# The North Dakota Petroleum Council Study on

Bakken Crude Properties

Bakken Crude Characterization Task Force

Prepared for the

By

Suite 2920, LB 38

2100 Ross Avenue

Dallas, Texas 75201

www.turnermason.com

August 4 , 2014 John R. Auers, P.E.

Ryan M . Couture

Dennis L. Sutton

### Table of Contents

Executive Summary

................................ ................................ ................................ ................................ ....... 1

Quality Characterization

................................ ................................ ................................ ........................... 2

Operating Conditions/Impact on Bakken Quality

................................ ................................ ..................... 7

Conclusions and Recommended Action Steps

................................ ................................ .......................... 9

Introduction

................................ ................................ ................................ ................................ ................ 1 1

Test R esults/Analys e s

................................ ................................ ................................ ................................ . 1 4

API Gravity

................................ ................................ ................................ ................................ .............. 1 5

D86 IBP

................................ ................................ ................................ ................................ .................... 1 6

Vapor Pressure

................................ ................................ ................................ ................................ ........ 1 6

Flash Point

................................ ................................ ................................ ................................ ............... 1 7

Light Ends

................................ ................................ ................................ ................................ ................ 1 7

Simulated Distillation

................................ ................................ ................................ .............................. 1 9

Sample Consistency

................................ ................................ ................................ ................................ 20

Sample Methodology Comparison: Floating Piston Cylinder (FPC) versus Standard Glass Bottle

......... 2 1

Interlaboratory (Round

- Robin) Testing

................................ ................................ ................................ ... 2 2

D86 Variation

................................ ................................ ................................ ................................ .......... 2 3

Rail Testing

................................ ................................ ................................ ................................ .............. 2 5

Member Contributed Data

................................ ................................ ................................ ..................... 2 6

AFPM Report Comparison

................................ ................................ ................................ .......................... 2 7

The Pipeline and Hazardous Materials Safety Administration (PHMSA) Report Comparison

................... 30

Operating Conditions

................................ ................................ ................................ ................................ .. 32

Overview of Sampling, Analytical Methods and Quality Control/Quality Assurance

................................ . 3 8

Sampling

................................ ................................ ................................ ................................ .................. 3 8

Analytical Methods and Quality Control/Quality Assurance

................................ ................................ .. 3 9Figures

Figure 1: Rail Sample Locations, With Average Sample Results

................................ ................................ . 1 3

Figure 2: Well Sample Locations, With Average Sample Results

................................ ................................ 1 4

Figure 3: API Distribution; Total, Rail, Well

................................ ................................ ................................ . 1 5

Figure 4: API Gravity vs. Measured Vapor Pressure ( V PCR 4 )

................................ ................................ ...... 1 5

Figure 5: D86 IBP Distribution; Total, Rail, Well

................................ ................................ ......................... 1 6

Figure 6: Vapor Pressure Distribution; Total, Rail, Well

................................ ................................ ............. 1 7

Figure 7: C2

- C4 Distribution: Total, Rail, Well

................................ ................................ ............................. 1 8

Figure 8: Light Ends (C2

- C4s) Concentration vs. Vapor Pressure

................................ ................................ 1 8

Figure 9: Bakken Crude Distillation Curve

................................ ................................ ................................ ... 1 9

Figure 10: Simple Distillation Apparatus

................................ ................................ ................................ ..... 2 4

Figure 11: Seasonality Data Collected by Member Company

................................ ................................ ..... 2 7

Figure 12: Horizontal Three Phase (Gas/Liquid/Water) Separator Diagram

................................ .............. 3 3

Figure 13: Vertical Treater Diagram

................................ ................................ ................................ ............ 3 4

Figure 14: Vapor Pressure versus Operating Temperature

................................ ................................ ........ 3 6

Figure 15: Ethane Liquid Vol. % versus Operating Temperature

................................ ................................ 3 7

Figure 16: Pr opane Liquid Vol. % versus Operating Temperature

................................ .............................. 3 7

Figure 17: Vapor Pressure versus Well Production Rate

................................ ................................ ............ 3 8

Tables

Table 1: Comparison of Crude Properties

................................ ................................ ................................ ..... 2

Table 2: Bakken Quality Comparison, NDPC to AFPM and PHMSA

................................ .............................. 3

Table 3: AFPM Bakken Report, Crude Quality Comparison Table

................................ ................................ 4

Table 4: NDPC Bakken Crude Sampling Data S ummary

................................ ................................ ................ 7

Table 5: BKN Field Operations Recommended Best Pr a ctices

................................ ................................ ...... 9

Table 6 : Distillation Data; Well, Rail, Total

................................ ................................ ................................ .. 20

Table 7 : Quality Comparison

– Well vs. Rail Te st Results

................................ ................................ ........... 2 1

Table 8 : Round

- Robin API and Vapor Pressure

................................ ................................ ........................... 2 2

Table 9 : Round

- Robin D86 IBP

................................ ................................ ................................ .................... 2 3

Table 10 : D86 IBP Variability Testing

................................ ................................ ................................ .......... 2 5

Table 1 1 : Rail Car Source and Destination Testing

................................ ................................ ..................... 2 5

Table 1 2 : Member Compa ny Laboratory Comparison (Round

- Robin)

................................ ....................... 2 6

Table 1 3 : Comparison of NDPC to AFPM Study Data

................................ ................................ ................. 2 9

Table 1 4 : Comparison of NDPC to PHMSA Study Data

................................ ................................ ............... 3 1

Table 15: Average Delta (Top

- Bottom) of Tank, Rail and Overall Samples

................................ ................. 3 5Appendices

Appendix 1: Additional Figures

Appendix 2: Summary Data

Appendix 3: Sample Conditions

- Rail

Appendix 4: Sample Conditions

- Well

Appendix 5: Operational Conditions

– Well Only

Appendix 6: Lab Data

– Rail

Appendix 7: Lab Data

– Well

Appendix 8: Light Ends Data

– Rail

Appendix 9: Light Ends Data

– Well

Appe ndix 10: Simulated Distillation Data

– Rail

Appendix 11: Simulated Distillation Data

– Well

Appendix 12: Seasonality Data (Member Contributed)

Appendix 13: Interlaboratory (Round

- Robin) Data

Appendix 14: Glossary of Terms1 

### The North Dakota Petroleum Council Study on Bakken Crude Properties

Bakken Crude Characterization Task Force

Pr oject Coordinator : Turner, Mason & Company

Executive Summary

This report documents the detailed sampling and testing program recently conducted on Bakken crude

oil. This program is the most thorough and comprehensive study of crude quality from a tight oil

production basin to date.

In the past year, considerable a ttention has been focused on transportation and quality issues related to

Bakken crude oil. As a result of several high profile railcar incidents in the U.S. and Canada, various

investigations have been launched by governmental and industry groups to bett er understand the safety

aspects of moving Bakken crude by rail. Questions as to whether Bakken is materially different from

other crude oils and if the current railroad materials classification is appropriate have been raised.

Investigations are ongoing as to the cause of the railcar accidents and potential hazards to the public

associated with crude oil rail movements in general. In response to these concerns, the North Dakota

Petroleum Council (NDPC) commissioned a comprehensive sampling and testing p rogram to answer

questions regarding the chemical and physical composition of Bakken, issues regardi ng proper

classification and establish a Bakken quality baseline . This program collected samples from seven rail

terminals and 15 well sites. The crude pro ducers that provided the well samples account for over 50% of

total N orth D akota (ND) production, and the rail facilities sampled represent a similar proportion of total

ND crude

- by

- rail capacity. The sampling locations cover the entire producing region a nd include both

“old” and “new” wells, giving a good representation of any property variations that result either from

geography , production rate

, or during processing and transit. At this time , we are not aware of any

field

- level crude oil quality assess ments as extensive or as controlled as this study in the Bakken or

elsewhere.

The NDPC commissioned this program to establish Bakken crude properties (Quality Characterization)

and to understand if these properties pose transportation and handling risks un ique to Bakken

compared to other light crude oils. The results from the study will be used to help establish and

maintain a Bakken quality baseline to ensure continued crude quality and consistency. The study was

also used to evaluate the impact of fiel d

- operating conditions (ambient temperature, tank settling

times/production rates, and field equipment operating temperatures and pressures) on Bakken

qualities. The se study results, together with follow

- up efforts, will be used to establish “management

b est practices” for operating production field equipment to minimize the light ends content and vapor

pressu re of Bakken crude sent to rail

- loading facilities and to meet the proposed quality specifications.

NDPC engaged Turner, Mason & Company (TM&C), an i nternationally recognized engineering

consultancy with over 40 years of experience in the petroleum industry (including a significant

background in crude oil quality and processing)

, to serve as project coordinator. The TM&C team2 included engineers with e xtensive refining and crude characterization/evaluation experience and a

chemist with over 40 years of laboratory experience in crude oil analyses who serves as Executive

Director of the Crude Oil Quality Association and on the Board of the Canadian Crude Quality Technical

Association . Analyses of all primary samples were conducted by SGS, a global leader in testing and

inspection with over 135 years in the business. Both the local North Dakota and U.S. Gulf Coast SGS labs

participated in the sampling and testing process.

The key findings were as follows:

Quality Characterization

**•** Bakken crude is a light sweet crude oil with an API gravity generally between 40 ° and 43° and a

sulfur content <0.2 wt.%. As such, it is similar to many other light sweet crude oils produced

and transported in the United States.

o As a point of reference, the E nergy I nformation Administration (EIA) categorizes crude

oil that has an API gravity between 35 ° and 50° and less than 0.3 wt% sulfur as light

sweet. Bakken falls in the mi ddle of those ranges for both properties.

**•** Although testing for sulfur, Total Acid Number (TAN) and other corrosivity

- specific testing were

o utside the scope of this project. R esults from other test programs , as summarized below in

Table 1 , indicate that Bakken has very low sulfur and TAN properties

.

**•** Table 1 compar es key Bakken q ualities to other important domestic and international crude oils:

o Note the quality data in Table 1 for crudes other than Bakken came from sources

without the extensiv e controls and systematic sampling procedures used in the NDPC

study.

Table 1 : Comparison of Crude Properties

Domestic Light Sweet Crudes API Gravity Sulfur (wt

. %) TAN (mg KOH)

Bakken (1) (2) 40 to 43* 0.1 < 0.1

WTI (4) (5) 37

- 42 0.42 0.28

LLS (2) (4) 36

- 40 0.39 0.4

Eagle Ford (2) 47.7 0.1 0.03

Eagle Ford Light (2) 58.8 0.04 0.02

International Crudes API Gravity Sulfur (wt

. %) TAN (mg KOH)

Light Sweet

Brent (2) (6) 37

- 39 0.4 < 0.05

Medium

Arabian Light (2) 33 1.98 < 0.1

Arabian Heavy (2) 27.7 2.99 < 0.1

Heavy

Western Canadian Select (Heavy Sour) (3) 21.3 3.46 0.93

Dalia (High TAN) (2) (7) 23.1 0.51 1.63 Source s :

1

- NDPC Study Data 5

- Crude Oil Quality Association

2

– Capline 6

- BP Crude Assay

3

- crudemonitor.ca 7

- ExxonMobil Crude Assay

4

- AFPM Bakken Report, 5/14/2014 * Majority of NDPC samples in this range

**•** The qualities of Bakken were very consistent within our sample population and throughout the

supply chain

– from wellhead to rail terminal to refining destination. Test results showed no

evidence of “spiking” with Natural Gas Liquids ( NGLs ) before rail sh ipment.

**•** The test results from this study are also consistent with reported results from others, including

the American Fuel & Petrochemical Manufacturers (AFPM) Bakken Report, the Pipeline and

Hazardous Safety Materials Administration (PHMSA) Operation Sa fe Delivery Report, NDPC

member

- gathered data and other recent studies and presentations on the quality of Bakken

crude oil.

Table 2 : Bakken Quality Comparison, NDPC to AFPM and PHMSA

NDPC Rail Av g (1) AFPM Report PHMSA Report (5)

API Gravity 41.7 42 Not Reported

Vapor Pressure (psi ) 11.5 7.83 (2) 12.3

IBP (°F) 100.3 69.6 (3) 87.0

Light Ends (C2

- C4s) ( Liq. Vol. % ) 4.95 3.5

- 11.9 (4) 4.65 (6)

Comments:

(1) Rail chosen because AFPM samples from Bakken at point of delivery, Rail data from

NDPC closest to direct comparison.

(2) AFPM reported RVP, NDPC reported VPCR 4 (D6377 ) at 37.8°C. AFPM also reported

VPCR 4 done at 50°C, results 13.9

- 16.7 psi.

(3) 87.3 Median, Multiple tests in AFPM data, some of which can report lower than

D86, which skewed average lower.

(4) AFPM report, three respondents average 3.5%, fourth had 12 samples, range 5.9

-

11.9%

.

(5) PHMSA data from Table E, data ranging from 3/17 to 5/2, to maximize overlap with

NDPC study data timeframe.

(6) PHMSA does not report isobutane, and C2

- C4 results do not appear to include

isobutane. By comparison, NDPC C2

- C4 without isobutane was 4.37 Liq. Vol. %.

**•** While the test results from PHMSA’s report agreed closely with the NDPC results, PHMSA did

make some assertions in their Executive Su mmary which do not appear to be supported by their

study or our findings.4 o The PHMSA report makes the statement that

, “ W e conclude that while this product

does not demonstrate the characteristics for a flammable gas, corrosive liquid or toxic

material, it i s more volatile than most other types of crude.” No comparative data was

provided to support this statement ; and

, as we note elsewhere in this report, the limited

data available on other crudes ( that we were able to obtain ) would not support that

conclusi on.

o PHMSA also claims that a higher degree of volatility “correlates to increased ignitability

and flammability.” Again, no support is provided for this statement in the report. While

we are aware that some groups, including API, are studying this very complex subject,

we are not aware of any results or conclusions from those studies to date.

**•** During the time f rame of our sampling program, Bakken had an average vapor pressure of

between 11.5 and 11.8 psi, which is more than 60% below the vapor pressure threshold limit for

liquids under the Hazardous Materials Regulations (43.5 psi).

o It should be noted that the vapor pressure testing was done using the EPA approved

method for crude oils (ASTM D6377), which results in readings about 1 psi higher than if

t he Reid Vapor Pressure (RVP) test method (ASTM D323) was used.

o Test data from an NDPC member’s rail terminal taken over a seven

- month period from

August 2013 through March 2014 showed RVP’s in the range of 8 to 11 psi; consistent

with the NDPC test results when adjusted for seasonality and test method.

o It is difficult to compare the “typical” vapor pressure of Bakken to other crudes because

of the dearth of consistent data ( regarding sampling and testing methodologies) for

other crudes. Most data show Bak ken vapor pressure to be within 2 to 3 psi of other

light sweet crudes (some higher, others lower). The AFPM Bakken Report contained the

following comparison (v ersus key crudes), shown below in Table 3 . Comparisons from

other studies (which are shown later in this report) show similar results.

Table 3 : AFPM Bakken Report, Crude Quality Comparison Table

RVP (psi) Vol

. % Light Ends (C2

- C5 s )

LLS 4.18 3.0

WTI 5.90 6.1

Alberta Dilbit 7.18 7.30 wt

. %

DJ Basin 7.82 8.0

Bakken 7.83 7.2

Eagle Ford 7.95 8.3

Brent 9.33 5.28 wt

. %

**•** The flash point of Bakken is below 73 ° F

, and the Initial Boiling Point ( IBP ) generally averaged

between 95 ° F and 100 ° F, both of which are in the normal range for a light crude oil.5 o The data supports the current Department of Transportatio n (DOT) Pipeline and PHMSA

classification for Bakken crude as a Class 3 Flammable Liquid (similar to other crude oils,

as well as gaso line, ethanol and other materials containing light components).

o As a result, Bakken crude oil meets all specifications for transport using existing DOT

111 tank cars.

o This conclusion is consistent with the recent AFPM Bakken Report , which stated

“Bakken crude oil does not pose risks significantly different than other crude oils or

other flammable liquids authorized for rail transport. Bakken and other crude oils have

been classified as flammable liquids. As noted, Bakken crude poses a lower risk than

othe r flammable liquids authorized for transport by rail in the same specification tank

cars. ”

**•** Flammable liquids fall into packing groups (PG) depending on their IBP as defined by the ASTM

D86 method. The testing performed in this study highlighted the difficulty with using this test

method for packing group determination. The results showed signi ficant (10°F+) variability

between labs on the same sample.

o This is because D86 was not developed for wide boiling range materials like crude oil,

w ith no specifically defined lab

- operating parameters specified. Therefore, different

labs used different operating conditions during testing, resulting in a wide variability of

values for the IBP.

**•** Because of the difficulty with achieving consistent IBP results, groups including API are working

on recommendations to update the current regulations.

o Based up on the findings of this study, the NDPC encourages all members to classify their

BKN crude as a Class 3 PG I flammable liquid until a more definitive testing protocol is

established

.

**•** It is critical to note t hat the determination of PG I versus PG II has no i mpact on the type of rail

car used or on first responder response to an incident and had no impact on any of the incidents

in which Bakken was involved.

**•** The accuracy and precision of our test program wer e ratified by a series of round

- robin tests

between b oth SGS laboratories (Williston, ND and St. Rose, LA) and a second internationally

recognized testing company.

o The results of the round

- robin testing, using identical samples (from four locations) of

Bakken ( tested at each of the three laboratories ) showed excellent agreement on API

gravity and vapor pressure.

o Significant variance did occur in the measured IBP from the D86 testing, as noted earlier.6 o A member co mpany conducted a similar round

- robin test comparison with samples of

Bakken taken from four rail cars. Duplicate samples were sent to SGS and a second

laboratory and the results of this testing also showed excellent agreement on API and

vapor p ressure and significant differences on D86 IBP.

**•** A series of side

- by

- side tests were performed using both the standard sealed glass jars (Boston

Rounds , used for testing during the study ) and Floating Piston Cylinders (FPCs) which have been

suggested by some industry groups for testing vapor pressure

.

o Preliminary results proved inconclusive. Results of samples t aken from the atmospheric

tanks using the glass bottles came back with hi gher vapor pressure readings than when

tested using either glass bottles or FPCs on the pressurized tank discharge

.

o Due to the requirement to sample from a pressurized tap with FPCs, there are

difficulties with sampling and finding appropriate sample locations , which restricts

where samples can be collected

.

o These i nitial results , though limited, indicate that sampling with the glass bottles was at

least as representative as testing wi th FPCs for vapor pressure , and allowed for a greater

variety of sample locations with greater consistency

.

Table 4 below summarizes the results from the sampling and testing program.

**•** API gravity of Bakken was generally in the low 40’s which falls in the range of what is considered

a light crude oil.

**•** Vapor pressure (via ASTM D6377 at 37.8°C/100°F) was in a fairly tight range, averaging between

11.5 and 11.8 psi, with over 90% of well and 100% of rail samples measuring below 13 psi. As

note d earlier, D6377 shows readings about 1 psi higher than the RVP test method (ASTM D323).

**•** D 86 IBP showed a range of approximately 15°F on samples. All samples meas ured as either a

PG I or II, with most of the test results close to the 95°F determination threshold. Because of

the limitations of the test and variability of test conditions, the exact result varied depending on

which laboratory conducted the testing.

**•** The light ends (C2

- C4s) content of Bakken, which averaged just below 5.5 liquid volume %, is

generally within 1 or 2% of other light crudes. Comprehensive data comparable to that

obtained in this study for the other major Light Tight Oil (LTO) basins is not available. However,

the data

, which is available

, indicates that Bakken light ends conte nt is more consistent ; and in

many cases

, lower than for most of the light crudes and condensates produced in the major LTO

basins (including Eagle Ford, Utica, Niobrara and Permian basins).

**•** It is important to note that the DOT

- 111 cars used to transport this crude are r ated for 1 00 psig

, and the type of car used is the same for both PG I and PG II material transport.7 Table 4 : NDPC Bakken Crude Sampling Data Summary

Sample Date Range 3/25 to 4/24/20 14

Total (152 Samples) Avg Min Max

API Gravity 41.0 36.7 46.3

Vapor Pressure (psi ) 11.7 8.9 14.4

D86 IBP (°F) 99.5 (PG II) 91.9 (PG I) 106.8 (PG II)

Light Ends (C2

- C4s) 5.45 3.33 9.30

Rail (49 Samples) Avg Min Max

API Gravity 41.7 39.2 44.0

Vapor Pressure (psi ) 11.5 9.6 12.9

D86 IBP (°F) 100.3 (PG II) 96.7 (PG II) 104.1 (PG II)

Light Ends (C2

- C4s) 4.95 3.91 6.44

Well (103 Samples) Avg Min Max

API Gravity 40.6 36.7 46.3

Vapor Pressure ( psi ) 11.8 8.9 14.4

D86 IBP (°F) 99.1 (PG II) 91.9 (PG I) 106.8 (PG II)

Light Ends (C2

- C4s) 5.69 3.33 9.30

The results indicate that the well

- to

- well quality of Bakken is very consistent. Testing across the

geographic area showed very limited geographical variation in key properties such as API, vapor

pressure and light ends content. Data provided by one of the NDPC member companies (which involved

testing over an eight

- month period) showed that while there was some seasonality in vapor pressure, it

was not significant (3 psi lower in summer mont hs vs. winter months) and it agreed very closely with the

AFPM seasonality data. The data was also consistent with the NDPC test results during the period when

the sampling overlapped.

Bakken quality

, throughout the supply chain in our sample pool

, was also consistent. There was no

evidence of “spiking” of Bakken crude with NGLs between the well and rail terminals, with rail terminals

showing less variation and tighter averages than well

- readings. This was expected

, given that regional

rail facilities receive oil from many wells. Additionally, limited sampling at both the rail terminal and

destination refinery showed no significant weathering or off

- gassing of light ends in transit

.

