___ ~~~~ __ I~~~I~~ Y As Cyanide (From Copper Cyanide) 

TWA 5 mg/m3 OSHA 

y 

CEILING 5 mg/m3 ACGIB 

DESIGNATED SKIN HAZARD OSHA/ACGIH 

As Copper TWA/TLV Dusts & Mists 1 mg/m3 OSHA/ACGIB 

----------1-----------1----------1----1-----

This product contains potassium, sodium, or other metal cyanides which can be absorbed through all body tissues includ1ng the skin, lungs, and stomach. The cyanide ion (CN-) inactivates cellular respiration within the body resulting in rapid cell death. The 

symptoms of cyanide poisoning, which occur in rapid succession, include salivation, gidiness, 

Continued On Page 2 

.. 

.... 

.... 

"'-

.... 

0' 

"'-

tV 

lSI 

lSI 

01 

lSI 

tJ) 

.. 

01 

0' 

tJ) 

.... 

m 

A 

A 

O'l 

.... 

W 

lSI 

A 

.... 

tJ) 

......

w 

w 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 2 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

Date: 16-NOV-200S 09:45:18.95 

100# DRUM 

SECTION II HEALTH HAZARDS (CONTINUED ) 

headache, heart palpitations, difficult¥ breathing, unconsciousness, and death. A cyanide antidote kit must be available at all t1mes. 

EYES 

Bye contact with product may cause irritation burns irreversible damage even death 

SKIN 

Skin contact may cause irritation burns even death Absorption thru skin may cause symptoms described under inhalation and ingestion. 

INHALATION 

Inhalation may cause headache dizziness nausea breathing difficulty vomiting unconsciousness 

convulsions even death 

INGBSTION 

Ingestion may cause headache dizziness nausea breathing difficulty vomiting unconsciousness 

convulsions even death 

TARGET ORGANS 

OVEREXPOSURE MAY CAUSE DAMAGE TO, 

DISORDERS OF, OR ADVERSELY AFFECT THE FOLLOWING SYSTEMS, FUNCTIONS, ORGANS: blood pressure FIRST AID 

FIRST AID EYES 

FOR CYANIDE EXPOSURE: Immediately flush eyes with plenty of water, remove contaminated clothing, and keep patient quiet and warm. If symptoms of cyanide exposure occur, see first aid for skin, below. Call a physician. FIRST AID SKIN 

FOR CYANIDE EXPOSURE: Wash skin promptly to remove the cyanide while removin!1 all contaminated 

clothing, including shoes. Do not delay. Skin absorption can occur from CYan1de dust, solutions, 

or BCN vapor. Absorption is slower than inhalation, usually measured in 1lll.nutes compared to 

seconds for inhalation. Patient should be watched for at least 1 to 2 hours because absorbed 

cyanide can continue to work into the bloodstream. Wash clothing before reuse and destroy contaminated shoes. Call a phrsician. UNCONSCIOUS BUT BREATHING: 

Break an amyl nitrite ampule n a cloth and hold lightly under the patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 

minutes until the patient regains consciousness (usually 1-4 ampules). Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, consiaer holding the 

amyl nitrite under the nose continuously for the first ampule or more. Call a physician. NOT BREATHING: Give artificial respiration (100% oxygen), preferably with an 

oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule inside the 

resuscitator face piece, bein~ careful that the ampule does not enter the patient'S mouth and 

cause choking. Give oxygen s1multaneously. Call a physician. FIRST AID INHALATION 

FOR CYANIDE EXPOSURE: carry patient to fresh air. Lay ~atient down. Administer oxygen and amyl nitrite. Keep patient quiet and warm. Even with inhalat10n poisoning, thoroughly check clothing 

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PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

SECTION II HEALTH HAZARDS 

Date: 16-NOV-200S 09:45:19.31 

100# DRUM 

(CONTINUED) 

and skin to assure no cyanide is present. Call a physician. Rescuers of patients in an HCN 

environment should wear SCBA equipment. CONSCIOUS: For inhalation and/or 

absorption if the patient is alert, oxygen may be all that is needed. But if the patient is not 

fully conscious or shows signs of poisoning, see below. Call a physician. UNCONSCIOUS BUT BREATHING: Break an amyl nitrite ampule in a cloth and bold lightly under the 

patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, 

use a fresh a~ule every 3 minutes until the patient regains consciousness (usually 1-4 ampules). Give oxygen s1multaneously to aid recovery. Where more severe poisoning bas occurred, consider holdin~ the amyl nitrite under the nose continously for the first ampule or more. Call a 

physic1an. NOT BREATHING: Give artificial respiration (1001/; oxygen), ~referably with an oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule 1nSide the resuscitator face piece, being careful that the ampule does not enter the patient'S mouth and cause choking. Give oxygen simultaneously. Call a physician. FIRST ~D INGBSTION 

FOR CYANcrDE EXPOSURE: Conscious: Immediately give patient one pint of 11/; sodium thiosulfate 

solution (or plain water) by mouth and induce vomiting by having patient stick finger into 

throat. Repeat until vomit fluid is clear. Never give anything by mouth to an unconscious 

person. Gi ve oxygen. Call a physician. UNCONSCIOUS BUT BREATHING: Break 

an amyl nitrite ampule in a cloth and hold lightly under the patient's nose for 15 seconds, then 

take away for 15 seconds. Repeat 5-6 times. If necessarr' use a fresh ampule every 3 minutes 

until the patient regains consciousness (usually 1-4 ampu es). Give oxygen simultaneously to aid 

recovery. Where more severe poisoning has occurred, consider holding the amyl nitrite under the 

nose continuously for the first ampule or more. Call a physician. NOT 

BREATHING: Give artificial respiration (1001/; oxygen), preferably with an oxygen resuscitator. 

Give amyl nitrite antidote by placing a broken ampule inside the resuscitator face piece, being careful that the ampule does not enter the patient's mouth and cause choking. Give oxygen simultaneously. Call a physician. OTHER INFORMATION 

NOTES TO PHYSICIAN 

MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Medical treatment is normally provided by a phYSician, but might be provided by a professionally trained "qualified medical person" where a need exists 

and where State and local laws permit. Specific training for handling cyanide poisoning emergencies is eBsential, as well as being "in practice" for giving intravenous injections. Du 

Pont trains all personnel working with cyanide to use the first aid procedures, but not the 

medical treatment ~rocedure. While preparin~ for sodium nitrite and sodium 

thiosulfate inject10ns, use amyl nitrite and oxygen as outl1ned in First Aid. When ready and if 

the patient is not responding to first aid, first inject the solution of sodium nitrite (10 mI. 

of a 3' solution) intravenouslr at the rate of 2.5 mL/minute, then immediately inject the sodium 

thioBulfate (50 mL of a 25\ so ution) at the same rate, taking care to avoid extravasation. This 

is a fairly lengthy treatment (24 minutes) since a total of 10 + 50, or 60 mL, is injected at a 

rate of 2.5 mL per minute. Consideration should be given to the size and 

Continued On Page 4 

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Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 4 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

Date: 16-NOV-200S 09:45:19.66 

100# DRUM 

--------------------------------------------------------------------------------------------------

SECTION II HEALTH HAZARDS (CONTINUED) 

condition if the patient as treatment is proceeding. The above sodium nitrite injection is about 

1/3 of a lethal dose (see below), so care should be taken to avoid excessive use. It is not 

essential that full quantities be given, just because treatment was started. Injections can be 

stopped at any point if recovery is evident, but be sure to keep track of quantities administered 

in case treatment needs to be restarted. Relapse is abnormal if cyanide intake is not 

continuing, unless a large intake from swallowin~ occurred. Don't overreact. 

While prompt treatment is essential where poison1ng has occurred, treatment of a lucid, conscious 

patient would rarely be necessary. The effects of cyanide ~oisoning are immediate, not delayed, and a conscious person that can communicate does not have s~gnificant cyanide poisoning. For most accidental pOisoning, complete recovery occurs within 1-2 hours. If cyanide 

exposure was severe, watch patient continuously for 24-49 hours. If there is any return of sym~toms during this period, consider repeating this treatment using one half the amounts of 

sod1um nitrite and sodium thiosulfate solutions. Blood chemistry should monitored during prolonged treatment. caution should be used to prevent overuse of medical treatment chemicals as 

the prescribed dose is about 1/3 the lethal dose for an average individual. The nitrite converts 

hemoglobin to methemoglobin which reduces the oxygen carrying capacity of the blood. This is 

done purposely as methemoglobin attracts cyanide away from the body cells, but nitrite use must 

be limited to prevent hemoglobin deficiency. Du Pont has not experienced nitrite overdose 

problems; but being alert to this is important information to medical personnel. If signs of excess methemoglobinemia develop (i.e., blue skin and mucous membranes, vomiting, shock and coma), 1t methylene blue solution should be given intravenously. Administering up to a 

1 to 2 mg/kg of body weight over a period of five to ten minutes should be considered and 

repeated in one hour if necessary. NOTE: This procedure can free cyanide from 

cyanomethemoglobin. The free cyanide can again bind with cytochrome oxidase and, therefore, 

repoison the patient. If methylene blue is used, it must be used very carefully. It is best to 

avoid overuse of nitrite so corrective action is not needed. Historically, Du Pont has not had 

to use methylene blue to counter exceoD nitrite use. In addition, oxygen inhalation will be 

helpful. Transfusion of whole fresh blood may be considered if there has been mechanical injury wi th external bleeding and simultaneous cyanide exposure. When handling potential cyanide poisoning emergencies, keep in mind: 1. Cyanide acts rapidly, usually within seconds once 

it enters the bloodstream. Delayed effects would only be expected during brief periods (e.g., 

up to about 20 minutes) when (a) cyanide was absorbed into the bloodstream from the stomach 

after ingestion or (b) absorption through the skin occurred prior to skin washing, but 

entry into the blood was not complete. In treatment, therefore, treat what you see; don't 

overreact. It's rare when "preventive" use of the antidotes would be warranted. If you can 

converse normally with the patient, cyanide intake is limited and no action is called for other 

than to closely monitor the patient and keep him calm by reassurance of his condition during the 

following 20-30 minute period. 2. The half-life of cyanide in the body is estimated at 

20-90 minutes. The body routinely destroys cyanides from foods, cigarette smoke, etc. so cyanide is not a cumulative poison. In case of accidental cyanide intake, normal body action ~icklY 

begins cyanide destruction. In diagnosis and monitor1ng as mentioned in item 1, the cr1tical 

Continued On Page 5 

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MATERIAL SAFETY DATA SHEET Page 5 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

Date: l6-NOV-200S 09:45:20.29 

100# DRUM 

SECTION II HEALTH HAZARDS (CONTINUED) 

period is therefore short. Normally what happens in the initial few minutes after exposure will 

indicate the degree of poisoning. Du Pont's experience in treating cyanide poison cases is 

that first aid procedures using oxygen and amyl nitrite were effective and the only treatment 

needed in most cases. Medical treatment, using intravenous injections, was used in a few cases. 