Operating Conditions/Impact on Bakken Quality

In addition to characte rizing the quality of Bakken crude, our study looked at the impact that well site

operating conditions have on th e quality

. These conditions include ambient temperature, production

volume flow rates/field tank settling time, vapor capture status and field equipment operating

parameters such as separator and treater temperatures and pressures. All of these measurements

were recorded during the sampling program and have been correlated to determine how they impact

test results. Based on this analysis

, we offer the following observations and conclusions :

**•** The samples were gathered during the spring season (late March to late April) and ambient

temperature s varied from a low of 10°F to a high of 65°F (average of about 34°F).8 o Vapor pressure wil l vary by season with lower vapor pressures (lower levels of dissolved

light ends) in the hott er summer months and higher vapor pressures (higher levels of

dissolved light ends) in the colder winter months. This was confirmed by the member

contributed data referred to ea rlier in this section (and included later in this report)

.

o The results during this sampling program were in the intermediate range due to the mid

range ambient temperatures experienced during sampling.

o Although the temperature range was limited, vapor pres sure levels did correlate with

temperatures (consistent with the more extensive member contributed data and the

AFPM data), and with higher measured vapor pressure for crude sampled with lower

ambient temperatures.

**•** While the companies operating in the Bak ken

, which participated in our sampling program

, use

a variety of well site production equipment and operating conditions (production rates,

equipment operating pressures and temperatures) varied across the study , key crude qualities

from our study were di stributed across a fairly narrow range.

o The data consistency indicates that field equipment is limited in its ability to significantly

impact vapor pressure and light ends content.

o This is consistent with the expected capabilities of the equipment.

o The field equipment is designed to separate gas, remove water and break emulsions to

prepare crude for transport, and not remove significant levels of dissolved light ends

from the crude.

**•** Despite the limitations of the field equipment, the data did show that the content of some of

the lighter components, specifically ethane and propane, was reduced in a measureable way by

running the equipment at higher temperatures.

o The difference between running cold (50°F) and running at close to the maximum

practical temperature (150°F) resulted in an average reduction of 0.13 liquid vol. %

ethane and 0.25 liquid vol. % propane, and about 0.40 liquid vol. % of total light ends

reduction.

o Total ethane levels were almost universally below 0.20 liquid vol. % (and often cl oser to

0.10 liquid vol. %) when treaters were run at temperatures above 140°F, compared to

levels averaging around 0.30 liquid vol. % (and as high as 0.40%) when temperatures

were less than 100°F.

o It is important to note that true “plant tests” were not c onducted where the field

equipment temperatures and pressures were varied systematically at individual well

sites, but rather results correlated across all samples at all locations.9 **•** Production rates were also obtained at the time of sampling in an effort t o determine whether

higher flowing wells retained more light ends and had a higher vapor pressure than lower

flowing wells where there was more opportunity to “weather” off the light components.

o The data from the study showed very limited correlation betwe en production rates and

vapor pressure.

o There was also little difference observed in vapor pressure between samples which

were obtained from wells which were directly connected to a gathering system (no

settling time) v ersus those which were obtained from stock tanks (where there was an

opportunity for settling).

o As with the analysis of treater conditions impact on crude quality, the fact that this

analysis was not done under systematic “plant test” conditions does not confirm that

there is not some impact on vapor pressure, but rather that the impact is likely limited.

Conclusions and Recommended Action Steps

**•** Bakken is a light sweet crude oil with very consistent properties throughout the entire

production basin

, and the properties measured meet all the req uirements of 49 CFR 171

- 180 for

safe transport by rail or truck.

**•** Based on the results of this study, the NDPC has developed a set of Field Operations

Recommended Best Practices. These cover the operation of the field treating equipment,

Bakken crude oil q uality, testing procedures and shipping classification, and are detailed in Table

5 below:

Table 5 : BKN Field Operations Recommended Best Pr actices

Field Treating Equipment (In an effort to minimize light ends in crude oil presented for market)

**•** Design and operate all equipment within manufacturers recommended operating limits.

**•** Operate Gas/Liquid Separator (if utilized) at the lowest pressure to accommodate gas sales and

fluid delivery to the Emulsion Separator/Heater Treater

.

**•** Operate Emulsion Separator/ Heater Treater pressure to the lowest operating pressure to safely

accommodate gas sales and fluid delivery to the production tank battery

.

**•** Mai ntain all fired treating equipment ( Emulsion Heater Treater, etc.) temperature between 90°

and 120 ° F+ year round.

**•** Provide maximum tank settling time possible prior to shipment.

**•** Reduce stock tank pressure to lowest pressure possible to maintain vapor colle ction equipment

(engineered flare, vapor recovery, etc

. ) operational integrity.10 Typical BKN * Specifications ( ranges reflect expected seasonality)

Range Typical

**•** API Gravity (hydrometer at 60°F) 3 5 ° to 4 5 ° 4 2 °

**•** Vapor Pressure (ASTM D6377 @ 100°F) 8 to 1 5 psi 11 .5 psi

**•** Initial Boiling Point (A STM D86) 90°F to 105°F 95 °F

**•** Sulfur <0. 3 % 0.15%

**•** H 2 S <1 0 ppm <1 ppm

**•** Light Ends (C2

– C4s) 3% to 9% 5%

*BKN refers to light sweet crude aggregated at rail and pipeline terminals within the Will iston Basin.

This crude is predominantly sourced from the Bakken common source of supply, but also includes legacy

production from various other producing formations located within the proximity of the Bakken field.

BKN does not include nonstabilized co ndensate recovered from wet gas gathering pipelines or from

product derived outside the U

. S

. Williston Basin. Individual well values may be higher or lower than the

aggregated values observed at the rail terminals.

Testing Procedures

**•** Well Site Operators/Purchasers

– Prior to each custody transfer or LACT EOM

o API gravity corrected to 60° F using hydrometer

o Basic Sediment & Water (BS&W) by field centrifugal grind

- out

o Spot test vapor pressure pending available field testing equipment

**•** Rail/Pipeline Terminal Operators

o Test each unit train loading or tank shipment batch

 API gravity corrected to 60° F using hydrometer

 BS&W by field centrifugal grind

- out

o Test at least mid month and EOM

 ASTM D6377 @100° F vapor pressure using certified laboratory

**•** DOT PHMSA Hazmat Shipping Category

o Flammable Liquid Category 3

o Packing Group I **

** P G I is recommended even though the majority of samples tested for the study would fall within

specifications for P G II. The margin of error for the test methodology can result in different labs testing

the same sample with values meeting both P G s. P G I has the more stringent standards and is therefore

recommended to avoid further confusion.

**•** Other recommended procedures

o DO NOT deliver fluid recovered from gas pipe lines (a

. k

. a

. “pi gging operations”) to crude

oil sales system unless processed by stabilization unit capable of lowering vapor

pressure below 10 psi at 100° F.

o DO NOT blend non

- Williston Basin crude oils into the BKN common stream.



### o DO NOT blend plant liquids (plant condens ates , pentanes, butanes or propane) in to the

BKN common stream.11 

### Introduction

Bakken crude has been produced for over 60 years , recently passing the one

- billion

- barrel produced

milestone. Bakken is moved by rail, pipeline and truck, and has been for decades. In the last few years,

crude

- by

- rail has increased rapidly as production has topped one million barrels per day , and as such

, the opportunities for incidents to occur ha ve increased

. Bakken is finding its way to refining markets

across the country, including along new routes to the East and West C oasts , increasing rail traffic on

those tracks. Recently, several high profile incidents in which Bakken crude was being transported

brought public attention on the pot ential hazards of crude

- by

- rail . Bakken has had an increased focus

recently , in large part due to the disaster in Lac Megantic, Quebec

, in July 2013, where 4 7 pe rsons lost

their lives. While human error played a significant role in the cause of the accid ent, the DOT

- 111 rail

cars involved have been heavily scrutinized. The reality is that no rail car is designed to always

withstand the full force of a high

- speed derailment ; and once con tainment is breached during such an

event

, there are countless igniti on sources

.

G overnment focus on these accidents has brought up the potential for changing regulations around the

transport of Bakken (or other light cru des). The oil and gas industry has been building newer style rail

cars since 2011, moving toward repla cing the older DOT

- 111 cars with revised car s that have thicker side

shells and other safety improvements. Additionally, regulations imposed since the accident in Quebec

have required both increased testing of crudes and notification of routes before ship ment. Industry

focus is on ensuring that all activities are conducted with a focus on safety, but t he industry expresses

concerns about additional testing requirements , regulations, or transitions to new transportation or

handling methods without a scientific basis that those changes will have a significant safety impact. The

industry supports regulation s that are implemented through scientific investigation and factual basis,

not implemented emotionally. The PHMSA Bakken Blitz study was started fo r that purpose. While the

federal government has been criticized for not moving immediately, they recognized the importance of

researching the material, railcar s and railcar movements to propose rules that increase overall safety. It

is with the focus on maintaining a scientific basis for decisions that this study was commissioned.

The s cope of this NDPC study was to perform a comprehensive, controlled sampling of Bakken from a

wide range of geographic locations at both individual wells and rail terminals

. The controlled sampling

ensured the same, consistent sampling techniques were used. Samples were sent to a single laboratory

for testing, and thus the same methods and equipment were used. This ensure d t he data would be

more consistent than data aggre gated from many member com panies, each using different labs and

sometimes different test methods.

In addition to the direct sampling of the seven rail terminals and 15 well sites , additional data was

collected. In order to evaluate the impact that shipp ing may have on crude ; samples were taken at the

rail terminal in Fryburg, ND, as well as upon receipt in St. James, LA. The same rail cars were sampled in

both locations, and s amples were sent to the same testing provider for analyses

. Another set of te sting

on an individual well was performed to determine laboratory test variability. Samples were taken at the

same time

, but sent to two different labs : SGS (the primary lab used for this study) and a second

internationally recognized lab

. This resulted in some variance, primarily around D86 IBP measurements,12 which are critical for proper PG determination. A third test was performed to compare D86

measurements between two SGS labs . One lab also did testing by varying some of the test parameters

around D86 instrument setup . Th e results highlighted the opportunity for significant variability of

results and the limitations of using the D86 test method on crude oil samples, which have wide r boiling

ranges than the method was intended.

Testing was c onducted starting March 25 and continued through April 24, 2014. Through the course of

testing, sample data was collected , including the following :

**•** Sample Date, Time, Company, Location (G eographic and Facility/Well ID);

**•** Ambient temperature at time of samp ling ;

**•** Size of tank where sample was pulled from ;

**•** Location in tank (top, bottom, or composite) where sample was taken ;

**•** For samples taken at well, operating conditions including treater / separator operat ing pressure

and temperature, as well as production rate s were recorded ;

**•** API Gravity ;

**•** D86 I BP ;

**•** Vapor Pressure via D6377, as measured at 37.8 ° C/100 ° F with a 4:1 V/L ratio ;

**•** Flash Point via D3278 ;

**•** Light Ends via IP344 ; and

**•** Simulated Distillation via D7169

.

Details on the sample conditions at time of sampling were recorded to evaluate what parameters may

have an impact on t he sample results. All samples were taken in sealed one

- quart glass bottles,

consistent with testing for stock oil tanks. The p rocess was similar to the procedure used for finished

gasoline testing with RVPs up to 15 psi.

On the first visit to each location , samples were taken at both the top and bottom of the tank . This was

done to determine if there was a variance or stratification taking place in tanks, either at the well or at

the rail terminals. On s ubsequent visits, samples at each location were composite samples of the tanks.

In order to capture any variances seen across the Bakken formation, sites were chosen to ensure a wide

variety of locations. The p oints have been plotted on the map s below with corresponding average

sample da ta for each location. The map of rail locations sampled, along w ith corresponding data is

shown in Figure 1

.13 Figure 1 : Rail Sample Locations, With Average Sample Results

The map of well locations sampled, along with corresponding data is sho wn i n Figure 2

.14 Figure 2 : Well Sample Locations, With Average Sample Results



### Test Results/Analys e s

Sampling was conducted beginning March 25, 2014. Each site was sampled from their stock or storage

tank

. For each location, a top and bottom tank sample was taken once, with the remainder of samples

taken as a composite. Samples were spaced every few days to gain the most representative snapshot

during the test period. All testing was completed on April 24, 2014. A complete listing of sample

dates/times by location ( along with all data ) can be seen in the appendix. A breakdown of the samples

is as follows:

**•** API Gravity: 152 Samples ;

**•** D86 I nitial B oiling P oint (IBP) : 152 Samples ;

**•** Vapor Pressure (D6377): 152 Samples;

**•** Flash Point (D3278): 152 Samples ;

**•** Light Ends (IP344) : 1 52 Samples ; and

**•** Simulated Distillation (D7169) : 111 Samples

.15 API Gravity

API Gravity was measured on all samples taken. API is a common property used to compare the relative

density of a given petroleum liquid

. While reported in degrees API gravity, i t inversely correlates to the

measur ed density of the liquid tested. For light crudes, the API gravi ty is generally around 40

- 45 API. Of

all Bakken samples tested, the API gravity ranged from 36.7 t o 46.3 API, averaging 41.0 API. The average

for rail samples w as slightly higher at 41.7 API , but with a tighter range of 39.2 to 44.0 API. These are all

w ithin the range expected for light crudes. By comparison, the common benchmark conventional light

crudes

, West Texas Intermediate ( WTI ) and Light Louisiana Sweet ( LLS )

, measure 36

- 42 API . Bakken is

not substantially lighter than other conventional light crudes. Higher API crudes may, but do not

necessarily correlate with higher vapor pressure crudes. Figure 3 shows the distribution of API gravity

dat a, and Figure 4 shows a plot of API gravity vs. measured vapor pressure.

Figure 3 : API Distribution; Total, Rail, Well

Figur e 4 : API Gravity vs. Measured Vapor Pressure ( VPCR 4 ) 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35

36 37 38 39 40 41 42 43 44 45 46 47

API Total

Well

Rail 40% 20% Avg. 20% 40%

8 9 10 11 12 13 14 15

35 37 39 41 43 45 47Vapor Pressure (psi)

API Gravity16 D86 IBP

D86 I BP measurements were conducted on all samples. As discussed in the summary section , t he D86

distillation IBP is used for determining the appropriate PG for a flammable liquid. Measured D86 IBP

ranged from 91.9 ° F to 106.8 ° F. Only 3 of the 152 readings , all of which were well samples, fell below the

95 ° F threshol d for PG I versus PG II. The IBP results are clustered around the 95 ° F value. Thus, it is

extremel y difficult to properly define the PG because laboratory variance could indicate differing PG

designations . While laboratory variance is a factor with any test, D86 is particularly susceptible because

D86 distillation was never intended for wide boiling r ange materials ; and

, as a result

, the test can have a

significant amount of variance. Due to the importance of this test, and the proximity to the cutoff,

additional laboratory comparisons were performed to determine the consistency of several properties

, with special attention paid to D86 IBP . This will be discussed in detail in the section covering the

interlaborator y ( round

- robin testing ) later in this report. Figure 5 s hows the distribution curve for

measured D86 IBP measurements. The line in green shows the 95 ° F cutoff.

Figure 5 : D86 IBP Distribution; Total, Rail, Well

Vapor Pressure

Vapor pressure was measured using ASTM D6377, Test Method for Determination of Vapor Pressure of

Crude Oil: VPCRx (Expansion Method) on all samples . It is important to note that the more traditional

ASTM D323 Reid Vapor Pressure was not used. Within the past few years, ASTM D6377 has become

widely accepted by industry and the U

. S

. EPA. For this reason, all vapor pressure analyses for this

project were conducted using D6377, with the standard conditions of 100°F (37.8°C) and a vapor

- liquid

ratio of 4:1. In contrast, ASTM D323: Test Method for Vapor Pressure of Petroleum Products (Reid

Method) is one of the oldest methods for determining vapor pressure of crude oils, and much of the

older data in the public domain was obtained using this method. In the va por pressure range of the

samples tested in this study , the RVP values will tend to be about 1 psi lower than the VPCR values. 0.00 0.05 0.10 0.15 0.20 0.25

90 95 100 105 110

D86 IBP ( ° F) Total

Well

Rail

95F Cutoff 40% 20% Avg. 20% 40%17 Vapor pressure samples in this study averaged 11.69 psi, well below the limit for the shipping

classification. Rail averaged sli ghtly lower at 11.52 psi, with a range of 9.57 to 12.85 psi. This is a more

accurate representation of the quality being transported. This is in line with the vapor pressure of

gasoline, which is transported under the same classification. Well vapor pre ssure averaged slightly

higher at 11.77 psi, with a slightly broader range of 8.93 to 14.37 psi. The aggregation of crude and

mixing that takes place at terminals, in addition to the potential slight losses of light ends during

handling and storage

, accou nts for the difference in ranges and absolute vapor pressure seen between

well and rail. Figure 6 show s the distribution of vapor pressures measured

.

Figure 6 : Vapor Pressure Distribution; Total, Rail, Well

Flash Point

Flash point tested via D3278 was performed on all samples . All flash point readings were <73 ° F (<23 ° C),

which is the threshold value to distinguish between PG I or II and PG III . This threshold means all Bakken

samples tested would fall in the PG I or PG II categories, and the ultimate PG I vs. II determination would

be based on the D86 IBP

, as discussed above. Because all samples were <73 ° F, no data analys is was

performed.

Light Ends

Light e nds

- testing via IP344 was performed on all samples

. While t he test measured concentrations of

C1 (methane) to C6 (hexanes) individually by compound

, the following light ends numbers account for

the sum of C2

- C4 s only. Methane was excluded because it was at or below detection limits (0.01 liquid

vol

. %) for all samples , and C5+ has less impact on vapor pressure. The w ell sam ples had both a wider

range (3.33

- 9.30 liquid vol

. %) and average (5.69 liquid vol

. %) concentrat ion than rail (3.91

- 6.44 and

4.95 liquid vol

. %, respectively). This is expected, as some small amount of light ends may be lost to

storage tank vapor recovery systems while in atmospheric storage tanks at the well or rail terminals

.

Also

, the mixing of various crudes into single t anks would help normalize any high or low concentration 0.0 0.1 0.2 0.3 0.4 0.5

8 9 10 11 12 13 14 15

Vapor Pressure D6377 VPCR4 (psi) Total

Well

Rail 40% 20% Avg. 20% 40%18 crudes

. This corresponds with the vapor pressure readings in the previous section. Figure 7 s hows the

distribution of C2

- C4 s as measured.

Figure 7 : C2

- C4 Distribution: Total, Rail, Well

Light ends concentration was plotted ver sus measured vapor pressure on Figure 8 , b elow. There is

some correl ation between the two, although significant scatter appears as the light ends concentration

increases. With a rough correlation between measured vapor pressure and C2

- C4s concentration

, looking at seasonality data presented later, one could conclude that ambient temperature would have

an effect on vapor pressure. Due to the short duration of testing, it was difficult to draw a clear

correlation between the effects of ambient temperature on light ends content directly, although based

on the seasonality data, colder temperatures would have the potential to leave greater amounts of light

ends in the crude. The maps shown in the introduction section highlight the variance in properties from

a geographic standpoint. While there is some variance in geographic measurements of light ends

content, there do es not appear to be any specific north to south or east to west correlation s visible.

Figure 8 : Light Ends (C2

- C4s) Concentration vs. Vapor Pressure 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

2 4 6 8 10

C2

- C4 Liquid Vol. % Total

Well

Rail 40% 20%Avg. 20% 40%

8 9 10 11 12 13 14 15

2 3 4 5 6 7 8 9 10Vapor Pressure (psi)

C2

- C4 Light Ends Liquid Vol. %19 Simulated Distillation

Simulated distillation (Sim D ist) via D7169 was conducted on 111 of the 152 samples. SimDist testing

was perform ed on the first five samples for those samples that started on or around March 25, and

three to four of the samples for the remaining few sites that had a more compressed sampling schedule.

As testing progressed, the results appeared very consistent

, and the im portance of the SimDist results

on overall analysis was determined to be limited . The test was subsequently excluded from later

samples. Simulated d istillation data showed consistent crude quality with the expected variance

, ranging from an IB P of <97°F (minimum detection limit) to a final boiling point over 1200°F. Comparing

Bakken to a pure liquid such as ethano l in a fire, the crude would vaporize more s lowly in a fire should

cars be heated versus ethanol

, which has a single boiling point ( 173°F) where the entire cargo would

vaporize. This temperature is roughly the SimDist 10% point for Bakken crude

. Figure 9 a nd Table 6

,

b e low, show the distillation curve and average distillation data for well, rail and cumulative

measurements

.

Figure 9 : Bakken Crude Distillation Curve

0 200 400 600 800 1000 1200 1400SimDist T (°F)

Max

Avg

Min20 Table 6 : Distillation Data; Well, Rail, Total

SimDist Well Rail Total

IBP < 97 < 97 < 97

5% * 10 6 113 10 8

10% * 15 3 165 1 57

20% 231 238 234

30% 310 316 312

40% 394 396 395

50% 481 482 481

60% 572 572 572

70% 671 670 671

80% 785 787 786

90% 935 939 936

95% 1053 1060 1056

FBP * 130 5 1 31 7 1 309

All values shown are in °F.

*Adjusted averages to account for one or more

values in group above/below detection limits (97 ° F

and 1382 ° F). Adjusted by averaging detection limit

for values, raw data in appendix.

Sample Consistency

Comparing the well versus rail properties for the API/ D86 IBP/vapor p ressure

, as well as light ends and

SimDis t, the qualities are very close and consistently correlate

, as exp ected, with some slightly lower

light ends numbers for rail properties for reasons discussed above. The light ends showed on average

lower numbers and distillation curves were very similar. This shows that there is no evidence of spiking

of Bakken crudes with light materials as some news reports had conjectured

. The r ail terminals sampled

accounted for approximately 50% of total rail capacity out of the Bakken . These terminals r eceive

crudes from many regional wells, not just member companies that contributed data : and

, given the span

of testing, it is highly likely results would have reflected such activity.21 Table 7 : Quality Comparison

– Well vs. Rail Test Results

Well Rail

API Gravity 40.6 41.7

D86 IBP ( ° F) 99.1 100

VPCR D63 77 (psi ) 11.8 11.5

Light Ends (Liquid Vol. % )

Ethane 0.24 0.23

Propane 1.63 1. 39

Isobutane 0.6 5 0.58

n

- Butane 3.1 6 2.75

Isopentane 1.52 1.42

n

- Pentane 2. 90 2.72

C2

- C4s 5. 6 9 4.95

C2

- C5 s * 10. 12 9. 1 0

*Excludes Cyclopentane

Sample Methodology Comparison: Floating Piston Cylinder (FPC) versus Standard Glass Bottle

The sampling methodology employed in the NDPC Study was the industry standard technique of

capturing material from tanks at either the well site or rail location in a glass bottle and sealing them

with a screw

- on cap. These quart

- sized (32oz) glass bottles, referred to as “Boston Rounds” are the

standard for sampling crude, gasoline and other hydrocarbons with similar vapor pressures to Bakken

crude. Recently, a new techni que has begun to gain acceptance as an alternate method, which involves

the use of a FPC . The sample is captured under pressure in a cylinder with a hydraulic piston which

minimizes any vapor space. The purpose of this is to minimize potential gas losses that could flash off

from a liquid sample as it is captured at atmospheric pressure in a bottle

, or is lost to the vapor space

left when capturing a sample in a bottle.

In order to determine if there was any variance between the standard bottle sampling te chnique and

the FPC, a set of four comparison tests at rail locations were performed. Rail locations were chosen

because the floating piston cylinders require a pressurized sample location in order to overcome the

pressure of the hydraulic piston in the c ylinder. In each case

, the samples were taken at the tap (spigot)

located downstream of the loading pumps from the storage tanks to the rail car loading racks . Samples

were taken while the line was in service and had flow (and adequate pressure) to fill the FPC’s. By

comparison, the samples taken during the NDPC testing were from the tank itself at atmospheric

pressure upstream of the loading pumps where the FPC samples were taken

.

The initial results from this testing proved inclusive. While some sampl es showed excellent agreement

both with historic NDPC sampling and between the glass bottle and FPC samples at the pressurized

sample point , others showed variation, with samples taken off the line having lower vapor pressure

values than the samples collec ted from the tan k . This implies that samples taken at the pressurized

sample point downstream of the tank somehow lost light ends by comparison. This brings into question22 sampling techniques, sample point location and effects of sampling while under pres sure in some

locations such as after a pump. Further evaluation

, regarding the comparison of FPC results to standard

sampling with Boston Round glass jars

, is being considered and will be provided as an addendum to this

report if co nduct ed

.

Interlaboratory ( Round

- Robin ) Testing

Due to the importance of ensuring both accuracy and precision in testing, and to gain a better

understanding of potential laboratory variability, a series of round

- robin tests were performed. These

tests were designed to determine what, if any, differences the individual labs had for id entical samples.

SGS ( th e testing provider for this study) participated using both their St. Rose , LA and Williston , ND

laboratorie s. Additionally, a second internationally recognized testing company participated to provide

a third

- party comparison (referred to as Lab M, in the T ables below) . Four different well locations wer e

sampled during this test. Three identical samples were taken, and one was sent to each of the three

lab s . Tests for API gravity, vapor pressure and D86 IBP were performed.

The results of this round

- robin showed extremely good consistency between labs on both API gravity

and vapor pressure. The consistency va lidated that the integrity of the samples were not compromised

during this test and that they were not affected by handling or shipping. Table 8 sho w s the consistency

among samples. Most samples had near zero maximum deltas between readings , with the exception of

one vapor pressure sample that was slightly lower than the others

.

Tabl e 8 : Round

- Robin API and Vapor Pressure

API Gravity ( Density, D5002 )

Sample Location Date @ Time Lab M SGS St. Rose SG S Williston Max Delta

1 5/1/14 @ 16:30 40.2 40.2 40.2 0.0

2 5/1/14 @ 16:30 43.0 42.9 42.9 0.1

3 4/30/14 @ 16:00 43.6 43.6 43.6 0.0

4 5/1/14 @ 16:30 43.0 42.9 42.9 0.1

Vapor Pressure ( VPCR4, psi)

Sample Location Date @ Time Lab M SGS St. Rose SGS Williston Max Delta

1 5/1/14 @ 16:30 10.1 10.3 10.1 0.2

2 5/1/14 @ 16:30 15.0 15.4 13.8 1.6

3 4/30/14 @ 16:00 10.6 10.6 10.6 0.0

4 5/1/14 @ 16:30 11.4 11.5 11.2 0.3

The consistency did not carry through for the D86 testing. There was noticeable inconsistency between

each lab, with samples varying by as much as 19.5 ° F for a given sample. While all samples tested during

this would fall within a Class 3 Flammable liquid, depending on the lab used, the same sample could fall

above or below the 95 ° F mark for PG I vs. PG II. Table 9 shows the readings for each sample, and the

maximum deltas measured.23 Table 9 : Round

- Robin D86 IBP

D86 IBP (°F)

Sample Location Date @ Time Lab M SGS St. Rose SGS Williston Max Delta

1 5/1/14 @ 16:30 89.9 95.4 101.8 11.9

2 5/1/14 @ 16:30 83.1 89.1 102.6 19.5

3 4/30/14 @ 16:00 87.8 90.7 105.5 17.7

4 5/1/14 @ 16:30 89.2 94.5 102.2 13.0

D86 Variation

The D86 testing showed that

, in fact, there were problems with variability betw een labs. This is a result

of the test not being designed for evaluating such a wide boiling range material, and thus different labs

choose different heating, condenser temperature and receiver temperatur e parameters. In addition, the

D86 distillation conditions do not allow for the accurate retention of butane and lighter material

. Thus,

samples containing significant quantities of butane and lighter material will not have this material

detected and will still yield an IBP in the 80

- 100°F range. The C1

- C4 compounds do not readily condense

at the condenser temperatures the D86 test is conducted at , and thus are not accurately measured.

Before we discuss this further, a brief description of how a D86 distillation is performed is warranted.

The setup consists of a flask of 100ml of liquid to be tested, a heater to boil the liquid, associated

instrumentation to measure the temperature and volume , a n overhead con denser which condenses the

vapor boiled off and a receiver which collects the condensed material. While it is allowable to perform

this test manually, almost all current analyses are conducted utilizing automatic instrumentation, which

use s microprocessor controlled instrumentation to produce more precise results with minimal human

intervention. All analyses conducted on this project utilized this type of automated instrumentation.

Current D86 instruments are automatic ; and typically

, the type of liquid b eing tested will dictate

parameters such as the condenser temperature and heat rate. The liquid is heated at the given rate

dictated by the operator, and as it boils, it is condensed overhead, and drops into the receiver , which is

maintained at a fixed temperature . The amount of liquid in the receiver is measured, and the distillation

curve is generated . The liquid at the end is measured to determine the total recovery, as light

components dissolved in the original sample can be lost if they are not a ble to be condensed at the

condenser ’s operating temperature. Figure 10 shows a sample simple distillation, similar in principle to

that used during D86 testing. The sample is heated, condenses, and is collected in the receiver. The

volume at a given temperature is recorded to generate the distillation curve.24 Figure 10 : Simple Distillation Apparatus

Initial boiling poin t by D86 is defined as the overhead temperature (corrected for atmospheric pressure)

observed at the instant the first drop of condensate falls from the lo wer end of the condenser tube. For

a material such as gasoline, which typically has a boiling range of about 100

- 400 ° F, t he liquid must first

be heated at least some before enough vaporization occurs and vapor begin s to condense . This is well

above the condenser tempe rature, and as such, a more complete recovery is achieved. In the case of a

li ght crud e sample, which contains dissolved gases (C1

- C4s) which do not condense at the typical

condenser te mperature, a lower recovery is achieved and less accurate actual IBP is measured.

The implications of this are that if parameters are not identical, the temperature with which the first

drop is perceived to form can vary considerably. The difference for a given sample will normalize out as

the 5% and 10% points are reached, but those v alues are not considered as part of the overall

requirement for DOT classification . The rate at which the sample is heated can affect how well the

sample was able to reach equilibrium temperature and drive off any light ends. The same goe s for how

cold t he condenser is; the colder

, the more it will condense. Faster heat rates and colder condenser

temperatures tend to drive the IBP temperature lower than if the sample is more slowly heated with a

higher condenser temperature.

Table 10 shows the impact that these parameters have on the boiling points. For the same sample,

significant error can be introduced, over 14 ° F in the case of this set, for the sa me lab and same

instrument, with slightly different operating parameters. This highlights a serious flaw in using the D86

test for compliance on determining PG s for materials such as Bakken crude. Because of the difficulty

with achieving consistent IBP re sults, groups including API are working on recommendations to update

the current regulations.25 Table 10 : D86 IBP Variability Testing

Lab SGS St. Rose SGS Williston SGS Williston

Condenser Temp 60 ° F 60 ° F 31 ° F

Receiver Temp 73 ° F 81 ° F 81 ° F

Sample D86 IBP Time to IBP D86 IBP Time to IBP D86 IBP Time to IBP

1 95 .4 4 min 53 sec 101.8 7 min 56 sec 91.1 7 min 45 sec

2 89.1 3 min 22 sec 102.6 6 min 27 sec 88.7 6 min 07 sec

3 90 .7 3 min 37 sec 105.5 7 min 26 sec 91.4 7 min 11 sec

4 94 .5 3 min 42 sec 102.2 6 min 50 sec 94.4 8 min 00 sec

Rail Testing

A separate set of testing was conducted in order to evaluate whether there was merit in the claims that

Bakken sees substantial weathering during transport. Five individual rail cars were sampled at t heir

origin in Fryburg, ND

, and destination of St. James, LA. Samples were tested by local labs in ND and LA

of the same company for vapor pressure via D6377 at 100 ° F, flash point via D 8 6, H 2 S in vapor phase at

77 ° F via ITM 3468 and light ends analysis by modified D6730. The results were then compared to

average NDPC test results from the same rail terminal. The testing showed that throughout

transportation, vapor pres sure and C2

- C4 concentration were co nsistent, indicating there were no light

ends losses. Additionally

, no detectable H

2 S was present in the samples . Comparing the samples tested

at the two labs, the greatest variance in results was with the D86 IBP, for reasons discussed previously.

Table 11 shows the table of average test data from both Fryburg and St. James and compares it to the

other data collected at the Fryburg rail terminal. The appendix contains the full set of sample data for

the cars.

Table 11 : Rail Car Source and Destination Testing

Test Units Avg. ND Rail

Terminal

5 Car Samples Avg. St. James

Rail Terminal

5 Car Samples Avg. NDPC Data for

ND Rail Terminal

VPCR 4 (37.8 0 C) psi 10.47 10.61 10.45

IBP 0 F 94.7 90.4 101.7

Flash Point 0 F <50 <50 <73

H 2 S in Vapor Phase ppm v/v <1 <1

C2

- C4s Vol % 4.00 4.08 4.23

C2

- C5s * Vol % 8.01 7.89 8.13

*Excludes Cyclopentane

Member Contributed Data

In addition to the data collected, member companies voluntarily submitted data to supplemen t data

gathered in this study

. The data contributed consisted of a smaller, less controlled round

- robin sample

test between one SGS laboratory and a second independent laboratory

, and a NDPC member rail26 company terminal who contributed vapor pressure operating data collected over a seven

- month period

from late August 2013 to late March 2014

.

A round

- robin test was conducted by a NDPC member company who sent samples from four rail cars to

both S GS and Lab M indep endently. The company had testing for API gravity, vapor pressure and D86

IBP measured on each sample . The results were similar to those found by NDPC conducted round

- robin.

API and vapor pressure had little variance, but the D86 IBP variance averaged o ver 13 ° F with a maximum

variance of 15.6 ° F. This

, again

, highlights the difficulty with getting consistent and accurate D86 IBP

measurements on a full boiling point material such as crude oil.

Table 12 : Member Compa ny Laboratory Co mparison (Round

- Robin)

Sample ID API Gravity D86 IBP (°F) VPCR4 D6377 (psi)

Sample 1: SGS 44.0 101 10.52

Sample 1: Lab M 44.4 85.4 11.35

Sample 2: SGS 43.9 101.9 10.47

Sample 2: Lab M 44.3 92.4 11.47

Sample 3: SGS 42.4 100.5 10.50

Sample 3: Lab M 44.4 86.5 11.29

Sample 4: SGS 43.1 103.7 10.28

Sample 4: Lab M 44.2 89.9 11.29

Avg. Variance 1.0 13.2 0.91

Max Variance 2.0 15.6 1.01

A second member company contributed operating data collected over the course of normal operations

on vapor pressure of Bakken crude being loaded into rail cars. It is known that as ambient temperature

changes, the amount of light ends material separated from the raw crude at the wellhead

, changes.

Higher temperat ures lead to higher gas separation, so winter and early spring conditions (when the

NDPC test was performed) would highlight some of the highe r vapor pressure Bakken crude throughout

the year. The range of vapor pressure data collected shows that while th ere is some change, even the

highest RVP readings in the winter peak at about 11 psi, nearly an order of magnitude below the 100

psi g for which the DOT

- 111 rail cars are rated.

The samples from this member company were analyzed in their in

- house lab and w ere measured for

RVP versus VPCR 4 that was used throughout the NDPC testing

. Due to the differences in test

methodology, RVP readings typically are 1 psi lower than VPCR 4 readings. There was a brief overlap of

time w hen sample data overlapped in late Ma rch, 2014. The data did correlate very well between

measured va p or pressure at rail terminals test ed compared to measurements at the member rail

terminal when accounting for the testing difference. Figure 11 shows the chart of member contributed

seasonality data, with NDPC test data overlaid , with the 1 psi correction.27 Figure 11 : Seasonality Data Collected by Member Comp any

The seasonality results are in line with the report from Transport Canada on the derailment in Quebec

which showed RVP results ranging from 9.0

- 9.6 psi. The derailment took place in July 2013, and the RVP

results recorded by Transport Canada are con sistent with the summer results measured by the

seasonality data above.



### AFPM Report Comparison

AFPM released a report on Bakken crude titled

, “A Survey of Bakken Crude Oil Characteristics Assembled

for the U.S. Department of Transportation” dated May 14, 2014. The report assembled a variety of

Bakken data and compared its results to the parameters as laid out by DOT PHMSA and other

international regulations for shipping . While raw data was not given for analysis, a statistical breakdown

and walkthrough of each captured parameter gave a good overview of Bakken crude properties from a

broad data set.

**•** The APFM report concluded that Bakken w as not materially different and posed no special

hazards versus other light crude oils.

o These findings coincide with the findings from this NDPC report.

**•** The AFPM report came to the same conclusions regarding the safety of Bakken in DOT

- 111 rail

cars.

o Vapor pressure was well below the allowable pressure for DOT

- 111 rail cars.

o Bakken was well within all specifications for a Class 3 flammable liquid.

**•** Despite the same conclusions

, a direct comparison between AFPM and NDPC cannot be

performed on all data points collected

. 6 7 8 9 10 11 12

8/1/13 9/30/13 11/29/13 1/28/14 3/29/14Vapor Pressure (psi)

Production Train A

Production Train B

NDPC Rail28 o The AFPM report collected voluntary data submissions from its members , in stead of a

controlled study

.

 Its members consist largely of fuel producers who sample and test the Bakken

as it arrives at their facility , versus at the well or rail terminal

.

o Sampling procedures and test methods were not uniform across all data.

 The AFPM report listed all test methods used for various properties.

 Samples were run at different labs, resulting in increased variability.

o The report did not indicate if tests of differing methods were correlated in any way prior

to comparison, nor what t he mi nimum detection limits were or how samples were

handled.

**•** This variety of testing led to certain peculiarities, such as the initial boiling point or flash point

data having what appeared to be varying test ranges.

Of particular focus was the IBP test ing. For the NDPC report, a ll data in the main data set was tested by

a single testing provider , SGS . Samples were consistently collected and handled throughout the testing

process , with a ll testing us ing the same ASTM D86 testing protocol. In contrast, t he AFPM report used

five different test methods for distillation alone , as discussed in their appendix. This resulted in I BP data

ranging down to 32 ° F (0 ° C). In particular, gas chromatographic methods are referenced as being used.

These methods, e.g. D2887, are known to yield much lower IBPs than the D86 method. Thus, this d ata

must be both used and compared with caution. Based on our earlier discussion of how D86 testing is

conducted, t he D86 test method does not lend itself to measuring boiling points that low. The

condenser does not operate at a temperature low enough (it would have to operate below 32 ° F to

condense materials boiling at that temperature). Additionally , the initial sa mple is not cooled to that

level before testing and the collector is held at roughly room temperature , meaning any collected

sample would evaporate . Th us

, any IBP results below about 60°F must

, therefore

, have been conducted

with another test method , assu med to be a gas chromatographi c simulated distillation method . Since

there was no indication that the data was correlated to D86, and the regulations are based around D86

testing, it raises questions about what the equivalent boiling points were for those samples, based on

DOT requirements . Similarly, other data that used multiple test methods did not show an indication of a

correlation between the two methods and makes the data good for information only, but not from

which to draw firm conclusions or cor relations. Table 13 shown below gives a brief comparison of the

results of the two tests.29 Table 13 : Comparison of NDPC to AFPM Study Data

NDPC Average

Well Rail Range AFPM Study Comments

API Gr avity 40.6 41.7 36.7

-

46.3 API Gravity 42 Reported in crude comparison

table.

D86 IBP ( ° F) 99.1 100.

3 91.9

-

106.8 IBP

(Various

Tests) 69.6 87.3 median IBP, m ultiple tests in

AFPM data, some of which can

report lower than D86, which

skewed average lower.

Vap. P D63 77

(37.8C) (psi ) 11.8 11.5 8.9

-

14.4 RVP ( psi )

(Various

Tests) 7.83 RVP reported by AFPM. Al so

reported D6377 done at 50C

(higher than NDPC), with range

13.9

- 16.7 psi.

Seasonality

RVP ( psi )

- 9.98 7.9

-

11.6 Seasonality

RVP ( psi ) 8

- 12.5 AFPM 807 data points to 215 for

NDPC, greater variety of

locations.

NDPC

Light Ends

(Liquid Vol. % ) Well Rail Range AFPM

Light Ends

(Liquid Vol. %) Comments

Ethane 0.24 0.23 0.08

-

0.67 Ethane 0.5

Reported as ranges only. Propane 1.63 1. 39 0.84

-

3.13 Propane <1

- 2%

Isobutane 0.6 5 0.58 0.35

-

0.95 Isobutane

3

- 4% n

- Butane 3.1 6 2.75 2.00

-

4.55 n

- Butane

Isopentane 1.52 1.42 1.10

-

1.93

n

- Pentane 2.9 0 2.72 2.07

-

3.70 n

- Pentane

-

C2

- C4s 5. 69 4.95 3.52

-

9.30 C2

- C4s 3.5

-

11.9% AFPM report, three respondents

average 3.5%, fourth had 12

samples, range 5.9

- 11.9%

C2

- C5 s * 10.12 9. 1 0 6. 77

-

14. 71 C2

- C5 7.2 *Excludes Cyclopentane

The AFPM report did include additional data

, which was not tested as part of the NDPC study. Many

samples were tested for hydrogen sulfide ( H 2 S ) in the vapor phase, and they were able to capture some

samples that contained detectable H 2 S. It is k nown that select pockets in legacy ND wells contain higher

H 2 S concentrations, but that crude is typically segregated from low H 2 S Bakken crude for safety reasons.

The AFPM study was also able to gather data on corrosivity using National Association of Corrosion

Engineers ( NACE ) TM 172 testing , which co nfirmed the low corrosivity of Bakken crude. The AFPM

paper also summarized data gathered on the pressure of rail cars measured as they reached their final

destination. Over 380 cars were sampled, with a majority arriving to the refinery in the 7

- 10 psig range.

The highest reported pressure recorded was 11.3 psig, well below the rated operating pressure of the

DOT

- 111 rail cars or their minimum relief valve setting of 35 psig.30 Despite the inability to draw a direct comparison between the AFPM and NDPC data , the results of both

studies lead to the same conclusion. Bakken crude is a consistent product that clearly fits the

classification of a Class 3 Flammable Liquid. The only point of debate would be the PG designation that

is used, PG I v ersus PG II. Tha t falls back to D86 testing of full boiling range materials, and the need for a

reevaluation as to whether that is the most appropriate test method for the classification of materials

such as Bakken for shipment.



### The Pipeline and Hazardous Materials Safety Administration ( PHMSA ) Report Comparison

PHMSA released a report on July 23 , 2014, which included the results of their findings as part of

Operation Safe Delivery

. PHMSA found that

, “Operation Classification has determined that the current

classification applied to Bakken crude is accurate under the current classification system.” The PHMSA

report outlined the efforts of their testing program

, which began in August 2013, and spanned through

M ay 2014. Sampling was unannounced and intended to capture a representative sample of Bakken

crude. The initial phase

, from August

- November 2013

, w as focused on verifying that appropriate hazard

classes that were being used ; and as such, testing was limited to flash point and boiling point. The

second phase from F ebruary

- May 2014 was to gain a complete understanding of Bakken properties and

more closely align with the NDPC study. This data from Phase 2 was the data used to compare to the

NDPC report.