Both procedures have been successful. For further information, see Du Pont Sodium Cyanide Storage and Handling Bulletin. 

ROUTES OF ENTRY 

eye contact skin contact skin absorption inhalation ingestion OVEREXPOSURE MAY AGGRAVATE DISORDERS OF THE 

central nervous system CARCINOGEN STATUS 

No components, present in excess ofO.~' by weight are listed as carcinogens by IARC, NTP, or 

OSHA. 

EXTRA INFORMATION 

FIRST AID MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Treatment for cyanide ~oisoning can be 

provided in two ways, aFirst Aid" and "Medical Treatment". Both require l.mmediate action to 

prevent further harm or death. First aid using oxygen and amyl nitrite is generally given by a 

layman before trained medical help arrives. Medical treatment is aggressive treatment involving intravenous injections of sodium nitrite and sodium thiosulfate, and must be administered by qualified medical personnel. Even if a doctor or nurse is present, the need for fast treatment 

dictates using first aid treatment with oxygen and amyl nitrite while medical treatment materials 

for intravenous injection are being prepared. ~erience shows that first aid given ~romptly is 

usually the only treatment needed for typical accl.dental poisonings. Larger cyanide l.ntake 

increases the need for medical treatment. Medical treatment is given if the 

patient does not respond to first aid. It provides a large quantity of antidote including sodium 

thiosulfate to chemically destroy cyanide in the body. However, even under optimum conditions, 

amyl nitrite can be administered faster and should be used even if medical treatment follows. 

Always have on hand the materials listed below. FIRST AID JUID 

MEDICAL TREATMENT KITS. Actions to be taken in case of cyanide exposure should be planned and 

practiced before beginning work with cyanides. In most cases, cyanide poisoning causes a 

deceitively healthy pink to red skin color; however; if a physical injury or lack of oxygen is 

invo ved, the skin color may be bluish. Reddening of the eyes and pupil dilation are also 

symptoms cyanide ~oisoning. workers should be trained to provide immediate first aid using 

oxygen and amyl n1trite resuscitators. In case of cyanide poisoning, start first 

aid treatment immediately, then call a physician. FIRST AID SUPPLIES FOR CYANIDE 

EXPOSURB: Adequate first aid supplies for cyanide poisoning should be conveniently placed throughout cyanide areas and should be immediately accessible at all times. They should be 

routinely inspected (typically daily) by people who would use them in an emergency. The total 

number of each item listed below should be adequate to handle the largest number of exposure 

cases reasonably anticipated, taking into account that some su~plie8 may be wasted, destroyed, or 

inaccessible in the emergency. 1. Oxygen Resuscl.tators-Tbe Flynn Series III Model 

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MATERIAL SAFETY DATA SHEET Page 6 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

Date: 16-NOV-2005 09:45:20.95 

100# DRUM 

--------------------------------------------------------------------------------------------------

SECTION II HEALTH HAZARDS (CONTINUED ) 

by O-Two Systems (800-387-3405) has performed well in Du Pont use. It is lightweight, rugged, and easy to use. 2. Amyl Nitrite Ampules (antidote) -One box of one dozen ampules 

per station is usually satisfactory. Locate stations throughout the cyanide area. 

CAUTION: Amyl Nitrite is not stable and must be replaced every 1 to 2 years. Store in the 

original dated box, away from heat. A common Du Pont practice is to use the resuscitator as the 

storage point for the amyl nitrite ampules. Avoid storage on vehicles where temperatures can 

reach 140-150 deg F or more. 3. A set of cyanide first aid instructions should be 

located at each amil nitrite storage location. Workers should be fully trained since in a real 

emergency there wi 1 be insufficient time to "read the book". 4. Two l-pint bottles 

of 1\ sodium thiosulfate solution for use in case of cyanide ingestion or plain water can be 

used. AMYL NITRITE NOTES FOR CYANIDE EXPOSURE: 1. Amyl nitrite is highly volatile and flammable, do not smoke or use around source of ignition. 2. If treating patient in a windy or drafty area, provide something-a rag, shirt, wall, drum, cupped hand, 

etc,-to prevent the amyl nitrite vapors from being blown away. Keep the ampule upwind from the 

nose. The objective is to get amyl nitrite into the patient's lungs. 3. Rescuers should 

avoid amyl nitrite inhalation so theI won't become dizzy and lose co~etence. 4. Lay the 

patient down for treatment to mainta n a good blood supply to the patl.ent's head. Since amyl nitrite dilates the blood vessels and lowers blood pressure, lying down will help prevent unconsciousness. MEDICAL TREATMENT KITS FOR CYANIDE BXPOSURB: Medical Treatment Kits for 

cyanide poisoning should be conveniently located for easy access by medical ~eople. Materials for 

intravenous injection are intended for use only bI a physician or fully quall.fied medical 

personnel. The location of kits should be careful y planned as part of the emergency preplan. Suggested locations for kits include: - in or near the cyanide area - plant medical station - entrance guard house - local hospital - doctor's office and residence CAUTION: 

Do not store amyl nitrite or Medical Treatment Kits on vehicles as heat build-up may ruin the 

amyl n~rite. Kits and amyl nitrite should be accessible but secured against tampering. They should be inspected regularly and the amyl nitrite ampules replaced every 1-2 years. Medical Treatment Kits should contain the following: 1. One box containing one dozen amyl nitrite ampules. 2. Two sterile ampules of sodium nitrite solution (10 mL of a 3\ solution in each) . 3. Two sterile atl1J?ules of sodium thiosulfate solution (50 mL of a 25% 

solution in each) . 4 . One 10 ml sterl.le syringe. One 50 mL sterile styringe. Two 

sterile intravenous needles. One tourniquet. S. One stomach tube. 6 . One dozen 

gauze pads. 7. A set of cyanide instructions on first aid and medical treatment. 

NOTE: QAmyI Nitrite" and "Medical Treatment Kits" can be purchased through local pharmacies with 

a physician'S prescription. As a help, you can inform the pharmacist that Eli Lilly and Co. 

produces the kit. 

SECTION III SPECIAL PROTECTION 

PROTECTIVE EQUIPMENT PROTECTIVE EQUIPMENT EYES 

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MATERIAL SAFETY DATA SHEET Page 7 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

Date: 16-NOV-200S 09:45:22.42 

100# DRUM ----~------------------------------------------------- --------------------------------------------

SECTION III SPECIAL PROTECTION 

chemical goggles face shield 

PROTECTIVE EQUIPMENT SKIN 

(CONTINUED) 

impervious gloves complete body covering PROTECTIVE EQUIPMENT INHALATION 

If exposure limits are exceeded, or if exposure may occur, use a NIOSH/MSHA respirator approved for your conditions of exposure. Refer to the most recent NIOSS publications concerning chemical 

hazards, or consult your safety equipment supplier. Respiratory protection pr~ams must be in co~liance with OSHA requirements in 29 CPR 1910.134. For emergencies, a NIOSB/MSHA approved pos1tive pressure breathing apparatus should be readily available. 

VENTILATION REQUIRED: Adequate ventilation is required to minimize exposure or to maintain exposure levels below 

OSHA/ACGIH requirements. Local mechanical ventilation may be required. ADDITIONAL PROTECTIVE MEASURES· 

Safety shower. eye wash fountain, and washing facilities should be readily available. In case 

of eme~ency or when dusting, misting, or splashing may occur, wear respiratory protection, eye protect1on, gloves, helmet, boots, and complete protective body covering. 

SECTION rv FIRE & EXPLOSION HAZARD DATA 

Flash Point (METHOD): > OR aN/A 

Flammable Limits (% Volume in Air) 

HMIS Info Health 4 

Fire 0 

React 0 

Special X 

EXTINGUISHING MEDIA 

UPPER: NID Lower: N/D 

media appropriate for surrounding fire 00 not use carbon dioxide. 

FIRE FIGHTING PROCEDURES 

Prevent human exposure to fire, fumes, smoke, and products of combustion. Evacuate non 

essential personnel. Firefighters should wear full face, self contained breathing apparatus and 

impervious protective clothing. UNUSUAL FIRE & EXPLOSION HAZARDS 

Toxic fumes may be released. Cyanides dissolve in water; therefore, cyanide solution runoff 

may occur if containers are opened or burned. Runoff should be contained to avoid environmental 

or safety problems. Contained cyanide solution can be detoxified with hypochlorite. 

SECTION V PHYSICAL DATA 

Continued On Page 8 

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MATERIAL SAFETY DATA SHEET Page 8 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 100# DRUM 

SECTION V PHYSICAL DATA 

Boiling Point: N/D 

Freezing Point: 883 deg. F 

Specific Gravity (H(2)O=l): > OR = 2.9000 @ 

Vapor Pressure (MM HG.): N/D 

Vapor Density (AIR=l) : N/D 

Evaporation Rate ( ~ =1): HID 

Solubility in Water: NIL 

Percent Volatile by Volume: NID 

pH: aqueous approx. N/D 

Appearance: SOLID - POWDER, CRYSTAL, FLAKE I GRANULE 

TABLET, PRILL, BRIQtJETTE, ETC. 

Odor : 

PLEASANT 

SECTION VI REACTIVITY DATA 

STABILITY 

68 deg. F 

Stable when stored in container under proper conditions. 