The results outlined showed good agreement with the data collect ed as part of the NDPC study

, especially when comparing data collected for the same general time p eriod. Since the NDPC test ing was

done during the period from late March to late April 2014 , the data points that fell in this general time

frame w ere separ ated out and compared (11 total samples), as w as the entire data set (88 total

samples). S ince the last round of PHMSA sampling was conducted at rail

- loading facilities

, for

consistency , comparisons were made specifically with the NDPC rail data

. As seen in Table 14 below,

the results agreed very well, despite not being identical samples nor identical locations. The variation is

minimal, and ranges agree well, with a trend toward slightly lower D86 IBP readings from PHMSA ;

although as discussed earlier, those results are subject to variation based on exact testing parameters

and procedures

.31 Table 14 : Comparison of NDPC to PHMSA Study Data

PHMSA Data Table E

Mar

- May (11 Samples) NDPC Data

Rail Only (49 Samples)

Dates: 3/17/14 to 5/2/14 Dates: 3/25/14 to 4/18/14

Average Min Max Average Min Max

Flash Point ( ° F) <50

- - <73

- -

D86 IBP (°F) 87.0 79.1 94.4 100.3 96.7 104.1

VPCR 4 @ 100 °F (psi) 12.28 10.22 14.28 11.52 9.57 12.85

Ethane (% Vol) 0.20 0.06 0.29 0.23 0.13 0.33

Propane (% Vol) 1.38 0.85 1.95 1.39 1.02 1.95

Butane* (% Vol) 3.49 3.01 4.44 3.32 2.63 4.24

C2

- C4 4.65 0.00 6.68 4.95 3.91 6.44

PHMSA Data Table E

Total (88 Samples) NDPC Data

Total (152 Samples)

Dates: 2/24/14 to 5/2/14 Dates: 3/25/14 to 4/24/14

Average Min Max Average Min Max

Flash Point ( ° F) <50

- - <73

- -

D86 IBP (°F) 88.1 79.1 97.5 99.5 91.9 106.8

VPCR 4 @ 100 °F (psi) 12.42 10.10 15.10 11.69 8.93 14.37

Ethane (Liq Vol %) 0.23 0.06 0.40 0.24 0.08 0.67

Propane (Liq Vol %) 1.45 0.85 2.08 1.55 0.84 3.13

Butane* (Liq Vol %) 3.55 2.74 4.48 3.66 2.35 5.50

C2

- C4s 5.17 0.00 6.88 5.45 3.33 9.30

*PHMSA report does not specify if isobutane was included in their measurements . For comparison

purposes, this report assumes b utane includes n

- b utane and i sobutane

.

In the conclusion of the report, PHMSA did note that

, “ W e conclude that while this product does not

demonstrate the characteristics for a flammable gas, corrosive liquid or toxic material, it is more volatile

than most other types of crude.” While PHMSA does say Bakken is currently classified appropriately as a

Class 3 Flammable Liquid, PG 1 or 2

, depending on D86 IBP, they claim that Bakken has “higher gas

content, lower flash point, lower boiling point and higher vapor pressure than other crude oils.” PHMSA

makes this claim without testing or reporting what the values are for these other crude oils.

As we have noted previously, th ere have been no extensive or controlled sampling and testing programs

for other light sweet crude oils, such as was done in both this NDPC study and the PHMSA program for

Bakken ; and

, therefore

, it is not possible to make a broad generalization on compara tive properties.

Based on limited information from the AFPM study, as well other publicly available data Bakken appears

to be generally similar in vapor pressure and light ends content to most light crude oils , and there are

certainly crudes, particularly those produced from tight oil formations , which are higher in those

parameters

. Additionally, making the claim that vapor pressure and light ends content correlates to32 increased ignitability and flammability is a broad statement that without extensive and complicated

testing cannot be factually stated or supported.



### Operating Conditions

As part of the sampling program, operating conditions at the time of sample collection were taken for

each well location sampled. This was done in order to determine if there were additional factors which

may affect crude qualities. The conditions recorded included ambient temperature, separator and

treater temperature and pressure, well production rate, equipment size and configuration, and for wells

not attached to a g athering system, the time the stock tank was isolated from the well.

In order to better understand the impact the operational conditions play, a brief overview of wellhead

crude processing is warranted. Raw crude

, as it comes out of the ground

, is a mix of gas, liquid

hydrocarbon s and water. The amount of each varies depending on geology and ambient temperature.

The raw crude stream requires separation to remove the gas phase and separate entrained water before

it is transferred to the stock tank. Thi s is achieved by passing the crude through a separator and/or

treater unit before it is stored and transported . Often, a standard three

- phase (gas/oil/water) separator

drum is used to separate the bulk water and gas from the hydrocarbon stream, as seen in Figure 12 . The

raw crude stream enters the separator drum and settles. Gas passes over and through a mist extractor,

essentially a fine metal mesh, to collect and knock out entrained liquid before passing out of the drum

to either be flared or captured. The liquid settles and separates as it flows through the vessel. In a

three

- phase separator, t he liquid level is controlled so that the oil layer passes over a baf fle and out of

the vessel to tankage or for additional treatment. The water, which collects behind the baffle, is drained

off and treated. Some wells may instead use a simple gas/liquid separator followed by a second

liquid/liquid separator. In this co nfiguration the liquid passes out without separating water and

hydrocarbons, which then pass es directly to a second separator or treater designed to separate the

liquid hydrocarbons and water

.33 Figure 12 : Horizontal Three Phase (Gas/Liquid/Water) Separator Diagram 1

Often, t he hydrocarbon stream that leaves a conventional separator still contains an emulsion of some

water, the severity of which varies from well to well and on ambient conditions. In order to minimize

water in the crude, the stream is often sent to a treater. A treater unit is

, in effect

, a second separator

designed to help break the emulsion via the addition of heat and passing the crude through a coalescer

or series of baffles to help separate out the remaining water. Heating the stream aids in separation of

the oil and water in part by lowering the viscosity of t he oil, which aids in coalescence of small water

droplets to larger ones that can more easily separate.

Figure 13 shows how the untreated hydrocarbon stream, in orange, flows into the vessel and down

through t he heated section . In thi s section, the stream is heated and the water has a chance to

separate. Similar to the separator, additional dissolved gasses evolved when the crude is heated are

separ ated as well, and are either flared or collected. Some wells that do not have a lot of water in the

crude

, may use only a treater for oil treatment.

1 Image: http://www.netl.doe.gov/Image%20Library/technologies/pwmis/BasSep_3PhaseSeparator.jp g34 Figure 13 : Vertical Treater Diagram 2

The separator and treater operate at relatively constant conditions as set by the well operator.

Typically

, they operate under pressure (a range of 8

- 80 psig was recorded in this study) as the flow

follows through the separator and treater to tankage. Adequate p ressure is requir ed to overcome any

head pressure and allow movement of oil into the stock tank. When a treater is used, the stream is

heated only enough to maximize separ ation of the emulsion ( range up to 160 ° F was observed in this

study ), while minimizing the temperatur e to which the stream needs to be heated . There are several

reasons to limiting temperature

, including energy cost of heating, increased hydrocarbon losses to flare

and potential for increased tank emissions.

Due to the difficulty and hazards associated w ith sampling a raw well stream, crude was sampled from

the stock tank after it passed through the sep arator and/or treater. This is consistent with measuring

the quality of the crude that would be transported via rail. Additional notes were taken on whet her the

wells were connected to gathering systems; small pipeline networks designed to take the oil to central

facilities to be loaded to rail or major pipeline systems. Other wells fill stock tanks and require trucks to

2 Image: http://www.des

- co.com/portfolioentry/heater

- treaters/35 haul crude away. Wells not on gat hering systems were sampled from their full stock tanks after they

were safely filled and isolated from the well.

As discussed previously, on the first visit to each location, samples were taken at both the top and

bottom of the tank. This was done to d etermine if there was a variance or stratification taking place in

tanks, either at the well or at the rail terminals. No stratification was observed , with relative uniformity

of properties from the top to bottom. On subsequent visits, samples at each lo cation were composite

samples of the tanks. The average delta ( top

- bottom) for rail, well and overall samples is summarized in

Table 15 , with complete data available in the appendix.

Table 15 : Average Delta (Top

- Bottom) of Tank, Rail and Overall Samples

Avg. Delta (Top

- Bottom)

Rail Well Overall

API Gravity 0.0 0.2 0.1

D86 IBP ( ° F) 0.5

- 0.9

- 0.5

Vapor P (psi) 0.12 0.01 0.05

Light Ends (Liquid Vol. %)

Ethane 0.00 0.02 0.01

Propane 0.00 0.05 0.03

Isobutane 0.00 0.01 0.01

n

- Butane 0.00 0.05 0.03

Isopentane 0.00 0.01 0.01

n

- Pentane 0.01 0.03 0.02

Cyclopentane 0.00 0.00 0.00

C2

- C4s

- 0.01 0.12 0.08

C2

- C5s * 0.00 0.15 0.10

*Excludes Cyclopentane

Vapor pressure showed no clear correlation with operating conditions. Production rate did not show

any appreciable impact on the vapor pressure (this is covered later in th is report) . The same was seen

with both operating pressure and temperature. The measured vapor pressure was scattered

throughout the range of temperatures and pressures, with no clear correlation. Figure 14 , below, shows

a plot of vapor pressure versus operational temperature. A plot of vapor pressure versus operating

pressure can be seen in F igure 1

- 1 in the A ppendix.36 Figure 14 : Vapor Pressure versus Operati ng Temperature

The results of the testing did show a slight correlation between operating temperature and light ends

(ethane/propane) content , which would be expected. Otherwise, there was no clear correlation

between either operating pres sure or production rate and the subsequent vapor pressure or

ethane/propane content in the crude. While both the separator and treater separate out gas phase

from the mixed stream, they are not designed as “stabilizers” to treat the crude. Their purpose is to

remove entrained gases and water. Stabilizers, often used in condensate ( crude API 50 ° +) service

separate out the lightest components from a given hydrocarbon stream. Those components are then

transported separately as liquefied petroleum gas (LPG) and NGLs in pressurized rail cars alongside

Bakken crude. This would ultimately be shifting responsibility from one type of rail car to another,

concentrating and magnifying potential risks. As with any crude oil, some dissolved light ends will exist

in Bakken , and will only be completely removed when the crude is fully fractionated in a refinery setting

. This is true of any light crude oil, regardless of the separator and treater setup is used.

Figure 15 and Figure 16 show the effect of operating temperature on the ethane and propane

concentrations. There is a slight trend t oward lower concentrations at higher temperatures. This is

plausible, as some of the lightest components will be driven off as the crude is heated. This would be

most apparent in winter months when this test was conducted and ambient temperatures are low . In

the summer months, ambient temperatures may reach 100 ° F or more, making use of the treater less

impactful . Figures 1

- 2 through 1

- 5 in the A ppendix show the charts of the ethane and propane v ersus

operating pressure and production rate, for reference. 8 9 10 11 12 13 14 15

0 20 40 60 80 100 120 140 160 180Vapor Pressure (psi)

Operating Temperature ( ° F) W1

W2

W3

W4

W5

W6

W7

W8

W9

W10

W11

W12

W13

W14

W1537 Figure 15 : Ethane Liquid Vol

. % versus Operati ng Temperature

Figure 16 : Propane Liquid Vol

. % versus Operat ing Temperature

Based on these findings, a general correlation between the operating temperature of the treater and

the ethane or propane concentration was developed. Excluding the few points that were anomalous

from W7, the following correlations were developed (charts can be seen in the A ppendix, F igures 1

- 6

and 1

- 7) :

1. Ethane (Liquid Vol %) =

- 0.0013 * Temp ( ° F) + 0.3568 ; and

2. Propane (Liquid Vol %) =

- 0.0025 * Temp ( ° F) + 1.8414

.

These equations hold that the difference in concentration between 50°F and 150°F operation is 0.13 and

0.25 liquid vol

. % for ethane and propane, respectively. This represents approximately 0.4 liquid vol

. % 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80

0 20 40 60 80 100 120 140 160 180Ethane (Liquid Vol. %)

Operating Temperature ( ° F) W1

W2

W3

W4

W5

W6

W7

W8

W9

W10

W11

W12

W13

W14

W15

0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50

0 20 40 60 80 100 120 140 160 180Propane (Liquid Vol. %)

Operating Temperature ( ° F) W1

W2

W3

W4

W5

W6

W7

W8

W9

W10

W11

W12

W13

W14

W1538 of the total crude stream. It would stand that operating the treaters toward the higher end of their

operating range would ensure maximum reduction of th e light ends fractions of the crude oil with

current equipment . Because of this, the NDPC recommends that operators run their treaters at the

highest feasible operational temperature that allows for safe and consistent operation, to help minimize

these components in the crude. This recognizes the limits of both treater design and the limits set forth

for the safe storage of crude in sto ck tanks, which have upper bounds on crude storage temperature.

The impact of stock tanks for crude storage versus being connected to a gathering system on vapor

pressure was also considered. Stock tanks hold produced crude and sit for a short time before being

pumped out. In the case of this study, the duration between a filled stock tank and sample collection

was as much as a day and a half. Because of this, there is a small opportunity for light ends to weather

off. The comparison showed there was no appreciable trend between samples collected from wells on a

gathering system versus those that used a stock tank and were isolated from the well before collection.

Figure 17 shows the data for this comparison, plotted for those wells with which we had distinct

information on their configuration. This is expected, as tanks are designed to minimize evaporative

emissions ; so significant changes in vapo r pressure would indicate the possibility of high tank emissions.

Figure 17 : Vapor Pressure versus Well Production Rate



### Overview of Sampling, Analytical Methods and Quality Control/Quality Assurance

Sampling

All samples were obta ined at both the well and rail facilities by trained SGS personnel, based out of

Williston, ND, following accepted industry practices for collection of crude oil samples. Sampling

procedures in API Chapter 8.1 “Manual Sampling of Petroleum and Petroleum P roducts” formed the

basis for their sampling methodology. SGS has also written in

- house sampling procedures that

supplement the API document, as part of their standard operating procedures. 8 9 10 11 12 13 14 15

0 200 400 600 800 1000Vapor Pressure (psi)

Prod. Rate (bbl/day) W1

W2

W3

- Gathering Sys

W4

W5

W6

- Tank

W7

- Gathering Sys

W8

- Gathering Sys

W9

- Tank

W10

- Gathering Sys

W11

- Tank

W12

- Gathering Sys

W13

W14

W15

- Tank39 The crude oil sample s were collected in chilled one

- quart glass bottles, immediately sealed, chilled, and

transported to the Williston lab. This is very similar to sampling procedures used for finished gasoline,

which has a RVP of up to 15 psi. All analyses in Williston were conducted within a few days of receipt.

As discussed before, on the first visit to each site, individual “top” and “bottom” level samples were

obtained and analyzed. This was conducted to evaluate tank stratification. On subsequent visits to each

site, “average” tank samples were collected.

On samples obtained from the last two visits to each site, the D7169 simulated distillation analysis was

excluded. Results from this test were showing good consistency

, and the continued a nalysis was adding

little to the understanding of the light end s port ion of the crude oil.

Analytical Methods and Quality Control/Quality Assurance

SGS, the primary contact lab utilized for the collection and analyses of the Bakken crude oil well and rail

loading facility samples, is ISO 9001 certified at the corporate le vel. The St. Rose, LA lab, used to

conduct the more sophisticated light ends and D7169 gas chromatographic simulated distillation

analyses, is fully certified. The more recently acquired Williston, ND lab, used for the sample collection,

API gravity, fla sh point, IBP by D86, and vapor pressure by D6377 analyses, is in the process of obtaining

ISO 9001 certification.

ISO 9001:2008 is based on eight quality management principles:

**•** Customer focus ;

**•** Leadership ;

**•** Involvement of people ;

**•** Process approach ;

**•** System approach ;

**•** Continual improvement ;

**•** Fact

- based decision making ; and

**•** Mutually beneficial supplier relationships

.

SGS follows standard ASTM methods. They ensure use of the most current standards by subscription to

Tracker Alert biweekly

, which provides prompt update notification. The updates are stored

electronically for analyst referral at both labs.

Corporately, approximately 50 of the SGS labs participate in the ASTM Crude Oil Proficiency Program.

This program, commonly referred to as a “round

- robin” progr am

, involves ASTM periodically preparing

and supplying identical crude oil samples to labs all over the world. The labs then conduct their analyses

and submit their results to ASTM. ASTM compiles the results and publishes the data, using lab code

numbers to protect the identity of the labs. Each lab receives their own code number so they know

their performance and how their results compare to the other participating labs , but do not know the

identity of other participants. Programs such as this are vita l for laboratories to evaluate their

performance, take corrective action, and continually improve.40 Specific QA/QC procedures for each of the analytical methods are described below

.

**•** API Gravity by ASTM D5002 “Standard Test Method for Density and Relative De nsity of Crude

Oils by Digital Density Meter”

- This method is specifically for the measurement of crude oils.

The instrumentation is calibrated with freshly distilled water as described in Section 10 of the

method.

**•** Flash Point by ASTM D3278 (Williston l ab) or ASTM D56 (St. Rose lab)

- Flash point measures the

tendency of the material to form a flammable mixture with air under controlled laboratory

conditions. Section §173.120 of Hazardous Material Regulations allows for the use of either

ASTM D56 or D382 8. Both D56 and D3278 are very similar. ASTM D56 is the “Standard Method

for Flash Point by Tag Closed Cup Tester

, ” while ASTM D3278 is “Standard Test Methods for

Flash Point of Liquids by Small Scale Closed

- Cup Apparatus

. ” Para

- Xylene is used as a

cali bration/check standard for this method

, and records were provided by SGS showing

acceptable results for this material.

In the case of f lash p oint, it was not necessary to determine the exact flash point, but only to

determine whether the value was above or below the critical value of 73°F, which distinguishes

between P G II and P G I II.

**•** IBP by ASTM D86 “Standard Test Method for Distillation of Petroleum Products at Atmospheric

Pressure”

- This method, originally approved by ASTM in 1921 is still utilized for certification of

petroleum products such as gasoline and diesel fuel. Temperature bias is determined using

reagent grade toluene as a standard

, as described in Section 9 of the method

. To verify the

temperature measurement, pure n

- hexadecane is used. SG S provided examples of the

instrument printouts for the analyses of both of these reference materials.

It should be noted that full boiling range crude oils are not within the scope of this method as

described in Section 1. Thus, various labs have employe d different conditions for the condenser

and receiver temperatures. These parameters were shown to have a significant impact on the

recorded IBP of whole crudes. However, these differences have only a minimal effect on the

analysis of the standard materi als. Thus, acceptable results on the standard materials do NOT

ensure correct IBPs on whole crude.

**•** Vapor Pressure of Crude Oil (VPCRx) by ASTM D6377 “Standard Test Method for Determination

of Vapor Pressure of Crude Oil: VPCRx (Expansion Method)”

- Thi s newer method (originally

published in 1999) has become the method of choice for vapor pressure measurements of

whole crude oils, and EPA recommended its use in a recent publication for determining storage

tank compliance. Section 11 of the method descri bes Quality Control Checks and indicates that

Pentane, 2,2

- Dimethylbutane, or 2,3

- Dimethylb utane may be used as acceptable reference

fluids. SGS uses 2,2

- Dimethylb utane, and provided results showing all values within the

acceptable limits of 10.58 psi

– 1 0.92 psi for this standard material.41 **•** Light Ends in Crude Oil by IP344

- 88 (2010) “Determination of light hydrocarbons in stabilized

crude oils

- Gas Chromatography method”

- This is an Institute of Petroleum (IP) method. IP is

the British equivalent of ASTM . This is an internal standard gas chromatography (GC) method.

No reference standard is used, but participation in the ASTM Crude Oil Proficiency program is

used to evaluate the accuracy of the results from this analysis.

**•** Boiling Range Distribution by AS TM D7169 “Standard Test Method for Boiling Point Distribution

of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High

Temperature Gas Chromatography”

- This newer method (originally published in 2005) is an

external standard approach to obtain distillation type data for full

- range crude oils. A reference

gas oil is used for determination of detector response and evaluation of boiling points. This

standard is run regularly. Blank runs are made to determine the baseline corr ection.