INCOMPATABILITY 

Date: 16-NOV-200S 09:45:22.93 

(CONTINUED) 

inorganic acids organic acids bleaching agents (oxidizers) Water or weak alkaline solution 

can produce dangerous amounts of poisonous hydrogen cyanide in confined areas. Avoid contact 

with bleaching agents and oxidizers which include chlorine, oxygen, permanganates, perchlorates, percarbonates, peroxides, chromates, hypochlorites, nitric acid~ and sulfuric acid. 

HAZARDOUS DECOMPOSITION PRODUCTS 

hydrogen cyanide Moisture will cause slow decomposition, releasing poisonous hydrogen cyanide and ammonia gas. HAZARDOUS POLYMERIZATION 

will not occur 

SECTION VII SPILL AND LEAK PROCEDURES 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: 

FOR CYANIDE SPILLS: Sweep up and shovel into a covered container or plastic bag, pending transfer, to secure the spill. Cover and keep spillage dry. Flush spill area with dilute 

solution of sodium hypochlorite or calcium hypochlorite to destroy the cyanide. Complr with 

Federal, State, and local regulations on reporting releasee. The EPA Reportable Quant ty for 

sodium or potassium cyanide is 10 pounds. DISPOSAL METHOD 

FOR CYANIDE DISPOSAL: This material may be a RCRA Hazardous Waste. Do not flush cyanide into 

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MATERIAL SAFETY DATA SHEBT Page 9 

PRODOCT NAME: COPPER CYANIDE 

PRODOCT CODE: 11237 

SECTION VII SPILL AND LEAK PROCEDURES 

Date: 16-NOV-200S 09:45:23.39 

100# DRUM 

(CONTINUED) 

sewers which may contain an acid. Detoxify with sodium hypochlorite, hydrogen peroxide, or 

calcium hypochlorite. Comply with Federal, State, and local regulations on disposal methods used 

to achieve the constituent based treatment standard, if permitted; or transfer to a licnesed 

disposal contractor. 

SECTION VIII 

Proper Shipping Name: 

Hazard Class: 

Label Requirements: Reportable Quantity: 

COPPER CYANIDE 

6.1, UN1587, PGII 

POISON 

All shipments are reportable 

SECTION IX ADDITIONAL INFORMATION 

LABBL SIGNAL WORD 

DANGER POISON 

PRECAUTIONS 

Wear protective equipment when handling. Use only with adequate ventilation. Wash thoroughly after handling. Do Not breathe dust. Do Not breathe vapor, mist I or dust. Do Not breathe gas. Do Not get in eyes, on skin, or clothing. Do not swallow. 

HANDLING 

For industrial use only. ATTENTION: This container hazardous when emptied. Since emptied container contains product residues (vapor or liquid), all labeled hazard precautions must be 

observed. 

STORAGE 

Keep container closed when not in use. Store in a cool dry place. Store in accordance with 

NFPA requirements. Keep out of reach of children. 

Continued On Page 10 

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MATERIAL SAFETY DATA SHEET Page 10 

PRODUCT NAME: COPPER CYANIDE 

PRODUCT CODE: 11237 

NAME: GENE TURNER 

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> .. MORE THAN 

100# DRUM 

N/A = NOT APPLICABLE 

N/D = NOT DETERMINED 

NIE = NOT ESTABLISHED 

Date: 16-NOV~2005 09:45:23.71 

DATE ISSUED: 930121 

DATE REVISED: 970107 

UNK '" UNKNOWN 

The information provided in this Material Saiet¥ data sheet has been obtained from sources 

believed to be reliable. Harcros Chemicals Inc prov1des no warranties, either expressed or 

implied and assumes no responsibility for the accuracy or completeness of the data contained 

herein. This information is offered for your information, consideration , and investigation. You should satisfy yourself that you have all current data relevant to your particular use. 

Barcros Chemicals Inc knows of no medical condition, other than those noted on this material 

safety data sheet, which are generally recognized as being aggravated by exposure to this product. 

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0,07 06/29/05 PERCBLOROETHYLENE INDUSTRIAL 

PRODUCT NAME: 

MSDS NUMBER: 

DATE ISSUED: 

SUPERSEDES: 

ISSUED BY: 

PRODUCT NAME: 

PERCHLOROETHYLENE INDUSTRIAL 

DW59009 

4/15/2002 

4/14/2000 

008360 

This MSDS has been reviewed and is 

current as of 6/28/2005. 

PERCHLOROETBYLENE INDUSTRIAL 

Distributed by: 

Univar USA Inc. 

6100 Carillon Point 

Kirkland, WA 98033 

425-889-3400 

Fax Server 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

TETRACHLOROETHYLENE CAS# 000127-18-4 99.9% 

3. HAZARDS IDENTIFICATION 

EMERGENCY OVERVIEW 

************************************************************************ * COLORLESS LIQUID. IRRITATING ODOR. TOXIC FUMES ARE RELEASED IN * 

* FIRE SITUATIONS. CAUSES SKIN IRRITATION. B.ARMFUL IF INHALED. * * CAN CAUSE DEATH IF TOO MUCH IS BREATHED. CLEAR ALL PERSONNEL * * FROM AREA. WEAR FULL PROTECTED EQUIPMENT. CONTAIN LIQUID TO * * PREVENT CONTAMINATION OF SOIL, SURFACE WATER OR GROUND WATER. * 

************************************************************************ 

POTENTIAL HEALTH EFFECTS (SEE SECTION 11 FOR TOXICOLOGICAL DATA.) 

EYE: MAY CAUSE PAIN. MAY CAUSE SLIGHT TRANSIENT (TEMPORARY) EYE 

IRRITATION. VAPORS MAY IRRITATE THE EYES AT ABOUT 100 PPM 

PERCHLOROETBYLENE. 

SKIN: SHORT SINGLE EXPOSURE MAY CAUSE SKIN IRRITATION. PROLONGED 

OR REPEATED EXPOSURE MAY CAUSE SEVERE SKIN IRRITATION, 

EVEN A BURN. REPEATED CONTACT MAY CAUSE DRYING OR FLAKING 

OF SKIN. A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT 

IN THE MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL 

AMOUNTS. DID NOT CAUSE ALLERGIC SKIN REACTIONS WHEN TESTED 

IN GUINEA PIGS. 

INGESTION: SINGLE DOSE ORAL TOXICITY IS CONSIDERED TO BE 

EXTREMELY LOW. SMALL AMOUNTS SWALLOWED INCIDENTAL TO NORMAL 

HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY; SWALLOWING 

AMOUNTS LARGER THAN THAT MAY CAUSE INJURY. IF ASPIRATED 

(LIQUID ENTERS THE LUNG), MAY BE RAPIDLY ABSORBED THROUGH 

THE LUNGS AND RESULT IN INJURY TO OTHER BODY SYSTEMS. 

INHALATION: IN CONFINED OR POORLY VENTILATED AREAS VAPORS CAN 

READILY ACCUMULATE AND CAN CAUSE UNCONSCIOUSNESS AND DEATH. 

DIZZINESS MAY OCCUR AT 200 PPM PERCHLOROETBYLENE; PROGRESSIVELY 

HIGHER LEVELS MAY ALSO CAUSE NASAL IRRITATION, NAUSEA, INCOORDINATION, DRUNKENNESS; AND OVER 1000 PPM, UNCONSCIOUSNESS AND 
Univar USA 11/16/2005 6:57:21 AM AM PAGE 3/010 Fax Server 

DEATH. A SINGLE BRIEF (MINUTES) INHALATION EXPOSURE TO LEVELS 

ABOVE 6000 PPM PERCHLOROETBYLENE MAY BE IMMEDIATELY FATAL. 

BASED ON STRUCTURAL ANALOGY AND/OR EQUIVOCAL DATA IN ANIMALS, 

EXCESSIVE EXPOSURE MAY POTENTIALLY INCREASE SENSITIVITY TO 

EPINEPHRINE AND INCREASE MYOCARDIAL IRRITABILITY (IRREGULAR 

HEARTBEATS). ALCOHOL CONSUMED BEFORE OR AFTER EXPOSURE MAY 

INCREASE ADVERSE EFFECTS. 

SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: SIGNS AND SYMPTOMS OF 

EXCESSIVE EXPOSURE MAY BE CENTRAL NERVOUS SYSTEM EFFECTS AND 

ANESTHETIC OR NARCOTIC EFFECTS. OBSERVATIONS IN ANIMALS INCLUDE 

LIVER AND KIDNEY EFFECTS. 

CANCER INFORMATION: FOR HAZARD COMMUNICATION PURPOSES UNDER OSHA 

STANDARD 29 CFR P~ 1910.1200, THIS CHEMICAL IS LISTED AS A 

POTENTIAL CARCINOGEN BY IARe AND NTP. PERCBLOROETBYLENE HAS 

BEEN SHOWN TO INCREASE THE INCIDENCE OF TUMORS IN CE~AIN 

STRAINS OF MICE AND RATS. OTHER LONG-TERM INHALATION STUDIES 

IN RATS FAILED TO SHOW TUMORIGENIC RESPONSE. HUMAN DATA ARE 

LIMITED AND HAVE NOT ESTABLISHED AN ASSOCIATION BETWEEN 

PERCHLOROETBYLENE EXPOSURE AND CANCER. PERCHLOROETBYLENE 

IS NOT BELIEVED TO POSE A MEASURABLE CARCINOGENIC RISK TO 

MAN WHEN HANDLED AS RECOMMENDED. 

TERATOLOGY (BI~H DEFECTS): BI~H DEFECTS ARE UNLIKELY. 

EXPOSURES HAVING NO EFFECT ON THE MOTHER SHOULD HAVE NO EFFECT 

ON THE FETUS. DID NOT CAUSE BI~H DEFECTS IN ANIMALS i OTHER 

EFFECTS WERE SEEN IN THE FETUS ONLY AT DOSES WHICH CAUSED TOXIC 

EFFECTS TO THE MOTHER. 