Documentation was also provided showing calibration information for balances and thermometers used

in various laboratory methods.Appendix 1: Additional Figures

Appendix 1

- Page 1 of 4 Figure 1

- 1 : Vapor Pressure versus Operating Pressure

Figure 1

- 2 : Ethane Liquid Vol

. % versus Operating Pressure 8 9 10 11 12 13 14 15

0 10 20 30 40 50 60 70 80 90Vapor Pressure (psi)

Operating Pressure (psig)

0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80

0 10 20 30 40 50 60 70 80 90Ethane (Liquid Vol. %)

Operating Pressure (psig)Appendix 1: Additional Figures

Appendix 1

- Page 2 of 4 Figure 1

- 3: Ethane Liquid Vol

. % versus Production Rate

Figure 1

- 4 : Propane Liquid Vol

. % versus Operating Pressure 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80

0 100 200 300 400 500 600 700 800Ethane (Liquid Vol. %)

Production Rate (b/d)

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

0 10 20 30 40 50 60 70 80 90Propane (Liquid Vol. %)

Operating Pressure (psig)Appendix 1: Additional Figures

Appendix 1

- Page 3 of 4 Figure 1

- 5: Propane Liquid Vol

. % versus Production Rate

Figure 1

- 6 : Ethane Liquid Vol

. % versus Operating Temperature: Correlation

Note: anomalous readings from W7 excluded to improve correlation. 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

0 100 200 300 400 500 600 700 800Propane (Liquid Vol. %)

Production Rate (b/d)

y =

- 0.0013x + 0.3568

R2 = 0.3387

0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45

0 20 40 60 80 100 120 140 160 180Ethane (Liquid Vol. %)

Operating Temp ( ° F)Appendix 1: Additional Figures

Appendix 1

- Page 4 of 4 Figure 1

- 7 : Propane Liquid Vol

. % versus Operating Temperature: Correlation

Note: anomalous readings from W7 excluded to improve correlation.

y =

- 0.0025x + 1.8414

R2 = 0.0467

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

0 20 40 60 80 100 120 140 160 180Propane (Liquid Vol. %)