REPRODUCTIVE EFFECTS: IN LABORATORY ANIMAL STUDIES, EFFECTS ON 

REPRODUCTION HAVE BEEN SEEN ONLY AT DOSES THAT PRODUCED 

SIGNIFICANT TOXICITY TO THE PARENT ANIMALS. IN ANIMAL STUDIES, 

BAS BEEN SHOWN NOT TO INTERFERE WITH FERTILITY. 

4. FIRST AID 

EYE: FLUSH EYES ~ITH PLENTY OF WATER. 

SKIN: WASH OFF IN FLOWING WATER OR SHOWER. 

INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR 

TRANSPO~ TO EMERGENCY FACILITY IMMEDIATELY. 

INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE 

~IFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN 

SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. CALL A PHYSICIAN 

OR TRANSPO~ TO A MEDICAL FACILITY. 

NOTE TO PBYSICIAN: BECAUSE RAPID ABSORPTION MAY OCCUR THROUGH 

LUNGS IF ASPIRATED AND CAUSE SYSTEMIC EFFECTS, THE DECISION OF 

WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MADE BY A 

PHYSICIAN. IF LAVAGE IS PERFORMED, SUGGEST ENDOTRACHEAL AND/OR 

ESOPHAGEAL CONTROL. DANGER FROM LUNG ASPIRATION MUST BE 

WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH. 

IF BURN IS PRESENT, TREAT AS ANY THERMAL BURN, AFTER 

DECONTAMINATION. EXPOSURE MAY INCREASE "MYOCARDIAL 

IRRITABILITY" • DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS UNLESS 

ABSOLUTELY NECESSARY. NO SPECIFIC ANTIDOTE. SUPPO~IVE CARE. 

TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO 

REACTIONS OF THE PATIENT. 

5. FIRE FIGHTING MEASURES 

FLAMMABLE PROPE~IES 

FLASH POINT: NONE 
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METHOD USED: TCC, TOC, COC 

AUTOIGNITION TEMPERATURE: NONE AVAILABLE. 

FLAMMABLE LIMITS 

LFL: NONE. 

OFL: NONE. 

BAZARDOUS COMBUSTION PRODUCTS: HAZARDOUS COMBUSTION PRODUCTS MAY 

INCLUDE AND ARE NOT LIMITED TO HYDROGEN CHLORIDE. HAZARDOUS 

COMBUSTION PRODUCTS MAY INCLUDE TRACE AMOUNTS OF PHOSGENE, 

CHLORINE. 

OTHER FLAMMABILITY INFORMATION: THIS MATERIAL DOES NOT BURN. 

CONTAINER MAY VENT AND/OR RUPTURE DUE TO FIRE. VAPORS ARE 

HEAVIER THAN AIR AND MAY TRAVEL A LONG DISTANCE AND ACCUMULATE 

IN LOW LYING ARES. VIOLENT STEAM GENERATION OR ERUPTION MAY 

OCCUR UPON APPLICATION OF DIRECT WATER STREAM. 

EXTINGUISHING MEDIA: THIS MATERIAL DOES NOT BURN. IF EXPOSED 

TO FIRE FROM ANOTHER SOURCE, USE SUITABLE EXTINGUISHING AGENT 

FOR THAT FIRE. 

MEDIA TO BE AVOIDED: DO NOT USE DIRECT WATER STREAM. 

FIRE FIGHTING INSTRUCTIONS: KEEP PEOPLE AWAY. ISOLATE FIRE 

AREA AND DENY UNNECESSARY ENTRY. CONTAIN FIRE RUN-OFF IF 

POSSIBLE. FIRE WATER RUN-OFF, IF NOT CONTAINED MAY CAUSE 

ENVIRONMENTAL DAMAGE. DO NOT USE DIRECT WATER STREAM. THIS 

MATERIAL DOES NOT BURN. FIGHT FIRE FOR OTHER MATERIAL THAT IS 

BURNING. 

PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: WEAR POSITIVE-PRESSURE 

SELF-CONTAINED BREATHING APPARATUS (SCBA) AND PROTECTIVE FIRE 

FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT, PANTS, 

BOOTS, AND GLOVES. IF PROTECTION EQUIPMENT IS NOT AVAILABLE 

OR NOT USED, FIGHT FIRE FROM A PROTECTED LOCATION OR SAFE 

DISTANCE. FOR PROTECTION EQUIPMENT IN POST-FIRE OR NON-FIRE 

CLEAN UP SITUATIONS, REFER TO THE RELEVANT SECTIONS. 

6. ACCIDENTAL RELEASE MEASURES (SEE SECTION 15 FOR REGULATORY 

INFORMATION) 

PROTECT PEOPLE: CLEAR ALL PERSONNEL FROM AREA. DO NOT BREATHE 

VAPORS. VENTILATE AREA OF LEAK OR SPILL. WEAR PROTECTIVE 

EQUIPMENT INCLUDING POSITIVE PRESSURE SELF CONTAINED OR AIR 

SUPPLIED BREATHING APPARATUS. FOLLOW CONFINED SPACE ENTRY 

PROCEDURES: ASTM D-4276 AND OSHA (29 CFR 1910.146). 

PROTECT ENVIRONMENT: CONTAIN LIQUID TO PREVENT CONTAMINATION OF 

SOIL, SURFACE WATER OR GROUND WATER. MATERIAL IS HEAVIER THAN 

WATER AND HAS LIMITED WATER SOLUBILITY. IT WILL COLLECT ON THE 

LOWEST SURFACE. 

CLEANUP: FOR LARGE SPILLS: CONTAIN LIQUID; TRANSFER TO PROPERLY 

LABELED CLOSED METAL CONTAINERS. FOR SMALL SPILLS: MOP OR SOAR 

UP IMMEDIATELY. PLACE IN PROPERLY LABELED METAL CONTAINERS. 

7. HANDLING AND STORAGE 

HANDLING: TO AVOID UNCONTROLLED EMISSIONS VENT VAPOR FROM 

CONTAINER TO STORAGE TANK. DO NOT EAT, DRINK, OR SMOKE IN 

WORKING AREA. REFER TO EXPOSURE CONTROLS/PERSONAL PROTECTION, 

SECTION 8, OF THE MSDS. CONTAINERS, EVEN THOSE THAT HAVE BEEN 

EMPTIED, CAN CONTAIN VAPORS. DO NOT CUT, DRILL, GRIND, WELD, OR 

PERFORM SIMILAR OPERATIONS ON OR NEAR EMPTY CONTAINERS. VAPORS 

. . 
UI11 Vl:U· U~A 1111~/~OO~ 6:57:21 AM AM PAGE 5/010 Fax Server 

OF THIS PRODUCT ARB HEAVIER THAN AIR AND WILL COLLECT IN LOW 

AREAS SUCH AS PITS, DEGREASERS, STORAGE TANKS, AND OTHER 

CONFINED AREAS. DO NOT ENTER THESE AREAS WHERE VAPORS OF THIS 

PRODUCT ARB SUSPECTED UNLESS SPECIAL BREATHING APPARATUS IS USED 

AND AN OBSERVER IS PRESENT FOR ASSISTANCE. 

STORAGE: KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. FOR 

MORE STORAGE AND HANDLING INFORMATION REFER TO BULLETIN 

1#100-06170. STORE IN A DRY PLACE. DO NOT STORE IN ALUMINUM, 

ZINC, ALUMINUM ALLOYS AND PLASTICS. PRODUCT SHOULD NOT BE 

PACKAGED IN ALUMINUM AEROSOL CANS OR WITH FINELY DIVIDED 

ALUMINUM OR ITS ALLOYS IN AN AEROSOL CAN. PRODUCT IS DENSER 

THAN WATER. DESIGN STORAGE CONTAINERS APPROPRIATELY. 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

ENGINEERING CONTROLS: PROVIDE GENERAL AND/OR LOCAL EXHAUST 

VENTILATION TO CONTROL AIRBORNE LEVELS BELOW THE EXPOSURE 

GUIDELINES. LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR 

VENTILATION. 

PERSONAL PROTECTIVE EQUIPMENT 

EYE/FACE PROTECTION: USE SAFETY GLASSES. IF VAPOR EXPOSURE 

CAUSES EYE DISCOMFO~, USE A FULL-FACE RESPIRATOR. 

SKIN PROTECTION: USE PROTECTIVE CLOTHING IMPERVIOUS TO THIS 

MATERIAL. SELECTION OF SPECIFIC ITEMS SUCH AS FACESHIELD, 

GLOVES, BOOTS, APRON, OR FULL BODY SUIT WILL DEPEND ON 

OPERATION. 

RESPIRATORY PROTECTION: ATMOSPHERIC LEVELS SHOULD BE MAINTAINED 

BELOW THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS 

REQUIRED, USE AN APPROVED AIR-PURIFYING OR POSITIVE-PRESSURE 

SUPPLIED-AIR RESPIRATOR DEPENDING ON THE POTENTIAL AIRBORNE 

CONCENTRATION. FOR EMERGENCY AND OTHER CONDITIONS WHERE THE 

EXPOSURE GUIDELINE MAY BE GREATLY EXCEEDED, USE AN APPROVED 

POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS OR 

POSITIVE-PRESSURE AIRLINE WITH AUXILIARY SELF-CONTAINED AIR 

SUPPLY. IN CONFINED OR POORLY VENTILATED AREAS, USE AN 

APPROVED POSITIVE-PRESSURE SUPPLIED-AIR RESPIRATOR. 

EXPOSURE GUIDELINE (S) : PERCHLOROETHYLENE (TETRACHOROETHYLENE): 

ACGIH TLV IS 25 PPM TWA, 100 PPM STEL, A3. OSHA PEL IS 25 PPM. 

PELS ARB IN ACCORD WITH THOSE RECOMMENDED BY OSHA, AS IN THE 

1989 REVISION OF PELS. 

9. PHYSICAL AND CHEMICAL PROPE~IES 

APPEARANCE: COLORLESS LIQUID. 

ODOR: IRRITATING ODOR 

VAPOR PRESSURE: 13 MMBG @ 20C 

VAPOR DENSITY: 5.76 

BOILING POINT: 250F (121.1C) 

SOLUBILITY IN WATER: 0.015 G/100G 25C 

SPECIFIC GRAVITY: 1.619 @ 25/25C 

10. STABILITY AND REACTIVITY 

CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS. 

SEE STORAGE SECTION. 

CONDITIONS TO AVOID: AVOID DIRECT SUNLIGHT OR ULTRAVIOLET 

SOURCES. AVOID OPEN FLAMES, WELDING ARCS, OR OTHER HIGH 

TEMPERATURE SOURCES WHICH INDUCE THERMAL DECOMPOSITION. HIGH 

ENERGY SOURCES SUCD AS WELDING ARCS CAN CAUSE DEGRADATION 
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GENERATING CHLORINE, HYDROGEN CHLORIDE AND POSSIBLE PHOSGENE, 

AND SHOULD BE AVOIDED. 

INCOMPATIBILITY WITH OTHER MATERIALS: AVOID CONTACT WITH METALS 

SUCH AS: ALUMINUM POWDERS, MAGNESIUM POWDERS, POTASSIUM, 

SODIUM, AND ZINC POWDER. AVOID UNINTENDED CONTACT WITH AMlNES. 

AVOID CONTACT WITH STRONG BASED AND STRONG OXIDIZERS. AVOID 

PROLONGED CONTACT WITH OR STORAGE IN ALUMINUM OR ITS ALLOYS. 

HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS DECOMPOSITION 

PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO HYDROGEN CHLORIDE 

AND TRACE AMOUNTS OF CHLORINE AND PHOSGENE. 

RAZAlIDOUS POLYMERIZATION: WILL NOT OCCUR. 

11. TOXICOLOGICAL INFORMATION (SEE SECTION 3 FOR POTENTIAL HEALTH 

EFFECTS. FOR DETAILED TOXICOLOGICAL DATA, WRITE OR CALL THE 

ADDRESS OR NON-EMERGENCY NUMBER SHOWN IN SECTION 1) 

SKIN: THE LD50 FOR SKIN ABSORPTION IN RABBITS IS > 10 G/KG. 

INGESTION: THE ORAL LDSO FOR RATS IS > 5000 MG/KG. 

MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): IN VITRO MUTAGENICITY 

STUDIES WERE NEGATIVE. ANIMAL MUTAGENICITY STUDIES WERE 

NEGATIVE. 

12. ECOLOGICAL INFORMATION (FOR DETAILED ECOLOGICAL DATA, WRITE OR CALL 

THE ADDRESS OR NON-EMERGENCY NUMBER SHOWN IN SECTION 1) 

ENVIRONMENTAL FATE 

MOVEMENT , PARTITIONING: BIOCONCENTRATION POTENTIAL IS LOW (BCF 

LESS THAN 100 OR LOG POW LESS THAN 3). BIOCONCENTRATION 

FACTOR (BCF) IS 49 IN THE BLUEGILL. BIOCONCENTRATION FACTOR 

(BCF) IS 38. 9 IN THE TROUT. LOG OCTANOL/WATER PARTITION 

COEFFICIENT (LOG POW) IS 3.4. POTENTIAL FOR MOBILITY IN SOIL 

IS MEDIUM (KOC BETWEEN 150 AND SOO). LOG SOIL ORGANIC CARBON 

PARTITION COEFFICIENT (LOG KOC) IS ESTIMATED TO BE 2.1-3.2. 

HENRY'S LAW CONSTANT (H) IS 1.49E-02 ATM-M3/MOL. LOG 

AIR/WATER PARTITION COEFFICIENT (LOG KAW) IS ESTIMATED TO BE 

-0.30 TP 0.37. 

DEGRADATION' PERSISTENCE: BIODEGRADATION UNDER AEROBIC 

CONDITIONS IS BELOW DETECTABLE LIMITS. THEORETICAL OXYGEN 

DEMAND (THOD) IS CALCULATED TO BE 0.19 PIP. BIODEGRADATION 

MAY OCCUR UNDER ANAEROBIC CONDITIONS (IN THE ABSENCE OF 

OXYGEN). DEGRADATION IS EXPECTED IN THE ATMOSPHERIC 

ENVIRONMENT WITHIN DAYS TO WEEKS. BIODEGRADATION RATE MAY 

INCREASE IN SOIL AND/OR WATER WITH ACCLIMATION. 

ECOTOXICOLOGY: MATERIAL IS MODERATELY TOXIC TO AQUATIC ORGANISMS 

ON AN ACUTE BASIS (LCSO BETWEEN 1 AND 10 MG/L IN MOST SENSITIVE 

SPECIES). ACUTE LCSO FOR JAPANESE MEDAKA OR RICE FISH 

(ORYZIAS LATIPES) IS 1. 6 MG/L. ACUTE LCSO FOR WATER FLEA 

(DAPHNIA MAGNA) IS 3.2-123 MG/L. ACUTE LCSO FOR RAINBOW TROUT 

(ONCORHYNCHUS MYKISS) IS 4.8-5.8 MG/L. ACUTE LC50 FOR 

SHEEPSHEAD MINNOW (CYPRINODON VAEaEGATUS) IS 8.0-52.2 MG/L. 

ACUTE LC50 FOR AMERICAN FLAGFISH JORDENELLA FLORIDAE IS 8.4-

24 MG/L. ACUTE LCSO FOR BLUEGILL (LEPOMIS MACROCHIROS) IS 

13 MG/L. ACUTE LCSO FOR FATHEAD MINNOW (PIMEPBALES PROMELAS) 

IS 13.4-23-8 MG/L. MAXIMUM ACCEPTABLE TOXICANT CONCENTRATION 

(MATC) IS 3.1 MG/L IN AMERICAN FLAGFISH. 
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, . 

13. DISPOSAL CONSIDERATIONS (SEE SECTION 15 FOR REGULATORY INFORMATION) 

DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY 

BODY OF WATER. ALL DISPOSAL METHODS MOST BE IN COMPLIANCE WITH 

ALL FEDERAL, STATE/PROVINCIAL AND LOCAL LAWS AND REGULATIONS. 

REGULATIONS MAY VARY IN DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR. THE VENDOR 

BAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING 

PROCESSES OF P~IES HANDLING OR USING THIS MATERIAL .. THE 

INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS 

SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2 

(COMPOSITION/INFORMATION ON INGREDIENTS). 

FOR UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS INCLUDE SENDING TO A LICENSED, PERMITTED RECYCLER, RECLAlMER, 

INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE. 

14. TRANSPORT INFORMATION 

DEPARTMENT OF TRANSPORTATION (D.O.T.): FOR D.O.T. REGULATORY 

INFORMATION, IF REQUIRED, CONSULT TRANSPORTATION REGULATIONS, 

PRODUCT SHIPPING PAPERS OR CONTACT YOUR VENDOR REPRESENTATIVE. 

CANADIAN TDG INFORMATION: FOR TOG REGULATORY INFORMATION, IF 

REQUIRED, CONSULT TRANSPO~TION REGULATIONS, PRODUCT SHIPPING 

PAPERS OR CONTACT YOUR VENDOR REPRESENTATIVE. 

15. REGULATORY INFORMATION (NOT MEANT TO BE ALL-INCLUSIVE--SELECTED 

REGULATIONS REPRESENTED) 

NOTICE: THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH AND 

BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. HOWEVER, 

NO WARRANTY, EXPRESS OR IMPLIED IS GIVEN. REGULATORY REQUIREMENTS 

ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE LO~ION TO ANOTHER; 

IT IS THE BUYER'S RESPONSIBILITY TO ENSURE THAT ITS ACTIVITIES COMPLY 

WITH FEDERAL, STATE OR PROVINCIAL, AND LOCAL LAWS. THE FOLLOWING 

SPECIFIC INFORMATION IS MADE FOR THE PURPOSE OF COMPLYING WITH 

NUMEROUS FEDERAL, STATE OR PROVINCIAL, AND LOCAL LAWS AND REGULATIONS. 

SEE OTHER SECTIONS FOR HEALTH AND SAFETY INFORMATION. 

SARA 313 INFORMATION: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES 

SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF 

THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 eFR 

PART 372: 

CHEMICAL NAME CAS NUMBER CONCENTRATION 

PERCHLOROETBYLENE 000127-18-4 99.9 

SARA HAZARD CATEGORY: THIS PRODUCT BAS BEEN REVIEWED ACCORDING TO THE 

EPA "HAZARD CATEGORIES" PROMULGATED UNDER SECTIONS 311 AND 312 OF THE 

SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND 

IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING 

CATEGORIES: 

AN IMMEDIATE HEALTH HAZARD 

A DELAYED HEALTH HAZARD 

CALIFORNIA PROPOSITION 65: THE FOLLOWING STATEMENT IS MADE IN ORDER TO 
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COMPLY WITH THE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT 

OF 1986: 

WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF 

CALIFORNIA TO CAUSE CANCER. 

TOXIC SUBSTANCES CONTROL ACT (TSCA): 

ALL INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE 

LISTED ON THE TSCA INVENTORY. 

STATE RIGHT-TO-KNOW: THE FOLLOWING PRODUCT COMPONENTS ARE CITED ON CE~IN STATE LISTS AS MENTIONED. NON-LISTED COMPONENTS MAY BE SHOWN 

IN THE COMPOSITION SECTION OF THE MSDS. 

CHEMICAL NAME CAS NUMBER LIST 

PERCHLOROETHYLENE 000127-18-49 NJl NJ2 NJ3 

PAl PA2 PA3 

NJ1=NEW JERSEY SPECIAL HEALTH HAZARD SUBSTANCE (PRESENT AT GREATER THAN 

OR EQUAL TO 0.1%). 

NJ2=NEW JERSEY ENVIRONMENTAL HAZARDOUS SUBSTANCE (PRESENT AT GREATER 

THAN OR EQUAL TO 1.0%). 

NJ3=NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN 

OR EQUAL TO 1.0%). 

PA1=PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL 

TO 1. 0%) . PA2=PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN 

OR EQUAL TO 0.01%). 

PA3=PENNSYLVANIA ENVIRONMENTAL HAZARDOUS SUBSTANCE (PRESENT AT GREATER 

THAN OR EQUAL TO 1.0%). 