Operating Temp ( ° F)Appendix2‐SummaryDataCount Min Avg Max StDev Count Min Avg Max StDev Count Min Avg Max StDevAmbientTemp(°F)108 10.033.865.0 13.7 37 10.028.747.0 9.8 71 11.036.565.0 14.7APIGravity152 36.741.046.3 2.2 49 39.241.744.0 1.3 103 36.740.646.3 2.4D86IBP(°F)152 91.999.5106.8 2.4 49 96.7100.3104.1 1.7 103 91.999.1106.8 2.6VaporPviaD6377(100°F,4:1V/L)(psi)152 8.9311.6914.37 0.97 49 9.5711.5212.85 0.80 103 8.9311.7714.37 1.04LightEndsviaIP344Count Min Avg Max StDev Count Min Avg Max StDev Count Min Avg Max StDevMethane152 0.000.000.01 0.00 27 0.000.000.01 0.00 79 0.000.000.01 0.00Ethane152 0.080.240.67 0.08 49 0.130.230.33 0.04 103 0.080.240.67 0.09Propane152 0.841.553.13 0.41 49 1.021.391.95 0.24 103 0.841.633.13 0.45Isobutane152 0.350.630.95 0.13 49 0.460.580.73 0.07 103 0.350.650.95 0.15n‐Butane152 2.003.034.55 0.56 49 2.172.753.51 0.33 103 2.003.164.55 0.60Neopentane150 0.000.010.01 0.00 49 0.000.010.01 0.00 101 0.000.010.01 0.00Isopentane152 1.101.491.93 0.20 49 1.171.421.69 0.11 103 1.101.521.93 0.23n‐Pentane152 2.072.843.70 0.38 49 2.122.723.33 0.23 103 2.072.903.70 0.43Cyclopentane152 0.170.220.30 0.03 49 0.170.210.25 0.02 103 0.170.230.30 0.03Hexanes152 4.986.337.64 0.56 49 5.466.336.96 0.32 103 4.986.347.64 0.64SimulatedDistillationviaD7169Count Min Avg Max StDev Count Min Avg Max StDev Count Min Avg Max StDevIBP111 <97<97<97 111 <97<97<97 111 <97<97<975%*111 97108151 17 21 98113151 17 28 97106150 1810%*111 103157188 17 35 143165186 10 71 103153188 1920%111 180234278 20 35 216238264 11 76 180231278 2330%111 244312375 25 35 289316346 12 76 244310375 2940%111 327395476 29 35 364396436 15 76 327394476 3450%111 412481578 33 35 443482527 17 76 412481578 3860%111 508572684 35 35 527572623 19 76 508572684 4170%111 611671796 39 35 620670730 23 76 611671796 4580%111 718786920 42 35 733787850 25 76 718785920 4890%111 8609361069 43 35 8889391012 30 76 8609351069 4895%111 96610561192 52 35 100010601180 44 76 96610531192 55FBP*111 118613091362 44 21 121713171342 40 51 118613051362 45Recovery(weight%)111 95.799.3100.0 1.1 35 95.999.3100.0 1.1 76 95.799.4100.0 1.1Rawdatacanbeseenintheothersheetsforreference.WellRailTotal*Itemswithastrickswereadjustedaverages,toaccountforoneormorevaluesthatwereaboveorbelowdetectionlimits(97°Fand1382°F,respectively).Thoseitemswereadjustedbyaveragingthedetectionlimitforthosevalues,andthustheaveragesmaybeslightlyaboveorbelowtheactualvalue.Appendix2‐Page1of1Appendix3‐SampleConditions‐RailLocationsClientIDSampleDate SampleTimeAmbientTemp(°F) SampleContainerTankSize(barrels)LevelHeightinTankSampleLocationR1 3/25/2014 17:20 32 GlassBottle 100,000 10ft TopR1 3/25/2014 17:00 32 GlassBottle 100,000 10ft BottomR1 3/27/2014 17:26 33 GlassBottle 100,000 10ft AllLevelsR1 3/31/2014 14:08 19 GlassBottle 100,000 16ft2in AllLevelsR1 4/9/2014 10:38 GlassBottle 100,000 AllLevelsR1 4/16/2014 15:30 GlassBottle 100,000 AllLevelsR1 4/18/2014 11:00 GlassBottle 100,000 AllLevelsR2 3/25/2014 18:00 20 GlassBottle 250,000 TopR2 3/25/2014 18:00 20 GlassBottle 250,000 BottomR2 3/27/2014 10:30 25 GlassBottle 250,000 AllLevelsR2 3/31/2014 12:30 13 GlassBottle 250,000 46ft9in AllLevelsR2 4/8/2014 10:20 45 GlassBottle 250,000 43ft AllLevelsR2 4/15/2014 11:30 GlassBottle 250,000 39ft6in AllLevelsR2 4/18/2014 10:20 34 GlassBottle 250,000 34ft AllLevelsR3 3/26/2014 14:30 29 GlassBottle 50ft 41ft TopR3 3/26/2014 14:30 29 GlassBottle 50ft 41ft BottomR3 3/28/2014 13:30 32 GlassBottle 50ft 42ft AllLevelsR3 4/1/2014 16:10 17 GlassBottle 50ft 33ft AllLevelsR3 4/10/2014 14:50 GlassBottle 50ft AllLevelsR3 4/15/2014 14:15 46 GlassBottle 50ft 42ft AllLevelsR3 4/17/2014 13:00 32 GlassBottle 50ft 42ft AllLevelsR4 3/25/2014 14:30 20 GlassBottle 250,000 23ft TopR4 3/25/2014 14:30 20 GlassBottle 250,000 23ft BottomR4 3/27/2014 11:50 19 GlassBottle 250,000 18ft AllLevelsR4 3/31/2014 11:20 10 GlassBottle 250,000 17ft AllLevelsR4 4/7/2014 13:45 47 GlassBottle 250,000 18ft AllLevelsR4 4/16/2014 12:35 GlassBottle 250,000 AllLevelsR4 4/18/2014 12:05 37 GlassBottle 250,000 23ft AllLevelsAppendix3‐Page1of2Appendix3‐SampleConditions‐RailLocationsClientIDSampleDate SampleTimeAmbientTemp(°F) SampleContainerTankSize(barrels)LevelHeightinTankSampleLocationR5 3/26/2014 12:00 36 GlassBottle 45ft 39ft TopR5 3/26/2014 12:00 36 GlassBottle 45ft 39ft BottomR5 3/28/2014 12:00 32 GlassBottle 45ft 32ft AllLevelsR5 4/1/2014 14:30 15 GlassBottle 45ft 39ft AllLevelsR5 4/10/2014 13:15 GlassBottle 45ft AllLevelsR5 4/15/2014 12:50 44 GlassBottle 45ft 40ft AllLevelsR5 4/17/2014 11:40 32 GlassBottle 45ft 28ft AllLevelsR6 3/26/2014 15:30 29 GlassBottle 250,000 TopR6 3/26/2014 15:30 29 GlassBottle 250,000 BottomR6 3/27/2014 15:30 33 GlassBottle 250,000 AllLevelsR6 3/31/2014 14:00 13 GlassBottle 250,000 27ft4in AllLevelsR6 4/7/2014 15:00 GlassBottle 250,000 AllLevelsR6 4/15/2014 14:00 GlassBottle 250,000 34ft6in AllLevelsR6 4/17/2014 12:00 GlassBottle 250,000 38ft6in AllLevelsR7 3/26/2014 19:30 28 GlassBottle 250,000 40ft TopR7 3/26/2014 19:30 28 GlassBottle 250,000 40ft BottomR7 3/28/2014 13:00 46 GlassBottle 250,000 42ft AllLevelsR7 3/31/2014 17:00 22 GlassBottle 250,000 35ft6in AllLevelsR7 4/11/2014 10:50 GlassBottle 250,000 AllLevelsR7 4/14/2014 12:30 27 GlassBottle 250,000 40ft AllLevelsR7 4/18/2014 10:00 GlassBottle 250,000 33ft AllLevelsAppendix3‐Page2of2Appendix4‐SampleConditions‐WellClientID SampleDate SampleTime AmbientTemp(°F) SampleContainer TankSize(barrels) LevelHeightinTankSampleLocationW1 3/25/2014 19:45 18 GlassBottle 400 15ft TopW1 3/25/2014 19:45 18 GlassBottle 400 15ft BottomW1 3/27/2014 18:15 26 GlassBottle 400 15ft AllLevelsW1 3/30/2014 16:00 39 GlassBottle 400 15ft AllLevelsW1 4/1/2014 11:00 GlassBottle 400 AllLevelsW1 4/7/2014 12:20 31 GlassBottle 400 18ft AllLevelsW1 4/16/2014 11:30 GlassBottle 400 14ft AllLevelsW2 3/26/2014 12:45 30 GlassBottle 400 14ft TopW2 3/26/2014 12:45 30 GlassBottle 400 14ft BottomW2 3/29/2014 15:00 52 GlassBottle 400 10ft AllLevelsW2 3/31/2014 10:00 12 GlassBottle 400 15ft AllLevelsW2 4/7/2014 13:05 51 GlassBottle 400 16ft AllLevelsW2 4/16/2014 12:00 GlassBottle 400 AllLevelsW2 4/19/2014 9:00 GlassBottle 400 AllLevelsW3 3/25/2014 12:30 15 GlassBottle 400 10ft TopW3 3/25/2014 12:30 15 GlassBottle 400 10ft BottomW3 3/27/2014 10:00 24 GlassBottle 400 10ft AllLevelsW3 3/31/2014 10:00 11 GlassBottle 400 10ft AllLevelsW3 4/7/2014 12:50 42 GlassBottle 400 12ft AllLevelsW3 4/16/2014 10:30 GlassBottle 400 12ft AllLevelsW3 4/18/2014 11:20 37 GlassBottle 400 10ft AllLevelsW4 3/26/2014 12:00 30 GlassBottle 400 6ft TopW4 3/26/2014 12:00 30 GlassBottle 400 6ft BottomW4 3/28/2014 13:15 23 GlassBottle 400 5ft9in AllLevelsW4 4/3/2014 17:25 37 GlassBottle 400 9ft AllLevelsW4 4/7/2014 18:14 49 GlassBottle 400 10ft6in AllLevelsW4 4/15/2014 16:00 GlassBottle 400 7ft7in AllLevelsW4 4/17/2014 14:30 GlassBottle 400 7ft2in AllLevelsAppendix4‐Page1of4Appendix4‐SampleConditions‐WellClientID SampleDate SampleTime AmbientTemp(°F) SampleContainer TankSize(barrels) LevelHeightinTankSampleLocationW5 3/26/2014 15:50 30 GlassBottle 400 5ft6in TopW5 3/26/2014 15:50 30 GlassBottle 400 5ft6in BottomW5 3/28/2014 13:50 23 GlassBottle 400 5ft AllLevelsW5 4/4/2014 17:28 39 GlassBottle 400 3ft AllLevelsW5 4/7/2014 19:08 46 GlassBottle 400 6ft AllLevelsW5 4/15/2014 17:00 48 GlassBottle 400 13ft3in AllLevelsW5 4/17/2014 15:30 46 GlassBottle 400 7ft7in AllLevelsW6 4/6/2014 14:55 58 GlassBottle 400 12ft10.5in TopW6 4/6/2014 14:55 58 GlassBottle 400 12ft10.5in BottomW6 4/8/2014 13:50 70 GlassBottle 400 14ft7in AllLevelsW6 4/15/2014 17:05 49 GlassBottle 400 16ft5.5in AllLevelsW6 4/17/2014 14:05 39 GlassBottle 400 14ft7.75in AllLevelsW6 4/21/2014 16:30 63 GlassBottle 400 13ft9in AllLevelsW6 4/24/2014 11:20 48 GlassBottle 400 13ft6in AllLevelsW7 3/25/2014 17:00 28 GlassBottle 400 18ft TopW7 3/25/2014 17:00 28 GlassBottle 400 18ft BottomW7 3/27/2014 13:00 25 GlassBottle 400 16ft AllLevelsW7 3/31/2014 13:00 16 GlassBottle 400 15ft AllLevelsW7 4/7/2014 16:00 47 GlassBottle 400 19ft AllLevelsW7 4/16/2014 14:20 GlassBottle 400 7ft AllLevelsW7 4/21/2014 13:45 65 GlassBottle 400 18ft AllLevelsW8 3/25/2014 14:53 27 GlassBottle 400 13ft TopW8 3/25/2014 14:33 27 GlassBottle 400 13ft BottomW8 3/27/2014 15:30 32 GlassBottle 400 7ft AllLevelsW8 3/31/2014 12:42 15 GlassBottle 400 10ft AllLevelsW8 4/9/2014 12:30 65 GlassBottle 400 8ft AllLevelsW8 4/16/2014 17:00 GlassBottle 400 8ft3in AllLevelsW8 4/18/2014 13:00 GlassBottle 400 9ft AllLevelsAppendix4‐Page2of4Appendix4‐SampleConditions‐WellClientID SampleDate SampleTime AmbientTemp(°F) SampleContainer TankSize(barrels) LevelHeightinTankSampleLocationW9 4/1/2014 11:20 13 GlassBottle 400 13ft6in TopW9 4/1/2014 12:10 13 GlassBottle 400 13ft6in BottomW9 4/3/2014 13:00 25 GlassBottle 400 13ft AllLevelsW9 4/8/2014 11:25 45 GlassBottle 400 6ft11in AllLevelsW9 4/15/2014 12:33 43 GlassBottle 400 15ft AllLevelsW9 4/22/2014 11:35 63 GlassBottle 400 12ft1in AllLevelsW9 4/24/2014 14:20 53 GlassBottle 400 18ft AllLevelsW10 4/15/2014 15:40 48 GlassBottle 400 4ft TopW10 4/15/2014 15:40 48 GlassBottle 400 4ft BottomW10 4/17/2014 12:50 37 GlassBottle 400 4ft AllLevelsW10 4/21/2014 15:30 58 GlassBottle 400 AllLevelsW10 4/24/2014 12:35 50 GlassBottle 400 8ft AllLevelsW10 4/29/2014 11:00 32 GlassBottle 400 10ft AllLevelsW11 4/7/2014 16:35 50 GlassBottle 400 19ft TopW11 4/7/2014 16:35 50 GlassBottle 400 19ft BottomW11 4/11/2014 14:55 55 GlassBottle 400 19ft AllLevelsW11 4/15/2014 15:00 GlassBottle 400 16ft4in AllLevelsW11 4/17/2014 13:30 GlassBottle 400 12ft2in AllLevelsW11 4/20/2014 11:00 GlassBottle 400 17ft2in AllLevelsW11 4/23/2014 13:00 GlassBottle 400 16ft4in AllLevelsW12 3/27/2014 12:46 27 GlassBottle 400 12ft TopW12 3/27/2014 12:16 27 GlassBottle 400 12ft BottomW12 3/30/2014 13:00 42 GlassBottle 400 18ft AllLevelsW12 4/1/2014 13:40 15 GlassBottle 400 14ft AllLevelsW12 4/8/2014 13:20 59 GlassBottle 400 10ft AllLevelsW12 4/17/2014 15:10 43 GlassBottle 400 13ft AllLevelsW12 4/17/2014 15:30 35 GlassBottle 400 8ft AllLevelsAppendix4‐Page3of4Appendix4‐SampleConditions‐WellClientID SampleDate SampleTime AmbientTemp(°F) SampleContainer TankSize(barrels) LevelHeightinTankSampleLocationW13 3/26/2014 17:00 31 GlassBottle400 11ft TopW13 3/26/2014 17:00 31 GlassBottle400 11ft BottomW13 3/28/2014 15:30 25 GlassBottle400 6ft AllLevelsW13 4/4/2014 15:15 39 GlassBottle 400 6ft AllLevelsW13 4/8/2014 11:00 46 GlassBottle 400 16ft AllLevelsW13 4/15/2014 19:30 GlassBottle 400 AllLevelsW13 4/19/2014 14:00 GlassBottle 400 AllLevelsW14 4/6/2014 16:20 GlassBottle 400 TopW14 4/6/2014 16:20 GlassBottle 400 BottomW14 4/4/2014 11:55 34 GlassBottle 400 2ft6in AllLevelsW14 4/8/2014 12:30 50 GlassBottle 400 6ft AllLevelsW14 4/18/2014 16:30 GlassBottle 400 AllLevelsW14 4/20/2014 14:00 GlassBottle 400 AllLevelsW14 4/22/2014 11:00 GlassBottle 400 AllLevelsW15 4/9/2014 17:20 GlassBottle 40,000bbl/50ft 30ft6in TopW15 4/9/2014 17:20 GlassBottle 40,000bbl/50ft 30ft6in BottomW15 4/18/2014 19:30 GlassBottle 40,000bbl/50ft 22ft9in AllLevelsW15 4/21/2014 18:30 GlassBottle 40,000bbl/50ft 36ft2in AllLevelsW15 4/23/2014 13:00 GlassBottle 40,000bbl/50ft 37ft4in AllLevelsW15 4/24/2014 16:30 57 GlassBottle 40,000bbl/50ft 32ft9in AllLevelsAppendix4‐Page4of4Appendix5‐OperationalConditions‐WellOnlyClientID SampleDate SampleTimeTankVaporCapture‐FlareStackorVRUProductionRatesfromProducer(b/d)LastMovementfromTank(DateandTime) SeparatorSizeSeparatorOperatingPressure(psig)SeparatorOperatingTemp(°F)Treater/EmulsionHeaterSizeTreater/EmulsionHeaterOperatingPressure(psig)Treater/EmulsionHeaterOperatingTemp(°F)Treater/EmulsionHeaterOilLineDia(inches)Treater/EmulsionHeaterOilDumpValveSize/Style AdditionalFieldInfoW1 3/25/14 19:4546 92 TreaterW1 3/25/14 19:4546 92 TreaterW1 3/27/14 18:1548 92 TreaterW1 3/30/14 16:0031 92 TreaterW1 4/1/14 11:00W1 4/7/14 12:2031 92W1 4/16/14 11:30W2 3/26/14 12:4520 46 TreaterW2 3/26/14 12:4520 46 TreaterW2 3/29/14 15:0019 90 TreaterW2 3/31/14 10:0055 92 TreaterW2 4/7/14 13:0544 54 TreaterW2 4/16/14 12:00W2 4/19/14 9:00W3 3/25/14 12:30 110 N/A 6'x20' 30 35 3" 3"KimrayW3 3/25/14 12:30 110 N/A 6'x20' 30 35 3" 3"KimrayW3 3/27/14 10:00 90 N/A 6'x20' 42 38 3" 3"KimrayW3 3/31/14 10:00 100 N/A 6'x20' 38 36 3" 3"KimrayW3 4/7/14 12:50 110 N/A 6'x20' 36 44 3" 3"KimrayW3 4/16/14 10:30 90 N/A 6'x20' 44 36 3" 3"KimrayW3 4/18/14 11:20 90 N/A 6'x20' 8 42 3" 3"KimrayW4 3/26/14 12:00 FlareStack 305 N/A N/A N/A 6'x22' 48 135 3" 3"GasOperated OnGatheringSystemW4 3/26/14 12:00 FlareStack 305 N/A N/A N/A 6'x22' 48 135 3" 3"GasOperated OnGatheringSystemW4 3/28/14 13:15 FlareStack 337 N/A N/A N/A 6'x22' 50 140 3" 3"GasOperated OnGatheringSystemW4 4/3/14 17:25 FlareStack 280 N/A N/A N/A 6'x22' 54 145 3" 3"GasOperated OnGatheringSystemW4 4/7/14 18:14 FlareStack 320 N/A N/A N/A 6'x22' 12 142 3" 3"GasOperated OnGatheringSystemW4 4/15/14 16:00 FlareStack 220 N/A N/A N/A 6'x22' 52 140 3" 3"GasOperated OnGatheringSystemW4 4/17/14 14:30 FlareStack 326 N/A N/A N/A 6'x22' 40 80 3" 3"GasOperated OnGatheringSystemW5 3/26/14 15:50 Both(Stack/VRU) 449 N/A N/A N/A 6'x22' 40 84 3" 3"GasOperated OnGatheringSystemW5 3/26/14 15:50 Both(Stack/VRU) 449 N/A N/A N/A 6'x22' 40 84 3" 3"GasOperated OnGatheringSystemW5 3/28/14 13:50 Both(Stack/VRU) 404 N/A N/A N/A 6'x22' 40 140 3" 3"GasOperated OnGatheringSystemW5 4/4/14 17:28 Both(Stack/VRU) 294 N/A N/A N/A 6'x22' 51 162 3" 3"GasOperated OnGatheringSystemW5 4/7/14 19:08 Both(Stack/VRU) 441 N/A N/A N/A 6'x22' 53 138 3" 3"GasOperated OnGatheringSystemW5 4/15/14 17:00 Both(Stack/VRU) 526 N/A N/A N/A 6'x22' 45 90 3" 3"GasOperated OnGatheringSystemW5 4/17/14 15:30 Both(Stack/VRU) 398 N/A N/A N/A 6'x22' 50 140 3" 3"GasOperated OnGatheringSystemW6 4/6/14 14:55 100 4/5/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW6 4/6/14 14:55 100 4/5/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW6 4/8/14 13:50 100 4/7/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW6 4/15/14 17:05 100 4/14/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW6 4/17/14 14:05 100 4/16/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW6 4/21/14 16:30 100 4/20/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW6 4/24/14 11:20 100 4/23/1411:00 30"x10' 80 6'x20' 30 3" 3"SteelW7 3/25/14 17:00 FlareStack 143 N/A 30"x10' 6'x20' 26 120 3" 3"floatoperatedW7 3/25/14 17:00 FlareStack 143 N/A 30"x10' 6'x20' 26 120 3" 3"floatoperatedW7 3/27/14 13:00 FlareStack 161 N/A 30"x10' 6'x20' 26 123 3" 3"floatoperatedW7 3/31/14 13:00 FlareStack 125 N/A 30"x10' 6'x20' 28 38 3" 3"floatoperatedW7 4/7/14 16:00 FlareStack 150 N/A 30"x10' 6'x20' 28 65 3" 3"floatoperatedW7 4/16/14 14:20 FlareStack 125 N/A 30"x10' 6'x20' 28 65 3" 3"floatoperatedW7 4/21/14 13:45 FlareStack 164 N/A 30"x10' 6'x20' 28 70 3" 3"floatoperatedAppendix5‐Page1of2Appendix5‐OperationalConditions‐WellOnlyClientID SampleDate SampleTimeTankVaporCapture‐FlareStackorVRUProductionRatesfromProducer(b/d)LastMovementfromTank(DateandTime) SeparatorSizeSeparatorOperatingPressure(psig)SeparatorOperatingTemp(°F)Treater/EmulsionHeaterSizeTreater/EmulsionHeaterOperatingPressure(psig)Treater/EmulsionHeaterOperatingTemp(°F)Treater/EmulsionHeaterOilLineDia(inches)Treater/EmulsionHeaterOilDumpValveSize/Style AdditionalFieldInfoW8 3/25/14 14:33 FlareStack 7 N/A 30"x10' 6'x20' 22 154 3" 3"floatoperatedW8 3/27/14 15:30 FlareStack 4 N/A 30"x10' 6'x20' 27 156 3" 3"floatoperatedW8 3/31/14 12:42 FlareStack 6 N/A 30"x10' 6'x20' 22 146 3" 3"floatoperatedW8 4/9/14 12:30 FlareStack 5 N/A 30"x10' 6'x20' 22 160 3" 3"floatoperatedW8 4/16/14 17:00 FlareStack 4 N/A 30"x10' 6'x20' 22 70 3" 3"floatoperatedW8 4/18/14 13:00 FlareStack 7 N/A 30"x10' 6'x20' 22 55 3" 3"floatoperatedW9 4/1/14 11:20 FlareStack 528 3/31/148:30 6'x20' 68 109 D3 Sunny,StillweatherW9 4/1/14 12:10 FlareStack 528 3/31/148:30 6'x20' 68 109 D3 Sunny,StillweatherW9 4/3/14 13:00 FlareStack 508 4/3/1410:20 6'x20' 68 110 D3 WindyandCloudyW9 4/8/14 11:25 FlareStack 360 NoteIndicatesN/A 6'x20' 68 110 D3 PartiallyCloudyW9 4/15/14 12:33 FlareStack 580 4/14/1412:33 6'x20' 41 108 D3 PartiallyCloudyandwindyW9 4/22/14 11:35 FlareStack 678 4/21/140:00 6'x20' 45 108 D3 Sunny20‐25mphwindsW9 4/24/14 14:20 FlareStack 770 4/24/149:05 6'x20' 45 100 D3 SunnyW10 4/15/14 15:40 150 N/A(Comingled) 6'x20' 35 37Observed:0.05%BS&WW10 4/15/14 15:40 150 N/A(Comingled) 6'x20' 35 37Observed:0.05%BS&WW10 4/17/14 12:50 150 N/A(Comingled) 35 37 6'x20' 35 37W10 4/21/14 15:30 150 N/A(Comingled) 42 44 6'x20' 42 44W10 4/24/14 12:35 150 N/A(Comingled) 24 38 6'x20' 24 38W10 4/29/14 11:00 150 N/A(Comingled) 6'x20' 5 39W11 4/7/14 16:35 FlareStack 180 4/7/1416:35 30"x10' 36 6'x22' 60 120 3" 3"Observed:36APIat75F,0.05%BS&WW11 4/7/14 16:35 FlareStack 180 4/7/1416:35 30"x10' 36 6'x22' 60 120 3" 3"Observed:36APIat75F,0.05%BS&WW11 4/11/14 14:55 FlareStack 180 4/11/1414:55 30"x10' 36 6'x22' 60 120 3" 3"Observed:32APIat76F,0.05%BS&WW11 4/15/14 15:00 FlareStack 180 4/15/1415:00 30"x10' 36 6'x22' 60 120 3" 3"Observed:34APIat72F,0.05%BS&WW11 4/17/14 13:30 FlareStack 180 4/17/1413:30 30"x10' 36 6'x22' 60 120 3" 3"Observed:34APIat73F,0.05%BS&WW11 4/20/14 11:00 FlareStack 180 4/20/1411:00 30"x10' 36 6'x22' 3" 3"Observed:36APIat73F,0.05%BS&WW11 4/23/14 13:00 FlareStack 180 4/23/1415:30 30"x10' 36 6'x22' 60 120 3" 3"Observed:36APIat75F,0.05%BS&WW12 3/27/14 12:46 FlareStack 132 N/A 30"x10' 6'x20' 40 115 3" 3"floatoperatedW12 3/27/14 12:16 FlareStack 132 N/A 30"x10' 6'x20' 40 115 3" 3"floatoperatedW12 3/30/14 13:00 FlareStack 160 N/A 30"x10' 6'x20' 50 125 3" 3"floatoperatedW12 4/1/14 13:40 FlareStack 135 N/A 30"x10' 6'x20' 28 117 3" 3"floatoperatedW12 4/8/14 13:20 FlareStack 135 N/A 30"x10' 6'x20' 49 115 3" 3"floatoperatedW12 4/17/14 15:10 FlareStack 138 N/A 30"x10' 6'x20' 30 110 3" 3"floatoperatedW12 4/17/14 15:30 FlareStack 138 N/A 30"x10' 6'x20' 30 65 3" 3"floatoperatedW13 3/26/14 17:00 75 80bbl 35 500,000btu/hr 35 92 3" 3"Kimray Observed42.3APIat60FW13 3/26/14 17:00 75 80bbl 35 500,000btu/hr 35 92 3" 3"Kimray Observed42.3APIat60FW13 3/28/14 15:30 75 80bbl 35 500,000btu/hr 35 90 3" 3"Kimray Observed42.3APIat60FW13 4/4/14 15:15 75 80bbl 35 500,000btu/hr 35 94 3" 3"Kimray Observed42.3APIat60FW13 4/8/14 11:00 75 80bbl 35 500,000btu/hr 36 90 3" 3"Kimray Observed42.3APIat60FW13 4/15/14 19:30 75 80bbl 35 500,000btu/hr 3" 3"Kimray Observed42.3APIat60FW13 4/19/14 14:00 75 80bbl 35 500,000btu/hr 3" 3"Kimray Observed42.3APIat60FW14 4/6/14 16:20W14 4/6/14 16:20W14 4/4/14 11:5530 90 30 90W14 4/8/14 12:3062 79 62 79W14 4/18/14 16:30W14 4/20/14 14:00W14 4/22/14 11:0047 114 47 114W15 4/9/14 17:20 4/9/1417:20Observed43APIW15 4/9/14 17:20 4/9/1417:20Observed43APIW15 4/18/14 19:30 4/18/1419:30Observed43APIW15 4/21/14 18:30 4/21/1418:30Observed43APIW15 4/23/14 13:00 4/23/1413:00Observed43APIW15 4/24/14 16:30 4/24/1416:30Observed43APIAppendix5‐Page2of2Appendix6‐LabData‐RailClientID SampleDate SampleTime APIGravity D86IBP(°F)VaporPviaD6377(100°F,4:1V/L)(psi)VaporPviaD6377(100°F,4:1V/L)(kPa)FlashPointD3278(°F)R1 3/25/2014 17:20 39.6 100.5 9.73 67.1 <73R1 3/25/2014 17:00 39.5 102.9 9.96 68.7 <73R1 3/27/2014 17:26 39.7 103.9 9.67 66.7 <73R1 3/31/2014 14:08 42.8 100.5 11.31 78.0 <73R1 4/9/2014 10:38 41.6 100.8 11.76 81.1 <73R1 4/16/2014 15:30 42.1 98.4 11.85 81.7 <73R1 4/18/2014 11:00 41.4 99.9 12.33 85.0 <73R2 3/25/2014 18:00 43.4 99.9 11.73 80.9 <73R2 3/25/2014 18:00 42.8 100.7 11.68 80.5 <73R2 3/27/2014 10:30 43.8 99.5 12.39 85.4 <73R2 3/31/2014 12:30 43.2 99.4 11.52 79.4 <73R2 4/8/2014 10:20 40.3 100.5 11.55 79.6 <73R2 4/15/2014 11:30 42.0 97.8 11.94 82.3 <73R2 4/18/2014 10:20 39.2 99.6 11.89 82.0 <73R3 3/26/2014 14:30 42.4 103.5 11.53 79.5 <73R3 3/26/2014 14:30 42.6 101.9 11.70 80.7 <73R3 3/28/2014 13:30 42.6 100.9 11.53 79.5 <73R3 4/1/2014 16:10 41.7 102.0 10.95 75.5 <73R3 4/10/2014 14:50 40.9 97.2 11.53 79.5 <73R3 4/15/2014 14:15 41.3 98.2 11.46 79.0 <73R3 4/17/2014 13:00 40.6 98.8 11.02 76.0 <73R4 3/25/2014 14:30 41.3 99.9 11.95 82.4 <73R4 3/25/2014 14:30 41.4 99.2 11.25 77.6 <73R4 3/27/2014 11:50 43.1 99.9 11.95 82.4 <73R4 3/31/2014 11:20 41.5 99.5 12.44 85.8 <73R4 4/7/2014 13:45 41.5 99.5 12.85 88.6 <73R4 4/16/2014 12:35 40.3 99.1 12.08 83.3 <73R4 4/18/2014 12:05 39.8 100.5 11.99 82.7 <73Appendix6‐Page1of2Appendix6‐LabData‐RailClientID SampleDate SampleTime APIGravity D86IBP(°F)VaporPviaD6377(100°F,4:1V/L)(psi)VaporPviaD6377(100°F,4:1V/L)(kPa)FlashPointD3278(°F)R5 3/26/2014 12:00 44.0 101.0 10.52 72.5 <73R5 3/26/2014 12:00 43.9 101.9 10.47 72.2 <73R5 3/28/2014 12:00 42.4 100.5 10.50 72.4 <73R5 4/1/2014 14:30 43.1 103.7 10.28 70.9 <73R5 4/10/2014 13:15 42.6 100.4 10.95 75.5 <73R5 4/15/2014 12:50 41.8 100.8 10.85 74.8 <73R5 4/17/2014 11:40 42.0 103.4 9.57 66.0 <73R6 3/26/2014 15:30 42.6 99.7 12.84 88.5 <73R6 3/26/2014 15:30 42.5 98.9 12.47 86.0 <73R6 3/27/2014 15:30 43.0 98.9 12.71 87.6 <73R6 3/31/2014 14:00 41.2 99.4 11.82 81.5 <73R6 4/7/2014 15:00 39.9 96.7 12.43 85.7 <73R6 4/15/2014 14:00 40.2 100.8 12.52 86.3 <73R6 4/17/2014 12:00 39.7 100.1 11.88 81.9 <73R7 3/26/2014 19:30 42.3 104.1 11.66 80.4 <73R7 3/26/2014 19:30 42.8 99.7 11.57 79.8 <73R7 3/28/2014 13:00 42.6 99.5 11.89 82.0 <73R7 3/31/2014 17:00 42.2 101.9 11.86 81.8 <73R7 4/11/2014 10:50 40.9 99.3 11.37 78.4 <73R7 4/14/2014 12:30 41.5 98.9 11.37 78.4 <73R7 4/18/2014 10:00 40.4 101.7 11.39 78.5 <73Appendix6‐Page2of2Appendix7‐LabData‐WellClientID SampleDate SampleTime APIGravity D86IBP(°F)VaporPviaD6377(100°F,4:1V/L)(psi)VaporPviaD6377(100°F,4:1V/L)(kPa)FlashPointD3278(°F)W1 3/25/2014 19:45 40.6 98.2 11.99 82.7 <73W1 3/25/2014 19:45 39.2 102.1 11.55 79.6 <73W1 3/27/2014 18:15 40.3 99.7 11.55 79.6 <73W1 3/30/2014 16:00 39.1 99.2 11.81 81.4 <73W1 4/1/2014 11:00 37.1 98.8 12.18 84 <73W1 4/7/2014 12:20 37.1 99.9 11.40 78.6 <73W1 4/16/2014 11:30 37.7 98.6 11.57 79.8 <73W2 3/26/2014 12:45 41.4 100.6 12.26 84.5 <73W2 3/26/2014 12:45 40.2 100.3 12.08 83.3 <73W2 3/29/2014 15:00 41.5 100.7 11.94 82.3 <73W2 3/31/2014 10:00 39.9 101.9 11.50 79.3 <73W2 4/7/2014 13:05 40.0 98.9 11.37 78.4 <73W2 4/16/2014 12:00 38.0 98.1 11.27 77.7 <73W2 4/19/2014 9:00 38.9 99.8 11.91 82.1 <73W3 3/25/2014 12:30 43.8 96.8 10.65 73.4 <73W3 3/25/2014 12:30 44.4 99.7 10.86 74.9 <73W3 3/27/2014 10:00 44.4 98.6 11.07 76.3 <73W3 3/31/2014 10:00 43.4 98.1 12.02 82.9 <73W3 4/7/2014 12:50 42.1 99.4 12.01 82.8 <73W3 4/16/2014 10:30 40.2 98.4 10.92 75.3 <73W3 4/18/2014 11:20 42.1 98.9 11.37 78.4 <73W4 3/26/2014 12:00 40.0 98.5 12.56 86.6 <73W4 3/26/2014 12:00 41.7 97.7 12.71 87.6 <73W4 3/28/2014 13:15 42.5 98.6 12.84 88.5 <73W4 4/3/2014 17:25 40.4 98.2 11.15 76.9 <73W4 4/7/2014 18:14 39.3 97.3 13.92 96 <73W4 4/15/2014 16:00 38.9 97.4 11.98 82.6 <73W4 4/17/2014 14:30 38.8 99.5 13.24 91.3 <73Appendix7‐Page1of4Appendix7‐LabData‐WellClientID SampleDate SampleTime APIGravity D86IBP(°F)VaporPviaD6377(100°F,4:1V/L)(psi)VaporPviaD6377(100°F,4:1V/L)(kPa)FlashPointD3278(°F)W5 3/26/2014 15:50 42.9 97.3 12.27 84.6 <73W5 3/26/2014 15:50 42.3 99.6 12.44 85.8 <73W5 3/28/2014 13:50 44.3 98.2 13.24 91.3 <73W5 4/4/2014 17:28 41.1 100.9 12.23 84.3 <73W5 4/7/2014 19:08 39.9 94.6 13.26 91.4 <73W5 4/15/2014 17:00 39.9 95.4 12.20 84.1 <73W5 4/17/2014 15:30 42.6 97.5 13.08 90.2 <73W6 4/6/2014 14:55 42.6 97.2 13.04 89.9 <73W6 4/6/2014 14:55 42.6 96.5 13.04 89.9 <73W6 4/8/2014 13:50 42.1 97.7 11.04 76.1 <73W6 4/15/2014 17:05 42.5 96.7 12.33 85 <73W6 4/17/2014 14:05 42.8 97.4 12.59 86.8 <73W6 4/21/2014 16:30 42.3 98.9 11.33 78.1 <73W6 4/24/2014 11:20 45.8 96.4 13.56 93.5 <73W7 3/25/2014 17:00 43.5 97.6 10.25 70.7 <73W7 3/25/2014 17:00 43.8 98.3 10.59 73 <73W7 3/27/2014 13:00 42.6 99.9 10.91 75.2 <73W7 3/31/2014 13:00 43.9 96.9 10.02 69.1 <73W7 4/7/2014 16:00 39.2 96.7 11.33 78.1 <73W7 4/16/2014 14:20 41.7 94.8 12.92 89.1 <73W7 4/21/2014 13:45 39.5 99 11.69 80.6 <73W8 3/25/2014 14:53 44.4 95 12.52 86.3 <73W8 3/25/2014 14:33 44.6 99.2 12.37 85.3 <73W8 3/27/2014 15:30 44.8 99 12.92 89.1 <73W8 3/31/2014 12:42 43.4 97.5 12.15 83.8 <73W8 4/9/2014 12:30 39.0 101.3 11.07 76.3 <73W8 4/16/2014 17:00 40.9 96.1 11.92 82.2 <73W8 4/18/2014 13:00 42.5 96.8 14.37 99.1 <73Appendix7‐Page2of4Appendix7‐LabData‐WellClientID SampleDate SampleTime APIGravity D86IBP(°F)VaporPviaD6377(100°F,4:1V/L)(psi)VaporPviaD6377(100°F,4:1V/L)(kPa)FlashPointD3278(°F)W9 4/1/2014 11:20 38.0 104.3 10.70 73.8 <73W9 4/1/2014 12:10 37.0 104 10.67 73.6 <73W9 4/3/2014 13:00 37.3 101.4 10.69 73.7 <73W9 4/8/2014 11:25 38.2 102 10.96 75.6 <73W9 4/15/2014 12:33 36.9 101.4 11.15 76.9 <73W9 4/22/2014 11:35 36.7 105.4 10.15 70 <73W9 4/24/2014 14:20 38.9 91.9 9.95 68.6 <73W10 4/15/2014 15:40 42.7 95 13.02 89.8 <73W10 4/15/2014 15:40 42.8 95.4 12.75 87.9 <73W10 4/17/2014 12:50 43.5 97.3 12.02 82.9 <73W10 4/21/2014 15:30 46.3 95 13.46 92.8 <73W10 4/24/2014 12:35 44.7 95.3 13.01 89.7 <73W10 45.5 95.8 13.58 93.6 <73W11 4/7/2014 16:35 38.6 96 10.41 71.8 <73W11 4/7/2014 16:35 38.2 97.3 11.02 76 <73W11 4/11/2014 14:55 41.8 95.7 13.29 91.6 <73W11 4/15/2014 15:00 38.4 98.1 11.43 78.8 <73W11 4/17/2014 13:30 39.3 99.4 12.07 83.2 <73W11 4/20/2014 11:00 37.0 104.5 9.96 68.7 <73W11 4/23/2014 38.9 98.3 12.13 83.6 <73W12 3/27/2014 12:46 38.8 100.1 10.99 75.8 <73W12 3/27/2014 12:16 38.2 101.3 10.94 75.4 <73W12 3/30/2014 13:00 38.7 101.9 10.47 72.2 <73W12 4/1/2014 13:40 38.1 102.2 10.81 74.5 <73W12 4/8/2014 13:20 37.7 98.9 10.50 72.4 <73W12 4/17/2014 15:10 37.9 101.8 9.95 68.6 <73W12 4/17/2014 15:30 37.9 100.7 10.59 73 <73Appendix7‐Page3of4Appendix7‐LabData‐WellClientID SampleDate SampleTime APIGravity D86IBP(°F)VaporPviaD6377(100°F,4:1V/L)(psi)VaporPviaD6377(100°F,4:1V/L)(kPa)FlashPointD3278(°F)W13 3/26/2014 17:00 42.5 100.4 12.71 87.6 <73W13 3/26/2014 17:00 41.4 99.9 12.60 86.9 <73W13 3/28/2014 15:30 40.6 100.7 12.27 84.6 <73W13 4/4/2014 15:15 42.7 99.4 12.75 87.9 <73W13 4/8/2014 11:00 38.5 98.9 11.57 79.8 <73W13 4/15/2014 19:30 39.3 98.3 12.56 86.6 <73W13 4/19/2014 14:00 39.7 99 12.81 88.3 <73W14 4/6/2014 16:20 37.4 99.8 11.47 79.1 <73W14 4/6/2014 16:20 38.1 98.3 11.31 78 <73W14 4/4/2014 11:55 