OSHA HAZARD COMMUNICATION STANDARD: 

THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD 

COMMUNICATION STANDARD, 29 CFR 1910.1200. 

COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT 

(CERCLA, OR SUPERFUND) : 

THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCE(S) LISTED AS "HAZARDOUS 

SUBSTANCES" UNDER CERCLA WHICH MAY REQUIRE REPORTING OF RELEASES: 

CATEGORY: 

CHEMICAL NAME CAS' RQ % IN PRODUCT 

PERCHLOROETHYLENE 000127-18-4 100 99.9 

CANADIAN REGULATIONS 

===================== 

WBMIS INFORMATION: THE CANADIAN WORKPLACE HAZARDOUS MATERIALS 

INFORMATION SYSTEM (WBMIS) CLASSIFICATION FOR THIS PRODUCT IS: 
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D1B - POISONOUS SUBSTANCE DEFINED BY TOG REGULATIONS 

D2A - POSSIBLE, PROBABLE OR KNOWN SUMAN CARCINOGEN ACCORDING TO 

CLASSIFICATIONS BY IARe OR ACGIH 

D2B - EYE OR SKIN IRRITANT 

REFER ELSEWHERE IN THE MSDS FOR SPECIFIC WARNINGS AND 

SAFE HANDLING INFORMATION. REFER TO THE EMPLOYER'S 

WORKPLACE EDUCATION PROGRAM. 

CPR STATEMENT: THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE 

HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) 

AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. 

HAZARDOUS PRODUCTS ACT INFORMATION: THIS PRODUCT CONTAINS THE FOLLOWING 

INGREDIENTS walCH ARE CONTROLLED PRODUCTS AND/OR ON THE INGREDIENT 

DISCLOSURE LIST (CANADIAN BPA SECTION 13 AND 14): 

COMPONENTS: CAS II AMOUNT (%W /W) 

TETRACHLOROETHYLENE 000127-18-4 99.9% 

16. OTHER INFORMATION 

HAZARD RATING SYSTEM: 

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS: 

HEALTH 2 

FLAMMABILITY 0 

REACTIVITY 0 

DISPOSAL OF CONTACT WATER: 

PROCESS WATER IN CONTACT WITH SOLVENT AND/OR WATER SEPARATORS OF 

CLEANING OR DISTILLATION EQUIPMENT SHOULD BE TREATED AS HAZARDOUS 

WASTE. DO NOT DISCHARGE WATER FROM WATER SEPARATORS TO DRAIN. 

GENERAL APPLICATION GUIDELINES: 

VENDOR DOES NOT RECOMMEND THE USE OF THIS PRODUCT IN APPLICATIONS 

WHERE: 

- SOIL OR GROUND WATER CONTAMINATION IS LIKELY (DIRECT 

APPLICATIONS TO THE GROUND, SINK DRAINS, SEWERS, OR SEPTIC 

TANKS) • 

- WHERE OVER EXPOSURE IS LIKELY (SMALL ROOMS OR CONFINED SPACE, 

OR WHERE THERE WOULD BE INADEQUATE VENTILATION) . - WHERE SKIN CONTACT IS LIKELY (ADHESIVE TAPE REMOVAL FROM SKIN 

OR AS BAND CLEANER TO REMOVE OILS AND GREASES). - WHERE THERE IS DIRECT FOOD CONTACT. - WHERE VAPOR CONCENTRATIONS WOULD BE IN THE FLAMMABLE RANGE. - WHERE DISPOSAL OF WASTE WOULD POSE AN ENVIRONMENTAL OR HEALTH 

RISK. - WHERE CHEMICAL REACTIVITY POSES A DANGER (CONTACT WITH STRONG 

ALKALI, OR IN AREAS WHERE WELDING IS DONE). 

MSDS STATUS: NO REVISIONS. REVIEWED FOR CANADIAN REGULATIONS. 

-------------------------- FOR ADDITIONAL INFORMATION -------------------------- CONTACT: MSDS COORDINATOR UNIVAR USA INC. 

DURING BUSINESS HOURS, PACIFIC TIME (425)889-3400 

------------------------------------ NOTICE ------------------------------------

*********** UNIVAR USA INC ("UNIVARII) EXPRESSLY DISCLAIMS 
Univar USA 11/1~/~UU~ ~:~/:~~ ~ ~ ~~u~ ~V/V~V 

ALL EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A 

PARXICULAR PURPOSE, WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN, 

AND SHALL UNDER NO CIRCUMSTANCES BE LIABLE FOR INCIDENTAL OR CONSEQUENTIAL 

DAMAGES.** 

DO NOT USE INGREDIENT INFORMATION AND/OR INGREDIENT PERCENTAGES IN THIS MSDS 

AS A PRODUCT SPECIFICATION. FOR PRODUCT SPECIFICATION INFORMATION REFER TO A 

PRODUCT SPECIFICATION SHEET AND/OR A CE~IFI~E OF ANALYSIS. THESE CAN BE 

OBTAINED FROM YOUR LOCAL UNlVAR SALES OFFICE. 

ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE 

MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMATION IS 

BELIEVED TO BE ACCURATE, UNIVAR MARES NO REPRESENTATIONS AS TO ITS ACCURACY OR 

SUFFICIENCY. CONDITIONS OF USE ARE BEYOND UNIVARS CONTROL AND THEREFORE USERS 

ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS TO 

DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR P~ICULAR PURPOSES AND THEY 

ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF THE PRODUCT, OR FROM 

THE PUBLICATION OR USE OF, OR RELIANCE UPON , INFORMATION CONTAINED HEREIN. 

THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT 

RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER 

PROCESS. 

* * * END 0 F M S D S * * * 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 1 

--------------------------------------------------------------------------------------------------

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

CAS #: 000143339 

FORMULA: Na C N 

CHEM. FAMILY: inorganic salts 

CHEMICAL NAME AND SYNONYMS: 

Sodium Cyanide; 

Cyanide of Sodium; 

Prussiate of Soda; 

MSDS 001764 DETAIL 00165 

Date: S-JAN-1999 12:01:13.63 

220# DRUM-BR 

MSDS No. 001764 Revision No./Date 02 970107 

Detail Number 00165/01 

SUPPLIERS NAME: Harcros Chemicals Inc. 

5200 Speaker Road 

Kansas City KS 66106-1095 

SUPPLIERS PHONE NUMBER : 913-321-3131 

TRANSPORTATION EMERGENCY PHONE NUMBER : 1-800-424-9300 

S.A.R.A. INFORMATION 

HAZARDS : Acute 

PHYSICAL DATA :. Pure Reactivity Solid 

SECTION I HAZARDOUS INGREDIENTS --------------------------------.------ -----------.--------------------------------------------. Ingredient 

Cas Number 

Sodium Cyanide Prussiate of Soda 

(CAS # 143-33-9 

SECTION II HEALTH HAZARDS 

POTENTIAL EFFECTS OF EXPOSURE 

EYES 

MAX 

%' w/w 

100.0 

SARA 

APPLIES 

312 313 372 

AIR CONTAMINENT LEVELS 

Y Y 

_~1~f;r~ __ I---~~~;r---I---~;~~:--I~~~~I~~~~ Y As Cyanide 

TWA/TLV 5 mg/m3 OSHA 

CEILING 5 mg/m3 ACGIH 

DESIGNATED SKIN HAZARD OSHA/ACGIH 

----------1-----------1----------1----1-----

Eye contact with product may cause irritation burns irreversible damage even death 

SKIN 

Skin contact may cause irritation burns even death Absorption thru skin may cause symptoms 

described under inhalation and ingestion. 

INHALATION 

Inhalation may cause headache dizziness nausea breathing difficulty vomiting unconsciousness 

convulsions even death 

Continued On Page 2 

.. 
Harcros Chemicals Inc 

Kansas City, Kansas 

f4ATERIAL SAFETY DATA SHEET Page 2 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

SECTION II HEALTH HAZARDS 

INGESTION 

Date: 5-JAN-1999 12:01:14.69 

220# DRUM-BR 

(CONTINUED) 

Ingestion may cause headache dizziness nausea breathing difficulty vomiting unconsciousness 

convulsions even death 

TARGET ORGANS 

OVEREXPOSURE MAY CAUSE DAMAGE TO, 

DISORDERS OF, OR ADVERSELY AFFECT THE FOLLOWING SYSTEMS, FUNCTIONS, ORGANS: blood pressure FIRST AID 

FIRST AID EYES 

FOR CYANIDE EXPOSURE: Immediately flush eyes with plenty of water, remove contaminated clothing, and keep patient quiet and warm. If symptoms of cyanide exposure occur, see first aid for skin, 

below. Call a physician. FIRST AID SKIN 

FOR CYANIDE EXPOSURE: Wash skin promptly to remove the cyanide while removing all contaminated 

clothing, including shoes. Do not delay. Skin absorption can occur from cyanide dust, solutions, 

or HCN vapor. Absorption is slower than inhalation, usually measured in m1nutes compared to 

seconds for inhalation. Patient should be watched for at least 1 to 2 hours because absorbed 

cyanide can continue to work into the bloodstream. Wash clothing before reuse and destroy contaminated shoes. Call a physician. UNCONSCIOUS BUT BREATHING: 

Break an amyl nitrite ampule 1n a cloth and hold lightly under the patient's nose for 15 seconds, 

then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 

minutes until the patient regains consciousness (usually 1-4 ampules). Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, cons1der holding the 

amyl nitrite under the nose continuously for the first ampule or more. Call a physician. NOT BREATHING: Give artificial respiration (100% oxygen), preferably with an 

oxygen resuscitator. Give amyl nitrite antidote by placing a broken ampule inside the 

resuscitator face piece, bein~ careful that the ampule does not enter the patient's mouth and 

cause choking. Give oxygen s1multaneously. Call a physician. FIRST AID INHALATION 

FOR CYANIDE EXPOSURE: Carry patient to fresh air. Lay ~atient down. Administer oxygen and amyl nitrite. Keep patient quiet and warm. Even with inhalat10n poisoning, thorou~hly check clothing and skin to assure no cyanide is present. Call a physician. Rescuers of pat1ents in an HCN 

environment should wear SCBA equipment. CONSCIOUS: For inhalation and/or 

absorption if the patient is alert, oxygen may be all that is needed. But if the patient is not 

fully conscious or shows signs of poisonin~, see below. Call a physician. UNCONSCIOUS BUT BREATHING: Break an amyl n1trite ampule in a cloth and hold lightly under the 

patient's nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, 

use a fresh ampule every 3 minutes until the patient regains consciousness (usually 1-4 ampules) . Give oxygen simultaneously to aid recovery. Where more severe poisoning has occurred, consider holdin~ the amyl nitrite under the nose continously for the first ampule or more. Call a 

physic1an. NOT BREATHING: Give artificial respiration (100% oxygen), preferably with an oxygen resuscitator. Give amrl nitrite antidote by placing a broken ampule inside the resuscitator face piece, being carefu that the ampule does not enter the patient'S mouth and cause choking. Give oxygen simultaneously. Call a physician. FIRST AID INGESTION 

FOR CYANIDE EXPOSURE: Conscious: Immediately give patient one pint of 1% sodium thiosulfate 

Continued On Page 3 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 3 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

SECTION II HEALTH HAZARDS 

Date: 5-JAN-1999 12:01:15.63 

220# DRUM-BR 

(CONTINUED) 

solution (or plain water) by mouth and induce vomiting by having patient stick finger into 

throat. Re~eat until vomit fluid is clear. Never give anything by mouth to an unconscious 

person. G1ve oxygen. Call a physician. UNCONSCIOUS BUT BREATHING: Break 

an amyl nitrite ampule in a cloth and hold lightly under the patient's nose for 15 seconds, then 

take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule every 3 minutes 

until the patient regains consciousness (usually 1-4 ampules). Give oxygen simultaneously to aid 

recovery. Where more severe poisoning has occurred, consider holding the amyl nitrite under the 

nose continuously for the first ampule or more. Call a physician. NOT 

BREATHING: Give artificial respiration (100% oxygen), ~referably with an oxygen resuscitator. 

Give amyl nitrite antidote by placing a broken ampule 1nside the resuscitator face piece, being careful that the ampule does not enter the patient's mouth and cause choking. Give oxygen simultaneously. Call a physician. OTHER INFORMATION 

NOTES TO PHYSICIAN 

MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Medical treatment is normally provided by a physician, but might be provided by a professionally trained "qualified medical person II where a need exists 

and where State and local laws permit. Specific training for handling cyanide poisoning emergencies is essential, as well as being "in practice" for giving intravenous injections. Du 

Pont trains all personnel working with cyanide to use the first aid ~rocedures, but not the 

medical treatment ~rocedure. While preparin~ for sod1um nitrite and sodium 

thiosulfate inject10ns, use amyl nitrite and oxygen as outl1ned in First Aid. When ready and if 

the patient is not responding to first aid, first inject the solution of sodium nitrite (10 mI. 

of a 3% solution) intravenously at the rate of 2.5 mL/minute, then immediately inject the sodium 

thiosulfate (50 mL of a 25% solution) at the same rate, taking care to avoid extravasation. This 

is a fairly lengthy treatment (24 minutes) since a total of 10 + 50, or 60 mL, is injected at a 

rate of 2.5 mL per minute. Consideration should be given to the size and 

condition if the patient as treatment is proceeding. The above sodium nitrite injection is about 

1/3 of a lethal dose (see below), so care should be taken to avoid excessive use. It is not 

essential that full quantities be given, just because treatment was started. Injections can be 

stopped at any point if recovery is evident, but be sure to keep track of quantities administered 

in case treatment needs to be restarted. Rela~se is abnormal if cyanide intake is not 

continuing, unless a large intake from swallow1n~ occurred. Don't overreact. 

While prompt treatment is essential where poison1ng has occurred, treatment of a lucid, conscious 

patient would rarely be necessary. The effects of cyanide ~oisoning are immediate, not delayed, and a conscious person that can communicate does not have s1gnificant cyanide poisoning. For most accidental poisoning, complete recovery occurs within 1-2 hours. If cyanide 

exposure was severe, watch patient continuously for 24-48 hours. If there is any return of sym~toms during this period, consider repeating this treatment using one half the amounts of 

sod1um nitrite and sodium thiosulfate solutions. Blood chemistry should monitored during prolonged treatment. Caution should be used to prevent overuse of medical treatment chemicals as 

the prescribed dose is about 1/3 the lethal dose for an average individual. The nitrite converts 

hemoglobin to methemoglobin which reduces the oxygen carrying capacity of the blood. This is 

done purposely as methemoglobin attracts cyanide away from the body cells, but nitrite use must 

be limited to prevent hemoglobin deficiency. Du Pont has not experienced nitrite overdose 

problems; but being alert to this is important information to medical personnel. 

Continued On Page 4 

: 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET page 4 --------------------------------------------------------------------------------------------------

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

Date: 5-JAN-1999 12:01:16.63 

220# DRUM-BR --------------------------------------------------------------------------------------------------

SECTION II HEALTH HAZARDS (CONTINUED) 

If signs of excess methemoglobinemia develop (i.e., blue skin and mucous membranes, vomiting, shock and coma), 1t methylene blue solution should be given intravenously. Administering up to a 

1 to 2 mg/kg of body weight over a period of five to ten minutes should be considered and 

repeated in one hour if necessary. NOTE: This procedure can free cyanide from 

cyanomethemoglobin. The free cyanide can again bind with cytochrome oxidase and, therefore, 

repoison the patient. If methylene blue is used, it must be used verr carefully. It is best to 

avoid overuse of nitrite so corrective action is not needed. Histor1cally, Du Pont has not had 

to use methylene blue to counter excess nitrite use. In addition, oxygen inhalation will be 

helpful. Transfusion of whole fresh blood may be considered if there has been mechanical injury with external bleeding and simultaneous cyanide exposure. When handling potential cyanide poisoning emergencies, keep in mind: 1. Cyanide acts rapidly, usually within seconds once 

it enters the bloodstream. Delayed effects would only be expected during brief periods (e.g., 

up to about 20 minutes) when (a) cyanide was absorbed into the bloodstream from the stomach 

after ingestion or (b) absorption through the skin occurred prior to skin washing, but 

entry into the blood was not complete. In treatment, therefore, treat what you see; don't 

overreact. It's rare when "preventive" use of the antidotes would be warranted. If you can 

converse normally with the patient, cyanide intake is limited and no action is called for other 

than to closely monitor the patient and keep him calm by reassurance of his condition during the 

following 20-30 minute period. 2. The half-life of cyanide in the body is estimated at 

20-90 minutes. The body routinely destroys cyanides from foods, cigarette smoke, etc. so cyanide is not a cumulative poison. In case of accidental cyanide intake, normal body action guickly begins cyanide destruction. In diagnosis and monitor1ng as mentioned in item 1, the cr1tical ~eriod is therefore short. Normally what happens in the initial few minutes after exposure will 

1ndicate the degree of poisoning. Du Pont's experience in treating cyanide poison cases is 

that first aid procedures using oxygen and amyl nitrite were effective and the only treatment 

needed in most cases. Medical treatment, using intravenous injections, was used in a few cases. 

Both procedures have been successful. For further information, see Du Pont Sodium Cyanide Storage and Handling Bulletin. 

ROUTES OF ENTRY 

eye contact skin contact skin absorption inhalation ingestion OVEREXPOSURE MAY AGGRAVATE DISORDERS OF THE 

central nervous system CARCINOGEN STATUS 

No components, present in excess of O.lt by weight are listed as carcinogens by IARC, NTP, or 

OSHA. 

EXTRA INFORMATION 

FIRST AID MEDICAL TREATMENT FOR CYANIDE EXPOSURE: Treatment for cyanide ~oisoning can be 

provided in two ways, "First Aid" and "Medical Treatment". Both require 1mmediate action to 

prevent further harm or death. First aid using oxygen and amyl nitrite is generally given by a 

layman before trained medical help arrives. Medical treatment is aggressive treatment involving intravenous injections of sodium nitrite and sodium thiosulfate, and must be administered by qualified medical personnel. Even if a doctor or nurse is present, the need for fast treatment 

dictates using first aid treatment with oxygen and amyl nitrite while medical treatment materials 

for intravenous injection are being prepared. Experience shows that first aid given ~romptly is 

usually the only treatment needed for typical accidental poisonings. Larger cyanide 1ntake 

Continued On Page 5 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 5 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

SECTION II HEALTH HAZARDS 

Date: 5-JAN-1999 12:01:17.86 

220# DRUM-BR 

(CONTINUED) 

increases the need for medical treatment. Medical treatment is given if the 

patient does not respond to first aid. It provides a large quantity of antidote including sodium 

thiosulfate to chemically destroy cyanide in the body. However, even under optimum conditions, 

amyl nitrite can be administered faster and should be used even if medical treatment follows. 

Always have on hand the materials listed below. FIRST AID AND 

MEDICAL TREATMENT KITS. Actions to be taken in case of cyanide exposure should be planned and 

practiced before beginning work with cyanides. In most cases, cyanide poisoning causes a 

deceptively healthy pink to red skin color; however; if a physical injury or lack of oxygen is 

involved, the skin color may be bluish. Reddening of the eyes and pupil dilation are also 

symptoms cyanide ~oisoning. Workers should be trained to provide immediate first aid using 

oxygen and amyl n1trite resuscitators. In case of cyanide poisoning, start first 

a1d treatment immediately, then call a physician. FIRST AID SUPPLIES FOR CYANIDE 

EXPOSURE: Adequate first aid supplies for cyanide poisoning should be conveniently placed throughout cyanide areas and should be immediately accessible at all times. They should be 

routinely inspected (typically daily) by people who would use them in an emergency. The total 

number of each item listed below should be adequate to handle the largest number of exposure 

cases reasonably anticipated, taking into account that some supplies may be wasted, destroyed, or 

inaccessible in the emergency. 1. Oxygen Resuscitators-The Flynn Series III Model 

by O-Two Systems (800-387-3405) has performed well in Du Pont use. It is lightweight, rugged, and easy to use. 2. Amyl Nitrite Ampules (antidote)-One box of one dozen ampules 

per station is usually satisfactorr' Locate stations throughout the cyanide area. 