38.5 103.1 11.76 81.1 <73W14 4/8/2014 12:30 37.4 100.7 11.46 79 <73W14 4/18/2014 16:30 38.9 100.2 10.96 75.6 <73W14 4/20/2014 14:00 37.1 105.3 9.35 64.5 <73W14 4/22/2014 11:00 37.5 106.8 8.93 61.6 <73W15 4/9/2014 17:20 40.1 100 11.75 81 <73W15 4/9/2014 17:20 39.9 101.3 11.44 78.9 <73W15 4/18/2014 19:30 40.9 101.8 12.84 88.5 <73W15 4/21/2014 18:30 40.4 103.2 12.59 86.8 <73W15 4/23/2014 13:00 41.9 99.9 11.04 76.1 <73W15 4/24/2014 16:30 42.9 102.2 11.21 77.3 <73Appendix7‐Page4of4Appendix8‐LightEndsData‐RailClientID SampleDate SampleTime Methane Ethane Propane Isobutane n‐Butane Neopentane Isopentane n‐Pentane Cyclopentane HexanesR1 3/25/2014 17:20 <0.01 0.18 1.16 0.49 2.27 0.01 1.22 2.21 0.21 5.64R1 3/25/2014 17:00 <0.01 0.17 1.14 0.49 2.27 0.01 1.22 2.21 0.21 5.66R1 3/27/2014 17:26 0.00 0.18 1.10 0.46 2.17 0.00 1.17 2.12 0.20 5.46R1 3/31/2014 14:08 <0.01 0.25 1.46 0.62 2.73 0.01 1.46 2.67 0.21 6.48R1 4/9/2014 10:38 0.00 0.25 1.46 0.62 2.74 0.01 1.44 2.67 0.20 6.38R1 4/16/2014 15:30 0.01 0.23 1.35 0.60 2.78 0.01 1.59 2.84 0.21 6.68R1 4/18/2014 11:00 0.00 0.20 1.23 0.55 2.56 0.01 1.41 2.65 0.20 6.50R2 3/25/2014 18:00 <0.01 0.28 1.56 0.62 2.91 0.01 1.46 2.87 0.21 6.49R2 3/25/2014 18:00 <0.01 0.27 1.55 0.62 2.90 0.01 1.47 2.86 0.21 6.49R2 3/27/2014 10:30 <0.01 0.26 1.60 0.66 3.04 0.01 1.57 2.98 0.21 6.88R2 3/31/2014 12:30 0.01 0.26 1.45 0.59 2.75 0.01 1.44 2.74 0.21 6.56R2 4/8/2014 10:20 0.00 0.25 1.46 0.58 2.74 0.01 1.38 2.66 0.21 6.10R2 4/15/2014 11:30 0.00 0.18 1.16 0.52 2.58 0.01 1.41 2.79 0.21 6.60R2 4/18/2014 10:20 0.00 0.21 1.37 0.56 2.81 0.01 1.43 2.80 0.23 6.49R3 3/26/2014 14:30 <0.01 0.27 1.46 0.58 2.69 0.01 1.37 2.62 0.19 6.45R3 3/26/2014 14:30 <0.01 0.25 1.39 0.57 2.63 0.01 1.35 2.58 0.20 6.08R3 3/28/2014 13:30 0.01 0.28 1.44 0.58 2.68 0.01 1.36 2.62 0.19 6.13R3 4/1/2014 16:10 0.00 0.20 1.18 0.50 2.39 0.01 1.27 2.46 0.18 5.61R3 4/10/2014 14:50 0.00 0.21 1.20 0.52 2.46 0.01 1.33 2.55 0.19 6.19R3 4/15/2014 14:15 0.00 0.25 1.31 0.54 2.55 0.01 1.35 2.59 0.19 6.22R3 4/17/2014 13:00 0.01 0.24 1.35 0.58 2.77 0.01 1.49 2.88 0.22 6.96R4 3/25/2014 14:30 <0.01 0.33 1.95 0.73 3.43 0.01 1.60 3.13 0.22 6.60R4 3/25/2014 14:30 <0.01 0.32 1.92 0.73 3.42 0.01 1.60 3.13 0.22 6.62R4 3/27/2014 11:50 <0.01 0.28 1.62 0.64 3.04 0.01 1.48 2.93 0.22 6.46R4 3/31/2014 11:20 <0.01 0.27 1.81 0.73 3.51 0.01 1.69 3.33 0.24 6.52R4 4/7/2014 13:45 0.00 0.13 1.09 0.51 2.60 0.01 1.37 2.74 0.20 5.97R4 4/16/2014 12:35 0.00 0.22 1.44 0.60 2.89 0.01 1.49 2.97 0.21 6.69R4 4/18/2014 12:05 0.00 0.20 1.35 0.58 2.84 0.01 1.47 2.93 0.21 6.62R5 3/26/2014 12:00 <0.01 0.19 1.10 0.50 2.39 0.01 1.33 2.60 0.18 6.36R5 3/26/2014 12:00 <0.01 0.22 1.20 0.53 2.46 0.01 1.34 2.60 0.18 6.29R5 3/28/2014 12:00 <0.01 0.21 1.17 0.52 2.44 0.01 1.33 2.60 0.19 6.33R5 4/1/2014 14:30 0.01 0.18 1.04 0.47 2.25 0.01 1.25 2.42 0.17 5.69R5 4/10/2014 13:15 0.01 0.23 1.25 0.54 2.50 0.01 1.34 2.59 0.18 6.21R5 4/15/2014 12:50 0.01 0.20 1.13 0.51 2.43 0.01 1.35 2.62 0.19 6.48R5 4/17/2014 11:40 0.00 0.17 1.02 0.48 2.30 0.01 1.30 2.54 0.19 6.33LightEndsIP344‐Allresultsinliquidvolume%Appendix8‐Page1of2Appendix8‐LightEndsData‐RailClientID SampleDate SampleTime Methane Ethane Propane Isobutane n‐Butane Neopentane Isopentane n‐Pentane Cyclopentane HexanesR6 3/26/2014 15:30 <0.01 0.26 1.84 0.69 3.38 0.01 1.56 2.96 0.25 6.38R6 3/26/2014 15:30 <0.01 0.26 1.81 0.69 3.36 0.01 1.56 2.96 0.25 6.40R6 3/27/2014 15:30 <0.01 0.25 1.71 0.66 3.26 0.01 1.54 2.94 0.25 6.43R6 3/31/2014 14:00 <0.01 0.26 1.71 0.66 3.22 0.01 1.53 2.95 0.24 6.49R6 4/7/2014 15:00 0.00 0.19 1.38 0.57 2.83 0.01 1.40 2.71 0.22 5.89R6 4/15/2014 14:00 0.00 0.14 1.20 0.54 2.79 0.01 1.46 2.85 0.23 6.53R6 4/17/2014 12:00 0.00 0.22 1.53 0.62 3.08 0.01 1.52 2.93 0.24 6.61R7 3/26/2014 19:30 <0.01 0.25 1.48 0.60 2.80 0.01 1.42 2.74 0.20 6.30R7 3/26/2014 19:30 <0.01 0.29 1.55 0.61 2.85 0.01 1.43 2.74 0.20 6.27R7 3/28/2014 13:00 <0.01 0.22 1.35 0.56 2.68 0.01 1.40 2.71 0.20 6.38R7 3/31/2014 17:00 0.01 0.28 1.45 0.58 2.71 0.01 1.39 2.67 0.20 6.25R7 4/11/2014 10:50 0.00 0.23 1.34 0.56 2.63 0.01 1.37 2.64 0.19 6.27R7 4/14/2014 12:30 0.00 0.22 1.29 0.55 2.58 0.01 1.36 2.62 0.19 6.21R7 4/18/2014 10:00 0.01 0.21 1.18 0.51 2.45 0.01 1.34 2.57 0.20 6.34Appendix8‐Page2of2Appendix9‐LightEndsData‐WellClientID SampleDate SampleTime Methane Ethane Propane Isobutane n‐Butane Neopentane Isopentane n‐Pentane Cyclopentane HexanesW1 3/25/2014 19:45 0.01 0.31 1.77 0.65 3.12 0.01 1.46 2.73 0.25 6.02W1 3/25/2014 19:45 0.01 0.36 1.85 0.67 3.19 0.01 1.48 2.76 0.25 6.02W1 3/27/2014 18:15 0.01 0.30 1.58 0.60 2.94 0.01 1.42 2.68 0.25 6.04W1 3/30/2014 16:00 0.01 0.29 1.67 0.63 3.06 0.01 1.45 2.73 0.25 6.13W1 4/1/2014 11:00 0.01 0.31 1.59 0.59 2.88 0.01 1.39 2.64 0.24 5.94W1 4/7/2014 12:20 0.00 0.15 1.05 0.46 2.39 0.01 1.28 2.46 0.23 5.75W1 4/16/2014 11:30 0.01 0.25 1.50 0.60 2.96 0.01 1.47 2.78 0.26 6.37W2 3/26/2014 12:45 <0.01 0.30 1.68 0.61 3.00 0.01 1.42 2.71 0.24 6.10W2 3/26/2014 12:45 0.01 0.35 1.82 0.65 3.15 0.01 1.47 2.81 0.25 6.29W2 3/29/2014 15:00 0.01 0.30 1.76 0.63 3.05 0.01 1.42 2.73 0.24 6.14W2 3/31/2014 10:00 0.01 0.34 1.53 0.53 2.62 0.01 1.28 2.48 0.23 5.92W2 4/7/2014 13:05 0.00 0.21 1.52 0.56 2.75 0.01 1.31 2.52 0.23 5.43W2 4/16/2014 12:00 0.00 0.29 1.79 0.66 3.22 0.01 1.49 2.84 0.25 6.36W2 4/19/2014 9:00 0.00 0.26 1.78 0.66 3.18 0.01 1.46 2.77 0.24 6.12W3 3/25/2014 12:30 0.01 0.41 1.95 0.75 3.60 0.01 1.76 3.55 0.24 7.01W3 3/25/2014 12:30 0.01 0.37 1.76 0.68 3.26 0.01 1.59 3.21 0.21 6.79W3 3/27/2014 10:00 0.01 0.39 1.99 0.78 3.71 0.01 1.81 3.65 0.24 7.17W3 3/31/2014 10:00 <0.01 0.30 1.75 0.70 3.36 0.01 1.63 3.28 0.22 7.00W3 4/7/2014 12:50 0.00 0.18 1.20 0.54 2.68 0.01 1.38 2.82 0.19 5.95W3 4/16/2014 10:30 0.00 0.21 1.40 0.61 3.05 0.01 1.57 3.19 0.22 6.93W3 4/18/2014 11:20 0.00 0.24 1.49 0.64 3.13 0.01 1.58 3.21 0.22 6.91W4 3/26/2014 12:00 <0.01 0.17 1.65 0.66 3.33 0.01 1.54 2.87 0.26 6.22W4 3/26/2014 12:00 <0.01 0.16 1.62 0.65 3.32 0.01 1.53 2.85 0.26 6.19W4 3/28/2014 13:15 <0.01 0.16 1.61 0.66 3.36 0.01 1.57 2.43 0.26 6.34W4 4/3/2014 17:25 0.00 0.09 1.23 0.58 3.14 0.01 1.53 2.90 0.26 6.36W4 4/7/2014 18:14 0.00 0.08 1.13 0.55 2.94 0.00 1.49 2.79 0.25 6.13W4 4/15/2014 16:00 0.00 0.19 1.70 0.67 3.38 0.00 1.58 2.95 0.27 6.49W4 4/17/2014 14:30 0.01 0.33 2.38 0.81 3.89 0.01 1.66 3.02 0.30 6.31W5 3/26/2014 15:50 <0.01 0.11 1.44 0.65 3.49 0.01 1.66 3.14 0.28 6.77W5 3/26/2014 15:50 <0.01 0.12 1.52 0.67 3.56 0.01 1.68 3.17 0.28 6.81W5 3/28/2014 13:50 <0.01 0.15 1.54 0.66 3.50 0.01 1.66 3.15 0.28 6.84W5 4/4/2014 17:28 0.00 0.09 1.23 0.57 3.13 0.01 1.53 2.89 0.26 6.10W5 4/7/2014 19:08 0.00 0.12 1.42 0.63 3.36 0.01 1.61 3.06 0.27 6.60W5 4/15/2014 17:00 0.00 0.27 2.34 0.86 4.06 0.01 1.86 3.46 0.30 7.23W5 4/17/2014 15:30 0.00 0.27 2.42 0.88 4.41 0.01 1.88 3.51 0.29 7.19LightEndsIP344‐Allresultsinliquidvolume%Appendix9‐Page1of3Appendix9‐LightEndsData‐WellClientID SampleDate SampleTime Methane Ethane Propane Isobutane n‐Butane Neopentane Isopentane n‐Pentane Cyclopentane HexanesW6 4/6/2014 14:55 0.00 0.24 1.67 0.73 3.28 0.01 1.61 3.11 0.17 6.38W6 4/6/2014 14:55 0.00 0.22 1.60 0.71 3.18 0.01 1.56 3.01 0.17 6.19W6 4/8/2014 13:50 0.00 0.32 2.02 0.83 3.65 0.01 1.72 3.30 0.18 6.82W6 4/15/2014 17:05 0.00 0.36 2.23 0.92 4.03 0.01 1.88 3.60 0.20 7.40W6 4/17/2014 14:05 0.00 0.31 1.94 0.82 3.66 0.01 1.76 3.38 0.19 7.07W6 4/21/2014 16:30 0.00 0.25 1.89 0.82 3.64 0.01 1.74 3.34 0.19 6.96W6 4/24/2014 11:20 0.00 0.28 1.93 0.83 3.68 0.01 1.75 3.35 0.21 6.87W7 3/25/2014 17:00 0.01 0.67 3.13 0.95 4.55 0.01 1.82 3.58 0.27 6.74W7 3/25/2014 17:00 <0.01 0.53 2.72 0.88 4.24 0.01 1.78 3.50 0.27 6.84W7 3/27/2014 13:00 0.01 0.46 2.42 0.82 4.01 0.01 1.74 3.47 0.27 6.96W7 3/31/2014 13:00 <0.01 0.37 2.14 0.77 3.82 0.01 1.71 3.41 0.27 6.96W7 4/7/2014 16:00 0.00 0.21 1.60 0.63 3.25 0.01 1.52 3.05 0.24 6.30W7 4/16/2014 14:20 0.00 0.32 1.98 0.74 3.75 0.01 1.72 3.43 0.27 7.06W7 4/21/2014 13:45 0.00 0.21 1.81 0.72 3.66 0.01 1.70 3.39 0.27 7.03W8 3/25/2014 14:53 <0.01 0.15 1.55 0.83 3.73 0.01 1.93 3.37 0.28 7.26W8 3/25/2014 14:33 <0.01 0.14 1.54 0.83 3.71 0.01 1.93 3.37 0.28 7.26W8 3/27/2014 15:30 <0.01 0.17 1.65 0.83 3.66 0.01 1.89 3.40 0.27 7.53W8 3/31/2014 12:42 <0.01 0.15 1.56 0.80 3.53 0.01 1.80 3.25 0.25 7.22W8 4/9/2014 12:30 0.00 0.12 1.27 0.68 3.13 0.01 1.68 3.20 0.26 6.84W8 4/16/2014 17:00 0.00 0.20 1.62 0.79 3.51 0.01 1.80 3.19 0.27 7.37W8 4/18/2014 13:00 0.00 0.19 1.55 0.76 3.40 0.01 1.80 3.27 0.30 7.64W9 4/1/2014 11:20 0.01 0.25 1.19 0.47 2.33 0.01 1.18 2.21 0.21 5.27W9 4/1/2014 12:10 0.01 0.26 1.22 0.47 2.36 0.01 1.19 2.23 0.21 5.30W9 4/3/2014 13:00 0.00 0.17 1.02 0.42 2.14 0.00 1.10 2.07 0.19 4.98W9 4/8/2014 11:25 0.00 0.19 1.21 0.48 2.41 0.01 1.20 2.24 0.20 5.24W9 4/15/2014 12:33 0.01 0.22 1.16 0.47 2.37 0.01 1.22 2.29 0.21 5.52W9 4/22/2014 11:35 0.01 0.18 1.03 0.43 2.19 <0.01 1.15 2.18 0.20 5.35W9 4/24/2014 14:20 <0.01 0.20 1.12 0.45 2.24 0.01 1.14 2.15 0.20 5.19W10 4/15/2014 15:40 0.00 0.37 2.29 0.94 4.12 0.01 1.91 3.70 0.20 7.41W10 4/15/2014 15:40 0.00 0.29 2.08 0.90 3.97 0.01 1.89 3.67 0.20 7.49W10 4/17/2014 12:50 0.00 0.36 2.25 0.92 4.03 0.01 1.88 3.64 0.19 7.36W10 4/21/2014 15:30 <0.01 0.33 2.19 0.90 3.98 0.01 1.82 3.52 0.19 7.02W10 4/24/2014 12:35 <0.01 0.25 1.95 0.86 3.81 0.01 1.82 3.54 0.19 7.23W10 0.00 0.20 1.76 0.81 3.66 0.01 1.78 3.46 0.19 7.09Appendix9‐Page2of3Appendix9‐LightEndsData‐WellClientID SampleDate SampleTime Methane Ethane Propane Isobutane n‐Butane Neopentane Isopentane n‐Pentane Cyclopentane HexanesW11 4/7/2014 16:35 0.00 0.16 1.56 0.62 3.09 0.01 1.42 2.63 0.24 5.62W11 4/7/2014 16:35 0.00 0.13 1.48 0.60 3.01 0.01 1.39 2.58 0.24 5.52W11 4/11/2014 14:55 0.00 0.34 2.69 0.86 4.03 0.01 1.60 2.91 0.26 5.99W11 4/15/2014 15:00 0.00 0.25 2.10 0.77 3.72 0.01 1.62 2.98 0.27 6.41W11 4/17/2014 13:30 0.00 0.27 2.17 0.77 3.69 0.01 1.59 2.92 0.27 6.23W11 4/20/2014 11:00 0.00 0.15 0.96 0.41 2.32 0.01 1.24 2.59 0.23 6.22W11 4/23/2014 <0.01 0.40 2.99 0.92 4.25 0.01 1.65 2.98 0.26 6.00W12 3/27/2014 12:46 0.00 0.21 1.26 0.50 2.53 0.01 1.26 2.41 0.21 5.57W12 3/27/2014 12:16 0.00 0.22 1.28 0.51 2.56 0.01 1.28 2.42 0.22 5.59W12 3/30/2014 13:00 0.01 0.23 1.25 0.49 2.45 0.01 1.22 2.31 0.21 5.48W12 4/1/2014 13:40 0.01 0.25 1.32 0.51 2.51 0.01 1.24 2.35 0.21 5.52W12 4/8/2014 13:20 0.00 0.18 1.17 0.48 2.41 0.01 1.22 2.32 0.21 5.42W12 4/17/2014 15:10 0.01 0.18 1.06 0.45 2.30 0.00 1.22 2.35 0.22 5.77W12 4/17/2014 15:30 0.01 0.20 1.11 0.46 2.30 0.01 1.21 2.32 0.21 5.63W13 3/26/2014 17:00 <0.01 0.22 1.69 0.69 3.25 0.01 1.49 2.72 0.22 5.85W13 3/26/2014 17:00 <0.01 0.21 1.65 0.68 3.22 0.01 1.49 2.72 0.22 5.88W13 3/28/2014 15:30 0.01 0.24 1.57 0.63 3.02 0.01 1.45 2.68 0.22 5.93W13 4/4/2014 15:15 0.00 0.16 1.42 0.61 2.93 0.01 1.38 2.52 0.20 5.34W13 4/8/2014 11:00 0.00 0.26 1.91 0.74 3.40 0.01 1.51 2.73 0.22 5.84W13 4/15/2014 19:30 0.00 0.19 1.73 0.74 3.56 0.01 1.69 3.10 0.25 6.84W13 4/19/2014 14:00 0.00 0.31 1.94 0.68 3.29 0.01 1.47 2.80 0.24 6.12W14 4/6/2014 16:20 0.01 0.22 1.12 0.43 2.32 0.01 1.20 2.49 0.21 5.63W14 4/6/2014 16:20 0.01 0.21 1.10 0.42 2.29 0.00 1.20 2.48 0.21 5.63W14 4/4/2014 11:55 <0.01 0.22 1.24 0.48 2.57 0.01 1.32 2.73 0.23 6.35W14 4/8/2014 12:30 0.00 0.26 1.53 0.56 2.89 0.01 1.38 2.81 0.23 6.20W14 4/18/2014 16:30 0.01 0.16 1.00 0.42 2.35 0.01 1.25 2.58 0.22 6.11W14 4/20/2014 14:00 0.01 0.16 0.89 0.37 2.10 0.00 1.16 2.45 0.22 6.13W14 4/22/2014 11:00 <0.01 0.14 0.84 0.35 2.00 <0.01 1.11 2.33 0.21 5.84W15 4/9/2014 17:20 0.00 0.25 1.41 0.58 2.67 0.01 1.38 2.61 0.20 6.12W15 4/9/2014 17:20 0.00 0.24 1.42 0.58 2.69 0.01 1.38 2.62 0.20 6.14W15 4/18/2014 19:30 0.00 0.21 1.16 0.50 2.40 0.01 1.33 2.55 0.20 6.22W15 4/21/2014 18:30 <0.01 0.24 1.38 0.56 2.62 0.01 1.36 2.59 0.20 6.13W15 4/23/2014 13:00 <0.01 0.24 1.40 0.58 2.67 0.01 1.38 2.60 0.20 6.13W15 4/24/2014 16:30 0.00 0.18 1.31 0.56 2.66 0.01 1.40 2.66 0.21 6.26Appendix9‐Page3of3Appendix10‐SimulatedDistillationData‐RailClientID SampleDate SampleTime SimDisIBP 5% 10% 20% 30% 40% 50% 60% 70% 80% 90% 95% FBPRecovery(weight%)AdditionalComments‐FieldorLabR1 3/25/2014 17:20 <97 151 186 264 343 430 517 609 710 823 967 1071 1278 100.0 OilTemp35°FR1 3/25/2014 17:00 <97 151 183 263 346 436 527 623 730 850 1012 1150 >1382 97.6R1 3/27/2014 17:26 <97 104 176 252 332 423 513 608 713 828 973 1076 1307 100.0R1 3/31/2014 14:08 <97 127 177 239 315 391 473 559 650 760 903 1009 1217 100.0R1 4/9/2014 10:38 <97 <97 153 222 300 376 459 549 647 761 909 1019 1246 100.0R1 4/16/2014 15:30R1 4/18/2014 11:00R2 3/25/2014 18:00 <97 135 168 235 313 388 470 557 651 763 909 1017 1226 100.0R2 3/25/2014 18:00 <97 138 178 246 320 388 477 564 659 772 921 1033 1317 99.7R2 3/27/2014 10:30 <97 98 158 223 289 364 443 527 620 733 888 1013 >1382 99.1R2 3/31/2014 12:30 <97 107 164 232 302 376 454 540 630 742 889 1000 1219 100.0R2 4/8/2014 10:20 <97 <97 143 216 295 379 468 561 664 783 936 1048 1257 100.0R2 4/15/2014 11:30R2 4/18/2014 10:20R3 3/26/2014 14:30 <97 112 175 245 325 405 488 576 675 788 933 1039 1244 100.0 OilTemp37°FR3 3/26/2014 14:30 <97 146 177 251 326 408 492 581 679 791 935 1040 1256 100.0 OilTemp37°FR3 3/28/2014 13:30 <97 <97 157 235 317 403 490 583 686 805 957 1073 1309 100.0 OilTemp49°FR3 4/1/2014 16:10 <97 <97 162 235 320 405 496 591 696 820 994 1180 >1382 95.9R3 4/10/2014 14:50 <97 <97 158 238 317 398 486 577 678 795 946 1062 >1382 99.1R3 4/15/2014 14:15R3 4/17/2014 13:00R4 3/25/2014 14:30 <97 111 156 234 314 393 480 573 674 796 962 1107 >1382 99.8R4 3/25/2014 14:30 <97 133 167 237 318 399 484 574 673 792 950 1077 >1382 98.9R4 3/27/2014 11:50 <97 <97 163 238 320 403 489 581 682 800 954 1072 1318 100.0R4 3/31/2014 11:20 <97 103 168 239 318 399 486 575 674 791 945 1065 >1382 99.1R4 4/7/2014 13:45 <97 <97 157 233 305 385 474 563 663 779 925 1029 1220 100.0R4 4/16/2014 12:35R4 4/18/2014 12:05R5 3/26/2014 12:00 <97 117 168 236 314 390 475 563 660 775 927 1049 >1382 98.7R5 3/26/2014 12:00 <97 <97 159 234 315 394 481 575 675 796 959 1089 1341 100.0R5 3/28/2014 12:00 <97 <97 160 233 311 389 475 564 662 777 924 1037 1276 100.0R5 4/1/2014 14:30 <97 <97 151 227 306 385 474 569 671 792 957 1116 >1382 96.6R5 4/10/2014 13:15 <97 <97 158 236 306 385 466 555 651 764 910 1019 1272 99.8R5 4/15/2014 12:50R5 4/17/2014 11:40SimulatedDistillationbyASTMD7169‐Allresultsreportedin°FAppendix10‐Page1of2Appendix10‐SimulatedDistillationData‐RailClientID SampleDate SampleTime SimDisIBP 5% 10% 20% 30% 40% 50% 60% 70% 80% 90% 95% FBPRecovery(weight%)AdditionalComments‐FieldorLabR6 3/26/2014 15:30 <97 116 156 232 310 388 471 558 650 758 900 1008 1342 99.5R6 3/26/2014 15:30 <97 131 165 235 315 394 476 562 654 762 900 1004 1230 100.0R6 3/27/2014 15:30 <97 <97 162 236 315 395 481 570 665 778 929 1056 >1382 98.5R6 3/31/2014 14:00 <97 106 168 237 320 404 490 580 680 797 962 1126 >1382 96.7R6 4/7/2014 15:00 <97 <97 152 225 302 383 466 555 650 763 909 1021 1308 100.0R6 4/15/2014 14:00R6 4/17/2014 12:00R7 3/26/2014 19:30 <97 138 171 237 316 394 479 570 668 783 931 1040 1278 100.0R7 3/26/2014 19:30 <97 146 179 255 330 418 504 596 700 822 987 1122 >1382 98.7R7 3/28/2014 13:00 <97 114 176 242 322 403 488 580 683 803 962 1086 >1382 98.8R7 3/31/2014 17:00 <97 127 179 254 327 409 496 587 691 811 971 1099 >1382 98.4R7 4/11/2014 10:50 <97 <97 154 236 313 391 480 575 647 792 941 1052 1297 100.0R7 4/14/2014 12:30R7 4/18/2014 10:00Appendix10‐Page2of2Appendix11‐SimulatedDistillationData‐WellClientID SampleDate SampleTime SimDisIBP 5% 10% 20% 30% 40% 50% 60% 70% 80% 90% 95% FBPRecovery(weight%)AdditionalComments‐FieldorLabW1 3/25/201419:45 <97 135 178 259 342 428 517 610 713 827 974 1086 1329 100.0W1 3/25/201419:45 <97 150 188 272 355 442 531 623 725 839 987 1102 1337 100.0W1 3/27/201418:15 <97 119 179 257 334 422 510 601 703 815 958 1071 >1382 98.8W1 3/30/201416:00 <97 142 180 262 344 432 524 621 726 846 1011 1176 >1382 96.7W1 4/1/2014 11:00 <97 <97 148 224 310 396 488 584 688 803 947 1050 1248 100.0W1 4/7/2014 12:20W1 4/16/201411:30W2 3/26/201412:45 <97 143 179 261 342 424 508 596 693 803 952 1072 1328 100.0W2 3/26/201412:45 <97 140 184 263 342 422 505 590 685 793 937 1050 1303 100.0W2 3/29/201415:00 <97 108 165 237 318 400 482 569 661 768 903 1004 1248 99.7W2 3/31/201410:00 <97 136 178 255 329 412 492 577 670 774 910 1013 1244 100.0W2 4/7/2014 13:05 <97 <97 154 235 316 398 481 570 664 772 911 1018 1316 100.0W2 4/16/201412:00W2 4/19/20149:00W3 3/25/201412:30 <97 <97 157 232 304 383 462 548 639 748 895 1016 >1382 98.6W3 3/25/201412:30 <97 <97 161 234 310 384 464 547 638 744 886 995 1283 99.8W3 3/27/201410:00 <97 <97 159 230 300 374 456 545 638 750 903 1037 >1382 98.1W3 3/31/201410:00 <97 97 159 230 298 371 453 537 629 737 879 990 >1382 99.4W3 4/7/2014 12:50 <97 <97 154 224 297 372 453 537 628 737 880 992 1329 100.0W3 4/16/201410:30W3 4/18/201411:20W4 3/26/201412:00 <97 100 158 236 318 406 491 579 675 788 940 1076 >1382 97.7W4 3/26/201412:00 <97 110 165 239 319 405 488 575 667 774 914 1023 >1382 99.4W4 3/28/201413:15 <97 119 169 243 322 409 493 581 678 792 947 1082 >1382 98.2W4 4/3/2014 17:25 <97 <97 104 207 286 373 460 552 648 760 904 1014 1273 100.0W4 4/7/2014 18:14 <97 <97 152 233 315 402 490 582 683 801 966 1121 >1382 98.3W4 4/15/201416:00W4 4/17/201414:30W5 3/26/201415:50 <97 101 160 234 312 390 475 562 656 767 914 1028 1289 100.0W5 3/26/201415:50 <97 <97 146 216 292 374 458 548 642 753 898 1008 1257 100.0W5 3/28/201413:50 <97 <97 156 225 300 377 458 547 640 751 896 1010 1272 100.0W5 4/4/2014 17:28 <97 <97 132 205 280 366 454 548 645 757 903 1020 >1382 98.7W5 4/7/2014 19:08 <97 <97 135 209 285 364 448 538 633 747 894 1009 1322 100.0W5 4/15/201417:00W5 4/17/201415:30W6 4/6/2014 14:55 <97 <97 129 204 277 349 436 528 629 751 914 1037 >1382 98.9W6 4/6/2014 14:55 <97 <97 103 189 264 336 420 513 613 734 891 1004 1218 99.9W6 4/8/2014 13:50 <97 <97 156 236 304 377 461 554 658 789 977 1157 >1382 96.6W6 4/15/201417:05 <97 <97 <97 188 257 331 419 510 611 734 895 1010 1217 100.0W6 4/17/201414:05 <97 <97 145 206 278 348 433 521 622 741 899 1011 1214 100.0W6 4/21/201416:30W6 4/24/201411:20SimulatedDistillationbyASTMD7169‐Allresultsreportedin°FAppendix11‐Page1of3Appendix11‐SimulatedDistillationData‐WellClientID SampleDate SampleTime SimDisIBP 5% 10% 20% 30% 40% 50% 60% 70% 80% 90% 95% FBPRecovery(weight%)AdditionalComments‐FieldorLabW7 3/25/201417:00 <97 118 155 231 302 376 453 536 623 727 867 975 1220 100.0W7 3/25/201417:00 <97 135 177 252 326 404 484 568 661 777 955 1192 >1382 95.7W7 3/27/201413:00 <97 <97 104 204 285 366 450 538 633 747 905 1035 1328 100.0W7 3/31/201413:00 <97 <97 156 221 296 372 453 536 627 735 883 1007 >1382 98.7W7 4/7/2014 16:00 <97 <97 132 208 282 356 437 520 611 718 860 971 1220 100.0W7 4/16/201414:20W7 4/21/201413:45W8 3/25/201414:53 <97 128 157 231 305 386 471 560 653 766 932 1121 >1382 96.5W8 3/25/201414:33 <97 112 153 217 290 370 452 535 623 726 861 966 1198 100.0W8 3/27/201415:30 <97 <97 158 219 294 376 461 549 643 755 914 1079 >1382 96.9W8 3/31/201412:42 <97 104 163 232 311 391 477 566 660 776 937 1060 1293 100.0W8 4/9/2014 12:30 <97 <97 153 222 301 381 459 545 629 734 870 976 1230 100.0W8 4/16/201417:00W8 4/18/201413:00W9 4/1/2014 11:20 <97 141 187 278 373 470 570 672 783 903 1044 1139 1320 100.0 StockTankID43047W9 4/1/2014 12:10 <97 137 180 276 375 476 578 684 796 920 1069 1182 >1382 97.8 StockTankID43047W9 4/3/2014 13:00 <97 97 178 265 358 456 558 660 772 893 1037 1134 1362 99.7 StockTankID43043W9 4/8/2014 11:25 <97 <97 174 263 353 451 549 649 758 879 1025 1124 1331 100.0 StockTankID43043W9 4/15/201412:33 <97 <97 157 243 341 439 538 641 754 876 1023 1118 1284 100.0 StockTankID43054W9 4/22/201411:35StockTankID43054W9 4/24/201414:20StockTankID43048W10 4/15/201415:40 <97 <97 126 200 267 344 432 525 631 754 912 1019 1209 100.0W10 4/15/201415:40 <97 <97 145 205 278 349 437 528 630 750 901 1005 1186 100.0W10 4/17/201412:50 <97 <97 <97 182 251 330 419 513 621 749 906 1013 1209 100.0W10 4/21/201415:30 <97 <97 <97 180 244 327 413 509 615 740 900 1010 1222 100.0W10 4/24/201412:35 <97 <97 <97 181 246 327 412 508 613 738 896 1005 1219 100.0W10W11 4/7/2014 16:35 <97 <97 132 211 289 375 466 560 657 769 913 1023 1255 100.0W11 4/7/2014 16:35 <97 <97 131 213 292 377 467 561 658 771 915 1025 1260 100.0W11 4/11/201414:55 <97 <97 150 219 298 383 469 561 656 769 913 1023 >1382 99.2W11 4/15/201415:00 <97 <97 146 213 289 371 455 546 639 752 898 1007 1210 100.0W11 4/17/201413:30 <97 <97 <97 204 283 370 459 554 653 769 916 1026 1241 100.0W11 4/20/201411:00W11 4/23/2014W12 3/27/201412:46 <97 <97 164 254 343 439 536 636 748 869 1015 1114 1327 100.0W12 3/27/201412:16 <97 <97 168 260 346 443 542 642 754 877 1025 1127 >1382 99.4W12 3/30/201413:00 <97 141 181 267 354 451 547 647 756 878 1022 1120 1308 100.0W12 4/1/2014 13:40 <97 146 184 270 359 454 552 652 763 886 1036 1140 >1382 99.0W12 4/8/2014 13:20 <97 100 179 266 355 453 550 651 762 885 1031 1130 1337 100.0W12 4/17/201415:10W12 4/17/201415:30Appendix11‐Page2of3Appendix11‐SimulatedDistillationData‐WellClientID SampleDate SampleTime SimDisIBP 5% 10% 20% 30% 40% 50% 60% 70% 80% 90% 95% FBPRecovery(weight%)AdditionalComments‐FieldorLabW13 3/26/201417:00 <97 110 165 240 327 418 503 589 684 792 938 1063 >1382 98.5W13 3/26/201417:00 <97 <97 155 231 313 403 490 578 674 783 924 1042 >1382 98.9W13 3/28/201415:30 <97 120 175 247 332 425 514 602 702 814 978 1165 >1382 96.5W13 4/4/2014 15:15 <97 <97 136 219 303 394 488 582 683 797 959 1141 >1382 96.2W13 4/8/2014 11:00 <97 <97 154 233 313 400 488 576 670 777 913 1018 1270 100.0W13 4/15/201419:30W13 4/19/201414:00W14 4/6/2014 16:20 <97 <97 149 229 315 397 484 574 670 780 926 1044 >1382 99.5W14 4/6/2014 16:20 <97 <97 168 248 325 409 495 584 679 789 936 1053 1298 100.0W14 4/4/2014 11:55 <97 <97 137 217 300 384 473 563 661 774 923 1039 1262 100.0W14 4/8/2014 12:30 <97 <97 155 236 315 392 477 565 660 768 910 1018 1257 100.0W14 4/18/201416:30 <97 98 174 244 328 411 496 585 681 790 931 1035 1225 100.0W14 4/20/201414:00 <97 110 181 250 331 416 500 587 683 792 931 1035 1225 100.0W14 4/22/201411:00 <97 <97 153 238 320 403 489 579 677 789 932 1040 1262 100.0W15 4/9/2014 17:20 <97 <97 158 237 313 390 477 570 671 789 942 1053 1282 100.0W15 4/9/2014 17:20 <97 <97 154 235 309 388 476 570 672 790 945 1058 1307 100.0W15 4/18/201419:30 <97 <97 153 232 307 389 478 572 674 794 947 1054 1251 100.0W15 4/21/201418:30 <97 <97 147 221 301 383 472 566 670 791 946 1055 1263 100.0W15 4/23/201413:00W15 4/24/201416:30Appendix11‐Page3of3Appendix12‐SeasonalityData(MemberContributed)DATEProd.TrainAProd.TrainBProd.TrainAProd.TrainBProd.TrainAProd.TrainBProd.TrainAProd.TrainB8/1/2013 8.96 8.62 10/30/2013 9.08 9.67 1/3/2014 10.51 10.12 2/23/2014 9.56 11.258/2/2013 8.75 8.47 11/7/2013 9.96 10.05 1/3/2014 10.38 10.44 2/24/2014 10.218/5/2013 8.48 8.54 11/8/2013 10.30 10.50 1/5/2014 10.45 2/26/2014 10.83 10.828/16/2013 8.58 8.28 11/9/2013 10.38 10.57 1/6/2014 9.53 10.84 2/28/2014 11.34 11.048/18/2013 8.75 8.33 11/11/2013 10.24 10.38 1/9/2014 10.62 10.66 3/2/2014 9.898/22/2013 8.82 8.04 11/14/2013 9.71 9.18 1/10/2014 10.75 10.83 3/3/2014 9.94 10.178/26/2013 8.56 8.25 11/17/2013 10.33 10.28 1/14/2014 10.93 11.05 3/4/2014 10.73 10.178/29/2013 8.48 11/18/2013 10.49 10.56 1/16/2014 11.07 11.02 3/5/2014 10.85 11.079/1/2013 8.43 7.94 11/19/2013 9.70 10.28 1/18/2014 10.42 10.48 3/6/2014 10.43 10.419/5/2013 7.99 7.93 11/22/2013 10.06 9.99 1/19/2014 10.56 10.20 3/7/2014 10.73 10.799/11/2013 8.29 8.31 11/24/2013 9.94 9.94 1/20/2014 10.14 10.91 3/7/2014 10.91 10.899/13/2013 8.43 8.29 11/25/2013 10.62 10.69 1/20/2014 10.67 10.98 3/8/2014 11.23 11.239/14/2013 7.90 7.96 11/26/2013 10.69 10.66 1/21/2014 10.86 11.01 3/9/2014 10.62 10.389/15/2013 8.73 8.89 12/2/2013 8.89 8.38 1/21/2014 10.85 10.25 3/11/2014 10.23 10.089/23/2013 8.50 8.80 12/4/2013 9.67 9.82 1/22/2014 10.67 10.44 3/11/2014 10.63 10.929/25/2013 8.27 8.57 12/8/2013 10.06 10.10 1/30/2014 10.95 3/13/2014 10.25 10.129/26/2013 8.43 8.63 12/8/2013 9.58 9.18 1/30/2014 10.89 3/15/2014 10.15 10.249/27/2013 8.41 8.77 12/9/2013 10.40 10.10 2/2/2014 10.83 3/16/2014 10.37 10.3010/4/2013 8.70 12/10/2013 10.76 10.77 2/5/2014 11.25 3/18/2014 10.41 10.3710/7/2013 9.09 8.83 12/13/2013 11.08 11.04 2/6/2014 10.77 3/20/2014 10.12 10.1110/10/2013 9.22 8.53 12/21/2013 10.61 11.18 2/7/2014 8.70 3/21/2014 10.11 9.9110/14/2013 9.79 8.70 12/22/2013 9.70 9.10 2/12/2014 11.45 11.60 3/22/2014 10.25 10.3010/19/2013 9.10 9.20 12/23/2013 10.90 10.94 2/13/2014 10.66 3/22/2014 10.25 10.3010/20/2013 9.79 9.69 12/24/2013 10.17 10.81 2/13/2014 10.62 10.60 3/23/2014 10.3310/22/2013 9.53 9.63 12/25/2013 10.21 10.23 2/14/2014 10.18 10.50 3/24/2014 10.4610/24/2013 9.44 12/27/2013 10.54 10.09 2/16/2014 10.81 10.86 3/28/2014 10.4110/25/2013 9.24 9.40 12/29/2013 10.96 10.29 2/18/2014 10.88 10.75 3/29/2014 10.52 10.2410/26/2013 9.24 9.56 12/30/2013 10.63 10.00 2/20/2014 10.43 10.33 3/30/2014 10.43 10.1810/28/2013 9.21 9.38 12/31/2013 9.89 9.89 2/22/2014 10.52 9.49RVP(psi) RVP(psi) RVP(psi) RVP(psi)Appendix12‐Page1of1Appendix13‐Interlaboratory(Round‐Robin)DataLab Sample API VaporPD6377(kPa) VaporPD6377(psi) D86IBP(°F) CondenserT(°F) RecieverT(°F)LabM 42.98 103.3 14.98 83.1 32.9 60.0SGS(St.Rose)42.91 106.5 15.44 89.1 60 73102.6 60 8188.7 31 82LabM 40.22 69.7 10.11 89.9 32.9 60.0SGS(St.Rose)40.18 70.7 10.26 95.4 60 73101.8 60 8091.1 31 82LabM 43.63 73.2 10.62 87.8 32.9 60.0SGS(St.Rose)43.56 73.4 10.64 90.7 60 73105.5 60 8191.4 31 81LabM 42.97 78.8 11.43 89.2 32.9 60.0SGS(St.Rose)42.89 79.5 11.53 94.5 60 73102..2 60 8194.4 31 82LabCondenserTemp(°F)ReceiverTemp(°F)Sample D86IBP D86IBP(°F) D86IBP(°F) TimetoIBP D86IBP(°F) TimetoIBP1 89.1 3min22sec 102.6 6min27sec 88.7 6min07sec2 95.4 4min53sec 101.8 7min56sec 91.1 7min45sec3 90.7 3min37sec 105.5 7min26sec 91.4 7min11sec4 94.5 3min42sec 102.2 6min50sec 94.4 8min00sec31SGS(Williston)SGS(Williston)SGS(Williston)SGS(Williston)SGS(Williston)SGS(Williston)43.61432142.888110.5940.1742.86 95.0 13.7810.1169.773.011.2177.3SGS(St.Rose)60736081Appendix13‐Page1of1Appendix 14

– Glossary of Terms

Page 1 of 2 AFPM

– American Fuel & Petrochemical Manufacturers

API

– American Petroleum Institute

ASTM

– American Soc iety for Testing and Materials

BKN

– Bakken

BS&W

– Basic Sediment & Water

DOT

– Department of Transportation

EPA

– Environmental Protection Agency

FPCs

– Floating Piston Cylinders

H 2 S

– Hydrogen Sulfide

IBP

– Initial Boiling Point

LLS

– Light Louisiana Sweet

LPG

- Liquefied Petroleum Gas

LTO

– Light Tight Oil

NACE

– National Association of Corrosion Engineers

ND

– North Dakota

NDPC

– North Dakota Petroleum Council

NGL

– Natural Gas Liquids

PG

– Packing Group

PHMSA

– Pipeline and Hazardous Safety Materials Administration

psi

– Pounds per Square Inch

psig

– Pounds per Square Inch Gauge

QA/QC

– Quality Assurance / Quality Control

R VP

– Reid Vapor Pressure

SGS

– Laboratory Testing ProviderAppendix 14

– Glossary of Terms

Page 2 of 2 SimDist

– Simulated Distillation

TAN

– Total Acid Number

TM&C

– Turner, Mason & Company

VPCR

– ASTM D 6377 Vapor Pressure

WTI

– West Texas Intermediate