CAUTION: Amyl Nitrite is not stab e and must be replaced every 1 to 2 years. Store in the 

original dated box, away from heat. A common Du Pont practice is to use the resuscitator as the 

storage point for the amyl nitrite ampUles. Avoid storage on vehicles where temperatures can 

reach 140-150 deg F or more. 3. A set of cyanide first aid instructions should be 

located at each amyl nitrite storage location. Workers should be fully trained since in a real 

emergency there will be insufficient time to "read the book". 4. Two 1-pint bottles 

of 1% sodium thiosulfate solution for use in case of cyanide ingestion or plain water can be 

used. AMYL NITRITE NOTES FOR CYANIDE EXPOSURE: 1. Amyl nitrite is highly 

volatile and flammable, do not smoke or use around source of ignition. 2. If treating 

patient in a windy or drafty area, provide something-a rag, shirt, wall, drum, cupped hand, 

etc,-to prevent the amyl nitrite vapors from being blown away. Keep the ampule upwind from the 

nose. The objective is to get amyl nitrite into the patient's lungs. 3. Rescuers should 

avoid amyl nitrite inhalation so they won't become dizzy and lose co~etence. 4. Lay the 

patient down for treatment to mainta1n a good blood supply to the pat1ent's head. Since amyl nitrite dilates the blood vessels and lowers blood pressure, lying down will help prevent 

unconsciousness. MEDICAL TREATMENT KITS FOR CYANIDE EXPOSURE: Medical Treatment Kits for 

cyanide poisoning should be conveniently located for easy access by medical ~eople. Materials for 

intravenous injection are intended for use only by a physician or fully qual1fied medical 

personnel. The location of kits should be carefully planned as part of the emergency ~replan. 

Suggested locations for kits include: - in or near the cyanide area - plant med1cal station - entrance guard house - local hospital - doctor's office and residence CAUTION: 

Do not store amyl nitrite or Medical Treatment Kits on vehicles as heat build-up may ruin the 

amyl nitrite. Kits and amyl nitrite should be accessible but secured against tampering. They should be inspected regularly and the amyl nitrite ampules replaced every 1-2 years. 

Continued On Page 6 

: 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 6 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

Date: s-JAN-1999 12:01:19.11 

220# DRUM-BR 

SECTION II HEALTH HAZARDS (CONTINUED) 

Medical Treatment Kits should contain the following: 1. One box containing one dozen amyl nitrite ampules. 2. Two sterile ampules of sodium nitrite solution (10 mL of a 3% 

solution in each). 3. Two sterile am~ules of sodium thiosulfate solution (SO mL of a 2st 

solution in each) . 4. One 10 ml ster~le syringe. One SO mL sterile styringe. Two 

sterile intravenous needles. One tourni9Uet. s. One stomach tube. 6. One dozen 

gauze pads. 7. A set of cyanide ~nstructions on first aid and medical treatment. 

NOTE: "Amyl Nitrite" and "Medical Treatment Kits" can be purchased through local pharmacies with 

a physician's ~rescription. As a help, you can inform the pharmacist that Eli Lilly and Co. 

produces the k~t. 

SECTION III SPECIAL PROTECTION 

PROTECTIVE EQUIPMENT PROTECTIVE EQUIPMENT EYES 

chemical goggles face shield 

PROTECTIVE EQUIPMENT SKIN 

impervious gloves complete body covering PROTECTIVE EQUIPMENT INHALATION 

If exposure limits are exceeded, or if exposure may occur, use a NIOSH/MSHA respirator approved for your conditions of exposure. Refer to the most recent NIOSH publications concerning chemical 

hazards, or consult your safety equipment supplier. Respiratory protection programs must be in com~liance with OSHA requirements in 29 CFR 1910.134. For emergencies, a NIOSH/MSHA approved pos~tive pressure breathing apparatus should be readily available. 

VENTILATION REQUIRED: 

Adequate ventilation is required to minimize exposure or to maintain exposure levels below 

OSHA/ACGIH requirements. Local mechanical ventilation may be required. ADDITIONAL PROTECTIVE MEASURES 

Safety shower, eye wash fountain, and washing facilities should be readily available. In case 

of emergency or when dusting, misting, or splashing may occur, wear respiratory protection, eye protection, gloves, helmet, boots, and complete protective body covering. 

SECTION IV FIRE & EXPLOSION HAZARD DATA 

Flash Point (METHOD): > OR ~ N/A 

Flammable Limits (t Volume in Air) 

HMIS Info Health 3 

Fire 0 

React 1 

Special X 

EXTINGUISHING MEDIA 

UPPER: N/D Lower: N/D 

media appropriate for surrounding fire Do not use carbon dioxide. 

FIRE FIGHTING PROCEDURES 

Prevent human exposure to fire, fumes, smoke, and products of combustion. Evacuate non 

Continued On Page 7 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 7 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

SECTION IV FIRE & EXPLOSION HAZARD DATA 

Date: 5-JAN-1999 12:01:20.30 

220# DRUM-BR 

(CONTINUED) 

essential personnel. Firefighters should wear full face, self contained breathing apparatus and 

impervious protective clothing. UNUSUAL FIRE & EXPLOSION HAZARDS 

Toxic fumes may be released. Cyanides dissolved in water; therefore, cyanide solution runoff 

may occur if containers are opened or burned. Runoff should be contained to avoid environmental 

or safety problems. Contained cyanide solution can be detoxified with hypochlorite. 

SECTION V PHYSICAL DATA 

Boiling Point: > OR = 2725 deg. F 

Freezing Point: 1047 deg. F 

Specific Gravity (H(2)O=1): > OR = 1.0600 @ 

Vapor Pressure (MM HG.): NID 

Vapor Density (AIR=l) : NID 

Evaporation Rate ( NA =1): NID 

Solubility in Water: 37% 

Percent Volatile by Volume: > OR 999.00 

pH: aqueous approx. 11.300 to 11.700 

Appearance: SOLID - POWDER, CRYSTAL, FLAKE, GRANULE 

TABLET, PRILL, BRIQUETTE, ETC. 

Odor : 

SHARP 

SECTION VI REACTIVITY DATA 

STABILITY 

68 deg. F 

Stable when stored in container under proper conditions. 

INCOMPATABILITY 

inorganic acids organic acids bleaching agents (oxidizers) Water or weak alkaline solution 

can produce dangerous amounts of poisonous hydrogen cyanide in confined areas. Avoid contact 

with bleaching agents and oxidizers which include chlorine, oxygen, permanganates, perchlorates, percarbonates, peroxides, chromates, hypochlorites, nitric acid, and sulfuric acid. 

HAZARDOUS DECOMPOSITION PRODUCTS 

hydrogen cyanide Moisture will cause slow decomposition, releasing poisonous hydrogen cyanide and ammonia gas. HAZARDOUS POLYMERIZATION 

Will not occur 

SECTION VII SPILL AND LEAK PROCEDURES 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: 

FOR CYANIDE SPILLS: Sweep up and shovel into a covered container or plastic bag, pending 

Continued On Page 8 

.~ 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 8 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

SECTION VII SPILL AND LEAK PROCEDURES 

Date: 5-JAN-1999 12:01:21.51 

220# DRUM-BR 

(CONTINUED) 

transfer, to secure the spill. Cover and keep spillage dry. Flush spill area with dilute 

solution of sodium hypochlorite or calcium hypochlorite to destroy the cyanide. Comply with 

Federal, State, and local regulations on reporting releases. The EPA Reportable Quant1ty is 10 

lb. 

DISPOSAL METHOD 

FOR CYANIDE DISPOSAL: This material may be a RCRA Hazardous Waste. Do not flush cyanide into 

sewers which may contain an acid. Detoxify with sodium hypochlorite, hydrogen peroxide, or 

calcium hypochlorite. Comply with Federal, state, and local regulations on disposal methods used 

to achieve the constituent based treatment standard, if permitted; or transfer to a licnesed 

disposal contractor. 

SECTION VIII 

Proper Shipping Name: 

Hazard Class: 

Label Requirements: Reportable Quantity: 

SODIUM CYANIDE 

6.1, UN1689, PGI 

POISON 

All shipments are reportable 

SECTION IX ADDITIONAL INFORMATION 

LABEL SIGNAL WORD 

DANGER POISON 

PRECAUTIONS 

Wear protective equipment when handling. Use only with adequate ventilation. Wash thoroughly after handling. Do Not breathe dust. Do Not breathe vapor or mist. Do Not breathe gas. Do Not get in eyes, on skin, or clothing. Do not swallow. 

HANDLING 

For industrial use only. ATTENTION: This container hazardous when emptied. Since emptied container contains product residues (vapor or liquid), all labeled hazard precautions must be 

observed. 

STORAGE 

Keep container closed when not in use. Store in a cool dry place. Store in accordance with 

NFPA requirements. Keep out of reach of children. 

Continued On Page 9 
Harcros Chemicals Inc 

Kansas City, Kansas 

MATERIAL SAFETY DATA SHEET Page 9 

PRODUCT NAME: SODIUM CYANIDE 

PRODUCT CODE: 12887 

NAME: GENE TURNER 

< = LESS THAN > = MORE THAN 

220# DRUM-BR 

N/A = NOT APPLICABLE 

N/D = NOT DETERMINED 

N/E = NOT ESTABLISHED 

Date: 5-JAN-1999 12:01:22.72 

DATE ISSUED: 940104 

DATE REVISED: 970107 

UNK = UNKNOWN 

The information provided in this Material Safety data sheet has been obtained from sources 

believed to be reliable. Harcros Chemicals Inc provides no warranties, either expressed or 

implied and assumes no res~onsibility for the accuracy or completeness of the data contained 

herein. This information 1S offered for your information, consideration , and investigation. You should satisfy yourself that you have all current data relevant to your particular use. 

Harcros Chemicals Inc knows of no medical condition, other than those noted on this material 

safety data sheet, which are generally recognized as being aggravated by exposure to this product. 

'. 

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